bluuebunny/crossref_metadata_2025 huggingface dataset:
Sage, Rosemary, and Bay Laurel Hydrodistillation By-Products as a Source of Bioactive Compounds
Authors: Miljanović Anđela , Dent Maja , Grbin Dorotea , Pedisić Sandra , Zorić Zoran , Marijanović Zvonimir , Jerković Igor , Bielen Ana
Published: June 2023

Essential oils from Mediterranean wild plants are widely used, but the hydrodistillation residues produced in parallel with these essential oils are significantly understudied and underexploited. Since there are only fragmentary data in the literature, we have, for the first time, systematically analyzed the chemical composition of the by-products obtained after hydrodistillation of sage, bay laurel, and rosemary leaves, i.e., hydrolates, water residues, and solid residues. The chemical composition of the hydrolates changed compared to their respective essential oils towards the dominance of more hydrophilic, oxygenated compounds, such as camphor in sage, 1,8-cineole in bay laurel, and berbenone in rosemary. However, some compounds, mostly sesquiterpenes, which were present in considerable amounts in essential oils, were absent or only present in very small amounts in the hydrolates. Furthermore, both the water and the solid residues were rich in polyphenols, such as procyanidins in bay laurel and rosmarinic acid in rosemary and sage. In conclusion, we demonstrate the valuable chemical composition of sage, rosemary, and bay laurel hydrodistillation by-products and discuss a wide range of their possible applications.
Specialized Metabolites Accumulation Pattern in Buckwheat Is Strongly Influenced by Accession Choice and Co-Existing Weeds
Authors: Vieites-Álvarez Yedra , Otero Paz , López-González David , Prieto Miguel Angel , Simal-Gandara Jesus , Reigosa Manuel J. , Hussain M. Iftikhar , Sánchez-Moreiras Adela M.
Published: June 2023

Screening suitable allelopathic crops and crop genotypes that are competitive with weeds can be a sustainable weed control strategy to reduce the massive use of herbicides. In this study, three accessions of common buckwheat Fagopyrum esculentum Moench. (Gema, Kora, and Eva) and one of Tartary buckwheat Fagopyrum tataricum Gaertn. (PI481671) were screened against the germination and growth of the herbicide-resistant weeds Lolium rigidum Gaud. and Portulaca oleracea L. The chemical profile of the four buckwheat accessions was characterised in their shoots, roots, and root exudates in order to know more about their ability to sustainably manage weeds and the relation of this ability with the polyphenol accumulation and exudation from buckwheat plants. Our results show that different buckwheat genotypes may have different capacities to produce and exude several types of specialized metabolites, which lead to a wide range of allelopathic and defence functions in the agroecosystem to sustainably manage the growing weeds in their vicinity. The ability of the different buckwheat accessions to suppress weeds was accession-dependent without differences between species, as the common (Eva, Gema, and Kora) and Tartary (PI481671) accessions did not show any species-dependent pattern in their ability to control the germination and growth of the target weeds. Finally, Gema appeared to be the most promising accession to be evaluated in organic farming due to its capacity to sustainably control target weeds while stimulating the root growth of buckwheat plants.
Combined Transcriptome and Proteome Analysis Provides Insights into Petaloidy in Pomegranate
Authors: Huo Yan , Yang Han , Ding Wenjie , Huang Tao , Yuan Zhaohe , Zhu Zunling
Published: June 2023

Petaloidy leads to a plump floral pattern and increases the landscape value of ornamental pomegranates; however, research on the mechanism of petaloidy in ornamental pomegranates is limited. In this study, we aimed to screen candidate genes related to petaloidy. We performed transcriptomic and proteomic sequencing of the stamens and petals of single-petal and double-petal flowers of ornamental pomegranates. Briefly, 24,567 genes and 5865 proteins were identified, of which 5721 genes were quantified at both transcriptional and translational levels. In the petal and stamen comparison groups, the association between differentially abundant proteins (DAPs) and differentially expressed genes (DEGs) was higher than that between all genes and all proteins, indicating that petaloidy impacts the correlation between genes and proteins. The enrichment results of transcriptome, proteome, and correlation analyses showed that cell wall metabolism, jasmonic acid signal transduction, redox balance, and transmembrane transport affected petaloidy. Nine hormone-related DEGs/DAPs were selected, among which ARF, ILR1, LAX2, and JAR1 may promote petal doubling. Sixteen transcription factor DEGs/DAPs were selected, among which EREBP, LOB, MEF2, MYB, C3H, and trihelix may promote petal doubling. Our results provide transcriptomic and proteomic data on the formation mechanism of petaloidy and a theoretical basis for breeding new ornamental pomegranate varieties.
Genotyping of Jujube (Ziziphus spp.) Germplasm in New Mexico and Southwestern Texas
Authors: Sapkota Dikshya , Zhang Dapeng , Park Sunchung , Meinhardt Lyndel W. , Yao Shengrui
Published: June 2023

Since the early 19th century, a substantial amount of jujube (Ziziphus spp.) germplasm has been introduced from China and Europe into the United States. However, due to a lack of passport data, cultivar mislabeling is common and the genetic background of the introduced germplasm remains unknown. In the present study, a low-density SNP array was employed to genotype 204 jujube trees sampled from multiple locations in New Mexico, Texas, Missouri, and Kentucky. Multilocus matching of SNP profiles revealed a significant rate of genetic redundancy among these jujube samples. A total of 14 synonymous groups were detected, comprising 48 accessions. Bayesian clustering analysis and neighbor-joining tree partitioned the US jujube germplasm into two major clusters. The first cluster included cultivated genotypes (Ziziphus jujuba Mill.), whereas the other major cluster comprised the wild/sour jujube (Ziziphus spinosa Hu.). The results also revealed a unique jujube population at Fabens/Tornillo, Texas, and a semi-naturalized population at Tucumcari, NM. These findings will provide valuable guidance to jujube growers and researchers on the effective utilization of jujube germplasm in the horticultural industry.
Silicon in Plants: Alleviation of Metal(loid) Toxicity and Consequential Perspectives for Phytoremediation
Authors: Puppe Daniel , Kaczorek Danuta , Stein Mathias , Schaller Jörg
Published: June 2023

For the majority of higher plants, silicon (Si) is considered a beneficial element because of the various favorable effects of Si accumulation in plants that have been revealed, including the alleviation of metal(loid) toxicity. The accumulation of non-degradable metal(loid)s in the environment strongly increased in the last decades by intensified industrial and agricultural production with negative consequences for the environment and human health. Phytoremediation, i.e., the use of plants to extract and remove elemental pollutants from contaminated soils, has been commonly used for the restoration of metal(loid)-contaminated sites. In our viewpoint article, we briefly summarize the current knowledge of Si-mediated alleviation of metal(loid) toxicity in plants and the potential role of Si in the phytoremediation of soils contaminated with metal(loid)s. In this context, a special focus is on metal(loid) accumulation in (soil) phytoliths, i.e., relatively stable silica structures formed in plants. The accumulation of metal(loid)s in phytoliths might offer a promising pathway for the long-term sequestration of metal(loid)s in soils. As specific phytoliths might also represent an important carbon sink in soils, phytoliths might be a silver bullet in the mitigation of global change. Thus, the time is now to combine Si/phytolith and phytoremediation research. This will help us to merge the positive effects of Si accumulation in plants with the advantages of phytoremediation, which represents an economically feasible and environmentally friendly way to restore metal(loid)-contaminated sites.
Chitosan, Gelatin, and Collagen Hydrogels for Bone Regeneration
Authors: Guillén-Carvajal Karen , Valdez-Salas Benjamín , Beltrán-Partida Ernesto , Salomón-Carlos Jorge , Cheng Nelson
Published: June 2023

Hydrogels are versatile biomaterials characterized by three-dimensional, cross-linked, highly hydrated polymeric networks. These polymers exhibit a great variety of biochemical and biophysical properties, which allow for the diffusion of diverse molecules, such as drugs, active ingredients, growth factors, and nanoparticles. Meanwhile, these polymers can control chemical and molecular interactions at the cellular level. The polymeric network can be molded into different structures, imitating the structural characteristics of surrounding tissues and bone defects. Interestingly, the application of hydrogels in bone tissue engineering (BTE) has been gathering significant attention due to the beneficial bone improvement results that have been achieved. Moreover, essential clinical and osteoblastic fate-controlling advances have been achieved with the use of synthetic polymers in the production of hydrogels. However, current trends look towards fabricating hydrogels from biological precursors, such as biopolymers, due to the high biocompatibility, degradability, and mechanical control that can be regulated. Therefore, this review analyzes the concept of hydrogels and the characteristics of chitosan, collagen, and gelatin as excellent candidates for fabricating BTE scaffolds. The changes and opportunities brought on by these biopolymers in bone regeneration are discussed, considering the integration, synergy, and biocompatibility features.
Characterization of a New Silk Sericin-Based Hydrogel for Water Retention in Soil
Authors: Jaramillo-Quiceno Natalia , Álvarez-López Catalina , Hincapié-Llanos Gustavo Adolfo , Hincapié Carlos A. , Osorio Marisol
Published: June 2023

Hydrogel-type absorbent materials are currently a technological alternative for improving water retention in the soil and reducing nutrient loss by leaching and evaporation. This study aimed to evaluate the application of a new hydrogel based on silk sericin (SS) as a water retention material in soil. The morphology of the hydrogel was characterized using Scanning Electron Microscopy (SEM), and its impact on moisture retention in sandy loam soil (SLS) under different levels of matric pressure (MP) was evaluated. Additionally, water content data were collected over time for both SLS and SLS with hydrogel (SLS + H), and the data were used to fit predictive models. The results indicate that the hydrogel had a porous morphology that promoted water retention and soil release. Under a MP of 0.3 bar, the use of the hydrogel increased water retention by 44.70% with respect to that of SLS. The predictive models developed were adequately adjusted to the behavior of the moisture data over time and evidenced the incidence of the absorbent material on the dynamics of the moisture content in the soil. Therefore, these models could be useful for facilitating subsequent simulations or for designing automatic soil moisture control systems oriented to smart farming.
Influence of a Multiple Epoxy Chain Extender on the Rheological Behavior, Crystallization, and Mechanical Properties of Polyglycolic Acid
Authors: Gao Jianfeng , Wang Kai , Xu Nai , Li Luyao , Ma Zhao , Zhang Yipeng , Xiang Kun , Pang Sujuan , Pan Lisha , Li Tan
Published: June 2023

This study investigated the impact of a multiple epoxy chain extender (ADR) on the rheological behavior, crystallization, and mechanical properties of polyglycolic acid (PGA). Tests of the torque and melt mass flow rate and dynamic rheological analysis were conducted to study the rheological behavior of PGA modified with ADR. The rheological results of the modified PGA showed a significantly increased viscosity and storage modulus with an increase in the ADR amount, which could be attributed to the chain extension/branching reactions between PGA and ADR. It was proved that ADR could be used as an efficient chain extender for tailoring the rheological performance of PGA. The Han plot of the modified PGA showed a transition of viscous behavior to elastic behavior, while the ADR content was increased from 0 to 0.9 phr. The formation of long-chain branches (LCBs) was confirmed via the Cole–Cole plot and weighted relaxation spectrum, wherein the LCBs substantially changed the rheological behavior of the modified PGA. The vGP plots predicted a star-type topological structure for the LCBs. The results of non-isothermal crystallization kinetics suggested that the crystallization of the modified PGA was predominantly homogeneous nucleation and three-dimensional growth. The crystallinity decreased slightly with the increase in the ADR amount. Compared to neat PGA, the modified PGA samples exhibited better tensile and flexural performances.
The Modification Mechanism, Evaluation Method, and Construction Technology of Direct-to-Plant SBS Modifiers in Asphalt Mixture: A Review
Authors: Yan Xiang , Wu Di , Hu Kui , Zhang Wengang , Xing Jianbao , Cui Lilong , Shi Silin , Yang Jixu , Yang Chengxu
Published: June 2023

To further promote the development of research on direct-to-plant SBS-modified asphalt, this article analyzes the development of direct-to-plant SBS modifiers. Starting from the material composition and mechanism of action, common direct-to-plant SBS modifiers were analyzed and classified into four categories based on their mechanism of action, including the instant dissolution principle, intramolecular lubrication principle, non-granulation principle, and vulcanization principle. From the evaluation of the modification effect, the method of studying the performance of direct-to-plant SBS-modified asphalt is summarized, including fluorescence microscopy, AFM technology, and molecular dynamics simulation technology. From the perspective of practical application, the construction process of direct-to-plant SBS-modified asphalt was discussed, including the design stage, raw material preparation stage, mix design stage, and on-site construction stage. The results show that common direct-to-plant SBS modifiers are primarily SBS with a small particle size (less than 200 mesh) or specific model, supplemented by additives (EVA, naphthenic oil, sulfur, petroleum resin, etc.), which improve melting efficiency and lubricity or make it undergo vulcanization reaction, change the proportion of asphalt components, and improve stability. In the evaluation of the modification effect of direct-to-plant SBS-modified asphalt, the disparity of the direct-to-plant SBS modifier is determined by observing the particle residue after dry mixing. Macroscopic indexes of modified asphalt and modified asphalt mixture are used to determine the cross-linking effect of direct-to-plant SBS modifier and asphalt, and the modification mechanism and modification effect of wet SBS modifier are evaluated at the microscopic level. The development of direct-to-plant SBS-modified asphalt should combine the characteristics of direct-to-plant SBS modifiers and the attributes of field application, targeted research, and the development of high-performance direct-to-plant SBS modifiers and complete production technologies applicable to different regions, strengthen the improvement of modification effect evaluation, and form a complete theoretical system.
Bioinspired Tannic Acid-Modified Coffee Grounds as Sustainable Fillers: Effect on the Properties of Polybutylene Adipate Terephthalate Composites
Authors: Wang Jiaxin , Zhao Dong , Jiang Guodong , Wu Yong , Shen Yucai , Wang Tingwei
Published: June 2023

Preparing composites from gricultural waste with biodegradable polymers is one of the strategies used to ensure the long-term sustainability of such materials. However, due to the differences in their chemical properties, biomass fillers often exhibit poor interfacial adhesion with polymer matrices. Inspired by mussel foot silk, this work focused on the surface modification of coffee grounds (CGs) using a combination of tannic acid (TA) and alkali treatment. CGs were used as a biomass filler to prepare polybutylene adipate terephthalate (PBAT)/CG composites. The modification of CGs was demonstrated by Fourier transform infrared spectroscopy (FTIR), the water contact angle, and scanning electron microscopy (SEM). The effect of CGs on the rheological, tensile, and thermal properties of the PBAT/CG composites was investigated. The results showed that the addition of CGs increased the complex viscosity, and the surface modification enhanced the matrix–filler adhesion. Compared with unmodified CG composites, the tensile strength and the elongation at break of the composite with TA-modified alkali-treated CGs increased by 47.0% and 53.6%, respectively. Although the addition of CGs slightly decreased the thermal stability of PBAT composites, this did not affect the melting processing of PBAT, which often occurs under 200 °C. This approach could provide a novel method for effectively using biomass waste, such as coffee grounds, as fillers for the preparation of polymer composites.
Mechano Chemical Compatibilization of Polyethylene with Graphite by Means of a Suitable Ester
Authors: Russo Simona , Acocella Maria Rosaria , Mariconda Annaluisa , Volpe Valentina , Pantani Roberto , Longo Pasquale
Published: June 2023

An effective non-covalent compatibilization method for graphite and low-density polyethylene is reported. To obtain this result, pyren-1-yl-stearate (P1S) was synthesized, characterized and mixed with graphite to provide a better dispersion in polyethylene matrix. The P1S improves the dispersion of carbon filler in polyethylene through non-covalent compatibilization: the pyrenyl group gives π−π stacking interactions with graphite and the stearyl chain provides van der Waals interaction with the polymer chain (specifically London dispersion forces). In this study, different P1S/graphite fillers were prepared with a ratio by weight of 90/10 and 50/50, respectively, by using manual and ball-milling mixing. Their stability, interaction and morphology were evaluated through TGA, RX, and SEM. Thermogravimetric analyses showed that ball-milling mixing is more effective than manual mixing in promoting π−π stacking interactions of molecules such as P1S ester containing an alkyl chain and aromatic rings. The role of ball milling is confirmed by X-ray diffraction measurements since it was possible to observe both exfoliation and intercalation phenomena when this technique was used to mix the P1S ester with graphite. SEM analyses of polyethylene containing 1% of the carbon fillers again highlighted the importance of ball milling to promote the interaction of the ester with graphite and, simultaneously, the importance of the alkyl chain in order to achieve polyethylene-graphite compatibilization.
Incorporation of Fly Ash in Flame-Retardant Systems of Biopolyesters
Authors: Batistella Marcos , Roux Jean-Claude , Masarra Nour-Alhoda , le Saout Gwenn , Xenopoulos Constantinos , Lopez-Cuesta José-Marie
Published: June 2023

The incorporation of fly ash in polybutyl succinate (PBS) and polybutyl adipate terephtalate (PBAT) in the partial replacement of ammonium polyphosphate and/or melamine polyphosphate is evaluated in the present work. Furthermore, the influence of the surface modification of fly ash with two silanes and titanate coupling agents was also studied. Cone calorimeter experiments, pyrolysis combustion flow calorimeters (PCFCs), and UL94V tests were used to assess the fire performance of the composites. Scanning electronic microscopy, X-microanalysis, and X-ray diffractometry analysis were carried out on cone calorimeter residues in order to access the fire-retardant mode of action. The formation of new components due to the presence of fly ash was highlighted by X-ray diffractometry, indicating the synergistic effects between the flame-retardant system and fly ash. The X-microanalysis results showed that the main fraction of initial phosphorous is present in the cone calorimeter residue, indicating that the proposed system acts in a condensed phase.
A Comparative Study of Abnormal Heating Composite Insulators
Authors: Gao Song , Liu Yunpeng , Li Le
Published: June 2023

The abnormal heating of composite insulators on transmission lines frequently occurs, seriously threatening the power grid’s safe and stable operation. For different types of abnormal heating composite insulators, undifferentiated replacement wastes a lot of labor and material resources. This study explores the abnormal heating composite insulators under different environmental humidity and wind speed conditions. The heating and discharge of composite insulators are observed, and the heating range, heating shape, and temperature rise (ΔT) are analyzed. The abnormal heating of the sheath-aging composite insulator is related to the aging of the silicone rubber and the environmental humidity. The partial discharge caused by the core rod’s defect is the primary source of the temperature rise in the decay-like insulator. The heating range of the contaminated insulator is connected to the environmental humidity, and the ΔT increases with the salt density. The ΔT and heating range of the three types of abnormal heating increase with the ambient humidity. The heating phenomenon under low humidity is an important characteristic that distinguishes decay-like and contaminated insulators from sheath-aging insulators. Therefore, the on-site infrared inspection should be carried out in sunny and windless weather to prevent the impact of high humidity and wind speed on infrared temperature measurement.
Human Serum Albumin Nanoparticles: Synthesis, Optimization and Immobilization with Antituberculosis Drugs
Authors: Galiyeva Aldana , Daribay Arailym , Zhumagaliyeva Tolkyn , Zhaparova Lyazzat , Sadyrbekov Daniyar , Tazhbayev Yerkeblan
Published: June 2023

The aim of this study was to create nanoparticles of human serum albumin immobilized with anti-TB drugs (rifampicin, isoniazid) using the desolvation method. Central Composite Design (CCD) was applied to study the effect of albumin, urea, L-cysteine, rifampicin and isoniazid concentration on particle size, polydispersity and loading degree of the drugs. The optimized nanoparticles were spherical in shape with an average particle size of 216.7 ± 3.7 nm and polydispersity of 0.286 ± 4.9. The loading degree of rifampicin and isoniazid in the optimized nanoparticles were 44% and 27%, respectively. The obtained nanoparticles were examined by Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC); the results showed the absence of drug–polymer interactions. The drug release from the polymer matrix was studied using dialysis membranes.
Study on the Coalescence-Induced Jumping of Droplets with Different Radii on Superhydrophobic Surface
Authors: Liao Ming-Jun , Ren Xin-Quan , Liu Zi-Han , Hong Wen-Peng , Xie Fang-Fang
Published: June 2023

The phenomenon of droplet coalescence and jumping has received increasing attention due to its potential applications in the fields of condensation heat transfer and surface self-cleaning. Basic research on the process and mechanism of coalescence-induced droplet jumping has been carried out, and some universal laws have been established. However, it is found that the focus of these studies is based on two identical droplets, and the coalescence-induced jumping with different radii is rarely investigated, which is commonly encountered in nature. Therefore, it is essential to proceed with the research of coalescence and jumping of droplets with unequal radii. In this paper, molecular dynamics (MD) simulations are performed to reveal the effects of radius ratio and radius of small droplets on jumping velocity. The results show that as the increasing of radius ratio with an unchanged small droplet radius of 8.1 nm, the jumping velocity increases then decreases, which indicates there is an optimal radius ratio to maximize the jumping velocity. Additionally, it is found that if the small droplet radius is changed, the critical radius ratio for characterizing whether the coalesced droplet jumping increases with increasing the small droplet radius. Furthermore, according to energy conservation, the conversion efficiency of energy is discussed. The results show that when the radius ratio is greater than 1.3 with three different small droplet radii, the energy conversion efficiency rapidly decreases to below 1.0%; and the critical radius ratios are consistent with the result obtained from the velocity analysis. This work broadens the understanding of the more general phenomenon of coalescence-induced droplet jumping and can better guide industrial applications.
Dynamical Simulation, Sensitivity, and Productivity Analysis of a Light-Photoacclimation Model for Microalgae-Based Carbohydrate Production in Continuous Photobioreactors
Authors: Guzmán-Palomino Abraham , Aguilera-Vázquez Luciano , Hernández-Escoto Héctor , García-Vite Pedro Martin , Martínez-Salazar Ana Lidia
Published: June 2023

The world’s human population is increasing as is the demand for new sustainable sources of energy. Accordingly, microalgae-based carbohydrates for biofuel production are being considered as an alternative source of raw materials for producing biofuels. Microalgae grow in photobioreactors under constantly changing conditions. Models improve our understanding of microalgae growth. In this paper, a photoacclimated model for continuous microalgae cultures in photobioreactors was used to study the time-varying behavior and sensitivity of solutions under optimal productivity conditions. From the perspective of dynamic simulation in this work, light intensity was found to play an influential role in modifying metabolic pathways as a cell stressor. Enhancing carbohydrate productivity by combining nutritional deficiency and light intensity regulation modeling strategies could be helpful to optimize the process for the highest yield in large-scale cultivation systems. Under the proposed simulation conditions, a maximum carbohydrate productivity of 48.11 gCm−3d−1 was achieved using an optimal dilution rate of 0.2625 d−1 and 350 μmolm−2s−1 of light intensity. However, it is important to note that, a particular set of manipulated inputs can generate multiple outputs at a steady state. A numerical solution of the sensitivity functions indicated that the model outputs were especially sensitive to changes in parameters corresponding to a minimum nitrogen quota, maximum nitrogen intake rate, dilution rate, and maximum nitrogen quota compared to to other model parameters.
Design of Intelligent Nonlinear H2/H∞ Robust Control Strategy of Diesel Generator-Based CPSOGSA Optimization Algorithm
Authors: Zou Yidong , Xiao Boyi , Qian Jing , Xiao Zhihuai
Published: June 2023

In today’s human society, diesel generators (DGs) are widely applied in the human energy and electricity supply system due to its technical, operational, and economic advantages. This paper proposes an intelligent nonlinear H2/H∞ robust controller based on the chaos particle swarm gravity search optimization algorithm (CPSOGSA), which controls the speed and excitation of a DG. In this method, firstly, establish the nonlinear mathematical model of the DG, and then design the nonlinear H2/H∞ robust controller based on this. The direct feedback linearization and the H2/H∞ robust control theory are combined and applied. Based on the design of the integrated controller for DG speed and excitation, the system’s performance requirements are transformed into a standard robust H2/H∞ control problem. The parameters of the proposed solution controller are optimized by using the proposed CPSOGSA. The introduction of CPSOGSA completes the design of an intelligent nonlinear H2/H∞ robust controller for DG. The simulation is implemented in MATLAB/Simulink, and the results are compared with the PID control method. The obtained results prove that the proposed method can effectively improve the dynamic accuracy of the system and the ability to suppress disturbances and improve the stability of the system.
Development of a Novel Hydrodynamic Sequencing Batch Reactor for Landfill Leachate Treatment by Shortcut Biological Nitrogen Removal
Authors: Kim Minkyung , Mo Kyung , Kim Moonil , Cui Fenghao
Published: June 2023

This study introduced an alternative shortcut biological nitrogen removal (SBNR) process for landfill leachate treatment by developing a novel hydrodynamic sequencing batch reactor (H-SBR). The reactor could enhance the oxygen transfer rate (OTR) and nitrite accumulation ratio (NAR) by modifying internal hydrodynamic turbulence intensity. The average chemical oxygen demand (COD) and total nitrogen (TN) concentrations introduced into the reactor were 660 and 250 mg L−1, respectively, and the average removal efficiencies were 93% (COD) and 96% (TN). The effect of geometric parameters on oxygen transfer was estimated by performing a hydrodynamic model and a nonlinear least square analysis. After correcting the constants (α and β) of mass transfer coefficients (KLa) to values of 0.7361 and 1.2639, the model data fit the experiment well with an R-squared value of 0.99. The OTR improved by up to 30%, and hence, increased the NAR by up to 20% with a reduction of about 0.5 kg N kW−1 for power efficiency. The H-SBR development is innovative because the oxygen transfer efficiency was improved by the hydrodynamic modification of internal turbulence intensity, although not by mechanical equipment or chemical supplements. For the SBNR process, the modification of the reactor configuration for OTR enhancement could significantly improve nitrogen removal efficiency with successful nitrite accumulation. In addition to landfill leachate treatment, the H-SBR process can be employed in the treatment of low C/N ratio wastewaters.
Analysis Method of Full-Scale Pore Distribution Based on MICP, CT Scanning, NMR, and Cast Thin Section Imaging—A Case Study of Paleogene Sandstone in Xihu Sag, East China Sea Basin
Authors: Chen Jinlong , Huang Zhilong , Yao Genshun , Zhang Weiwei , Pan Yongshuai , Qu Tong
Published: June 2023

Using different experimental methods, the pore radius ranges vary greatly, and most scholars use a single experiment to study pore structure, which is rarely consistent with reality. Moreover, the numerical models used in different experiments vary and cannot be directly compared. This article uniformly revised all experimental data into a cylinder model. Quantitative analysis of the full-scale pore distribution is established by mercury withdrawal–CT data, and semi-quantitative distribution is obtained by mercury–NMR–cast thin section imaging. In this paper, we introduce the tortuosity index (τ) to convert the CT ball-and-stick model into a cylinder model, and the pore shape factor (η) of the cast is used to convert the plane model into the cylinder model; the mercury withdrawal data is applied to void the influence of narrow throat cavities, and the NMR pore radius distribution is obtained using the mercury-T2 calibration method. Studies have shown that the thickness of bound water is 0.35~0.4 μm, so the pores with different radius ranges were controlled by different mechanisms in the NMR tests, with pores < 0.35~0.4 μm completely controlled by surface relaxation, including strong bound water and weak bound water; pores in the 0.4~4 μm reange were controlled by surface relaxation; and pores > 10 μm were completely controlled by free relaxation. The surface relaxivity rate of fine sandstone was 18~20 μm/s. The tortuosity index τ was generally 1~7; the larger the value, the more irregular the pores. The pore shape factor η was generally 0.2~0.5; the smaller the value, the more irregular the pores. Mercury withdrawal–CT scan data can quantitatively determine the pore radius distribution curve. The coefficient of the logarithm is positive considering porosity, and the constant is negative considering porosity. Permeability controls the maximum pore radius, with a max pore radius > 100 μm and a permeability > 1 mD. Mercury withdrawal–NMR–cast thin section imaging data can semi-quantitatively establish a pore radius distribution histogram. The histogram represents quasi-normal, stepped, and unimodal data. When 60 μm is the inflection point, if a large proportion of pores measure > 60 μm, good reservoir quality is indicated. If a large proportion of pores measures < 60 μm, the permeability is generally <0.5 mD.
Application of Improved Artificial Immune System Algorithm Based on Applied Mathematics for Optimization of Manpower Allocation in Construction Engineering
Authors: Huang Qingbo , Bai Yong
Published: June 2023

The outbreak of the COVID-19 pandemic has led construction companies to prioritize the intelligent and optimal scheduling of human resources in construction projects to reduce costs. This study addresses the problem of heterogeneity in human resource scheduling in construction projects, presents a mathematical model with generic human resources as an example, proposes an improved artificial immune system (NAIS) algorithm to solve the problem, and verifies its effectiveness. Experimental results show that the NAIS algorithm achieves the optimal duration of 9 days in just 2 s using the Matrix Laboratory (MATLAB), which is significantly faster than mathematical optimization technique software (CPLEX), thus confirming the feasibility of the NAIS algorithm. Additionally, the average PD values for the NAIS algorithm, calculated for different worker counts, skills, and the number of tasks, were lower compared to the comparison algorithm. Overall, the NAIS algorithm effectively addresses the heterogeneous problem of human resource scheduling in construction projects with multiple modes, thereby optimizing construction engineering labor allocation.
Trafficking Women for Sexual Exploitation: A Systematic Review
Authors: Gomes Sofia Patrício , Sani Ana Isabel
Published: June 2023

Human trafficking is a complex global problem that demands current and scientifically grounded knowledge capable of coordinating interventions among various sectors of society. To address this issue, a systematic collection of scientific articles was conducted in two databases (Web of Science and Scielo) using keywords in both English and Portuguese. After screening 267 articles based on title, abstract, and full text, an 11-article sample was analyzed for quality. The results revealed that conceptual inconsistency is a challenge in signaling human trafficking, particularly in cases of sexual exploitation of women where it may be associated with prostitution, pimping, or migration—all of which are activities tied to financial gain. Addressing human trafficking requires action from concept to practice, including strengthened policies for sanctions and necessary support for victims.
Carbon-Based Synthesized Materials for CO2 Adsorption and Conversion: Its Potential for Carbon Recycling
Authors: Hoang Tuan-Dung , Bandh Suhaib A. , Malla Fayaz A. , Qayoom Irteza , Bashir Shahnaz , Peer Suhail Bashir , Halog Anthony
Published: June 2023

During the last half-century, the CO2 concentration in the world’s atmosphere has increased from 310 p.p.m. to over 380 p.p.m. This is due to the widespread usage of fossil fuels as a main source of energy. Modeling forecasts have shown that this trend will continue to rise and reducing CO2 emissions is a challenging task for multi-stakeholders, including research institutions. The UN Climate Change Conference in Glasgow (COP26) has stressed that stakeholders need to work together to achieve a NetZero target. Technologies involving absorbents for the capture of CO2 from a gas mixture are energy-intensive. Carbon adsorption and conversion (CAC) approaches have been gaining attention recently since these technologies can mitigate CO2 emissions. In this review, materials ranging from advanced carbon-based materials to natural resources-based materials will be reviewed. Adsorption and conversion capacities as well as the scalability possibility of these technologies for solving the CO2 emission problem will be investigated. The review, therefore, is timely and meaningful concerning the net zero emission targets set by countries and developmental organizations worldwide.
Diaconia as the Art of the Possible: Diaconal Engagement for Roma Migrants in Oslo, Norway
Authors: Holte Bjørn Hallstein
Published: June 2023

Itinerant Roma migrants travelling from Eastern European countries have featured across the European Economic Area (EEA) since the European Union’s eastward expansions in 2004 and 2007. Being unskilled, many Roma migrants engage in casual work and street work such as playing music, selling magazines, collecting and recycling bottles and cans, and begging, making them conspicuously visible in countries with public welfare services and low poverty levels. Citizens of EEA countries can enter and stay legally in other countries in the EEA for up to three months, after which they must register as workers or jobseekers, and generally leave. It is well documented how the countries Roma citizens of EEA countries travel to have enacted migration control measures, often in the form of complex and fine-grained regulations, that exclude them from public welfare services. This is also true of the Nordic countries, such as Norway, where they coincide with universalistic welfare states aiming to cover everyone living in their territories with the same benefits and services. In the Nordic countries, as in other countries, service provision for Roma migrants is largely in the hands of non-governmental organisations, many of them diaconal organisations running emergency shelters, soup kitchens, and other humanitarian services to alleviate suffering for people at the margins of the welfare state. The diaconal organisations also engage in case work and advocacy work to ensure the realisation of the Roma migrants’ rights. Many of the organisations depend on public grants, making their relationship to the welfare state ambiguous. This article investigates Christian social practice in the form of diaconal engagement for Roma migrants in Oslo, Norway at the intersection of migration control, the universalistic welfare state, and the theological underpinnings of the organisations.
The Reception of the Mantra of Light in Republican Period Chinese Buddhism
Authors: An Saiping
Published: June 2023

This paper examines the utilization of the mantra of light and its associated maṇḍala practices by Wang Hongyuan 王弘願 (1876–1937), a Chinese Buddhist during the Republican Period, and his adherents, which has not yet been noticed by previous scholars. With the import of esoteric Buddhist doctrines and practices from Japan, the mantra of light, which was a rarely used mantra in pre-modern China, gained renewed significance. This led to the widespread adoption of the ritual practices of this mantra by Wang Hongyuan and his surrounding Buddhist groups in early modern China. The rituals of this mantra were used as a supplement or substitute for near-death Pure Land practices. This paper presents Pure Land Buddhist practices intertwined with esoteric Buddhist elements or “esoteric” approaches to Pure Land rebirth in modern Chinese Buddhism which have been overlooked by previous scholars.
Assessing the Impact of Syrian Refugee Influx on the Jordanian Stock Exchange Market
Authors: Al-Rousan Nadia , Al-Najjar Dana , Al-Najjar Hazem
Published: June 2023

The past decade has witnessed significant turmoil and political conflicts in several Middle Eastern countries, such as Egypt, Syria, and Libya, called the Arab Spring. These revolutions did not only affect the countries mentioned previously; their neighboring countries were also directly affected. This study explores the impact of the Syrian refugee influx on the stock exchange market of one of its neighboring countries, namely Jordan. The Syrian civil war represents a recent catastrophic event that has resulted in over three million refugees migrating to various countries worldwide. The main objective of this paper is to examine the effect of the Syrian war on Jordan’s stock exchange market. The study utilizes the stock exchange indices as indicators of the performance of the exchange market, including Financials, Services, Industries, and General indices as dependent variables, and seven dummy variables are defined as representatives of the main events occurring in the Syrian civil war during the period 2011–2018 as independent variables. Multiple statistical analysis techniques, including correlation coefficients, error functions, and stepwise regression, are employed to analyze the selected variables. The findings reveal an inverse influence of the Syrian war on Jordan’s stock market. These findings can potentially enhance the development of prediction models for stock indices in Jordan and other countries by incorporating relevant variables.
Building a Practical Multi-Sensor Platform for Monitoring Vessel Activity near Marine Protected Areas: Case Studies from Urban and Remote Locations
Authors: Cope Samantha , Tougher Brendan , Zetterlind Virgil , Gilfillan Lisa , Aldana Andres
Published: June 2023

Monitoring vessel activity is an important part of managing marine protected areas (MPAs), but small-scale fishing and recreational vessels that do not participate in cooperative vessel traffic systems require additional monitoring strategies. Marine Monitor (M2) is a shore-based, multi-sensor platform that integrates commercially available hardware, primarily X-band marine radar and optical cameras, with custom software to autonomously track and report on vessel activity regardless of participation in other tracking systems. By utilizing established commercial hardware, the radar system is appropriate for supporting the management of coastal, small-scale MPAs. Data collected in the field are transferred to the cloud to provide a continuous record of activity and identify prohibited activities in real-time using behavior characteristics. To support the needs of MPA managers, both hardware and software improvements have been made over time, including ruggedizing equipment for the marine environment and powering systems in remote locations. Case studies are presented comparing data collection by both radar and the Automatic Identification System (AIS) in urban and remote locations. At the South La Jolla State Marine Reserve near San Diego, CA, USA, 93% of vessel activity (defined as the cumulative time vessels spent in the MPA) was identified exclusively by radar from November 2022 through January 2023. At the Caye Bokel Conservation Area, within the Turneffe Atoll Marine Reserve offshore of Belize, 98% was identified exclusively by radar from April through October 2022. Spatial and temporal patterns of radar-detected and AIS activity also differed at both sites. These case study site results together demonstrate the common and persistent presence of small-scale vessel activity near coastal MPAs that is not documented by cooperative systems. Therefore, an integrated radar system can be a useful tool for independent monitoring, supporting a comprehensive understanding of vessel activity in a variety of areas.
Diurnal Cycle in Surface Incident Solar Radiation Characterized by CERES Satellite Retrieval
Authors: Lu Lu , Ma Qian
Published: June 2023

Surface incident solar radiation (Rs) plays an important role in climate change on Earth. Recently, the use of satellite-retrieved datasets to obtain global-scale Rs with high spatial and temporal resolutions has become an indispensable tool for research in related fields. Many studies were carried out for Rs evaluation based on the monthly satellite retrievals; however, few evaluations have been performed on their diurnal variation in Rs. This study used independently widely distributed ground-based data from the Baseline Surface Radiation Network (BSRN) to evaluate hourly Rs from the Clouds and the Earth’s Radiant Energy System Synoptic (CERES) SYN1deg–1Hour product through a detrended standardization process. Furthermore, we explored the influence of cloud cover and aerosols on the diurnal variation in Rs. We found that CERES-retrieved Rs performs better at midday than at 7:00–9:00 and 15:00–17:00. For spatial distribution, CERES-retrieved Rs performs better over the continent than over the island/coast and polar regions. The Bias, MAB and RMSE in CERES-retrieved Rs under clear-sky conditions are rather small, although the correlation coefficients are slightly lower than those under overcast-sky conditions from 9:00 to 15:00. In addition, the range in Rs bias caused by cloud cover is 1.97–5.38%, which is significantly larger than 0.31–2.52% by AOD.
Soil Moisture Retrieval Using GNSS-IR Based on Empirical Modal Decomposition and Cross-Correlation Satellite Selection
Authors: Ding Qin , Liang Yueji , Liang Xingyong , Ren Chao , Yan Hongbo , Liu Yintao , Zhang Yan , Lu Xianjian , Lai Jianmin , Hu Xinmiao
Published: June 2023

Global Navigation Satellite System interferometric reflectometry (GNSS-IR), as a new remote sensing detection technology, can retrieve surface soil moisture (SM) by separating the modulation terms from the effective signal-to-noise ratio (SNR) data. However, traditional low-order polynomials are prone to over-fitting when separating modulation terms. Moreover, the existing research mainly relies on prior information to select satellites for SM retrieval. Accordingly, this study proposes a method based on empirical modal decomposition (EMD) and cross-correlation satellite selection (CCSS) for SM retrieval. This method intended to adaptively separate the modulation terms of SNR through the combination of EMD and an intrinsic mode functions (IMF) discriminant method, then construct a CCSS method to select available satellites, and finally establish a multisatellite robust estimation regression (MRER) model to retrieve SM. The results indicated that with EMD, the different feature components implied in the SNR data of different satellites could be adaptively decomposed, and the trend and modulation terms of the SNR could more accurately be acquired by the IMF discriminant method. The available satellites could be efficiently selected through CCSS, and the SNR quality of different satellites could also be classified at different accuracy levels. Furthermore, MRER could fuse the multisatellite phases well, which enhanced the accuracy of SM retrieval and further verified the feasibility and effectiveness of combining EMD and CCSS. When rm=0.600 and rn=0.700, the correlation coefficient (r) of the multisatellite combination reached 0.918, an improvement of at least 40% relative to the correlation coefficient of a single satellite. Therefore, this method can improve the adaptive ability of SNR decomposition, and the selection of satellites has high flexibility, which is helpful for the application and popularization of the GNSS-IR technology.