bluuebunny/crossref_metadata_2025 huggingface dataset:
Equilibrium and Kinetic Modeling of Crystal Violet Dye Adsorption by a Marine Diatom, Skeletonema costatum
Authors: Ashour Mohamed , Alprol Ahmed E. , Khedawy Mohamed , Abualnaja Khamael M. , Mansour Abdallah Tageldein
Published: September 2022

Significant efforts have been made to improve adsorbents capable of eliminating pollutants from aqueous solutions, making it simple and quick to separate from the treated solution. In the current study, the removal of Crystal Violet Dye (CVD) from an aqueous synthetic solution onto a marine diatom alga, Skeletonema costatum, was investigated. Different experiments were conducted as a function of different pH, contact time, adsorbent dosage, temperature, and initial CVD concentration. The highest adsorption efficiency (98%) was obtained at 0.4 g of S. costatum, pH 3, and a contact time of 120 min, at 25 °C. Furthermore, Fourier-transform infrared spectroscopy (FTIR) results display that binding of CVD on S. costatum may occur by electrostatic and complexation reactions. Moreover, the Brunauer–Emmett–Teller surface area analysis (BET) obtained was 87.17 m2 g−1, which, in addition to a scanning electron microscope (SEM), reveals large pores that could enhance the uptake of large molecules. However, the equilibrium adsorption models were conducted by Halsey, Langmuir, Freundlich, Henderson, and Tempkin isotherm. In addition, multilayer adsorption isotherm best described the uptake of CVD onto S. costatum. The maximum monolayer adsorption capacity (qmax) was 6.410 mg g−1. Moreover, thermodynamic parameters of the adsorption studies suggested that the uptake of CVD onto S. costatum was endothermic and spontaneous. The pseudo-first-order, pseudo-second-order, and intra-particle diffusion kinetic equations were applied to model the adsorption kinetic data. It was seen that the kinetics of the adsorption may be described using pseudo-second-order kinetic equations. Finally, the present work concluded that the marine diatom alga S. costatum is suitable as a natural material for the adsorption of CVD.
Animal-Protein-Based and Synthetic-Based Foamed Mixture Lightweight Soil Doped with Bauxite Tailings: Macro and Microscopic Properties
Authors: Ou Xiaoduo , Mo Peng , Lyu Zhengfan , Luo Junhui , Jiang Jie , Bai Lu , Huang Zhongzheng
Published: September 2022

In order to explore the effect of the foaming agent type on the properties of foamed mixture lightweight soil mixed with bauxite tailings (FMLSB), low-density (437.5 kg/m3 and 670 kg/m3) and high-density (902.5 kg/m3 and 1170 kg/m3) FMLSB were prepared using protein-based and synthetic-based foaming agents (AF and SF, respectively). The foam stability, micro characteristics, compressive strength, fluidity, and volume of water absorption of the FMLSB were investigated. The results showed that the foam made from AF had better strength and stability compared to SF. The internal pore sizes of both AF- and SF-FMLSB at low density were large, but at high density the internal pore sizes and area porosity of AF-FMLSB were smaller than those of SF-FMLSB. In terms of compressive strength, the compressive strength of AF-FMLSB was improved by 17.5% to 43.2% compared to SF-FMLSB. At low density, the fluidity of AF- and SF-FMLSB is similar, while at high density the fluidity of AF-FMLSB is much higher than that of SF-FMLSB. In addition, the stable volume of water absorption of SF-FMLSB is smaller than that of AF-FMLSB at low density, and the corresponding water resistance is better, but the situation is reversed at high density.
Piezoelectric Properties of 0-3 Composite Films Based on Novel Molecular Piezoelectric Material (ATHP)2PbBr4
Authors: Guo Xin , Zhu Jialin , Zou Xiaoping , Li Junming , Cheng Jin , Zhang Chunqian , Wang Yifei , Wang Xiaolan , Wang Hao , Chen Xinyao , Wang Weimin , Gu Mingkai , Huang Shixian , Gui Ruoxia
Published: September 2022

Since their discovery, ferroelectric materials have shown excellent dielectric responses, pyroelectricity, piezoelectricity, electro-optical effects, nonlinear optical effects, etc. They are a class of functional materials with broad application prospects. Traditional pure inorganic piezoelectric materials have better piezoelectricity but higher rigidity; pure organic piezoelectric materials have better flexibility but havetoo small a piezoelectric coefficient. The material composite, on the other hand, can combine the advantages of both, so that it has both flexibility and a high piezoelectric coefficient. In this paper, a new molecular piezoelectric material (C5H11NO)2PbBr4 with a high Curie temperature Tc and a large piezoelectric voltage constant g33, referred to as (ATHP)2PbBr4, was used to prepare a 0-3 type piezoelectric composite film by compounding with an organic polymer material polyvinylidene fluoride (PVDF), and its ferroelectricity was investigated. The results show that the 0-3 type (ATHP)2PbBr4 piezoelectric composite film has good ferroelectricity and piezoelectricity, and the calculated piezoelectric voltage constant g33 after polarization is about 358.6 × 10−3 Vm/N, which is higher than that of PVDF material, and is important for the fabrication of high-performance piezoelectric sensors.
Enzyme-Triggered Crosslinked Hybrid Hydrogels for Bone Tissue Engineering
Authors: Sood Ankur , Ji Seong Min , Kumar Anuj , Han Sung Soo
Published: September 2022

The quest to develop state-of-the-art hydrogels for bone tissue engineering has accompanied substantial innovation and significant progression in the field of bioactive hydrogels. Still, there is scope for advancement in this cell-friendly and biocompatible scaffold system. The crosslinking approaches used for hydrogel synthesis plays a decisive role in guiding and regulating the mechanical stability, network framework, macroscopic architect, immunological behaviors, and cellular responses. Until recently, enzyme-based crosslinking strategies were considered as the pinnacle in designing efficient hybrid hydrogel systems. A variety of enzymes have been explored for manufacturing hydrogels while taking the advantage of the biocompatible nature, specificity, ability to produce nontoxic by products and high efficiency of enzymes. The current review focuses on the utility of different enzymes as crosslinking agents for hydrogel formation with their application in bone tissue engineering. The field of enzyme crosslinked hydrogel synthesis is rapidly maturing with a lot of opportunities to be explored in bone tissue engineering. Enzyme-based in situ and externally crosslinked hydrogels for bone regeneration is an attractive field, and with innovation in using engineered enzymes this field will continue to flourish with clinical orientation.
Prediction of Undrained Shear Strength by the GMDH-Type Neural Network Using SPT-Value and Soil Physical Properties
Authors: Kim Mintae , Okuyucu Osman , Ordu Ertuğrul , Ordu Seyma , Arslan Özkan , Ko Junyoung
Published: September 2022

This study presents a novel method for predicting the undrained shear strength (cu) using artificial intelligence technology. The cu value is critical in geotechnical applications and difficult to directly determine without laboratory tests. The group method of data handling (GMDH)-type neural network (NN) was utilized for the prediction of cu. The GMDH-type NN models were designed with various combinations of input parameters. In the prediction, the effective stress (σv’), standard penetration test result (NSPT), liquid limit (LL), plastic limit (PL), and plasticity index (PI) were used as input parameters in the design of the prediction models. In addition, the GMDH-type NN models were compared with the most commonly used method (i.e., linear regression) and other regression models such as random forest (RF) and support vector regression (SVR) models as comparative methods. In order to evaluate each model, the correlation coefficient (R2), mean absolute error (MAE), and root mean square error (RMSE) were calculated for different input parameter combinations. The most effective model, the GMDH-type NN with input parameters (e.g., σv’, NSPT, LL, PL, PI), had a higher correlation coefficient (R2 = 0.83) and lower error rates (MAE = 14.64 and RMSE = 22.74) than other methods used in the prediction of cu value. Furthermore, the impact of input variables on the model output was investigated using the SHAP (SHApley Additive ExPlanations) technique based on the extreme gradient boosting (XGBoost) ensemble learning algorithm. The results demonstrated that using the GMDH-type NN is an efficient method in obtaining a new empirical mathematical model to provide a reliable prediction of the undrained shear strength of soils.
The Regenerative Potential of Decellularized Dental Pulp Extracellular Matrix: A Systematic Review
Authors: Adanir Necdet , Khurshid Zohaib , Ratnayake Jithendra
Published: September 2022

Introduction: The regeneration of dental pulp remains a challenge. Although several treatment modalities have been proposed to promote pulpal regeneration, these treatments have several drawbacks. More recently, decellularized dental pulp extracellular matrix (DP-ECM) has been proposed to regenerate dental pulp. However, to date, no systematic review has summarized the overall outcome and assessed the available literature focusing on the endodontic use of DP-ECM. The aim of this systematic review is to critically appraise the literature, summarize the overall outcomes, and provide clinical recommendations about DP-ECM. Methodology: Following the Participants Intervention Control and Outcomes (PICO) principle, a focused question was constructed before conducting a search of the literature and of electronic research databases and registers. The focused question was: ‘Compared to controls, does decellularized dental pulp extracellular matrix (DP-ECM) stimulate the regeneration of dental pulp cells and tissue?’ Quality assessment of the studies was carried out using Guidelines for Reporting Pre-Clinical in Vitro Studies on Dental Materials and ARRIVE guidelines. Results: 12 studies were included in this review. Data from five in vitro experiments and eight in vivo experiments were extracted and the quality of the experiments was assessed. In majority of the studies, DP-ECM appeared to have stimulated pulpal regeneration. However, several sources of bias and methodological deficiencies were found during the quality assessment. Conclusion: Within the limitations of this review and the included studies, it may be concluded that there is insufficient evidence to deduce the overall efficacy of DP-ECM for pulpal regeneration. More research, clinical and pre-clinical, is required for more conclusive evidence.
A Dynamic Constitutive Model and Simulation of Braided CFRP under High-Speed Tensile Loading
Authors: Jin Wei , Zhang Yingchuan , Jiang Lanxin , Yang Guangwu , Chen Jingsong , Li Penghang
Published: September 2022

In this study, a dynamic constitutive model for woven-carbon-fiber-reinforced plastics (CFRP) is formulated by combining dynamic tensile test data and fitting curves and incorporating variation rules established for the modulus of elasticity, strength, and fracture strain with respect to the strain rate. The dynamic constitutive model is then implemented with finite element software. The accuracy and applicability of the dynamic constitutive model are evaluated by comparing the numerically predicted load–displacement curves and strain distributions with the test data. The stress distribution, failure factor, modulus, and strength of the material under dynamic tension are also explored. The results show that the response simulated with the dynamic constitutive model is in good agreement with the experimental results. The strain is uniformly distributed during the elastic phase compared with the DIC strain field. Subsequently, it becomes nonuniform when stress exceeds 600 MPa. Then, the brittle fracture occurs. With the increase in the strain rate, the input modulus decreased, and the tensile strength increased. When the displacement was 0.13 mm, the simulation model was damaged at a low strain rate, and the stress value was 837.8 MPa. When it reached the high strain rate of 800 s−1, no failure occurred, and the maximum stress value was 432.5 MPa. For the same specimen, the strain rate was the smallest on both clamped ends, and the modulus and strength were large at the ends and small in the middle. The fitting curve derived from the test data was completely input into the dynamic constitutive model to better capture the dynamic change in the material properties.
Special Issue: Innovations in Semiconducting Block Copolymers
Authors: Villafiorita-Monteleone Francesca , Zappia Stefania
Published: September 2022

The current Special Issue entitled “Innovations in Semiconducting Block Copolymers” aims to discuss cutting-edge research regarding the synthesis, characterization and application of semiconducting block copolymers, with a special focus on the realization of novel and innovative nanostructured materials for the production of advanced devices suitable in different fields, ranging from sensors applications to optic photovoltaics [...]
Amino-Functionalized Titanate Nanotubes: pH and Kinetic Study of a Promising Adsorbent for Acid Dye in Aqueous Solution
Authors: Sales Débora A. , Lima Paloma N. S. , Silva Lucinaldo S. , Marques Thalles M. F. , Gusmão Suziete B. S. , Ferreira Odair P. , Ghosh Anupama , Guerra Yuset , Morais Alan Í. S. , Bezerra Roosevelt D. S. , Silva-Filho Edson C. , Viana Bartolomeu C.
Published: September 2022

This work reports the functionalization of sodium titanate nanotubes with amine groups obtained from the reaction of titanate nanotubes with [3-(2-Aminoethylamino)propyl]trimethoxysilane, NaTiNT−2NH, and 3-[2-(2-Aminoethylamino)ethylamino]propyltrimethoxysilane, NaTiNT−3NH. It was verified that the crystalline and morphological structures of NaTiNT were preserved after the functionalization, spectroscopies showed that aminosilane interacted covalently with the surface of NaTiNT, and the incorporation of the aminosilane groups on the surface of NaTiNT can be confirmed. The adsorbent matrices NaTiNT−2NH and NaTiNT−3NH were used to remove the anionic dye from remazol blue R (RB) in aqueous medium, and the highest adsorption capacity was around 365.84 mg g−1 (NaTiNT−2NH) and 440.70 mg g−1 (NaTiNT−3NH) in the range of pH 5.0 to 10.0 and the equilibrium time was reached in 210 min (NaTiNT−2NH) and 270 min (NaTiNT−3NH). Furthermore, the Elovich model, which reports the adsorption in heterogeneous sites and with different activation energies in the chemisorption process, was the most appropriate to describe the adsorption kinetics. Thus, these adsorbent matrices can be used as an alternative potential for dye removal RB in aqueous solution.
Elliptic and Parabolic Equations with Involution and Degeneration at Higher Derivatives
Authors: Kozhanov Aleksandr I. , Bzheumikhova Oksana I.
Published: September 2022

We study the solvability in Sobolev spaces of boundary value problems for elliptic and parabolic equations with variable coefficients in the presence of an involution (involutive deviation) at higher derivatives, both in the nondegenerate and degenerate cases. For the problems under study, we prove the existence theorems as well as the uniqueness of regular solutions, i.e., those that have all weak derivatives in the equation.
Optimal Selection of Conductor Sizes in Three-Phase Asymmetric Distribution Networks Considering Optimal Phase-Balancing: An Application of the Salp Swarm Algorithm
Authors: Cortés-Caicedo Brandon , Grisales-Noreña Luis Fernando , Montoya Oscar Danilo
Published: September 2022

This paper presents a new methodology to simultaneously solve the optimal conductor selection and optimal phase-balancing problems in unbalanced three-phase distribution systems. Both problems were represented by means of a mathematical model known as the Mixed-Integer Nonlinear Programming (MINLP) model, and the objective function was the minimization of the total annual operating costs. The latter included the costs associated with energy losses, investment in conductors per network segment, and phase reconfiguration at each node in the system. To solve the problem addressed in this study, a master–slave methodology was implemented. The master stage employs a discrete version of the Salp Swarm Algorithm (SSA) to determine the set of conductors to be installed in each line, as well as the set of connections per phase at each of the nodes that compose the system. Afterward, the slave stage uses the three-phase version of the backward/forward sweep power flow method to determine the value of the fitness function of each individual provided by the master stage. Compared to those of the Hurricane-based Optimization Algorithm (HOA) and the Sine Cosine Algorithm (SCA), the numerical results obtained by the proposed solution methodology in the IEEE 8- and 25-node test systems demonstrate its applicability and effectiveness. All the numerical validations were performed in MATLAB.
A Vehicular Edge Computing-Based Architecture and Task Scheduling Scheme for Cooperative Perception in Autonomous Driving
Authors: Wei Yuankui , Zhang Jixian
Published: September 2022

Cooperative perception is an important domain of autonomous driving that helps to improve road safety and traffic efficiency. Nevertheless, the large amount of sensed data and complicated algorithms make storage and computation for autonomous vehicles (AVs) challenging. Furthermore, not every AV needs to individually process all sensed data from other AVs because the environmental information is the same in a small region. Inspired by vehicular edge computing (VEC), where AVs are interconnected with the help of roadside units (RSUs) for better storage and computation capabilities, we propose a VEC-based architecture for cooperative perception and design a key task scheduling algorithm for the above challenges. Specifically, a time slot-based VEC architecture with the help of an RSU is designed, and the task scheduling problem in the proposed architecture is formulated as a multitask multitarget scheduling problem with assignment restrictions. A two-stage heuristic scheme (TSHS) is designed for the problem. Finally, extensive simulations indicate that the proposed architecture with the TSHS can enable cooperative perception, with a fast running speed and advanced performance, that is superior to that of the benchmarks, especially when most AVs face limitations in terms of storage and computation.
On the Dynamic Geometry of Kasner Quadrilaterals with Complex Parameter
Authors: Andrica Dorin , Bagdasar Ovidiu
Published: September 2022

We explore the dynamics of the sequence of Kasner quadrilaterals (AnBnCnDn)n≥0 defined via a complex parameter α. We extend the results concerning Kasner triangles with a fixed complex parameter obtained in earlier works and determine the values of α for which the generated dynamics are convergent, divergent, periodic, or dense.
Evaluation of Cytotoxic and Antibacterial Effect of Methanolic Extract of Paeonia lactiflora
Authors: Choi Yu-Ri , Kang Min-Kyung
Published: September 2022

Background and objectives: Bacterial antibiotics have had several side effects. Therefore, interest in natural substances with less side effects is increasing these days. Paeonia lactiflora, the root of Paeonia lactiflora, is used as a raw material for medicines. In this study, we investigated the antibacterial effect and the cytotoxicity of Paeonia lactiflora extract. Materials and Methods: For cytotoxicity, MTT analysis according to ISO 10993-5 was performed. The antibacterial test of the Paeonia lactiflora was determined from bacterial viability, Inhibition zone test, CFU (colony forming unit) and SEM (scanning electron microscope). To confirm the antibacterial component of Paeonia lactiflora, the content of flavonoids and polyphenols was analyzed. Results: Our results showed that Paeonia lactiflora extract contained flavonoids and polyphenols, which exhibited antimicrobial activity against Streptococcus mutans (S. mutans) and Candida albicans (C. ablicans). Further, the cytotoxicity of Paeonia lactiflora extract was low. Conclusions: We believe that our study makes a significant contribution to the literature because it demonstrates that Paeonia lactiflora extract can be used as an antibiotic.
Cranial and Odontological Methods for Sex Estimation—A Scoping Review
Authors: Beschiu Laura Maria , Ardelean Lavinia Cosmina , Tigmeanu Codruta Victoria , Rusu Laura-Cristina
Published: September 2022

The estimation of sex from osteological and dental records has long been an interdisciplinary field of dentistry, forensic medicine and anthropology alike, as it concerns all the above mentioned specialties. The aim of this article is to review the current literature regarding methods used for sex estimation based on the skull and the teeth, covering articles published between January 2015 and July 2022. New methods and new approaches to old methods are constantly emerging in this field, therefore resulting in the need to summarize the large amount of data available. Morphometric, morphologic and biochemical analysis were reviewed in living populations, autopsy cases and archaeological records. The cranial and odontological sex estimation methods are highly population-specific and there is a great need for these methods to be applied to and verified on more populations. Except for DNA analysis, which has a prediction accuracy of 100%, there is no other single method that can achieve such accuracy in predicting sex from cranial or odontological records.
The Impact of COVID-19 Lockdowns in a Sample of Outpatients in a Mental Health Department of a Metropolitan Hospital in Milan
Authors: Percudani Mauro , Porcellana Matteo , Di Bernardo Ilaria , Limosani Ivan , Negri Attilio , Zerbinati Luigi , Morganti Carla
Published: September 2022

Background and Objectives: Italy was the first country in Europe to face the coronavirus 2019 (COVID-19) pandemic and its consequences, which led to two phases of severe restrictions for its population. This study aims to estimate the connections between the trauma of the COVID-19 emergency and the clinical features of a sample of outpatients in a Milan Community Mental Health setting, comparing the first (April 2020) and second lockdowns (November 2020). Materials and Methods: The sample included 116 consecutive outpatients recruited in April 2020 and 116 in November 2020. The subjects were evaluated with Clinical Global Impression Severity (CGI-S), Brief Psychiatric Rating Scale (BPRS-18), and Impact of Event Scale-Revised (IES-R). Results: The IES-R identified 47.4% participants in April and 50% in November with clinical scores over the cut-off. The network analysis of BPRS-18 and IES-R depicted the connection among different symptoms; in April, Unusual Thought Content, Anxiety, and Somatic Concern represented the most central items, and the strongest connections were found between Uncooperativeness and Hostility, Blunted Affect and Emotional Withdrawal, and IES-Intrusion and IES-Arousal. In the November group, the most central items were represented by Conceptual Disorganization and Emotional Withdrawal, whereas the strongest connections were found between IES-Arousal and IES-Intrusion, Excitement and Grandiosity, and Unusual Thought Content and Conceptual Disorganization. Conclusions: Our findings show continued high distress levels and increased psychological burdens during the second phase of restrictions; this could be described as “pandemic fatigue”, a general psychological weariness due to pandemic-related restrictions, as well as a lack of motivation to comply with them. As mental health professionals, our mission during these difficult times has been to keep community psychiatry services accessible, with particular regard to vulnerable and marginalized populations.
A Life-Threatening Infection after Endobronchial Ultrasound Transbronchial Lung Biopsy with Guide Sheath: A Case Report
Authors: Kim Insu , Oh Yeseul , Lee Min Ki , Eom Jung Seop
Published: September 2022

Background and Objectives: Endobronchial ultrasound transbronchial lung biopsy with guide sheath (EBUS-GS-TBLB) has been regarded as a reasonable diagnostic method with an acceptable diagnostic yield. In addition, EBUS-GS-TBLB is considered safer and less invasive compared to percutaneous needle biopsy and thoracoscopic surgery. However, we encountered a case of life-threatening procedure-related fatal infection, which was successfully managed. Case presentation: A 61-year-old man with a 30 pack-year smoking history was referred to our clinic with a necrotic lung mass in the right middle lobe on a chest computed tomography scan. EBUS-GS-TBLB was performed for a pathological diagnosis without immediate complications. Eight days after the procedure, the patient visited the hospital with sudden hemoptysis and severe dyspnea with fever. A chest computed tomography revealed a ruptured lung abscess and pneumonia, developed after EBUS-GS-TBLB. Extracorporeal membrane oxygenation (ECMO) and mechanical ventilation were initiated to manage refractory hypoxia. While maintaining ECMO, video-assisted thoracoscopic surgery was performed at the patient’s bedside in the intensive care unit. After surgery, the patient’s vital signs gradually improved, and a chest computed tomography revealed a reduction in the extent of the lung abscess. Results: Although EBUS-GS-TBLB is minimally invasive and relatively safe when used for the diagnosis of peripheral lung lesions, pulmonary physicians should be aware of this rare but critical complication. Conclusions: We suggest that the careful prescription of prophylactic antibiotics before EBUS-GS-TBLB would be wise if the mass featured a necrotic, cavitary, or cystic lesion.
Long-Term Effects of Rifaximin on Patients with Hepatic Encephalopathy: Its Possible Effects on the Improvement in the Blood Ammonia Concentration Levels, Hepatic Spare Ability and Refractory Ascites
Authors: Yokoyama Keiji , Fukuda Hiromi , Yamauchi Ryo , Higashi Masashi , Miyayama Takashi , Higashi Tomotaka , Uchida Yotaro , Shibata Kumiko , Tsuchiya Naoaki , Fukunaga Atsushi , Umeda Kaoru , Takata Kazuhide , Tanaka Takashi , Shakado Satoshi , Sakisaka Shotaro , Hirai Fumihito
Published: September 2022

Background and Objectives: To investigate the long-term efficacy of rifaximin (RFX) for hyperammonemia and efficacy for refractory ascites in patients with cirrhosis. Materials and Methods: We enrolled 112 patients with liver cirrhosis who were orally administered RFX in this study. Changes in the clinical data of patients were evaluated up to 36 months after RFX administration. The primary endpoint was a change in blood ammonia levels. Secondary endpoints included changes in clinical symptoms, Child–Pugh (CP) score, number of hospitalizations, degree of refractory ascites, adverse events, and the relationship between RFX administration and the renin-angiotensin-aldosterone system. Results: An improved rate of overt hepatic encephalopathy (HE) of 82.7% was observed 3 months after RFX administration, which significantly induced a progressive decrease in blood ammonia concentration and an improved CP score up to 36 months. No serious RFX treatment-related adverse events were observed. 36.5% in patients after RFX administration improved refractory ascites. After RFX administration, patients with satisfactory control of hepatic ascites without addition of diuretic had lower renin concentration than those with poor control (p < 0.01). At less than 41 pg/mL renin concentration, the control of refractory ascites was significantly satisfactory (p < 0.0001). Conclusions: RFX reduced blood ammonia concentration and improved hepatic spare ability and the quality of life of patients with long-term HE to up to 36 months. Our study revealed the effects of RFX against refractory ascites, suggesting that renin concentration may be a predictive marker for assessing ascites control.
The Outcome of Total Knee Arthroplasty for Patients with Psychiatric Disorders: A Single-Center Retrospective Study
Authors: Stoica Cristian Ioan , Nedelea Georgiana , Cotor Dragos C. , Gherghe Mihai , Georgescu Dragos Eugen , Dragosloveanu Christiana , Dragosloveanu Serban
Published: September 2022

Background and Objectives: For some years, psychiatric illness has been a major factor in evaluating the results of total knee arthroplasty. As with other patient-related items, patients diagnosed with mental illness have higher costs of medical treatment, longer recovery, and longer hospital stays. The aim of this paper is to evaluate the role of mental diseases on the surgical outcome compared with the normal population. Materials and Methods: At our hospital, we undertook a retrospective study between June 2020 and January 2022. The experimental group consisted of patients with mental diseases including schizophrenia, bipolar disease, depression, substance uses, or other psychiatric disorders. The control group consisted of patients who underwent total knee arthroplasty and did not have a mental disease. Postoperative complications and length of stay were also recorded during the study. We used the Western Ontario and McMaster Universities Osteoarthritis Index (WOMAC) and the Knee Society Score (KSS) as outcome measures. Results: Between June 2020 and January 2022, a total of 634 patients underwent total knee arthroplasty in our clinic, of which 239 had a mental disease. The majority of patients were female (61%), and the average length of stay was significantly longer for patients with mental illness (6.8 vs. 2.8 days). Preoperative WOMAC and KS function scores demonstrated statistically significant differences between groups (67.83 ± 17.8 vs. 62.75 ± 15.7 and 29.31 ± 19.8 vs. 34.98 ± 21.3). KS knee score did not show any significant differences preoperatively. All postoperative functional scores showed significantly better results for the control group compared to the mental illness group. Conclusions: Mental illness appears to be linked with lower TKA scores before and after the surgical procedure.
Physician-Patient Relationship in Current Cosmetic Surgery Demands More than Mere Respect for Patient Autonomy—Is It Time for the Anti-Paternalistic Model?
Authors: Hostiuc Mihaela , Hostiuc Sorin , Rusu Mugurel Constantin , Isailă Oana-Maria
Published: September 2022

The ethical framework of cosmetic surgery is distinct from the one associated with clinical medicine. This distinctiveness has led to significant difficulties in conceptualizing the physician-patient relationship (PPR), as most models have been developed specifically for the latter. The purpose of this article is to show that the PPR in cosmetic surgery can be better described through a distinct approach that we name the anti-paternalistic model of the PPR, and we will briefly present the differences between it and autonomy-based models. We will analyze the principle of non-interference, the variable degree of autonomy of both the patient and the physician within this relationship, the handling of the relevant information, the principle of beneficence as satisfaction, the difficulties regarding the informed consent, the algorithm allowing for the refusal of the procedure, and children-related issues. Based on this analysis, we will show that an anti-paternalistic model of the PPR is preferable to an autonomy-based one, as it allows for better clarification of the underlying ethical issues involved in cosmetic surgery.
Comparative Study on the Corro-Erosive Properties of Base Cemented Transition Metals TaC and HfC and TaX-HfX-C Coatings
Authors: Ortiz C. H. , Sanchez S. S. , Caicedo J. C. , Aperador W. , Sánchez-Molina Jorge , Ruiz J. Bautista
Published: September 2022

In this research, we report on a comparative study of the corro-erosive properties of TaC and HfC individual coatings and (Ta70-Hf30-C) and (Ta30-Hf70-C) coatings. These were subjected to different impact angles of abrasive particles, corresponding with angles of 30°, 60° and 90°. It was determined that at 90°, a higher structural damage of the coatings obtained was presented. In addition, for all the systems, it was possible to conclude that the coating formed by (Ta30-Hf70-C) presented a roughness of approximately 7.11 nm, which influenced corrosive properties such as the corrosion potential and corrosion rate. Finally, it was possible to conclude that the (Ta30-Hf70-C) coating presented a higher resistance against corro-erosive environments. This was attributed to structural and mainly superficial factors, making this coating the best option to be implemented as a protective coating against highly aggressive environments in industry.
Influences of Strain on the Microstructure and Mechanical Properties of High-Carbon Steel
Authors: Cai Zhen , Gan Xiaolong , Li Yanqi , Liu Sheng , Bao Siqian , Xu Guang
Published: September 2022

The effects of strain on the microstructure and mechanical properties of 0.81C-0.22Si-0.31Mn (wt%) high-carbon steel were investigated by thermal simulation, scanning electron microscopy, high-resolution transmission electron microscopy (HRTEM), and an electron backscatter diffractometer (EBSD). It was found that when the steel was deformed at 670 °C (a temperature between A1 and Ar1), a deformation-induced pearlite transformation and cementite spheroidization occurred. The volume fraction of pearlite and the spheroidization ratio of cementite increased with a strain increase from 20% to 75%. The microstructure mainly consisted of pearlite when the deformation strain exceeded 40%. The aspect ratio was at its maximum (5.3) at 40% strain and decreased to 1.4 at 75% strain. In addition, the strength of the steel decreased and the elongation increased rapidly with the increase in strain from 20% to 60% due to the spheroidization of cementite. However, as the strain further increased to 75%, the strength increased slightly due to the refinement of the ferrite matrix. The comprehensive performance of the investigated steel can be improved by applying a strain between A1 and Ar1.
Prediction Model of End-Point Phosphorus Content in EAF Steelmaking Based on BP Neural Network with Periodical Data Optimization
Authors: Zou Yuchi , Yang Lingzhi , Li Bo , Yan Zefan , Li Zhihui , Wang Shuai , Guo Yufeng
Published: September 2022

The phosphorus (P) content of molten steel is of great importance for the quality of steel products in the electric arc furnace (EAF) steelmaking process. At present, the initial conditions of smelting process in the prediction of end-point P content are still the core part. However, few studies focus on the influence between process data and end-point P content. In this research, the relationships between process data and end-point P content are explored by a BP neural network. Based on the theoretical analysis, influencing factors with high correlation were selected. The prediction model of P content coupled with process data and end-point P content is established. On this basis, the model is optimized with process data of oxygen supply and the time of the first addition of lime. Compared with the practical production data, the results indicate that the hit rate of the model optimized is 87.78% and 75.56% when prediction errors are within ±0.004 and ±0.003 of P content. The model established has achieved the effective prediction for end-point P content, and provided a reference for the control of P content in practical production.
Relationship between Cardiometabolic Factors and the Response of Blood Pressure to a One-Year Primary Care Lifestyle Intervention in Metabolic Syndrome Patients
Authors: Marin-Couture Elisa , Filion Marie-Josée , Boukari Ryma , Jeejeebhoy Khursheed , Dhaliwal Rupinder , Brauer Paula , Royall Dawna , Mutch David M. , Klein Doug , Tremblay Angelo , Rhéaume Caroline
Published: September 2022

Systemic hypertension has been recognized as a modifiable traditional cardiovascular risk factor and influenced by many factors such as eating habits, physical activity, diabetes, and obesity. The objective of this cross-sectional study was to identify factors that predict changes in blood pressure induced by a one-year lifestyle intervention in primary care settings involving a collaboration between family physicians, dietitians, and exercise specialists. Patients with metabolic syndrome diagnosis were recruited by family physicians participating in primary care lifestyle intervention among several family care clinics across Canada. Participants for whom all cardiometabolic data at the beginning (T0) and the end (T12) of the one-year intervention were available were included in the present analysis (n = 101). Patients visited the dietitian and the exercise specialist weekly for the first three months and monthly for the last nine months. Diet quality, exercise capacity, anthropometric indicators, and cardiometabolic variables were evaluated at T0 and at T12. The intervention induced a statistically significant decrease in waist circumference (WC), systolic (SBP) and diastolic (DBP) blood pressure, and plasma triglycerides, and an increase in cardiorespiratory fitness (estimated VO2max). Body weight (p < 0.001), body mass index (BMI) (p < 0.001), and fasting blood glucose (p = 0.006) reduction, and VO2max increase (p = 0.048) were all related to changes in SBP. WC was the only variable for which changes were significantly correlated with those in both SBP (p < 0.0001) and DBP (p = 0.0004). Variations in DBP were not associated with changes in other cardiometabolic variables to a statistically significant extent. Twelve participants were identified as adverse responders (AR) in both SBP and DBP and displayed less favorable changes in WC. The beneficial effects of the primary care lifestyle intervention on blood pressure were significantly associated with cardiometabolic variables, especially WC. These findings suggest that a structured lifestyle intervention in primary care can help improve cardiometabolic risk factors in patients with metabolic syndrome and that WC should be systematically measured to better stratify the patient’s hypertension risk.
Sugarcane Metabolome Compositional Stability in Pretreatment Processes for NMR Measurements
Authors: Date Yasuhiro , Ishikawa Chiaki , Umeda Makoto , Tarumoto Yusuke , Okubo Megumi , Tamura Yasuaki , Ono Hiroshi
Published: September 2022

Sugarcane is essential for global sugar production and its compressed juice is a key raw material for industrial products. Sugarcane juice includes various metabolites with abundances and compositional balances influencing product qualities and functionalities. Therefore, understanding the characteristic features of the sugarcane metabolome is important. However, sugarcane compositional variability and stability, even in pretreatment processes for nuclear magnetic resonance (NMR)-based metabolomic studies, remains elusive. The objective of this study is to evaluate sugarcane juice metabolomic variability affected by centrifugation, filtration, and thermal pretreatments, as well as the time-course changes for determining optimal conditions for NMR-based metabolomic approach. The pretreatment processes left the metabolomic compositions unchanged, indicating that these pretreatments are compatible with one another and the studied metabolomes are comparable. The thermal processing provided stability to the metabolome for more than 32 h at room temperature. Based on the determined analytical conditions, we conducted an NMR-based metabolomic study to discriminate the differences in the harvest period and allowed for successfully identifying the characteristic metabolome. Our findings denote that NMR-based sugarcane metabolomics enable us to provide an opportunity to collect a massive amount of data upon collaboration between multiple researchers, resulting in the rapid construction of useful databases for both research purposes and industrial use.
Identification of Plant-Derived Bioactive Compounds Using Affinity Mass Spectrometry and Molecular Networking
Authors: Ramatapa Thabo , Msobo Anathi , Maphari Pfano W. , Ncube Efficient N. , Nogemane Noluyolo , Mhlongo Msizi I.
Published: September 2022

Affinity selection-mass spectrometry (AS-MS) is a label-free binding assay system that uses UHPLC-MS size-based separation methods to separate target-compound complexes from unbound compounds, identify bound compounds, classify compound binding sites, quantify the dissociation rate constant of compounds, and characterize affinity-extracted ligands. This label-free binding assay, in contrast to conventional biochemical (i.e., high-throughput screening (HTS)) approaches, is applicable to any drug target, and is also concise, accurate, and adaptable. Although AS-MS is an innovative approach for identifying lead compounds, the possibilities of finding bioactive compounds are limited by competitive binding, which occurs during the equilibration of extracts with the target protein(s). Here, we discuss the potential for metabolite profiling complemented with molecular networking to be used alongside AS-MS to improve the identification of bioactive compounds in plant extracts. AS-MS has gained significant prominence in HTS labs and shows potential to emerge as the driving force behind novel drug development in the future.
Mango-Stone-Derived Nitrogen-Doped Porous Carbon for Supercapacitors
Authors: Wang Yi , Yuan Xinzi , Guan Xingyu , Ren Kunling , Yang Yan , Luo Jun , Zheng Yantao
Published: September 2022

The preparation of N-doped porous carbon (NC-800) is presented via facile mango stone carbonization at 800 °C. The NC-800 material exhibits good cycle stability (the capacity retention is 97.8% after 5000 cycles) and high specific capacitance of 280 F/g at 1 A/g. Furthermore, the assembled symmetric device of NC-800//NCs-800 exhibits about 31.1 Wh/kg of energy density at 800 W/kg in a voltage range of 0–1.6 V. The results of the study suggest that NC-800 may be a promising energy storage material for practical application.
Hierarchical Self-Assembly of Dipolar ZnO Nanoparticles and Microdroplets
Authors: Ghifari Najla , Bennacer Rachid , Chahboun Adil , El Abed Abdel I.
Published: September 2022

In this work, we investigated the orientation and the polarization of ZnO nanoparticles, which serve as building blocks of highly monodisperse microspheres, using a droplet microfluidic-assisted synthesis method. We observe, for the first time, a square lattice organization of liquid microdroplets, in a steady state, at the oil/water interface. Such square organization reveals clearly a dipolar organization of ZnO nanoparticles at the surfaces of droplets at the early stage of ZnO nanocrystal aggregation and microsphere formation. We discuss different models of organization of ZnO nanoparticles and show that the well-known tip-streaming effect in droplets in microfluidics explains the reason for the obtained dipolar droplets. The square organization is illustrated and explained.
Different Gut Microbiomes of Developmental Stages of Field-Collected Native and Invasive Western Bean Cutworm, Striacosta albicosta, in Western Nebraska
Authors: Ayayee Paul A. , Currie Austin , Peterson Julie A.
Published: September 2022

While insects harbor gut microbial associates that perform various functions for the host, lepidopterans have not been considered as prime examples of having such relationships. The western bean cutworm, Striacosta albicosta (Lepidoptera: Noctuidae), is native to North America and has historically been a significant corn pest in its western distribution. It is currently expanding eastwards and is invasive in these new regions. Using 16S rRNA gene sequencing data, this study focused on characterizing the microbiota associated with field-collected eggs, larvae, adults, and host plant materials of S. albicosta in its native range. The diversity of microbiomes varied significantly among S. albicosta eggs, larvae, adults, and the host plant materials. Microbial diversity was highest in adult stages relative to other insect stages. Furthermore, S. albicosta eggs, larvae, and adults harbored very distinct microbial communities, indicative of stage-specific microbiomes possibly performing different functions. Bacterial taxa underscoring these differences in composition identified four phyla and thirty families across samples. Members of the Firmicutes (Unassigned Lactobacillales), Proteobacteria (Pseudomonadaceae and Moraxellaceae), Bacteroidota (Weeksellaceae), and Chloroflexi dominated across all developmental stages. In addition, cellulose-degrading Lactobacillales (phylum: Firmicutes) dominated larval microbiomes, indicative of larval plant diet. This taxon was comparatively negligible in eggs and adults. Members of Proteobacteria dominated egg and host leaf microbiomes, while members of Bacteroidota dominated nectar-feeding adult gut microbiomes. Our results suggest a possible diet-dependent stage-specific microbiome composition and the potential for using stage-specific microbes as potential biological control tools against this important pest moving forward.
Impact of Cellulolytic Fungi on Biodegradation of Hemp Shives and Corn Starch-Based Composites with Different Flame-Retardants
Authors: Vasiliauskienė Dovilė , Boris Renata , Balčiūnas Giedrius , Kairytė Agnė , Urbonavičius Jaunius
Published: September 2022

Biocomposite boards (BcBs) composed of hemp shives and corn starch are known as thermal insulating or structural building materials. Therefore, they must be stable during exploitation. However, BcBs are exposed to microorganisms present in the environment, and it is of great interest to investigate the biodegradation behaviour of these materials. This work identified microorganisms growing on BcBs that contain either Flovan CGN or expandable graphite as flame retardants and selected fungi such as Rhizopus oryzae and Aspergillus fumigatus to test the way they affect the materials of interest. For this purpose, the enzymatic activity of cellulases and amylases produced by these organisms were determined. In addition, the apparent density as well as compressive strength of the affected boards were evaluated. The results showed that apparent density and compressive strength deteriorated in BcB composition with the Flovan CGN flame retardant. At the same time, the level of deterioration was lower when the expandable graphite was used, suggesting that it also acts as an antimicrobial agent. A scanning electronic microscopy analysis was employed to monitor the growth of microorganisms in the BcBs. Such analysis demonstrated that, regardless of BcB composition, fungi easily penetrate into the middle layers of the material.
A New Strain of Lecanicillium uredinophilum Isolated from Tibetan Plateau and Its Insecticidal Activity
Authors: Meng Yun , Wellabada Hewage Don P. I. Damithri , Wang Dun
Published: September 2022

A new strain QHLA of Lecanicillium uredinophilum was isolated from a Chinese caterpillar fungus complex and its optimum growth temperature and fermentation conditions were studied. Its insecticidal activity was tested against larvae of seven different insect pests, including Henosepilachna vigintioctopunctata, Spodoptera exigua, Plutella xylostella, Spodoptera frugiperda, Sitobion avenae, Hyalopterus perikonus, and Aphis citricola. The optimum growth temperature was 21–24 °C. The highest spore production of the strain QHLA was 4.08 × 106 spore/mL on solid medium with a nitrogen source of NH4Cl. However, the highest mycelial growth rate of the strain QHLA was on solid medium with a nitrogen source from yeast extract (4.63 ± 0.03 mm/d). When the liquid medium contained peptone, yeast extract, and glucose, the water content of the mycelia was the lowest, while the spore production was the highest until day 12. When the liquid medium contained glucose, tussah pupa powder, KH2PO4, and MgSO4, the mycelia production was highest until day 8. The bioassay for insecticidal activity indicated that the LC50 values of QHLA were 6.32 × 103 spore/mL and 6.35 × 103 spore/mL against Sitobion avenae and Aphis citricola, respectively, while the LC90 values of the strain QHLA against Aphis citricola and Sitobion avenae were 2.11 × 107 spore/mL and 2.36 × 108 spore/mL, respectively. Our results demonstrated that the strain QHLA was a high virulence pathogenic fungus against insect pests, with the potential to be developed as a microbial pesticide.