bluuebunny/crossref_metadata_2025 huggingface dataset:
PENYULUHAN GIZI PADA ANAK UNTUK PENCEGAHAN STUNTING DI KAMPUNG TENGGHER, KABUPATEN SAMPANG
Authors: Zulkarnain Fathurrozi Wali , Agustina Tri Siwi Agustina , Putri Daisyandini Hedianti , Busthomi Imam , Sonia Febby
Published: November 2022

Stunting adalah salah satu permasalahan besar yang dialami oleh kabupaten Sampang. Kabupaten Sampang adalah wilayah dengan tingkat prevalensi stunting tertinggi di provinsi Jawa Timur pada tahun 2018. Sebagai masyarakat terpelajar, para mahasiswa program Magister Pengembangan Sumber Daya Manusia (PSDM) Universitas Airlangga memiliki tanggung jawab untuk memberikan sumbangsih positif pada masyarakat. Para mahasiswa Magister PSDM ini bekerjasama dengan komunitas Senyum Untuk Desa (SUD) menyelenggarakan pengabdian masyarakat di Kampung Tenggher, Desa Banjar, Kecamatan Kedungdung, Kabupaten Sampang. Salah satu program yang diselenggarakan adalah penyuluhan gizi pada masyarakat Kampung Tenggher. Dengan menyelenggarakan kegiatan ini, pemateri dapat memberikan edukasi tentang pentingnya Makanan Pengganti Air Susu Ibu (MPASI) pada para ibu muda. Selain itu, kegiatan penyuluhan gizi dapat mengungkap faktor-faktor yang berpengaruh terhadap timbulnya stunting pada balita dari masyarakat secara langsung. Faktor-faktor ini nantinya dapat membantu identifikasi kondisi wilayah sekitar. Hasil analisis dari penemuan ini dapat dimanfaatkan untuk memberikan saran dan rekomendasi perbaikan untuk mengurangi tingkat prevalensi stunting balita kepada pemerintah Kabupaten Sampang.
PEMBERDAYAAN EKONOMI RUMAH TANGGA MELALUI PRODUKSI MASKER KAIN DI MASA PANDEMI COVID-19
Authors: Immanuela Intan , Dani Robik Anwar
Published: November 2022

Pemberdayaan sangat diperlukan utamanya pada masa sulit seperti saat ini yaitu masa Pandemi Covid-19. Pemberdayaan unutk meningkatan kulaitas diri dan keluarga dapat dilakukan dengan kemampuan mengisi peluang usaha terutama di masa pandemi ini. salah satu peluang usaha yang dapat dilakukan adalah dengan usaha/ bisnis masker dari kain. Kegiatan pemberdayaan kepada masyarakat ini memiliki tujuan sebagai berikut: 1). Membantu menciptakan keterampilan dan kenyamanan dalam kehidupan bermasyarakat melalui usaha/bisnis produk masker kain. 2) Membantu mitra melalui pendampingan psikologis untuk memiliki rasa percaya diri dan memiliki jiwa entrepreneurship. 3). Membantu mengembangkan mitra untuk tetap memiliki pendapatan keluarga ditengah Covid-19 melalui usaha produk masker kain dengan menyediakan alat bantu memproses produk masker kain. 4). Membantu mitra dengan edukasi penentuan harga jual produk masker kain dan pemasaran melalui medsos. Metode yang dilakukan unutk mencapai tujuan tersebut adalah dengan melakukan pelatiham pembuatan masker kain, pengadaan alat bantu proses produksi masker kain, pendampingan ranah psikologis untuk membentuk mental wirausaha yang tahan banting, kreatif, dan mampu melihat peluang, dan edukasi penentuan harga jual masker kain pemasaran melalui media sosial.
PELATIHAN PERHITUNGAN PAJAK PENGHASILAN PASAL 21 PADA STAI AL FITHRAH SURABAYA
Authors: Nugraheni Ratna , Qonitah Iffah , Kristiawan Agung
Published: November 2022

Pajak adalah salah satu bentuk iuran dari rakyat kepada negara dengan dapat dipaksakan dan berdasarkan undang-undang, digunakan untuk membiayai pengeluaran-pengeluaran negara. Sebagai wajib pajak hendaknya kita taat terhadap peratutan dan perundang-undangan perpajakan. Kepatuhan tersebut dapat dilakukan dengn pemenuhan kewajiban perpajakan. Untuk melakukan pemenuhan kewajiban perpajakan tersebut adalah dengan cara menghitung, membayar dan melaporkan jumlah pajak yang terutang. Tujuan kegiatan pengabdian adalah untuk memberikan pengetahuan tentang perpajakan terutama pengetahuan tentang cara menghitung pajak penghasilan pasal 21 pada Sekolah Tinggi Agama Islam (STAI) Al Fithrah Surabaya. Kegiatan ini dimaksudkan untuk membantu pihak STAI Al Fithrah yakni santri dan santriwati dalam menghitung jumlah pajak penghasilan pasal 21 yang terutang. Dengan perhitungan pajak penghasilan yang telah sesuai peraturan dan perundangan-undangan pajak yang berlaku maka santri dan santriwati Sekolah Tinggi Agama Islam (STAI) Al Fithrah Surabaya dapat melaporkan jumlah pajak yang terutang dengan benar. Metode yang digunakan dalam membe-rikan solusi   adalah: 1) penyampaian materi, 2) berdiskusi serta, 3) pelatihan menggunakan kertas kerja manual dan menggunakan program excel.
The Use of Tobit and Logistic Regression Models to Study Factors that Affect Blood Pressure in Cardiac Patients
Authors: Meran Banaz W. Y. , Sedeeq Bekhal S.
Published: November 2022

This research witnessed using the Tobit and logistic regression models to study the factors that affect blood pressure in cardiac patients. The data have been collected, from 500 patients with heart disease in hospital-heart center - Erbil. The two levels of blood pressure, low and high blood pressures, were taken from the patients, as dependent variables and some, independent variables (Gender, Age, Urea, Cholesterol, Creatinine, and Weight). The researcher found that the median of blood pressure by means of arterial pressure (MAP) equation contains each of high and low blood pressures differently because the threshold point was determined to be (99.33), which is equal to,12/8 mmHg, which is the normal amount of blood pressure. The aim of this research is to explain the main concepts and processes of Tobit regression analysis (Censored- and Truncated) and logistic regression analysis, which is used for knowing which factors of independent variables has more effect on the response variables (blood pressure), and to compare the outcomes of the two models (Tobit regression and logistic regression) in order to determine which of the models best fits our data in which AIC and BIC are used. The researcher reached a conclusion that the logistic regression model best fits our data compared with Tobit regression, and it arrived at the results obtained by utilizing the statistical packages in R programming, MATLAB and Statistical Packages of Social Sciences (SPSS) V.26, which was used to analyze data from our research
Monitoring Effects of Lockdown During Covid-19 Pandemic Towards the Air Pollution in Southeast Asia
Authors:   School of Civil Engineering, College of Engineering, Universiti Teknologi MARA, Shamshudin Nurul Fathimah , Daud Nurul Rabitah ,   School of Civil Engineering, College of Engineering, Universiti Teknologi MARA
Published: November 2022

This research explores one of the most serious environmental threats to human health which is air pollution. The objective of this study is to examine the concentration of several air pollutants that has been affecting the atmosphere specifically in Southeast Asia after the emergence of the pandemic. Throughout this research, the air pollution concentration is monitored using several observation satellites such as NASA GIOVANNI, Ozone Monitoring Instrument (OMI), and MODIS-Aqua to see the difference in air quality before and after the lockdown was implemented in the selected specific area. The average mean for the studied year of each selected pollutant was also observed to see the pattern of the air quality after the pandemic. Thailand and other northern Southeast Asian nations bordering China were found to be the most affected by transboundary pollution, which was brought on by the climatological changes that all Southeast Asian countries experienced. In addition, most Southeast Asian nations are regarded as developing countries that rely significantly on power produced by fossil fuels and individual transportation. Consequently, it significantly worsens the air pollution in the area. This study is significant as it allows the government to regulate the air quality in a specific region and it is important to monitor the air pollution in the atmosphere as it has a substantial impact on human health as well as the environment. By conducting this study, it can be seen that there are major positive changes in air quality in Southeast Asia as it is the result of the lockdown and lack of human activities in each countr
Karolina Zygmunt, Viajar y escribir en la era del turismo de masas. Relatos de viajes contemporáneos por la Ruta de la Seda
Authors: Rubio Martín María
Published: November 2022

Resumen
Antonio Orejudo Utrilla, Narrativa utópica contemporánea, Valladolid, Cátedra Miguel Delibes (Universidad de Valladolid-Graduate Center de CUNY)
Authors: Alonso Nicolás Noemí
Published: November 2022

Resumen
MOTIVASI SUBSCRIBER DALAM MENONTON CHANNEL YOUTUBE GADGETIN
Authors: Setyawan Sidiq , Putra Rizky Andika
Published: November 2022

Kajian motif menonton atau mengonsumsi konten Youtube merupakan dorongan yang menggerakkan seseorang dan bersumber pada suatu kebutuhan yang harus dipenuhi, jadi motivasi itu muncul dari kesadaran diri sendiri dengan tujuan secara esensial yang didapatkan dengan menonton channel Youtube tertentu dalam hal ini GadgetIn. Tujuan penelitian ini ingin mengetahui bagaimana motivasi menonton channel GadgetIn oleh subscriber ditinjau dengan pendekatan teori motivasi yaitu passing time, enjoyment, relaxation, information, dan excitement. Metode pada penelitian ini menggunakan pendekatan deskriptif kualitatif yang menemukan hasil yakni adanya keterkaitan dengan motivasi enjoyment, relaxation, dan excitement. Motif lain seperti companionship, social interaction, dan escape bukanlah merupakan motif yang menjadikan mereka melihat kanal Youtube tersebut. Penelitian ini juga menunjukkan bahwa passing time tidak menjamin bahwa pengguna media sosial akan mendapatkan kepuasan didalamnya tanpa menemukan apa yang mereka butuhkan atau cari. Sedangkan motif companionship, social interaction atau tentang percakapan, ekspresi ide yang spontan dan informal, menempati ruang dalam baik pikiran partisipan maupun dalam ranah sosial yang telah diberikan ruang oleh Youtube dengan kolom komentar disetiap videonya tidak menjadikan suatu yang terlalu diminati oleh para subscriber dari channel Youtube GadgetIn.
Polygonal linear depressions in the Coconino Sandstone (Permian) of Arizona, and their relevance for interpreting paleoenvironment
Authors: Brand Leonard R.
Published: November 2022

Polygonal “cracks” are common in the Coconino Sandstone in Arizona. They have been called desiccation cracks, but several features indicate they are not desiccation cracks. They were never open cracks, but are merely linear depressions, linked to form polygons. They occur only on bounding surfaces, containing almost no clay, and the cracks extend 10 to 15 cm above and below the bounding surfaces. The polygonal patterns continue down from one sandstone lamina to another, for several centimeters. They are persistently continuous across all surfaces within their 20–30 cm vertical range, from the bottomset beds, onto the bounding surface, and continuing into individual cross-beds below the bounding surface. The cracks occur at the Grand Canyon, and are especially numerous and visible in flagstone quarries in the Seligman and Ash Fork area. They occur on some bounding surfaces but not on others, and in some quarries but not in others. The polygonal cracks have been mentioned in passing, but this is the first reported research on these cracks in the Coconino Sandstone. Polygonal cracks have been reported in the Navajo, Page, and Entrada Sandstones, but there are significant differences between these and the Coconino Sandstone cracks, which may indicate differences in their origin.
Non-seroconversion in an HIV-tuberculosis co-infected patient-case report
Authors: Kanani Fatima , Asher Nadia , Zubairy Maliha
Published: November 2022

Background:

Most cases of negative serology in proven human immunodeficiency virus (HIV) patients occur due to testing during the window period. However, true non-seroconversion is a phenomenon that should always be considered.

Case Presentation:

A 13-year-old female with a family history of multi-drug resistant tuberculosis (MDR-TB) presented with cough without fever for 1 month. She was vitally stable and the physical examination was unremarkable. Chest X-ray was suggestive of active TB, sputum positive for acid-fast bacilli, and GeneXpert positive for Mycobacterium tuberculosis. Her HIV RNA polymerase chain reaction (PCR) was positive at 28,866 IU/ml. She was registered as presumed MDR-TB and started on anti-tuberculosis treatment. Serum specimen sent inadvertently 6 weeks later was positive for HIV- p24 antigen while negative for anti-HIV 1/2 on Determine HIV Early Detect fourth generation lateral flow assay. A fresh specimen 2 weeks later showed similar results and was also negative by Alinity HIV Ag/antibody Combo (Abbott Diagnostics) and Bio-Rad Geenius HIV-1/2 Supplemental Assay. HIV antibodies were still negative at 20 weeks (5 months) after positive PCR.

Conclusion:

This is a case of a seronegative HIV/TB co-infected patient. Non-seroconversion should always be considered in patients with clinical suspicion and discordant results.
Titrimetric methods for determining cationic surfactants
Authors: Blazheyevskіy Mykola Ye. , Bulska Ewa J. , Tupys Andrii M. , Koval’ska Olena V.
Published: November 2022

Aim. To generalize and systematize information on titrimetric methods for determining quaternary ammonium compounds (QACs).Results and discussion. The review summarizes and systematizes information on the properties of surfactants, provides their classification, shows the main ways of use in the national economy, and their role in pharmacy and medicine. Currently known titrimetric methods for determining cationic surfactants (СS), in particular quaternary ammonium compounds, which are widely used in medicine and pharmacy, are described and summarized.Conclusions. As a result of the study, the main directions of developing methods for determining QACs by titrimetry methods have been summarized; the disadvantages and advantages of each of the methods described have been shown. In the future, it can be the basis for developing new and more effective methods of analysis.
The study of the elemental and amino acid composition of Cetraria islandica (L.) Ach. thalli batches harvested in Ukraine
Authors: Shpychak Alina O. , Khvorost Olga P.
Published: November 2022

Aim. To study the elemental and amino acid composition of Cetraria islandica (L.) Ach. thalli batches harvested in Ukraine.Materials and methods. Seven batches of C. islandica thalli harvested in different regions of Ukraine in late summer/early fall 2019 were used for the study. The elemental composition of the raw material was studied by atomic absorption spectrometry with photographic registration. The component composition of free and bound amino acids in the raw material was determined by the HPLC method. Results and discussion. The presence of at least 19 macro-, trace and ultra-trace elements was determined in 7 batches of the raw material. The predominance of the following elements was found: potassium 190 mg/100 g (batch 6) – 325 mg/100 g (batch 7); silicon 30 mg/100 g (batch 1) – 115 mg/100 g (batch 4); calcium 37 mg/100 g (batch 6) – 86 mg/100 g (batch 4). It was determined that the quantitative content of molybdenum and cobalt did not exceed 0.03 mg/100 g, the content of cadmium, astatine and mercury did not exceed 0.01 mg/100 g. The quantitative content of lead met the requirements of the monograph of the State Pharmacopoeia of Ukraine (SPhU) 2.0. The total ash content in the batches of the raw material ranged from 0.61 ± 0.02 % to 1.43 ± 0.05 %, meeting the requirements of the monograph of the SPhU 2.0. The presence of 7 amino acids was determined; 5 of them were nonessential (aspartic and glutamic acids, serine, arginine, and alanine) and 2 were essential (threonine and valine). The quantitative content of the total amount of free amino acids was 0.794 μg mg-1, the total amount of bound ones was 3.276 μg mg-1.Conclusions. For the first time, the elemental composition of 7 batches of C. islandica thalli harvested in Ukraine was determined. In each batch, potassium was the predominant element (from 190 mg/100 g to 325 mg/100 g depending on the batch). The component composition of free and bound nonessential and essential amino acids was determined (the quantitative content of the total amount of free amino acids was 0.794 μg mg-1, the total amount of bound ones was 3.276 μg mg-1); alanine (0.289 μg mg-1) was the dominant component among free amino acids, while arginine (0.993 μg mg-1) prevailed among bound ones. The results obtained will be used for further studies of the raw material of C. islandica harvested in Ukraine.
The synthesis of N-substituted 4-fluoro-1,8-naphthalimides
Authors: Fedko Nadiia F. , Anikin Valeriy F. , Veduta Vira V.
Published: November 2022

Aim. To synthesize 4-fluoro-1,8-naphthalic acid imide and its derivatives substituted in the imide ring.Results and discussion. 4-Fluoro-1,8-naphthalimide was obtained using acenaphthene as the starting material. N-alkyl-4-fluoro-1,8-naphthalimides were synthesized via the phase transfer catalytic alkylation of 4-fluoro-1,8-naphthalimide with haloalkanes. Imidation of 4-fluoro-1,8-naphthalic anhydride with aminoacids resulted in the formation of N-carboxyalkyl-1,8-naphthalimides. These substances can be considered as potential fluorescent labels capable of binding to amino groups of various biological molecules as they contain carboxylic functionality in their structure.Experimental part. The structure of the compounds synthesized was confirmed by FT-IR, 1H NMR and 13C NMR spectroscopy, and mass-spectrometry.Conclusions. It has been shown that 4-fluoro-1,8-naphthalinedicarboxylic acid imide can be obtained following the synthetic route “acenaphthene – 5-fluoroacenaphthene – 4-fluoro-1,8-naphthalic anhydride – 4-fluoro-1,8-naphthalimide”. 4-Fluoro-1,8-naphthalimide can be alkylated by butyl iodide and octyl bromide using tetraalkylammonium salts as a phase transfer catalyst resulted in N-butyl-4-fluoro-1,8-naphthalimide and N-octyl-4-fluoro-1,8-naphthalimide. As a result, N-carboxyalkyl-4-fluoro-1,8-naphthalimides have been obtained for the first time by aminolysis of 4-fluoro-1,8-naphthalic anhydride with glycine, β-alanine and 6-aminocaproic acid.
N-Difluoromethylindazoles
Authors: Petko Kirill I. , Filatov Andrey A.
Published: November 2022

Aim. To study the possibility of the N-difluoromethylation and separation of 1-difluoromethyl and 2-difluoromethyl isomers of C-substituted indazoles, as well as some possibilities of functionalization of such molecules.Results and discussion. The N-difluoromethylation of indazole derivatives containing bromine, iodine, and nitro groups in various positions of the heterocyclic ring was studied. In all cases, the conditions for the separation of isomers – N-difluoromethylation products – in positions 1 and 2 were found. The corresponding amines, esters of carboxylic and boric acids were obtained as a result of further functionalization of 1- and 2-difluoromethylindazole derivatives.Experimental part. The structure of the compounds synthesized was proven by 1H and 19F NMR spectroscopy methods, as well as by the elemental analysis. The structure of isomeric difluoromethylindazoles was finally confirmed by the SELNOESY and 1H-13C HMBC experiments.Conclusions. A convenient method for the difluoromethylation of substituted indazoles has been found; difluoromethyl derivatives in positions 1 and 2 of the indazole ring have been obtained in high yields. The method for the efficient separation of isomeric difluoromethylindazoles has been found; some possibilities of their further functionalization have been described.
Experience of Material Incentives for Workers of Military Factories in the Early Years of the NEP (on the Example of the Tula Cartridge Factory)
Authors: Volodin Sergei Filippovich
Published: November 2022

Based on the methodology of the activity approach, the article examines the processes of material incentives for workers in the early years of the NEP. It deals in detail with the issues of material incentives for workers in the conditions of the NEP economy on the example of a large industrial enterprise - the Tula Cartridge Factory. How did the gradual tightening of rationing took place at this time? How did this process affected different groups of workers? What practices at the workshop level were used to regulate earnings? The purpose of the article is to clarify these and other interrelated issues affecting the stimulation of labor. In his research, the author proceeded from the principle of historicism and the methodology of the activity approach, according to which attention is focused on the practical activities of people, the mechanisms of their interaction.      The scientific novelty of the study is determined by the fact that it comprehensively highlights the process of organizing financial incentives for employees at a large military enterprise in the early period of the NEP, which is of particular relevance in the context of modern challenges. In the initial period of the NEP, the Tula Cartridge Factory underwent a general improvement of production processes. An important part of this work was to restore the effectiveness of material incentives in relation to labor productivity, primarily by increasing production standards. As it appears on the example of the TPZ, within the historical context of the early NEP, a relatively acceptable level of material incentives for industrial labor was achieved in Soviet industry.
EARNINGS MANAGEMENT DI INDONESIA: SEBUAH STUDI LITERATUR
Authors: Alexandra Celine , Lionardi Margaretha , Jennefer Sanchian , Lim William , Meiden Carmel
Published: November 2022

This study describes the evolution of earnings management research in Indonesia taken from journals studied in Indonesia and indexed with sinta 1-3 with the research year 2018-2021. The purpose of research is to add and develop research or articles on earnings management contained in journals in Indonesia. The sample was obtained as many as 23 articles. The research categorizes articles based on research years, research variables, research analysis methods, research theory, research types, research sectors, and research models contained in the articles. The research method used is a systematic literature review. From this literary study, we can conclude that research related to earnings management have decreased in the year 2021, the commonly used variable is leverage, the research method mostly used is multiple linear regression, generally used theory is agency theory, type of earnings management study normally used is quantitative, manufacture sector is often used research sector, and modified jones model by DeChow et al. is commonly used for measuring earnings management.
PENGARUH PENGUNGKAPAN SUSTAINABILITY REPORT, LEVERAGE DAN ACTIVITY TERHADAP KINERJA PERUSAHAAN
Authors: Anabella Anabella , Siregar Anitaria
Published: November 2022

The purpose of this research is to investigate the the influence of economic, environment and social part of sustainability report disclosures, leverage and activity towards the firm performance. The sample of this research is 15 company with sub- sector mining, agricultural and energy which registered in Indonesia Stock Exchange from period 2017 – 2019. This research uses IBM SPSS 27. The result shown that social part of sustainability report disclosures and activity influence the firm performance. Economic and environment part of sustainability report disclosures and leverage do not influnce the firm performance.
Association between Physical Activity Level and Sleep Quality in the Elderly
Authors: Dwi Cahya Nesya Kartika , Rika Ignatio
Published: November 2022

Introduction: The increase in a person’s age may cause degeneration in their physiological system, and these changes can affect various bodily functions, one of them is the sleep-wake cycle. The elderly usually have disturbed sleep-wake circadian rhythm that can cause sleep problems and decreased sleep quality. The action that can be done to increase sleep quality is doing physical activity.

Methods: This research used cross-sectional study design. The respondents were people who reside in Komplek Taman Pulo Indah and Perumahan Aneka Elok aged 60 and older and were not included in the exclusion criteria (n = 204). The instruments used were the Baecke questionnaire to measure physical activity level and the PSQI questionnaire to measure sleep quality. Data analysis was done in univariate and bivariate using chi-square test with significance level of p<0.005.

Results: The prevalence of elderly with low physical activity levels and good sleep quality was 33.8%. Meanwhile, elderly with moderate physical activity levels and good sleep quality was 50%, and elderly with high physical activity levels and good sleep quality was 64,7%. Chi-square test was carried out and resulted in p = 0.002 (p<0.005), which meant the null hypothesis was rejected. 

Conclusions: There was an association between physical activity level and sleep quality in the elderly.
Improving the quality of training of future sociologists by means of digital education
Authors: Сегал М.С. , Куц А.В. , Фирсов В.С.
Published: November 2022

Несмотря на существование «различных моделей профессиональной подготовки в европейских учреждениях высшего образования, формирование профессиональных качеств является одной из главных задач, которая решается благодаря прикладной направленности содержания образования, интеграции учебных дисциплин, большому объему практики, применению активных методов обучения: тренингов, учебных мастерских, методов кооперативного обучения» и преимуществ современного учебного цифрового пространства. Опыт профессиональной подготовки будущего социолога в России освещает недостаточную направленность учебных планов и программ на формирование профессиональных качеств, доминирование традиционного обучения, ориентированного прежде всего на овладение системе социологических знаний, умений и навыков. Следовательно, направление отечественной профессиональной подготовки будущего социолога на формирование профессиональных качеств является необходимым условием интеграции в европейское образовательное пространство и конкурентоспособности будущих специалистов. Именно об этом свидетельствует осуществленный сравнительный анализ опыта профессиональной подготовки будущего социолога в ведущих европейских и отечественных учреждениях высшего образования.

Despite the existence of "various models of vocational training in European institutions of higher education, the formation of professional qualities is one of the main tasks that is solved due to the applied orientation of the content of education, the integration of academic disciplines, a large amount of practice, the use of active teaching methods: trainings, training workshops, cooperative learning methods" and the advantages of the modern educational digital space. The experience of professional training of a future sociologist in Russia highlights the insufficient focus of curricula and programs on the formation of professional qualities, the dominance of traditional education, focused primarily on mastering the system of sociological knowledge, skills and abilities. Consequently, the direction of the national professional training of the future sociologist on the formation of professional qualities is a necessary condition for integration into the European educational space and the competitiveness of future specialists. This is evidenced by the comparative analysis of the experience of professional training of a future sociologist in leading European and domestic institutions of higher education.
The first Russian educational books on the French language: the aspect of retroinnovations
Authors: Колобкова А.А. , Турянская О.Ф.
Published: November 2022

В статье рассмотрены учебные франкоязычные книги, изданные в России в XVIII ‒ первой половине XIX века в аспекте ретроинноваций. Определено значение понятия «ретроинновация», выделены этапы распространения ретроинноваций в образовательной системе Российской Федерации. Проанализирована эволюция учебных книг по французскому языку на протяжении XVIII ‒ первой половины XIX века. Сопоставлены методы и функции старинных учебных книг и современные требования к учебным изданиям. Определен ретроинновационный потенциал учебных книг прошлых веков.

The article examines the educational French‒language books published in Russia in the XVIII - first half of the XIX century in the aspect of retroinnovations. The meaning of the concept of "retroinnovation" is defined, the stages of the spread of retroinnovations in the educational system of the Russian Federation are highlighted. The evolution of educational books on the French language during the XVIII ‒ first half of the XIX century is analyzed. The methods and functions of ancient educational books and modern requirements for educational publications are compared. The retro innovative potential of educational books of the past centuries has been determined.
The role of student self-government in the innovative management of the university
Authors: Сегал М.С. , Куц А.В. , Фирсов В.С.
Published: November 2022

Студенческое самоуправление в современных высших учебных заведениях (вузах) имеет достаточно развитую структуру, многоаспектные формы выявления на разных уровнях. Органы студенческого самоуправления осуществляют свою деятельность на уровне группы, факультета, общежития, студенческого городка и высшего учебного заведения. В то же время существуют студенческие научные общества, научные кружки, клубы по интересам и другие формы студенческого самоуправления. Для понимания сущности студенческого самоуправления как элемента в системе управления учебным заведением, что имеет свои функции, субъекты и задачи и предстает надежным фундаментом, практической базой становления навыков самоорганизации, самоуправления, принятия управленческих решений важно выявить характеристики отдельных аспектов активности студенчества как личностного способа удовлетворения потребностей в соответствии с собственной позиции. В современной системе образования органы студенческого самоуправления на законодательном уровне имеют широкий спектр прав и возможностей по участию в управлении вузов, а именно: участие в ученых советах факультета и Университета, организация и проведение научных, культурно-массовых, спортивных, оздоровительных и других мероприятий, содействие трудоустройству студентов и тому подобное. В то же время, по согласованию с органами студенческого самоуправления принимаются решения об отчислении, восстановлении, переводе, поселении лиц, обучающихся в высшем учебном заведении.

Student self-government in modern higher educational institutions (universities) has a sufficiently developed structure, multidimensional forms of identification at different levels. Student self-government bodies carry out their activities at the level of a group, faculty, dormitory, campus and higher educational institution. At the same time, there are student scientific societies, scientific circles, interest clubs and other forms of student self-government. To understand the essence of student self-government as an element in the management system of an educational institution, which has its own functions, subjects and tasks and appears as a reliable foundation, a practical basis for the formation of skills of self-organization, self-management, and managerial decision-making, it is important to identify the characteristics of individual aspects of student activity as a personal way of meeting needs in accordance with one's own position. In the modern education system, student self-government bodies at the legislative level have a wide range of rights and opportunities to participate in the management of universities, namely: participation in academic councils of the faculty and University, organization and conduct of scientific, cultural, sports, recreational and other events, assistance in the employment of students and the like. At the same time, in coordination with the student self-government bodies, decisions are made on the expulsion, restoration, transfer, settlement of persons studying at a higher educational institution.
Prevention of suicidal behavior of military personnel
Authors: Иванова О.П. , Мамедова Л.В.
Published: November 2022

Роль числа самоубийств в военных частях вызывает тревогу и озабоченность командирования, Анализ статистических данных свидетельствует, о том, что несмотря на применяемые меры, добиться устойчивого сокращения числа самоубийств (далее по тексту С) не удается, а в последнее время наметилась тенденция к их увеличению. Командиры и начальники упрощенно, часто субъективно подходят к оценке факторов (С), пытаются отнести его причины к негативным характеристикам военнослужащих, семейным неурядицам, экономическим трудностям, без связи реальным положением дел в части, организацией учебно-воспитательного процесса и социально-психологическим климатом в воинских подразделениях. Актуальность данной статьи, заключается в том, что большинство фактов (С) совершенно психически здоровыми людьми, под воздействием жизненных и служебных ситуаций, своевременное знание которых и грамотное реагирование со стороны командиров и специалистов социально-психологических служб (далее по тексту СПС), а также товарищей по службе могли бы уберечь людей от этого рокового шага. Одной из важнейших задач в деятельности командиров и специалистов СПС является своевременное выявление военнослужащих с отклоняющимся поведением. Особое место занимает проблема определения лиц, склонным к суицидальному поведению.

The role of the number of suicides in military units causes alarm and concern of the secondment, The analysis of statistical data shows that despite the measures taken, it is not possible to achieve a steady reduction in the number of suicides (hereinafter referred to as C), and recently there has been a tendency to increase them. Commanders and superiors simplistically, often subjectively approach the assessment of factors (C), try to attribute its causes to negative characteristics of military personnel, family troubles, economic difficulties, without connection with the real state of affairs in the unit, the organization of the educational process and the socio-psychological climate in military units. The relevance of this article lies in the fact that most of the facts (C) are completely mentally healthy people, under the influence of life and service situations, timely knowledge of which and competent response from commanders and specialists of socio-psychological services (hereinafter referred to as PCA), as well as comrades.
Digital determinants of trends in the training of industrial specialists
Authors: Двоеглазов С.И. , Забайкин Ю.В.
Published: November 2022

Новая эпоха цифровизации, в которую стремительно вошел мир, результаты четвертой промышленной революции ("Индустрия 4.0") вносят радикальные коррективы в традиционный уклад жизни, кардинально трансформируя общество. Перемещение аналоговых операций в интернет- пространство, развитие цифровой среды, замена классических моделей управления и бизнес-процессов цифровыми продуцируют качественно новый формат промышленного производства, раскрывая новые возможности персонализации предложений для каждого клиента. Процессы цифровизации и роботизации, обусловливая появление уникальных систем и процессов, являются императивом современного глобализированного мира. Цифровые технологии меняют практически все сферы жизни, составляют их новую ценностную сущность, способствуют росту эффективности и производительности труда, параллельно уменьшая спрос на человеческий ресурс. Согласно отчету об охвате цифровизации (Digita lSpillover) к 2023 г. будет оцифровано более 60% мирового ВВП. Ориентировочные 70% новой стоимости, созданной в экономике в течение следующего десятилетия, будут базироваться на платформах с цифровой поддержкой. Глобальный центр инфраструктуры оценивает глобальный дефицит финансирования почти в 1 трлн долл. США на инфраструктуру информационных и коммуникационных технологий до 2040 г.

The new era of digitalization, into which the world has rapidly entered, the results of the fourth industrial revolution ("Industry 4.0") are making radical adjustments to the traditional way of life, radically transforming society. The transfer of analog operations to the Internet space, the development of the digital environment, the replacement of classical management models and business processes with digital ones produce a qualitatively new format of industrial production, revealing new opportunities for personalization of offers for each client. The processes of digitalization and robotization, causing the emergence of unique systems and processes, are an imperative of the modern globalized world. Digital technologies are changing almost all spheres of life, constitute their new value essence, contribute to the growth of efficiency and labor productivity, while simultaneously reducing the demand for human resources. According to the Digitalization Coverage Report (Digita lSpillover), more than 60% of global GDP will be digitized by 2023. An estimated 70% of the new value created in the economy over the next decade will be based on digitally enabled platforms. The Global Infrastructure Center estimates a global funding shortfall of almost $1 trillion for information and communication technology infrastructure through 2040.
Mixed-Ligand Assisted Direct Synthesis of Redox-Active UiO-66-(SH)2 Metal Organic Frameworks and Their Behavioural Pattern in Reductive and Oxidative Environments
Authors: Chowdhury Sumanta , Sharma Parul , Kundu Koustav , Das Partha Pratim , Rathi Preeti , Siril Prem Felix
Published: November 2022

Synthesis, storage, and characterization of thiol functionalized metal-organic frameworks (MOFs) is highly challenging. However, they continue to be of great interest due to their broad spectrum of applications. In this work, for the first time, a solid solution approach has been adopted to dilute the thiol content in UiO-66-(SH)2 [Universitetet i Oslo] MOF by terephthalic acid linker without influencing its topology. The solid dilution had an overall impact on the crystallinity, defects, porosity and particle size of the UiO-66-(SH)2 framework. This study has the potential to significantly influence the syntheses of nanoscale thiol functionalized MOF materials and their applications in photocatalysis, water purification and drug delivery. This work also incorporates the performance study of the mixed-linker thiol MOFs under reductive and oxidative conditions. The rate of para-nitrophenolate hydrogenation under reductive conditions were mainly governed by the stability of the mixed-linker MOFs as catalyst supports. Whereas, post synthetic oxidation (PSO) was used to produce sulfonic acid tagged mixed-linker UiO-66 frameworks to probe the behavioral pattern in oxidative conditions of the parent mixed-linker thiol MOFs. The mixed-linker strategy was critical in preventing the frameworks from losing their crystallinity and porosity, upon oxidation. Thus, this work also paves the way for a general strategy to impart stability to thiol tagged UiO-66 framework having wide ranging applications.
Elementary Decomposition Mechanisms of Lithium Hexafluorophosphate in Battery Electrolytes and Interphases
Authors: Spotte-Smith Evan , Petrocelli Thea , Patel Hetal , Blau Samuel , Persson Kristin
Published: November 2022

Electrolyte decomposition constitutes an outstanding challenge to long-life Li-ion batteries (LIBs) as well as emergent energy storage technologies, contributing to protection via solid electrolyte interphase (SEI) formation and irreversible capacity loss over a battery's life. Major strides have been made to understand the breakdown of common LIB solvents; however, salt decomposition mechanisms remain elusive. In this work, we use density functional theory to explain the decomposition of lithium hexafluorophosphate (LiPF6) salt under SEI formation conditions. Our results suggest that LiPF6 forms POF3 primarily through rapid chemical reactions with Li2CO3, while hydrolysis should be kinetically limited at moderate temperatures. We further identify selectivity in the proposed autocatalysis of POF3, finding that POF3 preferentially reacts with highly anionic oxygens. These results provide a means of interphase design in LIBs, indicating that LiPF6 reactivity may be controlled by varying the abundance or distribution of inorganic carbonate species or by limiting the transport of PF6- through the SEI.
Computational Characterization of the Inhibition Mechanism of Xanthine Oxidoreductase by Topiroxostat
Authors: Maghsoud Yazdan , Dong Chao , Cisneros G. Andrés
Published: November 2022

Xanthine oxidase (XO) is a member of the molybdopterin-containing enzyme family. It interconverts xanthine to uric acid as the last step of purine catabolism in the human body. The high uric acid concentration in the blood directly leads to human diseases like gout and hyperuricemia. Therefore, drugs that inhibit the biosynthesis of uric acid by human XO have been clinically used for many years to decrease the concentration of uric acid in the blood. In this study, the inhibition mechanism of XO and a new promising drug, Topiroxostat (code: FYX-051), is investigated by employing molecular dynamics (MD) and quantum mechanics/molecular mechanics (QM/MM) calculations. This drug has been reported to act as both a non-covalent and covalent inhibitor and undergoes a stepwise inhibition by all its hydroxylated metabolites, which include 2-hydroxy-FYX-051, dihydroxy-FYX-051, and trihydroxy-FYX-051. However, the detailed mechanism of inhibition of each metabolite remains elusive and can be useful for designing more effective drugs with similar inhibition functions. Hence, herein we present the computational investigation of the structural and dynamical effects of FYX-051 and the calculated reaction mechanism for all the oxidation steps catalyzed by the molybdopterin center in the active site. Calculated results for the proposed reaction mechanisms for each metabolite’s inhibition reaction in the enzyme’s active site, binding affinities, and the non-covalent interactions with surrounding amino acid residues are consistent with previously reported experimental findings. Analysis of the non-covalent interactions via EDA and NCI suggests residues L648, K771, E802, R839, L873, R880, R912, F914, F1009, L1014, and A1079 can be used as key interacting residues for further hybrid-type inhibitor development.
Co-crystals of NHC Au(I) Aryl Complexes with Iodoperfluoroarenes as a Platform for the Study of Au(I) Involving Halogen Bonding
Authors: Mikherdov Alexander , Jin Mingoo , Ito Hajime
Published: November 2022

Among the known types of non-covalent interactions with Au(I) metal center, Au(I) involving halogen bonding (XB) remains a rare phenomenon that has not been studied systematically. Herein, using five N-heterocyclic carbene (NHC) Au(I) aryl complexes and two iodoperfluoroarenes as XB donors, we demonstrated that the XB involving the Au(I) metal center can be predictably obtained for neutral Au(I) complexes using the example of nine co-crystals. The presence of XBs involving the Au(I) center was experimentally investigated by single-crystal X-ray diffraction and solid-state 13C CP-MAS NMR methods, and their nature was elucidated through DFT calculations, followed by electron density, electrostatic potential, and orbital analyses. The obtained results revealed the connection between the structure of Au(I) complexes as XB acceptors and the geometrical, electronic, and spectroscopic features of XB interactions, as well as the supramolecular structure of the co-crystals
Computational studies of rubber ozonation explain the effectiveness of 6PPD as an antidegradant and the mechanism of its quinone formation
Authors: Rossomme Elliot , Hart-Cooper William , Orts William , McMahan Colleen , Head-Gordon Martin
Published: November 2022

The discovery that the commercial rubber antidegradant 6PPD reacts with ozone (\ce{O3}) to produce a highly toxic quinone (6PPDQ) spurred a significant research effort into non-toxic alternatives. Identification of non-toxic alternatives has been hampered by lack of a detailed understanding of the mechanism of protection that 6PPD affords rubber compounds against ozone. Herein, we report high-level density functional theory studies into early steps of rubber and PPD ($p$-phenylenediamine) ozonation, identifying key steps that contribute to the antiozonant activity of PPDs. In this, we establish that our density functional theory approach can achieve chemical accuracy for many ozonation reactions, which are notoriously difficult to model. Using adiabatic energy decomposition analysis, we examine and dispel the notion that one-electron charge transfer initiates ozonation in these systems, as is sometimes argued. Instead, we find direct interaction between \ce{O3} and PPD carbon atoms is kinetically accessible, and that this motif is more significant than interactions with PPD nitrogens. The former pathway results in a hydroxylated PPD intermediate, which reacts further with \ce{O3} to afford 6PPD hydroquinone and, ultimately, 6PPDQ. This mechanism directly links the toxicity of 6PPDQ to the antiozonant function of 6PPD. These results have significant implications for development of alternative antiozonants, which are discussed.
On the Question of the Place of Health Value in the System of Value Orientations of an Individual Research
Authors: Bolshakova Anastasia , Perevozna Tetiana , Videnieiev Igor
Published: November 2022

The article presents one of the aspects of a comprehensive study of the system of value formations of an individual. The aim of the article is to study the place of health value in the system of value orientations of an individual with the analysis of the conscious and unconscious attitudes of subjects to this value, as well as their perception of the place of health in the system of significant spheres of life and reality. The following were used: the method of "Value" and "Accessibility" in different spheres of life O.B. Fantalova, Color test of relationships O.M. Etkind and Repertoire J. Kelly's test of role constructs. The study group consisted of 70 people aged 20 to 50 years old. The results of the study show that the value of "health" is an organic component of the value system, which is harmoniously related to work, business qualities, intellectual achievements, material well-being, and personal life. In addition, the subjects recorded a fairly balanced harmonious attitude to the value of health in its conscious and unconscious aspects. At the same time, the value of "health" demonstrates a meaningful connection and interdependence with the values that reflect material well-being and intimate-personal relationships in the "picture of the world" of the subjects. According to the results, in the minds of the subjects between health and values such as intellectual achievement; work and business qualities; the degree of satisfaction with own "I" and the factor of the development of own existence in time, there are certain meaningful connections, but not strong enough in their motivating potential. At the same time, there is a contradiction between the value of health and compliance with social expectations and an active attitude to life. This contradiction reflects the lack of active life position in our society to maintain and increase health as our own life resource. Further study of attitude to the value of health will help to understand the value-based features of individual well-being.
Kasatura Körfezi Tabiatı Koruma Alanı Ciğerotları (Marchantiophyta) Florası
Authors: ŞİMŞEK Özcan , ÜNAL Yasin
Published: November 2022

2022 yılı itibari ile Türkiye’de 2873 sayılı Milli Parklar Kanunu’na göre ilan edilmiş toplamda 31 adet Tabiatı Koruma Alanı bulunmaktadır. Ancak bugüne kadar bu alanların hiçbirinin ciğerotları (Marchantiophyta) florası üzerine araştırma yapılmamıştır. Bu çalışma ile Kırklareli ili Vize ilçesinde bulunan 315 hektar büyüklüğündeki Kasatura Körfezi Tabiatı Koruma Alanı’nın ciğerotları florası araştırılmıştır. 2021 yılı içinde gerçekleştirilen arazi çalışmaları ile alandan 37 ciğerotu örneği toplanmış ve teşhis edilmiştir. Çalışmalar neticesinde tabiatı koruma alanında 11 familyaya ve 11 cinse ait toplamda 13 ciğerotu türü tespit edilmiştir. Tespit edilen türlerin tamamı daha önce A1 karesi ve Kırklareli ilinden bildirilmiş olan türlerdir. Gerçekleştirilen bu çalışma Türkiye’de bir tabiatı koruma alanında yapılan ilk ciğerotu florası araştırması olma niteliği taşımaktadır.