bluuebunny/crossref_metadata_2025 huggingface dataset:
Thermal Stability of Polycaprolactone Grafted Densely with Maleic Anhydride Analysed Using the Coats–Redfern Equation
Authors: Thangunpai Kotchaporn , Hu Donghao , Su Xianlong , Kajiyama Mikio , Neves Marcos A. , Enomae Toshiharu
Published: October 2022

The plastic waste problem has recently attracted unprecedented attention globally. To reduce the adverse eff ects on environments, biodegradable polymers have been studied to solve the problems. Poly(ε-caprolactone) (PCL) is one of the common biodegradable plastics used on its own or blended with natural polymers because of its excellent properties after blending. However, PCL and natural polymers are difficult to blend due to the polymers’ properties. Grafted polymerization of maleic anhydride and dibenzoyl peroxide (DBPO) with PCL is one of the improvements used for blending immiscible polymers. In this study, we first focused on the effects of three factors (stirring time, maleic anhydride (MA) amount and benzoyl peroxide amount) on the grafting ratio with a maximum value of 4.16% when applying 3.000 g MA and 1.120 g DBPO to 3.375 g PCL with a stirring time of 18 h. After that, the grafting condition was studied based on the kinetic thermal decomposition and activation energy by the Coats–Redfern method. The optimal fitting model was confirmed by the determination coefficient of nearly 1 to explain the contracting volume mechanism of synthesized PCL-g-MA. Consequently, grafted MA hydrophilically augmented PCL as the reduced contact angle of water suggests, facilitating the creation of a plastic–biomaterial composite.
Preparation and Characterization of Cyclodextrin Coated Red Phosphorus Double−Shell Microcapsules and Its Application in Flame Retardant Polyamide6
Authors: Lu Shangkai , Liu Junbang , Zeng Lijuan , Ai Lianghui , Liu Ping
Published: October 2022

Using the melamine borate and crosslinked β−cyclodextrin as shell materials, the double−shell microcapsules (Mic−DP) of red phosphorus (RP) was prepared, and its flame−retardant effect on polyamide 6 (PA6) was investigated. Compared with RP, Mic−DP showed lower hygroscopic and better inoxidizability. The limiting oxygen index (LOI) of PA6/13%Mic−DP was 27.8%, and PA6/13%Mic−DP reached V−0 rating. After the addition of 13% Mic−DP, the total exothermic (THR), peak exothermic (PK−HRR), and average effective thermal combustion (AV−EHC) rates of PA6 decreased. In addition, in order to investigate its flame−retardant mechanism, the pyrolysis gas chromatography−mass spectrometry (Py−GC−MS), scanning electron microscopy (SEM), and Fourier transform infrared (FT−IR) methods were used, and the results showed that mic DP acted as a flame retardant in the gas and condensed phases. The Mic−DP exhibited good compatibility and dispersibility in PA6.
The Synthesis of Bio-Based Michael Donors from Tall Oil Fatty Acids for Polymer Development
Authors: Pomilovskis Ralfs , Mierina Inese , Beneš Hynek , Trhlíková Olga , Abolins Arnis , Fridrihsone Anda , Kirpluks Mikelis
Published: October 2022

In this study, the synthesis of a Michael donor compound from cellulose production by-products—tall oil fatty acids—was developed. The developed Michael donor compounds can be further used to obtain polymeric materials after nucleophilic polymerization through the Michael reaction. It can be a promising alternative method for conventional polyurethane materials, and the Michael addition polymerization reaction takes place under milder conditions than non-isocyanate polyurethane production technology, which requires high pressure, high temperature and a long reaction time. Different polyols, the precursors for Michael donor components, were synthesized from epoxidized tall oil fatty acids by an oxirane ring-opening and esterification reaction with different alcohols (trimethylolpropane and 1,4-butanediol). The addition of functional groups necessary for the Michael reaction was carried out by a transesterification reaction of polyol hydroxyl groups with tert-butyl acetoacetate ester. The following properties of the developed polyols and their acetoacetates were analyzed: hydroxyl value, acid value, moisture content and viscosity. The chemical structure was analyzed using Fourier transform infrared spectroscopy, gel permeation chromatography, size-exclusion chromatography and nuclear magnetic resonance. Matrix-assisted laser desorption/ionization analysis was used for structure identification for this type of acetoacetate for the first time.
Image-Based Evaluation of In Vivo Degradation for Shape-Memory Polymer Polyurethane Foam
Authors: Graul Lance M. , Horn Staci J. , Nash Landon D. , Cheung Thomas B. , Clubb Fred J. , Maitland Duncan J.
Published: October 2022

Shape-memory polymer (SMP) polyurethane foams have been applied as embolic devices and implanted in multiple animal models. These materials are oxidatively degradable and it is critical to quantify and characterize the degradation for biocompatibility assessments. An image-based method using high-resolution and magnification scans of histology sections was used to estimate the mass loss of the peripheral and neurovascular embolization devices (PED, NED). Detailed analysis of foam microarchitecture (i.e., struts and membranes) was used to estimate total relative mass loss over time. PED foams implanted in porcine arteries showed a degradation rate of ~0.11% per day as evaluated at 30-, 60-, and 90-day explant timepoints. NED foams implanted in rabbit carotid elastase aneurysms showed a markedly faster rate of degradation at ~1.01% per day, with a clear difference in overall degradation between 30- and 90-day explants. Overall, membranes degraded faster than the struts. NEDs use more hydrophobic foam with a smaller pore size (~150–400 μm) compared to PED foams (~800–1200 μm). Previous in vitro studies indicated differences in the degradation of the two polymer systems, but not to the magnitude seen in vivo. Implant location, animal species, and local tissue health are among the hypothesized reasons for different degradation rates.
Mechanical and Thermal Properties of Functionally Graded Polyolefin Elastomer Foams
Authors: Rostami-Tapeh-Esmaeil Ehsan , Shojaei Sahar , Rodrigue Denis
Published: October 2022

In this work, uniform and graded polyolefin elastomer (POE) foams were prepared using a single-step technology based on a fixed chemical blowing agent (azodicarbonamide) concentration of 4 phr (parts per hundred rubber). The effect of molding temperature, including the average temperature (Tavg) and temperature difference (ΔT), on the foams’ morphology, mechanical properties (tension, compression and hardness) and thermal conductivity was investigated. Two series of samples were produced by fixing Tavg with different ΔT or setting different ΔT, leading to different Tavg. The morphological analyses showed that two or three regions inside the foams were produced depending on the molding conditions, each region having different cellular structure in terms of cell size, cell density and cell geometry. The results obtained for the conditions tested showed a range of density (0.55–0.72 g/cm3), tensile modulus (0.44–0.70 MPa) and compression elastic modulus (0.35–0.71 MPa), with a thermal conductivity between 0.125 and 0.180 W/m.K. Based on the information provided, it can be concluded that the foam’s properties can be easily controlled by the cellular structure and that graded samples are more interesting than uniform ones, especially for thermal insulation applications, such as packaging, construction, transportation, automotive and aerospace industries.
Chemical and Enzymatic Fiber Modification to Enhance the Mechanical Properties of CMC Composite Films
Authors: Li Xiaobao , Tang Zhengjie , Sun Zhenbing , Simonsen John , Luo Zhinan , Li Xiaoping , Morrell Jeffery J.
Published: October 2022

Carboxymethyl cellulose (CMC) is a cellulose derivative that can be obtained from wood, bamboo, rattan, straw, and other cellulosic materials. CMC can be used to produce biofilms for many purposes, but the properties of these resulting films make them unsuitable for some applications. The effects of three kinds of plant fiber addition on CMC film properties was investigated using CMC derived from eucalyptus bark cellulose. Tensile strength (TS) and elongation at break (EB) of CMC/sodium alginate/glycerol composite films were 26.2 MPa and 7.35%, respectively. Tensile strength of CMC composite films substantially increased, reaching an optimum at 0.50 g of fiber. The enhancement due to industrial hemp hurd fiber on CMC composite films was more obvious. Pretreatment with hydrogen peroxide (H2O2) and glacial acetic acid (CH3COOH) produced films with a TS of 35.9 MPa and an EB of 1.61%. TS values with pectinase pretreated fiber films was 41.3 MPa and EB was 1.76%. TS of films pretreated with pectinase and hemicellulase was 45.2 MPa and EB was 4.18%. Chemical and enzymatic treatment both improved fiber crystallinity, but film tensile strength was improved to a greater extent by enzymatic treatment. Surface roughness and pyrolysis residue of the film increased after fiber addition, but Fourier transform infrared spectroscopy (FTIR), opacity, and water vapor transmission coefficients were largely unchanged. Adding fiber improved tensile strength of CMC/sodium alginate/glycerol composite films and broadened the application range of CMC composite films without adversely affecting film performance.
Fully Coupled Three-Dimensional Simulation of Downward Flame Spread over Combustible Material
Authors: Snegirev A. , Kuznetsov E. , Korobeinichev O. , Shmakov A. , Paletsky A. , Shvartsberg V. , Trubachev S.
Published: October 2022

Three-dimensional simulations of laminar flame propagating downwards the vertical surface of a rigid polyurethane slab heated by a radiative panel are presented and compared with the measurement data. The gas-phase model (ANSYS Fluent) allows for finite-rate volatile oxidation, soot formation and oxidation, emission, transfer, and absorption of thermal radiation. The solid-phase model Pyropolis considers heat transfer across the material layer and generation of combustible volatiles in thermal decomposition of the material. Kinetic model of material decomposition is derived to obey the microscale combustion calorimetry data for different heating rates. Transient behavior of propagating flame and pyrolysis zone, as well as spatial distributions of heat flux components, temperature, and mass burning rates over the specimen surface are examined. Variation of the thermal properties of the material during its thermal decomposition, as well as the specimen surface emissivity and reradiation are shown to be the important issues strongly affecting model predictions. Two distinct modes of counterflow flame spread, thermal and kinetic, are identified. In the thermal mode corresponding to fast chemistry in the gaseous flame, the flame propagation velocity is governed by the heating rate of the combustible material ahead of the flame front. Alternatively, in the kinetic mode, it is limited by the burning velocity of the volatile-air mixture forming ahead of the flame front. Simulation results are favorably compared with the measured propagation velocity.
Effect of 3-Hydroxyvalerate Content on Thermal, Mechanical, and Rheological Properties of Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) Biopolymers Produced from Fermented Dairy Manure
Authors: Abbasi Maryam , Pokhrel Dikshya , Coats Erik R. , Guho Nicholas M. , McDonald Armando G.
Published: October 2022

Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) with various 3-hydroxyvalerate (3HV) contents biosynthesized by mixed microbial consortia (MMC) fed fermented dairy manure at the large-scale level was assessed over a 3-month period. The thermal, mechanical, and rheological behavior and the chemical structure of the extracted PHBV biopolymers were studied. The recovery of crude PHBV extracted in a large Soxhlet extractor with CHCl3 for 24 h ranged between 20.6% to 31.8% and purified to yield between 8.9% to 26.9% all based on original biomass. 13C-NMR spectroscopy revealed that the extracted PHBVs have a random distribution of 3HV and 3-hydroxybutyrate (3HB) units and with 3HV content between 16% and 24%. The glass transition temperature (Tg) of the extracted PHBVs varied between −0.7 and −7.4 °C. Some of the extracted PHBVs showed two melting temperatures (Tm) which the lower Tm1 ranged between 126.1 °C and 159.7 °C and the higher Tm2 varied between 152.1 °C and 170.1 °C. The weight average molar mass of extracted PHBVs was wide ranging from 6.49 × 105 g·mol−1 to 28.0 × 105 g·mol−1. The flexural and tensile properties were also determined. The extracted polymers showed a reverse relationship between the 3HV content and Young’s modulus, tensile strength, flexural modulus, and flexural strength properties.
Novel Transparent Films Composed of Bisphenol-A Polycarbonate and Copolyester
Authors: Hasegawa Hiroyuki , Kida Takumitsu , Yamaguchi Masayuki
Published: October 2022

In this paper, the structure and properties of transparent films composed of bisphenol-A polycarbonate (PC) and a commercially available copolyester, poly(1,4-cyclohexanedimethanol-co-2,2,4,4-tetramethyl-1,3-cyclobutanediol-co-terephthalate) (CPE), were studied. Both PC and CPE films are known to be transparent with good mechanical toughness. It was found that PC/CPE (50/50) showed miscibility in both the molten and solid states, indicating that there is a high possibility for the blend system to be miscible in the whole blend ratios. Because of the miscibility, the blend films showed no light scattering originating from phase separation. The mechanical properties of the films, such as Young’s modulus, yield stress, and strain at break, were determined by the blend ratio, and the glass transition temperature increased with the PC content, which corresponded well with the values predicted by the Fox equation. These results demonstrate that the thermal and mechanical properties of the films can only be controlled by the blend ratio. Since these transparent films showed excellent mechanical toughness irrespective of the blend ratios, they can be employed in various applications.
Nano-Hydroxyapatite from White Seabass Scales as a Bio-Filler in Polylactic Acid Biocomposite: Preparation and Characterization
Authors: Injorhor Preeyaporn , Trongsatitkul Tatiya , Wittayakun Jatuporn , Ruksakulpiwat Chaiwat , Ruksakulpiwat Yupaporn
Published: October 2022

Nano-hydroxyapatite (nHAp) as a bio-filler used in PLA composites was prepared from fish by acid deproteinization (1DP) and a combination of acid-alkali deproteinization (2DP) followed by alkali heat treatment. Moreover, the PLA/nHAp composite films were developed using solution casting method. The mechanical and thermal properties of the PLA composite films with nHAp from different steps deproteinization and contents were compared. The physical properties analysis confirmed that the nHAp can be prepared from fish scales using both steps deproteinization. 1DP-nHAp showed higher surface area and lower crystallinity than 2DP-nHAp. This gave advantage of 1DP-nHAp for use as filler. PLA composite with 1DP-nHAp gave tensile strength of 66.41 ± 3.63 MPa and Young’s modulus of 2.65 ± 0.05 GPa which were higher than 2DP-nHAp at the same content. The addition of 5 phr 1DP-nHAp into PLA significantly improved the tensile strength and Young’s modulus. PLA composite solution with 1DP-nHAp at 5 phr showed electrospinnability by giving continuous fibers without beads.
Smart Composites and Processing
Authors: Kim Kwang-Jea
Published: October 2022

Polymer composites have been at the forefront of research in recent decades as a result of the unique properties they provide for utilization in numerous applications [...]
Cellulose Fibre Degradation in Cellulose/Steel Hybrid Geotextiles under Outdoor Weathering Conditions
Authors: Manian Avinash Pradip , Paul Barbara , Lanter Helene , Bechtold Thomas , Pham Tung
Published: October 2022

Risks from rockfall and land sliding can be controlled by high-tensile steel nets and meshes which stabilise critical areas. In many cases, a recultivation of the land is also desired. However, high-tensile steel meshes alone are not always sufficient, depending on the location and the inclination of the stabilised slope, to achieve rapid greening. Cellulose fibres exhibit high water binding capacity which supports plant growth. In this work, a hybrid structure consisting of a nonwoven cellulose fibre web and a steel mesh was produced and tested under outdoor conditions over a period of 61 weeks. The cellulose fibres are intended to support plant growth and soil fixation, and thus the biodegradation of the structure is highly relevant, as these fibres will become part of the soil and must be biodegradable. The biodegradation of the cellulose fibres over the period of outdoor testing was monitored by microscopy and analytical methods. The enzymatic degradation of the cellulose fibres led to a reduction in the average degree of polymerisation and also a reduction in the moisture content, as polymer chain hydrolysis occurs more rapidly in the amorphous regions of the fibres. FTIR analysis and determination of carboxylic group content did not indicate substantial changes in the remaining parts of the cellulose fibre. Plant growth covered geotextiles almost completely during the period of testing, which demonstrated their good compatibility with the greening process. Over the total period of 61 weeks, the residual parts of the biodegradable cellulose web merged with the soil beneath and growing plants. This indicates the potential of such hybrid concepts to contribute a positive effect in greening barren and stony land, in addition to the stabilising function of the steel net.
Performance Analysis of PLA Material Based Micro-Turbines for Low Wind Speed Applications
Authors: Aljafari Belqasem , Samithas Devakirubakaran , Balachandran Praveen Kumar , Anandan Sambandam , Babu Thanikanti Sudhakar
Published: October 2022

Various studies have been conducted in recent years to find solutions to the issues in wind energy conversion systems. A 100W horizontal axis micro wind turbine is built for low wind speed applications in this work. The Blade Element Momentum theory approach was used to design the 100W micro wind turbine blade. The wind turbine blade 3D model was created using the CREO CAD 3.0 software. Based on the aerodynamic studies, the airfoil S9000 is chosen among others for generating high power at low wind speed. The density, Young’s modulus, and the Poisson ratio of the proposed wind turbine blade model with acrylonitrile butadiene styrene (ABS) and polylactic acid (PLA) materials were compared. ABS and PLA materials were investigated using a 0.33 mm layer of infill ranging from 10% to 100%. PLA and ABS output values were compared in terms of deformation, equivalent stress, and equivalent strain. PLA materials, on the other hand, have less deformation and greater structural properties than ABS materials. The wind blade structural analysis was performed in ANSYS 15 software, and the details of experimental and simulated results are presented in this paper.
Overviews on the Progress of Flowable Dental Polymeric Composites: Their Composition, Polymerization Process, Flowability and Radiopacity Aspects
Authors: Vouvoudi Evangelia C.
Published: October 2022

A review article has been conducted including the main research results and comments referring to flowable dental polymeric materials. To begin with, the synthesis and composition of this category of composites is discussed, revealing the major components of the commercial products in terms of chemistry and proportion. Later, the polymerization characteristics are unfolded regarding the reaction time and rate, volumetric shrinkage and depth of cure for both photocurable and self-curable composites. To continue, some perspectives of the pre-treatment or accompanying processes that a clinician may follow to enhance the materials’ performance are described. Fluidity is certainly associated with the progress of polymerization and the in-depth conversion of monomers to a polymeric network. Last, the aspects of radiopacity and translucency are commented on, showing that all flowable polymeric composites satisfy the radiography rule, while the masking ability depends on the fillers’ properties and specimen thickness. The reviewing article is addressed to all field scientists and practitioners dealing with flowable dental composites studies or applications.
Styrene-Free Bio-Based Thermosetting Resins with Tunable Properties Starting from Vegetable Oils and Terpenes
Authors: Bertini Fabio , Vignali Adriano , Marelli Marcello , Ravasio Nicoletta , Zaccheria Federica
Published: October 2022

The substitution of fossil-based monomers in the thermosetting formulations is a fundamental issue to face the environmental concerns related to the use of traditional resins. In this paper, styrene-free thermosetting resins were prepared to start from vegetable oils with different compositions and unsaturation degrees, namely soybean, hempseed, and linseed oils. Using terpenic comonomers such as limonene and β-myrcene allows one to prepare thermosets avoiding the traditional fossil-based diluents such as styrene, thus obtaining an outstanding gain in terms of both environmental and safety concerns. Furthermore, the materials obtained reveal tunable physical properties upon the proper choice of the monomers, with glass transition temperature ranging from 40 to 80 °C and Young’s modulus ranging from 200 to 1800 MPa. The possibility of preparing composite materials starting from the resins prepared in this way and natural fibres has also been explored due to the potential applications of bio-based composites in several industrial sectors.
Knot Factories with Helical Geometry Enhance Knotting and Induce Handedness to Knots
Authors: Rusková Renáta , Račko Dušan
Published: October 2022

We performed molecular dynamics simulations of DNA polymer chains confined in helical nano-channels under compression in order to explore the potential of knot-factories with helical geometry to produce knots with a preferred handedness. In our simulations, we explore mutual effect of the confinement strength and compressive forces in a range covering weak, intermediate and strong confinement together with weak and strong compressive forces. The results find that while the common metrics of polymer chain in cylindrical and helical channels are very similar, the DNA in helical channels exhibits greatly different topology in terms of chain knottedness, writhe and handedness of knots. The results show that knots with a preferred chirality in terms of average writhe can be produced by using channels with a chosen handedness.
Mushroom β-Glucan Recovered from Antler-Type Fruiting Body of Ganoderma lucidum by Enzymatic Process and Its Potential Biological Activities for Cosmeceutical Applications
Authors: Vaithanomsat Pilanee , Boonlum Nutthamon , Chaiyana Wantida , Tima Singkome , Anuchapreeda Songyot , Trakunjae Chanaporn , Apiwatanapiwat Waraporn , Janchai Phornphimon , Boondaeng Antika , Nimitkeatkai Hataitip , Jarerat Amnat
Published: October 2022

Mushrooms are incredibly valuable macro fungi that are an important and integral part of the ecosystem. In addition to being used as cuisine, mushrooms have been used for medicinal purposes for many centuries. This research applied a process for recovering β-glucan (BG) from the antler-type fruiting body of Ganoderma lucidum as well as tested the biological activities related to cosmeceutical applications. The characterization of complex structure was performed by fourier-transform infrared (FTIR) and nuclear magnetic resonance (MNR) spectroscopies. The obtained extract contained 40.57% BG and 7.47% protein, with the detectable bioactivities of anti-tyrosinase and antioxidation. Consequently, it showed the activity that can be used to whiten the skin by reducing or inhibiting the process of skin pigmentation. The BG also showed moderate activities of anti-collagenase, anti-elastase, and anti-hyaluronidase. The test by the HET-CAM confirmed no skin irritation of the complex extract. Based on human peripheral blood mononuclear cell (PBMC) test, the BG had no significant inhibiting effect on cell viability. In addition, the obtained BG had functional properties higher than commercially available BG, especially oil-binding capacity. These findings provided new insights into the potential application of G. lucidum BG as a polymeric material in the cosmeceutical industries.
Chain-End Functionalization of Poly(ε-caprolactone) for Chemical Binding with Gelatin: Binary Electrospun Scaffolds with Improved Physico-Mechanical Characteristics and Cell Adhesive Properties
Authors: Nifant’ev Ilya , Besprozvannykh Victoria , Shlyakhtin Andrey , Tavtorkin Alexander , Legkov Sergei , Chinova Maria , Arutyunyan Irina , Soboleva Anna , Fatkhudinov Timur , Ivchenko Pavel
Published: October 2022

Composite biocompatible scaffolds, obtained using the electrospinning (ES) technique, are highly promising for biomedical application thanks to their high surface area, porosity, adjustable fiber diameter, and permeability. However, the combination of synthetic biodegradable (such as poly(ε-caprolactone) PCL) and natural (such as gelatin Gt) polymers is complicated by the problem of low compatibility of the components. Previously, this problem was solved by PCL grafting and/or Gt cross-linking after ES molding. In the present study, composite fibrous scaffolds consisting of PCL and Gt were fabricated by the electrospinning (ES) method using non-functionalized PCL1 or NHS-functionalized PCL2 and hexafluoroisopropanol as a solvent. To provide covalent binding between PCL2 and Gt macromolecules, NHS-functionalized methyl glutarate was synthesized and studied in model reactions with components of spinning solution. It was found that selective formation of amide bonds, which provide complete covalent bonding of Gt in PCL/Gt composite, requires the presence of weak acid. With the use of the optimized ES method, fibrous mats with different PCL/Gt ratios were prepared. The sample morphology (SEM), hydrolytic resistance (FT-IR), cell adhesion and viability (MTT assay), cell penetration (fluorescent microscopy), and mechanical characteristics of the samples were studied. PCL2-based films with a Gt content of 20 wt% have demonstrated the best set of properties.
Effect of Organic Polymers on Mechanical Property and Toughening Mechanism of Slag Geopolymer Matrix
Authors: Xing Xiaotong , Wei Jiangxiong , Xu Weiting , Wang Beihan , Luo Shunjie , Yu Qijun
Published: October 2022

In this work, two series of chemically reactive polymers, silane coupling agents (SCAs) and water-soluble polymers, were specifically designed as an additive to improve the ductility of slag geopolymer paste by vibration pressure technique. The influences of organic polymers on the fluidity, rheological behavior, mechanical property, porosity, and toughening mechanism of slag geopolymer were investigated. The polycondensation and bonding characteristics of organic–inorganic products were calculated by 1H liquid nuclear magnetic resonance (NMR) technology and Fourier transform infrared (FT-IR). The polymerization degree of composite geopolymer was evaluated by 29Si NMR and X-ray photoelectron spectroscopy (XPS). The microscopic morphology of the geopolymer matrix was analyzed using scanning electron microscopy (SEM). The results showed that the dosage of the KH570 and PAA-Na with 5 wt% behaved best in improving the flexural strength and the compressive strength of geopolymer in their corresponding organic series, respectively. The addition of polymers decreased the fluidity and the fluidity loss ratio of geopolymer slurry but reduced the harmful pores of hardened geopolymer. The organic polymers acting as bridge-fixed water molecules weakened the repulsion force, and formed a three-dimensional network through molecular interweaving in a geopolymer matrix. Methacryloxy in silane coupling agents and carboxyl group in water-soluble polymers may contribute to the improvement of hydration product structure through strong bonding with C-A-S-H. Microscopic measurements indicated that the addition of KH570 and PAA-Na in geopolymer could form 73.55% and 72.48% Si-O-Si with C-A-S-H gel, higher than the reference, and increase the polycondensation degree of C-A-S-H phase, reflected by the increased generation of Q2 and Q2(1Al) and the longer chain length, leading to a higher densified geopolymer matrix with high ductility.
Effect of Accelerated Aging on Bamboo Fiber Lunch Box and Correlation with Soil Burial Degradation
Authors: Jiang Huan , Wang Ge , Chen Fuming , Deng Jianchao , Chen Xiaoyi
Published: October 2022

This study aimed to investigate the mechanical property decay that might occur during actual use and soil burial degradation of bamboo fiber lunch boxes. For this, the effects of three accelerated aging methods, namely damp–heat treatment, freeze–thaw cycle, and artificial weathering cycle, on the tensile strength, dynamic viscoelasticity, and chemical composition of bamboo fiber lunch boxes were compared, and a correlation of their mechanical property decay with soil burial degradation was established to obtain an acceleration factor (SAF) with aging time as a reference. The results showed that the mechanical properties of the bamboo fiber lunch box decreased to different degrees under the three accelerated methods, and the tensile strength decreased to less than 50% after 36 h of damp–heat treatment, 5 freeze–thaw cycles, and 11 artificial weathering cycles. However, after 10 days, the mechanical property of lunch box in soil degradation decreased by more than 50%. Infrared spectroscopy demonstrated rapid hemicellulose degradation during damp–heat treatment and freeze–thaw cycle, as well as a minor quantity of lignin, and a significant amount of lignin under artificial weathering cycle. With the freeze–thaw cycle and the artificial weathering cycle, the relative crystallinity dropped quickly, by 32.3% and 21.5%, respectively, but under damp–heat treatment, the crystallinity dropped barely, by 43.5%. The damage caused by the freeze–thaw cycle to the mechanical properties of bamboo fiber lunch boxes was greater than that by the damp–heat treatment and artificial weathering cycle. The fluctuation of SAF under freeze–thaw cycle was also more drastic. Compared to the artificial weathering cycle, the damp–heat treatment was more stable and reliable in predicting the decay law of soil burial degradation tensile strength of bamboo fiber lunch boxes.
Application Prospect and Preliminary Exploration of GelMA in Corneal Stroma Regeneration
Authors: Su Guanyu , Li Guigang , Wang Wei , Xu Lingjuan
Published: October 2022

Corneal regeneration has become a prominent study area in recent decades. Because the corneal stroma contributes about 90% of the corneal thickness in the corneal structure, corneal stromal regeneration is critical for the treatment of cornea disease. Numerous materials, including deacetylated chitosan, hydrophilic gel, collagen, gelatin methacrylate (GelMA), serine protein, glycerol sebacate, and decellularized extracellular matrix, have been explored for keratocytes regeneration. GelMA is one of the most prominent materials, which is becoming more and more popular because of its outstanding three-dimensional scaffold structure, strong mechanics, good optical transmittance, and biocompatibility. This review discussed recent research on corneal stroma regeneration materials and related GelMA.
4D Multiscale Origami Soft Robots: A Review
Authors: Son Hyegyo , Park Yunha , Na Youngjin , Yoon ChangKyu
Published: October 2022

Time-dependent shape-transferable soft robots are important for various intelligent applications in flexible electronics and bionics. Four-dimensional (4D) shape changes can offer versatile functional advantages during operations to soft robots that respond to external environmental stimuli, including heat, pH, light, electric, or pneumatic triggers. This review investigates the current advances in multiscale soft robots that can display 4D shape transformations. This review first focuses on material selection to demonstrate 4D origami-driven shape transformations. Second, this review investigates versatile fabrication strategies to form the 4D mechanical structures of soft robots. Third, this review surveys the folding, rolling, bending, and wrinkling mechanisms of soft robots during operation. Fourth, this review highlights the diverse applications of 4D origami-driven soft robots in actuators, sensors, and bionics. Finally, perspectives on future directions and challenges in the development of intelligent soft robots in real operational environments are discussed.
Controlled and Accelerated Hydrolysis of Polylactide (PLA) through Pentaerythritol Phosphites with Acid Scavengers
Authors: Polidar Matthias , Metzsch-Zilligen Elke , Pfaendner Rudolf
Published: October 2022

This study provides insight into the accelerated hydrolysis of polyester PLA through the addition of phosphites based on pentaerythritol. To control hydrolysis and ensure processing stability, different types of phosphites and combinations of phosphites with acid scavengers were studied. Therefore, commercially available PLA was compounded with selected additives on a twin-screw extruder, and hydrolysis experiments were performed at 23 °C, 35 °C and 58 °C in deionized water. Hydrolysis of PLA was evaluated by the melt volume rate (MVR) and size-exclusion chromatography (SEC). For example, after 4 days of water storage at 58 °C, the number average molecular weight of the PLA comparison sample was reduced by 31.3%, whereas PLA compounded with 0.8% phosphite P1 had a 57.7% lower molecular weight. The results are in good agreement with the expected and tested stability against hydrolysis of the investigated phosphite structures. 31P-NMR spectroscopy was utilized to elucidate the hydrolysis of phosphites in the presence of lactic acid. With the addition of phosphites based on pentaerythritol, the hydrolysis rate can be enhanced, and faster biodegradation behavior of biodegradable polyesters is expected. Accelerated biodegradation is beneficial for reducing the residence time of polymers in composting facilities or during home composting and as litter or microplastic residues.
Christian Shame and Religious Trauma
Authors: Downie Alison
Published: October 2022

The analysis of religious trauma is enriched by considering how it may be produced by formation in chronic shame. The testimony of those who have experienced religious trauma and severe religious shame is essential to interdisciplinary understanding of and response to this harm. The experiences of those harmed indicates that some traditional Christian doctrinal interpretations are shaming. Thus, the potential for Christian communities to create climates of chronic shame and cause religious trauma is present wherever such theological interpretations dominate. In this way, the religious teachings themselves, especially when communicated in chronically shaming environments, are traumatizing. In this approach, Christian religious trauma is not an added element to traumas of domestic, physical, or sexual abuse by a religious person or leader. Instead, the source of the trauma is formative experience of participating in Christianity. Religious trauma merits interdisciplinary study in Religious Studies and trauma studies, as well as Christian theology. Theological response to Christian religious trauma contributes to this interdisciplinary need.
Secularism as Equality: French Islamic Discourses on Laïcité
Authors: Belhaj Abdessamad
Published: October 2022

Islamic resistance to secularism is one of the most frequently stated problems in France. This paper addresses this issue as seen by French Muslim discourses. It is argued, here, that French Muslim discourses on laïcité are determined by the claim of equal treatment of Muslims and non-Muslims in France. Thus, this paper highlights the importance of the inequality framework and the tendency to give preference to rights over responsibilities in French Muslim discourses on secularism. Seven Islamic works published between 1994 and 2019 by mainstream-reformist Muslim intellectuals and activists will be analysed, showcasing that the general attitude of Islamic leadership in France is to demand the right to difference and equality, a laïcité that respects the autonomy and freedom to practice religion, including in the public space.
Spectacles of Disgrace: Nietzsche, Coetzee, and Life after the Death of God
Authors: Conway Daniel
Published: October 2022

My aim in this essay is to explore the complementarities that obtain between Nietzsche’s account (or teaching) of the “death of God” and J. M. Coetzee’s characterization of David Lurie in his 1999 novel Disgrace. I am particularly concerned to investigate the responses of Nietzsche’s Madman and Coetzee’s protagonist to their respective insights into (or experiences of) the “death of God.” Both respondents, I offer, may be seen and understood to create public spectacles in which they acquire (what they take to be) permanent, meaning-conferring identities that are meant, if not destined, to withstand the dislocations and calamities to come. In both cases, moreover, the point of the spectacle is to secure the conditions under which its architect may escape any responsibility for navigating the uncertainties that are bound to arise in the aftermath of the “death of God.” Whereas Nietzsche is primarily concerned to anticipate (and diagnose) the distress that leads to the creation of responsibility-deferring spectacles, Coetzee provides an instructive treatment of life after the death of God, as David Lurie is compelled to confront the emerging post-theistic order he had hoped to avoid.
Flavors of Ecstasy: States of Absorption in Islamic and Jewish Contemplative Traditions
Authors: Fisher Nathan E.
Published: October 2022

While the trait of absorption has received a considerable amount of scientific study, states of absorption have been comparatively understudied and even less scholarly or scientific attention has been paid to those that are cultivated within the contemplative traditions of Islam and Judaism. This paper explores canonical descriptions of states of contemplative absorption in Islamic and Jewish traditions, specifically highlighting how they are often cultivated using sensory deprivation and sensory withdrawal, can be distressing and entail functional impairment considered normative in some contexts, and how some are set apart as the goal of specific meditative paths. The import of this survey goes beyond just historical significance, since these traditions assume, and recent research suggests it is plausible, that such states may be hyper-plastic and pivotal in both adaptive and maladaptive directions.
Detecting Pest-Infested Forest Damage through Multispectral Satellite Imagery and Improved UNet++
Authors: Zhang Jingzong , Cong Shijie , Zhang Gen , Ma Yongjun , Zhang Yi , Huang Jianping
Published: October 2022

Plant pests are the primary biological threats to agricultural and forestry production as well as forest ecosystem. Monitoring forest-pest damage via satellite images is crucial for the development of prevention and control strategies. Previous studies utilizing deep learning to monitor pest-infested damage in satellite imagery adopted RGB images, while multispectral imagery and vegetation indices were not used. Multispectral images and vegetation indices contain a wealth of useful information for detecting plant health, which can improve the precision of pest damage detection. The aim of the study is to further improve forest-pest infestation area segmentation by combining multispectral, vegetation indices and RGB information into deep learning. We also propose a new image segmentation method based on UNet++ with attention mechanism module for detecting forest damage induced by bark beetle and aspen leaf miner in Sentinel-2 images. The ResNeSt101 is used as the feature extraction backbone, and the attention mechanism scSE module is introduced in the decoding phase for improving the image segmentation results. We used Sentinel-2 imagery to produce a dataset based on forest health damage data gathered by the Ministry of Forests, Lands, Natural Resource Operations and Rural Development (FLNRORD) in British Columbia (BC), Canada, during aerial overview surveys (AOS) in 2020. The dataset contains the 11 original Sentinel-2 bands and 13 vegetation indices. The experimental results confirmed that the significance of vegetation indices and multispectral data in enhancing the segmentation effect. The results demonstrated that the proposed method exhibits better segmentation quality and more accurate quantitative indices with overall accuracy of 85.11%, in comparison with the state-of-the-art pest area segmentation methods.
A Novel and Non-Invasive Approach to Evaluating Soil Moisture without Soil Disturbances: Contactless Ultrasonic System
Authors: Woo Dong Kook , Do Wonseok , Hong Jinyoung , Choi Hajin
Published: October 2022

Soil moisture has been considered a key variable in governing the terrestrial ecosystem. However, it is challenging to preserve indigenous soil characteristics using conventional soil moisture monitoring methods that require maximum soil contacts. To overcome this issue, we developed a non-destructive method of evaluating soil moisture using a contactless ultrasonic system. This system was designed to measure leaky Rayleigh waves at the air–soil joint-half space. The influences of soil moisture on leaky Rayleigh waves were explored under sand, silt, and clay in a controlled experimental design. Our results showed that there were strong relationships between the energy and amplitude of leaky Rayleigh waves and soil moisture for all three soil cases. These results can be explained by reduced soil strengths during evaporation processes for coarse soil particles as opposed to fine soil particles. To evaluate soil moisture based on the dynamic parameters and wave properties obtained from the observed leaky Rayleigh waves, we used the random forest model. The accuracy of predicted soil moisture was exceptional for test data sets under all soil types (R2 ≥ 0.98, RMSE ≤ 0.0089 m3 m−3). That is, our study demonstrated that the leaky Rayleigh waves had great potential to continuously assess soil moisture variations without soil disturbances.
Development of a Broadband (100–240 MHz) Surface Acoustic Wave Emitter Devoted to the Non-Destructive Characterization of Sub-Micrometric Thin Films
Authors: Duquennoy Marc , Smagin Nikolay , Kadi Tahar , Ouaftouh Mohammadi , Jenot Frédéric
Published: October 2022

In the ultrasonic non-destructive evaluation of thin films, it is essential to have ultrasonic transducers that are able to generate surface acoustic waves (SAW) of suitably high frequencies in a wide frequency range of between ten and several hundred megahertz. If the characterization is carried out with the transducer in contact with the sample, it is also necessary that the transducers provide a high level of mechanical displacement (>100 s pm). This level allows the wave to cross the transducer–sample interface and propagate over the distance of a few millimeters on the sample and be properly detected. In this paper, an emitter transducer formed of interdigitated chirp electrodes deposited on 128° Y-cut LiNbO3 is proposed. It is shown that this solution efficiently enables the generation of SAW (displacement level up to 1 nm) in a frequency range of between 100 and 240 MHz. The electrical characterization and a displacement field analysis of SAW by laser Doppler vibrometry are presented. The transducer’s significant unidirectionality is demonstrated. Finally, the characterization of two titanium thin films deposited on silicon is presented as an example. A meaningful SAW velocity dispersion (~10 m/s) is obtained, which allows for the precise estimation (5% of relative error) of the submicrometer thickness of the layers (20 and 50 nm).
Static Load Characteristics of Hydrostatic Journal Bearings: Measurements and Predictions
Authors: Yi Howon , Jung Hyunsung , Kim Kyuman , Ryu Keun
Published: October 2022

Hydrostatic bearings for liquid rocket engine turbopumps provide distinctive advantages, including high load capacity even with low viscosity cryogenic fluid and extending life span by minimizing friction and wear between rotor and bearing surfaces. Application of hydrostatic bearings into turbopumps demands a reliable test database with well-quantified operating parameters and experimentally validated accurate performance predictive tools. The present paper shows the comprehensive experimental data and validation of predicted static load characteristics of hydrostatic journal bearings lubricated with air, water, and liquid nitrogen. Extensive experiments for static load characteristics of hydrostatic bearings are conducted using a turbopump-rotor-bearing system simulator while increasing supply pressure (Ps) into the test bearings. The test results demonstrate notable effects of the test fluids and their temperatures, as well as Ps, on the bearing performance. In general, the measured bearing flow rate, rotor displacement, and stiffness of the test bearings steadily increase with Ps. The static load bearing characteristics predictions considering flow turbulence and compressibility matched well with the experimental results. The work with independent test data and engineering computational programs will further the implementation of hydrostatic bearings in high-performance turbopump shaft systems with improved efficiency and enhanced reusability of liquid rocket engine sub-systems.
Indirect Monitoring of Frequencies of a Multiple Span Bridge Using Data Collected from an Instrumented Train: A Field Case Study
Authors: Malekjafarian Abdollah , Khan Muhammad Arslan , OBrien Eugene J. , Micu E. Alexandra , Bowe Cathal , Ghiasi Ramin
Published: October 2022

In this paper, a field study is carried out to monitor the natural frequencies of Malahide viaduct bridge which is located in the north of Dublin. The bridge includes a series of simply supported spans, two of which collapsed in 2009 and were replaced. The replaced spans are stiffer than most of the others and these differences resulted in higher natural frequencies. An indirect bridge monitoring approach is employed in which acceleration responses from an instrumented train are used to estimate the natural frequencies of each span of the viaduct showing the locations of the two replaced spans with higher stiffness. For the indirect approach, an Ensemble Empirical Mode Decomposition (EEMD)-based Hilbert Huang Transform (HHT) technique is employed to identify the natural frequency of each span. This is carried out by analysing the Instantaneous Frequencies (IFs) from the calculated intrinsic mode functions. The average of the IFs calculated using 41 runs of the instrumented train (with varying carriage mass and speed for each run) are used to estimate the natural frequencies. To assess the feasibility of the indirect approach, a bespoke set of direct measurements was taken using accelerometers attached successively on each span of the viaduct. The free and forced vibrations from each span are used to estimate the first natural frequencies. The frequencies obtained from drive-by measurements are compared to those from direct measurements which confirms the effectiveness of indirect approaches. In addition, the instantaneous amplitudes of the drive-by signals are used to indicate the location of the stiffer spans. Finally, the accuracy and robustness of the indirect approaches for monitoring of multi span bridges are discussed.