bluuebunny/crossref_metadata_2025 huggingface dataset:
Redox‐Active Metal–Organic Frameworks: Highly Stable Charge‐Separated States through Strut/Guest‐to‐Strut Electron Transfer
Authors: Sikdar Nivedita , Jayaramulu Kolleboyina , Kiran Venkayala , Rao K. Venkata , Sampath Srinivasan , George Subi J. , Maji Tapas Kumar
Published: July 2015

Molecular organization of donor and acceptor chromophores in self‐assembled materials is of paramount interest in the field of photovoltaics or mimicry of natural light‐harvesting systems. With this in mind, a redox‐active porous interpenetrated metal–organic framework (MOF), {[Cd(bpdc)(bpNDI)]⋅4.5 H2O⋅DMF}n (1) has been constructed from a mixed chromophoric system. The μ‐oxo‐bridged secondary building unit, {Cd2(μ‐OCO)2}, guides the parallel alignment of bpNDI (N,N′‐di(4‐pyridyl)‐1,4,5,8‐naphthalenediimide) acceptor linkers, which are tethered with bpdc (bpdcH2=4,4′‐biphenyldicarboxylic acid) linkers of another entangled net in the framework, resulting in photochromic behaviour through inter‐net electron transfer. Encapsulation of electron‐donating aromatic molecules in the electron‐deficient channels of 1 leads to a perfect donor–acceptor co‐facial organization, resulting in long‐lived charge‐separated states of bpNDI. Furthermore, 1 and guest encapsulated species are characterised through electrochemical studies for understanding of their redox properties.
Tetraphenylethene Derivatives with Different Numbers of Positively Charged Side Arms have Different Multimeric G‐Quadruplex Recognition Specificity
Authors: Zhang Qi , Liu Yan‐Chen , Kong De‐Ming , Guo Dong‐Sheng
Published: July 2015

Some G‐rich sequences in the human genome have the potential to fold into a multimeric G‐quadruplex (G4) structure and the formation of telomeric multimeric G4 has been demonstrated. Searching for highly specific multimeric G4 ligands is important for structure probing and for study of the function of G‐rich gene sequences, as well as for the design of novel anticancer drugs. We found different numbers of positively charged side‐arm substituents confer tetraphenylethene (TPE) derivatives with different multimeric G4 recognition specificity. 1,2‐Bis{4‐[(trimethylammonium)butoxy]phenyl}‐1,2‐tetraphenylethene dibromide (DATPE), which contains two side arms and gives a fluorescence response to only multimeric G4, has a low level of cytotoxicity and little or no effect on multimeric G4 conformation or stability. These features make DATPE a promising fluorescent probe for detection of multimeric G4 specifically in biological samples or in vivo. 1,1,2,2‐Tetrakis{4‐[(trimethylammonium)butoxy]phenyl}tetraphenylethene tetrabromide (QATPE), which contains four side arms, has a lower level of specificity for multimeric G4 recognition compared to DATPE but its binding affinity to multimeric G4 is higher compared to other structural DNAs. Its high multimeric G4‐binding affinity, excellent multimeric G4‐stabilizing ability, and the promotion of parallel G4 formation make QATPE a good candidate for novel anticancer drugs targeting multimeric G4 specifically, especially telomeric multimeric G4. This work provides information that might aid the design of specific multimeric G4 probes and the development of novel anticancer drugs.
Bioorthogonal SERS Nanoprobes for Mulitplex Spectroscopic Detection, Tumor Cell Targeting, and Tissue Imaging
Authors: Wu Junzhou , Liang Duanwei , Jin Qingqing , Liu Jie , Zheng Meiling , Duan Xuanming , Tang Xinjing
Published: July 2015

A surface‐enhanced Raman scattering (SERS) technique shows extraordinary features for a range of biological and biomedical applications. Herein, a series of novel bioorthogonal SERS nanoprobes were constructed with Gold nanoflower (AuNF) and Raman reporters, the signals of which were located in a Raman‐silent region of biological samples. AS1411 aptamer was also co‐conjugated with AuNF through a self‐assembled monolayer coverage strategy. Multiplex SERS imaging using these nanoprobes with three different bioorthogonal small‐molecule Raman reporters is successfully achieved with high multiplexing capacity in a biologically Raman‐silent region. These Raman nanoprobes co‐conjugated with AS1411 showed high affinity for tumor cells with overexpressed nucleolin and can be used for selective tumor cell screening and tissue imaging.
Ring Contraction of 3‐Hydroxy‐3‐(trifluoromethyl)piperidines: Synthesis of 2‐Substituted 2‐(Trifluoromethyl)pyrrolidines
Authors: Feraldi‐Xypolia Alexandra , Gomez Pardo Domingo , Cossy Janine
Published: July 2015

A ring contraction of 3‐hydroxy‐3‐(trifluoromethyl)piperidines was achieved via an aziridinium intermediate. This contraction facilitates the synthesis of a series of 2‐substituted 2‐(trifluoromethyl)pyrrolidines incorporating a quaternary center at the C2 position.
Preparation of Information‐Containing Macromolecules by Ligation of Dyad‐Encoded Oligomers
Authors: Trinh Thanh Tam , Oswald Laurence , Chan‐Seng Delphine , Charles Laurence , Lutz Jean‐François
Published: July 2015

A simplified strategy for preparing non‐natural information‐containing polymers is reported. The concept relies on the successive ligation of oligomers that contain minimal sequence motifs. It was applied here to the synthesis of digitally‐encoded poly(triazole amide)s, in which propyl and 2‐methyl propyl motifs are used to code 0 and 1, respectively. A library of four oligo(triazole amide)s containing the information dyads 00, 01, 10, and 11 was prepared. These oligomers contain two reactive functions, that is, an alkyne and a carboxylic acid. Thus, they can be linked to another with the help of a reactive spacer containing azide and amine functions. Using two successive chemoselective steps, that is, azide‐alkyne Huisgen cycloaddition and carboxylic acid‐amine coupling, monodisperse polymers can be obtained. In particular, the library of dyads permits the implementation of any desired sequence using a small number of steps. As a proof‐of‐concept, the synthesis of molecular bytes 00000000 and 00000110 is described.
ChemInform Abstract: A New Lithium‐Rich anti‐Spinel in Li—O—Br System.
Authors: Zhang J. , Zhu J. , Wang L. , Zhao Y.
Published: July 2015

An “electronically inverted” anti‐spinel is obtained for the first time.
ChemInform Abstract: Crystal Structure Determination of Pb2F2(HF)(SbF6)2, PbFSbF6 and Ba(HF)(AF6)2: (A: As, Sb).
Authors: Tramsek Melita , Mazej Zoran , Goreshnik Evgeny , Tavcar Gasper
Published: July 2015

Pb(SbF6)2 and Ba(SbF6)2 and PbFSbF6 are prepared by reaction of the corresponding metal difluorides, SbF3, anhydrous HF, and excess elemental F2 (fluoroethylene‐hexafluoropropylene reaction vessels, 25 °C).
ChemInform Abstract: Synthesis, Crystal Structure and Photoluminescence Properties of New Blue‐Green Ba1‐x(PO3)2:Eux2+ (0 < x ≤ 0.040) Phosphors for Near Ultraviolet Based White Light‐Emitting Diodes.
Authors: Wu Zhan‐Chao , Fu Hong‐Hong , Liu Jie , Kuang Shao‐Ping , Wu Ming‐Mei , Xu Jun‐Gu , Kuang Xiao‐Jun
Published: July 2015

Ba1‐x(PO3)2:Eux2+ (x = 0.005‐0.040) phosphors are prepared by a solid‐state reaction of BaCO3, NH4H2PO4, and Eu2O3 in stoichiometric amounts (CO atmosphere, alundum crucible, 600 °C, 6 h).
ChemInform Abstract: Non‐aqueous Sol—Gel Synthesis of Ultra Small Persistent Luminescence Nanoparticles for Near‐Infrared in vivo Imaging.
Authors: Teston Eliott , Richard Sophie , Maldiney Thomas , Lievre Nicole , Wang Guillaume Yangshu , Motte Laurence , Richard Cyrille , Lalatonne Yoann
Published: July 2015

ZnGa2O4:Cr3+ (5 mol%) nanoparticles of 6 nm are prepared by a microwave‐assisted non‐aqueous sol‐gel method starting with microwave heating of ZnII‐, GaIII, and CrIII‐2,4‐pentanedionate monohydrates in BnOH in the presence of Cr (270 °C, 30 min) followed by grafting of the as‐prepared precipitate with a phosphonate‐PEG (MW 2000) aqueous solution leading to a highly stable dispersion (pH 2‐10) under physiological conditions.
ChemInform Abstract: Codoping in SnTe: Enhancement of Thermoelectric Performance Through Synergy of Resonance Levels and Band Convergence.
Authors: Tan Gangjian , Shi Fengyuan , Hao Shiqiang , Chi Hang , Zhao Li‐Dong , Uher Ctirad , Wolverton Chris , Dravid Vinayak P. , Kanatzidis Mercouri G.
Published: July 2015

The thermoelectric performance of p‐type SnTe is enhanced over a broad temperature range with a peak ZT (figure of merit) value of ≈1.4 at 923 K via In/Cd co‐doping and CdS nanostructuring.
ChemInform Abstract: High‐Yield Electrosynthesis of Hydrogen Peroxide from Oxygen Reduction by Hierarchically Porous Carbon.
Authors: Liu Yanming , Quan Xie , Fan Xinfei , Wang Hua , Chen Shuo
Published: July 2015

Hierarchically porous carbon (HPC) as a cost‐effective catalyst for the production of H2O2 via electroreduction of O2 in aqueous solution is prepared by solvothermal synthesis of a metal organic framework (MOF‐5) from Zn(NO3)2 and 1,4‐benzenedicarboxylic acid in DMF (autoclave, 100 °C, 0.5, 1, or 2 d) and subsequent carbonization under H2 (1100 °C, 5 h).
ChemInform Abstract: Simple Route for Gram Synthesis of Less Defective Few Layered Graphene and Its Electrochemical Performance.
Authors: Parveen Nazish , Ansari Mohd Omaish , Cho Moo Hwan
Published: July 2015

Fabrication of high‐quality graphene (GN) sheets is performed using a less corrosive technique for electrochemical graphite exfoliation under application of an optimized aqueous solution of NaOH, Na2S2O3, and NaClO4 as electrolyte.
ChemInform Abstract: Unusual Crystallographic Existence of a Hydrated Zinc(II) Bisulfate Complex: Experimental and Theoretical Observations.
Authors: Dey Dhananjay , Pal Sukanta , Yadav Hare Ram , Sengupta Partha Sarathi , Choudhury Angshuman Roy , Kole Niranjan , Biswas Bhaskar
Published: July 2015

[Zn(H2O)6] (HSO4·H2O)2 (I) is obtained in 72% yield from an aqueous MeOH solution of ZnSO4, 4,4′‐bipyridine, and NH4SCN.
ChemInform Abstract: Synthesis of RbREF4 (RE: Pr, Nd, Sm, Eu, and Tb) and RbRE2F7 (Dy, Ho, Er and Yb) under Non‐aqueous Conditions.
Authors: Tripathi Vikash Kumar , Saroj Sanjay Kumar , Nagarajan Rajamani
Published: July 2015

Crystalline phases of the title compounds are prepared by the reaction of Ln(acac)3 (Ln: lanthanide) with RbF in MeOH (25 °C, 12 h).
ChemInform Abstract: Extended Structural Materials Composed of Transition‐Metal‐Substituted Arsenicniobates and Their Photocatalytic Activity.
Authors: Lan Qing , Zhang Zhi‐Ming , Li Yang‐Guang , Wang En‐Bo
Published: July 2015

The novel cluster compounds [Cu(en)2(H2O)] [Cu(en)2] 4{AsNb9V7O44 }·8H2O (I) and [Cu(en)2(H2O)] [Cu(en)2] 4H{AsNb8V8O44 }·11H2O (II) are prepared in 41 and 38% yield, resp., by solvothermal reaction of K7HNb6O19, Cu(OAc)2, Na2VO3, As2O3, and en under nearly identical conditions (HCl, H2O, autoclave, 160 °C, 5 d) except for the pH value which should be in the range 10.3—10.6 for (I) and 10.7—11.0 for (II).
ChemInform Abstract: Flux Synthesis, Structure, Properties, and Theoretical Magnetic Study of Uranium(IV)‐Containing A2USi6O15 (A: K, Rb) with an Intriguing Green‐to‐Purple, Crystal‐to‐Crystal Structural Transition in the K Analogue.
Authors: Morrison Gregory , Ramanantoanina Harry , Urland Werner , Smith Mark D. , zur Loye Hans‐Conrad
Published: July 2015

The compounds M2USi6O15 (M: K, Rb, Cs) are prepared in 61, 29, and 37% yield, resp., by layering a mixture of UO2 and SiO2 under a MF/MCl mixture that acts as a flux (copper tube, N2 flow, 900 °C, 12 h).
ChemInform Abstract: Introduction of the 4,4,4‐Trifluorobut‐2‐ene Chain Exploiting a Regioselective Tsuji—Trost Reaction Catalyzed by Palladium Nanoparticles.
Authors: Hemelaere Remy , Desroches Justine , Paquin Jean‐Francois
Published: July 2015

An effective process for the regioselective Tsuji—Trost reaction of 4,4,4‐trifluorobut‐2‐ene derived carbonate (I) and (VI), or acetate (VII) with aromatic alcohols, secondary amines, and malonate type C‐nucleophiles is developed.
ChemInform Abstract: A Mild and Efficient Zn‐Catalyzed C‐Glycosylation: Synthesis of C(2)—C(3) Unsaturated C‐Linked Glycopyranosides.
Authors: Reddy Thurpu Raghavender , Rao Dodla Sivanageswara , Kashyap Sudhir
Published: July 2015

The reaction tolerates a broad range of nucleophiles, including silanes bearing hydrogen, alkyl, cyano, azido, and alkynyl groups, as well as hetaromatics, malonates, and trimethylaluminium.
ChemInform Abstract: Amine‐Catalyzed Tunable Reactions of Allenoates with Dithioesters: Formal [4 + 2] and [2 + 2] Cycloadditions for the Synthesis of 2,3‐Dihydro‐1,4‐oxathiines and Enantioenriched Thietanes.
Authors: Yang Hai‐Bin , Yuan Yu‐Chao , Wei Yin , Shi Min
Published: July 2015

Novel amine‐catalyzed tunable cycloadditions between allenoates and dithioesters, providing a divergent synthesis of 2,3‐dihydro‐1,4‐oxathiines and enantioenriched thietanes is reported.
ChemInform Abstract: A Facile Synthesis of Glyco 3‐Nitrochromane Hybrid Pyrrolidinyl Spiro Heterocycles via [3 + 2] Cycloaddition of Azomethine Ylides.
Authors: Naga Siva Rao J. , Raghunathan R.
Published: July 2015

Azomethine ylides generated in situ by the condensation of α‐amino acids and diketones undergo [3 + 2] cycloaddition reactions with glyco 3‐nitrochromenes such as (I) to give spirocyclic heterocycles.
ChemInform Abstract: Tuneable Hydrogenation of Nitriles into Imines or Amines with a Ruthenium Pincer Complex under Mild Conditions.
Authors: Choi Jong‐Hoo , Prechtl Martin H. G.
Published: July 2015

By adjustment of the reaction parameters an efficient transformation of aromatic and aliphatic nitriles into amines or imines is achieved.
ChemInform Abstract: One‐Pot Asymmetric Reductive Amination of Ketones Induced by Polyfluoroalkanesulfinamide.
Authors: Yang Kai , Liu Jin‐Tao
Published: July 2015

An efficient one‐pot method for the asymmetric reductive amination of ketones in the presence of sodium borohydride is presented.
ChemInform Abstract: Nickel‐Catalyzed Borylation of Arenes and Indoles via C—H Bond Cleavage.
Authors: Furukawa Takayuki , Tobisu Mamoru , Chatani Naoto
Published: July 2015

The first Ni‐catalyzed borylation of arenes and indoles is described.
ChemInform Abstract: Copper‐Catalyzed Trifluoromethylation of Organic Zinc Reagents with an Electrophilic Trifluoromethylating Reagent.
Authors: Wang Chang‐Sheng , Wang Haoyang , Yao Cheng
Published: July 2015

Various aryl‐, vinyl‐, and alkyl zinc reagents are trifluoromethylated with Togni′s reagent under mild reaction conditions.
ChemInform Abstract: Passerini/Tsuji—Trost Strategies Towards Achieving Lactams and Cyclopentane Derivatives.
Authors: Cordier Marie , Dos Santos Aurelie , El Kaim Laurent , Narboni Noisette
Published: July 2015

New Tsuji—Trost transformations of Passerini adducts derived from α,β‐unsaturated aldehydes are reported.
ChemInform Abstract: Cobalt‐Catalyzed Negishi Cross‐Coupling Reactions of (Hetero)Arylzinc Reagents with Primary and Secondary Alkyl Bromides and Iodides.
Authors: Hammann Jeffrey M. , Haas Diana , Knochel Paul
Published: July 2015

A one‐pot Negishi‐type cross‐coupling reaction of initially formed diarylzinc reagents with primary and secondary alkyl iodides is developed.
ChemInform Abstract: α‐Monoarylation and Tandem Arylation—Insertion of Malonates with Arynes.
Authors: Chen Qian , Zhang Changyuan , Chen Lili , Wen Chunxiao , Du Zhiyun , Chen Huixiong , Zhang Kun
Published: July 2015

The facile protocol allows the α‐monoarylation of malonates with in situ generated arynes.
ChemInform Abstract: The Reactivity of 4‐Hydroxy‐ and 4‐Silyloxy‐1,5‐allenynes with Homogeneous Gold(I) Catalysts.
Authors: Wegener Michael , Kirsch Stefan F.
Published: July 2015

Various mono‐ and bicyclic, polyunsaturated carbonyl compounds are obtained by new gold(I)‐catalyzed cascade reactions of 4‐hydroxy‐ and 4‐silyloxy‐1,5‐allenynes.
ChemInform Abstract: Pd‐Catalyzed Csp2—H Functionalization of Heteroarenes via Isocyanide Insertion: Concise Synthesis of Di‐(Hetero)aryl Ketones and Di‐(Hetero)aryl Alkylamines.
Authors: Sharma Upendra K. , Sharma Nandini , Xu Jun , Song Gonghua , Van der Eycken Erik V.
Published: July 2015

This Pd‐catalyzed three‐component reaction provides imine intermediates which are either hydrolyzed to give ketones or reduced to give amines.
ChemInform Abstract: Traceless Bond Construction via Rearrangement of N‐Boc‐N‐allylhydrazones Giving 1,1‐Disubstituted Olefins.
Authors: Dittrich Sebastian , Bracher Franz
Published: July 2015

Two of the four obtained products are contaminated with olefinic isomers [cf.
ChemInform Abstract: Ruthenium‐Catalyzed Highly Chemoselective Hydrogenation of Aldehydes.
Authors: Bonomo Lucia , Kermorvan Laurent , Dupau Philippe
Published: July 2015

The efficient hydrogenation of aliphatic and aromatic aldehydes in the presence of a range of functional groups is described, including ketones, carboxylic acids, esters, and amides, epoxides, nitriles, alkenes, as well as strained ring systems.
ChemInform Abstract: Decarbamoylation of Primary Carbamates Using Sodium in Silica Gel (Na SG).
Authors: Maurya Chandra Kant , Gupta Pradeep Kumar
Published: July 2015

Sodium metal stabilized in silica gel is found to be a powerful reducing agent which allows the efficient decarbamoylation of carbamates at room temperature.
ChemInform Abstract: Efficient Strategy for Construction of 6‐Carbamoylfulvene‐6‐carboxylate Skeletons via [3 + 2] Cycloaddition of 1‐Cyanocyclopropane 1‐Ester with β‐Nitrostyrenes.
Authors: Tan Chen , Ye Weijian , Yao Juan , Liu Juanjuan , Xue Shuwen , Li Yang , Wang Cunde
Published: July 2015

The reaction does not allow the use 1,1‐dicyanocyclopropanes instead of 1‐cyanocyclopropane‐1‐carboxylates.
ChemInform Abstract: Mild and Efficient Palladium/BrettPhos‐Catalyzed Methoxylation and Deuteriomethoxylation of Activated Aryl Bromides.
Authors: Rangarajan T. M. , Brahma Raju , Ayushee Ayushee , Prasad Ashok K. , Verma Akhilesh K. , Singh Rishi Pal
Published: July 2015

A simple and efficient methoxylation reaction of activated aryl bromides to give the corresponding ethers is presented.
ChemInform Abstract: Formation of C(sp2)—S Bonds Through Decarboxylation of α‐Oxocarboxylic Acids with Disulfides or Thiophenols.
Authors: Rong Guangwei , Mao Jincheng , Liu Defu , Yan Hong , Zheng Yang , Chen Jie
Published: July 2015

The method offers an efficient approach to thiocarboxylates.
ChemInform Abstract: Pd‐Catalyzed Desulfitative and Denitrogenative Suzuki‐Type Reaction of Arylsulfonyl Hydrazides.
Authors: Zhong Shuangling , Sun Chenggang , Dou Sen , Liu Wencong
Published: July 2015

The utility of the scalable method is demonstrated by the one‐pot two‐step coupling of bromophenylsulfonohydrazides in order to prepare terphenyl derivatives such as (VIII).
ChemInform Abstract: Tf2NH‐Catalyzed, Highly Regio‐ and Stereo‐Selective Synthesis of Trisubstituted Alkenes and Indane Derivatives from Benzylic Alcohols and Alkenes.
Authors: Li Hai‐Hua
Published: July 2015

The reaction of benzylic alcohols with terminal 1,1‐disubstituted alkenes affords trisubstituted alkenes whereas the reaction of benzylic alcohols with 1,2‐disubstituted or 1,1,2‐trisubstituted alkenes provides indane derivatives.
ChemInform Abstract: Hypervalent‐Iodine‐Mediated Cascade Annulation of Diarylalkynes Forming Spiro Heterocycles under Metal‐Free Conditions.
Authors: Zhang Xiang , Yang Chao , Zhang‐Negrerie Daisy , Du Yunfei
Published: July 2015

This unprecedented process involves two sequential C—N/C—O bond formations and insertion of a carbonyl oxygen in a convenient one‐pot process to give a wide variety of spiro heterocycles.
ChemInform Abstract: Regioselective Synthesis of Nitrofuran Containing Novel Spiropyrrolidine Library Through 1,3‐Dipolar Cycloaddition Reactions.
Authors: Mallya Sahana , Kalluraya Balakrishna , Girisha K. S.
Published: July 2015

A new class of functionalized spiropyrrolidines (IV) (10 examples) containing a nitrofuran moiety is formed with high stereo‐ and regioselectivity in good to excellent yields via 1,3‐dipolar cycloaddition of azomethine ylides derived from ninhydrin and sarcosine with various substituted chalcones (I).
ChemInform Abstract: Catalytic Activity of Reusable Nickel Oxide Nanoparticles in the Synthesis of Spirooxindoles.
Authors: Nasseri Mohammad Ali , Kamali Fateme , Zakerinasab Batol
Published: July 2015

The reaction between malonitrile, isatins, and 1,3‐dicarbonyl compounds including 1,3‐cyclohexadione, dimedone, and 4‐hydroxycoumarine provides indoline derivatives in high yields.
ChemInform Abstract: Regioselective One‐Pot Synthesis of New Unsymmetric Spiro Dihydrofurans in the Reaction of Mixed Two Different Cyclic β‐Dicarbonyl Compounds with BrCN and Aldehydes in the Presence of Et3N.
Authors: Noroozi Pesyan Nader , Shokr Alireza , Gharib Ali , Tunc Tuncay , Sahin Ertan
Published: July 2015

One‐pot reaction of cyclic β‐dicarbonyl with various aldehydes in the presence of cyanogen bromide and triethylamine leads to the selective and efficient formation of crossed new unsymmetrical spiro dihydrofurans at room temperature (no yields given).
ChemInform Abstract: Palladium‐Catalyzed Cycloisomerization and Aerobic Oxidative Cycloisomerization of Homoallenyl Amides: A Facile and Divergent Approach to 2‐Aminofurans.
Authors: Cheng Cungui , Liu Shuiyou , Zhu Gangguo
Published: July 2015

Various functionalized 2‐amino‐5‐alkylfurans and 2‐amino‐5‐formylfurans are selectively synthesized under mild and environmentally benign reaction conditions.
ChemInform Abstract: Regioselective Access to CF3S‐Substituted Dihydrofurans from Homopropargylic Alcohols with Trifluoromethanesulfenamide.
Authors: Chen Dao‐Qian , Gao Pin , Zhou Ping‐Xin , Song Xian‐Rong , Qiu Yi‐Feng , Liu Xue‐Yuan , Liang Yong‐Min
Published: July 2015

The title compounds are obtained from unprotected homopropargylic alcohols with high regioselectivity.
ChemInform Abstract: Sequential One‐Pot Approach for the Synthesis of Functionalized Phthalans via Heck‐Reduction—Cyclization (HRC) Reactions.
Authors: Krishna Jonnada , Niharika Pedireddi , Satyanarayana Gedu
Published: July 2015

A straightforward procedure for the synthesis of 1,3‐dihydroisobenzofurans via intermolecular Mizoroki‐Heck coupling of bromo benzaldehydes with β‐aryl allylic alcohols, reduction, and cyclization is elaborated.
ChemInform Abstract: Oxidative Conversion of δ‐Sultones to γ‐Lactones.
Authors: Liyanage Duminda S. , Jungong Christian S. , Novikov Alexei V.
Published: July 2015

This simple protocol allows the transformation of δ‐sultones to γ‐lactones.
ChemInform Abstract: Synthesis of N‐Substituted (Z)‐3‐Arylbenzo[c]thiophen‐1(3H)‐imines by the Reaction of 1‐[Aryl(methoxy)methyl]‐2‐lithiobenzenes with Isothiocyanates Followed by Acid‐Mediated Cyclization.
Authors: Kobayashi Kazuhiro , Shigemura Yuuho , Ezaki Kosuke
Published: July 2015

The title transformation provides benzothiophenimines some of which are further hydrolized to the corresponding benzothiophenones.
ChemInform Abstract: Highly Selective Copper‐Catalyzed Asymmetric [3 + 2] Cycloaddition of Azomethine Ylides with Acyclic 1,3‐Dienes.
Authors: Gonzalez‐Esguevillas Maria , Pascual‐Escudero Ana , Adrio Javier , Carretero Juan C.
Published: July 2015

Depending on the catalyst either exo‐ or endo‐products are obtained preferentially, usually with ≥98% d.e.
ChemInform Abstract: One‐Pot Total Synthesis of Streptindole, Arsindoline B and Their Congeners Through Tandem Decarboxylative Deaminative Dual‐Coupling Reaction of Amino Acids with Indoles.
Authors: Xiang Jiachen , Wang Jungang , Wang Miao , Meng Xianggao , Wu Anxin
Published: July 2015

A simple procedure is elaborated for the synthesis of arundine (VIIIa), vibrindole A (VIIIb), streptindole (VIIId), arsindole B (VIIIe), and analogues (III) and (VI).
ChemInform Abstract: Hypervalent Iodine Mediated Alkene Difunctionalization of Vinylphenols: Diastereoselective Synthesis of Substituted Indoles and Indolizines.
Authors: Zhang Kai , Wang Hang , Zheng Jingfeng , Yu Lei , Ding Hanfeng
Published: July 2015

The title reaction allows the facile synthesis of 3‐substituted indoles and 2‐substituted indolizines with good yields and high diastereoselectivities.
ChemInform Abstract: Efficient Access to Enantiopure 1,3‐Disubstituted Isoindolines from Selective Catalytic Fragmentation of an Original Desymmetrized Rigid Overbred Template.
Authors: Pandey Ganesh , Varkhedkar Rajesh , Tiwari Divya
Published: July 2015

The preparation of the asymmetric substrate (I) is elaborated and its KOtBu‐catalyzed conversion into enantiopure cis‐1,3‐disubstituted isoindoline carboxylates.
ChemInform Abstract: Synthesis of New Type of Betti Bases via Three‐Component Reaction of β‐Naphthol, Cyclic Amines and Isatins.
Authors: Gao Hong , Sun Jing , Yan Chao‐Guo
Published: July 2015

The reaction is very sensitive towards the structure of the substrates.
ChemInform Abstract: Catalytic Asymmetric Arylation of 3‐Indolylmethanols: Enantioselective Synthesis of 3,3′‐Bis(indolyl)oxindoles with High Atom Economy.
Authors: Sun Xiao‐Xue , Du Bai‐Xiang , Zhang Hong‐Hao , Ji Lei , Shi Feng
Published: July 2015

The products are delivered in high reaction yields with moderate to high enantioselectivities.
ChemInform Abstract: Pd‐Catalyzed Direct C2‐Acylation and C2,C7‐Diacylation of Indoles: Pyrimidine as an Easily Removable C—H Directing Group.
Authors: Kumar Govindharaj , Sekar Govindasamy
Published: July 2015

The reaction proves successful using aryl, hetaryl, alkyl, and alkenyl aldehydes as acylation agents.
ChemInform Abstract: Copper(II) Chloride Assisted Aryl Exchange in Arylmethanes: A Simple and Efficient Route to Triarylmethane Derivatives.
Authors: Kothandapani Jagatheeswaran , Ganesan Asaithampi , Vairaprakash Pothiappan , Ganesan Subramaniapillai Selva
Published: July 2015

Copper(II) chloride promotes aryl exchange reaction of substrates such as (I) and (IV) to form the unsymmetrical triarylmethane (III).
ChemInform Abstract: Organocatalytic Enantioselective Friedel—Crafts Reaction: An Efficient Access to Chiral Isoindolo‐β‐Carboline Derivatives.
Authors: Fang Fang , Hua Genghong , Shi Feng , Li Pengfei
Published: July 2015

The products are obtained in moderate to excellent yields and with high to excellent enantioselectivities.
ChemInform Abstract: Nano Zirconia Catalyzed One‐Pot Synthesis of Some Novel Substituted Imidazoles under Solvent‐Free Conditions.
Authors: Bajpai Shivam , Singh Sundaram , Srivastava Vandana
Published: July 2015

The efficient protocol starts from isatin derivatives, ammonium acetate, and aryl aldehydes.
ChemInform Abstract: Original Synthesis of Benzo[f]indole‐4,9‐dione Derivatives Using TDAE Strategy.
Authors: Nadji‐Boukrouche Aida R. , On Sopheak , Khoumeri Omar , Terme Thierry , Vanelle Patrice
Published: July 2015

One‐pot Sonogashira‐cyclization reaction of bromoquinone (I) and propargyl alcohol provides benzo[f]indole‐4,9‐diones (III) and (IV).
ChemInform Abstract: Microwave‐Assisted Direct Amidation of Ethyl 1‐Phenyl‐5‐hydroxy‐1H‐pyrazole‐4‐carboxylate.
Authors: Milosevic Mladena , Sterbal Ines , Fegus Urban , Baskovc Jernej , Prek Benjamin , Groselj Uros , Stanovnik Branko , Svete Jurij
Published: July 2015

A simple microwave‐assisted direct amidation of the title carboxylate (I) is reported which is limited to primary aliphatic amines and most reactive cyclic secondary amines, such as pyrrolidine and piperidine.
ChemInform Abstract: Synthesis of Novel Organosiliconsulfur‐Containing Tetrasubstituted Imidazoles Sonocatalyzed by LaxSr1‐xFeyCo1‐yO3 Nanoperovskites.
Authors: Safa Kazem D. , Allahvirdinesbat Maryam , Namazi Hassan
Published: July 2015

13 Tetrasubstituted imidazoles (IV) are prepared under ultrasonic irradiation.
ChemInform Abstract: I2‐Catalyzed Synthesis of Substituted Imidazoles from Vinyl Azides and Benzylamines.
Authors: Xiang Likui , Niu Yanning , Pang Xiaobo , Yang Xiaodong , Yan Rulong
Published: July 2015

Substituted imidazoles are obtained by a new and efficient I2‐catalyzed oxidative tandem cyclization of various simple vinyl azides and benzylamines.
ChemInform Abstract: Cp2ZrCl2‐Catalyzed Synthesis of 2‐Aminovinyl Benzimidazoles under Microwave Conditions.
Authors: Sun Qi , Wang Cheng‐Jun , Gong Shan‐Shan , Ai Yong‐Jian , Sun Hong‐Bin
Published: July 2015

Starting from 1,2‐phenylenediamine derivatives and 3‐aminoacrolein substrates the facile and efficient title process is developed.
ChemInform Abstract: Synthesis of Oxazolidinones from Epoxides and Isocyanates Catalyzed by Rare‐Earth‐Metal Complexes.
Authors: Wang Peng , Qin Jie , Yuan Dan , Wang Yaorong , Yao Yingming
Published: July 2015

The reaction tolerates a diverse range of 1‐substituted and 1,2‐disubstituted epoxides, and in most cases it proceeds with good regioselectivity in favor of the 3,5‐disubstituted vs.
ChemInform Abstract: Ligand‐Free Copper Powder‐Catalyzed and KOtBu‐Accelerated Expeditious Synthesis of Substituted Benzoxazoles.
Authors: Ahmed Atiur , Singha Raju , Ray Jayanta K.
Published: July 2015

This convenient and efficient cyclization reaction of ortho‐iodoanilides allows the synthesis of benzoxazoles under ligand free conditions.
ChemInform Abstract: Cu‐Catalyzed Selective Cascade sp3 C—H Bond Oxidative Functionalization Towards Isoxazoline Derivatives.
Authors: Wang Gang‐Wei , Cheng Ming‐Xing , Ma Ran‐Song , Yang Shang‐Dong
Published: July 2015

The first Cu‐catalyzed cascade C—H bond functionalization of various ethylazaarenes is developed.
ChemInform Abstract: Synthesis of Novel Tryptamine‐Based Macrocycles Using an Ugi 4‐CR/Microwave Assisted Click‐Cycloaddition Reaction Protocol.
Authors: Chavez‐Acevedo Lizbeth , Miranda Luis D.
Published: July 2015

The macrocycles comprise a peptoid moiety, a 1,3‐substituted indole nucleus and a triazole ring.
ChemInform Abstract: Intramolecular Decarboxylative Coupling as the Key Step in Copper‐Catalyzed Domino Reaction: Facile Access to 2‐(1,3,4‐Oxadiazol‐2‐yl)aniline Derivatives.
Authors: Xu Cheng , Jia Feng‐Cheng , Cai Qun , Li Deng‐Kui , Zhou Zhi‐Wen , Wu An‐Xin
Published: July 2015

(Oxadiazolyl)aniline derivatives (III) and (V) are obtained by a copper‐catalyzed domino reaction of simple and easily available isatins and hydrazides.
ChemInform Abstract: Stereoselective Domino Conjugate Addition of Grignard Reagents to Lactones Followed by Reaction with Activated Alkenes Catalyzed by Ferrocenyl Carbene Ligands.
Authors: Soradova Zuzana , Mazikova Jana , Meciarova Maria , Sebesta Radovan
Published: July 2015

The products are obtained in moderate yields and with good enantioselectivities.
ChemInform Abstract: Design, Synthesis, and Anticancer Activities of New Compounds Bearing the Quinone—Pyran—Lactone Tricyclic Pharmacophore.
Authors: Jiang Xue , Wang Meining , Song Shanshan , Xu Youjun , Miao Zehong , Zhang Ao
Published: July 2015

Tricyclic quinone‐pyran‐lactone skeleton derivatives [(VII) and (VIII)] are synthesized through a simple and effective four‐step procedure.
ChemInform Abstract: Efficient C(sp3)—H Bond Functionalization of Isochroman by AZADOL Catalysis.
Authors: Muramatsu Wataru , Nakano Kimihiro
Published: July 2015

The catalysis smoothly proceeds with a wide range of substrates and nucleophiles under environmentally friendly reaction conditions.
ChemInform Abstract: Rh‐Catalyzed Direct Cyclization of 1,4‐Naphthoquinone and 9,10‐Phenanthraquinone with Alkyne: Facile Access to 1,8‐Dioxapyrenes and 1,12‐Dioxaperylenes as Orange and Red‐Emitting Luminophores.
Authors: Wang Jing , Qin Dekun , Lan Jingbo , Cheng Yangyang , Zhang Shuai , Guo Qiang , Wu Jie , Wu Di , You Jingsong
Published: July 2015

A facile and efficient method for the synthesis of 1,8‐dioxapyrenes and 1,12‐dioxaperylenes through Rh‐catalyzed direct cyclization of 1,4‐naphthoquinones and 9,10‐phenanthraquinones with alkynes is developed.
ChemInform Abstract: Cubic Perovskite ZnTiO3 Nanopowder as a Recyclable Heterogeneous Catalyst for the Synthesis of 1,6‐Naphthyridines in Water.
Authors: Ray Suman , Das Paramita , Banerjee Biplab , Bhaumik Asim , Mukhopadhyay Chhanda
Published: July 2015

Naphthyridines (III) are simply, highly atom‐economically, and environmentally friendly synthesized in high yields using ZnTiO3 as catalyst.
ChemInform Abstract: An Intramolecular C—N Cross‐Coupling of β‐Enaminones: A Simple and Efficient Way to Precursors of Some Alkaloids of Galipea officinalis.
Authors: Dousova Hana , Horak Radim , Ruzickova Zdenka , Simunek Petr
Published: July 2015

A simple and efficient method for the intramolecular, palladium catalyzed amination of both chloro‐ and bromo‐substituted 3‐amino‐1,5‐diphenylpent‐2‐en‐1‐ones (I) is developed furnishing 2‐aroylmethylidene‐1,2,3,4‐tetrahydroquinolines (II) as suitable precursors for the synthesis of alkaloids from Galipea officinalis.
ChemInform Abstract: A General Synthesis of Bis(o‐azaheteroaryl)methane Derivatives from N‐Oxides of Azines and Azoles.
Authors: Szpunar Magdalena , Loska Rafal
Published: July 2015

The Et3N‐mediated reaction of methyl esters (I) and (VI) with N‐oxides (II) leads to desired adducts (III) and (VII), which can be converted in BODIPY analogues (V) and (IX).
ChemInform Abstract: Cu‐Catalyzed Aerobic Oxidative Cyclizations of 3‐N‐Hydroxyamino‐1,2‐propadienes with Alcohols, Thiols, and Amines to Form α‐O‐,S‐, and N‐Substituted 4‐Methylquinoline Derivatives.
Authors: Sharma Pankaj , Liu Rai‐Shung
Published: July 2015

A catalyzed aerobic oxidation of N‐hydroxyaminoallenes in the presence of a range of O‐, N‐, and S‐nucleophiles to afford 3‐substituted‐2‐en‐1‐ones is reported.
ChemInform Abstract: Indium‐Catalyzed C(sp3)—H Functionalization of 2‐Methylazaarenes Through Direct Benzylic Addition to Trifluoromethyl Ketones.
Authors: Jamal Zaini , Teo Yong‐Chua
Published: July 2015

The efficient protocol is not transferable to the benzylic addition to other types of ketone derivatives such as acetophenone and benzophenone.
ChemInform Abstract: Palladium‐Catalyzed Highly Efficient Synthesis of Functionalized Indolizines via Cross‐Coupling/Cycloisomerization Cascade.
Authors: Zhang Liangwei , Li Xiangdong , Liu Yuanhong , Zhang Dayong
Published: July 2015

A wide range of 1,3‐disubstituted indolizines are obtained by Pd‐catalyzed reaction of 3‐(2‐pyridyl) propargyl carbonates with organoboronic acids.
ChemInform Abstract: A Convenient Synthesis of Pyridophenanthroline Derivatives under Catalyst Free Conditions.
Authors: Mu Xing‐Ye , Li Chao , Li Yu‐Ling , Liu Yun , Wang Xiang‐Shan
Published: July 2015

via three‐component reaction of aminoquinolines with piperidinedione (II) and aromatic aldehydes
ChemInform Abstract: Synthesis of New 1, 10‐Phenanthroline Analogues as Potent Antimicrobial Agents Using Montmorillonite K‐10 as Catalyst.
Authors: Pagadala Ramakanth , Chidurala Praveen , Jetti Venkateshwarlu , Meshram Jyotsna S. , Maddila Suresh , Jonnalagadda Sreekanth B.
Published: July 2015

A series of new 1, 10‐phenanthroline derivatives (IV) are synthesized by four‐component domino reaction of 8‐hydroxyquinoline with aromatic aldehydes, acetoacetates and ammonium acetate under both conventional thermal or microwave irradiation conditions.
ChemInform Abstract: Cobalt(III)‐Catalyzed Directed C—H Coupling with Diazo Compounds: Straightforward Access Towards Extended π‐Systems.
Authors: Zhao Dongbing , Kim Ju Hyun , Stegemann Linda , Strassert Cristian A. , Glorius Frank
Published: July 2015

For the first time, an efficient and scalable cobalt‐catalyzed directed C—H functionalization with carbene precursors is presented.
ChemInform Abstract: Rh(III)‐Catalyzed Oxidative Annulation of 2‐Phenylimidazo[1,2‐a]pyridines with Alkynes: Mono versus Double C—H Activation.
Authors: Qi Zisong , Yu Songjie , Li Xingwei
Published: July 2015

While in the presence of AgOAc as oxidant only imidazopyridines are obtained, AgBF4 leads to isoquinolinium salts via mono C—H activation.
ChemInform Abstract: Tetrabutylammonium‐Assisted Diastereoselective [6π]‐Photocyclization of Acrylanilides.
Authors: Yamada Shinji , Okuda Mai , Yamamoto Natsuo
Published: July 2015

Tetrabutylammonium bromide is remarkably effective for improving the diastereoselectivity for [6π]‐photocyclization reactions of acrylanilides to form predominantly trans‐dihydroquinolines.
ChemInform Abstract: Palladium‐Catalyzed Dicarbonylative Synthesis of Tetracycle Quinazolinones.
Authors: Shen Chaoren , Man Nikki Y. T. , Stewart Scott , Wu Xiao‐Feng
Published: July 2015

Starting from 2‐bromobenzylamines, 2‐bromoanilines, and carbon monoxide the title transformation is effectively performed.
ChemInform Abstract: Al(H2PO4)3 as an Efficient and Recyclable Catalyst for the One‐Pot Synthesis of Naphthopyranopyrimidines.
Authors: Sajadikhah Seyed Sajad
Published: July 2015

The eco‐friendly reaction is successfully performed starting from 2‐naphthol, 6‐amino‐1,3‐dimethyl uracil, and a diverse range of aryl aldehydes, but fails using aliphatic aldehydes.
ChemInform Abstract: A POCl3‐Mediated Synthesis of Substituted Fused Azoacridones Derivatives.
Authors: Li Xi , Gao Chunmei , Yang Ti , Zhang Bin , Tan Chunyan , Liu Hongxia , Jiang Yuyang
Published: July 2015

Pyrimidine‐2,4‐diamines symmetrically or unsymmetrically N‐substituted with anthranilic acids are transformed according to a simple and efficient protocol.
ChemInform Abstract: Synthesis of Fused 9,10‐Dihydro‐6H‐azepino‐ and 9,10‐Dihydro‐6H‐[1,3]diazepino[1,2‐e]purines via Ring Closing Metathesis as Antilipid Peroxidation Agents.
Authors: Thalassitis Andreas N. , Hadjipavlou‐Litina Dimitra J. , Litinas Konstantinos E.
Published: July 2015

New compounds are tested as inhibitors of lipid peroxidation.
ChemInform Abstract: An Efficient Cascade Approach to Dibenzoxazepinones via Nucleophilic Aromatic Substitution and Smiles Rearrangement.
Authors: Liu Shihui , Hu Ying , Qian Pengfei , Hu Yanwei , Ao Guizhen , Chen Shaohua , Zhang Shilei , Zhang Yinan
Published: July 2015

Various substituted benzamides react with electron‐neutral and electron‐rich phenols to give dibenzoxazepinones.
ChemInform Abstract: Iron‐Catalyzed Asymmetric Hydrosilylation of 1,1‐Disubstituted Alkenes.
Authors: Chen Jianhui , Cheng Biao , Cao Minyi , Lu Zhan
Published: July 2015

The first enantioselective iron‐catalyzed anti‐Markovnikov hydrosilylation of 1,1‐disubstituted aryl alkenes is described.
ChemInform Abstract: Chemoselective Synthesis of β‐Ketophosphonates Using Lithiated α‐(Trimethylsilyl)methylphosphonate.
Authors: Specklin Simon , Cossy Janine
Published: July 2015

Dimethyl methylphosphonate as reactant gives lower yields.
ChemInform Abstract: Asymmetric Synthesis of α‐Hydroxymethylphosphonates and Phosphonic Acids via Hydrophosphonylation of Aldehydes with Chiral H‐Phosphonate.
Authors: Olszewski Tomasz K.
Published: July 2015

The scalable reaction is performed using aryl, hetaryl, and alkyl aldehydes and provides the corresponding α‐hydroxymethylphosphonates with high yield and high diastereomeric excess.
ChemInform Abstract: Room Temperature C—P Bond Formation Enabled by Merging Nickel Catalysis and Visible‐Light‐Induced Photoredox Catalysis.
Authors: Xuan Jun , Zeng Ting‐Ting , Chen Jia‐Rong , Lu Liang‐Qiu , Xiao Wen‐Jing
Published: July 2015

The dual‐catalytic reaction between diarylphosphine oxides and aryl iodides shows good functional group tolerance and allows the synthesis of various triarylphosphine oxides.
ChemInform Abstract: A Silver‐Initiated Free‐Radical Intermolecular Hydrophosphinylation of Unactivated Alkenes.
Authors: Li Zejiang , Fan Fenghua , Zhang Zengyan , Xiao Yingxia , Liu Dong , Liu Zhong‐Quan
Published: July 2015

A variety of alkyldiphenylphosphine oxides [(III), (V), (VII), (IX), and (XI)], alkyl phosphinates (XIa), and alkyl phosphonates (XIb) are facilely prepared via addition of H—P(O) compounds with unactivated alkenes through a silver(I)‐triggered free radical intermolecular C—P bond formation.
ChemInform Abstract: Preparation of 2H‐5,6‐Dihydroselenines Using α‐Alkoxy Carbonylselenoacetamide.
Authors: Ohnuma Akira , Nagata Tomohiro , Komura Kenichi , Ando Hiromune , Ishihara Hideharu , Koketsu Mamoru
Published: July 2015

and α,β‐unsaturated ketones
ChemInform Abstract: Synthesis and Selenation of Tandem Multicomponent Condensation Adducts.
Authors: Hua Guoxiong , Du Junyi , Fuller Amy L. , Arachchige Kasun S. A. , Cordes David B. , Slawin Alexandra M. Z. , Woollins J. Derek
Published: July 2015

Some four‐component condensation adducts are readily obtained by one‐pot reaction of aryl carboxylic acids, aryl aldehydes, arylamines, and c‐hexylisocyanide and treated with Woollins′ reagent leading to the formation of a series of new selenoamides.
ChemInform Abstract: Copper‐Catalyzed Asymmetric Three‐Component Borylstannation: Enantioselective Formation of C—Sn Bond.
Authors: Jia Tao , Cao Peng , Wang Ding , Lou Yazhou , Liao Jian
Published: July 2015

A simple one‐pot procedure using the chiral ligand (PPS) allows the synthesis of enantioenriched β‐boryl alkylstannanes through copper‐catalyzed borylstannation of the corresponding aryl substituted alkenes.
ChemInform Abstract: Alkynylation of Steroids via Pd‐Free Sonogashira Coupling.
Authors: Kotovshchikov Yury N. , Latyshev Gennadij V. , Lukashev Nikolay V. , Beletskaya Irina P.
Published: July 2015

Cu‐catalyzed Pd‐free Sonogashira is proposed as a straightforward and convenient route to valuable steroidal enynes using a biligand catalyst system based on Ph3P and TMEDA.
ChemInform Abstract: An Cost‐Effective and Safe Process of L‐cis‐4,5‐Methanoproline Amide, the Key Synthetic Intermediate of Saxagliptin, via an Improved Simmons—Smith Reaction.
Authors: Liu Feng , Ding Ding , Pan Xianhua , Yu Wansheng , Li Xiaojun , Chen Suke
Published: July 2015

The title compound (III) is obtained with excellent diastereoselectivity under optimized and improved Simmons—Smith reaction conditions.
ChemInform Abstract: IBr‐Catalyzed O‐Glycosylation of D‐Glucals: Facile Synthesis of 2,3‐Unsaturated‐O‐glycosides.
Authors: Sirion Uthaiwan , Saeeng Rungnapha , Siripru Onanong
Published: July 2015

2,3‐Unsaturated glycosides (20 examples) are obtained with good α‐selectivity by Ferrier rearrangement of tri‐O‐acetyl‐D‐glucal (I) in the presence of various alcohols (II).
ChemInform Abstract: Total Synthesis of Each Enantiomer of Falcarinol (Ia) and Panaxjapyne A (Ib) via Asymmetric Catalytic Alkynylation of an Aldehyde.
Authors: Yang Yan‐Qing , Li Shuo‐Ning , Zhong Jiang‐Chun , Zhou Yun , Zeng Hao‐Zhe , Duan Hong‐Jie , Bian Qing‐Hua , Wang Min
Published: July 2015

The racemic mixtures (I) are synthesized and each enantiomer thereof are isolated and structurally characterized.
ChemInform Abstract: Dynamic Inclusion Complexes of Metal Nanoparticles Inside Nanocups.
Authors: Alarcon‐Correa Mariana , Lee Tung‐Chun , Fischer Peer
Published: July 2015

A generic strategy towards the fabrication of dynamic 1:1 inclusion complexes of metal nanoparticles inside oxide nanocups with high yield (<70%) and regiospecificity (<90%) is demonstrated.
ChemInform Abstract: Metal Redispersion Strategies for Recycling of Supported Metal Catalysts: A Perspective
Authors: Morgan Kevin , Goguet Alexandre , Hardacre Christopher
Published: July 2015

Review: 198 refs.
ChemInform Abstract: Processing of Dielectric Oxynitride Perovskites for Powders, Ceramics, Compacts and Thin Films
Authors: Masubuchi Y. , Sun S.‐K. , Kikkawa S.
Published: July 2015

Review: 104 refs.
ChemInform Abstract: Carbon Nanosheets: Synthesis and Application
Authors: Fan Huailin , Shen Wenzhong
Published: July 2015

Review: [116 refs.
ChemInform Abstract: New Directions: Mineral Dust and Ozone ‐ Heterogeneous Chemistry
Authors: Ramachandran S.
Published: July 2015

Review: 11 refs.
ChemInform Abstract: Chelating σ‐Aryl Post‐Metallocenes: Probing Intramolecular [C—H.···F—C] Interactions and Unusual Reaction Pathways
Authors: Liu Cham‐Chuen , Chan Michael C. W.
Published: July 2015

Review: 56 refs.
ChemInform Abstract: Synthesis, Reactions and Biological Activity of Quinoxaline Derivatives
Authors: Abu‐Hashem Ameen Ali
Published: July 2015

Review: 203 refs.
ChemInform Abstract: Vacancy‐Mediated Processes in the Oxidation of CO on PdO(101)
Authors: Weaver Jason F. , Zhang Feng , Pan Li , Li Tao , Asthagiri Aravind
Published: July 2015

Review: 21 refs.
ChemInform Abstract: Synthesis of L‐Hexoses
Authors: Frihed Tobias Gylling , Bols Mikael , Pedersen Christian Marcus
Published: July 2015

Review: 504 refs.
ChemInform Abstract: Mechanistic Considerations of the Catalytic Guanylation Reaction of Amines with Carbodiimides for Guanidine Synthesis
Authors: Xu Ling , Zhang Wen‐Xiong , Xi Zhenfeng
Published: July 2015

Review: 132 refs.
ChemInform Abstract: Cucurbituril: Chiral Applications
Authors: Mandadapu Vijaybabu , Day Anthony I. , Ghanem Ashraf
Published: July 2015

Review: 100 refs.
ChemInform Abstract: Dearomatization Strategies of Heteroaromatic Compounds
Authors: Ramachandran Gunasekar , Sathiyanarayanan Kulathu Iyer
Published: July 2015

Review: 64 refs.
ChemInform Abstract: Azafullerene‐Based Donor‐Acceptor Dyads
Authors: Rotas Georgios , Tagmatarchis Nikos
Published: July 2015

Review: 35 refs.
ChemInform Abstract: Recent Advances in the Synthesis of β‐Lactam Derivatives Using Nitrone Cycloaddition Reactions
Authors: Chakraborty Bhaskar
Published: July 2015

Review: 38 refs.
ChemInform Abstract: Assessment of the Aromaticity of Borepin Rings by Spectroscopic, Crystallographic and Computational Methods: A Historical Overview
Authors: Messersmith Reid E. , Tovar John D.
Published: July 2015

Review: 72 refs.
ChemInform Abstract: Conjugated Diyne Chemistry: Synthesis, Natural Existence and Applications
Authors: Shi Wei
Published: July 2015

Review: 112 refs.
ChemInform Abstract: Recent Advances in Nickel‐Catalyzed C—H Bond Functionalized Reactions
Authors: Cai Xiao‐hua , Xie Bing
Published: July 2015

Review: 79 refs.
ChemInform Abstract: Deoxygenation of Biobased Molecules by Decarboxylation and Decarbonylation — A Review on the Role of Heterogeneous, Homogeneous and Bio‐Catalysis
Authors: Dawes Gwen J. S. , Scott Elinor L. , Le Notre Jerome , Sanders Johan P. M. , Bitter Johannes H.
Published: July 2015

Review: 222 refs.
ChemInform Abstract: Pyrazoloquinazolines: Synthetic Strategies and Bioactivities
Authors: Garg Mansi , Chauhan Monika , Singh Pankaj Kumar , Alex Jimi Marin , Kumar Raj
Published: July 2015

Review: 112 refs.
ChemInform Abstract: Quinoxaline, Its Derivatives and Applications: A State of the Art Review
Authors: Pereira Joana A. , Pessoa Ana M. , Cordeiro M. Natalia D. S. , Fernandes Ruben , Prudencio Cristina , Noronha Joao Paulo , Vieira Monica
Published: July 2015

Review: [63 refs.
ChemInform Abstract: Some Recent Developments in Surface and Interface Design for Photocatalytic and Electrocatalytic Hybrid Structures
Authors: Bai Song , Xiong Yujie
Published: July 2015

Review: 68 refs.
ChemInform Abstract: A Review of the Synthesis of α‐Carbolines
Authors: Wadsworth Andrew D. , Naysmith Briar J. , Brimble Margaret A.
Published: July 2015

Review: 61 refs.
ChemInform Abstract: From Structure to Function via Complex Supramolecular Dendrimer Systems
Authors: Sun Hao‐Jan , Zhang Shaodong , Percec Virgil
Published: July 2015

Review: [55 refs.
ChemInform Abstract: Hyperbranched Polyphosphates: Synthesis, Functionalization and Biomedical Applications
Authors: Liu Jinyao , Huang Wei , Pang Yan , Yan Deyue
Published: July 2015

Review: 50 refs.
ChemInform Abstract: From 1 → 3 Dendritic Designs to Fractal Supramacromolecular Constructs: Understanding the Pathway to the Sierpinski gasket
Authors: Newkome George R. , Moorefield Charles N.
Published: July 2015

Review: 76 refs.
ChemInform Abstract: Applications of Ferrocenium Salts in Organic Synthesis
Authors: Toma Stefan , Sebesta Radovan
Published: July 2015

Review: [70 refs.
ChemInform Abstract: Ionic Liquid/Water Mixture Promoted Organic Transformations
Authors: Reddy Pedavenkatagari Narayana , Padmaja Pannala , Subba Reddy Basireddy V. , Rambabu Gundla
Published: July 2015

Review: 150 refs.
ChemInform Abstract: Bioactive Nucleoside Analogues Possessing Selected Five‐Membered Azaheterocyclic Bases
Authors: Zeidler Joanna , Baraniak Dagmara , Ostrowski Tomasz
Published: July 2015

Review: 131 refs.
ChemInform Abstract: Bioactive Benzofuran Derivatives: A Review
Authors: Khanam Hena , Shamsuzzaman Shamsuzzaman
Published: July 2015

Review: 182 refs.
ChemInform Abstract: Targeting G‐Quadruplex Nucleic Acids with Heterocyclic Alkaloids and Their Derivatives
Authors: Xiong Yun‐Xia , Huang Zhi‐Shu , Tan Jia‐Heng
Published: July 2015

Review: 140 refs.
ChemInform Abstract: Benzotriazole: An Overview on Its Versatile Biological Behavior
Authors: Briguglio I. , Piras S. , Corona P. , Gavini E. , Nieddu M. , Boatto G. , Carta A.
Published: July 2015

Review: 317 refs.