bluuebunny/crossref_metadata_2025 huggingface dataset:
Development of Active Barrier Multilayer Films Based on Electrospun Antimicrobial Hot-Tack Food Waste Derived Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) and Cellulose Nanocrystal Interlayers
Authors: Figueroa-Lopez Kelly , Torres-Giner Sergio , Angulo Inmaculada , Pardo-Figuerez Maria , Escuin Jose , Bourbon Ana , Cabedo Luis , Nevo Yuval , Cerqueira Miguel , Lagaron Jose
Published: November 2020

Active multilayer films based on polyhydroxyalkanoates (PHAs) with and without high barrier coatings of cellulose nanocrystals (CNCs) were herein successfully developed. To this end, an electrospun antimicrobial hot-tack layer made of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) derived from cheese whey, a by-product from the dairy industry, was deposited on a previously manufactured blown film of commercial food contact PHA-based resin. A hybrid combination of oregano essential oil (OEO) and zinc oxide nanoparticles (ZnONPs) were incorporated during the electrospinning process into the PHBV nanofibers at 2.5 and 2.25 wt%, respectively, in order to provide antimicrobial properties. A barrier CNC coating was also applied by casting from an aqueous solution of nanocellulose at 2 wt% using a rod at 1m/min. The whole multilayer structure was thereafter assembled in a pilot roll-to-roll laminating system, where the blown PHA-based film was located as the outer layers while the electrospun antimicrobial hot-tack PHBV layer and the barrier CNC coating were placed as interlayers. The resultant multilayer films, having a final thickness in the 130–150 µm range, were characterized to ascertain their potential in biodegradable food packaging. The multilayers showed contact transparency, interlayer adhesion, improved barrier to water and limonene vapors, and intermediate mechanical performance. Moreover, the films presented high antimicrobial and antioxidant activities in both open and closed systems for up to 15 days. Finally, the food safety of the multilayers was assessed by migration and cytotoxicity tests, demonstrating that the films are safe to use in both alcoholic and acid food simulants and they are also not cytotoxic for Caco-2 cells.
Effect of Metallic or Non-Metallic Element Addition on Surface Topography and Mechanical Properties of CrN Coatings
Authors: Kuznetsova Tatyana , Lapitskaya Vasilina , Khabarava Anastasiya , Chizhik Sergei , Warcholinski Bogdan , Gilewicz Adam , Kuprin Aleksander , Aizikovich Sergei , Mitrin Boris
Published: November 2020

Alteration of the phase composition of a coating and/or its surface topography can be achieved by changing the deposition technology and/or introducing additional elements into the coating. Investigation of the effect of the composition of CrN-based coatings (including AlCrN and CrON) on the microparticle height and volume, as well as the construction of correlations between the friction coefficient at the microscale and the geometry of microparticles, are the goals of this study. We use atomic force microscopy (AFM), which is the most effective method of investigation with nanometer resolution. By revealing the morphology, AFM allows one to determine the diameter of the particles, their heights and volumes and to identify different phases in the studied area by contrasted properties. The evaluation of the distribution of mechanical properties (modulus of elasticity E and microhardness H) on the surfaces of multiphase coatings with microparticles is carried out by using the nanoindentation method. It is found that the roughness decreases with an increase in the Al concentration in AlCrN. For the CrON coatings, the opposite effect is observed. Similar conclusions are valid for the size of the microparticles and their height for both types of coating.
Cultural Differences in Stress-Related Psychological, Nutrition, Physical Activity and Oral Health Factors of Professors
Authors: Redondo-Flórez Laura , Fernández-Lucas Jesús , Clemente-Suárez Vicente Javier
Published: November 2020

With the aim to explore cultural differences in stress-related psychological, nutrition, physical activity, and oral health factors between Spanish and Latin American professors, we analysed stress-related factors in 598 professors (39.9% male, 60.1% female, 41.3 ± 9.8 years) by a collection of questionnaires, which involved psychological, nutritional, physical activity and oral health items. Results showed how Spanish professors presented significantly (p ≤ 0.05) higher scores than Latin American professors in perceived stress (Spanish: 21.40 ± 4.32 vs. Latin American: 20.36 ± 4.31), teaching stress (Spanish: 6.59 ± 2.28 vs. Latin American: 6.00 ± 2.99) and neuroticism (Spanish: 5.40 ± 2.10 vs. Latin American: 4.58 ± 1.72). Spanish professors also showed healthier nutritional and physical activity habits than their Latin American counterparts, presenting higher consumption of milk products and a higher numbers of meals per day, greater weekly meat and fish consumption and higher weekly resistance training, as well as less eating between hours and snacking consumption. Nevertheless, Spanish professors brushed their teeth less and showed a higher smoking habit than Latin American professors. We concluded that there were cultural differences between Spanish and Latin American professors. In the present research, Spanish professors showed significantly higher burnout levels, teaching stress, perceived stress, and neuroticism than Latin American professors, and several differences were also found around health behaviours. These differences in perceived stress, teaching stress and burnout syndrome may be due to the habituation process of Latin American professors, and probably are associated with a higher stressful and demanding socio-cultural context.
On the Question of Zwitterionic Intermediates in the [3+2] Cycloaddition Reactions: A Critical Review
Authors: Jasiński Radomir , Dresler Ewa
Published: November 2020

New discoveries require a fundamental revision of the view on the mechanism of the 32CAreaction (according to the older nomenclature defined as 1,3-dipolar cycloaddition reactions). The view of the one-step, “concerted” mechanism of such processes developed in the 20-century is very popular today, both in academic literature and among organic chemists who do not specialize in such transformations. Meanwhile, more and more reports bring examples of reactions that clearly cannot be treated as processes without intermediates. However, these examples are documented very differently. In addition to comprehensive studies using many complementary research techniques, there are also reports in which the presence of intermediates in the cycloaddition environment is postulated on the basis of very unreliable premises. This review is an attempt at a critical analysis and systematization of data in the presented area.
Anogenital-Associated Papillomaviruses in Animals: Focusing on Bos taurus Papillomaviruses
Authors: Yamashita-Kawanishi Nanako , Haga Takeshi
Published: November 2020

In contrast to the diverse studies on human papillomaviruses (HPVs), information on animal PVs associated with anogenital lesions is limited. In the animal kingdom, papillomas occur more commonly in cattle than in any other animals, and diverse types of Bos taurus papillomaviruses (BPVs) exist, including the very recently discovered BPV type 29 (BPV29). From this perspective, we will review previous studies describing PV types associated with anogenitals in animals, with a focus on BPVs. To date, two classical BPV types, classified into Deltapapillomavirus (BPV1 and BPV2) and Dyokappapapillomavirus (BPV22), and two novel Xipapillomaviruses (BPV28 and BPV29) have been identified from anogenital lesions and tissues of the domestic cow. Due to the limited reports describing anogenital-associated PVs in animals, the relationships between their phylogenetic and pathogenetic properties are still undiscovered. Animal studies are valuable not only for the veterinary field but also for human medicine, as animal diseases have been shown to mimic human diseases. Studies of anogenital-associated PVs in animals have a positive impact on various research fields.
Mycoplasma bovis Infections: Occurrence, Pathogenesis, Diagnosis and Control, Including Prevention and Therapy
Authors: Dudek Katarzyna , Szacawa Ewelina
Published: November 2020

Mycoplasma bovis (M. bovis) is an etiological agent of bronchopneumonia, mastitis, arthritis, otitis, keratoconjunctivitis, meningitis, endocarditis and other disorders in cattle [...]
Theoretical Effect of Coma and Spherical Aberrations Translation on Refractive Error and Higher Order Aberrations
Authors: Arba-Mosquera Samuel , Verma Shwetabh , Awwad Shady T.
Published: November 2020

(1) Background: The purpose of the study is to present a simple theoretical account of the effect of translation of coma and spherical aberrations (SA) on refractive error and higher order aberrations. (2) Methods: A computer software algorithm was implemented based on previously published methods. The effect of translation (0 to +1 mm) was analyzed for SA (0 to +2 µm) and coma (0 to +2 µm) for a circular pupil of 6 mm, without any rotation or scaling effect. The relationship amongst Zernike representations of various aberrations was analyzed under the influence of translation. (3) Results: The translation of +0.40 µm of SA (C[4,0]) by +0.25 mm with a pupil diameter of 6mm resulted in induction of tilt (C[1,1]), −0.03D defocus (C[2,0]), +0.03D astigmatism (C[2,2]) and +0.21 µm coma (C[3,1]). The translation of +0.4 µm of coma (C[3,1]) by +0.25 mm with a pupil diameter of 6 mm resulted in induction of tilt (C[1,1]), −0.13D defocus (C[2,0]) and +0.13D astigmatism (C[2,2]). A theoretical quantitative relationship between SA, coma, astigmatism and defocus is presented under the influence of translation. (4) Conclusion: The results can act as a guide for the clinician, in order to readily assess theoretical impact of wavefront map translation from pupil center to the visual axis. The resultant refractive coupling has to be taken into consideration especially when treating eyes with an abnormal corneal shape and/or large pupil center to corneal vertex chord.
Antiviral, Antioxidant, and Antihemolytic Effect of Annona muricata L. Leaves Extracts
Authors: Balderrama-Carmona Ana Paola , Silva-Beltrán Norma Patricia , Gálvez-Ruiz Juan-Carlos , Ruíz-Cruz Saúl , Chaidez-Quiroz Cristóbal , Morán-Palacio Edgar Felipe
Published: November 2020

Annona muricata L. is a tropical tree that is used in traditional medicine around the world. The high content of flavonoid, alkaloid, acetogenin, phenolic and lipophilic compounds of this tropical tree forms the basis of its traditional medical uses. Our objective was to study soursop leaf extracts to support their use as antiviral therapies and investigate their protective effects against oxidative damage. The aqueous extract (AE) and acidified ethanolic extract (AEE) of soursop leaves were characterized by ultra performance liquid chromatography (UPLC), and their effects on human erythrocytes and in vitro antioxidant capacity, as evaluated by 2,2-diphenyl-1-picrylhydrazyl (DPPH) and 2,2′-azino-bis (3-ethylbenzothiazoline-6-sulfonic acid (ABTS) assays, were investigated. The antiviral effects were evaluated using a bacteriophage surrogate. AEE showed the highest phenolic content, with rutin as the predominant compound. This extract showed higher values in the DPPH and ABTS assays, with 23.61 ± 0.42 and 24.91 ± 0.16 mmol of Trolox equivalent per gram, respectively. Inhibition of hemolysis was 34% and 51% for AE and AEE, respectively. AEE was selected for the antiviral study because of its higher antioxidant activity. The viral reduction ranged from 5–6 log10 plaque-forming units/volume (PFU) at contact times of 15–360 min. Soursop leaves have a positive effect on reducing oxidative stress in human erythrocytes and viral infections.
Understanding Physiology and Impacts of High Temperature Stress on the Progamic Phase of Coconut (Cocos nucifera L.)
Authors: Hebbar K. B. , Neethu P. , Sukumar P. Abhin , Sujithra M. , Santhosh Arya , Ramesh S. V. , Niral V. , Hareesh G. S. , Nameer Paingamadathil Ommer , Prasad P. V. V.
Published: November 2020

The reproductive phase of coconut is extremely sensitive to high temperature, manifesting as button (female flower) shedding and poor nut set. The progamic phase, which elapses from pollination to fertilization, is one of the most critical phases during the sexual reproduction processes in annuals and fruit trees and is extremely vulnerable to high temperature. Hence, we investigated the progamic phase of the tall coconut cultivar West Coast Tall (WCT) and the effect of high temperature on the phase under both in vivo and in vitro conditions. Coconut has a long pistil and its length was found to be 18.2 ± 4.9 mm in WCT. Pollen germination on stigma occurred one day after pollination and the pollen tube traversed through the pistil and reached micropyle of ovule four days after pollination at 29 °C. However, high temperature (Tmax > 33 °C), both under in vivo and in vitro conditions, significantly reduced pollen tube growth through the pistil, suggesting its inability to reach the ovule on time to effect fertilization. High temperature also advanced nectar secretion and stigma receptivity and the receptive stigma was dry without nectar, rendering it unappealing to insect pollinators. Thus, both poor pollination and the inability of pollen tube to reach the ovule on time to effect fertilization could be the cause of poor nut set in the coconut variety WCT under high temperature. However, it was encouraging to note that the pollen tube growth was less vulnerable to elevated temperature under high humidity, suggesting that climate change effect on coconut in coastal regions with high humidity might be less severe.
The Influence of Nitrogen Application Level on Eating Quality of the Two Indica-Japonica Hybrid Rice Cultivars
Authors: Zhang Xincheng , Fu Liangbo , Tu Yishan , Zhao Huifang , Kuang Liuhui , Zhang Guoping
Published: November 2020

Indica-japonica hybrid rice cultivars show great yield potential but poor eating quality and require more nitrogen (N) input relative to japonica rice. However, the effect of N levels on the eating quality of indica-japonica hybrid rice is little known. A field experiment was carried out to investigate the effects of four N levels on two indica-japonica hybrid rice cultivars (Yongyou12 and Yongyou17) differing in eating quality. The results showed that the contents of amylose chains and water-insoluble storage proteins, especially prolamin, increased largely under a high N level, leading to deterioration of the rice-eating quality, although a low N level (100 N kg/ha) had a less negative effect on the eating quality. Moreover, both of the indica-japonica hybrids had high ratios of inferior grains (IG), and the ratio of IG increased with the N level. Grain weight and the immature ratio of IG were reduced and increased with the N level, respectively, which are also factors for deterioration of the eating quality. The two cultivars differed greatly in the responses of eating quality to the N level, with Yongyou17 being more sensitive than Yongyou12. The current results indicated that a high N level deteriorates the eating quality of indica-japonica hybrid rice mainly due to a large increase of IG.
Application of Monopotassium Dipropylene Glycoxide for Homopolymerization and Copolymerization of Monosubstituted Oxiranes: Characterization of Synthesized Macrodiols by MALDI-TOF Mass Spectrometry
Authors: Grobelny Zbigniew , Jurek-Suliga Justyna , Golba Sylwia
Published: November 2020

Monopotassium dipropylene glycoxide, activated by a 18-crown-6 cation complexing agent (K-DPG/L, where DPG (dipropylene glycol) is a mixture of isomers) was used as an effective initiator of the homopolymerization and copolymerization of several monosubstituted oxiranes, i.e., propylene oxide (PO), 1.2-butylene oxide (BO), and some glycidyl ethers such as allyl, isopropyl, phenyl, and benzyl ones (AGE, IPGE, PGE, and BGE, respectively). The copolymers are novel and can be prospectively used for the fabrication of new thermoplastic or crosslinked polyurethanes. All processes were carried out in homogeneous mild conditions, i.e., tetrahydrofuran solution at room temperature and normal pressure. They resulted in new unimodal macrodiols with Mn = Mcalc in the range of 1500–8300, low dispersity Mw/Mn = 1.08–1.18 and a chemical structure well defined by several techniques, i.e., MALDI-TOF, size exclusion chromatography (SEC), 13C NMR, and FTIR. Monopotassium salts of homopolyether-diols, i.e., PPO-diol, PBO-diol, and PAGE-diol, appeared to be useful macroinitiators for the preparation of new triblock copolyether-diols by polymerization of glycidyl ethers. In BO/BGE random copolymerization initiated with K-DPG/L, macromolecules of copolyether-diol were exclusively formed. Macromolecules of copolyether-diol accompanied by homopolyether PPO-diol were identified in the PO/PGE system. However, AGE and PGE reacted by giving random copolyether-diol as well as homopolymer-diols, i.e., PAGE-diol and PPGE-diol. Macromolecules of prepared copolyether-diols contain various numbers of mers deriving from comonomers; the kind of comonomer determines the composition of the product. Several prepared homopolyether-diols and copolyether-diols could be useful for the synthesis of new thermoplastic polyurethanes.
Development of a Weight-Drop Impact Testing Method for Dental Applications
Authors: Watanabe Satoru , Ishida Yoshiki , Miura Daisuke , Miyasaka Taira , Shinya Akikazu
Published: November 2020

For evaluating the impact strength of dental materials, the Izod test or Charpy test has been used, but specimen preparation for these tests is difficult due to the adjustment of a notch on them. By contrast, a weight-drop impact test does not require notched specimens. Therefore, it might be possible to measure the impact strength more accurately than conventional methods. This study aimed to establish appropriate conditions for applying the weight-drop impact test on small specimens of acrylic resin. To determine the most reliable impact fracture energy of acrylic resins, different diameters and thicknesses of PMMA resin specimens, diameters and weights of the striker, and diameters of the supporting jig were compared. For all specimen thicknesses, when the striker diameter was 6–10 mm, the impact fracture energy was constant when the inner diameter of the specimen-supporting jig was 8–10 mm. In addition, the measured E50% value was mostly equal to the median value of the impact fracture energy. Thus, for the weight-drop impact test, this method was effective for material testing of small specimens, by clearly specifying the test conditions, such as the thickness of disc-shaped specimens, the diameter of the striker, and the inner diameter of the specimen-supporting jig.
Yerba Mate Extract in Microfibrillated Cellulose and Corn Starch Films as a Potential Wound Healing Bandage
Authors: Aliabadi Meysam , Chee Bor Shin , Matos Mailson , Cortese Yvonne J. , Nugent Michael J. D. , de Lima Tielidy A. M. , Magalhães Washington L. E. , de Lima Gabriel Goetten
Published: November 2020

Microfibrillated cellulose films have been gathering considerable attention due to their high mechanical properties and cheap cost. Additionally, it is possible to include compounds within the fibrillated structure in order to confer desirable properties. Ilex paraguariensis A. St.-Hil, yerba mate leaf extract has been reported to possess a high quantity of caffeoylquinic acids that may be beneficial for other applications instead of its conventional use as a hot beverage. Therefore, we investigate the effect of blending yerba mate extract during and after defibrillation of Eucalyptus sp. bleached kraft paper by ultrafine grinding. Blending the extract during defibrillation increased the mechanical and thermal properties, besides being able to use the whole extract. Afterwards, this material was also investigated with high content loadings of starch and glycerine. The results present that yerba mate extract increases film resistance, and the defibrillated cellulose is able to protect the bioactive compounds from the extract. Additionally, the films present antibacterial activity against two known pathogens S. aureus and E. coli, with high antioxidant activity and increased cell proliferation. This was attributed to the bioactive compounds that presented faster in vitro wound healing, suggesting that microfibrillated cellulose (MFC) films containing extract of yerba mate can be a potential alternative as wound healing bandages.
Innovative Incorporation of Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) as Hole Carrier Transport Layer and as Anode for Organic Solar Cells Performance Improvement
Authors: Hamui Leon , Sánchez-Vergara Maria Elena , Corona-Sánchez Ricardo , Jiménez-Sandoval Omar , Álvarez-Toledano Cecilio
Published: November 2020

In this work, we present a comparative study of benzoid poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) as electrode and as hole carrier transport layer (HTL) in the manufacture of organic photovoltaic devices using Fischer metal-carbene complexes. The performance of the different devices was evaluated for solar cell applications. Scanning electronic microscopy (SEM) and X-ray diffraction (XRD) were used to characterize the thin films that integrated the devices. A more ordered and crystallized active film microstructure is observed when using benzoid PEDOT:PSS as nucleation layer. The optical gap for both direct and indirect electronic transitions was evaluated from ultraviolet-visible spectroscopy data (UV-vis), as well as the absorption coefficient (α), and the values are in the range of 2.10–2.93 eV. Photovoltaic devices with conventional architecture, using two different chromium carbenes as active layers, were manufactured, and their electrical behavior was studied. The devices were irradiated with different wavelengths between the infrared and ultraviolet regions of the electromagnetic spectrum. Using the PEDOT:PSS film as hole carrier transport layer (HTL) decreases the slope on the ohmic and space charge limited current (SCLC) regions and eliminates the trap-charge limited current (T-CLC) mechanism. Furthermore, a saturation current of ~1.95 × 10−10 A and higher current values ~1.75 × 10−2 A at 4 V, ~4 orders in magnitude larger were observed. The PEDOT:PSS films as HTL in the devices reduced the injection barrier, thus showing a better performance than as anodes in this type of organic solar cells.
A Review of the Use of GPEs in Zinc-Based Batteries. A Step Closer to Wearable Electronic Gadgets and Smart Textiles
Authors: Lorca Sebastián , Santos Florencio , Fernández Romero Antonio J.
Published: November 2020

With the flourish of flexible and wearable electronics gadgets, the need for flexible power sources has become essential. The growth of this increasingly diverse range of devices boosted the necessity to develop materials for such flexible power sources such as secondary batteries, fuel cells, supercapacitors, sensors, dye-sensitized solar cells, etc. In that context, comprehensives studies on flexible conversion and energy storage devices have been released for other technologies such Li-ion standing out the importance of the research done lately in GPEs (gel polymer electrolytes) for energy conversion and storage. However, flexible zinc batteries have not received the attention they deserve within the flexible batteries field, which are destined to be one of the high rank players in the wearable devices future market. This review presents an extensive overview of the most notable or prominent gel polymeric materials, including biobased polymers, and zinc chemistries as well as its practical or functional implementation in flexible wearable devices. The ultimate aim is to highlight zinc-based batteries as power sources to fill a segment of the world flexible batteries future market.
Mode-Independent and Mode-Interactive Failure Criteria for Unidirectional Composites Based on Strain Energy Density
Authors: Li Nian , Ju Cheng
Published: November 2020

The strain energy released plays a crucial role in generating macroscopic failure in unidirectional (UD) composites. This paper proposes two new strain energy-based failure criteria, regarding fiber-dominated and matrix-dominated failure mode as independent and interactive, respectively. The failure expression is formulated based on rigorous mathematical deducing, accompanied by physical interpretation. Based on the lack of experimentally feasible multi-axial strengths, a predefined assumption of infinite strength under bi-axial and tri-axial compressive stress provides the possibility for determining all coefficients only by using conventional uniaxial strengths. The failure envelopes predicted by the proposed criteria have been validated against experimental results under biaxial, off-axis and tri-axial loading cases. A better agreement with physical reality was achieved by the failure mode-interactive criterion, suggesting a wide range of applicability.
Development of “New” Bread and Cheese
Authors: Wei Wei , Yano Hiroyuki
Published: November 2020

Bread and cheese have been a popular combination since early times. Indeed, the history of bread dates back to 8000 BC and that of cheese to 7200 BC. However, new types of breads and cheeses are increasingly popular for several reasons, such as allergies, lifestyles, economy and religion. The major challenge is that food manufacturers are offering new products most of which are not welcomed by consumers. Therefore, recently, researchers have placed importance on their relationships with consumers to boost the success of new products. This short review summarizes the backgrounds of recent trends, processes, and principles to manufacture new bread and cheese products, and discusses future perspectives. The development of additive-free, gluten-free rice bread we have recently done from basic research to commercialization of the products is highly focused in this review. Additionally, ongoing studies on plant-based cheeses are introduced from material selection to suggest future outlooks.
Synthesis of Dietetic Structured Lipids from Spent Coffee Grounds Crude Oil Catalyzed by Commercial Immobilized Lipases and Immobilized Rhizopus oryzae Lipase on Biochar and Hybrid Support
Authors: Mota Danyelle A. , Santos Jefferson C. B. , Faria Diana , Lima Álvaro S. , Krause Laiza C. , Soares Cleide M. F. , Ferreira-Dias Suzana
Published: November 2020

The aim of this study was the valorization of coffee industry residues, namely spent coffee grounds (SCG) as a source of oil, and silverskin (CS) as a source of both oil and biomass, under the concept of the circular economy. Therefore, crude oil from SCG was used to produce low-calorie structured lipids (SL) for food and pharmaceutical industries, and CS to produce biochar by pyrolysis for biotechnological uses. SL were obtained by acidolysis with caprylic or capric acid, or interesterification with ethyl caprylate or ethyl caprate, in solvent-free media, catalyzed by immobilized sn-1,3 regioselective lipases. Silverskin biochar (BIO) was directly used as enzyme carrier or to produce hybrid organic-silica (HB) supports for enzyme immobilization. Rhizopus oryzae lipase (ROL) immobilized on Amberlite (AMB), silica (SIL), BIO or HB, and the commercial immobilized Thermomyces lanuginosus (Lipozyme TL IM) and Rhizomucor miehei (Lipozyme RM IM) lipases were tested. Lipozyme RM IM showed better results in SL production than Lipozyme TLIM or ROL on BIO, SIL or HB. About 90% triacylglycerol conversion was attained after 7 h acidolysis or interesterification. Lipozyme RM IM was more stable in interesterification (80% and 65% activity with ethyl caprylate or ethyl caprate) than in acidolysis (first-order decay) after 10 reuses.
A Robust Method for the Estimation of Kinetic Parameters for Systems Including Slow and Rapid Reactions—From Differential-Algebraic Model to Differential Model
Authors: Salmi Tapio , Tirronen Esko , Wärnå Johan , Mikkola Jyri-Pekka , Murzin Dmitry , Eta Valerie
Published: November 2020

Reliable estimation of kinetic parameters in chemical systems comprising both slow and rapid reaction steps and rapidly reacting intermediate species is a difficult differential-algebraic problem. Consequently, any conventional approach easily leads to serious convergence and stability problems during the parameter estimation. A robust method is proposed to surmount this dilemma: the system of ordinary differential equations and nonlinear algebraic equations is converted to ordinary differential equations, which are solved in-situ during the parameter estimation. The approach was illustrated with two generic examples and an example from green chemistry: synthesis of dimethyl carbonate from carbon dioxide and methanol.
Thermal Stress and Deformation of Hollow Paddle-Shaft Components with Internal High Temperature Molten Salt Flow
Authors: Rajeh Taha , Al-Kbodi Basher Hassan , Zhang Houlei
Published: November 2020

Excessive thermal stress and deformation are important reasons causing disservice of high temperature heat exchangers. This paper presents thermal stress and expansion analysis of single-leaf type hollow paddle-shaft components with internal high temperature molten salt flow based on three-dimensional numerical simulations. The results show that the hollow paddles enhance the heat transfer and decrease the maximum thermal stress simultaneously with the expense of a much higher pressure drop than that of solid paddles. The cumulative von Mises stress distribution curve shows that the stress distribution of the component with hollow paddles is more uniform than that with solid paddles. The radial and axial deformations do not differ much for the components with hollow and solid paddles. A larger volume of the fluid space in the hollow paddles leads to stronger heat transfer, smaller maximum thermal stress, and more uniform stress distribution. The effects of the paddle height, the diameter and number of flow holes, the molten salt flow rate, and the material-side heat transfer coefficient are identified. The advantages of hollow paddle designs in both heat transfer and thermal stress (local and overall) performance are revealed. The work in this study can provide a reference for the design and optimization of hollow paddle heat exchangers with high temperature molten salt as working fluid.
On Being Consumed: The Martyred Body as a Site of Divine—Human Encounter in the Letters of Ignatius of Antioch
Authors: Smit Peter-Ben
Published: November 2020

The manner in which humans and the divine are brought into communion with each other, a key aspect of many religious traditions, is frequently, if not always, material (or sacramental) in character. Meals and food play an important role in this; such meals can include the consumption of the deity (theophagy), as well as the consumption of the human being by the deity. This paper takes its cue from the discussion of constructions of divine–human communion and explores this subject in the letters of Ignatius of Antioch (early second century CE). It shows how in the literary heritage of this bishop, the body as the physical site of martyrdom is of key importance, in particular due to its consumption in the Roman arena. This martyrdom is the way in which Ignatius hopes to enter into perfect communion with the divine. The body thus becomes, in its annihilation, the instrument through which divine–human communion is established. As this all relates to a case of martyrdom, Ignatius’ ideas about the body are also subversive in character: the punishment of his body is, through his theological imagination, transformed into a means of achieving Ignatius’ goal in life: attaining to God.
Comparison of Surface Solar Irradiance from Ground Observations and Satellite Data (1990–2016) over a Complex Orography Region (Piedmont—Northwest Italy)
Authors: Manara Veronica , Stocco Elia , Brunetti Michele , Diolaiuti Guglielmina Adele , Fugazza Davide , Pfeifroth Uwe , Senese Antonella , Trentmann Jörg , Maugeri Maurizio
Published: November 2020

Climate Monitoring Satellite Application Facility (CM SAF) surface solar irradiance (SSI) products were compared with ground-based observations over the Piedmont region (north-western Italy) for the period 1990–2016. These products were SARAH-2.1 (Surface Solar Radiation DataSet—Heliosat version 2.1) and CLARA-A2 (Cloud, Albedo and Surface Radiation dataset version A2). The aim was to contribute to the discussion on the representativeness of satellite SSI data including a focus on high-elevation areas. The comparison between SSI averages shows that for low OCI (orographic complexity index) stations, satellite series have higher values than corresponding ground-based observations, whereas for high OCI stations, SSI values for satellite records are mainly lower than for ground stations. The comparison between SSI anomalies highlights that satellite records have an excellent performance in capturing SSI day-to-day variability of ground-based low OCI stations. In contrast, for high OCI stations, the agreement is much lower, due to the higher uncertainty in both satellite and ground-based records. Finally, if the temporal trends are considered, average low-elevation ground-based SSI observations show a positive trend, whereas satellite records do not highlight significant trends. Focusing on high-elevation stations, the observed trends for ground-based and satellite records are more similar with the only exception of summer. This divergence seems to be due to the relevant role of atmospheric aerosols on SSI trends.
Surface Rupture Kinematics and Coseismic Slip Distribution during the 2019 Mw7.1 Ridgecrest, California Earthquake Sequence Revealed by SAR and Optical Images
Authors: Li Chenglong , Zhang Guohong , Shan Xinjian , Zhao Dezheng , Li Yanchuan , Huang Zicheng , Jia Rui , Li Jin , Nie Jing
Published: November 2020

The 2019 Ridgecrest, California earthquake sequence ruptured along a complex fault system and triggered seismic and aseismic slips on intersecting faults. To characterize the surface rupture kinematics and fault slip distribution, we used optical images and Interferometric Synthetic Aperture Radar (InSAR) observations to reconstruct the displacement caused by the earthquake sequence. We further calculated curl and divergence from the north-south and east-west components, to effectively identify the surface rupture traces. The results show that the major seismogenic fault had a length of ~55 km and strike of 320° and consisted of five secondary faults. On the basis of the determined multiple-fault geometries, we inverted the coseismic slip distributions by InSAR measurements, which indicates that the Mw7.1 mainshock was dominated by the right-lateral strike-slip (maximum strike-slip of ~5.8 m at the depth of ~7.5 km), with a small dip-slip component (peaking at ~1.8 m) on an east-dipping fault. The Mw6.4 foreshock was dominated by the left-lateral strike-slip on a north-dipping fault. These earthquakes triggered obvious aseismic creep along the Garlock fault (117.3° W–117.5° W). These results are consistent with the rupture process of the earthquake sequence, which featured a complicated cascading rupture rather than a single continuous rupture front propagating along multiple faults.
Landscape-Scale Crop Lodging Assessment across Iowa and Illinois Using Synthetic Aperture Radar (SAR) Images
Authors: Ajadi Olaniyi A. , Liao Heming , Jaacks Jason , Delos Santos Alfredo , Kumpatla Siva P. , Patel Rinkal , Swatantran Anu
Published: November 2020

Crop lodging, the tilting of stems from their natural upright position, usually occurs after a heavy storm event. Since lodging of a crop seriously affects its yield, rapid assessment of crop lodging is valuable for farmers, policymakers, agronomists, insurance companies, and relief workers. Synthetic Aperture Radar (SAR) sensors have been recognized as valuable data sources for mapping lodging extent because of their good penetrating power and high-resolution remote sensing ability. Compared to other sources, SAR’s weather and illumination independence and large area coverage at fine spatial resolution (3 m to 20 m) support frequent and detailed observations. Because of these advantages, SAR has the potential in supporting near real-time monitoring of lodging in fields when combined with automated image processing. In this study, a method based on change detection using modified Hidden Markov Random Field (HMRF) and Sentinel-1A data were utilized to identify lodging and map its extent. Results obtained have shown that when lodging occurs, the VH polarization’s backscatter (σVH) increases between the pre-lodging event image and the post-lodging event image. The increase in σVH is due to the increase in volume scattering and vegetation-soil double bounce scattering resulting from the structural changes in the crop canopy. Using Sentinel-1A images and applying our proposed approach across several fields in Iowa and Illinois, we mapped the extent of the 2020 Derecho (wind storm) lodging disaster. In addition, we separated lodged regions into severely and moderately lodged areas. We estimated that approximately 2.56 million acres of corn and 1.27 million acres of soybean were lodged. Further analysis also showed the separation between un-lodged (healthy) fields and lodged fields. The observations in this study can guide future use of SAR-based information for operational crop lodging assessment.
A Fast Three-Dimensional Convolutional Neural Network-Based Spatiotemporal Fusion Method (STF3DCNN) Using a Spatial-Temporal-Spectral Dataset
Authors: Peng Mingyuan , Zhang Lifu , Sun Xuejian , Cen Yi , Zhao Xiaoyang
Published: November 2020

With the growing development of remote sensors, huge volumes of remote sensing data are being utilized in related applications, bringing new challenges to the efficiency and capability of processing huge datasets. Spatiotemporal remote sensing data fusion can restore high spatial and high temporal resolution remote sensing data from multiple remote sensing datasets. However, the current methods require long computing times and are of low efficiency, especially the newly proposed deep learning-based methods. Here, we propose a fast three-dimensional convolutional neural network-based spatiotemporal fusion method (STF3DCNN) using a spatial-temporal-spectral dataset. This method is able to fuse low-spatial high-temporal resolution data (HTLS) and high-spatial low-temporal resolution data (HSLT) in a four-dimensional spatial-temporal-spectral dataset with increasing efficiency, while simultaneously ensuring accuracy. The method was tested using three datasets, and discussions of the network parameters were conducted. In addition, this method was compared with commonly used spatiotemporal fusion methods to verify our conclusion.
Monitoring Large-Scale Inland Water Dynamics by Fusing Sentinel-1 SAR and Sentinel-3 Altimetry Data and by Analyzing Causal Effects of Snowmelt
Authors: Tsai Ya-Lun S. , Klein Igor , Dietz Andreas , Oppelt Natascha
Published: November 2020

The warming climate is threatening to alter inland water resources on a global scale. Within all waterbody types, lake and river systems are vital not only for natural ecosystems but, also, for human society. Snowmelt phenology is also altered by global warming, and snowmelt is the primary water supply source for many river and lake systems around the globe. Hence, (1) monitoring snowmelt conditions, (2) tracking the dynamics of snowmelt-influenced river and lake systems, and (3) quantifying the causal effect of snowmelt conditions on these waterbodies are critical to understand the cryo-hydrosphere interactions under climate change. Previous studies utilized in-situ or multispectral sensors to track either the surface areas or water levels of waterbodies, which are constrained to small-scale regions and limited by cloud cover, respectively. On the contrary, in the present study, we employed the latest Sentinel-1 synthetic aperture radar (SAR) and Sentinel-3 altimetry data to grant a high-resolution, cloud-free, and illumination-independent comprehensive inland water dynamics monitoring strategy. Moreover, in contrast to previous studies utilizing in-house algorithms, we employed freely available cloud-based services to ensure a broad applicability with high efficiency. Based on altimetry and SAR data, the water level and the water-covered extent (WCE) (surface area of lakes and the flooded area of rivers) can be successfully measured. Furthermore, by fusing the water level and surface area information, for Lake Urmia, we can estimate the hypsometry and derive the water volume change. Additionally, for the Brahmaputra River, the variations of both the water level and the flooded area can be tracked. Last, but not least, together with the wet snow cover extent (WSCE) mapped with SAR imagery, we can analyze the influence of snowmelt conditions on water resource variations. The distributed lag model (DLM) initially developed in the econometrics discipline was employed, and the lagged causal effect of snowmelt conditions on inland water resources was eventually assessed.
Maximal Walking Distance in Persons with a Lower Limb Amputation
Authors: Hofstad Cheriel J. , Bongers Kim T.J. , Didden Mark , van Ee René F. , Keijsers Noël L.W.
Published: November 2020

The distance one can walk at a time could be considered an important functional outcome in people with a lower limb amputation. In clinical practice, walking distance in daily life is based on self-report (SIGAM mobility grade (Special Interest Group in Amputee Medicine)), which is known to overestimate physical activity. The aim of this study was to assess the number of consecutive steps and walking bouts in persons with a lower limb amputation, using an accelerometer sensor. The number of consecutive steps was related to their SIGAM mobility grade and to the consecutive steps of age-matched controls in daily life. Twenty subjects with a lower limb amputation and ten age-matched controls participated in the experiment for two consecutive days, in their own environment. Maximal number of consecutive steps and walking bouts were obtained by two accelerometers in the left and right trouser pocket, and one accelerometer on the sternum. In addition, the SIGAM mobility grade was determined and the 10 m walking test (10 MWT) was performed. The maximal number of consecutive steps and walking bouts were significantly smaller in persons with a lower limb amputation, compared to the control group (p < 0.001). Only 4 of the 20 persons with a lower limb amputation had a maximal number of consecutive steps in the range of the control group. Although the maximal covered distance was moderately correlated with the SIGAM mobility grade in participants with an amputation (r = 0.61), for 6 of them, the SIGAM mobility grade did not match with the maximal covered distance. The current study indicated that mobility was highly affected in most persons with an amputation and that the SIGAM mobility grade did not reflect what persons with a lower limb amputation actually do in daily life. Therefore, objective assessment of the maximal number of consecutive steps of maximal covered distance is recommended for clinical treatment.
Managing Big Data for Addressing Research Questions in a Collaborative Project on Automated Driving Impact Assessment
Authors: Bellotti Francesco , Osman Nisrine , Arnold Eduardo H. , Mozaffari Sajjad , Innamaa Satu , Louw Tyron , Torrao Guilhermina , Weber Hendrik , Hiller Johannes , De Gloria Alessandro , Dianati Mehrdad , Berta Riccardo
Published: November 2020

While extracting meaningful information from big data is getting relevance, literature lacks information on how to handle sensitive data by different project partners in order to collectively answer research questions (RQs), especially on impact assessment of new automated driving technologies. This paper presents the application of an established reference piloting methodology and the consequent development of a coherent, robust workflow. Key challenges include ensuring methodological soundness and data validity while protecting partners’ intellectual property. The authors draw on their experiences in a 34-partner project aimed at assessing the impact of advanced automated driving functions, across 10 European countries. In the first step of the workflow, we captured the quantitative requirements of each RQ in terms of the relevant data needed from the tests. Most of the data come from vehicular sensors, but subjective data from questionnaires are processed as well. Next, we set up a data management process involving several partners (vehicle manufacturers, research institutions, suppliers and developers), with different perspectives and requirements. Finally, we deployed the system so that it is fully integrated within the project big data toolchain and usable by all the partners. Based on our experience, we highlight the importance of the reference methodology to theoretically inform and coherently manage all the steps of the project and the need for effective and efficient tools, in order to support the everyday work of all the involved research teams, from vehicle manufacturers to data analysts.
Continual Learning Strategy in One-Stage Object Detection Framework Based on Experience Replay for Autonomous Driving Vehicle
Authors: Shieh Jeng-Lun , Haq Qazi Mazhar ul , Haq Muhamad Amirul , Karam Said , Chondro Peter , Gao De-Qin , Ruan Shanq-Jang
Published: November 2020

Object detection is an important aspect for autonomous driving vehicles (ADV), which may comprise of a machine learning model that detects a range of classes. As the deployment of ADV widens globally, the variety of objects to be detected may increase beyond the designated range of classes. Continual learning for object detection essentially ensure a robust adaptation of a model to detect additional classes on the fly. This study proposes a novel continual learning method for object detection that learns new object class(es) along with cumulative memory of classes from prior learning rounds to avoid any catastrophic forgetting. The results of PASCAL VOC 2007 have suggested that the proposed ER method obtains 4.3% of mAP drop compared against the all-classes learning, which is the lowest amongst other prior arts.
Electrically Transduced Gas Sensors Based on Semiconducting Metal Oxide Nanowires
Authors: Wang Ying , Duan Li , Deng Zhen , Liao Jianhui
Published: November 2020

Semiconducting metal oxide-based nanowires (SMO-NWs) for gas sensors have been extensively studied for their extraordinary surface-to-volume ratio, high chemical and thermal stabilities, high sensitivity, and unique electronic, photonic and mechanical properties. In addition to improving the sensor response, vast developments have recently focused on the fundamental sensing mechanism, low power consumption, as well as novel applications. Herein, this review provides a state-of-art overview of electrically transduced gas sensors based on SMO-NWs. We first discuss the advanced synthesis and assembly techniques for high-quality SMO-NWs, the detailed sensor architectures, as well as the important gas-sensing performance. Relationships between the NWs structure and gas sensing performance are established by understanding general sensitization models related to size and shape, crystal defect, doped and loaded additive, and contact parameters. Moreover, major strategies for low-power gas sensors are proposed, including integrating NWs into microhotplates, self-heating operation, and designing room-temperature gas sensors. Emerging application areas of SMO-NWs-based gas sensors in disease diagnosis, environmental engineering, safety and security, flexible and wearable technology have also been studied. In the end, some insights into new challenges and future prospects for commercialization are highlighted.