bluuebunny/crossref_metadata_2025 huggingface dataset:
Caracterização da Escola Municipal Presidente Castelo Branco, Salvador-BA: subsídios para a educação ambiental na prática pedagógica do ensino fundamental
Authors: Conrado Dália , Silva Sueli
Published: August 2019

Buscou caracterizar a prática educativa da Escola Municipal Presidente Castelo Branco, visando contribuir para a inserção da dimensão socioambiental na prática pedagógica do ensino fundamental, de acordo com as necessidades e a realidade da instituição. Foram investigadas as concepções da comunidade escolar, a realidade do bairro e as perspectivas pedagógicas que influenciam a prática do professor, além de projetos e do plano de desenvolvimento da escola. A análise dos dados obtidos revelou a necessidade de realização de cursos de capacitação, oficinas e palestras envolvendo a comunidade da escola e do bairro para possibilitar a mobilização coletiva e a transformação da situação atual.

Palavras-chave: educação ambiental formal; ensino fundamental; abordagens pedagógicas; técnica de projetos.

Abstract

The present work has tried to characterize the educative practice of Presidente Castelo Branco Municipal School, in order to contribute to the insertion of the social and environmental dimension in pedagogical practice of basic education, according to the necessities and the reality of the institution. The conceptions concerning the school community, the district reality and the pedagogical perspectives, which influence the educator's practice, have been investigated; besides, we also studied the school's projects and development plan. The analysis of the obtained data revealed the necessity for organizing qualification courses, workshops and lectures, involving the school community and the neighborhood, in order to make the collective mobilization for transformation of the current situation possible.

Keywords: environmental education; basic education; pedagogical approach; projects' technique.
Dívida política, educação popular e republicanismo
Authors: Brayner Flávio Henrique
Published: August 2019

O artigo principia mostrando as vertentes românticas e racionalistas que confluiram para a chamada ‘educação popular’, onde duas noções distintas de “povo” disputavam um espaço ao mesmo tempo político e pedagógico. Defenderemos a idéia de que o projeto republicano, herdeiro da primeira vertente, é inacabado e, em seguida, procuramos desenvolver algumas noções de “competência” ligadas à Educação Popular, insistindo em seus aspectos argumentativos, propositivos, decisórios e auto-interrogativos. Conclui mostrando que a exclusão não é só a não participação nos benefícios de uma sociedade moderna, mas a impotência lingüística para pronunciar a sua própria exclusão.

Palavras-chave: Competência, Dívida Política, Educação Popular

Abstract

Political debt, popular education and republicanism
This article at first deals with the Romantic and the racionalist trends that converged into the field of popular education, where two distinct notions of people fought both for a political and pedagogical space. We argue here that the Republican project , heir of the first trend, is incomplete. Moreover, we try to develop some notions of ‘competence’ associated to popular education by emphasizing their argumentative, propositional, decisive and self critical aspects. We conclude by pointing out that educational exclusion means not only being deprived from the welfare allowed by modern society, but linguistic inability to utter one´s own exclusion.

Keywords: Competence, Political liability, Popular education.
Autobiography as a Quest for Identity
Authors: Subramony Dr R.
Published: August 2019

What is the difference between biography and autobiography?  The former is more revealing and hence is more in demand.  According to Graham Greens autobiography is only ‘a sort of life’. It is more selective.  He observed that ‘it begins later and ends prematurely. If one cannot close a book of memoirs on the death bed, any conclusion must be arbitrary’. The reader of an autobiography becomes an interested witness to the writer’s account of his life. He is a keen observer of an author’s obsession with his identity and the crises of his life.  The reader can find lessons for his own life from the author’s account. Necessarily, he is more an active participant of the creative process while reading an autobiography than while reading a novel. The reader is bound to find parallels between the experiences of the writer and his own. The history of autobiographical writing dates back to the ‘confessions’ of       St. Augustine written in the second half of the fourth century.  The difference between Christian idea of confession and autobiography as it developed in the eighteenth, nineteenth and our century must be noted.  Peter Abbes says that ‘confessions, in their traditional form, crave forgiveness, autobiography desires understanding. Confessions are devoted to salvation, autobiographies to individuation’. It is only with Rousseau that the form of memoirs took its present shape – ‘simply myself’. The importance of the individual reader was understood by autobiographers after Rousseau. Gibbon, Goethe, Ruskin, Wordsworth, John Stuart Mill, Newman, Darwin and a host of others gave the field of autobiography its pride of place.  In our century autobiography has been used as a means for relentless self-exploration and for organising our experience.
Los factores internos y externos en la política exterior mexicana (2012-2018): una evaluación general
Authors: Velázquez Flores Rafael , De Alba Ulloa Jessica L.
Published: August 2019

El objetivo de este artículo es evaluar la política exterior de México durante la administración de Enrique Peña Nieto (2012-2018). El argumento principal es que esta actividad estuvo profundamente condicionada por factores internos y externos en las diferentes etapas del sexenio. La primera parte plantea las metas de la administración peñista en materia de política exterior. La segunda divide el sexenio en cuatro etapas: de 2012 a 2014, cuando plantea las reformas estructurales que tuvieron repercusiones en la política exterior de México; de 2014 a 2016, cuando analiza los problemas internos; de 2016 a mitad de 2018, cuando apareció en la escena política Donald Trump, y de mediados de 2018 hasta el final de la administración. La última parte del texto evalúa el cumplimiento de los objetivos trazados al inicio de la administración.
La política de Enrique Peña Nieto hacia América del Norte: normalización e institucionalización
Authors: Santa Cruz Arturo
Published: August 2019

Este trabajo tiene como objetivo presentar una panorámica general de la política exterior del gobierno de Enrique Peña Nieto hacia América del Norte, de importancia central debido al proceso de normalización de la cooperación en materia de seguridad con Washington. Asimismo, la defensa de la relativamente reciente institucionalización de la relación económica con Estados Unidos y Canadá es también relevante. Para abordar estos temas, se revisan brevemente algunos conceptos analíticos que servirán para anclar la narrativa; en la segunda sección se examina la relación de México con Estados Unidos con foco en las dos áreas temáticas antes mencionadas. En la tercera sección se hace un breve repaso de la relación con Canadá; en la cuarta se trata sucintamente la política de México hacia América del Norte en su conjunto y, a manera de conclusión, se presenta un breve señalamiento sobre el futuro de la región.
China y México 2012-2018, entre el inicio idílico y la realidad
Authors: Cornejo Romer
Published: August 2019

Las relaciones de México con China en el sexenio 2012-2018 no tuvieron cambios importantes en comparación con los gobiernos anteriores. México mantuvocontinuó con la política de no considerar el peso de China en la comunidad internacional, ni las características de su sistema político ni sus proyectos económicos de gran potencia. Si bien las relaciones entre ambos países dieron inicio con la consigna de “relanzamiento”, se vieron lesionadas por los fracasos de los proyectos económicos chinos en México. Las relaciones diplomáticas siguieron su curso normal, con encuentros entre funcionarios de diversos niveles y firma de interesantes acuerdos de cooperación. Por su parte, China mantuvo una eficaz política cultural de creación de opinión pública favorable entre académicos, políticos y medios de comunicación
México y la cooperación internacional para el desarrollo, 2012-2018
Authors: Prado Lallande Juan Pablo
Published: August 2019

Al inicio de su mandato, el presidente Enrique Peña Nieto estableció que la política exterior se basaría en la cooperación internacional para el desarrollo (cid). El objetivo de este artículo es analizar las características de orden institucional y fácticas más definitorias de la cid ejercida durante esa administración, poniendo énfasis en el papel de la Amexcid como la instancia responsable de coordinar esta actividad. El artículo concluye que, en los respectivos contextos nacional e internacional –entendidos como factores estructurales de la cid– que oscilaron de lo favorable a lo convulso, la cid del sexenio 2012-2018 se caracterizó por alentadores avances, aunque también por una falta de solidez que dificultó que se constituyera en un activo de la política exterior, conforme a las expectativas despertadas.
La participación de México en la Convención Marco de las Naciones Unidas sobre el Cambio Climático
Authors: Torres Ramírez Blanca
Published: August 2019

El presente artículo examina la participación del gobierno de México en el sexenio 2012-2018 en las negociaciones sobre cooperación y coordinación internacional para enfrentar el cambio climático dentro del ámbito de la Convención Marco de las Naciones Unidas para el Cambio Climático (CMNUCC). Se hace referencia también a la participación de actores subestatales y no estatales, como empresas y organizaciones no gubernamentales en ese ámbito. A la par que se refiere las posturas y coaliciones que se dan en distintos temas entre países de distintas regiones, acordes con sus niveles de desarrollo e intereses y capacidades, se destaca el papel activo de la cancillería en contextos de negociación de temas complejos, así como de situaciones desafiantes, tales como la llegada de Donald Trump a la presidencia de Estados Unidos y su decisión de retirar a su país del Acuerdo de París.  Esta participación activa en las negociaciones internacionales permitió darle importancia a un tema que no se consideraba prioritario en la agenda de desarrollo del sexenio.
Metabolic Syndrome and Myocardial Involvement in HIV-Infected Patients
Authors: Bajdechi Mircea , Micu Cristina-Elena , Rugină Sorin , Stoian Georgiana-Elena , Gurghean Adriana
Published: August 2019

The current HAART has modified natural history of HIV infection and it has practically turned the disease into a manageable chronic condition. Even though the benefits of HAART use are overwhelmingly greater than possible metabolic syndrome and cardiovascular disease risks, close management of those patients is called for, especially due to the fact that general population risk factors now overlap with specific ones in this population.

Cardiovascular screening for HIV-infected patients who are receiving HAART must be done constantly with a collaboration between the infectious disease specialist and the internist.
SUNSCREEN LOTION OF MIANA LEAVES (COLEUS ATROPURPUREUS BENTH)
Authors: Rusli Rolan , Rosniah Rosniah , Fridayanti Aditya
Published: August 2019

Sunscreen can protect the skin from the UV radiation. One of the plants that have the potential to be utilized as active ingredients of sunscreen lotion is miana leaves (Coleus atropurpureus Benth). Lotion made in 3 formulas F1, F2 and F3.  Lotion tested its stability with a freeze-thaw method, and evaluated organoleptic, homogeneity, pH, viscosity and scatterness and tested sunscreen activity of lotion preparation. The preparation shows good homogeneity, and has oleum rosae odor and a thick consistency with the lotion color is brown (F1), dark brown (F2) and slightly greenish brown (F3). Spreading, viscosity, and pH of the lotion meet the Indonesia Standart requirement. The lotion formula comes in the category of fast tanning (F2) and extra protection (F3) sunscreen.
GUILLAIN-BARRE SYNDROME: A CASE REPORT
Authors: Pati Nikunja Basini , Begum Ruksana , Vani. P Salome Satya , R Soujanya
Published: August 2019

Guillain-Barre syndrome (GBS) is a complicated degenerative neurological disorder which can be acute or chronic in nature. It is an acquired condition which is characterized by progressive, symmetrical, proximal and distal tingling and weakness. Muscle stretch reflexes are decreased to absent and loss of sensation is common. Etiology remains unclear but pathophysiology includes demyelination of spinal nerve roots. Death is rare. Early diagnosis and prompt referral should occur in severe cases due to the incidence of potential ventilation   failure and cardiovascular instability in some patients. The case of a 26-year-old male presenting to a physician is described. The importance of a correct diagnosis by the physician and the subsequent management is reviewed.

Key words: Guillain-Barre syndrome, extremity weakness, peripheral nerves, trauma
Continuities and transformations of Argentina´s teacher education
Authors: Fischman Gustavo Enrique , Razquin Paula
Published: August 2019

Understanding the continuities and transformations in Teacher Education in Argentina during the period 1985-2015 requires to simultaneously recognize two longstanding key dynamics: First, the ideological, political and pedagogical debates about who could and should be a teacher and closely linked which institution should be in charge to educate/produce good teachers in Argentina. Second, teaching as any other occupation is tensioned by multiple labor conflicts with intersecting economic, political, cultural, and social dimensions. In this chapter, we will argue that, in broad terms, these two dynamics coalesce and crystalize around the definition of the professional status of teachers and consequently in the institutions designated to educate them, the Teacher Education Programs.
Estratégias de enfrentamento do racismo na escola
Authors: Carvalho Daniela Melo da Silva , França Dalila Xavier de
Published: August 2019

O objetivo deste artigo foi efetuar uma revisão integrativa de literatura sobre as estratégias de enfrentamento do racismo na escola. Foi realizada uma busca nas bases de dados SciELO (Scientific Electronic Library Online), PePSIC (Periódicos Acadêmicos em Psicologia) e Periódicos CAPES, utilizando os descritores “racismo”, “preconceito racial”, “escola”, “educação”, “combate” e “enfrentamento”. O banco final foi constituído por 20 documentos e os temas mais frequentes nos artigos foram: Lei 10.639/03 e formação docente. Foi constatada pouca produção acerca de temas relacionados a questões raciais e educação infantil. Com relação ao enfrentamento, a maioria dos artigos enfatizavam a importância da formação docente e a Lei 10.639/03 como estratégias para o combate do racismo na escola. Foi verificado que os estudos sobre essa temática precisam se expandir, pois as discussões são importantes para aprofundar o tema e o compartilhamento dos recursos utilizados podem contribuir para o enfrentamento do racismo na escola.
ОЧИЩЕННЯ ВОДИ ВІД ІОНІВ ВАЖКИХ МЕТАЛІВ ВІДСТОЮВАННЯМ, НАНОФІЛЬТРУВАННЯМ ТА ФЛОТАЦІЄЮ
Authors: Trus Inna , Gomelya Nikolai , Melnychenko Yevheniia , Mihranova Valeriia
Published: August 2019

Актуальність теми дослідження. Проблема погіршення екологічної ситуації стає все більш актуальною. Тому пріоритетним напрямком є розробка ефективних методів очищення води від йонів важких металів. Постановка проблеми. Нині наявні методи вилучення йонів важких металів із водних розчинів придатні переважно для очищення промислових стічних вод і мало ефективні для очищення природних вод, які містять у високих концентраціях йони кальцію і магнію, які суттєво знижують ємність іонітів по йонах важких металів. Аналіз останніх досліджень і публікацій. Були розглянуті останні публікації у відкритому доступі, включаючи літературу про основні методи очищення та доочищення води від йонів важких металів. Виділення недосліджених частин загальної проблеми. Інформація про ефективність очищення природних вод, які містять у високих концентраціях йони кальцію і магнію. Постановка завдання. Вивчення ефективності видалення йонів міді та свинцю із розведених водних розчинів при використанні фероціаніду калію та флокулянтів при відстоюванні, фільтруванні на фільтрі «синя стрічка», на нанофільтраційній мембрані ОПМН-П та методом флотації.
Виклад основного матеріалу. Досліджено процеси очищення води від важких металів при їх висадженні фероціанідом калію. Показано, що при очищенні води від йонів міді та свинцю шляхом комплексоутворення з ціанофератом калію при використанні нанофільтрування після відстоювання та механічного фільтрування ефективність вилучення йонів важких металів зростає. Вивчено ефективність зв’язування ціаноферату калію та йонів міді при взаємодії з полікатіонними флокулянтами.
Висновки відповідно до статті. Наведено результати досліджень з вилучення йонів важких металів (на прикладі міді та свинцю), отримані при переведенні важких металів у нерозчинний стан зв’язуванням у фероціанідні комплекси їх відстоюванням та доочищенням методами фільтрування та нанофільтрування. Показано, що застосування нанофільтрування дозволяє підвищити на 4–15 % ступінь очищення води від йонів міді та свинцю. Високу ефективність очищення води від важких металів забезпечив метод флотації.
Presentación del libro Terapias Ocupacionales desde el Sur
Authors: Recabarren Hernández Eladio
Published: August 2019

En primer lugar quisiera agradecer esta invitación a ser parte del lanzamiento de un libro que, al menos en Chile, marca un antes y un después en la forma en que comprendemos la Terapia Ocupacional en este país y en la región latino e iberoamericana, como adelantan los autores.
Precursores de la Terapia Ocupacional en Colombia: sujetos, instituciones, oficios
Authors: Duarte Cuervo Clara , Fernández Moreno Aleida , Cruz Perdomo Jaqueline , García Ruiz Solángel
Published: August 2019

La investigación historiográfica en Terapia Ocupacional es un campo propicio para proyectar estudios subalternos y decoloniales; este artículo hace una aproximación a la comprensión y el análisis en clave de historia social de la profesión en Colombia. Hablar del pasado en Terapia Ocupacional significa encontrar los sentidos de la ocupación a través de las prácticas, las instituciones y los sujetos. El artículo se organiza en tres apartados: uso de las ocupaciones en hospitales y otras instituciones durante la colonia en el Nuevo Reino de Granada; prácticas e instituciones hacia la consolidación de la República, y entrada al siglo XX: de la corrección a la terapia. Se identifican el trabajo y la instrucción en oficios como opción correctiva y de redención empleada en hospicios, asilos y otras instituciones desde el siglo XVII. Este recorrido sugiere una constante histórica: los oficios –la ocupación–, como práctica de las instituciones y bajo principios de caridad y beneficencia, han sido utilizados para formar, ocupar, corregir, normalizar y, en cualquier caso, hacer productivas a las personas socialmente marginadas.
Terapia Ocupacional y desplazamiento humano forzado Colombia, febrero de 2012
Authors: Caballero Adriana , Fernández Moreno Aleida , García Ruíz Solángel , Navas Aida , Moreno - Sosa Maribel
Published: August 2019

Este documento fue enviado a la WFOT y divulgado al interior del Colegio Colombiano de Terapia Ocupacional en el año 2012; para su publicación en este número como documento histórico, se introdujeron correcciones mínimas de estilo respecto a la versión original, los datos de identificación de las autoras corresponden al año 2012. La discusión y construcción alrededor de los conceptos y propuestas que en su momento se plantearon resulta pertinente, pues en la actualidad el desplazamiento forzado sigue siendo un problema de grandes dimensiones en Colombia. Los datos estadísticos de 2012 han sido superados de manera importante por causa del conflicto armado y de las condiciones que persisten en algunos territorios, no obstante el importante resultado para Colombia que se deriva de la firma del Acuerdo de Paz con las FARC y el proceso que actualmente adelanta el Gobierno Nacional con el ELN.
Participación y calidad de vida en familias de personas con discapacidad
Authors: Palma Arroyo Daniela Vanessa , Zapata López Jhoan Sebastián , Satizabal Reyes Melania , Roa Urrutia Pablo Esteban
Published: August 2019

El estudio de la calidad de vida en familias de personas con discapacidad ha cobrado importancia desde un enfoque de capacidades. En esta categoría influye la comprensión de factores contextuales y de cómo estos facilitan la participación de las personas en su vida cotidiana. La investigación tuvo como objetivo caracterizar seis familias de personas con discapacidad de las zonas rural y urbana de Cali, en términos de calidad de vida familiar y participación. Se realizó un estudio cualitativo y se aplicaron la Escala de calidad de vida familiar para familias de personas con discapacidad, el cuestionario WHODAS 2.0 y una entrevista semiestructurada. Se concluye que la calidad de vida familiar en personas con discapacidad es subjetiva y multidimensional, y está mediada por las relaciones intrafamiliares y la decisión de lo que es importante o no para su satisfacción. La participación de las personas con discapacidad en sus familias depende de la relación entre las funciones corporales y su capacidad de aporte, acorde con las demandas de la actividad y el contexto. La multidimensionalidad de la calidad de vida condiciona su abordaje a factores objetivos y subjetivos de cada familia, y es influenciada por los contextos físico, cultural, social y político.
Perbandingan Kemampuan Pemecahan Masalah Matematis Siswa antara Problem Centered Learning dan Problem Based Learning
Authors: Rinaldi Erik , Afriansyah Ekasatya Aldila
Published: August 2019

This article is based on the fact that problem-solving is a basic skill that every student should possess. To improve the student`s mindset through the effort to find problem-solving independently, so the learning activities should be centered on the students. The purpose of this study is to determine the comparison and improvement of students mathematical problem-solving abilities, as well as student attitudes toward the learning model problem-centered learning and problem-based learning. The research method used was a quasi-experiment with purposive sampling. The first experimental class that was class VIII I that got problem-centered learning model as much as 31 students, and the second experimental class that was class VIII H who got the problem-based learning model as many as 31 students. From the research and statistical calculations result, obtained the conclusion that the mathematical problem-solving ability students who got the model centered learning problem was better than students who got the model of learning problem-based learning. Meanwhile, for improvement of problem-solving abilities of mathematical students who got the learning model problem-centered learning and problem based learning each intermediate interpretation. And generally, the students’ attitude to the learning of mathematics by using the learning model problem-centered learning and problem-based learning are well interpreted.
Derivation of Rapamycin: Adventures in Natural Product Chemistry
Authors: Cottens Sylvain , Kallen Jörg , Schuler Walter , Sedrani Richard
Published: August 2019

The macrolide rapamycin ( 1 ) was first described as an antifungal agent in 1975. Even though its biological target and the molecular details were yet to be discovered, rapamycin attracted our interest in the early 90s based on its reported immunosuppressive activity in transplantation
models and based on findings that its mechanism of action was different from those of the known immunosuppressive agents ciclosporin and FK506. In this review we describe our efforts to chemically modify this complex and chemically very sensitive natural product. Despite the limitations regarding
the reaction conditions compatible with rapamycin we discovered ways of selectively modifying specific functional groups. This allowed us, among others, to improve the stability of the parent molecule towards ring-opening. Our efforts culminated in the discovery and development of the 40-O-alkylated
derivative everolimus 2 which became a useful drug in solid organ transplantation, in various cancer indications and as the active principle of the market leading drug-eluting stent.
Perfil epidemiológico da sífilis gestacional e congênita no Brasil – período de 2007 a 2016 / Epidemiological profile of gestational and congenital syphilis in Brazil – from 2007 to 2016
Authors: Bottura Beatriz Raia , Matuda Laís , Rodrigues Priscila Simão Serrano , Amaral Cássia Maria Carvalho Abrantes do , Barbosa Lene Garcia
Published: August 2019

Objetivo: Descrever a ocorrência dos casos notificados de sífilis congênita e materna nas regiões do Brasil, considerando o perfil epidemiológico das mães. Métodos: Estudo transversal constituído pelos casos notificados de sífilis gestacional e congênita no Brasil, no período de 2007 a 2016. Os dados foram coletados no SINAN (Sistema de Informação de Agravos de Notificação). Resultados: Houve um aumento dos casos de sífilis gestacional e congênita, no período analisado. O perfil das gestantes com sífilis foi semelhante em todas as regiões do país, com idade 20 a 29 anos e ensino fundamental incompleto. O diagnóstico de sífilis gestacional foi predominantemente realizado durante o pré-natal e o de sífilis congênita no período neonatal. O pré-natal foi realizado em 80% dos casos. O tratamento inadequado da sífilis materna obteve valores extremamente baixos, devido ao não tratamento dos parceiros. Conclusão: Ao longo dos anos houve aumento do número de casos de sífilis gestacional e congênita evidenciando a necessidade de ações efetivas para tratamento correto e prevenção.Descritores: Sífilis congênita, Sífilis, Perfil de saúde, Prevalência, Doenças sexualmente transmissíveis, Estudos epidemiológicosABSTRACTObjective: To describe the occurrence of reported cases of congenital and maternal syphilis in Brazilian regions, considering the epidemiological profile of the mothers. Methods: A cross-sectional study of reported cases of gestational and congenital syphilis in Brazil, from 2007 to 2016. Data were collected at SINAN (Notification of Injury Information System). Results: There was an increase in gestational and congenital syphilis in the analyzed period. The profile of pregnant women with syphilis was similar in all regions of the country, aged 20 to 29 years and incomplete elementary school. The diagnosis of gestational syphilis was predominantly performed during prenatal and congenital syphilis in the neonatal period. Prenatal care was performed in 80% of the cases. The inadequate treatment of maternal syphilis obtained extremely low values due to the non-treatment of the partners. Conclusion: Over the years there was an increase in the number of cases of congenital and gestational syphilis evidencing the need for effective actions for correct treatment and prevention. Keywords: Syphilis, congenital; Syphilis, Health profile, Prevalence, Sexually transmitted diseases, Epidemiological studies
Direct Ortho-Metallation of Aryl Substituted Heteroaromatic Ligands with TiCl 4 and ZrCl 4 - An Experimental and DFT Study with 2-Phenyl Indole as the Ligand.
Authors: Arzoumanidis Gregory , Chamot Ernest
Published: August 2019

TiCl 4 and ZrCl 4 each react with aryl substituted heteroaromatic ligands such as 2-Phenyl-1H-indole, to thermally undergo one-pot direct orthometallations, and yield new types of cyclometallated complexes. TiCl 4 coordinates at ambient temperature to form the indole complex ( 1 ), which undergoes isomerization to the indolenine ( 2 ). DFT calculations indicate that complex ( 2 ) is more stable than ( 1 ) by 6.4 kcal/mol. Upon warming to about 105°C, extrusion of HCl takes place with simultaneous orthometallation ( 3 ), yielding a metallacyclic complex ( 4 ). The mechanism of the orthometallation has been investigated by DFT, and the transition state c onfir med by IRC. At the elevated temperature the transition state ( 3 ) involves the synchronous transformation of four atoms, Ti, ortho C, H, and the apical Cl. The ortho C of the phenyl group acquires a partial positive charge through conjugation, forming a (C-H)δ + ...Clδ - interaction, with a simultaneous elongation and breaking of the Ti-Cl bond, resulting in the formation of a Ti-C bond. The latter bond is created at the same time a Ti-Cl bond is breaking, and an HCl is being formed, as illustrated in transition state ( 3 ). This HCl is retained in the crystal structure of the final product ( 4 ), by electrostatic interaction with one of the chloride ligands. The reaction sequence may be repeated with ZrCl 4 in place of TiCl 4 . Complex ( 4 ) has been isolated and characterized by solid state 13 C NMR CPMAS/DDMAS spectra, X-ray photoelectron spectroscopy (XPS), infrared and analytical data. The intermediate structures ( 1 through 4 ), as well as the sequence of ligand transformations to produce the ortho-metallated complex are supported by DFT calculations. The new cyclometallated complexes are thermally stable, unlike several other complexes featuring a Ti-C bond. They may have important applications, such as in α-olefin polymerization catalysis, and as building blocks in metalodrugs for cancer therapy.
Visualization of Very Large High-Dimensional Data Sets as Minimum Spanning Trees
Authors: Probst Daniel , Reymond Jean-Louis
Published: August 2019

Here, we introduce a new data visualization and exploration method, TMAP (tree-map), which exploits locality sensitive hashing, Kruskal’s minimum-spanning-tree algorithm, and a multilevel multipole-based graph layout algorithm to represent large and high dimensional data sets as a tree structure, which is readily understandable and explorable. Compared to other data visualization methods such as t-SNE or UMAP, TMAP increases the size of data sets that can be visualized due to its significantly lower memory requirements and running time and should find broad applicability in the age of big data. We exemplify TMAP in the area of cheminformatics with interactive maps for 1.16 million drug-like molecules from ChEMBL, 10.1 million small molecule fragments from FDB17, and 131 thousand 3D-structures of biomolecules from the PDB Databank, and to visualize data from literature (GUTENBERG data set), cancer biology (PANSCAN data set) and particle physics (MiniBooNE data set). TMAP is available as a Python package. Installation, usage instructions and application examples can be found at http://tmap.gdb.tools.
Integrated Project Delivery Implementation Challenges in the Construction Industry
Authors: Kahvandi Zahra , Saghatforoush Ehsan , ZareRavasan Ahad , Preece Christopher
Published: August 2019

Huge financial resources are spent in the construction industry all over the world, which are frequently wasted largely due to a lack of proper planning. In recent decades, in an attempt to overcome challenges, various contractual and administrative systems have been used by construction owners/clients. One such system has been Integrated Project Delivery (IPD). Its implementation has, however, experienced drawbacks. Identifying such drawbacks is an initial step in attempting to resolve them, and this paper aims to identify and prioritize the IPD implementation drawbacks in the context of the Iranian construction industry. A comprehensive list of IPD implementation drawbacks is prepared using a questionnaire survey. An in-depth literature review of the IPD concept has been combined with a review of various case studies applying the IPD system. The results were analyzed using the Robust Exploratory Factor Analysis (EFA) method. 22 drawbacks in the Construction Industry were categorized under four themes; contractual, environmental, managerial, and technical. Results show that contractual drawbacks are the most significant. The implication of this research is that identifying and classifying IPD implementation drawbacks provides a useful reference to managers and owners of the construction industry, for identifying and codifying solutions to overcome them.
A exigência do ensino superior para ingresso na Polícia Militar do Paraná
Authors: Caetano Cristiano Israel
Published: August 2019

A pesquisa aponta as transformações legislativas em matéria de requisito de escolaridade para ingresso na Polícia Militar do Estado do Paraná, apresentando estatísticas da evolução educacional que a sociedade está alcançando, e consequentemente permeando a modelagem da Corporação, tendente a incluir a exigência do diploma de curso superior para ingresso nos quadros do Oficialato e das Praças da instituição, bem como para impulsionar o desenvolvimento interno nas carreiras. A investigação também registra os Estado Brasileiros que instituíram tal alteração para ingresso, diante da possível aprovação da Legislação Federal em relação a condição mínima a ser exigida dos candidatos à ingresso nas Polícia Militares Brasileiras.
As controvérsias legais quanto à revogação da majorante do crime de roubo com emprego de arma: a (in)constitucionalidade do art. 4º da lei 13.654/2018
Authors: Da Costa Mislene Lima , Valverde Marcos Cesar Silva , Santos Carolina Rosa , Cardoso Franciele Silva
Published: August 2019

O presente artigo objetiva analisar as controvérsias trazidas com o advento da lei 13.654/2018 no que concerne ao crime de roubo com emprego de arma. O art. 4º da referida lei revogou o inc. I, do § 2º, do art. 157 do Código Penal, que previa o aumento de pena de 1/3 até a metade em caso de a violência ou ameaça perpetrada pelo agente ser exercida com o emprego de arma. Com essa modificação legal, essa modalidade de crime passou de roubo circunstanciado para roubo simples. A alteração legislativa promovida pelo art. 4º tem proporcionado intensos debates no meio jurídico e nas instâncias judiciais, sobretudo pelos questionamentos quanto à constitucionalidade do referido dispositivo que foi incluído pela coordenação de redação legislativa do Senado Federal, na fase final de revisão do texto legal.  A (in)constitucionalidade do art. 4º da lei 13.654/2018 não foi declarada pelos tribunais superiores, contudo, infere-se dos projetos de lei PLS n. 279/2018 do Senado Federal, e PLS n. 10541/2018 da Câmara dos Deputados, que a intenção dos legisladores é retornar o crime de roubo praticado com emprego de arma como um crime majorado.
Estudo das dissertações de mestrado profssional em segurança pública de universidades brasileiras
Authors: Tavares Andréia Guimarães , Da Costa Leon Denis , Vilarinho Tatiane Ferreira
Published: August 2019

Este artigo mapeou os Mestrados Profissionais em Segurança Pública realizados em programas de universidades brasileiras, examinando as áreas temáticas, os principais autores e as instituições de origem ou de atuação profissional. Realizou-se uma busca na plataforma Sucupira das dissertações de Mestrados Profissionais em Segurança Pública, fazendo uso da bibliometria. A pesquisa conseguiu identificar que os assuntos mais estudados no biênio 2016-2017 são atividade policial, delinquência juvenil e violência de gênero, mas sempre levando em consideração fatores locais. Os seus principais autores são discentes oriundos de órgãos que têm relação direta com a segurança pública, tais como as policias militares e polícias civis. Os estados que concentram esses cursos de strictu sensu são norte, nordeste e sudeste. Com isso, evidenciou que os assuntos mais investigados nesses programas de mestrados variam de acordo com as especificidades de cada região em que estão localizados. As regiões onde os cursos de mestrado e doutorado ainda não estão muito bem estabelecidos e reconhecidos são as que mais oferecem tal mestrado profissional.
Nas páginas da revista Campanha Nacional de Educação Rural/CNER: “professoras missioneiras”, entre a formação e a missão
Authors: Campos Nilce Vieira , Oliveira Cleicinéia Souza de
Published: August 2019

Um dos objetivos da Campanha Nacional de Educação Rural – CNER era capacitar e/ou formar professoras/professores para atuar nas zonas rurais com o intuito de melhoria da educação e das instalações escolares rurais com uma concepção explícita de "civilizar o homem do campo". Segundo aqueles que estavam à frente da CNER, docentes que atuavam no meio rural mostravam-se incapazes de prover uma "mudança de mentalidade" ou de promover educação de qualidade para os campesinos. Medidas como: missões rurais, difusão de outros modos de cultura, uso de recursos de ensino como o cinema, organização de centros regionais de formação e treinamento de docentes e técnicos que atendessem a uma pretensa educação de base, entre outros meios de aculturação das comunidades rurais foram utilizadas pela CNER para "educar" a população rural. A campanha desconsiderava assim, tanto se considerarmos a história da organização do ensino, do funcionamento das escolas, dos recursos destinados à instrução pública quanto à formação de docentes, o interesse dos rurícolas, bem como tudo o que se referia ao atendimento da educação rural. Nosso interesse pela temática decorre dessa contradição entre a importância desempenhada pela campanha empreendida pela CNER e a formação de professoras/professores para a atuação no Brasil rural dos anos de 1952 quando a CNER foi implantada a 1963 quando a campanha foi extinta.
Cotidiano e materialidade da escola primária oitocentista: ruídos entre público e privado
Authors: Barra Valdeniza Maria Lopes da
Published: August 2019

Eis aqui a reunião de um conjunto de fatos “miúdos” cujas marcas são pinçadas no curso do século XIX, com vistas a pensar a implementação da escola primária. Embora a ênfase seja sobre a escola de Goiás, de vez em quando, como forma de alicerçar o entendimento, chamar-se-á evidências da escola primária da de São Paulo ou outras pistas, de escala nacional, num movimento que, nos seus limites, cuida da relação entre singularidade e totalidade. Face a este conjunto, o esforço de identificar o que está nas ordens da repetição e do acontecimento. Este último, o acontecimento, segundo Braudel (1995) se acredita “único” e se associa à instantaneidade.  Enquanto certos atos ou fatos se repetem e, em acontecendo, tornam-se generalidade ou estrutura. Inscritos no “rés do chão”, na “zona opaca” - o cotidiano - a repetição de fatos miúdos guarda em si, a “força da inércia” e se revela na capacidade de invadir diferentes níveis da sociedade, portanto, uma “obreira da história” que não se pode menosprezar. Em síntese, é esta a senha de acesso ao movimento de instituição da especificidade do espaço físico da escola primária no curso do século XIX.
Manuais e livros didáticos: objetos e fontes para a História da Educação no mundo
Authors: Loureiro Marcus Wagner Antunes
Published: August 2019

Resenha do livro:MOREIRA, Kênia Hilda; DÍAZ, José María Hernández (Orgs.). História da Educação e Livros Didáticos. Campinas: Pontes Editores, 2017.
Urgensi Bimbingan Pra Nikah Terhadap Tingkat Pencerian
Authors: Ridho Muhammad
Published: August 2019

Penelitian ini bertujuan untuk mengetahui Urgensi  Bimbingan pra nikah  di KUA Kecamatan Muara Tabir. Untuk mengetahui faktor pendukung dan penghambat Bimbingan pra nikah terhadap tingkat perceraian di KUA Kecamatan Muara Tabir. Ingin mengetahiu upaya apa yang dilakukan KUA terhadap bimbingan pra nikah dalam mengurangi tingkat perceraian di Kecamatan Muara Tabir. Hasil penelitian ini menunjukkan Tingginya angka perceraian diantaranya disebabkan, banyak pasangan suami istri (Pasutri) yang tidak mengikuti bimbingan pra nikah. Faktor-faktornya adalah, Terjalinnya kerja sama dengan instansi-instansi yang terkait dengan baik, sehingga akan memperlancar dan membantu, adanya lembaga pendidikan nonformal, peran serta dari tokoh-tokoh agama, Akhirnya peneliti merekomendasikan kepada Ketua Kantor Urusan Agama Kecamatan Muara Tabir dan pasutri agar memperhatikan pasutri mengikuti bimbingan pra nikah selama 10 hari tersebut, para calon pengantin akan diberi materi menyangkut segala aspek kehidupan yang berkaitan tentang pernikahan. Disiplin dalam waktu mengikuti bimbingan.
PENINGKATAN KINERJA SUMBER DAYA MANUSIA MELALUI INISIATIF DAN ORIENTASI PEMBELAJARAN SERTA KEMAMPUAN PENYESUAIAN
Authors: Asih Wulan
Published: August 2019

The purpose of this study is to describe and analyze the influence of initiative, learningorientation, adaptability to HR performance. Data obtained from HR nurses in RSUD DR. R.Soedjati Soemodiardjo Purwodadi Grobogan using the questionnaires of 96 respondents. Thesampling technique non probability sampling method. Data analysis method used is multiplelinier regression. Results from this study showed that the variables of initiative and learningorientation has a significant effect on adaptability. Learning orientation and adaptability hasa significant effect on HR performance. While of initiative is not a significant effect on HRperformance. The results show that adaptability is not able to become an intervening variablebetween initiative influence on HR performance and adaptability is not able to become anintervening variable between learning orientation influence on HR performance.Keywords : Initiative, Learning Orientation, Adaptability, and HR performance.
KEPUTUSAN PEMBELIAN E-COMMERCE MELALUI KEMUDAHAN PENGGUNAAN, KUALITAS INFORMASI DAN KUALITAS INTERAKSI LAYANAN WEB
Authors: Romla Siti , Ratnawati Alifah
Published: August 2019

Purchasing decisions become an important thing in retaining customers. The purchase decisionis a customer’s response to a discrepancy between the level of prior importance and the actualperformance it perceives after use. As for the population is a student class of 2013. Samplestaken in the study obtained for 96.04 then rounded up to 100 people. Based on the abovecalculation results, the number of samples taken in this study is the student class of 2013as many as 100 respondents. Criteria of sampling as a resource is a social networking siteusers who have made purchases two (2) times through social networking sites. The result ofresearch indicate that Ease, Quality of information, Quality of interaction have positive andsignificant influence to trust, Ease, Quality of information, Quality of interaction have positiveand significant influence to purchasing decision, Trust influence positively and significantly topurchasing decision.Keywords : Ease, Quality of information, Quality of trust interaction, purchase decision
PROFITABILITAS TERHADAP RETURN SAHAM
Authors: Devy Happy Sista
Published: August 2019

The development of the capital market is currently followed by the development of the stock

market is increasingly in demand by investors as well, seen from data on Indonesia Stock

Exchange (IDX) which shows that the stocks included in the sharia has increased. An investor

will do the analysis to make an investment decision. The analysis is technical and fundamental.

One of the fundamental analysis is profitability ratio analysis issued by the company. Good

financial performance will be the information used as a positive signal by investors, because

companies that have good financial performance will provide more benefits for investors. The

purpose of this research is to examine and analyze profitability variables on stock returns in

Jakarta Islamic Index (JII) period 2012-2016. Population of this research is a company included

in the Jakarta Islamic Index (JII). This research using sample criteria, we obtained a sample of 21

companies included in the Jakarta Islamic Index (JII) for the period of 2012-2016 and published

annual financial report data on Indonesia Stock Exchange (IDX) required during the study. The

variables used in this research are earning per share (EPS), return on equity (ROE), return on

asset (ROA), return on sales (ROS), return on investment (ROI), size as control variable, and

stock return as the dependent variable. Result of this research show that investor on Jakarta

Islamic Index (JII) see simultaneously the profitability ratio as a signal for investment decision

making. Variable size can be used as control variable in that used in this research. Profitability

ratios that are taken by investors are return on assets (ROA), earnings per share (EPS), and

return on investment (ROI). So that should be a special attention for companies incorporated in

the Jakarta Islamic Index (JII) to increase investor interest to invest in the company.

Keywords : stock return, profitability ratio, size.
ANALISIS PERAN BELANJA MODAL DAN INVESTASI SWASTA TERHADAP PERTUMBUHAN EKONOMI SERTA DAMPAKNYA PADA KESEJAHTERAAN MASYARAKAT
Authors: Pambudy Akhlis Priya , Syairozi Muhamad Imam
Published: August 2019

The purpose of economic development is to improve public welfare. Many factors influenceeconomic growth, including sustainable development. This study is aimed to analyze the impactof capital expenditure and private investment on economic growth of the regency/municipalduring the period of 2010-2015 as well as the impact of economic growth on public welfareproxied by the human development index figures. Using WarpPLS, used purposive samplingmethode, testing is done for the 415 autonomous regional and 93 autonomous municipalsin Indonesia using time series data 2010-015. The results of this study shows that capitalexpenditure positively effect economic growth as well as private investment has positive effecton economic growth. Furthermore, the economic growth has been proven to improve publicwalfare.Keywords: capital expenditure, private investment, economic growth, public welfare
PERSPEKTIF SIKLUS HIDUP PERUSAHAAN DALAM HUBUNGAN ANTARA INVENTORI DAN KINERJA FINANSIAL
Authors: Setiawan Ferry , Nofrisel Nofrisel
Published: August 2019

Research regarding the relationship between inventory management and financial performanceis so far inconclusive: some found it to be positive, others found it to be negative. One ofthe many factors that influence the variance, the organizational life cycle, will be exploredin this research. Organizational life cycle might influence the relationship between inventorymanagement and financial perfomance due to the different strategies and designs pursuedby the organizations along each of their life cycle stages. This study use a sample set of 33manufacturing companies listed in BEI, with 7 years observation period. A regression analysisis performed with dummy variables of organizational life cycle, resulting from a cluster analysiswith k-mean method. Regression analysis and cluster analysis are all done with Stata. Theresult shows that the relationship between inventory and financial performance is positive inthe early growth stage of organization life cycle and turns to negative at late growth stage. Therelationship is inconclusive at the conception and stability stage of organizational life cycle.Therefore, we can conclude that in making decisions about inventory, firms should considerwhat stage of organizational life cycle they are currently in so that the decisions made canimpact the financial performance positively.Keywords: Organizational Life Cycle, Financial Performance, Inventory Management