Black carbon content of traffic emissions significantly impacts black carbon mass size distributions and mixing states
Authors: Li Fei , Luo Biao , Zhai Miaomiao , Liu Li , Zhao Gang , Xu Hanbing , Deng Tao , Deng Xuejiao , Tan Haobo , Kuang Ye , Zhao Jun 
Published: June 2023

Abstract. Both the size and mixing state of black carbon (BC)-containing aerosols are
crucial in estimating the environmental, health and climate impacts of BC.
Traffic emissions are a major global source of BC; however, parameterization
of BC mass size distributions and mixing states associated with traffic
remains lacking due to its dependence on vehicle types and driving
conditions. To investigate BC mass size distributions and mixing states
associated with traffic emissions, a field campaign was conducted in
the Guangzhou urban area during winter, which used a system coupling a
differential mobility analyzer (DMA) and a single-particle soot photometer
(SP2) to measure BC mass size distributions in the range of 100 to 700 nm.
The resolved primary organic aerosols were hydrocarbon-like organic aerosols
(HOA) and cooking-like organic aerosols (COA), as well as refractory BC (rBC), which was
detected by the DMA–SP2 and correlated highly with HOA (R2=0.88),
confirming that traffic emissions are the dominant source of atmospheric BC
during the observations. The BC mass size distribution was found to be best
fitted by a lognormal distribution, with a geometric mean (Dg,BC) of
258±16 nm, varying between 200 and 300 nm. During daytime, active
formation of secondary nitrate and organic aerosols was observed, but it had
little effect on the variations of BC mass size distributions. Further
analyses revealed that Dg,BC was moderately correlated with rBC / HOA (R2=0.41) in a linear form of Dg,BC=34×rBC/HOA+177, demonstrating that the BC content of traffic emissions
significantly impacts the BC mass size distributions. In addition, the
size-dependent fractions of BC-containing aerosols in all types of aerosols
(fBCc) and the fraction of identified externally mixed (bare/thinly
coated) BC particles in all BC-containing aerosols (fext) were also
characterized. It was found that the daytime secondary aerosol formation
reduced both fBCc and fext, with the decrease in fext being
more pronounced for larger particles, possibly due to the higher relative
coating thickness. Variations in fext during nighttime were mainly
controlled by the emission conditions. For example, fext for 600 nm
particles decreased from 0.82 to 0.46 as rBC / HOA increased from 1 to 3.5,
while the mass ratios of secondary aerosols to rBC varied little,
demonstrating that the BC content also significantly affects the mixing
states of freshly emitted BC from traffic emissions. This study suggests
that BC content can be used as the key factor to parameterize both the BC
mass size distribution and mixing states from traffic emissions, which
warrants future comprehensive investigation. In addition, other sources such
as biomass burning and coal combustion also contribute substantially to BC
emissions, and it was important to investigate whether BC content of other major
BC sources than traffic is also important in determining BC mass size
distributions and mixing states. Overall, results of this study have
significant implications for accurate representation of BC from different
sources when modeling the impacts of BC.