bluuebunny/crossref_metadata_2025 huggingface dataset:
Surface Enhanced CdSe/ZnS QD/SiNP Electrochemical Immunosensor for the Detection of Mycobacterium Tuberculosis by Combination of CFP10-ESAT6 for Better Diagnostic Specificity
Authors: Mohd Bakhori Noremylia , Yusof Nor Azah , Abdullah Jaafar , Wasoh Helmi , Ab Rahman Siti Khadijah , Abd Rahman Siti Fatimah
Published: January 2020

In this study, an electrochemical immunosensor was introduced for the detection of tuberculosis (TB) via utilization of a modified electrode containing a quantum dot (CdSe/ZnS QD) and functionalized silica nanoparticles (SiNPs) on screen-printed carbon electrode (SPCE) CdSe/ZnS QD/SiNPs/SPCE, by employing indirect enzyme-linked immunosorbent assay (ELISA). Here, the fabricated electrode was linked to the biocatalytic action of enzyme catalase through antigen–antibody binding for the detection of the antigen (CFP10–ESAT6) by means of producing a differential pulse voltammetry (DPV) current. The characterization and cyclic voltammetry (CV) of the modified electrode showed good electrochemical behavior and enhanced high electron transfer between the electrode and analyte. Moreover, the active surface area was 4.14-fold higher than the bare SPCE. The developed method showed high selectivity towards CFP10–ESAT6 compared with the other TB proteins. The detection of CFP10–ESAT6 also showed a linear response towards different concentrations of CFP10–ESAT6 with R2 = 0.9937, yielding a limit of detection (LOD) of as low as 1.5 × 10−10 g/mL for a linear range of 40 to 100 ng/mL of CFP10–ESAT6 concentration. The proposed method showed good reproducibility of target analyte with a relative standard deviation of 1.45%.
Compressive Behavior Characteristics of High-Performance Slurry-Infiltrated Fiber-Reinforced Cementitious Composites (SIFRCCs) under Uniaxial Compressive Stress
Authors: Kim Seungwon , Han Seungyeon , Park Cheolwoo , Yun Kyong-Ku
Published: January 2020

The compressive stress of concrete is used as a design variable for reinforced concrete structures in design standards. However, as the performance-based design is being used with increasing varieties and strengths of concrete and reinforcement bars, mechanical properties other than the compressive stress of concrete are sometimes used as major design variables. In particular, the evaluation of the mechanical properties of concrete is crucial when using fiber-reinforced concrete. Studies of high volume fractions in established compressive behavior prediction equations are insufficient compared to studies of conventional fiber-reinforced concrete. Furthermore, existing prediction equations for the mechanical properties of high-performance fiber-reinforced cementitious composite and high-strength concrete have limitations in terms of the strength and characteristics of contained fibers (diameter, length, volume fraction) even though the stress-strain relationship is determined by these factors. Therefore, this study developed a high-performance slurry-infiltrated fiber-reinforced cementitious composite that could prevent the fiber ball phenomenon, a disadvantage of conventional fiber-reinforced concrete, and maximize the fiber volume fraction. Then, the behavior characteristics under compressive stress were analyzed for fiber volume fractions of 4%, 5%, and 6%.
Effects of Defects on Bond Behavior of Fiber Reinforced Cementitious Matrix Materials
Authors: Bilotta Antonio , Lignola Gian Piero
Published: January 2020

High-strength fibers embedded in inorganic matrix i.e., Fiber Reinforced Cementitious Mortar materials (FRCM) are commonly used as strengthening technique for existing masonry structures, due to the low sensitivity to debonding phenomena between substrate and matrix. Nevertheless, the use of lime or cement-based matrix instead of epoxy adhesive implies that attention has to be paid to the bond behavior between the fibers and the matrix, since sliding phenomena and cohesive failures in the mortar matrix can occur. The paper aims to investigate the effect of the mechanical properties of fiber and matrix on the FRCM efficiency, and potential geometrical defects, typical of real applications. The aim is to analyze the mechanical behavior of the FRCM system by simulating hypothetical bond tests, as they are usually performed in laboratories. The bond test has a significant role, as it is used for the qualification of the material, providing sometimes very scattered results. Hence, it is particularly important and greatly discussed in the scientific community and among manufactures and practitioners. The purpose is to understand where this variability could derive from and possibly how to contain it, to improve the characterization of FRCM systems. A mechanical model has been proposed to simulate the usual bond test to focus and stress the way in which each fiber slips out of the matrix as the load increases; and this has been recognized as the main reason for scattered results in bond tests. The model was then applied to the typical cases of PBO-FRCM and Glass-FRCM, hence considering different ratios for the fiber and matrix properties.
Exploratory Full-Field Strain Analysis of Regenerated Bone Tissue from Osteoinductive Biomaterials
Authors: Peña Fernández Marta , Black Cameron , Dawson Jon , Gibbs David , Kanczler Janos , Oreffo Richard O. C. , Tozzi Gianluca
Published: January 2020

Biomaterials for bone regeneration are constantly under development, and their application in critical-sized defects represents a promising alternative to bone grafting techniques. However, the ability of all these materials to produce bone mechanically comparable with the native tissue remains unclear. This study aims to explore the full-field strain evolution in newly formed bone tissue produced in vivo by different osteoinductive strategies, including delivery systems for BMP-2 release. In situ high-resolution X-ray micro-computed tomography (microCT) and digital volume correlation (DVC) were used to qualitatively assess the micromechanics of regenerated bone tissue. Local strain in the tissue was evaluated in relation to the different bone morphometry and mineralization for specimens (n = 2 p/treatment) retrieved at a single time point (10 weeks in vivo). Results indicated a variety of load-transfer ability for the different treatments, highlighting the mechanical adaptation of bone structure in the early stages of bone healing. Although exploratory due to the limited sample size, the findings and analysis reported herein suggest how the combination of microCT and DVC can provide enhanced understanding of the micromechanics of newly formed bone produced in vivo, with the potential to inform further development of novel bone regeneration approaches.
Microstructure Evolution and Mechanical Properties of 0.4C-Si-Mn-Cr Steel during High Temperature Deformation
Authors: Zhang Fei , Yang Yang , Shan Quan , Li Zulai , Bi Jinfeng , Zhou Rong
Published: January 2020

Herein, the effects of height-diameter ratios (H/D) on the microstructure evolution and mechanical properties of 0.4C-Si-Mn-Cr steel during high temperature deformation are reported. The compression experiments were performed on steel samples using Gleeble to obtain a reasonable deformation temperature, and the degree of deformation was assessed in the range of 1.5 to 2.0 H/D via forging. The forged specimens were quenched using the same heat treatment process. The hardness and impact toughness of the steel samples were tested before and after heat treatment. Grain sizes gradually increased with an increase in the compression temperature from 950 °C to 1150 °C, and the grain sizes decreased with an increase in H/D. The microstructure of the steel samples contained pearlite, bainite, martensite, and retained austenite phase. The microstructure after forging was more uniform and finer as compared to that of as-cast steel samples. The hardness and impact toughness of the steel samples were evaluated after forging; hardness first increased and then decreased with an increase in H/D, while the impact toughness continuously increased with an increase in H/D. Hence, the microstructure and properties of steel could be improved via high temperature deformation, and this was primarily related to grain refinement.
Prediction of Chloride Distribution for Offshore Concrete Based on Statistical Analysis
Authors: Liu Qing-feng , Hu Zhi , Lu Xian-yang , Yang Jian , Azim Iftikhar , Sun Wenzhuo
Published: January 2020

Chloride-induced corrosion is the main threat to the service life of concrete structures. In order to better investigate chloride distribution in offshore concrete, this study proposed a new prediction model based on statistical analysis as well as a large body of experimental results collected from various sources. A detailed discussion found that the key influential parameters, such as diffusion coefficient ( D ), surface chloride concentration ( C S ) and penetration depth ( x ) are all highly time-dependent. The exposure zone, water–cement ratio and service time were also considered as relevant factors. The proposed model is then validated by two alternative tests and the results suggest that it is feasible in predicting the chloride content and penetration depth of concrete structures in a marine environment under chloride attack.
Application of Machine Learning to Predict Grain Boundary Embrittlement in Metals by Combining Bonding-Breaking and Atomic Size Effects
Authors: Wu Xuebang , Wang Yu-xuan , He Kan-ni , Li Xiangyan , Liu Wei , Zhang Yange , Xu Yichun , Liu Changsong
Published: January 2020

The strengthening energy or embrittling potency of an alloying element is a fundamental energetics of the grain boundary (GB) embrittlement that control the mechanical properties of metallic materials. A data-driven machine learning approach has recently been used to develop prediction models to uncover the physical mechanisms and design novel materials with enhanced properties. In this work, to accurately predict and uncover the key features in determining the strengthening energies, three machine learning methods were used to model and predict strengthening energies of solutes in different metallic GBs. In addition, 142 strengthening energies from previous density functional theory calculations served as our dataset to train three machine learning models: support vector machine (SVM) with linear kernel, SVM with radial basis function (RBF) kernel, and artificial neural network (ANN). Considering both the bond-breaking effect and atomic size effect, the nonlinear kernel based SVR model was found to perform the best with a correlation of r2 ~ 0.889. The size effect feature shows a significant improvement to prediction performance with respect to using bond-breaking effect only. Moreover, the mean impact value analysis was conducted to quantitatively explore the relative significance of each input feature for improving the effective prediction.
Ultrahigh Energy Storage Properties in (Sr0.7Bi0.2)TiO3-Bi(Mg0.5Zr0.5)O3 Lead-Free Ceramics and Potential for High-Temperature Capacitors
Authors: Kong Xi , Yang Letao , Cheng Zhenxiang , Zhang Shujun
Published: January 2020

Due to the enhanced demand for numerous electrical energy storage applications, including applications at elevated temperatures, dielectric capacitors with optimized energy storage properties have attracted extensive attention. In this study, a series of lead-free strontium bismuth titanate based relaxor ferroelectric ceramics have been successfully synthesized by high temperature solid-state reaction. The ultrahigh recoverable energy storage density of 4.2 J/cm3 under 380 kV/cm, with the high efficiency of 88%, was obtained in the sample with x = 0.06. Of particular importance is that this ceramic composition exhibits excellent energy storage performance over a wide work temperature up to 150 °C, with strong fatigue endurance and fast discharge speed. All these merits demonstrate the studied ceramic system is a potential candidate for high-temperature capacitors as energy storage devices.
TEMPO-Nanocellulose/Ca2+ Hydrogels: Ibuprofen Drug Diffusion and In Vitro Cytocompatibility
Authors: Fiorati Andrea , Contessi Negrini Nicola , Baschenis Elena , Altomare Lina , Faré Silvia , Giacometti Schieroni Alberto , Piovani Daniele , Mendichi Raniero , Ferro Monica , Castiglione Franca , Mele Andrea , Punta Carlo , Melone Lucio
Published: January 2020

Stable hydrogels with tunable rheological properties were prepared by adding Ca2+ ions to aqueous dispersions of 2,2,6,6-tetramethylpiperidine 1-oxyl (TEMPO)-oxidized and ultra-sonicated cellulose nanofibers (TOUS-CNFs). The gelation occurred by interaction among polyvalent cations and the carboxylic units introduced on TOUS-CNFs during the oxidation process. Both dynamic viscosity values and pseudoplastic rheological behaviour increased by increasing the Ca2+ concentration, confirming the cross-linking action of the bivalent cation. The hydrogels were proved to be suitable controlled release systems by measuring the diffusion coefficient of a drug model (ibuprofen, IB) by high-resolution magic angle spinning (HR-MAS) nuclear magnetic resonance (NMR) spectroscopy. IB was used both as free molecule and as a 1:1 pre-formed complex with β-cyclodextrin (IB/β-CD), showing in this latter case a lower diffusion coefficient. Finally, the cytocompatibility of the TOUS-CNFs/Ca2+ hydrogels was demonstrated in vitro by indirect and direct tests conducted on a L929 murine fibroblast cell line, achieving a percentage number of viable cells after 7 days higher than 70%.
Analysis of Low-Velocity Impact Resistance of Carbon Fiber Reinforced Polymer Composites Based on the Content of Incorporated Graphite Fluoride
Authors: Leng Jing , Guo Tianzi , Yang Meng , Guo Zeshi , Fang Zhengqin , Liu Zhipeng , Li Dandan , Sun Dazhi
Published: January 2020

As a graphite derivative, graphite fluoride (GrF) has a remarkable fracture toughness improvement effect on epoxy materials. The fracture toughness variation of the epoxy could exert an influence on the low velocity impact resistance of the corresponding carbon fiber reinforced polymer (CFRP) composite. Therefore, the dependence of the low velocity impact resistance of the incorporated CFRP on the GrF content is worth analyzing. Here, different contents of GrF were applied to incorporate CFRP laminates and planned to find the optimal GrF content, in turn leading to the best impact resistance. Using a drop-weight impact test, the load vs. time curves and load vs. displacement curves were obtained. The incipient damage loads and maximum loads of various GrF contents of the samples were compared carefully. The absorbed energies during the impact process were calculated. The trend of absorbed energy decreased up to the 1 wt% sample, then increased significantly with the rise of GrF content. This deflection behavior can be explained by the combination of crack pinning, crack deflection and crack propagation, due to the rise in GrF content. Through the ultrasonic C-scan evaluation, the delamination areas of different GrF content of samples were measured. The trend of delamination area variation was accordant with the trend of absorbed energy variation. This presents a demonstration of the correlation between the absorbed energy and the damage level. The SEM images of the fracture surfaces were analyzed for the deflection behavior of the fracture toughness with various GrF contents. The plot of residual compression strength versus GrF content further indicated the 1 wt% was the optimal content at which the incorporated GrF endowed the most impact-resistant property to the CFRP laminates.
Hydrogels as Potential Nano-, Micro- and Macro-Scale Systems for Controlled Drug Delivery
Authors: Chyzy Adam , Tomczykowa Monika , Plonska-Brzezinska Marta E.
Published: January 2020

This review is an extensive evaluation and essential analysis of the design and formation of hydrogels (HGs) for drug delivery. We review the fundamental principles of HGs (their chemical structures, physicochemical properties, synthesis routes, different types, etc.) that influence their biological properties and medical and pharmaceutical applications. Strategies for fabricating HGs with different diameters (macro, micro, and nano) are also presented. The size of biocompatible HG materials determines their potential uses in medicine as drug carriers. Additionally, novel drug delivery methods for enhancing treatment are discussed. A critical review is performed based on the latest literature reports.
Experimental Analysis of the Extensional Flow of Very Weakly Viscoelastic Polymer Solutions
Authors: Rubio Manuel , Ponce-Torres Alberto , Vega Emilio José , Montanero José María
Published: January 2020

We study with ultra-high-speed imaging the thinning of the filament formed during the breakup of a pendant droplet of very weakly viscoelastic polymer solutions of polyvinylpyrrolidone (PVP) and polyethylene oxide (PEO). In the latter case, we consider two molecular weights: 10 5 g/mol (PEO100K) and 2 × 10 6 g/mol (PEO2M). The results allow us to measure with high reproducibility extensional relaxation times of the order of 10 μ s. Despite the noticeable differences between PVP and PEO100K, very similar values are obtained for the range of concentrations where the linear elasto-capillary is established. For PEO2M, the extensional relaxation time depends on the concentration even for values significantly smaller than the overlap one. The prediction c low for the concentration below which the linear elasto-capillary regime cannot be reached qualitatively agrees with the results for PVP and PEO2M, while it underestimates the critical concentration for PEO100K. The results for PEO2M are consistent with those reported in the literature for higher concentrations.
Comment on “Laboratory Measurement and Analysis of the Deteriorated Layer Permeability Coefficient of Soil–Cement Deteriorated in a Saline Environment”
Authors: Neves Rui
Published: January 2020

The derivation of a formula to compute the permeability coefficient in the commented paper assumes that the mass flow is homogeneous in a homogeneous layer of a specimen. This assumption is not correct when there is also, at least, one heterogeneous layer. Moreover, a mathematical lapse was found on one equation, that would prevent the right computation of the permeability coefficient, even if the assumption was correct. Although this does not invalidate the major conclusions of the study and has not an outstanding effect on the presented results, for the sake of rigor and sound background for future studies in this field, corrections to the published formulas and model are proposed.
Application of Boroisoquinoline Fluorophores as Chemodosimeters for Fluoride Ion and Pd (0)
Authors: Sóvári Dénes , Keserű György Miklós , Ábrányi-Balogh Péter
Published: January 2020

The development of novel chemodosimeters is currently a prosperous field in organic chemistry. Recently, a new family of fluorophores, the boroisoquinolines, were introduced with satisfying photophysical properties. As a continuation of this research, the application of boroisoquinolines is presented as chemodosimeters for fluoride anion and Pd (0). The new tools showed good selectivity for the detection of the analytes. Moreover, the mechanism of action was investigated experimentally.
Development of an Analytical Model for Optimization of Direct Laser Interference Patterning
Authors: Voisiat Bogdan , Aguilar-Morales Alfredo I. , Kunze Tim , Lasagni Andrés Fabián
Published: January 2020

Direct laser interference patterning (DLIP) has proven to be a fast and, at the same time, high-resolution process for the fabrication of large-area surface structures. In order to provide structures with adequate quality and defined morphology at the fastest possible fabrication speed, the processing parameters have to be carefully selected. In this work, an analytical model was developed and verified by experimental data, which allows calculating the morphological properties of periodic structures as a function of most relevant laser-processing parameters. The developed model permits to improve the process throughput by optimizing the laser spot diameter, as well as pulse energy, and repetition rate. The model was developed for the structures formed by a single scan of the beam in one direction. To validate the model, microstructures with a 5.5 µm spatial period were fabricated on stainless steel by means of picosecond DLIP (10 ps), using a laser source operating at a 1064 nm wavelength. The results showed a difference of only 10% compared to the experimental results.
Influence of Selected Warm Mix Asphalt Additives on Cracking Susceptibility of Asphalt Mixtures
Authors: Stienss Marcin , Szydlowski Cezary
Published: January 2020

Warm mix asphalt (WMA) has been widely accepted as a future asphalt paving technology. Besides clear advantages, there are still some concerns regarding durability and long-term performance of pavements made with this type of asphalt mixtures. One of the most important issues is low temperature behaviour of WMA because certain additives used for temperature reduction can affect bitumen properties. This paper presents the evaluation of low-temperature properties of laboratory-produced asphalt concrete for wearing course with selected WMA additives. One type of bitumen with paving grade 50/70 and five WMA additives of different nature (organic, surface tension reducer and combination of both) were used in this study. The production and compaction temperature of mixtures containing WMA additives was 25 °C lower in comparison with the temperature of the reference mix. To assess the susceptibility of WMA to low-temperature cracking, Semi-Circular Bending (SCB) and Thermal Stress Restrained Specimen Test (TSRST) were used. Supplementary rating was made by analysing Bending Beam Rheometer (BBR) test results of asphalt binders.
Dielectric Properties of Graphene/Titania/Polyvinylidene Fluoride (G/TiO2/PVDF) Nanocomposites
Authors: Ishaq Saira , Kanwal Farah , Atiq Shahid , Moussa Mahmoud , Azhar Umar , Losic Dusan
Published: January 2020

Flexible electronics have gained eminent importance in recent years due to their high mechanical strength and resistance to environmental conditions, along with their effective energy storage and energy generating abilities. In this work, graphene/ceramic/polymer based flexible dielectric nanocomposites have been prepared and their dielectric properties were characterized. The composite was formulated by combining graphene with rutile and anatase titania, and polyvinylidene fluoride in different weight ratios to achieve optimized dielectric properties and flexibility. After preparation, composites were characterized for their morphologies, structures, functional groups, thermal stability and dielectric characterizations by using scanning electron microscopy, X-ray diffraction, Raman spectroscopy, Fourier transform infrared spectroscopy, thermal gravimetric analysis and impedance spectroscopy. Dielectric results showed that prepared flexible composite exhibited dielectric constant of 70.4 with minor leakage current (tanδ) i.e., 0.39 at 100 Hz. These results were further confirmed by calculating alternating current (AC) conductivity and electric modulus which ensured that prepared material is efficient dielectric material which may be employed in electronic industry for development of next generation flexible energy storage devices.
Microstructural Characterization of TiC–White Cast-Iron Composites Fabricated by In Situ Technique
Authors: Moreira Aida B. , Sousa Ricardo O. , Lacerda Pedro , Ribeiro Laura M. M. , Pinto Ana M. P. , Vieira Manuel F.
Published: January 2020

High-chromium white cast-iron specimens locally reinforced with TiC–metal matrix composites were successfully produced via an in situ technique based on combustion synthesis. Powder mixtures of Ti, Al, and graphite were prepared and compressed to fabricate green powder compacts that were inserted into the mold cavity before the casting. The heat of the molten iron causes the ignition of the combustion reaction of the reactant powders, resulting in the formation of the TiC by self-propagating high-temperature synthesis. The microstructure of the resultant composites and the bonding interfaces was characterized by scanning electron microscopy and energy dispersive spectroscopy (SEM/EDS), X-ray diffraction (XRD), and transmission electron microscopy (TEM). The microstructural results showed a good adhesion of the composite, suggesting an effective infiltration of the metal into the inserted compact, yet a non-homogeneous distribution of the TiC in the martensite matrix was observed. Based on the results, the in situ synthesis appears to be a great potential technique for industrial applications.
Photoelectrochemical Water Splitting Reaction System Based on Metal-Organic Halide Perovskites
Authors: Kim Dohun , Lee Dong-Kyu , Kim Seong Min , Park Woosung , Sim Uk
Published: January 2020

In the development of hydrogen-based technology, a key challenge is the sustainable production of hydrogen in terms of energy consumption and environmental aspects. However, existing methods mainly rely on fossil fuels due to their cost efficiency, and as such, it is difficult to be completely independent of carbon-based technology. Electrochemical hydrogen production is essential, since it has shown the successful generation of hydrogen gas of high purity. Similarly, the photoelectrochemical (PEC) method is also appealing, as this method exhibits highly active and stable water splitting with the help of solar energy. In this article, we review recent developments in PEC water splitting, particularly those using metal-organic halide perovskite materials. We discuss the exceptional optical and electrical characteristics which often dictate PEC performance. We further extend our discussion to the material limit of perovskite under a hydrogen production environment, i.e., that PEC reactions often degrade the contact between the electrode and the electrolyte. Finally, we introduce recent improvements in the stability of a perovskite-based PEC device.
Statistical Aspects of High-Dimensional Sparse Artificial Neural Network Models
Authors: Yang Kaixu , Maiti Tapabrata
Published: January 2020

An artificial neural network (ANN) is an automatic way of capturing linear and nonlinear correlations, spatial and other structural dependence among features. This machine performs well in many application areas such as classification and prediction from magnetic resonance imaging, spatial data and computer vision tasks. Most commonly used ANNs assume the availability of large training data compared to the dimension of feature vector. However, in modern applications, as mentioned above, the training sample sizes are often low, and may be even lower than the dimension of feature vector. In this paper, we consider a single layer ANN classification model that is suitable for analyzing high-dimensional low sample-size (HDLSS) data. We investigate the theoretical properties of the sparse group lasso regularized neural network and show that under mild conditions, the classification risk converges to the optimal Bayes classifier’s risk (universal consistency). Moreover, we proposed a variation on the regularization term. A few examples in popular research fields are also provided to illustrate the theory and methods.
Solution of the Problem of Natural Gas Storages Creating in Gas Hydrate State in Porous Reservoirs
Authors: Musakaev Nail G. , Khasanov Marat K.
Published: January 2020

Underground gas hydrate storage of natural gas is a rather promising way of creating underground storage facilities for hydrocarbon raw materials in porous reservoirs. This paper presents a solution to the problem of the formation of CH4 hydrate in a porous medium during the injection of methane into a reservoir at a temperature lower than the initial temperature of the reservoir. Self-similar solutions of the problem in axisymmetric approximation are given, describing the pressure and temperature distribution in separate reservoir regions at the formation of gas hydrate on the frontal surface. On the basis of the method of sequential change of stationary states, an analytical solution was obtained, which allowed us to determine the position of the methane hydrate formation boundary depending on different parameters for any moment of time. The limits of the applicability of the proposed model are also given. Thus, the analysis of the calculation results showed that the constructed solution allows one to sufficiently and accurately determine the values of parameters at the frontal surface for a highly permeable medium (k0 > 10−13 m2). It was proved that in the case of a highly permeable medium, the methane hydrate formation intensity will be limited by convective heat dissipation during hydrate formation.
Linear Maps that Preserve Any Two Term Ranks on Matrix Spaces over Anti-Negative Semirings
Authors: Kang Kyung Tae , Song Seok-Zun , Jun Young Bae
Published: January 2020

There are many characterizations of linear operators from various matrix spaces into themselves which preserve term rank. In this research, we characterize the linear maps which preserve any two term ranks between different matrix spaces over anti-negative semirings, which extends the previous results on characterizations of linear operators from some matrix spaces into themselves. That is, a linear map T from p × q matrix spaces into m × n matrix spaces preserves any two term ranks if and only if T preserves all term ranks if and only if T is a ( P , Q , B )-block map.
Proof and Use of the Method of Combination Differences for Analyzing High-Resolution Coherent Multidimensional Spectra
Authors: Chen Peter C. , Ehme Jeffrey
Published: January 2020

High-resolution coherent multidimensional spectroscopy is a technique that automatically sorts rotationally resolved peaks by quantum number in 2D or 3D space. The resulting ability to obtain a set of peaks whose J values are sequentially ordered but not known raises the question of whether a method can be developed that yields a single unique solution that is correct. This paper includes a proof based upon the method of combined differences that shows that the solution would be unique because of the special form of the rotational energy function. Several simulated tests using a least squares analysis of simulated data were carried out, and the results indicate that this method is able to accurately determine the rotational quantum number, as well as the corresponding Dunham coefficients. Tests that include simulated random error were also carried out to illustrate how error can affect the accuracy of higher-order Dunham coefficients, and how increasing the number of points in the set can be used to help address that.
Slant Curves in Contact Lorentzian Manifolds with CR Structures
Authors: Lee Ji-Eun
Published: January 2020

In this paper, we first find the properties of the generalized Tanaka–Webster connection in a contact Lorentzian manifold. Next, we find that a necessary and sufficient condition for the ∇ ^ -geodesic is a magnetic curve (for ∇) along slant curves. Finally, we prove that when c ≤ 0 , there does not exist a non-geodesic slant Frenet curve satisfying the ∇ ^ -Jacobi equations for the ∇ ^ -geodesic vector fields in M. Thus, we construct the explicit parametric equations of pseudo-Hermitian pseudo-helices in Lorentzian space forms M 1 3 ( H ^ ) for H ^ = 2 c > 0 .
Carrying Capacity of a Population Diffusing in a Heterogeneous Environment
Authors: DeAngelis D.L. , Zhang Bo , Ni Wei-Ming , Wang Yuanshi
Published: January 2020

The carrying capacity of the environment for a population is one of the key concepts in ecology and it is incorporated in the growth term of reaction-diffusion equations describing populations in space. Analysis of reaction-diffusion models of populations in heterogeneous space have shown that, when the maximum growth rate and carrying capacity in a logistic growth function vary in space, conditions exist for which the total population size at equilibrium (i) exceeds the total population that which would occur in the absence of diffusion and (ii) exceeds that which would occur if the system were homogeneous and the total carrying capacity, computed as the integral over the local carrying capacities, was the same in the heterogeneous and homogeneous cases. We review here work over the past few years that has explained these apparently counter-intuitive results in terms of the way input of energy or another limiting resource (e.g., a nutrient) varies across the system. We report on both mathematical analysis and laboratory experiments confirming that total population size in a heterogeneous system with diffusion can exceed that in the system without diffusion. We further report, however, that when the resource of the population in question is explicitly modeled as a coupled variable, as in a reaction-diffusion chemostat model rather than a model with logistic growth, the total population in the heterogeneous system with diffusion cannot exceed the total population size in the corresponding homogeneous system in which the total carrying capacities are the same.
Integral Inequalities for s-Convexity via Generalized Fractional Integrals on Fractal Sets
Authors: Almutairi Ohud , Kılıçman Adem
Published: January 2020

In this study, we establish new integral inequalities of the Hermite–Hadamard type for s-convexity via the Katugampola fractional integral. This generalizes the Hadamard fractional integrals and Riemann–Liouville into a single form. We show that the new integral inequalities of Hermite–Hadamard type can be obtained via the Riemann–Liouville fractional integral. Finally, we give some applications to special means.
A New Angular Measurement in Minkowski 3-Space
Authors: Qian Jinhua , Tian Xueqian , Liu Jie , Kim Young Ho
Published: January 2020

In Lorentz–Minkowski space, the angles between any two non-null vectors have been defined in the sense of the angles in Euclidean space. In this work, the angles relating to lightlike vectors are characterized by the Frenet frame of a pseudo null curve and the angles between any two non-null vectors in Minkowski 3-space. Meanwhile, the explicit measuring methods are demonstrated through several examples.
Mathematical Analysis of a Thermostatted Equation with a Discrete Real Activity Variable
Authors: Bianca Carlo , Menale Marco
Published: January 2020

This paper deals with the mathematical analysis of a thermostatted kinetic theory equation. Specifically, the assumption on the domain of the activity variable is relaxed allowing for the discrete activity to attain real values. The existence and uniqueness of the solution of the related Cauchy problem and of the related non-equilibrium stationary state are established, generalizing the existing results.
Fixed-Point Results for a Generalized Almost (s, q)—Jaggi F-Contraction-Type on b—Metric-Like Spaces
Authors: Hammad Hasanen A. , De la Sen Manuel
Published: January 2020

The purpose of this article is to present a new generalized almost ( s , q ) − Jaggi F − contraction-type and a generalized almost ( s , q ) − Jaggi F − Suzuki contraction-type and some results in related fixed point on it in the context of b − metric-like spaces are discussed. Also, we support our theoretical results with non-trivial examples. Finally, applications to find a solution for the electric circuit equation and second-order differential equations are presented and an strong example is given here to support the first application.
Evaluation of Elite Athletes Training Management Efficiency Based on Multiple Criteria Measure of Conditioning Using Fewer Data
Authors: Krylovas Aleksandras , Kosareva Natalja , Dadelienė Rūta , Dadelo Stanislav
Published: January 2020

Innovative solutions and techniques in the sports industry are commonly used and tested in real conditions. Elite athletes have to achieve their peak performance before the main competition of the year, which is the World Championship, and every fourth year before the Olympic Games, when the main competition of athletes takes place. The present study aims to analyze and evaluate the ability of elite kayakers to achieve the best form at the right times, with the Olympic Games taking the greatest importance. Target values for multiple measures of conditioning are compared to target values set by experts. A weighted least squares metric with weights varied by time period is developed as a measure of fulfillment of the athletes’ conditioning plans. The novelty of the paper is the idea of using linear combination of polynomials and trigonometric functions for approximating the target functions and application of the proposed methodology for the optimization and evaluation of athletic training.
Approximation by Generalized Lupaş Operators Based on q-Integers
Authors: Qasim Mohd , Mursaleen M. , Khan Asif , Abbas Zaheer
Published: January 2020

The purpose of this paper is to introduce q-analogues of generalized Lupaş operators, whose construction depends on a continuously differentiable, increasing, and unbounded function ρ . Depending on the selection of q, these operators provide more flexibility in approximation and the convergence is at least as fast as the generalized Lupaş operators, while retaining their approximation properties. For these operators, we give weighted approximations, Voronovskaja-type theorems, and quantitative estimates for the local approximation.
Convergence Theorems for Modified Implicit Iterative Methods with Perturbation for Pseudocontractive Mappings
Authors: Jung Jong Soo
Published: January 2020

In this paper, first, we introduce a path for a convex combination of a pseudocontractive type of mappings with a perturbed mapping and prove strong convergence of the proposed path in a real reflexive Banach space having a weakly continuous duality mapping. Second, we propose two modified implicit iterative methods with a perturbed mapping for a continuous pseudocontractive mapping in the same Banach space. Strong convergence theorems for the proposed iterative methods are established. The results in this paper substantially develop and complement the previous well-known results in this area.
The Chebyshev Difference Equation
Authors: Cuchta Tom , Pavelites Michael , Tinney Randi
Published: January 2020

We define and investigate a new class of difference equations related to the classical Chebyshev differential equations of the first and second kind. The resulting “discrete Chebyshev polynomials” of the first and second kind have qualitatively similar properties to their continuous counterparts, including a representation by hypergeometric series, recurrence relations, and derivative relations.
Structure Functions of Pseudo Null Curves in Minkowski 3-Space
Authors: Qian Jinhua , Liu Jie , Tian Xueqian , Kim Young Ho
Published: January 2020

In this work, the embankment surfaces with pseudo null base curves are investigated in Minkowski 3-space. The representation formula of pseudo null curves is obtained via the defined structure functions and the k-type pseudo null helices are discussed completely. Based on the theories of pseudo null curves, a class of embankment surfaces are constructed and characterized by the structure functions of the pseudo null base curves.
Modulation of the Liver Protein Carbonylome by the Combined Effect of Marine Omega-3 PUFAs and Grape Polyphenols Supplementation in Rats Fed an Obesogenic High Fat and High Sucrose Diet
Authors: Méndez Lucía , Muñoz Silvia , Miralles-Pérez Bernat , Nogués Maria Rosa , Ramos-Romero Sara , Torres Josep Lluis , Medina Isabel
Published: January 2020

Diet-induced obesity has been linked to metabolic disorders such as cardiovascular diseases and type 2 diabetes. A factor linking diet to metabolic disorders is oxidative stress, which can damage biomolecules, especially proteins. The present study was designed to investigate the effect of marine omega-3 polyunsaturated fatty acids (PUFAs) (eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA)) and their combination with grape seed polyphenols (GSE) on carbonyl-modified proteins from plasma and liver in Wistar Kyoto rats fed an obesogenic diet, namely high-fat and high-sucrose (HFHS) diet. A proteomics approach consisting of fluorescein 5-thiosemicarbazide (FTSC) labelling of protein carbonyls, visualization of FTSC-labelled protein on 1-DE or 2-DE gels, and protein identification by MS/MS was used for the protein oxidation assessment. Results showed the efficiency of the combination of both bioactive compounds in decreasing the total protein carbonylation induced by HFHS diet in both plasma and liver. The analysis of carbonylated protein targets, also referred to as the ‘carbonylome’, revealed an individual response of liver proteins to supplements and a modulatory effect on specific metabolic pathways and processes due to, at least in part, the control exerted by the supplements on the liver protein carbonylome. This investigation highlights the additive effect of dietary fish oils and grape seed polyphenols in modulating in vivo oxidative damage of proteins induced by the consumption of HFHS diets.
Can an Open-Label Placebo Be as Effective as a Deceptive Placebo? Methodological Considerations of a Study Protocol
Authors: Druart Leo , Graham Longsworth SaraEve , Rolland Carole , Dolgopoloff Maïa , Terrisse Hugo , Bosson Jean-Luc , Pinsault Nicolas
Published: January 2020

Background: Placebo has been studied for many years and is ever-present in healthcare. In clinical practice, its use is limited by ethical issues raised by the deception entailed by its administration. Objective: To investigate whether, when given detailed information about pain and underlying placebo mechanisms, subjects will have a response similar to that of those subjected to a procedure in which they receive a conventional placebo treatment. Methods: The study is designed as a non-inferiority randomized, parallel with a nested crossover trial. In addition, 126 subjects without any known pathology will be included. They will be randomized into two groups. Each subject will undergo three Cold Pressor Tests (CPT): calibration, condition of interest (deceptive placebo or educated placebo), and control. Our main judgment criterion will be the comparison in pain intensity experienced on the visual analog scale between the two CPTs with placebo conditions. Results: This study will allow us to rule on the non-inferiority of an “educated” placebo compared to a deceptive placebo in the context of an acute painful stimulation. It is another step towards the understanding of open-label placebo and its use in clinical practice. Conclusions: This study has been approved by the ethics committee in France (2017-A01643-50) and registered on ClinicalTrials.gov (NCT03934138).
Sorption/Diffusion Contributions to the Gas Permeation Properties of Bi-Soft Segment Polyurethane/Polycaprolactone Membranes for Membrane Blood Oxygenators
Authors: Eusébio Tiago M. , Martins Ana Rita , Pon Gabriela , Faria Mónica , Morgado Pedro , Pinto Moisés L. , Filipe Eduardo J. M. , de Pinho Maria Norberta
Published: January 2020

Due to their high hemocompatibility and gas permeation capacity, bi-soft segment polyurethane/polycaprolactone (PU/PCL) polymers are promising materials for use in membrane blood oxygenators. In this work, both nonporous symmetric and integral asymmetric PU/PCL membranes were synthesized, and the permeation properties of the atmospheric gases N2, O2, and CO2 through these membranes were experimentally determined using a new custom-built gas permeation apparatus. Permeate pressure vs. time curves were obtained at 37.0 °C and gas feed pressures up to 5 bar. Fluxes, permeances, and permeability coefficients were determined from the steady-state part of the curves, and the diffusion and sorption coefficients were estimated from the analysis of the transient state using the time-lag method. Independent measurements of the sorption coefficients of the three gases were performed, under equilibrium conditions, in order to validate the new setup and procedure. This work shows that the gas sorption in the PU/PCL polymers is the dominant factor for the permeation properties of the atmospheric gases in these membranes.
Formation of Microfiltration Membranes from PMP/PIB Blends: Effect of PIB Molecular Weight on Membrane Properties
Authors: Ilyin Sergey , Ignatenko Viktoria , Anokhina Tatyana , Bakhtin Danila , Kostyuk Anna , Dmitrieva Evgenia , Antonov Sergey , Volkov Alexey
Published: January 2020

A series of microfiltration membranes were fabricated by the extraction of polyisobutylene (PIB) from its immiscible blends with polymethylpentene (PMP). Three PIB with different molecular weight of 7.5 × 104 (Oppanol B15), 34 × 104 (Oppanol B50) and 110 × 104 (Oppanol B100) g/mol, respectively, were used to evaluate the effect of molecular weight on the porous structure and transport properties of resulting PMP-based membranes. To mimic the conditions of 3D printing, the flat-sheet membranes were fabricated by means of melting of mixtures of various PMP and PIB concentrations through the hot rolls at 240 ∘ C followed by a quick cooling. The rheology study of individual components and blends at 240 ∘ C revealed that PIB B50 possessed the most close flow curve to the pure PMP, and their blends demonstrated the lowest viscosity comparing to the compositions made of PIB with other molecular weights (B15 or B100). SEM images of the cross-section PMP membranes after PIB extraction (PMP/PIB = 55/45) showed that the use of PIB B50 allowed obtaining the sponge-like porous structure, whereas the slit-shaped pores were found in the case of PIB B15 and PIB B100. Additionally, PMP/B50 blends demonstrated the optimum combinations of mechanical properties (str = 9.1 MPa, E = 0.20 GPa), adhesion to steel (adh = 0.8 kPa) and retention performance (R240 nm = 99%, R38 nm = 39%). The resulting membranes were non- or low-permeable for water if the concentration of PIB B50 in the initial blends was 40 wt.% or lower. The optimal filtration performance was observed in the case of PMP/B50 blends with a ratio of 55/45 (Pwater = 1.9 kg/m2hbar, R240 nm = 99%, R38 nm = 39%) and 50/50 (Pwater = 1100 kg/m2hbar, R240 nm = 91%, R38 nm = 36%).
Constitutive Model and Flow Behavior of B1500HS High-Strength Steel During the Hot Deformation Process
Authors: Li Muyu , Duan Yongchuan , Yao Dan , Guan Yingping , Yang Liu
Published: January 2020

Hot compression tests were carried out on a Gleeble-3800 thermal mechanical simulator in the temperature range from 700 to 900 °C and strain rate range from 0.005 to 10 s−1 to investigate the hot deformation behavior of B1500HS high-strength steel. Softening mechanisms of B1500HS high-strength steel under different deformation conditions were analyzed according to the characteristics of flow stress–strain curves. By analyzing and processing the experimental data, the values of steady flow stress, saturated stress, dynamic recovery (DRV) softening coefficient, and other factors were solved and these parameters were expressed as functions of Zener–Hollomon factors. Based on the dislocation density theory and the kinetic model of dynamic recrystallization (DRX), constitutive models corresponding to different softening mechanisms were established. The flow stress–strain curves of B1500HS predicted by a constitutive model are in good agreement with the experimental results and the correlation coefficient is . The comparison results indicate that the constitutive models can accurately reflect the deformation behavior of B1500HS high-strength steel under different conditions.