Riverine 137Cs dynamics and remoralization in coastal waters during high flow events
Authors: Wakiyama Yoshifumi , Takata Hyoe , Taniguchi Keisuke , Niida Takuya , Igarashi Yasunori , Konoplev Alexei 
Published: February 2023

Understanding riverine 137Cs dynamics during high-flow events is crucial for improving predictability of 137Cs transportation and relevant hydrological responses. It is frequently documented that the majority of 137Cs is exported during high-flow events triggered by intensive rainfall. Studies on 137Cs in coastal seawater suggested that a huge high-flow events resulted in high dissolved 137Cs concentration in seawater. Different temporal patterns of 137Cs concentrations in river water are found in the existing literature on 137Cs dynamics during high-flow events. Although such differences may reflect catchment characteristics, there is no comprehensive analysis for the relationships. This study explores catchment characteristics affecting 137Cs transport via river to ocean based on datasets obtained by sampling campaigns during high-flow events. 137Cs datasets obtained at 13 points in 6 river water systems were subject to the analysis. The analyses intended to explore relationship between catchment characteristics (scale and land use composition) and 137Cs dynamics in terms of variations in concentration, fluxes, and potential remobilization in seawater. We could not find any significant correlations between the parameters of catchment characteristics and mean values of normalized concentrations of 137Cs and apparent Kd. However, when approximating 137Cs concentrations and Kd value as a power function of suspended solid concentration (Y=&#945; X^&#946;), the power of &#946; in the equations for dissolved 137Cs concentration and Kd showed negative and positive correlations with the logarithm of the watershed area, respectively, and the positive &#946; was found when the catchment area was on the order of 100 km2 or larger and vice versa. This indicates that the concentration of dissolved 137Cs tends to decrease with increased water discharge in larger catchments for smaller catchments. These results suggest that the temporal pattern of dissolved 137Cs concentrations depends on watershed scale. 137Cs flux during a single event ranged from 1.9 GBq to 1.1 TBq and accounted for 0.00074% to 0.22% of total 137Cs deposited in relevant catchments. Particulate 137Cs flux accounted for more than 92% of total 137Cs flux, except for Ukedo River basin with a large dam reservoir. R-factor, an erosivity index in the Universal Soil Loss Equation model family, is a good parameter for reproducing sediment discharge and particulate 137Cs flux. Efficiency of particulate 137Cs flux, calculated by dividing the flux by R-factor of event, tended to be high in catchments with relatively low forest cover. Desorption ratio of 137Cs, obtained by 1-day shaking experiment of SS in seawater, ranged from 2.8 to 6.6%. The ratio was almost proportional of ratio of exchangeable 137Cs. The estimated amounts of desorbed 137Cs, obtained by multiplying particulate 137Cs and the desorption ratios, were greater than direct flux of dissolved 137Cs. Reanalysis of riverine 137Cs dataset in high flow events is revealing relationship between catchment characteristics and 137Cs dynamics. Further analyses, such as evaluation of decontamination impacts and inter-catchment comparisons of 137Cs fluxes, are required for better understanding.