bluuebunny/crossref_metadata_2025 huggingface dataset:
The Potential Effect of Changing Patient Position on Snoring: A Systematic Review
Authors: Moffa Antonio , Giorgi Lucrezia , Nardelli Domiziana , Iafrati Francesco , Iannella Giannicola , Magliulo Giuseppe , Baptista Peter , Vicini Claudio , Casale Manuele
Published: July 2024

Approximately 45% of adults snore occasionally, and 25% snore regularly, with a higher prevalence in men and an increase among postmenopausal women due to hormonal changes. Snoring is a health concern linked to vascular disease and decreased quality of life for both snorers and their bed partners. Effective snoring treatment, which aims to reduce or eliminate the sound, is challenging and depends on factors like age, comorbidities, disease severity, and anatomical features. This review aims to provide a systematic overview of the current literature on the effects of positional therapy (PT) on snoring. Various devices facilitate PT, including anti-snoring pillows and vibration alarms. PT devices maintain head and neck alignment to keep airways open, while head of bed elevation (HOBE) solutions reduce upper airway collapses by elevating the head and trunk. Studies show that PT and HOBE reduce snoring by increasing airway cross-sectional area and decreasing closing pressure. Despite their benefits, these non-surgical treatments have limitations, such as discomfort in certain sleeping positions and intolerance to prolonged head elevation. While reducing snoring intensity is critical for health reasons, further comparative studies between the different devices are needed to enhance snoring management.
Evolving Management of Breast Cancer in the Era of Predictive Biomarkers and Precision Medicine
Authors: Afzal Muhammad Zubair , Vahdat Linda T.
Published: July 2024

Breast cancer is the most common cancer among women in the world as well as in the United States. Molecular and histological differentiation have helped clinicians optimize treatments with various therapeutics, including hormonal therapy, chemotherapy, immunotherapy, and radiation therapy. Recently, immunotherapy has become the standard of care in locally advanced triple-negative breast cancer and an option across molecular subtypes for tumors with a high tumor mutation burden. Despite the advancements in personalized medicine directing the management of localized and advanced breast cancers, the emergence of resistance to these therapies is the leading cause of death among breast cancer patients. Therefore, there is a critical need to identify and validate predictive biomarkers to direct treatment selection, identify potential responders, and detect emerging resistance to standard therapies. Areas of active scientific and clinical research include novel personalized and predictive biomarkers incorporating tumor microenvironment, tumor immune profiling, molecular characterization, and histopathological differentiation to predict response and the potential emergence of resistance.
“Will You Buy It If They Recommend It?” Exploring the Antecedents of Intention to Purchase Podcaster-Endorsed Items
Authors: Huang Yi-Ting , Gong An-Di
Published: July 2024

The diverse content of and ease of listening to podcasts have made podcasts popular, particularly during the COVID-19 pandemic. Advertisers have begun to recognize their marketing potential and are now hiring podcasters to recommend their products. This study sought to determine the factors influencing podcast commitment, parasocial interaction (PSI), and the intention to purchase podcaster-endorsed items. It was conducted in Taiwan with a sample size of 578 participants and an online questionnaire. Structural equation modeling and mediation analysis were applied to the collected data from the perspective of uses and gratifications theory. We found that podcast commitment is positively related to edutainment, storytelling transportation, and social engagement. Social engagement is positively related to PSI, while storytelling transportation has a negative relationship with PSI. Additionally, there is a strong positive correlation between podcast commitment and PSI and both factors positively influence the intention to purchase podcaster-endorsed items. PSI also significantly moderates the positive relationship between podcast commitment and the intent to buy podcaster-endorsed items.
Determinants of Digitalization in Unorganized Localized Neighborhood Retail Outlets in India
Authors: Bhattacharjee Biplab , Kumar Shubham , Verma Piyush , Maiti Moinak
Published: July 2024

The increase in digital disruptions and changing preferences of different stakeholders has led to digital adoption in all hierarchies of business ecosystem. This study focused on the identification of the determinants of digitalization in unorganized small, localized retail outlets (Kirana stores) of an emerging economy. A theoretical model was constructed with certain modifications based on technology adoption models such as Technology Acceptance Model (TAM) and Unified Theory of Acceptance and Use of Technology 2 (UTAUT2) to study the impact on business performance in general and as an effect of pandemic. A survey of 285 Unorganized Localized Retail Outlets Stores from different regions of India was used to validate this theoretical model, and structural equation modeling was then further employed. The findings underscore that cost, compatibility, perceived ease of use, and perceived usefulness significantly affect the intention to digitalize. By addressing the post-pandemic impact of digitalization within an unorganized sector in an emerging economy, this study adds to the scant literature that exists in this context.
Harnessing Soil Diversity: Innovative Strategies for Potato Blight Management in Central-Eastern Poland
Authors: Sawicka Barbara , Barbaś Piotr , Skiba Dominika , Noaema Ali Hulail , Pszczółkowski Piotr
Published: July 2024

Faced with increasing climate challenges, this pioneering study introduces groundbreaking approaches to ensure the resilience of potato crops in east-central Poland. Our research was aimed at developing an innovative, cost-effective system tailored to the diverse local conditions of this region. Conducted between 2018 and 2020, the study analyzed integrated and organic production systems across different soil types and potato varieties. The experiment was conducted using a randomized block design with three replications in two locations. Integrated production systems involve the strategic use of mineral fertilization and chemical protection to optimize crop growth and health, whereas organic production systems rely solely on natural inputs and biological pest control methods. Integrated practices, enhanced by mineral fertilization and chemical protection, notably delayed the onset of late blight by 16 days and extended the critical infection period by 17% compared to their organic counterparts. Remarkably, the integrated systems resulted in a 49% increase in total production and a 52% increase in commercial yields, demonstrating their effectiveness in enhancing crop resilience. Different potato varieties exhibit varied responses to cultivation systems, influencing both yield and disease resistance. Further investigation into these varietal responses can help optimize cultivation practices, leading to improved efficiency and sustainability in potato farming. Location and soil conditions have a significant impact on potato yield and the spread of potato blight. Specific soil properties such as pH levels, organic matter content, soil texture (clay, silt, and sand composition), moisture retention capacity, and nutrient availability are crucial in determining potato productivity and disease dynamics. Further research into these soil properties and the adaptation of varieties to local conditions can contribute to increased productivity and stability in potato production. This study not only paves the way toward sustainable agriculture but also highlights the crucial role of soil diversity in shaping resilient farming practices. Potato producers in the eastern-central region of Poland should implement integrated production systems using mineral fertilization and chemical plant protection, adapted to local soil conditions and potato varieties. These practices can delay the appearance of late blight and increase the total and marketable potato yield. Further research on soil properties and variety adaptation may increase production stability and efficiency. Promoting soil diversity and modern technologies will ensure resilient and sustainable agricultural production in the face of climate change.
Multiscale Impacts of Land Environmental Features and Planning on Apartment Resale Prices in Jinan City, China
Authors: Xu Jiaqian , Zhang Zhihua , Crabbe M. James C.
Published: July 2024

As a typical city with a population of 5 to 10 million in China, Jinan has undergone significant increases in land supply during the past decade, resulting in substantial volatility in apartment sale/resale market prices. In this study, we investigated all second-hand apartment transactions from 826 communities of Jinan city and explored the multiscale impacts of land environmental features and planning on apartment resale prices throughout the city. Specifically, central and eastern regions had significantly positive impacts on apartment resale prices, while western regions had significantly negative impacts; education resources had consistently positive impacts throughout the city while shopping, business buildings, and medical resources had insignificant impacts; subway stations had insignificant impacts and bus stations had significant effects only in congestion points and northeastern edges. Our results revealed the formation mechanisms and spatial heterogeneity of apartment resale prices in Jinan. Our work will not only help in the decision making of potential apartment purchasers, but will also be conducive to enhancing the spatial justice of local governments in land supply and planning policies.
Assessing the Impact of Brackish Water on Soil Salinization with Time-Lapse Inversion of Electromagnetic Induction Data
Authors: De Carlo Lorenzo , Farzamian Mohammad
Published: July 2024

Over the last decade, electromagnetic induction (EMI) measurements have been increasingly used for investigating soil salinization caused by the use of brackish or saline water as an irrigation source. EMI measurements proved to be a powerful tool for providing spatial information on the investigated soil because of the correlation between the output geophysical parameter, i.e., the electrical conductivity, to soil moisture and salinity. In addition, their non-invasive nature and their capability to collect a high amount of data over broad areas and in a relatively short time makes these measurements attractive for monitoring flow and transport dynamics, which are otherwise undetectable with conventional measurements. In an experimental field, EMI measurements were collected during the growth season of tomatoes and irrigated with three different irrigation strategies. Time-lapse data were collected over three months in order to visualize changes in electrical conductivity associated with soil salinity. A rigorous time-lapse inversion procedure was set for modeling the soil salinization induced by brackish irrigation water. A clear soil response in terms of an increase in electrical conductivity (EC) in the upper soil layer confirmed the reliability of the geophysical tool to predict soil salinization trends.
Envisaging Participatory Management in Protected Areas: Local Response to Proposed Conservation Actions in Relation to Environmental Orientation
Authors: Kleftoyanni Vassiliki , Vrahnakis Michael
Published: July 2024

Involving local people in natural area management is very important to address the complexity of environmental management issues for the sustainable use of local resources. Participatory methods require the contribution of local stakeholders in decision-making. Mapping the environmental views of local communities allows for the detection of aspects that could facilitate management efforts. This research—in the frame of the Skyros LIFE project and the PAMNATURA project—measures the local acceptability of the conservation actions proposed by the LIFE project in Skyros island (Greece), in relation to recording local people’s environmental orientation using the 15-item revised New Ecological Paradigm (NEP) scale. The research was carried out by means of questionnaires. The LIFE project proposed actions were grouped into three categories according to their theme, i.e., promoting (a) nature protection, (b) agro-pastoralism and (c) ecotourism. The sample seems to largely agree with the LIFE project proposals, while the results showed high scores for most of the NEP scale items, implying pro-environmental beliefs, though there appears to be disagreement or neutrality regarding a few items. The local acceptability of the proposed actions was found to correlate to local people’s environmental concern measured through the NEP scale. Drawing on the results, the implementation of actions related directly or indirectly to economic activities and the preservation of traditional activities, as well as environmental education and interactive informing and consultation, could enhance local participation. Skyros island seems to offer an appropriate social background for applying participatory and adaptive management and implementing conservation programs.
Spatiotemporal Evolution and Coupling Analysis of Human Footprints and Habitat Quality: Evidence of 21 Consecutive Years in China
Authors: Xue Qiang , Lu Lu , Zhang Yang , Qin Changbo
Published: July 2024

Assessing the spatiotemporal evolution characteristics of habitat quality, human footprint, and coupling coordination between two systems in continuous cycles and on national scales is of great significance to maintaining biodiversity and sustainable development. This study took China as an example, based on land-use data from 2000 to 2020, using the Integrated Valuation of Ecosystem Services and Tradeoffs—Habitat Quality (InVEST-HQ) model and the human footprint framework, coupling trend analysis methods such as Theil–Sen Median Analysis, Mann–Kendall Test, and Grid Transition Matrix (GTM) Method and combining the four-quadrant model and the coupling coordination degree model (CCDM) to reveal the spatiotemporal evolution characteristics of habitat quality, human footprint, and CCDM in China for 21 consecutive years and the response relationship between the two systems of habitat quality and human footprint. The results show that the land cover change area from 2000 to 2020 accounted for 4.2% of the total area. Both habitat quality and human footprints exhibit apparent spatial heterogeneity along the “Hu Line” and generally fall into two evolutionary stages: “degradation–improvement”. The proportions of degradation and improvement were 14.37% and 8.36%, respectively, and the mutation point was in the year 2013; the average human footprint increased by 16.75%, and the increased and decreased area proportions were 63.40% and 21.53%, respectively. The mutation occurred in 2014. The right side of the “Hu Line” primarily hosts areas with high values of the coordinated coupling index of human footprints and habitat quality systems. The four quadrants generally have the following characteristics: “quadrant IV on the right is dominant, quadrants II and III on the left are dominant, and quadrant I is located in the transition zone of the ‘Hu Line’”. The coupling coordination degree (CCD) and human footprints have a weak, nonlinear “inverted U-shaped” relationship. This study provides compelling evidence for the spatiotemporal evolution and coupling relationship between habitat quality and human footprint in China, provides scientific decision-making support for biodiversity protection and sustainable economic development, and maintains the bottom line of ecological security for a beautiful China.
Predicting Factors and Clinical Characteristics of Pruritus in Psoriasis: A Cross-Sectional Survey
Authors: Morariu Silviu-Horia , Cotoi Ovidiu Simion , Tiucă Oana Mirela , Ambros Mircea , Ilcuș Roxana-Ioana , Garaga Liuba , Raluca Ailincăi , Horea Diana , Bălan Andreea-Beatrix , Husariu Mădălina , Gînj Anca , Țiplic Alexandra , Hidi Andrea , Szabo Biborka , Stan Radu Alexandru , Nicolescu Alin Codruț
Published: July 2024

Pruritus is an important symptom among patients affected by psoriasis. To date, no general agreement has been established regarding pruritus as a measure of psoriasis severity. This study aims to assess psoriatic pruritis prevalence and characteristics using a comprehensive itch questionnaire. A semi-structured questionnaire consisting of 48 questions was applied to patients diagnosed with psoriasis and admitted to the Dermatology Department of Mures Clinical County Hospital, Romania. A total of 163 patients were enrolled, out of which 115 (70.55%) reported itch. Patients with itch had higher PASI (p = 0.003) and DLQI scores (p < 0.001). The itch was most frequently described as a crawling sensation, mainly located in the lesional skin and aggravated by stress and temperature variation. It had a moderate intensity (6.18 ± 2.46). Emollients were the treatment preferred by most patients in alleviating itch, while biologics exerted a protective effect on itch development (OR = −0.24; p < 0.0001) and negatively correlated with itch intensity (r = −0.23; p < 0.0001). Advanced age, high BMI, and PASI scores were indicators of itch presence, while female gender, high PASI score, and frequent itch episodes indicate highly intense pruritus (≥7 on the VAS). A better understanding of itch and its clinical features will guide physicians toward the best treatment option and would, ultimately, benefit the patient.
The Use of Ascorbic Acid in Adjunctive Treatment for Schizophrenia—Current State of Knowledge
Authors: Piłat Patrycja , Nikel Kamil , Smolarczyk Joanna , Piegza Magdalena
Published: July 2024

Schizophrenia is a mental illness characterized by disturbances in the perception of reality, thinking, emotions, and social functioning. This significantly impacts the quality of life of patients and leads to long-term disability. Despite advances in understanding its pathogenesis and treatment, schizophrenia remains a clinical challenge, especially due to the diversity of its symptoms and the complexity of its mechanisms. Schizophrenia is associated with abnormal functioning of the dopaminergic system, disturbances in glutamatergic neurotransmission, and oxidative stress in the brain. In recent years, there has been increasing interest in optimizing the treatment of mental disorders. The potential use of ascorbic acid, or vitamin C, in the therapy of schizophrenia could bring substantial benefits to patients. Ascorbic acid exhibits antioxidant and neuroprotective properties, suggesting its potential efficacy in reducing brain oxidative stress and improving neurotransmission. Additionally, there have been reports of its positive effects on psychotic symptoms and its potential in reducing the side effects of antipsychotic drugs. In this review article, we present the current state of knowledge on the potential use of ascorbic acid in the treatment of schizophrenia as an adjunct to standard pharmacological therapy. We analyze existing clinical studies and the mechanisms of action of vitamin C, suggesting its promising role as an adjunctive therapy in the treatment of schizophrenia. These insights, though not yet widely disseminated, may be significant for the further development of therapeutic strategies for this mental illness.
Clinical Tools for Optimizing Therapeutic Decision-Making in Prostate Cancer: A Five-Year Retrospective Analysis
Authors: Latcu Silviu Constantin , Cumpanas Alin Adrian , Barbos Vlad , Buciu Victor-Bogdan , Raica Marius , Baderca Flavia , Gaje Pusa Nela , Ceausu Raluca Amalia , Dumitru Cristina-Stefania , Novacescu Dorin , Cut Talida Georgiana , Petrica Ligia
Published: July 2024

The effective staging of prostate cancer is essential for optimizing treatment and predicting outcomes. This study assessed the correlation between detailed preoperative diagnostic scores and postoperative outcomes to evaluate the accuracy of cancer restaging and its impact on treatment decisions and prognosis after prostatectomy. This retrospective study analyzed 133 prostate cancer patients who underwent prostatectomies at “Pius Brinzeu” Clinical Emergency Hospital in Timisoara over five years. Preoperative Gleason scores increased significantly across risk categories, from an average of 6.21 in low-risk patients to 7.57 in high-risk patients. This trend continued postoperatively, with scores rising from 7.04 to 8.33, respectively. The average increase in Gleason scores from preoperative to postoperative assessments was most pronounced in high-risk patients, at 0.76. Significant changes in clinical staging included increases in NCCN risk, where high-risk patients showed a 30% increase, and ISUP grade, with a 26.7% increase in the high-risk category. Notably, nodal status changes were also significant in high-risk patients, showing a 23.3% increase. The incidence of MRI-detected adenopathy was notably higher in the high-risk group (50%). Furthermore, there were significant correlations between the preoperative CAPRA score and postoperative ISUP grade (r = 0.261) and the preoperative PIRADS score and postoperative ISUP grade (r = 0.306). Similar observations were made between the preoperative and postoperative Gleason scores (r = 0.286) and the number of positive fragments (r = 0.227) with the postoperative ISUP grading. Furthermore, the preoperative CAPRA score was significantly correlated (r = 0.261) with the postoperative ISUP grading. Preoperative MRI findings, which included assessments of adenopathy and seminal vesicle invasion, were also significantly correlated (r = 0.218) with the postoperative pathological findings. Additionally, a significant correlation was found between the preoperative PIRADS score and postoperative ISUP grade (r = 0.306). In forecasting the aggressiveness and staging of prostate cancer following surgery, preoperative PSA levels showed an AUC of 0.631; the preoperative Gleason score had an AUC adjusted to 0.582, and the number of positive biopsy fragments indicated an AUC of 0.566. These results highlight the necessity of accurate and comprehensive preoperative assessments to better predict disease progression and refine treatment strategies.
A Comparative Morphological Study on the Characteristics of Egg Envelopes of Three Cultrinae Fishes (Cyprinidae, Teleostei) in Korea
Authors: Park Cheol-Woo , Kim Jae-Goo
Published: July 2024

Three species of subfamily Cultrinae currently live in Korea, but Erythroculter erythropterus has been introduced into the Nakdonggang River and has taken over the habitat, reducing the habitat of Culter brevicauda. Only the endangered species C. brevicauda still lives in the Yeongsangang River, and it is necessary to be careful not to introduce E. erythropterus in the future. Hemiculter eigenmanni is also found throughout the country. In order to effectively manage and conserve the species in its various habitats and against invasions, this study was initiated. The ultrastructure of the egg envelopes of three species of Cultrinae inhabiting the Geumgang and Yeongsangang Rivers—E. erythropterus, C. brevicauda, and H. eigenmanni—were observed. It was found that the zona radiata of the egg envelopes of all three species were divided into two layers, an outer and inner layer, with the outer surface having a non-structural form. This form is characteristic of fishes with muddy, stagnant habitats or spawning grounds. The number of pore canals on the surface of the egg envelopes was 83 for E. erythropterus, 75 for C. brevicauda, and 58 for H. eigenmanni per 10 μm2, and the thickness was 7.89 ± 0.34 μm, 12.27 ± 0.46 μm, and 7.42 ± 0.24 μm, respectively. The shape of the micropyle demonstrated a funnel shape narrowing toward the inner diameter in all three species, and the size of the inner diameter was 6.62 ± 0.29 μm in E. erythropterus, 4.19 ± 0.39 μm in C. brevicauda, and 3.98 ± 0.46 μm in H. eigenmanni. The differences between species were identified in the number of pore canals, thickness, and micropyle inner diameter of egg envelopes, which were species-specific. Our study reveals a morphological mechanism in the egg envelope that prevents the formation of interspecific hybrids, and these features can be taxonomic traits that clarify species names. It also provides useful data for the production (breeding) of the second generation in aquaculture.
Numerical Optimization Analysis of Floating Ring Seal Performance Based on Surface Texture
Authors: He Zhenpeng , Guo Yuhang , Si Jiaxin , Li Ning , Jia Lanhao , Zou Yuchen , Wang Hongyu
Published: July 2024

Much research and practical experience have shown that the utilization of textures has an enhancing effect on the performance of dynamic seals and the dynamic pressure lubrication of gas bearings. In order to optimize the performance of floating ring seals, this study systematically analyzes the effects of different texture shapes and their parameters. The Reynolds equation of the gas is solved by the successive over-relaxation (SOR) iteration method. The pressure and thickness distributions of the seal gas film are solved to derive the floating force, end leakage, friction, and the ratio of buoyancy to leakage within the seal. The effects of various texture shapes, including square, 2:1 rectangle, triangle, hexagon, and circle, as well as their parameters, such as texture depth, angle, and area share, on the sealing performance are discussed. Results show that the texture can increase the air film buoyancy and reduce friction, but it also increases the leakage by a small amount. Square textures and rectangular textures are relatively effective. The deeper the depth of the texture within a certain range, the better the overall performance of the floating ring seal. As the texture area percentage increases, leakage tends to increase and friction tends to decrease. A fractal roughness model is developed, the effect of surface roughness on sealing performance is briefly discussed, and finally the effect of surface texture with roughness is analyzed. Some texture parameters that can significantly optimize the sealing performance are obtained. Rectangular textures with certain parameters enhance the buoyancy of the air film by 81.2%, which is the most significant enhancement effect. This rectangular texture reduces friction by 25.8% but increases leakage by 79.5%. The triangular textures increase buoyancy by 28.02% and leakage increases by only 10.08% when the rotation speed is 15,000 r/min. The results show that texture with appropriate roughness significantly optimizes the performance of the floating ring seal.
trans-catena-Poly[[(bis-(µ-N,N′-bis[(pyridin-3-yl)methyl]ethanediamide))-diaqua-cadmium(II)] bis(nitrate) tetrahydrate)]
Authors: Caria Anna , Podda Enrico , Aragoni M. Carla , Lai Riccardo , Pintus Anna , Arca Massimiliano
Published: July 2024

The reaction between cadmium nitrate tetrahydrate and N,N′-bis(pyridin-3-ylmethyl)oxalamide (L) in a 1:3 molar ratio in a water/acetonitrile (1:6 v/v) mixture afforded single crystals of compound 1 suitable for X-ray diffraction analysis. Compound 1 consists of the coordination polymer (CP) [[Cd(L)2(OH2)2](NO3)2·4H2O]∞, in which CdII ions are bridged by neutral L antiperiplanar N-ligands in a wavy ribbon fashion developed along the c-axis. Two trans-disposed water molecules complete the pseudo-octahedral coordination geometry of the metal ion. The crystal packing of 1 revealed the interplay between π–π stacking interactions and an intricate hydrogen-bonded network involving oxalamides, nitrates, and water molecules. The donor properties of L and the intermolecular interactions in compound 1 are interpreted based on hybrid-DFT calculations.
Mechanical Properties and Durability of Composite Cement Pastes Containing Phase-Change Materials and Nanosilica
Authors: Ziga-Carbarín Javier , Gómez-Zamorano Lauren Y. , Cruz-López Arquímedes , Pushpan Soorya , Vázquez-Rodríguez Sofía , Balonis Magdalena
Published: July 2024

Escalating global surface temperatures are highlighting the urgent need for energy-saving solutions. Phase-change materials (PCMs) have emerged as a promising avenue for enhancing thermal comfort in the construction sector. This study assessed the impact of incorporating PCMs ranging from 1% to 10% by mass into composite Portland cement partially replaced by fly ash (FA) and nanosilica particles (NS). Mechanical and electrochemical techniques were utilized to evaluate composite cements. The results indicate that the presence of PCMs delayed cement hydration, acting as a filler without chemically interacting within the composite. The combination of FA and PCMs reduced compressive strength at early ages, while thermal conductivity decreased after 90 days due to the melting point and the latent heat of PCMs. Samples with FA and NS showed a significant reduction in the CO2 penetration, attributed to their pozzolanic and microfiller effects, as well as reduced water absorption due to the non-absorptive nature of PCMs. Nitrogen physisorption confirmed structural changes in the cement matrix. Additionally, electrical resistivity and thermal behavior assessments revealed that PCM-containing samples could reduce temperatures by an average of 4 °C. This suggested that PCMs could be a viable alternative for materials with thermal insulation capacity, thereby contributing to energy efficiency in the construction sector.
Correction: Pakhomova et al. High-Entropy Diborides—Silicon Carbide Composites by Reactive and Non-Reactive Spark Plasma Sintering: A Comparative Study. Materials 2024, 17, 718
Authors: Pakhomova Ekaterina , Cao Giacomo , Orrù Roberto , Garroni Sebastiano , Ferro Paolo , Licheri Roberta
Published: July 2024

In the original publication [...]
Surface Treatments’ Influence on the Interfacial Bonding between Glass Fibre Reinforced Elium® Composite and Polybutylene Terephthalate
Authors: Matta Ashish , Yadavalli Venkat Reddy , Manas Lukas , Kadleckova Marketa , Pavlinek Vladimir , Sedlacek Tomas
Published: July 2024

This study examines the process of using injection moulding to join two different materials to manufacture bi-component moulded products with improved performance characteristics. The two-component process, which combines the advantages of two different technologies—the high efficiency of the injection moulding process and the excellent mechanical properties of long glass fibre composites produced by resin transfer moulding (RTM) technology—offers a particular advantage and improved applicability of the prepared lightweight products in both the automotive and aerospace sectors. The composite studied here consists of Elium® thermoplastic resin (30%) reinforced with unwoven glass fibre fabric (70%) using the RTM process. The Elium® composite sample is consequently used as an insert overmoulded with polybutylene terephthalate (PBT) homopolymer reinforced with 20% w/w of short glass fibre through injection moulding. The influence of different mould temperatures and surface treatments on the adhesion between the materials used is investigated by evaluating the mechanical performance using tensile shear strength tests. It was found that while an increase in mould temperature from 40 °C to 120 °C resulted in a doubling of the initial average bond strength between untreated Elium® RTM inserts and overmoulded PBT parts (0.9 MPa), sandblasting the inserts ensured a further tripling of the bond strength of the composites to a value of 5.4 MPa.
Exploratory Studies of Mechanical Properties, Residual Stress, and Grain Evolution at the Local Regions near Pores in Additively Manufactured Metals
Authors: Li Wei , Bian Ning , Nagaraja Kishore Mysore , Zhang Xinchang , Lu Hongbing
Published: July 2024

Directed energy deposition (DED) is gaining widespread acceptance in various industrial applications since its unique manufacturing features allow the DED to print metallic parts with very complex geometries. However, DED inevitably generates a lot of internal pores which can limit the widespread applications of the DED technique. The current studies on DED porosity are mostly focused on analyzing pores’ bulk-scale influences on mechanical properties and performances. Since DED pores have a micro-scale existence, with dimensions ranging from a few microns to several hundred microns, it is fundamental to explore the pores’ influences on the micro-scale, including local mechanical properties, residual stress, and grains near pores. However, this important research direction has been neglected. The objective of this work is to fill the above gap in DED porosity research and acquire a fundamental understanding of the role of porosity on a microscopic scale. The authors used nanoindentation approaches to investigate internal pores’ effects on mechanical properties and residual stress in local regions surrounding the pores. In addition, the grains near pores were observed through EBSD, and simulated with the Kinetic Monte Carlo model. The research findings can be provided for DED researchers and industrial practitioners as technical guidance. Most importantly, the research results can work as a good reference for tracing the source of bulk-scale mechanical performances and properties of DED parts with internal pores.
Photoinduced Phase Transitions of Imine-Based Liquid Crystal Dimers with Twist–Bend Nematic Phases
Authors: Arakawa Yuki , Arai Yuto
Published: July 2024

Photoisomerizable molecules in liquid crystals (LCs) allow for photoinduced phase transitions, facilitating applications in a wide variety of photoresponsive materials. In contrast to the widely investigated azobenzene structure, research on the photoinduced phase-transition behavior of imine-based LCs is considerably limited. We herein report the thermal and photoinduced phase-transition behaviors of photoisomerizable imine-based LC dimers with twist–bend nematic (NTB) phases. We synthesize two homologous series of ester- and thioether-linked N-(4-cyanobenzylidene)aniline-based bent-shaped LC dimers with an even number of carbon atoms (n = 2, 4, 6, 8, and 10) in the central alkylene spacers, namely, CBCOOnSBA(CN) and CBOCOnSBA(CN), possessing oppositely directed ester linkages, C=OO and OC=O, respectively. Their thermal phase-transition behavior is examined using polarizing optical microscopy and differential scanning calorimetry. All dimers form a monotropic NTB phase below the temperature of the conventional nematic (N) phase upon cooling. Remarkably, the NTB phases of CBCOOnSBA(CN) (n = 2, 4, 6, and 8) and CBOCOnSBA(CN) (n = 6 and 8) supercool to room temperature and vitrify without crystallization. In addition, the phase-transition temperatures and entropy changes of CBCOOnSBA(CN) are lower than those of CBOCOnSBA(CN) at the same n. Under UV light irradiation, the NTB and N phases transition to the N and isotropic phases, respectively, and reversibly return to their initial LC phases when the UV light is turned off.
A Split-Plot Experimentation Strategy for Making Causal Inferences in Advanced Materials: Auxetic Polyurethane Foam Manufacturing and Processing Analysis
Authors: Wadsworth Matthew S. , Deloyer Md Jahan , Vanli Omer Arda , Zeng Changchun
Published: July 2024

Development of advanced materials is often time consuming and expensive because of the large number of variables involved and experiments needed. An effective experimentation strategy would accelerate development by reducing the required amount of experiments without sacrificing the obtainable information. In this paper, the development of auxetic polyurethane (PU) foams was discussed as a case study. Auxetic materials are materials with a negative Poisson’s ratio and have potential in many structural and functional applications. Auxetic PU foams are the most studied auxetic materials, and their manufacturing and properties are affected by many processing and environmental factors. This paper introduces a sophisticated design of experimental methodology to help reduce the experimental effort while effectively screening these factors. This methodology is then applied in an experiment to illustrate its utility and distinct advantages that greatly facilitate material development.
Conductometric H2S Sensors Based on TiO2 Nanoparticles
Authors: Alaya Yassine , Madani Malek , Bouguila Noureddine , El Mir Lassaad , Fazio Enza , Corsaro Carmelo , Neri Giovanni
Published: July 2024

High-performance hydrogen sulfide (H2S) sensors are mandatory for many industrial applications. However, the development of H2S sensors still remains a challenge for researchers. In this work, we report the study of a TiO2-based conductometric sensor for H2S monitoring at low concentrations. TiO2 samples were first synthesized using the sol-gel route, annealed at different temperatures (400 and 600 °C), and thoroughly characterized to evaluate their morphological and microstructural properties. Scanning electronic microscopy, Raman scattering, X-ray diffraction, and FTIR spectroscopy have demonstrated the formation of clusters of pure anatase in the TiO2 phase. Increasing the calcination temperature to 600 °C enhanced TiO2 crystallinity and particle size (from 11 nm to 51 nm), accompanied by the transition to the rutile phase and a slight decrease in band gap (3.31 eV for 400 °C to 3.26 eV for 600 °C). Sensing tests demonstrate that TiO2 annealed at 400 °C displays good performances (sensor response Ra/Rg of ~3.3 at 2.5 ppm and fast response/recovery of 8 and 23 s, respectively) for the detection of H2S at low concentrations in air.
Continuous Drive Friction Welded Al/Cu Joints Produced Using Short Welding Time, Elevated Rotational Speed, and High Welding Pressures
Authors: Milašinović Veljko , Alil Ana , Milašinović Mijat , Vencl Aleksandar , Hatala Michal , Dikić Stefan , Gligorijević Bojan
Published: July 2024

The present study aimed to enhance the efficiency and efficacy of the Al/Cu joint production process implemented by the company VEMID Ltd., Jagodina, Serbia, by attaining sound joints within a very short welding time. For this purpose, the present study aimed at investigating the accuracy and the quality of the continuous drive friction welding (CDFW) process, as well as the optimum combination of CDFW parameters with highest joint efficiency in terms of investigated properties. The accuracy was estimated through an analysis of temperature–time curves recorded during CDFW using an infrared camera. The quality was evaluated through an investigation of the properties of Al/Cu joints produced using different friction (66.7, 88.9, and 133.3 MPa) and forging (88.9, 222.2, and 355.6 MPa) pressures and a constant total welding time (4 s) and rotational speed (2100 rpm). Thermal imaging with an infrared camera demonstrated that the actual total welding time was 15% longer compared to the nominal value. This was attributed to the slow pressure response of the pneumatic brake system. The relative changes in the maximum surface temperature (TMS) during the CDFW process corresponded to changes in welding pressures, indicating the potential of the thermal imaging method for monitoring and assessing this process. A preliminary investigation demonstrated that Al/Cu joints produced using welding pressures less than 88.9 MPa often displayed the presence of non-joined micro-regions at the Al/Cu interface and a significant thickness of interfacial Al2Cu (up to 1 µm). However, when friction pressure was set at 66.7 MPa, an increase in the forging pressure to 222.2 MPa eliminated the presence of non-joined micro-regions and reduced the thickness of Al2Cu to 0.5 µm on the average level. These Al/Cu joints achieved the highest joint efficiencies in terms of strength (100%) and ductility (61%). They exhibited an electrical conductivity higher than 92% of the theoretical value. A further increase in any welding pressure produced similar or deteriorated properties, accompanied by an increase in the consumption of raw materials and energy. Such turn of events was counterproductive to the original goal of increasing the efficiency and efficacy of the CDFW process.
A Novel Error-Based Adaptive Feedback Zeroing Neural Network for Solving Time-Varying Quadratic Programming Problems
Authors: Yan Daxuan , Li Chunquan , Wu Junyun , Deng Jinhua , Zhang Zhijun , Yu Junzhi , Liu Peter X.
Published: July 2024

This paper introduces a novel error-based adaptive feedback zeroing neural network (EAF-ZNN) to solve the time-varying quadratic programming (TVQP) problem. Compared to existing variable gain ZNNs, the EAF-ZNN dynamically adjusts the parameter to adaptively accelerate without increasing to very large values over time. Unlike adaptive fuzzy ZNN, which only considers the current convergence error, EAF-ZNN ensures regulation by introducing a feedback regulation mechanism between the current convergence error, the historical cumulative convergence error, the change rate of the convergence error, and the model gain parameter. This regulation mechanism promotes effective neural dynamic evolution, which results in high convergence rate and accuracy. This paper provides a detailed analysis of the convergence of the model, utilizing four distinct activation functions. Furthermore, the effect of changes in the proportional, integral, and derivative factors in the EAF-ZNN model on the rate of convergence is explored. To assess the superiority of EAF-ZNN in solving TVQP problems, a comparative evaluation with three existing ZNN models is performed. Simulation experiments demonstrate that the EAF-ZNN model exhibits a superior convergence rate. Finally, the EAF-ZNN model is compared with the other three models through the redundant robotic arms example, which achieves smaller position error.
Rightful Rewards: Refining Equity in Team Resource Allocation through a Data-Driven Optimization Approach
Authors: Jiang Bo , Tian Xuecheng , Pang King-Wah , Cheng Qixiu , Jin Yong , Wang Shuaian
Published: July 2024

In group management, accurate assessment of individual performance is crucial for the fair allocation of resources such as bonuses. This paper explores the complexities of gauging each participant’s contribution in multi-participant projects, particularly through the lens of self-reporting—a method fraught with the challenges of under-reporting and over-reporting, which can skew resource allocation and undermine fairness. Addressing the limitations of current assessment methods, which often rely solely on self-reported data, this study proposes a novel equitable allocation policy that accounts for inherent biases in self-reporting. By developing a data-driven mathematical optimization model, we aim to more accurately align resource allocation with actual contributions, thus enhancing team efficiency and cohesion. Our computational experiments validate the proposed model’s effectiveness in achieving a more equitable allocation of resources, suggesting significant implications for management practices in team settings.
PDE-Based Two-Dimensional Radiomagnetotelluric forward Modelling Using Vertex-Centered Finite-Volume Scheme
Authors: Xie Wei , Zhu Wendi , Tong Xiaozhong , Ma Huiying
Published: July 2024

An efficient finite-volume algorithm, based on the vertex-centered technique, is proposed for solving two-dimensional radiomagnetotelluric forward modeling. Firstly, we derive the discrete expressions of the radiomagnetotelluric Helmholtz-type equation and the corresponding mixed boundary conditions using the vertex-centered finite-volume technique. Then, the corresponding approximate solutions of the radiomagnetotelluric forward problem can be calculated by applying the finite-volume scheme to treat the boundary conditions. Secondly, we apply the finite-volume algorithm to solve two-dimensional Helmholtz equations and the resistivity half-space model. Numerical experiments demonstrate the high accuracy of the proposed approach. Finally, we summarize the radiomagnetotelluric responses through a numerical simulation of a two-dimensional model, which enables qualitative interpretation of field data. Furthermore, our numerical method can be extended and implemented for three-dimensional radiomagnetotelluric forward modeling to achieve more accurate computation.
Investigation of the Functional Components in Health Beverages Made from Polygonatum cyrtonema Rhizomes Provides Primary Evidence to Support Their Claimed Health Benefits
Authors: Song Qiyan , Chen Youwu , Shao Ye , Pu Weiting , Ye Bihuan , Shi Xiaoxiao , Shen Jianjun , Li Haibo
Published: July 2024

This study aims to understand the functional component compositions of traditional herbal health beverages made from Polygonatum cyrtonema rhizomes and to reveal the pharmacodynamic chemical basis for their claimed health benefits. Two traditional methods, rhizome decoction and rhizome infusion, were used to make health herbal beverages, including “Huangjin” tea and “Huangjin” wine, respectively. The secondary metabolites of “Huangjin” beverages were investigated and compared by widely targeted metabolomics. The results clearly showed that the major functional components in “Huangjin” beverages were phenolic acids, flavonoids, and alkaloids. The “Huangjin” wine has a greater variety of flavonoids and alkaloids than “Huangjin” tea, and the functional components in “Huangjin” wine were more abundant than those in “Huangjin” tea. Homoisoflavones and amide alkaloids were the dominating flavonoids and alkaloids in “Huangjin” wine, respectively. Continuous rhizome infusion could not increase the content of functional components in “Huangjin” wine. In conclusion, this study not only provides primary evidence to support the claimed health benefits of “Huangjin” beverages but also suggests that making traditional herbal beverages by rhizome infusion has superior health benefits than making them by rhizome decoction, which is attributed to the higher yields of functional components extracted by Chinese liquor than hot water. Therefore, Chinese liquor shows advantages in its use as a superior binary ethanol–water solvent in making herbal health beverages to enhance the solubility of poorly water-soluble functional components.
Hybrid Coupler Used as Tunable Phase Shifter Based on Varactor Diodes
Authors: Benaouf Taleb Mohamed , Hamdoun Abdelaziz , Himdi Mohamed , Lafond Olivier , Ammor Hassan
Published: July 2024

This paper describes the design of a hybrid coupler with a continuously variable output phase difference. This is achieved by using reconfigurable transmission lines with electrically tunable lengths controlled by two biasing voltages through varactor diodes placed across the coupler branches. The design of the coupler is based on the quadrature hybrid structure for the case where the output phase difference is 90° and on the asymmetric structure for the other cases. The proposed coupler can achieve a tunable output phase difference from 52° to 128°, while keeping a coupling coefficient of −3 dB (± 0.5 dB) over the entire desired frequency band. To validate the simulated results, a prototype working at 3.5 GHz was fabricated and tested. The measurement results show good correspondence with the simulation results, especially when the output phase difference is 90°, while a phase mismatch of less than 7° was observed for the other cases. The presented coupler would be a great asset for antenna feeding arrays, especially the Butler matrix.