bluuebunny/crossref_metadata_2025 huggingface dataset:
Insulating or Metallic: Coexistence of Different Electronic Phases in Zinc Clusters
Authors: Aguado Andrés , Vega Andrés , Lebon Alexandre , von Issendorff Bernd
Published: December 2014

How many of the several attributes of the bulk metallic state persist in a nanoparticle containing a finite number of atoms of a metallic element? Do all those attributes emerge suddenly at a well‐defined cluster size or do they rather evolve at different rates and in a broad size range? These fundamental questions have been addressed through a conjoint experimental/theoretical investigation of zinc clusters. We report the observation of novel coexistence phenomena involving different electronic phases: for some sizes, metallic and insulating electronic states coexist within a single, Janus‐like, nanoparticle; for the rest of sizes, we report the coexistence of two weakly interacting metallic phases with different dimensionalities, localized at the shell and the core of the nanoparticle. These fascinating features are due to an anomalously long core–shell separation that equips the shell and core regions with largely independent structural, vibrational, and thermal properties.
Experimental and Computational Study of the Catalytic Asymmetric 4π‐Electrocyclization of N‐Heterocycles
Authors: Raja Sadiya , Nakajima Masaki , Rueping Magnus
Published: December 2014

The first asymmetric metal‐catalyzed Nazarov cyclization of N‐heterocycles has been developed. The use of a chiral catalyst allows the enantioselective electrocyclization of N‐heterocycles under mild conditions and the corresponding products are obtained in good yields with excellent enantio‐ and diastereoselectivity. The reaction mechanism and the absolute configuration of the obtained products are explained by means of computational studies.
Regiodivergent Addition of Phenols to Allylic Oxides: Control of 1,2‐ and 1,4‐Additions for Cyclitol Synthesis
Authors: Moschitto Matthew J. , Vaccarello David N. , Lewis Chad A.
Published: December 2014

Control of 1,2‐ and 1,4‐addition of substituted phenols to allylic oxides is achieved by intercepting palladium π‐allyl complexes. The interconversion of palladium complexes results in the total synthesis of MK 7607, cyathiformine B type, streptol, and a new cyclitol.
In vitro antimicrobial and antioxidant evaluation of rare earth metal Schiff base complexes derived from threonine
Authors: Logu Lekha , Raja Kamatchi Kanmani , Rajmohan Hariharan , Manohar Sathish , Gurusamy Rajagopal , Deivanayagam Easwaramoorthi
Published: December 2014

Six novel Ln(III) Schiff base complexes were synthesized using rare earth metals with threonine and 5‐bromosalicylaldehyde, namely Pr(III), Sm(III), Gd(III), Tb(III), Er(III) and Yb(III) Schiff bases. These complexes were characterized using elemental analysis, molar conductivity, Fourier transform infrared and UV–visible spectroscopies, and thermogravimetry–differential thermal analysis. The general formula of the complexes is [Ln(L)(NO3)2(H2O)].NO3 (L = Schiff base ligand). The spectroscopic data reveal that the Schiff base ligand behaves as a tridentate ligand with ONO donor atoms sequencing towards the central metal ion. An investigation of fluorescence properties of the Sm(III), Er(III) and Tb(III) complexes shows that the Ln(III) ions can be sensitized efficiently by the ligand to some extent. Antimicrobial activity testing indicates that all six complexes exhibit antibacterial and antifungal ability against microbes with broad antimicrobial spectra. In addition, the antioxidant properties of the complexes were also screened. Copyright © 2014 John Wiley & Sons, Ltd.
Biomechanical Implications of Intraspecific Shape Variation in Chimpanzee Crania: Moving Toward an Integration of Geometric Morphometrics and Finite Element Analysis
Authors: Smith Amanda L. , Benazzi Stefano , Ledogar Justin A. , Tamvada Kelli , Pryor Smith Leslie C. , Weber Gerhard W. , Spencer Mark A. , Dechow Paul C. , Grosse Ian R. , Ross Callum F. , Richmond Brian G. , Wright Barth W. , Wang Qian , Byron Craig , Slice Dennis E. , Strait David S.
Published: December 2014

In a broad range of evolutionary studies, an understanding of intraspecific variation is needed in order to contextualize and interpret the meaning of variation between species. However, mechanical analyses of primate crania using experimental or modeling methods typically encounter logistical constraints that force them to rely on data gathered from only one or a few individuals. This results in a lack of knowledge concerning the mechanical significance of intraspecific shape variation that limits our ability to infer the significance of interspecific differences. This study uses geometric morphometric methods (GM) and finite element analysis (FEA) to examine the biomechanical implications of shape variation in chimpanzee crania, thereby providing a comparative context in which to interpret shape‐related mechanical variation between hominin species. Six finite element models (FEMs) of chimpanzee crania were constructed from CT scans following shape‐space Principal Component Analysis (PCA) of a matrix of 709 Procrustes coordinates (digitized onto 21 specimens) to identify the individuals at the extremes of the first three principal components. The FEMs were assigned the material properties of bone and were loaded and constrained to simulate maximal bites on the P3 and M2. Resulting strains indicate that intraspecific cranial variation in morphology is associated with quantitatively high levels of variation in strain magnitudes, but qualitatively little variation in the distribution of strain concentrations. Thus, interspecific comparisons should include considerations of the spatial patterning of strains rather than focus only on their magnitudes. Anat Rec, 298:122–144, 2015. © 2014 Wiley Periodicals, Inc.
Three‐Dimensional Geometric Morphometric Analysis of the Nasopharyngeal Boundaries and Its Functional Integration with the Face and External Basicranium Among Extant Hominoids
Authors: Pagano Anthony S. , Laitman Jeffrey T.
Published: December 2014

The nasopharynx is a centrally located but understudied upper respiratory tract component. This study tested hypotheses related to the functional integration of the nasopharyngeal boundaries with the facial skeleton and external basicranium over the course of development in humans and nonhuman hominoids. It was hypothesized that facial morphology (width, length, and kyphosis) is related to nasopharyngeal width and choanal morphology, whereas relative external basicranial proportions are related to nasopharyngeal depth. Human infants were used as models of extreme orthognathy and external basicranial retroflexion, whereas nonhuman hominoids were used to model greater relative prognathism and external basicranial retroflexion. Both of these groups were contrasted against adult humans, who exhibit both extreme orthognathy and external basicranial flexion. Three‐dimensional landmark coordinate data were collected from age‐graded series of Homo, Pan, Gorilla, Pongo, and Hylobates. Generalized Procrustes Analysis was performed, and multivariate shape differences were evaluated via principal components analysis. Additionally, linear measures were extracted from the Procrustes‐corrected sets of landmark data. Results indicate that human adults are indeed distinct from all groups in possessing a relatively shallow nasopharyngeal roof and shorter, more flexed external basicranial axis. Human adults and infants both exhibit greater relative choanal and nasopharyngeal width. Nonhuman hominoid faces tended to become airorhynch into adulthood, whereas humans exhibited the opposite trend. When pooling all the hominoids, facial width and palate length were strongly correlated with choanal and nasopharyngeal width, whereas facial kyphosis was strongly correlated with choanal orientation. The hypotheses were supported as the results indicated a morphologic relationship among nasopharyngeal boundaries, the facial skeleton, and the external basicranium. Anat Rec, 298:85–106, 2015. © 2014 Wiley Periodicals, Inc.
Brief Report: Methotrexate Prevents Wear Particle–Induced Inflammatory Osteolysis in Mice Via Activation of Adenosine A2A Receptor
Authors: Mediero Aránzazu , Perez‐Aso Miguel , Wilder Tuere , Cronstein Bruce N.
Published: December 2014

Objective

Adenosine, acting at the A2A receptor, mediates the antiinflammatory effects of methotrexate (MTX) in models of inflammation. We previously reported that A2A receptor ligation diminishes wear particle–driven osteolysis. The aim of this study was to investigate whether MTX treatment could prevent bone resorption caused by inflammatory osteolysis.

Methods

C57BL/6 mice (6–8 weeks old) received intraperitoneal injections of 1 mg/kg MTX (n = 20) or 0.9% saline (n = 10), starting 2 weeks prior to surgical implantation of 3 mg of wear particles (ultrahigh molecular weight polyethylene [UHMWPE] particles). The MTX‐treated mice received daily injections of vehicle or ZM241385 at the surgical site until they were killed, 14 days later. XenoLight RediJect Bone Probe 680 was injected intravenously, and fluorescence analysis of the calvaria using an IVIS imaging system was performed to assess bone formation. Micro–computed tomography (micro‐CT) and immunostaining for osteoclast and osteoblast markers were performed.

Results

Implantation of wear particles induced bone pitting and thinning, as shown by micro‐CT. MTX treatment markedly reduced osteolysis, and this effect was abrogated by treatment with the A2A receptor antagonist ZM241385. Implantation of UHMWPE reduced new bone formation, and MTX treatment restored new bone formation, an effect that was completely reversed by treatment with ZM241385. Histologic examination of particle‐exposed calvariae demonstrated that MTX prevented accumulation of an inflammatory infiltrate at the site of particle implantation, increased the number of osteoblasts, and reduced the number of osteoclasts at the site of inflammation, an effect that was reversed by treatment with ZM241385.

Conclusion

MTX reduces inflammatory osteolysis indirectly via stimulation of A2A receptor and may represent a novel approach to enhance orthopedic implant survival, delaying or eliminating the need for revision arthroplasty surgery.
Sex determination from calcification of costal cartilages in a Scottish sample
Authors: Middleham Helen P. , Boyd Laura E. , Mcdonald Stuart W.
Published: December 2014

The pelvic bones and skull are not always available when human remains are discovered in a forensic setting. This study investigates the suitability to a Scottish sample of existing methods of sexing based on calcification patterns in the costal cartilages. Radiographs of chest plates of 41 cadavers, 22 male and 19 female aged 57–96 years were analyzed for their calcification patterns according to the methods of McCormick et al. (1985, Am. J. Phys. Anthropol. 68:173–195) and Rejtarova et al. (2004, Biomed. Pap. Med. Fac. Univ. Palacky. Olomouc. Czech. Repub. 148:241–243). With the method of Rejtarova et al. (2004, Biomed. Pap. Med. Fac. Univ. Palacky. Olomouc. Czech. Repub. 148:241–243) none of the male specimens was sexed correctly. Of the chest plates that were suitable for sexing, the method of McCormick et al. (1985, Am. J. Phys. Anthropol. 68:173–195) correctly sexed 82.4% of the female specimens but only 41.2% of the males. To improve the reliability, we suggest a new method of sex determination based on whether the calcified deposits in the second to seventh costal cartilages are predominantly trabecular bone or sclerotic calcified deposits. Specimens with minimal amounts or similar amounts of trabecular bone or sclerotic deposits in the costal cartilages are not appropriate for our method. When such specimens (10 specimens) were excluded, our method correctly sexed 16 of 17 (94%) males and 12 of 14 (86%) females. The authors acknowledge that their sample is small and that many of their subjects were elderly and that the method should be tested on a larger sample group before application in a forensic context. Clin. Anat. 28:888–895, 2015. © 2014 Wiley Periodicals, Inc.
The interrelation between aPKC and glucose uptake in the skeletal muscle during contraction and insulin stimulation
Authors: Santos J. M. , Benite‐Ribeiro S. A. , Queiroz G. , Duarte J. A.
Published: December 2014

Contraction and insulin increase glucose uptake in skeletal muscle. While the insulin pathway, better characterized, requires activation of phosphoinositide 3‐kinase (PI3K) and atypical protein kinase (aPKC), muscle contraction seems to share insulin‐activated components to increase glucose uptake. This study aimed to investigate the interrelation between the pathway involved in glucose uptake evoked by insulin and muscle contraction. Isolated muscle of rats was treated with solvent (control), insulin, wortmannin (PI3K inhibitor) and the combination of insulin plus wortmannin. After treatment, muscles were electrically stimulated (contracted) or remained at rest. Glucose transporter 4 (GLUT4) localization, glucose uptake and phospho‐aPKC (aPKC activated form) were assessed. Muscle contraction and insulin increased glucose uptake in all conditions when compared with controls not stimulating an effect that was accompanied by an increase in GLUT4 and of phospho‐aPKC at the muscle membrane. Contracted muscles treated with insulin did not show additive effects on glucose uptake or aPKC activity compared with the response when these stimuli were applied alone. Inhibition of PI3K blocked insulin effect on glucose uptake and aPKC but not in the contractile response. Thus, muscle contraction seems to stimulate aPKC and glucose uptake independently of PI3K. Therefore, aPKC may be a convergence point and a rate limit step in the pathway by which, insulin and contraction, increase glucose uptake in skeletal muscle. Copyright © 2014 John Wiley & Sons, Ltd.
Simultaneous Genotyping of Multiple Somatic Mutations by Using a Clamping PNA and PNA Detection Probes
Authors: Kim Yong‐Tae , Kim Jin Woo , Kim Sung Kee , Joe Goon Ho , Hong In Seok
Published: December 2014

It has been very difficult to detect and quantify multiple somatic mutations simultaneously in single‐tube qPCR. Here, a novel method for simultaneous detection of multiple mutations and a melting curve analysis was developed by using clamping PNA and detection PNA probes. Each PNA probe was designed to have a specific melting temperature by the introduction of γ‐PNA monomer. This technique was successfully applied to the detection of six genotypes in two different mutations of K‐RAS at the same time. Such simultaneous analysis of an amplified curve and a melting curve in qPCR can be widely used for the early diagnosis of cancer and determining the prognosis of drug treatments.
Percutaneous bi‐atrial extracorporeal membrane oxygenation for acute circulatory support in advanced heart failure
Authors: Jumean Marwan , Pham Duc Thinh , Kapur Navin K.
Published: December 2014

Veno‐arterial extracorporeal membrane oxygenation (VA‐ECMO) may improve survival after cardiac arrest by providing cardiopulmonary support. However, VA‐ECMO increases left ventricular (LV) afterload, which can promote progressive LV distension and often requires a secondary approach to reduce LV pressure and volume in patients with left heart failure. We report a case of biventricular unloading via biatrial cannulation in the presence of LV thrombus using a TandemHeart percutaneous trans‐septal cannula for VA‐ECMO in an adult patient with refractory ventricular fibrillation. © 2014 Wiley Periodicals, Inc.
A “Simplified” culotte technique using two dedicated bifurcation stents and additional angiographic stent enhancement to treat a complex bifurcation lesion in non‐ST segment elevation myocardial infarction with poor left ventricular function
Authors: Chan Yu Ho , Stella Pieter R. , Agostoni Pierfrancesco
Published: December 2014

We present a case of a bifurcation lesion treated with two dedicated sirolimus eluting bifurcation stents, BiOSS Lim in the setting of non‐ST elevation myocardial infarction and poor left ventricular function. We demonstrate the feasibility of a new technique, a “simplified” culotte technique. The key differences of this new technique compared with conventional culotte are: better sizing of the stent due to the specific design of the stent with a larger proximal diameter and smaller distal diameter, direct stenting of the second stent without predilatation of the stent struts of the first deployed stent, and possibility to perform post‐dilatation directly with properly sized balloons without additional predilatation. © 2015 Wiley Periodicals, Inc.
Influence of Design Parameters on Hydrodynamics and Heat Transfer of a Modularized Millireactor
Authors: Biessey Philip , Grünewald Marcus
Published: December 2014

An apparatus with rectangular product channels and static mixing elements for process intensification is investigated in terms of heat transfer and hydrodynamics. Herringbone‐like static mixing elements increase the overall heat transfer coefficient significantly, and the stall angle was found to have a major influence on hydrodynamics and heat transfer. The knowledge of structural parameters of the mixing elements is crucial for apparatus design and prediction of the apparatus performance. A method to derive mean structural parameters from experimental results is presented.
A Series of π‐Extended Thiadiazoles Fused with Electron‐Donating Heteroaromatic Moieties: Synthesis, Properties, and Polymorphic Crystals
Authors: Kato Shin‐ichiro , Furuya Takayuki , Nitani Masashi , Hasebe Naoya , Ie Yutaka , Aso Yoshio , Yoshihara Toshitada , Tobita Seiji , Nakamura Yosuke
Published: December 2014

π‐Extended thiadiazoles 4–8 fused with various electron‐donating heteroaromatic moieties have been designed and synthesized. Just like thiadiazoles 1–3 synthesized previously, 4–8 exhibit intramolecular charge‐transfer (CT) interactions, moderate‐to‐good fluorescence quantum yields of up to 0.78, and electrochemical amphoterism. In comparison with 1–3, the benzannulation in thiadiazoles 4–7 moderately extends the π conjugation and significantly increases the stability of the cationic species formed upon electrochemical oxidation. The fluorescence quantum yields increase remarkably from 3 to 6 and 7 due to the efficient suppression of nonradiative intersystem crossing resulting from the benzannulation. The properties of 4–8 strongly reflect the different species annulated to the pyrrole rings, namely benzothiophene, naphthalene, and benzofuran. Eleven crystals, including poly‐ and pseudopolymorphic crystals of 1 (1‐Crys.(Y) and 1‐Crys.(G)), 2 (2‐Crys.(O) and 2‐Crys.(G)), 4 (4‐Crys.(O) and 4‐Crys.(G)), and 6 (6‐Crys.(O) and 6‐Crys.(G)), were obtained and characterized by X‐ray crystallography. The fluorescence colors and efficiencies are distinct for each poly‐ and pseudopolymorph of 1, 2, 4, and 6. It has been suggested that both the extent of the electronic interactions in the π‐stacked dimers and the presence of excitonic interactions originating in the 1D face‐to‐face slipped columns affect the fluorescence wavelengths of the poly‐ and pseudopolymorphs.
Mechanism of [3+2] Cycloaddition of Alkynes to the [Mo3S4(acac)3(py)3][PF6] Cluster
Authors: Pino‐Chamorro Jose Ángel , Gushchin Artem L. , Fernández‐Trujillo M. Jesús , Hernández‐Molina Rita , Vicent Cristian , Algarra Andrés G. , Basallote Manuel G.
Published: December 2014

A study, involving kinetic measurements on the stopped‐flow and conventional UV/Vis timescales, ESI‐MS, NMR spectroscopy and DFT calculations, has been carried out to understand the mechanism of the reaction of [Mo3S4(acac)3(py)3][PF6] ([1]PF6; acac=acetylacetonate, py=pyridine) with two RCCR alkynes (R=CH2OH (btd), COOH (adc)) in CH3CN. Both reactions show polyphasic kinetics, but experimental and computational data indicate that alkyne activation occurs in a single kinetic step through a concerted mechanism similar to that of organic [3+2] cycloaddition reactions, in this case through the interaction with one Mo(μ‐S)2 moiety of [1]+. The rate of this step is three orders of magnitude faster for adc than that for btd, and the products initially formed evolve in subsequent steps into compounds that result from substitution of py ligands or from reorganization to give species with different structures. Activation strain analysis of the [3+2] cycloaddition step reveals that the deformation of the two reactants has a small contribution to the difference in the computed activation barriers, which is mainly associated with the change in the extent of their interaction at the transition‐state structures. Subsequent frontier molecular orbital analysis shows that the carboxylic acid substituents on adc stabilize its HOMO and LUMO orbitals with respect to those on btd due to better electron‐withdrawing properties. As a result, the frontier molecular orbitals of the cluster and alkyne become closer in energy; this allows a stronger interaction.
Functionalization of Hydride‐Terminated Photoluminescent Silicon Nanocrystals with Organolithium Reagents
Authors: Höhlein Ignaz M. D. , Angı Arzu , Sinelnikov Regina , Veinot Jonathan G. C. , Rieger Bernhard
Published: December 2014

Hydride‐terminated photoluminescent silicon nanocrystals (SiNCs) were functionalized with organolithium compounds. The reaction is proposed to proceed through cleavage of SiSi bonds and formation of a SiLi surface species. The method yields colloidally stabilized SiNCs at room temperature with short reaction times. SiNCs with mixed surface functionalities can be prepared in an easy two‐step reaction by this method by quenching of the SiLi group with electrophiles or by addressing free SiH groups on the surface with a hydrosilylation reaction.
Quantum Size Effects in the Size–Temperature Phase Diagram of Gallium: Structural Characterization of Shape‐Shifting Clusters
Authors: Steenbergen Krista G. , Gaston Nicola
Published: December 2014

Finite temperature analysis of cluster structures is used to identify signatures of the low‐temperature polymorphs of gallium, based on the results of first‐principle Born–Oppenheimer molecular dynamics simulations. Pre‐melting structural transitions proceed from either the β‐ and/or the δ‐phase to the γ‐ or δ‐phase, with a size‐ dependent phase progression. We relate the stability of each isomer to the electronic structures of the different phases, giving new insight into the origin of polymorphism in this complicated element.
Single Crystal‐to‐Single Crystal Site‐Selective Postsynthetic Metal Exchange in a Zn–MOF Based on Semi‐Rigid Tricarboxylic Acid and Access to Bimetallic MOFs
Authors: Bajpai Alankriti , Chandrasekhar Pujari , Govardhan Savitha , Banerjee Rahul , Moorthy Jarugu Narasimha
Published: December 2014

The metal ions in a neutral Zn–MOF constructed from tritopic triacid H3L with inherent concave features, rigid core, and peripheral flexibility are found to exist in two distinct SBUs, that is, 0D and 1D. This has allowed site‐selective postsynthetic metal exchange (PSME) to be investigated and reactivities of the metal ions in two different environments in coordination polymers to be contrasted for the first time. Site‐selective transmetalation of Zn ions in the discrete environment is shown to occur in a single crystal‐to‐single crystal (SCSC) fashion, with metal ions such as Fe3+, Ru3+, Cu2+, Co2+, etc., whereas those that are part of 1D SBU sustain structural integrity, leading to novel bimetallic MOFs, which are inaccessible by conventional approaches. To the best of our knowledge, site‐selective postsynthetic exchange of an intraframework metal ion in a MOF that contains metal ions in discrete as well as polymeric SBUs is heretofore unprecedented.
A Facile Route to Backbone‐Tethered N‐Heterocyclic Carbene (NHC) Ligands via NHC to aNHC Rearrangement in NHC Silicon Halide Adducts
Authors: Schneider Heidi , Schmidt David , Radius Udo
Published: December 2014

The reaction of 1,3‐diisopropylimidazolin‐2‐ylidene (iPr2Im) with diphenyldichlorosilane (Ph2SiCl2) leads to the adduct (iPr2Im)SiCl2Ph2 1. Prolonged heating of isolated 1 at 66 °C in THF affords the backbone‐tethered bis(imidazolium) salt [(aHiPr2Im)2SiPh2]2+ 2 Cl− 2 (“a” denotes “abnormal” coordination of the NHC), which can be synthesized in high yields in one step starting from two equivalents of iPr2Im and Ph2SiCl2. Imidazolium salt 2 can be deprotonated in THF at room temperature using sodium hydride as a base and catalytic amounts of sodium tert‐butoxide to give the stable N‐heterocyclic dicarbene (aiPr2Im)2SiPh2 3, in which two NHCs are backbone‐tethered with a SiPh2 group. This easy‐to‐synthesize dicarbene 3 can be used as a novel ligand type in transition metal chemistry for the preparation of dinuclear NHC complexes, as exemplified by the synthesis of the homodinuclear copper(I) complex [{a(ClCuiPr2Im)}2SiPh2] 4.
ChemInform Abstract: An Azide‐Bridged Copper(II) Complex: Poly[piperazine‐1,4‐dium [Tetra‐μ3‐azido‐ϰ12N1:N 1:N1‐hexa‐μ2‐azido‐ϰ 12N1:N1‐di‐μ2 ‐azido‐ϰ4N1:N3‐pentacopper(II)] Tetrahydrate].
Authors: Liu Hou‐Ting , Lu Jing
Published: December 2014

Crystals of the title compound {(H2pip) [Cu5(N3)12] ·4H2O}n (pip: piperazine) are synthesized by slow diffusion between an aq.
ChemInform Abstract: Hexabromo‐ and Hexaiododisilane: Small and Simple Molecules Showing Completely Different Crystal Structures.
Authors: Berger Matthias , Auner Norbert , Bolte Michael
Published: December 2014

Si2Br6 (I) and Si2I6 (II) are prepared in 69% resp.
ChemInform Abstract: Bi2Pt(hP9) by Low‐Temperature Reduction of Bi13Pt3I7: Reinvestigation of the Crystal Structure and Chemical Bonding Analysis.
Authors: Kaiser Martin , Baranov Alexey I. , Ruck Michael
Published: December 2014

Bi2Pt(hP9) or γ‐Bi2Pt is a high‐temperature modification which is metastable below 420 °C.
ChemInform Abstract: Synthesis, Crystal and Electronic Structure of the Sulfido Ferrate Oxide, Cs11[Fe5S8]2[O].
Authors: Schwarz Michael , Roehr Caroline
Published: December 2014

Cs11[Fe5S8]2[O] is prepared by heating a mixture of Fe, Cs2S2, and CsO2 or Fe2O3 as O source (corundum crucible, 1170 K, 12 h; cooling rate of 20 K/h).
ChemInform Abstract: Dihydrogen Tetrametaphosphate, [P4O12H2]2—: Synthesis, Solubilization in Organic Media, Preparation of Its Anhydride [P4O11]2— and Acidic Methyl Ester, and Conversion to Tetrametaphosphate Metal Complexes via Protonolysis.
Authors: Jiang Yanfeng , Chakarawet Khetpakorn , Kohout Andrea Laura , Nava Matthew , Marino Nadia , Cummins Christopher C.
Published: December 2014

The strong Broensted acid [P4O12H2]2‐ serves as precursor to numerous derivatives.
ChemInform Abstract: First Polymeric Polyphosphide via Solution Chemistry — Synthesis and Crystal Structure of CsP7.
Authors: Meier Martin , Faupel Victoria , Korber Nikolaus
Published: December 2014

CsP7 is prepared via a solution reaction of Cs3P11 and Te (molar ratio of 2:1) in liquid NH3 (195 K, storage for several weeks at 235 K).
ChemInform Abstract: An Acentric Calcium Borate Ca2[B5O9]·(OH)·H2O: Synthesis, Structure, and Nonliner Optical Property.
Authors: Wei Qi , Cheng Jian‐Wen , He Chao , Yang Guo‐Yu
Published: December 2014

The title compound is solvothermally synthesized from mixtures of Ca(OH)2, H3BO3, and Li2CO3 using pyridine and water as mixed solvent (autoclave, 230 °C, 6 d, 80% yield).
ChemInform Abstract: Aqueous Hafnium Sulfate Chemistry: Structures of Crystalline Precipitates.
Authors: Kalaji Ali , Soderholm L.
Published: December 2014

Crystalline precipitates resulting from the hydrolysis and subsequent condensation of HfIV aqueous acidic solutions are characterized by single crystal XRD and Raman spectroscopy.
ChemInform Abstract: All‐Inorganic Networks and Tetramer Based on Tin(II)‐Containing Polyoxometalates: Tuning Structural and Spectral Properties with Lone‐Pairs.
Authors: Zhao Chongchao , Glass Elliot N. , Chica Bryant , Musaev Djamaladdin G. , Sumliner Jordan M. , Dyer R. Brian , Lian Tianquan , Hill Craig L.
Published: December 2014

Structural and spectral features of Sn(II)‐containing polyoxometalate networks (IVa, b) and the molecular compound (VI) are investigated by XRD, Raman and UV/VIS spectroscopy, electrochemical measurements, and DFT calculations.
ChemInform Abstract: Chlorosulfonamide Salts Are Superior Electrophilic Chlorine Precursors for the Organocatalytic Asymmetric Chlorocyclization of Unsaturated Amides.
Authors: Jaganathan Arvind , Borhan Babak
Published: December 2014

Chloramine‐T is used as an inexpensive precursor of electrophilic chloride to produce asymmetric chlorocyclization of N‐allylic substituted aroylamides.
ChemInform Abstract: Catalytic, Formal Homo‐Nazarov‐Type Cyclizations of Alkylidene Cyclopropane‐1,1‐ketoesters: Access to Functionalized Arenes and Heteroaromatics.
Authors: Aponte‐Guzman Joel , Taylor J. Evans , Tillman Elayna , France Stefan
Published: December 2014

The outcome of the title reaction depends on the alkylidene substituents of the substrates.
ChemInform Abstract: Broad‐Spectrum Catalysts for the Ambient Temperature anti‐Markovnikov Hydration of Alkynes.
Authors: Li Le , Zeng Mingshuo , Herzon Seth B.
Published: December 2014

With the optimal catalyst system RUC/FMBP, many alkyne substrates can be hydrated to form terminal aldehydes.
ChemInform Abstract: The Reaction of Cyanamidium Salts with Ylidenecyanamide Derivatives.
Authors: Abu‐El‐Halawa Rajab , Zabin Sami A. , Al‐Refai Mahmoud , Ibrahim Mohammad , Kaimari Tawfeq , Mueller Thomas J. J.
Published: December 2014

Conjugated iminium salts (III) and (V) are obtained by ene reaction of cyanamidium salt (I) with ylidenecyanamide derivatives (II) and (IV), respectively.
ChemInform Abstract: Enantioselective Nucleophile‐Catalyzed Synthesis of Tertiary Alkyl Fluorides via the α‐Fluorination of Ketenes: Synthetic and Mechanistic Studies.
Authors: Lee Sarah Yunmi , Neufeind Stefan , Fu Gregory C.
Published: December 2014

The reaction can be scaled up.
ChemInform Abstract: CuI‐Catalyzed Cross‐Coupling of Terminal Alkynes with Dialkoxycarbenes: A General Method for the Synthesis of Unsymmetrical Propargylic Acetals.
Authors: Xiao Tiebo , Zhang Ping , Xie Yang , Wang Jun , Zhou Lei
Published: December 2014

Oxadiazolines (I) can be generally employed as a source of dialkoxycarbenes generated by thermal decomposition.
ChemInform Abstract: Synthesis of N‐(α‐Fluorovinyl)azoles by the Reaction of Difluoroalkenes with Azoles.
Authors: Xiong Yang , Zhang Xuxue , Huang Tao , Cao Song
Published: December 2014

A slight excess (1.2 equiv.) of difluoroalkene reacts with various N‐heterocycles to afford monosubstituted (E)‐configurated products.
ChemInform Abstract: Cinchona—Diaminomethylenemalononitrile Organocatalyst for Asymmetric Conjugate Addition of 1,3‐Diketone to Nitroalkene.
Authors: Miura Tsuyoshi , et al. et al.
Published: December 2014

The conjugate addition of acetylacetone to various nitroalkenes in the presence of a diaminomethylenemalononitrile substituted cinchona catalyst gives the corresponding addition products in good to excellent yields with up to 89% ee.
ChemInform Abstract: Iron‐Catalyzed Intermolecular Hydroamination of Styrenes.
Authors: Huehls C. Bryan , Lin Aijun , Yang Jiong
Published: December 2014

A simple iron‐catalyzed hydroamination reaction of styrenes with O‐benzoyl‐N‐hydroxylamines is described using cyclopentylmagnesium bromide as the reducing agent.
ChemInform Abstract: General Catalytic Methylation of Amines with Formic Acid under Mild Reaction Conditions.
Authors: Sorribes Ivan , Junge Kathrin , Beller Matthias
Published: December 2014

The new presented method for the methylation of amines employes, for the first time, formic acid as the C1 building block and silanes as reducing agents.
ChemInform Abstract: Synthesis of Structurally Diverse Diarylketones Through the Diarylmethyl sp3 C—H Oxidation.
Authors: He Chao , Zhang Xiaohui , Huang Ruofeng , Pan Jing , Li Jiaqiang , Ling Xuege , Xiong Yan , Zhu Xiangming
Published: December 2014

Diaryl methane derivatives are oxidized by N‐bromsuccinimide.
ChemInform Abstract: Dehydrogenative α‐Oxygenation of Ethers with an Iron Catalyst.
Authors: Gonzalez‐de‐Castro Angela , Robertson Craig M. , Xiao Jianliang
Published: December 2014

A green and efficient catalytic method for the chemoselective title reaction is presented.
ChemInform Abstract: Catalytic Conversion of Aryl Triazenes into Aryl Sulfonamides Using Sulfur Dioxide as the Sulfonyl Source.
Authors: Li Wanfang , Beller Matthias , Wu Xiao‐Feng
Published: December 2014

The first transformation of triazenes into sulfonamides catalyzed by boron trifluoride etherate or copper chloride is described.
ChemInform Abstract: Synthesis of Novel β‐Aryl‐β‐(methylthio)acroleins via Vilsmeier—Haack Protocol as Potential 1,3‐Dielectrophilic Three‐Carbon Building Blocks.
Authors: Byre Gowda G. , Charanraj T. P. , Pradeepa Kumara C. S. , Ramesh N. , Thomas S. P. , Sadashiva M. P. , Junjappa H.
Published: December 2014

The novel acroleine derivatives are obtained via active methylene compounds or by using β‐chloroacroleins as starting materials.
ChemInform Abstract: Decarboxylative Thioamidation of Arylacetic and Cinnamic Acids: A New Approach to Thioamides.
Authors: Guntreddi Tirumaleswararao , Vanjari Rajeshwer , Singh Krishna Nand
Published: December 2014

A practical synthesis of thioamides is achieved from arylacetic acids and a variety of primary and secondary amines using a decarboxylative approach with elemental sulfur as the reagent.
ChemInform Abstract: A Phosphine‐Mediated Stereocontrolled Synthesis of Z‐Enediynes by a Vicinal Dialkynylation of Ethynylphosphonium Salts.
Authors: Reichl Kyle D. , Radosevich Alexander T.
Published: December 2014

A convenient method is elaborated for the two‐step preparation of Z‐enediynes (VI) via a dialkynylation of isolated ethynylphosphonium bromides (III).
ChemInform Abstract: Highly Enantioselective Synthesis of Chiral Cyclic Allylic Amines via Rh‐Catalyzed Asymmetric Hydrogenation.
Authors: Zhou Ming , Liu Tang‐Lin , Cao Min , Xue Zejian , Lv Hui , Zhang Xumu
Published: December 2014

Mild conditions, broad substrate scope, and the commercially available Rh‐DuanPhos catalyst are features of this hydrogenation.
ChemInform Abstract: Enantioselective Synthesis of Decalin Structures with All‐Carbon Quaternary Centers via One‐Pot Sequential Cope/Rauhut—Currier Reaction.
Authors: Ross Tina Morgan , Burke Sarah J. , Malachowski William P.
Published: December 2014

The enantioselective synthesis of highly functionalized decalin structures is achieved through one‐pot sequential Cope/Rauhut—Currier reaction of substrates (I).
ChemInform Abstract: Synthesis of Angularly Substituted trans‐Fused Hydroindanes by Convergent Coupling of Acyclic Precursors.
Authors: Jeso Valer , Aquino Claudio , Cheng Xiayun , Mizoguchi Haruki , Nakashige Mika , Micalizio Glenn C.
Published: December 2014

Hydroindanes are formed from TMS‐alkynes and 4‐hydroxy‐1,6‐enynes in the presence of Ti(OiPr)4.
ChemInform Abstract: N‐Heterocyclic Carbene/Lewis Acid Strategy for the Stereoselective Synthesis of Spirocyclic Oxindole—Dihydropyranones.
Authors: Xiao Zhaoxin , Yu Chenxia , Li Tuanjie , Wang Xiang‐Shan , Yao Changsheng
Published: December 2014

A NHC/Lewis acid catalyzed [4 + 2] annulation of α‐bromo‐α,β‐unsaturated aldehydes bearing γ‐H with isatin is developed to yield spirocyclic oxindole—dihydropyranones in good enantioselectivity.
ChemInform Abstract: TFAA/H3PO4 Mediated Unprecedented N‐Acylation of Carbazoles Leading to Small Molecules Possessing anti‐Proliferative Activities Against Cancer Cells.
Authors: Kolli Sunder Kumar , Prasad Bagineni , Babu P. Vijaya , Ashfaq Mohd Ashraf , Ehtesham Nasreen Z. , Raju R. Ramesh , Pal Manojit
Published: December 2014

TFAA/H3PO4 is identified for the first time as an efficient coupling agent for the direct N‐acylation of carbazoles.
ChemInform Abstract: Formation of Condensed 1H‐Pyrrol‐2‐ylphosphonates and 1,2‐Dihydropyridin‐2‐ylphosphonates via Kabachnik—Fields Reaction of Acetylenic Aldehydes and Subsequent 5‐exo‐dig or 6‐endo‐dig Cyclizations.
Authors: Buksnaitiene Rita , Urbanaite Aurelija , Cikotiene Inga
Published: December 2014

The title process is found to strongly depend on the structure of the starting materials.
ChemInform Abstract: Fluoro‐Functionalized Polymeric Ionic Liquids: Highly Efficient Catalysts for CO2 Cycloaddition to Cyclic Carbonates under Mild Conditions.
Authors: Yang Zhen‐Zhen , Zhao Yanfei , Ji Guipeng , Zhang Hongye , Yu Bo , Gao Xiang , Liu Zhimin
Published: December 2014

The applied catalyst can be recycled and shows high stability.
ChemInform Abstract: Catalyst Selective and Regiodivergent O‐ to C‐ or N‐Carboxyl Transfer of Pyrazolyl Carbonates: Synthetic and Computational Studies.
Authors: Cheong Paul Ha‐Yeon , et al. et al.
Published: December 2014

Treatment of pyrazolyl carbonates (I) with DMAP in CH2Cl2 gives rise to N‐carboxyl isomers (II), whilst an O‐ to C‐carboxyl transfer is observed by treatment with potassium hexamethyldisilazide and NHC precursors in toluene leading to esters (III).
ChemInform Abstract: Metal‐Free 5‐exo‐Dig Cyclization of Propargyl Urea Using TBAF.
Authors: Huguenot Florent , Delalande Clemence , Vidal Michel
Published: December 2014

Depending on the substituents adjacent to the triple bond the intramolecular cyclization of propargyl ureas provide imidazolinones (II) or methylene‐imidazolidinones (IV) in good yields.
ChemInform Abstract: An Unexpected Copper(II)‐Catalyzed Three‐Component Reaction of Quinazoline 3‐Oxide, Alkylidenecyclopropane, and Water
Authors: An Yuanyuan , Zheng Danqing , Wu Jie
Published: December 2014

leading to formamides (III)
ChemInform Abstract: Regioselective Suzuki—Miyaura Cross‐Coupling Reactions of the Bis(triflate) of 4,7‐Dihydroxycoumarin.
Authors: Khaddour Zien , Akrawi Omer A. , Suleiman Ali S. , Patonay Tamas , Villinger Alexander , Langer Peter
Published: December 2014

Due to electronic reasons, the first cross‐coupling reaction takes place at the sterically more hindered position.
ChemInform Abstract: Regioselective Synthesis of Polysubstituted 4H‐Thiopyrans from β‐Oxodithioesters.
Authors: Madabhushi Sridhar , Kurva Srinivas , Vangipuram Venkata Sairam , Sriramoju Vinodkumar , Mallu Kishore Kumar Reddy , Nanubolu Jagadeesh Babu
Published: December 2014

A simple protocol allows the highly regioselective cyclocondensation of β‐oxothioesters with prop‐2‐yn‐1‐ols to afford 4H‐thiopyran derivatives.
ChemInform Abstract: Quinoxalinone—Benzimidazole Rearrangement: An Efficient Strategy for the Synthesis of Structurally Diverse Quinoline Derivatives with Benzimidazole Moieties.
Authors: Mamedov Vakhid A. , Galimullina Venera R. , Zhukova Nataliya A. , Kadyrova Saniya F. , Mironova Ekaterina V. , Rizvanov Il'dar Kh. , Latypov Shamil K.
Published: December 2014

Spiroquinoxalinone derivatives, generated in situ from 3‐(o‐aminophenyl)quinoxalinones (I) with acetophenones, undergo acid mediated rearrangement to give benzimidazolylquinolines (III).
ChemInform Abstract: Quinoline and Phenanthroline Preparation Starting from Glycerol via Improved Microwave‐Assisted Modified Skraup Reaction.
Authors: Saggadi Hanen , Luart Denis , Thiebault Nicolas , Polaert Isabelle , Estel Lionel , Len C.
Published: December 2014

Microwave‐assisted modified Skraup reaction of anilines with glycerol provides access to quinoline derivatives.
ChemInform Abstract: Efficient and Regiospecific Syntheses of Peptides with Piperazic and Dehydropiperazic Acids via a Multicomponent Reaction.
Authors: Handy Emma L. , Totaro Kyle A. , Lin Charlie P. , Sello Jason K.
Published: December 2014

The synthesis of piperazic acid derivatives via a novel multicomponent reaction of tetrahydropyridazines, isocyanides, and carboxylic acids is presented.
ChemInform Abstract: Chitosan: An Efficient Promoter for the Synthesis of 2‐Aminopyrimidine‐5‐carbonitrile Derivatives in Solvent Free Conditions.
Authors: Siddiqui I. R. , Rai Pragati , Rahila Rahila , Srivastava Anushree
Published: December 2014

Reusable chitosan without any post‐modification is found to be an efficient heterogeneous catalyst for the convenient synthesis of title compounds (IV) (12 examples) from guanidines (III), aldehydes (II), and cyanoketones such as (I).
ChemInform Abstract: Tetrasubstituted Pyrazinones Derived from the Reaction of Praziquantel with N‐Bromosuccinimide.
Authors: Zhao Qingjie , Wang Chunkai , Ezell Edward L. , Dong Yuxiang , Vennerstrom Jonathan L.
Published: December 2014

The cytotoxicity of the synthesized pyrazones are tested against several protozoan parasites.
ChemInform Abstract: Synthesis of Fused 3‐Aminoazepinones via Trapping of a New Class of Cyclic Seven‐Membered Allenamides with Furan.
Authors: Schurgers Ben , Brigou Ben , Urbanczyk‐Lipkowska Zofia , Tourwe Dirk , Ballet Steven , De Proft Frank , Van Lommen Guy , Verniest Guido
Published: December 2014

The corresponding allenamides are formed in situ and are directly trapped with furan to give the Diels‐Alder products.
ChemInform Abstract: Silver(I) and Gold(I)‐Promoted Synthesis of Alkylidene Lactones and 2H‐Chromenes from Salicylic and Anthranilic Acid Derivatives.
Authors: Nolla‐Saltiel Roberto , Robles‐Marin Elvis , Porcel Susana
Published: December 2014

The cycloisomerization of terminal alkynoic acids is catalyzed by Ag(I)‐ and Au(I)‐salts.
ChemInform Abstract: A Reagent for the One‐Step Preparation of Potassium Acyltrifluoroborates (KATs) from Aryl‐ and Heteroarylhalides.
Authors: Eros Gabor , Kushida Yo , Bode Jeffrey W.
Published: December 2014

A novel protocol for the synthesis of potassium acyltrifluoroborates from aryl‐ and heteroarylhalides using zwitterionic S‐ethyl thioformamide trifluoroboronate as CO‐ and BF3‐source is presented.
ChemInform Abstract: A New Halimane Diterpenoid from Croton crassifolius
Authors: Zhang Zhan‐Xin , Li Hui‐Hong , Qi Feng‐Ming , Xiong Hui‐Yan , Dong Le‐Le , Fan Gai‐Xia , Fei Dong‐Qing
Published: December 2014

isolation, structural elucidation and cytotoxicity of the new halimane diterpenoid crassifoliusin A (I)
ChemInform Abstract: New Cytotoxic C‐3 Dehydrated Bufadienolides from the Venom of Bufo bufo gargarizans.
Authors: Tian Hai‐Yan , Zhang Peng‐Wei , Liu Jun‐Shan , Zhang Dong‐Mei , Zhang Xiao‐Qi , Jiang Ren‐Wang , Ye Wen‐Cai
Published: December 2014

The title compounds (I) and (II) are isolated and screened for their cytotoxic activities against A549 and HepG2 cancer cell lines.
ChemInform Abstract: Synthesis of γ‐Oxo‐α,β‐dehydro‐α‐amino Acids from N‐tert‐Butyloxycarbonyl‐α‐imino Esters and Carbonylmethyl 2‐Pyridinylsulfones via an Mannich‐Elimination Cascade.
Authors: Wu Deyan , Zhu Jin , Sheng Chunquan , Wang Wei , Li Jian
Published: December 2014

The temperature is critical for the elimination sequence.
ChemInform Abstract: Two New Chemical Constituents from Leaves of Perilla frutescens var. acuta.
Authors: Woo Kyeong Wan , Han Ji Young , Suh Won Se , Lee Jei Hyun , Lee Kang Ro
Published: December 2014

isolation and structure of two new compounds, perillascens (I) and perillaside (II), along with 34 known compounds
ChemInform Abstract: A New Furfural Diglycoside and Other Carbohydrate Derivatives from Fermented Beverage of Prunus mume Fruit.
Authors: Yan Xi‐Tao , Li Wei , Sun Ya‐Nan , Yang Seo Young , Song Gyu Yong , Kim Young Ho
Published: December 2014

isolation and structure determination of the new furfural diglycoside (I) along with 18 known compounds
ChemInform Abstract: New Dibenzocyclooctadiene Lignan from Kadsura induta and Their Cytotoxic Activities.
Authors: Kim Seung Hyun , et al. et al.
Published: December 2014

Schizanrin O (I) is isolated along with six known compounds from the leaves of K.
ChemInform Abstract: Stereoselective Synthesis of C19—C27 Fragment of Bryostatin 11.
Authors: Yadav J. S. , Swamy T. , Subba Reddy B. V. , Ravinder V.
Published: December 2014

The key steps for the synthesis of the title fragment (I) are kinetic resolution, Grignard reaction, Sharpless dihydroxylation, and for the first time, AIBN radical cyclization to construct the six‐membered pyran system.
ChemInform Abstract: Synthesis of Natural Maleimides Farinomaleins C—E and Evaluation of Their Antifungal Activity.
Authors: Lahore Santosh , Aiwale Sachin T. , Sardi Paola , Dallavalle Sabrina
Published: December 2014

Farinomalein C (I) demonstrates promising antifungal activity against Cladosporium cladosporioides.
ChemInform Abstract: Succinct Synthesis of Bosentan Utilizing Glycol Mono‐THP Ether.
Authors: Lee Chung Ryul , Lee Sang Yeul , Nam Tae‐gyu
Published: December 2014

An improved synthetic method for bosentan (I) is presented.
ChemInform Abstract: Incredible Pace of Research on Mesoporous Silica Nanoparticles
Authors: Jadhav Sushilkumar A.
Published: December 2014

Review: 21 refs.
ChemInform Abstract: Magnetic Properties of Nanostructured Spinel Ferrites
Authors: Cruz‐Franco Berenice , Gaudisson Thomas , Ammar Souad , Bolarin‐Miro Ana Maria , Sanchez de Jesus Felix , Mazaleyrat Frederic , Nowak Sophie , Vazquez‐Victorio Gabriela , Ortega‐Zempoalteca Raul , Valenzuela Raul
Published: December 2014

Review: 40 refs.
ChemInform Abstract: Magnetocaloric Effect in Intermetallic Compounds and Alloys
Authors: Roy Sindhunil Barman
Published: December 2014

Review: 367 refs.
ChemInform Abstract: Advanced Chemical Compositions and Nanoarchitectures of Bismuth Based Complex Oxides for Solar Photocatalytic Application
Authors: Sun Songmei , Wang Wenzhong
Published: December 2014

Review: emphasis on BiVO4, Bi2WO6, and Bi2MoO6‐based photocatalysts; 206 refs.
ChemInform Abstract: Chemically Modified Gold Superatoms and Superatomic Molecules
Authors: Nishigaki Jun‐ichi , Koyasu Kiichirou , Tsukuda Tatsuya
Published: December 2014

Review: 158 refs.
ChemInform Abstract: Structure, Synthesis and Application of Azines: A Historical Perspective
Authors: Safari Javad , Gandomi‐Ravandi Soheila
Published: December 2014

Review: [144 refs.
ChemInform Abstract: Perspectives on Heterogeneous Photochemistry
Authors: Friend Cynthia M.
Published: December 2014

Review: 51 refs.
ChemInform Abstract: Microwave‐Assisted Synthesis of Five‐Membered O,N‐Heterocycles
Authors: Kaur Navjeet
Published: December 2014

Review: development in the last 5‐10 years; 87 refs.
ChemInform Abstract: Recent Developments in Alkyne Borylations
Authors: Barbeyron Renaud , Benedetti Erica , Cossy Janine , Vasseur Jean‐Jacques , Arseniyadis Stellios , Smietana Michael
Published: December 2014

Review: [152 refs.
ChemInform Abstract: A Concise Account of the Chemistry of Valuable Alkyl(methyl)maleic Anhydrides
Authors: Deore Prashant , Haval Kishan , Gadre Smita , Argade Narshinha P.
Published: December 2014

Review: [90 refs.
ChemInform Abstract: Rediscovering the Chemistry of Sulfur Dioxide: New Developments in Synthesis and Catalysis
Authors: Deeming Alex S. , Emmett Edward J. , Richards‐Taylor Charlotte S. , Willis Michael C.
Published: December 2014

Review: [88 refs.
ChemInform Abstract: Green Trends in Mannich Reaction
Authors: Sreevalli W. , Ramachandran G. , Madhuri W. , Sathiyanarayanan Kulathu Iyer
Published: December 2014

Review: 93 refs.
ChemInform Abstract: New Technology for Enantiopure Amino Acid Synthesis
Authors: Palais Laetitia , Brayer Jean‐Louis
Published: December 2014

Review: 11 refs.
ChemInform Abstract: Synthetic Methodologies in Organic Chemistry Involving Incorporation of [17O] and [18O] Isotopes
Authors: Theodorou Vassiliki , Skobridis Konstantinos , Alivertis Dimitrios , Gerothanassis Ioannis P.
Published: December 2014

Review: 234 refs.
ChemInform Abstract: Synthesis and Investigation of Ferrichrysin Derivatives
Authors: Kobayashi Yuka , Oishi Shinya , Kobayashi Kazuya , Ohno Hiroaki , Tsutsumi Hiroko , Hata Yoji , Fujii Nobutaka
Published: December 2014

Review: 2 refs.
ChemInform Abstract: Chemoenzymatic Synthesis of Glycoprotein
Authors: Asahina Yuya , Kamitori Shigehiro , Takao Toshifumi , Nishi Nozomu , Suzuki Akemi , Katayama Hidekazu , Nakahara Yoshiaki , Hojo Hironobu
Published: December 2014

Review: 4 refs.
ChemInform Abstract: Protein Chemical Synthesis with Serine/Threonine Ligation
Authors: Li Xuechen
Published: December 2014

Review: 7 refs.
ChemInform Abstract: Polarizability as a Landmark Property for Fullerene Chemistry and Materials Science
Authors: Sabirov Denis Sh.
Published: December 2014

Review: 257 refs.
ChemInform Abstract: Inorganic Nanomaterials for Bioimaging, Targeted Drug Delivery and Therapeutics
Authors: Liang Ruizheng , Wei Min , Evans David G. , Duan Xue
Published: December 2014

Review: [117 refs.