bluuebunny/crossref_metadata_2025 huggingface dataset:
Electrocatalytic O2 Reduction by an Organometallic Pd(III) Complex via a Binuclear Pd(III) Intermediate
Authors: Sinha Soumalya , Mirica Liviu M.
Published: January 2021

The development of electrocatalysts for the selective O2-to-H2O conversion, the O2 reduction reaction (ORR), is of great interest for improving the performance of fuel cells. In this context, molecular catalysts that are known to mediate the 4H+/4e– reduction of O2 to H2O tend to be marred by limited stability and selectivity in controlling the multi-proton and multi-electron transfer steps. Thus, evaluation of new transition metal complexes, including organometallic species, for ORR reactivity could uncover new molecular catalysts with improved properties. We have previously reported the synthesis and characterization of various organometallic PdIII complexes stabilized by the tetradentate ligand N,N′-di-tert-butyl-2,11-diaza[3.3](2,6)pyridinophane (tBuN4). These complexes were shown to react with O2 and undergo oxidatively-induced C–C and C–heteroatom bond formation reactions in the presence of O2. These O2-induced oxidative transformations prompted us to evaluate the ORR reactivity of such organometallic Pd complexes, which to the best of our knowledge has never been studied before for any molecular Pd catalyst. Herein, we report the ORR reactivity of the [(tBuN4)PdIIIMeCl]+ complex, under both homogeneous and heterogeneous conditions in a non-aqueous and acidic aqueous electrolyte, respectively. Cyclic voltammetry and hydrodynamic electrochemical studies for [(tBuN4)PdIIIMeCl]+ revealed the electrocatalytic reduction of O2 to H2O proceeds with Faradaic efficiencies (FE) of 50-70% in the presence of acetic acid (AcOH) in MeCN. The selectivity toward H2O production further improved to a FE of 80-90% in an acidic aqueous medium (pH 0), upon immobilization of the molecular catalyst onto edge plane graphite (EPG) electrodes. Analysis of electrochemical data suggests the formation of a binuclear PdIII intermediate in solution, likely a PdIII-peroxo-PdIII species, which dictates the thermochemistry of the ORR process for [(tBuN4)PdIIIMeCl]+ in MeCN, and thus being a rare example of a bimolecular ORR process. The maximum second-order turnover frequency TOFmax(2) = 2.76 x 108 M–1 sec–1 was determined for 0.32 mM of [(tBuN4)PdIIIMeCl]+ in the presence of 1 M AcOH in O2-saturated MeCN with an overpotential of 0.32 V. By comparison, a comparatively lower TOFmax(2) = 1.25 x 105 M–1 sec–1 at a higher overpotential of 0.8 V was observed for [(tBuN4)PdIIIMeCl]PF6 adsorbed onto EPG electrodes in O2-saturated 1 M H2SO4 aqueous solution. Overall, reported herein is a detailed ORR reactivity study using a novel PdIII organometallic complex and benchmark its selectivity and energetics toward O2 reduction in MeCN and acidic aqueous solutions.
Perception on clinical pharmacy services in a private hospital in Yogyakarta, Indonesia
Authors: Nurul Maziyyah  , Mustika Restriyani
Published: January 2021

Clinical pharmacist in Indonesian hospitals has begun to be recognized as an essential part of the healthcare team along with physicians, nurses and other healthcare professionals. While recognition is still on the way, the implementation of clinical pharmacy services is still limited. This could occur because of various factors, one of which is the lack of interprofessional collaboration. Interprofessional collaborations with other healthcare provider are necessary for a pharmacist to implement their clinical services. Hence, health professionals' perception of clinical pharmacy services would give a contribution to developing strategies for the service in the hospital. This study aims to determine perceptions of health professionals in a private hospital in Yogyakarta, Indonesia, on clinical pharmacy services. A total of 96 nurses and 17 physicians were given a questionnaire with items related to clinical pharmacy services. The result showed that health professionals had a positive perception of the role of the pharmacist in clinical pharmacy service with a total mean score of 0.83. Relationship between respondents' characteristic and their perceptions showed that nurses' workplace (ward) had a significant effect on their perceptions (p<0.05). In contrast, characteristics of age, gender, profession, length of work experience, and interaction intensity with the pharmacist did not reveal significant effect.
The Advantages of In situ Gel from Every Different Formulation
Authors: Iyan Sopyan  , Wulan Intani  , Insan Sunan K S  , Cikra Ikhda N H S
Published: January 2021

The in situ gel system is one of the polymer-based solutions that show the sol phase transition to gel. In addition to being used to improve bioavailability, this gel is also used to make the drug increase the residence time in the area of ​​use, so that it can provide maximum effectiveness via enhancing of per cent permeation, The use of in situ gel, usually used in ocular administration of drugs, for the treatment of cancer, administration of drugs in the vaginal, rectal, topical, oral, and any route administration. There are many formulations of in situ gel formation that are used for medicinal preparations for many purposes, with different lengths of stay. Searching for articles is done online, browsing the PubMed and Google scholar site with the keyword "Formulation In situ Gel". The fourty articles used, there were 40 in situ gel formulations with gelling agents and also different uses. The purpose of this article review is to look at the superiority of in situ gel formulations and to compare various in situ gel formulations studied from 40 articles used, so that it can be seen which formulation is most often used and has a good effect on drugs preparations.
COVID-19: HOW THE CLOSURE OF THE UNIVERSITY OF BARISHAL IMPACTS ON THE STUDENTS
Authors: Gazi Abdul Karim
Published: January 2021

The COVID-19 brings a lot of problems, signalling everyone is affected by this pandemic more or less. In this process, almost every country declared the closure of the academic institutions what created more pressures than ever on the students, especially Bangladesh.
COVID-19 PANDEMIC: BOTH A BLESSING AND CURSE
Authors: Apum Apilang
Published: January 2021

The novel Corona virus out broke at Wuhan city in China, as we know, in late December 2019. Since then, it has been spreading its egregious wings all over the world.
Analisis Human Capability dan Social Capability Pada Panti Sosial di Kalimantan Selatan
Authors: Wahyu Wahyu , Azkia Laila
Published: January 2021

Penelitian ini menggali tentang usaha-usaha peningkatan kesejahteraan sosial yang ada di Kalimanan Selatan. Peneliti menganalisis usaha-usaha peningkatan kesejahteraan sosial yang juga meningkatkan peningkatan kemampuan manusia dan kemampuan sosial khususnya pada Panti sosial yang ada di Kalimantan Selatan. Kemampuan manusia dilihat dari aspek pendidikan, keterampilan dan kesehatan. Segi kemampuan sosial dilihat dari adanya aspek kepemimpinan, relasi-relasi yang dilandasi kepercayaan, nilai-nilai yang dipegang teguh, dan mengembangkan jaringan sosial. Penelitian ini menggunakan metode penelitian kualitatif dengan metode pengumpulan data berupa wawancara, observasi dan dokumentasi. Lokus penelitian ini adalah 5 Panti Sosial yang ada di Kalimantan Selatan, yaitu Panti Panti Sosial Bina Laras (PSBL) Budi Luhur, Panti Sosial Bina Wanita (PSBW) Melati, Panti Sosial Bina Netra (PSBN) Fajar Harapan, Panti Sosial Tresna Werdha (PSTW) Budi Sejahtera, dan Panti Sosial Bina Remaja (PSBR) Budi Sejahtera. Hasil dari penelitian ini adalah bahwa kemampuan sosial berupa pendidikan, keterampilan dan kesehatan memang menjadi progam panti. Tetapi, pendidikan yang dimaksud adalah pendidikan formal. Tujuan dari program adalah meningkatkan kemandirian serta produktifitas penerima manfaat, meskipun ada panti yang memberikan program tersebut sekedar untuk mengisi waktu luang selama di panti. Sedangkan kemampuan sosial dalam hal aspek pengembangan jaringan sosial belum menjadi program utama di panti. Sehingga klien keluar dari panti belum memiliki jaringan sosial yang bisa dimanfaatkan.
Analisis Sosial Potensi Pariwisata Budaya “Uma Ncuhi” Mbawa
Authors: Anwar Anwar
Published: January 2021

Rumah Ncuhi atau biasa disebut uma leme secara manifestasi merupakan tempat lahirnya   nilai- nilai sosial, nilai-nilai estetika, religi, norma dan budaya. Sehingga untuk menjamin keberlanjutan dari nilai-nilai luhur  yang diwarisi oleh nenek moyang  sehingga  dapat membentuk karakter generasi, maka generasi penerus sebagai pewaris budaya harus menjaga dan merawat budaya rumah  adat,  tardisi  dan  nilai-nilai  luhur  ini,  dijadikan  sebagai  kekayaan  budaya masyarakat Mbawa. Potensi budaya tersebut akan sangat menunjang bagi wisata Uma Ncuhi untuk itu perlu adanya analis lebih lanjut terkait dengan penganggalian potensi wisata yang ada di Desa Mbawa lebih khususnya dan Kecamatan Donggo  pada umumnya.Jenis penelitian deskriptif dengan pendekatan kualitatif. Tempat penelitian di Desa Mbawa Kecamatan Donggo  Kabupaten Bima. Subjek penelitian masyarakat Desa Mbawa, pemerintah desa Mbawa, tokoh pemuda dan tokoh adat di desa Mbawa. Teknik pengumpulan data menggunakan observasi, wawancara dan dokumentasi. Keabsahan data menggunakan triangulasi sumber. Teknik analisis data dengan pengumpulan data, reduksi data, penyajian data, dan kesimpulan.Objek wisata utama Uma Ncuhi biasa atau sebut uma leme oleh orang Mbawa rumah ini berbentuk kerucut dan bentuk bangunan dari atap dan dinding terbuat dari alang-alang. Selain itu terdapat pula objek wisata penunjang diantaranya 1) Raju adalah sebuah  kegiatan adat masyarakat desa Mbawa yang dilakukan  sebelum memulai musim tanam sebagai tanda untuk mengusir hama yang menggangu tanaman warga. 2) Karawi rasa adalah kegiatan yang dilakukan di Uma Ncuhi oleh masyarakat dan para tetua adat untuk menghindari bala bencana. 3) Tari kalero adalah tari yang disajikan oleh para wanita dari kalangan masyarakat Mbawa untuk menyambut tamu dari luar daerah. 4) Tari toja/mpisi adalah tari yang biasa di sebut juga dengan tari kerasukan yang dilakukan oleh para laki-laki ketika menghadapi musuh.Dari penelitian ini bisa didapatkan bahwa pengembangan obyek wisata budaya Uma Ncuhi masih belum dikelolah dengan maksimal. Perlu sebuah kerja sama antar pemangku kepentingan untuk mengembangkannya. Selain itu juga perlu adanya payung kebijakan untuk mengembangkan. Peran masyarakat menjadi sangat penting, karena masyarakat merupakan pihak yang sangat mengerti dan mengetahui keberadaan obyek tersebut. sehingga pariwisata dengan potensi yang ada di objek wisata Uma Ncuhi harus dikelolah dengan berbasis masyarakat. Peran pemerintah adalah meningkatkan kapasitas SDM atau pengelola dengan melakukan pelatihan-pelatihan.
A efetivação da soberania alimentar na perspectiva do desenvolvimento sustentável
Authors: Ferreira Rui Miguel Zeferino , Pereira Leonardo Gomes , Oliveira Bruno Bastos de
Published: January 2021

O objetivo do presente artigo é analisar o tema da soberania alimentar, sob a perspectiva do desenvolvimento sustentável e dos novos valores biocêntricos. Pretende-se, dessa forma, analisar formas de resistência do cidadão frente às violações ao efetivo exercício do direito à alimentação. Por meio do método hipotético-dedutivo, utilizou-se a pesquisa bibliográfico-documental, com estudos sobre direito à alimentação e soberania alimentar; desenvolvimento agrícola, crises da agricultura e as suas consequências sociais; agropecuária, danos ambientais e os malefícios do consumo de carne para a saúde humana; desenvolvimento sustentável, decrescimento, biocentrismo e aptidão cultural da sociedade para concretizá-los. Concluiu-se que o deslocamento do poder político-estatal para o mercado é corolário da pós-democracia e do discurso desenvolvimentista tradicional, que se mostra incompatível com o exercício pleno do direito à alimentação, à soberania alimentar e com o direito à saúde.
Questões candentes da reforma trabalhista de 2017: percepções e realidade do Tribunal Regional do Trabalho da 1ª Região
Authors: Hartmann Ivar A. M. , Fragale Filho Roberto Da Silva , Abbas da Silva Lorena
Published: January 2021

Esta pesquisa tem como objetivo verificar o grau de compatibilidade entre a percepção subjetiva dos magistrados do TRT/RJ sobre aspectos da dinâmica do processo trabalhista e as modificações trazidas pela Lei nº 13.467/2017. Um survey online foi distribuído entre os magistrados do Tribunal Regional do Trabalho da 1ª Região (TRT/RJ) abordando questões sobre litigiosidade, carga de trabalho, acesso gratuito à justiça e honorários de sucumbência. A investigação foi pautada nas seguintes indagações: se uma mudança em relação à litigiosidade, e consequentemente à carga de trabalho individual, foi percebida pelos magistrados e pode ser constatada em nível institucional; e se a opinião dos magistrados é compatível com as mudanças promovidas pela reforma da CLT quanto ao benefício da justiça gratuita e à sistemática dos honorários de sucumbência. As respostas dos magistrados indicam uma percepção da diminuição da litigiosidade após a reforma trabalhista, apesar da manutenção da carga de trabalho. Ademais, verificou-se que as percepções subjetivas dos magistrados sobre o acesso gratuito à justiça e a cobrança de honorários sucumbenciais são compatíveis com as alterações realizadas pela Lei nº 13.467/2017.
As forças sociopolíticas e o processo de desenvolvimento nas áreas em transição
Authors: Cavalcante Belo Manoel Alexandre
Published: January 2021

O artigo trata do processo de desenvolvimento nas áreas em transição (sistemas transicionais, subdesenvolvidos ou emergentes), identificando estratégias possíveis de superação dos obstáculos que impedem a realização de suas aspirações. Para tanto, detém-se sobre a programação do desenvolvimento, sublinhando os atores que, na sua dimensão nacional e internacional, podem contribuir efetivamente para a concretização do processo.

Palavras-chave: Dedsenvolvimento. Estratégias. Políticas públicas. Democracia participativa. Globalização.
Para melhor entender a interseção existente entre o direito e a economia
Authors: Lucena Glauber
Published: January 2021

O presente texto tem como cerne apresentar algumas linhas sobre a importante relação que existe entre o Direito e a Economia. Nos tempos atuais, essas duas ciências sociais têm se interpenetrado de uma forma tal que fez surgir dentre os ramos da Jurisprudência nova disciplina, o direito econômico. Desta feita, procura-se apresentar os parâmetros para essa intersecção e ao final tecer alguns comentários sobre a chamada “Análise Econômica do Direito” (AED).

Palavras-chave: Direito. Economia. Análise econômica do direito.
Considerações sobre a responsabilidade civil por delito fiscal no direito espanhol
Authors: Sanz Díaz-Palacios José Alberto
Published: January 2021

Na Espanha, há previsão normativa que quando se comete um delito fiscal, a dívida tributária deve ser exigida a título de responsabilidade civil. O presente artigo destaca a existência de argumentos jurídicos contrários à tese da responsabilidade civil por delito fiscal. Além disso, cabe denunciar a dualidade de prazos de prescrição tributária e penal como elemento perturbador do sistema tributário espanhol, pois permite exigir via responsabilidade civil “ex delicto” uma dívida tributária já prescrita.

 

Palavras-chave: Responsabilidade civil. Delito fiscal. Direito espanhol.
As reformas econômicas no estado brasileiro pós-constituição federal de 1988: uma proposta desenvolvimentista
Authors: Urquiza Baracho Hertha , Farias Souza Jacyara
Published: January 2021

Este artigo analisa a influência das reformas econômicas que perpassaram o ordenamento jurídico brasileiro após a Constituição Federal de 1988 e mudaram as suas feições tencionando fomentar o desenvolvimento econômico. Pontua-se em pesquisa bibliográfica e interdisciplinar, a partir dos principais teóricos que abordaram a temática, especialmente as contribuições para a definição de Estado Social, e a influência da globalização como aporte marcante às reformas econômicas dos anos 90 e início do século XXI.

Palavras-chave: Reformas econômicas. Globalização. Desenvolvimento econômico.
La protección de las personas con discapacidad a través del sistema tributario en el derecho español
Authors: Nieto Montero Juan José
Published: January 2021

Este trabajo realiza una aproximación a las soluciones que ha adoptado el ordenamiento jurídico español en el ámbito de la protección de las personas con discapacidad a través del instrumento tributario. Para ello, se comienza por realizar una reflexión sobre el fundamento de esta utilización extrafiscal del tributo y por valorar el fundamento constitucional de la misma. Posteriormente, se entra en las normas contempladas por cada uno de los impuestos del sistema, ofreciendo una visión completa de la solución existente.

Palabras clave: Tributario. Personas con discapacidad. Tributo extrafiscal.
DIREITOS HUMANOS E AUTONOMIA DA VONTADE DA MULHER: A LIBERDADE SEXUAL E REPRODUTIVA E A PROBLEMÁTICA DO ABORTO
Authors: De Moraes Souza Machado Carvalho Joana , De Sousa Carvalho Valéria
Published: January 2021

Questão tormentosa é a que trata da legalização do aborto, pois envolve direitos da mais alta complexidade, como o direito à vida, malgrado, atualmente, se fale que não há mais direito fundamental de caráter absoluto. A discussão gira em torno de duas fortes concepções: de um lado, as feministas, chamadas de liberais; e de outro, os conservadores, liderados por concepções religiosas. Entretanto, nenhuma das duas correntes defende o aborto de forma absoluta e incondicional. Na ordem internacional, o aborto tem sido discutido na seara dos direitos de liberdade sexual e reprodutiva.
PANORAMA DA TUTELA JURISDICIONAL COLETIVA NO BRASIL E A NECESSÁRIA PREVALÊNCIA DE TÉCNICAS INIBITÓRIAS
Authors: Silva Nunes Leonardo
Published: January 2021

Durante as últimas quatro décadas, observou-se notável desenvolvimento do estudo dos direitos ou interesses coletivos, gênero do qual faz parte a espécie “direitos difusos”. Tais direitos, desde que positivados pelo legislador, refletem a evolução da sociedade, seus anseios e expectativas, impulsionada pelo fenômeno da coletivização e massificação das relações sociais e jurídicas. Para torná-los efetivos, é preciso coibir a prática de atos contrários ao direito, exigindo-se da jurisdição uma atuação eminentemente preventiva.
INSTRUMENTOS DE TUTELA EFETIVA E EFICAZ NA GESTÃO DO MEIO AMBIENTE
Authors: Ubaldo Rech Adir
Published: January 2021

Os fundamentos legais de proteção do meio ambiente, previstos na nossa Constituição, são excelentes. No entanto, a profusão de normas ambientais tem gerado mais conflitos do que soluções. Verifica-se que a ocupação dos espaços, por conta das atividades humanas e econômicas, continua ocorrendo, e a degradação ambiental é cada vez mais uma realidade. O modismo na produção de Direito Ambiental, sem efetividade e sem eficácia, necessita ser repensado, pois a questão ambiental é mais científica do que política.

Palavras-chave: Profusão de normas ambientais. Efetividade e eficácia. Construção científica. Zoneamento ambiental e urbanístico.
OS SERVIÇOS PÚBLICOS E AS ATIVIDADES ECONÔMICAS NA CONSTITUIÇÃO FEDERAL DE 1988
Authors: Nogueira de Queiroz Julian
Published: January 2021

O presente artigo tem por objetivo traçar as diretrizes delineadoras da distinção entre serviços públicos e atividades econômicas em sentido estrito, bem como estabelecer as premissas básicas do regramento jurídico dispensado a cada uma dessas modalidades, nos moldes do regime jurídico traçado pela Constituição Federal.

Palavras-chave: Serviço público. Atividades econômicas. Constituição Federal.
PAPEL DO MINISTÉRIO PÚBLICO DO TRABALHO NA EFETIVAÇÃO DO TRABALHO DECENTE DOS TRABALHADORES TERCEIRIZADOS
Authors: Macena de Araújo Jailton , Denise Gosson Barbosa Bruna
Published: January 2021

O presente artigo tem o objetivo de apresentar a forma de atuação do Ministério Público do Trabalho como garantidor dos direitos dos trabalhadores terceirizados. É nesse sentido que surge a preocupação das relações laborais sob uma perspectiva jurídico social, a qual eleva os princípios constitucionais que protegem o trabalhador, garantindo a realização da ideia de trabalho decente. Assim, proporciona a essas relações que nascem fragilizadas a garantia para que o empregado terceirizado não sofra discriminação e tratamento diferenciado, em virtude da orientação constitucional de isonomia entre trabalhadores efetivos e terceirizados. Em razão da determinação constitucional de promoção da igualdade, possibilita-se que tenha o Ministério Público do Trabalho, dentre as suas atribuições, o dever de proteger os direitos dos trabalhadores, combatendo a terceirização ilícita e proporcionando um meio ambiente do trabalho saudável, através do cumprimento das suas funções institucionais, utilizando-se de Termos de Compromisso de Ajuste de Conduta, propondo Ação Civil Pública e Ações de Execução, dentre outras medidas.

Palavras-chave: Terceirização. Trabalho Decente. Ministério Público do Trabalho.
A INTERFERÊNCIA BIOPOLÍTICA NA DELIMITAÇÃO LEGAL DA IDADE AVANÇADA: UMA ANÁLISE À LUZ DO BENEFÍCIO DE PRESTAÇÃO CONTINUADA (BPC)
Authors: Do Nascimento Silva Luciano , Brito Nunes Diniz Matheus
Published: January 2021

O presente artigo estuda as implicações do conceito agambeniano de biopolítica sobre as mais diversas esferas da sociedade brasileira, mais especificamente nas ações públicas direcionadas aos idosos por meio da Assistência Social. A demografia enquanto ciência se apresenta como instrumento essencial à Administração Pública que, com base no desenho etário nacional, define um critério etário de acesso ao Benefício de Prestação Continuada para os idosos com base em vetores puramente econômicos, e não biológicos ou médicos.

Palavras-chave: Idade avançada. Demografia. Biopolítica. Assistência Social. Benefício de Prestação Continuada.
OS LIMITES DO ESTADO NA PROMOÇÃO DO DESENVOLVIMENTO: DEMOCRACIA, DIREITOS HUMANOS E GLOBALIZAÇÃO
Authors: Barroso Fortes Gabriel , Marcilio Pompeu Gina
Published: January 2021

Buscou-se no trabalho analisar as relações entre direitos humanos, democracia e desenvolvimento, destacando-se o papel promotor do Estado nessa conjuntura. O objetivo foi identificar os limites à atuação estatal na persecução desses preceitos, que traduzem compromissos da comunidade internacional. A metodologia da abordagem é qualitativa, descritiva e exploratória, lastreada em bibliografia.

Palavras-chave: Desenvolvimento humano. Democracia. Globalização.
METHODS OF FORECAST CALCULATION OF GROUND WATER BACKWATER IN THE ZONE OF HYDRAULIC STRUCTURES INFLUENCE
Authors:   Timirâzevskaâ selʹskohozâjstvennaâ akademiâ, KARPENKO N.P. , SHIRYAEVA M.A.
Published: January 2021

The purpose of the work is to consider methods for calculating the forecast of groundwater backwater in the zone of influence of hydraulic structures. The analysis of analytical dependences of calculation of the forecast of groundwater backwater for various calculation schemes is carried out. For a homogeneous scheme of the geofiltration structure, a numerical model is proposed and a computational program for calculating the groundwater backwater is developed. It allows calculating the groundwater backwater from the channel at any time in the discrete mode. To simplify the solution of the problem of calculating the groundwater backwater, a computer program was created in the programming language Phyton Version 8.3 which quickly solves this hydrogeological problem. A possible range of geofiltration parameters is proposed for calculating the groundwater backwater near main channels. The adaptation and implementation of the software model was carried out for a specific object – the Bolshoy Stavropol channel-5, for which forecast calculations were made. The results of predictive calculations of groundwater backwater are the basis for the assessment of areas of possible flooding – the territory within which the level of ground water increases as a result of their backup by a hydraulic structure.
DEVELOPMENT OF PROGRAMS FOR SOLVING TASKS IN THE FIELD OF ENVIRONMENTAL PROTECTION ON WATER CATCHMENT AREAS
Authors:   Timirâzevskaâ selʹskohozâjstvennaâ akademiâ, NAUMENKO N.O. , FEDOTOVA E.V.
Published: January 2021

The purpose of this work is to develop software for calculating maximum permissible discharges and methods for assessing the overgrowth of water bodies with higher aquatic plants using the publicly available Google Earth program. In this paper, research has been carried out to improve the environmental monitoring system in catchment areas. A new approach is proposed for calculating the maximum allowable discharge for the current volume of water in the reservoir at a specific time. To implement the approach, software has been developed in which calculations are made to determine the value based on the actual volume of water in the Rybinsk reservoir based on the date of the expected discharge of pollutants from enterprises and the current content of pollutants in the water. A method has been developed for assessing the overgrowth of water bodies by higher aquatic plants using the publicly available Google Earth program, which will make it possible to make a forecast of siltation of reservoirs based on the degree of overgrowth. On the basis of the program Google Earth the dynamics of overgrowing of the lake Bezdonnoe is determined on the basis of space images for the 2013, 2015 and 2019 year relative to the 2009 year.
ANDRONYK STEPOVYCH KYIV PRIVATE GYMNASIUM: ESTABLISHMENT AND FUNCTION PECULIARITIES
Authors: Kukhto Artem
Published: January 2021

The article studies the process of establishment of Andronyk Stepovych Kyiv Private Boys Gymnasium in 1906–1913s. The analysis is made on the materials of archival documents of the funds of Manuscript Institute of Vernadsky National Library of Ukraine. The problems that Anronyk Stepovych, the founder of the institution, faced are indicated. The features of the functioning of the gymnasium and its place in the educational process of Kiev at the beginning of the 20th century are shown. Having founded a gymnasium, Andronyk Stepovych tried to improve the educational level of the youth in the region. Special efforts were aimed at attracting children from low-income families to the educational process. Realizing this plan, he had to overcome many organizational, administrative, material, and other difficulties. The introduction of self-management in the institution at the level of teachers and students was one of the important tasks that the gymnasium set itself. However, the tough and inconsistent policy of the Ministry of Public Education did not allow to do this as well as prohibited any independence for private educational institutions. In addition, every year the Kyiv private gymnasium lost a number of privileges, which made the work of the gymnasium impossible. The management and staff of Kyiv educationaldistrict body with their belated orders, meticulous inspections brought the gymnasium to almost complete destruction. As a result, the gymnasium operated in 1906–1913. Over the years, more than a thousand children acquired education at the educational institution where by Andronyk Stepovych Kyiv Private Boys Gymnasium made its contribution to the growth of the number of educated youth of Kyiv region.
Violent Extremism: A Challenge for Pacific Feminism
Authors: Magallón Portolés Carmen
Published: January 2021

The right of women to participate in peace processes was finally recognised and promoted by the international community in UN Security Council Resolution 1325/2000. This victory for reason was a long time coming. Diverse women thinkers and groups began pondering the issue over a century ago and they followed the path of anti-war initiatives. It is they who sowed the seeds of Pacifist Feminism. This participation has led to various achievements when it comes to: starting negotiations; resuming negotiations after stalemate; extending agreements; broadening the issues addressed; taking gender into account. Over the last few decades, armed violence against the population has widened and shifted in scope: most of the active armed conflicts in the world involve home-grown Violent Extremism (VE), which affects both the Global South and North. The paper discusses what the emergence of VE means for Pacifist Feminism, the challenges it poses and the core of the debate, strategiesand action within the context of growing globalised cyber-activism.
SÜRDÜRÜLEBİLİRLİK PERFORMANSINI ETKİLEYEN FİNANSAL VE FİNANSAL OLMAYAN FAKTÖRLER ÜZERİNE BİR ARAŞTIRMA: BIST SÜRDÜRÜLEBİLİRLİK ENDEKSİ ÖRNEĞİ
Authors: ACAR Merve , DURMAZ Şevket , COŞGUNARAS Şafak Nur
Published: January 2021

Küresel gelişmeler çerçevesinde, finansal tablolarda finansal bilgi yanında finansal olmayan bilgilerin raporlanmasına ilişkin paydaşlarca artan talep, entegre raporlama ve sürdürülebilirlik muhasebesi kavramlarının önemini de gitgide arttırmaktadır. Bu çalışmanın amacı, işletmelerin BIST (Borsa İstanbul) Sürdürülebilirlik Endeksine girmesinde etkili olan faktörleri finansal ve finansal olmayan değişkenler üzerinden tespit etmektir. Bu kapsamda, 431 firma-yılı gözlemden oluşan ve 2011-2018 dönemlerini kapsayan veri seti doğrusal ve lojistik regresyon testleri ile analiz edilmiştir. Elde edilen sonuçlara göre, şirketlerin BIST sürdürülebilirlik endeksinde işlem görme durumları üzerinde yönetim kurulu büyüklüğü, yönetim kurulu bağımsızlığı, denetim komitesi bağımsızlığı, denetçi şirketin dört büyük denetim firmasından biri olması, şirket içinde sürdürülebilirlik uygulamalarının var olması ve sorumlu denetçinin yaşı gibi faktörlerin anlamlı pozitif etkiye sahip oldukları gözlemlenmiştir. Bu sonuçların yanında genel müdür cinsiyetinin erkek ve sorumlu denetçi cinsiyetinin ise kadın olduğu işletmelerin daha yüksek bir oranda sürdürülebilirlik endeksinde yer aldığı da elde edilen sonuçlar arasındadır.
KİRALAMA İŞLEMLERİNİN KİRACI TARAFINDAN KGK YENİ HESAP PLANINA GÖRE RAPORLANMASININ TFRS 16 VE BOBİ FRS BÖLÜM 15 KAPSAMINDA İNCELENMESİ
Authors: ARZOVA Sabrı Burak , ŞAHİN Bertaç Şakir
Published: January 2021

Kiralama işlemleri, işletmelerin faaliyetlerinde ihtiyaç duyduğu mal ve hizmetleri karşılaması ve işletmelerin finansal risklerden korunması amacıyla önemli olduğu kadar, işletme çevresinin işletmelerin finansal durumunu değerlendirebilmesi açısından öneme sahiptir. İşletmelerin kiralama işlemlerini raporlama süreci, çevresiyle doğru bir iletişim kurması ve faaliyet sonuçlarını gerçeğe uygun bir şekilde yansıtabilmesini sağlayacaktır. Türkiye’de vergi mevzuatı dışında kiralama işlemlerinin raporlanması konusunda iki adet standart bulunmaktadır. Bu standartlar TFRS 16 Kiralamalar standardı ile BOBİ FRS’nin Kiralamalar başlıklı 15. bölümüdür. Bu çalışmada TFRS 16 ve BOBİ FRS’nin 15. bölümü incelenmiş, bu standartların benzerlikleri ve farklılıkları ortaya konmuş ve son olarak kiracı taraf açısından kiralama işlemlerinin raporlanması bir örnek ile incelenmiştir.
ENTEGRE RAPORLAMADA COVID-19 SALGININA İLİŞKİN VERİLERİN ANALİZİ
Authors: KÖSE Tunç , AĞDENİZ Şafak
Published: January 2021

Günümüzde bilgi kullanıcılarının, taleplerinin karşılanabilmesi amacıyla kurumsal raporlama çerçevesinin de geliştiği görülmektedir. Kurumsal raporlamanın, geleneksel finansal raporlamadan çevresel raporlamaya, sürdürülebilirlik raporlamasından entegre raporlamaya doğru evrildiği görülmüştür. Entegre raporlama, kurumsal raporlamada yaşanan son gelişme olarak karşımıza çıkmaktadır. Kurumların yarattığı değeri, en kısa, öz ve anlaşılır şekilde, bütüncül ve stratejik bir bakış açısı ile paydaşlarına aktarabilme yolu olarak ortaya çıkan entegre raporlama, finansal ve sürdürülebilirlik raporlarının birleştirilmesinin ötesine geçerek, bugün birçok ülkede kullanılan bir raporlama yöntemi haline gelmiştir. Bu kapsamda, tüm dünyayı etkileyen COVID-19 salgınına ilişkin, entegre raporlarda bilgi sunulması gerektiği değerlendirilmektedir. Çalışmanın temel amacı, entegre raporlarda COVID-19 salgının ne şekilde ele alındığının incelenmesidir. Çalışmada, Türkiye’de az sayıda entegre rapor yayınlayan şirket bulunması ve bu şirketlerden ise 5’inin raporlarında salgına yer vermesi sebebiyle Johannesburg Borsa’sına kayıtlı 23 şirketin 2019 yılına ait entegre raporu, içerik analizi kullanılarak incelenmiştir. Araştırma sonucunda, 9 şirketin entegre raporunda salgına ilişkin bilgi verdiği tespit edilmiştir. Bu şirketlerin de genel olarak entegre raporlarında COVID-19 salgınına ilişkin olarak kılavuz ilkeler ve içerik öğelere uyumlu olarak bilgi verdiği görülmüştür.
EFFECTS OF NON-COMPLIANCE TO LLIN AND IPT IN PREGNANCY ON MATERNAL AND NEONATAL MALARIA, AGE AND BIRTH WEIGHTS OF NEONATES AT UYO
Authors: Ikpeze  , Esu
Published: January 2021

Pregnant mothers and children under 5 years are most vulnerable to Plasmodium falciparum malaria in Nigeria. Non-compliance to LLIN and IPT, and resultant maternal and cord blood malaria on neonatal age and birth weights were studied in Uyo, Nigeria between September and October 2013. Peripheral and cord blood from 106 consenting pregnant women were examined for malaria parasites; and their usage of LLIN and IPT ascertained. Ages and weights of resulting neonates were recorded at birth.  Results showed that maternal and neonatal malaria infection rates (IR) were 54.7% (Mean± SD=49.23±26.41) and 45.3% (Mean± SD=40.6±20.6), with indications that maternal immunity increases with parity. Generally 29.2% and 39.6% of all neonates were respectively delivered pre-term and underweight. About 53.8% and 51.9% of the women were non-compliant to LLIN and IPT, respectively; and 91.4% of LLIN non-compliant as well as 94.8% of IPT non-compliant were infected with malaria. We inferred that use of LLIN and IPT would have offered the women protection against malaria. Heat generation, fear of toxic reactions, and difficulty in setting-up LLIN as well as ‘not sick’, fear of abortion, and doubtful efficacy of IPT were among the reasons given by pregnant women for non-compliance. Sustained health education on the use of LLIN and IPT will help to reduce malaria infection and its consequences in Uyo.
EFFECT OF NITROGEN FERTILIZER ON GROWTH, YIELD AND YIELD COMPONENTS OF MAIZE (ZEA MAYS L.) IN DECHA DISTRICT, SOUTHWESTERN ETHIOPIA
Authors: Woldesenbet Mitiku , Haileyesus Asnakech
Published: January 2021

Maize response to high nitrogenous fertilization levels is a means among other means to know maximum productivity, from this perspective, a field nitrogen management trial using five N levels (0, 23, 46, 69 and 92 kg N/ha) with three replications. The study was conducted in 2015 in Decha District, ModyoGomberaKebele of Kaffa Zone, SNNPR State. The experiment was laid out in RCBD. The result of this study indicated that effects of different rates of N fertilizer had influenced the growth and yield components of maize. The tallest plant (360.66 cm) was recorded from the application of 92 kg N ha-1 and the shortest (347.33 cm) from no N application. The ANoVA for the number of kernels per ear showed that the lowest kernels per ear (497.86) were obtained from no N application and the highest kernels per ear (588) were obtained from the application of 92 kg N ha-1 although there was no significant difference between the application of 69 and 92 kg N ha-1. Regarding to ear length the data showed that the longest ear (23.63 cm) was obtained from the application of 92 kg N ha-1. The effect of N on  grain yield indicated that there is no significant difference between the application of 69 and 92 kg N ha-1 even if there is a slight difference on yield. Generally, maximum N fertilization level (92 Kg N/ha) in this study area showed increase in growth and yield components (number of kernels per ear and ear length). However the application of 69 kg N ha-1 seems adequate to get the optimum yield.
EMPLOYING AGENTS IN DESCRIPTIVE MINING
Authors: Sabitha R. , Karthik
Published: January 2021

Agent technology and Data Mining have emerged as two of the prominent areas in information sciences. An effort has been activated towards the interaction and integration between agent technology and data mining which is referred to as “AGENT MINING”. Data Mining is the process of extracting interesting information or patterns from large volumes of data. Agents comprise a powerful technology for the analysis, design and implementation of autonomous intelligent systems that can handle distributed problem-solving, cooperation, coordination, communication, and organization in a multiplayer environment. This agent uses information technology to find trends and patterns in an abundance of information from many different sources. The user can sort through this information in order to find whatever information they are seeking. Intelligent agents are today accepted as powerful tools for data mining in a distributed environment. The interaction and integration between agent and mining has potential to not only strengthen either side, but generate new techniques for developing more powerful intelligence and intelligent information processing systems. This paper discusses how agents are used in the various descriptive models of Data Mining. The various challenges and methodologies are analyzed and it clearly indicates the need for and the promising potential of agent mining for the mutual enhancement of both fields and for the creation of super-intelligent systems. Even though many researchers have been committed, more efforts are required to develop techniques and systems in practical perspectives.
Dıfferent Cultures And Dıfferent Objects: Anish Kapoor
Authors: TAŞCI Fatih
Published: January 2021

yy.’ın ilk çeyreğinde artan bilimsel ve teknolojik gelişmeler insanın içinde bulunduğu durumu yansıtabilmek için kullandığı ifade biçimlerinde farklı bakış açıları geliştirmesini sağladı. Özellikle ikinci dünya savaşı sonrasında hızlı
bir değişime giren dünya halkları içinde bulundukları kaotik durumu, geliştirdikleri düşünce akımları ve teknik gelişmelerle aşmayı başardılar. Sanatçılar içinde bulundukları kaotik durumu fikir ve sanat eserlerine dönüştürmek
için fotoğraf ve türevlerine yöneldiler, fırça yerini elektronlara ve fotonlara bıraktı. Görece uygulanması daha basit görülerek dışlatılmak istense de sanatçıların dehaları ile birlikte yüz yıl gibi bir süreçte vazgeçilmez birer
sanat nesnelerine dönüştüler. 1839 yılı itibarı ile bahsedilmeye başlayan fotoğraf onu takip eden yıllarda geliştirilen yeni görüntüleme teknikleri ile hem bilim hem de sanat dünyasına kapılar açmış oldu. X ışınlarının keşfi ardından
elektron ışımasının karakterize edilebilmesi çıplak gözle görülemeyecek kadar küçük olan nesnelere bu yöntemler ile ortaya çıkarılabilmesini sağladı. Hayranlık uyandıracak derecede şekil, renk ve dokuların ortaya konulması sanatçıların
ilgisini bu yapılar üzerinden ifade biçimleri oluşturmasına itmiştir. Estetikte yeni arayışlara giren Tyurina sanat pratiklerini elektron mikrografileri üzerine yoğunlaştırmıştır. Suyun doğası üzerinde elektron mikrografik tanımlamalarda
bulunarak yaptığı çalışmanın bilimsel birer üretim olmasından ziyade bilimsel elektron mikrografiye estetik bir yaklaşım getirmiştir. Bu makalede elektron mikrografi kavramının tarihsel gelişim süreci ve bu alanda yapılan uygulamalar
araştırılmıştır. İlk mikroskobun gelişimi yapılan mikrografiler tanımlanmış daha sonra fotoğrafın icadı ile fotomikrografinin üzerine yapılan çalışmalar değerlendirilmiştir. Anahtar kelimeler: Elektron Mikrografi, Fotoğraf, Sanat,
SEM,
Eating habits and lifestyle changes during the COVID-19 lockdown: A comparative study (before and during isolation) on the 9 de Julio city (Buenos Aires, Argentina) population
Authors: Miriam Sosa , Paula Cardinal , Eliana Elizagoyen , Graciela Rodríguez , Soledad Arce , M Fernanda Gugole Ottaviano , Victoria Pieroni , Lorena Garitta
Published: January 2021

Following the COVID-19 proliferation beyond China’s borders at the beginning of 2020, containment measures have been taken by different countries around the globe. Citizens were forced to stay at home. Specifically, on March 19th, the Argentine Government decided to implement the “Social, preventive and mandatory isolation”, strategy that unfortunately impacts on the lifestyle, the practise of physical activity and on the nutritional aspect of the population. The aim of this study was analize eating habits and lifestyle changes during the COVID-19 lockdown on the 9 de Julio city, Bs. As., Argentina. The survey was conducted using Google Form. The questionnaire was divided into different sections: sociodemographic data, eating habits, physical activity and concepts and emotions associated with isolation. The research reached 287 responses with a medium socioeconomic level. During isolation, the frequency of purchases decreased. It was observed an increase in the consumption of pasta, bread and cakes. Concerning the physical activity, approximately 70% declared to train before the COVID-19 lockdown, decreased by 13% during the lockdown. Other activities conducted during the COVID-19 lockdown; the most mentioned were cleaning the house, cooking, watching television, series and movies. A percentage greater than 50% of the surveyed population associated the situation of lockdown with positive emotions (share with my family, stay at home); while only 24% associate it with negative emotions (anxiety, anguish, fear). It is expected that most habits will return to normal, however, it would be interesting to know which of those developed, adopted and implemented during lockdown will remain in the new normality.
Metal-carbon mesocomposites application possibilities as the medicine magnetic transport within an organism
Authors: VI Kodolov , VV Kodolova-Chukhontseva , IN Shabanova , NS Terebova
Published: January 2021

The paper is dedicated to the consideration of the metal-carbon mesocomposites application possibilities for the medicine magnetic transport. This trend is determined by correspondent peculiarities of content and structure of mesoscopic composites. The main peculiarities of these nanosized particles are the following: a) the presence of unpaired electrons on the carbon shell; b) the structure of carbon shell from poly acetylene and carbine fragments; c) the atomic magnetic moment of inner metal is equaled to more than 1–3 μB. The creation of reactive mesoscopic materials with regulated magnetic characteristics which can find application as medicine magnetic transport within an organism is very topical. The present investigation has fundamental character. It’s based on the ideas concerning to the change of metal-carbon mesocomposites reactivity. The use is possible as metal-carbon mesocomposites both and they are modified analogously.
Antifungal activity of epecific plant essential oils against fusarium graminearum
Authors: Esma Özsoy , Buket Kesercan , Emre Yörük
Published: January 2021

fusarium graminearum is one of the most popular phytopathogens of cereals worldwide. F. graminearum is the major causal agent of head blight of wheat and barley. Disease-resistant cultivar development, antagonistic microorganism usage and fungicide treatment are the most common strategies in head blight management strategies. However, these methods have some important disadvantages. The use of plant-derived essential oil against F. graminearum seems to be a promising approach due to the recent researches. This review summarizes the potential use of essential oils to fight against F. graminearum.
Distance Diminishes the Effect of Deltamethrin Exposure on the Monarch Butterfly,Danaus plexippus
Authors: Giordano Bryan V. , McGregor Bethany L. , Runkel Alfred E. , Burkett-Cadena Nathan D.
Published: January 2021

The monarch butterfly, Danaus plexippus (Lepidoptera: Nymphalidae), is threatened by substantial loss of habitat, extreme weather events linked to global climate change, and nontarget impacts of broad-spectrum insecticides. To investigate the impact of chronic ingestion of pyrethroids on monarchs, wild-type Florida D. plexippus were reared on milkweed (Asclepias curassavica) that was exposed to ultra-low volume applications of DeltaGard by a truck-mounted fogger, at distances of 25 and 50 m. We observed significant negative impacts on monarchs reared on milkweed at 25 m from the DeltaGard spray route, including significant decreases in survival, and significantly longer development times, compared with untreated controls. Larvae reared on host plants closest to the truck spray route were 3 times more likely to experience a mortality event than the control cohort in trial 1 and 6 times in trial 2. Survival of monarch caterpillars reared on milkweed sprayed at 50 m was not significantly different from controls. For monarchs that survived to adulthood, we did not observe statistically significant differences among cohorts for variables measured. These data demonstrate that ultra-low volume treatments of pyrethroids can result in significant mortality in monarchs, but that the effects diminish with distance from the spray route.
Gynandromorphic Specimens of Culex erythrothorax, Culex pipiens Complex, Culex tarsalis, and Culiseta incidens Collected in Northern San Joaquin Valley, California
Authors: De La Vega Sumiko R. , Smith David J. , Fritz John A. , Lucchesi Eddie F. , Huang Shaoming
Published: January 2021

Gynandromorphic insects bear both male and female characteristics. In mosquitoes, gynandromorphy has been documented in multiple species and it can include many different combinations of sex-specific traits such as plumose or filiform antennae, short or elongated palpi, and male or female terminalia. Here we report 4 gynandromorphic specimens of Culex erythrothorax, Cx. pipiens complex, Cx. tarsalis, and Culiseta incidens collected in the Northern San Joaquin Valley of California. Each of the specimens exhibited heads with female characteristics of short palpi and filiform antennae while displaying fully developed external male terminalia including basistyles and dististyles. The potential implication of gynandromorphism in genetic control of mosquito vectors is discussed.
Residual Activity of Pyriproxyfen Against Mosquitoes in Catch Basins in Northwestern Riverside County, Southern California
Authors: Mian Lal S. , Caranci Angela , Ramos Jesus , Nelson J. C. , Smith Nikia , Van Dyke William , Dhillon Major S.
Published: January 2021

A field study was carried out on the year-long residual activity of the insect growth regulator (IGR) pyriproxyfen (Nylar 0.5G) in comparison with methoprene (Altosid® XRP Pellets) against mosquito developmental stages in catch basins in northwestern Riverside County, southern California. Pyriproxyfen was applied at 75, 100, 125, 150, 175 g per catch basin and methoprene at 3.5 g per catch basin. A total of 80 catch basins (10 per each treatment and 20 for control) were used. Posttreatment observations of catch basins were carried out at weekly intervals, with all pupal collections reared to adults. Mosquito species composition in this study, consisting mostly of Culex species (693), was predominated by Cx. quinquefasciatus (92.8%), followed by Cx. erythrothorax (5.5%), Cx. tarsalis (1.2%), Cx. stigmatosoma (0.3%), and Cx. thriambus (0.2%). Activity of both IGRs was expressed as percent inhibition of adult emergence (% IAE). Data generated on % IAE showed that, like methoprene, pyriproxyfen provided complete control of mosquitoes at 75, 125, and 175 g per catch basin up to 50 wk posttreatment at the Riverside amusement park, whereas its activity against mosquitoes in catch basins treated with 100 g and 150 g at the Eastvale site was short-lived, up to 48 wk. Water samples, bioassayed against laboratory-reared, 4th-stage larvae of Cx. quinquefasciatus 1–2 wk after the 50-wk-long study, showed evidence of significant % IAE (∼50) by pyriproxyfen at the 2 higher rates (125 g, 175 g) used at the amusement park. In conclusion, pyriproxyfen can be used to effectively control mosquitoes in catch basins for 48–50 wk, depending on the rate of application.
Relation between Covid-19 and high capsaicin diets
Authors: Ahmad Gharaibeh  , Mahmoud M. Gharaibeh  , Sahm Gharaibeh
Published: January 2021

Covid-19 in the announced numbers of World Health organisation a significant discrepancy is seen in terms of number of infected cases to the total population in each county and by 1 million populations. It seems to be that having high capsaicin diet can prevent from Covid-19 infection and antiviral immune responses.