bluuebunny/crossref_metadata_2025 huggingface dataset:
Carbon-Doped Co2MnSi Heusler Alloy Microwires with Improved Thermal Characteristics of Magnetization for Multifunctional Applications
Authors: Salaheldeen Mohamed , Wederni Asma , Ipatov Mihail , Zhukova Valentina , Zhukov Arcady
Published: July 2023

In the current work, we illustrate the effect of adding a small amount of carbon to very common Co2MnSi Heusler alloy-based glass-coated microwires. A significant change in the magnetic and structure structural properties was observed for the new alloy Co2MnSiC compared to the Co2MnSi alloy. Magneto-structural investigations were performed to clarify the main physical parameters, i.e., structural and magnetic parameters, at a wide range of measuring temperatures. The XRD analysis illustrated the well-defined crystalline structure with average grain size (Dg = 29.16 nm) and a uniform cubic structure with A2 type compared to the mixed L21 and B2 cubic structures for Co2MnSi-based glass-coated microwires. The magnetic behavior was investigated at a temperature range of 5 to 300 K and under an applied external magnetic field (50 Oe to 20 kOe). The thermomagnetic behavior of Co2MnSiC glass-coated microwires shows a perfectly stable behavior for a temperature range from 300 K to 5 K. By studying the field cooling (FC) and field heating (FH) magnetization curves at a wide range of applied external magnetic fields, we detected a critical magnetic field (H = 1 kOe) where FC and FH curves have a stable magnetic behavior for the Co2MnSiC sample; such stability was not found in the Co2MnSi sample. We proposed a phenomenal expression to estimate the magnetization thermal stability, ΔM (%), of FC and FH magnetization curves, and the maximum value was detected at the critical magnetic field where ΔM (%) ≈ 98%. The promising magnetic stability of Co2MnSiC glass-coated microwires with temperature is due to the changing of the microstructure induced by the addition of carbon, as the A2-type structure shows a unique stability in response to variation in the temperature and the external magnetic field. In addition, a unique internal mechanical stress was induced during the fabrication process and played a role in controlling magnetic behavior with the temperature and external magnetic field. The obtained results make Co2MnSiC a promising candidate for magnetic sensing devices based on Heusler glass-coated microwires.
Fabrication of Nitrogen-Doped Carbon@Magnesium Silicate Composite by One-Step Hydrothermal Method and Its High-Efficiency Adsorption of As(V) and Tetracycline
Authors: Wang Xuekai , Wang Jinshu , Li Jianjun , Du Yucheng , Wu Junshu , He Heng
Published: July 2023

Tetracycline (TC) and arsenic contaminants are two main pollutants in aquaculture and livestock husbandry, and they have drawn worldwide attention. To address this issue, a novel N-doped carbon@magnesium silicate (CMS) was fabricated via a facile and low-cost hydrothermal route, adopting glucose and ammonia as C and N sources, respectively. The synergetic combination of carbon and magnesium silicate makes CMS possess a high surface area of 201 m2/g and abundant functional groups. Due to the abundant C- and N-containing functional groups and Mg-containing adsorptive sites, the maximum adsorption capacity values of CMS towards As(V) and TC are 498.75 mg/g and 1228.5 mg/g, respectively. The type of adsorption of As(V) and TC onto CMS is monolayer adsorption. An adsorption kinetic study revealed that the mass transfer and intraparticle process dominates the sorption rate of As(V) and TC adsorption onto CMS, respectively. Various functional groups synthetically participate in the adsorption process through complexion, π–π EDA interactions, and hydrogen bonds. This work provides a one-step, low-cost route to fabricate a N-doped carbonaceous adsorbent with a high surface area and abundant functional groups, which has great potential in the application of practical sewage treatment.
Predicting the Effect of Surface Waviness on Fatigue Life of a Wire + Arc Additive Manufactured Ti-6Al-4V Alloy
Authors: Shamir Muhammad , Zhang Xiang , Syed Abdul Khadar , Sadler Wayne
Published: July 2023

This paper reports the effect of as-deposited surface conditions on the fatigue strength of an additively manufactured titanium alloy, Ti-6Al-4V (WAAM Ti64). First, the local stress concentration caused by the surface waviness was quantified using a metrology technique and computer modelling. Fatigue tests were conducted under bending loads at a cyclic load ratio of 0.1. The applicability of two predictive methods was the focus of this study. The traditional notch stress method was unable to predict the correct S–N curve trend slope, which could be attributed to the early crack initiation from the troughs on the as-built surface, with crack propagation being the dominant failure mechanism. By treating the troughs as small cracks, the fracture mechanics approach delivered good predictions at every applied stress level. Surface machining and polishing may not always be practical or required; it depends on the applications and service load levels. This research demonstrated that the fracture mechanics approach can be used for predicting the fatigue life of WAAM titanium alloys in as-built conditions and, hence, can be a tool for decision making on the level of surface machining.
Preparation of Hydrophobic Octadecylphosphonic Acid-Coated Magnetite Nanoparticles for the Demulsification of n-Hexane-in-Water Nanoemulsions
Authors: Liang Jiling , Han Tingting , Wang Wenwu , Zhang Lunqiu , Zhang Yan
Published: July 2023

To design more environmentally friendly, economical, and efficient demulsifiers for oily wastewater treatment, hydrophobic octadecylphosphonic acid (ODPA)-modified Fe3O4 nanoparticles (referred to as Fe3O4@ODPA) were prepared by condensation of hydroxyl groups between ODPA and Fe3O4 nanoparticles using the co-precipitation method. The prepared magnetite nanoparticles were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscope (SEM), Fourier transform infrared (FTIR) spectroscopy, and thermogravimetric/differential thermogravimetric (TG/DTG) analysis. The water contact angles (θW) of Fe3O4@ODPA nanoparticles were more than 120°, indicating hydrophobic nature, and the diameter of the obtained spherical-shaped magnetite nanoparticles was 12–15 nm. The ODPA coating amount (AO) (coating weight per gram Fe3O4) and specific surface area (SO) of Fe3O4@ODPA were 0.124–0.144 g·g−1 and 78.65–91.01 m2·g−1, respectively. To evaluate the demulsification ability, stability, and reusability, the magnetite nanoparticles were used to demulsify an n-hexane-in-water nanoemulsion. The effects of the magnetite nanoparticle dosage (CS), pH value of nanoemulsion, and NaCl or CaCl2 electrolytes on the demulsification efficiency (RO) were investigated. The RO of Fe3O4@ODPA samples was found to be higher than that of bare Fe3O4 samples (S0, ST, and SN) under all CS values. With the increase in CS, the RO of Fe3O4@ODPA samples initially increased and then approached equilibrium value at Cs = 80.0 g·L−1. A maximum RO of ~93% was achieved at CS = 100.0 g·L−1 for the Fe3O4@ODPA sample S2. The pH and two electrolytes had a minor effect on RO. The Fe3O4@ODPA nanoparticles maintained high RO even after being reused for demulsification 11 times. This indicates that the hydrophobic Fe3O4@ODPA samples can be used as an effective magnetite demulsifer for oil-in-water nanoemulsions.
Simulation of Corrosion Phenomena in Automotive Components: A Case Study
Authors: Ferrarotti Annalisa , Ghiggini Elisa Vittoria , Rocca Riccardo , Dotoli Matteo , Scaglione Federico , Errigo Claudio , Marchiaro Giancarlo , Baricco Marcello
Published: July 2023

Mathematical modelling and software simulation nowadays are very effective tools for both understanding and predicting corrosion processes and the protection of metallic components. COMSOL Multiphysics 5.6 software provides validated mathematical models that can be used, for a given geometry, as a tool to predict and prevent corrosion of components. The corrosion of zinc-coated steel sheets has been studied in this work by comparing results of the simulations with laboratory tests carried out in a salt spray. Results of both the mathematical modelling and empirical tests give the possibility to estimate the stability of the protective zinc layer over time. The examination of the discrepancies between two analytical methods for the investigation of corrosion phenomena leads to possible modifications in the model in order to reach as much as possible coherence with experimental data. As a final result, a computational model of corrosion phenomena in an automotive component has been reached, allowing in the future to partially substitute laboratory tests, usually being highly time consuming and expensive.
Structure of Complex Concentrated Alloys Derived from Iron Aluminide Fe3Al
Authors: Pešička Josef , Kratochvíl Petr , Král Robert , Veselý Jozef , Jača Eliška , Preisler Dalibor , Daniš Stanislav , Minárik Peter , Čamek Libor
Published: July 2023

The phase structure and composition of a series of four alloys based on Fe3Al was investigated by means of scanning electron microscopy, X-ray diffraction and transmission electron microscopy. The materials were composed of Fe and Al with a fixed ratio of 3:1 alloyed with V, Cr and Ni at 8, 12, 15 and 20 at. % each (composition formula: Fe3(100−3x)/4 Al(100−3x)/4VxCrxNix). For 8% alloying, the material is single-phase D03. Furthermore, 12 and 15% alloying results in bcc–B2 phase separation on two length scales. Moreover, 20% alloying gives rise to the FeNiCrV σ phase supplemented by B2. These findings are discussed with respect to the results obtained via Calphad modeling using the TCHEA5 database and can serve in further improvement.
Ab Initio Characterization of Magnetoelectric Coupling in Fe/BaTiO3, Fe/SrTiO3, Co/BaTiO3 and Co/SrTiO3 Heterostructures
Authors: Piyanzina Irina , Evseev Kirill , Kamashev Andrey , Mamin Rinat
Published: July 2023

Magneto-electric coupling is a desirable property for a material used in modern electronic devices to possess due to the favorable possibilities of tuning the electronic properties using a magnetic field and vice versa. However, such materials are rare in nature. That is why the so-called superlattice approach to creating such materials is receiving so much attention. In the superlattice approach, the functionality of a combined heterostructure depends on the interacting components and can be adjusted depending on the desired property. In the present paper, we present supercells of ferromagnetic thin films of Fe and Co deposited on ferroelectric and piezoelectric substrates of BaTiO3 and SrTiO3 that exhibit magnetism, ferroelectric polarization and piezoelectric effects. Within the structures under investigation, magnetic moments can be tuned by an external electric field via the ferroelectric dipoles. We investigate the effect of magnetoelectric coupling by means of ab initio spin-polarized and spin–orbit calculations. We study the structural, electronic and magnetic properties of heterostructures, and show that electrostriction can reduce the magnitude of the magnetization vector of a ferromagnet. This approach can become the basis for controlling the properties of one of the ferromagnetic layers of a superconducting spin valve, and thus the superconducting properties of the valve.
A Parameterized Multi-Splitting Iterative Method for Solving the PageRank Problem
Authors: Xie Yajun , Hu Lihua , Ma Changfeng
Published: July 2023

In this paper, a new multi-parameter iterative algorithm is proposed to address the PageRank problem based on the multi-splitting iteration method. The proposed method solves two linear subsystems at each iteration by splitting the coefficient matrix, considering therefore inner and outer iteration to find the approximate solutions of these linear subsystems. It can be shown that the iterative sequence generated by the multi-parameter iterative algorithm finally converges to the PageRank vector when the parameters satisfy certain conditions. Numerical experiments show that the proposed algorithm has better convergence and numerical stability than the existing algorithms.
Three-Dimensional Printing Enabled Droplet Microfluidic Device for Real-Time Monitoring of Single-Cell Viability and Blebbing Activity
Authors: Lin Meiai , Liu Ting , Liu Yeqian , Lin Zequan , Chen Jiale , Song Jing , Qiu Yiya , Zhou Benqing
Published: July 2023

Droplet-based microfluidics with the characteristics of high throughput, low sample consumption, increasing reaction speed, and homogeneous volume control have been demonstrated as a useful platform for biomedical research and applications. The traditional fabrication methods of droplet microfluidics largely rely on expensive instruments, sophisticated operations, and even the requirement of an ultraclean room. In this manuscript, we present a 3D printing-based droplet microfluidic system with a specifically designed microstructure for droplet generation aimed at developing a more accessible and cost-effective method. The performance of droplet generation and the encapsulation capacity of the setup were examined. The device was further applied to measure the variation in cell viability over time and monitor the cell’s blebbing activity to investigate its potential ability and feasibility for single-cell analysis. The result demonstrated that the produced droplets remained stable enough to enable the long-time detection of cell viability. Additionally, cell membrane protrusions featuring the life cycle of bleb initiation, expansion, and retraction can be well-observed. Three-dimensional printing-based droplet microfluidics benefit from the ease of manufacture, which is expected to simplify the fabrication of microfluidics and expand the application of the droplet approach in biomedical fields.
Securing Embedded System from Code Reuse Attacks: A Lightweight Scheme with Hardware Assistance
Authors: An Zhenliang , Wang Weike , Li Wenxin , Li Senyang , Zhang Dexue
Published: July 2023

The growing prevalence of embedded systems in various applications has raised concerns about their vulnerability to malicious code reuse attacks. Current software-based and hardware-assisted security techniques struggle to detect or block these attacks with minor performance and implementation overhead. To address this issue, this paper presents a lightweight hardware-assisted scheme to enhance the security of embedded systems against code reuse attacks. We develop an on-chip lightweight hardware shadow stack to validate target addresses at runtime for backward-edge control flow integrity, which backs up valid return addresses during function calls and automatically verifies actual return addresses during the return phase. Additionally, we propose a lightweight stream cipher circuit that encrypts and decrypts critical stack data related to control flow manipulation, preventing attackers from analyzing or tampering with them. When designing and implementing the security mechanism for embedded systems, we fully consider the constraints of limited system resources and performance, optimizing both the architecture design and implementation of the proposed hardware. Finally, we integrate both the proposed lightweight hardware shadow stack and the runtime data encryption hardware into the OR1200 processor. We have verified the system security function on the Terasic DE1-SoC FPGA platform and evaluated the system performance as well as implementation overhead. The results show that the proposed lightweight hardware-assisted scheme can provide a dedicated defense capability against code reuse attacks for embedded systems, with an average system performance overhead of 0.39% and an area footprint of 0.316 mm2.
Enhancing EDM Machining Precision through Deep Cryogenically Treated Electrodes and ANN Modelling Approach
Authors: Ishfaq Kashif , Sana Muhammad , Waseem Muhammad Umair , Ashraf Waqar Muhammad , Anwar Saqib , Krzywanski Jaroslaw
Published: July 2023

The critical applications of difficult-to-machine Inconel 617 (IN617) compel the process to be accurate enough that the requirement of tight tolerances can be met. Electric discharge machining (EDM) is commonly engaged in its machining. However, the intrinsic issue of over/undercut in EDM complicates the achievement of accurately machined profiles. Therefore, the proficiency of deep cryogenically treated (DCT) copper (Cu) and brass electrodes under modified dielectrics has been thoroughly investigated to address the issue. A complete factorial design was implemented to machine a 300 μm deep impression on IN617. The machining ability of DCT electrodes averagely gave better dimensional accuracy as compared to non-DCT electrodes by 13.5% in various modified dielectric mediums. The performance of DCT brass is 29.7% better overall compared to the average value of overcut (OC) given by DCT electrodes. Among the non-treated (NT) electrodes, the performance of Cu stands out when employing a Kerosene-Span-20 modified dielectric. In comparison to Kerosene-Tween-80, the value of OC is 33.3% less if Kerosene-Span-20 is used as a dielectric against the aforementioned NT electrode. Finally, OC’s nonlinear and complex phenomena are effectively modeled by an artificial neural network (ANN) with good prediction accuracy, thereby eliminating the need for experiments.
Uniaxial Cyclic Cell Stretching Device for Accelerating Cellular Studies
Authors: Yadav Sharda , Singha Pradip , Nguyen Nhat-Khuong , Ooi Chin Hong , Kashaninejad Navid , Nguyen Nam-Trung
Published: July 2023

Cellular response to mechanical stimuli is a crucial factor for maintaining cell homeostasis. The interaction between the extracellular matrix and mechanical stress plays a significant role in organizing the cytoskeleton and aligning cells. Tools that apply mechanical forces to cells and tissues, as well as those capable of measuring the mechanical properties of biological cells, have greatly contributed to our understanding of fundamental mechanobiology. These tools have been extensively employed to unveil the substantial influence of mechanical cues on the development and progression of various diseases. In this report, we present an economical and high-performance uniaxial cell stretching device. This paper reports the detailed operation concept of the device, experimental design, and characterization. The device was tested with MDA-MB-231 breast cancer cells. The experimental results agree well with previously documented morphological changes resulting from stretching forces on cancer cells. Remarkably, our new device demonstrates comparable cellular changes within 30 min compared with the previous 2 h stretching duration. This third-generation device significantly improved the stretching capabilities compared with its previous counterparts, resulting in a remarkable reduction in stretching time and a substantial increase in overall efficiency. Moreover, the device design incorporates an open-source software interface, facilitating convenient parameter adjustments such as strain, stretching speed, frequency, and duration. Its versatility enables seamless integration with various optical microscopes, thereby yielding novel insights into the realm of mechanobiology.
Improving Pure Titanium’s Biological and Mechanical Characteristics through ECAP and Micro-Arc Oxidation Processes
Authors: Alemayehu Dawit Bogale , Todoh Masahiro , Hsieh Jang-Hsing , Li Chuan , Huang Song-Jeng
Published: July 2023

Pure titanium is limited to be used in biomedical applications due to its lower mechanical strength compared to its alloy counterpart. To enhance its properties and improve medical implants feasibility, advancements in titanium processing technologies are necessary. One such technique is equal-channel angular pressing (ECAP) for its severe plastic deformation (SPD). This study aims to surface modify commercially pure titanium using micro-arc oxidation (MAO) or plasma electrolytic oxidation (PEO) technologies, and mineral solutions containing Ca and P. The composition, metallography, and shape of the changed surface were characterized using X-ray diffraction (XRD), digital optical microscopy (OM), and scanning electron microscope (SEM), respectively. A microhardness test is conducted to assess each sample’s mechanical strength. The weight % of Ca and P in the coating was determined using energy dispersive spectroscopy (EDS), and the corrosion resistance was evaluated through potentiodynamic measurement. The behavior of human dental pulp cell and periodontal cell behavior was also studied through a biomedical experiment over a period of 1-, 3-, and 7-days using culture medium, and the cell death and viability can be inferred with the help of enzyme-linked immunosorbent assay (ELISA) since it can detect proteins or biomarkers secreted by cells undergoing apoptosis or necrosis. This study shows that the mechanical grain refinement method and surface modification might improve the mechanical and biomechanical properties of commercially pure (CP) titanium. According to the results of the corrosion loss measurements, 2PassMAO had the lowest corrosion rate, which is determined to be 0.495 mmpy. The electrode potentials for the 1-pass and 2-pass coated samples are 1.44 V and 1.47 V, respectively. This suggests that the coating is highly effective in reducing the corrosion rate of the metallic CP Ti sample. Changes in the grain size and the presence of a high number of grain boundaries have a significant impact on the corrosion resistance of CP Ti. For ECAPED and surface-modified titanium samples in a 3.6% NaCl electrolyte solution, electrochemical impedance spectroscopy (EIS) properties are similar to Nyquist and Bode plot fitting. In light of ISO 10993-5 guidelines for assessing in vitro cytotoxicity, this study contributes valuable insights into pulp and periodontal cell behavior, focusing specifically on material cytotoxicity, a critical factor determined by a 30% decrease in cell viability.
Design of a High-Speed Rotary Ultrasonic Machining Machine Tool for Machining Microstructure of Brittle Materials
Authors: Zhang Shanhua , Gong Manfeng , Lian Haishan , Wu Jianfeng , Zhu Weijie , Ou Zhengwei
Published: July 2023

Aiming at the problems of low machining accuracy and more serious tool wear in the traditional diamond grinding machining (DGM) microstructure of hard and brittle materials, this paper proposes high-speed rotary ultrasonic machining (HRUM) technology and develops a HRUM machine tool. The hardware part of the machine tool mainly includes the spindle module, micro-motion system module, ultrasonic machining tank module, and data acquisition (DAQ) system module. The LabView-based controlled machining control system, including motion selection, initialization, coarse tool setting, constant force tool setting, control machining, and coordinate display module, is developed. Comparative experimental research of the HRUM and DGM of small holes in Al2O3 ceramics is carried out in the developed HRUM machine tool. The results demonstrate that HRUM effectively reduces axial cutting forces, reduces binder adhesion, and suppresses slippage while improving tool-cutting ability and extending tool life compared to DGM under the same machining parameters. This technology has essential research significance for the high-precision and efficient machining of microstructures in hard and brittle materials.
Review of the Flight Control Method of a Bird-like Flapping-Wing Air Vehicle
Authors: Fang Xiaoqing , Wen Yian , Gao Zhida , Gao Kai , Luo Qi , Peng Hui , Du Ronghua
Published: July 2023

The Bird-like Flapping-wing Air Vehicle (BFAV) is a robotic innovation that emulates the flight patterns of birds. In comparison to fixed-wing and rotary-wing air vehicles, the BFAV offers superior attributes such as stealth, enhanced maneuverability, strong adaptability, and low noise, which render the BFAV a promising prospect for numerous applications. Consequently, it represents a crucial direction of research in the field of air vehicles for the foreseeable future. However, the flapping-wing vehicle is a nonlinear and unsteady system, posing significant challenges for BFAV to achieve autonomous flying since it is difficult to analyze and characterize using traditional methods and aerodynamics. Hence, flight control as a major key for flapping-wing air vehicles to achieve autonomous flight garners considerable attention from scholars. This paper presents an exposition of the flight principles of BFAV, followed by a comprehensive analysis of various significant factors that impact bird flight. Subsequently, a review of the existing literature on flight control in BFAV is conducted, and the flight control of BFAV is categorized into three distinct components: position control, trajectory tracking control, and formation control. Additionally, the latest advancements in control algorithms for each component are deliberated and analyzed. Ultimately, a projection on forthcoming directions of research is presented.
Tectonic Transition from Passive to Active Continental Margin of Nenjiang Ocean: Insight from the Middle Devonian-Early Carboniferous Granitic Rocks in Northern Great Xing’an Range, NE China
Authors: Zhang Li , Ma Yongfei , Liu Yongjiang , Yuan Sihua , Yang Hongzhi , Li Weimin , Liang Chenyue , Feng Zhiqiang
Published: July 2023

Northeast China occupies the majority of the eastern Central Asian Orogenic Belt, which mainly consists of continental blocks and accretionary terranes. The Devonian was a tectonic quiet period in the NE China region due to a lack of tectono-magmatism, but the tectonic background of this period has been unclear, especially for the Hegenshan-Heihe Suture between Xing’an and Songliao accretionary terranes, which represents the Paleozoic Nenjiang Ocean (a branch ocean of the eastern Paleo-Asian Ocean). Here we report granitic rocks from the Woluohe area, Northern Great Xing’an Range, NE China, to constrain the tectonic process of the transition from the Devonian quiet period to the Early Carboniferous active tectonic period. Three granitic rock samples produce zircon U-Pb ages of 389 Ma, 368 Ma, and 351 Ma, belonging to the Middle and Late Devonian and Early Carboniferous, respectively. They have high Si, Al, K, and Na contents, but with low Mg, Fe, and Ti contents, together with positive Hf isotopic features and low molar Al2O3/(MgO+FeOT) ratios, we suggest that they were derived from partial melting of lower crustal igneous rocks. Meanwhile, the narrow major element variation at odd with the fractionation process and their negative Nb and Ta anomalies imply the obvious contribution of crustal. Comprehensive tectonic setting analysis shows all samples are in calc-alkali magmatic series with rightward fractionated REE and trace element patterns that are enriched in LREE and LILE and depleted in HREE and HFS, indicating a subduction-related magmatic arc setting. Considering the regional tectonic setting and the small scale of the Devonian plutons, we suggest a limited subduction tectonic setting during the quiet period of the northern Great Xing’an Range, which might indicate the beginning of an initial northwestward subduction of the Nenjiang Oceanic lithosphere beneath the Xing’an Accretionary Terrane in the Middle Devonian, accelerated subduction in the Late Devonian, and bidirectional subduction in the Early Carboniferous.
The Influence of Surface Heterogeneity of Fluorite on the Adsorption of Alkyl Sulfonates
Authors: He Yuhao , Wang Zengzi , Ren Zijie , Zheng Renji , Gao Huimin , Chen Zhijie
Published: July 2023

Surface heterogeneity of minerals can significantly affect the adsorption of collectors. Petroleum sulfonate is widely used as a fluorite collector, but how the surface heterogeneity of fluorite influences the adsorption of alkyl sulfonates remains unknown. Herein, two kinds of surface heterogeneity situations, i.e., edge and (1 1 1) _vacancy, were modeled, and the adsorption of sodium dodecyl sulfonate on them was simulated. The results show that the stable adsorption configuration of sodium dodecyl sulfonate on the edge was in a bridged mode, and the stable interaction configuration with vacancy was in a tridentate mode. The 2p orbit of fluorine on the surface of the edge and the vacancy could hinder collector adsorption. After adsorption, the 3d orbit of calcium interacted with the collector orbit above Fermi level, and moved towards the lower energy level, benefiting the adsorption process. It was also found that the adsorption intensity/strength of alkyl sulfonate on fluorite was directly proportional to the interaction intensity of the collector with the 3d orbits of calcium ions on the surface and vacancy. Therefore, the rough fluorite surface had a stronger adsorption effect on the collector, and the existence of vacancy could improve the surface adsorption energy, and thus enhance the adsorption of the collector on the fluorite surface. The rough fluorite surface requires high collector concentration to achieve saturated monolayer adsorption, so increasing vacancy was the better choice to improve the adsorption capacity of alkyl sulfonate on the fluorite surface. This study provides novel insights into the flotation mechanism, in the context of surface heterogeneity, and could guide the design of high-performance collectors for fluorite ore flotation.
Bioleaching of Zinc from Blast Furnace Cast House Dust
Authors: Sasiain Amaia , Thallner Sophie , Habermaier Clemens , Spiess Sabine , Birklbauer Ludwig , Wallner Martin , Haberbauer Marianne
Published: July 2023

Metallurgical dusts are by-products from steel manufacturing. The high iron content of cast house dust (~64%) makes this by-product an interesting iron feedstock alternative. Therefore, its return into the internal steelmaking circuit, specifically in the sinter plant, is a common practice in the steel industry. However, this dust fraction also contains heavy metals, as zinc. As a result of the re-entry of zinc into the process, the zinc concentration in the blast furnace flue gas dust also increases. This prevents the full recirculation of the blast furnace flue gas dust in the steelmaking process despite its relatively high iron content (~35%), thus causing part of the blast furnace flue gas dust to end in the landfill. The goal of this study was to investigate the usage of bacteria, such as the sulfur oxidizing Acidithiobacillus thiooxidans or the iron and sulfur oxidizing Acidithiobacillus ferrooxidans, to leach the undesirable element zinc from the cast house dust while preventing the leaching of iron, by adjusting the sulfur addition and avoiding, at the same time, the accumulation of sulfur in the solid fraction. Experiments proved that a co-culture of A. thiooxidans and A. ferrooxidans can effectively leach zinc from metallurgical dusts, maintaining high iron concentrations in the material. The influence of elemental sulfur on the efficiencies reached was shown, since higher removal efficiencies were achieved with increasing sulfur concentrations. Maximum zinc leaching efficiencies of ~63% (w/w) and an iron enrichment of ~7% (w/w) in the remaining residue were achieved with sulfur concentrations of 15 g/L for cast house gas concentrations of 125 g/L.
Multi-Scale Potential Field Data Integration Using Fuzzy C-Means Clustering for Automated Geological Mapping of North Singhbhum Mobile Belt, Eastern Indian Craton
Authors: Kumar Santosh , Arasada Rama Chandrudu , Rao Gangumalla Srinivasa
Published: July 2023

Fuzzy C-Means (FCM) clustering is an unsupervised machine learning algorithm that helps to integrate multiple geophysical datasets and provides automated objective-oriented information. This study analyzed ground-based Bouguer gravity and aeromagnetic datasets using the FCM clustering algorithm to classify lithological units in the western part of the North Singhbhum Mobile Belt, a mineralized belt in the Eastern Indian Craton. The potential field signatures of clusters obtained using FCM correlate remarkably well with the existing surface geology on a broad scale. The cluster associated with the highest gravity signatures corresponds to the metabasic rocks, and the cluster with the highest magnetic response represents the mica schist rocks. The cluster characterized by the lowest gravity and magnetic responses reflects the granite gneiss rocks. However, few geological formations are represented by two or more clusters, probably due to the close association of similar rock types. The fuzzy membership scores for most of the data points in each cluster show above 0.8, indicating a consistent relationship between geophysical signatures and the existing lithological units. Further, the study reveals that integrating multi-scale geophysical data helps to disclose bedrock information and litho-units under the sediment cover.
Frankamenite: Relationship between the Crystal–Chemical and Vibrational Properties
Authors: Kaneva Ekaterina , Shendrik Roman , Pankrushina Elizaveta , Dokuchits Emilia , Radomskaya Tatiana , Pechurin Mikhail , Ushakov Aleksey
Published: July 2023

The study provides novel insights into the crystal–chemical and optical characteristics of frankamenite. Frankamenite belongs to a special group (canasite group) of the complex alkaline Ca-(K)-(Na) silicates, and it was found in charoitites from the only known location, Murun Massif, Eastern Siberia, Russia. The crystal–chemical, vibrational, and optical properties of frankamenite were investigated by combining electron probe microanalysis (EPMA), single-crystal X-ray diffraction (SCXRD), infrared (IR) absorption, Raman, UV-Visible absorption, and electron spin resonance (ESR) spectroscopy. The behavior of the peaks in the IR spectra was also studied using ab initio calculations. Detailed characteristics of the internal composition and structure of the mineral species were described, and vibrational and optical properties based on these peculiarities were interpreted. The thermally stimulated reorientation of the H2O molecules and OH− groups was studied by thermo-Raman spectroscopy. Octahedral cationic positions can be readily doped with transition metal and lanthanide ions that provide a promising opportunity to adjust the Ce3+ luminescence. Hence, frankamenite is a potential material for ion exchange, novel phosphors, and luminophores.
Dietary Fat Modulation of Gut Microbiota and Impact on Regulatory Pathways Controlling Food Intake
Authors: Hamamah Sevag , Amin Arman , Al-Kassir Abdul Latif , Chuang Judith , Covasa Mihai
Published: July 2023

Obesity is a multifactorial disease that continues to increase in prevalence worldwide. Emerging evidence has shown that the development of obesity may be influenced by taxonomic shifts in gut microbiota in response to the consumption of dietary fats. Further, these alterations in gut microbiota have been shown to promote important changes in satiation signals including gut hormones (leptin, ghrelin, GLP-1, peptide YY and CCK) and orexigenic and anorexigenic neuropeptides (AgRP, NPY, POMC, CART) that influence hyperphagia and therefore obesity. In this review, we highlight mechanisms by which gut microbiota can influence these satiation signals both locally in the gastrointestinal tract and via microbiota-gut-brain communication. Then, we describe the effects of dietary interventions and associated changes in gut microbiota on satiety signals through microbiota-dependent mechanisms. Lastly, we present microbiota optimizing therapies including prebiotics, probiotics, synbiotics and weight loss surgery that can help restore beneficial gut microbiota by enhancing satiety signals to reduce hyperphagia and subsequent obesity. Overall, a better understanding of the mechanisms by which dietary fats induce taxonomical shifts in gut microbiota and their impact on satiation signaling pathways will help develop more targeted therapeutic interventions in delaying the onset of obesity and in furthering its treatment.
Rosmarinic Acid Improves Cognitive Abilities and Glucose Metabolism in Aged C57Bl/6N Mice While Disrupting Lipid Profile in Young Adults in a Sex-Dependent Fashion
Authors: Musillo Chiara , Giona Letizia , Ristow Michael , Zarse Kim , Siems Karsten , Di Francesco Alessia , Collacchi Barbara , Raggi Carla , Cirulli Francesca , Berry Alessandra
Published: July 2023

A growing body of evidence suggests that regular consumption of natural products might promote healthy aging; however, their mechanisms of action are still unclear. Rosmarinic acid (RA) is a polyphenol holding anti-inflammatory, antioxidant and neuroprotective properties. The aim of this study was to characterise the efficacy of an oral administration of RA in promoting healthspan in a mouse model of physiological aging. Aged C57Bl/6 male and female (24-month-old) mice were either administered with RA (500 mg/Kg) or a vehicle in drinking bottles for 52 days while 3-month-old mice receiving the same treatment were used as controls. All subjects were assessed for cognitive abilities in the Morris water maze (MWM) and for emotionality in the elevated-plus maze test (EPM). Brain-derived Neurotrophic Factor (BDNF) protein levels were evaluated in the hippocampus. Since the interaction between metabolic signals and cerebral functions plays a pivotal role in the etiopathogenesis of cognitive decline, the glycaemic and lipid profiles of the mice were also assessed. RA enhanced learning and memory in 24-month-old mice, an effect that was associated to improved glucose homeostasis. By contrast, the lipid profile was disrupted in young adults. This effect was associated with worse glycaemic control in males and with reduced BDNF levels in females, suggesting powerful sex-dependent effects and raising a note of caution for RA administration in young healthy adult subjects.
Dietary Behaviour and Sociocultural Determinants of Dietary Diversity among Rural Women of Reproductive Age: A Case of Amhara Region, Ethiopia
Authors: Alamirew Simegn Kassa , Lemke Stefanie , Stadlmayr Barbara , Freyer Bernhard
Published: July 2023

Women of reproductive age have specific nutritional requirements due to pregnancy and lactation. Little is known about the sociocultural determinants of dietary diversity among women of reproductive age. This study assesses trends of dietary behaviour and associated determinants of dietary diversity of women of reproductive age. A community-based cross-sectional study was conducted in the Amhara region of Ethiopia in 2019. Using multistage systematic random sampling, the dietary diversity of n = 421 women of reproductive age was assessed by a qualitative 24 h dietary recall. Descriptive analysis revealed characteristics of dietary behaviour and a chi-square test enabled the identification of associated determinants of women’s dietary diversity. Only about a quarter (26.8%) of the women consumed five or more food groups per day and met the minimum dietary diversity score (MDD-W). Drawing on the socioecological framework, at an intrapersonal/individual level, women’s education, age, perception of nutritious diet, and frequency of consumption of animal-sourced foods, vegetables, and fruit were significantly associated with MDD-W. At an interpersonal/household level, the husbands’ education, women’s decision-making regarding food purchase/consumption, the family’s actual eating occasion, and women’s engagement in domestic and farming tasks were significantly associated with MDD-W. At a community level, access to clean water and especially cultural beliefs were significant determinants of MDD-W. Amharic proverbs and sayings prioritise men and pose severe restrictions on women regarding food allocation. The majority (76.7%) of women of reproductive age practise frequent religious fasting, relating to the institutional/national level. This undermines efforts to support healthy dietary behaviour of women of reproductive age. Indepth studies on religious and cultural practices are needed, to assess not only their negative effects on the dietary diversity of women of reproductive age but also on women’s lives.
Strategies to Improve Physical Activity and Nutrition Behaviours in Children and Adolescents: A Review
Authors: Jayasinghe Sisitha , Hills Andrew P.
Published: July 2023

Despite widespread acknowledgement of the multifarious health benefits of physical activity (PA), including prevention and control of obesity, an overwhelming majority of children and adolescents are not sufficiently active to realise such benefits. Concurrently, young people are significantly impacted by the rapid global rise of sedentarism, and suboptimal dietary patterns during key phases of development. Regrettably, the cumulative effects of unhealthy behaviours during the growing years predisposes young people to the early stages of several chronic conditions, including obesity. Clear and consistent approaches are urgently needed to improve eating and activity behaviours of children and adolescents. Based on existing evidence of “best bets” to prevent and control obesity and its comorbidities, we present a set of non-negotiable strategies as a ‘road map’ to achieving prevention and improving the health of children and adolescents.
How to Keep the Balance between Red and Processed Meat Intake and Physical Activity Regarding Mortality: A Dose-Response Meta-Analysis
Authors: Wu Yi , Wang Maoqing , Long Zhiping , Ye Jingyu , Cao Yukun , Pei Bing , Gao Yu , Yu Yue , Han Zhen , Wang Fan , Zhao Yashuang
Published: July 2023

Background: Non-communicable diseases have become a major threat to public health, with cardiovascular diseases (CVDs) and cancer being the top two causes of death each year. Objective: Our objective is to evaluate the balanced association between the effect of red and processed meat intake on the risk of death and the effect of physical activity on the risk of mortality, where the risk of death includes all causes, CVDs, and cancers. Methods: We searched electronic databases, including PubMed, ISI Web of Science, Embase, and the Cochrane Library, for prospective studies reporting risk estimates for the association between the intake of red and processed meat, walking, and muscle-strengthening activity (MSA) and the risk of mortality from all causes, CVDs, and cancer. We extracted fully adjusted effect estimates from original studies and performed a summary analysis using the fixed and random-effect models. Results: A conventional meta-analysis showed that red meat and processed meat were positively associated with the risk of mortality, and daily steps and MSA were negatively associated with the risk of death. Further analysis of the dose–response relationship showed that a risk reduction (20%) from 39.5 min/week of MSA or 4100 steps/d was equivalent to an increased risk of all-cause mortality from a daily intake of 103.4 g/d of red meat or 50 g/d of processed meat. The risk was further decreased as the number of steps per day increased, but the risk reversed when the MSA exceeded the threshold (39.5 min/week). Conclusions: Adherence to physical activity is an effective way to reduce the risk of mortality due to meat intake. However, the total intake of red meat and processed meat should be controlled, especially the latter. Walking is recommended as the main daily physical activity of choice, while MSAs are preferred when time is limited, but it should be noted that longer MSAs do not provide additional benefits.
Intervention Approaches in Studying the Response to Vitamin D3 Supplementation
Authors: Gospodarska Emilia , Ghosh Dastidar Ranjini , Carlberg Carsten
Published: July 2023

Vitamin D intervention studies are designed to evaluate the impact of the micronutrient vitamin D3 on health and disease. The appropriate design of studies is essential for their quality, successful execution, and interpretation. Randomized controlled trials (RCTs) are considered the “gold standard” for intervention studies. However, the most recent large-scale (up to 25,000 participants), long-term RCTs involving vitamin D3 did not provide any statistically significant primary results. This may be because they are designed similarly to RCTs of a therapeutic drug but not of a nutritional compound and that only a limited set of parameters per individual were determined. We propose an alternative concept using the segregation of study participants into different groups of responsiveness to vitamin D3 supplementation and in parallel measuring a larger set of genome-wide parameters over multiple time points. This is in accordance with recently developed mechanistic modeling approaches that do not require a large number of study participants, as in the case of statistical modeling of the results of a RCT. Our experience is based on the vitamin D intervention trials VitDmet, VitDbol, and VitDHiD, which allowed us to distinguish the study participants into high, mid, and low vitamin D responders. In particular, investigating the vulnerable group of low vitamin D responders will provide future studies with more conclusive results both on the clinical and molecular benefits of vitamin D3 supplementation. In conclusion, our approach suggests a paradigm shift towards detailed investigations of transcriptome and epigenome-wide parameters of a limited set of individuals, who, due to a longitudinal design, can act as their own controls.
The True Price of External Health Effects from Food Consumption
Authors: Seidel Felix , Oebel Benjamin , Stein Lennart , Michalke Amelie , Gaugler Tobias
Published: July 2023

Although global food consumption costs more in terms of impact on human life than money is spent on it, health costs have not been consistently quantified or included in food prices to date. In this paper, a method to determine the external health costs of nutrition and dietetics is developed by employing the cost-of-illness (COI) and true cost accounting (TCA) approaches. This is done exemplarily for the reference country Germany. The results show that 601.50 € per capita and 50.38 billion € in total external health costs are incurred annually due to nutrition. Overall, most costs are accrued through excessive meat consumption (32.56% of costs), deficient whole grain intake (15.42% of costs), and insufficient uptake of legumes (10.19% of costs). Comparing the external health costs with the external environmental costs in Germany, it can be seen that of the total annual costs of around 153.86 billion €, 67.26% originate from environmental impacts and 32.74% from impacts on human life. In order to achieve the 17 Sustainable Development Goals and to increase family as well as public health, there is a need to internalise these external costs into actual food prices.
Psoriasis and Vitamin D: A Systematic Review and Meta-Analysis
Authors: Formisano Elena , Proietti Elisa , Borgarelli Consuelo , Pisciotta Livia
Published: July 2023

Psoriasis is a chronic immune-dysregulated inflammatory disease and hypovitaminosis D is considered a risk factor. We conducted an online database search to review and meta-analyze the relationship between vitamin D, other bone metabolism parameters, and psoriasis. The efficacy of oral vitamin D supplementation in improving Psoriasis Area and Severity Index (PASI) was also evaluated. Non-original articles, case reports, and animal studies were excluded. Bias risk was assessed according to the Cochrane Collaboration’s tool and the Newcastle–Ottawa scale in randomized controlled trials (RCTs) and case–control studies, respectively. Unstandardized mean differences were used for data synthesis. Twenty-three studies reported serum 25 hydroxyvitamin D (25(OH)D) levels in 1876 psoriasis patients and 7532 controls. Psoriasis patients had significantly lower 25(OH)D levels than controls (21.0 ± 8.3 vs. 27.3 ± 9.8, p < 0.00001). Conversely, 450 psoriasis patients had lower levels of parathormone than 417 controls (38.7 ± 12.8 vs. 43.7 ± 16.5, p = 0.015). Four RCTs examined the effect of oral vitamin D supplementation on psoriasis for 173 patients and 160 patients were treated with placebo. No significant differences were found in PASI after 3, 6, and 12 months of supplementation. It is shown that 25(OH)D serum levels are significantly lower in psoriasis, but, although the granularity of RCT methodology may have influenced the pooled analysis, vitamin D supplementation did not seem to improve clinical manifestations.