bluuebunny/crossref_metadata_2025 huggingface dataset:
Modeling energy and mass balance of Shallap Glacier, Peru
Authors: Gurgiser W. , Marzeion B. , Nicholson L. , Kaser G. , Ortner M.
Published: August 2013

Abstract. We calculated the distributed surface mass and energy balance of Shallap Glacier, Cordillera Blanca, Peru (9° S, 77° W, 4700–5700 m a.s.l., ∼ 7 km2) on hourly time steps for two years (September 2006–August 2008) using a process-based model and meteorological measurements as input. Model parameter combinations were optimized against 21 temporal readings of 20 stakes in the ablation zone of the glacier. Uncertainty caused by model input parameters and parameterization schemes was estimated using a leave-one-out cross-validation scheme and yields values of root mean square deviation (RMSD) of surface height change < 1m (< 10% of the measured amplitude) for all stakes. With the best parameter combination (smallest RMSD) applied, the modeled annual surface mass balance of the glacier was −0.32 ± 0.4 m w.e. for September 2006–August 2007 and 0.51 ± 0.56 m w.e. for September 2007–August 2008. While the mass balance above 5000 m was similar in both years (Δ 0.35 ± 0.68 m w.e.) due to similar annual sums of solid precipitation, a difference of ∼ 2 ± 0.68 m w.e. was calculated for the lower parts of the glacier. This difference is associated with more frequent occurrence of higher snow line altitudes during the first year, which was mainly caused by a higher fraction of liquid precipitation due to higher mean air temperatures. As the net shortwave budget was found to be the main source for ablation throughout the year at Shallap Glacier, lower surface albedo caused by higher snow line altitudes explains most of the difference in modeled ablation and mass balance between the two years.
Endovascular Repair of Symptomatic Hemodialysis Access Graft Pseudoaneurysms
Authors: Fotiadis Nicos , Shawyer Andrew , Namagondlu Girish , Iyer Arun , Matson Matthew , Yaqoob Muhammad Magdi
Published: August 2013

Aim

Repeated needle punctures of arteriovenous hemodialysis grafts can lead to the development of pseudoaneurysms. As they enlarge, graft pseudoaneurysms are associated with significant morbidity and require treatment. We present our single-center experience using stent grafts in selected patients to exclude symptomatic hemodialysis graft pseudoaneurysms.

Materials and Methods

Between March 2007 and December 2010, 11 consecutive patients (7 men and 4 women, mean age 57 years) underwent percutaneous endovascular repair of symptomatic hemodialysis access graft pseudoaneurysms. Indications for treatment were rapidly enlarging pseudoaneurysm in 5 patients, high venous pressures, limb edema and pseudoaneurysm in 3, skin breakdown over the pseudoaneurysm site in 2 and acute rupture and bleeding in 1 patient. No patient was lost to follow-up.

Results

Technical success across the 11 patients was 90.9%. The patient who presented with rupture required ligation of the access due to continuous bleeding after stent graft insertion. Balloon angioplasty of a separate hemodynamically significant stenosis at the time of stent graft insertion was performed in 7 of 11 (63.6%) patients. The primary access patency rates were 72.7% (95% CI of 0.390-0.939) at 3 months and 36.4% (95% CI 0.109-0.692) at 6 months. Secondary access patency rates were 72.7% at 6 months (95% CI 0.233-0.832). There were no procedure-related complications. Mean follow-up was 9 months (range 2-29 months).

Conclusions

Endovascular treatment of symptomatic hemodialysis graft pseudoaneurysms is safe and effective with similar patency rates to surgical approaches. Importantly, this approach allows aggressive management of associated access circuit stenoses at the same time and avoids interval tunneled dialysis line insertion.
Sensor Feature Selection and Combination for Stress Identification Using Combinatorial Fusion
Authors: Deng Yong , Wu Zhonghai , Chu Chao-Hsien , Zhang Qixun , Hsu D. Frank
Published: August 2013

The identification of stressfulness under certain driving condition is an important issue for safety, security and health. Sensors and systems have been placed or implemented as wearable devices for drivers. Features are extracted from the data collected and combined to predict symptoms. The challenge is to select the feature set most relevant for stress. In this paper, we propose a feature selection method based on the performance and the diversity between two features. The feature sets selected are then combined using a combinatorial fusion. We also compare our results with other combination methods such as naïve Bayes, support vector machine, C4.5, linear discriminant function (LDF), and k-nearest neighbour (kNN). Our experimental results demonstrate that combinatorial fusion is an efficient approach for feature selection and feature combination. It can also improve the stress recognition rate.
Access to GLP-1 Weight Loss Drugs in the US, Canada, Switzerland, and Germany
Authors: Vokinger Kerstin N. , Nussli Emanuel , Dusetzina Stacie B.
Published: July 2024

This Viewpoint compares use and costs of glucagon-like peptide 1 (GLP-1) receptor agonists for weight loss between the US and 3 other peer countries.
Newborn Screening and Birth Prevalence for Spinal Muscular Atrophy in the US
Authors: Belter Lisa , Taylor Jennifer L. , Jorgensen Erica , Glascock Jacqueline , Whitmire Sarah M. , Tingey Jessica J. , Schroth Mary
Published: July 2024

This cross-sectional study describes the collection and use of state-provided data on newborn screening for spinal muscular atrophy.
Relationship of Handgrip Strength and Asymmetry with Walking Ability in Older Adults with Excess Adiposity
Authors: Cook Summer B. , Chaudhry Bilal A. , Petersen Curtis L. , Mackenzie Todd A. , Batsis John A.
Published: July 2024

When low muscle mass and impaired strength and physical function coexist with excess adiposity, it is termed sarcopenic obesity (SO). Handgrip strength (HGS) is a predictor of disability and mortality. Asymmetry in HGS, particularly ≥ 10% strength differences between hands, may indicate neuromuscular dysfunction observable prior to declines in maximal strength are detectedand therefore could be incorporated to identify those at risk of physical limitations and SO. This study compares HGS values and asymmetry in older adults with excess adiposity and evaluates their relationships with physical function. Baseline data from two previous pilot weight loss studies in 85 older adults with body mass index values ≥ 30 kg m−2 are included with measures of body composition, walking speed, and chair stand ability. Sixty‐three participants met the criteria for SO. HGS correlated to gait speed (r = 0.22), distance walked (r = 0.40), chair stand time for 5 repetitions (r = 0.42) and during 30 s (r = 0.31). HGS asymmetry is only correlated to gait speed (r = 0.31) and there are no differences in physical function between those with and without asymmetry. Maximal HGS tests should continue to be used to screen for functional decline and disability.
Transfer of Self‐Sustained Reactions between Thermally Coupled Reactive Material Elements
Authors: Shekhawat Deepshikha , Breiter Manuela , Döll Joachim , Daneshpazhooneja Farshad , Jung Anne , Pezoldt Jörg
Published: July 2024

System engineering requires the implementation of assembly methods allowing the formation of functional elements according to a desired system design. This is possible by joining prefabricated elements on a desired place in the system or by forming functional materials at wanted locations. Both approaches need temperature treatment. A typical system in part consists of materials restricting the use of annealing procedures above 300 °C. For this reason, higher‐temperature operations have to be localized to the point of use and transferred to the next reactive element. A further requirement is the reduction of the thermal budget of the localized joining process implementing ultrashort heat treatment operations. Reactive metallic multilayer offers the combined possibility of implementing a localized heat source and the formation of a functional intermetallic alloy. The article demonstrates the feasibility of a heat and reaction transfer chain in a topological structured pattern consisting of localized reactive multilayer materials under conditions of their gasless combustion. For the used Ni/Al multilayer material system, the critical (obstacle thickness) dimensions for the reaction and heat transfer are determined using a high‐speed camera and pyrometer measurements.
Stabilizing Donor/Acceptor Interfaces with Ordered Polymer Layers in Planar‐Heterojunction Organic Solar Cells Under Thermal Stress
Authors: Xu Yujie , Xiao Mengfei , Fu Zhen , Wang Linghua , Wang Chen , Sun Ming , Li Min , Yin Hang , Hao Xiaotao , Du Xiaoyan
Published: July 2024

As the efficiency of single‐junction organic solar cells (OSCs) is about to break 20%, more research effort is needed to achieve long‐term device stability for commercialization. The complex active layer microstructure of bulk‐heterojunctions challenges the degradation mechanism study, especially for the morphological changes under thermal stress. In this work, this issue can be overcome by employing planar‐heterojunction (PHJ) OSCs with well‐defined bi‐layered structures, which enables effective control of the microstructure of polymer donor layers. The evolution of photovoltaic parameters of the PHJ OSCs under thermal stress is specifically revealed, which is strongly related to the inter diffusion of small molecular acceptors into the amorphous phases of the polymer donors. Increasing the crystallinity of polymer donors can effectively stabilize the donor/acceptor interfaces and the photovoltaic performances. The work puts forward effective strategies to improve the morphological stability of OSCs and alternative approaches for mechanistic studies on the thermal stability of OSCs.
Electrochemical and Field Effect Transistor Dual‐Mode Biosensor Chip for Label‐Free Detection of Cytokine Storm Biomarker with High Sensitivity within a Wide Range
Authors: Ouyang Jiahao , Li Yaxin , Yang Feiran , Wu Xuewen , Qiu Zhenli , Shu Jian
Published: July 2024

Accurate and rapid quantification of cytokines in biofluids is crucial for early disease diagnosis, management, and prevention. However, it still remains challenging for existing sensors due to the broad dynamic range of cytokines and high interference from sample matrices. To overcome these challenges, electrochemical (EC) and field‐effect transistor (FET) dual‐mode biosensing is integrated on an extended‐gate carbon nanotube field‐effect transistor. This biosensor chip effectively eliminates direct contact between the device and the solution and employs independent signal readouts based on two distinct response mechanisms, thereby circumventing the limitations associated with conventional transistor biosensors. Selective detection of cytokine (e.g., Interferon‐γ, IFN‐γ) is achieved by the FET sensing mode (0.1 to 4000 pg mL−1, with a limit of detection of 24.1 fg mL−1) and the EC sensing mode (0.4–2000 ng mL−1) at different concentration range. The feasibility of real sample analysis using the EC‐FET dual‐mode biosensor is confirmed by detecting salivary levels of IFN‐γ. The combination of EC and FET sensing modes not only provides high sensitivity and a wide response range (seven orders of magnitude) to accommodate various biological samples but also improves the reliability of detection results, which shows promising applications in biological analysis and early disease diagnosis.
Harnessing the Trade‐Off between CoFe/Fe3C Interfacial Junction with Unparalleled Potential Gap of 0.58 V for Reversible Oxygen Electrocatalysis: Application toward Liquid and Solid‐State Zn‐Air Batteries
Authors: Das Srijib , Pathak Arupjyoti , Phadikar Ujjwal , Kuila Chinmoy , Maji Animesh , Kuila Tapas , Murmu Naresh Chandra , Thapa Ranjit , Kundu Aniruddha
Published: July 2024

Effective integration of multiple active moieties and strategic engineering of coordinated interfacial junctions are crucial for optimizing the reaction kinetics and intrinsic activities of heterogeneous electrocatalysts. Herein, a simple integrated heterostructure of biphasic Co0.7Fe0.3/Fe3C embedded on in situ grown N‐doped carbon sheets is constructed. Rationally designed CoFe/Fe3C‐T2 owns more accessible active sites and interfacial junction effects, cooperatively boosting the electron and mass transfer, needed for multifunctional electrocatalysis. Leveraging the synergistic effect of dual active sites, CoFe/Fe3C‐T2 demonstrates outstanding oxygen electrocatalytic activity in alkaline medium with an ultra‐low potential gap of 0.58 V, surpassing the recently available state‐of‐the‐art catalysts. Moreover, CoFe/Fe3C‐T2 air‐electrode achieves a high peak power density of 249 mW cm−2, a large specific capacity of 808 mAh g−1 and excellent cycling stability for aqueous Zn‐air batteries. Remarkably, the solid‐state flexible ZAB also exhibits satisfactory performance, showcasing an open‐circuit voltage of 1.43 V and a peak power density of 66 mW cm−2. These outstanding results push this catalyst to the top of the list of non‐noble metal‐based electrode materials. This work offers a viable method for using the active‐site‐uniting strategy to create double‐active‐site catalysts, which may find real‐time applications in energy conversion/storage devices.
Molecular Mechanisms and Enhancement of Piezoelectricity in the M13 Virus
Authors: Kim Han , Lee Seung‐Wuk
Published: July 2024

Understanding the structure and function of bioelectric materials is challenging due to the complex nature of biomaterials and a lack of appropriate tools. The precisely defined structures and genetic tunability of viruses provide an excellent model system to investigate bioelectrical behavior in biomaterials. This study presents the molecular mechanisms of piezoelectricity in the M13 bacteriophage (phage) under various mechanical stresses for bio‐piezoelectric generation. A computational approach is used to calculate the piezoelectric tensors of the M13 phage and quantify its direction‐dependent dipole moments. By computationally designing negatively charged residues on the phage surface, the surface charge density is enhanced to 16.7 µC cm−2. Using genetic engineering, phages are experimentally designed with different charges and tail structures to create model phage nanostructures, including individual phages, vertically standing phage films, and horizontally aligned phage films. Their vertical, horizontal, and shear‐mode piezoelectric properties are then measured using scanning probe microscopy techniques. The resulting phage‐based piezoelectric energy generators exhibit an effective piezoelectric coefficient of 15.4 pm V−1 and a power density of 4.2 µW cm−2. This phage‐based bioengineering approach provides a versatile platform for investigating fundamental mechanisms of bioelectricity and designing bioelectric materials for applications in energy harvesting, biomemory, and biosensors.
CrOx Modified Nickel Phosphides Electrocatalyst for Stable Hydrogen Evolution Reaction in Neutral Media
Authors: Zhang Pu , Man Han , Huo Yao , Zhang Fei , Liu Yang , Wu Renbing , Wang Fei , Sun Dalin
Published: July 2024

The development of efficient and long‐term stable electrodes for hydrogen evolution reaction (HER) in seawater is highly desirable for hydrogen generation but remains challenging. In this work, a highly active CrOx@Ni2P‐Ni5P4/NF electrode is developed and investigated its dynamic reconstruction for HER in neutral electrolytes. The combination of in situ Raman spectra and electrochemical measurements revealed the dynamic surface reconstruction of the catalyst during HER. The CrOx modification not only effectively facilitates water dissociation but also stabilizes the structure post‐reconstruction, enabling rapid and stable hydrogen generation in neutral media. Remarkably, CrOx@Ni2P‐Ni5P4/NF exhibits overpotentials of 109 and 263 mV at current densities of 10 and 100 mA cm−2 in 1 m PBS, respectively. Concurrently, it exhibits stable operation for 500 h in 1 m PBS and 140 h in natural seawater at current densities of 50 and 100 mA cm−2, respectively. The proposed catalytic electrode and the mechanistic insights present a significant stride toward the realization of metal phosphides for direct seawater splitting.
Layered Bismuth Selenide with a Kinetics‐Enhanced Iodine Doping Strategy Toward High‐Performance Aqueous Potassium‐Ion Storage
Authors: Zhang Wei , Sun Yuanhe , Yang Junwei , Ren Zhiguo , Zhao Yuanxin , Lei Qi , Si Jingying , Lin Mengru , Chen Jige , Li Xiaolong , Wen Wen , Li Aiguo , Zhu Daming
Published: July 2024

Aqueous potassium‐ion batteries with inherent safety, high abundance, and competitive hydrated ion‐radius point to future availability in energy storage. However, the extensively studied electrodes (metal‐oxides, Prussian‐blue‐analogues, etc.) typically suffer from undesirable capacities and sluggish kinetics owing to overwhelming ion diffusion barriers. Herein, for the first time, the metal chalcogenide bismuth selenide reinforced by iodine‐doping (I‐Bi2Se3) is implemented for high‐performance aqueous potassium‐ion storage. The co‐intercalation mechanism of potassium‐ion with proton in I‐Bi2Se3 is entirely revealed by operando synchrotron X‐ray diffraction and substantial ex‐situ analysis, and the excellent interlayer diffusion kinetics in the high‐conductive host are further enhanced by iodine‐doping, as proposed by theoretic calculations. Therefore, the resulting high diffusion coefficient and low interfacial transfer resistance endow I‐Bi2Se3 with superior rate performance (109.2 mAh g−1 at 10 A g−1) and cycling stability (91% capacity retention after 1200 cycles). Employing in hybrid‐ion batteries matching zinc metal, the highest reversible aqueous potassium‐ion storage to date of 316.8 mAh g−1 is demonstrated, permitting the establishment of reliable performance pouch cells. The promising aqueous potassium intercalation chemistry built in the improved metal chalcogenide is proven to be extendable to other hybrid‐ion devices, offering novel mechanistic insights and material practices for aqueous energy storage.
Programmable Release of Chemotherapeutics from Ferrocene‐Based Injectable Hydrogels Slows Melanoma Growth
Authors: Rothe Rebecca , Xu Yong , Wodtke Johanna , Brandt Florian , Meister Sebastian , Laube Markus , Lollini Pier‐Luigi , Zhang Yixin , Pietzsch Jens , Hauser Sandra
Published: July 2024

Hydrogel‐based injectable drug delivery systems provide temporally and spatially controlled drug release with reduced adverse effects on healthy tissues. Therefore, they represent a promising therapeutic option for unresectable solid tumor entities. In this study, a peptide‐starPEG/hyaluronic acid‐based physical hydrogel is modified with ferrocene to provide a programmable drug release orchestrated by matrix‐drug interaction and local reactive oxygen species (ROS). The injectable ROS‐responsive hydrogel (hiROSponse) exhibits adequate biocompatibility and biodegradability, which are important for clinical applications. HiROSponse is loaded with the two cytostatic drugs (hiROSponsedox/ptx) doxorubicin (dox) and paclitaxel (ptx). Dox is a hydrophilic compound and its release is mainly controlled by Fickian diffusion, while the hydrophobic interactions between ptx and ferrocene can control its release and thus be regulated by the oxidation of ferrocene to the more hydrophilic state of ferrocenium. In a syngeneic malignant melanoma‐bearing mouse model, hiROSponsedox/ptx slows tumor growth without causing adverse side effects and doubles the relative survival probability. Programmable release is further demonstrated in a tumor model with a low physiological ROS level, where dox release, low dose local irradiation, and the resulting ROS‐triggered ptx release lead to tumor growth inhibition and increased survival.
A Diketopyrrolopyrrole‐Based All‐in‐One Nanoplatform for Self‐Reinforcing Mild Photothermal Therapy Cascade Immunotherapy for Tumors
Authors: Li Xinsheng , Liu Lingyan , Yang Kaini , Wang Zhiqiang , Yuan Tao , Sha Qingyang , Chen Wei , Yi Tao , Hua Jianli
Published: July 2024

Mild photothermal therapy (PTT) has attracted attention for effectively avoiding the severe side effects associated with high‐temperature tumor ablation. However, its progress is hindered by the limited availability of high‐performance photothermal agents (PTAs) and the thermoresistance of cancer cells induced by heat shock reactions. Herein, this work proposes a new strategy to expand the library of high‐performance organic small‐molecule PTAs and utilize it to construct a multifunctional nano‐theranostic platform. By incorporating additional acceptors and appropriate π‐bridges, a diketopyrrolopyrrole‐based dye BDB is developed, which exhibits strong absorption and bright fluorescence emission in the near‐infrared (NIR) region. Subsequently, BDB is co‐coated with the heat shock protein (HSP) inhibitor tanespimycin (17‐AAG) using the functional amphiphilic polymers DSPE‐Hyd‐PEG2000‐cRGD to form an all‐in‐one nanoplatform BAG NPs. As a result, BAG NPs can precisely target tumor tissue, guide the treatment process in real‐time through NIR‐II fluorescence/photoacoustic/photothermal imaging, and release 17‐AAG on demand to enhance mild PTT. Additionally, the mild PTT has been demonstrated to induce immunogenic cell death (ICD) and activate a systemic anti‐tumor immune response, thereby suppressing both primary and distant tumors. Overall, this study presents a multifunctional nanoplatform designed for precise mild PTT combined with immunotherapy for effective tumor treatment.
Closed‐Loop Direct Upcycling of Spent Ni‐Rich Layered Cathodes into High‐Voltage Cathode Materials
Authors: Ji Haocheng , Wang Junxiong , Qu Haotian , Li Junfeng , Ji Wenhai , Qiu Xiao , Zhu Yanfei , Ren Hengyu , Shi Ruyu , Ji Guanjun , Zhao Wenguang , Zhou Guangmin
Published: July 2024

Facing the resource and environmental pressures brought by the retiring wave of lithium‐ion batteries (LIBs), direct recycling methods are considered to be the next generation's solution. However, the contradiction between limited battery life and the demand for rapidly iterating technology forces the direct recovery paradigm to shift toward “direct upcycling.” Herein, a closed‐loop direct upcycling strategy that converts waste current collector debris into dopants is proposed, and a highly inclusive eutectic molten salt system is utilized to repair structural defects in degraded polycrystalline LiNi0.83Co0.12Mn0.05O2 cathodes while achieving single‐crystallization transformation and introducing Al/Cu dual‐doping. Upcycled materials can effectively overcome the two key challenges at high voltages: strain accumulation and lattice oxygen evolution. It exhibits comprehensive electrochemical performance far superior to commercial materials at 4.6 V, especially its fast charging capability at 15 C, and an impressive 91.1% capacity retention after 200 cycles in a 1.2 Ah pouch cell. Importantly, this approach demonstrates broad applicability to various spent layered cathodes, particularly showcasing its value in the recycling of mixed spent cathodes. This work effectively bridges the gap between waste management and material performance enhancement, offering a sustainable path for the recycling of spent LIBs and the production of next‐generation high‐voltage cathodes.
Switchable Adhesion Interfaces: From General Mechanisms to Interfacial Design Strategies
Authors: Zhang Zhiang , He Ruokun , Ding Yuxuan , Han Bing , Wang Hesheng , Ma Zhuo‐Chen
Published: July 2024

Switchable adhesion, a phenomenon characterized by the ability to transition between attachment and detachment states under external stimuli, has recently gained popularity in various advanced devices. The realization of the desired functionalities on such surfaces relies on intricate interfacial designs. A general understanding of the commonalities and distinctions among these designs can foster the development of refined switchable adhesion interfaces (SAIs). To address this, this review first examines adhesion interfaces by focusing on the fundamental interactions at the atomic/molecular level, adhesion models, and their correlation with the diverse forces/bonds that dominate the adhesion behaviors. The latest progress in SAIs based on various forces/bonds, including electrostatic force, van der Waals force, capillary force, chemical bond, and suction force, is then discussed with regard to their specific design strategies, such as structures, components, and triggers. Additionally, an extensive overview of the broad applications of SAIs in fields ranging from space to biomedicine is provided, along with an exploration of the prevailing challenges and potential opportunities. With the rapid progress that has been made in state‐of‐the‐art mechanisms and design strategies, SAIs are expected to undergo booming development in the foreseeable future.
High‐Toughness Hydrated Polymer Electrolytes for Advanced Structural Supercapacitors
Authors: Chang Yu‐Che , Teymoory Parya , Shen Caiwei
Published: July 2024

Structural supercapacitors that simultaneously bear mechanical loads and store electrical energy have exciting potential for enhancing the efficiency of various mobile systems. However, a significant hurdle in developing practical structural supercapacitors is the inherent trade‐off between their mechanical properties and electrochemical capabilities, particularly within their electrolytes. This study demonstrates a tough polymer electrolyte with enhanced multifunctionality made through the controlled hydration of a solid polymer electrolyte with poly(lactic acid) (PLA) and lithium salts. Characterization via differential scanning calorimetry, X‐ray diffraction, and Fourier transform infrared spectroscopy confirms the consistent amorphous solid solution phase in varying salt concentrations, whether dried or hydrated. Electrochemical tests and tensile tests are performed to evaluate the ionic conductivity and mechanical properties of these electrolytes. The results indicate that the strategic incorporation of water in the polymer electrolyte significantly enhances the ionic conductivity while preserving its mechanical properties. A specific composition demonstrated a remarkable increase in ionic conductivity (3.11 µS cm−1) coupled with superior toughness (15.4 MJ m−3), significantly surpassing the base polymer. These findings open new horizons for integrating electrochemical functionality into structural polymers without compromising their mechanical properties. Additionally, the paper reports the successful fabrication and testing of structural supercapacitor prototypes combining carbon fibers with fabricated electrolytes, showcasing their potential for diverse applications.
Dynamic Infrared Radiation Regulator Enabling Positive and Reversible Modulation of Emissivity and Temperature
Authors: Huang Jingkai , Yuan Liming , Liao Jianming , Wang Yuetang , Liu Yang , Ji Chen , Huang Cheng , Luo Xiangang
Published: July 2024

The ongoing advancements and growing adoption of infrared detection technology have spurred a tremendous amount of interest in thermal camouflage technology. Various approaches are employed to develop infrared camouflage materials capable of manipulating emissivity or surface temperature. However, the range of thermal radiation regulation implemented by these materials is still somewhat limited. In this paper, a combined emissivity and temperature regulation strategy that integrates a thermoelectric device (TED) and a thermochromic structure is proposed. By utilizing this strategy, it becomes possible to simultaneously control the surface temperature and the emissivity without needing additional complex excitation. As a concept demonstration, large tunabilities of 0.38 for long‐wave infrared (8–14 µm) emittance and 87 °C for surface temperature are observed, resulting in a prominent tunability of the thermal radiation temperature that is 15.4 °C greater than that of a conventional TED with constant emissivity. This work aims to introduce a new design paradigm for future thermal radiation management and camouflage techniques.
Manipulating Light with Bound States in the Continuum: from Passive to Active Systems
Authors: Zeng Yixuan , Zhang Xudong , Ouyang Xu , Li Yingjie , Qiu Cheng‐Wei , Song Qinghai , Xiao Shumin
Published: July 2024

The manipulation of light has become the focus of various modern optical technologies. The emergence of bound states in the continuum (BICs) offers an alternative platform for controlling light, including the confinement and manipulation of polarization, amplitude, and phase. Currently, research on photonic BICs is maturing, with extensive exploration of methods for achieving BICs and their various applications, including lasing, sensing, and enhanced light‐matter interaction. In this review, an overview of photonic BICs is provided. Specifically, the unique properties of BICs are first presented, followed by their state‐of‐the‐art applications in passive systems, ranging from sensing to waveguiding, beam shaping, and chirality. The paradigm‐shifting developments in active systems resulting from the hybridization of BICs with active and novel materials are then highlighted. Finally, some of the challenges facing photonic BICs are discussed, along with  future directions in terms of physics, design, fabrication, engineering, and tunability.
Advances in Paper‐Based Photodetectors: Fabrications, Performances, and Applications
Authors: Tang Xing , Yang Jingwen , Duan Zaihua , Bu Yichen , Yuan Zhen , Jiang Yadong , Tai Huiling
Published: July 2024

With the development of wearable electronic technology, the flexible photodetectors have attracted widespread attention, and it is of great significance to develop flexible, eco‐friendly and low‐cost photodetectors. Cellulose paper, as a flexible, eco‐friendly, low‐cost, lightweight, customizable, biodegradable and renewable material, has received enthusiastic attention and rapid development in the field of photodetectors in recent years. In this review, it is focused on the research progress of paper‐based (PB) photodetectors. First, the fabrication methods of PB photodetectors are discussed, including electrode materials and optoelectronic functional materials. Then, this review systematically summarizes and analyzes the achievements of PB photodetectors on photoelectric performances (spectral response range, responsivity, detectivity, response/recovery times and on/off ratio) and flexibility characteristics (bending angle and bending cycle). In terms of key performance indicators, the PB photodetectors reported so far can detect multiple wavelengths of light from UV to near‐infrared with the maximum detectivity of 1013 Jones. In addition, the various applications of PB photodetectors is reviewed and discussed. Finally, it is look forward to the future development of PB photodetectors in terms of fabrication methods, photoelectric and flexible performances, and applications. With this review, it is hope that it will promoted the future development of PB photodetectors.
Unequilibrated Charge Carrier Mobility in Organic Semiconductors Measured Using Injection Metal–Insulator–Semiconductor Charge Extraction by Linearly Increasing Voltage
Authors: Gao Mile , Burn Paul L. , Juška Gytis , Pivrikas Almantas
Published: July 2024

The charge carrier mobility in tris(4‐carbazoyl‐9‐ylphenyl)amine (TCTA), a host and hole transport material typically used in organic light‐emitting diodes (OLEDs), is measured using charge carrier electrical injection metal–insulator–semiconductor charge extraction by linearly increasing voltage (i‐MIS‐CELIV). By employing the injection current i‐MIS‐CELIV method, charge transport at time scales shorter than the transit times typically observed in standard MIS‐CELIV is measured. The i‐MIS‐CELIV technique enables the experimental measurement of unequilibrated and pretrapped charge carriers. Through a comparison of injection and extraction current transients obtained from i‐MIS‐CELIV and MIS‐CELIV, it is concluded that hole trapping is negligible in evaporated neat films of TCTA within the time‐scales relevant to the operational conditions of optoelectronic devices, such as OLEDs. Furthermore, photocarrier generation in conjunction with i‐MIS‐CELIV (photo‐i‐MIS‐CELIV) to quantify the properties of charge injection from the electrode to the semiconductor of the MIS devices is utilized. Based on the photo‐i‐MIS‐CELIV measurements, it is observed that the contact resistance does not limit the injection current at the TCTA/molybdenum oxide/silver interface. Therefore, when TCTA is employed as the hole transport/electron‐blocking layer in OLEDs, it does not significantly reduce the injection current and remains compatible with the high injection current densities required for efficient OLED operation.
Intelligent Rock‐Climbing Robot Capable of Multimodal Locomotion and Hybrid Bioinspired Attachment
Authors: Zi Peijin , Xu Kun , Chen Jiawei , Wang Chang , Zhang Tao , Luo Yang , Tian Yaobin , Wen Li , Ding Xilun
Published: July 2024

Rock‐climbing robots have significant potential in fieldwork and planetary exploration. However, they currently face limitations such as a lack of stability and adaptability on extreme terrains, slow locomotion, and single functionality. This study introduces a novel multimodal and adaptive rock‐climbing robot (MARCBot), which addresses these limitations through spiny grippers that draw inspiration from morpho‐functionalities observed in beetles, arboreal birds, and hoofed animals. This hybrid bioinspired design enables high attachment strength, passive adaptability to different terrains, and quick attachment on rock surfaces. The multimodal functionality of the gripper allows for attachment during climbing and support during walking. A novel control strategy using dynamics and quadratic programming (QP) optimizes attachment wrench distribution, reducing cost‐of‐transport by 20.03% and 6.05% compared to closed‐loop inverse kinematic (CLIK) and virtual model control (VMC) methods, respectively. MARCBot achieved climbing speeds of 0.15 m min−1 on a vertical discrete rock surface under gravity and trotting speeds of up to 0.21 m s−1 on various complex terrains. It is the first robot capable of climbing on rock surfaces and trotting in complex terrains without the need for switching end‐effectors. This study highlights significant advancements in climbing and multimodal locomotion for robots in extreme environments.
Ultrahigh Performance UV Photodetector by Inserting an Al2O3 Nanolayer in NiO/n‐Si
Authors: Ma Xingzhao , Tang Libin , Jia Menghan , Zhang Yuping , Zuo Wenbin , Cai Yuhua , Li Rui , Yang Liqing , Teng Kar Seng
Published: July 2024

Ultraviolet (UV) photodetectors have gained much attention due to their numerous important applications ranging from environmental monitoring to space communication. To date, most p‐NiO/n‐Si heterojunction photodetectors (HPDs) exhibit poor UV responsivity and slow response. This is mainly due to a small valence band offset (ΔEV) at the NiO/Si interface and a high density of dangling bonds at the silicon surface. Herein, an UV HPD consisting of NiO/Al2O3/n‐Si is fabricated using magnetron sputtering technique. The HPD has a large rectification ratio of 2.4 × 105. It also exhibits excellent UV responsivity (R) of 15.8 A/W at −5 V and and detectivity (D*) of 1.14 × 1013 Jones at −4 V, respectively. The excellent performance of the HPD can be attributed to the defect passivation at the interfaces of the heterojunction and the efficient separation of photogenerated carriers by the Al2O3 nanolayer. The external quantum efficiency (EQE) of the HPD as high as 5.4 × 103%, hence implying a large optical gain due to carrier proliferation resulting from impact ionization. Furthermore, the ultrafast response speed with a rise time of 80 µs and a decay time of 184 µs are obtained.
A Solid‐Solution with Asymmetric Ni‐O‐Cr Sites for Boosting Protonation toward Anodic Oxidation
Authors: Feng Yihan , Wang Xunlu , Ma Junqing , Wang Nan , Liu Qiunan , Suenaga Kazu , Chen Wei , Zhang Jitang , Zhou Yin , Wang Jiacheng
Published: July 2024

Replacing the slow protonation process of oxygen evolution reaction (OER) with the fast protonation of alcohol electro‐oxidation can decrease the driving potentials, thus improving overall efficiency of electrochemical devices. However, the formation of effective catalytic sites for alcohol oxidation remains challenging in accelerating protonation to inhibit metal leaching and improve catalyst stability. Herein, asymmetric Ni‐O‐Cr sites are constructed by alloying Cr into the NiO matrix to optimize coordination environments, showing significantly enhanced stability during alcohol electro‐oxidation. The asymmetric Ni‐O‐Cr can maintain constant valence states of Cr and Ni during alcohol oxidation, efficiently suppressing metal dissolution even at high oxidation potentials. In situ electrochemical characterizations combined with theoretical calculations indicate that asymmetric Ni‐O‐Cr can improve adsorption and activation of OH* and alcohol molecules compared to pure NiO, thus increasing anodic kinetics. The theoretical results also indicate that the smaller gap of Ni 3d‐O 2p in asymmetric Ni‐O‐Cr strengthens charge transfer, leading to fast protonation of catalytic sites with enhanced stability. This work gives insights into boosting anodic protonation using asymmetric sites‐enriched solid‐solution electrocatalysts.
Interfacial Catalysis Strategy for High‐Performance Solid‐State Lithium Metal Batteries
Authors: Yang Li , Zhang Hong , Xu Hantao , Peng Wei , Wu Lu , Cheng Yu , Liu Yuheng , Xu Lin , Mai Liqiang
Published: July 2024

Solid‐state lithium metal batteries (SSLMBs) with polymer electrolytes (SPEs) have attracted tremendous attention owing to their superior safety and high energy density. However, the unstable solid electrolyte interphase (SEI) between Lithium (Li) and SPEs hinders their practical application. Herein, an innovative interfacial catalysis strategy is applied to the in situ construction of a multifunctional inorganic‐rich SEI. The transfer of unpaired electrons adjacent to calcium vacancies (VCa) to the TFSI− anion promotes the breaking of S─N and C─F bonds during the electrochemical decomposition of TFSI−, thus enhancing its decomposition kinetics. The inorganic‐rich SEI derived from TFSI− is super‐stable and kinetically favorable for fast and homogeneous transport of Li ions, thereby hindering the growth of lithium dendrites. Consequently, the interfacial catalysis strategy endows Li||Li symmetric cells, LFP||Li and NCM811||Li full batteries with enhanced cyclability. Thus, this work expands the interfacial catalysis strategy to a platform for designing multifunctional SEI in long‐life SSLMB.
A Five Micron Thick Aramid Nanofiber Separator Enables Highly Reversible Zn Anode for Energy‐Dense Aqueous Zinc‐Ion Batteries
Authors: Yang Lin , Zhu Ying‐Jie , Yu Han‐Ping , Wang Zhong‐Yi , Cheng Long , Li Dan‐Dan , Tao Jingchao , He Guo , Li Heng
Published: July 2024

The rampant dendrites growth caused by uncontrolled deposition of Zn2+ ions at Zn metal anode poses a significant obstacle to the practical applications of aqueous zinc‐ion batteries (ZIBs). Herein, an ultrathin (5 µm) aramid nanofiber (ANF) separator is reported to enhance the Zn anode stability and the ZIB energy density. Through systematic experimental studies and DFT simulations, it is demonstrated that the ANF separator with unique surface polarity can modify the solvation configuration, facilitate desolvation, and regulate the deposition orientation of Zn2+ ions. Consequently, the Zn anode with the ANF separator demonstrates an 85‐fold increase in running time beyond 850 h compared with the conventional glass fiber separator at 5 mA cm−2/2.5 mAh cm−2. Even under the harsh depth of discharge conditions of 50% and 80%, the Zn anodes still sustain extended cycling periods of over 475 and 200 h, respectively. As pairing this ANF separator with thin Zn anode and high‐areal‐capacity Mn2.5V10O24∙5.9H2O cathode in a low negative capacity/positive capacity ratio (2.64) full cell, superior gravimetric/volumetric energy density (129.2 Wh kg−1/142.5 Wh L−1) is achieved, far surpassing majority of the ZIB counterparts reported in the literature. This work offers a promising ultrathin separator for promoting the utilization of energy‐dense aqueous ZIBs.
Do outgrower schemes enhance technology adoption and productivity? Evidence from maize farmers in Northern Ghana
Authors: Konja Dominic Tasila , Abdulai Awudu
Published: July 2024

Nucleus outgrower schemes are contractual arrangements where well‐resourced large‐scale farmers (nucleus farmers) are empowered by development support agencies to take charge of smallholder farmers, by providing them with market access and the necessary training on agronomic practices and farm inputs for production. In this study, we examine the impact of participation in outgrower scheme on technology adoption and farm productivity, using data from 634 smallholder maize farmers in Northern Ghana. We use the linear regression with endogenous treatment effects model to account for both observable and unobservable selection bias. The results reveal positive and significant marginal effects of outgrower scheme participation on technology adoption and maize yields. Outgrower scheme participants applied 6% and 82% more inorganic fertilizer and weedicides, respectively, than nonparticipants. Maize yield increased by about 3% for the participants more than nonparticipants. The findings also show that factors such as distance to market, distance to nucleus farmers' satellite office, nucleus outgrower scheme awareness, input price, and farmer‐based organization significantly influence outgrower scheme participation decisions, as well as technology adoption and maize yields.
Hierarchically porous carbon confined cobalt nanoparticles for highly efficient oxidative esterification of 5‐hydroxymethylfurfural
Authors: Zhao Xin , Xiao Linghan , Wang Fengliang , Shen Zirong , Fang Ruiqi , Li Yingwei
Published: July 2024

Herein, we report a controllable and versatile strategy for the synthesis of highly dispersed Co nanoparticles embedded in open‐channel hierarchically porous N/O‐doped carbon skeleton. Moreover, the pore sizes of the hierarchical structures can be easily tuned by adjusting the size of precursors. The as‐obtained Co@NC‐2ST exhibits unprecedented activity and selectivity in the oxidative esterification of 5‐hydroxymethylfurfural (HMF) to dimethyl furan‐2,5‐dicarboxylate under base‐free and atmospheric conditions. In particular, the achieved turnover frequency value is an order of magnitude higher than that of the state‐of‐art heterogeneous catalysts reported to date. A combination of experimental and density function theory studies reveals that the unique features of Co@NC‐2ST enable a novel reaction route, that is, the CHO group of HMF is preferentially esterified instead of the OH group. This can be attributed to the nucleophilic addition reaction caused by the attack of methoxy anion on the CHO group of HMF.
Ultrasound‐assisted and landmark‐based nusinersen delivery in spinal muscular atrophy adults: A retrospective analysis
Authors: Zanfini Bruno Antonio , Patanella Agata Katia , Vassalli Francesco , Catarci Stefano , Pane Marika , Frassanito Luciano , Biancone Matteo , Di Muro Mariangela , Bravetti Chiara , Mercuri Eugenio Maria , Sabatelli Mario , Draisci Gaetano
Published: July 2024

Introduction/Purpose

Nusinersen, the first treatment approved for all spinal muscular atrophy (SMA) types, is administered intrathecally through lumbar puncture. We used ultrasound assistance or a landmark‐based technique to access the lumbar intrathecal space in adult SMA patients. This study aimed to evaluate the technical success and adverse events (AEs) in such patients using either technique over a long observation period.

Methods

Fifty‐one adult patients received 507 consecutive interlaminar nusinersen administrations. Patients presented with both ‘uncomplicated spines’ or ‘complicated spines’; two patients had previous back surgery. Technical success and AEs were recorded using either technique. A generalised linear mixed model was applied to evaluate predictors of technical success and complications.

Results

An overall success rate of 99.6%, with only two procedures failing to reach the intrathecal space, and an overall optimal procedure rate of 90.3% have been reported. A total of 455 procedures (89.7%) were uneventfully performed. One (0.2%) case of severe AE (puncture of a bulky abdominal annexal cyst) was recorded. Twenty‐seven episodes (5.3%) of post‐dural puncture headache (PDPH) and 24 episodes (4.7%) of radicular or back pain, both successfully treated with medical therapy, have also been reported. Technical success was significantly associated with ‘complicated spines’ (P = 0.022) and the use of ultrasound assistance (P = 0.01), and the use of ultrasound was the only independent predictor of uncomplicated procedures (P = 0.007).

Discussion

In adult patients with SMA both landmark‐based and ultrasound‐assisted techniques are safe and effective even in the long term. The use of assistance is associated with technical success and can predict uncomplicated procedures.

Conclusion

Our results support the use of ultrasonography in order to improve the success and reduce the burden of nusinersen intrathecal administration.
The Role of Phosphorus on Alkaline Hydrogen Oxidation Electrocatalysis for Ruthenium Phosphides
Authors: Jin Yiming , Fan Xinran , Cheng Wenjing , Zhou Yuheng , Xiao Li , Luo Wei
Published: July 2024

Transition metal/p‐block compounds are regarded as the most essential materials for electrochemical energy converting systems involving various electrocatalysis. Understanding the role of p‐block element on the interaction of key intermediates and interfacial water molecule orientation at the polarized catalyst‐electrolyte interface during the electrocatalysis is important for rational designing advanced p‐block modified metal electrocatalysts. Herein, taking a sequence of ruthenium phosphides (including Ru2P, RuP and RuP2) as model catalysts, we establish a volcanic‐relation between P‐proportion and alkaline hydrogen oxidation reaction (HOR) activity. The dominant role of P for regulating hydroxyl binding energy is validated by active sites poisoning experiments, pH‐dependent infection‐point behavior, in situ surface enhanced infrared absorption spectroscopy, and density functional theory calculations, in which P could tailor the d‐band structure of Ru, optimize the hydroxyl adsorption sites across the Ru−P moieties, thereby leading to improved proportion of strongly hydrogen‐bonded water and facilitated proton‐coupled electron transfer process, which are responsible for the enhanced alkaline HOR performance.