bluuebunny/crossref_metadata_2025 huggingface dataset:
Ship Autonomous Collision-Avoidance Strategies—A Comprehensive Review
Authors: Lyu Hongguang , Hao Zengrui , Li Jiawei , Li Guang , Sun Xiaofeng , Zhang Guoqing , Yin Yong , Zhao Yanjie , Zhang Lunping
Published: April 2023

Autonomous decision-making for ships to avoid collision is core to the autonomous navigation of intelligent ships. In recent years, related research has shown explosive growth. However, owing to the complex constraints of navigation environments, the Convention of the International Regulations for Preventing Collisions at Sea, 1972 (COLREGs), and the underactuated characteristics of ships, it is extremely challenging to design a decision-making algorithm for autonomous collision avoidance (CA) that is practically useful. Based on the investigation of many studies, current decision-making algorithms can be attributed to three strategies: alteration of course alone, alteration of speed alone, and alteration of both course and speed. This study discusses the implementation methods of each strategy in detail and compares the specific ways, applicable scenes, and limiting conditions of these methods to achieve alteration of course and/or speed to avoid collision, especially their advantages and disadvantages. Additionally, this study quantitatively analyzes the coupling mechanisms of alterations of course and speed for autonomous CA decision-making under different encounter situations, supplementing and optimizing the decision-making theory for ship autonomous CA. Finally, several feasible algorithms and improvement schemes for autonomous CA decision-making, combined with course and speed alterations, are discussed.
Morphological and Phylogenetic Analyses Reveal Three New Species of Distoseptispora (Distoseptisporaceae, Distoseptisporales) from Yunnan, China
Authors: Liu Jingwen , Hu Yafen , Luo Xingxing , Xu Zhaohuan , Castañeda-Ruíz Rafael F. , Xia Jiwen , Zhang Xiuguo , Zhang Lianhu , Cui Ruqiang , Ma Jian
Published: April 2023

Three new species of Distoseptispora, viz. D. mengsongensis, D. nabanheensis, and D. sinensis, are described and illustrated from specimens collected on dead branches of unidentified plants in Yunnan Province, China. Phylogenetic analyses of LSU, ITS, and TEF1 sequence data, using maximum-likelihood (ML) and Bayesian inference (BI), reveal the taxonomic placement of D. mengsongensis, D. nabanheensis, and D. sinensis within Distoseptispora. Both morphological observations and molecular phylogenetic analyses supported D. mengsongensis, D. nabanheensis, and D. sinensis as three new taxa. To extend our knowledge of the diversity of Distoseptispora-like taxa, a list of recognized species of Distoseptispora with major morphological features, habitat, host, and locality is also provided.
Biodiversity of Basidiomycetous Yeasts Associated with Cladonia rei Lichen in Japan, with a Description of Microsporomyces cladoniophilus sp. nov
Authors: Nguyen Ngoc-Hung , Nguyen Phuong-Thao , Otake Hitomi , Nagata Ayana , Hirano Nobuharu , Imanishi-Shimizu Yumi , Shimizu Kiminori
Published: April 2023

For more than a century, lichens have been used as an example of dual-partner symbiosis. Recently, this has been challenged by the discovery of various basidiomycetous yeasts that coexist in multiple lichen species, among which Cladonia lichens from Europe and the United States were discovered to be highly specifically associated with the basidiomycetous yeast of the family Microsporomycetaceae. To verify this highly specific relationship, we investigated the diversity of basidiomycetous yeasts associated with Cladonia rei, a widely distributed lichen in Japan, by applying two approaches: yeast isolation from the lichen thalli and meta-barcoding analysis. We obtained 42 cultures of Cystobasidiomycetous yeast which were grouped into six lineages within the family Microsporomycetaceae. Unexpectedly, although the cystobasidiomycetes-specific primer was used, not only the cystobasidiomycetous yeasts but species from other classes were also detected via the meta-barcoding dataset; in particular, pucciniomycetous yeasts were found at a high frequency in some samples. Further, Halobasidium xiangyangense, which was detected in every sample with high abundance, is highly likely a generalist epiphytic fungus that has the ability to associate with C. rei. In the pucciniomycetous group, most of the detected species belong to the scale insect-associated yeast Septobasidium genus. In conclusion, even though Microsporomyces species are not the only yeast group associated with Cladonia lichen, our study demonstrated that the thalli of Cladonia rei lichen could be a suitable habit for them.
Characteristics and Risk Factors of Ultra-High-Risk Patients with Newly Diagnosed Multiple Myeloma
Authors: Geng Chuanying , Yang Guangzhong , Zhou Huixing , Wang Huijuan , Li Yanchen , Leng Yun , Zhang Zhiyao , Jian Yuan , Chen Wenming
Published: April 2023

Objective: To investigate the clinical characteristics and risk factors of ultra-high-risk (UHR) patients with newly diagnosed multiple myeloma (MM). Methods: We screened UHR patients with a survival of less than 24 months and we selected patients with a concurrent survival of more than 24 months as a control group. We retrospectively analyzed the clinical characteristics of UHR patients with newly diagnosed MM and screened related risk factors. Results: In total we analyzed 477 patients, which included 121 (25.4%) UHR patients and 356 (74.6%) control patients. Median overall survival (OS) and progression-free survival (PFS) of UHR patients was 10.5 months (7.5–13.5 months) and 6.3 months (5.4–7.2 months), respectively. Univariate logistic regression analysis showed that age > 65 years, hemoglobin (HGB) < 100 g/L, lactate dehydrogenase (LDH) > 250 U/L, serum creatinine (SCr) > 2 mg/dL, corrected serum calcium (CsCa) > 2.75 mmol/L, B-type natriuretic peptide (BNP) or N-terminal prohormone BNP (NT-proBNP) > 2 upper limit of normal (ULN), high-risk cytogenetics, Barthel index score, and International Staging System (ISS) stage III were associated with UHR MM. In a multivariate analysis, age > 65 years, LDH > 250 U/L, CsCa > 2.75 mmol/L, BNP or NT-proBNP > 2 ULN, high-risk cytogenetics, and Barthel index score were independent risk factors for UHR MM. Moreover, UHR patients had a worse response rate than control patients. Conclusion: Our study highlighted the characteristics of UHR MM patients and suggested that the combination of organ insufficiency and highly malignant myeloma cells resulted in poor outcomes of patients with UHR MM.
“Stabilize the Unstable”: Treatment Pathophysiology in Bleeding Trauma Patients, from the Field to the ICU. State of the Art
Authors: Bini Roberto , Virdis Francesco , Cioffi Stefano , Altomare Michele , Sammartano Fabrizio , Borotto Erika , Chiara Osvaldo , Cimbanassi Stefania
Published: April 2023

The results of the Global Burden of Disease (GBD) study showed that, in 2019, 8% of deaths worldwide were trauma related [...]
PbDinEHR: A Novel Privacy by Design Developed Framework Using Distributed Data Storage and Sharing for Secure and Scalable Electronic Health Records Management
Authors: Semantha Farida Habib , Azam Sami , Shanmugam Bharanidharan , Yeo Kheng Cher
Published: April 2023

Privacy in Electronic Health Records (EHR) has become a significant concern in today’s rapidly changing world, particularly for personal and sensitive user data. The sheer volume and sensitive nature of patient records require healthcare providers to exercise an intense quantity of caution during EHR implementation. In recent years, various healthcare providers have been hit by ransomware and distributed denial of service attacks, halting many emergency services during COVID-19. Personal data breaches are becoming more common day by day, and privacy concerns are often raised when sharing data across a network, mainly due to transparency and security issues. To tackle this problem, various researchers have proposed privacy-preserving solutions for EHR. However, most solutions do not extensively use Privacy by Design (PbD) mechanisms, distributed data storage and sharing when designing their frameworks, which is the emphasis of this study. To design a framework for Privacy by Design in Electronic Health Records (PbDinEHR) that can preserve the privacy of patients during data collection, storage, access and sharing, we have analysed the fundamental principles of privacy by design and privacy design strategies, and the compatibility of our proposed healthcare principles with Privacy Impact Assessment (PIA), Australian Privacy Principles (APPs) and General Data Protection Regulation (GDPR). To demonstrate the proposed framework, ‘PbDinEHR’, we have implemented a Patient Record Management System (PRMS) to create interfaces for patients and healthcare providers. In addition, to provide transparency and security for sharing patients’ medical files with various healthcare providers, we have implemented a distributed file system and two permission blockchain networks using the InterPlanetary File System (IPFS) and Ethereum blockchain. This allows us to expand the proposed privacy by design mechanisms in the future to enable healthcare providers, patients, imaging labs and others to share patient-centric data in a transparent manner. The developed framework has been tested and evaluated to ensure user performance, effectiveness, and security. The complete solution is expected to provide progressive resistance in the face of continuous data breaches in the patient information domain.
Exploring the Terminology, Definitions, and Forms of Post-Occupancy Evaluation (POE) in Landscape Architecture
Authors: Chen Guanyu , Bowring Jacky , Davis Shannon
Published: April 2023

While the concept of Post-Occupancy Evaluation (POE) is widely applied in landscape architecture and other relevant fields, the term POE is not well-defined. By reviewing and analysing a representative set of POE definitions collected from existing academic and grey literature using content analysis methods, this study aims to enhance understanding of the breadth of the concept and its relevant practices. Our research found that the concept of POE was developed in architecture in the 1970s and subsequently adopted in landscape architecture in the 1980s. With the growth of the field in architecture and its adaptation to landscape architecture, the scope of POE was significantly expanded over recent decades, and with this growth, there have been considerable divergences in definitions and understandings of how to carry out POE. A range of different evaluation objects and four evaluation models were identified by this study. By surveying the conceptual terrain of POE, our research establishes the need for practitioners to be aware of the breadth of the concept and the potential ambiguity surrounding what is meant by the approach. Consequently, practitioners need to be specific and explicit about their understanding of POE. The findings also demonstrate how interdisciplinary differences appear to have been overlooked when adapting POE from one discipline to another. We, therefore, argue that it is crucial to keep shaping and trimming the concept to support the adaption of POE processes into different disciplinary domains.
Utilizing Fractal Dimensions as Indicators to Detect Elements of Visual Attraction: A Case Study of the Greenway along Lake Taihu, China
Authors: Fan Rong , Yocom Ken P. , Guo Yeyuan
Published: April 2023

It is widely acknowledged that the quality of greenway landscape resources enhances the visual appeal of people. While most studies have evaluated visual perception and preference, few have considered the relationship between the distribution of greenways in relation to the proximity of water bodies such as lakes and rivers. Such an investigation requires an in-depth analysis of how to plan and design greenways in order to better enhance people’s willingness to access and utilize them. In this research we propose specific color brightness and contour visual attraction elements to further discuss the quality of greenway landscape resources in the rapidly urbanizing Lake Taihu region of China. Specifically, we utilize a common method in fractal theory analysis called counting box dimension to calculate and analyze the sample images. The method generates data on fractal dimension (FD) values of two elements; the optimal fractal dimension threshold range; the characteristics exhibited by the maximum and minimum fractal dimension values in the greenway landscape; and the relationship between the two visual attraction elements allowing us to derive distribution of the greenway and water bodies. The results reveal that greenway segments with high values of the visual attraction element of color brightness fractal dimension (FD) are significantly closer to the lake than those subject to high values of the visual attraction element. Some segments are even close to the lake surface, which is because the glare from the direct sunlight and the reflection from the lake surface superimposed on each other, so that the greenway near the lake surface is also affected by the brightness and shows the result of high color brightness values. However, the greenway segments with high values of contour element FD are clearly more influenced by plants and other landscape elements. This is due to the rich self-similarity of the plants themselves. Most of the greenway segments dominated by contour elements are distant from the lake surface. Both color brightness and contour elements are important indicators of the quality of the visual resources of the Lake Taihu Greenway landscape. This reveals that the determination of the sub-dimensional values of color brightness (1.7608, 1.9337) and contour (1.7230, 1.9006) visual attraction elements and the optimal threshold range (1.7608, 1.9006) can provide theoretical implications for the landscape planning and design of lake-ring type greenways and practical implications for assessing the quality of visual resources in greenway landscapes.
Impact of Administrative Division and Regional Accessibility on Rural Mobility in the Pearl River Delta: Evidence from Cellphone Big Data
Authors: Zhao Yi , Lu Daming , Zhao Pu , Xie Senkai , Zhang Wenjia
Published: April 2023

Mobility plays a critical role in promoting rural development. However, the current knowledge regarding the factors that influence mobility between rural towns is limited. The objective of this study is to explore the impact of administrative division and regional accessibility on rural mobility to inform development policies and strategies. The administrative division is demarcated by district and city boundaries, and regional accessibility is assessed using various modes of transportation, including cars, high-speed railways (HSRs), and intercity commuter railways (ICRs). A flow-based geographically weighted regression (FGWR) method is employed based on mobile phone signaling data to quantify the associations and identify the local effects of these factors in the Pearl River Delta (PRD). The findings suggest that both administrative division and regional accessibility significantly influence rural mobility. Specifically, the effects of district boundaries on commuting mobility are more pronounced in the central areas along the Pearl River, while the effects of city boundaries on non-commuting mobility between the core area and surrounding regions are more significant. With regard to regional accessibility, cars are the preferred mode of transportation for connections between the core areas of cities along the Pearl River, whereas HSR is favored more for non-commuting trips between the northwest and center regions. This study provides novel empirical insights into the understanding of rural mobility and has significant implications for promoting regional integration.
Quantifying the Effects of Green-Town Development on Land Surface Temperatures (LST) (A Case Study at Karizland (Karizboom), Yazd, Iran)
Authors: Mansourmoghaddam Mohammad , Naghipur Negar , Rousta Iman , Alavipanah Seyed Kazem , Olafsson Haraldur , Ali Ashehad A.
Published: April 2023

Several earth science investigations depend heavily on knowing the surface energy budget and determining surface temperature. The primary factor affecting the energy balance in the surface physical processes of the planet is the land surface temperature (LST). Even in the case of small-scale green areas like local parks, plants have a significant impact on the climate of cities. The goal of this study was to estimate the construction-related impacts of the Karizland green town (green belt) on the LST of its surroundings over time, for the years 2013 (before construction began), 2015, 2020 and 2022 (after construction was completed). LST values and hot spot analyses were employed for thermal condition evaluation purposes on Landsat-8 satellite images, and normalized difference vegetation index (NDVI) and fractional vegetation cover (FVC) indices were used for examining the vegetation change. The results showed that after the establishment of the green town, the mean NDVI and FVC grew by 275% and 950%, respectively, compared to the initial period, which resulted in the addition of approximately 208.35 ha of green space to the study area. In this regard, the results showed that after these changes, compared to the first period, the mean LST decreased by 8%. In addition, the area of the class of hotspot analysis with less than 90% confidence increased by 9%. The results illustrated that almost 20% of the data in the LST range was below 55 °C in 2013, near 57 °C in 2015, and around 51 °C in 2020 and 2022. The results also showed a negative relationship between the distance from the established settlement and the values of NDVI and FVC in 2022 of 91% and 89% and in 2020 of 67% and 69%, respectively. Every year, LST has had a significant negative relationship with the NDVI and FVC of that year and a positive relationship with the LST of the following years, such that the correlation decreases in later years. In order to control LST and the temperature surrounding cities, this research strongly advises managers to develop these green towns.
Migration of Dissolved Organic Matter in the Epikarst Fissured Soil of South China Karst
Authors: Cheng Kun , Liu Ziqi , Xiong Kangning , He Qiufang , Li Yuan , Cai Lulu , Chen Yi
Published: April 2023

The efficient reactivity and mobility of dissolved organic matter (DOM) affect biogeochemical processes. As important components that link aboveground and belowground vertical systems under the binary 3D structure of karst, fissures provide soil–water–nutrient leakage channels and storage spaces. However, reports on DOM properties and drivers in fissured soil are extremely rare. This study characterizes DOM in the fissured soil of different vegetation types under medium-intensity rocky desertification conditions. Soil samples were characterized via ultraviolet (UV)–visible absorption spectroscopy and fluorescence excitation–emission matrix–parallel factor analysis. Five fluorescent fractions were identified. The controlling factors for the optical properties of soil DOM were determined via the redundancy analysis method. Results showed the following: (1) Dissolved organic C/soil organic C < 4.68 + 0.49‰, specific UV absorbance (SUVA)254 and SUVA260 exhibited low overall performance with the vast majority of the humification index (HIX) < 4, most of the fluorescence index (FI) ≥ 1.7, most of the biological index (BIX) in 0.6 < BIX < 1 and 31.67–41.67% of protein-like fractions. These data indicate that cleaved soil, except for topsoil, has low DOM content, weak aromaticity, and low humification; (2) Rainfall intensity, aperture, and near-surface vegetation type are the major causes of DOM transport and loss; and (3) Most DOM losses are likely to be protein-like and enhance the loss of soil P. In summary, environmental factors and the characteristics of fissures determine DOM content and migration, particularly rainfall intensity and vegetation type. The loss of lighter DOM components will be greater in an area with high karst desertification grade, strong fissure development, weaker soil aromaticity, and lower humification. These results provide a clearer basis for optimizing the fissure nutrient element migration scheme in karst areas.
Exercise Improves the Coordination of the Mitochondrial Unfolded Protein Response and Mitophagy in Aging Skeletal Muscle
Authors: Wang Yan , Li Jialin , Zhang Ziyi , Wang Runzi , Bo Hai , Zhang Yong
Published: April 2023

The mitochondrial unfolded protein response (UPRmt) and mitophagy are two mitochondrial quality control (MQC) systems that work at the molecular and organelle levels, respectively, to maintain mitochondrial homeostasis. Under stress conditions, these two processes are simultaneously activated and compensate for each other when one process is insufficient, indicating mechanistic coordination between the UPRmt and mitophagy that is likely controlled by common upstream signals. This review focuses on the molecular signals regulating this coordination and presents evidence showing that this coordination mechanism is impaired during aging and promoted by exercise. Furthermore, the bidirectional regulation of reactive oxygen species (ROS) and AMPK in modulating this mechanism is discussed. The hierarchical surveillance network of MQC can be targeted by exercise-derived ROS to attenuate aging, which offers a molecular basis for potential therapeutic interventions for sarcopenia.
Hallux Partial Necrosis Associated with Antiphospholipid Syndrome: The Importance of Early Accurate Diagnosis
Authors: Córdoba-Fernández Antonio , Marmol-García Francisco , Córdoba-Jiménez Victoria
Published: April 2023

This study highlights the importance of having a high clinical suspicion of hypercoagulopathy such as antiphospholipid syndrome (APS) in podiatric patients with normal foot pulses and normal standard coagulation tests. APS is an autoimmune disease that is characterized by inflammatory thrombosis in the arteries and veins and obstetric complications such as pregnancy loss. APS usually affects vessels of the lower extremities. We report herein the case of a 46-year-old woman with previous episodes of pre-eclampsia who suffered from partial ischemic necrosis of the hallux of the left foot. After several ischemic episodes of the hallux, with increased risk of toe amputation, the patient was finally diagnosed with APS and treated with specific anticoagulant medication. The patient’s symptoms subsided, and toe amputation was prevented. Early accurate diagnosis and appropriate clinical management are critical to providing optimal outcomes and reducing the risk of amputation.
Androgen-Induced Cardiovascular Risk in Polycystic Ovary Syndrome: The Role of T Lymphocytes
Authors: Moulana Mohadetheh
Published: April 2023

An estimated 15–20% of reproductive-age women are affected by polycystic ovary syndrome (PCOS). PCOS is associated with substantial metabolic and cardiovascular long-term consequences. In young women with PCOS, several cardiovascular risk factors may be found, including chronic inflammation, high blood pressure, and elevated leukocytes. These women are at an increased risk of cardiovascular diseases (CVD), not only during the reproductive years, but also with aging and menopause; therefore, the early prevention and treatment of future cardiovascular adverse effects are necessary. The fundamental characteristic of PCOS is hyperandrogenemia, which is associated with increased pro-inflammatory cytokines and T lymphocytes. Whether these factors play a role in the pathophysiology of hypertension, a risk factor of CVD, due to PCOS is not well established. This review will briefly discuss how a modest increase in androgens in females is linked to the development of hypertension through pro-inflammatory cytokines and T lymphocyte subsets and the promotion of renal injury. Moreover, it reveals a few existing research gaps in this area, including the lack of specific therapy directed at androgen-induced inflammation and immune activation, thus emphasizing the necessity to explore the systemic inflammation in women with PCOS to halt the inevitable inflammatory process targeting the underlying abnormalities of CVD.
Using Machine Learning Methods in Identifying Genes Associated with COVID-19 in Cardiomyocytes and Cardiac Vascular Endothelial Cells
Authors: Xu Yaochen , Ma Qinglan , Ren Jingxin , Chen Lei , Guo Wei , Feng Kaiyan , Zeng Zhenbing , Huang Tao , Cai Yudong
Published: April 2023

Corona Virus Disease 2019 (COVID-19) not only causes respiratory system damage, but also imposes strain on the cardiovascular system. Vascular endothelial cells and cardiomyocytes play an important role in cardiac function. The aberrant expression of genes in vascular endothelial cells and cardiomyocytes can lead to cardiovascular diseases. In this study, we sought to explain the influence of respiratory syndrome coronavirus 2 (SARS-CoV-2) infection on the gene expression levels of vascular endothelial cells and cardiomyocytes. We designed an advanced machine learning-based workflow to analyze the gene expression profile data of vascular endothelial cells and cardiomyocytes from patients with COVID-19 and healthy controls. An incremental feature selection method with a decision tree was used in building efficient classifiers and summarizing quantitative classification genes and rules. Some key genes, such as MALAT1, MT-CO1, and CD36, were extracted, which exert important effects on cardiac function, from the gene expression matrix of 104,182 cardiomyocytes, including 12,007 cells from patients with COVID-19 and 92,175 cells from healthy controls, and 22,438 vascular endothelial cells, including 10,812 cells from patients with COVID-19 and 11,626 cells from healthy controls. The findings reported in this study may provide insights into the effect of COVID-19 on cardiac cells and further explain the pathogenesis of COVID-19, and they may facilitate the identification of potential therapeutic targets.
A Comprehensive Review on Weight Loss Associated with Anti-Diabetic Medications
Authors: Haddad Fatma , Dokmak Ghadeer , Bader Maryam , Karaman Rafik
Published: April 2023

Obesity is a complex metabolic condition that can have a negative impact on one’s health and even result in mortality. The management of obesity has been addressed in a number of ways, including lifestyle changes, medication using appetite suppressants and thermogenics, and bariatric surgery for individuals who are severely obese. Liraglutide and semaglutide are two of the five Food and Drug Administration (FDA)-approved anti-obesity drugs that are FDA-approved agents for the treatment of type 2 diabetes mellitus (T2DM) patients. In order to highlight the positive effects of these drugs as anti-obesity treatments, we analyzed the weight loss effects of T2DM agents that have demonstrated weight loss effects in this study by evaluating clinical studies that were published for each agent. Many clinical studies have revealed that some antihyperglycemic medications can help people lose weight, while others either cause weight gain or neutral results. Acarbose has mild weight loss effects and metformin and sodium-dependent glucose cotransporter proteins-2 (SGLT-2) inhibitors have modest weight loss effects; however, some glucagon-like peptide-1 (GLP-1) receptor agonists had the greatest impact on weight loss. Dipeptidyl peptidase 4 (DPP-4) inhibitors showed a neutral or mild weight loss effect. To sum up, some of the GLP-1 agonist drugs show promise as weight-loss treatments.
The Fungal and Bacterial Interface in the Respiratory Mycobiome with a Focus on Aspergillus spp.
Authors: Rozaliyani Anna , Antariksa Budhi , Nurwidya Fariz , Zaini Jamal , Setianingrum Findra , Hasan Firman , Nugrahapraja Husna , Yusva Humaira , Wibowo Heri , Bowolaksono Anom , Kosmidis Chris
Published: April 2023

The heterogeneity of the lung microbiome and its alteration are prevalently seen among chronic lung diseases patients. However, studies to date have primarily focused on the bacterial microbiome in the lung rather than fungal composition, which might play an essential role in the mechanisms of several chronic lung diseases. It is now well established that Aspergillus spp. colonies may induce various unfavorable inflammatory responses. Furthermore, bacterial microbiomes such as Pseudomonas aeruginosa provide several mechanisms that inhibit or stimulate Aspergillus spp. life cycles. In this review, we highlighted fungal and bacterial microbiome interactions in the respiratory tract, with a focus on Aspergillus spp.
Evaluation of Various Shear-Thinning Models for Squalane Using Traction Measurements, TEHD and NEMD Simulations
Authors: Neupert Thomas , Bartel Dirk
Published: April 2023

The accurate prediction of friction in highly loaded concentrated contacts is one of the most challenging aspects of thermal elastohydrodynamic (TEHD) simulation. The correct modelling of fluid behaviour on the macroscale, in particular non-Newtonian flow behaviour, is an essential prerequisite. For many years, shear-thinning models have been developed and validated with different approaches and controversially discussed. In basic research, model fluids are often used in this context, which have a similar behaviour to practical lubricants. Accompanied by earlier research results, this paper carries out comprehensive investigations on the rheometric behaviour of the model fluid squalane. Based on traction measurements at four different tribometers, an overall parameter optimisation and performance evaluation of three different shear-thinning models is performed using numerical TEHD simulations. In order to additionally validate the theoretical viscosity behaviour, the optimised shear-thinning curves are then compared with comprehensive non-equilibrium molecular dynamics (NEMD) simulations. The key aspect of this paper is the simultaneous consideration of the shear-thinning models in terms of rheometric, experimental, and simulative investigations without changing the parameters. All investigations show that the Eyring model, despite its simplicity, provides the best agreement in both the numerical contact simulation and the NEMD simulations.
3-(4-Fluorophenyl)-1-(1-(4-fluorophenyl)-3,3,3-trifluoroprop-1-en-1-yl)-5-fluoro-1H-pyrazole
Authors: Paveliev Stanislav , Ustyuzhanin Alexander , Krylov Igor , Terent’ev Alexander
Published: April 2023

In this work, the title compound was synthesized via the visible-light-induced radical denitrogenative trifluoromethylation of the corresponding vinyl azide followed by Cs2CO3-mediated defluorinative cyclization of the resultant azine. The widely available sodium trifluoromethanesulfinate is used as a precursor of CF3 radicals, while graphitic carbon nitride (g-C3N4) is employed as an environmentally friendly, cheap, and efficient heterogeneous photocatalyst. The structure of the synthesized compound was established by 1H, 13C, 19F-NMR, IR spectroscopy, and mass-spectrometry.
Three-Dimensional-Printed Molds from Water-Soluble Sulfate Ceramics for Biocomposite Formation through Low-Pressure Injection Molding
Authors: Golubchikov Daniil , Evdokimov Pavel , Zuev Dmitry , Filippov Yaroslav , Shatalova Tatiana , Putlayev Valery
Published: April 2023

Powder mixtures of MgSO4 with 5–20 mol.% Na2SO4 or K2SO4 were used as precursors for making water-soluble ceramic molds to create thermoplastic polymer/calcium phosphate composites by low pressure injection molding. To increase the strength of the ceramic molds, 5 wt.% of tetragonal ZrO2 (Y2O3-stabilized) was added to the precursor powders. A uniform distribution of ZrO2 particles was obtained. The average grain size for Na-containing ceramics ranged from 3.5 ± 0.8 µm for MgSO4/Na2SO4 = 91/9% to 4.8 ± 1.1 µm for MgSO4/Na2SO4 = 83/17%. For K-containing ceramics, the values were 3.5 ± 0.8 µm for all of the samples. The addition of ZrO2 made a significant contribution to the strength of ceramics: for the MgSO4/Na2SO4 = 83/17% sample, the compressive strength increased by 49% (up to 6.7 ± 1.3 MPa), and for the stronger MgSO4/K2SO4 = 83/17% by 39% (up to 8.4 ± 0.6 MPa). The average dissolution time of the ceramic molds in water did not exceed 25 min.
An Ultra-Thin, Microwave-Absorbing Wear Layer for Pavement Deicing
Authors: Liu Xiaoming , Chang Fei , Zhao Yu
Published: April 2023

Microwave heating is widely employed in pavement deicing. However, it is difficult to improve the deicing efficiency because only a small part of the microwave energy is used and most of it is wasted. To improve the utilization efficiency of microwave energy and the deicing efficiency, we used silicon carbide (SiC)–replaced aggregates in asphalt mixtures to prepare an ultra-thin, microwave-absorbing wear layer (UML). The SiC particle size, SiC content, oil–stone ratio and thickness of the UML were determined. The effect of the UML on energy saving and material reduction was also evaluated. Results show that only a 10 mm UML was needed to melt a 2 mm ice layer within 52 s at −20 °C and rated power. In addition, the minimum layer thickness to meet the specification requirement (≥2000 με) of asphalt pavement was also 10 mm. SiC with larger particle sizes increased the temperature rise rate but decreased the temperature uniformity, instead increasing the deicing time. The deicing time of a UML with SiC particle size less than 2.36 mm was 35 s shorter than that of a UML with SiC particle size greater than 2.36 mm. Furthermore, more SiC content in the UML resulted in a higher temperature rise rate and less deicing time. The temperature rise rate and deicing time of the UML with 20% SiC were 4.4 times and 44% of those of the control group. When the target void ratio was 6%, the optimum oil–stone ratio of UML was 7.4%, and it had good road performance. Compared to overall heating, the UML saved 75% of power and SiC material under the same heating efficiency. Therefore, the UML reduces microwave deicing time and saves energy and material.
Infrared Imaging Analysis of Green Composite Materials during Inline Quasi-Static Flexural Test: Monitoring by Passive and Active Approaches
Authors: Rippa Massimo , Pagliarulo Vito , Napolitano Francesco , Valente Teodoro , Russo Pietro
Published: April 2023

Composite materials have been used for many years in a wide variety of sectors starting from aerospace and nautical up to more commonly used uses such as bicycles, glasses, and so on. The characteristics that have made these materials popular are mainly their low weight, resistance to fatigue, and corrosion. In contrast to the advantages, however, it should be noted that the manufacturing processes of composite materials are not eco-friendly, and their disposal is rather difficult. For these reasons, in recent decades, the use of natural fibers has gained increasing attention, allowing the development of new materials sharing the same advantages with conventional composite systems while respecting the environment. In this work, the behavior of totally eco-friendly composite materials during flexural tests has been studied through infrared (IR) analysis. IR imaging is a well-known non-contact technique and represents a reliable means of providing low-cost in situ analysis. According to this method, the surface of the sample under investigation is monitored, under natural conditions or after heating, by recording thermal images with an appropriate IR camera. Here, the results achieved for jute- and basalt-based eco-friendly composites through the use of both passive and active IR imaging approaches are reported and discussed, showing the possibilities of use also in an industrial environment.
Principles and Applications of Resonance Energy Transfer Involving Noble Metallic Nanoparticles
Authors: He Zhicong , Li Fang , Zuo Pei , Tian Hong
Published: April 2023

Over the past several years, resonance energy transfer involving noble metallic nanoparticles has received considerable attention. The aim of this review is to cover advances in resonance energy transfer, widely exploited in biological structures and dynamics. Due to the presence of surface plasmons, strong surface plasmon resonance absorption and local electric field enhancement are generated near noble metallic nanoparticles, and the resulting energy transfer shows potential applications in microlasers, quantum information storage devices and micro-/nanoprocessing. In this review, we present the basic principle of the characteristics of noble metallic nanoparticles, as well as the representative progress in resonance energy transfer involving noble metallic nanoparticles, such as fluorescence resonance energy transfer, nanometal surface energy transfer, plasmon-induced resonance energy transfer, metal-enhanced fluorescence, surface-enhanced Raman scattering and cascade energy transfer. We end this review with an outlook on the development and applications of the transfer process. This will offer theoretical guidance for further optical methods in distance distribution analysis and microscopic detection.
An Approach to the Automated Characterization of Out-of-Plane and In-Plane Local Defect Resonances
Authors: Zdziebko Paweł , Krzemiński Mateusz , Okoń Maciej , Loi Gabriela , Aymerich Francesco , Pieczonka Łukasz , Klepka Andrzej
Published: April 2023

The paper presents an approach to efficiently detect local defect resonances (LDRs) in solids with localized defects. The 3D scanning laser Doppler vibrometry (3D SLDV) technique is applied to acquire vibration responses on the surface of a test sample due to a broadband vibration excitation applied by a piezoceramic transducer and modal shaker. Based on the response signals and known excitation, the frequency characteristics for individual response points are determined. The proposed algorithm then processes these characteristics to extract both out-of-plane and in-plane LDRs. Identification is based on calculating the ratio between local vibration levels and the mean vibration level of the structure as a background. The proposed procedure is verified on simulated data obtained from finite element (FE) simulations and validated experimentally for an equivalent test scenario. The obtained results confirmed the effectiveness of the method in identifying in-plane and out-of-plane LDRs for both numerical and experimental data. The results of this study are important for damage detection techniques utilizing LDRs to enhance the efficiency of detection.
Carbonation of Alkali-Activated Materials: A Review
Authors: Lamaa Ghandy , Duarte António P. C. , Silva Rui Vasco , de Brito Jorge
Published: April 2023

This paper presents a literature review on the effects of accelerated carbonation on alkali-activated materials. It attempts to provide a greater understanding of the influence of CO2 curing on the chemical and physical properties of various types of alkali-activated binders used in pastes, mortars, and concrete. Several aspects related to changes in chemistry and mineralogy have been carefully identified and discussed, including depth of CO2 interaction, sequestration, reactions with calcium-based phases (e.g., calcium hydroxide and calcium silicate hydrates and calcium aluminosilicate hydrates), as well as other aspects related to the chemical composition of alkali-activated materials. Emphasis has also been given to physical alterations such as volumetric changes, density, porosity, and other microstructural properties caused by induced carbonation. Moreover, this paper reviews the influence of the accelerated carbonation curing method on the strength development of alkali-activated materials, which has been awarded little attention considering its potential. This curing technique was found to contribute to the strength development mainly through decalcification of the Ca phases existing in the alkali-activated precursor, leading to the formation of CaCO3, which leads to microstructural densification. Interestingly, this curing method seems to have much to offer in terms of mechanical performance, making it an attractive curing solution that can compensate for the loss in performance caused by less efficient alkali-activated binders replacing Portland cement. Optimising the application of such CO2-based curing methods for each of the potential alkali-activated binders is recommended for future studies for maximum microstructural improvement, and thus mechanical enhancement, to make some of the “low-performing binders” adequate Portland cement substitutes.
Analyze the Wear Mechanism of the Longwall Shearer Haulage System
Authors: Jaśkowiec Krzysztof , Pirowski Zenon , Głowacki Mirosław , Bisztyga-Szklarz Magdalena , Bitka Adam , Małysza Marcin , Wilk-Kołodziejczyk Dorota
Published: April 2023

The wear characteristics and related mechanisms of the Longwall Shearer Haulage System were investigated. Wear is one of the main reasons for failures and downtimes. This knowledge can help solve engineering problems. The research was carried out at a laboratory station and a test stand. The publication presents the results of tribological tests carried out in laboratory conditions. The aim research was to select the alloy intended for casting the toothed segments of the haulage system. The track wheel was made by the forging method using steel 20H2N4A. Haulage System was tested on the ground using a longwall shearer. Selected toothed segments were subjected to tests on this stand. The cooperation of the track wheel and toothed segments in the tootbar were analyzed by a 3D scanner. Debris chemical composition was also appointed, as well as mass loss of toothed segments. The developed solution toothed segment an increase in the service life of the track wheel in real conditions. The results of the research also contribute to reducing the operating costs of the mining process.
Effect of Copper Segregation at Low-Angle Grain Boundaries on the Mechanisms of Plastic Relaxation in Nanocrystalline Aluminum: An Atomistic Study
Authors: Krasnikov Vasiliy , Mayer Alexander , Bezborodova Polina , Gazizov Marat
Published: April 2023

The paper studies the mechanisms of plastic relaxation and mechanical response depending on the concentration of Cu atoms at grain boundaries (GBs) in nanocrystalline aluminum with molecular dynamics simulations. A nonmonotonic dependence of the critical resolved shear stress on the Cu content at GBs is shown. This nonmonotonic dependence is related to the change in plastic relaxation mechanisms at GBs. At a low Cu content, GBs slip as dislocation walls, whereas an increase in Cu content involves a dislocation emission from GBs and grain rotation with GB sliding.
Analysis of Degradation Products of Biodegradable ZnMgY Alloy
Authors: Panaghie Cătălin , Zegan Georgeta , Sodor Alina , Cimpoeșu Nicanor , Lohan Nicoleta-Monica , Istrate Bogdan , Roman Ana-Maria , Ioanid Nicoleta
Published: April 2023

Biodegradable metallic materials are increasingly gaining ground in medical applications. Zn-based alloys show a degradation rate between those recorded for Mg-based materials with the fastest degradation rate and Fe-based materials with the slowest degradation rate. From the perspective of medical complications, it is essential to understand the size and nature of the degradation products developed from biodegradable materials, as well as the stage at which these residues are eliminated from the body. This paper presents investigations conducted on the corrosion/degradation products of an experimental material (ZnMgY alloy in cast and homogenized state) after immersion tests in three physiological solutions (Dulbecco’s, Ringer’s and simulated body fluid (SBF)). Scanning electron microscopy (SEM) was used to highlight the macroscopic and microscopic aspects of corrosion products and their effects on the surface. An X-ray energy dispersive detector (EDS), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) provided general information about the compounds based on their non-metallic character. The pH of the electrolyte solution was recorded for 72 h during immersion. The pH variation of the solution confirmed the main reactions proposed for the corrosion of ZnMg. The agglomerations of corrosion products were on the micrometer scale, mainly oxides, hydroxides and carbonates or phosphates. The corrosion effects on the surface were homogeneously spread, with a tendency to connect and form cracks or larger corrosion zones, transforming the pitting corrosion pattern into a generalized one. It was noticed that the alloy’s microstructure strongly influences the corrosion characteristics.
A Novel Functionalized MoS2-Based Coating for Efficient Solar Desalination
Authors: Yu Qinghong , Wang Qingmiao , Feng Tao , Wang Li , Fan Zhixuan
Published: April 2023

Molybdenum disulfide (MoS2) has emerged as a promising photothermal material for solar desalination. However, its limitation in integrating with organic substances constrains its application because of the lack of functional groups on its surface. Here, this work presents a functionalization approach to introduce three different functional groups (-COOH -OH -NH2) on the surface of MoS2 by combining them with S vacancies. Subsequently, the functionalized MoS2 was coated on the polyvinyl alcohol-modified polyurethane sponge to fabricate a MoS2-based double-layer evaporator through an organic bonding reaction. Photothermal desalination experiments show that the functionalized material has higher photothermal efficiency. The evaporation rate of the hydroxyl functionalized the MoS2 evaporator evaporation rate is 1.35 kg m−2 h−1, and the evaporation efficiency is 83% at one sun. This work provides a new strategy for efficient, green, and large-scale utilization of solar energy by MoS2-based evaporators.
Optimization of PVDF-TrFE Based Electro-Conductive Nanofibers: Morphology and In Vitro Response
Authors: Serrano-Garcia William , Cruz-Maya Iriczalli , Melendez-Zambrana Anamaris , Ramos-Colon Idalia , Pinto Nicholas J. , Thomas Sylvia W. , Guarino Vincenzo
Published: April 2023

In this study, morphology and in vitro response of electroconductive composite nanofibers were explored for biomedical use. The composite nanofibers were prepared by blending the piezoelectric polymer poly(vinylidene fluoride–trifluorethylene) (PVDF-TrFE) and electroconductive materials with different physical and chemical properties such as copper oxide (CuO), poly(3-hexylthiophene) (P3HT), copper phthalocyanine (CuPc), and methylene blue (MB) resulting in unique combinations of electrical conductivity, biocompatibility, and other desirable properties. Morphological investigation via SEM analysis has remarked some differences in fiber size as a function of the electroconductive phase used, with a reduction of fiber diameters for the composite fibers of 12.43% for CuO, 32.87% for CuPc, 36.46% for P3HT, and 63% for MB. This effect is related to the peculiar electroconductive behavior of fibers: measurements of electrical properties showed the highest ability to transport charges of methylene blue, in accordance with the lowest fibers diameters, while P3HT poorly conducts in air but improves charge transfer during the fiber formation. In vitro assays showed a tunable response of fibers in terms of viability, underlining a preferential interaction of fibroblast cells to P3HT-loaded fibers that can be considered the most suitable for use in biomedical applications. These results provide valuable information for future studies to be addressed at optimizing the properties of composite nanofibers for potential applications in bioengineering and bioelectronics.