bluuebunny/crossref_metadata_2025 huggingface dataset:
Fluorescent Bulk Waveguide Sensor in Porous Glass: Concept, Fabrication, and Testing
Authors: Lijing Zhong , Zakoldaev Roman A. , Sergeev Maksim M. , Veiko Vadim P.
Published: October 2020

In this work, we suggest the new concept of sensing elements—bulk waveguides (BWGs) fabricated by the laser direct writing technique inside porous glass (PG). BWGs in nanoporous materials are promising to be applied in the photonics and sensors industries. Such light-guiding components interrogate the internal conditions of nanoporous materials and are able to detect chemical or physical reactions occurring inside nanopores especially with small molecules, which represent a separate class for sensing technologies. After the writing step, PG plates are impregnated with the indicator—rhodamine 6G—which penetrates through the nanoporous framework to the BWG cladding. The experimental investigation proved the concept by measuring the spectral characteristics of an output signal. We have demonstrated that the BWG is sensitive to ethanol molecules captured by the nanoporous framework. The sensitivity of the peak shift in the fluorescence spectrum to the refractive index of the solution is quantified as 6250 ± 150 nm/RIU.
Catalytic Performances of Cu/MCM-22 Zeolites with Different Cu Loadings in NH3-SCR
Authors: Chen Jialing , Peng Gang , Liang Tingyu , Zhang Wenbo , Zheng Wei , Zhao Haoran , Guo Li , Wu Xiaoqin
Published: October 2020

The NH3-SCR activities and hydrothermal stabilities of five xCu/MCM-22 zeolites with different Cu loadings (x = 2–10 wt%) prepared by incipient wetness impregnation method were systematically investigated. The physicochemical properties of xCu/MCM-22 zeolites were analyzed by XRD, nitrogen physisorption, ICP-AES, SEM, NH3-TPD, UV-vis, H2-TPR and XPS experiments. The Cu species existing in xCu/MCM-22 are mainly isolated Cu2+, CuOx and unreducible copper species. The concentrations of both isolated Cu2+ and CuOx species in xCu/MCM-22 increase with Cu contents, but the increment of CuOx species is more distinct, especially in high Cu loadings (>4 wt%). NH3-SCR experimental results demonstrated that the activity of xCu/MCM-22 is sensitive to Cu content at low Cu loadings (≤4 wt%). When the Cu loading exceeds 4 wt%, the NH3-SCR activity of xCu/MCM-22 is irrelevant to Cu content due to the severe pore blockage effects caused by aggregated CuOx species. Among the five xCu/MCM-22 zeolites, 4Cu/MCM-22 with moderate Cu content has the best NH3-SCR performance, which displays higher than 80% NOx conversions in a wide temperature window (160–430 °C). Furthermore, the hydrothermal aging experiments (xCu/MCM-22 was treated at 750 °C for 10 h under 10% water vapor atmosphere) illustrated that all the xCu/MCM-22 zeolites exhibit high hydrothermal stability in NH3-SCR reactions.
Ganoderma lucidum Extract Reduces Insulin Resistance by Enhancing AMPK Activation in High-Fat Diet-Induced Obese Mice
Authors: Lee Hyeon A , Cho Jae-Han , Afinanisa Qonita , An Gi-Hong , Han Jae-Gu , Kang Hyo Jeung , Choi Seong Ho , Seong Hyun-A
Published: October 2020

Ganoderma lucidum is used widely in oriental medicine to treat obesity and metabolic diseases. Bioactive substances extracted from G. lucidum have been shown to ameliorate dyslipidemia, insulin resistance, and type 2 diabetes in mice via multiple 5′ AMP-activated protein kinase (AMPK)-mediated mechanisms; however, further studies are required to elucidate the anti-obesity effects of G. lucidum in vivo. In this study, we demonstrated that 3% G. lucidum extract powder (GEP) can be used to prevent obesity and insulin resistance in a mouse model. C57BL/6 mice were provided with a normal diet (ND) or a high-fat diet (HFD) supplemented with 1, 3, or 5% GEP for 12 weeks and the effect of GEP on body weight, liver, adipose tissue, adipokines, insulin and glucose tolerance (ITT and GTT), glucose uptake, glucose-metabolism related proteins, and lipogenesis related genes was examined. GEP administration was found to reduce weight gain in the liver and fat tissues of the mice. In addition, serum parameters were significantly lower in the 3% and 5% GEP mice groups than in those fed a HFD alone, whereas adiponectin levels were significantly higher. We also observed that GEP improved glucose metabolism, reduced lipid accumulation in the liver, and reduced adipocyte size. These effects may have been mediated by enhanced AMPK activation, which attenuated the transcription and translation of lipogenic genes such as fatty acid synthase (FAS), stearoyl-CoA desaturase 1 (SCD1), and sterol regulatory element-binding protein-1c (SREBP1c). Moreover, AMP-activated protein kinase (AMPK) activation increased acetyl-CoA carboxylase (ACC), insulin receptor (IR), IR substrate 1 (IRS1), and Akt protein expression and activation, as well as glucose transporter type 1/4 (GLUT1/4) protein production, thereby improving insulin sensitivity and glucose metabolism. Together, these findings demonstrate that G. lucidum may effectively prevent obesity and suppress obesity-induced insulin resistance via AMPK activation.
The Impact of Micronutrient Fortified Foods on Cognitive Functioning among Low-Income Children: A Pilot and Feasibility Study
Authors: Cohen Juliana F. W. , Sagar Kelly , Dahlgren Mary Kathryn , Kurdziel Laura B. F. , Gruber Staci A.
Published: October 2020

Brain development continues throughout childhood and requires micronutrients for optimal maturation, but studies have typically examined only a limited number of micronutrients and there has been inconsistent use of validated cognitive measures. This study evaluated the impact of providing low-income children with a daily fortified meal (570 kcal) in the form of a bar and shake containing >75% of the FDA Daily Values for all essential vitamins and minerals, as well as macronutrients (e.g., omega-3 and omega-6 fatty acids and protein), in an afterschool care setting (instead of the usual meal provided) on cognitive functioning. Students aged 8–12 were randomly assigned to intervention (n = 19) or control (n = 16) meals. Students completed the Stroop Color Word Task, Trail Making Test, and Conner’s Continuous Performance Task (CPT) at baseline and 3 months post-intervention. Differences in cognitive scores were examined using 2 × 2 mixed model ANOVAs (Stroop and CPT) and ANCOVAs (Trail Making Test). Significant main effects of time indicated improvements in both intervention and control groups, but there were no significant main effects of group or group*time interactions. When the amount of meal consumed was examined, most results became non-significant, suggesting that overall meal consumption significantly impacted the observed results. Overall, this pilot study suggests that there may be limited additional benefits to short-term consumption of micronutrient fortified meals among low-income children in an afterschool care setting, and potential benefits observed may be directly related to the amount of food consumed.
Publisher’s Note: Continued Publication of Pediatric Reports by MDPI
Authors: Vazquez Franck , Vicario Unai , Lin Shu-Kun
Published: October 2020

Pediatric Reports was launched in 2009 and it has been published over the past eleven years by PAGEPress Publications [...]
A New Variant Mutation in SKIV2L Gene in Case of Trichohepatoenteric Syndrome
Authors: Taher Ziad A. , Alzahrani Saeed , Alsaghir Abdullah , Nouh Faris , Alshumrani Mesbah
Published: October 2020

Trichohepatoenteric syndrome is an autosomal recessive genetic disease with an estimated prevalence of 1:100,000. The mutation of the disease is placed either in SKIV2L or TTC37 genes. The onset of presentation is variable, but symptoms usually start with intractable diarrhea associated with woolly hair abnormality, immune dysfunction, and sometimes hepatic abnormality. This case is of a 10-month-old girl who was born at 37 + 2 weeks due to symmetrical intrauterine growth restriction (IUGR), with a low birth weight (1320 g). It was noticed during her stay in NICU that she had excessive diarrhea on day 8. Gastroenterology suggested starting an extensively-hydrolyzed formula, but no improvement noticed. The multidisciplinary teams decided to order whole-exome sequencing analysis after excluding diarrhea causes. The analysis detected a new variant mutation (c.1297C > T) p. (Arg433Cys). To our knowledge, this is the first time detected in a homozygous state in the SKIV2L gene, as this variant mutation has not been described in any previous literature. Our case was managed mainly by total parenteral nutrition. The patient responded to the treatment appropriately.
Inhibitory Effect of AB-PINACA, Indazole Carboxamide Synthetic Cannabinoid, on Human Major Drug-Metabolizing Enzymes and Transporters
Authors: Park Eun Jeong , Park Ria , Jeon Ji-Hyeon , Cho Yong-Yeon , Lee Joo Young , Kang Han Chang , Song Im-Sook , Lee Hye Suk
Published: October 2020

Indazole carboxamide synthetic cannabinoid, AB-PINACA, has been placed into Schedule I of the Controlled Substances Act by the US Drug Enforcement Administration since 2015. Despite the possibility of AB-PINACA exposure in drug abusers, the interactions between AB-PINACA and drug-metabolizing enzymes and transporters that play crucial roles in the pharmacokinetics and efficacy of various substrate drugs have not been investigated. This study was performed to investigate the inhibitory effects of AB-PINACA on eight clinically important human major cytochrome P450s (CYPs) and six uridine 5′-diphospho-glucuronosyltransferases (UGT) in human liver microsomes and the activities of six solute carrier transporters and two efflux transporters in transporter-overexpressing cells. AB-PINACA reversibly inhibited the metabolic activities of CYP2C8 (Ki, 16.9 µM), CYP2C9 (Ki, 6.7 µM), and CYP2C19 (Ki, 16.1 µM) and the transport activity of OAT3 (Ki, 8.3 µM). It exhibited time-dependent inhibition on CYP3A4 (Ki, 17.6 µM; kinact, 0.04047 min−1). Other metabolizing enzymes and transporters such as CYP1A2, CYP2A6, CYP2B6, CYP2D6, UGT1A1, UGT1A3, UGT1A4, UGT1A6, UGT1A9, UGT2B7, OAT1, OATP1B1, OATP1B3, OCT1, OCT2, P-glycoprotein, and BCRP, exhibited only weak interactions with AB-PINACA. These data suggest that AB-PINACA can cause drug-drug interactions with CYP3A4 substrates but that the significance of drug interactions between AB-PINACA and CYP2C8, CYP2C9, CYP2C19, or OAT3 substrates should be interpreted carefully.
Understanding the Seeding Pulse-Induced Optical Amplification in

N
2
+

Pumped by 800 NM Femtosecond Laser Pulses
Authors: Fan Zhengquan , Zhang Xiang , Lu Qi , Luo Yu , Liang Qingqing , Yuan Luqi , Zhang Zhedong , Liu Yi
Published: October 2020

Nitrogen ions pumped by intense femtosecond laser pulses present an optical gain at 391.4 nm, evident by energy amplification of an injected resonant seeding pulse. We report a time-resolved measurement of the amplification process with seeding pulses having varying intensities. It is found that the amplification factor depends on the intensity of the seeding pulse and the effective temporal window for the optical gain becomes longer by applying more intense seeding pulses. These two features are in sharp contrast with classic pump-probe experiments, pinpointing the crucial role of macroscopic coherence and its dynamics during the lasing process. We further measure the temporal profile of the amplified emission for seeding pulse injected at different time delays. A complicated temporal behavior is observed, which highlights the nature of the superfluorescence.
A Method for Simultaneous Polishing and Hydrophobization of Polycarbonate for Microfluidic Applications
Authors: Ogończyk Dominika , Jankowski Paweł , Garstecki Piotr
Published: October 2020

Here we present a new methodology for chemical polishing of microchannels in polycarbonate (PC). Tuning the time of exposition and the concentration of ammonia, the roughness arising from the micromachining process can be significantly reduced or completely removed while preserving the structure of microchannels. Besides smoothing out the surface, our method modifies the wettability of the surface, rendering it hydrophobic. The method increases the optical transparency of microchannels and eliminates undesired effects in two-phase microfluidic systems, including wetting by aqueous solutions and cross-contamination between aqueous droplets that could otherwise shed satellites via pinning.
Sodium Lignosulfonate Modified Polystyrene for the Removal of Phenol from Wastewater
Authors: Yang Keyan , Xing Jingchen , Chang Jianmin , Gu Fei , Li Zheng , Huang Zhenhua , Cai Liping
Published: October 2020

An eco-friendly and novel water treatment material was synthesized using sodium lignosulfonate modified polystyrene (SLPS), which can be used to eliminate phenols in aqueous solution. SLPS was characterized by BET, FTIR, SEM, and EDS. The effect of the initial pH value, phenol content, adsorption time, and temperature on the absorbability of phenol in SLPS was investigated through adsorption experiments. It was found that SLPS could efficiently adsorb phenol in aqueous solution at a pH value of about 7. The test results revealed that the kinetic adsorption and isotherm adsorption could be successfully described using the pseudo second-order and Langmuir models, respectively. It was illustrated that the phenol adsorption on SLPS was dominated by chemisorption and belonged to monolayer adsorption. The max. phenol adsorption value of SLPS was 31.08 mg/g at 30 °C. Therefore, SLPS displayed a great potential for eliminating phenol from polluted water as a kind of novel and effective adsorbent.
Effect of Chlorophyll Hybrid Nanopigments from Broccoli Waste on Thermomechanical and Colour Behaviour of Polyester-Based Bionanocomposites
Authors: Micó-Vicent Bàrbara , Ramos Marina , Luzi Francesca , Dominici Franco , Viqueira Valentín , Torre Luigi , Jiménez Alfonso , Puglia Debora , Garrigós María Carmen
Published: October 2020

Natural dyes obtained from agro-food waste can be considered promising substitutes of synthetic dyes to be used in several applications. With this aim, in the present work, we studied the use of chlorophyll dye (CD) extracted from broccoli waste to obtain hybrid nanopigments based on calcined hydrotalcite (HT) and montmorillonite (MMT) nanoclays. The synthesized chlorophyll hybrid nanopigments (CDNPs), optimized by using statistical designed experiments, were melt-extruded with a polyester-based matrix (INZEA) at 7 wt% loading. Mechanical, thermal, structural, morphological and colour properties of the obtained bionanocomposites were evaluated. The obtained results evidenced that the maximum CD adsorption into HT was obtained when adding 5 wt% of surfactant (sodium dodecyl sulphate) without using any biomordant and coupling agent, while the optimal conditions for MMT were achieved without adding any of the studied modifiers. In both cases, an improvement in CD thermal stability was observed by its incorporation in the nanoclays, able to protect chlorophyll degradation. The addition of MMT to INZEA resulted in large ΔE* values compared to HT incorporation, showing bionanocomposite green/yellow tones as a consequence of the CDNPs addition. The results obtained by XRD and TEM revealed a partially intercalated/exfoliated structure for INZEA-based bionanocomposites, due to the presence of an inorganic filler in the formulation of the commercial product, which was also confirmed by TGA analysis. CDNPs showed a reinforcement effect due to the presence of the hybrid nanopigments and up to 26% improvement in Young’s modulus compared to neat INZEA. Finally, the incorporation of CDNPs induced a decrease in thermal stability as well as limited effect in the melting/crystallization behaviour of the INZEA matrix. The obtained results showed the potential use of green natural dyes from broccoli wastes, adsorbed into nanoclays, for the development of naturally coloured bionanocomposites.
Utilization of Nano-TiO2 as an Influential Additive for Complementing Separation Performance of a Hybrid PVDF-PVP Hollow Fiber: Boron Removal from Leachate
Authors: Man Hasfalina Che , Abba Mohammed Umar , Abdulsalam Mohammed , Azis Raba’ah Syahidah , Idris Aida Isma , Hamzah Muhammad Hazwan
Published: October 2020

The continuous increase in anthropogenic activities resulting in an increase in boron concentration in the environment is becoming a serious threat to public health and the ecosystem. In this regard, a hybrid polyvinylidene fluoride (PVDF)-polyvinyl pyrrolidone (PVP) hollow fiber was synthesized with hydrophilic nano-titanium oxide (TiO2) at varied loadings of 0, 0.5, 1.0, 1.5, and 2.0 wt% using the phase inversion technique. The resultant membranes were characterized in terms of Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDX), contact angle, porosity, and zeta potential. The permeability flux was assessed using both pure water and leachate; also, rejection performance was evaluated based on boron removal from the leachate. The results revealed that the membrane with 1.0 wt% loading had the highest flux alongside an upturn in boron rejection percentage of 223 L/m2·h and 94.39%, respectively. In addition, the lowest contact angle of 50.01° was recorded with 1.0 wt% TiO2 loading, and this implies that it is the most hydrophilic. Throughout the experiment cycles, the fiber with 1.0 wt% TiO2 loading demonstrated a high flux recovery varying between 92.82% and 76.26% after 9 h filtration time. The physicochemical analysis of the permeate revealed that the boron concentration was significantly reduced to 0.43 mg/L, which is far lower than the discharge limit of 1.0 mg/L.
Investigation on Mode I Fracture Toughness of Woven Carbon Fiber-Reinforced Polymer Composites Incorporating Nanomaterials
Authors: Truong Gia Toai , Tran Hai Van , Choi Kyoung-Kyu
Published: October 2020

This study experimentally investigated the effects of nanomaterials and interface fiber angle on the mode I fracture toughness of woven carbon fiber-reinforced polymer (CFRP) composites. Three different types of nanomaterials were used: COOH-functionalized short multi-walled carbon nanotubes (S-MWCNT-COOH), multi-walled carbon nanotubes (MWCNTs), and graphene nanoplatelets (GnPs). Double cantilever beam specimens were composed of 12 woven carbon fiber fabrics with/without 1 wt% nanomaterials, and were manufactured using the hand lay-up method. Furthermore, two different stacking sequence series were used; the first series comprised only on-axis carbon-fiber fabrics (0° or 90°), and the second series comprised both on- and off-axis carbon-fiber fabrics (0° or 90° and ±45°). The test results showed that adding S-MWCNT-COOH, MWCNTs, and GnPs significantly increased the mode I fracture toughness of the CFRP composites for both the stacking sequence series. Moreover, the specimens that used only on-axis carbon fiber fabrics exhibited higher fracture toughness values than those of the specimens that used on- and off-axis carbon fiber fabrics together. In addition, an empirical model was established to predict the fracture toughness of the CFRP composites with nanomaterials by using on- and off-axis carbon fiber fabrics together, and the prediction results showed a good agreement with the experimental results.
Constructing Positively Charged Thin-Film Nanocomposite Nanofiltration Membranes with Enhanced Performance
Authors: Shao Wenyao , Liu Chenran , Yu Tong , Xiong Ying , Hong Zhuan , Xie Quanling
Published: October 2020

Using polyethylenimine (PEI) as the aqueous reactive monomers, a positively charged thin-film nanocomposite (TFN) nanofiltration (NF) membrane with enhanced performance was developed by successfully incorporating graphene oxide (GO) into the active layer. The effects of GO concentrations on the surface roughness, water contact angle, water flux, salt rejection, heavy metal removals, antifouling property, and chlorine resistance of the TFN membranes were evaluated in depth. The addition of 20 ppm GO facilitated the formation of thin, smooth, and hydrophilic nanocomposite active layers. Thus, the TFN-PEI-GO-20 membrane showed the optimal water flux of 70.3 L·m−2·h−1 without a loss of salt rejection, which was 36.8% higher than the thin-film composite (TFC) blank membrane. More importantly, owing to the positively charged surfaces, both the TFC-PEI-blank and TFN-PEI-GO membranes exhibited excellent rejections toward various heavy metal ions including Zn2+, Cd2+, Cu2+, Ni2+, and Pb2+. Additionally, compared with the negatively charged polypiperazine amide NF membrane, both the TFC-PEI-blank and TFN-PEI-GO-20 membranes demonstrated superior antifouling performance toward the cationic surfactants and basic protein due to their hydrophilic, smooth, and positively charged surface. Moreover, the TFN-PEI-GO membranes presented the improved chlorine resistances with the increasing GO concentration.
The Viable Fabrication of Gas Separation Membrane Used by Reclaimed Rubber from Waste Tires
Authors: Lin Yu-Ting , Zhuang Guo-Liang , Wey Ming-Yen , Tseng Hui-Hsin
Published: October 2020

Improper disposal and storage of waste tires poses a serious threat to the environment and human health. In light of the drawbacks of the current disposal methods for waste tires, the transformation of waste material into valuable membranes has received significant attention from industries and the academic field. This study proposes an efficient and sustainable method to utilize reclaimed rubber from waste tires after devulcanization, as a precursor for thermally rearranged (TR) membranes. The reclaimed rubber collected from local markets was characterized by thermogravimetric analyzer (TGA) and Fourier transfer infrared spectroscopy (FT-IR) analysis. The results revealed that the useable rubber in the as-received sample amounted to 57% and was classified as styrene–butadiene rubber, a type of synthetic rubber. Moreover, the gas separation measurements showed that the C7-P2.8-T250 membrane with the highest H2/CO2 selectivity of 4.0 and sufficient hydrogen permeance of 1124.61 GPU exhibited the Knudsen diffusion mechanism and crossed the Robeson trade-off limit. These findings demonstrate that reclaimed rubber is an appealing, cost effective, and sustainable alternative, as a precursor for TR membranes, for application in gas separation. The present approach is useful in the selection of a suitable reclaimed rubber precursor and related membrane preparation parameters, leading to the advancement in the recycling value of waste tires.
Acid Treatment Enhances the Antioxidant Activity of Enzymatically Synthesized Phenolic Polymers
Authors: Alfieri Maria Laura , Moccia Federica , D’Errico Gerardino , Panzella Lucia , d’Ischia Marco , Napolitano Alessandra
Published: October 2020

Phenolic polymers produced by enzymatic oxidation under biomimetic and eco-friendly reaction conditions are usually endowed with potent antioxidant properties. These properties, coupled with the higher biocompatibility, stability and processability compared to low-molecular weight phenolic compounds, open important perspectives for various applications. Herein, we report the marked boosting effect of acid treatment on the antioxidant properties of a series of polymers obtained by peroxidase-catalyzed oxidation of natural phenolic compounds. Both 2,2-diphenyl-1-picrylhydrazyl (DPPH) and ferric reducing/antioxidant power (FRAP) assays indicated a remarkable increase in the antioxidant properties for most phenolic polymers further to the acid treatment. In particular, up to a ca. 60% decrease in the EC50 value in the DPPH assay and a 5-fold increase in the Trolox equivalents were observed. Nitric oxide- and superoxide-scavenging assays also indicated highly specific boosting effects of the acid treatment. Spectroscopic evidence suggested, in most cases, that the occurrence of structural modifications induced by the acid treatment led to more extended π-electron-conjugated species endowed with more efficient electron transfer properties. These results open new perspectives toward the design of new bioinspired antioxidants for application in food, biomedicine and material sciences.
PEMFC Transient Response Characteristics Analysis in Case of Temperature Sensor Failure
Authors: Han Jaeyoung , Yu Sangseok , Yun Jinwon
Published: October 2020

In this study, transient responses of a polymer electrolyte fuel cell system were performed to understand the effect of sensor fault signal on the temperature sensor of the stack and the coolant inlet. We designed a system-level fuel cell model including a thermal management system, and a controller to analyze the dynamic behavior of fuel cell system applied with variable sensor fault scenarios such as stuck, offset, and scaling. Under drastic load variations, transient behavior is affected by fault signals of the sensor. Especially, the net power of the faulty system is 45.9 kW. On the other hand, the net power of the fault free system is 46.1 kW. Therefore, the net power of a faulty system is about 0.2 kW lower than that of a fault-free system. This analysis can help in understanding the transient behavior of fuel cell systems at the system level under fault situations and provide a proper failure avoidance control strategy for the fuel cell system.
Computer-Aided Nonlinear Frequency Response Method for Investigating the Dynamics of Chemical Engineering Systems
Authors: Živković Luka A. , Vidaković-Koch Tanja , Petkovska Menka
Published: October 2020

The Nonlinear Frequency Response (NFR) method is a useful Process Systems Engineering tool for developing experimental techniques and periodic processes that exploit the system nonlinearity. The basic and most time-consuming step of the NFR method is the derivation of frequency response functions (FRFs). The computer-aided Nonlinear Frequency Response (cNFR) method, presented in this work, uses a software application for automatic derivation of the FRFs, thus making the NFR analysis much simpler, even for systems with complex dynamics. The cNFR application uses an Excel user-friendly interface for defining the model equations and variables, and MATLAB code which performs analytical derivations. As a result, the cNFR application generates MATLAB files containing the derived FRFs in a symbolic and algebraic vector form. In this paper, the software is explained in detail and illustrated through: (1) analysis of periodic operation of an isothermal continuous stirred-tank reactor with a simple reaction mechanism, and (2) experimental identification of electrochemical oxygen reduction reaction.
CFD Modeling of Spatial Inhomogeneities in a Vegetable Oil Carbonation Reactor
Authors: Egedy Attila , Kummer Alex , Leveneur Sébastien , Varga Tamás , Chován Tibor
Published: October 2020

Fossil materials are widely used raw materials in polymerization processes; hence, in many cases, the primary goal of green and sustainable technologies is to replace them with renewables. An exciting and promising technology from this aspect is the isocyanate-free polyurethane production using vegetable oil as a raw material. Functional compounds can be formed by the epoxidation of vegetable oils in three reaction steps: epoxidation, carbonation, and aminolysis. In the case of vegetable oil carbonation, the material properties vary strongly, with the composition affecting the solubility of CO2 in the reaction mixture. Many attempts have been made to model these interactions, but they generally do not account for the changes in the material properties in terms of spatial coordinates. A 2D CFD model based on the combination of the k-ε turbulence model and component mass balances considering the spatial inhomogeneities on the performance of the reactor was created. After the evaluation of the mesh independence study, the simulator was used to calculate the carbonation reaction in a transient analysis with spatial coordinate-dependent density and viscosity changes. The model parameters (height-dependent mass transfer parameters and boundary flux parameters) were identified based on one physical experiment, and a set of 15 experiments were used for model validation. With the validated model, the optimal operating temperature, pressure, and catalyst concentration was proposed.
Preliminary Computational Analysis of Three Configurations for an Innovative Ventricular Chamber
Authors: Candela Valentina , Todesco Martina , Visentin Alberto , Meneghetti Giovanni , Fabozzo Assunta , Gerosa Gino , Bagno Andrea
Published: October 2020

(1) Background: shape, dimension, hemodynamics, and hemocompatibility are just a few of the several challenging key points that must be addressed in designing any suitable solution for the ventricular chamber of mechanical circulatory support devices. A preliminary evaluation of different geometries of bellow-like ventricular chambers is herein proposed. The chambers were made with a polycarbonate urethane that is acknowledged to be a hemocompatible polymer. (2) Methods: an explicit dynamic computational analysis was performed. The actuation of the three chambers was simulated without the presence of an internal fluid. Maximum stress and strain values were identified, as well as the most critical regions. Geometric changes were checked during simulated motion to verify that the dimensional constraints were satisfied. (3) Results: one chamber appeared to be the best solution compared to the others, since its dimensional variations were negligible, and effective stresses and strains did not reach critical values. (4) Conclusions: the identification of the best geometric solution will allow proceeding with further experimental studies. Fluid–structure interactions and fatigue analyses were investigated.
Biosensing on the Centrifugal Microfluidic Lab-on-a-Disc Platform
Authors: Miyazaki Celina M. , Carthy Eadaoin , Kinahan David J.
Published: October 2020

Lab-on-a-Disc (LoaD) biosensors are increasingly a promising solution for many biosensing applications. In the search for a perfect match between point-of-care (PoC) microfluidic devices and biosensors, the LoaD platform has the potential to be reliable, sensitive, low-cost, and easy-to-use. The present global pandemic draws attention to the importance of rapid sample-to-answer PoC devices for minimising manual intervention and sample manipulation, thus increasing the safety of the health professional while minimising the chances of sample contamination. A biosensor is defined by its ability to measure an analyte by converting a biological binding event to tangible analytical data. With evolving manufacturing processes for both LoaDs and biosensors, it is becoming more feasible to embed biosensors within the platform and/or to pair the microfluidic cartridges with low-cost detection systems. This review considers the basics of the centrifugal microfluidics and describes recent developments in common biosensing methods and novel technologies for fluidic control and automation. Finally, an overview of current devices on the market is provided. This review will guide scientists who want to initiate research in LoaD PoC devices as well as providing valuable reference material to researchers active in the field.
High-Performance Mg–Al–Bi Alloy Anode for Seawater Batteries and Related Mechanisms
Authors: Wu Changqing , Meng Xu , Wang Wei
Published: October 2020

Bi, a group 15 element, was added to magnesium alloys and applied to seawater batteries in marine operating machinery to improve the electrochemical performance and corrosion resistance of the battery. The electrochemical properties of as-cast pure Mg, Mg–8Al, and Mg–8Al–xBi alloy anodes in 3.5% NaCl solution were researched. Electrochemical impedance spectroscopy and an immersion test in 3.5% NaCl solution show that the Mg–8%Al–0.4%Bi alloy provides better corrosion resistance than Mg and the Mg–8Al alloy. The galvanostatic discharge results show that the Mg–8%Al–0.4%Bi alloy revealed better electrochemical properties and utilization efficiency in 3.5% NaCl solution. The Mg17Al12 and BiOCl phases formed during the discharge process of the Mg–8%Al–0.4%Bi alloy play an important role in improving the electrochemical performance and utilization efficiency of the alloy.
Fitness Landscape Analysis and Edge Weighting-Based Optimization of Vehicle Routing Problems
Authors: Kovács László , Agárdi Anita , Bányai Tamás
Published: October 2020

Vehicle routing problem (VRP) is a highly investigated discrete optimization problem. The first paper was published in 1959, and later, many vehicle routing problem variants appeared to simulate real logistical systems. Since vehicle routing problem is an NP-difficult task, the problem can be solved by approximation algorithms. Metaheuristics give a “good” result within an “acceptable” time. When developing a new metaheuristic algorithm, researchers usually use only their intuition and test results to verify the efficiency of the algorithm, comparing it to the efficiency of other algorithms. However, it may also be necessary to analyze the search operators of the algorithms for deeper investigation. The fitness landscape is a tool for that purpose, describing the possible states of the search space, the neighborhood operator, and the fitness function. The goal of fitness landscape analysis is to measure the complexity and efficiency of the applicable operators. The paper aims to investigate the fitness landscape of a complex vehicle routing problem. The efficiency of the following operators is investigated: 2-opt, order crossover, partially matched crossover, cycle crossover. The results show that the most efficient one is the 2-opt operator. Based on the results of fitness landscape analysis, we propose a novel traveling salesman problem genetic algorithm optimization variant where the edges are the elementary units having a fitness value. The optimal route is constructed from the edges having good fitness value. The fitness value of an edge depends on the quality of the container routes. Based on the performed comparison tests, the proposed method significantly dominates many other optimization approaches.
Influences of Ash-Existing Environments and Coal Structures on CO2 Gasification Characteristics of Tri-High Coal
Authors: Liu Lang , Jiao Qingrui , Yang Jian , Kong Bowen , Ren Shan , Liu Qingcai
Published: October 2020

Two kinds of tri-high coals were selected to determine the influences of ash-existing environments and coal structures on CO2 gasification characteristics. The TGA results showed that the gasification of ash-free coal (AFC) chars was more efficient than that of corresponding raw coal (RC) chars. To uncover the reasons, the structures of RCs and AFCs, and their char samples prepared at elevated temperatures were investigated with SEM, BET, XRD, Raman and FTIR. The BET, SEM and XRD results showed that the Ash/mineral matter is associated with coal, carbon forms the main structural framework and mineral matters are found embedded in the coal structure in the low-rank tri-high coal. The Raman and FTIR results show that the ash can hinder volatile matters from exposing to the coal particles. Those results indicate that the surface of AFC chars has more free active carbon sites than raw coal chars, which are favorable for mass transfer between C and CO2, thereby improving reactivity of the AFC chars. However, the gasification reactivity was dominated by pore structure at elevated gasification temperatures, even though the microcrystalline structure, functional group structure, and increase in the disorder carbon were improved by acid pickling.
Carbon Emission Reduction Potential in the Finnish Energy System Due to Power and Heat Sector Coupling with Different Renovation Scenarios of Housing Stock
Authors: Jokinen Ilkka , Bashir Arslan Ahmad , Hirvonen Janne , Jokisalo Juha , Kosonen Risto , Lehtonen Matti
Published: October 2020

In the pursuit of mitigating the effects of climate change the European Union and the government of Finland have set targets for emission reductions for the near future. This study examined the carbon emission reduction potential in the Finnish energy system with power-to-heat (P2H) coupling of the electricity and heat sectors with different housing renovation levels. The measures conducted in the energy system were conducted as follows. Wind power generation was increased in the Finnish power system with 10 increments. For each of these, the operation of hydropower was optimized to maximize the utilization of new wind generation. The excess wind generation was used to replace electricity and heat from combined heat and power production for district heating. The P2H conversion was performed by either 2000 m deep borehole heat exchangers coupled to heat pumps, with possible priming of heat, or with electrode boilers. The housing stock renovated to different levels affected both the electricity and district heating demands. The carbon emission reduction potential of the building renovation measures, and the energy system measures were determined over 25 years. Together with the required investment costs for the different measures, unit costs of emission reductions, €/t-CO2, were determined. The lowest unit cost solution of different measures was established, for which the unit cost of emission reductions was 241 €/t-CO2 and the reduced carbon emissions 11.3 Mt-CO2 annually. Moreover, the energy system measures were found to be less expensive compared to the building renovation measures, in terms of unit costs, and the P2H coupling a cost-efficient manner to increase the emission reductions.
Determination of Dissolved CO2 Concentration in Culture Media: Evaluation of pH Value and Mathematical Data
Authors: Adnan Amir Izzuddin , Ong Mei Yin , Nomanbhay Saifuddin , Show Pau Loke
Published: October 2020

Carbon dioxide is the most influential gas in greenhouse gasses and its amount in the atmosphere reached 412 µmol/mol in August 2020, which increased rapidly, by 48%, from preindustrial levels. A brand-new chemical industry, namely organic chemistry and catalysis science, must be developed with carbon dioxide (CO2) as the source of carbon. Nowadays, many techniques are available for controlling and removing carbon dioxide in different chemical processes. Since the utilization of CO2 as feedstock for a chemical commodity is of relevance today, this study will focus on how to increase CO2 solubility in culture media used for growing microbes. In this work, the CO2 solubility in a different medium was investigated. Sodium hydroxide (NaOH) and monoethanolamine (MEA) were added to the culture media (3.0 g/L dipotassium phosphate (K2HPO4), 0.2 g/L magnesium chloride (MgCl2), 0.2 g/L calcium chloride (CaCl2), and 1.0 g/L sodium chloride (NaCl)) for growing microbes in order to observe the difference in CO2 solubility. Factors of temperature and pressure were also studied. The determination of CO2 concentration in the solution was measured by gas analyzer. The result obtained from optimization revealed a maximum CO2 concentration of 19.029 mol/L in the culture media with MEA, at a pressure of 136.728 kPa, operating at 20.483 °C.
Nonlocal Interferences Induced by the Phase of the Wavefunction for a Particle in a Cavity with Moving Boundaries
Authors: Waegell Mordecai , Matzkin Alex
Published: October 2020

We investigate the dynamics of a particle in a confined periodic system—a time-dependent oscillator confined by infinitely high and moving walls—and focus on the evolution of the phase of the wavefunction. It is shown that, for some specific initial states in this potential, the phase of the wavefunction throughout the cavity depends on the walls motion. We further elaborate a thought experiment based on interferences devised to detect this form of single-particle nonlocality from a relative phase. We point out that, within the non-relativistic formalism based on the Schrödinger equation (SE), detecting this form of nonlocality can give rise to signaling. We believe this effect is an artifact, but the standard relativistic corrections to the SE do not appear to fix it. Specific illustrations are given, with analytical results in the adiabatic approximation, and numerical computations to show that contributions from high-energy states (corresponding to superluminal velocities) are negligible.
“Looking ‘Foreword’ to Milton in Toni Morrison’s Paradise”
Authors: Wilburn Reginald A.
Published: October 2020

Prior to the 2014 republication of Toni Morrison’s, Paradise, the novelist had not published any commentary about the role of literary influence John Milton might have had on her fictional writings. In a foreword to the republication of her 1997 novel, Morrison offers her first published acknowledgement of Milton’s influence on any work in her canon. My essay contends this Miltonic revelation constitutes a groundbreaking event in literary criticism. I explore the critical significance of this revelation by explicating the foreword, Milton’s significance within it, and its implications for reading the 17th-century epic writer’s (in)visible influential presence throughout Paradise. Placing particular emphasis on the interpretive significance of Morrison’s womanist critique of Milton’s portrayal of Eve, my essay turns to a focus on the Convent women as interrogated replicas of the first mother presented in Paradise Lost. This analysis of the novel enlarges the grounds of contention in Milton and African American studies, providing a richer interpretive reading experience that has never been cited or examined in existing literary criticism prior to now.
Being a Church in a Time of Violence: Peruvian Church during the Armed Internal Conflict 1980 to 2000
Authors: Samanez Cecilia Tovar
Published: October 2020

During the war with Shining Path (1980–2000) violence in Peru was brutal and extensive. Massive violations of human rights were common, with victims from all regions and social classes, but were particularly intense in rural areas like Ayacucho where the insurgency began. The churches supported and defended rights by providing organizational space, legal defense, publicity (through their radio networks) and by remaining among populations in danger, working with them and often sharing their fate. Important elements in the churches including leaders, priests, members of religious orders, sisters catechists, and ordinary people working through church organizations, were prominent among the victims. They were attacked both by Shining Path (who saw them as competitors) and by army and police forces, who saw their commitment to social justice and collective action as subversive. The choice to defend human rights in theory and action is rooted in a long term process of transformation in the church which drew strength and inspiration from the “option for the poor” articulated at the Catholic bishops meetings in Medellin (1968) and Puebla (1979), and in numerous statements and organizational efforts since then. The process of violence in Peru and the role of the churches is documented in the reports of the Peruvian Commission for Truth and Reconciliation and others from the Peruvian church as well from as regional and local groups.
Good-Deal Bounds for Option Prices under Value-at-Risk and Expected Shortfall Constraints
Authors: Desmettre Sascha , Laudagé Christian , Sass Jörn
Published: October 2020

In this paper, we deal with the pricing of European options in an incomplete market. We use the common risk measures Value-at-Risk and Expected Shortfall to define good-deals on a financial market with log-normally distributed rate of returns. We show that the pricing bounds obtained from the Value-at-Risk admit a non-smooth behavior under parameter changes. Additionally, we find situations in which the seller’s bound for a call option is smaller than the buyer’s bound. We identify the missing convexity of the Value-at-Risk as main reason for this behavior. Due to the strong connection between good-deal bounds and the theory of risk measures, we further obtain new insights in the finiteness and the continuity of risk measures based on multiple eligible assets in our setting.
Full Convolutional Neural Network Based on Multi-Scale Feature Fusion for the Class Imbalance Remote Sensing Image Classification
Authors: Ren Yuanyuan , Zhang Xianfeng , Ma Yongjian , Yang Qiyuan , Wang Chuanjian , Liu Hailong , Qi Quan
Published: October 2020

Remote sensing image segmentation with samples imbalance is always one of the most important issues. Typically, a high-resolution remote sensing image has the characteristics of high spatial resolution and low spectral resolution, complex large-scale land covers, small class differences for some land covers, vague foreground, and imbalanced distribution of samples. However, traditional machine learning algorithms have limitations in deep image feature extraction and dealing with sample imbalance issue. In the paper, we proposed an improved full-convolution neural network, called DeepLab V3+, with loss function based solution of samples imbalance. In addition, we select Sentinel-2 remote sensing images covering the Yuli County, Bayingolin Mongol Autonomous Prefecture, Xinjiang Uygur Autonomous Region, China as data sources, then a typical region image dataset is built by data augmentation. The experimental results show that the improved DeepLab V3+ model can not only utilize the spectral information of high-resolution remote sensing images, but also consider its rich spatial information. The classification accuracy of the proposed method on the test dataset reaches 97.97%. The mean Intersection-over-Union reaches 87.74%, and the Kappa coefficient 0.9587. The work provides methodological guidance to sample imbalance correction, and the established data resource can be a reference to further study in the future.
Postfire Tree Structure from High-Resolution LiDAR and RBR Sentinel 2A Fire Severity Metrics in a Pinus halepensis-Dominated Burned Stand
Authors: Viedma Olga , Almeida Danilo R. A. , Moreno Jose Manuel
Published: October 2020

Tree and plant structures remaining after fires reflect well their degree of consumption, and are therefore good indicators of fire severity. Satellite optical images are commonly used to estimate fire severity. However, depending on the severity of a fire, these sensors have a limited ability to penetrate the canopy down to the ground. Airborne light detection and ranging (LiDAR) can overcome this limitation. Assessing the differences between areas that have been burned in different fire severities based on satellite images of plant and tree structures remaining after fires is important, given its widespread use to characterize fires and fire impacts (e.g., carbon emissions). Here, we measured the remaining tree structures after a fire in a forest stand burned in SE Spain in the summer of 2017. We used high-resolution LiDAR data, acquired from an unmanned aerial vehicle (UAV) six months after the fire. This information was crossed with fire severity levels based on the relativized burnt ratio (RBR) derived from Sentinel 2A images acquired a few months before and after fire. LiDAR tree structure data derived from vertical canopy profiles (VCPs) were classified into three clusters, using hierarchical principal component analysis (HPCA), followed by a random forest (RF) to select the most important variables in distinguishing the cluster groups. Among these, crown leaf area index (LAI), crown leaf area density (LAD), crown volume, tree height and tree height skewness, among others, were the most significant variables, and reflected well the degree of combustion undergone by the trees based on the response of these variables to variations in fire severity from RBR Sentinel 2A. LiDAR metrics were able to distinguish crown fire from surface fire through changes in the understory LAI and understory and midstory vegetation. The three tree structure clusters were well separated among each other and significantly related with the RBR Sentinel 2A-derived fire severity categories. Unburned and low-severity burned areas were more diverse in tree structures than moderate and high severity burned ones. The LiDAR metrics derived from VCPs demonstrated promising potential for characterizing fine-grained post-fire plant structures and fire damage when crossed with satellite-based fire severity metrics, turning into a promising approach for better characterizing fire impacts at a resolution needed for many ecological processes.