bluuebunny/crossref_metadata_2025 huggingface dataset:
Cast Stainless Steels
Authors: Blair Malcolm
Published: December 2018

This article reviews the properties of cast steels that are specified for liquid corrosion service at temperatures above and below 650 deg C. Stainless steel castings are usually classified based on their resistance to corrosion and heat and generally fall into one category or the other. The article describes alternate methods for classifying cast stainless steels, one is based on grade designations, the other on microstructural analysis. It also addresses heat treatment, pointing out its similarities with the thermal processing of wrought materials, and establishes the importance of mechanical properties in material selection. The article presents information on the selection process and provides a detailed list of heat-resistant cast steels and alloys. It also includes key manufacturing characteristics to aid in foundry and welding-related decisions.
Polycrystalline Cast Superalloys
Authors: Erickson Gary L.
Published: December 2018

The initial cast superalloy developments in the United States centered on cobalt-base materials. Nickel-base and nickel-iron-base superalloys owe their high-temperature strength potential to their gamma prime content. For polycrystalline superalloy components, high-temperature strength is affected by the condition of the grain boundaries and, in particular, the grain-boundary carbide morphology and distribution. Vacuum induction melting offers more control over alloy composition and homogeneity than all other vacuum melting processes. The primary purification reaction occurring in the process is the removal of melt contained oxygen by means of a reaction with carbon to form carbon monoxide. A number of casting processes can provide near-net shape superalloy cast parts, but essentially all components are produced by investment casting. The solidification of investment cast superalloy components is precisely controlled so that the microstructure, which ultimately determines mechanical properties, remains consistent. Heat treating cast superalloys involves homogenization and solution heat treatments or aging heat treatments.
Strategic Materials Availability and Supply
Authors: Stephens Joseph R.
Published: December 2018

This article reviews some of the trends in superalloy development as they relate to U.S. strategic materials availability and the aerospace industry. It discusses the supply sources and availability of strategic materials and summarizes the status of U.S. resources and reserves. The article presents a list of several superalloys that have been used in gas turbine engines or that are emerging as replacements because of the promise of increased operating temperatures and higher efficiencies for the aircraft of the future. It concentrates on the objectives, results, and methodology of the NASA Conservation of Strategic Aerospace Materials (COSAM) program.
Classification and Basic Metallurgy of Cast Iron
Authors: Stefanescu Doru M.
Published: December 2018

This article discusses the classification schemes for cast irons and describes the characteristics of major categories, including gray iron, white iron, ductile iron, compacted graphite iron, mottled iron, malleable iron, and austempered ductile iron. It also discusses some of the basic principles of cast iron metallurgy. When discussing the metallurgy of cast iron, the main factors of influence on the structure include chemical composition, cooling rate, liquid treatment, and heat treatment. In terms of commercial status, cast irons can be classified as common cast irons and special cast irons. Special cast irons differ from the common cast irons mainly in the higher content of alloying elements. Alloying elements can be added in common cast iron to enhance some mechanical properties. They influence both the graphitization potential and the structure and properties of the matrix.
Properties of Cast Aluminum Alloys
Authors: Kearney A.L.
Published: December 2018

This article is a compilation of property data for standard grades of cast aluminum alloys. Data are provided for mechanical, thermal, and electrical properties. The listing for each alloy includes commercial names, chemical compositions, applications, relevant specifications, fabrication characteristics, and mass characteristics.
Copper Powder Metallurgy Products
Authors: Klar Erhard , Berry David F.
Published: December 2018

This article briefly reviews the subject of copper-base powder-metallurgy (P/M) products in terms of powder production methods (atomization, oxide reduction, electrolysis, and hydrometallurgy) and the product properties/consolidation practices of the major applications. Of the four major methods for making copper and copper alloy powders, atomization and oxide reduction are presently practiced on a large scale in North America. The article provides information on the mechanism, production, properties, composition and applications of different types of copper-base P/M products, including self-lubricating sintered bearings, structural parts, oxide-dispersion-strengthened copper, sintered metal friction materials, and porous filters.
Tin and Tin Alloys
Authors: Hampshire William B.
Published: December 2018

Tin is produced from both primary and secondary sources. This article discusses the chemical compositions, production, properties, microstructure and applications of tin and tin alloys. The major tin alloys discussed here are tin-antimony-copper alloy (pewter), bearing alloy, solder alloy and other alloys containing traces of tin. Data on tin consumption in the United States is presented graphically.
Zinc and Zinc Alloys
Authors: Barnhurst Robert J.
Published: December 2018

This article describes the zinc and zinc alloys for decorative and functional applications. It focuses on the types of zinc coatings, namely, hot dip galvanizing, electrogalvanizing, metallizing, and mechanical galvanizing. The article covers the uses of zinc alloy castings, including pressure die castings, and gravity castings. It details the wrought products of zinc and zinc alloys, including flat-rolled products, wire-drawn products, extruded products, and forged products. The article also describes various properties of zinc alloys, including mechanical, thermal, electrical, chemical, and magnetic properties. The listing for each alloy includes chemical compositions, relevant specifications, mass characteristics, and fabrication characteristics.
Titanium and Titanium Alloy Castings
Authors: Eylon Daniel , Newman Jeremy R. , Thorne John K.
Published: December 2018

The combination of high strength-to-weight ratio, excellent mechanical properties, and corrosion resistance makes titanium the best material choice for many critical applications. This article commences with a description of the historical perspective of titanium casting technology. It discusses the various types of molding methods, namely, rammed graphite molding, and lost-wax investment molding. The article provides information on the casting design, melting, and pouring practices, and describes the microstructure, hot isostatic pressing, heat treatment, and mechanical properties of Ti-6AI-4V alloy. It also talks about the chemical milling and weld repair, and describes the product applications of titanium alloy castings. Tensile properties, standard industry specifications, and chemical compositions of various titanium alloy castings are tabulated.
Beryllium
Authors: Stonehouse A. James , Marder James M.
Published: December 2018

Beryllium is a metal with an unusual combination of physical and mechanical properties that make it particularly effective in optical components, precision instruments, and specialized aerospace applications. Almost all of the beryllium in use is a powder metallurgy (P/M) product. Beginning with an overview of the mining and refining processes of beryllium, this article discusses powder production and consolidation methods, beryllium grades and their designations, and the protective measures that have been enacted to reduce exposure to beryllium.
Germanium and Germanium Compounds
Authors: Adams J.H.
Published: December 2018

Germanium is a semiconducting metalloid element found in Group IV A. Germanium is used in the field of electronics, infrared optics, and in the fields of gamma ray spectroscopy, catalysis, and fiber optics. This article discusses the sources, manufacturing, and processing of germanium, and focuses on the chemical properties of various germanium compounds, including germanium halides, germanates, germanides, germanes, inorganic, and organogermanium compounds. It also tabulates the physical, thermal, electronic, and optical properties of germanium, and explains the economical aspects and specifications of germanium. The article describes the analytical and test methods of germanium, including gravimetric method, titrimetric method, and spectral method. It provides a short note on toxicology, and concludes with the uses of germanium in different fields.
Metallic Glasses
Authors: Johnson W.L.
Published: December 2018

Metallic glasses can be prepared by solidification of liquid alloys at cooling rates sufficient to suppress the nucleation and growth of competing crystalline phases. This article presents a historical survey of the study of metallic glasses and other amorphous metals and alloys. This includes a discussion of synthesis and processing methods, structure and morphology, and a description of the electronic, magnetic, thermodynamic, chemical, and mechanical properties of metallic glasses. In addition, the article describes the development of metallic glasses as materials for technical applications.
Thermocouple Materials
Authors: Wang T.P.
Published: December 2018

This article provides an in-depth review of thermocouples and the metals from which they are made. It explains how dissimilar metal conductors in contact at opposite ends can generate an electromotive force if the junctions are heated or cooled to different temperatures. The article discusses thermocouple circuits and instrumentation, calibration methods, insulation requirements, operating ranges, measurement errors, and maintenance procedures. It also provides property data and emf curves for common metals and thermocouple types, and contains information on color coding used around the world.
Principles of Superconductivity
Authors: Warnes William H.
Published: December 2018

Superconductivity has been found in a wide range of materials, including pure metals, alloys, compounds, oxides, and organic materials. Providing information on the basic principles, this article discusses the theoretical background, types of superconductors, and critical parameters of superconductivity. It discusses the magnetic properties of selected superconductors and types of stabilization, including cryogenic stability, adiabatic stability, and dynamic stability. The article also focuses on alternating current losses in superconductors, including hysteresis loss, penetration loss, eddy current loss, and radio frequency loss. Furthermore, the article describes the flux pinning phenomenon and Josephson effects.
Large Probes for Characterization of Industrial Quenching Processes
Authors: Liščić Božidar , Singer Saša
Published: December 2018

This article provides a discussion on probes for laboratory tests and resultant curves of industrial quenching processes. It describes the scope of the tests, and the calculation of heat-transfer coefficient (HTC) based on the tests. The article highlights the differences between the laboratory tests and characterization of industrial quenching processes. It reviews the importance of initial heat-flux density and first critical heat-flux density. The theoretical principle behind and the purpose of the temperature gradient method are discussed. The article provides information on the design of the probe, heat-extraction dynamics, and influence of wetting kinematics. It also includes discussions on the simplified 1-D temperature-distribution model, calculation of the HTC, and the finite-volume method for the heat-conduction equation.
Plasma (Ion) Nitriding and Nitrocarburizing of Steels
Authors: Elwar Jan , Hunger Ralph
Published: December 2018

Plasma (ion) nitriding is a method of surface hardening using glow-discharge technology to introduce nascent (elemental) nitrogen to the surface of a metal part for subsequent diffusion into the material. This article describes the procedures and applications of plasma nitriding methods of steel. These methods include direct-current plasma nitriding, pulsed-current plasma nitriding, and active-screen plasma nitriding. The article reviews cold-walled and hot-walled furnaces used for plasma nitriding. It provides information on the importance of controlling three process parameters: atmosphere, pressure, and part temperature. The article includes a discussion on the influence of nitrogen concentration on case structure formation on nitrided steel, and explains the significance of microstructure, hardness, and fatigue strength on nitrided case. It also discusses processing, laboratory studies, and applications of nitrocarburizing of steel.
Fluidized-Bed Quenching
Authors: Gao Weimin , Kong Lingxue , Hodgson Peter
Published: December 2018

The fluidized bed provides a means for exchanging heat between a metal part, the solid particles, and the fluidizing gas and which is viable for quenching. This article briefly considers the design aspects of the gas distributor, plenum, container, immersed cooling tubes and surface air spray cooling system in the quenching fluidized bed. It describes the fundamental factors affecting quenching power of the fluidized beds, namely, particle size, particle material, fluidizing gas composition, fluidizing gas flow rate, bed temperature and pressure, and the arrangement of quenched parts with respect to one another and to the bed. The article discusses the advantages, disadvantages, various applications and processes, including conventional batch quenching, two-step batch quenching, and continuous quenching of fluidized bed quenching, in detail.
Design and Fabrication of Induction Coils for Heating Bars, Billets, and Slabs
Authors: Stambaugh Joe
Published: December 2018

This article is a compilation of best practices, materials, and techniques for the design and manufacture of modern induction forge coils. It presents the basics of induction coil design along with various design considerations, namely, copper tube selection, water flow considerations, and brazing and fabricating the copper coil winding for heating billets, bars, and slabs. The article describes refractory selection criteria and the methods of mounting and securing the induction coil winding, and presents general refractory installation guidelines for induction heating applications. It provides information on curing, form removal, dryout, and coil refractory seasoning. Wear rails that are designed to prevent damage to the coil refractory and subsequent coil winding are also discussed. The article concludes with a discussion on preventive maintenance practices for induction forging coils.
Using Infrared Thermometers to Control Temperature During Induction Heating
Authors: Lappe Vern
Published: December 2018

This article provides an overview of the basic theory of infrared (IR), including emissivity and E slope. It explains how the IR thermometer works, and provides guidance on choosing a thermometer, in particular, deciding between a two-color and a single-wavelength thermometer and installing and maintaining them. The article discusses typical applications of induction heating, and describes how the IR thermometer controls the temperature. While the majority of the article discusses spot thermometers, thermal imagers, which are fast and are used for both research and control of the induction process, are also addressed.
Metallurgy of Induction Hardening of Steel
Authors: Matlock David K.
Published: December 2018

This article focuses on induction hardening process for heat treating operations specifically designed to result in proper microstructure/property combinations in either localized or in the final parts. It briefly reviews the heat treating basics for conventional heat treating operations of steels with iron-carbon phase and transformation diagrams. The article provides a summary of the important temperatures, definitions, and microstructural constituents associated with heat-treated steels. Basic transformation characteristics of heat-treated steels are reviewed. The article also discusses the various aspects of steel heat treatment by induction processing, and concludes with a description of steel alloys for induction processing.
Tempering of Induction Hardened Steels
Authors: Rudnev Valery , Fett Gregory A. , Semiatin S. Lee
Published: December 2018

Tempering of induction-hardened steel is a form of subcritical heat treatment, primarily carried out to increase ductility, toughness, and dimensional stability, to relieve residual stresses, and to obtain specific values of mechanical properties. This article describes tempering with emphasis on different time-temperature exposure requirements for furnace and induction tempering. It discusses two parametric methods for correlating equivalent time-temperature condition: Hollomon-Jaffe tempering correlation and Grange-Baughman tempering correlation. The article describes different methods of induction tempering, namely, single-shot, progressive or continuous, scanning, and static heating methods. The effects of induction heating variables and hardenability on tempering response are examined. The article also provides examples of how tempering affects the mechanical properties of induction-hardened steels.
Electromagnetic Problem Solutions
Authors: Barglik Jerzy , Dołęga Dagmara
Published: December 2018

Electromagnetic problem solutions are based on the macroscopic theory of the continuous model for the electromagnetic field (EMF). It is described by a system of integral or partial differential equations for five vector quantities, namely, electric field strength, electric flux density, current density, magnetic field strength, and magnetic flux density. This article describes the behavior of the EMF by Maxwell's equations in integral or differential forms. It discusses the definition of potentials; methods of mathematical modeling; boundary conditions; and energy, power density, and electromagnetic forces.
Thermal Problem Solutions
Authors: Barglik Jerzy , Dołęga Dagmara
Published: December 2018

Temperature is a typical parameter characterizing the heating level of any particle belonging to a heated body. The basic problem of heat transfer computation is associated with appropriate determination of heat transfer coefficients. This article provides a discussion on the basic equations, initial and boundary conditions, and multiple reflection phenomena of mathematical modeling. These boundary conditions include the Dirichlet, Neumann, and Henkel conditions.
Induction Heating of Billets, Rods, and Bars
Authors: Brown Doug , Rudnev Valery , Dickson Peter
Published: December 2018

This article provides a rough estimate of the basic parameters, including coil efficiency, power, and frequency in induction heating of billets, rods, and bars. It focuses on the frequency selection for heating solid cylinders made of nonmagnetic metals, frequency selection when heating solid cylinders made from nonmagnetic alloys, and frequency selection when heating solid cylinders made from magnetic alloys. The article describes several design concepts that can be used for induction billet heating, namely, static heating and progressive/continuous heating. It presents the four major factors associated with the location and magnitude of subsurface overheating: frequency, refractory, final temperature, and power distribution along the heating line. The article summarizes the pros and cons of using a single power supply. It also reviews the design features of modular systems, and concludes with information on the temperature profile modeling software.
Melting of Glasses and Oxides
Authors: Jakovics Andris , Pavlovs Sergejs
Published: December 2018

This article provides an overview of the models of two induction heating devices, namely, induction crucible furnace (ICF) and induction furnace with slits, or segmented and water-cooled induction furnace with cold crucible (IFCC). These devices are used for melting with skull formation of low-conductivity materials such as glasses and oxides. The article presents the governing equations and boundary conditions for ICF and IFCC modeling. It includes a discussion on three electromagnetic field models in IFCC, namely, two-dimensional (2-D), quasi-three-dimensional, and three-dimensional (3-D) models. The article provides information on the simulation of skull formation in IFCC, and elucidates the transient axisymmetrical 2-D model and the transient 3-D model, including the primary results achieved for both glasses and skull formation.
Induction Heating in Optical Fiber Draw Processing
Authors: Hawtof Daniel W.
Published: December 2018

The optical fiber preform is a long cylinder of glass that contains core and cladding glasses. This article describes the relationship between the peak furnace temperature, fiber draw tension, and fiber draw speed. It focuses on temperature requirements such as product viscosity, hot zone length, temperature profile, and heating cycle to draw the glass. The article provides information on process gases in the draw induction furnace, insulation package for induction heating operations, and furnace design and scalability. It reviews the key factors for the selection of susceptor materials, namely, cost, temperature cycling, and the impact on the product.
Heat Treating of Magnesium Alloys
Authors: Abbott Trevor
Published: December 2018

Magnesium alloys are used predominantly for high-pressure die-cast applications in which the use of a deliberate heat treatment is uncommon. This article provides information on the heat treatment designations for magnesium alloys. It describes the effects of grain size on magnesium alloys and the relationship between hardness and mechanical properties of the alloys. The article discusses the effects of elements such as aluminum, zinc, manganese, rare earths, and yttrium, on precipitation hardening. It describes the types of heat treatment for magnesium alloys, including annealing, stress relieving, solution treating and aging, and reheat treating. The article also discusses the preventive measures for the common problems encountered in heat treating magnesium alloys; and the evaluation of the effectiveness of heat treating procedures. In addition, it presents the processing steps involved in the heat treatment of magnesium alloys and in the prevention and control of magnesium fires.
Quenching of Aluminum Alloys
Authors: MacKenzie D. Scott , Bogh Niels , Croucher Tom
Published: December 2018

Quenching refers to the rapid cooling of metal from the solution treating temperature, typically between 465 and 565 deg C (870 and 1050 deg F) for aluminum alloys. This article provides an overview on the appropriate quenching process and factors used to determine suitable cooling rate. It describes the quench sensitivity and severity of alloys, quench mechanisms and the different types of quenchants used in immersion, spray, and fog quenching. The article provides a detailed description of the quench-factor analysis that mainly includes residual stress and distortion, which can be controlled by proper racking. It concludes with information on agitation and the quench tank system used in the quenching of aluminum alloys.
Retrogression and Reaging
Authors: Robinson J.S.
Published: December 2018

Retrogression and reaging (RRA) is an established form of postquench aging heat treatment. RRA treatments can be applied to precipitation-hardened aluminum alloys that are used in aerospace applications. This article provides information on the development background of RRA and the steps involved in the RRA treatments. It discusses the process descriptions, applications, microstructural consequences, and limitations of RRA. In addition, the article describes the influence of RRA on mechanical properties.
Alkaline Cleaning
Authors: Cormier Gerald J.
Published: December 2018

Alkaline cleaning is a commonly used method for removing a wide variety of soils from the surface of metals. This article focuses on the composition, operating conditions, and test and control of alkaline cleaners, as well as equipment used and their application methods. It describes the mechanisms of alkaline cleaning, such as saponification, displacement, emulsification and dispersion, and metal oxide dissolution. The article concludes with information of the safety and environmental considerations in the usage of alkaline cleaners.
Finishing Methods Using Defined Cutting Edges
Authors: Venkatesh V.C. , Enomoto S.
Published: December 2018

This article focuses on precision and ultraprecision finish machining techniques that make use of defined cutting edges, such as polycrystalline diamond and cubic boron nitride compacts. The techniques are finish turning, finish broaching, finish milling, and finish drilling.
Topography of Surfaces
Authors: Morton R.K.
Published: December 2018

Most surfaces have regular and irregular spacings that tend to form a pattern or texture on the surface. This article provides information on the general background of surface topography and discusses the different methods for measuring surface topography, namely, contact and noncontact techniques, and the focus-follow method. Examples of different types of parameters obtained and how they are applied can best be described by discussing the various types of surfaces generated by finishing methods. The surfaces include ground, turned, and milled machined surfaces; surfaces subjected to stress; bearing surfaces; plateau honed and tapped surfaces; and reflective, painted, elastic, and wear-resistant surfaces.
Decorative Chromium Plating
Authors: Lindsay James H. , Snyder Donald L.
Published: December 2018

Most decorative chromium coatings have been applied using hexavalent and trivalent plating processes that are based on chromic anhydride. This article provides a discussion on chromium electrodeposits and their use as microdiscontinuous coating for corrosion protection. It focuses on the operating conditions of various chromium plating parameters: bath composition, temperature, voltage, anode materials, and current density. These parameters need to be considered for obtaining high quality decorative chromium coatings. An overview of plating problems encountered in chromium plating and their corrections is also provided.
Cadmium Plating
Authors: Stevenson Milton F.
Published: December 2018

Electrodeposits of cadmium are used to protect steel and cast iron against corrosion. This article provides an overview of the surface preparation of, and brighteners used in, cyanide baths. It focuses on the anode system, current density, deposition rates, and bath temperature of cadmium plating with attention to the materials of construction and equipment used. The article provides a description of the selection of plating method with examples, applications, and several postplating processes of cadmium plating.
Indium Plating
Authors: Grobin Allen W.
Published: December 2018

This article focuses on the electrodeposition of indium and its alloys, such as indium-antimony, indium-gallium, and indium-bismuth, in nonaqueous indium plating baths. It also provides information on the stripping of indium plate from plated components and presents an overview of the specifications, standards, and hazards of indium plating.
Lead Plating
Authors: Rynne George B.
Published: December 2018

Lead has been deposited from a variety of electrolytes, including fluoborates, fluosilicates, sulfamates, and methane sulfonic acid baths. This article provides a discussion on these electrolytic baths and includes information on the process sequence, equipment requirements, and applications of lead plating.
Tin Alloy Plating
Authors: Asher Reginald K.
Published: December 2018

Electrodeposition of tin alloys is used to protect steel against corrosion or wear, to impart resistance to etching, and to facilitate soldering. This article focuses on the compositions, operating conditions, advantages, and limitations of methane sulfonic acid plating solutions and fluoborate plating solutions for tin-lead. It briefly describes the solution compositions and operating conditions of tin-bismuth, tin-nickel, and tin-zinc.
Electroforming
Authors: Malone Glenn , Browning Myron E.
Published: December 2018

Electroforming is the process by which articles or shapes can be exactly reproduced by electrodeposition on a mandrel or form that is later removed, leaving a precise duplicate of the original. This article discusses electroforming applications, and explains electroforming of nickel, cobalt, iron, and copper, providing information on mandrel design and selection, electroforming solutions and operating variables. It discusses the significant aspects of electroforming that demand special considerations, such as metal distribution, internal deposit stress, roughness, and treeing. The article concludes with an overview of alloy electroforming.
Surface Preparation for Continuously Applied Coatings
Authors: Dunbar Curtiss
Published: December 2018

This article focuses on the various techniques for removing contaminants in the surface preparation of steel for hot-dip coatings: wet cleaning methods, including alkaline cleaning, electrolytic cleaning, chemical pickling, and electrolytic pickling; flame cleaning and furnace-atmosphere techniques, such as Sendzimir oxidation/reduction method; other specialized methods, namely, fluxes, mechanical cleaning, and ultrasonic methods; or a combination of these.
Porcelain Enameling
Authors:   Technical Publications Committee of the Porcelain Enamel Institute, Inc., Oliver John C. , Giese Douglas D. , Wright Jeffrey F. , Allen Ronald L. , Conrad Terry , Cook John K. , Furr Ted , Gordon Andrew , Hall Bernard L. , Horton Michael , Huyser William , Long Robert J. , Mazzuca Anthony R. , Oliveira Herbert , Preban Arnold , Rarey Charles R. , Sauder Donald R. , Sedalia Narayan M. , Sellins Jeffrey , Smith Lester N. , Steele Larry L. , Wolowicz Ted J.
Published: December 2018

Porcelain enamels are glass coatings applied primarily to products or parts made of sheet steel, cast iron, and aluminum to improve appearance and to protect the metal surface. This article describes the types of porcelain enamels, and details enamel frits for these materials. It provides a list of steels suitable for porcelain enameling and discusses the most important factors considered in the selection of steel for porcelain enameling. The article briefly presents the preparation methods of these materials for porcelain enameling and covers the methods, and furnaces of porcelain enameling. It examines the role of coating thickness, firing time and temperature, metal substrate, and color on the performance of enameled surfaces. The article concludes with a discussion on the properties of enameled surfaces, factors considered in process control, and test procedures for evaluating the quality of enameled surfaces.
Chemical Vapor Deposition of Nonsemiconductor Materials
Authors: Pierson Hugh O.
Published: December 2018

This article presents the principles of chemical vapor deposition (CVD) with illustrations. It discusses the types of CVD processes, namely, thermal CVD, plasma CVD, laser CVD, closed-reactor CVD, chemical vapor infiltration, and metal-organic CVD. The article reviews the CVD reactions of materials related to hard, tribological, and high-temperature coatings and to free-standing structures. It concludes by reviewing the advantages, disadvantages, and applications of CVD.
Arc Deposition
Authors: Sanders David M. , Glaser Joseph W. , Falabella Steven
Published: December 2018

This article describes the characteristics of continuous cathodic arc sources and filtering process for removing macroparticles from a cathodic arc. It provides information on the types of arc sources and the properties of deposited materials. The advantages, limitations, and applications of arc deposition are also discussed.
Pulsed-Laser Deposition
Authors: Horwitz James S.
Published: December 2018

This article presents a general description of pulsed-laser deposition. It describes the components of pulsed-laser deposition equipment. The article also discusses the effects of angular distribution of materials. Finally, the article reviews the characteristics of high-temperature superconductors and ferroelectric materials.
Corrosion Testing of Coatings
Authors: Jehn Hermann A. , Zielonka Andreas
Published: December 2018

This article focuses on the testing and typical corrosion behavior of coating-substrate systems in aqueous solutions and humid aggressive atmospheres. It includes a short review of the fundamentals of corrosion, followed by a discussion of specific system behavior, electrochemical and laboratory accelerated tests, and simulated service tests. The article also contains examples of different types of corrosion damage and presents guidelines for improving corrosion resistance.
Surface Engineering of Cast Irons
Authors: Davis J.R.
Published: December 2018

This article provides a brief review of the classification and characteristics of cast irons. It describes the processes used to clean iron castings, including mechanical cleaning and finishing and nonmechanical cleaning. The article discusses surface treatments used to extend casting life when resistance to corrosion, wear, and erosion is required. The common methods include electroplating, electroless plating, hardfacing, weld cladding, surface hardening, porcelain enameling, and organic coatings.
Surface Engineering of Specialty Steels
Authors: Davis J.R.
Published: December 2018

Specialty steels encompass a broad range of ferrous alloys noted for their special processing characteristics (powder metallurgy alloys), corrosion resistance (stainless steels), wear resistance and toughness (tool steels), high strength (maraging steels), or magnetic properties (electrical steels). This article provides a detailed discussion on the various surface treatments, including cleaning, nitriding, carburizing, coating, and plating, performed on specialty steels.
Surface Engineering of Heat-Resistant Alloys
Authors: Pettit F.S.
Published: December 2018

This article describes the methods for removing metallic contaminants, tarnish, and scale resulting from hot-working or heat-treating operations on nickel-, cobalt-, and iron-base heat-resistant alloys. It provides a brief description of applicable finishing and coating processes, including polishing, electroplating, ceramic coatings, diffusion coatings, and shot-peening. The article presents numerous examples that identify cleaning and finishing problems and the procedures used to solve them.
Surface Engineering of Titanium and Titanium Alloys
Authors: Bloyce A. , Morton P.H. , Bell T.
Published: December 2018

This article reviews cleaning and finishing operations that have proven to be effective on titanium, its alloys, and semi-fabricated titanium products. It explains how to remove scale, tarnish films, grease, and other soils and how to achieve required finishes and/or improve wear and oxidation resistance through the use of polishing, buffing, and wire brushing operations. The article also covers a wide range of surface modification and coating processes, including ion implantation, diffusion, chemical and physical vapor deposition, plating, anodizing, and chemical conversion coatings as well as sprayed and sol-gel coatings and laser and electron-beam treatments.
Surface Engineering for Chemical Activity
Authors: Deeba Michel , Feeley Jennifer S.
Published: December 2018

The chemical process being catalyzed should have a high productivity within a specified reactor volume with high reaction rates for the desired reactions and low rates for undesired reaction pathways. This article reviews the general catalyst preparation procedures, namely, impregnation, ion exchange, and precipitation. Catalyst carriers are usually high-surface-area inorganic materials with complex pore structures, into which catalytic materials such as palladium, platinum, cobalt, chromium oxide, and vanadium pentoxide are deposited using these procedures. The article also provides information on catalyst powder processing.
Compliant Organic Coatings
Authors: Kearney Thomas E.
Published: December 2018

This article discusses coating products available for use in the aerospace industry that are compliant with regulations requiring reductions in emissions from organic solvents. The coating products addressed include primers, topcoats, and chemical milling maskants. It describes their characteristics and limitations compared to conventional noncompliant materials. The article addresses the methods and products commonly used achieve regulatory compliance: waterborne coatings, exempt-solvent-based coatings, high-solids coatings, powder coating, and electro-deposition.
Corrosion Control for Marine- and Land-Based Infrastructure Applications
Authors: Paul Shiladitya
Published: December 2018

Corrosion of marine- and land-based infrastructure is of major concern and its control forms an important objective. Thermal spray coatings (TSCs) are widely used for corrosion protection. This article focuses on two types of TSCs: cathodic or noble coatings and anodic or sacrificial coatings. It describes the factors affecting the performance of sacrificial TSCs in atmospheric and immersion environments. The article provides information on the applications of sacrificial TSCs, non-sacrificial coatings, and sealants/top coats, and exemplifies the use of sacrificial TSCs on structures for corrosion protection.
Postcoating Operations
Authors: Knapp Jim , Lemen Don
Published: December 2018

Thermal spray coatings are often modified or treated by a variety of post-coating operations to transform the as-coated material into a final product based on coating composition and application. This article provides a detailed description of the post-coating operations that fall under two basic categories: surface treatments, such as dimensional, non-dimensional, and geometric finishing; and internal treatments, such as sealing, heat treating, and peening. It also describes various inspection and testing methods, including destructive and non-destructive inspections, often employed after post-coating operations.
Introduction to Testing and Characterization
Authors: Riggs Walter , Rucker Dana
Published: December 2018

Materials resulting from thermal spray processes are often different from their wrought, forged, and cast counterparts. Assessing the usefulness of thermal spray coatings requires understanding, developing, and using appropriate testing and characterization methods that are generally borrowed from other materials science disciplines. This article focuses on commonly used testing and characterization methods: metallography, image analysis, hardness, tensile adhesion testing, corrosion testing, x-ray diffraction, non-destructive testing, and powder characterization. It provides information on how the materials themselves respond to the various test methods. The article focuses on the test methods themselves, including those test parameters that can be varied and the influence of each on the results obtained.
Powder Testing and Characterization
Authors: Riggs Walter
Published: December 2018

The raw materials used in thermal spray processes are a critical parameter in the finished coating because the variations in their size, morphology, chemistry, and phase composition can significantly impact coating properties. Therefore, it is important to test and characterize the raw materials. This article discusses various characterization methods for powders. Topics discussed include: methods for determining particle size and/or size distribution; powder and coating stoichiometry; particle chemistry; and phase analysis by x-ray diffraction. This article discusses the characterization of thermal spray powders which involves the determination of particle size and/or size distribution and phase analysis by x-ray diffraction. It provides information on preferential volatilization and rapid solidification that influence compositional differences. Wet chemical methods, spectographic analysis, and atomic absorption spectrometry are also discussed.
Corrosion and Wear Control for Industrial Applications
Authors: Dorfman Mitchell R.
Published: December 2018

This article focuses on noble and neutral coatings and the requirements necessary to achieve successful industrial applications. These include corrosion and wear control and repair applications in processing and chemical industries, and valve and downhole drilling applications in the petrochemical industry. The article also discusses substrate chemistry and preparation; coating selection process and microstructure; sealing by chemical, post-heat treatments, and laser processing; and thermal spray process alternatives.
Powder Coatings—Pipelines
Authors: Kehr J. Alan
Published: December 2018

Functional fusion-bonded epoxy (FBE) coatings are used as external pipe coatings, base layer for three-layer pipe-coating systems, internal pipe linings, and corrosion coatings for concrete reinforcing steel (rebar). This article provides information on the chemistries of FBE, and discusses the application procedures for internal and external FBE pipe coating. The procedures involve pipe inspection, surface preparation, heating, powder application, curing, cooling, coating inspection, and repairing. It describes the problems and solutions for FBE external pipe coatings, girth weld FBE application, FBE custom coatings, internal FBE pipe linings, and FBE rebar coatings.
Worker Health and Environmental Hazards Associated with Coating Application and Removal
Authors: O'Malley Dan , Liang Stanford T.
Published: December 2018

This article discusses the occupational health hazards related to industrial protective coating application and removal. It explains the health hazards associated with coating constituents such as lead, cadmium, chromium, arsenic, silica, and asbestos. The article also discusses hazard evaluation, hazard controls, Occupational Safety and Health Administration standards, and industry consensus standards. It concludes with a description of containment systems to prevent environmental exposures from industrial paint removal projects.
Polyvinylidene Fluoride-Based Coatings Technology
Authors: Iezzi Robert A.
Published: December 2018

Polyvinylidene fluoride (PVDF)-based coatings are typically used in outdoor applications that require exceptionally high performance and excellent long-term exterior durability with little maintenance. This article provides a background of three fluoropolymers most commonly used for coatings, namely, PVDF, polyvinyl fluoride, and polytetrafluoroethylene. It focuses on general properties, polymerization, resin types, coating formulation, technology of organic coatings, coating properties, and health and related safety considerations of PVDF. The article describes the application and typical end uses of PVDF-based coatings and the opportunities for improvement in PVDF-based coatings as with all organic coatings.
Bitumens—Coal Tar and Asphalt Coatings
Authors: Tator Kenneth B.
Published: December 2018

Bitumen for coating usage can best be categorized as two fundamental but very different types: asphalts and coal tars. This article provides a detailed discussion on asphalt and coal tar hot-melt applications; asphalt and coal tar emulsions; asphalt and coal tar cutbacks; and coal tar epoxies. It reviews the similarities between asphaltic and coal tar coatings and discusses the health and environmental concerns of these materials.
Polyurea-Based Coatings
Authors: Primeaux Dudley J.
Published: December 2018

Two-component polyurea elastomeric coating/lining systems are the newest technology in the protective coating/lining industry and a wide variety of applications have been developed. These include coating/lining applications over concrete, geotextile membranes, various metals for corrosion and decorative areas, and some plastics. This article discusses the formulation basics of polyurea technology and compares the technology to that of polyurethane and polyurethane/polyurea systems. It addresses performance issues and describes application processing considerations and safety practices of polyurea coating/lining systems.
Green Coatings
Authors: Law Barry
Published: December 2018

This article presents a background of green chemistry and green coatings, and a summary of the key concerns of the green coating procurement process. It includes a discussion on green marketing and the seven sins of greenwashing, an overview of the environmental certification standards and regulatory environments, and the importance of performance during the duty cycle.
History of Powder Metallurgy
Authors: Adams James P.
Published: December 2018

Powder metallurgy (PM) has been called a lost art. Long before furnaces were developed that could approach the melting point of metal, PM principles were used. This article provides an overview of the major historical developments of various methods of platinum powder production. The development of production methods took place in various phases starting from prehistoric time, post-war period, to recent and commercial period. The article discusses the powder metallurgy of platinum, as well as the commercial and post-war developments of PM. Literature and trade associations are also discussed.
Materials Standards and Test Method Standards for Powder Metallurgy
Authors: James W. Brian
Published: December 2018

The organizations that are most active in the development of standards for powder metallurgy (PM) are the American Society for Testing and Materials (ASTM), Metal Powder Industries Federation (MPIF), and International Standards Organization (ISO). This article presents the test method standards, materials standards, and material designation codes for PM materials. It provides information on the codes for structural parts, PM soft magnetic materials, PM self-lubricating bearings, metal injection molded materials, and powder forged materials.
Modeling and Simulation of Press and Sinter Powder Metallurgy
Authors: Chung Suk Hwan , Kwon Young-Sam , Park Seong Jin , German Randall M.
Published: December 2018

This article discusses continuum modeling, which is the most relevant approach in modeling grain growth, densification, and deformation during sintering. Continuum plasticity models are frequently used to describe the mechanical response of metal powders during compaction. The article illustrates the typical procedure for computer simulation for press and sinter process. It describes the procedure to obtain the material properties based on the generalized Shima-Oyane model. The article presents a wide variety of tests, accounting for data on the grain growth, densification, and distortion where these data help in the development of a constitutive model for sintering simulation. Finally, the article provides information on the simulation approaches used to optimize die compaction and sintering.
Powder Metallurgy Presses and Tooling
Authors: Robinson Troy
Published: December 2018

Powder metallurgy compacting presses usually are mechanically or hydraulically driven, but they can incorporate a combination of mechanically, hydraulically, and pneumatically driven systems. This article provides a comparison of mechanical and hydraulic presses based on the cost, production rate, and machine overload protection. The article lists the classification of powder metallurgy parts based on complexity of shapes as suggested by the Metal Powder Industries Federation, such as Class I parts, Class II parts, Class III parts, and Class IV parts. It describes rigid tooling compaction and details the powder-fill ratio considerations for these classes. The article elaborates on the types of tooling systems and presses used for these classes. Some important factors and components used in designing a tool are also described. Finally, the article considers tool materials, including punches, core rods, and punch clamp rings.