bluuebunny/crossref_metadata_2025 huggingface dataset:
Response of glaciers in the Suntar–Khayata range, eastern Siberia, to climate change
Authors: Takahashi Shuhei , Sugiura Konosuke , Kameda Takao , Enomoto Hiroyuki , Kononov Yury , Ananicheva Maria D. , Kapustin Gregory
Published: September 2011

Abstarct

Following an International Geophysical Year project, we conducted meteorological observations during 2004–07 around the Suntar–Khayata range in eastern Siberia, where a strong temperature inversion exists throughout the winter. The temperature on the flat plain around Oymyakon (~700ma.s.l.) was ~20°C lower than that in a glaciated area located at ~2000ma.s.l. The inversion remained stable from October to April due to the Siberian high. Snowfall was limited to the beginning and end of winter. The stable conditions prevented atmospheric disturbances and inhibited snowfall during midwinter. From 1945 to 2003, glaciers in the Suntar–Khayata range retreated, with an area reduction of 19.3%. To assess this retreat, we estimated the response of the glaciers to climate change. According to US National Centers for Environmental Prediction (NCEP) data, the temperature in this region increased by ~1.9°C over 60 years. By calculating snow accumulation and ablation, the sensitivity of the equilibrium-line altitude (ELA) to the temperature shift was evaluated. We estimated snow precipitation based on precipitation at <0°C and ablation using the degree-day method. By these estimates, the ELA of Glacier No. 31, assumed 2350 m at present, could rise ~150m if temperature rises an average of 1°C. Furthermore, a 1.8°C temperature rise could cause the ELA to rise to 2600ma.s.l., removing the accumulation zone. With no accumulation zone, the glacier body would decrease, roughly halving in volume after ~400 years.
Wind and drifting-snow gust factor in an Alpine context
Authors: Naaim-Bouvet Florence , Naaim Mohamed , Bellot Hervé , Nishimura Kouichi
Published: September 2011

Abstarct

Wind-transported snow is a common phenomenon in cold windy areas, creating snowdrifts and contributing significantly to the loading of avalanche release areas. It is therefore necessary to take into account snowdrift formation both in terms of predicting and controlling drift patterns. Particularly in an Alpine context, drifting snow is a nonstationary phenomenon, which has not been taken into account in physical modeling carried out in wind tunnels or in numerical simulations. Only a few studies have been conducted to address the relation between wind gusts and drifting-snow gusts. Consequently, the present study was conducted at the Lac Blanc pass (2700ma.s.l.) experimental site in the French Alps using a snow particle counter and a cup anemometer in order to investigate drifting-snow gusts. First, it was shown that the behavior of the wind gust factor was coherent with previous studies. Then the definition of wind gust factor was extended to a drifting-snow gust factor. Sporadic drifting-snow events were removed from the analysis to avoid artificially high drifting-snow gust factors. Two trends were identified: (1) A high 1 s peak and a mean 10 min drifting-snow gust factor, greater than expected, were observed for events that exhibited a gamma distribution on the particle width histogram. The values of drifting-snow gust factors decreased with increasing gust duration. (2) Small drifting-snow gusts (i.e. smaller than or of the same order of magnitude as wind gusts) were also observed. However, in this case, they were systematically characterized by a snow particle size distribution that differed from the two-parameter gamma probability density function.
Glacier flow measurement and radio-echo sounding at Aurora Peak, Alaska, in 2008
Authors: Fukuda Takehiro , Sugiyama Shin , Matoba Sumito , Shiraiwa Takayuki
Published: September 2011

Abstarct

As part of a deep ice-core drilling project, GPS and ice-radar measurements were made in the vicinity of Aurora Peak, Alaska, USA. Surface and bed elevation maps were obtained over an area of 400 m×700 m, which includes the drilling site. Surface flow velocity was measured at 18 locations in the same area. The results showed that the drilling site was situated on a gentle north–south ridge with saddle-shaped surface geometry. The horizontal ice-flow velocity at the drilling site was <0.5ma–1 and the ice generally flowed eastward and westward along the surface slope. The glacier bed slopes to the east and has more complex topography than the ice surface. The drilling site was situated above a bedrock dip, with an ice thickness of 252±10 m. These data constitute important information for estimating the effect of ice flow to the ice core retrieved from the depth of up to 180.17 m.
Seasonal development of spatial snow-depth variability across different scales in the Swiss Alps
Authors: Egli Luca , Griessinger Nena , Jonas Tobias
Published: September 2011

Abstarct

The depth of snow cover is temporally and spatially heterogeneous at different scales in Alpine regions. For snow hydrology/climatology the spatial variability of snow depths is a key parameter for capturing the total amount of snow in a given area. Here a scale analysis of the spatial variability of snow depths during the accumulation period is investigated. The development of the variability is characterized by a parameter, β, describing the relationship between the standard deviation and the mean of snow depths. The analysis includes two datasets: (1) 141 snow-depth point measurements representing flat-field observations, and (2) snow precipitation from the numerical weather prediction model COSMO-7. The results reveal that β is almost invariant at scales between 10 and 300 km. The COSMO-7 data exhibit the same scale invariance above 50 km, indicating that the spatial variability of snow depths is formed by the precipitation pattern at these scales. The scaling analysis of β allows determination of the absolute accuracy of estimating the total amount of snow in a given area and helps to validate different snow models or remote-sensing techniques by ground truth verification.
Altitudinal dependency of snow amounts in two small alpine catchments: can catchment-wide snow amounts be estimated via single snow or precipitation stations?
Authors: Grünewald Thomas , Lehning Michael
Published: September 2011

Abstarct

The spatial distribution and the local amount of snow in mountainous regions strongly depend on the spatial characteristics of snowfall, snow deposition and snow redistribution. Uniform altitudinal gradients can only represent a part of these influences but are without alternative for use in larger-scale models. How well altitudinal gradients represent the true snow distribution has not been assessed. We analyse altitudinal characteristics of snow stored in two high-alpine catchments in Switzerland. Peak winter snow depths were monitored using high-resolution airborne laser scanning technology. These snow depths were transferred to snow water equivalent by applying simple density estimations. From these data, altitudinal gradients were calculated for the total catchment areas and for selected subareas characterized by different accumulation patterns. These gradients were then compared with gradients resulting from automated snow depth measurements obtained from several snow stations on different height levels located in the catchments, and with estimations from climatological precipitation gradients. The analysis showed that neither precipitation gradients nor flat-field stations estimate catchment-wide snow amounts accurately. While the climatological gradient showed different trends for different areas and years, the snow stations tended to overestimate mean snow amounts.
Simulation of a snow avalanche model test using computational fluid dynamics
Authors: Oda Kenichi , Moriguchi Shuji , Kamiishi Isao , Yashima Atsushi , Sawada Kazuhide , Sato Atsushi
Published: September 2011

Abstarct

Here we apply a two-phase flow model to simulate snow avalanche motion. Flowing snow is modeled as a Bingham fluid. Small-scale laboratory experiments were conducted using a rotating viscometer to validate the constitutive model. Experimental scale model test-runs were also performed, and run-out distances and impact pressures obtained in the model tests were reproduced using the two-phase flow model. Comparisons revealed that the simulated results were strongly dependent on the basal friction angle and calculation mesh size. Although the method reproduced the laboratory model results quite well, constitutive aspects of the basal surface remained unsolved. Future research will need to incorporate a numerical technique to handle the basal boundary, such as a boundary-fitted coordinate technique.
Sea-ice extent variation along the coast of Hokkaido, Japan: Earth’s lowest-latitude occurrence of sea ice and its relation to changing climate
Authors: Takahashi Shuhei , Kosugi Tomofumi , Enomoto Hiroyuki
Published: September 2011

Abstarct

The seasonal duration of sea-ice cover in the region immediately north of Hokkaido in the Sea of Okhotsk was estimated from daily sea-ice concentration maps (1995–2009) produced by the Japanese Coast Guard. The results show that this period is generally well represented by the proxy record of sea-ice duration in the region of Utoro in the Shiretoko peninsula. Comparison of the duration of seasonal sea-ice cover along the coast of Hokkaido with meteorological conditions over the period of sea-ice mapping by the Japanese Coast Guard indicates that all sea ice will disappear from the coast of Hokkaido once air temperature is increased by 2–4˚C over present values by the effects of climate change.
The English-Speaking Peoples Before Churchill
Authors: Clarke Peter
Published: September 2011

The English-speaking peoples' is a phrase indelibly associated with Winston Churchill, both as politician and as author. It is often assumed that this concept originated in socially privileged, politically conservative and generally establishment-minded circles and that it achieved its greatest currency in the Churchill-Roosevelt era spanning World War Two. But how much interest had Churchill actually shown in the English-speaking peoples in his early career? This artcile looks for the historical origins of the concept, initially by exploring the databases of some leading British and American newspapers. The significance of the American Civil War, in generating a common language of democratic populism, becomes clear. Likewise the use of Anglo-Saxonist terminology, not least by whiggish historians, is examined, as are concepts like Greater Britain and the term Commonweath as applied to the British Empire. Historians will not be surprised to learn that all these usages changed over time, appealing to different constituencies, and responding to political as well as intellectual influences. Thus the concept of the English-speaking peoples had its own history, long before it became a subject for the pen, and for the tongue, of Winston Churchill.
The United States, 1783–1861: Britain's Honorary Dominion?
Authors: Hopkins A. G.
Published: September 2011

This essay reinterprets the evolution of the United States between 1783 and 1861 from the perspective of imperial history. The established literature on this period focuses on the national story, and particularly on the struggle to achieve liberty and democracy. Historians of empire, however, routinely distinguish between formal and effective independence and evaluate the often halting progress of ex-colonial states in achieving a substantive transfer of power. Considered from this angle, the dominant themes of the period were the search for viability and development rather than for liberty and democracy. The article illustrates this proposition by re-evaluating the political, economic, and cultural themes that are central to the history of the period. The argument in each case is that the United States remained dependent on Great Britain to an extent that greatly limited her effective independence. The standard controversies of domestic political history, notably the battle between Hamiltonian and Jeffersonian visions of the state, are recast as differing strategies for achieving real and permanent independence. Strategies for achieving economic development made practical politics of competing arguments for protection and free trade, but failed to release the economy from its dependence on the British market and British capital. Attempts to create an independent national identity were compromised by the continuing influence of British culture and by the related notion of Anglo-Saxonism, on which prevailing policies of assimilation relied. In all these respects, the United States was an unexceptional ex-colonial state, and indeed closely followed the trajectory of other colonies of white settlement that were classified as dominions within the British Empire. The United States, however, was a dependent state that failed in 1861, and its struggle for independence had to be renewed after the Civil War.
The Past Re-imagined: Memory and Representations of Power in Historical Fiction for Children
Authors: WILSON KIM
Published: September 2011

This article argues that historical fiction functions as a collective memory: it provides a social framework for recollections that speak of a national agenda often through personal experiences. Taking as its examples three Australian and New Zealand fictions for children and young adults, from the late twentieth and early twentieth-first century, the article examines texts that focus on how we remember the past and what aspects of that past should be remembered: Memorial (1999), a picture book by Gary Crew (author) and Shaun Tan (illustrator), The Divine Wind (1998) by Garry Disher, and The Swap (2004) by Wendy Catran. Close analysis of these texts suggests that, like memory itself, historical fiction tends to eulogise the past. In historical fiction, for children especially, whilst power relations of cultural significance can be perpetuated, they can also be re-positioned or re-invented in order to re-imagine the past. Shifts in the present understanding of past power relationships contribute towards the reinvention of race relations, national ideologies and the locus of political dissent. The article concludes that historical fiction, because of its simultaneous claim to fact and imagination, can be a powerful and cunning mode of propaganda.
Of Nils and Nation: Selma Lagerlöf's The Wonderful Adventures of Nils
Authors: SUNDMARK BJÖRN
Published: September 2011

Recently past its centenary, The Wonderful Adventures of Nils (1906–7), by Selma Lagerlöf, has remained an international children's classic, famous for its charm and magical elements. This article returns to read the book in its original contexts, and sets out to demonstrate that it was also published as a work of instruction, a work of geography, calculated to build character and nation. Arguing that it represents the vested interests of the state school system, and the national ideology of modern Sweden, the article analyses Nils's journey as the production of a Swedish ‘space’. With a focus on representations of power and nationhood in the text, it points to the way Lagerlöf takes stock of the nation's natural resources, characterises its inhabitants, draws upon legends and history, and ultimately constructs a ‘folkhem’, where social classes, ethnic groups and linguistic differences are all made to contribute to a sense of Swedish belonging and destiny.
Approximating the Minimum Tour Cover of a Digraph
Authors: Nguyen Viet Hung
Published: September 2011

Given a directed graph G with non-negative cost on the arcs, a directed tour cover T of G is a cycle (not necessarily simple) in G such that either head or tail (or both of them) of every arc in G is touched by T. The minimum directed tour cover problem (DToCP), which is to find a directed tour cover of minimum cost, is NP-hard. It is thus interesting to design approximation algorithms with performance guarantee to solve this problem. Although its undirected counterpart (ToCP) has been studied in recent years, in our knowledge, the DToCP remains widely open. In this paper, we give a 2 log2(n)-approximation algorithm for the DToCP.
A Comparison of the Anti-Tumor Effects of a Chimeric versus Murine Anti-CD19 Immunotoxins on Human B Cell Lymphoma and Pre-B Acute Lymphoblastic Leukemia Cell Lines
Authors: Tsai Lydia K. , Pop Laurentiu M. , Liu Xiaoyun , Vitetta Ellen S.
Published: September 2011

Precursor B cell acute lymphoblastic leukemia (pre-B ALL) affects five to six thousand adults and almost three thousand children every year. Approximately 25% of the children and 60% of the adults die from their disease, highlighting the need for new therapies that complement rather than overlap chemotherapy and bone marrow transplantation. Immunotherapy is a class of therapies where toxicities and mechanisms of action do not overlap with those of chemotherapy. Because CD19 is a B cell- restricted membrane antigen that is expressed on the majority of pre-B tumor cells, a CD19-based immunotherapy is being developed for ALL. In this study, the anti-tumor activities of immunotoxins (ITs) constructed by conjugating a murine monoclonal antibody (MAb), HD37, or its chimeric (c) construct to recombinant ricin toxin A chain (rRTA) were compared both in vitro using human pre-B ALL and Burkitt’s lymphoma cell lines and in vivo using a disseminated human pre-B ALL tumor cell xenograft model. The murine and chimeric HD37 IT constructs were equally cytotoxic to pre-B ALL and Burkitt’s lymphoma cells in vitro and their use in vivo resulted in equivalent increases in survival of SCID mice with human pre-B ALL tumors when compared with control mice.
Terthiophene on Au(111): A scanning tunneling microscopy and spectroscopy study
Authors: Koslowski Berndt , Tschetschetkin Anna , Maurer Norbert , Mena-Osteritz Elena , Bäuerle Peter , Ziemann Paul
Published: September 2011

Terthiophene (3T) molecules adsorbed on herringbone (HB) reconstructed Au(111) surfaces in the low coverage regime were investigated by means of low-temperature scanning tunneling microscopy (STM) and spectroscopy (STS) under ultra-high vacuum conditions. The 3T molecules adsorb preferentially in fcc regions of the HB reconstruction with their longer axis oriented perpendicular to the soliton walls of the HB and at maximum mutual separation. The latter observation points to a repulsive interaction between molecules probably due to parallel electrical dipoles formed during adsorption. Constant-separation (I-V) and constant-current (z-V) STS clearly reveal the highest occupied (HOMO) and lowest unoccupied (LUMO) molecular orbitals, which are found at −1.2 eV and +2.3 eV, respectively. The HOMO–LUMO gap corresponds to that of a free molecule, indicating a rather weak interaction between 3T and Au(111). According to conductivity maps, the HOMO and LUMO are inhomogeneously distributed over the adsorbed 3T, with the HOMO being located at the ends of the linear molecule, and the LUMO symmetrically with respect to the longer axis of the molecule at the center of its flanks. Analysis of spectroscopic data reveals details of the contrast mechanism of 3T/Au(111) in STM. For that, the Shockley-like surface state of Au(111) plays an essential role and appears shifted outwards from the surface in the presence of the molecule. As a consequence, the molecule can be imaged even at a tunneling bias within its HOMO–LUMO gap. A more quantitative analysis of this detail resolves a previous discrepancy between the fairly small apparent STM height of 3T molecules (1.4–2.0 nm, depending on tunneling bias) and a corresponding larger value of 3.5 nm based on X-ray standing wave analysis. An additionally observed linear decrease of the differential tunneling barrier at positive bias when determined on top of a 3T molecule is compared to the bias independent barrier obtained on bare Au(111) surfaces. This striking difference of the barrier behavior with and without adsorbed molecules is interpreted as indicating an adsorption-induced dimensionality transition of the involved tunneling processes.
Use of mixed Li/K metal TMP amide (LiNK chemistry) for the synthesis of [2.2]metacyclophanes
Authors: Blangetti Marco , Fleming Patricia , O'Shea Donal F
Published: September 2011

A new two-step general approach to [2.2]metacyclophane synthesis from substituted m-xylenes is described. The strategy employs a selective benzylic metalation and oxidative C–C bond formation for both synthetic operations. Regioselective benzylic metalation is achieved using the BuLi, KOt-Bu, TMP(H) (2,2,6,6-tetramethylpiperidine) combination (LiNK metalation conditions) and oxidative coupling with 1,2-dibromoethane. The synthetic ease of this approach compares favourably with previously reported methods and allows for ready access to potentially useful planar chiral derivatives.
Rapid Viral Response of Once-Daily Tmc435 plus Pegylated Interferon/Ribavirin in Hepatitis C Genotype-1 Patients: A Randomized Trial
Authors: Manns Michael , Reesink Henk , Berg Thomas , Dusheiko Geoffrey , Flisiak Robert , Marcellin Patrick , Moreno Christophe , Lenz Oliver , Meyvisch Paul , Peeters Monika , Sekar Vanitha , Simmen Kenneth , Verloes Rene
Published: September 2011

Background

Antiviral activity of TMC435, an oral, once-daily, HCV NS3/4A protease inhibitor, was evaluated with pegylated interferon-α2a/ribavirin (P/R) in HCV genotype-1 patients.

Methods

Optimal Protease inhibitor Enhancement of Response to TherApy (OPERA-1; TMC435-C201; NCT00561353) is a Phase IIa, randomized, placebo-controlled study. Treatment-naive patients ( n=74) received 25, 75 or 200 mg TMC435 once daily, or placebo for 7 days followed by 21 days of triple therapy with P/R, or triple therapy for 28 days. Treatment-experienced patients ( n=37; 56.8% with cirrhosis) received 75, 150 or 200 mg TMC435 once daily, or placebo with P/R for 28 days. Patients continued P/R up to week 48.

Results

Treatment-naive patients who received initial monotherapy had a rapid decline in HCV RNA by day 3. At day 7, HCV RNA reductions were greatest for the 75 and 200 mg doses (0.02, -2.63, -3.43 and -4.13 log10 IU/ml for placebo, and TMC435 25, 75 and 200 mg, respectively). At day 28, all patients who received triple therapy with TMC435 75 or 200 mg had HCV RNA<25 IU/ml versus 4/9 for placebo. In total, 18/28 treatment- experienced patients (9/9 prior relapsers, 9/19 non-responders) who received TMC435 had HCV RNA<25 IU/ml at day 28 versus 0/9 for placebo; similar results were observed for the 150 and 200 mg doses. Most adverse events were grade 1/2. No relevant changes in laboratory parameters occurred, except mild and reversible bilirubin elevations, mostly at the 200 mg dose.

Conclusions

Once-daily TMC435 with P/R showed potent, dose-dependent antiviral activity over 28 days, and had a favourable tolerability profile.
Trace gas fluxes of CO2, CH4 and N2O in a permanent grassland soil exposed to elevated CO2 in the Giessen FACE study
Authors: Kaleem Abbasi M. , Müller C.
Published: September 2011

Abstract. Long-term field observations showed that N2O fluxes observed shortly after N application were not significantly affected by elevated CO2 in the Giessen Free Air Carbon dioxide Enrichment (FACE) study. To further investigate this unexpected result a 15N tracer study was carried out under controlled conditions where in parallel treatments either the NH4+ pool (15NH4NO3) or the NO3− pool (NH415NO3) was enriched with 15N. Fluxes of CO2, CH4, and N2O as well as the 15N enrichment of the N2O were measured. Denitrifying Enzyme Activity (DEA), total denitrification (N2 + N2O) and N2-to-N2O ratios were quantified in separate experiments. Over the 57 day incubation, N2O fluxes averaged 0.090 ng N2O-N g−1 h−1 under ambient and 0.083 ng N2O-N g−1 h−1 under elevated CO2 (not significantly different). The N2O production processes were identified by a two-source model. Results showed that N2O must have also been produced by a third source – possibly related to organic N transformation – which was stimulated by elevated CO2. Soil CO2 fluxes were approximately 20 % higher under elevated CO2 than soil from ambient but the differences were not significant. CH4 oxidation rates were on average −1.75 ng CH4-C g−1 h−1 in the elevated and −1.17 ng CH4-C g−1 h−1 in the ambient indicating that elevated CO2 increased the CH4 oxidation by 49 % compared to ambient CO2 under controlled conditions. N fertilization increased CH4 oxidation by 3-fold in both CO2 treatments. CO2 did not have any significant effect on DEA while total denitrification and N2-to-N2O ratios increased by 36 and 33 %, respectively. The results indicate that shortly after N application elevated CO2 must have stimulated both the N2O production and reduction to N2 to explain the increased N2-to-N2O ratio and at the same time explain the non-responsiveness of the N2O emissions. Thus, the observed variation of the CO2 effect on N2O emissions throughout the year is possibly governed by the dynamics of the N2O reductase activity.
Source apportionment of the carbonaceous aerosol in Norway – quantitative estimates based on 14C, thermal-optical and organic tracer analysis
Authors: Yttri K. E. , Simpson D. , Stenström K. , Puxbaum H. , Svendby T.
Published: September 2011

Abstract. In the present study, source apportionment of the ambient summer and winter time particulate carbonaceous matter (PCM) in aerosol particles (PM1 and PM10) has been conducted for the Norwegian urban and rural background environment. Statistical treatment of data from thermal-optical, 14C and organic tracer analysis using Latin Hypercube Sampling has allowed for quantitative estimates of seven different sources contributing to the ambient carbonaceous aerosol. These are: elemental carbon from combustion of biomass (ECbb) and fossil fuel (ECff), primary and secondary organic carbon arising from combustion of biomass (OCbb) and fossil fuel (OCff), primary biological aerosol particles (OCPBAP, which includes plant debris, OCpbc, and fungal spores, OCpbs), and secondary organic aerosol from biogenic precursors (OCBSOA). Our results show that emissions from natural sources were particularly abundant in summer, and with a more pronounced influence at the rural compared to the urban background site. 80% of total carbon (TCp, corrected for the positive artefact) in PM10 and ca. 70% of TCpin PM1 could be attributed to natural sources at the rural background site in summer. Natural sources account for about 50% of TCp in PM10 at the urban background site as well. The natural source contribution was always dominated by OCBSOA, regardless of season, site and size fraction. During winter anthropogenic sources totally dominated the carbonaceous aerosol (80–90%). Combustion of biomass contributed slightly more than fossil-fuel sources in winter, whereas emissions from fossil-fuel sources were more abundant in summer. Mass closure calculations show that PCM made significant contributions to the mass concentration of the ambient PM regardless of size fraction, season, and site. A larger fraction of PM1 (ca. 40–60%) was accounted for by carbonaceous matter compared to PM10 (ca. 40–50%), but only by a small margin. In general, there were no pronounced differences in the relative contribution of carbonaceous matter to PM with respect to season or between the two sites.
Tight coupling of particle size and composition in atmospheric cloud droplet activation
Authors: Topping D. , McFiggans G.
Published: September 2011

Abstract. The substantial uncertainty in the indirect effect on radiative forcing in large part arises from the influences of atmospheric aerosol particles on (i) the brightness of clouds, exerting significant shortwave cooling with no appreciable compensation in the longwave, and on (ii) their ability to precipitate, with implications for cloud cover and lifetime. Predicting the ambient conditions at which aerosol particles may become cloud droplets is largely reliant on an equilibrium relationship derived in 1936. However, the theoretical basis of the relationship restricts its application to particles solely comprising involatile compounds and water, whereas a substantial fraction of particles in the real atmosphere will contain potentially thousands of semi-volatile organic compounds in addition to containing semi-volatile inorganic components such as ammonium nitrate. We show that equilibration of atmospherically reasonable concentrations of organic compounds with a growing particle as the ambient humidity increases has larger implications on cloud droplet formation than any other equilibrium compositional dependence, owing to inextricable linkage between the aerosol composition and a particles size under ambient conditions. Whilst previous attempts to account for co-condensation of gases other than water vapour have been restricted to one inorganic condensate, our method demonstrates that accounting for the co-condensation of any number of organic compounds substantially decreases the saturation ratio of water vapour required for droplet activation. This effect is far greater than any other compositional dependence; moreso even than the unphysical effect of surface tension reduction in aqueous organic mixtures, ignoring differences in bulk and surface surfactant concentrations.
Aerosol simulation applying high resolution anthropogenic emissions with the EMAC chemistry-climate model
Authors: Pozzer A. , de Meij A. , Pringle K. J. , Tost H. , Doering U. M. , van Aardenne J. , Lelieveld J.
Published: September 2011

Abstract. The new high resolution global anthropogenic emission inventory (EDGAR-CIRCE) of gas and aerosol pollutants has been incorporated in the chemistry general circulation model EMAC (ECHAM5/MESSy Atmospheric Chemistry). A high horizontal resolution simulation is performed for the years 2005–2008 to evaluate the capability of the model and the emissions to reproduce observed aerosol concentrations and aerosol optical depth (AOD) values. Model output is compared with observations from different measurement networks (CASTNET, EMEP and EANET) and AODs from remote sensing instruments (MODIS and MISR). The model reproduces the main spatial and temporal atmospheric features of the sulfate, ammonium and nitrate aerosol distributions. A good spatial agreement of the distribution of sulfate and ammonium aerosol is found when compared to observations, while calculated nitrate aerosol concentrations show some discrepancies. The simulated temporal development of the inorganic aerosols is in line with measurements of sulfate and nitrate aerosol, while for ammonium aerosol some deviations from observations occur over the USA. The calculated AODs agree well with the satellite observations in most regions, while a negative bias is found for the equatorial area and in the dust outflow regions (i.e. Central Atlantic and Northern Indian Ocean), due to an underestimation of biomass burning and aeolian dust emissions, respectively.
Characterization of ions at Alpine waterfalls
Authors: Kolarž P. , Gaisberger M. , Madl P. , Hofmann W. , Ritter M. , Hartl A.
Published: September 2011

Abstract. During a three-year field campaign of measuring waterfall generated ions, we monitored five different waterfalls in the Austrian Alps. Most measurements were performed at the Krimml waterfall (Salzburg), which is the biggest and most visited one in Europe and the Gartl waterfall (Mölltal, Carinthia). Smallest ion sizes (0.9–2 nm) were measured with a cylindrical air ion detector (CDI-06) while ion sizes from 5.5 to 350 nm were measured using a modified Grimm SMPS aerosol spectrometer. Measurements showed high negative ion gradients nearby waterfalls whereas positive ions showed only a moderate increase. The most abundant sizes of nano-sized and sub-micrometer ions measured were at 2 nm and of the larger and heavier ones at 120 nm.
Sensitivity of Dobson and Brewer Umkehr ozone profile retrievals to ozone cross-sections and stray light effects
Authors: Petropavlovskikh I. , Evans R. , McConville G. , Oltmans S. , Quincy D. , Lantz K. , Disterhoft P. , Stanek M. , Flynn L.
Published: September 2011

Abstract. Remote sounding methods are used to derive ozone profile and column information from various ground-based and satellite measurements. Vertical ozone profiles measured in Dobson units (DU) are currently retrieved based on laboratory measurements of the ozone absorption cross-section spectrum between 270 and 400 nm published in 1985 by Bass and Paur (BP). Recently, the US National Aeronautics and Space Administration (NASA) and the European Space Agency (ESA) proposed using the set of ozone cross-section measurements made at the Daumont laboratory in 1992 (BDM) for revising the Aura Ozone Monitoring Instrument (OMI) and Global Ozone Monitoring Experiment (GOME) satellite ozone profiles and total ozone column retrievals. Dobson Umkehr zenith sky data have been collected by NOAA ground-based stations at Boulder, CO (BDR) and Mauna Loa Observatory, HI (MLO) since the 1980s. The UMK04 algorithm is based on the BP ozone cross-section data. It is currently used for all Dobson Umkehr data processing submitted to the World Ozone and Ultraviolet radiation Data Centre (WOUDC) under the Global Atmosphere Watch (GAW) program of the World Meteorological Organization (WMO). Ozone profiles are also retrieved from measurements by the Mark IV Brewers operated by the NOAA-EPA Brewer Spectrophotometer UV and Ozone Network (NEUBrew) using a modified UMK04 algorithm (O3BUmkehr v.2.6, Martin Stanek). This paper describes the sensitivity of the Umkehr retrievals with respect to the proposed ozone cross-section changes. It is found that the ozone cross-section choice only minimally (within the retrieval accuracy) affects the Dobson and the Brewer Umkehr retrievals. On the other hand, significantly larger errors were found in the MLO and Boulder Umkehr ozone data (−8 and +5% bias in stratosphere and troposphere respectively) when the out-of-band (OOB) stray light contribution to the Umkehr measurement is not taken into account (correction is currently not included in the UMK04). The vertical distribution of OOB effect in the retrieved profile can be related to the local ozone climatology, instrument degradation, and optical characteristics of the instrument. Nonetheless, recurring OOB errors do not contribute to the long-term ozone trends.
Non-lethal effects of ocean acidification on two symbiont-bearing benthic foraminiferal species
Authors: McIntyre-Wressnig A. , Bernhard J. M. , McCorkle D. C. , Hallock P.
Published: September 2011

Abstract. We conducted experiments to assess the effect of elevated atmospheric carbon dioxide concentrations on survival, fitness, shell microfabric and growth of two species of symbiont-bearing coral-reef benthic foraminifera, using pCO2 Ievels similar to those likely to occur in shallow marine pore waters in the decades ahead. Foraminifera were cultured at constant temperature and controlled pCO2 (385 ppmv, 1000 ppmv, and 2000 ppmv) for six weeks, and total alkalinity and dissolved inorganic carbon were measured to characterize the carbonate chemistry of the incubations. Foraminiferal survival and cellular energy levels were assessed using Adenosine Triphosphate (ATP) analyses, and test microstructure and growth were evaluated using high resolution SEM and image analysis. Fitness and survival of Amphistegina (A.) gibbosa and Archaias (A.) angulatus were not directly affected by elevated pCO2 and the concomitant decrease in pH and calcite saturation states (Ωc values) of the seawater (pH and Ωc values of 8.12, 7.86, and 7.50, and 5.4, 3.4, and 1.5, for control, 1000 ppmv, and 2000 ppmv, respectively). In A. gibbosa, a species precipitating low-Mg calcite, test growth was not affected by elevated pCO2, but areas of dissolved calcium carbonate were observed even though Ωc was >1 in all treatments; the fraction of test area dissolved increased with decreasing Ωc. Similar dissolution was observed in offspring produced in the 2000 ppmv pCO2 treatments. In A. angulatus, whose tests are more-solubile high-Mg calcite, growth was greatly diminished in the 2000 ppmv pCO2 treatment compared to the control. These non-lethal effects of ocean acidification – reduced growth in A. angulatus, and enhanced dissolution in A. gibbosa – may reflect differences in test mineralogy for the two species; the long-term ecological consequences of these effects are not yet known.
Towards reconstruction of the flow duration curve: development of a conceptual framework with a physical basis
Authors: Yokoo Y. , Sivapalan M.
Published: September 2011

Abstract. In this paper we investigate the climatic and landscape controls on the flow duration curve (FDC) with the use of a physically-based rainfall-runoff model. The FDC is a stochastic representation of the variability of runoff, which arises from the transformation, by the catchment, of within-year variability of precipitation that can itself be characterized by a corresponding duration curve for precipitation (PDC). Numerical simulations are carried out with the rainfall-runoff model under a variety of combinations of climatic inputs (i.e. precipitation, potential evaporation, including their within-year variability) and landscape properties (i.e. soil type and depth). The simulations indicated that the FDC can be disaggregated into two components, with sharply differing characteristics and origins: the FDC for surface (fast) runoff (SFDC) and the FDC for subsurface (slow) runoff (SSFDC), which included base flow in our analysis. SFDC closely tracked PDC and can be approximated with the use of a simple, nonlinear (threshold) filter model. On the other hand, SSFDC tracked the FDC that is constructed from the regime curve (i.e. mean monthly runoff), which can be closely approximated by a linear filter model. Sensitivity analyses were carried out to understand the climate and landscape controls on each component, gaining useful physical insights into their respective shapes. In particular the results suggested that evaporation from dynamic saturated areas, especially in the dry season, can contribute to a sharp dip at the lower tail of the FDCs. Based on these results, we develop a conceptual framework for the reconstruction of FDCs in ungauged basins. This framework partitions the FDC into: (1) a fast flow component, governed by a filtered version of PDC, (2) a slow flow component governed by the regime curve, and (3) a correction to SSFDC to capture the effects of high evapotranspiration (ET) at low flows.
Assessment of Circadian and Light‐Entrainable Parameters in Mice Using Wheel‐Running Activity
Authors: Banks Gareth T. , Nolan Patrick M.
Published: September 2011

In most organisms, physiological variables are regulated by an internal clock. This endogenous circadian (∼24‐hr) clock enables organisms to anticipate daily environmental changes and modify behavioral and physiological functions appropriately. Processes regulated by the circadian clock include sleep‐wake and locomotor activity, core body temperature, metabolism, water/food intake, and available hormone levels. At the core of the mammalian circadian system are molecular oscillations within the hypothalamic suprachiasmatic nucleus. These oscillations are modifiable by signals from the environment (so called zeitgebers or time‐givers) and, once integrated within the suprachiasmatic nucleus, are conveyed to remote neural circuits where output rhythms are regulated. Disrupting any of a number of neural processes can affect how rhythms are generated and relayed to the periphery and disturbances in circadian/entrainment parameters are associated with numerous human conditions. These non‐invasive protocols can be used to determine whether circadian/entrainment parameters are affected in mouse mutants or treatment groups. Curr. Protoc. Mouse Biol. 1:369‐381 © 2011 by John Wiley & Sons, Inc.
Controlled Fabrication of PbS Quantum‐Dot/Carbon‐Nanotube Nanoarchitecture and its Significant Contribution to Near‐Infrared Photon‐to‐Current Conversion
Authors: Wang Defa , Baral Jayanta K , Zhao Haiguang , Gonfa Belete Atomsa , Truong Vo‐Van , El Khakani My Ali , Izquierdo Ricardo , Ma Dongling
Published: September 2011

A solution‐processed nanoarchitecture based on PbS quantum dots (QDs) and multi‐walled carbon nanotubes (MWCNTs) is synthesized by simply mixing the pre‐synthesized high‐quality PbS QDs and oleylamine (OLA) pre‐functionalized MWCNTs. Pre‐functionalization of MWCNTs with OLA is crucial for the attachment of PbS QDs and the coverage of QDs on the surface of MWCNTs can be tuned by varying the ratio of PbS QDs to MWCNTs. The apparent photoluminescence (steady‐state emission and fluorescence lifetime) “quenching” effect indicates efficient charge transfer from photo‐excited PbS QDs to MWCNTs. The as‐synthesized PbS‐QD/MWCNT nanoarchitecture is further incorporated into a hole‐conducting polymer poly(3‐hexylthiophene)‐(P3HT), forming the P3HT:PbS‐QD/MWCNT nanohybrid, in which the PbS QDs act as a light harvester for absorbing irradiation over a wide wavelength range of the solar spectrum up to near infrared (NIR, ≈1430 nm) range; whereas, the one‐dimensional MWCNTs and P3HT are used to collect and transport photoexcited electrons and holes to the cathode and anode, respectively. Even without performing the often required “ligand exchange” to remove the long‐chained OLA ligands, the built nanohybrid photovoltaic (PV) device exhibits a largely enhanced power conversion efficiency (PCE) of 3.03% as compared to 2.57% for the standard bulk hetero‐junction PV cell made with P3HT and [6,6]‐Phenyl‐C61‐Butyric Acid Methyl Ester (PCBM) mixtures. The improved performance of P3HT:PbS‐QD/MWCNT nanohybrid PV device is attributed to the significantly extended absorption up to NIR by PbS QDs as well as the effectively enhanced charge separation and transportation due to the integrated MWCNTs and P3HT. Our research results suggest that properly integrating QDs, MWCNTs, and polymers into nanohybrid structures is a promising approach for the development of highly efficient PV devices.
A Highly Order‐Structured Membrane Electrode Assembly with Vertically Aligned Carbon Nanotubes for Ultra‐Low Pt Loading PEM Fuel Cells
Authors: Tian Zhi Qun , Lim San Hua , Poh Chee Kok , Tang Zhe , Xia Zetao , Luo Zhiqiang , Shen Pei Kang , Chua Daniel , Feng Yuan Ping , Shen Zexiang , Lin Jianyi
Published: September 2011

A simple method was developed to prepare ultra‐low Pt loading membrane electrode assembly (MEA) using vertically aligned carbon nanotubes (VACNTs) as highly ordered catalyst support for PEM fuel cells application. In the method, VACNTs were directly grown on the cheap household aluminum foil by plasma enhanced chemical vapor deposition (PECVD), using Fe/Co bimetallic catalyst. By depositing a Pt thin layer on VACNTs/Al and subsequent hot pressing, Pt/VACNTs can be 100% transferred from Al foil onto polymer electrolyte membrane for the fabrication of MEA. The whole transfer process does not need any chemical removal and destroy membrane. The PEM fuel cell with the MEA fabricated using this method showed an excellent performance with ultra‐low Pt loading down to 35 μg cm−2which was comparable to that of the commercial Pt catalyst on carbon powder with 400 μg cm−2. To the best of our knowledge, for the first time, we identified that it is possible to substantially reduce the Pt loading one order by application of order‐structured electrode based on VACNTs as Pt catalysts support, compared with the traditional random electrode at a comparable performance through experimental and mathematical methods.
Assessing the effects of cognitive experiments on the welfare of captive chimpanzees (Pan troglodytes) by direct comparison of activity budget between wild and captive chimpanzees
Authors: Yamanashi Yumi , Hayashi Misato
Published: September 2011

We investigated the effects of cognitive experiments by direct comparison of activity budgets between wild and captive chimpanzees. One goal of captive management is to ensure that the activity budgets of captive animals are as similar as possible to those of their wild counterparts. However, such similarity has rarely been achieved. We compared the activity budget among three groups of chimpanzees: wild chimpanzees in Bossou (Guinea, n = 10), and captive chimpanzees who participated in cognitive experiments (experimental chimpanzees, n = 6) or did not participate in the experiments (nonexperimental chimpanzees, n = 6) at the Primate Research Institute (Japan). The experimental chimpanzees voluntarily participated in computer‐controlled cognitive tasks and small pieces of fruits were provided as rewards. The data from captivity were obtained on the experimental days (weekdays) and nonexperimental days (weekends). In both study sites, we followed each chimpanzee from about 7 a.m. until the time when chimpanzees started to rest in the evening. The behaviors were recorded every 1 min. The results showed that on weekdays, feeding time and resting time of the experimental chimpanzees were almost the same as those of wild chimpanzees. However, for the nonexperimental chimpanzees, feeding time was significantly shorter and resting time was longer than those of the wild chimpanzees. In contrast, no difference was found in feeding time or resting time of the two groups of captive chimpanzees on weekends. The results suggested that the cognitive experiments worked as an efficient method for food‐based enrichment. Am. J. Primatol. 73:1231–1238, 2011. © 2011 Wiley Periodicals, Inc.
Sex differences in the stone tool‐use behavior of a wild population of burmese long‐tailed macaques (Macaca fascicularis aurea)
Authors: Gumert Michael D. , Hoong Low Kuan , Malaivijitnond Suchinda
Published: September 2011

We investigated sex differences in how Burmese long‐tailed macaques (Macaca fascicularis aurea) used stone tools to open shelled food items along the shores of two islands in Laemson National Park, Thailand. Over a 2‐week period in December 2009, we collected scan and focal samples on macaques when they were visible along the shores and mangroves. We found females used stones more often while feeding and used smaller tools than males. Females also processed sessile oysters more than males, whereas males processed unattached foods more than females. It was unclear which sex was overall more proficient at stone tool use, but males did perform significantly better at opening unattached food items with large pounding stones. Females also struck food items more times during tool‐use bouts and at a faster rate, but no significant difference was found in average tool‐use bout duration. Males processed foods slightly faster within a tool‐use bout, but we were unable to detect a significant difference in the rate of food processing while foraging with tools. In summary females chipped open sessile oysters with an axing technique more than males, while males used larger stones to pound open unattached shelled food more often than females. Despite using pounding more than females, males also regularly utilized the axing technique on sessile oysters. Our results are the first assessment of sex differences in macaque stone tool use, providing a basis for comparison with tool use in other primates, and to nonfunctional forms of stone use in other macaques. Am. J. Primatol. 73:1239–1249, 2011. © 2011 Wiley Periodicals, Inc.