bluuebunny/crossref_metadata_2025 huggingface dataset:
Hospital Incidence, Treatment, and Outcome of 885 Patients with Thoracoabdominal Aortic Aneurysms Treated in Switzerland over 10 Years—A Secondary Analysis of Swiss DRG Data
Authors: Stoklasa Kerstin , Menges Anna-Leonie , Reutersberg Benedikt , Meuli Lorenz , Zimmermann Alexander
Published: August 2023

Despite the development of fenestrated and branched endovascular aortic repair (f/bEVAR), the surgical management of thoraco-abdominal aortic aneurysms (TAAAs) remains a major challenge. The aim of this study was to analyse the hospital incidence and hospital mortality of patients treated for TAAAs in Switzerland. Secondary data analysis was performed using nationwide administrative discharge data from 2009–2018. Standardised incidence rates and adjusted mortality rates were calculated. A total of 885 cases were identified (83.2% nonruptured (nrTAAA), 16.8% ruptured (rTAAA)), where 69.3% were male. The hospital incidence rate for nrTAAA was 0.4 per 100,000 women and 0.9 per 100,000 men in 2009, which had doubled for both sexes by 2018. For rTAAA, there was no trend over the years. The most common procedure was f/bEVAR (44.2%), followed by OAR (39.5%), and 9.8% received a hybrid procedure. There was a significant increase in endovascular procedures over time. The all-cause mortality was 7.1% with nrTAAA and 55% with rTAAA. The mortality was lower for rTAAA when f/bEVAR or hybrid procedures were used. A ruptured aneurysm and higher comorbidity were associated with higher hospital mortality. This study demonstrates that the treatment approach has changed significantly over the observed period. The use of f/bEVAR nearly tripled in nrTAAA and doubled in rTAAA during this decade.
New Perianal Sepsis Risk Score Predicts Outcome of Elderly Patients with Perianal Abscesses
Authors: Reichert Martin , Eckerth Lukas , Fritzenwanker Moritz , Imirzalioglu Can , Amati Anca-Laura , Askevold Ingolf , Padberg Winfried , Hecker Andreas , Liese Juliane , Bender Fabienne
Published: August 2023

Antibiotic therapy following surgical perianal abscess drainage is debated, but may be necessary for high-risk patients. Frailty has been shown to increase the risk of unfavorable outcomes in elderly surgical patients. This study aims to identify high-risk patients by retrospectively analyzing a single-center cohort and using a pretherapeutic score to predict the need for postoperative antibiotics and extended nursing care following perianal abscess drainage surgery. The perianal sepsis risk score was developed through univariable and multivariable analysis. Internal validation was assessed using the area under receiver-operating characteristic curve. Elderly, especially frail patients exhibited more severe perianal disease, higher frequency of antibiotic therapy, longer hospitalization, poorer clinical outcomes. Multivariable analysis revealed that scores in the 5-item modified frailty index, severity of local infection, and preoperative laboratory markers of infection independently predicted the need for prolonged hospitalization and anti-infective therapy after abscess drainage surgery. These factors were combined into the perianal sepsis risk score, which demonstrated better predictive accuracy for prolonged hospitalization and antibiotic therapy compared with chronological age or frailty status alone. Geriatric assessments are becoming increasingly important in clinical practice. The perianal sepsis risk score identifies high-risk patients before surgery, enabling early initiation of antibiotic therapy and allocation of additional nursing resources.
Clothing, Gender, and Sociophonetic Perceptions of Mayan-Accented Spanish in Guatemala
Authors: Baird Brandon
Published: August 2023

Perceptual sociophonetic work on Guatemalan Spanish has demonstrated that listeners are more likely to link male voices with traditional Maya clothing, the traje típico, when their speech includes features of Mayan-accented Spanish. However, as Maya women are more likely than men to wear the traje típico, this matched-guise study investigates native Guatemalans’ perceptions of Mayan-accented Spanish produced by female voices. The results demonstrate that guises with features of Mayan-accented Spanish were more likely to have traje típico as a response than guises without these features. When compared to the previous studies with male-voiced guises, the findings suggest an interaction between gender and Mayan-accented Spanish. Traje típico responses were more common for female-voiced guises than male-voiced guises and occurred at the highest rate among female-voiced guises with features of Mayan-accented Spanish. Thus, gendered and cultural practices are reflected in the indexical fields of Mayan-accented Spanish in Guatemala, regardless of the gender or ethnicity of the listener. That is, the visual body–language link is significantly more essentialized for the identity of a woman than for the identity of a man in Guatemala, suggesting that gendered stereotypes, language ideologies, and embodied practices mutually reinforce one another in the collective consciousness of the region.
D-Penicillamine-Induced Myasthenia Gravis—A Probable Complication of Wilson’s Disease Treatment—A Case Report and Systematic Review of the Literature
Authors: Antos Agnieszka , Członkowska Anna , Bembenek Jan , Kurkowska-Jastrzębska Iwona , Litwin Tomasz
Published: August 2023

Wilson’s disease (WD) is a genetic disorder with copper accumulation in various tissues leading to related clinical symptoms (mainly hepatic and neuropsychiatric) which can be in 85% of patients successfully treated with anti-copper agents. However, during WD treatment neurological deterioration may occur in several patients. D-penicillamine (DPA) is one of the most frequently used drugs in WD treatment. Despite its efficacy, DPA can produce many adverse drug reactions, which should be recognized early. We present the case of a 51-year-old man diagnosed with the hepatic form of WD and initially treated with DPA in whom after 15 months of treatment, diplopia and evening ptosis occurred. WD treatment non-compliance as well as overtreatment were excluded. Supported by neurological symptoms, a positive edrophonium test, and high serum levels of antibodies against acetylcholine receptors (AChR-Abs), as well as low concentrations of antibodies against muscle-specific kinase (MuSK-Abs), the diagnosis of myasthenia gravis (MG), induced by DPA, was established. DPA was stopped; zinc sulfate for WD and pyridostigmine for MG symptoms were introduced. Diplopia and ptosis subsided after a few days, which supported our diagnosis. During a follow-up visit after 6 months, the patient did not present any MG symptoms. AChR-Abs level gradually decreased and MuSK-Abs were no longer detected. Pyridostigmine was stopped, and within 9 months of follow-up, the neurological symptoms of MG did not reoccur. The authors discussed the patient’s neurological deterioration, performed a systematic review of DPA-induced MG in WD and concluded that MG is a rare and usually reversible complication of DPA treatment. DPA-induced MG generally occurs 2–12 months after treatment initiation and ocular symptoms predominate. Response to pyridostigmine treatment is good and MG symptoms usually reverse within one year after DPA treatment cessation. However, symptoms may persist in some cases where DPA treatment is only a trigger factor for MG occurrence.
Graphene Oxide/Polyethyleneimine-Modified Cation Exchange Membrane for Efficient Selective Recovery of Ammonia Nitrogen from Wastewater
Authors: Yu Yuanyuan , Zeng Qin , Zhang Haoquan , Ao Maoqin , Yao Jingmei , Yang Chun , Velizarov Svetlozar , Han Le
Published: August 2023

Competition for the migration of interfering cations limits the scale-up and implementation of the Donnan dialysis process for the recovery of ammonia nitrogen (NH4+-N) from wastewater in practice. Highly efficient selective permeation of NH4+ through a cation exchange membrane (CEM) is expected to be modulated via tuning the surface charge and structure of CEM. In this work, a novel CEM was designed to form a graphene oxide (GO)-polyethyleneimine (PEI) cross-linked layer by introducing self-assembling layers of GO and PEI on the surface of a commercial CEM, which rationally regulates the surface charge and structure of the membrane. The resulting positively charged membrane surface exhibits stronger repulsion for divalent cations compared to monovalent cations according to Coulomb’s law, while, simultaneously, GO forms π–metal cation conjugates between metal cations (e.g., Mg2+ and Ca2+), thus limiting metal cation transport across the membrane. During the DD process, higher NH4+ concentrations resulted in a longer time to reach Donnan equilibrium and higher NH4+ flux, while increased Mg2+ concentrations resulted in lower NH4+ flux (from 0.414 to 0.213 mol·m−2·h−1). Using the synergistic effect of electrostatic interaction and non-covalent cross-linking, the designed membrane, referred to as GO-PEI (20) and prepared by a 20 min impregnation in the GO-PEI mixture, exhibited an NH4+ transport rate of 0.429 mol·m−2·h−1 and a Mg2+ transport rate of 0.003 mol·m−2·h−1 in single-salt solution tests and an NH4+/Mg2+ selectivity of 15.46, outperforming those of the unmodified and PEI membranes (1.30 and 5.74, respectively). In mixed salt solution tests, the GO-PEI (20) membrane showed a selectivity of 15.46 (~1.36, the unmodified membrane) for NH4+/Mg2+ and a good structural stability after 72 h of continuous operation. Therefore, this facile surface charge modulation approach provides a promising avenue for achieving efficient NH4+-selective separation by modified CEMs.
Effect of High-Energy Ball Milling Time on the Density and Mechanical Properties of W-7%Ni-3%Fe Alloy
Authors: Nokhrin Aleksey , Malekhonova Nataliya , Chuvil’deev Vladimir , Melekhin Nikolay , Bragov Anatoliy , Filippov Andrey , Boldin Maksim , Lantsev Eugeniy , Sakharov Nikita
Published: August 2023

The present work was aimed at the investigation of the effect of high-energy ball milling (HEBM) time on the sintering kinetics, structure, and properties of the heavy tungsten alloy (HTA) W-7%Ni-3%Fe. The HTA samples were obtained from nanopowders (20–80 nm) using conventional liquid-phase sintering (LPS) in hydrogen and using spark plasma sintering (SPS) in vacuum. The HTA density was shown to depend non-monotonously on the HEBM time that originates from the formation of nonequilibrium solid solutions in the W-Ni-Fe systems during HEBM. The SPS kinetics of the HTA nanopowders was shown to have a two-stage character, the intensity of which depends on the Coble diffusion creep rate and on the intensity of diffusion of the tungsten atoms in the crystal lattice of the γ-phase. The kinetics of sintering of the initial submicron powders has a single-stage character originating from the intensity of the grain boundary diffusion in the γ-phase. The dependencies of the hardness and of the yield strength on the grain sizes were found to obey the Hall–Petch relation. The hardness, strength, and dynamic strength in the compression tests of the fine-grained tungsten alloys obtained using SPS and LPS were studied.
Effects of Nickel Impregnation on the Catalytic Removal of Nitric Oxide by Polyimide-Based Activated Carbon Fibers
Authors: Jeong Hun-Seung , Kim Byung-Joo
Published: August 2023

Activated carbon fibers (ACFs) are beneficial for adsorbing harmful gases because of the well-developed micropores on their surface. Usually, the physical adsorption of harmful gases by ACFs is limited by their textural properties. In this study, the effect of nickel particle catalyst impregnation on the physicochemical removal of nitric oxide (NO) by polyimide (PI)-based ACFs (PI-ACFs) was investigated. Ni(NO3)2 was used as the precursor of nickel particle catalysts and impregnated on ACFs as a function of concentrations. The Ni(NO3)2/ACFs were then thermally reduced in an argon atmosphere containing 4% hydrogen (400 °C, 1 h). The gases generated during heat treatment were verified using Fourier transform infrared spectroscopy, and the impregnation amount of metallic nickel was also calculated based on the gas amount generated. The specific surface areas of the ACF and Ni-ACFs were determined to be 1010–1180 m2/g, while the nickel impregnation amount was 0.85–5.28 mg/g. The NO removal capacity of the Ni-ACF was found to be enhanced with the addition of Ni catalysts. In addition, metallic nickel particles on the ACFs maintained their chemical molecular structures before and after the NO removal tests.a
Macrophage Polarization Status Impacts Nanoceria Cellular Distribution but Not Its Biotransformation or Ferritin Effects
Authors: Graham Uschi M. , Dozier Alan K. , Feola David J. , Tseng Michael T. , Yokel Robert A.
Published: August 2023

The innate immune system is the first line of defense against external threats through the initiation and regulation of inflammation. Macrophage differentiation into functional phenotypes influences the fate of nanomaterials taken up by these immune cells. High-resolution electron microscopy was used to investigate the uptake, distribution, and biotransformation of nanoceria in human and murine M1 and M2 macrophages in unprecedented detail. We found that M1 and M2 macrophages internalize nanoceria differently. M1-type macrophages predominantly sequester nanoceria near the plasma membrane, whereas nanoceria are more uniformly distributed throughout M2 macrophage cytoplasm. In contrast, both macrophage phenotypes show identical nanoceria biotransformation to cerium phosphate nanoneedles and simultaneous nanoceria with ferritin co-precipitation within the cells. Ferritin biomineralization is a direct response to nanoparticle uptake inside both macrophage phenotypes. We also found that the same ferritin biomineralization mechanism occurs after the uptake of Ce-ions into polarized macrophages and into unpolarized human monocytes and murine RAW 264.7 cells. These findings emphasize the need for evaluating ferritin biomineralization in studies that involve the internalization of nano objects, ranging from particles to viruses to biomolecules, to gain greater mechanistic insights into the overall immune responses to nano objects.
Construction of Type-II Heterojunctions in Crystalline Carbon Nitride for Efficient Photocatalytic H2 Evolution
Authors: Zhang Jingyu , Li Zhongliang , Li Jialong , He Yalin , Tong Haojie , Li Shuang , Chai Zhanli , Lan Kun
Published: August 2023

As an encouraging photocatalyst, crystalline carbon nitride (CCN) exhibits unsatisfactory photocatalytic activity and stability due to its rapid recombination of photo-generative carriers. Herein, high-crystalline g-C3N4 was prepared, including CCN obtained in KCl (K-CCN), LiCl-KCl mixture (Li/K-CCN), and LiCl-NaCl-KCl mixture (Li/Na/K-CCN), via the molten salt strategy using pre-prepared bulk carbon nitride (BCN) as a precursor. The obtained BCN sample was formed by heptazine-based units, which convert into triazine-based units for K-CCN. Heptazine and triazine are two isotypes that co-exist in the Li/K-CCN and Li/Na/K-CCN samples. Compared with BCN and other CCN samples, the as-prepared Li/Na/K-CCN sample exhibited the optimal photocatalytic hydrogen evolution rates (3.38 mmol·g−1·h−1 under simulated sunlight and 2.25 mmol·g−1·h−1 under visible light) and the highest apparent quantum yield (10.97%). The improved photocatalytic performance of the Li/Na/K-CCN sample is mainly attributed to the construction of type-II heterojunction and the institution of the built-in electric field between triazine-based CCN and heptazine-based BCN. This work provides a new strategy for the structural optimization and heterostructure construction of crystalline carbon nitride photocatalysts.
A Review on Progress, Challenges, and Prospects of Material Jetting of Copper and Tungsten
Authors: Doddapaneni V. Vinay K. , Lee Kijoon , Aysal Havva Eda , Paul Brian K. , Pasebani Somayeh , Sierros Konstantinos A. , Okwudire Chinedum E. , Chang Chih-hung
Published: August 2023

Copper (Cu) and tungsten (W) possess exceptional electrical and thermal conductivity properties, making them suitable candidates for applications such as interconnects and thermal conductivity enhancements. Solution-based additive manufacturing (SBAM) offers unique advantages, including patterning capabilities, cost-effectiveness, and scalability among the various methods for manufacturing Cu and W-based films and structures. In particular, SBAM material jetting techniques, such as inkjet printing (IJP), direct ink writing (DIW), and aerosol jet printing (AJP), present a promising approach for design freedom, low material wastes, and versatility as either stand-alone printers or integrated with powder bed-based metal additive manufacturing (MAM). Thus, this review summarizes recent advancements in solution-processed Cu and W, focusing on IJP, DIW, and AJP techniques. The discussion encompasses general aspects, current status, challenges, and recent research highlights. Furthermore, this paper addresses integrating material jetting techniques with powder bed-based MAM to fabricate functional alloys and multi-material structures. Finally, the factors influencing large-scale fabrication and potential prospects in this area are explored.
South African Consumers’ Knowledge, Opinions and Awareness of Whole Grains and Their Health Benefits: A Cross-Sectional Online Survey
Authors: Taylor John R. N. , Rehm Colin D. , de Kock Henriëtte L. , Donoghue Suné , Johnson Andrew , Thompson Chanelle , Berezhnaya Yulia
Published: August 2023

Evidence indicates that whole-grain food consumption reduces the risk of cardiovascular disease, type-2 diabetes, and some cancers. Increasing whole-grain consumption in developing countries is likely to significantly benefit the health of the population. However, there is very limited information on consumer whole-grain knowledge, attitudes, and behaviors in developing countries. An online cross-sectional survey was conducted among 1000 South African consumers with sufficient income to make food purchase choices and who were generally representative in terms of gender, age, and ethnicity. Most respondents (64%) were confident of their whole-grain knowledge. However, 60% of all participants selected incorrect definitions of whole grains. Whilst most correctly identified common cereals as whole grains, at most 50% of participants correctly identified common whole-grain foods. Also, whilst most (67%) thought that they were consuming enough whole grains, the majority (62%) underestimated the recommended level of consumption. Furthermore, respondent knowledge regarding whole-grain food attributes and the health benefits of whole-grain consumption was generally poor. Clearly, consumer-focused strategies are needed in developing countries to increase whole-grain food consumption to help the broader population achieve a healthy and sustainable diet. Actions proposed include: simple-to-understand information on whole-grain content relative to recommendations on food product labels, the provision of whole-grain foods in school nutrition schemes, and coordinated social and behavior change communication initiatives.
Insights into Nutritional Strategies in Psoriasis
Authors: Constantin Carolina , Surcel Mihaela , Munteanu Adriana , Neagu Monica
Published: August 2023

Psoriasis, an autoimmune chronic inflammatory skin condition, has a high incidence in the general population, reaching 2–4%. Its pathogenesis involves an interplay of genetic factors, immune disturbances, and environmental factors. Within the environmental factors that aid the appearance of this autoimmune skin disease, the Western lifestyle and overall diet play important roles in the steady growth in psoriasis prevalence. Furthermore, psoriasis is associated with comorbidities such as psoriatic arthritis, cardiovascular disease, metabolic syndrome, and obesity. Accumulating evidence suggests that obesity is an important risk factor for psoriasis. Moreover, obesity aggravates established psoriasis, and a reduction in the body mass index can improve the clinical outcomes of psoriasis and increase the efficacy of standard psoriasis therapies. The possible connection between this autoimmune disease and obesity relies on the fact that white adipose tissue is an essential endocrine organ that secretes an array of immune mediators and inflammatory and metabolic factors with pro-inflammatory action. Thus, immune-mediated mechanisms in both psoriasis and obesity conditions are common factors. This paper describes the factors that link obesity with skin autoimmune disease and highlights the importance of the stimulatory or regulatory effects of nutrients and food in psoriasis and the possible improvement of psoriasis through nutritional strategies.
Tamarind Seed Polysaccharide Hydrolysate Ameliorates Dextran Sulfate Sodium-Induced Ulcerative Colitis via Regulating the Gut Microbiota
Authors: Jiang Kangjia , Wang Duo , Su Le , Liu Xinli , Yue Qiulin , Zhang Song , Zhao Lin
Published: August 2023

(1) Background: Ulcerative colitis (UC) is a disease caused by noninfectious chronic inflammation characterized by varying degrees of inflammation affecting the colon or its entire mucosal surface. Current therapeutic strategies rely on the suppression of the immune response, which is effective, but can have detrimental effects. Recently, different plant polysaccharides and their degradation products have received increasing attention due to their prominent biological activities. The aim of this research was to evaluate the mitigation of inflammation exhibited by tamarind seed polysaccharide hydrolysate (TSPH) ingestion in colitis mice. (2) Methods: TSPH was obtained from the hydrolysis of tamarind seed polysaccharide (TSP) by trifluoroacetic acid (TFA). The structure and physical properties of TSPH were characterized by ultraviolet spectroscopy (UV), thin-layer chromatography (TLC), fourier transform infrared spectroscopy (FT-IR), and High-Performance Liquid Chromatography and Electrospray Ionization Mass Spectrometry (HPLC–ESI/MS) analysis. Then, the alleviative effects of the action of TSPH on 2.5% dextran sodium sulfate (DSS)-induced colitis mice were investigated. (3) Results: TSPH restored pathological lesions in the colon and inhibited the over-secretion of pro-inflammatory cytokines in UC mice. The relative expression level of mRNA for colonic tight junction proteins was increased. These findings suggested that TSPH could reduce inflammation in the colon. Additionally, the structure of the gut microbiota was also altered, with beneficial bacteria, including Prevotella and Blautia, significantly enriched by TSPH. Moreover, the richness of Blautia was positively correlated with acetic acid. (4) Conclusions: In conclusion, TSPH suppressed colonic inflammation, alleviated imbalances in the intestinal flora and regulated bacterial metabolites. Thus, this also implies that TSPH has the potential to be a functional food against colitis.
Dendritic Structures Functionalized with Boron Clusters, in Particular Carboranes, and Their Biological Properties
Authors: Caminade Anne-Marie , Milewski Max , Hey-Hawkins Evamarie
Published: August 2023

The presence of a large number of boron atoms in boron clusters make them attractive tools for the treatment of cancer using boron neutron capture therapy (BNCT). Since the quantity of boron atoms present in the target cell directly affects the effectiveness of BNCT, the idea of gathering a high number of boron atoms in a single entity has emerged many years ago. In this perspective, using hyper-branched macromolecules such as dendrimers appears as an interesting solution. In this review, we will first present the synthesis of diverse dendritic entities (dendrimers, dendrons, and Janus dendrimers) that incorporate boron clusters, in particular carboranes, anywhere in their structure. Four parts of this review present the synthesis of dendrimers having boron clusters on the surface, or inside their structure, of dendrons and of Janus dendrimers, bearing boron clusters. Practically all these boronated dendritic structures were synthesized with the objective to study their biological properties, but in fact only a few of them have been tested against cancerous cells, and even a smaller number was tested in BNCT experiments. The biological experiments are discussed in the fifth part of this review. A good efficiency is generally observed with the boronated dendrimers, even in animal models, with an increase in their mean survival time (MST).
The Effects of Thermocycling on the Physical Properties and Biocompatibilities of Various CAD/CAM Restorative Materials
Authors: Kim Se-Young , Bae Han-Jin , Lee Hae-Hyoung , Lee Jong-Hyuk , Kim Yu-Jin , Choi Yu-Sung , Lee Jung-Hwan , Shin Soo-Yeon
Published: August 2023

The purpose of this study is to evaluate the changes in physical properties and biocompatibilities caused by thermocycling of CAD/CAM restorative materials (lithium disilicate, zirconia reinforced lithium silicate, polymer-infiltrated ceramic network, resin nanoceramic, highly translucent zirconia). A total of 225 specimens were prepared (12.0 × 10.0 × 1.5 mm) and divided into three groups subjected to water storage at 37 °C for 24 h (control group), 10,000 cycles in distilled water at 5–55 °C (first aged group), and 22,000 cycles in distilled water at 5–55 °C (second aged group) [(n= 15, each]). The nanoindentation hardness and Young’s modulus (nanoindenter), surface roughness (atomic force microscopy (AFM)), surface texture (scanning electron microscopy (FE-SEM)), elemental concentration (energy dispersive spectroscopy (EDS)) and contact angle were evaluated. The morphology, proliferation and adhesion of cultured human gingival fibroblasts (HGFs) were analyzed. The data were analyzed using one-way ANOVA and Tukey’s test (p < 0.05). The results showed that the nanoindentation hardness and Young’s modulus were decreased after thermocycling aging. Cell viability and proliferation of the material decreased with aging except for the highly translucent zirconia. Zirconia-reinforced lithium silicate exhibited significantly lower cell viability compared to other materials. The surface roughnesses of all groups increased with aging. Cell viability and Cell adhesion were influenced by various factors, including the surface chemical composition, hydrophilicity, surface roughness, and topography.
Multitemporal Land Use and Cover Analysis Coupled with Climatic Change Scenarios to Protect the Endangered Taxon Asphodelus bento-rainhae subsp. bento-rainhae
Authors: Almeida Alice Maria , Delgado Fernanda , Roque Natália , Ribeiro Maria Margarida , Fernandez Paulo
Published: August 2023

Climate change and land use and land cover (LULC) change are impacting the species’ geographic distribution, causing range shifts and reducing suitable habitats. Asphodelus bento-rainhae subsp. bento-rainhae (AbR) is an endangered endemic plant restricted to Serra da Gardunha (Portugal), and knowledge of those changes will help to design conservation measures. MaxEnt was used to model AbR’s current distribution and project it into the future, 2050, using the Shared Socioeconomic Pathway SSP3-7. The Portuguese LULC maps from 1951–1980, 1995, 2007, and 2018 were used to assess and quantify LULC changes over time. The results showed that the AbR current predicted distribution matches its actual known distribution, which will not be affected by future predicted climate change. The significant LULC changes were observed during the study periods 1951–1980 to 2018, particularly between 1951–1980 and 1995. Scrubland and Agriculture decreased by 5% and 2.5%, respectively, and Forests increased by 4% in the study area. In the occurrence area, Agriculture increased, and Forests decreased between 1980 and 2018, due to Orchard expansion (34%) and declines in Chestnut (16.9%) and Pine (11%) areas, respectively. The use of species distribution models and the LULC change analysis contributed to understanding current and future species distribution. The LULC changes will have a significant impact on future species distribution. To prevent the extinction of this endemic species in the future, it is crucial to implement conservation measures, namely species monitoring, replantation, and germplasm conservation, in addition to guidelines for habitat conservation.
Evaluation of Polycaprolactone Applicability for Manufacturing High-Performance Cellulose Nanocrystal Cement Composites
Authors: Lee Hyungjoo , Kim Woosuk
Published: August 2023

This experimental study examined the aplication effect of polycaprolactone (PCL), an organic resin material with excellent elasticity and ductility, on improving the mechanical performance of cellulose nanocrystal (CNC) cement composites. PCL was compared according to its shape, and in the case of Granules, which is the basic shape, interfacial adhesion with cement was not achieved, so a dichloromethane (DCM) solution was used to dissolve and use the Granules form. As a method for bonding PCL to the CNC surface, the CNC surface was modified using 3-aminopropyltriethoxysilane (APTES), and surface silylation was confirmed through Fourier transform infrared spectroscopy (FT-IR) analysis. In order to evaluate the dispersibility according to the application of PCL to the modified CNC, particle size analysis (PSA) and zeta potential analysis were performed according to the PCL mixing ratio. Through the PSA and zeta potential values, the highest dispersion stability was shown at 1 vol.%, the cohesive force of CNC was low, and the dispersion stability was high according to the application of PCL. According to the results of the dispersion stability evaluation, the degree of hydration of the dissolved PCL 1 vol.%, CNC-only specimens, and plain specimens were analyzed. CNC acted as a water channel inside the cement to accelerate hydration in the non-hydrated area, resulting in an increased degree of hydration. However, the incorporation of PCL showed a low degree of hydration, and the analysis of strength characteristics also showed a decrease of approximately 27% compared with that of plain specimens. This was because the bonding with SiO2 was not smooth owing to the solvent, thus affecting internal hydration. In order to investigate the effect of the PCL shape, the compressive and flexural strength characteristics were compared using PCL powder as an additional parameter. The compressive strength and flexural strength were improved by about 54% and 26%, respectively, in the PCL powder 15 wt% specimen compared to the general specimen. Scanning electron microscopy (SEM) analysis confirmed that the filler effect, which made the microporous structure denser, affects the mechanical performance improvement.
Diurnal Variation Characteristics of Summer Precipitation and Related Statistical Analysis in the Ili Region, Xinjiang, Northwest China
Authors: Li Zhiyi , Abulikemu Abuduwaili , Zhu Kefeng , Mamtimin Ali , Zeng Yong , Li Jiangang , Abulimiti Aerzuna , Kadier Zulipina , Abuduaini Abidan , Li Chunyang , Sun Qi
Published: August 2023

The diurnal variation characteristics and basic statistical features of summer precipitation (from June to August) in the Ili region from 2015 to 2019 were investigated based on 4 km resolution Weather Research and Forecasting model simulation data from Nanjing University (WRF_NJU). The results show that the overall diurnal variation characteristics of precipitation (DVCP) reflected by the WRF_NJU data were consistent with respect to the observations and reanalysis data. The total precipitation pattern exhibited high (low) values on the east (west), with higher (lower) values over the mountainous (valley) area. Hourly precipitation amount (PA), precipitation frequency (PF), and precipitation intensity (PI) show similar diurnal variation characteristics, with peaks occurring at around 1700 LST in the mountainous area and around 2000 LST in valleys. Furthermore, moderate to intense precipitation contributes up to 87.88% of the total precipitation. The peaks in the mountainous area occur earlier than the valleys, while the peaks in western part of the valleys occur earlier than the eastern part. The PA peaks over the valleys and slopes occurred from the evening to early morning and from the afternoon to evening, respectively. In addition, the rotated empirical orthogonal function (REOF) analysis implied that the DVCP exhibits distinct differences between mountainous and valleys, and peak precipitation occurs during the evening in basin– and wedge–shaped areas, while the mountain peaks and foothill regions exhibit semi–diurnal variation characteristics. Among several basic meteorological factors, the vertical velocity (VV) and water vapor mixing ratio (WVMR) provided major contributions to the DVCP in both areas with high and low coefficients of variation, and the WVMR (VV) probably played a more significant role in mountainous (valleys) areas.
Cloud Shadow Detection via Ray Casting with Probability Analysis Refinement Using Sentinel-2 Satellite Data
Authors: Layton Jeffrey C. , Wecker Lakin , Runions Adam , Samavati Faramarz F.
Published: August 2023

Analysis of aerial images provided by satellites enables continuous monitoring and is a central component of many applications, including precision farming. Nonetheless, this analysis is often impeded by the presence of clouds and cloud shadows, which obscure the underlying region of interest and introduce incorrect values that bias analysis. In this paper, we outline a method for cloud shadow detection, and demonstrate our method using Canadian farmland data obtained from the Sentinel-2 satellite. Our approach builds on other object-based cloud and cloud shadow detection methods that generate preliminary shadow candidate masks which are refined by matching clouds to their respective shadows. We improve on these components by using ray-casting and inverse texture mapping methods to quickly identify cloud shadows, allowing for the immediate removal of false positives during image processing. Leveraging our ray-casting-based approach, we further improve our results by implementing a probability analysis based on the cloud probability layer provided by the Sentinel-2 satellite to account for missed shadow pixels. An evaluation of our method using the average producer (82.82%) and user accuracy (75.55%) both show a marked improvement over the performance of other object-based methods. Methodologically, our work demonstrates how incorporating probability analysis as a post-processing step can improve the generation of shadow masks.
Land-Use Mapping with Multi-Temporal Sentinel Images Based on Google Earth Engine in Southern Xinjiang Uygur Autonomous Region, China
Authors: Chen Riqiang , Yang Hao , Yang Guijun , Liu Yang , Zhang Chengjian , Long Huiling , Xu Haifeng , Meng Yang , Feng Haikuan
Published: August 2023

Land-use maps are thematic materials reflecting the current situation, geographical diversity, and classification of land use and are an important scientific foundation that can assist decision-makers in adjusting land-use structures, agricultural zoning, regional planning, and territorial improvement according to local conditions. Spectral reflectance and radar signatures of time series are important in distinguishing land-use types. However, their impact on the accuracy of land-use mapping and decision making remains unclear. Also, the many spatial and temporal heterogeneous landscapes in southern Xinjiang limit the accuracy of existing land-use classification products. Therefore, our objective herein is to develop reliable land-use products for the highly heterogeneous environment of the southern Xinjiang Uygur Autonomous Region using the freely available public Sentinel image datasets. Specifically, to determine the effect of temporal features on classification, several classification scenarios with different temporal features were developed using multi-temporal Sentinel-1, Sentinel-2, and terrain data in order to assess the importance, contribution, and impact of different temporal features (spectral and radar) on land-use classification models and determine the optimal time for land-use classification. Furthermore, to determine the optimal method and parameters suitable for local land-use classification research, we evaluated and compared the performance of three decision-tree-related classifiers (classification and regression tree, random forest, and gradient tree boost) with respect to classifying land use. Yielding the highest average overall accuracy (95%), kappa (95%), and F1 score (98%), we determined that the gradient tree boost model was the most suitable for land-use classification. Of the four individual periods, the image features in autumn (25 September to 5 November) were the most accurate for all three classifiers in relation to identifying land-use classes. The results also show that the inclusion of multi-temporal image features consistently improves the classification of land-use products, with pre-summer (28 May–20 June) images providing the most significant improvement (the average OA, kappa, and F1 score of all the classifiers were improved by 6%, 7%, and 3%, respectively) and fall images the least (the average OA, kappa, and F1 score of all the classifiers were improved by 2%, 3%, and 2%, respectively). Overall, these analyses of how classifiers and image features affect land-use maps provide a reference for similar land-use classifications in highly heterogeneous areas. Moreover, these products are designed to describe the highly heterogeneous environments in the study area, for example, identifying pear trees that affect local economic development, and allow for the accurate mapping of alpine wetlands in the northwest.
Aboveground Biomass Dynamics of a Coastal Wetland Ecosystem Driven by Land Use/Land Cover Transformation
Authors: Wu Wenli , Zhang Jiahua , Bai Yun , Zhang Sha , Yang Shanshan , Henchiri Malak , Seka Ayalkibet Mekonnen , Nanzad Lkhagvadorj
Published: August 2023

Accurately estimating aboveground biomass (AGB) is essential for assessing the ecological functions of coastal wetlands, and AGB of coastal wetlands is affected by Land use/land cover (LULC) types of conversion. To address this issue, in the current study, we used the Boreal Ecosystem Productivity Simulator (BEPS) model to simulate the AGB of the Yellow River Delta during 2000–2015. Based on the LULC types transform, we analyzed the spatiotemporal dynamics of the AGB simulation results and their relationship with the human-nature driving process. At the same time, combined with the actual situation of LULC transformation in the Yellow River Delta, a new driving process (Replace) is introduced. The results show that from 2000 to 2015, 755 km2 of natural wetlands in the Yellow River Delta were converted into constructed wetlands, and AGB increased by 386,121 Mg. Both single and multiple driving processes contributed to the decrease in AGB, with 72.6% of the increase in AGB associated with single artificial (such as Restore) or natural (such as Accretion) driving processes and 27.4% of the increase in AGB associated with multiple driving processes. Naturally driven processes bring much more AGB gain than loss, and human-driven processes bring the largest AGB gain. LULC conversion brought on by anthropogenic and natural driving processes has a large impact on AGB in coastal wetlands, and exploring this impact has a significant role in planning coastal wetland land use and protecting blue carbon ecosystems.
The Effect of Esports Content Attributes on Viewing Flow and Well-Being: A Focus on the Moderating Effect of Esports Involvement
Authors: Yin Chaoyu , Huang Yihan , Kim Daehwan , Kim Kyungun
Published: August 2023

Despite being recognized as a global entertainment phenomenon, the nature of esports has been a subject of ongoing debate due to its content attributes and the controversial impact it has on individuals’ physical and mental well-being. We contend that the fundamental source of contention lies within the inherent content attributes of esports. Drawing on uses and gratification theory (UG) and cognitive appraisal theory, the purpose of the current study was to explore how esports content attributes and viewers’ individual characteristics (esports involvement) influence the viewer’s experience (flow experience) and well-being (happiness and vitality). The results of a latent moderated structural equations (LMS) modeling analysis using a total of 539 viewers revealed that entertainment, reliability, and diversity significantly influenced flow experience, which in turn influenced viewers’ happiness and vitality. Esports involvement was found to have moderating effects on the relationship between reliability and usefulness attributes and flow experience. The findings of this research provide important contributions to the literature and have implications for sport marketing managers.
Biochar with Organic and Inorganic Fertilizers Improves Defenses, Nitrogen Use Efficiency, and Yield of Maize Plants Subjected to Water Deficit in an Alkaline Soil
Authors: El-Syed Norhan M. M. , M. Helmy Ayman , Fouda Sara E. E. , M. Nabil Mohamed , Abdullah Tamer A. , K. Alhag Sadeq , Al-Shuraym Laila A. , Al Syaad Khalid M. , Ayyoub Anam , Mahmood Mohsin , S. Elrys Ahmed
Published: August 2023

Nutrient management practices, such as optimum fertilizer addition rate and co-addition of inorganic fertilizers and organic amendments (compost and biochar), were investigated to enhance crop production and nitrogen (N) use efficiency. However, how these practices improve the defense system, N use efficiency, yield quantity and quality, and physio-biochemical constituents of maize (Zea mays L.) plants grown on an alkaline soil under different irrigation levels (well-watered conditions, mild drought, and severe drought) remains unclear. A two-year field trial was carried out in a split–split plot with a randomized complete block design with three irrigation levels (100% evapotranspiration (ET), 80% ET, and 60% ET) as the main plots, two amendments (5 Mg ha–1 biochar or compost) as subplots, and three regimes of inorganic fertilization (119-16-69, 179-24-99, and 238-31-138 kg N-phosphorus (P)-potassium (K) ha−1) as sub-subplots. We found that maize yield, oil, starch, protein, carbohydrates, and NPK uptake significantly decreased with increasing drought levels, but catalase, peroxidase, superoxide dismutase, and proline contents significantly increased. The addition of organic amendments (compost or biochar) with inorganic fertilizers was more effective in enhancing the above attributes than inorganic fertilizers alone, but these attributes were positively related to inorganic fertilizer rates. The treatment of compost or biochar plus 238-31-138 kg N-P-K ha−1 was the best treatment. The agronomic efficiency of applied fertilizer N (NAE) significantly decreased with increasing drought levels by 28.4–34.7%. The addition of biochar with inorganic fertilizers significantly enhanced NAE by 11.6% compared to inorganic fertilizers alone. Comparing the effect of inorganic fertilizer rates across all irrigation levels, the treatment of 119-16-69 kg N-P-K ha−1 gave the highest NAE. Thus, the addition of optimum NPK fertilizer rate with biochar or compost is suitable to enhance the yield quantity and quality of maize plants grown on alkaline soils by improving its defensive system and N use efficiency, especially under the expected increase in aridity response to climate change.
Sustainability as Strategic Differentiator: The Promise and the Problems of Using Chicle vs. Petro-Chemicals in Chewing Gum
Authors: Paul Karen
Published: August 2023

Chewing gum as a commercial product was traditionally based on chicle, mainly harvested by indigenous people from trees in the tropical forest of southeastern Mexico. Chicle gum base has now been replaced by a petro-chemical gum base by the major manufacturers. However, several smaller companies are again attempting to market chewing gum using a chicle gum base. The question raised here is, will the differentiation provided by chicle gum—being natural, organic, and “plastic-free”—provide sufficient differentiation for meaningful competition against the less expensive brands using a petro-chemical gum base? This case provides an interesting application of Michael Porter’s strategy model in which differentiation and value are competing strategies.
Context Analysis for Transformative Change in the Ceramic Industry
Authors: Khalil Ahmed M. E. , Velenturf Anne P. M. , Ahmadinia Masoud , Zhang Shaowei
Published: August 2023

Foundation industries are under increasing pressure to transform for sustainable development. Ceramics play a key role within foundation industries as a necessary material for building manufacturing facilities. Therefore, transforming the ceramic industry could support changes across other foundation industries as well, making it one of the most important industries to transform. Given the limited finances, staff time, and other resources to support transformative change, this study aims to identify a set of key intervention points to enable transformative change in the ceramic industry in the United Kingdom. A desk-based study, reviewing written industry, government, and scientific materials available in the public domain, was carried out to identify initial key intervention points for transformative change. The PESTLE approach was used to analyse macro factors in political, environmental, social, technological, legal, and economic domains in order to understand how the context enables or constrains change in the ceramic industry. A SWOT analysis was conducted to further consolidate the findings. Our analysis detected over 50 transformative change drivers and barriers and showed that decarbonisation and energy-saving strategies were the main drivers for transforming the UK ceramic industry. On the other hand, foreign government policy and legislation, trade barriers, skills shortages, and costly alternative energy sources were among the major barriers.
One-Step Electrosynthesis of Bifunctional NiCu Nanosheets on Iron Foam for Remarkably Enhanced Alkaline Water Splitting
Authors: Liu Zhenwei , Wang Qiang , Kong Qingxiang , Tong Xiaoning , Wu Song , Zong Naixuan , Xu Ruidong , Yang Linjing
Published: August 2023

Electrocatalytic water splitting for hydrogen production driven by renewable electricity offers a promising way of achieving energy sustainability, but the design of highly efficient and cost-effective electrocatalysts is regarded as a bottleneck. Herein, a bifunctional microflowers NiCu is successfully deposited on an iron foam (IF) electrode via one-step electrolysis of spend cupronickel (SCN). Unexpectedly, the designed IF-supported NiCu (NiCu/IF) electrocatalysts exhibit excellent catalytic performance for oxygen evolution reactions (OER) and hydrogen evolution reactions (HER) in 1 M KOH. Only 98 and 267 mV are required to drive a current density of 10 mA cm−2 for HER and OER, respectively. Importantly, the self-supported NiCu/IF electrode requires a low cell voltage of 1.57 V to achieve 10 mA cm−2 of alkaline overall water splitting with extremely high stability. With the introduction of a glycerol oxidation reaction (GOR), the HER performance is further remarkably enhanced with an extremely low cell voltage of 1.29 V at 10 mA cem−2, highlighting an attractive energy-efficient hydrogen production coupled with biomass conversion process. This study reports a novel synthesis strategy for low-cost and high-performance Ni-based nanostructure catalysts using SCN as precursors, which is of vital significance for green hydrogen production and waste recycling.