bluuebunny/crossref_metadata_2025 huggingface dataset:
Potential Involvement of Oxidative Stress in Ligamentum Flavum Hypertrophy
Authors: Ito Kei , Kise Hideki , Suzuki Satoshi , Nagai Sota , Hachiya Kurenai , Takeda Hiroki , Kawabata Soya , Ikeda Daiki , Takubo Keiyo , Kaneko Shinjiro , Fujita Nobuyuki
Published: January 2023

Oxidative stress (OS) results in many disorders, of which degenerative musculoskeletal conditions are no exception. However, the interaction between OS and ligamentum flavum (LF) hypertrophy in lumbar spinal canal stenosis is not clearly understood. The first research question was whether OS was involved in LF hypertrophy, and the second was whether the antioxidant N-acetylcysteine (NAC) was effective on LF hypertrophy. In total, 47 LF samples were collected from patients with lumbar spinal disorders. The cross-sectional area of LF was measured on axial magnetic resonance imaging. Immunohistochemistry of 8-OHdG and TNF-α were conducted on human LF samples. A positive association was found between 8-OHdG or TNF-α expression and cross-sectional area of LF. Flow cytometry analysis showed that H2O2, buthionine sulfoximine, and TNF-α treatment significantly increased intracellular reactive oxygen species in primary LF cells. NAC inhibited the induction of LF hypertrophy markers by OS or TNF in a real-time reverse transcriptase polymerase chain reaction and enzyme-linked immunosorbent assay. Western blotting analysis indicated that p38, Erk, and p65 phosphorylation were involved in intracellular OS signaling in LF cells. In conclusion, our results indicated that OS could be a therapeutic target for LF hypertrophy. Although this study included no in vivo studies to examine the longitudinal efficacy of NAC on LF hypertrophy, NAC may have potential as a therapeutic agent against lumbar spinal canal stenosis.
Effects of Playing Position and Contextual Factors on Internal Match Loads, Post-Match Recovery and Well-Being Responses of Elite Male Water Polo Players
Authors: Perazzetti Andrea , Dopsaj Milivoj , Sansone Pierpaolo , Mandorino Mauro , Tessitore Antonio
Published: January 2023

This study aimed to investigate the effects of playing position and contextual factors (match outcome, final score difference, match location, travel duration, number of scored and conceded goals) on the internal match load, players’ perceived recovery and players’ well-being. The session-RPE (s-RPE), Perceived Recovery Scale (PRS) and Hooper Index (HI) of 17 male elite water polo players were monitored during all matches (regular season and play-out) of the 2021/22 Italian Serie A1 championship. Three separate, mixed linear models for repeated measures showed significant main effects: drawn compared to won matches led to higher s-RPE values (mean ± SE = 277 ± 17.6 vs. 237.3 ± 20.6), while longer travel duration (estimate = −0.148) and goals scored (estimate = −3.598) led to lower s-RPE values; balanced compared to unbalanced matches led to higher PRS values (mean ± SE = 6.8 ± 0.3 vs. 5.1 ± 0.4), while playing time (estimate = −0.041) and goals scored (estimate = −0.180) led to lower PRS values; higher scores of the HI were registered for regular season compared to the play-out (mean ± SE = 15.6 ± 0.9 vs. 13.5 ± 0.8). This study marks the importance of ecological and non-invasive monitoring tools to assess internal match load, recovery and the well-being of elite water polo players.
Analysis of Real-Time Face-Verification Methods for Surveillance Applications
Authors: Perez-Montes Filiberto , Olivares-Mercado Jesus , Sanchez-Perez Gabriel , Benitez-Garcia Gibran , Prudente-Tixteco Lidia , Lopez-Garcia Osvaldo
Published: January 2023

In the last decade, face-recognition and -verification methods based on deep learning have increasingly used deeper and more complex architectures to obtain state-of-the-art (SOTA) accuracy. Hence, these architectures are limited to powerful devices that can handle heavy computational resources. Conversely, lightweight and efficient methods have recently been proposed to achieve real-time performance on limited devices and embedded systems. However, real-time face-verification methods struggle with problems usually solved by their heavy counterparts—for example, illumination changes, occlusions, face rotation, and distance to the subject. These challenges are strongly related to surveillance applications that deal with low-resolution face images under unconstrained conditions. Therefore, this paper compares three SOTA real-time face-verification methods for coping with specific problems in surveillance applications. To this end, we created an evaluation subset from two available datasets consisting of 3000 face images presenting face rotation and low-resolution problems. We defined five groups of face rotation with five levels of resolutions that can appear in common surveillance scenarios. With our evaluation subset, we methodically evaluated the face-verification accuracy of MobileFaceNet, EfficientNet-B0, and GhostNet. Furthermore, we also evaluated them with conventional datasets, such as Cross-Pose LFW and QMUL-SurvFace. When examining the experimental results of the three mentioned datasets, we found that EfficientNet-B0 could deal with both surveillance problems, but MobileFaceNet was better at handling extreme face rotation over 80 degrees.
Application of Vortex Induced Vibration Systems to Improve Vertical Mixing and Create Light/Dark Cycles for Enhanced Algal Biomass Productivity in Raceway Ponds
Authors: Akca Mehmet Sadik , Ceylan-Perver Gamze , Duranay Aytekin , Kinaci Omer Kemal , Inanc Bulent
Published: January 2023

Limited light availability due to insufficient vertical mixing is one of the main drawbacks of raceway ponds (RWPs), the most common type of microalgae cultivation system. In this study, we have investigated the application of vortex induced vibration (VIV) systems to improve vertical mixing in order to enhance algal biomass productivity. The system consists of a cylinder submerged parallel to the bottom in the pond with two springs attached at its ends. The cylinder oscillates perpendicularly to the flow direction at the pond to increase vertical mixing. A VIV system, which requires no additional energy input, was installed in a 0.3 m deep raceway pond and continuous cylinder oscillation was successfully achieved. Cylinder oscillation frequency of 1.24 s−1 and amplitude of 6.5 cm have been obtained experimentally for 0.3 m s−1 flow velocity. Numerical simulations were carried out with experimental parameters using CFD code and were in good accordance with experimental results. Numerical analysis revealed that it is possible to create high frequency light/dark cycles; mean light/dark cycle frequencies were found to be 2.33 s−1, 5.28 s−1 and 21.17 s−1, at lowermost, middle and uppermost cylinder positions, respectively. Enhanced velocity magnitude of 0.3 m s−1 was achieved in the vertical direction; vertical motion of flow resulting from cylinder oscillation covers about two thirds of pond depth. Effectiveness of the VIV system on biomass growth was also verified by comparative Chlorella vulgaris cultivation under outdoor conditions. It has been observed that the VIV system installed reactor enhanced biomass production capacity by over 20% compared to the control pond. These results indicate that the presented method possesses a potential for enhanced algal biomass production without significant increase in installation and operating costs.
Development and Validation of Accumulation Term (Distributed and/or Point Source) in a Finite Element Hydrodynamic Model
Authors: Dresback Kendra M. , Szpilka Christine M. , Kolar Randall L. , Moghimi Saeed , Myers Edward P.
Published: January 2023

During tropical storms, precipitation and associated rainfall-runoff can lead to significant flooding, in both the upland and coastal areas. Flooding in coastal areas is compounded by the storm surge. Several hurricanes in recent history have exhibited the destructive force of compound flooding due to precipitation, rainfall-runoff, storm surge and waves. In previous work, various coupled modeling systems have been developed to model total water levels (defined as tides, waves, surge, and rainfall-runoff) for tropical storms. The existing coupled system utilizes a hydrologic model in the upland areas of the domain to capture the precipitation and rainfall-runoff associated with the storms; however, in the coastal areas the precipitation and rainfall-runoff is not captured. Herein a source/sink term is incorporated within the hydrodynamic model itself to capture precipitation and rainfall-runoff over the already inundated coastal areas. The new algorithm is verified for several idealized test cases, and then it is applied to Hurricane Irene. Validation indicates that the new methodology is comparable to the existing river flux forcing under most conditions and allows for the addition of streamflows due to overland runoff, as well as the actual precipitation itself.
Large-Scale Simulation of a Shipping Speed Limitation Measure in the Western Mediterranean Sea: Effects on Underwater Noise
Authors: Lajaunie Myriam , Ollivier Benjamin , Ceyrac Laura , Dellong David , Le Courtois Florent
Published: January 2023

Underwater noise from shipping activity can impact marine ecosystems in the long term and at large scale. Speed limitation has been considered to reduce noise emission levels. In this article, the effects of speed limitation on shipping noise levels are investigated at high spatial resolution (5 arc-min) in the Western Mediterranean Sea. Scenarios of maximum speed limits of 10 kt and 15 kn are computed. The impact of a speed reduction is time-dependent and tends to redistribute sources of noise temporally, smoothing the contrasts existing in marine traffic at the daily scale. The effectiveness of the measure is evaluated over short successive time windows (6 h), allowing for capture of the dynamic of the effect of speed reduction. Several metrics are proposed to evaluate the effectiveness of speed reduction as a mitigation measure according to its temporal stability. This study illustrates complex phenomena related to (1) the increased vessel density in the speed limitation area due to longer navigation time and (2) deep-water and shallow-water propagations. The bathymetry and the local distribution of traffic are two elements of importance with respect to the effectiveness and the stability of the measure, whereas the traffic properties seem to impact the stability of the effect in particular, and deep waters seem to increase the effectiveness. This research shows the areas in which the proposed measure would be the most effective.
Postoperative Nausea and Vomiting According to Target-Controlled or Manual Remifentanil Infusion in Gynecological Patients Undergoing Pelviscopic Surgery: A Randomized Controlled Trial
Authors: Lee Sangho , You Ann Hee , Kim Miyun , Kang Hee Yong
Published: January 2023

Background: We compared the incidence of postoperative nausea and vomiting (PONV) and postoperative outcomes, according to the remifentanil infusion method, during surgery in patients with a high-risk of PONV. Methods: Ninety patients undergoing elective gynecological pelviscopic surgery were randomly allocated to either target-controlled infusion (TCI, T) or manual (M) infusion. The primary outcome was the incidence of PONV until postoperative day (POD) 2. The secondary outcomes were perioperative heart rate (HR), blood pressure (BP), numerical rating scale pain scores up to POD2, and postoperative hospital length of stay. Results: Forty-four patients in the T group and 45 patients in the M group were analyzed. The total dose of remifentanil infusion was significantly higher in the T group (T group: 0.093 (0.078–0.112) μg/kg/min; M group: 0.062 (0.052–0.076) µg/kg/min, p < 0.001). Within POD2, the overall PONV was not significantly different (27 (61.4%) vs. 27 (60.0%), p = 0.895). The HR (82 ± 11.5/min vs. 87 ± 11.1/min, p = 0.046) and mean BP (83 ± 17.2 mmHg vs. 90 ± 16.7 mmHg, p = 0.035) were significantly lower in the T group after tracheal intubation. The other postoperative outcomes were comparable between the two groups. Conclusions: Although the total remifentanil infusion dose was higher in the T group than in the M group, the postoperative outcomes were similar. If stable vital signs are desired during tracheal intubation, remifentanil infusion with TCI should be considered.
Nature-Based Solutions Modeling and Cost-Benefit Analysis to Face Climate Change Risks in an Urban Area: The Case of Turin (Italy)
Authors: Biasin Anna , Masiero Mauro , Amato Giulia , Pettenella Davide
Published: January 2023

Increasing urbanization and climate change challenges are leading to relevant environmental, economic and social pressures on European cities. These include increasing flood hazards and the urban heat island (UHI) effect. Nature-Based Solutions (NBS) are increasingly recognized within strategies to provide multiple ecosystem services to mitigate existing risks and pressures, as well as to make cities more resilient and livable. Although being increasingly addressed within the literature, NBS implementation on the ground still faces many technical and financial barriers. This paper aims to test the potential of selected NBS in mitigating the effects of identified climate change risks, i.e., the UHI effect and urban floods, in the Turin urban area (north-western Italy). Four different intervention NBS-based scenarios are developed. The supply of ecosystem services by NBS in each scenario is assessed using InVEST models and the effectiveness of NBS investments is analyzed by calculating and comparing the associated costs and benefits. Different results in terms of effectiveness and economic viability are observed for each scenario and each NBS. Flood risk mitigation oriented NBS seem to have the most impact, in particular forested green areas and retention ponds. The results are relevant to suggest policy mix strategies to embed NBS in city planning.
Determinants of Smallholder Farmers’ Income-Generating Activities in Rubber Monoculture Dominated Region Based on Sustainable Livelihood Framework
Authors: Wang Jue , Jiang Haiwei , He Yuan
Published: January 2023

The rapid expansion of rubber plantations in Xishuangbanna, China, has severely decreased rubber prices in the last several years. The income loss and other adverse environmental impacts have brought livelihood challenges and opportunities to develop and adopt more diversified and environmental-friendly income-generating activities (IGAs). To better understand the constraints and opportunities for smallholder rubber farmers to sustain or improve their livelihoods, this study investigates which IGAs are applied by local farmers and the factors that determine their adoption, using the sustainable livelihood framework as the theoretical guideline. The qualitative approach is applied using semi-structured interviews and thematic analysis. Five directions of changes in IGAs (i.e., intercropping, other cash crops, livestock raising for marketing, part-time job, and land renting) are identified, and local farmers are categorized into three groups (i.e., rejective, affirmative, and hesitate groups) based on their attitudes towards these IGAs. The results reveal that the main adoption motivations of certain IGAs are closely related to price shock, economic return, information, and extension service. Based on the results, suggestions are provided to enhance farmers’ motivation to make changes and improve the adoption of emerging IGAs with attention given to vulnerability contexts, livelihood assets and institutional assistance.
Acknowledgment to the Reviewers of Laws in 2022
Authors:   Laws Editorial Office
Published: January 2023

High-quality academic publishing is built on rigorous peer review [...]
Variations in Soil Blue Carbon Sequestration between Natural Mangrove Metapopulations and a Mixed Mangrove Plantation: A Case Study from the World’s Largest Contiguous Mangrove Forest
Authors: Chowdhury Abhiroop , Naz Aliya , Maiti Subodh Kumar
Published: January 2023

Sundarban is the world’s largest mangrove wetland. This study, conducted in 2016, to compare blue carbon sequestration with different natural metapopulations and a four-year-old Avicennia marina (30% area)-Rhizophora mucronata (70% area)-mixed mangrove plantation under anthropoganic stress. The aims of the study is to find out the variations in soil ecological function indicators (pH, electrical conductivity, bulk density, soil texture, available nitrogn, phosphorus and soil organic carbon) and key ecological service indicator (soil blue carbon pool) between sites. Simpson’s Index of dominance, diversity and Shannon-Weiner Index revealed that all the sites are under ecological stress, with the Suaeda maritima-dominated mudflat having the least biodiversity. It is also revealed that pH and electrical conductivity were highest in Suaeda maritima and Phoenix padulosa-dominated metapopulations, whereas organic carbon was the highest under the mangrove plantation and Avicennia marina-dominated site. Available nitrogen was recorded highest in the community with the Sonneretia sp.-Avicennia marina association. The mixed mangrove plantation had the highest blue carbon pool. The species diversity was not found to be related with the distance from the nearby conserved mangrove forest, contrary to the island biogeography theory. This study concludes with a recommendation of mixed mangrove plantations to restore the degraded saline mudflats along the human settlements across the globe.
Improving the Fracture Toughness and Ductility of Liquid-Phase Sintered WNiFe Tungsten Heavy Alloys by High-Temperature Annealing
Authors: Alam Md Ershadul , Odette G. Robert
Published: January 2023

Tungsten heavy alloys (WHAs) are candidates for use in fusion reactor divertors. Here, we characterize liquid-phase sintered WHAs with 90, 92.5, 95, and 97 (wt.%) tungsten (W), with a balance of a 0.7Ni–0.3Fe ductile phase. These WHAs show remarkable room temperature (RT) fracture toughness at the maximum load, KJm, ranging from ≈ 38 to 107 MPa√m, compared to a monolithic W toughness of ≈ 8 MPa√m. In most cases, the fracture of WHAs occurs through stable crack tearing. However, the 97W WHA has the lowest toughness and fracture elastically in all but the smallest specimens. As lower Ni contents are desirable for fusion application, we explore the potential for improving the ductility and KJm of WHAs using vacuum annealing at 1300 °C for 24 h. The microstructural observations reveal negligible changes in the WHA microstructure and constituent compositions. While annealing reduces the Vickers microhardness (HV), it does not significantly change the RT yield (σy) and ultimate (σu) strengths but results in beneficial increases in total elongation in the 95 and 97W WHAs by a factor of 2. RT tests on the precracked three-point-bend (3PB) bars show that annealing increases the KJm of these WHAs, and in the case of the 97W WHA, the increase is from 42 to 92%, depending on the size of the specimen. Toughening is due to enhanced crack tip process zone microcracking and dilatation.
Deformation Mechanisms and Processing Maps for High Entropy Alloys (Presentation of Processing Maps in Terms of Zener–Hollomon Parameter): Review
Authors: Jeong Hee-Tae , Kim Woo Jin
Published: January 2023

In this review paper, the hot compressive deformation mechanisms and processing maps of high-entropy alloys (HEAs) with different chemical compositions and crystal structures are analyzed. The stress exponent (n1) values measured from the series of compression tests for the HEAs performed at different temperatures and strain rates are distributed between 3 and 35, and they are most populated between 3 and 7. Power law breakdown (PLB) is found to typically occur at T/Tm ≤ 0.6 (where T is the testing temperature and Tm is the melting temperature). In AlxCrMnFeCoNi (x = 0–1) and AlxCrFeCoNi (x = 0–1) HEAs, n1 tends to decrease as the concentration of Al increases, suggesting that Al acts as a solute atom that exerts a drag force on dislocation slip motion at high temperatures. The values of activation energy for plastic flow (Qc) for the HEAs are most populated in the range between 300 and 400 kJ/mol. These values are close to the activation energy of the tracer diffusivity of elements in the HEAs ranging between 240 and 408 kJ/mol. The power dissipation efficiency η of the HEAs is shown to follow a single equation, which is uniquely related to n1. Flow instability for the HEAs is shown to occur near n1 = 7, implying that the onset of flow instability occurs at the transition from power law creep to PLB. Processing maps for the HEAs are demonstrated to be represented by plotting η as a function of the Zener–Hollomon parameter (Z = expQcRT, where R is the gas constant). Flow stability prevails at Z ≤ 1012 s−1, while flow instability does at Z ≥ 3 × 1014 s−1.
Nondestructive Evaluation for Hydration and Setting Time of Gypsum Modified Calcium Sulfoaluminate Cement Paste
Authors: Jun Yubin , Ahn Yu-Rhee , Jeon Dongho , Yim Hong Jae
Published: January 2023

Calcium sulfoaluminate (CSA) cement is a promising solution for reducing CO2 emissions. While previous studies have attempted to investigate the usefulness of CSA cement via various approaches, early age nondestructive evaluations for the setting and hydration of CSA cement mixtures have not been reported. In this study, we measured the ultrasonic pulse velocity and electrical resistivity of early age CSA cement paste. Six types of samples were prepared according to different water-to-solid ratios and different amounts of gypsum. In addition, various microstructural analyses were performed to understand CSA cement hydration with the obtained nondestructive parameters. Consequently, the effect of added gypsum in CSA cement paste was discussed in terms of ye’elimite dissolution and the precipitation of ettringite, and different pore distributions produced by added gypsum were discussed in terms of compressive strength. The 5% addition of gypsum in CSA cement paste enhanced the hydration evolution, such as ettringite, and it can induce the faster setting time up to 6 h and strength development during 24 h.
Optimizing the Compressive Properties of Porous Aluminum Composites by Varying Diamond Content, Space Holder Size and Content
Authors: Parveez Bisma , Jamal Nur Ayuni , Maleque Md Abdul , Rozhan Alya Naili , Aabid Abdul , Baig Muneer
Published: January 2023

The compressive properties of powder metallurgy (PM)-based porous aluminum (Al) composites were optimized at three levels based on the following parameters: titanium (Ti)-coated diamond content, polymethylmethacrylate (PMMA) particle content, and PMMA particle size. A 3 × 3 matrix was used in the experimental design of an L9 orthogonal array to get nine sets of combinations. These nine compositions were then tested and analyzed for density, porosity, plateau stress, and energy absorption capacity. The effect of individual input parameters was assessed using the Taguchi-based means ratio and analysis of variance (ANOVA). The main effect plots articulated the optimal parameter levels for achieving maximum compressive property values (plateau stress and energy absorption capacity). The findings show that diamond content and PMMA particle size have a major impact on compressive properties. The ANOVA analysis yielded similar results, with diamond content accounting for the greatest value. Further, the response optimization of compressive properties revealed that maximum values could be obtained at optimum parameters: diamond content of 12 wt.%, PMMA particle size of 150 μm, and PMMA particle content of 25 wt.%. Confirmation tests on the optimal parameters revealed improved results as well as some minor errors and deviations, indicating that the chosen parameters are critical for controlling the compressive properties of Al composites.
Peculiarities of Fe and Ni Diffusion in Polycrystalline Cu
Authors: Rodin Alexey , Khairullin Ainur
Published: January 2023

The peculiarities of Ni and Fe diffusion in polycrystalline Cu and Cu-Fe alloys at a 650–750 °C temperature range were studied. It was shown that the bulk diffusion coefficients were in a good agreement with the available literature data obtained for different temperature concentration ranges. The obtained values of the Ni GB diffusion triple product could be described as sδDb=8.8×10−13×exp(−165 kJmol−1RT)m3s−1. The obtained values were an order of magnitude less than the values obtained by the radiotracer method. This fact was explained by the negative segregation of Ni at the Cu GB. A stronger negative segregation of Fe in the copper GB reduced the penetration depth of iron along the GB because of an additional (negative) “driving” force; this explained why there was no advanced grain boundary diffusion. Another peculiarity of the Fe diffusion that was confirmed was the significant supersaturation of the Cu-based solid solution near the Fe/Cu interface.
Active Biohybrid Nanocomposite Films Made from Chitosan, ZnO Nanoparticles, and Stearic Acid: Optimization Study to Develop Antibacterial Films for Food Packaging Application
Authors: Suyatma Nugraha Edhi , Gunawan Sanjaya , Putri Rani Yunia , Tara Ahmed , Abbès Fazilay , Hastati Dwi Yuni , Abbès Boussad
Published: January 2023

Chitosan is a biopolymer with great potential as food packaging due to its ability to create a film without additives and its better mechanical and antibacterial qualities compared to other biopolymers. However, chitosan film still has limitations due to its high moisture sensitivity and limited flexibility. Incorporating ZnO nanoparticles (ZnO-NPs) and stearic acid (SA) into chitosan films was expected to improve tensile strength, water vapor barrier, and antibacterial capabilities. This study aims to find the optimal formula for biohybrid nanocomposite films composed of chitosan, ZnO-NPs, and SA. The full factorial design approach—4 × 2 with 3 replicates, i.e., two independent variables, namely %ZnO-NPs at 4 levels (0%, 0.5%, 1%, and 3%, w/w) and %SA at 2 levels (0% and 5%, w/w)—was utilized to optimize chitosan-based biohybrid nanocomposite films, with the primary interests being antibacterial activities, water vapor barrier, and tensile strength. The incorporation of ZnO-NPs into chitosan films could increase antibacterial activity, while SA decreased it. The addition of SA had a good effect only in decreasing water vapor transmission rate (WVTR) values but a detrimental effect on other film properties mentioned above. The incorporation of ZnO-NPs enhanced all functional packaging properties of interest. The suggested solution of the optimization study has been validated. As a result, the formula with the inclusion of 1% ZnO-NPs without SA is optimal for the fabrication of active antibacterial films with excellent multifunctional packaging capabilities.
Kinetics of Oxygen Exchange and N2O Decomposition Reaction over MeOx/CeO2 (Me = Fe, Co, Ni) Catalysts
Authors: Sadovskaya Ekaterina , Pinaeva Larisa , Skazka Valerii , Prosvirin Igor
Published: January 2023

MeOx/CeO2 (Me = Fe, Co, Ni) samples were tested in an 18O2 temperature-programmed isotope exchange and N2O decomposition (deN2O). A decrease in the rate of deN2O in the presence of oxygen evidences the competitive adsorption of N2O and O2 on the same sites. A study of isotope oxygen exchange revealed dissociative oxygen adsorption with the subsequent formation of surface oxygen species. The same species, more probably, result from N2O adsorption and the following N2 evolution to the gas phase. We supposed the same mechanism of O2 formation from surface oxygen species in both reactions, including the stages responsible for its mobility. A detailed analysis of the kinetics of isotope exchange has been performed, and the rates of one-atom (RI) and two-atom (RII) types of exchange were evaluated. The rate of the stage characterizing the mobility of surface oxygen was calculated, supposing the same two-step mechanism was relevant for both types of exchange. The effect of oxygen mobility on the kinetics of deN2O was estimated. An analysis of the possible pathways of isotope transfer from MeOx to CeOx showed that direct oxygen exchange on the Me–Ce interface makes a valuable contribution to the rate of this reaction. The principal role of the Me–Ce interface in deN2O was confirmed with independent experiments on FeOx/CeO2 samples with a different iron content.
Hard Wear-Resistant Ti-Si-C Coatings for Cu-Cr Electrical Contacts
Authors: Kiryukhantsev-Korneev Ph. , Sytchenko A. , Moskovskikh D. , Kuskov K. , Volkova L. , Poliakov M. , Pogozhev Y. , Yudin S. , Yakushko E. , Nepapushev A.
Published: January 2023

In this study, hard wear-resistant Ti-Si-C coatings were deposited on Cu-Cr materials to improve their performance as sliding electrical contact materials. A ceramic disk composed of Ti3SiC2 and TiC phases was used as a target for DC magnetron sputtering to deposit the coatings. The influence of the power supplied to the magnetron on the chemical composition, structure, and friction coefficient of the coatings was examined. The coatings demonstrated high hardness (23–25 GPa), low wear rate (1–3 × 10−5 mm3/N/m) and electrical resistance (300 μOhm·cm), and fair resistance to electroerosion. The coating deposited at 450 W for 30 min displayed optimal properties for protecting the Cu-Cr alloy from the arc effect.
Influencing Mechanism of Titanium-Extracted Tailing Slag on the Strength of CaO Steel Slag Hardened Paste
Authors: Tang Song , Peng Tongjiang , Sun Hongjuan , Ding Wenjin , Luo Liming
Published: January 2023

Hardened pastes with different mass percentages of steel slag (SS)/titanium-extracted tailing slag (TETS) were prepared under fixed CaO content to determine the influencing mechanism of TETS on the strength of CaO SS hardened paste. Furthermore, the effects and laws of curing time and SS/TETS ratios on the strength of hardened pastes were also investigated in this study. Importantly, hydration products, microstructures and the micro-area compositions of hardened pastes were analysed using X-ray diffraction, Fourier-transform infrared spectroscopy and scanning electron microscopy–energy dispersive spectrometer, respectively, to reveal the influencing mechanism of TETS on the CaO SS hardened pastes. The results demonstrated that the early strength of hardened pastes increases considerably following the inclusion of TETS. Specifically, the strength of the sample with an SS/TETS ratio of 22.5:67.5 at 1 d can be increased by more than 14 times. Notably, its strength at 90 days reached 19.36 MPa. Moreover, the diffraction peaks of calcite and C-S-H in the samples were also strengthened. Meanwhile, a diffraction peak of hydrocalumite appeared, and the calcites in the samples were curled up. When the SS/TETS ratio was equal to or more than 45:45, a diffraction peak of Ca(OH)2 appeared in the sample. Only a diffraction peak of Ca(OH)2 and weak diffraction peaks of calcite and C-S-H were observed in the samples without TETS, but there was no diffraction peak of hydrocalumite. The strength at 90 days was only 4.92 MPa. The increased strength of the hardened paste is closely related to the production of new phases after adding TETS. Solid particles in the hardened paste are cemented into a whole because of the hydration of C-S-H. Calcite forms the skeleton of the hardened pastes, whereas hydrocalumite fills in the pores among particles in hardened pastes, thus making them more compacted. As a result, there is increased.
Decarburization in Laser Surface Hardening of AISI 420 Martensitic Stainless Steel
Authors: Aprilia Aprilia , Maharjan Niroj , Zhou Wei
Published: January 2023

Decarburization deteriorates the surface mechanical properties of steel. It refers to the loss of carbon from steel’s surface when exposed to an open-air environment in elevated-temperature conditions. Despite the short interaction time and fast thermal cycle of the laser surface-hardening process, decarburization may still occur. This paper investigates if decarburization occurs during the laser surface hardening of AISI 420 martensitic stainless steel. For comparison, surface-hardening results and decarburizations in a conventional air furnace-heated hardening process (water-quenched and air-cooled) of the same steel material were also investigated. Decarburization seems to have occurred in the laser surface hardening of AISI 420SS. However, the decarburization might not be significant, as the hardness of the steel’s surface was increased more than three times to 675 HV during the laser surface hardening, and the hardness drop due to decarburization was estimated to be only 3% with the decarburization depth of 40 μm. Simulations using ThermoCalc software to get the carbon concentration profiles along the depth for both laser-hardened and furnace-heated samples were also investigated.
Tet-Regulated Expression and Optical Clearing for In Vivo Visualization of Genetically Encoded Chimeric dCas9/Fluorescent Protein Probes
Authors: Maloshenok Liliya , Abushinova Gerel , Kazachkina Natalia , Bogdanov Alexei , Zherdeva Victoria
Published: January 2023

The catalytically inactive mutant of Cas9 (dCas9) endonuclease has multiple biomedical applications, with the most useful being the activation/repression of transcription. dCas9 family members are also emerging as potential experimental tools for gene mapping at the level of individual live cells and intact tissue. We performed initial testing on a set of tools for Cas9-mediated visualization of nuclear compartments. We investigated doxycycline (Dox)-inducible (Tet-On) intracellular distribution of constructs encoding dCas9 orthologs from St. thermophilus (St) and N. meningitides (Nm) fused with EGFP and mCherry fluorescent proteins (FP) in human A549 cells. We also studied time-dependent expression of these chimeric fluorescent constructs (dCas9-FP) after Tet-On induction in live cells and compared it with the time course of dCas9-FP expression in experimental dCas9-FP-expressing tumor xenografts using a combination of fluorescence imaging and in vivo contrast-assisted magnetic resonance imaging for assessing the extent of tumor perfusion. In vivo Dox-induction of mCherry-chimera expression occurred in tumor xenografts as early as 24 h post-induction and was visualized by using optical clearing (OC) of the skin. OC via topical application of gadobutrol enabled high-contrast imaging of FP expression in tumor xenografts due to a 1.1–1.2-fold increase in FI in both the red and green channels.
Fragmentation Mechanism in a Nitrogen Dielectric Barrier Discharge Plasma on Fluoropolymer Polymer Films
Authors: Fotouhiardakani Faegheh , Laurent Morgane , Profili Jacopo , Ravichandran Sethumadhavan , Dorairaju Gowri , Laroche Gaetan
Published: January 2023

Due to their chemical inertness and low friction coefficient, fluoropolymers are today widely employed in sectors of activity as diverse and distinct as the textile industry, architectural sector, and medicine. However, their low surface energy results in poor adhesion, for example, when used for a component in a composite device with multiple other materials. Among the techniques used to enhance their adhesion, atmospheric pressure discharges provide a fast and low-cost method with a reduced environmental impact. Although this approach has proven to be efficient, the different chemical and physical processes in the discharge remain not fully understood. In this study, fluoropolymer surfaces were modified using an atmospheric pressure dielectric barrier discharge in a nitrogen and organic precursor environment. To prevent any damage to fluoropolymer surfaces, the dissipated power in the discharges was tuned by applying a duty cycle. Evidence shows that plasma treatment allows for the incorporation of oxygen and nitrogen in the surface resulting in the formation of hydrophilic functionalities such as carbonyl groups both in ketone and amide form, amine, and hydroxyl groups after 180 s of treatment. Overall, the data reveal that the discharge duty cycle has more effect on the oxygen and carbon content in the coating than the precursor concentration. In addition, increasing the precursor concentration limits the molecular fragmentation and nitrogen incorporation into the coating. These experiments enable the building of a better fundamental understanding of the formation mechanism of such chemical moieties at the fluoropolymer surface.
Grain Structure Formation and Texture Modification through Multi-Pass Friction Stir Processing in AlSi10Mg Alloy Produced by Laser Powder Bed Fusion
Authors: Heidarzadeh Akbar , Javidani Mousa , Mofarrehi Mohammadreza , Motalleb-nejad Pouyan , Mohammadzadeh Roghayeh , Jafarian Hamidreza , Chen X.-Grant
Published: January 2023

A new strategy is proposed to modify the grain structure and crystallographic texture of laser-powder bed fusion AlSi10Mg alloy using multi-pass friction stir processing (FSP). Accordingly, 1–3 passes of FSP with 100% overlap were performed. Scanning electron microscopy and electron backscattered diffraction were used for microstructural characterization. Continuous dynamic recrystallization and geometric dynamic recrystallization are the governing mechanisms of grain refinement during FSP. The stir zones have bimodal grain structures containing large and fine grains. The multi-pass FSP caused a considerable increase in the volume fraction of the large-grained area in the stir zone, which contained higher values of low-angle boundaries and sharp shear texture components of B(11¯2)[110] and B¯(1¯12¯)[1¯1¯0]. The formation of low-energy grain boundaries in the stir zone and alignment of the low-energy crystallographic planes with the surface of the sample made the strategy of using multi-pass FSP a promising candidate for corrosion resistance enhancement in future studies. Moreover, the detailed evolution of the grains, texture components, grain boundaries, and Si particles is discussed.
Surface Topography Description after Turning Inconel 718 with a Conventional, Wiper and Special Insert Made by the SPS Technique
Authors: Szablewski Piotr , Legutko Stanisław , Mróz Adrian , Garbiec Dariusz , Czajka Rafał , Smak Krzysztof , Krawczyk Bartłomiej
Published: January 2023

This paper presents a comparison of surface morphology obtained after machining Inconel 718 by the conventional insert, by Wiper insert and by using the cutting insert made by Spark Plasma Sintering (SPS). The shape of the special insert was obtained by employing Wire Electrical Discharge Machining (WEDM). The paper focuses on the description of surface topography after turning in dry and wet conditions. The performed investigation included longitudinal turning tests of Inconel 718 performed in a range of variable feeds. Surface topography measurements have been performed with the application of Nanoscan 855. The performed analysis includes a parametric evaluation of the obtained surfaces. With the Wiper insert, the Sa surface roughness parameter was obtained below 0.6 µm in the whole range of used feed rates. The surface roughness parameter Sa measured on the surface after machining by special insert depends on the cutting conditions (wet and dry machining). After, the dry machining parameter Sa, similar to the Wiper insert, was below 0.6 µm in the whole range of used feed rates. Unfortunately, cutting Inconel 718 using special insert with feed rate f = 0.25 mm/rev and cooling generated a surface with Sa parameter over 2 times higher than for the same feed rate without cooling, while this parameter, after turning by conventional insert, increases over 4 times using feed rate f = 0.25 mm/rev compared to feed rate f = 0.05 mm/rev during machining with cooling. This ratio is lower for conventional insert in dry machining because of sticking, which arises at the smallest feed rate according to previous research.
Influence of Short-Pulse Microwave Radiation on Thermochemical Properties Aluminum Micropowder
Authors: Mostovshchikov Andrei , Gubarev Fedor , Nazarenko Olga , Pestryakov Alexey
Published: January 2023

The thermochemical properties of Al micropowder after exposure to microwave irradiation were investigated. The Al micropowder was exposed to microwave irradiation in air with a frequency of 2.85 GHz, a power density of 8 W/cm2, and a pulse duration of 25 ns and 3 µs. The thermochemical parameters of the irradiated metal powders were determined by the method of thermal analysis at the heating in air. It was found that an increase in the duration of microwave pulses and irradiation time leads to the thermal annealing of the metal particles, and the thermal processes of melting and sintering begin to dominate over non-thermal processes. The specific thermal effect of irradiated Al micropowder oxidation increases from 7744 J/g to 10,154 J/g in comparison with the unirradiated powder. The modeling of thermal heating processes of aluminum (Al) micropowder under the action of pulsed microwave radiation has been performed. It is shown that with an increase in the duration of microwave pulses and irradiation time, a significant heating of the Al micropowder occurs, leading to its melting and sintering. The results of modeling on the action of microwave radiation on the Al micropowder were compared with experimental results.
Flame-Retardant Foamed Material Based on Modified Corn Straw Using Two Nitrogenous Layers
Authors: Su Qiong , Wang Hongling , Wang Yanbin , Liang Shuang , Pang Shaofeng , Zhao Xiangfei , Sun Xiyang , Shi Xiaoqin , Zhao Jun
Published: January 2023

Foamed materials based on a biopolymer of crop straws are environmentally friendly, but ignitability limits their application. In this study, two nitrogenous layers were introduced onto corn straw by esterification and grafting for flame-retardant purposes. The inner thin nitrogenous layer consisted of imidazole rings, and the outer thick nitrogenous layer consisted of grafted acrylamide by a free-radical polymerization. The outer nitrogenous layer was simultaneously introduced into the system with a foaming process at 150 °C. Azodiisobutyronitrile acted both as initiator of the polymerization and the main foaming agent, and deionized water acted both as a plasticizing agent and an auxiliary foaming agent, which simplified the process and formula. It was found that cavities of two different sizes were formed. The nonuniformity of the foamed material was ascribed to the heterogeneous foaming precursor consisting of a rigid core and a soft shell. Its excellent flame-retard rating of UL-94 V-0 was ascribed to the two nitrogenous layers, which provides a sufficient nitrogen source for non-combustible gases. A relatively high compression strength of 17.7 MPa was partly due to the fiber of corn straw.
Solidification/Stabilization Technology for Radioactive Wastes Using Cement: An Appraisal
Authors: Luhar Ismail , Luhar Salmabanu , Abdullah Mohd Mustafa Al Bakri , Sandu Andrei Victor , Vizureanu Petrica , Razak Rafiza Abdul , Burduhos-Nergis Dumitru Doru , Imjai Thanongsak
Published: January 2023

Across the world, any activity associated with the nuclear fuel cycle such as nuclear facility operation and decommissioning that produces radioactive materials generates ultramodern civilian radioactive waste, which is quite hazardous to human health and the ecosystem. Therefore, the development of effectual and commanding management is the need of the hour to make certain the sustainability of the nuclear industries. During the management process of waste, its immobilization is one of the key activities conducted with a view to producing a durable waste form which can perform with sustainability for longer time frames. The cementation of radioactive waste is a widespread move towards its encapsulation, solidification, and finally disposal. Conventionally, Portland cement (PC) is expansively employed as an encapsulant material for storage, transportation and, more significantly, as a radiation safeguard to vigorous several radioactive waste streams. Cement solidification/stabilization (S/S) is the most widely employed treatment technique for radioactive wastes due to its superb structural strength and shielding effects. On the other hand, the eye-catching pros of cement such as the higher mechanical strength of the resulting solidified waste form, trouble-free operation and cost-effectiveness have attracted researchers to employ it most commonly for the immobilization of radionuclides. In the interest to boost the solidified waste performances, such as their mechanical properties, durability, and reduction in the leaching of radionuclides, vast attempts have been made in the past to enhance the cementation technology. Additionally, special types of cement were developed based on Portland cement to solidify these perilous radioactive wastes. The present paper reviews not only the solidification/stabilization technology of radioactive wastes using cement but also addresses the challenges that stand in the path of the design of durable cementitious waste forms for these problematical functioning wastes. In addition, the manuscript presents a review of modern cement technologies for the S/S of radioactive waste, taking into consideration the engineering attributes and chemistry of pure cement, cement incorporated with SCM, calcium sulpho–aluminate-based cement, magnesium-based cement, along with their applications in the S/S of hazardous radioactive wastes.
Micron- and Nanosized Alloy Particles Made by Electric Explosion of W/Cu-Zn and W/Cu/Ni-Cr Intertwined Wires for 3D Extrusion Feedstock
Authors: Lerner Marat , Suliz Konstantin , Pervikov Aleksandr , Tarasov Sergei
Published: January 2023

A novel approach to electric explosion of intertwined wires to obtain homogeneous powder mixtures intended for preparing feedstock for extrusion 3D printing has been applied. The powder were composed of spherical micron- and nano-sized W/Cu particles in-situ alloyed by Zn and Ni during electric explosion of intertwined dissimilar metal wires is offered. The mean particle size measured by micron-sized particles was not more than 20 μm. The average number size of these particles was 3 μm and it was dependent on the energy input. The powders contained phases such as α-W, β-W/W3O as well as FCC α-Cu(Zn) and α-Cu(Ni) solid solutions with the crystalline lattice parameters 3.629 and 3.61 A, respectively.
Conversion of a Small-Size Passenger Car to Hydrogen Fueling: Simulation of CCV and Evaluation of Cylinder Imbalance
Authors: Irimescu Adrian , Vaglieco Bianca Maria , Merola Simona Silvia , Zollo Vasco , De Marinis Raffaele
Published: January 2023

In the efforts to achieve zero-emission transportation, hydrogen offers a valid choice as a complete replacement of gasoline. Adapting spark ignition (SI) engines to this alternative fuel can be implemented with relatively minor changes and limited investment in added components. The conversion of a small-size passenger car to hydrogen fueling was evaluated initially from the perspective of achievable range and peak power. Overall, the concept was found to be feasible and comparable to the fully electric version of the vehicle. Cylinder imbalance was found to be one of the possible issues compared to gasoline operation. This study looks in more detail at cycle-to-cycle variability (CCV) and how this could influence vehicle dynamics as well as noise–harshness–vibration (NHV). CCV was simulated with a 0D/1D approach in vehicle-relevant engine speed–load conditions. A dedicated laminar flame speed sub-model was implemented so as to include fuel chemistry effects, while CCV was simulated by inducing perturbations in the initial combustion stages and fuel system characteristics as well as variation of air–fuel ratio throughout flame propagation. Significant improvement of stability was predicted with hydrogen, while cylinder imbalance was found to be one of the main sources of variability. Applying algorithms that compensate for the imbalance through individual injection valve regulation may not be enough to mitigate the identified issue, and more extensive changes of control strategies could be required. The start of injection settings may need to be adapted for each operating condition to maximize the effect of H2 combustion stabilization.