bluuebunny/crossref_metadata_2025 huggingface dataset:
Morphology–Dependent Electrochemical Sensing Properties of Iron Oxide–Graphene Oxide Nanohybrids for Dopamine and Uric Acid
Authors: Cai Zhaotian , Ye Yabing , Wan Xuan , Liu Jun , Yang Shihui , Xia Yonghui , Li Guangli , He Quanguo
Published: June 2019

Various morphologies of iron oxide nanoparticles (Fe2O3 NPs), including cubic, thorhombic and discal shapes were synthesized by a facile meta-ion mediated hydrothermal route. To further improve the electrochemical sensing properties, discal Fe2O3 NPs with the highest electrocatalytic activity were coupled with graphene oxide (GO) nanosheets. The surface morphology, microstructures and electrochemical properties of the obtained Fe2O3 NPs and Fe2O3/GO nanohybrids were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques. As expected, the electrochemical performances were found to be highly related to morphology. The discal Fe2O3 NPs coupled with GO showed remarkable electrocatalytic activity toward the oxidation of dopamine (DA) and uric acid (UA), due to their excellent synergistic effect. The electrochemical responses of both DA and UA were linear to their concentrations in the ranges of 0.02–10 μM and 10–100 μM, with very low limits of detection (LOD) of 3.2 nM and 2.5 nM for DA and UA, respectively. Moreover, the d-Fe2O3/GO nanohybrids showed good selectivity and reproducibility. The proposed d-Fe2O3/GO/GCE realized the simultaneous detection of DA and UA in human serum and urine samples with satisfactory recoveries.
Guided Mode Resonance Sensors with Optimized Figure of Merit
Authors: Zhou Yi , Wang Bowen , Guo Zhihe , Wu Xiang
Published: June 2019

The guided mode resonance (GMR) effect is widely used in biosensing due to its advantages of narrow linewidth and high efficiency. However, the optimization of a figure of merit (FOM) has not been considered for most GMR sensors. Aimed at obtaining a higher FOM of GMR sensors, we proposed an effective design method for the optimization of FOM. Combining the analytical model and numerical simulations, the FOM of “grating–waveguide” GMR sensors for the wavelength and angular shift detection schemes were investigated systematically. In contrast with previously reported values, higher FOM values were obtained using this method. For the “waveguide–grating” GMR sensors, a linear relationship between the grating period and groove depth was obtained, which leads to excellent FOM values for both the angular and wavelength resonance. Such higher performance GMR sensors will pave the way to lower detection limits in biosensing.
Reduced Graphene Oxide-Wrapped Super Dense Fe3O4 Nanoparticles with Enhanced Electromagnetic Wave Absorption Properties
Authors: Yu Qi , Wang Yiyi , Chen Ping , Nie Weicheng , Chen Hanlin , Zhou Jun
Published: June 2019

The efficient preparation of electromagnetic wave absorbing materials with low density and excellent electromagnetic wave absorption remains a considerable challenge. In this study, reduced graphene oxide (RGO) wrapped Fe3O4 nanoparticles (NPs) were synthesized based on one-step reaction by the reduction of graphene oxide (GO), and the generation of super-fine Fe3O4 NPs was achieved. The phase structure, chemical composition, micromorphology, and magnetism were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscope (XPS), scanning electron microscope (SEM), transmission electron microscope (TEM), and vibrating sample magnetometer (VSM), respectively. The electromagnetic characteristics were evaluated on a vector network analyzer by the coaxial line method. The results showed that super-fine Fe3O4 NPs with an average size of 6.18 nm are densely distributed on the surface of graphenes. The RGO/Fe3O4 nanocomposites exhibited excellent microwave absorption properties with a minimum reflection loss (RL) of up to −55.71 dB at 6.78 GHz at 3.5 mm thickness and the highest effective absorption bandwidth with RL values exceeding −10 dB is 4.76 GHz between 13.24 and 18 GHz at 1.7 mm thickness. This work provides a concise method for the development of RGO supported super dense Fe3O4 nanocomposites for high performance electromagnetic absorption applications.
Facile Synthesis of MnO2 Nanoflowers/N-Doped Reduced Graphene Oxide Composite and Its Application for Simultaneous Determination of Dopamine and Uric Acid
Authors: Wan Xuan , Yang Shihui , Cai Zhaotian , He Quanguo , Ye Yabing , Xia Yonghui , Li Guangli , Liu Jun
Published: June 2019

This study reports facile synthesis of MnO2 nanoflowers/N-doped reduced graphene oxide (MnO2NFs/NrGO) composite and its application on the simultaneous determination of dopamine (DA) and uric acid (UA). The microstructures, morphologies, and electrochemical performances of MnO2NFs/NrGO were studied using X-ray diffraction (XRD), scanning electron microscopy (SEM), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS), respectively. The electrochemical experiments showed that the MnO2NFs/NrGO composites have the largest effective electroactive area and lowest charge transfer resistance. MnO2NFs/NrGO nanocomposites displayed superior catalytic capacity toward the electro-oxidation of DA and UA due to the synergistic effect from MnO2NFs and NrGO. The anodic peak currents of DA and UA increase linearly with their concentrations varying from 0.2 μM to 6.0 μM. However, the anodic peak currents of DA and UA are highly correlated to the Napierian logarithm of their concentrations ranging from 6.0 μM to 100 μM. The detection limits are 0.036 μM and 0.029 μM for DA and UA, respectively. Furthermore, the DA and UA levels of human serum samples were accurately detected by the proposed sensor. Combining with prominent advantages such as facile preparation, good sensitivity, and high selectivity, the proposed MnO2NFs/NrGO nanocomposites have become the most promising candidates for the simultaneous determination of DA and UA from various actual samples.
Analysis of Health Benefits Conferred by Lactobacillus Species from Kefir
Authors: Slattery Conor , Cotter Paul D. , W. O’Toole Paul
Published: June 2019

Lactobacilli are among the most common microorganisms found in kefir; a traditional fermented milk beverage produced locally in many locations around the world. Kefir has been associated with a wide range of purported health benefits; such as antimicrobial activity; cholesterol metabolism; immunomodulation; anti-oxidative effects; anti-diabetic effects; anti-allergenic effects; and tumor suppression. This review critically examines and assesses these claimed benefits and mechanisms with regard to particular Lactobacillus species and/or strains that have been derived from kefir; as well as detailing further potential avenues for experimentation.
Increment in Dietary Potassium Predicts Weight Loss in the Treatment of the Metabolic Syndrome
Authors: Tal Brurya , Sack Jessica , Yaron Marianna , Shefer Gabi , Buch Assaf , Ben Haim Limor , Marcus Yonit , Shenkerman Galina , Sofer Yael , Shefer Lili , Margaliot Miri , Stern Naftali
Published: June 2019

Background: In the treatment of obesity/metabolic syndrome, dietary measures traditionally focus on reducing carbohydrate/fat-related caloric intake. The possibility that changes in potassium consumption may be related to the achieved weight loss has not been previously explored. Methods: Sixty-eight participants, with a mean age of 51.6 ± 11.0 years (F/M—30/38), who fulfilled the ATPIII criteria for the metabolic syndrome (MS) were enrolled into a 1-year intensive multidisciplinary program. Nutritional recommendation consisted of a moderate low calorie/high protein Mediterranean diet. Baseline assessment included clinical and biochemical profiling, and body composition. Nutritional components were registered over 7 days before and at the end of 1 year of treatment. Results: Mean baseline body mass index (BMI) was 35 ± 4 kg/m², which declined by 9.4 ± 0.1% after one year of combined intervention. Linear stepwise regression analysis revealed that 45% of the predicted variance of the % decline in BMI was related to increased consumption of dietary potassium (β = −0.865) and caproic acid (β = −0.423) and reduction in the consumption of dietary vitamin B6 (β = 0.542), calcium (β = 0.335), total carbohydrates (β = 0.239) and total caloric intake (β = 0.238; p < 0.001). Notably, the strongest correlate of the decline in BMI was the increase in dietary potassium intake (β = −0.865). Subjects whose achieved decrease in BMI was above the average (n = 30) increased potassium intake by 25% as compared to an increase in dietary potassium intake of only 3% by those whose decline in BMI was below the average (n = 36; p < 0.05). The change in dietary potassium was related to the percent increase in dietary protein (r = 0.433; p < 0.001). Conclusion: An increase in dietary potassium consumption is a previously unrecognized predictor of the achieved reduction in BMI in a weight-loss-oriented multidisciplinary intervention in obesity/MS. Prospective trials are underway to confirm this post-hoc finding.
Application of Size and Maturation Functions to Population Pharmacokinetic Modeling of Pediatric Patients
Authors: Back Hyun-moon , Lee Jong Bong , Han Nayoung , Goo Sungwoo , Jung Eben , Kim Junyeong , Song Byungjeong , An Sook Hee , Kim Jung Tae , Rhie Sandy Jeong , Ree Yoon Sun , Chae Jung-woo , Kim JaeWoo , Yun Hwi-yeol
Published: June 2019

Traditionally, dosage for pediatric patients has been optimized using simple weight-scaled methods, but these methods do not always meet the requirements of children. To overcome this discrepancy, population pharmacokinetic (PK) modeling of size and maturation functions has been proposed. The main objective of the present study was to evaluate a new modeling method for pediatric patients using clinical data from three different clinical studies. To develop the PK models, a nonlinear mixed effect modeling method was employed, and to explore PK differences in pediatric patients, size with allometric and maturation with Michaelis–Menten type functions were evaluated. Goodness of fit plots, visual predictive check and bootstrap were used for model evaluation. Single application of size scaling to PK parameters was statistically significant for the over one year old group. On the other hand, simultaneous use of size and maturation functions was statistically significant for infants younger than one year old. In conclusion, population PK modeling for pediatric patients was successfully performed using clinical data. Size and maturation functions were applied according to established criteria, and single use of size function was applicable for over one year ages, while size and maturation functions were more effective for PK analysis of neonates and infants.
Polydimethylsiloxane/Nanodiamond Composite Sponge for Enhanced Mechanical or Wettability Performance
Authors: Zhao Xuxin , Wang Tao , Li Yaoyao , Huang Lei , Handschuh-Wang Stephan
Published: June 2019

Polydimethylsiloxane (PDMS) is widely utilized in material science, chemical engineering, and environmental science due to its excellent properties. By utilizing fillers, so-called composite materials can be obtained with enhanced mechanical, wettability, or thermal conductivity performance. Here, we present a simple, cost-effective approach to vary either the mechanical properties (Young’s modulus) or surface wettability of bulk PDMS and PDMS sponges simply by adding nanodiamond filler with different surface terminations, either oxidized (oND) or hydrogenated (reduced, rND) nanodiamond. Minuscule amounts of oxidized nanodiamond particles as filler showed to benefit the compressive Young’s modulus of composite sponges with up to a 52% increase in its value, while the wettability of composite sponges was unaffected. In contrast, adding reduced nanodiamond particles to PDMS yielded inclined water contact angles on the PDMS/nanodiamond composite sponges. Finally, we show that the PDMS/rND composites are readily utilized as an absorbent for oil/water separation problems. This signifies that the surface termination of the ND particle has a crucial effect on the performance of the composite.
Improving the Thermal Stability of Hydrophobic Associative Polymer Aqueous Solution Using a “Triple-Protection” Strategy
Authors: Yang Bo , Mao Jincheng , Zhao Jinzhou , Shao Yang , Zhang Yang , Zhang Zhaoyang , Lu Qingye
Published: June 2019

Because of their high viscoelasticity, Hydrophobic Associative Water-Soluble Polymers (HAWSPs) have been widely used in many industrial fields, especially in oilfield flooding and fracturing. However, one major problem which limits the wide applications of HAWSPs is their weak resistance to high temperatures. Once the temperature increases over 100 °C, the viscosity of the fracturing fluid decreases rapidly, because high temperatures reduce fluid viscosity by oxidizing the polyacrylamide chains and weakening the association of hydrophobic groups. To improve the high temperature resistance of one HAWSP, a triple-protection strategy was developed. First, rigid N-vinyl-2-pyrrolidone moiety was introduced into the polymer chains. Second, an environmentally-friendly deoxidizer, carbohydrazide, was selected to prevent polymer oxidization by scavenging dissolved oxygen. Results showed that both the rigid groups and the deoxidizer improved the temperature resistance of the polymer and helped it maintain high viscosity under high temperature and shear rate. Using these two protection strategies, the resistant temperature of the polymer could reach 160 °C. However, the polymer network still got severely damaged at further elevated temperatures. Therefore, as the third protection strategy, the pre-added high temperature responsive crosslinking agent was applied to form new networks at elevated temperatures. The results have shown that the optimized polymer solution as a kind of fracturing fluid showed good temperature resistance up to 200 °C.
Synthesis, Characterization, and Antioxidant Evaluation of Novel Pyridylurea-Functionalized Chitosan Derivatives
Authors: Zhang Jingjing , Tan Wenqiang , Wei Lijie , Dong Fang , Li Qing , Guo Zhanyong
Published: June 2019

In order to improve the bioactivity of chitosan, we synthesized a novel series of chitosan derivatives: firstly, chitosan was reacted with methylclhlorofonmate obtaining N-methoxyformylated chitosan (1), which was then converted into N-pyridylurea chitosan derivatives (2a-2c) by amine-ester exchange reaction. In addition, N-pyridylurea chitosan derivatives were conducted by reacting with iodomethane to obtain quaternized N-pyridylurea chitosan derivatives (3a-3c). The structural characteristics of as-prepared chitosan derivatives were confirmed by fourier transform infrared (FT-IR), 1H nuclear magnetic resonance (1H NMR), elemental analysis, and scanning electron microscope (SEM). Meanwhile, the antioxidant activity of the chitosan derivatives was assessed in vitro. As shown in this paper, the antioxidant activity decreased in the order: c > b > a. Moreover, after the quaternization with iodomethane, quaternized N-pyridylurea chitosan derivatives immediately exhibited enhanced antioxidant capacity compared with N-pyridylurea chitosan derivatives. For example, in 1,1-Diphenyl-2-picrylhydrazyl (DPPH) radical scavenging assay, the scavenging activities of 3a-3c were 91.75%, 93.63%, and 97.63% while 2a-2c were 42.32%, 42.97%, and 43.07% at 0.4 mg/mL. L929 cells were also adopted for cytotoxicity test of chitosan and synthesized derivatives by CCK-8 assay and all samples showed decreased cytotoxicity. These results suggested that the novel pyridylurea-functionalized chitosan derivatives could be an ideal biomaterial.
Biodegradable Poly(acrylic acid-co-acrylamide)/Poly(vinyl alcohol) Double Network Hydrogels with Tunable Mechanics and High Self-healing Performance
Authors: Jing Zhanxin , Xu Aixing , Liang Yan-Qiu , Zhang Zhaoxia , Yu Chuanming , Hong Pengzhi , Li Yong
Published: June 2019

We proposed a novel strategy in the fabrication of biodegradable poly(acrylic acid-co-acrylamide)/poly(vinyl alcohol) (P(AAc-co-Am)/PVA) double network (DN) hydrogels with good mechanical and self-healing properties. In the DN hydrogel system, P(AAc-co-Am) polymers form a network through the ionic coordinates between –COO– and Fe3+ and hydrogen bonding between –COOH and –CONH2, while another network is fabricated by the complexation between PVA and borax. The influences of the composition on the rheological behaviors and mechanical properties of the synthesized DN hydrogels were investigated. The rheological measurements revealed that the viscoelasticity and stiffness of the P(AAc-co-Am)/PVA DN hydrogels increase as the acrylamide and Fe3+ concentrations increase. At 0.05 mmol of Fe3+ and 50% of acrylamide, tensile strength and elongation at break of P(AAc-co-Am)/PVA DN hydrogels could reach 329.5 KPa and 12.9 mm/mm, respectively. These properties arise from the dynamic reversible bonds existed in the P(AAc-co-Am)/PVA DN hydrogels. These reversible bonds also give good self-healing properties, and the maximum self-healing efficiency of P(AAc-co-Am)/PVA DN hydrogels is up to 96.4%. The degradation test of synthesized DN hydrogels was also conducted under simulated physiological conditions and the weight loss could reach 74% in the simulated intestinal fluid. According to the results presented here, the synthesized P(AAc-co-Am)/PVA DN hydrogels have a potential application prospect in various biomedical fields.
Improvement on Selective Laser Sintering and Post-Processing of Polystyrene
Authors: Zeng Zhi , Deng Xiaohu , Cui Jiangmei , Jiang Hai , Yan Shuo , Peng Bei
Published: June 2019

Amorphous polymers are heavily utilized materials in selective laser sintering (SLS) due to their good dimensional accuracy. However, sintered parts of amorphous polymers cannot be used as functional parts owing to their poor forming performance, including their low relative densities and tensile strength. Therefore, post-processing methods are employed to enhance the mechanical properties of amorphous polymers SLS parts without damaging their relatively high dimensional accuracy. In this study, the forming process of selective laser sintering (SLS) and post-processing on polystyrene (PS) was investigated. The orthogonal experiment was designed to obtain the optimal combination of process parameters. The effect of a single process parameter and the laser volumetric energy density (LVED) on dimension accuracy and warpage of the sintered parts were also discussed. In addition, a three-dimensional (3D) thermal model was developed to analyze the temperature fields of single-layer SLS parts and PS powder sintering mechanism. Then, infiltrating with epoxy resin was employed to enhance the mechanical properties of the PS parts. Good resin-infiltrated formulation was obtained based on the mechanical property tests and fractured surface analysis. This research provides guidance for SLS process and post-processing technology in polymers.
Thermo-Reversible Hybrid Gels Formed from the Combination of Isotactic Polystyrene and [Fe(II) (4-Octadecyl-1,2,4-Triazole)3(ClO4)2]n Metallo-Organic Polymer: Thermal and Viscoelastic Properties
Authors: Echeverría Coro , Rubio Miguel , López Daniel
Published: June 2019

Nano-sized one-dimensional metallo-organic polymers, characterized by the phenomenon of spin transition, are excellent candidates for advanced technological applications such as optical sensors, storage, and information processing devices. However, the main drawback of this type of polymers is their fragile mechanical properties, which hinders its processing and handling, and makes their practical use unfeasible. To overcome this problem, in this work, hybrid thermo-reversible gels are synthesized by combination of a metallo-organic polymer and isotactic polystyrene (iPS) in cis-decaline. A detailed investigation of the thermal and viscoelastic properties of the hybrid gels, in terms of iPS and metallo-organic polymer concentration is performed by means of differential scanning calorimetry and oscillatory rheology, respectively. From the analysis of the thermal properties, three transitions have been determined upon heating: Monotectic transition of the iPS gel, melting of the iPS gel, and melting of the metal-organic polymer gel, which suggest that the gels of the two polymers are formed independently in the hybrid gel, as long as the two polymers are in concentrations above the corresponding critical gelation concentrations. Results regarding viscoelastic properties and morphology confirmed that hybrid gels consisted of an interpenetrated network of polymer gels, formed by iPS and metallo-organic poymer gels growing independently.
Modification of NFA-Conjugated Bridges with Symmetric Structures for High-Efficiency Non-Fullerene PSCs
Authors: Lu Qiuchen , Qiu Ming , Zhao Meiyu , Li Zhuo , Li Yuanzuo
Published: June 2019

As electron acceptors, non-fullerene molecules can overcome the shortcomings of fullerenes and their derivatives (such as high cost, poor co-solubility, and weak light absorption). The photoelectric properties of two potential non-fullerene polymer solar cells (PSCs) PBDB-T:IF-TN (PB:IF) and PBDB-T:IDT-TN (PB:IDT) are studied by density functional theory (DFT) and time-dependent DFT (TD-DFT). Based on the optimized structure of the ground state, the effects of the electron donor (D) and electron acceptor (A) (D/A) interfaces PBDB-T/IF-TN (PB/IF) and PBDB-T/IDT-TN (PB/IDT) are studied by a quantum-chemical method (QM) and Marcus theory. Firstly, for two non-fullerene acceptors (NFAs) IF-TN and IDT-TN, the NFA IDT-TN has better optical absorption ability and better electron transport ability than IF-TN. Secondly, for the D/A interfaces PB/IF and PB/IDT, they both have high optical absorption and electron transfer abilities, and PB/IDT has better optical absorption and lower exciton binding energy. Finally, some important parameters (open-circuit voltage, voltage loss, fill factor, and power conversion efficiency) are calculated and simulated by establishing the theoretical model. From the above analysis, the results show that the non-fullerene PSC PB:IDT has better photoelectric characteristics than PB:IF.
Preparation of PolyHIPE Scaffolds for 3D Cell Culture and the Application in Cytotoxicity Evaluation of Cigarette Smoke
Authors: Sun Peijian , Yang Song , Sun Xuehui , Wang Yipeng , Jia Yunzhen , Shang Pingping , Tian Haiying , Li Guozheng , Li Ruyang , Zhang Xiaobing , Nie Cong
Published: June 2019

Polystyrene-based polyHIPE (polymerized high internal phase emulsion) materials were prepared by the copolymerization of styrene and divinylbenzene in the continuous phase of a HIPE. The resultant polyHIPE materials were found to have an open-cellular morphology and high porosity, and the polyHIPE structure could be well adjusted by varying the water/oil (W/O) ratio and the amount of emulsifier in the HIPE. Cell culture results showed that the resultant polyHIPE materials, which exhibited larger voids and connected windows as well as high porosity, could promote cell proliferation on the 3D scaffold. A 3D cell cytotoxicity evaluation system was constructed with the polystyrene-based polyHIPE materials as scaffolds and the cigarette smoke cytotoxicity was evaluated. Results showed that the smoke cytotoxicity against A549 cells is much lower in the 3D cell platform compared to the traditional 2D system, showing the great potential of the polyHIPE scaffolds for 3D cell culture and the cytotoxic evaluation of cigarette smoke.
Design and Optimization of Flexible Polypyrrole/Bacterial Cellulose Conductive Nanocomposites Using Response Surface Methodology
Authors: Chen Yasong , Wang Fuying , Dong Lipan , Li Zheng , Chen Li , He Xinhai , Gong Jixian , Zhang Jianfei , Li Qiujin
Published: June 2019

Flexible conductive materials have greatly promoted the rapid development of intelligent and wearable textiles. This article reports the design of flexible polypyrrole/bacterial cellulose (PPy/BC) conductive nanocomposites by in situ chemical polymerization. Box-Behnken response surface methodology has been applied to optimize the process. The effects of the pyrrole amount, the molar ratio of HCl to pyrrole and polymerization time on conductivity were investigated. A flexible PPy/BC nanocomposite was obtained with an outstanding electrical conductivity as high as 7.34 S cm−1. Morphological, thermal stability and electrochemical properties of the nanocomposite were also studied. The flexible PPy/BC composite with a core-sheath structure exhibited higher thermal stability than pure cellulose, possessed a high areal capacitance of 1001.26 mF cm−2 at the discharge current density of 1 mA cm−2, but its cycling stability could be further improved. The findings of this research demonstrate that the response surface methodology is one of the most effective approaches for optimizing the conditions of synthesis. It also indicates that the PPy/BC composite is a promising material for applications in intelligent and wearable textiles.
Fabrication of Cotton Linter-Based Adsorbents by Radiation Grafting Polymerization for Humic Acid Removal from Aqueous Solution
Authors: Du Jifu , Dong Zhen , Pi Yuxuan , Yang Xin , Zhao Long
Published: June 2019

Two kinds of cotton linter-based adsorbents were synthesized by grafting dimethylaminoethyl methacrylate (DMAEMA) on cotton linter via radiation grafting polymerization, followed by further quaternization (QCL) or protonation (PCL). The effect of radiation dose and monomer concentration on grafting yield was optimized. The synthesized adsorbents were characterized by Fourier transform infrared spectrometry (FT-IR), Thermogravimetric Analysis (TGA), scanning electron microscope (SEM) and X-ray photoelectron spectroscopy (XPS). The adsorption behaviors of the two adsorbents toward humic acid (HA) were investigated and discussed. pH effect studies showed that QCL was pH-independent, whereas PCL was just suitable for HA adsorption with pH < 6. The adsorption kinetics of the PCL and QCL adsorbent for HA removal were better described by pseudo-second-order kinetic mode and reached equilibrium in 40 min. The adsorption isotherms of the PCL and QCL adsorbent were well fitted with both Langmuir and Freundlich isotherm models, for which adsorption capacity reached 250 mg/g and 333 mg/g at pH 6, respectively. XPS analysis revealed the ratio of two amino group species at different pH, suggesting that the interaction mechanism of the adsorbent and HA was electrostatic adsorption.
Effect of Crosslinking Degree on Sulfonated Poly(aryl ether nitrile)s As Candidates for Proton Exchange Membranes
Authors: Zheng Penglun , Liu Quanyi , Li Zekun , Wang Donghui , Liu Xiaobo
Published: June 2019

In order to investigate the effect of crosslinking degree on the water uptake, swelling ratio, and methanol permeability of sulfonated poly(aryl ether nitrile)s (SPENs), the molar content of sulfonated group in bisphenol monomer is fixed at 60% in this work. The properties of sulfonated poly (aryl ether nitrile) with different crosslinking degrees are studied by changing the content of propenyl group in sulfonated poly (aryl ether nitrile)s. The cross-linking reaction of the propenyl groups in the SPENs is cured at 230 °C. All the results show that this method is an effective way to improve the water uptake, swelling ratio, and methanol permeability to meet the application requirements of the SPENs membranes as proton exchange membranes in fuel cells.
Optimized Synthesis of Biodegradable Elastomer PEGylated Poly(glycerol sebacate) and Their Biomedical Application
Authors: Wang Yanxiang , Wu Haiwa , Wang Zihao , Zhang Jingjing , Zhu Jing , Ma Yifan , Yang Zhaogang , Yuan Yuan
Published: June 2019

Poly(glycerol sebacate) (PGS), a biodegradable elastomer, has been extensively explored in biomedical applications for its favorable mechanical properties and biocompatibility. Efforts have been made to fabricate multifunctional PGS copolymer in recent years, in particular PGS-co-PEG (poly(glycerol sebacate)-co-polyethylene glycol) polymers. However, rare research has been systematically conducted on the effect of reactant ratios on physicochemical properties and biocompatibility of PGS copolymer till now. In this study, a serial of PEGylated PGS (PEGS) with PEG content from 20% to 40% and carboxyl to hydroxyl from 0.67 to 2 were synthesized by thermal curing process. The effects of various PEGS on the mechanical strength and biological activity were further compared and optimized. The results showed that the PEGS elastomers around 20PEGS-1.0C/H and 40PEGS-1.5C/H exhibited the desirable hydrophilicity, degradation behaviors, mechanical properties and cell viability. Subsequently, the potential applications of the 20PEGS-1.0C/H and 40PEGS-1.5C/H in bone repair scaffold and vascular reconstruction were investigated and the results showed that 20PEGS-1.0C/H and 40PEGS-1.5C/H could significantly improve the mechanical strength for the calcium phosphate scaffolds and exhibited preferable molding capability for fabrication of the vascular substitute. These results confirmed that the optimized PEGS elastomers should be promising multifunctional substrates in biomedical applications.
Reinforcement of Bonding Strength and Water Resistance of Soybean Meal-Based Adhesive via Construction of an Interactive Network from Biomass Residues
Authors: Chang Zhiwei , Pang Huiwen , Huang Anmin , Li Jianzhang , Zhang Shifeng
Published: June 2019

Soybean meal-based adhesives are attractive potential environmentally friendly replacements for formaldehyde-based adhesives. However, the low strength and poor water resistance of soybean meal-based adhesives limit their practical application. This study was conducted to develop a natural fiber-reinforced soybean meal-based adhesive with enhanced water resistance and bonding strength. Pulp fiber (PF), poplar wood fiber (WF), and bagasse fiber (BF) were added as fillers into the soybean meal-based adhesive to enhance its performance via hydrogen bonding between the PF and the soybean meal system. The enhanced adhesive exhibited a strong crosslinking structure characterized by multi-interfacial interactions wherein PF served as a bridging ligament and released residual stress into the crosslinking network. The crosslinked structure and improved interfacial interactions were confirmed by Fourier transform infrared (FTIR) spectrophotometry, thermogravimetric analysis (TGA), and scanning electron microscopy (SEM) measurements. Plywood bonded with 4 wt % PF-containing soybean meal-based adhesive exhibited a wet shear strength (1.14 MPa) exceeding that of plywood bonded with the control group by 75.4% due to the stable crosslinking network having efficiently transformed stress and prevented the permeation of water molecules.
Mechanisms of Adsorption of Heavy Metal Cations from Waters by an Amino Bio-Based Resin Derived from Rosin
Authors: Huang Wanting , Diao Kaisheng , Tan Xuecai , Lei Fuhou , Jiang Jianxin , Goodman Bernard A. , Ma Yahong , Liu Shaogang
Published: June 2019

Rosin derived from conifer trees is used as the basis for a novel environmentally-friendly adsorbent prepared from a sustainable resource. After treatment with ethylenediamine, ethylenediamine rosin-based resin (EDAR) is produced, which possesses cation exchange capacity that is comparable to that of the best commercial synthetic resins. This is demonstrated by its application to the removal of Pb, Cd, and Cu from water, in single and multicomponent systems. Maximum uptake was obtained at pH 5 and in the order Pb(II) > Cd(II) > Cu(II). The maximum adsorption of Pb was ~1.8 mmol/g, but the adsorption process resembled the Freundlich isotherm, whereas the adsorption of Cd(II) and Cu(II) followed the Langmuir isotherm. In the multicomponent systems, there was direct competition between Pb and Cd for sorption sites, whereas the results with Cu indicated it had a preference for different types of sites compared to Pb and Cd. The EDAR resin could be efficiently regenerated and used repeatedly with only a small decrease in performance. Characterization of EDAR, and investigations of its adsorption mechanisms using physical, spectroscopic, and theoretical techniques, including fourier transform infrared spectroscopy (FTIR), 13C nuclear magnetic resonance (13C NMR), scanning electron microscope (SEM), Brunauer Emmett Teller (BET) method, elemental analysis, thermogravimetric analysis (TGA), and molecular dynamics calculations, showed that amino groups have a critical role in determining the cation adsorption properties. We conclude that this new adsorbent derived from an abundant natural material has the potential to make valuable contributions to the routine removal of heavy metal ions (HMs) from drinking water and wastewater.
Natural Rubber Composites Filled with Crop Residues as an Alternative to Vulcanizates with Common Fillers
Authors: Masłowski Marcin , Miedzianowska Justyna , Strzelec Krzysztof
Published: June 2019

This present study is focused on exploring the possibility of using agricultural waste in the form of cereal straw as an active filler of biocomposites. The effect of lignocellulosic filler addition on the multifunctional properties of natural rubber composites was investigated. The results were compared with the properties of vulcanizates containing commonly used reinforcements in elastomer technology (carbon black, silica, chalk, talc). Rubber mixtures filled with straw showed the highest torque increase during rheometric measurements, which indirectly indicated a high degree of crosslinking and hardness of composites. It was found that the effect of straw addition on vulcanization time of elastomer blends was comparable with the results obtained for other conventional fillers. Moreover, the results confirmed that novel composites based on natural rubber filled with crop residues were attractive materials owing to their capacity for the formation of “structure” in combination with a good impact on reinforcement. Vulcanizates with the addition of straw showed the best barrier properties and resistance to thermo-oxidative aging from all tested samples. Furthermore, straw-based composites demonstrated that cereal straw waste could be used as an alternative, biodegradable and eco-friendly reinforcement of natural rubber composites.
Facile Fabrication of a Novel PZT@PPy Aerogel/Epoxy Resin Composite with Improved Damping Property
Authors: Zhang Chunmei , Li Yuchao , Zhan Yanhu , Xie Qian
Published: June 2019

A novel lead zirconate titanate@polypyrrole (PZT@PPy) aerogel (PPA) was fabricated via in-situ polymerization and subsequent freeze-drying method. The porous PPA was then saturated with epoxy resin to obtain the PPA/epoxy composite (PPAE) by a simple vacuum filling method. In this way, the filler content and dispersion uniformity are well guaranteed, which is in favor of improving the damping and mechanical properties of composites. The morphology and structure of PPAs were investigated using XRD, SEM, EDS and nitrogen absorption and desorption measurements. The results showed that the PPA possessed a three-dimensional porous structure with uniform lead zirconate titanate (PZT) distribution. The influence of PZT content on the damping property of PPAE composite was investigated by dynamic mechanical analysis (DMA). PPAE-75 (i.e., the mass ratio of PZT to PPy is 75 wt %) exhibited the maximum damping loss factor value, 360% higher than that of the epoxy matrix, suggesting good structural damping performance.
Analysis of Religious Socialization Based on Interviews Conducted with Young Adults
Authors: Pusztai Gabriella , Demeter-Karászi Zsuzsanna
Published: June 2019

The term religious socialization has become a pressing issue in the context of religious socialization research. It also raises the question whether religious transmission can be interpreted through the reproduction or constructivist approach. Previously, the reconstruction models determined the approach of studying religious socialization. According to these models, socialization meant the adoption of the patterns of religious practice in the family. In this sense, socialization is periodical. The constructivist and the social network models of sociology significantly changed our conception of religious socialization. The earlier model was replaced by a model which rests on activity, correlation and open-endedness. In this paper, 18 qualitative interviews were analyzeanalyzed. Because religiosity is a multidimensional phenomenon, we wanted to analyze development in each dimension, which is why we relied on Glock and Stark’s model. Based on our results, seven types emerged and these findings have strengthened the constructivist approach.
Global Assessment of the SMAP Freeze/Thaw Data Record and Regional Applications for Detecting Spring Onset and Frost Events
Authors: Kim Youngwook , Kimball John S. , Xu Xiaolan , Dunbar R. Scott , Colliander Andreas , Derksen Chris
Published: June 2019

More than half of the global land area undergoes seasonal frozen and thawed conditions that constrain eco-hydrological processes. The freeze-thaw (FT) retrieval from satellite microwave remote sensing detects landscape changes between frozen and non-frozen conditions due to the strong dependence of surface microwave emissions on liquid water abundance. We conducted an assessment of the latest version (R16) of the NASA Soil Moisture Active Passive (SMAP) Level 3 FT (L3_FT) global product. The L3_FT product provides a global FT classification with 3-day mean temporal fidelity derived using SMAP L-band (1.4 GHz) microwave brightness temperature (Tb) retrievals. The R16 product uses both normalized polarization ratio (NPR) and single channel vertically-polarized Tb (FT-SCV) algorithms to obtain FT retrievals over land areas where frozen temperatures are a significant ecological constraint. The L3_FT product is generated in a standard global grid with similar grid cell resolution (36-km) as the SMAP radiometer footprint. An enhanced 9-km global grid L3_FT product is also produced from optimally interpolated SMAP Tb retrievals. The resulting L3_FT products span a larger domain and longer period (2015–present) than earlier product releases. The L3_FT 36-km results showed a respective global mean annual FT classification accuracy of approximately 78 and 90 percent for descending (AM) and ascending (PM) orbit observations in relation to independent surface air temperature-based FT estimates from ~5000 global weather stations. The FT accuracy was lower in areas with greater terrain complexity, open water and vegetation cover; where the combined land cover factors explained 29–53% of the variability in the SMAP FT global accuracy. The L3_FT 9-km product showed an apparent enhancement of FT spatial patterns, but with ~4% lower accuracy than the 36-km product; the lower 9-km accuracy was attributed to stronger degradation from land cover heterogeneity, particularly in coastal areas, and artifact noise introduced from the spatial interpolation of SMAP Tb retrievals. Selected regional applications indicated product utility in capturing anomalous frost events over Australia and seasonal thaw and spring onset patterns over Alaska. Overall, the L3_FT global accuracy meets or exceeds the FT product science requirements established by the mission, while enabling studies of dynamic FT and water mobility constraints influencing hydrological and ecosystem processes, and global water-carbon-energy cycle linkages.
Establishment of a Real-Time Local Tropospheric Fusion Model
Authors: Yao Yibin , Xu Xingyu , Xu Chaoqian , Peng Wenjie , Wan Yangyang
Published: June 2019

The tropospheric delay is one major error source affecting the precise positioning provided by the global navigation satellite system (GNSS). This error occurs because the GNSS signals are refracted while travelling through the troposphere layer. Nowadays, various types of model can produce the tropospheric delay. Among them, the globally distributed GNSS permanent stations can resolve the tropospheric delay with the highest accuracy and the best continuity. Meteorological models, such as the Saastamoinen model, provide formulae to calculate temperature, pressure, water vapor pressure and subsequently the tropospheric delay. Some grid-based empirical tropospheric delay models directly provide tropospheric parameters at a global scale and in real time without any auxiliary information. However, the spatial resolution of the GNSS tropospheric delay is not sufficient, and the accuracy of the meteorological and empirical models is relatively poor. With the rapid development of satellite navigation systems around the globe, the demand for real-time high-precision GNSS positioning services has been growing dramatically, requiring real-time and high-accuracy troposphere models as a critical prerequisite. Therefore, this paper proposes a multi-source real-time local tropospheric delay model that uses polynomial fitting of ground-based GNSS observations, meteorological data, and empirical GPT2w models. The results show that the accuracy in the zenith tropospheric delay (ZTD) of the proposed tropospheric delay model has been verified with a RMS (root mean square) of 1.48 cm in active troposphere conditions, and 1.45 cm in stable troposphere conditions, which is significantly better than the conventional tropospheric GPT2w and Saastamoinen models.
Glacier Monitoring Using Frequency Domain Offset Tracking Applied to Sentinel-1 Images: A Product Performance Comparison
Authors: Amitrano Donato , Guida Raffaella , Di Martino Gerardo , Iodice Antonio
Published: June 2019

The Sentinel-1 mission has now reached its maturity, and is acquiring high-quality images with a high revisit time, allowing for effective continuous monitoring of our rapidly changing planet. The purpose of this work is to assess the performance of the different synthetic aperture radar products made available by the European Space Agency through the Sentinels Data Hub against glacier displacement monitoring with offset tracking methodology. In particular, four classes of products have been tested: the medium resolution ground range detected, the high-resolution ground range detected, acquired in both interferometric wide and extra-wide swath, and the single look complex. The first are detected pre-processed images with about 40, 25, and 10-m pixel spacing, respectively. The last category, the most commonly adopted for the application at issue, represents the standard coherent synthetic aperture radar product, delivered in unprocessed focused complex format with pixel spacing ranging from 14 to 20 m in azimuth and from approximately 2 to 6 m in range, depending on the acquisition area and mode. Tests have been performed on data acquired over four glaciers, i.e., the Petermann Glacier, the Nioghalvfjerdsfjorden, the Jackobshavn Isbræ and the Thwaites Glacier. They revealed that the displacements estimated using interferometric wide swath single look complex and high-resolution ground range detected products are fully comparable, even at computational level. As a result, considering the differences in memory consumption and pre-processing requirements presented by these two kinds of product, detected formats should be preferred for facing the application.
The 2018 Mw 7.5 Palu Earthquake: A Supershear Rupture Event Constrained by InSAR and Broadband Regional Seismograms
Authors: Fang Jin , Xu Caijun , Wen Yangmao , Wang Shuai , Xu Guangyu , Zhao Yingwen , Yi Lei
Published: June 2019

The 28 September 2018 Mw 7.5 Palu earthquake occurred at a triple junction zone where the Philippine Sea, Australian, and Sunda plates are convergent. Here, we utilized Advanced Land Observing Satellite-2 (ALOS-2) interferometry synthetic aperture radar (InSAR) data together with broadband regional seismograms to investigate the source geometry and rupture kinematics of this earthquake. Results showed that the 2018 Palu earthquake ruptured a fault plane with a relatively steep dip angle of ~85°. The preferred rupture model demonstrated that the earthquake was a supershear event from early on, with an average rupture speed of 4.1 km/s, which is different from the common supershear events that typically show an initial subshear rupture. The rupture expanded rapidly (~4.1 km/s) from the hypocenter and propagated bilaterally towards the north and south along the strike direction during the first 8 s, and then to the south. Four visible asperities were ruptured during the slip pulse propagation, which resulted in four significant deformation lobes in the coseismic interferogram. The maximum slip of 6.5 m was observed to the south of the city of Palu, and the total seismic moment released within 40 s was 2.64 × 1020 N·m, which was equivalent to Mw 7.55. Our results shed some light on the transtensional tectonism in Sulawesi, given that the 2018 Palu earthquake was dominated by left-lateral strike slip (slip maxima is 6.2 m) and that some significant normal faulting components (slip maxima is ~3 m) were resolved as well.
Past Themes and Tracking Research Trends in Entrepreneurship: A Co-Word, Cites and Usage Count Analysis
Authors: Ramírez Luis Javier Cabeza , Sánchez-Cañizares Sandra M. , Fuentes-García Fernando J.
Published: June 2019

This paper examines the evolution of research in Entrepreneurship published in Web of Science, a reference database. A bibliometric content analysis has been carried out as part of this investigation, allowing for a longitudinal study of the main research topics dealt with over time, ranging from classic topics such as its conception to more recent realities that include Social and Sustainable Entrepreneurship. This paper locates research trends by studying the evolution of citations and by incorporating use metrics. The results point to the existence of seven cognitive fronts that have marked the field’s growth and conceptual evolution. Furthermore, evidence is presented that shows how innovation has historically been the thread that links all the core themes. The topics and trends detected contribute specially to advancing the current discussion on entrepreneurship and coordinating future research efforts.
Corporate Environmental Strategy and Voluntary Environmental Behavior—Mediating Effect of Psychological Green Climate
Authors: Das Anupam Kumar , Biswas Shetu Ranjan , Abdul Kader Jilani Munshi Muhammad , Uddin Md. Aftab
Published: June 2019

Given the growing intent to prevent decay in environmental management, the present study seeks to unearth the impact of corporate environmental strategy on employees’ voluntary environmental behavior by regulating or facilitating their perceived psychological green climate. Research problems and research questions are built on the essence of multiple theories—goal-setting theory, social identity theory, and social learning theory for grounding the research model. A total of 294 replies were collected through a self-administered survey from diverse industrial panoramas. We used structural equation modeling (SEM) analytics via AMOS-version 20.0 for measuring the hypothesized results. The study revealed that the corporate environmental strategy is displaying an insignificant direct influence on voluntary environmental behavior. However, the corporate environmental strategy indirectly influences, via the mediation effect, voluntary environmental behavior of employees through their psychological green climate perception. Directions for future research are recommended based on insights from the implications and limitations of the study.