bluuebunny/crossref_metadata_2025 huggingface dataset:
Locais para a prática do Turismo Espiritual: qual é a relação da espiritualidade com a natureza?
Authors:   Universidad de São Paulo (Brasil), Borges Amanda Alves , Schreinert Ivaneli ,   Universidad de São Paulo (Brasil), Mendonça Diego Pinto de ,   Universidade Estadual de Goiás (Brasil), Scrivano Pedro ,   Universidad de São Paulo (Brasil), Lobo Heros Augusto Santos ,   Universidad de São Paulo (Brasil)
Published: January 2023

Tourism in search of spiritual oneness with Nature is considered to be one of the new trends in tour‑ ism. Thus, the objective of this article is to contextualise research into Spiritual Tourism and to understand its relationship with Nature. Initially a review of the literature was carried out to find academic papers on this topic and to identify the relationship between the segment and nature, with subsequent analysis using the IRAMUTEQ® software. In total 92 scientific papers were identified, 26 countries studied, with the country most studied as India, followed by Peru and Indonesia, with Brazil, Kazakhstan and Thailand in joint fourth place. It is concluded that this segment depends implicitly on a close relationship with nature, since natural environments provide spiritual experiences. In addition, Spiritual Tourism has the potential to contribute to the sustainability of tourism, through conservation of nature and heritage.
Synthesis of nickel nanorods and their conversion into nanoparticles
Authors: Verma Devendra Kumar , Meena Jagram , Verma Sudhir Kumar
Published: January 2023

Reduction techniques have been used to create nickel nanoparticles. For the creation of nickel nanoparticles, nickel acetate has been used as a precursor and hydrazine hydrate as a reducing agent. Researchers examined about how calcination affected the size of nanoparticles. The nickel nanoparticles were characterized by SEM, EDX, FTIR, UV.Vis. DLS and XRD. The results conclude that the size of particles is highly affected by calcination. The sizes of particles were determined by XRD Scherrer equation and confirmed by SEM (Scanning Electron Microscope). It was found that the structure of the nanoparticles was also changed from nanorods to nanosphere particle. Particle size decreases/decomposes before the melting point of the metals. But particles combine after cooling from the decomposing temperature, so we get a heterogeneous mixture of spherical nanoparticles. Thus we need such a procedure so that we could stabilise the nanoparticles at high temperature to low temperature.
Effect of Polyvinylpyrrolidone Molecular Weight on the Synthesis of Silver Nanoparticles using a Polyol Method
Authors: Sianturi Pierre F. , Umar Aminah , Handayani Windri
Published: January 2023

Nanoparticles possess a great interest for researchers because of their unique physicochemical properties and their various applications. Polyol synthesis is a kind of synthesis that can produce silver nanoparticles. It has been known that the molecular weight of polyvinylpyrrolidone (PVP) can influence the size and shape of the nanoparticles produced. This research used a polyol synthesis to fabricate silver nanoparticles in which AgNO3, PVPMW= 55,000 and PVPMW= 360,000, ethylene glycol (EG) and natrium bromide (NaBr) were used as precursor, capping agent and additives respectively. The synthesis was carried out at 60 and 100 °C. The silver nanoparticles were characterized using Ultraviolet-visible (UV-Vis) spectrophotometer, Transmission Electron Microscopy (TEM) and X-Ray Diffraction (XRD). The UV-Vis spectrum showed the presence of AgNPs peak between 400-500 nm. The AgNPs synthesized using PVPMW=55,000 produce a higher absorbance spectrum than PVPMW=360,000. The TEM image confirmed the size and shape of AgNPs from using PVPMW= 55,000 showing sphere and anisotropic shape. This result proved the role of oxidative etching caused by the addition of NaBr which affects the form of AgNPs. In addition, the XRD results showed typical crystalline peaks of AgBr and Ag.
Rapid and environment friendly method for acid free iodination of industrially important organics using I2/NaClO3/CH3OH system
Authors: Sharma Vivek , . Nishtha , Kumar Rakesh , Agarwal D.D.
Published: January 2023

I2/NaClO3/CH3OH act as an efficient iodinating agent for many industrially important organics especially those that do not react well with acids. The method can be performed in an acidfree environment, which provides a practical alternative to other procedures avoiding the use of harsh reaction conditions such as high temperatures and pressures, long reaction time and costly metal catalysts. Furthermore, the ambient conditions, simple synthesis procedure and commercially feasible route for synthesis of iodoorganics make the present method more attractive compared to other iodination protocols.
Theoretical and Experimental Study on Molecular Docking, Spectral and Electronic Properties of N,N-Bis (Salysylaldehyde-2,3-Diamino-1-Propanol) Nanostructure
Authors: Kafi Dhaidan Kh.
Published: January 2023

In this study, theoretical and experimental properties (Structural, Spectral and Electronic Properties) and molecular docking of N,N- bis (salysylaldehyde-2,3- Diamino-1-propanol) molecule were studied. Timedependent density functional theory (TDDFT) and density functional theory (DFT) are employed for the theoritcal calculation. The composite's spectroscopic surveys were conducted using Proton nuclear magnetic resonance, FT-IR and UV/Vis spectroscopy techniques. The 1H NMR spectra for proton nuclear magnetic resonance have been examined with DMSO4 solvent. The FT-IR spectrum in rigid situation has been calculated to be between 4000-400 cm-1. The absorption spectra intensity of the composite with ethanol has been calculated to be between 200 and 800 nm. Scanning electron microscope (SEM) image has been study. Results demonstrated that the compound scanning electron microscopy image resembled a sphericals with particle size of 50 nm. The data structure, vibrational central modes, UV/V spectrum with 1H NMR isotropic chemical shifts of this molecule in the ground state were assessed utilizing the theory of functional density (thus DFT) and the B3LYP/6- 311G(d,p) basis group. The energies of reorganization for the hole and the electron have also been calculated. Finally, the assessment between the data of experiment and the results that have been calculated showed a good agreement. The inhibitory potential of the investigated compound was assessed against the protein PBP1 bacteria in a molecular docking. The chemical's carbonyl group was demonstrated to show a substantial role in antibacterial application; out of seven contacts, the carbonyl group made five bonds with the bacteria's main protein (Van der Waals bond and four good hydrogen bonds). This high bind energy was computed (-6.9 kcal/mol) indicating considerable antibacterial action.
Coenzyme Q10 nanoparticles prevents monocrotophos exposure mediated neurotoxicity by attenuating the histological alterations in rats
Authors: Kumar Amit , Singh Jagjeet , Solanki Ritu , Kumar Vijay
Published: January 2023

Organophosphate (OP) insecticide monocrotophos (MCP) is extremely hazardous to all living beings. This study shows that coenzyme Q10 nanoparticles (CoQ10NPs) can protect rats from the neurotoxicity caused by MCP-induced oxidative stress. In this study, male albino rats were divided into six groups i.e. control, CoQ10NPs low dose (50mg/kg b. wt) treated group, CoQ10NPs high dose (100mg/kg b. wt) treated group, MCP (4.5mg/kg b. wt) exposed group, CoQ10NPs low dose + MCP (50mg and 4.5mg/kg b. wt) treated group and CoQ10NPs high dose + MCP (100mg and 4.5mg/kg b. wt) treated group. The observation showed the depletion in the level of AChE activity and elevation in the levels of protein oxidation and lipid peroxidation which indicated the emerging of oxidative stress resulting in the induction of neurotoxicity. A significant decrease in the level of various enzymatic and non-enzymatic antioxidants like glutathione (GSH), catalase and superoxide dismutase (SOD) was observed in rat brain. The histopathological study indicated the major structural alterations in neuronal tissues of rats. These additionally backed up the induction of toxic effects caused by MCP exposure in rats. The prior co-treatment of CoQ10NPs along with MCP exposure depicted the significant protection from the oxidative stress generation and improved the structural and histological alteration in the rat brain. Hence, it can be concluded that CoQ10NPs have the strong therapeutic potential to reduce the MCP-induced oxidative stress, indicating their protective effects against MCP-induced neuronal cell damage in rats.
Synthesis and Characterization of Biologically active Oxadiazole derivatives
Authors: Madhavi B. , Sharma G. Veera Raghava
Published: January 2023

The aryl-substituted oxadiazole motif is present in natural products and in many biologically active compounds. In this present communication, novel substituted oxadiazole derivatives were reported along with their isolation and synthesis by the reaction of 5- phenyl-1,3,4-oxadiazole-2-amine with several aldehydes in the presence of DMF and MK-10 as a catalyst. The compounds were characterized by spectral data such as IR, 1H NMR and 13C NMR.
Synthesis of novel Schiff’s base functionalized trifluoromethyl pyridine derivatives and their anticancer activity
Authors: Chiranjeevi Abba , Sailu Betala
Published: January 2023

A series of novel Schiff’s base functionalized trifluoromethyl pyridine derivatives was prepared starting from pyridine 1. Compound 1 on reaction with sulphuric acid gave compound 2, which on chlorination followed by reaction with hydrazine hydrate produced compounds 3 and 4. Compound 4 on reaction with diverse substituted aromatic aldehyde gave Schiff’s base derivatives 5a-l. All the final compounds were evaluated for anti-cancer activity against four human cancer cell lines such as HeLa - Cervical cancer (CCL-2), COLO 205- Colon cancer (CCL-222), HepG2- Liver cancer (HB-8065) and MCF7 - Breast cancer (HTB-22). Promising compounds 5c and 5f have been identified.
Synthesis of 2-(2-amino-1,3 –dihydroxypropane-2-ylamino) benzoic acid
Authors: Bhaskar T. , Shanmugasundari M. , Vijaya P. , Banumathi N.
Published: January 2023

Bronopol is used as consumer product, insecticide broad spectrum antimicrobial compound and as an effective preservative agent as well as in a wide variety of industrial applications. Bronopol was very popular as a preservative in many consumer products such as shampoo and cosmetics. 2-(2-amino-1,3–dihydroxypropane-2-ylamino) benzoic acid was synthesized from 2-amino-2-bromo-propane-1,3-diol and aminobenzoic acid. The synthesized compound was isolated and purified by preparative TLC. A brown solid was obtained. The compound was characterized by NMR and FTIR spectroscopy. Computational studies are carried out at density functional theory (DFT) level on a personal computer using Gaussian 03 W program package.
Low power LED assisted effective photodegradation of cationic and anionic dyes by zinc phthalocyanine based 2D polyamide sensitized CuO photocatalyst
Authors: Rajappa Shwetha , Shivarathri Poornima Gubbi , Swamygowda Divyashree Kalenahally , Devendrachari Mruthyunjayachari Chattanahalli , Harish Makri Nimbegondi Kotresh
Published: January 2023

The present investigation details the synthesis and photocatalytic performance of an organic-inorganic hybrid system involving phthalocyanine-based 2D polyamide sensitized CuO photocatalyst in the presence of low-power LED visible light. Zinc phthalocyanine-based 2D polyamide (2D-ZnPcPA), CuO nanomaterial and their nanocomposites (2D-ZnPcPA@CuO) were successfully synthesized and characterized by Fourier transform infrared spectroscopy (FTIR) and Scanning electron microscopy (SEM) to understand the structure, size, morphology and optical properties. To examine the photodegradation capability of newly synthesized photocatalysts in the presence of the low-power white LED (16 W) as a source of visible light, cationic methylene blue (MB) and anionic congo red (CR) dyes were employed as modular pollutants. The impact of different parameters on photocatalytic activity such as photocatalyst dosage, contact time, pH of dye solution and photocatalyst re-usage, is examined. The results indicate that photosensitizing CuO with 2D-ZnPcPA improved photocatalytic performance for the photodegradation of MB and CR dyes substantially. The removal effectiveness of MB and CR under optimised conditions was determined to be greater than 96 and 93% in 90 minutes respectively.
A Model Ensemble Approach Enables Data-Driven Property Prediction for Chemically Deconstructable Thermosets in the Low Data Regime
Authors: AlFaraj Yasmeen , Mohapatra Somesh , Shieh Peyton , Husted Keith , Ivanoff Douglas , Lloyd Evan , Cooper Julian , Dai Yutong , Singhal Avni , Moore Jeffrey , Sottos Nancy , Gomez-Bombarelli Rafael , Johnson Jeremiah
Published: January 2023

Data science can accelerate materials discovery by learning composition-processing-performance models from pre-existing data sets, which then feed into active learning cycles in the laboratory. Thermoset polymer waste is a pressing environmental challenge that may be addressed by the accelerated discovery of new deconstructable variants; however, the combinatorial space of possible monomers, crosslinkers, additives, and manufacturing conditions is vast and Edisonian experimentation may struggle to find optimal designs. Moreover, data-driven strategies are limited for complex (co)polymers like thermosets because the training data is scarce and sourced from heterogeneous experimental approaches, resulting in overfit transferable models. Here, we introduce a novel closed-loop approach to the predictive design of chemically deconstructable thermosets that leverages experimental synthesis and characterization, machine learning, and virtual screening. Our computational model learns to map the molecular features of bifunctional silyl ether (BSE)-based cleavable comonomers to the thermal properties of the industrial thermoset polydicyclopentadiene (pDCPD). We address the challenges of limited data and overfitting by relying on both structural and information-rich domain-specific molecular features as inputs and by thoroughly quantifying model uncertainty. By training an ensemble of predictive models mixing multiple model architectures and parametrizations, our approach achieves predictions of a key thermoset parameter—the glass transition temperature—within less than 15 °C error over a wide temperature range with only 101 data points. The trained models were used to screen new possible BSE comonomer compositions and synthesis conditions, with promising combinations successfully validated experimentally. This work offers a closed-loop design process that we expect to be widely applicable to the discovery of deconstructable polymeric materials.
Thermal Annealing Effects on the Mechanical Properties of Bio-based 3D Printed Thermosets
Authors: Cortés-Guzmán Karen , Parikh Ankit , Sparacin Marissa , Adegoke Lauren , Ecker Melanie , Voit Walter , Smaldone Ronald
Published: January 2023

3D printing technologies can address many sustainability aspects of creating new materials, such as reduced waste and on demand production, which reduces the carbon footprint of transport and storage. Additionally, creating bio-based resins for 3D printing is a viable way of improving the sustainability of polymeric materials. Coupled with this, by using dynamic covalent chemistry (DCC), we can provide materials with smart properties like self-healing or reprocessability to either extend their usable lifetime or provide an alternative to the materials ending up in a landfill. Here, we report a series of completely bio-based aromatic resins for digital light projection (DLP) printing. By incorporating β-hydroxyesters and a zinc catalyst, the polymer networks can participate in transesterification reactions to provide self-healing capabilities or reprocessability. The self-healing abilities of these materials were characterized using optical microscopy, and the reprocessability using a hot-press. Additionally, by subjecting the printed thermosets to thermal annealing, considerable changes in the mechanical performance were observed leading to more than a 2000% increase in the Young’s modulus. The thermal behavior after annealing was also studied and a discussion on the effect of the structural differences between the aromatic monomers is proposed. These resin formulations address two of the key goals of sustainable materials: using renewable resources and obtaining recyclable materials while remaining competitive through their mechanical performance and compatibility with 3D printing technologies.
Flavin-conjugated Pt(IV) anticancer agents
Authors: Sánchez-Camacho Juan , Tadeo-Infante Sonia , Carrasco Ana C. , Scoditti Stefano , Martínez Álvaro , Barroso-Bujans Fabienne , Sicilia Emilia , Pizarro Ana M. , Salassa Luca
Published: January 2023

In situ activation of Pt(IV) to Pt(II) species is a promising strategy to control anticancer activity and overcome off-target toxicity linked to classic platinum chemotherapeutic agents. Herein, we present the design and synthesis of two new asymmetric Pt(IV) derivatives of cisplatin and oxaliplatin (1·TARF and 2·TARF, respectively) bearing a 2',3',4',5'-tetraacetylriboflavin moiety (TARF) covalently bonded. 1H and 195Pt NMR spectroscopy shows that 1·TARF and 2·TARF can be effectively activated into toxic Pt(II) species, when incubated with NADH, sodium ascorbate, and glutathione (GSH) in the dark and under light irradiation. Density functional theory studies of the dark Pt(IV)-to-Pt(II) conversion of 2·TARF indicate that the process involves first a hydride transfer from the donor to the flavin moiety of the complex, followed by electron transfer to the Pt(IV) center. When administered to MDA-MB-231 breast cancer cells pre-incubated with non-toxic amounts of ascorbate, 2·TARF displays enhanced toxicity (between one and two orders of magnitude), suggesting that generation of oxaliplatin can selectively be triggered by redox activation. Such an effect is not observed when 2 and TARF are co-administered under the same conditions, demonstrating that covalent binding of the flavin to the Pt complex is pivotal.
Site-Selective C–H Alkenylation of N-Heteroarenes by Ligand-Directed Co/Al and Co/Mg Cooperative Catalysis
Authors: Yoshikai Naohiko , Saito Yuri , Kikuchi Jun , Wang Chen
Published: January 2023

We report herein the design and development of cobalt/aluminum- and cobalt/magnesium bimetallic catalysts, supported by a phosphine/secondary phosphine oxide (PSPO) bifunctional ligand, for the site-selective C–H alkenylation of nitrogen-containing heteroaromatic compounds with alkynes. These catalysts enable the alkenylation of pyridine, pyridone, and imidazo[1,2-a]pyridine derivatives at the C–H site proximal to the Lewis basic nitrogen or oxygen atom, which represents a selectivity profile distinct from that of the previously developed cobalt–diphosphine/aluminum Lewis acid catalyst. The alkenylated products were obtained in moderate to good yields with syn-selectivity across various heterocycles as well as differently substituted internal alkynes. Kinetic isotope effect experiments on the pyridine C–H alkenylation suggest that the C–H activation occurs in an irreversible manner, while its relevance to the rate-limiting step depends on the reaction conditions. Density functional theory calculations indicate that ligand-to-ligand hydrogen transfer is the mechanism that operates commonly across the substrates used in the present study.
Protodemetalation of (bpy)Ni(II)–Aryl Complexes Shows Evi-dence for 5, 6, and 7-Membered Cyclic Pathways
Authors: Piszel Paige , Orzolek Brandon , Olszewski Alyssa , Rotella Madeline , Spiewak Amanda , Kozlowski Marisa , Weix Daniel
Published: January 2023

Protonation of C–M bonds and its microscopic reverse, metalation of C–H bonds, are fundamental steps in a variety of metal-catalyzed processes. As such, studies on protonation of C–M bonds can shed light on C–H activation. We present here studies on the rate of protodemetalation (PDM) of a suite of arylnickel(II) complex-es with various acids that provide evidence for a concerted, cyclic transition state for the PDM of C–Ni bonds and demonstrate that five, six, and seven-membered transition states are particularly favorable. Our data show that while the rate of protodemetalation of arylnickel(II) complexes scales with acidity for many acids, several are faster than predicted by pKa. For example, while acetic acid and acetohydroxamic acid are much less acid-ic than HCl, they both protodemetalate arylnickel(II) complexes significantly faster than HCl. Our data also shows how in the case of acetohydroxamic acid, a seven-membered cyclic transition state (CH3C(O)NHOH) can be more favorable than a six-membered transition state (CH3C(O)NHOH). Similarly, five-membered transition states, such as for pyrazole, are highly favorable as well. Comparison of transition-state polarization (from den-sity functional theory) compares these new nickel transition states to better-studied precious metal systems and demonstrates how the base can change the polarization of the transition state giving rise to opposing electron-ic preferences. Collectively, these studies suggest several new avenues for study in C–H activation as well as approaches to accelerate or slow protodemetalation in nickel catalysis.
INDEFINITENESS IN LANGUAGE
Authors: Елена Александровна Бобкова,
Published: January 2023

Как свойство бытия, включающего и язык, неопределенность изучается в философии и частных науках, в частности лингвистике, разрабатываются параметры ее классификации. Неопределенность противопоставлена определенности и охватывает намного больший объем сущностей по сравнению с определенностью. Языковая неопределенность имеет субъективный характер, отражая процесс и результаты мышления. Выделяются три основных вида неопределенности: референтная, признаковая и модальная. Разные языки по-разному распоряжаются богатым набором средств выражения неопределенности.

As property of being that includes language, indefiniteness is studied in philosophy and science, as well as in linguistics. Its classification is developed according to different parameters. Indefiniteness is opposed to definiteness and comprises a much larger scope of entities than definiteness. Language indefiniteness is subjective, it reflects the process and result of thinking. Three basic kinds of indefiniteness are discriminated: referential, modal and property indefiniteness. Different languages vary in their use of a great volume of means of indefiniteness all of them possess.
THE TERM “METACONCEPT” AND THE NOTIONS OF THE TERMINOLOGICAL SERIES WITH THE COMPONENT «META»
Authors: Анна Дмитриевна Ефимова,
Published: January 2023

В данной статье рассмотрены термины с компонентом «мета»; выявлены различия в понятиях «когнитивное сознание», «языковое сознание», «метаязыковое сознание», определены подходы к толкованию термина «метаконцепт» и его соотношение с термином «концепт», предпринята попытка описания транснационального метаконцепта.

In this article the terms with the component «meta» are considered; differences in understanding «cognitive consciousness», «language consciousness», «metalanguage consciousness» are revealed; approaches to the interpretation of the term «metaconcept» and its relationship with the term «concept» are defined; the attempt of the definition of transnational concepts is made.
EVOLUTION OF THE MOTHER-IN-LAW SYMBOLIC CONCEPT
Authors: Марина Владимировна Пименова, , Гульсайра Озгонбаевна Ибраимова,
Published: January 2023

Цель статьи - описать развитие структуры символического концепта тёща . В результате анализа девяти исторических источников было найдено шесть мотивирующих признаков концепта тёща , в их числе три относится к классу символических: ‘мать’, ‘родительница’, ‘рождать’, объединяемые в блок «(Божественное) материнство». Понятийные признаки концепта тёща следующие: 1. Мать дочери (‘женщина (средних лет)’, ‘жены’, ‘мать’, ‘родительница’, ‘рождать’, ‘тетя’); 2. Имеющая замужнюю дочь (‘в отношении зятя’); 3. Отношение (‘уважение’, ‘недовольство/ нерасположение’).

The purpose of the article is to describe the signs` development of the Russian symbolic mother-in-law concept structure. As a result of the analysis of nine historical sources, six motivating signs of the mother-in-law concept were found, including three that belong to the symbolic class: ‘mother’, ‘parent’, ‘to give birth’, combined into the block «(Divine) motherhood». The conceptual signs of the mother-in-law concept are as follows: 1. Daughter's mother ('woman (middle-aged)', 'wife', 'mother', 'parent', 'give birth', 'aunt'); 2. Having a married daughter (‘in relation to son-in-law’); 3. Attitude ('respect', 'dissatis-faction / dislike').
THE WORD IS A BACKGROUND OF THE CONCEPT: ON EVALD ILYENKOV’S IDEAS IN LINGUISTICS PERSPECTIVE
Authors: Андрей Александрович Яковлев,
Published: January 2023

Согласно идеям Э.В. Ильенкова, наиболее конкретное в представлении оказывается наиболее абстрактным в мышлении. Но абстрактное или конкретное не нужны человеку как таковые, они обусловлены особенностями осуществляемой деятельности. Поэтому антропоцентрическое изучение языка рассматривает слово в контексте сознания и деятельности и должно основываться на соотношении абстрактного / конкретного в значении слова, с одной стороны, и деятельности, с другой. При антропоцентрическом подходе к языковым явлениям теряет смысл вопрос «Абстрактно или конкретно значение данного знака?». В данном случае целесообразен вопрос: «Соответствует ли соотношение абстрактного и конкретного в знаке целям и условиям деятельности?» Ответ на этот вопрос может быть получен только через анализ результатов речевой деятельности.

The paper discusses the problem of the relationship of a word with a concept and representation. According to Evald Ilyenkov, the most concrete in representation turns out to be the most abstract in thought. However the abstract or the concrete are not needed by a person as such, but are conditioned by the peculiarities of the activity being carried out. With an anthropocentric approach to linguistic phenomena, the question «Is the meaning of this sign abstract or concrete?» becomes nonsense. In this case, the following question is appropriate: «Does the ratio of the abstract and the concrete in the sign correspond to the goal and conditions of activity?» The answer to this question can be obtained only through the analysis of the results of speech activity.
STYLISTIC MEANS OF CREATING THE CITY IMAGE IN THE POETRY OF BORIS PASTERNAK (in French translations)
Authors: Кристина Александровна Гудий, , Ольга Анатольевна Егорова,
Published: January 2023

Описаны специфика стилистических средств, использованных для описания города в произведениях Бориса Пастернака, а также степень адекватности и эквивалентности в реконструкции городского образа при переводе произведений поэта на французский язык. В поэзии Б. Пастернака образ города формируется через нанизывание метафор, музыкальных коннотаций, а также общим меланхолическим настроением, при этом доминантными средствами образности в данных произведениях выступают авторские метафоры и сравнения.

The paper studies stylistic specificity used to describe the city concept in Boris Pasternak's works in comparison with French translations. In Pasternak’s poetry, the city images are determined by the strings of personifying metaphors, musical connotations and the general melancholy of the city description, while the dominating means of imagery in these works are the author's metaphors and comparisons.
META- AND HYPERTEXT ORGANIZATION OF INFORMATION IN A TRANSLATED TEXT WITH A TRANSLATION COMMENTARY
Authors: Наталья Владимировна Захарова,
Published: January 2023

В статье предпринята попытка рассмотреть признаки мета- и гипертекстовой организации информации в переводном тексте с переводческим комментарием.

The article attempts to consider the signs of meta- and hypertext organization of information in a translated text with a translation commentary.
CHALLENGES IN TRANSLATING ONOMATOPOEIC UNITS OF MANGA COMICS INTO RUSSIAN
Authors: Сергей Александрович Колосов, , Ян Вячеславович Туманов,
Published: January 2023

В статье обсуждаются структурные, содержательные и функциональные аспекты ономатопеических элементов в японских комиксах манга. Анализируются типичные трудности, возникающие при передаче ономатопей на русский язык: специфика вёрстки поликодового текста, лингвистические особенности японских ономатопей, межъязыковая лакунарность, семантико-прагматические нюансы.

The paper discusses the structural, semantic and functional aspects of onomatopoeic units in Japanese manga comics. It analyzes typical challenges translators and localizers into Russian face: the specific layout of the multimodal text, linguistic features of Japanese onomatopoeia, interlingual lacunas, semantic and pragmatic nuances.
TOWARDS COGNITIVE STYLE ASPECTS OF THE LINGUISTIC PERSONALITY OF THE TRANSLATOR
Authors: Дарья Михайловна Терентьева, , Лев Геннадьевич Васильев,
Published: January 2023

В статье анализируются особенности языковой личности на основе концепции когнитивных стилей. Дается детальное рассмотрение лексико-синтаксических особенностей вторичной (переводческой) вербализации художественного текста носителями когнитивного стиля «когнитивная простота / сложность». Устанавливаются особенности выраженности содержательных и формальных компонентов переводного текста у представителей обоих полюсов.

The article analyses peculiarities of the linguistic personality based on the concept of cognitive styles. Detailed consideration is given to the features of the secondary (translator’s) verbalization of the text by the bearers of the cognitive style ‘cognitive simplicity / complexity’. Formal and contentive peculiarities of the resulting texts for both style poles are characterized.
THE POLITICAL AND LEGAL (DEMOCRATIC) SYSTEM OF THE RUSSIAN FEDERATION: RELEVANCE AND DIRECTIONS OF CONSTITUTIONAL MODERNIZATION
Authors: Владимир Иванович Крусс,
Published: January 2023

Рассматривается проблема конституционной модернизации политико-правовой (демократической) системы Российской Федерации; обосновывается актуальность такой задачи и возможные направления ее практического решения. Необходимое научно-правовое содействие конституционной трансформации должно учитывать реалии глобального кризиса миропорядка.

The problem of constitutional modernization of the political and legal (democratic) system of the Russian Federation is considered; the relevance of such a task and possible directions of its practical solution are substantiated. The necessary scientific and legal assistance to constitutional transformation should take into account the realities of the global crisis of the world order.
SOME ISSUES OF LEGAL PROTECTION OF RIGHTS AND FREEDOMS A HUMAN BEING IN THE CONTEXT OF THE DEVELOPMENT OF NANOBIOTECHNOLOGY
Authors: Татьяна Владимировна Кувырченкова, , Владимир Владимирович Черевко,
Published: January 2023

Проведено исследование способов правовой защиты прав и свобод личности в условиях развития нанобиотехнологий. В результате проведенного анализа установлено, что в Российской Федерации не принят федеральный закон, закрепляющий механизм правовой защиты прав и свобод человека при внедрении нанобиотехнологий, а также отсутствует действенный механизм государственного контроля за развитием и применением нанобиотехнологий. Некоторые положения в этой сфере содержатся в ряде федеральных законов, подзаконных актах и программах развития. В связи с изложенным, необходимо усовершенствование законодательства, а также создание эффективного механизма контроля за внедрением нанобиотехнологий.

The research was conducted what legal protection methods of human rights and freedoms exist in the context of the Nanobiotechnologies development. The results of the research show that the Russian Federation has not adopted a federal law fixing the mechanism of human rights and freedoms legal protection in Nanobiotechnologies implementation. It was also found that there is no effective mechanism of state control over the Nanobiotechnologies development and implementation. Some provisions in this area are included in a number of federal laws, by-laws and development programs. The conclusion is made that it is necessary to improve legislation, as well as to create an effective mechanism for monitoring the implementation of Nanobiotechnologies.
ON THE ADMINISTRATIVE AND LEGAL STATUS OF MIGRANT CHILDREN IN THE RUSSIAN FEDERATION
Authors: Зинаида Николаевна Столярова,
Published: January 2023

Исследуется правовое положение детей мигрантов, находящихся на территории Российской Федерации, в контексте действующих норм национальной правовой системы, а также норм международного права. Автором описаны два вида правовых режимов: присутствие несовершеннолетних иностранных граждан и лиц без гражданства на территории Российской Федерации при наличии в качестве сопровождающих законных представителей (родителей, опекунов и т.д.) и, что особенно актуально, без сопровождения последних. Анализируются наиболее актуальные вопросы, связанные с административно-правовым статусом детей мигрантов, затрагивающие их права, обязанности и ответственность указанной категории лиц на территории российского государства, в контексте документов стратегического планирования в Российской Федерации и угроз национальной безопасности.

This article examines the legal status of migrant children located on the territory of the Russian Federation in the context of the current norms of the national legal system, as well as the norms of international law. The author describes two types of legal regimes: the presence of foreign minors and stateless persons on the territory of the Russian Federation in the presence of accompanying legal representatives (parents, guardians, etc.) and, most importantly, unaccompanied by the latter. The article analyzes the most pressing issues related to the administrative and legal status of migrant children, affecting their rights, duties and responsibilities of this category of persons on the territory of the Russian state, in the context of strategic planning documents in the Russian Federation and threats to national security.
THE RIGHT OF A MINOR TO APPEAL AGAINST JUDICIAL ACTS: QUESTIONS OF THEORY AND PRACTICE
Authors: Олеся Витальевна Жукова,
Published: January 2023

Рассмотрены особенности реализации права на судебную защиту несовершеннолетних при пересмотре судебных актов в гражданском процессе и административном судопроизводстве. Проведен анализ норм гражданского процессуального законодательства и законодательства об административном судопроизводстве, исследованы вопросы обеспечения доступности правосудия при рассмотрении дел с участием несовершеннолетних в проверочных инстанциях.

The article considers the peculiarities of the realization of the right to judicial protection of minors during the revision of judicial acts in civil proceedings and administrative proceedings. The author analyzes the norms of civil procedural legislation and legislation on administrative proceedings, examines the issues of ensuring the accessibility of justice when considering cases involving minors in the verification instances.
PROBLEMS OF ADMINISTRATION OF THE SECTIONS OF THE UNIFIED LIST OF GOODS TO WHICH PROHIBITIONS OR RESTRICTIONS APPLY WHEN MOVING THROUGH THE BORDER OF THE EURASIAN ECONOMIC UNION
Authors: Анастасия Сергеевна Логинова,
Published: January 2023

Рассмотрен алгоритм и формы администрирования разделов Единого перечня товаров, к которым применяются запреты и ограничения при их перемещении через таможенную границу Евразийского экономического союза. Цель исследования заключается в выявлении правовых пробелов в таможенном законодательстве при администрировании разделов Единого перечня товаров. С помощью сравнительно-правового и формально-юридического методов автором выявлены проблемы администрирования разделов Единого перечня товаров таможенными органами РФ.

The algorithm and forms of administration of sections of the Unified List of goods, which are subject to prohibitions and restrictions when they are moved across the customs border of the Eurasian Economic Union, are considered. The purpose of the study is to identify legal gaps in customs legislation in the administration of sections of the Unified List of Goods. With the help of comparative legal and formal legal methods, the author identified the problems of administration of sections of the Unified List of Goods by the customs authorities of the Russian Federation.
REFLECTIONS ON THE SIGNIFICANCE OF LIMITATION IN THE CONTEXT OF A.S. PUSHKIN «SHOT»
Authors: Лидия Владимировна Туманова,
Published: January 2023

В статье представлено понимание значения сроков давности на основе яркого отображения в повести А.С. Пушкина «Выстрел» последствий их отсутствия. Обращено внимание на проблемные моменты относительно неимущественных требований и возможного злоупотребления правом.

The article presents an understanding of the meaning of statute of limitations on the basis of a vivid display in the story of A.S. Pushkin's «Shot» of the consequences of their absence. Attention is drawn to problematic issues regarding non-property claims and possible abuse of the right.
Özalp (Van) Ve Yakın Çevresinin Jeomorfolojik Özellikleri (Geomorphological Characteristics of Özalp (Van) and Its Neighborhood)
Authors: Seyitoğulları Mehmet Akif , Matpay Bülent
Published: January 2023

Araştırma sahası Türkiye’nin doğusunda Van iline bağlı Özalp ilçesi ve çevresini kapsamaktadır. Saha aynı zamanda Van Gölü kapalı havzası içinde olup İran’a komşudur. Bu çalışmanın amacı daha önce coğrafi bir bakışla çalışılmamış alanın jeomorfolojik özelliklerinin izah edilmesidir. Çalışmada arazi gözlem ve çalışmaları, uydu görüntüleri ve fotoğraflamalar, çeşitli haritalardan faydalanılmıştır. Sahanın bugünkü jeomorfolojik özelliklerini kazanmasında jeolojik özellikler ön plandadır. Bunun yanında flüvyal süreçlerin etkin olduğu sahada birbirinden farklı jeomorfolojik unsurlar tanımlanmıştır. Bunlar; yüksek aşınım yüzeylerine denk gelen dağlık ve tepelik alanlar, sırt ve yamaçlar, vadiler, birikinti konileri, boğazlar ve ova sahasıdır. Sahada paleozoikten günümüze kadar çeşitli yaşlarda kayaçlar bulunup bunlar tektonizmadan oldukça etkilenmiştir. Sahanın ana akarsuyu D-B eksenli uzanan Özalp Çayı’dır. Buna K-G yönlerinde birçok yan kol katılmaktadır. Ova alanı ana akarsuya uyumlu olup D-B ekseninde uzanmaktadır. Belirli zamanlarda yağış ve kar erimelerine bağlı olarak yan kollar aracılığıyla ana kola katılan akarsular nedeniyle su baskınları olabilmektedir. Keza bu baskınlar morfolojik olarak birikinti konilerinin yanlara doğru genişlemesini sağlamaktadır. Saha sert karasal iklimin yaşandığı bir yerdedir. Ancak son yıllarda dünyayı etkileyen iklim değişiklikleri araştırma sahasında nitel olarak yüzeysel/yeraltı su kaynaklarının kuruması bazen de ani su baskınları şeklinde kendini göstererek hem morfolojik yapıyı değiştirmekte hem de morfoloji üzerinde mevcut yerleşim yerlerini tehdit ettiği söylenebilir. Bu yüzden özellikle Özalp Çayı’na ait yakın sahalarda ve yan kolların ana kola bağlandığı ağız kısımlarında yerleşim yerlerinin kurulmaması önerilir.
Eski Amaçların Yeni Araçlarla Sürdürülmesi: Dijital Aktivizm Greenpeace Türkiye “NAe São Paulo” Analizi (Maintaining Previous Objectives Through New Instruments: Digital Activism Greenpeace Turkey “NAe São Paulo” Analysis)
Authors: Çıkın Mürüvvet
Published: January 2023

Geleneksel toplumların birbirleriyle haberleşebilmek için kullandığı araçlar günümüzde yerini yeni iletişim teknolojilerine bırakmıştır. Ağ toplumuna geçişle hayatımızın merkezi olan bu teknolojik araçlar, sosyal alanlarda pek çok dönüşüme neden olmuştur. Belli bir toplumsal konuya dikkat çekmek, çatışmalı konuları çözüme ulaştırmak uğruna bir araya gelerek kolektif bir güç oluşturan toplumsal hareketler de bundan nasibini almış ve aktivistler yeni iletişim teknolojileriyle birlikte alternatif eylem pratikleri arayışına girmiştir. Daha önceleri meydanlarda verilen karşıt güç savaşları dijital bir yapıya bürünerek dijital aktivizm olgusunu doğurmuştur. Çalışmada toplumsal hareketlerin interneti kullanma pratikleri üzerinde durularak, en bilinen çevreci toplumsal hareket olarak Greenpeace’in NAe São Paulo isimli gemiye yönelik aktivist eylemleri twitter üzerinden incelenmiştir. 3 Ağustos-14 Eylül 2022 tarihleri arasında gemiye yönelik atılan 39 tweet seçilmiştir. Araştırma ağırlıklı olarak nitel bir içerik analizine dayanmakla birlikte bazı niceliksel yönlerde analiz edilmiştir. Analizler ışığında yeni medyanın aktivist eylemleri duyurma, farkındalık yaratma, eylemcilere organize olma ve proaktif bir biçimde hareket edebilme imkanı sağladığı görülmüştür.
Türkiye de Sekülerleşme ve Tüketim Bağlamında Değişen Dindar Yaşam Biçimleri (Changing Religious Lifestyles in the Context of Secularization and Consumption in Turkey)
Authors: Asanatuci Zülal
Published: January 2023

Türk toplumunda dindar yaşam biçimlerinde meydana gelen değişim, sosyal ve siyasal alanda önemli bir tartışma alanı oluşturmuştur. Seküler ve dindar kesim tarafından farklı şekillerde yorumlanan bu değişimin sebebi olarak karşımıza çıkan en önemli olgulardan biri, tüketimdir. Modern yaşamın gerekliliklerinden biri olan tüketim şüphesiz toplumdaki her bireyin hayatına etki etmekte, içinde yaşadığı topluma entegre olmasını sağlayan bir tahakküm aygıtı olarak işlev görmektedir. Dolayısıyla bireyler kendilerine dayatılan tüketim kültürünü, toplumla bütünleşmek adına içselleştirmektedir. 1980’li yıllardan itibaren bir tüketim toplumuna dönüşmeye başlayan Türkiye’de de tüketim gerek dindar gerek seküler yaşam tarzına sahip bireyler arasında popülaritesini gitgide artırmaktadır. Bu çalışmada dindar bireylerin 1980’li yıllardan itibaren toplumsal alanda görünürlüğünün artmaya başlamasına paralel olarak tüketim olgusunu içselleştirme biçimleri ile dindarlıklarını yaşama biçimlerinde meydana gelen değişimlerin toplumsal hayata yansımaları, ilgili literatür çerçevesinde değerlendirilmiştir.
Reassessment of Coagulation Dysfunction And Its Impact on Classification of Hemophilia in Duhok City
Authors: Bunyan Ibrahim Eman , Adil Hanoon Rana
Published: January 2023

The X-linked inherited coagulation disorders, hemophilia A (Factor VIII deficiency) and hemophilia B (factor IXdeficiency) are the most prevalent coagulation dysfunction. The current study involved 75hemophlic patients who have been assigned into two groups; hemophilia A group consisted of 62 patients and hemophilia B group represented by 13 patients. Venous blood of participants was withdrawn, routine coagulation (PT and aPTT) and specific clotting function test (FVIII, FIX, FXI and FXII) were investigated. PT and aPTT kit (BIOLAB®, France) were used for the measurements of PT and aPTT times. STA®-DEFICIENT VIII and IX reagent kit with Immuno-depleted plasma for FVIII and FIX assay were used for determination of FVIII and FIX activity, respectively. The procedure followed the manufacturer instructions of each particular test.The present study was investigated blood group in a hemophilic patient also . The results revealed that hemophilia A patients exceeded the patients of hemophilia B and were represented by 82.7% and17.3% respectively. Furthermore, moderate cases of both types of hemophilia were greater than mild and severe cases. The results of this study indicated no significant correlation between the type of hemophilia from the one side and blood group and age from the other side. Conversely, significant correlation has been found between hemophilia and family history(P=0.001). The present study showed significant correlation between prolonged aPTT and hemophilia (P=0.00), while no-significant correlation has been found between prolonged PT and hemophilia. Finally, no significant correlation has been shown between age and the prolonged aPTT
Research on the Interior Decoration Characteristics of Peking Union Medical College Phase I Project
Authors: Xiong Qiqi , Zhang Bo , Zheng Yi , Li Xin
Published: January 2023

Peking Union Medical College was founded in the late Qing Dynasty and the early Republic of China. Since then, society and politics have been rapidly changing, and its architectural aesthetics reflect the idea of advocating the West and inheriting tradition. Through research and actual investigation, this paper summarizes the current status of its building from two aspects, interior decoration art and interior decoration technology, analyzes the interior decoration characteristics of Peking Union Medical College Phase I Project, and records the archives of Peking Union Medical College’s decoration technology.
Carbon Footprint Analysis of Buildings Based on LCA Theory Under Carbon Neutrality Goals: Taking the 3rd China International Solar Decathlon Competition as an Example
Authors: Yang Zeyu , Li Zao , Wang Yitian
Published: January 2023

This paper focuses on the design of residential buildings oriented to the efficient use of solar energy, and selects the entries HUI HOUSE of Hefei University of Technology and Lille I University of France in the 3rd China International Solar Decathlon China Competition, based on the theory of the life cycle assessment (LCA) of buildings, and analyzes the carbon footprint from four aspects: building materials production and transportation stage, building construction stage, building operation stage, and building demolition stage. Through the calculation of the carbon footprint of buildings, the socio-economic benefits of HUI HOUSE in carbon reduction were analyzed; the result of the calculation was that HUI HOUSE achieved carbon neutrality in the ninth year, and continued carbon reduction after that, contributing a cumulative total of 947.54 tons of carbon negative in the life cycle of buildings.
Quotas for catch of aquatic biological resources
Authors: Asanov A. N. , Li E. L. , Ageshina E. Yu.
Published: January 2023

The transformation of the system for distributing quotas for the extraction of aquatic biological resources (ABR) in quotas in Russia affects the interests of many parties. The new system of allocation of rights to catch ABR, which provides for quotas for investment, changes the established order in Russia in ﬁsheries, which caused discussions in the industry. Innovations reduced the level of monopolization of industrial ﬁshing, the development of shipbuilding and the ABR processing in Russia’s territory. The aim of the study is to identify the structure of interests of economic entities and the population within the framework of the current quota system of ABR catch in Russia on the example of the Far Eastern ﬁshery basin of the country. Being studying the materials for the paper, the authors used methods of scientiﬁc analysis and comparison in the research of the regulatory framework and the distribution of total allowable catches. There is an inductive method prevails in the statistical part of the study, and the monographic method allowed to combine the results obtained in the scientiﬁc paper. According to the analysis of the detailed structure and short-term dynamics of the allocation of quotas for the catch of ABR in the Far Eastern Federal District (FEFD), the authors found that the current system of distribution of rights does not ﬁt to global trends aimed at reducing the catch of the wild resource, the capacity and number of ﬁshing vessels. Innovations mainly reﬂect the interests of large ﬁsh producers to the detriment of small ones. However, the potential effect of introducing investment quotas is positive, as it ensures intersectoral cooperation. Against the background of unstable external demand for Russian products, this mechanism stimulates reorienting the activities of ﬁshers from foreign markets to domestic ones, from the sale of raw materials to processed products and making added value within the country, including in the FEFD.