bluuebunny/crossref_metadata_2025 huggingface dataset:
CVD Encapsulation of Laser-Graphitized Electrodes in Diamond Electro-Optical Devices
Authors: Komlenok Maxim S. , Kononenko Vitali V. , Bolshakov Andrey P. , Kurochitskiy Nikolay D. , Pasternak Dmitrii G. , Ushakov Alexander A. , Konov Vitaly I.
Published: December 2023

Conductive graphitized grooves on the dielectric surface of diamond have been created by KrF excimer laser radiation. The advantages of such a circuit board in high-field applications is rather limited because the crystal surface has a relatively low electrical breakdown threshold. To increase the electrical strength, a method of encapsulating surface conductive graphitized structures by chemical vapor deposition of an epitaxial diamond layer has been proposed and realized. The quality of the growth diamond is proved by Raman spectroscopy. A comparative study of the electrical resistivity of graphitized wires and the breakdown fields between them before and after diamond growth was carried out. The proposed technique is crucial for diamond-based high-field electro-optical devices, such as THz photoconductive emitters.
Stability Improvement of the TDLAS-Based CO Monitoring Module in a Coal Mine by Using a Spectral Denoising Algorithm Based on SVR
Authors: Wang Yin , Li Lianqing , Li Haoran , Hu Feng , Qian Pengbo
Published: December 2023

CO gas is not only lethal but also a significant forecasting indicator for the spontaneous combustion of coal mines. It is imperative that monitoring modules for CO gas that work well in the coal mine environment are available. A feasible solution is the detection of CO by using monitoring modules based on tunable diode laser absorption spectroscopy (TDLAS) over a mid-infrared waveband near 4.6 μm. However, in most cases, the mid-infrared TDLAS-based CO monitoring module tends to introduce severe interference fringe noise into the TDLAS spectral backgrounds which is difficult to filter out using traditional spectral filtering methods, reducing the detection performance of the module. In order to filter out the noise and improve the stability of the module in complex coal mine environments, this work proposed an algorithm based on support vector regression (SVR) to extract the TDLAS spectral backgrounds. Spectral analysis indicates that the TDLAS spectral background can be predicted over the entire scanning spectrum range by using this algorithm, and the noise in the spectral background can be effectively filtered out when calculating the absorbance spectrum based on the Lambert–Beer law. Compared to extracting spectral backgrounds using the traditional least square polynomial fit, the obtained correlation coefficients between regression models of spectral backgrounds and corresponding training point datasets were increased from below 0.998 to above 0.999. The peak-to-peak value of the obtained N2 absorbance spectrum was suppressed below 0.022 from nearly 0.045. The signal-to-noise ratio of the obtained 25 ppm CO absorbance spectrum was increased to 13.35 from 6.95. A CO monitoring module polluted by dust was used to conduct experiments to further test the SVR-based algorithm. The experiment results showed that after programming the SVR-based algorithm to the module, the estimated limit of detection of the module was reduced to 5.46 ppm from 29.08 ppm, and all the absolute measuring errors of the standard CO gases with different low concentrations were reduced to less than 4 ppm from a majority of the errors of more than 10 ppm, compared to least square polynomial fit. The CO monitoring module could still maintain the performance of high-precision quantitative detection when using the SVR-based algorithm even if it had been polluted severely. So, the CO monitoring module has good adaptability to harsh field environments, and its operation stability can be effectively improved by using the algorithm proposed in this work.
The Effect of a Parabolic Apodizer on Improving the Imaging of Optical Systems with Coma and Astigmatism Aberrations
Authors: Reddy Andra Naresh Kumar , Dev Vasu , Pal Vishwa , Ganeev Rashid A.
Published: December 2023

We present the results of improving resolution in the imaging of two closely spaced point sources with an optical system under the influence of apodization and different types of aberrations. In particular, we consider the effect of coma and astigmatism, which are well-known aberrations that can deteriorate the resolution of an optical imaging system. Furthermore, a parabolic apodizer was included in an optical system to improve its imaging capabilities. We found that the two-point imaging performance of an optical system with a parabolic apodizer strongly depends on the coherence conditions of incident light. Furthermore, to analyze the efficiency of the parabolic apodizer, we compared the results of two-point imaging obtained with apodized and unapodized optical systems for distances between the two-point sources, less than or equal to the diffraction limit of an optical system. Moreover, the results of imaging the USAF chart with a parabolic apodizer are presented to show the apodizer’s efficacy in single-object imaging. Our results can be applied to the imaging of closely moving structures in microscopy, resolving dense spectral lines in spectroscopy experiments, and developing systems useful for resolving the images of closely associated far-distance objects in astronomical observations.
Computational Study of the Coupling Performances for a Long-Distance Vertical Grating Coupler
Authors: Yang Zhonghua , Luo Wenbo , Sun Yu
Published: December 2023

We present a high-efficiency silicon grating coupler design based on a left–right mirror-symmetric grating and a metal mirror. The coupler achieves nearly perfect 90-degree vertical coupling. When two SOI chips are placed face to face with a vertical working distance of 50 μm, the chip-to-chip interlayer coupling efficiency reaches as high as 96%. When the vertical working distance ranges from 45 μm to 55 μm, the coupling loss remains below 1 dB. We also verified the effectiveness of our designed vertical coupler through 3D FDTD full-model simulation. The results demonstrate that our proposed vertical coupling structure represents a high-efficiency solution for 3D optical interconnects. The integration of multiple photonic chips in a 3D package with vertical optical and electrical interconnects is also feasible in the foreseeable future.
Green Materials for Gel Formulation: Recent Advances, Main Features and Applications
Authors: Souza Maria Eduarda B. C. , Pereira Camila G.
Published: December 2023

Biogels (hydrogels, oleogels, and bigels) are structured systems used as delivery vehicles for bioactive substances. The objective of this study was to provide an updated view of green materials used as biogels, discussing the different aspects related to their formulation. An overview of the application possibilities of these gels in different areas, such as food, cosmetics, pharmaceuticals, and medicine, is reported. Furthermore, an evaluation of the profile of studies using biogels was carried out in the last decades (1980–2023), showing the advances in knowledge about these materials in different application domains. Additionally, a consideration of future demands regarding studies involving biogels from a technological and process engineering point of view is highlighted.
Geomagnetic Anomaly in the Growth Response of Peat Moss Sphagnum riparium to Temperature
Authors: Mironov Victor L.
Published: December 2023

Temperature plays an essential role in a plant’s life. The current investigation reveals that photoreceptors, whose activity is affected by the geomagnetic field, are a critical element of its perception. This knowledge suggests that plants’ responses to temperature could shift in different geomagnetic conditions. To test this hypothesis, we studied the change in the growth response of the peat moss Sphagnum riparium to temperature with a gradual increase in the geomagnetic Kp index. Growth data for this species were collected from Karelian mires by detailed monitoring over eight full growing seasons. The growth of 209,490 shoots was measured and 1439 growth rates were obtained for this period. The analysis showed a strong positive dependence of sphagnum growth on temperature (r = 0.58; n = 1439; P = 1.7 × 10−119), which is strongest in the Kp range from 0.87 to 1.61 (r = 0.65; n = 464; P = 4.5 × 10−58). This Kp interval is clearer after removing the seasonal contributions from the growth rate and temperature and is preserved when diurnal temperature is used. Our results are consistent with the hypothesis and show the unknown contribution of the geomagnetic field to the temperature responses of plants.
Nomenclature and Typification of the Jasione L. (Campanulaceae) Groups from the Eastern Mediterranean Basin
Authors: Serrano Miguel , Dimitrova Lyuboslava , Ortiz Santiago
Published: December 2023

In this research, all the published names of Jasione (Campanulaceae) in the species, subspecies, and variety ranks for populations from the Balkan and Anatolian peninsulas are reviewed, including names of taxa allied to these groups in surrounding areas. These two areas are among the main centers of diversity of the genus, albeit no recent revisions to address the regional taxonomical complexity of the genus have been published for the Balkans and Anatolia. In this work, the taxonomic status and typification of twenty-six published names are discussed, including the plethora of names within the Jasione heldreichii, J. supina, and J. orbiculata taxonomic complexes. In total, eleven lectotypes and one neotype are designated for names from the aforementioned regions, plus one from southern Italy. This nomenclatural clarification establishes a reference for ongoing and future taxonomic and evolutionary studies of Jasione in the Mediterranean basin. In a genus prone to micro-endemism and cryptospeciation, a number of the historically described forms, despite being disregarded by current taxonomic treatments, may, therefore, deserve further attention.
A New Method for Discovering Plant Biostimulants
Authors: Gao Peiwen , Wang Kui , Qi Chang , Chen Keming , Xiang Wensheng , Zhang Yue , Zhang Jie , Shu Changlong
Published: December 2023

Structurally well-defined compounds have advantages for quality control in plant biostimulant production and application processes. Humic acid (HA) is a biostimulant that significantly affects plant growth, and soil-dwelling Protaetia brevitarsis larva (PBLs) can rapidly convert agricultural waste into HA. In this study, we use PBLs as a model to investigate HA formation and screen for structurally well-defined HA-related plant biostimulant compounds. Dephasing magic angle spinning nuclear magnetic resonance (13C DD–MAS NMR) analysis indicated HA structural changes during PBL digestion; metabolic profiling detected seven HA-related aromatic ring-containing compounds. A total of six compounds that significantly stimulate plant growth were identified through plant experiments, and all six compounds demonstrate the ability to enhance seed germination. It is noteworthy that piperic acid exhibits a remarkable promotion of root growth in plants, a finding reported for the first time in this study. Thus, this study not only provides insights into the insect-mediated transformation of HA but also illustrates a new method for discovering structurally well-defined plant biostimulant compounds.
Comparison of the Morpho-Physiological and Molecular Responses to Salinity and Alkalinity Stresses in Rice
Authors: Shaban Abdelghany S. , Safhi Fatmah Ahmed , Fakhr Marwa A. , Pruthi Rajat , Abozahra Mahmoud S. , El-Tahan Amira M. , Subudhi Prasanta K.
Published: December 2023

Rice is a major food crop that has a critical role in ensuring food security for the global population. However, major abiotic stresses such as salinity and alkalinity pose a major threat to rice farming worldwide. Compared with salinity stress, there is limited progress in elucidating the molecular mechanisms associated with alkalinity tolerance in rice. Since both stresses coexist in coastal and arid regions, unraveling of the underlying molecular mechanisms will help the breeding of high-yielding stress-tolerant rice varieties for these areas. This study examined the morpho-physiological and molecular response of four rice genotypes to both salinity and alkalinity stresses. Geumgangbyeo was highly tolerant and Mermentau was the least tolerant to both stresses, while Pokkali and Bengal were tolerant to only salinity and alkalinity stress, respectively. A set of salinity and alkalinity stress-responsive genes showed differential expression in the above rice genotypes under both stress conditions. The expression patterns were consistent with the observed morphological responses in these rice genotypes, suggesting the potential role of these genes in regulating tolerance to these abiotic stresses. Overall, this study suggested that divergence in response to alkalinity and salinity stresses among rice genotypes could be due to different molecular mechanisms conferring tolerance to each stress. In addition to providing a basis for further investigations into differentiating the molecular bases underlying tolerance, this study also emphasizes the possibilities of developing climate-resilient rice varieties using donors that are tolerant to both abiotic stresses.
Physiological Analysis of Source–Sink Relationship in Rice Genotypes with Contrasting Grain Yields
Authors: Vishwakarma Chandrapal , Krishna Gopinathan Kumar , Kapoor Riti Thapar , Mathur Komal , Dalal Monika , Singh Nagendra Kumar , Mohapatra Trilochan , Chinnusamy Viswanathan
Published: December 2023

Rice is a major staple food, and, hence, doubling its productivity is critical to sustain future food security. Improving photosynthesis, source–sink relationships and grain-filling mechanisms are promising traits for improvement in grain yield. To understand the source–sink relationship and grain yield, a set of contrasting rice genotypes differing in yield and biomass were studied for physiological, biochemical and gene-expression differences. The physiological and yield component traits of selected rice genotypes were analyzed in 2016 and 2017 under field conditions. This led to the categorization of genotypes as high yielding (HY) and high biomass, viz., Dular, Gontra Bidhan 3, Way Rarem, Patchai Perumal, Sahbhagi Dhan, Indira Barani Dhan-1, MTU1010, and Maudamani; while, low yielding (LY) and low biomass, viz. Anjali, Ghanteswari, Parijat, Khao Daw Tai, RKVY-104, Ghati Kamma Nangarhar, BAM4510 and BAM5850. The HY genotypes in general had relatively better values of yield component traits, higher photosynthetic rate (Pn) and chlorophyll (Chl) content. The study revealed that leaf area per plant and whole plant photosynthesis are the key traits contributing to high biomass production. We selected two good-performing (Sahbhagi Dhan and Maudamani) and two poor-performing (Ghanteswari and Parijat) rice genotypes for a detailed expression analysis of selected genes involved in photosynthesis, sucrose synthesis, transport, and starch synthesis in the leaf and starch metabolism in grain. Some of the HY genotypes had a relatively high level of expression of key photosynthesis genes, such as RbcS, RCA, FBPase, and ZEP over LY genotypes. This study suggests that traits, such as leaf area, photosynthesis and grain number, contribute to high grain yield in rice. These good-performing genotypes can be used as a donor in a breeding program aimed at high yields in rice.
Phenotypic Variations and Bioactive Constituents among Selected Ocimum Species
Authors: Mulugeta Sintayehu Musie , Pluhár Zsuzsanna , Radácsi Péter
Published: December 2023

Basil (Ocimum species) represents an extraordinary group of aromatic plants that have gained considerable economic importance, primarily due to their essential oils, which have applications in medicine, culinary, and perfumery. The Ocimum genus encompasses more than 60 species of herbs and shrubs originally native to tropical regions. This genus stands out for its remarkable diversity, displaying a wide spectrum of variations in phenotype, chemical composition, and genetic makeup. In addition to genetic factors, the growth, development, and essential oil production of basil are also influenced by environmental conditions, ontogeny, and various other factors. Consequently, the primary objective of this study was to explore the diversity in both the morphological characteristics and essential oil composition among basil genotypes preserved within the gene bank of the Hungarian University of Agriculture and Life Sciences’ Department of Medicinal and Aromatic Plants. The investigation involved the assessment of fifteen basil genotypes, representing four distinct species: Ocimum basilicum (including ‘Anise’, ‘Clove’, ‘Fino Verde’, ‘Licorice’, ‘Mammoth’, ‘Mrs. Burns’, ‘Thai tömzsi’, ‘Thai hosszú’, and ‘Vietnamese basil’), Ocimum sanctum (green holy basils), Ocimum citrodora (Lemon basil), and Ocimum gratissimum (African and Vana holy basil). The genotypes exhibited significant variations in their morphological growth, essential oil content (EOC), and composition. African basil produced more biomass (408.3 g/plant) and showed robust growth. The sweet basil cultivars clove, licorice, Thai tömzsi, and Thai hosszú also exhibited similar robust growth trends. Vietnamese basil, on the other hand, displayed the lowest fresh biomass of 82.0 g per plant. Both holy basils showed EOC levels below 0.5%, while Mrihani basil stood out with the highest EOC of 1.7%. The predominant constituents of the essential oil among these genotypes comprised estragole, thymol, methyl cinnamate, linalool, and eugenol. In conclusion, this study showed that the genotypes of basil stored in the department’s gene bank exhibit a wide range of variability, both within and between species.
Integrative Physiological, Transcriptome, and Proteome Analyses Provide Insights into the Photosynthetic Changes in Maize in a Maize–Peanut Intercropping System
Authors: Ma Chao , Feng Yalan , Wang Jiangtao , Zheng Bin , Wang Xiaoxiao , Jiao Nianyuan
Published: December 2023

Intercropping is a traditional and sustainable planting method that can make rational use of natural resources such as light, temperature, fertilizer, water, and CO2. Due to its efficient resource utilization, intercropping, in particular, maize and legume intercropping, is widespread around the world. However, the molecular details of these pathways remain largely unknown. In this study, physiological, transcriptome, and proteome analyses were compared between maize monocropping and maize–peanut intercropping. The results show that an intercropping system enhanced the ability of carbon fixation and carboxylation of maize leaves. Apparent quantum yield (AQY), the light-saturated net photosynthetic rate (LSPn), the light saturation point (LSP), and the light compensation point (LCP) were increased by 11.6%, 9.4%, 8.9%, and 32.1% in the intercropping system, respectively; carboxylation efficiency (CE), the CO2 saturation point (Cisat), the Rubisco maximum carboxylation rate (Vcmax), the maximum electron transfer rate (Jmax), and the triose phosphate utilization rate (TPU) were increased by 28.5%, 7.3%, 18.7%, 29.2%, and 17.0%, respectively; meanwhile, the CO2 compensation point (Γ) decreased by 22.6%. Moreover, the transcriptome analysis confirmed the presence of 588 differentially expressed genes (DEGs), and the numbers of up-regulated and down-regulated genes were 383 and 205, respectively. The DEGs were primarily concerned with ribosomes, plant hormone signal transduction, and photosynthesis. Furthermore, 549 differentially expressed proteins (DEPs) were identified in the maize leaves in both the maize monocropping and maize–peanut intercropping systems. Bioinformatics analysis revealed that 186 DEPs were related to 37 specific KEGG pathways in each of the two treatment groups. Based on the physiological, transcriptome, and proteome analyses, it was demonstrated that the photosynthetic characteristics in maize leaves can be improved by maize–peanut intercropping. This may be related to PS I, PS II, cytochrome b6f complex, ATP synthase, and photosynthetic CO2 fixation, which is caused by the improved CO2 carboxylation efficiency. Our results provide a more in-depth understanding of the high yield and high-efficiency mechanism in maize and peanut intercropping.
Phytochemical Investigation and Biofilm-Inhibitory Activity of Bachtiari Savory (Satureja bachtiarica Bunge) Aerial Parts
Authors: Rahmani Samani Marzieh , D’Urso Gilda , Nazzaro Filomena , Fratianni Florinda , Masullo Milena , Piacente Sonia
Published: December 2023

Satureja bachtiarica is an endemic plant from the Lamiaceae family, growing in the Zagros mountain range in Iran. Even if S. bachtiarica is reported to possess many biological activities, little is known about its chemical composition. For this reason, in the present research, a phytochemical investigation of this species was carried out. To have a preliminary metabolite profile of S. bachtiarica, the n-BuOH extract was analyzed using LC-ESI/LTQOrbitrap/MS/MS in negative ion mode, allowing the identification of specialized metabolites belonging to flavonoid, monoterpene, indol, phenylpropanoid, phenolic, lignan, coumarin, biphenyl, and triterpene classes. The LC-MS/MS analysis guided the isolation of compounds, and their structures were characterized using spectroscopic methods including 1D- and 2D-NMR experiments and HRMSn analysis. In this way, a compound never reported before belonging to the biphenyl class was identified. Total flavonoid content of the extract along with the antioxidant activity were assessed. Based on the traditional uses of S. bachtiarica suggesting potential antibacterial properties, an evaluation of the biofilm inhibitory activity of the extract and isolated compounds against mature biofilms of Acinetobacter baumannii, Escherichia coli, Listeria monocytogenes, Pseudomonas aeruginosa, and Staphylococcus aureus, as well as their influence on the metabolism of sessile bacterial cells, was conducted. The results evidenced that some compounds including parmentin B, biphenyls, and 1-(1H-indole-3-carboxylate)-β-D-glucopyranoside might inhibit some changes occurring in the bacterial cells, which increases their virulence. In particular, biphenyl derivatives at a concentration of 80 μg/mL were capable of limiting remarkably the mature biofilms of A. baumannii and L. monocytogenes remarkably at a percentage ranging between 52.76% and 75.02%, and they reached an inhibition percentage of 69.28 % against E. coli. Biphenyl derivatives were also effective in exerting an inhibitory action against the mature biofilm of P. aeruginosa (inhibition ranging from 59.38% to 81.08%) and Staphylococcus aureus (inhibition percentage reached 82.94%). Of note, the biphenyl derivatives resulted in being capable of acting on the metabolism of the cells within the biofilm of all five pathogens.
Long-Cycle Stability of In Situ Ultraviolet Curable Organic/Inorganic Composite Electrolyte for Solid-State Batteries
Authors: Liang Xinghua , Wang Yuying , Liang Zhida , Yan Ge , Lan Lingxiao , Wang Yujiang , Shi Xueli , Yun Shuhong , Huang Meihong
Published: December 2023

Lithium-ion solid-state batteries with spinel Li4Ti5O12 (LTO) electrodes have significant advantages, such as stability, long life, and good multiplication performance. In this work, the LTO electrode was obtained by the atmospheric plasma spraying method, and a composite solid electrolyte was prepared by in situ ultraviolet (UV) curing on the LTO electrode. The composite solid electrolyte was designed using a soft–hard combination strategy, and the electrolyte was prepared into a composite of a poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) flexible structure and high-conductivity Li1.3Al0.3Ti1.7(PO4)3 (LATP) hard particles. The composite electrolyte exhibited a good ionic conductivity up to 0.35 mS cm−1 at 30 °C and an electrochemical window above 4.0 V. In situ and ex situ electrolytes were assembled into LTO//electrolyte//Li solid-state batteries to investigate their impact on the electrochemical performance of the batteries. As a result, the assembled Li4Ti5O12//in situ electrolytes//Li batteries exhibited excellent rate of performance, and their capacity retention rate was 90% at 0.2 mA/cm2 after 300 cycles. This work provides a new method for the fabrication of novel advanced solid-state electrolytes and electrodes for applications in solid-state batteries.
Applicability of a Material Constitutive Model Based on a Transversely Isotropic Behaviour for the Prediction of the Mechanical Performance of Multi Jet Fusion Printed Polyamide 12 Parts
Authors: Perez-Barcenilla Sergio , Cearsolo Xabier , Aramburu Amaia , Castano-Alvarez Ruben , Castillo Juan R. , Gayoso Lopez Jorge
Published: December 2023

Multi Jet Fusion (MJF), an innovative additive manufacturing (AM) technique in the field of Powder Bed Fusion (PBF) developed by Hewlett-Packard (HP) Inc. (Palo Alto, CA, USA), has been designed to produce polymer parts using thermoplastic-based powders, primarily focusing on polyamide 12 (PA12). Employing a layer-by-layer approach, MJF enables the rapid production of intricate components, reportedly up to 10 times faster than other AM processes. While the mechanical properties of MJF-printed PA12 and the impact of build orientation on those properties have already been explored in various studies, less attention has been given to the mechanical performance of MJF-printed PA12 components under complex loads and accurate predictive models. This contribution aims to assess the applicability of a constitutive model based on a transversely isotropic behaviour under linear elastic deformation for predicting the mechanical response of MJF-printed PA12 parts through numerical simulations. Both uniaxial tensile and shear tests were carried out on printed samples to determine the elastic properties of MJF-printed PA12, with additional testing on printed complex handle-shaped parts. Finally, a numerical model was developed to simulate the mechanical tests of the handles. Results from tests on printed samples showed that MJF-printed PA12, to some extent, behaves as a transversely isotropic material. Furthermore, using a constitutive model that assumes a transversely isotropic behaviour under linear elastic deformation for predicting the mechanical response of MJF-printed PA12 parts in numerical simulations could be a reasonable approach, provided that the material stress levels remain within the linear range. However, the particularities of the stress-strain curve of MJF-printed PA12 complicate determining the elasticity-to-plasticity transition point.
Examining the Water–Polymer Interactions in Non-Isocyanate Polyurethane/Polyhedral Oligomeric Silsesquioxane Hybrid Hydrogels
Authors: Łukaszewska Izabela , Bukowczan Artur , Raftopoulos Konstantinos N. , Pielichowski Krzysztof
Published: December 2023

Non-isocyanate polyurethane (NIPU) networks physically modified with octa(3-hydroxy-3-methylbutyldimethylsiloxy)POSS (8OHPOSS, 0–10 wt%) were conditioned in environments of different relative humidities (up to 97%) to study water–polymer interactions. The equilibrium sorption isotherms are of Brunauer type III in a water activity range of 0–0.97 and are discussed in terms of the Guggenheim (GAB) sorption model. The study shows that the introduction of 8OHPOSS, even in a large amount (10 wt%), does not hinder the water affinity of the NIPU network despite the hydrophobic nature of POSS; this is attributable to the homogenous dispersion of POSS in the polymer matrix. The shift in the urethane-derived carbonyl bands toward lower wavenumbers with a simultaneous shift in the urethane N-H bending bands toward higher wavenumbers exposes the breakage of polymer–polymer hydrogen bonds upon water uptake due to the formation of stronger water–polymer hydrogen bonds. Upon water absorption, a notable decrease in the glass transition temperature (Tg) is observed for all studied materials. The progressive reduction in Tg with water uptake is driven by plasticization and slaving mechanisms. POSS moieties are thought to impact slaving indirectly by slightly affecting water uptake at very high hydration levels.
Direct Observations of Ordered Nanoporosity in Deprotonated 2-(Acetoacetoxy)ethyl Methacrylate (AAEMA–) Polymer: Preliminary Results
Authors: Fiore Ambra M. , Fiore Saverio , Huertas F. Javier , Mastrorilli Piero
Published: December 2023

Polymers based on 2-(acetoacetoxy)ethyl methacrylate, charged with iron or sodium, were thermally heated at 150 °C. Both polymers were studied and characterized by SEM, TEM, STEM microscopy and SAEDF techniques. The morphological investigation revealed that, upon heating, both polymers were endowed with microholes, sometimes perfectly ordered, whose dimensions varied from 4–5 nm to approximately 500 nm. In the case of an Fe-containing copolymer, unexpectedly, iron did not fill in the cavities, thus implying that it was “dispersed” in the polymeric matrix. Electronic microdiffraction documented that both polymers exhibited a proto-crystallinity, likely induced by thermal heating.
Sustainable Particleboards Based on Brewer’s Spent Grains
Authors: Rossi Lucia , Wechsler Lucia , Peltzer Mercedes A. , Ciannamea Emiliano M. , Ruseckaite Roxana A. , Stefani Pablo M.
Published: December 2023

Brewer’s spent grain (BSG) is the main solid waste generated in beer production and primarily consists of barley malt husks. Based on the active promotion of circular economy practices aimed at recycling food industry by-products, this study assessed for the first time the production of particleboards based on BSG as the sole source of lignocellulosic material and natural adhesive without the use of additives or other substrates. In order to achieve particleboards from entirely sustainable sources, BSG particles have to self-bind by thermo-compression with water. In this context, the aim of this study is to assess the effects of pressing temperatures and particle size on properties such as modulus of elasticity, modulus of rupture, internal bond, thickness swelling, and water absorption. The performance of binderless boards was compared with that of a control panel (control) using BSG combined with phenolic resin. Processing conditions were selected to produce boards with a target density of 1000 kg/m³ and a thickness of 5 mm. To confirm the efficiency of the self-adhesion process, scanning electron microscopy was used to examine the boards. The processes of self-adhesion and particle-to-particle contact were facilitated at a pressing temperature of 170 °C and a particle size range of 200–2380 µm (ground BSG), resulting in improved flexural properties and enhanced water resistance. The properties of BSG-based binderless boards were comparable to those reported for other biomass residues, suggesting that they might be used in non-structural applications, such as interior decoration.
Influence of the Carbon Fiber Length Distribution in Polymer Matrix Composites for Large Format Additive Manufacturing via Fused Granular Fabrication
Authors: Burgos Pintos Pedro , Moreno Sánchez Daniel , Delgado Francisco J. , Sanz de León Alberto , Molina Sergio I.
Published: December 2023

Many studies assess the suitability of fiber-reinforced polymer composites in additive manufacturing. However, the influence of the fiber length distribution on the mechanical and functional properties of printed parts using these technologies has not been addressed so far. Hence, in this work we compare different composites based on Acrylonitrile Styrene Acrylate (ASA) and carbon fiber (CF) suitable for large format additive manufacturing (LFAM) technologies based on fused granular fabrication (FGF). We study in detail the influence of the CF size on the processing and final properties of these materials. Better reinforcements were achieved with longer CF, reaching Young’s modulus and tensile strength values of 7500 MPa and 75 MPa, respectively, for printed specimens. However, the longer CF also worsened the interlayer adhesion of ASA to a greater extent. The composites also exhibited electrical properties characteristic of electrostatic dissipative (ESD) materials (105–1010 Ω/sq) and low coefficients of thermal expansion below 15 µm/m·°C. These properties are governed by the CF length distribution, so this variable may be used to tune these values. These composites are promising candidates for the design of elements with enhanced mechanical and functional properties for ESD protection elements or molds, so the products can be manufactured on demand.
Tribological Investigation of Glass Fiber Reinforced Polymer Composites against 52100 Chrome Alloy Steel Based on ELECTRE Decision-Making Method
Authors: Birleanu Corina , Cioaza Mircea , Serdean Florina , Pustan Marius , Bere Paul , Contiu Glad
Published: December 2023

Fibers play an important role when studying the tribological behavior of reinforced friction composites. The purpose of the current research is to develop a glass fiber reinforced polymer (GFRP) recipe with improved tribological properties as well as to find the composites with the optimal tribological behavior. A ball-on-disc tribometer was used to perform dry sliding friction testing, the obtained results were then analyzed with the ELECTRE (ELimination Et Choix Traduisant la REalite-elimination and choice translating the reality) method based on a utility matrix having process parameters the applied load, sliding velocity, and weight percentage of the fiber content. The ELECTRE method was chosen to find the optimal tribological parameters, with respect to more performance criteria, because it is one of the best multiple criteria decision-making methods. The optimal combination of parameters for the multi-response characteristics of the investigated friction composite was at an applied load of 10 N, a sliding velocity of 0.1 ms−1 and a 54% weight fiber content. The results showed that the addition of glass fiber (GF) content did not considerably improve the tribological behavior of the friction composites. In addition, from the nano focus–optical 3D scanning electron microscopy, images of the friction, tested friction and wear composites, plate formation, fiber-matrix delamination, fiber pull-out, and matrix cracking and damage, various wear mechanisms were identified.
Fabrication and Performance of Continuous 316 Stainless Steel Fibre-Reinforced 3D-Printed PLA Composites
Authors: Clarke Alison J. , Dickson Andrew , Dowling Denis P.
Published: December 2023

This study investigates the feasibility of 3D printing continuous stainless steel fibre-reinforced polymer composites. The printing study was carried out using 316L stainless steel fibre (SSF) bundles with an approximate diameter of 0.15 mm. This bundle was composed of 90 fibres with a 14 μm diameter. This fibre bundle was first coated with polylactic acid (PLA) in order to produce a polymer-coated continuous stainless steel filament, with diameters tailored in the range from 0.5 to 0.9 mm. These filaments were then used to print composite parts using the material extrusion (MEX) technique. The SSF’s volume fraction (Vf) was controlled in the printed composite structures in the range from 4 to 30 Vf%. This was facilitated by incorporating a novel polymer pressure vent into the printer nozzle, which allowed the removal of excess polymer. This thus enabled the control of the metal fibre content within the printed composites as the print layer height was varied in the range from 0.22 to 0.48 mm. It was demonstrated that a lower layer height yielded a more homogeneous distribution of steel fibres within the PLA polymer matrix. The PLA-SSF composites were assessed to evaluate their mechanical performance, volume fraction, morphology and porosity. Composite porosities in the range of 2–21% were obtained. Mechanical testing demonstrated that the stainless steel composites exhibited a twofold increase in interlaminar shear strength (ILSS) and a fourfold increase in its tensile strength compared with the PLA-only polymer prints. When comparing the 4 and 30 Vf% composites, the latter exhibited a significant increase in both the tensile strength and modulus. The ILSS values obtained for the steel composites were up to 28.5 MPa, which is significantly higher than the approximately 13.8 MPa reported for glass fibre-reinforced PLA composites.
Influence of Epilobium parviflorum Herbal Extract on Physicochemical Properties of Thermoplastic Starch Films
Authors: Zdanowicz Magdalena
Published: December 2023

In this study, for the first time, Epilobium parviflorum Schreb. (E, hoary willowherb) aqueous extract was introduced into edible biopolymer films and its influence on physicochemical properties of the final products were investigated. Potato starch was gelatinized in the herbal tea to obtain thermoplastic starch (TPS) films via the casting method. The characterization of the films included mechanical, antioxidative, water (WVTR, contact angle, swelling degree) and UV radiation barrier properties as well as microstructure analysis (SEM). Obtained results indicated that the presence of the extract (rich in phenolic compounds) in the films acted as a co-plasticizer for starch and led to a higher elongation at break, up to 70%, with a parallel increase in tensile strength up to ca. 9 MPa. Moreover, TPS films with E exhibited lower WVTR values and absorption of UV light in comparison with the control TPS film. DPPH scavenging activity of TPS E films immersed in methanol was ca. 92%, and it was related to the release of the extract into liquid media. Novel TPS E films are characterized by multifunctional properties that can be used, e.g., in the active packaging sector.
Poly-ε-Caprolactone 3D-Printed Porous Scaffold in a Femoral Condyle Defect Model Induces Early Osteo-Regeneration
Authors: De Mori Arianna , Karali Aikaterina , Daskalakis Evangelos , Hing Richard , Da Silva Bartolo Paulo Jorge , Cooper Glen , Blunn Gordon
Published: December 2023

Large bone reconstruction following trauma poses significant challenges for reconstructive surgeons, leading to a healthcare burden for health systems, long-term pain for patients, and complex disorders such as infections that are difficult to resolve. The use of bone substitutes is suboptimal for substantial bone loss, as they induce localized atrophy and are generally weak, and unable to support load. A combination of strong polycaprolactone (PCL)-based scaffolds, with an average channel size of 330 µm, enriched with 20% w/w of hydroxyapatite (HA), β-tricalcium phosphate (TCP), or Bioglass 45S5 (Bioglass), has been developed and tested for bone regeneration in a critical-size ovine femoral condyle defect model. After 6 weeks, tissue ingrowth was analyzed using X-ray computed tomography (XCT), Backscattered Electron Microscopy (BSE), and histomorphometry. At this point, all materials promoted new bone formation. Histological analysis showed no statistical difference among the different biomaterials (p > 0.05), but PCL-Bioglass scaffolds enhanced bone formation in the center of the scaffold more than the other types of materials. These materials show potential to promote bone regeneration in critical-sized defects on load-bearing sites.
Intensification of Hydrogen Production: Pd–Ag Membrane on Tailored Hastelloy-X Filter for Membrane-Assisted Steam Methane Reforming
Authors: Agnolin Serena , Di Felice Luca , Tanaka Alfredo Pacheco , Tanco Margot Llosa , Ververs Wout J. R. , Gallucci Fausto
Published: December 2023

H2 production via membrane-assisted steam methane reforming (MA-SMR) can ensure higher energy efficiency and lower emissions compared to conventional reforming processes (SMR). Ceramic-supported Pd–Ag membranes have been extensively investigated for membrane-assisted steam methane reforming applications, with outstanding performance. However, costs, sealings for integration in the reactor structure, and resistance to solicitations remain challenging issues. In this work, the surface quality of a low-cost, porous Hastelloy-X filter is improved by asymmetric filling with α-Al2O3 of decreasing size and deposition of γ-Al2O3 as an interdiffusion barrier. On the modified support, a thin Pd–Ag layer was deposited via electroless plating (ELP), resulting in a membrane with H2/N2 selectivity >10,000. The permeation characteristics of the membrane were studied, followed by testing for membrane-assisted methane steam reforming. The results showed the ability of the membrane reactor to overcome thermodynamic conversion of the conventional process for all explored operating conditions, as well as ensuring 99.3% H2 purity in the permeate stream at 500 °C and 4 bar.
Study on the Unsteady Flow Characteristics of a Pump Turbine in Pump Mode
Authors: Zhang Fei , Chen Zhenmu , Han Shuangqian , Zhu Baoshan
Published: December 2023

Extensive research has been conducted on the performance of pump turbines, particularly focused on understanding the generation mechanism of S-shaped characteristics. However, there has been a lack of research on unsteady flow characteristics in hump characteristics with small guide vane openings. This study focuses on the hump characteristics of a pump turbine in pump mode. The unsteady numerical simulation method is used along with experimental testing to examine the internal flow characteristics and induced pressure fluctuations under pump operating conditions. The results indicate that flow separation occurs in the impeller when the flow rate decreases to the valley operating condition, and recirculation flow occurs near the impeller inlet at the partial flow rate. Moreover, the unstable flow on the positive slope exhibits a low-frequency characteristic of 0.15fn. The pressure fluctuation from the hub to shroud areas of the guide vane region diminishes sequentially. Notably, distinct vortex structures emerge at the draft tube cone section under the valley operating condition. These structures extend toward the elbow section of the draft tube as the flow rate decreases. This phenomenon generates low-frequency pressure fluctuation originating from the primary frequency of the vortex and dean vortex on the surface, located at 0.4 D of the draft tube under conditions of low flow rate.
A Human-Centric Design Method for Industrial Centrifugal Pump Based on Digital Twin
Authors: Shi Yue , Sheng Buyun , Zhu Jiaxing , Chen Geng , Zhang Tianao , Luo Ruiping
Published: December 2023

The worldwide demand for customized centrifugal pumps in numerous industries is intensifying steadily, posing significant challenges to the traditional design model characterized by extended design cycles, numerous errors, and elevated development costs. To address these issues, this paper introduces an intelligent collaborative design methodology for industrial centrifugal pumps grounded in digital twin (DT) technology. The methodology aims to handle the diversified types and intricate design requirements of industrial pumps and is specifically tailored to predict pump performance through a detailed multi-physics model. This model encapsulates various physical processes, including fluid dynamics, thermodynamics, and structural mechanics, and incorporates the designer’s professional knowledge and experience to support enhanced decision-making. Furthermore, the application of intelligent parametric models has facilitated the interconnected design of pump components. This advancement has led to significant improvements such as shortening production cycles, reducing errors and costs, and enhancing design efficiency and quality. Consequently, the paper demonstrates that adopting this intelligent collaborative design approach can greatly benefit the industrial centrifugal pump sector by meeting the growing customization demands with increased efficiency and precision. These findings underscore the potential of DT technology in revolutionizing traditional pump design methodologies, advancing the intelligent progression of industrial centrifugal pump design and manufacturing, and satisfying the expanding demands of the global manufacturing industry.
Optimizing Mass Transfer in Multiphase Fermentation: The Role of Drag Models and Physical Conditions
Authors: Mast Yannic , Wild Moritz , Takors Ralf
Published: December 2023

Detailed knowledge of the flow characteristics, bubble movement, and mass transfer is a prerequisite for the proper design of multiphase bioreactors. Often, mechanistic spatiotemporal models and computational fluid dynamics, which intrinsically require computationally demanding analysis of local interfacial forces, are applied. Typically, such approaches use volumetric mass-transfer coefficient (kLa) models, which have demonstrated their predictive power in water systems. However, are the related results transferrable to multiphase fermentations with different physicochemical properties? This is crucial for the proper design of biotechnological processes. Accordingly, this study investigated a given set of mass transfer data to characterize the fermentation conditions. To prevent time-consuming simulations, computational efforts were reduced using a force balance stationary 0-dimension model. Therefore, a competing set of drag models covering different mechanistic assumptions could be evaluated. The simplified approach of disregarding fluid movement provided reliable results and outlined the need to identify the liquid diffusion coefficients in fermentation media. To predict the rising bubble velocities uB, the models considering the Morton number (Mo) showed superiority. The mass transfer coefficient kL was best described using the well-known Higbie approach. Taken together, the gas hold-up, specific surface area, and integral mass transfer could be accurately predicted.
Study on Through-Flow Characteristics of a Diesel Two-Stage Supercharged Centrifugal Compressor under Variable-Altitude and Multiple Operating Conditions
Authors: Peng Qikai , Liu Ruilin , Zhou Guangmeng , Zhao Xumin , Dong Surong , Zhang Zhongjie
Published: December 2023

Understanding the influence of environmental boundary parameters on the through-flow characteristics of two-stage supercharged centrifugal compressors is the key to maximizing the power recovery potential of diesel engines at high altitudes. In this paper, the influence of the compressor through-flow characteristics on the full-load thermal cycle performance of a diesel engine under variable altitude is studied by means of tests and simulation. The results show that with the increase in altitude, the range of stable work flow decreases, and the pressure ratio of the plugging point changes greatly with altitude. The efficiency of the compressor with the same mass flow point decreases, and the highest efficiency point moves in the direction of the small flow range. With the goal of maximizing the torque of the diesel engine under full load and low speed, the key geometric parameters of the variable-altitude through-flow characteristics of the two-stage supercharged compressor were optimized as follows: at the altitudes of 0 m, 2500 m, and 5500 m, the diesel engine torque increased by 5.89%, 3.78%, and 2.18%, respectively. Based on the optimization method of the compressor through-flow design, a new direction is provided to break through the research on the independent limitation of the diesel engine thermal cycle performance optimization and compressor flow control.