bluuebunny/crossref_metadata_2025 huggingface dataset:
Geochemical characterization of moldavites from a new locality, the Cheb Basin, Czech Republic
Authors: Řanda Zdeněk , Mizera Jiří , Frána Jaroslav , KuČEra Jan
Published: January 2010

Abstract— Twenty‐three moldavites from a new locality, the Cheb Basin in Western Bohemia, were analyzed by instrumental neutron activation analysis for 45 major and trace elements. Detailed comparison of the Cheb Basin moldavites with moldavites from other substrewn fields in both major and trace element composition shows that the Cheb Basin is a separate substrewn field. The geochemical data obtained are discussed with respect to the source materials and processes leading to formation of moldavites. The data show that three groups of Cheb Basin moldavites exist. Ten samples of group 1 are characterized by the lowest content of Al, Fe, Na, and other elements representing phyllosilicate minerals, and by high Ca + Mg contents related probably to carbonates. They resemble the “poisonous green” moldavites, a subgroup of the Southern Bohemian moldavites. Seven samples of group 2 and 6 samples of group 3 are similar to typical moldavites of the Southern Bohemian substrewn field. These two groups differ from each other mainly in Al contents; with higher contents of Al and the elements associated with phyllosilicate minerals (namely Ba and Sr), group 3 also resembles the Moravian moldavites. Significant positive correlations between K, Ca, Mg, and Mn found in group 2 of the Cheb Basin moldavites and the enrichment in these elements observed generally in all moldavites, as well as other facts, e.g., high K/Na and K/Rb ratios and the reduced conditions during formation of moldavites, have been attributed to possible contribution to the moldavite source materials of the ash produced by burning of vegetation and soil organic matter present at the pre‐impact area.
The classification of micrometeorites
Authors: Genge M. J. , Engrand C. , Gounelle M. , Taylor S.
Published: January 2010

Abstract— Due to their small size, the mineralogical and chemical properties of micrometeorites (MMs) are not representative of their parent bodies on the centimeter to meter scales that are used to define parent body groups through the petrological study of meteorites. Identifying which groups of MM are derived from the same type of parent body is problematic and requires particles to be rigorously grouped on the basis of mineralogical, textural, and chemical properties that reflect the fundamental genetic differences between meteorite parent bodies, albeit with minimal bias towards preconceived genetic models. Specifically, the interpretation of MMs requires a rigorous and meaningful classification scheme. At present the classification of MMs is, however, at best ambiguous. A unified petrological‐chemical classification scheme is proposed in the current study and is based on observations of several thousand MMs collected from Antarctic ice.
Acquisition of shock remanent magnetization for demagnetized samples in a weak magnetic field (7 μT) by shock pressures 5–20 GPa without plasma‐induced magnetization
Authors: Funaki Minoru , Syono Yasuhiko
Published: January 2010

Abstract— Demagnetized samples of cobalt precipitates in a copper matrix were shocked to 5, 10, and 20 GPa in a weak magnetic field of 7.7 μT to elucidate the origins of the natural remanent magnetization of meteorites and the magnetic anomalies of impact craters on the moon and Mars. The samples placed in the target acquired shock remanent magnetization (SRM) whose intensity increased up to 21.3 times compared with the demagnetized state, but SRM intensity and shock intensity were not correlated. The SRM direction was in most cases approximately perpendicular to the shock direction. The samples placed 4.8 mm from the impacted surface did not acquire significant magnetization, suggesting no plasma‐induced remanent magnetization (PIRM) up to 20 GPa. When the samples were divided into 8 sub‐samples, the SRM intensities of sub‐samples increased up to 40 times compared with bulk ones and their directions were scattered. Higher coercive force grains were magnetized perpendicular to the shock direction for shocks of 5 and 10 GPa, but at 20 GPa the directions were less systematically oriented. These results suggest that the proposed plasma‐induced magnetization of impactites should be reconsidered.
The Meteoritical Bulletin, No. 93, 2008 March
Authors: Connolly Harold C. , Smith Caroline , Benedix Gretchen , Folco Luigi , Righter Kevin , Zipfel Jutta , Yamaguchi Akira , Aoudjehane Hasnaa Chennaoui
Published: January 2010

Abstract— In this edition of the Meteoritical Bulletin, 1443 approved meteorite names with their relevant data are reported, one from a specific location within Africa, 211 from Northwest Africa, 5 from KOREAMET, 598 from the Chinese Antarctic Expedition, 23 from the Americas, 151 from Asia, three from Australia, two from Europe, two from NOVA, and 447 from ANSMET that were not reported in the Meteoritical Bulletin no. 87. Also reported are 4 falls from the Americas. Some highlights of approved meteorites are 10 lunar (including NWA 5000, an 11.528 kg sample), 3 Martian, 4 irons (one from Indonesia), 2 ureilites, 5 mesosiderites, 1 pallasite, 6 brachinites, 3 CV3s, 4 CO3s, 8 CMs, 12 CK3s, and many more. Finally, the Committee on Nomenclature of the Meteoritical Society announces two new names series in North America.
Frontier Mountain meteorite specimens of the acapulcoite‐lodranite clan: Petrography, pairing, and parent‐rock lithology of an unusual intrusive rock
Authors: BURRONI Alessandro , FOLCO Luigi
Published: January 2010

Abstract— In this paper we reconstruct the heterogeneous lithology of an unusual intrusive rock from the acapulcoite‐lodranite (AL) parent asteroid on the basis of the petrographic analysis of 5 small (<8.3 g) meteorite specimens from the Frontier Mountain ice field (Antarctica). Although these individual specimens may not be representative of the parent‐rock lithology due to their relatively large grain size, by putting together evidence from various thin sections and literature data we conclude that Frontier Mountain (FRO) 90011, FRO 93001, FRO 99030, and FRO 03001 are paired fragments of a medium‐ to coarse‐grained igneous rock which intrudes a lodranite and entrains xenoliths. The igneous matrix is composed of enstatite (Fs13.3 ± 0.4 Wo3.1 ± 0.2), Cr‐rich augite (Fs6.1 ± 0.7 Wo42.3 ± 0.9), and oligoclase (Ab80.5 ± 3.3 Or3.2 ± 0.6). The lodranitic xenoliths show a fine‐grained (average grain size 488 ± 201 μm) granoblastic texture and consist of olivine Fa9.5 ± 0.4 and Fe,Ni metal and minor amounts of enstatite Fs12.7 ± 0.4 Wo1.8 ± 0.1, troilite, chromite, schreibersite, and Ca‐phosphates. Crystals of the igneous matrix and lodranitic xenoliths are devoid of shock features down to the scanning electron microscope scale. From a petrogenetic point of view, the lack of shock evidence in the lodranitic xenoliths of all the studied samples favors the magmatic rather than the impact melting origin of this rock.

FRO 95029 is an acapulcoite and represents a separate fall from the AL parent asteroid, i.e., it is not a different clast entrained by the FRO 90011, FRO 93001, FRO 99030, and FRO 03001 melt, as in genomict breccias common in the meteoritic record. The specimen‐to‐meteorite ratio for the AL meteorites so far found at Frontier Mountain is thus 2.5.
Experimental impacts into chondritic targets, part I: Disruption of an L6 chondrite by multiple impacts
Authors: CINTALA Mark J. , HöRZ Friedrich
Published: January 2010

Abstract— A fragment of an L6 chondrite (Allan Hills [ALH] 85017,13) with an initial mass (M0) of 464.1 g was the target in a series of experimental impacts in which the largest remaining fragment (MR) after each shot was impacted by a 3.18 mm ceramic sphere at a nominal speed of 2 km s−1. This continued until the mass of the largest remaining piece was less than half the mass of the target presented to that shot (MS). Two chunks of Bushveldt gabbro with similar initial masses were also impacted under the same conditions until MR was less than half M0. The two gabbro targets required a total of 1.51 × 107 and 1.75 × 107 erg g−1 to attain 0.27 and 0.33 MR/M0, respectively; the chondrite, however, was considerably tougher, reaching 0.40 and 0.21 MR/M0 only after receiving 2.37 × 107 and 3.10 × 107 erg g−1, respectively. The combined ejecta and spallation products from the gabbro impacts were coarser than those from the chondrite and in sufficient quantities that the new surface areas exceeded those from the meteorite until the fifth shot in the chondrite series, which was the number of impacts required to disrupt each gabbro target (i.e., MR/M0 ≤ 0.5). Unlike the behavior shown in previous regolith‐evolution series, neither gabbro target produced an enhancement in the size fraction reflecting the mean size of the crystals composing the rock (about 3 mm), an effect possibly related to the width of the shock pulse. The original chondrite was so fine‐grained and fractured, and the variance in its grain‐size distribution so large, that effects related to grain size were relegated to the<63 μm fraction. Impacts into ALH 85017 produced abundant, fine‐grained debris, but otherwise the slopes of its size distributions were comparable to those from other experiments involving natural and fabricated terrestrial targets. The characteristic slopes of the chondrite's size distributions, however, were notably more constant over the entire nine‐impact series than those from any of the terrestrial targets, a testament to the control over comminution apparently exerted by pre‐existing fractures and other, microscopic damage in the meteorite. The enhancement in the finer fraction of debris from ALH 85017 indicates that ordinary chondrites in solar orbit would be very efficient contributors to the cosmic‐dust complex. At the same time, the greater resistance to disruption displayed by ordinary chondrites relative to that exhibited by igneous rocks indicates that a selection effect could be operative between the annealed, ordinary‐chondritic breccias and relatively weaker, differentiated meteorites. Preferential survival from their time in the regoliths of their parent bodies through their transit to Earth and passage through the atmosphere suggests that meteorite collections could be biased in favor of the ordinary chondrites.
Numerical simulation of a permittivity probe for measuring the electric properties of planetary regolith and application to the near‐surface region of asteroids and comets
Authors: SPITZER Klaus , SOHL Frank , PANZNER Martin
Published: January 2010

Abstract— We present a numerical simulation technique for the retrieval of the electric properties relative permittivity and conductivity of planetary, asteroid, and cometary regolith. Our simulation techniques aim at accompanying hardware development and conducting virtual experiments, e.g., to assess the response of arbitrary heterogeneous conductivity and permittivity distributions or to scrutinize possibilities for spatial reconstruction methods using inverse schemes. In a first step, we have developed a finite element simulation code on the basis of unstructured, adaptive triangular grids for arbitrary two‐dimensional axisymmetric distributions of conductivity and permittivity. The code is able to take into account the spatial geometry of the probe and allows for possible inductive effects. In previous studies, the non‐inductive approach has been used to convert potential and phase data into apparent material properties. By our simulations, we have shown that this approach is valid for the frequency range from 102 Hz to 107 Hz and electric conductivities of 10−8 S/m that are typical for the near‐surface region of asteroids and comets composed of chondritic materials and/or frozen volatiles such as H2O and CO2 ice. We prove the accuracy of our code to be better than 10%, using mixed types of boundary conditions and present a simulated vertical log through a horizontally stratified subsurface layer as a representative example of a heterogeneous distribution of the electrical properties. Resolution studies for the given electrode separation reveal that the material parameters of layers having thicknesses of less than about half the electrode spread are not reconstructible if only apparent quantities are considered. Therefore, spatial distributions of the complex sensitivity are presented having in mind a future data inversion concept that will permit the multi‐dimensional reconstruction of material parameters in heterogeneous environments.
Finite difference time domain simulation of radar wave propagation through comet nuclei dielectric models
Authors: CARLEY Ruth A. , HEGGY Essam
Published: January 2010

Abstract— The 90 MHz radar‐wave experiment, Comet Nucleus Sounding Experiment by Radiowave Transmission (CONSERT), on board the Rosetta mission (ESA, 2004) is expected to probe the nucleus of the comet 67P/Churyumov‐Gerasimenko (67P/C‐G) to reveal information on its physical properties, chemical composition, and internal structure. This investigation assesses the potential to recognize lithological structure in the comet nucleus with a radar experiment such as CONSERT. Radar simulations at 90 MHz were performed with a finite difference time domain (FDTD) method. The amplitude and losses of the transmitted and reflected electric field components of an incident radar pulse were evaluated as a function of time. Seven different dielectric models of sections of a hypothetical comet nucleus were used, representative of existing theories of comet nuclei. Values of dielectric constant assigned to these models are based on mixing laws for a porous mixture of ice and meteoritic dust, employing laboratory measured values of relative permittivity for mainly chondritic meteorites. Our results confirm that structural differences such as layers or inclusions are discernable from transmitted and reflected radar signals at 90 MHz, the central frequency of the CONSERT instrument. Such simulations help to constrain the ambiguities that might exist in future radar data associated with the nature of the comet nuclei, whether conglomerate or layered in nature.
Ulasitai: A new iron meteorite likely paired with Armanty (IIIE)
Authors: XU Lin , MIAO Bingkui , LIN Yangting , OUYANG Ziyuan
Published: January 2010

Abstract— The Ulasitai iron was recently found about 130 km southeast to the find site of the Armanty (Xinjiang, IIIE) meteorite. It is a coarse octahedrite with a kamacite bandwidth of 1.2 ± 0.2 (0.9–1.8) mm. Plessite is abundant, as is taenite, kamacite, cohenite, and schreibersite with various microstructures. Schreibersite is Ni‐rich (30.5–55.5 wt%) in plessite or coexisting with troilite and daubreelite, in comparison with the coarse laths (20.6–21.2 wt%) between the Widmanstätten pattern plates. The correlation between the center Ni content and the half bandwidth of taenite suggest a cooling rate of ˜20 °C/Myr based on simulations. The petrography and mineral chemistry of Ulasitai are similar to Armanty.

The bulk samples of Ulasitai were measured, together with Armanty, Nandan (IIICD), and Mundrabilla (IIICD), by inductively coupled plasma atomic emission spectrometry (ICP‐AES) and mass spectrometry (ICP‐MS). The results agree with literature data of the same meteorites, and our analyses of four samples of Armanty (L1, L12, L16, L17) confirm a homogeneous composition (Wasson et al. 1988). The bulk composition of Ulasitai is identical to that of Armanty, both plotting within the IIIE field. We classify Ulasitai as a new IIIE iron and suggest that it pairs with Armanty.
Noble gas content and isotope abundances in phases of the Saint‐Aubin (UNGR) iron meteorite
Authors: NISHIMURA Chikako , MATSUDA Jun‐ichi , KURAT Gero
Published: January 2010

Abstract— We analyzed the noble gas isotopes in the Fe‐Ni metal and inclusions of the Saint‐Aubin iron meteorite, utilizing the stepwise heating technique to separate the various components of noble gases.

The light noble gases in all samples are mostly cosmogenic, with some admixture from the terrestrial atmosphere. Total abundances of noble gases in metal are one of the lowest found so far in iron meteorites and the 4He/21Ne ratio is as high as 503, suggesting that the Saint‐Aubin iron meteorite was derived from a very large meteoroid in space. The exposure ages obtained from cosmogenic 3He were 9–16 Ma.

Saint‐Aubin is very peculiar because it contains very large chromite crystals, which—like the metal—contain only cosmogenic and atmospheric noble gases. The noble gases in all the samples do not reveal any primordial components. The only exception is the 1000 °C fraction of schreibersite which contained about 5% of the Xe‐HL component. The Xe‐Q and the El Taco Xe components were not found and only the Xe‐HL is present in this fraction. Some presolar diamond, the only carrier for the HL component known today, must have been available during growth of the schreibersite. However, it is also possible that this excess is due to the addition of cosmogenic and fission components. In this case, all the primordial components are masked (or lost) by the later events such as cosmic‐ray irradiation, heating, and radioactive decay.
Ca,Al‐rich inclusions in Rumuruti (R) chondrites
Authors: ROUT Surya Snata , BISCHOFF Addi
Published: January 2010

Abstract— Rumuruti chondrites (R chondrites) constitute a well‐characterized chondrite group different from carbonaceous, ordinary, and enstatite chondrites. Many of these meteorites are breccias containing primitive type 3 fragments as well as fragments of higher petrologic type. Ca,Al‐rich inclusions (CAIs) occur within all lithologies. Here, we present the results of our search for and analysis of Al‐rich objects in Rumuruti chondrites.

We studied 20 R chondrites and found 126 Ca,Al‐rich objects (101 CAIs, 19 Al‐rich chondrules, and 6 spinel‐rich fragments). Based on mineralogical characterization and analysis by SEM and electron microprobe, the inclusions can be grouped into six different types: (1) simple concentric spinel‐rich inclusions (42), (2) fassaite‐rich spherules, (3) complex spinel‐rich CAIs (53), (4) complex diopside‐rich inclusions, (5) Al‐rich chondrules, and (6) Al‐rich (spinel‐rich) fragments. The simple concentric and complex spinel‐rich CAIs have abundant spinel and, based on the presence or absence of different major phases (fassaite, hibonite, Na,Al‐(Cl)‐rich alteration products), can be subdivided into several subgroups.

Although there are some similarities between CAIs from R chondrites and inclusions from other chondrite groups with respect to their mineral assemblages, abundance, and size, the overall assemblage of CAIs is distinct to the R‐chondrite group. Some Ca,Al‐rich inclusions appear to be primitive (e.g., low FeO‐contents in spinel, low abundances of Na,Al‐(Cl)‐rich alteration products; abundant perovskite), whereas others were highly altered by nebular and/or parent body processes (e.g., high concentrations of FeO and ZnO in spinel, ilmenite instead of perovskite, abundant Na,Al‐(Cl)‐rich alteration products). There is complete absence of grossite and melilite, which are common in CAIs from most other groups. CAIs from equilibrated R‐chondrite lithologies have abundant secondary Ab‐rich plagioclase (oligoclase) and differ from those in unequilibrated type 3 lithologies which have nepheline and sodalite instead.
Polycyclic aromatic hydrocarbons and amino acids in meteorites and ice samples from LaPaz Icefield, Antarctica
Authors: BOTTA Oliver , MARTINS Zita , EMMENEGGER Christian , DWORKIN Jason P. , GLAVIN Daniel P. , HARVEY Ralph P. , ZENOBI Renato , BADA Jeffrey L. , EHRENFREUND Pascale
Published: January 2010

Abstract— –We have analyzed ice samples and meteorites from the LaPaz region of Antarctica to investigate the composition of polycyclic aromatic hydrocarbons (PAHs) and amino acids with the goal to understand whether or not there is a compositional relationship between the two reservoirs. Four LL5 ordinary chondrites (OCs) and one CK carbonaceous chondrite were collected as part of the 2003/2004 ANSMET season. Ice samples collected from directly underneath the meteorites were extracted. In addition, exhaust particles from the snowmobiles used during the expedition were collected to investigate possible contributions from this source. The meteorite samples, the particulate matter and solid‐state extracts of the ice samples and the exhaust filters were subjected to two‐step laser mass spectrometry (L2MS) to investigate the PAH composition. For amino acids analysis, the meteorites were extracted with water and acid hydrolyzed, and the extracts were analyzed with offline OPA/NAC derivatization combined with liquid chromatography with UV fluorescence detection and time of flight mass spectrometry (LC‐FD/ToF‐MS). PAHs in the particulate matter of the ice were found to be qualitatively similar to the meteorite samples, indicating that micron‐sized grains of the meteorite may be embedded in the ice samples. The concentration levels of dissolved PAHs in all the ice samples were found to be below the detection limit of the L2MS. The PAH composition of the snowmobile exhaust is significantly different to the one in particulate matter, making it an unlikely source of contamination for Antarctic meteorites. The amino acids glycine, β‐alanine and γ‐amino‐n‐butyric acid that were detected at concentrations of 3 to 19 parts per billion (ppb) are probably indigenous to the Antarctic meteorites. Some of the LaPaz ice samples were also found to contain amino acids at concentration levels of 1 to 33 parts per trillion (ppt), in particular α‐aminoisobutyric acid (AIB), an abundant non‐protein amino acid of extraterrestrial origin found in some carbonaceous chondrites. We hypothesize that this amino acid could have been extracted from Antarctic micrometeorites and the particulate matter of the meteorites during the concentration procedure of the ice samples.
The lunar‐wide effects of basin ejecta distribution on the early megaregolith
Authors: PETRO Noah E. , PIETERS Carlé M.
Published: January 2010

Abstract— The lunar surface is marked by at least 43 large and ancient impact basins, each of which ejected a large amount of material that modified the areas surrounding each basin. We present an analysis of the effects of basin formation on the entire lunar surface using a previously defined basin ejecta model. Our modeling includes several simplifying assumptions in order to quantify two aspects of basin formation across the entire lunar surface: 1) the cumulative amount of material distributed across the surface, and 2) the depth to which that basin material created a well‐mixed megaregolith. We find that the asymmetric distribution of large basins across the Moon creates a considerable nearside‐farside dichotomy in both the cumulative amount of basin ejecta and the depth of the megaregolith. Basins significantly modified a large portion of the nearside while the farside experienced relatively small degrees of basin modification following the formation of the large South Pole‐Aitken basin. The regions of the Moon with differing degrees of modification by basins correspond to regions thought to contain geochemical signatures remnant of early lunar crustal processes, indicating that the degree of basin modification of the surface directly influenced the distribution of the geochemical terranes observed today. Additionally, the modification of the lunar surface by basins suggests that the provenance of lunar highland samples currently in research collections is not representative of the entire lunar crust. Identifying locations on the lunar surface with unique modification histories will aid in selecting locations for future sample collection.
Two distinct assemblages of high‐pressure liquidus phases in shock veins of the Sixiangkou meteorite
Authors: CHEN Ming , XIE Xiande
Published: January 2010

Abstract— Shock‐produced complex veins, including earlier and later veins, are identified in the Sixiangkou L6 chondrite. The early vein is intersected by the late vein and consists of coarse‐grained aggregates of ringwoodite, majorite, and lingunite, and fragments of olivine, pyroxene, plagioclase, metal, and troilite, as well as a fine‐grained matrix of garnet, ringwoodite, metal, and troilite. The late vein mainly consists of a fine‐grained matrix of garnet, magnesiowüstite, metal, and troilite, as well as a small amount of coarse‐grained aggregates. The amount of fine‐grained matrix suggests that the late vein was nearly completely melted, whereas the early vein underwent partial melting. Both fine‐grained assemblages of garnet plus ringwoodite in the early vein and garnet plus magnesiowüstite in the late vein are liquidus phases crystallized from shock‐induced melt. Based on our understanding of the liquidus assemblages, the late vein experienced a higher pressure and temperature than the early vein.
Petrology of Martian meteorite Northwest Africa 998
Authors: TREIMAN Allan H. , IRVING Anthony J.
Published: January 2010

Abstract— Nakhlite Northwest Africa (NWA) 998 is an augite‐rich cumulate igneous rock with mineral compositions and oxygen isotopic composition consistent with an origin on Mars. This 456‐gram, partially fusion‐crusted meteorite consists of (by volume) ∼75% augite (core composition Wo39En39Fs22), ∼9% olivine (Fo35), ∼7% plagioclase (Ab61An35) as anhedra among augite and olivine, ∼3.5% low‐calcium pyroxenes (pigeonite and orthopyroxene) replacing or forming overgrowths on olivine and augite, ∼1% titanomagnetite, and other phases including potassium feldspar, apatite, pyrrhotite, chalcopyrite, ilmenite, and fine‐grained mesostasis material. Minor secondary alteration materials include “iddingsite” associated with olivine (probably Martian), calcite crack fillings, and iron oxide/hydroxide staining (both probably terrestrial). Shock effects are limited to minor cataclasis and twinning in augite. In comparison to other nakhlites, NWA 998 contains more low‐calcium pyroxenes and its plagioclase crystals are blockier. The large size of the intercumulus feldspars and the chemical homogeneity of the olivine imply relatively slow cooling and chemical equilibration in the late‐ and post‐igneous history of this specimen, and mineral thermometers give subsolidus temperatures near 730 °C. Oxidation state was near that of the QFM buffer, from about QFM‐2 in earliest crystallization to near QFM in late crystallization, and to about QFM + 1.5 in some magmatic inclusions. The replacement or overgrowth of olivine by pigeonite and orthopyroxene (with or without titanomagnetite), and the marginal replacement of augite by pigeonite, are interpreted to result from late‐stage reactions with residual melts (consistent with experimental phase equilibrium relationships). Apatite is concentrated in planar zones separating apatite‐free domains, which suggests that residual magma (rich in P and REE) was concentrated in planar (fracture?) zones and possibly migrated through them. Loss of late magma through these zones is consistent with the low bulk REE content of NWA 998 compared with the calculated REE content of its parent magma.
Observations and interpretations at Vredefort, Sudbury, and Chicxulub: Towards an empirical model of terrestrial impact basin formation
Authors: GRIEVE Richard A. F. , REIMOLD W. Uwe , MORGAN Joanna , RILLER Ulrich , PILKINGTON Mark
Published: January 2010

Abstract— The structural, topographic and other characteristics of the Vredefort, Sudbury, and Chicxulub impact structures are described. Assuming that the structures originally had the same morphology, the observations/interpretations for each structure are compared and extended to the other structures. This does not result in any major inconsistencies but requires that the observations be scaled spatially. In the case of Vredefort and Sudbury, this is accomplished by scaling the outer limit of particular shock metamorphic features. In the case of Chicxulub, scaling requires a reasoned assumption as to the formation mechanism of an interior peak ring. The observations/interpretations are then used to construct an integrated, empirical kinematic model for a terrestrial peak‐ring basin. The major attributes of the model include: a set of outward‐directed thrusts in the parautochthonous rocks of the outermost environs of the crater floor, some of which are pre‐existing structures that have been reactivated during transient cavity formation; inward‐directed motions along the same outermost structures and along a set of structures, at intermediate radial distances, during transient cavity collapse; structural uplift in the center followed by a final set of radially outward‐directed thrusts at the outer edges of the structural uplift, during uplift collapse. The rock displacements on the intermediate, inward and innermost, outward sets of structures are consistent with the assumption that a peak ring will result from the convergence of the collapse of the transient cavity rim area and the collapse of the structural uplift.
Testing an integrated chronology: I‐Xe analysis of enstatite meteorites and a eucrite
Authors: BUSFIELD A. , TURNER G. , GILMOUR J. D.
Published: January 2010

Abstract— We have determined initial 129I/127I ratios for mineral concentrates of four enstatite meteorites and a eucrite. In the case of the enstatite meteorites the inferred ages are associated with the pyroxene‐rich separates giving pyroxene closure ages relative to the Shallowater standard of Indarch (EH4, 0.04 ± 0.67 Ma), Khairpur (EL6, −4.22 ± 0.67 Ma), Khor Temiki (aubrite, −0.06 Ma), and Itqiy (enstatite achondrite, −2.6 ± 2.6 Ma), negative ages indicate closure after Shallowater. No separate from the cumulate eucrite Asuka (A−) 881394 yielded a consistent ratio, though excess 129Xe was observed in a feldspar separate, suggesting disturbance by thermal metamorphism within 25 Ma of closure in Shallowater.

Iodine‐129 ages are mapped to the absolute Pb‐Pb time scale using the calibration proposed by Gilmour et al. (2006) who place the closure age of Shallowater at 4563.3 ± 0.4 Ma. Comparison of the combined 129I‐Pb data with associated 53Mn ages, for objects that have been dated by both systems, indicates that all three chronometers evolved concordantly in the early solar system. The enstatite chondrites are offset from the linear array described by asteroid‐belt objects when 53Mn ages are plotted against combined 129I‐Pb data, supporting the suggestion that 53Mn was radially heterogeneous in the early solar system.
Scanning electron microscopical and cross sectional analysis of extraterrestrial carbonaceous nanoglobules
Authors: A. J. GARVIE Laurence , BAUMGARDNER Grant , BUSECK Peter R.
Published: January 2010

Abstract— Carbonaceous nanoglobules are ubiquitous in carbonaceous chondrite (CC) meteorites. The Tagish Lake (C2) meteorite is particularly intriguing in containing an abundance of nanoglobules, with a wider range of forms and sizes than encountered in other CC meteorites. Previous studies by transmission electron microscopy (TEM) have provided a wealth of information on chemistry and structure. In this study low voltage scanning electron microscopy (SEM) was used to characterize the globule forms and external structures. The internal structure of the globules was investigated after sectioning by focused ion beam (FIB) milling. The FIB‐SEM analysis shows that the globules range from solid to hollow. Some hollow globules show a central open core, with adjoining smaller cores. The FIB with an SEM is a valuable tool for the analysis of extraterrestrial materials, even of sub‐micron‐sized “soft” carbonaceous particles. The rapid site‐specific cross‐sectioning capabilities of the FIB allow the preservation of the internal morphology of the nanoglobules, with minimal damage or alteration of the unsectioned areas.
Rosetta target asteroid 2867 Steins: An unusual E‐type asteroid
Authors: WEISSMAN Paul R. , HICKS Michael D. , ABELL Paul A. , CHOI Young‐Jun , LOWRY Stephen C.
Published: January 2010

Abstract— ESA's Rosetta spacecraft will fly by main‐belt asteroid 2867 Steins on September 5, 2008. We obtained new visible wavelength spectra of 2867 Steins on December 19, 2006 (UT), using the Palomar 5 m telescope and the facility Double Spectrograph. Two sets of spectra, taken ∼3 h apart, one half of the rotation period for 2867 Steins, show it to be an E‐type asteroid. The asteroid displays a 0.50 μm feature that is considered diagnostic of the E(II) sub‐class, but is deeper than any previously observed E‐type. This feature is most likely due to the presence of oldhamite (CaS) on the asteroid's surface. Also, the observed Steins spectra are far redder than any other known E‐types. There is potential evidence for heterogeneity on hemispheric scales, one side of the asteroid appearing to be significantly redder than the other. No known recovered meteorite sample matches the unusual spectra of 2867 Steins, but the closest analog would be similar to an enstatite achondrite (aubrite).
Yellow impact glass from the K/T boundary at Beloc (Haiti): XANES determination of the Fe oxidation state and implications for formation conditions
Authors: GIULI Gabriele , EECKHOUT Sigrid Griet , KOEBERL Christian , PRATESI Giovanni , PARIS Eleonora
Published: January 2010

Abstract— We determined the iron oxidation state and coordination number in five samples of yellow impact glass from the Cretaceous‐Tertiary (K/T) boundary section at Beloc, Haiti, which formed as the result of impact melting during the Chicxulub impact event. The samples were analyzed by Fe K‐edge XANES spectroscopy and the results were compared with published data on eight black impact glasses and one high Si‐K impact spherule from the same impact layer. The pre‐edge peak of our high‐resolution XANES spectra displays evident variations indicative of significant changes in the Fe oxidation state, spanning a wide range from about 75 to 100 mole% Fe3+. Yellow K/T glasses have significantly higher Fe3+/(Fe2+ + Fe3+) ratios compared to black K/T impact glasses (from 20 to 75 mole% Fe3+) and high Si‐K glass (20 mole% Fe3+). In particular, all the pre‐edge peak data on these three types of impact glasses plot between two mixing lines joining a point calculated as the mean of a group of tektites studied so far (consisting of [4]Fe2+ and [5]Fe2+) to [4]Fe3+ and [5]Fe3+, respectively. Thus, the XANES spectra of the yellow K/T glasses can be interpreted as a mixture of [4]Fe2+, [5]Fe2+, [4]Fe3+, and [5]Fe3+.

Our observations can be explained by a very large range of oxygen fugacity conditions during melt formation. Furthermore, there is a clear positive relationship between the Fe3+/(Fe2+ + Fe3+) ratio and the Ca content of these glasses, suggesting that the Fe oxidation state was influenced by the relative contribution of Ca‐sulfate‐ and Ca‐carbonate‐bearing sedimentary rocks at the impact site.
Crystallization experiments on a Gusev Adirondack basalt composition
Authors: FILIBERTO J. , TREIMAN A. H. , LE L.
Published: January 2010

Abstract— Until recently, the SNC meteorites represented the only source of information about the chemistry and petrology of the Martian surface and mantle. The Mars Exploration Rovers have now analyzed rocks on the Martian surface, giving additional insight into the petrology and geochemistry of the planet. The Adirondack basalts, analyzed by the MER Spirit in Gusev crater, are olivine‐phyric basaltic rocks which have been suggested to represent liquids, and might therefore provide new insights into the chemistry of the Martian mantle. Experiments have been conducted on a synthetic Humphrey composition at upper mantle and crustal conditions to investigate whether this composition might represent a primary mantle‐derived melt. The Humphrey composition is multiply saturated at 12.5 kbar and 1375 °C with olivine and pigeonite; a primary anhydrous melt derived from a “chondritic” mantle would be expected to be saturated in orthopyroxene, not pigeonite. In addition, the olivine and pigeonite present at the multiple saturation are too ferroan to have been from a Martian mantle as is understood now. Therefore, it seems likely that the Humphrey composition does not represent a primary anhydrous melt from the Martian mantle, but was affected by mineral/melt fractionations at lower (crustal) pressures.
Bulk chemical composition of lherzolitic shergottite Grove Mountains 99027—Constraints on the mantle of Mars
Authors: LIN Yangting , QI Liang , WANG Guiqin , XU Lin
Published: January 2010

Abstract— We report the concentration of 50 elements, including rare earth elements (REEs) and platinum group elements (PGEs) in bulk samples of the Grove Mountains (GRV) 99027 lherzolitic shergottite. The abundances of REEs are distinctly lower than those of Allan Hills (ALH) A77005 and other lherzolitic shergottites, indicating that GRV 99027 is not paired with them. It may, nevertheless, sample the same igneous unit as the others (Lin et al. 2005b; Wang and Chen 2006). The CI‐normalized elemental pattern of GRV 99027 reveals low (0.004–0.008 × CI) and unfractionated PGEs (except for Pd of 0.018 × CI) without depletion of W. or Ga relative to lithophile element trends. Fractionation between siderophile and lithophile elements become less pronounced with increase of volatility, except for high abundances of Ni and Co. These characteristics are probably representative of the mantle of Mars, which is consistent with previous work that the Martian mantle formed in a deep magma ocean followed by a later accretion of chondritic materials.
New impact‐melt rock from the Roter Kamm impact structure, Namibia: Further constraints on impact age, melt rock chemistry, and projectile composition
Authors: HECHT Lutz , REIMOLD W. Uwe , SHERLOCK Sarah , TAGLE Roald , KOEBERL Christian , SCHMITT Ralf‐Thomas
Published: January 2010

Abstract— A new locality of in situ massive impact‐melt rock was discovered on the south‐southwestern rim of the Roter Kamm impact structure. While the sub‐samples from this new locality are relatively homogeneous at the hand specimen scale, and despite being from a nearby location, they do not have the same composition of the only previously analyzed impact‐melt rock sample from Roter Kamm. Both Roter Kamm impact‐melt rock samples analyzed to date, as well as several suevite samples, exhibit a granitic‐granodioritic precursor composition. Micro‐chemical analyses of glassy matrix and Al‐rich orthopyroxene microphenocrysts demonstrate rapid cooling and chemical disequilibrium at small scales. Platinum‐group element abundances and ratios indicate an ordinary chondritic composition for the Roter Kamm impactor. Laser argon dating of two sub‐samples did not reproduce the previously obtained age of 3.7 ± 0.3 (1s̀) for this impact event, based on 40Ar/39Ar dating of a single vesicular impact‐melt rock. Instead, we obtained ages between 3.9 and 6.3 Ma, with an inverse isochron age of 4.7 ± 0.3 Ma for one analyzed sub‐sample and 5.1 ± 0.4 Ma for the other. Clearly a post‐5 Ma impact at Roter Kamm remains indicated, but further analytical work is required to better constrain the currently best estimate of 4–5 Ma. Both impactor and age constraints are clearly obstructed by the inherent microscopic heterogeneity and disequilibrium melting and cooling processes demonstrated in the present study.
Aragonite in the Murray (CM2) carbonaceous chondrite: Implications for parent body compaction and aqueous alteration
Authors: LEE Martin R. , ELLEN Rachael
Published: January 2010

Abstract— The matrix of the CM2 carbonaceous chondrite Murray contains rare micrometer‐sized prismatic crystals of aragonite that formed during late‐stage parent body aqueous alteration. The aragonite was identified by X‐ray microanalysis coupled with electron backscatter diffraction (EBSD), TEM selected area electron diffraction and cathodoluminescence spectroscopy. The sixteen crystals found all occur within loose and elongate submillimeter‐sized clusters and one cluster is present in each of the two thin sections studied. Orientation determinations using EBSD show that the c axes of aragonite crystals within each cluster lie roughly in a plane, itself aligned approximately parallel to the long axis of the host cluster. Aragonite is inferred to have crystallized after calcite but before completion of static/impact‐related compaction. The clusters developed by growth of aragonite within films of aqueous fluids that had a relatively high Mg/Ca ratio. These fluids were focused within zones of high porosity and permeability along a weak compactional fabric in the matrix and this fabric is also likely to have influenced the orientations of aragonite crystals as they grew. These results suggest that aragonite probably occurs in most of those carbonaceous chondrites that have undergone moderate degrees of parent body aqueous alteration and may provide further insights into the evolution of pore fluid compositions and volumes and the chronology of asteroidal evolution.
Physical distribution trends in Darwin glass
Authors: HOWARD Kieren T.
Published: January 2010

Abstract— Darwin glass formed by impact melting, probably during excavation of the 1.2 km diameter Darwin crater, Tasmania, Australia. The glass was ejected up to 20 km from the source crater and forms a strewn field of >400 km2. There is at least 11,250 m3of glass in the strewn field and relative to the size of the crater this is the most abundant ejected impact glass on Earth. The glass population can be subdivided on the basis of shape (74% irregular, 20% ropy, 0.5% spheroid, 6% droplet, and 0.7% elongate) and color (53% dark green, 31% light green, 11% black, and 5% white). The white glasses contain up to 92 wt% SiO2 and are formed from melting of quartzite. Black glasses contain a minimum of 76 wt% SiO2 and formed from melting of shale. Systematic variations in the proportion of glasses falling into each of the color and shape classes relative to distance from the crater show: 1) a decrease in glass abundance away from the crater; 2) the largest fragments of glass are found closest to the crater; 3) small fragments (<2 g) dominate finds close to the crater; 4) the proportion of white glass is greatest closest to the crater; 5) the proportion of black glass increases with distance from the crater and 6) the proportion of splashform glasses increases with distance from the crater. These distribution trends can only be explained by the molten glass having been ballistically ejected from Darwin crater during impact and are related to 1) the depth of excavation from the target rock stratigraphy and/or 2) viscosity contrasts between the high and low SiO2 melt. The high abundance and wide distribution of ejected melt is attributed to a volatile charged target stratigraphy produced by surface swamps that are indicated by the paleoclimate record.
The Puerto Lápice eucrite
Authors: LLORCA Jordi , CASANOVA Ignasi , TRIGO‐RODRÍGUEZ Josep M. , MADIEDO José M. , ROSZJAR Julia , BISCHOFF Addi , OTT Ulrich , FRANCHI Ian A. , GREENWOOD Richard C. , LAUBENSTEIN Matthias
Published: January 2010

Abstract— Puerto Lápice is a new eucrite fall (Castilla‐La Mancha, Spain, 10 May 2007). In this paper, we report its detailed petrography, magnetic characterization, mineral and bulk chemistry, oxygen and noble gas isotope systematics, and radionuclide data. Study of four thin sections from two different specimens reveal that the meteorite is brecciated in nature, and it contains basaltic and granulitic clasts, as well as recrystallized impact melt and breccia fragments. Shock veins are ubiquitous and show evidence of at least three different shock events. Bulk chemical analyses suggest that Puerto Lápice belongs to the main group of basaltic eucrites, although it has a significantly higher Cr content. Oxygen isotopes also confirm that the meteorite is a normal member of the HED suite. Noble gas abundances show typical patterns, with dominant cosmogenic and radiogenic contributions, and indicate an average exposure age of 19 ± 2 Ma, and a Pu‐fission Xe age well within typical eucrite values. Cosmogenic radionuclides suggest a preatmospheric size of about 20–30 cm in diameter.
The Fountain Hills impact‐modified CB chondrite and thermal history of the CB asteroid
Authors: WEISBERG Michael K. , EBEL Denton S.
Published: January 2010

Abstract— Fountain Hills is a metal‐rich chondrite with mineral and whole chondrite oxygen isotope compositions that suggest it is a CB chondrite. However, its petrologic characteristics suggest that it has been modified by shock and recrystallization to a greater degree than other CB chondrites. It differs texturally from the CB chondrites in that its metal is interstitial to the silicate and does not occur as discrete clasts as in the other CB chondrites. Portions of Fountain Hills appear to be recrystallized and it contains large (mm‐size) olivine rimmed by pyroxene. A characteristic of the CB chondrites is the presence of small sulfide blebs in large metal clasts and anomalously heavy (15N‐enriched) nitrogen often associated with metal surrounding the sulfide blebs, but Fountain Hills lacks sulfide and its nitrogen is relatively light. The differences between Fountain Hills and the other CB chondrites can be attributed to a secondary process, most likely impact‐melting and recrystallization, that overprinted its primary features and it is inferred that Fountain Hills is an impact‐modified CB chondrite.
Shergottites Dhofar 019, SaU 005, Shergotty, and Zagami: 40Ar‐39Ar chronology and trapped Martian atmospheric and interior argon
Authors: KOROCHANTSEVA Ekaterina V. , TRIELOFF Mario , BUIKIN Alexei I. , HOPP Jens
Published: January 2010

Abstract— We report a high‐resolution 40Ar‐39Ar study of mineral separates and whole‐rock samples of olivine‐phyric (Dhofar 019, Sayh al Uhaymir [SaU] 005) and basaltic (Shergotty, Zagami) shergottites. Excess argon is present in all samples. The highest (40Ar/36Ar)trapped ratios are found for argon in pyroxene melt inclusions (˜1500), maskelynite (˜1200), impact glass (˜1800) of Shergotty and impact glass of SaU 005 (˜1200). A high (40Ar/36Ar)trapped component‐usually uniquely ascribed to Martian atmosphere‐can also originate from the Martian interior, indicating a heterogeneous Martian mantle composition. As additional explanation of variable high (40Ar/36Ar)trapped ratios in shocked shergottites, we suggest argon implantation from a “transient atmosphere” during impact induced degassing.

The best 40Ar‐39Ar age estimate for Dhofar 019 is 642 ± 72 Ma (maskelynite). SaU 005 samples are between 700–900 Ma old. Relatively high 40Ar‐39Ar ages of melt inclusions within Dhofar 019 (1086 ± 252 Ma) and SaU 005 olivine (885 ± 66 Ma) could date entrapment of a magmatic liquid during early olivine crystallization, or reflect unrecognized excess 40Ar components. The youngest 40Ar‐39Ar age of Shergotty separates (maskelynite) is ˜370 Ma, that of Zagami is ˜200 Ma.

The 40Ar‐39Ar chronology of Dhofar 019 and SaU 005 indicate >1 Ga ages. Apparent ages uncorrected for trapped (e.g., Martian atmosphere, mantle) argon components approach 4.5 Ga, but are not caused by inherited 40Ar, because excess 40Ar is supported by 36Artrapped. Young ages obtained by 40Ar‐39Ar and other chronometers argue for primary rather than secondary events. The cosmic ray exposure ages calculated from cosmogenic argon are 15.7 ± 0.7 Ma (Dhofar 019), 1.0–1.6 Ma (SaU 005), 2.1–2.5 Ma (Shergotty) and 2.2–3.0 Ma (Zagami).