bluuebunny/crossref_metadata_2025 huggingface dataset:
Poloxamer 407 Based Gel Formulations for Transungual Delivery of Hydrophobic Drugs: Selection and Optimization of Potential Additives
Authors: Ullah Kamran Hidayat , Raza Faisal , Munawar Syed Mohsin , Sohail Muhammad , Zafar Hajra , Zafar Mazhar Iqbal , Ur-Rehman Tofeeq
Published: October 2021

The current study aimed to develop poloxamer 407 (P407) gel for transungual delivery of antifungal hydrophobic drugs with sufficient gel strength and drug loading. Gel strength and drug loading of P407 gel was improved by use of functional additives. Hydration enhancement effect was used to select optimum nail penetration enhancer. Face-centered central composite design (FCCCD) was used to observe the effect of the selected penetration enhancer (thioglycolic acid (TGA)) and cosolvent (ethanol) on gelation behavior to develop formulation with enough loading of hydrophobic drug, i.e., terbinafine HCl (TBN), and its permeation across the nail plate without compromising on gel strength. It was observed that increasing concentration of P407 and TGA significantly reduced gelation temperature and enhanced the gel strength of P407 gel and can be used to improve P407 gel strength. Under the scanning electron microscope, the significant effect of TGA as an ungual penetration enhancer was observed on the morphology of the nail plate. Optimized P407 gel prepared with modified cold method showed a gelation temperature of 8.7 ± 0.16 °C, gel strength of 122 ± 7.5 s and drug loading of 1.2% w/w, which was four times more than the drug loading in the gels prepared with conventional cold method. Rheological behavior was pseudoplastic with 47.75 ± 3.48% of gel erosion after 12 washings and 67.21 ± 2.16% of drug release after 12 h. A cumulative amount of TBN permeated from P407 gel with and without PE after 24 h was 27.30 ± 4.18 and 16.69 ± 2.31 µg/cm2, respectively. Thioglycolic acid can be used as a nail penetration enhancer without the chemical modification or addition of extra additives while retaining the gel strength. Water miscible cosolvents with moderate evaporability such as ethanol, can be incorporated to P407 gel by minor modification in method of preparation to load the required dose of hydrophobic drugs. Developed P407 gel formulation with sufficient gel strength and drug loading will be a promising carrier for transungual delivery of hydrophobic antifungal agents.
Fabrication of Novel and Potential Selective 4-Cyanophenol Chemical Sensor Probe Based on Cu-Doped Gd2O3 Nanofiber Materials Modified PEDOT:PSS Polymer Mixtures with Au/µ-Chip for Effective Monitoring of Environmental Contaminants from Various Water Samples
Authors: Rahman Mohammed Muzibur , Alfaifi S. Y.
Published: October 2021

Herein, a novel copper-doped gadolinium oxide (Cu-doped Gd2O3; CGO) nanofiber was synthesized by a simple solution method in the basic phase and successfully characterized. We have used Fourier Transform Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), Field Emission Scanning Electron Microscope (FESEM) and Energy-Dispersive Spectroscopy (EDS) techniques for characterization of the CGO nanofiber. The CGO nanofiber was used later to modify Au-coated μ-Chips with poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) polymer mixtures (coating binder) to selectively detect 4-cyanophenol (4-CP) in an aqueous medium. Notable sensing performance was achieved with excellent sensitivity (2.4214 µAµM−1 cm−2), fast response time (~12 s), wide linear dynamic range (LDR = 1.0 nM–1.0 mM: R2 = 0.9992), ultra-low detection limit (LoD; 1.3 ± 0.1 pM at S/N = 3), limit of quantification (LoQ; 4.33 pM), and excellent reproducibility and repeatability for CGO/Au/μ-Chip sensor. This CGO modified Au/μ-chip was further applied with appropriate quantification and determination results in real environmental sample analyses.
Efficient Synthesis and Characterization of Polyaniline@Aluminium–Succinate Metal-Organic Frameworks Nanocomposite and Its Application for Zn(II) Ion Sensing
Authors: Alsafrani Amjad E. , Adeosun Waheed A. , Marwani Hadi M. , Khan Imran , Jawaid Mohammad , Asiri Abdullah M. , Khan Anish
Published: October 2021

A new class of conductive metal-organic framework (MOF), polyaniline- aluminum succinate (PANI@Al-SA) nanocomposite was prepared by oxidative polymerization of aniline monomer using potassium persulfate as an oxidant. Several analytical techniques such as FTIR, FE-SEM, EDX, XRD, XPS and TGA-DTA were utilized to characterize the obtained MOFs nanocomposite. DC electrical conductivity of polymer-MOFs was determined by four probe method. A bare glassy carbon electrode (GCE) was modified by nafion/PANI@Al-SA, and examined for Zn (II) ion detection. Modified electrode showed improved efficiency by 91.9%. The modified electrode (PANI@Al-SA/nafion/GCE) exhibited good catalytic property and highly selectivity towards Zn(II) ion. A linear dynamic range of 2.8–228.6 µM was obtained with detection limit of LOD 0.59 µM and excellent sensitivity of 7.14 µA µM−1 cm−2. The designed procedure for Zn (II) ion detection in real sample exhibited good stability in terms of repeatability, reproducibility and not affected by likely interferents. Therefore, the developed procedure is promising for quantification of Zn(II) ion in real samples.
Rosin-Based Epoxy Vitrimers with Dynamic Boronic Ester Bonds
Authors: Zeng Yanning , Li Jiawei , Liu Shuxin , Yang Bin
Published: October 2021

Rosin is an abundantly available natural product. In this paper, for the first time, a rosin derivative is employed as the main monomer for preparation of epoxy vitrimers to improve the mechanical properties of vitrimers. Novel epoxy vitrimer networks with dynamic reversible covalent boronic ester bonds are constructed by a reaction between thiols in 2,2′–(1,4–phenylene)–bis (4–mercaptan–1,3,2–dioxaborolane) (BDB) as a curing agent and epoxy groups in the rosin derivative. The rosin-based epoxy vitrimer networks are fully characterized by Fourier transform infrared spectroscopy (FTIR), an equilibrium swelling experiment, and dynamic mechanical analysis (DMA). The obtained rosin-based epoxy vitrimers possess superior thermostability and good mechanical properties. Due to transesterification of boronic ester bonds, rosin epoxy vitrimer network topologies can be altered, giving welding, recycle, self-healing, and shape memory abilities to the fabricated polymer. Besides, the effects of treating time and temperature on welding capability is investigated, and it is found that the welding efficiency of the 20% C-FPAE sample is >93% after treatment for 12 h at 160 °C. Moreover, through a hot press, the pulverized samples of 20% C-FPAE can be reshaped several times and most mechanical properties are restored after reprocessing at 200 °C for 60 min. Finally, chemical degradation is researched for the rosin-based epoxy vitrimers.
Prediction of Geopolymer Concrete Compressive Strength Using Novel Machine Learning Algorithms
Authors: Ahmad Ayaz , Ahmad Waqas , Chaiyasarn Krisada , Ostrowski Krzysztof Adam , Aslam Fahid , Zajdel Paulina , Joyklad Panuwat
Published: October 2021

The innovation of geopolymer concrete (GPC) plays a vital role not only in reducing the environmental threat but also as an exceptional material for sustainable development. The application of supervised machine learning (ML) algorithms to forecast the mechanical properties of concrete also has a significant role in developing the innovative environment in the field of civil engineering. This study was based on the use of the artificial neural network (ANN), boosting, and AdaBoost ML approaches, based on the python coding to predict the compressive strength (CS) of high calcium fly-ash-based GPC. The performance comparison of both the employed techniques in terms of prediction reveals that the ensemble ML approaches, AdaBoost, and boosting were more effective than the individual ML technique (ANN). The boosting indicates the highest value of R2 equals 0.96, and AdaBoost gives 0.93, while the ANN model was less accurate, indicating the coefficient of determination value equals 0.87. The lesser values of the errors, MAE, MSE, and RMSE of the boosting technique give 1.69 MPa, 4.16 MPa, and 2.04 MPa, respectively, indicating the high accuracy of the boosting algorithm. However, the statistical check of the errors (MAE, MSE, RMSE) and k-fold cross-validation method confirms the high precision of the boosting technique. In addition, the sensitivity analysis was also introduced to evaluate the contribution level of the input parameters towards the prediction of CS of GPC. The better accuracy can be achieved by incorporating other ensemble ML techniques such as AdaBoost, bagging, and gradient boosting.
Simulation of Neutron/Self-Emitted Gamma Attenuation and Effects of Silane Surface Treatment on Mechanical and Wear Resistance Properties of Sm2O3/UHMWPE Composites
Authors: Toyen Donruedee , Paopun Yupadee , Changjan Dararat , Wimolmala Ekachai , Mahathanabodee Sithipong , Pianpanit Theerasarn , Anekratmontree Thitisorn , Saenboonruang Kiadtisak
Published: October 2021

This work reports on the simulated neutron and self-emitted gamma attenuation of ultra-high-molecular-weight polyethylene (UHMWPE) composites containing varying Sm2O3 contents in the range 0–50 wt.%, using a simulation code, namely MCNP-PHITS. The neutron energy investigated was 0.025 eV (thermal neutrons), and the gamma energies were 0.334, 0.712, and 0.737 MeV. The results indicated that the abilities to attenuate thermal neutrons and gamma rays were noticeably enhanced with the addition of Sm2O3, as seen by the increases in µm and µ, and the decrease in HVL. By comparing the simulated neutron-shielding results from this work with those from a commercial 5%-borated PE, the recommended Sm2O3 content that attenuated thermal neutrons with equal efficiency to the commercial product was 11–13 wt.%. Furthermore, to practically improve surface compatibility between Sm2O3 and the UHMWPE matrix and, subsequently, the overall wear/mechanical properties of the composites, a silane coupling agent (KBE903) was used to treat the surfaces of Sm2O3 particles prior to the preparation of the Sm2O3/UHMWPE composites. The experimental results showed that the treatment of Sm2O3 particles with 5–10 pph KBE903 led to greater enhancements in the wear resistance and mechanical properties of the 25 wt.% Sm2O3/UHMWPE composites, evidenced by lower specific wear rates and lower coefficients of friction, as well as higher tensile strength, elongation at break, and surface hardness, compared to those without surface treatment and those treated with 20 pph KBE903. In conclusion, the overall results suggested that the addition of Sm2O3 in the UHMWPE composites enhanced abilities to attenuate not only thermal neutrons but also gamma rays emitted after the neutron absorption by Sm, while the silane surface treatment of Sm2O3, using KBE903, considerably improved the processability, wear resistance, and strength of the composites.
Optimal Design and Testing of a Thermoplastic Pressurized Passenger Door Manufactured Using Thermoforming
Authors: Růžek Roman , Krena Josef , Doubrava Radek , Tkadlec Josef , Kadlec Martin , Bělský Petr
Published: October 2021

The present paper documents and discusses research work associated with a newly designed passenger door structure demonstrator. The composite structure was manufactured from carbon-fiber-reinforced thermoplastic resin. A composite frame with a variable cross-section was designed, optimized, and fabricated using thermoforming technology. Both numerical simulations and experiments supported structural verification according to the damage tolerance philosophy; i.e., impact damage is presented. The Tsai-Wu and maximal stress criteria were used for damage analysis of the composite parts. Topological optimization of the metal hinges from the point of view of weight reduction was used. All expected parameters and proposed requirements of the mechanical properties were proved and completed. The door panel showed an expected numerically evaluated residual strength (ultimate structure load) as well as meeting airworthiness requirements. No impact damage propagation in the composite parts was observed during mechanical tests, even though visible impact damage was introduced into the structure. No significant difference between the numerical simulations and the experimentally measured total deformation was observed. Repeated deformation measurements during fatigue showed a nonlinear structure behavior. This can be attributed to the relaxation of thermoplastics.
Poly-ε-Caprolactone/Fibrin-Alginate Scaffold: A New Pro-Angiogenic Composite Biomaterial for the Treatment of Bone Defects
Authors: Ren Jiongyu , Kohli Nupur , Sharma Vaibhav , Shakouri Taleen , Keskin-Erdogan Zalike , Saifzadeh Siamak , Brierly Gary I. , Knowles Jonathan C. , Woodruff Maria A. , García-Gareta Elena
Published: October 2021

We hypothesized that a composite of 3D porous melt-electrowritten poly-ɛ-caprolactone (PCL) coated throughout with a porous and slowly biodegradable fibrin/alginate (FA) matrix would accelerate bone repair due to its angiogenic potential. Scanning electron microscopy showed that the open pore structure of the FA matrix was maintained in the PCL/FA composites. Fourier transform infrared spectroscopy and differential scanning calorimetry showed complete coverage of the PCL fibres by FA, and the PCL/FA crystallinity was decreased compared with PCL. In vitro cell work with osteoprogenitor cells showed that they preferentially bound to the FA component and proliferated on all scaffolds over 28 days. A chorioallantoic membrane assay showed more blood vessel infiltration into FA and PCL/FA compared with PCL, and a significantly higher number of bifurcation points for PCL/FA compared with both FA and PCL. Implantation into a rat cranial defect model followed by microcomputed tomography, histology, and immunohistochemistry after 4- and 12-weeks post operation showed fast early bone formation at week 4, with significantly higher bone formation for FA and PCL/FA compared with PCL. However, this phenomenon was not extrapolated to week 12. Therefore, for long-term bone regeneration, tuning of FA degradation to ensure syncing with new bone formation is likely necessary.
Hybrid and Synthetic FRP Composites under Different Strain Rates: A Review
Authors: Farokhi Nejad Ali , Bin Salim Mohamad Yusuf , Rahimian Koloor Seyed Saeid , Petrik Stanislav , Yahya Mohd Yazid , Abu Hassan Shukur , Mohd Shah Mohd Kamal
Published: October 2021

As a high-demand material, polymer matrix composites are being used in many advanced industrial applications. Due to ecological issues in the past decade, some attention has been paid to the use of natural fibers. However, using only natural fibers is not desirable for advanced applications. Therefore, hybridization of natural and synthetic fibers appears to be a good solution for the next generation of polymeric composite structures. Composite structures are normally made for various harsh operational conditions, and studies on loading rate and strain-dependency are essential in the design stage of the structures. This review aimed to highlight the different materials’ content of hybrid composites in the literature, while addressing the different methods of material characterization for various ranges of strain rates. In addition, this work covers the testing methods, possible failure, and damage mechanisms of hybrid and synthetic FRP composites. Some studies about different numerical models and analytical methods that are applicable for composite structures under different strain rates are described.
Frequency and Temperature-Dependent Space Charge Characteristics of a Solid Polymer under Unipolar Electrical Stresses of Different Waveforms
Authors: Ren Hanwen , Li Qingmin , Tanaka Yasuhiro , Miyake Hiroaki , Gao Haoyu , Wang Zhongdong
Published: October 2021

In this paper, we studied the space charge phenomena of a solid polymer under thermal and electrical stresses with different frequencies and waveforms. By analyzing the parameter selection method of a protection capacitor and resistor, the newly built pulsed electro-acoustic (PEA) system can be used for special electrical stresses under 500 Hz, based on which the charge phenomena are studied in detail under positive and negative DC and half-wave sine and rectangular wave voltages. Experimental results show that the charge accumulated in the polyimide polymer under DC conditions mainly comes from the grounded electrode side, and the amount of charge accumulated with electric field distortion becomes larger in a high-temperature environment. At room temperature, positive charges tend to accumulate in low-frequency conditions under positive rectangular wave voltages, while they easily appear under high-frequency situations of negative ones. In contrast, the maximum electric field distortion and charge accumulation under both half-wave sine voltages occur at 10 Hz. When the measurement temperature increases, the accumulated positive charge decreases, with a more negative charge appearing under rectangular wave voltages, while a more positive charge accumulates at different frequencies of half-wave sine voltages. Therefore, our study of the charge characteristics under different voltage and temperature conditions can provide a reference for applications in the corresponding environments.
Mode of Action of Condensed- and Gaseous-Phase Fire Retardation in Some Phosphorus-Modified Polymethyl Methacrylate- and Polystyrene-Based Bulk Polymers
Authors: Joseph Paul , Arun Malavika , Bigger Stephen , Guerrieri Maurice , Pospiech Doris , Harnisch Christina
Published: October 2021

The aspects of fire retardation in some phosphorus-modified polymethyl methacrylate (PMMA) and polystyrene (PSt) polymers are reported in the present paper. Both additive and reactive strategies were employed to obtain the desired level of loading of the phosphorus-bearing compound/moiety (2 wt.% of P in each case). Test samples were obtained using bulk polymerization. The modifying compounds contained the P-atom in various chemical environments, as well as in an oxidation state of either III or V. With a view to gain an understanding of the chemical constitution of the gaseous products formed from the thermal decomposition of liquid additives/reactives, these materials were subjected to GC/MS analysis, whereas the decomposition of solid additives was detailed using the pyrolysis-GC/MS technique. Other investigations included the use of: Inductively-coupled Plasma/Optical Emission Spectroscopy (ICP/OES), solid-state NMR and FT-IR spectroscopy. In the case of PMMA-based systems, it was found that the modifying phosphonate ester function, upon thermal cracking, produced ‘phosphorus’ acid species which initiated the charring process. In the case of solid additives, it is more likely that the resultant phosphorus- and/or oxygenated phosphorus-containing volatiles acted as flame inhibitors in the gaseous phase. With the PSt-based systems, a probable process involving the phosphorylation of the phenyl groups leading to crosslinking and char formation is feasible.
Enhancement of the Processability and Properties of Nylon 6 by Blending with Polyketone
Authors: Zhang Tao , Kang Ho-Jong
Published: October 2021

Polyketones (PKs) having strong hydrogen bonding properties and a chain extender are used as additives in the melt processing of nylon 6 (PA6). Their effect on the chain structure and properties of PA6 is studied to enhance the processability of PA6 in melt processing. The addition of the chain extender to PA6 increases the melt viscosity by forming branches on the backbone. The addition of PKs results in an additional increase in viscosity through the hydrogen bonding between N–H of PA6 and C=O of PK. The change in the N–H bond FT-IR peak of PA6 and the swelling data of the PA6/PK blend containing a chain extender, styrene maleic anhydride copolymer (ADR), suggest that incorporation of chain extender and PK in the melt processing of PA6 results in physical crosslinks through hydrogen bonding between the branched PA6 formed by the addition of chain extender and PK chains. This change in the chain structure of PA6 not only increases the melt strength of PA6 but also increases randomness resulting in decreased crystallinity.
Enhancing Impact Energy Absorption, Flexural and Crash Performance Properties of Automotive Composite Laminates by Adjusting the Stacking Sequences Layup
Authors: Alshahrani Hassan , Ahmed Azzam
Published: October 2021

In response to the high demand for light automotive, manufacturers are showing a vital interest in replacing heavy metallic components with composite materials that exhibit unparalleled strength-to-weight ratios and excellent properties. Unidirectional carbon/epoxy prepreg was suitable for automotive applications such as the front part of the vehicle (hood) due to its excellent crash performance. In this study, UD carbon/epoxy prepreg with 70% and 30% volume fraction of reinforcement and resin, respectively, was used to fabricate the composite laminates. The responses of different three stacking sequences of automotive composite laminates to low-velocity impact damage and flexural and crash performance properties were investigated. Three-point bending and drop-weight impact tests were carried out to determine the flexural modulus, strength, and impact damage behavior of selected materials. Optical microscopy analysis was used to identify the failure modes in the composites. Scanning electron microscopy (SEM) and C-scan non-destructive methods were utilized to explore the fractures in the composites after impact tests. Moreover, the performance index and absorbed energy of the tested structures were studied. The results showed that the flexural strength and modulus of automotive composite laminates strongly depended on the stacking sequence. The highest crash resistance was noticed in the laminate with a stacking sequence of [[0, 90, 45, −45]2, 0, 90]S. Therefore, the fabrication of a composite laminate structure enhanced by selected stacking sequences is an excellent way to improve the crash performance properties of automotive composite structures.
The Bacterial Control of Poly (Lactic Acid) Nanofibers Loaded with Plant-Derived Monoterpenoids via Emulsion Electrospinning
Authors: Hemmatian Tahmineh , Seo Kwon Ho , Yanilmaz Meltem , Kim Juran
Published: October 2021

Plant-derived monoterpenoids have been shown to possess various biological effects, providing a scientific basis for their potential usage as antibacterial agents. Therefore, considering problems surrounding bacteria′s antibacterial resistance, the utilization of natural antimicrobial compounds such as monoterpenoids in different industries has gained much attention. The aim of this study was to fabricate and characterize various concentrations of plant-derived monoterpenoids, geraniol (G) and carvacrol (C), loaded into poly(lactic acid) (PLA) nanofibers via emulsion electrospinning. The antibacterial activities of the fabricated nanofibers were evaluated using three types of antibacterial assays (inhibition zone tests, live/dead bacterial cell assays, and antibacterial kinetic growth assays). Among the samples, 10 wt% carvacrol-loaded PLA nanofibers (C10) had the most bactericidal activity, with the widest inhibition zone of 5.26 cm and the highest visible dead bacteria using the inhibition zone test and live/dead bacterial cell assay. In order to quantitatively analyze the antibacterial activities of 5 wt% carvacrol-loaded PLA nanofibers (C5), C10, 5 wt% geraniol-loaded PLA nanofibers (G5), and 10 wt% geraniol-loaded PLA nanofibers (G10) against E. coli and S.epidermidis, growth kinetic curves were analyzed using OD600. For the results, we found that the antibacterial performance was as follows: C10 > C5 > G10 > G5. Overall, carvacrol or geraniol-loaded PLA nanofibers are promising antibacterial materials for improving fiber functionality.
Purification of Colon Carcinoma Cells from Primary Colon Tumor Using a Filtration Method via Porous Polymeric Filters
Authors: Wang Jia-Hua , Ban Lee-Kiat , Lee Henry Hsin-Chung , Chen Yen-Hung , Lin Hui-Yu , Zhu Zhe-Wei , Su Her-Young , Umezawa Akihiro , Almansour Abdulrahman I. , Arumugam Natarajan , Kumar Raju Suresh , Wu Gwo-Jang , Higuchi Akon
Published: October 2021

Cancer stem cells (CSCs) or cancer-initiating cells (CICs) are key factors for tumor generation and metastasis. We investigated a filtration method to enhance CSCs (CICs) from colon carcinoma HT-29 cells and primary colon carcinoma cells derived from patient colon tumors using poly(lactide-co-glycolic acid)/silk screen (PLGA/SK) filters. The colon carcinoma cell solutions were permeated via porous filters to obtain a permeation solution. Then, the cell cultivation media were permeated via the filters to obtain the recovered solution, where the colon carcinoma cells that adhered to the filters were washed off into the recovered solution. Subsequently, the filters were incubated in the culture media to obtain the migrated cells via the filters. Colon carcinoma HT-29 cells with high tumorigenicity, which might be CSCs (CICs), were enhanced in the cells in the recovered solution and in the migrated cells based on the CSC (CIC) marker expression, colony-forming unit assay, and carcinoembryonic antigen (CEA) production. Although primary colon carcinoma cells isolated from colon tumor tissues contained fibroblast-like cells, the primary colon carcinoma cells were purified from fibroblast-like cells by filtration through PLGA/SK filters, indicating that the filtration method is effective in purifying primary colon carcinoma cells.
Characterization of Collagen/Beta Glucan Hydrogels Crosslinked with Tannic Acid
Authors: Michalska-Sionkowska Marta , Warżyńska Oliwia , Kaczmarek-Szczepańska Beata , Łukowicz Krzysztof , Osyczka Anna Maria , Walczak Maciej
Published: October 2021

Hydrogels based on collagen/β-glucan crosslinked with tannic acid were obtained by neutralization using dialysis. The presence of tannic acid allowed obtaining stable hydrogel materials with better mechanical properties. Tannic acid was released from matrices gradually and not rapidly. The antioxidant properties of the obtained hydrogels increased over the course of their incubation in culture media and were dependent on the concentration of tannic acid in the matrices. The obtained materials influenced dehydrogenase activity and the ATP level of pathogens. Additionally, the materials’ extracts improved the HaCaT cells’ viability. Therefore, the obtained hydrogels seem to be promising biocompatible materials which display antimicrobial properties.
Thermal Behavior of Mixed Plastics at Different Heating Rates: I. Pyrolysis Kinetics
Authors: Dubdub Ibrahim , Al-Yaari Mohammed
Published: October 2021

The amount of generated plastic waste has increased dramatically, up to 20 times, over the past 70 years. More than 50% of municipal plastic waste is composed of polystyrene (PS), polypropylene (PP), and low-density polyethylene (LDPE) products. Therefore, this work has developed a kinetic model that can fully describe the thermal decomposition of plastic mixtures, contributing significantly towards the efficiency of plastic waste management and helping to save the environment. In this work, the pyrolysis of different plastic mixtures, consisting of PP, PS, and LDPE, was performed using a thermogravimetric analyzer (TGA) at three different heating rates (5, 20, and 40 K/min). Four isoconversional models, namely Friedman, Flynn–Wall–Qzawa (FWO), Kissinger–Akahira–Sunose (KAS), and Starink, have been used to obtain the kinetic parameters of the pyrolysis of different plastic mixtures with different compositions. For the equi-mass binary mixtures of PP and PS, the average values of the activation energies were 181, 144 ± 2 kJ/mol obtained using the Freidman and integral (FWO, KAS, and Starink) models, respectively. However, higher values were obtained for the equi-mass ternary plastic mixtures of PP, PS, and LDPE (Freidman: 255 kJ/mol, FWO: 222 kJ/mol, KAS: 223 kJ/mol, and Starink: 222 kJ/mol). The most suitable reaction mechanisms were obtained using the Coats–Redfern model. The results confirm that the most controlling reaction mechanisms obey the first-order (F1) and the third-order (F3) reactions for the pyrolysis of the equi-mass binary (PS and PP) and equi-mass ternary (PS, PP, and LDPE) mixtures, respectively. Finally, the values of the pre-exponential factor (A) were obtained using the four isoconversional models and the linear relationship between ln A and the activation energy was confirmed.
Solubilization Behavior of Homopolymer in Its Blend with the Block Copolymer Displaying the Feature of Lower Critical Ordering Transition
Authors: Lin Yu-Hsuan , Shiu Chang-Cheng , Chen Tien-Lin , Chen Hsin-Lung , Tsai Jing-Cherng
Published: October 2021

Blending with homopolymer offers a facile approach for tuning the microdomain morphology of block copolymer, provided that the homopolymer chains are uniformly solubilized in the corresponding microdomain to swell the junction point separation. Here we studied the solubilization behavior of poly(4-vinyl pyridine) homopolymer (h-P4VP) in the lamellar microdomain formed by its blends with a poly(ethylene oxide)-block-poly(4-vinyl pyridine) (PEO-b-P4VP) showing the feature of lower critical ordering transition (LCOT) in terms of weaker segregation strength at lower temperature. We revealed that, while the conventional criterion of homopolymer-to-block molecular weight ratio for attaining uniform solubilization was applicable to LCOT blend, there was an excess swelling of junction point separation upon the addition of homopolymer, leading to a decrease of interdomain distance with increasing homopolymer composition. This anomalous phenomenon was attributed to the reduction of interfacial free energy due to the incorporation of P4VP homopolymer into the microdomain interface.
Synthesis and Study of Morphology and Biocompatibility of Xanthan Gum/Titanium Dioxide-Based Polyurethane Elastomers
Authors: Naheed Shazia , Shahid Muhammad , Zahoor Rashida , Siddique Zumaira , Rasool Nasir , Haider Sajjad , Khan Shaukat
Published: October 2021

A series of xanthan gum/titanium dioxide-based polyurethane elastomers were synthesized through the prepolymer method by the step growth polymerization. In the present work, xanthan gum was used as a bioactive material, with TiO2 as a nanofiller. The structural characterization of newly prepared polyurethane samples was carried out with the help of Fourier Transform Infrared Spectroscopy. Thermogravimetric Analysis gave us the information about the thermal stability. Differential Scanning Calorimetry directs the thermal changes in the polyurethane samples. The Atomic Force Microscopy technique revealed that the degree of micro-phase separation increases by augmenting the % age of TiO2, which was further confirmed by X-Ray Diffraction results. XRD confirmed the crystallinity of the final sample at about 2θ = 20°. Antimicrobial activity determined through the Disc Diffusion Method, and the results indicated that the synthesized polyurethane have antimicrobial activity. The water absorption capability of the polyurethane samples showed that these polymer samples are hydrophilic in nature.
Attaining Toughness and Reduced Electrical Percolation Thresholds in Bio-Based PA410 by Combined Addition of Bio-Based Thermoplastic Elastomers and CNTs
Authors: Otaegi Itziar , Aranburu Nora , Guerrica-Echevarría Gonzalo
Published: October 2021

Multi-walled carbon nanotubes (CNTs) were added to provide electrical conductivity to bio-based polymer blends with improved toughness (based on commercially available Pebax thermoplastic elastomers and bio-based polyamide 4,10). A preliminary study including three different Pebax grades was carried out to select the grade and the composition that would best improve the impact properties of PA410. Thus, tough multiphasic PA/Pebax/CNT nanocomposites (NCs) with enhanced electrical conductivity were obtained. The CNTs were added either: (1) in the form of pristine nanotubes or (2) in the form of a PA6-based masterbatch. Hence, PA410/Pebax/CNT ternary NCs and PA410/PA6/Pebax/CNT quaternary NCs were obtained, respectively, up to a CNT content of 1 wt%. The ternary and quaternary NCs both showed similar mechanical and electrical properties. The electrical percolation threshold decreased with respect to previously studied corresponding NCs without Pebax, i.e., PA410/CNT and PA410/PA6/CNT, due to the partial volume exclusion effect of Pebax over the CNTs that were dispersed mainly in the PA matrix; materials with percolation concentrations as low as 0.38 wt% were obtained. With respect to mechanical properties, contrary to the NCs without Pebax, all the PA/Pebax/CNT NCs showed a ductile behavior and impact strength values that were from three to five-fold higher than that of the pure PA410.
Additive Manufacturing of Wood Composite Panels for Individual Layer Fabrication (ILF)
Authors: Buschmann Birger , Henke Klaudius , Talke Daniel , Saile Bettina , Asshoff Carsten , Bunzel Frauke
Published: October 2021

The renewable resource, wood, is becoming increasingly popular as a feedstock material for additive manufacturing (AM). It can help make those processes more affordable and reduce their environmental impact. Individual layer fabrication (ILF) is a novel AM process conceived for structural applications. In ILF, parts are formed by laminating thin, individually contoured panels of wood composites which are fabricated additively by binder jetting. The individual fabrication of single panels allows the application of mechanical pressure in manufacturing those board-like elements, leading to a reduction of binder contend and an increase of mechanical strength. In this paper, the ILF process is described in detail, geometric and processing limitations are identified, and the mechanical properties of the intermediate product (panels) are presented. It is shown that the thickness of panels significantly influences the geometric accuracy. Wood composite panels from spruce chips and pMDI adhesive showed flexural strengths between 24.00 and 52.45 MPa with adhesive contents between 6.98 and 17.00 wt %. Thus, the panels meet the mechanical requirements for usage in the European construction industry. Additionally, they have significantly lower binder contents than previously investigated additively manufactured wood composites.
A Dynamically Correlated Network Model for the Collective Dynamics in Glass-Forming Molecular Liquids and Polymers
Authors: Sasaki Takashi , Tsuzuki Yuya , Nakane Tatsuki
Published: October 2021

The non-Arrhenius behavior of segmental dynamics in glass-forming liquids is one of the most profound mysteries in soft matter physics. In this article, we propose a dynamically correlated network (DCN) model to understand the growing behavior of dynamically correlated regions during cooling, which leads to the viscous slowdown of supercooled liquids. The fundamental concept of the model is that the cooperative region of collective motions has a network structure that consists of string-like parts, and networks of various sizes interpenetrate each other. Each segment undergoes dynamical coupling with its neighboring segments via a finite binding energy. Monte Carlo simulations showed that the fractal dimension of the DCNs generated at different temperatures increased and their size distribution became broader with decreasing temperature. The segmental relaxation time was evaluated based on a power law with four different exponents for the activation energy of rearrangement with respect to the DCN size. The results of the present DCN model are consistent with the experimental results for various materials of molecular and polymeric liquids.
Surface Treatments of Coffee Husk Fiber Waste for Effective Incorporation into Polymer Biocomposites
Authors: Gonçalves Bárbara , Camillo Mayara , Oliveira Michel , Carreira Lilian , Moulin Jordão , Fantuzzi Neto Humberto , de Oliveira Bárbara , Pereira Artur , Monteiro Sergio
Published: October 2021

Natural lignocellulose fibers have been extensively investigated and applied as a reinforcement of polymer composites in industrial applications from food packing to automotive parts. Among the advantages of natural fibers stands their relatively low cost and sustainable characteristics. These are accentuated in the case of residual fibers such as those obtained from coffee husks, an agribusiness waste, usually burnt or disposed into the environment. As composite reinforcement, hydrophilic natural fibers display adhesion problems to the most hydrophobic polymer matrices. This adhesion might be improved with distinct types of fibers surface treatments. In the present work, the effectiveness of three surface treatments applied to coffee husk fiber wastes (CHFW) were investigated, aiming to improve the tensile performance of castor oil-based polyurethane (COPU) biocomposites. The effects of treatments associated with (i) chemical with sodium hydroxide, (ii) physical by temperature and pressure and hydrothermic treatment, and (iii) biological by fermentation with Phanerochaete Chrysosporium fungus were evaluated by means of Fourier transformed infrared spectroscopy, X-ray diffraction, thermal analyses and morphology by scanning electron microscopy for different concentration of NaOH, different hydrothermic times at 121 °C/98 kPa and exposition to P. chrysosporium. The most effective treatment was the hydrothermal one at 121 °C and 98.06 kPa for 30 min. Preliminary tensile tests were performed in COPU biocomposites reinforced with 20% CHFWs subjected to the optimized conditions for each distinct type of treatment. The results indicated that the hydrothermal treatment promoted significant enhancement in the fiber/matrix interfacial bond, increasing the tensile strength up to 60% compared to COPU reinforced with in natura CHFWs fibers. It is important to mention that these composites can be applied as plastic wood for household items’ internal parts and in the automobile industry.
Effect of Pectin/Nanochitosan-Based Coatings and Storage Temperature on Shelf-Life Extension of “Elephant” Mango (Mangifera indica L.) Fruit
Authors: Ngo Thi Minh Phuong , Nguyen Thanh Hoi , Dang Thi Mong Quyen , Do Thi Van Thanh , Reungsang Alissara , Chaiwong Nareekan , Rachtanapun Pornchai
Published: October 2021

The aim of extending shelf-life and maintaining quality is one of the major issues regarding mango fruit preservation. The quality of mango fruits is greatly affected by postharvest factors, especially temperature and fruit treatment. In this study, the effect of coating and storage temperature on the characteristics of mango fruits was investigated. The mango fruits were immersed in different concentrations (1.5%, 2.0%, and 2.5%) of pectin/nanochitosan dispersion (with ratios of pectin:nanochitosan 50:50), and (0.75%, 1% and 1.25%) of nanochitosan dispersion and stored at 17, 25, and 32 °C for 24 days. Changes in fruit, including weight loss, firmness, color, chemical composition (such as the total soluble solids concentration (TSS)), total sugar, reducing sugar, titratable acidity (TA), and vitamin C were periodically recorded. The results indicated that the pectin/nanochitosan coating significantly prevented reductions in the fruit weight, firmness, TSS, TA, and vitamin C content. Additionally, pectin/nanochitosan at a low temperature (17 °C) had a greater positive effect on fruit shelf-life and weight maintenance than 25 and 32 °C. The coated mango fruits maintained good quality for 24 days at 17 °C, while coated fruits stored at 25 °C and 32 °C, as well as uncoated ones stored at 17 °C, were destroyed after two weeks. At the maximum storage time evaluated, the coating formulations containing pectin and nanochitosan exhibited microbial counts below the storage life limit of 106 CFU/g of fruit. In general, the results showed that the pectin/nanochitosan coating (2%) with a storage temperature of 17 °C is the most effective strategy for improving quality and extending the shelf-life of mango fruits.
Production and Surface Modification of Cellulose Bioproducts
Authors: Liyanage Sumedha , Acharya Sanjit , Parajuli Prakash , Shamshina Julia L. , Abidi Noureddine
Published: October 2021

Petroleum-based synthetic plastics play an important role in our life. As the detrimental health and environmental effects of synthetic plastics continue to increase, the renewable, degradable and recyclable properties of cellulose make subsequent products the “preferred environmentally friendly” alternatives, with a small carbon footprint. Despite the fact that the bioplastic industry is growing rapidly with many innovative discoveries, cellulose-based bioproducts in their natural state face challenges in replacing synthetic plastics. These challenges include scalability issues, high cost of production, and most importantly, limited functionality of cellulosic materials. However, in order for cellulosic materials to be able to compete with synthetic plastics, they must possess properties adequate for the end use and meet performance expectations. In this regard, surface modification of pre-made cellulosic materials preserves the chemical profile of cellulose, its mechanical properties, and biodegradability, while diversifying its possible applications. The review covers numerous techniques for surface functionalization of materials prepared from cellulose such as plasma treatment, surface grafting (including RDRP methods), and chemical vapor and atomic layer deposition techniques. The review also highlights purposeful development of new cellulosic architectures and their utilization, with a specific focus on cellulosic hydrogels, aerogels, beads, membranes, and nanomaterials. The judicious choice of material architecture combined with a specific surface functionalization method will allow us to take full advantage of the polymer’s biocompatibility and biodegradability and improve existing and target novel applications of cellulose, such as proteins and antibodies immobilization, enantiomers separation, and composites preparation.
Solvent Effect on the Structure and Properties of RGD Peptide (1FUV) at Body Temperature (310 K) Using Ab Initio Molecular Dynamics
Authors: Baral Khagendra , Adhikari Puja , Jawad Bahaa , Podgornik Rudolf , Ching Wai-Yim
Published: October 2021

The structure and properties of the arginine-glycine-aspartate (RGD) sequence of the 1FUV peptide at 0 K and body temperature (310 K) are systematically investigated in a dry and aqueous environment using more accurate ab initio molecular dynamics and density functional theory calculations. The fundamental properties, such as electronic structure, interatomic bonding, partial charge distribution, and dielectric response function at 0 and 310 K are analyzed, comparing them in dry and solvated models. These accurate microscopic parameters determined from highly reliable quantum mechanical calculations are useful to define the range and strength of complex molecular interactions occurring between the RGD peptide and the integrin receptor. The in-depth bonding picture analyzed using a novel quantum mechanical metric, the total bond order (TBO), quantifies the role played by hydrogen bonds in the internal cohesion of the simulated structures. The TBO at 310 K decreases in the dry model but increases in the solvated model. These differences are small but extremely important in the context of conditions prevalent in the human body and relevant for health issues. Our results provide a new level of understanding of the structure and properties of the 1FUV peptide and help in advancing the study of RGD containing other peptides.
Fretting Fatigue Performance of Unidirectional, Laminated Carbon Fibre Reinforced Polymer Straps at Elevated Service Temperature
Authors: Stankovic Danijela , Bisby Luke A. , Triantafyllidis Zafiris , Terrasi Giovanni P.
Published: October 2021

The fretting fatigue performance of laminated, unidirectional (UD), pin-loaded, carbon fibre-reinforced polymer (CFRP) straps that can be used as bridge hanger cables was investigated at a sustained service temperature of 60 °C. The aim of this paper is to elucidate the influence of the slightly elevated service temperature on the tensile fatigue performance of CFRP straps. First, steady state thermal tests at ambient temperature and at 60 °C are presented, in order to establish the behaviour of the straps at these temperatures. These results indicated that the static tensile performance of the straps is not affected by the increase in temperature. Subsequently, nine upper stress levels (USLs) between 650 and 1400 MPa were chosen in order to establish the S–N curve at 60 °C (frequency 10 Hz; R = 0.1) and a comparison with an existing S–N curve at ambient temperature was made. In general, the straps fatigue limit was slightly decreased by temperature, up to 750 MPa USL, while, for the higher USLs, the straps performed slightly better as compared with the S–N curve at ambient temperature.
Effect of Geometric Error on Friction Behavior of Cylinder Seals
Authors: Lin Ange , Wu Jian , Li Haohao , Li Zhe , Su Benlong , Wang Youshan
Published: October 2021

The tribological characteristics of the cylinder directly affect the operation accuracy of the pneumatic servo system. However, the geometric error has a significant effect on its tribological behavior and the related research is insufficient. Thus, the dynamic friction process of rubber seals has been investigated considering the influence of geometric errors. Firstly, based on the self-made friction test platform, the friction force of the rubber seals was studied and the influence law of geometric error on the contact area of the rubber seal ring was revealed. Secondly, the numerical model of the friction and contact of the rubber seals for the cylinder segment was developed by using the finite element simulation method and the influence laws of machining errors, such as roundness and straightness on the friction characteristics, were revealed. Finally, synergy effects of roundness and straightness in the friction behavior of rubber seals considering geometric errors was investigated, which lays a foundation for the accurate prediction of cylinder dynamic mechanical properties.
Parametric Analysis of Epoxy/Crumb Rubber Composite by Using Taguchi—GRA Hybrid Technique
Authors: Shahapurkar Kiran , Chenrayan Venkatesh , Tesfamarium Belay Brehane , Soudagar Manzoore Elahi M. , Hossain Nazia , A. Rajhi Ali , Alamri Sagr , Alarifi Ibrahim M. , Shahapurkar Pavan , Mujtaba M. A. , Kiran M. C. , Sayeed Ahmed Gulam Mohammed
Published: October 2021

Effect of parameters affecting solid particle erosion of crumb rubber epoxy composite is investigated. Five important process parameters—impact velocity, impingement angle, standoff distance, erodent size, and crumb rubber content—are taken into consideration. Erosion rate and erosion efficiency are included as the chief objectives. The Taguchi coupled gray relational analysis type statistical model is implemented to study interaction, parameters’ effect on responses, and optimized parameters. ANOVA and regression model affirmed impingement angle and crumb rubber content play a significant role to minimize the erosion. Validity of the proposed model is justified with the standard probability plot and R2 value. A confirmation experiment conducted with A2B2C3D3E3 condition registers noticeable enhancement in GRG to the tune of 0.0893.