Rapid dose rate estimation for trapped charge dating using pXRF measurements of potassium concentration
Authors: Woor Sam , D'Arcy Mitch K. , Lian Olav B. , Schaarschmidt Maria , Durcan Julie A. 
Published: January 2025

Abstract. Quantifying environmental radiation dose rates is an essential step in age calculation using trapped charge dating methods. A means of rapid dose rate estimation would therefore be useful for a variety of reasons, especially in contexts where rapid equivalent dose estimates are available. For instance, for informing sampling strategy, providing initial age estimates, or supporting portable luminescence studies. However, high-precision methods often used for calculating dose rates are typically time consuming and expensive and are impractical for such ‘range-finder’ applications. Portable X-ray fluorescence (pXRF) offers a rapid means of measuring the Potassium (K) concentration of sediment, although the other radionuclides typically used to calculate dose rates (Uranium (U) and Thorium (Th)) fall beneath its detection limits at the quantities at which they are usually present in sediments. In this study, we investigate whether pXRF measurements of K concentration alone can be used to accurately estimate total environmental dose rates. A large, global training dataset of 1473 radionuclide samples is used to generate a set of linear relationships between (1) K concentration and external beta dose rate; (2) external beta and gamma dose rates; and (3) external gamma and alpha dose rates. We test the utility of these relationships by measuring the K contents of 67 sediment samples with independent high-precision radionuclide data from a variety of contexts using pXRF. The resulting K concentrations are then converted to external dose rate estimates using the training equations. A simplified set of attenuation parameters are used to correct infinite matrix dose rate estimates, and these are combined with cosmic ray and internal contributions to rapidly calculate total environmental dose rates for a range of theoretical, common luminescence dating scenarios (such as 180–250 μm quartz that has undergone etching). Results show that pXRF can accurately measure K concentrations in a laboratory setting. The training equations can predict external beta dose rates accurately based on K content alone, whilst external alpha dose rates are predicted less accurately. In combination, total estimated dose rates show good agreement with their counterparts calculated from high-precision methods, with 68–98 % of our results lying within ±20 % of unity depending on the scenario. We report better agreement for scenarios where alpha contributions are assumed to be negligible (e.g., in the case of etched, coarse-grained quartz or potassium feldspar). The use of simplified attenuation factors to correct estimated infinite matrix dose rates does not contribute significantly to resulting scatter, with uncertainties mostly resulting from the training equations. This study serves as a proof of concept that pXRF measurements, along with a set of linear equations and a simplified correction procedure, can be used to rapidly calculate range-finder environmental dose rates.