bluuebunny/crossref_metadata_2025 huggingface dataset:
Defying expectations: follicular carcinoma thyroid with lung metastasis and elevated CA 125: images
Authors: Babu Agil , Patel Pinakin , Lakhera Kamal Kishore , Singh Suresh , Singhal Pranav M. , Kumar Naina , Mehta Deeksha
Published: August 2023

Background:

Follicular thyroid carcinoma (FTC) is a type of thyroid cancer that arises from the follicular cells of the thyroid gland. It accounts for about 10%-15% of all thyroid cancers.

CA 125 is a protein that is often used as a tumor marker for ovarian cancer, but it can also be elevated in other types of cancers, including thyroid cancer. The significance of raised CA 125 levels in FTC is not clear, but it indicates a more advanced or aggressive form of the disease [1,2].

Case Presentation:

A 62-year-old male presented with a painless neck mass (Figure 1) for 8 years. Ultrasonography revealed a solid nodule in the left lobe of the thyroid gland. Fine-needle aspiration cytology of the nodule showed features of follicular neoplasm. Contrast-enhanced computed tomography (CECT) abdomen and blood routine ruled out other causes of raised CA 125. Chest X ray and CECT neck (Figure 2) and thorax showed lung (Figure 3) and thoracic vertebra metastasis (Figure 5). Total thyroidectomy with bilateral central compartment lymph node dissection was performed. Histopathology confirmed FTC (Figure 4) with capsular invasion, and lymphovascular and perineural invasion and lymph node-positive. The tumor was classified as T3bN1a according to the tumor, nodes, and metastasis staging system. I131 scan post-surgery showed uptake in lung metastasis sites which confirmed the diagnosis.

Conclusion:

The role of serum tumor markers, such as CA 125, in predicting the prognosis of FTC is not well established. However, elevated CA 125 levels have been reported in some cases of thyroid carcinoma with metastasis, and may reflect the presence of peritoneal or pleural involvement [3,4]. This case highlights the aggressive nature of FTC with metastasis and the limited treatment options available for patients with advanced disease. CA 125 as a prognostic marker in FTC warrants further investigation [5].
ESTIMULANDO REFLEXÕES SOBRE O AGRONEGÓCIO POR MEIO DE UMA SEQUÊNCIA DIDÁTICA
Authors: Ribeiro João Pedro Mardegan
Published: August 2023

Ainda há na sociedade uma visão arcaica de que o agronegócio brasileiro só apresenta malefícios para a sociedade, assim, a escola como instituição formadora de cidadãos críticos e reflexivos, deve oferecer um espaço dialógico para o debate de ideias e conhecimentos sobre a temática. Para tanto, o objetivo deste trabalho foi aplicar uma sequência didática de doze aulas com alunos de uma escola pública, localizada no interior do estado de São Paulo, versando sobre a dinâmica do agronegócio no Brasil, e como este pode auxiliar o país a atingir os Objetivos do Desenvolvimento Sustentável proposto pela Organização das Nações Unidas. No início, averiguamos as concepções iniciais dos alunos e, assim, após esta etapa, começamos a dialogar sobre o agronegócio no país, e os objetivos supracitados, e ao final da sequência didática, os alunos deveriam apresentar o que aprenderam na forma de texto ou vídeo. Os principais resultados demonstraram que os alunos tinham concepções repulsivas quanto ao agronegócio, e desconheciam, de forma efetiva, sua importância e significância, e a sequência didática favoreceu que os alunos compreendessem ambos os lados. Assim, a principal conclusão obtida é que nos espaços formativos faz-se necessário apresentar aos alunos a globalidade dos fenômenos, para que eles possam refletir, com base em fatos e evidências, e tomar decisões e posicionamentos mais coerentes e condizentes com a realidade.
TRANSPLANTE DE ILHOTAS DE LANGERHANS COMO TRATAMENTO PARA DIABETES MELLITUS TIPO I
Authors: Milani Froes Barbara
Published: August 2023

Com relatos desde 1500 a.C, a diabetes tem sido uma doença que se populariza pelo aumento de casos identificados no decorrer dos anos e que, atualmente, atinge cerca de 88 mil brasileiros. O Diabetes Mellitus é caracterizado pela regulação indefinida do metabolismo de carboidratos, lipídios e proteínas, em consequência à deficiência na produção de insulina, hormônio esse produzido pelas células β produzidas no pâncreas. O tratamento dessa patologia se dá pela injeção de insulina e medicamentos para o controle da homeostasia do organismo, porém com a grande demanda dos mesmos, parte dos portadores não tem acesso aos tratamentos pelo alto custo e escassez na rede pública de saúde. Estudos avaliam o uso do transplante de ilhotas de Langerhans como terapia de tratamento para Diabetes Mellitus tipo I, sendo essa opção uma alternativa promissora, diante desse contexto o objetivo desse estudo foi realizar uma revisão bibliográfica avaliando o transplante de ilhotas de Langerhans como tratamento para diabetes mellitus tipo I. Observou-se que o transplante de ilhotas pancreáticas é uma alternativa que tem alcançado sucesso em seus testes, e mostrou ser uma ótima solução para a restauração da independência de insulina e está sendo estudado para que seja o melhor tratamento contra diabetes.
Editorial: Narrativas docentes: gênero transgressor e (auto)formativo
Authors: Nacarato Adair Mendes , Suàrez Daniel Hugo , Ferreira Luciana Haddad
Published: August 2023

A escrita narrativa de professoras e professores tem ocupado, com grande frequência, espaço nos debates e estudos da comunidade acadêmica do campo educacional. Entre diferentes discussões metodológicas e epistemológicas acerca de seus usos, limites e potencialidades, uma constância: o gênero narrativo parece ter ocupado um importante e definitivo espaço de diálogo e intercâmbio entre a comunidade acadêmica e da Educação Básica. Narram professores e professoras, em diferentes contextos e momentos, dando visibilidade a fragmentos cotidianos, nem sempre vistos e percebidos por outras frestas, que não a da narrativa de quem vive.
Principios y reglas: la interseccionalidad como principio de interpretación en las sentencias de la Corte Constitucional
Authors: Carrillo Benítez Cristian Camilo , Tobón Franco Isabella
Published: August 2023

En el presente artículo se analizará la interseccionalidad como teoría que estudia rigurosamente la brecha social y política que surge en los diferentes actos de discriminación, en los cuales hay factores heterogéneos y concurre una multiplicidad de características propias de aquellas personas que se sitúan en estado de vulnerabilidad. Para ello se estudiará cómo la confluencia de estas características —raza, origen étnico, edad, sexo, género, orientación sexual, nivel educativo, situación migratoria, creencias religiosas, identidad, discapacidad física o mental, posición socioeconómica, etc.— se vuelve determinante en los círculos de discriminación y cómo la interseccionalidad se presenta como una herramienta que dinamiza su comprensión y su enfoque en ciertos parámetros sociopolíticos, permitiendo establecer el impacto de la discriminación para la adecuación de medidas que protejan y garanticen los derechos fundamentales de los individuos.
¿La defensa de los derechos justifica la politización de la justicia?
Authors: Moreira Lamounier Heringer Helimara
Published: August 2023

El presente trabajo cuestiona la razonabilidad del activismo judicial en la defensa de los derechos fundamentales, si puede ser utilizado para justificar la politización de la actividad judicial en Brasil, y si en alguna medida es beneficioso y no viola las libertades y garantías fundamentales. Se utiliza el método hipotético-deductivo y la investigación en libros, artículos científicos, legislación y jurisprudencia para analizar el proceso bilateral de judicialización de la política y politización de la justicia, con énfasis en el segundo aspecto, que ha desplazado el eje de fuerza entre los poderes del Estado, ya que está directamente vinculado al proceso de valorización de la adjudicación constitucional y la valorización de las cortes supremas en el escenario político. Se evalúa la importancia del poder constituyente y su injerencia entre los poderes del Estado. Se busca establecer los límites de la politización de la justicia, analizando dos casos específicos en sentencias del Supremo Tribunal Federal sobre cuestiones relacionadas con los derechos de la mujer referidos al aborto y con los del anciano atinentes a la reincorporación, en los que el tribunal tomó rumbos distintos en cuanto al ejercicio de la actividad legislativa. De la investigación se puede concluir que el actual modelo constitucional y el activismo judicial estimulan la actividad legislativa del Poder Judicial, por regla general, guiada por el sesgo político de los actores involucrados, lo que compromete las bases de la democracia y da lugar a prácticas despóticas por parte de los tribunales.
Editorial
Authors: Calvete Ivanna
Published: August 2023

Este número 32 de la revista Nuevo Derecho trae una serie de artículos que giran en torno a la reflexión y análisis de los problemas contemporáneos del derecho que conflictúan en diferentes escenarios que permiten pensar y repensar los mecanismos habituales para entender la forma en la cual se ha venido desarrollando los estudios jurídicos. En este orden de ideas, el número está integrado por seis artículos que abordan problemáticas actuales y pertinentes respecto del derecho.
The role of the regulerend function of groundwater tax on the conservation of water resources
Authors: Mulyanti Dewi , Farida Ida , Nuriyah  , Amalia Emma , Setiadi Yadi
Published: August 2023

The use of water is highly needed for human primary needs and industry. Thus, the government issued a policy related to the function of regulating groundwater taxes to regulate the use of groundwater to make it in harmony with the sustainability of the preservation of water resources. The regulatory function of groundwater tax is not optimal and tax collection plays a greater role in local government revenue, so it does not support the conservation function of water sources. Thus, this research is important for researchers to formulate ‘what is the role of the regular function of the groundwater tax that applies in Indonesia?’ and ‘what is the regulatory model which can synergize groundwater taxes with water resource conservation?’

         This research uses several methods in data collection and compilation. The approach method used in this study is normative juridical under qualitative data analysis. The analytical descriptive method is employed to comprehensively describe and systematically examine primary and secondary data, which then analyzes the research object to provide a clear picture connected to relevant legal theories to find the government policy as the concept of thought.

The research result showed that the function of the groundwater tax regulerend has not played a role in the conservation of water resources. The role of regular function of groundwater tax requires it to be used to control the sustainable use of groundwater for the greatest prosperity of the people, both now and in the future. Through "emarking or emarked tax," a groundwater management model that synergizes with soil conservation can be applied. This means that groundwater tax revenue is allocated for the conservation or restoration of water resources due to groundwater utilization.
Interdisciplinary perspectives on conservation and culture
Authors: Yuniawan Isyanto Agus , Fatimah Ai Tusi , Thoyyibah Luthfiyatun , Millah Ana Samiatul
Published: August 2023

This article describes conservation and cultural perspectives from various disciplines based on research from various disciplines. The description is categorized into three parts; conservation and culture of applied science and health, conservation and culture of social science and humanity, conservation and culture of business and entrepreneurship. Natural sciences, health, social humanities, business, and entrepreneurship have all contributed to the conservation of natural resources and the environment, according to the results of journal article searches. Conservation in applied science promotes environmental, water, agricultural, biodiversity, and wildlife conservation, as well as land preservation and building reuse. Conservation can be accomplished through management and strategies derived from indigenous peoples' traditions with implications for nature conservation. The use of environmentally friendly health infrastructure is part of conservation in the health sector. Conservation is the study of the relationship between human interaction and the environment in a society in order to achieve a better life in the field of social sciences and humanities. Conservation strategy, policy, and education are important studies on conservation issues in the social sciences and humanities. Furthermore, conservation strategies are critical for identifying efficiency and conservation in support of development integration and disaster mitigation. Conservation and local wisdom-based education is a learning process that aims to raise environmental and cultural awareness and concern. In particular, conservation and local wisdom-based entrepreneurship education is a promising topic to be studied and researched further to generate various businesses that support environmental and cultural preservation.
To the question of the clinical nature of concomitant strabismus, functional disorders, and it's distribution in the population. Literary review
Authors:   Saint-Petersburg State Pediatric Medical University, Saint-Petersburg, Russian Federation, Kononova N.E. , Somov E.E. ,   Saint-Petersburg State Pediatric Medical University, Saint-Petersburg, Russian Federation,   S. Fyodorov Eye Microsurgery Federal State Institution, Saint-Petersburg Branch, Saint-Petersburg, Russian Federation, Efimova E.L. ,   Saint-Petersburg State Pediatric Medical University, Saint-Petersburg, Russian Federation
Published: August 2023

The presented literature review summarizes existent data of domestic and foreign researchers devoted to the clinical nature of strabismus, functional disorders in this pathology and its frequency in the population. The description of the main theories of the occurrence of strabismus was given by: A. Grefe, F. Donders, A. Parino and S. Worth. The spectrum of opinions on the types of inheritance of strabismus is analyzed. Patients with concomitant strabismus have also several functional disorders, such as binocular vision dysfunction and refractive-strabismus amblyopia. The views of leading ophthalmologists E.S. Avetisov, E.E. Somov, S.I. Rychkov, K.J. Ciuffreda and others on amblyopia, the criteria for diagnosis and its various classifications are presented. The considered studies allow us to conclude – treatment of children with concomitant strabismus remains a complex and multidisciplinary problem today. The knowledge of the functional features of various types of concomitant strabismus allows pathogenetically justified treatment of this pathology. Key words: concomitant strabismus, theories of the occurrence of strabismus, amblyopia, genetics of concomitant strabismus
THE SUBJECT AND THE OBJECT OF CONSCIOUSNESS: NEW APPROACHES TO THE OLD PROBLEM
Authors: POUCHKOV DMITRII
Published: August 2023

The article deals with the classical philosophical problem of the relationship between the subject and the object of consciousness. The author clarifies the basic concepts of this topic, such as “consciousness”, “external reality”, “subject of consciousness”, “object of consciousness”. Two key approaches to the problem of subject and object are compared: realism and subjective idealism. The author shows that the contradiction between the thesis “There is no object without a subject”, which prohibits any judgments about reality outside the subject, and the principle of causality, requiring the recognition of the existence of external reality, is of decisive importance for the discussion between realism and subjective idealism.
THE CONCEPT OF A HOLISTIC HUMAN IN THE RELIGIOUS AND PHILOSOPHICAL PSYCHOLOGY OF VIKTOR NESMELOV
Authors: BINEVSKAIA ANNA
Published: August 2023

The article presents an analysis of the concept of a holistic person in the religious and philosophical psychology of Viktor Nesmelov. The author provides an understanding of human nature on the basis of the spiritual and moral development of the individual. Due to the integrative method, Nesmelov revealed the integrity of man in the unity of his material and ideal nature. There are some psychological categories in the concept of a holistic person, such as consciousness, self-awareness, personality, worldview, free will, the creative nature of the individual, morality, spirituality, the meaning of life. The article describes a schematic theoretical model of a holistic person, in which the central link is the moral choice of the individual.
CONCEPTUAL APPROACHES TO PROFESSIONAL TRAINING OF ARCHITECTS AT SOCHI STATE UNIVERSITY
Authors: ANCHUKOV SERGEY
Published: August 2023

The article provides a rationale for conceptual approaches to the content of the educational programme for professional training of architects in the direction 07.03.01 “Architecture” (the “Architectural design” profile) at Sochi State University. The author considers the strategic and tactical goals of the successful functioning of the model of educational plan for professional training of architects, taking into account the design and urban realities of the resort city of Sochi, located on the northeastern coast of the Black Sea.
THE METHODOLOGY FOR STUDYING PILOTS’ READINESS FOR FLIGHT IN THE PROCESS OF COMBAT TRAINING
Authors: MAKLACHKOV EGOR , KULESHOV DMITRY , RUZOV ALEXEY
Published: August 2023

The article focuses on the readiness of flight personnel for flights. The authors review research works that reflect the need for psychological tracking during the preparation for flights, studying the flight mission, conducting trainings in order to reduce aviation incidents. The “Methodology for Diagnosing the Readiness of Flight Personnel for Upcoming Flights” Прикладные исследования, технологии 85 is presented. The technique is simple in application and data counting, and will be useful for psychologists, deputy squadron commanders for military-political work and flight crew commanders.
IDEAS OF COSMISM AND PHILOSOPHY OF EDUCATION: DIALOGUE AND TRANSVERSALITY
Authors: VOSKRESENSKIY ALEKSEY , GRYAKALOV ALEKSEY GRYAKALOV ALEKSEY , RABOSH VASILIY , SULTANOV KONSTANTIN
Published: August 2023

The article is devoted to the study of the ideological, methodological and value dialogue between the ideas of Russian cosmism and the concepts of modern domestic education. The authors carried out a study of the semantic constants of domestic education; the analysis of their holistic combination makes it possible to understand the architectonics of education in its specificity and development. The main attention is paid to the concepts of understanding, the correlation of natural and social patterns; the concept of transpedagogy, which has already received recognition in critical literature, is introduced into the scientific context. The formation of the ideas of the philosophy of education is corrected with the development of the history of philosophy - a dialogue appears as an interaction of theoretical constructions and projected practical programmes of education and upbringing. The consideration of the ideas of cosmism in their conceptual correlation with the philosophy of education involves the substantiation of a holistic view of the socialisation processes. Determination of semantic and pragmatic characteristics of transpedagogy, which can help to understand the heterogeneous processes of socialisation and education in a systemic integrity, makes it possible to understand the architectonics and effectiveness of domestic education in the post-global world.
TEACHING FOREIGN LANGUAGE COMMUNICATION TO PRIMARY SCHOOL STUDENTS AT THE ENGLISH LANGUAGE CLUB: FROM INFORMAL EDUCATION TO EXTRACURRICULAR ACTIVITIES
Authors: OREKHOVA ELENA , ULYANOVA ANNA
Published: August 2023

The concept of informal foreign language education for primary school students based on the analysis of problems with formal subject education is presented. The potential of a language club as a modern form of organising extracurricular activities for primary school students is opened, highlighting its effectiveness as a means of teaching foreign language communication. The linguodidactic strategy for integrating interdisciplinary modules into the activities of the English Language Club is justified as a means to improve the level of speech competence among children of primary school age.
THE POTENTIAL OF THE FUNDAMENTALS OF LIFE SAFETY COURSE IN THE FORMATION OF THE LEGAL CULTURE OF SCHOOLCHILDREN
Authors: AVERIANOVA LIUBOV
Published: August 2023

The article deals with the problem of the formation of legal culture in general education organisations, provides an analysis of requirements of the Federal State Educational Standard for the formation of legal culture of students, reflects the potential of the Fundamentals of Life Safety course in terms of legal culture formation, and also the conditions under which this potential can be realised. The data of the research among the teachers-organisers and Life Safety teachers are presented.
DEVELOPMENT OF PRODUCTIVE ACTIVITY OF SUBJECTS OF EDUCATION BY MEANS OF PSYCHOLOGICAL AND PEDAGOGICAL TECHNOLOGIES
Authors: ZHARINOVA YEVGENIYA
Published: August 2023

The relevance of the research is justified by the fact that modernity requires an increase in the productivity of graduates of higher educational institutions in independent formulation and solution of professional tasks, as well greater requirements for their quality and products they create. The purpose of the study is to develop, justify and test a system of psychological and pedagogical methods to identify indicators of productivity of education subjects, their development in the professional, educational and scientific environment of the university. The hypothesis that psychological training of personal growth and productive 28 Научное мнение № 4 (2023) interaction of subjects of education develops activity in communication, confidence, emotional stability, internal locus control has been confirmed. The author comes to a conclusion that the creation of innovative educational technologies plays an important role in the intensification of personal growth and productive interaction of subjects of education by means of psychological training.
PRACTICE AS A SYSTEM-FORMING FACTOR OF A NEW MODEL OF TRAINING LANGUAGE AND LITERATURE TEACHERS: THE CONCEPTUAL APPROACH
Authors: VILANDEBERK ANNA , SHUBINA NATALIA
Published: August 2023

The article presents the results of developing the concept of practice in the system of higher pedagogical education, which has undergone preliminary testing in the implementation of bachelor and master educational programmes at the Faculty of Philology of Herzen University. The authors determine the main approaches to a new understanding of the functional purpose of practice in the new conditions of civilisational changes, taking into account the challenges of the time, from the points of view of both the state and society. The main trends in the development of programmes for all types of practice are formulated.
THE DIGITAL ACMELINGUISTIC TECHNOLOGY IN THE INDIVIDUAL EDUCATIONAL TRAJECTORY OF A MODERN STUDENT
Authors: GRUNINA ELENA
Published: August 2023

This article deals with the digital acmelinguistic technology in the individual educational trajectory of a modern student as an effective way to improve the professional communicative competence in the independent study of a foreign language. The scientific novelty lies in the response to the requirement for practice-oriented learning, immersion of students in an authentic professional environment. The methodological basis is acmelinguistics. The theoretical and methodological justification is the acmeological, activity-based, interdisciplinary, intercultural and communicative approaches. The principles of interfacing cultures, methods of content analysis, description of a communicative situation and participant observation prove that with the help of the technology under study it is possible to solve such important issues as: the development and improvement of different types of speech; unlocking of the creative potential; the ability to use an authentic learning environment to find the information needed.
HE PROPER PSYCHOLOGICAL LEVEL OF SELF-REGULATION OF SERVICE ACTIVITIES OF ROSGVARDIYA EMPLOYEES
Authors: UCHAEV NIKITA , ZOBKOV ALEKSANDR , KRUCHININA GALINA
Published: August 2023

The article describes the personalities of Rosgvardiya employees at the proper psychological level of self-regulation of service activities. The authors reveal the emotional profile of the employees’ personalities, their motivational orientation and type of selfesteem, self-evaluation of the emotional state, reflexivity and totality of personal qualities. The study was conducted on a sample of employees (n = 129). The authors present a structural organisation of the employees’ self-regulation at the proper psychological level of its analysis.
TECHNIQUES OF FORMING THE COMPENSATORY COMPETENCE IN FOREIGN LANGUAGE LESSONS AT NON-LINGUISTIC HIGHER EDUCATION INSTITUTIONS
Authors: AIMALETDINOV RENAT
Published: August 2023

This paper considers the formation of the compensatory competence through the example of specific techniques and exercises used in foreign language classes. The author analyses the peculiarity of using these techniques and exercises in the context of professionally oriented education of pedagogy students at non-linguistic universities.
“ESSAYS ON THE PIANO METHODS” BY M. N. BARINOVA IN HISTORY AND MODERNITY
Authors: SMIRNOVA MARINA
Published: August 2023

The article analyses the work of the famous musician of the first half of the 20th century M. N. Barinova “Essays on the Piano Methods”, which has been repeatedly reprinted. The structure of the work and its main problems are considered. Particular attention is paid to understanding those issues that have not lost their relevance for the current situation in piano teaching. These include the professional demand for pianists and their predisposition to various types of activity, primarily pedagogy.
TECHNICAL IMPROVEMENT OF PIANISTS USING THE “NOTEBOOK FOR THE YOUTH” BY RODION SHCHEDRIN
Authors: SMIRNOVA MARINA , WU YI
Published: August 2023

The paper deals with the original work of the Russian composer Rodion Shchedrin “Notebook for the Youth”. It is based on the analysis of technical problems facing teachers and students when learning this composition. A young pianist faces extraordinary tasks related to the peculiarities of the composer’s modern musical language, which gives rise to unusual technical difficulties. The paper is devoted to the ways to overcome them.
PHILOSOPHY OF SCHOOL IN THE LIGHT OF THE THEORY OF POST-INDUSTRIAL SOCIETY: THEORETICAL FOUNDATIONS AND DIRECTIONS OF CRITICISM
Authors: TYLIK ARTEM
Published: August 2023

The article is devoted to the analysis of the theory of speech generation in terms of the methodology of teaching foreign languages. Different views on the theory of speech generation are noted and for the first time the connection between research in the field of speech processes and teaching methods is substantiated. The author is talking about the methodology of teaching foreign languages. The language considered in the article is Chinese. According to the results of the study, it is concluded that today the methodology of teaching Chinese is poorly developed in the Russian scientific and methodological field. The methodology of teaching foreign languages in general needs the latest research and modern developments based on the theory of speech generation
A “PICTURE OF THE WORLD” AS A BASIC CONCEPT OF PSYCHOLOGICAL SECURITY OF A EDUCATIONAL INFORMATION ENVIRONMENT
Authors: SITNOV MIKHAIL
Published: August 2023

The article deals with the issues of attributing models of the educational information environment of distance education based on the “picture of the world” concept. It is noted that the fundamental point of the distance type of education is the ability of students to form their own personal educational information environment. At this stage of understanding the problem of psychological security, issues of personal security in interaction with an educational information environment and the use of distance education in general can be considered only as special cases of the general classification of types of security, where two of its backbone types are generic: physical and psychological ones. The main emphasis in the development of an educational information environment and distance education in general should be done on the study and creation of preventive methodological and instrumental means of ensuring safety in education, where the basic categories should be the concepts of forming a “picture of the world”, integrity of the worldview, based on the development of the moral and psychological world of participants in the interaction of the educational information environment.
https://elibrary.ru/item.asp?id=54084082
Authors: PANKRATOVA TATIANA
Published: August 2023

The article is devoted to the formation of self-presentation in older preschool children. The author analyses psychological and pedagogical research on this issue, revealing the peculiarities of the formation of self-presentation in older preschool children. The main attention is paid to the formation of self-presentation in older preschool children, since children of this age, after a short period of time, move to a new stage of life at school. The formation of self-presentation will take place with the help of didactic games. Didactic games and exercises were developed taking into account the age and individual characteristics of older preschool children. The article reveals the specifics of using didactic games and exercises with older preschool children.
THE THEORY OF SPEECH GENERATION AS AN IMPORTANT ASPECT OF THE METHODOLOGY OF TEACHING FOREIGN LANGUAGES
Authors: GORSTKA DMITRY
Published: August 2023

The article is devoted to the analysis of the theory of speech generation in terms of the methodology of teaching foreign languages. Different views on the theory of speech generation are noted and for the first time the connection between research in the field of speech processes and teaching methods is substantiated. The author is talking about the methodology of teaching foreign languages. The language considered in the article is Chinese. According to the results of the study, it is concluded that today the methodology of teaching Chinese is poorly developed in the Russian scientific and methodological field. The methodology of teaching foreign languages in general needs the latest research and modern developments based on the theory of speech generation.
THE CONTENT AND FUNCTIONAL FEATURES OF THE EDUCATIONAL TOURISM TECHNOLOGIES
Authors: KRYSOVA ELENA
Published: August 2023

The paper deals with the analysis of the educational tourism technologies as a complex phenomenon in the context of the development of the pedagogical and educational potential of the main types of tourism. The scientific novelty of the study lies in the clarification of the terminological boundaries of the educational tourism technologies and the disclosure of their functional features.
THE RELATION OF THE LOGICAL AND THE IRRATIONAL IN THE PHILOSOPHICAL TEACHINGS OF G. V. F. HEGEL AND A. SCHOPENHAUER
Authors: VOLODIN YAROSLAV
Published: August 2023

The article examines the process of formation of the principles of philosophical cognition, the relation of consciousness to reality, thinking and being, based on the metaphysical foundations laid down in the philosophical teachings of G. V. F. Hegel and A. Schopenhauer. The concepts of thinkers are analysed from the point of view of their influence on modern philosophy. The author proceeds from the fact that the logical teaching of Hegel and the irrationalist philosophy of Schopenhauer historically contributed to the formation of consciousness, spontaneously combining logical thinking and irrational perception of reality.
FEATURES OF INTERPERSONAL RELATIONS OF MILITARY PERSONNEL WITH DIFFERENT STRATEGIES OF BEHAVIOUR IN CONFLICT
Authors: PROKOFYEVA VIKTORIA
Published: August 2023

The article analyses theoretical and methodological approaches to the problem of conflicts, its features, types and causes of occurrence. The analysis of various types of interpersonal relationships among military personnel is presented. The authors consider the interrelation of types of interpersonal relations and behaviour strategies of cadets of a military institute in resolving conflict situations in educational and military professional activities.
FEATURES OF SOCIALISATION OF CADETS IN MILITARY UNIVERSITIES OF THE NATIONAL GUARD FORCES COMMAND OF THE RUSSIAN FEDERATION
Authors: BELYUSHINA IRINA
Published: August 2023

The article analyses the process of socialisation of cadets of military universities of the National Guard Forces Command of the Russian Federation and highlights its features related to the specifics of military professional training of future servicemen. The author notes the rapid transition of intergroup and intra-group relations from the formal level to the informal one while maintaining fairly strict regulation.
TEACHING LANDSCAPE PAINTING TO DESIGN STUDENTS (BASED ON THE UNIVERSITIES OF RUSSIA AND CHINA)
Authors: QI ZHUO
Published: August 2023

With the advent of the era of globalisation, different countries are faced with the need to exchange experience, including in the field of design education that is in demand now. At present, the scope of professional activity in the field of environmental, artistic and landscape design is becoming more and more extensive, and projects associated with it are becoming more and more complex. They not only pursue the realisation of a variety of forms and functions, technologies and materials, but also pay attention to how the idea is embodied, in which the figurative-emotional principle is expressed. In the methodology of teaching design in the universities of Russia and China, the role of such a discipline as painting and landscape in particular is being updated. Analysing the programmes of two reputable educational institutions 78 Научное мнение № 6 (2023) (Saint Petersburg Stieglitz State Academy of Art and Design and the School of Design and Art of Hunan University), the author of the paper considers the role of landscape painting in the training of designers.
POINT OF VIEW: SOFT SKILLS IN THE ENGLISH CLASSROOM
Authors: KUDINOVA NATALIA , CHANTURIDZE YULIA
Published: August 2023

This paper expresses an opinion on the part the English classroom may play in the development of soft skills. With the shift of the educational paradigm towards soft skills, a significant number of courses focusing on them have been introduced into the university curricula all over the world. Even though the English classroom seems to have considerable potential for 51 honing soft skills, which is reflected in the updated issue of the CEFR, there are no standalone courses on soft skills in English. In this paper we point out that there is a long tradition of embedding tasks on developing some soft skills into the English language course and provide examples from various coursebooks. We argue that it is high time this gained experience was transformed into a standalone course in which English stops being a goal and becomes a means.
Design of an Ad Hoc Bifunctional Chiral Ligand for the Preparation of Low-Dimensional Perovskites
Authors: Malavasi Lorenzo , Coccia Clarissa , Porta Alessio , Moroni Marco
Published: August 2023

We report here the preparation of a novel bifunctional chiral ligand (R) and (S)-1-ammino-2-butanol (AMOL) containing both an amine and hydroxyl group and its use in the preparation of chiral lead iodide perovskites. The incorporation of this bifunctional ligand leads to the synthesis of the [(R-/S-)-AMOL]2PbI3·I samples characterized by an uncommon structural motif composed by 1D double chains running along the crystallographic c-axis built up by face-sharing [PbI6]4- octahedra. Chiroptical properties determination shows and effective chirality transfer from the novel chiral ligands to the inorganic framework with a relevant optical response. The expansion of the library of actually known chiral ligands will not only help the design of novel chiral perovskites but will also provide useful insight into the definition of solid structure-property correlations.
Aggregation-induced emission materials based on restriction of intramolecular vibration
Authors: Lau Andreis , Yang Zhan , Wu Bo , Qiu Zijie , Zhao Zheng , Tang Ben Zhong
Published: August 2023

Aggregation-induced emission (AIE) is a photophysical phenomenon wherein luminescent materials exhibit weak emission in solution but strong emission after aggregation. This phenomenon has garnered significant attention in the realm of multifunctional luminescent materials. Specifically, AIE molecules, which operate through the restriction of intramolecular vibration (RIV) mechanism, have emerged as a pivotal constituent of AIE materials, captivating the interest of both academia and industry. This review aims to present a comprehensive overview of recent advancements in the domain of RIV-type AIE and its associated areas. It encompasses a survey of the classifications, molecular design strategies, and mechanisms underlying RIV-type AIE molecules. Furthermore, the review delves into the prospects and challenges encountered in the realm. We hope this review can provide novel insights into the theory, materials, and applications in the field of biochemistry and organic photoelectric.
Ultra-Microporous Fe-MOF with Exceptional NO Delivery Kinetics in Biological Media for Therapeutic Application
Authors: Pinto Rosana V , Cao Chen Chen , Lyu Pengbo , Dovgaliuk Iurii , Su Chen-Yong , Maurin Guillaume , Antunes Fernando , Pires Joao , André Vania , Henriques Carlos , Tissot Antoine , Pinto Moises , SERRE Christian
Published: August 2023

Nitric oxide (NO), as a key element in the regulation of essential biological mechanisms, presents huge potential as a therapeutic agent in the treatment and prevention of chronic diseases. Metal-organic frameworks (MOFs) with open metal sites are promising carriers for NO therapies but delivering it over an extended period in biological media remains a great challenge due to (i) a fast degradation of the material in body fluids and/or (ii) a rapid replacement of NO by water molecules onto the Lewis acid sites. Here, we propose an unprecedented NO adsorption mechanism based on a new ultra-narrow pores Fe bisphosphonate MOF, denoted MIP-210(Fe) or Fe(H2O)(Hmbpa) (Hmbpa = p-xylenediphosphonic acid). In MIP-210(Fe), the coordination of NO through the Fe(III) sites is unusually preferred, replacing the water, and creating a stable interaction with the free H2O and P-OH groups delimiting the very narrow pores. This, associated with the high chemical stability of the MOF enables a very slow replacement of NO by water molecules in biological media, achieving an extraordinarily extended NO delivery over at least 72 hours, exceeding by far the NO kinetics release reported by others porous materials, paving the way for the development of safe and successful gas therapies.
Laboratory Kilogram-Scale Graphene Production from Coal
Authors: Eddy Lucas , Luong Duy Xuan , Beckham Jacob , Wyss Kevin , Cooksey Tyler , Scotland Phelecia , Choi Chi Hun , Chen Weiyin , Advincula Paul , Zhang Zhiyong , Mancevski Vladimir , Tour James
Published: August 2023

The flash Joule heating (FJH) method converts many carbon feedstocks into graphene in milliseconds to seconds using an electrical pulse. This opens an opportunity for processing low or negative value resources, such as coal and plastic waste, into high value graphene. Here, we demonstrate a lab-scale automation FJH system that allows the synthesis of 1.1 kg of turbostratic flash graphene from coal-based metallurgical coke (MC) in 1.5 h. The process is based on the automated conversion of 5.7 g of MC per batch using an electrical pulse width modulation system to conduct the bottom-up upcycle of MC into flash graphene. We then compare this method to two other scalable graphene synthesis techniques by both a life cycle assessment and a technoeconomic assessment.
Highly luminescent TCNQ in melamine
Authors: Mishra Vipin , Mantel Arthur , Kapusta Peter , Prado-Roller Alexander , Shiozawa Hidetsugu
Published: August 2023

Optical properties of molecules change drastically as results of interactions with surrounding environments as observed in solutions, clusters and aggrergates. Here we make 7,7,8,8-tetracyanoquinodimethane (TCNQ) highly luminescent by encapsulating it in crystalline melamine. Coloured single crystals are synthesized by slow evaporation of a solution of melamine and TCNQ in water and tetrahydrofuran. Single crystal X-ray diffraction reveals the lattice structure of pure melamine, meaning that the colour is of impurities. Both mass spectrometry and UV-Vis spectroscopy combined with density-functional theory calculations elucidate that the impurity species are neutral TCNQ and its oxidation product, dicyano-$p$-toluoyl cyanide anion (DCTC$^-$), whose concentrations in a melamine crystal can be controlled by adjusting the molar ratio between melamine and TCNQ in the precursor solution. Fluorescence exciation-emission wavelength mappings on the precursor solutions illustrate dominant emissions from DCTC$^-$ while the emission from TCNQ is quenched by the resonance energy transfer to DCTC$^-$. On the contrary, TCNQ in crystalline melamine is a bright fluorophore whose emission wavelength centered at 450 nm and slow fluorescence lifetimes of about 2 ns. Our method of encapsulating molecules into transparent melamine would make many other molecules fluorescencent in solids.
Interlaboratory Study Assessing the Analysis of Supercapacitor Electrochemistry Data
Authors: Gittins Jamie W. , Chen Yuan , Arnold Stefanie , Augustyn Veronica , Balducci Andrea , Brousse Thierry , Frackowiak Elzbieta , Gómez-Romero Pedro , Kanwade Archana , Köps Lukas , Jha Plawan Kumar , Lyu Dongxun , Meo Michele , Pandey Deepak , Pang Le , Presser Volker , Rapisarda Mario , Rueda-García Daniel , Saeed Saeed , Shirage Parasharam M. , Ślesiński Adam , Soavi Francesca , Thomas Jayan , Titirici Maria-Magdalena , Wang Hongxia , Xu Zhen , Yu Aiping , Zhang Maiwen , Forse Alexander C.
Published: August 2023

Supercapacitors are fast-charging energy storage devices of great importance for developing robust and climate-friendly energy infrastructures for the future. Research in this field has seen rapid growth in recent years. Therefore, consistent reporting practices must be implemented to enable reliable comparison of device performance. Although several studies have highlighted the best practices for analysing and reporting data from such energy storage devices, there is yet to be an empirical study investigating whether researchers in the field are correctly implementing these recommendations, and which assesses the variation in reporting between different laboratories. Here, we address this deficit by carrying out the first interlaboratory study of the analysis of supercapacitor electrochemistry data. We find that the use of incorrect formulae and researchers having different interpretations of key terminologies are the primary causes of variability in data reporting. Furthermore, we highlight the more significant variation in reported results for electrochemical profiles showing non-ideal capacitive behaviour. From the insights gained through this study, we make additional recommendations to the community to help ensure consistent reporting of performance metrics moving forward.
Systematic exploration of accessible topologies of cage molecules via minimalistic models
Authors: Tarzia Andrew , Wolpert Emma H. , Jelfs Kim E. , Pavan Giovanni M.
Published: August 2023

Cages are macrocyclic structures with an intrinsic internal cavity that support applications in separations, sensing and catalysis. These materials can be synthesised via self-assembly of organic or metal-organic building blocks. Their bottom-up synthesis and the diversity in building block chemistry allows for fine-tuning of their shape and properties toward a target property. However, it is not straightforward to predict the outcome of self-assembly, and, thus, the structures that are practically accessible during synthesis. Indeed, such a prediction becomes more difficult as problems related to the flexibility of the building blocks or increased combinatorics lead to a higher level of complexity and increased computational costs. Molecular models, and their coarse-graining into simplified representations, may be very useful to this end. Here, we develop a minimalistic toy model of cage-like molecules to explore the stable space of different cage topologies based on a few fundamental geometric building block parameters. Our results capture, despite the simplifications of the model, known geometrical design rules in synthetic cage molecules and uncover the role of building block coordination number and preorganisation on the stability of cage topologies. This leads to a large-scale and systematic exploration of design principles, generating data that we expect could be analysed through expandable approaches toward the rational design of self-assembled porous architectures.
Branched-Selective Cross-Electrophile Coupling of 2-Alkyl Aziridines and (Hetero)aryl Iodides Using Ti/Ni Catalysis
Authors: Williams Wendy L. , Gutiérrez-Valencia Neyci E. , Doyle Abigail
Published: August 2023

The arylation of 2-alkyl aziridines by nucleophilic ring-opening or transition metal-catalyzed cross-coupling enables facile access to biologically relevant beta-phenethylamine derivatives. However, both approaches largely favor C–C bond formation at the less substituted carbon of the aziridine, thus enabling access to only linear products. Consequently, despite the attractive bond disconnection it poses, the synthesis of branched arylated products from 2-alkyl aziridines has remained inaccessible. Herein, we address this long-standing challenge and report the first branched-selective cross-coupling of 2-alkyl aziridines with aryl iodides. This unique selectivity is enabled by a Ti/Ni dual-catalytic system. We demonstrate the robustness of the method by a two-fold approach: an additive screening campaign to probe functional group tolerance and a feature-driven substrate scope to study the effect of the local steric and electronic profile of each coupling partner on reactivity. Furthermore, the diversity of this feature-driven substrate scope enabled the generation of predictive reactivity models that guided mechanistic understanding. Mechanistic studies demonstrated that the branched selectivity arises from a Ti(III)-induced radical ring-opening of the aziridine.