bluuebunny/crossref_metadata_2025 huggingface dataset:
Resonant Pressure Micro Sensors Based on Dual Double Ended Tuning Fork Resonators
Authors: Lu Yulan , Zhang Sen , Yan Pengcheng , Li Yadong , Yu Jie , Chen Deyong , Wang Junbo , Xie Bo , Chen Jian
Published: August 2019

This paper presents resonant pressure micro sensors based on dual double ended tuning fork (DETF) resonators, which are electrostatically excited and piezoresistively detected. In operation, the barometric pressure under measurement bends the pressure sensitive diaphragm functioning as the anchor of DETF resonators and therefore produces eigenfrequency shifts of the resonators. Theoretical analyses and finite element analyses (FEA) were conducted to optimize the key geometries of the DETF resonators with enhanced signal to noise ratios (SNRs). In fabrications, key steps including deep reactive ion etching (DRIE) and anodic bonding were used, where sleeve holes were adopted to form electrical connections, leading to high-efficiency structure layout. Experimental results indicate that the presented micro sensors produced SNRs of 63.70 ± 3.46 dB in the open-loop characterizations and differential sensitivities of 101.3 ± 1.2 Hz/kPa, in the closed-loop characterizations. In addition, pressure cycling tests with a pressure range of 5 to 155 kPa were conducted, revealing that the developed micro sensors demonstrated pressure shifts of 83 ± 2 ppm, pressure hysteresis of 67 ± 3 ppm, and repeatability errors of 39 ± 2 ppm. Thus, the developed resonant pressure micro sensors may potentially function as an enabling tool for barometric pressure measurements.
Selective Capture of Magnetic Wires to Particles in High Gradient Magnetic Separation
Authors: Zeng Jianwu , Tong Xiong , Yi Fan , Chen Luzheng
Published: August 2019

High gradient magnetic separation (HGMS) achieves effective separation to fine weakly magnetic minerals using numerous small magnetic wires in matrix, and its separation performance is inherently dependent on the capture characteristics of the wires. In this work, the selective capture of magnetic wire to particles in high gradient magnetic field was theoretically described and simulated using COMSOL Multiphysics. It was found that the capture trajectories of a small amount of particles under the ideal condition was significantly different from those of a large amount of particles under the actual condition, and non-magnetic particles would be much more easily entrained into magnetic deposits captured onto the wire surface under the actual condition than those under the ideal condition. These theoretical and simulated results were basically validated with the experimental magnetic capture to an ilmenite ore, and the wires in slow feed mode have achieved much higher capture selectivity than those in the fast feed mode. For instance, at the magnetic induction of 0.8 T, the TiO2 grade of magnetic deposits captured by 3 mm diameter wire in the slow feed model reached 36.78%, which is higher than 28.32% in the fast feed model. The selective capture difference between the fast and slow feed models increased with increase in the magnetic induction and with decrease in the pulsating frequency. This investigation contributes to improve HGMS performance in concentrating fine weakly magnetic ores.
In Situ Infrared Spectra for Hydrous Forsterite up to 1243 K: Hydration Effect on Thermodynamic Properties
Authors: Liu Dan , Wang Sha , Smyth Joseph R. , Zhang Junfeng , Wang Xiang , Zhu Xi , Ye Yu
Published: August 2019

Hydrogen substitution has significant effect on the physical properties of olivine, the most abundant mineral in the upper mantle. We collected high-temperature polarized Fourier Transform infrared (FTIR) spectra on hydrous forsterite (Mg-pure olivine) crystals, which were synthesized at 12 GPa, 1473–1673 K. The modes at 3612, 3578, 3566, 3551 cm−1 show comparable negative temperature dependence, and the magnitude of (∂vi/∂T)P decreases dramatically with frequency increasing. Whereas, the peak at 3477 cm−1, which is attributed to protonation along the O1...O2 edge on the Si tetrahedron, has a positive temperature dependence. The absorbance intensities of all these OH bands remained almost the same when quenched to room temperature. On the other hand, we also evaluate the hydration effect on the thermodynamic properties (heat capacities). For the anhydrous forsterite sample, the intrinsic anharmonicity could significantly increase the heat capacity by 5~6% when extrapolated to 2000 K. Hydration further increase such difference to ~9%, in both the cases of M-substitution or Si-substitution. Hence, hydration in olivine has significant impact on the anharmonic contribution to the thermodynamic properties, as well as Equations of State and equilibrium isotope fractionation β-factor at high-P,T conditions in the deep mantle.
Cytotoxic Polyketides from a Deep-Sea Sediment Derived Fungus Diaporthe phaseolorum FS431
Authors: Niu Zheng , Chen Yuchan , Guo Heng , Li Sai-Ni , Li Hao-Hua , Liu Hong-Xin , Liu Zhaoming , Zhang Weimin
Published: August 2019

Two new chromone-derived polyketides phaseolorins, G and H (1 and 2), and one new anthraquinone derivative, phaseolorin I (3), together with three known compounds (4–6), were isolated from the deep-sea sediment-derived fungus Diaporthe phaseolorum FS431. The structures of the new compounds were determined by comprehensive analysis of their spectroscopic data, and the absolute configuration of 1 was established by quantum chemical calculations of electron capture detection (ECD). All the isolated compounds (1–6) were tested for their in vitro cytotoxic activities against four human tumor cell lines, of which compound 4 exhibited significant effect against MCF-7, HepG-2, and A549 tumor cell lines with IC50 values of 2.60, 2.55, and 4.64 µM, respectively.
The Protective Role of Feruloylserotonin in LPS-Induced HaCaT Cells
Authors: He Yuzhu , Kim Byung-gook , Kim Hye-Eun , Sun Qiaochu , Shi Shuhan , Ma Guowu , Kim Young , Kim Ok-su , Kim Ok-joon
Published: August 2019

Epidermal inflammation is caused by various bacterial infectious diseases that impair the skin health. Feruloylserotonin (FS) belongs to the hydroxycinnamic acid amides of serotonin, which mainly exists in safflower seeds and has been proven to have anti-inflammatory and antioxidant activities. Human epidermis mainly comprises keratinocytes whose inflammation causes skin problems. This study investigated the protective effects of FS on the keratinocyte with lipopolysaccharides (LPS)-induced human HaCaT cells and elucidated its underlying mechanisms of action. The mechanism was investigated by analyzing cell viability, PGE2 levels, cell apoptosis, nuclear factor erythroid 2-related factor 2 (Nrf2) translocation, and TLR4/NF-κB pathway. The anti-inflammatory effects of FS were assessed by inhibiting the inflammation via down-regulating the TLR4/NF-κB pathway. Additionally, FS promoted Nrf2 translocation to the nucleus, indicating that FS showed anti-oxidative activities. Furthermore, the antioxidative and anti-inflammatory effects of FS were found to benefit each other, but were independent. Thus, FS can be used as a component to manage epidermal inflammation due to its anti-inflammatory and anti-oxidative properties.
Influence of Olive Extracts on the Expression of Genes Involved in Lipid Metabolism in Medaka Fish
Authors: Torró-Montell Luis , Cortés-Castell Ernesto , Sirvent-Segura Elia , Veciana-Galindo Carmen , Gil-Guillén Vicente , Rizo-Baeza Mercedes
Published: August 2019

Aims. To assess the possible effect of polyphenol-rich olive extracts on lipid metabolism in medaka fish by quantifying the expression of lipogenic and lipolytic genes. Materials and methods. Adult medaka fish were maintained in tanks for five days with five extracts at 0.01% in water, causing obesity through a diet rich in carbohydrates, with a control group maintained in water with a normal diet. The extracts contained polyphenols ranging between 7 and 116 mg/g (oleuropein, hydroxytyrosol) with an antioxidant power of 2–13 mmol of 2,4,6-tri(2-pyridyl)-1,3,5-triazine/100 g. After five days, the fish were sacrificed and the hepatic mRNA and its complementary DNA were extracted by reverse transcription. Complementary DNAs were quantified for three lipolytic and three lipogenic genes by real-time PCR. The relative gene expression was calculated from the amplification curves in reference to the control group. Results. The expression of genes involved in lipolysis, including peroxisome proliferator-activated receptor-±, acyl-CoA oxidase 1, and carnitine palmitoyltransferase 1, were clearly decreased in fish subjected to an obesogenic diet, and this situation could not be reversed in fish maintained with polyphenol-rich extracts. In contrast, lipogenic fatty acid synthase, acetyl-CoA carboxylase 1, and sterol regulatory element-binding protein 1 genes increased considerably with the obesogenic diet and reverted to the normal state with the olive extracts. The effect was not dependent on the total polyphenol content, the specific oleuropein or hydroxytyrosol concentration, or the antioxidant power, suggesting a synergistic effect. Conclusion. Olive polyphenols, acting as anti-lipogenic agents, have a positive effect on lipid metabolism, but their mechanism in each gene is different according to the extract, which supports synergistic mechanisms with the different proportions of polyphenols and accompanying phytochemicals in each extract.
Facile Synthesis of a Series of Non-Symmetric Thioethers Including a Benzothiazole Moiety and Their Use as Efficient In Vitro anti-Trypanosoma cruzi Agents
Authors: Avila-Sorrosa Alcives , Tapia-Alvarado Jazz D. , Nogueda-Torres Benjamín , Chacón-Vargas Karla Fabiola , Díaz-Cedillo Francisco , Vargas-Díaz María Elena , Morales-Morales David
Published: August 2019

A series of 2-benzylsulfanyl benzothiazole (BTA) derivatives were synthesized and fully characterized and in vitro tested against two strains of T. cruzi (NINOA and INC-5), exhibiting good activities at low concentrations.
Romanian Wormwood (Artemisia absinthium L.): Physicochemical and Nutraceutical Screening
Authors: Moacă Elena-Alina , Pavel Ioana Zinuca , Danciu Corina , Crăiniceanu Zorin , Minda Daliana , Ardelean Florina , Antal Diana Simona , Ghiulai Roxana , Cioca Andreea , Derban Mihnea , Simu Sebastian , Chioibaş Raul , Szuhanek Camelia , Dehelean Cristina-Adriana
Published: August 2019

Artemisia species are used worldwide for their antioxidant, antimicrobial and anti-inflammatory properties. This research was designed to investigate the phytochemical profile of two ethanolic extracts obtained from leaves and stems of A. absinthium L. as well as the biological potential (antioxidant activity, cytotoxic, anti-migratory and anti-inflammatory properties). Both plant materials showed quite similar thermogravimetric, FT-IR phenolic profile (high chlorogenic acid) with mild antioxidant capacity [ascorbic acid (0.02–0.1) > leaves (0.1–2.0) > stem (0.1–2.0)]. Alcoholic extracts from these plant materials showed a cytotoxic effect against A375 (melanoma) and MCF7 (breast adenocarcinoma) and affected less the non-malignant HaCaT cells (human keratinocytes) at 72 h post-stimulation and this same trend was observed in the anti-migratory (A375, MCF7 > HaCat) assay. Lastly, extracts ameliorated the pro-inflammatory effect of TPA (12-O-tetradecanoylphorbol-13-acetate) in mice ears, characterized by a diffuse neutrophil distribution with no exocytosis or micro-abscesses.
Characterization of Polysulfides, Polysulfanes, and Other Unique Species in the Reaction between GSNO and H2S
Authors: Kumar Murugaeson R , Farmer Patrick J
Published: August 2019

Glutathione-based products, GSnX, of the reaction of hydrogen sulfide, H2S, S-nitroso glutathione, and GSNO, at varied stoichiometries have been analyzed by liquid chromatography high-resolution mass spectrometry (LC-HRMS) and chemical trapping experiments. A wide variety of glutathione-based species with catenated sulfur chains have been identified including sulfanes (GSSnG), sulfides (GSSnH), and sulfenic acids (GSnOH); sulfinic (GSnO2H) and sulfonic (GSnO3H) acids are also seen in reactions exposed to air. The presence of each species of GSnX within the original reaction mixtures was confirmed using Single Ion Chromatograms (SICs), to demonstrate the separation on the LC column, and given approximate quantification by the peak area of the SIC. Further, confirmation for different GSnX families was obtained by trapping with species-specific reagents. Several unique GSnX families have been characterized, including bridging mixed di- and tetra-valent polysulfanes and internal trithionitrates (GSNHSnH) with polysulfane branches. Competitive trapping experiments suggest that the polysulfane chains are formed via the intermediacy of sulfenic acid species, GSSnOH. In the presence of radical trap vinylcyclopropane (VCP) the relative distributions of polysulfane speciation are relatively unaffected, suggesting that radical coupling is not a dominant pathway. Therefore, we suggest polysulfane catenation occurs via reaction of sulfides with sulfenic acids.
Determination of Volatile Compounds in Nut-Based Milk Alternative Beverages by HS-SPME Prior to GC-MS Analysis
Authors: Manousi Natalia , Zachariadis George A.
Published: August 2019

A reliable Headspace-Solid Phase Microextraction (HS-SPME) method was developed for the determination of polar volatile components of commercial nut-based milk alternative drinks prior to Gas Chromatography–Mass Spectrometry (GC-MS) analysis. Under the optimum extraction conditions, a divinylbenzene (DVB)/Carboxen™ CAR)/polydimethylsiloxane (PDMS) fiber was used and 2 mL of sample was heated at 60 °C for 40 min under stirring, without salt addition. Ten compounds from different chemical classes (heptane, a-pinene, toluene, 2-methylpyrazine, 3-heptanone, heptanal, 2-octanone, 1-heptanol, benzaldehyde and 1-octanol) were chosen as model analytes for quantification. Limits of detection and limits of quantification were found to be 0.33–1.67 ng g−1 and 1–5 ng g−1, accordingly. Good linearity, precision and accuracy were obtained as well as a wide linear range. The proposed method was successfully applied to various beverages including almond milk, walnut milk, peanut milk and almond chocolate milk. More than 70 volatile compounds were detected in the different samples. Most of the detected volatiles were aldehydes, ketones and alcohols. This technique can be used for the determination of volatile compounds in nut-based beverages, to detect compositional changes during storage and technological treatment used for their production.
Photocatalytic Degradation of Selected Pharmaceuticals Using g-C3N4 and TiO2 Nanomaterials
Authors: Smýkalová Aneta , Sokolová Barbora , Foniok Kryštof , Matějka Vlastimil , Praus Petr
Published: August 2019

Exfoliated graphitic carbon nitride (g-C3N4) and two commercially available nanomaterials from titanium dioxide (P25 and CG300) were tested for the photocatalytic degradation of paracetamol (PAR), ibuprofen (IBU), and diclofenac (DIC). Prior to photocatalytic experiments, the nanomaterials were characterized by common methods, such as X-ray diffraction (XRD), UV–VIS diffuse reflectance spectroscopy (DRS), Fourier transformed infrared spectroscopy in attenuated total reflection mode (FTIR–ATR), transmission electron microscopy (TEM), physisorption of nitrogen, and dynamic vapor adsorption (DVS) of water. The sizes and specific surface area (SSA) of the TiO2 nanoparticles were 6 nm and 300 m2·g−1 for CG300 and 21 nm and 50 m2·g−1 for P25. The SSA of g-C3N4 was 140 m2·g−1. All photocatalytic experiments were performed under UV (368 nm), as well as VIS (446 nm) irradiation. TiO2 P25 was the most active photocatalyst under UV irradiation and g-C3N4 was the most active one under VIS irradiation. Photodegradation yields were evaluated by means of high performance liquid chromatography (HPLC) and reaction intermediates were identified using gas chromatography with mass detection (GC–MS). Paracetamol and ibuprofen were totally removed but the intermediates of diclofenac were observed even after 6 h of irradiation. Some intermediates, such as carbazole-1-acetic acid, 2,6-dichloraniline, and hydroxylated derivates of diclofenac were identified. This study showed that g-C3N4 is a promising photocatalyst for the degradation of pharmaceuticals in an aqueous environment, under visible light.
Evaluating Potential Behavioral Mediators for Increasing Similarity in Friends’ Body Size among College Students
Authors: van Woerden Irene , Hruschka Daniel , Schaefer David R. , Fine Kimberly L. , Bruening Meg
Published: August 2019

College students and their friends become more similar in weight status over time. However, it is unclear which mediators explain this relationship. Using validated survey measures of diet, physical activity, alcohol intake, sleep behaviors, mental health, and food security status, we take a comprehensive look at possible factors associated with excess weight gain that may explain friends’ convergence on body mass index (BMI), waist circumference, waist to hip ratio, and waist to height ratio over time. We use linear mixed models applied to a longitudinal dataset of first-year college students to examine whether these variables satisfy two criteria for potential candidate mediators of friends’ influence on anthropometrics—cross-sectional similarity among friends (n = 509) and longitudinal associations with increasing anthropometrics (n = 428). While friends were similar on some survey measures (such as dining hall use, home cooked meal consumption, fruit intake, alcohol intake, hours of sleep, and stress). Only dining hall use and stress emerged as potential explanations for why friends’ BMI and anthropometric change may be similar. Given that only a few variables satisfied the two criteria as potential mediators, future research may need to consider alternative measurement approaches, including real-time assessments, objective measurements, and alternative factors causing the convergence of friends’ and college students’ body size over time.
Gluten-Free Products: From Dietary Necessity to Premium Price Extraction Tool
Authors: Gorgitano Maria Teresa , Sodano Valeria
Published: August 2019

Every year, the Italian National Health Service (NHS) provides about 200,000 celiac people (based on 2017 data) living in Italy with financial support of about 250 million euro to cover the cost of their specific dietary constrains. The existence of gluten-free products of high quality and affordable price is very important for the quality of life of celiac people and the sustainability of public support. Over the last decade, the market for gluten-free products has experienced a dramatic surge, with an increasing shelf space dedicated to these products in supermarkets, and a large variety of products both in terms of kind of agricultural inputs and processing and packaging methods. This study aimed at assessing the offer of gluten-free (GF) pasta in Italian supermarkets, with respect to its ability to meet the needs of celiac people in terms of variety, prices and safety. A hedonic price analysis was performed. Results indicated that GF pasta is sold only in 44% of the 212 stores of the sample, with a price equal to more than twice that of conventional pasta. A premium price was found for the following attributes: small packages, brands specialized in GF products, content in fiber and the presence of quinoa as ingredient.
In Vivo Ergogenic Properties of the Bifidobacterium longum OLP-01 Isolated from a Weightlifting Gold Medalist
Authors: Lee Mon-Chien , Hsu Yi-Ju , Chuang Hsiao-Li , Hsieh Pei-Shan , Ho Hsieh-Hsun , Chen Wei-Ling , Chiu Yen-Shuo , Huang Chi-Chang
Published: August 2019

In recent years, probiotics of human origin have shown superior results and performance compared to probiotics from plant or dairy sources, in both in vitro and animal studies. Towards this end, the current study was conducted to explore the ergogenic properties of Bifidobacterium longum subsp. longum OLP-01 isolated from the intestinal microbiome of the gold medalist from the 2008 Beijing Olympics women’s 48 kg weightlifting competition. Male Institute of Cancer Research (ICR) mice were divided into four groups (n = 10 per group) and orally administered OLP-01 for 4 weeks at 0 (vehicle), 2.05 × 109 (OLP-01-1X), 4.10 × 109 (OLP-01-2X), and 1.03 × 1010 (OLP-01-5X) CFU/kg/day. Physical performance tests including grip strength and endurance time were measured, with OLP-01 supplementation dose-dependently elevating grip strength and endurance. The anti-fatigue activity levels of serum lactate, ammonia, glucose, blood urea nitrogen (BUN), and creatine kinase (CK) were measured after an acute exercise challenge, and OLP-01 was found to significantly decrease lactate, ammonia, and CK levels. OLP-01 treatment was also found to significantly increase the resting levels of both hepatic and muscular glycogen, an indicator of energy storage. Supplementation by OLP-01 showed no subchronic toxic effects while supporting many health-promoting, performance-improving, and fatigue-ameliorating functions.
Development of a Portable Detection Method for Enteric Viruses from Ambient Air and Its Application to a Wastewater Treatment Plant
Authors: Matsubara Koichi , Katayama Hiroyuki
Published: August 2019

The ambient air from wastewater treatment plants has been considered as a potential source of pathogenic microorganisms to cause an occupational risk for the workers of the plants. Existing detection methods for enteric viruses from the air using a liquid as the collection medium therefore require special care to handle on-site. Knowledge accumulation on airborne virus risks from wastewater has been hindered by a lack of portable and handy collection methods. Enteric viruses are prevalent at high concentrations in wastewater; thus, the surrounding air may also be a potential source of viral transmission. We developed a portable collection and detection method for enteric viruses from ambient air and applied it to an actual wastewater treatment plant in Japan. Materials of the collection medium and eluting methods were optimized for real-time polymerase chain reaction-based virus quantification. The method uses a 4 L/min active air sampler, which is capable of testing 0.7–1.6 m3 air after 3–7 h sampling with a detection limit of 102 copies/m3 air in the field. Among 16 samples collected at five to seven locations in three sampling trials (November 2007–January 2008), 56% (9/16) samples were positive for norovirus (NV) GII, with the highest concentration of 3.2 × 103 copies/m3 air observed at the sampling point near a grit chamber. Adenoviruses (4/16), NV GI (6/16), FRNA bacteriophages GIII (3/16), and enteroviruses (3/16) were also detected but at lower concentrations. The virus concentration in the air was associated with that of the wastewater at each process. The results imply that the air from the sewer pipes or treatment process is contaminated by enteric viruses and thus special attention is needed to avoid accidental ingestion of viruses via air.
Antitumor Mechanism of the Essential Oils from Two Succulent Plants in Multidrug Resistance Leukemia Cell
Authors: Poma Paola , Labbozzetta Manuela , McCubrey James A. , Ramarosandratana Aro Vonjy , Sajeva Maurizio , Zito Pietro , Notarbartolo Monica
Published: August 2019

Drug resistance remains a major challenge in the treatment of cancer. The multiplicity of the drug resistance determinants raises the question about the optimal strategies to deal with them. Essential oils showed to inhibit the growth of different tumor cell types. Essential oils contain several chemical classes of compounds whose heterogeneity of active moieties can help prevent the development of drug resistance. In the present paper, we analyzed, by gas chromatography-mass spectrometry the chemical composition of the essential oil of the leaves of Kalanchoe beharensis obtained by hydrodistillation and compared the chemical composition of its essential oil with that of Cyphostemma juttae. Our results demonstrated the anticancer and proapoptotic activities of both species against acute myeloid leukemia on an in vitro model and its multidrug resistant variant involving NF-κB pathway. The essential oils of both species produced a significant decrease in many targets of NF-κB both at mRNA and protein levels. The results corroborate the idea that essential oils may be a good alternative to traditional drugs in the treatment of cancer, especially in drug resistant cancer.
T-Shaped Microfluidic Junction Processing of Porous Alginate-Based Films and Their Characteristics
Authors: Mutlu Betul , Farhan Muhammad , Kucuk Israfil
Published: August 2019

In this work, highly monodisperse porous alginate films from bubble bursting were formed on a glass substrate at ambient temperature, by a T-shaped microfluidic junction device method using polyethylene glycol (PEG) stearate and phospholipid as precursors in some cases. Various polymer solution concentrations and feeding liquid flow rates were applied for the generation of monodisperse microbubbles, followed by the conversion of the bubbles to porous film structures on glass substrates. In order to compare the physical properties of polymeric solutions, the effects of alginate, PEG stearate (surfactant), and phospholipid concentrations on the flowability of the liquid in a T-shaped microfluidic junction device were studied. To tailor microbubble diameter and size distribution, a method for controlling the thinning process of the bubbles’ shell was also explored. In order to control pore size, shape, and surface as well as internal structure morphologies in the scalable forming of alginate polymeric films, the effect of the feeding liquid’s flow rate and concentrations of PEG-stearate and phospholipid was also studied. Digital microscopy images revealed that the as-formed alginate films at the flow rate of 100 µL·min−1 and the N2 gas pressure of 0.8 bar have highly monodisperse microbubbles with a polydispersity index (PDI) of approximately 6.5%. SEM captures also revealed that the as-formed alginate films with high PDI value have similar monodisperse porous surface and internal structure morphologies, with the exception that the as-formed alginate films with the help of phospholipids were mainly formed under our experimental environment. From the Fourier-transform infrared spectroscopy (FTIR), Differential scanning calorimetry (DSC) and X-ray diffraction (XRD) measurements, we concluded that no chemical composition changes, thermal influence, and crystal structural modifications were observed due to the T-shaped microfluidic junction device technique. The method used in this work could expand and enhance the use of alginate porous films in a wide range of bioengineering applications, especially in tissue engineering and drug delivery, such as studying release behaviors to different internal and surface morphologies.
Biodegradable Oligoesters of ε-Caprolactone and 5-Hydroxymethyl-2-Furancarboxylic Acid Synthesized by Immobilized Lipases
Authors: Todea Anamaria , Bîtcan Ioan , Aparaschivei Diana , Păușescu Iulia , Badea Valentin , Péter Francisc , Gherman Vasile Daniel , Rusu Gerlinde , Nagy Lajos , Kéki Sándor
Published: August 2019

Following the latest developments, bio-based polyesters, obtained from renewable raw materials, mainly carbohydrates, can be competitive for the fossil-based equivalents in various industries. In particular, the furan containing monomers are valuable alternatives for the synthesis of various new biomaterials, applicable in food additive, pharmaceutical and medical field. The utilization of lipases as biocatalysts for the synthesis of such polymeric compounds can overcome the disadvantages of high temperatures and metal catalysts, used by the chemical route. In this work, the enzymatic synthesis of new copolymers of ε-caprolactone and 5-hydroxymethyl-2-furancarboxylic acid has been investigated, using commercially available immobilized lipases from Candida antarctica B. The reactions were carried out in solvent-less systems, at temperatures up to 80 °C. The structural analysis by MALDI TOF-MS, NMR, and FT-IR spectroscopy confirmed the formation of cyclic and linear oligoesters, with maximal polymerization degree of 24 and narrow molecular weight distribution (dispersity about 1.1). The operational stability of the biocatalyst was explored during several reuses, while thermal analysis (TG and DSC) indicated a lower thermal stability and higher melting point of the new products, compared to the poly(ε-caprolactone) homopolymer. The presence of the heterocyclic structure in the polymeric chain has promoted both the lipase-catalyzed degradation and the microbial degradation. Although, poly(ε-caprolactone) is a valuable biocompatible polymer with important therapeutic applications, some drawbacks such as low hydrophilicity, low melting point, and relatively slow biodegradability impeded its extensive utilization. In this regard the newly synthesized furan-based oligoesters could represent a “green” improvement route.
Dressed to Marry: Islam, Fashion, and the Making of Muslim Brides in Brazil
Authors: Fonseca Chagas Gisele , Mezabarba Solange R.
Published: August 2019

This article explores the dress practices of Muslim women in Brazil, focusing on the ways through which they choose, prepare, use, and talk about their wedding garments. The aim is to understand how religiously oriented women interpret the Islamic normative codes concerning the coverage of the female body when managing their appearance, particularly when “special celebrations” such as wedding rituals are involved. How do they combine bridal fashion trends with religious orientations? Drawing on ethnographic fieldwork and personal interviews, this analysis stresses that the desired aesthetic of Muslim women’s marital garments unfolds a search for a modest authenticity through which “Brazilian culture”, “female beauty”, and Islam are mobilized. In conclusion, the study points to the dynamic ways through which this specific encounter of religion and fashion produce an aesthetic based on a degree of improvisation and creativity, since the Islamic fashion industry is absent in the Brazilian market.
Australian Media and Islamophobia: Representations of Asylum Seeker Children
Authors: Patil Tejaswini Vishwanath , McLaren Helen Jacqueline
Published: August 2019

Australian media invests considerable attention in asylum seekers and their children, especially those arriving by boat. In this paper, we provide an analysis of Australian newsprint media published during the term of Australia’s Gillard’s government (2010–2013). This period is critical as it coincides with rising numbers of boat arrivals to Australian shores, fear towards Muslims, and growing Islamophobia. At the time, there were government promises to move children from offshore immigration detention into community-based detention, that would involve living among mainstream Australian society. A data set of 46 articles from major Australian newspapers articles was subject to a discourse analysis of representations of children in both the written texts and in silences. Manipulative tactics of ‘risk framing’ and ‘dispersed intentionality’ were identified as discursive acts aimed to confuse compassion and deviancy with respect to asylum seeker children presumed to be from Islamic backgrounds. We argue that this was achieved through binary characterizations in which Muslim parents and people smugglers were constructed as deviant alongside intentional silences, that may have otherwise elicited compassion for asylum seeker children. We propose that this period of media reporting is foundational to understanding the rise of Islamophobic discourses and the implication of Muslim children in Australia.
Bigger Is Not Always Safer: A Critical Analysis of the Subadditivity Assumption for Coherent Risk Measures
Authors: Rau-Bredow Hans
Published: August 2019

This paper provides a critical analysis of the subadditivity axiom, which is the key condition for coherent risk measures. Contrary to the subadditivity assumption, bank mergers can create extra risk. We begin with an analysis how a merger affects depositors, junior or senior bank creditors, and bank owners. Next it is shown that bank mergers can result in higher payouts having to be made by the deposit insurance scheme. Finally, we demonstrate that if banks are interconnected via interbank loans, a bank merger could lead to additional contagion risks. We conclude that the subadditivity assumption should be rejected, since a subadditive risk measure, by definition, cannot account for such increased risks.
Response of Tallgrass Prairie to Management in the U.S. Southern Great Plains: Site Descriptions, Management Practices, and Eddy Covariance Instrumentation for a Long-Term Experiment
Authors: Wagle Pradeep , Gowda Prasanna H. , Northup Brian K. , Starks Patrick J. , Neel James P. S.
Published: August 2019

Understanding the consequences of different management practices on vegetation phenology, forage production and quality, plant and microbial species composition, greenhouse gas emissions, and water budgets in tallgrass prairie systems is vital to identify best management practices. As part of the Southern Plains Long-Term Agroecosystem Research (SP-LTAR) grassland study, a long-term integrated Grassland-LivestOck Burning Experiment (iGLOBE) has been established with a cluster of six eddy covariance (EC) systems on differently managed (i.e., different burning and grazing regimes) native tallgrass prairie systems located in different landscape positions. The purpose of this paper is to describe this long-term experiment, report preliminary results on the responses of differently managed tallgrass prairies under variable climates using satellite remote sensing and EC data, and present future research directions. In general, vegetation greened-up and peaked early, and produced greater forage yields in burned years. However, drought impacts were greater in burned sites due to reductions in soil water availability by burning. The impact of grazing on vegetation phenology was confounded by several factors (e.g., cattle size, stocking rate, precipitation). Moreover, prairie systems located in different landscapes responded differently, especially in dry years due to differences in water availability. The strong correspondence between vegetation phenology and eddy fluxes was evidenced by strong linear relationships of a greenness index (i.e., enhanced vegetation index) with evapotranspiration and gross primary production. Results indicate that impacts of climate and management practices on vegetation phenology may profoundly impact carbon and water budgets of tallgrass prairie. Interacting effects of multiple management practices and inter-annual climatic variability on the responses of tallgrass prairie highlight the necessity of establishing an innovative and comprehensive long-term experiment to address inconsistent responses of tallgrass prairie to different intensities, frequencies, timing, and duration of management practices, and to identify best management practices.
Does Earlier and Increased Spring Plant Growth Lead to Reduced Summer Soil Moisture and Plant Growth on Landscapes Typical of Tundra-Taiga Interface?
Authors: Gonsamo Alemu , Ter-Mikaelian Michael T. , Chen Jing M. , Chen Jiaxin
Published: August 2019

Over the past four decades, satellite observations have shown intensified global greening. At the same time, widespread browning and reversal of or stalled greening have been reported at high latitudes. One of the main reasons for this browning/lack of greening is thought to be warming-induced water stress, i.e., soil moisture depletion caused by earlier spring growth and increased summer evapotranspiration. To investigate these phenomena, we use MODIS collection 6, Global Inventory Modeling and Mapping Studies third-generation (GIMMS) normalized difference vegetation index (NDVI3g), and Global Land Evaporation Amsterdam Model (GLEAM) satellite-based root-zone soil moisture data. The study area was the Far North of Ontario (FNO), 453,788 km2 of heterogeneous landscape typical of the tundra-taiga interface, consisting of unmanaged boreal forests growing on mineral and peat soils, wetlands, and the most southerly area of tundra. The results indicate that the increased plant growth in spring leads to decreased summer growth. Lower summer soil moisture is related to increased spring plant growth in areas with lower soil moisture content. We also found that earlier start of growing season leads to decreased summer and peak season maximum plant growth. In conclusion, increased spring plant growth and earlier start of growing season deplete summer soil moisture and decrease the overall summer plant growth even in temperature-limited high latitude ecosystems. Our findings contribute to evolving understanding of changes in vegetation dynamics in relation to climate in northern high latitude terrestrial ecosystems.
Relative Importance of Binocular Disparity and Motion Parallax for Depth Estimation: A Computer Vision Approach
Authors: Mansour Mostafa , Davidson Pavel , Stepanov Oleg , Piché Robert
Published: August 2019

Binocular disparity and motion parallax are the most important cues for depth estimation in human and computer vision. Here, we present an experimental study to evaluate the accuracy of these two cues in depth estimation to stationary objects in a static environment. Depth estimation via binocular disparity is most commonly implemented using stereo vision, which uses images from two or more cameras to triangulate and estimate distances. We use a commercial stereo camera mounted on a wheeled robot to create a depth map of the environment. The sequence of images obtained by one of these two cameras as well as the camera motion parameters serve as the input to our motion parallax-based depth estimation algorithm. The measured camera motion parameters include translational and angular velocities. Reference distance to the tracked features is provided by a LiDAR. Overall, our results show that at short distances stereo vision is more accurate, but at large distances the combination of parallax and camera motion provide better depth estimation. Therefore, by combining the two cues, one obtains depth estimation with greater range than is possible using either cue individually.
Monitoring Trace Gases over the Antarctic Using Atmospheric Infrared Ultraspectral Sounder Onboard GaoFen-5: Algorithm Description and First Retrieval Results of O3, H2O, and HCl
Authors: Li Xiaoying , Xu Jian , Cheng Tianhai , Shi Hailiang , Zhang Xingying , Ge Shule , Wang Hongmei , Zhu Songyan , Miao Jing , Luo Qi
Published: August 2019

AIUS (Atmospheric Infrared Ultraspectral Sounder) is an infrared occultation spectrometer onboard the Chinese GaoFen-5 satellite, which covers a spectral range of 2.4–13.3 μm (750–4100 cm−1) with a spectral resolution of about 0.02 cm−1. AIUS was designed to measure and to study the chemical processes of ozone (O3) and other trace gases in the upper troposphere and stratosphere over the Antarctic. In this study, the AIUS retrieval methodology is described. A comparison between AIUS measurements and simulated spectra illustrates that AIUS measurements agree well with the simulated spectra. To first evaluate the reliability of the AIUS retrieval algorithm, three retrieval O3 experiments were performed based on ACE-FTS (Atmospheric Chemistry Experiment—Fourier transform spectrometer) observed spectra. A comparison with the ACE-FTS official products shows that the relative difference of these three retrieval experiments was mostly within 10% between 20 and 70 km. These retrieval experiments demonstrate that the retrieval algorithm described in this study provided reliable results and reliably. Furthermore, O3, H2O, and HCl profiles were retrieved from 24 orbits of AIUS measurements and compared with the official Aura /MLS (Microwave Limb Sounder) level-2 v4.2 profiles. The relative difference was mostly within 10% (about 0.02–0.4 ppm) between 18 and 58 km for the O3 retrieval, within 10% (0–0.5 ppm) between 15 and 80 km for the H2O retrieval, and within 10% (about 0.1 ppb) between 30 and 60 km for the HCl retrieval. A good agreement in the retrieved trace gas profiles was reached between AIUS and MLS.
The 2017 Noneruptive Unrest at the Caldera of Cerro Azul Volcano (Galápagos Islands) Revealed by InSAR Observations and Geodetic Modelling
Authors: Guo Qian , Xu Caijun , Wen Yangmao , Liu Yang , Xu Guangyu
Published: August 2019

An unrest event occurred at the Cerro Azul volcano, Galápagos Islands, South America, in March 2017, leading to significant surface deformation on the southern Isabela Island, without eruption or surface rupture. We collected single-look complex synthetic aperture radar (SAR) images sensed by the Sentinel-1A satellite, obtaining eight differential interferograms, of which four showed extensive surface displacement during the co-unrest period. Geodetic data indicated that the unrest continued from 18 March to 25 March, reaching a negative peak displacement of −32.9 cm in the caldera and a positive peak displacement of 41.8 cm on the south-east plain in the line-of-sight direction. A joint magma source deformation model, consisting of a Mogi source below the caldera and a sill source south-east of the caldera, was inverted by the Markov chain Monte Carlo method combined with the Metropolis–Hasting algorithm, acquiring the best fit with the four interferograms. The magma transport mechanism of the event was explained by magma overflowing from the compressive Mogi to the tensile sill source, resulting in the observed “∞”-shaped deformation fields. Additionally, we investigated previous events with eruption rifts and lava lakes in 1979, 1998, and 2008, and proposed a potential hazard of tectonic volcanic activity for further volcanic susceptibility research in the Cerro Azul area.
An Action Plan Towards Fiducial Reference Measurements for Satellite Altimetry
Authors: Mertikas Stelios P. , Donlon Craig , Vuilleumier Pierrik , Cullen Robert , Féménias Pierre , Tripolitsiotis Achilles
Published: August 2019

Satellite altimeters have been producing, as of 1992, an amazing and historic record of sea level changes. As Europe moves into full operational altimetry, it has become imperative that the quality of these monitoring signals with their uncertainties should be controlled, fully and properly descripted, but also traced and connected to undisputable standards and units. Excellent quality is the foundation of these operational services of Europe in altimetry. In line with the above, the strategy of the Fiducial Reference Measurements for Altimetry (FRM4ALT) has been introduced to address and to achieve reliable, long-term, consistent, and undisputable satellite altimetry products for Earth observation and for sea-level change monitoring. FRM4ALT has been introduced and implemented by the European Space Agency in an effort to reach a uniform and absolute standardization for calibrating satellite altimeters. This paper examines the problem and the need behind the FRM4ALT principle to achieve an objective Earth observation. Secondly, it describes the expected FRM products and services which are to come into being out of this new observational strategy. Thirdly, it outlines the technology and the services required for reaching this goal. And finally, it elaborates upon the necessary resources, skills, partnerships, and facilities for establishing FRM standardization for altimetry.
UAS for Wetland Mapping and Hydrological Modeling
Authors: Jeziorska Justyna
Published: August 2019

The miniaturization and affordable production of integrated microelectronics have improved in recent years, making unmanned aerial systems (UAS) accessible to consumers and igniting their interest. Researchers have proposed UAS-based solutions for almost any conceivable problem, but the greatest impact will likely be in applications that exploit the unique advantages of the technology: work in dangerous or difficult-to-access areas, high spatial resolution and/or frequent measurements of environmental phenomena, and deployment of novel sensing technology over small to moderate spatial scales. Examples of such applications may be the identification of wetland areas and use of high-resolution spatial data for hydrological modeling. However, because of the large—and growing—assortment of aircraft and sensors available on the market, an evolving regulatory environment, and limited practical guidance or examples of wetland mapping with UAS, it has been difficult to confidently devise or recommend UAS-based monitoring strategies for these applications. This paper provides a comprehensive review of UAS hardware, software, regulations, scientific applications, and data collection/post-processing procedures that are relevant for wetland monitoring and hydrological modeling.
Source Characteristics of the 28 September 2018 Mw 7.4 Palu, Indonesia, Earthquake Derived from the Advanced Land Observation Satellite 2 Data
Authors: Wang Yongzhe , Feng Wanpeng , Chen Kun , Samsonov Sergey
Published: August 2019

On 28 September 2018, an Mw 7.4 earthquake, followed by a tsunami, struck central Sulawesi, Indonesia. It resulted in serious damage to central Sulawesi, especially in the Palu area. Two descending paths of the Advanced Land Observation Satellite 2 (ALOS-2) synthetic aperture radar (SAR) data were processed with interferometric synthetic aperture radar (InSAR) and pixel tracking techniques to image the coseismic deformation produced by the earthquake. The deformation measurement was used to determine the fault geometry and the coseismic distributed slip model with a constrained least square algorithm based on the homogeneous elastic half-space model. We divided the fault into four segments (named AS, BS, CS and DS, from the north to the south) in the inversion. The BS segment was almost parallel to the DS segment, the CS segment linked the BS and DS segments, and these three fault segments formed a fault step-over system. The Coulomb failure stress (CFS) change on the causative fault was also calculated. Results show that the maximum SAR line-of-sight (LOS) and horizontal deformation were −1.8 m and 3.6 m, respectively. The earthquake ruptured a 210-km-long fault with variable strike angles. The ruptured pattern of the causative fault is mainly a sinistral slip. Almost-pure normal characteristics could be identified along the fault segment across the Palu bay, which could be one of the factors resulting in the tsunami. The main slip area was concentrated at the depths of 0–20 km, and the maximum slip was 3.9 m. The estimated geodetic moment of the earthquake was 1.4 × 1020 Nm, equivalent to an earthquake of Mw 7.4. The CFS results demonstrate that the fault step-over of 5.3 km width did not terminate the rupture propagation of the main shock to the south. Two M>6 earthquakes (the 23 January 2005 and the 18 August 2012) decreased CFS along CS segment and the middle part of DS segment of the 2018 main shock. This implies that the stress release during the previous two earthquakes may have played a vital role in controlling the coseismic slip pattern of the 2018 earthquake.