bluuebunny/crossref_metadata_2025 huggingface dataset:
Arthropods Associated with Invasive Frangula alnus (Rosales: Rhamnaceae): Implications for Invasive Plant and Insect Management
Authors: Greenleaf Jennifer , Holásková Ida , Rowen Elizabeth , Gutensohn Michael , Turcotte Richard , Park Yong-Lak
Published: November 2023

The invasive shrub glossy buckthorn (Frangula alnus) has been progressively colonizing the Northeastern United States and Southeastern Canada for more than a century. To determine the dominant arthropod orders and species associated with F. alnus, field surveys were conducted for two years across 16 plots within the Allegheny National Forest, Pennsylvania, USA. Statistical analyses were employed to assess the impact of seasonal variation on insect order richness and diversity. The comprehensive arthropod collection yielded 2845 insects and arachnids, with hemipterans comprising the majority (39.8%), followed by dipterans (22.3%) and arachnids (15.5%). Notably, 16.2% of the hemipterans collected were in the immature stages, indicating F. alnus as a host for development. The two dominant insect species of F. alnus were Psylla carpinicola (Hemiptera: Psyllidae) and Drosophila suzukii (Diptera: Drosophilidae); D. suzukii utilized F. alnus fruits for reproduction. Species richness and diversity exhibited significant variations depending on the phenology of F. alnus. The profiles of volatile compounds emitted from the leaves and flowers of F. alnus were analyzed to identify factors that potentially contribute to the attraction of herbivores and pollinators. The results of our study will advance the development of novel F. alnus management strategies leveraging the insects associated with this invasive species.
Aerosolized Insecticide Spray Distributions and Relationships to Efficacy against Stored Product Pests
Authors: Brabec Daniel , Lanka Srinivas , Campbell James F. , Arthur Frank H. , Scheff Deanna S. , Yan-Zhu Kun
Published: November 2023

Aerosol insecticides are widely used in stored product insect management programs in food facilities. Previous research has shown spatial variation in aerosol efficacy within facilities, but information on how spatial patterns of aerosol droplet concentration, size distribution, dispersal, and deposition contribute to this variation in efficacy is limited. This study involved two aerosol application systems: a high-pressure cylinder containing TurboCide Py-75® with pyriproxyfen IGR (ChemTech Ltd., Des Moines, IA, USA) and a hand-held fogger containing Pyrocide 100® (MGK, Minneapolis, MN, USA) with Diacon II which contains methoprene IGR (Wellmark, Schaumburg, IL, USA). These systems were used at single or multiple application locations. The spray trials were conducted in a small-scale flour mill, Hall Ross Flour Mill (Kansas State University, Manhattan, KS, USA). The droplet size distributions were monitored at multiple positions within the room using nine aerodynamic particle sizing (APS, TSI Incorp, Shoreview, MN, USA) instruments. The APS data collected over the treatment period were summarized into a mass concentration index (MCI), which ranged from 155 to 2549 mg/m3 for Turbocide and 235–5658 mg/m3 for Pyrocide. A second parameter called the Deposition Index (Dep.Idx) was derived to estimate potential insecticide depositions on the floor and has units of g/m2. The Dep.Idx was below 5.3 g/m2 for most Turbocide applications, while the Dep.Idx was below 8.4 g/m2 for most Pyrocide applications. The MCI and Dep.Idx values varied with APS position and spray application location, with proximity to the aerosol application location and degree of obstruction between the release point and APS position contributing to this variation. We assessed the relationship between aerosol droplet parameters and insect efficacy using Tribolium confusum Jacqueline DuVal, the confused flour beetle. The adults were treated directly, while the larvae were treated two weeks later during the residual test (previously published). For Turbocide, efficacy against adults increased with MCI and Dep.Idx values, but for residual efficacy of the IGR, efficacy was high at all aerosol droplet values, so no relationship was apparent. In contrast, the relationship between Pyrocide deposition and adult insect efficacy was highly variable. But with larval insect efficacy, residual larvae control was directly related to increases in Pyrocide MCI and Dep.Idx. Contour plots of Dep.Idx values were developed, which could be used to predict areas of the mill that are not receiving an adequate application rate, and this could be used to develop more effective application strategies for aerosol insecticides in food facilities.
Modeling Field Electron Emission from a Flat Au (100) Surface with Density-Functional Theory
Authors: Li Yiming , Mann Joshua , Rosenzweig James
Published: November 2023

Field electron emission, or electron tunneling through a potential energy (PE) barrier under the influence of a strong electrostatic (ES) or radio frequency (RF) field, is of broad interest to the accelerator physics community. For example, it is the source of undesirable dark currents in resonant cavities, providing a limit to high-field operation. Field electron emission can also be applied to quasi-statically model electron emission induced by the electric field in a laser pulse. The classical approach to field electron emission is the Fowler–Nordheim (FN) framework, which incorporates a simplified PE profile and various assumptions. Here, we build a more realistic model using the PE and charge densities derived from a density-functional theory (DFT) calculation. We examine the correction factors associated with each model assumption. Compared to the FN framework, our results can be extended up to 80 GV/m, a limit that has been reached in laser-induced strong field emission scenarios.
Editorial for the Special Issue on Sustainable Composite Construction Materials
Authors: Roy Krishanu , Gurupatham Beulah Gnana Ananthi
Published: November 2023

Sustainable composite construction materials play a crucial role in creating more environmental friendly and energy-efficient buildings [...]
How Do 3D Printing Parameters Affect the Dielectric and Mechanical Performance of Polylactic Acid–Cellulose Acetate Polymer Blends?
Authors: Lecoublet Morgan , Ragoubi Mohamed , Kenfack Leonel Billy , Leblanc Nathalie , Koubaa Ahmed
Published: November 2023

Three-dimensional printing is a prototyping technique that is widely used in various fields, such as the electrical sector, to produce specific dielectric objects. Our study explores the mechanical and dielectric behavior of polylactic acid (PLA) and plasticized cellulose acetate (CA) blends manufactured via Fused Filament Fabrication (FFF). A preliminary optimization of 3D printing parameters showed that a print speed of 30 mm·s−1 and a print temperature of 215 °C provided the best compromise between print quality and processing time. The dielectric properties were very sensitive to the three main parameters (CA content WCA, infill ratio, and layer thickness). A Taguchi L9 3^3 experimental design revealed that the infill ratio and WCA were the main parameters influencing dielectric properties. Increasing the infill ratio and WCA increased the dielectric constant ε′ and electrical conductivity σAC. It would, therefore, be possible to promote the integration of CA in the dielectric domain through 3D printing while counterbalancing its greater polarity by reducing the infill ratio. The dielectric findings are promising for an electrical insulation application. Furthermore, the mechanical findings obtained through dynamic mechanical analysis are discussed.
Parental Understanding of Their Child’s Germline Genomic Testing: Intent of Disclosure to Their Child and Family
Authors: Mandrell Belinda N. , Blake Alise K. , Sharp Katianne M. Howard , Gattuso Jami S. , McGee Rose B. , Harrison Lynn , Ouma Annastasia , Caples Mary , Johnson Liza-Marie , Nichols Kim E.
Published: November 2023

Genomic testing is becoming increasingly common in the care of pediatric patients with cancer. Parental understanding of germline results and their intent and timing of results disclosure to their child and family may have significant implications on the family unit. The purpose of this study was to examine parental understanding of germline genomic results and plans for disclosure to their child and other relatives. Semi-structured interviews were conducted with 64 parents of children with cancer, approximately eight weeks after parents had received their child’s results. Parents of children with negative results (n = 20), positive results (n = 15), or variants of uncertain significance (n = 29), were interviewed. Fifty-three parents (83%) correctly identified their child’s results as negative, uncertain, or positive. Most parents had disclosed results to family members; however, only 11 parents (17%) acknowledged discussing results with their child. Most parents delayed disclosure due to the young age of their child at the time of testing. In summary, most parents appropriately described their child’s germline genomic results, yet few discussed the results with their child due to age. Families should be followed with supportive counseling to assist parents in the timing and content of result disclosure to their children.
Perioperative Hypotension in Patients Undergoing Orthopedic Upper Extremity Surgery with Dexmedetomidine Sedation: A Retrospective Study
Authors: Baek Sujin , Lee Jiyong , Shin Yong Sup , Jo Yumin , Park Juyeon , Shin Myungjong , Oh Chahyun , Hong Boohwi
Published: November 2023

(1) Background: limited data exist regarding the occurrence of hypotension associated with dexmedetomidine use and its risk factors in the context of intraoperative sedation for patients receiving peripheral nerve blocks. (2) Method: This single-center retrospective study assessed the incidence of hypotension in patients undergoing orthopedic upper extremity surgery with brachial plexus blockade. Patients were classified into three groups: group N (non-sedated), group M (midazolam), and group D (dexmedetomidine), based on their primary intraoperative sedative use. The primary outcome was the incidence of perioperative hypotension, defined as systolic blood pressure (SBP) < 90 mmHg or mean blood pressure (MBP) < 60 mmHg, at a minimum of two recorded time points during the intraoperative period and post-anesthesia care unit stay. Multivariable logistic models for the occurrence of hypotension were constructed for the entire cohort and group D. (3) Results: A total of 2152 cases (group N = 445, group M = 678, group D = 1029) were included in the analysis. The odds ratio for the occurrence of hypotension in group D was 5.68 (95% CI, 2.86 to 11.28) compared with group N. Concurrent use of a beta blocker, longer duration of surgery, and lower preoperative SBP and higher preoperative heart rate were identified as significant risk factors. (4) Conclusions: the increased risk of hypotension and the associated factors should be taken into account before using dexmedetomidine in these cases.
Resolved Proteinuria May Attenuate the Risk of Heart Failure: A Nationwide Population-Based Cohort Study
Authors: Chang Yoonkyung , Kang Min Kyoung , Park Moo-Seok , Leem Gwang-Hyun , Song Tae-Jin
Published: November 2023

Although proteinuria is a risk factor for heart failure (HF), proteinuria can be reversible or persistent. Our objective was to explore the link between changes in the proteinuria status and the risk of HF. We included participants from a Korean national health screening cohort who underwent health examinations in 2003–2004 and 2005–2006 and had no history of HF. Participants were categorized into four groups: proteinuria-free, proteinuria-resolved, proteinuria-developed, and proteinuria-persistent. The outcome of interest was the occurrence of HF. The study included 1,703,651 participants, among whom 17,543 (1.03%) were in the proteinuria-resolved group and 4585 (0.27%) were in the proteinuria-persistent group. After a median follow-up period of 14.04 years (interquartile range 14.19–15.07), HF occurred in 75,064 (4.41%) participants. A multivariable Cox proportional hazards regression analysis indicated that the proteinuria-persistent group had a higher risk of HF compared with the proteinuria-free group (hazard ratio (HR): 2.19, 95% confidence interval (CI): 2.03–2.36, p < 0.001). In a further pairwise comparison analysis, participants in the proteinuria-resolved group had a relatively low risk of HF compared with those in the proteinuria-persistent group (HR: 0.64, 95% CI: 0.58–0.70, p < 0.001). In conclusion, the risk of HF can change with alterations in the proteinuria status.
Minimizing Deformations during HP MJF 3D Printing
Authors: Ráž Karel , Chval Zdeněk , Thomann Sacha
Published: November 2023

(1) Background: The purpose of this study was to investigate deformations that occur during additive manufacturing by the HP (Hewlett-Packard) Multi Jet Fusion (MJF) process. These deformations affect the final properties of 3D-printed parts, and proper compensating technology has to be developed in order to minimize these deformations. (2) Methods: Parts were printed with powder composed of nylon plastic infused with glass beads (PA12GB). The HP MJF technology was used during investigations. All parts (specimens) were measured at different points over an extended period to follow the deformations at each point. Different finite element simulations were performed to compare them with real results and assess the viability of using simulations to save time. Various modules of the Digimat software, such as additive manufacturing (AM), material focused (MF), finite element (FE), and computer-aided engineering (CAE), were used to run the simulations. (3) Results: It was found that the printing position of the part in the printer had an impact on deformations. When the part was simulated in a tilted position but alone (deformation: 7.19 mm), the value of the deformation was 1.49 mm greater than when the other parts (two comparable parts) were simulated at the same time (deformation: 5.7 mm). The difference between the simulation with the three parts together (deformation: 5.7 mm) and reality (deformation: 3.44 mm) was 2.26 mm. Finally, the difference between the simulated single part (deformation: 7.19 mm) and the real part (deformation: 3.44) was 3.75 mm. (4) Conclusions: The results of this study will contribute to a better understanding of deformation mechanisms and will suggest solutions for improving the quality of printed parts. Three-dimensional printing is a rapidly growing technology that offers numerous possibilities across various fields. However, one commonly encountered issue is the deformation of printed parts. Methods for minimizing deformations were studied during the 3D printing process using HP MJF technology. Various factors contributing to deformation were investigated, and different techniques for reducing them were explored.
Investigation of Different Features for Baseline-Free RAPID Damage-Imaging Algorithm Using Guided Waves Applied to Metallic and Composite Plates
Authors: Asokkumar Aadhik , Raišutis Renaldas , Pasadas Dario J. , Samaitis Vykintas , Mažeika Liudas
Published: November 2023

In guided-wave-based damage-imaging algorithms, damage reconstruction typically involves comparing the signals with and without a defect. However, in many cases, defect-free data may not be available. Therefore, in this study, baseline and baseline-free approaches were used for damage imaging, exploiting not only the amplitude of the signal as the feature but also five additional features, namely, the amplitude of the sparse signal after deconvolution, the amplitude of the coefficients at the excitation frequency from the re-assigned short-time Fourier transform, the time of flight determined from cross-correlation, kurtosis in the time domain, and kurtosis in the frequency domain. For this study, three different plates with different types of defects were considered: a metallic plate with a notch-type artificial defect, a pultruded type of composite plate with an impact defect, and a laminate composite plate with plexiglass serving as an added mass damper artificial defect. The Reconstruction Algorithm for Probabilistic Inspection of Damage (the RAPID algorithm) was used to characterize the defects on the three plates, and the defect parameters were then quantified by creating an ellipse after thresholding.
Autonomous Self-Healing Methods as a Potential Technique for the Improvement of Concrete’s Durability
Authors: Gojević Anita , Netinger Grubeša Ivanka , Marković Berislav , Juradin Sandra , Crnoja Anđelko
Published: November 2023

The causes of cracks in concrete are varied, and regardless of their origin, these cracks invariably have a detrimental impact on the durability of concrete structures and escalate their maintenance costs. This paper presents a comprehensive review of current knowledge regarding the methods of self-healing in concrete, ranging from autogenic and improved autogenic self-healing to the autonomous self-healing of concrete. Particular emphasis is placed on the methods of autonomous concrete self-healing: the bacterial healing method, the crystalline hydrophilic additives healing method, and the capsule-based self-healing method. The hypothesis is that applying these self-healing methods could potentially prevent damages or cracks in concrete caused by freeze–thaw cycles, thereby extending the lifespan of concrete structures. The mechanism of action and current achievements in the field are provided for each method.
Exploring Microstructure, Wear Resistance, and Electrochemical Properties of AlSi10Mg Alloy Fabricated Using Spark Plasma Sintering
Authors: Rong Guangfei , Xin Wenjie , Zhou Minxu , Ma Tengfei , Wang Xiaohong , Jiang Xiaoying
Published: November 2023

Al-Si-Mg alloy has excellent casting performance due to its high silicon content, but the coarse eutectic silicon phase can lead to a decrease in its mechanical properties. Samples of AlSi10Mg alloy were prepared by using a spark plasma sintering method, and it was found that sintering temperature has a significant impact on the grain size, eutectic silicon size and wear and corrosion properties after heat treatment. At a sintering temperature of 525 °C, the alloy exhibits the best wear performance with an average friction coefficient of 0.29. This is attributed to the uniform precipitation of fine eutectic silicon phases, significantly improving wear resistance and establishing adhesive wear as the wear mechanism of AlSi10Mg alloy at room temperature. The electrochemical performance of AlSi10Mg sintered at 500 °C is the best, with Icorr and Ecorr being 1.33 × 10−6 A·cm−2 and −0.57 V, respectively. This is attributed to the refinement of grain size and eutectic silicon size, as well as the appropriate Si volume fraction. Therefore, optimizing the sintering temperature can effectively improve the performance of AlSi10Mg alloy.
Antibiofilm Property and Biocompatibility of Siloxane-Based Polymer Coatings Applied to Biomaterials
Authors: Ogawa Akiko , Tahori Akane , Yano Mayumi , Hirobe Shunma , Terada Satoshi , Kanematsu Hideyuki
Published: November 2023

Biofilm infections sometimes occur on biomaterials inserted into the body because biomaterials can block the attack of immune cells such as macrophages, promoting biofilm formation by invading bacteria. Owing to their use in antifouling applications, including biofilm formation, siloxane-based polymer coatings are considered a promising method to prevent biofilm formation on the surface of biomaterials. In this study, we explored the antibiofilm property and biocompatibility of siloxane-based polymer coatings. Biofilm formation and cytotoxicity tests were performed using Escherichia coli and Staphylococcus epidermidis to quantify the biofilms while U937 cells were used to measure the time course of viable cell concentration and viability, respectively. In both the biofilm formation and cytotoxicity tests, stainless steel SUS316L plates and titanium plates coated with the siloxane-based polymer and sterilized in an autoclave were used as the biomaterials. The amount of biofilm formed on the polymer-coated titanium plate was substantially higher than that on a noncoated titanium plate in the case of S. epidermidis. The viable cell concentration and viability of U937 cultured on the polymer-coated titanium plate were lower than those of U937 cultured on the noncoated titanium plate. The same trend was observed between polymer-coated and noncoated SUS316L plates. These results indicate that the siloxane-based polymer coatings need additional treatment to achieve a satisfactory antibiofilm property and that they are sensitive to autoclave treatment, resulting in cytotoxicity.
Shaping the Structure and Properties of TiO2-ZnO Oxide Coatings Produced by Plasma Electrolytic Oxidation on Titanium Substrate
Authors: Marny Magdalena , Sowa Maciej , Kazek-Kęsik Alicja , Rokosz Krzysztof , Raaen Steinar , Chapon Patrick , Viter Roman , Pshenychnyi Roman , Simka Wojciech , Michalska Joanna
Published: November 2023

The paper presents the results of preliminary research on the possibility of synthesizing ZnO-TiO2 mixed coatings by plasma electrochemical oxidation (PEO). The aim of the work was to synthesize TiO2-ZnO mixed coatings on a titanium substrate from an electrolyte containing ZnO nanoparticles (NPs) and to assess the parameters of PEO on the structure, chemical composition, and properties of the obtained oxide coatings. The PEO process was carried out under various current–voltage conditions using different signals: DC, DC pulse, and AC. In this work, optimal conditions for the PEO process were determined to obtain well-adhering oxide coatings with the highest possible content of ZnO. The structure and morphology of the resulting oxide coatings were investigated, and their chemical and phase composition was comprehensively examined (EDX, XRD, XPS, and GD-OES). In addition, their basic optical properties were assessed. It has been shown that in the PEO DC pulse process, it is possible to obtain oxide coatings characterized by a high degree of structure order, high ZnO content in the oxide coating (3.6 at.%, XPS), and prospective applications for photocatalytic purposes (3.12 eV).
Effect of ZrC on the Microstructure and Properties of CrMnFeCoNi High-Entropy Alloy Coatings Prepared by a Plasma Transferred Arc Process
Authors: Huang Long , Li Bingyuan , Xu Bopin , Zhou Yicheng , Li Mengzhao , Li Chenglin , Yang Bing , Pan Chunxu , Zhang Guodong
Published: November 2023

The low strength caused by the single FCC structure of the CrMnFeCoNi high entropy alloy (HEA) limits its application in the field of coating. Here, we prepared high-entropy alloy coatings of CrMnFeCoNi with different ZrC contents on Q235 steel by a plasma transferred arc process. The effects of ZrC on the microstructure and properties of the CrMnFeCoNi HEA coating were investigated by optical microscopy, scanning electron microscope, and X-ray diffraction and by employing a potensiostat/galvanostat. The results showed that ZrC mainly existed in the coatings as a second phase, having little influence on the main crystal structure and micromorphology of the CrMnFeCoNi HEA coating. The hardness of the CrMnFeCoNi HEA coating increased with the ZrC content. ZrC can effectively improve the corrosion resistance of the CrMnFeCoNi HEA coating. In a 1 mol/L NaCl solution with 4 wt% ZrC, the annual corrosion rate was only 5.997% of that of the HEA coating. Nevertheless, the improvement in the wear resistance of CrMnFeCoNi high-entropy alloy coatings was not apparent with the addition of ZrC. Consequently, the addition of ZrC to the FeCoCrNiMn high-entropy alloy coating holds promise for applications in corrosion resistance, particularly in oceanic environments.
Mechanical and Electromagnetic Wave Absorption Performance of Carbonyl Iron Powder-Modified Nonwoven Materials
Authors: Gu Wenyan , Shi Jiang , Pang Tianwen , Sun Qilong , Jia Qi , Hu Jiajia , Zhang Jiaqiao
Published: November 2023

In order to develop carbonyl iron-enhanced electromagnetic wave-absorbing composites, this paper utilizes two different morphologies of carbonyl iron powder (CIP), spherical and flake-like, which are blended with aqueous polyurethane (PU) in three different ratios to prepare impregnating solutions. Polyester (PET) needle-punched nonwoven materials are impregnated with these solutions to produce electromagnetic wave-absorbing composites. First, electromagnetic parameters of the two CIP particle types, spherical carbonyl iron (SCIP) and flake-like carbonyl iron (FCIP), are tested with the coaxial method, followed by calculation of the results of their electromagnetic wave absorption performance. Next, the composites are subjected to microscopic morphology observation, tensile testing, and arched frame method electromagnetic wave absorption performance testing. The results indicate that the microwave absorption performance of FCIP is significantly better than that of SCIP. The minimum reflection loss value for F3, a kind of FCIP-modified nonwoven fabric, at the thickness of 1 mm, at 18 GHz is −17 dB. This value is even better than the calculated RL value of CIP at the thickness of 1 mm. The anisotropic shape of flake-like magnetic materials is further strengthened when adhering to the surface of PET fiber material. Additionally, the modified composites with carbonyl iron exhibit higher tensile strength compared with pure PET. The addition of fibrous skeletal materials is expected to enhance the impedance matching of flake-like magnetic particles, forming a wearable and microwave-absorbing composite.
XPS Investigation of the Oxidation States of the As-Deposited Ta Films Prepared by Magnetron Sputtering Technology
Authors: Hu Ming , Li Zhaowang , Gao Xiaoming , Jiang Dong , Liu Zhilu , Guo Longbang , Zhao Xu , He Jun , Sun Jiayi , Weng Lijun , Wang Desheng
Published: November 2023

Due to their versatile and unique properties, tantalum-based thin films have been extensively studied. However, tantalum is susceptible to oxidation due to its higher chemical activity, which is crucial regardless of whether oxidations of Ta are beneficial or detrimental. Therefore, the oxidation of Ta during material processing, especially without conscious means, should be taken seriously. In this study, pure Ta films were fabricated by magnetron sputtering under set procedure parameters. The effects of base pressure and substrate temperature on the degree of oxidation of Ta films were investigated. The results revealed that the magnitude of the base pressure directly affects the oxidation state of the as-deposited Ta films. When preferably avoiding the oxidation of sputtered Ta films, the base pressure should be controlled below 4.4 × 10−4 Pa. The substrate temperature has little effect on the oxidation state of the as-deposited Ta films under a base pressure ranging from about 10−2 Pa to 10−4. We hope that this study can provide some references for controlling the oxidation states of Ta involved in relevant film preparation.
Development of Maximum Residual Stress Prediction Technique for Shot-Peened Specimen Using Rayleigh Wave Dispersion Data Based on Convolutional Neural Network
Authors: Choi Yeong-Won , Lee Taek-Gyu , Yeom Yun-Taek , Kwon Sung-Duk , Kim Hun-Hee , Lee Kee-Young , Kim Hak-Joon , Song Sung-Jin
Published: November 2023

Shot peening is a surface treatment process that improves the fatigue life of a material and suppresses cracks by generating residual stress on the surface. The injected small shots create a compressive residual stress layer on the material’s surface. Maximum compressive residual stress occurs at a certain depth, and tensile residual stress gradually occurs as the depth increases. This process is primarily used for nickel-based superalloy steel materials in certain environments, such as the aerospace industry and nuclear power fields. To prevent such a severe accident due to the high-temperature and high-pressure environment, evaluating the residual stress of shot-peened materials is essential in evaluating the soundness of the material. Representative methods for evaluating residual stress include perforation strain gauge analysis, X-ray diffraction (XRD), and ultrasonic testing. Among them, ultrasonic testing is a representative, non-destructive evaluation method, and residual stress can be estimated using a Rayleigh wave. Therefore, in this study, the maximum compressive residual stress value of the peened Inconel 718 specimen was predicted using a prediction convolutional neural network (CNN) based on the relationship between Rayleigh wave dispersion and stress distribution on the specimen. By analyzing the residual stress distribution in the depth direction generated in the model from various studies in the literature, 173 residual stress distributions were generated using the Gaussian function and factorial design approach. The distribution generated using the relationship was converted into 173 Rayleigh wave dispersion data to be used as a database for the CNN model. The CNN model was learned through this database, and performance was verified using validation data. The adopted Rayleigh wave dispersion and convolutional neural network procedures demonstrate the ability to predict the maximum compressive residual stress in the peened specimen.
Effect of Si Content on Microstructures and Electrochemical Properties of Al-xSi-3.5Fe Coating Alloy
Authors: Wu Yufeng , Shen Ying , Wang Qi , Liu Yuhang , Shi Dongming , Liu Ya , Su Xuping
Published: November 2023

Hot-dip aluminum alloy is widely used in the engineering fields. However, during the aluminum plating process, Fe inevitably enters and reaches a saturation state, which has a significant impact on the corrosion resistance and microstructure of the coating. Currently, adding Si during the hot-dip aluminum process can effectively improve the quality of the coating and inhibit the Fe-Al reaction. To understand the effect of Si content on the microstructure and electrochemical performance of Al-xSi-3.5Fe coating alloys, the microstructure and post-corrosion morphology of the alloys were analyzed using SEM (Scanning Electron Microscope) and XRD (X-ray Diffraction). Through electrochemical tests and complete immersion corrosion experiments, the corrosion resistance of the coating alloys in 3.5 wt.% NaCl was tested and analyzed. The results show that the Al-3.5Fe coating alloy mainly comprises α-Al, Al3Fe, and Al6Fe. With the increase in Si addition, the iron-rich phase changes from Al3Fe and Al6Fe to Al8Fe2Si. When the Si content reaches 4 wt.%, the iron-rich phase is Al9Fe2Si2, and the excess Si forms the eutectic Si phase with the aluminum matrix. Through SKPFM (Scanning Kelvin Probe Force Microscopy) testing, it was determined that the electrode potentials of the alloy phases Al3Fe, Al6Fe, Al8Fe2Si, Al9Fe2Si2, and eutectic Si phase were higher than that of α-Al, acting as cathode phases to the micro-galvanic cell with the aluminum matrix, and the corrosion form of alloys was mainly galvanic corrosion. With the addition of silicon, the electrode potential of the alloy increased first and then decreased, and the corrosion resistance results were synchronous with it. When the Si content is 10 wt.%, the alloy has the lowest electrode potential and the highest electrochemical activity.
Application of Metal-Based Catalysts for Semi-Hydrogenation of Alkynol: A Review
Authors: Wang Pengxian , Ma Yue , Shi Yiran , Duan Fangying , Wang Meng
Published: November 2023

Alkynol semi-hydrogenation plays a vital role in industrial processes, due to the significance of its main product, enol, in high-end chemical synthesis, such as medicine, pesticide, food additives, and polymer monomer synthesis. Multiple intermediates are formed through a complex series of parallel or continuous reactions under varying conditions. However, the selectivity and efficiency of catalysts for producing these products still pose significant challenges. This review aims to thoroughly discuss the challenges and advancements in catalysts using different species and supports under various reaction conditions. Furthermore, strategies to enhance the yield and rate of enols are summarized based on noble metals, non-noble metals, and metal comparisons. By addressing diverse catalysts and reaction conditions, this review provides valuable insights into improving the semi-hydrogenation of acetylenic alcohols to enols.
Android Malware Classification Based on Fuzzy Hashing Visualization
Authors: Rodriguez-Bazan Horacio , Sidorov Grigori , Escamilla-Ambrosio Ponciano Jorge
Published: November 2023

The proliferation of Android-based devices has brought about an unprecedented surge in mobile application usage, making the Android ecosystem a prime target for cybercriminals. In this paper, a new method for Android malware classification is proposed. The method implements a convolutional neural network for malware classification using images. The research presents a novel approach to transforming the Android Application Package (APK) into a grayscale image. The image creation utilizes natural language processing techniques for text cleaning, extraction, and fuzzy hashing to represent the decompiled code from the APK in a set of hashes after preprocessing, where the image is composed of n fuzzy hashes that represent an APK. The method was tested on an Android malware dataset with 15,493 samples of five malware types. The proposed method showed an increase in accuracy compared to others in the literature, achieving up to 98.24% in the classification task.
Obesity Is Associated with a Weakened Gingival Inflammatory Cytokine Response
Authors: Khocht Ahmed , Bellinger Denise , Lenoir Leticia , Irani Crissy , Fraser Gary
Published: November 2023

Background and Objectives: An obesity-related elevated body mass index (BMI) across life is associated with chronic low-grade inflammation and increased levels of C-reactive protein (CRP) in blood. CRP is a marker and promoter of inflammation. The objectives of this study were to examine the effect of obesity on the relationship between peripheral and gingival CRP levels and to examine the effects of gingival CRP levels on gingival fluid inflammatory cytokines in periodontitis-resistant obese individuals. Materials and Methods: Thirty-nine participants in good periodontal health were recruited. Twenty patients were classified as lean and nineteen as obese based on their BMI levels. A thorough periodontal assessment was carried out. Gingival crevicular fluid (GCF) and blood samples were collected. Both GCF and blood samples were analyzed for interleukin-1β (IL-1β), interleukin-6 (IL-6), interleukin-8 (IL-8), tumor necrosis factor-α (TNF-α), interleukin-10 (IL-10), interleukin-17A (IL-17A), and CRP. Results: GCF CRP levels were significantly higher in the obese than in the lean individuals. No statistically significant differences were noted between the two groups in either GCF or blood in terms of any of the inflammatory cytokine levels. IL-17A was not detected in the GCF of most subjects in both groups. GCF CRP levels were positively associated with blood CRP levels, and the association tended to be stronger in the obese individuals. GCF CRP showed no associations with GCF IL-10 in both groups. Although GCF CRP levels were positively associated with multiple GCF inflammatory cytokines (e.g., IL-1β, IL-6, IL-8, and TNF-α) in all subjects, the associations tended to be weaker in the obese individuals (e.g., IL-1β, IL-6, and TNF-α). Furthermore, the levels of the GCF inflammatory cytokines IL-6 and TNF-α were decreased in the obese individuals. Conclusions: Obesity unfavorably influences the relationship between blood and GCF CRP levels and promotes increased CRP levels in GCF. Collectively, the findings suggest a weakened inflammatory cytokine response in the gingival tissues of obese individuals.
Fabrication of Silver Iodide (AgI) Patterns via Photolithography and Its Application to In-Situ Observation of Condensation Frosting
Authors: Okabe Takao , Tang Jinchen , Nishimura Katsuhiko , Shikazono Naoki
Published: November 2023

This study introduces an innovative photolithography-based method for patterning ionic and inorganic particle materials such as silver iodide (AgI). Conventional methods lack precision when patterning powdered materials, which limits their applicability. The proposed method stacks layers of a particle material (AgI) and negative-tone photoresist for simultaneous ultraviolet exposure and development, resulting in well-defined AgI patterns. The sintering process successfully removed binders from the material layer and photoresist, yielding standalone AgI patterns on the Si substrate with good adhesion. The pitch remained consistent with the design values of the photomask when the pattern size was changed. In-situ observation of condensation frosting on the patterns was conducted, which confirmed the practicality of the developed patterning process. This versatile method is applicable to large areas with a high throughput and presents new opportunities for modifying functional surfaces.
Characterization of Root and Foliar-Applied Iron Oxide Nanoparticles (α-Fe2O3, γ-Fe2O3, Fe3O4, and Bulk Fe3O4) in Improving Maize (Zea mays L.) Performance
Authors: Yousaf Nauman , Ishfaq Muhammad , Qureshi Hassan Ali , Saleem Atif , Yang Haofeng , Sardar Muhammad Fahad , Zou Chunqin
Published: November 2023

Iron (Fe) oxide nanoparticles (NPs) improve crop growth. However, the comparative effect of root and foliar-applied different sources of Fe oxide NPs on plant performance at morphological and physiological levels still needs to be discovered. In this study, we characterized the growth and physiological responses of hydroponic-cultured maize seedlings to four sources of Fe (i.e., α-Fe2O3, γ-Fe2O3, Fe3O4 NPs, and bulk Fe3O4) and two application methods (root vs. foliar). Results showed that Fe concentration in root and shoot increased by elevating the level of NPs from 100 mg L−1 to 500 mg L−1. Overall, the responses of maize seedlings to different sources of Fe oxide NPs were as follows: Fe3O4 > γ-Fe2O3 > α-Fe2O3 > bulk Fe3O4. The application of Fe at concentrations ranging from 100 mg L−1 to 500 mg L−1 had no significant effects on various growth parameters of maize, including biomass, chlorophyll content, and root length. Iron oxide NPs increased the plant biomass by 23–37% by root application, whereas it was 5–9% by foliar application. Chlorophyll contents were increased by 29–34% and 18–22% by foliar and root applications, respectively. The non-significant response of reactive oxygen species (i.e., superoxide dismutase, catalase, and peroxidase) suggested optimum maize performance for supplementing Fe oxide NPs. A confocal laser scanning microscope suggested that Fe oxide NPs entered through the epidermis and from the cortex to the endodermis. Our results provide a scientific basis that the root application of Fe3O4 at the rate of 100 mg L−1 is a promising approach to obtain higher maize performance and reduce the quantity of fertilizer used in agriculture to minimize environmental effects while improving crop productivity and quality. These findings demonstrated the tremendous potential of Fe NPs as an environmentally friendly and sustainable crop approach.
Stability of the Macrocyclic Gd-DOTA Contrast Agent (DOTAREM) under Different Estuarine Environmental Conditions
Authors: Guerreiro Ana , Brito Pedro
Published: November 2023

Gadolinium-based contrast agents (GBCA) are complexes, highly stable in vivo, used in magnetic resonance imaging (MRI), administered in patients and then eliminated via the renal system, passing through wastewater treatment plants (WWTP) before being discarded in the receiving medium, without apparent removal. In this study, it was examined whether different exposure periods to several environmental parameters (solar radiation, different salinities, temperatures and pH) will influence the stability of these complexes, namely, the Gd-DOTA. Gd-DOTA solutions were processed in a seaFAST-pico saline matrix pre-concentration and elimination system, and Gd concentrations were determined using ICP-MS. The results showed that the complex remained stable in fresh, brackish and saline water environments, even when exposed to extreme temperatures (40 °C) or slightly acidic to basic conditions (6–10), for an exposure period of 96 h. A small increase in the free Gd concentration was observed after 18 days when exposed to pH < 4, in all tested salinities (0, 18 and 36 PSU), with a degradation increase of up to 29%, after 5 weeks of exposure in freshwater. When exposed to direct solar radiation, a low Gd-DOTA degradation (4%) was observed after 24 h at salinity 18 PSU and remained constant until the end of the exposure period (96 h), while the remaining salinities showed negligible values.
Identification of a Novel Hepacivirus in Southeast Asian Shrew (Crocidura fuliginosa) from Yunnan Province, China
Authors: Guo Ling , Li Bei , Han Peiyu , Dong Na , Zhu Yan , Li Fuli , Si Haorui , Shi Zhengli , Wang Bo , Yang Xinglou , Zhang Yunzhi
Published: November 2023

The genus Hepacivirus contains single-stranded positive-sense RNA viruses belonging to the family Flaviviridae, which comprises 14 species. These 14 hepaciviruses have been found in different mammals, such as primates, dogs, bats, and rodents. To date, Hepacivirus has not been reported in the shrew genus of Crocidura. To study the prevalence and genetic evolution of Hepacivirus in small mammals in Yunnan Province, China, molecular detection of Hepacivirus in small mammals from Yunnan Province during 2016 and 2017 was performed using reverse-transcription polymerase chain reaction (RT-PCR). Our results showed that the overall infection rate of Hepacivirus in small mammals was 0.12% (2/1602), and the host animal was the Southeast Asian shrew (Crocidura fuliginosa) (12.5%, 2/16). Quantitative real-time PCR showed that Hepacivirus had the highest viral RNA copy number in the liver. Phylogenetic analysis revealed that the hepaciviruses obtained in this study does not belong to any designated species of hepaciviruses and forms an independent clade. To conclude, a novel hepacivirus was identified for the first time in C. fuliginosa specimens from Yunnan Province, China. This study expands the host range and viral diversity of hepaciviruses.
Celecoxib/Cyclodextrin Eye Drop Microsuspensions: Evaluation of In Vitro Cytotoxicity and Anti-VEGF Efficacy for Retinal Diseases
Authors: Jansook Phatsawee , Soe Hay Man Saung Hnin , Asasutjarit Rathapon , Tun Theingi , Hnin Hay Marn , Maw Phyo Darli , Watchararot Tanapong , Loftsson Thorsteinn
Published: November 2023

Celecoxib (CCB), a cyclooxygenase-2 inhibitor, is capable of reducing oxidative stress and vascular endothelial growth factor (VEGF) expression in retinal cells and has been shown to be effective in the treatment of diabetic retinopathy and age-related macular degeneration. However, the ocular bioavailability of CCB is hampered due to its very low aqueous solubility. In a previous study, we developed 0.5% (w/v) aqueous CCB eye drop microsuspensions (MS) containing randomly methylated β-cyclodextrin (RMβCD) or γ-cyclodextrin (γCD) and hyaluronic acid (HA) as ternary CCB/CD/HA nanoaggregates. Both formulations exhibited good physicochemical properties. Therefore, we further investigated their cytotoxicity and efficacy in a human retina cell line in this study. At a CCB concentration of 1000 μg/mL, both CCB/RMβCD and CCB/γCD eye drop MS showed low hemolysis activity (11.1 ± 0.3% or 4.9 ± 0.2%, respectively). They revealed no signs of causing irritation and were nontoxic to retinal pigment epithelial cells. Moreover, the CCB eye drop MS exhibited significant anti-VEGF activity by reducing VEGF mRNA and protein levels compared to CCB suspended in phosphate buffer saline. The ex vivo transscleral diffusion demonstrated that a high quantity of CCB (112.47 ± 37.27 μg/mL) from CCB/γCD eye drop MS was deposited in the porcine sclera. Our new findings suggest that CCB/CD eye drop MS could be safely delivered to the ocular tissues and demonstrate promising eye drop formulations for retinal disease treatment.
Polymeric Particle BAM15 Targeting Macrophages Attenuates the Severity of LPS-Induced Sepsis: A Proof of Concept for Specific Immune Cell-Targeted Therapy
Authors: Udompornpitak Kanyarat , Bhunyakarnjanarat Thansita , Saisorn Wilasinee , Manipuntee Chonnavee , Plengplang Kittawat , Sittichaitaweekul Samarch , Jenphatanapong Panisa , Udomkarnjananun Suwasin , Kaewduangduen Warerat , Ariya-anandech Kasirapat , Samaeng Amanee , Insin Numpon , Ritprajak Patcharee , Leelahavanichkul Asada
Published: November 2023

Macrophage polarization requires different energy sources and metabolic processes. Therefore, cell energy interference to alter macrophage functions has been proposed as a treatment for severe inflammatory diseases, including sepsis. In this study, targeting cell energy using BAM15 (a mitochondrial uncoupling agent) in human THP-1 and mouse RAW264.7 macrophages prominently interfered with M1 but not M2 polarization. Free BAM15 (BAM15) and BAM15-loaded PLGA particles (BAM15 particles) reduced the inflammatory response of M1 macrophages and enhanced the expression of M2 signature genes with the restoration of mitochondrial activity (extracellular flux analysis) in RAW264.7 cells. Furthermore, BAM15 particles but not BAM15 showed specific effects on the inflammatory response of macrophages but not neutrophils, and the particles were actively captured by splenic and liver macrophages in vivo. Administration of BAM15 and BAM15 particles attenuated the severity of sepsis in LPS-induced sepsis mice. Interestingly, BAM15 particles but not BAM15 alleviated LPS-induced liver injury by reducing hepatic inflammation. Our findings substantiate the superior efficacy of macrophage-targeted therapy using a BAM15 particle-delivery system and provide further support for clinical development as a potential therapy for severe inflammatory diseases.
Differential Species Richness and Ecological Success of Epiphytes and Hemiepiphytes of Neotropical Araceae and Cyclanthaceae
Authors: Riordan Erin C. , Gerst Katharine L. , Vargas Ramirez Orlando , Rundel Philip W.
Published: November 2023

Numerous plant functional traits of ecophysiology and morphology associated with an epiphytic life history have promoted relatively high rates of evolutionary diversification and ecological success in tropical families such as the Orchidaeae, Polypodiaceae, Bromeliaceae, and Cactaceae. Epiphytic life histories are relatively uncommon in the Araceae and rare in the Cyclanthaceae which lack key functional traits for epiphytism. Only two lineages of Neotropical Araceae, Anthurium and Philodendron, include examples of epiphyte life histories. The evolution of a hemiepiphytic life history represented an important development for tropical Araceae by providing functional traits that have greatly expanded opportunities for adaptive radiation and ecological success as indicated by species richness and frequency of occurrence. The key adaptive trait allowing the diversification of hemiepiphytic Araceae was the development of heteroblastic growth of leaves and stems. Although hemiepiphytic life histories are present in the Cyclanthaceae, the family has undergone only modest speciation and limited ecological success in both its epiphytes and hemiepiphytes. Extensive sampling of more than 4600 trees from primary forest on four soil groups in northeastern Costa Rica have found a modest diversity of 15 species of epiphytic Araceae but only two species of epiphytic Cyclanthaceae. In contrast, 38 species of hemiepiphytic Araceae and 5 species of hemiepiphytic Cyclanthaceae were sampled, indicating relatively limited adaptive radiation of hemiepiphytic Cyclanthaceae and lower ecological success. Using summed values of frequency of occurrence as a measure of ecological success, epiphytic Araceae were 18 to 42 times more frequent than epiphytic Cyclanthaceae in swamp, alluvial, and residual soil forests. Summed frequencies of occurrence of hemiepiphytic Araceae were 7 to 13 times higher than those of hemiepiphytic Cyclanthaceae. The four soil groups were similar in their floristic composition of epiphytic and hemiepiphytic Araceae and Cyclanthaceae, but the frequencies of occurrence of both epiphytes and hemiepiphytes were, with few exceptions, highest on swamp soil plots, with alluvial soil plots slightly less favorable.