bluuebunny/crossref_metadata_2025 huggingface dataset:
The law of “economic actors” between certain and control. The case of the Italian, British and American Commodity Exchanges
Authors: Caporrino Veronica
Published: December 2022

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The paper analyzes, especially with reference to trade, the decentralization of legislative activity which translates into a new widespread sovereignty, that in some respects undermines the “rule of law”. The purpose of this analysis is to analyze, without any pretense of completeness, from a submission point of view, the Commodity Exchange, where it is possible to research a polychromatic law, which  may  also  be  implemented  by non-state authorities, and where an  attempt  is made to record, how actual reality is constituted by an orderly plurality and the relationship between autonomy and heteronomy is made to seek the balance between private and public interests.
Vicios de la voluntad en el acto administrativo reglado
Authors: Rojas Barrientos Sergio
Published: December 2022

Existen diferentes concepciones acerca del rol de la voluntad como elemento de validez del acto administrativo reglado. Se ejecutó una revisión de literatura integrativa que reveló las cuatro explicaciones en pugna. Deficiencias importantes fueron identificadas en las cuatro explicaciones y, como consecuencia, se propone un modelo alternativo que las resuelve exitosamente. El modelo propuesto atribuye la voluntad de la que emerge el acto administrativo al Estado y, sugiere que tal voluntad está segmentada en dos jerarquías: legislativa y administrativa.
La perspectiva LGBTIQ+ de las comisiones de la verdad de Perú, Ecuador y Brasil y sus aportes para el caso colombiano
Authors: Salazar Arce David Esteban
Published: December 2022

Dentro de los conflictos armados, las personas LGBTIQ+ son víctimas de violencia agravada por la discriminación histórica fundamentada en ciertos ideales biológicos, morales, heteronormativos y patriarcales. A partir de esta premisa, las Comisiones de la Verdad, como organismos encargados de esclarecer las graves violaciones a los derechos humanos, ocasionadas en determinados periodos, están llamadas a emplear un enfoque diferenciado para desentrañar aquellas transgresiones cometidas en contra de personas con orientaciones sexuales o identidades de género diversas, con el fin de ser visibilizadas y dignificadas. Este artículo de reflexión, tiene el propósito de exponer la importancia y el alcance de esta perspectiva por medio del análisis comparativo entre las Comisiones de la Verdad de Perú, Ecuador y Brasil, que en Suramérica han tratado el tema de manera diferenciada. Como resultado, se logran evaluar algunos parámetros utilizados por la Comisión para el Esclarecimiento de la Verdad, la Convivencia y la no Repetición en Colombia- CEV, en la elaboración de su Informe Final. Estas lecciones están encaminadas a promover la inclusión social y la visibilización, ahondar en la identificación y el estudio de este tipo de casos y, desentrañar las causas de la violencia LGBTIQ+ a partir de la identificación de los distintos sesgos ideológicos y normativos que se enardecen en tiempos de hostilidades.
Issue Notes
Authors:   Editor
Published: December 2022

The following papers were presented to the Canadian Society of Church Historyin 2013, but were not made available for publication: Bruce Douville, “‘The only Cultural entity that ever came to Rochdale . . . and came out ahead:’ The Jesus People Commune at Rochdale College in Toronto, 1971-74”; Hannah Lane, “Congregationalism in Eastern Maine and Southern New Brunswick, 1831-1881”; Patricia Janzen Loewen, “Band of Brothers: The Ryerson Riders and the Formation of Methodist Family Compact”; Renee Soulodre-La France, “Brothers (and Sisters) in Faith: Black Brotherhoods in Colonial Colombia”; Caryn Douglas; “Feministiza-tion Among United Church Deaconesses”; and Stuart Barnard, “The Bible Society in Canada.”
Issue Notes
Authors:   Editor
Published: December 2022

The following papers were presented to the Canadian Society of Church History, but were not made available for publication: Eleanor Stebner, “Apologizing for Past Wrongs: A Step Towards Global Citizenship?”; Marguerite Van Die, “‘What God hath joined . . .’: Religious Perspectives on Marriage and Divorce in Late Victorian Canada”; Darren Dochuk, “Hillybilly Preachers, Plain Folk, and ‘Ham and Eggs’: California’s Tumultuous Turn from Depression-era Populism to Post-war Conservatism”; Gary Miedema,“‘A Christian Country’: Religious Broadcasting and the Canadian Broadcasting Corporation, 1938-1960”; Sachiyo Takashima, “Women Who Made a Great Bridge Between North America and Japan: Gwen Norman and Haru Matsukata Reischauer, and their Efforts to Create Mutual Understanding”; and Gordon Heath, “‘Forming Sound Public Opinion’: Late Victorian Canadian Protestant Press and Nation-Building.” The conference also included a joint session with the Canadian Theological Society on “A Pilgrimage in Progress: A History of the United Church of Canada.”
Issue Notes
Authors:   Editor
Published: December 2022

The paper presented by Michael Di Giacomo, “Aimee Semple MacPherson, the Big Bang of Québécois Pentecostalism,” was not made available for publication. The paper presented by Jacques Kornberg, “Ignaz von Döllinger’s Die Juden in Europa: A Catholic Polemic against Antisemitism,” may be found in Zeitschrift für Neuere Theologiegeschichte / Journal for the History of Modern Theology Bd. 6 (Heft 2, 1999).
Issue Notes
Authors:   Editor
Published: December 2022

1. The paper presented by Lawrence Nixon, “Changing Trends in Manitoba Religion,” is forthcoming in A Geography of Manitoba: Its Land and People, eds. John Welsted, John Everitt and Christoph Stadel (Winnipeg: Univ. of Manitoba Press).2. The papers presented by Paul Laverdure, David Seljak and Marguerite Van Die were not made available for publication.
Gagasan Kultural Sutan Sjahrir (1931–1945)
Authors: Maulana Alif , Midawati
Published: December 2022

Penelitian ini mengambil topik “Gagasan Kultural Sutan Sjahrir (1931–1934)”. Tujuan penelitian ini adalah mendeskripsikan pemikiran kebudayaan Sutan Sjahrir serta jiwa zaman dan ikatan  kebudayaan  yang  berada  di  sekitar  si tokoh.  Penelitian ini  menggunakan  metode sejarah dengan fokus sejarah intelektual. Hasil penelitian menunjukkan bahwa Sutan Sjahrir mengkritik kapitalisme sebagai produk kebudayaan Barat yang menyengsarakan manusia. Namun  bukan  berarti  ia memilih  kebudayaan Timur untuk dijadikan sebagai jalan kebudayaan Indonesia di masa mendatang. Sjahrir berkesimpulan bahwa sintesa dari kedua kebudayaan itulah yang akan menjadi jalan kebudayaan yang akan ditempuh oleh Indonesia agar bisa menjadi bangsa yang sejajar dengan bangsa-bangsa lain di dunia, yaitu kebudayaan yang tidak menyengsarakan masyarakat serta mengedepankan rasionalitas

Kata kunci: gagasan, kultural, sejarah, intelektual, ikatan kebudayaan
The Dynamics of Fertility and Mortality of the Turkic-speaking Population of the Tobolsk Province (based on the Material of the Muslim Metric Books "on the Note of those Born and Dead")
Authors: Fajzullina Guzel Chakhvarovna
Published: December 2022

The article is devoted to the analysis of the dynamics of fertility and mortality of the Turkic-speaking population of the Tobolsk province. The analysis of the materials was preceded by research work in the state archives of Tobolsk (National Archive of the Republic of Bashkortostan) and Tobolsk (State Budgetary Institution of the Tyumen region "State Archive in Tobolsk") to identify the necessary sources, as well as systematization of the received materials, transliteration and translation into Russian. The material of our research is the metric records of the Komarov mosque of the Bukhara parish of the Tobolsk district of the Tobolsk province from 1835 to 1862 (with the exception of 1853). The novelty of the work is seen in the use of unexplored materials in the Old Tatar language – Muslim metric books "on the note of those born, on marriages, divorces and death" written on Arabic graphics. The study of the dynamics of fertility and mortality based on the material of mosque books will reveal the main demographic trends in the XIX century among the Turkic-speaking population of the Tobolsk province. The author comes to the conclusion that the observed: 1) excess of fertility over mortality, 2) excess of infant mortality over adult mortality, 3) a tendency to decrease the mortality rate by the end of the calendar year, 4) excess mortality (in some years) from epidemiological diseases (measles, smallpox, dysentery, rubella, etc.).
The Antioxidant Activity Comparison of Malus sylvestris Mill and Its Processed Products
Authors: Astuti Engrid Juni , Rafikayanti Agustin , Purwanto SeptianaTita , Puspitasari Chenchen , Rika Wenni Fista , Yesica Yeni
Published: December 2022

Chemical compounds that can donor one or more electrons to free radicals to inhibit free radical reactions are called antioxidants. Manalagi apple is a fruit with high antioxidant activity. Manalagi apple is a typical fruit of Batu City. Processed apple products are apple cider, vinegar, dodol, and chips. These products are sold in Batu city and produced the same home industry. The aim of this study was to determine the antioxidant activity comparison between Manalagi apple and four processed apple products based on IC50 values. This study used the ABTS method (2,2-azino bis (3-ethyl benzothiazoline-6-sulfonic acid) and analysis used spectrophotometric visible. IC50 value as  apples and their processed products were analyzed using a one-way ANOVA. The study results indicated that IC50 value of Manalagi apple was insignificantly different from the processed apple product of dodol and chips. However, the IC50 value of manalagi apple was significantly different from apple cider and vinegar.
Performance of Food Quality and Sensory Properties of Stick with Fortification of Fish Bone Flour Tuna and Kale Leaf Extract as Natural Food Coloran
Authors: Wardah  , Rahayu Sihmawati Rini
Published: December 2022

Sticks are pastries that are generally made from wheat flour, tapioca and other starch sources with a high carbohydrate content, but low in nutrition so they need to be added or fortified with other nutrients such as sources of fat, protein, vitamins or minerals. Utilization of tuna bone waste can be an alternative as a fortificant in making sticks. In addition, fish bones also contain high protein and calcium. The use of kale leaf extract is also an alternative as a natural dye. This study aims to evaluate the increase in the nutritional value and preference of panelists for stick products fortified with tuna fish bone meal and kale leaf extract as natural dyes with a certain dose. The results of the chemical test showed that the stick product at P3 had the highest protein and calcium content compared to other treatments (P0, P1, P2) with a value of 6.61+0.11% protein content and 4.133+0.01 mg/100g calcium content. However, the water content and crispness of the product decreased, the water content of P3 was the lowest compared to other treatments (P1, P2 and P3) with a value of 0.945+0.12% while the highest hardness (using a penetrometer) was obtained at P3 of 6.17+0.11 mm/ 100g/10s compared to just 1.50+0.12mm/100g/10s on the P1. The results of the sensory test, the overall preference of the panelists, the aroma and color of the stick product, P2 (sticks fortified with 20% tuna bone meal and 15% natural dye of kale leaf extract) were significantly (P<0.05) higher than the P0 treatment. , P1, P3. The highest value of P2 was 43% for dryness, 40% for aroma, and 57% for color. However, organoleptic assessment of taste and texture, P0 (sticks without fortification of fish bone meal and kale leaf extract) was significantly (P<0.05) higher than treatments P1, P2, P3 but between treatments had no significant effect (P>0 ,05). The highest score of P0 is 40% for taste and 43% for texture. The more addition of fish bone meal and kale leaf extract, the protein and calcium content of the sticks increased, but the water content and crispness of the sticks decreased. For this reason, it is recommended that in producing sticks that are added with tuna fish bone meal and natural dye, kale leaf extract should use the best composition, which is sticks with the addition of 20% tuna fish bones and 15% kale leaf extract.
Formula Optimization of Black Mulberry and Canistel Mixed Juice using Mixture D-Optimal from Design Expert Software
Authors: Irfan Yusuf , Taufik Yusman , Sutisna Achyadi Nana
Published: December 2022

Black mulberry (Morus nigra L.) and canistel (Pouteria campechiana) are classified as fruit commodities that are still not optimal in their utilization. Based on their sensory and nutritional characteristics, they have potential to be processed into products for a longer shelf life and more valuable. The purpose of this study was to determine the optimal formula for a mixed fruit juice product made from black mulberry and canistel in terms of chemical, physical and sensory characteristics. The optimization formula was analyzed by Design Expert software ver.11 and through the Mixture D-Optimal method. The independent variables in this study are black mulberry puree, canistel puree, and sucrose. The dependent variables were 0.05% sodium benzoate and a mixture of CMC and sodium alginate 0.25% with a ratio of CMC: sodium alginate 1:1. The chemical parameters analyzed consisted of anthocyanin, beta carotene, vitamin C, and antioxidant activity. The physical parameters consisted of viscosity and sensory parameters consisted of flavor, sweet taste, and sour taste. The results obtained that the optimal formulation was based on the highest desirability value from the results of the analysis using the Design Expert program and the value was 0.807. The optimal formula for mixed fruit juices was black mulberry puree 53.356%, canistel puree 35.252%, and sucrose 11.092%.
Prediction of IDR-USD Exchange Rate using the Cheng Fuzzy Time Series Method with Particle Swarm Optimization
Authors: Juwairiah Juwairiah , Winaldi Ersa Haidar  , Heru Cahya Rustamaji
Published: December 2022

Currently, much research on machine learning about prediction has been carried out. For example, to predict the exchange rate of the rupiah against the United States currency, namely the United States Dollar (USD). The continuing trend of USD depreciation has attracted many researchers to explore currency trading, especially in establishing an efficient method for predicting fluctuating exchange rates. The rapid development of time series prediction methods has resulted in many methods that can predict data according to needs. In this study, we apply the Fuzzy Time Series Cheng method with Particle Swarm Optimization (PSO) to predict the IDR exchange rate against USD. The data used in this research is sourced from Bank Indonesia in the form of time series data on the selling and buying exchange rate. The FTS Cheng method forecasts the IDR exchange rate against USD. In contrast, the PSO algorithm optimizes the interval parameter to increase the forecasting accuracy. Based on the implementation and the results of the tests, the results show that using the PSO algorithm can produce the best optimization interval parameters and increase the accuracy value. From the results of 10 trials with training data, testing data, and different iterations, it was obtained that the MAPE test for predicting the rupiah exchange rate against the US dollar using FTS Cheng with 60% training data and 40% testing data resulted in the lowest MAPE of 0.610145%. Furthermore, 70% of the training and 30% of the testing data resulted in the lowest MAPE of 0.313388%. Then the FTS Cheng and PSO testing with 60% training data and 40% testing data, and an iteration value of 200 resulted in the lowest MAPE of 0.394707%. Furthermore, 70% of training data and 30% of testing data and an iteration value of 90 resulted in the lowest MAPE of 0.263666%.
Body Temperature and Heart Rate Monitoring System Using Fuzzy Classification Method
Authors: Nurhadiansyah M. Yayan , Widyatra Sudibyo Rahardhita , Samsono Hadi Moch. Zen
Published: December 2022

Climbing becomes one of the extreme sports that test endurance with nature, just like in a mountainous environment. In addition to the excitement and fun that climbing provides, climbers enjoy the opportunity to view breathtaking natural scenery and breathe in the fresh air drawn directly from the surrounding environment. Because of the temperature in the cold mountains, there are frequent and common obstacles Not realized by the climbers, such as hypothermia. Hypothermia is a condition in which the body temperature drops below 35oC. When body temperature is below normal 37oC, nervous system function and other body organs will experience interference. If not soon Left untreated, hypothermia can lead to heart failure, disturbances respiratory system, and even death. To anticipate things requires a system that functions to know the condition of mountaineer health. The system to be created uses the Mamdani fuzzy logic method, which decides whether the climber is healthy.  The fuzzy logic method is used for decision-making based on body temperature and heart rate values. Implementation of the system in the form of a prototype containing sensors and mini-computers located at the climbing post, with data transmission using a node sent from post x to the main post to be uploaded to the database so that it can be known by the admin or rescue team when climbers need help in critical situations. This is done so that the condition can be monitored.
China in the Baltic States – from a Cause of Hope to Anxiety
Authors: Andžāns Māris ,   Rīga Stradiņš University; Center for Geopolitical Studies Riga, Mikelsaar Anniki ,   University of Oxford, Kante Justīne ,   Rīga Stradiņš University, Mačikėnaitė Vida ,   International University of Japan, Bērziņa-Čerenkova Una Aleksandra ,   Rīga Stradiņš University; Latvian Institute of International Affairs
Published: December 2022

The publication assesses the perception and the role of the Peopleā€™s Republic of China (China) in Latvia, Estonia, and Lithuania, with the emphasis on the implications of China for the national security of the three states and the North Atlantic Treaty Organization (NATO). Following a review of three decades of bilateral engagement between each of the Baltic states and China, the publication offers an analysis of the results from nationally representative surveys on Baltic attitudes toward China.
Renaming “Colonial” Congregations of UPCSA and the Politics of Toponym: The Case of Columba Mission, Centane
Authors: Mvenene Jongikhaya
Published: December 2022

This article is an offspring of Columba Kirk Session’s desire and request to change its name in favour of Reverend Frederick Wele Ngxenge. A discussion of the politics of toponyms, with special reference to Columba Mission, is the central theme of this article. In order to have an understanding of why there was this call for a name change, it is inescapable to not consider some background discussions of Rev. Ngxenge, who ministered in Southern amaGcalekaland, and Saint Columba, the man, who had never set foot in Africa. To that effect, this article presents Rev. Ngxenge within the context of his life and ministering and his connection with, and impact on, the rise and development of Columba Mission in the evangelising crusade. It provides Rev. Ngxenge’s contributions to the development of Columba Mission, Centane, from 1922 to 1971. It became clear that Rev. Ngxenge (1895–1971) belonged to Columba; he had spent his ministering life in this mission, where he and his wife, Dorothea Flora (1899–1974), were interred/laid to rest. It also provides a brief historical background of Columba, the man, as a basis for the elders and congregation to anchor their deliberations on a sound foundation. The author argues that the church, therefore colonial congregations and presbyteries, must tackle and dismantle the hegemony of White, Eurocentric and Western nomenclature and engage in debates around toponyms in favour of renaming their church after eminent personalities. The renaming of colonial congregations is one coin of the wider transformation agenda.
Calculation of number-average functionality and gel-point for stepwise polymerization
Authors: Deng Hui , Han Yan
Published: December 2022

The number-average functionality is proposed a simplified equation which can be used to predict the reaction progress of the stepwise polymerization expediently. According to the equation, once the average functionality of one reactant ((f_b ) ̅, for example) is fixed, there will be a critical functionality of (f_a ) ̅. The reaction system has no risk to gel with the increase of component A if (f_a ) ̅ is below the critical functionality, while gelation will occur with the increase of component A if (f_a ) ̅ is higher than the critical functionality, and the gel point is the degree of reaction when (f_nb ) ̅ diverges to indefinitely large. The deduced equation is suitable for polymerization between R-An and R’-Bn, in which one of the components could be consumed completely, such as polyurethane, polyester, or other stepwise polymerization reactions. The equation can calculate the number-average functionality of polymer mixtures, especially for grafting or branched polymerization.
Trapping hydrogen: Confined catalysis for improved hydrogen borrowing selectivity
Authors: Terra Julio , DeWolfe Jackson , Valdez Jesus Angel , Moores Audrey
Published: December 2022

Alcohol amination via hydrogen borrowing is an established method for the clean and simple alkylation of amines with alcohols, which are stable and available in bulk; it also does not require the addition of hydrogen to reduce the imines or the use of coupling agents. A common problem however in those systems is the need to employ additives to prevent stagnation of the product at the imine stage, which indicates inefficient usage of the borrowed hydrogen atoms. In this work, we designed a catalyst series to demonstrate that confined environments can assist with improved selectivity. To this end, we encapsulated Al2O3/Ru(OH)x nanocatalysts inside mesoporous silica in a yolk-shell architecture and were able to trap the hydrogens to increase the amine yield from 12% to 82%, with a 3-fold increase in selectivity without the need of any additive; we found the presence of mesopores in the silica shells to be essential to enable access to the cata-lytic sites and the yolk-shell gap size to be the key parameter influencing the reactivity of the catalytic system. To the best of our knowledge, this is the first report of a confined hydrogen borrowing reaction, an approach that can be extended to the other types of cascade reactions that produce labile intermediates.
Development of an improved reporter system for assessing the activity of programmable RNA regulators
Authors: Sinnott Riley , Cao Yang , Dickinson Bryan
Published: December 2022

RNA-binding proteins (RBPs) play a key role in the control of gene expression through their regulation of mRNA half-life, localization, chemical composition, and translation. Aside from their roles in native biological regulation, RBP functions can also be leveraged to create synthetic RNA regulators by fusing functional components of RBPs to programmable RNA-binding platforms such as RNA-targeting CRISPR-Cas systems or CRISPR-Cas Inspired RNA-targeting System (CIRTS). However, a key bottleneck for developing programmable RNA regulators is a lack of robust reporter systems and methods to characterize their function. To develop better reporters to characterize RNA regulator activity we optimized a dual luciferase reporter system by selecting luciferase enzymes that maximize reproducibility and signal stability. Additionally, we demonstrated that untranslated regions (UTRs) from disease-relevant transcripts could be incorporated into the reporter mRNAs, both to test RBPs in more native sequence contexts, but also to evaluate RBPs ability to affect gene expression from an mRNA when directed to those sequences. We also demonstrate the flexibility of the reporter by tuning its translational efficiency, testing the reporter in multiple cell lines, and by testing validated RNA regulators that target several UTRs from disease-relevant gene targets. The new reporter system showcased here should provide a valuable method to characterize and develop novel RNA regulators for both synthetic biology and therapeutic purposes.
Colorimetric transition pathway mapping in polydiacetylene by hyperspectral microscopy
Authors: Chen Jiali , Zheng Jianlu , Hou Yuge , Sugihara Kaori
Published: December 2022

The structural variance of polydiacetylene (PDA) at the nanoscale even under the same fabrication conditions is one of the origins of its poor reproducibility in chemo/biosensing. In this work, we present a spatial map of such structural distributions within a single crystal by taking an advantage of the recent development of hyperspectral microscopy in visible wavelength. Hyperspectral microscopy provides the distribution of absorption spectra at the spatial resolution of the standard optical microscopy. By track-ing the blue-to-red transition via this technique, we found that the heat application leaves a fingerprint in the transition pathways.
Quantum-chemical calculation of two-dimensional infrared spectra using localized-mode VSCF/VCI
Authors: Brüggemann Julia , Wolter Mario , Jacob Christoph
Published: December 2022

Computational protocols for the simulation of two-dimensional infrared (2D IR) spectroscopy usually rely on vibrational exciton models, which require an empirical parametrization. Here, we present an efficient quantum-chemical protocol for predicting static 2D IR spectra that does not require any empirical parameters. For the calculation of anharmonic vibrational energy levels and transition dipole moments, we employ the localized-mode vibrational self-consistent field (L-VSCF) / vibrational configuration interaction (L-VCI) approach previous established for (linear) anharmonic theoretical vibrational spectroscopy [Panek and Jacob, ChemPhysChem 15, 3365–3377 (2014)]. We demonstrate that with an efficient expansion of the potential energy surface using anharmonic one-mode potentials and harmonic two-mode potentials, 2D IR spectra of metal carbonyl complexes and of dipeptides can be predicted reliably. We further show how the close connection between L-VCI and vibrational exciton models can be exploited to extract the parameters of such models from those calculations. This provides a novel route to the fully quantum-chemical parametrization of vibrational exciton model for predicting 2D IR spectra.
Derivatives of Trigonal Lanthanide Complexes by Reaction with Long Aliphatic Chain Amines
Authors: Buch Christian Dirk , Zhou Yiwei , Hansen Steen Hansgaard , Piligkos Stergios
Published: December 2022

The trigonal lanthanide complexes LnL (H3L = tris(((3-formyl-5-methylsalicylidene)amino)ethyl)amine) contain three pending aldehyde groups and are known to react with primary amines. Reacting YbL and LuL with 1-octadecylamine yields the novel aliphatic lanthanide complexes (Yb, Lu)L18 (H3L18 = tris(((3-(1-octadecylimine)-5-methylsalicylidene)amino)ethyl)amine) where the three aldehyde groups are transformed to 1-octadecylimine groups. Herein the syntheses, structural characterisation and magnetic properties of YbL18 and LuL18 are presented. The crystal structure of YbL18 shows that the reaction of YbL with 1-octadecylamine leads to only very subtle perturbations in the first coordination sphere of Yb(III), with the Yb(III) ion retaining its heptacoordination and similar bond lengths and angles to the ligand. The three long octadecyl chains in each complex were found to direct crystal packing into lipophilic arrays of van-der-Waals interaction-driven hydrocarbon stacking. The static magnetic properties of YbL18 were compared to that of the non-derivatised complex YbL. The energy level splitting of the 2F7/2 ground multiplet was found, by emission spectroscopy, to be very similar between the derivatised and non-derivatised complexes. A.c. magnetic susceptibility measurements on YbL18 and YbL diluted at 5 % into the diamagnetic hosts LuL18 and LuL, respectively, revealed that the spin-lattice relaxation of both complexes is governed by a low temperature direct process and a high temperature Raman process. In the high temperature regime, the derivatised complex was also found to have faster spin-lattice relaxation, which is likely due to the increased number of phonons in the octadecyl chains.
Synthesis, characterization, and in vivo evaluation of the anticancer activity of a series of 5- and 6-(halomethyl)-2,2'-bipyridine rhenium tricarbonyl complexes.
Authors: Nasiri Sovari Sara , Kolly Isabelle , Schindler Kevin , Djuric Ana , Srdic-Rajic Tatjana , Crochet Aurelien , Pavic Aleksandar , Zobi Fabio
Published: December 2022

We report the synthesis, characterization, and in vivo evaluation of the anticancer activity of a series of 5- and 6-(halomethyl)-2,2'-bipyridine rhenium tricarbonyl complexes. The study was promoted in order to understand if the presence and position of a reactive halomethyl substituent on the diimine ligand system of fac-[Re(CO)3]+ species may be a key molecular feature for the design of active and non-toxic anticancer agents. Only compounds potentially able of ligand-based alkylating reactions show significant antiproliferative activity against colorectal and pancreatic cell lines. The anticancer potency of the species, does not correlate with the hydrolysis rate or rate of reaction of the coordinated 5- and 6-(halomethyl)-2,2'-bipyridine with the amino acid lysine. Of the new species presented in this study, one compound (5-(chloromethyl)-2,2'-bipyridine derivative) shows significant inhibition of pancreatic tumour growth in vivo in zebrafish-Panc-1 xenografts. The complex is noticeably effective at 8 uM concentration, lower than its in vitro IC50 values, being also capable of inhibiting in vivo cancer cells dissemination.
Development and Validation of Simple UV Spectrophotometric Method for the Determination of Pretomanid
Authors: Vaishali Pardeshi  , Tushar Lokhande  , Ashwini Shelke
Published: December 2022

In order to treat multidrug resistant TB, pretomanid, a nitroimidazooxazine antimycobacterial agent, is used with other antituberculosis medications. There is no technique for its analysis that uses spectroscopy, HPLC or HPTLC. Since a UV spectrophotometric approach for Pretomanid analysis must be developed. Utilizing a Shimadzu UV-2600, a quick, accurate, straightforward, and affordable UV spectrophotometric approach has been devised to determine Pretomanid. Solvent made of methanol to assess the bulk Pretomanid concentration. The detection process was placed at a wavelength of 321 nm. The parameters linearity, accuracy, precision, ruggedness, and robustness were taken into consideration during method validation in accordance with ICH Q2R1 criteria, as well as LOD and LOQ. It demonstrated linearity in the 10– 30(g/mL) range at a predetermined max of 321 nm, and had a strong correlation coefficient (R2-0.997) and outstanding mean recovery (99.00–100.07%). In terms of intraday and interday precision, Pretomanid’s% RSD was discovered to be 0.6366 and 0.666, respectively. Pretomanid identification using this approach was effective. The method’s  linearity,  accuracy,  repeatability, and reproducibility were statistically and empirically verified. The out- comes demonstrated the method’s applicability for both routine examinations of protomanid bulks and industrial formulations. The suggested UV-Vis Spectrophotometric approach was verified in accordance with ICH requirements and found to be simple, accurate, precise and quick for the determination of Pretomanid.
“Complete Freedom with the Right to Stay Everywhere...”: The Life and Work of N. M. Yadrintsev in St. Petersburg in 1874–1876
Authors:   Altai State University, Golovinov A. V. , Golovinova Yu. V. ,   Altai State Pedagogical University
Published: December 2022

The publication is devoted to the conceptualization of the biography of Nikolai Mikhailovich Yadrintsev in 1874–1875. during his stay in Petersburg. The chronological framework was not chosen by chance, since after receiving a pardon and moving to a reconciled capital, colossal changes took place in the fate of the Siberian regionalist. In general, guided mainly by sources of personal origin, it is shown that life in St. Petersburg for some two years presented N. M. Yadrintsev of the great significance of the event. From finding a faithful companion – a wife and a long-awaited meeting with a close friend, to public recognition and activation of public work against this background.
Efektivitas Kampanye Politik Di Media Sosial Pada Pemilihan Kepala Daerah Tahun 2018 Di Kecamatan Sajoanging Kabupaten Wajo
Authors: Sartikasari Sartikasari , Hardi Rudi , Hartaman Nursaleh
Published: December 2022

Penelitian ini bertujuan untuk mengetahui Efektivitas Kampanye Politik Di Media Sosial Pada Pemilihan Kepala Daerah Tahun 2018 Di Kecamatan Sajoanging Kabupaten Wajo. Menggunakan metode kualitatif dengan tipe fenomenologi. Sumber data, yaitu primer dan sekunder, jumlah informan 7 (tujuh) orang. Pengumpulan data menggunakan observasi, wawancara serta dokumentasi. Analisis data meliputi Reduksi data, penyajian data, dan penarikan kesimpulan. Hasil penelitian menunjukkan bahwa Efektivitas Kampanye Politik Di Media Sosial Pada Pemilihan Kepala Daerah Tahun 2018 Di Kabupaten Wajo pada 1.) Aspek tugas dan fungsi yaitu : KPU mengarahkan kandidat calon bupati wakil bupati untuk menyertakan akun media sosial saat pendaftaran berkas. 2.) Aspek Rencana atau program yaitu : KPU akan tetap memperbolehkan berkampanye di media sosial kedepannya. 3.) Aspek ketentuan dan peraturan yaitu : Kandidat calon bupati dan wakil bupati mengumpulkan akun media sosialnya kemudian jika terjadi pelanggaran pada kampanye politik di media sosial, bawaslu akan segera menindaklanjuti kemudian diserahkan ke kepolisian. 4.) Aspek tujuan dan kondisi ideal yaitu : bawaslu akan membentuk tim siber untuk menangani pelanggaran kampanye politik di media sosial
Pengaruh Kepemimpinan Terhadap Efektivitas Kerja Pegawai Pada Badan Kepegawaian Pendidikan Dan Pelatihan Daerah Kabupaten Luwu Timur
Authors: Juharni Juharni , Congge Umar
Published: December 2022

Penelitian ini bertujuan untuk mengetahui Pengaruh Kepemimpinan Terhadap Efektivitas Kerja Pegawai pada Badan Kepegawaian Pendidikan dan Pelatihan Daerah Kabupaten Luwu Timur. Aspek yang diteliti secara garis besar meliputi dua hal, yaitu kepemimpinan dan efektivitas kerja pegawai. Indikator yang digunakan untuk kepemimpinan adalah motivasi, Disiplin kerja, komunikasi dan pengambilan keputusan Sedangkan indikator untuk efektivitas kerja pegawai adalah Loyalitas Kerja, Ketepatan Waktu, Kreatifitas Kerja dan Prestasi Kerja. Metode penelitian yang digunakan adalah metode asosiatif kausal yang mana mencari hubungan sebab akibat, dengan teknik pengumpulan data melalui cara penyebaran angket, dan observasi, Dan ditunjang juga dengan sejumlah buku, karya ilmiah, dan arsip yang berhubungan dengan masalah yang ditelit, Jenis analisa data yang digunakan adalah jenis anlisa kuantitatif, dan Teknik analisis data yang digunakan adalah teknik korelasi product moment dan untuk mengetahui persen besarnya pengaruh kepemimpinan terhadap efektivitas kerja pegawai dan untuk mengetahui signifikan maka digunakan rumus t- hitung. Data diambil dan diperoleh dari 25 responden yang dilakukan melalui penyebaran angket. Hasil penelitian ini menunjukan bahwa ada hubungan positif dan signifikan antara kepemimpinan terhadap efektivitas kerja pegawai dan hubungannya ada pada kategori kuat, Berdasarkan hasil penelitian lapangan untuk uji signifikan 0,05% dengan responden 25 orang maka di uji dua pihak dan hasil t-tabel 2,069, dan ternyata t hitung 10,424 lebih besar dari t tabel 2,069 (10,424 ≥ 2,069) maka Ho ditolak artinya ada hubungan yang signifikan antara kepemimpinan dan efektivitas kerja pegawai pada Badan Kepegawaian Daerah Pendidikan dan Pelatihan Kabupaten Luwu Timur
Transparansi Bantuan Sosial dalam Pemutusan Penyebaran Virus Covid-19 di Kabupaten Soppeng
Authors: Mustari Nuryanti
Published: December 2022

Penelitian ini bertujuan untuk mengetahui Transparansi Bantuan Sosial Dalam Pemutusan Penyebaran COVID-19 Di Kelurahan Salo Karaja Kabupaten Soppeng. Jenis penelitian adalah Kualitatif. Tipe penelitian yaitu Deskriptif Kualitatif. Jumlah Informan 5 (Lima) Orang. Sumber data meliputi Data Primer dan Data Sekunder. Teknik Pengumpulan Data meliputi Observasi, Wawancara dan Dokumentasi. Teknik Analisis meliputi Pengumpulan Data, Reduksi Data, Sajian Data, Penarikan Kesimpulan. Hasil penelitian menunjukkan bahwa Transparansi Bantuan Sosial Dalam Pemutusan Penyebaran Virus COVID-19 di Kelurahan Salo Karaja Kecamatan Lalabata Kabupaten Soppeng 1) Keterbukaan Proses yaitu: Pemerintah melihat dalam 2 proses Transparansi yakni adanya Mekanisme Penganggaran dan Mekanisme Pendataan. 2) Peraturan dan Prosedur Pelayanan yaitu: a) Dalam hal pemberian Bantuan Sosial telah diatur dalam PERMENDAGRI Nomor 32 Tahun 2011 yang telah diubah dengan PERMENDAGRI Nomor 39 Tahun 2012. Sedangkan bantuan yang dikhususkan untuk Bantuan Sembako COVID-19 di Kabupaten Soppeng yakni Bantuan Sosial Pangan (BSP) telah di atur dalam PERBUB BUPATI Nomor 28 tahun 2020. b) Untuk Prosedur Pelayanannya terbagi 2 yakni Pelayanan Terpadu Satu Pintu dan Membuat Posko Tim Pengaduan di 8 Kecamatan Kabupaten Soppeng. 3)Kemudahan Informasi yaitu: Masyarakat mendapatkan informasi melalui sosialisasi dari Aparat Kelurahan maupun di Media Sosial namun masyarakat juga dapat mengakses melalui Aplikasi SIKS DATAKU dengan memasukkan NIK KTP yang sesuai dengan KK
culinária e o cuidado
Authors: Minguzzi Isabella Rodrigues , Albuquerque Joverlany Pessoa de , Oliveira Julicristie Machado de
Published: December 2022

O objetivo deste trabalho foi avaliar um processo pedagógico, alicerçado em “A Festa de Babette”, para estudantes de Nutrição, da Universidade Estadual de Campinas. Primeiramente, analisou-se o conto “A Festa de Babette”, de Karen Blixen, e o filme homônimo, de Gabriel Axel, com base em conceitos e obras de referência. Posteriormente, foi elaborado, aplicado e analisado um processo pedagógico na disciplina Educação Alimentar e Nutricional. Na coleta de dados, foram realizados dois grupos focais com sete estudantes voluntárias e discutidos os principais temas identificados: o choque de cultura entre a alimentação francesa e as práticas restritivas religiosas, a dedicação de Babette ao jantar e a relevância da comensalidade. Em conclusão, a culinária e o cuidado, atrelados ao cozinhar e ao comer, fomentaram rotas para a compreensão de conceitos trabalhados na disciplina, a sensibilização sobre essas dimensões e as possibilidades de atuação profissional que considerem outros matizes da vida social.
Políticas públicas para a infância e intervenção precoce no Brasil
Authors: Silva Maria Izabel Alves Felix da , Marini Bruna Pereira Ricci , Barba Patrícia Carla de Souza Della
Published: December 2022

O presente ensaio tem como objetivo tratar do diagnóstico da evolução das políticas públicas para a primeira infância no Brasil e sua relação com a Intervenção Precoce (IP). Para fundamentar este ensaio, as autoras apresentam os resultados de uma pesquisa\consulta formulário online preenchido por com profissionais que atuam em serviços de IP no Brasil a fim de analisar seu conhecimento e prática no campo. Constatou-se que ao mesmo tempo em que o Brasil avançou na legislação, as ações de IP têm se mantido no âmbito do setor de saúde, com forte prevalência de práticas voltadas à estimulação de habilidades e um modelo reabilitativo de cuidado, com enfoque centrado na criança e no déficit. Identifica-se uma potência em relação aos elementos que os Programas voltados à Primeira Infância oferecem, mas ao mesmo tempo as ações estão longe de construir uma prática de Intervenção Precoce a nível nacional.
Atendimento escolar hospitalar aos adolescentes com Insuficiência Renal Crônica
Authors: Fantacini Isabella Maria Cruz , Tinós Lúcia Maria Santos , Pedroso Cristina Cinto Araujo
Published: December 2022

O objetivo desta pesquisa foi entender como adolescentes com insuficiência renal crônica transplantados percebem os atendimentos escolares hospitalares. Trata-se de um estudo qualitativo, o qual teve por base o método fenomenológico. Os dados foram coletados por meio de entrevista com roteiro semiestruturado com três adolescentes e os responsáveis por dois deles. Os dados mostraram que apenas um adolescente dispôs do atendimento escolar hospitalar. Indicaram, também, a importância desse atendimento para a continuidade da escolarização. Contudo, os dados assinalaram que os cuidados ambulatoriais de alunos-pacientes, como hemodiálise e consultas, não garantem a eles o atendimento pelas Classes Hospitalares. Conclui-se que, apesar de a legislação garantir o direito ao atendimento escolar hospitalar dos alunos-pacientes, tal serviço ainda é restritivo e não abrange a todos os casos de alunos afastados das atividades escolares por problemas de saúde.
Calculating Wetland Interspersion Using Satellite Imagery
Authors:   , Sustaita Jessica
Published: December 2022

Birds are essential ecosystem drivers as they disperse seeds and nutrients, act as scavengers and decomposers, and fulfill prey and predator dynamics. Marsh bird populations have declined due to degenerative practices such as land development, invasive species introduction, and pollution. The National Audubon Society seeks to reverse and stop marsh bird declining populations and is currently working towards understanding how to measure marshland health and composition changes for ecological restoration projects. Wetland composition changes through time can indicate declining or improving health. Interspersion, a metric of land composition, has been used to measure the health of wetlands of interest. Previously, drone imagery was used to calculate wetland interspersion, but due to the large number of sites that need to be covered, many resources are required to collect and process drone data. In this project, Sentinel-2 10-meter resolution imagery and NAIP 0.6-meter resolution imagery were used to evaluate the feasibility of satellite imagery in calculating wetland interspersion rates. The NAIP data set was used to simulate high-resolution satellite imagery. To calculate interspersion, the imagery was classified using a pixel-based method and the support vector machine (SVM) classifier. Sentinel-2 imagery was broken down into three classes (i.e., Water, Vegetation, and Other). The weighted normalized difference water index (WNDWI) was used to mask and better classify water for Sentinel-2 imagery. NAIP imagery was divided into five classes (i.e., Water, Vegetation, Mud, Trees/Shrubs, and Other). The normalized difference vegetation index (NDVI) and texture layer were used to increase the classification accuracy of NAIP imagery. Interspersion was calculated by inputting the classified imagery into an R-script utilizing the Interspersion and Juxtaposition (IJI) formula. Sentinel-2 2020 imagery had higher interspersion values than Sentinel-2 2019 imagery, while NAIP 2020 imagery had higher interspersion values than 2019 and 2020 Sentinel-2 imagery.
Pelabelan Prima pada Graf Simpul Semi Total dari Graf Sikat
Authors: Putra Dany Riansyah , Kiftiah Mariatul , Fran Fransiskus
Published: December 2022

Artikel ini membahas mengenai pelabelan prima pada suatu graf sederhana  dengan himpunan simpul  dan himpunan sisi . Suatu graf  adalah graf prima jika terdapat pemetaan bijektif  sedemikian sehingga untuk setiap simpul  dan  yang bertetangga berlaku FPB. Selanjutnya, untuk graf sederhana yang berupa graf simpul semi total dari graf sikat, dikonstruksi suatu pelabelan prima dengan pembuktiannya memanfaatkan algoritma Euclidean. Hasil konstruksi menunjukkan bahwa graf simpul semi total dari graf sikat merupakan graf prima.

Kata Kunci:

Pemetaan; Graf Prima; Relatif Prima; Faktor Persekutuan Terbesar

 

Prime Labeling for a Semi-Total Point Graph of a Brush Graph

ABSTRACT

In this article, we investigate prime labeling for a simple graph G, where V(G) and E(G) are vertex set and edge set of G, respectively. A graph G is called a prime graph if there exists a bijective mapping  such that for each u and v are adjacent vertices in G then we have GCD. Furthermore, in terms of a semi-total point graph of a brush graph, a prime labeling was constructed using the Euclidean algorithm. As a result, this graph was a prime graph.
Penyelesaian Persamaan Bentuk Kuadrat Berbantuan Aplikasi Photomath Berdasarkan Sistem Bilangan Real
Authors: Meldi Nadya Febriani , Yani T. Ahmad , Suratman Dede
Published: December 2022

Penelitian ini bertujuan mendeskripsikan ketidaksesuaian istilah dalam prosedur pengerjaan matematika materi persamaan kuadrat berdasarkan aplikasi photomath yang disesuaikan dalam objek kajian dalam analisis real. Ketidaksesuaian yang dimaksud adalah prosedur pengerjaan yang kurang lengkap serta beberapa penamaan yang tidak dikenal dalam matematika. Penelitian ini merupakan penelitian kualitatif dengan metode deskriptif. Deskriptif dilakukan untuk mengungkap temuan ketidaksesuaian dari prosedur pengerjaan persamaan bentuk kuadrat yang dianalisis dari langkah pengerjaan yang tersaji pada aplikasi photomath. Langkah penyelesaian pada aplikasi photomath merupakan objek kajian serta aksioma lapangan yang menjadi dasar utama dalam proses kajian. Teknik analisis yang digunakan adalah tematik analisis. Hasil penelitian menunjukkan bahwa telah diperoleh empat langkah penyelesaian yang tidak bersesuaian pada disiplin ilmu matematika dalam menyelesaikan persamaan kuadrat pada aplikasi photomath, yaitu “keluarkan faktor”, “pindahkan satu suku ke ruas lainnya dan ubahlah tandanya (pindah ruas)”, ”hasil kali faktor-faktor adalah nol, setidaknya salah satu faktor adalah nol”, “bagi kedua ruas dengan suatu bilangan”.

Kata Kunci:

Penyelesaian Persamaan Bentuk Kuadrat; Aplikasi Photomath; Sistem Bilangan Real

 

Solving Quadratic Shape Equations Assisted Photomath Application Based on Real Number Systems

ABSTRACT

This study aims to describe the discrepancy of terms in the procedure for mathematical work of quadratic equation material based on the application of photomath adjusted in the object of study in real analysis. The discrepancies in question are incomplete workmanship procedures as well as some unknown naming in mathematics. This research was a qualitative research with a descriptive method. Descriptive is carried out to reveal findings of discrepancies from the procedure for working on quadratic shape equations analyzed from the work steps presented in the photomath application. The completion step in the photomath application was the object of study and the field axiom that was the main basis in the study process. The analysis technique used was thematic analysis. The results showed that four non-conforming solution steps have been obtained in the mathematical discipline in solving quadratic equations in the photomath application, namely "issue a factor", "move one tribe to another and change the sign (moving segments)", "the product of factors is zero, at least one of the factors is zero", "divide both fields by a number".
Reparar el mundo
Authors: López de Lizaga José Luis
Published: December 2022

Reseña de: Corine Pelluchon, Reparemos el mundo. Humanos, animales, naturaleza, s.l.: NED, 2022, 206 pp.
El naturalismo lógico de Dewey: ¿físico o cultural?
Authors: Vilanova Arias Javier
Published: December 2022

Tras un breve repaso a la propuesta de una Lógica Empírica de John Dewey, en la que trazo sus similitudes con la moderna Teoría de la Argumentación o Lógica Informal, examino el tipo de postura naturalista defendida en “Logic, The Theory of Inquiry” (1938), planteada en primer lugar como un naturalismo físico u orgánico que más tarde se abre a un naturalismo cultural o social. Examino críticamente la fusión de “causas naturales” y “razones culturales” de la aproximación de Dewey y concluyo que, si bien explica consistentemente la continuidad entre unos y otras, no resuelve la incompatibilidad entre perspectivas epistémicas.