bluuebunny/crossref_metadata_2025 huggingface dataset:
Inorganic Finishing for Textile Fabrics: Recent Advances in Wear-Resistant, UV Protection and Antimicrobial Treatments
Authors: Sfameni Silvia , Hadhri Mariam , Rando Giulia , Drommi Dario , Rosace Giuseppe , Trovato Valentina , Plutino Maria Rosaria
Published: January 2023

The surface modification of textile fabrics and therefore, the development of advanced textile materials featuring specific implemented and new properties, such as improved durability and resistance, is increasingly in demand from modern society and end-users. In this regard, the sol–gel technique has shown to be an innovative and convenient synthetic route for developing functional sol–gel coatings useful for the protection of textile materials. Compared with the conventional textile finishing process, this technique is characterized by several advantages, such as the environmentally friendly approaches based on one-step applications and low concentration of non-hazardous chemicals. The sol–gel method, starting from inorganic metal alkoxides or metal salts, leads to inorganic sols containing particles that enable a chemical or physical modification of fiber surfaces, giving rise to final multifunctional properties of treated textile fabrics. This review considered the recent developments in the synthesis of inorganic nanoparticles and nanosols by sol–gel approach for improving wear and UV resistance, as well as antibacterial or antimicrobial effects for textile applications.
Bulk Physical Properties of a Magnetic Weyl Semimetal Candidate NdAlGe Grown by a Laser Floating-Zone Method
Authors: Kikugawa Naoki , Terashima Taichi , Kato Takashi , Hayashi Momoko , Yamaguchi Hitoshi , Uji Shinya
Published: January 2023

In this study, we report the successful growth of single crystals of a magnetic Weyl semimetal candidate NdAlGe with the space group I41md. The crystals were grown using a floating-zone technique, which used five laser diodes, with a total power of 2 kW, as the heat source. To ensure that the molten zone was stably formed during the growth, we employed a bell-shaped distribution profile of the vertical irradiation intensity. After the nominal powder, crushed from an arc-melted ingot, was shaped under hydrostatic pressure, we sintered the feed and seed rods in an Ar atmosphere under ultra-low oxygen partial pressure (<10−26 atm) generated by an oxygen pump made of yttria-stabilized zirconia heated at 873 K. Single crystals of NdAlGe were successfully grown to a length of 50 mm. The grown crystals showed magnetic order in bulk at 13.5 K. The fundamental physical properties were characterized by magnetic susceptibility, magnetization, specific heat, thermal expansion, and electrical resistivity measurements. This study demonstrates that the magnetic order induces anisotropic magnetoelasticity, magneto-entropy, and charge transport in NdAlGe.
A Manganese(II) 3D Metal–Organic Framework with Siloxane-Spaced Dicarboxylic Ligand: Synthesis, Structure, and Properties
Authors: Stoica Alexandru-Constantin , Damoc Madalin , Shova Sergiu , Novitchi Ghenadie , Dascalu Mihaela , Cazacu Maria
Published: January 2023

A new metal–organic framework {[Mn4(Cx)3(etdipy)5]·2ClO4}n (1) was prepared via the complexation of manganese ion from a Mn(ClO4)2 source with 1,3-bis(carboxypropyl)tetramethyldisiloxane (Cx) and 1,2-di(4-pyridyl)ethylene (etdipy) in the presence of 2,4-lutidine as a deprotonating agent. The single-crystal X-ray diffraction analysis revealed a dense 3D framework structure. The presence in the structure of flexible tetramethyldisiloxane moieties, which tend to orient themselves at the interface with the air, gives the compound a highly hydrophobic character, as indicated by the result of the water vapor sorption analysis in the dynamic regime, as well as the shape and stability of the water droplet on the crystalline mass of the compound. The compound is an electrical insulator, and due to its hydrophobicity, this characteristic is unaffected by environmental dampness. The thermal analysis indicated thermal stability up to about 300 °C and an unusual thermal transition for an MOF structure, more precisely a glass transition at 24 °C, the latter also being attributed to the flexible segments in the structure. The magnetic studies showed dominant antiferromagnetic interactions along the metal ion chain in compound 1.
Synthesis of Piperine-Based Ester Derivatives with Diverse Aromatic Rings and Their Agricultural Bioactivities against Tetranychus cinnabarinus Boisduval, Aphis citricola Van der Goot, and Eriosoma lanigerum Hausmann
Authors: Li Tianze , Lv Min , Wen Houpeng , Wang Yanyan , Thapa Sunita , Zhang Shaoyong , Xu Hui
Published: January 2023

Exploration of plant secondary metabolites or by using them as leads for development of new pesticides has become one of the focal research topics nowadays. Herein, a series of new ester derivatives of piperine were prepared via the Vilsmeier–Haack–Arnold (VHA) reaction, and their structures were characterized by infrared spectroscopy (IR), melting point (mp), proton nuclear magnetic resonance spectroscopy (1H NMR), and carbon nuclear magnetic resonance spectroscopy (13C NMR). Notably, the steric configurations of compounds 6 and 7 were confirmed by single-crystal analysis. Against T. cinnabarinus, compounds 9 and 11 exhibited 47.6- and 45.4-fold more pronounced acaricidal activity than piperine. In particular, compounds 9 and 11 also showed 2.6-fold control efficiency on the fifth day of piperine. In addition, compound 6 (>10–fold higher than piperine) displayed the most potent aphicidal activity against A. citricola. Furthermore, some derivatives showed good aphicidal activities against E. lanigerum. Moreover, the effects of compounds on the cuticles of T. cinnabarinus were investigated by the scanning electron microscope (SEM) imaging method. This study will pave the way for future high value added application of piperine and its derivatives as botanical pesticides.
Chemical Composition, Repellent Action, and Toxicity of Essential Oils from Lippia origanoide, Lippia. alba Chemotypes, and Pogostemon cablin on Adults of Ulomoides dermestoides (Coleoptera: Tenebrionidae)
Authors: Caballero-Gallardo Karina , Fuentes-Lopez Katerin , Stashenko Elena E. , Olivero-Verbel Jesus
Published: January 2023

The essential oils (EOs) from bioactive species can provide an alternative tool for the management of stored grain insects that is less environmentally damaging than synthetic chemicals. The aim of this study was to assess the repellent action and toxicity of EOs obtained from phellandrene-rich Lippia origanoides, carvone-rich Lippia alba, citral-rich L. alba, and Pogostemon cablin aerial parts on adults of Ulomoides dermestoides. These EOs were isolated by hydrodistillation and characterized by gas chromatography coupled to mass spectrometry (GC-MS). The repellency assay was carried out using the area preference method, and the toxicity evaluated utilizing a filter paper contact test. The major components (>10%) of the studied EOs were sabinene (16.9%), trans-β-caryophyllene (18.6%) and α-humulene (10.1%) for phellandrene-rich L. origanoides EO; limonene (40.1%) and carvone (37.7%) for carvone-rich L. alba EO; geranial (24.5%), geraniol (19.0%), and neral (11.9%) for citral-rich L. alba EO; and α-guaiene (13.3%), α-bulnesene (15.7%), and patchoulol (35.3%) for P. cablin EO. All EOs displayed 100% repellency at a concentration of 16 μL/mL, with lower toxicity than that elicited by the commercial repellent DEET. EO concentrations up to 8 µL/mL did not induce any mortality on the beetle. These findings show that the EOs provide active and safe molecules for natural repellent formulations to prevent and control insect infestations of stored products.
Qualitative Study on Important Elements of Life for Japanese and Thai Older Adults
Authors: Shimizu Nobuko , Yamada Takako , Honda Nobuyuki , Mochizuki Miyako , Kato Mayumi , Hasegawa Noboru , Sethabouppha Hunsa , Suwankruhasn Nattaya , Suvanayos Chalinee
Published: January 2023

Previous studies have demonstrated relationships between religiosity, physical and mental health-related outcomes, and healthy collective longevity. This qualitative study investigated the elements of pleasure and fulfillment in older adults living in the super-aged society of Japan and the rapidly super-aging society of Thailand. Semi-structured interviews were conducted with 14 older adults—seven from Japan, and seven from Thailand, covering five topics: (1) pleasures in daily life; (2) purpose in daily life; (3) thoughts about aging; (4) things they do actively for their health; and (5) things they worry about. Data were analyzed using the Steps for Coding and Theorization method. Japanese older adults mostly engaged in individually accomplished pleasures, whereas Thai older adults aimed to experience pleasures involving others. Thai older adults viewed aging as a natural phenomenon and stressed the importance of self-regulation. The Japanese participants, however, focused on activities that would avoid the burden of long-term care, maintain their current lifestyle, and help with self-improvement and lifetime learning. Although Thai older adults derived pleasure and fulfillment from being helpful toward others, Japanese older adults’ narratives indicated that they tended to worry about others. Differences between the two countries’ lifestyles, environments, beliefs, and religious contexts explain the differences in the mechanisms by which Japanese and Thai older adults experience joy, fulfillment, and purpose in life. These results suggest ways to improve quality of life, extend healthy life expectancy, and prevent cognitive decline in older adults thriving in aging societies.
Cardiac Structure and Cardiorespiratory Fitness in Young Male Japanese Rugby Athletes
Authors: Iso Yoshitaka , Kitai Hitomi , Ichimori Keiko , Kubota Megumi , Tsujiuchi Miki , Nagumo Sakura , Toshida Tsutomu , Yonechi Toru , Ebato Mio , Suzuki Hiroshi
Published: January 2023

Limited data are available on athlete’s heart for rugby athletes. This study aimed to investigate cardiac structure and its relationship with cardiorespiratory fitness in young Japanese rugby athletes. A prospective cross-sectional study using echocardiography and cardiopulmonary exercise testing (CPET) was conducted on 114 male collegiate rugby players. There was a higher prevalence of increased left ventricular (LV), atrial, and aortic dimensions in the young athletes than that in previously published reports, whereas the wall thickness was within the normal range. Anthropometry and CPET analyses indicated that the forwards and backs presented muscular and endurance phenotypes, respectively. Indexed LV and aortic dimensions were significantly larger in the backs than in the forwards, and the dimensions significantly correlated with oxygen uptake measured by CPET. On the four-tiered classification for LV hypertrophy, abnormal LV geometry was found in 16% of the athletes. Notably, the resting systolic blood pressure was significantly higher in athletes with concentric abnormal geometry than in the other geometry groups, regardless of their field positions. Japanese young athletes may exhibit unique phenotypes of cardiac remodeling in association with their fitness characteristics. The four-tiered LV geometry classification potentially offers information regarding the subclinical cardiovascular risks of young athletes.
Rethinking the Role of the Renin-Angiotensin System in the Pandemic Era of SARS-CoV-2
Authors: Angeli Fabio , Zappa Martina , Verdecchia Paolo
Published: January 2023

After assessing the levels of spread and severity of the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) infection, academic literature focused on the pathophysiology of coronavirus disease 2019 (COVID-19) [...]
Removal of Insertable Cardiac Monitor for Cryptogenic Stroke: A Technical Note
Authors: Egashira Shuhei , Kimura Naoto , Doijiri Ryosuke
Published: January 2023

Objectives: Insertable cardiac monitors (ICM) allow continuous long-term electrocardiogram monitoring and the detection of paroxysmal atrial fibrillation (PAF) in patients with cryptogenic stroke (CS). Several years have passed since ICM was indicated for CS, and many stroke neurologists will experience cases in which ICM removal is required. As a standard protocol, reincision of the wound at the time of implantation has been proposed by ICM brands. However, it may be difficult due to adhesions of subcutaneous tissue, migration of the device from its original position, and the capsule formed around the device. Our objective is to describe simple alternative techniques for successful ICM removal. Materials and Methods: From December 2016 to September 2021, 37 patients with CS underwent ICM removal at our institution. The device was removed through an incision directly above the proximal end of the device, perpendicular to the wound at the time of ICM implantation. The subcutaneous tissue was removed bluntly using forceps along the edges of the proximal end of the device. When a capsule was attached to the device, we cut the capsule with the blade to release the device. Once the device was visible, the proximal end of the device was grasped with forceps, and the device was pulled from the pocket with gentle traction. All patients undergoing ICM removal received a systematic check for wound dehiscence, wound infection, bleeding, and tissue ischemia at an outpatient examination of 1 week. The 37 patients who underwent removal of ICM were retrospectively reviewed in the medical record and analyzed for procedural success, intraoperative complications, and wound course at one week. Results: All patients achieved procedural success. There were no intraoperative complications, wound dehiscence, bleeding, or skin ischemia at one week postoperatively. The reasons for removal were battery depletion in 65%, early removal before battery life after PAF detection in 32%, and exposure to the body surface in 3%. The devices removed were 62% Reveal LINQ (Medtronic, Minneapolis), 30% Confirm Rx (Abbott, Illinois), and 8% BioMonitor 2 (BIOTRONIK, Berlin), indicating that our method is effective regardless of model. Conclusion: We describe a simple technique for ICM removal for CS that is safe, reliable, and potentially effective in wound healing.
Can Lemborexant for Insomnia Prevent Delirium in High-Risk Patients with Pancreato-Biliary Disease after Endoscopic Procedures under Deep Sedation?
Authors: Ogura Takeshi , Ueno Saori , Okuda Atsushi , Nishioka Nobu , Miyano Akira , Yamamoto Yoshitaro , Bessho Kimi , Tomita Mitsuki , Hattori Nobuhiro , Nakamura Junichi , Nishikawa Hiroki
Published: January 2023

Background and aim: Pancreato-biliary patients who undergo endoscopic procedures have high potential risk of delirium. Although benzodiazepine has traditionally been used to treat insomnia, this drug might increase delirium. Lemborexant may be useful for patients with insomnia, without worsening delirium, although there is no evidence for high-risk patients with pancreato-biliary disease. The aim of this pilot study was to evaluate the safety and efficacy of lemborexant for insomnia and the frequency of delirium after endoscopic procedures under deep sedation in patients with pancreato-biliary disease. Method: This retrospective study included consecutive patients who were administered lemborexant after endoscopic procedures for pancreato-biliary disease between September 2020 and June 2022. The primary outcome of this study was evaluation of the safety and efficacy of lemborexant for insomnia. Frequency of delirium was the secondary outcome. Result: In total, 64 patients who had the complication of insomnia after an endoscopic procedure were included in the study. Risk factors for delirium were advanced age (n = 36, 56.3%), dementia (n = 10, 15.6%), and regular alcohol use (n = 13, 20.3%), as well as the sedatives midazolam and pentazocine that were administered to all patients at the time of the endoscopic procedure. Successful asleep was achieved by 61/64 patients (95.3%). No fall event was observed during the night following the procedure in any patient. However, mild consciousness transformation was observed in one patient. Conclusions: In conclusion, lemborexant use may be effective and safe for use after endoscopic procedures in pancreato-biliary patients, without increasing the risk of delirium.
The Ongoing Evolution of Abdominal Aortic Surgery
Authors: Oikonomou Kyriakos , Zimmler Carla Isabell
Published: January 2023

Abdominal aortic surgery has witnessed significant paradigm shifts in recent years with the introduction of structured screening programs, as well as the evolution of endovascular aortic aneurysm repair (EVAR), which has allowed physicians to promptly identify and successfully treat an increasing number of patients, even including those previously considered unfit for open repair [...]
Influence of Thermal and Thermomechanical Stimuli on Dental Restoration Geometry and Material Properties of Cervical Restoration: A 3D Finite Element Analysis
Authors: Sharma Uppangala Rohan , Pai Swathi , Patil Vathsala , Smriti Komal , Naik Nithesh , Shetty Raviraj , Gunasekar Pranesh , Jain Amritanshu , Tirupathi Jeswanthi , Hiremath Pavan , Patil Santosh , Rathnakar Rashmitha
Published: January 2023

Cervical restoration of a premolar tooth is a challenging task as it involves structural modification to ensure the functional integrity of the tooth. The lack of retention in the cervical area, with the cavity margins on dentin and the nonavailability of enamel, makes it challenging for restoration. The high organic content of dentin, along with its tubular structure and outward flow of fluid, make dentin bonding difficult to attain. The objective of this study is to evaluate the impact of thermal and thermomechanical stimuli on the geometry of dental restorations in the cervical region. In the present study, a three-layered restorative material made of glass ionomer cement, hybrid layer, and composite resin is considered by varying the thickness of each layer. Group 1 of elliptical-shaped cavities generates von Mises stress of about 14.65 MPa (5 °C), 41.84 MPa (55 °C), 14.83 MPa (5 °C and 140 N), and 28.89 MPa (55 °C and 140 N), respectively, while the trapezoidal cavity showed higher stress of 36.27 MPa (5 °C), 74.44 MPa (55 °C), 34.14 MPa (5 °C and 140 N), and 75.57 MPa (55 °C and 140 N), which is comparable to the elliptical cavity. The result obtained from the analysis helps to identify the deformation and volume change that occurs due to various real-time conditions, such as temperature difference and thermal stress. The study provides insight into the behavior of novel restorative materials of varied thicknesses and temperature levels through simulation.
Bioactive Glass-Ceramic Scaffolds Coated with Hyaluronic Acid–Fatty Acid Conjugates: A Feasibility Study
Authors: De Luca Stefania , Verdoliva Valentina , Kargozar Saeid , Baino Francesco
Published: January 2023

Promoting bone healing is a key challenge in our society that can be tackled by developing new implantable biomaterials provided with regenerative properties. In this work, the coating of three-dimensional porous glass-derived scaffolds with hyaluronic acid (HA)-fatty acids was investigated for the first time. The starting scaffolds, based on bioactive silicate glass, were produced by foam replication followed by sintering; then, HA-palmitate and HA-oleate conjugate coatings were deposited on the scaffold struts through a dipping procedure. FT-IR analysis confirmed the successful deposition of the coatings on the surface and struts of the scaffolds, the foam-like architecture of which was maintained as assessed by SEM investigations. The in vitro bioactivity of the HA–fatty-acid-coated scaffolds was studied by immersion tests in simulated body fluid and the subsequent evaluation of hydroxyapatite formation. The deposition of the polymeric coating did not inhibit the apatite-forming ability of scaffolds, as revealed by the formation of nanostructured hydroxyapatite agglomerates 48 h from immersion. These promising results motivate further investigation of these novel bioactive systems, which are expected to combine the bone-bonding properties of the glass with the wound-healing promotion carried out by the polymeric conjugates.
Acute Wheel-Running Increases Markers of Stress and Aversion-Related Signaling in the Basolateral Amygdala of Male Rats
Authors: Grigsby Kolter B. , Kerr Nathan R. , Kelty Taylor J. , Mao Xuansong , Childs Thomas E. , Booth Frank W.
Published: January 2023

Physical activity (PA) is a non-invasive, cost-effective means of reducing chronic disease. Most US citizens fail to meet PA guidelines, and individuals experiencing chronic stress are less likely to be physically active. To better understand the barriers to maintaining active lifestyles, we sought to determine the extent to which short- versus long-term PA increases stress- and aversion-related markers in wild-type (WT) and low voluntary running (LVR) rats, a unique genetic model of low physical activity motivation. Here, we tested the effects of 1 and 4 weeks of voluntary wheel-running on physiological, behavioral, and molecular measures of stress and Hypothalamic Pituitary Adrenal (HPA)-axis responsiveness (corticosterone levels, adrenal wet weights, and fecal boli counts). We further determined measures of aversion-related signaling (kappa opioid receptor, dynorphin, and corticotropin releasing hormone mRNA expression) in the basolateral amygdala (BLA), a brain region well characterized for its role in anxiety and aversion. Compared to sedentary values, 1, but not 4 weeks of voluntary wheel-running increased adrenal wet weights and plasma corticosterone levels, suggesting that HPA responsiveness normalizes following long-term PA. BLA mRNA expression of prodynorphin (Pdyn) was significantly elevated in WT and LVR rats following 1 week of wheel-running compared to sedentary levels, suggesting that aversion-related signaling is elevated following short- but not long-term wheel-running. In all, it appears that the stress effects of acute PA may increase molecular markers associated with aversion in the BLA, and that LVR rats may be more sensitive to these effects, providing a potential neural mechanism for their low PA motivation.
Computer Vision and Robotics for Cultural Heritage: Theory and Applications
Authors: Caron Guillaume , Bellon Olga Regina Pereira , Shimshoni Ilan
Published: January 2023

Computer vision and robotics are more and more involved in cultural heritage [...]
Visualization and Cybersecurity in the Metaverse: A Survey
Authors: Chow Yang-Wai , Susilo Willy , Li Yannan , Li Nan , Nguyen Chau
Published: January 2023

The popularity of the Metaverse has rapidly increased in recent years. However, despite the attention, investment, and promise of the Metaverse, there are various cybersecurity issues that must be addressed before the Metaverse can truly be adopted in practice for serious applications. The realization of the Metaverse is envisioned by many as requiring the use of visualization technologies such as Virtual Reality (VR) and Augmented Reality (AR). This visual aspect of the Metaverse will undoubtedly give rise to emerging cybersecurity threats that have not received much attention. As such, the purpose of this survey is to investigate cybersecurity threats faced by the Metaverse in relation to visualization technologies. Furthermore, this paper discusses existing work and open research directions on the development of countermeasures against such threats. As the Metaverse is a multidisciplinary topic, the intention of this work is to provide a background of the field to aid researchers in related areas.
Material Behavior around the FSW/FSP Tool Described by Molecular Dynamics
Authors: Medina Bentejui , Fernández Ricardo
Published: January 2023

Friction stir welding and processing (FSW/FSP) involves severe plastic deformation of metals or polymers at high temperature around a rotating tool. The material’s flow is usually modelled by FEM using a complex combination of thermomechanical and friction models. However, the description of the behavior of the first atomic layers in contact with the tool cannot be undertaken by continuum mechanics modelling such as FEM. Among the available simulation techniques, molecular dynamics (MD) where friction and heat are generated by material layers’ relative movement, allows the simulation of the behavior of the first atomic layers of the work piece in contact with the tool. In this work, in aluminum, the effect of temperature and advancing and rotating speeds on FSW/FSP material’s flow and crystallography in the vicinity of the tool are discussed. The data analyzed demonstrate that a normalization of the weld-pitch parameter by the pin radius allows obtaining reliable heat input, momentum, and temperatures typical of this critical region in the FSW/FSP processes by MD. The results show that MD provide reliable data as an input for the FEM in a multiscale FSW/FSP modelling.
Friction Resistance of Uncured Carbon/Epoxy Prepregs under Thermoforming Process Conditions: Experiments and Modelling
Authors: Aveiga David , Gómez David , Mocerino Davide , López-Romano Bernardo , González Carlos
Published: January 2023

The numerous prepreg characteristics benefit industries like the aerospace and automotive ones, producing a wide range of high-performance components for primary or secondary applications. Parts production is usually assisted by a thermoforming process in which the prepreg is heated and reshaped employing a moulding system. The ply-ply and ply-tool sliding behaviours in the Thermoforming govern the defects generation, such as wrinkles, making its study a crucial step. This work analyses ply-ply and ply-tool friction coefficients for UD AS4/8552 Carbon/Epoxy prepreg. A pull-out test method was employed to determine the friction coefficients at different velocities, pressures, and temperatures related to the thermoforming process conditions, supplying a detalied report of friction parameters and mechanisms. The measurements of the interlaminar resin layer thickness and the surface roughness geometry resulted respectively in a range of 11–14 μm and 3–4 μm were taken into account in the Lubrication Theory approach to developing an analytical model. Based on the Stribeck curve and Reynolds equation for a viscous fluid, the developed model accurately predicts friction coefficients for prepreg composite materials in the process and contact conditions mentioned below.
Powder Bed Fusion of Multimaterials
Authors: Dzogbewu Thywill Cephas , de Beer Deon
Published: January 2023

Powder bed fusion (PBF) process has been used successfully to produce 3D structures using single material properties. The current industrial demand is to use the technology to produce 3D structures of multimaterial properties. An electron beam melting (EBM) process has been used to produce 3D structures of multimaterial properties. However, due to the large beam size, the EBM process lacks geometrical accuracy, requiring a large machining allowance. A laser powder bed fusion (LPBF) process could be used to produce multimaterials with geometrical precision. However, the thermal gradient within the molten pool and the thermophysical difference between the multimaterials leads to defects (weak interfacial bonds, interlayer and intralayer cracks). Other challenges such as poor powder delivery system, powder cross-contamination, and lack of appropriate data processing software for producing 3D multimaterial structures are not yet fully resolved. Nonetheless, there have been encouraging results for producing the next generational multimaterial 3D components of intricate geometrical characteristics.
Approach for Installation and Logistics of a Floating Offshore Wind Farm
Authors: Díaz Hugo , Guedes Soares C.
Published: January 2023

An approach is developed for floating wind farm installation by creating a model that allows the planning of the main logistics and installation aspects of a floating wind farm. The method aims to preserve the coherency between logistic methods and project performance, as floating wind farm installation is a complex problem, due to the number of components that impose specific constraints in areas such as transportation and manufacturing. The planning tool is developed based on the knowledge about how to use the various approaches and on the analysis of different logistical solutions. A techno-economic view of the logistics and installation involved in the floating wind farm design is the main objective of this study. A case study for the CENTEC TLP concept implemented in Spanish and Irish waters is performed. Case study findings reveal the major aspects that affect the design and logistics factors. The tool is developed for the main types of floating wind platforms and is applicable for the preliminary design of wind farms worldwide. The tool suggests a strategy of design and logistic aspects dependent on a few inputs such as the number of components for installation, distances and the maximum number of turbines. These findings are especially important for the new floating wind farms being positioned further offshore.
4D Seismic Monitoring with Diffraction-Angle-Filtering for Carbon Capture and Storage (CCS)
Authors: Shin Youngjae , Ji Hyeong-Geun , Park Sea-Eun , Oh Ju-Won
Published: January 2023

Carbon capture and storage (CCS) is a key technology that directly removes industry driven CO2 to achieve carbon neutrality. In the process of CCS, it is necessary to monitor whether injected CO2 is properly stored and not leaking. The behavior of CO2 can be investigated using a 4D seismic survey that compares seismic data before and after injection. We proposed a two-step monitoring with diffraction-angle filtering (DAF) to effectively locate the CO2 plume. Because DAF allows us to control wavenumber components, the gradient of full-waveform inversion (FWI), which is the first step, is composed of low-wavenumber components, and reverse time migration (RTM) for seismic imaging is carried out with high-wavelength components. To verify our method, we implemented FWI and RTM with and without DAF using the velocity model in the Volve oil field in the North Sea. Numerical examples show that the CO2 plume is properly detected from the difference between baseline and post-injected survey and the extension of the reflective boundary is improved compared to the results of the conventional method. With our proposed method, local minima problem is mitigated in FWI, and the boundaries between layers can be clearly distinguished in RTM.
Vibration-Resistant Performance Study of a Novel Floating Wind Turbine with Double-Rope Mooring System and Stroke-Limited TMD
Authors: Feng Zhouquan , Huang Yuheng , Hua Xugang , Dai Jinyuan , Jing Haokun
Published: January 2023

Floating offshore wind turbines (FOWTs) are generally located in the harsh deep-sea environment and are highly susceptible to extreme loads. In order to ensure the normal operation of FOWTs, this article takes the semi-submersible FOWT as an example, proposes a new double-rope mooring system, and studies the dynamic performance of the FOWT with the double-rope mooring system and its effectiveness in reducing the dynamic response of the wind turbine. At the same time, the tuned mass damper (TMD) is installed in the nacelle of the wind turbine, and the TMD parameters are optimized considering the space limitation of the nacelle by limiting the TMD’s stroke, which further reduces the dynamic response of the FOWT and improves its stability. Numerical simulation and analytical studies show that the new double-rope mooring system can reduce the dynamic response of the wind turbine to a greater extent than the traditional single-rope mooring system. Considering the stroke restriction, the control performance of TMD will be slightly weakened, but it is more in line with the actual engineering requirements. Compared with the original FOWT, the proposed new type of FOWT has better dynamic stability and has the prospect of extending to real engineering applications.
The Feasibility of the ERA5 Forced Numerical Wave Model in Fetch-Limited Basins
Authors: Bujak Damjan , Lončar Goran , Carević Dalibor , Kulić Tin
Published: January 2023

Numerical wave models are critical in hindcasting reliable long-term time series of significant wave heights, which play a crucial role in coastal and ocean engineering activities. Although wind fields are an important input to numerical wave models, few studies have investigated the feasibility of the widely used ERA5 wind reanalysis dataset in fetch-limited basins. In this work, we investigated the feasibility of the ERA5 forced numerical wave model (SWAN) in fetch-limited basins. ERA5 wind velocities were first compared to ground-based meteorological stations, showing poorer accuracy compared to finer gridded ALADIN wind data. Subsequently, the white-capping coefficient Cds in the Janssen white-capping formulation was calibrated separately using a surrogate model when establishing the ERA5 and ALADIN forced wave models. The calibrated ERA5 forced model showed a similar agreement to wave buoy data as the calibrated ALADIN forced wave model during the calibration period and even superior accuracy in the validation period. Overall, these results show that the wave model calibration procedure mitigates the effect of the poorer accuracy of the ERA5 wind data on the significant wave height results. Nevertheless, both ERA5 and ALADIN forced wave models showed an alarming overprediction for high simulated significant wave heights.
Numerical Investigation on Hydrodynamic Processes of Extreme Wave Groups on Fringing Reef
Authors: Qu Ke , Men Jia , Wang Xu , Li Xiaohan
Published: January 2023

The low-lying reef islands distributed in the tropical and subtropical coastal regions are highly vulnerable to the devastating damages of surges and waves during the severe weather events. Over the past two decades, extreme waves have caused tremendous loss and damages to the tropical and subtropical coastal regions. Previous research has focused on the wave hydrodynamics of tsunami waves, as well as regular and irregular waves on the fringing reefs. The complex wave hydrodynamics of extreme waves on the fringing reefs are rarely studied. By applying the nonhydrostatic numerical flow solver (NHWAVE), transformation and breaking process of the crest- and trough-focused wave groups on the fringing reef are analyzed in this study. Influences of the major factors, i.e., water depth, significant wave height, peak wave period, forereef slope and backreef slope, and ridge width, are discussed in detail. The results show that there are complex interactions between the fringing reef and the focused wave group. Breaking waves of high intensity can form at the reef crest. Meanwhile, due to the wave breakings at the reef crest and bottom friction of the reef flat, the local wave height can be effectively reduced. Within the complex wave hydrodynamics of focused waves on the fringing reef, most of the wave energy can be dissipated. In addition, hydrodynamic difference between the crest- and trough-focused waves on the fringing reef is very limited. The research results of this study will further help researchers to better understand the wave hydrodynamics of extreme waves over the fringing reefs.
Morphological Characteristics and Molecular Evidence Reveal four New Species of Russula subg. Brevipedum from China
Authors: Chen Yanliu , An Mengya , Liang Jingying , Li Weijie , Deng Chunying , Wang Jing , Li Yangkun , Liang Junfeng
Published: January 2023

In this study, four new species of Russula subg. Brevipedum collected from China are described based on morphological characteristics and molecular evidence. Russula brevispora has a white body whose whole parts often stain brownish-orange or grayish-orange, extremely crowded lamellae with the presence of lamellulae, basidiospores with low warts and an inamyloid suprahilar spot, and clavate or lageniform hymenial cystidia often with a papillary or submoniliform appendage. Russula flavescens is characterized by a white pileus often turning yellowish brown when touched, white lamellae turning brown or light orange, basidiospores with an inamyloid suprahilar spot, and fusiform hymenial cystidia often with an appendage. Russula longicollis is morphologically characterized by a white pileus, turning grayish orange when bruised, white lamellae turning pale yellow when bruised, basidiospores with isolated warts and an amyloid suprahilar spot, and fusiform hymenial cystidia usually with a long appendage. Russula pseudojaponica has a yellowish-brown pileus center, yellowish lamellae unchanging when bruised, basidiospores with low warts and an inamyloid suprahilar spot, clavate hymenial cystidia often with a papillary appendage, and clavate pileocystidia with granulose contents. Phylogenetic analyses showed that R. flavescens, R. brevispora, and R. pseudojaponica are members of the subsect. Pallidosporinae, whereas R. longicollis belongs to subsect. Lactarioideae, and is somewhat related to R. leucocarpa.
Innovation Output and Idiosyncratic Volatility: US Evidence
Authors: Alshammasi Naji Mohammad , Almomen Adel Abdulkarim
Published: January 2023

Firms engaging in innovative practices have patents to prevent competitive forces from eroding the resulting economic rents; however, there is limited evidence regarding the impact of innovation on risk. We shed new light on how firms’ involvement in innovation activities impacts their volatility, particularly their idiosyncratic volatility. In this paper, we empirically examine the effect of innovation on idiosyncratic volatility. To do so, we empirically examine the impact of innovation, measured by patents weighted by citations and R&D expenditure, on the idiosyncratic volatility of firms. Using a large sample of 8256 US firms, we find that more innovation is associated with lower idiosyncratic volatility. We also find that information uncertainty is the channel through which innovation affects idiosyncratic risk. The results are robust for different measures of idiosyncratic volatility. These results have empirical implications for investors, managers, and firms engaging in innovation-related activities.
The Effect of COVID-19 on Cryptocurrencies and the Stock Market Volatility: A Two-Stage DCC-EGARCH Model Analysis
Authors: Ampountolas Apostolos
Published: January 2023

This research examines the correlations between the return volatility of cryptocurrencies, global stock market indices, and the spillover effects of the COVID-19 pandemic. For this purpose, we employed a two-stage multivariate volatility exponential GARCH (EGARCH) model with an integrated dynamic conditional correlation (DCC) approach to measure the impact on the financial portfolio returns from 2019 to 2020. Moreover, we used value-at-risk (VaR) and value-at-risk measurements based on the Cornish–Fisher expansion (CFVaR). The empirical results show significant long- and short-term spillover effects. The two-stage multivariate EGARCH model’s results show that the conditional volatilities of both asset portfolios surge more after positive news and respond well to previous shocks. As a result, financial assets have low unconditional volatility and the lowest risk when there are no external interruptions. Despite the financial assets’ sensitivity to shocks, they exhibit some resistance to fluctuations in market confidence. The VaR performance comparison results with the assets portfolios differ. During the COVID-19 outbreak, the Dow (DJI) index reports VaR’s highest loss, followed by the S&P500. Conversely, the CFVaR reports negative risk results for the entire cryptocurrency portfolio during the pandemic, except for the Ethereum (ETH).
How Do State-Owned and Private-Owned CVC Differ in Nurturing Innovation in China?
Authors: Gao Xiang , Shi Guoping , Wu Yige , Zhang Luming
Published: January 2023

We investigate how state-owned corporate venture capital differs from privately owned corporate venture capital in fostering innovation among startups. Based on the data of Chinese A-share listed companies and the startups in their portfolios that they invested in between 2009 and 2018, we find that startups backed by state-owned corporate venture capital are less innovative than startups backed by privately owned corporate venture capital. Using a two-stage least-squares analysis yields the same results. Further, we find evidence consistent with two potential mechanisms: Investors of state-owned corporate venture capital provide weaker technical support and are less tolerant of failure. These results have important implications for stakeholders, management, and policy makers who care about incentivizing young and rapidly growing companies to innovate more effectively.
Model of Priority Ranking of Cadastral Parcels for Planning the Implementation of Urban Consolidation
Authors: Kilić Pamuković Jelena , Rogulj Katarina , Jajac Nikša , Mastelić-Ivić Siniša
Published: January 2023

The paper proposes a Model of priority ranking of cadastral parcels for planning the implementation of urban consolidation, which is a continuation of the published research on the assessment of fragmentation and assessment bonitet values of cadastral parcels. The research deals with one segment of the Spatial Decision Support System and is one process in the planning of urban consolidation. Comparison criteria were identified for the evaluation and priority ranking of cadastral parcels. The subject of the research is private cadastral parcels in the area of large public project construction. The goal of the research is to find the optimal way to compare conflicting and incomparable criteria for the evaluation of private cadastral parcels and, at the same time, a way of fitting the opinions of stakeholders in the implementation planning process of urban consolidation. Due to the complexity of the task and realizing certain spatial criteria, unique models were developed. Special attention was paid to the participatory approach to problem-solving, in which all groups of stakeholders were identified, and the way of expressing their views was defined. The Complex proportional assessment (COPRAS) method and the Analytic Hierarchy Process method (AHP) methods were used to solve the problem. The defined models were tested in the field of construction of a large public project Campus at the University of Split.
Recent Advances in Research on Island Phenomena
Authors: Nyvad Anne Mette , Christensen Ken Ramshøj
Published: January 2023

In natural languages, syntactic elements can, in principle, be linked across an unbounded distance, as exemplified by filler-gap dependencies (also known as extractions or movement operations) [...]
Evaluation of CBR of Graded Crushed Stone of Flexible Base Structural Layer Based on Discrete Element Model
Authors: Hu Zhaoguang , Liu Heng , Zhang Weiguang , Hei Tianqing , Ding Xunhao , Dong Zezhen
Published: January 2023

In order to study the mechanical properties of graded crushed stone, the discrete element method is used to simulate the CBR test of graded crushed stone. Aiming at the composition structure of graded crushed stone material, the PFC3D simulation software is used to construct the test model, and the process of constructing the virtual specimen model of the graded crushed stone discrete element model is discussed in detail. A servo mechanism is used to control the speed of the wall in the software, so as to control the virtual confining pressure imposed on graded crushed stone by the wall and simulate the real CBR test environment. The micro-parameter calibration of the virtual test is carried out by comparing the indoor and virtual CBR specimens of a single particle size specimen and three groups of graded crushed stone specimens. The comparison result shows that the stress–strain characteristics of the graded crushed rock obtained by the discrete element simulation during the uniaxial penetration process have a high degree of similarity, which can verify the accuracy of the model establishment. With the increase in the penetration depth, the penetration force of the aggregates of various particle sizes gradually increases, and the penetration force and the penetration depth are basically linear, and when the particle size is greater than 9.5 mm, the increase in particle size has little effect on the CBR test results. Under the certain conditions, the contact stiffness of graded crushed stone particles with particle sizes of 4.75 mm, 9.5 mm, 13.2 mm, 16 mm, and 19 mm should be 0.88 × 107 (N/m), 0.98 × 107 (N/m), 1.10 × 107 (N/m), 1.25 × 107 (N/m), and 2.05 × 107 (N/m), respectively. The recommended value of the contact stiffness of the small spherical particles increases with the increase in the particle size. This model can provide a basis for studying the micromechanical state of graded crushed stone and physical mechanics tests.
Integration of Carbon Dots on Nanoflower Structured ZnCdS as a Cocatalyst for Photocatalytic Degradation
Authors: Zhou Jie , Zhao Xin , Xu Haoming , Wang Zhichao , Zhang Xiaoyuan , Su Zhiqiang
Published: January 2023

The application of catalysts is one of the most effective methods in the oil refining, chemical, medical, environmental protection, and other industries. In this work, carbon dots (CDs) were selected as an initiator and doped into the main catalyst, Zn0.2Cd0.8S, and a novel Zn0.2Cd0.8S@CD composite catalyst with a nanoflower structure was successfully obtained. The synthesized composites (Zn0.2Cd0.8S@CDs) were characterized by means of SEM, TEM, XRD, FT-IR, XPS, and UV-Vis DRS. Transient photocurrent response and Nyquist curve analysis further proved that the carrier separation efficiency of the composite catalyst was significantly improved. In addition, the photocatalytic activity of Zn0.2Cd0.8S@CDs for rhodamine B removal from aqueous solution was tested under visible-light irradiation. When the amount of Zn0.2Cd0.8S@CDs composite catalyst reached 50 mg, the degradation rate of rhodamine B was 79.35%. Finally, the photocatalytic degradation mechanism of the Zn0.2Cd0.8S@CDs complex was studied. CD doping enhances the adsorption capacity of Zn0.2Cd0.8S@CDs composite catalysts due to the increase in surface area, effectively inducing charge delocalization and enhancing the photocatalytic capacity. Zn0.2Cd0.8S@CDs composites with low cost and high carrier separation efficiency have broad application prospects in the photocatalytic degradation of dyes.
Thermal Expansion and Rattling Behavior of Gd-Filled Co4Sb12 Skutterudite Determined by High-Resolution Synchrotron X-ray Diffraction
Authors: Rodrigues João E. F. S. , Gainza Javier , Serrano-Sánchez Federico , Silva Romualdo S. , Dejoie Catherine , Nemes Norbert M. , Dura Oscar J. , Martínez José L. , Alonso José Antonio
Published: January 2023

In this work, Gd-filled skutterudite GdxCo4Sb12 was prepared using one step method under high pressure in a piston-cylinder-based press at 3.5 GPa and moderate temperature of 800 °C. A detailed structural characterization was performed using synchrotron X-ray diffraction (SXRD), revealing a filling fraction of x = 0.033(2) and an average  bond length of 3.3499(3) Å. The lattice thermal expansion accessed via temperature-dependent SXRD led to a precise determination of a Debye temperature of 322(3) K, from the fitting of the unit-cell volume expansion using the second order Grüneisen approximation. This parameter, when evaluated through the mean square displacements of Co and Sb, displayed a value of 265(2) K, meaning that the application of the harmonic Debye theory underestimates the Debye temperature in skutterudites. Regarding the Gd atom, its intrinsic disorder value was ~5× and ~25× higher than those of the Co and Sb, respectively, denoting that Gd has a strong rattling behavior with an Einstein temperature of θE = 67(2) K. As a result, an ultra-low thermal conductivity of 0.89 W/m·K at 773 K was obtained, leading to a thermoelectric efficiency zT of 0.5 at 673 K.