bluuebunny/crossref_metadata_2025 huggingface dataset:
Evaluate the Toxicity of Pyrethroid Insecticide Cypermethrin before and after Biodegradation by Lysinibacillus cresolivuorans Strain HIS7
Authors: Saied Ebrahim , Fouda Amr , Alemam Ahmed M. , Sultan Mahmoud H. , Barghoth Mohammed G. , Radwan Ahmed A. , Desouky Salha G. , Azab Islam H. El , Nahhas Nihal El , Hassan Saad El-Din
Published: September 2021

Herein, bacterial isolate HIS7 was obtained from contaminated soil and exhibited high efficacy to degrade pyrethroid insecticide cypermethrin. The HIS7 isolate was identified as Lysinibacillus cresolivuorans based on its morphology and physiology characteristics as well as sequencing of 16S rRNA. The biodegradation percentages of 2500 ppm cypermethrin increased from 57.7% to 86.9% after optimizing the environmental factors at incubation condition (static), incubation period (8-days), temperature (35 °C), pH (7), inoculum volume (3%), and the addition of extra-carbon (glucose) and nitrogen source (NH4Cl2). In soil, L. cresolivuorans HIS7 exhibited a high potential to degrade cypermethrin, where the degradation percentage increased from 54.7 to 93.1% after 7 to 42 days, respectively. The qualitative analysis showed that the bacterial degradation of cypermethrin in the soil was time-dependent. The High-Performance Liquid Chromatography (HPLC) analysis of the soil extract showed one peak for control at retention time (R.T.) of 3.460 min and appeared three peaks after bacterial degradation at retention time (R.T.) of 2.510, 2.878, and 3.230 min. The Gas chromatography–mass spectrometry (GC–MS) analysis confirmed the successful degradation of cypermethrin by L. cresolivuorans in the soil. The toxicity of biodegraded products was assessed on the growth performance of Zea mays using seed germination and greenhouse experiment and in vitro cytotoxic effect against normal Vero cells. Data showed the toxicity of biodegraded products was noticeably decreased as compared with that of cypermethrin before degradation.
A Critical Review of the Current Global Ex Situ Conservation System for Plant Agrobiodiversity. II. Strengths and Weaknesses of the Current System and Recommendations for Its Improvement
Authors: Engels Johannes M. M. , Ebert Andreas W.
Published: September 2021

In this paper, we review gene bank operations that have an influence on the global conservation system, with the intention to identify critical aspects that should be improved for optimum performance. We describe the role of active and base collections and the importance of linking germplasm conservation and use, also in view of new developments in genomics and phenomics that facilitate more effective and efficient conservation and use of plant agrobiodiversity. Strengths, limitations, and opportunities of the existing global ex situ conservation system are discussed, and measures are proposed to achieve a rational, more effective, and efficient global system for germplasm conservation and sustainable use. The proposed measures include filling genetic and geographic gaps in current ex situ collections; determining unique accessions at the global level for long-term conservation in virtual base collections; intensifying existing international collaborations among gene banks and forging collaborations with the botanic gardens community; increasing investment in conservation research and user-oriented supportive research; improved accession-level description of the genetic diversity of crop collections; improvements of the legal and policy framework; and oversight of the proposed network of global base collections.
Correction: Al-Askar et al. Discovering Penicillium polonicum with High-Lytic Capacity on Helianthus tuberosus Tubers: Oil-Based Preservation for Mold Management. Plants 2021, 10, 413
Authors: Al-Askar Abdulaziz A. , Rashad Ehsan M. , Ghoneem Khalid M. , Mostafa Ashraf A. , Al-Otibi Fatimah O. , Saber WesamEldin I. A.
Published: September 2021

The authors would like to advise that several corrections have been made to the original article [...]
Benefits of Cardamom (Elettaria cardamomum (L.) Maton) and Turmeric (Curcuma longa L.) Extracts for Their Applications as Natural Anti-Inflammatory Adjuvants
Authors: Cárdenas Garza Gustavo R. , Elizondo Luévano Joel H. , Bazaldúa Rodríguez Aldo F. , Chávez Montes Abelardo , Pérez Hernández Raymundo A. , Martínez Delgado Ameyalli J. , López Villarreal Sonia M. , Rodríguez Rodríguez José , Sánchez Casas Rosa M. , Castillo Velázquez Uziel , Rodríguez Luis Osvelia E.
Published: September 2021

The genus Zingiberaceae has been widely used for phytotherapeutic purposes in traditional medicine throughout the world for its anti-inflammatory activity. Experimental studies have established that inflammation caused by chronic infections represents a risk factor for different forms of cancer. The objective of this study was focused on determining the anti-inflammatory capacity and cytotoxic activity of aqueous extracts of Elettaria cardamomum (cardamom) and Curcuma Longa (turmeric). The extracts were obtained by maceration and, through GC-MS/MS, a total of 11 different chemical components were determined in the aqueous extract of cardamom and 7 in the extract of turmeric. The main compounds found in cardamom and turmeric were α-terpinyl acetate (54.46%) and β-turmerone (33.45%), respectively. RT-qPCR results showed significantly lower gene expression levels of innate inflammatory cytokines (IL-6 and TNF-α) compared to the control (LPS). Also, it was observed that the extracts do not possess cytotoxic activity against different cell lines, where E. cardamomum showed EC50 (µg/mL) of 473.84 (HeLa cells), 237.36 (J774A.1 cells), 257.51 (Vero E6 cells), and 431.16 (Balb/C peritoneal cells) and C. longa showed EC50 (µg/mL) of 351.17 (HeLa cells), 430.96 (J774A.1 cells), 396.24 (Vero E6 cells), and 362.86 (Balb/C peritoneal cells). The results of this research suggest that natural extracts of E. cardamomum and C. longa possess anti-inflammatory effects and no cytotoxic activity against HeLa, J774A.1, Vero E6, and Balb/C peritoneal cell lines. Finally, it was observed that the extracts also decreased nitric oxide (NO) production in peritoneal macrophages.
Germination and the Initial Seedling Growth of Lettuce, Celeriac and Wheat Cultivars after Micronutrient and a Biological Application Pre-Sowing Seed Treatment
Authors: Poštić Dobrivoj , Štrbanović Ratibor , Tabaković Marijenka , Popović Tatjana , Ćirić Ana , Banjac Nevena , Trkulja Nenad , Stanisavljević Rade
Published: September 2021

Seed treatments with zinc, boron, biostimulant Coveron and MIX (zinc + boron + Coveron) were applied to three lettuce and three celeriac cultivars. Seeds of three wheat cultivars were treated under laboratory conditions with Trichoderma harzianum and eight Bacillus spp. Seed germination, seedling growth, and the presence of the following pathogens were determined: Fusarium sp., Alternaria sp., Penicillium sp., and Mucor sp. The Coveron treatment was the most effective on lettuce seeds tested in the germination cabinet. Seed germination was higher by 4% than in the control. Alternatively, germination of seeds treated with boron in the greenhouse was higher by 12% than in the control. The Coveron treatment had the highest effect on the shoot length, which was greater by 0.7 and 2.1 cm in the germination cabinet and the greenhouse, respectively. This treatment was also the most effective on the root length. Zn, B, and MIX treatments increased celeriac seed germination by 14% in the germination cabinet. The Zn treatment was the most efficient on seeds tested in the greenhouse. The germination was higher by 15%. A significant cultivar × treatment interaction was determined in both observed species under both conditions. The maximum effect on wheat seed germination (8%) was achieved with the T. harzianum treatment in the Salazar cultivar. A significant interdependence (p ≤ 0.01 to p ≤ 0.001) was established between seed germination and the seedling growth. The interrelationship between seed germination and pathogens of all cultivars was negative.
Competitive Ability Effects of Datura stramonium L. and Xanthium strumarium L. on the Development of Maize (Zea mays) Seeds
Authors: Karimmojeni Hassan , Rahimian Hamid , Alizadeh Hassan , Yousefi Ali Reza , Gonzalez-Andujar Jose L. , Sweeney Eileen Mac , Mastinu Andrea
Published: September 2021

The objective of this study was to explore the physical properties of maize seeds in competition with weeds. The basic and complex geometric characteristics of seeds from maize plants, competing with Datura stramonium L. (DS) or Xanthium strumarium (XS) at different weed densities, were studied. It was found that the basic and complex geometric characteristics of maize seeds, such as dimension, aspect ratio, equivalent diameter, sphericity, surface area and volume, were significantly affected by weed competition. The increase in weed density from 0 to 8 plants m2 resulted in an increase in the angle of repose from 27° to 29°, while increasing weed density from 8 to 16 plants m2 caused a diminution of the angle of repose down to 28°. Increasing the density of XS and DS to 16 plants m2 caused a reduction in the maximum 1000 seed weight of maize by 40.3% and 37.4%, respectively. These weed side effects must be considered in the design of industrial equipment for seed cleaning, grading and separation. To our knowledge, this is the first study to consider the effects of weed competition on maize traits, which are important in industrial processing such as seed aeration, sifting and drying.
Eco-Geographical, Morphological and Molecular Characterization of a Collection of the Perennial Endemic Species Medicago tunetana (Murb.) A.W. Hill (Fabaceae) from Tunisia
Authors: Ferchichi Yosr , Sakhraoui Anis , Ltaeif Hela Belhaj , Ben Mhara Yosr , Elimem Mohamed , Ben Naceur M’barek , Ghrabi-Gammar Zeineb , Rouz Slim
Published: September 2021

In order to characterize and conserve the endemic pastoral species Medicago tunetana, many prospecting missions were carried out in mountainous regions of the Tunisian ridge. Twenty-seven eco-geographical and morphological traits were studied for six M. tunetana accessions and followed by molecular analysis using seven Simple Sequence Repeat (SSR). Only five markers were polymorphic and reproductible in the six M. tunetana populations. A total of 54 alleles were observed with an average of 10.8 bands/primer/genotype. Mean Polymorphism Information Content (PIC), Nei gene diversity (h) Shannon’s information index (I) indicated the high level of polymorphism. The generated dendrogram with hierarchical UPGMA cluster analysis grouped accessions into two main groups with various degree of subclustring. All the studied accessions shared 57% of genetic similarity. Analysis of variance showed high significant difference between morphological traits among M. tunetana populations where MT3 from Kesra showed different morphological patterns regarding leaf, pod and seeds traits. Canonical correspondence analysis (CCA) showed two principal groups of M. tunetana populations based on potassium, total and active lime contents in soil. Our results suggest that SSR markers developed in M. truncatula could be a valuable tool to detect polymorphism in M. tunetana. Furthermore, the studied morphological markers showed a large genetic diversity among M. tunetana populations. This approach may be applicable for the analysis of intra specific variability in M. tunetana accessions. Our study could help in the implementation of an effective and integrated conservation programs of perennial endemic Medicago.
Isotria medeoloides, a North American Threatened Orchid: Fungal Abundance May Be as Important as Light in Species Management
Authors: Whigham Dennis , McCormick Melissa , Brooks Hope , Josey Brian , Floyd Robert , Applegate Jason
Published: September 2021

The management of endangered or threatened plant species is difficult if protocols are not developed to propagate species for the purpose of restoration or the enhancement of existing populations. The management of endangered and threatened orchids is especially difficult because of the obligate interactions between orchids and orchid mycorrhizal fungi. Isotria medeoloides is a federally threatened forest-dwelling orchid species with a wide distribution in eastern North America. Seeds have not been successfully germinated and current management is based primarily on using subcanopy thinning to increase light in areas where monitoring demonstrates that populations are declining. We report the results of long-term monitoring efforts, canopy thinning, and orchid mycorrhizal fungus abundance studies at two locations in Virginia. The declining populations responded positively to the experimental and natural thinning of the canopy. At one site, the response was the result of understory canopy thinning. At the second site, the response was due to the natural death of a canopy tree. In light of the dramatic increase in fungal abundance following death of the canopy tree, we propose the Fungal Abundance Hypothesis as an additional approach to the management of endangered plant species. The removal of canopy trees in or adjacent to Isotria populations results in an increase in dead belowground biomass (i.e., roots of the dead canopy tree) that provides substrates for microbial growth, including orchid mycorrhizal fungi, that benefit Isotria.
The Road to Practical Application of Cadmium Phytoremediation Using Rice
Authors: Takahashi Ryuichi , Ito Masashi , Kawamoto Tomohiko
Published: September 2021

Cadmium (Cd) is a toxic heavy metal that causes severe health issues in humans. Cd accumulates in the human body when foods produced in Cd-contaminated fields are eaten. Therefore, soil remediation of contaminated fields is necessary to provide safe foods. Rice is one of the primary candidates for phytoremediation. There is a genotypic variation of Cd concentration in the shoots and grains of rice. Using the world rice core collection, ‘Jarjan’, ‘Anjana Dhan’, and ‘Cho-ko-koku’ were observed with a significantly higher level of Cd accumulation in the shoots and grains. Moreover, OsHMA3, a heavy metal transporter, was identified as a responsive gene of quantitative trait locus (QTL) for high Cd concentration in the shoots of these three varieties likewise. However, it is difficult to apply practical phytoremediation to these varieties because of their unfavorable agricultural traits, such as shatter and easily lodged. New rice varieties and lines were bred for Cd phytoremediation using OsHMA3 as a DNA marker selection. All of them accumulated Cd in the shoots equal to or higher than ‘Cho-ko-koku’ with improved cultivation traits. Therefore, they can be used for practical Cd phytoremediation.
Impacts of Effective Microorganisms, Compost Tea, Fulvic Acid, Yeast Extract, and Foliar Spray with Seaweed Extract on Sweet Pepper Plants under Greenhouse Conditions
Authors: Mohamed Mostafa H. M. , Sami Rokayya , Al-Mushhin Amina A. M. , Ali Maha Mohamed Elsayed , El-Desouky Heba S. , Ismail Khadiga Ahmed , Khalil Radwan , Zewail Reda M. Y.
Published: September 2021

Sweet pepperincludes several vitamins and is regarded as a great source of bioactive nutrients, such as carotenoids and phenolic compounds, for human growth and activities. This work aimed to investigate the effects of the soil addition of growth stimulants, namely, effective microorganisms (EM), compost tea, fulvic acid, and yeast extract, and foliar applications of seaweed extract, on the vegetative growth, enzyme activity, phytohormones content, chemical constituents of plant foliage, fruit yield, and fruit quality of sweet pepper plants (Capsicum annuum L. cv. Zidenka) growing under greenhouse conditions. The results showed that the tallest plant, largest leaf area/plant, and heaviest plant fresh and dry weights were recorded after combining a soil addition of yeast extract and foliar spray with seaweed extracts at 3 g/L in two growing seasons. The highest number of fruit/plant, fruit yield/m2, fruit values of vitamin C (VC), total sugars, total soluble solids (TSS), and carotenoids, along with the highest leaf of cytokines, P, K, Fe, and total carbohydrates values, were obtained using a soil addition of fulvic acid and spray with seaweed extract at 3 g/L in the two seasons of study. These treatments also provided the lowest abscisic acid, peroxidase, and super oxidase dismutase values in the same conditions. Sweet pepper plants supplemented with compost tea and seaweed extract foliar spray at 3 g/L were the most promising for inducing the highest values of fruit fresh and dry weights, fruit length and diameter, and the leavesrichest in N, Zn, and Mn; inversely, it induced the lowest catalase levels in both seasons. The applications of EM, yeast extract, and seaweed extract could be applied for high growth, mineral levels, enzymatic activity, fruit yield, and nutritional value of sweet pepper fruit and minimizing environmental pollution.
Eco-Friendly Rice Straw Paper Coated with Longan (Dimocarpus longan) Peel Extract as Bio-Based and Antibacterial Packaging
Authors: Chollakup Rungsima , Kongtud Wuttinant , Sukatta Udomlak , Premchookiat Maneenuch , Piriyasatits Kanyanut , Nimitkeatkai Hataitip , Jarerat Amnat
Published: September 2021

This study aimed to develop active paper from rice straw fibers with its function as antibacterial activity obtained from longan (Dimocarpus longan) peels. The morphology and mechanical properties of fibers of rice straw were examined as quality parameters for paper production. Rice straw paper (RSP) with basis weight ca 106.42 g/m2, 0.34 mm thickness, 34.15% brightness, and 32.26 N·m/g tensile index was successfully prepared from fibers and pulps without chemical bleaching process. Bioactive compounds of longan peels were extracted using maceration technique with a mixture of ethanol-water, and subsequently coated onto RSP at concentration of 10%, 15% and 20% (w/v). Fourier transform infrared (FTIR) spectroscopic analysis demonstrated the functional groups of phytochemicals in the peel extract. The results of physical properties showed that the coated RSP had similar thickness and tensile index, but had lower brightness compared to control papers. Scanning electron microscopy (SEM) confirmed the significantly different of surface and cross-section structures between coated and uncoated RSP. The coated RSP had relatively greater barrier properties to prevent water absorption. In addition, the RSP coated with longan peel extracts showed significant antibacterial activity against foodborne bacteria, Staphylococcus aureus and Bacillus cereus. This study reveals the benefits of natural byproducts as potential materials for active packaging prepared by environmentally friendly processes.
The Role of Interfacial Adhesion in Polymer Composites Engineered from Lignocellulosic Agricultural Waste
Authors: Kun Dávid , Kárpáti Zoltán , Fekete Erika , Móczó János
Published: September 2021

This paper presents a comprehensive study about the application of a lignocellulosic agricultural waste, sunflower husk in different polymer composites. Two types of milled sunflower husk with different geometrical factors were incorporated into polypropylene, low-density and high-density polyethylene, polystyrene (PS), glycol-modified polyethylene terephthalate (PETG) and polylactic acid (PLA). The filler content of the composites varied between 0 and 60 vol%. The components were homogenized in an internal mixer and plates were compression molded for testing. The Lewis–Nielsen model was fitted to the moduli of each composite series, and it was found that the physical contact of the filler particles is a limiting factor of composite modulus. Interfacial interactions were estimated from two independent approaches. Firstly, the extent of reinforcement was determined from the composition dependence of tensile strength. Secondly, the reversible work of adhesion was calculated from the surface energies of the components. As only weak van der Waals interactions develop in the interphase of polyolefins and sunflower husk particles, adhesion is weak in their composites resulting in poor reinforcement. Interfacial adhesion enhanced by specific interactions in the interphase, such as π electron interactions for PS, hydrogen bonds for PLA, and both for PETG based composites.
3D/4D Printing of Polymers: Fused Deposition Modelling (FDM), Selective Laser Sintering (SLS), and Stereolithography (SLA)
Authors: Kafle Abishek , Luis Eric , Silwal Raman , Pan Houwen Matthew , Shrestha Pratisthit Lal , Bastola Anil Kumar
Published: September 2021

Additive manufacturing (AM) or 3D printing is a digital manufacturing process and offers virtually limitless opportunities to develop structures/objects by tailoring material composition, processing conditions, and geometry technically at every point in an object. In this review, we present three different early adopted, however, widely used, polymer-based 3D printing processes; fused deposition modelling (FDM), selective laser sintering (SLS), and stereolithography (SLA) to create polymeric parts. The main aim of this review is to offer a comparative overview by correlating polymer material-process-properties for three different 3D printing techniques. Moreover, the advanced material-process requirements towards 4D printing via these print methods taking an example of magneto-active polymers is covered. Overall, this review highlights different aspects of these printing methods and serves as a guide to select a suitable print material and 3D print technique for the targeted polymeric material-based applications and also discusses the implementation practices towards 4D printing of polymer-based systems with a current state-of-the-art approach.
Prediction of Methylene Blue Removal by Nano TiO2 Using Deep Neural Network
Authors: Amor Nesrine , Noman Muhammad Tayyab , Petru Michal
Published: September 2021

This paper deals with the prediction of methylene blue (MB) dye removal under the influence of titanium dioxide nanoparticles (TiO2 NPs) through deep neural network (DNN). In the first step, TiO2 NPs were prepared and their morphological properties were analysed by scanning electron microscopy. Later, the influence of as synthesized TiO2 NPs was tested against MB dye removal and in the final step, DNN was used for the prediction. DNN is an efficient machine learning tools and widely used model for the prediction of highly complex problems. However, it has never been used for the prediction of MB dye removal. Therefore, this paper investigates the prediction accuracy of MB dye removal under the influence of TiO2 NPs using DNN. Furthermore, the proposed DNN model was used to map out the complex input-output conditions for the prediction of optimal results. The amount of chemicals, i.e., amount of TiO2 NPs, amount of ehylene glycol and reaction time were chosen as input variables and MB dye removal percentage was evaluated as a response. DNN model provides significantly high performance accuracy for the prediction of MB dye removal and can be used as a powerful tool for the prediction of other functional properties of nanocomposites.
Oligosaccharins as Elicitors of Defense Responses in Wheat
Authors: Ochoa-Meza Laura Celina , Quintana-Obregón Eber Addí , Vargas-Arispuro Irasema , Falcón-Rodríguez Alejandro Bernardo , Aispuro-Hernández Emmanuel , Virgen-Ortiz José J. , Martínez-Téllez Miguel Ángel
Published: September 2021

Wheat is a highly relevant crop worldwide, and like other massive crops, it is susceptible to foliar diseases, which can cause devastating losses. The current strategies to counteract wheat diseases include global monitoring of pathogens, developing resistant genetic varieties, and agrochemical applications upon diseases’ appearance. However, the suitability of these strategies is far from permanent, so other alternatives based on the stimulation of the plants’ systemic responses are being explored. Plants’ defense mechanisms can be elicited in response to the perception of molecules mimicking the signals triggered upon the attack of phytopathogens, such as the release of plant and fungal cell wall-derived oligomers, including pectin and chitin derivatives, respectively. Among the most studied cell wall-derived bioelicitors, oligogalacturonides and oligochitosans have received considerable attention in recent years due to their ability to trigger defense responses and enhance the synthesis of antipathogenic compounds in plants. Particularly, in wheat, the application of bioelicitors induces lignification and accumulation of polyphenolic compounds and increases the gene expression of pathogenesis-related proteins, which together reduce the severity of fungal infections. Therefore, exploring the use of cell wall-derived elicitors, known as oligosaccharins, stands as an attractive option for the management of crop diseases by improving plant readiness for responding promptly to potential infections. This review explores the potential of plant- and fungal-derived oligosaccharins as a practical means to be implemented in wheat crops.
Polypropylene Composites Reinforced by Nonmetallic from Waste Printed Circuit Boards Using Spout-Fluid Bed Coating with PP Particles Enhance Fluidization
Authors: Wu Man , Jiang Jingxia , Meng Cuiping , Hu Xiude , Xie Henglai , Wu Mingzhou , Guo Qingjie
Published: September 2021

Nonmetallic materials recycled from waste printed circuit boards (N-WPCBs) were modified by coating KH-550 in a spout-fluid bed. To improve the effect of the modification, PP particles were used to enhance the fluidization quality of the N-WPCB particles in the coating modification. Then, the modified N-WPCBs were used as fillers to fabricate PP/N-WPCB composites. The method of coating in a spout-fluid bed with PP particles enhanced fluidization and showed the best modification effect compared to other coating methods. The FT-IR and SEM results demonstrated that interfacial bonding between N-WPCBs and PP could be enhanced by modified N-WPCBs, which improved the mechanical properties of the composites. When the mass ratio of PP to N-WPCBs is 100:75 and the dose of KH-550 is 4 phr, the flexural strength, tensile strength, and impact strength of the composites increase by 16.60%, 23.22%, and 23.64%, respectively. This would realize the high-value utilization of N-WPCBs with coating modification in the spout-fluid bed.
The Development of Light-Curable Calcium-Silicate-Containing Composites Used in Odontogenic Regeneration
Authors: Lin Yi-Ting , Shie Ming-You , Lin Yen-Hong , Ho Chia-Che , Kao Chia-Tze , Huang Tsui-Hsien
Published: September 2021

Pulp regeneration is one of the most successful areas in the field of tissue regeneration, despite its current limitations. The biocompatibility of endodontic biomaterials is essential in securing the oral microenvironment and supporting pulp tissue regeneration. Therefore, the objective of this study was to investigate the new light-curable calcium silicate (CS)-containing polyethylene glycol diacrylate (PEGDA) biocomposites’ regulation of human dental pulp stem cells (hDPSCs) in odontogenic-related regeneration. The CS-containing PEGDA (0 to 30 wt%) biocomposites are applied to endodontics materials to promote their mechanical, bioactive, and biological properties. Firstly, X-ray diffraction and Fourier-transform infrared spectroscopy showed that the incorporation of CS increased the number of covalent bonds in the PEGDA. The diameter tension strength of the CS-containing PEGDA composite was significantly higher than that of normal PEGDA, and a different microstructure was detected on the surface. Samples were analyzed for their surface characteristics and Ca/Si ion-release profiles after soaking in simulated body fluid for different periods of time. The CS30 group presented better hDPSC adhesion and proliferation in comparison with CS0. Higher values of odontogenic-related biomarkers were found in hDPSCs on CS30. Altogether, these results prove the potential of light-curable CS-containing PEGDA composites as part of a ‘point-of-care’ strategy for application in odontogenesis-related regeneration.
Evaluating the Multifunctional Performance of Structural Composites for Thermal Energy Storage
Authors: Fredi Giulia , Dorigato Andrea , Fambri Luca , Pegoretti Alessandro
Published: September 2021

The simultaneous need for high specific mechanical properties and thermal energy storage (TES) function, present in several applications (e.g., electric vehicles), can be effectively addressed by multifunctional polymer-matrix composites containing a reinforcing agent and a phase change material (PCM). The PCMs generally decrease the mechanical properties of the host structural composites, but a multifunctional composite can still be beneficial in terms of mass saving, compared to two monofunctional units performing the structural and heat management functions individually. To quantify any possible advantages, this paper proposes an approach that determines the conditions for an effective mass saving at the system level and ranks the investigated structural TES composites with a parameter called multifunctional efficiency. It is found that the potential mass saving is higher when the volume fraction of the reinforcement is kept constant also when the PCM fraction increases or when the single phases (reinforcement, PCM) are themselves multifunctional.
Preparation of Nanofibers Mats Derived from Task-Specific Polymeric Ionic Liquid for Sensing and Catalytic Applications
Authors: Valverde David , Muñoz Iván , García-Verdugo Eduardo , Altava Belen , Luis Santiago V.
Published: September 2021

Nanofibers mats derived from the task-specific functionalized polymeric ionic liquids based on homocysteine thiolactone are obtained by electrospinning them as blends with polyvinylpyrrolidone. The presence of this functional moiety allowed the post-functionalization of these mats through the aminolysis of the thiolactone ring in the presence of an amine by a thiol–alkene “click” reaction. Under controlled experimental conditions the modification can be performed introducing different functionalization and crosslinking of the electrospun fibers, while maintaining the nanostructure obtained by the electrospinning. Initial studies suggest that the nanofibers based on these functionalized polymeric ionic liquids can be used in both sensing and catalytic applications.
The Influence of Substituents in Phosphazene Catalyst-Flame Retardant on the Thermochemistry of Benzoxazine Curing
Authors: Bornosuz Natalia V. , Korotkov Roman F. , Kolenchenko Alexander A. , Shapagin Alexey V. , Orlov Alexey V. , Gorbunova Irina Yu. , Kireev Vyacheslav V. , Sirotin Igor S.
Published: September 2021

This work is devoted to the influence of phosphazene modifiers with different substituents on the curing process, thermal properties and flammability of benzoxazine resin. Novel catalysts with m-toluidine substituents were introduced. The catalytic activity of studied phosphazene compounds decreased in the row: hexachlorocyclotriphosphazene (HCP) > tetra m-toluidine substituted phosphazene PN-mt (4) > hexa m-toluidine substituted phosphazene PN-mt (6) > hexaphenoxycyclotriphosphazene (HPP), where HPP is totally inactive. Two types of catalysis: basic and acid were proposed. A brief study of resulting properties of polybenzoxazines was presented. The addition of any studied modifier caused the decrease of glass transition temperature and thermal stability of polymers. The morphology of cured compositions was characterized by matrix-dispersion phase structure. All phosphazene containing polybenzoxazines demonstrated the improved flame resistance.
One Surface Treatment, Multiple Possibilities: Broadening the Use-Potential of Para-Aramid Fibers with Mechanical Adhesion
Authors: Palola Sarianna , Javanshour Farzin , Kolahgar Azari Shadi , Koutsos Vasileios , Sarlin Essi
Published: September 2021

Aramid fibers are high-strength and high-modulus technical fibers used in protective clothing, such as bulletproof vests and helmets, as well as in industrial applications, such as tires and brake pads. However, their full potential is not currently utilized due to adhesion problems to matrix materials. In this paper, we study how the introduction of mechanical adhesion between aramid fibers and matrix material the affects adhesion properties of the fiber in both thermoplastic and thermoset matrix. A microwave-induced surface modification method is used to create nanostructures to the fiber surface and a high throughput microbond method is used to determine changes in interfacial shear strength with an epoxy (EP) and a polypropylene (PP) matrix. Additionally, Fourier transform infrared spectroscopy, atomic force microscopy, and scanning electron microscopy were used to evaluate the surface morphology of the fibers and differences in failure mechanism at the fiber-matrix interface. We were able to increase interfacial shear strength (IFSS) by 82 and 358%, in EP and PP matrix, respectively, due to increased surface roughness and mechanical adhesion. Also, aging studies were conducted to confirm that no changes in the adhesion properties would occur over time.
The Efficacy of Silver-Based Electrospun Antimicrobial Dressing in Accelerating the Regeneration of Partial Thickness Burn Wounds Using a Porcine Model
Authors: Do Thien , Nguyen Tien , Ho Minh , Nguyen Nghi , Do Thai , Vo Dai , Hua Ha , Phan Thang , Tran Phong , Nguyen Hoai , Vo Toi , Nguyen Thi-Hiep
Published: September 2021

(1) Background: Wounds with damages to the subcutaneous are difficult to regenerate because of the tissue damages and complications such as bacterial infection. (2) Methods: In this study, we created burn wounds on pigs and investigated the efficacy of three biomaterials: polycaprolactone-gelatin-silver membrane (PCLGelAg) and two commercial burn dressings, Aquacel® Ag and UrgoTulTM silver sulfadiazine. In vitro long-term antibacterial property and in vivo wound healing performance were investigated. Agar diffusion assays were employed to evaluate bacterial inhibition at different time intervals. Minimum inhibitory concentration (MIC), minimum bactericidal concentration (MBC) and time-kill assays were used to compare antibacterial strength among samples. Second-degree burn wounds in the pig model were designed to evaluate the efficiency of all dressings in supporting the wound healing process. (3) Results: The results showed that PCLGelAg membrane was the most effective in killing both Gram-positive and Gram-negative bacteria bacteria with the lowest MBC value. All three dressings (PCLGelAg, Aquacel, and UrgoTul) exhibited bactericidal effect during the first 24 h, supported wound healing as well as prevented infection and inflammation. (4) Conclusions: The results suggest that the PCLGelAg membrane is a practical solution for the treatment of severe burn injury and other infection-related skin complications.
Production of Extrudate Food with Mango By-Products (Mangifera indica): Analysis of Physical, Chemical, and Sensorial Properties
Authors: Medina-Rendon Esther Alicia , Guatemala-Morales Guadalupe María , Padilla-Camberos Eduardo , Corona-González Rosa Isela , Arriola-Guevara Enrique , García-Fajardo Jorge Alberto
Published: September 2021

The novelty of this work is the use of two mango by-products, mango peel and kernel, to obtain an extruded food. As well as the development of this food through a design of mixtures, we conducted sensorial analysis of the food through a hedonic test, in order not only to develop an extruded food with mango by-products, but also to develop a food that will be accepted by the consumer. A simple lattice mixture design was carried out with 14 mixtures, where the components were white corn flour (WCF), mango peel flour (MPF) and mango kernel flour (MKF), both from the Tommy Atkins mango variety. Physical and chemical properties such as the expansion index (EI), hardness, water absorption index (WAI), water solubility index (WSI), total phenols, DPPH and ABTS were evaluated. An optimization region was found that included 3 design points. Mixtures 1, 6 and 12 were evaluated using a nine-point hedonic scale to determine the acceptability of the product. Appearance, taste, and texture of the extrudates was evaluated. The extrudate with the best overall acceptability and the optimum physical and chemical properties contained 58.33% white corn flour, 33.33% mango peel flour and 8.33% mango kernel flour.
Optimal Selection of Backside Roughing Parameters of High-Value Components Using Abrasive Jet Processing
Authors: Tsai Feng-Che
Published: September 2021

This paper mainly presents a set of new Sapphire Backside Roughing technology. Presently, the associated Sapphire Backside Roughing technology is still concentrated on chemical etching, as its yield rate and efficiency are often limited by lattice structures, and the derived chemical waste fluid after etching is most likely to cause ecological contamination. In this research, refined abrasive jet processing technology is adopted, and in the meantime, the Taguchi experiment design method is taken for detailed experimental planning. Through processing parameter conditions and abrasive selection and development, proper surface roughing and processing uniformity are obtained so as to improve the various weak points of the abovementioned traditional etching effectively. It is discovered that abrasive blasting processing technology is, respectively, combined with wax-coated #1000 SiC particles and wax-coated #800 Zirconium particles to process the sapphire substrate with initial surface roughness 0.8–0.9 μmRa from the experiment. A 1.1–1.2 μmRa surface roughness effect can be achieved about two minutes later. The experimental results show that the actual degree of sapphire substrate surface roughing obtained in the AJM process depends on the gas pressure, impact angle, wax-coated abrasives, and additives. The new Sapphire Backside Roughing technology has high flexibility, which not only meets the requirements for sapphire surface roughing specification but can also effectively reduce the sapphire substrate roughing time and related cost.
Application of Green Surfactants in the Remediation of Soils Contaminated by Hydrocarbons
Authors: da Silva Israel Gonçalves Sales , de Almeida Fabíola Carolina Gomes , da Rocha e Silva Nathália Maria Padilha , de Oliveira Joaquim Teodoro Romão , Converti Attilio , Sarubbo Leonie Asfora
Published: September 2021

Among the innovative technologies utilized for the treatment of contaminated soils, the use of green surfactants appears to be a biocompatible, efficient, and attractive alternative, since the cleaning processes that normally use synthetic surfactants as additives cause other problems due to toxicity and the accumulation of by-products. Three green surfactants, i.e., two biobased (biobased 1 and biobased 2) surfactants produced by chemical synthesis and a microbial surfactant produced from the yeast Starmerella bombicola ATCC 22214, were used as soil remediation agents and compared to a synthetic surfactant (Tween 80). The three surfactants were tested for their ability to emulsify, disperse, and remove different hydrophobic contaminants. The biosurfactant, which was able to reduce the water surface tension to 32.30 mN/m at a critical micelle concentration of 0.65 g/L, was then used to prepare a commercial formulation that showed lower toxicity to the tested environmental bioindicators and lower dispersion capacity than the biobased surfactants. All the green surfactants showed great emulsification capacity, especially against motor oil and petroleum. Therefore, their potential to remove motor oil adsorbed on different types of soils (sandy, silty, and clay soil and beach sand) was investigated either in kinetic (flasks) or static (packed columns) experiments. The commercial biosurfactant formulation showed excellent effectiveness in removing motor oil, especially from contaminated sandy soil (80.0 ± 0.46%) and beach sand (65.0 ± 0.14%) under static conditions, while, in the kinetic experiments, the commercial biosurfactant and the biobased 2 surfactant were able to remove motor oil from all the contaminated soils tested more effectively than the biobased 1 surfactant. Finally, the S. bombicola commercial biosurfactant was evaluated as a soil bioremediation agent. In degradation experiments carried out on motor oil-contaminated soils enriched with sugarcane molasses, oil degradation yield in the sandy soil reached almost 90% after 60 days in the presence of the commercial biosurfactant, while it did not exceed 20% in the presence of only S. bombicola cells. These results promise to contribute to the development of green technologies for the treatment of hydrophobic pollutants with economic gains for the oil industries.
Contemporary Influences on the Role of Imams in Britain: A Critical Analysis of Leadership and Professionalisation for the Imamate in 21st Century Britain
Authors: Hough Christine Victoria , Abbott-Halpin Edward , Mahmood Tariq , Giles Jessica
Published: September 2021

This article is based on the findings from a research project, referred to hereafter as #ImamsBritain, commenced with a series of discussions with Imams in the north of England. The role of the Imam has undergone far-reaching changes over the last thirty years chiefly due to the changing socio-economic and political climate, which in turn has directly affected the needs of Muslim communities. Consequently, Imams are now seen as professionals who need a wider range of pastoral care skills that go beyond those of their traditional role, which was mainly focused on religious teaching and spiritual guidance, The second stage of the data analysis for the research involved the exploratory Group Delphi technique, in which the Imam respondents underwent the processes of two critical reflections on the data collected. The resultant findings reflect their individual perceptions of the kind of training and development they need. This provides a unique framework for constructing a professional guide for Imams in Great Britain. The discussions and critical analyses in this paper draw on the discourses of professionalisation and pastoral care and relevant reports and reviews on Imam training in Europe and Canada.
“Translated” or “Transformed”: The Use of Western Hymns in the Evangelization of the Lisu of Southwest China
Authors: Arrington Aminta
Published: September 2021

Translated western hymns have a bad reputation in missiology. The term “translated” seems to convey a less than authentic expression of Christian faith. However, that was not how it happened when the Lisu of southwest China were evangelized by missionaries from the China Inland Mission in the 1920s and 1930s. The Lisu people exerted much more agency over their translated western hymns than the term “translated” implies. While the kernel of melody and message remained intact, four-part harmonies replaced unison singing. A cappella replaced piano or organ accompaniment. Phrases meaningful in a Victorian context were transformed into phrases meaningful in a Lisu mountain context. Abstract theological terms were replaced by concrete phrases. Western rhyming schemes were laid aside and Lisu poetic couplets were used instead. The end result is that in the everyday arena, in the practical living out of what it means to be a Christian for a communal and still largely oral-preference people such as the Lisu, the Lisu Christian hymns are the centerpiece of worship and devotion, of prayer and penitence. In other words, in the process of cross-cultural transmission, the Lisu hymns were not so much translated, as they were transformed.
Nut Unfastening by Robotic Surface Exploration
Authors: Rastegarpanah Alireza , Ner Rohit , Stolkin Rustam , Marturi Naresh
Published: September 2021

In this paper, we present a novel concept and primary investigations regarding automated unfastening of hexagonal nuts by means of surface exploration with a compliant robot. In contrast to the conventional industrial approaches that rely on custom-designed motorised tools and mechanical tool changers, we propose to use robot fingers to position, grasp and unfasten unknown random-sized hexagonal nuts, which are arbitrarily positioned in the robot’s task space. Inspired by how visually impaired people handle unknown objects, in this work, we use information observed from surface exploration to devise the unfastening strategy. It combines torque monitoring with active compliance for the robot fingers to smoothly explore the object’s surface. We implement a shape estimation technique combining scaled iterative closest point and hypotrochoid approximation to estimate the location as well as contour profile of the hexagonal nut so as to accurately position the gripper fingers. We demonstrate this work in the context of dismantling an electrically driven vehicle battery pack. The experiments are conducted using a seven degrees of freedom (DoF)–compliant robot fitted with a two-finger gripper to unfasten four different sized randomly positioned hexagonal nuts. The obtained results suggest an overall exploration and unfastening success rate of 95% over an average of ten trials for each nut.
Vertical Structure of Air Pollutant Transport Flux as Determined by Ground-Based Remote Sensing Observations in Fen-Wei Plain, China
Authors: Ji Xiangguang , Hu Qihou , Hu Bo , Wang Shuntian , Liu Hanyang , Xing Chengzhi , Lin Hua , Lin Jinan
Published: September 2021

Air pollutant transport plays an important role in local air quality, but field observations of transport fluxes, especially their vertical distributions, are very limited. We characterized the vertical structures of transport fluxes in central Luoyang, Fen-Wei Plain, China, in winter based on observations of vertical air pollutant and wind profiles using multi-axis differential optical absorption spectroscopy (MAX-DOAS) and Doppler wind lidar, respectively. The northwest and the northeast are the two privileged wind directions. The wind direction and total transport scenarios were dominantly the northwest during clear days, turning to the northeast during the polluted days. Increased transport flux intensities of aerosol were found at altitudes below 400 m on heavily polluted days from the northeast to the southwest over the city. Considering pollution dependence on wind directions and speeds, surface-dominated northeast transport may contribute to local haze events. Northwest winds transporting clean air masses were dominant during clean periods and flux profiles characterized by high altitudes between 200 and 600 m in Luoyang. During the COVID-19 lockdown period in late January and February, clear reductions in transport flux were found for NO2 from the northeast and for HCHO from the northwest, while the corresponding main transport altitude remained unchanged. Our findings provide better understandings of regional transport characteristics, especially at different altitudes.
Inverse Histogram-Based Clustering Approach to Seafloor Segmentation from Bathymetric Lidar Data
Authors: Jung Jaehoon , Lee Jaebin , Parrish Christopher E.
Published: September 2021

A current hindrance to the scientific use of available bathymetric lidar point clouds is the frequent lack of accurate and thorough segmentation of seafloor points. Furthermore, scientific end-users typically lack access to waveforms, trajectories, and other upstream data, and also do not have the time or expertise to perform extensive manual point cloud editing. To address these needs, this study seeks to develop and test a novel clustering approach to seafloor segmentation that solely uses georeferenced point clouds. The proposed approach does not make any assumptions regarding the statistical distribution of points in the input point cloud. Instead, the approach organizes the point cloud into an inverse histogram and finds a gap that best separates the seafloor using the proposed peak-detection method. The proposed approach is evaluated with datasets acquired in Florida with a Riegl VQ-880-G bathymetric LiDAR system. The parameters are optimized through a sensitivity analysis with a point-wise comparison between the extracted seafloor and ground truth. With optimized parameters, the proposed approach achieved F1-scores of 98.14–98.77%, which outperforms three popular existing methods. Further, we compared seafloor points with Reson 8125 MBES hydrographic survey data. The results indicate that seafloor points were detected successfully with vertical errors of −0.190 ± 0.132 m and −0.185 ± 0.119 m (μ ± σ) for two test datasets.