bluuebunny/crossref_metadata_2025 huggingface dataset:
Impact of reactive settler models on simulated WWTP performance
Authors: Gernaey K.V. , Jeppsson U. , Batstone D.J. , Ingildsen P.
Published: July 2007

Including a reactive settler model in a wastewater treatment plant model allows representation of the biological reactions taking place in the sludge blanket in the settler, something that is neglected in many simulation studies. The idea of including a reactive settler model is investigated for an ASM1 case study. Simulations with a whole plant model including the non-reactive Takács settler model are used as a reference, and are compared to simulation results considering two reactive settler models. The first is a return sludge model block removing oxygen and a user-defined fraction of nitrate, combined with a non-reactive Takács settler. The second is a fully reactive ASM1 Takács settler model. Simulations with the ASM1 reactive settler model predicted a 15.3% and 7.4% improvement of the simulated N removal performance, for constant (steady-state) and dynamic influent conditions respectively. The oxygen/nitrate return sludge model block predicts a 10% improvement of N removal performance under dynamic conditions, and might be the better modelling option for ASM1 plants: it is computationally more efficient and it will not overrate the importance of decay processes in the settler.
On-line supervision and control of an aerobic SBR process
Authors: Ciappelloni F. , Mazouni D. , Harmand J. , Lardon L.
Published: July 2007

This paper presents a new software developed in MATLAB for analyzing on-line data of an aerobic SBR, detecting faults and, in this case, proposing the most probable causes of fault. Process diagnosis is achieved using a statistical method divided in two main phases: off-line model building and on-line data diagnosis. The off-line model identifies the correct working conditions of the system (standard operative conditions). It includes the characterization of the deviation of the system from these standard conditions in the case of changing in the biomass properties or carbon and nitrogen load characteristics. The on-line diagnosis aims at collecting and analyzing all the available data available through industrial sensors, and at classifying the behavior of each treatment cycle. The diagnosis performance of the proposed method is tested using a data set of an aerobic SBR pilot plant.
Modelling biological processes under anaerobic conditions through integrating titrimetric and off-gas measurements–applied to EBPR systems
Authors: Yuan Z. , Pratt S. , Zeng R.J. , Keller J.
Published: July 2007

An innovative method for modelling biological processes under anaerobic conditions is presented and discussed. The method is based on titrimetric and off-gas measurements. Titrimetric data is recorded as the addition rate of hydroxyl ions or protons that is required to maintain pH in a bioreactor at a constant level. An off-gas analysis arrangement measures, among other things, the transfer rate of carbon dioxide. The integration of these signals results in a continuous signal which is solely related to the biological reactions. When coupled with a mathematical model of the biological reactions, the signal allows a detailed characterisation of these reactions, which would otherwise be difficult to achieve. Two applications of the method to the enhanced biological phosphorus removal processes are presented and discussed to demonstrate the principle and effectiveness of the method.
Structural and functional design of WWTP operation decision support system with a case study
Authors: Xu L.J. , Shi H.C. , Ke X.Y.
Published: July 2007

This paper developes the WWTP operation decision support system (ODSS) to simulate the dynamic behavior of the WWTP treatment process based on ASMs (activated sludge models) and WWTP experiential knowledge. The novel structure and functions of ODSS can offer more flexible and general instructions to the WWTP operations. The three independent sub-systems, namely expert system, simulation system and training system, can cooperate to achieve many more functions such as operation alert, fault diagnosis, process simulation and so forth. The expert system based on the dynamic simulation, an essential part of WWTP ODSS, has been proved to be feasible and effective by the implementation at Fang Zhuang WWTP. Our results indicated that the WWTP ODSS has significant potential for improving plant performance and reducing treatment costs by assisting the operators at the decision-making level.
The microbial signature of drinking waters: myth or reality?
Authors: Harmand J. , Paulou L. , Desmoutiers J. , Garrelly L , Dabert P. , Godon J.J.
Published: July 2007

This paper presents a new software developed for analyzing single strand conformation polymorphism (SSCP) electrophoresis patterns delivered by the genetic analyzer ABI310 (Applied Biosystems). SSCP is a molecular typing technique based on the PCR amplification of microbial 16S rDNA and used for the monitoring of complex microbial ecosystems dynamics. The software – a home-made MATLAB toolbox called MODIMECO – developed for the analysis of SSCP patterns is presented. MODIMECO includes a number of basic signal processing abilities as well as largely used statistical tools such as the well known principal component analysis. The use of the SSCP for assessing the hypothesis of the existence of a microbial signature of drinking waters illustrates the typical advantages of using such software tools. Results are discussed and conclusions drawn.
Efficient modelling necessitates standards for model documentation and exchange
Authors: Gernaey K.V. , Rosen C. , Batstone D.J. , Alex J.
Published: July 2007

In this paper, problems related to simulation model documentation and model exchange between users are discussed. Complex simulation models have gained popularity in the environmental field, but require extensive documentation to allow independent implementation. The existence of different simulation platforms puts high demands on the quality of the original documentation. Recent experiences from cross-platform implementations with the ASM2d and ADM1 models reveal that error-free model documentation is difficult to obtain, and as a consequence, considerable time is spent on searching for documentation and implementation errors of various sources. As such, the list of errors and coding pitfalls provided for ASM2d and ADM1 in this paper is vital information for any future implementation of both models. The time needed to obtain an error-free model implementation can be significantly reduced if a standard language for model documentation and exchange is adopted. The extensible markup language (XML) and languages based on this format may provide a remedy to the problem of platform independent model documentation and exchange. In this paper the possibility to apply this to environmental models is discussed, whereas the practical model implementation examples corroborate the necessity for a standardised approach.
Towards a benchmark simulation model for plant-wide control strategy performance evaluation of WWTPs
Authors: Jeppsson U. , Rosen C. , Alex J. , Copp J. , Gernaey K.V. , Pons M.-N. , Vanrolleghem P.A.
Published: July 2007

The COST/IWA benchmark simulation model has been available for seven years. Its primary purpose has been to create a platform for control strategy benchmarking of activated sludge processes. The fact that the benchmark has resulted in more than 100 publications, not only in Europe but also worldwide, demonstrates the interest in such a tool within the research community In this paper, an extension of the benchmark simulation model no 1 (BSM1) is proposed. This extension aims at facilitating control strategy development and performance evaluation at a plant-wide level and, consequently, includes both pre-treatment of wastewater as well as the processes describing sludge treatment. The motivation for the extension is the increasing interest and need to operate and control wastewater treatment systems not only at an individual process level but also on a plant-wide basis. To facilitate the changes, the evaluation period has been extended to one year. A prolonged evaluation period allows for long-term control strategies to be assessed and enables the use of control handles that cannot be evaluated in a realistic fashion in the one-week BSM1 evaluation period. In the paper, the extended plant layout is proposed and the new suggested process models are described briefly. Models for influent file design, the benchmarking procedure and the evaluation criteria are also discussed. And finally, some important remaining topics, for which consensus is required, are identified.
Distributed virtual experiments in water quality management
Authors: Claeys F. , Chtepen M. , Benedetti L. , Dhoedt B. , Vanrolleghem P.A.
Published: July 2007

Since the complexity of virtual experiments (VEs) and their underlying models is constantly increasing, computational performance of monolithic software solutions is rapidly becoming insufficient. Examples of VEs are probabilistic design, model calibration, optimal experimental design and scenario analysis. In order to tackle this computational bottleneck, a framework for the distributed execution of VEs on a potentially heterogeneous pool of work nodes has been implemented. This framework was named WDVE (WEST distributed virtual experimentation) and is built on top of technologies such as C++, XML and SOAP. It was designed for stability, expandability, performance, platform-independence and ease of use.

Complex VEs are most often composed of mutually independent sub-experiments, which can be run concurrently. With WDVE, a complex VE that is executed on a so-called Master machine will therefore attempt to execute its sub-experiments on Slave machines that have previously registered with the Master. The process of submitting requests for the execution of sub-experiments is transparent and involves the transfer of a description of the experiment to be executed, and the resources that are needed for the execution (i.e., model and input data). WDVE is in many ways similar to the Grid Computing paradigm, which is currently receiving widespread attention. However, WDVE is more geared towards application within the scope of water quality management.
Management of agricultural nonpoint source pollution in China: current status and challenges
Authors: Wang Xiaoyan
Published: July 2007

Water quality in China shows an overall trend of deterioration in recent years. Nonpoint source pollution from agricultural and rural regions is the leading source of water pollution. The agricultural nonpoint source pollutants are mainly from fertilization of cropland, excessive livestock and poultry breeding and undefined disposal of daily living wastes in rural areas. Agricultural nonpoint sources contribute the main source of pollution to most watersheds in China, but they are ignored in management strategy and policy. Due to the lack of full understanding of water pollution control and management and the lack of perfect water quality standard systems and practical legislative regulations, agricultural nonpoint source pollution will become one of the biggest challenges to the sustainable development of rural areas and to society as a whole. The system for agricultural nonpoint source pollution control in China should include an appropriate legislation and policy framework, financing mechanisms, monitoring system, and technical guidelines and standards. The management of agricultural nonpoint source pollution requires multidisciplinary approaches that will involve a range of government departments, institutions and the public.
Distribution of dioxins in surface soils and river-mouth sediments and their relevance to watershed properties
Authors: Kanematsu M. , Shimizu Y. , Sato K. , Kim S. , Suzuki T. , Park B. , Hattori K. , Nakamura M. , Yabushita H. , Yokota K.
Published: July 2007

The dioxins toxic equivalent (TEQ) concentration in surface soils, river sediments and river-mouth sediments was measured by the CALUX assay in the Yasu and Ado River basins around Lake Biwa, Japan. In order to examine the distribution of dioxins in each watershed, we evaluated and compared the correlation between the dioxins TEQ concentration and the solid characteristics (i.e. organic carbon content and particle size distribution) of all samples. In both basins, the dioxins TEQ concentration in forest soil correspondingly showed a very good linear relationship to organic carbon content. On the other hand, the dioxins TEQ concentration in paddy field was significantly high, although organic carbon content was relatively low. Generally, the smaller particles have the higher dioxins TEQ concentrations in surface soils, and river sediments were composed of very coarse particles and had relatively low dioxins TEQ concentration. Therefore, we expected high dioxins TEQ concentration in river-mouth sediment, which was, however, not the case. Although the dioxins TEQ concentration in river-mouth sediments is low, the degree of dioxins pollution was different in each basin. The difference was considered to come from the difference of watershed properties including land use, river-slope, dam construction as well as the surface soil pollution.
Study of water quality distribution in Lake Biwa in consideration of runoff pollutant loads from its catchment basin
Authors: Ichiki A. , Sasaki A. , Sakata N. , Nakakura K. , Yamate H.
Published: July 2007

Many strategies for water quality conservation in Lake Biwa are being carried out mainly by reducing runoff pollutant loads into the lake. But influence of the runoff load reduction on the water quality in Lake Biwa has not been clarified enough so far. This study is aimed at discussing methodology to estimate water quality distribution in Lake Biwa using runoff pollutant loads from its basin. The runoff loads from the basin are calculated by Macro Model with GIS database of the Lake Biwa basin, and the water quality distribution in the lake is estimated by the spline technique with the calculated runoff loads. As a result, it has been proved that the methodology has enough reproducibility to estimate the water quality distribution in Lake Biwa and is available to examine the water quality in the lake.
Estimation of annual pollutant loadings in two small catchments and examination of their differences caused by regional properties
Authors: Fujii S. , Moriya M. , Songprasert P. , Ihara H.
Published: July 2007

A series of runoff surveys was conducted for more than one year in two small catchments of the Kamo River basin (75.4 km2) and the Takano River basin (66.8 km2) in Kyoto, Japan, which adjoin each other, and may have the same precipitation pattern. The investigation consisted of a high-frequency periodic survey, a long-term regular survey and a storm event survey. The survey results were compared with the regional properties of the basins, and the following results were obtained. (1) Pollutant loadings were successfully estimated as two portions of base discharge and storm events discharge from the survey results. (2) Estimated annual loading of the sites was 2.9–4.5, 1.3–1.8, 17–27, 1.3–2.2, 0.076–0.97 t/km2/y, respectively for CODMn, DOC, SS, TN and TP. (3) 52–53% of the whole flow, which was caused by rainfall events, conveyed 81–87, 68–73, 92–95, 64–67, 76–81% of the whole loading, respectively for CODMn, DOC, SS, TN and TP. (4) Differences of regional properties in two basins cause different runoff patterns, but the differences in runoff patterns also depend on the rainfall patterns. In general, a more urbanized basin receives early and strong influence of precipitation on the storm event runoff.
Water chemistry gradient in a degraded bog area
Authors: Iqbal R. , Akimoto S. , Tokutake K. , Inoue T. , Tachibana H.
Published: July 2007

Surface and ground water was sampled in a degraded bog area 36 times during 1993–2003 at Five representative points: point E (natural area with Sphagnum as the main vegetal cover), point W (boundary between the natural and degraded areas), point W' (area installed with vinyl sheeting), point WW (area where Sasa thrives), and point NC (area with naturally formed ditches). Analysis of variance (ANOVA) was conducted for parameters measured in surface water and ground water at 0.5, 1.0, 1.5, and 2.0 m depths. “Sampling point” (i.e. locations along the degradation gradient) accounted for most of the variation in surface and ground water chemistry. It accounted for 30–80% of the total variation in pH, electrical conductivity, ammonia, dissolved nitrogen, major cations (Na+, K+, Ca2+ , Mg2+ ), alkalinity and dissolved organic carbon. “Year” accounted for more variation in nitrate, nitrite, chloride, and sulfate than the sampling point did, but the variation in dissolved reactive phosphorus and dissolved phosphorus concentrations was not based on any of the calculated variables.
Evaluation of nutrient loads from a mountain forest including storm runoff loads
Authors: Kunimatsu T. , Otomori T. , Osaka K. , Hamabata E. , Komai Y.
Published: July 2007

Water quality and flow rates at a weir installed on the end of Aburahi-S Experimental Watershed (3.34 ha) were measured once a week from 2001 to 2003 and in appropriate intervals from 30 min to 6 h during five storm runoff events caused by each rainfall from 8 mm to 417 mm. The average annual loads of total nitrogen (TN) and total phosphorus (TP) were calculated to be 19.0 and 0.339 kg ha−1 y−1 from the periodical data by using the integration interval-loads method (ILM), which did not properly account for storm runoff loads. Three types of L(Q) equations (L=aQb) were derived from correlations between loading rates L and flow rates Q obtained from the periodic observation and from storm runoff observation. L(Q) equation method (LQM), which was derived from the storm runoff observation and allowed for the hysteresis of discharge of materials, gave 9.68 and 0.159 kg ha−1 y−1, respectively, by substitution of the sequential hourly data of flow rates. L(R) equation (L=c(R−r)d) was derived from the correlations between the loads and the effective rainfall depth (R−r) measured during the storm runoff events, and L(R) equation method (LRM) calculated 9.83±1.68 and 0.175±0.0761 kg ha−1 y−1, respectively, by using the rainfall data for the past 16 years. The atmospheric input-fluxes of TN and TP were 16.5 and 0.791 kg ha−1 y−1.
Evaluation of hydrological processes in a mountainous small basin using a quinone biomarker
Authors: Fujita M. , Haga H. , Nishida K. , Sakamoto Y.
Published: July 2007

An applicability of quinone biomarker to the analysis of hillslope runoff was investigated. At first, quinone profiles of three streams as well as a hillslope runoff in a forested headwater catchment were compared. The quinone composition of hillslope runoff differed from others. Moreover, there were remarkable differences in quinone profile of hillslope runoff under different rainfall conditions. Then, the behavior of quinone biomarker during the increase and decrease of hillslope runoff after a rainfall event was examined. The fractional changes in Q-9 (H2), Q-10 (H2), Q-11, MK-6 and MK-10 suggested the effect of interflow.
Nitrogen removal function of recycling irrigation system
Authors: Hitomi T. , Yoshinaga I. , Feng Y.W. , Shiratani E.
Published: July 2007

The purpose of this study was to clarify the nitrogen (N) purification capacity of a paddy field in a recycling irrigation system. Irrigation water was sampled at 12-h intervals during the irrigation period from April to September 2003. In addition, ponded water in a paddy field was collected at three points (inlet, centre and outlet). Total amounts of N were 30.7 kg ha−1 in inflow and 27.8 kg ha−1 in outflow. Thus, the net outflow load was −2.9 kg ha−1. The N removal rate constant when N removal is expressed as a 1st-order kinetic was 0.017–0.024 m d−1. This value is close to values of wetlands and paddy fields in the literature. We found a good correlation between recycling ratio and N removal effect. These results indicate that the recycling irrigation system accumulates N in the irrigation/drainage system, and thus the paddy field does a good job of water purification by removing N.
Recycling mineral nutrients to farmland via compost application
Authors: Liu Y.Y. , Ukita M. , Imai T. , Higuchi T.
Published: July 2007

Increased cultivation of farmland has resulted in nutrient deficiency and consequently fertility degradation of soils. This research examined the application of composted wastes in terms of the feasibility and effectiveness of recycling plant essential minerals. Minerals in composts (derived from sewage sludge, livestock excrement, and municipal solid wastes, respectively) and in amended soils were observed. Ca/Mg ratios in amended soils and the effect of compost applications (mineral nutrients and heavy metals) on plant uptake were also studied. Results showed that composts, especially those made from sewage sludge and livestock excrement, were richer in mineral nutrients but also contained more heavy metals than untreated soil. The increase in some elements and plant-growth-essential Ca/Mg ratios were found in amended farmlands, implying that compost applications have made up for the nutrient deficiency and have adjusted chemical conditions of the soil. The soil contamination from heavy metals was noticeable. However, some results showed that the large existence of mineral nutrients and heavy metals in soils has caused no significant increase in the plant uptake of elements. The controlled composting process and farmland uses are believed necessary for reducing the heavy metal accumulation in agricultural plants.
Study on purification mechanism in soil penetration facility for effluents from urban area and control strategies
Authors: Yamada K. , Ujiie D. , Nishikawa K.
Published: July 2007

In this study, demonstration experiments for removal of pollutants from road surface runoff during storm events were carried out under natural conditions in an outdoor pilot-scale soil penetration facility. In general, soil retains suspended matter and removes dissolved matter by adsorption. However, issues such as reduced purification capacity resulting from clogging and recovery of purification capacity during periods of intermittent supply of the storm water affect the removal efficiency of pollutants. Therefore, this study aimed at clarifying purification mechanisms during storm events and understanding how the structural characteristics of the soil penetration facility affect purification capacity based on long-term continuous measurements. In addition, modeling the purification mechanism under changing characteristics of rainfall in the long-term was undertaken.
Lead isotope ratios in urban road runoff
Authors: Shinya M. , Funasaka K. , Katahira K. , Ishikawa M. , Matsui S.
Published: July 2007

Lead isotopic analyses of road runoff and airborne particulate matter have been carried out to elucidate sources of lead pollution at urban and suburban sites. While lead is often observed in road runoff in suspended form, suspended particle size had no relation to the lead isotopic distribution, as a result of comparison between runoff samples with total suspended solids and those with minute particles passed through a 75 μm sieve. Lead isotope ratios in airborne particulate matter in urban areas fell within a wider range than those in road runoff. Since there was little difference of the ratios between a heavy traffic-flow site and residential sites, airborne lead derived from vehicle exhaust was found to make little contribution to the contamination of road runoff. On the other hand, the ratios in road runoff at a suburban site showed the same range as those at an urban site. Lead in road runoff was therefore suggested to be produced on site by traffic related substances, such as tire wear, other than vehicle exhaust.
The characteristics and measuring technique of refractory dissolved organic substances in urban runoff
Authors: Wada K. , Yamanaka S. , Yamamoto M. , Toyooka K.
Published: July 2007

It is considered that refractory dissolved organic substances have caused an increase in the COD concentration in Lake Biwa in recent years. We investigated the organic matter in the first flush of stormwater runoff from a road in the watershed area of the lake, and studied the possibility of improvement in the water environment from that aspect. After percolating the stormwater through soil, we analyzed organic substances fractionated by using GPC-TC. And we examined the effect of removal of organic substances by comparing the peak height before and after percolation. In the result of the experiments, we found that soil infiltration reduced the refractory dissolved organic substance and we successfully designed a system for a simple and easy experimental facility to treat urban runoff.
Correlation analysis among highway stormwater pollutants and characteristics
Authors: Han Y.H. , Lau S.L. , Kayhanian M. , Stenstrom M.K.
Published: July 2007

Stormwater runoff from highway land use is a common non-point source of pollutants. A large quantity of highway stormwater runoff characteristics were collected in California during the past three years. Correlations among various water quality parameters and constituents were performed using data sets collected over the 2000–2001, 2001–2002, and 2002–2003 wet seasons for 18, 21 and 23 storm events at three highway sites in west Los Angeles, California. In addition, statistical and graphical correlation analysis of the mass first flush ratio (MFF) with storm characteristics was made to determine if the first flush is related to site or storm characteristics. The results and analyses performed indicate that (1) TSS correlates well with most particulate-bound metals. However, TSS was poorly correlated with most other pollutants. (2) Strong correlations were also observed among dissolved and total metals; DOC, COD, TKN and oil and grease; conductivity and Cl. (3) Total metals, COD and DOC were generally well correlated with mass first flush, suggesting that BMPs that treat the early portion of runoff have an opportunity to remove high concentrations of these pollutants. Keywords Correlation analysis; highway stormwater runoff; mass first flush; storm characteristics
Characteristics of particle-associated PAHs in a first flush of a highway runoff
Authors: Aryal R.K. , Furumai H. , Nakajima F. , Boller M.
Published: July 2007

Runoff monitoring of six rainfall events was carried out in a highway, Winterthur, Switzerland focusing on first flush (runoff volume up to 2.88 mm). Six runoff events were used to investigate the characteristics of particle-associated PAHs in first flush. The fine fraction (<45 μm) had a relatively higher contribution than the coarse fraction. A significant contribution of the coarse fraction was observed at some periods when the runoff flow rapidly increased. Fluctuation of PAH content during a runoff event was significant in the coarse fraction and, in contrast, the PAH content in the fine fraction was less fluctuating. The weighted average PAH content in each event ranged from 17 to 62 μg/g in total SS, from 23 to 54 μg/g in the fine fraction and from 16 to 84 μg/g in the coarse fraction. The loading of particle-associated PAHs from the first flush of highway runoff ranged from 0.06 to 0.22 g/ha in a total of 12 PAH species. Keywords First flush; highway runoff; PAH content; PAH profiles; suspended solids
Evaluation of AnnAGNPS in cold and temperate regions
Authors: Das S. , Rudra R.P. , Goel P.K. , Gharabaghi B. , Gupta N.
Published: July 2007

Identification of the pollution sources and understanding the processes related to runoff generation and pollution transportation is effective for the water quality management and selection of the Best Management Practices. The ANNualized AGricultural Non-Point Source (AnnAGNPS) model was applied to a watershed in Southern Ontario to evaluate the hydrology and sediment component from the non-point sources. The model was run for two years (1998 to 1999); one year's data was used to calibrate and the second year's data was used for validation purposes. The model has under predicted runoff amount and over predicted the sediment yield. However, the simulated runoff and sediment yield compared fairly well with the observed data indicating that the model had an acceptable performance in simulation of runoff and sediment. The study is still in progress to assess its performance for estimation of TMDL and improvements needed for the model to use under Ontario conditions.
Nonlinear regression approach to evaluate nutrient delivery coefficient
Authors: Bae M.S. , Ha S.R.
Published: July 2007

Implementation of the Korean Total Maximum Daily Load Act calls for new tools to quantify nutrient losses from diffuse sources at a river basin district scale. In this study, it was elucidated that the nonlinear regression model (NRM) reduces the uncertainty of the boundary conditions of the water quality model. The NRM was proposed to analyse the delivery coefficients of surface waters and retention coefficients of pollutants. Delivery coefficient of pollution load was considered as a function of two variables: the watershed form ratio, Sf, which is a measurable geomorphologic variable and the retention coefficient, ϕ, which is an empirical constant representing the basin-wide retarding capacity of pollutant wash-off. This model was applied on the Geum River, one of the major basins in South Korea. The QUAL2E was used to simulate stream water quality using NRM. In this paper, we elucidate the possibility to use a nonlinear regression model for delivery and retention of nutrients in a drainage basin characterized as both data-rich and data-poor, and the magnitude of the nutrient loads and sources has been uncertain for a long time. Keywords Delivery coefficient; diffuse pollution; pollution load runoff; retention coefficient
Integrating principles of nitrogen dynamics in a method to estimate leachable nitrogen under agricultural systems
Authors: Burkart M. , James D. , Liebman M. , van Ouwerkerk E.
Published: July 2007

Surplus nitrogen (N) in ground and surface water is of concern in intensive agricultural regions. Surplus N leaches during lengthy periods where annual crop systems are used in temperate regions. This paper presents a model to estimate the surplus N available for leaching to ground water beneath agricultural systems and applies the model to watersheds in an intensive maize and soybean production system. The model utilizes commonly available georeferenced data on soils, crops, and livestock, making it applicable to watersheds in many regions. The model links stocks of N in soil, crops, livestock, fertilizer and the atmosphere. Nitrogen flow centers on exchange between the soil N stocks. Nitrogen mineralization rates are defined for three soil organic matter pools, crop residue, and manure based on carbon:N ratios. Nitrogen exports from the system are harvested crops, livestock and losses to the atmosphere. Application of the model in 26 Iowa watersheds finds surpluses of 18 to 43 kg-N/ha. Surpluses exceeded measured annual nitrate-N loads in regional streams by amounts equivalent to denitrification rates in groundwater. Deficits in soil N were sufficiently small to suggest that the system is in equilibrium with soils of the region.
Application of monitored natural attenuation to remediate a petroleum-hydrocarbon spill site
Authors: Kao C.M. , Huang W.Y. , Chang L.J. , Chen T.Y. , Chien H.Y. , Hou F.
Published: July 2007

Contamination of groundwater by petroleum-hydrocarbons is a serious environmental problem. The Monitored Natural Attenuation (MNA) approach is a passive remediation to degrade and dissipate groundwater contaminants in situ. In this study, a full-scale natural bioremediation investigation was conducted at a gasoline spill site. Results show that concentrations of major contaminants (benzene, toluene, ethylbenzene, and xylenes) dropped to below detection limit before they reached the downgradient monitor well located 280 m from the spill location. The results also reveal that natural biodegradation was the major cause of the observed contaminant reduction. The calculated natural first-order attenuation rates for BTEX and 1,2,4-trimethylbenzene (1,2,4-TMB) ranged from 0.051 (benzene) to 0.189 1/day (1,2,4-TMB). Evidence for the occurrence of natural attenuation includes the following: (1) depletion of dissolved oxygen, nitrate, and sulfate; (2) production of dissolved ferrous iron, sulfide, and CO2; (3) decreased BTEX concentrations and BTEX as carbon to TOC ratio along the transport path; (4) increased alkalinity and microbial populations; (5) limited spreading of the BTEX plume; and (6) preferential removal of certain BTEX components along the transport path. Additionally, the biodegradation capacity (44.73 mg/L) for BTEX and 1,2,4-TMB was much higher than other detected contaminants within the plume. Hence, natural attenuation can effectively contain the plume, and biodegradation processes played an important role in contaminant removal.
Comparison of several methods for BAP measurement
Authors: Nakajima J. , Murata Y. , Sakamoto M.
Published: July 2007

It has been more important for management of water quality to estimate the amount of bioavailable phosphorus (BAP) in suspended solids (SS) entering lakes and estuaries. AGP test or extraction by 0.1 mol l−1 NaOH (C-BOD) is widely used. Recently, highly bioavailable phosphorus (HBAP) was introduced to indicate a more easily soluble and bioavailable fraction using successive extraction by 0.1 mol l−1 HCl and 0.1 mol l−1 NaOH. New biologically measured BAP (B-BAP) using bacterial respiration activity was introduced in this paper. B-BAP was estimated from oxygen uptake rate (OUR), which was measured by a respiratory meter for BOD measurement using a pressure sensor. B-BAP is useful for a rapid and direct measurement of phosphorus bioavailability. B-BAP, HBAP and C-BAP in river SS were measured and compared with each other. The percentages of HBAP and B-BAP to PP were large in the urban river, while the percentage of NaOH-P or C-BAP was large in the rivers flowing in agricultural areas. By comparison with phosphorus fractions in paddy soil and activated sludge it was suggested that SS in the rivers flowing in agricultural areas mainly consisted of clay, silt or sand, while the SS in the urban river consisted of a large percentage of organic particles as well. Phosphorus in SS was suggested to be more easily bioavailable in the urban river than the rivers in agricultural areas. The ratio of C-BAP/B-BAP was large in the rivers in agricultural areas and small in the urban river. As HBAP contents were almost similar to B-BAP contents in the river SS, HBAP can be a suitable index of phosphorus indicating easily and rapidly the bioavailable fraction in SS. Keywords Bacterial respiration; bioavailable phosphorus; eutrophication; lake water management; oxygen uptake rate; phosphate analysis
Evaluation of atmospheric deposition of nitrogen to the Feitsui Reservoir in Taipei
Authors: Lo S.L. , Chu H.A.
Published: July 2007

This research studied how the air pollutants of urban areas affect a neighboring reservoir and its water quality. Through the atmospheric dispersion process, air pollutants move from the Taipei metropolitan to the Feitsui reservoir and enter the water body through dry and wet depositions. ISCST3 (Industrial Source Complex Short Term Model), an air quality model, was used to simulate dispersion, dry deposition and wet deposition of the air pollutants. Then the nitrogen loadings to the Feitsui Reservoir were evaluated. The results indicate that wet deposition places a greater burden than dry deposition does on the water body. Wet and dry deposition of NH4+ together make up a rather large proportion of the total pollution. The ratio ranged from 21.9 to 25.2%. Those of nitrate make up a smaller proportion, ranged from 2.0 to 2.3%. If we take indirect deposition into account and calculate the NO3− and NH4+ together, the proportion is 15.9–17.6%.
Parathion degradation and toxicity reduction in solar photocatalysis and photolysis
Authors: Zoh K.-D. , Kim T.-S. , Kim J.-G. , Choi K. , Yi S.-M.
Published: July 2007

The solar photocatalytic degradation of methyl parathion was investigated using a circulating TiO2/solar light reactor. Under solar photocatalysis condition, parathion was more effectively degraded than solar photolysis and TiO2-only conditions. With solar photocatalysis, 20 mg/L of parathion was completely degraded within 60 min with a TOC decrease of 63% after 150 min. The main ionic byproducts during photocatalysis recovered from parathion degradation were mainly as NO3−, NO2− and NH4+, 80% of the sulphur as SO42−, and 5% of phosphorus as PO43−. The organic intermediates 4-nitrophenol and methyl paraoxon were also identified, and these were further degraded in solar photocatalytic condition. Two different bioassays (Vibrio fischeri and Daphnia magna) were used to test the acute toxicity of solutions treated by solar photocatalysis and photolysis. The Microtox test using V. fischeri showed that the toxicity expressed as EC50 (%) value increased from 5.5% to >82% in solar photocatalysis, indicating that the treated solution is non-toxic, but only increased from 4.9 to 20.5% after 150 min in solar photolysis. The acute toxicity test using D. magna showed that EC50 (%) increased from 0.05 to 1.08% under solar photocatalysis, but only increased to 0.12% after 150 min with solar photolysis, indicating the solution is still toxic. The pattern of toxicity reduction parallels the decrease in TOC and the parathion concentrations.
Pretreatment and biotreatment of saline industrial wastewaters
Authors: Tuin B.J.W. , Geerts R. , Westerink J.B. , van Ginkel C.G.
Published: July 2007

Wastewater from an Akzo Nobel production site contains more than 50 g/l total dissolved salts, mainly chlorides and sulphates, and is currently being treated after 10–20× dilution. Biological treatment of undiluted or less diluted wastewater is very desirable for environmental and economic reasons. Possibilities were investigated in laboratory scale reactors to treat this highly saline and high strength wastewater aerobically, either after long adaptation or after removing part of the salts by a pretreatment. Adaptation and selection from mixed activated sludge populations took approximately 40 days to finally achieve a COD removal in aerobic treatment of 55–65% at two times dilution (11–16 g/l chloride and 5–7 g/l sulphate). Undiluted wastewater was not treatable. A higher removal percentage (>80%) was possible at the original high salt concentration only when the sludge load was limited to approximately 0.4–0.5 kg COD/kg sludge/day. A longer adaptation time was required. Nanofiltration (NF) and crystallization could be used as a pretreatment to remove and recover up to 80% of the sulphate in the form of crystallized Glauber salt. Recovery strongly depended on the sulphate and chloride concentration in the NF concentrate and on crystallization temperature. The salt (sulphate) reduction through the NF improved the removal efficiency of a consecutive biotreatment only at a relatively low chloride level, demonstrating that the combination of nanofiltration-crystallization-aerobic biodegradation is less feasible for very saline wastewaters. Anaerobic pretreatment of saline waters turned out to be rather sensitive to high salinities. Only wastewater diluted to 10 g/l chloride could be treated well: sulphate concentration decreased by 80% and COD by 40%. Removal efficiencies of the combined anaerobic-aerobic treatment were approximately 80–85%, proving that this was a feasible route for 2–3× diluted wastewater. The study has shown that several alternatives are available for treatment of the very saline wastewaters at a much lower degree of dilution than currently practiced.
On-site treatment of high-strength alcohol distillery wastewater by a pilot-scale thermophilic multi-staged UASB (MS-UASB) reactor
Authors: Yamada M. , Yamauchi M. , Suzuki T. , Ohashi A. , Harada H.
Published: July 2007

A pilot-scale multi-staged UASB (MS-UASB) reactor with a working volume of 2.5 m3 was operated for thermophilic (55°C) treatment of an alcohol distillery wastewater for a period of over 600 days. The reactor steadily achieved a super-high rate COD removal, that is, 60 kgCOD m−3 d−1 with over 80% COD removal. However, when higher organic loading rates were further imposed upon the reactor, that is, above 90 kgCOD m−3 d−1 for barely-based alcohol distillery wastewater (ADWW) and above 100 kgCOD m−3 d−1 for sweet potato-based ADWW, the reactor performance somewhat deteriorated to 60 and 70% COD removal, respectively.

Methanogenic activity (MA) of the retained sludge in the thermophilic MS-UASB reactor was assessed along the time course of continuous run by serum-vial test using different substrates as a vial sole substrate. With the elapsed time of continuous run, hydrogen-utilizing MA, acetate-utilizing MA and propionate-fed MA increased at maximum of 13.2, 1.95 and 0.263 kgCOD kgVSS−1 d−1, respectively, indicating that propionate-fed MA attained only 1/50 of hydrogen-utilizing MA and 1/7 of acetate-utilizing MA. Since the ADWW applied herewith is a typical seasonal campaign wastewater, the influence of shut-down upon the decline in sludge MA was also investigated. Hydrogen-utilizing MA and acetate-utilizing MA decreased slightly by 3/4, during a month of non-feeding period, whereas propionate-fed MA were decreased significantly by 1/5. Relatively low values of propionate-fed MA and its vulnerability to adverse conditions suggests that the propionate degradation step is the most critical bottleneck of overall anaerobic degradation of organic matters under thermophilic condition.
Membrane bioreactors in industrial wastewater treatment – European experiences, examples and trends
Authors: Cornel P. , Krause S.
Published: July 2007

In wastewater treatment, micro- and ultra-filtration membranes are used for the separation of the activated sludge (biomass) from the treated water. This offers the advantages of a complete removal of solids and bacteria, as well as most of the viruses, namely those attached to the suspended solids. Compared to the conventional activated sludge process (CAS) this technology allows a much higher biomass concentration (MLSS) whereby the reactor volume and the footprint decreases. With increasing MLSS, the viscosity of the sludge increases, which leads to reduced oxygen transfer rates. Depending on the type of membrane and membrane module, the pre-treatment has to be more sophisticated to prevent clogging and sludging of the modules.

Due to fouling and scaling, the flux through the membranes will decrease with time. The decrease depends on the water quality as well as on the measurements taken to minimize fouling. Mainly, three strategies are available: lowering the flux, increasing the “crossflow” and cleaning of the membranes. Different strategies including backwash and chemical cleaning “in situ”, “on air” and “ex situ” can be applied. It has been proven more effective to apply preventive regular cleaning.

Besides the energy demand for oxygen supply – which is typically in the range of 0.3 kWh/m3 for municipal wastewater – the energy for fouling prevention is substantial. Immersed membranes need approximately 0.4 to 1 kWh/m3 for the coarse bubble aeration, whereas tubular modules require 1 to 4 kWh/m3 pump energy.

For proper design of industrial wastewater treatment, the verification of applicability and the development of adequate cleaning strategies, it is a precondition to run pilot tests for a sufficient period of time with the wastewater to be treated. More than 100 industrial wastewater treatment membrane bioreactors (MBR) are in operation in Europe. Data of three case studies for a sewage sludge dewatering plant in UK (12,000 m3/d), a plant for the treatment of pharmaceutical wastewater in Germany (3,600 m3/d), as well for revamping of an chemical WWTP >2,000 m3/d in Italy, are given.

MBRs will be used in future wherever high quality effluent is required, because of a sensitive receiving water body or due to the fact of water reuse as process water. MBRs are a perfect pre-treatment in industrial applications when further treatment with nanofiltration or reverse osmosis is considered.

The technique is advanced and can be applied both in municipal and industrial wastewater treatment. Higher operational costs must be balanced by superior effluent quality.
Development of MBR with reduced operational and maintenance costs
Authors: Annaka Y. , Hamamoto Y. , Akatsu M. , Maruyama K. , Oota S. , Murakami T.
Published: July 2007

To reduce MBR O&M costs, a new MBR process that conducts efficient simultaneous biological nitrogen and phosphorus removal (BNR) was developed. In the development of this process, various approaches were taken, including reduction of power demand, chemical consumption and sludge disposal costs. To address power demand reductions, air supply requirements for membrane cleaning were reduced. The process adopted an improved membrane that requires less air for cleaning than conventional membranes. It also introduced cyclic aeration, which alternately supplies washing air to the two series of membrane units. Adoption of biological phosphorus removal eliminated chemical costs for phosphorus removal and contributed to the reduction of sludge disposal costs. By combining these technologies, compared to conventional MBR processes, an approximately 27% reduction in O&M costs was achieved.
Performance of membrane bioreactors used for the treatment of wastewater from the chemical and textile industries
Authors: Baumgarten S. , Schröder H.Fr. , Pinnekamp J.
Published: July 2007

Within the scope of the study, nine waste waters from the chemical and textile industries were treated in bench-scale (laboratory scale) and small-scale (pilot scale) membrane bioreactors. Depending on wastewater characteristics, the resulting performance varied significantly. It was observed that MBR effectiveness was determined primarily by the degree of biodegradability of the wastewater. In the course of several months of operation, no significant changes associated with the complete retention of the biomass by the membranes were observed. In some cases, it was possible to improve effluent quality by using smaller molecular separation sizes. The flux performance of the membrane modules was dependent on wastewater composition. Occasionally, non-degradable macromolecular substances concentrated in the bioreactor, resulting in strongly reduced filterability and flow performance of the membrane modules, consequently also reducing the economic viability of the process. The results demonstrate that wastewater-specific pilot tests are absolutely necessary, in particular if the technology is to be used for new applications.
Domestic wastewater treatment with a small-scale membrane bioreactor
Authors: Abegglen C. , Siegrist H.
Published: July 2007

A small-scale membrane plant for treating the domestic wastewater of a four-person household is presented. The membrane bioreactor has been in operation for 6 months and achieves elimination rates of 90, 95 and 80% for total organic carbon, chemical oxygen demand and total nitrogen, respectively. Only a small amount sludge is produced. The permeate is reused for flushing toilets and has a yellowish colour. After investigations of the effluent quality, decolourisation of the permeate, energy efficiency and control strategies in the first year, urine will be treated separately in an automated precipitation reactor where struvite is produced to improve the overall phosphate removal of the plant.