bluuebunny/crossref_metadata_2025 huggingface dataset:
Inter-Cavity Coupling Strength Control in Metal/Insulator Multilayers for Hydrogen Sensing
Authors: Caligiuri Vincenzo , De Luca Antonio
Published: December 2021

Hydrogen (H2) sensing is crucial for modern energy storage technology, which looks to hydrogen as the most promising alternative to fossil fuels. In this respect, magnesium (Mg) offers unique possibilities, since magnesium and hydrogen easily undergo a reversible hydrogenation reaction where Mg reversibly converts into MgH2. From an optical point of view, this process produces an abrupt refractive index change, which can be exploited for sensing applications. To maximize this opportunity, we envision an architecture composed of two Ag/ITO/Mg metal/dielectric resonators facing each other and displaced by 200 nm of vacuum. This structure forms a so-called Epsilon-Near-Zero (ENZ) multi-cavity resonator, in which the two internal Mg layers, used as tunneling coupling metals, are accessible to environmental agents. We demonstrate that the hydrogenation of the two Mg layers leads to substantial changes in the strong coupling between the cavities composing the entire resonator, with a consequent abrupt modification of the spectral response, thus enabling the sensing mechanism. One of the main advantages of the proposed system with respect to previous research is that the proposed multilayered architecture avoids the need for lithographic processes. This feature makes the proposed architecture inexpensive and wafer-to-chip scalable, considering that each kind of substrate from common glass to silicon can be used. Therefore, our sensing architecture offers great promise for applications in embedded H2 sensors.
Nano-grating Assisted Light Absorption Enhancement for MSM-PDs Performance Improvement: An Updated Review
Authors: Das Narottam , Nur-E-Alam Mohammad , Islam Alif , Ain Ain Zulaikha Maslihan
Published: December 2021

The primary focus of this review article mainly emphasizes the light absorption enhancement for various nanostructured gratings assisted metal-semiconductor-metal photodetectors (MSM-PDs) that are so far proposed and developed for the improvement of light capturing performance. The MSM-PDs are considered as one of the key elements in the optical and high-speed communication systems for applications such as faster optical fiber communication systems, sensor networks, high-speed chip-to-chip interconnects, and high-speed sampling. The light absorption enhancement makes the MSM-PDs an ideal candidate due to their excellent performances in detection, especially in satisfying the high-speed or high-performance device requirements. The nano-grating assisted MSM-PDs are preordained to be decorous for many emerging and existing communication device applications. There have been a significant number of research works conducted on the implementation of nano-gratings, and still, more researches are ongoing to raise the performance of MSM-PDs particularly, in terms of enhancing the light absorption potentialities. This review article aims to provide the latest update on the exertion of nano-grating structures suitable for further developments in the light absorption enhancement of the MSM-PDs.
Gamma-ray Spectroscopy Using Inorganic Scintillator Coated with Reduced Graphene Oxide in Fiber-Optic Radiation Sensor
Authors: Kim Jin Ho , Kim Seunghyeon , Song Siwon , Lim Taeseob , Park Jae Hyung , Kim Jinhong , Pyeon Cheol Ho , Hwang Sung Won , Lee Bongsoo
Published: December 2021

In this study, we developed a remote gamma-ray spectroscopy system based on a fiber-optic radiation sensor (FORS) that is composed of an inorganic scintillator coated with reduced graphene oxide (RGO) and a plastic optical fiber (POF). As a preliminary experiment, we measured the transmitted light intensities using RGO membranes of different thicknesses with different wavelengths of emitted light. To evaluate the FORS performance, we determined the optimal thickness of the RGO membrane and measured the amounts of scintillating light and gamma energy spectra using radioactive isotopes such as 60Co and 137Cs. The amounts of scintillating light from the RGO-coated inorganic scintillators increased, and the energy resolutions of the gamma-ray spectra were enhanced. In addition, the gamma-ray energy spectra were measured using different types of RGO-coated inorganic scintillators depending on the lengths of the POFs for remote gamma-ray spectroscopy. It was expected that inorganic scintillators coated with RGO in FORS can deliver improved performance, such as increments of scintillating light and energy resolution in gamma-ray spectroscopy, and they can be used to identify nuclides remotely in various nuclear facilities.
Detection Probability Analysis of True Random Coding Photon Counting Lidar
Authors: Yu Yang , Wang Zhangjun , Ma Kuntai , Chen Chao , Wang Xiufen , Xue Boyang , Li Xianxin , Zhang Feng , Pan Xin , Zhuang Quanfeng , Li Hui
Published: December 2021

With the wide application of lidar in the future, the problem of crosstalk between lidars will become more serious. True random coding photon counting lidar with high anti-crosstalk ability will play an important role in solving this problem. In this paper, based on the working principle of Gm-APD, the detection probability theoretical model of true random coding photon counting lidar is built, and the impact of jitter on detection probability is considered for the first time. The influence of mean echo photon number, mean pulse count density, sequence length and pulse width on detection probability is analyzed. Monte Carlo simulation and experimental results are highly consistent with the theoretical model, which proves the correctness of the detection probability theoretical model. This theoretical model provides an effective means to evaluate the system performance.
Energy Mechanisms of Free Vibrations and Resonance in Elastic Bodies
Authors: Alyushin Yury A.
Published: December 2021

The scientific novelty of this work is determined by the rationale for the participation in transformations, along with the kinetic energy of particles, of four types of elastic energy, identified by the peculiarities of their phase changes in the oscillation process. Two types are converted into kinetic energy, while the other two types change the deformed state of particles in accordance with the equations of motion due to internal sources. The result is obtained based on the use of the superposition principle in the space of Lagrange variables with the imposition of forced and free oscillations, as well as a new model of mechanics based on the concepts of space, time, and energy with a new scale of average stresses that takes into account the energy of particles in the initial state. In such a model of mechanics, a generalized measure of the elastic energy of particles is a quadratic invariant of asymmetric tensor whose components are partial derivatives of Euler variables with respect to Lagrange variables. The concept of kinematic energy parameters is introduced, which differ from the corresponding volumetric energy densities by a multiplier equal to the modulus of elasticity, which is directly proportional to the density and heat capacity of the material, and inversely proportional to the volumetric compression coefficient. Comparison of the values of kinematic parameters shows that most of the energy required for oscillations is associated with the deformation of particles and comes from internal sources. The mechanisms of transformation of forced vibrations into their own for transverse, torsional, and longitudinal vibrations are considered, as well as the occurrence of resonance when free and forced vibrations are superimposed with the same or a similar frequency. The formation of a new free wave after each cycle of external influences with an increase in amplitude, which occurs mainly due to internal, and not external, energy sources is justified.
Evaluation of Cylindrical Asymmetric Surface Dielectric Barrier Discharge Actuators for Surface Decontamination and Mixing
Authors: Ngo Alvin D. , Pai Kedar , Timmons Christopher , Ma Li Maria , Jacob Jamey
Published: December 2021

Surface dielectric barrier discharge (SDBD) was used to evaluate cylindrical plasma actuators for inactivation of Salmonella enterica. A cylindrical SDBD configuration was evaluated to determine if the inherent induced body force could be leveraged to impel plasma species, such as reactive oxygen and nitrogen species (RONS), as an apparatus to sterilize surfaces. The cylindrical structure is evaluated in this study to observe whether an increase in mixing is possible to efficiently distribute the plasma species, thereby improving bacterial inactivation efficiency. The increase in induced airflow of SDBD actuators with increased numbers of electrodes correlates with increased bacterial inactivation. These results suggest that improving the particle velocity, airflow mixing tendencies, and plasma volume for the same power inputs (same net power to the actuators) results in increased surface decontamination efficiency.
Porous Bilayer Vascular Grafts Fabricated from Electrospinning of the Recombinant Human Collagen (RHC) Peptide-Based Blend
Authors: Do Thi My , Yang Yang , Deng Aipeng
Published: December 2021

Cardiovascular diseases, including coronary artery and peripheral vascular pathologies, are leading causes of mortality. As an alternative to autografts, prosthetic grafts have been developed to reduce the death rate. This study presents the development and characterization of bilayer vascular grafts with appropriate structural and biocompatibility properties. A polymer blend of recombinant human collagen (RHC) peptides and polycaprolactone (PCL) was used to build the inner layer of the graft by electrospinning and co-electrospinning the water-soluble polyethylene oxide (PEO) as sacrificial material together with PCL to generate the porous outer layer. The mechanical test demonstrated the bilayer scaffold’s appropriate mechanical properties as compared with the native vascular structure. Human umbilical vein endothelial cells (HUVEC) showed enhanced adhesion to the lumen after seeding on nanoscale fibers. Meanwhile, by enhancing the porosity of the microfibrous outer layer through the removal of PEO fibers, rat smooth muscle cells (A7r5) could proliferate and infiltrate the porous layer easily.
Effect of Polymer Dissolution Temperature and Conditioning Time on the Morphological and Physicochemical Characteristics of Poly(Vinylidene Fluoride) Membranes Prepared by Non-Solvent Induced Phase Separation
Authors: Teixeira João , Cardoso Vanessa Fernandes , Botelho Gabriela , Morão António Miguel , Nunes-Pereira João , Lanceros-Mendez Senentxu
Published: December 2021

This work reports on the production of poly(vinylidene fluoride) (PVDF) membranes by non-solvent induced phase separation (NIPS) using N,N-dimethylformamide (DMF) as solvent and water as non-solvent. The influence of the processing conditions in the morphology, surface characteristics, structure, thermal and mechanical properties were evaluated for polymer dissolution temperatures between 25 and 150 °C and conditioning time between 0 and 10 min. Finger-like pore morphology was obtained for all membranes and increasing the polymer dissolution temperature led to an increase in the average pore size (≈0.9 and 2.1 µm), porosity (≈50 to 90%) and water contact angle (up to 80°), in turn decreasing the β PVDF content (≈67 to 20%) with the degree of crystallinity remaining approximately constant (≈56%). The conditioning time did not significantly affect the polymer properties studied. Thus, the control of NIPS parameters proved to be suitable for tailoring PVDF membrane properties.
Analysis of the Mechanical and Preforming Behaviors of Carbon-Kevlar Hybrid Woven Reinforcement
Authors: Qu Zhengtao , Gao Sasa , Zhang Yunjie , Jia Junhong
Published: December 2021

Carbon-Kevlar hybrid reinforcement is increasingly used in the domains that have both strength and anti-impact requirements. However, the research on the preforming behaviors of hybrid reinforcement is very limited. This paper aims to investigate the mechanical and preforming behaviors of carbon-Kevlar hybrid reinforcement. The results show that carbon-Kevlar hybrid woven reinforcement presents a unique “double-peak” tensile behavior, which is significantly different from that of single fiber type reinforcement, and the in-plane shear deformation demonstrates its large in-plane shear deformability. Both the tensile and in-plane shear behaviors present insensitivity to loading rate. In the preforming process, yarn slippage and out-of-plane yarn buckling are the two primary types of defects. Locations of these defects are closely related to the punch shape and the initial yarn direction. These defects cannot be alleviated or removed by just increasing the blank holder pressure. In the multi-layer preforming, the compaction between the plies and the friction between yarns simultaneously affect the quality of final preforms. The defect location of multi-layer preforms is the same as that of single-layer, while its defect range is much wider. The results found in this paper could provide useful guidance for the engineering application and preforming modeling of hybrid woven reinforcement.
Development and Progression of Polymer Electrolytes for Batteries: Influence of Structure and Chemistry
Authors: Rollo-Walker Gregory , Malic Nino , Wang Xiaoen , Chiefari John , Forsyth Maria
Published: December 2021

Polymer electrolytes continue to offer the opportunity for safer, high-performing next-generation battery technology. The benefits of a polymeric electrolyte system lie in its ease of processing and flexibility, while ion transport and mechanical strength have been highlighted for improvement. This report discusses how factors, specifically the chemistry and structure of the polymers, have driven the progression of these materials from the early days of PEO. The introduction of ionic polymers has led to advances in ionic conductivity while the use of block copolymers has also increased the mechanical properties and provided more flexibility in solid polymer electrolyte development. The combination of these two, ionic block copolymer materials, are still in their early stages but offer exciting possibilities for the future of this field.
Synthesis, Characterization and Sorption Ability of Epoxy Resin-Based Sorbents with Amine Groups
Authors: Podkościelna Beata , Wawrzkiewicz Monika , Klapiszewski Łukasz
Published: December 2021

Water pollution by toxic substances, such as azo dyes, is a serious environmental problem that needs to be addressed. This study presents the synthesis and characterization of new polymeric sorbents, based on the epoxy resin Epidian® 5 (Ep5), as a potential adsorbent for the removal of the toxic azo dye C.I. Acid Violet 1 (AV1). Triethylenetetramine (TETA) was applied as a cross-linking agent in the amounts of 1 g (6.67 wt %), 1.5 g (10 wt %), and 2 g (13.33 wt %). The use of a compound with amino groups allows for the simultaneous functionalization of the obtained material. The reaction was carried out in an environment of ethylene glycol, with the addition of a porophore solvent (toluene) and bis(2-ethylhexyl)sulfosuccinate sodium salt (S). The attenuated total reflectance–Fourier transform infrared spectroscopy (ATR-FTIR) revealed the existence of a strong band in the 828–826 cm−1 range corresponding to the second-order amine group, which indicates their incorporation into the epoxy structure. The glass transition and decomposition temperatures of the resins decreased with the increasing amounts of amine in the material. The thermogravimetry (TGA) analysis demonstrated that all products are thermally stable up to 340 °C. The surface morphology and microstructural properties of the obtained sorbents were determined using scanning electron microscopy (SEM) images and showed an irregular star shape, with dimensions ranging from 400 to 1000 µm. The adsorption capacities of Ep5-TETA1, Ep5-TETA1.5, Ep5-TETA2 and Ep5-TETA1.5 + S for AV1 evaluated during batch experiments were found to be 2.92, 3.76, 7.90 and 3.30 mg/g, respectively.
The Impact of Fiber from Buckwheat Hulls Waste on the Pasting, Rheological and Textural Properties of Normal and Waxy Potato Starch Gels
Authors: Adamczyk Greta , Krystyjan Magdalena , Witczak Mariusz
Published: December 2021

The aim of this study was to investigate the impact of fiber from buckwheat hull waste (BH) on the pasting, rheological, and textural properties of 4% and 5% (w/w) pastes and gels based on the potato starches with different amylose/amylopectin contents. The starch and starch/fiber mixtures were characterized by pasting and flow measurements as well as by viscoelastic and textural analysis. The pasting properties showed a greater BH effect (0.2%) on the gelatinization of PS than WPS. The starch gels and starch fiber mixtures showed biopolymer gel behavior. In the WPS/BH pastes, a smaller increase in hardness was noted compared to PS/BH.
Modeling of the Influence of Input AM Parameters on Dimensional Error and Form Errors in PLA Parts Printed with FFF Technology
Authors: Luis-Pérez Carmelo J. , Buj-Corral Irene , Sánchez-Casas Xavier
Published: December 2021

As is widely known, additive manufacturing (AM) allows very complex parts to be manufactured with porous structures at a relatively low cost and in relatively low manufacturing times. However, it is necessary to determine in a precise way the input values that allow better results to be obtained in terms of microgeometry, form errors, and dimensional error. In an earlier work, the influence of the process parameters on surface roughness obtained in fused filament fabrication (FFF) processes was analyzed. This present study focuses on form errors as well as on dimensional error of hemispherical cups, with a similar shape to that of the acetabular cup of hip prostheses. The specimens were 3D printed in polylactic acid (PLA). Process variables are nozzle diameter, temperature, layer height, print speed, and extrusion multiplier. Their influence on roundness, concentricity, and dimensional error is considered. To do this, adaptive neuro-fuzzy inference systems (ANFIS) models were used. It was observed that dimensional error, roundness, and concentricity depend mainly on the nozzle diameter and on layer height. Moreover, high nozzle diameter of 0.6 mm and high layer height of 0.3 mm are not recommended. A desirability function was employed along with the ANFIS models in order to determine the optimal manufacturing conditions. The main aim of the multi-objective optimization study was to minimize average surface roughness (Ra) and roundness, while dimensional error was kept within the interval Dimensional Error≤0.01. When the simultaneous optimization of both the internal and the external surface of the parts is performed, it is recommended that a nozzle diameter of 0.4 mm be used, to have a temperature of 197 °C, a layer height of 0.1 mm, a print speed of 42 mm/s, and extrusion multiplier of 94.8%. This study will help to determine the influence of the process parameters on the quality of the manufactured parts.
Study of Allowable Interlaminar Normal Stress Based on the Time–Temperature Equivalence Principle in Automated Fiber Placement Process
Authors: Xiao Rui , Shi Jiaqi , Xiao Jun
Published: December 2021

Automatic fiber placement (AFP) is a type of labor-saving automatic technology for forming composite materials that are widely used in aviation and other fields. In this process, concave surface delamination is a common defect, as existing research on the conditions for this defect to occur is insufficient. To predict the occurrence of this defect, the concept of allowable interlaminar normal stress is proposed to define its occurrence conditions, and based on this concept, probe tests are carried out using the principle of time–temperature equivalence. Through the laying speed/allowable normal stress curve measured in the probe experiment, the physical meaning of allowable normal stress is discussed. At the same time, the measured curve is quantitatively analyzed, combined with viscoelastic theory and the molecular diffusion reptation model, and the dominating effect in the formation of a metal/prepreg layer and prepreg/prepreg layer is determined. Finally, the experimental data are used to guide the parameter selection in an automatic placement engineering case and prove its correctness.
Effect of a Symbiotic Mixture on Fecal Microbiota in Pediatric Patients Suffering of Functional Abdominal Pain Disorders
Authors: Becheanu Cristina Adriana , Smădeanu Roxana Elena , Ţincu Iulia Florentina
Published: December 2021

(1) Background: Functional abdominal pain disorders (FAPDs) represent one of the main etiologies of chronic abdominal pain in the pediatric population. A wide spectrum of probiotic or prebiotic mixtures has been evaluated in trials regarding benefits in patients with FAPDs, mainly in the adult population. (2) Methods: This study was interested in evaluating the effect of oral supplementation with a symbiotic mixture on intestinal microbiota in children with functional dyspepsia (FD), irritable bowel syndrome with diarrhea (IBS-D), and irritable bowel syndrome with constipation (IBS-C). A combination of six bacterial strains (Lactobacillus rhamnosus R0011, Lactibacillus casei R0215, Bifidobacterium lactis BI-04, Lactobacillus acidophilus La-14, Bifidobacterium longum BB536, Lactobacillus plantarum R1012) and 210 mg of fructo-oligosaccharides-inulin were administered orally, daily, for 12 weeks and patients were scored for severity of symptoms and fecal microbiota before and after the treatment. (3) Results: The proportion of patients with adequate symptom relief was higher in the IBS-D than in the IBS-C group; however, the difference was not statistically significant (74.4% vs. 61.9%, p = 0.230). There was an increasing proportion of bacterial genera associated with health benefits, for both IBS-C and IBS-D (IBS-C: 31.1 ± 16.7% vs. 47.7 ± 13.5%, p = 0.01; IBS-D: 35.8 ± 16.2% vs. 44.1 ± 15.1%, p = 0.01). (4) Conclusions: Administration of a symbiotic preparation resulted in significant changes to the microbiota and gastrointestinal symptoms in patients with FAPDs.
Endodontic Irrigants and Their Activation Efficacy on Cleansing Post-Space Root Canal Walls
Authors: Marchese Manuela , Denise Pontoriero I. K. , Ferrari Cagidiaco Edoardo , Iandolo Alfredo , Grandini Simone , Ferrari Marco
Published: December 2021

The aim of this study was to evaluate the efficacy of activated irrigants (EDTA e NaOCL) during the cleansing of root walls, of the smear layer, of the debris, and gutta-percha after the preparation of the restorative space. Twenty single and multi-rooted (n = 20) have been collected. All samples were prepared by the same operator, using Nickel-titanium rotating instruments (Mtwo) through the Simultaneous Shaping Technique. The continuous-wave of condensation technique of obturation was used. To all specimens, the restorative space has been made, leaving 5 mm of apical gutta-percha, and postoperative periapical X-rays were performed. The samples were randomly divided into two groups: Group (A): cleansing of the root walls with ultrasonic activation of the irrigants (NEWTRON P5 XS; Satelec Acteon); Group (B): radicular walls wash without ultrasonic activation of endodontic irrigants (NaOCl 5.25% and EDTA 17%). Both dental sample groups were cut longitudinally with a low-speed saw (Isomet); the samples were observed by using a scanning electron microscope (Jeol, Jsm-6060LV) in order to evaluate: (1) the amount of debris/smear layer; (2) the mount of obstruction of dentinal tubules found in the two groups; and (3) evaluation of the presence of gutta-percha. Then, the other five samples each group (with and without ultrasonic activation) were prepared following the same protocol. Then, a universal bonding system (G-Praemio Bond, GC) and a layer of a flowable resin composite (Gaenial Flow, GC) were light-cured and used on top of the prepared root canal walls. The samples were cut in two pieces along the long axis of the root. Then, half sample teeth were kept in an acidic solution (37% HCl) for 48 h in order to completely dissolve dental structures and to have a direct view of resin tags formation under SEM. The other half was prepared to observe the adhesive interface under SEM. The amount of debris was not satisfactory in 9 out of 10 cases in Group B, while in Group A, which has been treated with ultrasounds, the result was either good or great in most of the samples. For the sample group treated with ultrasound, the tubules were evaluated as perfectly clean in 9 out of 10 cases, instead, the results are unsatisfactory for 9 out of 10 cases of group B not treated with ultrasound. Differences between Group A and B were statistically significant. With respect to the presence of debris and tubules obstruction treatment with ultrasonic activation, it offers with no doubt better results. When ultrasonic activation is used in combination with endodontic irrigants, a clean dentin substrate is be obtained for the adhesion of restorative materials, but in order to confirm the findings of this study, further in vivo trials are needed.
Anonymiced Shareable Data: Using mice to Create and Analyze Multiply Imputed Synthetic Datasets
Authors: Volker Thom Benjamin , Vink Gerko
Published: December 2021

Synthetic datasets simultaneously allow for the dissemination of research data while protecting the privacy and confidentiality of respondents. Generating and analyzing synthetic datasets is straightforward, yet, a synthetic data analysis pipeline is seldom adopted by applied researchers. We outline a simple procedure for generating and analyzing synthetic datasets with the multiple imputation software mice (Version 3.13.15) in R. We demonstrate through simulations that the analysis results obtained on synthetic data yield unbiased and valid inferences and lead to synthetic records that cannot be distinguished from the true data records. The ease of use when synthesizing data with mice along with the validity of inferences obtained through this procedure opens up a wealth of possibilities for data dissemination and further research on initially private data.
The Application of the SKT Short Cognitive Performance Test to English-Speaking Populations
Authors: Stemmler Mark , Schneider Sophia , Poon Leonard
Published: December 2021

The SKT (Syndrom-Kurz-Test) is a well-established short cognitive performance test for the detection of attention and memory deficits in Germany. The goal of this paper is to test whether the SKT could be applied to English-speaking populations to screen cognitive impairments in the US, Australia, and Ireland. A regression-based continuous norming technique was applied. Standardized test results obtained from German-speaking (n = 1056) and English-speaking (n = 285) samples were compared. Both samples consisted of cognitively unimpaired, community-dwelling, and independently living volunteers (non-patients) over 60 years of age. Means, medians, and standard deviations of raw scores were calculated. A high similarity in the raw value distributions of the criterion variables and a comparison of German and English multiple regression residuals indicated the equivalence among the samples. In addition, the obtained multiple regression equations for predicting the subtest scores including the explained variances (R2) were highly comparable. Age and intelligence turned out to be the most important and necessary predictors for each subtest performance. The results suggest that the new regression-based norming of the SKT can be validly used in the three English-speaking countries.
Comparing the MCMC Efficiency of JAGS and Stan for the Multi-Level Intercept-Only Model in the Covariance- and Mean-Based and Classic Parametrization
Authors: Hecht Martin , Weirich Sebastian , Zitzmann Steffen
Published: December 2021

Bayesian MCMC is a widely used model estimation technique, and software from the BUGS family, such as JAGS, have been popular for over two decades. Recently, Stan entered the market with promises of higher efficiency fueled by advanced and more sophisticated algorithms. With this study, we want to contribute empirical results to the discussion about the sampling efficiency of JAGS and Stan. We conducted three simulation studies in which we varied the number of warmup iterations, the prior informativeness, and sample sizes and employed the multi-level intercept-only model in the covariance- and mean-based and in the classic parametrization. The target outcome was MCMC efficiency measured as effective sample size per second (ESS/s). Based on our specific (and limited) study setup, we found that (1) MCMC efficiency is much higher for the covariance- and mean-based parametrization than for the classic parametrization, (2) Stan clearly outperforms JAGS when the covariance- and mean-based parametrization is used, and that (3) JAGS clearly outperforms Stan when the classic parametrization is used.
New Discoveries and Theoretical Implications for the Last Foraging and First Farming in East Asia
Authors: Kelly Robert L.
Published: December 2021

A brief summation of the issue’s articles is presented. This leads to a discussion of thematic issues of concepts, methods, and theory that crosscut the articles. These include use of the EnvCalc2.1 program, some issues of terminology, the theoretical approaches of niche construction as opposed to human behavioral ecology (HBE), and the linkage between technology and subsistence change, notably the difference between biface and microblade production.
Who Killed the Small Mammals of Ittenheim (Northeastern France)? An Integrative Approach and New Taphonomic Data for Investigating Bone Assemblages Accumulated by Small Carnivores
Authors: Royer Aurélien , Mallye Jean-Baptiste , Pelletier Maxime , Griselin Sylvain
Published: December 2021

Small carnivores are susceptible to regularly accumulating small- to medium-sized mammal remains in both natural and archaeological sites. However, compared to nocturnal birds of prey, these accumulations are still poorly documented and are generally based on a limited number of samples, including those of relatively small size. Here, we present an analysis of European hamster remains from a rescue excavation at Ittenheim (Bas-Rhin, Grand-Est, France), which were recovered from an infilled burrow, three meters below the current surface. The remains are well preserved and exhibit large proportions of tooth marks. Comparisons with a new and existing reference collection combined with an analysis of all recovered faunal remains suggest the accumulation reflects the action of young red foxes. This is supported by the fact that, although these young individuals leave teeth mark, they do not necessarily consume all parts of medium-sized prey species, including the European hamster. Conversely, the remains of smaller rodents, such as microtine, show distinct patterns of digestion and tooth marks. Carnivore bone accumulations from scats are generally poorly preserved; however, our results demonstrate prey size plays a major role, both qualitatively and quantitatively, in skeletal representation, bone preservation, and bone surface modifications. The present paper underlines the need for more diversified taphonomic reference collections based on an integrative approach designed to evaluate multi-taxa accumulations.
Direct Dating of Chinese Immovable Cultural Heritage
Authors: Bednarik Robert G.
Published: December 2021

The most extensive corpus of ancient immovable cultural heritage is that of global rock art. Estimating its age has traditionally been challenging, rendering it difficult to integrate archaeological evidence of early cultural traditions. The dating of Chinese rock art by ‘direct methods’ began in the late 1990s in Qinghai Province. Since then, China has acquired the largest body of direct dating information about the rock art of any country. The establishment of the International Centre for Rock Art Dating at Hebei Normal University has been the driving force in this development, with its researchers accounting for most of the results. This centre has set the highest standards in rock art age estimation. Its principal method, microerosion analysis, secured the largest number of determinations, but it has also applied other methods. Its work with uranium-thorium analysis of carbonate precipitates in caves is of particular significance because it tested this widely used method. The implications of this work are wide-ranging. Most direct-dating of rock art has now become available from Henan, but results have also been reported from Heilongjiang, Inner Mongolia, Ningxia, Jiangsu, Hubei, Guangxi, Yunnan, Qinghai, Tibet, and Xinjiang. Intensive work by several teams is continuing and is expected to result in a significantly better understanding of China’s early immovable cultural heritage.
Rituals and Embodied Cultural Practices at the Beginning of Life: African Perspectives
Authors: Ohaja Magdalena , Anyim Chinemerem
Published: December 2021

Cultural beliefs and practices find expression through rituals. Rites of initiation or passage are some of the most common rituals among the indigenous African societies. Pregnancy and Childbirth are not only biological events, but also socially and culturally constructed with associated symbols that represent the social identities and cultural values of Africans. Birth is a rite of passage, and children are perceived as special gifts from the Supreme Being. As such, pregnancy and childbirth are special events cherished and celebrated through varied rituals. Drawing on empirical literature and relevant commentaries, this paper aims to discuss selected rituals and embodied practices surrounding the start of life (pregnancy, birth, and early motherhood). The paper will specifically focus on the following aspects: pregnancy rituals; birth songs and dancing; the omugwo (care after birth); the cord and placenta rituals; and the naming ceremony. Some of the pregnancy rituals are purificatory in nature and therefore beneficial for maternal and infant health. The celebrations surrounding the birth of a child are community events, marked with singing and dancing. Following childbirth, the new mothers are not expected to participate in house chores to allow them time to recuperate. In all, discourses concerning the beginning of life, i.e., pregnancy and the periods surrounding it, are filled with rituals which are embodiments or expressions of cultural values, customs, and beliefs.
The Effects of Over-Ground Robot-Assisted Gait Training for Children with Ataxic Cerebral Palsy: A Case Report
Authors: Yoo Myungeun , Ahn Jeong Hyeon , Park Eun Sook
Published: December 2021

Poor balance and ataxic gait are major impediments to independent living in ataxic cerebral palsy (CP). Robot assisted-gait training (RAGT) has been shown to improve the postural balance and gait function in children with CP. However, there is no report on the application of RAGT for children with ataxic CP. Here, we report two cases of children with ataxic CP who underwent over-ground RAGT along with conventional therapy for 4 weeks. Outcome measures including the gross motor function measure (GMFM), pediatric balance scale, pediatric reach scale, one-minute walk test, and Timed Up and Go test were assessed before and after the 4-week intervention. Both cases were well adapted to the RAGT system without any significant adverse event. Improvements in the GMFM after RAGT, compared with that in the GMFM, after intensive conventional therapy have been reported previously. It is noteworthy that over-ground RAGT improved areas of the GMFM that did not improve with conventional therapy. In addition, over-ground RAGT with conventional therapy led to improvements in functional balance and walking capacity. These findings suggest that over-ground RAGT is feasible and may be a potential option for enhancing balance and functional walking capacity in children with ataxic CP.
Characterization of the Safety Profile of Sweet Chestnut Wood Distillate Employed in Agriculture
Authors: Filippelli Arianna , Ciccone Valerio , Loppi Stefano , Morbidelli Lucia
Published: December 2021

In organic agriculture, synthetic pesticides and treatments are substituted by natural remedies with interesting success for product yield and environmental outcomes, but the safety of these bio-based products needs to be assessed in vertebrate and human models. Therefore, in this paper we assessed the safety profile of sweet chestnut (Castanea sativa) wood distillate (WD) on the different cellular components of tissues implied in transcutaneous absorption. We investigated the viability of different cell lines mimicking the skin (HaCaT keratinocytes), mucosa (A431), connective (normal human dermal fibroblasts, NHDF) and vascular (human umbilical vein endothelial cells, HUVEC) tissues after exposure to increasing concentrations (0.04–0.5%, v/v, corresponding to 1:2800–1:200 dilutions) of WD. A short exposure to increasing doses of WD was well tolerated up to the highest concentration. Instead, following a prolonged treatment, a concentration dependent cytotoxic effect was observed. Notably, a different behavior was found with the various cell lines, with higher sensitivity to cytotoxicity by the cells with higher proliferation rate and reduced doubling time (human keratinocytes). Moreover, to exclude an inflammatory effect at the not cytotoxic WD concentrations, the expression of the main inducible markers of inflammation, cyclooxygenase-2 (COX-2) and microsomal prostaglandin E synthase-1 (mPGES-1), were assessed, and no improvement was found both after brief and prolonged exposure. In conclusion, our data exclude any inflammatory and cytotoxic effect at the lowest WD concentrations, namely 0.07% and 0.04%, mimicking some recommended dilutions of the product and the potential exposure doses for the operators in agriculture. Nevertheless, higher concentrations showed a safe profile for short time usage, but caution should be used by farmers following persistent product exposure.
HPLC-DAD Analysis of Hemp Oil Supplements for Determination of Four Cannabinoids: Cannabidiol, Cannabidiolic Acid, Cannabinol and Delta 9-Tetrahydrocannabinol
Authors: Madej Katarzyna , Chmiołek Aleksandra , Szlachta Kamila , Piekoszewski Wojciech
Published: December 2021

Growing consumer interest in hemp oilseed supplements requires quality control. Therefore, appropriate, effective and verified analytical methods are needed for the determination of some bioactive cannabinoids in them. The aim of the study is to present an extended (compared to our previous research) validated high performance liquid chromatography with diode array detection (HPLC-DAD) method for the determination of four cannabinoids (cannabidiol, cannabidiolic acid, cannabinol and delta-9-tetrahydrocannabinol) in an oil matrix, which was used to determine these cannabinoids in seven commercial hemp oil supplements. In our method, the isolation of the target compounds was based on liquid extraction with acetonitrile combined with the freezing (at −41 °C) of the oil phase. The results show that in some cases, the determined concentrations of cannabinoids in the tested supplements differ significantly from those declared by the manufacturers. As for the main medicinal cannabinoid (CBD) in hemp oil supplements, in two cases, the measured concentration was significantly lower (1.45 and 1.81%) than the declared (5 and 5%), and in the other supplements, the obtained results confirm the declared amount of CBD within the error range from 3.29 to 9.2%. Therefore, to ensure the safe and beneficial use of these supplements by consumers, it is necessary to monitor their cannabinoid composition.
Evaluation of New, Sputtered Carbon SPME Fibers with a Multi-Functional Group Test Mixture
Authors: Patel Dhananjay I. , Roychowdhury Tuhin , Jacobsen Collin , Myers Colton , Herrington Jason S. , Linford Matthew R.
Published: December 2021

We report the first fabrication of sputtered carbon, solid-phase microextraction (SPME) fibers. These fibers have competitive extraction capabilities compared with the commercial carbon wide range (CWR) SPME fiber. This report also includes a demonstration of a newly developed SPME test mix that includes 15 different compounds with a wide range of functional groups and chemical properties. The fiber fabrication process involves sputtering carbon onto fused silica fibers, and the effects of throw distance on the morphology of the carbon coatings were studied. Four different carbon coating thicknesses were evaluated, with PDMS added as a stationary phase. These fibers were characterized with multiple analytical techniques, including scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), water contact angle (WCA) goniometry, as well as headspace (HS) and direct immersion (DI)–SPME–GC–MS. The best (11.5 µm) sputtered carbon SPME fibers, with and without PDMS, were evaluated using the new evaluation mix and compared with the commercial CWR fiber and a previously sputtered/developed silicon fiber. The new probe mix helped elucidate differences among the fibers, which would have been missed by current commercial test mixes. The sputtered carbon SPME fibers showed similar functional group selectivity as commercial CWR fibers. However, the sputtered carbon fibers showed higher responses per volume compared with the commercial CWR fiber, indicating the porous morphology of the sputtered carbon has the ability to overcome large phase thickness/volume discrepancies and increase the relative recovery for various compounds.
NMR Tracing of Food Geographical Origin: The Impact of Seasonality, Cultivar and Production Year on Data Analysis
Authors: Masetti Olimpia , Sorbo Angela , Nisini Luigi
Published: December 2021

The traceability of typical foodstuffs is necessary to protect high quality of traditional products. It is well-known that several factors could influence metabolites content in certified foods, but soil composition, altitude, latitude and coded production protocols constitute the territorial conditions responsible for the peculiar organoleptic and nutritional properties of labelled foods. Instead, regardless of origin, seasonality, cultivar, collection year can affect all agricultural products, so it is appropriate to include them in data analysis in order to obtain a correct interpretation of the differences linked to growing areas alone. Therefore, it is useful to use a flexible all-round technique, and NMR spectroscopy coupled with multivariate statistical analysis is considered a powerful means of assessing food authenticity. The purpose of this review is to investigate the relevance of year, cultivar, and seasonal period in the determination of food geographical origin using NMR spectroscopy. The strategy for testing these three factors may differ from author to author, but a preliminary study of cultivar or collection year effects on NMR spectra is the most popular method before starting the geographical characterization of samples. In summary, based on the available literature, the most significant influence is due to cultivar, followed by harvesting year, however seasonality is not considered a source of variability in data analysis.
Resilience in Water Infrastructures: A Review of Challenges and Adoption Strategies
Authors: Pamidimukkala Apurva , Kermanshachi Sharareh , Adepu Nikhitha , Safapour Elnaz
Published: December 2021

An increase in the number and strength of natural catastrophes experienced over the past few decades has accelerated the damage sustained by infrastructures. Drinking water and wastewater infrastructure systems are critical aspects of a healthy environment, and their ability to withstand disasters is vital for effective disaster response and recovery. Although numerous studies have been conducted to determine the challenges that natural disasters render to water infrastructures, few extensive examinations of these challenges have been conducted. The goal of this study, therefore, was to identify and categorize the challenges related to the resilience of drinking water and wastewater infrastructures, and to determine the strategies that most effectively minimize their unintended consequences. A comprehensive evaluation of the existing literature was conducted, and 537 publications were collected. After extensive screening, 222 publications were selected for rigorous evaluation and analysis based on the data collection methods and other criteria. A total of fifty-one (51) challenges were determined and classified, within the following five categories: environmental, technical and infrastructure, social, organizational, and financial and economic. The challenges were then ranked within each category according to their frequency of occurrence in previous research. The results reveal that climate change, aging infrastructure, lack of infrastructure capital, population growth, improper maintenance of water infrastructure, and rapid urbanization are the most frequently cited challenges. Next, 30 strategies and approaches were identified and categorized into either preventive or corrective actions, according to their implementation time. The findings of this study will help decision- and policymakers properly allocate their limited funding to enhance the robustness of their water infrastructures before, during, and after natural hazards.
Barriers to Implementing the Circular Economy in the Construction Industry: A Critical Review
Authors: Charef Rabia , Morel Jean-Claude , Rakhshan Kambiz
Published: December 2021

To facilitate the adoption of the circular economy (CE) in the architecture, engineering and construction (AEC) sector, some authors have demonstrated the potential of recent designs that take into account the sustainable management of an asset’s end-of-life (EOL), providing an alternative to the dominant designs that end with demolition. However, there is no review of the literature that encompasses a large range of sustainable designs in the current CE context. This paper provides a critical review of journal papers that deal with the barriers to implementing sustainable designs and approaches to the EOL management of assets that have the potential to fulfil the principles of the CE. Eighteen approaches related to prefabrication, design for change, design for deconstruction, reverse logistics, waste management and closed-loop systems were found. Through an analysis of the barriers that are common among these 18 approaches, we classified them into six different categories (organisational, economical, technical, social, political and environmental). Two Sankey diagrams illustrate the interrelation between the barriers, their categories and the 18 approaches. The diagrams clearly show that most of the barriers are common to multiple approaches and that most of the barriers relate to organisational concerns. The study gives a detailed map of the barriers that would help stakeholders from the AEC sector develop strategies to overcome the current obstacles in the shift to a CE.