bluuebunny/crossref_metadata_2025 huggingface dataset:
Glycosidically-Bound Volatile Phenols Linked to Smoke Taint: Stability during Fermentation with Different Yeasts and in Finished Wine
Authors: Whitmore Brandon A. , McCann Stephanie E. , Noestheden Matthew , Dennis Eric G. , Lyons Sarah M. , Durall Daniel M. , Zandberg Wesley F.
Published: July 2021

When wine grapes are exposed to smoke, there is a risk that the resulting wines may possess smoky, ashy, or burnt aromas, a wine flaw known as smoke taint. Smoke taint occurs when the volatile phenols (VPs) largely responsible for the aroma of smoke are transformed in grape into a range of glycosides that are imperceptible by smell. The majority of VP-glycosides described to date are disaccharides possessing a reducing β-d-glucopyranosyl moiety. Here, a two-part experiment was performed to (1) assess the stability of 11 synthesized VP-glycosides towards general acid-catalyzed hydrolysis during aging, and (2) to examine whether yeast strains differed in their capacity to produce free VPs both from these model glycosides as well as from grapes that had been deliberately exposed to smoke. When fortified into both model and real wine matrices at 200 ng/g, all VP-disaccharides were stable over 12 weeks, while (42–50 ng/g) increases in free 4-ethylphenol and p-cresol were detected when these were added to wine as their monoglucosides. Guaiacol and phenol were the most abundantly produced VPs during fermentation, whether originating from natural VP-precursors in smoked-exposed Pinot Noir must, or due to fortification with synthetic VP-glycosides. Significant yeast strain-specific differences in glycolytic activities were observed for phenyl-β-d-glycopyranoside, with two strains (RC212 and BM45) being unable to hydrolyze this model VP, albeit both were active on the guaiacyl analogue. Thus, differences in Saccharomyces cerevisiae β-glucosidase activity appear to be influenced by the VP moiety.
The Valence-Bond (VB) Model and Its Intimate Relationship to the Symmetric or Permutation Group
Authors: Nascimento Marco Antonio Chaer
Published: July 2021

VB and molecular orbital (MO) models are normally distinguished by the fact the first looks at molecules as a collection of atoms held together by chemical bonds while the latter adopts the view that each molecule should be regarded as an independent entity built up of electrons and nuclei and characterized by its molecular structure. Nevertheless, there is a much more fundamental difference between these two models which is only revealed when the symmetries of the many-electron Hamiltonian are fully taken into account: while the VB and MO wave functions exhibit the point-group symmetry, whenever present in the many-electron Hamiltonian, only VB wave functions exhibit the permutation symmetry, which is always present in the many-electron Hamiltonian. Practically all the conflicts among the practitioners of the two models can be traced down to the lack of permutation symmetry in the MO wave functions. Moreover, when examined from the permutation group perspective, it becomes clear that the concepts introduced by Pauling to deal with molecules can be equally applied to the study of the atomic structure. In other words, as strange as it may sound, VB can be extended to the study of atoms and, therefore, is a much more general model than MO.
Evaluation of Starch as an Environmental-Friendly Bioresource for the Development of Wood Bioadhesives
Authors: Arias Ana , Feijoo Gumersindo , Moreira María Teresa
Published: July 2021

The environment is a very complex and fragile system in which multiple factors of different nature play an important role. Pollution, together with resource consumption, is one of the main causes of the environmental problems currently affecting the planet. In the search for alternative production processes, the use of renewable resources seeks a way to satisfy the demands of resource consumption based on the premises of lower environment impact and less damage to human health. In the wood sector, the panel manufacturing process is based on the use of formaldehyde-based resins. However, their poor moisture resistance leads to hydrolysis of amino-methylene bonds, which induces formaldehyde emissions throughout the lifetime of the wood panel. This manuscript investigates the environmental profile associated with different wood bioadhesives based on starch functionalization as a renewable alternative to formaldehyde resins. Considering that this is a process under development, the conceptual design of the full-scale process will be addressed by process modeling and the environmental profile will be assessed using life cycle assessment methodology. A comparative study with synthetic resins will provide useful information for modify their development to become real alternatives in the wood-based panel industry. The results obtained show the enormous potential of starch bioadhesives, as their environmental impact values are lower compared to those based on petrochemicals. However, certain improvements in the energy process requirements and in the chemical agents used could be developed to provide even better results.
Catalytic Diversity of GH30 Xylanases
Authors: Šuchová Katarína , Puchart Vladimír , Spodsberg Nikolaj , Mørkeberg Krogh Kristian B. R. , Biely Peter
Published: July 2021

Catalytic properties of GH30 xylanases belonging to subfamilies 7 and 8 were compared on glucuronoxylan, modified glucuronoxylans, arabinoxylan, rhodymenan, and xylotetraose. Most of the tested bacterial GH30-8 enzymes are specific glucuronoxylanases (EC 3.2.1.136) requiring for action the presence of free carboxyl group of MeGlcA side residues. These enzymes were not active on arabinoxylan, rhodymenan and xylotetraose, and conversion of MeGlcA to its methyl ester or its reduction to MeGlc led to a remarkable drop in their specific activity. However, some GH30-8 members are nonspecific xylanases effectively hydrolyzing all tested substrates. In terms of catalytic activities, the GH30-7 subfamily is much more diverse. In addition to specific glucuronoxylanases, the GH30-7 subfamily contains nonspecific endoxylanases and predominantly exo-acting enzymes. The activity of GH30-7 specific glucuronoxylanases also depend on the presence of the MeGlcA carboxyl, but not so strictly as in bacterial enzymes. The modification of the carboxyl group of glucuronoxylan had only weak effect on the action of predominantly exo-acting enzymes, as well as nonspecific xylanases. Rhodymenan and xylotetraose were the best substrates for exo-acting enzymes, while arabinoxylan represented hardly degradable substrate for almost all tested GH30-7 enzymes. The results expand current knowledge on the catalytic properties of this relatively novel group of xylanases.
Adsorption in Mixtures with Competing Interactions
Authors: Litniewski Marek , Ciach Alina
Published: July 2021

A binary mixture of oppositely charged particles with additional short-range attraction between like particles and short-range repulsion between different ones in the neighborhood of a substrate preferentially adsorbing the first component is studied by molecular dynamics simulations. The studied thermodynamic states correspond to an approach to the gas–crystal coexistence. Dependence of the near-surface structure, adsorption and selective adsorption on the strength of the wall–particle interactions and the gas density is determined. We find that alternating layers or bilayers of particles of the two components are formed, but the number of the adsorbed layers, their orientation and the ordered patterns formed inside these layers could be quite different for different substrates and gas density. Different structures are associated with different numbers of adsorbed layers, and for strong attraction the thickness of the adsorbed film can be as large as seven particle diameters. In all cases, similar amount of particles of the two components is adsorbed, because of the long-range attraction between different particles.
Natural Products from Tongan Marine Organisms
Authors: Taufa Taitusi , Subramani Ramesh , Northcote Peter , Keyzers Robert
Published: July 2021

The islands of the South Pacific Ocean have been in the limelight for natural product biodiscovery, due to their unique and pristine tropical waters and environment. The Kingdom of Tonga is an archipelago in the central Indo-Pacific Ocean, consisting of 176 islands, 36 of which are inhabited, flourishing with a rich diversity of flora and fauna. Many unique natural products with interesting bioactivities have been reported from Indo-Pacific marine sponges and other invertebrate phyla; however, there have not been any reviews published to date specifically regarding natural products from Tongan marine organisms. This review covers both known and new/novel Marine Natural Products (MNPs) and their biological activities reported from organisms collected within Tongan territorial waters up to December 2020, and includes 109 MNPs in total, the majority from the phylum Porifera. The significant biological activity of these metabolites was dominated by cytotoxicity and, by reviewing these natural products, it is apparent that the bulk of the new and interesting biologically active compounds were from organisms collected from one particular island, emphasizing the geographic variability in the chemistry between these organisms collected at different locations.
Setup of an Ultrasonic-Assisted Extraction to Obtain High Phenolic Recovery in Crataegus monogyna Leaves
Authors: Martín-García Beatriz , Razola-Díaz María del Carmen , Gómez-Caravaca Ana María , Benítez Guillermo , Verardo Vito
Published: July 2021

Hawthorn leaves are a rich source of phenolic compounds that possess beneficial activities for human health. Ultrasonic-assisted extraction (UAE) is an extraction technique frequently used for the isolation of phenolic compounds in plants. Thus, in this study, a Box–Behnken design was used to optimize UAE conditions such as the percentage of acetone, the extraction time and solvent-to-solid ratio (v/w) in order to obtain the maximum content of total compounds by Folin–Ciocalteu and the maximum in vitro antioxidant activity by DPPH, ABTS and FRAP assays in Crataegus monogyna leaves. The optimum conditions to obtain the highest total phenolic content and antioxidant activities were 50% acetone, 55 min and 1/1000 (w/v). A total of 30 phenolic compounds were identified and quantified in C. monogyna leaf extract obtained at these optimum UAE conditions. HPLC-MS allows the identification and quantification of 19 phenolic compounds and NP-HPLC-FLD analyses showed the presence of 11 proanthocyanidins. According to the results, the most concentrated phenolic compounds in C. monogyna leaf extract obtained at optimum UAE conditions were phenolic acid derivatives such as protocatechuic acid-glucoside, dihydroxy benzoic acid pentoside and chlorogenic acid, flavones such as 2″-O-rhamnosyl-C-hexosyl-apigenin, flavonols such as hyperoside and isoquercetin and proanthocyanidins such as monomer and dimer. As a result, the optimized UAE conditions could be used to obtain an extract of C. monogyna leaves enriched with phenolic compounds.
Trans-(−)-Kusunokinin: A Potential Anticancer Lignan Compound against HER2 in Breast Cancer Cell Lines?
Authors: Rattanaburee Thidarath , Tanawattanasuntorn Tanotnon , Thongpanchang Tienthong , Tipmanee Varomyalin , Graidist Potchanapond
Published: July 2021

Trans-(−)-kusunokinin, an anticancer compound, binds CSF1R with low affinity in breast cancer cells. Therefore, finding an additional possible target of trans-(−)-kusunokinin remains of importance for further development. Here, a computational study was completed followed by indirect proof of specific target proteins using small interfering RNA (siRNA). Ten proteins in breast cancer were selected for molecular docking and molecular dynamics simulation. A preferred active form in racemic trans-(±)-kusunokinin was trans-(−)-kusunokinin, which had stronger binding energy on HER2 trans-(+)-kusunokinin; however, it was weaker than the designed HER inhibitors (03Q and neratinib). Predictively, trans-(−)-kusunokinin bound HER2 similarly to a reversible HER2 inhibitor. We then verified the action of (±)-kusunokinin compared with neratinibon breast cancer cells (MCF-7). (±)-Kusunokinin exhibited less cytotoxicity on normal L-929 and MCF-7 than neratinib. (±)-Kusunokinin and neratinib had stronger inhibited cell proliferation than siRNA-HER2. Moreover, (±)-kusunokinin decreased Ras, ERK, CyclinB1, CyclinD and CDK1. Meanwhile, neratinib downregulated HER, MEK1, ERK, c-Myc, CyclinB1, CyclinD and CDK1. Knocking down HER2 downregulated only HER2. siRNA-HER2 combination with (±)-kusunokinin suppressed HER2, c-Myc, CyclinB1, CyclinD and CDK1. On the other hand, siRNA-HER2 combination with neratinib increased HER2, MEK1, ERK, c-Myc, CyclinB1, CyclinD and CDK1 to normal levels. We conclude that trans-(±)-kusunokinin may bind HER2 with low affinity and had a different action from neratinib.
Intergenerational Transmission of Resistance of Callosobruchus maculatus to Essential Oil Treatment
Authors: Krzyżowski Michał , Baran Bartosz , Francikowski Jacek
Published: July 2021

Due to the rise of numerous legal restrictions as well as the increasing emergence of resistant populations, the number of available pesticides is decreasing significantly. One of the potential alternatives often described in the literature are essential oils (EOs). However, there is a lack of research addressing the potential emergence of resistance to this group of substances. In this paper, we investigated the multi-generational effects of sublethal concentrations of rosemary oil (Rosmarinus officinalis) on physiological and biochemical parameters of the cowpea weevil (Callosobruchus maculatus) such as egg laying, hatchability, oxygen consumption and acetylcholinesterase activity. Imago, which as larvae were exposed to EO at concentrations equivalent to LC25, showed significantly lower mortality. The results obtained indicate the potential development of resistance in insects exposed to EO in concentrations corresponding to LC25. In addition, in the case of the group treated with an EO concentration corresponding to LC3.12, a stimulation effect of the above-mentioned parameters was observed, which may indicate the occurrence of a hormesis effect. The obtained results may be an important reference for the development of future guidelines and EO-based insecticides.
Nutritional and Functional Evaluation of Inula crithmoides and Mesembryanthemum nodiflorum Grown in Different Salinities for Human Consumption
Authors: Lima Alexandre R. , Gama Florinda , Castañeda-Loaiza Viana , Costa Camila , Schüler Lisa M. , Santos Tamára , Salazar Miguel , Nunes Carla , Cruz Rui M. S. , Varela João , Barreira Luísa
Published: July 2021

The nutritional composition and productivity of halophytes is strongly related to the biotic/abiotic stress to which these extremophile salt tolerant plants are subjected during their cultivation cycle. In this study, two commercial halophyte species (Inula crithmoides and Mesembryanthemum nodiflorum) were cultivated at six levels of salinity using a soilless cultivation system. In this way, it was possible to understand the response mechanisms of these halophytes to salt stress. The relative productivity decreased from the salinities of 110 and 200 mmol L−1 upwards for I. crithmoides and M. nodiflorum, respectively. Nonetheless, the nutritional profile for human consumption remained balanced. In general, I. crithmoides vitamin (B1 and B6) contents were significantly higher than those of M. nodiflorum. For both species, β-carotene and lutein were induced by salinity, possibly as a response to oxidative stress. Phenolic compounds were more abundant in plants cultivated at lower salinities, while the antioxidant activity increased as a response to salt stress. Sensory characteristics were evaluated by a panel of culinary chefs showing a preference for plants grown at the salt concentration of 350 mmol L−1. In summary, salinity stress was effective in boosting important nutritional components in these species, and the soilless system promotes the sustainable and safe production of halophyte plants for human consumption.
Efficacy of Peat and Liquid Inoculant Formulations of Bradyrhizobium japonicum Strain WB74 on Growth, Yield and Nitrogen Concentration of Soybean (Glycine max L.)
Authors: Gatabazi Auges , Vorster Barend Juan , Mvondo-She Mireille Asanzi , Mangwende Edgar , Mangani Robert , Hassen Ahmed Idris
Published: July 2021

South African soils generally lack native Bradyrhizobium strains that nodulate and fix atmospheric nitrogen (N2) in soybeans (Glycine max L.). It is therefore very important to inoculate soybeans with products that contain effective Bradyrhizobium strains as active ingredients. In this study, a field experiment was conducted on two bioclimatic zones in South Africa during the 2019/2020 season to assess the effect of Bradyrhizobium japonicum strain WB74 inoculant formulation on nitrogen fixation, growth and yield improvement in soybeans. The first bioclimatic zone was characterized by a sandy clay loam soil, whereas the second bioclimatic zone has a sandy loam soil. The results showed that inoculation of soybeans with both peat and liquid formulations of Bradyrhizobium japonicum WB74 increased nitrogen uptake, which resulted in yield increase. The amount of N fixed was measured as 15N isotopes and increased with all treatments compared to the uninoculated control in both liquid and peat inoculant formulations. In bioclimatic zone A, slightly better results were obtained using the liquid formulation (1.79 t ha−1 for liquid compared to 1.75 t ha−1 for peat treatments), while peat formulations performed better in bioclimatic zone B (1.75 t ha−1 for peat compared to 1.71 t ha−1 for liquid treatments). In both areas higher yields were obtained with the formulations used in this study compared to the registered standards (treatment T3). The findings in this study provide vital information in the development and application of formulated microbial inoculants for sustainable agriculture in South Africa.
Optical See-through 2D/3D Compatible Display Using Variable-Focus Lens and Multiplexed Holographic Optical Elements
Authors: Ji Qinglin , Deng Huan , Zhang Hanle , Jiang Wenhao , Zhong Feiyan , Rao Fengbin
Published: July 2021

An optical see-through two-dimensional (2D)/three-dimensional (3D) compatible display using variable-focus lens and multiplexed holographic optical elements (MHOE) is presented. It mainly consists of a MHOE, a variable-focus lens and a projection display device. The customized MHOE, by using the angular multiplexing technology of volumetric holographic grating, records the scattering wavefront and spherical wavefront array required for 2D/3D compatible display. In particular, we proposed a feasible method to switch the 2D and 3D display modes by using a variable-focus lens in the reconstruction process. The proposed system solves the problem of bulky volume, and makes the MHOE more efficient to use. Based on the requirements of 2D and 3D displays, we calculated the liquid pumping volume of the variable-focus lens under two kinds of diopters.
Surface Plasmon Resonance Dependent Third-Order Optical Nonlinearities of Silver Nanoplates
Authors: Condorelli Marcello , Scardaci Vittorio , Pulvirenti Mario , D’Urso Luisa , Neri Fortunato , Compagnini Giuseppe , Fazio Enza
Published: July 2021

A systematic study of the surface plasmon resonance (SPR)-dependent nonlinear optical response of Ag nanoplates is presented and discussed. The Ag nanoplates were synthesized using the well-known seed-mediated growth method. By performing the z-scan method with a nanosecond laser (532 nm, 5 ns), the optical nonlinearities of the Ag nanoplates, prepared tuning the SPR contribution in the 400–1000 nm range, were determined. The results showed a SPR-related competition between the saturable absorption and reverse saturable absorption mechanisms, while the nonlinear refraction changed from self-defocusing to self-focusing. Furthermore, the scattering effects contribute to determine the nature of the optical limiting response. The observed SPR-tunable third order optical nonlinearities make Ag nanoplates a suitable candidate to be used in different fields, i.e., laser pulse generation, optical limiting, or bio-imaging applications.
Plasmon-Mediated Oxidation Reaction on Au/p-Cu2O: The Origin of Hot Holes
Authors: Hawe Philipp , Silveira Vitor , Bericat Vadell Robert , Lewin Erik , Sá Jacinto
Published: July 2021

More sustainable solutions are needed to produce chemicals and fuels, mainly to face rising demands and mitigate climate change. Light, as a reagent, has emerged as a route to activate small molecules, e.g., H2O, CO2, N2, and make complex chemicals in a process called photocatalysis. Several photosystems have been proposed, with plasmonic technology emerging as one the most promising technologies due to its high optical absorption and hot-carrier formation. However, the lifetime of hot carriers is unsuitable for direct use; therefore, they are normally coupled with suitable charge-accepting materials, such as semiconductors. Herein, a system is reported consisting of Au supported in p-Cu2O. The combination of p-Cu2O intrinsic photoactivity with the plasmonic properties of Au extended the system’s optical absorption range, increasing photocatalytic efficiency. More importantly, the system enabled us to study the underlying processes responsible for hot-hole transfer to p-Cu2O. Based on photocatalytic studies, it was concluded that most of the holes involved in aniline photo-oxidation come from hot-carrier injections, not from the PIRET process.
Assessment of Maternal Effects and Genetic Variability in Resistance to Verticillium dahliae in Olive Progenies
Authors: Valverde Caballero Pedro , Trapero Ramírez Carlos , Barranco Navero Diego , López-Escudero Francisco J. , Gordon Bermúdez-Coronel Ana , Díez Concepción Muñoz
Published: July 2021

The use of genetic resistance is likely the most efficient, economically convenient and environmentally friendly control method for plant diseases, as well as a fundamental piece in an integrated management strategy. This is particularly important for woody crops affected by diseases in which mainly horizontal resistance mechanisms are operative, such as Verticillium wilt, caused by Verticillium dahliae. In this study, we analyzed the variability in resistance to Verticillium wilt of olive trees in progenies from five crosses: ‘Picual’ × ‘Frantoio’, ‘Arbosana’ × ‘Koroneiki’, ‘Sikitita’ × ‘Arbosana’, ‘Arbosana’ × ‘Frantoio’ and ‘Arbosana’ × ‘Arbequina’ and their respective reciprocal crosses. Additionally, seedlings of ‘Picual’ and ‘Frantoio’ in open pollination were used as controls. In October 2016 and 2018, the fruits were harvested, and seeds germinated. Six-week-old seedlings were inoculated by dipping their bare roots in a conidial suspension of V. dahliae, and disease progress in terms of symptom severity and mortality was evaluated weekly. Additionally, seedling growth was evaluated every two weeks. At the end of the experiment, no significant differences were found for any of the assessed parameters when reciprocal crosses were compared. These results suggest that there is no maternal or paternal effect in regard to the heritability of resistance. In addition, this study identifies the best crosses for obtaining the highest number of resistant genotypes, highlighting the importance of the selection of specific cultivars to optimize the breeding process.
Fluctuation and Re-Establishment of Aerobic Granules Properties during the Long-Term Operation Period with Low-Strength and Low C/N Ratio Wastewater
Authors: Cha Lijuan , Liu Yong-Qiang , Duan Wenyan , Sternberg Christain E. W. , Yuan Qiangjun , Chen Fangyuan
Published: July 2021

Long-term structure stability of aerobic granules is critical to maintaining stable wastewater treatment performance. In this study, granulation and long-term stability of sludge-treating synthetic wastewater with a low chemical oxygen demand to nitrogen (COD/N) ratio of 4:1 and COD concentration of 400 mg/L in anoxic-oxic conditions were investigated for over 300 days. Inoculated suspended sludge gradually transformed into granules-dominant sludge on day 80. Due to the improved sludge volume index after 30 min settling (SVI30), mixed liquor suspended solids (MLSS) reached 5.2 g/L on day 140. Without any external intervention or disturbance, aerobic granules started to disintegrate from day 140, causing the increase in SVI and the decrease in biomass concentration until day 210, with the average sludge size reduced to 243 µm. From day 210, granular sludge started to be re-established by re-granulation, and the average granule size increased to 500 µm on day 302. During these disintegration and re-granulation periods, there was no obvious difference in terms of COD removal and nitrification, but microbial species were found more diverse after the re-granulation, with Thauera and Sphingomonas dominant. Although there was no external intervention, the food to microorganisms ratio (F/M) varied significantly due to the changes in biomass concentration caused by strong selective pressure and the change of sludge-settling ability in the reactor. F/M ratios should be controlled between 0.3 and 1.0 gCOD/gSS·d to maintain the stable structure of granules to minimize the fluctuation of sludge properties under the conditions used in this study. Although aerobic granular sludge is able to re-establish itself after disintegration, controlling F/M ratios in a certain range would benefit long-term stability. The findings in this study are significant to deepen the understanding of granule stability with low-strength and low COD ratio wastewater and, thus, provide guidance for maintaining the long-term stability of granules.
Study of Creep Mechanical Properties and a Rheological Model of Sandstone under Disturbance Loads
Authors: Li Xiaofeng , Yin Zhixiang
Published: July 2021

The stress environments of rock masses are complex. To explore the mechanical properties of sandstone under earthquake or disturbance loads, laboratory triaxial creep tests under different disturbance loads were conducted on sandstone from Fuxin, Liaoning Province, China. Given the disturbance load, a creep deformation pattern for sandstone was analyzed, and the influence of the disturbance load on the mechanical properties of rock was considered. Thus, a constitutive model of rock under creep disturbance load was established. The results show that (1) the creep curve can be divided into four stages: attenuation creep, steady creep, disturbance creep, and acceleration creep; the increment of disturbance creep varies for different disturbance loads and the larger the disturbance load, the larger the disturbance creep deformation; (2) with increasing disturbance loads, the long-term strength, failure time, and elastic modulus of sandstone decreases linearly, while the peak strain increases; and (3) considering the influence of the disturbance load and introducing an acceleration element to modify the Nishihara model, a constitutive model describing the whole deformation process of sandstone under creep disturbance load was established. The accuracy of the model was verified by test data and provides a theoretical basis for rock mass stability analysis.
Novel Hopfield Neural Network Model with Election Algorithm for Random 3 Satisfiability
Authors: Bazuhair Muna Mohammed , Jamaludin Siti Zulaikha Mohd , Zamri Nur Ezlin , Kasihmuddin Mohd Shareduwan Mohd , Mansor Mohd. Asyraf , Alway Alyaa , Karim Syed Anayet
Published: July 2021

One of the influential models in the artificial neural network (ANN) research field for addressing the issue of knowledge in the non-systematic logical rule is Random k Satisfiability. In this context, knowledge structure representation is also the potential application of Random k Satisfiability. Despite many attempts to represent logical rules in a non-systematic structure, previous studies have failed to consider higher-order logical rules. As the amount of information in the logical rule increases, the proposed network is unable to proceed to the retrieval phase, where the behavior of the Random Satisfiability can be observed. This study approaches these issues by proposing higher-order Random k Satisfiability for k ≤ 3 in the Hopfield Neural Network (HNN). In this regard, introducing the 3 Satisfiability logical rule to the existing network increases the synaptic weight dimensions in Lyapunov’s energy function and local field. In this study, we proposed an Election Algorithm (EA) to optimize the learning phase of HNN to compensate for the high computational complexity during the learning phase. This research extensively evaluates the proposed model using various performance metrics. The main findings of this research indicated the compatibility and performance of Random 3 Satisfiability logical representation during the learning and retrieval phase via EA with HNN in terms of error evaluations, energy analysis, similarity indices, and variability measures. The results also emphasized that the proposed Random 3 Satisfiability representation incorporates with EA in HNN is capable to optimize the learning and retrieval phase as compared to the conventional model, which deployed Exhaustive Search (ES).
Computational Modeling of Flow Characteristics in Three Products Hydrocyclone Screen
Authors: Yu Anghong , Wang Chuanzhen , Liu Haizeng , Khan Md.
Published: July 2021

Three products hydrocyclone screen (TPHS) can be considered as the combination of a conventional hydrocyclone and a cylindrical screen. In this device, particles are separated based on size under the centrifugal classification coupling screening effect. The objective of this work is to explore the characteristics of fluid flow in TPHS using the computational fluid dynamics (CFD) simulation. The 2 million grid scheme, volume fraction model, and linear pressure–strain Reynolds stress model were utilized to generate the economical grid-independence solution. The pressure profile reveals that the distribution of static pressure was axisymmetric, and its value was reduced with the increasing axial depth. The maximum and minimum were located near the tangential inflection point of the feed inlet and the outlets, respectively. However, local asymmetry was created by the left tangential inlet and the right screen underflow outlet. Furthermore, at the same axial height, the static pressure gradually decreased along the wall to the center. Near the cylindrical screen, the pressure difference between the inside and the outside cylindrical screen dropped from positive to negative as the axial depth increased from −35 to −185 mm. Besides, TPHS shows similar distributions of turbulence intensity I, turbulence kinetic energy k, and turbulence dissipation rate ε; i.e., the values fell with the decrease in axial height. Meanwhile, from high to low, the pressure values are distributed in the feed chamber, the cylindrical screen, and conical vessel; the value inside the screen was higher than the outer value.
CO2-Derived Carbon Capture Using Microalgae and Sodium Bicarbonate in a PhotoBioCREC Unit: Kinetic Modeling
Authors: Cordoba-Perez Maureen , de Lasa Hugo
Published: July 2021

By converting bicarbonates via Chlorella vulgaris photosynthesis, one can obtain valuable biofuel products and find a route toward carbon-derived fossil fuel conversion into renewable carbon. In this research, experiments were carried out in the PhotoBioCREC prototype under controlled radiation and high mixing conditions. Sodium bicarbonate (NaHCO3) was supplied as the inorganic carbon-containing species, at different concentrations, in the 18 to 60 mM range. Both the NaHCO3 concentrations and the organic carbon concentrations were quantified periodically during microalgae culture, with the pH being readjusted every day to the 7.00 level. It was found that sodium bicarbonate was converted with a selectivity up to 33.0% ± 2.0 by Chlorella vulgaris. It was also observed that the reaction rate constant for inorganic carbon conversion was 0.26 ± 0.09 day−1, while the maximum reaction rate constant for organic carbon formation was achieved with a 28 mM NaHCO3 concentration and displayed a 1.18 ± 0.05 mmole L−1day−1 value.
Bispacer Multi-Stage Direct Contact Membrane Distillation System: Analytical and Experimental Study
Authors: Aliabadi Morteza , Ghorashi Hassan , Shokri Motlagh Shamim , Nabavi Seyedeh Fatemeh , Pakzad Seyed Arash , Farshidianfar Mohamad Hossein , Farshidianfar Anooshiravan , Mahmoudi Farzaneh , Akbarzadeh Aliakbar
Published: July 2021

A multi-staged direct contact membrane distillation (MDCMD) system is designed considering a novel bispacer configuration in the present study. The proposed bispacer DCMD, which has not been addressed in the literature to best of our knowledge, is considered with two purposes, including increasing mechanical stability and turbulence. As increasing turbulence leads to increasing Nusselt number, the bispacer MDCMD provides higher permeate flux. An analytical approach is considered using energy and mass balance correlation. The effect of bispacer and feed operating conditions, including feed temperature, feed flow rate, feed salinity, and the number of stages on permeate flux and salt rejection of the developed MDCMD, are examined both analytically and experimentally. The performance and sustainability of the developed system were investigated by analyzing the parameters, including thermal efficiency (η), gained output ratio (GOR), and temperature polarization coefficient (TPC).
Effects of Different Injection Strategies on Combustion and Emission Characteristics of Diesel Engine Fueled with Dual Fuel
Authors: Luo Jianbin , Liu Zhonghang , Wang Jie , Chen Heyang , Zhang Zhiqing , Qin Boying , Cui Shuwan
Published: July 2021

In this work, an effective numerical simulation method was developed and used to analyze the effects of natural gas mixing ratio and pilot-main injection, main-post injection, and pilot-main-post injection strategies on the combustion and emission characteristics of diesel engine fueled with dual fuel. Firstly, the one-dimensional calculation model and three-dimensional CFD model of the engine were established by AVL-BOOST and AVL-Fire, respectively. In addition, the simplified chemical kinetics mechanism was adopted, which could accurately calculate the combustion and emission characteristics of the engine. The results show that the cylinder pressure and heat release rate decrease with the increase of the natural gas mixing ratio and the NOx emission is reduced. When the NG mixing ratio is 50%, the NOx and CO emission are reduced by 47% and 45%, respectively. When the SODI3 is 24 °CA ATDC, the NOx emission is reduced by 29.6%. In addition, with suitable pilot-main injection and pilot-main-post injection strategies, the combustion in the cylinder can be improved and the trade-off relationship between NOx and soot can be relaxed. Thus, the proper main-post injection strategy can improve the combustion and emission characteristics, especially the reduction in the NOx and CO emissions.
Bioelectricity Production from Blueberry Waste
Authors: Rojas-Flores Segundo , Benites Santiago M. , De La Cruz-Noriega Magaly , Cabanillas-Chirinos Luis , Valdiviezo-Dominguez Fiorela , Quezada Álvarez Medardo A. , Vega-Ybañez Victor , Angelats-Silva Luis
Published: July 2021

Global warming and the increase in organic waste from agro-industries create a major problem for the environment. In this sense, microbial fuel cells (MFC) have great potential for the generation of bioelectricity by using organic waste as fuel. This research produced low-cost MFC by using zinc and copper electrodes and taking blueberry waste as fuel. A peak current and voltage of 1.130 ± 0.018 mA and 1.127 ± 0.096 V, respectively, were generated. The pH levels were acid, with peak conductivity values of 233. 94 ± 0.345 mS/cm and the degrees Brix were descending from the first day. The maximum power density was 3.155 ± 0.24 W/cm2 at 374.4 mA/cm2 current density, and Cándida boidinii was identified by means of molecular biology and bioinformatics techniques. This research gives a new way to generate electricity with this type of waste, generating added value for the companies in this area and helping to reduce global warming.
Eliciting Risk Preferences Experimentally versus Using a General Risk Question. Does Financial Literacy Bridge the Gap?
Authors: Mudzingiri Calvin , Koumba Ur
Published: July 2021

The study investigates the stability of financial risk preference choices elicited from subjects by way of two methods, namely: experimentally elicited incentivized revealed risk preferences (IRRP) and (self-reported) perceived willingness to take a financial risk (PWTFR). The research further examines whether financial literacy (a human capital aspect) helps in reducing the gap between IRRP and PWTFR choices made by subjects. A total of 193 university students (where 53% were female) participated in the study. The subjects completed IRRP choices from four multiple price list (MPL) risk preference tasks and a financial literacy questionnaire. There is a tendency to anchor at extremes of risk-seeking behavior when subjects self-report their PWTFR choices. A paired t-test analysis of the two methods shows that the average responses from the two methods are significantly different. A random effect (RE) panel regression shows that an increase in financial literacy narrows the gap between IRRP and PWTFR choices. The study’s findings show that responses by subjects from a PWTFR general risk question (GRQ) and IRRP experiment are unstable and inconsistent. What people say in a survey does not always translate into what they do when faced with a risk preference choice dilemma. Financial literacy helps individuals to predict their risk attitudes more precisely.
Transformations in the Photogrammetric Co-Processing of Thermal Infrared Images and RGB Images
Authors: Dlesk Adam , Vach Karel , Pavelka Karel
Published: July 2021

The photogrammetric processing of thermal infrared (TIR) images deals with several difficulties. TIR images ordinarily have low-resolution and the contrast of the images is very low. These factors strongly complicate the photogrammetric processing, especially when a modern structure from motion method is used. These factors can be avoided by a certain co-processing method of TIR and RGB images. Two of the solutions of co-processing were suggested by the authors and are presented in this article. Each solution requires a different type of transformation–plane transformation and spatial transformation. Both types of transformations are discussed in this paper. On the experiments that were performed, there are presented requirements, advantages, disadvantages, and results of the transformations. Both methods are evaluated mainly in terms of accuracy. The transformations are presented on suggested methods, but they can be easily applied to different kinds of methods of co-processing of TIR and RGB images.
NiO Nanoparticles for Electrochemical Insulin Detection
Authors: Shepa Jana , Šišoláková Ivana , Vojtko Marek , Trnková Libuše , Nagy Géza , Maskaľová Iveta , Oriňak Andrej , Oriňaková Renáta
Published: July 2021

Diabetes mellitus represents one of the most widespread diseases in civilization nowadays. Since the costs for treating and diagnosing of diabetes represent several billions of dollars per year, a cheap, fast, and simple sensor for diabetes diagnosis is needed. Electrochemical insulin sensors can be considered as a novel approach for diabetes diagnosis. In this study, carbon electrode with electrodeposited NiO nanoparticles was selected as a suitable electrode material for insulin determination. The morphology and surface composition were studied by scanning electron microscopy (SEM), energy dispersive X-ray (EDX) spectroscopy, and X-ray photoelectron spectroscopy (XPS). For a better understanding of insulin determination on NiO-modified electrodes, the mechanism of electrochemical reaction and the kinetic parameters were studied. They were calculated from both voltammetric and amperometric measurements. The modified carbon electrode displayed a wide linear range from 600 nM to 10 µM, a low limit of detection of 19.6 nM, and a high sensitivity of 7.06 µA/µM. The electrodes were stable for 30 cycles and were able to detect insulin even in bovine blood serum. Additionally, the temperature stability of this electrode and its storage conditions were studied with appropriate outcomes. The above results show the high promise of this electrode for detecting insulin in clinical samples.
The Impacts of Agricultural Trade on Economic Growth and Environmental Pollution: Evidence from Bangladesh Using ARDL in the Presence of Structural Breaks
Authors: Ghimire Amogh , Lin Feiting , Zhuang Peifen
Published: July 2021

Agricultural trade significantly promotes the economic boom in developing countries. Extensive traditional agricultural production methods have increased the pressure on the agricultural environment by expanding agricultural trade, which has attracted the attention of many scholars. This study aims to empirically examine the impacts of agricultural trade on economic growth and agricultural environmental pollution in Bangladesh from 1972 to 2019, using an Auto Regressive Distributed Lag (ARDL) model with a structural break to examine the long-run and short-run determinants of agricultural environmental pollution in Bangladesh. The ARDL bounds analysis methodology showed that it does not support the hypothesis that agricultural trade led to environmental pollution in the long-run. The results suggest a relationship between economic growth, energy, and FDI towards agricultural environmental pollution, indicating a positive long-run relationship. Furthermore, in the short run, agricultural trade indicates positive drivers towards agricultural environmental pollution. Therefore, it is recommended that the enhancement of trade liberalization policies should ensure cleaner technologies and products that could help reduce environmental pollution.
Asymmetric Membranes
Authors: Buonomenna Maria Giovanna
Published: July 2021

Nowadays, membranes are key components in various relevant fields [...]
Editorial to the Special Issue “The Casimir Effect: From a Laboratory Table to the Universe”
Authors: Klimchitskaya Galina L.
Published: July 2021

This Special Issue presents a comprehensive picture of the Casimir effect as a multidisciplinary subject that plays an important role in diversified areas of physics ranging from quantum field theory, atomic physics and condensed matter physics to elementary particle physics, gravitation and cosmology [...]
Hantavirus Research in Finland: Highlights and Perspectives
Authors: Vaheri Antti , Henttonen Heikki , Mustonen Jukka
Published: July 2021

Finland has the highest incidence of hantavirus infections globally, with a significant impact on public health. The large coverage of boreal forests and the cyclic dynamics of the dominant forest rodent species, the bank vole Myodes glareolus, explain most of this. We review the relationships between Puumala hantavirus (PUUV), its host rodent, and the hantavirus disease, nephropathia epidemica (NE), in Finland. We describe the history of NE and its diagnostic research in Finland, the seasonal and multiannual cyclic dynamics of PUUV in bank voles impacting human epidemiology, and we compare our northern epidemiological patterns with those in temperate Europe. The long survival of PUUV outside the host and the life-long shedding of PUUV by the bank voles are highlighted. In humans, the infection has unique features in pathobiology but rarely long-term consequences. NE is affected by specific host genetics and risk behavior (smoking), and certain biomarkers can predict the outcome. Unlike many other hantaviruses, PUUV causes a relatively mild disease and is rarely fatal. Reinfections do not exist. Antiviral therapy is complicated by the fact that when symptoms appear, the patient already has a generalized infection. Blocking vascular leakage measures counteracting pathobiology, offer a real therapeutic approach.
Characteristics and Clinical Outcomes of 116,539 Patients Hospitalized with COVID-19—Poland, March–December 2020
Authors: Gujski Mariusz , Jankowski Mateusz , Rabczenko Daniel , Goryński Paweł , Juszczyk Grzegorz
Published: July 2021

The severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) causes Coronavirus Disease 2019 (COVID-19). This study aimed to characterize patients hospitalized with COVID-19 in Poland between March and December 2020, as well as to identify factors associated with COVID 19–related risk of in-hospital death. This retrospective analysis was based on data from the hospital discharge reports on COVID-19 patients hospitalized in Poland between March and December 2020. A total of 116,539 discharge reports on patients hospitalized with COVID-19 were analyzed. Among patients with COVID-19, 21,490 (18.4%) died during hospitalization. Patients over 60 years of age (OR = 7.74; 95%CI: 7.37–8.12; p < 0.001), men (OR = 1.42; 95%CI: 1.38–1.47; p < 0.001) as well as those with cardiovascular diseases (OR = 1.51; 95%CI: 1.46–1.56; p < 0.001) or disease of the genitourinary system (OR = 1.39; 95%CI: 1.31–1.47; p < 0.001) had much higher odds of COVID 19–related risk of in-hospital death. The presence of at least one comorbidity more than doubled the COVID 19–related risk of in-hospital death (OR = 2.23; 95%CI: 2.14–2.32; p < 0.01). The following predictors of admission to ICU were found in multivariable analysis: age over 60 years (OR: 2.03; 95%CI: 1.90–2.16), male sex (OR: 1.79; 95%CI: 1.69–1.89), presence of at least one cardiovascular disease (OR: 1.26; 95%CI: 1.19–1.34), presence of at least one endocrine, nutritional and metabolic disease (OR: 1.17; 95%CI: 1.07–1.28).
Legislative update of the norms for rational use of agricultural land in the Russian Federation
Authors: Efimova G. A. , Inshina Yu. Yu.
Published: July 2021

The article substantiates the expediency of updating the existing legal norms and proposes to update the system of legislative support for the rational land use in the Russian Federation, which is presented on the example of the Leningrad region. According to Rosreestr office of the Leningrad Region, the area of arable lands (and agricultural land in general) is shortened . The imperfect legal system, the need to modernize the systems of assessment, monitoring, protection, cadastre and control remain topical issues not only in the assessed region, but in Russia as a whole. Ineffective functioning of legal institutions impedes the planning and forecasting processes in agricultural land use.
Depreciation expense on soil fertility restoration
Authors: Alakoz V. V. , Nosov S. I.
Published: July 2021

The article explains necessary amount of depreciation expense on restoration of soilfertility of agricultural land used as a means of production and worn out in the process of agricultural use. The authors propose the approaches for assessing amortization costs and the value of arable land.
Eco-alternative development of the Arctic zone of Russia
Authors: Shelomentsev V. N.
Published: July 2021

The article analyzes the environmental directions of the annual message of the President of the Russian Federation to the Federal Assembly, as well as the ways of implementing the «Strategy for the development of the Arctic zone of the Russian Federation and ensuring national security for the period until 2020», and «Roadmap for eliminating environmental damage caused by the Ministry of Defense of Russia in the Arctic zone”, where great attention is paid to the issues of the internal ecological state of the country, as well as the implementation of national alternative environmental projects.

English version of the article on pp. 159-162 is available at URL: https://panor.ru/articles/alternative-environmental-development-of-the-arctic-zone-of-russia/64054.html

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