bluuebunny/crossref_metadata_2025 huggingface dataset:
Laser Diode Pumped Polymer Lasers with Tunable Emission Based on Microfluidic Channels
Authors: Niu Ben , Ge Kun , Xu Zhiyang , Shi Xiaoyu , Guo Dan , Zhai Tianrui
Published: October 2021

Tunable whispering-gallery-mode (WGM) lasers have been paid lots of attention for their potential applications in the photonic field. Here, a tunable polymer WGM laser based on laser diode pumping is realized with a threshold of 0.43 MW/cm2 per pulse. The WGM laser is realized by a microfluidic microcavity, which consists of a quartz capillary and gain materials. The laser performance keeps stable for a long time (3.5 h), pumped by a 50-ns 50 Hz laser diode with a pumping peak power density of 1.08 MW/cm2 per pulse. The lasing wavelength can be tuned over 15 nm by changing the gain material concentration from 3.5 mg/mL to 12.5 mg/mL in the microfluidic channel. Moreover, the lasing mode can be switched between transverse magnetic (TM) and transverse electric (TE) modes by adjusting the pump polarization. These results provide the basis for designing nanophotonic devices with laser diode pumping.
Enhanced Dissolution of Sildenafil Citrate Using Solid Dispersion with Hydrophilic Polymers: Physicochemical Characterization and In Vivo Sexual Behavior Studies in Male Rats
Authors: Aldawsari Mohammed F. , Anwer Md. Khalid , Ahmed Mohammed Muqtader , Fatima Farhat , Soliman Gamal A. , Bhatia Saurabh , Zafar Ameeduzzafar , Aboudzadeh M. Ali
Published: October 2021

Sildenafil citrate (SLC) is a frequently used medication (Viagra®) for the treatment of erectile dysfunction (ED). Due to its poor solubility, SLC suffers from a delayed onset of action and poor bioavailability. Hence, the aim of the proposed work was to prepare and evaluate solid dispersions (SDs) with hydrophilic polymers (Kolliphor® P188, Kollidon® 30, and Kollidon®-VA64), in order to enhance the dissolution and efficacy of SLC. The SLC-SDs were prepared using a solvent evaporation method (at the ratio drug/polymer, 1:1, w/w) and characterized by Differential Scanning Calorimetry (DSC), Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), Scanning electron microscope (SEM), drug content, yield, and in vitro release studies. Based on this evaluation, SDs (SLC-KVA64) were optimized, with a maximum release of drug (99.74%) after 2 h for all the developed formulas. The SDs (SLC-KVA64) were further tested for sexual behavior activity in male rats, and significant enhancements in copulatory efficiency (81.6%) and inter-copulatory efficiency (44.9%) were noted in comparison to the pure SLC drug, when exposed to the optimized SLC-KVA64 formulae. Therefore, SD using Kollidon®-VA64 could be regarded as a potential strategy for improving the solubility, in vitro dissolution, and therapeutic efficacy of SLC.
Mechanical Properties of PolyJet 3D-Printed Composites Inspired by Space-Filling Peano Curves
Authors: Wu Changlang , Do Truong Tho , Tran Phuong
Published: October 2021

This paper proposes a design of novel composite materials inspired by the Peano curve and manufactured using PolyJet 3D printing technology with Agilus30 (flexible phase) and VeroMagentaV (rigid phase) materials. Mechanical properties were evaluated through tensile and compression tests. The general rule of mixture (ROM) for composites was employed to approximate the tensile properties of the hybrid materials and compare them to the experimental results. The effect of reinforcement alignments and different hierarchies are discussed. The results indicated that the 5% inclusion of the Peano reinforcement in tensile samples contributed to the improvement in the elastic modulus by up to 6 MPa, but provided no obvious enhancement in ultimate tensile strength. Additionally, compressive strengths between 2 MPa and 6 MPa were observed for compression cubes with first-order reinforcement, while lower values around 2 MPa were found for samples with second-order reinforcement. That is to say, the first-order reinforcement has been demonstrated more effectively than the second-order reinforcement, given the same reinforcement volume fraction of 10% in compression cubes. Different second-order designs exhibited slightly different mechanical properties based on the ratio of reinforcement parallel to the loading direction.
First-Principle Study on p-n Control of PEDOT-Based Thermoelectric Materials by PTSA Doping
Authors: Arimatsu Hideki , Osada Yuki , Takagi Ryo , Fujima Takuya
Published: October 2021

PEDOT:Tos, a PSS-free PEDOT-based material, is a promising possible organic thermoelectric material for a practical conversion module because the material reportedly has a large power factor. However, since PEDOT:Tos is mainly reported to be a p-type thermoelectric material, the development of PSS-free PEDOT with n-type thermoelectric properties is desirable. Thus, in order to search for PSS-free PEDOT with n-type thermoelectric properties, we investigated the doping concentration of PTSA dependence of the thermoelectric property using the first-principle calculation. The band structure and the density of state indicated that the n-type thermal electromotive force was attributed to the electrons’ large effective mass. Such electrons were produced thanks to the binding of the dopant PTSA to the benzene ring. The contribution of the electron to the Seebeck coefficient increased with increasing PTSA doping concentrations.
The Effect of Different Soft Core/Hard Shell Ratios on the Coating Performance of Acrylic Copolymer Latexes
Authors: Cheaburu-Yilmaz Catalina , Yilmaz Onur , Darie-Nita Raluca
Published: October 2021

Core–shell acrylic copolymer latexes containing bio resourced itaconic acid with different compositions in respect with the core and shell segments were synthesized, characterized, and applied as coating materials for leather. The purpose of the study was to evidence the high coating performance of the latexes when the ratio of the core/shell differed from 90/10 to 50/50 wt %. The copolymers were prepared via emulsion copolymerization technique and the products were isolated and characterized by means of structure identity, thermal behavior (DSC and DMTA), coating performance. The particle size of the latexes varied from 83 to 173 nm with the variation of the ratio of core/shell segments. The influence of the composition of soft part and hard part was highlighted in the thermal and coating properties. The optimal composition giving the best coating performance could be determined as DS 60/40. Further increase of the hard segment content, resulted in decreased emulsion stability and the coating performance on the leathers. The use of itaconic acid seemed to increase the emulsion stability as well the adhesion of the latexes to the substrate.
Upconversion Nanoparticles Encapsulated with Molecularly Imprinted Amphiphilic Copolymer as a Fluorescent Probe for Specific Biorecognition
Authors: Chien Hsiu-Wen , Yang Chien-Hsin , Shih Yan-Tai , Wang Tzong-Liu
Published: October 2021

A fluorescent probe for specific biorecognition was prepared by a facile method in which amphiphilic random copolymers were encapsulated with hydrophobic upconversion nanoparticles (UCNPs). This method quickly converted the hydrophobic UCNPs to hydrophilic UNCPs. Moreover, the self-folding ability of the amphiphilic copolymers allowed the formation of molecular imprinting polymers with template-shaped cavities. LiYF4:Yb3+/Tm3+@LiYF4:Yb3+ UCNP with up-conversion emission in the visible light region was prepared; this step was followed by the synthesis of an amphiphilic random copolymer, poly(methacrylate acid-co-octadecene) (poly(MAA-co-OD)). Combining the UCNPs and poly(MAA-co-OD) with the templates afforded a micelle-like structure. After removing the templates, UCNPs encapsulated with the molecularly imprinted polymer (MIP) (UCNPs@MIP) were obtained. The adsorption capacities of UCNPs@MIP bound with albumin and hemoglobin, respectively, were compared. The results showed that albumin was more easily bound to UCNPs@MIP than to hemoglobin because of the effect of protein conformation. The feasibility of using UCNPs@MIP as a fluorescent probe was also studied. The results showed that the fluorescence was quenched when hemoglobin was adsorbed on UCNPs@MIP; however, this was not observed for albumin. This fluorescence quenching is attributed to Förster resonance energy transfer (FRET) and overlap of the absorption spectrum of hemoglobin with the fluorescence spectrum of UCNPs@MIP. To our knowledge, the encapsulation approach for fabricating the UCNPs@MIP nanocomposite, which was further used as a fluorescent probe, might be the first report on specific biorecognition.
Biobased Waterborne Polyurethane-Ureas Modified with POSS-OH for Fluorine-Free Hydrophobic Textile Coatings
Authors: Lacruz Amado , Salvador Mireia , Blanco Miren , Vidal Karmele , Goitandia Amaia M. , Martinková Lenka , Kyselka Martin , de Ilarduya Antxon Martínez
Published: October 2021

Waterborne polyurethane-urea dispersions (WPUD), which are based on fully biobased amorphous polyester polyol and isophorone diisocyanate (IPDI), have been successfully synthesized obtaining a finishing agent that provides textiles with an enhanced hydrophobicity and water column. Grafting of trans-cyclohexanediol isobutyl POSS (POSS-OH) to the biobased polymer backbone has also been investigated for the first time and its properties compared to a standard chain extender, 1,3-propanediol (PDO). The chemical structure of WPUD has been characterized by Fourier-transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (NMR). The thermal properties have been evaluated by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). Mechanical properties have been studied by tensile stress–strain analysis. Moreover, the particle size, particle size distribution (PSD), and stability of developed waterborne dispersions have been assessed by dynamic light scattering (DLS), Z-potential, storage aging tests, and accelerated aging tests by analytical centrifuge (LUM). Subsequently, selected fabrics have been face-coated by the WPUD using the knife coating method and their properties have been assessed by measuring the water contact angle (WCA), oil contact angle (OCA), water column, fabric stiffness, air permeability, and water vapor resistance (breathability). Finally, the surface morphology and elemental composition of uncoated and coated fabrics have been studied by scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS), respectively. All of the synthesized polyurethane-ureas provided the coated substrates with a remarkable hydrophobicity and water column, resulting in a more sustainable alternative to waterproof coatings based on fluoropolymers, such as PTFE. Grafting POSS-OH to the polymeric backbone has led to textile coatings with enhanced hydrophobicity, maintaining thermal, mechanical, and water column properties, giving rise to multifunctional coatings that are highly demanded in protective workwear and technical textiles.
Using Chitosan or Chitosan Derivatives in Cancer Therapy
Authors: Shakil Md Salman , Mahmud Kazi Mustafa , Sayem Mohammad , Niloy Mahruba Sultana , Halder Sajal Kumar , Hossen Md. Sakib , Uddin Md. Forhad , Hasan Md. Ashraful
Published: October 2021

Cancer is one of the major causes of death worldwide. Chemotherapeutic drugs have become a popular choice as anticancer agents. Despite the therapeutic benefits of chemotherapeutic drugs, patients often experience side effects and drug resistance. Biopolymers could be used to overcome some of the limitations of chemotherapeutic drugs, as well as be used either as anticancer agents or drug delivery vehicles. Chitosan is a biocompatible polymer derived from chitin. Chitosan, chitosan derivatives, or chitosan nanoparticles have shown their promise as an anticancer agent. Additionally, functionally modified chitosan can be used to deliver nucleic acids, chemotherapeutic drugs, and anticancer agents. More importantly, chitosan-based drug delivery systems improved the efficacy, potency, cytotoxicity, or biocompatibility of these anticancer agents. In this review, we will investigate the properties of chitosan and chemically tuned chitosan derivatives, and their application in cancer therapy.
Chrono::GPU: An Open-Source Simulation Package for Granular Dynamics Using the Discrete Element Method
Authors: Fang Luning , Zhang Ruochun , Vanden Heuvel Colin , Serban Radu , Negrut Dan
Published: October 2021

We report on an open-source, publicly available C++ software module called Chrono::GPU, which uses the Discrete Element Method (DEM) to simulate large granular systems on Graphics Processing Unit (GPU) cards. The solver supports the integration of granular material with geometries defined by triangle meshes, as well as co-simulation with the multi-physics simulation engine Chrono. Chrono::GPU adopts a smooth contact formulation and implements various common contact force models, such as the Hertzian model for normal force and the Mindlin friction force model, which takes into account the history of tangential displacement, rolling frictional torques, and cohesion. We report on the code structure and highlight its use of mixed data types for reducing the memory footprint and increasing simulation speed. We discuss several validation tests (wave propagation, rotating drum, direct shear test, crater test) that compare the simulation results against experimental data or results reported in the literature. In another benchmark test, we demonstrate linear scaling with a problem size up to the GPU memory capacity; specifically, for systems with 130 million DEM elements. The simulation infrastructure is demonstrated in conjunction with simulations of the NASA Curiosity rover, which is currently active on Mars.
Experimental Study on the Fire Resistance Performance of Partition Board under the Condition of Small Fire Source
Authors: Gao Butong , Wei Shanyang , Du Wei , Yang Huan , Chu Yunyun
Published: October 2021

Fire safety of ancient wooden buildings is one of the most important issues in the world. In this paper, partition boards with different thicknesses from 15 to 25 mm were heated by a 15-cm-diameter pool fire and a methane Bunsen burner. The temperatures and the carbonization rate of partition boards were measured and analyzed. The results show that when a pool fire was used to heat the wood sample at a distance of 30 cm, two flames appear on the sample surface. When a Bunsen burner heats the sample, the sample is burned until the center point is burned through. The thickness of the sample is increased by 5 mm, and the acceleration time of the temperature rise rate at the center is doubled. Under the condition of a pool fire, the thickness of the sample is increased by 5 mm, and the average carbonization rate at the center point is reduced by 40%. Under the condition of Bunsen burner, the average carbonization rate of the center point decreases exponentially when the thickness of the sample increases by 5 mm. In the case of the same fire source, the carbonization rate of the samples with different thicknesses has the same change trend in the horizontal and vertical directions. Compared with the pool fire, the burn-through time of the center point of the sample is reduced in the case of the Bunsen burner for a sample of the same thickness, and the average carbonization rate of each measuring point increases.
Recycling Thermal Insulation Materials: A Case Study on More Circular Management of Expanded Polystyrene and Stonewool in Switzerland and Research Agenda
Authors: Superti Valeria , Forman Tim V. , Houmani Cynthia
Published: October 2021

The limits to linear models of production based on material extraction, manufacture, use, and disposal are becoming increasingly apparent across the global economy. The Circular Economy (CE) describes an alternative to this problematic “take-make-waste” linear model that is concerned with resource efficiency and waste minimization. The construction and demolition sector represents an important focus for a CE transition due to its significant environmental impact. The use of thermal insulation to reduce energy demand associated with heating and cooling in buildings is vital for reducing the sector’s high environmental impact; however, there are significant challenges to recycling thermal insulation materials (IM). This study examines these challenges in the context of Switzerland and evaluates the potential for more circular management of expanded polystyrene and stonewool IM. The research provides an original analysis of the Swiss IM value chain in the context of the CE agenda based on a literature review, semi-structured interviews, and a workshop. Research gaps are highlighted based on scientific literature. The roles and agency of actors involved in the Swiss IM value chain are examined. Enablers of and barriers to wider IM recycling as reported by workshop participants are outlined. Interventions for tackling the current challenges faced for the recycling of thermal IM are suggested. Finally, an agenda for future research is proposed. Throughout the discussion, the importance of the involvement, commitment, and collaboration of stakeholders across the entire IM value chain for an effective and expedient transition to a CE is highlighted.
On the Use of Tri-Stereo Pleiades Images for the Morphometric Measurement of Dolines in the Basaltic Plateau of Azrou (Middle Atlas, Morocco)
Authors: Melis Maria Teresa , Pisani Luca , De Waele Jo
Published: October 2021

Hundreds of large and deep collapse dolines dot the surface of the Quaternary basaltic plateau of Azrou, in the Middle Atlas of Morocco. In the absence of detailed topographic maps, the morphometric study of such a large number of features requires the use of remote sensing techniques. We present the processing, extraction, and validation of depth measurements of 89 dolines using tri-stereo Pleiades images acquired in 2018–2019 (the European Space Agency (ESA) © CNES 2018, distributed by Airbus DS). Satellite image-derived DEMs were field-verified using traditional mapping techniques, which showed a very good agreement between field and remote sensing measures. The high resolution of these tri-stereo images allowed to automatically generate accurate morphometric datasets not only regarding the planimetric parameters of the dolines (diameters, contours, orientation of long axes), but also for what concerns their depth and altimetric profiles. Our study demonstrates the potential of using these types of images on rugged morphologies and for the measurement of steep depressions, where traditional remote sensing techniques may be hindered by shadow zones and blind portions. Tri-stereo images might also be suitable for the measurement of deep and steep depressions (skylights and collapses) on Martian and Lunar lava flows, suitable targets for future planetary cave exploration.
Detecting the Surface Signature of Riverine and Effluent Plumes along the Bulgarian Black Sea Coast Using Satellite Data
Authors: Gancheva Irina , Peneva Elisaveta , Slabakova Violeta
Published: October 2021

The clear and reliable detection of effluent plumes using satellite data is especially challenging. The surface signature of such events is of a small scale; it shows a complex interaction with the local environment and depends greatly on the effluent and marine water constitution. In the context of remote sensing techniques for detecting treated wastewater discharges, we study the surface signature of small river plumes, as they share specific characteristics, such as higher turbidity levels and increased nutrient concentration, and are fresh compared to the salty marine water. The Bulgarian Black Sea zone proves to be a challenging study area, with its optically complex waters and positive freshwater balance. Additionally, the Bulgarian Black Sea coast is a known tourist destination with an increased seasonal load; thus, the problem of the identification of wastewater discharges is a topical issue. In this study, we analyze the absorption components of the Inherent Optical Properties (IOPs) for 84 study points that are located at outfall discharging areas, river estuaries and at different distances from the shoreline, reaching the open sea area at a bottom depth of more than 2000 m. The calculations of IOPs take into account all available Sentinel 2 cloudless acquisitions for three years from 2017 until 2019 and are performed using the Case-2 Regional CoastColour (C2RCC) processor, implemented in the Sentinel Application Platform (SNAP). The predominant absorber for each study area and its temporal variation is determined, deriving the specific characteristics of the different areas and tracking their seasonal and annual course. Optical data from the Galata AERONET-OC site are used for validating the absorption coefficient of phytoplankton pigment. A conclusion regarding the possibility of distinguishing riverine, marine and coastal water is derived. The study provides a sound basis for estimating the advantages and drawbacks of optical satellite data for tracking the extent of effluent and fluvial plumes with unknown concentrations of optically significant seawater constituents.
RETRACTED: Li, J. Fault-Event Trees Based Probabilistic Safety Analysis of a Boiling Water Nuclear Reactor’s Core Meltdown and Minor Damage Frequencies. Safety 2020, 6, 28
Authors: Li Jinfeng
Published: October 2021

The author would like to retract the article, published on 17 June 2020, cited above [...]
From Information and Quantum Physics to Consciousness and Reality
Authors: Verheyen Peter
Published: October 2021

How does the world around us work and what is real? This question has preoccupied humanity since its beginnings. From the 16th century onwards, it has periodically been necessary to revise the prevailing worldview—but things became very strange at the beginning of the 20th century with the advent of relativity theory and quantum physics. The current focus is on the role of information, there being a debate about whether this is ontological or epistemological. A theory has recently been formulated in which spacetime and gravity emerges from microscopic quantum information—more specifically from quantum entanglement via entanglement entropy. A recent theory describes the emergence of reality itself through first-person perspective experiences and algorithmic information theory. In quantum physics, perception and observation play a central role. Perception of and interaction with the environment require an exchange of information. Via biochemical projection, information is given an interpretation that is necessary to make life and consciousness possible. The world around us is not at all what it seems.
Requirements and Architecture of a Cloud Based Insomnia Therapy and Diagnosis Platform: A Smart Cities Approach
Authors: Reichenpfader Daniel , Hanke Sten
Published: October 2021

Insomnia is the most common sleep disorder worldwide. Its effects generate economic costs in the millions but could be effectively reduced using digitally provisioned cognitive behavioural therapy. However, traditional acquisition and maintenance of the necessary technical infrastructure requires high financial and personnel expenses. Sleep analysis is still mostly done in artificial settings in clinical environments. Nevertheless, innovative IT infrastructure, such as mHealth and cloud service solutions for home monitoring, are available and allow context-aware service provision following the Smart Cities paradigm. This paper aims to conceptualise a digital, cloud-based platform with context-aware data storage that supports diagnosis and therapy of non-organic insomnia. In a first step, requirements needed for a remote diagnosis, therapy, and monitoring system are identified. Then, the software architecture is drafted based on the above mentioned requirements. Lastly, an implementation concept of the software architecture is proposed through selecting and combining eleven cloud computing services. This paper shows how treatment and diagnosis of a common medical issue could be supported effectively and cost-efficiently by utilising state-of-the-art technology. The paper demonstrates the relevance of context-aware data collection and disease understanding as well as the requirements regarding health service provision in a Smart Cities context. In contrast to existing systems, we provide a cloud-based and requirement-driven reference architecture. The applied methodology can be used for the development, design, and evaluation of other remote and context-aware diagnosis and therapy systems. Considerations of additional aspects regarding cost, methods for data analytics as well as general data security and safety are discussed.
Toward a Feminist Agroecology
Authors: Zaremba Haley , Elias Marlène , Rietveld Anne , Bergamini Nadia
Published: October 2021

Agroecology is gaining ground as a movement, science, and set of practices designed to advance a food systems transformation which subverts the patterns of farmer exploitation currently entrenched in dominant agricultural models. In order for agroecology to achieve its espoused twin aims of social and ecological wellbeing, women and other historically marginalized stakeholders must be empowered and centered as the movement’s protagonists. The importance of gender and social considerations is not limited to patently social aspects of the agroecological agenda, but bears relevance in every dimension of agroecology. Yet, issues related to gender have commanded relatively little attention in the agroeocological literature. In this paper, we review HLPE’s 13 defining principles of agroecology through a feminist lens to demonstrate the ways in which human dimensions and power dynamics are interwoven in every principle. Through this analysis, we demonstrate that a feminist approach is instrumental to establish a socially just and ecologically sustainable agroecological transition.
Towards a Single Integrative Metric on the Dynamics of Social-Environmental Systems
Authors: Chen Jiquan , John Ranjeet , Shao Changliang , Ouyang Zutao , Mack Elizabeth A. , Henebry Geoffrey M. , Dong Gang , Allington Ginger R. H. , Pearson Amber L. , Zhao Fangyuan , Roy David P. , Fan Peilei , Shirkey Gabriela E. , Tian Li , Kussainova Maira , Chen Jingyan , Reed David E. , Abraha Michael
Published: October 2021

Integrating the dynamics and interconnections of natural and human system properties into a single measure would make it simpler to reliably and repeatedly assess and compare different social-environmental systems (SES). We propose a novel metric to assess the magnitudes and variations in SES dynamics by integrating longitudinal gross domestic product, population, and ecosystem net primary production. We use annual public data across the Asian Drylands Belt (ADB) from 1992 through 2016 for 18 political entities as our testbed for assessing the efficacy of the metric. We perform cross-comparisons with existing natural and social science metrics to demonstrate the validity of the proposed metric, including the Human Development Index and the Palmer Drought Severity Index. The new metric demonstrates notable and meaningful differences in trends among the political entities that reflect major social, economic and environmental events over the 25-year period. It provides unique perspectives about the three pillar components (social, economic and environmental systems) in each of the 18 political entities (PE) of the ADB. The metric also shows meaningful associations with key economic and environmental indicators and great potential for broader application and evaluation, given additional testing in other countries, regions, and biomes.
Traffic Signal Control via Reinforcement Learning for Reducing Global Vehicle Emission
Authors: Kővári Bálint , Szőke Lászlo , Bécsi Tamás , Aradi Szilárd , Gáspár Péter
Published: October 2021

The traffic signal control problem is an extensively researched area providing different approaches, from classic methods to machine learning based ones. Different aspects can be considered to find an optima, from which this paper emphasises emission reduction. The core of our solution is a novel rewarding concept for deep reinforcement learning (DRL) which does not utilize any reward shaping, hence exposes new insights into the traffic signal control (TSC) problem. Despite the omission of the standard measures in the rewarding scheme, the proposed approach can outperform a modern actuated control method in classic performance measures such as waiting time and queue length. Moreover, the sustainability of the realized controls is also placed under investigation to evaluate their environmental impacts. Our results show that the proposed solution goes beyond the actuated control not just in the classic measures but in emission-related measures too.
An Empirical Study for Real Options of Water Management in the Three Gorges Reservoir Area
Authors: Lu Zuliang , Wu Xiankui , Cai Fei , Huang Fei
Published: October 2021

This paper investigates an empirical evaluation of water management on agricultural irrigation. To address this problem, a real options model was proposed. This model analysis the choice of investment in water savings. Also, the model discusses a linear complementary problem that can be transformed into the inequalities of parabolic variational. By using a power penalty method, we solved the parabolic variational inequalities. The results depicted that the nonlinear parabolic equations’ solution is converges to the rate of order O(h−k2). A numerical example is given at the end of the paper to demonstrate the theoretical analysis follows from the Three Gorges Reservoir Area.
A County Town in Ruins: Memories, Emotions, and Sense of Place in Post-Earthquake Beichuan, China
Authors: Qian Lili , Zheng Chunhui , Lai Qin , Guo Juncheng
Published: October 2021

Ruins serve as symbolic sites at which to re-examine people’s relationships with the past and bonds with places. In the context of the ruination caused by earthquakes and the displacement and resettlement of local residents post-disaster, this paper explores vernacular (residents’ and survivors’) memories, emotions, and senses of place triggered by the ruins of Beichuan county town, China. Results show vernacular memories of specific ruins were highly fragmented and multi-temporal. Interwoven before- and after-quake memories gave rise to complex emotions, mainly including traumatic feeling of sadness, fear, and painful nostalgia. The study further identifies people’s sense of place towards the ruined county town and finds that locals’ sense of place was not accompanied by the loss of physical dependence to the negative side; locals still expressed high levels of place identity (physical uniqueness, self-esteem, and meanings), place attachment (rootedness and emotional attachment), and positive consequences of place behaviours (protection intention and revisiting) post-earthquake. Moreover, it found that sociodemographic variables of age and length of residence in Beichuan and the variables of disaster loss had significant effect on people’s sense of place. This study balances the overriding focus on visual and representational concerns common in ruin scholarship and further reveals the complex psychological processes impacting on sense of place after large-scale disasters. The findings reflect on the relief practices of post-disaster planning and can serve to guide ruin preservation.
Cultural Sets Shape Adult Conceptualizations and Relationships to Nature
Authors: Tomasso Linda Powers , Cedeño Laurent Jose Guillermo , Chen Jarvis T. , Catalano Paul J. , Spengler John D.
Published: October 2021

The variability of nature and the nature construct have complicated interpretations of empirical evidence from nature-based health studies. The challenge of defining nature exposure for purposes of methodological standardization may encompass constructs beyond vegetated landcover. This study offers a new construct for defining ‘nature exposure’ that considers cultural sets and nature familiarity. Focus group discussions across the United States (N = 126) explored the concept of what constitutes the relationship to nature. The participant diversity included regions, cultural demographics, cumulative nature experience, and everyday nature exposure. Mixed methods of semi-structured discussion and a photo exercise that prompted nature connectedness allowed for data triangulation and the detection of contradictions between approaches. Individuals conceptualized nature in ways reflecting highly personal and differentiated experiences, which defied consensus toward a single nature construct. The group scoring of photo imagery showed consistent high and low levels of nature connectedness with respect to wildness and outdoor urban venues, respectively, but diverged in the assessment of nature within the built environment. Everyday nature exposure significantly differentiated how groups conceptualized and related to nature imagery. This result may indicate an unmet biophilic need among groups with low backgrounds of nature exposure. The contrasts between the discussion content and the observed reactions to nature imagery showed the value of using mixed methods in qualitative research.
Spatial Variation and Terrain Gradient Effect of Ecosystem Services in Heihe River Basin over the Past 20 Years
Authors: Zhang Lingge , Hu Ningke
Published: October 2021

With the advent of large-scale development, extreme imbalance in the ecology of the Heihe River Basin (HRB) has caused a series of ecological problems. In order to explore the spatiotemporal variation of ecosystem services (ESs) and to assess the characteristics of ESs under the terrain gradient effect (TGE), the three key ESs were quantified based on the InVEST model using five series of land-use data obtained from remote sensing images from 2000 to 2020 in this study. The terrain index was used to analyze the influence of terrain on ESs. The results show that most of the ESs were in high numbers in the south and low numbers in the north, as well as high numbers in the middle and upper reaches and low numbers at downstream locations. It was found that high-quality habitats degrade to general-quality habitats, and poor-quality habitats evolve into general-quality habitats. It was also found that the water production volume continues to decline and soil conservation becomes relatively stable with little change. This study illustrates different ESs showing obvious TGE with changes in elevation and slope. These results indicate that the effect of land-use change is remarkable and TGE is highly important to ESs in inland watersheds. This research study can provide a scientific basis for the optimization of regional ecosystem patterns. The results are of great significance in terms of rational planning land use, constructing ecological civilizations, and maintaining the physical conditions of land cover at inland river basins.
Lithium in the Green Energy Transition: The Quest for Both Sustainability and Security
Authors: Graham John D. , Rupp John A. , Brungard Eva
Published: October 2021

Considering the quest to meet both sustainable development and energy security goals, we explore the ramifications of explosive growth in the global demand for lithium to meet the needs for batteries in plug-in electric vehicles and grid-scale energy storage. We find that heavy dependence on lithium will create energy security risks because China has a dominant position in the lithium supply chain and both Europe and North America seek to curtail reliance on China throughout their supply chains. We also find that efforts to expand lithium mining have been much less successful in Chile, the United States, and Europe than in Australia. Local communities resist licensing of new lithium mines due to a variety of environmental, social, and economic concerns. There are alternative technologies that may make lithium mining more sustainable such as direct lithium extraction, but the timing of commercialization of this process is uncertain. Progress is also being made in battery recycling and in alternative battery designs that do not use lithium. Such advances are unlikely to attenuate the global rate of growth in lithium demand prior to 2030. We conclude that tradeoffs between sustainability and energy security are real, especially in the next decade.
Projected Impact of Climate Change on Habitat Suitability of a Vulnerable Endemic Vachellia negrii (pic.serm.) kyal. & Boatwr (Fabaceae) in Ethiopia
Authors: Semu Arayaselassie Abebe , Bekele Tamrat , Lulekal Ermias , Cariñanos Paloma , Nemomissa Sileshi
Published: October 2021

Species tend to shift their suitable habitat both altitudinally and latitudinally under climate change. Range shift in plants brings about habitat contraction at rear edges, forcing leading edge populations to explore newly available suitable habitats. In order to detect these scenarios, modeling of the future geographical distribution of the species is widely used. Vachellia negrii (Pic.-Serm.) Kyal. & Boatwr. is endemic to Ethiopia and was assessed as vulnerable due to changes to its habitat by anthropogenic impacts. It occurs in upland wooded grassland from 2000–3100 m.a.s.l. The main objective of this study is to model the distribution of Vachellia negrii in Ethiopia by using Maxent under climate change. Nineteen bioclimatic variables were downloaded from an open source. Furthermore, topographic position index (tpi), solar radiation index (sri) and elevation were used. Two representative concentration pathways were selected (RCP 4.5 and RC P8.5) for the years 2050 and 2070 using the Community Climate System Model (CCSM 5). A correlation analysis of the bioclimatic variables has resulted in the retention of 10 bioclimatic variables for modeling. Forty-eight occurrence points were collected from herbarium specimens. The area under curve (AUC) is 0.94, indicating a high-performance level of the model. The distribution of the species is affected by elevation (26.4%), precipitation of the driest month (Bio 14, 21.7%), solar radiation (12.9%) and precipitation seasonality (Bio15, 12.2%). Whereas the RCP 8.5 has resulted in decrease of suitable areas of the species from the current 4,314,153.94 ha (3.80%) to 4,059,150.90 ha (3.58%) in 2050, this area will shrink to 3,555,828.71 ha in 2070 under the same scenario. As climate change severely affects the environment, highly suitable areas for the growth of the study subject will decrease by 758,325 ha. The study’s results shows that this vulnerable, endemic species is facing habitat contraction and requires interventions to ensure its long-term persistence.
The Use of CO2 in the Production of Bioplastics for an Even Greener Chemistry
Authors: Fabien Drault , Snoussi Youssef , Itabaiana Ivaldo , Wojcieszak Robert
Published: October 2021

The high life expectancy of the world population provokes increase in demand for food and energy. As a result, the intense industrialization and the application of fossil sources is responsible for high levels of CO2 emission and waste generation. To mitigate the CO2 emission a practical solution at the very short term is urgently needed. The capture of CO2 and its application in chemical processes for the valorization of residual biomass are of great importance nowadays. The application of CO2 in the selective carboxylation of furoic acid for the production of 2,5-furandicarboxylic acid (FDCA), a bio-based monomer, has been an important step towards obtaining biopolymers to replace petroleum-based plastics such as polyethylene terephthalate (PET). In this project report, we discuss on the current challenges for obtaining the 2,5-FDCA precursor from the furfural in two main routes involving oxidation and carboxylation via heterogeneous catalysis. We present the main objectives and discuss the importance of this research for the development of more sustainable processes.
Impacts of COVID-19 on the Aquatic Environment and Implications on Aquatic Food Production
Authors: Yusoff Fatimah Md , Abdullah Ahmad Fikri , Aris Ahmad Zaharin , Umi Wahidah Ahmad Dini
Published: October 2021

The COVID-19 pandemic, caused by the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2), resulted in ecological changes of aquatic ecosystems, affected the aquatic food supply chain, and disrupted the socio-economy of global populations. Due to reduced human activities during the pandemic, the aquatic environment was reported to improve its water quality, wild fishery stocks, and biodiversity. However, the sudden surge of plastics and biomedical wastes during the COVID-19 pandemic masked the positive impacts and increased the risks of aquatic pollution, especially microplastics, pharmaceuticals, and disinfectants. The transmission of SARS-CoV-2 from wastewater treatment plants to natural water bodies could have serious impacts on the environment and human health, especially in developing countries with poor waste treatment facilities. The presence and persistence of SARS-CoV-2 in human excreta, wastewaters, and sludge and its transmission to aquatic ecosystems could have negative impacts on fisheries and aquaculture industries, which have direct implications on food safety and security. COVID-19 pandemic-related environmental pollution showed a high risk to aquatic food security and human health. This paper reviews the impacts of COVID-19, both positive and negative, and assesses the causes and consequences of anthropogenic activities that can be managed through effective regulation and management of eco-resources for the revival of biodiversity, ecosystem health, and sustainable aquatic food production.
Using the City Biodiversity Index as a Method to Protect Biodiversity in Korean Cities
Authors: Park Seok-Cheol , Han Bong-Ho
Published: October 2021

This study calculated the ecological network index (City Biodiversity Index 2) of 85 cities in Korea using the Land Cover Map. Based on the values of the index, four types of city were studied, including Miryang (Cluster A), Anseong (Cluster B), Samcheok (Cluster Cluster), and Yongin (Cluster D). Based on the current status of land use and natural green space in urban areas, small and medium-sized cities do not show many disconnected factors and have a positive (+) effect on the ecological network index (ENI) value. In order to promote urban biodiversity, it is necessary not only to expand the green area quantitatively, but also to improve the quality, such as expanding and connecting natural green areas, and reducing linear disconnection factors.
Revitalization Education in Problem Areas as a Tool for the Implementation of Social Welfare
Authors: Skubiak Beata
Published: October 2021

Achieving social well-being in problem areas requires social and economic activation, which is made possible by a change in the attitudes and behavior of the area’s inhabitants. In this systematic review article, the author points out that in order for current public interventions for people at risk in problem areas to be effective, the use of available research by neurobiologists is required. To this end, the author: (1) made a synthetic characterization of problem areas in the world, with particular emphasis on social challenges; (2) reviewed both the available research written by neuroscientists and their subsequent conclusions, which may contribute to better explanations of the social consequences of transformation; (3) on this basis, the author formulated conclusions and recommendations for decision makers. In addition, a review of available research by neuroscientists will help to understand why efforts so far targeting marginalized social groups have been ineffective or insufficient. Revitalization education is defined as all the processes and interactions that aim to change the attitudes and behaviors of people, in particular children and adolescents, in order to contribute to the integration and inclusion of people at risk of social exclusion, and thus improve their well-being. Revitalization education should be directed at people who are caught up in a negative loop of social patterns. Since their fate is shaped by the influence of parents and teachers, the method used for reconstructing positive life patterns towards prodevelopment skills and competences should also be directed at these groups. The article discusses: social problems of marginalized areas; the impact of neuroscience on economic decision making; and recommendations formulated for educational activities.
Rebuilding a Cluster While Protecting Knowledge within Low-Medium-Tech Supplier SMEs: A Spanish and French Comparison
Authors: Gadille Martine , Gallego-Bono Juan Ramón
Published: October 2021

Most of SMEs are engaged in open innovation practices, but they do not benefit from open innovation or from patenting in the same way as larger firms do. At the same time SMEs, as territorialized suppliers, play a crucial role within evolving regional specialization. In this context the purpose of our study is to examine how low and medium technology supplier SMEs learn and organize themselves at a territorial level to address the challenge of IP protection in an open innovation paradigm. We used a qualitative method with a longitudinal multi-case study involving 27 companies with a historical lance to compare the territorial dynamics of knowledge protection within clustered supplier SMEs in two European regions. The results show they protect their knowledge by learning how to design, in a direct relationship with clients, customized complex technological products to develop a new organizational matrix of multidisciplinary knowledge that reveals itself difficult to imitate within the clusters. They also cope with other supplier firms across sectors even if they show societal path dependencies in the way to build cooperation. This dynamic has given birth to changing structural relationships among regionally clustered SMEs and between them and large firms.
Woodland Extraction Rate Estimation in the Savanna Ecosystem (Case Study of Foley and Makomoto in Central-East Botswana)
Authors: Pelane Gaositwe Lillian , Mulalu Mulalu Innocent , Mmopelwa Gagoitseope , Stone Moren Tibabo
Published: October 2021

Savanna woodlands make a significant contribution to rural households’ livelihoods, providing a wide range of resources as well as generating income. However, the sustainability of the woodland ecosystem is generally affected by the human harvesting intensities. This study aimed at quantifying the woodland resource extraction rates and its effects on woodland structure and density. Data were collected from households using a semi-structured questionnaire, key informant interviews, and from 128 rectangular plots measuring 30 m × 30 m. Vegetation parameters, such as tree density, tree height, diameter at breast height, species, stump density, and stump diameter, were recorded. The results of the study revealed that a total of 649 woody stumps were recorded, with an average of 56 trees removed per hectare. The findings showed that the intensities of stumps varied widely, with a high number of stumps recorded at a distance of 10–15 km from the settlements, where major land-use activities are fuelwood extraction, cultivation, and livestock farming. The results also showed that the increased commercial fuelwood production led to cutting of large mopane trees, which is an indicator of unsustainable harvesting. Based on the harvest rates provided by the respondents, results showed that large quantities of fuelwood were harvested for trading, which could put pressure on the woodland ecosystem, consequently resulting in woodland degradation. This study provides forest and range resource managers with valuable information on the quantities of stumps as an indication of tree removals and could be useful in developing effective monitoring strategies and promoting sustainable forest and woodland management.