bluuebunny/crossref_metadata_2025 huggingface dataset:
Oxidation of Styrene to Benzaldehyde Catalyzed by Schiff Base Functionalized Triazolylidene Ni(II) Complexes
Authors: Lawal Nasir S. , Ibrahim Halliru , Bala Muhammad D.
Published: August 2022

Four new Schiff base functionalized 1,2,3-triazolylidene nickel complexes, [Ni-(L1NHC)2](PF6)2; 3, [Ni-(L2NHC)2](PF6)2; 4, [Ni-(L3NHC)](PF6)2; 7 and [Ni-(L4NHC)](PF6)2; 8, (where L1NHC = (E)-3-methyl-1-propyl-4-(2-(((2-(pyridin-2-yl)ethyl)imino)methyl)phenyl)-1H-1,2,3-triazol-3-ium hexafluorophosphate(V), 1, L2NHC = (E)-3-methyl-4-(2-((phenethylimino)methyl)phenyl)-1-propyl-1H-1,2,3-triazol-3-ium hexafluorophosphate(V), 2, L3NHC = 4,4′-(((1E)-(ethane-1,2-diylbis(azanylylidene))bis(methanylylidene))bis(2,1-phenylene))bis(3-methyl-1-propyl-1H-1,2,3-triazol-3-ium) hexafluorophosphate(V), 5, and L4NHC = 4,4′-(((1E)-(butane-1,4-diylbis(azanylylidene))bis(methanylylidene))bis(2,1-phenylene))bis(3-methyl-1-propyl-1H-1,2,3-triazol-3-ium) hexafluorophosphate(V), 6), were synthesised and characterised by a variety of spectroscopic methods. Square planar geometry was proposed for all the nickel complexes. The catalytic potential of the complexes was explored in the oxidation of styrene to benzaldehyde, using hydrogen peroxide as a green oxidant in the presence of acetonitrile at 80 °C. All complexes showed good catalytic activity with high selectivity to benzaldehyde. Complex 3 gave a conversion of 88% and a selectivity of 70% to benzaldehyde in 6 h. However, complexes 4 and 7–8 gave lower conversions of 48–74% but with higher (up to 90%) selectivity to benzaldehyde. Results from kinetics studies determined the activation energy for the catalytic oxidation reaction as 65 ± 3 kJ/mol, first order in catalyst and fractional order in the oxidant. Results from UV-visible and CV studies of the catalytic activity of the Ni-triazolylidene complexes on styrene oxidation did not indicate any clear possibility of generation of a Ni(II) to Ni(III) catalytic cycle.
Verbascoside: An Efficient and Safe Natural Antibacterial Adjuvant for Preventing Bacterial Contamination of Fresh Meat
Authors: Shi Chunyang , Ma Yangmin , Tian Lei , Li Jingyi , Qiao Guaiping , Liu Chang , Cao Wenqiang , Liang Chengyuan
Published: August 2022

Inappropriate and disproportionate antibiotic use contributes immensely to the development of antibiotic resistance in bacterial species associated with food contamination. Therefore, alternative strategies to treat multidrug-resistant (MDR) bacterial infections are urgently needed. In this study, verbascoside was shown to exhibit excellent antibacterial activity and synergistic effects in combination with cell wall synthesis-inhibiting antibiotics, indicating that it can be used as an adjuvant to restore or increase the activity of antibiotics against resistant pathogens. In a mechanistic study, higher concentrations of verbascoside resulted in a longer lag phase and a lower specific exponential-phase growth rate of bacteria. Furthermore, verbascoside exerted its antimicrobial activity through multiple mechanisms, including cell membrane dysfunction, biofilm eradication and changes in cell morphology. The promising antibacterial activity and in vitro safety assessment results suggested that verbascoside can be used as a food additive for fresh meat preservation. Treatment with medium and high doses of verbascoside caused significant bacterial death in meat samples, slowed the spoilage rate, and extended the shelf life. Collectively, verbascoside is expected to be useful as an antibiotic adjuvant to prevent or treat resistant bacteria-related infections and an alternative novel antimicrobial additive in the food industry.
5-Demethoxy-10′-ethoxyexotimarin F, a New Coumarin with MAO-B Inhibitory Potential from Murraya exotica L.
Authors: Xia-Hou Zhen-Ru , Feng Xiao-Fei , Mei Yu-Fei , Zhang Yin-Yan , Yang Tong , Pan Jie , Yang Jing-Hua , Wang Yun-Song
Published: August 2022

Rutaceae plants are known for being a rich source of coumarins. Preliminary molecular docking showed that there was no significant difference for coumarins in Clausena and Murraya, both of which had high scoring values and showed good potential inhibitory activity to the MAO-B enzyme. Overall, 32 coumarins were isolated from Murraya exotica L., including a new coumarin 5-demethoxy-10′-ethoxyexotimarin F (1). Their structures were elucidated on the basis of a comprehensive analysis of 1D and 2D NMR and HRMS spectroscopic data, and the absolute configurations were assigned via a comparison of the specific rotations and the ECD exciton coupling method. The potential of new coumarin (1) as a selective inhibitor of MAO-B was initially evaluated through molecular docking and pharmacophore studies. Compound (1) showed selectivity for the MAO-B isoenzyme and inhibitory activity in the sub-micromolar range with an IC50 value of 153.25 ± 1.58 nM (MAO-B selectivity index > 172).
Flavonoids from Lycium barbarum Leaves Exhibit Anti-Aging Effects through the Redox-Modulation
Authors: Niu Yinhong , Liao Jiale , Zhou Haitao , Wang Chih-chen , Wang Lei , Fan Yanli
Published: August 2022

Lycium barbarum leaves are a kind of vegetable, and modern nutrition studies have found that they have an anti-aging function. Our study aims to investigate the anti-aging effects of Lycium barbarum leaf flavonoid (LBLF) extracts and its underlying molecular mechanism. LBLFs were purified using D101 and polyamide resin, characterized by ultraperformance liquid chromatography coupled with mass spectrometry, and administered to hydrogen peroxide (H2O2)-treated human umbilical vein endothelial cells (HUVECs) and Caenorhabditis elegans. Appropriate enrichment conditions were optimized through dynamic adsorption and desorption experiments, the content of flavonoids reached 909.84 mg/g, rutin and kaempferol being the main ones. LBLFs attenuated H2O2-induced HUVEC apoptosis, decreased reactive oxygen species and malondialdehyde production levels, increased superoxide dismutase, glutathione peroxidase and catalase activities. Furthermore, pre-treatment with LBLF increased mRNA expression of erythropoietin (EPO) and heme oxygenase-1 (HO-1) via the mitogen-activated protein kinase (MAPK) signaling pathway in HUVECs. Compared with 100 µM rutin monomer, LBLF prolonged the lifespan of Caenorhabditis elegans, enhanced their mobility in middle life stages and upregulated expression of sod-2, gcs-1 and skn-1 genes, which indicated that the anti-aging effects of LBLF were due to its redox-modulation.
MgO Heterostructures: From Synthesis to Applications
Authors: Huma Tabasum , Hakimi Nadimullah , Younis Muhammad , Huma Tanzeel , Ge Zhenhua , Feng Jing
Published: August 2022

The energy storage capacity of batteries and supercapacitors has seen rising demand and problems as large-scale energy storage systems and electric gadgets have become more widely adopted. With the development of nano-scale materials, the electrodes of these devices have changed dramatically. Heterostructure materials have gained increased interest as next-generation materials due to their unique interfaces, resilient structures and synergistic effects, providing the capacity to improve energy/power outputs and battery longevity. This review focuses on the role of MgO in heterostructured magnetic and energy storage devices and their applications and synthetic strategies. The role of metal oxides in manufacturing heterostructures has received much attention, especially MgO. Heterostructures have stronger interactions between tightly packed interfaces and perform better than single structures. Due to their typical physical and chemical properties, MgO heterostructures have made a breakthrough in energy storage. In perpendicularly magnetized heterostructures, the MgO’s thickness significantly affects the magnetic properties, which is good news for the next generation of high-speed magnetic storage devices.
Evaluation of the Nutritional Status of Gaucher Disease Type I Patients under Enzyme Replacement Treatment
Authors: Iaccarino Idelson Paola , Speranza Enza , Marra Maurizio , Pasanisi Fabrizio , Sammarco Rosa , Galletti Ferruccio , Strazzullo Pasquale , Barbato Antonio
Published: August 2022

(1) Background: Gaucher disease (GD) is a rare lysosomal storage disease. The few studies analyzing Resting Energy Expenditure (REE) in GD involved mainly untreated patients and supported a hypermetabolic condition possibly due to the associated inflammatory state. Definitive conclusions could not be drawn also because of the heterogeneity and the small size of the samples investigated. In order to expand current knowledge concerning, in particular the condition of patients under Enzyme Replacement Therapy (ERT), we evaluated the nutritional status of a relatively large sample of GD patients followed at Federico II University Hospital in Naples, Italy. (2) Methods: The study, having a cross-sectional design and involving 26 patients on ERT, included routine biochemical analyses, bioelectrical impedance analysis, indirect calorimetry, and administration of food frequency and physical activity questionnaires. The results in GD patients were compared with those from an appropriate control group. (3) Results: GD patients had normal biochemical parameters in 80% of cases, except for HDL-cholesterol, consumed a hyper-lipidic diet, and had a 60% prevalence of overweight/obesity. Body composition did not differ between patients and controls; however, measured REE was significantly lower than predicted and was reduced in comparison with the healthy controls. (4) Conclusions: This study provided novel elements to the present knowledge about REE and the nutritional status of GD patients under ERT. Its results warrant confirmation in even larger GD population samples and a more in-depth investigation of the long-term effects of treatment superimposed on the basic pathophysiological disease condition.
Carotenoids in Palliative Care—Is There Any Benefit from Carotenoid Supplementation in the Adjuvant Treatment of Cancer-Related Symptoms?
Authors: Zasowska-Nowak Anna , Nowak Piotr Jan , Cialkowska-Rysz Aleksandra
Published: August 2022

Carotenoids are organic, liposoluble pigments found in nature, which are responsible for the characteristic colors of ripe tomatoes, carrots, peppers, and crustaceans, among others. Palliative care provided to patients with an incurable disease is aimed at improving the patient’s quality of life through appropriate treatment of symptoms accompanying the disease. Palliative care patients with burdensome symptoms related to advanced-stage cancers are especially interested in the use of natural dietary supplements and herbal remedies to reduce symptoms’ intensity and ameliorate the quality of life. Carotenoids seem to be a group of natural compounds with particularly promising properties in relieving symptoms, mainly due to their strong antioxidant, anti-inflammatory, and neuroprotective properties. Moreover, carotenoids have been used in folk medicine to treat various diseases and alleviate the accompanying symptoms. In this narrative review, the authors decided to determine whether there is any scientific evidence supporting the rationale for carotenoid supplementation in advanced-stage cancer patients, with particular emphasis on the adjuvant treatment of cancer-related symptoms, such as neuropathic pain and cancer-related cachexia.
Prospective Longitudinal Study of Putative Agents Involved in Complex Gill Disorder in Atlantic salmon (Salmo salar)
Authors: Herrero Ana , Rodger Hamish , Hayward Adam D. , Cousens Chris , Bron James E. , Dagleish Mark P. , Thompson Kim D.
Published: August 2022

Complex gill disorder (CGD) is an important condition in Atlantic salmon aquaculture, but the roles of the putative aetiological agents in the pathogenesis are uncertain. A longitudinal study was undertaken on two salmon farms in Scotland to determine the variations in loads of CGD-associated pathogens (Desmozoon lepeophtherii, Candidatus Branchiomonas cysticola, salmon gill pox virus (SGPV) and Neoparamoeba perurans) estimated by quantitative PCR. In freshwater, Ca. B. cysticola and SGPV were detected in both populations, but all four pathogens were detected on both farms during the marine stage. Candidatus B. cysticola and D. lepeophtherii were detected frequently, with SGPV detected sporadically. In the marine phase, increased N. perurans loads associated significantly (p < 0.05) with increases in semi-quantitative histological gill-score (HGS). Increased Ca. B. cysticola load associated significantly (p < 0.05) with increased HGS when only Farm B was analysed. Higher loads of D. lepeophtherii were associated significantly (p < 0.05) with increased HGS on Farm B despite the absence of D. lepeophtherii-type microvesicles. Variations in SGPV were not associated significantly (p > 0.05) with changes in HSG. This study also showed that water temperature (season) and certain management factors were associated with higher HGS. This increase in histological gill lesions will have a deleterious impact on fish health and welfare, and production performance.
Wavelength-Dependent Nonlinear Absorption in Platinum Nanoparticles at Off-Resonant Wavelength
Authors: Chen Chunyu , Gao Yachen , Jiang Jijuan , Han Jing
Published: August 2022

In order to obtain optical nonlinear materials with high transparency and low propagation loss in the visible and infrared range, noble metal materials in the off-resonant band have become a hot spot in the optical field in recent years. Therefore, the nonlinear absorption characteristics of platinum nanoparticles (PtNPs) with the surface plasmon resonance (SPR) in the ultraviolet band were investigated with multi-wavelength (500–700 nm) nanosecond Z-scan technology. The measurement results showed that the SPR wavelength of PtNPs was far away from the excitation wavelength, but there were still the saturated absorption (SA) and the reverse saturated absorption (RSA) phenomena, and the size of nonlinear absorption was related to the excitation wavelength and the excitation energy. When the excitation wavelength was constant, with the increase in excitation energy, PtNPs converted from SA to RSA. When the excitation energy was constant, with the excitation wavelength approaching SPR, PtNPs also converted from SA to RSA. The SA and RSA phenomena in the off-resonant region were complementary to the systematic study of the nonlinearity of PtNPs.
Growth Responses of Three European Weeds on Different AMF Species during Early Development
Authors: Säle Verena , Sieverding Ewald , Oehl Fritz
Published: August 2022

Arbuscular mycorrhizal fungi (AMF) have multiple functions in agroecosystems and affect many processes below- and aboveground, including plant productivity. Mycorrhizal symbiosis is not necessarily beneficial for the host plant and the growth response can be not only positive but also neutral or negative. Among other factors, the responsiveness of plants to AMF depends on the plant-fungus combination. To find out whether the AMF species or isolate is a decisive factor for growth responses of weeds, 44 AMF isolates were tested in a pot experiment for their effects on three agricultural weeds: Echinochloa crus-galli, Solanum nigrum and Papaver rhoeas. The 44 isolates cover 18 AMF species from 13 genera and all 5 orders of the Glomeromycota. The aboveground biomass of the weeds was determined after different times of growth of each weed. In most cases, the effects of AMF isolates on weed growth were negative or neutral. We conclude that some weed species do not benefit from AMF in terms of growth. AMF species can even cause negative growth responses, an effect that may be of practical interest for organic farming where the aim is to obtain a high diversity and concentration of native AMF for the benefit of the cultivated crops without increasing the labor for mechanical weeding.
Antioxidants Application Enhances Regeneration and Conversion of Date Palm (Phoenix dactylifera L.) Somatic Embryos
Authors: Zein El Din Amal F. M. , Darwesh Rasmia S. S. , Ibrahim Mohamed F. M. , Salama Gehan M. Y. , Shams El-Din Ibrahim M. , Abdelaal Walid B. , Ali Ghada A. , Elsayed Maha S. , Ismail Ismail A. , Dessoky Eldessoky S. , Abdellatif Yasmin M. R.
Published: August 2022

Many embryogenic systems have been designed to generate somatic embryos (SEs) with the morphology, biochemistry, and vigor uniformity of zygotic embryos (ZEs). During the current investigation, several antioxidants were added to the maturation media of the developing somatic embryos of date palm. Explant material was a friable embryogenic callus that was placed in maturation media containing ABA at 0.5 mg L−1, 5 g L−1 polyethylene glycol, and 10 g L−1 phytagel. Furthermore, α-tocopherol or reduced glutathione (GSH) were used separately at (25 and 50 mg L−1). These treatments were compared to a widely used date palm combination of reduced ascorbic acid (ASC) and citric acid at 150 and 100 mg L−1, respectively, and to the medium free from any antioxidants. The relative growth percentage of embryogenic callus (EC), globularization degree, differentiation%, and SEs number were significantly increased with GSH (50 mg L−1). Additionally, the latter treatment significantly enhanced the conversion% of SEs and the number of secondary somatic embryos (SSEs). ASC and citric acid treatment increased leaf length, while α-tochopherol (50 mg L−1) elevated the number of leaves plantlet−1. GSH at 50 mg L−1 catalyzed the activities of polyphenol oxidase (PPO) and peroxidase (POD) in EC and enhanced the accumulation of proteins in SEs.
Application of Silica Nanoparticles in Combination with Two Bacterial Strains Improves the Growth, Antioxidant Capacity and Production of Barley Irrigated with Saline Water in Salt-Affected Soil
Authors: Alharbi Khadiga , Rashwan Emadeldeen , Mohamed Hossam Hussein , Awadalla Abdelmoniem , Omara Alaa El-Dein , Hafez Emad M. , Alshaal Tarek
Published: August 2022

Exploitation of low-quality water or irrigation of field crops with saline water in salt-affected soil is a critical worldwide challenge that rigorously influences agricultural productivity and sustainability, especially in arid and semiarid zones with limited freshwater resources. Therefore, we investigated a synergistic amendment strategy for salt-affected soil using a singular and combined application of plant growth-promoting rhizobacteria (PGPR at 950 g ha−1; Azotobacter chroococcum SARS 10 and Pseudomonas koreensis MG209738) and silica nanoparticles (SiNPs) at 500 mg L−1 to mitigate the detrimental impacts of irrigation with saline water on the growth, physiology, and productivity of barley (Hordum vulgare L.), along with soil attributes and nutrient uptake during 2019/2020 and 2020/2021. Our field trials showed that the combined application of PGPR and SiNPs significantly improved the soil physicochemical properties, mainly by reducing the soil exchangeable sodium percentage. Additionally, it considerably enhanced the microbiological counts (i.e., bacteria, azotobacter, and bacillus) and soil enzyme activity (i.e., urease and dehydrogenase) in both growing seasons compared with the control. The combined application of PGPR and SiNPs alleviated the detrimental impacts of saline water on barley plants grown in salt-affected soil compared to the single application of PGPR or SiNPs. The marked improvement was due to the combined application of PGPR and SiNPs, which enhanced the physiological properties (e.g., relative chlorophyll content (SPAD), relative water content (RWC), stomatal conductance, and K/Na ratio), enzyme activity (superoxide dismutase (SOD), catalase (CAT), and peroxidase (POX)), and yield and yield-related traits and nutrient uptake (N, P, and K) of barley plants. Moreover, the Na+ content, hydrogen peroxide (H2O2) content, lipid peroxidation (MDA), electrolyte leakage (EL), and proline content were reduced upon the application of PGPR + SiNPs. These results could be important information for cultivating barley and other cereal crops in salt-affected soil under irrigation with saline water.
Chemical Composition of Reichardia tingitana Methanolic Extract and Its Potential Antioxidant, Antimicrobial, Cytotoxic and Larvicidal Activity
Authors: Salama Salama A. , Al-Faifi Zarraq E. , El-Amier Yasser A.
Published: August 2022

The biggest challenges are locating effective, reasonably priced, and eco-friendly compounds to treat diseases caused by insects and microbes. The aim of this study was to employ GC-MS to assess the biological potency and chemical composition of the aerial parts of Reichardia tingitana (L.) Roth. Using this technique, 17 components were interpreted from the extracted plant, accounting for around 100% of total volatile compounds. Commonly, 6,10,14-trimethylpentadecan-2-one (21.98%) and methyl oleate (27.26%) were positioned as the major components, which were ascertained after 19.25, and 23.34 min, respectively. The major components were classified as hydrocarbons (23.82%), fatty acids, esters of fatty acids (57.46%), steroids (17.26%), and terpenes (1.48%). The DPPH antioxidant activity of the R. tingitana extracted components revealed that the shoot extract is the most powerful, with an IC50 value of 30.77 mg L−1 and a radical scavenging activity percentage of 71.91%. According to the current result, methanolic extract of R. tingitana had the maximum zone of inhibition against Salmonella typhimurium and Bacillus cereus (25.71 ± 1.63 and 24.42 ± 0.81 mm, respectively), while Clostridium tetani and Staphylococcus xylosus were the main resistant species. In addition, the 50% methanol crude shoot extract of R. tingitana showed greater potential anticancer activity with high cytotoxicity for two tumor cells HepG-2 and PC3 cells (IC50 = 29.977 and 40.479 µg mL−1, respectively) and noncytotoxic activity for WI-38 normal cells (IC50 = >100 µg mL−1). The MeOH extract of plant sample was more effective against Aedes aegypti larvae with LC50 of extract being 46.85, 35.75, and 29.38 mg L−1, whereas the LC90 is 82.66, 63.82, and 53.30 mg L−1 for the various time periods of 24, 48, and 72 h, respectively. R. tingitana is a possible biologically active plant. Future study will include pure chemical isolation and individual component bioactivity evaluation.
Effects of the Combined Application of Trimethylated Chitosan and Carbodiimide on the Biostability and Antibacterial Activity of Dentin Collagen Matrix
Authors: Wang Xiangyao , Li Qilin , Lu Haibo , Liu Zhuo , Wu Yaxin , Mao Jing , Gong Shiqiang
Published: August 2022

The structural integrity of a dentin matrix that has been demineralized by the clinical use of etchants or calcium-depleting endodontic irrigants, such as endodontic ethylenediaminetetraacetic acid (EDTA), is often deteriorated due to the collagenolytic activities of reactivated endogenous enzymes as well as the infiltration of extrinsic bacteria. Therefore, the biomodification of dentin collagen with improved stability and antibacterial activity holds great promise in conservative dentistry. The purpose of this study was to evaluate the effects of the combined application of trimethylated chitosan (TMC) and 1-ethyl-3-[3-dimethylaminopropyl]carbodiimide hydrochloride (EDC) on the biostability and antibacterial activity of the demineralized dentin collagen matrix. The morphological changes in the collagen matrix were observed by scanning electron microscopy (SEM), the amount of TMC adsorbed on the collagen surface was detected by X-ray photoelectron spectroscopy, and the elastic modulus was measured by a three-point bending device. Dry weight loss and amino acid release were detected to evaluate its anti-collagenase degradation performance. The antibacterial performance was detected by confocal microscopy. The TMC-treated group had less collagen space and a more compact collagen arrangement, while the untreated group had a looser collagen arrangement. The combined application of TMC and EDC can increase the elastic modulus, reduce the loss of elastic modulus, and result in good antibacterial performance. The current study proved that a dentin collagen matrix biomodified by TMC and EDC showed improved biodegradation resistance and antibacterial activities.
Chitin Nanocomposite Based on Plasticized Poly(lactic acid)/Poly(3-hydroxybutyrate) (PLA/PHB) Blends as Fully Biodegradable Packaging Materials
Authors: Iglesias-Montes Magdalena L. , Soccio Michelina , Siracusa Valentina , Gazzano Massimo , Lotti Nadia , Cyras Viviana P. , Manfredi Liliana B.
Published: August 2022

Fully bio-based poly(lactic acid) (PLA) and poly(3-hydroxybutyrate) (PHB) blends plasticized with tributyrin (TB), and their nanocomposite based on chitin nanoparticles (ChNPs) was developed using melt mixing followed by a compression molding process. The combination of PHB and ChNPs had an impact on the crystallinity of the plasticized PLA matrix, thus improving its oxygen and carbon dioxide barrier properties as well as displaying a UV light-blocking effect. The addition of 2 wt% of ChNP induced an improvement on the initial thermal degradation temperature and the overall migration behavior of blends, which had been compromised by the presence of TB. All processed materials were fully disintegrated under composting conditions, suggesting their potential application as fully biodegradable packaging materials.
Gasification Characteristics and Kinetics of Lipid-Extracted Nannochloropsis gaditana
Authors: Atikah M. S. N. , Azlina W. A. K. G. Wan , Taufiq-Yap Y. H. , Mahmoud Omar , El-Shafay A. S. , Ilyas R. A. , Harun Razif
Published: August 2022

A thermal behavior study of lipid-extracted Nannochloropsis gaditana (LEA) was performed in a thermogravimetric analyzer. The study was performed by heating the sample under different heating rates (5, 10, and 15 °C/min) from room temperature to 1000 °C using N2 gas as the medium. This is crucial for thermal stability studies in a kinetic control regime. The following three stages of chemical decompositions were found: (1) moisture removal (2) devolatilization (3) fixed carbon decomposition; maximum decomposition was observed at the second stage. Activation energies of the LEA were studied using the Flynn–Wall–Ozawa model and Kissinger–Akahira–Sunose model. Main sample decomposition was observed from 100–700 °C during volatile matter evaporation. The thermal behavior study findings were used for the gasification of the sample with air to study the effect of varying reaction parameters on the compositions of the synthesis gas yield. Maximum H2 yield was found at 700 °C and 0.7 g, which were 51.2 mol% and 50.6 mol%, respectively. From the study, it was found that LEA is suitable to be used as feedstock in gasification for synthesis gas production.
FTIR as a Powerful Tool for Measurements of Diffusion in Supercritical Carbon Dioxide Using Taylor Dispersion Method
Authors: Santos Cecilia I. A. V. , Barros Marisa C. F. , Faro Maria P. R. T. , Shevtsova Valentina , Ribeiro Ana C. F.
Published: August 2022

A new experimental high-pressure setup for measuring diffusion coefficients in supercritical fluids, based on Taylor dispersion method, and using an FTIR detector to operate up to 25.0 MPa was designed and optimized. Tracer diffusivities, D12, of toluene and benzene in supercritical carbon dioxide were measured in the temperature range of 306.15–320.15 K, and pressure range of 7.5–17 MPa to evaluate the setup and experimental protocol. The effects of flow velocity, volume of the cell, absorbance at different wavenumbers on the diffusion coefficient as well as all parameters respecting the Taylor dispersion method have been analyzed. The obtained diffusion coefficients are in excellent agreement with the available literature data. The dependence of D12 on temperature, pressure, and solvent density were examined. Some correlation models based on the hydrodynamic theory were used to estimate the diffusion coefficients in supercritical carbon dioxide, which is the best agreement obtained for an improved version of the Wilke–Chang model.
A Case of Rheumatoid Meningitis
Authors: Tomizuka Takafumi , Kikuchi Hirotoshi , Asako Kurumi , Kono Hajime
Published: August 2022

Rheumatoid meningitis, a very rare complication, is not well-recognised, and there are few reports describing its treatment. We report the case of a 74-year-old Japanese woman who was diagnosed with rheumatoid meningitis by characteristic brain magnetic resonance imaging (MRI) and was successfully treated with glucocorticoids. We observed fluid-attenuated inversion recovery and diffusion-weighted imaging hyperintensity, which had a meningeal gadolinium-enhancing characteristic of rheumatoid meningitis. We suggest that it is possible to diagnose this disease based on characteristic MRI findings and treat patients early using glucocorticoids.
Classification of Alpine Grasslands in Cold and High Altitudes Based on Multispectral Landsat-8 Images: A Case Study in Sanjiangyuan National Park, China
Authors: Wei Yanqiang , Wang Wenwen , Tang Xuejie , Li Hui , Hu Huawei , Wang Xufeng
Published: August 2022

Land-use–cover change (LUCC)/vegetation cover plays a critical role in Earth system science and is a reflection of human activities and environmental changes. LUCC will affect the structure and function of ecosystems and a series of other terrestrial surface processes, such as energy exchange, water circulation, biogeochemical circulation, and vegetation productivity. Therefore, accurate LUCC mapping and vegetation cover monitoring are the bases for simulating the global carbon and hydrological cycles, studying the interactions of the land surface and climate, and assessing land degradation. Based on field GPS surveys and UAV data, with cloud-free and snow/glacier algorithms and the SVM classifier to train and model alpine grassland, the alpine grassland and LUCC were extracted by using Landsat-8 OLI satellite images in Sanjiangyuan National Park in this paper. The latest datasets of vegetation types with 30 m × 30 m spatial resolution in the three parks were prepared and formed. The classification results show that the SVM classifier could better distinguish the major land-use types, and the overall classification accuracy was very high. However, in the alpine grassland subcategories, the classification accuracies of the four typical grasslands were relatively low, especially between desert steppes and alpine meadows, and desert steppes and alpine steppes. It manifests the limitations of Landsat-8 multispectral remote sensing imageries in finer-resolution grassland classifications of high-altitude alpine mountains. The method can be utilized for other multispectral satellite imageries with the same band matching, such as Landsat 7, Landsat 9, Sentinel-2, etc. The method described in this paper can rapidly and efficiently process annual alpine grassland maps of the source areas of the Yellow River, the Yangtze River, and the Lancang River. It can provide timely and high-spatial-resolution datasets for supporting scientific decisions for the sustainable management of Sanjiangyuan National Park.
Evaluating Different TiO2 Nanoflower-Based Composites for Humidity Detection
Authors: Mohamed Zahidi Musa , Mamat Mohamad Hafiz , Malek Mohd Firdaus , Yaakob Muhamad Kamil , Ahmad Mohd Khairul , Abu Bakar Suriani , Mohamed Azmi , A Subki A Shamsul Rahimi , Mahmood Mohamad Rusop
Published: August 2022

Unique three-dimensional (3D) titanium dioxide (TiO2) nanoflowers (TFNA) have shown great potential for humidity sensing applications, due to their large surface area-to-volume ratio and high hydrophilicity. The formation of a composite with other materials could further enhance the performance of this material. In this work, the effect of different types of composites on the performance of a TNFA-based humidity sensor was examined. NiO, ZnO, rGO, and PVDF have been explored as possible composite pairing candidates with TiO2 nanoflowers, which were prepared via a modified solution immersion method. The properties of the composites were examined using field emission electron spectroscopy (FESEM), X-ray diffractometry (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), current-voltage (I-V) analysis, Hall effect measurement, and contact angle measurement. The performance of the humidity sensor was assessed using a humidity sensor measurement system inside a humidity-controlled chamber. Based on the result, the combination of TiO2 with rGO produced the highest sensor response at 39,590%. The achievement is attributed to the increase in the electrical conductivity, hydrophilicity, and specific surface area of the composite.
Unmanned Surface Vehicle Collision Avoidance Path Planning in Restricted Waters Using Multi-Objective Optimisation Complying with COLREGs
Authors: Gu Yang , Rong Zhenwei , Tong Huzhou , Wang Jia , Si Yulin , Yang Shujie
Published: August 2022

Navigation safety is one of the primary operational requirements for unmanned surface vehicles (USVs) in a complex marine environment, mainly guaranteed by a reliable path planning system for collision avoidance. This work proposes a novel weighted sum multi-objective optimisation strategy for USV collision avoidance path planning in restricted waters. In particular, the coefficients of different objectives could be tuned to emphasise the most critical design consideration under varying navigation scenarios. Moreover, in addition to the Convention on the International Regulations for Preventing Collisions at Sea (COLREGs), the terrain and weather constraints were also considered in the path planning system. The proposed USV collision avoidance path planning framework’s effectiveness was demonstrated through numerical simulations and hardware-in-the-loop (HIL) tests. The numerical simulation results indicate that the proposed method could avoid collision with dynamic and static obstacles, and it is also adaptive to different navigation restrictions and preferences. Moreover, a USV navigation platform was established by incorporating true Automatic Identification System (AIS) signals, and HIL tests were performed with real-time AIS data in a water channel in the Zhoushan archipelago. The results demonstrate that the proposed USV path planning strategy is applicable in restricted waters with complex terrains and weather constraints.
A Comprehensive Review of Endogenous EEG-Based BCIs for Dynamic Device Control
Authors: Padfield Natasha , Camilleri Kenneth , Camilleri Tracey , Fabri Simon , Bugeja Marvin
Published: August 2022

Electroencephalogram (EEG)-based brain–computer interfaces (BCIs) provide a novel approach for controlling external devices. BCI technologies can be important enabling technologies for people with severe mobility impairment. Endogenous paradigms, which depend on user-generated commands and do not need external stimuli, can provide intuitive control of external devices. This paper discusses BCIs to control various physical devices such as exoskeletons, wheelchairs, mobile robots, and robotic arms. These technologies must be able to navigate complex environments or execute fine motor movements. Brain control of these devices presents an intricate research problem that merges signal processing and classification techniques with control theory. In particular, obtaining strong classification performance for endogenous BCIs is challenging, and EEG decoder output signals can be unstable. These issues present myriad research questions that are discussed in this review paper. This review covers papers published until the end of 2021 that presented BCI-controlled dynamic devices. It discusses the devices controlled, EEG paradigms, shared control, stabilization of the EEG signal, traditional machine learning and deep learning techniques, and user experience. The paper concludes with a discussion of open questions and avenues for future work.
How Does Celebrity-Based Brand Endorsement Work in Social Media?—The Instagram Context
Authors: Um Namhyun
Published: August 2022

In social media, there is a prevalence of celebrity-based brand endorsement. How such endorsement works precisely, though, has received scant research. This study is thus designed to examine how consumers’ social media interaction affects parasocial relationships and self-disclosure. In addition, the current study delves into the impacts parasocial relationships and self-disclosure have on consumers’ attitude toward social media (i.e., Instagram). Lastly, this study also investigates the effects of consumers’ attitude toward social media on consumers’ purchase intention. Study results suggest that social media interaction has positive impacts on parasocial relationships and self-disclosure. Parasocial relationships and self-disclosure have a positive impact on consumers’ attitudes toward Instagram. Finally, this study finds that attitude toward Instagram has a positive impact on consumers’ purchase intention. Practical and theoretical implications are discussed.
Evaluation and Spatial Variability of Cryogenic Soil Properties (Yamal-Nenets Autonomous District, Russia)
Authors: Suleymanov Azamat , Nizamutdinov Timur , Morgun Evgeniya , Abakumov Evgeny
Published: August 2022

Agricultural development in northern polar areas has potential as a result of global warming. Such expansion requires modern soil surveys and large-scale maps. In this study, the abandoned arable experimental field founded by I.G. Eichfeld one century ago in Salekhard city (Russian Arctic), located in the polar circle, was investigated. Our aims were to assess the nutritional soil properties and their spatial variability. For spatial assessment and mapping, ordinary kriging (OK) and inverse distance-weighted (IDW) methods were employed. We found that due to long-term agriculture use, the soil cover was represented by a unique Plaggic Podzol (Turbic) that is not typical of the region. The soil was characterized by relatively low soil organic carbon (SOC) content, high acidity and a high content of plant-available forms of phosphorus in the humus-accumulative horizon. The results showed that some properties (pH H2O, pH CaCl2) were characterized by large-scale heterogeneity and showed clear spatial dependence. However, some properties (ammonium and nitrate nitrogen, basal respiration) showed a pure-nugget effect, presumably due to experimentation with fertilizer over a long period of time.
Optimization of Ground Control Point Distribution for Unmanned Aerial Vehicle Photogrammetry for Inaccessible Fields
Authors: Zhang Ke , Okazawa Hiromu , Hayashi Kiichiro , Hayashi Tamano , Fiwa Lameck , Maskey Sarvesh
Published: August 2022

Ground control point (GCP) is an important calibration factor when correcting position information during unmanned aerial vehicle (UAV) remote sensing. Studies of the optimal number and distribution shape of GCPs have been conducted worldwide in recent years. However, when conducting surveys at houses, construction sites, farming lands, forests, and some other locations, it is both difficult and destructive to install GCP inside the subject area. In many cases, it is only possible to install GCP at the outer edge around the area. Therefore, this study aims to suggest the optimal GCP distribution pattern, which can provide the highest accuracy, when only the outer edge of a particular area is available. In this research, 88 GCP patterns have been validated and compared at an 18 ha farm. Results show that the patterns with GCPs distributed evenly around the field provided the best calibration (RMSE = 0.15 m). If this kind of pattern is not achievable because of obstructions, patterns with GCPs distributed evenly around half of the field or forming an evenly distributed triangle can provide moderate accuracy (RMSE = 0.18 m and 0.43 m, respectively). Patterns with GCPs forming a straight line yielded the worst accuracy (RMSE = 2.10 m). This shows that GCP distributions of a two-dimensional shape, even if the surrounding area is small, are better calibrated than a long, straight line. These results strongly suggest that appropriate GCP distribution patterns in the study areas will provide satisfactory accuracy for constructing integrated monitoring systems of diverse resources.
Building Long-Term Business Sustainability: The Influence of Experiential Marketing on Sales Representatives’ Loyalty to Multi-Level Marketing Systems
Authors: Purcaru Ioana-Mădălina , Urdea Ana-Maria , Constantin Cristinel Petrişor , Brătucu Gabriel
Published: August 2022

Monitoring the satisfaction of sales representatives is a major challenge in business based on multi-level marketing systems (MLM), as a high level of satisfaction could determine the sales representatives’ loyalty and subsequent business growth. The purposes of this study are (i) to measure the sales representatives’ satisfaction with various experiences they face within the MLM system, (ii) to identify the main satisfaction factors that synthetically illustrate the sales representatives’ experiences with the MLM system, and (iii) to determine the influence of satisfaction factors with MLM experiences on the intention to recommend the system to other people interested in joining the business. The research was based on a survey among 412 sales representatives of companies that use an MLM system in various fields of activity. The main factors that summarize the experiences that sales representatives have within the MLM systems have been identified by using an exploratory factor analysis (EFA). Further, the satisfaction with these factors was analyzed in relationship with the intention to recommend the system for the development of their individual business. The research results indicate three major experiences of the sales representatives: (i) experiences within the MLM system, (ii) experiences with customer relationships, and (iii) experiences with the product. The results also show that the higher satisfaction with these factors is, the higher the likelihood to recommend the MLM system. This study provides a contribution to the body of knowledge in using experiential marketing for sustainable business development and provides management insights for companies that use MLM systems.
Involvement, Social Impact Experiences, and Event Support of Host Residents Before, during, and after the 2021 UCI Road World Championships
Authors: Helsen Kobe , Taks Marijke , Scheerder Jeroen
Published: August 2022

Host residents’ support is of paramount importance for the success of spectator sports events. Factors influencing event support have been investigated in past research, but usually in isolation. The current study includes multiple factors by analysing the relationship among involvement, social impact experiences, and event support. Data were collected online four and six months before, during, and two months after the 2021 UCI Road World Championships from 3219 from residents, representative for the city of Leuven (Belgium). The 2021 UCI Road World Championships offered a unique context, as it was the first large spectator sports event organised in Flanders since COVID-19. The event had a limited social impact, but this increased over time (e.g., community spirit and event support). Social impact experiences mainly exerted a significant influence on event support rather than attitudinal and behavioural involvement factors. The results of this study inform national and local policymakers to attract events, event organisers to achieve impact and legacy, and other scholars to improve the understanding of spectator sports event research.
Automated Storage and Retrieval Systems: An Attractive Solution for an Urban Warehouse’s Sustainable Development
Authors: Edouard Aurélie , Sallez Yves , Fortineau Virginie , Lamouri Samir , Berger Alexandre
Published: August 2022

In recent years, there has been an increasing awareness of sustainable development issues. Supply chain actors have become more and more aware of this situation, especially since the regulatory, social and societal pressures in this area are becoming more and more numerous. This state of affairs is not without consequences on company practices and economic. As a result, the urban warehouse model is emerging as one of the solutions studied in the urban logistics context. The characteristics, constraints and challenges of this model are presented in this article in order to define this new logistics facility. Secondly, automated storage and retrieval systems (AS/RS), today considered as a solution from Industry 4.0, are studied through a case study in order to determine their potential to meet the challenges of urban warehouses. Their ability to optimize available surfaces by densifying stocks in limited spaces is particularly demonstrated.
Residents’ Motivation and Place Meanings in a Hallmark Event: How to Develop a Sustainable Event in the Hosting Destination
Authors: Zhang Jie , Wu Shaofeng , Sun Huan
Published: August 2022

The main challenge for sustainable events is to attract residents to participate and to continue participating. Motivation can be used to explain a place and the intention to revisit a place. The main purpose of this study was to explore residents’ place meanings at Peony Culture Festival Luoyang China (PCFLC) and the impact of residents’ motivation on place meaning and place satisfaction with respect to PCFLC. A sequential mixed-methods approach was adopted. In-depth interviews and questionnaires were used to collect data. The thematic analysis yielded four themes of residents’ place meanings in PCFLC. Structural equation modeling via the bootstrap approach was used to examine the role of residents’ motivation in place making in PCLFC. The results indicated that residents’ place meanings in PCFLC consisted of self-identification, self-development, economic dependence, and leisure, which enriched the types of place meanings. In addition, place meaning had a mediating role in the relationship between autonomous motivation and place satisfaction and a masking role in the relationship between controlled motivation and place satisfaction from the perspective of the self-determination theory. The paper provides a theoretical perspective to explain the effects of motivation on place making and puts forward a practical proposal for the products and marketing of events.
Dominance Tracking Index for Measuring Pension Fund Performance with Respect to the Benchmark
Authors: Kopa Milos , Sutiene Kristina , Kabasinskas Audrius , Lakstutiene Ausrine , Malakauskas Aidas
Published: August 2022

This paper focuses on the performance of Lithuanian life-cycle second-pillar pension funds. Every such fund first specifies its benchmark and then attempts to follow the benchmark in some way. This is a form of regulation, meaning that every such fund is somehow regulated and controlled by the central bank authorities. The goal of this paper is twofold: (i) to analyse the returns of the pension funds with respect to their benchmarks and (ii) to determine whether less strict regulation leads to a better outperformance of the fund with respect to the benchmark. In order to achieve this, we introduced a new performance measure called the dominance-tracking index, which combines the ideas of almost stochastic dominance relations and tracking errors. While the tracking error and its modifications measure the strength of the regulation, almost stochastic dominance provides information about preferences between the funds and their benchmarks. Therefore, the new index was constructed in such a way as to take into account both approaches. The empirical section of the study then presents the results separately for the considered pension managers and participants’ age groups as usual in the life-cycle pension funds analysis. Finally, by taking into account various periods, we studied the effects of the COVID-19 crisis.