bluuebunny/crossref_metadata_2025 huggingface dataset:
Scientometric Research on Trend Analysis of Nano-Based Sustained Drug Release Systems for Wound Healing
Authors: Tang Kuangyun , Cai Zhengyu , Lv Yanhan , Liu Ruiqi , Chen Qianming , Gu Jun
Published: April 2023

Nanomaterials, such as the nanoparticle (NP), nanomicelle, nanoscaffold, and nano-hydrogel, have been researched as nanocarriers for drug delivery more and more recently. Nano-based drug sustained release systems (NDSRSs) have been used in many medical fields, especially wound healing. However, as we know, no scientometric analysis has been seen on applying NDSRSs in wound healing, which could be of great importance to the relevant researchers. This study collected publications from 1999 to 2022 related to NDSRSs in wound healing from the Web of Science Core Collection (WOSCC) database. We employed scientometric methods to comprehensively analyze the dataset from different perspectives using CiteSpace, VOSviewer, and Bibliometrix. The results indicated that China published the most significant number of documents in the last two decades, Islamic Azad Univ was the most productive institution, and Jayakumar, R was the most influential author. Regarding the analysis of keywords, trend topics indicate that “antibacterial”, “chitosan (CS)”, “scaffold”, “hydrogel”, “silver nanoparticle”, and “growth factors (GFs)” are the hot topics in recent years. We anticipate that our work will provide a comprehensive overview of research in this field and help scholars better understand the research hotspots and frontiers in this area, thus inspiring further explorations in the future.
An Alternative Method to Determine the Quantum Yield of the Excited Triplet State Using Laser Flash Photolysis
Authors: Borissevitch Iouri Evgenievitch , Silveira-Alves Eli , Almeida Claudio Gabriel Lemos , Souza Guilherme Rocha Lino , Sokolov Svyatoslav Sergeevich , Gonçalves Pablo José
Published: April 2023

The excited triplet state of a molecule (T1) is one of the principal intermediate products in various photochemical processes due to its high reactivity and relatively long lifetime. The T1 quantum yield (φT) is one of the most important characteristics in the study of photochemical reactions. It is of special interest to determine the φT of various photoactive compounds (photosensitizer, PS) used in photodynamic therapy (PDT). PDT is an effective medical technique for the treatment of serious diseases, such as cancer and bacterial, fungal and viral infections. This technique is based on the introduction of a PS to a patient’s organism and its further excitation by visible light, producing reactive oxygen species (ROS) via electron or energy transfer from the PS T1 state to the biological substrate or molecular oxygen. Therefore, information on the φT value is fundamental in the search for new and effective PSs. There are various experimental methods to determine φT values; however, these methods demonstrate a high discrepancy between φT values. This stimulates the analysis of various factors that can affect the determined φT. In this study, we analyze the effect of the intensity profile of the exciting laser pulse on the calculation of the φT value obtained by the Laser Flash Photolysis technique. The φT values were determined by analyzing the variation of a sample transient absorption in the function of the exciting laser pulse intensity, in combination with the spectral and kinetic PS characteristics obtained in nonlinear optical experiments by solving the rate equations of a five-level-energy diagram. Well-studied PSs: meso-tetra(4-sulfonatophenyl) (TPPS4) porphyrins, its zinc complex (ZnTPPS4) and the zinc complex of meso-tetrakis(N-methylpyridinium-4-yl) (ZnTMPyP) were chosen as test compounds to evaluate the proposed model. The φT values were determined through a comparison with the φT,TMPyP = 0.82 of meso-tetrakis(N-methylpyridinium-4-yl) (TMPyP), used as a standard. The obtained results (φT,TPPS4=0.75±0.02, φT,ZnTMPyP=0.90±0.03), and φT,ZnTPPS4=0.89±0.03) are highly compatible with the medium φT values obtained using the known methods.
Progress in Short Wavelength Energy-Efficient High-Speed Vertical-Cavity Surface-Emitting Lasers for Data Communication
Authors: Tian Si-Cong , Ahamed Mansoor , Bimberg Dieter
Published: April 2023

The current progress of energy-efficient high-speed VCSELs based on GaAs substrates is presented. Novel approaches for the design of VCSELs are presented, potentially leading to larger bandwidth bit rates and lower power consumption. The first approach is based on the optimization of the VCSEL photon lifetime. The second one introduces a novel design based on oxidizing the apertures from multiple etched holes of varying geometries. These designs are also essential for improving the energy efficiency of future modules by optimizing the match of the electronic driver and the photonic device.
Effective Induction of Fertile Gametes in Oriental × Trumpet (OT) Lily by High Temperatures
Authors: Huang Yi-Xuan , Yu Peng-Cheng , Zhang Qian , Yue Zhi-Yi , Piao Mei-Ling , Gao Xue , Jia Gui-Xia
Published: April 2023

Lily is a very important bulb crop, and interspecific distant hybridization is a crucial method of lily breeding. However, F1 interspecific hybrids tend to be highly sterile due to low levels of genetic homozygosity. This can be addressed by meiotic polyploidization, which has the advantage of reducing breeding time and being able to promote genetic recombination resulting in many variant progenies. High temperatures have been proven to induce 2n gametes via hindering a spindle formation in several plants, but little has been reported in lilies. In the present study, after observing the correlation between the development of the pollen mother cells (PMCs) and the length of the buds, 28–31 mm long buds were selected as the experimental material, which were at the stage of prophase I–metaphase I. Individual buds were induced at different temperatures (40 °C, 42 °C, and 44 °C) and durations (4 h and 6 h) using self-made multiwire heating equipment, and successfully induced fertile male gametes.. The best results were achieved with treatment of 42 °C for 4 h, reaching a maximum fertile pollen induction rate of 36.64%, while bud mortality was 40%. Two chemicals, colchicine and oryzalin, were also used by injection, and only the treatment with oryzalin obtained fertile gametes, with the highest fertile gamete rate of 15.39% at a concentration of 0.005%, while the bud mortality was 36.67%. This suggests that high temperatures have a superior effect on lily 2n gamete induction. In addition, the pollen obtained from the 6 h induction of high temperature was significantly larger than that from the 4 h induction, with an average diameter of 138.64 μm and 107.88 μm, respectively, 2.35 and 1.84 times wider than haploid pollen. The fertile pollen was crossed with four cultivars and two species, and a total of 267 embryonic seeds were obtained, with the highest embryonic rate of 4.52% in OT lily ‘Mister Cas’ as the parent, which had a germination rate of 26.27%. This suggests that the method of high-temperature induction for fertile gametes probably has important significance for ploidy and distant hybrid breeding in lilies.
Nuclear DNA Amounts in Chinese Bryophytes Estimated by Flow Cytometry: Variation Patterns and Biological Significances
Authors: Li Dandan , Luo Guangyu , Guo Shuiliang , Huang Ruoling , Yang Jun , Cao Tong , Yu Jing
Published: April 2023

There exists an obvious gap in our knowledge of the nuclear DNA amount of bryophytes, not only in terms of the low number of species represented, but also in systematic and geographic representation. In order to increase our knowledge of nuclear DNA amounts and variation patterns in bryophytes, and their potential phylogenetic significances and influences on phenotypes, we used flow cytometry to determine the DNA 1C values of 209 bryophyte accessions, which belong to 145 mosses and 18 liverworts collected from China, by using Physcomitrella patens as a standard. We quantified the differences in DNA 1C values among different orders and families and constructed a phylogenetic tree of 112 mosses with four gene sequences (nad5, rbcL, trnL-F, and 18S-ITS1-5.8S-ITS2-26S). DNA 1C values were mapped onto the phylogenetic tree to test a potential phylogenetic signal. We also evaluated the correlations of the DNA 1C value with the sizes of individuals, leaves, cells, and spores by using a phylogenetically controlled analysis. New estimates of nuclear DNA amounts were reported for 145 species. The DNA 1C values of 209 bryophyte accessions ranged from 0.422 pg to 0.860 pg, with an average value of 0.561 pg, and a 2.04-fold variation covered the extremes of all the accessions. Although the values are not significantly different (p = 0.355) between mosses (0.528 pg) and liverworts (0.542 pg), there are variations to varying extents between some families and orders. The DNA 1C value size exerts a positive effect on the sizes of plants, leaves, and cells, but a negative effect on spore size. A weak phylogenetic signal is detected across most moss species. Phylogenetic signals are comparatively strong for some lineages. Our findings show that bryophytes have very small and highly constrained nuclear DNA amounts. There are nucleotype effects of nuclear DNA amounts for bryophytes at the individual, organ, and cell levels. We speculate that smaller nuclear DNA amounts are advantageous for bryophytes in dry environments. Significant differences in the DNA 1C values among some moss families and orders, as well as phylogenetic signals for some lineages, imply that nuclear DNA amount evolution in mosses seems to be unidirectional.
The Impact of Carbohydrate Management on Coleoptile Elongation in Anaerobically Germinating Seeds of Rice (Oryza sativa L.) under Light and Dark Cycles
Authors: Hirano Haru , Watanabe Takeru , Fukuda Mika , Fukao Takeshi
Published: April 2023

The ability of rice to elongate coleoptiles under oxygen deprivation is a determinant of anaerobic germination tolerance, critical for successful direct seeding. Most studies on anaerobic coleoptile elongation have been performed under constant darkness or in flooded soils because a drilling method was the primary approach for direct seeding of rice. However, aerial seeding is becoming popular, in which seeds which land on flooded soils are exposed to light during the daytime. Here, we investigated physiological mechanisms underlying anaerobic elongation of coleoptiles under light and dark cycles. This study identified two novel varieties, LG and L202, enabling the development of long coleoptiles under oxygen limitation, comparable to well-characterized varieties with strong anaerobic germination tolerance. Germination experiments using these two tolerant and two intolerant varieties, including Takanari and IR64, revealed that light and dark cycles increased coleoptile length in LG, Takanari, and IR64 relative to constant darkness. Interestingly, even in intolerant lines, dramatic starch breakdown and soluble carbohydrate accumulation occurred under oxygen limitation. However, intolerant lines were more susceptible to a representative soluble sugar, glucose, than tolerant lines under oxygen deprivation, suggesting that coleoptile growth can be inhibited in intolerant lines due to hypersensitivity to soluble sugars accumulated in anaerobically germinating seeds.
Genotyping by Sequencing for SNP-Based Linkage Analysis and the Development of KASPar Markers for Male Sterility and Polyembryony in Citrus
Authors: Montalt Rafael , Cuenca José , Vives María Carmen , Mournet Pierre , Navarro Luis , Ollitrault Patrick , Aleza Pablo
Published: April 2023

Polyembryony and male sterility (MS) are essential characters for citrus breeding. MS, coupled with parthenocarpy, allows for addressing the diversification of diploid seedless mandarin varieties, and nucleocytoplasmic MS is the most prevalent system. Polyembryony limits the use of seed parents in scion breeding programs, and the recovery of monoembryonic hybrids to be used as female parents is a crucial pre-breeding component. The objectives of this work were the identification of SNPs closely linked with the genes implied in these traits for marker-assisted selection. Genotyping by sequencing was used to genotype 61 diploid hybrids from an F1 progeny recovered from crossing ‘Kiyomi’ and ‘Murcott’ tangors. A total of 6444 segregating markers were identified and used to establish the two parental genetic maps. They consisted of 1374 and 697 markers encompassing 1416.287 and 1339.735 cM for ‘Kiyomi’ and ‘Murcott’, respectively. Phenotyping for MS and polyembryony was performed. The genotype–trait association study identified a genomic region on LG8 which was significantly associated with MS, and a genomic region on LG1 which was significantly associated with polyembryony. Annotation of the identified region for MS revealed 19 candidate genes. One SNP KASPar marker was developed and fully validated for each trait.
Influence of Temperature on Seed Germination of Five Wild-Growing Tulipa Species of Greece Associated with Their Ecological Profiles: Implications for Conservation and Cultivation
Authors: Hatzilazarou Stefanos , Pipinis Elias , Kostas Stefanos , Stagiopoulou Rafaela , Gitsa Konstantina , Dariotis Eleftherios , Avramakis Manolis , Samartza Ioulietta , Plastiras Ioannis , Kriemadi Eleni , Bareka Pepy , Lykas Christos , Tsoktouridis Georgios , Krigas Nikos
Published: April 2023

Although tulips are famous worldwide as ornamental plants, the knowledge about the seed germination of wild-growing species remains limited. The aim of the present study was to investigate the effect of temperature on seed germination of the local, wild-growing Greek endemics Tulipa bakeri and T. goulimyi and the sub-Balkan endemic T. undulatifolia, which are threatened with extinction, as well as the Mediterranean T. australis and the Asiatic T. clusiana naturalized on Chios Island (Greece). The germination responses at five constant temperatures (5, 10, 15, 20, and 25 °C) were assessed for all studied species in growth chambers under a 12:12 light–dark photoperiod. The ecological profile for each species was developed in R using open-source bioclimatic data; this was built to illustrate the abiotic environmental conditions of their wild habitats, to facilitate the examination of temperature effects on seed germination, and to facilitate their cultivation in artificial environments. The results indicated that the seed germination requirements of the studied species had a range-specific temperature dependence, reflecting their natural adaptation to local ecological conditions. Seed germination of T. bakeri, T. australis, and T. clusiana was observed only in a narrow range of very low temperatures (5–10 °C), whereas germination of T. undulatifolia and T. goulimyi occurred at temperatures between 5 and 15 °C. A temperature increase to 20 or 25 °C resulted in the absence of seed germination for all five Greek tulip species. The germinated seeds were planted in pots and bulblets were developed under greenhouse conditions. Seeds and bulblets constitute valuable genetic materials for the cultivation and ex situ conservation of these five Greek tulip species, three of which are threatened with extinction.
Effect of Soil Texture, Nanoparticle Size, and Incubation Period on the Dissolution of ZnO Nanoparticles
Authors: Umar Wajid , Czinkota Imre , Gulyás Miklós , Ayub Muhammad Ashar , Sebők András , Nadeem Muhammad Yousaf , Zulfiqar Muhammad Arslan
Published: April 2023

Zinc is an essential plant and human nutrient and its primary source is Zn-rich food consumption. The only way to enrich plants with Zn is through the application of Zn fertilizers including various chemical and organic sources of ZnO nanoparticles (NPs). The Zn bioavailability from ZnO NPs must be considered for their recommendation as a fertilizer, and very little is known about the efficacy of such fertilizers in the Hungarian soil environment. In the present investigation, we prepared ZnO NPs of different sizes and applied them in two distinct textures of soils (sandy loam (SL) and silty clay (SC)) in an incubation experiment. The prepared ZnO NPs were characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM). ZnO NPs were applied in both soil types at 500 mg L−1 in the form of a suspension, and ZnSO4 was applied in the form of a solution. The soils were incubated for 7 and 14 days. Column leaching was performed to analyze the dissolved Zn. Retained Zn in the soil matrix was extracted using 0.05 M EDTA. The results showed that approximately 21–23% and 10–13% higher Zn was observed in the pore water of SL and SC soils, respectively, when spiked with small-sized NPs compared to large-sized NPs, while 14–26% higher dissolved Zn was observed in SL soil compared to SC soil. It is concluded that the size of NPs and the soil texture are the main factors that play important roles in deciding the fate of NPs under an alkaline soil environment.
Modification of Polyamide 66 for a Media-Tight Hybrid Composite with Aluminum
Authors: Lins Fabian , Kahl Christian , Zarges Jan-Christoph , Heim Hans-Peter
Published: April 2023

Metal–plastic composites are becoming increasingly important in lightweight construction. As a combination, e.g., for transmission housings in automobiles, composites made of die-cast aluminum housings and Polyamide 66 are a promising material. The interface between metal and plastic and the properties of the plastic component play an important role with regard to media tightness against transmission oil. The mechanical properties of the plastic can be matched to aluminum by glass fibers and additives. In the case of fiber-reinforced plastics, the mechanical properties depend on the fiber length and their orientation. These structural properties were investigated using computer tomography and dynamic image analysis. In addition to the mechanical properties, the thermal expansion coefficient was also investigated since a strongly different coefficient of the joining partners leads to stresses in the interface. Polyamide 66 was processed with 30 wt% glass fibers to align the mechanical and thermal expansion properties to those of aluminum. In contrast to the reinforcement additives, an impact modifier to improve the toughness of the composite, and/or a calcium stearate to exert influence on the rheological behavior of the composite, were used. The combination of the glass fibers with calcium stearate in Polyamide 66 led to high stiffnesses (11,500 MPa) and strengths (200 MPa), which were closest to those of aluminum. The coefficient of thermal expansion was found to be 6.6 × 10−6/K for the combination of Polyamide 66 with 30 wt% glass fiber and shows a low expansion exponent compared to neat Polamid 66. It was detected that the use of an impact modifier led to less orientated fibers along the injection direction, which resulted in lower modulus and strength in terms of mechanical properties.
Microbial Exopolysaccharide Composites in Biomedicine and Healthcare: Trends and Advances
Authors: Ahuja Vishal , Bhatt Arvind Kumar , Banu J. Rajesh , Kumar Vinod , Kumar Gopalakrishnan , Yang Yung-Hun , Bhatia Shashi Kant
Published: April 2023

Microbial exopolysaccharides (EPSs), e.g., xanthan, dextran, gellan, curdlan, etc., have significant applications in several industries (pharma, food, textiles, petroleum, etc.) due to their biocompatibility, nontoxicity, and functional characteristics. However, biodegradability, poor cell adhesion, mineralization, and lower enzyme activity are some other factors that might hinder commercial applications in healthcare practices. Some EPSs lack biological activities that make them prone to degradation in ex vivo, as well as in vivo environments. The blending of EPSs with other natural and synthetic polymers can improve the structural, functional, and physiological characteristics, and make the composites suitable for a diverse range of applications. In comparison to EPS, composites have more mechanical strength, porosity, and stress-bearing capacity, along with a higher cell adhesion rate, and mineralization that is required for tissue engineering. Composites have a better possibility for biomedical and healthcare applications and are used for 2D and 3D scaffold fabrication, drug carrying and delivery, wound healing, tissue regeneration, and engineering. However, the commercialization of these products still needs in-depth research, considering commercial aspects such as stability within ex vivo and in vivo environments, the presence of biological fluids and enzymes, degradation profile, and interaction within living systems. The opportunities and potential applications are diverse, but more elaborative research is needed to address the challenges. In the current article, efforts have been made to summarize the recent advancements in applications of exopolysaccharide composites with natural and synthetic components, with special consideration of pharma and healthcare applications.
Investigation on Properties of Raw and Alkali Treated Novel Cellulosic Root Fibres of Zea Mays for Polymeric Composites
Authors: Kavitha S. Anne , Priya R. Krishna , Arunachalam Krishna Prakash , Avudaiappan Siva , Maureira-Carsalade Nelson , Roco-Videla Ángel
Published: April 2023

Today, new materials based on natural fibres have been emerging day by day to completely eradicate plastics to favour our environmental nature. In this view, the present work is based on the extraction and characterisation of the novel root fibres of the Zea mays (Zm) plant, grown by the hydroponic method. Both the dried untreated and alkali treated root fibres are investigated using a variety of structural, morphological, thermal, elemental and mechanical tests by subjecting both the samples to p-XRD, FT-IR, SEM-EDAX, TGA-DTA, CHNS and tensile strength analyses. Thermal conductivity of the untreated and treated fibres is found using Lee’s disc experiment. From p-XRD analysis, the Crystallinity Index, Percentage Crystallinity and Crystallite size of the samples are found. FT-IR studies clarify the different vibrational groups associated with the fibre samples. SEM images show that the surface roughness increases for the chemically treated samples, such that it may be effectively utilised as reinforcement for polymeric composites. The diameter of the fibre samples is found using SEM analysis. According to the EDAX spectrum, Zm fibres in both their raw and processed forms have high levels of Carbon (C) and Oxygen (O). The TGA-DTA tests revealed that the samples of natural fibre have good thermal characteristics. CHNS studies show that Carbon content is high for these samples, which is the characteristic of many natural fibres. Chemical analysis is used to ascertain the prepared samples’ chemical makeup. It reveals that both samples have significant amounts of cellulose. The density of the fibres is found to be in the range 0.3–0.6 g/cc, which is much less than any other natural fibre. Therefore, it can be used in light weight applications. From the tensile strength analysis, physical properties such as Young’s modulus and micro-fibril angle are determined. The fibres in the roots exhibit a lower tensile strength. Thus, these fibres can be used in powdered form as reinforcement for natural rubber or epoxy composites. After examining all of its properties, it could be reasonably speculated that Zea mays root fibres can be considered as an efficient reinforcement for various matrices to produce attractive bio-composites.
Cd(II)/Mn(II)/Co(II)/Ni(II)/Zn(II) Coordination Polymers Built from Dicarboxylic Acid/Tetracarboxylic Acid Ligands: Their Structural Diversity and Fluorescence Properties
Authors: Liu Lu , Li Jian-Min , Zhang Meng-Di , Wang Hui-Jie , Li Ying , Zhang Zhen-Bei , Zhao Zi-Fang , Xi Yu , Huang Yuan-Yuan , Xu Jie , Zhang Bo , Chen Jun , Cui Cheng-Xing
Published: April 2023

Six Cd(II)/Mn(II)/Co(II)/Ni(II)/Zn(II) coordination complexes are formulated as [Cd2(X2−)2(μ3-O)2/3]n (1), [Mn2(X2−)2(μ3-O)2/3]n (2), {[Co1.5(Y4−)0.5(4,4′-bpy)1.5(OH−)]·2H2O}n (3), {[Ni(X2−)(4,4′-bpy)(H2O)2]·4H2O}n (4), [Zn(m-bdc2−)(bebiyh)]n (5), and [Cd(5-tbia2−)(bebiyh)]n (6) (H2X = 3,3′-(2,3,5,6-tetramethyl-1,4-phenylene) dipropionic acid. H4Y = 2,2′-(2,3,5,6-tetramethyl-1,4-phenylene)bis(methylene) dimalonic acid, bebiyh = 1,6-bis(2-ethyl-1H-benzo[d]imidazol-1-yl)hexane, m-H2bdc = 1,3-benzenedicarboxylic acid, and 5-H2tbia = 5-(tert-butyl)isophthalic acid) were obtained by hydrothermal reactions and structurally characterized. Complexes 1 and 2 have a 6-connected 3D architecture and with several point symbols of (36·46·53). Complex 3 features a 5-connected 3D net structure with a point symbol of (5·69). Complex 4 possesses a 4-connected 2D net with a vertex symbol of (44·62). Complex 5 is a 3-connected 2D network with a point symbol of (63). Complex 6 is a (3,3)-connected 2D network with a point symbol of (63)2. In addition, complexes 1 and 4 present good photoluminescence behaviors. The electronic structures of 1 and 4 were investigated with the density functional theory (DFT) method to understand the photoluminescence behaviors.
Polyaniline-Supported Nickel Oxide Flower for Efficient Nitrite Electrochemical Detection in Water
Authors: Al-Kadhi Nada S. , Hefnawy Mahmoud A. , Alamro Fowzia S. , Pashameah Rami Adel , Ahmed Hoda A. , Medany Shymaa S.
Published: April 2023

A modified electrode with conducting polymer (Polyaniline) and NiO nanoflowers was prepared to detect nitrite ions in drinking water. A simple method was used to prepare the NiO nanoflower (NiOnF). Several techniques characterized the as-prepared NiOnF to determine the chemical structure and surface morphology of the NiO, such as XRD, XPS, FT-IR, and TGA. The activity of the electrode toward nitrite sensing was investigated over a wide range of pH (i.e., 2 to 10). The amperometry method was used to determine the linear detection range and limit. Accordingly, the modified electrode GC/PANI/NiOnf showed a linear range of detection at 0.1–1 µM and 1–500 µM. At the same time, the limit of detection (LOD) was 9.7 and 64 nM for low and high concentrations, respectively. Furthermore, the kinetic characteristics of nitrite, such as diffusion and transport coefficients, were investigated in various media. Moreover, the charge transfer resistance was utilized for nitrite electrooxidation in different pH values by the electrochemical impedance technique (EIS). The anti-interfering criteria of the modified surfaces were utilized in the existence of many interfering cations in water (e.g., K+, Na+, Cu2+, Zn2+, Ba2+, Ca2+, Cr2+, Cd2+, Pd2+). A real sample of the Nile River was spiked with nitrite to study the activity of the electrode in a real case sample (response time ~4 s). The interaction between nitrite ions and NiO{100} surface was studied using DFT calculations as a function of adsorption energy.
Modelling across Multiple Scales to Design Biopolymer Membranes for Sustainable Gas Separations: 1—Atomistic Approach
Authors: Papchenko Kseniya , Ricci Eleonora , De Angelis Maria Grazia
Published: April 2023

In this work, we assessed the CO2 and CH4 sorption and transport in copolymers of 3-hydroxybutyrate and 3-hydroxyvalerate (PHBV), which showed good CO2 capture potential in our previous papers, thanks to their good solubility–selectivity, and are potential biodegradable alternatives to standard membrane-separation materials. Experimental tests were carried out on a commercial material containing 8% of 3-hydroxyvalerate (HV), while molecular modelling was used to screen the performance of the copolymers across the entire composition range by simulating structures with 0%, 8%, 60%, and 100% HV, with the aim to provide a guide for the selection of the membrane material. The polymers were simulated using molecular dynamics (MD) models and validated against experimental density, solubility parameters, and X-ray diffraction. The CO2/CH4 solubility–selectivity predicted by the Widom insertion method is in good agreement with experimental data, while the diffusivity–selectivity obtained via mean square displacement is somewhat overestimated. Overall, simulations indicate promising behaviour for the homopolymer containing 100% of HV. In part 2 of this series of papers, we will investigate the same biomaterials using a macroscopic model for polymers and compare the accuracy and performance of the two approaches.
Evolution of the Viscoelastic Properties of Filler Reinforced Rubber under Physical Aging at Room Temperature
Authors: Vizcaíno-Vergara María , Kari Leif , Tunnicliffe Lewis B. , Busfield James J. C.
Published: April 2023

Filler reinforced rubber is widely used for engineering applications; therefore, a sound characterization of the effects of physical aging is crucial for accurately predicting its viscoelastic properties within its operational temperature range. Here, the torsion pendulum is used to monitor the evolution of the storage and loss modulus of carbon black filled samples for four days after a temperature drop to 30 °C. The storage modulus presents a continuous increase, while the loss modulus generally displays a steady decrease throughout the four days that each test was conducted. The relationship of the recovery rates with the carbon black properties is also studied, analysing its dependency on the particle size and aggregate structure. The evolution of the recovery rate seems to depend linearly on the surface area while the carbon black structure appears to have a much weaker influence on the physical aging behavior for the set of compounds tested. The obtained results corroborate the presence of physical aging at room temperature for filler rubber materials and the ability of the torsion pendulum to monitor the storage and loss modulus change, providing pivotal data on the influence of physical aging on the viscoelastic properties of the material.
Pore Distribution Characteristics of Different Lithofacies Shales: Evidence from Scanning Electron Microscopy
Authors: Wang Junjie , Lu Shuangfang , Zhang Pengfei , Zhi Qi , Huang Hongsheng
Published: April 2023

To disclose the pore distribution characteristics of different lithofacies lacustrine shales, ten samples collected from the Shahejie Formation, Dongying Sag, Bohai Bay Basin, China, were examined using argon ion beam milling–scanning electron microscopy (SEM). A quantitative method was adopted to characterize shale pore distributions based on the SEM images. Mercury intrusion capillary pressure was employed to determine the pore throat size distributions of the shales. The SEM images indicated that in shale reservoirs, interparticle pores at the edges of brittle particles and intraparticle pores in clay mineral aggregates primarily contribute to the reservoir spaces and that in calcite-rich shales, dissolution pores provide secondary reservoir space. Among the morphologies of dissolution, intraparticle, and interparticle pores, the morphology of the dissolution pores is the simplest, followed by those of intraparticle and interparticle pores in that order. Clay and felsic minerals primarily control the shale pore sizes and the larger the clay mineral content in the shales, the smaller their pore size; the felsic minerals demonstrate the opposite behavior. The image-based point counting data indicate that shale pore sizes are mostly between 20 nm and 2 μm. In contrast, most pore throats are less than 20 nm in diameter, implying that the pores in the nanometer to micrometer scales are connected by tiny throats. Among the four lithofacies shales, felsic-rich shales are favorable for shale oil accumulation and seepage because of their large pore sizes and throats their ability to form intercalated shale oil adjacent to organic-rich shales. Calcareous shales with a large number of dissolution pores and a large content of organic matter could produce self-generation and self-storage matrix shale oil and would typically develop fractures, thereby creating a seepage channel for shale oil. This study presents the micro-distributions of different lithofacies of shale pores, which would help in understanding the occurrence and seepage of oil in shale reservoirs.
Thermal Stability, Kinetic Analysis, and Safe Temperature Assessment of Ionic Liquids 1-Benzyl-3-Methylimidazolium Bis (Trifluoromethylsulfonyl) Imide for Emerging Building and Energy Related Field
Authors: Hung Li-Chi , Pan Nai-Hsin
Published: April 2023

Ionic liquids are molten salts that possess excellent chemical and thermal stability. Due to their inherent qualities in green chemistry, ionic liquids have been identified as potential substitutes for traditional organic solvents. These useful physical and chemical properties lead to some promising applications in fields such as building polymer engineering alternative materials and renewable energy technologies. Although they are classified as green solvents, these new solvents exist in a high-temperature environment, which is related to thermochemical reactivity and safety; there are few related studies. To analyze the possible high-temperature application environment of ionic liquids in the future, we analyzed the new ionic liquid 1-Benzyl-3-methylimidILlium bis (trifluoromethylsulfonyl) imide ([BZMIM][TF2N]), which lacks thermal analysis basis. This study used thermogravimetric analysis as the basis of the reaction model. We calculated the thermal hazard, kinetics, and parameter analysis of the reaction characterized by experimental thermal analysis data. The reaction model can be used to construct the actual temperature change calculation. The results show that [BZMIM][TF2N] will enter a runaway reaction when the temperature exceeds 270 °C. When operating [BZMIM][TF2N] at high temperatures, attention should be paid to the possibility of thermal hazards caused by its self-decomposition reaction.
Textural, Rheological, and Sensory Modifications in Oaxaca Cheese Made with Ultrasonicated Raw Milk
Authors: Carrillo-López Luis M. , Huerta-Jiménez Mariana , Morales-Rodríguez Simón , Gámez-Piñón Jesús R. , Carballo-Carballo Diego E. , Gutiérrez-Méndez Néstor , Alarcón-Rojo Alma D.
Published: April 2023

In this research, we evaluated the effects of different frequencies (25 and 45 kHz) and times (15 and 30 min) of high-intensity ultrasound (HIU) applied to fresh raw milk on the textural properties of Oaxaca cheese. When HIU was applied for 15 min, the cheese melting time was reduced by up to 23.4 s compared to the control. The cheeses produced with ultrasonicated milk at 45 kHz presented larger melting and exudate areas. They were softer, but consumer acceptability was lower. Frequencies of 25 and 45 kHz (15 or 30 min) reduced the temperature of the solid–liquid transition by 1.9–3.6 °C and 0.6–1.8 °C, respectively, compared to controls. Consequently, the melting time in ultrasonicated cheese was significantly reduced. The strands were perfectly aligned and well organized in the direction of stretching with 25 kHz ultrasonication. In addition, these cheeses were more consistent, chewy, and rubbery. Consequently, they were preferred and more accepted in flavor, aroma, and texture, with high general acceptability. HIU is a promising technology to improve the textural and rheological properties of Oaxaca cheese made with raw milk, as HIU produced cheeses with better sensory acceptability by consumers and with a high melting capacity and thread formation.
Reactor Temperature Control Based on Improved Fractional Order Self-Anti-Disturbance
Authors: Tang Xiaowei , Xu Bing , Xu Zichen
Published: April 2023

In the chemical industry, a reactor is an absolutely necessary container. The fact that its dynamic qualities are nonlinear and unknown, however, is what causes the temperature to deviate from the value that was specified. As a result, the typical PID control cannot fulfill the prerequisites of the production process. A new nonlinear function is presented to replace the function that was previously used, and a temperature controller that is based on better fractional order active disturbance rejection is devised. On the basis of a new fractional order temperature detector (FOTD), a new fractional order equilibrium state observer (FOESO), and nonlinear function, an improved fractional order active disturbance rejection controller has been developed. A model of the reactor was created, and the dynamic properties of temperature control were investigated. By simulation and experimentation, it was demonstrated that the strategy has a number of benefits and is effective. In this approach, the information provided by the model is exploited to its maximum potential, and the temperature of the inlet cooling water is employed as the temperature control disturbance for feedforward compensation. Over the entirety of the process, this guarantees that the desired temperature will be preserved. When compared to FADRC, PID, and ADRC, the rising time is increased by 5 s, and the overshoot is raised by 25%. It has been established that the fraction-order active disturbance rejection controller has a quicker response speed, a higher capacity for anti-interference, and a quicker speed of stabilization.
Extension of the Equilibrium Stage Model to Include Rigorous Liquid Holdup Calculations for Reactive Distillation
Authors: Noll Lionel , van der Ham Louis , Oudenhoven Stijn , ten Kate Antoon , Bargeman Gerrald , Kersten Sascha
Published: April 2023

An extension of the equilibrium stage model to improve its applicability to reactive distillation is presented. The significant aeration of the liquid holdup on trays leads to the amount of clear liquid present being significantly less than the volume available. Tray hydraulic correlations are incorporated by leveraging the existing inside-out algorithm to rigorously calculate the liquid holdup on distillation trays, turning this parameter into an additional model output and eliminating the need to estimate this parameter beforehand. Application of this extended model shows that the aeration of the liquid holdup cannot be neglected for systems where the reaction kinetics limit the reactive productivity, and leads to column designs where additional reactive trays are needed to provide adequate reactive capacity. The workflow of this model provides a more robust path to obtaining reactive distillation column and tray designs that comply with liquid holdup requirements and tray hydraulic limitations.
Islamophobia and Twitter: The Political Discourse of the Extreme Right in Spain and Its Impact on the Public
Authors: Olmos-Alcaraz Antonia
Published: April 2023

This paper analyzes the discourse concerning Islam and Muslims by assessing the extreme right-wing party, Vox, on Twitter. In addition, this paper examines the incidence (impact and reactions) of this party on the users of this social network. The objectives of this study are as follows: to identify themes and topics concerning this discourse; to analyze how the discourse is articulated and represented; and to understand the impact of this discourse by measuring the engagement of the most viral publications. To do so, we observed the publications posted by the party via its official account throughout 2022. The research methodology was based on qualitative and quantitative content analysis, and the publications themselves were monitored to ascertain the level of engagement. The results of this study clearly show that Vox created Islamophobic narratives; thus, Islam and Muslims are explicit targets of Vox’s hate speech. Their rhetoric referred to security threats and threats to national identity, with the recurrent use of the idea that there is a “danger of Islamization” in Spain. The party uses disinformation and hoaxes, and users respond in a polarized way. The results of this study alert us to the worrying levels of radicalization and the normalization of Islamophobic racist discourse in the examined context.
Exploring Motivations and Benefits of Volunteering: The Perspectives of High School Students in Selected Australian Islamic Schools
Authors: Alzaareer Ahmad , Abdalla Mohamad
Published: April 2023

Substantial research in educational and non-educational contexts demonstrates the importance and value of volunteering broadly and among young people specifically. However, there is no research that explores volunteering from the perspectives of students in Australian Islamic schools. To fill this gap, this paper explores the motivations for, and benefits of, volunteering from the perspectives of high school students in three Australian Islamic schools (AIS). The research utilised a phenomenological qualitative approach to explore the lived experience of these students vis-à-vis volunteering. Semi-structured interviews were conducted with 26 (13 male and 13 female) high school students (HSS) (year 10 to 12) at three AIS across three states. The findings demonstrate that students were motivated to volunteer because of intrinsic religious reasons, self-satisfaction and development, altruism, knowledge and skill-based enhancement, social motives, employment-based motives, and inspiring parents’ motive. The benefits include individual and societal development, enhanced involvement and belonging within mainstream society, and countering Islamophobia.
Garbage Care as a Way for Eco-Spiritual Care in a Multifaith Society in Indonesia
Authors: Binawan Andang
Published: April 2023

This article will explain how garbage care can be a way of realizing eco-spiritual care in the multifaith context of Indonesia. In Indonesia, the environment is a common concern, and waste is also a common problem. With a qualitative reflective method, the activities in garbage care are reflected in an eco-spiritual care perspective. Eco-spiritual care is an effort to assist human beings to find themselves in their environment. This reflection concludes that with a phenomenological approach, garbage care will make people find their ‘oneness’. This will underlie the renewal of attitudes toward their lives in a deeper, more positive way. In addition, this reflection on the eco-spiritual will broaden the understanding of pastoral care that has existed so far, because eco-spiritual care is not only for people who are sick, but those who want to find their natural selves. This also means that the meaning of eco-spiritual care is much broader than pastoral care because it means giving ‘good food’, not just shepherding and merely giving spiritual food. Indeed, it must be a good and healthy spiritual food to let people grow better spiritually.
Terrestrial Laser Scanning for Non-Destructive Estimation of Aboveground Biomass in Short-Rotation Poplar Coppices
Authors: Menéndez-Miguélez María , Madrigal Guillermo , Sixto Hortensia , Oliveira Nerea , Calama Rafael
Published: April 2023

Poplar plantations in high-density and short-rotation coppices (SRC) are a suitable way for the fast production of wood that can be transformed into bioproducts or bioenergy. Optimal management of these coppices requires accurate assessment of the total standing biomass. However, traditional field inventory is a challenging task, given the existence of multiple shoots, the difficulty of identifying terminal shoots, and the extreme high density. As an alternative, in this work, we propose to develop individual stool and plot biomass models using metrics derived from terrestrial laser scanning (TLS) as predictors. To this aim, we used data from a SRC poplar plantation, including nine plots and 154 individual stools. Every plot was scanned from different positions, and individual stools were felled, weighed, and dried to compute aboveground biomass (AGB). Individual stools were segmented from the cloud point, and different TLS metrics at stool and plot level were derived following processes of bounding box, slicing, and voxelization. These metrics were then used, either alone or combined with field-measured metrics, to fit biomass models. Our results indicate that at individual-stool level, the biomass models combining TLS metrics and easy to measure in field metrics (stool diameter) perform similarly to the traditional allometric models based on field inventories, while at plot scales, TLS-derived models show superiority over traditional models. Our proposed methodology permits accurate and non-destructive estimates of the biomass fixed in SRC plantations.
Decline of Late Spring and Summer Snow Cover in the Scottish Highlands from 1984 to 2022: A Landsat Time Series
Authors: Spracklen Benedict D. , Spracklen Dominick V.
Published: April 2023

Late spring and summer snow cover, the remnants of winter and early spring snowfall, not only possess an intrinsic importance for montane flora and fauna, but also act as a sensitive indicator for climate change. The variability and potential trends in late spring and summer (snowmelt season) snow cover in mountain regions are often poorly documented. May to mid-September Landsat imagery from 1984 to 2022 was used to quantify changes in the snow-covered area of upland regions in the Scottish Highlands. There was substantial annual variability in the area of May to mid-September snow cover combined with a significant decline over the 39-year study period (p = 0.02). Long-term climate data used to show variability in May to mid-September snow cover was positively related to winter snowfall and negatively related to winter and April temperatures. The results from a long-running field survey counting the number of snow patches that survive until the following winter were used to check the veracity of the study. Further, accuracy was estimated through comparison with higher resolution Sentinel-2 imagery, giving a user and producer accuracy rate of 99.8% and 87%, respectively. Projected future warming will further diminish this scarce, valuable habitat, along with its associated plant communities, thus threatening the biodiversity and scenic value of the Scottish Highlands.
A Novel Hybrid Intelligent SOPDEL Model with Comprehensive Data Preprocessing for Long-Time-Series Climate Prediction
Authors: Zhou Zeyu , Tang Wei , Li Mingyang , Cao Wen , Yuan Zhijie
Published: April 2023

Long-time-series climate prediction is of great significance for mitigating disasters; promoting ecological civilization; identifying climate change patterns and preventing floods, drought and typhoons. However, the general public often struggles with the complexity and extensive temporal range of meteorological data when attempting to accurately forecast climate extremes. Sequence disorder, weak robustness, low characteristics and weak interpretability are four prevalent shortcomings in predicting long-time-series data. In order to resolve these deficiencies, our study gives a novel hybrid spatiotemporal model which offers comprehensive data preprocessing techniques, focusing on data decomposition, feature extraction and dimensionality upgrading. This model provides a feasible solution to the puzzling problem of long-term climate prediction. Firstly, we put forward a Period Division Region Segmentation Property Extraction (PD-RS-PE) approach, which divides the data into a stationary series (SS) for an Extreme Learning Machine (ELM) prediction and an oscillatory series (OS) for a Long Short-term Memory (LSTM) prediction to accommodate the changing trend of data sequences. Secondly, a new type of input-output mapping mode in a three-dimensional matrix was constructed to enhance the robustness of the prediction. Thirdly, we implemented a multi-layer technique to extract features of high-speed input data based on a Deep Belief Network (DBN) and Particle Swarm Optimization (PSO) for parameter searching of a neural network, thereby enhancing the overall system’s learning ability. Consequently, by integrating all the above innovative technologies, a novel hybrid SS-OS-PSO-DBN-ELM-LSTME (SOPDEL) model with comprehensive data preprocessing was established to improve the quality of long-time-series forecasting. Five models featuring partial enhancements are discussed in this paper and three state-of-the-art classical models were utilized for comparative experiments. The results demonstrated that the majority of evaluation indices exhibit a significant optimization in the proposed model. Additionally, a relevant evaluation system showed that the quality of “Excellent Prediction” and “Good Prediction” exceeds 90%, and no data with “Bad Prediction” appear, so the accuracy of the prediction process is obviously insured.