bluuebunny/crossref_metadata_2025 huggingface dataset:
Vibration Feature Analysis for Gas-Insulated Switchgear Mechanical Fault Detection under Varying Current
Authors: Feng Ying , Wu Jianwen
Published: February 2020

As a key component to ensure the safe operation of the power grid, mechanical defect diagnosis technology of gas-insulated switchgear (GIS) during operation is often neglected. At present, GIS mechanical fault detection based on vibration information has not been developed. The main reason is that the excitation current is considerable but uncontrollable in the actual operation of GIS. It is difficult to eliminate the influence of excitation on the vibration amplitude and form an effective vibration feature description technology. Therefore, this paper proposes a unified feature-extraction method for GIS vibration information that reduces the influence of current amplitude for mechanical fault diagnosis. Starting from the GIS mechanical analysis, the periodicity of vibration excitation and the influence of amplitude are discussed. Then, combined with the non-linear characteristics of GIS systems and non-linear vibration theory, the multiplier frequency energy ratio (MFER) is designed to extract vibration-unified features of GIS for diagnosing the mechanical fault under different current levels. The diagnosis results of the experimental data with different feature-extraction methods show the applicability and superiority of the proposed method in the GIS’s mechanical fault-detection field based on vibration information.
Spouted-Bed Gasification of Flame Retardant Textiles as a Potential Non-Conventional Biomass
Authors: Yasin Sohail , Curti Massimo , Rovero Giorgio , Hussain Munir , Sun Danmei
Published: February 2020

Renewable energy from thermal valorization plays a key part in today’s energy from natural cellulosic textiles that are resourceful biomass and safe from toxicity at high temperature treatments. The situation is opposite, when technical textiles are treated with synthetic chemical finishes adding functionality as anti-bacterial, water repellent or flame retardant, etc. Incineration of flame retardant textile results in possible unfavorable gases, toxic fumes and contaminated ash. Other thermal valorization techniques like gasification would assist in avoiding the formation of additional toxic hazards. Herein, gasification of flame retardant textile is carried out the likelihood to get quality gas composition. For comparative analysis, flame retardant textiles, after their flame retardant ability being revoked, are also gasified. The output gas components suggested that gasification can be a useful thermal valorization approach for flame retardant textiles and relevantly improved gas composition was seen in textiles with their flame retardant substrate/species being removed.
Plant-Derived Bioactives and Oxidative Stress-Related Disorders: A Key Trend towards Healthy Aging and Longevity Promotion
Authors: Salehi Bahare , Azzini Elena , Zucca Paolo , Maria Varoni Elena , V. Anil Kumar Nanjangud , Dini Luciana , Panzarini Elisa , Rajkovic Jovana , Valere Tsouh Fokou Patrick , Peluso Ilaria , Prakash Mishra Abhay , Nigam Manisha , El Rayess Youssef , El Beyrouthy Marc , N. Setzer William , Polito Letizia , Iriti Marcello , Sureda Antoni , Magdalena Quetglas-Llabrés Maria , Martorell Miquel , Martins Natália , Sharifi-Rad Mehdi , M. Estevinho Leticia , Sharifi-Rad Javad
Published: February 2020

Plants and their corresponding botanical preparations have been used for centuries due to their remarkable potential in both the treatment and prevention of oxidative stress-related disorders. Aging and aging-related diseases, like cardiovascular disease, cancer, diabetes, and neurodegenerative disorders, which have increased exponentially, are intrinsically related with redox imbalance and oxidative stress. Hundreds of biologically active constituents are present in each whole plant matrix, providing promissory bioactive effects for human beings. Indeed, the worldwide population has devoted increased attention and preference for the use of medicinal plants for healthy aging and longevity promotion. In fact, plant-derived bioactives present a broad spectrum of biological effects, and their antioxidant, anti-inflammatory, and, more recently, anti-aging effects, are considered to be a hot topic among the medical and scientific communities. Nonetheless, despite the numerous biological effects, it should not be forgotten that some bioactive molecules are prone to oxidation and can even exert pro-oxidant effects. In this sense, the objective of the present review is to provide a detailed overview of plant-derived bioactives in age-related disorders. Specifically, the role of phytochemicals as antioxidants and pro-oxidant agents is carefully addressed, as is their therapeutic relevance in longevity, aging-related disorders, and healthy-aging promotion. Finally, an eye-opening look into the overall evidence of plant compounds related to longevity is presented.
Force and Sound Pressure Sensors Used for Modeling the Impact of the Firearm with a Suppressor
Authors: Selech Jaroslaw , Kilikevičius Artūras , Kilikevičienė Kristina , Borodinas Sergejus , Matijošius Jonas , Vainorius Darius , Marcinkiewicz Jacek , Staszak Zaneta
Published: February 2020

In this paper, a mathematical model for projectiles shooting in any direction based on sensors distributed stereoscopically is put forward. It is based on the characteristics of a shock wave around a supersonic projectile and acoustical localization. Wave equations for an acoustic monopole point source of a directed effect used for physical interpretation of pressure as an acoustic phenomenon. Simulation and measurements of novel versatile mechanical and acoustical damping system (silencer), which has both a muzzle break and silencer properties studied in this paper. The use of the proposed damping system can have great influence on the acoustic pressure field intensity from the shooter. A silencer regarded as an acoustic transducer and multi-holes waveguide with a chamber. Wave equations for an acoustic monopole point source of a directed effect used for the physical interpretation of pressure as an acoustic phenomenon. The numerical simulation results of the silencer with different configurations presented allow trends to be established. A measurement chain was used to compare the simulation results with the experimental ones. The modeling and experimental results showed an increase in silencer chamber volume results in a reduction of recorded pressure within the silencer chamber.
An Intelligent Classification Model for Surface Defects on Cement Concrete Bridges
Authors: Zhu Jinsong , Song Jinbo
Published: February 2020

This paper mainly improves the visual geometry group network-16 (VGG-16), which is a classic convolutional neural network (CNN), to classify the surface defects on cement concrete bridges in an accurate manner. Specifically, the number of fully connected layers was reduced by one, and the Softmax classifier was replaced with a Softmax classification layer with seven defect tags. The weight parameters of convolutional and pooling layers were shared in the pre-trained model, and the rectified linear unit (ReLU) function was taken as the activation function. The original images were collected by a road inspection vehicle driving across bridges on national and provincial highways in Jiangxi Province, China. The images on surface defects of cement concrete bridges were selected, and divided into a training set and a test set, and preprocessed through morphology-based weight adaptive denoising. To verify its performance, the improved VGG-16 was compared with traditional shallow neural networks (NNs) like the backpropagation neural network (BPNN), support vector machine (SVM), and deep CNNs like AlexNet, GoogLeNet, and ResNet on the same sample dataset of surface defects on cement concrete bridges. Judging by mean detection accuracy and top-5 accuracy, our model outperformed all the contrastive methods, and accurately differentiated between images with seven classes of defects such as normal, cracks, fracturing, plate fracturing, corner rupturing, edge/corner exfoliation, skeleton exposure, and repairs. The results indicate that our model can effectively extract the multi-layer features from surface defect images, which highlights the edges and textures. The research findings shed important new light on the detection of surface defects and classification of defect images.
P-Wave Detection Using a Fully Convolutional Neural Network in Electrocardiogram Images
Authors: Costandy Rana N. , Gasser Safa M. , El-Mahallawy Mohamed S. , Fakhr Mohamed W. , Marzouk Samir Y.
Published: February 2020

Electrocardiogram (ECG) signal analysis is a critical task in diagnosing the presence of any cardiac disorder. There are limited studies on detecting P-waves in various atrial arrhythmias, such as atrial fibrillation (AFIB), atrial flutter, junctional rhythm, and other arrhythmias due to P-wave variability and absence in various cases. Thus, there is a growing need to develop an efficient automated algorithm that annotates a 2D printed version of P-waves in the well-known ECG signal databases for validation purposes. To our knowledge, no one has annotated P-waves in the MIT-BIH atrial fibrillation database. Therefore, it is a challenge to manually annotate P-waves in the MIT-BIH AF database and to develop an automated algorithm to detect the absence and presence of different shapes of P-waves. In this paper, we present the manual annotation of P-waves in the well-known MIT-BIH AF database with the aid of a cardiologist. In addition, we provide an automatic P-wave segmentation for the same database using a fully convolutional neural network model (U-Net). This algorithm works on 2D imagery of printed ECG signals, as this type of imagery is the most commonly used in developing countries. The proposed automatic P-wave detection method obtained an accuracy and sensitivity of 98.56% and 98.78%, respectively, over the first 5 min of the second lead of the MIT-BIH AF database (a total of 8280 beats). Moreover, the proposed method is validated using the well-known automatically and manually annotated QT database (a total of 11,201 and 3194 automatically and manually annotated beats, respectively). This results in accuracies of 98.98 and 98.9%, and sensitivities of 98.97 and 97.24% for the automatically and manually annotated QT databases, respectively. Thus, these results indicate that the proposed automatic method can be used for analyzing long-printed ECG signals on mobile battery-driven devices using only images of the ECG signals, without the need for a cardiologist.
Preparation of Palm Oil Ash Nanoparticles: Taguchi Optimization Method by Particle Size Distribution and Morphological Studies
Authors: Rizal Samsul , Abdullah C. K. , Olaiya N. G. , Sri Aprilia N. A. , Zein Ikramullah , Surya Indra , Abdul Khalil H. P. S.
Published: February 2020

The interest in the utilization of palm oil ash is high, mainly due to their renewable material, opportunity to enhance the properties and possibility to use in a wide range of applications. Palm oil ash is the by-product of the palm oil mill boilers and locally available in the form of micro-size particles. In this research, optimization of the milling process was designed using the Taguchi method to find the most influencing parameters for the preparation of palm oil ash (POA) nanoparticles using a ball milling technique. The experiment was applied using a L9 orthogonal array and signal to noise ratio to investigate the performance of parameters, which are milling time, milling speed, and balls size. The results from signal to noise ratio reveal that to produce POA nanoparticles in optimum parameters, the size of balls shows the highest significant effect on the production of POA nanoparticles, followed by milling time and speed. The results of the parameters optimization experiment were validated by a confirmation test of milling machine operations.
High-Intensity Ultrasound Pulses Effect on Physicochemical and Antioxidant Properties of Tilapia (Oreochromis niloticus) Skin Gelatin
Authors: Cuevas-Acuña Dulce Alondra , Arias-Moscoso Joe Luis , Torres-Arreola Wilfrido , Cadena-Cadena Francisco , Valdez-Melchor Ramón Gertrudis , Chaparro-Hernandez Sarai , Santacruz-Ortega Hisila del Carmen , Ruiz-Cruz Saúl
Published: February 2020

Ultrasonic pulses are considered green technology for the improvement of the functional properties of proteins. In this study, four high-intensity ultrasound pulse treatments (ultrasound-pulsed gelatin (UPG)-42, UPG-52, UPG-71, UPG-84, and non-pulsed control gelatin (CG)) were applied to tilapia (Oreochromis niloticus) skin gelatin in order to study their effect on its physicochemical and antioxidant properties; a non-treated gelatin was used as a control. UPGs showed a significant increase in soluble protein and surface hydrophobicity compared to the control gelatin, and no significant difference was found in the electrophoretic profiles. The effects on the secondary structure were studied by circular dichroism and infrared spectra, and these showed that the random coil conformation was the main component in all treatments and the ultrasonic treatments only affected the α-helix and β-sheet proportion. Finally, the ABTS ((2,2′-azino-bis-(3-ethylbenzothiazoline-6-sulfonic acid)) and FRAP (ferric reducing ability) assays demonstrated that ultrasound treatments could improve the antioxidant activity of gelatins as free radical scavengers and electron donors. These results suggest that high-intensity ultrasound pulse technology is useful to improve fish gelatin antioxidant properties, which could be associated with secondary structure disruption.
Introducing Applied Nano: An Interdisciplinary Open Access Journal Showing How Nanoscience Can Offer Solutions to Different Problems and Needs
Authors: Taglietti Angelo
Published: February 2020

The first question that came to mind when I received the proposal to lead the Editorial Board of Applied Nano was: “Do we really need a new nano-journal [...]
Oscillation Results for Higher Order Differential Equations
Authors: Park Choonkil , Moaaz Osama , Bazighifan Omar
Published: February 2020

The objective of our research was to study asymptotic properties of the class of higher order differential equations with a p-Laplacian-like operator. Our results supplement and improve some known results obtained in the literature. An illustrative example is provided.
Potential Antidiabetic Activity of Extracts and Isolated Compound from Adenosma bracteosum (Bonati)
Authors: Nguyen Ngoc Hong , Pham Quang Thang , Luong Thi Ngoc Han , Le Hoang Khai , Vo Van Giau
Published: February 2020

Adenosma bracteosum Bonati. (A. bracteosum) has been used in traditional and modern medicine in Vietnam for curing hepatitis. In this study, ethanol and aqueous extracts of A. bracteosum were evaluated for their α-glucosidase inhibitory activities and anti-hyperglycemic effects on glucose loaded hyperglycemic and streptozotocin (STZ) induced diabetic mice. The α-glucosidase inhibition of the extracts was evaluated by colorimetric assays, and the anti-diabetic activity was tested on a STZ-induced diabetic mice model. The ethanol and aqueous extracts showed a significant α-glucosidase inhibitory activity, which was more effective than acarbose at the same concentration. In the STZ-induced diabetic mice, both extracts showed a strong anti-hyperglycemic activity, with the group receiving 50 mg/kg of ethanol extract and the group receiving 50 mg/kg of aqueous extract presenting 64.42% and 57.69% reductions, respectively, in the blood glucose levels when compared with the diabetic control group, on day 21 (p > 0.05). Isoscutellarein-8-O-β-D-glucopyranoside (IG) was identified from the ethanol extract, which showed a strong inhibitory activity against α-glucosidase, with a ten times higher potency compared with the positive control acarbose. The anti-hyperglycemic effect of IG was effectively similar to the standard drug, glibenclamide, at the same dose of 10 mg/kg (p > 0.05). These results indicated that A. bracteosum has a great antidiabetic potential.
hNGF Peptides Elicit the NGF-TrkA Signalling Pathway in Cholinergic Neurons and Retain Full Neurotrophic Activity in the DRG Assay
Authors: Triaca Viviana , Fico Elena , Sposato Valentina , Caioli Silvia , Ciotti Maria Teresa , Zona Cristina , Mercanti Delio , La Mendola Diego , Satriano Cristina , Rizzarelli Enrico , Tirassa Paola , Calissano Pietro
Published: February 2020

In the last decade, Nerve Growth Factor (NGF)-based clinical approaches have lacked specific and efficient Tyrosine Kinase A (TrkA) agonists for brain delivery. Nowadays, the characterization of novel small peptidomimetic is taking centre stage in preclinical studies, in order to overcome the main size-related limitation in brain delivery of NGF holoprotein for Central Nervous System (CNS) pathologies. Here we investigated the NGF mimetic properties of the human NGF 1–14 sequence (hNGF1–14) and its derivatives, by resorting to primary cholinergic and dorsal root ganglia (DRG) neurons. Briefly, we observed that: 1) hNGF1–14 peptides engage the NGF pathway through TrkA phosphorylation at tyrosine 490 (Y490), and activation of ShcC/PI3K and Plc-γ/MAPK signalling, promoting AKT-dependent survival and CREB-driven neuronal activity, as seen by levels of the immediate early gene c-Fos, of the cholinergic marker Choline Acetyltransferase (ChAT), and of Brain Derived Neurotrophic Factor (BDNF); 2) their NGF mimetic activity is lost upon selective TrkA inhibition by means of GW441756; 3) hNGF1–14 peptides are able to sustain DRG survival and differentiation in absence of NGF. Furthermore, the acetylated derivative Ac-hNGF1–14 demonstrated an optimal NGF mimetic activity in both neuronal paradigms and an electrophysiological profile similar to NGF in cholinergic neurons. Cumulatively, the findings here reported pinpoint the hNGF1–14 peptide, and in particular its acetylated derivative, as novel, specific and low molecular weight TrkA specific agonists in both CNS and PNS primary neurons.
Development and Evaluation of a Screening Tool to Aid the Diagnosis of Cluster Headache
Authors: Buture Alina , Boland Jason W , Dikomitis Lisa , Huang Chao , Ahmed Fayyaz
Published: February 2020

Cluster headache (CH), a severe primary headache, is often misdiagnosed and mismanaged. The aim of this study was to develop and evaluate a screening tool to aid the diagnosis of CH. We developed a novel 12-item screening tool. This was comprised of four components: (1) images depicting headache pain; (2) pain descriptors; (3) key questions that could differentiate between CH and migraine; and (4) a visual analogue pain scale. The total possible questionnaire score ranged from 3-32. Patients with CH and migraines (control group) were recruited prospectively from a headache centre in the North of England, UK. Two-hundred and ninety-six patients were included in the study: 81 CH patients, 36 of which suffer with episodic CH and 45 with chronic CH; 215 migraine patients, 92 of which suffer with episodic migraine and 123 with chronic migraine. The mean questionnaire score was higher in CH patients versus migraine patients (28.4 versus 19.5). At a cut-off score of >25 out of 32, the screening tool had a sensitivity of 86.4% and a specificity of 92.0% in differentiating between CH and migraine. The screening tool could be a useful instrument to aid the diagnosis of a CH. The images depicting headache pain do not clearly discriminate between CH and migraine.
The RNA-Binding Ubiquitin Ligase MEX3A Affects Glioblastoma Tumorigenesis by Inducing Ubiquitylation and Degradation of RIG-I
Authors: Bufalieri Francesca , Caimano Miriam , Lospinoso Severini Ludovica , Basili Irene , Paglia Francesco , Sampirisi Luigi , Loricchio Elena , Petroni Marialaura , Canettieri Gianluca , Santoro Antonio , D’Angelo Luca , Infante Paola , Di Marcotullio Lucia
Published: February 2020

Glioblastoma multiforme (GB) is the most malignant primary brain tumor in humans, with an overall survival of approximatively 15 months. The molecular heterogeneity of GB, as well as its rapid progression, invasiveness and the occurrence of drug-resistant cancer stem cells, limits the efficacy of the current treatments. In order to develop an innovative therapeutic strategy, it is mandatory to identify and characterize new molecular players responsible for the GB malignant phenotype. In this study, the RNA-binding ubiquitin ligase MEX3A was selected from a gene expression analysis performed on publicly available datasets, to assess its biological and still-unknown activity in GB tumorigenesis. We find that MEX3A is strongly up-regulated in GB specimens, and this correlates with very low protein levels of RIG-I, a tumor suppressor involved in differentiation, apoptosis and innate immune response. We demonstrate that MEX3A binds RIG-I and induces its ubiquitylation and proteasome-dependent degradation. Further, the genetic depletion of MEX3A leads to an increase of RIG-I protein levels and results in the suppression of GB cell growth. Our findings unveil a novel molecular mechanism involved in GB tumorigenesis and suggest MEX3A and RIG-I as promising therapeutic targets in GB.
The Unfolded Protein Response: A Novel Therapeutic Target in Acute Leukemias
Authors: Martelli Alberto , Paganelli Francesca , Chiarini Francesca , Evangelisti Camilla , McCubrey James
Published: February 2020

The unfolded protein response (UPR) is an evolutionarily conserved adaptive response triggered by the stress of the endoplasmic reticulum (ER) due, among other causes, to altered cell protein homeostasis (proteostasis). UPR is mediated by three main sensors, protein kinase RNA-like endoplasmic reticulum kinase (PERK), activating transcription factor 6α (ATF6α), and inositol-requiring enzyme-1α (IRE1α). Given that proteostasis is frequently disregulated in cancer, UPR is emerging as a critical signaling network in controlling the survival, selection, and adaptation of a variety of neoplasias, including breast cancer, prostate cancer, colorectal cancer, and glioblastoma. Indeed, cancer cells can escape from the apoptotic pathways elicited by ER stress by switching UPR into a prosurvival mechanism instead of cell death. Although most of the studies on UPR focused on solid tumors, this intricate network plays a critical role in hematological malignancies, and especially in multiple myeloma (MM), where treatment with proteasome inhibitors induce the accumulation of unfolded proteins that severely perturb proteostasis, thereby leading to ER stress, and, eventually, to apoptosis. However, UPR is emerging as a key player also in acute leukemias, where recent evidence points to the likelihood that targeting UPR-driven prosurvival pathways could represent a novel therapeutic strategy. In this review, we focus on the oncogene-specific regulation of individual UPR signaling arms, and we provide an updated outline of the genetic, biochemical, and preclinical therapeutic findings that support UPR as a relevant, novel target in acute leukemias.
Catalytic Performance of Bulk and Al2O3-Supported Molybdenum Oxide for the Production of Biodiesel from Oil with High Free Fatty Acids Content
Authors: Navajas Alberto , Reyero Inés , Jiménez-Barrera Elena , Romero-Sarria Francisca , Llorca Jordi , Gandía Luis M.
Published: February 2020

Non-edible vegetable oils are characterized by high contents of free fatty acids (FFAs) that prevent from using the conventional basic catalysts for the production of biodiesel. In this work, solid acid catalysts are used for the simultaneous esterification and transesterification with methanol of the FFAs and triglycerides contained in sunflower oil acidified with oleic acid. Molybdenum oxide (MoO3), which has been seldom considered as a catalyst for the production of biodiesel, was used in bulk and alumina-supported forms. Results showed that bulk MoO3 is very active for both transesterification and esterification reactions, but it suffered from severe molybdenum leaching in the reaction medium. When supported on Al2O3, the MoO3 performance improved in terms of active phase utilization and stability though molybdenum leaching remained significant. The improvement of catalytic performance was ascribed to the establishment of MoO3-Al2O3 interactions that favored the anchorage of molybdenum to the support and the formation of new strong acidic centers, although this effect was offset by a decrease of specific surface area. It is concluded that the development of stable catalysts based on MoO3 offers an attractive route for the valorization of oils with high FFAs content.
A High-Throughput Screening Approach to Identify New Active and Long-Term Stable Catalysts for Total Oxidation of Methane from Gas-Fueled Lean–Burn Engines
Authors: Lenk Thomas , Gärtner Adrian , Stöwe Klaus , Schwarz Thomas , Breuer Christian , Kiemel Rainer , Casu Santiago
Published: February 2020

A unique high-throughput approach to identify new catalysts for total oxidation of methane from the exhaust gas of biogas-operated lean-burn engines is presented. The approach consists of three steps: (1) A primary screening using emission-corrected Infrared Thermography (ecIRT). (2) Validation in a conventional plug flow gas phase reactor using a model exhaust gas containing CH4, O2, CO, CO2, NO, NO2, N2O, SO2, H2O. (3) Ageing tests using a simplified exhaust gas (CH4, O2, CO2, SO2, H2O). To demonstrate the efficiency of this approach, one selected dataset with a sol-gel-based catalysts is presented. Compositions are 3 at.% precious metals (Pt, Rh) combined with different amounts of Al, Mn, and Ce in the form of mixed oxides. To find new promising materials for the abatement of methane, about two thousand different compositions were synthesized and ranked using ecIRT, and several hundred were characterized using a plug flow reactor and their ageing behaviour was determined.
The Natural Product Lepidiline A as an N-Heterocyclic Carbene Ligand Precursor in Complexes of the Type [Ir(cod)(NHC)PPh3)]X: Synthesis, Characterisation, and Application in Hydrogen Isotope Exchange Catalysis
Authors: Cochrane Alison R. , Kennedy Alan R. , Kerr William J. , Lindsay David M. , Reid Marc , Tuttle Tell
Published: February 2020

A range of iridium(I) complexes of the type [Ir(cod)(NHC)PPh3)]X are reported, where the N-heterocyclic carbene (NHC) is derived from the naturally-occurring imidaozlium salt, Lepidiline A (1,3-dibenzyl-4,5-dimethylimidazolium chloride). A range of complexes were prepared, with a number of NHC ligands and counter-ions, and various steric and electronic parameters of these complexes were evaluated. The activity of the [Ir(cod)(NHC)PPh3)]X complexes in hydrogen isotope exchange reactions was then studied, and compared to established iridium(I) complexes.
Transfer Hydrogenation from 2-propanol to Acetophenone Catalyzed by [RuCl2(η6-arene)P] (P = monophosphine) and [Rh(PP)2]X (PP = diphosphine, X = Cl−, BF4−) Complexes
Authors: Mannu Alberto , Grabulosa Arnald , Baldino Salvatore
Published: February 2020

The reduction of ketones through homogeneous transfer hydrogenation catalyzed by transition metals is one of the most important routes for obtaining alcohols from carbonyl compounds. The interest of this method increases when opportune catalytic precursors are able to perform the transformation in an asymmetric fashion, generating enantiomerically enriched chiral alcohols. This reaction has been extensively studied in terms of catalysts and variety of substrates. A large amount of information about the possible mechanisms is available nowadays, which has been of high importance for the development of systems with excellent outcomes in terms of conversion, enantioselectivity and Turn Over Frequency. On the other side, many mechanistic aspects are still unclear, especially for those catalytic precursors which have shown only moderate performances in transfer hydeogenation. This is the case of neutral [RuCl2(η6-arene)(P)] and cationic [Rh(PP)2]X (X = anion; P and PP = mono- and bidentate phosphine, respectively) complexes. Herein, a summary of the known information about the Transfer Hydrogenation catalyzed by these complexes is provided with a continuous focus on the more relevant mechanistic features.
RETRACTED: Experimental Study of CO2 Conversion into Methanol by Synthesized Photocatalyst (ZnFe2O4/TiO2) Using Visible Light as an Energy Source
Authors: Manzoor Numair , Sadiq Muhammad , Naqvi Muhammad , Sikandar Umair , Naqvi Salman
Published: February 2020

Ozone layer depletion is a serious threat due to the extensive release of greenhouse gases. The emission of carbon dioxide (CO2) from fossil fuel combustion is a major reason for global warming. Energy demands and climate change are coupled with each other. CO2is a major gas contributing to global warming; hence, the conversion of CO2 into useful products such as methanol, formic acid, formaldehyde, etc., under visible light is an attractive topic. Challenges associated with the current research include synthesizing a photocatalyst that is driven by visible light with a narrow band gap range between 2.5 and 3.0 eV, the separation of a mixed end product, and the two to three times faster recombination rate of an electron–hole pair compared with separation over yield. The purpose of the current research is to convert CO2 into useful fuel i.e., methanol; the current study focuses on the photocatalytic reduction of CO2into a useful product. This research is based on the profound analysis of published work, which allows the selection of appropriate methods and material for this research. In this study, zinc ferrite (ZnFe2O4) is synthesized via the modified sol–gel method and coupled with titanium dioxide (TiO2). Thereafter, the catalyst is characterized by Fourier transform infrared (FTIR), FE-SEM, UV–Vis, and XRD characterization techniques. UV–Vis illustrates that the synthesized catalyst has a low band gap and utilizes a major portion of visible light irradiation. The XRD pattern was confirmed by the formation of the desired catalyst. FE-SEM illustrated that the size of the catalyst ranges from 50 to 500 nm and BET analysis determined the surface area, which was 2.213 and 6.453 m2/g for ZnFe2O4 and ZnFe2O4/TiO2, respectively. The continuous gas flow photoreactor was used to study the activity of the synthesized catalyst, while titanium dioxide (TiO2) has been coupled with zinc ferrite (ZnFe2O4) under visible light in order to obtain the maximum yield of methanol as a single product and simultaneously avoid the conversion of CO2 into multiple products. The performance of ZnFe2O4/TiO2was mainly assessed through methanol yield with a variable amount of TiO2 over ZnFe2O4 (1:1, 1:2, 2:1, 1:3, and 3:1). The synthesized catalyst recycling ability has been tested up to five cycles. Finally, we concluded that the optimum conditions for maximum yield were found to be a calcination temperature of ZnFe2O4at 900 °C, and optimum yield was at a 1:1 w/w coupling ratio of ZnFe2O4/TiO2. It was observed that due to the enhancement in the electron–hole pair lifetime, the methanol yield at 141.22 μmol/gcat·h over ZnFe2O4/TiO2was found to be 7% higher than the earlier reported data.
Advanced Catalytic Materials for Ethanol Oxidation in Direct Ethanol Fuel Cells
Authors: Zheng Yun , Wan Xiaojuan , Cheng Xin , Cheng Kun , Dai Zhengfei , Liu Zhihong
Published: February 2020

Direct ethanol fuel cells (DEFCs) have emerged as promising and advanced power systems that can considerably reduce fossil fuel dependence, and thus have attracted worldwide attention. DEFCs have many apparent merits over the analogous devices fed with hydrogen or methanol. As the key constituents, the catalysts for both cathodes and anodes usually face some problems (such as high cost, low conversion efficiency, and inferior durability) that hinder the commercialization of DEFCs. This review mainly focuses on the most recent advances in nanostructured catalysts for anode materials in DEFCS. First, we summarize the effective strategies used to achieve highly active Pt- and Pd-based catalysts for ethanol electro-oxidation, including composition control, microstructure design, and the optimization of support materials. Second, a few non-precious catalysts based on transition metals (such as Fe, Co, and Ni) are introduced. Finally, we outline the concerns and future development of anode catalysts for DEFCs. This review provides a comprehensive understanding of anode catalysts for ethanol oxidation in DEFCs.
Copper–Zirconia Catalysts: Powerful Multifunctional Catalytic Tools to Approach Sustainable Processes
Authors: Scotti Nicola , Bossola Filippo , Zaccheria Federica , Ravasio Nicoletta
Published: February 2020

Copper–zirconia catalysts find many applications in different reactions owing to their unique surface properties and relatively easy manufacture. The so-called methanol economy, which includes the CO2 and CO valorization and the hydrogen production, and the emerging (bio)alcohol upgrading via dehydrogenative coupling reaction, are two critical fields for a truly sustainable development in which copper–zirconia has a relevant role. In this review, we provide a systematic view on the factors most impacting the catalytic activity and try to clarify some of the discrepancies that can be found in the literature. We will show that contrarily to the large number of studies focusing on the zirconia crystallographic phase, in the last years, it has turned out that the degree of surface hydroxylation and the copper–zirconia interphase are in fact the two mostly determining factors to be controlled to achieve high catalytic performances.
CO2 Hydrogenation to Methanol over La2O3-Promoted CuO/ZnO/Al2O3 Catalysts: A Kinetic and Mechanistic Study
Authors: Kourtelesis Marios , Kousi Kalliopi , Kondarides Dimitris I.
Published: February 2020

The hydrogenation of CO2 to methanol has been investigated over CuO/ZnO/Al2O3 (CZA) catalysts, where a part of the Al2O3 (0, 25, 50, 75, or 100%) was substituted by La2O3. Results of catalytic performance tests obtained at atmospheric pressure showed that the addition of La2O3 generally resulted in a decrease of CO2 conversion and in an increase of methanol selectivity. Optimal results were obtained for the CZA-La50 catalyst, which exhibited a 30% higher yield of methanol, compared to the un-promoted sample. This was attributed to the relatively high specific surface area and porosity of this material, the creation of basic sites of moderate strength, which enhance adsorption of CO2 and intermediates that favor hydrogenation steps, and the ability of the catalyst to maintain a large part of the copper in its metallic form under reaction conditions. The reaction mechanism was studied with the use of in situ infrared spectroscopy (DRIFTS). It was found that the reaction proceeded with the intermediate formation of surface formate and methoxy species and that both methanol and CO were mainly produced via a common formate intermediate species. The kinetic behavior of the best performing CZA-La50 catalyst was investigated in the temperature range 190–230 °C as a function of the partial pressures of H2 (0.3–0.9 atm) and CO2 (0.05–0.20 atm), and a kinetic model was developed, which described the measured reaction rates satisfactorily.
Mimicking the Catalytic Center for the Water-Splitting Reaction in Photosystem II
Authors: Li Yanxi , Yao Ruoqing , Chen Yang , Xu Boran , Chen Changhui , Zhang Chunxi
Published: February 2020

The oxygen-evolving center (OEC) in photosystem II (PSII) of plants, algae and cyanobacteria is a unique natural catalyst that splits water into electrons, protons and dioxygen. The crystallographic studies of PSII have revealed that the OEC is an asymmetric Mn4CaO5-cluster. The understanding of the structure-function relationship of this natural Mn4CaO5-cluster is impeded mainly due to the complexity of the protein environment and lack of a rational chemical model as a reference. Although it has been a great challenge for chemists to synthesize the OEC in the laboratory, significant advances have been achieved recently. Different artificial complexes have been reported, especially a series of artificial Mn4CaO4-clusters that closely mimic both the geometric and electronic structures of the OEC in PSII, which provides a structurally well-defined chemical model to investigate the structure-function relationship of the natural Mn4CaO5-cluster. The deep investigations on this artificial Mn4CaO4-cluster could provide new insights into the mechanism of the water-splitting reaction in natural photosynthesis and may help the development of efficient catalysts for the water-splitting reaction in artificial photosynthesis.
Loading of Primary Human T Lymphocytes with Citrate-Coated Superparamagnetic Iron Oxide Nanoparticles Does Not Impair Their Activation after Polyclonal Stimulation
Authors: Mühlberger Marina , Unterweger Harald , Band Julia , Lehmann Christian , Heger Lukas , Dudziak Diana , Alexiou Christoph , Lee Geoffrey , Janko Christina
Published: February 2020

For the conversion of immunologically cold tumors, characterized by a low T cell infiltration, into hot tumors, it is necessary to enrich T cells in the tumor area. One possibility is the use of magnetic fields to direct T cells into the tumor. For this purpose, primary T cells that were freshly isolated from human whole blood were loaded with citrate-coated superparamagnetic iron oxide nanoparticles (SPIONCitrate). Cell toxicity and particle uptake were investigated by flow cytometry and atomic emission spectroscopy. The optimum loading of the T cells without any major effect on their viability was achieved with a particle concentration of 75 µg Fe/mL and a loading period of 24 h. The cellular content of SPIONCitrate was sufficient to attract these T cells with a magnet which was monitored by live-cell imaging. The functionality of the T cells was only slightly influenced by SPIONCitrate, as demonstrated by in vitro stimulation assays. The proliferation rate as well as the expression of co-stimulatory and inhibitory surface molecules (programmed cell death 1 (PD-1), lymphocyte activation gene 3 (LAG-3), T cell immunoglobulin and mucin domain containing 3 (Tim-3), C-C motif chemokine receptor 7 (CCR7), CD25, CD45RO, CD69) was investigated and found to be unchanged. Our results presented here demonstrate the feasibility of loading primary human T lymphocytes with superparamagnetic iron oxide nanoparticles without influencing their viability and functionality while achieving sufficient magnetizability for magnetically controlled targeting. Thus, the results provide a strong fundament for the transfer to tumor models and ultimately for new immunotherapeutic approaches for cancer treatment.
High End Quality Measuring in Mango Drying through Multi-Spectral Imaging Systems
Authors: Jödicke Katrin , Zirkler Robin , Eckhard Timo , Hofacker Werner , Jödicke Bernd
Published: February 2020

In modern fruit processing technology, non-destructive quality measuring techniques are sought for determining and controlling changes in the optical, structural, and chemical properties of the products. In this context, changes inside the product can be measured during processing. Especially for industrial use, fast, precise, but robust methods are particularly important to obtain high-quality products. In this work, a newly developed multi-spectral imaging system was implemented and adapted for drying processes. Further it was investigated if the system could be used to link changes in the surface spectral reflectance during mango drying with changes in moisture content and contents of chemical components. This was achieved by recovering the spectral reflectance from multi-spectral image data and comparing the spectral changes with changes of the total soluble solids (TSS), pH-value and the relative moisture content xwb of the products. In a first step, the camera was modified to be used in drying, then the changes in the spectra and quality criteria during mango drying were measured. For this, mango slices were dried at air temperatures of 40–80 °C and relative air humidities of 5%–30%. Samples were analyzed and pictures were taken with the multi-spectral imaging system. The quality criteria were then predicted from spectral data. It could be shown that the newly developed multi-spectral imaging system can be used for quality control in fruit drying. There are strong indications as well, that it can be employed for the prediction of chemical quality criteria of mangoes during drying. This way, quality changes can be monitored inline during the process using only one single measuring device.
Surface Functionalization of Cotton and PC Fabrics Using SiO2 and ZnO Nanoparticles for Durable Flame Retardant Properties
Authors: Saleemi Sidra , Naveed Tayab , Riaz Tabinda , Memon Hafeezullah , Awan Javeed Ashraf , Siyal M. Irfan , Xu Fujun , Bae Jihyun
Published: February 2020

In recent years, the use of functional textiles has attained attention due to their advantageous health and safety issues. Therefore, this study investigated the flame retardancy on cotton (COT) and polyester-cotton (PC) fabrics treated with different concentrations of silica and zinc nanoparticles through a sol-gel finishing technique. FTIR, SEM, and TGA were conducted for the characterization of coated fabric samples. The FTIR and SEM of Pristine and Treated Cotton and PC fabrics illustrated that the SiO2 (silica dioxide) and ZnO (Zinc oxide) nanoparticles were homogeneously attached to the fiber surface, which contributed to the enhancement of the thermal stability. The starting thermal degradation improved from 320 to 350 °C and maximum degradation was observed from 400 to 428 °C for the COT-2 cotton substrate. However, the initial thermal degradation improved from 310 to 319 °C and the highest degradation from 500 to 524 °C for the PC substrate PC-2. The outcomes revealed that the silica has a greater influence on the thermal properties of COT and PC fabric samples. Additionally, the tensile strength and flexural rigidity of the treated samples were improved with an insignificant decrease in air permeability.
Effects of Defects and Doping on an Al Atom Adsorbed on Graphene: A First-Principles Investigation
Authors: Dai Xiaoshuang , Shen Tao , Chen Jiaojiao , Liu Hongchen
Published: February 2020

In order to enhance the interaction between an Al atom and graphene in graphene-reinforced aluminum-based composites, the method of first-principles calculation was used to investigate the adsorption behavior of Al atoms on graphene. Our calculations indicate that defective and doped graphene are energetically favored for Al atom adsorption compared with pristine graphene. The adsorption effects show that both defects and doping can improve the stability of the Al–graphene system. Furthermore, it was also found that defects and doping lead to a red-shift of the highest optical absorption peaks. The results of the investigation provide a theoretical basis for the future application of graphene-reinforced aluminum-based composites in optical and optoelectronic devices.
Comparative Study of DC and RF Sputtered MoSe2 Coatings Containing Carbon—An Approach to Optimize Stoichiometry, Microstructure, Crystallinity and Hardness
Authors: Yaqub Talha Bin , Vuchkov Todor , Sanguino Pedro , Polcar Tomas , Cavaleiro Albano
Published: February 2020

Low stoichiometry, low crystallinity, low hardness and incongruencies involving the reported microstructure have limited the applicability of TMD-C (Transition metal dichalcogenides with carbon) solid-lubricant coatings. In this work, optimized Mo–Se–C coatings were deposited using confocal plasma magnetron sputtering to overcome the above-mentioned issues. Two different approaches were used; MoSe2 target powered by DC (direct current) or RF (radio frequency) magnetron sputtering. Carbon was always added by DC magnetron sputtering. Wavelength dispersive spectroscopy displayed Se/Mo stoichiometry of ~2, values higher than the literature. The Se/Mo ratio for RF-deposited coatings was lower than for their DC counterparts. Scanning electron microscopy showed that irrespective of the low carbon additions, the Mo–Se–C coatings were highly compact with no vestiges of columnar growth due to optimal bombardment of sputtered species. Application of substrate bias further improved compactness at the expense of lower Se/Mo ratio. X-ray diffraction, transmission electron microscopy, and Raman spectroscopy confirmed the presence of MoSe2 crystals, and (002) basal planes. Even very low carbon additions led to an improvement of the hardness of the coatings. The work reports a comparison between RF and DC sputtering of MoSe2 coatings with carbon and provides a guideline to optimize the composition, morphology, structure, and mechanical properties.
ITO/SiO2/ITO Structure on a Sapphire Substrate Using the Oxidation of Ultra-Thin Si Films as an Insulating Layer for One-Glass-Solution Capacitive Touch-Screen Panels
Authors: Joo Shin Yong , Loka Chadrasekhar , Jo Young Woong , Reddyprakash Maddipatla , Moon Sung Whan , Choi YiSik , Lee Seong Eui , Cho Gue Serb , Lee Kee-Sun
Published: February 2020

The SiO2 generated by low-temperature oxidation of ultra-thin metallic silicon (thickness = 50 nm) film was evaluated for implementation in one-glass-solution capacitive touch-screen panels (OGS-TSPs) on sapphire-based substrates. Our results show that the silicon films oxidized at 823 K exhibited the highest visible transmittance about 91% at 550 nm, compared to ~72% transmittance of the as-deposited silicon films which were deposited at room temperature. Additionally, the annealed films exhibited a more uniform, dense, and smooth surface microstructure than that of the as-deposited Si films. X-ray photoelectron spectroscopy (XPS) results revealed that the low-temperature oxidation of Si films at 823 K yielded SiO2. Furthermore, when the insulating SiO2 film obtained by low-temperature oxidation was sandwiched between two indium tin oxide (ITO) layers (ITO/SiO2/ITO) on a sapphire substrate, the SiO2 film resulted in the dielectric strength of approximately 3 MV/cm. In addition, the highest optical transmittance obtained by the ITO/SiO2/ITO films is about 88.3%. The change in capacitance of the ITO/SiO2/ITO structure was approximately 3.2 pF, which indicates the possibility of implementation in capacitive touch-screen panel devices.
Interaction and Polarization Energy Relationships in σ-Hole and π-Hole Bonding
Authors: Murray Jane S. , Politzer Peter
Published: February 2020

We demonstrate that a wide range of σ- and π-hole interaction energies can be related to (a) the electrostatic potentials and electric fields of the σ- and π-hole molecules at the approximate positions of the negative sites and (b) the electrostatic potentials and polarizabilities of the latter. This is consistent with the Coulombic nature of these interactions, which should be understood to include both electrostatics and polarization. The energies associated with polarization were estimated and were shown to overall be greater for the stronger interactions; no new factors need be introduced to account for these. All of the interactions can be treated in the same manner.