bluuebunny/crossref_metadata_2025 huggingface dataset:
Inadequate Weight Gain According to the Institute of Medicine 2009 Guidelines in Women with Gestational Diabetes: Frequency, Clinical Predictors, and the Association with Pregnancy Outcomes
Authors: Xie Xinglei , Liu Jiaming , Pujol Isabel , López Alicia , Martínez María José , García-Patterson Apolonia , Adelantado Juan M. , Ginovart Gemma , Corcoy Rosa
Published: October 2020

Background: In the care of women with gestational diabetes mellitus (GDM), more attention is put on glycemic control than in factors such as gestational weight gain (GWG). We aimed to evaluate the rate of inadequate GWG in women with GDM, its clinical predictors and the association with pregnancy outcomes. Methods: Cohort retrospective analysis. Outcome variables: GWG according to Institute of Medicine 2009 and 18 pregnancy outcomes. Clinical characteristics were considered both as GWG predictors and as covariates in outcome prediction. Statistics: descriptive, multinomial and logistic regression. Results: We assessed 2842 women diagnosed with GDM in the 1985–2011 period. GWG was insufficient (iGWG) in 50.3%, adequate in 31.6% and excessive (eGWG) in 18.1%; length of follow-up for GDM was positively associated with iGWG. Overall pregnancy outcomes were satisfactory. GWG was associated with pregnancy-induced hypertension, preeclampsia, cesarean delivery and birthweight-related outcomes. Essentially, the direction of the association was towards a higher risk with eGWG and lower risk with iGWG (i.e., with Cesarean delivery and excessive growth). Conclusions: In this cohort of women with GDM, inadequate GWG was very common at the expense of iGWG. The associations with pregnancy outcomes were mainly towards a higher risk with eGWG and lower risk with iGWG.
Metal on Metal Bearing in Total Hip Arthroplasty and Its Impact on Synovial Cell Count
Authors: Bäcker Henrik C. , Wu Chia H. , Krüger David , Gwinner Clemens , Perka Carsten , Hardt Sebastian
Published: October 2020

Introduction: The effect of different bearings on synovial white blood cell (WBC) count and polymorphonuclear percentage (PMN%) in aspirations remains unclear. Therefore, this study investigates the impact of aseptic Metal-on-Metal (MoM) bearing on synovial fluid. Methods: We searched our arthroplasty registry for aseptic painful THAs with MoM bearings between 2011 and 2018. Then, a case-matched control group was selected with septic and aseptic Total Hip Arthroplasty (THA) with ceramic on a polyethylene (PE) bearing. The matching criteria consisted of gender, age +/−10 years, and time of aspiration (+/−2years). Periprosthetic Joint Infection (PJI) was defined according to the Infectious Diseases Society of America (IDSA), and Musculoskeletal Infection Society (MSIS) using bacterial cultures, sonication and histology. Results: In total, 19 patients who underwent hip aspiration with MoM bearing were identified. Five patients had to be excluded due to insufficient synovial fluid obtained (n = 2) or bacterial growth after sonication that was initially negative with the standard microbiological cultures (n = 3). As such, 14 were included. These patients were matched with 14 aseptic and 14 septic THAs with ceramic on a PE bearing, which constituted the control group. The mean serum chrome level was 20.0 ± 15.5 nmol/L and cobalt level 18.4 ± 22.1 nmol/L. The synovial WBC and PMN% varied significantly between MoM bearing group and the aseptic THA ceramic PE group (both p < 0.001), as well as the septic THA group (WBC p = 0.016, PMN% p < 0.001). Furthermore, the septic THA group had significantly higher CRP values than the aseptic MoM group (p = 0.016). Conclusion: MoM bearing shows significantly higher synovial WBC and PMN% when compared to aseptic THA with ceramic on PE bearing above the MSIS cut-off. This is an important consideration when diagnosing periprosthetic joint infection using the MSIS guidelines.
Predicting Perceived Stress Related to the Covid-19 Outbreak through Stable Psychological Traits and Machine Learning Models
Authors: Flesia Luca , Monaro Merylin , Mazza Cristina , Fietta Valentina , Colicino Elena , Segatto Barbara , Roma Paolo
Published: October 2020

The global SARS-CoV-2 outbreak and subsequent lockdown had a significant impact on people’s daily lives, with strong implications for stress levels due to the threat of contagion and restrictions to freedom. Given the link between high stress levels and adverse physical and mental consequences, the COVID-19 pandemic is certainly a global public health issue. In the present study, we assessed the effect of the pandemic on stress levels in N = 2053 Italian adults, and characterized more vulnerable individuals on the basis of sociodemographic features and stable psychological traits. A set of 18 psycho-social variables, generalized regressions, and predictive machine learning approaches were leveraged. We identified higher levels of perceived stress in the study sample relative to Italian normative values. Higher levels of distress were found in women, participants with lower income, and participants living with others. Higher rates of emotional stability and self-control, as well as a positive coping style and internal locus of control, emerged as protective factors. Predictive learning models identified participants with high perceived stress, with a sensitivity greater than 76%. The results suggest a characterization of people who are more vulnerable to experiencing high levels of stress during the COVID-19 pandemic. This characterization may contribute to early and targeted intervention strategies.
Coupling between Benthic Nutrient Cycling and Pelagic Phytoplankton Community in Taiwan Strait in Spring 2018
Authors: Li Xiaowen , Chai Xiaojie , Zheng Lingling , Deng Qinghui , Chen Xiaoyan , Zhang Qi , Wan Lingling , Song Chunlei , Song Lirong , Zhou Yiyong , Cao Xiuyun
Published: October 2020

Although the nutrient as a driving force for the red tide was intensively studied, the spatial patterns of the phytoplankton community and its response to benthic nutrient cycling remain unclear. We determined the pelagic phytoplankton community and its extracellular alkaline phosphatase qualitatively using enzyme-labeled fluorescence (ELF) technique, concomitantly with the concentrations of phosphorus (P) and nitrogen (N) in the water and sediments in the Taiwan Strait in spring 2018. A total of 30 phytoplankton genera were identified with a higher abundance of the abundance of Prorocentrum and Trichodesmium being observed at the north coast and the center of the southern strait, respectively. Both phytoplankton abundances and Trichodesmium were negatively correlated with the ratios of dissolved inorganic N and ammonium to soluble reactive P (DIN/SRP, NH4+/SRP) in the bottom. Furthermore, the ELF-labeling percentage in Trichodesmium was negatively correlated with total P and SRP but positively correlated with TN/TP, DIN/SRP, and NH4+/SRP in the bottom. In contrast to high DIN/SRP of the surface, lower DIN/SRP in the bottom was owing to a high P release potential and weak sequestration of P as evidenced by the distribution of P solubilizing bacteria and P content. Our findings indicated that the benthic nutrient regime might shape the structure of the pelagic phytoplankton community.
Sublethal Effects of Crude Oil and Chemical Dispersants on Multiple Life History Stages of the Eastern Oyster, Crassostrea virginica
Authors: Garcia Sara M. , Du Clos Kevin T. , Hawkins Olivia H. , Gemmell Brad J.
Published: October 2020

The eastern oyster Crassostrea virginica is an ecologically and economically important species that is vulnerable to oil pollution. We assessed sublethal effects of soluble fractions of crude oil alone (WAF) and crude oil in combination with Corexit 9500 dispersant (CEWAF) on oysters at three life history stages. Veliger swimming, pediveliger settlement, and adult clearance rates were quantified after 24 h exposures to the contaminants. Veliger swimming speeds were not significantly impacted by 24 h exposures to WAF or CEWAF. A larger proportion of veligers were inactive following WAF and CEWAF exposure as compared to the control, but the effect was greater for pediveligers, and pediveliger settlement in the highest concentration CEWAF treatment decreased by 50% compared to controls. Thus, pediveligers may be particularly vulnerable to oil exposure. In the adults, we found significant clearance rates reductions that persisted 33 days after acute exposure to CEWAF. Knowledge of sublethal effects of oil and dispersant at multiple life history stages aids understanding of how this important species will respond to an oil spill.
The Fungal Endophyte Serendipita williamsii Does Not Affect Phosphorus Status But Carbon and Nitrogen Dynamics in Arbuscular Mycorrhizal Tomato Plants
Authors: Hallasgo Anna M. , Spangl Bernhard , Steinkellner Siegrid , Hage-Ahmed Karin
Published: October 2020

Some members of the root endophytic Serendipitaceae were observed to frequently coexist with arbuscular mycorrhizal fungi (AMF), but their interactions and potential synergistic effects in plants have not yet been well elucidated. Here, we inoculated three-week-old tomato seedlings with Serendipita indica or Serendipita williamsii alone or in combination with the arbuscular mycorrhizal fungus Funneliformis mosseae and cultivated the plants in a greenhouse until the late vegetative stage. Our data show that the simultaneous presence of Serendipita spp. did not affect root colonization by AMF, proving the feasibility of their combination for future agronomic uses. The photosynthetic performance was enhanced in AM tomato plants, although growth remained unresponsive following single or dual inoculation with Serendipita spp. and AMF. With regard to nutrient status under dual inoculation, AMF-induced phosphorus increases remained unaffected, but nitrogen and carbon dynamics were highly altered. Specifically, the application of S. williamsii to mycorrhizal tomato plants significantly enhanced nitrogen concentration in the shoots, but this effect was also compensated with a carbon cost. Our findings indicate that S. williamsii performs differently from S. indica when co-inoculated with AMF, and this suggests an unknown mechanism that needs more detailed investigation.
Uncovering Ecosystem Services of Expropriated Land: The Case of Urban Expansion in Bahir Dar, Northwest Ethiopia
Authors: Admasu Wubante Fetene , Boerema Annelies , Nyssen Jan , Minale Amare Sewnet , Tsegaye Enyew Adgo , Van Passel Steven
Published: October 2020

In Ethiopia, urban expansion happens at high rates and results in land expropriations often at the cost of agriculture and forests. The process of urban expansion does not include assessment of ecosystem services (ES). This has been causing unintended environmental problems. This study aims to uncover ES of three most important land use types (cropland, agroforestry, and grassland) that are threatened by land expropriation for urban expansion in Bahir Dar City. The study applied a participatory approach using community perception and expert judgments (N = 108). Respondents were asked to locate their perceptions on the use of 35 different ES, and then to evaluate the potential of the land use. Respondents were shown to have the ability to differentiate between ES and land use in terms of their potential to deliver ES. The results show that agroforestry is expected to have a high relevant potential to deliver 31% of all ES, but cropland 20% and grassland 14%. Food, fodder, timber, firewood, fresh water, energy, compost, climate regulation, erosion prevention, and water purification and treatment were identified as the ten most important services. It is not only the provisioning services that are being supplied by the land use types which are expropriated for urbanization, but also regulating, supporting and cultural services. To ensure sustainable urban land development, we suggest the consideration of the use of ES and the potential of the land use to supply ES when making land use decisions, including land expropriation for urban expansion.
Effect of Welding Speed and Post Quenching on the Microstructure and Mechanical Properties of Laser-Welded B1500HS Joints
Authors: Li Muyu , Yao Dan , Guan Yingping , Duan Yongchuan , Yang Liu
Published: October 2020

In this research, B1500HS high-strength steel with different thicknesses were laser welded, and the effects of welding speed and post quenching were investigated by analyzing the microstructure, microhardness distribution, and high-temperature tensile properties of weld joints. The results show that an obvious difference can be found in the metallographic structure and grain morphology of the weld joint at different locations, which also lead to the significant uneven distribution of hardness. After quenching, the grain size of the original heat-affected zone was uniform, the columnar grains in the fusion zone were transformed into fine equiaxed grains, and no obvious hardness difference can be found in the weld joint. For the weld joint without quenching, the increase of welding speed can reduce the dimensions of grains of fusion zone and coarse grain zone, and slightly increase the hardness of these regions. In contrast, welding speed change has little influence on the microstructure and hardness of the weld joint after quenching. The high-temperature flow stress–strain curves of fusion zone welded under different welding speeds were calculated based on the mixture rule. The analysis results indicated that the fusion zone has higher strength but lower elongation than the base metal. In addition, the change of welding speed has a small impact on the high-temperature tensile properties of the fusion zone.
The Influence of Ambient Temperature on High Performance Concrete Properties
Authors: Kaleta-Jurowska Alina , Jurowski Krystian
Published: October 2020

This paper presents the results of tests on high performance concrete (HPC) prepared and cured at various ambient temperatures, ranging from 12 °C to 30 °C (the compressive strength and concrete mix density were also tested at 40 °C). Special attention was paid to maintaining the assumed temperature of the mixture components during its preparation and maintaining the assumed curing temperature. The properties of a fresh concrete mixture (consistency, air content, density) and properties of hardened concrete (density, water absorption, depth of water penetration under pressure, compressive strength, and freeze–thaw durability of hardened concrete) were studied. It has been shown that increased temperature (30 °C) has a significant effect on loss of workability. The studies used the concrete slump test, the flow table test, and the Vebe test. A decrease in the slump and flow diameter and an increase in the Vebe time were observed. It has been shown that an increase in concrete curing temperature causes an increase in early compressive strength. After 3 days of curing, compared with concrete curing at 20 °C, an 18% increase in compressive strength was observed at 40 °C, while concrete curing at 12 °C had a compressive strength which was 11% lower. An increase in temperature lowers the compressive strength after a period longer than 28 days. After two years of curing, concrete curing at 12 °C achieved a compressive strength 13% higher than that of concrete curing at 40 °C. Freeze–thaw performance tests of HPC in the presence of NaCl demonstrated that this concrete showed high freeze–thaw resistance and de-icing materials (surface scaling of this concrete is minimal) regardless of the temperature of the curing process, from 12 °C to 30 °C.
Facile Synthesis of Nanoporous NiS Film with Inverse Opal Structure as Efficient Counter Electrode for DSSCs
Authors: Chen Xu , Zhang Yang , Pang Yashuai , Jiang Qiwei
Published: October 2020

To satisfy the high requirement of catalytic activity for efficient dye-sensitized solar cells (DSSCs), a novel nanoporous NiS film with inverse opal structure and outstanding electrocatalytic properties was prepared by a facile template-assisted electrodeposition method. The inverse opal structure makes the film have a larger specific surface area and more catalytic sites, thereby result to a higher electrocatalytic activity. Compared with the flat NiS/FTO electrode, this kind of nanoporous NiS film with inverse opal structure has higher catalytic activity and can be used as a cheap and efficient Pt-free electrode to replace the traditional Pt/FTO electrode. It is of great significance to reduce the cost and promote the wide application of DSSCs. This study opens up a new experimental exploration for further improving the catalytic activity of NiS electrode and the according photovoltaic efficiency of DSSCs. The template-assisted electrodeposition method proposed in this work provides a facile method for morphology control and an easy to be realized way to optimize the catalytic performance of the metal sulfides counter electrode.
Fabrication of Eco-Friendly Betanin Hybrid Materials Based on Palygorskite and Halloysite
Authors: Li Shue , Mu Bin , Wang Xiaowen , Kang Yuru , Wang Aiqin
Published: October 2020

Eco-friendly betanin/clay minerals hybrid materials with good stability were synthesized by combining with adsorption, grinding, and heating treatment using natural betanin extracted from beetroot and natural 2:1 type palygorskite or 1:1 type halloysite. After incorporation of clay minerals, the thermal stability and solvent resistance of natural betanin were obviously enhanced. Due to the difference in the structure of palygorskite and halloysite, betanin was mainly adsorbed on the outer surface of palygorskite or halloysite through hydrogen-bond interaction, but also part of them also entered into the lumen of Hal via electrostatic interaction. Compared with palygorskite, hybrid materials prepared with halloysite exhibited the better color performance, heating stability and solvent resistance due to the high loading content of betanin and shielding effect of lumen of halloysite.
Understanding the Role of Silver Nanostructures and Graphene Oxide Applied as Surface Modification of TiO2 in Photocatalytic Transformations of Rhodamine B under UV and Vis Irradiation
Authors: Spilarewicz-Stanek Kaja , Jakimińska Anna , Kisielewska Aneta , Batory Damian , Piwoński Ireneusz
Published: October 2020

This work is focused on photocatalytic properties of titanium dioxide thin coatings modified with silver nanostructures (AgNSs) and graphene oxide (GO) sheets which were analyzed in processes of chemical transformations of rhodamine B (RhB) under ultraviolet (UV) or visible light (Vis) irradiation, respectively. UV-Vis spectroscopy was applied to analyze the changes in the RhB spectrum during photocatalytic processes, revealing decolorization of RhB solution under UV irradiation while the same process coexisting with the transformation of RhB to rhodamine 110 was observed under Vis irradiation. The novelty of this study is the elaboration of a methodology for determining the parameters characterizing the processes occurring under the Vis irradiation, which enables the comparison of photocatalysts’ activity. For the first time, the method for quantification of rhodamine B transformation into rhodamine 110 in the presence of a semiconductor under visible light irradiation was proposed. Photocatalysts with various surface architectures were designed. TiO2 thin coatings were obtained by the sol-gel method. GO sheets were deposited on their surface using the dip-coating method. AgNSs were photogenerated on TiO2 or grown spontaneously on GO flakes. For characterization of obtained photocatalysts, scanning electron microscopy (SEM), X-ray diffraction (XRD) and diffuse-reflectance spectroscopy (DRS) techniques were applied. The results indicate that the surface architecture of prepared coatings does not affect the main reaction path but have an influence on the reaction rates and yields of observed processes.
Influence of Long-Period-Stacking Ordered Structure on the Damping Capacities and Mechanical Properties of Mg-Zn-Y-Mn As-Cast Alloys
Authors: Lu Ruopeng , Jiao Kai , Zhao Yuhong , Li Kun , Yao Keyu , Hou Hua
Published: October 2020

Magnesium alloys are concerned for its mechanical properties and high damping performance. The influence of Mn toward the internal organization morphology of long-period stacking ordered (LPSO) second phase and the consistent damping performance in Mg-4.9Zn-8.9Y-xMn have been studies in this work. It has shown that the addition of Mn tends to diffuse to the LPSO interface and causes the LPSO phase to expand in the arc direction. The circular structure of LPSO can optimize the damping property of the alloy better than the structure with strong orientation, especially at the strain of 10−3 and 250 °C. With more additions of Mn, damping would have a reduction due to the dispersed fine LPSO phases and α-Mn particles. When the Mn content is higher than 1.02%, the grain is refined, and mechanical properties have been significantly improved. Mg-4.9%Zn-8.9%Y-1.33%Mn shows the best mechanical property.
Synthesis and Characterization of Graphene–Silver Nanoparticle Hybrid Materials
Authors: Osváth Zoltán , Pálinkás András , Piszter Gábor , Molnár György
Published: October 2020

Silver nanoparticles (Ag NPs) play important roles in the development of plasmonic applications. Combining these nanoparticles with graphene can yield hybrid materials with enhanced light–matter interaction. Here, we report a simple method for the synthesis of graphene–silver nanoparticle hybrids on highly oriented pyrolytic graphite (HOPG) substrates. We demonstrate by scanning tunneling microscopy and local tunneling spectroscopy measurements the electrostatic n-type doping of graphene by contact with silver. We show by UV-Vis reflectance investigations that the local surface plasmon resonance (LSPR) of Ag NPs partially covered with graphene is preserved for at least three months, i.e., three times longer than the LSPR of bare Ag NPs. The gradual loss of LSPR is due to the spontaneous sulfurization of non-covered Ag NPs, as revealed by scanning electron microscopy and energy-dispersive X-ray spectroscopy. We show that the Ag NPs completely sandwiched between graphene and HOPG do not sulfurize, even after one year.
Corrected Evolutive Kendall’s τ Coefficients for Incomplete Rankings with Ties: Application to Case of Spotify Lists
Authors: Pedroche Francisco , Conejero J. Alberto
Published: October 2020

Mathematical analysis of rankings is essential for a wide range of scientific, public, and industrial applications (e.g., group decision-making, organizational methods, R&D sponsorship, recommender systems, voter systems, sports competitions, grant proposals rankings, web searchers, Internet streaming-on-demand media providers, etc.). Recently, some methods for incomplete aggregate rankings (rankings in which not all the elements are ranked) with ties, based on the classic Kendall’s tau coefficient, have been presented. We are interested in ordinal rankings (that is, we can order the elements to be the first, the second, etc.) allowing ties between the elements (e.g., two elements may be in the first position). We extend a previous coefficient for comparing a series of complete rankings with ties to two new coefficients for comparing a series of incomplete rankings with ties. We make use of the newest definitions of Kendall’s tau extensions. We also offer a theoretical result to interpret these coefficients in terms of the type of interactions that the elements of two consecutive rankings may show (e.g., they preserve their positions, cross their positions, and they are tied in one ranking but untied in the other ranking, etc.). We give some small examples to illustrate all the newly presented parameters and coefficients. We also apply our coefficients to compare some series of Spotify charts, both Top 200 and Viral 50, showing the applicability and utility of the proposed measures.
Some Economic Dynamics Problems for Hybrid Models with Aftereffect
Authors: Bravyi Eugene , Maksimov Vladimir , Simonov Pyotr
Published: October 2020

In this paper, we consider a class of economic dynamics models in the form of linear functional differential systems with continuous and discrete times (hybrid models) that covers many kinds of dynamic models with aftereffect. The focus of attention is periodic boundary value problems with deviating argument, control problems with respect to general on-target vector-functional and questions of stability to solutions. For boundary value problems, some sharp sufficient conditions of the unique solvability are obtained. The attainability of on-target values is under study as applied to control problems with polyhedral constraints with respect to control, some estimates of the attainability set as well as estimates to a number of switch-points of programming control are presented. For a class of hybrid systems, a description of asymptotic properties of solutions is given.
Modeling and Solving a Latin American University Course Timetabling Problem Instance
Authors: Chávez-Bosquez Oscar , Hernández-Torruco José , Hernández-Ocaña Betania , Canul-Reich Juana
Published: October 2020

Timetabling problem is a complex task that is performed by a number of institutions worldwide, which has been usually addressed as an optimization problem where every approach considers the particular constraints of each institution under consideration. In this paper, we describe, model, and propose a solution to the timetabling problem at the División Académica de Ciencias y Tecnologías de la Información of the Universidad Juárez Autónoma de Tabasco (UJAT), México. We modeled the specific constraints of this problem instance using the Object Constraint Language (OCL) of the Unified Modeling Language (UML), and we validated the model while using the state-of-the-art tool USE: UML-based Specification Environment. The solution strategy tackles the problem in two stages: (1) ACA: academic assignments, i.e., assign lectures to professors and (2) TTP: the timetabling process. We developed a Tabu Search customization named Tabu Search with Probabilistic Aspiration Criterion (TS-PAC) in order to solve the timetabling problem, and we developed a software prototype to test our proposal. Two feasible timetables for two different semesters were obtained according to the modeled constraints.
Efficient Implementation of ARX-Based Block Ciphers on 8-Bit AVR Microcontrollers
Authors: Kim YoungBeom , Kwon Hyeokdong , An SangWoo , Seo Hwajeong , Seo Seog Chung
Published: October 2020

As the development of Internet of Things (IoT), the data exchanged through the network has significantly increased. To secure the sensitive data with user’s personal information, it is necessary to encrypt the transmitted data. Since resource-constrained wireless devices are typically used for IoT services, it is required to optimize the performance of cryptographic algorithms which are computation-intensive tasks. In this paper, we present efficient implementations of ARX-based Korean Block Ciphers (HIGHT and LEA) with CounTeR (CTR) mode of operation, and CTR_DRBG, one of the most widely used DRBGs (Deterministic Random Bit Generators), on 8-bit AVR Microcontrollers (MCUs). Since 8-bit AVR MCUs are widely used for various types of IoT devices, we select it as the target platform in this paper. We present an efficient implementation of HIGHT and LEA by making full use of the property of CTR mode, where the nonce value is fixed, and only the counter value changes during the encryption. On our implementation, the cost of additional function calls occurred by the generation of look-up table can be reduced. With respect to CTR_DRBG, we identified several parts that do not need to be computed. Thus, precomputing those parts in offline and using them online can result in performance improvements for CTR_DRBG. Furthermore, we applied several optimization techniques by making full use of target devices’ characteristics with AVR assembly codes on 8-bit AVR MCUs. Our proposed table generation way can reduce the cost for building a precomputation table by around 6.7% and 9.1% in the case of LEA and HIGHT, respectively. Proposed implementations of LEA and HIGHT with CTR mode on 8-bit AVR MCUs provide 6.3% and 3.8% of improved performance, compared with the previous best results, respectively. Our implementations are the fastest compared to previous LEA and HIGHT implementations on 8-bit AVR MCUs. In addition, the proposed CTR_DRBG implementations on AVR provide better performance by 37.2% and 8.7% when the underlying block cipher is LEA and HIGHT, respectively.
Chemical Defense in Marine Organisms
Authors: Lauritano Chiara , Ianora Adrianna
Published: October 2020

Marine organisms are constantly exposed to variations in physical parameters (e [...]
A Comparison of Clinical Outcomes between Endoscopic Resection and Surgical Resection in Ampullary Tumors
Authors: Pyo Jung-Soo , Son Byoung Kwan , Lee Hyo Young , Oh Il Hwan , Chung Kwang Hyun
Published: October 2020

Background and objectives: This study aimed to elucidate the clinical outcomes of endoscopic resection (ER) through comparison with surgical resection (SR) through a meta-analysis. Materials and Methods: This meta-analysis was performed using 32 studies. The complete resection and recurrence rates of treatment for ampullary tumors were investigated and compared between ER and SR. In addition, complications, including pancreatitis, cholangitis, cholecystitis, perforation, and papillary stenosis, and mortality of ER and SR, respectively, were estimated. Results: The rates of complete resection were 0.812 (95% confidence interval, CI, 0.758–0.856) and 0.929 (95% CI 0.739–0.984) in ER and SR, respectively. Recurrence rates were 0.145 (95% CI 0.107–0.193) and 0.126 (95% CI 0.057–0.257) in ER and SR, respectively. There were no significant differences in complete resection and recurrence rates between ER and SR in the meta-regression tests (p = 0.164 and p = 0.844, respectively). The estimated rates of pancreatitis, cholangitis/cholecystitis, perforation, and papillary stenosis were 12.8%, 4.4%, 5.2%, and 4.3% in ER and 9.9%, 5.6%, 2.3%, and 5.6% in SR, respectively. There was no significant difference in complications between ER and SR. The mortality rate of SR was slightly higher than that of ER (0.041, 95% CI 0.015–0.107 vs. 0.031, 95% CI 0.005–0.162). Our results show that ER had no significant differences in terms of complete resection and recurrence rates compared to SR, regardless of tumor behaviors. Conclusions: By comparing the complication and mortality rates between ER and SR, the safety of ER was proven.
A 1D Analytical Model for Slag Infiltration during Continuous Casting of Steel under Non-Sinusoidal Mold Oscillation
Authors: Yang Hyunjin
Published: October 2020

A 1D analytical model for slag infiltration during continuous casting of steel is developed to investigate the slag behavior in the mold–strand gap. The superposition principle and Fourier expansion are applied to obtain the analytical solution for transient slag flow under arbitrary mold oscillation including non-sinusoidal oscillation mode. The validated model using literature data partially explains several controversies such as slope of slag film channel, mechanism of non-sinusoidal mold oscillation, and timing of slag infiltration. The model shows that a converging slag film into the casting direction is required to open the mold–strand gap if compression is applied in between. Also, model calculations imply that higher slag consumption is achievable from non-sinusoidal mold oscillation by means of the increase of film thickness through longer positive pressure with higher peak pressure. The model demonstrates a time difference between slag flow and pressure near the meniscus and the discrepancy in timing of infiltration between previous works is attributed to the mismatch. The model provides a concise but reliable tool to understand slag infiltration behavior and design mold oscillation settings.
Extraction Chromatography Materials Prepared with HDEHP on Different Inorganic Supports for the Separation of Gadolinium and Terbium
Authors: Monroy-Guzman Fabiola , De la Cruz Barba Celia del Carmen , Jaime Salinas Edgar , Garibay-Feblés Vicente , Nava Entzana Tobias Noel
Published: October 2020

Bis(2-ethylhexyl)phosphoric acid (HDEHP) is frequently used as an extractant in the separation and recovery of lanthanides by solvent extraction and extraction chromatography, where HDEHP (stationary phase) is fixed on an inert support and the mobile phase is an aqueous solution. Because the results of extraction chromatography strongly depend on the support material, in this study, we aim to prepare solid extractants (extraction chromatography materials) with different inorganic supports impregnated with HDEHP for the adsorption of Gd and Tb from HCl solutions, putting emphasis on the effect of the supports on the solid extractant behavior. Gd and Tb partition data were determined in HCl solutions from the prepared extraction chromatography materials using elution analysis. Solid extractants were characterized by X-Ray diffraction, electron microscopy, and infrared spectroscopy in order to determine their properties and to explain their extraction behavior. The characterization of the solid extractants showed a heterogeneous distribution of the HDEHP on the surfaces of the different supports studied. The irregular shape of the support particles produces discontinuous and heterogenous silanization and HDEHP coatings on the support surface, affecting the retention performance of the solid extractant and the chromatographic resolution.
Electro-Hydrodynamics of Emulsion Droplets: Physical Insights to Applications
Authors: Abbasi Muhammad , Song Ryungeun , Cho Seongsu , Lee Jinkee
Published: October 2020

The field of droplet electrohydrodynamics (EHD) emerged with a seminal work of G.I. Taylor in 1966, who presented the so-called leaky dielectric model (LDM) to predict the droplet shapes undergoing distortions under an electric field. Since then, the droplet EHD has evolved in many ways over the next 55 years with numerous intriguing phenomena reported, such as tip and equatorial streaming, Quincke rotation, double droplet breakup modes, particle assemblies at the emulsion interface, and many more. These phenomena have a potential of vast applications in different areas of science and technology. This paper presents a review of prominent droplet EHD studies pertaining to the essential physical insight of various EHD phenomena. Here, we discuss the dynamics of a single-phase emulsion droplet under weak and strong electric fields. Moreover, the effect of the presence of particles and surfactants at the emulsion interface is covered in detail. Furthermore, the EHD of multi-phase double emulsion droplet is included. We focus on features such as deformation, instabilities, and breakups under varying electrical and physical properties. At the end of the review, we also discuss the potential applications of droplet EHD and various challenges with their future perspectives.
Spatial Changes in Microbial Communities along Different Functional Zones of a Free-Water Surface Wetland
Authors: Semenov Mikhail V. , Krasnov George S. , Rybka Ksenia Y. , Kharitonov Sergey L. , Zavgorodnyaya Yulia A. , Yudina Anna V. , Shchegolkova Nataliya M.
Published: October 2020

Constructed wetlands (CWs) are complicated ecosystems that include vegetation, sediments, and the associated microbiome mediating numerous processes in wastewater treatment. CWs have various functional zones where contrasting biochemical processes occur. Since these zones are characterized by different particle-size composition, physicochemical conditions, and vegetation, one can expect the presence of distinct microbiomes across different CW zones. Here, we investigated spatial changes in microbiomes along different functional zones of a free-water surface wetland located in Moscow, Russia. The microbiome structure was analyzed using Illumina MiSeq amplicon sequencing. We also determined particle diameter and surface area of sediments, as well as chemical composition of organic pollutants in different CW zones. Specific organic particle aggregates similar to activated sludge flocs were identified in the sediments. The highest accumulation of hydrocarbons was found in the zones with predominant sedimentation of fine fractions. Phytofilters had the highest rate of organic pollutants decomposition and predominance of Smithella, Ignavibacterium, and Methanothrix. The sedimentation tank had lower microbial diversity, and higher relative abundances of Parcubacteria, Proteiniclasticum, and Macellibacteroides, as well as higher predicted abundances of genes related to methanogenesis and methanotrophy. Thus, spatial changes in microbiomes of constructed wetlands can be associated with different types of wastewater treatment processes.
Effects of Wormwood (Artemisia montana) Essential Oils on Digestibility, Fermentation Indices, and Microbial Diversity in the Rumen
Authors: Lee Seong Shin , Kim Dong Hyeon , Paradhipta Dimas Hand Vidya , Lee Hyuk Jun , Yoon Hee , Joo Young Ho , Adesogan Adegbola T. , Kim Sam Churl
Published: October 2020

This study investigated the effects of essential oil (EO) from three Korean wormwood (Artemisia Montana) plants on in vitro ruminal digestibility, fermentation, and microbial diversity. Dried (0.5 g) soybean meal (SBM) or bermudagrass hay (BGH) were incubated in buffered rumen fluid (40 mL) for 72 h with or without EO (5 mg/kg) from Ganghwa (GA), Injin (IN), or San (SA) wormwood (Experiment 1). Both SA and IN improved (p < 0.05) dry matter digestibility (DMD) of BGH, while GA reduced (p < 0.05) total short-chain fatty acid of BGH and SBM. Besides, SA increased (p < 0.05) numbers of Ruminococcus albus and Streptococcus bovis in SBM. Experiment 2 examined different doses (0, 0.1, 1, and 10 mg/kg) of SA, the most promising EO from Experiment 1. Applying SA at 10 mg/kg gave the highest DMD (L; p < 0.01) and neutral detergent fiber (Q; p < 0.05) digestibility for BGH. Applying SA at 1 mg/kg gave the highest R. albus population (Q; p < 0.05) in SBM. Therefore, SA was better than GA and IN at improving rumen fermentation, and the 0.1 to 1 and 10 mg/kg doses improved ruminal fermentation and in vitro digestibility of SBM and BGH, respectively.
Simultaneous Qualitative and Quantitative Evaluation of the Coptidis Rhizoma and Euodiae Fructus Herbal Pair by Using UHPLC-ESI-QTOF-MS and UHPLC-DAD
Authors: Li Yan-Ying , Guo Min-Qun , Li Xue-Mei , Yang Xiu-Wei
Published: October 2020

The herbal pair of Coptidis Rhizoma (CR) and Euodiae Fructus (EF) is a classical traditional Chinese medicine formula used for treating gastro-intestinal disorders. In this study, we established a systematic method for chemical profiling and quantification analysis of the major constituents in the CR-EF herbal pair. A method of ultra high performance liquid chromatography/quadrupole time-of-flight mass spectrometry (UHPLC-QTOF-MS) for qualitative analysis was developed. Sixty-five compounds, including alkaloids, phenolics, and limonoids, were identified or tentatively assigned by comparison with reference standards or literature data. The UHPLC fingerprints of 19 batches of the CR-EF herbal pair samples were obtained and the reference fingerprint chromatograms were established. Furthermore, nine compounds among 24 common peaks of fingerprints were considered as marker components, which either had high contents or significant bioactivities, were applied to quality control of the CR-EF herbal pair by quantitative analysis. This UHPLC-DAD analysis method was validated by precision, linearity, repeatability, stability, recovery, and so on. The method was simple and sensitive, and thus reliable for quantitative and chemical fingerprint analysis for the quality evaluation and control of the CR-EF herbal pair and related traditional Chinese medicines.
The Mechanical Effect of MnO2 Layers on Electrochemical Actuation Performance of Nanoporous Gold
Authors: Han Zhifei , Qi Zhengpan , Wei Qiang , Deng Qibo , Wang Ke
Published: October 2020

This study investigated the electrochemical actuation behavior of nanoporous material during the capacitive process. The length change of nanoporous gold (npg) was in situ investigated in a liquid environment using the dilatometry technique. The mechanical effect of MnO2 layers was introduced in this work to improve the actuation characteristics of the npg samples. Our work found that the actuation behavior of npg sample could be significantly modulated with a covering of MnO2 layers. The electrochemical actuation amplitude was efficiently improved and strongly dependent on the thickness of MnO2 layers covered. Aside from the amplitude, the phase relation between the length change and the electrode potential was inverted when covering the MnO2 layer on the npg samples. This means the expansion of the npg samples and the contraction of samples covered with the MnO2 layer when electrochemical potential sweeps positively. A simple finite element model was built up to understand the effect of the MnO2 layer. The agreement between the simulation result and the experimental data indicates that the sign-inverted actuation-potential response of nanoporous gold contributes to the mechanical effect of MnO2. It is believed that our work could offer a deep understanding on the effect of the MnO2 layer on the electrochemical actuation and then provide a useful strategy to modulate the actuation performance of nanoporous metal materials.
Hexagonal and Monoclinic Phases of La2O2CO3 Nanoparticles and Their Phase-Related CO2 Behavior
Authors: Yu Hongyan , Jiang Kaiming , Kang Sung Gu , Men Yong , Shin Eun Woo
Published: October 2020

In this study, we prepared hexagonal and monoclinic phases of La2O2CO3 nanoparticles by different wet preparation methods and investigated their phase-related CO2 behavior through field-emission scanning microscopy, high-resolution transmission electron microscopy, Fourier transform infrared, thermogravimetric analysis, CO2-temperature programmed desorption, and linear sweeping voltammetry of CO2 electrochemical reduction. The monoclinic La2O2CO3 phase was synthesized by a conventional precipitation method via La(OH)CO3 when the precipitation time was longer than 12 h. In contrast, the hydrothermal method produced only the hexagonal La2O2CO3 phase, irrespective of the hydrothermal reaction time. The La(OH)3 phase was determined to be the initial phase in both preparation methods. During the precipitation, the La(OH)3 phase was transformed into La(OH)CO3 owing to the continuous supply of CO2 from air whereas the hydrothermal method of a closed system crystallized only the La(OH)3 phase. Based on the CO2-temperature programmed desorption and thermogravimetric analysis, the hexagonal La2O2CO3 nanoparticles (HL-12h) showed a higher surface CO2 adsorption and thermal stability than those of the monoclinic La2O2CO3 (PL-12h). The crystalline structures of both La2O2CO3 phases predicted by the density functional theory calculation explained the difference in the CO2 behavior on each phase. Consequently, HL-12h showed a higher current density and a more positive onset potential than PL-12h in CO2 electrochemical reduction.
Rapid Weight Gain, Infant Feeding Practices, and Subsequent Body Mass Index Trajectories: The CALINA Study
Authors: Flores-Barrantes Paloma , Iguacel Isabel , Iglesia-Altaba Iris , Moreno Luis A. , Rodríguez Gerardo
Published: October 2020

We aimed to study growth patterns according to rapid weight gain (RWG) and infant feeding practices during the first 120 days and whether infant feeding practices mediated the association between RWG in the first semester of life and subsequent body mass index (BMI) z-score in children from age 1 to 6. (1) Methods: 862 children from the Growth and Feeding during Lactation and Early Childhood in Children of Aragon study (CALINA in Spanish) were examined. Repeated-measures ANOVA analyses were conducted to assess growth trajectories according to RWG and type of feeding practice. The product of coefficients mediation method was used to assess the potential contribution of infant feeding practices to the association between RWG and BMI z-score. Mediation models were conducted using IBM SPSS-PROCESS Statistics for Windows, Version 26.0. Armonk, NY: IBM Corp. (2) Results: BMI and weight z-score trajectories were significantly higher in the RWG group and the formula-fed group. No significant differences were found regarding height. Infant feeding practices did not mediate the association between RWG and BMI z-score but were associated with BMI at 6 years. (3) Conclusions: Infant feeding practices and RWG determine different growth trajectories of BMI and weight during childhood. Although infant feeding practices did not mediate the association between early RWG and BMI later in life, formula feeding is independently related to higher BMI growth patterns later in childhood.
A Genome-Wide Association Study Identifies the Association between the 12q24 Locus and Black Tea Consumption in Japanese Populations
Authors: Furukawa Kyohei , Igarashi Maki , Jia Huijuan , Nogawa Shun , Kawafune Kaoru , Hachiya Tsuyoshi , Takahashi Shoko , Saito Kenji , Kato Hisanori
Published: October 2020

Several genome-wide association studies (GWASs) have reported the association between genetic variants and the habitual consumption of foods and drinks; however, no association data are available regarding the consumption of black tea. The present study aimed to identify genetic variants associated with black tea consumption in 12,258 Japanese participants. Data on black tea consumption were collected by a self-administered questionnaire, and genotype data were obtained from a single nucleotide polymorphism array. In the discovery GWAS, two loci met suggestive significance (p < 1.0 × 10−6). Three genetic variants (rs2074356, rs144504271, and rs12231737) at 12q24 locus were also significantly associated with black tea consumption in the replication stage (p < 0.05) and during the meta-analysis (p < 5.0 × 10−8). The association of rs2074356 with black tea consumption was slightly attenuated by the additional adjustment for alcohol drinking frequency. In conclusion, genetic variants at the 12q24 locus were associated with black tea consumption in Japanese populations, and the association is at least partly mediated by alcohol drinking frequency.
Diet to Reduce the Metabolic Syndrome Associated with Menopause. The Logic for Olive Oil
Authors: Hidalgo-Mora Juan José , Cortés-Sierra Laura , García-Pérez Miguel-Ángel , Tarín Juan J. , Cano Antonio
Published: October 2020

The rates of metabolic syndrome are increasing in parallel with the increasing prevalence of obesity, primarily due to its concomitant insulin resistance. This is particularly concerning for women, as the years around menopause are accompanied by an increase in visceral obesity, a strong determinant of insulin resistance. A fall in estrogens and increase in the androgen/estrogen ratio is attributed a determining role in this process, which has been confirmed in other physiological models, such as polycystic ovary syndrome. A healthy lifestyle, with special emphasis on nutrition, has been recommended as a first-line strategy in consensuses and guidelines. A consistent body of evidence has accumulated suggesting that the Mediterranean diet, with olive oil as a vital component, has both health benefits and acceptable adherence. Herein, we provide an updated overview of current knowledge on the benefits of olive oil most relevant to menopause-associated metabolic syndrome, including an analysis of the components with the greatest health impact, their effect on basic mechanisms of disease, and the state of the art regarding their action on the main features of metabolic syndrome.