bluuebunny/crossref_metadata_2025 huggingface dataset:
Triple Negative Breast Cancer: An Analysis of the Subtypes and the Effects of Menopausal Status on Invasive Breast Cancer
Authors: Nishimura Reiki , Osako Tomofumi , Okumura Yasuhiro , Nakano Masahiro , Otsuka Hiroko , Fujisue Mamiko , Arima Nobuyuki
Published: April 2022

Background: Triple negative breast cancer (TNBC) is a subtype of breast cancer which lacks hormone receptor (HR) expression and HER2 gene amplification and is the most aggressive subtype, with a heterogeneous genetic profile. The aim of this retrospective study was to evaluate the clinical significance of menopausal status in breast cancer cases with TNBC. Methods: Primary breast cancer patients who underwent curative surgery were enrolled in this retrospective study. A total of 5153 invasive breast cancer cases with Stage I–III were analyzed. The distribution of cases according to the menopausal status and subtypes was investigated and the clinicopathological characteristics and prognosis were compared between pre- and postmenopausal TNBC patients. Results: TNBC was frequently seen in postmenopausal patients and Luminal B and Luminal/HER2 subtypes were more common in premenopausal patients. There was no difference in DFS in the Luminal A/B and HER2 subtypes, but a significant difference was seen in the TNBC patients. Premenopausal patients with TNBC frequently had an overexpression of the p53 protein, a significantly higher Ki-67 index value, and a higher nuclear grade. A multivariate analysis revealed that menopausal status, nodal status, and tumor size were significant factors for DFS in TNBC cases. Conclusion: Menopausal status significantly correlates with breast cancer subtypes. TNBC was often seen in postmenopausal patients and these patients tend to have more favorable factors and a better DFS than premenopausal patients. These findings suggest that menopausal status is an important factor for evaluating biology and prognosis in TNBC cases.
Accuracy of DICOM–DICOM vs. DICOM–STL Protocols in Computer-Guided Surgery: A Human Clinical Study
Authors: D’Addazio Gianmaria , Xhajanka Edit , Traini Tonino , Santilli Manlio , Rexhepi Imena , Murmura Giovanna , Caputi Sergio , Sinjari Bruna
Published: April 2022

Guided implant surgery can enhance implant placement positioning, increasing predictability and decreasing postoperative complications., To date, the best protocol to be used for template realization is still unknown. Thus, the aim herein was to clinically compare the accuracy of two different protocols. A total of 48 implants were divided into Group A (24 implants), in which a stereolithographic template was realized using the digital imaging and communications in medicine (DICOM) data arrived from cone beam computer tomographies (CBCTs) (patients and prothesis alone), and Group B (24 implant), in which a standard intraoral stent with a standardized extraoral support was used for patients’ intraoral impressions and CBCT. The preimplant virtual planning and postsurgery CBCT images of both groups were superimposed, and differences were registered in terms of average deviations at the platform (a) and implant apex (b), mean depth change (c), and angular deviation (d). The results demonstrated that there were no statistically significant differences between groups (p = 0.76) for the parameters measured. However, statistically significant differences (p < 0.05) were found between maxillary and mandible implant surgery, as the latter showed greater accuracy. Additional studies are necessary to further reduce discrepancies between planning and surgical procedures.
Utility of Lymphadenectomy in Prostate Cancer: Where Do We Stand?
Authors: Małkiewicz Bartosz , Kiełb Paweł , Karwacki Jakub , Czerwińska Róża , Długosz Paulina , Lemiński Artur , Nowak Łukasz , Krajewski Wojciech , Szydełko Tomasz
Published: April 2022

The purpose of this review is to summarize the current knowledge on lymph node dissection (LND) in prostate cancer (PCa) patients undergoing radical prostatectomy (RP). Despite a growing body of evidence, the utility and therapeutic and prognostic value of such an approach, as well as the optimal extent of LND, remain unsolved issues. Although LND is the most accurate staging procedure, the direct therapeutic effect is still not evident from the current literature, which limits the possibility of establishing clear recommendations. This indicates the need for further robust and adequately designed high-quality clinical trials.
Relationship between Rate of Force Development of Tongue Pressure and Physical Performance
Authors: Saito Syota , Nakao Yuta , Hasegawa Yoko , Nagai Koutatsu , Sano Kyoko , Uchiyama Yuki , Kishimoto Hiromitsu , Shinmura Ken , Domen Kazuhisa
Published: April 2022

In the assessment of skeletal muscle strength, rate of force development (RFD) is clinically identified as a functional index that reflects the effects of aging, but there are few reports on RFD of the tongue. The purpose of this study was to examine the relationship between RFD of tongue pressure (RFD-TP) and oral and whole-body physical performance in older adults, and to clarify its characteristics. We enrolled adults aged ≥65 years with pathological occlusal contact in premolar and molar regions of teeth in the Tamba-Sasayama area, Japan, from 2017 to 2018. Maximum tongue pressure (MTP) and the speed to reach the maximum tongue pressure (RFD-TP) were evaluated as measures of tongue function. Oral functions related to objective measures of tongue function, such as repetitive saliva swallowing test, oral diadochokinesis, and physical status or performance, such as mini mental state examination, body mass index, skeletal mass index, knee extension force, one-leg standing time, grip strength, walking speed, timed up-and-go test, and five-time chair stand speed was evaluated. No significant correlation was found between MTP and age, but RFD-TP had a significant negative correlation with age. Neither RFD-TP nor MTP showed a significant correlation with oral function. RFD-TP was associated with physical performance, such as knee extension force and one-leg standing time. RFD-TP is more sensitive to aging than MTP. In addition, RFD-TP is related to physical performance and may be useful for the early detection of frailty.
Contemporary Management of Male Anterior Urethral Strictures by Reconstructive Urology Experts—Results from an International Survey among ESGURS Members
Authors: Campos-Juanatey Felix , Fes-Ascanio Enrique , Adamowicz Jan , Castiglione Fabio , Cocci Andrea , Mantica Guglielmo , Rosenbaum Clemens , Verla Wesley , Vetterlein Malte W. , Waterloos Marjan , Kluth Luis A. ,   on behalf of the Trauma and Reconstructive Urology Working Party of the European Association of Urology Young Academic Urologists (EAU YAU)
Published: April 2022

Assessment of anterior urethral stricture (US) management of European urology experts is relevant to evaluate the quality of care given to the patients and plan future educational interventions. We assessed the practice patterns of the management of adult male anterior US among reconstructive urology experts from European countries. A 23-question online survey was conducted among European Association of Urology Section of Genito-Urinary Reconstructive Surgeons (ESGURS) members. A total of 88 invitations were sent by email at two different times (May and October 2019). Data were prospectively collected from May 2019 to December 2019. The response rate was 55.6%. Most of the responders were between 50 and 59 y.o. and mainly from University Public Teaching/Academic Hospitals. A total of 73.5% treated ≥20 patients/year with US. Retrograde urethrogram (RUG) was the commonest diagnostic tool, followed by uroflowmetry (UF) +/− post-void residual (PVR). Urethroplasty using grafts was the most frequent treatment (91.8%). Of responders, 55.3% performed >20 urethroplasties/year. Anastomotic urethroplasties were performed by 83.7%, skin flap repairs by 61.2%, perineal urethrostomy by 77.6% and non-transecting techniques by 63.3%. UF was the most common follow-up tool. Most of the responders considered urethroplasty as the primary option when indicated. Male anterior US among ESGURS members are treated mainly using urethroplasty graft procedures. RUG is preferred for diagnosis, and UF for follow-up.
New Advanced Imaging Parameters and Biomarkers—A Step Forward in the Diagnosis and Prognosis of TTR Cardiomyopathy
Authors: Rimbas Roxana Cristina , Balinisteanu Anca , Magda Stefania Lucia , Visoiu Simona Ionela , Ciobanu Andrea Olivia , Beganu Elena , Nicula Alina Ioana , Vinereanu Dragos
Published: April 2022

Transthyretin amyloid cardiomyopathy (ATTR-CM) is an infiltrative disorder characterized by extracellular myocardial deposits of amyloid fibrils, with poor outcome, leading to heart failure and death, with significant treatment expenditure. In the era of a novel therapeutic arsenal of disease-modifying agents that target a myriad of pathophysiological mechanisms, timely and accurate diagnosis of ATTR-CM is crucial. Recent advances in therapeutic strategies shown to be most beneficial in the early stages of the disease have determined a paradigm shift in the screening, diagnostic algorithm, and risk classification of patients with ATTR-CM. The aim of this review is to explore the utility of novel specific non-invasive imaging parameters and biomarkers from screening to diagnosis, prognosis, risk stratification, and monitoring of the response to therapy. We will summarize the knowledge of the most recent advances in diagnostic, prognostic, and treatment tailoring parameters for early recognition, prediction of outcome, and better selection of therapeutic candidates in ATTR-CM. Moreover, we will provide input from different potential pathways involved in the pathophysiology of ATTR-CM, on top of the amyloid deposition, such as inflammation, endothelial dysfunction, reduced nitric oxide bioavailability, oxidative stress, and myocardial fibrosis, and their diagnostic, prognostic, and therapeutic implications.
Experimental Analysis of Plastic-Based Composites Made by Composite Plastic Manufacturing
Authors: Bhaskar Raghunath , Butt Javaid , Shirvani Hassan
Published: April 2022

The significance of composites cannot be overstated in the manufacturing sector due to their unique properties and high strength-to-weight ratio. The use of thermoplastics for composites manufacturing is also gaining attention due to their availability, ease of operation, and affordability. However, the current methods for plastic-based composites are limited due to the requirements of long curing times and pre- and post-treatment, thereby resulting in longer lead times for the desired product. These methods also limit the freedom to operate with different forms of materials. Therefore, a new manufacturing process for plastic-based composites is required to overcome such limitations. This research presents a new manufacturing process to produce high-quality plastic-based composites with bespoke properties for engineering applications. The process is referred to as Composite Plastic Manufacturing (CPM) and is based on the principle of fused filament fabrication (FFF) equipped with a heat chamber. The process integrates two material extrusion additive manufacturing technologies, i.e., filament and syringe extrusion. The paper presents the principle of the process, both in theory and in practice, along with the methodology and materials used to manufacture plastic composites. Various composites have been manufactured using the CPM process with thermally activated materials and tested according to British and International standards. Polylactic Acid (PLA) has been interlaced with different thermally activated materials such as graphene-carbon hybrid paste, heat cure epoxy paste, and graphene epoxy paste. The process is validated through a comparative experimental analysis involving tests such as ultrasonic, tensile, microstructural, and hardness to demonstrate its capabilities. The results have been compared with commercially available materials (PLA and Graphene-enhanced PLA) as well as literature to establish the superiority of the CPM process. The CPM composites showed an increase of up to 10.4% in their tensile strength (54 MPa) and 8% in their hardness values (81 HD) when compared to commercially available PLA material. The composites manufactured by CPM have also shown strong bonding between the layers of PLA and thermally activated materials; thus, highlighting the effectiveness of the process. Furthermore, the composites showed a significant increase of up to 29.8% in their tensile strength and 24.6% in their hardness values when compared to commercially available Graphene-enhanced PLA material. The results show that the CPM process is capable of manufacturing superior quality plastic composites and can be used to produce products with bespoke properties.
Extraction and Calculation of Roadway Area from Satellite Images Using Improved Deep Learning Model and Post-Processing
Authors: Yerram Varun , Takeshita Hiroyuki , Iwahori Yuji , Hayashi Yoshitsugu , Bhuyan M. K. , Fukui Shinji , Kijsirikul Boonserm , Wang Aili
Published: April 2022

Roadway area calculation is a novel problem in remote sensing and urban planning. This paper models this problem as a two-step problem, roadway extraction, and area calculation. Roadway extraction from satellite images is a problem that has been tackled many times before. This paper proposes a method using pixel resolution to calculate the area of the roads covered in satellite images. The proposed approach uses novel U-net and Resnet architectures called U-net++ and ResNeXt. The state-of-the-art model is combined with the proposed efficient post-processing approach to improve the overlap with ground truth labels. The performance of the proposed road extraction algorithm is evaluated on the Massachusetts dataset and it is shown that the proposed approach outperforms the existing solutions which use models from the U-net family.
Mucormycosis and COVID-19-Associated Mucormycosis: Insights of a Deadly but Neglected Mycosis
Authors: García-Carnero Laura C. , Mora-Montes Héctor M.
Published: April 2022

The ongoing COVID-19 pandemic has quickly become a health threat worldwide, with high mortality and morbidity among patients with comorbidities. This viral infection promotes the perfect setting in patients for the development of opportunistic infections, such as those caused by fungi. Mucormycosis, a rare but deadly fungal infection, has recently increased its incidence, especially in endemic areas, since the onset of the pandemic. COVID-19-associated mucormycosis is an important complication of the pandemic because it is a mycosis hard to diagnose and treat, causing concern among COVID-19-infected patients and even in the already recovered population. The risk factors for the development of mucormycosis in these patients are related to the damage caused by the SARS-CoV-2 itself, the patient’s overstimulated immune response, and the therapy used to treat COVID-19, causing alterations such as hyperglycemia, acidosis, endothelial and lung damage, and immunosuppression. In this review, the molecular aspects of mucormycosis and the main risk factors for the development of COVID-19-associated mucormycosis are explained to understand this virus–fungi–host interaction and highlight the importance of this neglected mycosis.
High Diversity of Type I Polyketide Genes in Bacidia rubella as Revealed by the Comparative Analysis of 23 Lichen Genomes
Authors: Gerasimova Julia V. , Beck Andreas , Werth Silke , Resl Philipp
Published: April 2022

Fungi involved in lichen symbioses produce a large array of secondary metabolites that are often diagnostic in the taxonomic delimitation of lichens. The most common lichen secondary metabolites—polyketides—are synthesized by polyketide synthases, particularly by Type I PKS (TI-PKS). Here, we present a comparative genomic analysis of the TI-PKS gene content of 23 lichen-forming fungal genomes from Ascomycota, including the de novo sequenced genome of Bacidia rubella. Firstly, we identify a putative atranorin cluster in B. rubella. Secondly, we provide an overview of TI-PKS gene diversity in lichen-forming fungi, and the most comprehensive Type I PKS phylogeny of lichen-forming fungi to date, including 624 sequences. We reveal a high number of biosynthetic gene clusters and examine their domain composition in the context of previously characterized genes, confirming that PKS genes outnumber known secondary substances. Moreover, two novel groups of reducing PKSs were identified. Although many PKSs remain without functional assignments, our findings highlight that genes from lichen-forming fungi represent an untapped source of novel polyketide compounds.
Drop Weight Impact Test on Prepacked Aggregate Fibrous Concrete—An Experimental Study
Authors: Murali Gunasekaran , Abid Sallal Rashid , Amran Mugahed , Vatin Nikolai Ivanovich , Fediuk Roman
Published: April 2022

In recent years, prepacked aggregate fibrous concrete (PAFC) is a new composite that has earned immense popularity and attracted researchers globally. The preparation procedure consists of two steps: the coarse aggregate is initially piled into a mold to create a natural skeleton and then filled with flowable grout. In this instance, the skeleton was completely filled with grout and bonded into an integrated body due to cement hydration, yielding a solid concrete material. In this research, experimental tests were performed to introduce five simple alterations to the ACI 544 drop weight impact test setup, intending to decrease result dispersion. The first alteration was replacing the steel ball with a steel bar to apply a line impact instead of a single point impact. The second and third introduced line and cross notched specimens at the specimen’s top surface and the load applied through a steel plate of cross knife-like or line load types. These modifications distributed impact load over a broader area and decrease dispersion of results. The fourth and fifth were bedding with sand and coarse aggregate as an alternate to the solid base plate. One-hundred-and-eight cylindrical specimens were prepared and tested in 12 groups to evaluate the suggested alteration methods. Steel and polypropylene fibers were utilized with a dosage of 2.4% to produce PAFC. The findings indicated that the line notched specimens and sand bedding significantly decreased the coefficient of variation (COV) of the test results suggesting some alterations. Using a cross-line notched specimen and line of impact with coarse bedding also effectively reduced COV for all mixtures.
Experimental Investigation of Phase Equilibria in the Co-Ta-Si Ternary System
Authors: Wang Cuiping , Huang Xiang , Huang Liangfeng , Yang Mujin , Yang Peng , Cui Yunrui , Zhang Jinbin , Yang Shuiyuan , Liu Xingjun
Published: April 2022

In this work, two isothermal sections of the Co-Ta-Si ternary system at 900 °C and 1100 °C are constructed in the whole composition range via phase equilibrium determination with the help of electron probe microanalysis (EPMA) and X-ray diffraction (XRD) techniques. Firstly, several reported ternary phases G (Co16Ta6Si7), G″ (Co4TaSi3), E (CoTaSi), L (Co3Ta2Si) and V (Co4Ta4Si7) are all re-confirmed again. The G″ phase is found to be a kind of high-temperature compound, which is unstable at less than 1100 °C. Additionally, the L phase with a large composition range (Co32–62Ta26–36Si10–30) crystallizes with a hexagonal crystal structure (space group: P63/mmc, C14), which is the same as that of the binary high-temperature λ1-Co2Ta phase. It can be reasonably speculated that the ternary L phase results from the stabilization toward low-temperature of the binary λ1-Co2Ta through adding Si. Secondly, the binary CoTa2 and SiTa2 phases are found to form a continuous solid solution phase (Co, Si)Ta2 with a body-centered tetragonal structure. Thirdly, the elemental Si shows a large solid solubility for Co-Ta binary compounds while the Ta and Co are hardly dissolved in Co-Si and Ta-Si binary phases, respectively.
Analytical Hysteretic Behavior of Square Concrete-Filled Steel Tube Pier Columns under Alternate Sulfate Corrosion and Freeze-Thaw Cycles
Authors: Zhang Tong , Wen Qianxin , Gao Lei , Xu Qian , Tang Jupeng
Published: April 2022

The hysteretic behavior of square concrete-filled steel tube (CFST) stub columns subjected to sulfate corrosion and freeze-thaw cycle is examined by numerical investigation. The constitutive model of steel considered the Bauschinger effect, and compression (tension) damage coefficient was also adopted for the constitutive model of core concrete. The experimental results are used to verify the finite element (FE) model, which could accurately predict the hysteretic behaviors of the CFST piers. Then, the effects of the yield strength of steel, compressive strength of concrete, steel ratio, axial compression ratio, and alternation time on ultimate horizontal load are evaluated by a parametric study. The results showed that the yield strength of steel and the steel ratio have a positive effect of hysteretic behavior. The compressive strength of concrete and alternation time significantly decreased the unloading stiffness which causes the pinching phenomenon. The yield strength of steel, compressive strength of concrete, and alternation time of environmental factors (corrosion-freeze-thaw cycles) has no obvious effect on the initial stiffness, while the steel ratio has a remarkable effect. The ultimate horizontal load increases with the increasing steel ratio, yield strength of steel and compressive strength of concrete. Meanwhile, the decrement of alternation time led to the increase of ultimate horizontal load. This suggests that the confinement coefficient and alternation time are the two main factors that impact the ultimate horizontal load. A formula which considers the reduction coefficient for the ultimate horizontal load of the CFST columns subjected to sulfate corrosion and freeze-thaw cycles is proposed. The formulae can accurately predict the ultimate horizontal load with mean value of 1.022 and standard deviation of 0.003.
Cyclically Loaded Copper Slag Admixed Reinforced Concrete Beams with Cement Partially Replaced with Fly Ash
Authors: Raju Sumathy , Rathinam Jagadheeswari , Dharmar Brindha , Rekha Sasi , Avudaiappan Siva , Amran Mugahed , Usanova Kseniia Iurevna , Fediuk Roman , Guindos Pablo , Ramamoorthy Ramkumar Velayutham
Published: April 2022

Generally, the concrete with higher strength appears to produce brittle failure more easily. However, the use of mineral admixture can help in enhancing the ductility, energy dissipation, and seismic energy in the designed concrete. This paper presents energy absorption capacity, stiffness degradation, and ductility of the copper slag (CS) admixed reinforced concrete with fly ash (FA) beams subjected to forward cyclic load. The forward cyclic load was applied with the help of servo-hydraulic universal testing machines with 250 kN capacity. Twenty-four beams with a size of 100 mm × 150 mm × 1700 mm made with CS replaced for natural sand from 0% to 100% at an increment of 20%, and FA was replaced for cement from 0% to 30% with an increment of 10% were cast. Beams are designed for the grade of M30 concrete. Based on the preliminary investigation results, compressive strength of the concrete greatly increased when adding these two materials in the concrete. Normally, Grade of concrete can change the behaviour of the beam from a brittle manner to be more ductile manner. So, in this work, flexural behaviour of RC beams are studied with varying compressive strength of concrete. Experimental results showed that the RC beam made with 20% FA and 80% CS (FA20CS80) possesses higher ultimate load-carrying capacity than the control concrete beam. It withstands up to 18 cycles of loading with an ultimate deflection of 60 mm. The CS and FA admixed reinforced concrete composite beams have excellent ultimate load carrying capacity, stiffness, energy absorption capacity, and ductility indices compared to the control concrete beam.
Stress Evaluation of Welded Joints with Metal Magnetic Memory Testing Based on Tension–Compression Fatigue Test
Authors: Wang Huipeng , Xu Zhiwei , Cai Dongwei , Dong Lihong , Ma Guozheng , Wang Haidou , Liu Bin
Published: April 2022

Metal magnetic memory testing (MMMT) is an effective nondestructive technique for fatigue damage monitoring of weldments because of its capacity for stress evaluation. An experimental investigation of the effect of the applied fatigue stress on MMMT signals, including the tangential component Bx and the normal component Bz, during tension–compression fatigue tests in welded joints was carried out systematically. The Bx and Bz signals at different fatigue cycles and fatigue stresses were collected and analyzed, and the results showed that there was a peak of Bx and abnormal peaks of Bz that existed at the welded joint before loading. After loading, the peak of Bx and the abnormal peaks of Bz reversed, and the Bx signals moved upward and the Bz signals rotated anticlockwise dramatically in the first few fatigue cycles. After the fatigue cycle number was larger than 1000, Bx and Bz were stable, with very little fluctuation. In addition, the characteristics of Bx signals, the mean value, and the peak value of the average of Bx had an extremely significant linear relationship with the applied fatigue stress during the stable stage of the fatigue test, which indicates that MMMT is a feasible method for fatigue stress evaluation and even residual fatigue life estimation for weldments in service.
Correction: Kong et al. Preparation of Poly Aluminum-Ferric Chloride (PAFC) Coagulant by Extracting Aluminum and Iron Ions from High Iron Content Coal Gangue. Materials 2022, 15, 2253
Authors: Kong Deshun , Zhou Zihan , Song Shuojiang , Feng Shan , Lian Minglei , Jiang Rongli
Published: April 2022

Missing Citation [...]
Analysis of a Pure Magnesium Membrane Degradation Process and Its Functionality When Used in a Guided Bone Regeneration Model in Beagle Dogs
Authors: Rider Patrick , Kačarević Željka Perić , Elad Akiva , Rothamel Daniel , Sauer Gerrit , Bornert Fabien , Windisch Peter , Hangyási Dávid , Molnar Balint , Hesse Bernhard , Witte Frank
Published: April 2022

For the surgical technique of guided bone regeneration (GBR), the choice of available barrier membranes has until recently not included an option that is mechanically strong, durable, synthetic and resorbable. The most commonly used resorbable membranes are made from collagen, which are restricted in their mechanical strength. The purpose of this study is to evaluate the degradation and regeneration potential of a magnesium membrane compared to a collagen membrane. In eighteen beagle dogs, experimental bone defects were filled with bovine xenograft and covered with either a magnesium membrane or collagen membrane. The health status of the animals was regularly monitored and recorded. Following sacrifice, the hemimandibles were prepared for micro-CT (μ-CT) analysis. Complications during healing were observed in both groups, but ultimately, the regenerative outcome was similar between groups. The μ-CT parameters showed comparable results in both groups in terms of new bone formation at all four time points. In addition, the μ-CT analysis showed that the greatest degradation of the magnesium membranes occurred between 1 and 8 weeks and continued until week 16. The proportion of new bone within the defect site was similar for both treatment groups, indicating the potential for the magnesium membrane to be used as a viable alternative to collagen membranes. Overall, the new magnesium membrane is a functional and safe membrane for the treatment of defects according to the principles of GBR.
Role of Surface Topography in the Superhydrophobic Effect—Experimental and Numerical Studies
Authors: Haj Ibrahim Samih , Wejrzanowski Tomasz , Przybyszewski Bartłomiej , Kozera Rafał , García-Casas Xabier , Barranco Angel
Published: April 2022

Within these studies, the effect of surface topography for hydrophobic coatings was studied both numerically and experimentally. Chemically modified polyurethane coating was patterned by application of a laser beam. A set of patterns with variously distant linear peaks and grooves was obtained. The cross section of the pattern showed that the edges of the peaks and grooves were not sharp, instead forming a rounded, rectangle-like shape. For such surfaces, experimental studies were performed, and in particular the static contact angle (SCA), contact angle hysteresis (CAH), and roll-off angle (ROA) were measured. Profilometry was used to create a numerical representation of the surface. Finite volume method was then applied to simulate the behavior of the water droplets. The model developed herewith enabled us to reproduce the experimental results with good accuracy. Based on the verified model, the calculation was extended to study the behavior of the water droplet on the simulated patterns, both spiked and rectangular. These two cases, despite a similar SCA of the water droplet, have shown extremely different ROA. Thus, more detailed studies were dedicated to other geometrical features of such topography, such as the size and distance of the surface elements. Based on the results obtained herewith, the future design of superhydrophobic and/or icephobic topography is discussed.
Modelling of the Flow in the Process of Washing Out Automotive Catalyst Carriers with the PbLi Alloy
Authors: Saternus Mariola , Fornalczyk Agnieszka , Gąsior Władysław , Dębski Adam , Terlicka Sylwia , Golak Sławomir , Ciepliński Piotr
Published: April 2022

The process of platinum recovery from used car catalysts is highly desirable for both economic and environmental reasons. From the many available methods of processing used car catalysts, the article conducted both numerical and experimental studies using a device based on the collector metal method with lead as a modified medium through a magnetohydrodynamic pump for washing platinum from the channels of the ceramic catalyst carrier. It was assumed that lead alloys with the addition of lithium increase the extraction of platinum from thin catalytic layers and accelerate the platinum dissolution reaction in the Pb-Li alloy, which is the result of a greater affinity of lithium for platinum compared to lead. This assumption was verified by numerical simulations as well as laboratory tests. Tests were carried out for the secondary supply voltage range between 40 and 60 V and the catalyst flushing time between 240 and 480 s. Graphical results of the research were discussed.
Prediction of Hardenability Curves for Non-Boron Steels via a Combined Machine Learning Model
Authors: Geng Xiaoxiao , Wang Shuize , Ullah Asad , Wu Guilin , Wang Hao
Published: April 2022

Hardenability is one of the most basic criteria influencing the formulation of the heat treatment process and steel selection. Therefore, it is of great engineering value to calculate the hardenability curves rapidly and accurately without resorting to any laborious and costly experiments. However, generating a high-precision computational model for steels with different hardenability remains a challenge. In this study, a combined machine learning (CML) model including k-nearest neighbor and random forest is established to predict the hardenability curves of non-boron steels solely on the basis of chemical compositions: (i) random forest is first applied to classify steel into low- and high-hardenability steel; (ii) k-nearest neighbor and random forest models are then developed to predict the hardenability of low- and high-hardenability steel. Model validation is carried out by calculating and comparing the hardenability curves of five steels using different models. The results reveal that the CML model works well for its distinguished prediction performance with precise classification accuracy (100%), high correlation coefficient (≥0.981), and low mean absolute errors (≤3.6 HRC) and root-mean-square errors (≤3.9 HRC); it performs better than JMatPro and empirical formulas including the ideal critical diameter method and modified nonlinear equation. Therefore, this study demonstrates that the CML model combining material informatics and data-driven machine learning can rapidly and efficiently predict the hardenability curves of non-boron steel, with high prediction accuracy and a wide application range. It can guide process design and machine part selection, reducing the cost of trial and error and accelerating the development of new materials.
The Use of Synthesized CoO/Co3O4 Nanoparticles as A Corrosion Inhibitor of Low-Carbon Steel in 1 M HCl
Authors: Al-Senani Ghadah M. , Al-Saeedi Sameerah I.
Published: April 2022

CoO/Co3O4 nanoparticles (CoO/Co3O4 NPs) were synthesized with egg white. The effectiveness of CoO/Co3O4 NPs to inhibit the corrosion of carbon steel has verified in acidic medium (1 M HCl). It has been found that Langmuir adsorption isotherm is the dominant adsorption process of CoO/Co3O4 NPs on the surface of low-carbon steel. The thermodynamic parameters also demonstrated that the adsorption process of CoO/Co3O4 NPs was a physicochemical, spontaneous, and exothermic process. The electrochemical impedance spectroscopy technique and potentiodynamic polarization were applied. The results obtained in this study showed that CoO/Co3O4 NPs acted as a mixed inhibitor for the anodic reaction and the cathodic reaction, and the efficiency to inhibit the corrosion was 93% at 80 ppm of the inhibitor. The results of scanning electron microscopy (SEM) technique, energy-dispersive X-ray spectroscopy (EDS), and X-ray electron spectroscopy (XPS) confirmed the effectiveness that was obtained using the inhibitor to protect the surface of low carbon steel. Thus, low-carbon steel can be protected against corrosion in acidic medium using CoO/Co3O4 NPs as inhibitors.
Explosive Spalling Mechanism and Modeling of Concrete Lining Exposed to Fire
Authors: Qiao Rujia , Guo Yinbo , Zhou Hang , Xi Huihui
Published: April 2022

Traditional heat transfer analysis has been adopted to predict the damage in a tunnel under fire without considering the effect of concrete spalling, which leads to underestimation of the fire damage of concrete. However, accounting for the spalling effect of concrete under high temperature in an analytical heat transfer model is difficult because of the complexity of the spalling mechanism. This study aims to establish an analytical model to estimate the influence of concrete spalling on the fire-damage depth prediction. To overcome this challenge, first, a series of fire tests were conducted in a unidirectional heating system. The spalling phenomenon and spalling characteristics were observed. Based on the experimental test results, the moisture content of concrete is one of the key factors of spalling. Obvious layered spalling characteristics of concrete samples without drying could be observed under the unidirectional heat conduction system. The critical temperature of spalling is 600 °C, and the thickness of the spalling layer is 2 cm~2.5 cm. These two parameters are critical spalling conditions. Second, a multilayer model for the heat transfer analysis considering the spalling effect of tunnel lining under fire was proposed. By using Laplace transform and the series solving method for ordinary differential equations, the time-dependent temperature and stress fields of concrete lining during tunnel fire could be obtained, which are the basis of damage evolution. The analytical results agreed with the experimental data. The spalling depth of tunnel lining related to the temperature rise of tunnel fire could be predicted by using the proposed analytical model. The results of this research can be used to provide a better damage evaluation of tunnel lining under fire.
Role of Air Bubble Inclusion on Polyurethane Reaction Kinetics
Authors: Brondi Cosimo , Santiago-Calvo Mercedes , Di Maio Ernesto , Rodríguez-Perez Miguel Ángel
Published: April 2022

In this study, we investigated the influence of mixing conditions on the foaming process of water blown polyurethane (PU) foams obtained at different mixing speeds (50, 500, 1000 and 2000 rpm). In particular, the morphological evolution during the foaming process, in terms of the bubble size and bubble density, was studied via optical observations, while the effects on the reaction kinetics were monitored using in situ FTIR spectroscopy. At the slow mixing speed (50 rpm), no air bubbles were included and the early foaming process was characterized by the formation of new bubbles (CO2 nucleation), provided by the blowing reaction. Later on, it was observed that the coalescence affected the overall foaming process, caused by the gelling reaction, which was inhibited by the indigent mixing conditions and could not withstand the bubbles expansion. As a result, a PU foam with a coarse cellular structure and an average bubble size of 173 µm was obtained. In this case, the bubbles degeneration rate, dN/dt, was −3095 bubble·cm−3·s−1. On the contrary, at 500 rpm, air bubbles were included into the PU reaction system (aeration) and no formation of new bubbles was observed during the foaming process. After this, the air bubbles underwent growth caused by diffusion of the CO2 provided by the blowing reaction. As the gelling reaction was not strongly depleted as in the case at 50 rpm, the coalescence less affected the bubble growth (dN/dt = −2654 bubble·cm−3·s−1), leading to a PU foam with an average bubble size of 94 µm. For the foams obtained at 1000 and 2000 rpm, the bubble degeneration was first affected by coalescence and then by Ostwald ripening, and a finer cellular structure was observed (with average bubble sizes of 62 µm and 63 µm for 1000 rpm and 2000 rpm, respectively). During the first foaming stage, the coalescence was less predominant in the bubble growth (with dN/dt values of −1838 bubble·cm−3·s−1 and −1601 bubble·cm−3·s−1, respectively) compared to 50 rpm and 500 rpm. This occurrence was ascribed to the more balanced process between the bubble expansion and the PU polymerization caused by the more suitable mixing conditions. During the late foaming stage, the Ostwald ripening was only responsible for the further bubble degeneration (with dN/dt values of −89 bubble·cm−3·s−1 and −69 bubble·cm−3·s−1, respectively).
Acoustic Performance of Sound Absorbing Materials Produced from Wool of Local Mountain Sheep
Authors: Kobiela-Mendrek Katarzyna , Bączek Marcin , Broda Jan , Rom Monika , Espelien Ingvild , Klepp Ingun
Published: April 2022

Wool of mountain sheep, treated nowadays as a waste or troublesome byproduct of sheep husbandry, was used for the production of sound-absorbing materials. Felts of two different thicknesses were produced from loose fibres. Additionally, two types of yarn, ring spun and core rug, were obtained. The yarns were used for the production of tufted fabric with cut and loop piles. During the examinations, basic parameters of the obtained materials were determined. Then, according to standard procedure with the use of impedance tube, the sound absorption coefficient was measured, and the noise reduction coefficient (NRC) was calculated. It was revealed that felt produced from coarse wool exhibits high porosity, and its sound absorbing capacity is strongly related to the felt thickness. For thicker felt the NRC achieved 0.4, which is comparable with the NRC of commercial ceiling tiles. It was shown that the crucial parameter influencing the sound absorption of the tufted fabrics was the pile height. For both types of yarns, when the height of the pile was increased from 12 to 16 mm, the NRC increased from 0.4 to 0.42. The manufactured materials made from local wool possess good absorption capacity, similar to commercial products usually made from more expensive wool types. The materials look nice and can be used for noise reduction as inner acoustic screens, panels, or carpets.
Influence of Manufacturing Conditions on Binder-Less Boards from Steam-Exploded Hemp Shives and Wheat Straw
Authors: Tupciauskas Ramunas , Rizhikovs Janis , Andzs Martins , Bikovens Oskars
Published: April 2022

In the current decade, based on the European Green Deal, new challenges of the wood-based panel industry have arisen, seeking for formaldehyde-free bio-based adhesives and broadening raw lignocellulosics. In order to contribute to the potential solution to the challenges, binder-less boards of steam-exploded (SE 220 °C/2 min) hemp shives and wheat straw were investigated. The objective of this study was to find out the optimal hot-pressing conditions in terms of temperature (150–200 °C) and time (5–16 min) for the boards with three density levels (800–1000–1200 kg·m−3). An experimental design was created and the influence of the variables on binder-less panels were evaluated using a randomized central composite design of the response surface methodology. Water absorption (WA) and thickness swelling (TS) during 24 h, modulus of elasticity (MOE), and modulus of rupture (MOR) in bending test, internal bonding (IB), and Fourier-transform infrared spectroscopy were determined for the obtained boards. Each detected physical-mechanical property of the obtained boards was described by statistical models being different at each density level. The optimal conditions of the obtained binder-less boards were different depending on the raw material and density. For example, the optimal conditions of the boards from SE wheat straw with a density of 800 kg m−3 were found at T = 220 °C and t = 15 min, with the achieved properties of WA = 53%, TS = 4%, MOE = 2750 N mm−2, MOR = 15.5 N mm−2, and IB = 0.64 N mm−2. Based on the achieved properties at the optimal conditions, the boards meet the requirements of the conventional particleboard Type P3 according to EN 312.
Special Issue: Processing, Structure, Dynamics and Mechanical Properties of Polymeric Materials
Authors: Sikora Janusz W.
Published: April 2022

The current Special Issue entitled “Processing, structure, dynamics and mechanical properties of polymeric materials” brings together scientists working at universities, research institutes, laboratories and various industries to discuss cutting-edge research on processing new polymeric materials using standard and innovative machines and to understand the structure and properties of these materials [...]
Aplitic Granite Waste as Raw Material for the Production of Outdoor Ceramic Floor Tiles
Authors: Vasić Milica Vidak , Mijatović Nevenka , Radojević Zagorka
Published: April 2022

One of the significant problems in the production of ceramic tiles is the very high consumption of natural resources such as clay, feldspar, and quartz. The possibility of replacing part of the formulation of ceramic batches is of great importance. In this research, the possibility of using aplitic granite waste from dimensional stone production was analyzed in detail. The waste is considered a low-cost substitute for feldspar in Serbia. The milled powdery waste was analytically tested to reveal its chemical and mineralogical contents, particle size distribution, and other important properties. The ceramic tiles containing aplitic granite waste (GW) and GW/raw clay mixture (CGW) were hydraulically pressed, and the ceramic and technological properties determined. This waste can act as a filler while forming, drying, and firing, since the high content of quartz helps to control the shrinkage and acts as a fluxing agent in high temperatures due to its feldspathic nature. The waste was found favorable in the production of ceramic tiles, as the gained values of modulus of rupture and water absorption were 28.68 MPa and 1.33%, respectively. The parameters defined in the series of standards EN ISO 10545 were tested on a semi-industrial probe, determining that this combination of materials (without the addition of quartz) may be efficiently used to produce ceramic floor tiles. The usage of what would otherwise be waste material contributes to sustainable management and environmentally friendly solutions by avoiding landfilling, while at the same time it enabling the conservation of scarce natural feldspar deposits.
Concentration Quantification of TiO2 Nanoparticles Synthesized by Laser Ablation of a Ti Target in Water
Authors: Blažeka Damjan , Car Julio , Krstulović Nikša
Published: April 2022

In this work, we present a quantitative method for determining the concentration of metal oxide nanoparticles (NP) synthesized by laser ablation in liquid. The case study was performed with titanium dioxide nanoparticles (TiO2 NP), which were synthesized by laser ablation of a Ti target in water. After synthesis, a colloidal solution was analyzed with UV-Vis spectroscopy. At the same time, the craters that remained on the Ti target after ablation were evaluated with an optical microscope to determine the volume of the ablated material. SEM microscopy was used to determine the TiO2 NP size distribution. It was found that synthesized TiO2 NP followed a Log-Normal diameter distribution with a maximum at about 64 nm. From the volume of ablated material and NP size distribution, under the assumption that most of the ablated material is consumed to form nanoparticles, a concentration of nanoparticles can be determined. The proposed method is verified by comparing the calculated concentrations to the values obtained from the Beer–Lambert law using the Mie scattering theory for the NP cross-section calculation.
On the Residual Continuity of Global Attractors
Authors: Wang Xingxing , Cui Hongyong
Published: April 2022

In this brief paper, we studied the residual continuity of global attractors Aλ in varying parameters λ∈Λ with Λ a bounded Borel set in Rd. We first reviewed the well-known residual continuity result of global attractors and then showed that this residual continuity is equivalent to the dense continuity. Then, we proved an analogue continuity result in measure sense that, under certain conditions, the set-valued map λ↦Aλ is almost (in the Lebesgue measure sense) uniformly continuous: for any small ε>0 there exists a closed subset Cε⊂Λ with Lebesgue measure m(Cε)>μ(Λ)−ε such that the set-valued map ε↦Aε is uniformly continuous on Cε. This, in return, indicates that the selected attractors {Aλ:λ∈Cε} can be equi-attracting.
Confining Fluorescent Probes in Nanochannels to Construct Reusable Nanosensors for Ion Current and Fluorescence Dual Gating
Authors: Zhang Dan , Wang Chunfei , Wu Changfeng , Zhang Xuanjun
Published: April 2022

Here, we confined fluorescent probes to solid nanochannels to construct nanosensors, which not only significantly improved the reusability of the molecular probes, but also achieved ion current and fluorescence dual gating for more reliable detection. The combination of optical and electrical modalities can provide comprehensive spatiotemporal information that can be used to elucidate the sensing mechanism within the nanochannel. As a proof-of-concept experiment, fluorescein isothiocyanate (FITC)–hydrazine (N2H4) was selected to modify nanochannels for the effective detection of Hg2+. Based on spirolactam opening tactics, the system synergistically alters the surface charge and fluorescence intensity in response to Hg2+, establishing a dual open state of current and fluorescence. The newly prepared nanosensor exhibited a fast response (<1 min), high sensitivity, and selectivity towards Hg2+. Importantly, the nanodevice could be recovered by simple N2H4 treatment. Such sensing behavior could be used to implement optoelectronic dual-output XOR logical gates under the management of Hg2+ and N2H4. This strategy is anticipated to find broad applications in other nanochannel-based systems for various sensing applications used for monitoring of pollutants, food additives, and biomolecules.