bluuebunny/crossref_metadata_2025 huggingface dataset:
New Community and Sociohealth Challenges Arising from the Early Diagnosis of Mild Cognitive Impairment (MCI)
Authors: López Carolina , Altuna Miren
Published: September 2023

Population aging increases the risk of developing neurodegenerative diseases that cause cognitive impairment. Advances in clinical practice and greater social awareness of the importance of cognitive impairment have led to an increase in the number of people with early diagnosis, predementia. Increasing access to biomarkers to assess whether Alzheimer’s disease (AD) is the underlying cause of mild cognitive impairment (MCI) has undoubted clinical benefits (access to potentially disease-modifying treatments, among others) but is also responsible for new social–health care challenges. Understanding the psychosocial impact of a diagnosis of MCI due to AD or another neurodegenerative disease is essential to create future strategies to reduce the emotional overload of patients, their risk of discrimination and stigmatization, and to favor their social inclusion. We present a narrative review of the diagnostic process of mild cognitive impairment in clinical practice, with a holistic person-centered approach, and discuss the implications of such diagnosis (benefits and risks) and strategies on how to address them.
Integrating Neuromonitoring in Pediatric Emergency Medicine: Exploring Two Options for Point-of-Care Electroencephalogram (pocEEG) via Patient Monitors—A Technical Note
Authors: Simma Leopold , Romano Fabrizio , Schmidt Steffen , Ramantani Georgia , Bölsterli Bigna K.
Published: September 2023

Central nervous system (CNS) disorders are among the most frequent presentations in critically ill children. Status epilepticus (SE) is a frequent scenario in the resuscitation bay. In patients with altered mental status, non-convulsive SE (NCSE) is often underrecognized and critically impacts the neurological outcome and duration of hospitalization. An electroencephalogram (EEG) is required to diagnose NCSE. However, standard EEG recordings are time- and staff-intensive, and their availability is limited, especially outside regular working hours. We aimed to improve patient care by developing a simplified EEG recording method, using a reduced lead montage (point-of-care EEG—pocEEG), that is suitable for use in pediatric emergency departments. The objective was to devise a cost-effective unit with low space requirements that fitted the existing technical infrastructure. We present two technical options for clinical pocEEG acquisition using patient monitors (GE Carescape, Philips IntelliVue) that enable data collection for educational and research purposes. A simplified, rapid response EEG like the pocEEG enables neuromonitoring of patients with CNS disorders in pediatric emergency settings, facilitating timely diagnosis and treatment initiation when standard EEG is not readily available.
microRNA as a Maternal Marker for Prenatal Stress-Associated ASD, Evidence from a Murine Model
Authors: Woo Taeseon , King Candice , Ahmed Nick I. , Cordes Madison , Nistala Saatvika , Will Matthew J. , Bloomer Clark , Kibiryeva Nataliya , Rivera Rocio M. , Talebizadeh Zohreh , Beversdorf David Q.
Published: September 2023

Autism Spectrum Disorder (ASD) has been associated with a complex interplay between genetic and environmental factors. Prenatal stress exposure has been identified as a possible risk factor, although most stress-exposed pregnancies do not result in ASD. The serotonin transporter (SERT) gene has been linked to stress reactivity, and the presence of the SERT short (S)-allele has been shown to mediate the association between maternal stress exposure and ASD. In a mouse model, we investigated the effects of prenatal stress exposure and maternal SERT genotype on offspring behavior and explored its association with maternal microRNA (miRNA) expression during pregnancy. Pregnant female mice were divided into four groups based on genotype (wildtype or SERT heterozygous knockout (Sert-het)) and the presence or absence of chronic variable stress (CVS) during pregnancy. Offspring behavior was assessed at 60 days old (PD60) using the three-chamber test, open field test, elevated plus-maze test, and marble-burying test. We found that the social preference index (SPI) of SERT-het/stress offspring was significantly lower than that of wildtype control offspring, indicating a reduced preference for social interaction on social approach, specifically for males. SERT-het/stress offspring also showed significantly more frequent grooming behavior compared to wildtype controls, specifically for males, suggesting elevated repetitive behavior. We profiled miRNA expression in maternal blood samples collected at embryonic day 21 (E21) and identified three miRNAs (mmu-miR-7684-3p, mmu-miR-5622-3p, mmu-miR-6900-3p) that were differentially expressed in the SERT-het/stress group compared to all other groups. These findings suggest that maternal SERT genotype and prenatal stress exposure interact to influence offspring behavior, and that maternal miRNA expression late in pregnancy may serve as a potential marker of a particular subtype of ASD pathogenesis.
A Multifaced Aspect of Clostridium difficile Infection in Pediatric Patients with Inflammatory Bowel Disease: Case Series and Literature Review
Authors: Iana Elena , Boboc Catalin , Vlad Andreea Gabriela , Cosoreanu Maria Teodora , Anghel Malina , Boboc Anca Andreea , Ioan Andreea , Ionescu Mara Ioana , Gavriliu Liana , Galos Felicia
Published: September 2023

Children with inflammatory bowel disease (IBD) have an increased susceptibility to Clostridium difficile infection (CDI), with a rising incidence over time. Differentiating between CDI and IBD exacerbation is challenging due to overlapping symptoms. In our cohort of 55 pediatric IBD patients, 6 were diagnosed with CDI. Upon conducting a thorough patient evaluation and subsequent data analysis, an exhaustive review of the existing literature was undertaken. CDI is more prevalent in ulcerative colitis (UC) than Crohn’s disease (CD) patients, as seen in our patients and in the existing literature. The management of a pediatric patient with IBD is itself a challenge for a clinician because of the chronic, possibly relapsing course, and substantial long-term morbidity. When CDI is added, it becomes even more demanding, since CDI leads to more severe disease in children with IBD. A multidisciplinary approach and intensive treatment for possible sepsis, anemia, hypoalbuminemia, and hydro-electrolytic and acid-base imbalances are frequently mandatory in patients with CDI and IBD, which leads to a significant health care burden in hospitalized children with IBD. After the infection is treated with antibiotic therapy, important considerations regarding the future treatment for the underlying IBD are also necessary; in most cases, a treatment escalation is required, as also seen in our study group.
Association between Proteinuria Status and Risk of Hypertension: A Nationwide Population-Based Cohort Study
Authors: Lee Hyungwoo , Park Moo-Suk , Kang Min Kyoung , Song Tae-Jin
Published: September 2023

Proteinuria is associated with cardiovascular disease. However, the relationship between changes in proteinuria status and hypertension remains unclear. This study aimed to explore the association between changes in proteinuria status and the risk of developing hypertension with the data from the Korean National Health Insurance Database. We included participants without prior hypertension history who underwent their first health examination in 2003–2004 and a second examination in 2005–2006. Based on their proteinuria status during these two examinations, participants were classified into four groups: the proteinuria-free, proteinuria-resolved, proteinuria-developed, and chronic proteinuria groups. The study outcome was the incidence of hypertension. The study included 935,723 participants followed for a median of 14.2 years (mean age: 40.96 ± 11.01, 62.5% male participants). During this period, 346,686 (37.1%) cases of hypertension were reported. The chronic proteinuria group had the highest hypertension risk, followed by the proteinuria-developed, proteinuria-resolved, and proteinuria-free groups (p < 0.001). Those who recovered from proteinuria had a lower risk of developing hypertension than those with chronic proteinuria (hazard ratio: 0.58; 95% confidence interval: 0.53–0.63, p < 0.001). In contrast, individuals who developed proteinuria had a higher risk of hypertension than proteinuria-free individuals (hazard ratio: 1.31; 95% confidence interval: 1.26–1.35, p < 0.001). Our findings suggest a significant association between proteinuria status changes and hypertension. Effective management of proteinuria may potentially decrease the risk of developing hypertension.
Effectiveness of Dry Needling versus Manual Therapy in Myofascial Temporomandibular Disorders: A Single-Blind Randomized Controlled Trial
Authors: García-de la-Banda-García Rocío , Cortés-Pérez Irene , Ibancos-Losada María del Rocío , López-Ruiz María del Carmen , Obrero-Gaitán Esteban , Osuna-Pérez María Catalina
Published: September 2023

Dry needling (DN) is an invasive physiotherapy technique employed for reducing myofascial pain. To compare the effectiveness of dry needling (DN) versus manual therapy (MT) in improving pain, active maximal mouth opening (AMMO) and cervical disability in patients with myofascial pain from temporomandibular disorders (TMDs) were investigated against these treatments. A single-blind, randomized controlled trial was carried out. Individuals (n = 50) with TMDs were randomly allocated in a 1:1 ratio to the DN (n = 25) or MT group (n = 25). Each group received three sessions, separated by 4 days, of either DN or MT. Outcomes were assessed according to pain intensity (Numeric Pain Rating Scale), AMMO (cm), disability (Neck Disability Index), and pressure–pain threshold (PPT) (digital algometry) from the active myofascial trigger points. In both groups, pain and neck disability were significantly lower at the end of treatment compared with those measured at baseline (pain: −2.52 with 95% CI: −3.43 to −1.60 for DN group; pain: −2.92 with 95% CI: −3.77 to −2.07 for MT group; disability: −3.2 with 95% CI: −4.31 to −2.09 for DN group; disability: −2.68 with 95% CI: −3.56 to −1.79 for MT group), but not were not lower after the first session, without differences between the groups. AMMO was significantly higher after the first session (0.16 with 95% CI: 0.03 to 0.29 for DN group; 0.30 with 95% CI: 0.20 to 0.41 for MT group) and at the end of treatment in both groups (0.27 with 95% CI: 0.14 to 0.41 for DN group; 0.37 with 95% CI: 0.22 to 0.52 for MT group) compared with the baseline measurements. Finally, PPT results for the masseter and pterygoid muscles were significantly higher at the end of treatment in both groups (without statistically significant differences between groups), but not after the first session. The assessed therapies, DN and MT, are equally effective in improving pain, AMMO, cervical disability, and PPT in the muscles directly involved in the temporomandibular joint biomechanics of patients with myofascial TMDs.
Bladder Cancer during Pregnancy: A Review of the Literature
Authors: Peteinaris Angelis , Perros Paraskevas , Prokopakis Ioannis , Fasoulakis Zacharias , Ntounis Thomas , Daglas Konstantinos , Kostopoulou Ira Eirini , Samara Athina A. , Pagonis Konstantinos , Tatanis Vasileios , Faria-Costa Gabriel , Xhaferi Rudi , Arzumanyan Karen , Martínez Begoña Ballesta , Chionis Athanasios , Pergialiotis Vasilios , Daskalakis George , Kontomanolis Emmanuel N. , Koutras Antonios
Published: September 2023

Bladder malignancy represents the fourth most common cancer in men and the eighth in women in the western world. Women under 75 years of age have a risk of 0.5–1% of developing bladder cancer. The diagnosis usually occurs between 65 and 70 years of age, whereas the mortality rate for women varies from 0.5 to 4 per 100,000 every year. Nulliparous women present a greater risk than women who have given birth. The risk is further decreased when parity increases. Theoretically, hormonal changes occurring during pregnancy play a protective role. Smoking and occupational exposure to specific chemicals are the most common risk factors of bladder cancer. Other risk factors such as chronic urinary tract inflammation, cyclophosphamide, radiotherapy, and familial correlation have been reported. The aim of this review is to highlight a rare combination, which is the co-existence of bladder malignancy and pregnancy. We present thirteen different cases of women who were diagnosed with malignant bladder tumors during their pregnancy. A review of the literature was conducted, focusing on the unspecific symptoms, possible diagnostic tools, and suitable treatment modalities. The management of bladder cancer in pregnancy is a challenging process. The fragile balance between the possible complications of pregnancy and maternal health is yet to be discussed.
Integrated Modeling of Land Degradation Dynamics and Insights on the Possible Future Management Alternatives in the Gidabo River Basin, Ethiopian Rift Valley
Authors: Girma Rediet , Moges Awdenegest , Fürst Christine
Published: September 2023

Land degradation is a pivotal environmental concern, bearing substantial impacts in the Gidabo river basin (GRB) in Ethiopia, prompting a critical need for effective mitigation strategies. In this study, we aimed to assess the dynamics of land degradation pathways in the context of change in climate and land use. The identification of potential erosion hotspots and the appraisal of management strategies was also carried out. The Soil and Water Assessment Tool (SWAT) and the Good Practice Guidance (GPG) framework was employed. The results revealed a compelling synergy between land use dynamics and climate changes, asserting joint and individual prevalence in influencing surface runoff and sediment yield. The past simulation revealed 4–5.9% and 24–43% increments in mean annual runoff and sediment yield, respectively. While the near (2021–2040) and mid (2041–2060) future scenarios displayed varying trends under RCP4.5 and RCP8.5. Furthermore, sub-basins prone to soil erosion risk were identified, thereby enabling targeted conservation efforts. The assessment of trends in land degradation neutrality (LDN) unveiled the expansion of land degradation trajectories (by 26%) from 1985–2003 to 2003–2021. This might be attributed to the dynamic interplay between climate and land use land cover (LULC) change, with croplands and bare land emerging as high-risk degraded areas. Addressing these concerns, soil/stone bund, terracing, contour farming, and reforestation practice can significantly reduce the annual sediment yield in the future. The integration of soil erosion indicators with LDN sub-indicators can provide a more comprehensive approach that can lead to more effective land management and restoration strategies to achieve the LDN goal. The findings of this study could contribute crucial insights and substantial implications for policymakers, land managers, and conservationists. Moreover, future efforts should be directed to expand investigations into diverse land degradation pathways and mitigation measures.
Spatiotemporal Variation and Influencing Factors of Grain Yield in Major Grain-Producing Counties: A Comparative Study of Two Provinces from China
Authors: Wang Zhipeng , Zhang Ershen , Chen Guojun
Published: September 2023

The exploration of the spatiotemporal variations and influencing factors of grain yield in major grain-producing regions is greatly important to maintain stable and sustainable agriculture. Taking Henan Province and Heilongjiang Province as examples, this study reveals the spatiotemporal characteristics of grain yield at the county level by using multisource data on the economy, society, and natural geography from 2000 to 2021 and employing methods such as coefficients of variation, standard deviational ellipses, and spatial autocorrelation analysis. Moreover, geographical detector and geographically weighted regression models are combined to explore the differences in significant influencing factors between these provinces and the spatial heterogeneity of regression coefficients, respectively. The following findings are drawn: (1) Grain yield in both provinces gradually increased, with notable differences in the annual growth rate, the proportion, and at the county level. (2) The number of high-yield counties significantly increased and their spatial distribution became more concentrated, indicating a notable shift in the main regions. (3) The overall spatial correlation of grain yield steadily increased, and the local spatial correlation transitioned from random distribution to gradual aggregation. (4) There were significant differences in the influencing factors, where geographical environment, socio-economic factors, and input factors all affected both provinces. In summary, this study provides a scientific reference for governments worldwide to formulate rational and effective food production policies, thereby contributing to global food security and sustainable social development.
Diffuse Reflectance Spectroscopy for Mapping Soil Carbon Stock in the Gilbués Desertification Region at Brazilian Cerrado
Authors: Sousa Julio César Galdino de , Silva Yuri Jacques Agra Bezerra da , Martins Vanessa , Rodrigues Sueli , Teixeira Marcos Paulo Rodrigues , Dalto Paulo Henrique , Neves Laércio Vieira de Melo Wanderley , Sánchez-Rodríguez Antonio Rafael , Barbosa Ronny Sobreira
Published: September 2023

The carbon stock (C Stock) is a key soil attribute, especially in areas under degradation. The objective of this study was to map the C Stock and other physical and chemical attributes on the soil surface of a micro-watershed located in the Gilbués Desertification Nucleus and to calibrate pedometric functions to map them, applying spectra obtained by Diffuse Reflectance Spectroscopy (DRS) in the near-infrared (NIR) region. This study was developed in the Piripiri Stream Micro-watershed (PSMW), which presents different levels of degradation. A total of 214 composite soil samples were collected from the 0–0.10 m depth layer. Spectral and laboratory analyses were performed following traditional methods. The results from 100 samples were subjected to descriptive analysis, pedometric modeling, and geostatistics, while the remainder were used exclusively for the prediction and modeling of the predicted attribute maps. C Stock ranged from 0.3 to 11%, with the highest values associated with the least sandy sites. We assert that stakeholders, including government agencies, could utilize DRS for mapping main soil attributes, such as C Stocks, soil granulometry, or total organic carbon, in regions characterized by similar parent material and soil properties. This application can support informed decision-making regarding land management in extensive areas facing soil threats.
Unconventional Usage of Gender-Based Japanese Sentence-Final Particles: A Study of wa and no in Youth Conversations
Authors: Wang Yan
Published: September 2023

Japanese society’s traditional gender norms are reflected by sentence-final particles (SFPs) in daily conversation. However, recently, Japanese young people have started to use gendered SFPs in “unclassical” ways. This study mainly examines the usage of the so-called “female” SFPs wa and no by male speakers. In total, 68 cases of wa (43 by male speakers and 25 by female speakers) and 84 cases of no (47 by male speakers and 37 by female speakers) usage were collected from casual conversations of Japanese college students in TalkBank, a public linguistic database. This study demonstrates that the “female” SFPs wa and no are used more frequently by male speakers than by female speakers. Different from the female speakers’ usage to soften the utterances and enhance conversational rapport, wa and no used by male speakers perform other functions. In particular, wa directly indexes self-centeredness, serving the speaker to express emotion, share personal ideas, or perform speech acts such as teasing or amae in a self-focused way, while no directly indexes truthfulness, which allows the speaker to share a story in a vivid tone, reconfirm the speaker’s prior statement, or provide the speaker’s explanation/reasoning in an assertive tone. This study suggests that the new, unconventional gender-based usages of SFPs reveal the social changes in gender dynamics in modern Japanese society, which should not be overlooked in language education.
Fipronil Degradation in Soil by Enterobacter chengduensis Strain G2.8: Metabolic Perspective
Authors: Prado Caio , Pereira Rodrigo , Durrant Lucia , Júnior Rômulo , Piubeli Francine , Bonfá Maricy
Published: September 2023

Fipronil is an insecticide widely used in the agricultural and veterinary sectors for its efficacy in pest control. The presence of fipronil in the environment is mainly due to agricultural and domestic practices and is frequently found in different types of environmental matrices in concentrations ranging from µg/L to mg/L and can be hazardous to non-target organisms due to its high toxicity. This study was carried out to obtain and characterize microorganisms from soil which are capable of biodegrading fipronil that could be of great biotechnological interest. For this purpose, bioprospecting was carried out using fipronil (0.6 g/L) as the main source of carbon and nitrogen for growth. Once obtained, the strain was identified by sequencing the 16S ribosomal RNA (rRNA) gene and the capacity to degrade fipronil was monitored by GC-MS. Our study showed a presence in soil samples of the strain identified as Enterobacter chengduensis, which was able to metabolize fipronil and its metabolites during the mineralization process. Enterobacter chengduensis was able to biodegrade fipronil (96%) and its metabolites fipronil-sulfone (92%) and fipronil-sulfide (79%) in 14 days. Overall, the results of this study provided a bacterium with great potential that could contribute to the degradation of fipronil in the environment.
Secretory IgA-ETEC F5 Immune Complexes Promote Dendritic Cell Differentiation and Prime T Cell Proliferation in the Mouse Intestine
Authors: Qin Da , Li Ying , Chen Xiaoyan , Li Liyang , Wang Guihua , Hou Xilin , Yu Liyun
Published: September 2023

Although secretory IgA (SIgA) is the dominant antibody in mucosal secretions, the capacity of the SIgA–antigen complex to prime the activation of dendritic cells (DCs) and T cells in the intestinal epithelium is not well understood. To this end, the SIgA–ETEC F5 immune complexes (ICs) were prepared via Ni-NTA pull-down. After injecting the ICs into the intestines of SPF BALB/c mice, most ICs were observed in the Peyer’s patch (PP). We established a microfold (M) cell culture model in vitro for transport experiments and the inhibition test. To evaluate the priming effect of mucosal immunity, we employed the DC2.4 stimulation test, T lymphocyte proliferation assays, and cytokine detection assays. We found that the ICs were taken up via clathrin-dependent endocytosis through M cells. The high expression of costimulatory molecules CD86, CD80, and CD40 indicated that the ICs promoted the differentiation and maturation of DC2.4 cells. The stimulation index (SI) in the complex group was significantly higher than in the control group, suggesting that the ICs stimulated the proliferation of primed T cells. The secretion of some cytokines, namely TNF-α, IFN-γ, IL-2, IL-4, IL-5, and IL-6, in spleen cells from the immunized mice was upregulated. These results indicate that ETEC F5 delivery mediated by SIgA in PPs initiates mucosal immune responses.
First Record of the Family Malachiidae (Coleoptera: Cleroidea) from Mid-Cretaceous Burmese Amber with a Description of Burmalachius acroantennatus Gen. et Spec. Nov.
Authors: Tshernyshev Sergei E. , Legalov Andrei A.
Published: September 2023

A new soft-winged flower beetle, Burmalachius acroantennatus gen. et sp. nov. belonging to the tribe Malachiini (Coleoptera: Malachiidae), discovered in mid-Cretaceous Burmese amber is described. The new genus differs from the congeners of the tribe Malachiini in possessing the following characteristics: anterior tibiae widened and slightly curved inwards and excavate near the apices, tarsomeres of anterior legs depressed, 1st to 3rd tarsomeres simple and almost of equal size, tarsal comb lacking, “clavate” antennae due to dilated three apical antennomeres, 1st and 2nd antennomeres enlarged and of identical size, head strongly elongate, sides of elytra with carinate margins and widened epipleurae. This is the first record of the family Malachiidae in Burmese amber. Illustrations of the newly described species are provided. Keys for the identification of Melyrid lineage families, subfamilies of Malachiidae, tribes of the subfamily Malachiinae and genera of the tribe Malachiini are also given.
Revascularization and Left Ventricular Dysfunction for ICD Eligibility
Authors: Romano Letizia Rosa , Spaccarotella Carmen Anna Maria , Indolfi Ciro , Curcio Antonio
Published: September 2023

Common triggers for sudden cardiac death (SCD) are transient ischemia, hemodynamic fluctuations, neurocardiovascular influences, and environmental factors. SCD occurs rapidly when sinus rhythm degenerates into ventricular tachycardia (VT) and/or ventricular fibrillation (VF), followed by asystole. Such progressive worsening of the cardiac rhythm is in most cases observed in the setting of ischemic heart disease and often associated with advanced left ventricular (LV) impairment. Revascularization prevents negative outcomes including SCD and heart failure (HF) due to LV dysfunction (LVD). The implantable cardioverter–defibrillator (ICD) on top of medical therapy is superior to antiarrhythmic drugs for patients with LVD and VT/VF. The beneficial effects of ICD have been demonstrated in primary prevention of SCD as well. However, yet debated is the temporal management for patients with LVD who are eligible to ICD prior to revascularization, either through percutaneous or surgical approach. Restoration of coronary blood flow has a dramatic impact on adverse LV remodeling, while it requires aggressive long-term antiplatelet therapy, which might increase complication for eventual ICD procedure when percutaneous strategy is pursued; on the other hand, when LV and/or multiorgan dysfunction is present and coronary artery bypass grafting is chosen, the overall risk is augmented, mostly in HF patients. The aims of this review are to describe the pathophysiologic benefits of revascularization, the studies addressing percutaneous, surgical or no revascularization and ICD implantation, as well as emerging defibrillation strategies for patients deemed at transient risk of SCD and/or at higher risk for transvenous ICD implantation.
The Effect of Al and Ti Additions on Solid Solution Strengthening and Precipitation Hardening in CoNiFe Medium-Entropy Alloys
Authors: Bała Piotr , Górecki Kamil , Dziurka Rafał , Kozieł Tomasz
Published: September 2023

The effect of Al and Ti additions on the microstructure and properties of CoNiFe alloys was studied in this paper. The investigations were conducted on four specially designed and produced arc furnace alloys (from 3 to 5 components, with medium to high entropy). Samples in various states were analyzed, i.e., as-cast, after homogenization, after solution heat treatment, and after solution heat treatment and aging. The obtained samples were characterized by: SEM observations, EDS, XRD, TEM analyses, and finally, hardness measurements. The solid solution strengthening coming from the addition of 5 at. pct. Al was negligible, while the effect from the 5 at. pct. of Ti addition was significant. The precipitation hardening effect related to the presence of the (CoNi)3Ti phase caused by the Ti addition is comparable with the total effect of the Al and Ti addition, which caused the precipitation of (NiCo)3AlTi.
Emergent Magnonic Materials: Challenges and Opportunities
Authors: Gaur Samanvaya S. , Marinero Ernesto E.
Published: September 2023

Advances in information technology are hindered by energy dissipation from Joule losses associated with charge transport. In contrast, the process of information based on spin waves propagation (magnons) in magnetic materials is dissipationless. Low damping of spin wave excitations is essential to control the propagation length of magnons. Ferrimagnetic Y3Fe5O12 garnets (YIG) exhibit the lowest magnetic damping constants. However, to attain the lowest damping constant, epitaxial growth of YIG on single crystal substrates of Gd3Ga5O12 at elevated temperatures is required, which hinders their CMOS integration in electronic devices. Furthermore, their low saturation magnetization and magnetocrystalline anisotropy are challenging for nanoscale device applications. In the search for alternative material systems, polycrystalline ferromagnetic Co25Fe75 alloy films and ferrimagnetic spinel ferrites, such as MgAl0.5Fe1.5O4 (MAFO), have emerged as potential candidates. Their damping constants are comparable, although they are at least one order of magnitude higher than YIG’s. However, Co25Fe75 alloy thin film growth is CMOS compatible, and its magnon diffusion length is 20× longer than in MAFO. In addition, MAFO requires epitaxial growth on lattice-matched MgAl2O4 substrates. We discuss the material properties that control the Gilbert damping constant in CoxFe1−x alloys and MAFO and conclude that CoxFe1−x alloy thin films bring us closer to the realization of the exploitation of spin waves for magnonics.
Machine Learning-Enabled Quantitative Analysis of Optically Obscure Scratches on Nickel-Plated Additively Manufactured (AM) Samples
Authors: Mengesha Betelhiem N. , Grizzle Andrew C. , Demisse Wondwosen , Klein Kate L. , Elliott Amy , Tyagi Pawan
Published: September 2023

Additively manufactured metal components often have rough and uneven surfaces, necessitating post-processing and surface polishing. Hardness is a critical characteristic that affects overall component properties, including wear. This study employed K-means unsupervised machine learning to explore the relationship between the relative surface hardness and scratch width of electroless nickel plating on additively manufactured composite components. The Taguchi design of experiment (TDOE) L9 orthogonal array facilitated experimentation with various factors and levels. Initially, a digital light microscope was used for 3D surface mapping and scratch width quantification. However, the microscope struggled with the reflections from the shiny Ni-plating and scatter from small scratches. To overcome this, a scanning electron microscope (SEM) generated grayscale images and 3D height maps of the scratched Ni-plating, thus enabling the precise characterization of scratch widths. Optical identification of the scratch regions and quantification were accomplished using Python code with a K-means machine-learning clustering algorithm. The TDOE yielded distinct Ni-plating hardness levels for the nine samples, while an increased scratch force showed a non-linear impact on scratch widths. The enhanced surface quality resulting from Ni coatings will have significant implications in various industrial applications, and it will play a pivotal role in future metal and alloy surface engineering.
Novel Antibacterial Materials and Coatings—A Perspective by the Editors
Authors: Haidari Hanif , Vasilev Krasimir
Published: September 2023

The fight between humans and bacteria has escalated to a new level
Influence Analysis of Modified Polymers as a Marking Agent for Material Tracing during Cyclic Injection Molding
Authors: Eggers Tom , Blumberg Sonja Marit , von Lacroix Frank , Berlin Werner , Dröder Klaus
Published: September 2023

Injection molding (IM) is already an established technology for manufacturing polymer products. However, in the course of the increased use of recyclates for economic and ecological reasons, its application capability has been confronted with new requirements for reliability and reproducibility. In addition, the IM process is confronted with regulations regarding a verifiable recycling degree in polymers. With regard to the material identification and storage of manufacturer-, process- or product-related data in polymers, the implementation of a material-inherent marking technology forms a potential answer. The IM process combined with modified polymers (MP) as a marking technology turns out to be a feasible approach to manufacturing reproducibly and offers a high quality based on increased process awareness and fulfilling the required traceability. Therefore, this work focuses on the trial evaluation of MP within the IM process. The influence of MP on the material process behavior and mechanical and thermal component properties, as well as the influence of the IM process and recycling on MP traceability, are investigated. No discernible influences of MP on the investigated properties could be identified, and the traceability from the initial material to a recyclate could be confirmed. MP is suitable for monitoring the aging state of polymers in IM.
A Preliminary Study on the Use of Highly Aromatic Pyrolysis Oils Coming from Plastic Waste as Alternative Liquid Fuels
Authors: Asueta Asier , Fulgencio-Medrano Laura , Miguel-Fernández Rafael , Leivar Jon , Amundarain Izotz , Iruskieta Ana , Arnaiz Sixto , Gutiérrez-Ortiz Jose Ignacio , Lopez-Urionabarrenechea Alexander
Published: September 2023

In this work, the low-temperature pyrolysis of a real plastic mixture sample collected at a WEEE-authorised recycling facility has been investigated. The sample was pyrolysed in a batch reactor in different temperature and residence time conditions and auto-generated pressure by following a factorial design, with the objective of maximising the liquid (oil) fraction. Furthermore, the main polymers constituting the real sample were also pyrolysed in order to understand their role in the generation of oil. The pyrolysis oils were characterised and compared with commercial fuel oil number 6. The results showed that in comparison to commercial fuel oil, pyrolysis oils coming from WEEE plastic waste had similar heating values, were lighter and less viscous and presented similar toxicity profiles in fumes of combustion.
Effect of CrF3 Addition on Photoluminescence Properties of Lead-Free Cs4SnBr6−xFx Zero-Dimensional Perovskite
Authors: Chen Jianni , Wu Haixia , Huang Yaqian , Xu Jisheng , Lu Xinye , Zhou Wendi , Song Jie , Huang Rui
Published: September 2023

Zero-dimensional (0D) tin halide perovskites, characterized by their broadband and adjustable emissions, high photoluminescence quantum yield, and absence of self-absorption, are crucial for the fabrication of high-efficiency optoelectronic devices, such as LEDs, solar cells, and sensors. Despite these attributes, boosting their emission efficiency and stability poses a significant challenge. In this work, Cr3+-doped Cs4SnBr6−xFx perovskites were synthesized using a water-assisted wet ball-milling method. The effect of CrF3 addition on photoluminescence properties of Cs4SnBr6−xFx Perovskites was investigated. We found that Cr3+-doped Cs4SnBr6−xFx Perovskites exhibit a broad emission band, a substantial Stokes shift, and an efficient green light emission centered at about 525 nm at ambient temperature. The derived photoluminescence quantum yield amounted to as high as 56.3%. In addition, these Cr3+-doped Cs4SnBr6−xFx perovskites outperform their undoped counterparts in terms of thermal stability. Through a comprehensive analysis of photoluminescence measurements, our findings suggested that the elevated photoluminescence quantum yield can be attributed to the enhanced exciton binding energy of self-trapped excitons (STEs) and the suitable electron−phonon coupling resulting from the substantial distortion of [SnBr6]4− octahedra instigated by the addition of CrF3.
Lead-Free Halide Perovskite Nanocrystals for Light-Emitting Diodes
Authors: Kim Do-Young , Jung Jae-Geun , Lee Ye-Ji , Park Min-Ho
Published: September 2023

Lead-based halide perovskite nanocrystals (PeNCs) have demonstrated remarkable potential for use in light-emitting diodes (LEDs). This is because of their high photoluminescence quantum yield, defect tolerance, tunable emission wavelength, color purity, and high device efficiency. However, the environmental toxicity of Pb has impeded their commercial viability owing to the restriction of hazardous substances directive. Therefore, Pb-free PeNCs have emerged as a promising solution for the development of eco-friendly LEDs. This review article presents a detailed analysis of the various compositions of Pb-free PeNCs, including tin-, bismuth-, antimony-, and copper-based perovskites and double perovskites, focusing on their stability, optoelectronic properties, and device performance in LEDs. Furthermore, we address the challenges encountered in using Pb-free PeNC-LEDs and discuss the prospects and potential of these Pb-free PeNCs as sustainable alternatives to lead-based PeLEDs. In this review, we aim to shed light on the current state of Pb-free PeNC LEDs and highlight their significance in driving the development of eco-friendly LED technologies.
Complexity-Efficient Sidelink Synchronization Signal Detection Scheme for Cellular Vehicle-to-Everything Communication Systems
Authors: You Young-Hwan , Jung Yong-An
Published: September 2023

Synchronization is a challenging issue in vehicle-to-everything (V2X) cellular communication, especially when V2X devices need to directly communicate with each other outside the network coverage area. By adopting the maximum likelihood principle, we propose joint detection of the sidelink secondary synchronization signal (SL-SSS) and carrier frequency offset (CFO) in a V2X system using 5G new radio sidelink. We formulate an effective joint coherent synchronization scheme for cellular V2X applications by decoupling the estimation of the sidelink identity and CFO, which requires a priori knowledge of channel state information. To verify the feasibility of the proposed detection scheme, we derive a simplified implementation of the proposed SL-SSS detector and a closed-form expression for the detection probability. Simulation results demonstrate that the proposed SL-SSS detector exhibits either comparable performance in terms of detection probability or reduced complexity when compared with conventional SL-SSS detectors. Using the proposed method in the cellular V2X system enables V2X devices to achieve robust synchronization with reduced power consumption during the initial synchronization procedure, while also offering valuable insights for designing a simple, efficient sidelink synchronization receiver.
Identifying Bias in Social and Health Research: Measurement Invariance and Latent Mean Differences Using the Alignment Approach
Authors: Tsaousis Ioannis , Jaffari Fathima M.
Published: September 2023

When comparison among groups is of major importance, it is necessary to ensure that the measuring tool exhibits measurement invariance. This means that it measures the same construct in the same way for all groups. In the opposite case, the test results in measurement error and bias toward a particular group of respondents. In this study, a new approach to examine measurement invariance was applied, which was appropriately designed when a large number of group comparisons are involved: the alignment approach. We used this approach to examine whether the factor structure of a cognitive ability test exhibited measurement invariance across the 26 universities of the Kingdom of Saudi Arabia. The results indicated that the P-GAT subscales were invariant across the 26 universities. Moreover, the aligned factor mean values were estimated, and factor mean comparisons of every group’s mean with all the other group means were conducted. The findings from this study showed that the alignment procedure is a valuable method to assess measurement invariance and latent mean differences when a large number of groups are involved. This technique provides an unbiased statistical estimation of group means, with significance tests between group pairs that adjust for sampling errors and missing data.
Age Differences in Cardiopulmonary Exercise Testing Parameters in Heart Failure with Reduced Ejection Fraction
Authors: Garcia Brás Pedro , Gonçalves António Valentim , Reis João Ferreira , Moreira Rita Ilhão , Pereira-da-Silva Tiago , Rio Pedro , Timóteo Ana Teresa , Silva Sofia , Soares Rui M. , Ferreira Rui Cruz
Published: September 2023

Background and Objectives: Cardiopulmonary exercise testing (CPET) is a cornerstone of risk stratification in heart failure with reduced ejection fraction (HFrEF). However, there is a paucity of evidence on its predictive power in older patients. The aim of this study was to evaluate the prognostic power of current heart transplantation (HTx) listing criteria in HFrEF stratified according to age groups. Materials and Methods: Consecutive patients with HFrEF undergoing CPET between 2009 and 2018 were followed-up for cardiac death and urgent HTx. Results: CPET was performed in 458 patients with HFrEF. The composite endpoint occurred in 16.8% of patients ≤50 years vs. 14.1% of patients ≥50 years in a 36-month follow-up. Peak VO2 (pVO2), VE/VCO2 slope and percentage of predicted pVO2 were strong independent predictors of outcomes. The International Society for Heart and Lung Transplantation thresholds of pVO2 ≤ 12 mL/kg/min (≤14 if intolerant to β-blockers), VE/VCO2 slope > 35 and percentage of predicted pVO2 ≤ 50% presented a higher overall diagnostic effectiveness in younger patients (≤50 years). Specific thresholds for each age subgroup outperformed the traditional cut-offs. Conclusions: Personalized age-specific thresholds may contribute to an accurate risk stratification in HFrEF. Further studies are needed to address the gap in evidence between younger and older patients.
Cardiovascular Collapse after the Induction of Anesthesia Due to the MASS Effect of Unruptured Giant Bullae
Authors: Park Junghyun , Kim Dulee , Park Jae-Hoo , Lee Ji-Yun , Cho Eun-Jung
Published: September 2023

Background and Objectives: Giant bullae rupture easily and cause tension pneumothorax, which can cause problems during general anesthesia. However, the hemodynamic instability that can occur due to the mass effect of an unruptured giant bulla should not be overlooked. Case report: A 43-year-old male patient visited the emergency room with an abdominal wound. There was a giant emphysematous bulla in the left lung. Emergency surgery was decided upon because there was active bleeding according to abdominal CT. After tracheal intubation, the patient’s blood pressure and pulse rate dramatically decreased. His blood pressure did not recover despite the use of vasopressors and discontinuation of positive pressure ventilation applied to the lungs. Thus, a bullectomy was immediately performed. The patient’s blood pressure and pulse rate were normalized after the bullectomy. Conclusions: If emergency surgery under general anesthesia is required in a patient with a giant emphysematous bulla, it is safe to minimize positive pressure ventilation and remove the giant emphysematous bulla as soon as possible before proceeding with the remainder of the surgery. Tension pneumothorax due to the rupturing of a bulla should be considered first. However, hemodynamic changes might occur due to the mass effect caused by a giant bulla.
Tuning Non-Isothermal Crystallization Kinetics between Fe20Co20Ni20Cr20(P0.45B0.2C0.35)20 High-Entropy Metallic Glass and the Predecessor Fe75Cr5P9B4C7 Metallic Glass
Authors: Xu Tao , Yao Jiansheng , Zhuo Longchao , Jie Ziqi
Published: September 2023

In the present work, comparisons of non-isothermal crystallization kinetics between Fe20Co20Ni20Cr20(P0.45B0.2C0.35)20 high-entropy metallic glass (HEMG) and the predecessor Fe75Cr5P9B4C7 metallic glass (MG) were performed with X-ray diffraction and differential scanning calorimetry approaches. The HEMG possesses a harsher crystallization process compared with the predecessor MG, deriving from a higher triggering energy for all the characteristic transitions and local activation energy along with a smaller local Avrami exponent and a growth with pre-existing nuclei. Meanwhile, the glass transition is the easiest process, but the nucleation of the second crystallization case is the hardest transition for the HEMG. However, the predecessor MG possesses distinctly different crystallization features of a moderate difficulty for the glass transition, the harshest process for the growth transition of the second crystallization case, and a crystallization of growth with a diverse nucleation rate. These results conclusively prove that the non-isothermal crystallization kinetics can be significantly changed after the present high-entropy alloying with the substitution of similar solvent elements Co, Ni, and Cr with Fe in Fe75Cr5P9B4C7 MG. Moreover, the two alloys possess a strong glassy formation melt with high thermal stability and diverse crystallized products after non-isothermal crystallization.
Hydrothermal Leaching Kinetics of Vanadium from an Iron Vanadate Mineral Using Oxalic Acid
Authors: Shen Biao , Chen Xuexin , Yan Baijun
Published: September 2023

Hydrothermal leaching vanadium using oxalic acid is a novel method reported recently to overcome the serious environmental problems caused by traditional extracting processes. In view of its promising application potential, the hydrothermal leaching kinetics of vanadium from a concentrate mainly composed of Fe3−xVxO4 mineral via oxalic acid were investigated in this study. Firstly, the effects of the temperature and concentration of oxalic acid on the leaching behavior of vanadium were studied by measuring the leaching efficiency of vanadium at various times. Then, by fitting the measured leaching efficiency data to the proposed kinetic model, the leaching mechanism was analyzed and the rate-controlling step of the leaching process, the apparent activation energy, and the order of the chemical reactions were determined. Finally, a kinetic model was proposed to describe the present investigated leaching process. Detailed results are as follows: (1) an interfacial chemical reaction was the rate-controlling step of the present hydrothermal leaching process within temperatures ranging from 363 to 403 K, and the leaching efficiency was less than 85%; (2) the apparent activation energy of the interfacial chemical reaction was 45.6 kJ/mol; (3) the order of the interfacial chemical reaction to the concentration of oxalic acid was around 1.66.