bluuebunny/crossref_metadata_2025 huggingface dataset:
Emotion Classification in Spanish: Exploring the Hard Classes
Authors: Rosá Aiala , Chiruzzo Luis
Published: October 2021

The study of affective language has had numerous developments in the Natural Language Processing area in recent years, but the focus has been predominantly on Sentiment Analysis, an expression usually used to refer to the classification of texts according to their polarity or valence (positive vs. negative). The study of emotions, such as joy, sadness, anger, surprise, among others, has been much less developed and has fewer resources, both for English and for other languages, such as Spanish. In this paper, we present the most relevant existing resources for the study of emotions, mainly for Spanish; we describe some heuristics for the union of two existing corpora of Spanish tweets; and based on some experiments for classification of tweets according to seven categories (anger, disgust, fear, joy, sadness, surprise, and others) we analyze the most problematic classes.
Access Site Related Vascular Complications following Percutaneous Cardiovascular Procedures
Authors: Hetrodt Johanna , Engelbertz Christiane , Gebauer Katrin , Stella Jacqueline , Meyborg Matthias , Freisinger Eva , Reinecke Holger , Malyar Nasser
Published: October 2021

Vascular access site complications (ASC) are among the most frequent complications of percutaneous cardiovascular procedures (PCP) and are associated with adverse outcome and high resources utilization. In this prospective study, we investigated patients with postprocedural clinical suspicion of ASC evaluated by duplex ultrasound (DUS) for the presence of ASC. We assessed the incidence, in-hospital outcome, treatment of complications and predictors for ASC. Overall, 12,901 patients underwent PCP during a 40 months period. Of those, 2890 (22.4%) patients had postprocedural clinical symptoms of ASC and were evaluated using DUS. An ASC was found in 206 of the DUS examined patients (corresponding to 7.1% of the 2890 DUS examined patients). In 6.7% of all valvular/TAVI procedures, an ASC was documented, while coronary, electrophysiological and peripheral PCP had a comparable and low rate of complications (1.2–1.5%). Pseudoaneurysm (PSA) was the most frequent ASC (67.5%), followed by arteriovenous fistula (13.1%), hematoma (7.8%) and others (11.7%). Of all PSA, 84 (60.4%) were treated surgically, 44 (31.6%) by manual compression and 11 (7.9%) conservatively. Three (0.02%) patients died due to hemorrhagic shock. In conclusion, femoral ASC are rare in the current era of PCP with PSA being the leading type of ASC. Nonetheless, patients with predisposing risk factors and postprocedural suspicious clinical findings should undergo a DUS to early detect and mitigate ASC-associated outcome.
Long-Term Outcomes of Endoscopic Gallbladder Drainage for Cholecystitis in Poor Surgical Candidates: An Updated Comprehensive Review
Authors: Inoue Tadahisa , Yoshida Michihiro , Suzuki Yuta , Kitano Rena , Okumura Fumihiro , Naitoh Itaru
Published: October 2021

Laparoscopic cholecystectomy is the standard and fundamental treatment of choice for acute cholecystitis; however, there are cases in which patients may be poor surgical candidates due to advanced age, comorbidities, and/or general condition. The rate of recurrent cholecystitis is high in patients who are not surgically treated; therefore, the prevention of recurrence in this patient population is an important subject of investigation in the management of cholecystitis. Although it has recently been reported that long-term stent placement by endoscopic gallbladder stenting or endoscopic ultrasound-guided gallbladder drainage may reduce the recurrence rate, its efficacy and safety remain controversial. Additionally, details surrounding the long-term stent management of these treatment methods should be further investigated. In this review, we summarize the updated evidence regarding the usefulness of long-term stent placement with endoscopic gallbladder stenting or endoscopic ultrasound-guided gallbladder drainage as a preventive measure for recurrence of cholecystitis and discuss issues that should be addressed in future studies.
Preliminary Study with the Use of a Titanium Mesh as Space Maker and Implant Primary Stabilization for One-Stage Sinus Lift in Cases with Less Than 1.5 mm Residual Bone
Authors: Filipov Iulian , Bolognesi Federico , Chirila Lucian , Cristache Corina Marilena , Corinaldesi Giuseppe , Park Kwang Bum
Published: October 2021

(1) Background: In the lateral area of the maxilla, the alveolar bone can lose significant volume due to maxillary sinus pneumatization following teeth extractions. This preliminary study evaluated the effectiveness of a novel technique for one-stage sinus lifting and simultaneous implant placement in cases with less than 1.5 mm residual alveolar bone. The subsequent survival rate at 1-year post-occlusal loading was assessed. (2) Methods: 15 patients were selected, the main inclusion criteria were the partially edentulous area in the posterior maxilla with alveolar bone height of less than 1.5 mm below the sinus. All of the patients underwent one-stage sinus lifting, along with simultaneous implant placement using a “butterfly” anchorage device to optimize the primary stability and xenograft bone as graft material. At 6 to 9 months after surgery, the anchorage device was removed and implants were loaded. Panoramic x-ray images were used to assess the new bone formation, while the biological stability was measured using resonance frequency analysis. (3) Results: 15 implants were inserted. The mean implant stability quotient (ISQ) value was 71.3 (SD = ±2.51) and the mean healing period was 7.3 (SD = ±1.23) months. The mean bone height after the healing period was 14.4 (SD = ±2.05). A statistically significant correlation was found between the healing period and the ISQ value (Spearman rho = 0.684, sig. = 0.005). No statistically significant correlation was found between the ISQ value and the new regenerated bone height (Person r = 0.389, sig. = 0.152). Smoking was identified as a risk factor involved in postoperative complications. (4) Conclusions: The results of the present preliminary study demonstrated that the proposed “butterfly” technique was effective when performing one-stage sinus lifting and simultaneous implant placement in cases with less than 1.5 mm of residual alveolar bone. The survival rate was 100% at 1-year post occlusal loading.
Biochemical Markers for the Diagnosis of Mitochondrial Fatty Acid Oxidation Diseases
Authors: Ruiz-Sala Pedro , Peña-Quintana Luis
Published: October 2021

Mitochondrial fatty acid β-oxidation (FAO) contributes a large proportion to the body’s energy needs in fasting and in situations of metabolic stress. Most tissues use energy from fatty acids, particularly the heart, skeletal muscle and the liver. In the brain, ketone bodies formed from FAO in the liver are used as the main source of energy. The mitochondrial fatty acid oxidation disorders (FAODs), which include the carnitine system defects, constitute a group of diseases with several types and subtypes and with variable clinical spectrum and prognosis, from paucisymptomatic cases to more severe affectations, with a 5% rate of sudden death in childhood, and with fasting hypoketotic hypoglycemia frequently occurring. The implementation of newborn screening programs has resulted in new challenges in diagnosis, with the detection of new phenotypes as well as carriers and false positive cases. In this article, a review of the biochemical markers used for the diagnosis of FAODs is presented. The analysis of acylcarnitines by MS/MS contributes to improving the biochemical diagnosis, both in affected patients and in newborn screening, but acylglycines, organic acids, and other metabolites are also reported. Moreover, this review recommends caution, and outlines the differences in the interpretation of the biomarkers depending on age, clinical situation and types of samples or techniques.
Meaning in Life Buffers the Association between Perceived Burdensomeness, Thwarted Belongingness, and Frequency of Non-Suicidal Self-Injuries in Spanish Adolescents
Authors: Marco Jose H. , Gallego-Hernández de Tejada Blanca , Guillén Verónica , Baños Rosa M. , Pérez Sandra
Published: October 2021

Background: Adolescence is a developmental stage when there is a high risk of engaging in non-suicidal self-injury (NSSI). There is recent interest in the study of thwarted belongingness and perceived burdensome as variables associated with the frequency of NSSI in adolescents. Meaning in life (MIL) might be negatively associated with thwarted belongingness and perceived burdensomeness. To date, no studies have analyzed the buffering role of MIL in the association between thwarted belongingness and perceived burdensomeness and the frequency of lifetime NSSI in Spanish adolescents. Aims: (a) To test whether thwarted belongingness and perceived burdensomeness are associated with frequency of lifetime NSSI; (b) to test whether MIL moderates the association between thwarted belongingness and frequency of lifetime NSSI; and (c) to test whether MIL moderates the association between perceived burdensomeness and frequency of lifetime NSSI. Method: The sample consisted of N = 1531 participants (n = 736, 48.1%, were men, and n = 795, 51.9%, were women) between 12 and 18 years old from Spain. The participants filled out the Inventory of Statements about Self-Injury, Purpose-In-Life Test-Adolescent Version, and Interpersonal Needs Questionnaire. Moderation analyses were performed. Results: No statistically significant differences were found in the frequency of lifetime NSSI in the adolescents based on gender. Thwarted belongingness and perceived burdensomeness were positively associated with the frequency of lifetime NSSI in Spanish adolescents. MIL was a moderating variable between thwarted belongingness and the frequency of lifetime NSSI, and between perceived burdensomeness and the frequency of lifetime NSSI. Conclusions: Thwarted belongingness and perceived burdensomeness might be positively associated with the frequency of lifetime NSSI, and MIL might be negatively associated with the frequency of lifetime NSSI. Thus, adding these variables to current descriptive theories of NSSI in adolescents would allow us to improve assessment and treatment protocols for adolescents with NSSI.
Prognostic Value of N-Terminal Pro-Brain Natriuretic Peptide and High-Sensitivity Troponin T Levels in the Natural History of Transthyretin Amyloid Cardiomyopathy and Their Evolution after Tafamidis Treatment
Authors: Oghina Silvia , Josse Constant , Bézard Mélanie , Kharoubi Mounira , Delbarre Marc-Antoine , Eyharts Damien , Zaroui Amira , Guendouz Soulef , Galat Arnault , Hittinger Luc , Fanen Pascale , Teiger Emmanuel , Mouri Nadir , Montestruc François , Damy Thibaud
Published: October 2021

Background: We assesse the evolution and prognostic value of N-terminal pro-brain natriuretic peptide (NT-proBNP) and high-sensitivity troponin T (cTnT-HS) in transthyretin amyloid cardiomyopathy (ATTR-CA) before and after tafamidis treatment. Methods and Results: 454 ATTR-CA patients without tafamidis (Cohort A) and 248 ATTR-CA with tafamidis (Cohort B) were enrolled. Event-free survival (EFS) events were death, heart transplant, or acute heart failure. In Cohort A, 27% of patients maintained NT-proBNP < 3000 ng/L and 14% cTnT-HS < 50 ng/L at 12 months relative to baseline levels. In Cohort B, the proportions were 49% and 29%, respectively. In Cohort A, among the 333 patients without an increased NT-proBNP > 50% relative to baseline EFS was extended compared to the 121 patients with an increased NT-proBNP > 50% (HR: 0.75 [0.57; 0.98]; p = 0.032). In Cohort A, baseline NT-proBNP > 3000 ng/L and cTnT-HS > 50 ng/L and a relative increase of NT-proBNP > 50% during follow-up were independent prognostic factors of EFS. The slopes of logs NT-proBNP and cTnT-HS increased with time before and stabilized after tafamidis. Conclusion: ATTR-CA patients with increasing NT-proBNP had an increased risk of EFS. Tafamidis stabilize NT-proBNP and cTnT-HS increasing, even if initial NT-proBNP levels were >3000 ng/L. Thus suggesting that all patients, irrespective of baseline NT-proBNP levels, may benefit from tafamidis.
Education Attainment, Intelligence and COVID-19: A Mendelian Randomization Study
Authors: Li Gloria Hoi-Yee , Lam Stanley Kam-Ki , Wong Ian Chi-Kei , Chu Jody Kwok-Pui , Cheung Ching-Lung
Published: October 2021

Background: Evidence of socioeconomic inequality in COVID-19-related outcomes is emerging, with a higher risk of infection and mortality observed among individuals with lower education attainment. We aimed to evaluate the potential interventions against COVID-19 from the socioeconomic perspective, including improvement in education and intelligence. Methods: With a two-sample Mendelian randomization approach using summary statistics from the largest genome-wide association meta-analysis, univariable analysis was adopted to evaluate the total causal effects of genetically determined education attainment and intelligence on COVID-19 outcomes. Multivariable analysis was performed to dissect the potential mechanisms. Results: Genetic predisposition to higher education attainment by 1 SD (4.2 years) was independently associated with reduced risk of COVID-19 severity (OR = 0.508 [95% CI: 0.417–0.617]; p < 0.001). Genetically higher education attainment also lowered the risk of COVID-19 hospitalization (0.685 [0.593–0.791]; p < 0.001), but the association was attenuated after adjustment for beta estimates of intelligence in multivariable analysis. Genetically higher intelligence was associated with reduced risk of COVID-19 hospitalization (0.780 [0.655–0.930]; p = 0.006), with attenuation of association after adjustment for education attainment. Null association was observed for genetically determined education attainment and intelligence with SARS-CoV-2 infection. Conclusion: Education may act independently and jointly with intelligence in improving the COVID-19 outcomes. Improving education may potentially alleviate the COVID-19-related health inequality.
Unsteady Linearisation of Bed Shear Stress for Idealised Storm Surge Modelling
Authors: Roos Pieter C. , Lipari Giordano , Pitzalis Chris , Reef Koen R. G. , Campmans Gerhardus H. P. , Hulscher Suzanne J. M. H.
Published: October 2021

The modelling of time-varying shallow flows, such as tides and storm surges, is complicated by the nonlinear dependency of bed shear stress on flow speed. For tidal flows, Lorentz’s linearisation circumvents nonlinearity by specifying a (steady) friction coefficient r based on a tide-averaged criterion of energy equivalence. However, this approach is not suitable for phenomena with episodic and irregular forcings such as storm surges. Here, we studied the implications of applying Lorentz’s energy criterion in an instantaneous sense, so that an unsteady friction coefficient r(t) adjusts to the temporal development of natural wind-driven flows. This new bed-stress parametrisation was implemented in an idealised model of a single channel, forced by time-varying signals of wind stress (acting over the entire domain) and surface elevation (at the channel mouth). The solution method combines analytical solutions of the cross-sectionally averaged linearised shallow-water equations, obtained in the frequency domain, with an iterative procedure to determine r(t). Model results, compared with a reference finite-difference solution retaining the quadratic bed shear stress, show that this new approach accurately captures the qualitative and quantitative aspects of the surge dynamics (height and timing of surge peaks, sloshing, friction-induced tide-surge interaction) for both synthetic and realistic wind forcings.
Headland Rip Modelling at a Natural Beach under High-Energy Wave Conditions
Authors: Mouragues Arthur , Bonneton Philippe , Castelle Bruno , Martins Kévin
Published: October 2021

A XBeach surfbeat model is used to explore the dynamics of natural headland rip circulation under a broad range of incident wave conditions and tide level. The model was calibrated and extensively validated against measurements collected in the vicinity of a 500-m rocky headland. Modelled bulk hydrodynamic quantities were in good agreement with measurements for two wave events during which deflection rips were captured. In particular, the model was able to reproduce the tidal modulation and very-low-frequency fluctuations (≈1 h period) of the deflection rip during the 4-m wave event. For that event, the synoptic flow behaviour shows the large spatial coverage of the rip which extended 1600 m offshore at low tide, when the surf zone limit extends beyond the headland tip. These results emphasize a deflection mechanism different from conceptualised deflection mechanisms based on the boundary length to surf zone width ratio. Further simulations indicate that the adjacent embayment is responsible for the seaward extent of the rip under energetic wave conditions. The present study shows that the circulation patterns along natural rugged coastlines are strongly controlled by the natural variability of the coastal morphology, including headland shape and adjacent embayments, which has implications on headland bypassing expressions.
Modelling of Parametric Resonance for Heaving Buoys with Position-Varying Waterplane Area
Authors: Lelkes János , Davidson Josh , Kalmár-Nagy Tamás
Published: October 2021

Exploiting parametric resonance may enable increased performance for wave energy converters (WECs). By designing the geometry of a heaving WEC, it is possible to introduce a heave-to-heave Mathieu instability that can trigger parametric resonance. To evaluate the potential of such a WEC, a mathematical model is introduced in this paper for a heaving buoy with a non-constant waterplane area in monochromatic waves. The efficacy of the model in capturing parametric resonance is verified by a comparison against the results from a nonlinear Froude–Krylov force model, which numerically calculates the forces on the buoy based on the evolving wetted surface area. The introduced model is more than 1000 times faster than the nonlinear Froude–Krylov force model and also provides the significant benefit of enabling analytical investigation techniques to be utilised.
Complete Coverage Path Planning of an Unmanned Surface Vehicle Based on a Complete Coverage Neural Network Algorithm
Authors: Xu Peng-Fei , Ding Yan-Xu , Luo Jia-Cheng
Published: October 2021

In practical applications, an unmanned surface vehicle (USV) generally employs a task of complete coverage path planning for exploration in a target area of interest. The biological inspired neural network (BINN) algorithm has been extensively employed in path planning of mobile robots, recently. In this paper, a complete coverage neural network (CCNN) algorithm for the path planning of a USV is proposed for the first time. By simplifying the calculation process of the neural activity, the CCNN algorithm can significantly reduce calculation time. To improve coverage efficiency and make the path more regular, the optimal next position decision formula combined with the covering direction term is established. The CCNN algorithm has increased moving directions of the path in grid maps, which in turn has further reduced turning-angles and makes the path smoother. Besides, an improved A* algorithm that can effectively decrease path turns is presented to escape the deadlock. Simulations are carried out in different environments in this work. The results show that the coverage path generated by the CCNN algorithm has less turning-angle accumulation, deadlocks, and calculation time. In addition, the CCNN algorithm is capable to maintain the covering direction and adapt to complex environments, while effectively escapes deadlocks. It is applicable for USVs to perform multiple engineering missions.
Fungal Keratitis Due to Fusarium lichenicola: A Case Report and Global Review of Fusarium lichenicola Keratitis
Authors: Halim Isra , Singh Prabhakar , Sarfraz Asim , Kokkayil Prathyusha , Pati Binod Kumar , Thakuria Bhaskar , Raj Amit
Published: October 2021

Fusarium species are among the most commonly isolated causes of fungal keratitis. Most species of the genus Fusarium belong to Fusarium solani species complex (FSSC). Fusarium lichenicola, a member of the FSSC complex, is a well-established plant and human pathogen. However, reports of fungal keratitis due to Fusarium lichenicola have not been frequently reported. To the best of our knowledge, only twelve cases of Fusarium lichenicola keratitis have been reported in the past fifty years. Clinical cases of Fusarium lichenicola may have most likely been misidentified because of the lack of clinical and microbiological suspicion, as well as inadequate diagnostic facilities in many tropical countries where the burden of the disease may be the highest. We report a case of fungal keratitis caused by Fusarium lichenicola and present a global review of the literature of all cases of fungal keratitis caused by this potentially blinding fungus.
Phosphorus Starvation- and Zinc Excess-Induced Astragalus sinicus AsZIP2 Zinc Transporter Is Suppressed by Arbuscular Mycorrhizal Symbiosis
Authors: Xie Xianan , Fan Xiaoning , Chen Hui , Tang Ming
Published: October 2021

Zinc (Zn) is one of the most essential micronutrients for plant growth and metabolism, but Zn excess can impair many basic metabolic processes in plant cells. In agriculture, crops often experience low phosphate (Pi) and high Zn double nutrient stresses because of inordinate agro-industrial activities, while the dual benefit of arbuscular mycorrhizal (AM) fungi protects plants from experiencing both deficient and toxic nutrient stresses. Although crosstalk between Pi and Zn nutrients in plants have been extensively studied at the physiological level, the molecular basis of how Pi starvation triggers Zn over-accumulation in plants and how AM plants coordinately modulate the Pi and Zn nutrient homeostasis remains to be elucidated. Here, we report that a novel AsZIP2 gene, a Chinese milk vetch (Astragalus sinicus) member of the ZIP gene family, participates in the interaction between Pi and Zn nutrient homeostasis in plants. Phylogenetic analysis revealed that this AsZIP2 protein was closely related to the orthologous Medicago MtZIP2 and Arabidopsis AtZIP2 transporters. Gene expression analysis indicated that AsZIP2 was highly induced in roots by Pi starvation or Zn excess yet attenuated by arbuscular mycorrhization in a Pi-dependent manner. Subcellular localization and heterologous expression experiments further showed that AsZIP2 encoded a functional plasma membrane-localized transporter that mediated Zn uptake in yeast. Moreover, overexpression of AsZIP2 in A. sinicus resulted in the over-accumulation of Zn concentration in roots at low Pi or excessive Zn concentrations, whereas AsZIP2 silencing lines displayed an even more reduced Zn concentration than control lines under such conditions. Our results reveal that the AsZIP2 transporter functioned in Zn over-accumulation in roots during Pi starvation or high Zn supply but was repressed by AM symbiosis in a Pi-dependent manner. These findings also provide new insights into the AsZIP2 gene acting in the regulation of Zn homeostasis in mycorrhizal plants through Pi signal.
Characterization of Biomarkers in Colorectal Cancer Liver Metastases as a Prognostic Tool
Authors: Michal Sternschuss , Tal Goshen-Lago , Gali Perl , Miki Goldenfeld , Elana Brook , Baroch Brenner , Hanoch Kashtan , Irit Ben Aharon , Riad Haddad
Published: October 2021

Background: Unfortunately, the majority of patients with colorectal cancer liver metastases (CRCLM) experience disease recurrence following hepatic surgery. The key challenge is therefore optimal patient selection, which currently relies on anatomical and clinical parameters. Exploring a potential molecular signature may be predictive for seeing a clinical benefit from CRCLM resection. Methods: Consecutive patients who underwent CRCLM resection at our medical center between 2006 and 2016 were divided into cohorts of “good prognosis” (GP) or “poor prognosis” (PP) based on the time interval between their resection and disease recurrence. Proteomic analysis was performed on the surgical specimen and correlation analysis was carried out with demographics and clinical outcomes. Results: Proteomic analysis revealed 99 differentially expressed proteins of which a third were associated with extracellular matrix (ECM) pathways as the matrix metalloproteinases (MMPs). Multivariate analysis yielded a statistically differential proteomic pattern between the cohort regardless of perioperative treatment. Conclusion: Our results indicate a different proteomic landscape in the cohort of patients who had a clinical benefit from CRCLM resection which appears to be correlated with ECM pathways. Further prospective studies are needed to define the role of ECM pathways in prognostics and patient selection for surgical procedures for CRCLM.
Severe Anaphylaxis in Pregnancy: A Systematic Review of Clinical Presentation to Determine Outcomes
Authors: Simionescu Anca Angela , Danciu Bianca Mihaela , Stanescu Ana Maria Alexandra
Published: October 2021

Anaphylactic reactions during pregnancy can range from subjective cutaneous symptoms to anaphylaxis and lethal anaphylactic shock. The fetal and maternal outcomes are unpredictable. This study is the first systematic review of the clinical presentation of severe anaphylaxis in pregnancy as defined by the World Allergy Organization to determine maternal and fetal outcomes. We searched PubMed, the Web of Science, and Scopus databases for articles published between 1 January 1985 and 15 April 2021 using the following terms (((anaphylactic shock) AND (pregnancy)) OR ((anaphylaxis) AND (pregnancy))). In 42 studies involving 47 patients, 36.17% of patients were 31–35 years old, and 74.47% of cases occurred peripartum, mostly during cesarean section. Accurate diagnosis with valid and reliable outcome measures was reported for 71.74% of cases. Twenty-two allergens were identified: antibiotics (penicillins and cephalosporins), anesthetic drugs (suxamethonium, mepivacaine), latex, oxytocin, sodium and sucrose iron, laminaria, misoprostol, rubber from Foley catheter, oral phytomenadione, ranitidine, chamomile, and ant sting. Two cases of maternal death related to latex and intravenous iron sucrose, and six infants with neurological disease were reported, mostly related to antibiotics. This review of the currently available literature shows that favorable outcomes are attainable with a high degree of observation, multidisciplinary cooperation, and rapid treatment.
Managing Financial Risks while Performing International Commercial Transactions. Intertemporal Lessons from Athens in Classical Times
Authors: Economou Emmanouil M. L. , Kyriazis Nikolaos A. , Kyriazis Nicholas C.
Published: October 2021

In this paper, we mainly focus on two institutional aspects that are related to financial risk, that is, profiteering and the use of non-fraudulent coins when performing financial transactions. We argue that these two prerequisites were important for the success of the commercially oriented economy of the Athenian state in comparison with its allies in the East Mediterranean during the classical period. In particular, we briefly explain the structure of the Athenian economy, and then we focus on the agoranomoi and the dokimastai, the two main financial institutions related to (i) measures against profiteering and (ii) ensuring the purity of the currency when performing commercial transactions. Then, following a game theoretical approach, we provide a fictional example as to how the two institutions functioned in practice. Our findings confirm that these institutions were crucial in reducing financial risk when performing international commercial transactions, since they provided symmetrical information on the quality and purity of the currencies circulating in the Athenian economy. In the case of the Athenian state, we further convey that measures against profiteering and the use of unadulterated currency comprise intertemporal axioms, in the sense that their importance is not merely a phenomenon of modern times, but rather, on the contrary, one that dates back to much earlier times.
Forecasting Stochastic Volatility Characteristics for the Financial Fossil Oil Market Densities
Authors: Solibakke Per Bjarte
Published: October 2021

This paper builds and implements multifactor stochastic volatility models for the international oil/energy markets (Brent oil and WTI oil) for the period 2011–2021. The main objective is to make step ahead volatility predictions for the front month contracts followed by an implication discussion for the market (differences) and observed data dependence important for market participants, implying predictability. The paper estimates multifactor stochastic volatility models for both contracts giving access to a long-simulated realization of the state vector with associated contract movements. The realization establishes a functional form of the conditional distributions, which are evaluated on observed data giving the conditional mean function for the volatility factors at the data points (nonlinear Kalman filter). For both Brent and WTI oil contracts, the first factor is a slow-moving persistent factor while the second factor is a fast-moving immediate mean reverting factor. The negative correlation between the mean and volatility suggests higher volatilities from negative price movements. The results indicate that holding volatility as an asset of its own is insurance against market crashes as well as being an excellent diversification instrument. Furthermore, the volatility data dependence is strong, indicating predictability. Hence, using the Kalman filter from a realization of an optimal multifactor SV model visualizes the latent step ahead volatility paths, and the data dependence gives access to accurate static forecasts. The results extend market transparency and make it easier to implement risk management including derivative trading (including swaps).
The Legal, Administrative, and Governance Frameworks of Spatial Policy, Planning, and Land Use: Interdependencies, Barriers, and Directions of Change
Authors: Nowak Maciej , Cotella Giancarlo , Śleszyński Przemysław
Published: October 2021

The article provides an overview of the legal and administrative aspects of spatial governance and planning and of the related challenges. The legal dimension of spatial planning, administrative spatial planning traditions, as well as different frameworks and conditions for the governance of territorial regions are briefly introduced. On this basis, the various contributions that compose the special issue are framed and presented to the readers. In conclusion, a number of directions for further research are identified. Overall, the article serves as an editorial introduction and the various issues it touches upon are further specified in the individual contributions the compose the special issue.
Exploring Spatiotemporal Variation of Carbon Storage Driven by Land Use Policy in the Yangtze River Delta Region
Authors: Cai Wenbo , Peng Wanting
Published: October 2021

Land use/land cover (LULC) change driven by land use policy always leads to dramatic change in carbon storage and sequestration, especially in a rapidly urbanizing region. However, few studies explored the influences of land use polices on carbon storage and sequestration in a rapidly urbanizing region. Through Integrated Valuation of Ecosystem Services and Tradeoffs (InVEST) model, the spatial-temporal pattern of carbon storage altered by LULC transformation and its linkage with land use policies were analyzed in five periods (1990–1995, 1995–2000, 2000–2005, 2000–2010, 2010–2015) in the Yangtze River Delta (YRD) Region. The results indicated that: (1) the carbon storage in the YRD was substantially altered by continuous LULC transformation, totally decreased by 1.49 × 107 Mg during 1990–2015. (2) The total amount of carbon storage increased from 2.91 × 109 Mg in 1990 to 2.95 × 109 Mg in 1995, and then decreased to 2.90 × 109 Mg in 1995–2015. Thus, the total economic value of carbon storage increased approximately from 467.42 million dollars in 1990 to 472.99 million dollars in 1995, and then decreased to 465.01 million dollars in 2015. (3) The carbon storage and sequestration were influenced by LULC transformation driven by land use policies in five periods: large areas of grassland converted to woodland in 1990–1995 led by Forest Law, then clustered areas of cropland converted to built-up land in 1995–2015 around large cities of YRD Region led by Land Management Law and Development Plans, and finally, the conversion of cropland to built-up land was decreased and scattered in the entire region influenced by land use polices led by early stage of ecocivilization construction. The study can facilitate to develop regional land use policy for carbon storage conservation and carbon neutrality in a rapidly urbanizing region.
N,N-Bis(4′-(hexyloxy)-[1,1′-biphenyl]-4-yl)thiophen-2-amine
Authors: Chmovzh Timofey N. , Rakitin Oleg A.
Published: October 2021

N,N-Diarylthiophen-2-amine units are of great interest for the synthesis of optoelectronic devices. In this communication, N,N-bis (4′-(hexyloxy)-[1,1′-biphenyl]-4-yl)thiophen-2-amine was obtained by means of a Buchwald–Hartwig cross-coupling reaction of bis(4′-(hexyloxy)-[1,1′-biphenyl]-4-yl)amine and 2-bromothiophene in the presence of tris(dibenzylideneacetone)dipalladium(0), tri-tert-butyl phosphine and sodium tert-butanolate. The structure of newly synthesized compounds was established by means of elemental analysis, high-resolution mass spectrometry, 1H, 13C NMR, IR and UV spectroscopy and mass-spectrometry.
Detection and Quantification of Precious Elements in Astrophyllite Mineral by Optical Spectroscopy
Authors: Ahmad Altaf , Abbasi Shahab Ahmed , Hafeez Muhammad , Khan Taj Muhammad , Rafique Muhammad , Ahmed Nasar , Ahmad Pervaiz , Faruque Mohammad Rashed Iqbal , Khandaker Mayeen Uddin , Javed Muhammad
Published: October 2021

With many advantages over well-established methods, laser induced breakdown spectroscopy (LIBS) has emerged as a useful analytical technique for the compositional analysis of multi-elemental geological materials. In this study, LIBS was employed for qualitative and quantitative analysis of a rare mineral, astrophyllite, bearing precious elements of industrial and technological interest. The experiment was carried out using second harmonic generation of Nd:YAG laser of pulse width 5 ns and repetition rate of 10 Hz. Microplasma was produced by focusing laser beam on an astrophyllite target, and optical emissions from the generated plasma were recorded in the spectral range of 200–720 nm with the help of a LIBS2000+ detection system. On analyzing the optical spectra, existence of 15 elements in astrophyllite target were revealed. These elements include: Ti, W, Ag, Al, Ba, Ca, Cr, Cu, Fe, Li, Mg, Na, Ni, Si and H. For quantification, calibration-free method was used. Only ten elements, namely Ti, W, Fe, Cr, Cu, Ca, Mg, Ni, Si and Al, were quantified with relative weight concentrations of 55.39%, 18.79%, 18.30%, 4.05%, 2.66, 0.43%, 0.18%, 0.12%, 0.06% and 0.02%, respectively. To benchmark these results, XRF analysis was performed, which confirmed the presence of all the elements detected in the optical spectrum of the sample, except for Na, Li, and H. The concentrations of these ten elements as measured by XRF were in reasonable agreement, especially for the major elements. The presence of a significant amount of Ti and W in an astrophyllite sample, found in Pakistan, highlights the economic value of this mineral. This study may be of further interest in commissioning LIBS technology for exploration of minerals in the region.
The Electrical and Thermal Transport Properties of La-Doped SrTiO3 with Sc2O3 Composite
Authors: Guo Kai , Yang Fan , Weng Tianyao , Chen Jianguo , Zhang Jiye , Luo Jun , Li Han , Rao Guanghui , Zhao Jingtai
Published: October 2021

Donor-doped strontium titanate (SrTiO3) is one of the most promising n-type oxide thermoelectric materials. Routine doping of La at Sr site can change the charge scattering mechanism, and meanwhile can significantly increase the power factor in the temperature range of 423–773 K. In addition, the introduction of Sc partially substitutes Sr, thus further increasing the electron concentration and optimizing the electrical transport properties. Moreover, the excess Sc in the form of Sc2O3 composite suppresses multifrequency phonon transport, leading to low thermal conductivity of κ = 3.78 W·m−1·K−1 at 773 K for sample Sr0.88La0.06Sc0.06TiO3 with the highest doping content. Thus, the thermoelectric performance of SrTiO3 can be significantly enhanced by synergistic optimization of electrical transport and thermal transport properties via cation doping and composite engineering.
Archaeological and Chemical Investigation on Mortars and Bricks from a Necropolis in Braga, Northwest of Portugal
Authors: Fragata Ana , Candeias Carla , Ribeiro Jorge , Braga Cristina , Fontes Luís , Velosa Ana , Rocha Fernando
Published: October 2021

This investigation intends to study and characterize the mortars and bricks from walls and floors used in the funerary nucleus of the archaeological site of Dr. Gonçalo Sampaio Street (Braga, Portugal), associated with the Via XVII necropolis of the Bracara Augusta Roman city. The diversity of the funeral structures and their exceptional state of conservation make this sector of the necropolis an unprecedented case and a reference site in the archaeology of Braga, a determinant for its conservation and musealization. Nineteen mortars samples were analysed by X-ray Fluorescence. The results showed clear chemical composition differences among coating and floor mortars (CFM), masonry mortars (MM) and bricks (B) groups of samples. The chemical affinity between CFM from the V to IV centuries, CFM from the IV to V centuries, MM from brick walls (IV–V centuries), MM from stone walls (V–VII centuries) and B from the IV to V centuries samples were confirmed by statistical analyses. Their composition was distinctly related to the use of different raw materials, according to their chronological context; in mortars, according to their function in the structures; and in some samples, from contamination.
Development and Characteristics of Aerated Alkali-Activated Slag Cement Mixed with Zinc Powder
Authors: Kim Taewan , Kang Choonghyun , Seo Kiyoung
Published: October 2021

Experiments on the development and properties of aerated concrete based on alkali-activated slag cement (AASC) and using Zn powder (ZP) as a gas agent were carried out. The experiments were designed for water-binding material (w/b) ratios of 0.35 and 0.45, curing temperatures of 23 ± 2 °C and 40 ± 2 °C, and ZP of 0.25%, 0.50%, 0.75%, and 1.0%. ZP generates hydrogen (H2) gas in AASC to form pores. At a w/b of 0.35, the curing temperature had little effect on the pore size by ZP. However, a w/b of 0.45 showed a clear correlation that the pore diameter increased as the curing temperature increased. The low w/b of 0.35 showed a small change in the pore size according to the curing temperature due to the faster setting time than 0.45 and the increased viscosity of the paste. Therefore, at a termination time exceeding at least 60 min and a w/b of 0.45 or more, it was possible to increase the size and expansion force of the pores formed by the ZP through the change of the curing temperature. ZP showed applicability to the manufacture of AASC-based aerated concrete, and the characteristics of foaming according to the curing temperature, w/b ratio, and ZP concentration were confirmed.
Possible Evidence for Berezinskii–Kosterlitz–Thouless Transition in Ba(Fe0.914Co0.086)2As2 Crystals
Authors: Jiao Wen-He , Xu Xiao-Feng , Jiang Hao , Xu Zhu-An , Chen Qing-Hu , Cao Guang-Han
Published: October 2021

In this study, we measure the in-plane transport properties of high-quality Ba(Fe0.914Co0.086)2As2 single crystals. Signatures of vortex unbinding Berezinskii–Kosterlitz–Thouless (BKT) transition are shown from both the conventional approach and the Fisher–Fisher–Huse dynamic scaling analysis, in which a characteristic Nelson–Kosterlitz jump is demonstrated. We also observe a non-Hall transverse signal exactly at the superconducting transition, which is explained in terms of guided motion of unbound vortices.
Fabrication and Characterization of PCL/PLGA Coaxial and Bilayer Fibrous Scaffolds for Tissue Engineering
Authors: Bazgir Morteza , Zhang Wei , Zhang Ximu , Elies Jacobo , Saeinasab Morvarid , Coates Phil , Youseffi Mansour , Sefat Farshid
Published: October 2021

Electrospinning is an innovative new fibre technology that aims to design and fabricate membranes suitable for a wide range of tissue engineering (TE) applications including vascular grafts, which is the main objective of this research work. This study dealt with fabricating and characterising bilayer structures comprised of an electrospun sheet made of polycaprolactone (PCL, inner layer) and an outer layer made of poly lactic-co-glycolic acid (PLGA) and a coaxial porous scaffold with a micrometre fibre structure was successfully produced. The membranes’ propriety for intended biomedical applications was assessed by evaluating their morphological structure/physical properties and structural integrity when they underwent the degradation process. A scanning electron microscope (SEM) was used to assess changes in the electrospun scaffolds’ structural morphology such as in their fibre diameter, pore size (μm) and the porosity of the scaffold surface which was measured with Image J software. During the 12-week degradation process at room temperature, most of the scaffolds showed a similar trend in their degradation rate except the 60 min scaffolds. The coaxial scaffold had significantly less mass loss than the bilayer PCL/PLGA scaffold with 1.348% and 18.3%, respectively. The mechanical properties of the fibrous membranes were measured and the coaxial scaffolds showed greater tensile strength and elongation at break (%) compared to the bilayer scaffolds. According to the results obtained in this study, it can be concluded that a scaffold made with a coaxial needle is more suitable for tissue engineering applications due to the improved quality and functionality of the resulting polymeric membrane compared to the basic electrospinning process. However, whilst fabricating a vascular graft is the main aim of this research work, the biological data will not present in this paper.
Effect of Different Tool Probe Profiles on Material Flow of Al–Mg–Cu Alloy Joined by Friction Stir Welding
Authors: Naumov Anton , Rylkov Evgenii , Polyakov Pavel , Isupov Fedor , Rudskoy Andrey , Aoh Jong-Ning , Popovich Anatoly , Panchenko Oleg
Published: October 2021

Friction Stir Welding (FSW) was utilized to butt−join 2024–T4 aluminum alloy plates of 1.9 mm thickness, using tools with conical and tapered hexagonal probe profiles. The characteristic effects of FSW using tools with tapered hexagonal probe profiles include an increase in the heat input and a significant modification of material flow, which have a positive effect on the metallurgical characteristics and mechanical performance of the weld. The differences in mechanical properties were interpreted through macrostructural changes and mechanical properties of the welded joints, which were supported by numerical simulation results on temperature distribution and material flow. The material flow resulting from the tapered hexagonal probe was more complicated than that of the conical probe. If in the first case, the dynamic viscosity and strain rate are homogeneously distributed around the probe, but in the case of the tapered hexagonal probe tool, the zones with maximum values of strain rates and minimum values of dynamic viscosity are located along the six tapered edges of the probe.
Electrodeposition of Hybrid Magnetostrictive/Magnetoelectric Layered Systems
Authors: Abad Sara , Prados Alicia , Maicas Marco , Biskup Neven , Varela Maria , Ranchal Rocio
Published: October 2021

The potential use of electrodeposition to synthesize a hybrid magnetostrictive/magnetoelectric layered system is shown in this paper. By appropriately adjusting pH, growth potential, and electrolyte composition, it is possible to achieve thin films in which magnetoelectric oxide GaFeO3 (GFO) is formed in close contact with magnetostrictive metallic FeGa alloy. X-ray diffractometry shows the formation of FeGa as well as GFO and Fe oxides. Electron microscopy observations reveal that GFO mainly segregates in grain boundaries. Samples are ferromagnetic with an isotropic magnetic behavior in the sample plane. Magnetic stripes are observed by magnetic force microscopy and are correlated to Fe3O4. When its segregation is minimal, the absence of stripes can be used to monitor Fe oxide segregation.
A Review of Friction Performance of Lubricants with Nano Additives
Authors: Waqas Muhammad , Zahid Rehan , Bhutta Muhammad Usman , Khan Zulfiqar Ahmad , Saeed Adil
Published: October 2021

It has been established in literature that the addition of nanoparticles to lubricants at an optimum concentration results in a lower coefficient of friction compared to lubricants with no nanoparticle additives. This review paper shows a comparison of different lubricants based on the COF (coefficient of friction) with nanoadditives. The effect of the addition of nanoparticles on the friction coefficient was analyzed for both synthetic and biolubricants separately. The limitations associated with the use of nanoparticles are explained. The mechanisms responsible for a reduction in friction when nanoparticles are used as an additive are also discussed. Various nanoparticles that have been most widely used in recent years showed good performance within lubricants, including CuO (copper oxide), MoS2 (molybdenum disulfide), and TiO2 (titanium dioxide). The paper also indicates some research gaps that need to be addressed.
s-Sequences and Monomial Modules
Authors: Failla Gioia , Staglianó Paola Lea
Published: October 2021

In this paper we study a monomial module M generated by an s-sequence and the main algebraic and homological invariants of the symmetric algebra of M. We show that the first syzygy module of a finitely generated module M, over any commutative Noetherian ring with unit, has a specific initial module with respect to an admissible order, provided M is generated by an s-sequence. Significant examples complement the results.
Risk Transfer in an Electricity Market
Authors: Rodriguez David Esteban , Trespalacios Alfredo , Galeano David
Published: October 2021

Energy is traded using different products; long-term contracts or electricity forward contracts can assure the future transaction price. However, due to the difficulties in storing electrical energy for long periods and in large amounts, risks must be incorporated when defining contract prices through a Forward Risk Premia (FRP). This study analyzes the transfer of uncertainty from electricity market variables to the FRP in long-term contracts. We evaluate a type of econometric risk with the construction of Autoregressive Distributed Lag contagion models for the FRP using electricity demand, spot price, power generation via different technologies, and the Oceanic Niño Index. As a case study, we consider the Colombian electricity market. Our results show empirical models where the FRP has a short-term response with the following variables: hydropower generation, coal power generation, electricity demand, and Oceanic Niño Index, even though its transaction is reflected one or two years after the occurrence of the event.