bluuebunny/crossref_metadata_2025 huggingface dataset:
Anatomical Vascular Differences and Leishmania-Induced Vascular Morphological Changes Are Associated with a High Parasite Load in the Skin of Dogs Infected with Leishmania infantum
Authors: Ribeiro Francini N. , de Souza Tainã L. , Menezes Rodrigo C. , Keidel Lucas , dos Santos João Paulo R. , da Silva Igor J. , Pelajo-Machado Marcelo , Morgado Fernanda N. , Porrozzi Renato
Published: April 2024

Canine visceral leishmaniasis (CVL), caused by the protozoan Leishmania infantum, affects several organs, including the skin. Dogs are considered the major domestic reservoir animals for leishmaniasis, and through their highly parasitized skin, they can serve as a source of infection for sandfly vectors. Therefore, studies of the skin parasite–host relationship can contribute to the understanding of the infectious dissemination processes of parasites in the dermis and help to identify targets for diagnosis and treatment. Thus, the aim of this study was to evaluate the association of anatomical vascular differences and Leishmania-induced vascular morphological changes with clinical signs and parasite load by analyzing the ear and abdominal skin from dogs naturally infected with L. infantum. Paired samples of ear and abdominal skin from L. infantum-positive dogs (n = 26) were submitted for histological and immunohistochemistry analyses. The ear skin samples showed a more intense and more diffusely distributed granulomatous inflammatory reaction, a higher number and larger diameter of blood vessels, increased parasite load, higher expression of VEGF+ (vascular endothelial growth factor) and MAC 387+ (calprotectin) recently infiltrating cells, and more intense collagen disruption compared to the abdominal skin samples. Intracellular amastigotes were observed in blood vessels and inside endothelial cells and were diffusely distributed throughout the dermis in the ear skin samples. The NOS2/MAC387+ cell ratio was lower in the ear skin samples than in those of the abdomen, suggesting that in the ear dermis, the inflammatory infiltrate was less capable of producing NO and thereby control the parasite load. Together, these findings indicate how parasites and immune cells are distributed in the skin and suggest an important role for dermal vascularization in cellular influx and thereby in parasite dissemination through the skin of naturally infected dogs.
Evaluation of an Erbium-Doped Fiber Ring Laser as an Edge Filtering Device for Fiber Bragg Grating Sensor Interrogation
Authors: Stathopoulos Nikolaos A. , Lazakis Christos , Simos Iraklis , Simos Christos
Published: April 2024

An easy-to-implement and cost-effective Fiber Bragg Grating (FBG) sensor interrogation technique based on a ring Erbium-Doped Fiber Laser (EDFL) topology is proposed and experimentally assessed. The FBG sensor is part of the EDFL cavity and must have a central wavelength located within the linear region of the EDF’s amplified spontaneous emission (ASE) spectrum, which occurs at between 1530 and 1540 nm. In this manner, the wavelength-encoded response of the FBG under strain is converted to a linear variation in the laser output power, removing the need for spectrum analysis as well as any limitations from the use of external edge-filtering components. In addition, the laser linewidth is significantly reduced with respect to the FBG bandwidth, thus improving the resolution of the system, whereas its sensitivity can be controlled through pumping power. The performance of the system has been characterized by modeling and experiments for EDFs with different lengths, doping concentrations, and pumping power levels. The influence of mode-hopping in the laser cavity on the resolution and accuracy of the system has also been investigated.
Far-Field Super-Resolution Optical Microscopy for Nanostructures in a Reflective Substrate
Authors: Zhang Aiqin , Li Kunyang , Guan Guorong , Liang Haowen , Xie Xiangsheng , Zhou Jianying
Published: April 2024

The resolution of an optical microscope is determined by the overall point spread function of the system. When examining structures significantly smaller than the wavelength of light, the contribution of the background or surrounding environment can profoundly affect the point spread function. This research delves into the impact of reflective planar substrate structures on the system’s resolution. We establish a comprehensive forward imaging model for a reflection-type confocal laser scanning optical microscope, incorporating vector field manipulation to image densely packed nanoparticle clusters. Both theoretical and experimental findings indicate that the substrate causes an interference effect between the background field and the scattered field from the nanoparticles, markedly enhancing the overall spatial resolution. The integration of vector field manipulation with an interferometric scattering approach results in superior spatial resolution for imaging isolated particles and densely distributed nanoscale particle clusters even with deep subwavelength gaps as small as 20 nm between them. However, the method still struggles to resolve nanoparticles positioned directly next to each other without any gap, necessitating further work to enhance the resolving ability. This may involve techniques like deconvolution or machine learning-based post-processing methods.
A Novel Inserting Pilot Radio over Fiber System without the Bit Walk-Off Effect for the Generation and Distribution of Frequency 16-Tupling Millimeter Waves by Mach–Zehnder Modulators
Authors: Chen Xu , Chen Xinqiao , Dai Siyuan , Li Bin , Wang Ling
Published: April 2024

A novel inserting pilot scheme to generate and distribute a frequency 16-tupling millimeter wave (MMW) radio over fiber (ROF) system without the bit walk-off effect via Mach–Zehnder modulators (MZMs) is proposed. The operation principle is analyzed and the feasibility of our proposed scheme is verified by simulation test. The main part of our scheme is a ±8th-order sidebands generator (SG), which is constructed by four MZMs connected in parallel. In the back-to-back (BTB) transmission case, by properly adjusting the voltage and initial phase of the radio frequency (RF) drive signals of the MZMs, ±8th-order sidebands are generated by the SG. In the data transmission case, the data signal is first split into two beams, one of which modulates the RF drive signal with an electrical phase modulator (PM) while the other is amplified by an electrical gainer (EG), and then the two beams are combined into one and used as the composite RF drive signal of the MZMs. By adjusting the modulation index of the PM and the gain of the EG, the data signal can only be modulated to the +8th-order sideband of the output of the SG. The optical carrier from the continuous wave (CW) laser is split into two paths: one is sent into the SG, and the other is used as a pilot signal. The output signal of SG is combined with the pilot signal and is transmitted to the base station (BS) via optical fiber. At the BS, the pilot signal is filtered out by a fiber Bragg grating (FBG) and used as the carrier for the uplink for carrier reuse. After filtering out the pilot, the signal from the FBG, which is composed of ±8th-order sidebands, is injected into a photodetector, and a frequency 16-tupling MMW with downlink data is generated. The key parameters’ influence on the bit error rate (BER) and Q factor in the system is also analyzed. Our scheme can not only effectively overcome the bit walk-off effect caused by optical fiber chromatic dispersion and greatly increase the fiber transmission distance but can also effectively improve the performance and the tunability of system. Therefore, it has important application prospects in ROF systems.
Design and Analysis of a Narrow Linewidth Laser Based on a Triple Euler Gradient Resonant Ring
Authors: Wang Yikai , Yan Boxia , Zhou Mi , Sun Chenxi , Qi Yan , Wang Yanwei , Fan Yuanyuan , Wang Qian
Published: April 2024

We designed a narrow-linewidth external-cavity hybrid laser leveraging a silicon-on-insulator triple Euler gradient resonant ring. The laser’s outer cavity incorporates a compact, high-Q resonant ring with low loss. The straight waveguide part of the resonant ring adopts a width of 1.6 μm to ensure low loss transmission. The curved section is designed as an Euler gradient curved waveguide, which is beneficial for low loss and stable single-mode transmission. The design features an effective bending radius of only 26.35 μm, which significantly improves the compactness of the resonant ring and, in turn, reduces the overall footprint of the outer cavity chip. To bolster the laser power and cater to the varying shapes of semiconductor optical amplifier (SOA) spots, we designed a multi-tip edge coupler. Theoretical analysis indicates that this edge coupler can achieve an optical coupling efficiency of 85%. It also reveals that the edge coupler provides 3 dB vertical and horizontal alignment tolerances of 0.76 μm and 2.4 μm, respectively, for a spot with a beam waist radius of 1.98 μm × 0.99 μm. The outer cavity, designed with an Euler gradient micro-ring, can achieve a side-mode suppression ratio (SMSR) of 30 dB within a tuning range of 100 nm, with a round-trip loss of the entire cavity at 1.12 dB, and an expected theoretical laser linewidth of 300 Hz.
Creating Climate-Resilient Crops by Increasing Drought, Heat, and Salt Tolerance
Authors: Sugumar Tharanya , Shen Guoxin , Smith Jennifer , Zhang Hong
Published: April 2024

Over the years, the changes in the agriculture industry have been inevitable, considering the need to feed the growing population. As the world population continues to grow, food security has become challenged. Resources such as arable land and freshwater have become scarce due to quick urbanization in developing countries and anthropologic activities; expanding agricultural production areas is not an option. Environmental and climatic factors such as drought, heat, and salt stresses pose serious threats to food production worldwide. Therefore, the need to utilize the remaining arable land and water effectively and efficiently and to maximize the yield to support the increasing food demand has become crucial. It is essential to develop climate-resilient crops that will outperform traditional crops under any abiotic stress conditions such as heat, drought, and salt, as well as these stresses in any combinations. This review provides a glimpse of how plant breeding in agriculture has evolved to overcome the harsh environmental conditions and what the future would be like.
Trichoderma virens and Pseudomonas chlororaphis Differentially Regulate Maize Resistance to Anthracnose Leaf Blight and Insect Herbivores When Grown in Sterile versus Non-Sterile Soils
Authors: Huang Pei-Cheng , Yuan Peiguo , Grunseich John M. , Taylor James , Tiénébo Eric-Olivier , Pierson Elizabeth A. , Bernal Julio S. , Kenerley Charles M. , Kolomiets Michael V.
Published: April 2024

Soil-borne Trichoderma spp. have been extensively studied for their biocontrol activities against pathogens and growth promotion ability in plants. However, the beneficial effect of Trichoderma on inducing resistance against insect herbivores has been underexplored. Among diverse Trichoderma species, consistent with previous reports, we showed that root colonization by T. virens triggered induced systemic resistance (ISR) to the leaf-infecting hemibiotrophic fungal pathogens Colletotrichum graminicola. Whether T. virens induces ISR to insect pests has not been tested before. In this study, we investigated whether T. virens affects jasmonic acid (JA) biosynthesis and defense against fall armyworm (FAW) and western corn rootworm (WCR). Unexpectedly, the results showed that T. virens colonization of maize seedlings grown in autoclaved soil suppressed wound-induced production of JA, resulting in reduced resistance to FAW. Similarly, the bacterial endophyte Pseudomonas chlororaphis 30-84 was found to suppress systemic resistance to FAW due to reduced JA. Further comparative analyses of the systemic effects of these endophytes when applied in sterile or non-sterile field soil showed that both T. virens and P. chlororaphis 30-84 triggered ISR against C. graminicola in both soil conditions, but only suppressed JA production and resistance to FAW in sterile soil, while no significant impact was observed when applied in non-sterile soil. In contrast to the effect on FAW defense, T. virens colonization of maize roots suppressed WCR larvae survival and weight gain. This is the first report suggesting the potential role of T. virens as a biocontrol agent against WCR.
Optimizing the Mulching Pattern and Nitrogen Application Rate to Improve Maize Photosynthetic Capacity, Yield, and Nitrogen Fertilizer Utilization Efficiency
Authors: Zhang Hengjia , Chen Tao , Yu Shouchao , Zhou Chenli , Teng Anguo , Lei Lian , Li Fuqiang
Published: April 2024

Residual film pollution and excessive nitrogen fertilizer have become limiting factors for agricultural development. To investigate the feasibility of replacing conventional plastic film with biodegradable plastic film in cold and arid environments under nitrogen application conditions, field experiments were conducted from 2021 to 2022 with plastic film covering (including degradable plastic film (D) and ordinary plastic film (P)) combined with nitrogen fertilizer 0 (N0), 160 (N1), 320 (N2), and 480 (N3) kg·ha−1. The results showed no significant difference (p > 0.05) in dry matter accumulation, photosynthetic gas exchange parameters, soil enzyme activity, or yield of spring maize under degradable plastic film cover compared to ordinary plastic film cover. Nitrogen fertilizer is the main factor limiting the growth of spring maize. The above-ground and root biomass showed a trend of increasing and then decreasing with the increase in nitrogen application level. Increasing nitrogen fertilizer can also improve the photosynthetic gas exchange parameters of leaves, maintain soil enzyme activity, and reduce soil pH. Under the nitrogen application level of N2, the yield of degradable plastic film and ordinary plastic film coverage increased by 3.74~42.50% and 2.05~40.02%, respectively. At the same time, it can also improve water use efficiency and irrigation water use efficiency, but it will reduce nitrogen fertilizer partial productivity and nitrogen fertilizer agronomic use efficiency. Using multiple indicators to evaluate the effect of plastic film mulching combined with nitrogen fertilizer on the comprehensive growth of spring maize, it was found that the DN2 treatment had the best complete growth of maize, which was the best model for achieving stable yield and income increase and green development of spring maize in cold and cool irrigation areas.
MicroRNA164 Affects Plant Responses to UV Radiation in Perennial Ryegrass
Authors: Xu Chang , Huang Xin , Ma Ning , Liu Yanrong , Xu Aijiao , Zhang Xunzhong , Li Dayong , Li Yue , Zhang Wanjun , Wang Kehua
Published: April 2024

Increasing the ultraviolet radiation (UV) level, particularly UV-B due to damage to the stratospheric ozone layer by human activities, has huge negative effects on plant and animal metabolism. As a widely grown cool-season forage grass and turfgrass in the world, perennial ryegrass (Lolium perenne) is UV-B-sensitive. To study the effects of miR164, a highly conserved microRNA in plants, on perennial ryegrass under UV stress, both OsmiR164a overexpression (OE164) and target mimicry (MIM164) transgenic perennial ryegrass plants were generated using agrobacterium-mediated transformation, and UV-B treatment (~600 μw cm−2) of 7 days was imposed. Morphological and physiological analysis showed that the miR164 gene affected perennial ryegrass UV tolerance negatively, demonstrated by the more scorching leaves, higher leaf electrolyte leakage, and lower relative water content in OE164 than the WT and MIM164 plants after UV stress. The increased UV sensitivity could be partially due to the reduction in antioxidative capacity and the accumulation of anthocyanins. This study indicated the potential of targeting miR164 and/or its targeted genes for the genetic manipulation of UV responses in forage grasses/turfgrasses; further research to reveal the molecular mechanism underlying how miR164 affects plant UV responses is needed.
The First Records of the In Silico Antiviral and Antibacterial Actions of Molecules Detected in Extracts of Algerian Fir (Abies numidica De Lannoy) Using LC-MS/MS Analysis
Authors: Benouchenne Djamila , Bellil Ines , Bendjedid Samira , Ramos Ana , Nieto Gema , Akkal Salah , Khelifi Douadi
Published: April 2024

(1) Background: Due to the wide application in medicinal and pharmaceutical chemistry of flavonoid molecules, which are one of the most famous types of secondary plant metabolites, our work has come within the framework of bio-consulting to help in the identification of the molecule(s) responsible for the antibacterial effect which will be the active principle of a natural antibiotic developed from Algerian fir using bioinformatics tools. (2) Methods: The docking method was used to test the antiviral activity on SARS-CoV-2 virus and the antibacterial activity on Gram-positive Staphylococcus aureus and Gram-negative Escherichia coli of 12 polyphenolic molecules present in the ethyl acetate and n-butanol extracts of Numidian fir leaves, and identify the molecules responsible for these specific biological activities. (3) Results: The findings revealed that it is possible that two molecules, hyperoside and quercitrin, have a high capacity to inhibit SARS-CoV-2, and it is important to mention that they are the most quantitatively abundant molecules in the extract. The molecule luteolin-7-glucoside is probably responsible for the antibacterial activity in the extract against Gram-negative bacteria such as Escherichia coli, and the molecule hesperidin is responsible for the antibacterial activity in the extract against Gram-positive bacteria such as Staphylococcus aureus.
Multilocus Gene Analyses Indicate Tamarix aphylla as Reservoir Host of Diverse Phytoplasmas Associated with Witches’ Broom and Yellowing Symptomatology
Authors: Esmaeilzadeh-Hosseini Seyyed Alireza , Babaei Ghobad , Pacini Francesco , Bertaccini Assunta
Published: April 2024

Tamarisk witches’ broom, yellowing, and little leaf symptoms were observed during 2018–2023 surveys of rural deserts in central regions of Iran with the highest disease incidence up to 72% in Chah Afzal (Yazd province). A verification of the presence and identity of phytoplasmas associated with these symptoms was then performed. Tamarisk tree branch cuttings obtained from symptomatic plants sprouted up to 90.3% but with 15–25 days’ delay compared to the asymptomatic ones and showed internode shortening and witches’ broom, while the branch cuttings from asymptomatic plants had normal growth and sprouted up to 97.8%. Phytoplasma transmission by dodder bridges to periwinkle did not succeed, while nested polymerase chain reaction on the phytoplasma ribosomal gene followed by RFLP and phylogenetic analyses revealed the presence of ‘Candidatus Phytoplasma asteris’, ‘Ca. P. australasiae=australasiaticum’, and ‘Ca. P. trifolii’ (ribosomal subgroups 16SrI-B, 16SrII-D, and 16SrVI-A, respectively) in the samples from symptomatic plants only. Further amplifications were performed on selected phytoplasma-positive samples on tuf and secA genes, and the produced sequences indicated the presence of mixed phytoplasma infection in some of the samples. In particular, in the tuf gene, a mixed infection of ‘Ca. P. australasiae=australasiaticum’ and ‘Ca. P. trifolii’ was detected, while in the secA gene, the presence of ‘Ca. P. asteris’ or ‘Ca. P. tritici’ strains was identified. The first-time detection of diverse phytoplasma strains in symptomatic T. aphylla suggests that this species represent a relevant source of infection for the agricultural crops and for landscape plants especially when temperature allows insect vector transmission, and therefore, it represents a risk in every environment especially in the frame of climatic changes.
Changes in the Carotenoids of Zamia dressleri Leaves during Development
Authors: Murillo Enrique , Nagy Veronika , Menchaca Dania , Deli József , Agócs Attila
Published: April 2024

It has been observed that the leaves of some Zamia species undergo a kind of “reverse ripening”; that is, they change from their original brown color to green during development. We assumed that this strange color change was due to the change in carotenoid composition, so we followed the changes for several weeks. The detailed carotenoid composition and content at different stages of development of the leaves was determined with HPLC-DAD focusing on the changes in red and yellow carotenoids. The total and relative amounts of red and yellow carotenoids were determined simultaneously from one measurement from a saponified and/or unsaponified extract. At the beginning of development, the concentration of red carotenoids was higher than that of the yellow ones; it decreased drastically until 22 days and continued to decrease slowly until they completely disappeared. The concentration of yellow carotenoids decreased at the beginning as well, but after 22 days it started to increase. The amount of red carotenoids started to decrease when the leaflet stopped growing. Lutein is the main component in old leaflets, which is not a red carotenoid precursor. Red carotenoids can always be found in their esterified form in the leaves. These findings support the hypothesis that red and yellow carotenoid accumulation are independent and probably have different functions in the leaflet. The strange color change was explained based on the compartmentalization of red and yellow carotenoids and on the changing activity of the enzyme capsanthin–capsorubin synthase responsible for the synthesis of red carotenoids capsorubin and capsanthin.
Chemical Relationship among Genetically Authenticated Medicinal Species of Genus Angelica
Authors: Kim Jung-Hoon , Doh Eui-Jeong , Kim Han-Young , Lee Guemsan
Published: April 2024

The genus Angelica comprises various species utilized for diverse medicinal purposes, with differences attributed to the varying levels or types of inherent chemical components in each species. This study employed DNA barcode analysis and HPLC analysis to genetically authenticate and chemically classify eight medicinal Angelica species (n = 106) as well as two non-medicinal species (n = 14) that have been misused. Nucleotide sequence analysis of the nuclear internal transcribed spacer (ITS) region revealed differences ranging from 11 to 117 bp, while psbA-trnH showed variances of 3 to 95 bp, respectively. Phylogenetic analysis grouped all samples except Angelica sinensis into the same cluster, with some counterfeits forming separate clusters. Verification using the NCBI database confirmed the feasibility of species identification. For chemical identification, a robust quantitative HPLC analysis method was developed for 46 marker compounds. Subsequently, two A. reflexa-specific and seven A. biserrata-specific marker compounds were identified, alongside non-specific markers. Moreover, chemometric clustering analysis reflecting differences in chemical content between species revealed that most samples formed distinct clusters according to the plant species. However, some samples formed mixed clusters containing different species. These findings offer crucial insights for the standardization and quality control of medicinal Angelica species.
Study on the Properties of PLA- and PP-Based Films for Food Applications Incorporating Orange Peel Extract from Agricultural by-Products
Authors: Tone Ana Maria , Herranz Solana Nuria , Khan Muhammad Rehan , Borriello Angela , Torrieri Elena , Sánchez Reig Carmen , Monedero Prieto F. María
Published: April 2024

The aim of this work was to develop active packaging based on polypropylene (PP) and polylactic acid (PLA) matrices using a high value by-product extracted from orange peel as an active compound for food packaging applications. Different films with and without orange peel extract (OPE) based on PP and PLA were obtained via cast extrusion and characterized in terms of their mechanical, thermal, optical, and sealing properties. The films obtained were transparent, but when OPE was incorporated, the transmittance spectrum decreased, causing slight coloration. Mechanical properties were affected by the incorporation of OPE, as elongation at break and tensile strength increased in the cross-direction of the PP film, although the main differences found were related to the polymer itself. In addition, sealing strength also increased via the incorporation of OPE in the PP matrix. However, thermal properties were not affected by OPE in the PP matrix but slightly decreased stability in PLA. Regarding antimicrobial activity in in vitro studies, no inhibition of the growth of Listeria innocua, Saccharomyces cerevisiae, Aspergillus niger, or Escherichia coli was observed. Finally, antioxidant activity was observed in in vitro studies with 2,2-Diphenyl-1picrylhydrazyl (DPPH) radical. The results of this study showed that the obtention of materials with OPE incorporated into the PLA and PP matrix is feasible. The new materials obtained can be used for applications of oxidation-sensitive fresh products.
Macroalgae Bioplastics: A Sustainable Shift to Mitigate the Ecological Impact of Petroleum-Based Plastics
Authors: Elkaliny Nehal E. , Alzamel Nurah M. , Moussa Shaaban H. , Elodamy Nour I. , Madkor Engy A. , Ibrahim Esraa M. , Elshobary Mostafa E. , Ismail Gehan A.
Published: April 2024

The surge in global utilization of petroleum-based plastics, which notably heightened during the COVID-19 pandemic, has substantially increased its harm to ecosystems. Considering the escalating environmental impact, a pivotal shift towards bioplastics usage is imperative. Exploring and implementing bioplastics as a viable alternative could mitigate the ecological burden posed by traditional plastics. Macroalgae is a potential feedstock for the production of bioplastics due to its abundance, fast growth, and high cellulose and sugar content. Researchers have recently explored various methods for extracting and converting macroalgae into bioplastic. Some of the key challenges in the production of macroalgae bioplastics are the high costs of large-scale production and the need to optimize the extraction and conversion processes to obtain high-quality bioplastics. However, the potential benefits of using macroalgae for bioplastic production include reducing plastic waste and greenhouse gas emissions, using healthier materials in various life practices, and developing a promising area for future research and development. Also, bioplastic provides job opportunities in free enterprise and contributes to various applications such as packaging, medical devices, electronics, textiles, and cosmetics. The presented review aims to discuss the problem of petroleum-based plastic, bioplastic extraction from macroalgae, bioplastic properties, biodegradability, its various applications, and its production challenges.
Preparation and Performance Study of HTPB-g-(PNIPAM/PEG) Thermoresponsive Polymer Brush
Authors: Bi Pengzhi , Zhu Xiuzhong , Tian Li , Han Jinbang , Zhang Wanbin , Wang Tong
Published: April 2024

In recent years, a great deal of work has been devoted to the development of thermoresponsive polymers that can be made into new types of smart materials. In this paper, a branched polymer, HTPB-g-(PNIPAM/PEG), with polyolefin chain segments as the backbone and having polyethylene glycol (PEG) and poly(N-isopropylacrylamide) (PNIPAM) as side chains was synthesized by ATRP and click reactions using N3-HTPB-Br as the macroinitiator. This initiator was designed and synthesized using hydroxyl-terminated polybutadiene (HTPB) as the substrate. The temperature-responsive behavior of the branched polymer was investigated. The lower critical solution temperature (LCST) of the branched polymer was determined by ultraviolet and visible spectrophotometry (UV-vis) and was found to be 35.2 °C. The relationship between the diameter size of micelles and temperature was determined by dynamic light scattering (DLS). It was found that the diameter size changed at 36 °C, which was nearly consistent with the result obtained by UV-vis. The results of the study indicate that HTPB-g-(PNIPAM/PEG) is a temperature-responsive polymer. At room temperature, the polymer can self-assemble into composite micelles, with the main chain as the core and the branched chain as the shell. When the temperature was increased beyond LCST, the polyolefin main chain along with the PNIPAM branched chain assembled to form the nucleus, and the PEG branched chain constituted the shell.
Strengthening Mechanism of Polyurea to Anti-Penetration Performance of Spherical Cell Porous Aluminum
Authors: Fan Zhiqiang , Guo Yujian , Cui Yongxin , Yang Xiaopeng
Published: April 2024

A composite structure containing a metallic skeleton and polyurea elastomer interpenetrating phase was fabricated, and its anti-penetration performance for low-velocity large mass fragments was experimentally studied. The protection capacity of three polyurea was compared based on the penetration resistance force measurement. Results show that the polyurea coating layer at the backside improves the performance of the polyurea-filled spherical cell porous aluminum (SCPA) plate due to its backside support effect and phase transition effect, which are accompanied by a large amount of energy absorption. The frontal-side-coated polyurea layer failed to shear and provided a very limited strengthening effect on the penetration resistance of the interpenetrating phase composite panel. The filling polyurea in SCPA increased the damage area and formed a compression cone for the backside coating layer, leading to a significant stress diffusion effect. The anti-penetration performance was synergistically improved by the plug block effect of the interpenetrating phase composite and the backside support effect of the PU coating layer. Compared with SCPA, the initial impact failure strength and the average resistance force of the composite plate were improved by 120–200% and 108–274%, respectively.
Temperature and Strain Rate Related Deformation Behavior of UHMWPE Fiber-Reinforced Composites
Authors: Yi Chenhong , Xu Jianhui , Tian Lizhi , Zhang Chun
Published: April 2024

As they possess the qualities of high specific strength, high specific modulus, high specific energy absorption, and excellent designability, ultra-high molecular weight polyethylene (UHMWPE) fiber-reinforced composites have gradually replaced traditional materials such as ceramics and steel plates as the main ballistic protection materials. Using an improved test method, the uniaxial tensile tests of UHMWPE fiber-reinforced composites at two strain rates of 10−4 s−1 and 10−2 s−1 and a temperature range from −20 °C to 80 °C are carried out to study the effects of strain rate and temperature on the tensile behavior of UHMWPE fiber-reinforced composites. The experimental results indicate that the tensile responses exhibit nonlinear characteristics and the sensitivity of strain rate and temperature. The yield strength and modulus decrease with increasing temperature and increase with the increase in strain rate. A phenomenological viscoelastic constitutive model composed of a nonlinear spring and a nonlinear Maxwell element is proposed to characterize the temperature and strain rate dependent deformation behavior of UHMWPE fiber-reinforced composites before yielding. The results show that the model can accurately predict the tensile nonlinear viscoelastic responses of UHMWPE fiber-reinforced composites before yielding over a wide temperature range under quasi-static loading.
Green and Heavy-Duty Anticorrosion Coatings: Waterborne Epoxy Thermoset Composites Modified through Variation of Zinc Dust Loading and Incorporation of Amine-Capped Aniline Trimer and Graphene Oxide
Authors: Lan Yun-Xiang , Chen Yun-Hsuan , Chao Ying-Lung , Chang Yu-Hsuan , Huang Yu-Chi , Liu Wei-Ren , Wong Wei-Tsan , Sun Andrew Chi-Fa , Santiago Karen S. , Yeh Jui-Ming
Published: April 2024

In this study, an array of environmentally friendly and heavy-duty anticorrosion composite coatings were prepared. The synthesis involved amine-capped aniline trimer (ACAT) produced by an oxidative coupling reaction and graphene oxide (GO) prepared based on Hummer’s method, and later, the waterborne epoxy thermoset composite (WETC) coatings were prepared by thermal ring-opening polymerization of EP 147w, a commercial waterborne epoxy resin, in the presence of ACAT and/or GO with zinc dust (ZD). A synergistic effect was observed by replacing a significant amount of the ZD loading in the WETC by simultaneously incorporating a small amount of ACAT and GO. The electrochemical corrosion measurements of the as-prepared WETC coatings indicated that incorporating 5% w/w ACAT or 0.5% w/w GO separately replaced approximately 30% w/w or 15% w/w of the ZD, respectively. Moreover, the WETC coatings containing 5% w/w ACAT and 0.5% w/w GO simultaneously were found to replace 45% w/w of the ZD. A salt spray test based on ASTM B-117 also showed a consistent trend with the electrochemical results. Incorporating small amounts of ACAT and GO in WETC coatings instead of ZD not only maintains the anticorrosion performance but also enhances adhesion and abrasion resistance, as demonstrated by the adhesion and abrasion tests.
Poly(dl-lactide) Polymer Blended with Mineral Phases for Extrusion 3D Printing—Studies on Degradation and Biocompatibility
Authors: Vater Corina , Bräuer Christian , Grom Stefanie , Fecht Tatjana , Ahlfeld Tilman , von Witzleben Max , Placht Anna-Maria , Schütz Kathleen , Schehl Jan Marc , Wolfram Tobias , Reinauer Frank , Scharffenberg Martin , Wittenstein Jakob , Hoess Andreas , Heinemann Sascha , Gelinsky Michael , Lauer Günter , Lode Anja
Published: April 2024

A promising therapeutic option for the treatment of critical-size mandibular defects is the implantation of biodegradable, porous structures that are produced patient-specifically by using additive manufacturing techniques. In this work, degradable poly(DL-lactide) polymer (PDLLA) was blended with different mineral phases with the aim of buffering its acidic degradation products, which can cause inflammation and stimulate bone regeneration. Microparticles of CaCO3, SrCO3, tricalcium phosphates (α-TCP, β-TCP), or strontium-modified hydroxyapatite (SrHAp) were mixed with the polymer powder following processing the blends into scaffolds with the Arburg Plastic Freeforming 3D-printing method. An in vitro degradation study over 24 weeks revealed a buffer effect for all mineral phases, with the buffering capacity of CaCO3 and SrCO3 being the highest. Analysis of conductivity, swelling, microstructure, viscosity, and glass transition temperature evidenced that the mineral phases influence the degradation behavior of the scaffolds. Cytocompatibility of all polymer blends was proven in cell experiments with SaOS-2 cells. Patient-specific implants consisting of PDLLA + CaCO3, which were tested in a pilot in vivo study in a segmental mandibular defect in minipigs, exhibited strong swelling. Based on these results, an in vitro swelling prediction model was developed that simulates the conditions of anisotropic swelling after implantation.
A Study on the Preparation of a Vulcanizing Mixture and Its Application in Natural Rubber Latex
Authors: Fang Haobin , He Yingping , Li Yulan , Du Jie
Published: April 2024

The traditional preparation process of natural rubber latex requires tedious treatment of a variety of rubber additives. In this paper, a new process of wet mixed grinding was used to prepare a reinforced vulcanization mixture and a rapid vulcanization effect. The effect of different amounts of vulcanization mixtures on the mechanical properties of natural latex film was studied, and the pre-vulcanization process of latex and the vulcanization process of film were optimized. The results showed that with the increase in the amount of vulcanization mixture, the tensile strength increased from 5.96 MPa to 29.28 MPa, and the tear strength increased from 7.59 kN/m to 52.81 kN/m. When the vulcanization temperature of the latex film is heated from 80 °C to 100 °C, the vulcanization time is shortened by 5~6 times. The new vulcanization mixture prepared in this work has the characteristics of simple production and fast vulcanization speed, which provides a new solution for the development of the latex product industry.
Design of a Multimodal Detection System Tested on Tea Impurity Detection
Authors: Kuang Zhankun , Yu Xiangyang , Guo Yuchen , Cai Yefan , Hong Weibin
Published: April 2024

A multimodal detection system with complementary capabilities for efficient detection was developed for impurity detection. The system consisted of a visible light camera, a multispectral camera, image correction and registration algorithms. It can obtain spectral features and color features at the same time and has higher spatial resolution than a single spectral camera. This system was applied to detect impurities in Pu’er tea to verify its high efficiency. The spectral and color features of each pixel in the images of Pu’er tea were obtained by this system and used for pixel classification. The experimental results showed that the accuracy of a support vector machine (SVM) model based on combined features was 93%, which was 7% higher than that based on spectral features only. By applying a median filtering algorithm and a contour detection algorithm to the label matrix extracted from pixel-classified images, except hair, eight impurities were detected successfully. Moreover, taking advantage of the high resolution of a visible light camera, small impurities could be clearly imaged. By comparing the segmented color image with the pixel-classified image, small impurities such as hair could be detected successfully. Finally, it was proved that the system could obtain multiple images to allow a more detailed and comprehensive understanding of the detected items and had an excellent ability to detect small impurities.
Comparative Evaluation of Semi-Empirical Approaches to Retrieve Satellite-Derived Chlorophyll-a Concentrations from Nearshore and Offshore Waters of a Large Lake (Lake Ontario)
Authors: Shahvaran Ali Reza , Kheyrollah Pour Homa , Van Cappellen Philippe
Published: April 2024

Chlorophyll-a concentration (Chl-a) is commonly used as a proxy for phytoplankton abundance in surface waters of large lakes. Mapping spatial and temporal Chl-a distributions derived from multispectral satellite data is therefore increasingly popular for monitoring trends in trophic state of these important ecosystems. We evaluated products of eleven atmospheric correction processors (LEDAPS, LaSRC, Sen2Cor, ACOLITE, ATCOR, C2RCC, DOS 1, FLAASH, iCOR, Polymer, and QUAC) and 27 reflectance indexes (including band-ratio, three-band, and four-band algorithms) recommended for Chl-a concentration retrieval. These were applied to the western basin of Lake Ontario by pairing 236 satellite scenes from Landsat 5, 7, 8, and Sentinel-2 acquired between 2000 and 2022 to 600 near-synchronous and co-located in situ-measured Chl-a concentrations. The in situ data were categorized based on location, seasonality, and Carlson’s Trophic State Index (TSI). Linear regression Chl-a models were calibrated for each processing scheme plus data category. The models were compared using a range of performance metrics. Categorization of data based on trophic state yielded improved outcomes. Furthermore, Sentinel-2 and Landsat 8 data provided the best results, while Landsat 5 and 7 underperformed. A total of 28 Chl-a models were developed across the different data categorization schemes, with RMSEs ranging from 1.1 to 14.1 μg/L. ACOLITE-corrected images paired with the blue-to-green band ratio emerged as the generally best performing scheme. However, model performance was dependent on the data filtration practices and varied between satellites.
Iterative Adaptive Based Multi-Polarimetric SAR Tomography of the Forested Areas
Authors: Jin Shuang , Bi Hui , Guo Qian , Zhang Jingjing , Hong Wen
Published: April 2024

Synthetic aperture radar tomography (TomoSAR) is an extension of synthetic aperture radar (SAR) imaging. It introduces the synthetic aperture principle into the elevation direction to achieve three-dimensional (3-D) reconstruction of the observed target. Compressive sensing (CS) is a favorable technology for sparse elevation recovery. However, for the non-sparse elevation distribution of the forested areas, if CS is selected to reconstruct it, it is necessary to utilize some orthogonal bases to first represent the elevation reflectivity sparsely. The iterative adaptive approach (IAA) is a non-parametric algorithm that enables super-resolution reconstruction with minimal snapshots, eliminates the need for hyperparameter optimization, and requires fewer iterations. This paper introduces IAA to tomographicinversion of the forested areas and proposes a novel multi-polarimetric-channel joint 3-D imaging method. The proposed method relies on the characteristics of the consistent support of the elevation distribution of different polarimetric channels and uses the L2-norm to constrain the IAA-based 3-D reconstruction of each polarimetric channel. Compared with typical spectral estimation (SE)-based algorithms, the proposed method suppresses the elevation sidelobes and ambiguity and, hence, improves the quality of the recovered 3-D image. Compared with the wavelet-based CS algorithm, it reduces computational cost and avoids the influence of orthogonal basis selection. In addition, in comparison to the IAA, it demonstrates greater accuracy in identifying the support of the elevation distribution in forested areas. Experimental results based on BioSAR 2008 data are used to validate the proposed method.
Analysis of Hydrogen Value Chain Events: Implications for Hydrogen Refueling Stations’ Safety
Authors: Badia Eulàlia , Navajas Joaquín , Sala Roser , Paltrinieri Nicola , Sato Hitomi
Published: April 2024

Renewable hydrogen is emerging as the key to a sustainable energy transition with multiple applications and uses. In the field of transport, in addition to fuel cell vehicles, it is necessary to develop an extensive network of hydrogen refueling stations (hereafter HRSs). The characteristics and properties of hydrogen make ensuring the safe operation of these facilities a crucial element for their successful deployment and implementation. This paper shows the outcomes of an analysis of hydrogen incidents and accidents considering their potential application to HRSs. For this purpose, the HIAD 2.0 was reviewed and a total of 224 events that could be repeated in any of the major industrial processes related to hydrogen refueling stations were analyzed. This analysis was carried out using a mixed methodology of quantitative and qualitative techniques, considering the following hydrogen value chain: production, storage, delivery and industrial use. The results provide general information segmented by event frequency, damage classes and failure typology. The analysis shows the main processes of the value chain allow the identification of key aspects for the safety management of refueling facilities.
History Matters: The Institutionalization and Innovation Paradox in the Judiciary
Authors: de Moraes Thiago Maia Sayão , Sousa Marcos de Moraes
Published: April 2024

The judiciary is a field lacking research in relation to its administration and innovation; however, different theoretical perspectives can be followed. This work reviews this trend while adding to it. An institutional perspective is presented, as is its explanatory potential. This perspective captures the context of the public sector; however, when analyzing its interpretation in terms of innovation, it is revealed to be doubly paradoxical. From the theoretical point of view, institutionalization focuses on the maintenance of processes, while innovation, gradually or abruptly, investigates their disruptions. Nevertheless, institutionalization can be observed as part of the sedimentation of innovation. Institutionalization is presented, in the context of innovation, as a selection mechanism that shapes such innovation. This paradox is presented under the review of organizational institutionalism vis-à-vis innovation and, for its unfolding, considers the adoption of innovation as an adaptation to the prevalent rationalized elements. This presentation is paralleled with the interpretation that innovation is limited by a structure that, sometimes rationalized, forms its trajectory. Considering the social function of the judiciary that is anchored in institutionalism, historical institutionalism is thus added, centrally placing the judiciary in the current institutional matrix and associating its path dependence with the dimensions of its innovation. Based on these outlines, propositions and a suggested agenda for future research are presented.
Impacts of Urban Flooding on Gender in a Slum of Bangladesh
Authors: Subah Zarin , Bala Sujit Kumar , Ryu Jae Hyeon
Published: April 2024

Urban flooding is a frequent disaster during the monsoon period (June–October), hindering the daily lives of city dwellers, especially slum dwellers in Dhaka, Bangladesh. This study assessed the impact of urban flooding on the lives of Baganbari slum dwellers in Dhaka, Bangladesh using Moser analytical tools to explore how urban flooding affects individuals of different genders. Participatory and survey methods involving 50 slum dwellers (25 men, 25 women) were carried out to collect feedback and comments. Additionally, focus group discussions (FGDs) and semi-structured and key informant interviews (KII) were also conducted to express gender-related discrimination (e.g., men vs. women). Women are usually involved in “double day” roles (100% in reproductive and 72% in productive roles) while 92% of men are found to have no contribution in those roles. Moreover, women’s participation in community roles is significantly affected during urban flooding (almost 100%) as it imposes a compulsion for them to stay home and carry out their reproductive work. Thus, women encounter numerous challenges in meeting their practical and strategic needs, including ensuring food supplies, managing diseases and menstrual health, upholding sanitation, restricted movement, education obstacles, and more. The result shows that women in the Baganbari slum are found to have only 35% access and 6% control over resources, benefits, health facilities, and decision-making power during urban flooding. The significant decline in the access and control profile of women during urban flooding aggregates their difficulties and drives them into vulnerable positions in their own households.