bluuebunny/crossref_metadata_2025 huggingface dataset:
Minimum Quantity Lubrication Jet Noise: Passive Control
Authors: Hu Xiaodong , Yu Junhao , Li Yuanlong , Xia Yu , Xu Xuefeng , Zhang Ruochong
Published: September 2023

Jet noise is a common problem in minimum quantity lubrication (MQL) technology. This should be given great attention because of its serious impacts on the physical and mental health of the operators. In this study, a micro-grooved nozzle is proposed based on the noise reduction concept of biological micro-grooves. The flow field and acoustic characteristics of an original nozzle and a micro-grooved nozzle were investigated numerically to help better understand the noise reduction mechanism. The reasons for noise generation and the effects of the length (L), width (W) and depth (δ) of the micro-grooves on noise reduction were analyzed. It was found that jet noise is generated by the large-scale vortex ring structure and the pressure fluctuations caused by its motion. The overall sound pressure level (OASPL) decreased with the increases in W and δ, and increased with the increase in L. Among of them, δ has the greatest effect on noise reduction. The maximum noise reduction achieved was 6.66 dB, as verified by the OASPL test. Finally, the noise reduction mechanism was discussed in terms of the flow field, vorticity and the frequency characteristics. Micro-grooves can enhance the mixing of airflow inside the nozzle and accelerate the process of large-scale vortices breaking into smaller-scale vortices. It also reduces the sound pressure level (SPL) of middle frequencies, as well as the SPL of high frequencies on specific angles.
Construction of Ag-TiO2 Hierarchical Micro-/Nanostructures on a Ti Plate for Photocatalysts via Femtosecond Laser Hybrid Technology
Authors: Li Qian-Kun , Li Yue , Wang Yan-Jun , Qi Jin-Yong , Wang Yan , Liu Yao-Dong , Liu Xue-Qing
Published: September 2023

Titanium dioxide photocatalysts can break down pollutants using natural light. They possess notable light stability, chemical stability, and catalytic effects, thus leading to extensive research worldwide. However, the limited light absorption range of titanium dioxide and their inefficiencies in generating and transporting photogenerated carriers hinder the enhancement of their photocatalytic performance. In this study, we employ a femtosecond laser composite processing method to create an Ag-TiO2 nanoplate composite catalyst. This method doubles the catalytic efficiency compared with the structure processed solely with the femtosecond laser. The resulting Ag-TiO2 nanoplate composite catalysts show significant promise for addressing environmental and energy challenges, including the photodegradation of organic pollutants.
A 0.8 V, 14.76 nVrms, Multiplexer-Based AFE for Wearable Devices Using 45 nm CMOS Techniques
Authors: Tamilarasan Esther , Duraisamy Gracia Nirmala Rani , Elangovan Muthu Kumaran , Sarasam Arun Samuel Thankmony
Published: September 2023

Wearable medical devices (WMDs) that continuously monitor health conditions enable people to stay healthy in everyday situations. A wristband is a monitoring format that can measure bioelectric signals. The main part of a wearable device is its analog front end (AFE). Wearables have issues such as low reliability, high power consumption, and large size. A conventional AFE device uses more analog-to-digital converters, amplifiers, and filters for individual electrodes. Our proposed MUX-based AFE design requires fewer components than a conventional AFE device, reducing power consumption and area. It includes a single-ended differential feedback operational transconductance amplifier (OTA) and n-pass MUX-based AFE circuits which are related to the emergence of low power, low area, and low cost AFE-integrated chips that are required for wearable biomedical applications. The proposed 6T n-pass multiplexer measures a gain of −68 dB across a frequency range of 100 kHz with a 136.5 nW power consumption and a delay of 0.07 ns. The design layout area is approximately 9.8 µm2 and uses 45 nm complementary metal oxide semiconductor (CMOS) technology. Additionally, the proposed single-ended differential OTA has an obtained input referred noise of 0.014 µVrms, and a gain of −5.5 dB, while the design layout area is about 2 µm2 and was designed with the help of the Cadence Virtuoso layout design tool.
High-Q Quasi-Bound States in the Continuum in Terahertz All-Silicon Metasurfaces
Authors: Jiao Ruiqing , Wang Qing , Liu Jianjun , Shu Fangzhou , Pan Guiming , Jing Xufeng , Hong Zhi
Published: September 2023

Bound states in the continuum (BIC)-based all-silicon metasurfaces have attracted widespread attention in recent years because of their high quality (Q) factors in terahertz (THz) frequencies. Here, we propose and experimentally demonstrate an all-silicon BIC metasurface consisting of an air-hole array on a Si substrate. BICs originated from low-order TE and TM guided mode resonances (GMRs) induced by (1,0) and (1,1) Rayleigh diffraction of metagratings, which were numerically investigated. The results indicate that the GMRs and their Q-factors are easily excited and manipulated by breaking the lattice symmetry through changes in the position or radius of the air-holes, while the resonance frequencies are less sensitive to these changes. The measured Q-factor of the GMRs is as high as 490. The high-Q metasurfaces have potential applications in THz modulators, biosensors, and other photonic devices.
Investigation of Hydrothermal Performance in Micro-Channel Heat Sink with Periodic Rectangular Fins
Authors: Zhao Heng , Ma Honghua , Yan Xiang , Yu Huaqing , Xiao Yongjun , Xiao Xiao , Liu Hui
Published: September 2023

The micro-channel heat sink (MCHS) is an excellent choice due to its exceptional cooling capabilities, surpassing those of its competitors. In this research paper, a computational fluid dynamics analysis was performed to investigate the laminar flow and heat transfer characteristics of five different configurations of a variable geometry rectangular fin. The study utilized a water-cooled smooth MCHS as the basis. The results indicate that the micro-channel heat sink with a variable geometry rectangular fin has better heat dissipation capacity than a straight-type micro-channel heat sink, but at the same time, it has larger pressure loss. Based on the analysis of various rectangular fin shapes and Reynolds numbers in this study, the micro-channel heat sink with rectangular fins exhibits Nusselt numbers and friction factors that are 1.40–2.02 and 2.64–4.33 times higher, respectively, compared to the smooth heat sink. This significant improvement in performance results in performance evaluation criteria ranging from 1.23–1.95. Further, it is found that at a relatively small Reynolds number, the micro-channel heat sink with a variable geometry rectangular fin has obvious advantages in terms of overall cooling performance. Meanwhile, this advantage will decrease when the Reynolds number is relatively large.
Differentiating True and False Cinnamon: Exploring Multiple Approaches for Discrimination
Authors: Feltes Giovana , Ballen Sandra , Steffens Juliana , Paroul Natalia , Steffens Clarice
Published: September 2023

This study presents a comprehensive literature review that investigates the distinctions between true and false cinnamon. Given the intricate compositions of essential oils (EOs), various discrimination approaches were explored to ensure quality, safety, and authenticity, thereby establishing consumer confidence. Through the utilization of physical–chemical and instrumental analyses, the purity of EOs was evaluated via qualitative and quantitative assessments, enabling the identification of constituents or compounds within the oils. Consequently, a diverse array of techniques has been documented, encompassing organoleptic, physical, chemical, and instrumental methodologies, such as spectroscopic and chromatographic methods. Electronic noses (e-noses) exhibit significant potential for identifying cinnamon adulteration, presenting a rapid, non-destructive, and cost-effective approach. Leveraging their capability to detect and analyze volatile organic compound (VOC) profiles, e-noses can contribute to ensuring authenticity and quality in the food and fragrance industries. Continued research and development efforts in this domain will assuredly augment the capacities of this promising avenue, which is the utilization of Artificial Intelligence (AI) and Machine Learning (ML) algorithms in conjunction with spectroscopic data to combat cinnamon adulteration.
Realization of Artificial Neurons and Synapses Based on STDP Designed by an MTJ Device
Authors: Wang Manman , Yuan Yuhai , Jiang Yanfeng
Published: September 2023

As the third-generation neural network, the spiking neural network (SNN) has become one of the most promising neuromorphic computing paradigms to mimic brain neural networks over the past decade. The SNN shows many advantages in performing classification and recognition tasks in the artificial intelligence field. In the SNN, the communication between the pre-synapse neuron (PRE) and the post-synapse neuron (POST) is conducted by the synapse. The corresponding synaptic weights are dependent on both the spiking patterns of the PRE and the POST, which are updated by spike-timing-dependent plasticity (STDP) rules. The emergence and growing maturity of spintronic devices present a new approach for constructing the SNN. In the paper, a novel SNN is proposed, in which both the synapse and the neuron are mimicked with the spin transfer torque magnetic tunnel junction (STT-MTJ) device. The synaptic weight is presented by the conductance of the MTJ device. The mapping of the probabilistic spiking nature of the neuron to the stochastic switching behavior of the MTJ with thermal noise is presented based on the stochastic Landau–Lifshitz–Gilbert (LLG) equation. In this way, a simplified SNN is mimicked with the MTJ device. The function of the mimicked SNN is verified by a handwritten digit recognition task based on the MINIST database.
Design of Multiplexers for IoT-Based Applications Using Stub-Loaded Coupled-Line Resonators
Authors: Idrees Muhammad , Khalid Sohail , Rehman Muhammad Abdul , Ullah Syed Sajid , Hussain Saddam , Iqbal Jawaid
Published: September 2023

This paper presents the design of microstrip-based multiplexers using stub-loaded coupled-line resonators. The proposed multiplexers consist of a diplexer and a triplexer, meticulously engineered to operate at specific frequency bands relevant to IoT systems: 2.55 GHz, 3.94 GHz, and 5.75 GHz. To enhance isolation and selectivity between the two passband regions, the diplexer incorporates five transmission poles (TPs) within its design. Similarly, the triplexer filter employs seven transmission poles to attain the desired performance across all three passbands. A comprehensive comparison was conducted against previously reported designs, considering crucial parameters such as size, insertion loss, return loss, and isolation between the two frequency bands. The fabrication of the diplexer and triplexer was carried out on a compact Rogers Duroid 5880 substrate. The experimental results demonstrate an exceptional performance, with the diplexer exhibiting a low insertion loss of 0.3 dB at 2.55 GHz and 0.4 dB at 3.94 GHz. The triplexer exhibits an insertion loss of 0.3 dB at 2.55 GHz, 0.37 dB at 3.94 GHz, and 0.2 dB at 5.75 GHz. The measured performance of the fabricated diplexer and triplexer aligns well with the simulated results, validating their effectiveness in meeting the desired specifications.
Investigation of the Electrical Coupling Effect for Monolithic 3-Dimensional Nonvolatile Memory Consisting of a Feedback Field-Effect Transistor Using TCAD
Authors: Oh Jong Hyeok , Yu Yun Seop
Published: September 2023

In this study, the electrical characteristics and electrical coupling effect for monolithic 3-dimensional nonvolatile memory consisting of a feedback field-effect transistor (M3D-NVM-FBFET) were investigated using technology computer-aided design. The M3D-NVM-FBFET consists of an N-type FBFET with an oxide–nitride–oxide layer and a metal–oxide–semiconductor FET (MOSFET) in the top and bottom tiers, respectively. For the memory simulation, the programming and erasing voltages were applied at 18 and −18 V for 1 μs, respectively. The memory window of the M3D-NVM-FBFET was 1.98 V. As the retention simulation was conducted for 10 years, the memory window decreased from 1.98 to 0.83 V. For the M3D-NVM-FBFET, the electrical coupling that occurs through an electrical signal in the bottom-tier transistor was investigated. As the thickness of the interlayer dielectric (TILD) decreases from 100 to 10 nm, the change in the VTH increases from 0.16 to 0.87 V and from 0.15 to 0.84 V after the programming and erasing operations, respectively. M3D-NVM-FBFET circuits with a thin TILD of 50 nm or less need to be designed considering electrical coupling.
Noise Suppression of Nitrogen-Vacancy Magnetometer in Lock-In Detection Method by Using Common Mode Rejection
Authors: Li Yang , Zheng Doudou , Liu Zhenhua , Wang Hui , Liu Yankang , Hou Chenyu , Guo Hao , Li Zhonghao , Sugawara Yashuhiro , Tang Jun , Ma Zongmin , Liu Jun
Published: September 2023

Nitrogen-vacancy (NV) centers in diamonds are promising solid-state magnetic sensors with potential applications in power systems, geomagnetic navigation, and diamond NV color center current transformers, in which both high bandwidth and high magnetic field resolution are required. The wide bandwidth requirement often necessitates high laser power, but this induces significant laser fluctuation noise that affects the detection magnetic field resolution severely. Therefore, enhancement of the magnetic field resolution of wide-bandwidth NV center magnetic sensors is highly important because of the reciprocal effects of the bandwidth and magnetic field resolution. In this article, we develop a common mode rejection (CMR) model to eliminate the laser noise effectively. The simulation results show that the noise level of the light-detected magnetic resonance signal is significantly reduced by a factor of 6.2 after applying the CMR technique. After optimization of the laser power and modulation frequency parameters, the optimal system bandwidth was found to be 75 Hz. Simultaneously, the system’s detection magnetic field resolution was enhanced significantly, increasing from 4.49 nT/Hz1/2 to 790.8 pT/Hz1/2, which represents an improvement of nearly 5.7 times. This wide-bandwidth, high-magnetic field resolution NV color center magnetic sensor will have applications including power systems, geomagnetic navigation, and diamond NV color center current transformers.
Influence of Molecular Structure and Material Properties on the Output Performance of Liquid–Solid Triboelectric Nanogenerators
Authors: Ling Ziyun , Lin Fang , Huang Xili , Pang Hongchen , Zhang Qianxi , Zhang Cheng , Li Xiaoning , Wang Xianzhang , Pan Xinxiang
Published: September 2023

With the advantages of superior wear resistance, mechanical durability, and stability, the liquid–solid triboelectric nanogenerator (LS-TENG) has been attracting much attention in the field of energy harvesting and self-powered sensors. However, most of the studies on LS-TENG focused on device innovations, changes in solid materials, and the effect of solid properties on output performance, and there is a lack of studies on liquids, especially at the molecular level. A U-tube LS-TENG was assembled to conduct experiments, whereby the effects of molecular structures, including molecular composition, carbon chain length, functional groups and material properties on the output performance were investigated. The deuterium replacing hydrogen and the atomic compositions could not achieve the enhancement of the output performance. Whether the chemical functional groups improve the output performance of LS-TENG depends on the mating solid material. Hydroxyl and cyanogenic groups can improve the output performance for the FEP case, while amide and cyanogenic groups can improve the output performance for the PTFE case. The order of output performances for functional groups of four groups of liquids with both FEP and PTFE materials is also obtained. It was also found that the dielectric constant is not positively correlated with the output performance. The results of this study might provide a reference for the deeper study and application of LS-TENG.
Epidemiology of HEV Infection in Blood Donors in Southern Switzerland
Authors: Fontana Stefano , Ripellino Paolo , Niederhauser Christoph , Widmer Nadja , Gowland Peter , Petrini Orlando , Aprile Manuela , Merlani Giorgio , Bihl Florian
Published: September 2023

From 2014 to 2016, the number of hepatitis E virus (HEV) infections in southern Switzerland increased dramatically and suggested food as a potential infection reservoir. We evaluated the effects of food control measures introduced to limit HEV infections, assessing anti-HEV IgG and IgM rates in blood donors before and after the implementation of food control measures in 2017. From 2012 to 2013, we screened 1283, and from 2017 to 2019, we screened 1447 donors for IgG and IgM antibodies. No statistically significant differences were detected for IgG (32.8% from 2012 to 2013 vs. 31.1% from 2017 to 2019, p = 0.337) or IgM rates (2.0% from 2012 to 2013 vs. 2.8% from 2017 to 2019, p = 0.21). Rural provenience and age > 66 are predictors for positive IgG serology. A total of 5.9% of 303 donors included in both groups lost IgG positivity. We also determined nucleic acid testing (NAT) rates after the introduction of this test in 2018, comparing 49,345 donation results from southern Switzerland with those of 625,559 Swiss donor controls, and only 9 NAT-positive donors were found from 2018 to 2023. The high HEV seroprevalence in southern Switzerland may depend on different food supply chains in rural and urban areas. Local preventive measures probably have a limited impact on blood HEV risk; thus, continuous NAT testing is recommended.
Regulation of σB-Dependent Biofilm Formation in Staphylococcus aureus through Strain-Specific Signaling Induced by Diosgenin
Authors: Kim Seo-Young , Kim Minjun , Kim Tae-Jong
Published: September 2023

Staphylococcus aureus is a commensal skin bacterium and a causative agent of infectious diseases. Biofilm formation in S. aureus is a mechanism that facilitates the emergence of resistant strains. This study proposes a mechanism for the regulation of biofilm formation in S. aureus through strain-specific physiological changes induced by the plant steroid diosgenin. A comparison of diosgenin-induced changes in the expression of regulatory genes associated with physiological changes revealed the intracellular regulatory mechanisms involved in biofilm formation. Diosgenin reduced biofilm formation in S. aureus ATCC 6538 and methicillin-resistant S. aureus (MRSA) CCARM 3090 by 39% and 61%, respectively. Conversely, it increased biofilm formation in S. aureus ATCC 29213 and MRSA CCARM 3820 by 186% and 582%, respectively. Cell surface hydrophobicity and extracellular protein and carbohydrate contents changed in a strain-specific manner in response to biofilm formation. An assessment of the changes in gene expression associated with biofilm formation revealed that diosgenin treatment decreased the expression of icaA and spa and increased the expression of RNAIII, agrA, sarA, and sigB in S. aureus ATCC 6538 and MRSA CCARM 3090; however, contrasting gene expression changes were noted in S. aureus ATCC 29213 and MRSA CCARM 3820. These results suggest that a regulatory mechanism of biofilm formation is that activated sigB expression sequentially increases the expression of sarA, agrA, and RNAIII. This increased RNAIII expression decreases the expression of spa, a surface-associated adhesion factor. An additional regulatory mechanism of biofilm formation is that activated sigB expression decreases the expression of an unknown regulator that increases the expression of icaA. This in turn decreases the expression of icaA, which decreases the synthesis of polysaccharide intercellular adhesins and ultimately inhibits biofilm formation. By assessing strain-specific contrasting regulatory signals induced by diosgenin in S. aureus without gene mutation, this study elucidated the signal transduction mechanisms that regulate biofilm formation based on physiological and gene expression changes.
Detection of SARS-CoV-2 Δ426 ORF8 Deletion Mutant Cluster in NGS Screening
Authors: Cecchetto Riccardo , Tonon Emil , Medaina Nicoletta , Turri Giona , Diani Erica , Piccaluga Pier Paolo , Salomoni Angela , Conti Michela , Tacconelli Evelina , Lagni Anna , Lotti Virginia , Favarato Mosé , Gibellini Davide
Published: September 2023

Next-generation sequencing (NGS) from SARS-CoV-2-positive swabs collected during the last months of 2022 revealed a large deletion spanning ORF7b and ORF8 (426 nt) in six patients infected with the BA.5.1 Omicron variant. This extensive genome loss removed a large part of these two genes, maintaining in frame the first 22 aminoacids of ORF7b and the last three aminoacids of ORF8. Interestingly, the deleted region was flanked by two small repeats, which were likely involved in the formation of a hairpin structure. Similar rearrangements, comparable in size and location to the deletion, were also identified in 15 sequences in the NCBI database. In this group, seven out of 15 cases from the USA and Switzerland presented both the BA.5.1 variant and the same 426 nucleotides deletion. It is noteworthy that three out of six cases were detected in patients with immunodeficiency, and it is conceivable that this clinical condition could promote the replication and selection of these mutations.
The Signal Transduction Protein PII Controls the Levels of the Cyanobacterial Protein PipX
Authors: Llop Antonio , Tremiño Lorena , Cantos Raquel , Contreras Asunción
Published: September 2023

Cyanobacteria, microorganisms performing oxygenic photosynthesis, must adapt their metabolic processes to environmental challenges such as day and night changes. PipX, a unique regulatory protein from cyanobacteria, provides a mechanistic link between the signalling protein PII, a widely conserved (in bacteria and plants) transducer of carbon/nitrogen/energy richness, and the transcriptional regulator NtcA, which controls a large regulon involved in nitrogen assimilation. PipX is also involved in translational regulation through interaction with the ribosome-assembly GTPase EngA. However, increases in the PipX/PII ratio are toxic, presumably due to the abnormally increased binding of PipX to other partner(s). Here, we present mutational and structural analyses of reported PipX-PII and PipX-NtcA complexes, leading to the identification of single amino acid changes that decrease or abolish PipX toxicity. Notably, 4 out of 11 mutations decreasing toxicity did not decrease PipX levels, suggesting that the targeted residues (F12, D23, L36, and R54) provide toxicity determinants. In addition, one of those four mutations (D23A) argued against the over-activation of NtcA as the cause of PipX toxicity. Most mutations at residues contacting PII decreased PipX levels, indicating that PipX stability would depend on its ability to bind to PII, a conclusion supported by the light-induced decrease of PipX levels in Synechococcus elongatus PCC7942 (hereafter S. elongatus).
Optimization of the Fermentation Conditions of Metarhizium robertsii and Its Biological Control of Wolfberry Root Rot Disease
Authors: He Jing , Zhang Xiaoyan , Wang Qinghua , Li Nan , Ding Dedong , Wang Bin
Published: September 2023

Fusarium solani is the main pathogenic fungus causing the root rot of wolfberry (Lycium barbarum). The endophytic fungus Metarhizium robertsii has been widely used for the biocontrol of plant pathogenic fungi, but the biocontrol effects of this fungus on wolfberry root rot and its antifungal mechanism against F. solani have not been reported. In this study, the antagonism of endophytic fungus M. robertsii against F. solani was verified. Further, we optimized the fermentation conditions of M. robertsii fermentation broth based on the inhibition rate of F. solani. In addition, the effects of M. robertsii fermentation broth on the root rot of wolfberry and its partial inhibition mechanism were investigated. The results showed that M. robertsii exhibited good antagonism against F. solani. Glucose and beef extracts were the optimal carbon and nitrogen sources for the fermentation of M. robertsii. Under the conditions of 29 °C, 190 rpm, and pH 7.0, the fermentation broth of M. robertsii had the best inhibition effect on F. solani. Furthermore, the fermentation broth treatment decreased the activities of superoxide dismutase, catalase, and peroxidase of F. solani; promoted the accumulation of malondialdehyde; and accelerated the leakage of soluble protein and the decrease in soluble sugar. In addition, inoculation with M. robertsii significantly reduced the decay incidence and disease index of wolfberry root rot caused by F. solani. These results indicate that M. robertsii could be used as a biological control agent in wolfberry root rot disease management.
Effects of Anthropogenic Disturbance and Seasonal Variation on Aerobiota in Highly Visited Show Caves in Slovenia
Authors: Tomazin Rok , Simčič Saša , Stopinšek Sanja , Kopitar Andreja Nataša , Kukec Andreja , Matos Tadeja , Mulec Janez
Published: September 2023

Aerosols in caves are natural tracers and, together with climatic parameters, provide a detailed insight into atmospheric conditions, responses to climatic changes and anthropogenic influences in caves. Microbiological air monitoring in show caves is becoming increasingly useful to understand changes in cave ecosystems and to implement and review measures for sustainable cave use and tourism development. In 2017 and 2018, air along tourist trails in caves Postojnska jama and Škocjanske jame (Slovenia) was sampled before and after tourist visits. Samples were analysed using culture-dependent methods, flow cytometry, detection of β-D-glucan and lipopolysaccharide and compared with CO2 and temperature data to measure anthropogenic influences and seasonality on aerobiota. While the presence of tourists significantly increased concentrations of airborne microorganisms (p < 0.05), β-D-glucan and CO2 did not show such a trend and were more dependent on seasonal changes. Locally, concentrations of cultivable microorganisms above 1000 CFU/m3 were detected, which could have negative effects on the autochthonous microbiota and possibly on human health. A mixture of bacteria typically associated with humans was found in the air and identified with MALDI-TOF MS. Using MALDI-TOF MS, we achieved a 69.6% success rate in identification. Micrococcus luteus, Streptococcus mitis, Staphylococcus epidermidis and Moraxella spp. were recognized as good indicators of cave anthropisation.
Exposure to Treponema pallidum Infection among Adolescent and Young Adult Women in Roraima, Amazon Region of Brazil
Authors: Avelino Maria Eduarda de Sousa , Silva Andrio Silva da , Figueiredo Leonardo Gabriel Campelo Pinto de , Fonseca Ricardo Roberto de Souza , Menezes Cláudia Ribeiro , Lima Sandra Souza , Mendes Ana Luísa , Silva Carla Hart Borges da , Reis Isabela Vanessa Sampaio dos , Nunes Huendel Batista de Figueiredo , Sequeira Bianca Jorge , Machado Luiz Fernando Almeida
Published: September 2023

Background: Syphilis is a chronic infectious disease, and its prevalence has been described since the 15th century. Because of the high prevalence of this infection in Brazil, this study aimed to evaluate the prevalence of syphilis and its associated factors among adolescent and young women living in the city of Boa Vista, Roraima, Brazil. Methods: The present study was cross-sectional, descriptive, analytical and quantitative. It involved 200 young and adolescent women. Laboratory tests were performed to diagnose syphilis, and a sociodemographic and epidemiological questionnaire was employed. Results: In the studied sample, 10 women had a positive result for syphilis, characterizing a prevalence of 5% for infection with Treponema pallidum. There was a statistically significant association between a monthly family income of less than 1 minimum wage and syphilis (p = 0.0449) and between illicit drug use and syphilis (p = 0.0234). Conclusions: These results indicate the need for public health interventions, action plans, and the implementation of risk reduction strategies focused on this population.
Microbial Consortium HJ-SH with Very High Degradation Efficiency of Phenanthrene
Authors: Chen Rui , Zhao Zhenhua , Xu Tao , Jia Xiaoqiang
Published: September 2023

Phenanthrene (PHE) is one of the model compounds of polycyclic aromatic hydrocarbons (PAHs). In this study, a natural PHE-degrading microbial consortium, named HJ-SH, with very high degradation efficiency was isolated from soil exposed to long-term PHE contamination. The results of GC analysis showed that the consortium HJ-SH degraded 98% of 100 mg/L PHE in 3 days and 93% of 1000 mg/L PHE in 5 days, an efficiency higher than that of any other natural consortia, and even most of the engineered strains and consortia reported so far. Seven dominating strains were isolated from the microbial consortium HJ-SH, named SH-1 to SH-7, which were identified according to morphological observation and 16S rDNA sequencing as Pseudomonas sp., Stenotrophomonas sp., Delftia sp., Pseudomonas sp., Brevundimonas sp., Curtobacterium sp., and Microbacterium sp., respectively. Among all the seven single strains, SH-4 showed the strongest PHE degradation ability, and had the biggest degradation contribution. However, it is very interesting that the microbial consortium can hold its high degradation ability only with the co-existence of all these seven single strains. Moreover, HJ-SH exhibited a very high tolerance for PHE, up to 4.5 g/L, and it can degrade some other typical organic pollutants such as biphenyl, anthracene, and n-hexadecane with the degradation ratios of 93%, 92% and 70%, respectively, under 100 mg/L initial concentration in 5 days. Then, we constructed an artificial consortium HJ-7 consisting of the seven single strains, SH-1 to SH-7. After comparing the degradation ratios, cell growth, and relative degradation rates, it was concluded that the artificial consortium HJ-7 with easier reproducibility, better application stability, and larger room for modification can largely replace the natural consortium HJ-SH. In conclusion, this research provided novel tools and new insights for the bioremediation of PHE and other typical organic pollutants using microbial consortia.
Simulation of the Frequency Response Analysis of Gas Diffusion in Zeolites by Means of Computational Fluid Dynamics
Authors: Grau Turuelo Constantino , Grün Rebecca , Breitkopf Cornelia
Published: September 2023

Frequency response (FR) analysis allows the characterization of gas diffusion occurring within a porous solid system. The shape of the pressure response curves obtained after a volume modulation in the reactor gives essential information about the gas adsorption and desorption properties of the porous material, e.g., zeolites, which is in contact with a certain gas environment, as well as information about the transport phenomena such as diffusion. In this work, a simulation model developed in COMSOL Multiphysics® is introduced to reproduce the experimental behavior of the tested solid/gas systems. This approach covers, for the first time, a coupling of computational fluid dynamics (CFD), porous media flow, and a customized mass adsorption/desorption function to simulate the behavior of real frequency response systems. The simulation results are compared to experimental data obtained from the interaction of propane in MFI zeolites as well as additional data from the literature to evaluate the model validity. Furthermore, a small variation study of the effect of simulation parameters such as the mass of the sample, bed porosity, or geometry is performed and analyzed. The essential advantage of this model with respect to other analytical approaches is to observe the spatial pressure and adsorption distribution (along with other local effects) of the gas within the porous material. Thus, local environments can be visualized, and non-idealities can, therefore, be detected in contrast to the general integral simulation approach.
Microfacies Analysis of Mixed Siliciclastic-Carbonate Deposits in the Early-Middle Ordovician Meitan Formation in the Upper Yangtze Platform in SW China: Implications for Sea-Level Changes during the GOBE
Authors: Wang Xing , Lin Xiaobing , Tian Jingchun , Liang Qingshao , Chen Weizhen , Wu Baiyi
Published: September 2023

During the Early-Middle Ordovician, the Upper Yangtze Platform experienced extensive development of a distinctive set of mixed siliciclastic-carbonate deposits known as the Meitan Formation. To conduct a comprehensive study of the relationship between mixed sedimentation and sea-level changes, the Hailong section, situated at the southwest margin of the Upper Yangtze Platform in SW China, was selected as the study area due to its typical mixed sedimentary sequence. This section was effectively compared with sections in other regions. Clustering analysis of the point-count groups from the Honghuayuan and Meitan Formations revealed nine microfacies that developed during this period. Such a diverse range of microfacies provides the evidence of frequent sea-level changes in the Yangtze Platform throughout this period. Specifically, two sea-level rises were identified during the early TS.2b and early TS.3b, with the early TS.2b event occurring globally. Furthermore, four sea-level falls were observed in the late TS.2b, TS.2c, TS.3a, and late TS.3b periods. The late TS.2b sea-level fall was globally significant. From TS.2c onwards, distinct variations in sea-level changes among the Yangtze Platform, North China, Baltoscandia, Australia, and North America emerged due to alterations in the paleogeographic pattern. By comparing the sea-level curves in the Upper Yangtze Platform with the diversity curves of chitinozoans, acritarchs, and brachiopods, it became evident that environmental changes played a crucial role in the Great Ordovician Biodiversification Event (GOBE), especially during the Floian. The rising sea level and increased detrital materials fostered the development of diverse habitats, prompting organisms to adapt to varying environments. In general, rising sea levels favored increased brachiopod diversity, while falling sea levels favored enhanced planktonic diversity among chitinous and acritarch species. By shedding new light on the relationship between Ordovician sea-level changes and biodiversification in the Yangtze region, this study offers a fresh perspective on the subject from the microfacies analysis.
Study of Using Quartz Powder as a Mineral Admixture to Produce Magnesium Oxysulfate Cement
Authors: Wang Shaoyan , Pang Daijun , Chen Shengyang , Zhang Tongqing , Bi Wanli , Chen Xiaoyang
Published: September 2023

Magnesium oxysulfate (MOS) cement features potential advantages, including light weight, green and environmental protection, low thermal conductivity, and high frost- and fire-resistance, but its poor mechanical strength limits the extensive utilization in the architectural engineering. In this study, low-cost quartz (Q) was used as a mineral admixture to increase the mechanical strength of MOS pastes. The impact of the filler Q on the early and later mechanical strength of MOS cement was investigated, in which also had an impact on fluidity, setting times, volume stability, hydration processes, phase transformations, and microstructure. The results show that hydration of periclase to form 5Mg(OH)2·MgSO4·7H2O (phase 5-1-7) in this system was a multi-stage reaction process. 3Mg(OH)2·MgSO4·8H2O was the first sediment in this system and was converted into phase 5-1-7. The dilution and dispersion effects of the filler Q increased the early hydration rate, shortened the setting time, and increased the content and crystallite size of phase 5-1-7, increasing the early mechanical strength of MOS cement, while the volume-filling effect of the filler Q reduced the content of large pore and total pore volume, and improved the pore structure of the MOS cement, improving the later mechanical strength of MOS cement. MOS cement containing 15 wt.% of filler Q exhibited the highest early and later mechanical strength, and the lowest volume shrinkage, which is more suitable for application in architectural engineering. Based on these results, filler Q can be used as an enhancer in MOS cement, however its enhancement mechanisms are effective only when the content of filler Q is no more than 20 wt.%.
Trade-Off Curves for Performance Optimization in a Crushing Plant
Authors: Bhadani Kanishk , Asbjörnsson Gauti , Soldinger Almefelt Monica , Hulthén Erik , Evertsson Magnus
Published: September 2023

Operational flexibility in an aggregate production process is required to adapt to changes in customer demands. Excessive demand for a particular product fraction can lead to operational alteration wherein re-crushing of the existing larger-sized product fraction is necessary. The choice of re-crushing existing product fractions results in feed condition changes to the crusher. One common approach to producing the desired product is by varying the operation settings of a crusher in a crushing plant. However, knowledge of differences in operational performance for changing feed conditions in the circuit is required. This potentially leads to a problem of performance optimization based on the desired target product, available feed material and capability of the crusher. The paper presents an application of a multi-objective optimization method to generate multiple operational settings for the dynamic change in the operation condition in a crushing plant. Controlled experimental survey data with varying feed conditions are used to calibrate the crusher model using an unconstrained optimization problem solved using a gradient-based algorithm (Quasi-Newton method). Trade-off curves between various performance indicators of the crushing plant using a dynamic simulation platform are generated using multi-objective optimization using a non-gradient-based algorithm (genetic algorithm). The results of the application can help the operators and plant managers to make proactive decisions to steer the operation of the crushing plant towards the desired needs of the operation.
Automated Mineralogy and Diagnostic Leaching Studies on Bulk Sulfide Flotation Concentrate of a Refractory Gold Ore
Authors: Guner Mustafa K. , Bulut Gülay , Hassanzadeh Ahmad , Lode Stefanie , Aasly Kurt
Published: September 2023

Obtaining detailed and precise information from a classified refractory gold ore has been a long-standing challenge in mineral processing and process mineralogy. Although the concept of diagnostic leaching has been extensively addressed in the literature, very little information is available linking this approach with current advanced characterization techniques such as automated mineralogy. The present research study aims to characterize the flotation concentrate of refractory gold ore by combining diagnostic leaching and automated mineralogy to examine its processability. The diagnostic leaching process was applied stepwise at five stages, and the automated mineralogy was performed on different size fractions of the flotation concentrate. The chemical (X-ray fluorescence (XRF), atomic absorption spectroscopy (AAS), and inductively coupled plasma-optical emission spectroscopy (ICP-OES)) and mineralogical (X-ray diffraction (XRD)) analyses of the feed sample confirmed that the ore is a low-grade gold ore with 0.7 g/t Au. Initially, bottle roll tests were carried out to investigate leaching behavior, and the ore’s refractory nature, and gold recoveries of bottle roll tests in different sizes were below 40 wt%; it is classified as a high refractory gold ore as a result of direct cyanide leaching. Bulk sulfide flotation was applied to increase the gold content of the material. Automated mineralogy results demonstrated that most of the gold in the concentrate is present as an invisible gold form, and 63.7 wt% of gold was distributed in pyrite. Diagnostic leaching results showed 39.7 wt% of total gold was leachable using direct cyanide leaching, and around 33 wt% of undissolved gold was located in pyrite and arsenopyrite.
The Role of Biomodification in Mineral Processing
Authors: Pawlowska Agnieszka , Sadowski Zygmunt
Published: September 2023

Increasing environmental concern forces the reduction in the share of synthetic surfactants in the production of various industries, including mineral processing, by replacing them with more environmentally friendly compounds of biological origin. Several studies on the use of biosurfactants in mineral processing are currently available in the literature, but they contain limited information related to the physicochemistry of these processes. Therefore, this review aims to summarise publications from the last decade related to the role of microorganisms and their metabolic products in mineral surface modification applied in mineral processing. Theoretical principles of bacteria–mineral interactions are presented. Salt-type, sulphide, and oxide minerals were discussed with greater attention to the physicochemistry of biosurfactant–mineral interactions, such as the wettability and surface charge. The advantages and disadvantages of using bacterial cells and surface-active microbial compounds were proposed. The trends and challenges of biomodification in flotation and flocculation were discussed.
Impact of Long-Term Exposure to High Chlorine and to Low pH Solutions during Chlorine Regeneration of Ammonia-Loaded Zeolite
Authors: Narbaitz Roberto Martin , Zhang Tianguang , Akerele Grace Oluwatomisin , Sartaj Majid , Downey Jason
Published: September 2023

An earlier study has shown that chlorine solutions were capable of effectively regenerating an ammonium-loaded zeolite column; however, the chlorine concentrations were high (1000 mg Cl2/L), and for two hours of the regeneration cycle, the pH was approximately 3. This led to concerns regarding the long-term durability of the zeolite. The objective of this study is to investigate the durability of a zeolite by conducting long-term batch exposure tests using (a) high concentration chlorine solutions and (b) low pH solutions. Particle size analysis, SEM images, N2 gas adsorption tests, FTIR characterization and batch loading tests showed that 35-day exposure to 1000 mg Cl2/L solutions did not significantly impact the zeolite studied. This chlorine exposure is equivalent to 840,000 ppm-h, which is three orders of magnitude higher than the values recommended by the supplier. The 90-day-long low pH exposure tests showed that pH = 4 solutions only slightly impacted the zeolite’s characteristics and ammonium uptake; however, the pH = 3 exposure led to discernable changes, and the pH = 2 exposure led to an even greater impact. At pH = 2, there was a breakdown of some external part of the zeolite particles, leading to a 7.1-fold increase in the fines and a 56% reduction in the ammonium uptake. The decrease in the ammonium uptake was proportional to the percent of fines.
Pore Structure and Geochemical Characteristics of Alkaline Lacustrine Shale: The Fengcheng Formation of Mahu Sag, Junggar Basin
Authors: Li Caijun , Hu Tao , Cao Tingting , Pang Xiongqi , Xiong Zhiming , Lin Xiaofei , Xiao Huiyi , Chen Yuxuan , Yang Fan , Jiang Liwei , Jiang Fujie
Published: September 2023

Shale oil and gas are currently the major fields of unconventional hydrocarbon exploration and development. The Fengcheng Formation (FF) shale in the Mahu Sag of the Junggar Basin is an alkaline lacustrine organic-rich shale with an extremely prospective shale oil potential. However, its strong heterogeneity and complex pore structure greatly influence the development of shale oil. It is significant to investigate the pore and geochemical characteristics of shale reservoirs for shale oil extraction. In this study, the pore structure and geochemical characteristics of FF have been investigated using core analysis, Rock-Eval pyrolysis, X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), mercury injection capillary pressure (MICP), low-temperature gas adsorption (LTGA), and X-ray computed tomography (X-ray CT). The results show that the shale of FF has moderate organic matter abundance, and the kerogen is mainly of Type II, which is now at the peak of oil generation. Shale minerals are mainly composed of carbonate (dolomite and calcite) and siliceous (quartz and feldspar) minerals, with extremely low clay mineral content. The pore types are mainly intergranular pores (inter-P), intragranular pores (intra-P), and microfractures associated with mineral particles. The pore space is contributed predominantly by micropores of 0.5–1.2 nm and mesopores of 10–50 nm, whereas macropores are underdeveloped. The pores are mostly ink bottle- and slit-shaped, and the pore connectivity is relatively poor. The pore development of shale in the FF is influenced by organic matter abundance, thermal maturity, mineral composition, etc. Organic matter content (TOC), thermal maturity (Ro), and carbonate minerals have a positive effect on pore development, and the pore volume (PV) increases with TOC, Ro, and carbonate minerals. While clay minerals show a negative effect, the PV decreases with clay minerals. Additionally, the influence of the clay mineral content on the pore morphology of shale should not be ignored. This study investigates the pore structure and geochemical characteristics of the alkaline lacustrine shale of FF in Mahu Sag, which is significant to deepen the understanding of alkaline lacustrine shale and to improve the production of shale oil.
Characterization and Origin of Basalt-Derived Carnelian in the Mesozoic Newark Basin, New Jersey, USA
Authors: Volkert Richard A. , Gorring Matthew L. , Peck William H. , Stanford Scott D.
Published: September 2023

Carnelian occurs locally in New Jersey in the Newark basin as medium- to coarse-size pebbles in fluvial gravel and alluvium and colluvium formed from erosion of Lower Jurassic Preakness Basalt. Vesicles and molds of glauberite are preserved on lower surfaces and botryoidal textures on the upper surfaces of some pieces. The microstructure consists of length-fast chalcedony characterized by parallel fibrous bundles overlain by repetitive, wavy extinction bands. Only peaks of ɑ-quartz and minor moganite are recognized in X-ray diffraction patterns. Carnelian contains 97–98 wt.% SiO2, ~1.0 wt.% Fe2O3, and 1.0–1.4 wt.% LOI; other major elements are <0.1 wt.%. Trace element abundances are low except for Y, Nb, Ta, W, Th, and U. Rare earth element (REE) patterns display heavy REE enrichment and large negative Eu anomalies. Most trace elements were mobilized from Proterozoic sources, whereas Si was likely derived from the alteration of basaltic glass in the Preakness. Carnelian δ18OVSMOW values are high and range from +18.3 to +31.2‰, comparable to global occurrences of volcanic rock-derived chalcedony. We propose that carnelian precipitated in the first Preakness flow from the mixing of hydrothermal fluid with meteoric water under conditions of low temperature (20–80 °C) and neutral to slightly alkaline pH.