bluuebunny/crossref_metadata_2025 huggingface dataset:
Extended π-Systems in Diimine Ligands in [Cu(P^P)(N^N)][PF6] Complexes: From 2,2′-Bipyridine to 2-(Pyridin-2-yl)Quinoline
Authors: Keller Sarah , Alkan-Zambada Murat , Prescimone Alessandro , Constable Edwin C. , Housecroft Catherine E.
Published: March 2020

We describe the synthesis and characterization of [Cu(POP)(1)][PF6], [Cu(POP)(2)][PF6], [Cu(xantphos)(1)][PF6], and [Cu(xantphos)(2)][PF6] in which ligands 1 and 2 are 2-(pyridin-2-yl)quinoline and 2-(6-methylpyridin-2-yl)quinoline, respectively. With 2,2'-bipyridine (bpy) as a benchmark, we assess the impact of the extended π-system on structural and solid-state photophysical properties. The single crystal structures of [Cu(POP)(2)][PF6], [Cu(xantphos)(1)][PF6], and [Cu(xantphos)(2)][PF6] were determined and confirmed a distorted tetrahedral copper(I) coordination environment in each [Cu(P^P)(N^N)]+ cation. The xanthene unit in [Cu(xantphos)(1)][PF6] and [Cu(xantphos)(2)][PF6] hosts the quinoline unit of 1, and the 6-methylpyridine group of 2. 1H NMR spectroscopic data indicate that these different ligand orientations are also observed in acetone solution. In their crystal structures, the [Cu(POP)(2)]+, [Cu(xantphos)(1)]+, and [Cu(xantphos)(2)]+ cations exhibit different edge-to-face and face-to-face π-interactions, but in all cases, the copper(I) centre is effectively protected by a ligand sheath. In [Cu(POP)(2)][PF6], pairs of cations engage in an efficient face-to-face π-stacking embrace, and we suggest that this may contribute to this compound having the highest photoluminescence quantum yield (PLQY = 21%) of the series. With reference to data from the Cambridge Structural Database, we compare packing effects and PLQY data for the complexes incorporating 2-(pyridin-2-yl)quinoline and 2-(6-methylpyridin-2-yl)quinoline, with those of the benchmark bpy-containing compounds. We also assess the effect that Cu⋯O distances in the {Cu(POP)} and {Cu(xantphos)} domains of [Cu(P^P)(N^N)][X] compounds have on solid-state PLQY values.
Structural, Spectroscopic, and Chemical Bonding Analysis of Zn(II) Complex [Zn(sal)](H2O): Combined Experimental and Theoretical (NBO, QTAIM, and ELF) Investigation
Authors: Usman Mohammad , Khan Rais Ahmad , Alsalme Ali , Alharbi Walaa , Alharbi Khadijah H. , Jaafar Mohammad H. , Abu Khanjer Maymonah , Tabassum Sartaj
Published: March 2020

The Zn(II) complex of salen-like scaffold [Zn(sal)](H2O) was synthesized and characterized by elemental analysis, IR, UV–Vis, and 1H-NMR spectroscopic techniques. The structure of complex was confirmed by single crystal X-ray diffraction studies. In the complex, Zn (II) was placed in the inner N2O2 compartment of the salen scaffold in square planar geometry and crystallized in the monoclinic space group P21/n. DFT and TDDFT calculations were performed to reproduce the experimentally observed structural and spectroscopic (IR and UV–vis) findings. The bonding of the Zn(II) framework in the [Zn(sal)](H2O) complex was explored in depth. The theoretical approaches employed were perturbation theory within the context of the natural bond orbital (NBO) framework, and quantum theory of atoms in molecule (QTAIM) and electron localization function (ELF) analysis. The study begins by delineating the difference between the NBO and QTAIM approaches. This paper thus exhibits the supportive nature of NBO theory and QTAIM in discussion of the bonding in the [Zn(sal)](H2O) complex, when both the methodologies are used in combination.
Functional Diversity Effects of Vegetation on Runoff to Design Herbaceous Hedges for Sediment Retention
Authors: Kervroëdan Léa , Armand Romain , Saunier Mathieu , Faucon Michel-Pierre
Published: March 2020

Background: Functional diversity effects on ecosystem processes, like on soil erosion, are not fully understood. Runoff and soil erosion in agricultural landscapes are reduced by the hydraulic roughness (HR) of vegetation patches, which furthers sediment retention. Vegetation with important stem density, diameters, leaf areas, and density impact the HR. A functional structure composed of these negatively correlated traits involved in the increase of the HR would constitute a positive effect of the functional diversity. Methods: Runoff simulations were undertaken on four mono-specific and two multi-specific communities, using herbaceous plant species from North-West Europe, presenting six contrasting aboveground functional traits involved in the HR increase. Results: An effect of dominant traits in the community was found on the HR, identified as the community-weighted leaf density. The non-additive effect of functional diversity on the HR could be explained by the presence of species presenting large stems in the communities with high functional diversity. Conclusion: We argued that functional diversity effect on the HR could change due to idiosyncratic effects of the plant traits, which would be influenced by soil properties, phylogeny diversity, and plant species interactions. These findings constitute an advancement in the understanding of plant trait assemblage on runoff and soil erosion processes.
Effects of Forest Composition and Disturbance on Arbuscular Mycorrhizae Spore Density, Arbuscular Mycorrhizae Root Colonization and Soil Carbon Stocks in a Dry Afromontane Forest in Northern Ethiopia
Authors: Birhane Emiru , Gebretsadik Kbrom Fissiha , Taye Gebeyehu , Aynekulu Ermias , Rannestad Meley Mekonen , Norgrove Lindsey
Published: March 2020

We investigated arbuscular mycorrhizal fungi (AMF) spore density and root colonization in three distinct dry Afromontane forest plant communities, representing differing levels of disturbance and soil properties. Soil and root samples were collected from sixty-five 50 × 50-m plots from four plant communities. We collected data for AMF spore density, AMF root colonization and soil organic carbon stocks in 0–25 and 25–50 cm soil depth ranges. AMF spore density, and root colonization differed significantly among plant communities. The least disturbed Juniperus procera–Maytenus senegalensis (Jupr-Mase) plant community, which contained high tree and shrub density, had the highest AMF spore density, root colonization and soil carbon stocks. The most disturbed Cadia purpurea–Opuntia ficus-indica (Capu-Opfi) community which contained the lowest tree and shrub density supported the lowest AMF spore density, root colonization and soil carbon stocks. There was no significant difference in spore density between the two soil depths, but AMF root colonization was significantly higher in the upper soil than in the subsoil (p < 0.001). The difference in soil properties was not uniform between plant communities. Conserving remnant dry Afromontane forests and restoring the degraded forests are critical to improve and maintain forest ecosystem functioning and sustain ecosystem services.
Multiple Regression Analysis and Frequent Itemset Mining of Electronic Medical Records: A Visual Analytics Approach Using VISA_M3R3
Authors: Abdullah Sheikh S. , Rostamzadeh Neda , Sedig Kamran , Garg Amit X. , McArthur Eric
Published: March 2020

Medication-induced acute kidney injury (AKI) is a well-known problem in clinical medicine. This paper reports the first development of a visual analytics (VA) system that examines how different medications associate with AKI. In this paper, we introduce and describe VISA_M3R3, a VA system designed to assist healthcare researchers in identifying medications and medication combinations that associate with a higher risk of AKI using electronic medical records (EMRs). By integrating multiple regression models, frequent itemset mining, data visualization, and human-data interaction mechanisms, VISA_M3R3 allows users to explore complex relationships between medications and AKI in such a way that would be difficult or sometimes even impossible without the help of a VA system. Through an analysis of 595 medications using VISA_M3R3, we have identified 55 AKI-inducing medications, 24,212 frequent medication groups, and 78 medication groups that are associated with AKI. The purpose of this paper is to demonstrate the usefulness of VISA_M3R3 in the investigation of medication-induced AKI in particular and other clinical problems in general. Furthermore, this research highlights what needs to be considered in the future when designing VA systems that are intended to support gaining novel and deep insights into massive existing EMRs.
Clinical Significance of Circulating Tumor Cells in Gastrointestinal Carcinomas
Authors: Konczalla Leonie , Wöstemeier Anna , Kemper Marius , Karstens Karl-Frederik , Izbicki Jakob , Reeh Matthias
Published: March 2020

The idea of a liquid biopsy to screen, surveil and treat cancer patients is an intensively discussed and highly awaited tool in the field of oncology. Despite intensive research in this field, the clinical application has not been implemented yet and further research has to be conducted. However, one component of the liquid biopsy is circulating tumor cells (CTCs) whose potential for clinical application is evaluated in the following. CTCs can shed from primary tumors to the peripheral blood at any time point during the progress of a malignant disease. Following, one single CTC can be the origin for distant metastasis at later cancer stage. Thus, CTCs have great potential to either be used in cancer diagnostics and patient stratification or to function as a target for new therapeutic approaches to stop tumor dissemination and metastasis at the very early beginning. Due to the biological fundamental role of CTCs in tumor progression, here, we provide an overview of CTCs in gastrointestinal cancers and their potential use in the clinical setting. In particular, we discuss the usage of CTC for screening and stratifying patients’ risk. Moreover, we will discuss the potential role of CTCs for treatment specification and treatment monitoring.
Testing the KAPS Model of Reading Comprehension in a Turkish Elementary School Context from Low Socioeconomic Background
Authors: Yildirim Kasim , Cetinkaya Fatih Cetin , Ates Seyit , Kaya Dudu , Rasinski Timothy
Published: March 2020

This correlational study aimed to explore the relations of background knowledge, automaticity (rate), prosody, and strategy use with reading comprehension (KAPS model of reading comprehension) in the written Turkish language context with 207 fourth grade students. Successful comprehension requires readers to make meaning out of what they read. Our KAPS model of reading comprehension hypothesizes relations of background knowledge, fluency components (rate and prosody), and strategy use with reading comprehension components (literal and deep) in the Turkish language and addresses the direct effects of these predictors on the reading comprehension of fourth grade students. The results showed that, whereas fluency and strategy use made statistically significant contributions to reading comprehension, background knowledge did not. Based on the results, the study affirms the importance of automaticity in word recognition, prosody, and comprehension strategies in contributing to reading comprehension in Turkish and, as such, should be given priority for literacy instruction in Turkish.
Inverse Design of Artificial Materials Based Lens Antennas through the Scattering Matrix Method
Authors: Palmeri Roberta , Isernia Tommaso
Published: March 2020

The design of spatially varying lens antennas based on artificial materials is of high interest for their wide range of applicability. In this paper, we propose a novel design procedure relying on an inverse formulation of the scattering matrix method (SMM). Differently from many adopted approaches, which resort to global optimizations or homogenization procedures, the inverse SMM (I-SMM) allows the synthesis of optimal parameters (geometrical and/or electromagnetic) for the inclusions realizing the overall device in a very effective manner. With reference to the 2D TM case, the proposed tool has been successfully assessed through the synthesis of different kinds of lenses radiating a pencil beam.
Building a Better Baseline for Residential Demand Response Programs: Mitigating the Effects of Customer Heterogeneity and Random Variations
Authors: Schwarz Peter , Mohajeryami Saeed , Cecchi Valentina
Published: March 2020

Peak-time rebates offer an opportunity to introduce demand response in electricity markets. To implement peak-time rebates, utilities must accurately determine the consumption level if the program were not in effect. Reliable calculations of customer baseline load elude utilities and independent system operators, due to factors that include heterogeneous demands and random variations. Prevailing research is limited for residential markets, which are growing rapidly with the presence of load aggregators and the availability of smart grid systems. Our research pioneers a novel method that clusters customers according to the size and predictability of their demands, substantially improving existing customer baseline calculations and other clustering methods.
Hardware in the Loop Implementation of the Oscillator-based Heart Model: A Framework for Testing Medical Devices
Authors: Mascio Chiara Di , Gruosso Giambattista
Published: March 2020

The hardware in the loop technologies allow to simulate physical models in combination with real devices in order to validate the behavior of the latter under different conditions, not easily reproducible in the real world. They are widely used in various industrial applications. In this work we want to extend the methodology to medical devices. These must interact with the patient to obtain the desired clinical result, however, during the development and validation phase of medical devices, the patient cannot be involved in the testing process. In this article the hardware in the loop methodology is proposed starting from a mathematical model of the heart, based on oscillators, that can be used to validate pacemakers or other medical devices.
Selective Epitaxial Growth of In Situ Doped SiGe on Bulk Ge for p+/n Junction Formation
Authors: Garidis Konstantinos , Abedin Ahmad , Asadollahi Ali , Hellström Per-Erik , Östling Mikael
Published: March 2020

Epitaxial in situ doped Si0.73Ge0.27 alloys were grown selectively on patterned bulk Ge and bulk Si wafers. Si0.73Ge0.27 layers with a surface roughness of less than 3 nm were demonstrated. Selectively grown p+Si0.73Ge0.27 layers exhibited a resistivity of 3.5 mΩcm at a dopant concentration of 2.5 × 1019 boron atoms/cm3. P+/n diodes were fabricated by selectively growing p+- Si0.73Ge0.27 on n-doped bulk Ge and n-doped Si wafers, respectively. The geometrical leakage current contribution shifts from the perimeter to the bulk as the diode sizes increase. Extracted near midgap activation energies are similar to p+/n Ge junctions formed by ion implantation. This indicates that the reverse leakage current in p+/n Ge diodes fabricated with various doping methods, could originate from the same trap-assisted mechanism. Working p+/n diodes on Ge bulk substrates displayed a reverse current density as low as 2.2·10−2 A/cm2 which was found to be comparable to other literature data. The layers developed in this work can be used as an alternative method to form p+/n junctions on Ge substrates, showing comparable junction leakage results to ion implantation approaches.
Simulation and Experimental Validation of Novel Trajectory Planning Strategy to Reduce Vibrations and Improve Productivity of Robotic Manipulator
Authors: Ariano Andrea , Perna Valerio , Senatore Adolfo , Scatigno Roberto , Nicolò Fabio , Fazioli Francesco , Avallone Giuseppe , Pesce Stefano , Gagliano Alberto
Published: March 2020

This paper aims at investigating vibrational behaviors of the industrial manipulator Racer 7-1.4, designed and manufactured by COMAU S.p.A., with the target of new trajectory planning strategies to improve productivity rate without any loss of positioning accuracy. Starting from the analysis of a 9DoF multi-body system with lumped parameter, the first natural frequency of the robot was calculated in seven reference positions. Then, static and dynamic simulations were run by applying saturated ramp input and large motions to analyze the vibrational behavior of the manipulator. This research underlines that the optimal way to design the robot move is to set its duration at twice a period of free oscillation according to the first vibrational mode. Due to strong analogy of dynamic response of both 1DoF and 9DoF robot models, the closed-form solution of the 1DoF undamped system—featured by natural frequency equal to the first frequency of the 9DoF system—may be successfully adopted by the real-time trajectory planning process to predict residual vibration at move end-condition. This strategy was confirmed by experimental tests, allowing either residual vibration decrease and execution time reduction as well.
People Walking Classification Using Automotive Radar
Authors: Senigagliesi Linda , Ciattaglia Gianluca , De Santis Adelmo , Gambi Ennio
Published: March 2020

Automotive radars are able to guarantee high performances at the expenses of a relatively low cost, and recently their application has been extended to several fields in addition to the original one. In this paper we consider the use of this kind of radars to discriminate different types of people’s movements in a real context. To this end, we exploit two different maps obtained from radar, that is, a spectrogram and a range-Doppler map. Through the application of dimensionality reduction methods, such as principal component analysis (PCA) and t-distributed stochastic neighbor embedding (t-SNE) algorithm, and the use of machine learning techniques we prove that is possible to classify with a very good precision people’s way of walking even employing commercial devices specifically designed for other purposes.
Carbon-Based Composite Microwave Antennas
Authors: Dugin Nikolai A. , Zaboronkova Tatiana M. , Krafft Catherine , Belyaev Grigorii R.
Published: March 2020

Applications of metamaterials to microwave antennas are reviewed over the past decade. The manufacturing of microwave antennas using graphene-containing carbon composite materials was developed and prototypes of dipole and horn antennas made from such materials were created. The radiation properties of the designed antennas and their metal analogs were measured and compared. The standing wave ratios, the radiation patterns and the amplitude-frequency characteristics were analyzed for horn antennas at frequencies 1.6 GHz and 5 GHz and for dipole antennas in the frequency range 0.2–0.6 GHz. The polarization characteristics of the horn antennas were studied. The effects of different carbon composite materials’ structures (fiber or fabric) on the antennas’ parameters were estimated. It is shown that antennas made from graphene-containing composite materials are able to operate efficiently and exhibit almost the same radiation properties as conventional metal antennas of the same geometry and size. However, the carbon-based antennas have much smaller weights and enhanced stability in a wide range of temperatures. In the future, such antennas should replace the conventional ones for many applications, especially for the excitation and reception of electromagnetic waves in space plasmas.
Analysis and Design of Harmonic Rejection Low Noise Amplifier with an Embedded Notch Filter
Authors: Gyaang Raymond , Lee Dong-Ho , Kim Jusung
Published: March 2020

This paper presents the analysis and design of the harmonic rejection (HR) low-noise amplifier (LNA) with the fully passive source degeneration notch filter. The proposed HR LNA provides the rejection for the strong harmonics ( 3 r d ) of the local oscillator (LO) frequencies, where the HR mixer does not provide sufficient HR performance. The proposed 3 r d harmonic notch filter modulates the source degeneration factor and the impedance matching performance thereafter. This effect further helps the blocking of the harmonic signal. The proposed LNA provides 11 dB gain at the fundamental frequency (2.1 GHz) while rejecting the 3rd harmonic component by 37 dBc. Compared to the conventional LNA, the 3rd harmonic notch performance is improved by 23 dB. Additionally, the LNA achieves a minimum noise figure of 3.1 dB, third order input intercept point ( I I P 3 ) of 0.5 dBm, input reflection (S 11 ) below −10 dB from 1.8 GHz–2.3 GHz operational frequency range, and consumed 19 mW of power from a 1.2 V supply.
Deceptive Targets Generation Simulation Against Multichannel SAR
Authors: Ji Penghui , Xing Shiqi , Dai Dahai , Pang Bo
Published: March 2020

Traditional synthetic aperture radar (SAR) deceptive jamming can effectively generate deceptive scenes or false targets in SAR images. However, these false targets or scenes can be easily distinguished or eliminated by the multichannel SAR system. To interfere with the multichannel SAR, we first analyzed the results of SAR deceptive jamming generated by one transponder and two transponders against three-channel SAR- ground moving target indication (GMTI). Then, we propose a new deceptive jamming method against three-channel SAR-GMTI by using three synergetic transponders. By modulating each transponder with a complex coefficient, three synergetic transponders can generate false moving targets with the controllable radial velocity and located azimuth position in three-channel SAR-GMTI. Besides, in this paper, we also introduce an algorithm to deploy three transponders reasonably by utilizing the minimum condition number. In the end, a general architecture of multiple transponders deceiving multichannel SAR is given. The proposed method can not only generate deceptive false targets against multichannel SAR-GMTI, but also guide the production of a deceptive digital elevation model (DEM) against multichannel interferometric SAR (InSAR). Simulations verify the effectiveness of the proposed method.
Multi-Factorial Load Analysis of Pine Sawlogs in Transport to Sawmill
Authors: Tymendorf Łukasz , Trzciński Grzegorz
Published: March 2020

This study analyzed the variability of truckloads of large-sized pine logs transported to a furniture manufacturing mill, depending on the origin of the timber, delivery period, length of the transported logs, volume of the load and its mass. It was assumed that the volume and mass of the transported timber load depends on the season of the year and the origin of the timber, which has a significant impact on the mass of one cubic meter of the load. The analysis of the wood origin parameters (location of its growth) took into account the type of forest habitat, soil type and stand abundance. The characteristics of the tree parameters from which the roundwood was obtained took into account age, diameter at breast height (DBH) and height of the stand. The origin of the timber was determined for 1063 timber loads from 40 forest districts transported over a 12 month period. We obtained an average timber load volume of 29.34 m3 which includes single shipments differing significantly in their volume of between 24.21 and 36.51 m3. The origin of the timber, habitat conditions and stand parameters of the harvesting site influence load mass and the mass of 1 m3 of load. The delivery date has an impact on the studied elements of the sawlogs load, with two similar periods—spring and summer. The volume of the transported timber is already at a stabilized level in accordance with legal regulations, which is no longer dependent on other factors and only on the accepted conversion factors for roundwood density and the mass of the empty vehicle set. This has not influenced a reduction in the mass of the transported timber.
Forest Roads from the Perspective of Managerial Accounting—Empirical Evidence from Austria
Authors: Toscani Philipp , Sekot Walter , Holzleitner Franz
Published: March 2020

State-of-the-art forest management requires an adequate opening-up in terms of forest roads. In addition to the increased efficiency of harvesting operations, a higher road density may trigger other positive and negative side-effects. Austria has a long tradition of forestry, and also of monitoring the economic performance of forest enterprises by means of forest accountancy data networks. Using these almost unique preconditions, this research paper approaches the topic of forest roads from a managerial accounting perspective. Based on a specially designed report, the results for the fiscal years 2008–2017 were investigated. On average, Austrian forest enterprises larger than 500 ha report a road density of 50.5 m/ha. The yearly net cost of forest roads, including depreciation and reduction of revenue, is 32.4 €/ha. The pure maintenance cost amounts to 27.9 €/ha on average. The annual investment in forest roads accounts for 9.4 €/ha. Whereas the enterprises’ average annual cost of maintenance is 0.63 €/m, the actual maintenance cost of forest roads is 5.6 €/m. To cover the ongoing costs of maintenance, 12.1% of the allowable annual cut is needed. Grouping the analyzed enterprises according to different attributes, namely size of forest land, production conditions, coherence of estate, average slope, and share of forest land requiring cable yarding, showed some statistically significant differences in the maintenance costs of forest roads. In almost all of the tested groupings, significant differences of maintenance costs (expressed as €/ha, €/m3 felling volume, or €/m) were found. However, an initially expected significant correlation between road density and harvesting cost could not be established. The challenges brought about by the trend towards a bioeconomy on the one hand and climate change on the other most likely further enhance the significance of the opening-up of forests and the efficiency of road maintenance.
Seemingly Unrelated Mixed-Effects Biomass Models for Young Silver Birch Stands on Post-Agricultural Lands
Authors: Bronisz Karol , Mehtätalo Lauri
Published: March 2020

Secondary succession that occurs on abandoned farmlands is an important source of biomass carbon stocks. Both direct and indirect tree biomass estimation methods are applied on forest lands. Using empirical data from 148 uprooted trees, we developed a seemingly unrelated mixed-effects models system for the young silver birch that grows on post agricultural lands in central Poland. Tree height, biomass of stem, branches, foliage, and roots are used as dependent variables; the diameter at breast height is used as the independent variable. During model elaboration we used restricted cubic spline: 5 knots at the quantiles (0.05, 0.275, 0.5, 0.725, and 0.95) of diameter at breast height provided sufficiently flexible curves for all biomass components. In this study, we demonstrate the use of the model system through cross-model calibration of the biomass component model using tree height measured from 0, 2, 3, and 4 available extreme trees feature in the plot in question. A different number of extreme trees were measured for final model system and our results indicated that for all analyzed components, random-effect predictions are characterized by higher accuracy than fixed-effects predictions.
Wood Density Determination by Drilling Chips Extraction in Ten Softwood and Hardwood Species
Authors: Martínez Roberto D. , Balmori José-Antonio , F. Llana Daniel , Bobadilla Ignacio
Published: March 2020

Research Highlights: The novelty of this study is the development of an accurate wood density estimation method based on a relatively brand new semi-destructive testing technique (drilling chips extraction). This method is especially crucial in the assessment of existing timber structures. Background and Objectives: Probing, drilling, and coring are non-destructive and semi-destructive techniques commonly used for timber density estimation in existing timber structures. Most of these techniques show poor or medium accuracy or are so expensive or destructive. This paper aims to obtain accurate estimation models for wood density in existing structures using the easy to use drilling chips extraction technique. Materials and Methods: 300 specimens (95 × 65 × 200 mm3) from ten softwood and hardwood species covering a wide range of density (from 350 to 980 kg·m−3) were tested after conditioning. The Wood Extractor device based on the drilling chips extraction technique was used in the radial and the tangential direction. Mass of the chips collected (drilling residue) from each drill was recorded. Results: Density obtained from drilling residue was not statistically significantly different between radial and tangential directions avoiding take into account direction when measuring. The density obtained in the whole specimens is slightly higher than the density obtained by drilling residue being this difference uniformly through the range of densities studied. Two different estimation models were presented with high determination coefficients (96% and 97%) and low standard errors. These results were similar to those obtained by other authors using core drilling but causing less damage. Conclusions: Drilling chips extractor is a simple, reliable and inexpensive method to estimate density in existing structures with accuracy.
Ease of Access to An Alternative Food Source Enables Wallabies to Strip Bark in Tasmanian Pinus radiata Plantations
Authors: Smith Anna H. , Ratkowsky David A. , Wardlaw Timothy J. , Mohammed Caroline L.
Published: March 2020

Bark stripping by the Bennett’s wallaby (Macropus rufogriseus (Desmarest) subsp. rufogriseus) from the lower stems of 3–6-year-old radiata pine (Pinus radiata D. Don) causes significant damage in Tasmanian plantations. The usual diet of this generalist herbivore is mainly grasses and broadleaved forbs. As the factors that attract a wallaby to supplement its diet by eating the bark of plantation pine trees are currently not elucidated, the present study aimed to determine how the incidence and severity of bark damage in 12 Tasmanian radiata pine plantations was influenced by various inter-site factors such as the floristic composition of the surrounding forest, and by various intra-site factors such as the height and circumference of individual trees, the number of branches in the first two whorls at the base of the tree, and their internode lengths. It was found that the greater the percentages of bare ground, bracken, and moss present in the five plots at each site, and the greater the percentage of grass, the wallaby’s main food source, the greater the likelihood of bark stripping. The difference between the mean minimum soil and air temperatures in spring, a driving force for carbohydrate production that occurs with tree growth in spring or early summer, was the only meteorological observation at the sites that was found to be significantly related to the extent of bark stripping.
Silenced Motherhood(s): Forbidden Motherings in the Early Childhood Classroom
Authors: Bentley Dana Frantz
Published: March 2020

What is the role of mothering in the early childhood classroom? Given the focus of the field of “professionalization” and “scientific” practices, how might the role of maternal nurturance be woven into our understandings of pedagogies? This paper addresses the disempowerment experienced by an early childhood practitioner when maternal subjectivities and practices are framed as oppositional to the “professionalization” of the field. Through narrative research as a teacher-scholar, I explore my own experiences around my role as “not-mother” in the classroom, looking critically at the interwovenness of mothering and teaching in classroom relationships and communities. Through this narrative examination, I explore the role of maternal relationships in early childhood, in conversation with my practices of mothering as the teacher-not-mother. Through narrative inquiry and analysis, I attempt to make visible the forbidden subjectivities of the not-mother, and her centrality to meaningful early childhood pedagogy.
Growing Communities in a Garden Undone: Worldly Justice, Withinness and Women
Authors: Blom Simone Miranda , Crinall Sarah
Published: March 2020

Where communities are ecological and humans are nature, ways of reimagining and regenerating communities as human and more, offer a timely response to the call of the Anthropocene for worldly justice. We, the authors, as women and mothers, look into time, place and space, harvesting our ‘becoming (undone)’ for the reader, seeded in the botanical world. Creeping and whispering, still and subtle, plant species are ever present in our survival yet often go unnamed and unnoticed, and to date are under-represented in multi-species becoming research. Via Foucault’s shining light upon power, we muse with Barad, Haraway and Grosz—how does growing (with) plant-life, amongst what is ‘said’ and ‘unsaid’, matter (to) the world as it turns? We have been returned to the same sediment after a decade: Our bowed-together life revived in the childhood–motherhood–nature community entanglements of the Anthropocene. Now, this paper, waters plant–human relationalities living beyond the traditional parochial human-to-human role. We accept our humanness in its onerousness and ownership but look to the leaf litter to reacquaint with our multispecies lives in a garden that has, at times, been sacrificed and lost. Our contribution is chlorophyllic. New ideas enfold and energise what constitutes a community. As women woven with botanica and academia, where mothering is a collaboration rather than a raising, we invite the reader to journey with us into the worldly, life-giving relations that garden a community undone.
Geochemistry of Deccan Tholeiite Flows and Dykes of Elephanta Island: Insights into the Stratigraphy and Structure of the Panvel Flexure Zone, Western Indian Rifted Margin
Authors: Patel Vanit , Sheth Hetu , Cucciniello Ciro , Joshi Gopal W. , Wegner Wencke , Samant Hrishikesh , Sen Bibhas , Koeberl Christian
Published: March 2020

Elephanta Island near Mumbai is an important area for understanding the stratigraphic and structural framework of the Deccan flood basalt province in the tectonically disturbed Panvel flexure zone on the western Indian rifted margin. Elephanta exposes a west-dipping, 66–65 Ma sequence of tholeiitic lava flows and dykes. Geochemical correlations with the thick, horizontal, 66–65 Ma Western Ghats sequence to the east show that lava flows of the Khandala and Ambenali formations are present at Elephanta, with two lava flows probably being locally derived. The Elephanta tholeiites have experienced crystal fractionation and accumulation, particularly of olivine. They have εNd(t) ranging from +5.4 to −7.9 and (87Sr/86Sr)t from 0.70391 to 0.70784, with most tholeiites little contaminated by continental lithosphere, probably lower crust. Field and geochemical data indicate a normal fault along the central part of Elephanta with a 220 m downthrow, consistent with a domino-type block-faulted structure of Elephanta, and the surrounding area as previously known. Seventeen of the 20 analyzed Elephanta intrusions, striking ~N–S, belong to the Coastal dyke swarm of the western Deccan province. Several of these are probable feeders to the Ambenali Formation in the Western Ghats sequence, requiring reconsideration of the current view that the voluminous Wai Subgroup lavas of the Western Ghats were erupted without organized crustal extension. East–west-directed extensional strain was already active at 66–65 Ma along this future (62.5 Ma) rifted continental margin. A young (~62 Ma) ankaramite dyke on Elephanta Island is a probable feeder to the Powai ankaramite flow in the 62.5 Ma Mumbai sequence 20 km to the northwest.
Hydrological Impact of Ilisu Dam on Mosul Dam; the River Tigris
Authors: Al-Madhhachi Abdul-Sahib T. , Rahi Khayyun A. , Leabi Wafa K.
Published: March 2020

The Ilisu Dam is part of the Turkish Southeastern Anatolia Project (GAP) and is the largest dam on the Tigris River in Turkey. It is located on the main river course 65 km upstream of the Syrian and Iraqi border. The Ilisu Dam watershed is the same as that of the Mosul Dam in Iraq. Sharing the same watershed with the Mosul Dam and located upstream, the Ilisu Dam will usurp most of the watershed and deprive the Mosul Dam of most of its current inflow. This paper presents an assessment of the hydrological impact (basically predicts changes on future inflow) of the Ilisu Dam on the Mosul Dam. The assessment is based on the worst-case scenario. The analyses that are employed include geographic information system (GIS) techniques and regression models, along with statistical analyses to numerate expected future impacts on the Mosul Dam’s inflow distribution. Results reveal that the Ilisu will have a drastic impact on the inflow regime of the Mosul Dam. A reduction as high as 78% of the inflow of the Mosul Dam may occur if the operation of the Ilisu and the Cizre Dams is conducted with no consideration of downstream hydrological and environment impacts.
Pyrolysis of Technogenic-Redeposited Coal-Bearing Rocks of Spoil Heaps
Authors: Akulov Nikolay I. , Akulova Varvara V.
Published: March 2020

The paper presents the results of a study of epigenetic changes in technogenic-redeposited coal-bearing rocks of Irkutsk and Kuznetsk coal basin spoil heaps (Russia). Hydrocarbon products formed under high-temperature and low-temperature pyrolysis of coal-bearing rocks were studied by using a chromatography-mass spectrometer GCMS-QP2010NC Plus (made by Shimadzu Company). The average temperature of low-temperature natural pyrolysis does not exceed 120 °C, and its average speed is approximately 2 m/year. In this case, three pyrolysis zones gradually built metamorphic rock mass (from bottom to top) are clearly established: heating (focal) activated and enriched. The average temperature of high-temperature pyrolysis reaches 850 °C, and its average speed is approximately 20 m/year. Unlike low-temperature pyrolysis, high-temperature pyrolysis is accompanied by the presence of two major zones (from bottom to top): pyrogenic (focal) and enriched (coke). The chemical composition of the enriched pyrolysis zone was studied in detail. It has been established that hydrocarbon compounds in samples of the pyrolysis zone are presented by six classes: asphaltic-resinous substances; polycyclic aromatic hydrocarbons, heterocyclic compounds, organic sulphur compounds; pyrolytic hydrocarbon and heavy hydrocarbon residue. Quantitative content of hydrocarbon compounds in the analyzed samples varies from 0.35% to 41.88%.
Metasedimentary Metatexites with Trondhjemitic Leucosomes from NE Sicily: Another Example of Prograde Water-fluxed Melting in Collisional Belts
Authors: Fiannacca Patrizia , Cirrincione Rosolino
Published: March 2020

Trondhjemitic leucosomes, hosted in late Variscan metasedimentary migmatites from the upper amphibolite-facies basement of the north-eastern Peloritani Mountains (southern Italy), have petrographic and geochemical features consistent with their origin as near-pure melts derived from in situ water-fluxed melting of their paragneiss host-rocks. Comparison with results of experimental melting and thermodynamic modelling of metasedimentary rocks suggests a dominant derivation of the leucosomes by melting, at c. 1.0 GPa and 700 °C, metagreywackes with a high pelitic content. Migmatization likely began at the thickening-related baric peak, or during the early post-collisional exhumation stages. A subsequent heating stage following the decompression and solidification of the leucosomes triggered a second melting stage, involving muscovite and biotite incongruent breakdown, with an associated production of peritectic sillimanite and garnet, and small leucogranitic patches within the trondhjemitic leucosomes. These melting events can be framed in the typical clockwise P-T-(t) evolution of the Variscan Belt in western and southern Europe, depicting collision-related thickening followed by widespread migmatization, starting close to the baric peak at c. 345 Ma and continuing during exhumation, with a duration of c. 25 Ma, up to c. 320 Ma.
Oromo Orature: An Ecopoetic Approach, Theory and Practice (Oromia/Ethiopia, Northeast Africa)
Authors: Dibaba Assefa Tefera
Published: March 2020

Using available empirical data of Oromo Orature, particularly folksongs, obtained from the field through interview and observation in Oromia, central Ethiopia, in 2009 and 2010, and other sources in print, this study has two objectives to tackle. First, reflecting upon the questions of a native model of origin narratives in relation to ecology, this study examines some examples of Oromo ecopoetics to determine: (a) how ecology and creative process conspire in the production of folksongs and performance, and (b) how the veil of nature hidden in the opacity of songs is revealed through the rites of creative process and performance as the human and ecological realms intersect. When put in relation to ecology, I theorize, the ecocultural creative act and process go beyond the mundane life activities to determine the people’s use (of nature), perceptions, and implications. Second, damages to the ecology are, I posit, damages to ecoculture. Drawing on the notion of ecological archetypes, thus, the study makes an attempt to find a common ground between the idea of recurrent ecological motifs in Oromo orature and the people’s ecological identity. The findings show that the political and social attitudes the Oromo songs embody are critical of authorities and the injustices authorities inflict on peoples and the environment they live in. For the folksinger, singing folksongs is a form of life, and through performance, both the performance and the song sustain the test of time. In its language, critique, imagination, and cultural referents, Oromo Orature is a voice of the people who rely on traditional agricultural life close to nature along with facing challenges of the dominating religious, political and scientific cultures.
The Perceptions of Professional Values among Students at a Spanish Nursing School
Authors: Bleda Silvia , Alvarez Isabel , Prat Mercè
Published: March 2020

(1) Background: This study aims to reflect student nurses’ perceptions of professional values across the four training years. (2) Methods: This study was designed as a cross-sectional study; data were collected using the Nurses’ Professional Values Scale-Revised, adapted by Basurto-Hoyuelos. A total of 315 student nurses participated from a Nursing Faculty in Spain representing each of the four academic years. (3) Results: Students’ perceptions of professional values were significantly correlated with their academic year. Overall, students’ scores were higher in the ethics dimension. The two highest scores were for Maintain patient confidentiality for years 1 and 2 (4.77 and 4.68, respectively) and Safeguard patients’ right to privacy for years 3 and 4 (4.95 and 4.98, respectively). Lower scores were observed in the professional expertise dimension across all years, and corresponded to a single item Participate in peer review (3.51, 3.38, 3.98, and 3.26, respectively). (4) Conclusions: This study is relevant as it highlights how nursing students’ perceptions of professional values change overtime, even during the four years of their training. The ethics dimension was the most highly regarded across all academic years. However, the professional expertise dimension requires greater attention throughout the degree as students regarded it as less important for their immediate future.
Colonization Resistance in the Infant Gut: The Role of B. infantis in Reducing pH and Preventing Pathogen Growth
Authors: Duar Rebbeca M. , Kyle David , Casaburi Giorgio
Published: March 2020

Over the past century, there has been a steady increase in the stool pH of infants from industrialized countries. Analysis of historical data revealed a strong association between abundance of Bifidobacterium in the gut microbiome of breasted infants and stool pH, suggesting that this taxon plays a key role in determining the pH in the gut. Bifidobacterium longum subsp. infantis is uniquely equipped to metabolize human milk oligosaccharides (HMO) from breastmilk into acidic end products, mainly lactate and acetate. The presence of these acidic compounds in the infant gut is linked to a lower stool pH. Conversely, infants lacking B. infantis have a significantly higher stool pH, carry a higher abundance of potential pathogens and mucus-eroding bacteria in their gut microbiomes, and have signs of chronic enteric inflammation. This suggests the presence of B. infantis and low intestinal pH may be critical to maintaining a protective environment in the infant gut. Here, we summarize recent studies demonstrating that feeding B. infantis EVC001 to breastfed infants results in significantly lower fecal pH compared to controls and propose that low pH is one critical factor in preventing the invasion and overgrowth of harmful bacteria in the infant gut, a process known as colonization resistance.
DMETTM Genotyping: Tools for Biomarkers Discovery in the Era of Precision Medicine
Authors: Agapito Giuseppe , Settino Marzia , Scionti Francesca , Altomare Emanuela , Guzzi Pietro Hiram , Tassone Pierfrancesco , Tagliaferri Pierosandro , Cannataro Mario , Arbitrio Mariamena , Di Martino Maria Teresa
Published: March 2020

The knowledge of genetic variants in genes involved in drug metabolism may be translated into reduction of adverse drug reactions, increase of efficacy, healthcare outcomes improvement and economic benefits. Many high-throughput tools are available for the genotyping of Single Nucleotide Polymorphisms (SNPs) known to be related to drugs and xenobiotics metabolism. DMETTM platform represents an example of SNPs panel to discover biomarkers correlated to efficacy or toxicity in common and rare diseases. The difficulty in analyzing the mole of information generated by DMETTM platform led to the development and implementation of algorithms and tools for statistical and data mining analysis. These softwares allow efficient handling of the omics data to validate the explorative SNPs identified by DMET assay and to correlate them with drug efficacy, toxicity and/or cancer susceptibility. In this review we present a suite of bioinformatic frameworks for the preprocessing and analysis of DMET-SNPs data. In particular, we introduce a workflow that uses the GenoMetric Query Language, a high-level query language specifically designed for genomics, able to query public datasets (such as ENCODE, TCGA, GENCODE annotation dataset, etc.) as well as to combine them with private datasets (e.g., output from Affymetrix® DMETTM Platform).
On the Ability of LIDAR Snow Depth Measurements to Determine or Evaluate the HRU Discretization in a Land Surface Model
Authors: Weber Michael , Feigl Moritz , Schulz Karsten , Bernhardt Matthias
Published: March 2020

To find the adequate spatial model discretization scheme, which balances the models capabilities and the demand for representing key features in reality, is a challenging task. It becomes even more challenging in high alpine catchments, where the variability of topography and meteorology over short distances strongly influences the distribution of snow cover, the dominant component in the alpine water cycle. For the high alpine Research Catchment Zugspitze (RCZ) a new method for objective delineation of hydrological response units (HRUs) using a time series of high resolution LIDAR derived snow depth maps and the physiographic properties of the RCZ is introduced. Via principle component analysis (PCA) of these maps, a dominant snow depth pattern, that turned out to be largely defined during the (winter) accumulation period was identified. This dominant pattern serves as a reference for HRU delineations on the basis of cluster analyses of the catchment’s physiographic properties. The method guarantees for an appropriate, objective, spatial discretization scheme, which allows for a reliable and meaningful reproduction of snow cover variability with the Cold Regions Hydrological Model—at the same time avoiding significant increase of computational demands. Different HRU schemes were evaluated with measured snow depth and the comparison of their model results identified significant differences in model output and best performance of the scheme which best represents measured snow depth distribution.