bluuebunny/crossref_metadata_2025 huggingface dataset:
Free Agency and Determinism: Is There a Sensible Definition of Computational Sourcehood?
Authors: Krumm Marius , Müller Markus P.
Published: June 2023

Can free agency be compatible with determinism? Compatibilists argue that the answer is yes, and it has been suggested that the computer science principle of “computational irreducibility” sheds light on this compatibility. It implies that there cannot, in general, be shortcuts to predict the behavior of agents, explaining why deterministic agents often appear to act freely. In this paper, we introduce a variant of computational irreducibility that intends to capture more accurately aspects of actual (as opposed to apparent) free agency, including computational sourcehood, i.e., the phenomenon that the successful prediction of a process’ behavior must typically involve an almost-exact representation of the relevant features of that process, regardless of the time it takes to arrive at the prediction. We argue that this can be understood as saying that the process itself is the source of its actions, and we conjecture that many computational processes have this property. The main contribution of this paper is technical, in that we analyze whether and how a sensible formal definition of computational sourcehood is possible. While we do not answer the question completely, we show how it is related to finding a particular simulation preorder on Turing machines, we uncover concrete stumbling blocks towards constructing such a definition, and demonstrate that structure-preserving (as opposed to merely simple or efficient) functions between levels of simulation play a crucial role.
A Multicriteria-Based Comparison of Electric Vehicles Using q-Rung Orthopair Fuzzy Numbers
Authors: Biswas Sanjib , Sanyal Aparajita , Božanić Darko , Kar Samarjit , Milić Aleksandar , Puška Adis
Published: June 2023

The subject of this research is the evaluation of electric cars and the choice of car that best meets the set research criteria. To this end, the criteria weights were determined using the entropy method with two-step normalization and a full consistency check. In addition, the entropy method was extended further with q-rung orthopair fuzzy (qROF) information and Einstein aggregation for carrying out decision making under uncertainty with imprecise information. Sustainable transportation was selected as the area of application. The current work compared a set of 20 leading EVs in India using the proposed decision-making model. The comparison was designed to cover two aspects: technical attributes and user opinions. For the ranking of the EVs, a recently developed multicriteria decision-making (MCDM) model, the alternative ranking order method with two-step normalization (AROMAN), was used. The present work is a novel hybridization of the entropy method, full consistency method (FUCOM), and AROMAN in an uncertain environment. The results show that the electricity consumption criterion (w = 0.0944) received the greatest weight, while the best ranked alternative was A7. The results also show robustness and stability, as revealed through a comparison with the other MCDM models and a sensitivity analysis. The present work is different from the past studies, as it provides a robust hybrid decision-making model that uses both objective and subjective information.
Selected Materials and Technologies for Electrical Energy Sector
Authors: Stryczewska Henryka Danuta , Boiko Oleksandr , Stępień Mariusz Adam , Lasek Paweł , Yamazato Masaaki , Higa Akira
Published: June 2023

Ensuring the energy transition in order to decrease CO2 and volatile organic compounds emissions and improve the efficiency of energy processes requires the development of advanced materials and technologies for the electrical energy sector. The article reviews superconducting materials, functional nanomaterials used in the power industry mainly due to their magnetic, electrical, optical, and dielectric properties and the thin layers of amorphous carbon nitride, which properties make them an important material from the point of view of environmental protection, optoelectronic, photovoltaic and energy storage. The superconductivity-based technologies, material processing, and thermal and nonthermal plasma generation have been reviewed as technologies that can be a solution to chosen problems in the electrical energy sector and environment. The study explains directly both—the basics and application potential of low and high-temperature superconductors as well as peculiarities of the related manufacturing technologies for Roebel cables, 1G and 2G HTS tapes, and superconductor coil systems. Among the superconducting materials, particular attention was paid to the magnesium di-boride MgB2 and its potential applications in the power industry. The benefits of the use of carbon films with amorphous structures in electronics, sensing technologies, solar cells, FETs, and memory devices were discussed. The article provides the information about most interesting, from the R&D point of view, groups of materials for PV applications. It summarises the advantages and disadvantages of their use regarding commercial requirements such as efficiency, lifetime, light absorption, impact on the environment, costs of production, and weather dependency. Silicon processing, inkjet printing, vacuum deposition, and evaporation technologies that allow obtaining improved and strengthened materials for solar cell manufacturing are also described. In the case of the widely developed plasma generation field, waste-to-hydrogen technology including both thermal and non-thermal plasma techniques has been discussed. The review aims to draw attention to the problems faced by the modern power industry and to encourage research in this area because many of these problems can only be solved within the framework of interdisciplinary and international cooperation.
Tubular C3N4 Nanotubes as Metal-Free Sulfur Hosts toward Stable Lithium–Sulfur Batteries
Authors: Zhang Chaoqi , Du Ruifeng , Martí-Sánchez Sara , Xiao Ke , Yang Dawei , Zhang Chaoyue , Li Canhuang , Zeng Guifang , Chang Xingqi , He Ren , Arbiol Jordi , Li Junshan , Jacas Biendicho Jordi , Cabot Andreu
Published: June 2023

Lithium–sulfur batteries (LSBs) with high energy density have the potential to replace current commercial lithium-ion batteries. However, the shuttle effect and the low conversion kinetics of lithium polysulfide (LiPS) remain the main challenges in the development of LSBs. In this study, a metal-free and simple-to-prepare carbon nitride with a high surface area and tubular morphology (CN-nt) is used as the sulfur host for LSBs. Due to its unique nanostructure and rich active sites, it not only effectively disperses the active sulfur material and anchors soluble polysulfide species, but it also promotes the nucleation process of Li2S, thus achieving fast and sustainable Li-S redox reactions. Experimental results show that the obtained S@CN-nt electrodes exhibit a high sulfur utilization of 1296.2 mAh g−1 at 0.1 C and a significant rate capability of 689.4 mAh g−1 at the high current rate of 3C. More importantly, the capacity retention reaches 87.7% after 500 cycles. This simple strategy of engineering unique carbon-based nanostructured hosts can inspire new ideas for developing cost-effective and metal-free host materials for sulfur-based batteries.
Effect of GaN-Based Distributed Bragg Reflector on Optical Properties of CH3NH3PbBr3 Crystals
Authors: Jiang Feng , Duan Yiwei , Song Jiawen , Luo Zhe
Published: June 2023

As a photoelectric material, the luminescent efficiency improvement of organic–inorganic perovskite material is a hot topic. This work fabricated a nanoporous distributed Bragg reflector based on GaN with a periodic structure using electrochemical etching methods. Considering the fact that hybrid perovskite materials are difficult to prepare on an inorganic GaN-based substrate, ultraviolet ozone treatment was implemented to enhance the surface activity of the prepared distributed Bragg reflector substrate. Cubic CH3NH3PbBr3 crystals with smooth surfaces and precise edges were successfully prepared on the ozone-treated distributed Bragg reflector substrate by a two-step immersion method in the air environment. The structural property of the prepared CH3NH3PbBr3 crystals was investigated using X-ray diffraction, scanning electron microscopy and Fourier-transform infrared spectroscopy. The structural analysis results showed that CH3NH3PbBr3 crystals grown on the prepared distributed Bragg reflector and reference substrates have the same structure, with a good crystal quality. The photoluminescence intensity of CH3NH3PbBr3 crystals grown on the distributed Bragg reflector was significantly enhanced. The enhancement is approximately 3.11-fold compared with CH3NH3PbBr3 crystals grown on the unetched reference GaN substrate. Moreover, there is a 7.2 nm spectral blue shift. The enhancement of the photoluminescence intensity could be attributed to the out-coupling of emission light in the prepared crystals, and the blue shift could be attributed to the stress relaxation caused by the nanoporous GaN structure of the distributed Bragg reflector substrate.
Effects of Coupling Combined Heat and Power Production with District Cooling
Authors: Lepiksaar Kertu , Mašatin Vladislav , Krupenski Igor , Volkova Anna
Published: June 2023

Over the past decades, combined heat and power production (CHP) has proven itself to be an efficient means of meeting both heat and power demands. However, high efficiency can be achieved with CHP plants when the heat load is sufficient, while lower-priority CHP plants must deal with the excess heat associated with power generation. This excess heat can be used for district cooling with absorption chillers. Although the absorption chiller is an efficient technology for using excess heat for cooling generation, its efficiency is very sensitive to driving hot water temperature. This paper provides a detailed analysis of how cooling generation in CHP plants using absorption chillers affects power generation and primary energy consumption. This study is based on the operational parameters of the Mustamäe CHP plant (Tallinn, Estonia) and the cooling demand of the Tehnopol science and business campus and proposes a sufficient cooling production capacity based on the estimation of the campus’ cooling demand. Additional cooling production opportunities to meet district cooling demand are discussed and compared in this paper in terms of primary energy savings and economic profit. The study finds that for the effective use of CHP excess heat and efficient cooling production, the use of an 0.8 MW absorption cooler and 11.6 MW heat pumps is recommended. This system would use 1.9 times less primary energy for cooling generation than local cooling.
Social and Emotional Wellbeing of Aboriginal Community Controlled Health Services Staff during the COVID-19 Pandemic
Authors: Nepal Smriti , Bailey Sandra , Newman Jamie , Wright Lachlan , Smith Natalie , Dickson Michelle , Williamson Anna
Published: June 2023

This study explores the impact of the COVID-19 pandemic on the work and social and emotional well-being (SEWB) of staff at Aboriginal Community Controlled Health Services (ACCHS) in Australia. Between September and November 2021, staff from three ACCHSs in New South Wales completed an online survey to report changes to their roles, concerns about becoming infected with the COVID-19 virus, and job satisfaction in the last month. The survey measured emotional exhaustion and psychological distress by using the Maslach Burnout Inventory-Human Services Survey and Kessler-5 scale, respectively. The survey determined staff’s access to SEWB support. Descriptive statistics were calculated for each variable. Among 92 staff from three ACCHSs, 36% reported a COVID-19-related change in their role and 64% were concerned about becoming infected. In spite of the pandemic, most staff (69%) were satisfied with their job. While most staff were not burnt out or psychologically distressed, 25% had high emotional exhaustion and 30% had high to very high psychological distress. Relatedly, 37% had accessed SEWB support at least once in their lifetime and 24% had accessed support in the last month. As the pandemic continues, it is important to identify factors influencing burnout or psychological distress among ACCHS staff and implement evidence-based solutions.
Consequences of Exposure to War Violence: Discriminating Those with Heightened Risk for Aggression from Those with Heightened Risk for Post-Traumatic Stress Symptoms
Authors: Huesmann L. Rowell , Dubow Eric F. , Boxer Paul , Smith Cathy , Shikaki Khalil , Landau Simha F. , Gvirsman Shira Dvir
Published: June 2023

Chronic exposure to ethnic–political and war violence has deleterious effects throughout childhood. Some youths exposed to war violence are more likely to act aggressively afterwards, and some are more likely to experience post-traumatic stress symptoms (PTS symptoms). However, the concordance of these two outcomes is not strong, and it is unclear what discriminates between those who are at more risk for one or the other. Drawing on prior research on desensitization and arousal and on recent social–cognitive theorizing about how high anxious arousal to violence can inhibit aggression, we hypothesized that those who characteristically experience higher anxious arousal when exposed to violence should display a lower increase in aggression after exposure to war violence but the same or a higher increase in PTS symptoms compared to those low in anxious arousal. To test this hypothesis, we analyzed data from our 4-wave longitudinal interview study of 1051 Israeli and Palestinian youths (ages at Wave 1 ranged from 8 to 14, and at Wave 4 from 15–22). We used the 4 waves of data on aggression, PTS symptoms, and exposure to war violence, along with additional data collected during Wave 4 on the anxious arousal participants experienced while watching a very violent film unrelated to war violence (N = 337). Longitudinal analyses revealed that exposure to war violence significantly increased both the risk of subsequent aggression and PTS symptoms. However, anxious arousal in response to seeing the unrelated violent film (measured from skin conductance and self-reports of anxiety) moderated the relation between exposure to war violence and subsequent psychological and behavioral outcomes. Those who experienced greater anxious arousal while watching the violent film showed a weaker positive relation between amount of exposure to war violence and aggression toward their peers but a stronger positive relation between amount of exposure to war violence and PTS symptoms.
A Systematic Review of the Factors That Influence Teachers’ Occupational Wellbeing
Authors: Nwoko Joy C. , Emeto Theophilus I. , Malau-Aduli Aduli E. O. , Malau-Aduli Bunmi S.
Published: June 2023

Teachers belong to a high-demand occupational group and experience work-related challenges and discretely diverse emotional turmoils of varying intensity while teaching and interacting with students. These experiences often result in high stress levels that contribute to burnout and, consequently, a breach of teachers’ occupational wellbeing. Promoting positive teacher wellbeing substantially influences teaching quality, with a flow-on effect on student wellbeing and academic development. This literature review utilised a framework to systematically explore the factors that impact the occupational wellbeing of kindergarten, primary, and secondary schoolteachers. Thirty-eight (38) studies from an initial 3766 peer-reviewed articles sourced from various databases (CINAHL, Emcare, PychINFO, Scopus, ERIC, and PsycARTICLES) were utilized for this systematic review. Four major factors were identified, including personal capabilities, socioemotional competence, personal responses to work conditions, and professional relationships. Findings highlight the importance of teachers’ occupational wellbeing in dealing with numerous challenges and competing demands, with the need for a high level of self-efficacy for instruction and behavioural management being critically significant. Teachers require adequate organisational support to successfully carry out their roles with stronger resilience and efficient job execution. Teachers also need to have social–emotional competence to be able to create a high-quality classroom environment and a conducive atmosphere that supports healthy teacher–student relationships, reduces stress and increases the occupational wellbeing of teachers. Collaborating with other relevant stakeholders such as parents, colleagues, and a school’s leadership team is critical for creating a positive work environment. A good workplace has the potential to contribute to teachers’ occupational wellbeing and provide a supportive platform for student learning and engagement. This review clearly points to the beneficial effects of prioritising teachers’ occupational wellbeing and its intentional inclusion in the professional development plan of practising teachers. Finally, while primary school teachers and secondary school teachers share many similarities in terms of the challenges they face, there are also some differences in how these challenges impact their wellbeing, and these warrant further investigation.
MCD Diet Modulates HuR and Oxidative Stress-Related HuR Targets in Rats
Authors: Ferrigno Andrea , Campagnoli Lucrezia Irene Maria , Barbieri Annalisa , Marchesi Nicoletta , Pascale Alessia , Croce Anna Cleta , Vairetti Mariapia , Di Pasqua Laura Giuseppina
Published: June 2023

The endogenous antioxidant defense plays a big part in the pathogenesis of non-alcoholic fatty liver disease (NAFLD), a common metabolic disorder that can lead to serious complications such as cirrhosis and cancer. HuR, an RNA-binding protein of the ELAV family, controls, among others, the stability of MnSOD and HO-1 mRNA. These two enzymes protect the liver cells from oxidative damage caused by excessive fat accumulation. Our aim was to investigate the expression of HuR and its targets in a methionine-choline deficient (MCD) model of NAFLD. To this aim, we fed male Wistar rats with an MCD diet for 3 and 6 weeks to induce NAFLD; then, we evaluated the expression of HuR, MnSOD, and HO-1. The MCD diet induced fat accumulation, hepatic injury, oxidative stress, and mitochondrial dysfunction. A HuR downregulation was also observed in association with a reduced expression of MnSOD and HO-1. Moreover, the changes in the expression of HuR and its targets were significantly correlated with oxidative stress and mitochondrial injury. Since HuR plays a protective role against oxidative stress, targeting this protein could be a therapeutic strategy to both prevent and counteract NAFLD.
The rs16969968 Tobacco Smoking-Related Single-Nucleotide Variant Is Associated with Clinical Markers in Patients with Severe COVID-19
Authors: Valencia-Pérez Rea Daniela , Falfán-Valencia Ramcés , Fricke-Galindo Ingrid , Buendía-Roldán Ivette , Chávez-Galán Leslie , Nava-Quiroz Karol J. , Alanis-Ponce Jesús , Pérez-Rubio Gloria
Published: June 2023

Tobacco smoking is the leading risk factor for many respiratory diseases. Several genes are associated with nicotine addiction, such as CHRNA5 and ADAM33. This research aims to evaluate the association of the polymorphisms rs16969968 (CHRNA5) and rs3918396 (ADAM33) in patients who developed severe COVID-19. We included 917 COVID-19 patients hospitalized with critical disease and oxygenation impairment. They were divided into two groups, tobacco-smoking (n = 257) and non-smoker (n = 660) patients. The genotype and allele frequencies of two single nucleotide variants, the rs16969968 (CHRNA5) and rs3918396 (ADAM33), were evaluated. The rs3918396 in ADAM33 does not show a significative association. We analyzed the study population according to the rs16969968 genotype (GA + AA, n = 180, and GG, n = 737). The erythrocyte sedimentation rate (ESR) shows statistical differences; the GA + AA group had higher values than the GG group (p = 0.038, 32 vs. 26 mm/h, respectively). The smoking patients and GA or AA genotype carriers had a high positive correlation (p < 0.001, rho = 0.753) between fibrinogen and C-reactive protein. COVID-19 patients and smokers carriers of one or two copies of the risk allele (rs16969968/A) have high ESR and a positive correlation between fibrinogen and C-reactive protein.
Lysophosphatidic Acid Receptor Signaling in the Human Breast Cancer Tumor Microenvironment Elicits Receptor-Dependent Effects on Tumor Progression
Authors: Benesch Matthew G. K. , Wu Rongrong , Tang Xiaoyun , Brindley David N. , Ishikawa Takashi , Takabe Kazuaki
Published: June 2023

Lysophosphatidic acid receptors (LPARs) are six G-protein-coupled receptors that mediate LPA signaling to promote tumorigenesis and therapy resistance in many cancer subtypes, including breast cancer. Individual-receptor-targeted monotherapies are under investigation, but receptor agonism or antagonism effects within the tumor microenvironment following treatment are minimally understood. In this study, we used three large, independent breast cancer patient cohorts (TCGA, METABRIC, and GSE96058) and single-cell RNA-sequencing data to show that increased tumor LPAR1, LPAR4, and LPAR6 expression correlated with a less aggressive phenotype, while high LPAR2 expression was particularly associated with increased tumor grade and mutational burden and decreased survival. Through gene set enrichment analysis, it was determined that cell cycling pathways were enriched in tumors with low LPAR1, LPAR4, and LPAR6 expression and high LPAR2 expression. LPAR levels were lower in tumors over normal breast tissue for LPAR1, LPAR3, LPAR4, and LPAR6, while the opposite was observed for LPAR2 and LPAR5. LPAR1 and LPAR4 were highest in cancer-associated fibroblasts, while LPAR6 was highest in endothelial cells, and LPAR2 was highest in cancer epithelial cells. Tumors high in LPAR5 and LPAR6 had the highest cytolytic activity scores, indicating decreased immune system evasion. Overall, our findings suggest that potential compensatory signaling via competing receptors must be considered in LPAR inhibitor therapy.
Insights into the Transcriptomics of Crop Wild Relatives to Unravel the Salinity Stress Adaptive Mechanisms
Authors: Abdul Aziz Mughair , Masmoudi Khaled
Published: June 2023

The narrow genomic diversity of modern cultivars is a major bottleneck for enhancing the crop’s salinity stress tolerance. The close relatives of modern cultivated plants, crop wild relatives (CWRs), can be a promising and sustainable resource to broaden the diversity of crops. Advances in transcriptomic technologies have revealed the untapped genetic diversity of CWRs that represents a practical gene pool for improving the plant’s adaptability to salt stress. Thus, the present study emphasizes the transcriptomics of CWRs for salinity stress tolerance. In this review, the impacts of salt stress on the plant’s physiological processes and development are overviewed, and the transcription factors (TFs) regulation of salinity stress tolerance is investigated. In addition to the molecular regulation, a brief discussion on the phytomorphological adaptation of plants under saline environments is provided. The study further highlights the availability and use of transcriptomic resources of CWR and their contribution to pangenome construction. Moreover, the utilization of CWRs’ genetic resources in the molecular breeding of crops for salinity stress tolerance is explored. Several studies have shown that cytoplasmic components such as calcium and kinases, and ion transporter genes such as Salt Overly Sensitive 1 (SOS1) and High-affinity Potassium Transporters (HKTs) are involved in the signaling of salt stress, and in mediating the distribution of excess Na+ ions within the plant cells. Recent comparative analyses of transcriptomic profiling through RNA sequencing (RNA-Seq) between the crops and their wild relatives have unraveled several TFs, stress-responsive genes, and regulatory proteins for generating salinity stress tolerance. This review specifies that the use of CWRs transcriptomics in combination with modern breeding experimental approaches such as genomic editing, de novo domestication, and speed breeding can accelerate the CWRs utilization in the breeding programs for enhancing the crop’s adaptability to saline conditions. The transcriptomic approaches optimize the crop genomes with the accumulation of favorable alleles that will be indispensable for designing salt-resilient crops.
Molecular Aspects of Hematological Malignancies and Benign Hematological Disorders
Authors: Găman Amelia Maria
Published: June 2023

Hematology represents a dynamic specialty in clinical medicine that requires solid knowledge of normal and pathological hematopoiesis, cytomorphology, pathology, immunology, genetics and molecular biology [...]
L-Poly(lactic acid) Production by Microwave Irradiation of Lactic Acid Obtained from Lignocellulosic Wastes
Authors: Senila Lacrimioara , Cadar Oana , Kovacs Eniko , Gal Emese , Dan Monica , Stupar Zamfira , Simedru Dorina , Senila Marin , Roman Cecilia
Published: June 2023

L-polylactic acid (PLA), a semi–crystalline aliphatic polyester, is one of the most manufactured biodegradable plastics worldwide. The objective of the study was to obtain L-polylactic acid (PLA) from lignocellulosic plum biomass. Initially, the biomass was processed via pressurized hot water pretreatment at a temperature of 180 °C for 30 min at 10 MPa for carbohydrate separation. Cellulase and the beta-glucosidase enzymes were then added, and the mixture was fermented with Lacticaseibacillus rhamnosus ATCC 7469. The resulting lactic acid was concentrated and purified after ammonium sulphate and n-butanol extraction. The productivity of L-lactic acid was 2.04 ± 0.18 g/L/h. Then, the PLA was synthesized in two stages. Firstly, lactic acid was subjected to azeotropic dehydration at 140 °C for 24 h in the presence of xylene, using SnCl2 (0.4 wt.%) as a catalyst, resulting in lactide (CPLA). Secondly, microwave-assisted polymerization was carried out at 140 °C for 30 min with 0.4 wt.% SnCl2. The resulting powder was purified with methanol to produce PLA with 92.1% yield. The obtained PLA was confirmed using electrospray ionization mass spectrometry, nuclear magnetic resonance, thermogravimetric analysis, Fourier transform infrared spectroscopy, scanning electron microscopy, and X-ray diffraction. Overall, the resulting PLA can successfully replace the traditional synthetic polymers used in the packaging industry.
Integrated Transcriptome and Metabolome Dynamic Analysis of Galls Induced by the Gall Mite Aceria pallida on Lycium barbarum Reveals the Molecular Mechanism Underlying Gall Formation and Development
Authors: Yang Mengke , Li Huanle , Qiao Haili , Guo Kun , Xu Rong , Wei Hongshuang , Wei Jianhe , Liu Sai , Xu Changqing
Published: June 2023

Galls have become the best model for exploring plant–gall inducer relationships, with most studies focusing on gall-inducing insects but few on gall mites. The gall mite Aceria pallida is a major pest of wolfberry, usually inducing galls on its leaves. For a better understanding of gall mite growth and development, the dynamics of the morphological and molecular characteristics and phytohormones of galls induced by A. pallida were studied by histological observation, transcriptomics and metabolomics. The galls developed from cell elongation of the epidermis and cell hyperplasia of mesophylls. The galls grew quickly, within 9 days, and the mite population increased rapidly within 18 days. The genes involved in chlorophyll biosynthesis, photosynthesis and phytohormone synthesis were significantly downregulated in galled tissues, but the genes associated with mitochondrial energy metabolism, transmembrane transport, carbohydrates and amino acid synthesis were distinctly upregulated. The levels of carbohydrates, amino acids and their derivatives, and indole-3-acetic acid (IAA) and cytokinins (CKs), were markedly enhanced in galled tissues. Interestingly, much higher contents of IAA and CKs were detected in gall mites than in plant tissues. These results suggest that galls act as nutrient sinks and favor increased accumulation of nutrients for mites, and that gall mites may contribute IAA and CKs during gall formation.
Theoretical Strategy for Interface Design and Thermal Performance Prediction in Diamond/Aluminum Composite Based on Scattering-Mediated Acoustic Mismatch Model
Authors: Hua Zhiliang , Wang Kang , Li Wenfang , Chen Zhiyan
Published: June 2023

Inserting modification layers at the diamond/Al interface is an effective technique in improving the interfacial thermal conductance (ITC) of the composite. However, few study reports the effect of interfacial structure on the thermal conductivity (TC) of diamond/Al composites at room temperature. Herein, the scattering-mediated acoustic mismatch model, suitable for evaluating the ITC at room temperature, is utilized to predict the TC performance of the diamond/Al composite. According to the practical microstructure of the composites, the reaction products at diamond/Al interface on the TC performance are concerned. Results indicate that the TC of the diamond/Al composite is dominantly affected by the thickness, the Debye temperature and the TC of the interfacial phase, meeting with multiple documented results. This work provides a method to assess the interfacial structure on the TC performance of metal matrix composite at room temperature.
High-Entropy Perovskite Thin Film in the Gd-Nd-Sm-La-Y-Co System: Deposition, Structure and Optoelectronic Properties
Authors: Krawczyk Pawel A. , Salamon Wojciech , Marzec Mateusz , Szuwarzyński Michał , Pawlak Jakub , Kanak Jarosław , Dziubaniuk Małgorzata , Kubiak Władyslaw W. , Żywczak Antoni
Published: June 2023

Multicomponent equimolar perovskite oxides (ME-POs) have recently emerged as a highly promising class of materials with unique synergistic effects, making them well-suited for applications in such areas as photovoltaics and micro- and nanoelectronics. High-entropy perovskite oxide thin film in the (Gd0.2Nd0.2La0.2Sm0.2Y0.2)CoO3 (RECO, where RE = Gd0.2Nd0.2La0.2Sm0.2Y0.2, C = Co, and O = O3) system was synthesized via pulsed laser deposition. The crystalline growth in an amorphous fused quartz substrate and single-phase composition of the synthesized film was confirmed by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Surface conductivity and activation energy were determined using a novel technique implementing atomic force microscopy (AFM) in combination with current mapping. The optoelectronic properties of the deposited RECO thin film were characterized using UV/VIS spectroscopy. The energy gap and nature of optical transitions were calculated using the Inverse Logarithmic Derivative (ILD) and four-point resistance method, suggesting direct allowed transitions with altered dispersions. The narrow energy gap of RECO, along with its relatively high absorption properties in the visible spectrum, positions it as a promising candidate for further exploration in the domains of low-energy infrared optics and electrocatalysis.
Effect of Manganese Alloying on Infrared Detectors Made of Pb1−xMnxTe/CdTe Multilayer Composite
Authors: Chusnutdinow Sergij , Kazakov Alexander , Jakieła Rafał , Szot Michał , Schreyeck Steffen , Brunner Karl , Karczewski Grzegorz
Published: June 2023

The properties of Pb1−xMnxTe/CdTe multilayer composite grown by molecular beam epitaxy on a GaAs substrate were studied. The study included morphological characterization by X-ray diffraction, scanning electron microscopy, secondary ion mass spectroscopy, as well as electron transport and optical spectroscopy measurements. The main focus of the study was on the sensing properties of photoresistors made of Pb1−xMnxTe/CdTe in the infrared spectral region. It was shown that the presence of Mn in the Pb1−xMnxTe conductive layers shifted the cut-off wavelength toward blue and weakened the spectral sensitivity of the photoresistors. The first effect was due to an increase in the energy gap of Pb1−xMnxTe with an increase in Mn concentration, and the second was due to a pronounced deterioration in the crystal quality of the multilayers owing to the presence of Mn atoms, as shown by the morphological analysis.
Eco-Concrete in High Temperatures
Authors: Sundin Marcin , Hedlund Hans , Cwirzen Andrzej
Published: June 2023

Concrete technology is becoming more and more sustainable and ecological following more extensive and focused research. The usage of industrial waste and by-products, such as steel ground granulated blast-furnace slag (GGBFS), mine tailing, fly ash, and recycled fibers, is a very important step toward a good transition of concrete into a “green” future and significant improvement in waste management in the world. However, there are also several known durability-related problems with some types of eco-concretes, including exposure to fire. The general mechanism occurring in fire and high-temperature scenarios is broadly known. There are many variables that weightily influence the performance of this material. This literature review has gathered information and results regarding more sustainable and fire-resistant binders, fire-resistant aggregates, and testing methods. Mixes that utilize industrial waste as a total or partial cement replacement have been consistently achieving favorable and frequently superior outcomes when compared to conventional ordinary Portland cement (OPC)-based mixes, especially at a temperature exposure up to 400 °C. However, the primary emphasis is placed on examining the impact of the matrix components, with less attention given to other factors such as sample treatment during and following exposure to high temperatures. Furthermore, there is a shortage of established standards that could be utilized in small-scale testing.
Synthesis of Sulfur@g-C3N4 and CuS@g-C3N4 Catalysts for Hydrogen Production from Sodium Borohydride
Authors: Alshammari Khulaif , Alotaibi Turki , Alshammari Majed , Alhassan Sultan , Alshammari Alhulw H. , Taha Taha Abdel Mohaymen
Published: June 2023

In this work, the S@g-C3N4 and CuS@g-C3N4 catalysts were prepared via the polycondensation process. The structural properties of these samples were completed on XRD, FTIR and ESEM techniques. The XRD pattern of S@g-C3N4 presents a sharp peak at 27.2° and a weak peak at 13.01° and the reflections of CuS belong to the hexagonal phase. The interplanar distance decreased from 0.328 to 0.319 nm that facilitate charge carrier separation and promoting H2 generation. FTIR data revealed the structural change according to absorption bands of g-C3N4. ESEM images of S@g-C3N4 exhibited the described layered sheet structure for g-C3N4 materials and CuS@g-C3N4 demonstrated that the sheet materials were fragmented throughout the growth process. The data of BET revealed a higher surface area (55 m2/g) for the CuS-g-C3N4 nanosheet. The UV–vis absorption spectrum of S@g-C3N4 showed a strong peak at 322 nm, which weakened after the growth of CuS at g-C3N4. The PL emission data showed a peak at 441 nm, which correlated with electron–hole pair recombination. The data of hydrogen evolution showed improved performance for the CuS@g-C3N4 catalyst (5227 mL/g·min). Moreover, the activation energy was determined for S@g-C3N4 and CuS@g-C3N4, which showed a lowering from 47.33 ± 0.02 to 41.15 ± 0.02 KJ/mol.
In Situ Inclusion Detection and Material Characterization in an Electron Beam Powder Bed Fusion Process Using Electron Optical Imaging
Authors: Gardfjell Martin , Reith Marcel , Franke Martin , Körner Carolin
Published: June 2023

Electron Beam Powder Bed Fusion (PBF-EB) is an Additive Manufacturing (AM) method that utilizes an electron beam to melt and consolidate metal powder. The beam, combined with a backscattered electron detector, enables advanced process monitoring, a method termed Electron Optical Imaging (ELO). ELO is already known to provide great topographical information, but its capabilities regarding material contrast are less studied. In this article the extents of material contrast using ELO are investigated, focusing mainly on identifying powder contamination. It will be shown that an ELO detector is capable of distinguishing a single 100 μm foreign powder particle, during an PBF-EB process, if the backscattering coefficient of the inclusion is sufficiently higher than its surroundings. Additionally, it is investigated how the material contrast can be used for material characterization. A mathematical framework is provided to describe the relationship between the signal intensity in the detector and the effective atomic number Zeff of the imaged alloy. The approach is verified with empirical data from twelve different materials, demonstrating that the effective atomic number of an alloy can be predicted to within one atomic number from its ELO intensity.
Fish Skin Mucus Extracts: An Underexplored Source of Antimicrobial Agents
Authors: Díaz-Puertas Rocío , Adamek Mikolaj , Mallavia Ricardo , Falco Alberto
Published: June 2023

The slow discovery of new antibiotics combined with the alarming emergence of antibiotic-resistant bacteria underscores the need for alternative treatments. In this regard, fish skin mucus has been demonstrated to contain a diverse array of bioactive molecules with antimicrobial properties, including peptides, proteins, and other metabolites. This review aims to provide an overview of the antimicrobial molecules found in fish skin mucus and its reported in vitro antimicrobial capacity against bacteria, fungi, and viruses. Additionally, the different methods of mucus extraction, which can be grouped as aqueous, organic, and acidic extractions, are presented. Finally, omic techniques (genomics, transcriptomics, proteomics, metabolomics, and multiomics) are described as key tools for the identification and isolation of new antimicrobial compounds. Overall, this study provides valuable insight into the potential of fish skin mucus as a promising source for the discovery of new antimicrobial agents.
Polymorphisms of Fat Mass and Obesity-Associated Gene in the Pathogenesis of Child and Adolescent Metabolic Syndrome
Authors: Song Yongyan , Wade Henry , Zhang Bingrui , Xu Wenhao , Wu Rongxue , Li Shujin , Su Qiaozhu
Published: June 2023

Childhood metabolic syndrome (MetS) is prevalent around the world and is associated with a high likelihood of suffering from severe diseases such as cardiovascular disease later in adulthood. MetS is associated with genetic susceptibility that involves gene polymorphisms. The fat mass and obesity-associated gene (FTO) encodes an RNA N6-methyladenosine demethylase that regulates RNA stability and molecular functions. Human FTO contains genetic variants that significantly contribute to the early onset of MetS in children and adolescents. Emerging evidence has also uncovered that FTO polymorphisms in intron 1, such as rs9939609 and rs9930506 polymorphisms, are significantly associated with the development of MetS in children and adolescents. Mechanistic studies reported that FTO polymorphisms lead to aberrant expressions of FTO and the adjacent genes that promote adipogenesis and appetite and reduce steatolysis, satiety, and energy expenditure in the carriers. The present review highlights the recent observations on the key FTO polymorphisms that are associated with child and adolescent MetS with an exploration of the molecular mechanisms underlying the development of increased waist circumference, hypertension, and hyperlipidemia in child and adolescent MetS.
Eggs: Healthy or Risky? A Review of Evidence from High Quality Studies on Hen’s Eggs
Authors: Myers Madeleine , Ruxton Carrie Helen Stevenson
Published: June 2023

Hen’s eggs (from Gallus gallus domesticus) provide choline, folate, vitamin D, iodine, B vitamins and high-quality protein and are no longer viewed by national bodies as a risk factor for hypercholesterolaemia and cardiovascular disease (CVD). Yet, questions remain about the benefits and risks of eating eggs regularly. This review evaluates recent high-quality evidence from randomised controlled trials (RCT) and meta-analyses of observational studies and considers new areas of interest, such as weight management, protein metabolism, allergy risk and sustainability. In several RCT, eggs increased muscle protein synthesis and lowered fat mass, which could support optimal body composition. Eggs within a meal improved satiety, which could translate into lower energy intakes, although more RCT are needed. In observational studies, higher egg consumption was associated with a null effect or a modest reduced risk of CVD. For type 2 diabetes (T2D) incidence and risk of CVD in people with T2D, there were inconsistencies between observational and RCT data, with the former noting positive associations and the latter seeing no effect of higher egg intake on markers of T2D and CVD. Sustainability metrics suggest that eggs have the lowest planetary impact amongst animal proteins. To lower allergy risk, earlier introduction of eggs into weaning diets is warranted. In conclusion, the balance of evidence points to eggs being a nutritious food suggesting there are broad health benefits from including eggs in the diet at intakes higher than that currently consumed by European populations.
Youth and Peer Mentor Led Interventions to Improve Biometric-, Nutrition, Physical Activity, and Psychosocial-Related Outcomes in Children and Adolescents: A Systematic Review
Authors: Lavelle Margaret A. , Knopp Miriam , Gunther Carolyn W. , Hopkins Laura C.
Published: June 2023

The utilization of youth (older) and peer (same age) mentor-led interventions to improve nutrition and physical activity has been an emerging trend in recent years. This systematic review is intended to synthesize the effectiveness of these intervention programs on participants and mentors based on biometric, nutrition, physical activity, and psychosocial outcomes of youth and peer mentor-led interventions among children and adolescents. Online databases, including PubMed, ScienceDirect, EBSCOhost and Google Scholar, were searched, and the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) guidelines were followed. A three-step screening process was used to meet the proposed eligibility criteria, and the risk-of-bias tool for randomized trials (RoB 2) was used to assess bias for the included studies. Nineteen unique intervention programs and twenty-five total studies were deemed eligible when considering the criteria required for review. Multiple studies demonstrated positive evidence of the biometric and physical activity outcomes that were considered significant. The findings regarding the nutritional outcomes across the included studies were mixed, as some studies reported significant changes in eating habits while others did not find a significant change. Overall, the utilization of youth and peer mentor-led models in nutrition- and physical-activity-related interventions may be successful in overweight and obesity prevention efforts for those children and adolescents receiving the intervention and the youths and peers leading the interventions. More research is needed to explore the impact on the youths and peers leading the interventions and disseminating more detailed implementation strategies, e.g., training mentors would allow for advancements in the field and the replicability of approaches. Terminology: In the current youth- and peer-led nutrition and physical activity intervention literature, a varying age differential exists between the targeted sample and the peers, and varying terminology with regards to how to name or refer to the youth. In some instances, the youth mentors were individuals of the same grade as the target sample who either volunteered to serve in the peer role or were selected by their fellow students or school staff. In other cases, the youth mentors were slightly older individuals, either in high school or college, who were selected based upon their experience, leadership skills, passion for the project, or demonstration of healthy lifestyle behaviors.
Remote Sensing and Data Analyses on Planetary Topography
Authors: Kim Jungrack , Lin Shih-Yuan , Xiao Haifeng
Published: June 2023

Planetary mapping product established by topographic remote sensing is one of the most significant achievements of contemporary technology. Modern planetary remote sensing technology now measures the topography of familiar solid planets/satellites such as Mars and the Moon with sub-meter precision, and its applications extend to the Kuiper Belt of the Solar System. However, due to a lack of fundamental knowledge of planetary remote sensing technology, the general public and even the scientific community often misunderstand these astounding accomplishments. Because of this technical gap, the information that reaches the public is sometimes misleading and makes it difficult for the scientific community to effectively respond to and address this misinformation. Furthermore, the potential for incorrect interpretation of the scientific analysis might increase as planetary research itself increasingly relies on publicly accessible tools and data without a sufficient understanding of the underlying technology. This review intends to provide the research community and personnel involved in planetary geologic and geomorphic studies with the technical foundation of planetary topographic remote sensing. To achieve this, we reviewed the scientific results established over centuries for the topography of each planet/satellite in the Solar System and concisely presented their technical bases. To bridge the interdisciplinary gap in planetary science research, a special emphasis was placed on providing photogrammetric techniques, a key component of remote sensing of planetary topographic remote sensing.
Correction: Zhang et al. Lunar Procellarum KREEP Terrane (PKT) Stratigraphy and Structure with Depth: Evidence for Significantly Decreased Th Concentrations and Thermal Evolution Consequences. Remote Sens. 2023, 15, 1861
Authors: Zhang Jingyi , Head James W. , Liu Jianzhong , Potter Ross W. K.
Published: June 2023

Additional Affiliation(s) [...]
Rice False Smut Monitoring Based on Band Selection of UAV Hyperspectral Data
Authors: Wang Yanxiang , Xing Minfeng , Zhang Hongguo , He Binbin , Zhang Yi
Published: June 2023

Rice false smut (RFS) is a late-onset fungal disease that primarily affects rice panicle in recent years. Severe RFS can decrease the yield by 20–30% and severely affect rice quality. This research used hyperspectral remote sensing data from unmanned aerial vehicles (UAV). On the basis of genetic algorithm combined with partial least squares to select the feature bands, this paper creates a new method to use the Pearson correlation coefficient method and Instability Index between Classes (ISIC) method to further select characteristic bands, which further eliminated 27.78% of the feature bands when the model monitoring accuracy was improved overall. The prediction accuracy of the Gradient Boosting Decision Tree model and Random Forest model was the best, which were 85.62% and 84.10%, respectively, and the monitoring accuracy was improved by 2.22% and 2.4% compared with that before optimization. Then, based on the UAV hyperspectral data and the combination of characteristic bands selected by the three band optimization methods, the sensitive band ranges of rice false smut monitoring were determined, which were 698–800 nm and 974–997 nm. This paper provides an effective method of selecting characteristic bands of hyperspectral data and a method of monitoring crop diseases’ using unmanned aerial vehicles.