bluuebunny/crossref_metadata_2025 huggingface dataset:
Staged Sinus Floor Elevation Using Novel Low-Crystalline Carbonate Apatite Granules: Prospective Results after 3-Year Functional Loading
Authors: Ogino Yoichiro , Ayukawa Yasunori , Tachikawa Noriko , Shimogishi Masahiro , Miyamoto Youji , Kudoh Keiko , Fukuda Naoyuki , Ishikawa Kunio , Koyano Kiyoshi
Published: October 2021

The aim of this study was to evaluate clinical outcomes of staged sinus floor elevation (SFE) using novel low-crystalline carbonate apatite (CO3Ap) granules. Patients who needed SFE for implant placement were recruited into this clinical trial. A staged procedure (lateral window technique using CO3Ap granules, followed by implant placement after 7 ± 2 months) was employed in 13 patients. Bone-height increase and insertion torque values (ITVs) were assessed along with histological evaluation. The survival and success rates of 3-year functioning implants were also evaluated. Mean of bone-height increase after SFE using CO3Ap granules was 7.2 ± 2.5 mm and this increase allowed implant placement in all cases (17 implants). Mean of ITV was 25.1 ± 13.2 Ncm and primary stability was achieved successfully in all cases. Histological analyses revealed mature new bone formation (36.8 ± 17.3%) and residual CO3Ap granules (16.2 ± 10.1%) in the compartment after SFE. The survival and success rates after 3-year functional loading were 100% and no complications were found. These results clearly indicate the clinical usefulness of CO3Ap granules for SFE.
Assessment of the Bending Moment Capacity of Naturally Corroded Box-Section Beams
Authors: Fiołek Przemysław , Jakubowski Jacek
Published: October 2021

The steel constructions of mine shaft steelwork are particularly exposed to aggressive environments, which cause large, nonuniform corrosion loss throughout the steel members. A correct assessment of corrosion loss and load-carrying capacity of shaft steelwork is crucial for its maintenance and safe operation. In this article, we present the results of laboratory, numerical, and analytical investigations conducted on naturally corroded steel guides disassembled from shaft steelwork. The steel guides considered had a closed profile formed by welding two hot-rolled channel sections. Laboratory bending tests were carried out on beams with various levels of corrosion loss, corresponding to compact, non-compact, and slender cross sections. Multiple detailed measurements of the thicknesses of naturally corroded walls were used in order to reproduce their nonuniform geometry in finite element (FE) models. The results of numerical simulations of five bending tests showed good agreement with laboratory measurements and replicated the observed failure modes, therefore confirming the applicability of this modeling approach for assessing the moment capacity of highly corroded steel beams when the deteriorated geometry is known. For the purpose of generalization, a series of derived models reflecting the natural corrosion pattern was then developed, and moment capacity statistics were collected through multiple simulations. They showed that the mean moment capacity is determined by the mean wall thickness. However, the minimum moment capacity is strongly affected by corrosion loss variation, particularly for the highly corroded beams. A simplified, analytical modeling approach was also examined, providing fairly good assessments of the mean; however, the minimum moment capacity could not be estimated. This study contributes to the body of knowledge on the mechanical behavior of highly corroded hot-rolled box-section beams.
New Edge Crush Test Configuration Enhanced with Full-Field Strain Measurements
Authors: Garbowski Tomasz , Knitter-Piątkowska Anna , Marek Aleksander
Published: October 2021

The standard edge crush test (ECT) allows the determination of the crushing strength of the corrugated cardboard. Unfortunately, this test cannot be used to estimate the compressive stiffness, which is an equally important parameter. This is because any attempt to determine this parameter using current lab equipment quickly ends in a fiasco. The biggest obstacle is obtaining a reliable measurement of displacements and strains in the corrugated cardboard sample. In this paper, we present a method that not only allows for the reliable identification of the stiffness in the loaded direction of orthotropy in the corrugated board sample, but also the full orthotropic material stiffness matrix. The proposed method uses two samples: (a) traditional, cut crosswise to the wave direction of the corrugated core, and (b) cut at an angle of 45°. Additionally, in both cases, an optical system with digital image correlation (DIC) was used to measure the displacements and strains on the outer surfaces of samples. The use of a non-contact measuring system allowed us to avoid using the measurement of displacements from the crosshead, which is burdened with a large error. Apart from the new experimental configuration, the article also proposes a simple algorithm to quickly characterize all sought stiffness parameters. The obtained results are finally compared with the results obtained in the homogenization procedure of the cross-section of the corrugated board. The results were consistent in both cases.
Effect of Hole Arrangement on Failure Mechanism of Multiple-Hole Fiber Metal Laminate under On-Axis and Off-Axis Loading
Authors: Zhang Jipeng , Wang Yue , Yang Wen , Zhao Yuan
Published: October 2021

Mechanical joints are commonly required in structures made of fiber metal laminate (FML), which pose a threat due to multi-site stress concentrations at rivet or bolt holes. Thus, for a reasonably designed FML joint, it is essential to characterize the failure mechanism of multiple-hole FML; however, little information about this has been found in open literature. In the present work, influences of hole arrangement and loading strategy (on-axis or off-axis) on the failure mechanism of multiple-hole FML were investigated, by performing finite element analyses and energy dissipation analyses with elastoplastic progressive damage models that took curing stress into account. Six types of specimens with holes arranged in parallel and staggered forms were designed, whose geometrical parameters were in strict accordance with those specified for composites joints. It indicated that the stress distribution, gross/net notched strength, critical fracture path, and damage evaluation process were only slightly influenced by the hole number and hole arrangement. On the other hand, they were strongly influenced by the loading strategy, due to the transition of failure domination. Results presented here can provide evidence for introducing design regulations of composite joints into the more hybrid FML, and for reasonably determining its multiple-hole strength merely based on the sing-hole specimen.
First-Principles Simulation of Dielectric Function in Biomolecules
Authors: Adhikari Puja , Podgornik Rudolf , Jawad Bahaa , Ching Wai-Yim
Published: October 2021

The dielectric spectra of complex biomolecules reflect the molecular heterogeneity of the proteins and are particularly important for the calculations of electrostatic (Coulomb) and electrodynamic (van der Waals) interactions in protein physics. The dielectric response of the proteins can be decomposed into different components depending on the size, structure, composition, locality, and environment of the protein in general. We present a new robust simulation method anchored in rigorous ab initio quantum mechanical calculations of explicit atomistic models, without any indeterminate parameters to compute and gain insight into the dielectric spectra of small proteins under different conditions. We implement this methodology to a polypeptide RGD-4C (1FUV) in different environments, and the SD1 domain in the spike protein of SARS-COV-2. Two peaks at 5.2–5.7 eV and 14.4–15.2 eV in the dielectric absorption spectra are observed for 1FUV and SD1 in vacuum as well as in their solvated and salted models.
Physical and Dielectric Properties of Ni-Doped In2S3 Powders for Optical Windows in Thin Film Solar Cells
Authors: Timoumi Abdelmajid , Belhadj Walid , Alamri Salah Noaiman , Al-Turkestani Mohamed Khalil
Published: October 2021

This paper reports the effect of Nickel (Ni) on indium sulfide (In2S3) powder. This work presents a systematic study of the physical and dielectric properties of In2-xS3Nix powders with 0, 2, 4, and 6 at.% of nickel. Doped and undoped samples were investigated by X-ray powder diffraction (XRD), energy dispersive X-ray spectroscopy, thermal gravimetric analysis, Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy, scanning electron microscopy (SEM), and impedance spectroscopy. XRD patterns revealed that each In2-xS3Nix composition was crystalline, which was also confirmed by the FTIR results. The presence of Ni in the samples was confirmed by energy dispersive spectroscopy (EDS). The Raman studies show different peaks related to the In2S3 phase and do not reveal any secondary phases of In–Ni and Ni–S. The SEM images of the undoped and Ni-doped In2S3 samples indicated a correlation between dopant content and the surface roughness and porosity of the samples. The impedance analysis indicated semiconductor behavior present in all samples, as well as a decrease in resistance with increasing Ni content. This work opens up the possibility of tailoring the properties and integrating Ni-doped In2S3 nanocomposites as thin film layers in future solar cells.
In-Plane Behaviour of Masonry Walls: Numerical Analysis and Design Formulations
Authors: Celano Thomas , Argiento Luca Umberto , Ceroni Francesca , Casapulla Claudia
Published: October 2021

This paper presents the results of several numerical analyses aimed at investigating the in-plane resistance of masonry walls by means of two modelling approaches: a finite element model (FEM) and a discrete macro-element model (DMEM). Non-linear analyses are developed, in both cases, by changing the mechanical properties of masonry (compressive and tensile strengths, fracture energy in compression and tension, shear strength) and the value of the vertical compression stress applied on the walls. The reliability of both numerical models is firstly checked by means of comparisons with experimental tests available in the literature. The analyses show that the numerical results provided by the two modelling approaches are in good agreement, in terms of both failure loads and modes, while some differences are observed in their load-displacement curves, especially in the non-linear field. Finally, the numerical in-plane resistances are compared with the theoretical formulations provided by the Italian building code for both flexural and shear failure modes and an amendment for the shape factor ‘b’ introduced in the code formulation for squat walls is proposed.
Preparation Process and Phase Transformation of Al-5Ti-0.25C Master Alloy Adopting Ti Machining Chips
Authors: Li Sanbo , Zhao Chunfang , Wang Fei , Hu Maoliang , Ji Zesheng , Sugiyama Sumio
Published: October 2021

The refining performance of Al-Ti-C master alloys is substantially compromised by the inferior wettability between graphite and molten aluminum. In this paper, the Al-5Ti-0.25C master alloy was successfully prepared by reacting Ti machining chips, graphite, and molten aluminum. In order to determine a simple method of improving the wettability, the optimal preparation process and phase transformation of the Al-5Ti-0.25C master alloy were investigated using an optical microscope, X-ray diffractometer, and scanning electron microscope equipped with an energy dispersive spectrometer. The results show that the feeding method using a prefabricated block made from Ti chips, Al chips, and graphite effectively improves the wettability between graphite and molten aluminum and increases the recovery rate of graphite. When the reaction temperature is low (1223 K), the agglomeration of TiAl3 is caused. When the reaction temperature is high (1373 K), the morphology of TiAl3 changes from block-like to needle-like and increases its size. Further, a short reaction time (30 min) results in the incomplete dissolution of the Ti chips, while a long reaction time (90 min) causes the TiAl3 to transform into needle-like morphologies. The microstructural observation of undissolved Ti chips shows that TiAl3 and TiC are formed around it, which proves the transformation of Ti chips to TiAl3 and TiC. In addition, the enrichment of TiC and Al4C3 was observed in the vicinity of TiAl3, and a reaction model for the formation of TiC from the reaction of Al4C3 and TiAl3 was presented.
Exploring Dielectric Constant and Dissipation Factor of LTCC Using Machine Learning
Authors: Liu Yu-chen , Liu Tzu-Yu , Huang Tien-Heng , Chiu Kuo-Chuang , Lin Shih-kang
Published: October 2021

Low-temperature co-fired ceramics (LTCCs) have been attracting attention due to rapid advances in wireless telecommunications. Low-dielectric-constant (Dk) and low-dissipation-factor (Df) LTCCs enable a low propagation delay and high signal quality. However, the wide ranges of glass, ceramic filler compositions, and processing features in fabricating LTCC make property modulating difficult via experimental trial-and-error approaches. In this study, we explored Dk and Df values of LTCCs using a machine learning method with a Gaussian kernel ridge regression model. A principal component analysis and k-means methods were initially performed to visually analyze data clustering and to reduce the dimension complexity. Model assessments, by using a five-fold cross-validation, residual analysis, and randomized test, suggest that the proposed Dk and Df models had some predictive ability, that the model selection was appropriate, and that the fittings were not just numerical due to a rather small data set. A cross-plot analysis and property contour plot were performed for the purpose of exploring potential LTCCs for real applications with Dk and Df values less than 10 and 2 × 10−3, respectively, at an operating frequency of 1 GHz. The proposed machine learning models can potentially be utilized to accelerate the design of technology-related LTCC systems.
Microstructure and Wear Property of ZrO2-Added NiCrAlY Prepared by Ultrasonic-Assisted Direct Laser Deposition
Authors: Yi Zhengyao , Song Chenchen , Zhang Guohui , Tong Tianqi , Ma Guangyi , Wu Dongjiang
Published: October 2021

For improving the wear properties of NiCrAlY, the 10 wt %, 20 wt % and 30 wt % ZrO2-added NiCrAlY samples were prepared by ultrasonic-assisted direct laser deposition, respectively. The results showed that the ultrasonic-assisted direct laser deposition can realize the ZrO2-added NiCrAlY preparation. Furthermore, due to the cavitation effect and agitation of the ultrasound in the molten pool, ultrasonic-assisted could make the upper surface of the samples smoother and flatter, and it also improved the microstructural homogeneity. The microstructure was mainly composed of columnar dendrites, and most of ZrO2 particles were located in the intergranular regions. The principal phase constituents were found to contain γ-Ni and t-NiZr2, and the amorphous (Ni, Zr) intermetallic phase generated, because of more rapid solidification after ultrasound assisted. The microhardness was improved slightly with the increase of ZrO2 contents, rising from 407.9 HV (10% ZrO2) to 420.4 HV (30% ZrO2). Correspondingly, wear mass loss was decreased with the maximum drop 22.7% of 30% ZrO2 compared to that of 10% ZrO2, and wear mechanisms were mainly abrasive wear with slightly adhesive wear. After applying ultrasound, the oxide islands in samples disappeared, and more ceramic particles were retained. Thus, the hardness and wear performance of the samples were improved.
Effect of Process Factors on Tensile Shear Load Using the Definitive Screening Design in Friction Stir Lap Welding of Aluminum–Steel with a Pipe Shape
Authors: Choy Leejon , Kim Seungkyung , Park Jeonghun , Kang Myungchang , Jung Dongwon
Published: October 2021

Recently, friction stir welding of dissimilar materials has emerged as one of the most significant issues in lightweight, eco-friendly bonding technology. In this study, we welded the torsion beam shaft—an automobile chassis component—with cast aluminum to lighten it. The study rapidly and economically investigated the effects of friction stir welding and process parameters for A357 cast aluminum and FB590 high-strength steel; 14 decomposition experiments were conducted using a definitive screening design that could simultaneously determine the effects of multiple factors. Friction stir welding experiments were conducted using an optical microscope to investigate the tensile shear load behavior in the welding zone. In addition to understanding the interactions between tool penetration depth and plunge speed and tool penetration depth and dwell time, we investigated and found that tool penetration depth positively affected the size of the hooking area and contributed to the stabilization and size reduction of the cavity. The experimental results showed that the plunge depth and tool penetration depth effects were most important; in this case, the plunge depth negatively affected the magnitude of tensile shear load, whereas the tool penetration depth had a positive effect. Therefore, when selecting a tool, it is important to consider the plunge depth and tool penetration depth in lap welding.
Characterization of Wet Olive Pomace Waste as Bio Based Resource for Leather Tanning
Authors: Solé M. Mercè , Pons Laia , Conde Mireia , Gaidau Carmen , Bacardit Anna
Published: October 2021

Olive mill wastes represent an important environmental problem. Their high phenol, lipid, and organic acid concentrations turn them into phytotoxic materials. Specifically, wet olive pomace (WOP) is the waste generated in the two-phase continuous extraction process. WOP is a paste with around 60% water. The total volume of WOP generated is around 0.25 L/kg of olives processed. Its current waste management practices result in environmental problems as soil contamination, underground seepage, water-bodies pollution, and foul odor emissions. Some valorization alternatives include composting, biological treatments, direct combustion for energy production, or direct land application. The leather industry is making great efforts to apply cleaner processes while substituting chemical products for natural products. In this way, different alternatives are being studied, such as the use of zeolites, triazine derivatives, grape seed extract, olive leaf extract, etc. In this work, the use of wet olive pomace is presented as a possible alternative to conventional vegetable tannins (mimosa, quebracho, chestnut, etc.). Although different projects and studies have been developed for the valorization of olive mill wastes, there is completely a new approach to the WOP application for tanning purposes. This study shows that WOP has a significant number of polyphenolic substances, so it has a great potential to be used as a tanning agent. Specifically, this study has been able to determine that, of the polyphenols present in WOP, 39.6% correspond to tannins that are capable of tanning the skin. Additionally, it contains 14.3% non-tannins, that is, molecules that by themselves do not have the capacity to tan the leather but promote the tanning mechanism and improve the properties of the tanned leather.
Efficient Temporal Third/Fourth-Order Finite Element Method for a Time-Fractional Mobile/Immobile Transport Equation with Smooth and Nonsmooth Data
Authors: Nong Lijuan , Chen An
Published: October 2021

In recent years, the numerical theory of fractional models has received more and more attention from researchers, due to the broad and important applications in materials and mechanics, anomalous diffusion processes and other physical phenomena. In this paper, we propose two efficient finite element schemes based on convolution quadrature for solving the time-fractional mobile/immobile transport equation with the smooth and nonsmooth data. In order to deal with the weak singularity of solution near t=0, we choose suitable corrections for the derived schemes to restore the third/fourth-order accuracy in time. Error estimates of the two fully discrete schemes are presented with respect to data regularity. Numerical examples are given to illustrate the effectiveness of the schemes.
A Comparative Study of Corrosion AA6061 and AlSi10Mg Alloys Produced by Extruded and Additive Manufacturing
Authors: Estupiñan-López Francisco , Gaona-Tiburcio Citlalli , Jáquez-Muñoz Jesús , Zambrano-Robledo Patricia , Maldonado-Bandala Erick , Cabral-Miramontes José , Nieves-Mendoza Demetrio , D. Delgado Anabel , Flores-De los Rios Juan Pablo , Almeraya-Calderón Facundo
Published: October 2021

The aim of this work was to evaluate the corrosion behavior of the AA6061 and AlSi10Mg alloys produced by extruded and additive manufacturing (selective laser melting, SLM). Alloys were immersed in two electrolytes in H2O and 3.5 wt. % NaCl solutions at room temperature and their corrosion behavior was studied by electrochemical noise technique (EN). Three different methods filtered EN signals, and the statistical analysis was employed to obtain Rn, the localization index (LI), Kurtosis, skew, and the potential spectral density analysis (PSD). The Energy Dispersion Plots (EDP) of wavelets method was employed to determine the type of corrosion and the Hilbert–Huang Transform (HHT), analyzing the Hilbert Spectra. The result indicated that the amplitude of the transients in the time series in potential and current is greater in the AlSi10Mg alloy manufactured by additive manufacturing. The amplitude of the transients decreases in both alloys (AA6061 and AlSi10Mg) as time increases.
In Situ Observation of the Tensile Deformation and Fracture Behavior of Ti–5Al–5Mo–5V–1Cr–1Fe Alloy with Different Microstructures
Authors: Pan Suping , Fu Mingzhu , Liu Huiqun , Chen Yuqiang , Yi Danqing
Published: October 2021

The plastic deformation processes and fracture behavior of a Ti–5Al–5Mo–5V–1Cr–1Fe alloy with bimodal and lamellar microstructures were studied by room-temperature tensile tests with in situ scanning electron microscopy (SEM) observations. The results indicate that a bimodal microstructure has a lower strength but higher ductility than a lamellar microstructure. For the bimodal microstructure, parallel, deep slip bands (SBs) are first noticed in the primary α (αp) phase lying at an angle of about 45° to the direction of the applied tension, while they are first observed in the coarse lath α (αL) phase or its interface at grain boundaries (GBs) for the lamellar microstructure. The β matrix undergoes larger plastic deformation than the αL phase in the bimodal microstructure before fracture. Microcracks are prone to nucleate at the αp/β interface and interconnect, finally causing the fracture of the bimodal microstructure. The plastic deformation is mainly restricted to within the coarse αL phase at GBs, which promotes the formation of microcracks and the intergranular fracture of the lamellar microstructure.
Tailoring a Refractory High Entropy Alloy by Powder Metallurgy Process Optimization
Authors: Moravcikova-Gouvea Larissa , Moravcik Igor , Pouchly Vaclav , Kovacova Zuzana , Kitzmantel Michael , Neubauer Erich , Dlouhy Ivo
Published: October 2021

This paper reports the microstructural evolution and mechanical properties of a low-density Al0.3NbTa0.8Ti1.5V0.2Zr refractory high-entropy alloy (RHEA) prepared by means of a combination of mechanical alloying and spark plasma sintering (SPS). Prior to sintering, the morphology, chemical homogeneity and crystal structures of the powders were thoroughly investigated by varying the milling times to find optimal conditions for densification. The sintered bulk RHEAs were produced with diverse feedstock powder conditions. The microstructural development of the materials was analyzed in terms of phase composition and constitution, chemical homogeneity, and crystallographic properties. Hardness and elastic constants also were measured. The calculation of phase diagrams (CALPHAD) was performed to predict the phase changes in the alloy, and the results were compared with the experiments. Milling time seems to play a significant role in the contamination level of the sintered materials. Even though a protective atmosphere was used in the entire manufacturing process, carbide formation was detected in the sintered bulks as early as after 3 h of powder milling. Oxides were observed after 30 h due to wear of the high-carbon steel milling media and SPS consolidation. Ten hours of milling seems sufficient for achieving an optimal equilibrium between microstructural homogeneity and refinement, high hardness and minimal contamination.
Direct Surface Modification of Polycaprolactone-Based Shape Memory Materials to Introduce Positive Charge Aiming to Enhance Cell Affinity
Authors: Zako Takafumi , Matsushita Shoko , Hoshi Toru , Aoyagi Takao
Published: October 2021

In this study, the introduction of a positive charge on the surface of a shape memory material was investigated to enhance cell affinity. To achieve this, the direct chemical modification of a material surface was proposed. Sheet-type, crosslinked poly(caprolactone-co-α-bromo-ɤ-butyrolactone) (poly(CL-co-BrBL)) were prepared, and the direct reaction of amino compounds with bromo groups was conducted on the material surface with a positive charge. Branched poly(CL-co-BrBL) was prepared, followed by the introduction of methacryloyl groups to each chain end. Using the branched macromonomers, stable and sheet-type materials were derived through UV-light irradiation. Then, the materials were soaked in an amino compound solution to react with the bromo groups under various conditions. Differential scanning calorimetry and surface analysis of the modified materials indicated that 10 vol% of N, N-dimethylethylenediamine in n-hexane and 1 h soaking time were optimal to maintain the inherent thermal properties. The achievement of increased luminance and a positive zeta potential proved that the direct modification method effectively introduced the positive charge only on the surface, thereby enhancing cell affinity.
Review of Organic Photorefractive Materials and Their Use for Updateable 3D Display
Authors: Blanche Pierre-Alexandre , Ka Jae-Won , Peyghambarian Nasser
Published: October 2021

Photorefractive materials are capable of reversibly changing their index of refraction upon illumination. That property allows them to dynamically record holograms, which is a key function for developing an updateable holographic 3D display. The transition from inorganic photorefractive crystals to organic polymers meant that large display screens could be made. However, one essential figure of merit that needed to be worked out first was the sensitivity of the material that enables to record bright images in a short amount of time. In this review article, we describe how polymer engineering was able to overcome the problem of the material sensitivity. We highlight the importance of understanding the energy levels of the different species in order to optimize the efficiency and recording speed. We then discuss different photorefractive compounds and the reason for their particular figures of merit. Finally, we consider the technical choices taken to obtain an updateable 3D display using photorefractive polymer. By leveraging the unique properties of this holographic recording material, full color holograms were demonstrated, as well as refreshing rate of 100 hogels/second.
Bone Stress Evaluation with and without Cortical Bone Using Several Dental Restorative Materials Subjected to Impact Load: A Fully 3D Transient Finite-Element Study
Authors: Medina-Galvez Raul , Cantó-Navés Oriol , Marimon Xavier , Cerrolaza Miguel , Ferrer Miquel , Cabratosa-Termes Josep
Published: October 2021

Statement of problem. Previous peri-implantitis, peri-implant bone regeneration, or immediate implant placement postextraction may be responsible for the absence of cortical bone. Single crown materials are then relevant when dynamic forces are transferred into bone tissue and, therefore, the presence (or absence) of cortical bone can affect the long-term survival of the implant. Purpose: the purpose of this study is to assess the biomechanical response of dental rehabilitation when selecting different crown materials in models with and without cortical bone. Methods: several crown materials were considered for modeling six types of crown rehabilitation: full metal (MET), metal-ceramic (MCER), metal-composite (MCOM), peek-composite (PKCOM), carbon fiber-composite (FCOM), and carbon fiber-ceramic (FCCER). An impact-load dynamic finite-element analysis was carried out on all the 3D models of crowns mentioned above to assess their mechanical behavior against dynamic excitation. Implant-crown rehabilitation models with and without cortical bone were analyzed to compare how the load-impact actions affect both type of models. Results: numerical simulation results showed important differences in bone tissue stresses. The results show that flexible restorative materials reduce the stress on the bone and would be especially recommendable in the absence of cortical bone. Conclusions: this study demonstrated that more stress is transferred to the bone when stiffer materials (metal and/or ceramic) are used in implant supported rehabilitations; conversely, more flexible materials transfer less stress to the implant connection. Also, in implant-supported rehabilitations, more stress is transferred to the bone by dynamic forces when cortical bone is absent.
Fatigue Life Assessment of Welded Joints by Combined Measurements Using DIC and XRD
Authors: Wang Yixun , Ueda Kazushi , Nagao Ryota , Tsutsumi Seiichiro
Published: October 2021

The existing methods of assessing the fatigue life of welded joints fail to consider local strain ranges and mean stress at the weld toe. The present work proposes a novel approach to assessing the fatigue life of welded joints by conducting measurements with digital image correlation (DIC) and X-ray diffraction (XRD) in combination. Local strain ranges at the weld toe of gusset welded joints were measured by DIC. Hammer peening was conducted on the welded joints to introduce different initial stresses. The influence of mean stress was investigated by considering initial residual stress measured by XRD and a perfect plastic material model. The fatigue experiment was carried out on specimens with and without hammer peening. The results showed that hammer peening could offset adverse welding deformation effectively, and introduce significant residual compressive stress. The fatigue failure life increased by more than 15 times due to hammer peening. The fatigue initiation life assessed by the proposed method was close to that based on nominal stress, indicating that the proposed method is reliable for predicting the fatigue initiation life of welded joints.
Model of Production System Evaluation with the Influence of FDM Machine Reliability and Process-Dependent Product Quality
Authors: Paprocka Iwona , Kempa Wojciech M.
Published: October 2021

This paper investigates the Job Shop Scheduling Problem (JSSP) with FDM (Fused Deposition Modeling) machine unavailability constraints due to Predictive Maintenance (PdM) tasks, under the objective of minimizing the makespan, total tardiness and machine idle time. The Ant-Colony Optimization (ACO) algorithm is elaborated to deal with the JSSP. The reliability characteristics of the critical machine (FDM) influence the product as well as the production system quality. PdM periods are estimated based on historical data on failure-free times of the FDM machine components and deviations from the standards established for the key process parameters: infill density, layer thickness and extruder temperature. The standards for the key process parameters are identified based on investigation of the mechanical properties of printed elements. The impact of failure time and the number of nonstandard measurements of parameters on the quality of the Job Shop System (JSS) are observed. Failure rate of the FDM machine is corrected with the probability of a stoppage in the future period due to the “outlier” in measurements of any key parameters of the additive process. The quality robustness of production schedules increases with the disturbance-free operation of the FDM up to the peak value. After reaching the peak value the quality robustness decreases. The original issue of this paper is a model of scheduling production and maintenance tasks in a job shop system with an FDM machine as a bottleneck using ACO. Additionally, an original FDM-reliability model is also proposed. The model is based on weighted p-moving averages of the observed number of deviations from the norms, established for key process parameters such as fill density, layer thickness and extruder temperature.
Sorption and Micro-Scale Strength Properties of Coals Susceptible to Outburst Caused by Changes in Degree of Coalification
Authors: Godyń Katarzyna , Dutka Barbara
Published: October 2021

Coals from the south-western part of the Upper Silesian Coal Basin have a strong outburst susceptibility. The objective of this study was to identify the influence of coalification degree on methane sorption and micro scale strength properties of 24 coals from Jastrzębie Zdrój. Coal samples showed a reflectance Ro between 0.98 and 1.25%. Sorption measurements were carried out by gravimetric method. Sorption capacities were determined at mean deposit temperature of 35 °C. Using the unipore model and solution of Fick’s second law, the effective diffusion coefficients of methane in the studied coals were obtained. The Vickers method was used to study the microhardness and the modulus of elasticity. It has been shown that the increase in the coalification degree reduces the sorption capacity of coal and also reduces the rate of methane emission. Coals the most susceptible to outbursts, were the most brittle. With the increase in Ro, the methane seam pressure p increased as well as desorbable methane content DMC, both due to the reduction in the sorption capacity of coal. The increased dp index is a warning sign indicating an increased total methane content of coal seam, an increased seam pressure or an alternation of coal structure.
Tensile Properties and Deformation of AISI 316L Additively Manufactured with Various Energy Densities
Authors: Jaskari Matias , Ghosh Sumit , Miettunen Ilkka , Karjalainen Pentti , Järvenpää Antti
Published: October 2021

Additive manufacturing (AM) is an emerging fabrication technology that offers unprecedented potential for manufacturing end-to-end complex shape customized products. However, building products with high performance by AM presents a technological challenge. Inadequate processing parameters, fabrication environment or changes in powder properties may lead to high defect density in the part and poor mechanical properties. Microstructure, defect structure, and mechanical properties of AISI 316L stainless steel pieces, additively manufactured by the laser powder bed fusion method using three different volume energy densities (VEDs), were investigated and compared with those of a commercial wrought AISI 316L sheet. Scanning and transmission electron microscopies were employed for characterization of grain and defect structures, and mechanical properties were determined by tensile testing. It was found that the number of defects such as pores and lack of fusion in AM specimens did not affect the strength, but they impaired the post-uniform elongation, more significantly when processed with the low VED. Twinning was found to be an active deformation mechanism in the medium and high VED specimens and in the commercially wrought material in the later stage of straining, but it was suppressed in the low VED specimens presumably because the presence of large voids limited the strain attained in the matrix.
Investigations of Effects of Intermetallic Compound on the Mechanical Properties and Shape Memory Effect of Ti–Au–Ta Biomaterials
Authors: Chiu Wan-Ting , Fuchiwaki Kota , Umise Akira , Tahara Masaki , Inamura Tomonari , Hosoda Hideki
Published: October 2021

Owing to the world population aging, biomedical materials, such as shape memory alloys (SMAs) have attracted much attention. The biocompatible Ti–Au–Ta SMAs, which also possess high X–ray contrast for the applications like guidewire utilized in surgery, were studied in this work. The alloys were successfully prepared by physical metallurgy techniques and the phase constituents, microstructures, chemical compositions, shape memory effect (SME), and superelasticity (SE) of the Ti–Au–Ta SMAs were also examined. The functionalities, such as SME, were revealed by the introduction of the third element Ta; in addition, obvious improvements of the alloy performances of the ternary Ti–Au–Ta alloys were confirmed while compared with that of the binary Ti–Au alloy. The Ti3Au intermetallic compound was both found crystallographically and metallographically in the Ti–4 at.% Au–30 at.% Ta alloy. The strength of the alloy was promoted by the precipitates of the Ti3Au intermetallic compound. The effects of the Ti3Au precipitates on the mechanical properties, SME, and SE were also investigated in this work. Slight shape recovery was found in the Ti–4 at.% Au–20 at.% Ta alloy during unloading of an externally applied stress.
Internal Stress and Dislocation Interaction of Plate-Shaped Misfitting Precipitates in Aluminum Alloys
Authors: Muraishi Shinji
Published: October 2021

The fine misfit precipitates in age-hardenable aluminum alloys have important roles due to their excellent age-hardening ability, by their interaction with dislocations. The present study focused on the internal stress field of plate-shaped misfitting precipitates to evaluate their roles in dislocation overcoming the precipitates by means of micromechanics based on Green’s function method. The stress field of misfit precipitates on {001} and {111} habit planes were reproduced by homogeneous misfit strain (eigenstrain) of the precipitate (Eshelby inclusion method), and the dislocation motion vector on the primary slip plane was predicted by the force acted on the dislocation by the Peach–Koehler formula. According to simulation results, the dislocation interaction strongly depends on the stress field and geometry of misfit precipitates; repulsive and attractive forces are operated on the dislocations lying on the primary slip plane when the dislocation approaches the misfit precipitates. The hardening ability of different orientations of precipitation variants was discussed in terms of interaction force acted on the dislocation.
Theft-Safe Explosive Mixtures Based on Hydrogen Peroxide: Study of Properties and Built-In Self-Deactivation Kinetics
Authors: Polis Mateusz , Nikolczuk Karolina , Maranda Andrzej , Stolarczyk Agnieszka , Jarosz Tomasz
Published: October 2021

The current focus on both environmental and general safety is an important issue in the field of explosives. As such, environmentally-friendly explosives, based on hydrogen peroxide (HTP) as an oxidising agent, are of significant interest. These explosives can be designed to undergo self-deactivation, denying access to them by any unlawful third parties that may attempt scavenging blasting sites for any residual energetic materials. Such deactivation also improves blasting safety, as, after a set time, misfired charges no longer pose any explosive threat. In this work, we have designed HTP-based explosive formulations that undergo deactivation after approximately 12 h. To this effect, Al powders were used both as fuels and HTP decomposition promoters. The shock wave parameters and ability to perform mechanical work of the proposed explosive formulations are comparable to those of dynamites and bulk emulsion explosives, and the details of the changes of these parameters over time are also reported.
Preparation and Tribological Properties of Lanthanum Stearate Modified Lubricating Oil for Wire Rope in a Mine Hoist
Authors: Zhang Yewei , Zhang Qing , Peng Yuxing , Wang Chen , Chang Xiangdong , Chen Guoan
Published: October 2021

In view of the serious friction and wear on the surface of a hoisting wire rope caused by the failure of lubrication under severe hoisting conditions, a study on the tribological characteristics of lanthanum stearate modified lubricating oil (LSMLO) was carried out. First, lanthanum stearate was prepared by the saponification reaction, and its surface morphology, chemical structure, thermal stability, and dispersion stability in IRIS-550A lubricating oil (IRIS) for wire rope were analyzed. Then, the tribological properties of LSMLO were investigated through four-ball friction tests and sliding wear tests of wire ropes. The results show that stearic acid almost completely reacts to produce lanthanum stearate, which has good thermal stability and a disordered layered structure. With the help of oleic acid, the dispersion stability of lanthanum stearate in IRIS can be significantly improved. The four-ball friction tests show that the optimal addition amount of lanthanum stearate in IRIS is 0.2 wt.%, and the CoF and wear scar diameter are reduced by about 35% and 25% respectively when lubricated with LSMLO compared to that with IRIS. LSMLO can better reduce the wear of the wire rope under different sliding speeds and contact loads than IRIS, and it exhibits improved anti-friction and anti-wear properties under high speed and low load.
Synthesized Nanorods Hydroxyapatite by Microwave-Assisted Technology for In Vitro Osteoporotic Bone Regeneration through Wnt/β-Catenin Pathway
Authors: Shaban Nadia Z. , Kenawy Marwa Y. , Taha Nahla A. , Abd El-Latif Mona M. , Ghareeb Doaa A.
Published: October 2021

This research presents an optimal and inexpensive, without any additives, method for the synthesis and sintering of hydroxyapatite (HA) by microwave-assisted technology (MAT) furnace. The target sintering temperature of the furnace (1100 ℃) was held for one and two hours for conventional sintering. With regard to the microwave hybrid sintering, it was held at 100%MW for 20 and 30 min. FTIR, XRD, TGA, SEM/EDS, and TEM were assessed to determine HA phase composition, and structural as well as thermal decomposition behavior. The in vitro effects of sintered HA discs on cultured aged mice-isolated osteoblast cells and hydrocortisone-induced osteoclast cells were assessed by measuring ALP, osteocalcin, TRAP, calcium, and Alizarin red S staining. Moreover, their effects on cell differentiation (CD90 and CD 105 and PARR- ɣ) and death markers (GSK3b, MAPK, and β-catenin) were evaluated. The results demonstrate the production of ≈35 nm crystal-sized pure hydroxyapatite nanorod-like particles with a high degree of crystallinity and no impurities as required for biomedical application. HA increased osteogenesis (ALP, osteocalcin, and calcium) markers and decreased cell resorption markers. In addition, HA nanorods reversed the effect of cortisone on cell differentiation and death markers. In conclusion, microwave hybrid sintered HA is a potential nanomaterial for osteoporotic bone regeneration as HA reversed the cortisone adverse effect on osteoblast cell death through canonical and non-canonical pathways.
Transition from High-Entropy to Conventional Alloys: Which Are Better?
Authors: Babić Emil , Drobac Đuro , Figueroa Ignacio Alejandro , Laurent-Brocq Mathilde , Marohnić Željko , Mikšić Trontl Vesna , Pajić Damir , Perrière Loїc , Pervan Petar , Remenyi Gyorgy , Ristić Ramir , Salčinović Fetić Amra , Starešinić Damir , Zadro Krešo
Published: October 2021

The study of the transition from high-entropy alloys (HEAs) to conventional alloys (CAs) composed of the same alloying components is apparently important, both for understanding the formation of HEAs and for proper evaluation of their potential with respect to that of the corresponding CAs. However, this transition has thus far been studied in only two types of alloy systems: crystalline alloys of iron group metals (such as the Cantor alloy and its derivatives) and both amorphous (a-) and crystalline alloys, TE-TL, of early (TE = Ti, Zr, Nb, Hf) and late (TL = Co, Ni, Cu) transition metals. Here, we briefly overview the main results for the transition from HEAs to CAs in these alloy systems and then present new results for the electronic structure (ES), studied with photoemission spectroscopy and specific heat, atomic structure, thermal, magnetic and mechanical properties of a-TE-TL and Cantor-type alloys. A change in the properties of the alloys studied on crossing from the HEA to the CA concentration range mirrors that in the ES. The compositions of the alloys having the best properties depend on the alloy system and the property selected. This emphasizes the importance of knowing the ES for the design of new compositional complex alloys with the desired properties.
Large Area Deposition by Radio Frequency Sputtering of Gd0.1Ce0.9O1.95 Buffer Layers in Solid Oxide Fuel Cells: Structural, Morphological and Electrochemical Investigation
Authors: Coppola Nunzia , Polverino Pierpaolo , Carapella Giovanni , Ciancio Regina , Rajak Piu , Dario Montinaro , Martinelli Francesca , Maritato Luigi , Pianese Cesare
Published: October 2021

We investigate the influence of position, under large circular sputtering targets, on the final electrochemical performance of 35 mm diameter button solid oxide fuel cells with sputter-deposited Gadolinium doped Ceria barrier layers, positioned in order to almost cover the entirety of the area associated with a 120 × 80 mm2 industrial cell. We compare the results obtained via structural and morphological analysis to the Electrochemical Impedance Spectroscopy (EIS) measurements performed on the button cells, disentangling the role of different parameters. The Atomic Force Microscopy analysis makes it possible to observe a decrease in the roughness values from the peripheral to the central zones under the sputtering target, with peak-to-valley roughness values, respectively, decreasing from 380 nm to 300 nm, while Scanning Electron Microscopy and Energy Dispersive Spectroscopy show a dependence of the layer coverage from the position. The electrochemical performances of button cells with buffer layers of only 200 nm in thickness, and with negligible thickness gradients across them, show current density values of up to 478 mA/cm2 at 0.8 V and 650 °C, with an improvement of more than 67% with respect to button cells with standard (screen printed) buffer layers. These results point out the major influence exerted by parameters such as the thickness gradient and the coverage of the sputtered buffer layers in determining the final electrochemical performances.
A Strategy towards Light-Absorbing Coatings Based on Optically Black Nanoporous Alumina with Tailored Disorder
Authors: Pashchanka Mikhail , Cherkashinin Gennady
Published: October 2021

This work provides a conceptually new way of thinking about the light-absorbing mechanism in additive-free black porous anodic alumina (black PAA, or b-PAA) layers obtained via “burning” anodizing regime. The new insight into the controllable photonic effects in PAA allows the implementation of the optical blackening method based on the deliberate randomization of the initially well-ordered nanopore arrangement. The proposed black coloration mechanism rests solely on the destructive interference of light after its multiple scattering. Similar effects have been earlier considered for some natural or artificially created biomimetic structures (e.g., the so-called “moth eye effect”, or the coloration mechanism in the Neurothemis tullia dragonfly wings). Comprehensive analysis confirmed that the chemical composition of b-PAA has only a minor influence on the color changes and the optical density increase, and that the light-absorbing properties most likely result from the structural effects. The new functional 2D materials exhibit strong adhesion to aluminum surface, are cost-effective and suitable for application under harsh thermal or UV-light conditions. They are potentially useful for manufacturing of optical devices or heat-resistant coatings in aerospace technologies, as well as solid supports for biological filtration and fluorescence imaging.