bluuebunny/crossref_metadata_2025 huggingface dataset:
Water‐Soluble and Lowly Toxic Sulphur Quantum Dots
Authors: Li Shunxing , Chen Dejian , Zheng Fengying , Zhou Haifeng , Jiang Shaoxiong , Wu Yijin
Published: September 2014

Here, a new class of quantum dots, that is, sulphur quantum dots (SQDs), which are synthesized by the phase interfacial reaction, is reported. The prepared SQDs are monodisperse with a narrow size distribution (average 1.6 nm in size), excellent aqueous dispersibility, ultrahigh photostability, and lowly toxicity. Because of abundant oxidized sulphur species on the surface of SQDs, the incorporation of TiO2 with SQDs results in a synergistic effect for the TiO2‐based photocatalysts offering more effective environmental applications. It is demonstrated that SQDs‐TiO2 nanocomposite can enhance the photocatalytic activity of producing hydrogen (enhancement factor for 191) in methanol‐water system. The SQDs also can used as fluorescent probe for highly selective quantitative detection Fe3+ in an aqueous solution contained various metal ions.
Effect of Transition Metals on the Electrical Conductivity Response of dPPV/Zeolite Y Composites toward Ketone Vapors
Authors: KAMONSAWAS JIRARAT , SIRIVAT ANUVAT
Published: September 2014

Doped poly(p‐phenylene vinylene) (dPPV) is mixed with modified zeolite Y to improve the selective and sensitive response of zeolite Y toward three different ketone vapors (acetone, methyl ethyl ketone, and methyl iso‐butyl ketone), which are known as the toxic components. Zeolite Y (Si/Al 5.1, Na+) or NaY is ion exchanged with transition cations, Cu2+, Ni2+, and Fe2+, at 80% cation exchanged to prepare 80CuNaY, 80NiNaY, and 80FeNaY. In this work, the effects of transition cations, ketone vapor type, and ketone vapor concentration are systematically investigated. The highest electrical conductivity response and sensitivity toward acetone vapor at the vapor concentration of 30,000 ppm is obtained with 80CuNaY, whereas 80FeNaY shows the lowest values due to the electrostatic interaction between the zeolite framework and the cation. dPPV is mixed with 80CuNaY and exposed to the three ketone vapors. The electrical conductivity response and sensitivity of the composites toward acetone exhibits the highest values, whereas with MIBK they show the lowest value. After mixing of 80CuNaY with dPPV, the minimum vapor concentration toward acetone vapor decreases from 9 to 5 ppm. The response of the composite is irreversible as evidenced by Fourier transform infrared and atomic force microscopy techniques.
Continuous Flow and Microwave‐Assisted Vorbrüggen Glycosylations: Historical Perspective to High‐Throughput Strategies
Authors: Manvar Atul , Shah Anamik
Published: September 2014

In recent years organic chemistry has been impacted tremendously by the explosive growth of fashionable, innovative technologies, such as microwave flash heating, continuous micro/flow processes, polymer‐supported reagents/catalysts, and so on. In the repertoire of high‐throughput techniques, microwave‐assisted heating is heavily used in academic laboratories and in industry. The use of continuous flow/microreactors is also no longer academic curiosity but is widely exploited in scale‐up (“scale‐out”) for process intensification in the pharmaceutical as well as the fine chemical industries. Glycosylations via high‐throughput strategies have remained underdeveloped, albeit over a period of nine decades, they have been successfully used to decorate bioactive nucleosides. The coupling between silanolate nucleophiles and the corresponding sugar partners in the presence of a Lewis acid is commonly referred to as the silyl Hilbert—Johnson reaction or Vorbrüggen glycosylation, which is considered one of the most frequently used methods of glycosylation. The aim of this Focus Review is to showcase the remarkable influence of “superheating” generated by high‐speed non‐conventional heating devices, continuous flow/microreactors, or microwaves over classical thermal heating to accomplish efficient Vorbrüggen glycosylations for the resourceful collection of functionalized nucleosides.
Über den chemischen Informationsaustausch zwischen gesteuerten Nanopartikeln
Authors: Giménez Cristina , Climent Estela , Aznar Elena , Martínez‐Máñez Ramón , Sancenón Félix , Marcos M. Dolores , Amorós Pedro , Rurack Knut
Published: September 2014

Das Design von vergleichsweise einfachen und modular konfigurierbaren künstlichen Systemen, die über den Austausch von chemischen Botenstoffen miteinander kommunizieren können, ist unseres Wissens ein bislang unerforschtes Gebiet. In einer grundlegenden Arbeit präsentieren wir hier eine Serie von Nanopartikeln, die in hierarchischer Art und Weise miteinander kommunizieren können. Das Konzept beruht auf gedeckelten mesoporösen Silikat‐Trägern, bei denen der aus einem ersten Typ von gesteuerten Nanopartikeln freigesetzte chemische Botenstoff einen zweiten Typ von gedeckelten Nanopartikeln öffnet, welche wiederum einen anderen Botenstoff freisetzen, die eine dritte Gruppe von gesteuerten Nanoobjekten öffnen. Dieses Konzept, das nanoskopische Objekte so aufgebaut werden können, dass sie miteinander Informationen austauschen, kann unserer Meinung nach zu einer Reihe neuartiger Anwendungen führen und wird Fortschritte im Bereich kooperativer Systeme mit komplexen Eigenschaften, die auf der Kommunikation einfacher individueller abiotischer Komponenten basieren, befördern.
Ein einfacher Zugang zu cyclischen photoaktivierbaren Tubulysin‐Derivaten
Authors: Hoffmann Judith , Kazmaier Uli
Published: September 2014

Die Entwicklung einer neuen photolabilen Schutzgruppe mit integrierter Allyleinheit ermöglicht die Synthese cyclischer photoaktivierbarer Naturstoffderivate. Die Cyclisierung erfolgt dabei über die Allyleinheit der Schutzgruppe und eine zweite Doppelbindung durch Ringschlussmetathese. Die so induzierte Konformationsänderung soll zum einen die biologische Aktivität des Naturstoffs verringern, und durch die Cyclisierung soll gleichzeitig seine metabolische Stabilität erhöht werden. Photochemische Ringöffnung bewirkt schließlich eine Aktivierung des Wirkstoffs. Am Beispiel von Tubulysin‐Derivaten wird gezeigt, wie in nur zwei Stufen ausgehend von einfachen Bausteinen durch Ugi‐Reaktion und Ringschlussmetathese cyclische photoaktivierbare Wirkstoffe hergestellt werden können. Die photolabile Schutzgruppe wird dabei über die Isocyanid‐Komponente während der Ugi‐Reaktion eingeführt.
An Alternative to the Classical α‐Arylation: The Transfer of an Intact 2‐Iodoaryl from ArI(O2CCF3)2
Authors: Jia Zhiyu , Gálvez Erik , Sebastián Rosa María , Pleixats Roser , Álvarez‐Larena Ángel , Martin Eddy , Vallribera Adelina , Shafir Alexandr
Published: September 2014

The α‐arylation of carbonyl compounds is generally accomplished under basic conditions, both under metal catalysis and via aryl transfer from the diaryl λ3‐iodanes. Here, we describe an alternative metal‐free α‐arylation using ArI(O2CCF3)2 as the source of a 2‐iodoaryl group. The reaction is applicable to activated ketones, such as α‐cyanoketones, and works with substituted aryliodanes. This formal CH functionalization reaction is thought to proceed through a [3,3] rearrangement of an iodonium enolate. The final α‐(2‐iodoaryl)ketones are versatile synthetic building blocks.
An Organotrifluoroborate for Broadly Applicable One‐Step 18F‐Labeling
Authors: Liu Zhibo , Pourghiasian Maral , Radtke Mark Alex , Lau Joseph , Pan Jinhe , Dias Gemma M. , Yapp Donald , Lin Kuo‐Shyan , Bénard Francois , Perrin David M.
Published: September 2014

A new zwitterionic organotrifluoroborate is appended to three radiosynthons that afford undergo facile bioconjugation to several clinically relevant peptides and one enzyme inhibitor. Molecularly complex bioconjugates are 18F‐labeled in a single aqueous step in rapid time (<15 min) without HPLC purification to afford tracers in good yields (>200 mCi, 20–40 %) at high specific activity (≥3 Ci/μmol) and at >98 % purity. PET imaging shows in vivo stability and tumor uptake.
Synthesis of Aryldiazoacetates through Palladium(0)‐Catalyzed Deacylative Cross‐Coupling of Aryl Iodides with Acyldiazoacetates
Authors: Ye Fei , Wang Chengpeng , Zhang Yan , Wang Jianbo
Published: September 2014

Palladium(0)‐catalyzed deacylative cross‐coupling of aryl iodides and acyldiazocarbonyl compounds can be achieved at room temperature under mild reaction conditions. The coupling reaction represents a highly efficient and general method for the synthesis of aryldiazocarbonyl compounds, which have found wide and increasing applications as precursors for generating donor/acceptor‐substituted metallocarbenes.
The Many Faces of Soot: Characterization of Soot Nanoparticles Produced by Engines
Authors: Niessner Reinhard
Published: September 2014

Soot nanoparticles produced by engines constitute a threat to human health. For the analytical chemist, soot is a hard nut to crack as the released particles undergo rapid changes in their size, shape, and number concentration. The complete characterization of soot will be essential to meet future low‐emission standards. Besides measuring the light extinction, modern analytical chemistry can determine a variety of less‐known effects, such as condensation properties, immune response in vertebrates, and impact on the cardiovascular function of a beating heart. Photon emission and in particular Raman spectroscopy provides information on the nanocrystallinity, while thermoelectron emission allows the number of electrical particles to be counted. Even the “simple” combustion of soot nanoparticles offers potential for the characterization of the particles.
Soft Magnets from the Self‐Organization of Magnetic Nanoparticles in Twisted Liquid Crystals
Authors: Matt Benjamin , Pondman Kirsten M. , Asshoff Sarah J. , ten Haken Bennie , Fleury Benoit , Katsonis Nathalie
Published: September 2014

Organizing magnetic nanoparticles into long‐range and dynamic assemblies would not only provide new insights into physical phenomena but also open opportunities for a wide spectrum of applications. In particular, a major challenge consists of the development of nanoparticle‐based materials for which the remnant magnetization and coercive field can be controlled at room temperature. Our approach consists of promoting the self‐organization of magnetic nanoparticles in liquid crystals (LCs). Using liquid crystals as organizing templates allows us to envision the design of tunable self‐assemblies of magnetic nanoparticles, because liquid crystals are known to reorganize under a variety of external stimuli. Herein, we show that twisted liquid crystals can be used as efficient anisotropic templates for superparamagnetic nanoparticles and demonstrate the formation of hybrid soft magnets at room temperature.
Simulation and analysis of multiple steady states in dividing wall column
Authors: Wang Erqiang
Published: September 2014

This paper presents simulation and analysis of multiple steady states (MSS) in dividing wall column (DWC). First steady state simulation of benzene–toluene–xylene (BTX) separation in DWC is run to obtain its four different solutions using Aspen Plus software, and then detailed comparisons and analysis of these solutions are carried out. From simulation results, it can be concluded that MSS inevitably exists in DWC, which is important for its design, operation and control but has not been declared in open literature up to now. In addition, obvious grouping feature is found among the four solutions of BTX DWC case, and light component benzene and heavy component xylene have, respectively, two different recoveries at the top of the side column among the four solutions. The grouping feature is interesting and important for DWC, which may be explained by the existence of impurities in side product stream and their different flow paths from the feed to the side product stream, that is, above or under the dividing wall. © 2014 Curtin University of Technology and John Wiley & Sons, Ltd.
Viscoelastic behavior of hybrid building materials
Authors: Papanicolaou George Christopher , Lagas Georgios P. , Zaoutsos Stefanos Polymeros
Published: September 2014

The objective of this experimental work is the investigation of the viscoelastic behavior of a hybrid matrix, fiber‐reinforced building material. Hybrid matrix consisted of epoxy resin mixed with fine marble sand, whereas short steel fibers were used as reinforcement. The experimental procedure involved, first, the manufacturing of specimens using different hybrid matrix types and different reinforcement by weight ratios. Subsequently, bending relaxation experiments at room temperature were executed, under three‐point bending test experimental configuration, at different strain levels and the variation of stress of the hybrid matrix material with time was monitored. The data obtained were used to (i) investigate the effect of reinforcement mass fraction contained in the composite on the viscoelastic behavior and (ii) to apply existed and newly developed viscoelastic models for the description of the observed viscoelastic behavior. More precisely, the four‐parameter (Burgers) viscoelastic model and the modified Residual Property Model were calibrated and used to simulate the relaxation behavior of the materials manufactured and tested. Experimental results exhibited a clear influence of both reinforcement ratio and initial displacement on the viscoelastic behavior of the materials manufactured and tested, whereas the models proposed and used can adequately reproduce the variation of relaxation stress with time. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 41429.
Output Feedback Stabilization for a Class of Stochastic High‐Order Feedforward Nonlinear Systems with Time‐Varying Delay
Authors: Ai Weiqing , Zhai Junyong , Fei Shumin
Published: September 2014

This paper considers the output feedback control problem for a class of stochastic high‐order feedforward nonlinear systems with time‐varying delay. Compared with existing works, the features of our system include different bounded time‐varying delays, more general high‐order power and homogeneous feedforward growth conditions. Firstly, we use the adding one power integrator technique to construct an output feedback controller without nonlinearities. Then, by introducing a scaling gain into the controller and choosing an appropriate Lyapunov–Krasovskii functional, the closed‐loop system can be rendered globally asymptotically stable in probability. A simulation example is provided to illustrate the effectiveness of the designed controller.
The Sharing Dilemma: Joining Cooperative Groups and Sharing Resources as a Means of Coping with Environmental Risk
Authors: Suleiman Ramzi , Aharonov‐Majar Efrat , Luzon Pini
Published: September 2014

The “social insurance” hypothesis posits that individuals join cooperative groups and share resources in order to reduce environmental risk. Despite its significance for explaining cooperative groups' formation, in small‐scale and in developing societies, the hypothesis has been subjected to little experimental testing. The present research is designed to examine the relative weight of the motivation for social insurance compared with other psychological motivations for sharing risk. We conducted two studies to test the tendency to share risk under different risk conditions and for groups of different sizes. A third experiment extends the risk‐sharing research to situations involving losses instead of gains. The findings of the first two studies lend strong support to the risk‐sharing hypothesis in the gain domain. For the loss domain, the results of the third experiment demonstrate an intriguing shift from strong reluctance to join groups under lower risk, to ubiquitous readiness to join groups under higher risk. We discuss these results in light of prospect theory and decisions from experience. Copyright © 2014 John Wiley & Sons, Ltd.
Bladder exstrophy–epispadias complex and triple‐X syndrome: Incidental finding or causality?
Authors: Ramaekers Paul , Loeys Bart , von Lowtzow Catharina , Reutter Heiko , Leroy Yves , Colpaert Cécile , Blaumeiser Bettina , Janssens Katrien , Parizel Maxim , Jacquemyn Yves
Published: September 2014

Background

Bladder exstrophy is a rare malformation. Prenatal diagnosis is usually an incidental finding on routine ultrasound examination. Triple‐X syndrome (karyotype 47,XXX) is the most frequent sex chromosome aneuploidy in live‐born females (approximately 1 in 1000). The diagnosis is often not made because women with 47,XXX karyotype have no or hardly any clinical symptoms during life.

Methods

Prenatal diagnosis of triple X karyotype is usually an incidental finding when an invasive prenatal diagnosis is performed for other reasons.

Results

Here, we report on two cases with bladder exstrophy and triple‐X syndrome, one in a fetus and one in an adult. In view of two previous reports of this association in literature, causality of these two conditions should be considered.

Conclusion

A gene dosage effect as possible underlying mechanisms will be discussed. Birth Defects Research (Part A) 100:797–800, 2014. © 2014 Wiley Periodicals, Inc.
CRISPR/Cas9‐mediated genome engineering: An adeno‐associated viral (AAV) vector toolbox
Authors: Senís Elena , Fatouros Chronis , Große Stefanie , Wiedtke Ellen , Niopek Dominik , Mueller Ann‐Kristin , Börner Kathleen , Grimm Dirk
Published: September 2014

Its remarkable ease and efficiency make the CRISPR (clustered regularly interspaced short palindromic repeats) DNA editing machinery highly attractive as a new tool for experimental gene annotation and therapeutic genome engineering in eukaryotes. Here, we report a versatile set of plasmids and vectors derived from adeno‐associated virus (AAV) that allow robust and specific delivery of the two essential CRISPR components – Cas9 and chimeric g(uide)RNA – either alone or in combination. All our constructs share a modular design that enables simple and stringent guide RNA (gRNA) cloning as well as rapid exchange of promoters driving Cas9 or gRNA. Packaging into potent synthetic AAV capsids permits CRISPR delivery even into hard‐to‐transfect targets, as shown for human T‐cells. Moreover, we demonstrate the feasibility to direct Cas9 expression to or away from hepatocytes, using a liver‐specific promoter or a hepatic miRNA binding site, respectively. We also report a streamlined and economical protocol for detection of CRISPR‐induced mutations in less than 3 h. Finally, we provide original evidence that AAV/CRISPR vectors can be exploited for gene engineering in vivo, as exemplified in the liver of adult mice. Our new tools and protocols should foster the broad application of CRISPR technology in eukaryotic cells and organisms, and accelerate its clinical translation into humans.
Identification of metabolites of rupestonic acid in rat urine by liquid chromatography combined with electrospray ionization quadrupole time‐of‐flight tandem mass spectrometry
Authors: Gu Dongyu , Yang Yi , Chen Qibin , Habasi Madina , Zhao Jiangyu , Aisa Haji Akber
Published: September 2014

Rupestonic acid, a potential anti‐influenza agent, is an important and characteristic compound in Artemisia rupestris L., a well‐known traditional Uighur medicine for the treatment of colds. In the present study, high‐performance liquid chromatography combined with electrospray ionization quadrupole time‐of‐flight tandem mass spectrometry was used to detect and identify the metabolites in rat urine after oral administration of rupestonic acid. A total of 10 metabolites were identified or partially characterized. The structure elucidations of the metabolites were performed by comparing the changes in accurate molecular masses and fragment ions with those of the parent compound. The results showed that the main metabolites of rupestonic acid in rat urine were formed by oxidation, hydrogenation and glucuronidation. A metabolism pathway was proposed for the first time based on the characterized structures. This metabolism study can provide essential information for drug discovery, design and clinical application of rupestonic acid. Copyright © 2014 John Wiley & Sons, Ltd.
A realistic generator of power quality disturbances for practicing in courses of electrical engineering
Authors: Montenegro Davis , Hernandez Miguel E. , Ramos Gustavo A.
Published: September 2014

This paper presents a realistic generator of power quality (PQ) disturbances developed using real time—hardware in the loop (RT‐HIL) technologies; the aim is to reduce the gap between the PQ mathematical theory and its practical application by improving the technical skills of students through the use of instruments in a controlled and safe laboratory environment. The implementation of this interactive teaching tool in a graduate level course has significantly enhanced the communication process between the teacher and students and thus, resulted in a highly effective teaching methodology. © 2014 Wiley Periodicals, Inc. Comput Appl Eng Educ 23:391–402, 2015; View this article online at wileyonlinelibrary.com/journal/cae; DOI 10.1002/cae.21609
Regulatory FeII/III Heme: The Reconstruction of a Molecule's Biography
Authors: Kühl Toni , Imhof Diana
Published: September 2014

More than 20 years of research on heme as a temporary effector molecule of proteins have revealed its widespread impact on virtually all primary functions in the human organism. As our understanding of this influence is still growing, a comprehensive overview of compiled data will give fresh impetus for creativity and developing new strategies in heme‐related research. From known data concerning heme‐regulated proteins and their involvement in the development of diseases, we provide concise information of FeII/III heme as a regulator and the availability of “regulatory heme”. The latter is dependent on the balance between free and bound FeII/III heme, here termed “hemeostasis”. Imbalance of this system can lead to the development of diseases that were not always attributed to this small molecule. Diseases such as cancer or Alzheimer's disease highlight the reawakened interest in heme, whose function was previously believed to be completely understood.
Prolonged survival in metastatic colorectal cancer following chemotherapy
Authors: Paul Doru , Gold Menachem , Nouraddin Nouraddin
Published: September 2014

Key Clinical Message

The cost of treating metastatic colorectal cancer has increased significantly after the introduction of targeted antivascular therapies. We report the unusual case of a patient with colorectal cancer with several large liver metastases at diagnosis, who was cured after removal of the primary tumor and treatment with 5‐FU/LV only.
Transcatheter CoreValve valve‐in‐valve implantation in a stentless porcine aortic valve for severe aortic regurgitation
Authors: Yong Celina M. , Buchbinder Maurice , Giacomini John C.
Published: September 2014

Key Clinical Message

We describe the first valve‐in‐valve Corevalve transcatheter aortic valve replacement in the St. Jude Toronto stentless porcine aortic valve in the United States, which enabled this 59‐year‐old patient with a history of bacterial endocarditis and aortic regurgitation to avoid heart transplant with complete resolution of his severe left ventricular dysfunction.
Snapshots in surgery: small bowel intussusception following ileojejunal bypass
Authors: Ward Joseph , Jaber Basel , Leaman Charlotte , Barry Jonathan , Khot Umesh
Published: September 2014

Key Clinical Message

Jejunal intussusception is a known complication of ileojejunal bypass surgery for obesity that may present as an acute abdomen. It can be avoided if the jejunum is anchored to the transverse mesocolon intra‐operatively.
CNN Pincer Ruthenium Catalysts for Hydrogenation and Transfer Hydrogenation of Ketones: Experimental and Computational Studies
Authors: Baratta Walter , Baldino Salvatore , Calhorda Maria José , Costa Paulo J. , Esposito Gennaro , Herdtweck Eberhardt , Magnolia Santo , Mealli Carlo , Messaoudi Abdelatif , Mason Sax A. , Veiros Luis F.
Published: September 2014

Reaction of [RuCl(CNN)(dppb)] (1‐Cl) (HCNN=2‐aminomethyl‐6‐(4‐methylphenyl)pyridine; dppb=Ph2P(CH2)4PPh2) with NaOCH2CF3 leads to the amine‐alkoxide [Ru(CNN)(OCH2CF3)(dppb)] (1‐OCH2CF3), whose neutron diffraction study reveals a short RuO⋅⋅⋅HN bond length. Treatment of 1‐Cl with NaOEt and EtOH affords the alkoxide [Ru(CNN)(OEt)(dppb)]⋅(EtOH)n (1‐OEt⋅n EtOH), which equilibrates with the hydride [RuH(CNN)(dppb)] (1‐H) and acetaldehyde. Compound 1‐OEt⋅n EtOH reacts reversibly with H2 leading to 1‐H and EtOH through dihydrogen splitting. NMR spectroscopic studies on 1‐OEt⋅n EtOH and 1‐H reveal hydrogen bond interactions and exchange processes. The chloride 1‐Cl catalyzes the hydrogenation (5 atm of H2) of ketones to alcohols (turnover frequency (TOF) up to 6.5×104 h−1, 40 °C). DFT calculations were performed on the reaction of [RuH(CNN′)(dmpb)] (2‐H) (HCNN′=2‐aminomethyl‐6‐(phenyl)pyridine; dmpb=Me2P(CH2)4PMe2) with acetone and with one molecule of 2‐propanol, in alcohol, with the alkoxide complex being the most stable species. In the first step, the Ru‐hydride transfers one hydrogen atom to the carbon of the ketone, whereas the second hydrogen transfer from NH2 is mediated by the alcohol and leads to the key “amide” intermediate. Regeneration of the hydride complex may occur by reaction with 2‐propanol or with H2; both pathways have low barriers and are alcohol assisted.
The π‐Back‐Bonding Modulation and Its Impact in the Electronic Properties of CuII Antineoplastic Compounds: An Experimental and Theoretical Study
Authors: García‐Ramos Juan Carlos , Galindo‐Murillo Rodrigo , Tovar‐Tovar Araceli , Alonso‐Saenz Ana Luisa , Gómez‐Vidales Virginia , Flores‐Álamo Marcos , Ortiz‐Frade Luis , Cortes‐Guzmán Fernando , Moreno‐Esparza Rafael , Campero Antonio , Ruiz‐Azuara Lena
Published: September 2014

A complete study of the electronic density distribution in antineoplastic mixed chelate complexes of the type [Cu(NN)(glycinate)H2O]NO3 (NN=2,2′‐bipyridine (bpy) (1), 4,4′‐dimethyl‐bpy (2), 5,5′‐dimethyl‐2,2′‐bipyridine (3), 1,10‐phenanthroline (phen) (4), 4‐methyl‐phen (5); 5‐methyl‐phen (6); 4,7‐dimethyl‐phen (7), 5,6‐dimethyl‐phen (8), and 3,4,7,8‐tetramethyl‐phen (9)), a family known as Casiopeínas, was carried out with cyclic voltammetry, EPR, and computational methods. Crystal structures of 1⋅H2O, 2⋅H2O, 3⋅H2O, 6⋅H2O, and 8⋅H2O show the variability in the geometries adopted by the copper compounds in the solid state. Experimental properties are described employing electronic descriptors obtained from computational methods. The main descriptors found were: The total electronic population of the metal ion (N(Cu)), delocalization of the metal ion electrons over the donor atoms (Δ(Cu)), atomic dipolar moment (μ(Cu)), and the atomic quadrupole moment (Q(Cu)). It was found that π‐back‐bonding is the principal factor that modulates the distribution of the electron density around the metal ion. The electronic descriptors obtained from the computational approach can be used as electronic descriptors of inorganic compounds that have shown antiproliferative activities instead the experimental data, aiding the rational design of good candidates of metal‐based drugs.
Adding Remnant Magnetization and Anisotropic Exchange to Propeller‐like Single‐Molecule Magnets through Chemical Design
Authors: Westrup Kátia Cristina M. , Boulon Marie‐Emmanuelle , Totaro Pasquale , Nunes Giovana G. , Back Davi F. , Barison Andersson , Jackson Martin , Paulsen Carley , Gatteschi Dante , Sorace Lorenzo , Cornia Andrea , Soares Jaísa F. , Sessoli Roberta
Published: September 2014

The selective replacement of the central iron(III) ion with vanadium(III) in a tetrairon(III) propeller‐shaped single‐molecule magnet has allowed us to increase the ground spin state from S=5 to S=13/2. As a consequence of the pronounced anisotropy of vanadium(III), the blocking temperature for the magnetization has doubled. Moreover, a significant remnant magnetization, practically absent in the parent homometallic molecule, has been achieved owing to the suppression of zero‐field tunneling of the magnetization for the half‐integer molecular spin. Interestingly, the contribution of vanadium(III) to the magnetic anisotropy barrier occurs through the anisotropic exchange interaction with iron(III) spins and not through single ion anisotropy as in most single‐molecule magnets.
Enantioselective Construction of 2,3‐Dihydrofuro[2,3‐b]quinolines through Supramolecular Hydrogen Bonding Interactions
Authors: Zhong Fangrui , Bach Thorsten
Published: September 2014

The first asymmetric synthesis of 2,3‐dihydrofuro[2,3‐b]quinolines has been achieved by a cascade asymmetric aziridination/intramolecular ring‐opening process of differently substituted 3‐alkenylquinolones. Good yields and high enantioselectivities (up to 78 % yield and 95 % ee) were recorded when employing 2,2,2‐trichloroethoxysulfonamide as the nitrene source, PhI(OCOtBu)2 as the oxidant, and a chiral C2‐symmetric RhII complex as the catalyst (1 mol %). The catalyst bears two lactam motifs, which serve as binding sites for substrate coordination through supramolecular hydrogen‐bonding interactions.
ChemInform Abstract: La3Si6N11.
Authors: Yamane Hisanori , Nagura Toshiki , Miyazaki Tomohiro
Published: September 2014

Colorless transparent single crystals of the title compound are prepared by high‐pressure high‐temperature reaction of LaN and Si3N4 (BN crucible, 2273 K, 0.85 MPa N2, 2 h).
ChemInform Abstract: Cs3ScCl6.
Authors: Ward Matthew D. , Ibers James A.
Published: September 2014

Purple blocks of the title compound are obtained as a side product from the reaction of U, SnCl2, Sc, and S in a CsCl flux (evacuated silica tube, 1073 K, 96 h).
ChemInform Abstract: Nickel Hexayttrium Decaiodide, [NiY6]I10.
Authors: Steinberg Simon , Meyer Gerd
Published: September 2014

Comproportionation reactions of YI3, Y, and Ni leads to the formation of the title compound (sealed Ta tube in an evacuated silica tube, 1050 °C, 1 week) which is isostructural with the prototypical [RuY6]I10.
ChemInform Abstract: Ba4GaN3O.
Authors: Hashimoto Takayuki , Yamane Hisanori
Published: September 2014

Red transparant platelet‐shaped single crystals of the title compound are grown by the Na flux method from a mixture of Ba, Ga, Na, Si, and NaN3 (BN crucible in stainless steel tube, 750 °C, 2 h).
ChemInform Abstract: Na4.25Mo15S19: A Novel Ternary Reduced Molybdenum Sulfide Containing Mo6 and Mo9 Clusters.
Authors: Salloum D. , Gougeon P. , Gall P.
Published: September 2014

Single crystals of the title compound are prepared by ion exchange of In3+xMo15S19 with an excess of NaI (evacuated silica tube, 1073 K, 2 d).
ChemInform Abstract: Intercalation‐Driven Reversible Control of Magnetism in Bulk Ferromagnets.
Authors: Dasgupta Subho , Das Bijoy , Knapp Michael , Brand Richard. A. , Ehrenberg Helmut , Kruk Robert , Hahn Horst
Published: September 2014

Nondestructive intercalation and de‐intercalation of mobile Li ions in γ‐Fe2O3 results in a significant reversible change of the magnetic state of the material.
ChemInform Abstract: Carbon Nanotubes Decorated with CoP Nanocrystals: A Highly Active Non‐Noble‐Metal Nanohybrid Electrocatalyst for Hydrogen Evolution.
Authors: Liu Qian , Tian Jingqi , Cui Wei , Jiang Ping , Cheng Ningyan , Asiri Abdullah M. , Sun Xuping
Published: September 2014

Carbon nanotubes decorated with CoP nanocrystals are prepared by calcination of a mixture of Co3O4/carbon nanotubes (hydrothermally obtained from carbon nanotubes, Co(OAc)2, and NH4OH dissolved in EtOH/H2O in an autoclave at 150 °C for 3 h) and NaH2PO2 at 300 °C for 2 h.
ChemInform Abstract: Expansion of the Rich Structures and Magnetic Properties of Neptunium Selenites: Soft Ferromagnetism in Np(SeO3)2.
Authors: Diefenbach Kariem , Lin Jian , Cross Justin N. , Dalal Naresh S. , Shatruk Michael , Albrecht‐Schmitt Thomas E.
Published: September 2014

The reaction of NpO2, SeO2, Pb(NO3)2 in the molar ratio of 1:4:1 under mild hydrothermal conditions (autoclave, 200 °C, 3 d) yields NpIV(SeO3)2 (I) besides NpVIO2(SeO3) (II) as minor product.
ChemInform Abstract: Novel Tartrate‐Derived Guanidine‐Catalyzed Highly Enantio‐ and Diastereoselective Michael Addition of 3‐Substituted Oxindoles to Nitroolefins
Authors: Zou Liwei , Bao Xiaoze , Ma Yuanyuan , Song Yuming , Qu Jingping , Wang Baomin
Published: September 2014

30 examples
ChemInform Abstract: An Unexpected Lewis Acids‐Catalyzed Tandem Ring‐Opening Rearrangement of Vinylcyclopropane Ketone with Aryl Aldehyde.
Authors: Ren Jun , Bai Yu , Tao Weijie , Wang Zhongwen
Published: September 2014

Nitrobenzaldehyde, 2‐furaldehyde, and aliphatic aldehydes do not give the corresponding products.
ChemInform Abstract: Synthesis of Entacapone by Pd‐Catalyzed Heck Coupling Reaction.
Authors: Veerareddy Arava , Reddy Gogireddy Surendra
Published: September 2014

The title compound (IV) can be readily obtained by further treatment of the key intermediate (III) with nitric acid and subsequent demethylation with AlCl3.
ChemInform Abstract: Gold‐Catalyzed Oxidative Reactions of Propargylic Carbonates Involving 1,2‐Carbonate Migration: Stereoselective Synthesis of Functionalized Alkenes.
Authors: Sun Ning , Chen Ming , Liu Yuanhong
Published: September 2014

The reaction provides an efficient access to α‐functionalized‐α,β‐unsaturated ketones with excellent stereocontrol via regioselective attack of the N‐oxide to the activated alkyne followed by 1,2‐carbonate migration.
ChemInform Abstract: 1,n‐Rearrangement of Allylic Alcohols Promoted by Hot Water: Application to the Synthesis of Navenone B, a Polyene Natural Product.
Authors: Li Pei‐Fang , Wang Heng‐Lu , Qu Jin
Published: September 2014

The 1,n‐rearrangement of acyclic and cyclic allylic alcohols under aqueous conditions represents a novel method for the synthesis of various β,γ‐unsaturated alcohols.
ChemInform Abstract: Diastereoselective Carbocyclization of 1,6‐Heptadienes Triggered by Rhodium‐Catalyzed Activation of an Olefinic C—H Bond.
Authors: Aissa Christophe , Ho Kelvin Y. T. , Tetlow Daniel J. , Pin‐No Maria
Published: September 2014

The first example of a metal‐catalyzed functionalization of an olefinic C—H bond, i.
ChemInform Abstract: Aluminum Chloride Hexahydrate (AlCl3·6H2O): An Efficient, Facile, Mild, and Highly Chemoselective Catalytic Deprotection of tert‐Butyldimethylsilyl (TBS) Ethers.
Authors: Gonzalez‐Calderon Davir , Benitez‐Puebla Luis J. , Gonzalez‐Gonzalez Carlos A. , Garcia‐Eleno Marco A. , Fuentes‐Benitez Aydee , Cuevas‐Yanez Erick , Corona‐Becerril David , Gonzalez‐Romero Carlos
Published: September 2014

The reaction can be performed either under microwave irradiation or conventional heating whereas, slightly better results are achieved by heating the reaction mixture in methanol.
ChemInform Abstract: Photooxidative Cleavage of Aromatic Alkenes into Aldehydes Using Catalytic Iodine and Molecular Oxygen under Visible Light Irradiation.
Authors: Fujiya Akitoshi , Kariya Atsumasa , Nobuta Tomoya , Tada Norihiro , Miura Tsuyoshi , Itoh Akichika
Published: September 2014

Cleavage reaction proceeds well for arenes with electron‐donating substituents while arenes with electron‐withdrawing substituents gave poor yield or fail.
ChemInform Abstract: Regioselective ortho‐Carboxylation of Phenols Catalyzed by Benzoic Acid Decarboxylases: A Biocatalytic Equivalent to the Kolbe—Schmitt Reaction.
Authors: Wuensch Christiane , Gross Johannes , Steinkellner Georg , Lyskowski Andrzej , Gruber Karl , Glueck Silvia M. , Faber Kurt
Published: September 2014

Several decarboxylases are tested for exclusively selective ortho‐carboxylation of phenols under ambient reaction conditions using bicarbonate as CO2 source.
ChemInform Abstract: Ethyl 2‐Cyano‐2‐(4‐nitrophenylsulfonyloxyimino)acetate‐Mediated Lossen Rearrangement: Single‐Pot Racemization‐Free Synthesis of Hydroxamic Acids and Ureas from Carboxylic Acids.
Authors: Thalluri Kishore , Manne Srinivasa Rao , Dev Dharm , Mandal Bhubaneswar
Published: September 2014

Ethyl 2‐cyano‐2‐(4‐nitrophenylsulfonyloxyimino)acetate (ECN) is employed as a new coupling reagent for the preparation of hydroxamic acids and their subsequent Lossen rearrangement into the corresponding isocyanates.
ChemInform Abstract: Gold Nanoparticle Decorated Reduced Graphene Oxide Sheets with High Catalytic Activity for Ullmann Homocoupling.
Authors: Movahed Siyavash Kazemi , Fakharian Mahsa , Dabiri Minoo , Bazgir Ayoob
Published: September 2014

Au nanoparticle‐reduced graphene oxide nanocomposite is found to be an efficient and reusable catalyst for the Ullmann homocoupling of aryl iodides.
ChemInform Abstract: Divergent Synthesis of Pseudoenantiomers for ABC‐Ring Moiety of Steroids.
Authors: Furuta Miyu , Hanaya Kengo , Sugai Takeshi , Shoji Mitsuru
Published: September 2014

One of the key steps in the synthesis of the ABC‐Ring moiety is the radical domino cyclization reaction of the precursor (I).
ChemInform Abstract: An Efficient and Green Synthesis of Phthalide‐Fused Pyrazole and Pyrimidine Derivatives.
Authors: Motamedi Anahita , Sattari Elahe , Mirzaei Peiman , Armaghan Mahsa , Bazgir Ayoob
Published: September 2014

The reaction of 2‐formylbenzoic acid with 6‐amino uracils, pyrazol‐5‐amine, and cyclic 1,3‐diketone derivatives in water results in the formation of phthalide fused pyrimidine, pyrazole, and cyclic 1,3‐dione derivatives.
ChemInform Abstract: Synthesis of Functionalized Octahydroindoles Related to Daphnyphyllum Alkaloids.
Authors: Dorich Stephane , Del Valle Juan R. , Hanessian Stephen
Published: September 2014

A variety of octahydroindole compounds are prepared via key intermediate (IV), which is synthesized from racemic cyclohex‐2‐en‐1‐ol.
ChemInform Abstract: Synthesis of Pharmacologically Active Bis(indolyl) and Tris(indolyl) Derivatives Using Chlorotrimethylsilane.
Authors: Singh Nongthombam G. , Kathing Chingrishon , Rani Jims W. S. , Nongkhlaw Rishan L.
Published: September 2014

TmsCl is demonstrated to be an efficient catalyst for the condensation of indoles with aldehydes or chalcone to yield bis(indolyl)methane derivatives.
ChemInform Abstract: Divergent Synthesis of 6H‐Isoindolo[2,1‐a]indol‐6‐ones and Indenoindolones: An Investigation of Pd‐Catalyzed Isocyanide Insertion.
Authors: Tang Ting , Jiang Xiao , Wang Jin‐Mei , Sun Yin‐Xing , Zhu Yong‐Ming
Published: September 2014

Pd‐catalyzed reaction of 2‐(o‐bromophenyl)‐indoles with isocyanides affords isoindoloindolones [cf.
ChemInform Abstract: Catalysis by Amberlyst A‐21: A Greener Approach to 4,5,6,7‐Tetrahydro‐1H‐indazol‐3(2H)‐ones via Construction of Cyclohexanones.
Authors: Rao Manam Sreenivasa , Haritha Meda , Kolli Sunder Kumar , Basaveswara Rao Mandava V. , Pal Manojit
Published: September 2014

The title compounds (III) are obtained via a two‐step one‐pot synthesis involving the construction of the cyclohexanone ring from aromatic aldehydes and β‐ketoesters as initial step under mild reaction conditions.
ChemInform Abstract: A Novel Atom‐Economic Synthesis of Functionalized Imidazolidines Through Copper(I)‐Catalyzed Domino Three‐Component Coupling and Cyclization Reactions.
Authors: Li Yufeng , Wu Zhengguang , Shi Jie , Bu Hongzhong , Gu Jiachao , Pan Yi
Published: September 2014

Transformation of (I) with phenyl or trimethylsilylacetylene, respectively, leads to propargylamine intermediates instead of the desired imidazolidines.
ChemInform Abstract: One‐Pot Synthesis of Benzimidazoles in Water in the Presence of SiO2—OPO3H.
Authors: Mirjalili B. F. , Bamoniri A. , Rahimi Kazerouni M.
Published: September 2014

Silica‐bound phosphoric acid is used for the synthesis of benzimidazoles from o‐phenylenediamine and aldehydes.
ChemInform Abstract: An Efficient and Green Procedure for Synthesis of Rhodanine Derivatives by Aldol‐Thia‐Michael Protocol Using Aqueous Diethylamine Medium.
Authors: Barakat Assem , Al‐Majid Abdullah M. , AL‐Najjar Hany J. , Mabkhot Yahia N. , Ghabbour Hazem A. , Fun Hoong‐Kun
Published: September 2014

A general procedure for the condensation of rhodanione (I) with aromatic aldehydes is developed.
ChemInform Abstract: A Simple, Efficient Thermally Promoted Protocol for Huisgen‐Click Reaction Catalyzed by CuSO4·5H2O in Water.
Authors: Jiang Yuqin , Kong Duanyang , Zhao Jinglin , Zhang Weiwei , Xu Wenjing , Li Wei , Xu Guiqing
Published: September 2014

A one‐pot three‐component reaction between alkyl chlorides, sodium azide and terminal alkynes is also reported.
ChemInform Abstract: Microwave‐Assisted Azide‐Alkyne Cycloaddition in Water Using a Heterogeneous Cu‐Catalyst.
Authors: Jacob Katharina , Stolle Achim
Published: September 2014

Several triazoles are synthesized by a Cu‐catalyzed cycloaddition of azides and alkynes.
ChemInform Abstract: Synthesis of Pyranopyrazoles Using Magnetic Fe3O4 Nanoparticles as Efficient and Reusable Catalyst.
Authors: El‐Remaily M. Abd. El Aleem. Ali. Ali.
Published: September 2014

Pyranopyrazoles are prepared within a few minutes via a four‐component reaction of malononitrile, hydrazine hydrate, ethyl acetoacetate and carbonyl compounds in water as green solvent.
ChemInform Abstract: Synthesis of 3‐(2‐(4‐Chlorophenylimino)‐3‐ (4‐chlorophenyl)‐2,3‐dihydrothiazol‐4‐yl)‐2H‐chromen‐2‐one via Multicomponent Approach.
Authors: Ramagiri Raj Kumar , Vedula Rajeswar Rao
Published: September 2014

A one‐pot, three‐component method for the synthesis of the title compounds is reported.
ChemInform Abstract: Efficient One‐Pot Synthesis of 3‐Amino‐7‐azaindoles under Microwave Irradiation.
Authors: Yang Hai‐Kui , You Wen‐Wei , Yan Guang‐Hua , Jiang Zhi‐Hong , Zhao Pei‐Liang , Zhou Zhong‐Zhen
Published: September 2014

Title compounds (III) are obtained in a microwave‐assisted Thorpe—Ziegler cyclization of carbamates (I) and various α‐bromoketones (II).
ChemInform Abstract: One‐Pot Microwave‐Assisted Synthesis of 3,4‐Disubstituted 2‐Quinolinones.
Authors: Bui Chinh T.
Published: September 2014

The title compounds are effectively obtained from various substituted benzophenones or ketones and acid chlorides under classical thermal or microwave irradiation conditions.
ChemInform Abstract: rac‐BINAP‐PdCl2 Catalyzed Heck Reactions of 3‐Formylquinolin‐2‐yl Chlorides with Methyl Acrylate: Synthesis of Methyl 3‐(3‐Formylquinolin‐2‐yl) Acrylates.
Authors: Sharma Neha , Asthana Mrityunjaya , Kumar Ritush , Mishra Kalpana , Singh Radhey M.
Published: September 2014

Under optimized conditions, the title process affords the coupling products in good yields.
ChemInform Abstract: A Silver(I) Triflate‐Catalyzed Reaction of 1‐((Cyclopropylidenemethyl)‐2‐alkynyl)arene with 2‐Alkynylbenzaldoxime.
Authors: Sheng Jie , Fan Congbin , Ding Yechun , Fan Xiaona , Wu Jie
Published: September 2014

The title reaction offers a facile route to afford dihydroisobenzofuran‐1‐yl‐substituted isoquinolines through a radical process.
ChemInform Abstract: Diastereoselective One‐Pot Synthesis of Novel ABCD‐Fused Chromeno[2,3‐d]pyrazolo[3,4‐b]pyridines.
Authors: Dimitriadou Eleni , Stephanidou‐Stephanatou Julia , Tsoleridis Constantinos A. , Hadjipavlou‐Litina Dimitra J. , Kontogiorgis Christos , Kostakis George E.
Published: September 2014

Title compounds (IV) (11 examples) are obtained via a diastereo‐ and regioselective three‐component, one‐pot reaction.
ChemInform Abstract: A Novel and Efficient Synthesis of δ‐Sultones
Authors: Rad‐Moghadam Kurosh , Roudsari Saeedeh Toorchi , Sheykhan Mehdi
Published: September 2014

via self‐condensation of acetophenones catalyzed by methyl(sulfonyl)imidazolium triflate hydrochloride
ChemInform Abstract: Mild and Direct Access to 7‐Substituted‐4‐trifluoromethylpyrimido[1,2‐b]pyridazin‐2‐one Systems.
Authors: Petrignet Julien , Thiery Emilie , Silpa Laurence , Abarbri Mohamed
Published: September 2014

Aniline and diisopropylamine are found to be unreactive in the transformation with (VI).
ChemInform Abstract: Structural Optimization of Cyclic Sulfonamide Based Novel HIV‐1 Protease Inhibitors to Picomolar Affinities Guided by X‐Ray Crystallographic Analysis.
Authors: Ganguly Ashit K. , et al. et al.
Published: September 2014

Novel cyclic sulfonamide‐based inhibitors of HIV‐1 protease are designed, synthesis and evaluated for their activity.
ChemInform Abstract: Synthesis of a Guanidine NHC Complex and Its Application in Borylation Reactions.
Authors: Tai Chia‐Cheng , Yu Ming‐Shiuan , Chen Yi‐Lin , Chuang Wen‐Hang , Lin Ting‐Hua , Yap Glenn P. A. , Ong Tiow‐Gan
Published: September 2014

The title catalyst is successfully applied to hydroboration, semihydroboration, and carboboration of alkynes with high stereo‐ and regioselectivity by using MeOH or H2O as hydrogen source.
ChemInform Abstract: Efficient Visible Light‐Mediated Cross‐Dehydrogenative Coupling Reactions of Tertiary Amines Catalyzed by a Polymer‐Immobilized Iridium‐Based Photocatalyst.
Authors: Yoo Woo‐Jin , Kobayashi Shu
Published: September 2014

The polymer‐immobilized iridium‐based catalyst is synthesized by a previously reported method by using ethylene glycol dimethacrylate and benzyl methacrylate and the Ir‐based monomer (IRC).
ChemInform Abstract: Synthesis and Derivatization of Highly‐Functionalized λ5‐Phospholes.
Authors: Ruiz Javier , Gonzalo Marta P. , Vivanco Marilin , Garcia‐Granda Santiago
Published: September 2014

A variety of highly functionalized λ5‐phosphole derivatives are synthesized by regiospecific [3 + 2] cycloaddition reactions of diphosphinoketenimine (I) with electron‐poor alkenes.
ChemInform Abstract: Efficient Transformation of 7,14‐Dihydroxy‐ent‐kaurenes to Novel ent‐Abietanes Having cis‐Fused α‐Methylene γ‐Lactones under Mitsunobu Reaction Conditions and Their Cytotoxicities.
Authors: Aoyagi Yutaka , et al. et al.
Published: September 2014

Cytoxicity assays (murine P388 leukemia calls, MTT assay) show same activities of semi‐synthetic ent‐abietanes such as (II) and the natural ent‐kaurenes excisanin, rabdokunmin, kamebanin and kamebakaurin.
ChemInform Abstract: Topsendines A—F, New 3‐Alkylpyridine Alkaloids from a Hainan Sponge Topsentia sp.
Authors: Sun Ji‐Zheng , Jiang Cheng‐Shi , Chen Xue‐Qin , Chen Kao‐Shan , Zhen Xue‐Chu , van Soest Rob W. M. , Guo Yue‐Wei
Published: September 2014

Topsendine A (Ia), B (Ib), C (IV), D (IIa), E (III) and F (IIb) as well as 2‐methyl‐12‐(pyridine‐3‐yl)dodecanal (IIc) are isolated and their structures are elucidated.
ChemInform Abstract: Synthesis of 2‐(4‐Isopropylthiazol‐2‐yl)‐7‐methoxy‐8‐methylquinolin‐4‐ol; a Quinoline Building Block for Simeprevir Synthesis.
Authors: Radl Stanislav , Rezkova Hana , Obadalova Iva , Srbek Jan , Brichac Jiri , Pekarek Tomas
Published: September 2014

Two different approaches to the title compound which is a building block of the drug candidate simeprevir with specific HCV protease inhibitory activity are described.
ChemInform Abstract: Nanochemistry‐Derived Bi2WO6 Nanostructures: Towards Production of Sustainable Chemicals and Fuels Induced by Visible Light
Authors: Zhang Nan , Ciriminna Rosaria , Pagliaro Mario , Xu Yi‐Jun
Published: September 2014

Review: 132 refs.
ChemInform Abstract: Biosynthesis of Silver Nanoparticles
Authors: Silambarasan Sivagnanam , Abraham Jayanthi
Published: September 2014

Review: 98 refs.
ChemInform Abstract: Preparation and Characterization of Some Metal Complexes with Synthesized Ligand of Derived Schiff′s Base‐a‐Review
Authors: Singh R. K. , Neetu Neetu , Thakur K. N.
Published: September 2014

Review: 29 refs.
ChemInform Abstract: Review of Recent Advances in Nucleophilic C—F Bond‐Forming Reactions at sp3 Centers
Authors: Wu Jimmy
Published: September 2014

Review: 77 refs.
ChemInform Abstract: Catalytic Asymmetric Nucleophilic Openings of 3‐Substituted Oxetanes
Authors: Wang Zhaobin , Chen Zhilong , Sun Jianwei
Published: September 2014

Review: [10 refs.
ChemInform Abstract: Organic Synthetic Transformations Using Organic Dyes as Photoredox Catalysts
Authors: Fukuzumi Shunichi , Ohkubo Kei
Published: September 2014

Review: 117 refs.
ChemInform Abstract: Arenes and Hetarenes in Reactions with Unsaturated Nitro Compounds
Authors: Smirnov A. N. , Aksenov N. A. , Malikova I. V. , Aksenov A. V.
Published: September 2014

Review: 96 refs.
ChemInform Abstract: Synthesis and Transformations of Naphtho[2,3‐b]furans
Authors: Uchuskin M. G. , Shcherbinin V. A. , Butin A. V.
Published: September 2014

Review: 69 refs.
ChemInform Abstract: Synthesis of Nitrogen‐Containing Heterocycles from Nitroarenes
Authors: Kotov A. D. , Prokaznikov M. A. , Antonova E. A. , Rusakov A. I.
Published: September 2014

Review: 31 refs.