bluuebunny/crossref_metadata_2025 huggingface dataset:
Comparison of different oxygen transfer testing procedures in full-scale membrane bioreactors
Authors: Krause S. , Cornel P. , Wagner M.
Published: May 2018

Membrane bioreactors (MBRs) for wastewater treatment offer the advantage of a complete removal of solids from the effluent. The secondary clarifier is replaced by a membrane filtration and therefore high biomass concentrations (MLSS) in the reactor are possible. The design of the aeration system is vital for an energy efficient operation of any wastewater treatment plant. Hence the exact measurement of oxygen transfer rates (OTR) and α-values is important. For MBRs these values reported in literature differ considerably. The OTR can be measured using non-steady state methods or using the off-gas method. The non-steady state methods additionally require the determination of the respiration rate (oxygen uptake rate ≡ OUR), which usually is measured in lab scale units. As there are differences of OUR between lab scale and full scale measurements, off-gas tests (which do not require an additional respiration test) were performed in order to compare both methods at high MLSS concentrations. Both methods result in the same average value of OTR. Due to variations in loading and wastewater composition variations of OTR in time can be pointed out using the off-gas method. For the first time a comparison of different oxygen transfer tests in full scale membrane bioreactors is presented.
Investigation of membrane processes for the removal of volatile fatty acids
Authors: Barnes S. , Dalhoff R. , Keller J. , Wilderer P. , Kendall L.
Published: May 2018

The accumulation of volatile fatty acids such as acetic acid can cause reactor pH problems and the inhibition of microorganisms utilised in anaerobic digestion processes. A cross-flow membrane process using Teflon and ion-exchange membranes was investigated as a means of separating acetic acid from pure acetic acid solution and rumen fluid. Acetic acid transfer across the Teflon membrane was dependent on the free acid concentration (CH3COOH) in the acid solution. Concurrent transfer of water was minimal due to the hydrophobic nature of the membrane. The strong base anionic exchange membrane facilitated the separation of acetic acid from both pure solutions and rumen fluid with flux again being dependent on the free acid gradient across the membrane. Flux rates were lower than other studies of diffusion dialysis, however, this may be partly attributed to improper preparation of the membrane. The currently achieved rates of transfer using these membranes are very low and are therefore not yet suitable for full-scale use in anaerobic digestion. Additional research is needed to achieve higher trans-membrane transport rates at reasonable costs.
Anaerobic digestion of excess activated sludge with ozone pretreatment
Authors: Goel R. , Tokutomi T. , Yasui H.
Published: May 2018

Source minimization of excess sludge production by economical means can be considered an attractive option to deal with the problem of sludge disposal under strict disposal standards. In this paper long-term operational results for a process that combines the oxidative ozone pretreatment with anaerobic sludge digestion are described. The ozone pretreatment solubilized around 19% and 37% of the solids at 0.015 and 0.05 gO3/gTS ozone dose. The solubilization ratios during ozonation did not show any significant difference for the sludge concentrations ranging from 1.8-2.6%. The TVS concentrations after ozone treatment were observed to be about 3% lower than the feed sludge concentrations suggesting only partial mineralization during ozonation. The ozone pretreatment resulted in improved solid reduction efficiencies during anaerobic digestion leading to higher methane recovery. The TVS removal efficiencies during anaerobic digestion were observed to increase by a maximum of 35-90% depending on the applied ozone dose during ozone pretreatment. The improvement in TVS degradation efficiency at different applied ozone doses correlated well with the extent of solubilization during ozonation. Long-term data also suggested that biomass acclimation to ozonated sludge was necessary before higher degradation efficiencies could be achieved.
Anaerobic hydrolysis of a municipal wastewater in a pilot-scale digester
Authors: Álvarez J.A. , Zapico C.A. , Gómez M. , Presas J. , Soto M.
Published: May 2018

Raw domestic wastewater from the city of Santiago de Compostela (Northwest Spain) was fed into a pilot-scale hydrolytic up flow sludge bed (HUSB) digester with an active volume of 25.5 m3. The total influent chemical oxygen demand (COD) ranged from 360 to 470 mg/l, the influent SS varied from 190 to 370 mg/l, and the temperature was between 17° and 20°C. The organic load rate (OLR) applied increased step by step from 1.2 to 3.9 kgCOD/m3.d, while the hydraulic retention time (HRT) decreased from 7.1 h to 2.9 h. A high suspended solids (SS) removal of about 82-85% from the influent was reached, most of which (81 to 88%) was eliminated by hydrolysis, while the rest remained in the purge stream. The total COD removal ranged from 46 to 59%. On the other hand, a high acidification of the COD remaining in the effluent was obtained, so the percent COD in the form of volatile fatty acids (VFACOD) with respect to total effluent COD was about 43% for the highest HRT applied, and about 27% for the lowest HRT. The soluble to total COD ratio (CODs/CODt) increased from 25-32% for the influent to 71-86% for the effluent. The results obtained confirm the viability and interest of direct anaerobic hydrolytic pre-treatment of domestic wastewater.
Impact of net pen aquaculture on lake water quality
Authors: Veenstra J. , Nolen S. , Carroll J. , Ruiz C.
Published: May 2018

A 3-year study was conducted by the U.S. Army Corps of Engineers assessing water quality related impacts of aquaculture of 250,000 channel catfish (Ictalurus punctatus) in floating net pens in the Rock Creek Arm of Lake Texoma, Oklahoma/Texas. Five large nylon nets suspended from a floating framework of galvanized metal anchored in open water 100 m offshore made up the net pens with fish stocking densities varying from 88 to 219 fish/m3. Water quality sampling was conducted biweekly from April to September and monthly from October to March at three locations. On all sampling dates field measurements of water temperature, pH, dissolved oxygen, and conductivity were recorded at 1 m depth intervals and water samples were collected at a depth of 0.5 m and near the bottom of the water column at each site. Sample analyses included: total alkalinity, total hardness, turbidity, chloride, sulfate, orthophosphate, total phosphorus, nitrate-N, nitrite-N, total Kjeldahl nitrogen, total organic carbon, dissolved organic carbon, biochemical oxygen demand, and chlorophyll a. The results showed statistically significant decreases in water temperature and dissolved oxygen and significant increases in field conductivity in surface waters near the net pens relative to other sampling sites. The most dramatic water quality effect observed during the study was decrease in dissolved oxygen levels near the net pens following lake turnover in the second year.
Water and wastewater related issues in Sri Lanka
Authors: Bandara N.J.G.J.
Published: May 2018

The primary problems concerning water resources in Sri Lanka are the depletion and degradation of the resource caused by various anthropogenic activities. Surface inland waters in urban areas are polluted heavily with domestic sewage and industrial effluents, and in rural areas with agricultural runoff. With regard to ground water in certain areas of the dry zone, there is a high fluoride content and in hard, rocky, alluvial areas, there is a high concentration of iron. In urban over-crowded cities, there is biological contamination of ground water. Over-utilization, particularly through tube wells, is another major problem affecting ground water resources in Sri Lanka. Oil spills, dumping of waste from ships, coral and sand mining, and industrial activities are the main causes of marine pollution in the country. Except for pipe-borne water supply, irrigation and hydropower schemes, in general water resources in Sri Lanka are managed very poorly. Regulations are available to control most water related problems but enforcement of these regulations is lacking.

The ultimate result of degradation and depletion of water resources is the increasing health hazards. Water-borne and vector-borne diseases are prevalent, particularly amongst urban low-income communities with poor sanitary facilities and drainage. Despite government initiatives and legislation, very slow progress has been made towards combating water pollution. This paper examines the most significant water and wastewater related issues in Sri Lanka and their controlling mechanisms.
Hydraulics of sub-superficial flow constructed wetlands in semi arid climate conditions
Authors: Ranieri E.
Published: May 2018

This paper reports the evaluation of the hydraulics of two constructed wetland (cws) plants located in Apulia (the South Eastern Italy region characterized by semi arid climate conditions). These fields were planted with Phragmites australis hydrophytes and are supplied with local secondary wastewater municipal treatment plant effluent. Each plant - Kickuth Root-Zone method based - covers an area of approx. 2,000 m2. The evapotranspiration phenomenon has been evaluated within perforated tubes fixed to the field bottom and very high values - up to 40 mm/d - were found. Hydraulic conductivity has been evaluated by in situ measurements at different field points. Hydraulic gradients and the piezometric curve within the field are also reported.
Evaluation of factors influencing diffusion of pollutant loads in urban highway runoff
Authors: Shinya M. , Tsuruho K. , Konishi T. , Ishikawa M.
Published: May 2018

Many studies have identified the first flush phenomenon and runoff characteristics. The purpose of this study is to elucidate which parameters influence the runoff pollutant loads. Eight runoff events during the period from May 1999 to September 2000 were investigated. From the dimensionless cumulative analysis, it was suggested that particulate substances such as suspended solids (SS), iron and total phosphorus (T-P) were inclined to be washed off in heavier rainfall condition. The cumulative curves of particulate constituents were appreciably variable in slope, while those of dissolved were approximately constant. Accordingly it was indicated that dissolved load was discharged regardless of rainfall conditions. Event mean runoff intensity and cumulative runoff height showed significant correlation with the cumulative runoff load of the constituents except for total nitrogen (T-N). On the other hand, antecedent dry weather period (ADWP) and traffic flow volume during ADWP did not show correlation with the cumulative runoff loads. Only T-N load showed correlation with those factors, consequently it was suggested that vehicular exhausts affected nitrogen load on the surface of urban highway.
Accounting for water quality effects of future urbanization: diffuse pollution loads estimates and control in Mantua's Lakes (Italy)
Authors: Capodaglio A.G. , Muraca A. , Becchi G.
Published: May 2018

The three shallow lakes of Mantua (Upper, Middle and Lower) formed by the Mincio River are today classified by Italian water authorities as sensitive areas, after, in the second half of the 20th century, the hydrologic regime of the lakes was heavily modified, and the influence of industrial activities operating in the 1960s - without much environmental consideration - created a substantial decline in the water quality of the lakes. The City of Mantua is one of the most vital industrial centers of Northern Italy, and development plans are under way, that should approximately double the extension of the urban and industrial area within the next 20 years. This paper deals with estimating the effects of the aforementioned urbanization on the future water quality of the three lakes.
Repressive effects of yeast extract on photoreactivation of Escherichia coli
Authors: Oguma J. , Katayama H. , Mitani H. , Ohgaki S.
Published: May 2018

Photoreactivation of Escherichia coli K12 (IFO 3301), in the presence or absence of yeast extract (YE), was investigated after inactivation by low-pressure UV lamp. An endonuclease sensitive site (ESS) assay was used to determine the UV-induced pyrimidine dimers in the genome of E. coli, while a colony-forming ability (CFA) test was also used to examine the survival ratio of E. coli. The YE solution reduced the CFA recovery at a final concentration of 125 mg/L. A dialysis of the YE solution indicated that the YE fraction (with nominal molecular weight >1,000 and <3,500) was effective at repressing the CFA recovery. Interestingly, the repair of ESS was equivalent regardless of the presence of the YE dialysate, while the CFA recovery was significantly repressed in the presence of YE. It was, therefore, suggested that YE components, probably with molecular weights of 1,000-3,500, were effective at repressing the CFA recovery of E. coli without affecting the ESS repair during photoreactivation.
Coupling pH-stat and DO-stat titration to monitor degradation of organic substrates
Authors: Ficara E. , Rozzi A.
Published: May 2018

A combined titration methodology at constant pH and dissolved oxygen concentration to monitor the degradation of organics as carbon dioxide evolution rate (CER) and oxygen uptake rate (OUR) is presented. Equations necessary to assess CER from alkali titration rates and the instrument used to test the technique are described. Experiments were performed on samples of activated sludge from a domestic wastewater treatment plant using glucose and ethanol as substrates. OUR and CER were calculated for both substrates, as well as the respiratory quotient RQ = CER/OUR and biomass to substrate yields coefficients. RQ data for ethanol compared better with corresponding stoichiometric values than those for glucose.
Bioremediation of methyl tertiary-butyl ether (MTBE) by an innovative biofilter
Authors: Hu C. , Acuna-Askar K. , Englande A.J.
Published: May 2018

Methyl tertiary-butyl ether (MTBE) is a synthetic chemical used in unleaded gasoline as an additive to reduce levels of ozone and carbon monoxide from auto exhaust. Due to its chemical and recalcitrant properties, MTBE has caused groundwater contamination worldwide. A laboratory-scale biofilter made of a natural fiber (kenaf) mat and inoculated with MTBE-degrading microorganisms, was evaluated for MTBE removal efficiency. Operational parameters of oxygen flow rate, hydraulic retention time (HRT), yeast extract and initial MTBE concentration were varied and MTBE removal efficiencies determined. Four kinetic models were evaluated to describe the MTBE removal in the reactor. Formaldehyde and tertiary butyl alcohol (the most two reported MTBE biodegradation byproducts) were not found in the effluent; instead, carbon dioxide was monitored as the end product based on the results of a metabolic mass balance evaluation. Toxicity of treated effluent was evaluated by employing the Microtox acute toxicity test and comparing that to the influent.
Performance of basaltic dust issued from an asphaltic plant as a flocculant additive for wastewater treatment
Authors: Ramírez Zamora R.M. , Chávez Mejía A. , Domínguez Mora R. , Durán Moreno A.
Published: May 2018

The feasibility of using basaltic dust as a flocculant additive or coagulant aid for wastewater treatment was assessed in this research. The experimental study was divided into two stages: 1) physicochemical characterisation of the basaltic dust by applying standardised techniques, and 2) evaluation of this material as flocculant additive for the coagulation-flocculation of wastewater treated for reuse. Coagulation-flocculation experiments were carried out in the laboratory with a mixture of industrial and municipal wastewater samples collected from two points of the final discharge of the Mexico City sewerage system. Aluminium sulphate and lime were used as coagulants and the basaltic dust as flocculant additive, by applying the jar-test technique. The results of the corrosivity, reactivity, explosiveness, toxicity, inflammability and biological risk tests indicated that this material is classified as a non-hazardous waste (according to the Mexican legislation, NOM-052-ECOL-1993). The density, oxide content and particle size values of basaltic dust were similar to those reported for the flocculant additive denominated activated silica. The jar test results showed a positive effect of basaltic dust over the effluent and sludge qualities, to the extent that coagulant doses can be reduced 30% (from 150 mg/L to 110 mg/L of Al2(SO4)3).
Microbicidal efficacy of an advanced oxidation process using ozone/hydrogen peroxide in water treatment
Authors: Sommer R. , Pribil W. , Pfleger S. , Haider T. , Werderitsch M. , Gehringer P.
Published: May 2018

The combined application of ozone and hydrogen peroxide represents a kind of advanced oxidation for water treatment. The radicals that are generated during the process are used for the degradation of organic pollutants from groundwater and industrial effluents. The aim of our study was to evaluate the possible microbicidal, and particularly virucidal, efficacy of such a process, since no substantial data were available. The investigations were performed at a pilot plant installed for the elimination of perchloroethylene from polluted groundwater (reduction efficacy for perchloroethylene from 26 mg/L to 5 mg/L). To enable a reliable evaluation of the microbicidal effect, a set of alternate test organisms was used. As model viruses we chose bacteriophages MS2 (F+ specific, single-stranded RNA), ΦX174 (single-stranded DNA) and PRD-1 (coated, double-stranded DNA). Furthermore, spores of Bacillus subtilis were included as possible surrogates for protozoa and Escherichia coli as representative for traditional indicator bacteria used in water analysis. The microbicidal efficiency was compared to the inactivation by means of ozone under two standard conditions (20°C): (a) 0.4 mg/L residual after 4 min and (b) 0.1 mg/L residual after 10 min. Surprisingly, a good microbicidal effect of the ozone/hydrogen peroxide process was found. This was somewhat unexpected, because we had assumed that the disinfection potential of ozone would have been interfered with by the presence of hydrogen peroxide. Escherichia coli and the three test viruses revealed a reduction of about 6-log. In contrast, spores of Bacillus subtilis showed after the total process a reduction of 0.4-log. These results matched the effect of the ozone treatment (a) with a residual of 0.4 mg/L after 4 min contact time (20°C). The test condition (b) with a residual of 0.1 mg/L ozone after a contact time of 10 min at 20°C gave a higher reduction of the B. subtilis spores (1.5-log). The presented study revealed a satisfying microbicidal efficacy of the ozone/hydrogen peroxide process with respect to vegetative bacteria and viruses (bacteriophages). However, it has to be emphasised that intense mixing and sufficient contact time have to be optimised and tested for each individual installation.
Evaluation of a rapid polymerase chain reaction based identification technique for Vibrio cholerae isolates
Authors: le Roux W.J. , Masoabi D. , de Wet C.M.E. , Venter S.N.
Published: May 2018

Rapid and accurate identification of waterborne pathogens, such as Vibrio cholerae, in drinking-water sources is important to enable effective resource management and public health protection. Phenotypic systems currently being used for the identification of Vibrio cholerae isolates are time-consuming and the need exists for the development of suitable molecular techniques that can offer both fast and reliable identification. During this study, isolates identified as Vibrio cholerae by means of two different biochemical test systems (API 20E and VITEK 32) were analysed with the polymerase chain reaction (PCR) to compare the reliability of the various identification systems. The selected PCR technique amplified a sequence within the outer membrane protein of Vibrio cholerae, a gene specific for V. cholerae. It was found that out of 243 isolates biochemically identified as V. cholerae with either the API or VITEK system, 21 isolates did not give a positive result with the PCR detection method. Sequencing the 16S rDNA of more than half of these isolates and comparison of the sequences with Internet databases indicated that most of the isolates belonged to the genus Aeromonas. The results indicated that the rapid PCR procedure was more accurate than the API or VITEK systems currently being used for the phenotypic identification of Vibrio cholerae isolates.
Development of procedures for rapid detection of E. coli O157:H7 from source and finished water samples
Authors: Bukhari Z. , Weihe J. , LeChevallier M.
Published: May 2018

Enterohaemorrhagic Escherichia coli (EHEC) O157:H7, the causative agent for haemolytic uraemic syndrome, has become a significant health concern, due to an increasing number of cases. The focus of this project was rapid (<8 h) detection of E. coli O157:H7 from source and finished waters samples, either directly or indirectly, by dovetailing the procedures with existing total coliform procedures. Evaluation of four immunological lateral diffusion assays determined a detection range between 1 7times; 104 and 1 × 106 CFU, with the Reveal® E. coli O157:H7 Test System (Neogen) being the most sensitive for detecting E. coli O157:H7. Evaluation of the BAX® System for molecular detection determined that as few as 10 CFU could be reproducibly detected. Coupling either of these detection procedures with organism propagation using Tryptic Soy Broth (TSB) enabled sufficient quantities of E. coli O157:H7, such that the Reveal® and BAX® detection methods could be used with the 8 h time frame. Examination of matrix effects on the overall procedure indicated little impact on method performance.
Assessment of microbial infection risks posed by ingestion of water during domestic water use and full-contact recreation in a mid-southern African region
Authors: Steyn M. , Jagals P. , Genthe B.
Published: May 2018

A customised Water-related Quantitative Microbial Risk Assessment (WRQMRA) process was used to determine risk of infection to water ingested by users in the south-eastern Free State, South Africa. The WRQMRA consisted of an observed-adverse-effect-level approach (OAELA) and a quantitative microbial risk assessment (QMRA). The OAELA was based on the occurrence of E. coli in the study waters to determine the possible risk of infection and the QMRA probable risk of infection by salmonellae. The WRQMRA was applied to recreational surface resource waters as well as waters from an unprotected spring and waters from the treated municipal supply that were stored in containers for domestic purposes. E. coli numbers were measured against expected infection levels expressed in water quality guidelines, while Salmonella counts were calculated to give the probable infection risk (Pi). Ingestion was based on intake volumes compiled for the various water uses. E. coli occurred in numbers <106 in the surface waters, while the untreated spring and treated supply water contained E. coli of <102 and <101 respectively. Salmonella occurred in numbers of <103 in recreational waters, and <10-1 in water used for domestic purposes. A single exposure to the mean (as well as 95th percentile) risk was calculated using a β-Poisson dose-response model at ingestion volumes of 100 mL (for full-contact recreation) and 1,318 mL (for domestic water use). Both the OAELA and the QMRA approaches indicated a risk of infection to recreational and domestic water users, even for a single exposure event, with the OAELA either over- or under-estimating the risk of infection for singular exposure events. This indicated that this method, used on its own, could not reliably predict a realistic risk of infection. It is recommended that the full WRQMRA process be used, and further developed to address several uncertainties that became evident during this study.
Guidelines for the safe use of wastewater in agriculture: revisiting WHO guidelines
Authors: Carr R.M. , Blumenthal U.J. , Duncan Mara D.
Published: May 2018

The use of wastewater in agriculture is occurring more frequently because of water scarcity and population growth. Often the poorest households rely on this resource for their livelihood and food security needs. However, there are negative health implications of this practice that need to be addressed. WHO developed Guidelines for the Safe Use of Wastewater in Agriculture in 1989. The Guidelines are currently being revised based on new data from epidemiological studies, quantitative microbial risk assessments and other relevant information. WHO guidelines must be practical and offer feasible risk management solutions that will minimize health threats and allow for the beneficial use of scarce resources. To achieve the greatest impact on health, guidelines should be implemented with other health measures such as: health education, hygiene promotion, provision of adequate drinking water and sanitation, and other health care measures.
Tools to monitor corrosion of cement-containing water mains
Authors: Slaats P.G.G. , Mesman G.A.M. , Rosenthal L.P.M. , Brink H.
Published: May 2018

Approximately 40,000 km of the drinking water network in The Netherlands consists of asbestos cement water pipes. The number of fractures in these pipes has increased greatly in recent years. This is due to corrosion of the asbestos cement (AC) which affects the condition of the pipe. Every time a fracture occurs, the question is raised of whether the pipe in question has to be replaced or repaired. A relatively simple destructive technique and non-destructive tests are used on a large scale to assess the condition of the AC pipes in use. Not only is corrosion detrimental to the pipes themselves, it also influences the water quality. Corrosion of the inner walls of cement-containing pipes involves the leaching of hydroxides. This causes pH changes resulting in scaling in water mains and domestic installations. Monitoring techniques have been developed to determine the effects of leaching on water quality. The large-scale use of the relatively simple techniques at water companies increases insight into the condition of the drinking water network, the life expectancy of the pipes and the effects of corrosion on the water quality. Applying these techniques enables those involved to make decisions on pipe replacement and to provide solutions for reducing the effects of leaching.
Copper corrosion: understanding and modelling general corrosion
Authors: Merkel T.H.
Published: May 2018

Based on a literature study and on pipe-rig studies a mechanism is proposed which subdivides general corrosion of copper into three subprocesses: oxidation, scale formation and dissolution. The subprocesses are further characterized and a mathematical model is built on the identified kinetic rate laws. Finally, conclusions for optimising corrosion control strategies are discussed.
Membrane bio-reactor for advanced textile wastewater treatment and reuse
Authors: Lubello C. , Gori R.
Published: May 2018

Textile wastewater contains slowly- or non-biodegradable organic substances whose removal or transformation calls for advanced tertiary treatments downstream Activated Sludge Treatment Plants (ASTP). This work is focused on the treatment of textile industry wastewater using Membrane Bio-reactor (MBR) technology. An experimental activity was carried out at the Baciacavallo Wastewater Treatment Plant (WWTP) (Prato, Italy) to verify the efficiency of a pilot-scale MBR for the treatment of municipal wastewater, in which textile industry wastewater predominates. In the Baciacavallo WWTP the biological section is followed by a coagulation-flocculation treatment and ozonation. During the 5 months experimental period, the pilot-scale MBR proved to be very effective for wastewater reclamation. On average, removal efficiency of the pilot plant (93% for COD, 96% for ammonium and 99% for total suspended solids) was higher than the WWTP ones. Color was removed as in the WWTP. Anionic surfactants removal of pilot plant and WWTP were very similar (92.5 and 93.3% respectively), while the non-ionic surfactants removal was higher in the pilot plant (99.2 vs. 97.1). In conclusion the MBR technology demonstrated to be effective for textile wastewater reclamation, leading both to an improvement of pollutants removal and to a draw-plate simplification.
Anaerobic/aerobic treatment of colorants present in textile effluents
Authors: Melgoza R. Ma. , Cruz A. , Buitrón G.
Published: May 2018

The operation of an anaerobic/aerobic process used to degrade the colorants present in textile wastewater is presented. The objective is to produce water that can be reused. Two particular cases were studied: the degradation of a synthetic wastewater containing the colorant disperse blue 79 (DB79) as a model compound and a real textile effluent containing reactive azo dyes. The biodegradation was achieved using a single tank operated as sequencing batch reactor. It was observed that the DB79 was biotransformed to amines in the anaerobic stage decolorizing the wastewater. The amines formed were subsequently mineralized in the aerobic phase. An increase of toxicity was observed in the anaerobic stage due to the amines formation, but the wastewater was detoxified after the aerobic treatment. Removal efficiencies of DB79 around 92% were observed after the treatment. Around 96% of the initial color of the real wastewater was effectively removed. It was observed that the biomass pre-acclimatized to the degradation of DB79 was more effective for the color removal than a freshly inoculum used.
Microbiological water quality in a large in-building, water recycling facility
Authors: Birks R. , Colbourne J. , Hills S. , Hobson R.
Published: May 2018

The Thames Water recycling plant at the Millennium Dome, London, reclaimed three sources of water: greywater from the washbasins, rainwater from the Dome roof and groundwater from a borehole on site. These were pre-treated separately, and the mixed stream filtered using ultrafiltration and reverse osmosis membranes. Monitoring for indicator microorganisms was undertaken throughout the plant and in the reclaimed water distribution system, as well as ad-hoc monitoring for the presence of pathogens in the raw waters. Treatment to the level of ultrafiltration was more than adequate to produce a water quality meeting existing worldwide reclaimed water guidelines for toilet flushing. Owing to the excellent quality of the water leaving the plant, no significant microbiological growth was observed in the reclaimed water distribution system during the year. The raw greywater exhibited a higher faecal bacterial load than the rainwater and groundwater, as predicted from more human contact (i.e. hand washing). Environmental strains of Legionella were observed in the three raw greywater samples analysed for pathogens, as was Cryptosporidium, Giardia and faecal enterococci. The rainwater had relatively high levels of faecal bacteria, probably of avian origin. Giardia was detected in one rainwater sample confirming the potential for this water source to contain pathogens.
Some magnetic field effects on in situ precipitated calcium carbonate
Authors: Chibowski E. , Holysz L. , Szczes A. , Chibowski M.
Published: May 2018

Magnetic field (MF) (B = 0.4 T) effects were studied on CaCO3 precipitated from Na2CO3 and CaCl2 solutions, which at 30°C were exposed for 30 min to the field. One of the impurity ions Mg2+, Zn2+, Fe2+, SO42-, HPO42- at 10-5 mol l-1 concentration was also added to CaCl2 or Na2CO3, respectively. The changes of zeta potential, pH and light absorbance (at λ=543.2 nm) of the slurry after CaCO3 precipitation were measured on the time. In some experiments changes in the deposited amounts of CaCO3 due to MF treatment were determined on glass plates. MF affected all the parameters measured and the effects depended on the kind of impurity ion present.
Removal mechanisms of endocrine disrupting compounds (steroids) during soil aquifer treatment
Authors: Mansell J. , Drewes J.E. , Rauch T.
Published: May 2018

The objective of this study was to determine the primary removal mechanisms of endocrine disruptors such as steroidal hormones present in reclaimed water, specifically 17b-estradiol, estriol, and testosterone, during groundwater recharge via soil aquifer treatment (SAT). Steroidal hormones were quantified using enzyme-linked immunosorbent assays. Bench-scale studies and laboratory-scale soil column experiments were employed to determine what mechanisms (i.e., adsorption, biodegradation, photolytic degradation) dominate the removal of the three compounds of interest during SAT. Findings of these studies revealed that the dominating removal mechanism for the compounds of interest during SAT is adsorption to the porous media matrix and additional attenuation to below the detection limit occurred in the presence of bioactivity. This additional removal occurred regardless of dominating redox conditions (aerobic vs. anoxic) or the type of organic carbon matrix present (hydrophobic acids, hydrophilic carbon vs. colloidal carbon).
Assessing the removal potential of soil-aquifer treatment systems for bulk organic matter
Authors: Rauch T. , Drewes J.E.
Published: May 2018

The fate of effluent organic matter (EfOM) during groundwater recharge was investigated by studying the removal behavior of four bulk organic carbon fractions isolated from a secondary effluent: Hydrophilic organic matter (HPI), hydrophobic acids (HPO-A), colloidal organic matter (OM), and soluble microbial products (SMPs). Short-term removal of the bulk organic fractions during soil infiltration was simulated in biologically active soil columns. Results revealed that the four organic fractions showed a significantly different behavior with respect to biological removal. HPI and colloidal OM were prone to biological removal during initial soil infiltration (0-30 cm) and supported soil microbial biomass growth in the infiltrative surface. Additionally, colloidal OM was partly removed by physical adsorption or filtration. HPO-A and SMPs reacted recalcitrant towards biological degradation as indicated by low soil biomass activity responses. Adsorbability assessment of the biologically refractory portions of the fractions onto powered activated carbon (PAC) indicated that physical removal is not likely to play a significantly role in further diminishing recalcitrant HPO-A, HPI and SMPs during longer travel times in the subsurface.
The reuse of treated wastewater for agricultural purposes in Nicaragua; Central America
Authors: Platzer M. , Cáceres V. , Fong N.
Published: May 2018

The first subsurface flow wetland (SSFW) system for about 1,000 PE, was constructed in Nicaragua in 1996 to apply this technology in the form of an integral project, combining the treatment of domestic wastewater with its reuse for crop production in small and medium size communities. The SSFW-effluent meets all standards established in the national regulations for wastewater reuse in agriculture, except for faecal coliforms, existent at an average concentration of 7 × 104 MPN/100 ml. A conventional surface irrigation method was used to irrigate different crop species selected to establish their risk of contamination. To judge the potential health risk for consumers and farmers, samples of vegetables and fruits harvested in the dry seasons of the years 1997 to 2002, were analyzed for the presence of pathogenic microorganisms like faecal coliforms, salmonella and shigella. In addition, a yield comparison between crops irrigated with well water using chemical fertilizers, and crops irrigated with the effluent of the SSFW-system was made, to analyze the economical benefits of the wastewater reuse.
Changes in nutrient levels in some Eastern European rivers in response to large-scale changes in agriculture
Authors: Stålnacke P. , Vandsemb S.M. , Vassiljev A. , Grimvall A. , Jolankai G.
Published: May 2018

Since the late 1980s, the use of commercial fertilisers in most Eastern European countries has decreased at an unprecedented rate. We examined the impact of this dramatic reduction in agricultural inputs on concentrations of nutrients in four rivers in Eastern Europe: the Emajogi and Õhnejogi (Estonia), the Daugava (Latvia), and the Tisza (Hungary). Time series of nitrate (NO3-N) and phosphate (PO4-P) concentrations and data on runoff were selected to represent catchments with substantial areas of agricultural land and available time series of sufficient length and frequency. The study period was 1987-1998. We detected downward trends in nitrate-N and phosphate-P in only two of the four rivers. Our results imply that the response to the extensive decrease in agricultural intensity since the late 1980s has been slow and limited in many rivers. Corresponding results in the literature are inconclusive and comprise several examples of both decreasing and non-decreasing nutrient concentrations. Our findings, along with similar data from other studies, indicate that large cuts in nutrient inputs do not necessarily induce an immediate response, particularly in medium-sized and large catchment areas. Moreover, the difference we noted between nitrogen and phosphorus suggests that factors other than reduced fertiliser application influenced the inertia of the water quality response.
Environmental effects of manure policy options in The Netherlands
Authors: Oenema O. , van Liere L. , Plette S. , Prins T. , van Zeijts H. , Schoumans O.
Published: May 2018

This study explores the effects of manure policy options for agricultural land in The Netherlands on nitrate leaching to groundwater, ammonia and nitrous oxide emissions to the atmosphere and on eutrophication of surface waters. The implementation of the farm gate balance MINAS at farm level, with levy-free N surpluses in the range of 300 to 40 kg per ha per year, and levy-free P surpluses in the range of 17.5 to 0.4 kg of P per ha per year, have been examined. Results indicate that nitrate concentrations in the upper groundwater are related to N surplus, land use, soil type and groundwater level. On dry sandy soils, the N surplus has to be below 60 to 140 kg of N per ha per year, depending on land use, to decrease the nitrate concentrations in the upper groundwater to below 50 mg nitrate per litre. Decreases of N and P concentrations in surface waters, upon lowering levy-free surpluses appear relatively small. For improving the ecological state of surface waters, we recommend a combination of low levy-free N and P surpluses with dredging P rich sediments, flushing of ditches, and decreasing discharges from other sources.
Dutch approach to abating agricultural non-point pollution: farmers' behaviour and their motivation
Authors: Sloots K. , Spierenburg P. , van der Vlies A.W.
Published: May 2018

In The Netherlands, agricultural activities are one of the major diffuse sources of nutrients and crop protection chemicals. A national legal and regulatory framework has been developed to combat the environmental burden from the agricultural industry. This resulted in the implementation of a government decree (AMvB) in the year 2000. Under pressure from NGOs, the Hollandse Eilanden en Waarden Water Board worked on a regional regulation in advance of this national legislation. ZHEW followed an approach of research, communication and partnering prior to implementing the national decree. The most important result of the chosen approach is that compliance with one of the most important measures, the crop-free zone, is close to 100%. There has been little improvement in the amount of pesticides in the open waters. Both water board and farmers are positive about the approach followed. Monitoring and evaluation proved to be essential when communicating with the agricultural sector. The results of attempts to influence behaviour must be recorded in order maintain the motivation to change behaviour. Information on the effects of the approach adopted to combating diffuse agricultural sources is gathered from a number of sources.
Ozonolysis mechanism of lignin model compounds and microbial treatment of organic acids produced
Authors: Nakamura Y. , Daidai M. , Kobayashi F.
Published: May 2018

Treatment methods comprising ozonolysis and microbial treatment of lignin discharged from the pulp manufacture industries were investigated by using a sulfite pulp wastewater and a lignin model compound, i.e. sodium lignosulfonate. Dynamic behaviors for the formations of intermediate derivatives such as muconic acid, maleic acid, and oxalic acid produced from the ozonolysis of sulfite pulp wastewater were observed from data of UV absorption at 280 nm by a spectrophotometer and at 210 nm by high performance liquid chromatography. The microorganisms that were isolated by the enrichment culture method were used to degrade the organic acids such as oxalic acid and acetic acid. Time courses of biological degradation of these organic acids indicated diauxic growth, which was found in a culture with mixed substrates. In the treatment of sodium lignosulfonate, the ozonolysis and microbial treatment using activated sludge converted sodium lignosulfonate into carbon dioxide and water almost completely.
Pulp mill process closure: a review of global technology developments and mill experiences in the 1990s
Authors: Stratton S.C. , Gleadow P.L. , Johnson A.P.
Published: May 2018

The impact of effluent discharges continues to be an important issue for the pulp manufacturing industry. Considerable progress has been made in pollution prevention to minimize waste generation, so-called manufacturing “process closure.” Since the mid-1980s many important technologies have been developed and implemented, many of these in response to organochlorine concerns. Zero effluent operation is now a reality for a few bleached chemi-thermomechanical pulp (BCTMP) pulp mills. In kraft pulp manufacturing, important developments include widespread adoption of new cooking techniques, oxygen delignification, closed screening, improved process control, new bleaching methods, and systems that minimize pulping liquor losses. Coupled to this is a commitment to reduce water use and maximize reuse of in-mill process streams. Some companies pursued bleach plant closure, and many have been successful in eliminating a portion of their bleaching wastewaters. However, the difficulties inherent in closing bleach plants are considerable. For many mills the optimal solution has been found to be a high degree of closure coupled with external biological treatment of the remaining process effluent. No bleach plants at papergrade bleached kraft mills are known to be operating effluent-free on a continuous basis. This paper reviews the important worldwide technological developments and mill experiences in the 1990s that were focused on minimizing environmental impacts of pulp manufacturing operations.
Dynamic actor network analysis for diffuse pollution in the province of North-Holland
Authors: Hermans L.M.
Published: May 2018

Diffuse pollution problems involve numerous different organizations and this requires decision makers to involve different actors if they want to develop policies that have a chance of being implemented effectively. A first step in such interactive policy development would be to gain an overview of the different actors involved in diffuse pollution problems, as well as their views on the problem, their interests and their means to influence policy development and implementation. Dynamic Actor Network Analysis (DANA) offers a method that helps analysts in providing such an overview, and the use of this method is explored through its application to a case in the Dutch province of North Holland. The described case specifically focuses on the use of herbicides in public space and involves actors from regional water management authorities, municipalities and private sector users. An important finding is that there is an imbalance in the perceptions of actors that needs to be addressed by water management authorities. The paper concludes that DANA is a promising tool for offering new and useful insights to decision makers, although more practical experience is needed to better assess the utility of this analysis tool.
New method for measuring potential secondary stickies in deinked pulp filtrates
Authors: Sarja T. , Zabihian M. , Kourunen P. , Niinimäki J.
Published: May 2018

Secondary stickies refer to sticky material in recycled fiber process streams, which has been dissolved in one part of process, but turned to solid phase due to changes in process conditions. The material that can later form secondary stickies is called potential secondary stickies. A new, fast, and simple method for measuring the amount of potential secondary stickies was developed to measure the purification result in the deinked pulp (DIP) filtrates. The new method, now called potential secondary stickies method, was tested with process waters from a recycled fiber (RCF) plant. The method was found to be reliable. Several chemicals and chemical combinations were tested in laboratory scale and compared as coagulation-flocculation agents in two dissolved air flotations (DAF) used as internal water treatment units at the RCF plant. With potential secondary stickies method, significant differences between the effectiveness of the chemicals were found, whereas no difference was seen in the quality of purified process water with traditional measuring methods. The measurement method was also used in mill during a two-week measuring period. As a conclusion, it can be said that this method can be used to monitor the quality and to predict the changes in DIP process water.
Effects of oxidative treatment techniques on molecular size distribution of humic acids
Authors: Kerc A. , Bekbolet M. , Saatci A.M.
Published: May 2018

In this study ultrafiltration has been used for the fractionation of humic acid samples. Humic acids were treated in a sequential oxidation system in which ozonation was followed by photocatalytic oxidation using TiO2. Evaluation of the spectroscopic characteristics of the oxidized and fractionated humic acid samples have shown that molecular size distribution ranges shift to lower molecular sizes depending on the oxidation stages. Applied ozone dosage and irradiation time during the photocatalysis stage are the factors affecting the molecular size distribution in the treated humic acid samples. Formation of lower molecular weight compounds during the ozonation stage resulted in increased degradation rates during the photocatalysis stage.
Influence of mass transfer and chemical reaction on ozonation of azo dyes
Authors: Choi I.S. , Wiesmann U.
Published: May 2018

Azo dyes can be only mineralised by chemical oxidation. In this paper the oxidation of Reactive Black 5 (RB 5) and Reactive Orange 96 (RO 96) with concentrations between 35 and 5,700 mgL-1 (RB 5) and between 20 and 2,050 mgL-1 (RO 96) was investigated in a lab-scale bubble column. The reactor was modelled for two cases, a completely mixed and a plug flow gas phase. The oxidation rate was influenced by mass transfer for all dye concentrations used. For low dye concentrations mass transfer alone was decisive for the reaction rate showing no enhancement due to chemical reaction, E = 1. However, in the region of high dye concentrations, the slope of the ozone concentration profile inside the liquid boundary layer increases more and more with increasing dye concentration as a result of a chemical oxidation. Therefore, the enhancement factor depends on the type and concentration of the azo dyes. For RB 5, a diazo dye, an enhancement factor of E = 5.5 was observed for cd = 2,000 mgL-1, RO 96, a mono azo dye, with a remarkably higher chemical oxidation rate shows an E = 16 for cd = 2,050 mgL-1.