bluuebunny/crossref_metadata_2025 huggingface dataset:
Physiological and Growth Responses of Potato (Solanum Tuberosum L.) to Air Temperature and Relative Humidity under Soil Water Deficits
Authors: Zhang Peng , Yang Xin , Manevski Kiril , Li Shenglan , Wei Zhenhua , Andersen Mathias Neumann , Liu Fulai
Published: April 2022

Drought stress often occurs concurrently with heat stress, yet the interacting effect of high vapor pressure deficit (VPD) and soil drying on the physiology of potato plants remains poorly understood. This study aimed to investigate the physiological and growth responses of potatoes to progressive soil drying under varied VPDs. Potato plants were grown either in four separate climate-controlled greenhouse cells with different VPD levels (viz., 0.70, 1.06, 1.40, and 2.12 kPa, respectively) or under a rainout shelter in the field. The VPD of each greenhouse cell was caused by two air temperature levels (23 and 30 °C) combined with two relative humidity levels (50 and 70%), and the VPD of the field was natural conditions. Irrigation treatments were commenced three or four weeks after planting in greenhouse cells or fields, respectively. The results indicated that soil water deficits limited leaf gas exchange and shoot dry matter (DMshoot) of plants while increasing the concentration of abscisic acid (ABA) in the leaf and xylem, as well as water use efficiency (WUE) across all VPD levels. High VPD decreased stomatal conductance (gs) but increased transpiration rate (Tr). High VPD increased the threshold of soil water for Tr began to decrease, while the soil water threshold for gs depended on temperature due to the varied ABA response to temperature. High VPD decreased leaf water potential, leaf area, and DMshoot, which exacerbated the inhibition of soil drying to plant growth. Across the well-watered plants in both experiments, negative linear relationships of gs and WUE to VPD and positive linear relations between Tr and VPD were found. The results provide some novel information for developing mechanistic models simulating crop WUE and improving irrigation scheduling in future arid climates.
Cyperus (Cyperus esculentus L.): A Review of Its Compositions, Medical Efficacy, Antibacterial Activity and Allelopathic Potentials
Authors: Zhang Shengai , Li Peizhi , Wei Zunmiao , Cheng Yan , Liu Jiayao , Yang Yanmin , Wang Yuyan , Mu Zhongsheng
Published: April 2022

Cyperus (Cyperus esculentus L.) is an edible perennial grass-like plant, which propagates exclusively with underground tubers. Its tubers are rich in starch (20–30%), fat (25–35%), sugar (10–20%), protein (10–15%) and dietary fiber (8–9%). In addition, the tubers also contain alkaloids, organic acids, vitamins (C and E), steroids, terpenoids and other active components. The contents of oleic acid and linoleic acid in Cyperus oil are very high, which have important medicinal value and health-promoting properties. Most of the extracts from the tubers, stems and leaves of Cyperus have allelopathic potential and antibacterial, antioxidant and insecticidal activities. In recent years, the planting area of Cyperus has increased significantly all over the world, especially in China and some other countries. This paper presents the current status of Cyperus and the recent trend in research in this area. Published reports on its nutritional contents, active ingredients, medicinal efficacy, antibacterial activity and allelopathic potential were also reviewed.
The Biodiversity of Grapevine Bacterial Endophytes of Vitis amurensis Rupr.
Authors: Aleynova Olga A. , Nityagovsky Nikolay N. , Dubrovina Alexandra S. , Kiselev Konstantin V.
Published: April 2022

In this paper, the composition profiles of bacterial endophytes in wild-growing Amur grape Vitis amurensis Rupr. grown in the south of the Russian Far East were analyzed using both a cultivation-dependent (sowing bacteria) and a cultivation-independent (next generation sequencing, NGS) approach. Both methods revealed the prevalent endophytes in V. amurensis were represented by Gammaproteobacteria—40.3–75.8%, Alphaproteobacteria—8.6–18.7%, Actinobacteria—9.2–15.4%, and Bacilli—6.1–6.6%. NGS also showed a large proportion of Bacteroidia (12.2%) and a small proportion of other classes (less than 5.7%). In general, NGS revealed a greater variety of classes and genera in the endophytic bacterial community due to a high number of reads (574,207) in comparison with the number of colonies (933) obtained after the cultivation-dependent method. A comparative analysis performed in this study showed that both wild grape V. amurensis from Russia and domesticated cultivars of V. vinifera from Germany and California (USA) exhibit the same basic composition of endophytic bacteria, while the percentages of major taxa and minor taxa showed some differences depending on the plant organ, grape individuals, environmental conditions, and sampling time. Furthermore, the obtained data revealed that lower temperatures and increased precipitation favored the number and diversity of endophytic bacteria in the wild Amur grape. Thus, this study firstly described and analyzed the biodiversity of endophytic bacteria in wild grapevine V. amurensis.
Bergenia pacumbis (Buch.-Ham. ex D.Don) C.Y.Wu & J.T.Pan: A Comprehensive Review on Traditional Uses, Phytochemistry and Pharmacology
Authors: Gohain Apurba , Sharma Ajay , Gogoi Hirok Jyoti , Cooper Raymond , Kaur Ramandeep , Nayik Gulzar Ahmad , Shaikh Ayaz Mukarram , Kovács Béla , Areche Franklin Ore , Ansari Mohammad Javed , Alabdallah Nadiyah M. , AL-Farga Ammar
Published: April 2022

The influence of medicinal plants on humanity spans time immemorial. These plants are also used at present with local and tribal peoples for the cures of various illnesses. Nature has produced an immense number of medicinal plants, which directly or indirectly help to treat various ailments and have numerous applications in the fields of pharmaceuticals, agriculture, food flavors and preservatives, aromas, and cosmetics. Bergenia pacumbis (Buch.-Ham. ex D.Don) C.Y.Wu & J.T.Pan (synonym: Bergenia ligulate Engl.), is an important medicinal plant belonging to the Saxifragaceae family, and not to be confused with Bergenia ciliata (Haw.) Sternb., and is popularly known as Pashanbheda (meaning to dissolve the kidney stone). This plant is a rich source of secondary metabolites (SMs) such as coumarins, flavonoids, benzenoids, lactones, tannins, phenols, and sterols, which make this plant a highly valued medicinal herb with a broad spectrum of pharmacological activities such as anti-urolithic, antioxidant, anti-viral, free radical scavenging, antidiabetic, anti-hepatotoxic, diuretic, antipyretic, anti-oxaluria, anti-tumour, antibacterial, antifungal, anti-inflammatory, antimicrobial, and cardioprotective. This review summarizes traditional uses and offers up to date data for future research on B. pacumbis.
Phytochemical Profiling, Antimicrobial and α-Glucosidase Inhibitory Potential of Phenolic-Enriched Extracts of the Aerial Parts from Echium humile Desf.: In Vitro Combined with In Silico Approach
Authors: Aouadi Kaïss , Hajlaoui Hafedh , Arraouadi Soumaya , Ghannay Siwar , Snoussi Mejdi , Kadri Adel
Published: April 2022

The current study aimed to evaluate the naturally occurring antimicrobial and antidiabetic potential of various Echium humile (E. humile) solvent extracts (hexane, dichloromethane, ethyl acetate, methanol and aqueous). The bioactive compounds were identified using HPLC–MS, revealing the presence of sixteen phytochemical compounds, with the most abundant being p-coumaric acid, followed by 4,5-di-O-caffeoylquinic acid, trans-ferulic acid and acacetin. Furthermore, E. humile extracts showed marked antimicrobial properties against human pathogen strains, with MIC values for the most relevant extracts (methanol and ethyl acetate) ranging from 0.19 to 6.25 mg/mL and 0.39 to 12.50 mg/mL, respectively. Likewise, methanol was found to be bactericidal towards S. aureus, B. cereus and M. luteus, fungicidal against P. catenulatum and F. oxysporum and have a bacteriostatic/fungicidal effect for the other strains. In addition, the E. humile methanolic extract had the greatest α-glucosidase inhibitory effect (IC50 = 0.06 ± 0.29 mg/mL), which is higher than the standard drug, acarbose (IC50 = 0.80 ± 1.81 mg/mL) and the aqueous extract (IC50 = 0.70 ± 0.67 mg/mL). A correlation study between the major phytochemicals and the evaluated activities was investigated. Docking studies evidenced that most of the identified phenolic compounds showed strong interactions into the binding sites of S. aureus tyrosyl-tRNA synthetase and human lysosomal acid-α-glucosidase, confirming their suitable inhibitory effect. In summary, these results may provide rational support to explore the clinical efficacy of E. humile and its secondary metabolites in the treatment of dual diabetes and infections.
Genetic Diversity and Environmental Influence on Yield and Yield-Related Traits of Adzuki Bean (Vigna angularis L.)
Authors: Hu Liangliang , Luo Gaoling , Zhu Xu , Wang Suhua , Wang Lixia , Cheng Xuzhen , Chen Honglin
Published: April 2022

Adzuki beans are an important food legume crop in East Asia. A large number of adzuki bean accessions are maintained in the Chinese national seed genebank. A collection of 59 elite cultivars, 389 landraces, and 27 wild adzuki beans were selected and phenotyped extensively for yield and yield-related traits at two different locations (Nanning and Nanyang, China). Ten agronomic and yield-related traits were scored, and the data were subjected to analysis of variance (ANOVA), principal component analysis (PCA), correlation, and cluster analysis. Significant variation was observed for genotypes, locations, and genotype x environment interaction for most traits. Also, there were significant differences in the phenotypes among accessions of different germplasm types. The broad-sense heritability of traits studied ranged from 4.4% to 77.8%. The number of seeds per pod (77.8%), 100-seed weight (68.0%), and number of plant branches (63.9%) had a high heritability. A total of 10 traits were transformed into 3 comprehensive factors by principal component analysis, and the first three principal component factors contributed 72.31% of the total variability. Cluster analysis categorized the 475 adzuki bean accessions into five distinct groups. The results described in this study will be useful for adzuki bean breeders for the development of varieties with high end-use quality.
Molecular Biology, Composition and Physiological Functions of Cuticle Lipids in Fleshy Fruits
Authors: García-Coronado Heriberto , Tafolla-Arellano Julio César , Hernández-Oñate Miguel Ángel , Burgara-Estrella Alexel Jesús , Robles-Parra Jesús Martín , Tiznado-Hernández Martín Ernesto
Published: April 2022

Fleshy fruits represent a valuable resource of economic and nutritional relevance for humanity. The plant cuticle is the external lipid layer covering the nonwoody aerial organs of land plants, and it is the first contact between fruits and the environment. It has been hypothesized that the cuticle plays a role in the development, ripening, quality, resistance to pathogen attack and postharvest shelf life of fleshy fruits. The cuticle’s structure and composition change in response to the fruit’s developmental stage, fruit physiology and different postharvest treatments. This review summarizes current information on the physiology and molecular mechanism of cuticle biosynthesis and composition changes during the development, ripening and postharvest stages of fleshy fruits. A discussion and analysis of studies regarding the relationship between cuticle composition, water loss reduction and maintaining fleshy fruits’ postharvest quality are presented. An overview of the molecular mechanism of cuticle biosynthesis and efforts to elucidate it in fleshy fruits is included. Enhancing our knowledge about cuticle biosynthesis mechanisms and identifying specific transcripts, proteins and lipids related to quality traits in fleshy fruits could contribute to the design of biotechnological strategies to improve the quality and postharvest shelf life of these important fruit crops.
Characterization of Zanthoxylum rhoifolium (Sapindales: Rutaceae) Essential Oil Nanospheres and Insecticidal Effects to Bemisia tabaci (Sternorrhyncha: Aleyrodidae)
Authors: Pereira Karla de Castro , Quintela Eliane Dias , do Nascimento Vinicius A. , da Silva Daniel José , Rocha Dannilo V. M. , Silva José Francisco A. , Arthurs Steven P. , Forim Moacir Rossi , Silva Fabiano Guimarães , Cazal Cristiane de Melo
Published: April 2022

Encapsulation via nanotechnology offers a potential method to overcome limited thermal and photo-stability of botanical pesticides. In this study, nanospheres of essential oils (NSEO) derived from Zanthoxylum rhoifolium Lam. fruit were characterized and evaluated for their photostability and insecticidal activity against Bemisia tabaci. Three major compounds of Z. rhoifolium fruits were detected by CG-MS: β-phellandrene (76.8%), β-myrcene (9.6%), and germacrene D (8.3%). The nanoprecipitation method was used to obtain homogeneous spherical NSEO, with ≥98% encapsulation efficiency. Tests with UV/Vis spectrophotometry showed significantly reduced photodegradation from exposed NSEO samples when compared with essential oil (EO) controls. Whitefly screenhouses bioassays with bean plants treated with 0.25, 0.5, 1 and 1.5% suspensions showed EO treatments in both free and nanoencapsulated forms reduced adult whitefly oviposition by up to 71%. In further tests, applications at 1.5% caused ≥64% mortality of second instar nymphs. When the test was conducted under high temperature and light radiation conditions, the insecticidal effect of NSEO treatments was improved (i.e., 84.3% mortality) when compared to the free form (64.8%). Our results indicate the insecticidal potential of EO-derived from Z. rhoifolium fruits with further formulation as nanospheres providing greater photostability and enhanced insecticidal activity against B. tabaci under adverse environmental conditions.
Constitutive and Adaptive Traits of Environmental Stress Tolerance in the Threatened Halophyte Limonium angustebracteatum Erben (Plumbaginaceae)
Authors: Mir Ricardo , Romero Ignacio , González-Orenga Sara , Ferrer-Gallego P. Pablo , Laguna Emilio , Boscaiu Monica , Oprică Lăcrămioara , Grigore Marius-Nicușor , Vicente Oscar
Published: April 2022

Limonium angustebracteatum is a halophyte endemic to the E and SE Iberian Peninsula with interest in conservation. Salt glands represent an important adaptive trait in recretohalophytes like this and other Limonium species, as they allow the excretion of excess salts, reducing the concentration of toxic ions in foliar tissues. This study included the analysis of the salt gland structure, composed of 12 cells, 4 secretory and 8 accessory. Several anatomical, physiological and biochemical responses to stress were also analysed in adult plants subjected to one month of water stress, complete lack of irrigation, and salt stress, by watering with aqueous solutions of 200, 400, 600 and 800 mM NaCl. Plant growth was inhibited by the severe water deficit and, to a lesser extent, by high NaCl concentrations. A variation in the anatomical structure of the leaves was detected under conditions of salt and water stress; plants from the salt stress treatment showed salt glands sunken between epidermal cells, bordered by very large epidermal cells, whereas in those from the water stress treatment, the epidermal cells were heterogeneous in shape and size. In both, the palisade structure of the leaves was altered. Salt excretion is usually accompanied by the accumulation of salts in the foliar tissue. This was also found in L. angustebracteatum, in which the concentration of all ions analysed was higher in the leaves than in the roots. The increase of K+ in the roots of plants subjected to water stress was also remarkable. The multivariate analysis indicated differences in water and salt stress responses, such as the accumulation of Na and Cl, or proline, but K+ homeostasis played a relevant role in the mechanism of tolerance to both stressful conditions.
The Response to Inoculation with PGPR Plus Orange Peel Amendment on Soybean Is Cultivar and Environment Dependent
Authors: Pacheco da Silva Maria Letícia , Moen Francesco S. , Liles Mark R. , Feng Yuchen , Sanz-Saez Alvaro
Published: April 2022

Plant growth-promoting rhizobacteria (PGPR) effects on plant yield are highly variable under field conditions due to competition with soil microbiota. Previous research determined that many Bacillus velezensis PGPR strains can use pectin as a sole carbon source and that seed inoculation with PGPR plus pectin-rich orange peel (OP) can enhance PGPR-mediated increases in plant growth. Because the previous studies used a single soybean cultivar, the objective of this research was to test the effect of PGPR plus OP inoculation on plant responses in a wide range of soybean cultivars. Preliminary screening with 20 soybean cultivars in the greenhouse showed that the PGPR plus OP produced a positive increase in all plant growth parameters when all cultivar data was averaged. However, when the inoculation response was examined cultivar by cultivar there was a range of cultivar response from a 60% increase in growth parameters to a 12% decrease, pointing to the presence of a cultivar-PGPR specificity. Further greenhouse and field experiments that studied cultivars with contrast responses to synbiotic inoculation revealed that the environment and/or the molecular interactions between the plant and microorganisms may play an important role in plant responsiveness.
Cultivable Fungal Endophytes in Roots, Rhizomes and Leaves of Posidonia oceanica (L.) Delile along the Coast of Sicily, Italy
Authors: Torta Livio , Burruano Santella , Giambra Selene , Conigliaro Gaetano , Piazza Gaia , Mirabile Giulia , Pirrotta Maria , Calvo Roberta , Bellissimo Giancarlo , Calvo Sebastiano , Tomasello Agostino
Published: April 2022

The presence of endophytic fungi in the roots, rhizomes, and leaves of Posidonia oceanica was evaluated in different localities of the Sicilian coast. Samples of roots, rhizomes, and leaves were submitted to isolation techniques, and the obtained fungal colonies were identified by morphological and molecular (rRNA sequencing) analysis. Fungal endophytes occurred mainly in roots and occasionally in rhizomes and leaves. Lulwoana sp. was the most frequent of the isolated taxa, suggesting a strong interaction with the host. In addition, eight other fungal taxa were isolated. In particular, fungi of the genus Ochroconis and family Xylariaceae were identified as endophytes in healthy plants at all sampling stations, whereas Penicillium glabrum was isolated at only one sampling station. Thus, several organs, especially roots of Posidonia oceanica, harbor endophytic fungi, potentially involved in supporting the living host as ascertained for terrestrial plants.
Plant-Insect Interactions
Authors: Badenes-Pérez Francisco Rubén
Published: April 2022

The central part of the study of plant-insect interactions comes from our quest for knowledge on why and how these interactions occur [...]
Quantifying Cardinal Temperatures of Chia (Salvia hispanica L.) Using Non-Linear Regression Models
Authors: Cabrera-Santos Daniel , Ordoñez-Salanueva Cesar A. , Sampayo-Maldonado Salvador , Campos Jorge E. , Orozco-Segovia Alma , Flores-Ortiz Cesar M.
Published: April 2022

Temperature is the main factor that impacts germination and therefore the success of annual crops, such as chia (Salvia hispanica L.), whose seeds are known for their high nutritional value related to its oil. The effect of temperature on germination is related to cardinal-temperature concepts that describe the range of temperature over which seeds of a particular species can germinate. Therefore, in this study, in addition to calculated germinative parameters such as total germination and germination rate of S. hispanica seeds, the effectiveness of non-linear models for estimating the cardinal temperatures of chia seeds was also determined. We observed that germination of S. hispanica occurred in cold to moderate-high temperatures (10–35 °C), having an optimal range between 25 and 35 °C, with the highest GR and t50 at 30 °C. Temperatures higher than 35 °C significantly reduced germination. Output parameters of the different non-linear models showed that the response of chia germination to temperature was best explained by beta models (B). Cardinal temperatures calculated by the B1 model for chia germination were: 2.52 ± 6.82 °C for the base, 30.45 ± 0.32 °C for the optimum, and 48.58 ± 2.93 °C for the ceiling temperature.
Chemical and Molecular Characterization of Wound-Induced Suberization in Poplar (Populus alba × P. tremula) Stem Bark
Authors: Rains Meghan K. , Caron Christine , Regan Sharon , Molina Isabel
Published: April 2022

Upon mechanical damage, plants produce wound responses to protect internal tissues from infections and desiccation. Suberin, a heteropolymer found on the inner face of primary cell walls, is deposited in specific tissues under normal development, enhanced under abiotic stress conditions and synthesized by any tissue upon mechanical damage. Wound-healing suberization of tree bark has been investigated at the anatomical level but very little is known about the molecular mechanisms underlying this important stress response. Here, we investigated a time course of wound-induced suberization in poplar bark. Microscopic changes showed that polyphenolics accumulate 3 days post wounding, with aliphatic suberin deposition observed 5 days post wounding. A wound periderm was formed 9 days post wounding. Chemical analyses of the suberin polyester accumulated during the wound-healing response indicated that suberin monomers increased from 0.25 to 7.98 mg/g DW for days 0 to 28, respectively. Monomer proportions varied across the wound-healing process, with an overall ratio of 2:1 (monomers:glycerol) found across the first 14 days post wounding, with this ratio increasing to 7:2 by day 28. The expression of selected candidate genes of poplar suberin metabolism was investigated using qRT-PCR. Genes queried belonging to lipid polyester and phenylpropanoid metabolism appeared to have redundant functions in native and wound-induced suberization. Our data show that, anatomically, the wounding response in poplar bark is similar to that described in periderms of other species. It also provides novel insight into this process at the chemical and molecular levels, which have not been previously studied in trees.
Novel QTL for Low Seed Cadmium Accumulation in Soybean
Authors: Nissan Nour , Hooker Julia , Pattang Arezo , Charette Martin , Morrison Malcolm , Yu Kangfu , Hou Anfu , Golshani Ashkan , Molnar Stephen J. , Cober Elroy R. , Samanfar Bahram
Published: April 2022

Soybean is a valuable crop, used in animal feed and for human consumption. Selecting soybean cultivars with low seed cadmium (Cd) concentration is important for the purpose of minimizing the transfer of Cd into the human body. To ensure international trade, farmers need to produce soybean that meets the European Union (EU) Cd limit of 0.2 mg kg−1. In this study, we evaluated two populations of recombinant inbred lines (RILs), X5154 and X4050, for seed Cd accumulation. Linkage maps were constructed with 325 and 280 polymorphic simple sequence repeat (SSR) markers, respectively, and used to identify a novel minor quantitative trait locus (QTL) on chromosome 13 in the X4050 population between SSR markers Satt522 and Satt218. Based on a gene ontology search within the QTL region, seven genes were identified as candidates responsible for low seed Cd accumulation, including Glyma.13G308700 and Glyma.13G309100. In addition, we confirmed the known major gene, Cda1, in the X5154 population and developed KASP and CAPS/dCAPS allele-specific markers for efficient marker-assisted breeding for Cda1.
Trends of CO and NO2 Pollutants in Iran during COVID-19 Pandemic Using Timeseries Sentinel-5 Images in Google Earth Engine
Authors: Shami Siavash , Ranjgar Babak , Bian Jinhu , Khoshlahjeh Azar Mahdi , Moghimi Armin , Amani Meisam , Naboureh Amin
Published: April 2022

The first case of COVID-19 in Iran was reported on 19 February 2020, 1 month before the Nowruz holidays coincided with the global pandemic, leading to quarantine and lockdown. Many studies have shown that environmental pollutants were drastically reduced with the spread of this disease and the decline in industrial activities. Among these pollutants, nitrogen dioxide (NO2) and carbon monoxide (CO) are widely caused by anthropogenic and industrial activities. In this study, the changes in these pollutants in Iran and its four metropolises (i.e., Tehran, Mashhad, Isfahan, and Tabriz) in three periods from 11 March to 8 April 2019, 2020, and 2021 were investigated. To this end, timeseries of the Sentinel-5P TROPOMI and in situ data within the Google Earth Engine (GEE) cloud-based platform were employed. It was observed that the results of the NO2 derived from Sentinel-5P were in agreement with the in situ data acquired from ground-based stations (average correlation coefficient = 0.7). Moreover, the results showed that the concentration of NO2 and CO pollutants in 2020 (the first year of the COVID-19 pandemic) was 5% lower than in 2019, indicating the observance of quarantine rules, as well as people’s initial fear of the coronavirus. Contrarily, these pollutants in 2021 (the second year of the COVID-19 pandemic) were higher than those in 2020 by 5%, which could have been due to high vehicle traffic and a lack of serious policy- and law-making by the government to ban urban and interurban traffic. These findings are essential criteria that might be used to guide future manufacturing logistics, traffic planning and management, and environmental sustainability policies and plans. Furthermore, using the COVID-19 scenario and free satellite-derived data, it is now possible to investigate how harmful gas emissions influence air quality. These findings may also be helpful in making future strategic decisions on how to cope with the virus spread and lessen its negative social and economic consequences.
Towards 4D Printing of Very Soft Heterogeneous Magnetoactive Layers for Morphing Surface Applications via Liquid Additive Manufacturing
Authors: Brusa da Costa Linn Lucas , Danas Kostas , Bodelot Laurence
Published: April 2022

This work explores the use of liquid additive manufacturing (LAM) to print heterogeneous magnetoactive layers. A general method is proposed where, by studying the printing of pure silicone lines, the successful printing of closed shapes, open shapes, and a combination thereof, can be achieved while accounting for the continuous deposition that is specific to LAM. The results of this characterization are subsequently exploited for the printing of a heterogeneous layer composed of four magnetoactive discs embedded in a pure silicone square. Such a layer, when affixed to a softer silicone substrate, yields a system that produces truly three-dimensional surface patterns upon application of a magnetic field. Hence, this work demonstrates that LAM is a promising approach for the rapid 4D printing of morphing surfaces exhibiting 3D surface patterns that can be actuated remotely and reversibly via a magnetic field. Such heterogenous layers have a wide range of applications, ranging from haptics to camouflage to differential cell growth.
Synthesis of a New Chelating Iminophosphorane Derivative (Phosphazene) for U(VI) Recovery
Authors: Atia Bahig M. , Sakr Ahmed K. , Gado Mohamed A. , El-Gendy Hassan S. , Abdelazeem Nagwa M. , El-Sheikh Enass M. , Hanfi Mohamed Y. , Sayyed M. I. , Al-Otaibi Jamelah S. , Cheira Mohamed F.
Published: April 2022

A new synthetic chelating N–hydroxy–N–trioctyl iminophosphorane (HTIP) was prepared through the reaction of trioctylphosphine oxide (TOPO) with N–hydroxylamine hydrochloride in the presence of a Lewis acid (AlCl3). Specifications for the HTIP chelating ligand were successfully determined using many analytical techniques, 13C–NMR, 1H–NMR, FTIR, EDX, and GC–MS analyses, which assured a reasonable synthesis of the HTIP ligand. The ability of HTIP to retain U(VI) ions was investigated. The optimum experimental factors, pH value, experimental time, initial U(VI) ion concentration, HTIP dosage, ambient temperature, and eluents, were attained with solvent extraction techniques. The utmost retention capacity of HTIP/CHCl3 was 247.5 mg/g; it was achieved at pH = 3.0, 25 °C, with 30 min of shaking and 0.99 × 10−3 mol/L. From the stoichiometric calculations, approximately 1.5 hydrogen atoms are released during the extraction at pH 3.0, and 4.0 moles of HTIP ligand were responsible for chelation of one mole of uranyl ions. According to kinetic studies, the pseudo–first order model accurately predicted the kinetics of U(VI) extraction by HTIP ligand with a retention power of 245.47 mg/g. The thermodynamic parameters ΔS°, ΔH°, and ΔG° were also calculated; the extraction process was predicted as an exothermic, spontaneous, and advantageous extraction at low temperatures. As the temperature increased, the value of ∆G° increased. The elution of uranium ions from the loaded HTIP/CHCl3 was achieved using 2.0 mol of H2SO4 with a 99.0% efficiency rate. Finally, the extended variables were used to obtain a uranium concentrate (Na2U2O7, Y.C) with a uranium grade of 69.93% and purity of 93.24%.
Characterization and Modeling of Free Volume and Ionic Conduction in Multiblock Copolymer Proton Exchange Membranes
Authors: Gomaa Mahmoud Mohammed , Sánchez-Ramos Arturo , Ureña Nieves , Pérez-Prior María Teresa , Levenfeld Belen , García-Salaberri Pablo A. , Elsharkawy Mohamed Rabeh Mohamed
Published: April 2022

Free volume plays a key role on transport in proton exchange membranes (PEMs), including ionic conduction, species permeation, and diffusion. Positron annihilation lifetime spectroscopy and electrochemical impedance spectroscopy are used to characterize the pore size distribution and ionic conductivity of synthesized PEMs from polysulfone/polyphenylsulfone multiblock copolymers with different degrees of sulfonation (SPES). The experimental data are combined with a bundle-of-tubes model at the cluster-network scale to examine water uptake and proton conduction. The results show that the free pore size changes little with temperature in agreement with the good thermo-mechanical properties of SPES. However, the free volume is significantly lower than that of Nafion®, leading to lower ionic conductivity. This is explained by the reduction of the bulk space available for proton transfer where the activation free energy is lower, as well as an increase in the tortuosity of the ionic network.
Organic Brake Friction Composite Materials: Impact of Mixing Duration on Microstructure, Properties, Tribological Behavior and Wear Resistance
Authors: Makni Fatma , Cristol Anne-Lise , Elleuch Riadh , Desplanques Yannick
Published: April 2022

The lack of knowledge on the link between the manufacturing process and performance constitutes a major issue in brake lining development. The manufacturing process of organic brake friction composite materials includes several steps (mixing, preforming, hot molding and post-curing), which define their final microstructure, properties and performances. This study focuses on the effect of mixing duration on the microstructure, properties and tribological behavior of organic friction composite materials. The adopted methodology is based on simplified formulations effective in limiting synergistic effects by reducing the number and size distribution of constituents. Two simplified materials are here developed according to the mixing duration of the constituent introduction sequence. The microstructural characteristics are studied using 2D and 3D analyses, and then correlated with the thermophysical and mechanical properties. Wear mechanisms and tribological behavior are studied in relation to the microstructure and properties of the materials. The results show the effect of mixing duration as regards particle distribution and fiber arrangement. The distribution and size of fiber entanglements contribute to the formation of carbonaceous particle clusters, which create bulk bridges improving thermal conductivity. Moreover, the arrangement of rock fibers affects density, porosity and thermo-physical properties. In addition, the mixing disrupts the cohesion of fiber bundles with the matrix, affecting compressive modulus and wear behavior. This microstructural defect also fosters abundant third-body source flow, which disturbs the tribological circuit and behavior. Porosities induced by fiber entanglements, having a large and irregular size and distribution on the frictional surface, result in low wear resistance and alter the frictional stability.
Preparation and Characterization of Yellow Peach Peel/Sodium Alginate/Glycerol Antioxidant Film Applicable for Oil Package
Authors: Lu Xiaomeng , Chen Zhizhou , Ma Qianyun , Mu Jianlou , Li Xiaoyuan , Liu Han
Published: April 2022

This work was dedicated to improving the utilization rate of yellow peach peel (YPP), with the addition of sodium alginate (SA) and glycerol (G) to prepare a biodegradable antioxidant film. First, the formulation of the film was optimized via response surface methodology (RSM) combined with the multi-index comprehensive evaluation method, considering physical properties including tensile strength (TS), elongation at break (E%), water solution (WS) and light transmittance (T). The RSM results displayed the best process condition was 2.50% of YPP, 0.60% SA and 0.80% of G (based on water) and compared with pure YPP film and YPP-SA film, the optimized (YPP-SA-G) film presented excellent properties with TS of 21.52 MPa, E of 24.8%, T of 21.56% on 600 nm, and WS of 41.61%, the comprehensive evaluation score of the film was 0.700. Furthermore, the films were characterized by Fourier transform infrared (FTIR) spectroscopy, scanning electron microscope (SEM), X-ray diffraction (XRD), and thermogravimetric analysis (TGA). FTIR analysis showed the main interaction of hydrogen between YPP, SA and G make the film has excellent compatibility, and the SEM images displayed that the film was dense and compacted with a little roughness. In addition, the optimized film had excellent thermal stability, suggested by TGA and XRD showed that the film’s crystal structure has been changed significantly when the SA and G were mixed in. The TPC and the ability of DPPH radical scavenging of the YPP-SA-G film was 17.68 mg·g−1 of GAE and 18.65%, then potential packaging applications were evaluated using soybean oil and the YPP-SA-G antioxidant film significantly decreased peroxide value (POV) to delay oil oxidation during storage. Therefore, the YPP-SA-G film is expected to provide a new theoretical basis for the use of food processing by-products and the packaging industry.
Effect of Sunlight on the Change in Color of Unsteamed and Steamed Beech Wood with Water Steam
Authors: Dudiak Michal , Dzurenda Ladislav , Kučerová Viera
Published: April 2022

This paper presents the differences in the color changes of unsteamed and steamed beech wood (Fagus sylvatica L.) caused by long-term exposure to sunlight on the surface of wood in interiors for 36 months. The light white-gray color of the yellow tinge of native beech wood darkened under the influence of sunlight, and the wood took on a pale brown color of yellow tinge. The degree of darkening and browning is quantified by the value of the total color difference ∆E* = 13.0. The deep brown-red color of steamed beech under the influence of sunlight during the exposure brightened, and the surface of the wood took on a pale brown hue. The degree of lightening of the color of steamed beech wood in the color space CIE L*a*b* is quantified by the value of the total color difference ∆E* = 7.1. A comparison of the color changes of unsteamed and steamed beech wood through the total color difference ∆E* due to daylight shows that the surface of steamed beech wood shows 52.2% smaller changes than unsteamed beech wood. The lower value of the total color difference of steamed beech wood indicates the fact that steaming of beech wood with saturated water steam has a positive effect on the color stability and partial resistance of steamed beech wood to the initiation of photochemical reactions induced by UV–VIS wavelengths of solar radiation. Spectra ATR-FTIR analyses declare the influence of UV–VIS components of solar radiation on unsteamed and steamed beech wood and confirm the higher color stability of steamed beech wood.
Preparation and Characterizations of PSS/PDADMAC Polyelectrolyte Complex Hydrogel
Authors: Sungoradee Thichakorn , Srikulkit Kawee
Published: April 2022

Polyelectrolyte complex (PEC) hydrogel, formed via physically electrostatic crosslinks between polyanion and polycation, is an interesting hydrogel in terms of its nontoxicity and solvent-free technique. In this work, poly (sodium 4-styrenesulfonate) (PSS)/poly (diallyl dimethyl ammonium chloride) (PDADMAC) complex hydrogels were prepared. Firstly, the PSS/PDADMAC complex aggregates using various PSS/PDADMAC mole fractions that were prepared in the presence of NaCl solution. Then, the aggregates were resolubilized under stirring at 70 °C for 2 h to obtain a homogeneous PEC solution. Finally, the PEC solution was dialyzed using a dialysis membrane with 3500 molecular cut-off for 1 day. The dialysis bath was changed every interval period of 2 h to control the rate of reversible electrostatic interaction, resulting in the homogenous PEC hydrogel with porous morphology as revealed by SEM and BET investigations. The dimensional stability and viscoelasticity of the PEC hydrogel was studied by DMA experiment, which showed the viscoelastic behavior at a compressive force ranging from 0 to 0.1 N. Finally, PSS/PDADMAC hydrogels showed a high water absorbency property and excellent affinity to textile anionic dyes.
Green Corrosion Inhibition on Carbon-Fibre-Reinforced Aluminium Laminate in NaCl Using Aerva Lanata Flower Extract
Authors: Hynes Navasingh Rajesh Jesudoss , Vignesh Nagarajan Jawahar , Barile Claudia , Velu Pitchumani Shenbaga , Baskaran Thangagiri , Jappes Jebas Thangiah Winowlin , Al-Khashman Omar Ali , Brykov Michail , Ene Antoaneta
Published: April 2022

Aluminium-based fibre–metal laminates are lucrative candidates for aerospace manufacturers since they are lightweight and high-strength materials. The flower extract of aerva lanata was studied in order to prevent the effect of corrosion on the aluminium-based fibre–metal laminates (FMLs) in basic media. It is considered an eco-friendly corrosion inhibitor using natural sources. Its flower species belong to the Amaranthaceae family. The results of the Fourier-transform infrared spectroscopy (FTIR) show that this flower extract includes organic compounds such as aromatic links, heteroatoms, and oxygen, which can be used as an organic corrosion inhibitor in an acidic environment. The effectiveness of the aerva-lanata flower behaviour in acting as an inhibitor of the corrosion process of FMLs was studied in 3.5% NaCl solution. The inhibition efficiency was calculated within a range of concentration of the inhibitor at room temperature, using the weight-loss method, potentiodynamic polarization measurements and electrochemical-impedance spectroscopy (EIS). The results indicate a characterization of about 87.02% in the presence of 600 ppm of inhibitor. The Tafel curve in the polarization experiments shows an inhibition efficiency of 88%. The inhibition mechanism was the absorption on the FML surface, and its absorption was observed with the aid of the Langmuir adsorption isotherm. This complex protective film occupies a larger surface area on the surface of the FML. Hence, by restricting the surface of the metallic layer from the corrosive medium, the charge and ion switch at the FML surface is reduced, thereby increasing the corrosion resistance.
Flame-Retarding Properties of Injected and 3D-Printed Intumescent Bio-Based PLA Composites: The Influence of Brønsted and Lewis Acidity of Montmorillonite
Authors: Martins Raíssa Carvalho , Ribeiro Simone Pereira da Silva , Rezende Michelle Jakeline Cunha , Nascimento Regina Sandra Veiga , Nascimento Marco Antonio Chaer , Batistella Marcos , Lopez-Cuesta José-Marie
Published: April 2022

The influence of processing intumescent bio-based poly(lactic acid) (PLA) composites by injection and fused filament fabrication (FFF) was evaluated. A raw (ANa) and two acidic-activated (AH2 and AH5) montmorillonites were added to the intumescent formulation, composed by lignin and ammonium polyphosphate, in order to evaluate the influence of the strength and the nature (Brønsted or Lewis) of their acidic sites on the fire behavior of the composites. The thermal stability and the volatile thermal degradation products of the composites were assessed. The injected and 3D-printed composites were submitted to cone calorimeter (CC), limit oxygen index (LOI), and UL-94 flammability tests. A similar tendency was observed for the injected and 3D-printed samples. The high density of strong Lewis sites in AH2 showed to be detrimental to the fire-retarding properties. For the CC test, the addition of the intumescent composite reduced the peak of heat released (pHRR) in approximately 49% when compared to neat PLA, while the composites containing ANa and AH5 presented a reduction of at least 54%. However, the addition of AH2 caused a pHRR reduction of around 47%, close to the one of the composite without clay (49%). In the LOI tests, the composites containing ANa and AH5 achieved the best results: 39% and 35%, respectively, for the injected samples, and 35 and 38% for the 3D-printed samples. For the composite containing AH2 the LOI values were 34% and 32% for injected and 3D-printed samples, respectively. Overall, the best performance in the flammability tests was achieved by the composites containing clays with only weak and moderate strength acidic sites (ANa and AH5).
Microwave-Assisted Synthesis of Azo Disperse Dyes for Dyeing Polyester Fabrics: Our Contributions over the Past Decade
Authors: Al-Etaibi Alya M. , El-Apasery Morsy Ahmed
Published: April 2022

Organic reactions utilizing the microwave strategy have become able to conduct in shorter times, with higher yields, and are compatible with green chemistry protocols. In recent years, microwave technologies as an effective agent in organic synthesis have been successful utilized in textile industries and for the synthesis of dyes, especially disperse dyes. Herein, we present our contributions over the past decade through the use of microwave technology not only in the synthesis of new biologically active organic compounds and disperse dyes, but also the use of this effective, environmentally friendly technology in dyeing polyester fabrics as an alternative to conventional heating methods. We also demonstrate both the fastness properties and biological activities of the newly prepared compounds. In addition, we present the treatment of dyeing baths by reusing them again in the dyeing process, using microwave energy to achieve this goal, and this has environmentally friendly dimensions. Some of the possible utilizations of microwave irradiation have been presented in many different fields of chemistry. We recommend relying on this effective and environmentally safe technology instead of relying on conventional methods that take a lot of time, give low yields, and may have a negative impact on the environment.
Free Radical Copolymerization of Diallylamine and Itaconic Acid for the Synthesis of Chitosan Base Superabsorbent
Authors: Al-Mughrabi Wafa , Al-dossary Abeer O. , Abdel-Naby Abir
Published: April 2022

Copolymerization of diallylamine (DAA) and itaconic acid (IA) was synthesized using benzoyl peroxide as a free radical initiator, in dioxane as the solvent. The composition of the copolymer was determined by the nitrogen content using Edx. The solubility of the copolymer was also investigated. The water solubility of the synthesized copolymer depends on the comonomers’ ratio. The structure of the copolymer was confirmed by 13C-NMR spectroscopy. To increase the water insolubility of the copolymers, and keep their hydrophilicity, the copolymer was allowed to react with chitosan to form a superabsorbent polymeric material (SP). The structure of the synthesized superabsorbent was confirmed using 13C-NMR spectroscopy. The thermal property of the (SP) was also investigated by TGA. The investigation of the chitosan-based superabsorbent, as water-retaining agents, was studied. The results revealed that the superabsorbent polymers exhibited a good swelling ability and salt tolerance.
Diblock Copolymers Containing Titanium-Hybridized Polyhedral Oligomeric Silsesquioxane Used as a Macromolecular Flame Retardant for Epoxy Resin
Authors: Zhou Ruirui , Lin Lijie , Zeng Birong , Yi Xindan , Huang Chenyu , Du Kunpeng , Liu Xiaohui , Xu Yiting , Yuan Conghui , Dai Lizong
Published: April 2022

In this paper, the 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO)-containing diblock copolymer poly[(p-hydroxybenzaldehyde methacrylate)m-b-(2-((6-oxidodibenzo[c,e][1,2]oxaphosphinin-6-yl)oxy)ethyl methacrylate)n] (abbrev. poly(HAMAm-b-HEPOMAn)) was synthesized by reversible addition fragmentation chain transfer (RAFT) polymerization. When it was continued to react with titanium-hybridized aminopropyl-polyhedral oligomeric silsesquioxane (Ti-POSS) through a Schiff-base reaction, new grafted copolymers poly[(Ti-POSS-HAMA)m-b-HEPOMAn] (abbrev. PolyTi) were obtained. Then, they were used as macromolecular flame retardant to modify epoxy resin materials. The thermal, flame retardant and mechanical properties of the prepared EP/PolyTi composites were tested by TGA, DSC, LOI, UL-94, SEM, Raman, DMA, etc. The migration of phosphorus moiety from epoxy resin composites was analyzed by immersing the composites into ethanol/H2O solution and recording the extraction solution by UV-Vis spectroscopy. The results showed that the added PolyTi enhanced the glass transition temperature, the carbon residue, the graphitization of char, LOI, and mechanical properties of the EP/PolyTi composites when compared to pure cured EP. Furthermore, the phosphorus moieties were more likely to migrate from EP/DOPO composites than that from EP/PolyTi composites. Obviously, compared with small molecular flame retardant modified EP, the macromolecular flame retardant modified EP/PolyTi composites exhibited better thermal stability, flame retardancy, and resistance to migration.
Surface Modification of Sponge-like Porous Poly(3-hydroxybutyrate-co-4-hydroxybutyrate)/Gelatine Blend Scaffolds for Potential Biomedical Applications
Authors: Azuraini Mat Junoh , Vigneswari Sevakumaran , Huong Kai-Hee , Khairul Wan M. , H.P.S. Abdul Khalil , Ramakrishna Seeram , Amirul Al-Ashraf Abdullah
Published: April 2022

In this study, we described the preparation of sponge-like porous scaffolds that are feasible for medical applications. A porous structure provides a good microenvironment for cell attachment and proliferation. In this study, a biocompatible PHA, poly(3-hydroxybutyrate-co-4-hydroxybutyrate) was blended with gelatine to improve the copolymer’s hydrophilicity, while structural porosity was introduced into the scaffold via a combination of solvent casting and freeze-drying techniques. Scanning electron microscopy results revealed that the blended scaffolds exhibited higher porosity when the 4HB compositions of P(3HB-co-4HB) ranged from 27 mol% to 50 mol%, but porosity decreased with a high 4HB monomer composition of 82 mol%. The pore size, water absorption capacity, and cell proliferation assay results showed significant improvement after the final weight of blend scaffolds was reduced by half from the initial 0.79 g to 0.4 g. The pore size of 0.79g-(P27mol%G10) increased three-fold while the water absorption capacity of 0.4g-(P50mol%G10) increased to 325%. Meanwhile, the cell proliferation and attachment of 0.4g-(P50mol%G10) and 0.4g-(P82mol%G7.5) increased as compared to the initial seeding number. Based on the overall data obtained, we can conclude that the introduction of a small amount of gelatine into P(3HB-co-4HB) improved the physical and biological properties of blend scaffolds, and the 0.4g-(P50mol%G10) shows great potential for medical applications considering its unique structure and properties.