bluuebunny/crossref_metadata_2025 huggingface dataset:
Learning Prosody in a Video Game-Based Learning Approach
Authors: Aguilar Lourdes
Published: July 2019

With the growth in popularity of video games in our society many teachers have worked to incorporate gaming into their classroom. It is generally agreed that by adding something fun to the learning process students become more engaged and, consequently, retain more knowledge. However, although the characteristics of video games facilitate the dynamics of the educational process it is necessary to plan a pedagogical project that includes delimitation of learning goals and profile of the addressees, the conditions of application of the educational project, and the methodologies of evaluation of the learning progress. This is how we can make a real difference between gamification and video game based learning. The paper addresses the design of an educational resource for special education needs (SEN) students that aims to help teach communicative skills related to prosody. The technological choices made to support the pedagogic issues that underlie the educational product, the strategies to convert learning content into playful material, and the methodology to obtain measures of its playability and effectiveness are described. The results of the motivation test certified that the video game is useful in encouraging the users to exercise their voice and the indicators of the degree of achievement of the learning goals serve to identify the most affected prosodic skills.
Antimicrobial and Conductive Nanocellulose-Based Films for Active and Intelligent Food Packaging
Authors: Vilela Carla , Moreirinha Catarina , Domingues Eddy M. , Figueiredo Filipe M. L. , Almeida Adelaide , Freire Carmen S. R.
Published: July 2019

Bacterial nanocellulose (BNC) is becoming an important substrate for engineering multifunctional nanomaterials with singular and tunable properties for application in several domains. Here, antimicrobial conductive nanocomposites composed of poly(sulfobetaine methacrylate) (PSBMA) and BNC were fabricated as freestanding films for application in food packaging. The nanocomposite films were prepared through the one-pot polymerization of sulfobetaine methacrylate (SBMA) inside the BNC nanofibrous network and in the presence of poly(ethylene glycol) diacrylate as cross-linking agent. The ensuing films are macroscopically homogeneous, more transparent than pristine BNC, and present thermal stability up to 265 °C in a nitrogen atmosphere. Furthermore, the films have good mechanical performance (Young’s modulus ≥ 3.1 GPa), high water-uptake capacity (450–559%) and UV-blocking properties. The zwitterion film with 62 wt.% cross-linked PSBMA showed bactericidal activity against Staphylococcus aureus (4.3–log CFU mL−1 reduction) and Escherichia coli (1.1–log CFU mL−1 reduction), and proton conductivity ranging between 1.5 × 10−4 mS cm−1 (40 °C, 60% relative humidity (RH)) and 1.5 mS cm−1 (94 °C, 98% RH). Considering the current set of properties, PSBMA/BNC nanocomposites disclose potential as films for active food packaging, due to their UV-barrier properties, moisture scavenging ability, and antimicrobial activity towards pathogenic microorganisms responsible for food spoilage and foodborne illness; and also for intelligent food packaging, due to the proton motion relevant for protonic-conduction humidity sensors that monitor food humidity levels.
Effect of Piezoresistive Behavior on Electron Emission from Individual Silicon Carbide Nanowire
Authors: Zhao Peng , Zhang Yu , Tang Shuai , Zhan Runze , She Juncong , Chen Jun , Xu Ningsheng , Deng Shaozhi
Published: July 2019

The excellent properties of silicon carbide (SiC) make it widely applied in high-voltage, high-power, and high-temperature electronic devices. SiC nanowires combine the excellent physical properties of SiC material and the advantages of nanoscale structures, thus attracting significant attention from researchers. Herein, the electron vacuum tunneling emission characteristics of an individual SiC nanowire affected by the piezoresistive effect are investigated using in situ electric measurement in a scanning electron microscope (SEM) chamber. The results demonstrate that the piezoresistive effect caused by the electrostatic force has a significant impact on the electronic transport properties of the nanowire, and the excellent electron emission characteristics can be achieved in the pulse voltage driving mode, including lower turn-on voltage and higher maximum current. Furthermore, a physical model about the piezoresistive effect of SiC nanowire is proposed to explain the transformation of electronic transport under the action of electrostatic force in DC voltage and pulsed voltage driving modes. The findings can provide a way to obtain excellent electron emission characteristics from SiC nanowires.
Comparative in Vitro Cytotoxicity of Realistic Doses of Benchmark Multi-Walled Carbon Nanotubes towards Macrophages and Airway Epithelial Cells
Authors: Di Cristo Luisana , Bianchi Massimiliano , Chiu Martina , Taurino Giuseppe , Donato Francesca , Garzaro Giacomo , Bussolati Ovidio , Bergamaschi Enrico
Published: July 2019

Multi-walled carbon nanotubes (MWCNT) have many outstanding physical and chemical properties that make them useful in many applications in nanotechnology. However, these properties are reported to be potentially harmful for the human body. The effects of low and realistic doses of three well-characterized preparations of MWCNT, obtained from the Joint Research Centre (JRC) (NM-400, NM-401, and NM-402), were assessed in two murine macrophage lines, Raw264.7, of peritoneal origin, and MH-S, derived from alveolar macrophages. Macrophage viability, evaluated with two distinct methods, was significantly lowered by NM-401 (needle-like, average length 4 μm, diameter 67 nm) with IC50 values of 10 μg/cm2, whereas NM-400 and NM-402 (tangled, average lengths 846–1372 nm, diameter 11 nm) had much smaller effects. In contrast, at 10 μg/cm2, NM-400 and NM-402 induced the M1 marker Nos2 and, consistently, a sizable accumulation of nitrites in the medium, whereas NM-401 had no significant effect. None of the MWCNT preparations induced the M2 marker Arg1. Phagocytic activity, assessed in Raw264.7 macrophages, was significantly reduced in cells exposed to NM-401, but not to NM-400 or NM-402. When tested on Calu-3 bronchial epithelial cell monolayers, the three MWCNT preparations did not affect cell viability, but decreased the trans-epithelial electrical resistance at the maximal dose tested (80 μg/cm2), with the most evident effect detected for NM-401, even at 10 μg/cm2. In conclusion, among the possible structural determinants of the toxic effects exerted by MWCNT towards macrophages and airway epithelial cells, shape and length appear the most relevant at low, realistic doses.
Improved Surface-Enhanced Raman Scattering Properties of ZrO2 Nanoparticles by Zn Doping
Authors: Ji Peng , Mao Zhu , Wang Zhe , Xue Xiangxin , Zhang Yu , Lv Jiaao , Shi Xiumin
Published: July 2019

In this study, ZrO2 and Zn–ZrO2 nanoparticles (NPs) with a series of Zn ion doping amounts were synthesized by the sol-gel process and utilized as substrates for surface-enhanced Raman scattering (SERS). After absorbing the probing molecule 4–mercaptobenzoic acid, the SERS signal intensities of Zn–ZrO2 NPs were all greater than that of the pure ZrO2. The 1% Zn doping concentration ZrO2 NPs exhibited the highest SERS enhancement, with an enhancement factor (EF) value of up to 104. X-ray diffraction, X-ray photoelectron spectroscopy, Ultraviolet (UV) photoelectron spectrometer, UV–vis spectroscopy, Transmission Electron Microscope (TEM), and Raman spectroscopy were used to characterize the properties of Zn–ZrO2 NPs and explore the mechanisms behind the SERS phenomenon. The charge transfer (CT) process is considered to be responsible for the SERS performance of 4–MBA adsorbed on Zn–ZrO2. The results of this study demonstrate that an appropriate doping ratio of Zn ions can promote the charge transfer process between ZrO2 NPs and probe molecules and significantly improve the SERS properties of ZrO2 substrates.
Synthesis of Nitrogen-Doped Graphene on Copper Nanowires for Efficient Thermal Conductivity and Stability by Using Conventional Thermal Chemical Vapor Deposition
Authors: Park Minjeong , Ahn Seul-Ki , Hwang Sookhyun , Park Seongjun , Kim Seonpil , Jeon Minhyon
Published: July 2019

Cu nanowires (NWs) possess remarkable potential a slow-cost heat transfer material in modern electronic devices. However, Cu NWs with high aspect ratios undergo surface oxidation, resulting in performance degradation. A growth temperature of approximately <1000 °C is required for preventing the changing of Cu NW morphology by the melting of Cu NWs at over 1000 °C. In addition, nitrogen (N)-doped carbon materials coated on Cu NWs need the formation hindrance of oxides and high thermal conductivity of Cu NWs. Therefore, we investigated the N-doped graphene-coated Cu NWs (NG/Cu NWs) to enhance both the thermal conductivity and oxidation stability of Cu NWs. The Cu NWs were synthesized through an aqueous method, and ethylenediamine with an amine group induced the isotropic growth of Cu to produce Cu NWs. At that time, the amine group could be used as a growth source for the N-doped graphene on Cu NWs. To grow an N-doped graphene without changing the morphology of Cu NWs, we report a double-zone growth process at a low growth temperature of approximately 600 °C. Thermal-interface material measurements were conducted on the NG/Cu NWs to confirm their applicability as heat transfer materials. Our results show that the synthesis technology of N-doped graphene on Cu NWs could promote future research and applications of thermal interface materials in air-stable flexible electronic devices.
Non-Resorbable Nanocomposite Membranes for Guided Bone Regeneration Based on Polysulfone-Quartz Fiber Grafted with Nano-TiO2
Authors: Nechifor Gheorghe , Eftimie Totu Eugenia , Nechifor Aurelia Cristina , Isildak Ibrahim , Oprea Ovidiu , Cristache Corina Marilena
Published: July 2019

The polymer-inorganic nanoparticles composite membranes are the latest solutions for multiple physicochemical resistance and selectivity requirements of membrane processes. This paper presents the production of polysulfone-silica microfiber grafted with titanium dioxide nanoparticles (PSf-SiO2-TiO2) composite membranes. Silica microfiber of length 150–200 μm and diameter 12–15 μm were grafted with titanium dioxide nanoparticles, which aggregated as microspheres of 1–3 μm, applying the sol-gel method. The SiO2 microfibers grafted with nano-TiO2 were used to prepare 12% polysulfone-based nanocomposite membranes in N-methyl pyrrolidone through the inversion phase method by evaporation. The obtained nanocomposite membranes, PSf-SiO2-TiO2, have flux characteristics, retention, mechanical characteristics, and chemical oxidation resistance superior to both the polysulfone integral polymer membranes and the PSf-SiO2 composite membranes. The antimicrobial tests highlighted the inhibitory effect of the PSf-SiO2-TiO2 composite membranes on five Gram (-) microorganisms and did not allow the proliferation of Candida albicans strain, proving that they are suitable for usage in the oral environment. The designed membrane met the required characteristics for application as a functional barrier in guided bone regeneration.
The Impact of Nylon-3 Copolymer Composition on the Efficiency of siRNA Delivery to Glioblastoma Cells
Authors: Hartl Natascha , Adams Friederike , Costabile Gabriella , Isert Lorenz , Döblinger Markus , Xiao Ximian , Liu Runhui , Merkel Olivia M.
Published: July 2019

Glioblastoma multiforme is a devastating disease that has attracted enormous attention due to poor prognosis and high recurrence. Small interfering RNA (siRNA) in principle offers a promising therapeutic approach by the downregulation of disease-related genes via RNA interference. For efficient siRNA delivery to target sites, cationic polymers are often used in preclinical studies for the protection of siRNA and complex formation based on electrostatic interactions. In an effort to develop biocompatible and efficient nanocarriers with a translational outlook for optimal gene silencing at reduced toxicity, we synthesized two sets of nylon-3 copolymers with variable cationic content (DM or NM monomer) and hydrophobic subunits (CP monomer) and evaluated their suitability for in vitro siRNA delivery into glioblastoma cells. DM0.4/CP0.6 and NM0.4/CP0.6 polymers with similar subunit ratios were synthesized to compare the effect of different cationic subunits. Additionally, we utilized NM0.2/CP0.8 polymers to evaluate the impact of the different hydrophobic content in the polymer chain. The siRNA condensation ability and polymer–siRNA complex stability was evaluated by unmodified and modified SYBR gold assays, respectively. Further physicochemical characteristics, e.g., particle size and surface charge, were evaluated by dynamic light scattering and laser Doppler anemometry, whereas a relatively new method for polyplex size distribution analysis—tunable resistive pulse sensing—was additionally developed and compared to DLS measurements. Transfection efficiencies, the route of cell internalization, and protein knockdown abilities in glioblastoma cells were investigated by flow cytometry. Furthermore, cellular tolerability was evaluated by MTT and LDH assays. All the polymers efficiently condensed siRNA at N/P ratios of three, whereas polymers with NM cationic subunits demonstrated smaller particle size and lower polyplex stability. Furthermore, NM0.2/CP0.8 polyplexes with the highest hydrophobic content displayed significantly higher cellular internalization in comparison to more cationic formulations and successful knockdown capabilities. Detailed investigations of the cellular uptake route demonstrated that these polyplexes mainly follow clathrin-mediated endocytotic uptake mechanisms, implying high interaction capacity with cellular membranes. Taken together with conducive toxicity profiles, highly hydrophobic nylon-3 polymers provide an appropriate siRNA delivery agent for the potential treatment of glioblastoma.
Low-Dose Curcumin Nanoparticles Normalise Blood Pressure in Male Wistar Rats with Diet-Induced Metabolic Syndrome
Authors: du Preez Ryan , Pahl Jessica , Arora Meenakshi , Ravi Kumar M. N. V. , Brown Lindsay , Panchal Sunil K.
Published: July 2019

Nanoparticle formulations improve bioavailability and so may allow low-dose formulations of food-derived compounds such as curcumin to attenuate chronic systemic disease despite intrinsically low oral bioavailability. The current study induced metabolic syndrome in male Wistar rats aged eight–nine weeks using a high-carbohydrate, high-fat diet (H) with corn starch diet (C) as control. Using a reversal protocol, rats were given curcumin as either nanoparticles encapsulated in poly(lactic–co–glycolic acid) (5 mg/kg/day, HCNP) or as an unformulated low dose or high-dose suspension in water (low-dose, 5 mg/kg/day, HC5; high-dose, 100 mg/kg/day, HC100) or blank nanoparticles (HBNP) for the final eight weeks of the 16 week study. We analysed cardiovascular parameters including systolic blood pressure and left ventricular diastolic stiffness along with histopathology, liver parameters including plasma liver enzymes, histopathology and metabolic parameters, including glucose tolerance, blood lipid profile and body composition, and plasma curcumin concentrations. HC100 and HCNP but not HBNP normalised systolic blood pressure (C = 120 ± 4; H = 143 ± 5; HBNP = 141 ± 3; HC5 = 143 ± 4; HC100 = 126 ± 4; HCNP = 128 ± 4 mmHg), left ventricular diastolic stiffness and liver fat deposition. No other improvements were induced in HC100 or HCNP or other intervention groups (HC5 and HBNP). We conclude that 5 mg/kg/day curcumin nanoparticles in H rats showed similar improvements in cardiovascular function as 100 mg/kg/day unformulated curcumin correlating with similar plasma curcumin concentrations.
Correction: Roberts et al. “Satiating Effect of High Protein Diets on Resistance-Trained Individuals in Energy Deficit” Nutrients 2019, 11(1), 56
Authors: Roberts Justin , Zinchenko Anastasia , Mahbubani Krishnaa , Johnstone James , Smith Lee , Merzbach Viviane , Blacutt Miguel , Banderas Oscar , Villasenor Luis , Vårvik Fredrik T. , Henselmans Menno
Published: July 2019

The authors wish to make a correction to the published version of their paper [...]
Impact of Gas Flow and Humidity on Trans-Nasal Aerosol Deposition via Nasal Cannula in Adults: A Randomized Cross-Over Study
Authors: Alcoforado Luciana , Ari Arzu , Barcelar Jacqueline , Brandão Simone , Fink James , de Andrade Armele
Published: July 2019

Background: Trans-nasal pulmonary aerosol delivery using high flow nasal cannula (HFNC) devices is described with the administration of high gas flows exceeding patient inspiratory flow (HF) and with lower flows (LF). The aim of this pilot clinical trial was to compare deposition and distribution of radiolabeled aerosol via nasal cannula in healthy adults across three rates of gas flow delivered with active heated humidification, and to further identify the impact of aerosol administration without heated humidity. Methods: Twenty-three (23) healthy adults (16F) were randomized to receive aerosol with active heated humidification or unheated oxygen at gas flows of 10 L/min (n = 8), 30 L/min (n = 7), or 50 L/min (n = 8). Diethylenetriaminepentaacetic acid labeled with 1 millicurie (37 MBq) of Technetium-99m (DTPA-Tc99m) was mixed with NaCl to a fill volume of 1 mL, and administered via mesh nebulizer placed at the inlet of the humidifier. Radioactivity counts were performed using a gamma camera and the regions of interest (ROIs) were delimited with counts from the lungs, upper airways, stomach, nebulizer, circuit, and expiratory filter. A mass balance was calculated and each compartment was expressed as a percentage of the total. Results: Lung deposition (mean ± SD) with heated humidified gas was greater at 10 L/min than 30 L/min or 50 L/min (17.2 ± 6.8%, 5.71 ± 2.04%, and 3.46 ± 1.24%, respectively; p = 0.0001). Using unheated carrier gas, a lung dose of aerosol was similar to the active heated humidification condition at 10 L/min, but greater at 30 and 50 L/min (p = 0.011). Administered gas flow and lung deposition were negatively correlated (r = −0.880, p < 0.001). Conclusions: Both flow and active heated humidity inversely impact aerosol delivery through HFNC. Nevertheless, aerosol administration across the range of commonly used flows can provide measurable levels of lung deposition in healthy adult subjects (NCT 02519465).
Student Perspectives on a Collaborative International Doctorate of Pharmacy Program
Authors: Pham Jennifer T. , Azzopardi Lilian M. , Lau Alan H. , Jarrett Jennie B.
Published: July 2019

Objectives: To evaluate the educational experience and teaching methods of the collaborative Doctorate of Pharmacy (PharmD) program between the University of Malta (UM) and the University of Illinois at Chicago (UIC). Methods: A 41-question survey was developed to identify student demographics, satisfaction with the PharmD program and the utility of the current curricular components. Students who enrolled in the program in May 2017 were invited to participate. The survey contained open-ended, 5-point Likert, and multiple-choice type questions. The primary outcomes were the overall satisfaction and student motivations for pursuing the program. Secondary outcomes included the level of difficulty of courses, evaluation of assessment methods, and confidence in an interdisciplinary team. Results: Thirty-six students completed the survey (a response rate of 83.7%). The mean age was 30.1 ± 7.9 years. The majority of the students pursued the PharmD program to improve their knowledge, skills, and opportunity for obtaining a clinical position. The mean overall satisfaction of the program was 3.81 ± 1.1 (5 = very satisfied). Among the core courses, Pharmacotherapeutics had the highest overall satisfaction (4.45 ± 0.91) and level of difficulty (3.84 ± 0.51). Students felt that the tutorials/recitation case discussion sessions were the most effective teaching method (48.4%) and ranked faculties conducting case-based lectures highest for overall performance. Most students felt somewhat confident (54.8%) for participating in a multidisciplinary team. Conclusions: The UM/UIC PharmD Program is a unique program, utilizing a hybrid model of teaching, including distance education, to expose students to a broad and challenging curriculum in clinical pharmacy practice. Students are satisfied with this collaborative, international postgraduate PharmD program.
lpa1-5525: A New lpa1 Mutant Isolated in a Mutagenized Population by a Novel Non-Disrupting Screening Method
Authors: Borlini Giulia , Rovera Cesare , Landoni Michela , Cassani Elena , Pilu Roberto
Published: July 2019

Phytic acid, or myo-inositol 1,2,3,4,5,6-hexakisphosphate, is the main storage form of phosphorus in plants. It is localized in seeds, deposited as mixed salts of mineral cations in protein storage vacuoles; during germination, it is hydrolyzed by phytases to make available P together with all the other cations needed for seed germination. When seeds are used as food or feed, phytic acid and the bound cations are poorly bioavailable for human and monogastric livestock due to their lack of phytase activity. Therefore, reducing the amount of phytic acid is one strategy in breeding programs aimed to improve the nutritional properties of major crops. In this work, we present data on the isolation of a new maize (Zea mays L.) low phytic acid 1 (lpa1) mutant allele obtained by transposon tagging mutagenesis with the Ac element. We describe the generation of the mutagenized population and the screening to isolate new lpa1 mutants. In particular, we developed a fast, cheap and non-disrupting screening method based on the different density of lpa1 seed compared to the wild type. This assay allowed the isolation of the lpa1-5525 mutant characterized by a new mutation in the lpa1 locus associated with a lower amount of phytic phosphorus in the seeds in comparison with the wild type.
Phylogenetic Reconstruction and Divergence Time Estimation of Blumea DC. (Asteraceae: Inuleae) in China Based on nrDNA ITS and cpDNA trnL-F Sequences
Authors: Zhang Ying-bo , Yuan Yuan , Pang Yu-xin , Yu Fu-lai , Yuan Chao , Wang Dan , Hu Xuan
Published: July 2019

The genus Blumea is one of the most economically important genera of Inuleae (Asteraceae) in China. It is particularly diverse in South China, where 30 species are found, more than half of which are used as herbal medicines or in the chemical industry. However, little is known regarding the phylogenetic relationships and molecular evolution of this genus in China. We used nuclear ribosomal DNA (nrDNA) internal transcribed spacer (ITS) and chloroplast DNA (cpDNA) trnL-F sequences to reconstruct the phylogenetic relationship and estimate the divergence time of Blumea in China. The results indicated that the genus Blumea is monophyletic and it could be divided into two clades that differ with respect to the habitat, morphology, chromosome type, and chemical composition of their members. The divergence time of Blumea was estimated based on the two root times of Asteraceae. The results indicated that the root age of Asteraceae of 76–66 Ma may maintain relatively accurate divergence time estimation for Blumea, and Blumea might had diverged around 49.00–18.43 Ma. This common ancestor had an explosive expansion during the Oligocene and Miocene and two major clades were differentiated during these epochs 29.60 Ma (17.76–45.23 Ma 95% HPD (Highest Posterior Density). Evidence from paleogeography and paleoclimate studies has confirmed that Blumea experienced differentiation and an explosive expansion during the Oligocene and Miocene.
Achieving High Thermal Conductivity in Epoxy Composites: Effect of Boron Nitride Particle Size and Matrix-Filler Interface
Authors: Moradi Sasan , Calventus Yolanda , Román Frida , Hutchinson John M
Published: July 2019

For the thermal management of high watt density circuit layers, it is common to use a filled epoxy system to provide an electrically insulating but thermally conducting bond to a metal substrate. An epoxy-thiol system filled with boron nitride (BN), in the form of 2, 30 and 180 µm platelets, has been investigated with a view to achieving enhanced thermal conductivity. The effect of BN content on the cure reaction kinetics has been studied by differential scanning calorimetry and the thermal conductivity of the cured samples has been measured by the Transient Hot Bridge method. The heat of reaction and the glass transition temperature of the fully cured samples are both independent of the BN content, but the cure reaction kinetics is systematically affected by both BN content and particle size. These results can be correlated with the thermal conductivity of the cured systems, which is found to increase with both BN content and particle size. For a given BN content, the thermal conductivity found here is significantly higher than most others reported in the literature; this effect is attributed to a Lewis acid-base interaction between filler and matrix.
Pharmacologic Application Potentials of Sulfated Polysaccharide from Marine Algae
Authors: Manlusoc Joanne Katherine Talens , Hsieh Chieh-Lun , Hsieh Cheng-Yang , Salac Ellen San Nicolas , Lee Ya-Ting , Tsai Po-Wei
Published: July 2019

With the advent of exploration in finding new sources for treating different diseases, one possible natural source is from marine algae. Having an array of potential benefits, researchers are interested in the components which comprise one of these activities. This can lead to the isolation of active compounds with biological activities, such as antioxidation of free radicals, anti-inflammation, antiproliferation of cancer cells, and anticoagulant to name a few. One of the compounds that are isolated from marine algae are sulfated polysaccharides (SPs). SPs are complex heterogenous natural polymers with an abundance found in different species of marine algae. Marine algae are known to be one of the most important sources of SPs, and depending on the species, its chemical structure varies. This variety has important physical and chemical components and functions which has gained the attention of researchers as this contributes to the many facets of its pharmacologic activity. In this review, recent pharmacologic application potentials and updates on the use of SPs from marine algae are discussed.
Using Annual Resolution Pollen Analysis to Synchronize Varve and Tree-Ring Records
Authors: Theuerkauf Martin , Engelbrecht Eike , Dräger Nadine , Hupfer Michael , Mrotzek Almut , Prager Anja , Scharnweber Tobias
Published: July 2019

Fossil wood and varved lake sediments allow proxy analysis with exceptionally high, (sub-)annual resolution. Both archives provide dating through ring and layer counting, yet with different accuracy. In wood, counting errors are small and can be eliminated through cross-dating because tree-rings show regionally synchronous patterns. In varved sediments, counting errors are larger and cross-dating is hampered by missing regional patterns in varve parameters. Here, we test whether annual pollen analysis is suited to synchronize varve records. To that end, annual pollen deposition was estimated in three short cores from two lakes in north-eastern Germany for the period 1980–2017 CE. Analysis has focused on Fagus sylvatica and Picea abies, which show the strongest annual variations in flowering (mast). For both tree taxa, annual flowering variations recorded by forest and pollen monitoring are well represented in varved lake sediments, hence indeed allow us to synchronize the records. Some pollen mast events were not recognized, which may relate to sampling uncertainties, redeposition or regional variations in flowering. In Fagus sylvatica, intense flowering limits wood growth in the same year. Peaks in pollen deposition hence correlate with minima in tree-ring width, which provides a link between varved lake sediments and fossil wood.
The Time-Spatial Dimension of Eurozone Banking Systemic Risk
Authors: Foglia Matteo , Angelini Eliana
Published: July 2019

In this paper, we measure the systemic risk with a novel methodology, based on a “spatial-temporal” approach. We propose a new bank systemic risk measure to consider the two components of systemic risk: cross-sectional and time dimension. The aim is to highlight the “time-space dynamics” of contagion, i.e., if the CDS spread of bank i depends on the CDS spread of other banks. To do this, we use an advanced spatial econometrics design with a time-varying spatial dependence that can be interpreted as an index of the degree of cross-sectional spillovers. The findings highlight that the Eurozone banks have strong spatial dependence in the evolution of CDS spread, namely the contagion effect is present and persistent. Moreover, we analyse the role of the European Central Bank in managing contagion risk. We find that monetary policy has been effective in reducing systemic risk. However, the results show that systemic risk does not imply a policy intervention, highlighting how financial stability policy is not yet an objective.
An Urn-Based Nonparametric Modeling of the Dependence between PD and LGD with an Application to Mortgages
Authors: Cheng Dan , Cirillo Pasquale
Published: July 2019

We propose an alternative approach to the modeling of the positive dependence between the probability of default and the loss given default in a portfolio of exposures, using a bivariate urn process. The model combines the power of Bayesian nonparametrics and statistical learning, allowing for the elicitation and the exploitation of experts’ judgements, and for the constant update of this information over time, every time new data are available. A real-world application on mortgages is described using the Single Family Loan-Level Dataset by Freddie Mac.
The Reduction Method of Bathymetric Datasets that Preserves True Geodata
Authors: Wlodarczyk-Sielicka Marta , Stateczny Andrzej , Lubczonek Jacek
Published: July 2019

Water areas occupy over 70 percent of the Earth’s surface and are constantly subject to research and analysis. Often, hydrographic remote sensors are used for such research, which allow for the collection of information on the shape of the water area bottom and the objects located on it. Information about the quality and reliability of the depth data is important, especially during coastal modelling. In-shore areas are liable to continuous transformations and they must be monitored and analyzed. Presently, bathymetric geodata are usually collected via modern hydrographic systems and comprise very large data point sequences that must then be connected using long and laborious processing sequences including reduction. As existing bathymetric data reduction methods utilize interpolated values, there is a clear requirement to search for new solutions. Considering the accuracy of bathymetric maps, a new method is presented here that allows real geodata to be maintained, specifically position and depth. This study presents a description of a developed method for reducing geodata while maintaining true survey values.
Gaussian Processes for Vegetation Parameter Estimation from Hyperspectral Data with Limited Ground Truth
Authors: Gewali Utsav B. , Monteiro Sildomar T. , Saber Eli
Published: July 2019

An important application of airborne- and satellite-based hyperspectral imaging is the mapping of the spatial distribution of vegetation biophysical and biochemical parameters in an environment. Statistical models, such as Gaussian processes, have been very successful for modeling vegetation parameters from captured spectra, however their performance is highly dependent on the amount of available ground truth. This is a problem because it is generally expensive to obtain ground truth information due to difficulties and costs associated with sample collection and analysis. In this paper, we present two Gaussian processes based approaches for improving the accuracy of vegetation parameter retrieval when ground truth is limited. The first is the adoption of covariance functions based on well-established metrics, such as, spectral angle and spectral correlation, which are known to be better measures of similarity for spectral data owing to their resilience to spectral variabilities. The second is the joint modeling of related vegetation parameters by multitask Gaussian processes so that the prediction accuracy of the vegetation parameter of interest can be improved with the aid of related vegetation parameters for which a larger set of ground truth is available. We experimentally demonstrate the efficacy of the proposed methods against existing approaches on three real-world hyperspectral datasets and one synthetic dataset.
RF Energy Harvesting Wireless Communications: RF Environment, Device Hardware and Practical Issues
Authors: Luo Yu , Pu Lina , Wang Guodong , Zhao Yanxiao
Published: July 2019

Radio frequency (RF) based wireless power transfer provides an attractive solution to extend the lifetime of power-constrained wireless sensor networks. Through harvesting RF energy from surrounding environments or dedicated energy sources, low-power wireless devices can be self-sustaining and environment-friendly. These features make the RF energy harvesting wireless communication (RF-EHWC) technique attractive to a wide range of applications. The objective of this article is to investigate the latest research activities on the practical RF-EHWC design. The distribution of RF energy in the real environment, the hardware design of RF-EHWC devices and the practical issues in the implementation of RF-EHWC networks are discussed. At the end of this article, we introduce several interesting applications that exploit the RF-EHWC technology to provide smart healthcare services for animals, wirelessly charge the wearable devices, and implement 5G-assisted RF-EHWC.
Formal Education of Asylum Seeker Children in Belgrade, Serbia: Expanded Meaning of Social Inclusion
Authors: Jovanović Teodora
Published: July 2019

Formal education of asylum seeker children in Serbia officially started in September 2017, when the consequences of European border regime became more obvious. In spite of the official attitude that Serbia is a transit country, there was a pressure to improve integration policies regarding migration, since a lot of people wanting to seek asylum in European Union have remained in Serbia for months. Educational inclusion is the aspect of asylum seekers’ integration in which the most resources and effort was invested. In this article, I try to define the notions of social and educational inclusion in relation to integration policies of asylum seekers coming from different cultural backgrounds and in relation to existing educational inclusion policies.
Soil Erosion Spatial Prediction using Digital Soil Mapping and RUSLE methods for Big Sioux River Watershed
Authors: Taghizadeh-Mehrjardi Ruhollah , Bawa Arun , Kumar Sandeep , Zeraatpisheh Mojtaba , Amirian-Chakan Alireza , Akbarzadeh Ali
Published: July 2019

A recent conversion of the grasslands to cropland degrading the soil quality (SQ), and impacting the soil erosion and crop productivity in the West Corn Belt (WCB) of the USA. The current study was conducted to estimate the spatial distribution of soil erosion at Big Sioux River (BSR) watershed scale using the Geographical Information System (GIS)-enabled Revised Universal Soil Loss Equation (RUSLE). Spatial data such as weather, a digital elevation model (DEM), land use maps and soils were used for assessment of soil erosion was downloaded from the easily available online sources. Data showed that about 7% of grassland acreage reduced from 2008 (24%) to 2015 (17%), whereas, about 7.4% of cropland acreage increased from 2008 (64.6%) to 2015 (72%) in the BSR watershed. This grassland conversion to cropland increased the soil erosion (estimated using the RUSLE model) from 12.2 T ha−1 year−1 in 2008 to 14.8 T ha−1 year−1 in 2015. The present study concludes that grassland conversion to cropland in the BSR watershed increased the soil erosion, therefore, management practices essential to be applied to reduce the erosion risk and various other ecosystem services.
“Trachytes” from Sardinia: Geoheritage and Current Use
Authors: Careddu Nicola , Grillo Silvana Maria
Published: July 2019

Sardinia was affected by an intense igneous activity which generated calc-alkaline products during the Oligo-Miocene period. The volcanic substance shows large variations, ranging from pyroclastic flow deposits, lava flows and domes. By composition, the deposits are all primarily dacites and rhyolites, with subordinate andesites and very scarce basalts. The rhyolite lavas show porphyritic and ash-flow tuffs. Ignimbrite structures are found in the dacitic domes and rhyolitic lavas. These rocks—commercially known as “Trachytes of Sardinia”—used to be quarried in all historical provinces, mainly in the central part of the island to be used as ornamental and building stone. They continue to be commonly used nowadays, but their use dates back to the prehistoric age. They are easily found in many nuraghi, “domus de janas”, holy wells, Roman works (mosaics, paving, roads, bridges), many churches built in Sardinia and practically in all kinds of structural elements in public and private buildings, such as walls, houses, and bridges. Contrary to the granitoid rocks, whose appearance is largely influenced by the mineralogical composition, the aesthetic feature of volcanic rocks is rather affected by the widest range of colors, structure and texture, i.e., shape, size and distribution of mineral components, porphyric index, etc. “Trachyte” is quarried opencast with the “single low step” method, with descending development, with prevalent use of double-disc sawing machines. Whenever the stone deposit allows higher steps, the chain cutting machine, in combination with diamond wire, becomes the preferred extraction solution. This study aims to at look Sardinian “trachytes” from a geoheritage perspective. After a geological-petrographic framework, the paper discusses the historical uses of “trachyte” in Sardinia. The current state of the art of “trachyte” quarrying, processing and usage in the Island is also described. An analysis of the “trachyte” production has been carried out. Finally, a consideration about how to enhance geotourism in the area is suggested.
Green Procurement Decisions with Carbon Leakage by Global Suppliers and Order Quantities under Different Carbon Tax
Authors: Kondo Rena , Kinoshita Yuki , Yamada Tetsuo
Published: July 2019

Manufactures have been pressed to reduce greenhouse gas (GHG) emissions by environmental regulations and policies. Towards to reduction of GHG emissions, a carbon tax has been already introduced in 40 countries. Owing to different carbon prices among countries, there are potential risks of carbon leakage, where manufacturers transfer production operations to the countries with lower taxes to pursue lower costs. Moreover, procurement costs and GHG emissions vary by country because of economic conditions and electric energy mixes. Therefore, total GHG emissions could be globally reduced if manufactures relocate their production bases or switch suppliers in the country with lower GHG emission levels. This study proposes a green procurement decision for the supplier selection and the order quantity for minimizing GHG emission and costs considering the different carbon taxes in different countries. First, a bill of materials for each part is constructed through the life cycle inventory database with the Asian international input/output tables for a case study. Second, a green procurement decision considering the different carbon prices is formulated using integer programming. Finally, the results, including carbon leakage, are analyzed from the viewpoint of manufacturers, governments, and global perspectives.
Corporate Social Responsibility and Financial Performance: A Quantile Regression Approach
Authors: Liu Nana , Liu Chuanzhe , Guo Quan , Da Bowen , Guan Linna , Chen Huiying
Published: July 2019

A prominent claim within the literature is that corporate social responsibility-disclosured firms are fundamentally more resilient to financial shocks, relative to firms that take no corporate social responsibility action. To test this, we examine the impact of corporate social responsibility (CSR) information disclosure on financial constraints (FC). Our sample is composed of A-share publicly listed firms from Shanghai and Shenzhen in China during 2013–2017. We find that CSR disclosure influences negatively financial constraints. The quantile regression results also indicate that the influences would more obvious when a company faces stronger financial constraints. Further, CSR disclosure influences negatively financial constraints in financially opaque firms, and the effect of financial opaque on the relationship strengthens when the company faces great financial constraints. After considering the problems of missing variables and endogenous, changing the level of CSR and FC measurement, using 2SLS and two-step GMM methods, the conclusion is still robust. However, the results should not be generalized, since the sample was based on 434 A-share publicly listed firms for 2013–2017. From the perspective of FC, this study contributes to the literature in the field of CSR and expands the empirical research on the economic consequences of CSR. It also can encourage enterprises to voluntarily disclose social responsibility information and it is of great significance to promote the stable development of the capital market and society.
Application of Roadway Backfill Mining in Water-Conservation Coal Mining: A Case Study in Northern Shaanxi, China
Authors: Yu Yihe , Ma Liqiang
Published: July 2019

The mining induced subsidence and strata deformation are likely to affect the stability of the aquiclude, resulting in loss of water resources in the mining area. In order to reduce the disturbance of coal mining to the overlying strata and to preserve the water resources in the coal mining area, the roadway backfill mining (RBM) method was trialed in Yuyang coal mine in Northern Shaanxi, China. Based on pressure arch theory and ultimate strength theory, a mechanical model was developed to analyze the stability of coal pillars. Then the maximum number of vacant roadways between the mining face and the backfilling face was determined according to the stability of coal pillar and filling body. The method to calculate aquiclude subsidence and deformation was also proposed. Furthermore, as indicated by FLAC3D numerical simulations, the maximum tensile stress subjected by the aquiclude was 0.14 MPa, which is smaller than its tensile strength; the horizontal deformation was 0.24 mm/m, which is also smaller than the critical deformation of failure. Field monitoring data demonstrated a maximum of 2.76 m groundwater level drop in the mining area after mining. The groundwater level was determined to be 4.45~10.83 m below surface, ensuring the normal growth of surface vegetation and realizing the water-conservation coal mining (WCCM).
Ecological Urban Planning and Design: A Systematic Literature Review
Authors: Heymans Angela , Breadsell Jessica , Morrison Gregory , Byrne Joshua , Eon Christine
Published: July 2019

Urbanization is a defining feature of the modern age, yet the current model of urban development profoundly alters the natural environment, often reducing biodiversity and ultimately threatening human wellbeing. An ecologically based urban planning and design paradigm should consider a more harmonious relationship. Through a systematic literature review of 57 papers, this research identified relevant concepts and theories that could underpin this new paradigm. It revealed a noticeable increase in academic interest in this subject since 2013 and the development of concepts and theories that reflect a more holistic socio-ecological systems approach to urban planning and design based on a transdisciplinary integration and synthesis of research. Seven main themes underpin the academic literature: ecosystem services, socio-ecological systems, resilience, biodiversity, landscape, green infrastructure, as well as integrated and holistic approaches. Six of these can be organised into either a sustainability stream or a spatial stream, representing the foundations of a potential new ecological urban planning and design paradigm that applies sustainability-related concepts in a spatial setting. The final theme, integrated and holistic, includes concepts that reflect the fundamental characteristics of this new paradigm, which can be termed ‘urban consonance’.
Sustainable Development of Coastal Food Services
Authors: Iamkovaia Mariia , Arcila Manuel , Cardoso Martins Filomena , Izquierdo Alfredo
Published: July 2019

Coastal food services are an important segment within ‘sea and sun’ tourism. They have a direct impact on the environment from liquid and solid waste generation, air contamination, and excessive energy and water consumption. Mass tourism and the contemporary threat of climate change enhance the anthropogenic intrusion, especially in vulnerable coastal zones. To prevent overexploitation of the coastal zones, the adaptation of the sustainable principles by coastal stakeholders is an urgent matter. Thus, this study aims to design a model of sustainable development for restaurants and to examine the level of its adoption by seaside restaurant owners in two touristic beach areas of Cadiz province, Spain. A questionnaire was performed during the high summer season in 2018. The obtained data was analysed by IBM SPSS software. The survey results showed that the model of sustainable development has been poorly adopted by restaurant managers. Foreign managers of international restaurants are less involved in the adoption of the sustainable model in comparison to Spanish restaurant owners. Moreover, restaurants that have been opened more than 10–20 years provide a more sustainable way of business operation in comparison with newly established food service organizations.
Mechanical Behavior of Hot-Mix Asphalt Made with Recycled Concrete Aggregates from Construction and Demolition Waste: A Design of Experiments Approach
Authors: Galan Juan J. , Silva Luís M. , Pérez Ignacio , Pasandín Ana R.
Published: July 2019

The present work is a re-evaluation of previous research on the durability of hot-mix asphalt made with recycled concrete aggregates from construction and demolition waste (CDW) with a different approach. Response surface methodology (RSM) was used to conduct this study. The kind of natural aggregates (schist and calcite-dolomite), the recycled concrete aggregates percentage (0%, 20%, 40% and 60%) and the water saturation (0% and 100%) were the pertinent factors for this methodology. Indirect tensile stress (ITS) was determined in mixtures fabricated with 0%, 20%, 40% and 60% recycled concrete aggregates. According to the results, the ITS of the bituminous mixtures increases as the percentage of recycled concrete aggregate increases. This behavior is more significant when calcite-dolomite is used as a natural aggregate. Water saturation has the same influence in both natural aggregates. The indirect tensile strength ratio (ITSR) was calculated to evaluate the stripping potential. According to the Spanish specifications, the results suggest that the percentage of CDW that can be used for hot mixes is 17% when schist is used as natural aggregate and 14% for calcite-dolomite.