bluuebunny/crossref_metadata_2025 huggingface dataset:
Evaluation of Thermal and Mechanical Properties of Foamed Phosphogypsum-Based Cementitious Materials for Well Cementing in Hydrate Reservoirs
Authors: Tang Jiadi , Zhao Yusheng , Cheng Wan , Liu Tianle , Yang Guokun , Chen Mingsheng , Lei Gang , Xu Jian , Huang Yongning
Published: June 2024

As detrimental byproduct waste generated during the production of fertilizers, phosphogypsum can be harmlessly treated by producing phosphogypsum-based cementitious materials (PGCs) for offshore well cementing in hydrate reservoirs. To be specific, the excellent mechanical properties of PGCs significantly promote wellbore stability. And the preeminent temperature control performance of PGCs helps to control undesirable gas channeling, increasing the formation stability of natural gas hydrate (NGH) reservoirs. Notably, to further enhance temperature control performance, foaming agents are added to PGCs to increase porosity, which however reduces the compressive strength and increases the risk of wellbore instability. Therefore, the synergetic effect between temperature control performance and mechanical properties should be quantitatively evaluated to enhance the overall performance of foamed PGCs for well cementing in NGH reservoirs. But so far, most existing studies of foamed PGCs are limited to experimental work and ignore the synergetic effect. Motivated by this, we combine experimental work with theoretical work to investigate the correlations between the porosity, temperature control performance, and mechanical properties of foamed PGCs. Specifically, the thermal conductivity and compressive strength of foamed PGCs are accurately determined through experimental measurements, then theoretical models are proposed to make up for the non-repeatability of experiments. The results show that, when the porosity increases from 6% to 70%, the 7 d and 28 d compressive strengths of foamed PGCs respectively decrease from 21.3 MPa to 0.9 MPa and from 23.5 MPa to 1.0 MPa, and the thermal conductivity decreases from 0.33 W·m−1·K−1 to 0.12 W·m−1·K−1. Additionally, an overall performance index evaluation system is established, advancing the application of foamed PGCs for well cementing in NGH reservoirs and promoting the recycling of phosphogypsum.
Numerical Modelling of the Hydrodynamic Performance of Biodegradable Drifting Fish Aggregating Devices in Currents
Authors: Zhang Tongzheng , Zhang Junbo , Hou Qinglian , Yu Gangyi , Chen Ao , Liu Zhiqiang , Wan Rong
Published: June 2024

Fish Aggregating Devices (FADs) are essential supplementary structures used in tropical tuna purse-seine fishing. They are strategically placed to attract tuna species and enhance fishing productivity. The hydrodynamic performance of FADs has a direct effect on their structural and environmental safety in the harsh marine environment. Conventional FADs are composed of materials that do not break down naturally, leading to the accumulation of waste in the ocean and potential negative effects on marine ecosystems. Therefore, this work aimed to examine the hydrodynamic performance of biodegradable drifting FADs (Bio-DFADs) in oceanic currents by numerical modelling. The Reynolds-averaged Navier–Stokes equation was used to solve the flow field and discretized based on the realizable k-ε turbulence model, employing the finite volume method. A set of Bio-DFADs was developed to assess the hydrodynamic performance under varying current velocities and attack angles, as well as different balsa wood diameters and sinker weights. The results indicated that the relative current velocity significantly affected the relative velocity of Bio-DFADs. The relative length of the raft significantly affected both the relative velocity and the relative wetted area in a pure stream. Finally, the diameter of the balsa wood affected the drift velocity, and the sinker’s relative weight affected the hydrodynamic performance of the Bio-DFADs.
Aerodynamic Performance and Coupling Gain Effect of Archimedes Spiral Wind Turbine Array
Authors: Song Ke , Huan Huiting , Wei Liuchuang , Liu Chunxia
Published: June 2024

The Archimedes spiral wind turbine (ASWT), as a novel type of horizontal-axis wind turbine, is well suited for remote islands. To explore the aerodynamic performance and coupling gain effect of ASWT array, a three-dimensional numerical simulation was carried out using the computational fluid dynamics (CFD) method. The influence of arrangement, relative spacing, and rotation configuration on the performance of a double-unit array and triangular array is studied. The results demonstrate that, in parallel arrangements, the double unit achieve higher performance than an isolated ASWT within a specific range of parallel spacing. However, the effect of performance improvement gradually diminishes as the parallel spacing increases. In tandem arrangements, the upstream unit performance remains largely unaffected when tandem spacing exceeds 5 D, while the downstream unit’s performance declines notably with reducing tandem spacing. The downstream unit in reverse rotation configuration accrues more energy than its counterpart operating at the co-rotation configuration. In triangular arrangements, the reverse rotation configuration can achieve better performance due to the meshing effect between the wake of the upstream ASWT and the downstream ASWT. This configuration allows the array system to maintain a higher maximum power output within a smaller spacing. The research results can provide a basis and reference for designing the layout scheme of a multi-unit ASWT power station.
Right Ventricular Subclinical Dysfunction as a Predictor of Postoperative Adverse Clinical Outcomes in Patients with Femoral Fracture
Authors: Kim Hyun-Jin , Kim Hyun-Sun , Heo Jeong-Heon
Published: June 2024

Background: Femoral fractures often lead to complications such as altered pulmonary hemodynamics. Right ventricular global longitudinal strain (RV GLS), which correlates with pulmonary hemodynamics, indicates the subclinical function of the right ventricle (RV). This study aimed to investigate the predictive value of RV GLS for the risk of adverse clinical composite outcomes in patients with femoral fractures. Methods: Data were obtained from a prospective single-center cohort of patients hospitalized for femoral fractures and followed up for at least 1 year between March 2021 and October 2022. The primary outcome was the development of an adverse composite clinical event, which included pneumonia, pulmonary oedema or effusion, pulmonary thromboembolism, and all-cause mortality within the 1-year period following surgery. Results: Among the 163 patients, 36 (22.09%) experienced adverse composite clinical events during 1-year follow-up. The adverse outcome group demonstrated poorer RV GLS and RV free wall strain values than the non-adverse outcome group. The optimal cut-off value of RV GLS for predicting composite adverse clinical events was −12.55%. The cumulative composite event-free survival rate was significantly lower in the RV GLS ≥ −12.55% group (log-rank p-value = 0.003). After adjusting for confounding factors, multivariate Cox proportional hazards regression analyses showed that RV GLS ≥ −12.55% independently increased the risk of composite adverse clinical events by 2.65-fold. Conclusions: Poor RV GLS is a significant predictor of adverse clinical outcomes in patients with femoral fractures. Specifically, an RV GLS value of ≥ −12.55% indicated a substantially increased risk of adverse events.
Localized Sustainable Development Goals Changes and Their Response to Ecosystem Services—A Case of Typical Southern Hilly Regions in China
Authors: You Chang , Zhang Shidong , Liu Wenshu , Guo Luo
Published: June 2024

Sustainability has become an indispensable core consideration when nations formulate their development policies. This study delves into the dynamic correlations between ecosystem services (ESs) and localized Sustainable Development Goals (SDGs) in a typical hilly region in southern China. Various ESs were computed using the InVEST model, while spatial econometric models were employed to assess ES responses to SDG targets at the county, sectoral, and overall spatial levels. The findings revealed the following. (1) From 2005 to 2020, there were differences in the development rates of various SDG targets in Ganzhou. Except for SDG 15, which declined, the development of the other targets showed an overall increasing trend. The development of the various SDG targets was relatively balanced, but SDG 9 and SDG 7 had the highest growth rates, ranging from 9.4% to 10.7% and 9.4% to 10.3%, respectively. The comprehensive SDG assessment index exhibited significant spatiotemporal variation, with a general trend of higher values in the north and lower values in the south. (2) The local ES showed a delayed response to SDG 1 and SDG 2, but there was a significant positive response to SDG 3, SDG 4, SDG 6, SDG 8, and SDG 9. However, responses to SDG 7, SDG 11, SDG 13, and SDG 15 showed regional differences. This study not only provides valuable insights for sustainable development in Ganzhou and other regions of China but also offers Chinese perspectives and experiences that may inform global efforts towards SDG implementation. This study fills the gap in existing research by constructing a localized SDG indicator system and quantifying each SDG indicator, further exploring the response of the ES to each SDG in the region. Looking ahead, we anticipate further research to deepen the understanding of the relationship between ESs and SDG targets on a broader geographical scale and over longer timeframes, aiming to provide a more robust scientific foundation for building a harmonious coexistence between humans and nature in the future.
Heritage Evaluation of the Carob Tree MTAS in the Territory of Valencia: Analysis and Social Perception of the Ecosystem Services and Values from Cultivating It
Authors: Mayordomo-Maya Sandra , Hermosilla-Pla Jorge
Published: June 2024

The concept of Multifunctional Territorialized Agrifood Systems (MTASs) arose as an alternative to global hegemonic models in the 21st century. This study intends to identify the main ecosystem values and services generated by the MTAS of the carob tree in the territory of Valencia, which is one of the most characteristic dryland fruit tree species farmed in the Mediterranean. To do so, a multi-criteria quantitative evaluation system has been used that enables values to be assigned to the kinds of significance placed on MTASs. For this purpose, a questionnaire was carried out with 268 local inhabitants. The global score obtained is 7.6 points, indicating a high heritage value. Some of the criteria with the best scores are related to the authenticity of the carob tree and its social and historical values since this crop is a testament to ancestral techniques and traditions. Furthermore, this Mediterranean crop provides numerous ecosystem services and has multiple properties and applications, mainly in the food and pharmaceutical industries. The local population has scored the vulnerability value with only 4.1 points as a consequence of the progressive abandonment of the cultivated area in recent decades. Therefore, greater involvement from social stakeholders is essential in order to preserve this crop.
A Systematic Review on the Application of Virtual Reality for Muscular Dystrophy Rehabilitation: Motor Learning Benefits
Authors: Kiper Pawel , Federico Sara , Szczepańska-Gieracha Joanna , Szary Patryk , Wrzeciono Adam , Mazurek Justyna , Luque-Moreno Carlos , Kiper Aleksandra , Spagna Mattia , Barresi Rita , Cieślik Błażej
Published: June 2024

Using virtual reality (VR) for Muscular Dystrophy (MD) rehabilitation promises to be a novel therapeutic approach, potentially enhancing motor learning, functional outcomes, and overall quality of life. This systematic review primarily aimed to provide a comprehensive summary of the current understanding regarding the application of VR in supporting MD rehabilitation. A systematic search was performed in PubMed, Scopus, Cochrane Library, and Web of Science to identify relevant articles. The inclusion criteria encompassed studies involving individuals diagnosed with MD who underwent VR interventions, with a primary focus on assessing functional improvement. Methodological quality of the studies was assessed by using the Physiotherapy Evidence Database (PEDro) scale. Seven studies, involving 440 individuals with Duchenne Muscular Dystrophy (DMD), were included in the review. Among these studies, six primarily explored the motor learning potential of VR, while one study investigated the impact of VR training on functional abilities. In conclusion, the qualitative synthesis supports VR-based interventions’ potential positive effects on motor learning, performance improvement, and functional outcomes in individuals with DMD. However, current usage mainly focuses on assessing the potential mechanisms’ benefits, suggesting the importance of expanding clinical adoption to harness their therapeutic potential for MD patients.
Hydrogen Gas Inhalation Treatment for Coronary Artery Lesions in a Kawasaki Disease Mouse Model
Authors: Shih Wen-Ling , Yeh Tsung-Ming , Chen Kuang-Den , Leu Steve , Liu Shih-Feng , Huang Ying-Hsien , Kuo Ho-Chang
Published: June 2024

Background: Kawasaki disease (KD) is a syndrome primarily affecting young children, typically under the age of five, and is characterized by the development of acute vasculitis. Through extensive research conducted on both murine and human subjects, it has been demonstrated that heightened levels of reactive oxygen species (ROS) play a pivotal role in the development of KD, especial coronary artery lesions (CALs). Hydrogen gas exhibits potent antioxidant properties that effectively regulate ROS production and the inflammatory response. Methods: We used Lactobacillus casei cell wall extract (LCWE)-induced vasculitis in mice as an animal model of KD and treated the mice with hydrogen gas inhalation. Results: We observed significant dilatation and higher Z scores in the left coronary artery (LCA) in D21 and D28 in mice after LCWE treatment compared to the control group (p < 0.001) and a significant resolution of LCA diameters (p < 0.01) and Z scores (p < 0.01) after treatment with inhaled hydrogen gas. We further demonstrated that serum IL-6 expression was higher in mice after LCWE treatment (p < 0.01) and IL-6 significantly decreased after inhaled hydrogen gas therapy (p < 0.001). Conclusion: According to our literature review, this is the first report where hydrogen gas inhalation has been demonstrated to be effective for the treatment of coronary artery dilatation in a KD murine model.
Quantification of Nitrate Level in Shallow and Deep Groundwater Wells for Drinking, Domestic and Agricultural Uses in Northeastern Arid Regions of Saudi Arabia
Authors: Mamun Al , Sharif Hatim O.
Published: June 2024

Nitrate (NO3−) is a vulnerable natural contaminant that can be found in groundwater. The estimated nitrate concentrations for four categories of wells in the northeastern arid regions of Saudi Arabia—commercial treated water stations for drinking, commercial stations of untreated water for domestic uses, private wells of residences for households, and private wells for agricultural uses—were found to be in the 16–380 mg/L range. Drinking water from all commercial treated water stations has lower nitrate levels, based on the WHO standard of 50 mg/L. In contrast, almost 33% of commercial stations with untreated water (used only for domestic purposes) in the studied areas had higher nitrate levels that were unsuitable for drinking. Approximately half of the private wells of residences and wells for agricultural uses had very high nitrate levels. They can be considered unsuitable for drinking due to excessive levels of nitrates but can be used for domestic and agricultural purposes. Thus, adopting specific strategies to reduce nitrate levels in public wells in the studied areas is crucial. The data obtained in the present study are essential for equipping decision-makers with valuable insights, allowing them to enact appropriate measures, as needed, and uphold community health in the studied regions.
Ethyl 5-Hydroxy-2-methyl-1-(pyridin-2-ylmethyl)benzo[g]indole-3-carboxylate
Authors: Satta Giuseppe , Gaspa Silvia , Luca Lidia De , Pisano Luisa , Carraro Massimo
Published: June 2024

Indole ring is widely represented in natural compounds, as well as in a great variety of drugs. In this paper, the synthesis of a 5-hydroxybenzoindole derivative carrying a pyridyl substituent on position 1 is reported. The method involved no chromatography for purification and used solvents and catalysts of very low toxicity.
Structure of Polaronic Centers in Proton-Intercalated AWO4 Scheelite-Type Tungstates
Authors: Bakradze Georgijs , Welter Edmund , Kuzmin Alexei
Published: June 2024

The studies of polaronic centers in a homologous series of scheelite-type compounds AWO4 (A = Ca, Sr, Ba) were performed using the W L3-edge and Sr K-edge X-ray absorption spectroscopy combined with the reverse Monte Carlo simulations, X-ray photoelectron spectroscopy (XPS), and first-principles calculations. Protonated scheelites HxAWO4 were produced using acid electrolytes in a one-step route at ambient conditions. The underlying mechanism behind this phenomenon can be ascribed to the intercalation of H+ into the crystal structure of tungstate, effectively resulting in the reduction of W6+ to W5+, i.e., the formation of polaronic centers, and giving rise to a characteristic dark blue-purple color. The emergence of the W5+ was confirmed by XPS experiments. The relaxation of the local atomic structure around the W5+ polaronic center was determined from the analysis of the extended X-ray absorption fine structures using the reverse Monte Carlo method. The results obtained suggest the displacement of the W5+ ions from the center of [W5+O4] tetrahedra in the structure of AWO4 scheelite-type tungstates. This finding was also supported by the results of the first-principles calculations.
Activated Carbon Prepared from Waste Coffee Grounds: Characterization and Adsorption Properties of Dyes
Authors: Aouay Feryelle , Attia Afef , Dammak Lasâad , Ben Amar Raja , Deratani Andre
Published: June 2024

Spent coffee grounds (SCGs) have great potential as a useful, value-added biological material. In this context, activated carbon (AC) was prepared from SCGs by an activation process using H3PO4 at 600 °C in the air and used as an adsorbent for the azo dye AO7, a model molecule for dye colorants found in textile industry effluents. X-ray diffraction, SEM and BET revealed that the AC was predominantly amorphous, consisting of a powder of 20–100 µm particles with mesopores averaging 5.5 nm in pore size. Adsorption kinetics followed a pseudo-second-order law, while the Langmuir model best fitted the experimental isotherm data (maximum capacity of 119.5 mg AO7 per AC g). The thermodynamic parameters revealed that adsorption was endothermic and spontaneous. All the characterizations indicated that adsorption occurred by physisorption via mainly π–π interactions. The best experimental removal efficiency optimized by means of a Box–Behnken design and response surface methodology was 98% for an initial AO7 concentration of 20 mg·L−1 at pH 7.5 with a dose of 0.285 g·L−1 of AC and a contact time of 40 min. These results clearly show that activated carbon prepared from SCGs can be a useful material for efficiently removing organic matter from aqueous solutions.
Examination of Beam Theories for Buckling and Free Vibration of Functionally Graded Porous Beams
Authors: Wu Shuaishuai , Li Yilin , Bao Yumei , Zhu Jun , Wu Helong
Published: June 2024

This paper examines the accuracy and effectiveness of various beam theories in predicting the critical buckling loads and fundamental frequencies of functionally graded porous (FGP) beams whose material properties change continuously across the thickness. The beam theories considered are classical beam theory (CBT), first-order shear deformation beam theory (FSDBT), third-order shear deformation beam theory (TSDBT), and the broken-line hypothesis-based shear deformation beam theory (BSDBT). Governing equations for those beam theories are formulated by using the Hamilton’s principle and are then solved by means of the generalised differential quadrature method. Finite element simulation solutions are provided as reference results to assess the predictions of those beam theories. Comprehensive numerical results are presented to evaluate the influences of the porosity distribution and coefficient, slenderness ratio, and boundary condition on the difference between theoretical predictions and simulation results. It is found that the differences significantly increase as the porosity coefficient rises, and this effect becomes more noticeable for the rigid beam with a smaller slenderness ratio. Nonetheless, the results produced by the BSDBT are always the closest to simulation ones. The findings in this paper will contribute to the establishment of more refined theories for the mechanical analysis of FGP structures.
Evaluation of Bio-Rejuvenator and Compaction Conditions on Stiffness Modulus and Indirect Tensile Strength of Recycled Hot Mix Asphalt
Authors: Forton Andrei , Ciutina Adrian , Stirb Adelin , Marc Paul , Costescu Ciprian , Ciopec Alexandra
Published: June 2024

This study focuses on the investigation of the effect of a reclaimed asphalt material (RAP) and a bio-rejuvenator (mix of vegetable oils) on the stiffness modulus and indirect tensile strength (ITS) values of eight bituminous mixtures produced by using three types of compaction, with different RAP amounts (25% and 50%) and rejuvenator (0%, 0.20%, 0.40% and 0.60% by mass of RAP). A conventional hot mix asphalt was considered as the reference mix. All tests were performed on cylindrical samples produced using: Marshall compaction with 50 blows/side, cored cylindrical specimens from slabs compacted using a roller compactor (39 passes), and, respectively, gyratory compaction on 80 gyrations. Stiffness modulus and ITS values showed strong linear variation with the increase in rejuvenator content, independently of test temperature and type of compaction. The rejuvenating effect of the bio-rejuvenator was observed to counterbalance the impact of RAP. The results at 20 °C for gyratory specimens for the mix with 50% RAP and 0.40% bio-rejuvenator were comparable/closer (under 5% relative difference) to those obtained for the reference mix. A strong correlation between stiffness modulus values of mixes and penetration values of the corresponding binder blends was obtained (R2≥0.977).
Modern Rare Earth Imprinted Membranes for the Recovery of Rare Earth Metal Ions from Coal Fly Ash Extracts
Authors: Rybak Aleksandra , Rybak Aurelia , Boncel Sławomir , Kolanowska Anna , Jakóbik-Kolon Agata , Bok-Badura Joanna , Kaszuwara Waldemar
Published: June 2024

The need to identify secondary sources of REEs and their recovery has led to the search for new methods and materials. In this study, a novel type of ion-imprinted adsorption membranes based on modified chitosan was synthesized. Their application for the recovery of chosen REEs from synthetic coal fly ash extracts was analyzed. The examined membranes were analyzed in terms of adsorption kinetics, isotherms, selectivity, reuse, and their separation abilities. The experimental data obtained were analyzed with two applications, namely, REE 2.0 and REE_isotherm. It was found that the adsorption of Nd3+ and Y3+ ions in the obtained membranes took place according to the chemisorption mechanism and was significantly controlled by film diffusion. The binding sites on the adsorbent surface were uniformly distributed; the examined ions showed the features of regular monolayer adsorption; and the adsorbents showed a strong affinity to the REE ions. The high values of Kd (900–1472.8 mL/g) demonstrate their high efficiency in the recovery of REEs. After five subsequent adsorption–desorption processes, approximately 85% of the value of one cycle was reached. The synthesized membranes showed a high rejection of the matrix components (Na, Mg, Ca, Al, Fe, and Si) in the extracts of the coal fly ashes, and the retention ratio for these Nd and Y ions was 90.11% and 80.95%, respectively.
Experimental Evidence of Efficient Phononic-Based Vibration Isolators for Mechanical Applications
Authors: Policarpo Hugo , Almeida Raquel A. B. , Neves Miguel M. , Maia Nuno M. M.
Published: June 2024

Even though the design of vibration isolators is well-established for many engineering applications, their efficiency in wide and multiple frequency ranges is still a challenge. In these cases, the use of Phononic-Based Vibration Isolators (PBVIs) may be advantageous as they present different Attenuation Regions (ARs) in which the elastic waves are strongly attenuated. Therefore, the present paper is devoted to the experimental evaluation, in terms of force transmissibility, of different types of supporting devices tested on a load mass and a motor of a Hermetic Compressor (HC). Those devices are the original Helical Coil Spring (HS) that equips the HC, the PBVI, and the Combined Structure (CS) which is composed of a PBVI combined in series with the HS. Results evidentiate the capability of the CSs to isolate vibrations, where the PBVI contributes with its ARs, thus operating as a “filter” in specific frequency ranges, while the HSs maintain the flexibility of the CSs, which is advantageous for impact-loads and/or transient-case scenarios. Hence, the capability, relevance and impact that these PBVIs present for force transmissibility reduction applications is highlighted here, which should capture the attention of and motivate the industry, e.g., producers of isolation systems, since it has wide-ranging engineering applications.
Quantitative Assessment of Bed-Separation Dynamic Development Caused by Inclined Coal Seam Longwall Mining
Authors: Li Yaxing , Yang Keming , Wei Xiangping , Tang Wei , Jiang Kegui
Published: June 2024

Coal mining under the Quaternary thick loose layer affects key strata breakage, Bed-separations development, ground subsidence, and other studies. This paper presents a method for solving the deflection of a large-deflection inclined thin plate under a thick loose-layer cover with additional lateral loads and midplane forces. The methods presented are based on the principle of large-deflection of thin-plate, energy method, and fracture mechanics theory. The 7225 work face in Anhui Province, China, was studied. Combined with the large-deflection inclined thin plate model, the initial breakage distance within the main roof plate was calculated to be 33 m with the initial breakage angle of 61.2°, and the period breakage distance was calculated to be 21 m with the period breakage angle of 55.4°. The distribution range of “Vertical Three Zones” from 7225 working face to the ground, including the height of the caved zone is 38.07 m, the height of the fractured zone is 41.13 m, and the height of the curved zone with the thick loose layer removed is 187.56 m. During the dynamic development of the principal key strata (PKS), the deflection value develops from 0 mm to 2714 mm with 7225 working face mining, and the maximum value of the spatial volume is 56,485 m3, which is verified by Three-dimensional Discrete Element Code (3DEC) numerical simulation. The dynamic development of Bed-separation within the overlying strata, with a maximum development height of 545.2 mm and a maximum volume of 11,228.1 m3 of the Bed-separation cavity. The dynamic development of the Bed-separation height and the cavity under different mining length and width conditions of the working face are also discussed. The large-deflection inclined thin plate model proposed in this paper effectively explores the dynamic deflection and fragmentation law of the overlying strata induced by the inclined working face of Longwall mining and provides a theoretical basis and computational model for quantitatively evaluating the dynamic development of the Bed-separation cavity.
Plastic Shakedown Behavior and Deformation Mechanisms of Ti17 Alloy under Long Term Creep–Fatigue Loading
Authors: Wang Jianguo , Man Tongchi , Liu Dong , Zhang Zhihong , Zhang Chi , Sun Yuxiang
Published: June 2024

Ti17 alloy is mainly used to manufacture aero-engine discs due to its excellent properties such as high strength, toughness and hardenability. It is often subjected to creep–fatigue cyclic loading in service environments. Shakedown theory describes the state in which the accumulated plastic strain of the material stabilizes after several cycles of cyclic loading, without affecting its initial function and leading to failure. This theory includes three behaviors: elastic shakedown, plastic shakedown and ratcheting. In this paper, the creep–fatigue tests (CF) were conducted on Ti17 alloy at 300 °C to study its shakedown behavior under creep–fatigue cyclic loading. Based on the plasticity–creep superposition model, a theory model that accurately describes the shakedown behavior of Ti17 alloy was constructed, and ABAQUS finite element software was used to validate the accuracy of the model. TEM analysis was performed to observe the micro-mechanisms of shakedown in Ti17 alloy. The results reveal that the Ti17 alloy specimens exhibit plastic shakedown behavior after three cycles of creep–fatigue loading. The established finite element model can effectively predict the plastic shakedown process of Ti17 alloy, with a relative error between the experimental and simulation results within 4%. TEM results reveal that anelastic recovery controlled by dislocation bending and back stress hardening caused by inhomogeneous deformation are the main mechanisms for the plastic shakedown behavior of Ti17 alloy.
Exploring the Microbial Mosaic: Insights into Composition, Diversity, and Environmental Drivers in the Pearl River Estuary Sediments
Authors: Zvi-Kedem Tal , Lalzar Maya , Sun Jing , Li Jiying , Tchernov Dan , Meron Dalit
Published: June 2024

River estuaries are dynamic and complex ecosystems influenced by various natural processes, including climatic fluctuations and anthropogenic activities. The Pearl River Estuary (PRE), one of the largest in China, receives significant land-based pollutants due to its proximity to densely populated areas and urban development. This study aimed to characterize the composition, diversity, and distribution patterns of sediment microbial communities (bacteria, archaea, and eukaryotes) and investigated the connection with environmental parameters within the PRE and adjacent shelf. Physicochemical conditions, such as oxygen levels, nitrogen compounds, and carbon content, were analyzed. The study found that the microbial community structure was mainly influenced by site location and core depth, which explained approximately 67% of the variation in each kingdom. Sites and core depths varied in sediment properties such as organic matter content and redox conditions, leading to distinct microbial groups associated with specific chemical properties of the sediment, notably C/N ratio and NH4+ concentration. Despite these differences, certain dominant taxonomic groups were consistently present across all sites: Gammaproteobacteria in bacteria; Bathyarchaeia, Nitrososphaeria, and Thermoplasmata in archaea; and SAR in Eukaryota. The community diversity index was the highest in the bacteria kingdom, while the lowest values were observed at site P03 across the three kingdoms and were significantly different from all other sites. Overall, this study highlights the effect of depth, core depth, and chemical properties on sediment microbiota composition. The sensitivity and dynamism of the microbiota, along with the possibility of identifying specific markers for changes in environmental conditions, is valuable for managing and preserving the health of estuaries and coastal ecosystems.
Technological Advancement in Solar Photovoltaic Recycling: A Review
Authors: Martínez Monserrat , Barrueto Yahaira , Jimenez Yecid P. , Vega-Garcia Dennis , Jamett Ingrid
Published: June 2024

This review examines the technological surveillance of photovoltaic panel recycling through a bibliometric study of articles and patents. The analysis considered the number of articles and patents published per year, per country, and, in the case of patents, per applicant. This analysis revealed that panel recycling is an increasingly prominent research area. However, the number of patents filed annually has varied in recent years, averaging fewer than 200 per year. The state-of-the-art review identified three main types of treatment for photovoltaic panel recycling: mechanical, chemical, and thermal. Among these, mechanical treatment serves as a preliminary stage before the recovery of valuable elements, which is achieved through chemical or thermal processes. The articles reviewed cover a range of processes, including hydrometallurgical and pyrometallurgical methods, and explore various classification processes, solvents, and oxidizing agents. In contrast, patents predominantly focus on pyrometallurgical processes. This analysis is supplemented by a survey of market-ready technologies, many of which include stages such as size reduction or delamination followed by pyrometallurgical processes. Additionally, the review highlights the collection processes implemented by some companies, noting that the volume of panels considered waste is currently insufficient to maintain a continuous and year-round operational process. This study identifies key challenges such as (i) reducing solar panel size due to the EVA polymer complicating conventional machinery use, (ii) high process costs from the need for high temperatures and costly additives, (iii) the environmental impact of thermal treatments with high energy consumption and air pollution, and (iv) the necessity for environmentally friendly solvents in hydrometallurgical treatments to reduce contamination during recycling. Future directions include developing specific machinery for panel size reduction, either creating or modifying a polymer to replace EVA for easier treatment, adopting hydrometallurgical treatments with green solvents proven effective in recycling minerals and electronic waste, and addressing the lack of detailed information on industrial processes to make more precise recommendations.
Electrocatalytic Decomposition of Lithium Oxalate-Based Composite Microspheres as a Prelithiation Additive in Lithium-Ion Batteries
Authors: Liu Jian , Lin Jingyi , Yin Zuwei , Tong Zhen , Liu Junke , Wang Zhen , Zhou Yao , Li Juntao
Published: June 2024

In conventional lithium-ion batteries (LIBs), the active lithium from the lithium-containing cathode is consumed by the formation of a solid electrolyte interface (SEI) at the anode during the first charge, resulting in irreversible capacity loss. Prelithiation additives can provide additional active lithium to effectively compensate for lithium loss. Lithium oxalate is regarded as a promising ideal cathode prelithiation agent; however, the electrochemical decomposition of lithium oxalate is challenging. In this work, a hollow and porous composite microsphere was prepared using a mixture of lithium oxalate, Ketjen Black and transition metal oxide catalyst, and the formulation was optimized. Owing to the compositional and structural merits, the decomposition voltage of lithium oxalate in the microsphere was reduced to 3.93 V; when being used as an additive, there is no noticeable side effect on the performance of the cathode material. With 4.2% of such an additive, the first discharge capacity of the LiFePO4‖graphite full cell increases from 139.1 to 151.9 mAh g−1, and the coulombic efficiency increases from 88.1% to 96.3%; it also facilitates the formation of a superior SEI, leading to enhanced cycling stability. This work provides an optimized formula for developing an efficient prelithiation agent for LIBs.
Targeted Stimulation of Micropores by CS2 Extraction on Molecular of Coal
Authors: Zhang Zhen , Liu Gaofeng , Wang Xiaoming , Lin Jia , Barakos George , Chang Ping
Published: June 2024

The targeted stimulation of micropores based on the transformation of coal’s molecular structure is proposed due to the chemical properties and difficult-to-transform properties of micropores. Carbon disulfide (CS2) extraction is used as a targeted stimulation to reveal the internal evolution mechanism of micropore transformation. The variations of microcrystalline structures and micropores of bituminous coal and anthracite extracted by CS2 were analyzed with X-ray diffraction (XRD), low-temperature carbon dioxide (CO2) adsorption, and molecular simulation. The results show that CS2 extraction, with the broken chain effect, swelling effect, and aromatic ring rearrangement effect, can promote micropore generation of bituminous coal by transforming the microcrystalline structure. Furthermore, CS2 extraction on bituminous coal can decrease the average micropore size and increase the micropore volume and area. The aromatic layer fragmentation effect of CS2 extraction on anthracite, compared to the micropore generation effect of the broken chain effect and swelling effect, can enlarge micropores more remarkably, as it induces an enhancement in the average micropore size and a decline in the micropore volume and area. The research is expected to provide a theoretical basis for establishing reservoir stimulation technology based on CS2 extraction.
Revisiting and Updating the Interaction between Human Serum Albumin and the Non-Steroidal Anti-Inflammatory Drugs Ketoprofen and Ketorolac
Authors: Cunha Rita S. , Cruz Pedro F. , Costa Telma , Almeida Zaida L. , Lima Marco Edilson Freire de , Serpa Carlos , Chaves Otávio A.
Published: June 2024

Ketoprofen (KTF) and ketorolac (KTL) are among the most primarily used non-steroidal anti-inflammatory drugs (NSAIDs) in humans to alleviate moderate pain and to treat inflammation. Their binding affinity with albumin (the main globular protein responsible for the biodistribution of drugs in the bloodstream) was previously determined by spectroscopy without considering some conventional pitfalls. Thus, the present work updates the biophysical characterization of the interactions of HSA:KTF and HSA:KTL by 1H saturation-transfer difference nuclear magnetic resonance (1H STD-NMR), ultraviolet (UV) absorption, circular dichroism (CD), steady-state, and time-resolved fluorescence spectroscopies combined with in silico calculations. The binding of HSA:NSAIDs is spontaneous, endothermic, and entropically driven, leading to a conformational rearrangement of HSA with a slight decrease in the α-helix content (7.1% to 7.6%). The predominance of the static quenching mechanism (ground-state association) was identified. Thus, both Stern–Volmer quenching constant (KSV) and binding constant (Kb) values enabled the determination of the binding affinity. In this sense, the KSV and Kb values were found in the order of 104 M−1 at human body temperature, indicating moderate binding affinity with differences in the range of 0.7- and 3.4-fold between KTF and KTL, which agree with the previously reported experimental pharmacokinetic profile. According to 1H STD-NMR data combined with in silico calculations, the aromatic groups in relation to the aliphatic moiety of the drugs interact preferentially with HSA into subdomain IIIA (site II) and are stabilized by interactions via hydrogen bonding and hydrophobic forces. In general, the data obtained in this study have been revised and updated in comparison to those previously reported by other authors who did not account for inner filter corrections, spectral backgrounds, or the identification of the primary mathematical approach for determining the binding affinity of HSA:KTF and HSA:KTL.
A Tight-Connection g-C3N4/BiOBr (001) S-Scheme Heterojunction Photocatalyst for Boosting Photocatalytic Degradation of Organic Pollutants
Authors: Zhang Xinyi , Li Weixia , Hu Liangqing , Gao Mingming , Feng Jing
Published: June 2024

The efficient separation of photogenerated charge carriers and strong oxidizing properties can improve photocatalytic performance. Here, we combine the construction of a tightly connected S-scheme heterojunction with the exposure of an active crystal plane to prepare g-C3N4/BiOBr for the degradation of high-concentration organic pollutants. This strategy effectively improves the separation efficiency of photogenerated carriers and the number of active sites. Notably, the synthesized g-C3N4/BiOBr displays excellent photocatalytic degradation activity towards various organic pollutants, including methylene blue (MB, 90.8%), congo red (CR, 99.2%), and tetracycline (TC, 89%). Furthermore, the photocatalytic degradation performance of g-C3N4/BiOBr for MB maintains 80% efficiency under natural water quality (tap water, lake water, river water), and a wide pH range (pH = 4–10). Its excellent photocatalytic activity is attributed to the tight connection between g-C3N4 and BiOBr in the S-scheme heterojunction interface, as well as the exposure of highly active (001) crystal planes. These improve the efficiency of the separation of photogenerated carriers, and maintain their strong oxidation capability. This work presents a simple approach to improving the separation of electrons and holes by tightly combining two components within a heterojunction.
Solvothermal Synthesis of Cu2ZnSnSe4 Nanoparticles and Their Visible-Light-Driven Photocatalytic Activity
Authors: Henríquez Rodrigo , Salazar Nogales Paula , Grez Moreno Paula , Muñoz Cartagena Eduardo , Leyton Bongiorno Patricio , Zerega Garate Pablo , Navarrete-Astorga Elena , Dalchiele Enrique A.
Published: June 2024

Cu2ZnSnSe4 (CZTSe) nanoparticles (NPs) were successfully synthesized via a solvothermal method. Their structural, compositional, morphological, optoelectronic, and electrochemical properties have been characterized by X-ray diffraction (XRD), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), Field-emission scanning electron microscopy (FE-SEM), transmission electron microscope (TEM), UV–vis absorption spectroscopy, and electrochemical impedance spectroscopy (EIS) techniques. Porosimetry and specific surface area in terms of the Brunauer–Emmett–Teller (BET) technique have also been studied. XRD indicates the formation of a polycrystalline kesterite CZTSe phase. Raman peaks at 173 and 190 cm−1 confirm the formation of a pure phase. TEM micrographs revealed the presence of nanoparticles with average sizes of ~90 nm. A BET surface area of 7 m2/g was determined. The CZTSe NPs showed a bandgap of 1.0 eV and a p-type semiconducting behavior. As a proof of concept, for the first time, the CZTSe NPs have been used as a visible-light-driven photocatalyst to Congo red (CR) azo dye degradation. The nanophotocatalyst material under simulated sunlight results in almost complete degradation (96%) of CR dye after 70 min, following a pseudo-second-order kinetic model (rate constant of 0.334 min−1). The prepared CZTSe was reusable and can be repeatedly used to remove CR dye from aqueous solutions.
MnO2 Nanoparticles Decorated PEDOT:PSS for High Performance Stretchable and Transparent Supercapacitors
Authors: Liu Guiming , Huang Zhao , Xu Jiujie , Lin Tiesong , Zhang Bowen , He Peng
Published: June 2024

With the swift advancement of wearable electronics and artificial intelligence, the integration of electronic devices with the human body has advanced significantly, leading to enhanced real-time health monitoring and remote disease diagnosis. Despite progress in developing stretchable materials with skin-like mechanical properties, there remains a need for materials that also exhibit high optical transparency. Supercapacitors, as promising energy storage devices, offer advantages such as portability, long cycle life, and rapid charge/discharge rates, but achieving high capacity, stretchability, and transparency simultaneously remains challenging. This study combines the stretchable, transparent polymer PEDOT:PSS with MnO2 nanoparticles to develop high-performance, stretchable, and transparent supercapacitors. PEDOT:PSS films were deposited on a PDMS substrate using a spin-coating method, followed by electrochemical deposition of MnO2 nanoparticles. This method ensured that the nanosized MnO2 particles were uniformly distributed, maintaining the transparency and stretchability of PEDOT:PSS. The resulting PEDOT:PSS/MnO2 nanoparticle electrodes were gathered into a symmetric device using a LiCl/PVA gel electrolyte, achieving an areal capacitance of 1.14 mF cm−2 at 71.2% transparency and maintaining 89.92% capacitance after 5000 cycles of 20% strain. This work presents a scalable and economical technique to manufacturing supercapacitors that combine high capacity, transparency, and mechanical stretchability, suggesting potential applications in wearable electronics.
The Effect of the Lacticaseibacillus paracasei BEPC22 and Lactiplantibacillus plantarum BELP53 Combination (BN-202M) on Body Fat Percentage Loss in Overweight Individuals: A Randomized, Double-Blind, Placebo-Controlled Study
Authors: Kwon Han-Seul , Kim Seok-Jin , Shin Kum-Joo , Kim Sanghoon , Yun Jongbok , Bae Jaewoong , Tak Hyun-Ji , Lee Na-Rae , Kim Hyeong-Jun
Published: June 2024

BN-202M is derived from humans and consists of two strains, Lacticaseibacillus paracasei BEPC22 and Lactiplantibacillus plantarum BELP53. Body fat reduction effect and safety of BN-202M were assessed in overweight participants. A total of 150 participants were randomly assigned to the BN-202M and placebo groups at a 1:1 ratio. Dual-energy X-ray absorptiometry was used to objectively measure body fat. After 12 weeks of oral administration, the body fat percentage (−0.10 ± 1.32% vs. 0.48 ± 1.10%; p = 0.009) and body fat mass (−0.24 ± 1.19 kg vs. 0.23 ± 1.05 kg; p = 0.023) of the BN-202M group decreased significantly compared to those of the placebo group. The body weight (−0.58 kg, p = 0.004) and body mass index (BMI; −0.23, p = 0.003) was found to decrease significantly at 12 weeks in the BN-202M group, but not in the placebo group. Metabolome analysis revealed that β-alanine, 3-aminoisobutyric acid, glutamic acid, and octopamine decreased in the weight-decreased BN-202M post-intake group. In the gut microbiota analysis, Akkermansia showed a statistically significant increase in the BN-202M group post-intake compared to the placebo group. No serious adverse events were observed in either group. These results suggest that BN-202M is safe and effective for reducing body fat and weight.