bluuebunny/crossref_metadata_2025 huggingface dataset:
CONSUMO DE ÁLCOOL EM UNIVERSITÁRIO E SUA ASSOCIAÇÃO COM O COMPORTAMENTO SEXUAL DE RISCO: UMA REVISÃO SISTEMÁTICA
Authors: Sousa Kennedy Stênio da Paz , Nunes Jomar Diogo Costa , Gomes Marianne César
Published: May 2023

O consumo de substâncias psicoativas, principalmente o álcool, encontra-se presente em diversos meios de comunicação, geralmente tendo seu uso associado a fatores desejáveis como poder, prazer, sucesso financeiro e sexual. Os jovens universitários quando ingressam em cursos de graduação, demonstram mudanças comportamentais, ocasionadas por novas responsabilidades, além de terem maior contato e oportunidade de uso de álcool, drogas e prática de sexo inseguro. Assim, tornam-se mais vulneráveis aos comportamentos sexuais de risco (CSR), como relação sexual desprotegida, multiplicidade de parceiros e uso de drogas (lícitas ou ilícitas). Os CSR podem ter como consequência as infecções sexualmente transmissíveis (ISTs) e a gravidez não planejada. OBJETIVO: Analisar como o consumo de álcool por universitários, associa-se ao comportamento sexual de risco desses indivíduos. METODOLOGIA: Trata-se de uma revisão sistemática em que a busca de artigos para pesquisa ocorreu no mês de agosto de 2022 nas bases de dados LILACS, SciELO e PubMed, resultando em 313 artigos, que após os critérios de inclusão e exclusão resultaram em 22 artigos para o desenvolvimento do estudo. RESULTADOS: Constatou-se um alto nível de consumo de álcool entre os universitários, com elevada propensão à comportamentos sexuais de risco, principalmente não utilizar preservativos e múltiplos parceiros sexuais. CONCLUSÃO: Existe associação entre o consumo de álcool e o comportamento sexual de risco entre os acadêmicos e que existe à necessidade de uma intervenção para conscientizar e educar esses jovens à respeito da disseminação de IST’s.
DIFICULDADES NA AMAMENTAÇÃO DE LACTENTES COM FISSURA LABIOPALATINA
Authors: Silva Jorgnelma Ferreira , Freire Naiara Gabrielly Costa , De Souza Natasha de Almeida , Da Silva Fabiana Morbach , Lima Nadime Dias , Dos Santos Ravenna Cardoso , Feitosa Lana Ramos , Costa Carla Monique Lavareda
Published: May 2023

A partir da malformação congênita ocorrida pela 4ª semana a 12ª semana de vida uterina, com etiologia multifatorial , a fissura labiopalatina consiste em processos faciais acometidos com irregularidades o qual , dependendo da complexidade da abertura acarretará em dificuldades para a amamentação de lactantes. Neste sentido, o objetivo deste estudo é expor as principais dificuldades quanto ao processo de amamentação, trazendo referências atualizadas sobre o tema vinculado ao conhecimento científico. Para tal, realizou-se uma revisão integrativa de literatura com busca de artigos originais e revisões indexadas na base de dados da Biblioteca Virtual em Saúde (BVS), disponíveis pela seleção das plataformas LILACS, BDENF e MEDLINE, adotando critérios de inclusão e exclusão de artigos. Dentre os achados, 70% deles foram de origem internacional, e demonstram que, os lactantes encontram dificuldades para a amamentação conforme o grau da fissura labiopalatina, quanto maior a complexidade da fenda, menor a chance de se realizar o Aleitamento Materno Exclusivo (AME) e as principais dificuldades encontradas foram: desnutrição, perda de peso, sucção débil, pega inadequada da mama e deglutição prejudicada. Destaca-se, também, que, na maioria dos estudos abordados, as mães apresentam dificuldades frente ao diagnóstico não esperado. Portanto, torna-se indispensável aos profissionais da equipe de enfermagem ter o conhecimento científico e preparo assistencial para propor a família dos lactantes formas viáveis para a amamentação.
ATENDIMENTO ÀS VÍTIMAS DE ACIDENTE VASCULAR ENCEFÁLICO ISQUÊMICO EM UMA UNIDADE DE REFERÊNCIA INTERIORIZADA
Authors: De Almeida Deybson Borba , Leite Fabrícia Cristine Santos , Amaral Jocelio Matos , Aguiar Ricardo Santos
Published: May 2023

O atendimento às vítimas de Acidente Vascular Encefálico (AVE) precisa ser rápido e efetivo, a fim de reduzir mortalidade e complicações na fase aguda. Assim, esse estudo teve como objetivo identificar o perfil do atendimento prestado às vítimas de AVE isquêmico agudo em um Hospital de Referência no Interior da Bahia. Trata-se de um estudo documental, transversal e quantitativo, desenvolvido através da análise de 31 prontuários de vítimas de AVE Isquêmico atendidas em 2019. Sobre o perfil de atendimento, a admissão via Serviço Móvel de Urgência foi a mais frequente. Não houve registros da aplicação de escalas de avaliação neurológica. Quanto ao tempo de realização das etapas de atendimento, identificou-se que, a partir da média geral do tempo utilizado, o Acolhimento com Classificação de Risco e o acionamento do código de AVEi foram realizados fora do tempo ideal. Enquanto isso, embora o início da neuroimagem tenha sido dentro do tempo preconizado, os resultados dos exames não ficaram disponíveis com celeridade. Quanto à realização da trombólise, embora a média geral de tempo utilizado tenha sido ideal em relação ao início dos sintomas, essa não teve celeridade quando comparada ao tempo de admissão na unidade. Além disso, o tempo para transferência do paciente para unidade de terapia intensiva foi aquém do ideal. Foi identificada também a deficiência nos registros das ações realizadas, inclusive da enfermagem. As fragilidades existentes denotam a necessidade de medidas para aprimoramento dos protocolos e fluxogramas institucionais que permitam maior celeridade no atendimento às vítimas de AVE isquêmico.
Protection of wildlife sites: individual legal constructions and models of their implementation (regional features)
Authors: Pletnikov Viktor Sergeevich
Published: May 2023

The author focuses on the fact that the normative legal structure is implemented within the framework of various models. Moreover, every model that has developed in practice has the right to exist, of course, with the exception of defective models (including those recognized as such). Close attention is paid to the peculiarities of the application of certain legal constructions due to the models of its implementation (Articles 258 of the UKRF, Articles 7.11 and 8.37 of the Administrative Code of the Russian Federation). Special attention should be paid to the generalization of the practice of applying norms that ensure the protection of wildlife objects in the regions of Russia. At the same time, the emphasis is placed on those norms that are implemented depending on the region. The analysis, comparative research, as well as the legal and technical method used to prepare the text of the article, allowed us to formulate conclusions and recommendations aimed at solving problems arising in the field of protection of wildlife objects, both for employees of the bodies of inquiry and for supervising prosecutors. In particular, in order to give uniformity to legal practice, the implementation of legal construction strictly within the framework of a single model, it is necessary: 1) the legislator should pay close attention to the quality of the legal structure being formed; 2) to oblige the subject with the right of official interpretation, in case of occurrence of various models of implementation of the normative establishment, with a certain periodicity, to prepare materials explaining the content; 3) police officers should be guided by the explanations contained in the acts of interpretation; 4) in the extraction of hunting resources without permission and without the person in whose name the permit was issued, the act must be considered illegal hunting; 5) it is necessary to strengthen control by supervising prosecutors over the content of the decisions issued on the refusal to initiate criminal proceedings, on the initiation of criminal cases and the suspension of criminal proceedings, on the facts of illegal hunting.
Lyrical miniatures by Grigory Petnikov: historical and cultural context
Authors: Tsaregorodtseva Svetlana Sergeevna , Pogodina Yuliya Yur'evna
Published: May 2023

Grigory Nikolaevich Petnikov (1894-1971) was a Russian and Ukrainian poet, translator, publisher. He actively published as a poet during the futuristic period (1913-1922), when he joined the literary avant-garde, was the Second Chairman of the Globe and one of the founders of the Kharkov publishing house "Liren". Since the mid-20s, Grigory Petnikov has been mainly engaged in translations and is still better known as a translator of myths of Ancient Greece, fairy tales of the brothers Grimm, Ukrainian and Belarusian folk tales, poems by Taras Shevchenko, prose by Ivan Franko, Marko Vovchok, German poetry. The second period of Grigory Petnikov's poetic creativity began with the time of the thaw and lasted until the last years of the poet's life. In 1958, Petnikov moved to the Crimea, wrote a lot and actively published as a poet. The article attempts to analyze the late poems-miniatures of Grigory Petnikov from his last lifetime collection "Lyrics", published in 1969. Special attention is paid to the genre and style features of Petnikov's lyrical miniatures, the cultural and historical context of the poems; an attempt is made to determine whether the poems from the collection "Lyrics" belong to the poetic trends and trends in the lyrics of the Silver Age.
Nurses’ Leadership in the Work: A Systematic Review
Authors: Qtait Mohammed
Published: May 2023

Background: Nurse leadership has a significant impact on the healthcare team’s ability to produce good patient outcomes.
Objective: The objective of this research is to determine what strategies are most useful for empowering nurses to take on leadership roles in a hospital setting.
Method: A systematic literature review was conducted, utilising Preferred Reporting Items for Systematic Reviews (PRISMA). The databases that were featured are PubMed, CINAHL, and Google Scholar from 2011 to 2023. A quality appraisal was used to assess the quality of the studies.
Result: There were 97 articles found in a literature search. A total of eight articles met the inclusion criteria.
Conclusion: The evidence shows that interventions to improve nurses’ leadership are complex and need to address cognitive, interpersonal as well as psychological empowerment, emotional intelligence, and critical reflexivity skills. Multicomponent, theory-based, and mixed-format programmes may be better suited to facilitate nurses’ leadership in the hospital setting.
Nursing implications: Efforts to improve nurses’ clinical leadership in healthcare settings should take into account both their theoretical understanding of the issue and their actual experience in finding workable solutions through teamwork. As a result, it would encourage high-quality care, nurse satisfaction, and nurse retention.
Pregnancy Risk and Coerced Interventions after Dobbs
Authors: Kukura Elizabeth
Published: May 2023

Only nine months after the Supreme Court eliminated the federal constitutional right to abortion in Dobbs v. Jackson Women’s Health Organization, fourteen states had banned abortion entirely, and experts estimate the ultimate number of states imposing complete or near-complete restrictions on abortion care will likely rise to twenty-four. Millions of people with the capacity for pregnancy now (or will soon) live in places where getting pregnant means there is no choice other than to carry the pregnancy to term and give birth. One underappreciated, though critically important, impact of Dobbs is the extent to which newly enacted abortion restrictions will increase both the number of people with high-risk pregnancies and, relatedly, the number of people who are coerced into medical treatment during labor and delivery. Such mistreatment in the form of coerced interventions will compound the harm of forced pregnancy after Dobbs with negative consequences for the physical and emotional well-being of birthing people and their babies.
The Ripple Effects of Dobbs on Health Care Beyond Wanted Abortion
Authors: Manian Maya
Published: May 2023

The Supreme Court’s momentous decision in Dobbs v. Jackson Women’s Health Organization to overturn fifty years of precedent on the constitutional right to abortion represents a sea of change, not only in constitutional law, but also in the public health landscape. Although state laws on abortion are still evolving after Dobbs, the decision almost immediately wreaked havoc on the delivery of medical care for both patients seeking abortion care and those not actively seeking to terminate a pregnancy. This Article also argues that focusing the public’s attention on the deleterious consequences of abortion bans for health care beyond wanted abortion care could help fend off further restrictions on abortion. Post-Dobbs, abortion policy is largely in the hands of voters, as state legislation and ballot initiatives now dictate the fate of abortion rights. Exposing Dobbs’s ripple effects on forms of health care that are less stigmatized than wanted abortion care could help educate the public on the links between abortion and a wide array of health care issues. Informing the public about the wide-ranging health care consequences of overturning Roe could help reframe abortion bans as government mandates that interfere with the physician–patient relationship and harm women’s health. Reframing abortion as a core health care concern for the public—as opposed to a debate about a constitutional right to privacy—is a potentially powerful strategy for resisting anti-abortion legislation post-Dobbs.
INDEPENDÊNCIA DA AUTORIDADE FISCALIZADORA E EFETIVIDADE DA PROTEÇÃO DE DADOS PESSOAIS NA SOCIEDADE EM REDE
Authors: Santiago Mariana Ribeiro , Santos Paulo Jorge
Published: May 2023

O presente artigo busca demonstrar a importância de se conceder independência e autonomia à Autoridade de Proteção de Dados Pessoais, instituição que se constitui como base para a eficácia e efetividade da Lei Geral de Proteção de Dados Pessoais, através de sua transformação em autarquia especial federal. Para este fim, é apresentado um desenho do atual contexto por que passa a sociedade e, consequentemente, a economia mundial, os quais ganharam os novéis conceitos de sociedade em rede e economia da informação. Procede-se a uma análise do que venha ser Big Data, com o intuito de sedimentar o caminho para se entender o contexto em que nasceram as leis de proteção aos dados pessoais em todo o mundo. Percorre-se a evolução dos normativos de proteção da privacidade e dados pessoais, os quais foram delineados em quatro gerações. Explica-se o conceito, a função, a importância e a posterior ineficácia do papel do consentimento como instrumento único de proteção de tais direitos. Por fim, busca-se demonstrar a importância de dotar tal entidade de um mínimo de independência e autonomia, imperativo para que essas instituições alcancem a finalidade para a qual foi criada. O método de abordagem utilizado é o dedutivo, com o auxílio do método de pesquisa bibliográfico. Conclui-se que a independência de uma autoridade nacional de proteção de dados amplia a efetividade da legislação específica sobre a matéria.
HIPERPRESIDENCIALISMO, CONSTITUCIONALISMO ABUSIVO E NOVO CONSTITUCIONALISMO LATINO-AMERICANO
Authors: Bacha e Silva Diogo , Barbosa Quinaud Pedron Flávio
Published: May 2023

O artigo explora uma leitura acerca dos acontecimentos recentes na América Latina e, ao mesmo tempo, realiza uma análise do regime de governo instituído no novo constitucionalismo latino-americano. Para alcançar o objetivo, há o entrelaçamento de categorias teóricas como constitucionalismo abusivo e hiperpresidencialismo. A questão é indagar se e em que medida o novo constitucionalismo latino-americano adotaria um hiperpresidencialismo e, a partir daí, possibilitaria que o Poder Executivo utilizasse os poderes constitucionais contra a própria Constituição. Diante das intensas críticas dirigidas à parte orgânica da Constituição no novo constitucionalismo latino-americano, o ensaio é uma releitura de acordo com uma teoria constitucional latino-americana
DESAFIOS DA COVID-19 À SEGURIDADE SOCIAL BRASILEIRA
Authors: Wolfgang Sarlet Ingo , Ferreira Barbosa Jeferson
Published: May 2023

O presente trabalho investiga as medidas para proteger empregos e renda, as medidas de auxílio à economia e as principais inciativas para facilitar o acesso ao sistema de proteção social, tomadas em nível federal, entre março de 2020 e outubro de 2021, no combate ao coronavírus. O objetivo é investigar as conexões de tais medidas com o sistema de seguridade social brasileiro. A pesquisa é predominantemente do tipo qualitativa, com uma abordagem mais indutiva que dedutiva. As medidas de proteção a empregos e renda aparecem em primeiro lugar devido à sua conexão com as medidas de auxílio à economia. Depois seguem as medidas de estímulo à economia. O último tópico trata das principais inciativas para facilitar o acesso ao sistema de proteção social. O que se constata é a existência de significativo risco de instabilidade para o sistema de seguridade social brasileiro, tendo em vista a quantidade de recursos políticos, sociais e econômicos mobilizados pelo Brasil em uma base altamente insegura. Risco que é intensificado pelos embates institucionais e pelos déficits de organização. O Benefício Emergencial é uma experiência nova e oferece oportunidade para que se discuta a responsabilidade do Estado e seus limites. Mesmo as medidas direcionadas a manter emprego e renda possuem uma sinergia sem precedentes com a proteção da economia, mas aqui possivelmente não se esteja diante de uma particularidade brasileira.
PARA ALÉM DO PODER CONSTITUINTE:
Authors: Prado Danilo Luchetta , Casalino Vinícius
Published: May 2023

O trabalho pretende questionar a dicotomia entre poder constituinte e de reforma como fundamento das cláusulas pétreas do ordenamento constitucional. Para isso, foram revisitadas as obras de Emmanuel Joseph Sieyès e Carl Schmitt, juntamente com a análise de obras contemporâneas, das quais se destacam os trabalhos de Monika Polzin, Ulrich Preuss, Norberto Bobbio e Luigi Ferrajoli. O objetivo consiste em demonstrar que uma suposta hierarquia do poder constituinte, como “representante da nação”, não é suficiente para fundamentar a imutabilidade de normas constitucionais. A conclusão desse artigo é de que esse fundamento é insuficiente, mas que isso não implica a inexistência de um núcleo imutável, oportunidade em que o trabalho conclui pela existência de um núcleo essencial de direitos fundamentais inalterável, cujo fundamento deriva do próprio sistema democrático.
A RELATIVIZAÇÃO DA PENHORABILIDADE SALARIAL E O INSTITUTO DA DESCONSIDERAÇÃO DA PERSONALIDADE JURÍDICA NAS DEMANDAS TRABALHISTAS EM ATENDIMENTO AO PRINCÍPIO DA DIGNIDADE DA PESSOA HUMANA COM APLICABILIDADE RECÍPROCA.
Authors: Santiago Pereira Émerson , Mollica Rogério
Published: May 2023

O presente estudo buscou examinar na seara trabalhista os padrões legislativos de aplicabilidade do instituto da desconsideração da personalidade jurídica e (im) penhorabilidade do salário em respeito ao princípio basilar da dignidade da pessoa humana. Preliminarmente, foi estabelecido a conceituação do princípio ora citado, sob a premissa de subsidiar compreensões sobre sua aplicabilidade, relevância e mérito social empregados no bojo de uma sociedade com possibilidade de estabelecer parâmetros mínimos a serem observados pelos operadores de direito. Em seguida procurou constituir considerações sobre a utilização do instituto da desconsideração da personalidade jurídica e sua convergência processual diante de atos fraudulentos e inibidores de cumprimento obrigacional. Por último, discutiu-se a relativização da penhorabilidade salarial em processos trabalhistas, tendo em vista o caráter alimentar esculpido nestes, fomentando a aplicação cumulada com o instituto da desconsideração, observando os regramentos existentes em atendimento e respeito ao princípio da dignidade humana. Por meio do método dedutivo com pesquisas bibliográficas e jurisprudências participou na propositura de ponderações e considerações hábeis a ascender e impulsionar a essência do princípio da dignidade humana no apreço das demandas processuais e sua aplicabilidade processual de forma recíproca.
EXIGIBILIDADE DO DIREITO À EDUCAÇÃO EM FACE AOS PRINCÍPIOS CONSTITUCIONAIS DA IGUALDADE E DA DIFERENÇA
Authors: Correa Doutor Paulo Sergio de Almeida , Vieira de Abreu Joniel
Published: May 2023

Esta pesquisa teve por finalidade compreender a importância dos princípios da igualdade e da diferença para a promoção do direito, mediante a oferta da educação enquanto um direito fundamental que impõe responsabilidades ao Estado, bem como entender a funcionalidade dos critérios formais a serem cumpridos para assegurar a exigibilidade do direito à educação. Por que os princípios da igualdade e da diferença são relevantes para tornar efetivas as ações do Estado mediante a promoção de direitos? O que significa pensar a educação enquanto um bem jurídico a ser ofertado pelo Estado a fim de promover direitos? Sob quais fundamentos jurídico-constitucionais se demanda a exigibilidade do direito à educação perante o Estado? Realizou-se um estudo bibliográfico envolvendo produções teóricas de autores versando sobre o objeto de estudo investigado, assim como se deu prioridade às análises de normas contidas na Constituição da República Federativa do Brasil de 1988 e no texto da Lei 9.394 de 1996. Por se constituir um direito público subjetivo, o combate em favor da efetivação do direito à educação poderá ensejar demanda judicial perante o ente público que esteja a promover frontal ameaça, ou, ao agir com o propósito de dar efetividade, comete lesão a esse bem jurídico tido como direito fundamental, por força de previsão constitucional.
Taşıma Şekillerine Göre İhracatı Etkileyen Faktörler: Türkiye Üzerine Bir Uygulama
Authors: ALBAYRAK Zehra , KAPLAN Fatih
Published: May 2023

Bu çalışmanın amacı, Türkiye’nin taşıma şekillerine göre ihracatını etkileyen faktörleri araştırmaktır. Bu amaç doğrultusunda; Türkiye’de kara yolu, demir yolu, deniz yolu ve hava yolu taşıma şekilleri kullanılarak gerçekleştirilen ihracat hacmini etkilemesi muhtemel faktörler belirlenmiştir. 2000:01-2019:12 dönemine ait aylık verilerin kullanıldığı çalışmada, taşıma şekillerine göre (kara yolu, demir yolu, deniz yolu ve hava yolu) ihracat verileri bağımlı değişken, Türkiye’nin sanayi üretim endeksi, AB ülkelerinin sanayi üretim endeksi, reel döviz kur endeksi ve Brent petrol fiyatı ise bağımsız değişkenler olarak ele alınmıştır. Yapısal kırılmaları dikkate alan FMOLS düzey değişimi ve FMOLS rejim değişimi analizleri sonucunda, tüm taşıma şekillerine göre ihracatı etkileyen en önemli değişkenin Türkiye’nin sanayi üretim endeksi olduğu belirlenmiştir. Sanayi üretim endeksinin ardından reel döviz kur endeksinin, oluşturulan model ve kullanılan yöntemlere göre; Türkiye’nin taşıma şekillerine göre ihracatını etkileyen diğer önemli değişkenlerden biri olduğu tespit edilmiştir. Sonuç olarak Türkiye’nin taşıma şekillerine göre ihracatını, rekabetçi kur politikalarından daha çok üretim kapasitesini arttırmaya yönelik politikaların etkileyeceği tespit edilmiştir.
TOLEDO: Accelerated Maestro GUI molecular dynamics simulations
Authors: Carmena-Bargueño Miguel , Martínez-Cortés Carlos , Banegas-Luna Antonio Jesús , Pérez-Sánchez Horacio
Published: May 2023

Classical Molecular Dynamics (MD) simulate the dynamical evolution of biological systems at the atomic level. Using MD in conjunction with high-performance computing (HPC) architectures we can evaluate the possible interactions between a ligand library against one protein target to find a drug that can influence a protein target to cure a disease. Simultaneously we can also obtain information about their dynamical evolution  One of the main software of MD is Desmond, which uses Maestro to set up, run and analyze MD with a graphical interface (GUI), allowing it to be used by non-expert users. However, using the GUI, users can typically run only one short (less than 1000 ns) MD simultaneously.  Our work aims to create a method/protocol to run several MD simultaneously on a remote HPC cluster within Maestro-Desmond. In this work, we provide a method called TOLEDO (Throughput Optimization of Ligand-Protein systems Exploration through Dynamics simulation in Optimized HPC systems) to overcome such limitations and run several MD simultaneously time. Also, TOLEDO is independent of the time limitation of many clusters, the only limitation is the storage space that users have in the cluster. To run TOLEDO, first, we prepare/set up the protein-ligand complex before running MD via Maestro GUI. Next, we run the main script of TOLEDO to run several MD in a supercomputer such as Turgalium of CIEMAT (https://www.ceta-ciemat.es/) or SAGA (https://documentation.sigma2.no/hpc_machines/saga.html), when the MD are finished. TOLEDO run the analysis. Finally, the results obtained by users are the reports and the graphics, which are very simple to interpret. In summary, TOLEDO is a tool that allows researchers to run MD with higher throughput than the Maestro GUI.
Open-chain thiamine analogues as potent inhibitors of thiamine pyrophosphate (TPP)-dependent enzymes
Authors: Chan Alex H. Y. , Ho Terence C. S. , Leeper Finian James
Published: May 2023

A common approach to studying thiamine pyrophosphate (TPP)-dependent enzymes is by chemical inhibition with thiamine/TPP analogues which feature a neutral aromatic ring in place of the positive thiazolium ring of TPP. These are potent inhibitors but their preparation generally involves multiple synthetic steps to construct the central ring. We report efficient syntheses of novel, open-chain thiamine analogues which potently inhibit TPP-dependent enzymes and are predicted to share the same binding mode as TPP. We also report some open-chain analogues that inhibit pyruvate dehydrogenase E1-subunit (PDH E1) and are predicted to occupy additional pockets in the enzyme other than the TPP-binding pockets. This opens up new possibilities for increasing the affinity and selectivity of the analogues for PDH, which is an established anti-cancer target.
Catalysis distillation neural network for the few-shot open catalyst challenge
Authors: Deng Bowen
Published: May 2023

The integration of artificial intelligence and science has resulted in substantial progress in computational chemistry methods for the design and discovery of novel catalysts. Nonetheless, the challenges of electrocatalytic reactions and developing a “large-scale language model” in catalysis persist, and the recent success of ChatGPT's (Chat Generative Pre-trained Transformer) few-shot methods surpassing BERT (Bidirectional Encoder Representation from Transformers) underscores the importance of addressing limited data, expensive computations, time constraints and structure-activity relationship in research. Hence, the development of few-shot techniques for catalysis is critical and essential, regardless of present and future requirements. This paper introduces the Few-Shot Open Catalyst Challenge 2023, a competition aimed at advancing the application of machine learning technology for predicting catalytic reactions on catalytic surfaces, with a specific focus on dual-atom catalysts in hydrogen peroxide electrocatalysis. To address the challenge of limited data in catalysis, we propose a machine learning approach based on MLP-Like and a framework called Catalysis Distillation Graph Neural Network (CDGNN). Our results demonstrate that CDGNN effectively learns embeddings from catalytic structures, enabling the capture of structure-adsorption relationships. This accomplishment has resulted in the utmost advanced and efficient determination of the reaction pathway for hydrogen peroxide, surpassing the current graph neural network approach by 16.1%. Consequently, CDGNN presents a promising approach for few-shot learning in catalysis.
The poisonous truth about the mercury drop test: the effect of elemental mercury on Pd(0) and Pd(II)ArX intermediates
Authors: Chagunda Ian , Fisher Tiago , Schierling Makenna , McIndoe Scott
Published: May 2023

The mercury drop test is a widely used method for distinguishing between homogeneous and heterogeneous catalysis in organometallic systems. However, recent research has highlighted the limitations of this test due to the intrinsic reactivity of some organometallic compounds towards elemental mercury. In this study, we used real-time mass spectrometry with charge-tagged substrates to investigate the effect of elemental mercury on LnPd0 and PdIIArX intermediates common in palladium-catalysed cross-coupling reactions. Our findings demonstrate that mercury can interact with both species through redox-transmetallation and amalgamation processes, leading to a decrease in catalytic activity. This result further calls into question the fundamental assumption of mercury selectivity towards heterogeneous catalytic species. These results highlight the importance of careful consideration of the results the mercury drop test provides and encourages further research to gain a more comprehensive understanding of catalyst poisoning mechanisms.
La oferta informativa de los medios de comunicación del Perú en periodos electorales y su rol en el fortalecimiento de la democracia: análisis de caso
Authors: Vílchez Samanez Prisea Georgina , Palomino Villanueva Luis Fernando
Published: May 2023

Este artículo analiza las características de la oferta informativa de los medios de comunicación escritos del Perú en un periodo electoral concreto, el de las Elecciones Regionales y Municipales 2018, y reflexiona sobre su rol y aporte a la democracia. Para la recolección de datos se utilizó el monitoreo de medios, técnica cuantitativa que tiene como instrumentos el libro de códigos y la ficha de codificación. En total, se revisaron 3261 noticias de seis diarios seleccionados (tres de Lima y tres de otras regiones). Esta investigación puso en evidencia algunas tendencias o patrones sobre las características de la oferta informativa de los medios seleccionados, entre ellas que, en las elecciones del 2018, el eje del proceso electoral fue el candidato y no el ciudadano; que existió una escasa visibilización de temas clave como participación ciudadana en el proceso electoral y el financiamiento de los partidos; que la mayoría de las noticias sobre las elecciones fue “encuadrada” como conflicto; que la nota informativa fue el formato periodístico más utilizado; y que hubo un escaso uso de la opinión, lo cual hubiera permitido un mayor y mejor debate, y una deliberación pública sobre temas de interés común. El estudio saca a la luz aquellas características de la oferta informativa que ponen en cuestión el rol político de los seis medios de comunicación analizados y su aporte al fortalecimiento de la democracia.
Claves de la narrativa 360° a través del estudio de la retransmisión de la gala de los Premios Goya en RTVE
Authors: Caerols Mateo Raquel , Casal Balbuena Manuel Gerardo , Garrido Pintado Pablo
Published: May 2023

El empuje del uso de narrativas 360° es un fenómeno que se viene popularizando en redes, especialmente, desde el 2015. En España, el Laboratorio de Innovación Audiovisual de Radio y Televisión Española (Lab RTVE) ha experimentado con esta tecnología ofreciendo grabaciones de espectáculos y documentales, y al ser pioneros en la grabación del primer episodio de realidad virtual interactiva de una serie de televisión. Con objeto de conocer las características, retos y dificultades de la retransmisión de eventos en 360°, el presente trabajo toma como caso de estudio la retransmisión de la gala de los Premios Goya en RTVE. Se trata de un evento en directo donde se premia a los personajes más destacados del cine español durante el año anterior. El método escogido parte de una entrevista previa a dos responsables del Lab RTVE encargados de la realización 360° de la gala. A partir de los datos recabados en la entrevista se diseñó un modelo de análisis de contenido aplicado a un fragmento de la producción. Del análisis realizado se deduce que, pese a que la retransmisión tradicional y 360° comparten aspectos formales, existen unas marcadas diferencias entre las narrativas. Unas diseñadas para ser visionadas (narrativa tradicional) y otras para ser experimentadas (narrativa 360°). La convivencia entre ambos ecosistemas sígnicos se presenta difícil, pero no imposible, ya que ambos tipos de realización comparten muchos parámetros relativos a la producción de significado. Asimismo, se ve necesaria una estandarización de la tecnología 360° para una vivencia satisfactoria en primera persona y una aclimatación por parte del espectador-usuario.
Rice Husks as Green Adsorbents for Removal of Anionic Dyes: Kinetic, Isotherm and Thermodynamic Adsorption Studies
Authors: Ahmad Nur , Palapa Neza Rahayu , Taher Tarmizi
Published: May 2023

Rice husk, a green adsorbent, was used for procion red adsorption. Analysis with BET, XRD, FTIR, and SEM confirmed the formation of rice husk. The results indicate that rice husk is more porous and has a rougher surface. The surface of the rice husk has a non-uniform shape and uneven morphology. The pore of rice husk is critical to the adsorption process of procion red. The procion red will enter the pore of the rice husk to make an interaction. The rice husk has a surface area, pore volume, and pore diameter of 7.08 m2/g, 0.011 cc/g, and 3.14 nm, respectively. The vibrational peak at 3448 1620, 1103, and 794 cm−1. the XRD powder patterns of rice husk characterization diffraction peak at 2θ 23°. Rice husk’s adsorption system for procion red removal follows PSO kinetic and Freundlich isotherm models with a maximal removal capacity of 158.730 mg/g. This study sheds light on the effectiveness of rice husk as an adsorbent for procion red contaminants.
DEVELOPMENT OF THE REMOTE BANKING SYSTEM
Authors: Vyadrova Inna , Mozgovska Anna , Vyadrova Valeria
Published: May 2023

In the context of innovative development of the national economy, globalization and integration of financial markets, an increase in the share of non-cash payments made using electronic payment instruments, expansion of banking service channels and transition to remote banking services (RBS) is a priority vector for the development of the payment system and the banking sector of Ukraine.
Today, the economy is undergoing processes of information and financial transformation. The banking sector is most susceptible to the impact of such processes, as banks, being financial intermediaries and possessing significant material resources, are actively implementing modern financial technologies in their operations, bringing innovative financial products to the market, and transferring their operations from offices to online banking. Along with the resulting benefits for banks and their customers, this transformation is becoming one of the reasons for the growth of information risks in banking.
The relevance of the topic is related to the existence of problems and imperfections in the system of remote banking services in Ukrainian banks.
That is why the paper considers the essence and main features of remote banking services at the current stage of development of the banking system of Ukraine. The author analyzes the set of banking services through which bank customers can remotely perform various financial transactions. The article studies remote banking services in the United States of America, which is a leader in this area, in the countries of the European Union, as well as in modern Ukraine. The main types of remote banking are analyzed. The main types of risks are identified. The factors that hinder the development of remote banking in Ukraine and potential ways to overcome them are identified.
Every year, banks strive to improve and simplify their mobile phone applications, thereby attracting more and more customers. After all, it was the complexity and distrust of Internet banking that prevented this technology from spreading properly in Ukraine. The results of the study can be used in the analysis and development of mobile applications for banks.
Nursing Management During Public Health Emergencies
Authors: Zhou Qilan
Published: May 2023

Public health emergencies are difficult to predict, have complex causes, and are extremely destructive. In order to reduce the impact of public health emergencies, this paper introduces a refined nursing management method to deal with public health emergencies. By establishing a sound management system, implementing scientific management processes, ensuring the overall quality of nursing, and improving the logistics, etc., the cooperation between the medical staff can be improved, and the safety of personnel can be ensured.
Relationship Between the Efficacy of Low-Dose Glucocorticoids Combined with Tacrolimus in the Treatment of Adult Idiopathic Membranous Nephropathy and the Level of Serum Anti-PLA2R Antibodies
Authors: Guo Shanshan , Guo Li , Li Jiandong , Gong Youlan , Xu Yang , Chen Hang , Zheng Xijie
Published: May 2023

Objective: To further evaluate the efficacy and safety of low-dose glucocorticoids combined with tacrolimus in the treatment of adult idiopathic membranous nephropathy (IMN) in a clinical setting. Methods: We carried out a single-center prospective study of 88 patients with IMN who were admitted into the Affiliated Hospital of Hebei University from January 2019 to December 2021, and the participants were divided into two groups based on their serum anti-PLA2R antibody levels: the negative group and the positive group. 46 patients were positive for anti-PLA2R antibodies and 42 were negative. Results: After 6 months of treatment, the serum albumin, cholesterol, and 24h urine protein quantification in the anti-PLA2R negative group improved more significantly compared to the positive group (P < 0.05); after 6 months of treatment, the remission rate of the positive group was significantly lower than that of the negative group, and (P < 0.05); Conclusion: After treatment with tacrolimus combined with low-dose glucocorticoids, patients with idiopathic membranous nephropathy who were tested positive for anti-PLA2R antibodies had a higher overall remission rate compared those who were tested negative for serum anti-PLA2R antibodies.
Right Sub-axillary Incision for Right Pulmonary Vein Atresia in a Child: A Case Report and Literature Review
Authors: Zhang Weitao , Wei Xinhua , Zhang Jintao , Li Qun
Published: May 2023

Unilateral pulmonary vein atresia (UPVA) in children is a rare disease that is characterized by a recurrent pulmonary infection and hemoptysis in childhood. This paper is a report of a case of pulmonary venous atresia treated by a right sub-axillary incision. Hopefully, more literature can be produced to improve the awareness and treatment level of pulmonary vein atresia.
Systematic review and meta-analysis of maternal mortality ratio and related factors in the Islamic Republic of Iran
Authors: Khalili Malahat , Mashrouteh Mahdieh , Haghdoost Ali , Torkian Samaneh , Chegeni Maryam
Published: May 2023

Background: Maternal mortality is an indication of the health status of women in the society. Aims: To investigate the maternal mortality ratio, causes of maternal mortality, and related risk factors among Iranian women. Methods: Using the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) checklist and the Peer Review of Electronic Search Strategies (PRESS) guideline, we systematically searched electronic databases, and the grey literature, for publications in Farsi and English from 1970 to January 2022 for studies that reported the number of maternal deaths and/or maternal mortality ratio and their related factors. Data analysis was conducted using Stata 16 and 2-sided P ≤ 0.05 was considered statistically significant, if not otherwise specified. Results: A subgroup meta-analysis of studies conducted since 2000 estimated the maternal mortality ratio as 45.03 per 100 000 births during 2000–2004, 36.05 during 2005–2009, and 23.71 after 2010. The most frequent risk factors for maternal mortality were caesarean section, poor antenatal and delivery care, unskilled birth attendance, age, low maternal education level, lower human development index, and residence in rural or remote areas. Conclusion: There has been a significant decrease in maternal mortality in the Islamic Republic of Iran during the last few decades. Mothers in the country need to be monitored more carefully by trained healthcare workers during the pregnancy, delivery and postpartum periods so they can effectively handle postpartum complications, such as haemorrhage and infection, thereby further reducing maternal mortality.
Vaccine hesitancy in the Gulf Cooperation Council countries
Authors: Algabbani Aljoharah , AlOmeir Othman , Algabbani Fahad
Published: May 2023

Background: Vaccination has a tremendous impact on health at the regional and global levels, however, the tendency for people to hesitate on vaccination has been increasing in the past few decades. Aims: We assessed vaccine hesitancy and its determinants in the Gulf Cooperation Council countries. Methods: We conducted a literature review to assess peer-reviewed articles published up to March 2021 on vaccine hesitancy in the Gulf Cooperation Council countries using the Preferred Reporting Items for Systematic Reviews and Meta-Analyses approach. A search was conducted via PubMed and 29 articles were identified. After the removal of duplicates and irrelevant articles, 14 studies remained relevant and were used for the review. Results: Vaccine hesitancy in the Gulf Cooperation Council countries ranged from 11% to 71%. Differences in rates were noted for vaccine type, with COVID-19 vaccine having the highest reported hesitancy (70.6%). The likelihood of accepting vaccination was associated with previous individual acceptance of vaccine, specifically the seasonal influenza vaccine. The most common determinants of vaccine hesitancy were distrust in vaccine safety and concerns about side-effects. Healthcare workers were among the main sources of information and recommendations about vaccination, but 17–68% of them were vaccine-hesitant. The majority of the healthcare workers had never received any training on addressing vaccine hesitancy among patients. Conclusions: Vaccine hesitancy is prevalent among the publics and healthcare workers in the Gulf Cooperation Council countries. There is a need to continually monitor perceptions and knowledge about vaccines and vaccination in these countries to better inform interventions to improve vaccine uptake in the sub-region.
Luminancias:
Authors: Cartagena Proaño María Fernanda
Published: May 2023

Texto curatorial de la última muestra individual del artista contemporáneo Jose Luis Macas Paredes presentada en la galería de arte N24 en Quito, Ecuador. La sostenida investigación-acción del artista en y desde la pacha o tiempo-espacio andino continúa en dos series concebidas para el espacio de la galería: Luminancias y Achikyakushuyu (Dibujos de sol y agua). De la primera serie se analiza la restitución de gráficas y patrones precolombinos relacionados a la astronomía y a la luz como elemento activador. Las dinámicas composiciones también retoman el legado del neoconcreto brasilero. La segunda serie, integrada por dibujos en cianotipia, remite a la sincronía del artista con elementos vitales del mundo andino como son la agencia del sol y del agua. La exhibición se presentó en el marco del Kolla Raymi – Equinoccio de septiembre, festividad que honra al ciclo lunar, a las aguas, y a la fertilidad de la Pacha Mama.
Creando otro cuerpo posible: una vía de hacer desde el arte
Authors: Alarcón Pino Natalia
Published: May 2023

El presente ensayo nace de la investigación en práctica pictórica en la que busco desde diferentes formas de representar el cuerpo, tanto visible como invisible, reflexionar sobre su estatuto visual, por ello social y político. Por lo que, el presente texto aborda como ese cuerpo es posible mediantes otras formas de representar desde las artes visuales. Dando pie a pensar en el cuerpo sin órganos, que propone Artaud y toman Deleuze y Guattari, para salir de la organización del cuerpo y pensarnos fuera de lógicas espectaculares posicionarnos dentro del campo de las sensaciones y sentidos.
Arquitecturas Precolombinas: Representar y Habitar el pasado.
Authors: Montalvo Puente Carlos Eduardo
Published: May 2023

Resumen: Este artículo presenta un acercamiento a los procesos de investigación y curaduría desarrollados para la exhibición “ Arquitecturas Precolombinas: representar y habitar el pasado”. Esta exhibición se ha planteado como objetivo el acercamiento de los públicos contemporáneos a las relaciones entre personas, estructuras y paisajes, es decir al concepto de habitar, a través de las diferentes miradas de la arquitectura precolombina a través del tiempo. Para lograr su objetivo, la exhibición plantea un diálogo entre piezas arqueológicas, documentos, narraciones y testimonios, incluyendo datos de investigaciones recientes con tecnologías de punta.

Abstract: This paper aims to present the research and curatorship processes developed for the exhibition “Pre-Columbian Architectures: Represent and Inhabit the Past”. This exhibition points to  create a connection between the contemporary public and the interrelation of people, structures and landscapes enclosed in the concept of inhabit, by the views of the pre-columbian architectures across time. To achieve his goal, the exhibition proposes a dialog between archaeological artifacts, documents, narrations and testimonies, including recent investigation data collected with recent technologies.
Service Transformation as a Tool for Promoting Sustainable Rural Development in Central Java
Authors: Muhammad Adji Suradji , Tyas B. Hari Saptaning , Puspitasari Condrodewi , Mardhika Juang Gagah , Atmajha Maulana Chandra
Published: May 2023

The current developments in Information Technology (IT) should not only be utilized by the public and the private sectors but also by all parties effectively. The government must also be able to take advantage of these advances in many ways, such as in providing government services. The role of IT in managing government has now become an essential part of the society. This study examines the people's expectations in Melikan Village and focuses on using IT advances to create an independent village. The author then draws upon SDG theories to delineate the service transformation process. It is a qualitative study consisting of primary and secondary data. The data collection techniques used in this study include in-depth interviews, FGD, observations, and document analysis. The findings show that IT has become a vital need for the people in Melikan, but the village government fails to meet those expectations. The study suggests that the local government needs technological innovation to develop Melikan Village and add more personnel to help with government services.
The Impact of Regulation on Islamic Financial Institutions Toward the Monopolistic Practices in the Banking Industrial in Aceh, Indonesia
Authors: Fahmi Chairul
Published: May 2023

The ratification of Aceh regulation (Hereafter called Qanun) Number 11 of 2018 concerning Islamic Financial Institutions (Hereafter called Qanun LKS) has provided special rights for Islamic banking institutions, while non-Islamic banking institutions are not permitted to run their business in the province. At the same time, the central Government also decided to merge three state-owned Islamic banks, namely BNI Syariah, BRI Syariah, and Mandiri Syariah, to become Bank Syariah Indonesia (BSI). These policies have potentially violated Law on Antitrust, especially in Aceh Province. This article aimed to analyze whether the local Government's policy in enacting the Qanun LKS and consolidating the BSI is part of monopoly practices and unfair business competition in the banking sector in the Aceh region. This research was classified as normative qualitative research, where data was obtained from secondary sources, such as laws, books, journals and related studies. The results showed that the enactment of Qanun LKS has restricted conventional banking from expanding its business in the region. In addition, the Government’s policy to consolidate three state-owned Islamic banks, which control more than seventy-five of the market share in Aceh province, was considered contrary to the law on the Prohibition of Monopolistic Practices and Unfair Business Competition Number 5 of 1999.