bluuebunny/crossref_metadata_2025 huggingface dataset:
The Dispersion and Hydration Improvement of Silica Fume in UHPC by Carboxylic Agents
Authors: Wu Taige , Wang Honghu , Rong Zhidan
Published: August 2024

Silica fume (SF) is an essential component in ultra-high-performance concrete (UHPC) to compact the matrix, but the nucleus effect also causes rapid hydration, which results in high heat release and large shrinkage. In this paper, the carboxylic agents, including polyacrylic acid and polycarboxylate superplasticizer, were used to surface modify SF to adjust the activity to mitigate hydration at an early time and to promote continuous hydration for a long period. The surface and dispersion properties of modified SF (MSF), as well as the strength and pore structure of UHPC, were studied, and the stability of the modification was also investigated. The results demonstrated that, after treatment, the carboxylic groups were grafted on the SF surface, the dispersion of SF was improved due to the increased negative pentanal of the particle surface and the steric hindrance effect, the early hydration was delayed about 3–5 h, and the hydration heat release was also mitigated. The compressive strength of UHPC with MSF reached a maximum of 138.7 MPa at 3 days, which decreased about 3.7% more than the plain group, while flexural strength varied insignificantly. More pores and cracks were observed in the matrix with MSF, and the hydration degree was promoted with MSF addition. The grafted group on SF fell off under an alkali environment after 1 h.
Miscibility Studies of Bismesogen CBnCB Forming Nematic Twist-Bend Phase with Cyanobiphenyls nCB
Authors: Tykarska Marzena , Klucznik Barbara , Dziaduszek Jerzy , Jóźwiak Stanisław
Published: August 2024

This work aims to determine how the nematic twist-bend phase (NTB) of bismesogens containing two rigid parts of cyanobiphenyls connected with a linking chain containing n = 7, 9, and 11 methylene groups behaves in mixtures with structurally similar cyanobiphenyls nCB, n = 4–12, 14. The whole phase diagrams are presented for the CB7CB-nCB system. For the other systems, CB9CB-nCB and CB11CB-nCB, only curves corresponding to NTB-N phase transition are presented. Based on the temperature-concentration range of the existence of NTB phase, it was established that an increase in the alkyl chain length of CBnCB causes an increase in the stability of the NTB phase. But surprisingly, an increase in the alkyl chain length of nCB compounds does not change the slope of the NTB-N equilibrium line on phase diagrams. It is slightly bigger when the nCB compound has the same length of alkyl chain as the length of the linking group of a bismesogen. XRD studies were carried out for two mixtures.
Epitaxial Growth of Ga2O3: A Review
Authors: Rahaman Imteaz , Ellis Hunter D. , Chang Cheng , Mudiyanselage Dinusha Herath , Xu Mingfei , Da Bingcheng , Fu Houqiang , Zhao Yuji , Fu Kai
Published: August 2024

Beta-phase gallium oxide (β-Ga2O3) is a cutting-edge ultrawide bandgap (UWBG) semiconductor, featuring a bandgap energy of around 4.8 eV and a highly critical electric field strength of about 8 MV/cm. These properties make it highly suitable for next-generation power electronics and deep ultraviolet optoelectronics. Key advantages of β-Ga2O3 include the availability of large-size single-crystal bulk native substrates produced from melt and the precise control of n-type doping during both bulk growth and thin-film epitaxy. A comprehensive understanding of the fundamental growth processes, control parameters, and underlying mechanisms is essential to enable scalable manufacturing of high-performance epitaxial structures. This review highlights recent advancements in the epitaxial growth of β-Ga2O3 through various techniques, including Molecular Beam Epitaxy (MBE), Metal-Organic Chemical Vapor Deposition (MOCVD), Hydride Vapor Phase Epitaxy (HVPE), Mist Chemical Vapor Deposition (Mist CVD), Pulsed Laser Deposition (PLD), and Low-Pressure Chemical Vapor Deposition (LPCVD). This review concentrates on the progress of Ga2O3 growth in achieving high growth rates, low defect densities, excellent crystalline quality, and high carrier mobilities through different approaches. It aims to advance the development of device-grade epitaxial Ga2O3 thin films and serves as a crucial resource for researchers and engineers focused on UWBG semiconductors and the future of power electronics.
Effect of Extrusion Process on Microstructure, Corrosion Properties, and Mechanical Properties of Micro-Alloyed Mg–Zn–Ca–Zr Alloy
Authors: Yu Zemin , Hu Wenxin , Chen Zhiqiang , Shi Lei , Yang Lei , Jin Jianfeng , Zhang Erlin
Published: August 2024

The effect of the extrusion process on the microstructure, corrosion, and mechanical properties of Mg–Zn–Ca–Zr alloy has been investigated. Zn and Ca were both in a solid solution and only the Zr-rich phase was observed in the homogenized and extruded alloys. The Zr-rich phase was obviously refined after extrusion. The corrosion rate of the homogenized alloy decreased by about 25% after extrusion. This is because the refined Zr-rich phase was easier to cover with the deposited corrosion products, which reduced the cathodic reaction activity of the Zr-rich phase. The corrosion rate is similar for the alloys extruded at 320 °C and 350 °C since the size and distribution of the Zr-rich phase were not different in the two conditions. The alloy extruded at 320 °C has a smaller grain size and better comprehensive mechanical properties.
Improvement of Hydrogen-Resistant Gas Turbine Engine Blades: Single-Crystal Superalloy Manufacturing Technology
Authors: Balitskii Alexander I. , Kvasnytska Yulia H. , Ivaskevych Ljubomyr M. , Kvasnytska Katrine H. , Balitskii Olexiy A. , Miskiewicz Radoslaw M. , Noha Volodymyr O. , Parkhomchuk Zhanna V. , Veis Valentyn I. , Dowejko Jakub Maciej
Published: August 2024

This paper presents the results of an analysis of resistance to hydrogen embrittlement and offers solutions and technologies for manufacturing castings of components for critical applications, such as blades for gas turbine engines (GTEs). The values of the technological parameters for directional crystallization (DC) are determined, allowing the production of castings with a regular dendritic structure of the crystallization front in the range of 10 to 12 mm/min and a temperature gradient at the crystallization front in the range of 165–175 °C/cm. The technological process of making GTE blades has been improved by using a scheme for obtaining disposable models of complex profile castings with the use of 3D printing for the manufacture of ceramic molds. The ceramic mold is obtained through an environmentally friendly technology using water-based binders. Short-term tensile testing of the samples in gaseous hydrogen revealed high hydrogen resistance of the CM-88 alloy produced by directed crystallization technology: the relative elongation in hydrogen at a pressure of 30 MPa increased from 2% for the commercial alloy to 8% for the experimental single-crystal alloy.
Unraveling the Magnetic Properties of NiO Nanoparticles: From Synthesis to Nanostructure
Authors: Moya Carlos , Ara Jorge , Labarta Amílcar , Batlle Xavier
Published: August 2024

NiO nanoparticles have garnered significant interest due to their diverse applications and unique properties, which differ markedly from their bulk counterparts. NiO nanoparticles are p-type semiconductors with a wide bandgap, high discharge capacity, and high carrier density, making them ideal for use in batteries, sensors, and catalysts. Their ability to generate reactive oxygen species also imparts disinfectant and antibiotic properties. Additionally, the higher Néel temperature of NiO compared with other antiferromagnetic materials makes it suitable for high-temperature applications in spintronic devices and industrial settings. This review focuses on the critical role of structure and composition in determining the magnetic properties of NiO nanoparticles. It examines how finite-size surface effects, morphology, crystallinity, and nickel distribution influence these properties. Fundamental physical properties and characterization techniques are discussed first. Various synthesis methods and their impact on NiO nanoparticle properties are then explored. Their magnetic phenomenology is examined in detail, highlighting the effects of finite size, particle composition and surface, and crystal quality. The review concludes with a summary of key insights and future research directions for optimizing NiO nanoparticles in technological applications.
An Enhanced Credit Risk Evaluation by Incorporating Related Party Transaction in Blockchain Firms of China
Authors: Chen Ying , Liu Lingjie , Fang Libing
Published: August 2024

Related party transactions (RPTs) can serve as channels for the spread of credit risk events among blockchain firms. However, current credit risk-assessment models typically only consider a firm’s individual characteristics, overlooking the impact of related parties in the blockchain. We suggest incorporating RPT network analysis to improve credit risk evaluation. Our approach begins by representing an RPT network using a weighted adjacency matrix. We then apply DANE, a deep network embedding algorithm, to generate condensed vector representations of the firms within the network. These representations are subsequently used as inputs for credit risk-evaluation models to predict the default distance. Following this, we employ SHAP (Shapley Additive Explanations) to analyze how the network information contributes to the prediction. Lastly, this study demonstrates the enhancing effect of using DANE-based integrated features in credit risk assessment.
A Penalized Empirical Likelihood Approach for Estimating Population Sizes under the Negative Binomial Regression Model
Authors: Ji Yulu , Liu Yang
Published: August 2024

In capture–recapture experiments, the presence of overdispersion and heterogeneity necessitates the use of the negative binomial regression model for inferring population sizes. However, within this model, existing methods based on likelihood and ratio regression for estimating the dispersion parameter often face boundary and nonidentifiability issues. These problems can result in nonsensically large point estimates and unbounded upper limits of confidence intervals for the population size. We present a penalized empirical likelihood technique for solving these two problems by imposing a half-normal prior on the population size. Based on the proposed approach, a maximum penalized empirical likelihood estimator with asymptotic normality and a penalized empirical likelihood ratio statistic with asymptotic chi-square distribution are derived. To improve numerical performance, we present an effective expectation-maximization (EM) algorithm. In the M-step, optimization for the model parameters could be achieved by fitting a standard negative binomial regression model via the R basic function glm.nb(). This approach ensures the convergence and reliability of the numerical algorithm. Using simulations, we analyze several synthetic datasets to illustrate three advantages of our methods in finite-sample cases: complete mitigation of the boundary problem, more efficient maximum penalized empirical likelihood estimates, and more precise penalized empirical likelihood ratio interval estimates compared to the estimates obtained without penalty. These advantages are further demonstrated in a case study estimating the abundance of black bears (Ursus americanus) at the U.S. Army’s Fort Drum Military Installation in northern New York.
Weak ψ-Contractions on Directed Graphs with Applications to Integral Equations
Authors: Filali Doaa , Dilshad Mohammad , Akram Mohammad
Published: August 2024

This article deals with a few outcomes ensuring the fixed points of a weak (G,ψ)-contraction map of metric spaces comprised with a reflexive and transitive digraph G. To validate our findings, we furnish several examples. The findings we obtain enable us to seek out the unique solution of a nonlinear integral equation. The outcomes presented herewith sharpen, subsume, unify, improve, enrich, and compile a number of existing theorems.
A Two-Echelon Routing Model for Sustainable Last-Mile Delivery with an Intermediate Facility: A Case Study of Pharmaceutical Distribution in Rome
Authors: De Maio Annarita
Published: August 2024

This paper introduces a two-echelon optimization model for the integrated routing of an electric vehicle (EV) and a traditional internal combustion engine vehicle (ICEV) in an urban environment. The scientific context of this study is sustainable urban logistics. The case study focuses on the distribution of pharmaceuticals in the metropolitan area of Rome. Distributing pharmaceuticals in large cities presents significant challenges, including heavy traffic congestion, the need for strict temperature control, and the maintenance of the integrity and timely delivery of sensitive medications. Furthermore, the complexity of urban logistics and adherence to regulatory requirements introduce additional layers of difficulty. Therefore, the implementation of fast and sustainable distribution mechanisms is crucial in this context. Specifically, the model seeks to minimize both total CO2 emissions and transportation costs while optimizing the use of an EV and an ICEV, all while ensuring that service level requirements are met. Computational results demonstrate the effectiveness of the proposed method in improving the sustainability of pharmaceutical distribution.
Comprehensive Assessment of Herbicide Toxicity on Navicula sp. Algae: Effects on Growth, Chlorophyll Content, Antioxidant System, and Lipid Metabolism
Authors: Zheng Chunyan , Yang Jie , Wang Yunting , Ahmed Waqas , Khan Amir , Li Jiannan , Weng Jiechang , Mehmood Sajid , Li Weidong
Published: August 2024

This study investigated the effects of herbicide exposure on Navicula sp. (MASCC-0035) algae, focusing on growth density, chlorophyll content, antioxidant system, and lipid metabolism. Navicula cultures were exposed to different concentrations of atrazine (ATZ), glyphosate (Gly), and acetochlor (ACT) for 96 h. Results showed a significant decrease in cell numbers, with higher herbicide concentrations having the most noticeable impacts. For instance, Gly-G2 had reduced cell populations by 21.00% at 96 h. Chlorophyll content varied, with Gly having a greater impact on chlorophyll a compared to ATZ and ACT. Herbicide exposure also affected the antioxidant system, altering levels of soluble sugar, soluble protein, and reactive oxygen species (ROS). Higher herbicide rates increased soluble sugar content (e.g., ATZ, Gly, and ACT-G2 had increased by 14.03%, 19.88%, and 19.83%, respectively, at 72 h) but decreased soluble protein content, notably in Gly-G2 by 11.40%, indicating cellular stress. Lipid metabolism analysis revealed complex responses, with changes in free proline, fatty acids, and lipase content, each herbicide exerting distinct effects. These findings highlight the multifaceted impacts of herbicide exposure on Navicula algae, emphasizing the need for further research to understand ecological implications and develop mitigation strategies for aquatic ecosystems.
Diagnostic Value of Whole-Body MRI in Pediatric Patients with Suspected Rheumatic Diseases
Authors: Ożga Joanna , Ostrogórska Monika , Wojciechowski Wadim , Żuber Zbigniew
Published: August 2024

Background and Objectives: The diagnosis of rheumatic diseases in children is challenging and requires the use of advanced imaging examinations such as whole-body magnetic resonance imaging (MRI). Whole-body MRI allows visualization of bone marrow edema (BME), muscle edema, joint effusion and changes in the soft tissues surrounding the joints. The aim of this study was to collect and compare whole-body MRI findings, laboratory results and clinical manifestations of pediatric patients with suspected rheumatic disease. Materials and methods: In this retrospective single-center study, 33 patients who underwent whole-body MRI were included. Their age ranged from 9 to 17 years, and 24 (72.73%) of the patients were female. Patients were diagnosed as follows: juvenile idiopathic arthritis (27.27%), juvenile idiopathic inflammatory myopathies (21.21%), chronic nonbacterial osteomyelitis (21.21%) and other medical conditions (30.30%), such as arthritis associated with infection, scleroderma, Takayasu arteritis, polyarteritis nodosa and joint damage. Results: The most common symptom reported by 26 (79.79%) patients was pain. On physical examination, the limitation of joint mobility was examined in 17 (51.51%), swelling of the joints was observed in 12 (36.36%) patients and decreased muscle strength was noticed in 11 (33.33%) patients. An increase in the C-reactive protein (12%), erythrocyte sedimentation rate (9%), leukocyte count (9%) and creatine kinase (CK) (18%) was observed. Whole-body MRI revealed myositis (30%), joint effusion (27%) and BME (24%). The statistical analysis showed a significant relationship between myositis and the elevated CK level (p < 0.05). Conclusions: The most common symptom in the studied population was pain, while the limitation of joint mobility was found in more than half of patients. Myositis was the most commonly imaged lesion on the whole-body MRI and it was related to an increase in the CK level.
Comparative Studies of the Properties of Copper Components: Conventional vs. Additive Manufacturing Technologies
Authors: Malec Witold , Kulasa Joanna , Brudny Anna , Hury Anna , Adamczyk Bartlomiej , Rzepecki Ryszard , Sekula Robert , Kmita Grzegorz , Rybak Andrzej
Published: August 2024

This article presents a comparative analysis of the crucial physical properties of electrically conductive components made of pure copper, produced by various additive manufacturing technologies such as binder jetting (BJ) and direct metal laser sintering (DMLS). The comparison concerned the assessment of critical parameters important from the application point of view, such as: electrical conductivity, hardness, yield point, microstructure and the occurrence of internal material defects. Same-sized components made in a conventional casting and subtractive method (machining) were used as a reference material. Comprehensive tests and the comparison of a wide range of parameters allowed us to determine that among the selected methods, printing using the DMLS technique allowed for obtaining arcing contact with mechanical and electrical parameters very similar to the reference element. Therefore, the obtained results showed the possibility of using the copper elements made by additive manufacturing for the switching and protection devices used in electrification and energy distribution industrial sectors.
Effect of Ti and S Content on the Properties and Machinability of Low-Carbon Ferritic–Pearlitic Steel
Authors: Arh Boštjan , Tehovnik Franc , Vode Franci , Podgornik Bojan
Published: August 2024

This research was focused on the effect of Ti and S content on the formation of non-metallic inclusions and their influence on the mechanical properties and machinability of low-carbon ferritic–pearlitic steels. An analysis and classification of the non-metallic inclusions were carried out. The tensile strength and impact toughness were determined from samples taken in the rolling direction. Machinability investigations were carried out on a CNC turning machine and by analyzing the surface roughness. TiO-TiN inclusions are present in steels with an increased Ti content. In these steels, the hardness, tensile strength, and cutting forces increase with a higher proportion of Ti. In the second group of steels with increased contents of S, Al, and Ca, MnS and CaO-Al2O3-MnS non-metallic inclusions are formed. As the S content increases, the tensile strength and cutting forces decrease, while the impact toughness increases. In steels with added Ti, the machining is more difficult, but a finer surface is achieved after turning, while a higher S content results in an increased fraction of softer sulfide inclusions, which reduce the cutting forces but also result in a reduced surface quality.
Microbiological Quality and Antibiotic Resistance of Relevant Bacteria from Horsemeat
Authors: Gonzalez-Fandos Elena , da Silva Guedes Jessica
Published: August 2024

The aim of this work was to assess the microbiological safety and quality of horsemeat. A total of 19 fresh horsemeat samples were analysed. Mesophile counts were 4.89 ± 1.08 log CFU/g, and Enterobacteriaceae, Staphylococcus spp., and enterococci were only isolated from 36.84%, 21.05%, and 15.79% of the samples, respectively. Neither Staphylococcus aureus nor Escherichia coli were found in any sample. Listeria spp. and Listeria monocytogenes were detected in 31.58% and 21.05% of the samples, respectively. Campylobacter jejuni was not detected in any sample. The dominant bacteria were lactic acid bacteria. Seven different Staphylococcus spp. were identified, the most common being S. delphini, S. saprophyticus, and S. warneri. S. delphini showed resistance against mupirocin and cefoxitin. All the L. monocytogenes strains showed resistance against ampicillin, cefotaxime, and oxacillin. Multi-resistant Yersinia enterocolitica, Stenotrophomonas maltophilia, and Vagococcus. fluvialis strains were found, with resistance to 11, 7, and 8 antibiotics, respectively, causing significant concern. Therefore, specific actions should be taken to decrease the contamination of horsemeat.
Extended-Spectrum Beta-Lactamase- and Plasmidic AmpC-Producing Enterobacterales among the Faecal Samples in the Bulgarian Community
Authors: Stankova Petya , Boyanova Lyudmila , Atanasova Daniela , Mihaylova Sashka , Sredkova Mariya , Gergova Raina , Mihova Kalina , Markovska Rumyana
Published: August 2024

The aim of the present work was to genetically characterise cefotaxime-resistant enterobacteria isolated from community carriers in Bulgaria. In total, 717 faecal samples from children and adults in five medical centres in Sofia, Pleven and Burgas were examined. Antimicrobial susceptibility was evaluated by the disk diffusion method. blaESBL or plasmidic AmpC (pAmpC) genes were detected by PCR and sequencing. MLST and ERIC-PCR were used to detect clonal relatedness. Among the faecal samples, 140 cefotaxime-resistant enterobacteria were found. The most frequently detected species was Escherichia coli (77.9%, 109/140 samples), followed by Klebsiella pneumoniae (7.9%, 11/140). Among the isolates, blaCTX-M-15 (37.1%) was predominant, followed by blaCTX-M-3 (19.2%), blaCTX-M-14 (10%), and blaCTX-M-27 (4.3 %). Genes encoding pAmpC were observed in 11.4% (blaDHA-1, 16/140) and in 1.4% (blaCMY-2, 2/140). The frequency of ESBL and pAmpC producers among the subjects was 14.6% and 2.5%, respectively. No carbapenem-resistant isolates were found. Four main clonal complexes (CC131, CC10, CC38, and CC155) were detected among E. coli isolates. The most common type was ST131, phylogroup B2 (16.5%). The increased frequency of ESBL- and pAmpC-producing enterobacteria in the community is a prerequisite for treatment failures of the associated infections and a good background for further studies.
The Relative Importance of Cytotoxins Produced by Methicillin-Resistant Staphylococcus aureus Strain USA300 for Causing Human PMN Destruction
Authors: Nygaard Tyler K. , Borgogna Timothy R. , Pallister Kyler B. , Predtechenskaya Maria , Burroughs Owen S. , Gao Annika , Lubick Evan G. , Voyich Jovanka M.
Published: August 2024

Staphylococcus aureus (S. aureus) is a prominent Gram-positive bacterial pathogen that expresses numerous cytotoxins known to target human polymorphonuclear leukocytes (PMNs or neutrophils). These include leukocidin G/H (LukGH, also known as LukAB), the Panton–Valentine leukocidin (PVL), γ-hemolysin A/B (HlgAB), γ-hemolysin B/C (HlgBC), leukocidin E/D (LukED), α-hemolysin (Hla), and the phenol-soluble modulin-α peptides (PSMα). However, the relative contribution of each of these cytotoxins in causing human PMN lysis is not clear. In this study, we used a library of cytotoxin deletion mutants in the clinically relevant methicillin-resistant S. aureus (MRSA) isolate LAC (strain ST8:USA300) to determine the relative importance of each for causing human PMN lysis upon exposure to extracellular components as well as following phagocytosis. Using flow cytometry to examine plasma membrane permeability and assays quantifying lactose dehydrogenase release, we found that PVL was the dominant extracellular factor causing human PMN lysis produced by USA300. In contrast, LukGH was the most important cytotoxin causing human PMN lysis immediately following phagocytosis with contributions from the other bicomponent leukocidins only observed at later time points. These results not only clarify the relative importance of different USA300 cytotoxins for causing human PMN destruction but also demonstrate how two apparently redundant virulence factors play distinctive roles in promoting S. aureus pathogenesis.
Shifts in Fusarium Communities and Mycotoxins in Maize Residues, Soils, and Wheat Grains throughout the Wheat Cycle: Implications for Fusarium Head Blight Epidemiology
Authors: Nguyen Toan Bao Hung , Henri-Sanvoisin Amandine , Coton Monika , Le Floch Gaétan , Picot Adeline
Published: August 2024

Fusarium Head Blight (FHB), predominantly caused by Fusarium species, is a devastating cereal disease worldwide. While considerable research has focused on Fusarium communities in grains, less attention has been given to residues and soil, the primary inoculum sources. Knowledge of Fusarium spp. diversity, dynamics, and mycotoxin accumulation in these substrates is crucial for assessing their contribution to wheat head infection and the complex interactions among Fusarium communities throughout the wheat cycle. We monitored six minimum-tillage wheat fields, with maize as the preceding crop, over two years. Soils, maize residues, and wheat grains were sampled at four stages. Fusarium composition was analyzed using a culture-dependent method, species-specific qPCR, and EF1α region metabarcoding sequencing, enabling species-level resolution. The Fusarium communities were primarily influenced by substrate type, accounting for 35.8% of variance, followed by sampling location (8.1%) and sampling stage (3.2%). Among the 32 identified species, F. poae and F. graminearum dominated grains, with mean relative abundances of 47% and 29%, respectively. Conversely, residues were mainly contaminated by F. graminearum, with a low presence of F. poae, as confirmed by species-specific qPCR. Notably, during periods of high FHB pressure, such as in 2021, F. graminearum was the dominant species in grains. However, in the following year, F. poae outcompeted F. graminearum, resulting in reduced disease pressure, consistent with the lower pathogenicity of F. poae. Source Tracker analysis indicated that residues were a more significant source of Fusarium contamination on wheat in 2021 compared to 2022, suggesting that F. graminearum in 2021 primarily originated from residues, whereas F. poae’s sources of infection need further investigation. Additionally, multiple mycotoxins were detected and quantified in maize residues during the wheat cycle, raising the question of their ecological role and impact on the soil microbiota.
Thermophysical Profile of Industrial Graphene Water-Based Nanofluids
Authors: Gal Soulayma , Cabaleiro David , Hassen Walid , Nasri Anaghim , Lafue Yannick , Pham-Huu Cuong , Ba Housseinou , Estellé Patrice
Published: August 2024

The exceptional properties of high-grade graphene make it an ideal candidate for thermal dissipation and heat exchange in energy applications and nanofluid development. Here, we present a comprehensive study of few-layer graphene (FLG) nanofluids prepared in an industrial context. FLG nanofluids were synthesized through an ultrasound-assisted mechanical exfoliation process of graphite in water with a green solvent. This method produces FLG of high structural quality and stable nanofluids, as demonstrated by electron microscope, dynamic light scattering and ζeta potential analyses. Thermal conductivity measurements of FLG-based nanofluids were conducted in the temperature range of 283.15 K to 313.15 K, with FLG concentrations ranging from 0.005 to 0.200% in wt. The thermal conductivity of FLG nanofluids is up to 20% higher than water. The modeling of nanofluid thermal conductivity reveals that this enhancement is supported by the influence of the thermal resistance at the FLG interface, and the content, average dimensions and flatness of FLG sheets; this latter varying with the FLG concentration in the nanofluid. Additionally, the density and heat capacity of FLG suspensions were measured and compared with theoretical models, and the rheological behavior of FLG nanofluids was evaluated. This behavior is mainly Newtonian, with a weak 5% viscosity increase.
Tailoring of Circularly Polarized Beams Employing Bound States in the Continuum in a Designed Photonic Crystal Metasurface Nanostructure
Authors: Xu Chunhao , Chao Minghao , Liu Zhizhong , Liu Qingsong , Zhang Wenjing , Zhuang Lingyun , Cheng Bo , Jiang Botao , Liu Jietao , Song Guofeng
Published: August 2024

We propose a photonic crystal (PC) nanostructure that combines bound states In the continuum (BIC) with a high-quality factor up to 107 for emitting circularly polarized beams. We break the in-plane inversion symmetry of the unit cell by tilting the triangular hole of the hexagonal lattice, resulting in the conversion of a symmetrically protected BIC to a quasi-BIC. High-quality circularly polarized light is obtained efficiently by adjusting the tilt angles of the hole and the thickness of the PC layer. By changing the hole’s geometry in the unit cell, the Q-factor of circularly polarized light is further improved. The quality factor can be adjusted from 6.0 × 103 to 1.7 × 107 by deliberately changing the shape of the holes. Notably, the proposed nanostructure exhibits a large bandgap, which significantly facilitates the generation of stable single-mode resonance. The proposed structure is anticipated to have practical applications in the field of laser technology, particularly in the advancement of low-threshold PC surface emitting lasers (PCSELs).
Molecular Mechanisms of Healthy Aging: The Role of Caloric Restriction, Intermittent Fasting, Mediterranean Diet, and Ketogenic Diet—A Scoping Review
Authors: Surugiu Roxana , Iancu Mihaela Adela , Vintilescu Ștefănița Bianca , Stepan Mioara Desdemona , Burdusel Daiana , Genunche-Dumitrescu Amelia Valentina , Dogaru Carmen-Adriana , Dumitra Gheorghe Gindrovel
Published: August 2024

As the population ages, promoting healthy aging through targeted interventions becomes increasingly crucial. Growing evidence suggests that dietary interventions can significantly impact this process by modulating fundamental molecular pathways. This review focuses on the potential of targeted dietary strategies in promoting healthy aging and the mechanisms by which specific nutrients and dietary patterns influence key pathways involved in cellular repair, inflammation, and metabolic regulation. Caloric restriction, intermittent fasting, the Mediterranean diet, as well as the ketogenic diet showed promising effects on promoting healthy aging, possibly by modulating mTORC1 AMPK, an insulin signaling pathway. By understanding the intricate interplay between diet and molecular pathways, we can develop personalized dietary strategies that not only prevent age-related diseases, but also promote overall health and well-being throughout the aging process.
Public Procurement Practices for Cereal Products in Polish Educational Institutions: Analysis and Implications for Nutrition Policy
Authors: Brukało Katarzyna , Kołodziejczyk Aleksandra , Nowak Justyna , Kowalski Oskar
Published: August 2024

Public procurement of food is crucial for ensuring proper nutrition and the provision of high-quality products in public institutions like schools and kindergartens. It should be seen as an investment in health promotion, particularly for young children. Notably, when no quality criteria are specified, the cheapest and often lowest-quality products are typically selected. This study analyzed 1126 public procurement orders processed by schools and kindergartens in Poland between November 2022 and March 2023, with a focus on cereal products and their derivatives. Of these orders, 197 met the inclusion criteria, yielding a total of 5084 cereal products for detailed analysis. The study assessed the quantities ordered and the quality characteristics specified in the procurement documents. The results revealed that the most commonly described criteria pertained to product composition, especially typical characteristics and the absence of additives. Sensorial characteristics such as consistency and color were also frequently specified, while sustainable public procurement criteria were mentioned the least, indicating their marginal importance in current procurement practices. This underscores the critical importance of establishing minimum standards for describing cereal products in terms of sensorial characteristics, composition, and sustainability. Such standards are essential for improving the quality of grain products supplied to public institutions and ensuring that these institutions actively contribute to promoting healthy eating habits among children.
Modifiable and Non-Modifiable Factors That Affect Human Milk Oligosaccharides Composition
Authors: Konieczna Małgorzata , Koryszewska-Bagińska Anna , Bzikowska-Jura Agnieszka , Chmielewska-Jeznach Magdalena , Jarzynka Sylwia , Olędzka Gabriela
Published: August 2024

Human milk, the gold standard in infant nutrition, is a unique fluid that provides essential nutrients such as lactose, lipids, proteins, and free oligosaccharides. While its primary role is nutritional, it also protects against pathogens. This protection mainly comes from immunoglobulins, with human milk oligosaccharides (HMOs) providing additional support by inhibiting pathogen binding to host cell ligands. The prebiotic and immune-modulatory activity of HMOs strongly depends on their structure. Over 200 individual structures have been identified so far, with the composition varying significantly among women. The structure and composition of HMOs are influenced by factors such as the Lewis blood group, secretor status, and the duration of nursing. HMO profiles are heavily influenced by maternal phenotypes, which are defined based on the expression of two specific fucosyltransferases. However, recent data have shown that HMO content can be modified by various factors, both changeable and unchangeable, including diet, maternal age, gestational age, mode of delivery, breastfeeding frequency, and race. The first part of this overview presents the historical background of these sugars and the efforts by scientists to extract them using the latest chromatography methods. The second part is divided into subchapters that examine modifiable and non-modifiable factors, reviewing the most recent articles on HMO composition variations due to specific reasons and summarizing potential future challenges in conducting these types of studies.
Treating Deep-Seated Tumors with Radiodynamic Therapy: Progress and Perspectives
Authors: Zhu Shengcang , Lin Siyue , Han Rongcheng
Published: August 2024

Radiodynamic therapy (RDT), as an emerging cancer treatment method, has attracted attention due to its remarkable therapeutic efficacy using low-dose, high-energy radiation (such as X-rays) and has shown significant potential in cancer treatment. The RDT system typically consists of scintillators and photosensitizers (PSs). Scintillators absorb X-rays and convert them to visible light, activating nearby PSs to generate cytotoxic reactive oxygen species (ROS). Challenges faced by the two-component strategy, including low loading capacity and inefficient energy transfer, hinder its final effectiveness. In addition, the tumor microenvironment (TME) with hypoxia and immunosuppression limits the efficacy of RDTs. Recent advances introduce one-component RDT systems based on nanomaterials with high-Z metal elements, which effectively inhibit deep-seated tumors. These novel RDT systems exhibit immune enhancement and immune memory, potentially eliminating both primary and metastatic tumors. This review comprehensively analyzes recent advances in the rational construction of RDTs, exploring their mechanisms and application in the treatment of deep-seated tumors. Aimed at providing a practical resource for oncology researchers and practitioners, the review offers new perspectives for potential future directions in RDT research.
Developments of Waveguide Lasers by Femtosecond Laser Direct–Writing Technology
Authors: Zhang Yang , Yu Boyan , Zhang Zihao , Duan Xinghao , Wang Junli
Published: August 2024

Waveguide lasers have the advantages of miniature and compact structure and have broad application prospects in photonic integration and on–chip laboratories. The development of femtosecond laser direct–writing technology makes the processing of transparent materials more flexible and controllable. This paper mainly introduces a waveguide laser based on femtosecond laser direct–writing technology. Firstly, the applications of femtosecond laser direct–writing technology in an optical waveguide are introduced, including the principles of femtosecond laser direct–writing technology, common optical wave scanning methods, and types of optical waveguides. After that, we summarize the development of a waveguide continuous–wave laser, a Q–switched laser and a mode–locked laser from visible to mid–infrared wavebands and analyze some new representative work. Finally, we explain the difficulty of compensating for dispersion in pulse waveguide lasers and summarize some new ideas that have been proposed to solve the problem.
Effects of Water and Nitrogen Regulation on Apple Tree Growth, Yield, Quality, and Their Water and Nitrogen Utilization Efficiency
Authors: Li Xingqiang , Li Siqi , Qiang Xiaolin , Yu Zhao , Sun Zhaojun , Wang Rong , He Jun , Han Lei , Li Qian
Published: August 2024

Apple tree productivity is influenced by the quantity of water and nutrients that are supplied during planting. To enhance resource utilization efficiency and optimize yields, a suitable strategy for supplying water and nitrogen must be established. A field experiment was conducted using a randomized block group design on five-year-old apple trees in Ningxia, with two irrigation lower limit levels (55%FC (W1) and 75%FC (W2)) and four N application levels (0 (N1), 120 (N2), 240 (N3), and 360 (N4) kg·ha−1). Our findings showed that leaf N content increased with a higher irrigation lower limit, but the difference was not statistically significant. However, the leaf N content significantly increased with increasing N application. The growth pattern of new shoots followed logistic curve characteristics, with the maximum new shoot growth rate and time of new shoot growth being delayed under high water and high nitrogen treatments. Apple yield and yield components (weight per fruit and number of fruits per plant) were enhanced under N application compared to no N application. The maximum apple yields were 19,405.3 kg·ha−1 (2022) and 29,607 kg·ha−1 (2023) at the N3 level. A parabolic relationship was observed between apple yield and N application level, with the optimal range of N application being 230–260 kg⸱ha−1. Apple quality indicators were not significantly affected by the irrigation lower limit but were significantly influenced by N application levels. The lower limit of irrigation did not have a significant impact on the quality indicators of the apples. Water and N utilization efficiencies improved with the W2 treatment at the same N application level. A negative relationship was observed between the amount of nitrogen applied and the biased productivity of nitrogen fertilizer. The utilization of nitrogen fertilizer was 127.6 kg·kg−1 (2022) and 200.3 kg·kg−1 (2023) in the W2N2 treatment. The apple yield was sustained, the quality of the fruit improved, and a substantial increase in water productivity was achieved with the W2N3 treatment. The findings of this study can be used as a reference for accurate field irrigation.
Prasiolopsis wulf-kochii (Prasiolales, Trebouxiophyceae), a New Species Occurring in Hairs of the Sloth Bradypus tridactylus
Authors: Darienko Tatyana , Pröschold Thomas
Published: August 2024

The monotypic genus Prasiolopsis has been known for a long time, but is often overlooked because of difficulties in identification and the morphological variability between uniseriate filaments and cell packages forming pseudoparenchymatic thalli depending on age. We investigated a strain (SAG 84.81) originally denoted as Trichophilus welckeri, which was isolated from the hairs of the sloth Bradypus tridactylus, and compared it with other available strains of Prasiolopsis and of the sister genus Pseudomarvania. Our investigations clearly showed that this strain differed in morphology, especially of the chloroplast, from those originally described for Trichophilus. Phylogenetic analyses of the SSU and ITS rDNA sequences revealed that the strain SAG 84.81 is sister to several strains of P. ramosa within the Prasiola clade (Trebouxiophyceae). Using the ITS-2/CBC approach, we clearly demonstrated that this strain represented a new species of Prasiolopsis, which we proposed here as P. wulf-kochii. In addition, we evaluated the ITS-2/CBC approach by comparing it with the two species of Pseudomarvania. All investigated strains showed CBCs and HCBCs, which support their species delimitation. The sequencing data of Trichophilus welckeri available in GenBank were phylogenetically re-evaluated by including all representatives of the Ulotrichales (Ulvophyceae). Our analyses showed that these sequences formed their own lineage within this order.
Physiological Responses and Salt Tolerance Evaluation of Different Varieties of Bougainvillea under Salt Stress
Authors: Zhang Di , Xue Yuan , Feng Ning , Bai Jing , Ma Dexing , Sheng Qianqian , Cao Fuliang , Zhu Zunling
Published: August 2024

Soil salinization significantly impacts the ecological environment and agricultural production, posing a threat to plant growth. Currently, there are over 400 varieties of Bougainvillea with horticultural value internationally. However, research on the differences in salt tolerance among Bougainvillea varieties is still insufficient. Therefore, this study aims to investigate the physiological responses and tolerance differences of various Bougainvillea varieties under different concentrations of salt stress, reveal the effects of salt stress on their growth and physiology, and study the adaptation mechanisms of these varieties related to salt stress. The experimental materials consisted of five varieties of Bougainvillea. Based on the actual salinity concentrations in natural saline-alkali soils, we used a pot-controlled salt method for the experiment, with four treatment concentrations set: 0.0% (w/v) (CK), 0.2% (w/v), 0.4% (w/v), and 0.6% (w/v). After the Bougainvillea plants grew stably, salt stress was applied and the growth, physiology, and salt tolerance of the one-year-old plants were systematically measured and assessed. The key findings were as follows: Salt stress inhibited the growth and biomass of the five varieties of Bougainvillea; the ‘Dayezi’ variety showed severe salt damage, while the ‘Shuihong’ variety exhibited minimal response. As the salt concentration and duration of salt stress increase, the trends of the changes in antioxidant enzyme activity and osmotic regulation systems in the leaves of the five Bougainvillea species differ. Membrane permeability and the production of membrane oxidative products showed an upward trend with stress severity. The salt tolerance of the five varieties of Bougainvillea was comprehensively evaluated through principal component analysis. It was found that the ‘Shuihong’ variety exhibited the highest salt tolerance, followed by the ‘Lvyehuanghua’, ‘Xiaoyezi’, ‘Tazi’, and ‘Dayezi’ varieties. Therefore, Bougainvillea ‘Shuihong’, ‘Lvyehuanghua’, and ‘Xiaoyezi’ are recommended for extensive cultivation in saline-alkali areas. The investigation focuses primarily on how Bougainvillea varieties respond to salt stress from the perspectives of growth and physiological levels. Future research could explore the molecular mechanisms behind the responses to and tolerance of different Bougainvillea varieties as to salt stress, providing a more comprehensive understanding and basis for practical applications.
Straw Tar Epoxy Resin for Carbon Fiber-Reinforced Plastic: A Review
Authors: Jiang Zhanpeng , He Jingyi , Li Huijie , Liu Yiming , Pang Jiuyin , Li Chuanpeng , Jiang Guiquan
Published: August 2024

The massive consumption of fossil fuels has led to the serious accumulation of carbon dioxide gas in the atmosphere and global warming. Bioconversion technologies that utilize biomass resources to produce chemical products are becoming widely accepted and highly recognized. The world is heavily dependent on petroleum-based products, which may raise serious concerns about future environmental security. Most commercially available epoxy resins (EPs) are synthesized by the condensation of bisphenol A (BPA), which not only affects the human endocrine system and metabolism, but is also costly to produce and environmentally polluting. In some cases, straw tar-based epoxy resins have been recognized as potential alternatives to bisphenol A-based epoxy resins, and are receiving increasing attention due to their important role in overcoming the above problems. Using straw tar and lignin as the main raw materials, phenol derivatives were extracted from the middle tar instead of bisphenol A. Bio-based epoxy resins were prepared by replacing epichlorohydrin with epoxylated lignin to press carbon fiber sheets, which is a kind of bio-based fine chemical product. This paper reviews the research progress of bio-based materials such as lignin modification, straw pyrolysis, lignin epoxidation, phenol derivative extraction, and synthesis of epoxy resin. It improves the performance of carbon fiber-reinforced plastic (CFRP) while taking into account the ecological and environmental protection, so that the epoxy resin is developed in the direction of non-toxic, harmless and high-performance characteristics, and it also provides a new idea for the development of bio-based carbon fibers.
Synthesis, Characterization and Application of Advanced Antimicrobial Electrospun Polymers
Authors: Somogyi Škoc Maja , Meštrović Ernest , Mouthuy Pierre-Alexis , Rezić Iva
Published: August 2024

The aim of this work was to synthesize, characterize and apply advanced antimicrobial biocompatible electrospun polymers suitable for medical implants for surgical repairs. Injuries to the musculoskeletal system often necessitate surgical repair, but current treatments can still lead to high failure rates, such as 40% for the repair of rotator cuff tears. Therefore, there is an urgent need for the development of new biocompatible materials that can effectively support the repair of damaged tissues. Additionally, infections acquired during hospitalization, particularly those caused by antibiotic-resistant bacteria, result in more fatalities than AIDS, tuberculosis, and viral hepatitis combined. This underscores the critical necessity for the advancement of antimicrobial implants with specialized coatings capable of combating Methicillin-resistant Staphylococcus aureus (MRSA) and Methicillin-sensitive Staphylococcus aureus (MSSA), two strains notoriously known for their antibiotic resistance. Therefore, we developed an antimicrobial coating incorporating nanoparticle mixtures using the sol-gel process and applied it to electrospun polycaprolactone (PCL) filaments, followed by thorough characterization by using spectroscopic (FTIR, Raman, NMR) microscopic (SEM and SEM-EDX), and tensile test. The results have shown that the integration of electro-spinning technology for yarn production, coupled with surface modification techniques, holds significant potential for creating antimicrobial materials suitable for medical implants for surgical repairs.