bluuebunny/crossref_metadata_2025 huggingface dataset:
ChemInform Abstract: Crystal Structure of α‐TlSm(WO4)2.
Authors: MUMM H.‐C. , MUELLER‐BUSCHBAUM HK. +
Published: May 2016

Single crystals of the title compound are obtained by heating a mixture of Tl2WO4, WO3, and Sm2O3 to 900 °C (5:2:1, Pt crucible, 24 h; the excess tungstate is used as a flux).
ChemInform Abstract: Electrolyte‐Induced Changes in Charge Transport Rates Across the CuInSe2 Interface.
Authors: MENEZES S.
Published: May 2016

The role of electrochemical parameters (particular electrolyte pH) in the formation, composition, and photoconductivity of films on the CuInSe2 surface, and their effect on the charge transfer kinetics and on the quantum efficiency, have been investigated by combining a variety of optoelectrochemical methods.
ChemInform Abstract: Li/MoSe3S Secondary Battery.
Authors: ABRAHAM K. M. , PASQUARIELLO D. M. , MCANDREWS G. F.
Published: May 2016

MoSe3S has been identified as a highly reversible Li insertion cathode material for ambient temp. secondary Li batteries.
ChemInform Abstract: New Iron(II) Spin‐Crossover Complexes with Heterocyclic Amine‐Derived Ligands and STEPS Experiments on Photogenerated Metastable High‐Spin States.
Authors: ADDISON A. W. , BURMAN S. , WAHLGREN C. G. , RAJAN O. A. , ROWE T. M. , SINN E.
Published: May 2016

Cationic complexes (I)‐(IV) are prepared by reaction of ligand and Fe2+ in hot MeOH and isolated as Cl‐, ClO4‐ or BF4‐ salts (yields partially given).
ChemInform Abstract: An Unexpected Course of the Meisenheimer Reaction: Aryl Phosphates in the Reaction of Phosphoryl Chloride with 2,3‐Diphenylquinoxaline‐N1‐oxide.
Authors: NASIELSKI J. , HEILPORN S. , NASIELSKI‐HINKENS R. , GEERTS‐EVRARD F.
Published: May 2016

The influence of experimental conditions (e.g.
ChemInform Abstract: Synthesis of Linear Aliphatic Compounds. Part 3. The Synthesis of Paraffins with Very Long Chains.
Authors: BIDD I. , HOLDUP D. W. , WHITING M. C.
Published: May 2016

The routes from C12 starting materials to the long‐chain paraffins derived in the preceding paper are modified to increase the purities and yields of the intermediates.
ChemInform Abstract: Strained Hydrocarbon Skeletons: Pentacyclo(6.4.0.02,4.03,10.07,9)dodecanes by (2 + 2 + 2)Cycloadditions to Substituted Dihydrobullvalenes.
Authors: KIRCHMEYER S. , DE MEIJERE A.
Published: May 2016

Reaction of the dihydrobullvalenes (Ia)‐(Ic) with tetracyanoethylene (II) yields the title compound (III).
ChemInform Abstract: Base and Acid Catalyzed Reactions of Phenylazo 1‐Naphthyl Ether, a New Reactive Diazoether. Reply to the Kekule Mechanism for the Diazo Coupling Reaction.
Authors: TEZUKA T. , SASAKI K. , ANDO S.
Published: May 2016

Phenylazo 1‐naphthyl ether (I) is cleaved with bases or acids to give the products (II) ‐ (V).
ChemInform Abstract: Synthesis, Stereochemistry and Isomeric Conversions of Tetracyclo(10.3.0.02,607,11)pentadecane.
Authors: VOROB'EVA N. S. , PEKHK T. I. , ZEMSKOVA Z. K. , PETROV AL. A.
Published: May 2016

Condensation of cyclopentylidenecyclopentanone (I) with cyclopentanone (II) according to a known procedure yields tris(trimethylene)benzene (III) whose hydrogenation affords a mixture (IV) of seven stereoisomers.
ChemInform Abstract: Electrophilic Substitution in Indoles. Part 15. The Reaction Between Methylenediindoles and p‐Nitrobenzenediazonium Fluoroborate.
Authors: JACKSON A. H. , PRASITPAN N. , SHANNON P. V. R. , TINKER A. C.
Published: May 2016

The diazonium tetrafluoroborate (II) reacts under aqueous conditions with the di‐indoles (I) to give the azo compounds (III).
ChemInform Abstract: Synthesis and Transformations of Urazoles Derived from 7,7‐Dicarboxynorcaradiene: Formation of 2,4‐Dioxohexahydro‐1,3,5‐triazines by an Unusual Base‐Catalyzed Rearrangement.
Authors: ADAM W. , GRABOWSKI S. , HINZ R. F. , LUCCHINI V. , PETERS E.‐M. , PETERS K. , REBOLLO H. , VON SCHNERING H. G.
Published: May 2016

Reaction of the triene (I) with the dione (II) yields the endo‐urazole (III) (no yield given).
ChemInform Abstract: One‐Pot Synthesis of Diaryl Alkyl Carbinols and Substituted Derivatives Through Carbon Monoxide Insertion Reactions into Aryllithiums.
Authors: VITALE A. A. , DOCTOROVICH F. , NUDELMAN N. S.
Published: May 2016

The diaryl alkyl carbinols (IV) are prepared by carbonylation of phenyllithium (I) in THF in the presence of the alkyl bromides (II).
ChemInform Abstract: Intramolecular Cycloaddition of Azoalkenes Derived from Terminal Alkenoic and Alkynoic Acids.
Authors: GILCHRIST T. L. , WASSON R. C. , KING F. D. , WOOTTON G.
Published: May 2016

The azoalkenes (II), (V) or (VIII) derived from (I), (IV) or (VII) undergo cyclization to give the fused pyridazines (IIIa), (VI) and (IX).
ChemInform Abstract: Pteridines. Part 51. A New and Unequivocal Route to C‐6 Carbon‐Substituted Pterins and Pteridines.
Authors: TAYLOR E. C. , RAY P. S.
Published: May 2016

Reaction of the acetylenes (II) with the bromopyrazine (Ib) gives the 5‐ethynyl derivatives (III) which are cyclized with guanidine hydrochloride (IV) to yield the pteridines (V).
ChemInform Abstract: Synthesis of Macrocyclic Acetals Containing Lipophilic Substituents.
Authors: BRADSHAW J. S. , KRAKOWIAK K. E. , LINDH G. C. , IZATT R. M.
Published: May 2016

Reaction of the alcohols (I) with the aldehydes (II) yields the ditosylates (III), which undergo cyclization with the diols (IV) to give the title compounds (V).
ChemInform Abstract: Phosphorylation of N‐Methyldiacetamide.
Authors: DMITRICHENKO M. YU. , ROZINOV V. G. , DONSKIKH V. I. , DOLGUSHIN G. V. , FESHIN V. P. , KALABINA A. V.
Published: May 2016

N‐Methyldiacetamide (I) reacts with PCl5 to give the bisphosphorylated diene (III) which cyclizes to produce the 1,4‐azaphosphorinium salt (IV) upon heating.
ChemInform Abstract: Synthesis and Isomerization of 2‐Hydroxyalkyloxy‐2‐oxo‐1,3,2‐dioxaarsolanes.
Authors: GAMAYUROVA V. S. , NIYAZOV N. A. , KHALITOV F. G. , ARKHIPOV V. P.
Published: May 2016

The trialkyl arsenates (I) and (IV) react with the diols (II) to give the dioxaarsolanes (III).
ChemInform Abstract: Ultrasound in Organic Synthesis. Part 12. In situ Generation and Uses of Butyllithium Reagents in Several Synthetic Reactions.
Authors: EINHORN J. , LUCHE J.‐L.
Published: May 2016

Large‐scale preparation of the lithium amides (III) is performed by treatment of the corresponding amines (I) with lithium and butyl chloride (II) under ultrasonic irradiation.
ChemInform Abstract: Subvalent Group 14 Metal Compounds. Part 10. Syntheses and Structures of Some Bis(metallo)plumbylenes (Pb(Mo(R)(CO)3)2(OC4H8)) (R: η‐C5H5, η‐C5H3(SiMe3)2‐1,3, or η‐C5Me5); X‐Ray Crystal Structures of (Pb(Mo(η‐C5Me5)(CO)3)2(OC4H8)) and ((Pb(Mo(η‐C5Me5)(CO)3) (Mo(η‐C5Me5)(CO)2(μ‐CO)))2).
Authors: HITCHCOCK P. B. , LAPPERT M. F. , MICHALCZYK M. J.
Published: May 2016

Treatment of the lead(II) amide (I) with two equiv. of the appropriate Mo hydrides (II) in THF (III) results in the formation of the three‐coordinate Pb(II) complexes (IV) ((IVc) decomposes within 1 d at 25 °C).
ChemInform Abstract: Monometallic, Homo‐ and Hetero‐bimetallic Complexes Based on Redox Active Tris(3,5‐dimethylpyrazolyl)borato Molybdenum and Tungsten Nitrosyls. Part 6. Synthesis and Electrochemistry of Complexes Containing Saturated Heterocyclic Amide Ligands. X‐Ray Crystal and Molecular Structure of ((Mo(NO)(HB(Me2pz)3)Cl)2(NC4H8N)).
Authors: AL OBAIDI N. , HAMOR T. A. , JONES C. J. , MCCLEVERTY J. A. , PAXTON K.
Published: May 2016

The reaction of the appropriate dichloro complexes with an excess of the cyclic amines leads to the coordinatively unsaturated complexes (I).
ChemInform Abstract: Synthesis, Reactions, and Dynamic NMR Studies of η2‐Vinyl Complexes of Molybdenum and Tungsten, (M(η3‐C(CF3)C(CF3)(L‐L))(CF3CCCF3)(η3‐C5H5)) (L‐L: MeCO‐ 2, Me2PS‐ 2, Et2NCS‐ 2, or Me2NCS‐ 2).
Authors: DAVIDSON J. L.
Published: May 2016

Reactions of the bis(hexafluorobut‐2‐yne) complexes (I) with acetate (II), dimethyldithiophosphinate or N,N‐dialkyldithiocarbamates (IV) give adducts which exhibit a bis(alkyne) structure containing a monodentate ligand such as (III) (major product) or an isomeric η2‐vinyl structure (V) in which the ligand forms a bridge between the metal and the η2‐vinyl ligand.
ChemInform Abstract: Heteronuclear Complexes Containing Group 6 Transition Metals; Chemical, Spectroscopic, and Theoretical Studies on Some Binuclear Complexes and the X‐Ray Crystal Structure Determination of (WNi(CO)3(PPh3)2(η5‐C5H5)).
Authors: CARLTON L. , LINDSELL W. E. , MCCULLOUGH K. J. , PRESTON P. N.
Published: May 2016

Reactions of the anions (I) with the Ni complex (II) afford the paramagnetic bimetallic complexes (III).
ChemInform Abstract: Rhodium(I)‐Iron(0) Carbonyl Complexes Containing One Bridging Ph2PCH2PPh2 Ligand, Including the Formation of a Tetranuclear Cluster from a Heterobimetallic Precursor: Crystal Structures of ((OC)4Fe(μ‐Ph2PCH2PPh2)RhCl(CO)) and (Fe2Rh2(μ‐Ph2PCH2PPh2)2(CO)8).
Authors: JACOBSEN G. B. , SHAW B. L. , THORNTON‐PETT M.
Published: May 2016

Treatment of the Fe complexes (I) with the dimer (II) gives the complexes (III) which are converted with lithium acetate to the tetranuclear clusters (IV).
ChemInform Abstract: The Chemistry of Tetraphenylcyclopentadienone Complexes of Ruthenium and Rhodium: The X‐Ray Crystal Structure of (Ru(η5‐C5Ph4OC(O)CH(OMe)Ph)(CO)2Cl).
Authors: BAILEY N. A. , JASSAL V. S. , VEFGHI R. , WHITE C.
Published: May 2016

The title complexes (I) and (V) react with L‐(‐)‐(II) with ligand substitution to give (IIIa) or (VI) rather than to form Schiff‐base complexes.
ChemInform Abstract: Preparation and Spectroscopic Study of Functionally Substituted Cyclopentadienides of Thallium(I), Potassium, Rhodium(I), and Iridium(I).
Authors: ARTHURS M. , AL‐DAFFAEE H. K. , HASLOP J. , KUBAL G. , PEARSON M. D. , THATCHER P. , CURZON E.
Published: May 2016

A 13C and 1H NMR study is carried out on the compounds (I) (some preparations are described).
ChemInform Abstract: Photochemical Synthesis of Halleridone, Hallerone, Rengyol and Derivatives.
Authors: BRETON J. L. , LLERA L. D. , NAVARRO E. , TRUJILLO J.
Published: May 2016

1O2 oxidation of p‐hydroxyphenethyl alcohol (Ia) yields halleridone (II) whereas the same oxidation of the acetate (Ib) leads to the epoxide (III) and hallerone (IV), the latter being transformed to halleridone acetate on standing.
ChemInform Abstract: Selective Doped Polysilicon Growth. Effect of Carbon on the Selective Doped Silicon Film Growth.
Authors: MIENO F. , FURUMURA Y. , NISHIZAWA T. , MAEDA M.
Published: May 2016

It is demonstrated that the selective growth of doped polysilicon is possible when CH4 is introduced in the growth of epitaxial silicon.
ChemInform Abstract: Preparation of Germanium Nitride Films by Low Pressure Chemical Vapor Deposition
Authors: YOUNG A. B. , ROSENBERG J. J. , SZENDRO I.
Published: May 2016

(LPCVD).
ChemInform Abstract: On the Existence of Discrete TeCl‐ 5 Ions.
Authors: SCHOENHERR T. +
Published: May 2016

Solid pentachlorotellurate compounds ATeCl5 (A: Et3NH, Et4N, Bu4N, Ph4P) are prepared by stoichiometric titration of TeCl4 in CH2Cl2 with the corresponding chloride solutions (no yields given).
ChemInform Abstract: Sulfur Compounds. Part 112. The Molecular Composition of Hydrophilic Sulfur Sols Prepared by Acid Decomposition of Thiosulfate.
Authors: STEUDEL R. , GOEBEL T. + , HOLDT G.
Published: May 2016

Hydrophilic sulfur sols, obtained by acid decomposition of Na2S2O3 in water (so‐called Raffo sols) are analytically characterized using chemical analysis, IR and Raman spectra, ion‐pair chromatography, and reversed‐phase HPLC.
ChemInform Abstract: Proton and 13C NMR Studies of cis‐eq‐ and trans‐eq‐Ethylenediamine‐N,N,N′‐triacetatocobalt(III) and cis‐eq‐N‐Methylethylenediamine‐N,N′,N′‐triacetatocobaltate(III). Crystal Structure of NH4cis‐eq‐(Co(ed3a)CN).
Authors: MARICONDI C. , UTSUNO S. , RADANOVIC D. J. , TRIFUNOVIC S. R. , ABOLA J. E. , DOUGLAS B.
Published: May 2016

The complexes (I) and (II) as their K salts are investigated by NMR spectroscopy and compared with the corrresponding nitro compounds.
ChemInform Abstract: Highly Reactive Titanium on Graphite. A Universal Reducing Agent for the Coupling of Carbonyl Compounds to Alkenes.
Authors: FUERSTNER A. + , WEIDMANN H.
Published: May 2016

Titanium on graphite, derived from titanium trichloride and potassium‐graphite, is a universally applicable McMurry reagent for the conversion of the carbonyl (I) and dicarbonyl compounds (IV) to the alkenes (II) or the cycloalkenes (V).
ChemInform Abstract: Halogenation Using Ammonium Polyhalides. Part 5. Iodination of Phenols by Use of Benzyltrimethylammonium Dichloroiodate(1‐).
Authors: KAJIGAESHI S. , KAKINAMI T. , YAMASAKI H. , FUJISAKI S. , KONDO M. , OKAMOTO T.
Published: May 2016

Benzyltrimethylammonium chloride (I) reacts with ICl to give the iodination agent (II) mentioned in the title.
ChemInform Abstract: Reactions of Trimethylsilyl Ketene Acetals with Benzoyl Cyanide and with α‐Keto Esters.
Authors: REDDY C. P. , TANIMOTO S.
Published: May 2016

The ketene acetals (Ia)‐(Ic) react with benzoyl cyanide (II) in the absence of a catalyst to give the iminopropionates (III).
ChemInform Abstract: Synthesis and Properties of Some Silylethynylsilanes. Molecular Structure of Tetrakis(trimethylsilylethynyl)silane.
Authors: SCHMIDBAUR H. , EBENHOECH J. + , MUELLER G. +
Published: May 2016

The silane (VI), a colorless liquid, decomposes above 100 °C with loss of the self‐combustible SiH4.
ChemInform Abstract: 2,4,6‐Tris(bis(trimethylsilyl)methyl)phenyl, a New Sterically Demanding Group for Kinetic Stabilization of Unstable Compounds.
Authors: OKAZAKI R. , UNNO M. , INAMOTO N.
Published: May 2016

1,3,5‐Trimethylbenzene (I) is photochlorinated and then treated with the chlorosilane (III) to produce the tris(disilylmethyl)benzene (IV) which is converted to the corresponding aniline (VI).
ChemInform Abstract: Octabutoxyphthalocyanine, a New Electron Donor.
Authors: WOEHRLE D. + , SCHMIDT V.
Published: May 2016

The preparation of the Zn complex (V) of the title ligand by the "nitrile method" is described in the scheme.
ChemInform Abstract: Synthesis and Crystal Structure of Tris(bis(trimethylsilyl)amido)oxoniobium(V): A Four‐Coordinated Oxo Niobium Precursor.
Authors: HUBERT‐PFALZGRAF L. G. , TSUNODA M. , LE BORGNE G.
Published: May 2016

The reaction of the tetrachloride (I) with an excess of the Li amide (II) leads to O abstraction of the THF ligand and formation of the first non‐chlorine oxoamido‐Nb compound (III).
ChemInform Abstract: Synthesis, Spectroscopic Studies, and Crystal and Molecular Structure of Bismuth Hexacyanoferrate(III) Tetrahydrate, BiFe(CN)6·4 H2O.
Authors: MULLICA D. F. , PERKINS H. O. , SAPPENFIELD E. L.
Published: May 2016

The title complex is obtained by reaction of K3(Fe(CN)6) with Bi(NO3)3 in aqueous solution at pH 3. This complex is characterized by IR spectroscopy, analytic methods, and an X‐ray structure analysis (space group P21/m, Z=2).
ChemInform Abstract: Thermolysis of Re2(CO)10‐n(P(C6H5)3)n (n = 1, 2).
Authors: HAUPT H.‐J. , BALSAA P. , FLOERKE U. +
Published: May 2016

Thermolysis of the bis(phosphine) complex (I) containing axial phosphines gives six products of the two types (II) and (III).
ChemInform Abstract: Reaction of 1,2‐Diferrocenylcyclopropanes with Triphenylcarbenium Tetrafluoroborate.
Authors: KLIMOVA E. I. , PUSHIN A. N. , SAZONOVA V. A.
Published: May 2016

The bisferrocenylcyclopropane (I) (E,Z‐mixture) reacts with tritylium tetrafluoroborate (II) to give the allyl cation (III).
ChemInform Abstract: Calorimetric Study on Oxygen Addition to Cobalt(II) Complexes with Tris(2‐aminoethyl)amine and 3,7‐Diazanonane‐1,9‐diamine.
Authors: CABANI S. , CECCANTI N. , TINE M. R.
Published: May 2016

Through spectrophotometric and potentiometric measurements it is shown that in aerated aqueous solution of (I) and (II) the complex ion (III) is totally formed, whereas in solutions containing (IV) only (V) is observed.
ChemInform Abstract: Dicopper(I) Complexes Containing Intramolecular 1,2‐Diaza Bridging Ligands. Behavior of the Dicopper Site in the Dehydrogenation of Hydrazobenzene. Crystal Structure of (Cu2L2(pydz)2) (ClO4)2.
Authors: DREW M. G. B. , YATES P. C. , TROCHA‐GRIMSHAW J. , LAVERY A. , MCKILLOP K. P. , NELSON S. M. , NELSON J.
Published: May 2016

The macrocyclic ligands of the complexes investigated were synthesized by template Schiff base condensation of 2,5‐diformylfuran with the appropriate diamine on Group 2 metal ions.
ChemInform Abstract: Synthesis and Reactivities of trans‐Dioxoosmium(VI) Schiff Base Complexes. X‐Ray Crystal Structure of Dioxo(N,N′‐(1,1,2,2‐tetramethylethylene)bis(3‐tert‐butylsalicylidenaminato))osmium(VI).
Authors: CHE C.‐M. , CHENG W.‐K. , MAK T. C. W.
Published: May 2016

The Os(VI) Schiff base complexes (I) are prepared by reaction of K2(OsO2(OH)4) with the appropriate substituted Schiff base in methanol.
ChemInform Abstract: Enantioselective Synthesis of the Tricyclo(5.2.2.01,5)undecane Skeleton Using Aprotic Michael Additions: Formal Total Synthesis of (+)‐Isoeremolactone.
Authors: SPITZNER D. , SAWITZKI G.
Published: May 2016

Michael addition of the ester (I) to the enone (II) affords the adduct (III) (space group P212121; Z=4).
ChemInform Abstract: Porous and Electrically Conducting Clay‐Carbon Composite as Positive Electrodes of Zinc‐Oxygen Primary Cells and Zinc‐Iodine Secondary Cells.
Authors: YAMAMOTO T. , KANBARA T.
Published: May 2016

A new porous and electrically conducting clay‐carbon composite, prepared by sintering mixtures of a clay (composed mainly of kaolinite) and porous carbon, can be used as excellent positive electrodes of zinc‐oxygen primary cells and zinc‐iodine secondary cells.
ChemInform Abstract: Liquid Corrosion and High‐Temperature Oxidation Effects on Silicon Carbide/Titanium Diboride Composites.
Authors: SESHADRI S. G. , SRINIVASAN M.
Published: May 2016

SiC/TiB2 composites have been exposed to aqua regia solution for 200 h, to 50% aqueous NaOH, and to 10% HF/57% HNO3/H2O solution for up to 500 h at room temperature.
ChemInform Abstract: The Redispersion of Sintered Pt, Rh, and Pt/Rh Catalysts.
Authors: D'ANIELLO M. J. JUN. , MONROE D. R. , CARR C. J. , KRUEGER M. H.
Published: May 2016

The redispersion of thermally aged automotive catalysts containing Pt, Rh, or bimetallic Pt/Rh using high temp. chlorine treatments is investigated by hydrogen chemisorption, HRTEM, and catalytic activity measurements.
ChemInform Abstract: Regulated Dioxygen Affinities by Steric Restrictions on Axial Bases in “Jellyfish” Type Cobalt(II) Porphyrins.
Authors: UEMORI Y. , MIYAKAWA H. , KYUNO E.
Published: May 2016

The title compounds are prepared from the free porphyrin bases (syntheses described) and CoCl2 in THF or Co(O‐Ac)2 in AcOH (no yield given).
ChemInform Abstract: Extraction of 3d‐Metal Ions by Bidentate Sulfonamides. Part 1. Ligands with Sulfur or Heterocyclic Nitrogen as a Second Donor Atom.
Authors: DOERING M. + , HEPPNER A. , UHLIG E. , UNDEUTSCH B. , GLOE K. , MUEHL P. +
Published: May 2016

The hydrazone (I) extracts Cu(II) and Zn(II) from weak acid solutions analogously to LIX 34 via coordination through the amide nitrogen.
ChemInform Abstract: Reactions of 3‐Alkyl‐ and 3,3‐Dialkyl‐1‐bromoallenes with Organocuprates: Effects of the Nature of the Cuprate Reagent on the Regio‐ and Stereoselectivity.
Authors: CAPORUSSO A. M. , POLIZZI C. , LARDICCI L.
Published: May 2016

Reaction of the monoalkylbromoallene (Ia) with the organocuprates (IIa) and (IIb) yields the alkynes (III), whereas the dialkylated bromoallene (Ib) and the cuprates (II), (IV), or (VI) produce the trisubstituted allenes (V).
ChemInform Abstract: Intramolecular Diels‐Alder Reaction of Bicyclo(6.4.0)dodeca‐4,9,11‐triene.
Authors: GRIMME W. , WIECHERS G.
Published: May 2016

1,1‐Dimethoxytetrachlorocyclopentadiene (I) and 1,5‐cyclooctadiene (II) give the Diels‐Alder adduct (III) which is reductively dechlorinated and then selectively chlorinated, yielding (IV).
ChemInform Abstract: Epoxidation of Alkenes and Terpenes with Iodylbenzene Catalyzed by Vanadylacetylacetonate.
Authors: BARRET R. , PAUTET F. , DAUDON M. , SABOT J. F.
Published: May 2016

Simple alkenes such as the cyclohexenes (I) are epoxidized with iodylbenzene in the presence of vanadyl acetylacetonate to form the corresponding oxiranes such as (II).
ChemInform Abstract: Synthesis of Alkyl‐ and Phenyl‐Substituted 4‐Aminomethyl‐2‐butenolides‐4.
Authors: KUKHAREV A. S. , TISHCHENKO I. G. , TYVORSKII V. I.
Published: May 2016

Base‐catalyzed cyclization of the aminohydroxyalkenoates (I) produces the butenolides (II).
ChemInform Abstract: Structure and Reactivity of Isoanellated Heterocyclic Systems with 4nπ‐ and (4n + 2)π‐Electrons. Part 14. Tri‐ and Tetracyclic Hetarenes with Localized or Delocalized Pyrrole Units.
Authors: KREHER R. P. , HILDEBRAND T.
Published: May 2016

The title compounds (V) and (VII) are prepared by analogous routes and characterized by spectroscopic data.
ChemInform Abstract: A New Access to 2‐Benzoylquinoline and 1‐Benzoylisoquinoline Using a Novel Mode of Base‐Induced Decomposition of N‐Alkoxypyridinium Salts.
Authors: SLIWA H. , OUATTARA L.
Published: May 2016

Quinoline‐N‐oxide (I) and isoquinoline‐N‐oxide (VI) are alkylated with α‐bromoisobutyrophenone (II) to give the N‐alkoxy perchlorates (III) and (VII) which undergo intramolecular cyclization in the presence of 2,2,6,6‐tetramethylpiperidine, producing the tricyclic (iso)quinolinium perchlorates (IV) and (VIII).
ChemInform Abstract: Photooxidation of α‐Phellandrene: The Formation of Cyclohexadienyl Hydroperoxides and Their Reduction to Arene 1,4‐Hydrates.
Authors: ATKINS R. , CARLESS H. A. J.
Published: May 2016

Dye‐sensitized photooxygenation of α‐phellandrene (I) gives the stereoisomeric endo‐peroxides (II) and (III), together with the hydroperoxides (IV).
ChemInform Abstract: Cyclobisintercalands: Synthesis and Structure of an Intercalative Inclusion Complex, and Anion Binding Properties.
Authors: JAZWINSKI J. , BLACKER A. J. , LEHN J.‐M. , CESARIO M. , GUILHEM J. , PASCARD C.
Published: May 2016

The macrocyclic tetramide (III) is obtained by cyclocondensation of the dianhydride (I) with the diamine (II) using the high dilution method.
ChemInform Abstract: The Synthesis of 11‐13‐Membered Diacetylenic and 18‐Membered Tetraacetylenic Ring Systems.
Authors: JUST G. , SINGH R.
Published: May 2016

Stepwise substitution of 1,2‐dibromobenzene (I) with the alkynes (II) in the presence of Pd catalysts gives the dialkynylbenzenes (III).
ChemInform Abstract: Selective Silylation with Hexamethyldisilazane.
Authors: COSSY J. , PALE P.
Published: May 2016

The compounds (I), (IV), or (VII), containing acidic protons, are silylated with hexamethyldisilazane (II) partly in the presence of chlorotrimethylsilane (V).
ChemInform Abstract: Research on the Calcium Inhibition of a Heterocyclic Oxygen Compound Series.
Authors: MOUYSSET G. , BELLAN J. , PAYARD M. , TISNE‐VERSAILLES J.
Published: May 2016

Starting with the carboxylic acids (I), the chloromethyl derivatives (III) are synthesized via the alcohols (II).
ChemInform Abstract: Reaction of Bis(2‐mercaptoethyl)phosphines with Organotin Compounds. Molecular Structure of a Tin Containing Sixteen‐Membered Ring.
Authors: JURKSCHAT K. , UHLIG W. , MUEGGE C. + , TZSCHACH A. , SCHMIDT B. , DRAEGER M. +
Published: May 2016

A trans configuration is shown for the dimers (I), derived from tBu2Sn (OMe)2 and the corresponding phosphine followed by the oxidation with S or Se (space group of (Ia): P21/n).
ChemInform Abstract: Diastereospecific Reformatsky Reactions with Chiral Arylaldehyde Tricarbonylchromium Complexes.
Authors: BROCARD J. , PELINSKI L. , LEBIBI J.
Published: May 2016

Reformatsky reaction of the bromo esters or nitriles (II) with tricarbonylchromium 2‐methoxybenzaldehyde (I) yields diastereoselectively the chiral complexed benzylic alcohols (III).
ChemInform Abstract: Oxo‐Molybdenum(IV) and ‐Tungsten(IV) Complexes with Dithio Acid Ligands. Synthesis and Structural Investigation of MoO(S2C(PMe3)S‐i‐Pr‐S,S′)(S2CS‐i‐Pr‐S,S′,C).
Authors: CARMONA E. , GALINDO A. , GUILLE‐PHOTIN C. , LAI R. , MONGE A. , RUIZ C. , SANCHEZ L.
Published: May 2016

The title compound (IIIa) is synthesized according to the scheme.
ChemInform Abstract: Ligand Substitution in (Ind)W(CO)3Cl and (Ind)W(CO)‐ 3Na+ (Ind = Indenyl): Examples of Mixed Associative and Dissociative Substitution.
Authors: TURAKI N. N. , HUGGINS J. M. , LEBIODA L.
Published: May 2016

(I), prepared from W(CO)6 and sodium indenyl in 1,4‐dioxane at 100 °C (yield: 52%), crystallizes in Pc with Z=4 and its substitution product (IV) in P21/c with Z=4.
ChemInform Abstract: Copper(II), Nickel(II), and Cobalt(III) Complexes with New Macrocyclic Ligands. 6,14‐Dimethyl‐1,5,9,13‐tetraazacyclohexadeca‐5,13‐diene (Me2(16)diene) and C‐meso‐ and C‐rac‐6,14‐Dimethyl‐1,5,9,13‐tetraazacyclohexadecane (C‐meso‐ and C‐rac‐Me2(16)ane).
Authors: BEMBI R. , ROY T. G. , JHANJI A. K.
Published: May 2016

The unstable macrocyclic title ligand (III) is synthesized as its dihydroperchlorate by the nontemplate condensation shown in the scheme and is reduced to give the saturated C‐meso and C‐racemic isomers (IVa) and (IVb).
ChemInform Abstract: BINAP‐Ruthenium(II) Dicarboxylate Complexes: New, Highly Efficient Catalysts for Asymmetric Hydrogenations.
Authors: OHTA T. , TAKAYA H. , NOYORI R.
Published: May 2016

The diastereomeric title complexes (I) are prepared by treatment of (RuCl2(cod))n (III) with (S)‐ or (R)‐2,2'‐bis(diarylphosphino)‐1,1'‐binaphthyls and then with sodium carboxylate as shown for the examples (S)‐(Ia) and (R)‐(Ib).
ChemInform Abstract: Crystal Structure Determination of Dipotassium Dihydroxotrioxoruthenate(VI): Configuration of the Ruthenate Ion and Its Electronic Properties.
Authors: ELOUT M. O. , HAIJE W. G. , MAASKANT W. J. A.
Published: May 2016

A crystal structure determination of K2RuO3(OH)2, formerly known as K2RuO4·H2O, reveals a five‐coordinate ruthenium with three equatorial oxygens and two apical OH ions in a trigonal‐bipyramidal arrangement (approximately D3h symmetry).
ChemInform Abstract: N,N‐Dialkylated Monophenolic trans‐2‐Phenylcyclopropylamines: Novel Central 5‐Hydroxytryptamine Receptor Agonists.
Authors: ARVIDSSON L.‐E. , JOHANSSON A. M. , HACKSELL U. , NILSSON J. L. G. , SVENSSON K. , HJORTH S. , MAGNUSSON T. , CARLSSON A. , LINDBERG P. , ANDERSSON B. , SANCHEZ D. , WIKSTROEM H. + , SUNDELL S.
Published: May 2016

Cyclopropanation reaction of the trans‐cinnamate (I) with diazomethane (II) followed by saponification of the ester yields the trans‐phenylcyclopropanecarboxylic acid (III).
ChemInform Abstract: A Simple Synthesis of 2,3‐Disubstituted Furans.
Authors: SRIKRISHNA A. , SUNDERBABU G.
Published: May 2016

The propargylic alcohols (I) react with ethyl vinyl ether (II) and NBS to give the alkynyl bromo acetals (III).
ChemInform Abstract: Regiospecific Synthesis and Spectroscopic Identification of New F‐Alkyl Substituted Aminopyrazoles.
Authors: FABRON J. , PASTOR R. , CAMBON A.
Published: May 2016

Starting with the phosphonium salt (I), the cyanooctanoyltriphenylphosphorane (IV) is prepared via the ylide (II).
ChemInform Abstract: Reaction of 4‐tert‐Butyldimethylsiloxy‐1‐benzopyrylium Salt with Enol Silyl Ethers and Active Methylenes.
Authors: IWASAKI H. , KUME T. , YAMAMOTO Y. , AKIBA K.
Published: May 2016

Chromone (I) reacts with the silyl triflate (II) to give the benzopyrylium salt (III) which is coupled with the enol ethers (IV) or the activated methylene compounds (VI) to give the substituted derivatives (V) and (VII).
ChemInform Abstract: α‐Lithiated O,O‐Diethyl Trimethylsilylchloromethylphosphonate. Part 1. Preparations and Properties.
Authors: TEULADE M.‐P. , SAVIGNAC P.
Published: May 2016

The α‐lithiated phosphonate (IV) mentioned in the title is prepared by treatment of the trichloromethylphosphonate (I) with butyllithium (II) and chlorotrimethylsilane (III).
ChemInform Abstract: Polylithiumorganic Compounds. Part 8. A Tetramethylene‐1,4‐distannacyclohexane from 3,4‐Dilithio‐2,5‐dimethyl‐2,4‐hexadiene and Dichlorodimethylstannane, the First Dimetalla(6)radialene.
Authors: MAERCKER A. , BRAUERS F. , BRIEDEN W. , JUNG M. , LUTZ H. D.
Published: May 2016

The compound (III), obtained in the title reaction crystallizes in P21/c with Z = 8 and has a twisted conformation.
ChemInform Abstract: EPR, Ligand Field Spectra and Antimicrobial Activity of Some N‐Pyruvideneglycinatocopper(II) Complexes.
Authors: PLESCH G. , FRIEBEL C. , SVAJLENOVA O. , KRAETSMAR‐SMOGROVIC J. + , MLYNARCIK D.
Published: May 2016

The N‐pyruvideneglycinato‐Cu(II) complexes (III) containing the N‐ligands (II) are prepared according to the scheme.
ChemInform Abstract: The Reaction of Ruthenium(II) Octaethylporphyrin and Ruthenium(II) Tetraphenylporphyrin Complexes with Carbon Monoxide.
Authors: PAULSON D. R. , BHAKTA S. B. , HYUN R. Y. , YUEN M. , BEAIRD C. E. , LEE S. C. , KIM I. , YBARRA J. JUN.
Published: May 2016

For the ligand exchange reactions of the title complexes (I) with CO the kinetics are studied.
ChemInform Abstract: Synthesis and Reactivity of Two cis‐PtH2(Diphosphine) Complexes (Diphosphine = 1,3‐Bis(diphenylphosphino)propane and 1,4‐Bis(diphenylphosphino)butane).
Authors: SCRIVANTI A. , CAMPOSTRINI R. , CARTURAN G.
Published: May 2016

IR, 1H and 31P NMR spectral data of (II) and (IV) are reported.
ChemInform Abstract: Simple 4‐Acetoxy‐5,6‐dihydropyridinium Salts: New Synthons for the Preparation of Functionalized Piperidine Systems.
Authors: TUBERY F. , GRIERSON D. S. , HUSSON H.‐P.
Published: May 2016

N‐Methyl‐4‐piperidone (I) is converted to the Δ2‐derivative (IV).
ChemInform Abstract: Observations on the Composition of Prussian Blue Films and Their Electrochemistry.
Authors: LUNDGREN C. A. , MURRAY R. W.
Published: May 2016

Prussian blue (PB) films grown on Pt and SnO2 electrodes are investigated by cyclic voltammetry, energy dispersive X‐ray analysis (EDX), XPS, ferric equivalent weight determination, and spectroelectrochemistry.
ChemInform Abstract: Synthesis and Characterization of Ca(HSO4)2·2 H2SO4 or H2(Ca(HSO4)4), respectively.
Authors: HASS D. , KEMNITZ E. , WORZALA H.
Published: May 2016

A crystalline compound of the empirical formula CaSO4·3 H2SO4, obtained by crystallization from CaSO4 saturated, hot, conc.
ChemInform Abstract: A New Oxoindate K2Na3(InO4).
Authors: HOPPE R. , GLAUM H.
Published: May 2016

The hitherto unknown nesoindate (IV), obtained on two different ways, is found to be isotypic with Na2Li3(GaO4) and K2Na3(TlO4) (Pnnm, Z=4).
ChemInform Abstract: The Hydrogen Bonding of Ligand Fluoride: The X‐Ray Crystal Structure of Difluoro(2,2′:6′,2′′‐terpyridine)copper(II) Trihydrate.
Authors: EMSLEY J. , ARIF M. , BATES P. A. , HURSTHOUSE M. B.
Published: May 2016

Dissolving CuF2 in wet methanol containing terpyridine yields the title complex (I) which crystallizes in Pbcn with Z = 8. The basal Cu‐F bond (1.862 Å) is the shortest such bond so far reported.
ChemInform Abstract: A Comparison of Counterion Effects in Surfactant and Classical Colloid Systems.
Authors: EVANS D. F. , EVANS J. B. , SEN R. , WARR G. G.
Published: May 2016

The changes of micellar and interfacial properties (critical micelle concentrations, area/molecule, aggregation numbers in solutions of the dodecyl sulfates of Li+, Na+, K+, Me4N+, Ag+, Ca2+, and Ba2+ are studied in the presence of neutral cryptate ligands (18‐crown‐6, (Ia) and (Ib)) with and without added salts.
ChemInform Abstract: Evidence for the Essential Role of Hydrogen Bonding in Promoting Amphiphilic Self‐Assembly: Measurments in 3‐Methylsydnone.
Authors: BEESLEY A. H. , EVANS D. F. , LAUGHLIN R. G.
Published: May 2016

In contrast to H‐bonding solvents with comparable polarity (such as formamide) no association is observed for (I) (surface tension, conductance measurements) or (II) (diffusive interfacial transport experiments) in the aprotic title solvents.
ChemInform Abstract: Addition of 1,4‐Diphenyl‐1‐azabutadiene to Allenic Esters.
Authors: GANDHI R. P. , ISHAR M. P. S. , WALI A.
Published: May 2016

1,4‐Diphenyl‐1‐azabutadiene (I) reacts with the allenic carboxylates (II), producing the cyclohexenones (III).
ChemInform Abstract: Sodium Borohydride Desulfurization of Thiolactams to Amines.
Authors: MANDAL S. B. , GIRI V. S. , PAKRASHI S. C.
Published: May 2016

Reductive desulfurization of the thiolactams (Ia), (II), and (IV) with sodium boranate yields the amines (Ib), (III), and (V).
ChemInform Abstract: A New Aromatization of 1,2‐Cyclohexanediones: Easy Synthesis of 3‐Arylcatechols.
Authors: FEIGENBAUM A. , PETE J.‐P. , POQUET‐DHIMANE A.
Published: May 2016

The 2‐hydroxy‐2‐cyclohexenones (I) react with tosyl chloride (II) and AIBN to give the catechols (III).
ChemInform Abstract: Heterocyclization of Primary Amines with Highly Activated Cyclopropanes: A New Route to Isoretronecanol.
Authors: CELERIER J. P. , HADDAD M. , JACOBY D. , LHOMMET G.
Published: May 2016

The 1,1‐diacylcyclopropanes (I) are coupled with the amines (II) to give the pyrrolines (III).
ChemInform Abstract: Synthesis and Reactions of 4,5‐Diaryl‐2‐mercaptoimidazoles.
Authors: SALAMA M. A. , YOUSIF N. M. , HAMMAM A. G.
Published: May 2016

The imidazoles (III), prepared from the substituted benzils (I) and thiourea (II), are coupled with chloroacetic acid (IV) to give the derivatives (V) which are cyclized, forming the imidazothiazolones (VI).
ChemInform Abstract: Chemistry of the 5:7‐Fused Heteroaromatic Systems: A Novel Rearrangement Involving the Imidazo(4,5‐e)(1,3,4)triazepine and Pyrazolo(3,4‐e)‐(1,3,4)triazepine Systems.
Authors: HOSMANE R. S. , LIM B. B.
Published: May 2016

Treatment of the heterocyclic hydrazidines (I) and (IV) with TFA gives the primary amines (II) and (V), together with the methyltriazolyl‐substituted imidazole (III) or pyrazole (VI).
ChemInform Abstract: Towards New Inhibitors of D‐Alanine‐D‐Alanine Ligase: The Synthesis of 3‐Aminobutenylphosphonic and Aminophosphonamidic Acids.
Authors: VO‐QUANG Y. , GRAVEY A. M. , SIMONNEAU R. , VO‐QUANG L. , LACOSTE A. M. , LE GOFFIC F.
Published: May 2016

The aminophosphonic acid (IV) and the aminophosphonamidic acid (X) are prepared as outlined in the reaction scheme.
ChemInform Abstract: Stereoselective Synthesis of trans‐Olefins by the Reaction of Wittig Reagents with Selenium. Formation of Selenocarbonyl Compounds.
Authors: OKUMA K. , SAKATA J. , TACHIBANA Y. , HONDA T. , OHTA H.
Published: May 2016

The methylenephosphoranes (I) undergo coupling reaction in the presence of selenium (II) to form the olefins (IV) and triphenylphosphine selenide (V) via the selenoaldehydes or selenoketones (III).
ChemInform Abstract: Highly Reduced Organometallics. Part 24. (M(CO)4(CH3C(CH2PMe2)3)), M: Ti, Zr, Hf, Complexes with Zero‐Valent Titanium, Zirconium, and Hafnium; First Structural Characterization of a Zr(0) Carbonyl Complex.
Authors: BLACKBURN D. W. , CHI K. M. , FRERICHS S. R. , TINKHAM M. L. , ELLIS J. E.
Published: May 2016

The air‐sensitive, thermally stable title complexes (IV) are prepared according to the scheme and characterized by IR, 13C(1H) and 31P(1H) NMR spectral data.
ChemInform Abstract: Methyl‐ and Phenylgermanium Derivatives of Diethyldithiocarbamic Acid. The Crystal and Molecular Structure of Diphenylbis(N,N‐diethyldithiocarbamato)germanium.
Authors: CHADHA R. K. , DRAKE J. E. , SARKAR A. B.
Published: May 2016

Methyl‐ and phenylgermanes (I) react with the Na‐salt (II) in CS2 at low temp. under exclusion of moisture to yield the compounds (III).
ChemInform Abstract: ((η5‐C5Me4Et)Rh(μ,η2‐P2)2Rh(η5‐C5Me4Et)), a Sandwich Complex with a P4 Rectangle.
Authors: SCHERER O. J. , SWAROWSKY M. , WOLMERSHAEUSER G. +
Published: May 2016

The title complex (IIIb) and its analogue (IIIa) are synthesized according to the scheme and characterized by MS, 1H and 31P(1H) NMR data.
ChemInform Abstract: Mechanism of Acyl Group Isomerization in Palladium(II) Complexes. Development of a Catalytic Process for the Isomerization of Carboxylic Acid Chlorides.
Authors: BRUMBAUGH J. S. , SEN A.
Published: May 2016

The complexes (I), when dissolved in weakly coordinating solvents, spontaneously isomerize to equilibrium mixtures of (I) and (II).
ChemInform Abstract: Reduction Using Yeast Cells. Key Step in an Efficient Synthesis of (3S,4S)‐4‐Amino‐3‐hydroxypentanoic Acids.
Authors: RADDATZ P. , RADUNZ H.‐E. , SCHNEIDER G. , SCHWARTZ H.
Published: May 2016

Depending on the yeast culture employed the stereoselective reduction of the ketone (III) leads to the alcohols (IVa) or (IVb) (no yields given).
ChemInform Abstract: Characteristics of ZrO2‐Dispersed Si3N4 without Additives Fabricated by Hot Isostatic Pressing.
Authors: TERAO K. , MIYAMOTO Y. , KOIZUMI M.
Published: May 2016

Si3N4‐ZrO2 composistes can be densified to >96% of theoretical by hot isostatic pressing.
ChemInform Abstract: Electronic Structure and Orientation of Dioxygen Species on the Surface of CoO‐MgO Solid Solutions.
Authors: SOJKA Z. , GIAMELLO E. , CHE M. , ZECCHINA A. , DYREK K.
Published: May 2016

The adsorption of oxygen on the CoO‐MgO surface is studied by EPR using 17O‐enriched oxygen.
ChemInform Abstract: Base Hydrolysis of Pentaammine Complexes of Cobalt(III): Structure, Reactivity, and Lifetime of the Intermediates.
Authors: ROTZINGER F. P.
Published: May 2016

Base hydrolysis of the complexes (I), (II), and (III), studied in 0.01 M NaOH and 0.02‐0.40 M NaN3 at 25 °C, results in the formation of Co(NH3)5N32+ and Co(NH3)5OH2+.
ChemInform Abstract: Reactions of Dichlorocarbene with 2,2,4,4‐Tetraalkylsubstituted Bicyclobutanes.
Authors: MOLCHANOV A. P. , KOPTELOV YU. B. , KOSTIKOV R. R.
Published: May 2016

The reaction between the bicyclobutanes (I) and dichlorocarbene proceeds via ring cleavage to yield the penta‐1,4‐dienes (III).
ChemInform Abstract: Photoassisted C‐H Bond Activation with RhCl(CO)(PR3)2 in the Presence of Isocyanides Leading to Catalytic Formation of Aldimines.
Authors: TANAKA M. , SAKAKURA T. , TOKUNAGA Y. , SODEYAMA T.
Published: May 2016

Cyclohexyl isocyanide (I) is irradiated in benzene (II) or pentane (VI) in the presence of Rh catalysts, yielding the imines (III) or (VII) ‐(IX), the amine (IV), and diphenyl (V).
ChemInform Abstract: Deamination Reactions. Part 48. Decomposition of 5‐ and 6‐Alkoxy‐2‐norbornanediazonium Ions.
Authors: KIRMSE W. , SIEGFRIED R. , FELDMANN G. , SCHOEN S. , SCHWARZ J.
Published: May 2016

The effects of 5‐ and 6‐alkoxy substituents on the Wagner‐Meerwein rearrangement of the 2‐norbornyl cations, generated by photolysis of the corresponding diazonium ions derived from (I) and (II), to give products such as (III)‐(VI) are investigated.
ChemInform Abstract: Cumulated Ylides. Part 19. Chain‐Lenghthening Difunctionalization of Grignard Compounds by Reaction with Ketenylidenetriphenylphosphorane. A New Route to E‐α,β‐Unsaturated Ketones and the Queen Substance.
Authors: BESTMANN H. J. , SCHMIDT M. , SCHOBERT R.
Published: May 2016

The reaction of ketenylidenetriphenylphosphorane (II) with Grignard reagents (III) followed by hydrolysis yields the phosphoranes (IV) which are employed in Wittig reactions to produce E‐α,β‐unsaturated ketones (VI).
ChemInform Abstract: Reaction of Phenol with Methyl 1‐Adamantyl Ketone in the Presence of Aluminum Phenolate.
Authors: KOZLIKOVSKII YA. B. , CHERNYAEV B. V. , YURCHENKO A. G.
Published: May 2016

The reaction between methyl 1‐adamantyl ketone (I) and phenol (II) gives the products (III)‐(VII) (no yields given).
ChemInform Abstract: Optically Pure Isoproterenol Analogues with Side Chains Containing an Amide Bond: Synthesis and Biological Properties.
Authors: MAERKI H. P. + , CRAMERI Y. , EIGENMANN R. , KRASSO A. , RAMUZ H. , BERNAUER K. , GOODMAN M. , MELMON K. L.
Published: May 2016

In order to test the inotropic activity, the 4 isoproterenol diastereomers (III) are synthesized by condensation of the respective isomers of the compounds (I) and (II) followed by hydrogenolytic debenzylation.
ChemInform Abstract: Scope and Limitations of the TiCl4‐Mediated Additions of Isocyanides to Aldehydes and Ketones with Formation of α‐Hydroxycarboxylic Acid Amides.
Authors: SEEBACH D. , ADAM G. , GEES T. , SCHIESS M. , WEIGAND W.
Published: May 2016

The adduct obtained from the achiral isocyanide (I) and TiCl4 (II), presumably possessing the structure (III), is combined with the keto compounds (IV) to give the hydroxyamides (V) (Passerini‐type reaction).
ChemInform Abstract: Radical Decarboxylation of Formic Acid Furfuryl‐ and Tetrahydrofurfuryl Esters.
Authors: NURBERDIEV R. , ROL'NIK L. Z. , KHEKIMOV YU. B. , ZLOTSKII S. S. , RAKHMANKULOV D. L.
Published: May 2016

The tert‐butyl peroxide catalyzed decarboxylation of furfuryl formate (I) gives 2‐methylfuran (II) as the sole product.
ChemInform Abstract: Antiviral Activity of 4‐Hydroxybenzofuran Derivatives.
Authors: GRINEV A. N. , LYUBCHANSKAYA V. M. , NIKOLAEVA I. S. , FOMINA A. N. , SARKISOVA L. S. , KRYLOVA L. YU. , ALEKSEEVA L. M.
Published: May 2016

The Mannich bases (I) are acetylated to give the acetamides (III) which are converted to the derivatives (VI) and (VII) respectively.
ChemInform Abstract: Synthesis and Fungicidal Activity of 3‐Aryl‐6,7‐dihydro‐5H‐pyrrolo‐(1,2‐a)imidazoles.
Authors: DEMCHENKO A. M. , SINCHENKO V. G. , PRODANCHUK N. G. , KOVTUNENKO V. A. , PATRATII V. K. , TYLTIN A. K. , BABICHEV F. S.
Published: May 2016

Coupling of the methoxypyrroline (I) with the aminoacetophenone hydrochlorides (II) and subsequent cyclization of the condensation products (III) give the pyrroloimidazole hydrochlorides (IV).
ChemInform Abstract: First Synthesis of a Benzodihydroborete.
Authors: SCHACHT W. , KAUFMANN D.
Published: May 2016

Dichloro(2‐bromomethyl)phenylborane (I) is methylated with tetramethylstannane (II) to give the B‐methyl derivative (IIIa).
ChemInform Abstract: A Simple Preparation of Vinyl‐ or Allyldiphenylphosphine Oxides.
Authors: SANTELLI‐ROUVIER C.
Published: May 2016

Reaction of diphenyl(methyl)phosphine oxide (I) with butyllithium followed by treatment with the carbonyl compounds (II) yields the hydroxyalkylphosphine oxides (III) which are converted to the vinyldiphenylphosphine oxides (VI) via the silyl ethers (V).
ChemInform Abstract: Synthesis of Vinylselenonium Salts.
Authors: MAGDESIEVA N. N. , GORDEEV M. F.
Published: May 2016

The β‐bromoselenonium bromides (I), on treatment with Na2CO3 and subsequent work‐up with Na(BPh4) (II) afford the vinylselenonium salts (III) in high yields.
ChemInform Abstract: Preparation and Properties of Inclusion Compounds of Ferrocene and Its Derivatives with Cyclodextrins.
Authors: HARADA A. , HU Y. , YAMAMOTO S. , TAKAHASHI S.
Published: May 2016

The 1:1 and 1:2 inclusion compounds of ferrocenes with β‐ and γ‐cylodextrins L1 or α‐cyclodextrin L2 are prepared in crystalline state in high yields.
ChemInform Abstract: Synthesis, Spectroscopic, Magnetic and Electrochemical Properties of Diruthenium(II,III) and ‐(III,III) Complexes Containing the Mixed‐Carboxylato Ligand Systems CH3CO‐ 2‐CF3CO‐ 2 and C6H5CO‐ 2‐CF3CO‐ 2.
Authors: HIGGINS P. , MCCANN G. M.
Published: May 2016

The interaction of the tetra‐μ‐carboxylates (I) with alcoholic solutions of Ag trifluoroacetate (II) yields the mixed‐carboxylato, monotrifluoroacetato derivatives (III).
ChemInform Abstract: Modeling of Bipolar Semiconductor Photoelectrode Arrays for Electrolytic Processes
Authors: CERVERA‐MARCH S. , SMOTKIN E. S. , BARD A. J. , CAMPION A. , FOX M. A. , MALLOUK T. E. , WEBBER S. E. , WHITE J. M.
Published: May 2016

is performed using current‐voltage data from a single bipolar CdSe||CoS photoelectrode to describe the relationship between the water splitting efficiency and electrical power efficiency and how these quantities depend on the number of panels, the overpotentials of the electrodes, light intensity, and redox couple concentrations.
ChemInform Abstract: Pulse Stimulated Potentiostatic Deposition of Silver on Single Crystal RuO2(110) Surface.
Authors: HEPEL T. , POLLAK F. H. , O'GRADY W. E.
Published: May 2016

In the case of electrodeposition of Ag on RuO2(110) it is found that the deposit‐substrate interactions are relatively weak in comparison to strong lateral attractions between the Ag adatoms.
ChemInform Abstract: Kinetics of CO Oxidation by O2 or NO on Rh(111) and Rh(100) Single Crystals
Authors: PEDEN C. H. F. , GOODMAN D. W. , BLAIR D. S. , BERLOWITZ P. J. , FISHER G. B. , OH S. H.
Published: May 2016

are studied in a high‐pressure reaction/high‐vacuum surface analysis apparatus as a function of temp. and partial pressures of CO, O2, and NO.
ChemInform Abstract: Surface Structure and Catalytic Properties of the MoO3‐MgF2 System.
Authors: HABER J. , WOJCIECHOWSKA M.
Published: May 2016

Introduction of molybdate species into MgF2 causes changes in the MgF2 surface composition.
ChemInform Abstract: Reactions of Cyclic Anhydrides with Thiosemicarbazide: Synthesis of Fused Heterocyclic Systems.
Authors: MEHTA A. M. , PEDNEKAR S. R. , MAYADEO M. S. , DEODHAR K. D.
Published: May 2016

The title reaction of the cyclic anhydrides (III), (V), (XI) and of benzalpthalide (IX) with (II) yields the fused heterocyclic systems shown in the scheme.
ChemInform Abstract: Photochemistry of α,β‐Unsaturated Thiones: Addition to Electron‐Rich Olefins from T1.
Authors: RAO V. P. , RAMAMURTHY V.
Published: May 2016

The thioxodihydronaphthalene (I) is subjected to photochemical cycloaddition reaction with the vinyl ethers (II), yielding mixtures of the 1,4‐dithianes (III) and the thietanes (IV).
ChemInform Abstract: Synthesis of β‐Arylvinyl Ethers by the Palladium‐Catalyzed Reaction of Aroyl Chlorides with Vinyl Ethers.
Authors: ANDERSSON C.‐M. , HALLBERG A.
Published: May 2016

The benzoic acids (I) are converted to the corresponding benzoyl chlorides which are directly treated with butyl vinyl ether in the presence of palladium acetate and N‐ethylmorpholine to form the styryl ethers (III).
ChemInform Abstract: Squaraine Chemistry: Synthesis, Characterization, and Xerographic Properties of Bis(4‐methylbenzylaminophenyl)squaraine and Its Derivatives.
Authors: LAW K.‐Y. , BAILEY F. C.
Published: May 2016

Squaric acid (I) is coupled with the N‐benzyl‐N‐methylanilines (II) under removal of water by azeotropic distillation to produce the squaraines (III).
ChemInform Abstract: Diisophorone and Related Compounds. Part 21. Synthesis and Nucleophilic Reactions of 4,4,8‐ and 4,6,8‐Tribromodiisophorones.
Authors: KURZER F. , PATEL J. N.
Published: May 2016

Diisophorone (Ia) is brominated in acetic acid or diethyl ether, yielding the tribromides (Ib) and/or (VIII).
ChemInform Abstract: Addition of Fluorenylidene to Hexafluorobenzene and an Answer to the Question: How does Hexafluorobenzene Influence the Reactions of Diazofluorene with Olefins?
Authors: GASPAR P. P. , MACK D. P. , LIN C.‐T. , STANLEY G. G. , JONES M. JUN.
Published: May 2016

Irradiation of 9‐diazofluorene (I) in hexafluorobenzene (II) yields bifluorenylidene (III) and the spirocycloheptatriene (IV) via the intermediate fluorenylidene.
ChemInform Abstract: 3‐Halogenated N‐Arylazetidin‐2‐ones and Benzocarbacephems, Inhibitors of β‐Lactamases.
Authors: JOYEAU R. , MOLINES H. , LABIA R. , WAKSELMAN M.
Published: May 2016

The halogenated azetidinones (V), prepared by cyclization of the 3‐bromopropionanilides (III), are evaluated as TEM‐1 β‐lactamase inhibitors.
ChemInform Abstract: Intramolecular Chemoselective Heterocyclization of 4‐Oxothiazolidin‐5yl N‐Aryldithiocarbamates to Fungitoxic 1,3‐Dithiolo‐, 1,3‐Oxathiolo‐ and Thiazolo‐thiazoles.
Authors: SINGH H. , MISHRA A. R. , YADAV L. D. S.
Published: May 2016

The products (III)‐(V) and (VII) are tested for their fungicidal activity.
ChemInform Abstract: Pyridiniumcarbons: Perpyridinium Derivatives of Cyclopropene and Allyl Anion.
Authors: WATERMAN K. C. , SPEER D. V. , STREITWIESER A. JUN. , LOOK G. C. , NGUYEN K. O. , STACK J. G.
Published: May 2016

The so‐called pyridiniumcarbons (III) and (IV) are prepared by coupling of tetrachlorocyclopropene (I) with 4‐dimethylaminopyridine (II) depending on the reaction conditions.
ChemInform Abstract: New Ferroelectric Liquid Crystal Materials: (+)‐4‐(2‐Methylbutoxycarbonyl)phenyl 4‐(5‐Alkyl‐1,3‐dioxan‐2‐yl)benzoate.
Authors: HARAMOTO Y. , KAWASHIMA K. , KAMOGAWA H.
Published: May 2016

The optically active benzoates (III) are synthesized (in most cases the trans‐isomers are isolated by TLC) and their mesomorphic behavior is measured.