bluuebunny/crossref_metadata_2025 huggingface dataset:
On the Multi-Functional Behavior of Graphene-Based Nano-Reinforced Polymers
Authors: Zafeiropoulou Konstantina , Kostagiannakopoulou Christina , Geitona Anna , Tsilimigkra Xenia , Sotiriadis George , Kostopoulos Vassilis
Published: October 2021

The objective of the present study is the assessment of the impact performance and the concluded thermal conductivity of epoxy resin reinforced by layered Graphene Nano-Platelets (GNPs). The two types of used GNPs have different average thicknesses, <4 nm for Type 1 and 9–12 nm for Type 2. Graphene-based polymers containing different GNP loading contents (0.5, 1, 5, 10, 15 wt.%) were developed by using the three-roll mill technique. Thermo-mechanical (Tg), impact tests and thermal conductivity measurements were performed to evaluate the effect of GNPs content and type on the final properties of nano-reinforced polymers. According to the results, thinner GNPs were proven to be more promising in all studied properties when compared to thicker GNPs of the same weight content. More specifically, the glass transition temperature of nano-reinforced polymers remained almost unaffected by the GNPs inclusion. Regarding the impact tests, it was found that the impact resistance of the doped materials increased up to 50% when 0.5 wt.% Type 1 GNPs were incorporated within the polymer. Finally, the thermal conductivity of doped polymers with 15 wt.% GNPs showed a 130% enhancement over the reference material.
Effect of Different Root Canal Irrigant Solutions on the Release of Dentin-Growth Factors: A Systematic Review and Meta-Analysis
Authors: Tavares Sandro , Pintor Andrea , Mourão Carlos Fernando de Almeida Barros , Magno Marcela , Montemezzi Pietro , Sacco Roberto , Alves Gutemberg , Scelza Miriam Zaccaro
Published: October 2021

Irrigant solutions are used to promote dentin-growth factors (GF) release for regenerative endodontics. This review aimed to evaluate the reports comparing the release of GFs using different root canal irrigant solutions. Eligible studies compared the in vitro GF release in human teeth after the use of at least two distinct solutions. A search was conducted on Pubmed, Scopus, Web of Science, and Lilacs on 11 August 2021. Risk of bias was assessed using SciRAP. Study characteristics and quantitative data were extracted, and meta-analyses were performed for the mean difference (95% confidence interval) of the release of transforming growth factors Beta 1 (TGF-β1) by EDTA compared to other irrigants. Of sixteen eligible studies, eight were included in quantitative analysis. ELISA assays showed higher TGF-β1 release from 10% EDTA compared to 10% citric acid (p < 0.00001). Immunogold assays showed higher levels of TGF-β1 for 17% EDTA (p < 0.00001) compared to 10% citric acid. GRADE identified a low to very low certainty of evidence. These results point to an increased release of TGF-β1 in dentin treated with EDTA. The high heterogeneity and very low certainty of the evidence demand further studies before EDTA indication as a better irrigant for regenerative endodontics. Registration: CRD42020160871 (PROSPERO).
Effect of Printing Parameters on Mechanical Behaviour of PLA-Flax Printed Structures by Fused Deposition Modelling
Authors: Belarbi Yassine Elias , Guessasma Sofiane , Belhabib Sofiane , Benmahiddine Ferhat , Hamami Ameur El Amine
Published: October 2021

Few studies have reported the performance of Polylactic acid (PLA) flax feedstock composite for additive manufacturing. In this work, we report a set of experiments conducted by fused filament technology on PLA and PLA-flax with the aim of drawing a clear picture of the potential of PLA-flax as a feedstock material. Nozzle and bed temperatures are both combined with the printing angle to investigate their influence on structural and mechanical properties. The study shows a low sensitivity of PLA-flax to process parameters compared to PLA. A varied balance between shearing and uniaxial deformation is found consistent with tensile results where filament crossing at −45/+45° provides the optimal load-bearing capabilities. However, Scanning Electron Microscopy (SEM) and high-speed camera recording shows a limiting reinforcing effect of flax fibre due to the presence of intra-filament porosity and a significant amount of fibre pull-out resulting from the tensile loading. These results suggest that the quality of the bond between PLA matrix and flax fibre, intra-filament porosity, and surface roughness should receive more attention as well as the need for more continuous fibre reinforcement in PLA filaments to optimise the performance of PLA-flax printed materials.
Estimation of the Plastic Zone in Fatigue via Micro-Indentation
Authors: Lopez-Crespo Cristina , Cruces Alejandro S. , Seitl Stanislav , Moreno Belen , Lopez-Crespo Pablo
Published: October 2021

Accurate knowledge of the plastic zone of fatigue cracks is a very direct and effective way to quantify the damage of components subjected to cyclic loads. In this work, we propose an ultra-fine experimental characterisation of the plastic zone based on Vickers micro-indentations. The methodology is applied to different compact tension (CT) specimens made of aluminium alloy 2024-T351 subjected to increasing stress intensity factors. The experimental work and sensitivity analysis showed that polishing the surface to #3 μm surface finish and applying a 25 g-force load for 15 s produced the best results in terms of resolution and quality of the data. The methodology allowed the size and shape of both the cyclic and the monotonic plastic zones to be visualised through 2D contour maps. Comparison with Westergaard’s analytical model indicates that the methodology, in general, overestimates the plastic zone. Comparison with S355 low carbon steel suggests that the methodology works best for alloys exhibiting a high strain hardening ratio.
Comparison of Microstructure and Mechanical Properties of High Strength and Toughness Ship Plate Steel
Authors: Wang Dong , Zhang Peng , Peng Xingdong , Yan Ling , Li Guanglong
Published: October 2021

E36 ship plate steel was, respectively, produced by as rolling and normalizing process (ARNP), and EH36 and FH36 ship plate steel was produced by the thermo-mechanical control process (TMCP) with low carbon and multi-element micro-alloying. The microstructure of the three grades of ship plate steel was composed of ferrite, pearlite, and carbides at room temperature. The average grain size on 1/4 width sections (i.e., longitudinal sections) of the three grades of ship plate steel was, respectively, 5.4 μm, 10.8 μm, and 11.9 μm. EH36 and FH36 ship plate steel had the higher strength due to precipitation and grain boundary strengthening effect, while the E36 ship plate steel had the lower strength due to the recovery phenomenon in the normalizing process. EH36 and FH36 ship plate steel had higher impact toughness due to lower carbon (C) and silicon (Si) content and higher manganese (Mn) content than E36 ship plate steel. E36 ship plate steel had the best plasticity due to the two strong {110} and {111} texture components. The fracture toughness KJ0.2BL(30) values of E36 and EH36 and KJ0.2BL value of FH36 ship plate steel were, respectively, obtained at 387 MPa·m1/2, 464 MPa·m1/2 and 443 MPa·m1/2. EH36 and FH36 ship plate steel had higher KJ0.2BL(30) due to lower C and Si and higher Mn, niobium (Nb), vanadium (V), and aluminum (Al) content than the E36 ship plate steel. The fatigue crack growth rate of E36 ship plate steel was higher than that of EH36 and FH36 ship plate steel due to its higher carbon content and obviously smaller grain size. The analysis results and data may provide a necessary experimental basis for quantitatively establishing the relationship between fracture toughness, yield strength and impact toughness, as well as the relationship between fatigue crack growth rate and both strength and fracture toughness.
Viscoelastic Damage Characteristics of Asphalt Mixtures Using Fractional Rheology
Authors: Zhang Qipeng , Gu Xingyu , Yu Zilu , Liang Jia , Dong Qiao
Published: October 2021

The mechanical behavior of asphalt mixtures at high stress levels are characterized by non-linear viscoelasticity and damage evolution. A nonlinear damage constitutive model considering the existence of creep hardening and creep damage mechanisms in the entire creep process is proposed in this study by adopting the fractional rheology theory to characterize the three-stage creep process of mixtures. A series of uniaxial compressive creep tests under various stresses were conducted at different temperatures to verify the model. The results indicated that the model predictions were in good agreement with the creep tests. The relationship between the model parameters and applied stresses was established, and the stress range in which the mixture exhibited only creep consolidation was obtained. The damage to the asphalt mixture was initiated in the steady stage; however, it developed in the tertiary stage. A two-parameter Weibull distribution function was used to describe the evolution between the damage values and damage strains at different stress levels and temperatures. The correlation coefficients were greater than 0.99 at different temperatures, indicating that a unified damage evolution model could be established. Thus, the parameters of the unified model were related to material properties and temperature, independent of the stress levels applied to the mixtures.
Trivalent Ions and Their Impacts on Effective Conductivity at 300 K and Radio-Protective Behaviors of Bismo-Borate Glasses: A Comparative Investigation for Al, Y, Nd, Sm, Eu
Authors: ALMisned Ghada , Tekin Huseyin O. , Bilal Ghaida , Ene Antoaneta , Kilic Gokhan , Issa Shams A. M. , Algethami Merfat , Zakaly Hesham M. H.
Published: October 2021

We aimed to determine the contribution of various trivalent ions like Al and rare-earths (Y, Nd, Sm, Eu) on resistance behaviors of different types of bismo-borate glasses. Accordingly, eight different bismuth borate glasses from the system: 40Bi2O3–59B2O3–1Tv2O3 (where Tv = Al, Y, Nd, Sm, and Eu) and three glasses of (40Bi2O3–60B2O3; 37.5Bi2O3–62.5B2O3; and 38Bi2O3–60B2O3–2Al2O3) compositions were extensively investigated in terms of their nuclear attenuation shielding properties, along with effective conductivity and buildup factors. The Py-MLBUF online platform was also utilized for determination of some essential parameters. Next, attenuation coefficients, along with half and tenth value layers, have been determined in the 0.015 MeV–15 MeV photon energy range. Moreover, effective atomic numbers and effective atomic weight, along with exposure and energy absorption buildup factors, were determined in the same energy range. The result showed that the type of trivalent ion has a direct effect on behaviors of bismo-borate glasses against ionizing gamma-rays. As incident photon energy increases, the effective thermal conductivity decreases rapidly, especially in the low energy range, where photoelectric effects dominate the photon–matter interaction. Sample 8 had the minimum heat conductivity at low photon energies; our findings showed that Eu-reinforced bismo-borate glass composition, namely 40Bi2O3–59B2O3–1Eu2O3, with a glass density of 6.328 g/cm3 had superior gamma-ray attenuation properties. These outcomes would be useful for the scientific community to observe the most suitable additive rareearth type and related glass composition for providing the aforementioned shielding properties, in terms of needs and utilization requirements.
Corrosion Performance of Nano-TiO2-Modified Concrete under a Dry–Wet Sulfate Environment
Authors: Xu Chao , Liao Hao-Hao , Chen You-Liang , Du Xi , Peng Bin , Fernandez-Steeger Tomas Manuel
Published: October 2021

This study compared the effects of the sulfate dry–wet cycle on the properties of ordinary concrete and nano-TiO2-modified concrete, including the mass loss rate, ultrasonic wave velocity, compressive strength, and XRD characteristics. In addition, a series of compression simulations carried out using the PFC2D software are also presented for comparison. The results show the following: (1) with an increase in dry–wet cycles, the damage to the concrete gradually increased, and adding nano-TiO2 into ordinary concrete can improve the material’s sulfate resistance; (2) after 50 sulfate dry–wet cycles, the mass loss rate of ordinary concrete was –3.744%, while that of nano-TiO2-modified concrete was −1.363%; (3) the compressive strength of ordinary concrete was reduced from 41.53 to 25.12 MPa (a reduction of 39.51%), but the compressive strength of nano-TiO2-modified concrete was reduced from 49.91 to 32.12 MPa (a reduction of 35.64%); (4) after a sulfate dry–wet cycle, the nano-TiO2-modified concrete surface produced white crystalline products, considered to be ettringite based on the XRD analysis; (5) when considering the peak stress and strain of the concrete samples, the numerical results agreed well with the test results, indicating the reliability of the method.
Electrochromism of Viologen/Polymer Composite: From Gel to Insulating Bulk for High-Voltage Applications
Authors: Nie Yongjie , Zhang Meng , Zhu Yuanwei , Jing Yu , Shi Wenli , Li Guoping , Chen Haopeng , Jiang Yihang , Zhao Xianping , Zhao Tengfei , Lu Guanghao , Li Shengtao
Published: October 2021

Power equipment operates under high voltages, inducing space charge accumulation on the surface of key insulating structures, which increases the risk of discharge/breakdown and the possibility of maintenance workers experiencing electric shock accidents. Hence, a visualized non-equipment space charge detection method is of great demand in the power industry. Typical electrochromic phenomenon is based on redox of the material, triggered by a voltage smaller than 5 V with a continuous current in μA~mA level, which is not applicable to high electric fields above 106 V/m with pA~nA operation current in power equipment. Until now, no naked-eye observation technique has been realized for space charge detection to ensure the operation of power systems as well as the safety of maintenance workers. In this work, a viologen/poly(vinylidene fluoride-co-hexafluoropropylene)(P(VDF–HFP)) composite is investigated from gel to insulating bulk configurations to achieve high-voltage electrical-insulating electrochromism. The results show that viologen/P(VDF–HFP) composite bulk can withstand high electric fields at the 107 V/m level, and its electrochromism is triggered by space charges. This electrochromism phenomenon can be visually extended by increasing viologen content towards 5 wt.% and shows a positive response to voltage amplitude and application duration. As viologen/P(VDF–HFP) composite bulk exhibits a typical electrical insulating performance, it could be attached to the surface of insulating structures or clamped between metal and insulating materials as a space charge accumulation indicator in high-voltage power equipment.
Analysis and Prediction of Sulfate Erosion Damage of Concrete in Service Tunnel Based on ARIMA Model
Authors: Liu Dunwen , Chen Haofei , Tang Yu , Gong Chun , Jian Yinghua , Cao Kunpeng
Published: October 2021

Sulfate erosion is a major cause of concrete durability deteriorations, especially for the service tunnels that suffer sulfate erosion for a long time. Accurately predicting the concrete damage failure under sulfate erosion has been a challenging problem in the evaluation and maintenance of concrete structures. Here we design the dry–wet cycle test of service tunnel concrete under sulfate erosion and analyze the Elastic relative dynamic modulus (Erd) and mass under 35 times cycle periods. Then we develop an autoregressive integrated moving average (ARIMA) prediction model linking damage failure to Erd and mass. The results show that the deterioration of concrete first increased and then decreased with an extension of the dry–wet cycle period. Moreover, based on a finite set of training data, the proposed prediction approach shows high accuracy for the changes of concrete damage failure parameters in or out of the training dataset. The ARIMA method is proven to be feasible and efficient for predicting the concrete damage failure of service tunnels under sulfate erosion for a long time.
Modelling of SMA Vibration Systems in an AVA Example
Authors: Rączka Waldemar , Konieczny Jarosław , Sibielak Marek
Published: October 2021

Vibration suppression, as well as its generation, is a common subject of scientific investigations. More and more often, but still rarely, shape memory alloys (SMAs) are used in vibrating systems, despite the fact that SMA springs have many advantages. This is due to the difficulty of the mathematical description and the considerable effortfulness of analysing and synthesising vibrating systems. The article shows the analysis of vibrating systems in which spring elements made of SMAs are used. The modelling and analysis method of vibrating systems is shown in the example of a vibrating system with a dynamic vibration absorber (DVA), which uses springs made of a shape memory alloy. The formulated mathematical model of a 2-DOF system with a controlled spring, mounted in DVA suspension, uses the viscoelastic model of the SMA spring. For the object, a control system was synthesised. Finally, model tests with and without a controller were carried out. The characteristics of the vibrations’ transmissibility functions for both systems were determined. It was shown that the developed DVA can tune to frequency excitation changes of up to ±10%.
Manufacturing of Closed Impeller for Mechanically Pump Fluid Loop Systems Using Selective Laser Melting Additive Manufacturing Technology
Authors: Adiaconitei Alexandra , Vintila Ionut Sebastian , Mihalache Radu , Paraschiv Alexandru , Frigioescu Tiberius Florian , Popa Ionut Florian , Pambaguian Laurent
Published: October 2021

In the space industry, the market demand for high-pressure mechanically pumped fluid loop (MPFL) systems has increased the interest for integrating advanced technologies in the manufacturing process of critical components with complex geometries. The conventional manufacturing process of a closed impeller encounters different technical challenges, but using additive manufacturing (AM) technology, the small component is printed, fulfilling the quality requirements. This paper presents the Laser Powder Bed Fusion (LPBF) process of a closed impeller designed for a centrifugal pump integrated in an MPFL system with the objective of defining a complete manufacturing process. A set of three closed impellers was manufactured, and each closed impeller was subjected to dimensional accuracy analysis, before and after applying an iterative finishing process for the internal surface area. One of the impellers was validated through non-destructive testing (NDT) activities, and finally, a preliminary balancing was performed for the G2.5 class. The process setup (building orientation and support structure) defined in the current study for a pre-existing geometry of the closed impeller takes full advantages of LPBF technology and represents an important step in the development of complex structural components, increasing the technological readiness level of the AM process for space applications.
The Influence of Surface Quality on Flow Length and Micro-Mechanical Properties of Polycarbonate
Authors: Ovsik Martin , Stanek Michal , Dockal Adam , Fluxa Petr , Chalupa Vlastimil
Published: October 2021

This study describes the influence of polymer flow length on mechanical properties of tested polymer, specifically polycarbonate. The flow length was examined in a spiral shaped mould. The mould cavity’s surface was machined by several methods, which led to differing roughness of the surface. The cavity was finished by milling, grinding and polishing. In order to thoroughly understand the influence of the mould surface quality on the flow length, varying processing parameters, specifically the pressure, were used. The polymer part was divided into several segments, in which the micro-mechanical properties, such as hardness and indentation modulus were measured. The results of this study provide interesting data concerning the flow length, which was up to 3% longer for rougher surfaces, but shorter in cavities with polished surface. These results are in disagreement with the commonly practiced theory, which states that better surface quality leads to greater flow length. Furthermore, evaluation of the micro-mechanical properties measured along the flow path demonstrated significant variance in researched properties, which increased by 35% (indentation hardness) and 86% by indentation modulus) in latter segments of the spiral in comparison with the gate.
Physicochemical Properties of Two Generations of MTA-Based Root Canal Sealers
Authors: Abu Zeid Sawsan , Edrees Hadeel Yaseen , Mokeem Saleh Abeer Abdulaziz , Alothmani Osama S.
Published: October 2021

This study evaluated the physicochemical properties and the effect of solubility on the surface morphology and composition of the root canal sealers MTA-Bioseal, MTA-Fillapex, and Adseal. Discs (n = 10) of freshly mixed sealer were prepared and then analyzed by Fourier transform infrared (FTIR) spectroscopy and scanning electron microscopy/energy-dispersive X-ray spectroscopy (SEM/EDX). The discs were immersed for 1, 7, 14, and 28 days in deionized water. The solubility %; pH change of the solution; and released calcium, phosphate, and silicon were measured for each period. The flowability and film thickness were also evaluated. Changes in the surface morphology and composition after 28 days of immersion were evaluated by SEM/EDX. The data were statistically analyzed by one-way ANOVA at p < 0.05. The FTIR and EDX results revealed similar compositions of MTA-Bioseal and MTA-Fillapex, but with different concentrations. The two MTA-based sealers had higher solution alkalinity (pH > 10) than Adseal (pH ≈ 8.5). MTA-Fillapex exhibited the highest solubility % and the largest calcium and silicon ion release. MTA-Bioseal had the highest phosphate ion release. After 28 days, the sealer surfaces showed large micropores, with larger pores in MTA-Fillapex. Adseal had an intermediate flowability but exhibited the greatest film thickness. Finally, the highest solubility and largest amount of silicon release was exhibited by MTA-Fillapex, which might predispose it to the development of large micropores, compromising the apical seal of obturation.
Study on the Compressive Stress Retention in Quenched Cam of 100Cr6 Steel Based on Coupled Thermomechanical and Metallurgical Modeling
Authors: Chen Jianbin , Zuo Zhidong , Zhou Songze , Wang Xiaofeng , Chen Yonglong , Ling Guoping
Published: October 2021

The assembled camshaft has obvious advantages in material optimization and flexible manufacturing. As the most important surface modification technique, the heat treatment process is utilized in this work to promote the desired compressive residual stress on the near-surface of the 100Cr6 steel assembled cam. The Johnson-Mehl-Avrami equation and Koistinen-Marbuger law are integrated into the ABAQUS software via user subroutines to simulate the evolution of diffusional transformation and diffusionless transformation, respectively. The linear mixture law is used for describing the coupled thermomechanical and metallurgical behaviors in the quenching of steel cam. The influences of various quenchants and the probable maximum phase volume fractions on surface residual stress or hardness are analyzed. Results show that a greater amount of martensite volume fraction and a slower martensitic transformation rate are beneficial for the compressive stress retention. Compared with the conventional quenching oil, the fast oil quenched cam surface has higher final compressive stress and hardness.
Development of Janus Cellulose Acetate Fiber (CA) Membranes for Highly Efficient Oil–Water Separation
Authors: Yu Xiaotian , Zhang Xian , Xing Yajie , Zhang Hongjing , Jiang Wuwei , Zhou Ke , Li Yongqiang
Published: October 2021

A new type of Janus cellulose acetate (CA) fiber membrane was used to separate oil–water emulsions, which was prepared with plasma gas phase grafting by polymerizing octamethylcyclotetrasiloxane (D4) onto a CA fiber membrane prepared by centrifugal spinning. The Janus–CA fiber membrane was described in terms of chemical structure using Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) analysis, energy dispersive X-ray spectroscopy (EDX) analysis and morphology by field emission scanning electron microscopy (FESEM). In this contribution, we examine the influence of spinning solution concentration, spinning speed and nozzle aperture on the centrifugal spinning process and the fiber morphology. Superhydrophobic/hydrophilic Janus–CA fiber membrane was used to separate water and 1,2-dibromoethane mixture and Toluene-in-water emulsion. Unidirectional water transfer Janus–CA fiber membrane was used to separate n-hexane and water mixture. The separation for the first-time interception rate was about 98.81%, 98.76% and 98.73%, respectively. Experimental results revealed that the Janus cellulose acetate (CA) fiber membrane gave a permeate flux of about 43.32, 331.72 and 275.27 L/(m2·h), respectively. The novel Janus–CA fiber membrane can potentially be used for sustainable W/O emulsion separation. We believe that this is a facile strategy for construction of filtration materials for practical oil–water separation.
Formation of Dislocations and Stacking Faults in Embedded Individual Grains during In Situ Tensile Loading of an Austenitic Stainless Steel
Authors: Neding Benjamin , Pagan Darren C. , Hektor Johan , Hedström Peter
Published: October 2021

The formation of stacking faults and dislocations in individual austenite (fcc) grains embedded in a polycrystalline bulk Fe-18Cr-10.5Ni (wt.%) steel was investigated by non-destructive high-energy diffraction microscopy (HEDM) and line profile analysis. The broadening and position of intensity, diffracted from individual grains, were followed during in situ tensile loading up to 0.09 strain. Furthermore, the predominant deformation mechanism of the individual grains as a function of grain orientation was investigated, and the formation of stacking faults was quantified. Grains oriented with [100] along the tensile axis form dislocations at low strains, whilst at higher strains, the formation of stacking faults becomes the dominant deformation mechanism. In contrast, grains oriented with [111] along the tensile axis deform mainly through the formation and slip of dislocations at all strain states. However, the present study also reveals that grain orientation is not sufficient to predict the deformation characteristics of single grains in polycrystalline bulk materials. This is witnessed specifically within one grain oriented with [111] along the tensile axis that deforms through the generation of stacking faults. The reason for this behavior is due to other grain-specific parameters, such as size and local neighborhood.
Raman Spectroscopic Study of TiO2 Nanoparticles’ Effects on the Hemoglobin State in Individual Red Blood Cells
Authors: Perevedentseva Elena , Lin Yu-Chung , Karmenyan Artashes , Wu Kuan-Ting , Lugovtsov Andrei , Shirshin Evgeny , Priezzhev Alexander , Cheng Chia-Liang
Published: October 2021

Titanium dioxide (TiO2) is considered to be a nontoxic material and is widely used in a number of everyday products, such as sunscreen. TiO2 nanoparticles (NP) are also considered as prospective agents for photodynamic therapy and drug delivery. These applications require an understanding of the potential effects of TiO2 on the blood system and its components upon administration. In the presented work, we analyze the interaction of TiO2 nanoparticles of different crystal phases (anatase and rutile) with individual rat Red Blood Cells (RBC) and the TiO2 influence on the oxygenation state and functionality of RBC, estimated via analysis of Raman spectra of Hemoglobin (Hb) and their distribution along individual RBC. Raman spectral signals also allow localization of the TiO2 NP on the RBC. No penetration of the NP inside RBC was observed; however, both kinds of TiO2 NP adsorbed on the RBC membrane can affect the Hb state. Mechanisms involving the NP–membrane–Hb interaction, resulting in partial deoxygenation of Hb and TiO2 photothermal effect on Hb under Raman laser excitation, are suggested. The possible influence on the safety of TiO2 use in advanced medical application, especially on the safety and efficiency of photothermal therapy, is discussed.
Acetone Sensing and Catalytic Conversion by Pd-Loaded SnO2
Authors: Gschwend Pascal M. , Schenk Florian M. , Gogos Alexander , Pratsinis Sotiris E.
Published: October 2021

Noble metal additives are widely used to improve the performance of metal oxide gas sensors, most prominently with palladium on tin oxide. Here, we photodeposit different quantities of Pd (0–3 mol%) onto nanostructured SnO2 and determine their effect on sensing acetone, a critical tracer of lipolysis by breath analysis. We focus on understanding the effect of operating temperature on acetone sensing performance (sensitivity and response/recovery times) and its relationship to catalytic oxidation of acetone through a packed bed of such Pd-loaded SnO2. The addition of Pd can either boost or deteriorate the sensing performance, depending on its loading and operating temperature. The sensor performance is optimal at Pd loadings of less than 0.2 mol% and operating temperatures of 200–262.5 °C, where acetone conversion is around 50%.
Properties of Structural Lightweight Aggregate Concrete Based on Sintered Fly Ash and Modified with Exfoliated Vermiculite
Authors: Przychodzień Patrycja , Katzer Jacek
Published: October 2021

Despite the undoubted advantages of using lightweight concrete, its actual use for structural elements is still relatively small in comparison to ordinary concrete. One of the reasons is the wide range of densities and properties of lightweight aggregates available on the market. As a part of the research, properties of concrete based on sintered fly ash were determined. The ash, due to its relatively high density is suitable to be used as a filler for structural concretes. Concrete was based on a mixture of sintered fly ash and exfoliated vermiculite aggregate also tested. The purpose of the research was to determine the possibility of using sintered fly ash as alternative aggregate in structural concrete and the impact of sintered fly ash lightweight aggregate on its physical, mechanical and durability properties. Conducted tests were executed according to European and Polish standards. Created concretes were characterized by compressive strength and tensile strength ranging from 20.3 MPa to 54.2 MPa and from 2.4 MPa to 3.8 MPa, respectively. The lightest of created concretes reached the apparent density of 1378 kg/m3.
The Stability Analysis of Periodic Beams Interacting with Periodic Elastic Foundation with the Use of the Tolerance Averaging Technique
Authors: Marczak Jakub , Jędrysiak Jarosław
Published: October 2021

In this paper a stability analysis of microperiodic beams resting on the periodic inhomogeneous foundation is carried out. The main issue of this considerations, which is the analytical solution to the governing equations characterised by periodic, highly oscillating and non-continuous coefficients, is overwhelmed by the application of the tolerance averaging technique. As a result of such application, the governing equation is transformed into a form with constant coefficients which can be solved using well-known mathematical methods. In several calculation examples, the convergence of the results of two derived averaged models is examined, as well as the convergence of the lowest value of the critical force parameter derived from the averaged models with the FEM model. The results prove the superiority of the presented analytical solution over the FEM analysis in the optimisation process.
Thermal Analysis-Based Field Validation of the Deformation of a Recycled Base Course Made with Innovative Road Binder
Authors: Mazurek Grzegorz , Buczyński Przemysław , Iwański Marek , Podsiadło Marcin
Published: October 2021

The deformation of the cold recycled mixture with foamed bitumen in a recycled base with an innovative three-component road binder and foamed bitumen is analysed. Numerical simulation results for the pavement constructed, based on laboratory test results, were verified against the data from the monitoring system installed on the road trial section. In addition, environmental effects, such as air temperature and humidity levels in the pavement structure layers, were considered. Thermal analyses were conducted to identify the thermal properties of the pavement materials under steady heat transfer rate. Determining temperature distribution in the road cross-section in combination with relaxation functions determined for individual pavement layers contributed to the high effectiveness of the numerical simulation of deformation and displacement in the recycled base and the entire pavement. The experimental method of identifying thermal properties allows a fast and satisfactory prediction of temperature distribution in the pavement cross-section.
X-ray Imaging and Computed Tomography for the Identification of Geometry and Construction Elements in the Structure of Old Violins
Authors: Stanciu Mariana Domnica , Mihălcică Mircea , Dinulică Florin , Nauncef Alina Maria , Purdoiu Robert , Lăcătuș Radu , Gliga Ghiorghe Vasile
Published: October 2021

Numerous studies on heritage violins have shown that there are a number of factors that contribute to the acoustic quality of old violins. Among them are the geometric shape of the violin, the thickness of the tiles, the arching of the tiles, the dimensions and position of the bass bar, the size and position of the acoustic holes. Thus, the paper aims to compare the structural and constructive elements of old violins made in various famous violin workshops (Stainer, Klotz, Leeb, Babos Bela), using nondestructive and noncontact techniques based on image analysis. The violins that were studied date from 1716 to 1920, being in good condition, most of them being used by artists from the Brașov Philharmonic of Romania. In the first stage of the study, the violins were optically analyzed and scanned to identify the structure of the resonant wood, using the WinDENDRO Density 2007 program. X-ray imaging and computed tomography (CT) were also used. Combining the types of analyses, capitalizing on the expertise of violin producers and the knowledge of researchers in the field, valuable data on the geometric and constructive characteristics of old violins were extracted.
Investigation of Electromechanical Properties on 3-D Printed Piezoelectric Composite Scaffold Structures
Authors: Sebastian Tutu , Bach Miriam , Geiger Andreas , Lusiola Tony , Kozielski Lucjan , Clemens Frank
Published: October 2021

Piezoelectric composites with 3-3 connectivity gathered attraction due to their potential application as an acoustic transducer in medical imaging, non-destructive testing, etc. In this contribution, piezoelectric composites were fabricated with a material extrusion-based additive manufacturing process (MEX), also well-known under the names fused deposition modeling (FDM), fused filament fabrication (FFF) or fused deposition ceramics (FDC). Thermoplastic filaments were used to achieve open and offset printed piezoelectric scaffold structures. Both scaffold structures were printed, debinded and sintered successfully using commercial PZT and BaTiO3 powder. For the first time, it could be demonstrated, that using the MEX processing method, closed pore ferroelectric structure can be achieved without pore-former additive. After ceramic processing, the PZT scaffold structures were impregnated with epoxy resin to convert them into composites with 3-3 connectivity. A series of composites with varying ceramic content were achieved by changing the infill parameter during the 3D printing process systematically, and their electromechanical properties were investigated using the electromechanical aix PES device. Also, the Figure of merit (FOM) of these composites was calculated to assess the potential of this material as a candidate for transducer applications. A maximum for the FOM at 25 vol.% of PZT could be observed in this study.
Novel Nano-Precursor Inhibiting Material for Improving Chloride Penetration Resistance of Concrete: Evaluation and Mechanism
Authors: Chen Ruixing , Mu Song , Liu Jiaping , Cai Jingshun , Xie Deqing , Liu Guangyan , Guo Zheng
Published: October 2021

Durability improvement is always important for steel–concrete structures exposed to chloride salt environment. The present research investigated the influence of a novel nano-precursor inhibiting material (NPI), organic carboxylic acid ammonium salt, on the mechanical and transport properties of concrete. The NPI caused a slight reduction in the strength of concrete at later ages. NPI significantly decreased water absorption and slowed down the speed of water absorption of concrete. In addition, the NPI decreased the charge passed and the chloride migration coefficient, and the results of the natural chloride diffusion showed that the NPI decreased the chloride concentration and the chloride diffusion coefficient. The NPI effectively improved the resistance of chloride penetration into testing concrete. The improvement in the impermeability of concrete was ascribed to the incorporation with the NPI, which resulted in increasing the contact angle of cement pastes. The contact angle went up from 17.8° to 85.8° for 0% and 1.2% NPI, respectively, and cement pastes became less hydrophilic. Some small pore throats were unconnected. Besides, the NPI also optimized the pore size distribution of hardened cement paste.
Damage Fracture Characterization of Asphalt Mixtures Considering Freeze–Thaw Cycling and Aging Effects Based on Acoustic Emission Monitoring
Authors: Fu Liuxu , Zhou Huanyun , Yuan Jing , An Weiliang , Chen Xianhua
Published: October 2021

Freeze–thaw (F–T) cycling and aging effects are the main factors contributing to the deterioration of asphalt mixtures. The acoustic emission (AE) technique enables real-time detection regarding the evolution of internal damage in asphalt mixtures during the loading process. This study set out to investigate the effects of F–T cycling and aging on the damage characteristics of asphalt mixture under splitting loads. Firstly, the Marshall specimens were prepared and then exposed to various numbers of F–T cycles (one, three, five, and seven) and different durations of aging (short-term aging and long-term aging for 24, 72, 120 and 168 h), after which the specimens were loaded by means of indirect tensile (IDT) testing, and corresponding parameters were synchronously collected by the AE acquisition system during the fracture process. Finally, the energy, cumulative energy and peak frequency were selected to investigate the damage mechanisms of asphalt mixtures. The findings demonstrate that the AE parameters provided effective identification of the deterioration for all specimens in real-time, and that the F–T cycling and aging effects altered the damage characteristics of asphalt mixtures, causing early damage, exacerbating the formation of micro-cracks in the early stage, accelerating the expansion of macro-cracks and advancing the debonding between the asphalt and aggregates. The findings of this study provide further insight into the mechanism of F–T cycling and aging effects on the deterioration of asphalt mixture.
Strain Acquisition Framework and Novel Bending Evaluation Formulation for Compression-Loaded Composites Using Digital Image Correlation
Authors: D’haen Jonas J. A. , May Michael , Knoll Octavian , Kerscher Stefan , Hiermaier Stefan
Published: October 2021

Consistent and reproducible data are key for material characterization. This work presents digital image correlation (DIC) strain acquisition guidelines for compression-loaded carbon fiber composites. Additionally, a novel bending criterion is formulated which builds up on the DIC strain data so that it is able to completely replace state-of-the-art tactile strain devices. These guidelines are derived from a custom test setup that simultaneously investigates the front and side view of the specimen. They reflect both an observation and post-processing standpoint. It is found that the DIC-based strain progress matches closely with state-of-the-art strain gauges up to failure initiation. The new bending evaluation criterion allows the bending state—and therefore, the validity of the compression test—to be monitored analogously to the methodology defined in the standards. Furthermore, the new bending criterion eliminates a specific bending mode, caused by an offset of clamps, which cannot be detected by the traditional strain gauge-based monitoring approach.
Microstructure and Soil Wear Resistance of D517 Coating Deposited by Electric Spark Deposition
Authors: Wei Min , Wan Qiang , Li Shanjun , Meng Liang , Cao Daocheng , Dai Chaoyue , Huang Yongjun , Xiao Yangyi , Dong Wanjing , Zheng Kan
Published: October 2021

The abrasion failure is the key factor for prolonging the service life and energy saving of furrow openers. The hardness enhancement was reported to be an effective strategy to increase the wear resistance against the soil abrasion. D517 coatings were deposited on Q235 steel by electric spark to improve the wear-resistant property with an affordable cost for farmers. The wear behavior of the coatings was characterized in a pin on disk friction equipment and a homemade soil abrasion simulation system. The soil adhesion, which is highly related to energy consumption, was also evaluated. Results showed that D517 coatings revealed dendrite structure with some randomly distributed carbides. The electric current exerted a great influence on the microstructure, hardness, friction coefficient, and soil wear rate. The wear rate of samples deposited with 80 A and 90 A reduced to 79% and 84%, respectively, as compared with the normalized heat-treated 65 Mn steel after 6 h in soil. This work provides a promising solution to increase the wear resistance of furrow openers. It needs to be noted that the coating would increase the soil adhesion of the opener, which needs to be further explored to decrease the energy consumption.
Evaluation of Mechanical and Permeability Characteristics of Microfiber-Reinforced Recycled Aggregate Concrete with Different Potential Waste Mineral Admixtures
Authors: Alyousef Rayed , Ali Babar , Mohammed Ahmed , Kurda Rawaz , Alabduljabbar Hisham , Riaz Sobia
Published: October 2021

Plain recycled aggregate concrete (RAC) struggles with issues of inferior mechanical strength and durability compared to equivalent natural aggregate concrete (NAC). The durability issues of RAC can be resolved by using mineral admixtures. In addition, the tensile strength deficiency of RAC can be supplemented with fiber reinforcement. In this study, the performance of RAC was evaluated with individual and combined incorporation of microfibers (i.e., glass fibers) and various potential waste mineral admixtures (steel slag, coal fly ash (class F), rice husk ash, and microsilica). The performance of RAC mixtures with fibers and minerals was appraised based on the results of mechanical and permeability-related durability properties. The results showed that generally, all mineral admixtures improved the efficiency of the microfibers in enhancing the mechanical performance of RAC. Notably, synergistic effects were observed in the splitting tensile and flexural strength of RAC due to the combined action of mineral admixtures and fibers. Microsilica and rice husk ash showed superior performance compared to other minerals in the mechanical properties of fiber-reinforced RAC, whereas slag and fly ash incorporation showed superior performance compared to silica fume and husk ash in the workability and chloride penetration resistance of RAC. The combined incorporation of microsilica and glass fibers can produce RAC that is notably stronger and more durable than conventional NAC.
One-Pot Synthesis of TiO2-rGO Photocatalysts for the Degradation of Groundwater Pollutants
Authors: Balsamo Stefano Andrea , Fiorenza Roberto , Condorelli Marcello , Pecoraro Roberta , Brundo Maria Violetta , Lo Presti Francesca , Sciré Salvatore
Published: October 2021

A non-conventional approach to prepare titanium dioxide-reduced graphene oxide (TiO2-rGO) nanocomposites based on solar photoreduction is here presented. The standard hydro-solvothermal synthesis of the TiO2-rGO composites requires high temperatures and several steps, whereas the proposed one-pot preparation allows one to obtain the photocatalysts with a simple and green procedure, by exploiting the photocatalytic properties of titania activated by the solar irradiation. The TiO2-rGO catalysts were tested in the solar photodegradation of a widely adopted toxic herbicide (2,4-Dichlorophenoxyacetic acid, 2,4-D), obtaining the 97% of degradation after 3 h of irradiation. The as-prepared TiO2-rGO composites were more active compared to the same photocatalysts prepared through the conventional thermal route. The structural, optical, and textural properties of the composites, determined by Raman, Photoluminescence, Fourier Transform InfraRed (FTIR), UV-vis diffuse reflectance (DRS) spectroscopies, and N2 absorption-desorption measurements, showed as the solar irradiation favors the reduction of graphene oxide with higher efficiency compared to the thermal-driven synthesis. Furthermore, the possible toxicity of the as-synthesized composites was measured exposing nauplii of microcrustacean Artemia sp. to solutions containing TiO2-rGO. The good results in the 2,4-D degradation process and the easiness of the TiO2-rGO synthesis allow to consider the proposed approach a promising strategy to obtain performing photocatalysts.
Understanding the Microstructure of Mortars for Cultural Heritage Using X-ray CT and MIP
Authors: Brunello Valentina , Canevali Carmen , Corti Cristina , De Kock Tim , Rampazzi Laura , Recchia Sandro , Sansonetti Antonio , Tedeschi Cristina , Cnudde Veerle
Published: October 2021

In this study, the microstructure of mock-up mortar specimens for a historic environment, composed of different mixtures, was studied using mercury intrusion porosity (MIP) and microcomputed tomography (µCT), highlighting the advantages and drawbacks of both techniques. Porosity, sphericity, and pores size distribution were studied, evaluating changes according to mortar composition (aerial and hydraulic binders, quartz sand, and crushed limestone aggregate). The µCT results were rendered using 3D visualization software, which provides complementary information for the interpretation of the data obtained using 3D data-analysis software. Moreover, µCT contributes to the interpretation of MIP results of mortars. On the other hand, MIP showed significant ink-bottle effects in lime and cement mortars samples that should be taken into account when interpreting the results. Moreover, the MIP results highlighted how gypsum mortar samples display a porosity distribution that is best studied using this technique. This multi-analytical approach provides important insights into the interpretation of the porosimetric data obtained. This is crucial in the characterization of mortars and provides key information for the study of building materials and cultural heritage conservation.