bluuebunny/crossref_metadata_2025 huggingface dataset:
A Comparative Study on Pasting and Hydration Properties of Native Rice Starches and Their Mixtures
Authors: Hagenimana Anastase , Ding Xiaolin
Published: June 2007

Four rice starches were isolated from waxy and nonwaxy rice cultivars collected from different places in China. Individual rice starches were examined, along with their corresponding mixtures in different ratios, in terms of pasting and hydration properties. Analysis by micro‐viscoamylography (MVAG) showed that waxy rice starch and its blends had higher peak viscosity (PV), breakdown (BD), and setback (SB) than the remaining starches and mixtures. Apparent amylose content (AC) was 16.95–29.85% in nonwaxy individual rice starches and 13.69–25.07% in rice starch blends. Incorporating waxy rice starch (25%) significantly decreased the AC. AC correlated negatively with swelling power (SP) (r = ‐0.925, P < 0.01). SP exhibited nonlinear relationship (r2 = 0.8204) with water solubility (WS) and both increased with temperature. The correlation showed that WS is also an index of starch characteristics and the granules rigidity affected the granule swelling potential. The results show that turbidity of gelatinized starch suspensions stored at 4 ± 0.5°C generally increased during storage up to five days.
Melt‐Intercalated Starch Acetate Nanocomposite Foams as Affected by Type of Organoclay
Authors: Xu Yixiang , Zhou Jiahua , Hanna Milford A.
Published: June 2007

Starch acetate nanocomposite foams with four organoclays (Cloisite 30B, 10A, 25A, and 20A) were prepared by melt‐intercalation methods. The structural properties, thermal behaviors, and mechanical properties were characterized by X‐ray diffraction (XRD), scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermogravimetry analyses (TGA), and Instron universal testing machine. XRD results indicated that the intercalation of starch acetate into the nanoclay layers occurred for all four clays. The extent of intercalation depended on the type of organoclay and was exhibited in the sequence of Cloisite 30B >10A >25A >20A. SEM results indicated a decrease in cell size in the starch acetate foam matrix with the addition of nanoclay. Glass transition temperature (Tg) and onset temperatures of thermal degradation increased with the addition of organoclay into the starch acetate matrix. The incorporation of organoclays decreased significantly the compressibilities of starch acetate nanocomposites and did not substantially affect their spring indices.
A Better Understanding of Factors That Affect the Hardness and Stickiness of Long‐Grain Rice
Authors: Cameron Devon K. , Wang Ya‐Jane
Published: June 2007

Eight U.S. long‐grain rice cultivars were studied for chemical compositions, physicochemical properties, and leaching characteristics in relation to hardness and stickiness of rice flour paste and cooked rice. There were differences in the chemical composition of rice kernels among the eight rice cultivars, including crude protein (6.6–9.3%), crude fat (0.18–0.51%), and apparent amylose content by iodine colorimetry (19.6–27.0%). Differences were also observed in gelatinization temperatures and enthalpies, pasting temperatures and viscosities, leached/insoluble amylose, soluble solids, and hardness and stickiness of rice flour pastes and cooked rice kernels. The quantity and molecular size distribution of the leached starch molecules varied greatly among the samples. Protein and crude lipid contents negatively correlated with hardness of rice flour paste and cooked rice, but positively correlated with stickiness. Apparent amylose content correlated with gel properties but not cooked rice texture, whereas the ratio of A and short B chains to long B chains of amylopectin correlated significantly with cooked rice texture.
Effect of Shortening Replacement with Oatrim on the Physical and Rheological Properties of Cakes
Authors: Lee Suyong , Kim Sanghoon , Inglett George E.
Published: June 2007

Oatrim (oat β‐glucan amylodextrins) was evaluated as a fat substitute in a cake system. The physical and rheological properties of cakes containing shortening replaced with 20, 40, and 60% by weight of Oatrim were characterized. The increase in the specific gravity of the cakes and the decrease in the viscosity as more shortening was replaced with Oatrim were correlated with the change in the cake volume. The number of air bubbles present in the cake batters varied significantly; however, the size of the observed bubbles did not change. The cakes containing more Oatrim displayed a higher starch gelatinization temperature due to the amylodextrins in the Oatrim. The dynamic rheological properties of the cakes were investigated during baking and correlated with the differential scanning calorimetry results. The oscillatory shear storage moduli decreased upon initial heating, then increased due to starch gelatinization, and finally reached a plateau value that varied based on the sample composition. Moreover, increased replacement of shortening with Oatrim resulted in higher observed oscillatory shear storage moduli. The cakes prepared with up to 20% by weight of Oatrim did not evidence significant changes in softness (P < 0.01) and generally exhibited similar physical properties to the control cake.
Determination of Surface Tension Properties of Wheat Endosperms, Wheat Flours, and Wheat Glutens
Authors: Blancher G. , Morel M. H. , Gastaldi E. , Cuq B.
Published: June 2007

During wheat dough processing, a large part of the interactions with water are governed by wettability properties of flour. The wettability properties of wheat materials (flat slices of wheat endosperm, flour‐based pellets, and gluten‐based pellets) were assessed by the measurement of contact angles of a sessile drop of three reference liquids (water, diiodomethane, and formamide) and estimated by equilibrium properties (contact angles and surface tension properties) and drop penetration rates. The surface tension (γs) of wheat materials was measured between 49.6 and 55.3 mJ/m‐2. The present work permitted the evaluation of specific wheat types (hard wheat vs. soft wheat) and evaluation of the influence of material structure (flat slices of endosperm vs. flour‐based pellets), and material nature (flour‐based pellets vs. gluten‐based pellets) on the wettability properties. The surface tension properties were considered with regard to the nonideal structure of sample surfaces by considering surface roughness and material porosity.
Characteristics of Starch from Eight Quinoa Lines
Authors: Lindeboom Nienke , Chang Peter R. , Falk Kevin C. , Tyler Robert T.
Published: June 2007

Starches ranging in amylose content from 3 to 20% from eight quinoa (Chenopodium quinoa Willd.) lines were characterized with respect to thermal, retrogradation, and pasting properties; swelling and solubility behavior; freeze‐thaw stability; water‐binding capacity; shear stability; and granule size and morphology. The starches differed in gelatinization onset temperatures, peak temperatures, and retrogradation tendencies; these characteristics were positively correlated with amylose content. No variation in gelatinization enthalpy was observed. With the exception of pasting temperature, large variations in pasting characteristics were found among starches and were correlated with amylose content. Swelling, solubility, freeze‐thaw stability, and water‐binding capacity also differed among starches and were correlated with amylose content. Granule morphology and size were similar for all starches. The wide variation in amylose content and physicochemical characteristics of quinoa starches suggests applications in a variety of food and nonfood products.
Heat Treatments of Milled Rice and Properties of the Flours
Authors: Takahashi Toru , Miura Makoto , Ohisa Naganori , Mori Katsumi , Kobayashi Shoichi
Published: June 2007

The effects of autoclave and oven treatments on the gelatinization of rice flour and on the rheological characteristics of its pastes were studied by differential scanning calorimetry (DSC), rapid viscoanalysis (RVA), and rotational viscometry. Flours from autoclave‐treated rice (ATR) and oven‐treated rice (OTR) were prepared, respectively, by heating at 120°C for 60 min and 160°C for 60 min followed by drying (ATR sample), and grinding at 2.2–12.9% moisture content. The rice flour dispersions were adjusted between pH 6.3 and 2.8 using 0.2M citrate buffer. The retort processing of rice flour in water pastes were done at 120°C for 20 min either once or twice. The gelatinization peak temperature (PT and To) and the peak temperature corresponding to the amylose‐lipid complexes (Tp3) of ATR increased at pH 6.3 and 2.8 compared with OTR and UTR flour. This indicates that the internal structures of the starch granules in ATR became more stable to heat and acid, even though the damaged starch content of ATR was 23% compared with 16 and 7%, respectively, for untreated rice flour (UTR) and OTR. The OTR flour pastes showed a gel‐like behavior at pH 4.5 after retort processing in water at 120°C for 20 min; however, the ATR mixture behaved more like a liquid paste. Decreases in the reducing sugar content of OTR and ATR pastes suggested that enzymes in the heat‐treated rice were denatured, which retarded the hydrolysis of glucose chains and the rupture of starch granules during pasting.
Rheological and Sensory Evaluation of Wheat Flour Tortillas During Storage
Authors: Bejosano Feliciano P. , Joseph Suman , Lopez Rita Miranda , Kelekci Nurettin N. , Waniska Ralph D.
Published: June 2007

Texture of wheat flour tortillas over 15 days at room temperature was evaluated using an expert sensory panel, consumer panels, subjective rollability test, large deformation rheological methods (i.e., bending, extensibility [1‐D and 2‐D], and puncture tests), and stress relaxation method. Most of the changes in texture occurred during the initial 8 days of storage, while texture of tortillas changed slowly thereafter. Differences in texture between fresh and 1‐day‐old tortillas were detected by many objective rheological methods but not by either sensory panel. The expert sensory panel observed a rapid decrease in tortilla extensibility and an increase in staleness between 1 and 8 days of storage and smaller changes in sensory scores after 8 days of storage. Most objective rheological parameters changed rapidly between 0 and 5 days, and slowly after 5 days of storage. Significant correlations and factor analysis reveal that changes occurring in flour tortillas during staling are estimated better by subjective rollability, sensory evaluation (expert and consumer panels), and 2‐dimensional extensibility test than by other methods. Hence, some rheological methods are useful to estimate sensory properties of flour tortillas.
Detection of Proteins in Starch Granule Channels
Authors: Han Xian‐Zhong , Benmoussa Mustapha , Gray Jonathan A. , BeMiller James N. , Hamaker Bruce R.
Published: June 2007

Proteins were detected in channels of commercial starches of normal maize, waxy maize, sorghum, and wheat through labeling with a protein‐specific dye and examination using confocal laser scanning microscopy (CLSM). The dye, specifically 3‐(4‐carboxybenzoyl)quinoline‐2‐carboxaldehyde (CBQCA), fluoresces only after it reacts with primary amines in proteins, and CLSM detects fluorescence‐labeled protein distribution in an optical section of a starch granule while it is still in an intact state. Starch granules in thin sections of maize kernels also had channel proteins, indicating that proteins are native to the channels and not artifacts of isolation. Incubation of maize starch with protease (thermolysin) removed channel proteins, showing that channels are open to the external environment. SDS‐PAGE analysis of total protein from gelatinized commercial waxy maize starch revealed two major proteins of about Mr 38,000 and 40,000, both of which disappeared after thermolysin digestion of raw starch. Commercial waxy maize starch granule surface and channel proteins were extracted by SDS‐PAGE sample buffer without gelatinization of the granules. The major Mr 40,000 band was identified by MALDI‐TOF‐MS and N‐terminal sequence analysis as brittle‐1 (bt1) protein.
Impact of a Reduced Wheat Meal Sample Size on the Falling Number Test
Authors: Hatcher D. W.
Published: June 2007

The impact of a smaller sample of whole meal wheat (5.5 or 6.0 g) to replace the official 7.0 g used in the Falling Number test was investigated using samples of Canada Western Amber Durum (CWAD) and Canada Western Red Spring (CWRS) wheat. Use of either of the smaller sample sizes resulted in a significant shortening of the analysis time of the test. Reproducibility studies, using high and low falling number (FN) CWRS and CWAD samples, with three analyses per day over six days indicated no appreciable change in the coefficient of variation for the test using a smaller sample size. The maximum daily standard deviation of three replicates, 25.7 sec, was observed using the official 7.0‐g moisture‐corrected CWAD sample and was not significantly different from the 23.0 sec value obtained for a 5.5‐g sample of CWRS. The maximum average standard deviations observed over the six days of analysis were 13.7, 7.7, and 5.3 sec for the 5.5‐, 6.0‐, and 7.0‐g sample sizes, respectively, and were all associated with the sound, high FN, CWRS sample. While the use of 5.5 g allowed significant differentiation between high and low FN CWRS samples, the ability to discriminate high and low FN CWAD samples was lost at this sample size. FN analysis of CWRS (n = 144) and CWAD (n = 141) at 7.0 vs. 6.0 g, yielded correlation coefficients of 0.95 and 0.88, respectively. Regression analysis indicated a ±14.1 sec error associated with estimating a 7.0‐g FN value using 6.0 g of CWRS which increased to 26.4 sec for CWAD. Particle size analyses of whole meal after grinding indicated that the harder CWAD wheat fractured into a significantly greater percentage of larger particles than the corresponding CWRS. This difference may be a contributing factor to the greater variance associated with the CWAD 6.0‐g test and the inability to differentiate sound and slightly sprouted wheat at 5.5 g. Use of the 6.0‐g method, stopping the test after 200 sec, would also be applicable for screening purposes at commercial facilities where normal testing times (350–450 sec) could be reduced to meet designated quality requirements. This would offer a savings of 2.5 min/sample over the conventional method.
Impact of Proteins on Pasting and Cooking Properties of Nonparboiled and Parboiled Rice
Authors: Derycke V. , Veraverbeke W. S. , Vandeputte G. E. , De Man W. , Hoseney R. C. , Delcour J. A.
Published: June 2007

The role of proteins in the pasting and cooking properties of non‐parboiled (npb) and parboiled (pb) rice was tested by means of a reducing agent dithiothreitol (DTT) and a protease (trypsin). DTT increased the swelling power and carbohydrate leaching of flour from npb rice flour but decreased its amylose leaching. Although DTT slightly increased the Rapid Visco Analyser (RVA) viscosity at the initial stages of the pasting process, it decreased RVA viscosity in the further phases of the experiment. Preincubation of flour with a trypsin decreased RVA viscosity along the whole temperature profile. Addition of DTT to the cooking water decreased water absorption and rice hardness and increased leaching of solids during cooking and stickiness of the cooked npb rice. Addition of DTT to the cooking water of flour from pb rice increased swelling power, carbohydrate leaching, and amylose leaching. Addition of DTT also increased RVA viscosity. Preincubation with trypsin had a similar effect but the changes were less pronounced. Addition of DTT increased stickiness of cooked pb rice and increased water absorption and leaching of solids during cooking. Taken together, the results provide evidence for the existence of a protein barrier affecting starch swelling, rheological, and cooking properties of both npb and pb rice.
Enzymatic Milling Product Yield Comparison with Reduced Levels of Bromelain and Varying Levels of Sulfur Dioxide
Authors: Johnston David B. , Singh Vijay
Published: June 2007

Enzymatic milling (E‐Milling) is a process that could potentially replace the sulfur dioxide procedure currently used in all commercial wet‐milling facilities. E‐Milling incorporates the use of a short water soaking step (≤6 hr), a coarse grind, and the use of a protease to release the starch granules from the corn endosperm. E‐Milling does not require sulfur dioxide to obtain starch yields equivalent to conventional wet milling; however, the important antimicrobial effects of sulfur dioxide are not duplicated by the enzymatic process. The use of low levels of sulfur dioxide (sufficient for antimicrobial activity) is being proposed as an easily implemented means of microbial control during E‐Milling. To assess the effectiveness of E‐Milling under these conditions, fraction yields for milling experiments adding sulfur dioxide with and without added enzyme were compared with fraction yields from conventional 24‐hr steeping with 2,000 ppm SO2 and 0.55% lactic acid. Because adding enzyme and SO2 can both improve product yields and compositions independently, it was necessary to use a reduced level of enzyme (much less than necessary to generate “product quality” material) to observe differences in terms of product yields. The results show significant differences in starch, fiber, total gluten, and insoluble gluten recoveries between samples milled with SO2 and enzyme compared with those at the same SO2 level without enzyme addition. No significant differences were observed for soakwater or germ yields regardless of the SO2 level used. The yield benefits from adding both enzyme and SO2 are clearly shown over the addition of each individually, for all coproduct yields with the exception of the yields for germ.
Nitrogen Fertilizer Increases Seed Protein and Milling Quality of Rice
Authors: Leesawatwong M. , Jamjod S. , Kuo J. , Dell B. , Rerkasem B.
Published: June 2007

Rice grain breakage during milling is a problem in many parts of Asia. It has been suggested that nitrogen (N) fertilizer can improve the milling quality of rice. Therefore, this study investigates effects of N fertilization on grain N concentration, endosperm storage protein distribution, and milling quality of rice. Four Thai extra long grain commercial rice cultivars (KDML105, KLG1, PTT1, and CNT1) were grown at Chiang Mai University in the wet season of 2001 with 0 or 120 kg of N/ha at flowering. Anatomical sections showed that there was more storage protein accumulated in the lateral regions of polished grain of high N concentration than in grain of low N concentration. Percent (%) unbroken rice was positively correlated with relative abundance of storage protein in the lateral region of the endosperm in all cultivars. Applying N increased head rice N concentration in all cultivars, whereas % unbroken rice was increased in KLG1 and CNT1. KDML105 cultivar, on the other hand, already had high % unbroken rice and more abundant storage protein in the lateral region with the grain of low N concentration. It is hypothesized that high density of storage protein in the lateral region of the endosperm provides resilience and lessens grain breakage during milling. The additional protein may increase hardness in rice grains and thus could make the rice more resistant to breakage during milling. Furthermore, N fertilization may enhance the nutritional quality of rice grain by increasing the glutelin content, which is rich in lysine.
Barley Contains Two Cationic Acetylxylan Esterases and One Anionic Feruloyl Esterase
Authors: Sun Alberto , Faulds Craig B. , Bamforth Charles W.
Published: June 2007

Various carbohydrate‐active esterases are detected in extracts of malted barley when analyzed by polyacrylamide gel electophoresis. The slowest migrating and most heat‐resistant of these are relatively cationic acetylxylan esterases. Two such activities, one with a high affinity for esterase substrates including acetylated xylan, and one with a low affinity, are indicated. These enzymes did not hydrolyze methyl ferulate. A relatively heat‐labile anionic feruloyl esterase has also been purified. It has some, albeit low, ability to act on acetylated xylan. The feruloyl esterase effects extensive release of ferulate from endosperm cell walls isolated from barley, whereas the acetylxylan esterases are only capable of very limited release of acetate.
Rice Milling Quality, Grain Dimensions, and Starch Branching as Affected by High Night Temperatures
Authors: Counce P. A. , Bryant R. J. , Bergman C. J. , Bautista R. C. , Wang Y.‐J. , Siebenmorgen T. J. , Moldenhauer K. A. K. , Meullenet J.‐F. C.
Published: June 2007

Important rice grain quality characteristics such as percentage of chalky rice kernels are affected by both high and low night temperatures and by different day and day/night temperature combinations. High nighttime temperatures have also been suspected of reducing rice milling quality including head rice yields. Experiments to confirm or refute this have not been reported. A controlled climate experiment was conducted. Conditions in the chambers were identical except between 2400 and 0500 hours (midnight and 5 am). For those times, two temperature treatments were imposed: 1) 18°C (low temperature treatment) and 2) 24°C (high temperature treatment). Two cultivars were tested: LaGrue and Cypress. The high temperature treatment reduced head rice yields compared with the low temperature treatment. Grain widths were reduced for the high temperature treatment compared with the low temperature treatment. There was no effect of temperature on grain length or thickness. Amylopectin chain lengths 13–24 were increased by the high temperature treatment by ≈1%. Future research will focus on determining whether genetic variability exists among cultivars in their head rice yield response to high temperatures. After identifying a source of resistance to high temperature effects, this characteristic can be incorporated into rice cultivars. In addition, ways to reduce this effect, including biotechnological remedies, have the potential for increasing rice yield and quality.
Formation of Enzyme‐Resistant Starch in Bread as Affected by High‐Amylose Wheat Flour Substitutions
Authors: Van Hung Pham , Yamamori Makoto , Morita Naofumi
Published: June 2007

High‐amylose wheat flour was used to substitute for normal wheat flour in breadmaking and formation of resistant starch (RS) in bread during storage was determined. Substitution with high‐amylose wheat flour (HAF) decreased peak and final viscosities, breakdown, and setback. Doughs with HAF substitutions were weaker and less elastic, and absorbed more water than those of the normal wheat flour. After baking, RS contents in breads with 10, 30, and 50% HAF substitutions were 1.6, 2.6, and 3.0% (db), respectively, higher than that of the control (0.9%, db). The levels of RS increased gradually during storage for one, three, and five days. With substitutions of 30 and 50% HAF, the total levels of dietary fiber (DF) and RS in bread after five days of storage were 15.5 and 16.8% (db), respectively, as compared to 13.0% (db) in bread from the normal wheat flour. The loaf volumes and appearances of bread crumbs made from HAF substitutions of 10 and 30% were not significantly different from those of the control, whereas the substitution with 50% HAF decreased loaf volume and resulted in inferior appearance of breadcrumbs. The firmness of breadcrumbs increased along with increase in the level of HAF substitutions after baking. During storage, the firmness of breadcrumb with 10% HAF substitutions was higher than that of the control, whereas breads with 30 and 50% HAF substitutions had similar firmness to the control. As a result, HAF might be used to substitute for up to 50% normal wheat flour to make bread with acceptable bread quality and significantly high amount of RS.
Development of Laboratory Techniques to Mimic Industrial‐Scale Nixtamalization
Authors: Yglesias Roxana , Parkhurst Anne M. , Jackson David S.
Published: June 2007

A laboratory nixtamalization process was developed to imitate larger scale cooking/steeping conditions. Corn (45 kg) was cooked in a pilot plant gas‐fired cook/steep tank and temperature was monitored every 30 sec. Cooling and heating rates were mimicked in the laboratory using a digital temperature programmable hot plate that adjusted grain‐water‐lime temperature changes at a specified rate. A Response Surface Central Composite Design was used to model pasting and thermal properties of nixtamal and masa as a function of cooking temperature (86–96°C), cooking time (20–40 min), and steeping time (3–11.77 hr). Nixtamal and masa moisture, dry matter loss, nixtamal and masa RVA peak temperature, shear thinning, nixtamal peak viscosity, masa final viscosity, nixtamal and masa DSC enthalpy peak and end temperatures, and nixtamal onset temperature were explained by the same regression terms for results obtained using both processes conditions. The intercept and slopes of the fitted models for the pilot plant and laboratory responses were not significantly different (P < 0.05). The laboratory method can be used to mimic larger scale processing over a wide range of nixtamalization conditions.
Using Multivariate Techniques to Predict Wheat Flour Dough and Noodle Characteristics from Size‐Exclusion HPLC and RVA Data
Authors: Ohm J.‐B. , Ross A. S. , Ong Y.‐L. , Peterson C. J.
Published: June 2007

Flour proteins of hard and soft winter wheats grown in Oregon were characterized by size‐exclusion HPLC (SE‐HPLC). Flour pasting characteristics were assessed by a Rapid Visco Analyser (RVA). Principle component scores (PCS) were calculated from both RVA data and from absorbance area and % absorbance values from SE‐HPLC. The PCS and cross‐products, ratios, and squares were used to derive wheat classification and quality prediction models. A classification model calculated from PCS of SE‐HPLC data could reliably separate these hard and soft wheats. The prediction models for mixing and noodle characteristics showed better performance when calculated from PCS values of both SEHPLC and RVA data than from SE‐HPLC data only. The R2 values of prediction models for mixograph absorption, peak time, and tolerance were 0.827, 0.813, and 0.851, respectively. Prediction models for noodle hardness, cohesiveness, chewiness, and resilience immediately after cooking had R2 values of 0.928, 0.928, 0.896, and 0.855, respectively. These results suggest that multivariate methods could be used to develop reliable prediction models for dough mixing and noodle characteristics using just SE‐HPLC and RVA data.
Effect of Gamma Irradiation on the Functional and Nutritive Properties of Rice Flours from Different Cultivars
Authors: Zuleta Angela , Dyner Luis , Sambucetti María Elena , de Francisco Alicia
Published: June 2007

The purpose of this work was to study the effect of minimal doses of γ‐irradiation to reduce microbial loads (Co60, doses of 0, 1.5, and 3 kGy) on flour from three rice cultivars with different amylose contents (AC) grown in Argentina: RP2 (AC 25%), Yeruá (Y) (AC 19%), and Higokumochi (H) (AC 5%). Studies on some starch characteristics such as digestibility (rate of starch hydrolysis in vitro), gel viscosity and syneresis, and scanning electron microscopy (SEM) were performed. Results showed that γ‐irradiation affects rice functional and nutritive characteristics proportionally with the dosage used. With 3 kGy, original digestibility values increased 37.5, 60, and 76%; gel viscosity decreased 52, 77, and 90%; and syneresis increased 0, 193, and 546% on RP2, Y, and H, respectively. Amylopectin was the starch fraction most affected as shown by SEM. Although some of these changes in cultivar attributes might be considered negative for traditional food formulations, they could help in the design of new foods or for fermented beverages.
In Vitro Bile Acid Binding Capacity of Wheat Bran Extruded at Five Specific Mechanical Energy Levels
Authors: Kahlon T. S. , de J. Berrios J. , Smith G. E. , Pan J. L.
Published: June 2007

The in vitro binding of bile acids of extruded wheat bran (EWB) at five specific mechanical energy (SME) levels of 120 (EWB‐120), 177 (EWB‐177), 234 (EWB‐234), 291 (EWB‐291), and 358 (EWB‐358) Wh/kg on a dry weight basis, was determined using a mixture of bile acids secreted in human bile at a duodenal physiological pH 6.3. Experiments were conducted using six treatments and two blank incubations to test unextruded and extruded wheat bran samples on an equal dry matter (DM) basis. Relative to cholestyramine (bile acid binding, cholesterol‐lowering drug), in vitro bile acid binding ability of unextruded and extruded wheat bran treatments on an equal DM basis was 14–23%. The bile acid binding ability of the total dietary fiber (TDF) was 28–51% and insoluble dietary fiber (IDF) was 29–53%. Bile acid binding on DM, TDF, and IDF bases for EWB‐177 was significantly (P ≤ 0.05) higher, and EWB‐358 was significantly lower than UWB, EWB‐120, EWB‐234, and EWB‐291. Bile acid binding for EWB‐120 was significantly higher than that for UWB, EWB‐234, and EWB‐291. These results demonstrate the relative health promoting potential of EWB‐177 > EWB‐120 > UWB = WB‐234 = EWB‐291 >EWB‐358 as indicated by bile acid binding ability on DM, TDF, and IDF bases. The variability in bile acid binding of wheat bran treatments may be due to fragmenting of particles or macromolecules, creating new linkages in proteins, starches, and nonstarch polysaccharides, changes in physical and chemical characteristics, and binding sites.
Milling Characteristics of Rice Cultivars and Hybrids
Authors: Siebenmorgen T. J. , Matsler A. L. , Earp C. F.
Published: June 2007

Many rice cultivars and hybrids have unique physical characteristics that affect milling performance. The purpose of this study was to quantify the rate of bran removal during milling for several rice cultivars and hybrids common to the southern United States, and compare the quantity of lipids remaining on the kernel surface to that located throughout the kernel. This was accomplished by analyzing two sample sets. The first comprised cultivars Cocodrie, Cypress, and Lemont, and hybrids XL7 and XL8, which were milled for 0 (brown rice), 20, 30, 40, 50, 60, and 70 sec in a laboratory mill. In the second set, cultivars Cocodrie, Cypress, and Wells, and hybrids XL7 and XL8 were milled for 0, 20, 40, and 60 sec. The surface lipid content (SLC) and color of head rice samples were measured as indications of the degree of milling (DOM). The total lipid content (TLC) of ground head rice was also measured to determine the total amount of lipids present throughout the entire kernel. Results showed that at a given milling duration, SLC and color varied across cultivars and hybrids. In particular, the SLC levels of hybrids were lower than those of cultivars, particularly for Cocodrie, for all milling durations. This research indicated that it may be necessary to mill different cultivars and hybrids for varying durations to attain comparable DOM levels. Milling to a consistent DOM level is necessary to ensure equitable head rice yield comparisons across cultivars and hybrids.
Effect of Temperature on Texture of Corn Tortilla With and Without Antistaling Agents
Authors: Bueso Francisco J. , Waniska Ralph D. , Moreira Rosana , Seetharaman Koushik , Rooney Lloyd W.
Published: June 2007

Tortilla stiffening should occur between ‐23 to 57°C, showing a maximum rate near the midpoint of this range (17°C). Starch recrystallization below the glass transition temperature (Tg = ‐23°C) in corn tortillas is minimal due to lack of molecular mobility. The objective of this study was to determine the effect of storage temperature (‐20 to 21°C) on the stiffening rate of corn tortillas with or without additives (carboxy‐methylcellulose [CMC] and maltogenic amylase). Tortilla pliability, stiffness, and energy dissipated obtained by stress relaxation, and amylopectin recrystallization determined by differential scanning calorimetry (DSC) showed a second‐order polynomial relationship with temperature. Tortillas became stiff faster during refrigerated storage (3–10°C). Adding 0.25% CMC and 1,650 AU of amylase maintained tortilla softness and flexibility, both at room temperature and under refrigeration for at least three weeks.
Solvent Retention Capacity Values in Relation to Hard Winter Wheat and Flour Properties and Straight‐Dough Breadmaking Quality
Authors: Xiao Z. S. , Park S. H. , Chung O. K. , Caley M. S. , Seib P. A.
Published: June 2007

Solvent retention capacity (SRC) was investigated in assessing the end use quality of hard winter wheat (HWW). The four SRC values of 116 HWW flours were determined using 5% lactic acid, 50% sucrose, 5% sodium carbonate, and distilled water. The SRC values were greatly affected by wheat and flour protein contents, and showed significant linear correlations with 1,000‐kernel weight and single kernel weight, size, and hardness. The 5% lactic acid SRC value showed the highest correlation (r = 0.83, P < 0.0001) with straight‐dough bread volume, followed by 50% sucrose, and least by distilled water. We found that the 5% lactic acid SRC value differentiated the quality of protein relating to loaf volume. When we selected a set of flours that had a narrow range of protein content of 12–13% (n = 37) from the 116 flours, flour protein content was not significantly correlated with loaf volume. The 5% lactic acid SRC value, however, showed a significant correlation (r = 0.84, P < 0.0001) with loaf volume. The 5% lactic acid SRC value was significantly correlated with SDS‐sedimentation volume (r = 0.83, P < 0.0001). The SDS‐sedimentation test showed a similar capability to 5% lactic acid SRC, correlating significantly with loaf volume for flours with similar protein content (r = 0.72, P < 0.0001). Prediction models for loaf volume were derived from a series of wheat and flour quality parameters. The inclusion of 5% lactic acid SRC values in the prediction model improved R2 = 0.778 and root mean square error (RMSE) of 57.2 from R2 = 0.609 and RMSE = 75.6, respectively, from the prediction model developed with the single kernel characterization system (SKCS) and near‐infrared reflectance (NIR) spectroscopy data. The prediction models were tested with three validation sets with different protein ranges and confirmed that the 5% lactic acid SRC test is valuable in predicting the loaf volume of bread from a HWW flour, especially for flours with similar protein contents.
Network Formation by Pilot Plant and Laboratory‐Extracted Barley β‐Glucan and Its Rheological Properties in Aqueous Solutions
Authors: Burkus Zvonko , Temelli Feral
Published: June 2007

Barley and oat β‐glucans of low viscosity form reversible gels when prepared in sufficiently high concentrations. Solutions of three barley β‐glucan gums differing in molecular weight and thus in viscosity were prepared at 1.0, 2.5, or 5.0% (w/w) concentration levels. Medium‐ and high‐viscosity gums were prepared in a pilot plant (PP) and laboratory (LAB), respectively. Low‐viscosity (LV) gum was extracted in the laboratory at pH 7, which allowed for native enzymatic activity and decreased molecular weight. Network formation was monitored overnight through changes in storage (G′) and loss (G″) moduli. The strength of the formed network was determined from oscillatory rheological measurements by increasing the strain from 2 to 100%. Findings demonstrate that gelation of β‐glucan is molecular weight dependent and practically an instantaneous process for low‐viscosity gum solutions at concentrations of ≤5% gum (or ≤4% β‐glucan), levels lower than previously anticipated. The purity of β‐glucan also seems to affect gelation rate. Better understanding of the β‐glucan gelation behavior is important for its functionality in both food product applications and physiological mechanisms of its health benefits.
Bran Size Distribution at Milling and Mechanical and Biochemical Characterization of Common Wheat Grain Outer Layers: A Relationship Assessment
Authors: Greffeuille V. , Abecassis J. , Lapierre C. , Lullien‐Pellerin V.
Published: June 2007

Mechanical properties of wheat grain outer layers from common wheat (Triticum aestivum L.) cultivars known to display distinct milling behavior were analyzed using uniaxial tension tests. Tensile modulus and strain to rupture of the tissues distinguished between the wheat cultivars. Values of strain to rupture were related to coarse bran size generated by grain milling, a characteristic that distinguishes the two hardness classes. As content of an aleurone marker in total or first break flour was also related to coarse bran size, extensibility of wheat grain outer layers' could be a key parameter to explain the observed tissue mechanical behavior and thus distribution of the aleurone layer content in flours. As tissue mechanical properties are generally linked to the cell wall biochemical composition and structure, analysis of the main wheat outer layers' cell wall compounds was undertaken to establish relationships with the differences observed in mechanical properties. No clear correlation could be found with one of the wheat outer layers' component but involvement of the outer layers' cell wall structure in the tissues behavior at milling was confirmed.
Physicochemical Properties of Rice Endosperm Proteins Extracted by Chemical and Enzymatic Methods
Authors: Paraman Ilankovan , Hettiarachchy N. S. , Schaefer Christian , Beck Markus I.
Published: June 2007

Rice proteins are nutritional, hypoallergenic, and healthy for human consumption. Efficient extraction with approved food‐grade enzymes and chemicals are essential for commercial production and application of rice protein as a functional ingredient. Rice endosperm proteins were isolated by alkali, salt, and enzymatic methods and evaluated for extractability and physicochemical properties. Alkali (RPA) and salt (RPS) methods extracted 86.9 and 87.3% of proteins with 65.9 and 58.9% yield, respectively. The enzymatic methods with Termamyl (RPET) and amylase S (RPEA) extracted 85.8 and 81.0% proteins with 85.2 and 86.2% yield, respectively. Enthalpy values of RPA (1.79 J/g), RPS (1.22 J/g), RPET (nondetectable), and RPEA (0.17 J/g), determined by differential scanning calorimetry, demonstrated that the varying level of denaturation of proteins depends on the method of extraction. Surface hydrophobicity data supported this observation. Alkali‐ and salt‐extracted proteins had higher solubility and emulsifying properties than those of enzyme‐extracted proteins. Comparatively, more favorable protein composition, lower surface hydrophobicity, higher solubility, and a lower degree of thermal denaturation of alkali‐ and salt‐extracted proteins contributed to higher emulsifying and foaming properties than those of enzyme‐extracted proteins; therefore, alkali‐ and salt‐extracted proteins can have enhanced functional use and a potential starting material for preparing tailored rice protein isolates.
Gelatinizing, Pasting, and Gelling Properties of Potato and Amaranth Starch Mixtures
Authors: Gunaratne Anil , Corke Harold
Published: June 2007

Physicochemical properties of mixtures of native potato and native amaranth (Amaranthus cruentus), heat‐moisture treated (HMT) potato and heat‐moisture treated amaranth, cross‐linked potato and cross‐linked amaranth, native potato and heat‐moisture treated amaranth, and heat‐moisture treated potato, and native amaranth were tested at different ratios. Two peaks were noticed in the pasting curves when large differences of swelling factor and amylose leaching existed between individual components in the mixture. It seems that amylose leaching from one starch in a mixture may affect the swelling and much of the granular break down of the other. The mixtures showed stabilities in hot pastes that were higher than the less stable components in a mixture. Some mixtures such as HMT potato and native amaranth showed very specific nonadditive pasting behavior. Mixing 10% of native amaranth to HMT potato starch caused a large reduction of peak viscosity and cold paste viscosity, resulting in a very soft gel. In the differential scanning calorimeter, each component of a mixture gelatinized independently, showing two peaks corresponding to the individual components. When transition temperatures of both components were similar in DSC, the result was a single endotherm. Dramatic changes of pasting and subsequent gel properties resulted when thermal transition of the two components occurred in the same temperature range. Retrogradation enthalpies as measured by DSC were between the two individual components in all tested mixtures.
Oat Tocols: Saponification vs. Direct Extraction and Analysis in High‐Oil Genotypes
Authors: Peterson David M. , Jensen Camille M. , Hoffman David L. , Mannerstedt‐Fogelfors Birgitta
Published: June 2007

Tocols are natural antioxidants that occur in grains that may benefit human and animal health. Therefore, it is important to accurately measure their concentrations in foods and feeds and to determine how genetics and growing environment can influence their levels. The first objective was to evaluate saponification versus direct extraction for the analysis of tocols in oat (Avena sativa L.). The second was to determine the effects of growing environment, hulled versus hulless phenotype, and genetic background on tocol concentration, and to see whether tocol and lipid concentrations were associated. For the first objective, oat grain samples from two locations were either extracted by saponification or directly with methanol, and extracts were analyzed by HPLC. The saponification method increased yield by ≈25% and was less time‐consuming, so it was adopted for the second objective. For the second objective, oat genotypes were developed by crossing high‐oil parents from Iowa State University with hulled and hulless cultivars adapted to arid Western environments. These were grown at Aberdeen and Tetonia, ID, and the tocols and lipid concentrations were analyzed at Madison, WI. There were significant effects of growing environment, genotype, and the presence or absence of hulls on tocol concentrations. Tocol and lipid concentrations were not correlated. Progeny of crosses involving the genotype IA91098‐2 had tocol concentrations that exceeded both parents.
Correcting Head Rice Yield for Surface Lipid Content (Degree of Milling) Variation
Authors: Cooper N. T. W. , Siebenmorgen T. J.
Published: June 2007

Head rice yield (HRY) is the primary parameter used to quantify rice milling quality. However, HRY is affected by the degree of milling (DOM) and thus HRY may not be comparable between different lots if the DOM is different. The objective of this study was to develop a method by which HRY values can be adjusted for varying DOM values when measured by surface lipid content (SLC). Seventeen rough rice lots including long‐grain and medium‐grain cultivars and hybrids were harvested from two 2003 and five 2004 locations. Duplicate subsamples of each lot were milled in a McGill No. 2 laboratory mill for 10, 15, 20, or 40 sec after zero, one, two, three, and six months of storage. HRY and SLC were measured. The average HRY versus SLC slope across all milling duration data sets was 9.4. As such, it is suggested that, when milling with a McGill No. 2 laboratory mill, the HRY of a rice lot can be adjusted by a factor of 9.4 percentage points for every percentage point difference between the rice lot SLC and a specified SLC.
Effect of Moisture Content at Harvest and Degree of Milling (Based on Surface Lipid Content) on the Texture Properties of Cooked Long‐Grain Rice
Authors: Saleh Mohammed I. , Meullenet Jean‐Francois
Published: June 2007

The effects of the degree of milling (based on surface lipids content [SLC]) on cooked rice physicochemical properties were investigated. Head rice yield (HRY), protein, and SLC decreased with increasing milling, while the percent of bran removed and whiteness increased. Results showed that SLC significantly (P < 0.05) affected milled as well as cooked rice properties across cultivar, moisture content (MC) at harvest, and location (Stuttgart, AR, and Essex, MO). Cooked rice firmness ranged from 90.12 to 111.26 N after milling to various degrees (SLC). The decrease in cooked rice firmness with increasing milling was attributed to the lowering of total proteins and SLC. Cooked rice water uptake increased with increasing degree of milling. Water uptake by the kernel during cooking dictated the cooked rice firmness. The increase in cooked rice stickiness with increasing degree of milling was attributed to an increase in starch leaching during cooking because of the greater starch granule swelling associated with a greater water uptake.
Gelatinization and Retrogradation Traits of Starches from Argentinian Maize Inbred Lines: Patterns of Correlation Among Traits
Authors: Eyhérabide G. , Borrás F. , Robutti J. , Presello D. , White P.
Published: June 2007

Efforts are being made to identify sources of starches with unique end‐use properties, such as thermal properties, within a wide array of maize germplasm. Because redundancy may exist when evaluating these traits, it would be useful to know the pattern of correlation among traits involved to focus the expensive stage of evaluation of germplasm on traits that do not provide redundant information. The objectives of this study were to analyze the pattern of correlations between starch gelatinization and retrogradation‐associated traits in a group of 12 Argentine maize inbred lines and to develop predictive models among traits when possible. Traits measured by differential scanning calorimetry included gelatinization and retrogradation properties. Pearson correlation coefficients among starch thermal properties were determined from univariate analyses, and canonical correlations were determined from multivariate analyses. Canonical correlation analyses were more sensitive in detecting associations between starch gelatinization and retrogradation parameters than univariate analyses. Multiple regression equations to estimate the change in enthalpy of starch gelatinization and retrogradation traits, especially for change in enthalpy and percentage of retrogradation, were obtained and validated with an independent data set.
Near‐Infrared Spectroscopy for Estimation of Ergosterol Content in Barley: A Comparison Between Reflectance and Transmittance Techniques
Authors: Börjesson T. , Stenberg B. , Schnürer J.
Published: June 2007

The fungal‐specific lipid ergosterol correlates with fungal biomass and often also with the degree of mycotoxin contamination of cereals. We compared the ability of a near‐infrared reflectance (NIR) instrument with a broad wavelength range (400–2500 nm) and a near‐infrared transmittance (NIT) instrument with a narrower wavelength range (850–1050 nm) to predict the ergosterol content of naturally infected barley samples. The two instruments were equally good at predicting ergosterol content in Swedish samples (r2 = 0.81 and 0.83 for NIT and NIR, respectively). The NIT instrument was then used for samples from three countries (Sweden, Ireland, UK). This model had about the same root mean‐squared error (≈5 mg of ergosterol/kg, db, of grain) as the dataset with only Swedish samples, although the r2 value was lower (0.58). The investigation has shown that it is possible to predict ergosterol content in whole barley samples using NIR or NIT instrumentation, and acceptable models can be obtained using different barley cultivars and samples from different countries and harvest years. This should make it possible to routinely predict the fungal biomass at grain terminals.