bluuebunny/crossref_metadata_2025 huggingface dataset:
Low-Platinum-Content Exchange-Coupled CoPt Nanoalloys with Enhanced Magnetic Properties
Authors: Basina Georgia , Alexandrakis Vasileios , Panagiotopoulos Ioannis , Niarchos Dimitrios , Devlin Eamonn , Gjoka Margarit , Hadjipanayis George C. , Tzitzios Vasileios
Published: March 2024

Bimetallic colloidal CoPt nanoalloys with low platinum content were successfully synthesized following a modified polyol approach. Powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), and transmission electron microscopy (TEM) studies were performed to estimate the crystal structure, morphology, and surface functionalization of the colloids, respectively, while the room-temperature magnetic properties were measured using a vibrating sample magnetometer (VSM). The particles exhibit excellent uniformity, with a narrow size distribution, and display strong room-temperature hysteretic ferromagnetic behavior even in the as-made form. Upon annealing at elevated temperatures, progressive formation and co-existence of exchange coupled, of both chemically ordered and disordered phases significantly enhanced the room-temperature coercivity.
Nanostructured Pr-Rich CexPr1-xO2-δ Mixed Oxides for Diesel Soot Combustion: Importance of Oxygen Lability
Authors: Mekki Imene , Grzybek Gabriela , Kotarba Andrzej , García-García Avelina
Published: March 2024

Soot combustion experiments with 5%O2/He were conducted using model soot, and four distinct compositions of CexPr1-xO2-δ oxides of varying nominal cerium compositions (x = 0, 0.2, 0.3, and 1) were prepared. The catalyst samples were comprehensively characterized using techniques such as XRD, Raman spectroscopy, HR-TEM, N2 adsorption at −196 °C, XPS, O2-TPD, H2-TPR, and work function measurements. The Pr-rich compositions, ranging from Ce0.3Pr0.7O2-δ to PrO2-δ, resulted in a significant increase in the total evolved O2 amounts and enhanced catalyst reducibility. However, a decrease in the textural properties of the catalysts was noted, which was particularly important for the pure praseodymia under the synthesis route conducted. The catalytic activity was investigated under the two following contact modes of mixing between soot and catalyst: loose and tight. The results revealed that the catalytic performance is associated with the surface contact in tight contact mode and with the combination of surface/subsurface/bulk oxygen mobility and the BET surface area in loose contact mode. Notably, the temperatures estimated at 10% and 50% of the conversion (T10 and T50) parameters were achieved at much lower temperatures than the uncatalyzed soot combustion, even under loose contact conditions. Specifically, the 50% conversion was achieved at 511 °C and 538 °C for Ce0.3Pr0.7O2 and Ce0.2Pr0.8O2, respectively. While no direct correlation between catalytic activity and work function was observed, a significant relationship emerges between work function values and the formation of oxygen vacancies, whatever the conditions used for these measurements. On the other hand, the ability to generate a high population of oxygen vacancies at low temperatures, rather than the direct activation of gas-phase O2, influences the catalytic performance of Pr-doped ceria catalysts, highlighting the importance of surface/subsurface oxygen vacancy generation, which was the parameter that showed a better correlation with the catalytic activity, whatever the soot conversion value or the mode of contact considered.
Investigating the Influence of Diverse Functionalized Carbon Nanotubes as Conductive Fibers on Paper-Based Sulfur Cathodes in Lithium–Sulfur Batteries
Authors: Ren Xuan , Wu Haiwei , Xiao Ya , Wu Haoteng , Wang Huan , Li Haiwen , Guo Yuchen , Xu Peng , Yang Baohong , Xiong Chuanyin
Published: March 2024

Lithium–sulfur (Li–S) batteries are expected to be one of the next generations of high-energy-density battery systems due to their high theoretical energy density of 2600 Wh kg−1. Embracing the trends toward flexibility, lightweight design, and cost-effectiveness, paper-based electrodes offer a promising alternative to traditional coated cathodes in Li–S batteries. Within paper-based electrodes, conductive fibers such as carbon nanotubes (CNTs) play a crucial role. They help to form a three-dimensional network within the paper matrix to ensure structural integrity over extended cycling while mitigating the shuttle effect by confining sulfur within the cathode. Herein, we explore how variously functionalized CNTs, serving as conductive fibers, impact the physical and electrochemical characteristics of paper-based sulfur cathodes in Li–S batteries. Specifically, graphitized hydroxylated carbon nanotubes (G-CNTs) exhibit remarkable capacity at low currents owing to their excellent conductivity and interaction with lithium polysulfide (LiPS), achieving the highest initial specific capacity of 1033 mAh g−1 at 0.25 C (1.1 mA cm−2). Aminated multi-walled carbon nanotubes (NH2-CNTs) demonstrate an enhanced affinity for LiPS due to the -NH2 groups. However, the uneven distribution of these fibers may induce electrode surface passivation during charge–discharge cycles. Notably, hydroxylated multi-walled carbon nanotubes (OH-CNTs) can establish a uniform and stable 3D network with plant fibers, showcasing superior mechanical properties and helping to mitigate Li2S agglomeration while preserving the electrode porosity. The paper-based electrode integrated with OH-CNTs even retains a specific capacity of approximately 800 mAh g−1 at about 1.25 C (5 mA cm−2), demonstrating good sulfur utilization and rate capacity compared to other CNT variants.
Risk of Excess Maternal Folic Acid Supplementation in Offspring
Authors: Xu Xiguang , Zhang Ziyu , Lin Yu , Xie Hehuang
Published: March 2024

Folate, also known as vitamin B9, facilitates the transfer of methyl groups among molecules, which is crucial for amino acid metabolism and nucleotide synthesis. Adequate maternal folate supplementation has been widely acknowledged for its pivotal role in promoting cell proliferation and preventing neural tube defects. However, in the post-fortification era, there has been a rising concern regarding an excess maternal intake of folic acid (FA), the synthetic form of folate. In this review, we focused on recent advancements in understanding the influence of excess maternal FA intake on offspring. For human studies, we summarized findings from clinical trials investigating the effects of periconceptional FA intake on neurodevelopment and molecular-level changes in offspring. For studies using mouse models, we compiled the impact of high maternal FA supplementation on gene expression and behavioral changes in offspring. In summary, excessive maternal folate intake could potentially have adverse effects on offspring. Overall, we highlighted concerns regarding elevated maternal folate status in the population, providing a comprehensive perspective on the potential adverse effects of excessive maternal FA supplementation on offspring.
Dietary Factors and the Risk of Depression among Women with Polycystic Ovary Syndrome
Authors: Łagowska Karolina , Bajerska Joanna , Pieczyńska-Zając Joanna Maria
Published: March 2024

This study aimed to assess the association between dietary factors and depression in a group of polycystic ovary syndrome (PCOS) women and to evaluate potential interactions and the mediating role of BMI in this relationship. One hundred and sixteen women with PCOS were asked to complete the Dietary Habits and Nutrition Beliefs Questionnaire and the manual for developing of nutritional data (KomPAN questionnaire) and the Beck Depression Inventory. The population was divided into two groups: (1) not at risk of depression (ND), n = 61, and (2) at risk of depression (RD), n = 55. Significantly higher BMI values were observed in the RD group than in the ND group. In the RD group, the intake of vegetables and legumes was lower than in the LD group, but the consumption of sweet beverages and energy drinks was higher. Consumption of vegetables and legumes at least twice per day is known to be associated with a 62% lower probability of the risk of depression in PCOS women. Furthermore, women with overweight and obesity have a 5.82 times greater chance of depression than women with normal body weight. Our findings show that there is a significant association between certain dietary factors, BMI, and symptoms of depression in PCOS women.
Reduction in Placental Metal and Metalloid in Preeclampsia: A Case–Control Study
Authors: Hao Yanhui , Yu Wen , Wu Jiaying , Yue Yingyu , Wu Yanting , Huang Hefeng , Wu Weibin
Published: March 2024

Preeclampsia is a primary placental disorder, with impaired placental vascularization leading to uteroplacental hypoperfusion. We aimed to investigate differences in metal and metalloid content between the placentas of women with preeclampsia and healthy controls. This was a case–control study in 63 women with preeclampsia and 113 healthy women. Clinical data were obtained from medical records. Inductively coupled plasma mass spectrometry (ICP-MS) was used to measure the placental metals and metalloids content. Compared with healthy control subjects, preeclampsia was associated with a significantly lower concentration of essential elements (magnesium, calcium, iron, copper, zinc, and selenium) in the placental tissue. After multivariable adjustment, an interquartile range (IQR) increase in selenium concentration was associated with a reduced risk of preeclampsia with an OR of 0.50 (95% CI: 0.33–0.77). The joint effects of multiple selected metals and metalloids were associated with a reduced risk of preeclampsia. The lower placental magnesium, chromium, iron, zinc, and selenium concentrations of preeclampsia cases indicate a potential link to its pathogenesis. It also provides an intriguing avenue for future research in revealing the underlying mechanisms and potential intervention strategies for preeclampsia.
Current Knowledge of Enterococcal Endocarditis: A Disease Lurking in Plain Sight of Health Providers
Authors: Nappi Francesco
Published: March 2024

Enterococcus faecalis is a bacterial pathogen that can cause opportunistic infections. Studies indicate that initial biofilm formation plays a crucial regulatory role in these infections, as well as in colonising and maintaining the gastrointestinal tract as a commensal member of the microbiome of most land animals. It has long been thought that vegetation of endocarditis resulting from bacterial attachment to the endocardial endothelium requires some pre-existing tissue damage, and in animal models of experimental endocarditis, mechanical valve damage is typically induced by cardiac catheterisation preceding infection. This section reviews historical and contemporary animal model studies that demonstrate the ability of E. faecalis to colonise the undamaged endovascular endothelial surface directly and produce robust microcolony biofilms encapsulated within a bacterially derived extracellular matrix. This report reviews both previous and current animal model studies demonstrating the resilient capacity of E. faecalis to colonise the undamaged endovascular endothelial surface directly and produce robust microcolony biofilms encapsulated in a bacterially derived extracellular matrix. The article also considers the morphological similarities when these biofilms develop on different host sites, such as when E. faecalis colonises the gastrointestinal epithelium as a commensal member of the common vertebrate microbiome, lurking in plain sight and transmitting systemic infection. These phenotypes may enable the organism to survive as an unrecognised infection in asymptomatic subjects, providing an infectious resource for subsequent clinical process of endocarditis.
Assessment of Fertility Dynamics and Nutritional Quality of Potato Tubers in a Compost-Amended Mars Regolith Simulant
Authors: Caporale Antonio Giandonato , Paradiso Roberta , Palladino Mario , Arouna Nafiou , Izzo Luana , Ritieni Alberto , De Pascale Stefania , Adamo Paola
Published: March 2024

Mars exploration will foresee the design of bioregenerative life support systems (BLSSs), in which the use/recycle of in situ resources might allow the production of food crops. However, cultivation on the poorly-fertile Mars regolith will be very challenging. To pursue this goal, we grew potato (Solanum tuberosum L.) plants on the MMS-1 Mojave Mars regolith simulant, pure (R100) and mixed with green compost at 30% (R70C30), in a pot in a cold glasshouse with fertigation. For comparison purposes, we also grew plants on a fluvial sand, pure (S100) and amended with 30% of compost (S70C30), a volcanic soil (VS) and a red soil (RS). We studied the fertility dynamics in the substrates over time and the tuber nutritional quality. We investigated nutrient bioavailability and fertility indicators in the substrates and the quality of potato tubers. Plants completed the life cycle on R100 and produced scarce but nutritious tubers, despite many critical simulant properties. The compost supply enhanced the MMS-1 chemical/physical fertility and determined a higher tuber yield of better nutritional quality. This study demonstrated that a compost-amended Mars simulant could be a proper substrate to produce food crops in BLSSs, enabling it to provide similar ecosystem services of the studied terrestrial soils.
Morphology and Molecular Phylogeny of the Genus Stigeoclonium (Chaetophorales, Chlorophyta) from China, Including Descriptions of the Pseudostigeoclonium gen. nov.
Authors: Liu Benwen , Lan Qiumei , Dai Qingyu , Zhu Huan , Liu Guoxiang
Published: March 2024

Stigeoclonium is a genus of green algae that is widely distributed in freshwater habitats around the world. The genus comprises species with variously developed prostrates and erect systems of uniseriate branched filaments and grows attached to a wide range of different surfaces. It holds significant promise for applications in water quality indicators, sewage treatment, and the development of high-value-added products. Nevertheless, our comprehension of Stigeoclonium remains unclear and perplexing, particularly regarding its fundamental systematic taxonomy. Recent molecular analyses have revealed that the morphologically well-defined genus Stigeoclonium is polyphyletic and requires taxonomic revision. Phylogenetic analysis based on a single molecular marker and limited samples is insufficient to address the polyphyletic nature of Stigeoclonium. In the present study, 34 out of 45 strains of Stigeoclonium were newly acquired from China. Alongside the morphological data, a concatenated dataset of three markers (18S rDNA + ITS2 + tufA) was utilized to determine their molecular phylogeny. The phylogenetic analysis successfully resolved the broadly defined Stigeoclonium into three robustly supported clades (Stigeoclonim tenue clade, S. farctum clade, and S. helveticum clade). The morphological characteristics assessment results showed that the cell type of the main axis-producing branch, considered a crucial morphological characteristic of the Stigeoclonium taxonomy, did not accurately reflect the real phylogeny of the genus. A new taxonomical classification of the genus Stigeoclonium was proposed based on zoospores’ germination types, which aligned well with the phylogenetic topologies. Species where zoospores showed erect germination (S. helveticum clade) formed a distinct monophyletic clade, clearly separated from the other two clades, with zoospores showing prostrate germination or pseudo-erect germination. Consequently, a new genus, Pseudostigeoclonium gen. nov., is suggested to include all species in the broadly defined Stigeoclonium with zoospores with erect germination. The taxonomic diversity is supported by distinctive morphological differences and phylogenetic divergence within the broadly defined Stigeoclonium identified in this study. Further evaluation of the genus Stigeoclonium is necessary, especially via examining additional specimens and re-evaluating morphological characters under precisely defined laboratory conditions.
Experimental Global Warming Potential-Weighted Specific Stiffness Comparison among Different Natural and Synthetic Fibers in a Composite Component Manufactured by Tailored Fiber Placement
Authors: Cáceres Gustavo de Abreu , Lisbôa Tales de Vargas , Elschner Cindy , Spickenheuer Axel
Published: March 2024

This work aims to evaluate experimentally different fibers and resins in a topologically optimized composite component. The selected ones are made of carbon, glass, basalt, flax, hemp, and jute fibers. Tailored Fiber Placement (TFP) was used to manufacture the textile preforms, which were infused with two different epoxy resins: a partly biogenic and a fully petro-based one. The main objective is to evaluate and compare the absolute and specific mechanical performance of synthetic and natural fibers within a component framework as a base for improving assessments of sustainable endless-fiber reinforced composite material. Furthermore, manufacturing aspects regarding the different fibers are also considered in this work. In assessing the efficiency of the fiber-matrix systems, both the specific stiffness and the specific stiffness relative to carbon dioxide equivalents (CO2eq.) as measures for the global warming potential (GWP) are taken into account for comparison. The primary findings indicate that basalt and flax fibers outperform carbon fibers notably in terms of specific stiffness weighted by CO2eq.. Additionally, the selection of epoxy resin significantly influences the assessment of sustainable fiber-plastic composites.
Photopolymer Holographic Lenses for Solar Energy Applications: A Review
Authors: Alfaro Eder , Lloret Tomás , Vilardy Juan M. , Bastidas Marlón , Morales-Vidal Marta , Pascual Inmaculada
Published: March 2024

Holographic lenses (HLs) are part of holographic optical elements (HOE), and are being applied to concentrate solar energy on a focal point or focal line. In this way, the concentrated energy can be converted into electrical or thermal energy by means of a photovoltaic cell or a thermal absorber tube. HLs are able to passively track the apparent motion of the sun with a high acceptance angle, allowing tracking motors to be replaced, thus reducing the cost of support structures. This article focuses on a review of the materials used in the recording of a holographic lens (HL) or multiple HLs in photovoltaic and/or concentrating solar collectors. This review shows that the use of photopolymers for the recording of HLs enables high-performance efficiency in physical systems designed for energy transformation, and presents some important elements to be taken into account for future designs, especially those related to the characteristics of the HL recording materials. Finally, the article outlines future recommendations, emphasizing potential research opportunities and challenges for researchers entering the field of HL-based concentrating solar photovoltaic and/or concentrating solar thermal collectors.
A New Sight of Ozone Usage in Textile: Improving Flame Retardant Properties
Authors: Eren Semiha , Yiğit İdil , Kutlay Kadriye , Kaya Zehra , Basrık Cansu , Eren Hüseyin Aksel
Published: March 2024

Ozone, widely recognized as an environmentally friendly gas, is extensively used in various textile industry applications. These include pre-treatment processes like bleaching and desizing, as well as creating pattern and vintage effects, wastewater clarification, and surface modification. This study focuses on ozone as a novel solution to a specific challenge: addressing the reduction in flame retardancy properties experienced by flame-retardant (FR) polyester fabrics during post-treatment processes in the production line. Experimentation involved subjecting the fabrics to ozonation and exploring different combinations of ozone flow rates and treatment durations. Mechanical and functional properties of the fabrics were examined, with flammability tested according to International Maritime Organization (IMO) standards. Notably, treatment with a 5 L/min ozone flow rate, a 7.01 g/h ozone concentration ratio, and a duration of 10 min showed significant improvements in IMO values, ensuring compliance with required standards. Furthermore, treated samples underwent comprehensive tests for fastness and strength, yielding results within acceptable ranges. Fourier-transform infrared (FT-IR) and thermogravimetric analysis (TGA) measurements were conducted to evaluate the impact of ozonation. FT-IR results indicated that the presence of C-H groups associated with dyestuff contributed to decreased flame retardancy in the original fabric post-dyeing. However, these groups were effectively eliminated through ozonation, thereby enhancing the fabric’s flame retardancy.
From Fathers to Fathers—Telephone-Based Peer Support: A Feasibility Study
Authors: Andersson Ewa , Espinosa Lisa , Wells Michael B.
Published: March 2024

Background: Men can struggle with adapting to their new roles as they transition into fatherhood. While social support has been shown to be effective at aiding this transition, little research has focused on the implementation of, and satisfaction with, telephone-based peer support for new fathers. Aims: This qualitative study aimed to investigate the implementation of, and satisfaction with, a telephone-based peer support program for new fathers. Methods: A qualitative study with 13 interviews of first-time fathers and peers was analysed using content analysis, in accordance with Elo and Kyngäs. Individual interviews were conducted using a semi-structured interview guide that lasted between 30–45 min. Results: Two themes emerged from the fathers’ interviews (n = 6): (1) conditions that affect the telephone support experience; and (2) the importance of support. The fathers appreciated the confirmation stories shared by their peers, as these stories served as valuable examples that they could adapt and incorporate into their own parenting approaches. Two themes emerged from the peer interviews (n = 7): (1) peers’ own role and experience; and (2) the Importance of listening to fathers. Peers felt appreciated and acted like role models for new fathers, helping them to adjust to parenting life. Study limitations: The results may not transfer to multi-time fathers. Conclusions: The findings of this study provide valuable insights into the potential benefits and challenges of implementing a telephone-based peer support program for first-time fathers, which could further inform similar interventions.
Potential Environmental Impacts of a Hospital Wastewater Treatment Plant in a Developing Country
Authors: Khan Muhammad Tariq , Ahmad Riaz , Liu Gengyuan , Zhang Lixiao , Santagata Remo , Lega Massimiliano , Casazza Marco
Published: March 2024

Assessing the quality of a hospital wastewater treatment process and plant is essential, especially if the presence of chemical and biological toxic compounds is considered. There is less literature on hospital wastewater treatment in developing countries because of a lack of managerial awareness and stakeholder cooperation, accompanied by the limited capacity of investment meant to upgrade the existing infrastructures. Limited access to data further hampers the reliable analysis of hospital wastewater treatment plants (WWTPs) in developing countries. Thus, based on the possibility of collecting a sufficient amount of primary (i.e., field) data, this study performed an assessment of the potential impacts generated by the WWTP of Quaid-Azam International Hospital in Islamabad (Pakistan) considering its construction and operational phases. The major identified impacts were attributed to the energy mix used to operate the plant. Marine ecotoxicity was the most impactful category (34% of the total potential impacts accounted for), followed by human carcinogenic toxicity (31%), freshwater toxicity (18%), terrestrial ecotoxicity (7%), and human non-carcinogenic toxicity (4%). An analysis of potential impacts was combined with an assessment of potential damage according to an endpoint approach. In particular, the endpoint analysis results indicated that human health damage (quantified as DALY) was mainly dependent on the “fine PM (particulate matter) formation” category (51%), followed by “global warming and human health” (43%). Other categories related to human health impacts were human carcinogenic toxicity (3%), water consumption (2%), and human non-carcinogenic toxicity (1%). The other impact categories recorded a percentage contribution lower than 1%. With respect to ecosystem damage, “global warming and terrestrial ecosystems” played a major role (61%), followed by terrestrial acidification (24%), ozone formation (10%), water consumption (5%), and freshwater eutrophication (1%). This study’s findings support an increase in awareness in the hospital management board while pointing out the need to further implement similar studies to improve the quality of decision-making processes and to mitigate environmental impacts in more vulnerable regions. Finally, this research evidenced the need to overcome the existing general constraints on data availability. Consequently, further field work, supported by hospital managers in developing countries, would help in enhancing managerial procedures; optimizing treatment plant efficiency; and facilitating the implementation of circular options, such as sludge management, that often remain unexplored.
The Response of Carbon Storage to Multi-Objective Land Use/Cover Spatial Optimization and Vulnerability Assessment
Authors: Jiang Yuncheng , Ouyang Bin , Yan Zhigang
Published: March 2024

The dynamic changes in land use/cover (LULC) significantly influence carbon storage, and assessing the vulnerability of carbon storage services in different basins is crucial for a comprehensive understanding of the impacts of human activities on ecosystems. The objective of this study is to propose a framework for optimizing LULC, simulating carbon storage, and assessing vulnerability by integrating the MOP, PLUS, and InVEST models. The results show that forests play a crucial role in enhancing carbon storage services in the Yangtze River Basin (YRB). Carbon storage in the upper reaches of the YRB is on the rise, counteracting the decrease in carbon storage caused by the expansion of built-up land. However, in the middle and lower reaches of the YRB, LULC has a negative impact on ecosystem carbon storage services. Under natural development scenarios, carbon storage is projected to decrease by 68.84 × 106 tons, leading to increased vulnerability of ecosystem carbon storage services. Under the scenario of ecological and economic balance, carbon storage is expected to increase by 97 × 106 tons. In the future, while restricting built-up land expansion, emphasis should be placed on expanding forest areas to more effectively enhance ecosystem services in basins.
Chlorobenzene Oxidation over Phosphotungstic-Acid-Coated Cerium Oxide: Synergistic Effect of Phosphotungstic and Cerium Oxide and Inhibition Mechanism of Sulfur Dioxide
Authors: Jiang Keyu , Dong Leyuan , Shen Qi , Wu Wei , Wu Xue , Mei Jian , Yang Shijian
Published: March 2024

Ce–based catalysts exhibit a poor stability and activity in chlorinated volatile organic compound (Cl–VOC) oxidation due to their rapid Cl poisoning. Herein, phosphotungstic acid (HPW) was coated on CeO2 to improve its activity and stability for chlorobenzene (CB) oxidation. The HPW coating not only promoted CB adsorption onto CeO2, but also provided Brønsted acid sites to CeO2 for Cl species removal as HCl, thus avoiding Cl poisoning. Hence, a synergistic effect of CeO2 and HPW on HPW/CeO2 was observed, resulting in superior CB oxidation activity and stability. Additionally, to improve the sulfur resistance of the catalyst, the inhibition mechanism of SO2 on CB oxidation by HPW/CeO2 was explored. HPW/CeO2 was prone to sulfation due to the formation of Ce2(SO4)3 from the reaction of SO2 and CeO2. Thus, the oxidation ability of HPW/CeO2; the amount of adsorption sites for CB adsorption; and the amounts of Ce4+ bonded with O2−, lattice oxygen species, and adsorbed oxygen species were decreased by SO2. Meanwhile, SO2 competed with CB for the adsorption sites on HPW/CeO2. Therefore, CB oxidation by HPW/CeO2 was remarkably restrained by SO2. The present work promotes further work on Cl–VOC removal by Ce-based catalysts for anti-SO2 poisoning modification in the future.
An Optimization Strategy for Provincial “Production–Living–Ecological” Spaces under the Guidance of Major Function-Oriented Zoning in China
Authors: Bao Shanju , Lu Lin , Zhi Junjun , Li Junfeng
Published: March 2024

The comprehensive evaluation of China’s major function-oriented zoning, grounded in scientific principles, has evolved into a nationwide initiative aimed at promoting regional coordinated sustainable development. A pivotal focus during this transitional phase is the optimization of a “production–living–ecological” spatial pattern within the main national functional areas. This involves a meticulous examination of the main functions, encompassing the distinct categories of production, living, and ecology, as well as prioritizing scenarios aligned with the functional orientation of towns, agriculture, and ecology in land-use simulation. Utilizing the PLUS model’s land-use simulation technology, a detailed investigation into Anhui Province’s main function orientation was conducted to achieve an optimal simulation of the “production–living–ecological” spatial pattern. The findings underscore the inadequacy of a singular scenario in attaining a global optimal solution for simulating the three spaces of production, living, and ecology. However, a gradual stabilization was observed in the overall quantitative structure and spatial transition frequency of these three spaces in Anhui Province. The continuous optimization of local spatial patterns and functional layouts was achieved through a multi-scenario optimization simulation based on main function orientation. Noteworthy improvements were identified in the optimization of the three spaces in specific regions: the northern part of Anhui, urban living spaces around Hefei and Wuhu, and ecological spaces in southern and western Anhui. Crucially, the simulation results align with the strategic goal orientation of the provincial main functional areas, the optimization trajectory of the “production–living–ecological” spatial pattern, and the strategic imperative for the coordinated and sustainable development of territorial space in Anhui Province. These findings furnish a robust scientific foundation for decomposing and transmitting the core indicators of provincial territorial spatial planning, as well as delineating the “three zones and three lines” in municipal territorial spatial planning.
Characterization and Risk Assessment of Nutrient and Heavy Metal Pollution in Surface Sediments of Representative Lakes in Yangxin County, China
Authors: Yang Xiaoqing , Leng Mingkai , Ge Xuguang , Wu Xiaodong , Liu Haoran , Lin Guiying , Huang Zhi , Chen Yuhan
Published: March 2024

Increased urbanization and industrialization globally have led to the widespread pollution of water bodies (e.g., lakes) by heavy metals (HMs) and nutrients. These pollutants accumulate in water and surface sediments, posing risks to both aquatic organisms and human health. In November 2022, surface sediment samples from three lakes—Lianhua Lake, Mati Lake, and North Lake—were collected to assess nutrient (nitrogen and phosphorous) and HM content. Total N (TN), total P (TP), and HM concentrations were analyzed. The pollution status was evaluated using comprehensive pollution index (FF) methods and the potential ecological risk index (RI) (Eri). The results were as follows: (1) Variations in nutrient and HM contents were observed among the three lakes. Lianhua Lake exhibited the highest average TN content (1600 mg/kg), while North Lake had the highest average TP content (2230 mg/kg). The average concentrations of Cd, Hg, and As in the surface sediment surpassed the soil background values of Hubei Province, reaching 1.41, 2.74, and 1.76 times the background values, respectively. Notably, Hg exceeded the standard in Lianhua Lake by 3.39 times, followed by North Lake (2.52 times) and Mati Lake (2.24 times). (2) The FF and potential Eri revealed that the average RI values for Mati Lake, North Lake, and Lianhua Lake were 106.88, 126.63, and 162.18, respectively. These indices categorized the ecological risk levels as moderate, while nutrient salts in the surface water reached a severe pollution level. (3) Correlation and PCA indicated that Cu, Pb, Cd, and Ni were linked to mineral smelting, aquaculture feed, and agricultural fertilizers. Hg and nutrient salts originated from atmospheric deposition of surrounding domestic waste water and traffic exhaust gases. Agricultural activities seemed to contribute to As concentration in the lakes, while Cr has its main origin in the weathering of the rock matrix.
Quantization of a New Canonical, Covariant, and Symplectic Hamiltonian Density
Authors: Chester David , Arsiwalla Xerxes D. , Kauffman Louis H. , Planat Michel , Irwin Klee
Published: March 2024

We generalize Koopman–von Neumann classical mechanics to poly symplectic fields and recover De Donder–Weyl’s theory. Compared with Dirac’s Hamiltonian density, it inspires a new Hamiltonian formulation with a canonical momentum field that is Lorentz-covariant with symplectic geometry. We provide commutation relations for the classical and quantum fields that generalize the Koopman–von Neumann and Heisenberg algebras. The classical algebra requires four fields that generalize spacetime, energy–momentum, frequency–wavenumber, and the Fourier conjugate of energy–momentum. We clarify how first and second quantization can be found by simply mapping between operators in classical and quantum commutator algebras.
Performance Analysis of ARIS-NOMA Systems under Cascade Rician Channels
Authors: Liu Xuliang , Yue Xinwei , Lu Zhiping , Hou Tianwei
Published: March 2024

Active reconfigurable intelligent surface (ARIS) has sparked more attention due to its capability to overcome the impact of double fading. This paper introduces using an ARIS to aid non-orthogonal multiple access (NOMA) communications over cascade Rician fading channels, where the direct links between the base station and users are seriously blocked. By applying ARIS, it can amplify the superposed signals to overcome the double pass loss effect caused by passive RIS. Both ARIS and NOMA can have synergistic impacts on sixth-generation communication systems. New approximated and asymptotic expressions in terms of outage probability and ergodic data rate of the k-th user are deduced for ARIS-NOMA systems. Based on asymptotic analytical results, we further calculate the diversity order and high signal-to-noise ratio slope of the k-th user. Finally, the system throughput of ARIS-NOMA is discussed in the delay-constrained transmission mode. Monte Carlo numerical results are performed to verify that: (1) the outage behaviors of ARIS-NOMA are better than that of ARIS-assisted orthogonal multiple access (OMA); (2) as the impact of thermal noise caused by ARIS becomes larger, the communication performance from the base station to ARIS, then to users, becomes worse; (3) the ARIS-NOMA systems have the ability to provide the improved ergodic data rate relative to ARIS-OMA.
A Functional Inequality and a New Class of Probabilities in the N-Person Red-and-Black Game
Authors: Fechner Włodzimierz , Słomian Maria
Published: March 2024

In this paper, we explore a model of an N-player, non-cooperative stochastic game, drawing inspiration from the discrete formulation of the red-and-black gambling problem, as initially introduced by Dubins and Savage in 1965. We extend upon the work of Pontiggia from 2007, presenting a main theorem that broadens the conditions under which bold strategies by all players can achieve a Nash equilibrium. This is obtained through the introduction of a novel functional inequality, which serves as a key analytical tool in our study. This inequality enables us to circumvent the restrictive conditions of super-multiplicativity and super-additivity prevalent in the works of Pontiggia and others. We conclude this paper with a series of illustrative examples that demonstrate the efficacy of our approach, notably highlighting its ability to accommodate a broader spectrum of probability functions than previously recognized in the existing literature.
Heterogeneity of Size and Toxin Distribution in Aggregatibacter actinomycetemcomitans Outer Membrane Vesicles
Authors: Nice Justin B , Collins Shannon M. , Agro Samuel M. J. , Sinani Anxhela , Moros Spencer D. , Pasch Leah M. , Brown Angela C.
Published: March 2024

Aggregatibacter actinomycetemcomitans is a Gram-negative bacterium associated with localized aggressive periodontitis as well as some systemic diseases. The strains of A. actinomycetemcomitans most closely associated with disease produce more of a secreted leukotoxin (LtxA) than isolates from healthy carriers, suggesting a key role for this toxin in disease progression. LtxA is released into the bacterial cytosol in a free form as well as in association with the surface of outer membrane vesicles (OMVs). We previously observed that the highly leukotoxic A. actinomycetemcomitans strain JP2 produces two populations of OMVs: a highly abundant population of small (<100 nm) OMVs and a less abundant population of large (>300 nm) OMVs. Here, we have developed a protocol to isolate the OMVs produced during each specific phase of growth and used this to demonstrate that small OMVs are produced throughout growth and lack LtxA, while large OMVs are produced only during the exponential phase and are enriched with LtxA. Our results indicate that surface-associated DNA drives the selective sorting of LtxA into large OMVs. This study provides valuable insights into the observed heterogeneity of A. actinomycetemcomitans vesicles and emphasizes the importance of understanding these variations in the context of bacterial pathogenesis.
Severe Pneumonia Caused by Respiratory Syncytial Virus and Adenovirus in Children from 2 to 24 Months at Children’s Hospital 1 in Ho Chi Minh City, Vietnam
Authors: Nguyen Suong Thi Thu , Tran Tuan Anh , Vo Giau Van
Published: March 2024

In Vietnam, due to the lack of facilities to detect respiratory viruses from patients’ specimens, there are only a few studies on the detection of viral pathogens causing pneumonia in children, especially respiratory syncytial virus (RSV) and adenovirus (Adv). Here, we performed a cross-sectional descriptive prospective study on 138 children patients from 2 to 24 months old diagnosed with severe pneumonia hospitalized at the Respiratory Department of Children’s Hospital 1 from November 2021 to August 2022. The number of patients selected in this study was based on the formula n = ([Z(1 − α/2)]2 × P [1 − P])/d2, with α = 0.05, p = 0.5, and d = 9%, and the sampling technique was convenient sampling until the sample size was met. A rapid test was used to detect RSV and Adv from the nasopharyngeal swabs and was conducted immediately after the patient’s hospitalization. Laboratory tests were performed, medical history interviews were conducted, and nasotracheal aspirates were collected for multiplex real-time PCR (MPL-rPCR) to detect viral and bacterial pathogens. The results of the rapid test and the MPL-rPCR in the detection of both pathogens were the same at 31.9% (44/138) for RSV and 8.7% (7/138) for Adv, respectively. Using MPL-rPCR, the detection rate was 21% (29/138) for bacterial pathogens, 68.8% (95/138) for bacterial–viral co-infections, and 6.5% (9/138) for viral pathogens. The results showed few distinctive traits between RSV-associated and Adv-associated groups, and the Adv group children were more prone to bacterial infection than those in the RSV group. In addition, the Adv group experienced a longer duration of treatment and a higher frequency of re-hospitalizations compared to the RSV group. A total of 100% of Adv infections were co-infected with bacteria, while 81.82% of RSV co-infected with bacterial pathogens (p = 0.000009). This study might be one of the few conducted in Vietnam aimed at identifying viral pathogens causing severe pneumonia in children.
A Novel IoT-Based Performance Testing Method and System for Fire Pumps
Authors: Zhang Shangcong , Li Yongfang , Chen Xuefei , Zhou Ruyi , Wu Ziran , Zarhmouti Taha
Published: March 2024

Fire pumps are the key components of water supply in a firefighting system. At present, there is a lack of fire water pump testing methods that intelligently detect faulty states. Existing testing approaches require manual operation, which leads to low efficiency and accuracy. To solve the issue, this paper presents an automatic and smart testing approach that acquires measurements of the flow, pressure, shaft power and efficiency from smart sensors via an IoT network, so that performance curves are obtained in the testing processes. An IoT platform is developed for data conversion, transmission and storage. The Discrete Fréchet Distance is applied to evaluate the similarities between the acquired performance curves and metric performance curves, to determine the working condition of the fire pump. The weights of the measurement dimensions for distance computation are optimized by the Genetic Algorithm to improve the distinction between normal and faulty performance curves. Finally, the experimental results show that the proposed method can completely detect faulty states and prove its high practicality for real firefighting systems.
Comparative Analysis of the Disinfection Efficiency of Steel and Polymer Surfaces with Aqueous Solutions of Ozone and Sodium Hypochlorite
Authors: Romanovski Valentin , Paspelau Andrei , Kamarou Maksim , Likhavitski Vitaly , Korob Natalia , Romanovskaia Elena
Published: March 2024

Disinfection of surfaces with various functional purposes is a relevant measure for the inactivation of microorganisms and viruses. This procedure is used almost universally, from water treatment facilities to medical institutions and public spaces. Some of the most common disinfectants the World Health Organization recommends are chlorine-containing compounds. Sodium and calcium hypochlorites are only used for disinfection of the internal surfaces of water treatment facilities. However, it is known that ozone is a more powerful oxidizing agent. This study compares the effectiveness of inactivating yeast-like fungi Candida albicans, Gram-positive Bacillus subtilis, and Gram-negative bacteria Escherichia coli with aqueous ozone and sodium hypochlorite solutions. This study used ozone solutions in water with a concentration of 0.5–1.5 mg/L and sodium hypochlorite solutions with an active chlorine concentration of 50–150 mg/L. Steel and polymeric plates were used as substrates. Comparison of the CT (concentration by time) criterion at the ratio of LD50 in NaClO to ozonated water shows that the smallest difference, around 100 times, was observed in the inactivation of Candida albicans. The maximum difference is up to 230 times in the inactivation of Bacillus subtilis.
Using Bacteriophages to Treat Resilient Bacteria Found in Produced Water
Authors: Sanchez-Rosario Ramon , Garcia Jesus , Rodriguez Vivian , Schug Kevin A. , Hildenbrand Zacariah L. , Bernal Ricardo A.
Published: March 2024

Numerous treatment modalities have been employed over the years to eradicate bacterial communities in industrial wastewater. Oxidizing agents and chemical additives, such as ozone, permanganate, glutaraldehyde, and chlorine, are effective in treating microbial contaminants that are typically found in domestic wastewater. However, the chemical complexity of water produced from fracking requires novel approaches, because the microbes have developed mechanisms to overcome typical disinfectants. In this work, we test the effectiveness of bacteriophages for the eradication of two model bacteria from produced water: Pseudomonas aeruginosa and Bacillus megaterium. These bacteria were grown in low salinity produced water and exposed to their corresponding phage. Overall, the total inactivation of the P. aeruginosa population was achieved, as well as the inactivation of B. megaterium. These promising results provide a potentially useful tool for bacterial elimination in overall PW treatment, at an industrial scale. Particularly, since phage treatment is a rapid and cost-effective alternative. Moreover, these results fall within the objectives proposed as part of the sustainable development goals adopted worldwide.
Flow Characteristics in Partly Vegetated Channels: An Experimental Investigation
Authors: Ben Meftah Mouldi , Bhutto Danish Ali , De Padova Diana , Mossa Michele
Published: March 2024

In this study, we attempt to experimentally investigate the flow turbulence structure in a partly vegetated channel. To achieve the objective of this study, we conducted extensive measurements of flow velocities within and outside the vegetated area, where the flow is fully developed. The experiments were conducted in a very large channel at the Coastal Engineering Laboratory of the Department of Civil, Environmental, Building Engineering and Chemistry at the Polytechnic University of Bari, Italy. The instantaneous three flow velocity components were accurately measured using a 3D-Acoustic Doppler Velocimeter (ADV)-Vectrino system at high frequency. Flow behaviors through the vegetated area, at the interface, and in the unobstructed area were analyzed via time-averaged velocities, turbulence intensity, correlation properties, spectral analysis, and vortex identification. Experimental results showed the development of three distinct characteristic flow zones: (i) a vegetated area of low streamwise velocity, high turbulence intensities, dominant inward interactions, and more intense power spectrum, (ii) a shear layer zone of increasing streamwise velocity, more enhanced transverse flow motion, exponential decrease in turbulence intensities, and frequent ejection and/or outward interaction events, and (iii) a free-stream zone of higher and almost constant streamwise velocity, lower turbulence intensities, frequent sweep and/or inward interaction events, and less intense streamwise power spectrum. The results brought further insights into the flow behaviors in these characteristic flow zones. The extensive and detailed measured data can provide a basis for improving and calibrating numerical simulations of partly vegetated channels.
Integrated Application of SWAT and L-THIA Models for Nonpoint Source Pollution Assessment in Data Scarce Regions
Authors: Zhang Peiyao , Chen Shuang (Sophia) , Dai Ying , Sekadende Baraka , Kimirei Ismael Aaron
Published: March 2024

Nonpoint source pollution (NPS) has become the most important reason for the deterioration of water quality, while relevant studies are often limited to African river and lake basins with insufficient data. Taking the Simiyu catchment of the Lake Victoria basin as the study area, we set up a NPS model based on the soil and water assessment tool (SWAT). Furthermore, the rationality of this model is verified with the field-measured data. The results manifest that: (1) the temporal variation of NPS load is consistent with the variation pattern of rainfall, the average monthly output of total nitrogen (TN) and total phosphorus (TP) in the rainy season was 1360.6 t and 336.2 t, respectively, while in the dry season was much lower, only 13.5 t and 3.0 t, respectively; (2) in view of spatial distribution among 32 sub-basins, TN load ranged from 2.051 to 24.288 kg/ha with an average load of 12.940 kg/ha, and TP load ranged from 0.263 to 8.103 kg/ha with an average load of 3.321 kg/ha during the 16-month study period; (3) Among the land use types, the cropland contributed the highest proportion of TN and TP pollution with 50.28% and 76.29%, respectively, while the effect of forest on NPS was minimal with 0.05% and 0.02% for TN and TP, respectively. (4) Moreover, the event mean concentration (EMC) values of different land use types have been derived based on the SWAT model, which are key parameters for the application of the long-term hydrological impact assessment (L-THIA) model. Therefore, this study facilitates applying the L-THIA model to other similar data-deficient catchments in view of its relatively lower data requirement.