bluuebunny/crossref_metadata_2025 huggingface dataset:
Hagiographicals Plots and Motives on the Modern Period: On Issue of Research and Classification
Authors: Nepomnyashchikh N. A.
Published: November 2019

Studying the hagiographic traditions in the literature the modern period, one faces several issues. Firstly, it is assumed that a scholar who compares the hagiographic motifs and plots to the motifs and plots of the modern period, deals with the a hypothetical complex of the already identified and described the hagiographic motifs and plots and all he has to do is to compare them to the motifs and plots of the literature works written in the later times. However, there is no yet such a thing as a complete research on all hagiographic motifs and plots. There are studies of the certain hagiographic texts and the certain types of hagiographic texts, but there is no comprehensive list or index of the hagiographic motifs and plots. Secondly, there is no uniformly accepted scholarly terminology defining what a hagiographic motif is. Can any element of a hagiographic text be considered as such? Should the motif be defined as a unit of a theme or of a plot depending on the theory a scholar chooses to base on: Veselovsky’s vs Tomashevsky’s? How is the term “topos”, which becomes more and more popular among the researchers of the hagiography, related to the hagiographic motifs and plots? Thirdly, the number of the hagiographic and literary texts as well as researches and studies on the subject is so huge that it is only possible to specify some trends of development of the hagiographic elements and traditions in the succeeding literature. The article summarizes and analyzes the existing scientific approaches to the issues of analysis, classification, typology of the hagiographic plots and some hagiographic motifs in the Russian literature of the modern period.

The conclusion of the survey is that the modern literature does not need the hagiography as a sapless model; such components of the hagiographic framework as its structure, plot, character, details are transformed from typical, similar to each other, copying the model ones to the unique ones interpreted in new original ways. Usage of the hagiographic sources can not be associated with a certain single genre; the hagiographic elements can be assimilated in any narrative or even in poetry. The literature of the modern period borrows plots, motifs and other elements of the hagiography but it lacks the utilitarian role that the hagiographic texts used to play as calendar reading. Names and dates become just literary symbols, references to some significant analogues but they do not demand to treat a literary character as a hagiographic character.

The main purpose of this work is to actualize the discussion on how an index of the hagiographic plots and motifs should be compiled, what a hagiographic motif and plot are, what should be considered hagiographic plots and motifs in later narratives, taking into account that not all the topoi and elements as well as rhetoric and periods, which are recognizable as the indicators of the “hagiographic tradition” in the narrative, can be defined as the motifs in the strict sense of the term.
On the Issue of Execution of the Obligation to Pay Tax Payments in the Liquidation of the Organization
Authors: Shabanova I. N.
Published: November 2019

The article deals with the issues of execution of the obligation to pay taxes and fees. The subject of the tax obligation is only money, based on the concept of “tax” and the fact that the tax is one of the sources of the budget, which is a form of formation and expenditure of funds. The features of monetary obligation as a type of public-legal obligations are distinguished. The conditions of execution of the tax duty are analyzed. Discusses the problem of a tax debt in the liquidation of the organization, the time to enforce which the tax authority has expired. This problem leads to the need to apply to the arbitration court to recognize the tax debt as hopeless for collection and exclusion of the relevant record from the personal account of the taxpayer, which in turn leads to an increase in the period of liquidation and additional financial security. It is proposed to transfer to the tax authority the powers to write off and exclude tax debts, the period for compulsory collection of which has expired, in an administrative procedure.
The State of Law in the Application of Preventive Measures in the Form of Detention
Authors: Galochkin D. A.
Published: November 2019

Based on the analysis of statistical indicators of Prosecutor's office work on supervision on implementation of laws by administrations of detentions, the main problems prevailing in detention centers and related with application of a preventive measure as a pre-trial detention against suspects and accused of committing crimes are given in the article. The analysis of the activity of the European court of human rights on consideration of Russian citizens claims about violations of the Federal law of 15.07.1995 No. 103-FZ "About incarceration of suspects and accused of committing crimes" is carried out, as well as measures taken by the Russian Federation to eliminate them. The causes of overcrowding in remand centers occurred in Moscow, Moscow region and a number of other regions are analyzed. The author made suggestions to improve current legislation. The article contains recommendations to prosecutors supervising the implementation of laws by administrations of pre-trial detention facilities, as well as the preliminary investigation of criminal cases.
THE MODELS DESCRIBING ASD FORMATION: WHETHER DIALOGUE IS POSSIBLE?
Authors: Dorosheva E. A.
Published: November 2019

Whether dialogue is possible between different models describing formation autism spectrum disorders (ASD)? This problem is considered. Features of methodical bases and the corresponding terminology in the model of mind, approaches based on interpersonal interactions, model of sensory integration were compared. In addition to earlier described “through” phenomena connected with development of RAS (intolerance to uncertainty and deficiency of self-perception) the contribution of interpersonal attachment disturbances was described. The conclusion about ability to integrate approaches by consideration of basic phenomena in development of RAS is drawn.
Nitrene Transfer Catalyzed by a Non-Heme Iron Enzyme and Enhanced by Non-Native Small-Molecule Cofactors
Authors: Goldberg Nathaniel , Knight Anders M. , Zhang Ruijie , Arnold Frances H.
Published: November 2019

Transition-metal catalysis is a powerful tool for the construction of chemical bonds. Here we show that a non-heme iron enzyme can catalyze olefin aziridination and nitrene C–H insertion, and that these activities can be improved by directed evolution. The non-heme iron center allows for facile modification of the primary coordination sphere by addition of metal-coordinating molecules, enabling control over enzyme activity and selectivity using small molecules.
Spontaneous and Template-Directed Emergence of Low-Symmetry Foldamers from Dynamic Homomeric Sequences
Authors: Pappas Charalampos , Mandal Pradeep , Liu Bin , Kauffmann Brice , Miao Xiaoming , Komaromy David , Hoffmann Waldemar , Manz Christian , Chang Rayoon , Liu Kai , Pagel Kevin , Huc Ivan , Otto Sijbren
Published: November 2019

Creating large objects from simple subunits rarely results in structures that are of low symmetry as well as of low polydispersity. We now report the spontaneous and uniquely selective oligomerization of simple monomer units into oligomers that are of uniform length, have complex low symmetry structures and are conformationally well-defined. The occurrence of such structures is both frequent and diverse. It is driven by the spontaneous folding into three-dimensional shapes akin to those exhibited by biopolymers. We also show that templates can direct the formation of new functional foldamers. The resulting structures carry imprints of the templates and are therefore capable of binding these. This behavior resembles that of molecularly imprinted polymers (MIPs), with the important distinction that the selected oligomers are uniform and conformationally well-defined, whereas MIPs suffer from heterogeneity in structure, shape and size.
Investigating Electrode Flooding in a Flowing Electrolyte, Gas-Fed Carbon Dioxide Electrolyzer
Authors: Leonard McLain , Clarke Lauren E. , Forner-Cuenca Antoni , Brown Steven M. , Brushett Fikile
Published: November 2019

Managing the gas-liquid interface within gas diffusion electrodes (GDEs) is key to maintaining high product selectivities in carbon dioxide electroreduction. By screening silver-catalyzed GDEs over a range of applied current densities, we observe an inverse correlation between carbon monoxide selectivity and the electrochemical double-layer capacitance, a proxy for wetted electrode area. We find that plotting current-dependent performance as a function of cumulative charge leads to data collapse onto a single sigmoidal curve indicating that the passage of faradaic current accelerates flooding. We hypothesize that high cathode alkalinity, driven by both initial electrolyte conditions and cathode half-reactions, promotes carbonate formation and precipitation which, in turn, facilitates electrolyte permeation. This mechanism is reinforced by the observations that post-test GDEs retain less hydrophobicity than pristine materials and that water rinsing and drying electrodes temporarily recovers peak selectivity. This knowledge offers an opportunity to design electrodes with greater carbonation tolerance to improve device longevity.
The development of analytical methods to determine metoclopramide-hydrochloric acid in the standard raw and it compared with pharmaceuticals
Authors: Khawla Salman Abd-Alrassol  , Qutaiba A. Qasim  , Maitham Ali AL-Rikabi  , H. N. K. AL-Salman
Published: November 2019

The three novel easy, to the prepare and sensitive spectral methods, were used to estimate metoclopramide in both standard and pharmaceuticals. The effective double–electron, was present in the metoclopramide compound helps to interact in an acidic medium with a reagent such as diazetide resorcinol and 8-hydroxyquinoline reagents. The present article was extended to find out three analytical methods with UV-V is the detector. In both A and B methods, two azo-dyes are formed, they are orange-red and red stable and have high water solubility, giving highest absorption values at 415 nm and 485 nm but the C method will depend on a complex colour configuration with the p-benzoquinone reagent, which has a maximum absorption at a wavelength of 285 nm. Beer's law was applied in a range of concentrations between 1 and 10 μg / ml, 2-20 μg / ml and 1-30 μg / ml. The values ​​of the molar absorption factors were (4.1224 × 104, 3.0229 × 104 and 1.7373 × 104) L mol-1cm-1 with a sensitivity of Sandell’s equal to 0.2606 × 10-4, 0.9834 × 10-4 and 0.2568 × 10 - 4 μg cm-2 to methods A, B respectively and LLOD values ​​were 0.255, 0.553 and 0.158 μg / ml to methods A, B and C. LLOQ 0.512, 0.898 and 0.455 μg / ml to methods A, B, C respectively. The constant fixed Kf configuration was also calculated for the colored outputs of the reaction where it was found to be equal to 43.6435 × 108, 54.6261 × 10-8 and 17.29099 × 106 L2 mol-2 to all methods A, B, C respectively. The values ​​of G were calculated based on -43.9293 KJ / mol, -44.3735 and -51.2019. G values, molar absorption factor, Sandell sensitivity, detection limit.
CLIMATE OF ORGANIZATIONAL ETHICS TO BUSINESS SATISFACTION (STUDY OF SME IN SOUTH SULAWESI)
Authors: Taba Idrus , Ismail Muhammad , Sobarsyah Muhammad , Tasrim Tasrim
Published: November 2019

Organizational ethics plays an important role in shaping a good climate for all members of the organization. The ethical issues concerning to social problem, protection of the rights of employees, public society (social responsibility) and also consumers. The application of ethics in organization raises the employee job satisfaction (seeorganizational justice theory and cognitive dissonance theory). This study was analyzed using multiple regression method by taking the object of research on 350 SME businesses in three regencies, East Luwu, Bone and Tana Toraja in South Sulawesi. This study was focused in three forms, namely egoistic ethical climate, benevolent, and principled ethical climate. The results of the study show that organizational climate is like egoistic ethics climate and benevolence ethical climate the organization does not show positive results on employee job satisfaction. However, the coefficient of egoistic climate has negative influence to job satisfaction. Whereas principled ethical climate shows a positive and significant influence on employee job satisfaction.
DEFINING THE ROOT CAUSE OF JAKARTA MBA STUDENTS’ COMPLAINT USING 5-C TQM MODEL OF ACADEMIC EXCELLENCE
Authors: Salam Karta Negara , Salam Sri Wijaya
Published: November 2019

In the competitive world of education, there are many universities competing to improve the quality of education services, employee performance, and produce graduates with integrity and professional skills. One of them is SBM ITB Jakarta which is the location for the research. The purpose of this study was to determine the root causes of the quality of MBA ITB Jakarta services by using a qualitative approach and “5C TQM of academic excellence” model as a guideline to improve the quality of education services. While for the technique of collecting data and analyzing qualitative data using interviews with respondents, the respondents in the study were university staff, lecturers, SBM ITB Jakarta management, and students. The results of the study concluded that there absence of such clear role from every unit involved (in this case SBM ITB Jakarta staff, lecturers, and management) as the root cause of student complaints related to the service quality of SBM ITB Jakarta. Miscommunication and misperception cannot be avoided because every unit has different perceptions and expectations toward each other.
浅析电影“中国风”意境的营造——以《影》为例
Authors: 房 悦
Published: November 2019

众所周知，张艺谋导演在电影中善于运用色彩、光线、构图等来展示奇观的视觉效果，向世界展示不同形象的中国，并借其塑造了一个个有关人性与情感的中国故事。不同于以往的作品，张艺谋导演在最新作品《影》中结合了中国传统文化中的太极图、水墨画、书法、琴瑟等精华，呈现了一个几乎黑白的、水墨式的视觉效果，营造出了阴阳合一、虚实结合、圆动和谐的“中国风”意境。本文将从影片《影》所营造出的“中国风”意境进行分析，探讨其所呈现出的“中国风”意境。
现代漆陶工艺的探讨
Authors: 于 航
Published: November 2019

装饰胎体表面或者陶泥的工艺，指的是现代漆陶工艺，在该工艺当中主要采用了综合材料或者大漆等。漆器工艺和陶瓷工艺的相互融合，共同促进了漆陶工艺的产生与发展。两者在工艺方面存在相同之处，同时也存在较大的差异性。从新石器时期开始，漆陶工艺就已经开始出现，发展至今呈现出不同的特点与变化。本文将通过分析现代漆陶工艺的类别与特点，探索现代漆陶工艺的现状和发展趋势。
艺术介入乡村途径探究——以乌镇横港村为例
Authors: 郭 佳欣
Published: November 2019

用艺术介入乡村，激发本地乡村活力，实现村落经济复苏的方式已成为乡村建设的主流。本文以中国乌镇横港村 2015 至2019 年的乡建成果为研究内容，通过对不同的艺术介入乡村模式的探讨，以及不断变化发展的艺术 IP 理念的分析，总结出一条适应当下乡村建设、可借鉴、可推广的发展道路，为艺术介入乡村的可持续发展提供新的思路。
读者图书借阅权利限定因素的多维思考
Authors: 银 霞
Published: November 2019

中国社会经济及科技水平的迅速发展，推动了人们生活质量水平的不断提升。目前，人们的物质生活丰富多元化，人们对于精神文明的追求也不断上升，文化馆作为丰富人们精神生活的重要载体，只有不断改革发展，才能为满足人们多元化的发展需求。图书馆作为丰富拓展人们知识的重要场所之一，对人们精神文明的发展有着至关重要的作用。基于此，文章简要分析当前读者图书借阅权利限定的因素。
刍议如何做好文艺演出的策划和组织工作
Authors: 谢 君文
Published: November 2019

文艺演出活动包含很多内容，为了能够使演出顺利落幕，需要做好文艺演出活动的策划以及管理工作。作为文艺演出工作的策划人员以及管理人员需要遵循文艺演出的主题，做好节目的遴选和安排等工作，同时还需要掌控好活动的整体进度，保障文艺演出活动能够顺利进行。
Der Sprechende und das Unaussprechliche – Literarische Kunst als „Kampf mit der Sprache“
Authors: Kotin Andriej
Published: November 2019

Der vorliegende Beitrag befasst sich mit dem Problem der Verhältnisse zwischen dem Schreibenden und der Schrift, dem Sprechenden und der Sprache, wobei unter der Letzteren ein unbegrenztes (Selbst) Ausdrucks - und Benennungspotenzial verstanden wird. Die wichtigsten Themen, die in diesem Kontext diskutiert werden – Literatur und andere Kunstformen, die Dialektik der Autor - und Erzählerkonzepte, die Idee des Unaussprechlichen usw. – kreisen um die Kernfrage: Ist es etwa der Autor, der die Sprache benutzt, um bestimmte Gedanken und Gefühle auszudrücken, oder wird er vielleicht selbst benutzt, ja überhaupt kreiert von einem ihm übergeordneten Phänomen, das man ‚Sprache‘ nennt?
Schreiben auf der Schwelle: Zum besonderen Charakter literarischer Beschreibungen des Unsagbaren in der Moderne
Authors: Klein Andreas
Published: November 2019

Der vorliegende Beitrag richtet den Fokus auf die Schwierigkeiten moderner Schriftsteller, transzendente Erfahrungen konkret literarisch zu beschreiben. Im Schwellenzustand der Moderne verbleibt die Kunst als letzter Ort der Darstellung des Absoluten und transzendenter Phänomene. Angesichts des Vertrauensverlusts in religiöse Traditionen sind die Autoren in der Moderne gezwungen, in individueller Weise Worte, Symbole und Metaphern zu finden, um ihre Erfahrungen zur Sprache zu bringen und das Unsagbare doch zu sagen.
„Bilder, eigentlich Worte, eigentlich Evidenzen“ – Konturierungen des Unsagbaren in Friederike Mayröckers Texten zur bildenden Kunst
Authors: Sommerfeld Beate
Published: November 2019

Der Beitrag verortet Friederike Mayröckers Texte zur bildenden Kunst im Kontext des Sprachdenkens der literarischen Moderne. In der medienreflexiven Literatur zu Beginn des zwanzigsten Jahrhunderts fasziniert das Bild als das Andere der Sprache, es verspricht eine Grenzerweiterung der Sprache ins Unsagbare hinein und birgt ein Evidenzversprechen, das die literarische Sprache nicht mehr einzulösen vermag. Anhand von Textbeispielen wird aufgezeigt, wie Mayröckers Sprache sich am Bild als dem Unsagbaren konturiert.
A SUPPORT VECTOR-BASED PREDICTIVE MODEL TO REVEAL THE RELATIONSHIPS AMONG ANTIBODY FEATURES AND THEIR EFFECTIVE FUNCTIONS AGAINST HIV
Authors: SARAC Ferdi
Published: November 2019

Despite 4 decades’ effort, an effective HIV-1 vaccine has not been produced owing to the inevitable antigenic diversity of the virus and millions of people around the world have lost their lives due to HIV. Increasing the knowledge of adaptive immune response to vaccination would ultimately lead to an effective HIV cure. Antibodies, which are responsible for protection and fighting against antigens, are vital parts of immune system response. In order to identify discriminative antibodies, which provide protection against HIV, and to disclose the associations between antibody features and their functional outcomes, computational methods, such as feature selection, regression and classification can be used to construct predictive models. Here we used our unsupervised K-Means Based Feature Selection (KBFS) method which is presented in our previous study, to identify functional antibodies that fight against HIV. The accuracy results for the proposed KBFS framework are compared with those presented in a recent study and are also compared with results from four different state-of-the-art unsupervised feature selection methods, namely MCFS, InFS, LapFS, and SPFS, along with the entire feature set. Then, support vector based systems are utilised to predict the associations between antibody features and their functional activities, namely gp120-specific antibody dependent cellular phagocytosis (ADCP), antibody dependent cellular cytotoxicity (ADCC) and cytokine release activities on RV144 vaccine recipients. Pearson Correlation Coefficient (PCC) metric is used to evaluate the prediction accuracy of the predictive models and to be consistent with the previous study. Our SVR based KBFS framework presented higher accuracy than the original study by improving prediction performance 16% for ADCP assay, 200% for the ADCC assay.
VOLTAMMETRIC AND CHROMATOGRAPHIC DETERMINATION OF NAPROXEN IN DRUG FORMULATION
Authors: YILMAZ Selehattin , YANIK Suzan , SAGLIKOGLU Gulsen , SADIKOGLU Murat , TONGUC YAYINTAS Ozlem
Published: November 2019

In this work, the electrochemical oxidation of naproxen (NAP) was studied at an ultra-trace graphite electrode (UTGE). The cyclic voltammetry (CV) technique was used to determine the optimum conditions and the effect of pH on the electrochemical oxidation of NAP. Acetate buffer (pH 4.50) was selected as the support electrolyte due to obtaining the highest electronic signal increase during oxidation of NAP at UTGE. The differential pulse voltammetry (DPV) technique was performed for electrochemical determination of NAP. In the optimum conditions, the limits of detection (LOD) and quantification (LOQ) were determined to be 8.6610-8 M and 2.8810-7 M. In addition, the amount of NAP was determined in drug tablets. The recovery studies of NAP from the drug tablet were completed in order to check the accuracy and precision of the applied voltammetric method. Furthermore, the determination of NAP was performed with the high-performance liquid chromatography (HPLC) method. These two methods were compared in terms of accuracy, precision and recovery studies.
RESEARCH ABOUT VISITOR PERCEPTIONS OF ÇANAKKALE MARTYRS’ MEMORIAL
Authors: ALKAN Yavuz , KELKİT Abdullah
Published: November 2019

The Martyrs’ Memorial and historical area, located within the boundaries of Çanakkale province and scene of historically important events, is important for all time with significant domestic and foreign visitor potential from Turkey and many other countries. Due to visitor numbers reaching significant amounts, especially in the summer months, the necessity to renovate, develop and ensure sustainability of landscaping infrastructure and furnishings was revealed in line with visitor perceptions. The study applied face-to-face surveys to 100 individuals over the age of 18 years visiting the area. Data obtained from the survey were evaluated with linear regression analysis in the SPSS 15.0 statistical program. The results of the analysis found an R2 value of 0.516, showing that the independent variables of “open and enclosed viewing terraces, car park, furnishings (like pergolas, seating groups, waste bins, digital information panels) and planting” explained 52% of the variation in the dependent variable of “satisfaction rate”. With the ANOVA test, the “p” value of “0.000” was found, indicating that the regression model was significant for the whole study. The VIF value was 3 and above showing no correlations between independent variables and emphasizing that four variables should remain in the model (open and enclosed viewing terraces, furnishings, car park). In conclusion, in line with visitor perceptions, the necessity to include landscaping in the area especially the role of planting as shade and windbreaks, car park, furnishings like pergola, waste bins, digital information panels and seating groups, and open and enclosed viewing terraces was determined. Applications of these appropriate to the day’s conditions and visitor requirements will contribute to visitor satisfaction.
EFFECTS OF SOME OF HEAVY METALS ON TOTAL PROTEIN AMOUNT AND PEROXIDASE ACTIVITY IN SOLANUM LYCOPERSICUM MILL
Authors: YÜCEL Gülru , AKI Cüneyt
Published: November 2019

In this research, different concentrations of cadmium, nickel, copper heavy metals applied on 10 weeks old Solanum lycopersicum Mill. cv. invictus seedlings by irrigation water. As a result of heavy metal applications total protein amount and peroxidase [EC 1.11.1.7] enzyme activity has been determined by spectrophotometrically. Changing in total protein amount and peroxidase activity in S. lycopersicum seedlings after heavy metal applications has been compared with control group. Depending the application of heavy metals on S. lycopersicum seedlings total protein amount decreased as 57% in 100 ppm of copper application and 10,9% increased in 10 ppm nickel application. The highest increases in peroxidase activity 100 ppm of copper applied and in proportion as 536,03% and treated group with 10 ppm nickel in proportion as 5.97%were determined.
Molecular structural properties of [n] annulene (n = 8, 10, 12 and 14) and its boron nitride derivatives: Analysis of NMR, NBO, ELF and PDI
Authors: Monajjemi M. , Mollaamin F.
Published: November 2019

Due to the importance of structural properties of annulene in physical and inorganic chemistry, the trajectory of the NBO to MO evolution can be written as natural atomic orbitals (NAO) → natural hybrid orbital (NHO) → natural bond orbital (NBO) → natural semi-localized MO (NLMO) → MO. The electron density distribution in this [n]-annulene series (both ions and molecules) (n = 8, 10, 12, 14) is investigated by NMR, NBO, ELF, FLU, and PDI analyses. The (4n+2)p and also 4np systems (Hückel's rule) on variants of those compounds via the localized orbital localization (LOL) and electron localized function (ELF) are discussed, and a diatropic ring current (aromatic) is also distinguished for some other paratropic currents (anti-aromatic). The NHO direction and bond bending deviations from the line of nuclear centers are exhibited for understanding the situation of p and s orbitals. In this work, for each NAO function, core, valence, or Rydberg, the orbital occupancy and the orbital energies are discussed. In addition, nucleus independent chemical shifts (NICSs) and statistical nucleus chemical shifts (S-NICSs) confirm the aromaticity and anti-aromaticity amounts in those rings.
[CuEn3]МоO4: синтез, структура, эффект Яна—Теллера, превращения в интервале 100—1263 K
Authors: Храненко С.П. , Сухих А.С. , Николаев Р.Е. , Громилов С.А.
Published: November 2019

Кристаллическая структура [CuEn3]MoO4 (En — этилендиамин) изучена в интервале 100—390 K. Кристаллографические данные при 100 K: а = 27.5808(9), с = 9.9043(4) Å, пр. гр. Р-3, V = 6524.8(4) Å3, Z = 18. Координация атомов меди — искаженная квадратная бипирамида, в трех кристаллографически независимых катионах четыре коротких расстояния Cu—N лежат в интервале 2.041(2)—2.093(2) Å, два длинных в транс-положении — 2.397(2)—2.496(2) Å (при 200 K эти интервалы 2.039(4)—2.148(4) и 2.332(2)—2.461(4) Å соответственно). В интервале от 200 K до 298 K происходит переход к пространственной группе P-3c1 (а = 15.9992(6), с = 9.9385(4) Å, V = 2203.17(19) Å3, Z = 6), расстояния Cu—N сближаются: 2.086(6), 2.162(7), 2.273(8) Å. При 390 K эффект Яна—Теллера исчезает, расстояния Cu—N 2.153(4) Å (а = 9.2785(14), с = 10.0035(18) Å, P-31c, V = 745.8(3) Å3, Z = 2). Показано, что при повышении температуры от 100 K до 320 K средние расстояния Mo—О уменьшаются от 1.766 Å до 1.699 Å. Проведено ex situ рентгенографическое исследование процесса образования металлических и карбидных фаз при термическом разложении [CuEn3]MoO4 в атмосфере Не в присутствии LiH: начиная с 973 K образуется смесь Mo2C и ГЦК-фазы на основе структуры Cu (а ≈ 3.65 Å).
Кристаллические структуры 1,2-бис[(2,6-дибензгидрил- 4-метилфенил)имино]аценафтена
Authors: Москалев М.В. , Разборов Д.А. , Копцева Т.С. , Скатова А.А. , Румянцев Р.В. , Федюшкин И.Л.
Published: November 2019

Кристаллизацией пространственно-затрудненного 1,2-бис[(2,6-дибензгидрил-4-метил­фенил)имино]аценафтена (dbhmp-bian) (1) из тетрагидрофурана (THF) или ацетона выделены и охарактеризованы структурно две кристаллические формы (dbhmp-bian)(THF)3 (1a) и dbhmp-bian (1b). При DFT расчетах (уровень B3LYP/6-31G(d)) не выявлено существенных различий между электронным строением 1 и некоторых других Ar-bian лигандов (Ar = 2,6-Me2—C6H3; 2,6-Et2—C6H3; 2,6-iPr2—C6H3). Энергии ВЗМО и НСМО этих соединений находятся в диапазонах –5.60 ... –5.51 и –2.07 ... –2.04 эВ соответственно. Геометрические параметры дииминового фрагмента лигандов, полученные на основании DFT расчетов и данных РСА, практически аналогичны.
A new Ni(II)-containing coordination complex based on the multiple N-donor ligand: crystal structure and application of its nanoparticle as P. gingivalis biofilm inhibitor for periodontitis treatment
Authors: Gan J.-C. , Zhao J.-J. , Hu Y.-T. , Dai Y.
Published: November 2019

A solvothermal reaction of Ni(NO3)2·6H2O, the multiple N-donor ligand 6,6'-bis(1H-benzo[d]imidazol-2-yl)-2,2'-bipyridine (H2L), in a mixed solvent of DMF and water give rise to a new Ni(II)-containing coordination complex with the chemical formula [Ni(HCOO)(HL)(H2O)] (1). The chemical composition of as-prepared complex 1 is determined via the elemental analysis and the structural arrangement is probed via single crystal X-ray diffraction. Furthermore, we use the grinding method to prepare nanoparticles of complex 1 with an average size of 89 nm. To overcome the difficulty of P. gingivalis infected periodontal diseases, the antibiofilm activity of nano 1 is evaluated by the crystal violet staining assay, and the RT-PCR measurement is performed to detect the activity of nano 1 on reducing hagB and hagC genes expression.
TEACHING THE VOCATIONAL SUBJECTS IN ENGLISH AT THE
UKRAINIAN HIGHER EDUCATION INSTITUTIONS: EDUCATIONAL
EXPERIMENT OR TODAY’S CHALLENGE
(THE CASE OF DISCIPLINES OF THE DEPARTMENT OF ADVERTISING AND PUBLIC
RELATIONS OF HUMANITARIAN INSTITUTE OF BORYS GRINCHENKO KYIV UNIVERSITY)
Authors: Vernyhora Svitlana
Published: November 2019

The article is devoted to the experience of teaching in English of the profile disciplines “Copywriting in
advertising”, “Copywriting in PR”, “Public service advertising”, “Theory of mass information”, “Communication
strategies” of the Department of Advertising and Public Relations of Humanitarian Institute of Borys Grinchenko Kyiv
University. The purpose, results and prospects of development of such direction of students’ teaching are represented.
VALUE APPROACH TO COMMUNICATION
WITH THE TARGET AUDIENCE THROUGH SPIRAL DYNAMICS
Authors: Yezhyzhanska Tetiana
Published: November 2019

The article deals with the peculiarities of value approach to communication with the target audience
through spiral dynamics. It is considered the approaches to building corporate communication through spiral dynamics;
it is explained that the paradigm of thinking, models of values are the certain filters through which the messages of
the company are passing; the peculiarities of communication process for each type of recipients according to the theory
of spiral dynamics are defined.
Using a value approach to segmentation of public organization, which is based on the theory of spiral dynamics, allows
looking more comprehensively at the problem of efficiency of corporate communications. The communication of the
company with its target audiences should be based on the vMemes; the messages of the company should contain such
models of values. Thus, the theory of spiral dynamics allows us to understand the problems of communication efficiency
in the different spheres, including the field of public relations.
THE MAIN MODELS OF PUBLIC RELATIONS
IN THE SOCIO-CULTURAL SPHERE
Authors: Kyianytsia Yevheniia
Published: November 2019

The article analyzes the geographical classification models of public relations used in the cultural sphere.
The selection of such a classification is due to the national cultural specificity, which performs integrative function,
combining artificial objects into stable integrities with separated values and meanings within the society. This all ows
to identify the social groups according to the ir characteristic cultural needs and priorities. Also, the study reveals a
tendency to improvement of adaptation of institutions of socio-cultural sphere in the market environment through the
use of PR-technologies. This trend makes the socio-cultural organization focusing on businessneeds, while articulating
the ir own interests. The article stresses on the importance of active implementation of fundraising technology, the use
of which has to provide for development of institutions that work in the socio-cultural sphere
ARCHETYPE IN A MEDIA TEXT: SPACE IMAGES
Authors: Rosinska Olena A.
Published: November 2019

The article studies the space images that are the basis for the mental fields represented in the Ukrainian media space. In general, the material provided is a part of a comprehensive research devoted to the special nature of space images in the textual communication, including in belles-lettres and media. In the author’s opinion, particular space concepts as a basis of the mental field of the information consumer, specify the interpretation of this information and create an opportunity for miscellaneous information manipulations. In the article a concept of a mental map, which is the key one for the theory of space mental mapping is used. The Ukrainian media space shows a clear opposition of “east”- “west” in the context of establishing the positive/negative and axiological; as well as they display the fixation of particular geographic myths taken as an axiom and failed to become a subject of reflection and re-assessment not only by ordinary information consumers but also by the authors of media texts in the reality changed.
THE TRENDS OF INTRODUCTION OF NEW TECHNOLOGIES INTO DOCUMENTATION PROCESS MANAGEMENT IN TERMS OF SOCIETY INFORMATION
Authors: Herasymiuk Lesia S.
Published: November 2019

The information, like human resources, capital, materials and technology, is one of the main resources used by the institution. Due to its increasing significance in today's society of informatization, more attention is paid to the methods of managing document processes based on documenting and documenting technologies, as well as the active use of computer technology and information technologies.

Therefore, due to insufficient number of domestic works on the topic, the theory and practice of document management, in particular using the latest information technologies, is an actual and perspective direction of scientific research. The article deals with the concept of «documentation processes management».The urgency of the need of new information technologies implementation into the field of documentation support and their efficiency in administrative work has been highlighted. The objective of the study. To analyze the leading tendencies of introduction of
the newest technologies in management of documentation processes in the conditions of information society. The tasks of the study are following:

to disclose the content of the concept “document management”;
to trace the impact of transition to electronic document management on the effectiveness of working with documents in institutions;
to describe the main advantages of electronic document management systems for working with electronic documents.
The results of the study confirmed that due to the continuous increase in the number of information the traditional methods of managing of documentation processes become ineffective. In terms of informatization of the society, the innovative information technologies are rapidly developing, which are rapidly being implemented into the field of documentation procedures.
KURBAN O. V. MODERN CYBERWARFARE: TEXTBOOK. CONTENTS INDEX
Authors: Kurban Sofia
Published: November 2019

The publication is dedicated to the new textbook that was published in
2016 of modern researcher of information space and pedagogue of higher school, Candidate of Sciences in Social Communications O. V. Kurban. The author considers the present topical problems.
Sağlık Çalışanları, Hastalar ve Mdr Uzmanlarının Geleneksel ve Tamamlayıcı Tıp’ın (Getat’ın) Dini Yaşantı ile Etkileşimine Bakışları
Authors: GÖCEN Gülüşan , GÜGEN Büşra
Published: November 2019

Bu makalenin amacı, sağlık çalışanlarının (doktor, tıp öğrencisi ve eczacı), hastaların ve MDR uzmanlarının; a)geleneksel ve tamamlayıcı tıp tanımlarının ne olduğunu b)bireylerin sağlıklarına kavuşabilmek için geleneksel tedavinin öngördüğü yeme-içme davranışlarına yönelmelerine nasıl baktıklarını c) bu uygulamaların tercih edilmesinde neleri etkili gördüklerini tespit etmek d)GETAT uygulamaları ile dini inanç arasında ilişki kurup kurmadıklarını belirlemek ve e)inanç ve sağlık arasındaki bağlantıyı nasıl ele aldıklarını ortaya çıkarmaktır. Bir durum çalışması olarak nitel desende kurgulanan makalede veriler, yarı yapılandırılmış görüşmelerle toplanmıştır. Araştırmanın çalışma grubu, hastalar, sağlık çalışanları ve MDR uzmanları olmak üzere toplam 23 kişiden (17-59 yaş aralığında, 13 kadın ve 10 erkek) oluşmaktadır. Grubun oluşturulmasında maksimum çeşitlilik örneklemeyi de içeren amaçlı örnekleme yönteminden yararlanılmıştır. Araştırma bulgularına göre, sağlık çalışanlarının çoğunlukla “alternatif tıp” kavramının kullanımına; kısmen de “tamamlayıcı tıp” kavramına karşı olup; “bütünleyici tıp” ile “geleneksel tıp” kavramlarına daha makul yaklaştıkları görülmüştür. Hastalar arasında en yoğun kullanım “alternatif tıp” şeklindedir.  Genel olarak doktorlar ve eczacılar GETAT eğitimlerini, geleneksel bilgilerin göz ardı edilmemesi gerekliliğinden hareketle desteklemekte ancak eğitimde uzlaşma ve alan denetimini gerekli görmektedir. Hastalar ve MDR uzmanları inanç ve sağlık ilişkisini dini yönelimleri ile ilişkilendirmeye meyilli ve GETAT’ı dini yaşantıya daha yakın bulurken, sağlık çalışanları bu ilişkiyi tedaviye ve hekime inanç bağlamında algılamakta ve GETAT’ı çoğunlukla dini çevrelerce suiistimal edilmeye açık bir sağlık yönelimi olarak değerlendirmektedir.
In Memoriam: Dr. Almeida Gonçalves (1929-2011)
Authors: Marques Maria São José
Published: November 2019

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AS ASSOCIAÇÕES DE DOENTES – EM QUE MEDIDA PERVERTEM A PRÁTICA MÉDICA? – PROF. HON. EDOUARD GROSSHANS
Authors: Baptista A. Poiares
Published: November 2019

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VASCULITES SISTÉMICAS PRIMÁRIAS DA INFÂNCIA
Authors: Pereira Nádia , Amaro Cristina
Published: November 2019

As vasculites sistémicas constituem um grupo de doenças, pouco frequentes na infância, caracterizadas por inflamação e necrose vascular. A sua tradução clínica é heterogénea, condicionada pelo tipo de vaso e orgão afectados. Recentemente foi proposta uma classificação das vasculites em idade pediátrica, que tem em conta a dimensão dos vasos envolvidos, sendo também validados critérios de diagnóstico para os tipos mais frequentes em crianças. A presente revisão tem como objectivo abordar os tipos mais frequentes de vasculites na infância, suas ma- nifestações clínicas, diagnóstico e terapêutica.PALAVRAS-CHAVE – Vasculites; Criança.
NEVOS RECORRENTES – UMA REVISÃO DE 5 ANOS
Authors: Maio Paula , Antunes Joana , Pacheco David , De Almeida Luís Soares , Marques Manuel Sacramento
Published: November 2019

A persistência de uma lesão melanocítica, em local onde tenha sido previamente excisado um nevo me- lanocítico pode colocar, clínica e histologicamente, problemas no diagnóstico diferencial com melanoma, designado por alguns autores como ‘pseudomelanoma’. Neste estudo, os autores pretendem realizar uma análise comparativa entre os achados clínicos e histopatológicos das lesões melanocíticas primárias e dos nevos recorrentes. Procura-se também avaliar eventuais factores predisponentes para este fenómeno.PALAVRAS-CHAVE – Nevo recorrente; Pseudomelanoma; Melanoma; Regressão.
RETALHO DE AVANÇO V-Y DE PEDÍCULO PROXIMAL PARA ENCERRAMENTO DE DEFEITO CIRÚRGICO DO DORSO DA MÃO
Authors: Tavares Ermelindo , Castellano David Pacheco , Rosa José
Published: November 2019

Introdução: O retalho de avanço V-Y é largamente utilizado na reconstrução de defeitos cirúrgicos da face, particularmente das regiões perioculares ou palpebrais. Sua utilização noutras localizações tem vindo a ter no- vas indicações com elevada qualidade reconstrutiva. Relato de caso: Doente do sexo feminino, de 86 anos, subme- tida a exérese alargada de carcinoma espinocelular do dorso da mão direita. O defeito cirúrgico foi encerrado com retalho de avanço V-Y de pedículo proximal que emergiu a partir do bordo radial da mão. Não se observou necrose parcial ou total do retalho. O resultado estético foi bastante aceitável. Conclusão: O retalho de avanço V-Y é uma alternativa viável na reconstrução dos defeitos cirúrgicos do dorso da mão. PALAVRAS-CHAVE – Mão; Carcinoma espinocelular; Retalho pediculado; Transplantação de pele.
Carta ao Editor
Authors: Bello Rui Tavares
Published: November 2019

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ALERGIA A FÁRMACOS COM MANIFESTAÇÕES CUTÂNEAS - ABORDAGEM DIAGNÓSTICA
Authors: Antunes João , Brás Susana , Prates Sara , Amaro Cristina , Leiria-Pinto Paula
Published: November 2019

As reacções adversas a fármacos (RAF) representam um problema frequente na prática clínica. A alergia a fármacos resulta de mecanismos de hipersensibilidade imunológica e representa 6-10% do total de RAF. Clinica- mente, as reacções alérgicas a fármacos podem ser classificadas como imediatas (tipo I) ou não-imediatas (com manifestações clínicas diversas e associadas sobretudo a reacções de tipo IV). Neste artigo são abordados aspectos gerais, nomeadamente os mecanismos imunopatogénicos implicados na alergia a fármacos e reactividade cruzada mas também as manifestações cutâneas mais relevantes, nomeadamente exantemas máculo-papulares, eritema fixo a fármacos (EFF), pustulose exantemática aguda generalizada (PEAG), síndrome de hipersensibilidade a fármacos (DRESS – drug rash with eosinophilia and systemic symptoms), síndrome de Stevens-Johnson/necrólise epidérmica tóxica (SSJ/NET). O papel dos testes cutâneos (epicutâneos ou intradérmicos de leitura tardia) na abordagem de reacções não-imediatas é também revisto. Os beta-lactâmicos (BL) são o grupo farmacológico mais frequentemente envolvido em reacções de hipersensibilidade imunológica e que mais dificuldades coloca na prática clínica diária, nomeadamente devido aos riscos de reactividade cruzada, pelo que é analisado em maior detalhe ao longo da revisão. A indução de tolerância a fármacos poderá ser considerada em casos selecionados, sobretudo quando na ausência de alternativas terapêuticas igualmente eficazes ou seguras.PALAVRAS-CHAVE – Hipersensibilidade a fármacos; Beta-Lactâmicos; Reactividade cruzada; Testes cutâneos.
SARCOMAS CUTÂNEOS – DO DIAGNÓSTICO AO TRATAMENTO
Authors: Fernandes Sónia , Pinto Gabriela Marques , Moura Cecília , Afonso Ana , Cardoso Jorge
Published: November 2019

O diagnóstico dos sarcomas cutâneos é desafiante, devido à complexidade e heterogeneidade deste gru- po de lesões, cuja apresentação nos tecidos superficiais (pele e tecido celular subcutâneo) impõe diagnóstico diferen- cial obrigatório com tumores benignos e processos inflamatórios. Apesar de serem tumores pouco frequentes alguns tipos assumem grande importância por serem localmente invasivos, com elevada morbi-mortalidade associada, taxas de recidiva local e metastização significativas. Os autores apresentam cinco casos clínico-patológicos de sarcomas cutâneos – sarcoma de Kaposi, dermatofibros- sarcoma protuberans, fibroxantoma atípico, leiomiossarcoma e angiossarcoma – e fazem uma breve revisão da literatura sobre os tipos de sarcoma cutâneo com maior interesse na Dermatologia, salientando os aspectos fisiopa- tológicos, clínicos, histopatológicos e terapêuticos particulares.PALAVRAS-CHAVE – Neoplasias da pele; Sarcoma, Sarcoma de Kaposi; Dermatofibrossarcoma protuberans; Fibro- xantoma atípico, Leiomiossarcoma; Angiossarcoma; Lipossarcoma, Neoplasia da bainha do nervo periférico.
INCISÕES DE RELAXAMENTO PARA REPARAÇÃO DE DEFEITOS CIRÚRGICOS DE GRANDES DIMENSÕES NO COURO CABELUDO
Authors: Pacheco David , Travassos Ana Rita , Fraga Ana , André Marisa , Soares Rui Oliveira , Marques Manuel Sacramento
Published: November 2019

Doente do sexo masculino de 91 anos de idade, caucasiano, fototipo II, com nódulo ulcero-vegetante de 35x40mm, localizado na região parietal direita. Devido a dimensão do defeito não se conseguiu realizar encer- ramento primário, pelo que se optou por fazer incisões de relaxamento paralelas ao defeito cirúrgico. As incisões de relaxamento para correção de grandes defeitos do couro cabeludo e proposta como uma alternativa eficaz, que evita a realização de retalhos ou enxertos complexos, e que tem um resultado cosmético aceitável.PALAVRAS-CHAVE – Incisões de relaxamento; Cirurgia reconstrutiva; Couro cabeludo.
REKONSTRUKSI PENDIDIKAN ISLAM DALAM PERSPEKTIF MUHAMMAD ABDUH
Authors: Jamaluddin Muhammad , Laili Moh. , Rosyid Moh. Zaiful
Published: November 2019

Education is a major milestone in advancing a nation, with a good nation's education will make a nation that is developed, peaceful and prosperous. Muhammad Abduh planned that there would be a concrete change in education at that time, he had an important role in an al-Azhar tertiary education. Muhammad Abduh slowly entered the education curriculum starting from the basic, secondary, upper and tertiary level curriculum, as well as the philosophy of education in the existing courses at al-Azhar higher education, not only stopped in the curriculum, Muhammad Abduh also made improvements to the methods learning method, because at that time the method applied was only focused on writing and memorizing, so according to Muhammad Abduh it was very difficult for students to progress and develop, so with that all Muhammad Abduh gave a new method, namely Discussion. Because the discussion learning method of a student will increase his scientific insight.
REGIONAL INPUT-OUTPUT MATRICES AND AN APPLICATION TO ANALYZE A MANUFACTURING EXPORT SHOCK IN MEXICO
Authors: A. Alvarado Jorge , Quiroga Miroslava , E. Torre Leonardo , I. Chiquiar Daniel
Published: November 2019

Based on the national Input-Output Matrix (IOM) 2012 calculated by INEGI, we estimate with the Flegg approach four regional Input-Output Matrices (RIOMs) using Banco de México’s regionalization (Northern, North-Central, Central and Southern). These RIOMs are employed to evaluate the impact on regional gross output, value added and employment from a 10,000 million dollar shock on Mexican manufacturing exports. The results show that the effects on the absolute values of gross output, value added and employment in the North are clearly larger than those estimated for the other regions. Another finding is that the total effects of the regional shocks tend to concentrate in the manufacturing sector, with the highest concentration observed in the North, and the lowest in the South. It is also shown that the North is, by far, the region experiencing the greatest change in its value added relative to GDP, followed by the North Central, the Central and the South. The results suggest a strong linkage between the manufacturing sector and tertiary activities, particularly commerce and services in the central regions, as well as between manufacturing and oil and gas extraction in the South.
Los Estudiantes de Pregrado en Ecuador: Un Análisis de Datos
Authors: Stefos Efstathios
Published: November 2019

El objetivo del estudio es analizar y presentar características demográficas y sociales de los estudiantes de pregrado en Ecuador, para lo cual se ha realizado un análisis estadístico descriptivo y un análisis estadístico multidimensional utilizando datos de la Encuesta Nacional de Empleo, Desempleo y Subempleo del año 2017. El 86.26% de los estudiantes matriculados en Universidades del Ecuador vive en área urbana y el 13.74% en área rural; el 89.39% se consideran mestizos, el 3.35% indígenas, el 4.25% afroecuatorianos, negros o mulatos, el 1.67% se consideran montubios y el 1.29% blancos; el 66.60% de los alumnos de pregrado en Ecuador estudia en universidades públicas y el 32.54% en universidades particulares; el 8.27% se consideran pobres.
EFEKTIVITAS PELATIHAN IDENTIFIKASI ANAK BERKEBUTUHAN KHUSUS PADA GURU SEKOLAH INKLUSI
Authors: Satwika Yohana Wuri , Khoirunnisa Riza Noviana , Laksmiwati Hermien , Jannah Miftakhul
Published: November 2019

Kemampuan guru sekolah inklusi dalam melakukan identifkasi anak berkebutuhan khusus sangat diperlukan agar dapat memberikan pelayanan pendidikan yang sesuai. Guru sekolah inklusi harus mengetahui jenis-jenis, gejala dan ciri-ciri anak berkebutuhan khusus untuk dapat melakukan identifikasi yang sesuai. Tujuan penelitian ini adalah mengetahui efektivitas pelatihan identifikasi anak berkebutuhan khusus (ABK) pada guru sekolah inklusi. Penelitaian ini adalah penelitian kuasi eksperimen dengan rancangan one group pre-test dan post-test design. Peserta dalam pelatihan identifikasi ABK ini adalah guru-guru yang menangani siswa ABK dengan jumlah 30 orang. Analisis dilakukan dengan paired sample t-test dengan nilai signifikansi 0,000 < alpha (0.05). Hasil penelitian ini menunjukkan bahwa pelatihan identifikasi ABK ini efektif bagi para guru di sekolah inklusi. Kemampuan para guru sekolah inklusi dalam melakukan identifikasi pada ABK mengalami peningkatan setelah dilakukannya pelatihan.Kata Kunci: Pelatihan dentifikasi ABK, guru sekolah inklusi.