bluuebunny/crossref_metadata_2025 huggingface dataset:
Dos dados à matéria: experiências em esculturas de dados
Authors: Kosminsky Doris , De Oliveira Douglas Thomaz , Da Silva Luana Carolina , Isiris Eduarda Alves
Published: February 2020

A visualização de informações trata da representação visual e interativa de dados com o objetivo de ampliar a cognição. Apesar desta produção ter um maior foco na criação de visualizações funcionalistas e pragmáticas, tem se presenciado um avanço no campo das visualizações artísticas e também das visualizações físicas. Este artigo relata os desdobramentos de uma disciplina experimental de visualização física, ministrada no curso de Comunicação Visual Design da Escola de Belas Artes da Universidade Federal do Rio de Janeiro. Os três melhores projetos realizados na disciplina são descritos, seguidos por uma análise que aponta a necessidade de ações específicas relacionadas à coleta e entendimento dos dados; elaboração descritiva do projeto; escolha e emprego de materiais; testes e avaliações quanto à transmissão de conhecimento e sentimentos despertados. Conclui-se que elaborar estes problemas será útil ao design de esculturas de dados.
n-короны в разбиениях тора на множества ограниченного остатка
Authors: Жукова Алла Адольфовна , Шутов Антон Владимирович
Published: February 2020

Теория геометрических подстановок Арно-Ито позволяет строить последовательности обобщенных перекладывающихся разбиений d-мерного тора. Эти разбиения состоят из параллелепипедов d + 1 типа, а действие некоторого сдвига тора на разбиении сводится к перекладыванию d+1 центрального параллелепипеда. Более того, множество вершин всех параллелепипедов разбиения представляет собой фрагмент орбиты нуля относительно этого сдвига тора. Рассматриваемые разбиения активно используются в различных задачах теории чисел, комбинаторики и теории динамических систем. В настоящей работе изучается локальная структура разбиений тора, получаемых на основе геометрических подстановок. n-короной параллелепипеда называется множество всех параллелепипедов, отстоящих от данного на расстояние не более n в естественной метрике разбиения. Задача состоит в описании всех возможных типов n-корон. Каждому параллелепипеду разбиения естественным образом присваивается номер – его номер в орбите соответствующего центрального параллелепипеда относительно сдвига тора. Доказано, что множество всех номеров распадается на конечное число полуинтервалов, определяющих возможные типы n-корон. Более того, доказано, что границы соответствующих полуинтервалов определяются номерами параллелепипедов, входящих в n-корону набора из d + 1 центрального параллелепипеда. Показано, что этот результат можно рассматривать как некоторое многомерное обобщение знаменитой теоремы о трех длинах. Ранее аналогичное описание было получено для 1-корон разбиений тора получаемых при помощи одной конкретной геометрической подстановки: подстановки Рози. Кроме того, аналогичные результаты ранее были получены для ряда квазипериодических разбиений плоскости. В заключении сформулирован ряд направлений для дальнейшего исследования.
Assessing the performance of regional soybean prices in Ghana
Authors: Martey Edward , Gatti Nicolas , Goldsmith Peter
Published: February 2020

Soybean production has been widely promoted in sub-Saharan Africa as a means of improving rural household income. Numerous studies point to poor adoption levels, low yield levels, and limited profitability among smallholder farmers. Poor performance of soybean among smallholders generates numerous hypotheses as to the root causes. One logical cause is low prices, which result from anecdotes from the field, especially among producers and policymakers. In this study, the first of its kind that we are aware of, analyzes regional soybean prices over time across six key growing and commercial regions of Ghana. We employ cointegration and multivariate vector error correction model to measure the level of international and inter-market integration and performance. The results show regional and international integration as well as Granger Causality results consistent with the local supply-demand context. Specifically, the international market Granger causes Kumasi, Bolgatanga, and Wa markets, while the Tamale and Kumasi, serve as the leading production and demand markets, respectively. The results of the study provide evidence that prices do perform well in Ghana and are not a major source of weak adoption and low levels of profitability among smallholder soybean farmers.
OTOMATISASI ALAT PENGECEK PWB DI PT. LG ELECTRONICS INDONESIA
Authors: Adriansyah Andi
Published: February 2020

PT. LG Electronics Indonesia Tangerang yang merupakan perusahaan elektronik yang memproduksi refrigerator atau kulkas. Masalah yang terjadi adalah banyaknya temuan defect PWB (Pcb assembly,main) yang terjadi di line proses ataupun di customer . Pengecekan PWB yang sekarang ini dilakukan dengan menggunakan alat yang masih manual dan tidak bisa mendeteksi error yang terjadi sehingga memungkinkan terjadinya human error pada proses pengecekan. Pada alat manual saat ini hanya terdapat led indicator sehingga untuk memutuskan bagus tidaknya PWB yang di cek mengandalkan pengamatan dari operator.Dalam penelitian ini akan dibuat suatu alat pengecek PWB yang mana alat ini akan bekerja secara otomatis dan bisa mendeteksi error yang terjadi selama proses pengecekan berlangsung. Di harapkan dengan adanya alat ini akan bisa menghilangkan terjadinya human error dalam pengecekan PWB dan meningkatkan efisiensi kerja bagi operator. Dalam pembuatan alat ini terdiri dari beberapa tahap diantaranya pembuatan hardware dan sofware. Pada alat ini akan dilengkapi LCD display sebagai penampil informasi dan mikrokontroler sebagai otak dari alat ini.Mikrokontroler yang di gunakan yaitu AT89S51 sebanyak dua buah karena banyaknya port yang digunakan. Dan alat ini juga dilengkapi dengan adanya led indicator untuk mengetahui proses pengecekan yang terjadi. Dalam alat ini dapat langsung melakukan pengecekan PWB sebanyak 4 buah PWB. Sehingga mempercepat pengecekan. PWB ini mempunyai fungsi diantaranya untuk menghidupkan dan mematikan kompressor, defrost dan mengatur temperatur suhu kulkas. Pada proses pengaturan suhu terdapat tiga buah led yang mana akan berubah posisinya apabila tombol setting suhu di tekan. Pada alat ini akan mendeteksi berfungsi tidaknya fungsi dari PWB tersebut. Adapun fungsi yang akan dicek yaitu compressor, defrost dan LED control box. Dalam percobaan yang telah dilakukan alat ini mampu melakukan proses pengecekan PWB sekaligus bisa mendeteksi error yang terjadi dan menampilkannya ke LCD Display. Dan apabila terjadi error pada PWB alat ini juga akan membunyikan buzzer Kata Kunci : refrigerator, defect PWB, kompressor, defrost, buzzer
STUDI ANALISA PERFORMANSI TROUBLESHOOTING NATIVE IP TRANSMISI MINILINK TN PADA LINK SINDANGRASA – RANCAMAYA
Authors: Attamimi Said , Fadillah Dadang
Published: February 2020

Untuk menyelesaikan masalah transmisi data besar salah satu solusinya adalah penggunaan peralatan transmisi berbasis IP (Native IP). Penelitian ini dilakukan analisa hasil penerapan peralatan transmisi berbasis IP pada jalur transmisi Rancamaya – Sindangrasa. Analisa ini melihat adanya bottleneck pada sisi peralatan transmisi dengan melihat bandwidth uility yang mencapai 100%. Akibat dari terjadinya bottlenect tersebut adalah munculnya alarm NTP Server pada Node-B (BTS 3G) ericsson, dan congestion disertai dropcall pada sisi BTS 2G ericsson. Dengan melakukan aktifitas upgrade peralatan transmisi berbasis IP dari 18 Mbps menjadi 51 Mbps diharapkan dapat menyelesaikan masalah bottleneck akibat transmisi data yang besar tersebut.Hasil dari aktifitas upgrade kapasitas transmisi berbasis IP tersebut ternyata dapat menghilangkan adanya bottleneck tersebut, dengan melihat bandwidth utility yang turun sampai 50% serta hilangnya alarm NTP Server pada sisi Node-B (BTS 3G) ericsson, congestion dan dropcall pada sisi BTS 2G ericsson membuktikan hal tersebut. Sehingga dapat ditarik kesimpulan bahwa peralatan transmisi berbasis IP adalah mutlak untuk diterapkan pada masa sekarang ini.Kata kunci : E1toIP, Transmission Link, HSDPA, HSUPA, Native IP, Ericsson Minilink TN
RANCANG BANGUN SISTEM EMERGENCY BLUECODE RUMAH SAKIT MENGGUNAKAN MIKROKONTROLLER ARDUINO UNO
Authors: Supegina Fina , Septiadi Indra
Published: February 2020

Pada penelitian ini dirancang peralatan dalam rangka peningkatan mutu pelayanan dari perawat yaitu Bluecode. Alat ini dilengkapi dengan RFID yang berfungsi untuk membuka kuncian Keypad dan dilengkapi dengan 2 LCD, LCD yang pertama berfungsi sebagai pemberitahu kepada perawat bahwa keypad yang mereka tekan sesuai dengan ruangan yang membutuhkan tindakan medis sedangkan LCD yang kedua berfungsi untuk meberitahukan ruangan yang mebutuhkan tindakan medis, dokter dan perawat yang berada diruangan IGD, ICU dan Treadmill serta peneliti menggunakan GPRS Shield yang berfungsi sebagai pengganti instalasi kabel yang berserakan. Bluecode ini dirancang dengan teknologi terbaru sehingga dengan hasil yang dirancang dapat membantu perawat dalam menjalankan tugasnya dengan baik dengan cara yang cukupmenempalkan RFID dan menekan nomor ruangan maka akan secara otomatis terkoneksi secara ke bagian IGD, ICU dan treadmill. Hasil yang didapatkan adalah adanya bunyi bazzer yang bertanda adanya panggilan darurat dari kamar perawatan, adanya lampu indikator hijau untuk standby, lampu indikator merah berarti adanya panggilan emergency dan lampu indikator biru menandakan panggilan emergency berakhir serta tampilan pada LCD yang memberitahukan ruangan yang membutuhkan tenaga medis. Apabila disaat RFID error kita bisa mengunakan handphone sebagai pengganti keypad. Kata kunci: RFID, ID, keypad, Bluecode
APLIKASI LED RGB PADA POLA DAN WARNA TAS MENGGUNAKAN STRIP LED DENGAN SENSOR WARNA DAN CONTROL ARDUINO ANDROID
Authors: Supegina Fina
Published: February 2020

Inovasi baru dibidang fashion khususnya dalam hal pembuatan pola dan warna pada tas. Sebagai seorang fashionista pasti ingin up to date dalam perkembangan fashion dan  selalu  ingin  tampil  fashionable.  Untuk  itu  mereka  harus  pandai  dalam  memadu padankan  warna  antara  baju  dan  aksesoris  yang  digunakan.  Sangat  boros  jika  harus membeli tas dengan model yang sama tapi berbeda warna. Dalam penelitian ini, penulis mencoba memberikan solusi bagi para fashionista yang selalu ingin tampil up to date dan fashionable. Penulis  membuat  inovasi  baru  dalam  pembuatan  pola  dan  warna  pada  tas  agar bisa  berubah-ubah  sesuai  dengan  yang  diinginkan.  Metode ini  menggunakan  Strip  LED RGB dengan Arduino Android sebagai pusat kontrolnya.     Penggunaan  Strip  LED  RGB(  Light  Emiting  Dioda  Red,  Green,  Blue)  dapat menerima  sinyal  dari  remote  dengan  jarak  30  meter  dan  dapat  memancarkan  cahaya berwarna merah, biru, hijau, kuning dan pink. Sensor warna berfungsi dengan baik, dapat mendeteksi 5 warna dengan benar dan pengontrolan tas dilakukan dengan menggunakan Android dan tas dapat berganti warna sesuai dengan perintah dari handphone android.Kata Kunci :Strip LED RGB, Arduino, Sensor warna, Android, Tas
PENERAPAN ALGORITMA LALR PARSER DAN CONTEXT-FREE GRAMMAR UNTUK STRUKTUR KALIMAT BAHASA INDONESIA
Authors: Pratama Mudafiq Riyan , Kusumadewi Sri , Hidayat Taufiq
Published: February 2020

Penyajian bahasa dalam bentuk tulisan, dapat menyimpan pengetahuan dari generasi ke generasi berikutnya. Setiap penulisan karya tulis seperti buku, hendaknya ditulis dengan tata bahasa yang benar sesuai kaidah-kaidah bahasa Indonesia, karena akan berpengaruh pada kesempurnaan proses penyampaian ide atau pesan. Parsing adalah proses untuk memeriksa kebenaran struktur kalimat berdasarkan suatu grammar (tata bahasa). Salah satu algoritma untuk parsing kata dalam Context-Free Grammar (CFG) adalah LALR Parser. LALR Parser merupakan salah satu varian dari LR Parser yang mampu menangani grammar (Gupta, 2013). Uji coba dilakukan pada tiga jenis kalimat yaitu kalimat tunggal, kalimat majemuk setara, dan kalimat majemuk bertingkat. LALR Parser efektif dalam melakukan parsing terhadap CFG bahasa Indonesia pada kalimat tunggal (nilai akurasi 90.30%), kalimat majemuk setara (nilai akurasi 76.66%), dan kalimat majemuk bertingkat (nilai akurasi 78.57%). Kegagalan deteksi dipengaruhi oleh 3 hal yaitu (1) struktur kalimat tidak sesuai dengan kaidah bahasa Indonesia, (2) unsur pembentuk kalimat tidak tersedia dalam CFG, dan (3) kata yang terdapat dalam kalimat tidak tersedia dalam lexicon.
Learning Outcomes From Lecture and an Online Module in the Family Medicine Clerkship
Authors: Everard Kelly  M. , Schiel Kimberly Zoberi
Published: February 2020

Background and Objectives: With younger generations of learners and readily available technology, medical educators are challenged to include active learning methods that may be better for student learning than traditional lecture. Some of these methods, like online modules, can also reduce the demands on clerkship faculty time. We examined how content delivered via interactive, online module compared to traditional lecture for student learning and satisfaction.
Methods: Third-year family medicine clerkship students completed questionnaires following either an online module or lecture on orofacial pain. We conducted the study over four consecutive rotations, alternating who received the content via classroom lecture or interactive online module. Students completed a questionnaire comprised of six multiple-choice knowledge questions, five questions with a clinical vignette format to assess application of knowledge, and six questions to assess satisfaction with elements of the course. The Centers of Excellence in Pain Education developed the online module and questionnaire.
Results: We found no differences in knowledge between the in-person lecture and the online module. However, students who completed the online module performed better on the application questions. Students in the lecture group reported greater satisfaction with the course than students in the online group.
Conclusions: Lecture resulted in adequate knowledge recall, but the interactive method resulted in better scores on applying knowledge to new situations. Providing an online module where students can practice applying knowledge is important for higher levels of learning, but it should be noted that satisfaction ratings may decline.
Estimación de la producción láctea del ganado Jersey usando variables temporales, intrínsecas y ambientales
Authors: WingChing-Jones Rodolfo , Conejo-Morales Juan Federico
Published: February 2020

Introducción: Predecir el comportamiento de la producción láctea es una actividad constante en los sistemas de producción en busca del uso eficiente de los recursos. Objetivo: Generar un modelo matemático de predicción de la producción láctea que relacione las condiciones climáticas presentes en el momento que se recolectó la información y las características intrínsecas que presentaban los semovientes en dos sistemas de producción ubicados a 600 y 1 800m.s.n.m. en la provincia de Cartago, Costa Rica. Métodos: Utilizamos bases de datos generadas desde el 2003 al 2014, en el sistema ubicado a 660m.s.n.m. para un total de 61 animales, mientras que a 1 800m.s.n.m., la información la registramos entre 2011 al 2014, con el aporte de 387 animales. Resultados: Generamos tres ecuaciones bajo la hipótesis de que los productores no registran la información completa, la primera considera la interacción de las variables ambientales, temporales e intrínsecas del animal, mientras que las siguientes dos ecuaciones, separan el efecto ambiental y las características del animal. A 600m.s.n.m, la temperatura (-4,52), el número de lactancia (-0,99), la humedad relativa (-0,16), el mes (-0,14) y los días de lactancia (-0,02) presentaron un efecto negativo hacia la producción, mientras que la precipitación (0,0004), radiación (0,044), la edad del semoviente (0,084), y el índice de humedad y temperatura (2,68), favorecieron la productividad. En cambio a 1 800m.s.n.m., la radiación (-0,06), la humedad relativa (-0,04) y los días de lactancia (-0,03) disminuyeron la productividad del animal, por el contrario, la precipitación (0,02), el mes de evaluación (0,07) y el número de lactancia (0,57) la aumentaron. Conclusión: Estas ecuaciones son un insumo para que los responsables de los sistemas productivos, tengan una forma de seleccionar o tomar acciones para mantener la homeostasis de los animales.
Contemporary understanding of the spiritual message of the Kosovo myth
Authors: Grozdic Borislav , Dabetic Valerija
Published: February 2020

In the aggressive dominance of critical rational thinking over the mythical
worldview, myth as a historical and effective force does not lose its
actuality and importance, because myths often hide deeper messages than what
history can offer. In such a social context, the significance of the
spiritual message of the Kosovo myth - the commitment to the Heavenly
Kingdom, as a lasting common value of the Serbian people, returns as a
theme. In spite of its omnipresence, the opinion prevails that the myth
belongs to the past, and if it is not yet obsolete, it certainly should be.
The authors advocate the idea that myth, as a comprehensive experience of
the world, and therefore the Kosovo myth as well, is a factor of national
integration, a part of collective identity, and a common value system.
Analysing the secular and spiritual understanding of the Kosovo myth, the
authors point out the importance of the vivid memory of the prince Lazar?s
commitment to the Heavenly Kingdom. For Christians, this represents the
value and goal above all others and it forms the core of the Serbian
historical consciousness and spiritual community. The paper shows that the
spiritual message of the Kosovo myth is not understood or it is
misunderstood nowadays, since the commitment to Kosovo is perceived as a
call and an obligation to die for it. The authors conclude that the Kosovo
myth is not a call to die in the war, on the contrary, it is a struggle for
external and internal freedom, as well as for the highest values that are
implied by the definition of the Heavenly Kingdom ? peace, love, honour,
justice, dignity, and others.
Zur lage des serbischen philosophischen denkens: Was kommt nach der praxis-philosophie? (Eine betrachtung vor dem hintergrund des dialogs mit den thesen von Michailo Markowitsch)
Authors: Jakovljevic Dragan
Published: February 2020

Ausgehend von enstprechenden Einsch?tzungen von M. Markowitsch, werden in
diesem Aufsatz mehrfach relevante Aspekte der aktuellen Lage der serbischen
Philosophie beleuchtet. So wird das Verh?ltnis zum Erbe der
Praxis-Philosophie betrachtet, mit kritischer Untersuchung von Markowitschs?
Thesen, sowie dem Verweis auf weitere m?gliche Perspektiven zur Entfaltung
des serbischen philosophischen Denkens. Parallel dazu wird eine Bilanz aus
den bisherigen Leistungen gezogen, wobei B. Petronijewitsch als der
weiterhin bedeutendste Autor ausgesondert wird. Zugleich werden das Thema
des Provinzialismus und des Epigonentums sowie die M?glichkeit einer
Affirmation auf internationaler Ebene er?ffnet. Dabei wird zugleich auf die
M?glichkeit der Sch?pfung einer christlichen Philosophie orthodoxen
Zuschnitts, als auch auf die des Anschlie?ens an bestimmte, heute aktuelle
philosophische Str?mungen in der Welt hingewiesen. Letztlich wird die
St?rkung des kritischen fachlichen Bewu?tseins, der freie Austausch und die
Konkurrenz verschiedener Autoren an den akademischen Einrichtungen durch
Verdr?ngung von bestimmten Anomalien und die F?rderung internationaler
Wettbewerbsf?higkeit bef?rwortet. ?ber solche Fragen gilt es, unverz?glich
einen Dialog aufzunehmen und entschlossen fortzuf?hren.
Dietary Nonheme, Heme, and Total Iron Intake and the Risk of Diabetes in Adults: Results From the China Health and Nutrition Survey
Authors: He Jingjing , Fang Aiping , Yu Siwang , Shen Xin , Li Keji
Published: February 2020

OBJECTIVE

Excessive iron intake has been linked to diabetes risk. However, the evidence is inconsistent. This study examined the association between dietary heme and nonheme iron intake and diabetes risk in the Chinese population.

RESEARCH DESIGN AND METHODS

We included 17,026 adults (8,346 men and 8,680 women) who were part of the China Health and Nutrition Survey (1991–2015) prospective cohort. Dietary intake was measured by three consecutive 24-h dietary recalls combined with a household food inventory. Diabetes cases were identified through a questionnaire. Cox proportional hazards models were used to estimate hazard ratios (HRs) and 95% CIs.

RESULTS

A total of 547 men and 577 women developed diabetes during 202,138 person-years of follow-up. For men, the adjusted HRs (95% CIs) for quintiles of nonheme iron intake were 1.00, 0.77 (0.58–1.02), 0.72 (0.54–0.97), 0.63 (0.46–0.85), and 0.87 (0.64–1.19) (P-nonlinearity = 0.0015). The corresponding HRs (95% CIs) for women were 1.00, 0.63 (0.48–0.84), 0.57 (0.43–0.76), 0.58 (0.43–0.77), and 0.67 (0.49–0.91) (P-nonlinearity < 0.0001). The dose-response curves for the association between nonheme iron and total iron intake and diabetes followed a reverse J shape in men and an L shape in women. No significant associations were observed between heme iron intake and diabetes risk.

CONCLUSIONS

Total iron and nonheme iron intake was associated with diabetes risk, following a reverse J-shaped curve in men and an L-shaped curve in women. Sufficient intake of nonheme or total iron might be protective against diabetes, while excessive iron intake might increase the risk of diabetes among men.
Gender and Disability in Literature
Authors: Abinaya R. Munish
Published: February 2020

Literature is something which transfers the thoughts and prespectives of the author to the readers and thus results the success of any literary work on the other hand it reflects the society. This paper describes the differences which is prevailing  among the human community that has the power to destroy them too. Disability, is the physical or mental condition that limits a person’s movements,senses or activities. Though the people live together they are strongly rooted with their differences. Both Gender and disability has ruined the dreams of many achievers and there are few who have over came all those in the journey towards their goals.
Entre la expansión urbana y la producción de alimentos
Authors: Baldini Carolina , Marasas Mariana Edith , Drozd Andrea Alejandra
Published: February 2020

La falta de políticas de ordenamiento territorial adecuadas, las deficiencias en su aplicación y los múltiples intereses de los actores vinculados al periurbano productivo en el Partido de La Plata, entre otros factores, han delineado el actual uso insustentable del territorio. Recientemente, han surgido experiencias novedosas de extensión y de investigación-acción participativa, que incorporan lineamientos surgidos como demandas de distintos actores del territorio. En este trabajo buscamos aportar nuevos conocimientos sobre los usos y coberturas del suelo actualizados, sobre las relaciones espaciales entre ellos y con variables físicas, y formular consideraciones para colaborar en las estrategias de planificación colectiva en el territorio. El mapa de usos/coberturas se realizó a partir de imágenes Landsat 8 (2015) aplicando “support vector machine” (ENVI). Éste se integró con mapas de aptitud del suelo, modelo de drenaje y límites de delegaciones municipales. Se identificaron 11 usos/coberturas. Entre ellas, las coberturas semi-naturales se encontraron mucho menos representadas en la zona hortícola. Un 67,93% de los invernáculos se hallaron a menos de 1000 m de zonas urbanas y el 51,16% del área urbana se asentó sobre suelos aptos para la agricultura. La delegación con mayor concentración de invernáculos fue Abasto (23,5%). Por último, el 45,06% de los invernáculos se hallaron a menos de 200 m de arroyos y un 10,19% a menos de 50 m. Esta información es de gran utilidad para un futuro proceso de planificación territorial sustentable, y proporciona una base útil para nutrir el debate acerca de los modelos de agricultura periurbana en Argentina, y en particular en la región de La Plata.
Authors: Syafri Mohamad
Published: February 2020

Penelitian ini melakukan kajian bagaimana generasi Z di IAIN Palu dalam hal keaktifannya di media sosial Instagram, serta bagaimana mereka melih tokoh-tokoh agama. Penelitian memfokuskan media sosial Instagram merujuk kepada tingkat kepopuleran Instagram pada generasi Z. Penelitian ini dilaksanakan dengan menggunakan desain survey yang dilaksanakan secara menyeluruh dengan jumlah sampel 222 orang. Penelitian menunjukkan adanya perbedaan dalam memilih da’I dan tokoh agama di antara mereka yang aktif menggunakan media sosial Instagram dan mereka yang tidak menggunakan Instagram. Hasil penelitian ini menunjukkan perlu adanya kajian yang lebih mendalam terkait dengan media sosial dalam hal fungsinya sebagai salam satu media dakwah. Terutama melihat tingginya animo masyarakat dalam menggunakan media sosial.
THE ROLE OF THE ARTISTIC DETAIL IN DONNA TARTT’S NOVEL «THE GOLDFINCH»
Authors: КOZII Оlhа
Published: February 2020

«The Goldfi nch» is a story of a boy and later an adult male Theodore Decker who accidentally obtains a masterpiece. The writer, as a surgeon, separates one second of expectation from the other, detail from detail. The reader is presented not just a frightened child but deep sorrow of the loss of the whole world. In the second chapter of the fi rst part D.Tartt reveals herself as a skillful psychologist, skillfully a ccustoms herself to the inner state of the main character, with him she travels through the memories, tracks associative relationships he makes. The writer brilliantly follows all defense mechanisms of a man who is faced with the inevitability. The author uses gradation way of describing while stringing visual and auditory details, retards artistic time. The writing of D. Tartt is characterized by the unique skill in the detail describing. The role of artistic detail in the process of inner state depicting is investigated. The author touches upon the problem of the depicting of critical situation in the novel. The attention is paid to the writer’s skills in showing main character’s feelings, memoirs, thoughts, associative relations and human nocifensor in critical situations. It is admitted that in case of such temporal and space detail the most suitable way of analysis is «in succession to the author».
RELATIONSHIP OF THE ART OF WORD AND SCIENCE AS LITERATURE SYNTHESIS
Authors: CHOBANYUK Maria
Published: February 2020

The purpose of the article is to investigate the issues of literary synthesis belonging to different spheres of humanities. Finding your own literary identity is a sign and a constant process. The debate on the new status and new quality of Ukrainian literature is not exhausted and is not over, but is breaking out with renewed vigor. Som e scholars provoke its development, others point to the repetitiveness of arguments, others advocate Ukrainian opportunism and call for an end to all literary disputes, since they distract the writer from the main thing – writing texts. It is proved that the idea of synthesis, its character and role in the science of literature is extremely blurred. Synthesis is explained by the notion of becoming a dynamic, open process, driven by the desire of art to approach the «true life». Synthesis results in organic unity, a complex integrity in which the correlation of part and whole emerges from the intrinsic objectivity of the object, from the «common» basis of the joined forms, which directs search and transformation. The study analyzes the views of literary critics on the consideration of fundamental synthesis studies in contemporary literature on science, which are refl ected in literary and critical practice.
КОНЦЕПТ «СВОБОДА» В КОГНІТИВНО-СЕМАНТИЧНОМУ ПОЛІ ВІРША ІВАНА ФРАНКА «ЩЕ НЕ ПРОПАЛО!»
Authors: ПЕТРІВ Оксана
Published: February 2020

У статті виявлено суть концепту «свобода» в когнітивно-семантичному полі вірша І.Франка «Ще не пропало!», з’ясовано особливості його вербальної репрезентації в поетичному дискурсі; обґрунтовано його відповідність лінгво- культурному профілю української мови. Встановлено, що мовне оформлення тексту є прикладом дискурсивної конфігурації концепту, у якому відображено індивідуально-авторське світорозуміння.
НАВЧАЛЬНІ ІГРИ У ФОРМУВАННІ АНГЛОМОВНОЇ КОМУНІКАТИВНОЇ КОМПЕТЕНТНОСТІ СТУДЕНТІВ
Authors: ФЕДУРКО Оксана
Published: February 2020

У статті розглядається один із активних методів навчання у ВНЗ – навчально-педагогічні ігри. Наголошено на важливості їх використання на уроках англійської мови з метою формування іншомовної комунікативної компетентності майбутніх учителів.
A Thermal Imaging Methodology To Study Evaporation Kinetics in Mine Tailings
Authors: Maurais Josée , Beaumont Étienne , Bourret Joanick , Dauphinais Emrik , Bouchard Nicolas-Alexandre , Ayotte Patrick
Published: February 2020

Predicting why, how, and when mine tailings disposal sites become prone to dust scattering events is often hampered by our limited understanding of the factors that affect the drying rates from their surface layers. As a case study, thermal imaging is demonstrated here to be a valuable tool to study the evaporation mechanisms and rates from bauxite residues as a function of their thickness and physicochemical properties, as well as environmental conditions. These investigations reveal their that late stage drying rates are limited by gas phase diffusion through the interstitial air within their internal microporosity. The smallness of the effective diffusion coefficient indicates that water adsorption on bauxite residues surfaces is the dominant phenomenon responsible for their slow water vapour transport kinetics, a phenomenon that ultimately controls their late stage drying rates, that is when dust scattering is most likely to occur. As such, application of this thermal imaging methodology in the field may also contribute to improve the accuracy of risk assessment protocols, support intervention and mitigation strategies, underpin optimization efforts for mining residues management, and improve forecasting of fugitive dust emissions from mine tailings by enabling more accurate predictions of the evolution in their surface drying state.
Plasma CVD of B-C-N Thin Films Using Triethylboron in Argon-Nitrogen Plasma
Authors: Souqui Laurent , Palisaitis Justinas , Högberg Hans , Pedersen Henrik
Published: February 2020

Amorphous boron-carbon-nitrogen (B-C-N) films with low density are potentially interesting as alternative low-dielectric-constant (low-κ) materials for future electronic devices. Such applications require deposition at temperatures below 300 °C, making plasma chemical vapor deposition (plasma CVD) a preferred deposition method. Plasma CVD of B-C-N films is today typically done with separate precursors for B, C and N or with precursors containing B–N bonds and an additional carbon precursor. We present an approach to plasma CVD of B-C-N films based on triethylboron (B(C2H5)3) a precursor with B-C bonds in an argon-nitrogen plasma. From quantitative analysis with Time-of-Flight Elastic Recoil Detection Analysis (ToF-ERDA), we find that the deposition process can afford B-C-N films with a B/N ratio between 0.98 and 1.3 and B/C ratios between 3.4 and 8.6 and where the films contain between 3.6 and 7.8 at. % H and 6.6 and 20 at. % of O. The films have low density, from 0.32 to 1.6 g/cm3 as determined from cross-section scanning electron micrographs and ToF-ERDA with morphologies ranging from smooth films to separated nanowalls. Scaning transmission electron microscopy shows that C and BN does not phase seperarte in the film. The static dielectric constant κ, measured by capacitance–voltage measurements, varies with the Ar concentration in the range from 3.3 to 35 for low and high Ar concentrations, respectively. We suggest that this dependence is caused by the energetic bombardment of plasma species during film deposition.
Geometric Landscapes for Material Discovery within Energy-Structure-Function Maps
Authors: Moosavi Seyed Mohamad , Xu Henglu , Chen Linjiang , Cooper Andrew I. , Smit Berend
Published: February 2020

Porous molecular crystals are an emerging class of porous materials formed by crystallisation of molecules with weak intermolecular interactions, which distinguishes them from extended nanoporous materials like metal-organic frameworks (MOFs). To aid discovery of porous molecular crystals for desired applications, energy-structure-function (ESF) maps were developed that combine a priori prediction of both the crystal structure and its functional properties. However, it is a challenge to represent the high-dimensional structural and functional landscapes of an ESF map and to identify energetically favourable and functionally interesting polymorphs among the 1,000s-10,000s of structures typically on a single ESF map. Here, we introduce geometric landscapes, a representation for ESF maps based on geometric similarity, quantified by persistent homology. We show that this representation allows the exploration of complex ESF maps, automatically pinpointing interesting crystalline phases available to the molecule. Furthermore, we show that geometric landscapes can serve as an accountable descriptor for porous materials to predict their performance for gas adsorption applications. A machine learning model trained using this geometric similarity could reach a remarkable accuracy in predicting the materials' performance for methane storage applications.
Visible-Light Activated [2+2] Photocycloaddition Reaction Enabled Identification of Carbon-Carbon Double Bonds Position Isomerism in Structural Lipidomics
Authors: Feng Guifang , Hao Yanhong , Wu Liang , Chen Suming
Published: February 2020

The photocycloaddition of olefins with carbonyls is of fundamental interest and practical importance in C=C bond location in unsaturated lipids. However, the traditional UV light activated [2+2] photocycloaddition reaction suffers side reactions and potential health damage. Here, we reported the first example of visible-light activated [2+2] photocycloaddition of anthraquinone with unsaturated lipids. This reaction showed great capability for locating the C=C bonds in various kinds of monounsaturated and polyunsaturated lipids by combining with tandem mass spectrometry (MS), such as fatty acids, phospholipids and glycerides. Based on this developed reaction, a workflow with liquid chromatography tandem MS method was developed for the global identification of unsaturated lipids in human serum, and 86 of monounsaturated and complicated polyunsaturated lipids were identified with definitive positions of C=C bonds. This approach provides new insights both on the photocycloaddition reactions and the structural lipidomics.
Mass Spectral Similarity Mapping Applied to Fentanyl Analogs
Authors: Moorthy Arun , Kearsley Anthony J. , Mallard W. Gary , Wallace William E.
Published: February 2020

: This manuscript outlines a straight-forward procedure for generating a map of similarity between spectra of a set. When applied to a reference set of spectra for Type I fentanyl analogs (molecules differing from fentanyl by a single modification), the map illuminates clustering that is applicable to automated structure assignment of unidentified molecules. An open-source software implementation that generates mass spectral similarity mappings of unknowns against a library of Type I fentanyl analog spectra is available at http://github.com/asm3-nist/FentanylClassifier.
The Superior Hydrothermal Stability of Pd/SSZ-39 in Low Temperature Passive NOx Adsorption (PNA) and Methane Combustion
Authors: Khivantsev Konstantin , Jaegers Nicholas R. , Kovarik Libor , Wang Meng , Hu Jian Zhi , Wang Yong , Derewinski Miroslaw A. , Szanyi János
Published: February 2020

We successfully synthesized uniform SSZ-39 with an average crystal size of about a micron. Pd (0.7 - 3 wt%) was supported on SSZ-39 with Si/Al ratio ~12. The as-synthesized materials were characterized by FTIR, XRD, Helium Ion Microscopy, HAADF-STEM imaging, 27Al, 29Si and H solid state NMR spectroscopic techniques.

FTIR studies with CO and NO probe molecules reveal that the 0.7 wt% Pd/SSZ-39 material with Si/Al ~12 has the majority of Pd dispersed atomically as isolated Pd(II) and Pd(II)-OH centers, and thus can be used as a low-temperature passive NOx adsorber. Pd(II)-NO, Pd(II)(OH)(NO) and Pd(II)(CO)(NO) complexes form during PNA in this material. We compare this PNA material directly with the Pd/SSZ-13 system (with Si/Al ratio ~12) and show its superior hydrothermal stability. Remarkably, Pd/SSZ-39 with Si/Al ratio ~12 survives hydrothermal aging up to 815 ºC in 10% H2O/Air vapor for 16 hours without significant loss in activity. The SSZ-39 crystal structure remains intact during hydrothermal aging up to 1,000 ºC as we elucidate it with XRD and HAADF-STEM imaging/EDS mapping. However, changes to the framework during such harsh hydrothermal treatment significantly change the NOx release profiles during PNA as evidenced by high-field 27Al NMR on fresh and aged Pd/SSZ-39 samples as well as PNA performance measurements.

Besides PNA application, these hydrothermally very stable materials (3 wt% Pd on SSZ-39 with Si/Al ratio ~12) can be used as a robust methane combustion catalyst under industrially relevant conditions (GHSV~600,000hr-1). This catalyst shows minimal deactivation after both harsh hydrothermal aging at 750 and 800 ºC, and prolonged time on stream (105 hrs) at 425 ⁰C. In contrast, both 3wt% Pd/alumina and 3wt% SSZ-13 supported samples lose a significant portion of their activity.
AT-CuAAC Synthesis of Mechanically Interlocked Oligonucleotides
Authors: Acevedo-Jake Amanda , Ball Andrew , Galli marzia , Kukwikila Mikiembo , denis mathieu , Singleton Daniel , tavassoli ali , Goldup Stephen
Published: February 2020

We present a simple strategy for the synthesis of main chain oligonucleotide rotaxanes with precise control over the position of the macrocycle. The novel DNA-based rotaxanes were analyzed to assess the effect of the mechanical bond on their properties.
The Declaration of Helinski Revised by the World Medical Organisation, Edinburgh 2000
Authors: Deutsch Erwin
Published: February 2020

This is an edited version of a paper delivered at a conference in Gijon, Spain in 2001. Professor Deutsch provides an introduction to, and overview of, the recently revised Declaration of Helsinki. Early sets of international rules put the benefit and the wellbeing of the experimental subject in the first place and insist on weighing the benefit and the danger of the experiment against each other. The article covers the history of the Declaration, arguments about reforming the Declaration, a critique of the New Declaration of Helsinki 2000, and the relationship between the Declaration and the European Union.
Napster and New Zealand: Authorisation Under the Copyright Act 1994
Authors: Apáthy Paul
Published: February 2020

This article critically examines the concept of authorisation under the Copyright Act 1994 and considers how New Zealand courts might deal with the issues raised by the Napster litigation in the United States.
The New Game with the Old Rules: Boundary Determination Under MMP
Authors: Beever Graham
Published: February 2020

In 1996, New Zealand experienced its first election under MMP, a system of proportional representation. MMP had been recommended ten years earlier by the Royal Commission on the Electoral System. However, some of the details surrounding the operation of the new system differ significantly from the original recommendations of the Royal Commission.In relation to the determination of electoral boundaries, an issue of considerable importance under the previous First Past the Post system but of diminished significance under MMP, there are two particularly important differences. One of these is the retention of two political representatives on the Representation Commission, the body responsible for determining electoral boundaries. The other is the retention of the electoral tolerance at the relatively low level of five percent. The electoral tolerance is the quantity that determines the acceptable variation in population between electorates.The paper concludes that the political representatives should be removed from the Representation Commission, and that the tolerance should be raised to ten percent, as originally envisaged by the Royal Commission. The entrenched status of these provisions makes reform especially challenging. However, there is evidence to suggest, at least in relation to the tolerance level, that cross-party consensus may be able to be achieved.
Accident Compensation: The Role of Incentives, Consumer Choice and Competition
Authors: Evans Lewis , Quigley Neil
Published: February 2020

In the 1990s, the insurance aspect, as opposed to the social welfare or more communitarian face of the Accident Compensation was prominent in public debate.  In this paper, Professors Evans and Quigley argue that Accident Compensation is indeed more appropriately seen as an insurance scheme. As such they question the appropriateness of state monopoly provision, believing that competition would give both employers and workers greater choice.
Towards Electronic Democracy: The Impact of Technological Change on the Official Information Act 1982
Authors: White Jessica
Published: February 2020

The paper considers the impact of recent technological advancements on the law and policy of the Official Information Act 1982. As the capacity and potential of technology increases, the ability to store, retrieve, and disseminate information could add immense value to the purposes and operation of the Act. However, there are two substantial difficulties with the technological changes. First, there are insufficient efforts to improve access to technology for certain segments of society. Second, co-ordination between initiatives to improve government information management systems have so far proved ineffective. These two problems pose substantial threats to the usefulness of the new technology. Consequently, the paper concludes by recommending that a co-ordinated, educational approach led by central government will ensure that the Act's benefits for citizens are enhanced by technological change, rather than undermined by it.
New Zealand's Oceans Policy
Authors: Foster Angela
Published: February 2020

In light of recent Oceans Policy developments this paper proposes a legal and institutional framework for the management of New Zealand's oceans. It focuses on one key existing problem: the lack of a comprehensive, coherent framework for the sustainable management of the marine environment. The proposed framework addresses this issue by suggesting an overarching statute, based on the approach taken by the Resource Management Act, under which several layers of policy refinement and implementation create national consistency coexisting with localised solutions based on the purpose of sustainability and broad guiding principles. The proposal is consistent with New Zealand's international obligations, other domestic legislation and existing institutional structures. The paper concludes with a statement on the importance to our future well-being of developing a comprehensive and enduring Oceans Policy.
Colin Campbell Aikman: Reflections
Authors: Keith Sir Kenneth , Angelo A H
Published: February 2020

Dr Colin Aikman served as Dean of the Victoria University of Wellington Law School. This article focuses on aspects of Dr Aikman's seminal lecture of the 1960s on law in the South Pacific, and on the impact of the constitutional thinking of Dr Aikman in the Pacific on a generation of students and colleagues in the Law Faculty of Victoria University of Wellington.
You're The Voice – Try and Understand it: Some Practical Problems of the Citizens Initiated Referenda Act
Authors: Goschik Ben
Published: February 2020

This paper examines the New Zealand’s Citizens Initiated Referenda Act 1993. The first part of the paper examines the democratic nature of the ‘direct democracy’ of citizens initiated referenda. The second part of the paper tackles certain of the practical concerns that flow from the legislation and the process that the legislation requires. In particular, the paper considers the uneasy relationship between the Clerk of the House and the role that the Clerk plays in determining the referendum question. Then, the paper examines problems concerning the referendum question itself, considering the limitation of only allowing a ‘yes’ or ‘no’ answer, as well as questions that ‘demand’ one answer over the other or raise more than one issue. The author argues that there is a real concern surrounding the ability of citizens initiated referenda to improve the democratic process through involving people in the legislative process.
Первопринципные расчеты углеродных бислоев с алмазоподобными структурами
Authors: Грешняков В.А. , Беленков Е.А.
Published: February 2020

Выполнены первопринципные расчеты моноатомных и двухатомных углеродных слоев из четырехкоординированных (sp3-гибридизированных) атомов. По расчетам моноатомные алмазоподобные слои L4, L3-6 и L3-4-6 неустойчивы даже при температуре 0 K. Структура двухатомных слоев может быть сформирована при полимеризации слоев гексагонального графена. В результате анализа всех возможных вариантов сшивок пар графеновых слоев установлено, что устойчивым может быть только один двухатомный слой. Кристаллическая решетка этого слоя относится к группе симметрии p6/mmm. (Гексагональная элементарная ячейка содержит четыре атома, ее параметр a = 2.737 Å). Поверхностная плотность, энергия сублимации, ширина прямой запрещенной зоны слоя равны 0.123 мкг/см2, 6.64 эВ/атом и 3.37 эВ соответственно. Также установлено, что при нормальном давлении структура гексагонального алмазоподобного слоя должна быть стабильной до 250 K. Для экспериментальной идентификации алмазоподобных слоев в углеродных материалах рассчитана порошковая рентгенограмма.
Two new entangled Zn and Cd coordination polymers based on a rich «mix» feature of the O- and N-donor ligand system: Synthesis, structure, and fluorescent properties
Authors: Wang X.F.
Published: February 2020

A prominent mixed-ligand system with rich «mix» features, which are rigid multicarboxylate O-donor ligands cooperating with flexible bisazole N-donor linkers, is explored to coordinate with Zn2+/Cd2+ centers. Two new entangled coordination polymers ([Cd(Hbtc)(bbi)] (1) and [Zn(btec)0.5(dtp)]×5H2O (2)) are gained. Complex 1 exhibits a fascinating 3D (3,5)-connected net with a Schläfli symbol of the (63.610) topology, and 3D nets penetrate into each other to give rise to twofold interpenetrations. Complex 2 displays a 2D layer with similar 9.9·12.0 Å2 hexagonal channels, the adjacent layers stacking with each other to form a 3D supramolecular structure. The effects and functions of the ligands in the complexes are discussed. Moreover, the thermal stabilities and fluorescence properties of complexes 1 and 2 are investigated.
One-pot synthesis of 1,4-dihydropyridine derivatives and their X-ray crystal structures: role of fluorine in weak interactions
Authors: Shashi R. , Prasad N.L. , Begum N.S.
Published: February 2020

1,4-dihydropyridines, namely diethyl 4-(4-fluorophenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate (1a), diethyl 2,6-dimethyl-4-(3,4,5-trimethoxyphenyl)-1,4-dihydropyridine-3,5-dicarboxylate(1b), and diethyl 4-(3,4-dimethoxyphenyl)-2,6-dihydroxy-2,6-bis(trifluoro­methyl)piperidine-3,5-dicarboxylate (2), are synthesized by one-pot multicomponent condensation of aromatic aldehyde with ethyl acetoacetate and liquid ammonia in the presence of an ethanol-water mixture and are characterized by single crystal X-ray diffraction. The effect of a fluorine atom on the dihydropyridine nucleus give insight into the self-assembly of compounds with various types of non-covalent interactions that greatly affect the crystal packing.