bluuebunny/crossref_metadata_2025 huggingface dataset:
Analysis of the Properties of Modified Asphalt Binder by FTIR Method
Authors: Lim Chi-Su , Jang Dae-Sung , Yu Sang-Min , Lee Jae-Jun
Published: August 2022

The usage of modified asphalt binder in road pavements has been increasing in the past few decades. Therefore, quality control and understanding of modified asphalt binders have become an important issue. This study was conducted as a part of a larger study on the efficient management of these modified asphalt binders by evaluating the characteristics of asphalt binders mixed with styrene–butadiene–styrene (SBS), ethylene-vinyl acetate (EVA), and wax-based warm-mix additives using Fourier transform infrared (FTIR) analysis. For original asphalt binders modified with SBS, response wavenumbers were 700 and 966 cm−1, which means a particular wavenumber of polybutadiene and polystyrene, while in the case of binders modified with EVA, peak response wavenumbers were at 1242 and 1739 cm−1, which represents a particular wavenumbers of a single stretching bond between carbon and hydrate and a double stretching bond between carbon and oxygen. Asphalt binders modified with wax-type additives showed peak response at 730 and 1540 cm−1, which represents a double stretching bond of carbon and a single stretching bond between nitrogen and oxygen. It was also found that peak values increased as addition rates also increased. The results showed that the additives used in this study have particular wavenumbers that show peak responses even when mixed into asphalt binders. Using these characteristics of the additives, FTIR analysis confirms that it is possible to determine whether or not a binder has been modified.
Distinguishing Genuine Imperial Qing Dynasty Porcelain from Ancient Replicas by On-Site Non-Invasive XRF and Raman Spectroscopy
Authors: Colomban Philippe , Gironda Michele , Simsek Franci Gulsu , d’Abrigeon Pauline
Published: August 2022

The combined use of non-invasive on-site portable techniques, Raman microscopy, and X-ray fluorescence spectroscopy on seven imperial bowls and two decorated dishes, attributed to the reigns of the Kangxi, Yongzheng, Qianlong, and Daoguang emperors (Qing Dynasty), allows the identification of the coloring agents/opacifiers and composition types of the glazes and painted enamels. Particular attention is paid to the analysis of the elements used in the (blue) marks and those found in the blue, yellow, red, and honey/gilded backgrounds on which, or in reserve, a floral motif is principally drawn. The honey-colored background is made with gold nanoparticles associated with a lead- and arsenic-based flux. One of the red backgrounds is also based on gold nanoparticles, the second containing copper nanoparticles, both in lead-based silicate enamels like the blue and yellow backgrounds. Tin and arsenic are observed, but cassiterite (SnO2) is clearly observed in one of the painted decors (dish) and in A676 yellow, whereas lead (calcium/potassium) arsenate is identified in most of the enamels. Yellow color is achieved with Pb-Sn-Sb pyrochlore (Naples yellow) with various Sb contents, although green color is mainly based on lead-tin oxide mixed with blue enamel. The technical solutions appear very different from one object to another, which leads one to think that each bowl is really a unique object and not an item produced in small series. The visual examination of some marks shows that they were made in overglaze (A608, A616, A630, A672). It is obvious that different types of cobalt sources were used for the imprinting of the marks: cobalt rich in manganese for bowl A615 (Yongzheng reign), cobalt rich in arsenic for bowl A613 (but not the blue mark), cobalt with copper (A616), and cobalt rich in arsenic and copper (A672). Thus, we have a variety of cobalt sources/mixtures. The high purity of cobalt used for A677 bowl indicates a production after ~1830–1850.
Preparatory Conditions Optimization and Characterization of Hierarchical Porous Carbon from Seaweed as Carbon-Precursor Using a Box—Behnken Design for Application of Supercapacitor
Authors: Yang Wein-Duo , Wang Jing-Xuan , Wu Yu-Tse , Chang Hsun-Shuo , Ko Horng-Huey
Published: August 2022

This study has developed an environmentally friendly, simple, and economical process by utilizing seaweed as a carbon precursor to prepare a hierarchical porous carbon for the application of a supercapacitor. In the carbonization process, the design of experiment (DOE) technology is used to obtain the optimal preparatory conditions with the best electrochemical properties for the electrode materials of supercapacitors. Without using strong acid and alkali solution of the green process, NaCl is used as the pore structure proppant of seaweed (SW) for carbonization to obtain hierarchical porous carbon material to improve the pore size distribution and surface area of the material. In the experiment of SW activation, the interaction between factors has been explored by the response surface methodology (RSM) and Box–Behnken design, and the optimal conditions are found. The activated carbon with the specific surface area of 603.7 m2 g−1 and its capacitance reaching 110.8 F g−1 is successfully prepared. At a current density of 1 A g−1, the material still retains 95.4% of the initial capacitance after 10,000 cycles of stability testing. The hierarchical porous carbon material prepared by the design of experiment planning this green process has better energy storage properties than supercapacitors made of traditional carbon materials.
Impacts of Lubricant Type on the Densification Behavior and Final Powder Compact Properties of Cu–Fe Alloy under Different Compaction Pressures
Authors: Korim Nada S. , Elsayed Ayman , Hu Lianxi
Published: August 2022

A Cu–15Fe alloy was fabricated using a powder metallurgy (PM) route, with the addition of different solid lubricants (i.e., paraffin wax (PW) and stearic acid (SA) as well as their composites (PW+SA)). Green compacts were produced via cold compaction at different pressure levels of 50 MPa, 200 MPa, and 350 MPa, then sintered for 60 min under vacuum at 1050 °C. The systematic evolution of the densification, porosity, and pore-size behavior were studied. Vickers Hardness Tests were used to measure hardness. The analysis of the morphological alterations was performed using scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques. Moreover, under dry sliding conditions, pin-on-disk wear tests were conducted in order to determine tribological properties such as the coefficient of friction (µ), specific wear rate (K), and friction temperature gain. Results revealed that the lubrication process and compaction pressure play a crucial role in defining the characteristics of the final compact. Higher sintered densities and hardnesses were achieved at 50 MPa when PW was used as a solid lubricant, and became reduced as the compaction pressure increased. In contrast, in the case of SA, higher sintered densities and hardnesses were obtained at a compaction pressure of 350 MPa, and increased with increasing pressure. Moreover, PW samples exhibited lower coefficients of friction and wear properties. The addition of SA improves the wear loss of friction materials as well as their coefficients of friction. Compared to blank and PW samples, SA samples show a nearly 50% reduction in wear rate.
Modeling and Analysis of Micro-Grinding Processes with the Use of Grinding Wheels with a Conical and Hyperboloid Active Surface
Authors: Kacalak Wojciech , Szafraniec Filip , Lipiński Dariusz , Banaszek Kamil , Rypina Łukasz
Published: August 2022

In this article, a method of grinding small ceramic elements using hyperboloid and conical grinding wheels was presented. The method allowed for machining with a lower material removal speed and extending the grinding zone without reducing the efficiency of the process. In order to assess the process output parameters, numerical simulations were carried out for single-pass machining. This strategy allows for automation of the process. Grinding with a low material removal speed is recommended for the machining of small and thin elements, since this can avoid fracturing the elements. The methodology for selecting process parameters as well as the results of the abrasive grains activity analyses were presented. The analyses also concerned the roughness of machined surfaces and the variability of their textures. This grinding method was applied in the production of small ceramic elements that are used in the construction of electronic systems, and in the processing of small piezoceramic parts. This grinding technique could also be used in other grinding processes, where the removal of small machining allowances with high efficiency is required.
Influence of Ca2+ on Early Degradation of Cast-In-Situ Mortar Induced by Sulfate-Magnesium Multiple Combined Attack
Authors: Zhao Gaowen , Guo Mengzhen , Li Shaomin , Weng Xiaolin , Ding Shijun , Han Fangzhou , Wang Haoran
Published: August 2022

Early degradation of cast-in-situ concrete induced by multiple internal–external sulfate combined attacks significantly affects the development of concrete strength. An experimental study regarding the effects of Ca2+ on the early degradation of cast-in-situ mortars subjected to internal–external sulfate and magnesium combined attacks is investigated in this paper. In particular, a specific method for accurately simulating the degradation of cast-in-situ structures was proposed in this experiment. Physical properties (including weight, size changes, and porosity), mechanical properties (including flexural strength and compressive strength), sulfate concentration, and microstructural properties were monitored during 28 days of immersion. The results show that an internal sulfate and magnesium combined attack (ISA-IMA) obviously retards the development of early strength and accelerates the degradation induced by external sulfate attack (ESA). The diffusion path of sulfate ions from outside is blocked by flake-shaped magnesium hydrates, delaying the penetration of external sulfate attacks. However, it is far from neutralizing the strength loss induced by an internal magnesium attack (IMA) at an early age. Premixed excessive Ca2+ would improve the strength development and pore structure of concrete or mortar, enhancing durability against corrosive conditions.
Use of Organic Materials to Limit the Potential Negative Effect of Nitrogen on Maize in Different Soils
Authors: Brodowska Marzena S. , Wyszkowski Mirosław , Kordala Natalia
Published: August 2022

This study was launched to test organic materials in the form of humic acids (HA) applied to soil to improve the effect of nitrogen on maize, and to determine an optimal dose of HA, which will be ecologically safe and will counteract potential negative (phytotoxic) influences of excessive nitrogen fertiliser doses, on two soils with different textural composition. The maize plants grown on the loamy sand were characterised by a higher value of the SPAD leaf greenness index, yields, and a lower content of total-N and sulphate sulphur in maize. Urea, and especially UAN, promoted higher SPAD leaf greenness index values during the stem elongation stage and particularly during the tassel emergence stage. The effect of urea on maize yields was positive on both soils, but UAN had a positive effect on this parameter only on the loamy sand. HA tended to increase the SPAD leaf greenness index. The impact of HA on plant height and yields (especially medium dose) was generally positive. However, a negative effect of the interaction of HA with UAN on the plant height and maize yield on the sand was observed. HA caused an increase in the total-N content, and their highest dose also decreased the sulphate sulphur content in maize. The application of HA to soil has a positive influence on the growth and development of plants and can create positive effects by mitigating adverse consequences of intensive agricultural production in the natural environment.
Rebuilding of Turbocharger Shafts by Hardfacing
Authors: Kupiec Bogdan , Opiekun Zenon , Dec Andrzej
Published: August 2022

This paper presents the results of structural tests and hardness measurements of rebuilding coatings manually applied by the gas tungsten arc welding (GTAW) method on damaged surfaces of steel shafts of turbochargers of automotive engines. Single- and double-layer coatings were applied in an argon atmosphere by fusing a 1.2 mm diameter wire with a Fluxofil M58 flux core, using a current of 35A and an arc voltage of 8–9 V. The hardfacing resulted in coatings with a martensitic–bainitic structure with fine dispersed carbides rich in M23C6-type chromium. The hardness of the coatings on the rebuilt shafts averaged from about 740HV5 for the single-layer coating to about 770HV5 for the double-layer coating and was two times higher than the hardness of the tempered shafts without coatings.
Current Trends in Wick Structure Construction in Loop Heat Pipes Applications: A Review
Authors: Szymanski Pawel , Mikielewicz Dariusz , Fooladpanjeh Sasan
Published: August 2022

Thermal control systems have been introduced as an important part of electronic devices, enabling thermal management of their electronic components. Loop heat pipe (LHP) is a passive two-phase heat transfer device with significant potential for numerous applications, such as aerospace applications, high-power LEDs, and solar central receivers. Its advantages are high heat transfer capability, low thermal resistance, long-distance heat transfer, and compact structure. The essential role of wick structures on the performance of LHPs has already been highlighted, but no comprehensive review is available that deals with different parameters such as LHP design and wick size, which are largely decisive and effective in achieving a practical level of thermal transmission governed by wick structures. To rely on this necessity, this article summarizes, analyzes, and classifies advancements in the design and fabrication of wick structures. The main conclusion to be drawn after careful monitoring and weighing of the related literature is that LHPs with composites and additively manufactured wicks show a higher heat transfer coefficient than other conventional structures. Indeed, future works should be focused on the design of more structurally efficient wicks, which may allow us to optimize materials and geometrical parameters of wick structure for higher heat transfer through LHPs.
Research on the Evolution Law Physical Short Fatigue Crack and Tip Deformation Fields during Crack Closure Process of the Q&P Steel
Authors: Shang Hongbin , Lin Zhiyuan , Gao Hongli , Shan Xiaofeng , Zhan Jingsong
Published: August 2022

In this paper, a novel dual microscopic fatigue-crack and tip-deformation-fields measurement method based on a hybrid image-processing technique is proposed that was used to research the physical short fatigue crack (SFC) closure effect and the evolution law of the tip deformation fields of Quenching–Partitioning (Q&P) steel during the crack-closure process. The measurement problems are solved, such as the small SFC tip region, large deformation gradient, and strong material anisotropy. Microscopic crack and speckle images are acquired simultaneously on both sides of a compact tensile (CT) specimen of Q&P steel by dual microscopic cameras. A digital image processing (DIP) method is used to identify crack-growth morphology and measure crack length in Q&P steel, and the SFC growth rates are analyzed under different stress ratios. Microscopic digital image correlation (Micro-DIC) is used to analyze displacement fields at the crack tip of SFC and, combined with virtual extensometer technology, analyze the evolution law of crack closure and the evolution of crack-growing morphologies during the closure process under different lengths and stress ratios. Accordingly, the evolution of strain fields at the crack tip in one load cycle for different crack lengths and stress ratios during the SFC closure process is analyzed. The results show that the stress ratio affects the crack-closure behavior and crack growth rate of Q&P steel in the physical SFC crack-growing stage. The crack-closure effect has an obvious influence on the evolution process of displacement and strain fields at the crack tip. The evolution of short-fatigue-crack-tip morphology and strain field of Q&P steel conforms to the crack-closure law. The research results provide experimental and theoretical support for the further study of the SFC growth mechanism and fatigue life prediction of Q&P steel.
Damage Evolution Characteristics of Back-Filling Concrete in Gob-Side Entry Retaining Subjected to Cyclical Loading
Authors: Gao Xicai , Liu Shuai , Zhao Cheng , Yin Jianhui , Fan Kai
Published: August 2022

The back-filling body in the gob-side entry retaining is subject to continuous disturbance due to repeated mining. In this study, uniaxial and cyclical loading tests of back-filling concrete samples were carried out under laboratory conditions to study damage evolution characteristics with respect to microscopic hydration, deformation properties, and energy evolution. The results showed that, due to the difference in the gradation of coarse and fine aggregates, the cemented structure was relatively loose, and the primary failure modes under cyclical loading were tensile and shearing failure, which significantly decreased its strength. With an increasing number of loadings, a hysteresis loop appeared for the axial strain, and the area showed a pattern of decrease–stabilization–increase. This trend, to a certain extent, reflected the evolution of the cracks in the back-filling concrete samples. The axial, radial, and volumetric plastic strain curves of the back-filling concrete samples showed a “U” shape. The plastic strain changed in three stages, i.e., a rapid decrease, stabilization, and a rapid increase. A damage parameter was defined according to the plastic strain increment to accurately characterize the staged failure of the samples. The plastic strain and energy dissipation of the samples were precursors to sample failure. Prior to the failure of the back-filling samples, the amount and speed of change of both the plastic strain and energy parameters increased significantly. Understanding the characteristics of plastic strain, damage evolution, and energy dissipation rate of the back-filling samples are of great reference value for realizing real-time monitoring of back-filling concrete in the gob-side entry retaining and providing early warning of failure.
Two Magnetic Orderings and a Spin–Flop Transition in Mixed Valence Compound Mn3O(SeO3)3
Authors: Zhang Wanwan , Cui Meiyan , Tian Jindou , Jiang Pengfeng , Qian Guoyu , Lu Xia
Published: August 2022

A mixed-valence manganese selenite, Mn3O(SeO3)3, was successfully synthesized using a conventional hydrothermal method. The three-dimensional framework of this compound is composed of an MnO6 octahedra and an SeO3 trigonal pyramid. The magnetic topological arrangement of manganese ions shows a three-dimensional framework formed by the intersection of octa-kagomé spin sublattices and staircase-kagomé spin sublattices. Susceptibility, magnetization and heat capacity measurements confirm that Mn3O(SeO3)3 exhibits two successive long-range antiferromagnetic orderings with TN1~4.5 K and TN2~45 K and a field-induced spin–flop transition at a critical field of 4.5 T at low temperature.
Universal Dependence of Nuclear Spin Relaxation on the Concentration of Paramagnetic Centers in Nano- and Microdiamonds
Authors: Panich Alexander M.
Published: August 2022

An analysis of our data on 1H and 13C spin–lattice and spin–spin relaxation times and rates in aqueous suspensions of purified nanodiamonds produced by detonation technique (DNDs), DNDs with grafted paramagnetic ions, and micro- and nanodiamonds produced by milling bulk high-temperature high-pressure diamonds is presented. It has been established that in all the studied materials, the relaxation rates depend linearly on the concentration of diamond particles in suspensions, the concentration of grafted paramagnetic ions, and surface paramagnetic defects produced by milling, while the relaxation times exhibit a hyperbolic dependence on the concentration of paramagnetic centers. This is a universal law that is valid for suspensions, gels, and solids. The results obtained will expand the understanding of the properties of nano- and microdiamonds and will be useful for their application in quantum computing, spintronics, nanophotonics, and biomedicine.
Ecofriendly Biopolymer-Based Nanocomposite Films with Improved Photo-Oxidative Resistance
Authors: Morici Elisabetta , Infurna Giulia , Dintcheva Nadka Tz.
Published: August 2022

The interest towards high performance biopolymer-based materials increases continuously and, to guarantee appropriately industrial applications, the photo-oxidative resistance and stability of these materials must be adequately addressed. In this study, innovative biopolymer-based nanocomposites, i.e., Polyamide 11 (PA11), containing ad-hoc modified Layered Double Hydroxides (LDH), were successfully formulated and characterized. Particularly, LDH were considered carriers for hindered amine light stabilizing molecules, so two different hindered amine moieties (HALS1 and HALS2) were anchored on LDH layered internal structures and/or outer surfaces. The presence of HALS1 and HALS2 in LDH were confirmed by X-ray diffraction, spectroscopy, and thermogravimetric analysis. Then, the novel LDH-HALS nanofillers (here named LDH-HALS1 and LDH-HALS2) were introduced into a PA11 matrix by melt mixing at 5 wt.%; the produced nanocomposites were characterized by differential scanning calorimetry, rheological, and morphological analysis. All obtained results suggest that the LDH-HALS1/HALS2 nanofillers were very well dispersed into the PA11 matrix. Additionally, the photo-oxidative resistance of the PA11-based nanocomposite films was evaluated by subjecting thin films to UVB exposure and the degradation process was monitored by spectroscopic analysis over time. The photo-oxidative resistance of the PA11/LDH-HALS1/HALS2 was compared to that of PA11-based nanocomposites containing unmodified LDH and the commercial hindered amine UV-stabilizer (Cyasorb® UV-3853). It was established that by anchoring the hindered amine moieties to the LDH, the PA11 nanocomposites were successfully protected against UVB exposure. This was because the hindered amine light stabilizing molecules were available to act at the critical zone where the degradation phenomena occur, which is at the interface between the matrix and the inorganic particles.
The Volumetric Wear Assessment of a Mining Conical Pick Using the Photogrammetric Approach
Authors: Pawlik Jan , Wróblewska-Pawlik Aleksandra , Bembenek Michał
Published: August 2022

The rapid wear of conical picks used in rock cutting heads in the mining industry has a significant economic impact in cost effectiveness for a given mineral extraction business. Any mining facility could benefit from decreasing the cost along with a substantial durability increase of a conical pick; thus, the hardfacing method of production and regeneration should be taken into account. In order to automatize the regeneration, the wear rate assessment is necessary. This paper presents a methodology used to create a 3D photogrammetric model of most of the commercially available tangential-rotary cutters in their before and after abrasive exploitation state. An experiment of three factors on two levels is carried out to indicate the proper setup of the scanning rig to obtain plausible results. Those factors are: light level, presence of polarizing filter and the distance from the scanned object. The 3D scan of the worn out specimen is compared to the master model via algorithm developed by the authors. This approach provides more detailed information about the wear mechanism and can help either in roadheader cutting head diagnostics or to develop a strategy and optimize the toolpath for the numerically controlled hardfacing machine.
Stewart Platform Motion Control Automation with Industrial Resources to Perform Cycloidal and Oceanic Wave Trajectories
Authors: Silva Diego , Garrido Julio , Riveiro Enrique
Published: August 2022

Research on motion control automation of Stewart Platforms with industrial configurations (motion and controllers) is less present in the literature than other types of automation with low-cost devices such as Arduino, or via simulations in MATLAB or Simulink. Moreover, direct kinematics is less widely applied because of heavy calculation in real-time device implementations. The paper first analyzes the design, kinematic modelling, and trajectory generation of a Stewart Platform robot and addresses direct kinematics and motion automation. Next, the automation architecture with industrial controllers is detailed. The paper presents the results of the inverse kinematic in two use scenarios: cycloidal trajectories that carry out point-to-point and oceanic wave movements. The efficient calculation of direct kinematics in real time was also studied. This opens the possibility of closing the positioning loop at the controller or implementing supervisors such as the “tracking error”. Further research might investigate the effects of the sequence planning to avoid collisions with objects inside the workspace while considering the feedback of the tracking error.
A Non-Invasive Method to Evaluate Fuzzy Process Capability Indices via Coupled Applications of Artificial Neural Networks and the Placket–Burman DOE
Authors: Villalón-Turrubiates Iván E. , López-Herrera Rogelio , García-Alcaraz Jorge L. , Díaz-Reza José R. , Soto-Cabral Arturo , González-Lazalde Iván , Grijalva-Avila Gerardo , Rodríguez-Álvarez José L.
Published: August 2022

The capability analysis of a process against requirements is often an instrument of change. The traditional and fuzzy process capability approaches are the most useful statistical techniques for determining the intrinsic spread of a controlled process for establishing realistic specifications and use for comparative processes. In the industry, the traditional approach is the most commonly used instrument to assess the impact of continuous improvement projects. However, these methods used to evaluate process capability indices could give misleading results because the dataset employed corresponds to the final product/service measures. This paper reviews an alternative procedure to assess the fuzzy process capability indices based on the statistical methodology involved in the modeling and design of experiments. Firstly, a model with reasonable accuracy is developed using a neural network approach. This model is embedded in a graphic user interface (GUI). Using the GUI, an experimental design is carried out, first to know the membership function of the process variability and then include this variability in the model. Again, an experimental design identifies the improved operating conditions for the significative independent variables. A new dataset is generated with these operating conditions, including the minimum error reached for each independent variable. Finally, the GUI is used to get a new prediction for the response variable. The fuzzy process capability indices are determined using the triangular membership function and the predicted response values. The feasibility of the proposed method was validated using a random data set corresponding to the basis weight of a papermaking process. The results indicate that the proposed method provides a better overview of the process performance, showing its true potential. The proposed method can be considered non-invasive.
Reliability Assessment of an Unscented Kalman Filter by Using Ellipsoidal Enclosure Techniques
Authors: Rauh Andreas , Wirtensohn Stefan , Hoher Patrick , Reuter Johannes , Jaulin Luc
Published: August 2022

The Unscented Kalman Filter (UKF) is widely used for the state, disturbance, and parameter estimation of nonlinear dynamic systems, for which both process and measurement uncertainties are represented in a probabilistic form. Although the UKF can often be shown to be more reliable for nonlinear processes than the linearization-based Extended Kalman Filter (EKF) due to the enhanced approximation capabilities of its underlying probability distribution, it is not a priori obvious whether its strategy for selecting sigma points is sufficiently accurate to handle nonlinearities in the system dynamics and output equations. Such inaccuracies may arise for sufficiently strong nonlinearities in combination with large state, disturbance, and parameter covariances. Then, computationally more demanding approaches such as particle filters or the representation of (multi-modal) probability densities with the help of (Gaussian) mixture representations are possible ways to resolve this issue. To detect cases in a systematic manner that are not reliably handled by a standard EKF or UKF, this paper proposes the computation of outer bounds for state domains that are compatible with a certain percentage of confidence under the assumption of normally distributed states with the help of a set-based ellipsoidal calculus. The practical applicability of this approach is demonstrated for the estimation of state variables and parameters for the nonlinear dynamics of an unmanned surface vessel (USV).
Using Matlab/Simulink Software Package to Investigate Fault Behaviors in HVDC System
Authors: Ikotun Olumoroti , Agyekum Ephraim Bonah , Ahmed Emad M. , Kamel Salah
Published: August 2022

Existing studies show that several performance issues will arise in the HVDC link during the three phase-to-ground fault at the side of the inverter and that the DC voltage will oscillate around zero and will not affect the rectifier of the AC system though the inverter of the AC system, and the AC voltages will become zero and the AC currents will show high amplitude as well as minor disturbances. It has also been argued that when the fault is applied on a single-phase to ground fault at the inverter side on the AC side, the voltage will decrease. In this paper, we focus on single line-to-ground fault, double line-to-ground fault, and three phase-to-ground fault at the inverter of the AC system and their behavior on the DC link as well as on the AC system of the rectifier with detailed simulations. A high voltage direct current (HVDC) Monopolar system is modeled using a Matlab/Simulink software package for the research. The results show that during the three phase-to-ground fault at the AC system of the inverter, the DC voltage will increase with a bogus waveform and the currents of the AC system at the rectifier will collapse to zero.At the double phase-to-ground fault level, the DC voltage will experience an increase in waveform while the currents of the AC system of the rectifier will experience different disturbances. At the single phase-to-ground fault level, the DC voltage will remain stable and the rectifier side of the AC system will also experience a stable state for both currents and voltages.
A New Robust and Secure 3-Level Digital Image Watermarking Method Based on G-BAT Hybrid Optimization
Authors: Devi Kilari Jyothsna , Singh Priyanka , Dash Jatindra Kumar , Thakkar Hiren Kumar , Santamaría José , Krishna Musalreddy Venkata Jayanth , Romero-Manchado Antonio
Published: August 2022

This contribution applies tools from the information theory and soft computing (SC) paradigms to the embedding and extraction of watermarks in aerial remote sensing (RS) images to protect copyright. By the time 5G came along, Internet usage had already grown exponentially. Regarding copyright protection, the most important responsibility of the digital image watermarking (DIW) approach is to provide authentication and security for digital content. In this paper, our main goal is to provide authentication and security to aerial RS images transmitted over the Internet by the proposal of a hybrid approach using both the redundant discrete wavelet transform (RDWT) and the singular value decomposition (SVD) schemes for DIW. Specifically, SC is adopted in this work for the numerical optimization of critical parameters. Moreover, 1-level RDWT and SVD are applied on digital cover image and singular matrices of LH and HL sub-bands are selected for watermark embedding. Further selected singular matrices SLH and SHL are split into 3×3 non-overlapping blocks, and diagonal positions are used for watermark embedding. Three-level symmetric encryption with low computational cost is used to ensure higher watermark security. A hybrid grasshopper–BAT (G-BAT) SC-based optimization algorithm is also proposed in order to achieve high quality DIW outcomes, and a broad comparison against other methods in the state-of-the-art is provided. The experimental results have demonstrated that our proposal provides high levels of imperceptibility, robustness, embedding capacity and security when dealing with DIW of aerial RS images, even higher than the state-of-the-art methods.
Conotoxin Patenting Trends in Academia and Industry
Authors: Sanchez-Campos Noemi , Bernaldez-Sarabia Johanna , Licea-Navarro Alexei F.
Published: August 2022

Sea snails of the genus Conus produce toxins that have been the subjects of numerous studies, projects, publications, and patents over the years. Since Conus toxins were discovered in the 1960s, their biological activity has been thought to have high pharmaceutical potential that could be explored beyond the limits of academic laboratories. We reviewed 224 patent documents related to conotoxins and conopeptides globally to determine the course that innovation and development has taken over the years, their primary applications, the technological trends over the last six years, and the leaders in the field, since the only previous patent review was performed in 2015 and focused in USA valid patents. In addition, we explored which countries/territories protect their inventions and patents and the most relevant collaborations among assignees. We also evaluated whether academia or pharmaceutical companies are the future of conotoxin research. We concluded that the 224 conotoxin patents reviewed in this study have more academic value than industrial value, which was noted by the number of active patents that have not yet been licensed and the contributions to medical research, especially as tools to study neuropathic pain, inflammation, immunology, drug design, receptor binding sites, cancer, neurotransmission, epilepsy, peptide biosynthesis, and depression. The aim of this review is to provide an overview of the current state of conotoxin patents, their main applications, and success based on the number of licensing and products in the market.
Structural and Biochemical Analysis Reveals Catalytic Mechanism of Fucoidan Lyase from Flavobacterium sp. SA-0082
Authors: Wang Juanjuan , Liu Zebin , Pan Xiaowei , Wang Ning , Li Legong , Du Yuguang , Li Jianjun , Li Mei
Published: August 2022

Fucoidans represent a type of polyanionic fucose-containing sulfated polysaccharides (FCSPs) that are cleaved by fucoidan-degrading enzymes, producing low-molecular-weight fucoidans with multiple biological activities suitable for pharmacological use. Most of the reported fucoidan-degrading enzymes are glycoside hydrolases, which have been well studied for their structures and catalytic mechanisms. Little is known, however, about the rarer fucoidan lyases, primarily due to the lack of structural information. FdlA from Flavobacterium sp. SA-0082 is an endo-type fucoidan-degrading enzyme that cleaves the sulfated fuco-glucuronomannan (SFGM) through a lytic mechanism. Here, we report nine crystal structures of the catalytic N-terminal domain of FdlA (FdlA-NTD), in both its wild type (WT) and mutant forms, at resolutions ranging from 1.30 to 2.25 Å. We show that the FdlA-NTD adopts a right-handed parallel β-helix fold, and possesses a substrate binding site composed of a long groove and a unique alkaline pocket. Our structural, biochemical, and enzymological analyses strongly suggest that FdlA-NTD utilizes catalytic residues different from other β-helix polysaccharide lyases, potentially representing a novel polysaccharide lyase family.
Carrageenophyte Kappaphycus malesianus Inhibits Microglia-Mediated Neuroinflammation via Suppression of AKT/NF-κB and ERK Signaling Pathways
Authors: Lai Nicole Jean-Yean , Ngu Ee-Ling , Pang Jun-Rui , Wong Kah-Hui , Ardianto Chrismawan , Ming Long Chiau , Lim Siew-Huah , Walvekar Shweta Gangasa , Anwar Ayaz , Yow Yoon-Yen
Published: August 2022

Neuroinflammation is an inflammatory response in any part of the central nervous system triggered by the activation of microglia and astrocytes to produce proinflammatory cytokines in the brain. However, overproduction of proinflammatory cytokines further contributes to the development of neurodegenerative disorders. Red seaweed, Kappaphycus malesianus, is a predominant carrageenophyte commercially cultivated in Semporna, Sabah, Malaysia. It is an important source of raw material for kappa-carrageenan productions in the food, pharmaceutical and cosmetics industries. However, no studies have been conducted focusing on the antineuroinflammatory effects of K. malesianus. The aim of the present study was to investigate the effect of the antineuroinflammatory activity of K. malesianus extracts (ethyl acetate, ethanol and methanol) on lipopolysaccharide-stimulated BV2 microglia and the underlying mechanisms involved in the regulation of neuroinflammatory pathways. Extract with the most promising antineuroinflammatory activity was analyzed using liquid chromatography-mass spectrometry (LC-MS). Our results show that methanol extract has a convincing antineuroinflammatory effect by suppressing both AKT/NF-κB and ERK signaling pathways to inhibit the expression of all proinflammatory cytokines without causing a cytotoxicity effect. LC-MS analysis of methanol extract revealed two compounds: prosopinine and eplerenone. Our findings indicated that metabolites of K. malesianus are potent antineuroinflammatory agents with respect to prevention of neurological disorders.
Progress in Research of Chitosan Chemical Modification Technologies and Their Applications
Authors: Chen Qizhou , Qi Yi , Jiang Yuwei , Quan Weiyan , Luo Hui , Wu Kefeng , Li Sidong , Ouyang Qianqian
Published: August 2022

Chitosan, which is derived from chitin, is the only known natural alkaline cationic polymer. Chitosan is a biological material that can significantly improve the living standard of the country. It has excellent properties such as good biodegradability, biocompatibility, and cell affinity, and has excellent biological activities such as antibacterial, antioxidant, and hemostasis. In recent years, the demand has increased significantly in many fields and has huge application potential. Due to the poor water solubility of chitosan, its wide application is limited. However, chemical modification of the chitosan matrix structure can improve its solubility and biological activity, thereby expanding its application range. The review covers the period from 1996 to 2022 and was elaborated by searching Google Scholar, PubMed, Elsevier, ACS publications, MDPI, Web of Science, Springer, and other databases. The various chemical modification methods of chitosan and its main activities and application research progress were reviewed. In general, the modification of chitosan and the application of its derivatives have had great progress, such as various reactions, optimization of conditions, new synthetic routes, and synthesis of various novel multifunctional chitosan derivatives. The chemical properties of modified chitosan are usually better than those of unmodified chitosan, so chitosan derivatives have been widely used and have more promising prospects. This paper aims to explore the latest progress in chitosan chemical modification technologies and analyze the application of chitosan and its derivatives in various fields, including pharmaceuticals and textiles, thus providing a basis for further development and utilization of chitosan.
The Mechanical Performance of Aluminum Foam Fabricated by Melt Processing with Different Foaming Agents: A Comparative Analysis
Authors: Byakova Alexandra , Gnyloskurenko Svyatoslav , Vlasov Andrey , Yevych Yan , Semenov Nikolay
Published: August 2022

The study presents the comparative analysis of the compressive response for the experimental aluminium foams of different parent alloys fabricated by melt processing with/without Ca additive and an expensive conventional TiH2 foaming agent or a cheap alternative CaCO3. It was recognized that the response of the foams is significantly dependent on the type of foaming agent and Ca additive due to the formation of low ductile and brittle products created in the foaming process. The presence of deformation bands and brittle eutectics in material, Al3Ti particles/layers, partially decomposed TiH2, Ca containing compounds, etc. cause a reduction of the foam’s compressive strength and deviation of its mechanical profile from the theoretical predictions. In addition, the usage of an inexpensive CaCO3 foaming agent offers numerous indisputable advantages compared to TiH2, resulting, particularly, in enhancing the energy absorption ability of foams.
Trans-Species Fecal Transplant Revealed the Role of the Gut Microbiome as a Contributor to Energy Metabolism and Development of Skeletal Muscle
Authors: Cai Liyuan , Li Min , Zhou Shuyi , Zhu Xiaoyan , Zhang Xianghua , Xu Qingbiao
Published: August 2022

The aim of this study was to investigate the influence of the exogenous gut microbiome at early life stages on the development of mice skeletal muscle in adulthood. First, the characteristics of skeletal muscle and the gut microbiota composition of the gut microbiota donors—Erhualian (EH) pigs (a native Chinese breed)—were studied. EH pigs had significantly higher fiber densities and thinner fiber diameters than Duroc × Landrace × Yorkshire crossed (DLY) pigs (p < 0.05). The expression levels of genes related to oxidized muscle fibers, mitochondrial function, and glucose metabolism in the skeletal muscle of EH pigs were significantly higher than those in DLY pigs (p < 0.05). Moreover, the abundances of 8 gut microbial phyla and 35 genera correlated with the skeletal muscle fiber diameters and densities exhibited significant differences (p < 0.05) between EH and DLY pigs. Subsequently, newborn mice were treated with saline (CG) and fecal microbiota suspensions collected from EH pigs (AG), respectively, for 15 days, starting from the day of birth. In adulthood (60 days), the relative abundances of Parabacteroides, Sutterella, and Dehalobacterium were significantly higher in the feces of the AG mice than those of the CG mice. The microbes contribute to improved functions related to lipid and carbohydrate metabolism. The weight, density, and gene expression related to the oxidized muscle fibers, mitochondrial function, and glucose metabolism of the AG group were significantly higher than those of the CG group (p < 0.05), whereas the fiber diameters in the skeletal muscle of the AG mice were significantly lower (p < 0.05) than those of the CG mice. These results suggested that intervention with exogenous microbiota at early stages of life can affect the fiber size and energy metabolism of their skeletal muscle.
The PROVIT Study—Effects of Multispecies Probiotic Add-on Treatment on Metabolomics in Major Depressive Disorder—A Randomized, Placebo-Controlled Trial
Authors: Kreuzer Kathrin , Reiter Alexandra , Birkl-Töglhofer Anna , Dalkner Nina , Mörkl Sabrina , Mairinger Marco , Fleischmann Eva , Fellendorf Frederike , Platzer Martina , Lenger Melanie , Färber Tanja , Seidl Matthias , Birner Armin , Queissner Robert , Mendel Lilli-Marie , Maget Alexander , Kohlhammer-Dohr Alexandra , Häussl Alfred , Wagner-Skacel Jolana , Schöggl Helmut , Amberger-Otti Daniela , Painold Annamaria , Lahousen-Luxenberger Theresa , Leitner-Afschar Brigitta , Haybaeck Johannes , Habisch Hansjörg , Madl Tobias , Reininghaus Eva , Bengesser Susanne
Published: August 2022

The gut–brain axis plays a role in major depressive disorder (MDD). Gut-bacterial metabolites are suspected to reduce low-grade inflammation and influence brain function. Nevertheless, randomized, placebo-controlled probiotic intervention studies investigating metabolomic changes in patients with MDD are scarce. The PROVIT study (registered at clinicaltrials.com NCT03300440) aims to close this scientific gap. PROVIT was conducted as a randomized, single-center, double-blind, placebo-controlled multispecies probiotic intervention study in individuals with MDD (n = 57). In addition to clinical assessments, metabolomics analyses (1H Nuclear Magnetic Resonance Spectroscopy) of stool and serum, and microbiome analyses (16S rRNA sequencing) were performed. After 4 weeks of probiotic add-on therapy, no significant changes in serum samples were observed, whereas the probiotic groups’ (n = 28) stool metabolome shifted towards significantly higher concentrations of butyrate, alanine, valine, isoleucine, sarcosine, methylamine, and lysine. Gallic acid was significantly decreased in the probiotic group. In contrast, and as expected, no significant changes resulted in the stool metabolome of the placebo group. Strong correlations between bacterial species and significantly altered stool metabolites were obtained. In summary, the treatment with multispecies probiotics affects the stool metabolomic profile in patients with MDD, which sets the foundation for further elucidation of the mechanistic impact of probiotics on depression.
Rapid and Sensitive Electrochemical Assay of Cefditoren with MWCNT/Chitosan NCs/Fe2O3 as a Nanosensor
Authors: Aydogdu Nida , Ozcelikay Goksu , Ozkan Sibel A.
Published: August 2022

In this research, a glassy carbon electrode (GCE) modified by MWCNT/chitosan NCs/Fe2O3 was prepared for the determination of the cephalosporin antibiotic cefditoren (CFT) using adsorptive stripping differential pulse and cyclic voltammetry techniques. The effects of pH, the scan rate, the deposition potential, the accumulation time, and modification agents on the determination of CFT were analyzed. The results showed that the modified electrode significantly increased the oxidation peak current of CFT. Under optimized conditions, the MWCNT/chitosan NCs/Fe2O3/GCE nanosensor exhibited a linear response between 0.2 µM and 10 µM toward CFT. The limit of detection and quantification were determined to be 1.65 nM and 5.50 nM, respectively. Model drugs (cefdinir, cefpodoxime, cephalexin, and ceftazidime compounds) were used to enlighten the CFT oxidation mechanism. Moreover, the nanosensor was used to analyze CFT in a pharmaceutical dosage form and commercial deproteinated human serum samples. The accuracy of these methods was proven in the recovery studies, with values of 96.98 and 98.62% for the pharmaceutical dosage form and commercial deproteinated human serum sample, respectively.
A Piezoelectric Heterostructure Scavenging Mechanical Energy from Human Foot Strikes
Authors: He Wei
Published: August 2022

This paper presents a piezoelectric heterostructure for extracting mechanical energy from human foot strikes based on the impact of a moving block on the tips of the piezoelectric unimorph cantilevers. The use of the magnetic springs allows low-frequency and high-amplitude movements of the device. The piezoelectric unimorph cantilevers deform under a human foot strike on the pedal, and the piezoelectric elements in d31-mode produce output voltages. An analysis was conducted, and the working principle was stated. A prototype was fabricated to validate the feasibility of the proposed design. The experimental results show that the generated RMS voltage increases with human walking (running) speed. At the walking speed of 6 km/h, an average power of 36.26 μW is produced across a matching resistive load of 4 MΩ with an initial separating distance of 9 mm. Improvements of the device are possible, allowing an increase in the average power by increasing the number of piezoelectric unimorph cantilevers and using the piezoelectric materials with higher piezoelectric constants.