bluuebunny/crossref_metadata_2025 huggingface dataset:
Vapor and Liquid Phase Profiles of Essential Oils from Abies, Picea and Pinus Species and Their Phytotoxic Interactions with Weed Growth in Pre- and Post-Emergence Conditions
Authors: Garzoli Stefania , Vaglia Valentina , Iriti Marcello , Vitalini Sara
Published: March 2023

The chemical content of essential oils (EO) obtained from the leaves of four Pinaceae (Abies alba, Picea abies, Pinus cembra and Pinus mugo) was investigated by SPME-GC-MS technique. The vapor phase was characterized by the monoterpenes with values higher than 95.0%. Among them, α-pinene (24.7–48.5%), limonene (17.2–33.1%) and β-myrcene (9.2–27.8%) were the most abundant. The monoterpenic fraction prevailed over the sesquiterpenic one (≥74.7%) in the EO liquid phase. Limonene was the major compound in A. alba (30.4%), P. abies (20.3%) and P. mugo (78.5%), while α-pinene in P. cembra (36.2%). Regarding the phytotoxic properties, EOs were studied at different doses (2–100 μL) and concentrations (2–20/100 μL/mL). All EOs were found to be significantly active (p-value ˂ 0.05) against the two recipient species in a dose-dependent way. In pre-emergence tests, germination of Lolium multiflorum and Sinapis alba was reduced by up to 62–66% and 65–82%, respectively, as well as their growth by up to 60–74% and 65–67%, due to the effects of compounds in both the vapor and liquid phases. In post-emergence conditions, at the highest concentration, the phytotoxicity of EOs caused heavy symptoms and, in the case of S. alba, A. alba EO completely destroyed (100%) the treated seedlings.
Propagation of Medicinal Plants for Sustainable Livelihoods, Economic Development, and Biodiversity Conservation in South Africa
Authors: Fajinmi Olufunke O. , Olarewaju Olaoluwa O. , Van Staden Johannes
Published: March 2023

South Africa is blessed with vast plant resources and unique vegetation types. Indigenous South African medicinal plants have been well-harnessed to generate income in rural communities. Many of these plants have been processed into natural products to heal a variety of diseases, making them valuable export commodities. South Africa has one of the most effective bio-conservation policies in Africa, which has protected the South African indigenous medicinal vegetation. However, there is a strong link between government policies for biodiversity conservation, the propagation of medicinal plants as a source of livelihood, and the development of propagation techniques by research scientists. Tertiary institutions nationwide have played a crucial role in the development of effective propagation protocols for valuable South African medicinal plants. The government-restricted harvest policies have also helped to nudge natural product companies and medicinal plant marketers to embrace the cultivated plants for their medicinal uses, and thus have helped support the South African economy and biodiversity conservation. Propagation methods used for the cultivation of the relevant medicinal plants vary according to plant family and vegetation type, among others. Plants from the Cape areas, such as the Karoo, are often resuscitated after bushfires, and propagation protocols mimicking these events have been established through seed propagation protocols with controlled temperatures and other conditions, to establish seedlings of such plants. Thus, this review highlights the role of the propagation of highly utilized and traded medicinal plants in the South African traditional medicinal system. Some valuable medicinal plants that sustain livelihoods and are highly sought-after as export raw materials are discussed. The effect of South African bio-conservation registration on the propagation of these plants and the roles of the communities and other stakeholders in the development of propagation protocols for highly utilized and endangered medicinal plants are also covered. The role of various propagation methods on the bioactive compounds’ composition of medicinal plants and issues of quality assurance are addressed. The available literature, media online news, newspapers, and other resources, such as published books and manuals, were scrutinized for information.
Growth Developmental Defects of Mitochondrial Iron Transporter 1 and 2 Mutants in Arabidopsis in Iron Sufficient Conditions
Authors: Vargas Joaquín , Gómez Isabel , Vidal Elena A. , Lee Chun Pong , Millar A. Harvey , Jordana Xavier , Roschzttardtz Hannetz
Published: March 2023

Iron is the most abundant micronutrient in plant mitochondria, and it has a crucial role in biochemical reactions involving electron transfer. It has been described in Oryza sativa that Mitochondrial Iron Transporter (MIT) is an essential gene and that knockdown mutant rice plants have a decreased amount of iron in their mitochondria, strongly suggesting that OsMIT is involved in mitochondrial iron uptake. In Arabidopsis thaliana, two genes encode MIT homologues. In this study, we analyzed different AtMIT1 and AtMIT2 mutant alleles, and no phenotypic defects were observed in individual mutant plants grown in normal conditions, confirming that neither AtMIT1 nor AtMIT2 are individually essential. When we generated crosses between the Atmit1 and Atmit2 alleles, we were able to isolate homozygous double mutant plants. Interestingly, homozygous double mutant plants were obtained only when mutant alleles of Atmit2 with the T-DNA insertion in the intron region were used for crossings, and in these cases, a correctly spliced AtMIT2 mRNA was generated, although at a low level. Atmit1 Atmit2 double homozygous mutant plants, knockout for AtMIT1 and knockdown for AtMIT2, were grown and characterized in iron-sufficient conditions. Pleiotropic developmental defects were observed, including abnormal seeds, an increased number of cotyledons, a slow growth rate, pinoid stems, defects in flower structures, and reduced seed set. A RNA-Seq study was performed, and we could identify more than 760 genes differentially expressed in Atmit1 Atmit2. Our results show that Atmit1 Atmit2 double homozygous mutant plants misregulate genes involved in iron transport, coumarin metabolism, hormone metabolism, root development, and stress-related response. The phenotypes observed, such as pinoid stems and fused cotyledons, in Atmit1 Atmit2 double homozygous mutant plants may suggest defects in auxin homeostasis. Unexpectedly, we observed a possible phenomenon of T-DNA suppression in the next generation of Atmit1 Atmit2 double homozygous mutant plants, correlating with increased splicing of the AtMIT2 intron containing the T-DNA and the suppression of the phenotypes observed in the first generation of the double mutant plants. In these plants with a suppressed phenotype, no differences were observed in the oxygen consumption rate of isolated mitochondria; however, the molecular analysis of gene expression markers, AOX1a, UPOX, and MSM1, for mitochondrial and oxidative stress showed that these plants express a degree of mitochondrial perturbation. Finally, we could establish by a targeted proteomic analysis that a protein level of 30% of MIT2, in the absence of MIT1, is enough for normal plant growth under iron-sufficient conditions.
Crop Seed Phenomics: Focus on Non-Destructive Functional Trait Phenotyping Methods and Applications
Authors: Hacisalihoglu Gokhan , Armstrong Paul
Published: March 2023

Seeds play a critical role in ensuring food security for the earth’s 8 billion people. There is great biodiversity in plant seed content traits worldwide. Consequently, the development of robust, rapid, and high-throughput methods is required for seed quality evaluation and acceleration of crop improvement. There has been considerable progress in the past 20 years in various non-destructive methods to uncover and understand plant seed phenomics. This review highlights recent advances in non-destructive seed phenomics techniques, including Fourier Transform near infrared (FT-NIR), Dispersive-Diode Array (DA-NIR), Single-Kernel (SKNIR), Micro-Electromechanical Systems (MEMS-NIR) spectroscopy, Hyperspectral Imaging (HSI), and Micro-Computed Tomography Imaging (micro-CT). The potential applications of NIR spectroscopy are expected to continue to rise as more seed researchers, breeders, and growers successfully adopt it as a powerful non-destructive method for seed quality phenomics. It will also discuss the advantages and limitations that need to be solved for each technique and how each method could help breeders and industry with trait identification, measurement, classification, and screening or sorting of seed nutritive traits. Finally, this review will focus on the future outlook for promoting and accelerating crop improvement and sustainability.
Evaluation of Propiophenone, 4-Methylacetophenone and 2′,4′-Dimethylacetophenone as Phytotoxic Compounds of Labdanum Oil from Cistus ladanifer L.
Authors: Espinosa-Colín María , Hernandez-Caballero Irene , Infante Celia , Gago Irene , García-Muñoz Javier , Sosa Teresa
Published: March 2023

This is the first study to evaluate the phytotoxic activity of three phenolic compounds present in the essential oil of the labdanum of Cistus ladanifer, an allelopathic species of the Mediterranean ecosystem. Propiophenone, 4′-methylacetophenone, and 2′,4′-dimethylacetophenone slightly inhibit total germination and radicle growth of Lactuca sativa, and they strongly delay germination and reduce hypocotyl size. On the other hand, the inhibition effect of these compounds on Allium cepa was stronger on total germination than on germination rate, and radicle length compared to hypocotyl size. The position and number of methyl groups will affect the efficacy of the derivative. 2′,4′-dimethylacetophenone was the most phytotoxic compound. The activity of the compounds depended on their concentration and presented hormetic effects. In L. sativa, on paper, propiophenone presented greater inhibition of hypocotyl size at greater concentrations, with IC50 = 0.1 mM, whereas 4′-methylacetophenone obtained IC50 = 0.4 mM for germination rate. When the mixture of the three compounds was applied, in L. sativa, on paper, the inhibition effect on total germination and the germination rate was significantly greater compared to the effect of the compounds when they were applied separately; moreover, the mixture inhibited radicle growth, whereas propiophenone and 4′-methylacetophenone did not exert such effect when applied separately. The activity of the pure compounds and that of the mixture also changed based on the substrate used. When the trial was conducted in soil, the separate compounds delayed the germination of the A. cepa to a greater extent compared to the trial on paper, although they stimulated seedling growth. In soil, L. sativa against 4′-methylacetophenone also showed the opposite effect at low concentrations (0.1 mM), with stimulation of germination rate, whereas propiophenone and 4′-methylacetophenone presented a slightly increased effect.
Plant Growth, Yield, and Fruit Size Improvements in ‘Alicia’ Papaya Multiplied by Grafting
Authors: Salinas Irene , Hueso Juan José , Força Baroni Danilo , Cuevas Julián
Published: March 2023

Papaya (Carica papaya L.) is one of the few fruit crops still propagated by seeds. However, its trioecious condition and the heterozygosity of the seedlings make urgent the development of reliable vegetative propagation procedures. In this experiment, we compared, in a greenhouse sited in Almería (Southeast Spain), the performance of plantlets of ‘Alicia’ papaya originated by seed, grafting, and micropropagation. Our results show that grafted papayas were more productive than seedlings papayas (7% and 4% for total and commercial yield), while in vitro micropropagated papayas were the least productive (28 and 5% less in total and commercial yield than grafted papayas, respectively). Root density and dry weight were both higher in grafted papayas, while the seasonal production of good quality, well-formed, flowers was also enhanced in grafted papayas. On the contrary, micropropagated ‘Alicia’ plants yielded less and lighter fruit despite these in vitro plants blooming earlier and setting fruit at desirable lower trunk height. Less tall and less thick plants and reduced production of good quality flowers might explain these negative results. In addition, the root system of micropropagated papaya was more superficial, while in grafted papayas, the root system was larger and had more fine roots. Our results suggest that the cost-benefit ratio does not favor the choice of micropropagated plants unless elite genotypes are used. On the contrary, our results encourage more research on grafting, including the search for suitable rootstocks for papaya.
Floating Mat Formation Makes Zizania latifolia More Competitive under the Conditions of Continuous Significant Water Level Rise
Authors: Wen Ji-Hui , Li Bing-Yao , Xiao Hong-Yu , Gong Cai-Ying , Gao An-Guo , Wang Yan-Hong , Li De-Liang , Zeng Hong-Yuan , Li You-Zhi , Yuan Gui-Xiang , Fu Hui , Wu Ai-Ping
Published: March 2023

Water level rise is considered an environmental filter for the growth and reproduction of aquatic plants in lakes. Some emergent macrophytes can form floating mats, enabling them to escape from the negative effects of deep water. However, an understanding of which species can be uprooted and form floating mats easily and what factors affect these tendencies remains greatly elusive. We conducted an experiment to determine whether the monodominance of Zizania latifolia in the emergent vegetation community in Lake Erhai was related to its floating mat formation ability and to try to find the reasons for its floating mat formation ability during the continuous increase in water level over the past few decades. Our results showed that both the frequency and biomass proportion of Z. latifolia were greater among the plants on the floating mats. Furthermore, Z. latifolia was more likely to be uprooted than the other three previously dominant emergent species due to its smaller angle between the plant and the horizontal plane, rather than the root:shoot or volume:mass ratios. The dominance of Z. latifolia in the emergent community in Lake Erhai is due to its easier ability to become uprooted, allowing it to outperform other emergent species and become the single dominant emergent species under the environmental filter of deep water. The ability to uproot and form floating mats may be a competitive survival strategy for emergent species under the conditions of continuous significant water level rise.
Application of Plasma Bridge for Grounding of Conductive Substrates Treated by Transferred Pulsed Atmospheric Arc
Authors: Korzec Dariusz , Hoffmann Markus , Nettesheim Stefan
Published: March 2023

An atmospheric pressure plasma jet (APPJ) sustained by a pulsed atmospheric arc (PAA) transferred on an electrically conducting surface was operated with a mean power of 700 W, a pulse frequency of 60 kHz, and a gas mixture of N2 and H2 with up to 10% H2, flowing at 30 to 70 SLM. It was shown that the plasma bridge ignited between the grounded injector and electrically conducting and floating substrates can be used for electrical grounding. This allowed for arc transfer on such substrates. The plasma bridge was stable for Argon flow through the injector from 3 to 10 SLM. Its length was between 5 and 15 mm. The plasma bridge current was 350 mA. The copper contact pads on an alumina electronic board were treated using the plasma bridge sustained by Ar injection for grounding. First, an oxide film of about 65 nm was grown by a compressed dry air (CDA) plasma jet. Then, this film was reduced at a speed of 4 cm2/s by forming gas 95/5 (95% of N2 and 5% of H2) plasma jet.
Refined Spherulites of PP Induced by Supercritical N2 and Graphite Nanosheet and Foaming Performance
Authors: Liu Ya , Guan Yanjin , Zhai Jiqiang , Zhang Lei , Chen Fengjiao , Lin Jun
Published: March 2023

The isothermal crystallization properties of polypropylene/graphite nanosheet (PP/GN) nanocomposites under supercritical N2 were systematically studied by a self-made in situ high-pressure microscope system. The results showed that the GN caused irregular lamellar crystals to form within the spherulites due to its effect on heterogeneous nucleation. It was found that the grain growth rate exhibits a decreasing and then increasing trend with the enhancement of N2 pressure. Using the secondary nucleation model, the secondary nucleation rate for spherulites of PP/GN nanocomposites was investigated from an energy perspective. The increase in free energy introduced by the desorbed N2 is the essential reason for the increase in the secondary nucleation rate. The results from the secondary nucleation model were consistent with those acquired through isothermal crystallization experiments, suggesting that the model can accurately predict the grain growth rate of PP/GN nanocomposites under supercritical N2 conditions. Furthermore, these nanocomposites demonstrated good foam behavior under supercritical N2.
Adhesion-Induced Demolding Forces of Hard Coated Microstructures Measured with a Novel Injection Molding Tool
Authors: Schoenherr Maximilian , Ruehl Holger , Guenther Thomas , Zimmermann André , Gundelsweiler Bernd
Published: March 2023

The demolding of plastic parts remains a challenging aspect of injection molding. Despite various experimental studies and known solutions to reduce demolding forces, there is still not a complete understanding of the effects that occur. For this reason, laboratory devices and in-process measurement injection molding tools have been developed to measure demolding forces. However, these tools are mostly used to measure either frictional forces or demolding forces for a specific part geometry. Tools that can be used to measure the adhesion components are still the exception. In this study, a novel injection molding tool based on the principle of measuring adhesion-induced tensile forces is presented. With this tool, the measurement of the demolding force is separated from the actual ejection step of the molded part. The functionality of the tool was verified by molding PET specimens at different mold temperatures, mold insert conditions and geometries. It was demonstrated that once a stable thermal state of the molding tool was achieved, the demolding force could be accurately measured with a comparatively low force variance. A built-in camera was found to be an efficient tool for monitoring the contact surface between the specimen and the mold insert. By comparing the adhesion forces of PET molded on polished uncoated, diamond-like carbon and chromium nitride (CrN) coated mold inserts, it was found that a CrN coating reduced the demolding force by 98.5% and could therefore be an efficient solution to significantly improve demolding by reducing adhesive bond strength under tensile loading.
Phosphazene Functionalized Silsesquioxane-Based Porous Polymer as Thermally Stable and Reusable Catalyst for Bulk Ring-Opening Polymerization of ε-Caprolactone
Authors: Piskun Yuliya A. , Ksendzov Evgenii A. , Resko Anastasiya V. , Soldatov Mikhail A. , Timashev Peter , Liu Hongzhi , Vasilenko Irina V. , Kostjuk Sergei V.
Published: March 2023

The bulk ring-opening polymerization (ROP) of ε-caprolactone using phosphazene-containing porous polymeric material (HPCP) has been studied at high reaction temperatures (130–150 °C). HPCP in conjunction with benzyl alcohol as an initiator induced the living ROP of ε-caprolactone, affording polyesters with a controlled molecular weight up to 6000 g mol−1 and moderate polydispersity (Ð~1.5) under optimized conditions ([BnOH]/[CL] = 50; HPCP: 0.63 mM; 150 °C). Poly(ε-caprolactone)s with higher molecular weight (up to Mn = 14,000 g mol−1, Ð~1.9) were obtained at a lower temperature, at 130 °C. Due to its high thermal and chemical stability, HPCP can be reused for at least three consecutive cycles without a significant decrease in the catalyst efficiency. The tentative mechanism of the HPCP-catalyzed ROP of ε-caprolactone, the key stage of which consists of the activation of the initiator through the basic sites of the catalyst, was proposed.
Effects of Process Parameters on the Fibrous Structure and Textural Properties of Calcium Caseinate Extrudates
Authors: Zhao Ziqi , Wang Zhaojun , He Zhiyong , Zeng Maomao , Chen Jie
Published: March 2023

Textured calcium caseinate extrudates are considered promising candidates in producing fish substitutes. This study aimed to evaluate how the moisture content, extrusion temperature, screw speed, and cooling die unit temperature of the high-moisture extrusion process affect the structural and textural properties of calcium caseinate extrudates. With an increase in moisture content from 60% to 70%, there was a decrease in the cutting strength, hardness, and chewiness of the extrudate. Meanwhile, the fibrous degree increased considerably from 1.02 to 1.64. The hardness, springiness, and chewiness showed a downward trend with the rise in extrusion temperature from 50 °C to 90 °C, which contributed to the reduction in air bubbles in the extrudate. Screw speed showed a minor effect on fibrous structure and textural properties. A low temperature (30 °C) in all cooling die units led to damaged structure without mechanical anisotropy, which resulted from fast solidification. These results show that the fibrous structure and textural properties of calcium caseinate extrudates can be effectively manipulated by adjusting the moisture content, extrusion temperature, and cooling die unit temperature.
All-Organic PTFE Coated PVDF Composite Film Exhibiting Low Conduction Loss and High Breakdown Strength for Energy Storage Applications
Authors: Meng Xiang-Shuo , Zhou Yujiu , Li Jianfeng , Ye Hu , Chen Fujia , Zhao Yuetao , Pan Qifeng , Xu Jianhua
Published: March 2023

Plastic film capacitors are widely used in pulse and energy storage applications because of their high breakdown strength, high power density, long lifetime, and excellent self-healing properties. Nowadays, the energy storage density of commercial biaxially oriented polypropylene (BOPP) is limited by its low dielectric constant (~2.2). Poly(vinylidene fluoride) (PVDF) exhibits a relatively high dielectric constant and breakdown strength, making it a candidate material for electrostatic capacitors. However, PVDF presents significant losses, generating a lot of waste heat. In this paper, under the guidance of the leakage mechanism, a high-insulation polytetrafluoroethylene (PTFE) coating is sprayed on the surface of a PVDF film. The potential barrier at the electrode–dielectric interface is raised by simply spraying PTFE and reducing the leakage current, and then the energy storage density is increased. After introducing the PTFE insulation coating, the high-field leakage current in the PVDF film shows an order of magnitude reduction. Moreover, the composite film presents a 30.8% improvement in breakdown strength, and a 70% enhancement in energy storage density is simultaneously achieved. The all-organic structure design provides a new idea for the application of PVDF in electrostatic capacitors.
A Review of the Use of Coconut Fiber in Cement Composites
Authors: Martinelli Flávia Regina Bianchi , Ribeiro Francisco Roger Carneiro , Marvila Markssuel Teixeira , Monteiro Sergio Neves , Filho Fabio da Costa Garcia , Azevedo Afonso Rangel Garcez de
Published: March 2023

The use of plant fibers in cementitious composites has been gaining prominence with the need for more sustainable construction materials. It occurs due to the advantages natural fibers provide to these composites, such as the reduction of density, fragmentation, and propagation of cracks in concrete. The consumption of coconut, a fruit grown in tropical countries, generates shells that are improperly disposed of in the environment. The objective of this paper is to provide a comprehensive review of the use of coconut fibers and coconut fiber textile mesh in cement-based materials. For this purpose, discussions were conducted on plant fibers, the production and characteristics of coconut fibers, cementitious composites reinforced with coconut fibers, cementitious composites reinforced with textile mesh as an innovative material to absorb coconut fibers, and treatments of coconut fiber for improved product performance and durability. Finally, future perspectives on this field of study have also been highlighted. Thus, this paper aims to understand the behavior of cementitious matrices reinforced with plant fibers and demonstrate that coconut fiber has a high capacity to be used in cementitious composites instead of synthetic fibers.
Cotton Woven Fabrics as Protective Polymer Materials against Solar Radiation in the Range of 210–1200 nm
Authors: Dubrovski Polona Dobnik , Fakin Darinka , Ojstršek Alenka
Published: March 2023

The proposed paper describes the influence of woven fabric constructional parameters (type of weave, relative fabric density) and colouration (obtained by eco-friendly dyeing) on the solar transmittance of cotton woven fabrics in the range of 210–1200 nm. The cotton woven fabrics in their raw state were prepared according to Kienbaum’s setting theory, at three levels of relative fabric density and three levels of the weave factor, and then exposed to the dyeing process with natural dyestuffs (beetroot, walnut leaves). After ultraviolet/visible/near-infrared (UV/VIS/IRA) solar transmittance and reflection in the range of 210–1200 nm were recorded, the influence of the fabric construction and colouration were analysed. The guidelines for fabric constructor were proposed. The results show that the walnut-coloured satin samples at the third level of relative fabric density provide the best solar protection in the whole solar spectrum. All the tested eco-friendly dyed fabrics offer good solar protection, while only raw satin fabric at the third level of relative fabric density can be classified as solar protective material with even better protection in IRA region than some coloured samples.
Black Tea Extracts/Polyvinyl Alcohol Active Nanofibers Electrospun Mats with Sustained Release of Polyphenols for Food Packaging Applications
Authors: Quintero-Borregales Lucía M. , Vergara-Rubio Alicia , Santos Ayelen , Famá Lucía , Goyanes Silvia
Published: March 2023

The efficiency in the capabilities to store and release antioxidants depends on the film morphology and its manufacturing process, as well as on the type and methodology used to obtain the polyphenol extracts. Here, hydroalcoholic extracts of black tea polyphenols (BT) were obtained and dropped onto different polyvinyl alcohol (PVA) aqueous solutions (water or BT aqueous extract with and without citric acid, CA) to obtain three unusual PVA electrospun mats containing polyphenol nanoparticles within their nanofibers. It was shown that the mat obtained through the nanoparticles precipitated in BT aqueous extract PVA solution presented the highest total polyphenol content and antioxidant activity, and that the addition of CA as an esterifier or PVA crosslinker interfered with the polyphenols. The release kinetics in different food simulants (hydrophilic, lipophilic and acidic) were fitted using Fick’s diffusion law and Peppas’ and Weibull’s models, showing that polymer chain relaxation is the main mechanism in all food simulants except for the acidic, which presented an abrupt release by Fick’s diffusion mechanism of about 60% before being controlled. This research provides a strategy for the development of promising controlled-release materials for active food packaging, mainly for hydrophilic and acidic food products.
Dislodgment Resistance, Adhesive Pattern, and Dentinal Tubule Penetration of a Novel Experimental Algin Biopolymer-Incorporated Bioceramic-Based Root Canal Sealer
Authors: Lin Galvin Sim Siang , Luddin Norhayati , Ghani Huwaina Abd , Lai Josephine Chang Hui , Noorani Tahir Yusuf
Published: March 2023

The currently available bioceramic-based sealers still demonstrate low bond strength with a poor seal in root canal despite desirable biological properties. Hence, the present study aimed to determine the dislodgment resistance, adhesive pattern, and dentinal tubule penetration of a novel experimental algin-incorporated bioactive glass 58S calcium silicate-based (Bio-G) sealer and compared it with commercialised bioceramic-based sealers. A total of 112 lower premolars were instrumented to size 30. Four groups (n = 16) were assigned for the dislodgment resistance test: control, gutta-percha + Bio-G, gutta-percha + BioRoot RCS, and gutta-percha + iRoot SP, with exclusion of the control group in adhesive pattern and dentinal tubule penetration tests. Obturation was done, and teeth were placed in an incubator to allow sealer setting. For the dentinal tubule penetration test, sealers were mixed with 0.1% of rhodamine B dye. Subsequently, teeth were cut into a 1 mm-thick cross section at 5 mm and 10 mm levels from the root apex, respectively. Push-out bond strength, adhesive pattern, and dentinal tubule penetration tests were performed. Bio-G showed the highest mean push-out bond strength (p < 0.05), while iRoot SP showed the greatest sealer penetration (p < 0.05). Bio-G demonstrated more favourable adhesive patterns. No significant association was noted between dislodgment resistance and dentinal tubule penetration (p > 0.05).
One-Step High-Speed Finish Drilling of Inconel 718 Superalloy via Novel Inserts
Authors: Anwar Saqib , Khan Nauman Ahmad , Khan Sarmad Ali , Raza Syed Farhan
Published: March 2023

Inconel 718 is considered the most widely adopted nickel-based superalloy, and drilling of this alloy is always challenging for researchers. Cemented carbide twist drills have been evaluated in the drilling of this alloy by changing the cutting environment or by varying the tool geometry. In the latter case, the cutting speed has been extended from 30 m/min to 60 m/min when drills are micro-textured or ground. In this study, contrary to cemented carbide twist drills, for the first time, inserts named stepped (central) and peripheral (wiper) are evaluated in the drilling of this alloy. The central insert is designed for balanced forces, while the peripheral is a wiper insert designed for better surface finish. Drilling experiments are conducted in flood cooling conditions with a 12 mm diameter twist drill equipped with novel stepped and wiper inserts at varying cutting speeds (25, 35, and 45 m/min) and feed rates (0.04, 0.06, and 0.08 mm/rev). At a cutting speed (Vc) of 25 m/min and feed rate (f) of 0.04 mm/rev, 25 holes are drilled with roughness (Ra) values ranging from 0.40 µm to 0.60 µm, which represents a significant increase in the number of holes per drill and improved surface finish over to previous work. The new inserts showed almost three-fold longer tool life compared to a standard drill bit at a higher Vc of 45 m/min and 0.04 mm/rev f with an Ra between 0.22 µm to 0.43 µm, which is deemed acceptable for aerospace applications. In addition, minimal surface and sub-surface defects were observed, eliminating the need for a post-drilling finishing operation; therefore, a one-step drilling operation was achieved.
From Waste Biomass to Hard Carbon Anodes: Predicting the Relationship between Biomass Processing Parameters and Performance of Hard Carbons in Sodium-Ion Batteries
Authors: Jin Yanghao , Shi Ziyi , Han Tong , Yang Hanmin , Asfaw Habtom Desta , Gond Ritambhara , Younesi Reza , Jönsson Pär G. , Yang Weihong
Published: March 2023

Sodium-ion batteries (SIBs) serve as the most promising next-generation commercial batteries besides lithium-ion batteries (LIBs). Hard carbon (HC) from renewable biomass resources is the most commonly used anode material in SIBs. In this contribution, we present a review of the latest progress in the conversion of waste biomass to HC materials, and highlight their application in SIBs. Specifically, the following topics are discussed in the review: (1) the mechanism of sodium-ion storage in HC, (2) the HC precursor’s sources, (3) the processing methods and conditions of the HCs production, (4) the impact of the biomass types and carbonization temperature on the carbon structure, and (5) the effect of various carbon structures on electrochemical performance. Data from various publications have been analyzed to uncover the relationship between the processing conditions of biomass and the resulting structure of the final HC product, as well as its electrochemical performance. Our results indicate the existence of an ideal temperature range (around 1200 to 1400 °C) that enhances the formation of graphitic domains in the final HC anode and reduces the formation of open pores from the biomass precursor. This results in HC anodes with high storage capacity (>300 mAh/g) and high initial coulombic efficiency (ICE) (>80%).
Numerical Analysis of CFST Column with PBL Stiffeners under Axial Compression
Authors: Diao Yan , Guo Jiahao , He Shiyi
Published: March 2023

PBL stiffeners, made of thin-walled steel plates with circular openings and welded to the steel tube of a square concrete-filled steel tubular (CFST) column, can improve the combined effect effectively by co-carrying axial compressive forces and confining the concrete core. A numerical simulation study based on the previous test was conducted to study the ultimate strength of the CFST stub column with PBL stiffeners. Finite element models of CFST with different stiffeners were made and verified by the test results of typical failure modes and load–strain curves of specimens. The parameter study was conducted, including PBL stiffener detailing (i.e., material strength, stiffener thickness, opening diameter, and opening spacing). Finally, based on the study and analysis results, an ultimate bearing capacity prediction formula was proposed, which can reasonably predict the bearing capacity of a square CFST column with longitudinal or diagonal stiffeners, while the methods in ACI, BS5400, EC4, AIJ, and DBJ were more conservative.
Environmental Prediction in Cold Chain Transportation of Agricultural Products Based on K-Means++ and LSTM Neural Network
Authors: Jiang Junjie , Peng Cuiling , Liu Wenjing , Liu Shuangyin , Luo Zhijie , Chen Ningxia
Published: March 2023

Experiments have proven that traditional prediction research methods have limitations in practice. Proposing countermeasures for environmental changes is the key to optimal control of the cold chain environment and reducing the lag of control effects. In this paper, a cold chain transportation environment prediction method, combining k-means++ and a long short-term memory (LSTM) neural network, is proposed according to the characteristics of the cold chain transportation environment of agricultural products. The proposed prediction model can predict the trend of cold chain environment changes in the next ten minutes, which allows cold chain vehicle managers to issue control instructions to the environmental control equipment in advance. The fusion process for temperature and humidity data measured by multiple data sensors is performed with the k-means++ algorithm, and then the fused data are fed into an LSTM neural network for prediction based on time series. The prediction error of the prediction model proposed in this paper is very satisfactory, with a root-mean-square error (RMSE), mean absolute error (MAE), mean squared error (MSE), mean absolute percentage error (MAPE) and R-squared of 0.5707, 0.2484, 0.3258, 0.0312 and 0.9660, respectively, for temperature prediction, and with an RMSE, MAE, MSE, mean absolute percentage error and R-squared of 1.6015, 1.1770, 2.5648, 0.2736 and 0.9702, respectively, for humidity prediction. Finally, the LSTM neural network and back propagation (BP) neural network are compared in order to enhance the reliability of the results. In terms of the prediction effect of the temperature and humidity in cold chain vehicles transporting agricultural products, the proposed model has a higher prediction accuracy than that of existing models and can provide strategic support for the fine management and regulation of the cold chain transportation environment.
Optimized Proteome Reduction for Integrative Top–Down Proteomics
Authors: Woodland Breyer , Necakov Aleksandar , Coorssen Jens R.
Published: March 2023

Integrative top–down proteomics is an analytical approach that fully addresses the breadth and complexity needed for effective and routine assessment of proteomes. Nonetheless, any such assessments also require a rigorous review of methodology to ensure the deepest possible quantitative proteome analyses. Here, we establish an optimized general protocol for proteome extracts to improve the reduction of proteoforms and, thus, resolution in 2DE. Dithiothreitol (DTT), tributylphosphine (TBP), and 2-hydroxyethyldisulfide (HED), combined and alone, were tested in one-dimensional SDS-PAGE (1DE), prior to implementation into a full 2DE protocol. Prior to sample rehydration, reduction with 100 mM DTT + 5 mM TBP yielded increased spot counts, total signal, and spot circularity (i.e., decreased streaking) compared to other conditions and reduction protocols reported in the literature. The data indicate that many widely implemented reduction protocols are significantly ‘under-powered’ in terms of proteoform reduction and thus, limit the quality and depth of routine top–down proteomic analyses.
Can Retracted Social Science Articles Be Distinguished from Non-Retracted Articles by Some of the Same Authors, Using Benford’s Law or Other Statistical Methods?
Authors: Schumm Walter R. , Crawford Duane W. , Lockett Lorenza , Ateeq Asma bin , AlRashed Abdullah
Published: March 2023

A variety of ways to detect problems in small sample social science surveys has been discussed by a variety of authors. Here, several new approaches for detecting anomalies in large samples are presented and their use illustrated through comparisons of seven retracted or corrected journal articles with a control group of eight articles published since 2000 by a similar group of authors on similar topics; all the articles involved samples from several hundred to many thousands of participants. Given the small sample of articles (k = 15) and low statistical power, only 2/12 of individual anomaly comparisons were not statistically significant, but large effect sizes (d > 0.80) were common for most of the anomaly comparisons. A six-item total anomaly scale featured a Cronbach alpha of 0.92, suggesting that the six anomalies were moderately correlated rather than isolated issues. The total anomaly scale differentiated the two groups of articles, with an effect size of 3.55 (p < 0.001); an anomaly severity scale derived from the same six items, with an alpha of 0.94, yielded an effect size of 3.52 (p < 0.001). Deviations from the predicted distribution of first digits in regression coefficients (Benford’s Law) were associated with anomalies and differences between the two groups of articles; however, the results were mixed in terms of statistical significance, though the effect sizes were large (d ≥ 0.90). The methodology was able to detect unusual anomalies in both retracted and non-retracted articles. In conclusion, the results provide several useful approaches that may be helpful for detecting questionable research practices, especially data or results fabrication, in social science, medical, or other scientific research.
A Typology of Ad-Libbing: Performing Authenticity in Contemporary Worship
Authors: Baker Shannan K.
Published: March 2023

Since 2010, the contemporary worship scene has changed. New prominent church bands have emerged and streaming services have made worship music more accessible. While solo worship artists such as Chris Tomlin and Tim Hughes primarily released studio albums in the 2000s, two new prominent collectives, Bethel Music and Elevation Worship, followed Hillsong and Passion in releasing live albums. These live tracks have heavily influenced the local congregation. One example of this influence is the performance practice of singing ad-libs. This article will first define ad-libs within the contemporary worship context and examine how ad-libs provide authenticity to worship leaders. Then, it will explain how this performance practice moved from worship artists to local church vocalists. Finally, the article will conclude with a new typology for identifying and analyzing ad-libs in contemporary worship. Singing ad-libs in contemporary worship is an authenticating performance practice that has extended into the local church through the prominence of live recordings and therefore requires a typology for further research.
Last Prophet and Last Day: Shaykhī, Bābī and Bahā’ī Exegesis of the “Seal of the Prophets” (Q. 33:40)
Authors: Buck Christopher , Ioannesyan Youli A.
Published: March 2023

The appearance of post-Islamic religions, the Bābī and Bahā’ī Faiths, is a theoretical impossibility from an orthodox Muslim perspective, since the Qur’ān designates the Prophet Muḥammad as the “Seal of the Prophets” (Q. 33:40), widely understood as meaning the “Last of the Prophets”. To overcome this problem, the respective prophet-founders, the Bāb (1819–1850) and Bahā’u’llāh (1817–1892), each presented novel approaches which this article will explore. In short, the Bāb revealed a “new” Qur’ān, i.e., the Qayyūm al-Asmā’ (1844), and Bahā’u’llāh wrote the Kitāb-i Īqān (Book of Certitude) in January 1861. While acknowledging Muḥammad as the last prophet in the “Prophetic Cycle”, the Bāb and Bahā’u’llāh inaugurated the advent of the “Cycle of Fulfillment”. This new era was foretold in the Qur’ān by way of a symbolic code, understood metaphorically and spiritually. A key concept is that of the “divine presence” (liqā’ Allāh), i.e., the encounter/“meeting” with God, whereby Q. 33:44, Q. 83:6, Q. 7:35 (and their respective parallels) effectively transcend Q. 33:40. Recognizing that the Bāb and Bahā’u’llāh each manifests the “divine presence” thereby constitutes a “realized eschatology”. This paper represents the first time that a wide-ranging survey and analysis of the Shaykhī, Bābī, and Bahā’ī viewpoints on the subject of the “Seal of the Prophets” has been made and is the result of a collaboration between two scholars working in the United States and Russia.
The Journey through the Netherworld and the Death of the Sun God: A Novel Reading of Exodus 7–15 in Light of the Book of Gates
Authors: Lee Sanghwan
Published: March 2023

Exodus 7:8–15:21 contains a sequence of conflicts between YHWH and Pharaoh that can be divided into three parts: the Snake Confrontation, the Ten Plagues of Egypt, and the Parting of the Reed Sea. A careful reading of the entire narrative in conjunction with a New Kingdom Egyptian funerary text—the Book of Gates (BG)—reveals that both works share a number of similarities in terms of themes, terminologies, and structure. However, significant differences also occur at some crucial junctures as the respective stories unfold. These findings suggest that the Israelite author (or group of authors) might have made use of the tradition related to BG—with polemical changes—as one of his sources in framing the Exodus 7–15 narrative, in order to juxtapose the sequence of YHWH’s miracles with the progression of Pharaoh’s impending death. In this regard, Exodus 7:8–15:21 can be read as a polemical parody of the already well-established myth concerning the sun god’s journey through the Netherworld. According to this parodic reading, YHWH is the deity par excellence who stands above the Egyptian pantheon and controls order in Egypt.
Spatial Reflections on Muslims’ Segregation in Britain
Authors: Tahar Farouq , Mehan Asma , Nawratek Krzysztof
Published: March 2023

The diversity of multicultural, multi-religious, and multi-ethnic groups and communities within Britain has created cohesion and integration challenges for different community groups and authorities to adapt to the current diverse society. More recently, there has been an increased focus on Muslim segregation in Britain in official reports and reviews. Those documents mentioned the Muslims’ segregation (directly or indirectly) for various reasons, and some recommendations have aimed to improve “community cohesion” in general and Muslims’ “integration” in particular. However, community participation in the design or planning of regeneration and development projects has yet to be focused on, although these documents recommended promoting community cohesion and integration through these projects. Community participation in architecture—in its broader sense—is a crucial aspect that contributes towards fulfilling the tasks of serving communities with different religious and ethnic backgrounds. Muslims’ religious and cultural practices have been problematised in urban spaces and perceived as leading to social and spatial segregation. This paper intends to explore how secular urban spaces are used and perceived by Muslims through their religious and cultural practices. Therefore, the article aspires to inform the community participation in urban projects and demonstrates the role that Muslims’ inclusion in designing urban projects has in promoting cohesion and integration. The Ellesmere Green project in Burngreave, Sheffield, UK, is an empirical example of exploring this locally through semi-structured interviews with community members, leaders, and local authorities’ officials. The findings demonstrate that sacred and secular spaces are interconnected in Muslims’ everyday lives, and the boundaries between them are blurry. The data also show that having the ability to manifest their religious and cultural practices in secular urban spaces does not suggest the desire for segregation, nor does it reduce Muslims’ willingness to have social and spatial interactions with non-Muslims.
Inverse Kinematics of a Class of 6R Collaborative Robots with Non-Spherical Wrist
Authors: Carbonari Luca , Palpacelli Matteo-Claudio , Callegari Massimo
Published: March 2023

The spread of cobotsin common industrial practice has led constructors to prefer the development of collaborative features that are necessary to prevent injuries to operators over the realization of simple kinematic structures for which the joints-to-workspace mapping is well known. An example is given by the replacement in serial robots of spherical wrists with safer solutions, where the danger of crushing and shearing is intrinsically avoided. Despite this tendency, the kinematic map between actuated joints and the Cartesian workspace remains of paramount importance for robot analysis and programming, deserving the attention of the research community. This paper proposes a closed-form solution for the inverse kinematics of a class of 6R robotic arms with six degrees of freedom and non-spherical wrists. The solutions are worked out by a single polynomial, of minimum degree, in terms of one of the positioning parameters chosen for the description of the robot posture. The roots of such a polynomial are then back-substituted to determine all the remaining unknowns. A numerical example is finally shown to verify the validity of the proposed implementation for a commercial collaborative robot.
Spatiotemporal and Vertical Distribution of Asian Tropopause Aerosol Layer Using Long-Term Multi-Source Data
Authors: Liu Hongchao , Li Ren , Ma Junjie
Published: March 2023

The Asian tropopause aerosol layer (ATAL) is an enhanced aerosol concentration layer in the upper troposphere and lower stratosphere over Asia, and it has important effects on radiation balance, atmospheric circulation, regional climate, and atmospheric chemical processes. However, despite its importance, the specific structure and long-term variation trend of the ATAL have been rarely analyzed, which is critical for assessing the impact of ATAL on climate change and evaluating the performance of climate models. This study compared and analyzed the three-dimensional spatial distribution characteristics and temporal variability using CALIPSO, SAGEII, and MERRA-2 data and discussed the possible causes of the variation. The results showed that the ATAL began to appear in the mid-to-late 1990s and then strengthened rapidly until 2010, after which this trend was no longer observed. Moreover, significant heterogeneity existed in the distribution of aerosol concentration in the ATAL, showing north–south differences (NSDs) in both time and space. In addition, it was found that besides surface emissions, atmospheric circulation, the strength of convective transport, and stratosphere–troposphere exchange processes also contribute to this pattern. This study has important implications for quantifying the climate consequences of the ATAL.