bluuebunny/crossref_metadata_2025 huggingface dataset:
High-Performance Biomemristor Embedded with Graphene Quantum Dots
Authors: Wang Lu , Yang Jing , Zhang Xiafan , Wen Dianzhong
Published: November 2023

By doping a dielectric layer material and improving the device’s structure, the electrical characteristics of a memristor can be effectively adjusted, and its application field can be expanded. In this study, graphene quantum dots are embedded in the dielectric layer to improve the performance of a starch-based memristor, and the PMMA layer is introduced into the upper and lower interfaces of the dielectric layer. The experimental results show that the switching current ratio of the Al/starch: GQDs/ITO device was 102 times higher than that of the Al/starch/ITO device. However, the switching current ratio of the Al/starch: GQDs/ITO device was further increased, and the set voltage was reduced (−0.75 V) after the introduction of the PMMA layer. The introduction of GQDs and PMMA layers can regulate the formation process of conductive filaments in the device and significantly improve the electrical performance of the memristor.
Structure and Magnetic Properties of Mechanosynthesized Nanocrystalline Fe2CrSi Heusler Alloy
Authors: Jartych Elżbieta , Jaskółowska Paulina , Oleszak Dariusz , Pękała Marek
Published: November 2023

Heusler alloys constitute an interesting group of materials with wide applications. The purpose of the present study was to use the mechanical alloying method to synthesize Fe2CrSi Heusler alloy and learn about its structure and magnetic properties. Pure metal elements were ground for various periods of time in a planetary ball mill, and the process of alloy formation was monitored using X-ray diffraction and Mössbauer spectroscopy. It was found that after 20 h of milling, the disordered BCC solid solution was formed, with an average crystallite size ~11 nm. After thermal treatment, the desired Fe2CrSi Heusler alloy was obtained, with a small amount of secondary phases. Detailed XRD analysis showed the coexistence of two varieties of Heusler phase, namely Fm-3m and Pm-3n. The main result of this work is the detection of the hyperfine magnetic field distribution using Mössbauer spectroscopy. The occurrence of this distribution proves atomic disorder in the crystalline structure of the obtained Heusler alloy. Macroscopic magnetic measurements revealed soft magnetic properties of the alloy, with a magnetic moment of ~2.3 μB/f.u., only slightly larger than the theoretically predicted value.
Tuning Electromagnetic Parameters Induced by Synergistic Dual-Polarization Enhancement Mechanisms with Amorphous Cobalt Phosphide with Phosphorus Vacancies for Excellent Electromagnetic Wave Dissipation Performance
Authors: Wen Bo , Miao Yunzi , Zhang Zhijie , Li Na , Xiao Jiyuan , Li Yushuo , Feng Jiangtao , Ding Shujiang , Yang Guorui
Published: November 2023

The understanding of amorphous and heterojunction materials has been widely used in the field of electromagnetic wave absorption due to their unique physical and chemical properties. However, the effectiveness of individual strategies currently used is still limited. Well-designed compositions and amorphous structures simplify the effect of different polarization mechanisms on the absorption of electromagnetic waves. In this work, through the carbonization and controlled phosphating of one-dimensional Co Metal–Organic Framework (Co-MOF) nanorods, the synthesis of complex components and amorphous CoPx with phosphorus vacancies is successfully accomplished, thus adjusting the optimization of electromagnetic parameters. Phosphorus-vacancy-induced defective polarization loss and enhanced-electronegativity-differences-induced dipole polarization loss synergistically as a dual-polarization strategy significantly improved the electromagnetic parameters and impedance matching. In conclusion, the electromagnetic parameters of the Co@CoPx@C composites are indeed significantly regulated, with reflection losses of −55 dB and a bandwidth of up to 5.5 GHz. These innovative research ideas provide instructive thinking for the development of amorphous absorbers with vacancies.
Combustion Synthesis of Materials for Application in Supercapacitors: A Review
Authors: Sisakyan Narek , Chilingaryan Gayane , Manukyan Aram , Mukasyan Alexander S.
Published: November 2023

A supercapacitor is an energy storage device that has the advantage of rapidly storing and releasing energy compared to traditional batteries. One powerful method for creating a wide range of materials is combustion synthesis, which relies on self-sustained chemical reactions. Specifically, solution combustion synthesis involves mixing reagents at the molecular level in an aqueous solution. This method allows for the fabrication of various nanostructured materials, such as binary and complex oxides, sulfides, and carbon-based nanocomposites, which are commonly used for creating electrodes in supercapacitors. The solution combustion synthesis offers flexibility in tuning the properties of the materials by adjusting the composition of the reactive solution, the type of fuel, and the combustion conditions. The process takes advantage of high temperatures, short processing times, and significant gas release to produce well crystalline nanostructured materials with a large specific surface area. This specific surface area is essential for enhancing the performance of electrodes in supercapacitors. Our review focuses on recent publications in this field, specifically examining the relationship between the microstructure of materials and their electrochemical properties. We discuss the findings and suggest potential improvements in the properties and stability of the fabricated composites based on the results.
Exploring Factors Associated with Gender Differences in Perceived Stress among Adults with Higher Body Weight in the United States—A Cross-Sectional Analysis
Authors: Wijayatunga Nadeeja N. , Wellman Joseph D. , Tomasko Kevin
Published: November 2023

This study aimed to explore factors associated with perceived stress in adults with higher body sizes. An analysis of data from participants who self-reported higher body weight was conducted (n = 1716). The mean (standard deviation) age was 55.92 (15.94) years and 71.3% and 28.7% identified themselves as women and men, respectively. Gender differences in perceived stress, desire for weight loss, trust in physicians, body affirmation, and perceived weight discrimination were examined. Perceived stress and perceived weight discrimination were significantly higher in women than in men, while trust in physicians and body affirmation was higher in men than women. Trust in physicians and body affirmation were both negatively associated with perceived stress. Perceived weight discrimination and desire for weight loss were both positively associated with perceived stress. Trust in physicians, body affirmation, and perceived weight discrimination were examined as mediators of the observed gender differences between men and women. Trust in physicians, body affirmation, and perceived weight discrimination were significant mediators of the relationship between gender and perceived stress. These results suggest that a possible point of intervention for addressing gender differences in rates of perceived stress among higher body weight adults may be to increase trust in physicians, encourage body affirmation, and reduce weight discrimination.
Skeletal Anchorage in Treating Skeletal Class II Malocclusion in Growing Patients Using the Herbst Appliance
Authors: Manni Antonio , Pera Stefano , Gastaldi Giorgio , Boggio Andrea , Cozzani Mauro
Published: November 2023

Skeletal Class II is a common malocclusion affecting the Caucasian population and characterized, in most cases, by a convex profile and mandibular retrusion. Therefore, the treatment plan often requires the use of functional appliances to promote mandibular advancement. In particular, the Herbst appliance is recommended because of its efficiency and minimal need for compliance. However, in addition to skeletal favorable effects, undesired dental compensations could prematurely reduce the overjet needed for a proper orthopedic outcome. The combination of this appliance with skeletal anchorage and elastic ligatures in the lower or both, in the upper and the lower arch, enables effective control of unfavorable tooth movements, improving the therapeutic potential of such a treatment. These improvements have significantly shifted the main focus on facial aesthetics rather than dental occlusion, with the creation of innovative treatment protocols and a new diagnostic approach to Class II malocclusion.
Pathology of Severe Malaria
Authors: Gallego-Delgado Julio
Published: November 2023

Malaria, a devastating disease transmitted by mosquitoes, continues to plague many regions worldwide, affecting millions of lives annually [...]
Campylobacter jejuni Response When Inoculated in Bovine In Vitro Fecal Microbial Consortia Incubations in the Presence of Metabolic Inhibitors
Authors: Dittoe Dana K. , Anderson Robin C. , Krueger Nathan A. , Harvey Roger B. , Poole Toni L. , Crippen Tawni L. , Callaway Todd R. , Ricke Steven C.
Published: November 2023

Infection with the foodborne pathogen Campylobacter is the leading bacterial cause of human foodborne illness in the United States. The objectives of this experiment were to test the hypothesis that mixed microbial populations from the bovine rumen may be better at excluding Campylobacter than populations from freshly voided feces and to explore potential reasons as to why the rumen may be a less favorable environment for Campylobacter than feces. In an initial experiment, C. jejuni cultures inoculated without or with freshly collected bovine rumen fluid, bovine feces or their combination were cultured micro-aerobically for 48 h. Results revealed that C. jejuni grew at similar growth rates during the first 6 h of incubation regardless of whether inoculated with the rumen or fecal contents, with rates ranging from 0.178 to 0.222 h−1. However, C. jejuni counts (log10 colony-forming units/mL) at the end of the 48 h incubation were lowest in cultures inoculated with rumen fluid (5.73 log10 CFUs/mL), intermediate in cultures inoculated with feces or both feces and rumen fluid (7.16 and 6.36 log10 CFUs/mL) and highest in pure culture controls that had not been inoculated with the rumen or fecal contents (8.32 log10 CFUs/mL). In follow-up experiments intended to examine the potential effects of hydrogen and hydrogen-consuming methanogens on C. jejuni, freshly collected bovine feces, suspended in anaerobic buffer, were incubated anaerobically under either a 100% carbon dioxide or 50:50 carbon dioxide/hydrogen gas mix. While C. jejuni viability decreased <1 log10 CFUs/mL during incubation of the fecal suspensions, this did not differ whether under low or high hydrogen accumulations or whether the suspensions were treated without or with the mechanistically distinct methanogen inhibitors, 5 mM nitrate, 0.05 mM 2-bromosulfonate or 0.001 mM monensin. These results suggest that little if any competition between C. jejuni and hydrogen-consuming methanogens exists in the bovine intestine based on fecal incubations.
RhoG-Binding Domain of Elmo1 Ameliorates Excessive Process Elongation Induced by Autism Spectrum Disorder-Associated Sema5A
Authors: Okabe Miyu , Miyamoto Yuki , Ikoma Yuta , Takahashi Mikito , Shirai Remina , Kukimoto-Niino Mutsuko , Shirouzu Mikako , Yamauchi Junji
Published: November 2023

Autism spectrum disorder (ASD) is a neurodevelopmental disorder that includes autism, Asperger’s syndrome, and pervasive developmental disorder. ASD is characterized by poor interpersonal relationships and strong attachment. The correlations between activated or inactivated gene products, which occur as a result of genetic mutations affecting neurons in ASD patients, and ASD symptoms are now of critical concern. Here, for the first time, we describe the process in which that the respective ASD-associated mutations (Arg676-to-Cys [R676C] and Ser951-to-Cys [S951C]) of semaphorin-5A (Sema5A) localize Sema5A proteins themselves around the plasma membrane in the N1E-115 cell line, a model line that can achieve neuronal morphological differentiation. The expression of each mutated construct resulted in the promotion of excessive elongation of neurite-like processes with increased differentiation protein markers; R676C was more effective than S951C. The differentiated phenotypes were very partially neutralized by an antibody, against Plexin-B3 as the specific Sema5A receptor, suggesting that the effects of Sema5A act in an autocrine manner. R676C greatly increased the activation of c-Jun N-terminal kinase (JNK), one of the signaling molecules underlying process elongation. In contrast, the blocking of JNK signaling, by a chemical JNK inhibitor or an inhibitory construct of the interaction of RhoG with Elmo1 as JNK upstream signaling molecules, recovered the excessive process elongation. These results suggest that ASD-associated mutations of Sema5A, acting through the JNK signaling cascade, lead to excessive differentiated phenotypes, and the inhibition of JNK signaling recovers them, revealing possible therapeutic targets for recovering the potential molecular and cellular phenotypes underlying certain ASD symptoms.
Optimized Liposomal Delivery of Bortezomib for Advancing Treatment of Multiple Myeloma
Authors: Zhang Chi , Kuo Jimmy Chun-Tien , Huang Yirui , Hu Yingwen , Deng Lan , Yung Bryant C. , Zhao Xiaobin , Zhang Zhongkun , Pan Junjie , Ma Yifan , Lee Robert J.
Published: November 2023

Bortezomib (BTZ), a boronic acid-derived proteasome inhibitor, is commonly employed in treating multiple myeloma (MM). However, the applications of BTZ are limited due to its poor stability and low bioavailability. Herein, we develop an optimized liposomal formulation of BTZ (L-BTZ) by employing a remote-loading strategy. This formulation uses Tiron, a divalent anionic catechol derivative, as the internal complexing agent. Compared to earlier BTZ-related formulations, this alternative formulation showed significantly greater stability due to the Tiron–BTZ complex’s higher pH stability and negative charges, compared to the meglumine–BTZ complex. Significantly, the plasma AUC of L-BTZ was found to be 30 times greater than that of free BTZ, suggesting an extended blood circulation duration. In subsequent therapeutic evaluations using two murine xenograft tumor models of MM, the NCI-H929 and OPM2 models showed tumor growth inhibition (TGI) values of 37% and 57%, respectively. In contrast, free BTZ demonstrated TGI values of 17% and 11% in these models. Further, L-BTZ presented enhanced antitumor efficacy in the Hepa1-6 HCC syngeneic model, indicating its potential broader applicability as an antineoplastic agent. These findings suggest that the optimized L-BTZ formulation offers a significant advancement in BTZ delivery, holding substantial promise for clinical investigation in not merely MM, but other cancer types.
Antibacterial Bionanocomposites Based on Drug-Templated Bifunctional Mesoporous Silica Nanocontainers
Authors: Shishmakova Elena M. , Ivchenko Anastasia V. , Bolshakova Anastasia V. , Staltsov Maxim S. , Urodkova Ekaterina K. , Grammatikova Natalia E. , Rudoy Victor M. , Dement’eva Olga V.
Published: November 2023

The creation of antibacterial nanocomposites that provide prolonged release of encapsulated drugs is of great interest for various fields of medicine (dentistry, tissue regeneration, etc.). This article demonstrates the possibility of creating such nanocomposites based on sodium alginate and drug-templated mesoporous silica nanocontainers (MSNs) loaded with two bioactive substances. Herein, we thoroughly study all stages of the process, starting with the synthesis of MSNs using antiseptic micelles containing the hydrophobic drug quercetin and ending with assessing the activity of the resulting composites against various microorganisms. The main emphasis is on studying the quercetin solubilization in antiseptic micelles as well as establishing the relationship between the conditions of MSN synthesis and micelle morphology and capacity. The effect of medium pH on the release rate of encapsulated drugs is also evaluated. It was shown that the MSNs contained large amounts of encapsulated drugs and that the rate of drug unloading depended on the medium pH. The incorporation of such MSNs into the alginate matrix allowed for a prolonged release of the drugs.
The Design and Optimization of Ceramide NP-Loaded Liposomes to Restore the Skin Barrier
Authors: Şahin Bektay Hümeyra , Sağıroğlu Ali Asram , Bozali Kübra , Güler Eray Metin , Güngör Sevgi
Published: November 2023

The impairment of skin integrity derived from derangement of the orthorhombic lateral organization is mainly caused by dysregulation of ceramide amounts in the skin barrier. Ceramides, fatty acids, and cholesterol-containing nano-based formulations have been used to impair the skin barrier. However, there is still a challenge to formulate novel formulations consisting of ceramides due to their chemical structure, poor aqueous solubility, and high molecular weight. In this study, the design and optimization of Ceramide 3 (CER-NP)-loaded liposomes are implemented based on response surface methodology (RSM). The optimum CER-NP-loaded liposome was selected based on its particle size (PS) and polydispersity index (PDI). The optimum CER-NP-loaded liposome was imagined by observing the encapsulation by using a confocal laser scanning microscope (CLSM) within fluorescently labeled CER-NP. The characteristic liquid crystalline phase and lipid chain conformation of CER-NP-loaded liposomes were determined using attenuated total reflectance infrared spectroscopy (ATR-IR). The CER-NP-loaded liposomes were imagined using a field emission scanning electron microscope (FE-SEM). Finally, the in vitro release of CER-NP from liposomes was examined using modified Franz Cells. The experimental and predicted results were well correlated. The CLSM images of optimized liposomes were conformable with the other studies, and the encapsulation efficiency of CER-NP was 93.84 ± 0.87%. ATR-IR analysis supported the characteristics of the CER-NP-loaded liposome. In addition, the lipid chain conformation shows similarity with skin barrier lipid organization. The release pattern of CER-NP liposomes was fitted with the Korsmeyer–Peppas model. The cytotoxicity studies carried out on HaCaT keratinocytes supported the idea that the liposomes for topical administration of CER-NP could be considered relatively safe. In conclusion, the optimized CER-NP-loaded liposomes could have the potential to restore the skin barrier function.
Ultra-Broadband and Compact 2 × 2 3-dB Silicon Adiabatic Coupler Based on Supermode-Injected Adjoint Shape Optimization
Authors: Chen Hongliang , Su Guangchen , Fu Xin , Yang Lin
Published: November 2023

The 2 × 2 3-dB couplers are one of the most widely used and important components in silicon photonics. Here, we propose an ultra-broadband and compact 2 × 2 3-dB adiabatic coupler defined by b-splines and optimized with an efficient supermode-injected adjoint shape optimization. By employing mode adiabatic evolution and mode coupling at two different wavelength ranges, respectively, we achieve an ultra-broad bandwidth of 530 nm from 1150 nm to1680 nm with a power imbalance below ±0.76 dB in a compact coupling length of 30 µm according to our simulation results. The supermode-injected adjoint shape optimization can also be applied to the design of other photonic devices based on supermode manipulation.
Numerical Investigation of Mechanical Performance and Micro-Structure Failure of Polymer-Fiber Reinforced Sand
Authors: Zhang Runqi , Huang Guojiao , Song Zezhuo , Zheng Jiaqiang , Wu Peng , Zhang Chenyang , Lu Yipin , Wang Zhengjie , Dai Chengjiang
Published: November 2023

Natural sand has a loose and porous structure with low strength, and is prone to many geoengineering problems that cause huge losses. In this study, an organic polymer-polymer-fiber blend was used to improve the strength of sand. Using a series of laboratory and numerical simulation tests, researchers have investigated the microdamage behavior of an organic polymer and fiber-treated sand in various types of mechanical tests and explored the improvement mechanism. The results showed that the polymer- and fiber-treated sand enhanced the integrity and exhibited differential damage responses under different test conditions. The increase in polymer content induced uniform force transfer, leading to a wider range of particle motion and crack initiation, whereas the fibers adhered and confined the surrounding particles, inducing an arching force chain and dispersive/buckling cracking. Polymer- and fiber-treated sands increased their energy-carrying capacity and improved their energy release, which affected the damage characteristics. Organic polymers, fibers, and sand particles were wrapped around each other to form an effective interlocking structure, which enhances the integrity and mechanical properties of sand. This study provides novel ideas and methods in the polymer-fiber composite treatment of sand in the microscopic field.
Effect of the Graphene Quantum Dot Content on the Thermal, Dynamic-Mechanical, and Morphological Properties of Epoxy Resin
Authors: Schneider Bárbara , Ornaghi Jr. Heitor Luiz , Monticeli Francisco Maciel , Romanzini Daiane
Published: November 2023

Different amounts of graphene quantum dots (CQDs) (0, 1, 2.5, and 5 wt%) were incorporated into an epoxy matrix. The thermal conductivity, density, morphology, and dynamic mechanical thermal (DMTA) properties were reused from the study of Seibert et al.. The Pearson plot showed a high correlation between mass loading, thermal conductivity, and thermal diffusivity. A poorer correlation with density and heat capacity was observed. At lower CQD concentrations (0.1 wt%), the fracture surface showed to be more heterogeneous, while at higher amounts (2.5 and 5 wt%), a more homogeneous surface was observed. The storage modulus values did not change with the CQD amount. But the extension of the glassy plateau increased with higher CQD contents, with an increase of ~40 °C for the 5 wt% compared to the 2.5 wt% and almost twice compared to the neat epoxy. This result is attributed to the intrinsic characteristics of the filler. Additionally, lower energy dissipation and a higher glass transition temperature were observed with the CQD amount. The novelty and importance are related to the fact that for more rigid matrices (corroborated with the literature), the mechanical properties did not change, because the polymer bridging mechanism was not present, in spite of the excellent CQD dispersion as well as the filler amount. On the other hand, thermal conductivity is directly related to particle size and dispersion.
Improvement of the Ductility of Environmentally Friendly Poly(lactide) Composites with Posidonia oceanica Wastes Plasticized with an Ester of Cinnamic Acid
Authors: Barandiaran Alejandro , Lascano Diego , Montanes Nestor , Balart Rafael , Selles Miguel Angel , Moreno Virginia
Published: November 2023

New composite materials were developed with poly(lactide) (PLA) and Posidonia oceanica fibers through reactive extrusion in the presence of dicumyl peroxide (DCP) and subsequent injection molding. The effect of different amounts of methyl trans–cinnamate (MTC) on the mechanical, thermal, thermomechanical, and wettability properties was studied. The results showed that the presence of Posidonia oceanica fibers generated disruptions in the PLA matrix, causing a decrease in the tensile mechanical properties and causing an impact on the strength due to the stress concentration phenomenon. Reactive extrusion with DCP improved the PO/PLA interaction, diminishing the gap between the fibers and the surrounding matrix, as corroborated by field emission scanning electron microscopy (FESEM). It was observed that 20 phr (parts by weight of the MTC, per one hundred parts by weight of the PO/PLA composite) led to a noticeable plasticizing effect, significantly increasing the elongation at break from 7.1% of neat PLA to 31.1%, which means an improvement of 338%. A considerable decrease in the glass transition temperature, from 61.1 °C of neat PLA to 41.6 °C, was also observed. Thermogravimetric analysis (TGA) showed a loss of thermal stability of the plasticized composites, mainly due to the volatility of the cinnamate ester, leading to a decrease in the onset degradation temperature above 10 phr MTC.
Determination of Tetracycline Antibiotics in Milk by Solid-Phase Extraction Using a Coordination Polymer Based on Cobalt Trimesinate as a Sorbent
Authors: Naumkina Victoria N. , Lyamina Veronika M. , Zhinzhilo Vladimir A. , Uflyand Igor E.
Published: November 2023

The coordination polymer was obtained based on cobalt trimesinate. It was characterized by elemental analysis, IR spectroscopy, X-ray diffraction analysis and scanning electron microscopy. The polymer was studied as a sorbent for solid-phase extraction of tetracycline antibiotics. Cobalt trimesinate had a high adsorption capacity (400 mg/g). Antibiotic adsorption followed the pseudo-second-order kinetic model and the Freundlich isotherm model. The process proceeded spontaneously, as indicated by the calculated thermodynamic parameters. The resulting coordination polymer has good stability and recyclability. The possibility of using cobalt trimesinate for the determination of tetracycline in various milk samples was investigated. This work holds great promise for the development and application of a cobalt trimesinate-based coordination polymer for use in sample preparation to replace the time-consuming vacuum evaporation procedure with a relatively simple solid-phase extraction procedure.
A Comparative Study of Resistant Dextrins and Resistant Maltodextrins from Different Tuber Crop Starches
Authors: Chen Xinyang , Hou Yinchen , Wang Zhen , Liao Aimei , Pan Long , Zhang Mingyi , Xue Yingchun , Wang Jingjing , Liu Yingying , Huang Jihong
Published: November 2023

The anti-digestibility of resistant dextrin (RD) and resistant maltodextrin (RMD) is usually significantly affected by processing techniques, reaction conditions, and starch sources. The objective of this investigation is to elucidate the similarities and differences in the anti-digestive properties of RD and RMD prepared from three different tuber crop starches, namely, potato, cassava, and sweet potato, and to reveal the associated mechanisms. The results show that all RMDs have a microstructure characterized by irregular fragmentation and porous surfaces, no longer maintaining the original crystalline structure of starches. Conversely, RDs preserve the structural morphology of starches, featuring rough surfaces and similar crystalline structures. RDs exhibite hydrolysis rates of approximately 40%, whereas RMDs displaye rates lower than 8%. This disparity can be attributed to the reduction of α-1,4 and α-1,6 bonds and the development of a highly branched spatial structure in RMDs. The indigestible components of the three types of RDs range from 34% to 37%, whereas RMDs vary from 80% to 85%, with potato resistant maltodextrin displaying the highest content (84.96%, p < 0.05). In conclusion, there are significant differences in the processing performances between different tuber crop starches. For the preparation of RMDs, potato starch seems to be superior to sweet potato and cassava starches. These attributes lay the foundation for considering RDs and RMDs as suitable components for liquid beverages, solid dietary fiber supplements, and low glycemic index (low-GI) products.
Facile Preparation of PVDF/CoFe2O4-ZnO Hybrid Membranes for Water Depollution
Authors: Popa Adriana , Stefan Maria , Macavei Sergiu , Perhaita Ioana , Tudoran Lucian Barbu , Toloman Dana
Published: November 2023

In this investigation, CoFe2O4-PVDF and CoFe2O4-ZnO-PVDF hybrid membranes were prepared using a modified phase inversion method in which a magnetic field was applied during the casting process to ensure a uniform distribution of nanomaterials on the membrane surface. Thus, better absorption of light and increased participation of nanoparticles in the photodegradation process is ensured. The influence of nanomaterials on the crystalline structure, surface morphology, and hydrophilicity properties of the PVDF membrane was investigated. The obtained results indicated that the hybrid membrane exhibited significant differences in its intrinsic properties due to the nanomaterials addition. The hydrophilicity properties of the PVDF membrane were improved by the presence of nanoparticles. The photocatalytic decomposition of aqueous Rhodamine B solution in the presence of the prepared membrane and under visible light irradiation was tested. The hybrid membrane containing CoFe2O4-ZnO on its surface exhibited a high removal rate.
Will There Be Teachers? An Analysis of the Congruence of Religious Beliefs of Initial Teacher Education Students and the Patron’s (Religious Education) Programme for Catholic Schools
Authors: O’Connell Daniel , Harmon Maurice , Meehan Amalee
Published: November 2023

For historical reasons, the vast majority of primary schools in the Republic of Ireland are under the patronage of the Catholic church. Patronage involves a number of responsibilities, including the provision of a Patron’s Programme. Traditionally in the form of Religious Education (RE), such programmes should satisfy the curricular requirement for religious/ethical education and act as an expression of school ethos. In order to meet this responsibility, the Irish Episcopal conference in 2015 published its first curriculum in Religious Education, which forms the basis for the Grow in Love programme for pupils from Junior Infants to Sixth Class in all Catholic primary schools. However, effective teaching and learning of RE is dependent on the ‘buy in’ of those teaching it. The religious beliefs, understandings, and practices of those teaching RE are influential in this regard. Drawing from the data of a large-scale, multi-phase study, this paper describes the religious identity and beliefs of first-year students entering an Initial Teacher Education programme in Ireland—in this case, the Bachelor of Education (BEd) degree—to qualify as primary-level teachers. It situates the data in the wider context of religious identity and beliefs in Ireland and goes on to explore how the religious profiles of these students fit with the required understanding, knowledge and ability to teach Religious Education in Catholic schools. Findings indicate that the majority of these students identify as Catholic and believe in God. For most, God is important in their lives. However, there is a complexity to these beliefs, with a significant number who do not know what to think. This paper concludes with a discussion of the implications of these findings for the teaching of Religious Education and for the patrons of Catholic schools.
Remote Sensing Image Super-Resolution via Multi-Scale Texture Transfer Network
Authors: Wang Yu , Shao Zhenfeng , Lu Tao , Huang Xiao , Wang Jiaming , Chen Xitong , Huang Haiyan , Zuo Xiaolong
Published: November 2023

As the degradation factors of remote sensing images become increasingly complex, it becomes challenging to infer the high-frequency details of remote sensing images compared to ordinary digital photographs. For super-resolution (SR) tasks, existing deep learning-based single remote sensing image SR methods tend to rely on texture information, leading to various limitations. To fill this gap, we propose a remote sensing image SR algorithm based on a multi-scale texture transfer network (MTTN). The proposed MTTN enhances the texture feature information of reconstructed images by adaptively transferring texture information according to the texture similarity of the reference image. The proposed method adopts a multi-scale texture-matching strategy, which promotes the transmission of multi-scale texture information of remote sensing images and obtains finer-texture information from more relevant semantic modules. Experimental results show that the proposed method outperforms state-of-the-art SR techniques on the Kaggle open-source remote sensing dataset from both quantitative and qualitative perspectives.
Crustal Imaging across the Princess Elizabeth Land, East Antarctica from 2D Gravity and Magnetic Inversions
Authors: Li Lin , Xiao Enzhao , Wei Xiaolong , Qiu Ning , Latif Khalid , Guo Jingxue , Sun Bo
Published: November 2023

The Princess Elizabeth Land landscape in East Antarctica was shaped by a complex process, involving the supercontinent’s breakup and convergence cycle. However, the lack of geological knowledge about the subglacial bedrock has made it challenging to understand this process. Our study aimed to investigate the structural characteristics of the subglacial bedrock in the Mount Brown region, utilizing airborne geophysical data collected from the China Antarctic Scientific Expedition in 2015–2017. We reconstructed bedrock density contrast and magnetic susceptibility models by leveraging Tikhonov regularized gravity and magnetic inversions. The deep bedrock in the inland direction exhibited different physical properties, indicating the presence of distinct basement sources. The east–west discontinuity of bedrock changed in the inland areas, suggesting the possibility of large fault structures or amalgamation belts. We also identified several normal faults in the western sedimentary basin, intersected by the southwest section of these survey lines. Furthermore, lithologic separators and sinistral strike-slip faults may exist in the northeast section, demarcating the boundary between Princess Elizabeth Land and Knox Valley. Our study provides new insights into the subglacial geological structure in this region, highlighting the violent impact of the I-A-A-S (Indo-Australo-Antarctic Suture) on the subglacial basement composition. Additionally, by identifying and describing different bedrock types, our study redefines the potential contribution of this region to the paleocontinent splicing process and East Antarctic basement remodeling.
Forecasting the Propagation from Meteorological to Hydrological and Agricultural Drought in the Huaihe River Basin with Machine Learning Methods
Authors: Hao Ruonan , Yan Huaxiang , Chiang Yen-Ming
Published: November 2023

Revealing the mechanism of hydrological and agricultural drought has been challenging and vital in the environment under extreme weather and water resource shortages. To explore the evolution process from meteorological to hydrological and agricultural drought further, multi-source remote sensing data, including the Gravity Recovery and Climate Experiment (GRACE) product, were collected in the Huaihe River basin of China during 2002–2020. Three machine learning methods, including long short-term memory neural network (LSTM), convolutional neural network (CNN), and categorical boosting (CatBoost), were constructed for hydrological and agricultural drought forecasting. The propagation time from meteorological drought to surface water storage and terrestrial water storage drought, evaluated by the standardized precipitation evapotranspiration index, was 8 and 11 months with Pearson correlation coefficients (R) of 0.68 and 0.48, respectively. Groundwater storage drought was correlated with evapotranspiration and vegetation growth with a 12-month lag time, respectively. In addition, vegetation growth was affected by the drought of soil moisture at depths ranging from 100 to 200 cm with an 8-month lag time with an R of −0.39. Although the forecasting performances of terrestrial water storage drought were better than those of groundwater storage drought and agricultural drought, CNN always performed better than LSTM and CatBoost models, with Nash–Sutclife efficiency values during testing ranging from 0.28 to 0.70, 0.26 to 0.33, and −0.10 to −0.40 for terrestrial water storage drought, groundwater storage drought, and agricultural drought at lead times of 0–3 months, respectively. Furthermore, splitting training and testing data at random significantly improved the performances of CNN and CatBoost methods for drought forecasting rather than in chronological order splitting for non-stationary data.
Inpainting Saturation Artifact in Anterior Segment Optical Coherence Tomography
Authors: Li Jie , Zhang He , Wang Xiaoli , Wang Haoming , Hao Jingzi , Bai Guanhua
Published: November 2023

The cornea is an important refractive structure in the human eye. The corneal segmentation technique provides valuable information for clinical diagnoses, such as corneal thickness. Non-contact anterior segment optical coherence tomography (AS-OCT) is a prevalent ophthalmic imaging technique that can visualize the anterior and posterior surfaces of the cornea. Nonetheless, during the imaging process, saturation artifacts are commonly generated due to the tangent of the corneal surface at that point, which is normal to the incident light source. This stripe-shaped saturation artifact covers the corneal surface, causing blurring of the corneal edge, reducing the accuracy of corneal segmentation. To settle this matter, an inpainting method that introduces structural similarity and frequency loss is proposed to remove the saturation artifact in AS-OCT images. Specifically, the structural similarity loss reconstructs the corneal structure and restores corneal textural details. The frequency loss combines the spatial domain with the frequency domain to ensure the overall consistency of the image in both domains. Furthermore, the performance of the proposed method in corneal segmentation tasks is evaluated, and the results indicate a significant benefit for subsequent clinical analysis.
Combining Feature Selection Techniques and Neurofuzzy Systems for the Prediction of Total Viable Counts in Beef Fillets Using Multispectral Imaging
Authors: Alshejari Abeer , Kodogiannis Vassilis S. , Leonidis Stavros
Published: November 2023

In the food industry, quality and safety issues are associated with consumers’ health condition. There is a growing interest in applying various noninvasive sensorial techniques to obtain quickly quality attributes. One of them, hyperspectral/multispectral imaging technique has been extensively used for inspection of various food products. In this paper, a stacking-based ensemble prediction system has been developed for the prediction of total viable counts of microorganisms in beef fillet samples, an essential cause to meat spoilage, utilizing multispectral imaging information. As the selection of important wavelengths from the multispectral imaging system is considered as an essential stage to the prediction scheme, a features fusion approach has been also explored, by combining wavelengths extracted from various feature selection techniques. Ensemble sub-components include two advanced clustering-based neuro-fuzzy network prediction models, one utilizing information from average reflectance values, while the other one from the standard deviation of the pixels’ intensity per wavelength. The performances of neurofuzzy models were compared against established regression algorithms such as multilayer perceptron, support vector machines and partial least squares. Obtained results confirmed the validity of the proposed hypothesis to utilize a combination of feature selection methods with neurofuzzy models in order to assess the microbiological quality of meat products.
Impact of the Smoking Process on Biogenic Amine Levels in Traditional Dry-Cured Chorizo
Authors: Valente Inês M. , Sousa Cláudia S. , Guido Luís F.
Published: November 2023

This study aimed to investigate the influence of various production stages on the quality and spoilage conditions of traditionally dry-cured chorizo. To accomplish this, we employed an experimental design that examined three key production parameters: the batch, the filling stage, and the food smoking process. The study was conducted in collaboration with a local producer who adheres to traditional curing methods utilizing oak wood smoke and heat. Biogenic amine levels were closely monitored throughout the process. This involved their extraction and derivatization through the salting-out technique, followed by identification and quantification using LC-ESI/MSn and HPLC-DAD, respectively. The findings suggest that both raw materials and the production process are well controlled during the filling stage. However, it became evident that the 14-day oak wood smoking period had a significant impact on biogenic amine formation, whose total mean values increased from 126 to 1385 mg kg−1, particularly with respect to putrescine (PUT), cadaverine (CAD), and tyramine (TYR), although these levels remained below the oral toxicity limit (2000 mg kg−1). Consequently, the concentration of these compounds can influence the quality and safety of traditionally dry-cured chorizos. Therefore, the combined levels of PUT, CAD, and TYR can serve as a valuable quality indicator for these products.
Nearly Linear-Phase 2-D Recursive Digital Filters Design Using Balanced Realization Model Reduction
Authors: Omar Abdussalam , Shpak Dale , Agathoklis Panajotis
Published: November 2023

This paper presents a new method for the design of separable-denominator 2-D IIR filters with nearly linear phase in the passband. The design method is based on a balanced realization model reduction technique. The nearly linear-phase 2-D IIR filter is designed using 2-D model reduction from a linear-phase 2-D FIR filter, which serves as the initial filter. The structured controllability and observability Gramians Ps and Qs serve as the foundation for this technique. onal positive-definite matrices that satisfy 2-D Lyapunov equations. An efficient method is used to compute these Gramians by minimizing the traces of Ps and Qs under linear matrix inequality (LMI) constraints. The use of these Gramians ensures that the resulting 2-D IIR filter preserves stability and can be implemented using a separable-denominator 2-D filter with fewer coefficients than the original 2-D FIR filter. Numerical examples show that the proposed method compares favorably with existing techniques.
Environmental Impact Analysis of Residential Energy Solutions in Latvian Single-Family Houses: A Lifecycle Perspective
Authors: Kramens Janis , Feofilovs Maksims , Vigants Edgars
Published: November 2023

This study aims to compare the technological solutions that can contribute to more sustainable energy use in the residential sector. Specifically, the goal of the study is to evaluate the environmental impact of different energy (heat and electricity) supply technologies applicable for an average size single-family building in Latvia, a country known for climatic condition characterized by cold winters with frequent snowfall. The study applies the lifecycle assessment methodology of ISO 14040 and the impact assessment method known as ReCiPe 2016 v1.1, which has not been used before for the scope addressed in the study in the context of single-family building energy supply technologies for climatic conditions in Latvia. Thus, the results of the study will provide new information for more sustainable energy solutions in this area of study. The technologies included in the defined scenarios are conventional boiler, electricity from the grid, Stirling engine, and solar photovoltaics (PV). The results of the lifecycle impact assessment for damage categories revealed that all scenarios have a high impact on human health due to fine particulate matter formation followed by global warming. Regarding the damage to the ecosystem, the terrestrial ecotoxicity category has highest impact, followed by global warming. Sensitivity analyses affirmed the model’s validity and also showed that the impacts of conventional systems were most sensitive to changes in electricity consumption, and therefore, the scenarios with electricity supply from a Stirling engine or PV can be considered a more robust solution under changing electricity demands from an environmental perspective.
The Relationship between Physical Fitness and Cognitive Functions in Older People: A Systematic Review
Authors: Tinôco Maria Antonieta , Nascimento Marcelo de Maio , Marques Adilson , Gouveia Élvio Rúbio , Miguel Salvador , Santos Francisco , Ihle Andreas
Published: November 2023

The ageing process is associated with vulnerabilities, such as cognitive decline. Physical activity and exercise are key for preserving cognitive health in older age. This systematic review aims to analyse the effects of physical fitness programs on healthy older adults’ cognitive functions. An electronic search was performed in the PubMed, Web of Science, and Scopus databases. It included observational and experimental studies published between February 2017 and March 2023. Of the 1922 studies identified, 38 met the inclusion criteria. The findings show the positive effects of physical training on cognitive function in older adults. The most examined cognitive domains were executive function, memory function, and global cognition. Aerobic training prevailed, followed by resistance strength training and exergames. There was high variability in the characteristics of the protocols. The average length of interventions was 3–6 months; the frequency varied in the range of 1–4-times a week and 30–90 min sessions. The findings of this systematic review emphasise that physical fitness programs positively improve the specific domains of cognitive function in healthy older adults. These results can contribute to planning future interventions to improve the mental health of the older population and strengthen the development of policies for healthy ageing.
Automated Monitoring of the Uniform Demagnetization Faults in Permanent-Magnet Synchronous Motors: Practical Methods and Challenges
Authors: Li Junxiang , Li Ziang , Zhang Jian , Zhao Shuyuan , Cheng Feitian , Qian Chuan , Hu Xingyu , Zhou Guoxiang
Published: November 2023

Due to its high power, high efficiency, low pollution, and compact size, permanent-magnet synchronous motors (PMSMs) have been widely used in a variety of fields, including electric vehicles, aerospace, wind turbines, and marine devices, which are used in renewable, sustainable, and environmentally friendly energy resources. However, in these practical scenarios, the motor operating conditions are complex and variable. Under high-temperature and high-current conditions, PMSMs may experience demagnetization failures, not only leading to performance degradation but also inducing unexpected failures of the motors. To reduce the risk of unexpected losses caused by demagnetization faults and improve the safety and reliability of motor systems, it is necessary to apply automated monitoring of the magnet flux of the motor’s permanent magnets and achieve real-time diagnosis of early demagnetization faults, ensuring the safe operation of the motor. This review article tries to summarize the current detection methods of the automated monitoring of demagnetization faults in PMSMs. The main online monitoring technologies from both practical and academic perspectives are summarized and their benefits and challenges are reviewed. Finally, the research trends and suggestions for future improvements are provided. This review article not only sheds light on the origins of the automated monitoring of demagnetization faults but also helps to design highly effective and sustainable permanent-magnet synchronous motors.