bluuebunny/crossref_metadata_2025 huggingface dataset:
Investigation on the Atomic Mechanism for Grain Refinement of Magnesium Alloys by Mg-Zr Master Alloy
Authors: Zhang Aimin , Li Jing , Li Fenglin , Su Guang
Published: October 2022

The valence electron structure, bond energy, and cohesive energy of Mg, Zr, and α-Mg containing Zr, and α-Zr containing Mg crystals were calculated using the empirical electron theory of solids and molecules (EET). The calculation results show that the bond and cohesive energies of Zr were much greater than those of Mg, so Zr particles could precipitate ahead of α-Mg in general magnesium alloy melts or insoluble Zr particles exist when the magnesium melt temperature is relatively low. The bond energy of α-Zr decreases with the increase in Mg content; therefore, at the end of the growth of Zr particles, the remaining Zr atoms in the melt exist in the form of Mg-Zr clusters. In order to reduce the surface energy of Zr particles, the outer surface of Zr particles tends to terminate with a Zr-Mg atomic layer, that is, a stable two-dimensional Zr-Mg atomic layer is formed first on the (0001) crystal surface of the outermost surface of Zr particles. Furthermore, on the basis of the calculated results, a complementary criterion to the edge-to-edge model of heterogeneous nucleation is also proposed. {ure and single Zr particles cannot become the heterogeneous nucleus of α-Mg, but when there is an atomic layer of two-dimensional Zr-Mg on its surface, the nucleation of particles can be activated. Mg atoms in the liquid phase preferentially attach to the Zr-Mg/Mg-Zr atomic layer on the surface of Zr particles to grow and form a stable ordered structure, which lastly transforms Zr particles into efficient heterogeneous cores.
Testing and Evaluation of Flexural Tensile Strength of Prestressed CFRP Cables
Authors: Xia Jiajun , Xu Zhirong , Zhuge Ping , Wang Bing , Cai Wanyun , Fu Jiaping
Published: October 2022

To expand the application scope of prestressed carbon fiber-reinforced polymer (CFRP) cables in civil engineering, the ultimate tensile strength of these cables was tested and evaluated under bending conditions. First, the study analyzed the tensile failure mechanism of CFRP cables under bending conditions based on elastic bending analysis theory. Thereafter, the ultimate stress state of individual tendons and cables was derived and a calculation model for the tensile strength of bent CFRP cables was established. Second, 14 sets of test conditions were created for CFRP cables under bending angles of 20–40° and bending radii of 1.5–3 m. Then, bending tensile tests were conducted to evaluate the effects of the above factors on the ultimate tensile strength, and the correctness of the computational model was verified using experiments. Finally, the ultimate performance of CFRP cables was theoretically predicted using the established model. The results showed that the cable bending tensile strength was associated with the radius r, tensile strength f, and elastic modulus E of the reinforced material and the bending radius R, but was not correlated with the interface buffer material or the bending angle of the steering system. Moreover, the flexural tensile residual strength was only affected by R/r and E/f. When E/f involved conventional material parameters, the residual strength increased nonlinearly with increased R/r. When R/r ≥ 600, the residual strength reached more than 80%. Therefore, R/r at 600 could be used as the design basis for a safe critical radius.
The Stress−Dilatancy Behaviour of Artificially Bonded Soils
Authors: Szypcio Zenon , Dołżyk-Szypcio Katarzyna
Published: October 2022

In this study, the results of triaxial compression tests of some naturally and artificially bonded soils presented in the literature were analysed. It was shown that the three characteristic stages of plastic flow during shear can be identified. In all stages, the stress–dilatancy behaviour could be approximated by the general linear stress–dilatancy equation of the Frictional State Concept. For many shear tests, the failure states and newly defined dilatant failure states are not identical. The points representing dilatant failure states lie on a straight line, for which the position and slope in the η-D plane depend on the soil type and the amount of cement admixture. This line defines the critical frictional state angle, and its slope for bonded soils is greater than for unbonded soils.
Negative Magnetoresistivity in Highly Doped n-Type GaN
Authors: Konczewicz Leszek , Iwinska Malgorzata , Litwin-Staszewska Elzbieta , Zajac Marcin , Turski Henryk , Bockowski Michal , Schiavon Dario , Chlipała Mikołaj , Juillaguet Sandrine , Contreras Sylvie
Published: October 2022

This paper presents low-temperature measurements of magnetoresistivity in heavily doped n-type GaN grown by basic GaN growth technologies: molecular beam epitaxy, metal-organic vapor phase epitaxy, halide vapor phase epitaxy and ammonothermal. Additionally, GaN crystallized by High Nitrogen Pressure Solution method was also examined. It was found that all the samples under study exhibited negative magnetoresistivity at a low temperature (10 K < T < 50 K) and for some samples this effect was observed up to 100 K. This negative magnetoresistivity effect is analyzed in the frame of the weak localization phenomena in the case of three-dimensional electron gas in a highly doped semiconductor. This analysis allows for determining the phasing coherence time τφ for heavily doped n-type GaN. The obtained τφ value is proportional to T−1.34, indicating that the electron–electron interaction is the main dephasing mechanism for the free carriers.
Development of PZN-PMN-PZT Piezoelectric Ceramics with High d33 and Qm Values
Authors: Kim So-Won , Lee Hee-Chul
Published: October 2022

To achieve good long-term temperature stability in devices used in energy-conversion applications, this study is aimed at developing combined ceramics, referred to as PZN-PMN-PZT, comprising Pb(Zn1/3Nb2/3)O3 (PZN) and Pb(Mn1/3Nb2/3)O3 (PMN), which are typical relaxor ferroelectric materials, and Pb(Zr,Ti)O3 (PZT). The piezoelectric properties were compared based on several parameters according to the change in the composition ratio between relaxor materials, amounts of Sb2O3 dopant, and Zr/Ti ratio in the PZT system. Finally, we established optimal poling conditions to improve the electrical properties of the optimized piezoelectric material, based on the evaluation of ceramic properties according to the applied voltage during the poling process. The optimized composition of the investigated piezoelectric ceramics is represented by 0.14PZN-0.06PMN-0.80PbZr0.49Ti0.51 + 0.3 wt.% CuO + 0.3 wt.% Fe2O3 with 0.1 wt.% Sb2O3 doping, which yielded the superior properties (d33 = 361 pC/N, Qm = 1234, Tc = 306 °C).
Effect of Different Etching Times with Hydrofluoric Acid on the Bond Strength of CAD/CAM Ceramic Material
Authors: Avram Liane Tabitha , Galațanu Sergiu-Valentin , Opriș Carmen , Pop Cristian , Jivănescu Anca
Published: October 2022

The objective of this study was to evaluate the influence of hydrofluoric acid (HF) and conditioning time on the micro-shear bond strength (µSBS) between dual-cure resin cement and glass-ceramic materials, such as lithium disilicate ceramic (IPS e.max CAD, Ivoclar Vivadent) (EX) and leucite-reinforced ceramic (IPS Empress CAD, Ivoclar Vivadent) (EP), and also a hybrid ceramic (Vita Enamic, Vita Zahnfabrik) (VE). Eighteen sections with 1 mm thickness were cut from each CAD/CAM material and randomly divided into three groups, according to the surface etching time (30 s, 60 s, 90 s). The surface treatment was performed using 9.5% HF acid gel, then resin cement was applied on the prepared ceramic plates and light cured. µSBS values between resin cement and the ceramic material were measured with a universal testing machine at a crosshead speed of 0.5 mm/min until the failure occurred. The fractured surfaces of specimens were microscopically evaluated, and failure modes were classified as: adhesive between resin cement and ceramic, cohesive within ceramic or cement and mixed failure. Surface roughness of etched samples was examined using a scanning electron microscope. Obtained data were statistically analysed using one-way analysis of variance (ANOVA) and Bonferroni post hoc test with a level of significance α = 0.05. The results of the statistical methods applied indicate that µSBS mean difference for leucite-reinforced ceramic (EP) was statistically significant (p < 0.05). However, µSBS values for hybrid ceramic (VE) and lithium disilicate ceramic (EX) were not affected, from a statistical point of view, by the conditioning time (p > 0.05).
Stress-Induced Microcracking and Fracture Characterization for Ultra-High-Temperature Ceramic Matrix Composites at High Temperatures
Authors: Gu Mingyu , Wu Chunyan , Chen Xingyu , Wan Yu , Liu Yumeng , Zhou Shan , Cai Hongwei , Jia Bi , Wang Ruzhuan , Li Weiguo
Published: October 2022

In this paper, we estimated the temperature-dependent critical inclusion size for microcracking under residual stress and applied stress for particulate-reinforced ultra-high-temperature ceramic matrix composites. The critical flaw size and applied stress for the stable growth of radial cracks under different temperatures were also estimated. It was found that under a lower applied stress, the critical inclusion size was sensitive to the temperature. Under higher applied stresses, the sensitivity became smaller. For ceramic materials with pre-existing microcracks, the crack resistance could be improved by increasing the service stress when the service stress was low. As the temperature increased, the critical flaw size of the materials decreased; the applied stress first increased and then decreased. Finally, a temperature-dependent fracture strength model of composites with a pre-existing critical flaw was proposed. A good agreement was obtained between the model prediction and the experimental data. In this work, we show a method for the characterization of the effects of temperature on the fracture behavior of ceramic-based composites.
Tribological Behavior of PEEK/PTFE Composites Reinforced with Carbon Fibers and Graphite
Authors: Li Yingji , Chen Yi , Guo Yongxin , Bian Da , Zhao Yongwu
Published: October 2022

In this study, poly (ether ether ketone) (PEEK)/polytetrafluoroethylene (PTFE) composites reinforced with carbon fibers (CFs) and graphite (Gr) were fabricated by compressive molding technology. The friction and wear properties of the PEEK/PTFE composites sliding against Si3N4 balls were investigated using ball-on-disk configuration under dry sliding conditions, and the morphologies of the worn surfaces were also observed with a scanning electron microscope (SEM) and a three-dimensional morphometer. The results indicated that the introduction of CFs significantly improved the tribological properties of the composites, but the friction coefficient of the PEEK/PTFE/CFs composites were higher than the pure PEEK/PTFE composites. However, it was found that a combinative addition of CFs and Gr creates an obvious synergetic effect of improving the friction-reducing and anti-wear abilities of the composites. The mechanisms of the improved tribological properties of the PEEK/PTFE/CFs/Gr composites were discussed based on the analysis of the worn surfaces and tribofilms.
Huber Regression Analysis with a Semi-Supervised Method
Authors: Wang Yue , Wang Baobin , Peng Chaoquan , Li Xuefeng , Yin Hong
Published: October 2022

In this paper, we study the regularized Huber regression algorithm in a reproducing kernel Hilbert space (RKHS), which is applicable to both fully supervised and semi-supervised learning schemes. Our focus in the work is two-fold: first, we provide the convergence properties of the algorithm with fully supervised data. We establish optimal convergence rates in the minimax sense when the regression function lies in RKHSs. Second, we improve the learning performance of the Huber regression algorithm by a semi-supervised method. We show that, with sufficient unlabeled data, the minimax optimal rates can be retained if the regression function is out of RKHSs.
A Study of Generalized QL′-Implications
Authors: Grammatikopoulos Dimitrios S. , Papadopoulos Basil
Published: October 2022

In this paper, we introduce and study the GQL′-operations. We prove that this class is a hyper class of the known class of QL′-operations. Similar to QL′-operations, GQL′-operations are not always fuzzy implications. On the other hand, we present and prove a necessary but not sufficient condition that leads to the generation of a GQL′-implication. Our study is completed by studying the satisfaction or the violation of some basic properties of fuzzy implications, such as the left neutrality property, the exchange principle, the identity principle and the left ordering property. Our study also completes the study of the aforementioned basic properties for QL′-implications and leads to a new connection between QL-operations and D′-operations.
Vehicle and UAV Collaborative Delivery Path Optimization Model
Authors: Li Jianxun , Liu Hao , Lai Kin , Ram Bhagwat
Published: October 2022

In the context of frequent public emergencies, emergency logistics distribution is particularly critical, and because of the unique advantages of unmanned aerial vehicles (UAVs), the model of coordinated delivery of vehicles and UAVs is gradually becoming an essential form of emergency logistics distribution. However, the omission of start-up costs prevents the cost of UAV battery replacement and the sorting, assembly and verification of packages from being factored into the total cost. Furthermore, most existing models focus on route optimization and delivery cost, which cannot fully reflect the customer’s desire for service satisfaction under emergency conditions. It is necessary to convert the unsatisfactory degree of time window into a penalty cost rather than a model constraint. Additionally, there is a lack of analysis on the mutual waiting cost between vehicles and UAVs when one of them is performing delivery tasks. Considering the effects of the time window, customer demand, maximum load capacity, and duration of distribution benefits, we propose a collaborative delivery path optimization model for vehicles and UAVs to minimize the total distribution cost. A genetic algorithm is used to obtain the model solution under the constraints of distribution subloops, distribution order, and take-off and landing nodes. To assess the efficacy of the vehicle and UAV collaborative delivery path optimization model, this paper employs a county-level district in Xi’an city as a pilot area for an emergency delivery. Compared with the vehicle-alone delivery model, the UAV-alone delivery model and vehicle-UAV collaborative delivery model, this model can significantly reduce the utilization of distribution vehicles while also significantly lowering the start-up cost, waiting cost and penalty cost. Thus, the model can effectively improve delivery timeliness and customer satisfaction. The total cost of this model is 39.2% less than that of the vehicle-alone delivery model and 16.5% less than that of the UAV-alone delivery model. Although its delivery cost is slightly higher than the vehicle-UAV collaborative delivery model, the reduction in the start-up cost and penalty cost decrease the overall cost of distribution by 11.8%. This suggests that to cut costs of all sizes and conserve half of the resources used by vehicles, employing the vehicle-UAV collaborative delivery model for emergency distribution is preferable. Moreover, the model integrating the start-up cost, penalty cost, waiting cost, etc., can more effectively express the requirements of timeliness for UAV delivery under emergency conditions.
Perilipin Isoforms and PGC-1α Are Regulated Differentially in Rat Heart during Pregnancy-Induced Physiological Cardiac Hypertrophy
Authors: Rosas-Rodríguez Jesús A. , Virgen-Ortíz Adolfo , Ruiz Enrico A. , Ortiz Rudy M. , Soñanez-Organis José G.
Published: October 2022

Background and Objectives: Perilipins 1–5 (PLIN) are lipid droplet-associated proteins that participate in regulating lipid storage and metabolism, and the PLIN5 isoform is known to form a nuclear complex with peroxisome proliferator-activated receptor-gamma coactivator 1-alpha (PGC-1α) to regulate lipid metabolism gene expression. However, the changes in PLIN isoforms’ expression in response to pregnancy-induced cardiac hypertrophy are not thoroughly studied. The aim of this study was to quantify the mRNA expression of PLIN isoforms and PGC-1α along with total triacylglycerol (TAG) and cholesterol levels during late pregnancy and the postpartum period in the rat left ventricle. Materials and Methods: Female Sprague-Dawley rats were divided into three groups: non-pregnant, late pregnancy, and postpartum. The mRNA and protein levels were evaluated using quantitative RT-PCR and Western blotting, respectively. TAG and total cholesterol content were evaluated using commercial colorimetric methods. Results: The expression of mRNAs for PLIN1, 2, and 5 increased during pregnancy and the postpartum period. PGC-1α mRNA and protein expression increased during pregnancy and the postpartum period. Moreover, TAG and total cholesterol increased during pregnancy and returned to basal levels after pregnancy. Conclusions: Our results demonstrate that pregnancy upregulates differentially the expression of PLIN isoforms along with PGC-1α, suggesting that together they might be involved in the regulation of the lipid metabolic shift induced by pregnancy.
Automatic Plaque Removal Using Dual-Energy Computed Tomography Angiography: Diagnostic Accuracy and Utility in Patients with Peripheral Artery Disease
Authors: Koo Byeong-Ju , Won Jung-Ho , Choi Ho-Cheol , Na Jae-Boem , Kim Ji-Eun , Park Mi-Jung , Jo Sa-Hong , Park Hyun-Oh , Lee Chung-Eun , Kim Mi-Ji , Park Sung-Eun
Published: October 2022

Background and Objectives: This study aimed to evaluate the utility and accuracy of dual-energy automatic plaque removal (DE-APR) in patients with symptomatic peripheral arterial disease (PAD) using digital subtraction angiography (DSA) as the reference standard. Materials and Methods: We retrospectively analyzed 100 patients with PAD who underwent DE computed tomography angiography (DE-CTA) and DSA of the lower extremities. DE-CTA was used to generate APR subtracted images. In the three main arterial segments (aorto-iliac segment, femoro-popliteal segment, and below-the-knee segment), the presence or absence of hemodynamically significant stenosis (>50%) and calcification was assessed using the images. CTA data were analyzed using different imaging approaches (DE-standard reconstruction image (DE-SR), DE-APR maximum intensity projection image (APR), and DE-SR with APR). Results: For all segments evaluated, the sensitivity, specificity, and accuracy for detecting significant stenosis were 98.16%, 81.01%, and 89.58%, respectively, with DE-SR; 97.79%, 83.33%, and 90.56%, respectively, with APR; and 98.16%, 92.25%, and 95.20%, respectively, with DE-SR with APR. DE-SR with APR had greater accuracy than DE-SR or APR alone (p < 0.001 and p < 0.001, respectively). When analyzed based on vascular wall calcification, the accuracy of DE-SR with APR remained greater than 90% regardless of calcification severity, whereas DE-SR showed a considerable reduction in accuracy in moderate to severe calcification. In the case of APR, the degree of vascular wall calcification did not significantly influence the accuracy in the aorto-iliac and femoro-popliteal segments. DE-SR with APR achieved significantly higher diagnostic accuracy for all lower extremity segments in evaluating hemodynamically significant stenosis in patients with symptomatic PAD and transcended the impact of vascular wall calcification compared with DE-SR. Conclusions: APR demonstrated favorable diagnostic performance in the aorto-iliac and femoro-popliteal segments, exhibiting good agreement with DSA even in cases of moderate to severe vascular wall calcification.
Physicochemical Characterization and Prospecting Biological Activity of Some Authentic Transylvanian Essential Oils: Lavender, Sage and Basil
Authors: Vârban Dan , Zăhan Marius , Pop Carmen Rodica , Socaci Sonia , Ștefan Răzvan , Crișan Ioana , Bota Loredana Elena , Miclea Ileana , Muscă Adriana Sebastiana , Deac Alexandru Marius , Vârban Rodica
Published: October 2022

Essential oils are a category of agro-based industrial products experiencing increasing demand. In this research, three essential oils obtained by steam distillation from lavender, sage and basil plants cultivated in temperate continental conditions of Transylvania were investigated for chemical composition, physical characteristics and biological activity (antimicrobial and cytotoxic effect on cancer cell lines). The number of identified compounds varied: 38 for lavender, 29 for sage essential oil and 41 for basil. The volatile profile was dominated by terpenes and terpenoids (>80%). Major components were beta-linalool and linalool acetate in lavender essential oil; thujones and camphor in sage essential oil; beta-linalool, thujone, camphor and eucalyptol in basil essential oil. Refractive index of the essential oils was lowest for lavender and highest for sage. Antibacterial activity was strongest for basil, moderate for lavender and weakest for sage essential oil. The most active on both colon adenocarcinoma (Caco-2) and ovary carcinoma (A2780) was sage essential oil.
Experimental Investigation on Part Quality and Dust Emission during Minimum Quantity Lubricated (MQL) Edge Finishing of Granite
Authors: Bahri Haithem , Songmene Victor , Kouam Jules
Published: October 2022

Edge-finishing of granites by grinding is a process frequently used in the granite processing industry to generate the final desired shape and edge quality of products. However, this process releases significant amounts of fine and ultrafine particles (FPs and UFPs) containing crystalline silica. When inhaled, this dust can cause silicosis disease and threaten the health and safety of workers. The purpose of this study is to optimize the process by decreasing the concentrations of dust generated while also maintaining the required surface finish. Experimental tests were planned and performed on granite samples using a full factorial design. Two cutting tool edge shapes were studied (chamfer and concave) using G150 and G600 grit size tools, at various spindle speeds (1500, 2500, 3500 rpm), feed rates (500, 1000, 1500 mm/min) and lubrication flow rates (20, 40, 60 mL/min). The findings show that the particle emissions as well as the surface finish depend on the tool shape, its grit size, and the machining and lubrication parameters used. Higher MQL flow rates led to better finished surface quality and lower concentrations of fine dust. Polishing with flood lubrication reduces the maximum number concentration of FPs corresponding to particles smaller than 1 µm diameter by about 85% as compared to dry polishing and produced the best surface finish. Polishing with lubrication in MQL mode at 60 mL/min led to the production of part with Ra-value comparable with that obtained in flood lubrication condition.
A Highly Accurate Method for Measuring Response Time of MEMS Thermopiles
Authors: Xiang Zeqing , Shi Meng , Zhou Na , Zhang Chenchen , Ding Xuefeng , Ni Yue , Chen Dapeng , Mao Haiyang
Published: October 2022

The response time is an important parameter for thermopiles sensors, which reflects the response speed of the device. The accurate measurement of response time is extremely important to evaluate device characteristics for using them in suitable scenarios. In this work, to accurately measure the response time of thermopile sensors, an Al microheater is integrated in a MEMS thermopile as an in situ heat source. Compared with the traditional chopper measurement method for response time, this approach avoids mechanical delay induced by chopper blades. Accordingly, based on this approach, the response time of the device is measured to be 6.9 ms, while that is 12.7 ms when a chopping system is used, demonstrating that an error of at least 5.8 ms is avoided. Such an approach is quite simple to realize and provides a novel route to accurately measure the response time.
Recent Synthetic Biology Approaches for Temperature- and Light-Controlled Gene Expression in Bacterial Hosts
Authors: Choi Jongdoo , Ahn Jiyeun , Bae Jieun , Koh Minseob
Published: October 2022

The expression of genes of interest (GOI) can be initiated by providing external stimuli such as temperature shifts and light irradiation. The application of thermal or light stimuli triggers structural changes in stimuli-sensitive biomolecules within the cell, thereby inducing or repressing gene expression. Over the past two decades, several groups have reported genetic circuits that use natural or engineered stimuli-sensitive modules to manipulate gene expression. Here, we summarize versatile strategies of thermosensors and light-driven systems for the conditional expression of GOI in bacterial hosts.
CO2 Sorbents Based on Spherical Carbon and Photoactive Metal Oxides: Insight into Adsorption Capacity, Selectivity and Regenerability
Authors: Pełech Iwona , Kusiak-Nejman Ewelina , Staciwa Piotr , Sibera Daniel , Kapica-Kozar Joanna , Wanag Agnieszka , Latzke Filip , Pawłowska Karolina , Michalska Adrianna , Narkiewicz Urszula , Morawski Antoni W.
Published: October 2022

This work aimed to obtain hybrid composites based on photoactive metal oxide and carbon having adsorption properties. The materials, composed of titanium dioxide or zinc oxide and spherical carbon, were obtained from resorcinol-formaldehyde resin, treated in a solvothermal reactor heated with microwaves and then subjected to carbonization, were received. The functional groups of pure carbon spheres (unsaturated stretching C=C, stretching C−OH and C−H bending vibrations), CS/ZnO and CS/TiO2 samples were determined by FT-IR analysis. The characteristic bands for ZnO and TiO2 were observed below 1000 cm−1. The thermal oxidative properties are similar for TiO2- and ZnO-modified carbon spheres. We have observed that the increased carbon sphere content in nanocomposites results in starting the decomposition process at a lower temperature, therefore, nanocomposites have a broader combustion temperature range. The effect of the oxides’ addition to carbon spheres on their adsorption properties was evaluated in detail by examining CO2 adsorption from the gas phase. The selectivity of CO2 over N2 at a temperature of 25 °C and pressure of 1 bar (a novelty in testing CS-based sorbents) calculated for 3.00 CS/TiO2 and 4.00 CS/ZnO was 15.09 and 16.95, respectively. These nanocomposites exhibit excellent cyclic stability checked over 10 consecutive adsorption–desorption cycles.
Molecular Engineering of Quinone-Based Nickel Complexes and Polymers for All-Organic Li-Ion Batteries
Authors: Danchovski Yanislav , Rasheev Hristo , Stoyanova Radostina , Tadjer Alia
Published: October 2022

All-organic Li-ion batteries appear to be a sustainable and safer alternative to the currently-used Li-ion batteries but their application is still limited due to the lack of organic compounds with high redox potentials toward Li+/Li0. Herein, we report a computational design of nickel complexes and coordination polymers that have redox potentials spanning the full voltage range: from the highest, 4.7 V, to the lowest, 0.4 V. The complexes and polymers are modeled by binding low- and high-oxidized Ni ions (i.e., Ni(II) and Ni(IV)) to redox-active para-benzoquinone molecules substituted with carboxyl- and cyano-groups. It is found that both the nickel ions and the quinone-derived ligands are redox-active upon lithiation. The type of Ni coordination also has a bearing on the redox potentials. By combining the complex of Ni(IV) with 2-carboxylato-5-cyano-1,4-benzoquinones as a cathode and Ni(II)-2,5-dicarboxylato-3,6-dicyano-1,4-benzoquinone coordination polymer as an anode, all-organic Li-ion batteries could be assembled, operating at an average voltage exceeding 3.0 V and delivering a capacity of more than 300 mAh/g.
A Generalized Method for the Synthesis of Carbon-Encapsulated Fe3O4 Composites and Its Application in Water Treatment
Authors: Duan Shengxia , Liu Jian , Pang Yanling , Lin Feng , Meng Xiangyan , Tang Ke , Li Jiaxing
Published: October 2022

In this paper, a simple and environmentally friendly method was developed for the preparation of highly stable C@Fe3O4 composites with controllable morphologies using sodium alginate as the carbon source and the easily obtained α-Fe2O3 as the precursors. The morphologies of the as-prepared C@Fe3O4 composites, inherited from their corresponding precursors of α-Fe2O3, survived from the annealing treatments, were characterized by the field-emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) and inductively coupled plasma-atomic emission spectroscopy (ICP-AES). The C@Fe3O4 composites resisted to oxidation, acidification and aggregation, exhibiting porous structures and ferromagnetic properties at room temperature. Moreover, the adsorption performance of the C@Fe3O4 composites was evaluated by absorbing MB (methylene blue) in liquid environment. Experiments indicated that the C@Fe3O4 composites exhibited highly enhanced adsorption capacities and efficiencies as compared with their corresponding precursors of α-Fe2O3. This generalized method for the synthesis of C@Fe3O4 composites provides promising applications for the highly efficient removal of MB from industrial effluents.
One-Pot Synthesis of N-Rich Porous Carbon for Efficient CO2 Adsorption Performance
Authors: Yu Qiyun , Bai Jiali , Huang Jiamei , Demir Muslum , Altay Bilge Nazli , Hu Xin , Wang Linlin
Published: October 2022

N-enriched porous carbons have played an important part in CO2 adsorption application thanks to their abundant porosity, high stability and tailorable surface properties while still suffering from a non-efficient and high-cost synthesis method. Herein, a series of N-doped porous carbons were prepared by a facile one-pot KOH activating strategy from commercial urea formaldehyde resin (UF). The textural properties and nitrogen content of the N-doped carbons were carefully controlled by the activating temperature and KOH/UF mass ratios. As-prepared N-doped carbons show 3D block-shaped morphology, the BET surface area of up to 980 m2/g together with a pore volume of 0.52 cm3/g and N content of 23.51 wt%. The optimal adsorbent (UFK-600-0.2) presents a high CO2 uptake capacity of 4.03 mmol/g at 0 °C and 1 bar. Moreover, as-prepared N-doped carbon adsorbents show moderate isosteric heat of adsorption (43–53 kJ/mol), acceptable ideal adsorption solution theory (IAST) selectivity of 35 and outstanding recycling performance. It has been pointed out that while the CO2 uptake was mostly dependent on the textural feature, the N content of carbon also plays a critical role to define the CO2 adsorption performance. The present study delivers favorable N-doped carbon for CO2 uptake and provides a promising strategy for the design and synthesis of the carbon adsorbents.
Comparison of the Main Metabolites in Different Maturation Stages of Camelliavietnamensis Huang Seeds
Authors: Yan Heqin , Zheng Wei , Ye Zhouchen , Yu Jing , Wu Yougen
Published: October 2022

Camellia vietnamensis Huang is an important woody oil crop in China, which has attracted much attention because of its abundant nutritional components and pharmaceutical value. Its seeds undergo a complex series of physiological and biochemical changes during maturation, with consequent alterations in metabolites. In order to investigate the endogenous metabolism of C. vietnamensis on Hainan Island during seed development, in this study, ultra-high-performance liquid tandem chromatography coupled with quadrupole time-of-flight mass spectrometry (UHPLC/Q-TOF-MS) and multivariate statistical analysis (MSA) were used to analyze the differences in the chemical compounds of C. vietnamensis seeds among the four maturation stages. A total of 293 metabolites were identified from the methanol extract of the seeds of C. vietnamensis. Five metabolites, belonging to benzene and substituted derivatives, 5′-deoxyribonucleosides and linear 1,3-diarylpropanoids, were found in all three comparison groups, with consistently down-regulated trends. The Kyoto Encyclopedia of Genes and Genomes (KEGG) results showed that phloretin and 5′-methylthioadenosine were the differentially expressed metabolites when seeds were in the growth periods of S2 and S3, and indole and L-tryptophan were the differentially expressed metabolites when seeds were in the growth periods of S3 and S4. In addition, 34 flavonoid metabolites were detected, of which 4 were differentially expressed. It was indicated that flavonoids dynamically change during all the oil-tea camellia seed development stages. The findings provide data for the better understanding of endogenous metabolic pathways during C. vietnamensis seed development.
Biosourced Poly(lactic acid)/polyamide-11 Blends: Effect of an Elastomer on the Morphology and Mechanical Properties
Authors: Fazli Ali , Rodrigue Denis
Published: October 2022

Fully biobased polylactide (PLA)/polyamide-11 (PA11) blends were prepared by melt mixing with an elastomer intermediate phase to address the low elasticity and brittleness of PLA blends. The incorporation of a biobased elastomer made of poly(butylene adipate-co-terephthalate) (PBAT) and polyethylene oxide (PEO) copolymers was found to change the rigid interface between PLA and PA11 into a much more elastic/deformable one as well as promote interfacial compatibility. The interfacial tension of the polymer pairs and spreading coefficients revealed a high tendency of PEO to spread at the PLA/PA11 interface, resulting in a complete wetting regime (interfacial tension of 0.56 mN/m). A fully percolated rubbery phase (PEO) layer at the PLA/PA11 interface with enhanced interfacial interactions and PLA chain mobility contributed to a better distribution of the stress around the dispersed phase, leading to shear yielding of the matrix. The results also show that both the morphological modification and improved compatibility upon PEO addition (up to 20 wt %) contributed to the improved elongation at break (up to 104%) and impact strength (up to 292%) of the ternary PLA/PA11/PEO blends to obtain a super-tough multiphase system.
Synthesis and Application of New Salan Titanium Complexes in the Catalytic Reduction of Aldehydes
Authors: Hipólito Joana , Martins Ana M. , Alves Luis G.
Published: October 2022

Complexes of formula [(H2N2O2)TiCl2] and [(H2N2O2)Ti(OiPr)2] (H2N2O2H2 = HOPh’CH2NH(CH2)2NHCH2Ph’OH, where Ph’ = 2,4-(CMe2Ph)C6H2) were synthesized by the reaction of the salan ligand precursor H2N2O2H2 with TiCl4 and Ti(OiPr)4, respectively, in high yields. The dichlorido complex [(H2N2O2)TiCl2] revealed to be an efficient catalyst for the reduction of benzaldehyde in toluene. Full conversion was observed after 24 h at 55 °C in THF. The same catalyst also converted phenylacetaldehyde and hydrocinnamaldehyde into the corresponding alkanes quantitatively.
Optimization of N-PERT Solar Cell under Atacama Desert Solar Spectrum
Authors: Ferrada Pablo , Marzo Aitor , Ferrández Miriam Ruiz , Reina Emilio Ruiz , Ivorra Benjamin , Correa-Puerta Jonathan , Campo Valeria del
Published: October 2022

In the Atacama Desert, the spectral distribution of solar radiation differs from the global standard, showing very high levels of irradiation with a particularly high ultraviolet content. Additionally, the response of photovoltaic (PV) technologies is spectrally dependent, so it is necessary to consider local conditions and type of technology to optimize PV devices since solar cells are usually designed for maximum performance under standard testing conditions (STC). In this work, we determined geometrical and doping parameters to optimize the power of an n-type bifacial passivated emitter and rear totally diffused solar cell (n-PERT). Six parameters (the thicknesses of cell, emitter, and back surface field, as well as doping concentration of emitter, base, and back surface field) were used to optimize the cell under the Atacama Desert spectrum (AM 1.08) and under standard conditions (AM 1.5) through a genetic algorithm. To validate the model, the calculated performance of the n-PERT cell was compared with experimental measurements. Computed and experimental efficiencies showed a relative difference below 1% under STC conditions. Through the optimization process, we found that different geometry and doping concentrations are necessary for cells to be used in the Atacama Desert. Reducing the thickness of all layers and increasing doping can lead to a relative increment of 5.4% in the cell efficiency under AM 1.08. Finally, we show the potential effect of metallization and the viability of reducing the thicknesses of the emitter and the back surface field.
Fetal Alcohol Spectrum Disorder and Iron Homeostasis
Authors: Bradley Regan , Lakpa Koffi L. , Burd Michael , Mehta Sunil , Katusic Maja Z. , Greenmyer Jacob R.
Published: October 2022

Prenatal alcohol exposure results in a spectrum of behavioral, cognitive, and morphological abnormalities collectively referred to as fetal alcohol spectrum disorder (FASD). FASD presents with significant phenotypic variability and may be modified by gestational variables such as maternal nutritional status. Iron serves a critical function in the development of and processes within central nervous system (CNS) structures. Gestational iron deficiency alters CNS development and may contribute to neurodevelopmental impairment in FASD. This review explores the relationship between iron deficiency and fetal alcohol spectrum disorder as described in small animal and human studies. Consideration is given to the pathophysiologic mechanisms linking iron homeostasis and prenatal alcohol exposure. Existing data suggest that iron deficiency contributes to the severity of FASD and provide a mechanistic explanation linking these two conditions.
Association between Ultra-Processed Food Consumption and Diabetes in Chinese Adults—Results from the China Health and Nutrition Survey
Authors: Li Ming , Shi Zumin
Published: October 2022

Aims: We aimed to assess the association between ultra-processed food (UPF) consumption with diabetes in Chinese adults. Methods: This study included 12,849 eligible adults aged 20 years and over attending at least two surveys in the China Nutrition and Health Survey during 1997–2011. Food intake at each survey was assessed by a 3-day 24-h dietary recall method. UPF was defined based on the NOVA classification. Diabetes was obtained from questionnaires and/or ascertained by fasting blood tests. The association of diabetes with UPF was examined using mix effect logistic regression adjusting for potential confounding factors. Results: The mean age of the participants was 43.3 (SD 14.8) years. The age and gender adjusted mean UPF intake increased four times and the prevalence of diabetes increased eight times in 1997–2011. Compared with non-consumers, the odds ratios (95% CI) of diabetes for those with mean UPF consumption of 1–19 g/day, 20–49 g/day, and ≥50 g/day were 1.21 (0.98, 1.48), 1.49 (1.19, 1.86), and 1.40 (1.08, 1.80), respectively (p trend < 0.001) after adjusted for the measured covariates including lifestyle factors (smoking, alcohol drinking, and physical activity), BMI and hypertension. Conclusions: both UPF consumption and prevalence of diabetes increased among adults in China during 1997–2011. Higher UPF consumption was positively associated with diabetes.
Antimicrobial Peptides Can Generate Tolerance by Lag and Interfere with Antimicrobial Therapy
Authors: Sandín Daniel , Valle Javier , Morata Jordi , Andreu David , Torrent Marc
Published: October 2022

Antimicrobial peptides (AMPs) are widely distributed molecules secreted mostly by cells of the innate immune system to prevent bacterial proliferation at the site of infection. As with classic antibiotics, continued treatment with AMPs can create resistance in bacteria. However, whether AMPs can generate tolerance as an intermediate stage towards resistance is not known. Here, we show that the treatment of Escherichia coli with different AMPs induces tolerance by lag, particularly for those peptides that have internal targets. This tolerance can be detected as different morphological and physiological changes, which depend on the type of peptide molecule the bacterium has been exposed to. In addition, we show that AMP tolerance can also affect antibiotic treatment. The genomic sequencing of AMP-tolerant strains shows that different mutations alter membrane composition, DNA replication, and translation. Some of these mutations have also been observed in antibiotic-resistant strains, suggesting that AMP tolerance could be a relevant step in the development of antibiotic resistance. Monitoring AMP tolerance is relevant vis-á-vis the eventual therapeutic use of AMPs and because cross-tolerance might favor the emergence of resistance against conventional antibiotic treatments.
The Phenomenology of Semiosis: Approaches to the Gap between the Encyclopaedia and the Porphyrian Tree Spanned by Sedimentation
Authors: Sonesson Göran H.
Published: October 2022

When putting semiotics and phenomenology in juxtaposition, the first task necessarily is to find out what a study of meaning, conceiving of itself as an empirical science, has to do with a philosophical school, the business of which it is to secure the epistemological foundations of all the sciences (broadly understood). Our answer, in short (but we will go at some length to show it), is that since all results of phenomenology also count as contributions to phenomenological psychology, the phenomenological method constitutes a part of the panoply of methods offered to semiotics. Our second task will be to review the fragmentary semiotics proposed, originally employing that term, by Edmund Husserl, to gauge its value for contemporary semiotics. Since our investigation of Husserl’s semiotics will demonstrate that it sometimes concerns the sign in a narrow sense, and sometimes broadens up to a study of meaning in general, our third and final task, in this paper, will be to consider a proposal made by a close follower of Husserl, Alfred Schütz, whose idea of a system of relevancies, wedded to Husserl’s notion of sedimentation, might be amended when considered in connection with Umberto Eco’s idea of the encyclopaedia.
Increasing the Photocatalytic Activity of BiVO4 by Naked Co(OH)2 Nanoparticle Cocatalysts
Authors: Gomes Luiz E. , Plaça Luiz F. , Rosa Washington S. , Gonçalves Renato V. , Ullah Sajjad , Wender Heberton
Published: October 2022

Bismuth vanadate (BiVO4 or BVO) is one of the most studied photocatalysts for water oxidation because of its excellent visible light absorption and appropriate band energy positions. However, BVO presents a low charge mobility and a high electron–hole recombination rate. To address these fundamental limitations, this study proposes the coating of previously synthesized phase-pure monoclinic scheelite BVO with different amounts of naked cobalt (further oxidized to cobalt hydroxide) nanoparticles (NPs) via a modified magnetron sputtering deposition. The resulting BVO/Co photocatalysts were investigated for methylene blue (MB) photodegradation, photocatalytic oxygen evolution, and photoelectrochemical (PEC) water oxidation. In the MB photodegradation tests, the BVO/Co sample prepared with a deposition time of 5 min (BVO/Co(5 min)) presented the highest photoactivity (k = 0.06 min−1) compared with the other sputtering investigated times (k = 0.01–0.02 min−1), as well as the pristine BVO sample (k = 0.04 min−1). A similar trend was evidenced for the PEC water oxidation, where a photocurrent density of 23 µA.cm−2 at 1.23 V (vs. RHE) was observed for the BVO/Co(5 min) sample, a value 4.6 times higher compared with pristine BVO. Finally, the BVO/Co(5 min) presented an O2 evolution more than two times higher than that of the pristine BVO. The increased photocatalytic performance was ascribed to increased visible-light absorption, lesser electron–hole recombination, and enhanced charge transfer at the liquid/solid interface. The deposition of Co(OH)2 NPs via magnetron sputtering can be considered an effective strategy to improve the photocatalytic performance of BVO for different target catalytic reactions, including oxygen evolution, water oxidation, and pollutant photodegradation.
Tunable High-Q Factor Substrate for Selectively Enhanced Raman Scattering
Authors: Qi Zhengqing , Li Jinhuan , Chen Peng , Zhang Lingling , Ji Ke
Published: October 2022

Most Surface-enhanced Raman scattering (SERS) substrates enhance all the Raman signals in a relative broad spectral range. The substrates enhance both the interested and background signals together. To improve the identification of target molecules from numerous background ones, substrates with multi high-quality (Q) factor resonance wavelengths can be designed to achieve the selective enhancement of specific Raman transitions. When the resonance frequencies are modulated to match the excitation and Raman scattering frequencies, the detection of the target molecule can be more effective. In this paper, we design a tunable high-Q SERS substrate with periodic silver bowtie nanoholes on silica spacer and silver film. The substrate possessed three high-Q and high electric field resonance modes, which resulted from the interaction of the localized surface plasmon resonance (LSPR) of the bowtie nanoholes, the surface plasmon polariton (SPP) of the period bowtie nanoholes and the Fabry–Perot (FP) resonance between the bowtie and silver film bottom. The interaction between these resonance modes resulted in not only a higher quality (Q) factor, but also a higher electric field, which can be employed to realize a potential substrate in high-sensitivity and selective-detection fields.
Low- and High-Order Optical Nonlinearities of Quantum Dots
Authors: Ganeev Rashid A.
Published: October 2022

Various potential applications of quantum dots (QDs) require knowledge of their optical nonlinearities. In this review, the third-order nonlinearities responsible for the saturable absorption, two-photon absorption, reverse saturable absorption, and nonlinear refraction in QDs, as well as the high-order harmonics generation in the laser-induced plasmas containing QDs, are analyzed. The methods of QD synthesis and preparation strongly affect their optical nonlinearities. Above-mentioned nonlinear optical studies in QDs are analyzed for various potential applications (sources of coherent extreme ultraviolet radiation, optical limiters, mode-lockers, etc.).
Correction: Costanzo, V.; Costanzo, M. Intravital Imaging with Two-Photon Microscopy: A Look into the Kidney. Photonics 2022, 9, 294
Authors: Costanzo Vincenzo , Costanzo Michele
Published: October 2022

In the original publication [...]