bluuebunny/crossref_metadata_2025 huggingface dataset:
Changes in Economic Network Patterns and Influencing Factors in the Urban Agglomeration of Guangdong–Hong Kong–Macao Greater Bay Area: A Comprehensive Study
Authors: Li Ruipu , Yu Bo , Wang Qun , Wu Gang , Ma Zhiyu
Published: April 2024

The aim of this study is to comprehensively evaluate the economic network patterns and their influencing factors of the Guangdong–Hong Kong–Macao Greater Bay Area (GHMGBA) in China, considering population scale, economic development level, and land-resource endowment. By employing a modified gravity model and a social-network method, we quantitatively analyzed urban agglomeration integrity indices, such as network density, edge–core structure, cohesive-subgroup index, and urban individual index (e.g., centrality degree) of this region, encompassing nine cities in Guangdong Province and two special administrative regions. The results revealed significant changes in the economic network patterns within the GHMGBA over time. Furthermore, the quadratic assignment procedure correlation analysis index was used to identify the various factors affecting the strength of the economic interaction. The findings demonstrated an annual increase in the strength of economic interaction between cities and regions within the GHMGBA over the past 20 years, along with the emergence of a polycentric economic development pattern. The results also suggest that the spatial location and level of economic development are key determinants influencing the strength of economic linkages in this area. This study supports the conclusion that deepening exchanges and cooperation among core cities, bolstering economic development in sub-core cities, and facilitating the construction of an integrated regional transportation network will expedite the process of economic integration.
Metal–Organic Frameworks-Derived FeCo/C–CNT Nanocomposites Modified Epoxy Resin for Electromagnetic Protection Coatings for Buildings
Authors: Lei Dongyi , Liu Jiaxin , Liu Chengkan , Dong Chunlei , Yang Donglei , Li Ying , Zhang Jiqing , Han Feizi , Guo Zihan
Published: April 2024

Exploring an efficient electromagnetic protection strategy for buildings is of great significance to solve the problems caused by increasing electromagnetic pollution, as the rapid progress of technology continues. In this work, FeCo alloy/carbon–carbon nanotube (FeCo/C–CNT) nanocomposites, with significant microwave absorption performance, were successfully synthesized using a simple pyrolysis method involving FeCo–ZIF MOFs precursors and added to epoxy resin to prepare a novel electromagnetic wave absorption (EWA) coating. The minimum reflection loss (RLmin) of the coating applied on the surface of the ceramic tiles was −23.89 dB at 11.37 GHz and the effective absorption bandwidth (EAB) reached 8.85 GHz. Through microscopic characterization and analysis of the electromagnetic parameters of the FeCo/C–CNT nanocomposites, it was found that the EWA coating has an ultrabroad band wave absorption effect, mainly due to the comprehensive advantages of the polarization loss from CNTs, impedance matching, the dual loss synergy effect, and multiple reflection between the FeCo alloys, the carbon layer, and the CNTs. This study has successfully developed high-performance EWA materials and demonstrated the feasibility of an EWA coating applied to building surfaces, contributing to the improvement of electromagnetic protection functions of buildings.
Compressive Behaviors of High-Strength Geopolymeric Concretes: The Role of Recycled Fine Aggregate
Authors: Zhong Huaicheng , Fu Huanchang , Feng Yuan , Li Liming , Zhang Baifa , Chen Zhanbiao , Lu Zhongyu , Xie Jianhe
Published: April 2024

In this study, natural fine aggregates (NFAs) in high-strength fly ash (FA)/ground granulated blast furnace slag (GGBFS)-based geopolymer concretes were both partially and completely replaced by RFAs to prepare geopolymer recycled fine aggregate concrete (GRFC). Herein, the impacts of RFA content (0%, 25%, 50%, 75%, and 100%) on the fresh and hardened performance and microstructural characteristics of a GRFC were investigated. The results indicated that with increasing RFA substitution ratio, the setting time of the GRFC decreases. In addition, the compressive strength and elastic modulus decrease. However, owing to the enhanced adhesion of the geopolymer matrix and recycled aggregate, RFA has a relatively small impact on the compressive strength, with a maximum strength loss of 9.7% at a replacement level of 75%. When the RFA content is less than 75%, the internal structure of the concrete remains relatively compact. The incorporation of RFA in concrete has been found to adversely affect its compressive strength and elastic modulus, while simultaneously increasing its brittleness. The increase in dosage of RFA leads to a reduction in the compressive strength and elastic modulus of concrete, while partial failure occurs when the GRFC constitutes 100% of the RFA. The existing stress–strain model for conventional concrete is recalibrated for the GRFC. Observed by SEM, with increasing RFA, the damage is mainly concentrated at the interface associated with the attached cement. Although the recalibrated model predicts the stress–strain responses of the GRFC reasonably well, an acceptable range of deviation is present when predicting the residual stress due to the relatively high strength and brittle behavior of the GRFC during compression. Through this research, the applicability of RFA is expanded, making it feasible to apply large quantities of this material.
Research on the Pressure Distribution Law of Synchronous Grouting in Shield Tunnels and the Force on Segments
Authors: Cheng Yang , Liu Xiangyang
Published: April 2024

The pressure distribution and the force on tunnel segments of synchronous grouting in the shield tail gap channel of shield tunnels are key to controlling the stability and surface settlement of the strata surrounding such tunnels. Based on the basic principles of fluid mechanics and the limit equilibrium method, this study establishes a mathematical model of synchronous grouting in shield tunnels, derives the expressions of the grouting pressure and the force on tunnel segments in the shield tail gap channel, and verifies them using an engineering case study. Studies have shown that the force on tunnel segments and the speed of shield excavation are increasing. An excessive shield excavation speed will cause the load on tunnel segments to increase, which exacerbates the uneven distribution of the grouting pressure. The force on tunnel segments and the grouting pressure also have a positive relationship with the thickness of the shield tail gap, but the impact is limited to a certain range. With an increase in the tunnel radius, the number of grouting holes should be appropriately increased to balance the water and soil pressure in the surrounding strata. These research results can provide a theoretical reference for the design of synchronous grouting for shield tunnels in the future.
Experimental Evaluation of Noise Exposure Effects on Subjective Perceptions and Cognitive Performance
Authors: Zhang Jie , Pang Liping , Yang Chenyuan , Fan Yurong , Zhao Bingxu , Cao Xiaodong
Published: April 2024

Individuals exposed to elevated noise levels experience heightened emotional intensity, leading to increased cognitive disruption and a higher likelihood of accidents. This study seeks to investigate the impact of noise exposure on human cognitive performance, and the moderating role of emotion. Twelve healthy male college-age students underwent exposure to three noise conditions, each characterized by different sound pressure levels and sharpness. Each condition included an initial acoustic/thermal adaption period lasting approximately 40 min, followed by intermittent questionnaire tests and a battery of computerized cognitive tests. Statistical analysis revealed that reducing noise levels proved advantageous, enhancing perceived sound quality, positive emotions, and auditory perception abilities, while concurrently reducing false alerts and accelerating execution speed. Many of these effects were found to be counteracted by elevated sharpness. Correlation analyses and partial least squares structural equation modeling (PLS-SEM) results suggested that human emotions mediate the relationship between noise exposure and cognitive performance. The potential underlying mechanism suggests that negative feelings towards noise contribute to poor emotional states, subsequently influencing cognitive processes and impairing executive function. The outcomes of this study provide valuable insights into the mechanism of noise exposure and its effects on human cognition and subjective perceptions.
Non-Destructive Testing and Synergistic Investigation of a Historic Tower
Authors: Saisi Antonella , Borlenghi Paolo , Gentile Carmelo
Published: April 2024

This paper focuses on the reliability of a synergistic procedure, involving dynamic tests complemented by documentary and architectural research, for the structural assessment of heritage towers. The reliability of the presented method is exemplified in a relevant case study, the Zuccaro’s Tower in Mantua. As is known, historic buildings require addressed procedures in order to consider past building transformation and eventual damage/decay, which can affect the masonry properties and, more generally, the structural behavior. The proposed investigation procedure is based on multidisciplinary information (i.e., merging data) from historical and document studies, direct inspections, surveys of geometry and front surfaces, and dynamic tests in operational conditions. The processed information allowed the development and the calibration of a simplified numerical model, useful in driving the seismic/structural assessment of the tower. The results of past investigations, found during the archival research, contributed to the structural evaluation. This paper describes the main research outcomes and the model tuning with a special focus on the key role of the synergy between the applied methods for the assessment of a historic building.
Experimental Study on Repairing/Restoration and Reinforcement Methods of the Reinforced Concrete Structures Damaged by Earthquakes
Authors: Ni Guowei , Zhang Wanying , Song Congbo , Wang Zirui , Liu Bo
Published: April 2024

For earthquake-damaged reinforced concrete structures, the static loading test method is adopted to carry out loading tests under cyclic loading on reinforced concrete beams with different reinforcement rates and columns with different axial compression ratios, and the effect of reinforcing and repairing the damaged reinforced concrete structure by using adhesive steel plates and carbon fiber cloth is investigated. Through comparative studies of structural hysteresis curves and skeleton curves under different reinforcement methods, it is concluded that reinforcement has significantly improved the hysteresis characteristics and ductility of members, and the seismic performance of the carbon fiber reinforcement method is better than that of the steel plate reinforcement. This study provides valuable references and suggestions for practical earthquake-damaged building reinforcement and repair works and seismic reinforcement works.
Effect of High Temperatures on Mechanical and Shielding Properties of Lead–Zinc Tailings Concrete for Radiation Protection
Authors: Wang Minghui , Chen Zhenfu , Tao Qiuwang , Yang Yan’e , Xie Liping , Wu Dan , Jin Dan , Luo Lincheng
Published: April 2024

Due to the high prices, the popularity of radiation shielding concrete (RSC) has been greatly limited. To solve this, this research reused the lead–zinc tailings (LZT) as a fine aggregate replacement ranging from 0% to 60% for the RSC. The results revealed that the RSC containing 30% LZT presented better workability and achieved 95.84% of the compressive strength and 98.49% of the linear attenuation coefficient of the RSC, and reached the highest splitting tensile strength values, which increased by 4.43%. Meanwhile, after the heat treatments, there were favorable correlations between the relative velocity and relative strength, as well as between the damage index and the relative linear attenuation coefficient, which could accurately reflect the degradation of not only the mechanical but also the shielding properties. Considering the temperature and shielding thickness, the reuse of LZT can bring considerable economic and environmental benefits.
XPC Protects against Carcinogen-Induced Histologic Progression to Lung Squamous Cell Carcinoma by Reduced Basal Epithelial Cell Proliferation
Authors: Sears Catherine R. , Zhou Huaxin , Hulsey Emily , Aidoo Bea A. , Sandusky George E. , Al Nasrallah Nawar
Published: April 2024

Lung squamous cell carcinoma (LUSC) is the second leading cause of lung cancer. Although characterized by high DNA mutational burdens and genomic complexity, the role of DNA repair in LUSC development is poorly understood. We sought to better understand the role of the DNA repair protein Xeroderma Pigmentosum Group C (XPC) in LUSC development. XPC knock-out (KO), heterozygous, and wild-type (WT) mice were exposed topically to N-nitroso-tris-chloroethylurea (NTCU), and lungs were evaluated for histology and pre-malignant progression in a blinded fashion at various time-points from 8–24 weeks. High-grade dysplasia and LUSC were increased in XPC KO compared with XPC WT NTCU mice (56% vs. 34%), associated with a higher mean LUSC lung involvement (p < 0.05). N-acetylcysteine pre-treatment decreased bronchoalveolar inflammation but did not prevent LUSC development. Proliferation, measured as %Ki67+ cells, increased with NTCU treatment, in high-grade dysplasia and LUSC, and in XPC deficiency (p < 0.01, ANOVA). Finally, pre-LUSC dysplasia developed earlier and progressed to higher histologic classification sooner in XPC KO compared with WT mice. Overall, this supports the protective role of XPC in squamous dysplasia progression to LUSC. Mouse models of early LUSC development are limited; this may provide a valuable model to study mechanisms of LUSC development and progression.
The Performance of Different Parametric Ultrasounds in Prostate Cancer Diagnosis: Correlation with Radical Prostatectomy Specimens
Authors: Jawli Adel , Nabi Ghulam , Huang Zhihong
Published: April 2024

Background: Prostate cancer is a prevalent cancer among men. Multiparametric ultrasound [mpUS] is a diagnostic instrument that uses various types of ultrasounds to diagnose it. This systematic review aims to evaluate the performance of different parametric ultrasounds in diagnosing prostate cancer by associating with radical prostatectomy specimens. Methodology: A review was performed on various ultrasound parameters using five databases. Systematic review tools were utilized to eliminate duplicates and identify relevant results. Reviewers used the Quality Assessment of Diagnostic Accuracy Results [QUADAS-2] to evaluate the bias and applicability of the study outcomes. Result: Between 2012 and 2023, eleven studies were conducted to evaluate the performance of the different ultrasound parametric procedures in detecting prostate cancer using grayscale TRUS, SWE, CEUS, and mpUS. The high sensitivity of these procedures was found at 55%, 88.6%, 81%, and 74%, respectively. The specificity of these procedures was found to be 93.4%, 97%, 88%, and 59%, respectively. This high sensitivity and specificity may be associated with the large lesion size. The studies revealed that the sensitivity of these procedures in diagnosing clinically significant prostate cancer was 55%, 73%, 70%, and 74%, respectively, while the specificity was 61%, 78.2%, 62%, and 59%, respectively. Conclusions: The mpUS procedure provides high sensitivity and specificity in PCa detection, especially for clinically significant prostate cancer.
Measurable (Minimal) Residual Disease in Myelodysplastic Neoplasms (MDS): Current State and Perspectives
Authors: Zhang Linsheng , Deeb George , Deeb Kristin K. , Vale Colin , Peker Barclift Deniz , Papadantonakis Nikolaos
Published: April 2024

Myelodysplastic Neoplasms (MDS) have been traditionally studied through the assessment of blood counts, cytogenetics, and morphology. In recent years, the introduction of molecular assays has improved our ability to diagnose MDS. The role of Measurable (minimal) Residual Disease (MRD) in MDS is evolving, and molecular and flow cytometry techniques have been used in several studies. In this review, we will highlight the evolving concept of MRD in MDS, outline the various techniques utilized, and provide an overview of the studies reporting MRD and the correlation with outcomes.
Type I Diabetes Mellitus Suppresses Experimental Skin Carcinogenesis
Authors: Giakoumaki Maria , Lambrou George I. , Vlachodimitropoulos Dimitrios , Tagka Anna , Vitsos Andreas , Kyriazi Maria , Dimakopoulou Aggeliki , Anagnostou Vasiliki , Karasmani Marina , Deli Heleni , Grigoropoulos Andreas , Karalis Evangelos , Rallis Michail Christou , Black Homer S.
Published: April 2024

This study explores the previously uncharted territory of the effects of ultraviolet (UV) radiation on diabetic skin, compared to its well-documented impact on normal skin, particularly focusing on carcinogenesis and aging. Employing hairless SKH-hr2, Type 1 and 2 diabetic, and nondiabetic male mice, the research subjected these to UV radiation thrice weekly for eight months. The investigation included comprehensive assessments of photoaging and photocarcinogenesis in diabetic versus normal skin, measuring factors such as hydration, trans-epidermal water loss, elasticity, skin thickness, melanin, sebum content, stratum corneum exfoliation and body weight, alongside photo documentation. Additionally, oxidative stress and the presence of hydrophilic antioxidants (uric acid and glutathione) in the stratum corneum were evaluated. Histopathological examination post-sacrifice provided insights into the morphological changes. Findings reveal that under UV exposure, Type 1 diabetic skin showed heightened dehydration, thinning, and signs of accelerated aging. Remarkably, Type 1 diabetic mice did not develop squamous cell carcinoma or pigmented nevi, contrary to normal and Type 2 diabetic skin. This unexpected resistance to UV-induced skin cancers in Type 1 diabetic skin prompts a crucial need for further research to uncover the underlying mechanisms providing this resistance.
Biodiesel Production via Transesterification Reaction over Mono- and Bimetallic Copper-Noble Metal (Pt, Ru) Catalysts Supported on BEA Zeolite
Authors: Szkudlarek Łukasz , Chałupka-Śpiewak Karolina , Maniukiewicz Waldemar , Albińska Jadwiga , Szynkowska-Jóźwik Małgorzata Iwona , Mierczyński Paweł
Published: April 2024

This work focuses on the study of biodiesel production from commercial rapeseed oil and methanol via transesterification reactions on monometallic copper and bimetallic copper–noble metal (platinum, ruthenium) catalysts supported on BEA zeolite. The catalysts were prepared by wet impregnation method on the hydrogen form of BEA zeolite. As part of the study, the physicochemical and catalytic properties of the prepared catalytic materials were determined. The catalytic activity tests were carried out in the transesterification reaction over prepared catalysts at 220 °C for 2 h in an autoclave. The physicochemical properties of the obtained catalysts were investigated by X-ray diffraction (XRD), specific surface area and porosity (BET), a scanning electron microscope equipped with an energy dispersive spectrometer (SEM–EDS) and temperature-programmed desorption of ammonia (TPD-NH3) method. The results of the catalytic activity showed the promotional effect of the noble metal on the TG conversion and FAME efficiency of copper catalysts in the biodiesel production process. The most active catalyst turned out to be the calcined 5%Cu–1%Ru/BEA catalyst, which showed the highest TG conversion of 85.7% and the second highest FAME efficiency of 58.4%. The high activity of this system is explained by its surface acidity and large specific surface area.
Investigation into the Exciton Binding Energy of Carbon Nitrides on Band Structure and Carrier Concentration through the Photoluminescence Effect
Authors: Lin Zhiyou , Cai Xu , Lin Wei
Published: April 2024

Carbon nitrides form a series of polymer semiconductors popular in photocatalysis. In the course of photoresponse, the separation of light-induced electron–hole pairs is one of the critical factors that affect the conversion rate from photoenergy to chemical substance. Exciton binding energy (Eb) is treated as a classical parameter to evaluate the barrier of exciton dissociation. In this work, we study the electronic and optical nature of two specific members of the carbon nitride family, polymeric carbon nitride (melon) and crystallized poly(triazine imide) (PTI/Li+Cl−) by employing the photoluminescence spectra and density functional theory (DFT) calculations based on the Wannier-Mott exciton module. The results of self-consistent GW computation were applied. The measurement of photoluminescence spectra, by which exciton binding energies are estimated, is likewise discussed. Generally, compared with the results calculated by GW-BSE, the DFT results based on the Wannier-Mott model are closer to the experimental values. From a materials perspective, on the other hand, the exciton binding energy of the melon is lower than that of PTI/Li+Cl−.
Visible-Light-Photocatalyzed C5-H Nitration of 8-Aminoquinoline Amides
Authors: Liu Pugen , Qiao Huijie , Su Xiaoxue , Bai Peirong , Yang Fan
Published: April 2024

A mild and efficient protocol for visible-light-photocatalyzed C5 nitration of 8-aminoquinoline derivatives was developed utilizing Cu(NO3)2∙3H2O as a nitro source. The reaction proceeded smoothly under very mild conditions, employing Acid Red 94 and a commercial household light bulb as an organic photosensitizer and a light source, respectively, making this synthetic procedure green and easy to operate. Furthermore, most products could be obtained through recrystallization, which enhanced the operational simplicity of this method.
Identity and Maturity of iPSC-Derived Oligodendrocytes in 2D and Organoid Systems
Authors: Zeldich Ella , Rajkumar Sandeep
Published: April 2024

Oligodendrocytes originating in the brain and spinal cord as well as in the ventral and dorsal domains of the neural tube are transcriptomically and functionally distinct. These distinctions are also reflected in the ultrastructure of the produced myelin, and the susceptibility to myelin-related disorders, which highlights the significance of the choice of patterning protocols in the differentiation of induced pluripotent stem cells (iPSCs) into oligodendrocytes. Thus, our first goal was to survey the different approaches applied to the generation of iPSC-derived oligodendrocytes in 2D culture and in organoids, as well as reflect on how these approaches pertain to the regional and spatial fate of the generated oligodendrocyte progenitors and myelinating oligodendrocytes. This knowledge is increasingly important to disease modeling and future therapeutic strategies. Our second goal was to recap the recent advances in the development of oligodendrocyte-enriched organoids, as we explore their relevance to a regional specification alongside their duration, complexity, and maturation stages of oligodendrocytes and myelin biology. Finally, we discuss the shortcomings of the existing protocols and potential future explorations.
Inhibition of Immunoproteasome Attenuates NLRP3 Inflammasome Response by Regulating E3 Ubiquitin Ligase TRIM31
Authors: Lee Yubin , Yoon Boran , Son Sumin , Cho Eunbin , Kim Kyung Bo , Choi Eun Young , Kim Dong-Eun
Published: April 2024

Excessive secretion of pro-inflammatory cytokines leads to the disruption of intestinal barrier in inflammatory bowel disease (IBD). The inflammatory cytokine tumor necrosis factor alpha (TNFα) induces the assembly of the NLRP3 inflammasome, resulting in the augmented secretion of inflammatory cytokines implicated in the pathogenesis of inflammatory bowel disease (IBD). TNFα has also been known to induce the formation of immunoproteasome (IP), which incorporates immunosubunits LMP2, LMP7, and MECL-1. Inhibition of IP activity using the IP subunit LMP2-specific inhibitor YU102, a peptide epoxyketone, decreased the protein levels of NLRP3 and increased the K48-linked polyubiquitination levels of NLRP3 in TNFα-stimulated intestinal epithelial cells. We observed that inhibition of IP activity caused an increase in the protein level of the ubiquitin E3 ligase, tripartite motif-containing protein 31 (TRIM31). TRIM31 facilitated K48-linked polyubiquitination and proteasomal degradation of NLRP3 with an enhanced interaction between NLRP3 and TRIM31 in intestinal epithelial cells. In addition, IP inhibition using YU102 ameliorated the symptoms of colitis in the model mice inflicted with dextran sodium sulfate (DSS). Administration of YU102 in the DSS-treated colitis model mice caused suppression of the NLRP3 protein levels and accompanied inflammatory cytokine release in the intestinal epithelium. Taken together, we demonstrated that inhibiting IP under inflammatory conditions induces E3 ligase TRIM31-mediated NLRP3 degradation, leading to attenuation of the NLRP3 inflammatory response that triggers disruption of intestinal barrier.
Novel Photoluminescence and Optical Thermometry of Solvothermally Derived Tetragonal ZrO2:Ti4+,Eu3+ Nanocrystals
Authors: Li Lu , Qu Xuesong , Pan Guo-Hui , Jeong Jung Hyun
Published: April 2024

In this paper, we report on the solvothermal preparation and detailed characterization of pristine and intentionally doped zirconium dioxide (ZrO2) nanocrystals (NCs, ~5 nm) with Eu3+ or Ti4+/Eu3+ ions using alkoxide precursors. The results indicated that the ZrO2 NCs were dominantly of a tetragonal phase (t-ZrO2) with a small proportion of monoclinic ZrO2 (m-ZrO2). The high purity of t-ZrO2 NCs could be synthesized with more Eu3+ doping. It was found that the as-obtained ZrO2 NCs contain some naturally present Ti4+ ions originating from precursors, but were being overlooked commonly, and some carbon impurities produced during synthesis. These species showed distinct photoluminescence (PL) properties. At least two types of Eu3+, located at low- and high-symmetry sites (probably sevenfold and eightfold oxygen coordination), respectively, were demonstrated to build into the lattice structure of t-ZrO2 NCs together. The cationic dopants were illustrated to be distributed non-randomly over the sites normally occupied by Zr, while Ti impurities preferentially occupied the sites near the low-symmetry site of Eu3+, yielding efficient energy transfer from the titanate groups to the neighboring Eu3+. Luminescence nanothermometry could measure temperature in a non-contact and remote way and could find great potentials in micro/nano-electronics, integrated photonics, and biomedicine. On the basis of the dual-emitting combination strategy involving the white broadband CT (Ti3+→O−) emissions of the titanate groups and red sharp Eu3+ emissions, t-ZrO2:Eu3+ nanophosphors were demonstrated to be ratiometric self-referencing optical thermometric materials, with a working range of 130–230 K and a maxima of relative sensitivity of ~1.9% K−1 at 230 K.
Magnetron-Deposited FeTiB Films: From Structural Metastability to the Specific Magnetic State
Authors: Sheftel Elena N. , Tedzhetov Valentin A. , Harin Eugene V. , Kiryukhantsev-Korneev Philipp V. , Zhigalina Olga M. , Usmanova Galina Sh.
Published: April 2024

Results of XRD and TEM studies of a metastable phase state in Fe73Ti5B19O3 and Fe55Ti16B27O2 films, which is formed upon magnetron deposition under preset conditions, and of the evolution of the state in the course of subsequent annealing at 500 °C for 1, 5, and 9 h and experimental data on the magnetic microstructure and magnetic properties are reported. The annealed films were found to be characterized by a nanocrystalline structure, which is represented by two crystalline phases, namely, the ferromagnetic solid solution αFe(Ti), and nonferromagnetic boride FenB. The Ti content in the films determines the grain size of the αFe(Ti) phase, whereas the content of B localized within the grain boundaries determines the ratio of the volume fractions of amorphous and nanocrystalline phases in the structure. In contrast to the ferromagnetic Fe73Ti5B19O3 films, the Fe55Ti16B27O2 films are superparamagnets both in the deposited state and after annealing at 500 °C for 1 and 5 h because of the higher volume fraction of the amorphous phase in the structure. The 9 h annealing of the Fe55Ti16B27O2 films transfers them into the ferromagnets owing to the development of the amorphous phase crystallization, increase in the content of nanocrystalline ferromagnetic phase αFe(Ti) grains, and realization of exchange interaction between them.
Improving the Wear Resistance Properties of 7A04 Aluminum Alloy with Three Surface Modification Coatings
Authors: Hu Jinmeng , Zhang Cheng , Wang Xiaodong , Meng Xiaobo , Dou Caihong , Yu Hua , Wang Changji , Xue Jun , Qiao Ziping , Jiang Tao
Published: April 2024

Multiple advantages, such as good formability, high specific strength, excellent thermal conductivity, and high corrosion resistance, enable aluminum alloy wide application in various fields; however, low surface hardness and poor wear resistance limit its further development. In this study, three surface modification coatings were successfully prepared on the surface of 7A04 aluminum alloy by microarc oxidation (MAO) and a combination of hard anodizing treatment (HA) and physical vapor deposition (PVD), named MAO, HA+W+DLC, and HA+Ti+ta-C, respectively. The microstructure, hardness, and tribological properties of the three coatings and the 7A04 aluminum alloy substrate were studied. The results show that the surface quality and hardness of the coated samples were higher than those of the 7A04 aluminum alloy and that the HA+Ti+ta-C coating possessed the highest hardness of 34.23 GPa. Moreover, the wear resistance of the two multilayer coatings was significantly improved during the ring-block wear tests under oil lubrication, exhibiting a wear rate of 1.51 × 10−7 mm3/N·m for HA+W+DLC and 1.36 × 10−7 mm3/N·m for HA+Ti+ta-C.
Removing Aged Polymer Coatings from Porous Stone Surfaces Using the Gel Cleaning Method
Authors: Weththimuni Maduka , Fiocco Giacomo , Girella Alessandro , Vigani Barbara , Sacchi Donatella , Rossi Silvia , Licchelli Maurizio
Published: April 2024

Acrylic polymers were extensively used in past restoration practices, usually as consolidants or protecting agents. Their removal is often required because polymer coatings can improve some decay processes of stone substrates and, after ageing, may generate undesirable materials on the surface of artifacts. Therefore, the removal of old polymer coating from the surface of artifacts has become a common operation in the conservation of cultural heritage. As with other cleaning operations, it is a delicate process that may irreversibly damage the artifacts if not correctly carried out. The main aim of this study was to determine the appropriate cleaning procedure for efficiently removing old acrylic polymers (e.g., Paraloid B-72) from the surface of historical buildings. For this purpose, a polymer was applied to two different porous stone substrates (bio-calcarenite and arenaria stone). The hydrogel cleaning approach was used for the present study, as preliminary results suggested that it is the most promising polymer-removing method. The considered hydrogel (based on a semi-interpenetrating polymer network involving poly(2-hydroxyethyl methacrylate) and polyvinylpyrrolidone) was prepared and characterized using different techniques in order to assess the gel’s properties, including the gel content, equilibrium water content, retention capability, hardness, Young’s modulus, and morphology. After that, the hydrogel was loaded with appropriate amounts of nano-structured emulsions (NSEs) containing a surfactant (EcoSufTM), organic solvents, and H2O, then applied onto the coated surfaces. Moreover, plain EcoSurfTM in a water emulsion (EcoSurf/H2O) was also used to understand the polymer-removing behavior of the surfactant without any organic solvent. A comparative study was carried out on artificially aged and unaged polymer-coated samples to better understand the cleaning effectiveness of the considered emulsions for removing decayed polymer coatings. The experimental results showed that the NSE-loaded hydrogel cleaning method was more effective than other common cleaning procedures (e.g., cellulose pulp method). In fact, only one cleaning step was enough to remove the polymeric material from the stone surfaces without affecting their original properties.
A Comprehensive Study on Microstructure and Wear Behavior of Nano-WC Reinforced Ni60 Laser Coating on 17-4PH Stainless Steel
Authors: Wang Jie , Zhang Xiaoqiang , Qiao Lei , Zhao Yue , Ren Mengfei , Li Tiaotiao , Li Ruifeng
Published: April 2024

The surface of 17-4PH martensitic stainless steel was laser-cladded with Ni60 and Ni60+nano-WC composites and a comprehensive investigation was conducted of the microstructure and wear mechanism. The findings demonstrate that despite the added nano-WC particles being fused and dissolved during laser cladding, they still lead to a reduction in grain size and a decrease in crystallographic orientation strength. Furthermore, the dissolution of nano-WC makes the lamellar M23C6 carbides transform into a rod or block morphology, and leads to the CrB borides becoming finer and more evenly dispersed. This microstructural evolution resulted in a uniform increase in hardness and wear resistance, effectively preventing crack formation. When the nano-WC addition increased to 20 wt.%, there was a 27.12% increase in microhardness and an 85.19% decrease in volume wear rate compared to that of the pure Ni60 coating. Through analysis of the microstructure and topography of wear traces, it can be inferred that as the nano-WC addition increased from 0 wt.% up to 20 wt.%, there was a gradual transition from two-body abrasive wear to three-body abrasive wear, ultimately resulting in adherent wear.
Self-Healing Phenomenon at the Cut Edge of Zn-Al-Mg Alloy Coated Steel in Chloride Environments
Authors: Kim Sang-Hee , Jin Seo-Yun , Yang Ji-Hoon , Yang Jeong-Hyeon , Lee Myeong-Hoon , Yun Yong-Sup
Published: April 2024

This study explores the self-healing phenomenon at the cut edges of Zn-Al-Mg alloy coated steel in chloride environments, a critical consideration for materials exposed to marine conditions. Zn-Al-Mg coatings offer superior resistance to cut-edge corrosion. This research aims to unravel the self-healing properties observed in these coatings. Through cyclic corrosion tests (CCTs), we compared the corrosion resistance of Zn-Al-Mg coated steel with traditional zinc alloy coatings. Our findings show a notable reduction in corrosion with ZMA4 coatings after 120 CCT cycles. This is due to the formation of corrosion products, namely layered double hydroxides (LDHs) and Mg(OH)2. X-ray diffraction and X-ray photoelectron spectroscopy analyses were employed to confirm the presence of these products and elucidate their roles in the self-healing process. This study highlights the potential of Zn-Al-Mg coatings for enhancing the durability of steel structures in corrosive environments, suggesting a paradigm shift in corrosion protection strategies for marine applications. The development of coatings that exhibit self-healing capabilities in chloride-rich environments could significantly mitigate the challenges posed by cut-edge corrosion, promising extended service life and reduced maintenance costs.
Characterization of ZrBSiTaNx Films
Authors: Yeh Kuo-Hong , Chang Li-Chun , Chen Yung-I
Published: April 2024

In this study, ZrBSiTa and (ZrBSiTa)Nx films were deposited on silicon wafers through direct current magnetron cosputtering. The nitrogen flow ratio (RN2) of the reactive gas and the sputter power applied to the Si target (PSi) were the variables in the fabricating processes. The influence of the N and Si contents on the mechanical properties, thermal stability, and oxidation behavior of the ZrBSiTa and (ZrBSiTa)Nx films were investigated. All the as-fabricated films exhibited amorphous structures. The RN2 set at 0.1, 0.2, and 0.4 caused the ZrBSiTaNx films to exhibit high N contents of 52–55, 62–64, and 63–64 at.%, respectively. The Si content of the ZrBSiTa films increased from 0 to 42 at.% as PSi increased from 0 to 150 W, and this was accompanied by decreases in hardness and Young’s modulus values from 19.1 to 14.3 GPa and 264 to 242 GPa, respectively. In contrast, the increase in Si content of the (ZrBSiTa)Nx films from 0 to 21 at.% increased the hardness from 11.5 to 14.0 GPa, and Young’s modulus from 207 to 218 GPa. Amorphous BN and SiNx phases in the (ZrBSiTa)Nx films varied the structural and mechanical properties. The thermal stability of the (ZrBSiTa)Nx films was evaluated by annealing at 800–900 °C for 10–30 min in Ar. The oxidation behavior of the (ZrBSiTa)Nx films was evaluated in the ambient air at 800 °C for 0.5–24 h. The amorphous (ZrBSiTa)Nx films with a high Si content had high thermal stability and oxidation resistance.
Structural Study of Nematogenic Compound 5OS5
Authors: Deptuch Aleksandra , Sęk Bartosz , Lalik Sebastian , Zając Wojciech , Ossowska-Chruściel Mirosława D. , Chruściel Janusz , Marzec Monika
Published: April 2024

The S-(4-pentylphenyl) 4-(pentyloxy)benzothioate, forming the nematic phase, is investigated by X-ray diffraction in temperatures between 263 K and 365 K, with the support of differential scanning calorimetry and polarizing optical microscopy. The microscopic observations show changes within the solid state, while X-ray diffraction does not indicate any transitions between the crystal phases. The Rietveld refinement shows that the crystal phase formed from the melt is the same monoclinic crystal phase with the P21/c space group as reported for a single crystal grown from an ethanol solution. The temperature dependence of the unit cell parameters in the 263–335 K range is determined and the coefficients of thermal expansion are obtained. The unit cell expands on heating along the longer ac-diagonal and b-axis while, along the shorter ac-diagonal, a very small shrinkage occurs. The diffraction patterns of the liquid crystalline nematic phase indicate the formation of dimers via hydrogen bonding. Density functional theory calculations (def2TZVPP basis set, B3LYP-D3(BJ) correlation-exchange functional) are applied for geometry optimization of an isolated molecule and selected dimers.
AdMISC: Advanced Multi-Task Learning and Feature-Fusion for Emotional Support Conversation
Authors: Jia Xuhui , He Jia , Zhang Qian , Jin Jin
Published: April 2024

The emotional support dialogue system is an emerging and challenging task in natural language processing to alleviate people’s emotional distress. Each utterance in the dialogue has features such as emotion, intent, and commonsense knowledge. Previous research has indicated subpar performance in strategy prediction accuracy and response generation quality due to overlooking certain underlying factors. To address these issues, we propose Advanced Multi-Task Learning and Feature-Fusion for Emotional Support Conversation (AdMISC), which extracts various potential factors influencing dialogue through neural networks, thereby improving the accuracy of strategy prediction and the quality of generated responses. Specifically, we extract features affecting dialogue through dynamic emotion extraction and commonsense enhancement and then model strategy prediction. Additionally, the model learns these features through attention networks to generate higher quality responses. Furthermore, we introduce a method for automatically averaging loss function weights to improve the model’s performance. Experimental results using the emotional support conversation dataset ESConv demonstrate that our proposed model outperforms baseline methods in both strategy label prediction accuracy and a range of automatic and human evaluation metrics.
Immersive Emotion Analysis in VR Environments: A Sensor-Based Approach to Prevent Distortion
Authors: Joo Jae-Hong , Han Seung-Hyun , Park Inyoung , Chung Tae-Sun
Published: April 2024

As virtual reality (VR) technology advances, research has focused on enhancing VR content for a more realistic user experience. Traditional emotion analysis relies on surveys, but they suffer from delayed responses and decreased immersion, leading to distorted results. To overcome these limitations, we propose an emotion analysis method using sensor data in the VR environment. Our approach can take advantage of the user’s immediate response and not reduce immersion. Linear regression, classification analysis, and tree-based methods were applied to electrocardiogram and galvanic skin response (GSR) sensor data to measure valence and arousal values. We introduced a novel emotional dimension model by analyzing correlations between emotions and the valence and arousal values. Experimental results demonstrated the highest accuracy of 77% and 92.3% for valence and arousal prediction, respectively, using GSR sensor data. Furthermore, an accuracy of 80.25% was achieved in predicting valence and arousal using nine emotions. Our proposed model improves VR content through more accurate emotion analysis in a VR environment, which can be useful for targeting customers in various industries, such as marketing, gaming, education, and healthcare.
Several Approaches for the Prediction of the Operating Modes of a Wind Turbine
Authors: Yun Hannah , Giurcăneanu Ciprian Doru , Dobbie Gillian
Published: April 2024

Growing concern about climate change has intensified efforts to use renewable energy, with wind energy highlighted as a growing source. It is known that wind turbines are characterized by distinct operating modes that reflect production efficiency. In this work, we focus on the forecasting problem for univariate discrete-valued time series of operating modes. We define three prediction strategies to overcome the difficulties associated with missing data. These strategies are evaluated through experiments using five forecasting methods across two real-life datasets. Two of the forecasting methods have been introduced in the statistical literature as extensions of the well-known context algorithm: variable length Markov chains and Bayesian context tree. Additionally, we consider a Bayesian method based on conditional tensor factorization and two different smoothers from the classical tools for time series forecasting. After evaluating each pair prediction strategy/forecasting method in terms of prediction accuracy versus computational complexity, we provide guidance on the methods that are suitable for forecasting the time series of operating modes. The prediction results that we report demonstrate that high accuracy can be achieved with reduced computational resources.
Optimizing Hydrogen-Rich Biofuel Production: Syngas Generation from Wood Chips and Corn Cobs
Authors: Oliveira Matheus , Monteiro Eliseu , Rouboa Abel
Published: April 2024

This study investigates gasification using wood chips (WC) and corn cobs (CC) for hydrogen-rich syngas production. A simulation model developed in Aspen Plus was used to evaluate the performance of biomass gasification. The model incorporates a system of Fortran subroutines that automate the definition of input parameters based on the analysis of biomass composition. Furthermore, the model’s equilibrium constants were adjusted based on experimentally measured gas concentrations, increasing the precision of the variations. The numerical results predicted hydrogen yields of 65–120 g/kg biomass, with 60–70% energy efficiency for steam gasification (versus 40–50% for air gasification). The hydrogen concentration ranged from 34% to 40%, with CO (27–11%), CO2 (9–20%), and CH4 (<4%). The gasification temperature increased hydrogen production by up to 40% but also increased CO2 emissions by up to 20%. Higher biomass moisture content promoted hydrogen production by up to 15% but reduced energy efficiency by up to 10% if excessive. Steam gasification with wood chips and corn cobs shows promising potential for hydrogen-rich syngas production, offering benefits such as reduced emissions (up to 30% less CO) and sustainability by utilizing agricultural residues.
Outlook for Offshore Wind Energy Development in Mexico from WRF Simulations and CMIP6 Projections
Authors: Meza-Carreto Jaime , Romero-Centeno Rosario , Figueroa-Espinoza Bernardo , Moreles Efraín , López-Villalobos Carlos
Published: April 2024

This study presents a comprehensive assessment of the offshore wind energy potential in Mexico across 40 years (1979–2018) of numerical simulations using the Weather Research and Forecasting (WRF) model and data from the Coupled Model Intercomparison Project Phase 6 (CMIP6). The WRF identifies three regions with moderate to good wind potential: off the north coast of Tamaulipas (Zone I), the northwest coast of Yucatan (Zone II), and the Gulf of Tehuantepec (Zone III). The analysis involves comparing 47 CMIP6 climate models with the WRF results and selecting the best performing models to obtain future projections for the short term (2040–2069) and the long term (2070–2099). Two ensemble-based strategies were implemented. The first one, which uses an intersection approach from which four CMIP6 models were considered, reveals positive percentage differences in Zone II for both future projections, especially for the long-term one. In Zones I and III, positive values are also observed near the coast, mainly for the long-term projection, but they are considerably lower compared to those in Zone II. The second ensemble strategy uses weight assignment through the Mean Absolute Percentage Error, so that a greater weight is given to the model that performed better in each particular zone, potentially providing more accurate results. The findings suggest the likelihood of increased offshore wind energy in these three zones of Mexico, for both short- and long-term future projections, with positive percentage differences of up to 10% in certain areas.
Methodology for Circuit Breaker Contact Diagnosis through Dynamic Resistance Measurements and Fuzzy-Logic-Based Analysis
Authors: Souza Ronimack T. , Lira George R. S. , Costa Edson G. , Oliveira Adriano C. , Leite Neto Antonio F.
Published: April 2024

This paper presents a methodology capable of measuring, processing, and extracting contact resistance parameters that enable the identification of the contact degradation level inside arc extinction chambers in medium- and high-voltage circuit breakers (CB). To determine the contact degradation level, an algorithm was developed to extract the characteristic parameters from the results of dynamic resistance measurement (DRM). To analyze the dataset parameters, this work employs the combination of different statistical tools, such as boxplots and fuzzy logic, enabling the evaluation to be conducted without the subjectivity inherent in human decision. Therefore, a more objective and reliable diagnosis could be achieved. The DRM tests were performed on two types of minimum-oil CB (MOCB), 800 A/15 kV/12.5 kA (CB-A) and 2000 A/72.5 kV/31.5 kA (CB-B and CB-C). For CB-A and CB-B, three contacts were utilized for each CB, with significant contact degradation. For CB-C, a single contact was employed without significant degradation. The DRM curves of the CB-C contact were used as the reference for evaluation of the CB-B contacts. For this purpose, a new DRM system was developed. The proposed methodology can be defined as a complement for other diagnostic techniques, serving as a non-subjective asset management tool, supporting decisions regarding equipment interventions.