bluuebunny/crossref_metadata_2025 huggingface dataset:
Revealing the Nature of Chemical Bonding in an ALn2Ag3Te5-Type Alkaline-Metal (A) Lanthanide (Ln) Silver Telluride
Authors: Göbgen Kai C. , Fries Kai S. , Gladisch Fabian C. , Dronskowski Richard , Steinberg Simon
Published: May 2019

Although the electronic structures of several tellurides have been recognized by applying the Zintl-Klemm concept, there are also tellurides whose electronic structures cannot be understood by applications of the aforementioned idea. To probe the appropriateness of the valence-electron transfers as implied by Zintl-Klemm treatments of ALn2Ag3Te5-type tellurides (A = alkaline-metal; Ln = lanthanide), the electronic structure and, furthermore, the bonding situation was prototypically explored for RbPr2Ag3Te5. The crystal structure of that type of telluride is discussed for the examples of RbLn2Ag3Te5 (Ln = Pr, Nd), and it is composed of tunnels which are assembled by the tellurium atoms and enclose the rubidium, lanthanide, and silver atoms, respectively. Even though a Zintl-Klemm treatment of RbPr2Ag3Te5 results in an (electron-precise) valence-electron distribution of (Rb+)(Pr3+)2(Ag+)3(Te2−)5, the bonding analysis based on quantum-chemical means indicates that a full electron transfer as suggested by the Zintl-Klemm approach should be considered with concern.
Nutritional Laboratory Markers in Malnutrition
Authors: Keller Ulrich
Published: May 2019

Serum visceral proteins such as albumin and prealbumin have traditionally been used as markers of the nutritional status of patients. Prealbumin is nowadays often preferred over albumin due to its shorter half live, reflecting more rapid changes of the nutritional state. However, recent focus has been on an appropriate nutrition-focused physical examination and on the patient’s history for diagnosing malnutrition, and the role of inflammation as a risk factor for malnutrition has been more and more recognized. Inflammatory signals are potent inhibitors of visceral protein synthesis, and the use of these proteins as biomarkers of the nutritional status has been debated since they are strongly influenced by inflammation and less so by protein energy stores. The current consensus is that laboratory markers could be used as a complement to a thorough physical examination. Other markers of the nutritional status such as urinary creatinine or 3-methylhistidine as indicators of muscle protein breakdown have not found widespread use. Serum IGF-1 is less influenced by inflammation and falls during malnutrition. However, its concentration changes are not sufficiently specific to be useful clinically as a marker of malnutrition, and serum IGF-1 has less been used in clinical trials. Nevertheless, biomarkers of malnutrition such as prealbumin may be of interest as easily measurable predictors of the prognosis for surgical outcomes and of mortality in severe illnesses.
Post-Weld Heat Treatment Effects on Mechanical Properties and Microstructure of AA6061-T6 Butt Joints Made by Friction Stir Welding at Right Angle (RAFSW)
Authors: Momeni Mahboubeh , Guillot Michel
Published: May 2019

Friction stir welding (FSW) provides users with many advantages over fusion welding techniques. Nevertheless, it is not widely employed in current industry mainly due to high equipment costs and royalties. To overcome these issues, a low-cost FSW technique operated at a right angle, called RAFSW, has recently been developed by our research team. To make the RAFSW technique reliable for potential users, we are going to analyze the effect of various post-weld heat treatments (PWHT) on the mechanical and physical properties of the RAFSW joints. To this end, optimized process parameters are used to weld butt joints of an AA6061-T6 alloy. The joints were characterized using a tensile test, a micro-hardness test, and metallography techniques. The most efficient aging time was obtained for various aging temperatures. Moreover, it was found that artificial aging at 220 °C for 30 min could be used as a fast and cost-effective artificial aging PWHT for the industrial sector. In addition, the repeatability of the PWHTs were demonstrated by studying the effect of waiting time prior to the artificial aging. Finally, it was revealed that a single fast artificial aging process is more beneficial than solubilizing followed by an artificial aging process in terms of tensile properties, consumed time, and cost.
Is Bitcoin a Relevant Predictor of Standard & Poor’s 500?
Authors: Muglia Camilla , Santabarbara Luca , Grassi Stefano
Published: May 2019

The paper investigates whether Bitcoin is a good predictor of the Standard & Poor’s 500 Index. To answer this question we compare alternative models using a point and density forecast relying on Dynamic Model Averaging (DMA) and Dynamic Model Selection (DMS). According to our results, Bitcoin does not show any direct impact on the predictability of Standard & Poor’s 500 for the considered sample.
Modelling Cyclic Behaviour of Martensitic Steel with J2 Plasticity and Crystal Plasticity
Authors: Sajjad Hafiz Muhammad , Hanke Stefanie , Güler Sedat , ul Hassan Hamad , Fischer Alfons , Hartmaier Alexander
Published: May 2019

In order to capture the stress-strain response of metallic materials under cyclic loading, it is necessary to consider the cyclic hardening behaviour in the constitutive model. Among different cyclic hardening approaches available in the literature, the Chaboche model proves to be very efficient and convenient to model the kinematic hardening and ratcheting behaviour of materials observed during cyclic loading. The purpose of this study is to determine the material parameters of the Chaboche kinematic hardening material model by using isotropic J2 plasticity and micromechanical crystal plasticity (CP) models as constitutive rules in finite element modelling. As model material, we chose a martensitic steel with a very fine microstructure. Thus, it is possible to compare the quality of description between the simpler J2 plasticity and more complex micromechanical material models. The quality of the results is rated based on the quantitative comparison between experimental and numerical stress-strain hysteresis curves for a rather wide range of loading amplitudes. It is seen that the ratcheting effect is captured well by both approaches. Furthermore, the results show that concerning macroscopic properties, J2 plasticity and CP are equally suited to describe cyclic plasticity. However, J2 plasticity is computationally less expensive whereas CP finite element analysis provides insight into local stresses and plastic strains on the microstructural length scale. With this study, we show that a consistent material description on the microstructural and the macroscopic scale is possible, which will enable future scale-bridging applications, by combining both constitutive rules within one single finite element model.
Sorption of Selected Heavy Metals with Different Relative Concentrations in Industrial Effluent on Biochar from Human Faecal Products and Pine-Bark
Authors: Koetlisi Koetlisi Andreas , Muchaonyerwa Pardon
Published: May 2019

The removal of heavy metals from effluents at source could reduce contamination of soil and water bodies. A batch sorption experiment was performed to determine the effects of feedstock of biochars pyrolysed at increasing temperature on sorption capacities of Cu, Cr and Zn from industrial effluent and aqueous solutions. Sewage sludge, latrine faecal waste and pine-bark biochars were used. The sorption data were fitted to the Langmuir isotherm. Maximum sorption capacities of latrine waste, sewage sludge and pine-bark biochar (350 °C) were, respectively, 313, 400 and 233 mg kg−1 for Zn, 102, 98.0 and 33.3 mg kg−1 for Cu, and 18.9, 13.8 and 67.1 mg kg−1 for Cr from industrial effluent. Conversely, sorption capacities from single metal solutions were 278, 227 and 104 mg Zn kg−1, 97.1, 137 and 21.3 mg Cu kg−1, 122, 106 and 147 mg Cr kg−1 on latrine waste, sewage sludge and pine-bark biochar, respectively. Step-wise regression analysis showed that the combined effects of ash, fixed C, pH influenced Zn sorption, ash and fixed C affected Cu sorption, and Cr sorption by ash and specific surface area of the biochar. The findings of the study imply that biochar from human faecal waste, particularly sewage sludge, has the potential to be utilized as sorbents of heavy metals from multiple metal effluent and that the sorption is affected by relative concentrations.
Recent Progress on Organic Electrodes Materials for Rechargeable Batteries and Supercapacitors
Authors: Mauger Alain , Julien Christian , Paolella Andrea , Armand Michel , Zaghib Karim
Published: May 2019

Rechargeable batteries are essential elements for many applications, ranging from portable use up to electric vehicles. Among them, lithium-ion batteries have taken an increasing importance in the day life. However, they suffer of several limitations: safety concerns and risks of thermal runaway, cost, and high carbon footprint, starting with the extraction of the transition metals in ores with low metal content. These limitations were the motivation for an intensive research to replace the inorganic electrodes by organic electrodes. Subsequently, the disadvantages that are mentioned above are overcome, but are replaced by new ones, including the solubility of the organic molecules in the electrolytes and lower operational voltage. However, recent progress has been made. The lower voltage, even though it is partly compensated by a larger capacity density, may preclude the use of organic electrodes for electric vehicles, but the very long cycling lives and the fast kinetics reached recently suggest their use in grid storage and regulation, and possibly in hybrid electric vehicles (HEVs). The purpose of this work is to review the different results and strategies that are currently being used to obtain organic electrodes that make them competitive with lithium-ion batteries for such applications.
Mineralogical and Microstructural Characteristics of Two Dental Pulp Capping Materials
Authors: Voicu Georgeta , Didilescu Andreea C. , Stoian Andrei B. , Dumitriu Cristina , Greabu Maria , Andrei Mihai
Published: May 2019

This paper aims to investigate the composition, surface, and microstructural characteristics, and bioactivity of two commercially available pulp capping materials known as TheraCal LC and BIO MTA+. The materials were prepared as cylindrical samples and assessed by X-ray diffraction (XRD) and complex thermal analysis for mineralogical characterization, and by scanning electron microscopy (SEM) coupled with energy dispersive of X-ray (EDX), Fourier-Transformed Infrared Spectroscopy (FT-IR), and atomic force microscopy (AFM) for microstructural and surface characteristics. The in vitro bioactivity was highlighted by surface mineralization throughout SEM coupled with EDX and FT-IR analysis. XRD analysis performed on both materials showed calcium silicate phases and different radiopacifying compounds. AFM measurements indicated a smoother and more homogenous surface with a lower average roughness for TheraCal LC due to the resin matrix from its composition. FT-IR analysis displayed bands for several compounds in both materials. Both materials exhibited bioactive properties showing surface mineralization after being immersed in solution similar to the human physiological environment. However, the MTA cement showed a better mineralization due to the anhydrous and hydrated phases.
Influence of Nature Support on Methane and CO2 Conversion in a Dry Reforming Reaction over Nickel-Supported Catalysts
Authors: Fakeeha Anis Hamza , Kasim Samsudeen Olajide , Ibrahim Ahmed Aidid , Abasaeed Ahmed Elhag , Al-Fatesh Ahmed Sadeq
Published: May 2019

A promising method to reduce global warming has been methane reforming with CO2, as it combines two greenhouse gases to obtain useful products. In this study, Ni-supported catalysts were synthesized using the wet impregnation method to obtain 5%Ni/Al2O3(SA-5239), 5%Ni/Al2O3(SA-6175), 5%Ni/SiO2, 5%Ni/MCM41, and 5%Ni/SBA15. The catalysts were tested in dry reforming of methane at 700 °C, 1 atm, and a space velocity of 39,000 mL/gcat h, to study the interaction of Ni with the supports, and evaluation was based on CH4 and CO2 conversions. 5%Ni/Al2O3(SA-6175) and 5%Ni/SiO2 gave the highest conversion of CH4 (78 and 75%, respectively) and CO2 (84 and 82%, respectively). The catalysts were characterized by some techniques. Ni phases were identified by X-ray diffraction patterns. Brunauer–Emmett–Teller analysis showed different surface areas of the catalysts with the least being 4 m2/g and the highest 668 m2/g belonging to 5%Ni/Al2O3(SA-5239) and 5%Ni/SBA15, respectively. The reduction profiles revealed weak NiO-supports interaction for 5%Ni/Al2O3(SA-5239), 5%Ni/MCM41, and 5%Ni/SBA15; while strong interaction was observed in 5%Ni/Al2O3(SA-6175) and 5%Ni/SiO2. The 5%Ni/Al2O3(SA-6175) and 5%Ni/SiO2 were close with respect to performance; however, the former had a higher amount of carbon deposit, which is mostly graphitic, according to the conducted thermal analysis. Carbon deposits on 5%Ni/SiO2 were mainly atomic in nature.
Effects of Silicone Oil Viscosity and Carbonyl Iron Particle Weight Fraction and Size on Yield Stress for Magnetorheological Grease Based on a New Preparation Technique
Authors: Wang Kejie , Dong Xiaomin , Li Junli , Shi Kaiyuan , Li Keju
Published: May 2019

This paper investigated the effects of silicone oil viscosity (SOV) and carbonyl iron particle (CIP) weight fraction and size on dynamic yield stress for magnetorheological (MR) grease. The MR grease samples were prepared using orthogonal array L9 on the basis of a new preparation technology. The shear rheological tests were undertaken using a rotational shear rheometer and yield stress was obtained based on the Bingham fluid model. It was found that CIP fractions ranging from 65 wt% to 75 wt% and SOV varying from 50 m2·s−1 to 1000 m2·s−1 significantly affect the magnetic field-dependent yield stress of MR grease, but the CIPs with sizes of 3.2–3.9 μm hardly had any influence based on the analysis of variance (ANOVA). In addition, the yield stress of MR grease mainly depended on the CIP fraction and SOV by comparing their percent contribution (PC). It was further confirmed that there were positive effects of CIP fraction and SOV on yield stress through response surface analysis (RSA). The results showed a high dynamic yield stress. It indicated that MR grease is an intelligent material candidate which can be applied to many different areas requiring high field-induced rheological capabilities without flow for suspension. Moreover, based upon the multivariate regression equation, a constitutive model was developed to express the function of the yield stress as the SOV and fraction of CIPs under the application of magnetic fields.
New Naphtho-γ-Pyrones Isolated from Marine-Derived Fungus Penicillium sp. HK1-22 and Their Antimicrobial Activities
Authors: Zheng Yao-Yao , Liang Zhao-Yang , Shen Nan-Xing , Liu Wen-Long , Zhou Xiao-Jian , Fu Xiu-Mei , Chen Min , Wang Chang-Yun
Published: May 2019

Three novel monomeric naphtho-γ-pyrones, peninaphones A–C (compounds 1–3), along with two known bis-naphtho-γ-pyrones (compounds 4 and 5) were isolated from mangrove rhizosphere soil-derived fungus Penicillium sp. HK1-22. The absolute configurations of compounds 1 and 2 were determined by electronic circular dichroism (ECD) spectra, and the structure of compound 3 was confirmed by single-crystal X-ray diffraction analysis. Compounds 4 and 5 are a pair of hindered rotation isomers. A hypothetical biosynthetic pathway for the isolated monomeric and dimeric naphtho-γ-pyrones is also discussed in this study. Compounds 1–3 showed antibacterial activity against Staphylococcus aureus (ATCC 43300, 33591, 29213, and 25923) with minimum inhibitory concentration (MIC) values in the range of 12.5–50 μg/mL. Compound 3 exhibited significant activity against the rice sheath blight pathogen Rhizoctonia solani.
Influence of Deep Cryogenic Treatment on Microstructure and Properties of 7A99 Ultra-High Strength Aluminum Alloy
Authors: Gao Wenlin , Wang Xiangjie , Chen Junzhou , Ban Chunyan , Cui Jianzhong , Lu Zheng
Published: May 2019

The hardness, toughness, wear resistance, and fatigue behavior of materials can be improved through a deep cryogenic treatment (DCT). During this treatment, low temperatures (−100 °C to −196 °C) are maintained and then increased to room or higher. In this work, an indirect-extrusion plate of 7A99 ultra-high strength aluminum alloy was subjected to a T6 (peak aging) treatment and a T6-DCT treatment. The influence of the T6-DCT treatment on the mechanical properties, grain morphologies, precipitates, and atom–cluster distribution was investigated via tensile testing, electron backscatter diffraction, transmission electron microscopy, and three-dimensional atom probe analysis. The tensile strength (maximum: 705 deep cryogenic treatment), yield strength (maximum: 678 MPa), and elongation (maximum: 14%) of the T6-DCT-treated alloy were higher than those of the T6-treated alloy. Moreover, the T6-DCT treatment resulted in (i) grain size refinement and increased uniformity of the microstructure (homogeneous distribution of η’-MgZn2- and η-phase precipitates), and (ii) reduced segregation degree of Zn, Mg, and Cu atoms in the matrix (fraction of small atom clusters (sizes: 10–20 nm, 20–50 nm) increased, fraction of large clusters (size: >1,000 nm) decreased). Therefore, DCT can refine the precipitates and increase the uniformity of the precipitate distribution, thereby improving the strength and plasticity of the alloy.
An Integrated Germanium-Based THz Impulse Radiator with an Optical Waveguide Coupled Photoconductive Switch in Silicon
Authors: Chen Peiyu , Hosseini Mostafa , Babakhani Aydin
Published: May 2019

This paper presents an integrated germanium (Ge)-based THz impulse radiator with an optical waveguide coupled photoconductive switch in a low-cost silicon-on-insulator (SOI) process. This process provides a Ge thin film, which is used as photoconductive material. To generate short THz impulses, N++ implant is added to the Ge thin film to reduce its photo-carrier lifetime to sub-picosecond for faster transient response. A bow-tie antenna is designed and connected to the photoconductive switch for radiation. To improve radiation efficiency, a silicon lens is attached to the substrate-side of the chip. This design features an optical-waveguide-enabled “horizontal” coupling mechanism between the optical excitation signal and the photoconductive switch. The THz emitter prototype works with 1550 nm femtosecond lasers. The radiated THz impulses achieve a full-width at half maximum (FWHM) of 1.14 ps and a bandwidth of 1.5 THz. The average radiated power is 0.337 μ W. Compared with conventional THz photoconductive antennas (PCAs), this design exhibits several advantages: First, it uses silicon-based technology, which reduces the fabrication cost; second, the excitation wavelength is 1550 nm, at which various low-cost laser sources operate; and third, in this design, the monolithic excitation mechanism between the excitation laser and the photoconductive switch enables on-chip programmable control of excitation signals for THz beam-steering.
New Logic-In-Memory Paradigms: An Architectural and Technological Perspective
Authors: Santoro Giulia , Turvani Giovanna , Graziano Mariagrazia
Published: May 2019

Processing systems are in continuous evolution thanks to the constant technological advancement and architectural progress. Over the years, computing systems have become more and more powerful, providing support for applications, such as Machine Learning, that require high computational power. However, the growing complexity of modern computing units and applications has had a strong impact on power consumption. In addition, the memory plays a key role on the overall power consumption of the system, especially when considering data-intensive applications. These applications, in fact, require a lot of data movement between the memory and the computing unit. The consequence is twofold: Memory accesses are expensive in terms of energy and a lot of time is wasted in accessing the memory, rather than processing, because of the performance gap that exists between memories and processing units. This gap is known as the memory wall or the von Neumann bottleneck and is due to the different rate of progress between complementary metal–oxide semiconductor (CMOS) technology and memories. However, CMOS scaling is also reaching a limit where it would not be possible to make further progress. This work addresses all these problems from an architectural and technological point of view by: (1) Proposing a novel Configurable Logic-in-Memory Architecture that exploits the in-memory computing paradigm to reduce the memory wall problem while also providing high performance thanks to its flexibility and parallelism; (2) exploring a non-CMOS technology as possible candidate technology for the Logic-in-Memory paradigm.
Towards Laterally Resolved Ferromagnetic Resonance with Spin-Polarized Scanning Tunneling Microscopy
Authors: Hervé Marie , Peter Moritz , Balashov Timofey , Wulfhekel Wulf
Published: May 2019

We used a homodyne detection to investigate the gyration of magnetic vortex cores in Fe islands on W(110) with spin-polarized scanning tunneling microscopy at liquid helium temperatures. The technique aims at local detection of the spin precession as a function of frequency using a radio-frequency (rf) modulation of the tunneling bias voltage. The gyration was excited by the resulting spin-polarized rf current in the tunneling junction. A theoretical analysis of different contributions to the frequency-dependent signals expected in this technique is given. These include, besides the ferromagnetic resonance signal, also signals caused by the non-linearity of the I ( U ) characteristics. The vortex gyration was modeled with micromagnetic finite element methods using realistic parameters for the tunneling current, its spin polarization, and the island shape, and simulations were compared with the experimental results. The observed signals are presented and critically analyzed.
Fabrication of Various Plasmonic Pt Nanostructures via Indium Assisted Solid-State Dewetting: From Small Nanoparticles to Widely Connected Networks
Authors: Pandit Sanchaya , Sui Mao , Kunwar Sundar , Pandey Puran , Pant Sandesh , Lee Jihoon
Published: May 2019

In this paper, the modified solid-state dewetting (MSSD) of well-defined and various uniform Pt nanostructures is demonstrated by the auxiliary diffusion enhancement. The MSSD utilizes the introduction of metallic indium (In) layers with high diffusivity in between sapphire and platinum (Pt) layer, through which the global diffusion and dewetting of metallic atoms can be significantly enhanced. Subsequently, the In atoms can be sublimated from the NP matrix, resulting in the formation of pure Pt NPs. By the systematic control of In and Pt bi-layer thickness, various areal density, size and configuration of Pt NPs are demonstrated. The In2 nm/Pt2 nm bilayers establish very small and highly dense NPs throughout the temperature range due to the early maturation of growth. Intermediate size of NPs is demonstrated with the In45 nm/Pt15 nm bilayers with the much improved interparticle spacings by annealing between 650 and 900 °C for 450 s. Finally, the In30 nm/Pt30 nm bilayers demonstrate the widely connected network-like nanostructures. In addition, the finite difference time domain (FDTD) simulation is employed to exploit the local electric field distributions at resonance wavelengths. The dewetting characteristics of In/Pt bilayers is systematically controlled by the modifications of layer thickness and annealing temperature and is systematically described based on the diffusion of atoms, Rayleigh instability and surface energy minimization mechanism. The optical properties demonstrate dynamic and widely tunable localized surface plasmon resonance (LSPR) responses depending upon the various surface morphologies of Pt nanostructures.
Facile Synthesis and Optical Properties of CsPbX3/ZIF-8 Composites for Wide-Color-Gamut Display
Authors: Mei Shiliang , Yang Bobo , Wei Xian , Dai Hanqing , Chen Zhihao , Cui Zhongjie , Zhang Guilin , Xie Fengxian , Zhang Wanlu , Guo Ruiqian
Published: May 2019

All-inorganic CsPbX3 (X = Cl, Br, and I) perovskite quantum dots (QDs), an emerging type of luminescent materials, have drawn extensive attention in recent years. However, the amelioration of their stability is becoming a critical issue. Herein, we present a facile and efficient approach to prepare novel perovskite QDs/metal–organic frameworks (CsPbX3/ZIF-8) composites under ambient-atmospheric conditions. The obtained composites exhibit better properties including high photoluminescence (PL) quantum yields (QYs) (41.2% for green and 34.8% for red), narrow-band emission (20 nm for green and 31 nm for red), and enhanced stability in comparison to bare QDs. Furthermore, their application in a remote-type white-light-emitting device was explored and a wide color gamut (~137% of the National Television System Committee standard) was achieved, verifying that these novel luminescent composites have great prospect in backlight display application.
Mung Bean (Vigna radiata L.): Bioactive Polyphenols, Polysaccharides, Peptides, and Health Benefits
Authors: Hou Dianzhi , Yousaf Laraib , Xue Yong , Hu Jinrong , Wu Jihong , Hu Xiaosong , Feng Naihong , Shen Qun
Published: May 2019

Mung bean (Vigna radiata L.) is an important pulse consumed all over the world, especially in Asian countries, and has a long history of usage as traditional medicine. It has been known to be an excellent source of protein, dietary fiber, minerals, vitamins, and significant amounts of bioactive compounds, including polyphenols, polysaccharides, and peptides, therefore, becoming a popular functional food in promoting good health. The mung bean has been documented to ameliorate hyperglycemia, hyperlipemia, and hypertension, and prevent cancer and melanogenesis, as well as possess hepatoprotective and immunomodulatory activities. These health benefits derive primarily from the concentration and properties of those active compounds present in the mung bean. Vitexin and isovitexin are identified as the major polyphenols, and peptides containing hydrophobic amino acid residues with small molecular weight show higher bioactivity in the mung bean. Considering the recent surge in interest in the use of grain legumes, we hope this review will provide a blueprint to better utilize the mung bean in food products to improve human nutrition and further encourage advancement in this field.
Bone Health, Body Composition, and Vitamin D Status of Black Preadolescent Children in South Africa
Authors: White Zelda , White Samantha , Dalvie Tasneem , Kruger Marlena C. , Van Zyl Amanda , Becker Piet
Published: May 2019

Optimal bone health is important in children to reduce the risk of osteoporosis later in life. Both body composition and vitamin D play an important role in bone health. This study aimed to describe bone health, body composition, and vitamin D status, and the relationship between these among a group of conveniently sampled black preadolescent South African children (n = 84) using a cross-sectional study. Body composition, bone mineral density (BMD), and bone mineral content (BMC) were assessed using dual x-ray absorptiometry. Levels of 25-hydroxyvitamin D (25(OH)D) (n = 59) were assessed using dried blood spots. A quarter (25%) of children presented with low bone mass density for their chronological age (BMD Z-score < −2) and 7% with low BMC-for-age (BMC Z-score < −2), while only 34% of the children had sufficient vitamin D status (25(OH)D ≥ 30 ng/mL). Lean mass was the greatest body compositional determinant for variances observed in bone health measures. Body composition and bone health parameters were not significantly different across vitamin D status groups (p > 0.05), except for lumbar spine bone mineral apparent density (LS-BMAD) (p < 0.01). No association was found between bone parameters at all sites and levels of 25(OH)D (p > 0.05). Further research, using larger representative samples of South African children including all race groups is needed before any conclusions and subsequent recommendation among this population group can be made.
The Relationship between Whole Grain Intake and Body Weight: Results of Meta-Analyses of Observational Studies and Randomized Controlled Trials
Authors: Maki Kevin C. , Palacios Orsolya M. , Koecher Katie , Sawicki Caleigh M. , Livingston Kara A. , Bell Marjorie , Nelson Cortes Heather , McKeown Nicola M.
Published: May 2019

Results from some observational studies suggest that higher whole grain (WG) intake is associated with lower risk of weight gain. Ovid Medline was used to conduct a literature search for observational studies and randomized controlled trials (RCTs) assessing WG food intake and weight status in adults. A meta-regression analysis of cross-sectional data from 12 observational studies (136,834 subjects) and a meta-analysis of nine RCTs (973 subjects) was conducted; six prospective cohort publications were qualitatively reviewed. Cross-sectional data meta-regression results indicate a significant, inverse correlation between WG intake and body mass index (BMI): weighted slope, −0.0141 kg/m2 per g/day of WG intake (95% confidence interval (CI): −0.0207, −0.0077; r = −0.526, p = 0.0001). Prospective cohort results generally showed inverse associations between WG intake and weight change with typical follow-up periods of five to 20 years. RCT meta-analysis results show a nonsignificant pooled standardized effect size of −0.049 kg (95% CI −0.297, 0.199, p = 0.698) for mean difference in weight change (WG versus control interventions). Higher WG intake is significantly inversely associated with BMI in observational studies but not RCTs up to 16 weeks in length; RCTs with longer intervention periods are warranted.
Adiposity Mediates the Association between the Dietary Inflammatory Index and Markers of Type 2 Diabetes Risk in Middle-Aged Black South African Women
Authors: Mtintsilana Asanda , Micklesfield Lisa K. , Chorell Elin , Olsson Tommy , Shivappa Nitin , Hebert James R , Kengne Andre P. , Goedecke Julia H.
Published: May 2019

The dietary inflammatory index (DII®), a validated tool used to measure the inflammatory potential of the diet, has been associated with metabolic disorders in various settings, but not in African populations. The aim of this study was to investigate whether the DII is associated with markers of type 2 diabetes (T2D) risk, and if this association is mediated by adiposity and/or low-grade inflammation, in black South Africa women. Energy-adjusted-DII (E-DII) scores were calculated in 190 women (median age, 53 years) from the Birth-to-Twenty plus cohort using a validated food frequency questionnaire. Fasting glucose, insulin, HbA1c, and inflammatory cytokines were measured, and an oral glucose tolerance test performed. Basic anthropometry and dual-energy x-ray absorptiometry-derived body fat, including estimate of visceral adipose tissue (VAT) area, were measured. E-DII scores were associated with all markers of T2D risk, namely, fasting glucose and insulin, HbA1c, HOMA2-IR, two-hour glucose and Matsuda index (all p < 0.05). After adjusting for age, measures of adiposity, but not inflammatory cytokines, mediated the association between E-DII and markers of T2D risk (p < 0.05). Measures of central obesity had proportionally higher (range: 23.5–100%) mediation effects than total obesity (range: 10–60%). The E-DII is associated with T2D risk through obesity, in particular central obesity, among black middle-aged South African women.
Ultrasound Muscle Assessment and Nutritional Status in Institutionalized Older Adults: A Pilot Study
Authors: Mateos-Angulo Alvaro , Galán-Mercant Alejandro , Cuesta-Vargas Antonio Ignacio
Published: May 2019

Muscle thickness, measured by ultrasonography, has been investigated for nutritional assessment in older adults, however the associations between muscle ultrasound parameters in the lower limb and nutritional status have not been studied. The aim of this study was to investigate the relationship between muscle thickness echo intensity (EI), and nutritional status in home care residents. A cross sectional study was conducted involving 19 older adults from a home care in Malaga (Spain). We evaluated lower leg muscles by ultrasound, anthropometric data, physical function (measured by gait speed and the Short Physical Performance Battery), strength (handgrip and knee extensors strength) and nutritional status across the Mini-Nutritional Assessment Short-Form (MNA-SF). We found that muscle thickness assessed by ultrasonography independently predicts nutritional status by MNA-SF and after adjusting for handgrip strength or age and sex. As secondary findings, we found relations between strength, functional capacity and the MNA-SF test. These results suggest that lower leg muscle ultrasound parameters could be used as a low-cost objective method for muscle evaluation in nutritional assessment in older adults.
Dietary Patterns and Their Association with Anxiety Symptoms among Older Adults: The ATTICA Study
Authors: F. Masana Maria , Tyrovolas Stefanos , Kollia Natasa , Chrysohoou Christina , Skoumas John , Haro Josep Maria , Tousoulis Dimitrios , Papageorgiou Charalambos , Pitsavos Christos , B. Panagiotakos Demosthenes
Published: May 2019

By 2050, the global population aged 60 years and over is expected to reach nearly 2.1 billion and affective disorders might be also expected to increase. Although nutrition has been related with affective disorders, there is a lack of studies assessing the relation between dietary habits and anxiety among European and Mediterranean older populations. In the present study, we aimed to evaluate the association between dietary habits, energy intake, and anxiety symptoms using data from 1128 Greek older adults (>50 years) without pre-existing cardiovascular disease (CVD) or any other chronic disease who participated in the ATTICA study. Various socio demographic lifestyle, bio-clinical (e.g., blood pressure), and psychological (e.g., depression) characteristics were used, and dietary habits as well as energy intake were calculated using standard procedures. Older people with anxiety were more likely to be sedentary, to be smokers, and to show symptoms of depression. The saturated fat and added sugars (SFAS) dietary pattern was associated with higher anxiety levels (non-standardized b (95% CI): 5.82 (0.03 to 11.61)). No association between energy intake tertiles and anxiety levels pictured in the later regression model. Moreover, female gender, family status, and depression were positively related to anxiety. Therefore, promoting healthy dietary habits could reduce anxiety symptoms of the older adults.
A Self-Adhesive Elastomeric Wound Scaffold for Sensitive Adhesion to Tissue
Authors: Boyadzhieva Silviya , Sorg Katharina , Danner Martin , Fischer Sarah C. L. , Hensel René , Schick Bernhard , Wenzel Gentiana , Arzt Eduard , Kruttwig Klaus
Published: May 2019

Pressure sensitive adhesives based on silicone materials are used particularly for skin adhesion, e.g., the fixation of electrocardiogram (ECG) electrodes or wound dressings. However, adhesion to sensitive tissue structures is not sufficiently addressed due to the risk of damage or rupture. We propose an approach in which a poly-(dimethylsiloxane) (PDMS)-based soft skin adhesive (SSA) acts as cellular scaffold for wound healing. Due to the intrinsically low surface free energy of silicone elastomers, functionalization strategies are needed to promote the attachment and spreading of eukaryotic cells. In the present work, the effect of physical adsorption of three different proteins on the adhesive properties of the soft skin adhesive was investigated. Fibronectin adsorption slightly affects adhesion but significantly improves the cellular interaction of L929 murine fibroblasts with the polymeric surface. Composite films were successfully attached to explanted tympanic membranes. This demonstrates the potential of protein functionalized SSA to act as an adhesive scaffold in delicate biomedical applications.
Reducing off-Flavour in Commercially Available Polyhydroxyalkanoate Materials by Autooxidation through Compounding with Organoclays
Authors: García-Quiles Lidia , Valdés Arantzazu , Cuello Ángel Fernández , Jiménez Alfonso , Garrigós María del Carmen , Castell Pere
Published: May 2019

Polyhydroxyalkanoates (PHAs) are nowadays considered competent candidates to replace traditional plastics in several market sectors. However, commercial PHA materials exhibit unsatisfactory smells that can negatively affect the quality of the final product. The cause of this typical rancid odour is attributed to oxidized cell membrane glycolipids, coming from Gram-negative production strains, which remain frequently attached to PHAs granules after the extraction stage. The aim of this research is the development of customised PHA bio-nano-composites for industrial applications containing organomodified nanoclays with high adsorbance properties able to capture volatile compounds responsible for the displeasing fragrance. To this end, a methodology for the detection and identification of the key volatiles released due to oxidative degradation of PHAs has been established using a headspace solid-phase microextraction technique. We report the development of nine bio-nano-composite materials based on three types of commercial PHA matrices loaded with three species of nanoclays which represent a different polar behaviour. It has been demonstrated that although the reached outcoming effect depends on the volatile nature, natural sepiolite might result in the most versatile candidate for any the PHA matrices selected.
Editorial for Special Issue: Neuroproteomics
Authors: Williams Kenneth R. , Nairn Angus C.
Published: May 2019

Recent advances in mass spectrometry (MS) instrumentation [...]
Memories of the Gate: On the Rhetoric in The Pilgrim’s Progress and Its Chinese Versions
Authors: Chu Xiaobai
Published: May 2019

The Pilgrim’s Progress was one of the most popular translated novels in China from the late 19th until the 20th century. In this paper, I argue that one of the main reasons for the book’s success in China lies in an intricate rhetoric of the original version, which focuses on the memories of the Gate, and in the skillful transformation of this rhetoric into the Chinese versions. By analyzing this rhetoric and its transformation, this paper shows how The Pilgrim’s Progress marked the cultural memories of the Gate in China’s modern period and provides a theoretical foundation on which studies on contemporary Chinese translations of this book can build.
Short-Term Energy Demand Forecast in Hotels Using Hybrid Intelligent Modeling
Authors: Casteleiro-Roca José-Luis , Gómez-González José , Calvo-Rolle José , Jove Esteban , Quintián Héctor , Gonzalez Diaz Benjamin , Mendez Perez Juan
Published: May 2019

The hotel industry is an important energy consumer that needs efficient energy management methods to guarantee its performance and sustainability. The new role of hotels as prosumers increases the difficulty in the design of these methods. Also, the scenery is more complex as renewable energy systems are present in the hotel energy mix. The performance of energy management systems greatly depends on the use of reliable predictions for energy load. This paper presents a new methodology to predict energy load in a hotel based on intelligent techniques. The model proposed is based on a hybrid intelligent topology implemented with a combination of clustering techniques and intelligent regression methods (Artificial Neural Network and Support Vector Regression). The model includes its own energy demand information, occupancy rate, and temperature as inputs. The validation was done using real hotel data and compared with time-series models. Forecasts obtained were satisfactory, showing a promising potential for its use in energy management systems in hotel resorts.
A Smart Phone Based Handheld Wireless Spirometer with Functions and Precision Comparable to Laboratory Spirometers
Authors: Zhou Ping , Yang Liu , Huang Yao-Xiong
Published: May 2019

We report a smart phone based handheld wireless spirometer which uses a Lilly type sensing flowhead for respiratory signal acquisition and transmits the data to smartphone or other mobile terminals with Bluetooth signal transmission for data processing and result display. The developed spirometer was demonstrated to be able to detect flow rates ranging from 0–15 L/s with an accuracy of 4 mL/s, and can perform tests of flow volume (FV), forced vital capacity (FVC), forced expiratory volume in 1 s (FEV1), peak expiratory flow (PEF), etc. By having the functions and precision comparable to laboratory spirometers, it satisfies the American Thoracic Society and European Respiratory Society (ATS/ERS) proposed performance requirements for spirometer. At the same time, it is low cost, light and handy, low power consumption battery-powered. The test of 12 cases of subjects using the developed spirometer also indicated that it was easy to use for both providers and patients, and suitable for the Point of Care Test (POCT) of chronic obstructive pulmonary disease (COPD) and asthma at general-practice settings and homes.
Non-Specific Adsorption Reduction Methods in Biosensing
Authors: Lichtenberg Jessanne Y. , Ling Yue , Kim Seunghyun
Published: May 2019

Non-specific adsorption (NSA) is a persistent problem that negatively affects biosensors, decreasing sensitivity, specificity, and reproducibility. Passive and active removal methods exist to remedy this issue, by coating the surface or generating surface forces to shear away weakly adhered biomolecules, respectively. However, many surface coatings are not compatible or effective for sensing, and thus active removal methods have been developed to combat this phenomenon. This review aims to provide an overview of methods of NSA reduction in biosensing, focusing on the shift from passive methods to active methods in the past decade. Attention is focused on protein NSA, due to their common use in biosensing for biomarker diagnostics. To our knowledge, this is the first review to comprehensively discuss active NSA removal methods. Lastly, the challenges and future perspectives of NSA reduction in biosensing are discussed.
New Detection Paradigms to Improve Wireless Sensor Network Performance under Jamming Attacks
Authors: Del-Valle-Soto Carolina , Mex-Perera Carlos , Aldaya Ivan , Lezama Fernando , Nolazco-Flores Juan Arturo , Monroy Raul
Published: May 2019

In this work, two new self-tuning collaborative-based mechanisms for jamming detection are proposed. These techniques are named (i) Connected Mechanism and (ii) Extended Mechanism. The first one detects jamming by comparing the performance parameters with respect to directly connected neighbors by interchanging packets with performance metric information, whereas the latter, jamming detection relays comparing defined zones of nodes related with a collector node, and using information of this collector detects a possible affected zone. The effectiveness of these techniques were tested in simulated environment of a quadrangular grid of 7 × 7, each node delivering 10 packets/sec, and defining as collector node, the one in the lower left corner of the grid. The jammer node is sending packets under reactive jamming. The mechanism was implemented and tested in AODV (Ad hoc On Demand Distance Vector), DSR (Dynamic Source Routing), and MPH (Multi-Parent Hierarchical), named AODV-M, DSR-M and MPH-M, respectively. Results reveal that the proposed techniques increase the accurate of the detected zone, reducing the detection of the affected zone up to 15% for AODV-M and DSR-M and up to 4% using the MPH-M protocol.
Exploiting Direct Laser Writing for Hydrogel Integration into Fragile Microelectromechanical Systems
Authors: Menges Julian , Klingel Steffen , Oesterschulze Egbert , Bart Hans-Jörg
Published: May 2019

The integration of chemo-responsive hydrogels into fragile microelectromechanical systems (MEMS) with reflective surfaces in the micron to submicron range is presented. Direct laser writing (DLW) for 3D microstructuring of chemoresponsive “smart” hydrogels on sensitive microstructures is demonstrated and discussed in detail, by production of thin hydrogel layers and discs with a controllable lateral size of 2 to 5 µm and a thickness of some hundred nm. Screening results of polymerizing laser settings for precision microstructuring were determined by controlling crosslinking and limiting active chain diffusion during polymerization with macromers. Macromers are linear polymers with a tunable amount of multifunctional crosslinker moieties, giving access to a broad range of different responsive hydrogels. To demonstrate integration into fragile MEMS, the gel was deposited by DLW onto a resonator with a 200 nm thick sensing plate with high precision. To demonstrate the applicability for sensors, proof of concept measurements were performed. The polymer composition was optimized to produce thin reproducible layers and the feasibility of 3D structures with the same approach is demonstrated.
Synchronous Vibration Measurements for Shrouded Blades Based on Fiber Optical Sensors with Lenses in a Steam Turbine
Authors: Ye Dechao , Duan Fajie , Jiang Jiajia , Cheng Zhonghai , Niu Guangyue , Shan Peng , Zhang Jiamin
Published: May 2019

It is important to obtain accurate dynamic vibrations of steam turbine blades for safe operation. Strain gauge (SG) measurements cannot fully obtain vibrations of all blades and nodal diameter (ND) details. The blade tip timing (BTT) technique could resolve this problem because it has the advantage of measuring all blades’ vibrations. This article proposed an improved BTT technique for measuring synchronous vibrations of shrouded blades in a steam turbine based on fiber optical sensors with lenses. The newly developed sensor was equipped with a Plano-convex lens, and the optical path was specifically designed to collimate the beam within a large working distance from 4 to 19 mm and improve the measuring accuracy. A method to search the spectra of all peak vibration amplitudes of all the blades was proposed to obtain the ND details of synchronous vibration. Experimental results validated the efficiency and accuracy of the proposed methods and sensors. Comparison results of BTT measurements with SG measurements showed that the relative errors of normalized frequency and strain were small and acceptable.
Energy-Level Jumping Algorithm for Global Optimization in Compressive Sensing-Based Target Localization
Authors: Wang Tianjing , Guan Xinjie , Wan Xili , Liu Guoqing , Shen Hang
Published: May 2019

Target localization is one of the essential tasks in almost applications of wireless sensor networks. Some traditional compressed sensing (CS)-based target localization methods may achieve low-precision target localization because of using locally optimal sparse solutions. Solving global optimization for the sparse recovery problem remains a challenge in CS-based target localization. In this paper, we propose a novel energy-level jumping algorithm to address this problem, which achieves high-precision target localization by solving the globally optimal sparse solution of l p -norm ( 0 < p < 1 ) minimization. By repeating the process of energy-level jumping, our proposed algorithm establishes a global convergence path from an initial point to the global minimizer. Compared with existing CS-based target localization methods, the simulation results show that our localization algorithm obtain more accurate locations of targets with the significantly reduced number of measurements.