bluuebunny/crossref_metadata_2025 huggingface dataset:
Growth of Pinus cembroides Zucc. in Response to Hydroclimatic Variability in Four Sites Forming the Species Latitudinal and Longitudinal Distribution Limits
Authors: Herrera-Soto Gerardo , González-Cásares Marcos , Pompa-García Marín , Camarero J. Julio , Solís-Moreno Raúl
Published: July 2018

Climate change modifies the distribution and dominance of forest tree species, particularly near their distribution limits. This study used tree-ring width data for Pinus cembroides Zucc. at its distribution limits in Mexico and the SW USA to assess how tree populations responded to hydroclimatic variability. Indexed ring-width chronologies were built and correlated with climate and drought records at four marginal stands. We found that P. cembroides responds differently to climatic conditions depending on the bioclimatic and biogeographic conditions, with the forests situated in the driest area (Nuevo León) presenting the highest growth association to maximum temperatures and drought, while the forest situated in the wettest area (Puebla) was the least correlated to these hydroclimatic factors. In particular, dry and hot conditions, during the prior autumn and winter, reduced radial growth. Drought conditions could result in more vulnerable forests at the driest sites. These results advance our understanding of the radial growth responses of P. cembroides and similar widely distributed trees to climatic change near their biogeographical limits.
What Can We Learn from an Early Test on the Adaptation of Silver Fir Populations to Marginal Environments?
Authors: Klisz Marcin , Ukalski Krzysztof , Ukalska Joanna , Jastrzębowski Szymon , Puchałka Radosław , Przybylski Paweł , Mionskowski Marcin , Matras Jan
Published: July 2018

In order to determine the adaptive potential of silver fir in the southeast of Poland, the stability of the height of its five-year-old progeny was analyzed. The study was conducted in two different population groups in a total of four environments, including one ecologically marginal environment. The linear mixed model was used to evaluate the differentiation of populations in terms of height growth. The genotype and genotype-by-environment interaction biplot (GGE) were used to verify the stability of height. The climate of populations origin, in relation to actual fir distribution in Poland, was verified based on principal components analysis (PCA) of bioclimatic parameters. The highest total variability was explained by the genotype-environment interaction effect (GE) (54.50%), while the genotype effect (G) explained 41.27% and only 4.23% was explained by the site effect. The result of height growth variations revealed the Komańcza site as the most representative among study sites, while the Lesko site characterized the highest discriminating ability. The progeny occurring in climatic conditions most different from the average testing conditions showed a heterogeneous growth reaction, only adapting to the marginal environment, while the progeny of the second population in this region as well as the northernmost one was characterized by a mean but stable growth. The westernmost population revealed maladaptation. The assessment of the adaptability of silver fir depends on the broad spectrum of test conditions considering the ecologically marginal environments.
Quantifying and Trending the Thermal Signal as an Index of Perfusion in Patients Sedated with Propofol
Authors: Rajasekaran Surender , Pressler Mark , Parker Jessica L. , Scales Alex , Andersen Nicholas J. , Olivero Anthony , Ballard John R. , McGough Robert
Published: July 2018

We examined the feasibility of a thermal imager smart phone attachment as a potential proxy of skin perfusion by assessing shifts in skin temperature following administration of the vasodilatory anesthetic propofol. Four limb distal extremity thermal images were taken before propofol administration and at 5-min intervals thereafter during monitored anesthesia. The study enrolled 60 patients with ages ranging from 1.3 to 18 years (mean 10.7 years old) from April 2016 to January 2017. Five minutes following propofol administration, the median temperature differential (delta temperature) between the core and extremity skin significantly decreased in both upper and lower extremities, 7.9 to 3.6 °C (p < 0.0001) and 12.1 to 6.9 °C (p < 0.0001), respectively. By 10 min, the median delta temperatures further decreased significantly in the upper (p = 0.0068) and lower extremities (p = 0.0018). There was a concordant decrease in mean blood pressure (MBP). These trends reverted back when the subject awoke. There was no significant difference between the four operators who used the camera (p = 0.0831). Blood pressure and time temperature change was the only value of significance. Mobil thermal imaging represents a non-invasive modality to assess perfusion in real time. Further studies are required to validate the clinical utility.
Drinking Water Nitrate and Human Health: An Updated Review
Authors: Ward Mary , Jones Rena , Brender Jean , De Kok Theo , Weyer Peter , Nolan Bernard , Villanueva Cristina , Van Breda Simone
Published: July 2018

Nitrate levels in our water resources have increased in many areas of the world largely due to applications of inorganic fertilizer and animal manure in agricultural areas. The regulatory limit for nitrate in public drinking water supplies was set to protect against infant methemoglobinemia, but other health effects were not considered. Risk of specific cancers and birth defects may be increased when nitrate is ingested under conditions that increase formation of N-nitroso compounds. We previously reviewed epidemiologic studies before 2005 of nitrate intake from drinking water and cancer, adverse reproductive outcomes and other health effects. Since that review, more than 30 epidemiologic studies have evaluated drinking water nitrate and these outcomes. The most common endpoints studied were colorectal cancer, bladder, and breast cancer (three studies each), and thyroid disease (four studies). Considering all studies, the strongest evidence for a relationship between drinking water nitrate ingestion and adverse health outcomes (besides methemoglobinemia) is for colorectal cancer, thyroid disease, and neural tube defects. Many studies observed increased risk with ingestion of water nitrate levels that were below regulatory limits. Future studies of these and other health outcomes should include improved exposure assessment and accurate characterization of individual factors that affect endogenous nitrosation.
The Impact of the Parameterisation of Physiographic Features of Urbanised Catchment Areas on the Spatial Distribution of Components of the Water Balance Using the WetSpass Model
Authors: Graf Renata , Jawgiel Kamil
Published: July 2018

An analysis was conducted of the activity of individual homogeneous Hydrological Response Units (HRUs) and their impact on the components of the spatially distributed water balance based on the example of two urbanised catchments of the city of Poznań (Western Poland). Water balance was developed using the WetSpass model and GIS spatial data, based on hydrometeorological data from the reference period of 1961–2000 including projected land usage changes and precipitation changes expected by 2025 in the city. The catchments were parameterised with reference to land usage, soil permeability, terrain declivities and the level of groundwater waters in summer and winter. The dependence between HRUs and their impact on components of the water balance was determined. Water balance forecasts have shown two-way changes in the components of approximately 12% of the catchments. A significant increase of surface runoff (an increase of 20–30 mm/HRU) at the expense of effective infiltration reduction (by 15–20 mm/HRU) was determined for arable land intended for development. An increase of infiltration and evapotranspiration at the expense of the surface runoff reduction is forecast for areas designed for urban afforestation. The tendency of increase of atmospheric precipitation within the city until 2025 was indicated by changes in the water balance components. Changes in the landscape resulting from urban expansion may lead to detrimental hydrological effects: accumulation of surface runoffs and occurrence of local flash flooding, as confirmed by the simulations carried out using the WetSpass model. The results may contribute to a more accurate understanding of the impact of urban landscape modification patterns on the water balance at the regional and local scale.
Assessing the Impacts of Streamside Ordinance Protection on the Spatial and Temporal Variability in Urban Riparian Vegetation
Authors: Weilert Trina E. , Ji Wei , Zubair Opeyemi A.
Published: July 2018

Preserving riparian vegetation is important for maintaining water quality and riparian functions. Streamside protection ordinances have been widely established in many rapidly urbanizing areas, however, there has been a lack of assessment of the effectiveness of such ordinances. A study was conducted to determine the effectiveness of riparian vegetation preservation with and without ordinance protection. SPOT imagery was used to classify landscape changes over time (1992 through 2012) across multiple jurisdictions and pre- and post-ordinance implementation periods. Results indicated the spatial and temporal patterns of vegetation change differed by administrative areas and ordinance boundaries. The rate of tree loss and gains in developed lands in ordinance-protected areas generally increased following implementation of ordinances but at a lower rate than in non-ordinance areas. These findings suggest spatial and temporal monitoring of riparian ordinance implementation across adjacent jurisdictions is important to ensure the full effects of the ordinance protection on stream systems. Such monitoring and assessments can be used by local decision makers to adapt existing ordinances or in the development of new ordinances.
A New Method for the Assessment of Spatial Accuracy and Completeness of OpenStreetMap Building Footprints
Authors: Brovelli Maria Antonia , Zamboni Giorgio
Published: July 2018

OpenStreetMap (OSM) is currently the largest openly licensed collection of geospatial data, widely used in many projects as an alternative to or integrated with authoritative data. One of the main criticisms against this dataset is that, being a collaborative product created mainly by citizens without formal qualifications, its quality has not been assessed and therefore its usage can be questioned for some applications. This paper provides a map matching method to check the spatial accuracy of the building footprint layer, based on a comparison with a reference dataset. Moreover, from the map matching and a similarity check, buildings can be detected and therefore an index of completeness can also be computed. This process has been applied in Lombardy, a region in Northern Italy, covering an area of 23,900 km2 and comprising respectively about 1 million buildings in OSM and 2.8 million buildings in the authoritative dataset. The results of the comparison show that the positional accuracy of the OSM buildings is at least compatible with the quality of the reference dataset at the scale of 1:5000 since the average deviation, with respect to the authoritative map, is below the expected tolerance of 3 m. The analysis of completeness, given in terms of the number of buildings appearing in the authoritative dataset and not present in OSM, shows an average percentage in the whole region equal to 57%. However, worth noting that the opposite, namely the number of buildings in OSM and not in the reference dataset, is not zero, but corresponds to 9%. The OSM building map can therefore be considered to be a valid base map for direct use (territorial frameworks, map navigation, urban analysis, etc.) and for derived use (background for the production of thematic maps) in all those cases where an accuracy corresponding to 1:5000 is required. Moreover it could be used for integrating the authoritative map at this scale (or smaller) where it is not complete and a rigorous quality certification in terms of metric precision is not required.
Shp2graph: Tools to Convert a Spatial Network into an Igraph Graph in R
Authors: Lu Binbin , Sun Huabo , Harris Paul , Xu Miaozhong , Charlton Martin
Published: July 2018

In this study, we introduce the R package shp2graph, which provides tools to convert a spatial network into an ‘igraph’ graph of the igraphR package. This conversion greatly empowers a spatial network study, as the vast array of graph analytical tools provided in igraph are then readily available to the network analysis, together with the inherent advantages of being within the R statistical computing environment and its vast array of statistical functions. Through three urban road network case studies, the calculation of road network distances with shp2graph and with igraph is demonstrated through four key stages: (i) confirming the connectivity of a spatial network; (ii) integrating points/locations with a network; (iii) converting a network into a graph; and (iv) calculating network distances (and travel times). Throughout, the required R commands are given to provide a useful tutorial on the use of shp2graph.
Newborn Hearing Screening in Bavaria—Is It Possible to Reach the Quality Parameters?
Authors: Brockow Inken , Söhl Kristina , Nennstiel Uta
Published: July 2018

Since the 1 January, 2009, newborn hearing screening (NHS) has been obligatory for every child in Germany. NHS is part of the Pediatrics Directive of the Federal Joint Committee. In this directive, details of the procedures and screening quality to be achieved are given. We evaluate if these quality criteria were met in Bavaria in 2016. The NHS data of children born in 2016 in Bavaria were evaluated for quality criteria, such as screening coverage in screening facilities, screening methods, referral rate (rate of failed tests at discharge) and a child’s age at the diagnosis of a hearing disorder. NHS was documented for 116,776 children born in Bavaria in 2016. In the first step, 78,904 newborns were screened with transient evoked otoacoustic emissions and 37,865 with automated auditory brainstem response. Of these, 9182 (7.8%) failed the first test in one or both ears. A second screening before discharge was performed on 53.3% of the newborns with a refer result in the first test, out of which 58.7% received a pass result. After the screening process, 4.6% of the newborns were discharged with a refer result. Only 18% of the first controls after discharge were performed by a pediatric audiologist. In 37.9% of the newborns, the screening center intervened to assure the control of any failed screening test. The median age of diagnosis for bilateral hearing loss was 5.3 months. In Bavaria, NHS was implemented successfully. A tracking system for all children who failed the hearing screening test is pivotal for early diagnosis and therapy of children with hearing deficiency.
A Review and Classification of Assisted Living Systems
Authors: Byrne Caroline A. , Collier Rem , O’Hare Gregory M. P.
Published: July 2018

Europe’s social agenda for the “active elderly” is based upon a series of programs that provide a flexible infrastructure for their lives so that they are motivated, engaged in lifelong learning, and contributing to society. Economically speaking, Europe must engage in active aging research in order to avoid unsustainable health costs, and ambient assisted living (AAL) systems provide a platform for the elderly to remain living independently. This paper reviews research conducted within the area of AAL, and offers a taxonomy within which such systems may be classified. This classification distinguishes itself from others in that it categorises AAL systems in a top-down fashion, with the most important categories placed immediately to the left. In this paper, each section is explored further, and AAL systems are the focus. Entire AAL systems still cannot be fully evaluated, but their constituent technical parts can be assessed. The activities of daily living (ADLs) component was given further priority due to its potential for system evaluation, based on its ability to recognise ADLs with reasonable accuracy.
Temperature Acclimation Ability by an Oceanic Sea Skater, Halobatesgermanus, Inhabiting the Tropical Pacific Ocean
Authors: Furuki Takahiro , Fujita Hiroki , Nakajo Mitsuru , Harada Tetsuo
Published: July 2018

Temperature acclimation and heat shock experiments were performed on adult oceanic skaters, Halobates germanus, inhabiting the tropical Pacific Ocean. Acclimation for 10 or 24 h to 25 °C or 28 °C promoted significantly lower cool coma temperatures by specimens than acclimation to 31 °C. After heat shock by exposure to the relatively moderate temperature of 32.5 °C for 12 h, 52.9% or 61.1%% of specimens died in the 24 h period following acclimation at 28 °C or 31 °C, respectively, whereas all survived when there was no experience of heat shock. The average cool coma temperature was 14 to 17 °C in the specimens which had suffered no heat shock, whereas it was much higher (22 to 23 °C) in specimens that had suffered heat shock. The lower survival rate and the higher cool coma temperature can be attributed to damage suffered by exposure to 32.5 °C. The upper limit of the surface water temperature in the tropical ocean (15° N to 15° S) is currently around 30 to 31 °C, and Halobates appear to have no experience in 32 to 33 °C environments. Nevertheless, 32 °C, i.e., a temperaturethat is only slightly higher than 30 to 31 °C, may occur in the future due to global warming. This species may develop resistance to 32 to 33 °C in the near future.
Numerical and Experimental Analysis of the Gear Size Influence on Density Variations and Distortions during the Manufacturing of PM Gears with an Innovative Powder Processing Route Incorporating HIP
Authors: Khodaee Alireza , Melander Arne
Published: July 2018

The paper is the result of research intended to develop a process route for the manufacturing of powder metallurgical (PM) gears for application in transmissions units for heavy duty powertrain applications. The main problem of PM for such applications is that the generated pores that occur through conventional pressing and sintering processes reduce the gear strength, which reduces the capacity for power transmission by the gear. In prior work, removing the pores and reaching 100% density by adding Hot Iso-static Pressing (HIP) after two times pressing and two times sintering steps in the process route was suggested to solve the mentioned problem. During the investigations of this work it was revealed that the gear dimensions could influence the process results with respect to geometrical distortions. In this paper we have presented a finite element (FE) model based analysis on how the gear geometrical parameters influenced the distortions occurring in HIP. The simulation model is validated with experiments. Furthermore, the simulation model is used to create a prediction model for further investigations. The research showed that PM gears with different sizes during the proposed process route behaved differently in terms of distortions. This was illustrated with a series of simulations with different gear geometries. A regression model was developed based on the FE results for further practical predictive use. The distortions caused by HIP should be considered in the process design to prevent expensive post processes afterwards to reach the gear with accurate geometry and keep the costs of manufacturing low. It is concluded that it is possible to use the innovative process route including HIP to reach the full density and close all the open pores but not for all kind of gear geometries.
Physician-Reported Benefits and Barriers to Clinical Implementation of Genomic Medicine: A Multi-Site IGNITE-Network Survey
Authors: Owusu Obeng Aniwaa , Fei Kezhen , Levy Kenneth D. , Elsey Amanda R. , Pollin Toni I. , Ramirez Andrea H. , Weitzel Kristin W. , Horowitz Carol R.
Published: July 2018

Genetic medicine is one of the key components of personalized medicine, but adoption in clinical practice is still limited. To understand potential barriers and provider attitudes, we surveyed 285 physicians from five Implementing GeNomics In pracTicE (IGNITE) sites about their perceptions as to the clinical utility of genetic data as well as their preparedness to integrate it into practice. These responses were also analyzed in comparison to the type of study occurring at the physicians’ institution (pharmacogenetics versus disease genetics). The majority believed that genetic testing is clinically useful; however, only a third believed that they had obtained adequate training to care for genetically “high-risk” patients. Physicians involved in pharmacogenetics initiatives were more favorable towards genetic testing applications; they found it to be clinically useful and felt more prepared and confident in their abilities to adopt it into their practice in comparison to those participating in disease genetics initiatives. These results suggest that investigators should explore which attributes of clinical pharmacogenetics (such as the use of simplified genetics-guided recommendations) can be implemented to improve attitudes and preparedness to implement disease genetics in care. Most physicians felt unprepared to use genetic information in their practice; accordingly, major steps should be taken to develop effective clinical tools and training strategies for physicians.
Modelling Land Sharing and Land Sparing Relationship with Rural Population in the Cerrado
Authors: Pompeu João , Soler Luciana , Ometto Jean
Published: July 2018

Agricultural expansion and intensification enabled growth of food production but resulted in serious environmental changes. In light of that, debates concerning sustainability in agriculture arises on scientific literature. Land sharing and land sparing are two opposite models for framing agricultural sustainability. The first aims to integrate agricultural activities with biodiversity conservation by means of enhancing the quality of the agricultural matrix in the landscape towards a wildlife friendly matrix. The other model aims to spare natural habitats from agriculture for conservation. This work aimed to explore spatial evidences of land sharing/sparing and its relationship with rural population in the Brazilian Cerrado. A Land Sharing/Sparing Index based on TerraClass Cerrado map was proposed. Spatial analysis based on Global and Local Moran statistics and Geographically Weighted Regression were made in order to explore the influence of local rural population on the probability of spatial land sharing/sparing clusters occurrence. Spatial patterns of land sharing were found in the Cerrado and a positive association with rural population was found in some regions, such as in its northern portion. Land use policies should consider regional infrastructural and participative governance potentialities. The results suggests possible areas where joint agricultural activities and human presence may be favourable for biodiversity conservation.
Global Molecular Diversity of the Halotolerant Fungus Hortaea werneckii
Authors: Marchetta Alessia , Gerrits van den Ende Bert , Al-Hatmi Abdullah M. S. , Hagen Ferry , Zalar Polona , Sudhadham Montarop , Gunde-Cimerman Nina , Urzì Clara , De Hoog Sybren , De Leo Filomena
Published: July 2018

A global set of clinical and environmental strains of the halotolerant black yeast-like fungus Hortaea werneckii are analyzed by multilocus sequencing and AFLP, and physiological parameters are determined. Partial translation elongation factor 1-α proves to be suitable for typing because of the presence/absence of introns and also the presence of several SNPs. Local clonal expansion could be established by a combination of molecular methods, while the population from the Mediterranean Sea water also responds differently to combined temperature and salt stress. The species comprises molecular populations, which in part also differ physiologically allowing further diversification, but clinical strains did not deviate significantly from their environmental counterparts.
Hierarchical Characterization and Nanomechanical Assessment of Biomimetic Scaffolds Mimicking Lamellar Bone via Atomic Force Microscopy Cantilever-Based Nanoindentation
Authors: Wingender Brian , Ni Yongliang , Zhang Yifan , Taylor Curtis , Gower Laurie
Published: July 2018

The hierarchical structure of bone and intrinsic material properties of its two primary constituents, carbonated apatite and fibrillar collagen, when being synergistically organized into an interpenetrating hard-soft composite, contribute to its excellent mechanical properties. Lamellar bone is the predominant structural motif in mammalian hard tissues; therefore, we believe the fabrication of a collagen/apatite composite with a hierarchical structure that emulates bone, consisting of a dense lamellar microstructure and a mineralized collagen fibril nanostructure, is an important first step toward the goal of regenerative bone tissue engineering. In this work, we exploit the liquid crystalline properties of collagen to fabricate dense matrices that assemble with cholesteric organization. The matrices were crosslinked via carbodiimide chemistry to improve mechanical properties, and are subsequently mineralized via the polymer-induced liquid-precursor (PILP) process to promote intrafibrillar mineralization. Neither the crosslinking procedure nor the mineralization affected the cholesteric collagen microstructures; notably, there was a positive trend toward higher stiffness with increasing crosslink density when measured by cantilever-based atomic force microscopy (AFM) nanoindentation. In the dry state, the average moduli of moderately (X51; 4.8 ± 4.3 GPa) and highly (X76; 7.8 ± 6.7 GPa) crosslinked PILP-mineralized liquid crystalline collagen (LCC) scaffolds were higher than the average modulus of bovine bone (5.5 ± 5.6 GPa).
Study on Quasi-Static Uniaxial Compression Properties and Constitutive Equation of Spherical Cell Porous Aluminum-Polyurethane Composites
Authors: Bao Haiying , Li Aiqun
Published: July 2018

Quasi-static uniaxial compression properties and the constitutive equation of spherical cell porous aluminum-polyurethane composites (SCPA-PU composites) were investigated in this paper. The effects of relative density on the densification strain, plateau stress and energy absorption properties of the SCPA-PU composites were analyzed. It is found that the stress-strain curves of SCPA-PU composites consist of three stages: The linear elastic part, longer plastic plateau segment and densification region. The results also demonstrate that both the plateau stress and the densification strain energy of the SCPA-PU composites can be improved by increasing the relative density of the spherical cell porous aluminum (SCPA), while the densification strain of the SCPA-PU composites shows little dependence on the relative density of the SCPA. Furthermore, the applicability of three representative phenomenological models to the constitutive equations of SCPA-PU composites are verified and compared based on the experimental results. The error analysis result indicates that the Avalle model is the best model to characterize the uniaxial compression constitutive equation of SCPA-PU composites.
Enhancement Mechanism of the Dynamic Strength of Concrete Based on the Energy Principle
Authors: Ren Jie , Dang Faning , Wang Huan , Xue Yi , Fang Jianyin
Published: July 2018

This paper analyzes the relationship between the rates of change of elastic strain energy, the strength during the concrete failure process, and proposes that the increased dynamic strength of concrete was caused by the hysteresis effect of energy release—according to the basic principle of energy conversion. Dynamic Brazilian disc tests were carried out on concrete specimens, with diameter of 100 mm, by using the split Hopkinson pressure bar. Test results were obtained through using a gas gun, with an impact pressure of 0.15 MPa, 0.20 MPa and 0.25 MPa, respectively. The dynamic failure process of concrete is then reproduced by numerical calculation methods. Finally, the energy characteristics during the concrete failure process at different strain rates are studied, and the enhancement mechanism of the dynamic strength of concrete is verified. The results showed that the dynamic tensile strength of concrete increased by 9.79% when the strain rate increased by 61% from 60.25 s−1; and when the strain rate increased by 92.8% from 60.25 s−1, the dynamic tensile strength of the concrete rose by 46.28%. The rates of change of both input energy and dissipated energy meet at the peak stress of the material. The increases in rates of change for the two kinds of energy were not synchronized, so excess input energy could be stored as concrete strength increased. As a result, the extra energy stored after peak stress led to a higher degree of concrete fragmentation and greater kinetic energy of the fragment. These results offer research directions for improving the dynamic strength of concrete.
Causes of Pulmonary Fibrosis in the Elderly
Authors: López-Ramírez Cecilia , Suarez Valdivia Lionel , Rodríguez Portal Jose Antonio
Published: July 2018

Idiopathic pulmonary fibrosis (IPF) is the most common and most lethal type of idiopathic interstitial pneumonia. It is a chronic, aging-associated lung disease characterized by fibrotic foci and inflammatory infiltrates, with no cure and very limited therapeutic options. Although its etiology is unknown, several pathogenic pathways have been described that could explain this process, involving aging, environmental factors, genomic instability, loss of proteostasis, telomere attrition, epigenetic changes, mitochondrial dysfunction, cell senescence, and altered intercellular communication. One of the main prognostic factors for the development of IPF in broad epidemiological studies is age. The incidence increases with age, making this a disease that predominantly affects the elderly population, being exceptional under 45 years of age. However, the degree to which each of these mechanisms is involved in the etiology of the uncontrolled fibrogenesis that defines IPF is still unknown. Clarifying these questions is crucial to the development of points of intervention in the pathogenesis of the disease. This review briefly summarizes what is known about each possible etiological factor, and the questions that most urgently need to be addressed.
Forward Osmosis Application in Manufacturing Industries: A Short Review
Authors: Haupt Anita , Lerch André
Published: July 2018

Forward osmosis (FO) is a membrane technology that uses the osmotic pressure difference to treat two fluids at a time giving the opportunity for an energy-efficient water and wastewater treatment. Various applications are possible; one of them is the application in industrial water management. In this review paper, the basic principle of FO is explained and the state-of-the-art regarding FO application in manufacturing industries is described. Examples of FO application were found for food and beverage industry, chemical industry, pharmaceutical industry, coal processing, micro algae cultivation, textile industry, pulp and paper industry, electronic industry, and car manufacturing. FO publications were also found about heavy metal elimination and cooling water treatment. However, so far FO was applied in lab-scale experiments only. The up-scaling on pilot- or full-scale will be the essential next step. Long-term fouling behavior, membrane cleaning methods, and operation procedures are essential points that need to be further investigated. Moreover, energetic and economic evaluations need to be performed before full-scale FO can be implemented in industries.
Recovery of Gold and Iron from Cyanide Tailings with a Combined Direct Reduction Roasting and Leaching Process
Authors: Fu Pingfeng , Li Zhenyu , Feng Jie , Bian Zhenzhong
Published: July 2018

Cyanide tailings are the hazardous waste discharged after gold cyanidation leaching. The recovery of gold and iron from cyanide tailings was investigated with a combined direct reduction roasting and leaching process. The effects of reduction temperature, coal dosage and CaO dosage on gold enrichment into Au-Fe alloy (FexAu1−x) were studied in direct reduction roasting. Gold containing iron powders, i.e., Au-Fe alloy, had the gold grade of 8.23 g/t with a recovery of 97.46%. After separating gold and iron in iron powders with sulfuric acid leaching, ferrous sulfate in the leachate was crystallized to prepare FeSO4·7H2O with a yield of 222.42% to cyanide tailings. Gold enriched in acid-leaching residue with gold grade of 216.58 g/t was extracted into pregnant solution. The total gold recovery of the whole process reached as high as 94.23%. The tailings generated in the magnetic separation of roasted products, with a yield of 51.33% to cyanide tailings, had no toxic cyanide any more. The gold enrichment behaviors indicated that higher reduction temperature and larger dosage of coal and CaO could promote the allocation of more gold in iron phase rather than in slag phase. The mechanism for enriching gold from cyanide tailings into iron phase was proposed. This work provided a novel route to simultaneously recover gold and iron from cyanide tailings.
Retained Austenite Control for the Soft Machining of High-Hardness Tool Steels
Authors: Muro Maider , Artola Garikoitz , Leunda Josu , Soriano Carlos , Angulo Carlos
Published: July 2018

Most high-hardness tool steels comprising forming dies require expensive finish machining operations to compensate for the dimensional distortion and surface oxidation caused by the die heat treatment. Precipitation-hardening (PH) tool steels allow for soft finish machining followed by an aging treatment without major deformation or oxidation in the die, but exhibit poor wear performance owing to the lack of carbides in their structure. This drawback can be overcome by combining laser cladding technology, austenite retention, and cryogenic treatments. Hence, an alternative die manufacturing route based on laser cladding was explored. The forming surface of a modified chemistry tool steel die was subjected to cladding. The martensite finish (Mf) temperature of the steel was tuned to enhance austenite retention at room temperature. The cladded surface was then machined in a reduced-hardness condition resulting from retained austenite formation. Subsequent deep cryogenic treatment of the die favoured the retained-austenite-to-martensite transformation, thereby increasing the die hardness without major distortion or oxidation. This process combined the advantages of high-carbide-bearing tool steels and PH steels, allowing for a die with hardness exceeding 58 HRC to be finish machined at <52 HRC. Controlling the occurrence of retained austenite represents an effective strategy for achieving new manufacturing scenarios.
Liquid Metal Enabled Electrobiology: A New Frontier to Tackle Disease Challenges
Authors: Wang Xuelin , Ren Yi , Liu Jing
Published: July 2018

In this article, a new conceptual biomedical engineering strategy to tackle modern disease challenges, called liquid metal (LM) enabled electrobiology, is proposed. This generalized and simple method is based on the physiological fact that specially administrated electricity induces a series of subsequent desired biological effects, either shortly, transitionally, or permanently. Due to high compliance within biological tissues, LM would help mold a pervasive method for treating physiological or psychological diseases. As highly conductive and non-toxic multifunctional flexible materials, such LMs can generate any requested electric treating fields (ETFields), which can adapt to various sites inside the human body. The basic mechanisms of electrobiology in delivering electricity to the target tissues and then inducing expected outputs for disease treatment are interpreted. The methods for realizing soft and conformable electronics based on LM are illustrated. Furthermore, a group of typical disease challenges are observed to illustrate the basic strategies for performing LM electrobiology therapy, which include but are not limited to: tissue electronics, brain disorder, immunotherapy, neural functional recovery, muscle stimulation, skin rejuvenation, cosmetology and dieting, artificial organs, cardiac pacing, cancer therapy, etc. Some practical issues regarding electrobiology for future disease therapy are discussed. Perspectives in this direction for incubating a simple biomedical tool for health care are pointed out.
An Improved Phase-Robust Configuration for Vibration Amplitude-Phase Extraction for Capacitive MEMS Gyroscopes
Authors: Zheng Xudong , Liu Siqi , Lin Yiyu , Wu Haibin , Teng Lai , Jin Zhonghe
Published: July 2018

This paper presents for the first time an improved algorithm for vibration amplitude-phase information extraction of capacitive microelectromechanical systems (MEMS) gyroscopes. Amplitude and phase information resulting from the improved algorithm is insensitive to the phase variation of an interface capacitance-voltage (CV) circuit, thus both long time drift of the gyroscope and bias instability have been improved. Experimental results show that both the phase and amplitude information extracted using this improved algorithm is insensitive to phase variation of CV circuit which is in accordance with theory. Bias instability using this improved configuration is 0.64°/h, which is improved two times more than the configuration using traditional double-side-band (DSB) demodulation configuration, and 4.3 times more than the configuration using single-side-band (SSB) demodulation, respectively. Allan deviation analysis shows that the slow varying drift term using D&S configuration is effectively reduced due to its robustness to CV phase variation compared to test results using DSB or SSB configuration.
Stabilization of Microrobot Motion Characteristics in Liquid Media
Authors: Demircali Ali Anil , Uvet Huseyin
Published: July 2018

Magnetically actuated microrobot in a liquid media is faced with the problem of head-tilting reaction caused by its hydrodynamic structure and its speed while moving horizontally. When the instance microrobot starts a lateral motion, the drag force acting on it increases. Thus, the microrobot is unable to move parallel to the surface due to the existence of drag force that cannot be neglected, particularly at high speeds such as >5 mm/s. The effect of it scales exponentially at different speeds and the head-tilting angle of the microrobot changes relative to the reference surface. To the best of our knowledge, there is no prior study on this problem, and no solution has been proposed so far. In this study, we developed and experimented with 3 control models to stabilize microrobot motion characteristics in liquid media to achieve accurate lateral locomotion. The microrobot moves in an untethered manner, and its localization is carried out by a neodymium magnet (grade N48) placed inside its polymer body. This permanent magnet is called a carrier-magnet. The fabricated microrobot is levitated diamagnetically using a pyrolytic graphite placed under it and an external permanent magnet, called a lifter-magnet (grade N48), aligned above it. The lifter-magnet is attached to a servo motor mechanism which can control carrier-magnet orientation along with roll and pitch axes. Controlling the angle of this servo motor, together with the lifter-magnet, allowed us to cope with the head-tilting reaction instantly. Based on the finite element method (FEM), analyses that were designed according to this experimental setup, the equations giving the relation of microrobot speed with servo motor angle along with the microrobot head-tilting angle with servo motor angle, were derived. The control inputs were obtained by COMSOL® (version 5.3, COMSOL Inc., Stockholm, Sweden). Using these derived equations, the rule-based model, laser model, and hybrid model techniques were proposed in this study to decrease the head-tilting angle. Motion control algorithms were applied in di-ionized water medium. According to the results for these 3 control strategies, at higher speeds (>5 mm/s) and 5 mm horizontal motion trajectory, the average head-tilting angle was reduced to 2.7° with the ruled-based model, 1.1° with the laser model, and 0.7° with the hybrid model.
Editorial for Special Issue “Fluid Inclusions: Study Methods, Applications, and Case Histories”
Authors: Feely Martin
Published: July 2018

The pioneering work of H.C. Sorby [1] in the mid-19th century highlighted the scientific importance of fluid inclusions in minerals [...]
Synchrotron Nano-Diffraction Study of Thermally Treated Asbestos Tremolite from Val d’Ala, Turin (Italy)
Authors: Giacobbe Carlotta , Wright Jonathan P. , Di Giuseppe Dario , Zoboli Alessandro , Zapparoli Mauro , Gualtieri Alessandro F.
Published: July 2018

Nowadays, due to the adverse health effects associated with exposure to asbestos, its removal and thermal inertization has become one of the most promising ways for reducing waste risk management. Despite all the advances in structure analysis of fibers and characterization, some problems still remain that are very hard to solve. One challenge is the structure analysis of natural micro- and nano-crystalline samples, which do not form crystals large enough for single-crystal X-ray diffraction (SC-XRD), and their analysis is often hampered by reflection overlap and the coexistence of multiple fibres linked together. In this paper, we have used nano-focused synchrotron X-rays to refine the crystal structure of a micrometric tremolite fibres from Val d’Ala, Turin (Italy) after various heat treatment. The structure of the original fibre and after heating to 800 °C show minor differences, while the fibre that was heated at 1000 °C is recrystallized into pyroxene phases and cristobalite.
Facile Strategy for Synthesizing Non-Stoichiometric Monoclinic Structured Tungsten Trioxide (WO3−x) with Plasma Resonance Absorption and Enhanced Photocatalytic Activity
Authors: Chen Shihao , Xiao Yang , Xie Wei , Wang Yinhai , Hu Zhengfa , Zhang Wei , Zhao Hui
Published: July 2018

Oxygen vacancy defects play an important role in improving the light-capturing and photocatalytic activity of tungsten trioxide (WO3). However, the hydrogen treatment method that is commonly used to introduce oxygen vacancies is expensive and dangerous. Therefore, the introduction and control of oxygen vacancy defects in WO3 remains a challenge. Here, we demonstrated that oxygen vacancies could be successfully introduced into WO3−x while using a facile method through low temperature annealing in alcohol. The obtained WO3−x samples with optimal oxygen vacancies showed strong absorption of light, extending from the ultraviolet to the visible and near-infrared regions, and exhibits strong plasmon resonance from 400–1200 nm peaking at approximately 800 nm. When compared to pristine WO3, the photocatalytic activity of WO3−x was greatly improved in the ultraviolet and visible regions. This study provides a simple and efficient method to generate oxygen vacancies in WO3 for photocatalysis, which may be applied in the photoelectrochemical, electrochromic, and photochromic fields. Because oxygen vacancy is a common characteristic of metal oxides, the findings that are presented herein may be extended to other metal oxides.
Femtosecond Laser-Based Modification of PDMS to Electrically Conductive Silicon Carbide
Authors: Nakajima Yasutaka , Hayashi Shuichiro , Katayama Akito , Nedyalkov Nikolay , Terakawa Mitsuhiro
Published: July 2018

In this paper, we experimentally demonstrate femtosecond laser direct writing of conductive structures on the surface of native polydimethylsiloxane (PDMS). Irradiation of femtosecond laser pulses modified the PDMS to black structures, which exhibit electrical conductivity. Fourier-transform infrared (FTIR) and X-ray diffraction (XRD) results show that the black structures were composed of β-silicon carbide (β-SiC), which can be attributed to the pyrolysis of the PDMS. The electrical conductivity was exhibited in limited laser power and scanning speed conditions. The technique we present enables the spatially selective formation of β-SiC on the surface of native PDMS only by irradiation of femtosecond laser pulses. Furthermore, this technique has the potential to open a novel route to simply fabricate flexible/stretchable MEMS devices with SiC microstructures.
Preparation of Filtration Sorptive Materials from Nanofibers, Bicofibers, and Textile Adsorbents without Binders Employment
Authors: Otrisal Pavel , Obsel Vladimir , Buk Jan , Svorc Lubomír
Published: July 2018

The article deals with the preparation and possibilities of using combined filtration sorption systems usable for the construction of folded filters or respirators. The studied materials are made of several structural layers—a filter membrane made of polymeric nanofibers, an adsorbent containing active carbon or porous silicon dioxide nanofibers, and a supporting or cover nonwoven bicomponent fabric. The layers are connected only by pressure at an elevated temperature without the use of binders, according to utility model PUV 31 375. The result is a compact fabric material of textile character with a high permeability, good mechanical resistance, which effectively catches the submicron particles and the gases of the organic substances. The prepared samples of the filter sorptive material have been evaluated not only from the point of view of morphology and microstructure, but also from the point of view of the capture of pollutants.
Cancer Prevention and Therapy with Polyphenols: Sphingolipid-Mediated Mechanisms
Authors: Dei Cas Michele , Ghidoni Riccardo
Published: July 2018

Polyphenols, chemically characterized by a polyhydroxylated phenolic structure, are well known for their widespread pharmacological properties: anti-inflammatory, antibiotic, antiseptic, antitumor, antiallergic, cardioprotective and others. Their distribution in food products is also extensive especially in plant foods such as vegetables, cereals, legumes, fruits, nuts and certain beverages. The latest scientific literature outlines a resilient interconnection between cancer modulation and dietary polyphenols by sphingolipid-mediated mechanisms, usually correlated with a modification of their metabolism. We aim to extensively survey this relationship to show how it could be advantageous in cancer treatment or prevention by nutrients. From this analysis it emerges that a combination of classical chemotherapy with nutrients and especially with polyphenols dietary sources may improve efficacy and decreases negative side effects of the antineoplastic drug. In this multifaceted scenario, sphingolipids play a pivotal role as bioactive molecules, emerging as the mediators of cell proliferation in cancer and modulator of chemotherapeutics.