bluuebunny/crossref_metadata_2025 huggingface dataset:
Mechanical Behavior of Titanium Based Metal Matrix Composites Reinforced with TiC or TiB Particles under Quasi-Static and High Strain-Rate Compression
Authors: Markovsky Pavlo E. , Janiszewski Jacek , Stasyuk Oleksandr O. , Bondarchuk Vadim I. , Savvakin Dmytro G. , Cieplak Kamil , Goran Daniel , Soni Purvesh , Prikhodko Sergey V.
Published: November 2021

The mechanical behavior of titanium alloys has been mostly studied in quasi-static conditions when the strain rate does not exceed 10 s−1, while the studies performed in dynamic settings specifically for Ti-based composites are limited. Such data are critical to prevent the “strength margin” approach, which is used to assure the part performance under dynamic conditions in the absence of relevant data. The purpose of this study was to obtain data on the mechanical behavior of Ti-based composites under dynamic condition. The Metal Matrix Composites (MMC) on the base of the alloy Ti-6Al-4V (wt.%) were made using Blended Elemental Powder Metallurgy with different amounts of reinforcing particles: 5, 10, and 20% of TiC or 5, 10% (vol.) of TiB. Composites were studied at high strain rate compression ~1–3 × 103·s−1 using the split Hopkinson pressure bar. Mechanical behavior was analyzed considering strain rate, phase composition, microstructure, and strain energy (SE). It is shown that for the strain rates up to 1920 s−1, the strength and SE of MMC with 5% TiC are substantially higher compared to particles free alloy. The particles TiC localize the plastic deformation at the micro level, and fracturing occurs mainly by crushing particles and their aggregates. TiB MMCs have a finer grain structure and different mechanical behavior. MMC with 5 and 10% TiB do not break down at strain rates up to almost 3000 s−1; and 10% MMC surpasses other materials in the SE at strain rates exceeding 2200 s−1. The deformation mechanism of MMCs was evaluated.
Structure of a Fe4O6-Heteraadamantane-Type Hexacation Stabilized by Chelating Organophosphine Oxide Ligands
Authors: Pietrzak Anna , Guschlbauer Jannick , Kaszyński Piotr
Published: November 2021

Metal-containing heteraadamantanes are compounds of interest due to their spectroscopic and magnetic properties, which make them promising materials for non-linear optics and semiconductors. Herein we report the comprehensive structural characterization of a new coordination compound of the formula [(µ-OH′)2(µ-OH″)4(O = P(Ph2)CH2CH2(Ph2)P = O)4{Fe(t-BuOH)}4](PF6)4(Cl)2 with the chelating ligand Ph2P(O)-CH2CH2-P(O)Ph2. The compound crystallizes as a polynuclear metal complex with the adamantane-like core [Fe4O6] in the space group I-43d of a cubic system. The single-crystal XRD analysis showed that the crystal contains one symmetrically independent octahedrally coordinated Fe atom in the oxidation state +3. The adamantine-like scaffold of the Fe complex is formed by hydroxy bridging oxygen atoms only. Hirshfeld surface analysis of the bridging oxygen atoms revealed two types of µ-OH groups, which differ in the degree of exposure and participation in long-range interactions. Additionally, the Hirshfeld surface analysis supported by the enrichment ratio calculations demonstrated the high propensity of the title complex to form C-H…Cl, C-H…F and C-H…O interactions.
Methods Development for the Constrained Elastic Modulus Investigation of Organic Material in Natural Soil Conditions
Authors: Meyer Zygmunt , Olszewska Magdalena
Published: November 2021

Compressibility is one of the most important mechanical properties of soil. The parameter that characterizes compressibility is the constrained modulus of elasticity. Knowledge of this is important to calculate the settlement of a structure foundation on peat material. According to soil classification by EN ISO 14688-2, peat is an organic soil that contains min. 20% organic matter. It is a highly organic type of soil. Peat material has large compressibility. The value of the constrained elasticity modulus for peat is ca. 400 kPa, while it may be ca 1.0–1.6 MPa for consolidated peat. Due to the extensive range of the modulus, experimental research in this field is proposed. It is suggested to load the peat material layer with an embankment and to determine its total settlement. Based on this, a program was developed to determine the settlement–strain relationship. The authors propose an approach according to two models: the first is based on constant stress distribution in the soil with an oedometer test. The second considers the variability of stresses in the soil and the influence of the loaded area. Both methods were tested based on numerical simulations, and then an experimental field in Szczecin was used. The formulae for the constrained modulus of elasticity measurement were derived; in practical conditions, a uniaxial deformation state can be used with the combination of the total settlement.
Enhancing Thermal and Mechanical Properties of Ramie Fiber via Impregnation by Lignin-Based Polyurethane Resin
Authors: Handika Sucia Okta , Lubis Muhammad Adly Rahandi , Sari Rita Kartika , Laksana Raden Permana Budi , Antov Petar , Savov Viktor , Gajtanska Milada , Iswanto Apri Heri
Published: November 2021

In this study, lignin isolated and fractionated from black liquor was used as a pre-polymer to prepare bio-polyurethane (Bio-PU) resin, and the resin was impregnated into ramie fiber (Boehmeria nivea (L.) Gaudich) to improve its thermal and mechanical properties. The isolated lignin was fractionated by one-step fractionation using two different solvents, i.e., methanol (MeOH) and acetone (Ac). Each fractionated lignin was dissolved in NaOH and then reacted with a polymeric 4,4-methane diphenyl diisocyanate (pMDI) polymer at an NCO/OH mole ratio of 0.3. The resulting Bio-PU was then used in the impregnation of ramie fiber. The characterization of lignin, Bio-PU, and ramie fiber was carried out using several techniques, i.e., Fourier-transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), pyrolysis-gas-chromatography-mass-spectroscopy (Py-GCMS), Micro Confocal Raman spectroscopy, and an evaluation of fiber mechanical properties (modulus of elasticity and tensile strength). Impregnation of Bio-PU into ramie fiber resulted in weight gain ranging from 6% to 15%, and the values increased when extending the impregnation time. The reaction between the NCO group on Bio-PU and the OH group on ramie fiber forms a C=O group of urethane as confirmed by FTIR and Micro Confocal Raman spectroscopies at a wavenumber of 1600 cm−1. Based on the TGA analysis, ramie fiber with lignin-based Bio-PU had better thermal properties than ramie fiber before impregnation with a greater weight residue of 21.7%. The mechanical properties of ramie fiber also increased after impregnation with lignin-based Bio-PU, resulting in a modulus of elasticity of 31 GPa for ramie-L-isolated and a tensile strength of 577 MPa for ramie-L-Ac. The enhanced thermal and mechanical properties of impregnated ramie fiber with lignin-based Bio-PU resins could increase the added value of ramie fiber and enhance its more comprehensive industrial application as a functional material.
Ni-Mn-Sn-Cu Alloys after Thermal Cycling: Thermal and Magnetic Response
Authors: Wederni Asma , Ipatov Mihail , González Julián-María , Khitouni Mohamed , Suñol Joan-Josep
Published: November 2021

Heusler Ni-Mn-Sn-based alloys are good candidates for magnetic refrigeration. This application is based on cycling processes. In this work, thermal cycles (100) have been performed in three ribbons produced by melt-spinning to check the thermal stability and the magnetic response. After cycling, the temperatures were slowly shifted and the thermodynamic properties were reduced, the entropy changed at about 3–5%. Likewise, the thermomagnetic response remains similar. Thus, these candidates maintain enough thermal stability and magnetic response after cycling. Likewise, Cu addition shifts the structural transformation to higher temperatures, whereas the Curie temperature is always near 310 K. Regarding magnetic shape memory applications, the best candidate is the Ni49Mn36 Sn14Cu1 alloy.
Durability Investigation of Carbon Fiber Reinforced Concrete under Salt-Freeze Coupling Effect
Authors: Ji Yongcheng , Liu Wenchao , Jia Yanmin , Li Wei
Published: November 2021

In order to study the durability behavior of CFRP (carbon fiber reinforced polymer) reinforced concrete, three category specimens (plain, partially reinforced, and fully reinforced) were selected to investigate its performance variation concerning chlorine salt and salt-freeze coupled environment, which included the microscopic examination, the distribution of chloride ion concentration, and the compressive properties. By observing the microscopic of the specimens, the surface and cross-section corrosion deterioration was examined with increasing exposure time, and the physical behavior of CFRP and core concrete were discussed. The chloride ion diffusion test exerted that the chloride ion concentration in plain specimens is at least 200 times higher than that of fully reinforced specimens. Therefore, the effectiveness of CFRP reinforcement will be proved to effectively hinder the penetration of chloride ions into the core section. The formula of the time-dependent effect of concrete diffusivity with salt-freeze coupling effect was presented and its accuracy verified. A time-varying finite element model of chloride ion distribution was established by using ABAQUS software. It can be seen from the axial compression test that the strength loss rate of three categories of specimens was varied when subjected to the corrosion environment. Therefore, it is proved that CFRP reinforcement can effectively reduce the deterioration of the specimen’s mechanical properties caused by the exposure environment. The research results can provide technical reference for applying the CFRP strengthened concrete in a severe salt-freeze environment.
The ZnO-In2O3 Oxide System as a Material for Low-Temperature Deposition of Transparent Electrodes
Authors: Akhmedov Akhmed , Abduev Aslan , Murliev Eldar , Asvarov Abil , Muslimov Arsen , Kanevsky Vladimir
Published: November 2021

The development of optoelectronic devices based on flexible organic substrates substantially decreases the possible process temperatures during all stages of device manufacturing. This makes it urgent to search for new transparent conducting oxide (TCO) materials, cheaper than traditional indium-tin oxide (ITO), for the low-temperature deposition of transparent electrodes, a necessary component of most optoelectronic devices. The article presents the results of a vertically integrated study aimed at the low-temperature production of TCO thin films based on a zinc-indium oxide (ZIO) system with acceptable functional characteristics. First, dense and conducting ceramic targets based on the (100-x) mol% (ZnO) + x mol% (In2O3) system (x = 0.5, 1.5, 2.5, 5.0, and 10.0) were synthesized by the spark plasma sintering method. The dependences of the microstructure and phase composition of the ZIO ceramic targets on the In2O3 content have been studied by powder X-ray diffraction, scanning electron microscopy and energy dispersive X-ray spectroscopy methods. Then, a set of ZIO thin films with different Zn/In ratios were obtained on unheated glass substrates by direct current (dc) magnetron sputtering of the sintered targets. Complex studies of microstructure, electrical and optical properties of the deposited films have revealed the presence of an optimal doping level (5 mol% In2O3) of the ZIO target at which the deposited TCO films, in terms of the combination of their electrical and optical properties, become comparable to the widely used expensive ITO.
Discoloration Potential of Biodentine: A Systematic Review
Authors: Slaboseviciute Monika , Vasiliauskaite Neringa , Drukteinis Saulius , Martens Luc , Rajasekharan Sivaprakash
Published: November 2021

The aim of this systematic review is to investigate the teeth discoloration potential of Biodentine. An electronic search in six databases (PubMed, Cochrane Library, LILACS, SCIELO, Web of Science, and Scopus) was conducted by three independent reviewers to identify eligible articles. The following search terms were used: ((discolo*, staining potential, color, colour, or spectrophotomet*), (teeth or tooth), and (Biodentine)). Methodology following the PRISMA (Preferred Reporting Items for Systematic Reviews and Meta-Analysis) guidelines was adopted for this investigation. At the end of the selection process, 30 articles were identified as eligible, of which 14 in vitro studies were included in this systematic review. Nine of the included studies evaluated the discoloration potential of Biodentine in the presence of blood. Within the limitations of this review, teeth discoloration using Biodentine is highly expected when material is placed in direct contact with blood during dental procedures. In the absence of blood, Biodentine causes less teeth color changes than MTA-based materials, but it is still unclear what clinically relevant results could be expected regarding the discoloration frequency and intensity induced by Biodentine.
Determination of Mechanical and Fracture Properties of Silicon Single Crystal from Indentation Experiments and Finite Element Modelling
Authors: Skalka Petr , Kotoul Michal
Published: November 2021

It is well-known that cracks are observed around the impression during indentation of brittle materials. The cracks inception depends on load conditions, material and indenter geometry. The paper aims to use experimental micro-indentation data, FE simulations with cohesive zone modelling, and an optimisation procedure to determine the cohesive energy density of silicon single crystals. While previous studies available in the literature, which use cohesive zone finite element techniques for simulation of indentation cracks in brittle solids, tried to improve methods for the evaluation of material toughness from the indentation load, crack size, hardness, elastic constants, and indenter geometry, this study focuses on the evaluation of the cohesive energy density 2Γ from which the material toughness can be easily determined using the well-known Griffith-Irwin formula. There is no need to control the premise of the linear fracture mechanics that the cohesive zone is much shorter than the crack length. Hence, the developed approach is suitable also for short cracks for which the linear fracture mechanics premise is violated.
Colloidal Shear-Thickening Fluids Using Variable Functional Star-Shaped Particles: A Molecular Dynamics Study
Authors: Salehin Rofiques , Xu Rong-Guang , Papanikolaou Stefanos
Published: November 2021

Complex colloidal fluids, depending on constituent shapes and packing fractions, may have a wide range of shear-thinning and/or shear-thickening behaviors. An interesting way to transition between different types of such behavior is by infusing complex functional particles that can be manufactured using modern techniques such as 3D printing. In this paper, we perform 2D molecular dynamics simulations of such fluids with infused star-shaped functional particles, with a variable leg length and number of legs, as they are infused in a non-interacting fluid. We vary the packing fraction (ϕ) of the system, and for each different system, we apply shear at various strain rates, turning the fluid into a shear-thickened fluid and then, in jammed state, rising the apparent viscosity of the fluid and incipient stresses. We demonstrate the dependence of viscosity on the functional particles’ packing fraction and we show the role of shape and design dependence of the functional particles towards the transition to a shear-thickening fluid.
Scattering of Magnetoacoustic Waves and Dynamic Stress Concentration around Double Openings in Piezomagnetic Composites
Authors: Xue Huanhuan , Zhou Chuanping , Cheng Gaofei , Bao Junqi , Wang Maofa , Gong Yongping , Ji Huawei , Yang Wu , Hou Bo , Zhou Weihua , Wang Qiaoyi , Ni Jing
Published: November 2021

Based on the magnetoacoustic coupled dynamics theory, the wave function expansion method is used to solve the problem of acoustic wave scattering and dynamic stress concentration around the two openings in e-type piezomagnetic composites. To deal with the multiple scattering between openings, the local coordinate method is introduced. The general analytical solution to the problem and the expression of the dynamic stress concentration are derived. As an example, the numerical results of the dynamic stress distribution around two openings with equal diameters are given. The effects of the parameters, such as the incident wave number and the spacing between the openings, on the dynamic stress concentration factor are analyzed.
Development and Experimental Validation of Real Fluid Models for CFD Calculation of ORC and Steam Turbine Flows
Authors: Rusanov Andrii , Rusanov Roman , Klonowicz Piotr , Lampart Piotr , Żywica Grzegorz , Borsukiewicz Aleksandra
Published: November 2021

The article describes an interpolation–analytical method of reconstruction of the IAPWS-95 equations of state and the modified Benedict–Webb–Rubin equations of state with 32 terms (mBWR32). The method enables us to provide the thermodynamic closure in 3D computational fluid dynamics (CFD) calculations of turbomachinery flows with real working media, such as steam and Organic Rankine Cycle (ORC) fluids. The described approach allows for the sufficient accuracy of 3D flow calculations and does not require a significant increase in computational cost over perfect gas calculations. The method is validated against experimental data from measurements and compared with computational results from the model using the Tammann equation of state. Three turbine blading systems are considered—a multi-stage configuration from a low-pressure cylinder of a large-power steam turbine and two ORC microturbines working with organic media HFE7100 and R227ea. The calculation results obtained using the described method of approximation of the IAPWS-95 and mBWR32 equations exhibit satisfactory agreement with the experimental data, considering pressures, temperatures and enthalpies in key sections, as well as turbine power and efficiency in a wide range of changing thermodynamic parameters. In contrast, the Tammann equation of state provides acceptable results only for relatively small changes of thermodynamic parameters.
A Numerical Study on 3D Printed Cementitious Composites Mixes Subjected to Axial Compression
Authors: Liu Hanqiu , Egbe King-James Idala , Wang Haipeng , Matin Nazar Ali , Jiao Pengcheng , Zhu Ronghua
Published: November 2021

Aptly enabled by recent developments in additive manufacturing technology, the concept of functionally grading some cementitious composites to improve structural compression forms is warranted. In this work, existing concrete models available in Abaqus Finite Element (FE) packages are utilized to simulate the performance of some cementitious composites numerically and apply them to functional grading using the multi-layer approach. If yielding good agreement with the experimental results, two-layer and three-layer models case combinations are developed to study the role of layer position and volume. The optimal and sub-optimal performance of the multi-layer concrete configurations based on compressive strength and sustained strains are assessed. The results of the models suggest that layer volume and position influence the performance of multi-layer concrete. It is observed that when there exists a substantial difference in material strengths between the concrete mixes that make up the various layers of a functionally graded structure, the influence of position and of material volume are significant in a two-layer configuration. In contrast, in a three-layer configuration, layer position is of minimal effect, and volume has a significant effect only if two of the three layers are made from the same material. Thus, a multilayered design approach to compression structures can significantly improve strength and strain performance. Finally, application scenarios on some structural compression forms are shown, and their future trajectory is discussed.
Electrochemical Study of Clean and Pre-Corroded Reinforcements Embedded in Mortar Samples with Variable Amounts of Chloride Ions
Authors: González María de las Nieves , Prieto María Isabel , Cobo Alfonso , Olmedo Fernando Israel
Published: November 2021

The present study investigates the possibility of re-surfacing previously corroded reinforcements and the suitability of the two electrochemical techniques that are widely used to determine the state of corrosion of steel (the corrosion potential Ecorr and the corrosion rate icorr). In order to test this, 32 pre-corroded B500SD reinforcing steel bars have been used for one year, where half of the bars have been cleaned to eliminate corrosion products. The other half have been maintained with the generated corrosion products. Subsequently, the bars have been embedded in cement mortar samples with variable amounts of chloride ion, and Ecorr and icorr have been measured for 250 days. The results showed that it is not possible to rework the reinforcement without removing corrosion products and that it is not possible to predict the passive or active state of steel by measuring Ecorr only.
Experimental Study of HFE 7000 Refrigerant Condensation in Horizontal Pipe Minichannels
Authors: Sikora Małgorzata , Bohdal Tadeusz , Formela Karolina
Published: November 2021

This article presents the results obtained from our own experimental investigations on heat exchange and pressure drop during the condensation flow of the HFE 7000 refrigerant in pipe minichannels with an internal diameter of di = 1.2–2.5 mm. The influence of vapor quality x and the mass flux density G on the two-phase flow pressure drops and heat transfer is presented. The tests were performed for the mass flux density range of G = 110–4700 kg/m2s, saturation inlet temperature of Ts = 36–43 °C and heat flux density of q = 1 ÷ 20 kW/m2. The pressure drop characteristics and heat transfer coefficient as a function of the internal diameter of minichannels are illustrated. The results of experimental research on the heat transfer coefficient and two-phase pressure drop are compared with correlations developed by other authors. The best accuracy has a comparison of experimental study with correlation of Rahman-Kariya-Miyara et al. and Mikielewicz et al.
Adsorption and Oxidation of CO on Ceria Nanoparticles Exposing Single-Atom Pd and Ag: A DFT Modelling
Authors: Nasluzov Vladimir A. , Ivanova-Shor Elena A. , Shor Aleksey M. , Laletina Svetlana S. , Neyman Konstantin M.
Published: November 2021

Various COx species formed upon the adsorption and oxidation of CO on palladium and silver single atoms supported on a model ceria nanoparticle (NP) have been studied using density functional calculations. For both metals M, the ceria-supported MCOx moieties are found to be stabilised in the order MCO < MCO2 < MCO3, similar to the trend for COx species adsorbed on M-free ceria NP. Nevertheless, the characteristics of the palladium and silver intermediates are different. Very weak CO adsorption and the small exothermicity of the CO to CO2 transformation are found for O4Pd site of the Pd/Ce21O42 model featuring a square-planar coordination of the Pd2+ cation. The removal of one O atom and formation of the O3Pd site resulted in a notable strengthening of CO adsorption and increased the exothermicity of the CO to CO2 reaction. For the analogous ceria models with atomic Ag instead of atomic Pd, these two energies became twice as small in magnitude and basically independent of the presence of an O vacancy near the Ag atom. CO2-species are strongly bound in palladium carboxylate complexes, whereas the CO2 molecule easily desorbs from oxide-supported AgCO2 moieties. Opposite to metal-free ceria particle, the formation of neither PdCO3 nor AgCO3 carbonate intermediates before CO2 desorption is predicted. Overall, CO oxidation is concluded to be more favourable at Ag centres atomically dispersed on ceria nanostructures than at the corresponding Pd centres. Calculated vibrational fingerprints of surface COx moieties allow us to distinguish between CO adsorption on bare ceria NP (blue frequency shifts) and ceria-supported metal atoms (red frequency shifts). However, discrimination between the CO2 and CO32− species anchored to M-containing and bare ceria particles based solely on vibrational spectroscopy seems problematic. This computational modelling study provides guidance for the knowledge-driven design of more efficient ceria-based single-atom catalysts for the environmentally important CO oxidation reaction.
Antiparasitic Effects of Sulfated Polysaccharides from Marine Hydrobionts
Authors: Besednova Natalya N. , Zaporozhets Tatyana S. , Andryukov Boris G. , Kryzhanovsky Sergey P. , Ermakova Svetlana P. , Kuznetsova Tatyana A. , Voronova Anastasia N. , Shchelkanov Mikhail Y.
Published: November 2021

This review presents materials characterizing sulfated polysaccharides (SPS) of marine hydrobionts (algae and invertebrates) as potential means for the prevention and treatment of protozoa and helminthiasis. The authors have summarized the literature on the pathogenetic targets of protozoa on the host cells and on the antiparasitic potential of polysaccharides from red, brown and green algae as well as certain marine invertebrates. Information about the mechanisms of action of these unique compounds in diseases caused by protozoa has also been summarized. SPS is distinguished by high antiparasitic activity, good solubility and an almost complete absence of toxicity. In the long term, this allows for the consideration of these compounds as effective and attractive candidates on which to base drugs, biologically active food additives and functional food products with antiparasitic activity.
From Natural Xanthones to Synthetic C-1 Aminated 3,4-Dioxygenated Xanthones as Optimized Antifouling Agents
Authors: Resende Diana I. S. P. , Almeida Joana R. , Pereira Sandra , Campos Alexandre , Lemos Agostinho , Plowman Jeffrey E. , Thomas Ancy , Clerens Stefan , Vasconcelos Vitor , Pinto Madalena , Correia-da-Silva Marta , Sousa Emília
Published: November 2021

Biofouling, which occurs when certain marine species attach and accumulate in artificial submerged structures, represents a serious economic and environmental issue worldwide. The discovery of new non-toxic and eco-friendly antifouling systems to control or prevent biofouling is, therefore, a practical and urgent need. In this work, the antifouling activity of a series of 24 xanthones, with chemical similarities to natural products, was exploited. Nine (1, 2, 4, 6, 8, 16, 19, 21, and 23) of the tested xanthones presented highly significant anti-settlement responses at 50 μM against the settlement of mussel Mytilus galloprovincialis larvae and low toxicity to this macrofouling species. Xanthones 21 and 23 emerged as the most effective larval settlement inhibitors (EC50 = 7.28 and 3.57 µM, respectively). Additionally, xanthone 23 exhibited a therapeutic ratio (LC50/EC50) > 15, as required by the US Navy program attesting its suitability as natural antifouling agents. From the nine tested xanthones, none of the compounds were found to significantly inhibit the growth of the marine biofilm-forming bacterial strains tested. Xanthones 4, 6, 8, 16, 19, 21, and 23 were found to be non-toxic to the marine non-target species Artemia salina (<10% mortality at 50 μM). Insights on the antifouling mode of action of the hit xanthones 21 and 23 suggest that these two compounds affected similar molecular targets and cellular processes in mussel larvae, including that related to mussel adhesion capacity. This work exposes for the first time the relevance of C-1 aminated xanthones with a 3,4-dioxygenated pattern of substitution as new non-toxic products to prevent marine biofouling.
Wound Healing and Therapy in Soft Tissue Defects of the Hand and Foot from a Surgical Point of View
Authors: Demmer Wolfram , Sorg Heiko , Steiert Andreas , Hauser Jörg , Tilkorn Daniel Johannes
Published: November 2021

Wounds and tissue defects of the hand and foot often lead to severe functional impairment of the affected extremity. Next to general principles of wound healing, special functional and anatomic considerations must be taken into account in the treatment of wounds in these anatomical regions to achieve a satisfactory reconstructive result. In this article, we outline the concept of wound healing and focus on the special aspects to be considered in wounds of the hand and foot. An overview of different treatment and dressing techniques is given with special emphasis on the reconstruction of damaged structures by plastic surgical means.
Rational Design and Porosity of Porous Alumina Ceramic Membrane for Air Bearing
Authors: Du Jianzhou , Ai Duomei , Xiao Xin , Song Jiming , Li Yunping , Chen Yuansheng , Wang Luming , Zhu Kongjun
Published: November 2021

Air bearing has been widely applied in ultra-precision machine tools, aerospace and other fields. The restrictor of the porous material is the key component in air bearings, but its performance is limited by the machining accuracy. A combination of optimization design and material modification of the porous alumina ceramic membrane is proposed to improve performance within an air bearing. Porous alumina ceramics were prepared by adding a pore-forming agent and performing solid-phase sintering at 1600 °C for 3 h, using 95-Al2O3 as raw material and polystyrene microspheres with different particle sizes as the pore-forming agent. With 20 wt.% of PS50, the optimum porous alumina ceramic membranes achieved a density of 3.2 g/cm3, a porosity of 11.8% and a bending strength of 150.4 MPa. Then, the sintered samples were processed into restrictors with a diameter of 40 mm and a thickness of 5 mm. After the restrictors were bonded to aluminum shells for the air bearing, both experimental and simulation work was carried out to verify the designed air bearing. Simulation results showed that the load capacity increased from 94 N to 523 N when the porosity increased from 5% to 25% at a fixed gas supply pressure of 0.5 MPa and a fixed gas film thickness of 25 μm. When the gas film thickness and porosity were fixed at 100 μm and 11.8%, respectively, the load capacity increased from 8.6 N to 40.8 N with the gas supply pressure having been increased from 0.1 MPa to 0.5 MPa. Both experimental and simulation results successfully demonstrated the stability and effectiveness of the proposed method. The porosity is an important factor for improving the performance of an air bearing, and it can be optimized to enhance the bearing’s stability and load capacity.
Mathematical Modeling of the Phenomenon of Space-Charge Breakdown in the Galvanostatic Mode in the Section of the Electromembrane Desalination Channel
Authors: Uzdenova Aminat , Urtenov Makhamet
Published: November 2021

One of the ways to increase the efficiency of the desalination process in membrane systems is to use intensive current modes. Recently, the phenomenon of space-charge breakdown was theoretically described for desalination under intensive current modes. The space-charge breakdown is a decrease in the magnitude and size of the extended space charge regions (SCRs) of opposite signs, formed at the cation- and anion-exchange membranes in the desalination channel, when they approach each other. Therefore, this phenomenon negatively affects the intensity of electroconvection and the efficiency of mass transfer in membrane systems. We report the results of the first theoretical analysis of the space-charge breakdown in the galvanostatic electric mode, which is generally used in the research and operation of membrane systems. For this purpose, a one-dimensional model of the ion transfer of the electrolyte solution in the section of the desalination channel at the direct current is developed. The regularities of changes in the extended SCRs in the galvanostatic mode are determined. A relation is obtained for the onset time of the space-charge breakdown, which makes it possible to determine the parameters of the effective operation of the membrane system.
Effect of Different Influent Conditions on Biomass Production and Nutrient Removal by Aeration Microalgae Membrane Bioreactor (ICFB-MMBR) System for Mariculture Wastewater Treatment
Authors: Ding Yi , Wang Shiyuan , Ma Hang , Ma Binyu , Guo Zhansheng , You Hong , Mei Junxue , Hou Xuguang , Liang Zhenlin , Li Zhipeng
Published: November 2021

The nutrient removal and biomass production of the internal circulating fluidized bed microalgae membrane bioreactor (ICFB-MMBR) was studied under different cultivation modes, influent TOC, influent pH, and influent N/P. Platymonas helgolandica tsingtaoensis was used as the biological source. The growth of P. helgolandica tsingtaoensis and the removal efficiency of pollutants in the mixotrophy culture mode were improved compared with other culture modes. With the increased influent TOC, the average growth rate of P. helgolandica tsingtaoensis increased, and ammonia nitrogen and total phosphorus removal rate were improved. The P. helgolandica tsingtaoensis growth rate and nutrient removal efficiencies at the influent pH of 8 were the best among the different influent pH values. As the influent N/P ratio increased from 5 to 20, the P. helgolandica tsingtaoensis growth rate and pollutant removal rate increased gradually. When the influent N/P ratio was higher than 20, the P. helgolandica tsingtaoensis growth rate and pollutant removal rate tended to be stable and did not significantly change with the increase of influent N/P ratio. At the proper influent conditions, the high P. helgolandica tsingtaoensis biomass and nutrient removal efficiency could be obtained in the microalgae membrane bioreactor, which could provide a theoretical basis for the application of the system for wastewater treatment.
Preparation, Performance and Challenges of Catalyst Layer for Proton Exchange Membrane Fuel Cell
Authors: Xie Meng , Chu Tiankuo , Wang Tiantian , Wan Kechuang , Yang Daijun , Li Bing , Ming Pingwen , Zhang Cunman
Published: November 2021

In this paper, the composition, function and structure of the catalyst layer (CL) of a proton exchange membrane fuel cell (PEMFC) are summarized. The hydrogen reduction reaction (HOR) and oxygen reduction reaction (ORR) processes and their mechanisms and the main interfaces of CL (PEM|CL and CL|MPL) are described briefly. The process of mass transfer (hydrogen, oxygen and water), proton and electron transfer in MEA are described in detail, including their influencing factors. The failure mechanism of CL (Pt particles, CL crack, CL flooding, etc.) and the degradation mechanism of the main components in CL are studied. On the basis of the existing problems, a structure optimization strategy for a high-performance CL is proposed. The commonly used preparation processes of CL are introduced. Based on the classical drying theory, the drying process of a wet CL is explained. Finally, the research direction and future challenges of CL are pointed out, hoping to provide a new perspective for the design and selection of CL materials and preparation equipment.
Technology Innovation for the Manual Laser Cladding of High-Alloy Tool Steels
Authors: Kimme Jonas , Zeisig Josephine , Fröhlich Alexander , Kräusel Verena
Published: November 2021

This paper presents the development and successful application of an inductive preheating system running simultaneously with the manual laser cladding process in order to enable the repair of high-alloy tool steels having a highly limited weldability. In this study, the design and optimization of a suitable inductor as well as the analysis of the welding process were carried out by means of FE-simulation in order to generate material deposition without imperfections. Parameter variation studies were conducted while parallel modifying the generator power resulting in different preheating temperatures. These examinations showed that by using appropriate process parameters and an inductive preheating temperature of 200 °C, crack- and pore-free deposition layers could be produced on the commercial high-alloyed PM steel Elmax. This result can be explained by FE-simulation demonstrating that the cooling rate was halved in the weld and in the heat-affected zone. In conclusion, this study shows the high potential of the developed technical innovation for the manual laser cladding of high-performance tools.
Microstructure and Texture Evolution during Severe Plastic Deformation at Cryogenic Temperatures in an Al-0.1Mg Alloy
Authors: Huang Yan , Jiang Jun
Published: November 2021

The deformation structures formed in an Al-0.1Mg single-phase aluminium alloy have been studied during plane strain compression (PSC) down to liquid nitrogen temperature, following prior equal channel angular extrusion (ECAE) to a strain of ten. Under constant deformation conditions a steady state was approached irrespective of the temperature, where the rate of grain refinement stagnated and a minimum grain size was reached which could not be further reduced. A 98% reduction at 77 K (−196 °C) only transformed the ECAE processed submicron grain structure into a microstructure with thin ribbon grains, where a nanoscale high angle boundary (HAB) spacing was only approached in the sheet normal direction. It is shown that the minimum grain size achievable in severe deformation processing is controlled by a balance between the rate of compression of the HAB structure and dynamic recovery. The required boundary migration rate to maintain a constant boundary spacing is found far higher than can be justified from conventional diffusion-controlled grain growth and at low temperatures, a constant boundary spacing can only be maintained by invoking an athermal mechanism and is considered to be dominated by the operation of grain boundary dislocations.
Modelling the Effect of Solution Composition and Temperature on the Conductivity of Zinc Electrowinning Electrolytes
Authors: Wang Zulin , Aji Arif Tirto , Wilson Benjamin Paul , Jørstad Steinar , Møll Maria , Lundström Mari
Published: November 2021

Zinc electrowinning is an energy-intensive step of hydrometallurgical zinc production in which ohmic drop contributes the second highest overpotential in the process. As the ohmic drop is a result of electrolyte conductivity, three conductivity models (Aalto-I, Aalto-II and Aalto-III) were formulated in this study based on the synthetic industrial electrolyte conditions of Zn (50–70 g/dm3), H2SO4 (150–200 g/dm3), Mn (0–8 g/dm3), Mg (0–4 g/dm3), and temperature, T (30–40 °C). These studies indicate that electrolyte conductivity increases with temperature and H2SO4 concentration, whereas metal ions have negative effects on conductivity. In addition, the interaction effects of temperature and the concentrations of metal ions on solution conductivity were tested by comparing the performance of the linear model (Aalto-I) and interrelated models (Aalto-II and Aalto-III) to determine their significance in the electrowinning process. Statistical analysis shows that Aalto-I has the highest accuracy of all the models developed and investigated in this study. From the industrial validation, Aalto-I also demonstrates a high level of correlation in comparison to the other models presented in this study. Further comparison of model Aalto-I with the existing published models from previous studies shows that model Aalto-I substantially improves the accuracy of the zinc conductivity empirical model.
Effect of Grain Refinement on the Dynamic, Mechanical Properties, and Corrosion Behaviour of Al-Mg Alloy
Authors: Ahmed Haitham M. , Ahmed Hussin A. M. , Hefni Mohammed , Moustafa Essam B.
Published: November 2021

In this investigation, aluminium Al-2.5% Mg cast alloy was modified by adding 0.5 Ti and 0.1 B wt % modifiers to investigate their impact on the dynamic behaviour, as well as the mechanical and microstructure properties. The dynamic properties were analysed experimentally using a free vibration impact test and predicted using finite element methods. This study used a high-resolution polarised optical microscope to analyse the microstructure of the studied alloys and X-ray Powder Diffraction (XRD) analysis to determine the developed phases. Microstructure and mechanical properties were mostly enhanced as a result of grain refining during solidification and through the metal segregation process. The microstructure analysis of the modified alloy showed a significant improvement in the grain refinement; hence, the grains were 10 times finer than the cast alloy. The modified Al-2.5% Mg/Ti-B alloy demonstrated reduced inter-granular corrosion (IGC) than the Al-2.5% Mg standard cast alloy. By incorporating Ti-B modifiers into the composition of the cast Al-Mg alloy, the ultimate tensile strength (UTS), strain (ε), and hardness values (HV) were increased by 30.5%, 100%, and 18.18%, respectively. The dynamic properties of the modified alloy showed an enhancement in the resonant (fn) and damping ratio (ζ) by 7% and 68%, respectively. The predicted resonance frequencies of the investigated alloys showed results close to the experimental dynamic tests.
2C-B-Fly-NBOMe Metabolites in Rat Urine, Human Liver Microsomes and C. elegans: Confirmation with Synthesized Analytical Standards
Authors: Nykodemová Jitka , Šuláková Anna , Palivec Petr , Češková Hedvika , Rimpelová Silvie , Šíchová Klára , Leonhardt Tereza , Jurásek Bronislav , Hájková Kateřina , Páleníček Tomáš , Kuchař Martin
Published: November 2021

Compounds from the N-benzylphenethylamine (NBPEA) class of novel psychoactive substances are being increasingly utilized in neurobiological and clinical research, as diagnostic tools, or for recreational purposes. To understand the pharmacology, safety, or potential toxicity of these substances, elucidating their metabolic fate is therefore of the utmost interest. Several studies on NBPEA metabolism have emerged, but scarce information about substances with a tetrahydrobenzodifuran (“Fly”) moiety is available. Here, we investigated the metabolism of 2-(8-bromo-2,3,6,7-tetrahydrobenzo[1,2-b:4,5-b’]difuran-4-yl)-N-(2-methoxybenzyl)ethan-1-amine (2C-B-Fly-NBOMe) in three different systems: isolated human liver microsomes, Cunninghamella elegans mycelium, and in rats in vivo. Phase I and II metabolites of 2C-B-Fly-NBOMe were first detected in an untargeted screening and identified by liquid chromatography–tandem mass spectrometry (LC–MS/MS). Several hypothesized metabolites were then synthesized as reference standards; knowledge of their fragmentation patterns was utilized for confirmation or tentative identification of isomers. Altogether, thirty-five phase I and nine phase II 2C-B-Fly-NBOMe metabolites were detected. Major detected metabolic pathways were mono- and poly-hydroxylation, O-demethylation, oxidative debromination, and to a lesser extent also N-demethoxybenzylation, followed by glucuronidation and/or N-acetylation. Differences were observed for the three used media. The highest number of metabolites and at highest concentration were found in human liver microsomes. In vivo metabolites detected from rat urine included two poly-hydroxylated metabolites found only in this media. Mycelium matrix contained several dehydrogenated, N-oxygenated, and dibrominated metabolites.
Hematological, Micro-Rheological, and Metabolic Changes Modulated by Local Ischemic Pre- and Post-Conditioning in Rat Limb Ischemia-Reperfusion
Authors: Korei Csaba , Szabo Balazs , Varga Adam , Barath Barbara , Deak Adam , Vanyolos Erzsebet , Hargitai Zoltan , Kovacs Ilona , Nemeth Norbert , Peto Katalin
Published: November 2021

In trauma and orthopedic surgery, limb ischemia-reperfusion (I/R) remains a great challenge. The effect of preventive protocols, including surgical conditioning approaches, is still controversial. We aimed to examine the effects of local ischemic pre-conditioning (PreC) and post-conditioning (PostC) on limb I/R. Anesthetized rats were randomized into sham-operated (control), I/R (120-min limb ischemia with tourniquet), PreC, or PostC groups (3 × 10-min tourniquet ischemia, 10-min reperfusion intervals). Blood samples were taken before and just after the ischemia, and on the first postoperative week for testing hematological, micro-rheological (erythrocyte deformability and aggregation), and metabolic parameters. Histological samples were also taken. Erythrocyte count, hemoglobin, and hematocrit values decreased, while after a temporary decrease, platelet count increased in I/R groups. Erythrocyte deformability impairment and aggregation enhancement were seen after ischemia, more obviously in the PreC group, and less in PostC. Blood pH decreased in all I/R groups. The elevation of creatinine and lactate concentration was the largest in PostC group. Histology did not reveal important differences. In conclusion, limb I/R caused micro-rheological impairment with hematological and metabolic changes. Ischemic pre- and post-conditioning had additive changes in various manners. Post-conditioning showed better micro-rheological effects. However, by these parameters it cannot be decided which protocol is better.
The Effects of Consuming White Button Mushroom Agaricus bisporus on the Brain and Liver Metabolome Using a Targeted Metabolomic Analysis
Authors: Solano-Aguilar Gloria I. , Lakshman Sukla , Jang Saebyeol , Gupta Richi , Molokin Aleksey , Schroeder Steven G. , Gillevet Patrick M. , Urban Joseph F.
Published: November 2021

A targeted metabolomic analysis was performed on tissues derived from pigs fed diets supplemented with white button mushrooms (WBM) to determine the effect on the liver and brain metabolome. Thirty-one pigs were fed a grower diet alone or supplemented with either three or six servings of freeze-dried WBM for six weeks. Tissue metabolomes were analyzed using targeted liquid chromatography-mass spectrometry (LC-MS) combined with chemical similarity enrichment analysis (ChemRICH) and correlated to WBM-induced changes in fecal microbiome composition. Results indicated that WBM can differentially modulate metabolites in liver, brain cortex and hippocampus of healthy pigs. Within the glycero-phospholipids, there was an increase in alkyl-acyl-phosphatidyl-cholines (PC-O 40:3) in the hippocampus of pigs fed six servings of WBM. A broader change in glycerophospholipids and sphingolipids was detected in the liver with a reduction in several lipid species in pigs fed both WBM diets but with an increase in amino acids known as precursors of neurotransmitters in the cortex of pigs fed six servings of WBM. Metabolomic changes were positively correlated with increased abundance of Cryomorphaceae, Lachnospiraceae, Flammeovirgaceae and Ruminococcaceae in the microbiome suggesting that WBM can also positively impact tissue metabolite composition.
A New Data-Driven Control System for MEMSs Gyroscopes: Dynamics Estimation by Type-3 Fuzzy Systems
Authors: Alattas Khalid A. , Mohammadzadeh Ardashir , Mobayen Saleh , Aly Ayman A. , Felemban Bassem F. , Vu Mai The
Published: November 2021

In this study, a novel data-driven control scheme is presented for MEMS gyroscopes (MEMS-Gs). The uncertainties are tackled by suggested type-3 fuzzy system with non-singleton fuzzification (NT3FS). Besides the dynamics uncertainties, the suggested NT3FS can also handle the input measurement errors. The rules of NT3FS are online tuned to better compensate the disturbances. By the input-output data set a data-driven scheme is designed, and a new LMI set is presented to ensure the stability. By several simulations and comparisons the superiority of the introduced control scheme is demonstrated.