bluuebunny/crossref_metadata_2025 huggingface dataset:
judul artikel
Authors: Kadek Wiwin asita , Wirawan Ketut Adi , Payana Gede Andra Uky
Published: November 2024

Penerapan asas fiksi hukum terhadap suatu peraturan menimbulkan permasalahan dalam masyarakat,  banyak masyarakat yang tidak mengetahui pemberlakuan suatu peraturan akibat dari kurangnya akses informasi dan sosialisasi dari pemerintah serta rendahnya kualitas sumber daya manusia yang tidak dapat memahami isi peraturan yang telah diberlakukan, sehingga peraturan tersebut tidak berlaku secara efektif dalam masyarakat dan tanpa sadar hal ini menyebabkan banyak terjadinya penyimpangan dalam pelaksanaannya. Permasalahan dalam penelitian ini yaitu berlakunya asas fiksi hukum yang menimbulkan permasalahan di Kabupaten Buleleng mengenai tidak optimalnya pemberlakuan peraturan daerah terkait bea perolehan hak atas tanah dan bangunan terhadap masyarakat. Dalam hal ini, masyarakat dirugikan akibat tidak mengetahui isi peraturan daerah khususnya dalam hal pelaksanaan pengalihan hak atas sertifikat tanah melalui pewarisan, sehingga hal ini banyak dimanfaatkan oleh oknum yang tidak bertanggung jawab, dengan memungut biaya yang tidak sesuai peraturan yang berlaku. Jenis Penelitian ini menggunakan penelitian hukum empiris. Hasil dari penelitian ini yaitu, bahwa Perda Kabupaten Buleleng Nomor 1 tahun 2011 tentang Bea Perolehan Hak Atas Tanah dan Bangunan belum efektif diterapkan pada masyarakat bueleleng, akibat masyarakat belum mengetahui dan memahami keseluruhan isi peraturan ini sehingga dapat dikatakan berlakunya asas fiksi hukum dalam pemberlakuan peraturan ini, lalu banyak pejabat umum sebagai oknum yang memanfaatkan permasalahan ini untuk menipu dan mencari keuntungan dari masyarakat. Agar tidak terjadi kerugian yang semakin banyak oleh masyarakat yang memiliki kepentingan ini, diperlukan adanya pemerataan informasi yang dilakukan oleh setiap lapisan pemerintah dan pejabat umum serta sosialisasi yang lebih komprehensif mengenai pemberlakuan peraturan ini, sehingga dapat berlaku secara efektif di masyarakat.
Life Experiences and Well-Being Among Children Born to Mothers Living With HIV in Two Provinces of Thailand
Authors:   Institute for Population and Social Research(IPSR), Mahidol University,Thailand, Chantcharas Parichart
Published: November 2024

This study explores the complex experiences of children living with HIV (CLHIV) who were born to mothers living with HIV (MLHIV), particularly during their transition into adolescence and beyond, aiming to enhance their well-being. By investigating life experiences and determinants of well-being, the research seeks to uncover intricate challenges and offer insights into the factors influencing their well-being. The study uses a mixed-methods approach, combining a cross-sectional survey with structured tools and case studies involving in-depth interviews for a comprehensive analysis. The study settings encompass community and provincial hospitals in two provinces within Thailand’s Central region, chosen for the presence of organizations supporting people living with HIV (PLHIV). The study examines well-being using standardized instruments: the Pictorial Thai Self-Esteem Scale (PTSS) and the PedsQL™ 4.0: Pediatric Quality of Life Inventory TM (Thai version). The findings illuminate various challenges faced by CLHIV, such as educational barriers, psychosocial difficulties, and stigma and discrimination rooted in past experiences. Recommendations emphasize the importance of quality education and employment opportunities, alongside addressing psychosocial challenges, to support the well-being of CLHIV. The study’s outcomes provide valuable insights for policymakers, healthcare providers, and organizations working with CLHIV, guiding future interventions and policies to uplift this vulnerable population.
Macro-regions in the Russian system of territorial administration: problems and prospects
Authors: Lavrikova YUliya  Georgievna , Suvorova Arina Valer'evna
Published: November 2024

The object of the study is the macroregion as one of the elements of the territorial management system, and its purpose is to identify the limitations and prospects for use in modern conditions of the zoning policy. Special attention is paid to determining the prerequisites for the successful implementation of this type of policy, carried out through the prism of an analysis of both Soviet and modern approaches to the allocation of macro-regions in the country's space. An important place in the conducted research is also occupied by the identification of a number of conceptual provisions that ensure the effectiveness of the implemented zoning policy, which makes it possible to use the results of the work carried out in the activities of authorities at various levels, which form and implement a system of measures aimed at ensuring the spatial development of the country and its individual territorial units. The theoretical and methodological basis of the study is a set of scientific ideas in the field of regional economics and public administration, and its methodological base includes methods of synthesis and scientific abstraction. As a result of the conducted research, a method of express analysis of the implemented zoning policy is proposed, based on the characteristics of the triad of components of its success: target setting, criteria, mechanisms for achieving goals. It is shown that in Soviet practice, all the elements of this triad can be considered clearly defined and interrelated with each other; in the case of federal districts, the triad is transformed: one of its elements falls out of the system, which, nevertheless, does not significantly affect the resulting effect. The analysis of the approach to the allocation of macroregions proposed in the Spatial Development Strategy of the Russian Federation is carried out, which allows us to conclude that each element of the triad "goal – criteria – mechanisms" of the emergence of macroregions can be seriously criticized, which causes the lack of influence of this process on the situation in the country. The possibility of using a project approach to the formation and development of macroregions in modern rapidly changing conditions, involving their consideration as temporary associations, the rules of functioning of which are subordinated to the achievement of a specific and ambitious goal, is substantiated. A number of conceptual provisions are characterized that ensure the success of the implemented zoning policy and are based on the need to pay attention to each element of the proposed triad.
Students’ Experiences of Navigating Online Teaching Practice Modules
Authors: Kotze Christy Jean , Meeran Safura
Published: November 2024

Globally, more and more institutions are moving to offer Comprehensive Open Distance e-Learning (CODeL) opportunities for distance education (DE) students. With this move to an online mode of teaching and learning, the focus has also shifted from a teacher-centred DE pedagogy to a student-centred ODeL pedagogy, with a strong focus on student success through improved student support to promote SDG4 (quality education for all). With an aim to improve the support offered to ODeL students in a South African context, the authors of this article set out to investigate student teacher experiences of teaching practice modules in an ODeL environment. This qualitative case study investigated the experiences of 30 student teachers studying teacher education at an ODeL institution. The module evaluation forms of students from two teaching practice modules were used to collect data. While literature revealed a need for improved student support in an ODeL context, research is limited on the support needs of student teachers in their ODeL teaching practice modules, which necessitated this research. The findings of this study revealed students struggled with online placement for their teaching practice, had varied experiences with online communication within the module, and had an overall positive experience with ODeL learning. We recommend that online tools be upgraded to make it easier for students to use and that there needs to be a diverse system of communication to meet the needs of all students. We believe that fully online teaching practice systems will open up future research activities
Popularization of Russian Culture and Development of Librarianship: To the 200th Anniversary of Vladimir Vasilyevich Stasov
Authors: Likhomanov Anton V.
Published: November 2024

The activity of the outstanding Russian art and music critic V.V. Stasov (1824—1906) is considered. In 2024 the 200th anniversary of his birth is celebrated. V.V. Stasov was closely connected with the “Mighty Handful” group of composers (he helped to create subjects for operas) and members of the Association of Travelling Art Exhibitions (he selected material for paintings). V.V. Stasov promoted the achievements of Russian art in our country and abroad. Having given more than 50 years of his life to service in the Imperial Public Library, V.V. Stasov made an invaluable contribution to its development: during the years of his work the volume of collections of the art department of the library, which was headed by the scientist in 1872—1906, increased by one third, a unique collection of engraved portraits of Peter the Great was formed, a clear system of catalogues was established, etc.

V.V. Stasov was always an active defender of the interests of the Imperial Public Library, striving to do everything in his power to improve the service to readers and the system of placing the collections.
ЭКОХИМИЧЕСКОЕ ИЗУЧЕНИЕ ПРОБ ВОДЫ, ВЗЯТЫХ В САБИРАБАДСКОМ РАЙОНЕ ИЗ РЕКИ АРАЗ
Authors: М.А. Набиева , С.Р. Гаджиева , Н.Т. Шамилов , Т.И. Алиева
Published: November 2024

С целью оценки современного экологического и химического состояния реки Араз и проведения дальнейших научных исследований были взяты пробы воды в Сабирабадскомрайоне, также известном как участок «Суговушан», где сходятся реки Кура и Араз. Собранные пробы воды были проанализированы на предмет физических и химических показателей, таких как температура, мутность, электропроводность, общее количество растворенных твердых веществ, растворенный кислород, щелочность, pH, а также количество сульфатов, хлоридов, нитратов, нитритов, фосфат-анионов и ионов аммония. Для измерения количества фосфат-, хлорид- и сульфат-ионов в пробах воды использовали стандартный титриметрический метод. Дополнительно количество тяжелых металлов в пробах определялось с использованием стандартного метода EPA 200.7: Определение металлов и микроэлементов в воде методом атомно-эмиссионной спектрометрии с индуктивно связанной плазмой. Суммарные углеводороды и полициклические ароматические углеводороды (ПАУ) определяли методом жидкостной экстракции и газовым хроматографом с пламенно-ионизационным детектором.

In order to evaluate the current biological and chemical state of the Araz River and to carry out further scientific research, water samples were collected from the Sabirabad region, also known as the «Sugovushan» location, where the Kura and Araz rivers converge. The collected water samples were analyzed for physical and chemical indicators such as temperature, turbidity, electrical conductivity, total dissolved solids, dissolved oxygen, alkalinity, pH, and the amounts of sulfate, chloride, nitrate, nitrite, phosphate anions, and ammonium ions. To measure the quantity of phosphate, chloride, and sulfate ions in water samples, a standard titrimetric technique was employed. Additionally, the amount of heavy metals in the samples was ascertained using the EPA 200.7: Determination of metals and trace elements in water by inductively coupled plasma-atomic emission spectrometry method. Total hydrocarbons and polycyclic aromatic hydrocarbons (PAH) were determined by liquid extraction method and gas chromatograph with flame ionization detector.
ПРОИСХОЖДЕНИЕ ПОЛИЦИКЛИЧЕСКИХ АРОМАТИЧЕСКИХ УГЛЕВОДОРОДОВ В ПОВЕРХНОСТНЫХ ВОДАХ И ДОННЫХ ОТЛОЖЕНИЯХ БАЙКАЛЬСКОЙ ПРИРОДНОЙ ТЕРРИТОРИИ
Authors: М.Ю. Семенов , И.И. Маринайте , Ю.М. Семенов
Published: November 2024

Цель исследования заключалась в выявлении происхождения полициклических ароматических углеводородов (ПАУ) в поверхностных водах и донных отложениях. Концентрации четырех приоритетных ПАУ в пробах были измерены с использованием газовой хроматографии с масс-спектрометрическим детектированием. Выявление источников ПАУ производилось на основе величин отношений концентраций маркерных ПАУ. Установлено, что высокие концентрации ПАУ обусловлены высокой плотностью населения, в то время как низкие концентрации ПАУ - малой плотностью. Также установлено, что точность идентификации источников ПАУ в значительной степени зависит от уровня загрязнения и выбранного маркерного отношения концентраций ПАУ. Кроме того, установлено, что из-за разной устойчивости отдельных ПАУ к разложению результаты выявления источников выбросов являются весьма условными.
ЭФФЕКТИВНОСТЬ РЕАЛИЗАЦИИ ПРОЕКТНОЙ ДЕЯТЕЛЬНОСТИ В ВУЗЕ НА ПРИМЕРЕ ПРОВЕДЕНИЯ КОНКУРСА ВИДЕОРОЛИКОВ
Authors: Ю.В. Бубнова
Published: November 2024

Статья посвящена актуальным проблемам реализации проектной деятельности в вузе. Цель данной работы – показать ее эффективность, раскрыть преимущества применения данного метода обучения в вузе и определить его значимость в развитии гармоничной личности и в профессиональной подготовке будущих специалистов.
ПРИМЕНЕНИЕ И ПРАКТИКА РЕЗУЛЬТАТИВНО-ОРИЕНТИРОВАННОГО ПОДХОДА В ОБУЧЕНИИ РУССКОМУ ЯЗЫКУ НЕРУСИСТОВ В КИТАЙСКИХ ВУЗАХ
Authors: Л. Ван
Published: November 2024

В данной статье рассматривается применение результативно-ориентированного подхода (production-oriented approach, далее – POA) в обучении русскому языку нерусистов в китайских вузах. Основная цель – решить проблему разрыва между знаниями и практикой в традиционном обучении иностранным языкам. В статье дается обзор истории развития и основных аспектов теории POA как оригинальной китайской теории обучения иностранным языкам, подробно анализируется конкретное применение теории POA в обучении русскому языку нерусистов в китайских вузах, включая проектирование и реализацию этапов мотивации, поддержки и оценки на уроке, подводятся итоги о преимуществах теории POA в повышении языковых навыков учащихся и отмечаются аспекты, требующие особого внимания.
РОЛЬ ТВОРЧЕСКОГО ПОДХОДА В ОБУЧЕНИИ ИНОСТРАННОМУ ЯЗЫКУ СТУДЕНТОВ В НЕЯЗЫКОВОМ ВУЗЕ
Authors: Е.В. Щекочихина
Published: November 2024

В статье рассматривается возможность реализации творческого подхода при обучении иностранному языку студентов неязыковых направлений. Автор приводит примеры применения активных и интерактивных методов на занятиях иностранным языком. Внимание уделяется вопросу о том, как подобные методы работы могут реализовать творческий потенциал студентов, активизировать учебно-познавательную деятельность и повысить мотивацию и интерес обучающихся к изучению иностранного языка.
Préface
Authors: Bohas Georges
Published: November 2024

Lors du colloque La Submorphologie motivée de Georges BOHAS : vers un nouveau paradigme en sciences du langage du 3 juin 2022, certains intervenants s’étaient contentés de reprendre (en résumant ou développant) leur participation à l’ouvrage La Submorphologie Motivée De Georges Bohas - Vers Un Nouveau Paradigme En Sciences Du Langage (2021), d’autres avaient présenté des communications originales qui sont publiées ici. Mise à part la dernière, ces communications se situent toutes à des degrés divers dans le cadre des études de linguistique submorphémique et de la motivation du signe linguistique.
Les onomatopées et la distinction langue/parole
Authors: Meinard Maruszka Eve-Marie
Published: November 2024

La motivation du signe linguistique est une notion saussurienne considérée comme la propriété définitoire principale de l’onomatopée. Cependant, les nombreuses recherches consacrées à la motivation ont démontré l’omniprésence de ce phénomène, de l’échelle du phonème à l’échelle du discours, en passant par le submorphème. Comment, dans ce cas, la motivation pourrait-elle permettre de circonscrire le fait onomatopéique? Nous avons dirigé notre attention vers la dichotomie langue/parole. Il sera montré que l’onomatopée se distingue des autres signes linguistiques dans sa propension à être définie différemment selon qu’on l’observe en langue, en parole, et comme nous le défendrons, en corpus. À l’occasion d’un colloque principalement consacré aux recherches sur la motivation et l’iconicité dans le lexique, cette présentation exposera une approche théorique où la partie du discours la plus emblématique de la motivation du signe se trouve finalement décrite à l’aune de ses statuts en langue et en parole.
Les séquences s, f, st et la question de l’être: notes de lecture submorphémique
Authors: Neyrod Dominique
Published: November 2024

On observe que dans le discours heideggérien les différentes déterminations de l’Être sont largement articulées au moyen de la séquence ‘st’ dans les verbes ‘stand’, ‘stellen’, ‘stehen’ et tous leurs composés, ainsi que dans certaines formes (‘west’, ‘ist’) du paradigme du verbe ‘sein’. Racine indo-européenne porteuse du sens de stabilité, de permanence, représentation iconique du temps, incarnation de la notion de limite, de terme d’un processus, la séquence ‘st’ apparaît chez Heidegger propre à dire le ‘Sein’ et la ‘Phusis’ et nous le suivrons sur ce chemin dans la première partie de cet article. Dans la deuxième partie, nous nous intéresserons aux séquences ‘f’ et ‘s’ présentes dans ‘phusis’: nous considérons qu’elles forment avec ‘st’ un groupe de submorphèmes dotés d’une forte motivation dans le cadre de la quête de l’Être poursuivie par Heidegger et nous proposons en conclusion de les envisager comme parole matricielle et comme expérience vitale incarnée.
Le projet dictionnaire des séquences bilitères initiales de l’arabe classique
Authors: Rolland Jean-Claude
Published: November 2024

On avait depuis longtemps constaté que des racines arabes parasynonymes avaient une séquence bilitère en commun, généralement la séquence initiale. Ce constat a abouti à la Théorie des étymons et matrices de Georges Bohas. Il était temps de procéder à une étude exhaustive des séquences initiales qui seule permettrait de valider définitivement cette théorie.Le Dictionnaire arabe-français de Kazimirski offrait la garantie d’un honnête corpus de données. Le travail en cours, réalisé aux trois quarts, consiste à rassembler en un même chapitre tous les items lexicaux dotés de la même séquence initiale, à les regrouper en racines, noms-bases, termes scientifiques ou techniques, et emprunts. Les racines, le plus souvent polysémiques, sontfractionnées, réorganisées et regroupées en fonction de leurs sens. Les items isolés apparaissant comme relevant d’une autre séquence radicale y sont renvoyés.
The Pedagogical Tipiṭaka: OER & the Three Baskets of Ancient Language Instruction
Authors: B.Krause Todd , C.Boas Hans , Law Danny
Published: November 2024

Ancient languages present a unique teaching challenge: for spoken languages, common pedagogy recommends engaging students via dialogue; for ancient languages, no speakers survive with whom to practise. This paper highlights how the Linguistics Research Center at the University of Texas at Austin has approached this challenge by creating the Early Indo-European OnLine (EIEOL) collection, an online educational resource whose lesson series present early languages directly through original, unsimplified ancient texts. Currently accessed by over 20,000 users per month, EIEOL spans 18 languages, from Greek and Latin to Old Church Slavonic, Sanskrit, and other important languages of ancient Asia such as Hittite, Classical Armenian, Avestan, and Tocharian. Each series presents extensively annotated excerpts of original texts in the target language, with accompanying modules explaining grammar and context. The text-centred approach affords learners a direct path to understanding that suits a variety of experience levels and minimises the conceptual grammatical apparatus necessary to begin interpreting original texts. This format fosters theoretical flexibility, adaptable to different approaches and grammatical descriptions of ancient languages. It is also useful for languages whose grammatical structures have shifted dramatically over their history, like Tocharian, or remain hotly debated or under-described by experts. Finally, it facilitates applications to typologically diverse languages and language families, with early Mesoamerican, Semitic, and Sino-Tibetan language series already under development. The EIEOL infrastructure therefore provides a robust platform for free, text-centred, self-paced introductions to ancient languages from a variety of language families.
Towards a Pedagogy of Ancient Egyptian Language and Hieroglyphs
Authors: Mosleth King Maiken
Published: November 2024

This paper discusses the challenges of teaching the Middle Egyptian language and Egyptian hieroglyphs to adult anglophone learners outside university settings. These challenges include the lack of L1 speakers; the large volume of signs in the script; the difficulty in reconstructing pronunciation due to the paucity of written vowels; and the lack of accessible learning tools such as readers and textbooks for the intermediate stage. As spoken proficiency in this extinct language is not a feasible goal, it is argued here that teaching should revolve around achieving reading competence.
The paper advocates for a pedagogical approach that centres on using vocabulary, including variant spellings, as the fundamental building blocks of learning. This entails reading words, sentences and paragraphs of increasing complexity, which over time aids memorisation of vocabulary and builds confidence. Grammar and syntax can be gradually introduced and contextualised by reading practice sentences. It is also argued here that producing digitised versions of ancient Egyptian texts using hieroglyphic font software such as JSesh allows for the creation of practice texts in a standardised and legible format. This, in turn, makes it possible to use pedagogical aids such as adding spaces between words and adding signs omitted by the ancient scribes.
Finally, it is argued that learning vocabulary and grammar is enhanced by discussions of the wider semantic and cultural meaning(s) of the ancient text in question.
The Language Teachers’ Committee Workshops: an Oxford Case Study
Authors: Çakır Emine , Kaji Hiroe
Published: November 2024

This study briefly recounts the journey of the teacher-led Language Teachers’ Committee (LTC) workshops that started in 2015 as a simple space for the language teachers of less commonly taught languages at the Faculty of Asian and Middle Eastern Studies (AMES), University of Oxford, to find out more about how individual teachers teach their specific target language, but that later developed into a platform for Continuous Professional Development (CPD) to share best practice and scholarship, and even went beyond these.
During the LTC workshops, teachers discovered resources they already had while reflecting on, appreciating, embracing, and enriching them; this had a positive impact on teachers’ wellbeing, future actions, and crucial joint professional decisions. The platform was not only important to overcome or ease challenging times like the COVID-19 pandemic when language teachers had to switch to online teaching overnight, but it also led to more sustainable kinds of impact, such as raising awareness to the fundamental rights of language teachers as part of their wellbeing.
Thus, this paper aims to give a chronological outline of and insights into the last twenty-five years of an HE institution in the UK that has been shaping/affecting the wellbeing of its language teachers. It endeavours to set an example and to raise awareness of the importance of language teaching and to rethink the position of language teachers in the academic world.
القيادة الرقمية وعلاقتها بإدارة التغيير بالمدارس الابتدائية الحكومية بمدينة الرياض من وجهة نظر المعلمات والمديرات
Authors: القحطاني فضة سعيد , العريفي حصة سعد
Published: November 2024

هدفت الدراسة إلى التعرف على درجة ممارسة أبعاد القيادة الرقمية وطبيعة العلاقة الارتباطية بينهما لدى مديرات المدارس الابتدائية الحكومية بمدينة الرياض، استخدمت الباحثة المنهج الوصفي الارتباطي، واستبانة تم توزيعها على عينة من (307) مديرات ومعلمات، توصلت الدراسة لعدد من النتائج هي: حصل ممارسة مديرات المدارس الابتدائية الحكومية بمدينة الرياض لأبعاد القيادة الرقمية على متوسط عام (3.41 من 5)، بتقدير (كبيرة)، وعلى مستوى الأبعاد جاء مستوى الوعي الرقمي بمتوسط (3.44)، ثم القيادة الرقمية للأعمال الإدارية بمتوسط (3.32)، وأخيراً الموارد البشرية الرقمية بمتوسط (2.55)،فيما حصل ممارسة المديرات لأبعاد إدارة التغيير على متوسط عام (3.26 من 5) بتقدير (متوسطة)، وقد جاء ترتيبها (بُعْد علاقة المدرسة بالمجتمع بمتوسط (3.36)، ثم بُعْد القيادة المدرسية بمتوسط (3.27)، وأخيرا بُعْد التخطيط الاستراتيجي بمتوسط (3.15). توجد علاقة طردية بلغت (84.) وتعكس علاقة (قوية)، (موجبة) بين كلٍّ من أبعاد القيادة الرقمية، وبين أبعاد إدارة التغيير، بناء على النتائج أوصت الباحثة مديرات ومعلمات المدارس باستخدام وسائل وتطبيقات رقمية متنوعة لانجاز مهامهم الادارية؛ من أجل بناء بيئة رقمية بالمدارس يتم من خلالها تطبيق ابعاد القيادة الرقمية، كما قدمت مقترحات بدراسات مكملة في الموضوع.
التفكير الإيجابي وعلاقته بأبعاد الصحة النفسية لدى طالبات كلية التربية في جامعة حائل
Authors: المطاوع ملكه مرضي
Published: November 2024

هدفت هذه الدراسة إلى التعرف على مستوى التفكير الإيجابي ومستوى أبعاد الصحة النفسية والعلاقة بينهما لدى طالبات كلية التربية في جامعة حائل، واتبعت الدراسة المنهج الوصفي الارتباطي، وتكونت عينة الدراسة من (203) طالبة، تم اختيارهن بطريقة العينة العشوائية الطبقية، وتمثلت أدوات الدراسة في: مقياس التفكير الإيجابي إعداد الوليد أحمد (2019)، ومقياس الصحة النفسية إعداد السيد يوسف (1998). وأظهرت نتائج الدراسة وجود درجة عالية من التفكير الإيجابي لدى عينة الدراسة بمتوسط حسابي (3.92)، ودرجة عالية من الصحة النفسية بمتوسط (0.82). كما وجدت علاقة ارتباطية موجبة ذات دلالة إحصائية بين التفكير الإيجابي وأبعاد الصحة النفسية لدى طالبات كلية التربية في جامعة حائل. وفي ضوء نتائج أوصت الباحثة بإدماج مفاهيم التفكير الإيجابي في جميع المناهج، وفقًا للمرحلة الدراسية ونوع المادة، وذلك لتعزيز الصحة النفسية، وإقامة مؤتمرات دورية تستقطب مجموعة متحدثين من ذوي التفكير الإيجابي، وضرورة تشجيع الطلاب والطالبات على تطبيق مفاهيم التفكير الإيجابي في سياقات واقعية وتبني مواقف إيجابية تجاه التحديات وتعزيز الاستعداد للتعامل مع النجاح والفشل بشكل صحيح، مما ينعكس بشكل إيجابي على صحتهم النفسية.
معوقات تطبيق مجتمعات التعلم المهنية لدى معلمي مدارس وكالة الغوث الدولية في منطقة القدس؛ أريحا من وجهة نظرهم
Authors: مربوع سحر سعيد
Published: November 2024

هدفت الدراسة إلى الكشف عن معوقات تطبيق مجتمعات التعلم المهنية لدى معلمي مدارس وكالة الغوث الدولية في منطقة القدس؛ أريحا من وجهة نظرهم؛ ولتحقيق ذلك استخدمت الباحثة المنهج الوصفي التحليلي، وتمثلت الأداة في استبانة تكونت من (36) عبارة، تمثل ثلاثة مجالات لمعوقات تطبيق مجتمعات التعلم المهنية تم توزيعها على عينة عشوائية بلغت (100) معلم ومعلمة، وأظهرت نتائج الدراسة أن معوقات تطبيق مجتمعات التعلم المهنية جاءت بمتوسط كلي (3.15)، وبدرجة (متوسطة)، وحصل مجال المعوقات المرتبطة بالبيئة المدرسية على أعلى متوسط(3.47) وبدرجة كبيرة، يليه المعوقات المرتبطة بالمعلم بمتوسط (3.04)، ثم المعوقات المرتبطة بالإدارة المدرسية بمتوسط (2.92)، وكلاهما بدرجة متوسطة كما أظهرت النتائج وجود فروق ذات دلالة إحصائية عند مستوى 0.05) ≥ (α حول معوقات تطبيق مجتمعات التعلم المهنية، تبعاً لمتغير الجنس، ولصالح الذكور، وتبعاً للمؤهل العلمي، ولصالح حملة الماجستير، وعدم وجود فروق تبعاً لمتغير سنوات الخدمة على جميع المجالات، وفي ضوء النتائج أوصت الباحثة بضرورة تدريب وتأهيل العاملين لتطبيق مجتمعات التعلم المهنية، وتعاون الإدارة معهم لتفعيلها. واستناداً إلى نتائج هذه الدراسة، يجدر النظر في بعض القضايا التي ظهرت، بالإضافة إلى إجراء مزيد من الدراسات في هذا المجال.
Unveiling JP-10 Fuel: A DFT and NMR Study of Exo-TCD Chair and Boat Conformers
Authors: Wang Feng , Vasilyev Vladislav
Published: November 2024

The rational design of high-energy-density (HED) sustainable aviation fuels (SAFs) relies on understanding the electronic structures of fuel hydrocarbons. This study uses density functional theory (DFT) to investigate the exo-chair and exo-boat isomers of Jet Propellant 10 (JP-10). The exo-chair isomer is found to be more stable by 1.83 kcal/mol, with an energy barrier of 3.65 kcal/mol separating the two using the B3LYP/cc-pVTZ method. Despite small geometric differences, significant changes in the shape, dipole moments (0.0156 Debye for the exo-chair and 0.0426 Debye for the exo-boat) and NMR chemical shifts at the flag carbon (C5), the boat tip carbon (C10) and the hydrogens bonding with them. The B3PW91/cc-pVTZ method produces more accurate carbon NMR chemical shifts than the B3LYP/cc-pVTZ method, RMSD (C) =1.48 ppm and 3.21 ppm, respectively, whereas the reverse holds for the proton-NMR chemical shifts, RMSD (H) =0.33 ppm and 0.31 ppm, in agreement with early studies. The NMR trajectories during the chair and boat transition reveal the most significant changes at the transition state (TS). In addition, the carbon atoms engaging larger strain (eg junction carbons and the flag carbon) exhibit apparent deshielding. Excess orbital energy spectrum (EOES) analysis further identifies key inner valence orbital changes during isomerization, indicating the role of bonding interactions in stabilizing the exo-chair isomer. These findings offer valuable insights into the electronic structural factors that influence the stability of multicyclic hydrocarbons, aiding the future design of more efficient SAFs.
Unraveling Defect-Dependent Conductivity-Type Switching in CuFe2O4 for Enhanced Photoelectrocatalytic Reduction of Benzaldehyde
Authors: Huang Yen-Chun , Fong Jun-Lin , Reyes Abdul M. , Reyes-Lillo Sebastian E. , Jiang Chang-Ming
Published: November 2024

Photoelectrocatalytic (PEC) reduction of carbonyl-containing compounds provides a sustainable approach to upgrading biomass-derived feedstocks with reduced energy requirements. However, PEC reduction has primarily focused on hydrogen evolution and carbon dioxide reduction reactions, limited by the availability of stable photocathode materials. In this study, we demonstrate the extended PEC performance of defect-engineered CuFe2O4 films, achieving over 18 hours of stable benzaldehyde reduction to benzyl alcohol. Modulating CuFe2O4 conductivity from n-type to p-type through controlled annealing conditions enhanced its hole concentration, achieving a cathodic photocurrent density of 1.5 mA/cm2 at 0.5 V vs. RHE. Using 1,4-benzoquinone as a redox mediator in a mixed acetonitrile/water electrolyte, the PEC system produced benzyl alcohol at a rate of 2.57 μmol/h with a Faradaic efficiency of 51.3% at 0.50 V vs. Ag/AgNO₃. Photoelectrochemical impedance spectroscopy (PEIS) revealed that oxygen-rich annealing conditions improved charge transport and surface catalytic activity, resulting in a threefold increase in benzyl alcohol production rate. This PEC approach lowered the required applied potential by ~1 V compared to traditional electrocatalysis methods, offering a more energy-efficient route for carbonyl reduction. These findings underscore the potential of CuFe₂O₄ as a viable photocathode material for sustainable organic transformations under mild reaction conditions.
Bonded water is an integral component of dissolved organic matter in the ocean
Authors: Lu Kaijun , You Xiao , Guo Laodong , Baiz Carlos , Liu Zhanfei
Published: November 2024

Dissolved organic matter (DOM) in the ocean, as one of the largest pools of reduced carbon on Earth, plays an important role in the global carbon cycle, yet its chemical structure remains largely unknown. Here we show that high molecular weight DOM (HMW-DOM) contains approximately 10% bonded water (H2O) by weight. The bonded H2O molecules are an integral part of the DOM organic complex, likely maintained through strong intermolecular hydrogen bonds, as the H2O is not released during freeze drying and barely exchangeable with surrounding H2O in solution. When the bonded H2O was removed by mild heating (70 °C), the HMW-DOM became more bioavailable as shown by laboratory incubation experiments. These findings suggest that the bonded H2O plays a key role in regulating the stability and biogeochemical cycling of DOM in the ocean.
FCIQMC–CASPT2 with Imaginary–Time–Averaged Wave Functions
Authors: Safari Arta , Anderson Robert , Alavi Ali , Li Manni Giovanni
Published: November 2024

A new method to perform complete active space second–order perturbation theory on–top of large active spaces optimised with full configuration quantum Monte Carlo is presented. Three– and four–particle density matrices, including contractions with the Fock matrix, are computed from imaginary–time–averaged wave functions, which resolves fermionic positivity violations and ensures numerical stability. The protocol is applied to [NiFe]$^{2-}$ , [Cu(NH$_3$)]$_2$O$_2^{2+}$ and Fe–porphyrin model systems up to 26 electrons in 27 orbitals and benchmarked against DMRG–CASPT2.
Enhanced Upconversion and Photoconductive Nanocomposites of Lanthanide-Doped Nanoparticles Functionalized with Low-Vibrational-Energy Inorganic Ligands
Authors: Pan Jia-Ahn , Qi Xiao , Chan Emory
Published: November 2024

Upconverting nanoparticles (UCNPs) convert near-infrared (IR) light into higher-energy visible light, allowing them to be used in applications such as biological imaging, nano-thermometry, and photodetection. It is well known that the upconversion luminescent efficiency of UCNPs can be enhanced by using a host material with low phonon energies, but the use of low-vibrational-energy inorganic ligands and non-epitaxial shells has been relatively underexplored. Here, we investigate the functionalization of lanthanide-doped NaYF4 UCNPs with low-vibrational-energy Sn2S64- ligands. Raman spectroscopy and elemental mapping are employed to confirm the binding of Sn2S64- ligands to UCNPs. This binding enhances upconversion efficiencies up to a factor of 16, consistent with an increase in the luminescent lifetimes of the lanthanide ions. Annealing Sn2S64--capped UCNPs results in the formation of a nanocomposite comprised of UCNPs embedded within an interconnected matrix of SnS2, enabling each UCNP to be electrically accessible through the semiconducting SnS2 matrix. This facilitates the integration of UCNPs into electronic devices, which we demonstrate through the fabrication of a UCNP-SnS2 photodetector that detects UV and near-IR light. Our findings show the promise of using low-phonon inorganic capping agents to enhance the properties of UCNPs while assisting their integration in optoelectronic devices.
Comment on “Localized and Delocalized States of a Diamine Cation: Resolution of a Controversy”
Authors: Phun Gabriel , Wong Bryan
Published: November 2024

Since its appearance in [Cheng, X.; Zhang, Y.; Jónsson, E.; Jónsson, H.; Weber, P. M. Nat. Commun. 2016, 7, 11013] and recently re-visited in [Gałyńska, M.; Ásgeirsson, V.; Jónsson, H.; Bjornsson, J. Phys. Chem. Lett., 2021, 12, 1250-1255], the dimethylpiperazine cation (DMP+) has generated considerable discussion and controversy in the scientific literature over the existence of stable, local energy minima in this molecular system. Specifically, prior assumptions that the Rydberg state and radical cation of DMP are similar have led to significant confusion and debate regarding the accuracy of various quantum chemistry methods and the existence of stable configurations of DMP+ itself. The purpose of this Viewpoint article is to highlight recent studies that call into question the main findings in the previously mentioned works as well as present new CCSDT (Coupled-Cluster with Single and Double and full Triple excitations) to finally bring closure to this controversy.
Potassium Isopropyl(trimethylsilyl)amide and Potassium tert-Butyl(trimethylsilyl)amide: Solvent-Dependent Solution Structures and Reactivities
Authors: Spivey Jesse , Collum David
Published: November 2024

Potassium isopropyl(trimethylsilyl)amide (KPTA) and potassium tertbutyl(trimethylsilyl)amide (KBTA) were prepared as stable 1.0 M stock solutions in Et3N or isolable crystalline solids. A combination of the Method of Continuous Variations and a heavy reliance on 29Si NMR spectroscopy revealed solventdependent dimers and monomers. DFT computations offered insights into the solvation. Weakly coordinating solvents such as toluene and triethylamine afford dimers. In THF, KPTA is dimeric whereas KBTA is dimeric at low THF concentration and monomeric in neat THF. Chronic and often poorly understood loss of the 29Si resonance made a broadly based, systematic study difficult and may have obscured deaggregation or ionization. Reactivity was probed using orthometalations by KBTA, which pressed the limits of its basicity and probably impacted the yields in some cases.
Neural Network-Based Interatomic Potential for the Study of Thermal and Mechanical Properties of Siliceous Zeolites
Authors: Brugnoli Luca , Ducamp Maxime , Coudert François-Xavier
Published: November 2024

Molecular dynamics simulations of zeolites are commonly employed for the characterization of their framework dynamics and response to the application of temperature and pressure. While classical interatomic potentials are commonly used for this task, they offer a description of the interactions in the system with limited accuracy. Density Functional Theory, meanwhile, is accurate but its high computational expense limits its scalability for large systems or long dynamics. Recent advances in machine learning interatomic potentials, trained on computational data obtained at the quantum chemical level, offer a promising alternative combining high accuracy with computational efficiency. In this study, we developed an MLIP specifically for pure silica zeolites, trained on data from high- temperature ab initio MD simulations across various zeolitic topologies. This MLIP was then applied to predict structural properties, thermal expansion, and pressure response of different zeolites, demonstrating its potential for accurate and generalizable in simulations of topologies beyond its initial training set.
Trajectory-based Non-adiabatic Simulations of the Polariton Relaxation Dynamics
Authors: Hu Deping , Chng Benjamin , Ying Wenxiang , Huo Pengfei
Published: November 2024

We benchmark the accuracy of various trajectory-based non-adiabatic methods in simulating the polariton relaxation dynamics under the collective coupling regime. The Holstein-Tavis-Cummings (HTC) Hamiltonian is used to describe the hybrid light-matter system of N molecules coupled to a single cavity mode. We apply various recently developed trajectory-based methods to simulate the population relaxation dynamics by initially exciting the upper polariton state, and benchmark the results against populations computed from exact quantum dynamical propagation using the hierarchical equations of motion (HEOM) approach. In these benchmarks, we have systematically varied the number of molecules N , light-matter detunings, and the light-matter coupling strengths. Our results demonstrate that the symmetrical quasi-classical method with γ correction (γ-SQC) and spin-mapping linearized semi-classical (spin-LSC) approaches yield more accurate polariton population dynamics than traditional mixed quantum-classical (MQC) methods such as the Ehrenfest and surface hopping techniques.
Active learning meets metadynamics: Automated workflow for reactive machine learning potentials
Authors: Vitartas Valdas , Zhang Hanwen , Juraskova Veronika , Johnston-Wood Tristan , Duarte Fernanda
Published: November 2024

Atomistic simulations driven by machine learning-based potentials (MLPs) are a cost-effective alternative to ab initio molecular dynamics (AIMD). Yet, their broad applicability in reaction modelling remains hindered, in part, by the need for large training datasets that adequately sample the relevant potential energy surface, including high-energy transition state (TS) regions. To optimise dataset generation and extend the use of MLPs for reaction modelling, we present a workflow that combines automated active learning with well-tempered metadynamics, requiring no prior knowledge of TSs. Using data-efficient architectures, such as the linear Atomic Cluster Expansion, we illustrate the performance of this strategy in various organic reactions where the environment is described at different levels, including the SN2 reaction between fluoride and chloromethane in implicit water, the methyl shift of 2,2-dimethylisoindene in the gas phase, and a glycosylation reaction in explicit dichloromethane solution, where competitive pathways exist. The proposed training strategy yields accurate and stable MLPs for all three cases, highlighting its versatility for modelling reactive processes.
Photoresponsive Carbodiimide-Fueled Transiently Crosslinked Polymer Hydrogels
Authors: Raji Ibrahim O. , Wilcox Torin , Hartley C. Scott , Konkolewicz Dominik
Published: November 2024

Light- and carbodiimide-responsive hydrogels were synthesized. An “AND” gate was developed using ortho-nitrobenzyl (ONB) protected carboxylic acids in the polymer backbone. Crosslinking was only realized in the presence of both UV stimulus to photocleave the ONB group and carbodiimide fuels to induce anhydride bonds. In the presence of water, the anhydride bonds eventually hydrolyze to carboxylic acids and the system returns to the solution state. The mechanical properties of the out-of-equilibrium hydrogels were investigated using oscillatory rheology to examine the effects of deprotection efficiency, carbodiimide concentration and chain architecture on the hydrogels’ moduli and decrosslinking time. Higher moduli and longer decrosslinking times were found with increased carbodiimide concentration and deprotection efficiency. These discoveries unveil new possibilities for photoresponsive chemically fueled soft materials.
Folklorisms in Contemporary Kazakh, Kyrgyz, and Uzbek Stories
Authors:   AL-FARABI KAZAKH NATIONAL UNIVERSITY, Akhmetova Gulnar
Published: November 2024

The article examines folkloric motifs as an active artistic unit describing the (post)colonial scene using comparative typological, qualitative interview, and genetic methods in contemporary Kazakh, Kyrgyz, and Uzbek stories. In the analyzed stories, superstitious prohibitions associated with the cult of the tree, the reasons for connecting toponymic legends with the work serve the interpretation of such folklore samples of diverse postcolonial significance, such as the motive of turning a person into a stone or mountain or mythical transformation. The wooden totem in the stories “The Tree of Life” by the rep-resentative of Uzbek literature, Muyassar Tilovova, and “The Deity of the Apple Tree” by the Kazakh writer Lira Konysa, taken as the object of study is defined as an archetypal image expressing historical periods, the national worldview of each people, then in the literary works “The Stone Bride” by Top-chugul Shaidullaeva and “Earth” by Sultan Raev demonstrates the mutual associative connection of the phenomena of the promised land, the native land in the consciousness of the ethnic group. Writer Serik Sagyntai’s “Monster,” in its theme, idea, and style, is considered a specific story based on a mourning motif about the deplorable situation of the Kazakhs in KarLag. The etymological aspect of the toponymic legend in the story “Stone Bride” by Isajon Sulton is comprehensively interpreted from a literary study perspective. During the analysis of the story, an examination of some views in science on the secrets of the universe and the miracle of nature, told concerning sacred places, was also studied. Along with the specificity inherent in the Turkic peoples in general, the images of sacred places and the holy tree, the native land, the mystical and religious properties, and the symbolic and semantic meaning of sacred objects are analyzed.
MODELING FOREIGN LANGUAGE CURRICULUM: INTERNATIONAL INTERNSHIP RESEARCH AND PROGRAM DEVELOPMENT
Authors:   AL-FARABI KAZAKH NATIONAL UNIVERSITY, Berkinbayeva Gulzat
Published: November 2024

The article investigates how internship research programs promote global partnerships, cultural exchanges, and human development, focusing on the Minnesota English Language Program (MELP) practices in designing adaptable foreign language curricula. The research demonstrates the importance of internships in enriching language programs and highlights how collaboration between international universities contributes to curriculum improvements. This approach aims to better prepare students for real-world communication, fostering language proficiency and intercultural understanding.The article delves into the MELP’s excellent practices in designing foreign language teaching cur-ricula adaptive to diverse contexts.The research studies the UMN and KBTU language course curricula and analyzes the survey data. The data provided statistical evidence to quantify identified features and shortcomings, contributing to a deeper understanding of the research questions.Based on the findings, the goal is to develop a new course curriculum for teaching the Kazakh lan-guage to non-native speakers in multicultural settings. The study adopts a mixed-methods approach, combining qualitative and quantitative methods, to comprehensively investigate the research objectives. Specifically, a survey was administered to 50 students from Narxoz University (Narxoz) and Kazakh-British Technical University (KBTU) to gather quantitative data on perceptions of the existing curriculum.
A few Words on the Issues of the Poetic Corpus of the Kazakh Language
Authors:   AL-FARABI KAZAKH NATIONAL UNIVERSITY, Malbakov Myrzabergen , Kobdenova Gulzhikhan , Assau Kairat
Published: November 2024

The article is devoted to the study of the problem of the poetic language of the constituent poetic corpus of the Kazakh language. The poetic features of the variants of the song "Kozy Korpesh – Bayan Sulu", taken as the main version, are analyzed. Examples from the poem "Kyz Zhibek" are partially given. The purpose, main direction and idea of the research is to reveal the poetic value of the variants of the poem "Kozy Korpesh – Bayan Sulu". The article uses methods of selection, systematization, division into lexico-semantic and thematic groups, structural, descriptive, semantic grouping, synchronous analysis, and construction. The article examines from a historical and poetic point of view selected versions of one of the oldest cultural relics of the Kazakh people, "Kozy Korpesh-Bayan Sulu", with a comparison among themselves. It is known that this epic is a common heritage for all Turkic peoples. For example, the Altaians, Bashkirs, and Tatars have preserved several versions of this lyric epic. As for the Kazakh versions of the poem, this poem was first published in the third volume of V.Radlov's work in 1870 "Samples of folk literature of Turkic tribes" and in 1876 by I.Berezin as part of the "Turkish Anthology". Many intellectuals, led by Sh. Ualikhanov, G.N.Potanin participated in publication and research of the epic. The results obtained during the study: 1) comparing the poetic language of the main versions of the epic, we find, as the most basic, ancient and artistic version, the version sung by Zhanak akyn; 2) issues related to the life and fate of the main characters of lyric-epic poems, such as "Kozy Korpesh-Bayan Sulu", "Kyz Zhibek" are identified; 3) it is proved who is actually a positive hero, since in different versions of the epic Sarybai and Karabai are perceived differently as positive and negative characters.