bluuebunny/crossref_metadata_2025 huggingface dataset:
Prostate Cancer-Specific Lysine 53 Acetylation of Cytochrome c Drives Metabolic Reprogramming and Protects from Apoptosis in Intact Cells
Authors: Morse Paul T. , Wan Junmei , Arroum Tasnim , Herroon Mackenzie K. , Kalpage Hasini A. , Bazylianska Viktoriia , Lee Icksoo , Heath Elisabeth I. , Podgorski Izabela , Hüttemann Maik
Published: June 2024

Cytochrome c (Cytc) is important for both mitochondrial respiration and apoptosis, both of which are altered in cancer cells that switch to Warburg metabolism and manage to evade apoptosis. We earlier reported that lysine 53 (K53) of Cytc is acetylated in prostate cancer. K53 is conserved in mammals that is known to be essential for binding to cytochrome c oxidase and apoptosis protease activating factor-1 (Apaf-1). Here we report the effects of this acetylation on the main functions of cytochrome c by expressing acetylmimetic K53Q in cytochrome c double knockout cells. Other cytochrome c variants analyzed were wild-type, K53R as a control that maintains the positive charge, and K53I, which is present in some non-mammalian species. Intact cells expressing K53Q cytochrome c showed 49% decreased mitochondrial respiration and a concomitant increase in glycolytic activity (Warburg effect). Furthermore, mitochondrial membrane potential was decreased, correlating with notably reduced basal mitochondrial superoxide levels and decreased cell death upon challenge with H2O2 or staurosporine. To test for markers of cancer aggressiveness and invasiveness, cells were grown in 3D spheroid culture. K53Q cytochrome c-expressing cells showed profoundly increased protrusions compared to WT, suggesting increased invasiveness. We propose that K53 acetylation of cytochrome c is an adaptive response that mediates prostate cancer metabolic reprogramming and evasion of apoptosis, which are two hallmarks of cancer, to better promote tumor survival and metastasis.
Enhancing Selective Antimicrobial and Antibiofilm Activities of Melittin through 6-Aminohexanoic Acid Substitution
Authors: Radhakrishnan Naveenkumar , Kumar Sukumar Dinesh , Shin Song-Yub , Yang Sungtae
Published: June 2024

Leucine residues are commonly found in the hydrophobic face of antimicrobial peptides (AMPs) and are crucial for membrane permeabilization, leading to the cell death of invading pathogens. Melittin, which contains four leucine residues, demonstrates broad-spectrum antimicrobial properties but also significant cytotoxicity against mammalian cells. To enhance the cell selectivity of melittin, this study synthesized five analogs by replacing leucine with its structural isomer, 6-aminohexanoic acid. Among these analogs, Mel-LX3 exhibited potent antibacterial activity against both Gram-positive and Gram-negative bacteria. Importantly, Mel-LX3 displayed significantly reduced hemolytic and cytotoxic effects compared to melittin. Mechanistic studies, including membrane depolarization, SYTOX green uptake, FACScan analysis, and inner/outer membrane permeation assays, demonstrated that Mel-LX3 effectively permeabilized bacterial membranes similar to melittin. Notably, Mel-LX3 showed robust antibacterial activity against methicillin-resistant Staphylococcus aureus (MRSA) and multidrug-resistant Pseudomonas aeruginosa (MDRPA). Furthermore, Mel-LX3 effectively inhibited biofilm formation and eradicated existing biofilms of MDRPA. With its improved selective antimicrobial and antibiofilm activities, Mel-LX3 emerges as a promising candidate for the development of novel antimicrobial agents. We propose that the substitution of leucine with 6-aminohexanoic acid in AMPs represents a significant strategy for combating resistant bacteria.
Simultaneous Electrochemical Detection of Dopamine and Tryptophan Using 3D Goethite–Spongin Composites
Authors: Falahi Sedigheh , Kubiak Anita , Voronkina Alona , Ehrlich Hermann , Joseph Yvonne , Rahimi Parvaneh
Published: June 2024

In this study, a facile approach for simultaneous determination of dopamine (DA) and tryptophan (TRP) using a 3D goethite–spongin-modified carbon paste electrode is reported. The prepared electrode exhibited excellent electrochemical catalytic activity towards DA and TRP oxidation. The electrochemical sensing of the modified electrode was investigated using cyclic voltammetry, differential pulse voltammetry, and electrochemical impedance spectroscopy. Through differential pulse voltammetry analysis, two well-separated oxidation peaks were observed at 28 and 77 mV, corresponding to the oxidation of DA and TRP at the working electrode, with a large peak separation of up to 490 mV. DA and TRP were determined both individually and simultaneously in their dualistic mixture. As a result, the anodic peak currents and the concentrations of DA and TRP were found to exhibit linearity within the ranges of 4–246 μM for DA and 2 to 150 μM for TRP. The detection limits (S/N = 3) as low as 1.9 μM and 0.37 μM were achieved for DA and TRP, respectively. The proposed sensor was successfully applied to the simultaneous determination of DA and TRP in human urine samples with satisfactory recoveries (101% to 116%).
A Hybrid EEG-Based Stress State Classification Model Using Multi-Domain Transfer Entropy and PCANet
Authors: Dong Yuefang , Xu Lin , Zheng Jian , Wu Dandan , Li Huanli , Shao Yongcong , Shi Guohua , Fu Weiwei
Published: June 2024

This paper proposes a new hybrid model for classifying stress states using EEG signals, combining multi-domain transfer entropy (TrEn) with a two-dimensional PCANet (2D-PCANet) approach. The aim is to create an automated system for identifying stress levels, which is crucial for early intervention and mental health management. A major challenge in this field lies in extracting meaningful emotional information from the complex patterns observed in EEG. Our model addresses this by initially applying independent component analysis (ICA) to purify the EEG signals, enhancing the clarity for further analysis. We then leverage the adaptability of the fractional Fourier transform (FrFT) to represent the EEG data in time, frequency, and time–frequency domains. This multi-domain representation allows for a more nuanced understanding of the brain’s activity in response to stress. The subsequent stage involves the deployment of a two-layer 2D-PCANet network designed to autonomously distill EEG features associated with stress. These features are then classified by a support vector machine (SVM) to determine the stress state. Moreover, stress induction and data acquisition experiments are designed. We employed two distinct tasks known to trigger stress responses. Other stress-inducing elements that enhance the stress response were included in the experimental design, such as time limits and performance feedback. The EEG data collected from 15 participants were retained. The proposed algorithm achieves an average accuracy of over 92% on this self-collected dataset, enabling stress state detection under different task-induced conditions.
Neuroprotective Potentials of Berberine in Rotenone-Induced Parkinson’s Disease-like Motor Symptoms in Rats
Authors: Tseng Hsiang-Chien , Wang Mao-Hsien , Fang Chih-Hsiang , Lin Yi-Wen , Soung Hung-Sheng
Published: June 2024

Rotenone (RTN) induces neurotoxicity and motor dysfunction in rats, mirroring the pathophysiological traits of Parkinson’s disease (PD), including striatal oxidative stress, mitochondrial dysfunction, and changes in neural structure. This makes RTN a valuable model for PD research. Berberine (BBR), an isoquinoline alkaloid recognized for its antioxidative, anti-inflammatory, and neuroprotective properties, was evaluated for its ability to counteract RTN-induced impairments. Rats received subcutaneous RTN at 0.5 mg/kg for 21 days, resulting in weight loss and significant motor deficits assessed through open-field, bar catalepsy, beam-crossing, rotarod, and grip strength tests. BBR, administered orally at 30 or 100 mg/kg doses, one hour prior to RTN exposure for the same duration, effectively mitigated many of the RTN-induced motor impairments. Furthermore, BBR treatment reduced RTN-induced nitric oxide (NO) and lipid peroxidation (LPO) levels, bolstered antioxidative capacity, enhanced mitochondrial enzyme activities (e.g., succinate dehydrogenase (SDH), ATPase, and the electron transport chain (ETC)), and diminished striatal neuroinflammation and apoptosis markers. Notably, the co-administration of trigonelline (TGN), an inhibitor of the nuclear factor erythroid-2-related factor 2 (Nrf2) pathway, significantly attenuated BBR’s protective effects, indicating that BBR’s neuroprotective actions are mediated via the Nrf2 pathway. These results underscore BBR’s potential in ameliorating motor impairments akin to PD, suggesting its promise in potentially delaying or managing PD symptoms. Further research is warranted to translate these preclinical findings into clinical settings, enhancing our comprehension of BBR’s therapeutic prospects in PD.
Wideband Tympanometry and Pressurized Otoacoustic Emissions in Children with Surgical Excision of Palatine and/or Pharyngeal Tonsils
Authors: Sanches Aline Buratti , Sanfins Milaine Dominici , Skarzynski Piotr Henryk , Skarżyńska Magdalena Beata , Penatti Henrique Costa , Donadon Caroline , Souza Ingrid Pereira de , Silva Ingridy Vitoria da , Colella-Santos Maria Francisca
Published: June 2024

Palatine and pharyngeal tonsil hypertrophy may lead to dysfunction of the auditory tube due to a propensity for infection, potentially giving rise to otitis media. This is a quantitative and longitudinal study, developed from 2019 to 2021, at the State University of Campinas (UNICAMP). The studied sample comprised 15 participants aged 5 to 12 years (mean 7.9 years), 12 male and 3 female, arranged into two groups: children diagnosed with pharyngeal and/or palatine tonsil hypertrophy who were candidates for surgery (G1), and children who were later evaluated after surgery (G2). As part of the test, an otoscopy and measurements of logoaudiometry, pure-tone threshold audiometry, wideband tympanometry (ambient and peak pressure), and otoacoustic emissions (TEOAEs and DPOAEs, both at ambient and peak pressure) were all performed. There were statistically significant differences between phases in pure-tone audiometry, in terms of 226 Hz tympanometry, wideband tympanometry in peak pressure conditions, in the amplitude measurement TEOAEs in both pressure conditions, in DPOAEs in ambient pressure conditions, and in the signal/noise measurement in both pressures in DPOAEs. Overall, it was found that hearing tests were different for subjects with palatine and pharyngeal tonsil hypertrophy compared to the post-surgical group.
Correction: Greiner et al. Consecutive-Day Ventricular and Atrial Cardiomyocyte Isolations from the Same Heart: Shifting the Cost–Benefit Balance of Cardiac Primary Cell Research. Cells 2022, 11, 233
Authors: Greiner Joachim , Schiatti Teresa , Kaltenbacher Wenzel , Dente Marica , Semenjakin Alina , Kok Thomas , Fiegle Dominik J. , Seidel Thomas , Ravens Ursula , Kohl Peter , Peyronnet Rémi , Rog-Zielinska Eva A.
Published: June 2024

In the original publication [...]
A Psychometric Examination of the Abbreviated Version of the Parenting Styles Scale Using a Sample of Chilean Adolescents
Authors: Gálvez-Nieto José Luis , Polanco-Levicán Karina , Salvo-Garrido Sonia , Godoy-Bello María Pía
Published: June 2024

Parenting styles have been related to a series of variables that contribute positively to adulthood. The maternal and paternal parenting styles scale is a measure that presents a multidimensional structure of six correlated factors. However, the version available for Chile is extensive, with 82 items measuring this latent trait. Therefore, the aim of this study was to examine the psychometric properties of the reliability and validity of the abbreviated version of the maternal and paternal parenting styles scale using a sample of Chilean adolescents. The sample consisted of 2131 students of both the male and female sexes (51% males and 49% females) with a mean age of 15.85 years (SD = 1.37). The results of the exploratory and confirmatory factor analyses supported the six-factor correlated model, showing robust psychometric indices for both modelling approaches. In relation to the factorial invariance models, the results show factorial equivalence at the scalar invariance level for the variables of sex, age, academic achievement, and type of school. The scale showed adequate levels of reliability. This study concludes that the abbreviated version of the maternal and paternal parenting styles scale is a reliable and valid instrument for its application in Chilean adolescents.
Exploring the Relationship between Wind Patterns and Hospital Admissions Due to Respiratory Symptoms in Children
Authors: Boura Despoina , Spanakis Marios , Markakis George , Notas George , Lionis Christos , Tzanakis Nikolaos , Paraskakis Emmanouil
Published: June 2024

Respiratory disorders significantly impact adolescents’ health, often resulting in hospital admissions. Meteorological elements such as wind patterns have emerged as potential contributors to respiratory symptoms. However, it remains uncertain whether fluctuations in wind characteristics over extended periods have a tangible impact on respiratory health, particularly in regions characterized by distinct annual wind patterns. Crete is situated in the central-eastern Mediterranean Sea and frequently faces southerly winds carrying Sahara Desert sand from Africa and northerly winds from the Aegean Sea. This retrospective study analyzes long-term wind direction data and their relationship to respiratory symptoms observed in children up to 14 years old admitted at the University Hospital of Heraklion between 2002 and 2010. Symptoms such as headache, dyspnea, dry cough, dizziness, tachypnea, throat ache, and earache were predominantly reported during the presence of southern winds. Fever, productive cough, and chest pain were more frequently reported during northern winds. Cough was the most common symptom regardless of the wind pattern. Southern winds were significantly associated with higher probabilities of productive or non-productive cough, headache, dyspnea, tachypnea, dizziness, earache, and throat ache. Northern winds were related to a higher incidence of productive cough. Rhinitis, asthma, allergies, pharyngitis, and sinusitis were related to southern winds, while bronchiolitis and pneumonia were associated with northern winds. These findings underscore the critical role of local climatic factors, emphasizing their potential impact on exacerbating respiratory conditions in children. Moreover, they point out the need for further research to elucidate the underlying mechanisms and develop targeted interventions for at-risk populations.
Incidence and Importance of Peripheral Vestibular Dysfunction in Adolescent Idiopathic Scoliosis
Authors: Vlădăreanu Liliana , Iliescu Mădălina Gabriela , Andronache Iulia Tania , Danteș Elena
Published: June 2024

Adolescent idiopathic scoliosis (AIS) is a common form of scoliosis. As the name suggests, etiopathogenesis is not clearly defined, so treatment is still anchored in the musculoskeletal theory and correction/prevention of high Cobb angle values. This study aimed to determine whether there is any connection between developing scoliotic curvature and a positive history of motion sickness as a symptom of a peripheral vestibular dysfunction/deficit, and if vestibular rehabilitation exercises could be integrated into the treatment plan. The study was conducted over 12 months on a selected population of 159 patients to evaluate or treat scoliotic curvatures in a private clinic. The collected data were analyzed using IBM SPSS Statistics 25 and illustrated using Microsoft Office Excel/Word 2021. Patients with peripheral vestibular dysfunction had significantly higher Cobb angle values when compared to patients with a negative result in an instrumental test for peripheral vestibular dysfunction. Motion sickness was considerably more associated with peripheral vestibular dysfunction, and a positive Fukuda stepping test was associated with a positive history of motion sickness. Adolescent idiopathic scoliosis with higher Cobb angles is related to positive motion sickness history as part of peripheral vestibular dysfunction. Conservative treatment for scoliosis could incorporate sensory integration techniques, and a positive history of motion sickness could be an indicator of a higher risk of progression in adolescent idiopathic scoliosis.
Polarization-Dependent Plasmon Coupling in Gold Nanoparticles and Gold Thin-Film Systems
Authors: Shan Feng , Zhu Yanyan , Huang Jingyi
Published: June 2024

The characteristics of gap plasmon formed by nanoparticle-on-mirror (NPOM) structures composed of metal nanoparticles (MNPs) and metal thin films have aroused interest for use in various optoelectronic devices. The resonance enhancement characteristics in the gap region of an NPOM structure composed of gold nanoparticles and gold thin films are simulated theoretically by the finite element method (FEM). The resonant spectrum obtained by the internal coupling effect of the gap can be flexibly controlled by the polarization of incident light and the thickness of the dielectric layer between the MNPs and the metal thin films. We study the resonance spectra of polarization-dependent gold ellipsoidal nanoparticles (GENPs) and gold thin films in the gap region of an NPOM structure. The GENPs and gold thin films are separated by a dielectric layer with a refractive index of 1.36. We observe that the intensity of the resonance electric field in the gap region is inversely proportional to the polarization angle. Similarly, the intensity of the local electric field resonance peak in the gap region is inversely proportional to the thickness of the dielectric layer. When the thickness of the dielectric layer is 0.3 nm and the polarization angle is 0°, the best resonant electric field intensity of 2200 V/m is obtained in the gap region of the NPOM structure (the power of incident light is 1 mW). Finally, the resonant peak wavelength of the electric field in the gap region of the NPOM structure is also controlled by the polarization angle of the incident light and the thickness of the dielectric layer.
The Effect of Different Coating Agents on the Microhardness, Water Sorption, and Solubility of EQUIA Forte® HT
Authors: Alqasabi Saleh Y. , Sulimany Ayman M. , Almohareb Thamer , Alayad Abdullah S. , Bawazir Omar A.
Published: June 2024

Objective: This study aimed to assess the effect of four different surface-coating agents on the microhardness, water sorption, and solubility of the highly viscous glass ionomer cement EQUIA Forte® HT. Materials and methods: A total of 100 cylindrical EQUIA Forte® HT samples were examined, with 50 tested for Vickers hardness and the other 50 for water sorption and solubility. For each test, the specimens were divided into five groups (10 specimens/group) according to coating method: Group 1—no coating (control), Group 2—EQUIA Forte® Coat, Group 3—Single Bond™ Universal Adhesive, Group 4—ExciTE®F adhesive, and Group 5—petroleum jelly. Data were analyzed using the paired t-test, one-way analysis of variance, and Tukey’s post hoc test for multiple comparisons. Statistical significance was set at p < 0.05. Results: The mean microhardness of the coated groups was significantly higher than that of the uncoated group. Moreover, a significant difference in the microhardness value was detected between the coated groups. Furthermore, EQUIA Forte® Coat had the highest mean hardness value. The mean water sorption at 7 days showed that EQUIA Forte® Coat had the lowest values. In terms of water solubility, a statistically significant difference was found between no coating and all groups except EQUIA Forte®, between Single Bond Universal Adhesive and petroleum jelly, between petroleum jelly and EQUIA Forte Coat, and between EQUIA Forte® Coat and ExciTE®F. Conclusions: The study revealed that all coating agents significantly increased the microhardness of EQUIA Forte® HT, with EQUIA Forte® Coat showing the highest hardness and the lowest water sorption values.
The Effects of Preharvest Silicon Treatment and Passive MAP on Quality and Shelf Life of White Button Mushrooms in Thermoformed Recycled PET Packaging System
Authors: Shonte Tigist T. , Grogan Helen , Frias Celayeta Jesus Maria , Giordano Francesco S. , Reynolds Andrew , O’Halloran Orla , Foley Lorraine , Pathania Shivani
Published: June 2024

A crop pretreatment with silicon was combined with passive modified atmosphere packaging (PMAP) in a thermoformed recycled PET packaging format as a novel approach to minimize the quality degradation in mushrooms. This study was aimed to evaluate the effects of (a) two preharvest treatments, namely preharvest control (PHTC) and preharvest silicon treatment (PHTS) and (b) four packaging lid formats, namely PMAP1: a single hole of 1.1 mm size, PMAP2: two holes of 0.53 mm size, PMAP3: three holes of 0.53 mm size, and PMAPC: OMNI-PW micro perforated cling film as a control on the quality and shelf life of mushrooms during five days of storage at 4 °C and 99.9% RH. The results of the analysis of variance showed that packaging type, storage days, and the double interaction effects of storage days × packaging type had significant effects (p < 0.0001) on the changes in O2, CO2, colour L* and a* values, ΔE, total soluble solids (TSS), and the density of mushrooms. Density, electrolyte leakage (EL), and TSS were significantly affected by the double interaction effects of preharvest treatment × packaging type. Overall, PMAP1, PMAP2, and PMAP3 resulted in lower O2 + higher CO2 within packages compared with the conventional control. A preharvest silicon treatment had little overall effect. PMAP 1, 2 and 3 had a significantly lower ΔE (=better quality) after 5 days storage compared to PMAPC which had the highest ΔE (lowest quality) overall. PMAP1 and PMAP2 had the lowest EL values compared to PMAP3 and PMAPC. PMAP1, PMAP2, and PMAP3 all gave better TSS levels and density compared to PMAPC. Notably, this study proved that a perforation-mediated MAP design for mushrooms packaged in a thermoformed recycled PET packaging format maintained improved CO2, lowered O2, and reduced EL while maintaining TSS and the density of the mushrooms during the storage period.
Effect of Deep Cryogenic Treatment on the Artificial Aging Behavior of 6082 Aluminum Alloy
Authors: Qiu Sawei , Tang Jian , Tian Yiran , Wu Changping , Ye Tuo , Xia Erli , Wu Yuanzhi
Published: June 2024

This study investigates the impact of cryogenic treatment duration on the mechanical properties and microstructural evolution of 6082 aluminum alloy subjected to subsequent artificial aging. Tensile tests were conducted using an electronic universal testing machine, and the microstructure was characterized by employing optical microscopy (OM), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The results indicate that both the tensile strength and elongation of the alloy first increase and then decrease with the extension of cryogenic treatment duration. The alloy treated with 12 h of cryogenic treatment followed by artificial aging at 180 °C for 8 h achieved a peak strength of 390 MPa. Meanwhile, the alloy treated with 8 h of cryogenic treatment and the same artificial aging process reached a maximum elongation of 13%. All specimens of 6082 aluminum alloy subjected to cryogenic and aging treatments exhibited ductile fracture under room temperature tensile conditions. The size of dimples at the fracture surface first increased and then decreased with increasing cryogenic treatment duration, indicating a transition from deeper to shallower dimples. The cryogenic treatment did not significantly affect the grain size of the alloy, which remained approximately 230 µm on average. Cryogenic treatment facilitated the precipitation of fine, densely distributed precipitates, enhancing the pinning effect of dislocations and thus improving the tensile strength. Additionally, cryogenic treatment increased the dislocation density and promoted the formation of subgrains, while the grain boundary precipitates transitioned from a continuous to a discontinuous distribution, all of which contribute to the enhancement of the plasticity.
Modeling for the Fabrication Process of a ϕ1185 mm C/C Composite Thermal Insulation Tube in an Isothermal Chemical Vapor Infiltration Reactor
Authors: Zhou Jicheng , Zhan Jianyong , Liang Huiling , Guo Yan , Zhao Baoxing , Hao Linzhao , Zhang Tong , Jiang Bingchun
Published: June 2024

The large-size chemical vapor infiltration (CVI) of the carbon/carbon (C/C) composite thermal insulation tube is a key component for drawing large diameter monocrystalline silicon rods. However, the CVI densification process is complex, and the cost of experiment optimization is extremely high. In this article, a multi-physics coupling simulation model was established and validated based on COMSOL Multiphysics v.5.6 software to simulate the fabrication process of an isothermal CVI process for a Φ1185 mm C/C composite thermal insulation tube. The influence of process parameters on densification was explored, and a method of optimization was proposed. Our modeling results revealed that the deposition status in areas of low densification was effectively and significantly enhanced after process optimization. At the monitoring site, the carbon density was no less than 1.08 × 103 kg·m−3, the average density of the composite-material thermal insulation tube improved by 5.7%, and the densification rate increased by 26.5%. This article effectively simulates the CVI process of large-sized C/C composite thermal insulation tubes, providing an important technical reference scheme for the preparation of large-sized C/C composite thermal insulation tubes.
Joining and Coating of Plasma Electrolytic Oxidated Aluminum Using a Silica Preceramic Polymer
Authors: Ferraris Monica , Benelli Alessandro , Casalegno Valentina , Shashkov Pavel , Sglavo Vincenzo Maria
Published: June 2024

This study evaluates the effectiveness of a silica preceramic polymer for joining and coating Plasma Electrolytic Oxidated (PEO) aluminum components at temperatures below 200 °C. PEO aluminum slabs were coated and joined with a silica precursor polymer (Durazane1800, Merck, Darmstadt, Germany), both with and without the addition of 48 wt% silica nanoparticles, and cured at 180 °C for 4 h in air. Thermogravimetric analysis assessed the curing process and thermal stability, while X-ray diffraction confirmed the polymer’s conversion to amorphous silica after heating at 1200 °C. Resistance to humid environments was tested by soaking coated samples in tap water for a week, with no mass variation observed. Mechanical testing through tensile mode and tensile lap tests showed that adding 48 wt% silica nanoparticles significantly improved joint cohesion and nearly quadrupled mechanical strength. Fracture surfaces were examined using Field Emission Scanning Electron Microscopy, and composition analysis was performed with Energy Dispersion X-ray Spectroscopy. Crack detection was conducted using Computer Tomography with an in situ bending test setup to obtain the mechanical resistance of the PEO coating. The results indicate that the silica preceramic polymer is suitable for joining and coating PEO aluminum components, with silica nanoparticles enhancing mechanical strength and providing excellent thermal stability and resistance to humidity.
Water-Borne Photo-Thermal Superhydrophobic Coating for Anti-Icing, Self-Cleaning and Oil–Water Separation
Authors: Huang Jinsong , Lu Shengqi , Hu Yan , Liu Liming , You Hui
Published: June 2024

Superhydrophobic coatings with photo-thermal effects have advantages in anti-/de-icing and self-cleaning. Here, an eco-friendly and low-cost fabrication of superhydrophobic coating was proposed by spraying a water-borne suspension including carbon black and paraffin wax onto substrate-independent surfaces. The a water-borne suspension coated on stain steel plate showed a strong water-repellence, delaying the ice freezing time to 665 s, which is much higher than that of bare stain steel plate (210 s) under the same experimental condition. The ice-melting time was measured as 120 s under a solar irradiation of 0.1 W/cm2, while the control group had no sign of ice-melting during the same time. As a concept of proof, the self-cleaning, anti-corrosion, and oil–water separation were enabled by spraying the water-borne suspension on various substrates, demonstrating its diverse performances. Hence, the water-borne superhydrophibic coating provides an efficient, safe, and sustainable solution for wettability-related applications.
Superlattice Symmetries Reveal Electronic Topological Transition in CaC6 with Pressure
Authors: Wang Bruce , Bianconi Antonio , Mackinnon Ian D. R. , Alarco Jose A.
Published: June 2024

The electronic properties of calcium-intercalated graphite (CaC6) as a function of pressure are revisited using density functional theory (DFT). The electronic band structures of CaC6, like many other layered superconducting materials, display cosine-shaped bands at or near the Fermi level (FL). Such bands encompass bonding/antibonding information with a strong connection to superconducting properties. Using a hexagonal cell representation for CaC6, the construction of a double supercell in the c-direction effects six-folding in the reciprocal space of the full cosine function, explicitly revealing the bonding/antibonding relationship divide at the cosine midpoint. Similarly, folding of the Fermi surface (FS) reveals physical phenomena relevant to electronic topological transitions (ETTs) with the application of pressure. The ETT is characterised by a transition of open FS loops to closed loops as a function of pressure. As the highest transition temperature is reached with pressure, the dominant continuous, open FS loops shift to a different region of the FS. For CaC6, the peak value for the superconducting transition temperature, Tc, occurs at about 7.5 GPa, near the observed pressure of the calculated ETT. At this pressure, the radius of the nearly spherical Ca 4s-orbital FS coincides with three times the distance from the Γ centre point to the Brillouin zone (BZ) boundary of the 2c supercell. In addition, the ETT coincides with the alignment of the nonbonding (inflection) point of the cosine band with the FL. At other calculated pressure conditions, the Ca 4s-orbital FS undergoes topological changes that correspond and can be correlated with experimentally determined changes in Tc. The ETT is a key mechanism that circumscribes the known significant drop in Tc for CaC6 as a function of increasing pressure. Consistent calculated responses of the ETT to pressure match experimental measurements and validate the examination of superlattices as important criteria for understanding mechanisms driving superconductivity.
Four New Sudanonautes Species of Freshwater Crabs (Crustacea: Decapoda: Potamonautidae) from Cameroon, Central Africa
Authors: Mvogo Ndongo Pierre A. , Clark Paul F. , von Rintelen Thomas , Cumberlidge Neil
Published: June 2024

Four new species of freshwater crab are described from material collected in northern and southwestern Cameroon and assigned to Sudanonautes Bott, 1955. Sudanonautes cameroonensis sp. n., S. eyimba sp. n., S. ngaoundere sp. n. and S. nkam sp. n., are distinguished by characters of the carapace, thoracic sternum, chelipeds, mandibles, adult male gonopods, and in addition by genetic analyses using the mitochondrial CO1 and 16S rRNA genes. Diagnoses, illustrations, and a phylogenetic tree based on mtDNA sequences are provided, as well as a discussion of the threats and conservation of all species.
The Complete Mitogenomes of Two Species of Snakehead Fish (Perciformes: Channidae): Genome Characterization and Phylogenetic Analysis
Authors: Xu Tangjun , Zhang Wenwen , Li Yao , Wang Jiachen , Bai Yawen , Liu Hongyi
Published: June 2024

Channidae (snakehead fish) is a family of medium-to-large freshwater carnivorous fish and contain the genus, Channa. Here, the complete mitogenomes of two Channa fish were determined and comparatively analyzed with the mitogenomes of 16 other Channidae fish species. The two newly sequenced complete mitogenomes were circular DNA molecules with sizes of 16,953 bp (Channa burmanica; OP954106) and 16,897 bp (Channa aurantimaculata; OQ134162). The mitogenomes were composed of 37 genes and one D-loop region. Positive AT skews and negative GC skews were found in the mitogenomes. Most protein-coding genes (PCGs) started with the conventional start codon, ATG; however, the sequence of the stop codon was variable. There was no obvious difference in relative synonymous codon usage among the two mitogenomes, and the two species shared a similar number of codon usage of mitogenomic PCGs, which was also similar to the mean values for the other 15 species of Channa. All Ka/Ks values were <1; cox1 had the lowest value, and atp8 had the highest. All of the tRNAs were typical clover structures, except trnS1. Phylogenetic analysis showed that C. burmanica and C. aurantimaculata shared a close relationship and that they were also closely related to C. gachua. These findings enrich the gene database of Channidae species, clarify the mitochondrial genome structure of the two species, and provide basic data for invasive biological surveillance in the future.
CrazyPAD: A Dataset for Assessing the Impact of Structural Defects on Nano-Quadcopter Performance
Authors: Masalimov Kamil , Muslimov Tagir , Kozlov Evgeny , Munasypov Rustem
Published: June 2024

This article presents a novel dataset focused on structural damage in quadcopters, addressing a significant gap in unmanned aerial vehicle (UAV or drone) research. The dataset is called CrazyPAD (Crazyflie Propeller Anomaly Data) according to the name of the Crazyflie 2.1 nano-quadrocopter used to collect the data. Despite the existence of datasets on UAV anomalies and behavior, none of them covers structural damage specifically in nano-quadrocopters. Our dataset, therefore, provides critical data for developing predictive models for defect detection in nano-quadcopters. This work details the data collection methodology, involving rigorous simulations of structural damages and their effects on UAV performance. The ultimate goal is to enhance UAV safety by enabling accurate defect diagnosis and predictive maintenance, contributing substantially to the field of UAV technology and its practical applications.
Modeling the Economic Impact of the COVID-19 Pandemic Using Dynamic Panel Models and Seemingly Unrelated Regressions
Authors: Vrontos Ioannis D. , Galakis John , Panopoulou Ekaterini , Vrontos Spyridon D.
Published: June 2024

The importance of assessing and estimating the impact of the COVID-19 pandemic on financial markets and economic activity has attracted the interest of researchers and practitioners in recent years. The proposed study aims to explore the pandemic’s impact on the economic activity of six Euro area economies. A class of dynamic panel data models and their corresponding Seemingly Unrelated Regression (SUR) models are developed and applied to model the economic activity of six Eurozone countries. This class of models allows for common and country-specific covariates to affect the real growth, as well as for cross-sectional dependence in the error processes. Estimation and inference for this class of panel models are based on both Bayesian and classical techniques. Our findings reveal that significant heterogeneity exists among the different economies with respect to the explanatory/predictive factors. The impact of the COVID-19 pandemic varied across the Euro area economies under study. Nonetheless, the outbreak of the COVID-19 pandemic profoundly affected real economic activity across all regions and countries. As an exogenous shock of such magnitude, it caused a sharp increase in overall uncertainty that spread quickly across all sectors of the global economy.
The Von Neumann–Morgenstern Curve and Bank Capital Adequacy Penalties—An Empirical Analysis
Authors: Draper Thomas , Cavagnetto Stefano
Published: June 2024

The risk of lending money collected from savers is that it leaves banks liable to default with depositors if events (and hence repayment demands) become ‘abnormal’. Even though international and national regulation has been introduced to ensure that a certain level of capital is retained by banks, such regulation can be subverted. The current system of international regulation based on the Basel III agreements does not stipulate a standardised approach for inspection frequency or penalty magnitude. This leaves the potential for regulatory arbitrage. The scientific value of an analysis to optimise regulatory efficiency and reduce such arbitrage is therefore considerable. This work therefore assesses the results of the empirical testing of a model based on the Von Neumann–Morgenstern utility function and consequently proposes that this model be used as a basis for standardising capital adequacy limit infraction penalties on an international level to prevent regulatory arbitrage. A survey is undertaken in order to test the responses of participants on the level of penalty which would deter them from regulatory transgression under different theorised levels of profit and probability of discovery. Based on the responses of two distinct subject groups (‘bankers’ and ‘non-bankers’) in different scenarios of hypothetical capital adequacy violation, the Von Neumann–Morgenstern utility function is reviewed against empirical results and revealed to show a semi-strong correlation. Lastly, the analysis reveals the striking similarities of the two groups’ responses, posing regulatory implications for the industry.
PhDs of International Students—The Case of Israeli PhDs
Authors: Mashraki Nissim , Tavor Dorith , Gerkerova Aleksandra , Davidovitch Nitza
Published: June 2024

Pursuing academic studies in foreign countries is a globally prevalent phenomenon for diverse reasons: earning a degree in high-demand subjects from a prestigious university opens more doors than a diploma earned locally. Earning a degree overseas is an opportunity to expand one’s horizons and gain new experiences and exposure to other cultures. In addition, other personal and/or academic reasons that prevent students from pursuing a degree in their home country, such as age, admission requirements, and difficulty in finding an appropriate supervisor, motivate them to choose a degree program in a foreign country. The current study examines the motives of PhD degree holders who are Israeli residents who completed their doctorate studies overseas and explores the aspirations they hope to achieve through such studies. The study examines several aspects of the profiles of PhD holders who chose to study overseas, including demographic, socioeconomic, academic, financial, and professional, as well as their aims. The study sample comprised 153 PhD holders who earned their PhD degree in the field of education overseas and applied to the Israeli Ministry of Education for accreditation of their degree. The sample focuses on PhD holders in the social sciences and humanities, specifically in education. The study was conducted using the quantitative method and is based on a survey. The findings of the study offer insights into decision makers in higher education in Israel and their efforts to assess the value of the degrees presented for accreditation by PhD holders who earned their degrees overseas.
Correction: Chu et al. Temporal Attention Mechanism Based Indirect Battery Capacity Prediction Combined with Health Feature Extraction. Electronics 2023, 12, 4951
Authors: Chu Fanyuan , Shan Ce , Guo Lulu
Published: June 2024

There was an error in the original publication [...]
Dynamic Difficulty Adaptation Based on Stress Detection for a Virtual Reality Video Game: A Pilot Study
Authors: Orozco-Mora Carmen , Fuentes-Aguilar Rita , Hernández-Melgarejo Gustavo
Published: June 2024

Virtual reality (VR) is continuing to grow as more affordable technological devices become available. Video games are one of the most profitable applications, while rehabilitation has the most significant social impact. Both applications require a proper user evaluation to provide personalized experiences that avoid boring or stressful situations. Despite the successful applications, there are several opportunities to improve the field of human–machine interactions, one of the most popular ones being the use of affect detection to create personalized experiences. In that sense, this study presents the implementation of two dynamic difficulty adaptation strategies. The person’s affective state is estimated through a machine learning classification model, which later serves to adapt the difficulty of the video game online. The results show that it is possible to maintain the user at a given difficulty level, which is analogous to achieving the well-known flow state. Among the two implemented strategies, no statistical differences were found in the workload induced by the users. However, more physical demands and a higher frustration were induced by one of the strategies, validated with the recorded muscular activity. The results obtained contribute to the state of the art of DDA strategies in virtual reality driven by affective data.
RSCAN: Residual Spatial Cross-Attention Network for High-Fidelity Architectural Image Editing by Fusing Multi-Latent Spaces
Authors: Zhu Cheng , Zhao Guangzhe , Lin Benwang , Wang Xueping , Yan Feihu
Published: June 2024

Image editing technology has brought about revolutionary changes in the field of architectural design, garnering significant attention in both the computer and architectural industries. However, architectural image editing is a challenging task due to the complex hierarchical structure of architectural images, which complicates the learning process for the high-dimensional features of architectural images. Some methods invert the images into the latent space of a pre-trained generative adversarial network (GAN) model, completing the editing process by manipulating this latent space. However, the task of striking a balance between reconstruction fidelity and editing efficacy through latent space mapping presents a formidable challenge. To address this issue, we propose a Residual Spatial Cross-Attention Network (RSCAN) for architectural image editing, which is an encoder model integrating multiple latent spaces. Specifically, we introduce the spatial feature extractor, which maps the image to the high-dimensional space F of the synthesis network, to enhance the spatial information retention and preserve the structural consistency of the architectural image. In addition, we propose the residual cross-attention to learn the mapping relationship between the low-dimensional space W and F space, generating modified features corresponding to the latent code and leveraging the benefits of multiple latent spaces to facilitate editing. Extensive experiments are performed on the LSUN Church dataset, and the experimental results indicate that our proposed RSCAN achieves significant improvements over the relevant methods in quantitative analysis metrics including the reconstruction quality, SSIM, FID, L2, LPIPS, PSNR, and editing effect ΔS, with enhancements of 29.49%, 17.29%, 8.81%, 11.43%, 11.26%, and 47.8%, respectively, thereby enhancing the practicality of architectural image editing.
Entity Alignment with Global Information Aggregation
Authors: Zhang Liguo , Li Zhao , Li Ye , Wu Shiwei , Chen Tong
Published: June 2024

Entity alignment (EA) is a critical task in knowledge graph fusion, aiming to associate equivalent entities across disparate knowledge graphs (KGs). Current methods typically leverage entity representations derived from triples or neighboring entities, employing similarity matching for alignment. These approaches, however, tend to be overly reliant on proximal neighbor information and struggle with graph over-smoothing introduced by neighborhood aggregation. In response to these limitations, this study introduces a Global Information Aggregator (GIA), a new method that aims to enhance entity representation and simultaneously alleviate over-smoothing by merging the global structural information of the entire knowledge graph. Specifically, we propose a PageRank-based method to aggregate the global structural information of KGs. In addition, the GIA generates a diffusion-augmented graph by propagating and integrating the global information of the KGs. This graph is subsequently compared with a structural perturbation-augmented graph to yield more robust and comprehensive entity representations, thus further improving the model’s alignment performance. Extensive experiments on four benchmark datasets show that the GIA model is highly competitive with current state-of-the-art entity alignment frameworks.
Constraints on Organic Matter Stability in Pyrenean Subalpine Grassland Soils: Physical Protection, Biochemical Quality, and the Role of Free Iron Forms
Authors: Rovira Pere , Sauras-Yera Teresa , Poch Rosa Maria
Published: June 2024

The stability of soil organic matter (SOM) depends on its degree of physical protection, biochemical quality (q), and mineralogical features such as the abundance of iron or aluminum oxyhydroxides: All constraints stabilize SOM, but the relevance of each is herein discussed. We studied from this point of view the stability of SOM in four grassland soils. The SOM in these profiles was characterized for its physical protection (ultrasonic dispersion + size fractionation) and its q (acid hydrolysis, carbohydrates, phenolics, and unhydrolyzable carbon). The profiles were also analyzed for free iron forms extracted with several chemicals: dithionite-citrate-bicarbonate, citric acid, oxalic-oxalate (Tamm’s solution), and DTPA. Soil horizons were incubated under optimal conditions to obtain the C lost after 33 days (Cresp33) and basal respiration rate (BRR). The microbial C was obtained at the end of the incubation. The microbial activity rate (MAR: mg C respired per g microbial C per day) was obtained from these measures. The sum soluble + microbial C was taken as the active C pool. As expected, the stability of SOM depends on its distribution between the size fractions: The higher the proportion of particulate organic matter (POM: >20 µm size), the higher the soil respiration rate. In contrast, q barely affects SOM decomposition. Both physical availability (size fractionation) and q (acid hydrolysis) affect the size of the microbial C pool, but they barely affect MAR. The effects of free iron on SOM stability are complex: While dithionite-extracted Fe negatively affected Cresp33, BRR, and MAR, the Fe extracted by smoother methods (Tamm’s reagent and DTPA) positively relates to Cresp33, BRR, and MAR. Free iron apparently modulates soil microbial metabolism because it is the only studied parameter that significantly affected MAR; however, the precise effect depends on the precise free Fe fraction. From our data, SOM stability relies on a net of constraints, including physical availability and free Fe forms, with q being of minor relevance. Our dataset suggests a role for free iron as a modulator of microbial activity, deserving future research.