bluuebunny/crossref_metadata_2025 huggingface dataset:
Sex Differences and Commonalities in the Impact of a Palatable Meal on Thalamic and Insular Connectivity
Authors: Kilpatrick Lisa , Pribic Teodora , Ciccantelli Barbara , Malagelada Carolina , Livovsky Dan M. , Accarino Anna , Pareto Deborah , Azpiroz Fernando , Mayer Emeran A.
Published: June 2020

The neural mechanisms underlying subjective responses to meal ingestion remain incompletely understood. We previously showed in healthy men an increase in thalamocortical, and a decrease in insular-cortical connectivity in response to a palatable meal. As sex is increasingly recognized as an important biological variable, we aimed to evaluate sex differences and commonalities in the impact of a well-liked meal on thalamic and anterior insular connectivity in healthy individuals. Participants (20 women and 20 age-matched men) underwent resting-state magnetic resonance imaging (rsMRI) before and after ingesting a palatable meal. In general, the insula showed extensive postprandial reductions in connectivity with sensorimotor and prefrontal cortices, while the thalamus showed increases in connectivity with insular, frontal, and occipital cortices, in both women and men. However, reductions in insular connectivity were more prominent in men, and were related to changes in meal-related sensations (satiety and digestive well-being) in men only. In contrast, increases in thalamic connectivity were more prominent in women, and were related to changes in satiety and digestive well-being in women only. These results suggest that brain imaging may provide objective and sex-specific biomarkers of the subjective feelings associated with meal ingestion.
Plate Waste Generated by Spanish Households and Out-of-Home Consumption: Results from the ANIBES Study
Authors: Partearroyo Teresa , Samaniego-Vaesken Mª de Lourdes , Ruiz Emma , Aranceta-Bartrina Javier , Gil Ángel , González-Gross Marcela , Ortega Rosa M. , Serra-Majem Lluis , Varela-Moreiras Gregorio
Published: June 2020

Food waste is a major environmental issue that must be tackled in order to achieve a sustainable food supply chain. Currently, in Spain there are no studies that examine the amounts and sources of plate waste (PW) produced by both household and out-of-home consumption. The present study aims to provide this information from a representative sample from the Spanish population. A total of 2009 individuals aged 9–75 years, from the ANIBES study (“anthropometric data, macronutrients and micronutrients intake, practice of physical activity, socioeconomic data and lifestyles in Spain”), completed a three-day dietary record, collected by a tablet device. Photographs of all foods and beverages consumed both at home and outside were taken before and after meals. Median PW across the total population was 7.3 (0.0–37.3) g/day and was significantly higher in females than males (p < 0.05) and in children vs. adolescents, adults, and elderly (p < 0.01). Regarding meals, PW across all age groups was higher at lunch (40%), dinner (27%), and breakfast (11%). The highest PW was observed for bread (25%) main courses (16%), first and second courses (15%), vegetables and fruits (12%), ready-to-eat meals (10%), cereals and grains (10%), oils and fats (10%), pulses (10%), meat products (8%), sauces and condiments (8%), and starters (8%). Our results reinforce the need for new strategies to focus on reducing plate leftovers, which are crucial from a nutritional, economic, and environmental point of view. Additionally, this evidence is important for relying on more accurate information on actual intakes when using dietary surveys.
Diplotaxis tenuifolia (L.) DC. Yield and Quality as Influenced by Cropping Season, Protein Hydrolysates, and Trichoderma Applications
Authors: Caruso Gianluca , El-Nakhel Christophe , Rouphael Youssef , Comite Ernesto , Lombardi Nadia , Cuciniello Antonio , Woo Sheridan Lois
Published: June 2020

Increasing attention is being given to plant biostimulants as a sustainable farming practice aimed to enhance vegetable crop performance. This research was conducted on greenhouse-grown perennial wall rocket (Diplotaxis tenuifolia (L.) DC.), comparing three biostimulant treatments (legume-derived protein hydrolysates, Trichoderma harzianum T22, and protein hydrolysates + Trichoderma harzianum T22) plus an untreated control, in a factorial combination with three cropping seasons (autumn–winter, winter, winter–spring). Measurements were performed on leaf yield components, colorimetric indicators, mineral composition, bioactive compounds, and antioxidant activity. Leaf marketable yield and mean weight, as well as plant dry weight, showed the highest values in winter crop cycle. Biostimulant treatments resulted in 18.4% and 26.4% increase in leaf yield and number of leaves per rosette, respectively, compared to the untreated control. Protein hydrolysates led to the highest plant dry weight (+34.7% compared to the control). Soil plant analysis development (SPAD) index as well as NO3, PO4, SO4, and Ca contents were influenced more during the winter–spring season than the winter cropping season. The winter production season resulted in a 19.8% increase in the leaf lipophilic antioxidant activity, whereas the hydrophilic antioxidant activity was 34.9% higher during the winter–spring season. SPAD index was the highest with protein hydrolysates + Trichoderma applications, which also increased the colorimetric parameters compared to the untreated control. The treatment with protein hydrolysates + Trichoderma enhanced N, PO4, Mg, and Na contents, compared to both biostimulants applied singly and to the untreated control. Both biostimulants applied alone or the protein hydrolysates + Trichoderma combination led to the increase of the lipophilic and hydrophilic antioxidant activity, as well as ascorbic acid and chlorophyll b, compared to the untreated control. The present research revealed that protein hydrolysates and Trichoderma single applications, and even more their combination in the case of some nutrients content, represent an effective tool for enhancing the yield and the quality attributes of perennial wall rocket produced under the perspective of sustainable crop system.
Phytochemistry, Toxicology and Therapeutic Value of Petasites hybridus Subsp. Ochroleucus (Common Butterbur) from the Balkans
Authors: Mihajilov-Krstev Tatjana , Jovanović Boris , Zlatković Bojan , Matejić Jelena , Vitorović Jelena , Cvetković Vladimir , Ilić Budimir , Đorđević Ljubiša , Joković Nataša , Miladinović Dragoljub , Jakšić Tatjana , Stanković Nemanja , Stankov Jovanović Vesna , Bernstein Nirit
Published: June 2020

Petasites hybridus (Common butterbur) is extensively used in traditional medicine, and is currently gaining interest and popularity as a food supplement and for its medicinal properties. It contains a large number of active compounds of potential therapeutic activity, but also toxic pyrrolizidine alkaloids. Science-based information is needed to support the developing modern use of this plant, and to direct continued safe practice in traditional medicine. The present study focused on the essential oils from leaves and rhizomes of the understudied P. hybridus ssp. ochroleucus from the Balkans, and evaluated its phytochemistry and potential therapeutic activities (antimicrobial, antioxidant, anti-cholinesterase and anti-inflammatory), as well its toxicology potential (acute toxicity in insects and mice). We studied the essential oils, which are not commonly used in traditional practices, but have a potential for safe use since the toxic pyrrolizidine alkaloids, which are non-volatiles, are usually not present in the distilled essential oils. Pyrrolizidine alkaloids were indeed not detected in the essential oils; ingestion of the essential oils did not induce toxicity signs in mice, and topical application did not elicit skin irritation in humans. The essential oils had no antimicrobial properties against 20 pathogenic bacterial strains, but demonstrated good local anti-inflammatory activity in a Carrageenan-induced paw edema test. An insect toxicity test demonstrated that the leaf essential oil is an efficient insect repellent, and the demonstrated anti-cholinesterase activity suggests a potential for the treatment of neurological conditions. Isopetasin, a sesquiterpene found in plants of the genus Petasites, known to have anti-inflammatory effects, was present only in the rhizomes essential oil (3.9%), and sesquiterpene lactones concentrations were high, likely contributing to the antioxidant activity.
Salt Distribution and Potato Response to Irrigation Regimes under Varying Mulching Materials
Authors: Abd El-Wahed Mohamed Hassan , Al-Omran Abdulrasoul Mosa , Hegazi Mahmoud Mohamed , Ali Mahmoud Mohamed , Ibrahim Yahia Abdelaty Mohamed , EL Sabagh Ayman
Published: June 2020

Water scarcity and frequent drought spells are becoming critical challenges to sustainable agricultural development, especially in arid and semiarid regions. Thus, this work aims to investigate the effect of deficit irrigation and varying mulching materials on soil moisture content, salt distribution, and potato yield. The experiment consisted of three irrigation regimes (I100%, I80%, and I60%) of crop evapotranspiration (ETc), designated as I100%, I80%, and I60% of ETc, and five mulching treatments viz. (i) without mulch (WM), (ii) poultry manure mulch (PMM), (iii) rice straw mulch (RSM), (iv) white plastic mulch (WPM), and (v) black plastic mulch (BPM), which were continued for two consecutive growing seasons. The results showed that soil salinity was affected by mulching and irrigation levels as the salt content increased from the initial soil salinity. Moreover, I60% recorded the highest salt accumulation in the soil profile for WM treatment compared to the rest of the irrigation and mulching treatments. It was also revealed that PMM remained unmatched by significantly producing the highest potato yield compared to other mulching materials. However, the average potato yield decreased by 13.83% and 29.16% in the 2016 season for I80% and I60% and by 12.95% and 30.91% in the 2017 season, respectively, in comparison to full irrigation (I100%). So, when sufficient irrigation water is available, full irrigation (I100%) and PMM treatment are recommended to achieve the maximum potato tuber yield, which has a minimum impact on increasing salinity. However, when the discharge is insufficient, deficit irrigation (I80%) and PMM treatment are recommended to conserve 20% of the irrigation water applied with a minimum reduction in tuber yield and a slight increase in soil salinity.
Mechanisms Underlying the Anti-Inflammatory Activity of Bergamot Essential Oil and Its Antinociceptive Effects
Authors: Lombardo Giovanni Enrico , Cirmi Santa , Musumeci Laura , Pergolizzi Simona , Maugeri Alessandro , Russo Caterina , Mannucci Carmen , Calapai Gioacchino , Navarra Michele
Published: June 2020

Renewed interest in natural products as potential source of drugs led us to investigate on both the anti-inflammatory and anti-nociceptive activity of Citrus bergamia Risso et Poiteau (bergamot) essential oil (BEO). Carrageenan-induced paw edema in rats was used as an experimental model of inflammation. Because of the toxicity of furocoumarins, we performed our study by using the BEO fraction deprived of these compounds (BEO-FF). Treatment with BEO-FF led to a significant inhibition of paw edema induced by a sub-plantar injection of carrageenan. Moreover, histological examination of BEO-FF-treated rat paw biopsies showed a reduction of pathological changes typical of edema. Pre-treatment with BEO-FF significantly reduced interleukin (IL)-1β, IL-6, and tumor necrosis factor (TNF)-α levels in the paw homogenates, as well as nitrite/nitrate and prostaglandin E2 (PGE2) content in exudates. In addition, BEO-FF possesses antioxidant properties, as determined by cell-free assays. Furthermore, results of the writhing test showed that BEO-FF elicited a pronounced analgesic response, as demonstrated by a significant inhibition of constrictions in mice receiving acetic acid, with respect to control animals, whereas the results of the hot plate test suggested that the supra-spinal analgesia participates in the anti-nociceptive effect of BEO-FF. Our study indicates that BEO-FF exerts anti-inflammatory and anti-nociceptive effects, and suggests its potential role as an anti-edemigen and analgesic drug.
Nutritional Value of Savory Herb (Satureja hortensis L.) and Plant Response to Variable Mineral Nutrition Conditions in Various Phases of Development
Authors: Skubij Natalia , Dzida Katarzyna , Jarosz Zbigniew , Pitura Karolina , Jaroszuk-Sierocińska Monika
Published: June 2020

Mineral nutrition and plant ontogeny influence both the physiological balance between nutrients in a plant and determine the proper nutritional status of a plant, which is necessary to realize the yielding potential of a cultivated species. The aim of the present study was to assess the effect of nitrogen doses (0, 4, 8, 12, 16 g N·m−2) and plant development phases (the beginning and full flowering) on the content of macroelements and changes in ionic ratios occurring in the herb of the summer savory cv. ‘Saturn’. The two-factor experiment was carried out in a random-block design with five replications. The mineral nitrogen nutrition applied increased the concentration of total nitrogen and its mineral forms in the plants. There was a change in ion homeostasis in the individual stages of the ontogenesis process, i.e., a higher content of P, K, Ca, and S in the initial flowering phase as well as Mg and Cl in the full flowering phase. The increase in the availability of mineral nitrogen in the soil solution caused a decrease in total sorption capacity, reducing the potential of the soil for saturation with alkaline cations.
Flame Retardancy of Bio-Based Polyurethanes: Opportunities and Challenges
Authors: Vahabi Henri , Rastin Hadi , Movahedifar Elnaz , Antoun Karina , Brosse Nicolas , Saeb Mohammad Reza
Published: June 2020

Sustainable polymers are emerging fast and have received much more attention in recent years compared to petro-sourced polymers. However, they inherently have low-quality properties, such as poor mechanical properties, and inadequate performance, such as high flammability. In general, two methods have been considered to tackle such drawbacks: (i) reinforcement of sustainable polymers with additives; and (ii) modification of chemical structure by architectural manipulation so as to modify polymers for advanced applications. Development and management of bio-based polyurethanes with flame-retardant properties have been at the core of attention in recent years. Bio-based polyurethanes are currently prepared from renewable, bio-based sources such as vegetable oils. They are used in a wide range of applications including coatings and foams. However, they are highly flammable, and their further development is dependent on their flame retardancy. The aim of the present review is to investigate recent advances in the development of flame-retardant bio-based polyurethanes. Chemical structures of bio-based flame-retardant polyurethanes have been studied and explained from the point of view of flame retardancy. Moreover, various strategies for improving the flame retardancy of bio-based polyurethanes as well as reactive and additive flame-retardant solutions are discussed.
The Effect of Poly(ethylene glycol) (PEG) Length on the Wettability and Surface Chemistry of PEG-Fluoroalkyl-Modified Polystyrene Diblock Copolymers and Their Two-Layer Films with Elastomer Matrix
Authors: Guazzelli Elisa , Galli Giancarlo , Martinelli Elisa
Published: June 2020

Diblock copolymers composed of a polystyrene first block and a PEG-fluoroalkyl chain-modified polystyrene second block were synthesized by controlled atom transfer radical polymerization (ATRP), starting from the same polystyrene macroinitiator. The wettability of the polymer film surfaces was investigated by measurements of static and dynamic contact angles. An increase in advancing water contact angle was evident for all the films after immersion in water for short times (10 and 1000 s), consistent with an unusual contraphilic switch of the PEG-fluoroalkyl side chains. Such a contraphilic response also accounted for the retained wettability of the polymer films upon prolonged contact with water, without an anticipated increase in the hydrophilic character. The copolymers were then used as surface-active modifiers of elastomer poly(styrene-b-(ethylene-co-butylene)-b-styrene) (SEBS)-based two-layer films. The elastomeric behavior of the films was varied by using SEBS matrices with different amounts of polystyrene. Whereas the mechanical properties strictly resembled those of the nature of the SEBS matrix, the surface properties were imposed by the additive. The contraphilic switch of the PEG-fluoroalkyl side chains resulted in an exceptionally high enrichment in fluorine of the film surface after immersion in water for seven days.
Development of Polymeric Nanocomposite (Xyloglucan-co-Methacrylic Acid/Hydroxyapatite/SiO2) Scaffold for Bone Tissue Engineering Applications—In-Vitro Antibacterial, Cytotoxicity and Cell Culture Evaluation
Authors: Aslam Khan Muhammad Umar , Mehboob Hassan , Abd Razak Saiful Izwan , Yahya Mohd Yazid , Mohd Yusof Abdul Halim , Ramlee Muhammad Hanif , Sahaya Anand T. Joseph , Hassan Rozita , Aziz Athar , Amin Rashid
Published: June 2020

Advancement and innovation in bone regeneration, specifically polymeric composite scaffolds, are of high significance for the treatment of bone defects. Xyloglucan (XG) is a polysaccharide biopolymer having a wide variety of regenerative tissue therapeutic applications due to its biocompatibility, in-vitro degradation and cytocompatibility. Current research is focused on the fabrication of polymeric bioactive scaffolds by freeze drying method for nanocomposite materials. The nanocomposite materials have been synthesized from free radical polymerization using n-SiO2 and n-HAp XG and Methacrylic acid (MAAc). Functional group analysis, crystallinity and surface morphology were investigated by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction analysis (XRD) and scanning electron microscopy (SEM) techniques, respectively. These bioactive polymeric scaffolds presented interconnected and well-organized porous morphology, controlled precisely by substantial ratios of n-SiO2. The swelling analysis was also performed in different media at varying temperatures (27, 37 and 47 °C) and the mechanical behavior of the dried scaffolds is also investigated. Antibacterial activities of these scaffolds were conducted against pathogenic gram-positive and gram-negative bacteria. Besides, the biological behavior of these scaffolds was evaluated by the Neutral Red dye assay against the MC3T3-E1 cell line. The scaffolds showed interesting properties for bone tissue engineering, including porosity with substantial mechanical strength, biodegradability, biocompatibility and cytocompatibility behavior. The reported polymeric bioactive scaffolds can be aspirant biomaterials for bone tissue engineering to regenerate defecated bone.
Calorimetric and Dielectric Study of Renewable Poly(hexylene 2,5-furan-dicarboxylate)-Based Nanocomposites In Situ Filled with Small Amounts of Graphene Platelets and Silica Nanoparticles
Authors: Sanusi Olawale Monsur , Papadopoulos Lazaros , Klonos Panagiotis A. , Terzopoulou Zoi , Hocine Nourredine Aït , Benelfellah Abdelkibir , Papageorgiou George Z. , Kyritsis Apostolos , Bikiaris Dimitrios N.
Published: June 2020

Poly(hexylene 2,5 furan-dicarboxylate) (PHF) is a relatively new biobased polyester prepared from renewable resources, which is targeted for use in food packaging applications, owing to its great mechanical and gas barrier performance. Since both properties are strongly connected to crystallinity, the latter is enhanced here by the in situ introduction in PHF of graphene nanoplatelets and fumed silica nanoparticles, as well as mixtures of both, at low amounts. For this investigation, we employed Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), X-ray diffraction (XRD) and dielectric spectroscopy (BDS). The fillers were found to improve crystallization in both the rate (increasing Tc) and fraction (CF), which was rationalized via the concept of fillers acting as crystallization agents. This action was found stronger in the case of graphene as compared to silica. BDS allowed the detection of local and segmental dynamics, in particular in PHF for the first time. The glass transition dynamics in both BDS (α relaxation) and DSC (Tg) are mainly dominated by the relatively high CF, whereas in the PHF filled uniquely with silica strong spatial confinement effects due to crystals were revealed. Finally, all samples demonstrated the segmental-like dynamics above Tg, which screens the global chain dynamics (normal mode).
Durability of LDPE/UHMWPE Composites under Accelerated Degradation
Authors: Zaharescu Traian , Râpă Maria , Blanco Ignazio , Borbath Tunde , Borbath Istvan
Published: June 2020

This study presents a detailed analysis of thermal and radiation resistances of low density polyethylene (LDPE)/ultra-high molecular weight polyethylene (UHMWPE) blends containing hydroxyapatite as functional filler and rosemary acting as antioxidant against oxidative degradation. Three main procedures, chemiluminescence (CL), Fourier transform infrared spectroscopy (FTIR), and differential scanning calorimetry (DSC), were applied for the determination of the degree of degradation when these materials are subjected to heat and radiation action. The crystallinity was also assessed for the characterization of diffusion peculiarities. The contributions of the mixing components are discussed based on their oxidation strength. The activation energies required for the oxidative degradation of the studied formulations were calculated.
Deformation-Induced Crystallization Behavior of Isotactic Polypropylene Sheets Containing a β-Nucleating Agent under Solid-State Stretching
Authors: Ji Huajian , Zhou Xulin , Chen Xin , Zhao Haili , Wang Yu , Zhu Huihao , Ma Yulu , Xie Linsheng
Published: June 2020

The deformation-induced crystallization of an isotactic polypropylene (iPP) sheet containing a β-nucleating agent was evaluated. The phase transformation of the β-modifications was investigated and the crystal morphology was observed at room temperature after stretching at different temperatures. The results showed that the crystallinity increased after solid-state stretching. When the stretching temperature was below the initial crystallization temperature, stretching deformation promoted the orientation of amorphous molecular chains. When the deformation temperature exceeded the crystallization temperature, part of the β-modifications underwent a phase transformation process and was stretched into a shish-kebab structure. However, once the stretching temperature was close to the melting point, the β-modifications melted and recrystallized, and the shish-kebab structure underwent stress relaxation due to poor thermal stability, transforming into α-modifications. It was revealed that the crystal phase transformation mechanism of the β-modifications was based on the orientation of the molecular chains between the adjacent lamellae. In addition, the shish-kebab cylindrite structure played an important role in modifying the tensile and impact properties of the iPP sheet. The tensile and impact strengths increased by as much as 34% and 126%, respectively.
Less Reactive Thiol Ligands: Key towards Highly Mucoadhesive Drug Delivery Systems
Authors: Shahzadi Iram , Fürst Andrea , Akkus-Dagdeviren Zeynep Burcu , Arshad Shumaila , Kurpiers Markus , Matuszczak Barbara , Bernkop-Schnürch Andreas
Published: June 2020

As less reactive s-protected thiomers can likely interpenetrate the mucus gel layer to a higher extent before getting immobilized via disulfide bond formation with mucins, it was the aim of this study to develop a novel type of s-protected thiomer based on the less reactive substructure cysteine-N-acetyl cysteine (Cys-NAC) in order to obtain improved mucoadhesive properties. For this purpose, two types of s-protected thiomers, polyacrylic acid-cysteine-mercaptonicotinic acid (PAA-Cys-MNA) and polyacrylic acid-cysteine-N-acetyl cysteine (PAA-Cys-NAC), were synthesized and characterized by Fourier-transform infrared spectroscopy (FT-IR) and the quantification of attached disulfide ligands. The viscosity of both products was measured in the presence of NAC and mucus. Both thiomers were also evaluated regarding swelling behavior, tensile studies and retention time on the porcine intestinal mucosa. The FT-IR spectra confirmed the successful attachment of Cys-MNA and Cys-NAC ligands to PAA. The number of attached sulfhydryl groups was in the range of 660–683 µmol/g. The viscosity of both s-protected thiomers increased due to the addition of increasing amounts of NAC. The viscosity of the mucus increased in the presence of 1% PAA-Cys-MNA and PAA-Cys-NAC 5.6- and 10.9-fold, respectively, in comparison to only 1% PAA. Both s-protected thiomers showed higher water uptake than unmodified PAA. The maximum detachment force (MDF) and the total work of adhesion (TWA) increased in the case of PAA-Cys-MNA up to 1.4- and 1.6-fold and up to 2.4- and 2.8-fold in the case of PAA-Cys-NAC. The retention of PAA, PAA-Cys-MNA, and PAA-Cys-NAC on porcine intestinal mucosa was 25%, 49%, and 76% within 3 h, respectively. The results of this study provide evidence that less reactive s-protected thiomers exhibit higher mucoadhesive properties than highly reactive s-protected thiomers.
Axial Strength of Eccentrically Loaded FRP-Confined Short Concrete Columns
Authors: Jiang Cheng , Wu Yu-Fei
Published: June 2020

This paper presents an experimental program that includes 78 fiber reinforced polymer (FRP)-confined square concrete columns subjected to eccentric loading. The degradation of the axial strength of FRP-confined short concrete columns due to the load eccentricity is investigated in this work. A larger load eccentricity leads to a greater decrease in the axial strength. From the test results, it is found that FRP confinement can cause less strength degradation compared with that of unconfined concrete specimens. For FRP-confined square concrete specimens, the strength enhancement due to FRP confinement increases with increasing load eccentricity. However, the increasing load eccentricity decreases the confinement efficiency for FRP-confined circular concrete specimens. The relationship between the strength of eccentrically loaded FRP-confined square columns and their corner radii is evaluated.
Molecular Dynamics Simulation on the Interfacial Behavior of Over-Molded Hybrid Fiber Reinforced Thermoplastic Composites
Authors: Jiang Bingyan , Zhang Muhan , Fu Liang , Zhou Mingyong , Zhai Zhanyu
Published: June 2020

Hybrid fiber reinforced thermoplastic composites are receiving important attention in lightweight applications. The fabrication process of hybrid thermoplastic composites is that discontinuous fiber reinforced thermoplastics are injected onto the continuous fiber reinforced thermoplastics by over-molding techniques. The key issue during this process is to get a reliable interfacial bonding strength. To understand the bonding mechanism at the heterogeneous interface of hybrid thermoplastic composites which is difficult to obtain through experimental investigations, a series of molecular dynamic (MD) simulations were conducted in this paper. The influence of processing parameters on the interfacial characteristics, i.e., the distribution of interfacial high-density enrichment areas, radius of gyration, diffusion coefficient and interfacial energy, were investigated during the forming process of a heterogeneous interface. Simulation results reveal that some of molecule chains get across the interface and tangle with the molecules from the other layer, resulting in the penetration phenomenon near the interface zone. In addition, the melting temperature and injection pressure exhibit positive effects on the interfacial properties of hybrid composites. To further investigate the interfacial bonding strength and fracture mechanism of the heterogeneous interface, the uniaxial tensile and sliding simulations were performed. Results show that the non-bonded interaction energy plays a crucial role during the fracture process of heterogeneous interface. Meanwhile, the failure mode of the heterogeneous interface was demonstrated to evolve with the processing parameters.
Selective Photocatalytic Oxidation of 5-HMF in Water over Electrochemically Synthesized TiO2 Nanoparticles
Authors: Ulyankina Anna , Mitchenko Sergey , Smirnova Nina
Published: June 2020

TiO2 nanoparticles were prepared via an electrochemical method using pulse alternating current and applied in the photocatalytic oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-diformylfuran (DFF). Its physicochemical properties were characterized by SEM, HRTEM, XRD, and BET methods. The effect of scavenger and UVA light intensity was studied. The results revealed that electrochemically synthesized TiO2 nanoparticles exhibit higher DFF selectivity in the presence of methanol (up to 33%) compared with commercial samples.
A Novel Approach in Crude Enzyme Laccase Production and Application in Emerging Contaminant Bioremediation
Authors: Nguyen Luong N. , Vu Minh T. , Johir Md Abu Hasan , Pathak Nirenkumar , Zdarta Jakub , Jesionowski Teofil , Semblante Galilee U. , Hai Faisal I. , Khanh Dieu Nguyen Hong , Nghiem Long D.
Published: June 2020

Laccase enzyme from white-rot fungi is a potential biocatalyst for the oxidation of emerging contaminants (ECs), such as pesticides, pharmaceuticals and steroid hormones. This study aims to develop a three-step platform to treat ECs: (i) enzyme production, (ii) enzyme concentration and (iii) enzyme application. In the first step, solid culture and liquid culture were compared. The solid culture produced significantly more laccase than the liquid culture (447 vs. 74 µM/min after eight days), demonstrating that white rot fungi thrived on a solid medium. In the second step, the enzyme was concentrated 6.6 times using an ultrafiltration (UF) process, resulting in laccase activity of 2980 µM/min. No enzymatic loss due to filtration and membrane adsorption was observed, suggesting the feasibility of the UF membrane for enzyme concentration. In the third step, concentrated crude enzyme was applied in an enzymatic membrane reactor (EMR) to remove a diverse set of ECs (31 compounds in six groups). The EMR effectively removed of steroid hormones, phytoestrogen, ultraviolet (UV) filters and industrial chemical (above 90%). However, it had low removal of pesticides and pharmaceuticals.
Dynamic Metabolic Analysis of Cupriavidus necator DSM545 Producing Poly(3-hydroxybutyric acid) from Glycerol
Authors: Sun Chenhao , Pérez-Rivero Cristina , Webb Colin , Theodoropoulos Constantinos
Published: June 2020

Cupriavidus necator DSM 545 can utilise glycerol to synthesise poly(3-hydroxybutyric acid) under unbalanced growth conditions, i.e., nitrogen limitation. To improve poly(3-hydroxybutyric acid) (PHB) batch production by C. necator through model-guided bioprocessing or genetic engineering, insights into the dynamic effect of the fermentation conditions on cell metabolism are crucial. In this work, we have used dynamic flux balance analysis (DFBA), a constrained-based stoichiometric modelling approach, to study the metabolic change associated with PHB synthesis during batch cultivation. The model employs the ‘minimisation of all fluxes’ as cellular objectives and measured extracellular fluxes as additional constraints. The mass balance constraints are further adjusted based on thermodynamic considerations. The resultant flux distribution profiles characterise the evolution of metabolic states due to adaptation to dynamic extracellular conditions and provide further insights towards improvements that can be implemented to enhance PHB productivity.
Thermochemical Conversion of Olive Oil Industry Waste: Circular Economy through Energy Recovery
Authors: Nunes Leonel J. R. , Loureiro Liliana M. E. F. , Sá Letícia C. R. , Silva Hugo F.C.
Published: June 2020

The demand for new sources of energy is one of the main quests for humans. At the same time, there is a growing need to eliminate or recover a set of industrial or agroforestry waste sources. In this context, several options may be of interest, especially given the amounts produced and environmental impacts caused. Olive pomace can be considered one of these options. Portugal, as one of the most prominent producers of olive oil, therefore, also faces the problem of dealing with the waste of the olive oil industry. Olive pomace energy recovery is a subject referenced in many different studies and reports since long ago. However, traditional forms of recovery, such as direct combustion, did not prove to be the best solution, mainly due to its fuel properties and other characteristics, which cause difficulties in its storage and transportation as well. Torrefaction and pyrolysis can contribute to a volume reduction, optimizing storage and transportation. In this preliminary study, were carried out torrefaction and pyrolysis tests on olive pomace samples, processed at 300 °C, 400 °C, and 500 °C, followed by laboratory characterization of the materials. It was verified an improvement in the energy content of the materials, demonstrating that there is potential for the use of these thermochemical conversion technologies for the energy recovery of olive pomace.
Fast Split Bregman Based Deconvolution Algorithm for Airborne Radar Imaging
Authors: Zhang Yin , Zhang Qiping , Zhang Yongchao , Pei Jifang , Huang Yulin , Yang Jianyu
Published: June 2020

Deconvolution methods can be used to improve the azimuth resolution in airborne radar imaging. Due to the sparsity of targets in airborne radar imaging, an L 1 regularization problem usually needs to be solved. Recently, the Split Bregman algorithm (SBA) has been widely used to solve L 1 regularization problems. However, due to the high computational complexity of matrix inversion, the efficiency of the traditional SBA is low, which seriously restricts its real-time performance in airborne radar imaging. To overcome this disadvantage, a fast split Bregman algorithm (FSBA) is proposed in this paper to achieve real-time imaging with an airborne radar. Firstly, under the regularization framework, the problem of azimuth resolution improvement can be converted into an L 1 regularization problem. Then, the L 1 regularization problem can be solved with the proposed FSBA. By utilizing the low displacement rank features of Toeplitz matrix, the proposed FSBA is able to realize fast matrix inversion by using a Gohberg–Semencul (GS) representation. Through simulated and real data processing experiments, we prove that the proposed FSBA significantly improves the resolution, compared with the Wiener filtering (WF), truncated singular value decomposition (TSVD), Tikhonov regularization (REGU), Richardson–Lucy (RL), iterative adaptive approach (IAA) algorithms. The computational advantage of FSBA increases with the increase of echo dimension. Its computational efficiency is 51 times and 77 times of the traditional SBA, respectively, for echoes with dimensions of 218 × 400 and 400 × 400 , optimizing both the image quality and computing time. In addition, for a specific hardware platform, the proposed FSBA can process echo of greater dimensions than traditional SBA. Furthermore, the proposed FSBA causes little performance degradation, when compared with the traditional SBA.
Determining the Genetic Control of Common Bean Early-Growth Rate Using Unmanned Aerial Vehicles
Authors: Parker Travis A. , Palkovic Antonia , Gepts Paul
Published: June 2020

Vigorous early-season growth rate allows crops to compete more effectively against weeds and to conserve soil moisture in arid areas. These traits are of increasing economic importance due to changing consumer demand, reduced labor availability, and climate-change-related increasing global aridity. Many crop species, including common bean, show genetic variation in growth rate, between varieties. Despite this, the genetic basis of early-season growth has not been well-resolved in the species, in part due to historic phenotyping challenges. Using a range of UAV- and ground-based methods, we evaluated the early-season growth vigor of two populations. These growth data were used to find genetic regions associated with several growth parameters. Our results suggest that early-season growth rate is the result of complex interactions between several genetic and environmental factors. They also highlight the need for high-precision phenotyping provided by UAVs. The quantitative trait loci (QTLs) identified in this study are the first in common bean to be identified remotely using UAV technology. These will be useful for developing crop varieties that compete with weeds and use water more effectively. Ultimately, this will improve crop productivity in the face of changing climatic conditions and will mitigate the need for water and resource-intensive forms of weed control.
Magnitude Agreement, Occurrence Consistency, and Elevation Dependency of Satellite-Based Precipitation Products over the Tibetan Plateau
Authors: Wang Yibing , Xie Xianhong , Meng Shanshan , Wu Dandan , Chen Yuchao , Jiang Fuxiao , Zhu Bowen
Published: June 2020

Satellite remote sensing is a practical technique to estimate global precipitation with adequate spatiotemporal resolution in ungauged regions. However, the performance of satellite-based precipitation products is variable and uncertain for the Tibetan Plateau (TP) because of its complex terrain and climate conditions. In this study, we evaluated the abilities of nine widely used satellite-based precipitation products over the Eastern Tibetan Plateau (ETP) and quantified precipitation dynamics over the entire TP. The evaluation was carried out from three aspects, i.e., magnitude agreement, occurrence consistency, and elevation dependency, from grid-cell to regional scales. The results show that the nine satellite-based products exhibited different agreement with gauge-based reference data with median correlation coefficients ranging from 0.15 to 0.95. Three products (climate hazards group infrared precipitation with stations (CHIRPS), multi-source weighted-ensemble precipitation (MSWEP), and tropical rainfall measuring mission multi-satellite precipitation analysis (TMPA)) generally presented the best performance with the reference data, even in complex terrain regions, given their root mean square errors (RMSE) of less than 25 mm/mon. The climate prediction center merged analysis of precipitation (CMAP) product has relatively coarse spatial resolution, but it also exhibited good performance with a bias of less than 20% in watershed scale. Two other products (precipitation estimation from remotely sensed information using artificial neural networks-cloud classification system (PER-CCS) and climate prediction center morphing technique-raw (CMORPH-RAW)) overestimated precipitation with median RMSEs of 87 mm/mon and 45 mm/mon, respectively. All the precipitation products generally exhibited better agreement with the reference data for rainy season and lower-elevation regions. All of the products captured precipitation occurrence well, with hit event over 60%, and similar percentages of missed and false event. According to the evaluation, the four products (CHIRPS, MSWEP, TMPA, and CMAP) revealed that the annual precipitation over the TP fluctuated between 333 mm/yr and 488 mm/yr during the period 2003 to 2015. The study indicates the importance of integration of multiple data sources and post-processing (e.g., gauge data fusion and elevation correction) for satellite-based products and have implications for selection of suitable precipitation products for hydrological modeling and water resources assessment for the TP.
Aboveground Biomass Estimation in Amazonian Tropical Forests: a Comparison of Aircraft- and GatorEye UAV-borne LiDAR Data in the Chico Mendes Extractive Reserve in Acre, Brazil
Authors: d’Oliveira Marcus , Broadbent Eben , Oliveira Luis , Almeida Danilo , Papa Daniel , Ferreira Manuel , Zambrano Angelica , Silva Carlos , Avino Felipe , Prata Gabriel , Mello Ricardo , Figueiredo Evandro , Jorge Lúcio , Junior Leomar , Albuquerque Rafael , Brancalion Pedro , Wilkinson Ben , Oliveira-da-Costa Marcelo
Published: June 2020

Tropical forests are often located in difficult-to-access areas, which make high-quality forest structure information difficult and expensive to obtain by traditional field-based approaches. LiDAR (acronym for Light Detection And Ranging) data have been used throughout the world to produce time-efficient and wall-to-wall structural parameter estimates for monitoring in native and commercial forests. In this study, we compare products and aboveground biomass (AGB) estimations from LiDAR data acquired using an aircraft-borne system in 2015 and data collected by the unmanned aerial vehicle (UAV)-based GatorEye Unmanned Flying Laboratory in 2017 for ten forest inventory plots located in the Chico Mendes Extractive Reserve in Acre state, southwestern Brazilian Amazon. The LiDAR products were similar and comparable among the two platforms and sensors. Principal differences between derived products resulted from the GatorEye system flying lower and slower and having increased returns per second than the aircraft, resulting in a much higher point density overall (11.3 ± 1.8 vs. 381.2 ± 58 pts/m2). Differences in ground point density, however, were much smaller among the systems, due to the larger pulse area and increased number of returns per pulse of the aircraft system, with the GatorEye showing an approximately 50% higher ground point density (0.27 ± 0.09 vs. 0.42 ± 0.09). The LiDAR models produced by both sensors presented similar results for digital elevation models and estimated AGB. Our results validate the ability for UAV-borne LiDAR sensors to accurately quantify AGB in dense high-leaf-area tropical forests in the Amazon. We also highlight new possibilities using the dense point clouds of UAV-borne systems for analyses of detailed crown structure and leaf area density distribution of the forest interior.
Driving Factors of Recent Vegetation Changes in Hexi Region, Northwest China Based on a New Classification Framework
Authors: Wang Ju , Xie Yaowen , Wang Xiaoyun , Guo Kunming
Published: June 2020

Since other factors (soil properties, topography, etc.) under natural conditions are relatively invariant over one or two decades, climate variables (precipitation and temperature) and human activities are the two fundamental factors driving vegetation changes in global or large-scale areas. However, the combined effects of either single climatic factor and human activities on vegetation changes and the role of human activities itself in a specific region has not been fully discussed. In this study, the Hexi region, a typical dryland consisting of three inland river basins in northwest China was selected as a case area. A new classification framework combining Pearson correlation analysis and residual trend approach was proposed to assess their individual and conjoint contributions of climate variables and human activities in areas of significant vegetation changes. Our results indicated that most of vegetation covered areas in the Hexi region experienced significant changes during the period 2001−2017, and vegetation improvements were widespread except the interior of oases; significant changes in vegetation caused by human activities, precipitation, the interactions of precipitation and human activities, temperature, the interactions of temperature and human activities, the interactions of temperature and precipitation, and the interactions of the three factors accounted for 50.46%, 16.39%, 19.90%, 4.33%, 2.32%, 2.11%, and 4.49% of the total change areas, respectively. Generally, the influence of temperature was relatively weaker than that of precipitation, and the contributions of the interactions of climate variables and human activities on vegetation changes were greater than that of climate contributions alone. Moreover, the results of various investigations, according to the trends and the time of vegetation changes, indicate that decreasing trends of the normalized difference vegetation index (NDVI) in the Hexi region were chiefly attributed to the adjustments of agricultural planting structure while the comprehensive treatment programs implemented in river basins supported a large proportion of vegetation improvements.
Comparison of Smartphone and Drone Lidar Methods for Characterizing Spatial Variation in PAI in a Tropical Forest
Authors: E. Rudic Tamara , A. McCulloch Lindsay , Cushman Katherine
Published: June 2020

Estimating leaf area index (LAI) and assessing spatial variation in LAI across a landscape is crucial to many ecological studies. Several direct and indirect methods of LAI estimation have been developed and compared; however, many of these methods are prohibitively expensive and/or time consuming. Here, we examine the feasibility of using the free image processing software CAN-EYE to estimate effective plant area index (PAIeff) from hemispherical canopy images taken with an extremely inexpensive smartphone clip-on fisheye lens. We evaluate the effectiveness of this inexpensive method by comparing CAN-EYE smartphone PAIeff estimates to those from drone lidar over a lowland tropical forest at La Selva Biological Station, Costa Rica. We estimated PAIeff from drone lidar using a method based in radiative transfer theory that has been previously validated using simulated data; we consider this a conservative test of smartphone PAIeff reliability because above-canopy lidar estimates share few assumptions with understory image methods. Smartphone PAIeff varied from 0.1 to 4.4 throughout our study area and we found a significant correlation (r = 0.62, n = 42, p < 0.001) between smartphone and lidar PAIeff, which was robust to image processing analytical options and smartphone model. When old growth and secondary forests are assumed to have different leaf angle distributions for the lidar PAIeff algorithm (spherical and planophile, respectively) this relationship is further improved (r = 0.77, n = 42, p < 0.001). However, we found deviations in the magnitude of the PAIeff estimations depending on image analytical options. Our results suggest that smartphone images can be used to characterize spatial variation in PAIeff in a complex, heterogenous tropical forest canopy, with only small reductions in explanatory power compared to true digital hemispherical photography.