bluuebunny/crossref_metadata_2025 huggingface dataset:
Designing Decentralized Multi-Variable Robust Controllers: A Multi-Objective Approach Considering Nearly Optimal Solutions
Authors: Pajares Alberto , Blasco Xavier , Herrero Juan Manuel , Sanchis Javier , Simarro Raúl
Published: July 2024

This article presents a new methodology for designing a robust, decentralized control structure that considers stochastic parametric uncertainty and uses a multi-objective approach. This design tunes the loop pairing and controller to be implemented. The proposed approach obtains the optimal and nearly optimal controllers relevant to the nominal scenario. Once obtained, the robustness of these solutions is analyzed. This methodology is compared with a traditional approach for selecting the most robust control pairings. The traditional approach obtains lightly robust controllers, i.e., the most robust controllers with an acceptable performance for the nominal scenario, and it obtains trade-offs between robustness and nominal performance. However, the traditional approach has a high computational cost because it is necessary to consider uncertainty in the optimization stage. The proposed approach mathematically guarantees the acquisition of at least one neighbor controller for each existing lightly robust controller. Therefore, this approach obtains solutions similar to lightly robust solutions with a significantly lower computational cost. Furthermore, the proposed approach provides the designer with more diversity and interesting solutions that are not lightly robust. The different approaches are compared using an example of a multi-variable process with two alternative control structures. The results show the usefulness of the proposed methodology.
A Hybrid News Recommendation Approach Based on Title–Content Matching
Authors: Jiang Shuhao , Lu Yizi , Song Haoran , Lu Zihong , Zhang Yong
Published: July 2024

Personalized news recommendation can alleviate the information overload problem, and accurate modeling of user interests is the core of personalized news recommendation. Existing news recommendation methods integrate the titles and contents of news articles that users have historically browsed to construct user interest models. However, this method ignores the phenomenon of “title–content mismatching” in news articles, which leads to the lack of precision in user interest modeling. Therefore, a hybrid news recommendation method based on title–content matching is proposed in this paper: (1) An interactive attention network is employed to model the correlation between title and content contexts, thereby enhancing the feature representation of both; (2) The degree of title–content matching is computed using a Siamese neural network, constructing a user interest model based on title–content matching; and (3) neural collaborative filtering (NCF) based on factorization machines (FM) is integrated, taking into account the perspective of the potential relationships between users for recommendation, leveraging the insensitivity of neural collaboration to news content to alleviate the impact of title–content mismatching on user feature modeling. The proposed model was evaluated on a real-world dataset, achieving an nDCG of 83.03%, MRR of 81.88%, AUC of 85.22%, and F1 Score of 35.10%. Compared to state-of-the-art news recommendation methods, our model demonstrated an average improvement of 0.65% in nDCG and 3% in MRR. These experimental results indicate that our approach effectively enhances the performance of news recommendation systems.
Updating Correlation-Enhanced Feature Learning for Multi-Label Classification
Authors: Zhou Zhengjuan , Zheng Xianju , Yu Yue , Dong Xin , Li Shaolong
Published: July 2024

In the domain of multi-label classification, label correlations play a crucial role in enhancing prediction precision. However, traditional methods heavily depend on ground-truth label sets, which can be incompletely tagged due to the diverse backgrounds of annotators and the significant cost associated with procuring extensive labeled datasets. To address these challenges, this paper introduces a novel multi-label classification method called updating Correlation-enhanced Feature Learning (uCeFL), which extracts label correlations directly from the data instances, circumventing the dependency on potentially incomplete label sets. uCeFL initially computes a revised label matrix by multiplying the incomplete label matrix with the label correlations extracted from the data matrix. This revised matrix is then utilized to enrich the original data features, enabling a neural network to learn correlation-enhanced representations that capture intricate relationships between data features, labels, and their interactions. Notably, label correlations are not static; they are dynamically updated during the neural network’s training process. Extensive experiments carried out on various datasets emphasize the effectiveness of the proposed approach. By leveraging label correlations within data instances, along with the hierarchical learning capabilities of neural networks, it offers a significant improvement in multi-label classification, even in scenarios with incomplete labels.
Frames of Group Sets and Their Application in Bundle Theory
Authors: Pap Eric , Waalkens Holger
Published: July 2024

We study fiber bundles where the fibers are not a group G but a free G-space with disjoint orbits. The fibers are then not torsors but disjoint unions of these; hence, we like to call them semi-torsors. Bundles of semi-torsors naturally generalize principal bundles, and we call these semi-principal bundles. These bundles admit parallel transport in the same way that principal bundles do. The main difference is that lifts may end up in another group orbit, meaning that the change cannot be described by group translations alone. The study of such effects is facilitated by defining the notion of a basis of a G-set, in analogy with a basis of a vector space. The basis elements serve as reference points for the orbits so that parallel transport amounts to reordering the basis elements and scaling them with the appropriate group elements. These two symmetries of the bases are described by a wreath product group. The notion of basis also leads to a frame bundle, which is principal and so allows for a conventional treatment. In fact, the frame bundle functor is found to be a retraction from the semi-principal bundles to the principal bundles. The theory presented provides a mathematical framework for a unified description of geometric phases and exceptional points in adiabatic quantum mechanics.
Effect of Intermediate Annealing on Microstructure and Cold Rolling Hardness of AlFeMn Alloy
Authors: Pan Yanfeng , Shen Yifu , Cao Lingyong
Published: July 2024

The microstructure and texture of an AlFeMn alloy were studied under different intermediate annealing processes, and the changes in microhardness during cold rolling were analyzed. After annealing at 420 °C with a slow heating rate, the alloy showed a high number of small dispersed particles and recrystallization textures dominated by R texture, with deformation textures of 23.5%. Annealing at 610 °C with a rapid heating rate resulted in a significant decrease in the number of small-sized particles and an increase in recrystallization texture contents, with CubeND being the majority. The deformation texture contents decreased to 14.9%. The electrical conductivity of the 420 °C annealed sheet was higher than before annealing, whereas the sheet annealed at 610 °C showed a decrease in electrical conductivity after annealing. This indicated that annealing at 610 °C led to a higher degree of recrystallization and the development of Cube/CubeND due to the dissolution of dispersed particles. During the subsequent cold rolling process, the microhardness of both annealed sheets initially increased and then decreased. However, the microhardness of the 420 °C annealed sheet with varying cold rolling reductions consistently remained lower than that of the 610 °C annealed sheet, as was the cold rolling reduction corresponding to the peak microhardness. The results showed that the precipitation at 420 °C facilitated work softening, while the dissolution at 610 °C promoted work hardening.
Experimental Characterization and Phase-Field Damage Modeling of Ductile Fracture in AISI 316L
Authors: Dunić Vladimir , Gubeljak Nenad , Živković Miroslav , Milovanović Vladimir , Jagarinec Darko , Djordjevic Nenad
Published: July 2024

(1) Modeling and characterization of ductile fracture in metals is still a challenging task in the field of computational mechanics. Experimental testing offers specific responses in the form of crack-mouth (CMOD) and crack-tip (CTOD) opening displacement related to applied force or crack growth. The main aim of this paper is to develop a phase-field-based Finite Element Method (FEM) implementation for modeling of ductile fracture in stainless steel. (2) A Phase-Field Damage Model (PFDM) was coupled with von Mises plasticity and a work-densities-based criterion was employed, with a threshold to propose a new relationship between critical fracture energy and critical total strain value. In addition, the threshold value of potential internal energy—which controls damage evolution—is defined from the critical fracture energy. (3) The material properties of AISI 316L steel are determined by a uniaxial tensile test and the Compact Tension (CT) specimen crack growth test. The PFDM model is validated against the experimental results obtained in the fracture toughness characterization test, with the simulation results being within 8% of the experimental measurements. (4) The novel implementation offers the possibility for better control of the ductile behavior of metallic materials and damage initiation, evolution, and propagation.
Advances in Energy Harvesting Technologies for Wearable Devices
Authors: Kang Minki , Yeo Woon-Hong
Published: July 2024

The development of wearable electronics is revolutionizing human health monitoring, intelligent robotics, and informatics. Yet the reliance on traditional batteries limits their wearability, user comfort, and continuous use. Energy harvesting technologies offer a promising power solution by converting ambient energy from the human body or surrounding environment into electrical power. Despite their potential, current studies often focus on individual modules under specific conditions, which limits practical applicability in diverse real-world environments. Here, this review highlights the recent progress, potential, and technological challenges in energy harvesting technology and accompanying technologies to construct a practical powering module, including power management and energy storage devices for wearable device developments. Also, this paper offers perspectives on designing next-generation wearable soft electronics that enhance quality of life and foster broader adoption in various aspects of daily life.
The Latest Research Progress on Bionic Artificial Hands: A Systematic Review
Authors: Guo Kai , Lu Jingxin , Wu Yuwen , Hu Xuhui , Yang Hongbo
Published: July 2024

Bionic prosthetic hands hold the potential to replicate the functionality of human hands. The use of bionic limbs can assist amputees in performing everyday activities. This article systematically reviews the research progress on bionic prostheses, with a focus on control mechanisms, sensory feedback integration, and mechanical design innovations. It emphasizes the use of bioelectrical signals, such as electromyography (EMG), for prosthetic control and discusses the application of machine learning algorithms to enhance the accuracy of gesture recognition. Additionally, the paper explores advancements in sensory feedback technologies, including tactile, visual, and auditory modalities, which enhance user interaction by providing essential environmental feedback. The mechanical design of prosthetic hands is also examined, with particular attention to achieving a balance between dexterity, weight, and durability. Our contribution consists of compiling current research trends and identifying key areas for future development, including the enhancement of control system integration and improving the aesthetic and functional resemblance of prostheses to natural limbs. This work aims to inform and inspire ongoing research that seeks to refine the utility and accessibility of prosthetic hands for amputees, emphasizing user-centric innovations.
Terminal Ileitis as the Exclusive Manifestation of COVID-19 in Children
Authors: Schuler Lea Maria , Falkensammer Barbara , Orlik Peter , Auckenthaler Michael , Kranewitter Christof , Bante David , von Laer Dorothee , Fink Franz-Martin
Published: July 2024

The clinical presentation, organ involvement, and severity of disease caused by SARS-CoV-2 are highly variable, ranging from asymptomatic or mild infection to respiratory or multi-organ failure and, in children and young adults, the life-threatening multisystemic inflammatory disease (MIS-C). SARS-CoV-2 enters cells via the angiotensin-converting enzyme-2 receptor (ACE-2), which is expressed on the cell surfaces of all organ systems, including the gastrointestinal tract. GI manifestations have a high prevalence in children with COVID-19. However, isolated terminal ileitis without other manifestations of COVID-19 is rare. In March 2023, two previously healthy boys (aged 16 months and 9 years) without respiratory symptoms presented with fever and diarrhea, elevated C-reactive protein levels, and low procalcitonin levels. Imaging studies revealed marked terminal ileitis in both cases. SARS-CoV-2 (Omicron XBB.1.9 and XBB.1.5 variants) was detected by nucleic acid amplification in throat and stool samples. Both patients recovered fast with supportive measures only. A differential diagnosis of acute abdominal pain includes enterocolitis, mesenteric lymphadenitis, appendicitis, and more. During SARS-CoV-2 epidemics, this virus alone may be responsible for inflammation of the terminal ileum, as demonstrated. Coinfection with Campylobacter jejuni in one of our patients demonstrates the importance of a complete microbiological workup.
Effect of Combining Wuyiencin and Pyrimethanil on Controlling Grape Gray Mold and Delaying Resistance Development in Botrytis cinerea
Authors: Xie Jiabei , Li Boya , Li Jia , Zhang Kecheng , Ran Longxian , Ge Beibei
Published: July 2024

By screening the compounding combination of Wuyiencin and chemical agents, this study aims to delay the emergence of chemical agent resistance, and provide a technical reference for scientific and rational fungicides technology. This study investigated the impacts of the antibiotic wuyiencin derived from Streptomyces albulus var. wuyiensis and its combination with pyrimethanil on the inhibition of Botrytis cinerea. Treatment with wuyiencin (≥80 µg mL−1) strongly inhibited the pathogenicity of B. cinerea and activated the plant defense response against B. cinerea. Application of 80–100 µg mL−1 wuyiencin effectively controlled grape gray mold (by 57.6–88.1% on leaves and 46.7–96.6% on fruits). Consequently, the application of 80–100 µg mL−1 wuyiencin effectively mitigated grape gray mold incidence, leading to a substantial reduction in disease symptoms to nearly imperceptible levels. When wuyiencin (at the median effective concentration [EC50]) was combined with pyrimethanil (EC50) at a ratio of 7:3, it exhibited the highest efficacy in inhibiting B. cinerea growth. This combination was significantly more potent (p < 0.05) than using wuyiencin or pyrimethanil alone in controlling gray mold on grape leaves and fruits. Furthermore, the combination effectively delayed resistance development in gray mold. The experimental results show that wuyiencin can delay resistance development by affecting the expression of methionine biosynthesis genes and reducing the activity of the cell wall-degrading enzyme activity.
Recruitment of Vitronectin by Bacterial Pathogens: A Comprehensive Overview
Authors: Pellegrini Angelica , Pietrocola Giampiero
Published: July 2024

The key factor that enables pathogenic bacteria to establish successful infections lies largely in their ability to escape the host’s immune response and adhere to host surfaces. Vitronectin (Vn) is a multidomain glycoprotein ubiquitously present in blood and the extracellular matrix of several tissues, where it plays important roles as a regulator of membrane attack complex (MAC) formation and as a mediator of cell adhesion. Vn has emerged as an intriguing target for several microorganisms. Vn binding by bacterial receptors confers protection from lysis resulting from MAC deposition. Furthermore, through its Arg-Gly-Asp (RGD) motif, Vn can bind several host cell integrins. Therefore, Vn recruited to the bacterial cell functions as a molecular bridge between bacteria and host surfaces, where it triggers several host signaling events that could promote bacterial internalization. Each bacterium uses different receptors that recognize specific Vn domains. In this review, we update the current knowledge of Vn receptors of major bacterial pathogens, emphasizing the role they may play in the host upon Vn binding. Focusing on the structural properties of bacterial proteins, we provide details on the residues involved in their interaction with Vn. Furthermore, we discuss the possible involvement of Vn adsorption on biomaterials in promoting bacterial adhesion on abiotic surfaces and infection.
A Step towards CO2 Sequestration through Mineral Carbonation: Using Ammonium-Based Lixiviants for the Dissolution of Calcium from Iron-Making Blast Furnace Slag
Authors: Kohitlhetse Itumeleng C. , Manono Malibongwe S. , Motsetse Catherine K. , Mendonidis Peter M.
Published: July 2024

In recent years, technical processes for the sequestration of CO2 through industrial waste mineral carbonation have been explored and developed. There is a large portfolio of carbon capture, utilisation, and storage (CCUS) techniques that have been employed in laboratories and at pilot scale. These include geological storage, ocean storage, and mineralisation by carbonate ores. In view of this, the main purpose of this research was to investigate and explore chemical variables, particularly ammonium salts as lixiviants for calcium mineral extraction from iron-making slag. The slag in use was acquired from a steel mill in the Vaal Triangle Region in Gauteng, South Africa. The experimental test work was conducted using different ammonium lixiviants, namely, NH4NO3, NH4Cl, and CH3COONH4, to understand the influence of anion type as well as possible differences in mechanisms of interactions. Lixiviant concentration as well as reaction time were varied in this research study. The three selected ammonium-based lixiviants showed different extents of calcium extraction owing to differences in the anion groups. NH4NO3, NH4Cl, and CH3COONH4 were found to be capable of dissolving 50% to 80% of the calcium from the selected slag for different molar concentrations. Anion type and leaching time also had significant influences on the leaching of calcium from the slag. Rapid pH degradation resulted in better calcium extraction capabilities. This work has shown that the selected ammonium salts have the potential to be lixiviants for calcium dissolution from iron-making blast furnace slags. These lixiviants would, therefore, be important to consider during calcium mineral carbonation for CO2 sequestration.
Nanostructured Glass-Ceramic Materials from Glass Waste with Antimicrobial Activity
Authors: Caland Juliani P. , Baptista João , Peiter Gabrielle Caroline , de Aguiar Kelen M. F. Rossi , Coelho-Júnior Horácio , Sinnecker João P. , Felix Jorlandio F. , Schneider Ricardo
Published: July 2024

Modern consumption patterns have led to a surge in waste glass accumulating in municipal landfills, contributing to environmental pollution, especially in countries that do not have well-established recycling standards. While glass itself is 100% recyclable, the logistics and handling involved present significant challenges. Flint and amber-colored glass, often found in high quantities in municipal waste, can serve as valuable sources of raw materials. We propose an affordable route that requires just a thermal treatment of glass waste to obtain glass-based antimicrobial materials. The thermal treatment induces crystallized nanoregions, which are the primary factor responsible for the bactericidal effect of waste glass. As a result, coarse particles of flint waste glass that undergo thermal treatment at 720 °C show superior antimicrobial activity than amber waste glass. Glass-ceramic materials from flint waste glass, obtained by thermal treatment at 720 °C during 2 h, show antimicrobial activity against Escherichia coli after just 30 min of contact time. Laser-induced breakdown spectroscopy (LIBS) was employed to monitor the elemental composition of the glass waste. The obtained glass-ceramic material was structurally characterized by transmission electron microscopy, enabling the confirmation of the presence of nanocrystals embedded within the glass matrix.
Ruthenium p-Cymene Complexes Incorporating Substituted Pyridine–Quinoline-Based Ligands: Synthesis, Characterization, and Cytotoxic Properties
Authors: Kokkosi Afroditi , Garofallidou Elpida , Zacharopoulos Nikolaos , Tsoureas Nikolaos , Diamanti Konstantina , Thomaidis Nikolaos S. , Cheilari Antigoni , Machalia Christina , Emmanouilidou Evangelia , Philippopoulos Athanassios I.
Published: July 2024

Organometallic complexes of the formula [Ru(N^N)(p-cymene)Cl][X] (N^N = bidentate polypyridyl ligands, p-cymene = 1-methyl-4-(1-methylethyl)-benzene, X = counter anion), are currently studied as possible candidates for the potential treatment of cancer. Searching for new organometallic compounds with good to moderate cytotoxic activities, a series of mononuclear water-soluble ruthenium(II)–arene complexes incorporating substituted pyridine–quinoline ligands, with pending -CH2OH, -CO2H and -CO2Me groups in the 4-position of quinoline ring, were synthesized, for the first time, to study their possible effect to modulate the activity of the ruthenium p-cymene complexes. These include the [Ru(η6-p-cymene)(pqhyme)Cl][X] (X = Cl− (1-Cl), PF6− (1-PF6), pqhyme = 4-hydroxymethyl-2-(pyridin-2-yl)quinoline), [Ru(η6-p-cymene)(pqca)Cl][Cl] ((2-Cl), pqca = 4-carboxy-2-(pyridin-2-yl)quinoline), and [Ru(η6-p-cymene)(pqcame)Cl][X] (X = Cl− (3-Cl), PF6− (3-PF6), pqcame = 4-carboxymethyl-2-(pyridin-2-yl)quinoline) complexes, respectively. Identification of the complexes was based on multinuclear NMR and ATR-IR spectroscopic methods, elemental analysis, conductivity measurements, UV–Vis spectroscopic, and ESI-HRMS techniques. The solid-state structures of 1-PF6 and 3-PF6 have been elucidated by single-crystal X-ray diffraction revealing a three-legged piano stool geometry. This is the first time that the in vitro cytotoxic activities of these complexes are studied. These were conducted in HEK293T (human embryonic kidney cells) and HeLa cells (cervical cancer cells) via the MTT assay. The results show poor in vitro anticancer activities for the HeLa cancer cell lines and 3-Cl proved to be the most potent (IC50 > 80 μΜ). In both cell lines, the cytotoxicity of the ligand precursor pqhyme is significantly higher than that of cisplatin.
Probiotic-Enriched Ice Cream with Fermented White Kidney Bean Homogenate: Survival, Antioxidant Activity, and Potential for Future Health Benefits
Authors: Ziarno Małgorzata , Cichońska Patrycja , Kowalska Ewa , Zaręba Dorota
Published: July 2024

This study investigated a novel probiotic-enriched ice cream containing fermented white kidney bean homogenate to explore its potential health benefits in the future. We assessed the viability of various probiotic strains during ice cream production and storage, focusing on their potential to reach the gut, and evaluated overall antioxidant activity using 2,2-diphenyl-1-picrylhydrazyl (DPPH), 2,2′-Azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS), ferric reducing antioxidant power (FRAP), and total polyphenol content (TPC) assays. The incorporation of fermented white bean homogenate significantly increased antioxidant capacity compared to the control group. Notably, strains such as Lacticaseibacillus rhamnosus GG and Lactiplantibacillus plantarum 299v demonstrated the most pronounced effects on antioxidant activity, suggesting potential synergistic benefits between probiotics and bioactive compounds in fermented white beans. Although all probiotic strains experienced decreased viability during storage, certain strains, particularly L. plantarum 299v and Lacticaseibacillus casei DN-114001, showed promising survival rates even after 6 months. These results suggest the potential for developing probiotic ice cream containing viable bacteria capable of reaching the gut and contributing to a healthy gut microbiota. Overall, this study highlights the potential of probiotic-enriched ice cream with fermented white kidney bean homogenate to combine the established benefits of probiotics for gut health with the enjoyment of consuming ice cream.
The Synergetic Reduction of the Condensation Degree of Dissolved Lignin (DL) during the Refining Process of Wheat Straw Biomass Based on the MA/O3 System
Authors: Chen Xiuguang , Liu Zhulan , Zhou Zhenyu , Li Renai , Li Lizi , Cao Yunfeng
Published: July 2024

Lignin, a natural pol2ymer with a complex structure that is difficult to separate, is prone to C-C bond condensation during the separation process. To reduce the condensation of lignin, here, a novel method is proposed for separating the components by using a combination of maleic acid (MA)/ozone (O3) to co-treat wheat straw. The removal of lignin, glucan, and xylan was 38.07 ± 0.2%, 31.44 ± 0.1%, and 71.98 ± 0.1%, respectively, under the conditions of ball-milling of wheat straw for 6 h, reaction temperature of 60 °C, and O3 holding time of 9 min. Lignin-rich solutions were collected to extract the dissolved lignin (DL) after washing the treated samples. The DL obtained under MA/O3 conditions had a carboxyl group (-COOH) content of 2.96 mmol/g. The carboxyl group of MA underwent esterification with the hydroxyl group (-OH) at the γ position of lignin and O3 reacted on the positions of the lignin side chain or the phenolic ring, resulting in a break in the side chain and the opening of the phenolic ring to introduce the carboxyl group. The 2D-HSQC-NMR results revealed that the phenolic ring-opening reaction of lignin in the presence of O3 was essentially free of β-β and β-5 condensation bonds.
Enhancing Performance of Organic Pollutant Degradation via Building Heterojunctions with ZnO Nanowires and Na Doped Conjugated 2,4,6-Triaminopyrimidin-g-C3N4
Authors: Liu Ziyi , Ruan Zixin , Yang Xiaojie , Huang Yaqiong , Xing Jun
Published: July 2024

Organic pollutants were one of the main sources of environmental pollutants. The degradation of organic pollutants through photocatalytic technology was one of the effective solutions. By preparing zinc oxide(ZnO) nanowires modified with sodium-doped conjugated 2,4,6-triaminopyrimidin-g-C3N4 (NaTCN) heterojunction (ZnO/NaTCN), the photocatalytic performance of NaTCN modified with different ratios of ZnO was systematically studied. The photocatalytic performance was studied through the degradation performance of methyl blue (MB) dye. The results showed that 22.5 wt% ZnO/NaTCN had the best degradation effect on MB dye. The degradation rate of MB reached 98.54% in 70 min. After three cycles, it shows good cycling stability (degradation rate is 96.99%) for dye degradation. It was found that there are two types of active species: ·OH and h+, of which h+ is the main active species produced by photocatalytic degradation of dyes. The excellent degradation performance was attributed to the fact that ZnO facilitated the extraction and transport of photogenerated carriers. The doping of sodium facilitated charge transfer. The NaTCN conjugated system promoted the extraction and transfer of photogenerated carriers. It provided guidance for designing efficient composite catalysts for use in other renewable energy fields.
Plasma-Etched Black GaAs Nanoarrays with Gradient Refractive Index Profile for Broadband, Omnidirectional, and Polarization-Independent Antireflection
Authors: Huang Yi-Fan , Jen Yi-Jun , Modak Varad A. , Chen Li-Chyong , Chen Kuei-Hsien
Published: July 2024

Black GaAs nanotip arrays (NTs) with 3300 nm lengths were fabricated via self-masked plasma etching. We show, both experimentally and numerically, that these NTs, with three gradient refractive index layers, effectively suppress Fresnel reflections at the air–GaAs interface over a broad range of wavelengths. These NTs exhibit exceptional UV-Vis light absorption (up to 99%) and maintain high NIR absorption (33–60%) compared to bare GaAs. Moreover, possessing a graded layer with a low refractive index (n = 1.01 to 1.12), they achieve angular and polarization-independent antireflection properties exceeding 80° at 632.8 nm, aligning with perfect antireflective coating theory predictions. This approach is anticipated to enhance the performance of optoelectronic devices across a wide range of applications.
Green Synthesis of CuO Nanoparticles from Macroalgae Ulva lactuca and Gracilaria verrucosa
Authors: Marmiroli Marta , Villani Marco , Scarponi Paolina , Carlo Silvia , Pagano Luca , Sinisi Valentina , Lazzarini Laura , Pavlicevic Milica , Marmiroli Nelson
Published: July 2024

Macroalgae seaweeds such as Ulva lactuca and Gracilaria verrucosa cause problems on the northern coast of the Italian Adriatic Sea because their overabundance hinders the growth of cultivated clams, Rudatapes philippinarum. This study focused on the green synthesis of CuO nanoparticles from U. lactuca and G. verrucosa. The biosynthesized CuO NPs were successfully characterized using FTIR, XRD, HRTEM/EDX, and zeta potential. Nanoparticles from the two different algae species are essentially identical, with the same physical characteristics and almost the same antimicrobial activities. We have not investigated the cause of this identity, but it seems likely to arise from the reaction of Cu with the same algae metabolites in both species. The study demonstrates that it is possible to obtain useful products from these macroalgae through a green synthesis approach and that they should be considered as not just a cause of environmental and economic damage but also as a potential source of income.
Accelerated Discovery of Halide Perovskite Materials via Computational Methods: A Review
Authors: Sheng Ming , Zhu Hui , Wang Suqin , Liu Zhuang , Zhou Guangtao
Published: July 2024

Halide perovskites have gained considerable attention in materials science due to their exceptional optoelectronic properties, including high absorption coefficients, excellent charge-carrier mobilities, and tunable band gaps, which make them highly promising for applications in photovoltaics, light-emitting diodes, synapses, and other optoelectronic devices. However, challenges such as long-term stability and lead toxicity hinder large-scale commercialization. Computational methods have become essential in this field, providing insights into material properties, enabling the efficient screening of large chemical spaces, and accelerating discovery processes through high-throughput screening and machine learning techniques. This review further discusses the role of computational tools in the accelerated discovery of high-performance halide perovskite materials, like the double perovskites A2BX6 and A2BB′X6, zero-dimensional perovskite A3B2X9, and novel halide perovskite ABX6. This review provides significant insights into how computational methods have accelerated the discovery of high-performance halide perovskite. Challenges and future perspectives are also presented to stimulate further research progress.
Maternal Weight Gain in Early Pregnancy with Healthy Live Offspring: Based on the China Birth Cohort Study
Authors: Wang Jingjing , Zhang Simin , Li Qiao , Xiong Xiaowei , Wu Qingqing
Published: July 2024

Background: Research on maternal weight gain in early pregnancy with healthy live offspring is lacking for Chinese women. Based on the China birth cohort study (CBCS), we aimed to explore maternal weight gain in different groups. Methods: Singleton pregnancies of 6 + 0~13 + 6 weeks of gestation from the CBCS were considered, not including missing data or outliers, those lost at follow-up, or those with non-typical conditions of the offspring. Maternal first-trimester weight and body mass index (BMI) gain was considered as the early pregnancy weight minus the pre-pregnancy weight. Using Pearson’s or Spearman’s correlation and linear regression models to explore the relationship between maternal weight and BMI gain and gestational age (GA), stratified and sensitivity analyses were carried out to identify the study’s robustness. Results: There were 25,292 singleton pregnancies with healthy live offspring who were ultimately enrolled, and there was a linear correlation between GA and maternal weight gain (=0.55 + 0.05 × GA (weeks), p < 0.001, r2 = 0.002) and BMI change (=0.21 + 0.02 × GA (weeks), p < 0.001, r2 = 0.002). The association remained robust in the stratified and sensitivity analyses of the subgroups. Conclusions: Although the association between GA and maternal pre-pregnancy weight and BMI gain is weak, a slight correlation was shown, especially in pregnant women with a typical or low pre-pregnancy BMI, Han ethnicity, moderate levels of physical activity, natural conception, and folic acid (FA) and/or multivitamin supplementation.
Polyphenols in Cereals: State of the Art of Available Information and Its Potential Use in Epidemiological Studies
Authors: Ficco Donatella Bianca Maria , Petroni Katia , Mistura Lorenza , D’Addezio Laura
Published: July 2024

Cereals are the basis of much of the world’s daily diet. Recently, there has been considerable interest in the beneficial properties of wholegrains due to their content of phytochemicals, particularly polyphenols. Despite this, the existing data on polyphenolic composition of cereal-based foods reported in the most comprehensive databases are still not updated. Many cereal-based foods and phenolic compounds are missing, including pigmented ones. Observational epidemiological studies reporting the intake of polyphenols from cereals are limited and inconsistent, although experimental studies suggest a protective role for dietary polyphenols against cardiovascular disease, diabetes, and cancer. Estimating polyphenol intake is complex because of the large number of compounds present in foods and the many factors that affect their levels, such as plant variety, harvest season, food processing and cooking, making it difficult matching consumption data with data on food composition. Further, it should be taken into account that food composition tables and consumed foods are categorized in different ways. The present work provides an overview of the available data on polyphenols content reported in several existing databases, in terms of presence, missing and no data, and discusses the strengths and weaknesses of methods for assessing cereal polyphenol consumption. Furthermore, this review suggests a greater need for the inclusion of most up-to-date cereal food composition data and for the harmonization of standardized procedures in collecting cereal-based food data and adequate assessment tools for dietary intake.
Investigating Water Balance as a Nutritional Determinant in Breastfeeding: A Comparative Study of Water Consumption Patterns and Influencing Factors
Authors: Malisova Olga , Apergi Kyriaki , Niaos Emmanouil , Xenaki Fotini , Kapsokefalou Maria
Published: July 2024

Background: Ensuring adequate hydration is critical for breastfeeding women, yet their water consumption patterns and hydration status is poorly understood. This study investigates the water consumption patterns and estimated water balance among women, practicing exclusive, mixed, and no breastfeeding methods. Methods: 529 healthy women completed the Nursing Water Balanced Questionnaire (N-WBQ). Participants were distributed across breastfeeding groups as follows: exclusive (39.7%), mixed (31.9%), and no breastfeeding (28.4%). Results: Significant differences were noted in water consumption patterns among breastfeeding groups regarding intake from beverages (p < 0.001), juices (p = 0.019), coffee (p < 0.001), and milk (p = 0.015). Water intake from liquids, except for drinking water (p < 0.001), juices (p = 0.024) and coffee (p < 0.001) differed significantly among groups in women with adequate total water intake based on recommendation, with exclusive breastfeeding mothers prioritizing plain water over other beverages. Total water loss (p < 0.001) and estimated water balance (p < 0.001) significantly varied among breastfeeding groups, with exclusive breastfeeding mothers to exhibit the lowest water balance (−475.36 mL/day), indicating potential dehydration risk. Apart from plain water, water from foods, coffee and milk significantly contributed to positive water balance. Conclusions: Our findings highlight a risk of dehydration in this population, while water consumption patterns are influenced by breastfeeding method, likely affected by varying lactational demands and lifestyle factors. Further research to develop more accurate and individualized methods for assessing water balance in breastfeeding women is needed.
Parental Neglect and Childhood Obesity Amidst COVID-19: A Developmental Psychopathology Perspective on Health and Developmental Risks
Authors: Cimino Silvia
Published: July 2024

The COVID-19 pandemic has profoundly impacted the mental health and developmental trajectories of children and adolescents, catalyzing a range of psychological and behavioral issues due to enforced lockdowns and other restrictions. This text explores these impacts through the lens of developmental psychopathology, which integrates clinical psychology and developmental science to examine the emergence and evolution of psychological disorders across a lifespan. This paper highlights how pandemic-related disruptions have exacerbated conditions such as anxiety and depression and, notably, increased childhood obesity due to changes in lifestyle and reductions in physical activity. The analysis includes a discussion of how isolation has not only restricted access to educational and psychological resources but also increased the risk of parental mental illness and related familial stress, thereby intensifying issues of neglect and their consequent impact on child health. By employing a developmental psychopathology framework, this paper argues for the necessity of targeted interventions that address these complex interplays of genetic, environmental, and psychological factors. Such interventions aim to support children through structured educational and health-oriented strategies, ensuring their well-being amidst the ongoing challenges posed by the pandemic. This approach underscores the importance of early, multifaceted strategies involving parents, educators, and healthcare providers to foster healthier developmental outcomes for children facing unprecedented global health crises.
Association of Body Water Balance, Nutritional Risk, and Sarcopenia with Outcome in Patients with Acute Ischemic Stroke: A Single-Center Prospective Study
Authors: Akimoto Takayoshi , Tasaki Kenta , Ishihara Masaki , Hara Makoto , Nakajima Hideto
Published: July 2024

In the present study, we examined the inter-relationships between body water balance, nutritional risk, sarcopenia, and outcome after acute ischemic stroke (AIS) in patients who were living independently. We defined abnormal body water balance as overhydration, with an extracellular fluid/total body water ratio > 0.390. A geriatric nutritional risk index (GNRI) < 98 was considered low GNRI. Sarcopenia was defined according to the 2019 Asian Working Group for sarcopenia criteria. Poor outcome was defined as a modified Rankin scale (mRS) score ≥ 3 at discharge. Among 111 eligible patients (40 females, median age: 77 years), 43 had a poor prognosis, 31 exhibited overhydration, 25 had low GNRI, and 44 experienced sarcopenia. Patients with poor outcomes had significantly higher National Institutes of Health Stroke Scale (NIHSS) scores, which were significantly more common with overhydration, low GNRI, and sarcopenia (p < 0.001 for all). Concomitant overhydration, low GNRI, and sarcopenia were associated with poorer outcomes. In multivariate analysis, overhydration [odds ratio (OR) 5.504, 95% confidence interval (CI) 1.717–17.648; p = 0.004], age (OR 1.062, 95%CI 1.010–1.117; p = 0.020), and NIHSS score (OR 1.790, 95%CI 1.307–2.451; p < 0.001) were independent prognostic factors for poor outcome. The results indicated that the combination of overhydration, low GNRI, and sarcopenia predict poor outcomes following AIS. Overhydration was particularly associated with poor outcomes.
Correlation of Maternal Vitamin D Status in Early Pregnancy and Vitamin D Supplementation during Pregnancy with Atopic Dermatitis in Infants: A Prospective Birth Cohort Study
Authors: Zhang Qianqian , Yang Dongjian , Shen Qianwen , Li Wei , Li Ruoxuan , Tang Yanan , Lei Zhimin , Li Baihe , Ding Xiya , Ni Meng , Chen Ze , Lin Zhenying , Cheng Chunyu , Yao Dongting , Hu Yi , Liu Xiaorui , Zhao Jiuru , Chen Hao , Liu Zhiwei
Published: July 2024

Objective: This study aimed to investigate the association of maternal first-trimester vitamin D levels and vitamin D supplementation during pregnancy with infant atopic dermatitis (AD) and to determine the effect of variables such as mode of conception on the association. Methods: This study was based on the Shanghai sub-cohort of the International Birth Cohort of China. A total of 4051 woman–infant pairs with singleton pregnancies were recruited. Vitamin D deficiency and insufficiency were defined as serum 25-hydroxyvitamin D concentrations of 25 and 50 nmol/L, respectively. AD in infants was assessed during the first six months using a standardized questionnaire based on the British Working Party criteria. Modified Poisson regression estimated the association between maternal vitamin D status and infant AD. Results: The risk of AD in infants was higher in women with deficient 25-hydroxyvitamin D levels in the first trimester (RR: 1.77, 95% CI: 1.41–2.23). This increased risk was seen in naturally conceived pregnancies, but not in those conceived using assisted reproductive technology (ART). The incidence of AD decreased in infants of mothers who took multi-vitamin (RR: 0.79, 95% CI: 0.67–1.98) and vitamin D supplements (RR: 0.51, 95% CI: 0.37–0.71) compared to those whose mothers did not take any supplements. Maternal vitamin D deficiency had varying effects on AD risk based on passive smoking exposure and breastfeeding patterns. Conclusions: Our findings highlight the importance of monitoring and supplementing vitamin D during pregnancy, especially in specific maternal populations, to reduce the risk of AD in offspring.
Evaluation of Selective Culling as a Containment Strategy for African Swine Fever at a Vietnamese Sow Farm
Authors: Nga Bui Thi To , Auer Agathe , Padungtod Pawin , Dietze Klaas , Globig Anja , Rozstalnyy Andriy , Hai Tran Minh , Depner Klaus
Published: July 2024

Selective culling, also known as the “tooth extraction approach”, is a strategy for controlling African swine fever (ASF) by removing only sick and suspect animals instead of the entire herd in Vietnam. This method prioritizes preserving healthy animals, particularly valuable breeding pigs. Despite its implementation in various forms, no standardized protocol based on scientific principles has been established. Farms typically adapt this strategy based on their understanding, which can vary significantly. In implementing of selective culling that is not based on scientific principles, there is a significant risk of spreading the disease. The aim of this study is to evaluate the consequences of selective culling as currently implemented in Vietnam. Our analysis on a large sow farm revealed that current practices rely heavily on clinical observations without laboratory confirmations. This approach allows ASF-infected animals to remain on the farm longer, potentially exacerbating the spread of the virus. Thus, selective culling poses a substantial risk by potentially exacerbating the spread of disease. Our findings emphasize that early diagnosis of ASF and systematic removal of infected pigs are critical components for the effective implementation of selective culling strategies and that a high level of fragmentation to minimize contact between animals plays a key role. The optimal approach is to test conspicuous animals and separate them. Under no circumstances should suspect animals be left in the herd for several days before they become severely ill and succumb to the disease.
Dementia Prevalence and Onchocerca volvulus Infection among Rural Elderly Persons in the Ntui Health District, Cameroon: A Population-Based Study
Authors: Njamnshi Wepnyu Yembe , Siewe Fodjo Joseph Nelson , Njamnshi Kongnyu Gamnsi , Ngarka Leonard , Mengnjo Michel K. , Nfor Leonard N. , Tsasse Martine A. F. , Njamnshi Julius N. Taryunyu , Maestre Gladys , Cavazos Jose E. , Seshadri Sudha , Etoundi Ngoa Laurent S. , Obama Abena Ondoa Marie-Thérèse , Fongang Bernard , Zoung-Kanyi Bissek Anne-Cécile , Njamnshi Alfred K.
Published: July 2024

Recent research suggests that infection with Onchocerca volvulus induces neurocognitive decline. This study sought to compare the cognitive outcomes of elderly persons based on onchocerciasis infection status and report the overall prevalence of dementia in the rural Ntui Health District in Cameroon. A community-based approach was used to recruit 103 participants aged ≥60 years. Dementia screening was done using the Community Screening Interview for Dementia (CSID) tool with a cut-off value of ≤29.5. O. volvulus infection was determined via microscopic examination of skin snips and serological testing of Ov16 antibodies using rapid diagnostic tests. Overall, the prevalence of dementia was 10.7%. Among the tested individuals, 17.9% (15/84) and 62.1% (41/66) were positive for O. volvulus and Ov16 antibodies, respectively. A multivariable linear regression model of CSID scores found a significant positive association with education level (8.654; 95% CI: 2.0870 to 15.222). However, having a positive skin snip for O. volvulus (−3.399; 95% CI: −6.805 to 0.007) and inhaling tobacco (−5.441; 95% CI: −9.137 to −1.744) tended to lower the CSID scores. Ongoing onchocerciasis transmission in the Ntui Health District may constitute a risk factor for dementia. Strengthening onchocerciasis elimination and adopting healthier lifestyles would contribute to dementia prevention among the elderly residing in endemic communities.
Are Chlamydia Trachomatis and Neisseria Gonorrhoeae Screenings in Pregnant Women Being Properly Performed? A Single-Center Retrospective Observational Study in Italy
Authors: Mondì Vito , Caravetta Jacopo , Paolillo Piermichele , Salce Nicola , Tzialla Chryssoula , Vasapollo Barbara , Valensise Herbert , Bedetta Manuela , Picone Simonetta
Published: July 2024

A new Italian intersociety position statement on the prevention of ophthalmia neonatorum was published in 2023. In this document, attention was paid to the indications for the screening of gonococcal and chlamydial infections during pregnancy according to the international and national guidelines for the prevention of sexually transmitted infections (STIs). We conducted an observational retrospective study to assess whether the current guidelines for the prevention of STIs are being followed correctly. From February to August 2022, 2507 women nearing childbirth were enrolled. Among them, 42.4% received a swab for Chlamydia and only 0.5% for gonococcus. Concerning the geographical area of origin, most of the screened women came from Western Europe. None of the women who received gonococcal swabs and only 105 women out of 1062 screened for Chlamydia were under 25 years of age. Overall, only seven swabs were positive for Chlamydia, while none were positive for gonococcus. Concerning the age, geographical area of origin, and medical history of the women with a positive screening for Chlamydia, all were over 25 years old, six were from Western Europe, one was from South America, and none had other STIs. Although monocentric in nature, this study shows that the guidelines are not being followed correctly.