bluuebunny/crossref_metadata_2025 huggingface dataset:
Investigating the Impact of Robotic Milling Parameters on the Surface Roughness of Al-Alloy Fabricated by Wire Arc Additive Manufacturing
Authors: Yan Zhaoyang , Ren Xikang , Zhao Hongyan , Chen Shujun
Published: October 2024

This paper takes the single-wall wall manufactured by wire arc additive manufacturing (WAAM) as the research object and compares it with the as-cast aluminum alloy with the same series. By using feed rate, cutting depth, spindle speed, etc., as single or compound parameters, the machinability of the sample is analyzed. The results indicate that the influence of varying parameters on the as-deposited aluminum alloy follows the order of feed rate > cutting depth > spindle speed. As the feed rate increases, the surface roughness initially decreases and then increases, with the optimal surface quality achieved at 12 mm/s (with a surface roughness of 2.013 μm). Different from the as-deposited alloy, the influence of the parameters on the as-cast alloys follows the order of spindle speed > cutting depth > feed rate. The experiments reveal that, for both as-deposited and as-cast states, the trends of the impact of cutting depth and spindle speed on surface quality are consistent. However, at low feed rates (2–12 mm/s), for as-deposited states, the surface quality of as-deposited samples becomes smoother as the feed rate increases (contrary to common knowledge). This result can be attributed to the elevated milling temperature, which softens the material, making it easier to remove and reducing the surface roughness.
Galling-Free Dry Near-Net Forging of Titanium Using Massively Carbon-Supersaturated Tool Steel Dies
Authors: Aizawa Tatsuhiko , Kihara Takeshi , Shiratori Tomomi
Published: October 2024

Massively carbon-supersaturated (MCSed) tool steel dies were developed to make galling-free forging products from titanium bar feedstocks in dry conditions without lubricating oils. Two types of tool steel dies were used, SKD11 and ACD56, following the Japanese Industrial Standard (JIS). The plasma-immersion carburizing process was employed to induce massive carbon supersaturation in two kinds of tool steel dies at 673 K for 14.4 ks. A pure titanium bar was upset in a single stroke up to the reduction of thickness of 70% using the MCSed SKD11 die. Very few bulging displacements of the upset bar proved that μ = 0.05 on the contact surface of the MCSed SKD11 die to pure titanium work. Two continuous forging experiments were performed to demonstrate that an in situ lubrication mechanism played a role to prevent the contact surface from galling to titanium works in both laboratory- and industry-scaled forging processes. After precise microstructure analyses of the contact surface, the free-carbon film formed in situ acted as a lubricating tribofilm to reduce friction and adhesive wear in continuous forging processes. The MCSed ACD56 dies were also used to describe the galling-free forging behavior of manufacturing eyeglass frames and to evaluate the surface quality of the finished temples. The applied load was reduced by 30% when using the MCSed ACD56 dies. The average surface roughness of the forged product was also greatly reduced, from 4.12 μm to 0.99 μm, together with a reduction in roughness deviations. High qualification of forged products was preserved together with die life prolongation even in dry manufacturing conditions of the titanium and titanium alloys.
Functional Silsesquioxanes—Tailoring Hydrophobicity and Anti-Ice Properties of Polylactide in 3D Printing Applications
Authors: Konieczna Roksana , Przekop Robert E. , Pakuła Daria , Głowacka Julia , Ziętkowska Katarzyna , Kozera Rafał , Sztorch Bogna
Published: October 2024

To explore the tailoring of hydrophobicity in 3D-printed polylactide (PLA) composites for advanced applications using additive manufacturing (AM), this study focuses on the use of Fused Deposition Modeling (FDM) 3D printing. PLA, a material derived from renewable sources, is favored for its eco-friendliness and user accessibility. Nonetheless, PLA’s inherent hydrophilic properties result in moisture absorption, negatively affecting its performance. This research aims to modify PLA with organosilicon compounds to enhance its hydrophobic and anti-icing properties. Incorporating fluorinated siloxane derivatives led to significant increases in water contact angles by up to 39%, signifying successful hydrophobic modification. Mechanical testing demonstrated that the addition of organosilicon additives did not compromise the tensile strength of PLA and, in some instances, improved impact resistance, especially with the use of OSS-4OFP:2HEX:2TMOS, which resulted in an increase in the tensile strength value of 25% and increased impact strength by 20% compared to neat PLA. Differential scanning calorimetry (DSC) analysis indicated that the modified PLA exhibited reduced cold crystallization temperatures without altering the glass transition or melting temperatures. These results suggest that organosilicon-modified PLA has the potential to expand the material’s application in producing moisture and ice-resistant 3D-printed prototypes for various industrial uses, thereby facilitating the creation of more durable and versatile 3D-printed components.
Eco-Design of Thermopressing through Induction of 100% Coriander-Based Fiberboards: Optimization of Molding Conditions
Authors: Guaygua-Amaguaña Priscila , Vaca-Medina Guadalupe , Vialle Claire , Sablayrolles Caroline , Evon Philippe
Published: October 2024

The hot pressing process for 100% coriander-based fiberboards was optimized using an induction RocTool system, which offers rapid mold heating and cooling. The fiberboards were made using deoiled press cake as a protein binder and extrusion-refined straw as reinforcement. Doehlert’s experimental design was used to evaluate the influence of pressure (10–50 MPa), molding time (60–300 s), and mold temperature (155–205 °C) on fiberboard properties, energy consumption, cost, and environmental impact. The results showed that the RocTool device allows for better temperature control during shaping throughout the mold, resulting in mechanical properties that are both more homogeneous across the entire surface of the panel and, more importantly, substantially improved. Using the isoresponse curves, the optimal hot pressing conditions were 35 MPa, 300 s, and 205 °C, corresponding to a 40.6 MPa flexural strength. However, it was observed that to achieve an MDF-like fiberboard with minimal production costs, much less restrictive molding conditions were sufficient, i.e., 32.5 MPa, 170 s, and 160 °C. The study revealed that maximum thermopressing conditions emitted 3.87 kg of CO2 eq., while conditions leading to the MDF-like board reduced emissions to 1.45 kg CO2 eq., resulting in a more environmentally friendly material.
Resilient Reinforcement Learning for Voltage Control in an Islanded DC Microgrid Integrating Data-Driven Piezoelectric
Authors: Sheida Kouhyar , Seyedi Mohammad , Afridi Muhammad Ali , Ferdowsi Farzad , Khattak Mohammad J. , Gopu Vijaya K. , Rupnow Tyson
Published: October 2024

This research study presents a resilient control scheme for an islanded DC microgrid (DC MG) integrating solar photovoltaic (PV), battery storage (BESS), and piezoelectric (PE) energy harvesting modules. The microgrid (MG) case study represents an energy hub designed to provide electricity for lighting systems in transportation, roads, and other infrastructure. To enhance practicality, the PE is modeled using the real data captured from a traffic simulator. The proposed reinforcement learning (RL) method was tested against four severe and unexpected failure scenarios, including short circuit at the load side, sudden and severe change of load, open circuit, and converter failure. The performance of the controller was quantitatively compared with a conventional PI controller. The results show marginal improvement in one scenario and significant improvement in the other three, suggesting that the proposed scheme is a robust candidate for microgrids with high levels of uncertainty, such as those involving solar and PE harvesters.
Optimizing Magnetic Separation and Cleaning Module in Fully Automated Chemiluminescence Immunoassay Analyzer Using a Special Arrangement of Spliced Magnets and a Three-Stage Magnetic Bead Collection Method
Authors: Lyu Chuan , Jiang Yu , Dai Zhen , Xu Xu , Cai Yu , Liang Bo , Zhou Congcong , Ye Xuesong , Wang Jing
Published: October 2024

The magnetic separation and cleaning module, as a core component of the fully automated chemiluminescence immunoassay (CLIA) analyzer, encounters issues including high magnetic bead loss rate, long cleaning time, and poor cleaning effect. Based on a simulation analysis using COMSOL, we proposed a novel magnetic separation and cleaning module applied to a fully automated CLIA analyzer. The module adopted a method of arranging spliced rectangular magnets on opposite sides, where the same polarity faced each other, as well as a three-stage magnetic bead collection method. With the proposed method, the total cleaning process can be accomplished within 225 s; the total magnetic bead loss rate over three rounds of cleaning is 6.03%, whereas that of traditional instruments is 25.85%; the coefficient of variation (CV) of the magnetic bead loss rate is less than 0.5%; effective cleaning of free markers is achieved under various sample conditions. Compared with traditional CLIA instruments, this method comprehensively improves key performance indicators of the magnetic separation and cleaning module, providing a reference for similar modules in fully automated CLIA analyzers and positively impacting the accuracy of CLIA for the detection of disease biomarkers.
Exploring the Physicochemical Characteristics of Marine Protein Hydrolysates and the Impact of In Vitro Gastrointestinal Digestion on Their Bioactivity
Authors: Sharma Deepanshi , Gite Snehal , Tuohy Maria G.
Published: October 2024

Fish protein hydrolysates (FPHs) were obtained from different fish sources using a combination of microbial enzymes. The industrially produced FPHs from blue whiting (Micromesistius poutassou) and sprat (Sprattus sprattus) were compared to freeze-dried FPHs generated in-house from hake (Merluccius merluccius) and mackerel (Scomber scombrus) in terms of their physicochemical composition and functionality. Significant differences (p < 0.05) were observed in the protein, moisture, and ash contents of the FPHs, with the majority having high levels of protein (73.24–89.31%). Fractions that were more extensively hydrolysed exhibited a high solubility index (74.05–98.99%) at different pHs. Blue whiting protein hydrolysate-B (BWPH-B) had the highest foaming capacity at pH 4 (146.98 ± 4.28%) and foam stability over 5 min (90–100%) at pH 4, 6, and 8. The emulsifying capacity ranged from 61.11–108.90 m2/g, while emulsion stability was 37.82–76.99% at 0.5% (w/v) concentration. In terms of peptide bioactivity, sprat protein hydrolysate (SPH) had the strongest overall reducing power. The highest Cu2+ chelating activity was exhibited by hake protein hydrolysate (HPH) and mackerel protein hydrolysate (MPH), with IC50 values of 0.66 and 0.78 mg protein/mL, respectively, while blue whiting protein hydrolysate-A (BWPH-A) had the highest activity against Fe2+ (IC50 = 1.89 mg protein/mL). SPH scavenged DPPH and ABTS radicals best with IC50 values of 0.73 and 2.76 mg protein/mL, respectively. All FPHs displayed noteworthy scavenging activity against hydroxyl radicals, with IC50 values ranging from 0.48–3.46 mg protein/mL. SPH and MPH showed the highest scavenging potential against superoxide radicals with IC50 values of 1.75 and 2.53 mg protein/mL and against hydrogen peroxide with 2.22 and 3.66 mg protein/mL, respectively. While inhibition of α-glucosidase was not observed, the IC50 values against α-amylase ranged from 8.81–18.42 mg protein/mL, with SPH displaying the highest activity. The stability of FPHs following simulated gastrointestinal digestion (SGID) showed an irregular trend. Overall, the findings suggest that marine-derived protein hydrolysates may serve as good sources of natural nutraceuticals with antioxidant and antidiabetic properties.
Novel, Fluorine-Free Membranes Based on Sulfonated Polyvinyl Alcohol and Poly(ether-block-amide) with Sulfonated Montmorillonite Nanofiller for PEMFC Applications
Authors: Al-Mashhadani Manhal H. Ibrahim , Szijjártó Gábor Pál , Sebestyén Zoltán , Károly Zoltán , Mihály Judith , Tompos András
Published: October 2024

Novel blend membranes containing S-PVA and PEBAX 1657 with a blend ratio of 8:2 (referred to as SPP) were prepared using a solution-casting technique. In the manufacturing process, sulfonated montmorillonite (S-MMT) in ratios of 0%, 3%, 5%, and 7% was used as a filler. The crystallinity of composite membranes has been investigated by X-ray diffraction (XRD), while the interaction between the components was evaluated using Fourier-transform infrared spectroscopy (FT-IR). With increasing filler content, good compatibility between the components due to hydrogen bonds was established, which ultimately resulted in improved tensile strength and chemical stability. In addition, due to the sulfonated moieties of S-MMT, the highest ion exchange capacity (0.46 meq/g) and water uptake (51.61%) can be achieved at the highest filler content with an acceptable swelling degree of 22.65%. The composite membrane with 7% S-MMT appears to be suitable for application in proton exchange membrane fuel cells (PEMFCs). Amongst the membranes studied, this membrane achieved the highest current density and power density in fuel cell tests, which were 149.5 mA/cm2 and 49.51 mW/cm2. Our fluorine-free composite membranes can become a promising new membrane family in PEMFC applications, offering an alternative to Nafion membranes.
Chemistry and Physics of Wet Foam Stability for Porous Ceramics: A Review
Authors: Fatema Kamrun Nahar , Biswas Md Rokon Ud Dowla , Park Jung Gyu , Kim Ik Jin
Published: October 2024

The unique structural properties of porous ceramics, such as low thermal conductivity, high surface area, controlled permeability, and low density, make this material valuable for a wide range of applications. Its uses include insulation, catalyst carriers, filters, bio-scaffolds for tissue engineering, and composite manufacturing. However, existing processing methods for porous ceramics, namely replica techniques and sacrificial templates, are complex, release harmful gases, have limited microstructure control, and are expensive. In contrast, the direct foaming method offers a simple and cost-effective approach. By modifying the surface chemistry of ceramic particles in a colloidal suspension, the hydrophilic particles are transformed into hydrophobic ones using surfactants. This method produces porous ceramics with interconnected pores, creating a hierarchical structure that is suitable for applications like nano-filters. This review emphasizes the importance of interconnected porosity in developing advanced ceramic materials with tailored properties for various applications. Interconnected pores play a vital role in facilitating mass transport, improving mechanical properties, and enabling fluid or gas infiltration. This level of porosity control allows for the customization of ceramic materials for specific purposes, including filtration, catalysis, energy storage, and biomaterials.
Composite Granitic Plutonism in the Southern Part of the Wadi Hodein Shear Zone, South Eastern Desert, Egypt: Implications for Neoproterozoic Dioritic and Highly Evolved Magma Mingling during Volcanic Arc Assembly
Authors: Abdelfadil Khaled M. , Mansour Sherif , Asran Asran M. , Younis Mohammed H. , Lentz David R. , Fowler Abdel-Rahman , Fnais Mohammed S. , Abdelrahman Kamal , Radwan Abdelhady
Published: October 2024

The Abu Farayed Granite (AFG), located in the southeastern desert of Egypt, was intruded during the early to late stages of Pan-African orogeny that prevailed within the Arabian–Nubian Shield. The AFG intrudes an association of gneisses, island arc volcano–sedimentary rocks, and serpentinite masses. Field observations, supported by remote sensing and geochemical data, reveal a composite granitic intrusion that is differentiated into two magmatic phases. The early granitic phase comprises weakly deformed subduction-related calc–alkaline rocks ranging from diorite to tonalite, while the later encloses undeformed granodiorite and granite. Landsat-8 (OLI) remote sensing data have shown to be highly effective in discriminating among the different varieties of granites present in the area. Furthermore, the data have provided important insights into the structural characteristics of the AFG region. Specifically, the data indicate the presence of major tectonic trends with ENE–WSW and NW–SE directions transecting the AFG area. Geochemically, the AFG generally has a calc–alkaline metaluminous affinity with relatively high values of Cs, Rb, K, Sr, Nd, and Hf but low contents of Nb, Ta, P, and Y. The early magmatic phase has lower alkalis and REEs, while the later phases have higher alkalis and REEs with distinctly negative Eu anomalies. The AFG is structurally controlled, forming a N–S arch, which may be due to the influence of the wadi Hodein major shear zone. The diorite and tonalite are believed to have been originally derived from subduction-related magmatism during regional compression. This began with the dehydration of the descending oceanic crust with differential melting of the metasomatized mantle wedge. Magma ascent was long enough to react with the thickened crust and therefore suffered fractional crystallization and assimilation (AFC) to produce the calc–alkaline diorite–tonalite association. The granodiorite and granites were produced due to partial melting, assimilation, and fractionation of lower crustal rocks (mainly diorite–tonalite of the early stage) after subduction and arc volcanism during a late orogenic relaxation–rebound event associated with uplift transitioning to extension.
Mixed Systems of Quaternary Ammonium Foam Drainage Agent with Carbon Quantum Dots and Silica Nanoparticles for Improved Gas Field Performance
Authors: Sun Yongqiang , Zhang Yongping , Wei Anqi , Shan Xin , Liu Qingwang , Fan Zhenzhong , Sun Ao , Zhu Lin , Kong Lingjin
Published: October 2024

Foam drainage agents enhance gas production by removing wellbore liquids. However, due to the ultra-high salinity environments of the Hechuan gas field (salinity up to 32.5 × 104 mg/L), no foam drainage agent is suitable for this gas field. To address this challenge, we developed a novel nanocomposite foam drainage system composed of quaternary ammonium and two types of nanoparticles. This work describes the design and synthesis of a quaternary ammonium foam drainage agent and nano-engineered stabilizers. Nonylphenol polyoxyethylene ether sulfosuccinate quaternary ammonium foam drainage agent was synthesized using maleic anhydride, sodium chloroacetate, N,N-dimethylpropylenediamine, etc., as precursors. We employed the Stöber method to create hydrophobic silica nanoparticles. Carbon quantum dots were then prepared and functionalized with dodecylamine. Finally, carbon quantum dots were incorporated into the mesopores of silica nanoparticles to enhance stability. Through optimization, the best performance was achieved with a (quaternary ammonium foam drainage agents)–(carbon quantum dots/silica nanoparticles) ratio of 5:1 and a total dosage of 1.1%. Under harsh conditions (salinity 35 × 104 mg/L, condensate oil 250 cm3/m3, temperature 80 °C), the system exhibited excellent stability with an initial foam height of 160 mm, remaining at 110 mm after 5 min. Additionally, it displayed good liquid-carrying capacity (160 mL), low surface tension (27.91 mN/m), and a long half-life (659 s). These results suggest the effectiveness of nanoparticle-enhanced foam drainage systems in overcoming high-salinity challenges. Previous foam drainage agents typically exhibited a salinity resistance of no more than 25 × 104 mg/L. In contrast, this innovative system demonstrates a superior salinity tolerance of up to 35 × 104 mg/L, addressing a significant gap in available agents for high-salinity gas fields. This paves the way for future development of advanced foam systems for gas well applications with high salinity.
Effect of Personalized Prebiotic and Probiotic Supplements on the Symptoms of Irritable Bowel Syndrome: An Open-Label, Single-Arm, Multicenter Clinical Trial
Authors: Matsuura Nozomi , Kanayama Masaya , Watanabe Yuta , Yamada Hirokazu , Lili Loukia , Torii Akira
Published: October 2024

Background/Objectives: Prebiotics and probiotics have been reported to improve symptoms of irritable bowel syndrome (IBS). Nevertheless, the effects of prebiotics/probiotics can vary depending on the IBS subtypes. The purpose of this study was to investigate the effects of personalized prebiotic and probiotic supplements based on intestinal microbiota and IBS subtypes in patients. Methods: Patients with diarrhea-type IBS (IBS-D), constipation-type IBS (IBS-C), and mixed-type IBS (IBS-M) were enrolled (n = 40 per group; total: n = 120). Personalized prebiotic and probiotic supplements were determined according to the IBS subtypes and intestinal microbiota. The patients received supplements for 4 weeks. The primary outcome was the change in the IBS-severity scoring system from baseline to week 4. Results:The IBS-severity scoring system significantly decreased in all patients (−38.0 [95% confidence interval (CI): −53.6, −22.4]; p < 0.001), in patients with IBS-D (−44.5 [95% CI: −70.6, −18.5]; p = 0.004) and IBS-C (−51.2 [95% CI: −79.4, −22.9]; p = 0.002), but not in those with IBS-M (−20.0 [95% CI: −48.0, 8.1]; p = 0.47). In this study, no serious adverse events were observed that had a causal relationship with the intervention. Conclusions: In conclusion, personalized prebiotic and probiotic supplements selected according to individual intestinal microbiota and IBS subtype may alleviate the severity of IBS symptoms, particularly in patients with IBS-C and IBS-D.
The Role of Nutrition in Maintaining the Health and Physical Condition of Sports Volunteers
Authors: Rozmiarek Mateusz
Published: October 2024

Nutrition plays a key role in maintaining health and physical condition, particularly for active individuals, including athletes. It can therefore be assumed that individuals performing physically demanding tasks during the organization of sporting events, such as volunteers, should also pay attention to their nutrition. While the importance of diet for athletes has been widely studied, the impact of nutrition on sports volunteers remains under-researched. Volunteers often have to cope with varying degrees of physical and mental exertion, which may affect their nutritional needs. A qualitative study was conducted using in-depth individual interviews (IDIs) with 17 sports volunteers who had experience in organizing various sporting events. Participants were purposefully selected based on specific inclusion criteria, which included active involvement in sports volunteering (with a minimum of two years of experience in volunteer activities) as well as volunteering experience at sports events of various scales. The interviews aimed to understand the eating habits, dietary awareness, and impact of nutrition on health and physical fitness. The data were transcribed and subjected to thematic analysis, focusing on coding responses and identifying recurring themes. Most participants did not place much importance on their diet, making random food choices due to a busy lifestyle and lack of time. Only a few volunteers consciously adjusted their diet when they had knowledge of the physically demanding tasks they were expected to perform during their volunteer work. The majority of volunteers relied on less reliable sources of nutritional information, such as blogs or social media, rather than credible sources of knowledge. This study revealed that many individuals involved in sports volunteering are unaware of the impact of diet on their fitness and health. There is a need for nutritional education for this group to improve their awareness of the importance of a balanced diet in the context of increased physical activity. It is also advisable to provide better nutritional conditions during sporting events and to promote the use of professional sources of information about healthy eating.
Investigation of Sonication Parameters for Large-Volume Focused Ultrasound-Mediated Blood–Brain Barrier Permeability Enhancement Using a Clinical-Prototype Hemispherical Phased Array
Authors: McMahon Dallan , Jones Ryan M. , Ramdoyal Rohan , Zhuang Joey Ying Xuan , Leavitt Dallas , Hynynen Kullervo
Published: October 2024

Background/Objectives: Focused ultrasound (FUS) and microbubble (MB) exposure is a promising technique for targeted drug delivery to the brain; however, refinement of protocols suitable for large-volume treatments in a clinical setting remains underexplored. Methods: Here, the impacts of various sonication parameters on blood–brain barrier (BBB) permeability enhancement and tissue damage were explored in rabbits using a clinical-prototype hemispherical phased array developed in-house, with real-time 3D MB cavitation imaging for exposure calibration. Initial experiments revealed that continuous manual agitation of MBs during infusion resulted in greater gadolinium (Gd) extravasation compared to gravity drip infusion. Subsequent experiments used low-dose MB infusion with continuous agitation and a low burst repetition frequency (0.2 Hz) to mimic conditions amenable to long-duration clinical treatments. Results: Key sonication parameters—target level (proportional to peak negative pressure), number of bursts, and burst length—significantly affected BBB permeability enhancement, with all parameters displaying a positive relationship with relative Gd contrast enhancement (p < 0.01). Even at high levels of BBB permeability enhancement, tissue damage was minimal, with low occurrences of hypointensities on T2*-weighted MRI. When accounting for relative Gd contrast enhancement, burst length had a significant impact on red blood cell extravasation detected in histological sections, with 1 ms bursts producing significantly greater levels compared to 10 ms bursts (p = 0.03), potentially due to the higher pressure levels required to generate equal levels of BBB permeability enhancement. Additionally, albumin and IgG extravasation correlated strongly with relative Gd contrast enhancement across sonication parameters, suggesting that protein extravasation can be predicted from non-invasive imaging. Conclusions: These findings contribute to the development of safer and more effective clinical protocols for FUS + MB exposure, potentially improving the efficacy of the approach.
Isolation and Structural Characterization of Natural Deep Eutectic Solvent Lignin from Brewer’s Spent Grains
Authors: Antoun Karina , Tabib Malak , Salameh Sarah Joe , Koubaa Mohamed , Ziegler-Devin Isabelle , Brosse Nicolas , Khelfa Anissa
Published: October 2024

Brewer’s spent grains (BSG) offer valuable opportunities for valorization beyond its conventional use as animal feed. Among its components, lignin—a natural polymer with inherent antioxidant properties—holds significant industrial potential. This work investigates the use of microwave-assisted extraction combined with acidic natural deep eutectic solvents (NaDESs) for efficient lignin recovery, evaluating three different NaDES formulations. The results indicate that choline chloride–lactic acid (ChCl-LA), a NaDES with superior thermal stability as confirmed via thermogravimetric analysis (TGA), is an ideal solvent for lignin extraction at 150 °C and 15 min, achieving a balance of high yield and quality. ChCl-LA also demonstrated good solubility and cell disruption capabilities, while microwaves significantly reduced processing time and severity. Under optimal conditions, i.e., 150 °C, 15 min, in the presence of ChCl-LA NaDES, the extracted lignin achieved a purity of up to 79% and demonstrated an IC50 (inhibitory concentration 50%) of approximately 0.022 mg/L, indicating a relatively strong antioxidant activity. Fourier transform infrared (FTIR) and 2D-HSQC NMR (heteronuclear single quantum coherence nuclear magnetic resonance) spectroscopy confirmed the successful isolation and preservation of its structural integrity. This study highlights the potential of BSG as a valuable lignocellulosic resource and underscores the effectiveness of acidic NaDESs combined with microwave extraction for lignin recovery.
Investigation on Erosion Resistance in Polyester–Jute Composites with Red Mud Particulate: Impact of Fibre Treatment and Particulate Addition
Authors: Rajendran Sundarakannan , Shanmugam Vigneshwaran , Palani Geetha , Marimuthu Uthayakumar , Veerasimman Arumugaprabu , Korniejenko Kinga , Oliinyk Inna , Trilaksana Herri , Sundaram Vickram
Published: October 2024

This research investigates the manufacturing and characterisation of polyester-based composites reinforced with jute fibres and red mud particulates. The motivation stems from the need for sustainable, high-performance materials for applications in industries, like aerospace and automotive, where resistance to erosion is critical. Jute, a renewable fibre, combined with red mud, an industrial byproduct, offers an eco-friendly alternative to conventional composites. The composites were fabricated using compression moulding with varying red mud contents (10, 20, and 30 wt.%) and a fixed 40 wt.% of jute fibre. Fibre treatments included sodium hydroxide (NaOH) and silane treatments to improve bonding and performance. Erosion tests were performed using an air-jet erosion tester, examining the effects of the red mud content, fibre treatment, and impact angles. Scanning Electron Microscope (SEM) analysis provided insights into the erosion mechanisms. A distinctive reduction in erosion rates at higher impact angles (30°–60°) was observed, attributed to the semi-ductile nature of the composites. The addition of red mud enhanced erosion resistance, although an excess of 30 wt.% reduced resistance due to poor surface bonding. Silane-treated composites showed the lowest erosion rates. This study provides new insights into the interplay among material composition, fibre treatment, and erosion dynamics, contributing to the development of optimised, eco-friendly composite materials.
Study on the Accumulation Model of the Cretaceous Reservoir in AHDEB Oilfield, Iraq
Authors: Wang Qiang , Wen Tao , Li Bo , Xin Jun , Tian Meng , Wu Baiyi
Published: October 2024

The Ahdeb oil field is located in the southwestern part of the Zagros fold deformation zone. The study of the model of the formation of the oil reservoir in this field will be helpful to deepen the pattern of hydrocarbon distribution in this zone. In this paper, we use the seismic data of the Ahdeb oil field to recover the tectonic evolution history of the field. Under neotectonic movement, the oil field formed in the early stage, migrated to the high point in the late stage, and finally entered the present formation. From here, for the oil-bearing inclusions within the reservoir, the photometric absorption values of the organic matter groups were measured by infrared spectroscopy. Their ratios were used to evaluate the maturity, thus discovering two phases of oil charging. Finally, using the hydrocarbon generation history and tectonic evolution history, combined with the oil and gas transportation periods in the reservoir, we deduce that the reservoir formation mode in the area is a two-phase gathering and final adjustment formation mode. This understanding of the hydrocarbon formation patterns will promote oil and gas exploration in this zone.
The Influence of Filler Particle Size on the Strength Properties and Mechanical Energy Dissipation Capacity of Biopoly(Ethylene Terephthalate) BioPET/Eggshell Biocomposites
Authors: Kuciel Stanisław , Rusin-Żurek Karina , Kurańska Maria
Published: October 2024

This work aims to evaluate how the particle size of a waste filler in the form of eggshells changes the mechanical properties of biopoly(ethylene terephthalate) (bioPET). BioPET was modified with three different waste fractions: 1.60–3 mm—large particles; 1.60–1 mm—medium particles; 1 mm–200 μm—small particles. Waste filler was added to the biopolymer matrix in the amount of 10 wt.%. Static tensile tests, as well as bending and impact tests, were carried out to assess the strength properties of the waste-enriched materials. Dissipation energy changes and relaxation processes were observed and evaluated by means of a low-cycle dynamic test. Waste particles were shown to be an effective modifier of bioPET by increasing its stiffness (all particle sizes) and strength (the smallest ones). Studies of the wetting angle and mechanical energy dissipation in the first hysteresis loops indicate the better adhesion of small particles to the biopolymer and their greater ability to dissipate mechanical energy.
A Strategic Framework for Establishing Additional In Situ Data Acquisition Sites for Satellite Data Calibration and Validation: A Case Study in South Korean Forests
Authors: Lee Cheolho , Seo Minji , Lim Joongbin
Published: October 2024

This study aims to evaluate the representativeness of Calibration/Validation (Cal/Val) sites for satellite data, develop a framework for establishing new Cal/Val sites, and propose a heterogeneity index to be applied within this framework, specifically focusing on South Korea. The proposed framework assesses the representativeness of existing Cal/Val sites, and, if found inadequate, provides a methodology for optimizing the location and number of additional Cal/Val sites, along with a prioritization strategy for their installation. Furthermore, the framework includes a methodology for evaluating the suitability of utilizing existing ground observation networks as additional Cal/Val sites and for prioritizing their use. The heterogeneity index is derived by synthesizing differences in geographic, climatic, vegetation, and spectral characteristics between the current Cal/Val sites and the broader regions. A higher heterogeneity index indicates significant divergence from existing Cal/Val sites across these factors, highlighting areas with a need for additional Cal/Val sites and a higher expected impact from their establishment. This index serves as a key tool within the framework to determine the optimal locations and number of new Cal/Val sites, as well as to evaluate the efficacy of utilizing existing ground observation networks. The framework was applied to South Korea, where the representativeness of the current eight Cal/Val sites was found to be insufficient. The optimal number of Cal/Val sites was determined to be 33, requiring the addition of 25 new sites in South Korea. The southeastern peninsula and surrounding islands were identified as priority regions for new installations. Additionally, the potential for utilizing the existing ground observation network was examined. Twenty-three Automatic Mountain Meteorology Observation System (AMOS) sites in South Korea were selected and compared with the optimized Cal/Val sites. The inclusion of these 23 AMOS sites was found to significantly improve representativeness, approaching the level of the optimized Cal/Val sites. This strategic deployment is expected to enhance the accuracy and reliability of remote sensing data, contributing to improved environmental monitoring and research in South Korea.
Modular and Portable System Design for 3D Imaging of Breast Tumors Using Electrical Impedance Tomography
Authors: Gómez Cortés Juan Carlos , Diaz Carmona José Javier , Barranco Gutiérrez Alejandro Israel , Padilla Medina José Alfredo , Alonso Ramírez Adán Antonio , Morales Viscaya Joel Artemio , Villegas-Saucillo J. Jesús , Prado Olivarez Juan
Published: October 2024

This paper presents a prototype of a portable and modular electrical impedance tomography (EIT) system for breast tumor detection. The proposed system uses MATLAB to generate three-dimensional representations of breast tissue. The modular architecture of the system allows for flexible customization and scalability. It consists of several interconnected modules. Each module can be easily replaced or upgraded, facilitating system maintenance and future enhancements. Testing of the prototype has shown promising results in preliminary screening based on experimental studies. Agar models were used for the experimental stage of this project. The 3D representations provide clinicians with valuable information for accurate diagnosis and treatment planning. Further research and refinement of the system is warranted to validate its performance in future clinical trials.
Challenges and Solutions for Leave-One-Out Biosensor Design in the Context of a Rugged Fitness Landscape
Authors: Banerjee Shounak , Fraser Keith , Crone Donna E. , Patel Jinal C. , Bondos Sarah E. , Bystroff Christopher
Published: October 2024

The leave-one-out (LOO) green fluorescent protein (GFP) approach to biosensor design combines computational protein design with split protein reconstitution. LOO-GFPs reversibly fold and gain fluorescence upon encountering the target peptide, which can be redefined by computational design of the LOO site. Such an approach can be used to create reusable biosensors for the early detection of emerging biological threats. Enlightening biophysical inferences for nine LOO-GFP biosensor libraries are presented, with target sequences from dengue, influenza, or HIV, replacing beta strands 7, 8, or 11. An initially low hit rate was traced to components of the energy function, manifesting in the over-rewarding of over-tight side chain packing. Also, screening by colony picking required a low library complexity, but designing a biosensor against a peptide of at least 12 residues requires a high-complexity library. This double-bind was solved using a “piecemeal” iterative design strategy. Also, designed LOO-GFPs fluoresced in the unbound state due to unwanted dimerization, but this was solved by fusing a fully functional prototype LOO-GFP to a fiber-forming protein, Drosophila ultrabithorax, creating a biosensor fiber. One influenza hemagglutinin biosensor is characterized here in detail, showing a shifted excitation/emission spectrum, a micromolar affinity for the target peptide, and an unexpected photo-switching ability.
Optimal Service Strategies of Online Platform Based on Purchase Behavior
Authors: Lin Xudong , Shi Tingyi , Luo Hanyang , Zhu Hao
Published: October 2024

In the rapidly evolving platform economy, online platforms have emerged as pivotal providers of digital services to sellers. The paper investigates how online platforms optimize service strategies based on consumers’ purchase behavior, influencing sellers’ pricing and social welfare. Using a two-period Hotelling model and a cooperative game framework, we discover that the optimal service strategies of a platform with data collecting capabilities are collaborating with two sellers to offer to extend services to new consumers in the second period, maximizing profits for all sellers and platform. Applying Shapley value analysis, we determine the platform’s equitable service charge strategies. When sellers adopt behavior-based pricing (BBP), the pricing escalates in the first period, and the platform’s optimal service strategies also enhance the pricing of sellers. However, in the second period, BBP intensifies competition, leading to generally lower pricing. Our findings suggest that optimal pricing in the second period for new consumers should increase with enhanced quality perception, which is provided by the platform’s digital services and heightened by consumers’ privacy concerns, while decreasing for regular consumers. Lastly, we offer policy recommendations, exploring optimal regulatory scenarios—limiting or not limiting data collection—to maximize social welfare or consumer surplus, and the Mathematica software is used to identify distinct optimal policy intervals.
Essential Quality Attributes of Culture Media Used as Substrates in the Sustainable Production of Pre-Basic Potato Seeds
Authors: Peña Haydee , Santos Mila , Ramírez Beatriz , Sulbarán José , Arias Karen , Huertas Victoria , Diánez Fernando
Published: October 2024

The sustainability of the primary sector is closely linked to meeting the demand for seeds using agro-industrial waste and bioresidues. Sustainability is a multidimensional concept focused on achieving environmental health, social justice, and economic viability. To this end, an experiment was designed based on a combination of biotechnological strategies accessible to many individuals. The first strategy involves the use of compost and vermicompost as cultivation substrates; the second is the in vitro acclimatization of potato plants to these substrates; and the third is the incorporation of Trichoderma asperellum into these substrates to determine the synergistic effect of both. The compost used in this work came from sewage sludge from an agri-food company (Cp); a dining room and pruning waste from a university campus (Cu); and vermicomposted coffee pulp waste (Cv). Each sample was mixed with coconut fiber (Fc) in proportions of 100, 75, 50, and 25%. In the resulting mixtures, María Bonita variety vitroplants were planted and placed in a greenhouse. The biometric response in the three cases indicated a dependence on the type of compost and the proportion of the coconut fiber mixture. The inoculation of Trichoderma asperellum with sewage sludge compost increased stem thickness (42.58%) and mini-tuber weight (6.74%). In contrast, uninoculated treatments showed the best performance in terms of the number of mini-tubers. A 50:50 mixture of sewage sludge compost with coconut fiber and without inoculation of Trichoderma asperellum was the best treatment for the production of pre-basic seeds of the María Bonita potato variety. The use of composted agricultural waste and bioresidues is shown as a valid and low-cost alternative for the sector, even independently of the incorporation of additional inoculants.
The Intelligent Upgrading of Logistics between an Internet Enterprise and a Logistics Enterprise Based on Differential Game Theory
Authors: Jiang Weidong , Li Naiwen
Published: October 2024

At the background of “Internet + Logistics”, intelligent logistics has high operational efficiency and provides a superior customer experience, meeting the requirements of sustainable development. It also plays a crucial role in promoting the modernization of the industrial chain in China. This paper develops a mathematic model based on differential game theory, which sets the intelligent level of logistics and the goodwill of intelligent logistics as state variables. The research reveals the collaborative strategies between a logistics enterprise and an Internet enterprise for the intelligent upgrading of logistics, and separately calculates the optimal effort levels and optimal revenues of participating enterprises under the non-cooperative mechanism, the cost-sharing mechanism, and the cooperative mechanism. This paper also observes the crucial parameters that affect the optimal revenue for the intelligent upgrading of logistics. The research findings are as follows: (1) Cost-sharing mechanism and cooperative mechanism can motivate the Internet enterprise and the logistics enterprise to improve their effort levels and increase the total revenue, which achieves the Pareto improvement. Under the cooperative mechanism, the intelligent level of logistics and the goodwill of intelligent logistics are the highest. (2) Participating enterprises can promote the intelligent upgrading of logistics by accumulating innovative resources for intelligent logistics, attaining cost-conversion efficiency, and cultivating customer preferences for intelligent logistics services. (3) When the revenue-sharing ratio of the logistics enterprise is relatively low, although the cost-sharing mechanism can continuously motivate a logistics enterprise to make an effort in the intelligent upgrading of logistics, it is not conducive to enhance the goodwill of intelligent logistics. This paper highlights the pivotal role of enterprise collaboration in the intelligent upgrading of logistics, and proposes practical recommendations.
An Improved NSGA-III with a Comprehensive Adaptive Penalty Scheme for Many-Objective Optimization
Authors: Xu Xinghang , Cheng Du , Wang Dan , Li Qingliang , Yu Fanhua
Published: October 2024

Pareto dominance-based algorithms face a significant challenge in handling many-objective optimization problems. As the number of objectives increases, the sharp rise in non-dominated individuals makes it challenging for the algorithm to differentiate their quality, resulting in a loss of selection pressure. The application of the penalty-based boundary intersection (PBI) method can balance convergence and diversity in algorithms. The PBI method guides the evolution of individuals by integrating the parallel and perpendicular distances between individuals and reference vectors, where the penalty factor is crucial for balancing these two distances and significantly affects algorithm performance. Therefore, a comprehensive adaptive penalty scheme was proposed and applied to NSGA-III, named caps-NSGA-III, to achieve balance and symmetry between convergence and diversity. Initially, each reference vector’s penalty factor is computed based on its own characteristic. Then, during the iteration process, the penalty factor is adaptively adjusted according to the evolutionary state of the individuals associated with the corresponding reference vector. Finally, a monitoring strategy is designed to oversee the penalty factor, ensuring that adaptive adjustments align with the algorithm’s needs at different stages. Through a comparison involving benchmark experiments and two real-world problems, the competitiveness of caps-NSGA-III was demonstrated.
Salinity as an Abiotic Stressor for Eliciting Bioactive Compounds in Marine Microalgae
Authors: Macías-de la Rosa Adrián , López-Rosales Lorenzo , Contreras-Gómez Antonio , Sánchez-Mirón Asterio , García-Camacho Francisco , Cerón-García María del Carmen
Published: October 2024

This study investigated the impact of culture medium salinity (5–50 PSU) on the growth and maximum photochemical yield of photosystem II (Fv/Fm) and the composition of carotenoids, fatty acids, and bioactive substances in three marine microalgae (Chrysochromulina rotalis, Amphidinium carterae, and Heterosigma akashiwo). The microalgae were photoautotrophically cultured in discontinuous mode in a single stage (S1) and a two-stage culture with salt shock (S2). A growth model was developed to link biomass productivity with salinity for each species. C. rotalis achieved a maximum biomass productivity (Pmax) of 15.85 ± 0.32 mg·L−1·day−1 in S1 and 16.12 ± 0.13 mg·L−1·day−1 in S2. The salt shock in S2 notably enhanced carotenoid production, particularly in C. rotalis and H. akashiwo, where fucoxanthin was the main carotenoid, while peridinin dominated in A. carterae. H. akashiwo also exhibited increased fatty acid productivity in S2. Salinity changes affected the proportions of saturated, monounsaturated, and polyunsaturated fatty acids in all three species. Additionally, hyposaline conditions boosted the production of haemolytic substances in A. carterae and C. rotalis.