bluuebunny/crossref_metadata_2025 huggingface dataset:
Online Monitoring Technology of Metal Powder Bed Fusion Processes: A Review
Authors: Hou Zhuo-Jun , Wang Qing , Zhao Chen-Guang , Zheng Jun , Tian Ju-Mei , Ge Xiao-Hong , Liu Yuan-Gang
Published: October 2022

Metal powder bed fusion (PBF) is an advanced metal additive manufacturing (AM) technology. Compared with traditional manufacturing techniques, PBF has a higher degree of design freedom. Currently, although PBF has received extensive attention in fields with high–quality standards such as aerospace and automotive, there are some disadvantages, namely poor process quality and insufficient stability, which make it difficult to apply the technology to the manufacture of critical components. In order to surmount these limitations, it is necessary to monitor the process. Online monitoring technology can detect defects in time and provide certain feedback control, so it can greatly enhance the stability of the process, thereby ensuring its quality of the process. This paper presents the current status of online monitoring technology of the metal PBF process from the aspects of powder recoating monitoring, powder bed inspection, building process monitoring, and melt layer detection. Some of the current limitations and future trends are then highlighted. The combination of these four–part monitoring methods can make the quality of PBF parts highly assured. We unanimously believe that this article can be helpful for future research on PBF process monitoring.
Dynamic Deformation Behavior and Fracture Characteristics of a near α TA31 Titanium Alloy at High Strain Rates
Authors: Yu Weixin , Li Xiaofen , Zhang Jinyong , Hou Shusen , Lv Yifan
Published: October 2022

The quasi-static and dynamic impact compression tests of the TA31 titanium alloy were conducted at the strain rates from 0.001 s−1 to 4000 s−1 and deformation temperatures from 293 K to 773 K, and the TA31 titanium alloy showed typical elastic-plastic characteristics. In the initial stage of compression (elastic deformation), the stress and strain are proportional, and the stress–strain curve is a straight line. In the plastic deformation stage, the flow stress decreases significantly with the increase of deformation temperature, while the strain rate has no significant effect on the flow stress during dynamic compression. A constitutive model has been established to predict the flow stress, and the relative error is 2.32%. It is shown by observing the microstructure that when the deformation temperature is 293 °C, and the strain rate reaches 1600 s−1, a shear band with an angle of about 45° to the axial direction of the specimen appears, and the severe shear deformation makes the α phase in the shear band fibrous and contains high-density dislocations. The formation process of the shear band and its influence on fracture are analyzed and discussed.
Preparation and Characteristics of Na2HPO4·12H2O-K2HPO4·3H2O/SiO2 Composite Phase Change Materials for Thermal Energy Storage
Authors: Ye Rongda , Wang Jun , Li Yanna , Sun Wanchun , Huang Qizhang , Gong Sheng , Shu Xugang
Published: October 2022

In this paper, a series of eutectic hydrated salts was obtained by mixing Na2HPO4·12H2O (DHPD) with K2HPO4·3H2O (DHPT) in different proportions. With the increase in the content of DHPT, the phase transition temperature and melting enthalpy of eutectic hydrated salts decreased gradually. Moreover, the addition of appropriate deionized water improved the thermal properties of eutectic hydrated salts. Colloidal silicon dioxide (SiO2) was selected as the support carrier to adsorb eutectic hydrated salts, and the maximum content of eutectic hydrated salts in composite PCMs was 70%. When the content of the nucleating agent (Na2SiO3·9H2O) was 5%, the supercooling degree of composite PCMs was reduced to the minimum of 1.2 °C. The SEM and FT-IR test results showed that SiO2 and eutectic hydrated salts were successfully combined, and no new substances were formed. When the content of DHPT was 3%, the phase transition temperature and melting enthalpy of composite PCMs were 26.5 °C and 145.3 J/g, respectively. The results of thermogravimetric analysis and heating–cooling cycling test proved that composite PCMs had good thermal reliability and stability. The application performance of composite PCMs in prefabricated temporary houses was investigated numerically. The results indicated that PCM panels greatly increased the Grade I thermal comfort hours and reduced energy consumption. Overall, the composite PCM has great development potential building energy conservation.
Development and Characterization of Phosphate Glass Fibers and Their Application in the Reinforcement of Polyester Matrix Composites
Authors: Saloumi Nezha , Daki Iliass , El Bouchti Mehdi , Oumam Mina , Manoun Bouchaib , Yousfi Mohamed , Hannache Hassan , Cherkaoui Omar
Published: October 2022

This study focused on the production and characterization of phosphate glass fibers (PGF) for application as composite reinforcement. Phosphate glasses belonging to the system 52P2O524CaO13MgO (11-(X + Y)) K2OXFe2O3YTiO2 (X:1, 3, 5) and (Y:0.5, 1) were elaborated and converted to phosphate glass fibers. First, their mechanical properties and chemical durability were investigated. Then, the optimized PGF compositions were used afterward as reinforcement for thermosetting composite materials. Polyester matrices reinforced with short phosphate glass fibers (sPGF) up to 20 wt % were manufactured by the contact molding process. The mechanical and morphological properties of different sPGF-reinforced polyester systems were evaluated. The choice between the different phosphate-based glass syntheses (PGFs) was determined by their superior mechanical performance, their interesting chemical durability, and their high level of dispersion in the polyester matrix without any ad sizing as proven by SEM morphological analysis. Moreover, the characterization of mechanical properties revealed that the tensile and flexural moduli of the developed polyester-based composites were improved by increasing the sPGF content in the polymer matrix in perfect agreement with Takayanagi model predictions. The present work thus highlights some promising results to obtain high-quality phosphate glass fiber-reinforced polyester parts which can be transposed to other thermosetting or thermoplastic-based composites for high-value applications.
Effect of Sintering Temperature and Iron Addition on Properties and Microstructure of High Speed Steel Based Materials Produced by Spark Plasma Sintering Method
Authors: Madej Marcin , Leszczyńska-Madej Beata , Garbiec Dariusz
Published: October 2022

Attempts were made to describe the effect of the sintering temperature and pure iron powder addition on the properties of HSS-based materials produced by the spark plasma sintering method (SPS). After sintering, their density, hardness, flexural strength, and tribological properties were determined. The sintered materials were also subjected to microstructural analysis to determine the phenomena occurring at the particle contact boundaries during sintering. On the basis of analysis of the obtained results, it was found that the mechanical properties and microstructure were mainly influenced by the sintering temperature, which was selected in relation to the previously tested steel M3/2, adjusted upwards due to its chemical composition. The use of the temperature of 1050 °C allows materials to be obtained with a density close to the theoretical density (97%), characterized by a high hardness of about 360 HB. The addition of iron slightly reduces the hardness and also increases the flexural strength to 577 MPa. There was no diffusion of the alloying elements from the steel to the iron due to the short time of exposure to the sintering temperature.
An Enhanced Bounding Surface Model for Modelling Various Cyclic Behaviour of Clay
Authors: Wang Junxiang , Xotta Giovanna , De Marchi Nico , Salomoni Valentina
Published: October 2022

Many results from cyclic triaxial experiments indicate that porous media, such as clays, exhibit various long-term behaviours under different cyclic stress ratios (CSRs). These can be classified into three main categories, namely, cyclic shakedown, cyclic stable and cyclic failure. Modelling these soil deformation responses, along with pore pressure and other fundamental cyclic aspects, such as closed hysteresis cycles and degradation, is still an open challenge, and research to date is limited. In order to properly describe and capture these characteristics, an enhanced plasticity model, based on the bounding surface and stress distance concepts, is developed here. In detail, a new uniform interpolation function of the plastic modulus, suitable for all loading stages, is proposed, and a new damage factor associated with the plastic shear strain and the deformation type parameter, is also incorporated into the plastic modulus. Accordingly, cyclic shakedown and cyclic failure can be distinguished, and degradation is achieved. Closed hysteresis loops, typical of clays, are obtained through a radial mapping rule along with a moving projection centre, located by the stress reversal points. Comparisons between the obtained numerical results and the experimental ones from literature confirm the suitability of the constitutive approach, which is capable of correctly capturing and reproducing the key aspects of clays’ cyclic behaviour.
Femtosecond Laser Fabrication of Anisotropic Structures in Phosphorus- and Boron-Doped Amorphous Silicon Films
Authors: Shuleiko Dmitrii , Zabotnov Stanislav , Martyshov Mikhail , Amasev Dmitrii , Presnov Denis , Nesterov Vyacheslav , Golovan Leonid , Kashkarov Pavel
Published: October 2022

Femtosecond laser-modified amorphous silicon (a-Si) films with optical and electrical anisotropy have perspective polarization-sensitive applications in optics, photovoltaics, and sensors. We demonstrate the formation of one-dimensional femtosecond laser-induced periodic surface structures (LIPSS) on the surface of phosphorus- (n-a-Si) and boron-doped (p-a-Si) amorphous silicon films. The LIPSS are orthogonal to the laser polarization, and their period decreases from 1.1 ± 0.1 µm to 0.84 ± 0.07 µm for p-a-Si and from 1.06 ± 0.03 to 0.98 ± 0.01 for n-a-Si when the number of laser pulses per unit area increases from 30 to 120. Raman spectra analysis indicates nonuniform nanocrystallization of the irradiated films, with the nanocrystalline Si phase volume fraction decreasing with depth from ~80 to ~40% for p-a-Si and from ~20 to ~10% for n-a-Si. LIPSS’ depolarizing effect, excessive ablation of the film between LIPSS ridges, as well as anisotropic crystalline phase distribution within the film lead to the emergence of conductivity anisotropy of up to 1 order for irradiated films. Current–voltage characteristic nonlinearity observed for modified p-a-Si samples may be associated with the presence of both the crystalline and amorphous phases, resulting in the formation of potential barriers for the in-plane carrier transport and Schottky barriers at the electric contacts.
Investigating the Effect of Tube Diameter on the Performance of a Hybrid Photovoltaic–Thermal System Based on Phase Change Materials and Nanofluids
Authors: Alqaed Saeed , Mustafa Jawed , Almehmadi Fahad Awjah , Alharthi Mathkar A. , Sharifpur Mohsen , Cheraghian Goshtasp
Published: October 2022

The finite element (FEM) approach is used in this study to model the laminar flow of an eco-friendly nanofluid (NF) within three pipes in a solar system. A solar panel and a supporting phase change material (PCM) that three pipelines flowed through made up the solar system. An organic, eco-friendly PCM was employed. Several fins were used on the pipes, and the NF temperature and panel temperature were measured at different flow rates. To model the NF flow, a two-phase mixture was used. As a direct consequence of the flow rate being raised by a factor of two, the maximum temperature of the panel dropped by 1.85 °C, and the average temperature dropped by 1.82 °C. As the flow rate increased, the temperature of the output flow dropped by up to 2 °C. At flow rates ranging from low to medium to high, the PCM melted completely in a short amount of time; however, at high flow rates, a portion of the PCM remained non-melted surrounding the pipes. An increase in the NF flow rate had a variable effect on the heat transfer (HTR) coefficient.
Surface Properties and In Vitro Corrosion Studies of Blasted and Thermally Treated Ti6Al4V Alloy for Bioimplant Applications
Authors: Hussein Mohamed A. , Demir Baha Y. , Kumar Arumugam Madhan , Abdelaal Ahmed F.
Published: October 2022

The biomedical Ti6Al4V alloy was thermally treated under sandblasting and mirror finish surface preparation conditions. The surface morphology, structure, roughness, wettability, and energy were characterized. Microhardness and in vitro corrosion studies were carried out. X-ray diffraction results showed a formation of rutile TiO2 phase for thermally treated samples under different pretreated conditions. The thermally oxidized samples exhibited an increase in microhardness compared to the untreated mirror finish and sandblasted samples by 22 and 33%, respectively. The wettability study revealed enhanced hydrophilicity of blasted and thermally treated samples. The surface energy of the thermal treatment samples increased by 26 and 32.6% for mirror surface and blasted preconditions, respectively. The acquired in vitro corrosion results using potentiodynamic polarization measurement and electrochemical impedance spectroscopy confirmed the surface protective performance against corrosion in Hank’s medium. The enhanced surface characteristics and corrosion protection of treated Ti6Al4V alloy give it potential for bio-implant applications.
Effect of Polyphenylene Sulphide Particles and Films on the Properties of Polyphenylene Sulphide Composites
Authors: Sun Zeyu , Sun Li , Zhu Chengyan , Tian Wei , Shao Lingda , Feng Xuhuang , Huang Kunzhen
Published: October 2022

Glass fibre-reinforced polyphenylene sulphide composites were prepared by hot-pressing glass fibre fabrics and polyphenylene sulphide resins. The effects of different polyphenylene sulphide resin forms on the properties of the composites were investigated using scanning electron microscopy, dynamic mechanical analyser, pendulum impact tester and universal testing machine. The results showed that different polyphenylene sulphide resin forms had nearly no effect on the glass transition temperature of the composites, which are all located at about 100 °C. Compared with other polyphenylene sulphide composites, the bending strength of polyphenylene sulphide film composites was the highest, reaching 314.58 MPa, and the impact strength of polyphenylene sulphide particle composites was the highest, reaching 245.4 KJ/m2. The bending strength and impact strength were calculated using a standard fraction, and the highest standard fraction was obtained when the ratio of polyphenylene sulphide film to particle was 1:2. The impact strength and bending strength could be obtained. The impact strength reached 229.8 KJ/m2, and the bending strength reached 284.16 MPa.
Investigations on the Phase Transformations, Equilibria and Athermal ω in Ni-Ga-Cr Ternary System
Authors: Ruan Jingjing , Chen Yuyuan , Kobayashi Kosei , Ueshima Nobufumi , Oikawa Katsunari
Published: October 2022

In the present work, the phase equilibria of the Ni-Ga-Cr ternary system at 850, 1000 and 1150 °C were experimentally investigated to provide the essential data for developing the high-entropy shape memory alloys (HESMAs) containing Ni, Ga and Cr. At 850 °C, in the Ni-rich portion, the B2 phase shows equilibrium with the L12 phase when the Cr content is less than 10.49 at. %, while displaying the equilibrium with L12 and BCC phases when the Cr content increases. The B2 + L12 + BCC changes into B2 + FCC + BCC three-phase equilibria from 850 to 1150 °C, as the L12 phase region becomes narrow with rising temperature. The two-phase equilibrium, B2 + BCC, was found at all the isothermal sections investigated. Other three-phase equilibria were also discovered: B2 + α-Cr3Ga + BCC and Ni2Ga3 + α-Cr3Ga + L at 850 °C, and B2 + α-Cr3Ga + L at 1000 °C. Significantly, an athermal ω intermetallic compound with the space group of P3¯m1 was observed distributing at the B2 phase in the quenched Ni45.98-Ga25.50-Cr28.52, Ni42.23-Ga15.70-Cr42.07 and Ni16.54-Ga13.63-Cr69.83 (at. %) alloys after being annealed at 1150 °C for 10 days. The high-resolution transmission electron microscopy (HRTEM) results reveal that the ω shows a crystallographic orientation of [11¯0]B2//[112¯0]ω; (111)B2//(0001)ω with the B2 parent phase.
Study on Dynamic Impact Response and Optimal Constitutive Model of Al-Mg-Si Aluminum Alloy
Authors: Zhang Qinmin , Huang Xiaomin , Guo Ran , Chen Dongyu
Published: October 2022

Al-Mg-Si series aluminum alloy is a heat-treatment-strengthened alloy. Research on the impact resistance of Al-Mg-Si series aluminum alloy is of great significance to expand its application in engineering. Taking 6082-T6 aluminum alloy as the concrete research object, using the split Hopkinson pressure bar (SHPB) device, the dynamic mechanical response of the material under different temperatures and average strain rates was studied, and the service performance of the material under extreme conditions was determined. The absolute temperature rise was introduced to optimize the existing constitutive model. The results show that when the environment temperature is 298.15~473.15 K under high-speed impact, the internal thermal softening effect of the material is dominant in the competition with the work hardening, resulting in a decrease in the flow stress of the material. Through the analysis of the real stress–strain curve, it was found that the elastic modulus of the material was negatively correlated with the strain rate, negatively correlated with the temperature, and showed an obvious temperature-softening effect. Yield strength was negatively correlated with temperature and positively correlated with strain rate, which showed an obvious strain rate hardening effect. Based on SEM microscopic analysis, it was found that under given conditions, adiabatic shear bands appeared in some samples, and their internal structures demonstrated obvious change. It was judged that when high-speed impact occurs, cracks are induced at the shear bands, and the cracks will continue to develop along the adiabatic shear bands, resulting in many oblique cracks which will gradually become larger and eventually lead to material failure. Finally, based on the model, the strain rate and temperature softening terms were improved, and a rise in adiabatic temperature rise was introduced. The improved model can better describe the strain rate effect of the material and accurately describe its flow stress. It provides a theoretical basis for the engineering application of materials.
Octahedral Tilting in Homologous Perovskite Series CaMoO3-SrMoO3-BaMoO3 Probed by Temperature-Dependent EXAFS Spectroscopy
Authors: Bakradze Georgijs , Kuzmin Alexei
Published: October 2022

Local distortions in perovskites can be induced by cation displacements and/or by the tilting and rotating of cation–anion octahedra. Both phenomena have been subject to intense investigations over many years. However, there are still controversies in the results obtained from experimental techniques that are sensitive to long-range order (X-ray, neutron, or electron diffraction) and those sensitive to short-range order (X-ray absorption spectroscopy). In this study, we probed the details of the local environment in AMoO3 perovskites (A = Ca, Sr, Ba) using extended X-ray absorption fine structure (EXAFS) in a wide temperature range (10–300 K). An advanced analysis of the EXAFS spectra within the multiple-scattering formalism using the reverse Monte Carlo method enhanced by an evolutionary algorithm allowed us (i) to extract detailed information on metal–oxygen and metal–metal radial distribution functions, and metal–oxygen–metal and oxygen–metal–oxygen bond angle distribution functions, and (ii) to perform polyhedral analysis. The obtained results demonstrate the strong sensitivity of the EXAFS spectra to the tilting of [MoO6] octahedra induced by the differences in the sizes of alkaline earth metal cations (Ca2+, Sr2+, and Ba2+).
Analysis of Wear Properties of Hardox Steels in Different Soil Conditions
Authors: Ligier Krzysztof , Zemlik Martyna , Lemecha Magdalena , Konat Łukasz , Napiórkowski Jerzy
Published: October 2022

This paper presents the results of wear tests of three types of commercial abrasion-resistant steels. The samples, cut from commercially available sheets of metal, were subjected to wear tests to a total friction path of 20,000 m. The tests were provided using the “rotating bowl” method in three types of natural soil masses. The soil moisture and test parameters were kept constant. The tests were carried out in six replications for each material. The testing results indicate that hardness does not determine the resistance to abrasive wear, which is supported by the weight loss results for particular materials. Hardox 600 steel, which is not characterized by the highest hardness, exhibited the lowest weight loss value compared to the other materials in all test soils. For the light soil, the weight loss for Hardox 600 was approx. 1.3 times lower than for Hardox 500 steel and approx. 1.6 times higher than for Hardox Extreme steel. With regards to the medium and heavy soil, the weight losses for Hardox 600 in relation to Hardox 500 steel were approx. 1.7 and 1.6 times lower, respectively, while in relation to Hardox Extreme steel the weight losses were 1.5 and 1.7 times higher, respectively.
Experimental Study on the Application of Cementless Material with Industrial By-Products to Steam-Cured Precast Concrete Products
Authors: Hata Minoru , Sato Makoto , Miyazawa Shingo
Published: October 2022

The purpose of this study was to apply a cementless binder using industrial by-products (fly ash, ground-granulated blast furnace slag, and silica fume) to precast concrete products. In this binder, calcium hydroxide was included as an alkali stimulant but Portland cement was not included. Experiments on the compressive strength and durability of this type of material were conducted and its applicability to precast concrete products was investigated using full-scale specimens. The experiments proved that high-temperature steam curing is effective at obtaining strength development and that compressive strength can be expressed as a linear function of the binder–water ratio. Experimental results of chloride ion diffusion coefficient and sulfuric acid resistance suggested that the proposed material has higher resistances than conventional cement concrete against these deterioration factors. It was also demonstrated that full-scale specimens of a box culvert and a centrifugally compacted pipe using this type of material have almost the same load-bearing capacity and deformation performance as those using conventional cement concrete. It is believed that the proposed material could be used as a construction material instead of cement concrete, contribute to reducing CO2 emission, and increase the reuse of industrial by-products.
Microstructural Characteristics of Al-Ti-B Inoculation Wires and Their Addition to the AlSi7Mg0.3 Alloy
Authors: Knaislová Anna , Michna Štefan , Hren Iryna , Vlach Tomáš , Michalcová Alena , Novák Pavel , Stančeková Dana
Published: October 2022

Commercially supplied inoculation wires have a guaranteed chemical composition but not the size and distribution of individual phases, which are very important for nucleation. Therefore, two commercial alloys used for the inoculation of Al-Si alloys (AlTi3B1 and AlTi5B1) are investigated in this paper. The emphasis is placed on their structural analysis and the size and distribution of individual intermetallic phases. Furthermore, the grain refinement effect will be tested by adding these alloys to the AlSi7Mg0.3 alloy and testing the optimal amount of added inoculation wires. The results showed that the size and distribution of the individual phases in AlTi3B1 and AlTi5B1 meet the requirements for the successful inoculation of aluminum alloys, the intermetallic phases based on the TiAl3 phase are fine enough, and there is no agglomeration that would reduce the number of nuclei. This assumption was confirmed by adding these inoculants to the AlSi7Mg0.3 alloy, and it was found that the most ideal amount of inoculants added is 0.01 wt % when the structure was refined by approximately 32%.
The Effect of Surface Characteristics of Clays on the Properties of Starch Nanocomposites
Authors: Fekete Erika , Angyal Lilla , Csiszár Emília
Published: October 2022

In this research, different clays such as laponite and montmorillonite (NaMMT) are used as fillers in the preparation of thermoplastic starch/clay nanocomposites. Thin films are produced by casting and evaporation in a wide composition range, using glycerol as the plasticizer at two different concentrations. The surface energy of clay fillers is measured by inverse gas chromatography (IGC); X-ray diffraction (XRD) and light transmission measurements (UV-VIS) are carried out to characterize the structure of nanocomposites; and mechanical properties and water vapor permeability are also studied. While all the starch/montmorillonite nanocomposites possess intercalated structures, significant exfoliation can be noted in the starch/laponite nanocomposites, mainly at low clay contents. Due to the larger surface energy of montmorillonite, stronger polymer/clay interactions and better mechanical properties can be assumed in starch/NaMMT composites. The smaller surface energy of laponite, however, can facilitate the delamination of laponite layers. Thus, the specific surface area of laponite can be further increased by exfoliation. Based on the results, the better exfoliation and the much larger specific surface area of laponite lead to higher reinforcement in starch/laponite nanocomposites.
Numerical Investigation on Progressive Collapse Mitigation of Steel Beam–Column Joint Using Steel Plates
Authors: Alrubaidi Mohammed , Alhammadi S. A.
Published: October 2022

This research employed extensive numerical analyses to locate the weak areas and determine the structural issues critical to preventing the spread of collapse. As a result, three specimens were tested using scaled models of strengthened and unstrengthened steel beam–column joint assemblies. The data were utilized to verify numerical models. One simple shear joint from the three experimental assemblies was used as the control specimen (unstrengthened joint). The second was a bolted steel beam–column joint utilized as a reference specimen to reflect the ideal beam–column joint generally employed in intermediate moment-resisting frames in seismic zones worldwide. Similar to the control, the third specimen (strengthened joint) had two side plates welded together to strengthen the connection site. Numerical finite element models were developed using ABAQUS (2020) software to extensively investigate the behavior of steel frame assemblies before and after upgrading. The FEM matrix comprised 17 specimens with varying parameters, including plate thickness, steel grade, a joint between the beam flange-strengthening plates, and a column that was either welded or not welded. The effectiveness of the strengthening techniques was established by comparing the mode of failure and load–displacement characteristics of the investigated specimens. The results indicate that the average increase in peak load due to a change in plate thickness for grades A36 and A572 is approximately 22% and 8%, respectively. Plates made of A572 steel increase peak load by 30%. All strengthened specimens attained catenary action, mitigating the possibility of progressive collapse.
Theoretical Analysis and Experimental Verification of the Stress and Strain of Axially Compressed Steel-Reinforced Concrete Columns under Long-Term Loads
Authors: Han Weiwei , Wang Cui , Lv Yigang , Su Miao , Liu Yuting , Peng Hui
Published: October 2022

The objective of this study is to provide a theoretical method to accurately calculate the stress and strain of steel-reinforced concrete (SRC) columns under long-term axial compression. First, considering the cross-sectional stress redistribution and the influence of each stress increment in the process, the theoretical formula of stress and strain under long-term loading was deduced. Then, the stress and strain calculation program of SRC columns under long-term axial compression was programmed by using object-oriented Visual C++ language. Finally, an experimental study on the long-term deformation performance of SRC axial compression columns was performed to validate the accuracy of the proposed theoretical method. By comparing the calculated results with the experimental results, the influence of steel bars on the long-term stress and strain of SRC columns under axial compression was analyzed and the corresponding long-term stress–strain variation law was studied. Results show that the changing trend of the long-term strain of plain concrete (PC) and SRC with loading time is basically the same, increasing rapidly in the first 270 days and gradually tending to be stable beyond 270 days. After 750 days, the maximum difference in the total strain between the PC columns and SRC columns reaches 26.60%, and the steel bars have a strong influence on the long-term strain of the concrete columns. The errors between the measured values of the two SRC columns, and the calculated results are 2.96% and 5.78%, respectively. Therefore, the derived stress–strain calculation formula and calculation program of SRC columns under long-term loads are accurate and reliable. When the loading time is 750 days, the tensile stress increment of 1.92 MPa and a compressive stress increment of 168.26 MPa are produced in concrete and steel bars. The long-term stress of concrete columns is markedly influenced by steel bars. In the first three years, the stress and strain of the concrete and steel bars develop rapidly and then gradually slow down.
Surface Properties of Eggshell Powder and Its Influence on Cement Hydration
Authors: He Yinghou , Che Dehao , Ouyang Xiaowei , Niu Yanfei
Published: October 2022

Using eggshell powder (EP) to replace partial cement in cement-based materials can abate pollution caused by eggshell discard and cement production. In this paper, the surface property of EP and its influence on cement hydration were studied. Quartz powder (QP) and limestone powder (LP) were used as references. First, the chemical composition of EP was characterized. Then, the surface charge properties of these materials were analyzed using zeta potential measurement. The interactions between EP surface and Ca2+ were discussed based on the zeta potential test. Afterward, a scanning electron microscope (SEM) was applied to observe the morphology of hydrates on the surfaces of these materials. The results indicated that, although the compositions of EP and LP are similar, the surface charge properties are significantly different. This is likely due to the existence of organic matter on the surface of EP and the difference in the atomic structure. As shown from the zeta potential test, EP exhibits similar interaction with Ca2+ as QP. The interactions between EP surface and Ca2+ are much weaker than that between LP and Ca2+. These weak interactions lead to the growth of C–S–H on the surface of EP particles less than that of LP particles. The chemical reactivity of EP can be improved by using heat treatment, electrical oven, etc. This study will provide theoretical support for the better use of EP in cement-based materials.
Salicylic Acid Co-Precipitation with Alginate via Supercritical Atomization for Cosmetic Applications
Authors: Baldino Lucia , Reverchon Ernesto
Published: October 2022

Alginate-based microparticles were produced via supercritical assisted atomization (SAA) with the aim of obtaining a biocompatible and low-cost carrier for the delivery of active compounds in cosmetic applications. Salicylic acid was selected as an active model compound, and it was co-precipitated with alginate via SAA, operating at 82 bar and 80 °C. In particular, the drug-to-polymer weight ratio was fixed at 1/4, whereas polymer concentration was varied from 5 to 20 mg/mL in the starting aqueous solution. Operating in this way, alginate-salicylic acid microparticles were characterized by a mean diameter of 0.72 ± 0.25 µm, and the active compound became amorphous after processing. A salicylic acid encapsulation efficiency close to 100% was reached, and the drug release time from the biopolymeric microparticles was prolonged up to nine times with respect to untreated salicylic acid powder.
Porous Carbon–Carbon Composite Materials Obtained by Alkaline Dehydrochlorination of Polyvinyl Chloride
Authors: Kryazhev Yury G. , Anikeeva Irina V. , Trenikhin Mikhail V. , Gulyaeva Tatiana I. , Melnikov Valeriy P. , Likholobov Vladimir A. , Belskaya Olga B.
Published: October 2022

Porous carbon–carbon composite materials (PCCCM) were synthesized by the alkaline dehydrochlorination of polyvinyl chloride solutions in dimethyl sulfoxide containing the modifying additives of a nanostructured component (NC): graphite oxide (GO), reduced graphite oxide (RGO) or nanoglobular carbon (NGC), with subsequent two-step thermal treatment of the obtained polyvinylene–NC composites (carbonization at 400 °C and carbon dioxide activation at 900 °C). The focus of the study was on the analysis and digital processing of transmission electron microscopy images to study local areas of carbon composite materials, as well as to determine the distances between graphene layers. TEM and low-temperature nitrogen adsorption studies revealed that the structure of the synthesized PCCCM can be considered as a porous carbon matrix in which either carbon nanoglobules (in the case of NGC) or carbon particles with the “crumpled sheet” morphology (in the case of GO or RGO used as the modifying additives) are distributed. Depending on the features of the introduced 5–7 wt.% nanostructured component, the fraction of mesopores was shown to vary from 11% to 46%, and SBET—from 791 to 1115 m2 g−1. The synthesis of PCCNC using graphite oxide and reduced graphite oxide as the modifying additives can be considered as a method for synthesizing a porous carbon material with the hierarchical structure containing both the micro- and meso/macropores. Such materials are widely applied and can serve as adsorbents, catalyst supports, elements of power storage systems, etc.
Comparative Study of Carbon Nanotube Composites as Capacitive and Piezoresistive Pressure Sensors under Varying Conditions
Authors: Oh Jihyeon , Kim Dong-Young , Kim Hyunwoo , Hur Oh-Nyoung , Park Sung-Hoon
Published: October 2022

Conducting polymer composites consisting of carbon nanotubes (CNTs) as a conductive filler and polydimethylsiloxane (PDMS) as a polymer matrix were fabricated to investigate their capacitive and piezoresistive effects as pressure sensors. The pressure-sensing behavior and mechanism of the composites were compared in terms of basic configuration with a parallel plate structure. Various sensing experiments, such as sensitivity, repeatability, hysteresis, and temperature dependence according to the working principle, were conducted with varying filler contents. The hysteresis and repeatability of the pressure-sensing properties were investigated using cyclic tensile tests. In addition, a temperature test was performed at selected temperatures to monitor the change in the resistance/capacitance.
Design and Application of Non-Circular Gear with Cusp Pitch Curve
Authors: Liu Jian-Gang , Tong Zhi-Peng , Yu Gao-Hong , Zhao Xiong , Zhou Hai-Li
Published: October 2022

To solve the design problem of non-circular gears with cusp pitch curves, this paper proposed a new variable-involute and incomplete variable-cycloid composite tooth profile (VIIVC-CTF), deduced the new VIIVC-CTF mathematical model, and constructed the conjugate gear model based on the envelope method. The design software of the non-circular gear with a cusp pitch curve was developed based on MATLAB. The variation law of rolling radius on an incomplete cycloid profile and its characteristics such as pressure angle and radius of curvature were analyzed. The variation relationship of the rolling radius on the meshing line and the contact ratio of the VIIVC-CTF were studied. The variation relationship of incomplete variable-cycloid profile shape, pressure angle, and curvature radius corresponding to different elliptical eccentricities were analyzed. The meshing analysis of the non-circular gear transmission mechanism was carried out based on virtual software. A comparison of the consistency of the theoretical value and simulation value of the transmission ratio curve verified that the tooth profile design method was feasible, and the VIIVC-CTF was applied to the seedling pick-up mechanism of the non-circular gear planetary gear train. Through the seedling picking experiment of the seedling pick-up mechanism, the feasibility of the application of the VIIVC-CTF was verified.
Research on Acceleration Performance Optimization of Large Inertia Hydraulic Actuator Based on Main Valve Input Shaping
Authors: Fu Wenbo , Yuan Xiaoming , Li Yongquan , Zhang Lijie
Published: October 2022

In order to optimize the acceleration performance of a large inertia hydraulic actuator, this paper proposes a main valve input shaping control strategy, which makes the valve flow supply match the load-control demand by adjusting the main valve flow growth rate. Taking a load-independent flow distribution system as the research object, and aiming at the problems of large pressure overshoot, excessive overflow and oscillation tendency during the actuator acceleration process, this paper divides the acceleration process into the pressure build-up condition, the inertia-acceleration condition and the stable-flow regulation condition according to the change characteristics of the actuator driving pressure, and divides the main valve control signal into five stages to design the valve flow growth rate, thereby smoothing the driving pressure fluctuations by adjusting the actuator inertial load and mitigating the pressure release process. Based on the key structure-hydraulic parameters and test data of a 6-ton excavator, a virtual excavator that can accurately simulate the swing action and boom lifting action is built, and the software-in-the-loop test of the input-shaping control algorithm is carried out. The test results indicate that the proposed control strategy can effectively suppress the pressure overshoot, oscillation, and flow overmatching, thereby improving the dynamic stability and energy efficiency of the system.
Large-Scale Measurement Layout Optimization Method Based on Laser Multilateration
Authors: Sheng Ying , Wang Yukun , Liu Siwei , Wang Cuiping , Xi Juntong
Published: October 2022

Laser multilateration is a measurement method based on the distance intersection of multiple laser trackers which has been widely used in large-scale measurements. However, the layout of laser trackers has a great impact on the final measurement accuracy. In order to improve the overall measurement accuracy, firstly, a measurement uncertainty model based on laser multilateration is established. Secondly, a fast laser intersection detection constraint algorithm based on a k-DOPS bounding box and an adaptive target ball incident angle constraint detection algorithm are established for large-scale measurement scenes. Finally, the constrained layout optimization of the laser trackers is realized by using an improved cellular genetic algorithm. The results show that the optimized system layout can achieve the full coverage of measurement points and has higher measurement accuracy. Compared with the traditional genetic algorithm, the improved cellular genetic algorithm converges faster and obtains a better position layout.
Decision Support Method for Dynamic Production Planning
Authors: Skėrė Simona , Žvironienė Aušra , Juzėnas Kazimieras , Petraitienė Stasė
Published: October 2022

Small and medium-sized engineering production companies face challenges that are related to unpredicted rapid changes of availability of the work force, materials and equipment. Those challenges are especially difficult to solve for companies focusing on unit or batch production and when they are collaborating with customers who require short lead times. A four-month observation was carried out in a metal processing company in Lithuania to understand the most common rising problems and developing solution for computerised decision support systems. It was discovered that the company needs a computerised “employee centred” system for the improvement of the allocation of tasks to employees. Such a need proved to be the most urgent one, especially during pandemics. An algorithm for the analysis and automated allocation of the employees’ tasks has been developed and tested. The proposed algorithm is universal and may be applied in different SMEs for engineering production.
SWLC-DT: An Architecture for Ship Whole Life Cycle Digital Twin Based on Vertical–Horizontal Design
Authors: Xiao Wei , He Ming , Wei Zhengxian , Wang Nianbin
Published: October 2022

With the development of IoT technology, the digital twin has been applied in many fields. It is the key to realizing the integration of physical information space and an effective means for intelligent upgrading of products, providing a novel idea for the whole life cycle management of complex products. As a pillar industry at the national strategic level, the shipbuilding industry is in the stage of informatization transformation and upgrading and needs to improve its own competitiveness. The ship whole life cycle includes design, construction, operation, and maintenance, as well as scrapping and recycling, but each stage has a certain independence, which makes it prone to the problem of information islands. However, the current research on the product full lifecycle digital twin has not yet considered the impact of historical data of successive generation products on each stage of the current product lifecycle. To address the above issues, this paper firstly proposes the vertical–horizontal design idea from the perspective of the product whole life cycle and combining historical experience (vertical) with real-time data (horizontal) to realize the construction and evolution of digital twin models at all stages of the life cycle. Then, on the basis of the vertical–horizontal design idea, a framework for the ship whole life cycle digital twin is proposed. Finally, the operation mechanism of the framework is elaborated from the four stages of the ship life cycle, with a view to providing a reference for the transformation and upgrading of the future ship industry.
Study on the Preparation and Performance of Self-Regressive Fixed Abrasive Chemical Mechanical Polishing Pad
Authors: Yao Jianguo , Liu Haixu , Wang Zhankui , Zhu Yongwei , Su Jianxiu
Published: October 2022

Chemical mechanical polishing (CMP) technology is one of the key technologies to realize the global planarization of semiconductor wafer surfaces. With the increasing popularity and universality of its application, more and higher requirements are put forward for ultra-precision machining. As an important part of the CMP system, polishing pads occupy a dominant position. In this paper, a self-regressive fixed abrasive polishing pad (SR-FAPP) was prepared by photo-curing. The physical and mechanical properties of the SR-FAPP and the retreat threshold of the abrasive particles on the SR-FAPP were studied. After the CMP of the SiC wafer with a polyurethane polishing pad and the SR-FAPP, it was found that the material removal rate of the former was 75% higher than that of the latter, and the surface roughness of the latter was 75% higher than that of the former. In the micro-morphology, the scratches on the surface of the latter’s polished SiC wafer were obviously reduced, which effectively improved the unevenness of the scratches on the surface of the SiC wafer after polishing, thus providing a reference for the preparation and performance research of the polishing pad.
Layered Organic Conductors Based on BEDT-TTF and Ho, Dy, Tb Chlorides
Authors: Flakina Alexandra M. , Zhilyaeva Elena I. , Shilov Gennady V. , Faraonov Maxim A. , Torunova Svetlana A. , Konarev Dmitri V.
Published: October 2022

Molecular semiconductors with lanthanide ions have been synthesized based on BEDT-TTF and lanthanide chlorides: (BEDT-TTF)2[HoCl2(H2O)6]Cl2(H2O)2 (1, which contains a 4f holmium cation), and (BEDT-TTF)2LnCl4(H2O)n (Ln = Dy, Tb, Ho (2–4), which contain 4f anions of lanthanides). Conductivity and EPR measurements have been carried out along with the SQUID magnetometry, and the crystal structure has been established for 1. The structure of 1 is characterized by an alternation of organic radical cation layers composed of BEDT-TTF chains and inorganic layers consisting of chains of the [HoCl2(H2O)6]+ cations interlinked by chlorine anions and crystallization water molecules. The magnetic susceptibility of 1–3 determined mainly by lanthanide ions follows the Curie–Weiss law with the Weiss temperatures of −3, −3, −2 K for 1–3, respectively, indicating weak antiferromagnetic coupling between paramagnetic lanthanide ions. The signals attributed to the BEDT-TTF+· radical cations only are observed in the EPR spectra of 1–3, which makes it possible to study their magnetic behavior. There are two types of chains in the organic layers of 1: the chains composed of neutral molecules and those formed by BEDT-TTF+· radical cations. As a result, uniform 1D antiferromagnetic coupling of spins is observed in the BEDT-TTF+· chains with estimated exchange interaction J = −10 K. The study of dynamic magnetic properties of 1–3 shows that these compounds are not SMMs.
Hydrophobic Magnetite Nanoparticles for Bioseparation: Green Synthesis, Functionalization, and Characterization
Authors: Alimohammadi Vahid , Seyyed Ebrahimi Seyyed Ali , Kashanian Faezeh , Lalegani Zahra , Habibi-Rezaei Mehran , Hamawandi Bejan
Published: October 2022

In this study, three types of hydrophobized alkyl-modified magnetic nanoparticles (MNPs) comprising direct alkylated-MNPs (A-MNPs), silica-mediated alkyl MNPs (A-SiMNPs), and arginine (Arg)-mediated alkyl MNPs (A-RMNPs) were synthesized successfully. For this purpose, the co-precipitation method was used to synthesize, and octadecyl trimethoxy silane (OTMS) was used as a functionalizing agent. Accordingly, the hydrophobic octadecyl moieties were connected to MNPs. The nanoparticles (NPs) were characterized by XRD, SEM, FTIR, CHN, DLS, and zeta potential analyses. The synthesized coated MNPs represented a decrease in surface charge and magnetization alongside increased surface hydrophobicity and size. It was revealed that the alkylation process was successfully performed to all three MNPs, but A-SiMNPs showed the highest hydrophobicity. Additionally, the novel A-RMNPs, as the most biocompatible type, and A-MNPs showed the highest magnetization among the synthesized MNPs. The results indicate that synthesized NPs can play an important role in bio applications. However, it was revealed that alkyl chains are easily connected to all three MNPs, and that A-MNPs contained the highest alkyl chains and could affect the re-folding and denaturation process of recombinant proteins.