bluuebunny/crossref_metadata_2025 huggingface dataset:
Removal of Sodium from Vanadium Tailings by Calcification Roasting in Reducing Atmosphere
Authors: Wang Chao , Guo Yufeng , Wang Shuai , Chen Feng , Yang Lingzhi , Zheng Yu
Published: January 2023

Vanadium tailings from vanadium extraction by a sodium roasting process are solid waste and cannot be used in sintering and ironmaking due to their high sodium content. In this paper, a calcification and reduction roasting process was proposed to remove sodium from vanadium tailings. The effects of Ca(OH)2 addition, reduction temperature, and roasting time on the sodium removal behavior and compression strength of pellets were studied. The addition of Ca(OH)2 and the reduction of iron oxides promoted the sodium-containing phases to transform to be simpler, which could enhance sodium removal. The sodium removal rate was up to 93.47% and the compression strength of the reduced products was 4497 N/P, and the metallized ratio of the product was higher than 70% under the optimal conditions: roasting at 1200 °C for 2 h with the Ca(OH)2 addition of 35%. The treated product after removing sodium can be recycled in the ironmaking process in a steel company.
Modeling and Characterization of Surface Discharges in Insulating Material for Spacers: Electrode Shape, Discharge Mode, and Revision of the Creepage Concept
Authors: Nath Debasish , Yang Qichen , Montanari Giancarlo , Yin Weijun , Xiong Han , Younsi Karim
Published: January 2023

In the design of MV AC and DC spacers, the predominant factors are surface and interface conditions. Design is generally carried out on specifications and standards which are based on long-term experience and lab testing. However, the diffusion of power electronics with a trend to increase electric field, switching frequency, and rise time to achieve higher power density calls for an innovative, global approach to optimized insulation system design. A new methodology, based on field simulation, discharge modeling, and partial discharge inception measurements, called the three-leg approach, can form the basis to optimize insulation design for any type of supply voltage waveform. This paper focuses on the influence of the type of electrode on the inception and phenomenology of surface discharges and, as a consequence, on the interpretation of the results used for application of the three-leg approach. It is demonstrated that a typical electrode system used for insulating material testing can generate both gas and surface discharges at the triple point, when the electrodes have a smooth profile that is used to avoid corona or flashover. Hence, testing partial discharge may not provide a straightforward indication of the surface discharge inception and, thus, be partially misleading for insulation design. Another takeover is that such analysis must benefit from PD testing tools endowed with analytics able to provide automatic identification of the type of defect generating PD, i.e., internal, surface, and corona, since design and remedy actions can be taken, and adequate insulating materials developed, only knowing the type of source generating PD. Hence, testing partial discharge may not provide a straightforward indication of surface discharge inception and, thus, be partially misleading for insulation design. In addition to the importance of the three-leg approach to favor reliable and optimized design of insulation systems, there is a clear need to have a PD testing tool endowed with analytics. It should preferably be able to provide automatic identification of the type of defect generating PD, i.e., internal, surface, and corona.
(Na, Zr) and (Ca, Zr) Phosphate-Molybdates and Phosphate-Tungstates: I–Synthesis, Sintering and Characterization
Authors: Karaeva M. E. , Savinykh D. O. , Orlova A. I. , Khainakov S. A. , Nokhrin A. V. , Boldin M. S. , Garcia-Granda S. , Murashov A. A. , Chuvil’deev V. N. , Yunin P. A. , Nazarov A. A. , Tabachkova N. Y.
Published: January 2023

Submicron-grade powders of Na1-xZr2(PO4)3-x(XO4)x compounds (hereafter referred to as NZP) and Ca1-xZr2(PO4)3-x(XO4)x compounds (hereafter, CZP), X = Mo, W (0 ≤ x ≤ 0.5) were obtained by sol-gel synthesis. The compounds obtained were studied by X-ray diffraction phase analysis and electron microscopy. An increase in the W or Mo contents was shown to result in an increase in the unit cell volume of the NZP and CZP crystal lattices and in a decrease in the coherent scattering region sizes. Thermal expansion behavior at high temperatures of synthesized NZP and CZP compounds has been investigated. The dependencies of the parameters a and c on the heating temperature, as well as the temperature dependence of the crystal lattice unit cell volume V in the range from the room temperature up to 800 °C, were obtained. The dependencies of the average thermal expansion coefficient (αav) and of the volume coefficient (β) on the W and Mo contents in the compositions of NZP and CZP compounds were studied. Ceramics Na1-xZr2(PO4)3-x(XO4)x with relatively high density (more than 97.5%) were produced by spark plasma sintering (SPS). The increase in the W or Mo contents in the ceramics leads to an increase in the relative density of NZP and to a decrease of the optimum sintering temperature. The mean grain size in the NZP ceramics decreases with increasing W or Mo contents. The study of strength characteristics has revealed that the hardness of the NZP ceramics is greater than 5 GPa, and that the minimum fracture toughness factor was 1 MPa·m1/2.
Additive Manufacturing of Alloys and Composites
Authors: Dong Haokai , Lu Haizhou , Zhao Chao , Liu Lehua
Published: January 2023

The emergence and development of high-performance materials have benefited from the revolution in modern manufacturing technology, in which additive manufacturing (AM) is the most representative over the last four decades [...]
Recent Developments of High-Pressure Spark Plasma Sintering: An Overview of Current Applications, Challenges and Future Directions
Authors: Le Godec Yann , Le Floch Sylvie
Published: January 2023

Spark plasma sintering (SPS), also called pulsed electric current sintering (PECS) or field-assisted sintering technique (FAST) is a technique for sintering powder under moderate uniaxial pressure (max. 0.15 GPa) and high temperature (up to 2500 °C). It has been widely used over the last few years as it can achieve full densification of ceramic or metal powders with lower sintering temperature and shorter processing time compared to conventional processes, opening up new possibilities for nanomaterials densification. More recently, new frontiers of opportunities are emerging by coupling SPS with high pressure (up to ~10 GPa). A vast exciting field of academic research is now using high-pressure SPS (HP-SPS) in order to play with various parameters of sintering, like grain growth, structural stability and chemical reactivity, allowing the full densification of metastable or hard-to-sinter materials. This review summarizes the various benefits of HP-SPS for the sintering of many classes of advanced functional materials. It presents the latest research findings on various HP-SPS technologies with particular emphasis on their associated metrologies and their main outstanding results obtained. Finally, in the last section, this review lists some perspectives regarding the current challenges and future directions in which the HP-SPS field may have great breakthroughs in the coming years.
Study on Mechanical Properties of Two-Component Polyurethane Based on Multi-Scale Molecular Simulation
Authors: Wang Xingyu , Yu Tianlai , Wu Yuxuan , Sheng Yingjie , Wang Yifan , Hang Yutong
Published: January 2023

Mechanical properties determine the use of two-component polyurethane materials. The compatibility of two components in the polyether polyol-MDI molecular system greatly influences the formation of mechanical properties in polyurethane materials. In this paper, we studied and evaluated the compatibility and mechanical properties of two-component polyurethane at multiple scales by combining molecular dynamics simulation with macroscopic experiments, which is an important guideline for synthesizing and preparing two-component polyurethanes. We evaluated the stability of the two-component polyurethane system by calculating the solubility parameter, binding energy, and diffusion coefficient at four temperatures with three isocyanate contents. The Perl scripting language obtained the mechanical properties of the MDI-polyether polyol system. The MD calculation results show that the solubility parameter of two-component polyurethane negatively correlated with temperature, and the intermolecular binding energy and MDI diffusion coefficient positively correlated with temperature. When the mass ratio of polyether polyol to isocyanate was 1:0.6, the solubility parameter difference between the two was 1.43 (J/cm3)1/2, the intermolecular binding energy was 531.68 kcal/mol, and the two-component system was more stable. A macroscopic direct tensile test was employed to assess the polyurethane elastomers’ tensile properties. Our results show that the tensile strength of polyurethane elastomers increased with the increase in isocyanate content and decrease in temperature. Furthermore, the elongation at the break decreased, and the modulus increased, which is consistent with the law of molecular simulation.
Numerical Modelling of the Constitutive Behaviour of FRCM Composites through the Use of Truss Elements
Authors: Oddo Maria Concetta , Minafó Giovanni , Di Leto Marielisa , La Mendola Lidia
Published: January 2023

The modeling of the mechanical behavior of Fabric Reinforced Cementitious Matrix (FRCM) composites is a difficult task due to the complex mechanisms established at the fibre-matrix and composite-support interface level. Recently, several modeling approaches have been proposed to simulate the mechanical response of FRCM strengthening systems, however a simple and reliable procedure is still missing. In this paper, two simplified numerical models are proposed to simulate the tensile and shear bond behavior of FRCM composites. Both models take advantage of truss and non-linear spring elements to simulate the material components and the interface. The proposed approach enables us to deduce the global mechanical response in terms of stress-strain or stress-slip relations. The accuracy of the proposed models is validated against the experimental benchmarks available in the literature.
Volumetric Properties and Stiffness Modulus of Asphalt Concrete Mixtures Made with Selected Quarry Fillers: Experimental Investigation and Machine Learning Prediction
Authors: Rondinella Fabio , Daneluz Fabiola , Vacková Pavla , Valentin Jan , Baldo Nicola
Published: January 2023

In recent years, the attention of many researchers in the field of pavement engineering has focused on the search for alternative fillers that could replace Portland cement and traditional limestone in the production of asphalt mixtures. In addition, from a Czech perspective, there was the need to determine the quality of asphalt mixtures prepared with selected fillers provided by different local quarries and suppliers. This paper discusses an experimental investigation and a machine learning modeling carried out by a decision tree CatBoost approach, based on experimentally determined volumetric and mechanical properties of fine-grained asphalt concretes prepared with selected quarry fillers used as an alternative to traditional limestone and Portland cement. Air voids content and stiffness modulus at 15 °C were predicted on the basis of seven input variables, including bulk density, a categorical variable distinguishing the aggregates’ quarry of origin, and five main filler-oxide contents determined by means of X-ray fluorescence spectrometry. All mixtures were prepared by fixing the filler content at 10% by mass, with a bitumen content of 6% (PG 160/220), and with roughly the same grading curve. Model predictive performance was evaluated in terms of six different evaluation metrics with Pearson correlation and coefficient of determination always higher than 0.96 and 0.92, respectively. Based on the results obtained, this study could represent a forward feasibility study on the mathematical prediction of the asphalt mixtures’ mechanical behavior on the basis of its filler mineralogical composition.
Structural, Vibrational, and Magnetic Characterization of Orthoferrite LaFeO3 Ceramic Prepared by Reaction Flash Sintering
Authors: Manchón-Gordón Alejandro F. , Sánchez-Jiménez Pedro E. , Blázquez Javier S. , Perejón Antonio , Pérez-Maqueda Luis A.
Published: January 2023

LaFeO3 perovskite ceramics have been prepared via reaction flash technique using Fe2O3 and La2O3 as precursors. The obtained pellets have been investigated using several techniques. The formation of LaFeO3 has been clearly confirmed by X-ray diffraction. The scanning electron microscopy micrographs have shown the microporous character of the obtained pellets due to the low temperature and dwell time used in the synthesis process (10 min at 1173 K). The orthorhombic-rhombohedral phase transition has been observed at approximately 1273 K in differential thermal analysis measurements, which also allows us to determine the Néel temperature at 742 K. The fitted Mössbauer spectra exposed the presence of a single sextet ascribed to the Fe+3 ions in the tetrahedral site. Finally, magnetic measurements at room temperature indicate the antiferromagnetic character of the sample.
PT Symmetry-Based AUV Dual Transmission Coil Wireless Power Transfer System Design
Authors: Fu You , Shi Zhuoqun , Zhu Yu , Lv Kai , Peng Zhouhua
Published: January 2023

Autonomous underwater vehicles (AUVs) are widely used for ocean exploration; however, the way they are replenished becomes the biggest issue limiting their range and efficiency. A dual transmission coil wireless power transfer (DTCWPT) system based on parity–time (PT) symmetry is proposed in this paper to realize an autoadaptive constant power transmission. A shielded housing structure for coils is equipped to realize WPT in the ocean. In the offset experiments, the proposed dual transmitting coil structure was able to achieve a stable power transmission of 39 W within an offset range of 8.1 cm. It is obvious that the DTCWPT system based on PT symmetry could charge an AUV in the ocean with high robustness. This paper provides a novel solution based on DTCWPT for AUV energy supply. The proposed DTCWPT system could offer remarkable improvements in the navigation performance of AUVs.
Numerical and Experimental Investigations of Axial Flow Fan with Bionic Forked Trailing Edge
Authors: Liang Zhong , Wang Jun , Wang Wei , Jiang Boyan , Ding Yanyan , Qin Wanxiang
Published: January 2023

To improve the performance of the aerodynamic properties and reduce the aerodynamic noise of an axial flow fan in the outdoor unit of an air conditioner, this study proposed a bionic forked trailing-edge structure inspired by the forked fish caudal fin and implemented by modifying the trailing edge of the prototype fan. The effect of the bionic forked trailing edge on the aerodynamic and aeroacoustic performance was investigated experimentally, and detailed analyses of the blade load and internal vortex structures were performed based on large-eddy simulations (LES). It is shown that the bionic forked trailing edge could effectively adjust the blade load distribution, reduce the pressure difference between the pressure side and suction side near the trailing edge of the blade tip region, and weaken the intensity and influence range of the inlet vortex (IV) and the tip leakage vortex (TLV). The discrete noise caused by the vortices in the rotor tip area was also reduced, particularly at the blade passing frequency (BPF) and its harmonic frequency. The experimental results confirmed the existence of an optimal bionic forked trailing-edge structure, resulting in the maximum power-saving rate γ of 7.5% and the reduction of 0.3 ~ 0.8 dB of aerodynamic noise, with an included angle θt of 13.5°. The detailed analysis of the internal vortex structures provides a good reference for the efficiency improvement and noise reduction of axial flow fans.
Microstructural Model of Magnetic and Deformation Behavior of Single Crystals and Polycrystals of Ferromagnetic Shape Memory Alloy
Authors: Rogovoy Anatoli A. , Stolbova Olga S.
Published: January 2023

In this article, a microstructural model of the Heusler alloy with the shape memory effect caused by the application of an external magnetic field is constructed. The dynamics of the magnetization process are described using the Landau–Lifshitz–Gilbert equation. For the numerical implementation of the model using the finite element method, the variational equations corresponding to the differential formulation of the magnetic problem are used. Such an approach makes it possible to reduce (weaken) the requirements for the smoothness of the sought solution. The problem of magnetization of single crystals of the Ni2MnGa alloy, which has a “herringbone”-type martensitic structure (a twinned variant of martensite), is considered. In each element of the twin, the magnetic domains with walls of a certain thickness are formed. The motion and interaction of these walls and the rotation of magnetization vector in the walls and domains under the action of the external differently directed magnetic fields are studied. These processes in the Heusler alloy are also accompanied by the detwinning process. A condition for the detwinning of a ferromagnetic shape memory alloy in a magnetic field is proposed, and the effect of the reorientation (detwinning) of martensitic variants forming a twin on the magnetization of the material and the occurrence of structural (detwinning) deformation in it are taken into account. First, the processes of magnetization and structural deformation in a single grain are considered at different angles between the anisotropy axes of twinned variants and the external magnetic field. For these cases, the magnetization curves are constructed, and the deformed states are identified. The model described such experimental facts as the detwinning process and the jump in magnetization on these curves as a result of this process. It was shown that the jump occurred at a certain magnitude of the strength of the applied external magnetic field and a certain direction of its action relative to the twinning system. Then, based on the obtained results, deformed states arising due to the detwinning process were determined for various (isotropic and texture-oriented) polycrystalline samples, and magnetization curves taking into account this process were constructed for these materials.
Effects of Diesel Price on Changes in Agricultural Commodity Prices in Bulgaria
Authors: Ivanova Miroslava , Dospatliev Lilko
Published: January 2023

The aim of this article is to supply the first empirical research inspecting how changes in diesel prices influence the prices of four agricultural commodities in Bulgaria. For this purpose, using a VECM and monthly agricultural commodity prices between January 2011 and July 2022, we estimated short-run and long-run changes in producer and retail prices of cow’s milk, chicken eggs, greenhouse tomatoes and cucumbers due to the change in average monthly diesel prices. The Granger causality test indicates that diesel prices cannot be used to forecast the behavior of producer and retail prices in the four markets considered. Diesel prices can be used to forecast the behavior of producer prices in only the cow’s milk market, and the diesel price predicts retail prices in the chicken egg and greenhouse cucumber markets. The results of the response of the researched prices of agricultural commodities to diesel price shocks indicate a positive response of both upstream and downstream prices of cow’s milk and chicken egg markets and upstream prices of the greenhouse tomato market despite the initial negative shock.
A Distributed Blocking Flowshop Scheduling with Setup Times Using Multi-Factory Collaboration Iterated Greedy Algorithm
Authors: Zhang Chenyao , Han Yuyan , Wang Yuting , Li Junqing , Gao Kaizhou
Published: January 2023

As multi-factory production models are more widespread in modern manufacturing systems, a distributed blocking flowshop scheduling problem (DBFSP) is studied in which no buffer between adjacent machines and setup time constraints are considered. To address the above problem, a mixed integer linear programming (MILP) model is first constructed, and its correctness is verified. Then, an iterated greedy-algorithm-blending multi-factory collaboration mechanism (mIG) is presented to optimize the makespan criterion. In the mIG algorithm, a rapid evaluation method is designed to reduce the time complexity, and two different iterative processes are selected by a certain probability. In addition, collaborative interactions between cross-factory and inner-factory are considered to further improve the exploitation and exploration of mIG. Finally, the 270 tests showed that the average makespan and RPI values of mIG are 1.93% and 78.35% better than the five comparison algorithms on average, respectively. Therefore, mIG is more suitable to solve the studied DBFSP_SDST.
Stabilization of Stochastic Dynamical Systems of a Random Structure with Markov Switches and Poisson Perturbations
Authors: Lukashiv Taras , Litvinchuk Yuliia , Malyk Igor V. , Golebiewska Anna , Nazarov Petr V.
Published: January 2023

An optimal control for a dynamical system optimizes a certain objective function. Here, we consider the construction of an optimal control for a stochastic dynamical system with a random structure, Poisson perturbations and random jumps, which makes the system stable in probability. Sufficient conditions of the stability in probability are obtained, using the second Lyapunov method, in which the construction of the corresponding functions plays an important role. Here, we provide a solution to the problem of optimal stabilization in a general case. For a linear system with a quadratic quality function, we give a method of synthesis of optimal control based on the solution of Riccati equations. Finally, in an autonomous case, a system of differential equations was constructed to obtain unknown matrices that are used for the construction of an optimal control. The method using a small parameter is justified for the algorithmic search of an optimal control. This approach brings a novel solution to the problem of optimal stabilization for a stochastic dynamical system with a random structure, Markov switches and Poisson perturbations.
An Improved DEA Prospect Cross-Efficiency Evaluation Method and Its Application in Fund Performance Analysis
Authors: Ning Yangxue , Zhang Yan , Wang Guoqiang
Published: January 2023

It is well known that a traditional data envelopment analysis (DEA) cross-efficiency evaluation model assumes that the decision-makers are completely rational, which causes the evaluation results to be inconsistent with the actual situation. To remedy this, in this paper, we propose an improved DEA prospect cross-efficiency evaluation method called EPCE model. The EPCE model captures the risk attitude of decision-makers and retains the decision information in the evaluation process. In particular, this new approach generates a more practical, realistic weighting scheme to measure the cross-efficiency and provides a reliable technique for ordering the decision-making units (DMUs) from the perspective of multi-criteria decision analysis. Finally, to demonstrate the validity and reliability of the proposed approach, we show an empirical analysis of mutual fund investment selection from Chinese fund market.
Effect of Macrophages and Latent Reservoirs on the Dynamics of HTLV-I and HIV-1 Coinfection
Authors: Elaiw A. M. , AlShamrani N. H. , Dahy E. , Abdellatif A. A. , Raezah Aeshah A.
Published: January 2023

Human immunodeficiency virus type 1 (HIV-1) and human T-lymphotropic virus type I (HTLV-I) are two retroviruses that have a similar fashion of transmission via sharp objects contaminated by viruses, transplant surgery, transfusion, and sexual relations. Simultaneous infections with HTLV-I and HIV-1 usually occur in areas where both viruses have become endemic. CD4+T cells are the main targets of HTLV-I, while HIV-1 can infect CD4+T cells and macrophages. It is the aim of this study to develop a model of HTLV-I and HIV-1 coinfection that describes the interactions of nine compartments: susceptible cells of both CD4+T cells and macrophages, HIV-1-infected cells that are latent/active in both CD4+T cells and macrophages, HTLV-I-infected CD4+T cells that are latent/active, and free HIV-1 particles. The well-posedness, existence of equilibria, and global stability analysis of our model are investigated. The Lyapunov function and LaSalle’s invariance principle were used to study the global asymptotic stability of all equilibria. The theoretically predicted outcomes were verified by utilizing numerical simulations. The effect of including the macrophages and latent reservoirs in the HTLV-I and HIV-1 coinfection model is discussed. We show that the presence of macrophages makes a coinfection model more realistic when the case of the coexistence of HIV-1 and HTLV-I is established. Moreover, we have shown that neglecting the latent reservoirs in HTLV-I and HIV-1 coinfection modeling will lead to the design of an overflow of anti-HIV-1 drugs.
Exact Closed-Form Solution for the Oscillator with a New Type of Mixed Nonlinear Restitution Force
Authors: Cveticanin Livija
Published: January 2023

This paper shows an oscillator with a spring made of material where the stress is a function not only of strain but also strain rate. The corresponding restitution force is of strong nonlinear monomial type and is the product of displacement and velocity of any order. The mathematical model of the oscillator is a homogenous strong nonlinear second-order differential equation with an integer- or non-integer-order mixed term. In the paper, an analytical procedure for solving this new type of strong nonlinear equation is developed. The approximate solution is assumed as the perturbed version of the exact solution in the form of a sine Ateb function. As a result, it is obtained that the amplitude, period, and frequency of vibration depend not only on the coefficient and order of nonlinearity, but also on the initial velocity. The procedure is tested on two examples: oscillator perturbed with small linear damping and small linear displacement functions. The analytically obtained results are compared with the exact numerical ones and show good agreement. It is concluded that the mathematical model and also the procedure developed in the paper would be convenient for prediction of motion for this type of oscillator without necessary experimental testing.
Botryllin, a Novel Antimicrobial Peptide from the Colonial Ascidian Botryllus schlosseri
Authors: Franchi Nicola , Ballarin Loriano , Cima Francesca
Published: January 2023

By mining the transcriptome of the colonial ascidian Botryllus schlosseri, we identified a transcript for a novel styelin-like antimicrobial peptide, which we named botryllin. The gene is constitutively transcribed by circulating cytotoxic morula cells (MCs) as a pre-propeptide that is then cleaved to mature peptide. The synthetic peptide, obtained from in silico translation of the transcript, shows robust killing activity of bacterial and unicellular yeast cells, causing breakages of both the plasma membrane and the cell wall. Specific monoclonal antibodies were raised against the epitopes of the putative amino acid sequence of the propeptide and the mature peptide; in both cases, they label the MC granular content. Upon MC degranulation induced by the presence of nonself, the antibodies recognise the extracellular nets with entrapped bacteria nearby MC remains. The obtained results suggest that the botryllin gene carries the information for the synthesis of an AMP involved in the protection of B. schlosseri from invading foreign cells.
Cryptic Diversity of Black Band Disease Cyanobacteria in Siderastrea siderea Corals Revealed by Chemical Ecology and Comparative Genome-Resolved Metagenomics
Authors: Meyer Julie L. , Gunasekera Sarath P. , Brown Anya L. , Ding Yousong , Miller Stephanie , Teplitski Max , Paul Valerie J.
Published: January 2023

Black band disease is a globally distributed and easily recognizable coral disease. Despite years of study, the etiology of this coral disease, which impacts dozens of stony coral species, is not completely understood. Although black band disease mats are predominantly composed of the cyanobacterial species Roseofilum reptotaenium, other filamentous cyanobacterial strains and bacterial heterotrophs are readily detected. Through chemical ecology and metagenomic sequencing, we uncovered cryptic strains of Roseofilum species from Siderastrea siderea corals that differ from those on other corals in the Caribbean and Pacific. Isolation of metabolites from Siderastrea-derived Roseofilum revealed the prevalence of unique forms of looekeyolides, distinct from previously characterized Roseofilum reptotaenium strains. In addition, comparative genomics of Roseofilum strains showed that only Siderastrea-based Roseofilum strains have the genetic capacity to produce lasso peptides, a family of compounds with diverse biological activity. All nine Roseofilum strains examined here shared the genetic capacity to produce looekeyolides and malyngamides, suggesting these compounds support the ecology of this genus. Similar biosynthetic gene clusters are not found in other cyanobacterial genera associated with black band disease, which may suggest that looekeyolides and malyngamides contribute to disease etiology through yet unknown mechanisms.
Influence of Three Different Surgical Techniques on Microscopic Damage of Saphenous Vein Grafts—A Randomized Study
Authors: Zivkovic Igor , Krasic Stasa , Stankovic Milica , Milacic Petar , Milutinovic Aleksandar , Zdravkovic Djordje , Tabakovic Zoran , Peric Miodrag , Krstic Miljan , Bojic Milovan , Milic Dragan , Micovic Slobodan
Published: January 2023

Background and Objectives: The saphenous vein is one of the most common used grafts (SVG) for surgical revascularization. The mechanism of the SVGs occlusion is still unknown. Surgical preparation techniques have an important role in the early and late graft occlusion. Our study analyzed the influence of the three different surgical techniques on the histological and immunohistochemical characteristics of the vein grafts. Methods: Between June 2019 and December 2020, 83 patients who underwent surgical revascularization were prospectively randomly assigned to one of the three groups, according to saphenous vein graft harvesting (conventional (CVH), no-touch (NT) and endoscopic (EVH)) technique. The vein graft samples were sent on the histological (hematoxylin-eosin staining) and immunohistochemical (CD31, Factor VIII, Caveolin and eNOS) examinations. Results: The CVH, NT, and EVH groups included 27 patients (mean age 67.66 ± 5.6), 31 patients (mean age 66.5 ± 7.4) and 25 patients (mean age 66 ± 5.5), respectively. Hematoxylin-eosin staining revealed a lower grade of microstructural vein damage in the NT group (2, IQR 1-2) in comparison with CVH and EVH (3, IQR 2-4), (4, IQR 2-4) respectively (p < 0.001). Immunohistochemical examination revealed a high grade of staining in the NT group compared to the CVH and EVH group (CD 31 antibody p = 0.02, FVIII, p < 0.001, Caveolin, p = 0.001, and eNOS, p = 0.003). Conclusion: The best preservation of the structural vein integrity was in the NT group, while the lowest rate of leg wound complication was in the EVH group. These facts increase the interest in developing and implementing the endoscopic no-touch technique.
Free Flaps for Skin and Soft Tissue Reconstruction in the Elderly Patient: Indication or Contraindication
Authors: Sorg Heiko , Sorg Christian G. G. , Tilkorn Daniel J. , Thönnes Simon , Karimo Rees , Hauser Jörg
Published: January 2023

Background: Increased lifespan and the improvement of medical treatment have given rise to research in reconstructive procedures in elderly patients. Higher postoperative complication rates, longer rehabilitation, and surgical difficulties remain a problem in the elderly. We asked whether a free flap in elderly patients is an indication or a contraindication and performed a retrospective, monocentric study. Methods: Patients were divided into two groups (YOUNG 0–59 years; OLD > 60 years). The endpoint was the survival of flaps and their dependence on patient- and surgery-specific parameters using multivariate analysis. Results: A total of 110 patients (OLD n = 59) underwent 129 flaps. The chance of flap loss increased as soon as two flaps were performed in one surgery. Anterior lateral thigh flaps had the highest chance for flap survival. Compared with the lower extremity, the head/neck/trunk group had a significantly increased chance of flap loss. There was a significant increase in the odds of flap loss in linear relation to the administration of erythrocyte concentrates. Conclusion: The results confirm that free flap surgery can be indicated as a safe method for the elderly. Perioperative parameters such as two flaps in one surgery and transfusion regimens must be considered as risk factors for flap loss.
Carboxylated Graphene Oxide (c-GO) Embedded ThermoPlastic Polyurethane (TPU) Mixed Matrix Membrane with Improved Physicochemical Characteristics
Authors: Zahid Muhammad , Saeeda Maryam , Nadeem Nimra , Shakir Hafiz Muhammad Fayzan , El-Saoud Waleed A. , Attala Osama A. , Attia Kamal A. , Rehan Zulfiqar Ahmad
Published: January 2023

Water is an important component of our life. However, the unavailability of fresh water and its contamination are emerging problems. The textile industries are the major suppliers of contamination of water, producing high concentrations of heavy metals and hazardous dyes posing serious health hazards. Several technologies for water purification are available in the market. Among them, the membrane technology is a highly advantageous and facile strategy to remediate wastewater. Herein, the distinguished combination of pore-forming agents, solvent, and nanoparticles has been used to achieve improved functioning of the polymeric composite membranes. To do so, graphene oxide (GO) was fabricated via Hummer’s technique and GO functionalization using chloroacetic acid (c-GO) was performed. Thermoplastic polyurathane (TPU) membranes having different concentrations c-GO were made using the phase inversion technique. Scanning electron microscopy (SEM), Fourier transforms infrared spectroscopy (FT-IR), and X-ray diffraction (XRD) was used to examine surface morphology, chemical functionalities on membranes surfaces, and crystallinity of membranes, respectively. The temperature-dependent behavior of c-GO composite membranes has been analyzed using DSC technique. The water contact angle measurements were performed for the estimation of hydrophilicity of the c-GO based TPU membrane. The improved water permeability of the composite membrane was observed with increasing the c-GO concentration in polymeric membranes. c-GO was observed as a potential candidate that enhanced membrane physicochemical properties. The proposed membranes can behave as efficient candidates in multiple domains of environmental remediation. Furthermore, the improved dye rejection characteristics of proposed composite membranes suggest that the membranes can be best suited for wastewater treatment as well.
Influence of the Cutting Feed Rate on the Hardness and Microstructure of Copper Using Plasma Arc Machining (PAM)
Authors: Abouzaid Abdelrahman , Mousa Saeed
Published: January 2023

This study investigated the influence of the cutting feed rate on the hardness and microstructure of copper machined using a plasma arc (PA) to examine the resulting changes and their impact on the quality of the cut surface. Various constant cutting feed rates and amperage values were used as parameters to measure the cutting performance. Pre- and post-cut hardness measurements and scanning electron microscope (SEM) images were taken. The hardness of the copper surface was the same before and after plasma arc cutting (PAC). PAC did not affect the copper’s hardness or the microstructure of the thermally affected cutting zone. The copper from the cut surface was melted by the PA operation near the edge of the cutting surface with no change in the microstructure. SEM imaging of the cut confirmed this. Thus, the quality of the cutting surface was not affected. In addition, the microstructure of the copper’s thermally affected cutting zone did not alter the cutting surface’s quality. Hardness measurements post-cutting yielded 69.28, 71.65, 70.15, and 60.09 HB for four tests at 500 mm/min and 30 A. The lowest cutting width was 1.504 mm at 12,000 mm/min, and the surface roughness was 2.5 µm at 500 mm/min.
Effects of Al2O3/TiO2/Na2O on Lime Dissolution in Steelmaking Slag
Authors: Yu Kan , Zhang Yanling , Zhang Shuai , Gao Ming
Published: January 2023

The mechanism of lime dissolution in steelmaking slag and the factors that influence the dissolution rate are highly significant in improving the efficiency of the steelmaking process; however, they are yet to be fully understood. Here, the effects of Al2O3/TiO2/Na2O additives on the dissolution rate of lime and the composition of molten slag were investigated using a rotating cylinder technique. The results indicate that the promotion coefficients at 1400 °C decrease in the order of Na2O > TiO2 > Al2O3. Furthermore, the CaO dissolution rate and kinetic parameters were calculated, and the lime dissolution mechanisms in the presence or absence of Al2O3, TiO2, and Na2O were compared. Additionally, the data show that ATN (a mixture with a mass ratio of Al2O3:TiO2:Na2O = 15:4:3) can be used as a suitable flux in the steelmaking process.
Effects of Saline-Alkaline Stress on Metabolome, Biochemical Parameters, and Histopathology in the Kidney of Crucian Carp (Carassius auratus)
Authors: Ding Lu , Liu Yingjie , Wei Xiaofeng , Geng Chuanye , Liu Wenzhi , Han Lin , Yuan Fangying , Wang Peng , Sun Yanchun
Published: January 2023

The salinization of the water environment caused by human activities and global warming has increased which has brought great survival challenges to aquatic animals. Crucian carp (Carassius auratus) is an essential freshwater economic fish with superior adaptability to saline-alkali water. However, the physiological regulation mechanism of crucian carp adapting to saline-alkali stress remains still unclear. In this study, crucian carp were exposed to freshwater or 20, 40, and 60 mmol/L NaHCO3 water environments for 30 days, the effects of saline-alkali stress on the kidney were evaluated by histopathology, biochemical assays and metabolomics analysis from renal function, antioxidant capacity and metabolites level. Our results showed different degrees of kidney damage at different exposure concentrations, which were characterized by glomerular atrophy and swelling, renal tubular degranulation, obstruction and degeneration, renal interstitial edema, renal cell proliferation and necrosis. Saline-alkali stress could change the levels of several physiological parameters with renal function and antioxidant capacity, including creatinine (CREA), urea nitrogen (BUN), superoxide dismutase (SOD), catalase (CAT), glutathione peroxidase (GSH-Px) and malondialdehyde (MDA). In addition, metabolomics analysis showed that differential metabolites (DMs) were involved in various metabolic pathways, including phenylalanine, tyrosine, and tryptophan biosynthesis, aminoacyl-tRNA biosynthesis, purine metabolism, glycerophospholipid metabolism, sphingolipid metabolism, glycolysis/gluconeogenesis and the TCA cycle. In general, our study revealed that saline-alkaline stress could cause significant changes in renal function and metabolic profiles, and induce severe damage in the crucian carp kidney through destroying the anti-oxidant system and energy homeostasis, inhibiting protein and amino acid catabolism, as well as disordering purine metabolism and lipid metabolism. This study could contribute to a deeper understanding the adverse effects of saline-alkali stress on crucian carp kidney and the regulatory mechanism in the crucian carp of saline-alkali adaptation at the metabolic level.
Potential Mammalian Vector-Borne Diseases in Live and Wet Markets in Indonesia and Myanmar
Authors: Nijman Vincent , Nekaris K. A. I. , Shepherd Chris R. , Vigne Lucy , Ardiansyah Ahmad , Imron Muhammad Ali , Ni Qinyong , Hedger Katherine , Campera Marco , Morcatty Thais Q.
Published: January 2023

Vector-borne diseases spread from wild animals and their associated ectoparasites to humans and domesticated animals. Wildlife markets are recognized as important areas where this transfer can take place. We assessed the potential for spreading vector-borne diseases in two live and wet markets in Myanmar (Mong La, on the Myanmar-China border) and Indonesia (Sukahaji in Bandung on the island of Java) by making an inventory of all live and freshly killed wild mammals for sale. For eight mammal families, we quantified the number of animals on offer, and we used a heatmap cluster analysis to map vector-borne diseases that these families may carry. In Myanmar, we observed large numbers of wild pigs and deer (potentially carrying West Nile and various encephalitis viruses) whereas in Indonesia we observed Old World fruit bats (potentially carrying Chikungunya and encephalitis viruses) and squirrels (potentially carrying West Nile and encephalitis viruses). The trade in Indonesia was dominated by live mammals offered for sale as pets, and only Old World fruit bats and squirrels traded for traditional Asian medicine were killed in the markets. The trade in Myanmar was more geared towards wild meat (e.g., wild pigs, deer, primates) and traditional Asian medicine (squirrels). The combined risks of vector-borne diseases spreading from traded animals to human health highlight the need for an integrated approach protecting public health, economic interests and biodiversity.
Assessing the Baseline Uranium in Groundwater around a Proposed Uraninite Mine and Identification of a Nearby New Reserve
Authors: Bhavya Ravinder , Sivaraj Kaveri , Elango Lakshmanan
Published: January 2023

The presence of uranium in groundwater is a cause of concern all over the world. In mineralized regions where elevated concentrations of uranium are possible in groundwater, mining activities can further degrade the water quality. Hence, it is essential to document the baseline uranium concentration in groundwater before the commencement of mining. This study was carried out with the objective of assessing the concentration of uranium in groundwater around a proposed uraninite mining site in the Gogi region, Karnataka, India. Gogi is a village in the Yadgir district of Karnataka where groundwater is the main source of water for domestic needs. The uranium mineralized zone in this region occurs along the major E-W trending Gogi-Kurlagere fault at a depth of about 150 m. Groundwater samples were collected every three months from January 2020 to October 2020 from 52 wells located in this area. The concentration of uranium in groundwater ranged from 1.5 ppb to 267 ppb. The USEPA and WHO have recommended a permissible limit of 30 ppb, while the Atomic Energy Regulatory Board of India has a limit of 60 ppb for the purpose of drinking water. Based on these permissible limits for uranium in drinking water, concentrations exceeded the limit in about 25% of wells within 20 km from the mineralized region. Wells present in the granitic and limestone terrain exhibited higher concentrations of uranium in this area. Uranium concentration in groundwater changes depending on the degree of weathering, lithology, and rainfall recharge. This study will serve as a baseline and will help to assess the impact of mining activities in this region in the future. In wells where the uranium concentration exceeds permissible limits, it is suggested not to use groundwater directly for drinking purposes. These sites need to be explored further for the possible presence of uranium-bearing minerals.
Accuracy of Measurements of Thermophysical Parameters by Dual-Beam Thermal-Lens Spectrometry
Authors: Khabibullin Vladislav R. , Franko Mladen , Proskurnin Mikhail A.
Published: January 2023

Thermal-lens spectrometry is a sensitive technique for determination of physicochemical properties and thermophysical parameters of various materials including heterogeneous systems and nanoparticles. In this paper, we consider the issues of the correctness (trueness) of measurements of the characteristic time of the thermal-lens effect and, thus, of the thermal diffusivity determined by dual-beam mode-mismatching thermal lensing. As sources of systematic errors, major factors—radiation sources, sample-cell and detector parameters, and general measurement parameters—are considered using several configurations of the thermal-lens setups, and their contributions are quantified or estimated. Furthermore, with aqueous ferroin and Sudan I in ethanol as inert colorants, the effects of the intermolecular distance of the absorbing substance on the correctness of finding the thermophysical parameters are considered. The recommendations for checking the operation of the thermal-lens setup to ensure the maximum accuracy are given. The results obtained help reducing the impact of each investigated factor on the value of systematic error and correctly measure the thermophysical parameters using thermal-lens spectrometry.
Carbon Hybrid Materials—Design, Manufacturing, and Applications
Authors: Pujari Anuptha , Chauhan Devika , Chitranshi Megha , Hudepohl Ronald , Kubley Ashley , Shanov Vesselin , Schulz Mark
Published: January 2023

Carbon nanotubes (CNTs) have extraordinary properties and are used for applications in various fields of engineering and research. Due to their unique combination of properties, such as good electrical and thermal conductivity and mechanical strength, there is an increasing demand to produce CNTs with enhanced and customized properties. CNTs are produced using different synthesis methods and have extraordinary properties individually at the nanotube scale. However, it is challenging to achieve these properties when CNTs are used to form macroscopic sheets, tapes, and yarns. To further improve the properties of macroscale forms of CNTs, various types of nanoparticles and microfibers can be integrated into the CNT materials. The nanoparticles and microfibers can be chosen to selectively enhance the properties of CNT materials at the macroscopic level. In this paper, we propose a technique to manufacture carbon hybrid materials (CHMs) by combining CNT non-woven fabric (in the form of sheets or tapes) with microfibers to form CNT-CF hybrid materials with new/improved properties. CHMs are formed by integrating or adding nanoparticles, microparticles, or fibers into the CNT sheet. The additive materials can be incorporated into the synthesis process from the inlet or the outlet of the reactor system. This paper focuses on CHMs produced using the gas phase pyrolysis method with microparticles/fibers integrated at the outlet of the reactor and continuous microfiber tapes integrated into the CNT sheet at the outlet using a tape feeding machine. After synthesis, characterizations such as microscopy and thermogravimetric analysis were used to study the morphology and composition of the CNTs, and examples for potential applications are discussed in this paper.