Fluid-mediated, brittle-ductile deformation at seismogenic depth: Part I – Fluid record and deformation history of fault-veins in a nuclear waste repository (Olkiluoto Island, Finland)
Authors: Marchesini Barbara , Garofalo Paolo Stefano , Menegon Luca , Mattila Jussi , Viola Giulio 
Published: January 2019

Abstract. The dynamic evolution of fault zones at the seismogenic brittle-ductile transition zone (BDTZ) expresses the delicate interplay of numerous physical and chemical processes that occur at the time of strain localization. Deformation and flow of aqueous fluids in these zones, in particular, are closely related and mutually dependent during cycles of repeating, transient frictional and viscous deformation. Despite numerous studies documenting in detail seismogenic faults exhumed from the BDTZ, uncertainties remain as to the role of fluids in facilitating deformation in this zone, particularly with regard to the mechanics of broadly coeval brittle and ductile deformation. We combine here structural analysis, fluid inclusion data and mineral chemistry data from synkinematic and authigenic minerals to reconstruct the temporal variations in P, T and bulk composition of the fluids that mediated deformation and steered strain localization in a strike-slip fault from the BDTZ. This is a fault formed within the Paleoproterozoic migmatitic basement of southwestern Finland, hosting in its core two laterally continuous quartz veins formed by two texturally distinct quartz types – Qtz I and Qtz II, where Qtz I is demonstrably older than Qtz II. Veins within the diffuse damage zone of the fault are infilled by Qtz I. Multi-scalar structural analysis indicates recurrent cycles of mutually overprinting brittle and ductile deformation. Fluid inclusion microthermometry and mineral pair geothermometry indicate that both quartz types precipitated from a fluid that was in a homogeneous state during the recurrent cycles of faulting, and whose bulk salinity was in the 0–5 wt % NaCleq range. The temperature of the fluid phase involved with the various episodes of initial strain localization and later reactivation changed with time, from c. 240 °C in the damage zone to c. 350 °C in the core during Qtz I precipitation to < 200 °C at the time of Qtz II crystallization. Fluid pressure estimates show an oscillation in pore pressure comprised between 160 and 10 MPa during the fault activity stages. Our results suggest significant variability in the overall physical conditions during the fault deformation history, possibly reflecting the interaction of several batches of compositionally similar fluids ingressing the dilatant fault zone at different stages of its evolution, each with specific T and P conditions. Initial, fluid-mediated embrittlement of the faulted rock volume generated a diffuse network of joint and/or hybrid/shear fractures in the damage zone, whereas progressive strain localization led to more localized deformation within the fault core. Localization was guided by cyclically increasing fluid pressure and transient embrittlement of a system that was otherwise at overall ductile conditions. Our analysis implies that fluid overpressure at the brittle-ductile transition can play a key role in the initial embrittlment of the metamorphic basement and strain localization mechanisms.