MODIFICATION OF CERAMIC MEMBRANES BY PYROCARBON FROM CARBONIZED POLY(URETHANE UREA)S
Authors:   Dumanskii Institute of Colloid Chemistry and the Chemistry of Water of NAS of Ukraine, 42, Akademik Vernadsky boulevard, Kyiv, 03142, Ukraine, GONCHARUK V.V. , OGENKO V.M. ,   Vernadsky Institute of General and Inorganic Chemistry of NAS of Ukraine, 32/34, Akademik Palladin avenue, Kyiv, 03680, Ukraine, DUBROVINA L.V. ,   Vernadsky Institute of General and Inorganic Chemistry of NAS of Ukraine, 32/34, Akademik Palladin avenue, Kyiv, 03680, Ukraine,   Dumanskii Institute of Colloid Chemistry and the Chemistry of Water of NAS of Ukraine, 42, Akademik Vernadsky boulevard, Kyiv, 03142, Ukraine, VYSHNEVSKYI O.A. ,   Semenenko Institute of Geochemistry, Mineralogy and Ore Formation of NAS of Ukraine, 34, Akademik Palladin avenue, Kyiv, 03142, Ukraine, DUBROVIN I.V. ,   Chuiko Institute of Surface Chemistry of the National Academy of NAS of Ukraine, 17, General Naumov Str., Kyiv, 03164, Ukraine, KRUCHKO I.M. ,   Dumanskii Institute of Colloid Chemistry and the Chemistry of Water of NAS of Ukraine, 42, Akademik Vernadsky boulevard, Kyiv, 03142, Ukraine
Published: October 2022

Modification of tubular ceramic membranes made of clay minerals, which were obtained by slip casting (produced by the Dumansky Institute of Colloid Chemistry and Water Chemistry of the National Academy of Sciences of Ukraine) was carried out. The membranes were modified with pyrocarbon, which was obtained by carbonization of a precursor – poly(urethane urea)s. The carbonization precursor was synthesized from polyisocyanate (average functionality 2.7) and laprol grade 5003, which was introduced into the membrane by impregnation of the corresponding solutions in ethylacetate. When laprol reacts with polyisocyanate, three-dimensional polyurethane is formed. Since undried reagents were used, water entered the pores of the membrane, which reacted with the NCO groups of the polyisocyanate to form polyurea. The parallel course of these reactions leads to the formation of poly(urethane urea)s in the pores of the membrane. Carbonization was carried at 800 °C in an argon flow. The apparent density and open porosity of the membranes were determined by CCl4 uptake. After modification, the open porosity of the membrane decreased from 29.9 to 27.3 %, the apparent density increased from 1.86 to 1.87 g/cm3. The composition and structure of the membranes were studied by X-ray diffraction analysis and SEM. It is shown that the obtained modifier is pyrocarbon - the relative intensity of reflexes increases at 26,0 - 26,4 and 41,3 and 44,2° 2Θ. Pyrocarbon covers the surface of the pores with a continuous layer, and there are also three-dimensional formations of various shapes and sizes from several nm to several microns. Testing of modified membranes was carried out by water purification from direct scarlet dye and from Ca2+ of calcium chloride using the baromembrane method at a working pressure of 0.7 MPa. The unmodified membrane does not retain direct scarlet dye and Ca2+ at all. Tests of modified membranes have shown that the membranes acquire ultrafiltration properties. The retention factor (R) for direct scarlet dye is 100 % and 25 % for Ca2+.