bluuebunny/crossref_metadata_2025 huggingface dataset:
Chemically Modifying Vegetable Oils to Prepare Green Lubricants
Authors: Karmakar Gobinda , Ghosh Pranab , Sharma Brajendra
Published: November 2017

Chemically modifying vegetable oils to produce an alternative to petroleum-based materials is one of the most important emerging industrial research areas today because of the adverse effects of petroleum products on the environment and the shortage of petroleum resources. Biolubricants, bioplasticizers, non-isocyanate polyurethanes, biofuel, coating materials, biocomposites, and other value-added chemicals can easily be produced by chemically modifying vegetable oils. This short review discusses using vegetable oils or their derivatives to prepare lubricants that are environmentally safe. Chemically modified vegetable oils are generally used as base fluids to formulate environmentally friendly lubricants. Reports of their application as sustainable additives have attracted special attention recently because of their enhanced multifunctional performances (single additives perform several functions, i.e., viscosity index improver, pour point depressant, antiwear products) and biodegradability compared with commercial additives. Here, we have reviewed the use of chemically modified vegetable oils as base fluids and additives to prepare a cost-effective and environmentally friendly lubricant composition.
Some Properties of Densified Eastern Redcedar as Function of Heat and Pressure
Authors: Ulker Onur , Hiziroglu Salim
Published: November 2017

The objective of this study was to evaluate some of the properties of densified eastern redcedar as function of temperature and pressure. Surface quality, adhesive bondline shear strength, hardness, and color changes of the samples compressed using different temperature levels ranging from 100 °C to 180 °C were investigated. Based on the findings in this work, surface roughness of compressed specimens decreased with increased temperature. Overall adhesive bondline shear strength of the samples decreased as compared to that of control specimens as a result of compression. It appears that densified samples exposed to a temperature of 180 °C had significantly darker surface than those of the others, based on color measurement. Data found in this work provide some basic information for more efficient use of underutilized species such as eastern redcedar.
Low-Temperature Crystal Structures of the Hard Core Square Shoulder Model
Authors: Gabriëlse Alexander , Löwen Hartmut , Smallenburg Frank
Published: November 2017

In many cases, the stability of complex structures in colloidal systems is enhanced by a competition between different length scales. Inspired by recent experiments on nanoparticles coated with polymers, we use Monte Carlo simulations to explore the types of crystal structures that can form in a simple hard-core square shoulder model that explicitly incorporates two favored distances between the particles. To this end, we combine Monte Carlo-based crystal structure finding algorithms with free energies obtained using a mean-field cell theory approach, and draw phase diagrams for two different values of the square shoulder width as a function of the density and temperature. Moreover, we map out the zero-temperature phase diagram for a broad range of shoulder widths. Our results show the stability of a rich variety of crystal phases, such as body-centered orthogonal (BCO) lattices not previously considered for the square shoulder model.
Cytotoxic and Antibacterial Compounds from the Coral-Derived Fungus Aspergillus tritici SP2-8-1
Authors: Wang Weiyi , Liao Yanyan , Tang Chao , Huang Xiaomei , Luo Zhuhua , Chen Jianming , Cai Peng
Published: November 2017

Three novel compounds, 4-methyl-candidusin A (1), aspetritone A (2) and aspetritone B (3), were obtained from the culture of a coral-derived fungus Aspergillus tritici SP2-8-1, together with fifteen known compounds (4–18). Their structures, including absolute configurations, were assigned based on NMR, MS, and time-dependent density functional theory (TD-DFT) ECD calculations. Compounds 2 and 5 exhibited better activities against methicillin-resistant strains of S. aureus (MRSA) ATCC 43300 and MRSA CGMCC 1.12409 than the positive control chloramphenicol. Compound 5 displayed stronger anti-MRSA and lower cytotoxic activities than 2, and showed stronger antibacterial activities against strains of Vibrio vulnificus, Vibrio rotiferianus, and Vibrio campbellii than the other compounds. Compounds 2 and 10 exhibited significantly stronger cytotoxic activities against human cancer cell lines HeLa, A549, and Hep G2 than the other compounds. Preliminary structure–activity relationship studies indicated that prenylation of terphenyllin or candidusin and the tetrahydrobenzene moiety in anthraquinone derivatives may influence their bioactivity.
Experimental Investigation of Forming Forces in Frictional Stir Incremental Forming of Aluminum Alloy AA6061-T6
Authors: Baharudin B.T.H.T. , Azpen Q.M. , Sulaima Shamsuddin , Mustapha F.
Published: November 2017

The incremental sheet forming (ISF) process is an emerging flexible sheet-forming process, which is adequate for the manufacturing of unique or small-volume batches. Single-point incremental forming (SPIF) is the original technology of incremental sheet-forming processes. In this article, frictional stir-assisted SPIF was used to deform AA6061-T6 aluminum alloy. Experimental tests were conducted to measure the forming forces during this process for the concerned lightweight material. The influence of process parameters was investigated, which included tool rotation speed, feed rate, step size and tool diameter on the produced forming forces. A Taguchi technique for the design of experiment (DOE) and the varying wall angle conical frustum (VWACF) test was employed in this study. The results show that the rotation spindle speed was the most dominant parameter that affects the forming forces, followed by the step size, feed rate and tool diameter. In addition, the interaction between the feed rate and step size has a notable impact on the values of the forming forces.
Identification of Zn-Bearing Micas and Clays from the Cristal and Mina Grande Zinc Deposits (Bongará Province, Amazonas Region, Northern Peru)
Authors: Arfè Giuseppe , Mondillo Nicola , Balassone Giuseppina , Boni Maria , Cappelletti Piergiulio , Di Palma Tommaso
Published: November 2017

Zn-bearing phyllosilicates are common minerals in nonsulfide Zn deposits, but they seldom represent the prevailing economic species. However, even though the presence of Zn-bearing clays is considered as a disadvantage in mineral processing, their characteristics can give crucial information on the genesis of the oxidized mineralization. This research has been carried out on the Mina Grande and Cristal Zn-sulfide/nonsulfide deposits, which occur in the Bongará district (Northern Peru). In both of the deposits, Zn-bearing micas and clays occur as an accessory to the ore minerals. The XRD analyses and scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDS) investigations revealed that the Zn-bearing micas that are occurring in both deposits mostly consist of I/S mixed layers of detrital origin, which have been partly altered or overprinted by sauconite during the supergene alteration of sulfides. Sporadic hendricksite was also identified in the Cristal nonsulfide mineral assemblage, whereas at Mina Grande, the fraipontite-zaccagnaite (3R-polytype) association was detected. The identified zaccagnaite polytype suggests that both fraipontite and zaccagnaite are genetically related to weathering processes. The hendricksite detected at Cristal is a product of hydrothermal alteration, which is formed during the emplacement of sulfides. The complex nature of the identified phyllosilicates may be considered as evidence of the multiple processes (hydrothermal and supergene) that occurred in the Bongará district.
Effects of Polysaccharides from Platycodon grandiflorum on Immunity-Enhancing Activity In Vitro
Authors: Zhao Xiaona , Wang Yuge , Yan Peng , Cheng Guodong , Wang Cheng , Geng Na , Wang Xuepeng , Liu Jianzhu
Published: November 2017

The study is aimed at investigating the immunoenhancement activity of polysaccharides from Platycodon grandiflorum polysaccharides (PGPSs) in vitro. In this study, some research on lymphocyte proliferation, cell cycle, and the levels of CD4+ and CD8+ T cells were performed. Four different concentrations of PGPSs (PGPStc, PGPS60c, PGPS80c, and PGPStp) were harvested and added to peripheral blood T lymphocytes. We observed significant increases in T lymphocyte proliferation at PGPStc groups individually or synergistically with phytohemagglutinin (PHA) at most concentrations, and their lymphocyte proliferation rates were the highest. The active sites of PGPStc and PGPS60c were subsequently chosen. Then, we utilized flow cytometry to determine lymphocyte cell cycle distribution and levels of CD4+ and CD8+ T cells. At most time points, PGPStc could facilitate lymphocyte cell cycle progression from the G0/G1 phase to the S and G2/M phases and, simultaneously, increase the levels of CD4+ and CD8+ T cells. These results indicate that PGPStc enhances the immune functions, suggesting that PGPStc could be a potential immunopotentiator for further in vivo and clinical trial experiments.
Efficacy and Effectiveness of Carnitine Supplementation for Cancer-Related Fatigue: A Systematic Literature Review and Meta-Analysis
Authors: Marx Wolfgang , Teleni Laisa , Opie Rachelle , Kelly Jaimon , Marshall Skye , Itsiopoulos Catherine , Isenring Elizabeth
Published: November 2017

Background: Carnitine deficiency has been implicated as a potential pathway for cancer-related fatigue that could be treated with carnitine supplementation. The aim of this systematic literature review and meta-analysis was to evaluate the literature regarding the use of supplemental carnitine as a treatment for cancer-related fatigue. Methods: Using the PRISMA guidelines, an electronic search of the Cochrane Library, MEDLINE, Embase, CINAHL and reference lists was conducted. Data were extracted and independently assessed for quality using the Academy of Nutrition and Dietetics evidence analysis by two reviewers. In studies with positive quality ratings, a meta-analysis was performed using the random-effects model on Carnitine and cancer-related fatigue. Results: Twelve studies were included for review with eight reporting improvement in measures of fatigue, while four reported no benefit. However, many studies were non-randomized, open-label and/or used inappropriate dose or comparators. Meta-analysis was performed in three studies with sufficient data. Carnitine did not significantly reduce cancer-related fatigue with a standardized mean difference (SMD) of 0.06 points ((95% CI −0.09, 0.21); p = 0.45). Conclusion: Results from studies with lower risk of bias do not support the use of carnitine supplementation for cancer-related fatigue.
Mechanical Properties Distribution within Polypropylene Injection Molded Samples: Effect of Mold Temperature under Uneven Thermal Conditions
Authors: Liparoti Sara , Speranza Vito , Sorrentino Andrea , Titomanlio Giuseppe
Published: November 2017

The quality of the polymer parts produced by injection molding is strongly affected by the processing conditions. Uncontrolled deviations from the proper process parameters could significantly affect both internal structure and final material properties. In this work, to mimic an uneven temperature field, a strong asymmetric heating is applied during the production of injection-molded polypropylene samples. The morphology of the samples is characterized by optical and atomic force microscopy (AFM), whereas the distribution of mechanical modulus at different scales is obtained by Indentation and HarmoniX AFM tests. Results clearly show that the temperature differences between the two mold surfaces significantly affect the morphology distributions of the molded parts. This is due to both the uneven temperature field evolutions and to the asymmetric flow field. The final mechanical property distributions are determined by competition between the local molecular stretch and the local structuring achieved during solidification. The cooling rate changes affect internal structures in terms of relaxation/reorganization levels and give rise to an asymmetric distribution of mechanical properties.
Extraction and Characterization of Cellulose Nanocrystals from Tea Leaf Waste Fibers
Authors: Abdul Rahman Nur Hayati , Chieng Buong Woei , Ibrahim Nor Azowa , Abdul Rahman Norizah
Published: November 2017

The aim was to explore the utilization of tea leaf waste fibers (TLWF) as a source for the production of cellulose nanocrystals (CNC). TLWF was first treated with alkaline, followed by bleaching before being hydrolyzed with concentrated sulfuric acid. The materials attained after each step of chemical treatments were characterized and their chemical compositions were studied. The structure analysis was examined by Fourier transform infrared (FTIR) spectroscopy and X-ray diffraction (XRD). From FTIR analysis, two peaks at 1716 and 1207 cm−1—which represent C=O stretching and C–O stretching, respectively—disappeared in the spectra after the alkaline and bleaching treatments indicated that hemicellulose and lignin were almost entirely discarded from the fiber. The surface morphology of TLWF before and after chemical treatments was investigated by scanning electron microscopy (SEM) while the dimension of CNC was determined by transmission electron microscopy (TEM). The extraction of CNC increased the surface roughness and the crystallinity index of fiber from 41.5% to 83.1%. Morphological characterization from TEM revealed the appearance of needle-like shaped CNCs with average diameter of 7.97 nm. The promising results from all the analyses justify TLWF as a principal source of natural materials which can produce CNC.
Urban Sprawl and Adverse Impacts on Agricultural Land: A Case Study on Hyderabad, India
Authors: Gumma Murali , Mohammad Irshad , Nedumaran Swamikannu , Whitbread Anthony , Lagerkvist Carl
Published: November 2017

Many Indian capitals are rapidly becoming megacities due to industrialization and rural–urban emigration. Land use within city boundaries has changed dynamically, accommodating development while replacing traditional land-use patterns. Using Landsat-8 and IRS-P6 data, this study investigated land-use changes in urban and peri-urban Hyderabad and their influence on land-use and land-cover. Advanced methods, such as spectral matching techniques with ground information were deployed in the analysis. From 2005 to 2016, the wastewater-irrigated area adjacent to the Musi river increased from 15,553 to 20,573 hectares, with concurrent expansion of the city boundaries from 38,863 to 80,111 hectares. Opportunistic shifts in land-use, especially related to wastewater-irrigated agriculture, emerged in response to growing demand for fresh vegetables and urban livestock feed, and to easy access to markets due to the city’s expansion. Validation performed on the land-use maps developed revealed 80–85% accuracy.
Estimating Daily Global Evapotranspiration Using Penman–Monteith Equation and Remotely Sensed Land Surface Temperature
Authors: Raoufi Roozbeh , Beighley Edward
Published: November 2017

Daily evapotranspiration (ET) is modeled globally for the period 2000–2013 based on the Penman–Monteith equation with radiation and vapor pressures derived using remotely sensed Land Surface Temperature (LST) from the MODerate resolution Imaging Spectroradiometer (MODIS) on the Aqua and Terra satellites. The ET for a given land area is based on four surface conditions: wet/dry and vegetated/non-vegetated. For each, the ET resistance terms are based on land cover, leaf area index (LAI) and literature values. The vegetated/non-vegetated fractions of the land surface are estimated using land cover, LAI, a simplified version of the Beer–Lambert law for describing light transition through vegetation and newly derived light extension coefficients for each MODIS land cover type. The wet/dry fractions of the land surface are nonlinear functions of LST derived humidity calibrated using in-situ ET measurements. Results are compared to in-situ measurements (average of the root mean squared errors and mean absolute errors for 39 sites are 0.81 mm day−1 and 0.59 mm day−1, respectively) and the MODIS ET product, MOD16, (mean bias during 2001–2013 is −0.2 mm day−1). Although the mean global difference between MOD16 and ET estimates is only 0.2 mm day−1, local temperature derived vapor pressures are the likely contributor to differences, especially in energy and water limited regions. The intended application for the presented model is simulating ET based on long-term climate forecasts (e.g., using only minimum, maximum and mean daily or monthly temperatures).
Hyperspectral Image Spatial Super-Resolution via 3D Full Convolutional Neural Network
Authors: Mei Shaohui , Yuan Xin , Ji Jingyu , Zhang Yifan , Wan Shuai , Du Qian
Published: November 2017

Hyperspectral images are well-known for their fine spectral resolution to discriminate different materials. However, their spatial resolution is relatively low due to the trade-off in imaging sensor technologies, resulting in limitations in their applications. Inspired by recent achievements in convolutional neural network (CNN) based super-resolution (SR) for natural images, a novel three-dimensional full CNN (3D-FCNN) is constructed for spatial SR of hyperspectral images in this paper. Specifically, 3D convolution is used to exploit both the spatial context of neighboring pixels and spectral correlation of neighboring bands, such that spectral distortion when directly applying traditional CNN based SR algorithms to hyperspectral images in band-wise manners is alleviated. Furthermore, a sensor-specific mode is designed for the proposed 3D-FCNN such that none of the samples from the target scene are required for training. Fine-tuning by a small number of training samples from the target scene can further improve the performance of such a sensor-specific method. Extensive experimental results on four benchmark datasets from two well-known hyperspectral sensors, namely hyperspectral digital imagery collection experiment (HYDICE) and reflective optics system imaging spectrometer (ROSIS) sensors, demonstrate that our proposed 3D-FCNN outperforms several existing SR methods by ensuring higher quality both in reconstruction and spectral fidelity.
Satellite-Derived Spatiotemporal Variations in Evapotranspiration over Northeast China during 1982–2010
Authors: Zhang Lilin , Yao Yunjun , Wang Zhiqiang , Jia Kun , Zhang Xiaotong , Zhang Yuhu , Wang Xuanyu , Xu Jia , Chen Xiaowei
Published: November 2017

Evapotranspiration (ET) is a critical process for the climate system and water cycles. However, the spatiotemporal variations in terrestrial ET over Northeast China over the past three decades calculated from sparse meteorological point-based data remain large uncertain. In this paper, a recently proposed modified satellite-based Priestley–Taylor (MS–PT) algorithm was applied to estimate ET of Northeast China during 1982–2010. Validation results show that the square of the correlation coefficients (R2) for the six flux tower sites varies from 0.55 to 0.88 (p < 0.01), and the mean root mean square error (RMSE) is 0.92 mm/d. The ET estimated by MS–PT has an annual mean of 441.14 ± 18 mm/year in Northeast China, with a decreasing trend from southeast coast to northwest inland. The ET also shows in both annual and seasonal linear trends over Northeast China during 1982–2010, although this trend seems to have ceased after 1998, which increased on average by 12.3 mm per decade pre-1998 (p < 0.1) and decreased with large interannual fluctuations post-1998. Importantly, our analysis on ET trends highlights a large difference from previous studies that the change of potential evapotranspiration (PET) plays a key role for the change of ET over Northeast China. Only in the western part of Northeast China does precipitation appear to be a major controlling influence on ET.
Spatial Recognition of the Urban-Rural Fringe of Beijing Using DMSP/OLS Nighttime Light Data
Authors: Yang Yuli , Ma Mingguo , Tan Chao , Li Wangping
Published: November 2017

Spatial identification of the urban-rural fringes is very significant for deeply understanding the development processes and regulations of urban space and guiding urban spatial development in the future. Traditionally, urban-rural fringe areas are identified using statistical analysis methods that consider indexes from single or multiple factors, such as population densities, the ratio of building land, the proportion of the non-agricultural population, and economic levels. However, these methods have limitations, for example, the statistical data are not continuous, the statistical standards are not uniform, the data is seldom available in real time, and it is difficult to avoid issues on the statistical effects from edges of administrative regions or express the internal differences of these areas. This paper proposes a convenient approach to identify the urban-rural fringe using nighttime light data of DMSP/OLS images. First, a light characteristics–combined value model was built in ArcGIS 10.3, and the combined characteristics of light intensity and the degree of light intensity fluctuation are analyzed in the urban, urban-rural fringe, and rural areas. Then, the Python programming language was used to extract the breakpoints of the characteristic combination values of the nighttime light data in 360 directions taking Tian An Men as the center. Finally, the range of the urban-rural fringe area is identified. The results show that the urban-rural fringe of Beijing is mainly located in the annular band around Tian An Men. The average inner radius is 19 km, and the outer radius is 26 km. The urban-rural fringe includes the outer portions of the four city center districts, which are the Chaoyang District, Haidian District, Fengtai District, and Shijingshan District and the part area border with Daxing District, Tongzhou District, Changping District, Mentougou District, Shunyi District, and Fangshan District. The area of the urban-rural fringe is approximately 765 km2. This paper provides a convenient, feasible, and real-time approach for the identification of the urban-rural fringe areas. It is very significant to extract the urban-rural fringes.
Similarities and Improvements of GPM Dual-Frequency Precipitation Radar (DPR) upon TRMM Precipitation Radar (PR) in Global Precipitation Rate Estimation, Type Classification and Vertical Profiling
Authors: Gao Jinyu , Tang Guoqiang , Hong Yang
Published: November 2017

Spaceborne precipitation radars are powerful tools used to acquire adequate and high-quality precipitation estimates with high spatial resolution for a variety of applications in hydrological research. The Global Precipitation Measurement (GPM) mission, which deployed the first spaceborne Ka- and Ku-dual frequency radar (DPR), was launched in February 2014 as the upgraded successor of the Tropical Rainfall Measuring Mission (TRMM). This study matches the swath data of TRMM PR and GPM DPR Level 2 products during their overlapping periods at the global scale to investigate their similarities and DPR’s improvements concerning precipitation amount estimation and type classification of GPM DPR over TRMM PR. Results show that PR and DPR agree very well with each other in the global distribution of precipitation, while DPR improves the detectability of precipitation events significantly, particularly for light precipitation. The occurrences of total precipitation and the light precipitation (rain rates < 1 mm/h) detected by GPM DPR are ~1.7 and ~2.53 times more than that of PR. With regard to type classification, the dual-frequency (Ka/Ku) and single frequency (Ku) methods performed similarly. In both inner (the central 25 beams) and outer swaths (1–12 beams and 38–49 beams) of DPR, the results are consistent. GPM DPR improves precipitation type classification remarkably, reducing the misclassification of clouds and noise signals as precipitation type “other” from 10.14% of TRMM PR to 0.5%. Generally, GPM DPR exhibits the same type division for around 82.89% (71.02%) of stratiform (convective) precipitation events recognized by TRMM PR. With regard to the freezing level height and bright band (BB) height, both radars correspond with each other very well, contributing to the consistency in stratiform precipitation classification. Both heights show clear latitudinal dependence. Results in this study shall contribute to future development of spaceborne radar precipitation retrievals and benefit hydrological and meteorological research.
The Development of an IMU Integrated Clothes for Postural Monitoring Using Conductive Yarn and Interconnecting Technology
Authors: Kang Sung-Won , Choi Hyeob , Park Hyung-Il , Choi Byoung-Gun , Im Hyobin , Shin Dongjun , Jung Young-Giu , Lee Jun-Young , Park Hong-Won , Park Sukyung , Roh Jung-Sim
Published: November 2017

Spinal disease is a common yet important condition that occurs because of inappropriate posture. Prevention could be achieved by continuous posture monitoring, but most measurement systems cannot be used in daily life due to factors such as burdensome wires and large sensing modules. To improve upon these weaknesses, we developed comfortable “smart wear” for posture measurement using conductive yarn for circuit patterning and a flexible printed circuit board (FPCB) for interconnections. The conductive yarn was made by twisting polyester yarn and metal filaments, and the resistance per unit length was about 0.05 Ω/cm. An embroidered circuit was made using the conductive yarn, which showed increased yield strength and uniform electrical resistance per unit length. Circuit networks of sensors and FPCBs for interconnection were integrated into clothes using a computer numerical control (CNC) embroidery process. The system was calibrated and verified by comparing the values measured by the smart wear with those measured by a motion capture camera system. Six subjects performed fixed movements and free computer work, and, with this system, we were able to measure the anterior/posterior direction tilt angle with an error of less than 4°. The smart wear does not have excessive wires, and its structure will be optimized for better posture estimation in a later study.
Optimal Quantization Scheme for Data-Efficient Target Tracking via UWSNs Using Quantized Measurements
Authors: Zhang Senlin , Chen Huayan , Liu Meiqin , Zhang Qunfei
Published: November 2017

Target tracking is one of the broad applications of underwater wireless sensor networks (UWSNs). However, as a result of the temporal and spatial variability of acoustic channels, underwater acoustic communications suffer from an extremely limited bandwidth. In order to reduce network congestion, it is important to shorten the length of the data transmitted from local sensors to the fusion center by quantization. Although quantization can reduce bandwidth cost, it also brings about bad tracking performance as a result of information loss after quantization. To solve this problem, this paper proposes an optimal quantization-based target tracking scheme. It improves the tracking performance of low-bit quantized measurements by minimizing the additional covariance caused by quantization. The simulation demonstrates that our scheme performs much better than the conventional uniform quantization-based target tracking scheme and the increment of the data length affects our scheme only a little. Its tracking performance improves by only 4.4% from 2- to 3-bit, which means our scheme weakly depends on the number of data bits. Moreover, our scheme also weakly depends on the number of participate sensors, and it can work well in sparse sensor networks. In a 6 × 6 × 6 sensor network, compared with 4 × 4 × 4 sensor networks, the number of participant sensors increases by 334.92%, while the tracking accuracy using 1-bit quantized measurements improves by only 50.77%. Overall, our optimal quantization-based target tracking scheme can achieve the pursuit of data-efficiency, which fits the requirements of low-bandwidth UWSNs.
Carbon Nanotubes as Fluorescent Labels for Surface Plasmon Resonance-Assisted Fluoroimmunoassay
Authors: Ashiba Hiroki , Iizumi Yoko , Okazaki Toshiya , Wang Xiaomin , Fujimaki Makoto
Published: November 2017

The photoluminescence properties of carbon nanotubes (CNTs), including the large Stokes shift and the absence of fluorescent photobleaching, can be used as a fluorescent label in biological measurements. In this study, the performance of CNTs as a fluorescent label for surface plasmon resonance (SPR)-assisted fluoroimmunoassay is evaluated. The fluorescence of (8, 3) CNTs with an excitation wavelength of 670 nm and an emission wavelength of 970 nm is observed using a sensor chip equipped with a prism-integrated microfluidic channel to excite the SPR. The minimum detectable concentration of a CNT dispersed in water using a visible camera is 0.25 μg/mL, which is equivalent to 2 × 1010 tubes/mL. The target analyte detection using the CNT fluorescent labels is theoretically investigated by evaluating the detectable number of CNTs in a detection volume. Assuming detection of virus particles which are bound with 100 CNT labels, the minimum number of detectable virus particles is calculated to be 900. The result indicates that CNTs are effective fluorescent labels for SPR-assisted fluoroimmunoassay.
Quantitative Explanation of Retention Mechanisms of Hydrophobic and Hydrophilic-Interaction Liquid Chromatography-Inductive Effect of Alkyl Chain
Authors: Hanai Toshihiko
Published: November 2017

The basic retention mechanisms of reversed-phase and hydrophilic-interaction liquid chromatography (HILIC) were quantitatively analyzed using simple molecular mechanics (MM) calculations. The model bonded phases were composed of an alkyl chain bonded to siloxane-like molecules. The head of the alkyl chain was a hydroxyl group, used to study retention mechanisms of HILIC. The standard analytes were benzoic acid, aniline, benzene, water, and acetonitrile. The molecular interaction (MI) energy values of the van der Waals (VW) force were predominant for the reversed-phase chromatography, and those of hydrogen bonding (HB) were predominant for HILIC. Up to 5 units of methylene affected the MI.
Protecting of Marble Stone Facades of Historic Buildings Using Multifunctional TiO2 Nanocoatings
Authors: Aldoasri Mohammad , Darwish Sawsan , Adam Mahmoud , Elmarzugi Nagib , Ahmed Sayed
Published: November 2017

Stone surfaces and façades of historic buildings, due to their predominately outdoor location, suffer from many deterioration factors, including air pollution, soluble salts, relative humidity (RH)/temperature, and biodeterioration, which are the main causes of decay. In particular, the façades of the buildings deteriorate with direct exposure to these factors; deformation and disfiguration of superficial decoration and formation of black crusts are often observed on the stones. The development and application of self-cleaning and protection treatments on historical and architectural stone surfaces could be a significant improvement in the conservation, protection and maintenance of Cultural Heritage. A titanium dioxide nanoparticle has become a promising photocatalytic material, owing to its ability to catalyze the complete degradation of many organic contaminants and environmental factors. In this study, TiO2 nanoparticles, dispersed in an aqueous colloidal suspension, were applied directly to historic marble stone surfaces, by spray-coating, in order to obtain a nanometric film over the stone surface. The study started with an investigation of some properties of TiO2 nanoparticles, to assess the feasibility of the use of TiO2 on historic stone and architectural surfaces. Scanning electron microscopy (SEM) was, coupled with energy dispersive X-ray (EDX) microanalysis, (SEM-EDX), in order to obtain information on coating homogeneity and surface morphology, before and after artificial aging; the activity of the coated surface was evaluated through UV-light exposure, to evaluate photo-induced effects. The changes of molecular structure occurring in treated samples were spectroscopically studied by attenuated total reflection infrared spectroscopy (ATR-FTIR); activity of the hydrophobic property of the coated surface was evaluated by Sterio microscopy, model Zeiss 2010 from Munich, Germany, equipped with photo camera S23 under 80X magnification. The efficacy of the treatments was evaluated through capillary water absorption, and colorimetric measurements, performed to evaluate the optical appearance. Results showed that TiO2 nanoparticles are good candidates for coating applications on historic stone surfaces, where self-cleaning photo-induced effects are well evident; they enhanced the durability of stone surfaces toward UV aging, improved resistance to relative humidity (RH)/temperature and abrasion affect, reduced accumulation of dirt on stone surfaces when left in open air for 6 months, and did not alter the original features.
Modelling Interactions between Land Use, Climate, and Hydrology along with Stakeholders’ Negotiation for Water Resources Management
Authors: Farjad Babak , Pooyandeh Majeed , Gupta Anil , Motamedi Mohammad , Marceau Danielle
Published: November 2017

This paper describes the main functionalities of an integrated framework to model the interactions between land use, climate, and hydrology along with stakeholders’ negotiation. Its novelty lies in the combination of individual-based and spatially distributed models within the Socio-Hydrology paradigm to capture the complexity and uncertainty inherent to these systems. It encompasses a land-use/land-cover cellular automata model, an agent-based model used for automated stakeholders’ negotiation, and the hydrological MIKE SHE/MIKE 11 model, which are linked and can be accessed through a web-based interface. It enables users to run simulations to explore a wide range of scenarios related to land development and water resource management while considering the reciprocal influence of human and natural systems. This framework was developed with the involvement of key stakeholders from the initial design stage to the final demonstration and validation.
A New Strategy for the Prevention and Control of Eupatorium adenophorum under Climate Change in China
Authors: Wang Chong , Lin Huilong , Feng Qisheng , Jin Cangyu , Cao Aocheng , He Lan
Published: November 2017

Eupatorium adenophorum has caused tremendous ecological and economic losses in China since the 1940s. Although a great deal of money has been expended on the prevention and control of the weed, the situation is still deteriorating. To identify its crucial environmental constraints, an ecological niche factor analysis was employed. The distribution of the weed was predicted by the maximum entropy model. The results indicate that the temperature in winter is more influential than that in other quarters of a year, and the maximum temperature in March restricts the spread of E. adenophorum most. Currently, the weed is mainly distributed in four provinces of southwest China. From the present to the 2080s, the center of L3, which has a potential distribution probability of 0.7 to 1.0, will move 53 km to the southwest. Accordingly, the area of L3 will expand by 16.04%. To prevent its further expansion, we suggest differentiating the prevention and control measures according to the potential distribution levels predicted. Meanwhile, the integration of various means of removal and comprehensive utilization of E. adenophorum is highly encouraged. Additionally, precautions should be taken in regions that have not yet, or have been only slightly, invaded by the E. adenophorum.
All-Inclusiveness versus Exclusion: Urban Project Development in Latin America and Africa
Authors: Klaufus Christien , Van Lindert Paul , Van Noorloos Femke , Steel Griet
Published: November 2017

This paper scrutinizes current processes of urban fragmentation, segregation, and exclusion that result from the increasing flows of capital in gated communities, walled-off condominiums, and similar exclusivist investment hubs in Latin America and sub-Saharan Africa. Gated community-like developments are growing and spreading into new areas. Although not all of the walled projects offer all-inclusiveness, they are unanimously based on the pre-selection of specific categories of residents. Moreover, all-inclusive urban developments are taking on new and more encompassing forms, such as ‘gated cities’. Hence, socio-spatial inclusion and exclusion in the urban built environment are continuously transforming under the influence of investment capital (i.e., new urban investment flows and speculation), urbanistic concepts (e.g., different interpretations of safety and crime), and human mobilities. This paper builds on a comparison of empirical cases from Latin America and Africa to develop a qualitative framework of segregation indicators. In Latin America, gated communities have a long history, but exclusionary developments are changing in form, as well as in implications. In Africa, research on gated communities has particularly focused on South Africa (where they have a longer history), but exclusionary developments are spreading rapidly across the continent, and will influence future real estate development and land markets. Based on such complementary experiences, this paper grapples with the question of how these new all-inclusive developments influence the possibilities of achieving inclusive and sustainable urban transitions, as advocated in Sustainable Development Goal 11 (SDG11) and the New Urban Agenda.
The impact of Lighting on Vandalism in Hot Climates: The Case of the Abu Shagara Vandalised Corridor in Sharjah, United Arab Emirates
Authors: Mushtaha Emad , Ayssar Nahlé Ranime , Bin Saifan Maitha , Altan Hasim
Published: November 2017

This study mainly discusses how the immature behaviour of a part of the society, resulting in vandalism, affects the building aesthetics and design features in the districts of the city of Sharjah, in the United Arab Emirates (UAE). Initially explaining the term “vandalism” in itself, this study goes on to debate on the reasons behind vandalism, its different types, and its effects on the environment. Throughout the discussion, studies of the relationship between vandalism and reflectivity are examined, considering how the characteristics and features of the buildings affect vandalism. Three methodology tools were used: a questionnaire, an Integrated Environmental Solution Virtual Environment (IESVE) software program, and illuminance measurements. Simulation scenarios of the current situation of Abu Shagara were performed, which took into account several options with respect to wall material, flooring material, and types of lighting. All in all, ten simulation cases were conducted and compared, which allowed the identification of the best simulation scenario. The type of lighting had a greater impact on the simulation scenario results than the type of wall and flooring materials. The type of lighting varied as per its polar grid and light distribution.
Building Sustainable Development through Technology Transfer in a Romanian University
Authors: Vac Calin S. , Fitiu Avram
Published: November 2017

To improve university and commercial ties with industry, many universities operate a technology transfer office (TTO) as a vehicle to support the creation of spin-off companies. Run effectively, the TTO can define roles and responsibilities, structures and processes that support the creation and development of new ventures. The challenge for universities is to create TTOs with the right skill set. This paper aims to analyze the TTO activities to support transforming research outputs into commercialization in the context of the University of Agricultural Sciences and Veterinary Medicine from Cluj-Napoca, Romania (UASVMCN). Throughout this paper, different commercialization channels, the roles of technology transfer offices and multiple associative structures are further discussed with a special focus on agricultural open innovations and technologies. This study contributes to sustainable development of both Academia and agricultural Industry research, development and commercialization activities by illustrating current innovation and technology transfer activities produced by UASVMCN and its own TTO as a catalyst entity, a new model in Romania, so that the Academia-TTO-Economy partners association draw a functional and productive triple helix. In order to assess the sustainability of using the above-mentioned TTO, the methodological tools involving analysis are implemented. Finally, this paper states that correct operating of a university TTO is a real opportunity for technology transfer, both from the perspective of an alternative to research funding or entrepreneurship, and from the cultural perspective of the university correlation to the current trends in research, innovation and technology transfer, on a unique and entrepreneurial European market.
Social Vulnerability to Natural Hazards in Urban Systems. An Application in Santo Domingo (Dominican Republic)
Authors: Giovene di Girasole Eleonora , Cannatella Daniele
Published: November 2017

The concept of risk has become increasingly complex, and has been used not only in relation to the natural features of a region, but also to its socio-economic context. In this conceptualization, the latter directly influences the capacity of a community to cope with, recover from, and adapt to natural hazards. Conceiving vulnerability as a measure of a socio-ecological system’s resilience, and at the same time, as a multidimensional variable that changes in space and time, makes the study of the different ways in which natural hazards impact on society all the more urgent. This is particularly true for developing countries, where risk related to natural hazards affects populations and areas that must deal with stress conditions, such as humanitarian, social and military emergencies. This article presents a methodology for the analysis of social vulnerability, defined and experimented in the context of the international cooperation project “Estudio de la amenaza sísmica y vulnerabilidad física del Gran Santo Domingo”. The methodology, implemented through the employment of a Geographic Information System, led to the elaboration of a “Social Vulnerability Index” and a “Social Vulnerability Map”. These seek to describe the current condition of vulnerability of the city of Santo Domingo de Guzmán (Distrito Nacional) in the Dominican Republic (DR), and are used to define context-related vulnerability scenarios, as well as to indicate the adequate set of mitigation objectives and actions. The results highlight the importance of using social vulnerability study as the point of departure for defining seismic-risk mitigation policies, emergency management, and territorial planning in order to reduce the impacts of disasters.
Effects of Lonomia obliqua Venom on Vascular Smooth Muscle Cells: Contribution of NADPH Oxidase-Derived Reactive Oxygen Species
Authors: Moraes João , Rodrigues Genilson , Nascimento-Silva Vany , Renovato-Martins Mariana , Berger Markus , Guimarães Jorge , Barja-Fidalgo Christina
Published: November 2017

Envenomation caused by human contact with the caterpillar Lonomia is characterized by deleterious effects on coagulation and patency of blood vessels. The cellular effects induced by Lonomia obliqua venom highlights its capacity to activate endothelial cells, leading to a proinflammatory phenotype. Having more knowledge about the mechanisms involved in envenomation may contribute to better treatment. We aimed to evaluate the effects of Lonomia obliqua caterpillar bristle extract (LOCBE) on vascular smooth muscle cells (VSMC). We observed that LOCBE induced VSMC migration, which was preceded by alterations in actin cytoskeleton dynamics and Focal Adhesion Kinase activation. LOCBE also induced Extracellular Signal-Regulated Kinase (ERK) phosphorylation in VSMC, and the inhibition of this pathway impaired cell proliferation. Stimulation of VSMC with LOCBE triggered reactive oxygen species (ROS) production through the activation of NADPH oxidase. The rapid increase in these ROS further induced mitochondrial ROS production, however only NADPH oxidase-derived ROS were involved in ERK activation in VSMC. We that demonstrated the chemotactic and proliferative effects of LOCBE on VSMC were dependent on ROS production, mainly through NADPH oxidase. Together, the data show that Lonomia obliqua venom can interact with and activate VSMC. These effects rely on ROS production, suggesting new potential targets for treatment against vascular damage during envenomation.
Efficacy of Bee Venom Acupuncture for Chronic Low Back Pain: A Randomized, Double-Blinded, Sham-Controlled Trial
Authors: Seo Byung-Kwan , Han Kyungsun , Kwon Ojin , Jo Dae-Jean , Lee Jun-Hwan
Published: November 2017

Bee venom acupuncture (BVA) is an effective treatment for chronic low back pain (CLBP) through the pharmacological effects of bee venom and the simultaneous stimulation of acupoints. However, evidence of its efficacy and safety in humans remains unclear. Using a double-blind, randomized study, 54 patients with non-specific CLBP were assigned to the BVA and sham groups. All participants underwent six sessions of real or sham BVA for 3 weeks, in addition to administration of 180 mg of loxonin per day. The primary outcome, that is, “bothersomeness” derived from back pain, was assessed using the visual analog scale. Secondary outcomes included pain intensity, dysfunction related to back pain (Oswestry Disability Index), quality of life (EuroQol 5-Dimension), and depressive mood (Beck’s depression inventory). Outcomes were evaluated every week during the treatment period and followed up at weeks 4, 8, and 12. After 3 weeks of the treatment, significant improvements were observed in the bothersomeness, pain intensity, and functional status in the BVA group compared with the sham group. Although minimal adverse events were observed in both groups, subsequent recovery was achieved without treatment. Consequently, our results suggest that it can be used along with conventional pharmacological therapies for the treatment of CLBP.
Rapid Construction of Complex Plant RNA Virus Infectious cDNA Clones for Agroinfection Using a Yeast-E. coli-Agrobacterium Shuttle Vector
Authors: Sun Kai , Zhao Danyang , Liu Yong , Huang Changjun , Zhang Wei , Li Zhenghe
Published: November 2017

The availability of infectious full-length clone is indispensable for reverse genetics studies of virus biology, pathology and construction of viral vectors. However, for RNA viruses with large genome sizes or those exhibiting inherent cloning difficulties, procedure to generate biologically active complementary DNA (cDNA) clones can be time-consuming or technically challenging. Here we have constructed a yeast-Escherichia coli-Agrobacterium shuttle vector that enables highly efficient homologous recombination in yeast for assembly of Agrobacterium compatible plant virus clones. Using this vector, we show that infectious cDNA clones of a plant negative-stranded RNA virus, sonchus yellow net rhabdovirus, can be rapidly assembled. In addition, one-step assembly of infectious clones of potato virus Y in yeast, either with or without intron, was readily achieved from as many as eight overlapping DNA fragments. More importantly, the recovered yeast plasmids can be transformed directly into Agrobacterium for inoculation, thereby obviating the E. coli cloning steps and associated toxicity issues. This method is rapid, highly efficient and cost-effective and should be readily applicable to a broad range of plant viruses.