bluuebunny/crossref_metadata_2025 huggingface dataset:
Vacuum Heat Treating Processes
Authors: Fradette Real , Osterman Virginia , Jones William R. , Dossett Jon
Published: December 2018

Vacuum heat treating consists of thermally treating metals and alloys in cylindrical steel chambers that have been pumped down to less than normal atmospheric pressure. This article provides a detailed account of the operations and designs of vacuum furnaces, discussing their pressure levels, resistance heating elements, quenching systems, work load support, pumping systems, and temperature control systems. It describes the classification of instruments used for measuring and recording pressure inside a vacuum processing chamber. Common devices include hydrostatic measuring devices and devices for measuring thermal and electrical conductivity. The article also describes the applications of the vacuum heat treating process, namely, vacuum nitriding and vacuum carburizing. Finally, it reviews the heat treating process of tool steels, stainless steels, Inconel 718, and titanium and its alloys.
Heat Treating of Gray Irons
Authors: Dossett J.L. , White C.V.
Published: December 2018

Gray irons are a group of cast irons that form flake graphite during solidification, in contrast to the spheroidal graphite morphology of ductile irons. The heat treatment of gray irons can considerably alter the matrix microstructure with little or no effect on the size and shape of the graphite achieved during casting. This article provides a detailed account of classes of gray iron, and heat treating methods of gray irons with examples. These methods include stress relieving, annealing, normalizing, transformation hardening, austenitizing, quenching, austempering, martempering, flame hardening, induction hardening, and nitriding.
Introduction to Heat Treating of Tool Steels
Authors: Mesquita Rafael A. , Schneider Reinhold E.
Published: December 2018

Tool steels are an important class of steels due to their distinct applications and their specific heat treating issues. This article provides an overview of the classification and production of tool steels, and discusses the procedures and process control requirements for heat treating principal types of tool steels. It reviews the various heat treating processes, namely, normalizing, annealing, stress relieving, austenitizing, quenching, and tempering, and surface treatments and cold treating. The article also provides information on the applicability of these processes to various types of tool steels.
Heat Treating of Air-Hardening High-Strength Structural Steels
Authors: Shan Aidang , Fu Liming
Published: December 2018

Air hardening steel is a type of steel that has deep hardenability and can be hardened in large sections by air cooling.  This article discusses the principles of heat treatment of air-hardening steel, and describes the recommended heat treating practices for air-hardening high-strength structural steels, namely, H11 Mod, H13 steel, 300M steel, D-6A and D-6AC, and AF1410 steel. It also provides information on recommended heat treating practices for air-hardening martensitic stainless steels.
Processes and Furnace Equipment for Heat Treating of Tool Steels
Authors: Schneider R. , Mesquita R. , Altena H. , Müller T. , Seemann P.
Published: December 2018

This article provides a detailed discussion on the heating equipment used for austenitizing, quenching, and tempering tool steels. These include salt bath furnaces, controlled atmosphere furnaces, fluidized-bed furnaces, and vacuum furnaces. The article discusses the types of nitriding and nitrocarburizing processes and the equipment required for heat treating tool steels to improve hardness, wear resistance, and thermal fatigue. The various nitriding and nitrocarburizing processes covered are salt bath nitrocarburizing, gas nitriding and nitrocarburizing, and plasma nitriding and nitrocarburizing.
Low-Temperature Surface Hardening of Stainless Steel
Authors: Somers M.A.J. , Christiansen T.L.
Published: December 2018

Low-temperature surface hardening is mostly applied to austenitic stainless steels when a combination of excellent corrosion performance and wear performance is required. This article provides a brief history of low-temperature surface hardening of stainless steel, followed by a discussion on physical metallurgy, including crystallographic identity, thermal stability and decomposition, nitrogen and carbon solubility in expanded austenite, and diffusion kinetics of interstitials. It provides a description of low-temperature nitriding and nitrocarburizing processes for primarily austenitic and, to a lesser extent, other types of stainless steels along with practical examples and industrial applications of these steels.
Heat Treatment of Powder Metallurgy Steels
Authors: Newkirk Joseph W.
Published: December 2018

Powder metallurgy (PM) processes include press and sinter hardening, metal injection molding, powder forging, hot isostatic pressing, powder rolling, and spray forming. This article provides an overview of PM processing methods and general considerations of heat treatment of PM parts that are case-hardened to obtain higher hardness, wear, fatigue, and impact properties. It describes the effects of porosity on heat treatment, alloy content on PM hardenability, and starting material on homogenization of PM steels. The article describes the properties, following heat treatment, of low-alloy steels tempered at 175 ºC for one hour, and lists recommended quench and temper parameters to achieve good wear resistance and core strength based on different ranges of porosity.
Heat Treating of Cold-Work Tool Steels—Medium-Alloy Air-Hardening, High-Carbon High-Chromium and High-Vanadium-Powder Metallurgy Steels
Authors: Mesquita Rafael Agnelli , Schneider Reinhold S.E. , Gonçalves Cristiane Sales
Published: December 2018

This article focuses on various heat-treating practices, namely, normalizing, annealing, stress relieving, preheating, austenitizing, quenching, tempering, and nitriding for cold-work tool steels. The cold-work tool steels include medium-alloy air-hardening tool steels, high-carbon high-chromium tool steels, and high-vanadium-powder metallurgy tool steels. The article also describes the properties, types, nominal compositions and designations of these cold-work tool steels.
Heat Treating of High-Speed Tool Steels
Authors: Mesquita Rafael Agnelli , Schneider Reinhold , Gonçalves Cristiane Sales
Published: December 2018

This article focuses on various heat treatment practices recommended for different types of high-speed tool steels. Commonly used methods include annealing, stress relieving, preheating, austenitizing, quenching, tempering, carburizing, and nitriding. The article describes hardening for various types of cutting tools, namely, broaches, chasers, milling cutters, drills, taps, reamers, form tools, and hobs, and for thread rolling dies, threading dies, and bearings.
Transfer of Heat and Mass to the Base Metal in Gas-Metal Arc Welding
Authors: Smartt Herschel B.
Published: December 2018

This article provides information on heat and mass transfer from the arc to the base metal in the gas-metal arc welding (GMAW) process. It discusses the development of welding procedures and the general operation of the process. The issues described in this article include the: total heat transferred to the base metal; partitioning of heat transfer between the arc and the molten electrode droplets; transfer modes of the droplets; role of the arc in droplet transfer; and simple model for welding procedure development based on an understanding of heat and mass transfer to the base metal.
Arc Physics of Gas-Tungsten Arc Welding
Authors: Key J.F.
Published: December 2018

The gas-tungsten arc welding (GTAW) process is performed using a welding arc between a nonconsumable tungsten-base electrode and the workpieces to be joined. The arc discharge requires a flow of electrons from the cathode through the arc column to the anode. This article discusses two cases of electron discharge at the cathode: thermionic emission and nonthermionic emission, also called cold cathode, or field emission. It schematically illustrates relative heat transfer contributions to workpiece in the GTAW process. The article provides information on the effects of cathode tip shape and shielding gas composition in the GTAW process.
Introduction to Brazing and Soldering
Authors: Schwartz Mel M.
Published: December 2018

This article presents an introduction to brazing, including information on its mechanics, advantages, and limitations. It reviews soldering with emphasis on chronology, solder metals, and flux technology. The article also provides useful information on mass, wave, and drag soldering. It presents a table which contains information on the comparison of soldering, brazing, and welding.
Fundamentals of Soldering
Authors: Schwartz Mel M.
Published: December 2018

Soldering is defined as a joining process by which two substrates are bonded together using a filler metal with a liquidus temperature. This article provides an overview of fundamentals of soldering and presents guidelines for flux selection. Types of fluxes, including rosin-base fluxes, organic fluxes, inorganic fluxes, and synthetically activated fluxes, are reviewed. The article describes the joint design and precleaning and surface preparation for soldering. It addresses some general considerations in the soldering of electronic devices. Soldering process parameters, affecting wetting and spreading phenomena, such as temperature, time, vapor pressure, metallurgical and chemical nature of the surfaces, and surface geometry, are discussed. The article also describes the applications of furnace soldering, resistance soldering, infrared soldering, and ultrasonic soldering. It contains a table that lists tests commonly used to evaluate the solderability properties of selected soldered components.
Fundamentals of Metal and Metal-to-Ceramic Adhesion
Authors: Dixon Ray , Chen S.P.
Published: December 2018

This article reviews quantifying adhesion, bonding, and interfacial characterization and strength in a solid-state welding process. It discusses metal-metal configurations and provides information on experimental work carried out in measuring the mechanical properties of interfaces based on theoretical analysis. A discussion on the properties affecting adhesion is also provided.
Fundamentals of Diffusion Bonding
Authors: Mahoney Murray W. , Bampton Cliff C.
Published: December 2018

Diffusion bonding is only one of many solid-state joining processes wherein joining is accomplished without the need for a liquid interface (brazing) or the creation of a cast product via melting and resolidification. This article offers a qualitative summary of the theory of diffusion bonding. It discusses factors that affect the relative difficulty of diffusion bonding oxide-bearing surfaces. These include surface roughness prior to welding, mechanical properties of the oxide, relative hardness of the metal and its oxide film, and prestraining or work hardening of the material. The article describes the mechanism of diffusion bonding in terms of microasperity deformation, diffusion-controlled mass transport, and interface migration. It concludes with a discussion on diffusion bonding with interface aids.
Plasma Arc Welding
Authors: Harris Ian D.
Published: December 2018

Plasma arc welding (PAW) can be defined as a gas-shielded arc welding process where the coalescence of metals is achieved via the heat transferred by an arc that is created between a tungsten electrode and a workpiece. This article discusses the melt-in mode and the keyhole mode of the PAW process, as well as the advantages and disadvantages. It describes the components of a basic PAW system, namely the power source, plasma control console, water cooler, welding torch, and gas supply system for the plasma and shielding gases. The article provides information on the applications of the PAW process and discusses the typical components and joints used. It concludes with information on personnel requirements and safety issues.
Submerged Arc Welding
Authors: Ogborn Jonathan S.
Published: December 2018

Submerged arc welding (SAW) is an arc welding process in which the arc is concealed by a blanket of granular and fusible flux. This article provides a schematic illustration of a typical setup for automatic SAW and discusses the advantages and limitations and the process applications of SAW. The article discusses flux classification relative to production method, relative to effect on alloy content of weld deposit, and relative to basicity index. It describes the procedural variations and the effect of weld current, weld voltage, electrical stickout, travel speed, and flux layer depth on weld bead characteristics. The article concludes with information on weld defects, such as lack of fusion, slag entrapment, solidification cracking, hydrogen cracking, or porosity.
Resistance Spot Welding
Authors: Williams Neville T.
Published: December 2018

Resistance spot welding (RSW) is a process in which faying surfaces are joined in one or more spots by the heat generated by resistance to the flow of electric current through workpieces that are held together under force by electrodes. This article discusses the major advantages of spot welding and the three principal elements, such as electrical circuit, control circuit, and mechanical system, of RSW machines. It reviews the three basic types of RSW machines: pedestal-type welding machines, portable welding guns, and multiple spot welding machines. The article provides information on weldabilily of uncoated steels and zinc-coated steels, as well as aluminum alloys.
Flash Welding
Authors: Latimer H.J. , Matteson R.B.
Published: December 2018

Flash welding (FW) is a resistance welding process in which a butt joint weld is produced by a flashing action and by the application of pressure. Flash welding is used to join metallic parts that have similar cross sections in terms of size and shape. This article discusses flash-welding applications, including chain links, transmission bands, automotive flywheel ring gears, aircraft landing gear, band-saw blades, and crankshaft counter weights. It describes the components of a typical flash-welding machine. The article provides information on the electrical controls of flash-welding equipment. These include programmable controllers, welding current controllers, and either motor or servo-valve controllers.
Torch Brazing
Authors: Fuerstenau Charles E.
Published: December 2018

Torch brazing utilizes a fuel gas flame as a heat source for the brazing process. This article discusses the advantages, limitations, applications, and key techniques of torch brazing, and presents an overview of the equipment used.
Induction Brazing
Authors: Libsch J.F.
Published: December 2018

This article begins with a discussion on the principle of induction brazing and addresses applications, advantages, and limitations of the process. It provides information on the induction brazing equipment and solid-state induction generators that are used in induction brazing. The article illustrates several basic joint designs for induction brazing as well as typical coils and some frequent applications and lists joint parameters for parts which are to be brazed by induction heating. It concludes with a discussion on the effect of thermal expansion on stress in the joint.
Torch Soldering
Authors: Fuerstenau Charles E.
Published: December 2018

Torch soldering utilizes a fuel gas flame as the heat source in the soldering process to produce a leak-tight assembly with some degree of mechanical strength. This article describes the advantages, limitations, and applications of torch soldering. It reviews the equipment used and the basic heating techniques required for the soldering.
Furnace and Infrared Soldering
Authors: Zarrow Phil
Published: December 2018

Furnace soldering (FS) encompasses a group of reflow soldering techniques in which the parts to be joined and preplaced filler metal are put in a furnace and then heated to the soldering temperature. This article describes three reflow soldering techniques in surface-mount technology, namely, vapor-phase reflow, area conduction, and infrared heating. These three techniques are considered as mass reflow techniques, because all of the solderable interconnections on the surface of a printed wiring board (PWB) assembly are brought through the reflow heating cycle simultaneously. The article explains four regions of reflow profile, namely, preheat (prebake), preflow (soak), reflow, and cooldown. It concludes with a description on the bare copper assembly process, which is carried out in the inert atmosphere.
Hot Gas Soldering
Authors: Frederickson Michael D.
Published: December 2018

Hot gas soldering is a process that is commonly used in applications where the workpiece thermal mass is small and the melting temperature of the solder is relatively low. This article describes the characteristics of hot gas heating that are critical to its effectiveness in soldering. These characteristics include the focus of gas flow, gas flow rates (velocity and volume), gas temperature, and typical gas media. The article explains the thermal profile of a component being soldered and the temperature across adjacent components, which helps to understand time-temperature relationship. It concludes with a discussion on reliability concerns and processing concerns when using hot gas soldering in electronics assembly.
Wave Soldering
Authors: Vianco Paul T.
Published: December 2018

This article focuses on the design considerations and process parameters critical to the successful implantation of wave soldering on printed circuit boards. The design considerations include the through-hole technology and the surface-mount technology. The article presents information on process parameters, which can be divided into three groups: the fluxing operation, solder wave properties, and process schedule. It provides information on various solder defects.
Influence of Welding on Steel Weldment Properties
Authors: Chen C.C. , Pollack Abe
Published: December 2018

This article describes the fundamental and specific factors that control the properties of steel weldments in both the weld metal and heat-affected zone (HAZ) of carbon and low-alloy steels. It provides information on steel types and their weldability. The article also explains the influence of welding procedure factors on the weldment properties. These procedure factors include preheat temperature, interpass temperature, postweld heat treatment, and heat input.
Selection of Cast Stainless Steels
Authors: Cieslak Michael J.
Published: December 2018

This article discusses two categories of stainless steel casting alloys and their nomenclature. It provides information on two situations in which welding of stainless steel castings is required. These situations are based on casting defects and selection of welding processes. The article presents compositions and typical microstructures of corrosion-resistant stainless steel casting alloys in tabular form. It presents special considerations for the welding of martensitic stainless steel castings. The article reviews the two most serious problems encountered in the welding of stainless steel castings, namely, solidification hot cracking and heat-affected zone hot cracking. It concludes with a discussion on the some useful considerations for welding corrosion-resistant alloys to avoid defects.
Selection and Weldability of Conventional Titanium Alloys
Authors: Baeslack W.A. , Davis J.R. , Cross C.E.
Published: December 2018

This article emphasizes the physical metallurgy of titanium and titanium alloys along with their microstructural response to fusion welding condition. The titanium alloys are classified into unalloyed or commercially pure titanium, alpha and near-alpha alloys, alpha-beta alloys, and metastable beta alloys. The article further discusses the weld microstructure for alpha-beta and metastable beta alloys and describes welding defects observed in titanium alloys. The influence of macro- and microstructural characteristics of titanium weldment on mechanical properties is also discussed. The article concludes with a discussion on the different welding processes used in the welding of titanium and titanium alloys.
Selection and Weldability of Dispersion-Strengthened Aluminum Alloys
Authors: Sampath K. , Baeslack III W.A.
Published: December 2018

Conventional high-strength aluminum alloys produced via powder metallurgy (P/M) technologies, namely, rapid solidification (RS) and mechanical alloying (mechanical attrition) have high strength at room temperature and elevated temperature. This article focuses on the metallurgy and weldability of dispersion-strengthened aluminum alloys based on the aluminum-iron system that are produced using various RS-P/M processing techniques. It describes weldability issues related to weld solidification behavior, the formation of hydrogen-induced porosity in the weld zone, and the high-temperature deformation behavior of these alloys, which affect the selection and application of fusion and solid-state welding processes. The article provides specific examples of material responses to welding conditions and highlights the microstructural development in the weld zone.
General Welding Characteristics of High-Temperature Materials
Authors: Lingenfelter A.C.
Published: December 2018

This article addresses the general welding characteristics common to both solid-solution-strengthened and precipitation-hardened nickel-, iron-, and cobalt alloys.
Welding Metallurgy of Nonferrous High-Temperature Materials
Authors: Thompson R.G.
Published: December 2018

This article focuses on the physical metallurgy of nonferrous high-temperature materials that affects weldability on the precipitates used for age hardening (strain-age cracking). Those precipitates associated with solidification and solidification segregation, primarily Laves and carbides (heat-affected zone grain boundaries cracking), are also discussed. The article examines the parameters that affect heat-affected zone liquation cracking and presents a solution for each problem.
Special Metallurgical Welding Considerations for Nickel and Cobalt Alloys and Superalloys
Authors: Kiser S.D.
Published: December 2018

The process of making assemblies of solid-solution and precipitation hardening groups of alloys and superalloys often requires welding of dissimilar metals, welding of diffusion-bonded materials, and sometimes weld overlay cladding and even thermal spraying that in turn requires special knowledge and treatments developed specifically for each material. This article emphasizes the special metallurgical welding considerations for welding solid-solution and precipitation hardening nickel alloys, cobalt alloys, and superalloys.
Introduction to the Selection of Nonferrous Corrosion-Resistant Materials
Authors: Matthews S.J.
Published: December 2018

Improvement in the corrosion performance of a component or structure can be achieved through proper design, surface protection, proper material selection, or combinations of all three parameters. This is an introductory article on the selection of nonferrous corrosion-resistant materials.
Welding of Cast Irons
Authors: Bushey Roger A.
Published: December 2018

Cast iron can be described as an alloy of predominantly iron, carbon, and silicon. This article discusses the classification of cast irons, such as gray cast iron, white cast iron, malleable cast iron, ductile cast iron, and compacted graphite iron. It reviews the various special techniques, such as groove face grooving, studding, joint design modifications, and peening, for improving the strength of a weld or its fitness for service. The article discusses the need for postweld heat treatment that depends on the condition of the casting, possible distortion during subsequent machining, the desired finish of the machined surfaces, and prior heat treatment. It describes various welding process for welding cast irons, including oxyfuel welding, braze welding, shielded metal arc welding, gas metal arc welding, and gas-tungsten arc welding.
Welding of Aluminum Alloys
Authors: Dickerson Paul B.
Published: December 2018

Aluminum and its alloys can be joined by as many or more methods than any other metal. This article discusses the properties of aluminum, namely hydrogen solubility, electrical conductivity, and thermal characteristics. It analyses the primary factors commonly considered when selecting a welding filler alloy. These include ease of welding or freedom from cracking, tensile or shear strength of the weld, weld ductility, service temperature, corrosion resistance, and color match between the weld and base alloy after anodizing. The article provides a detailed description of gas-shielded arc welding processes for welding of aluminum alloys and also reviews other welding processes such as oxyfuel gas welding and laser-beam welding.
Welding of Copper Alloys
Authors: Rogers M. Ned
Published: December 2018

Copper and copper alloys offer a unique combination of material properties that makes them advantageous for many manufacturing environments. This article begins with a discussion on common metals that are alloyed with copper to produce the various copper alloys. It then reviews the factors that affect the weldability of copper alloys, including thermal conductivity of the alloy being welded, shielding gas, type of current used during welding, joint design, welding position, and surface condition. The article provides information on arc welding processes such as gas-metal arc welding, shielded metal arc welding, submerged arc welding, plasma arc welding, and gas-tungsten arc welding. It concludes with a discussion on safe welding practices.
Welding of Zirconium Alloys
Authors: Webster R. Terrence
Published: December 2018

Zirconium and its alloys are available in two general categories: commercial grade and reactor grade. This article discusses the welding processes that can be used for welding any of the zirconium alloys. These include gas-tungsten arc welding (GTAW), gas-metal arc welding (GMAW), plasma arc welding (PAW), electron-beam welding (EBW), laser-beam welding (LBW), friction welding (FRW), resistance welding (RW), resistance spot welding (RSW), and resistance seam welding (RSEW). The article reviews the selection of shielding gases and filler metals for welding zirconium alloys. It concludes with a discussion on process procedures for welding zirconium alloys.
Procedure Development and Practice Considerations for Inertia and Direct-Drive Friction Welding
Authors: Stotler Tim
Published: December 2018

Friction welding (FRW) is a solid-state welding process that uses the compressive force of the workpieces that are rotating or moving relative to one another, producing heat and plastically displacing material from the faying surfaces to create a weld. This article reviews practice considerations for the two most common variations: inertia welding and direct-drive friction welding. Direct-drive friction welding differs from inertia welding, primarily in how the energy is delivered to the joint. The article discusses the parameter calculations for inertia welding and direct-drive friction welding. It provides information on friction welding of carbon steels, stainless steels, aluminum-base alloys, and copper-, nickel-, and cobalt-base materials.
Brazing of Stainless Steels
Authors: Lucas Matthew J.
Published: December 2018

The quality of brazed stainless steel joints depends on the selection of the brazing process, process temperature, filler metal, and the type of protective atmosphere or flux. This article provides a detailed discussion on the applicability and brazeability of stainless steel and lays an emphasis on the selection of suitable filler metal, brazing processes, and its corresponding furnace atmosphere for brazing different grades of stainless steel. The types of brazing processes include torch brazing, furnace brazing in different atmospheres (dissociated ammonia, dry hydrogen, and vacuum atmosphere), dip brazing in salt bath, and high-energy-beam brazing. A complete list of the typical compositions and properties of standard brazing filler metals for brazing stainless steel is also provided.
Soldering in Electronic Applications
Authors: Vianco Paul T.
Published: December 2018

Soldering represents the primary method of attaching electronic components, such as resistors, capacitors, or packaged integrated circuits, to either printed wiring board whose defects is minimized by consideration of proper PWB design, device packages, and board assembly. This article discusses the categories that are most important to successful electronic soldering, namely, solders and fluxes selection, nature of base materials and finishes, solder joint design, and solderability testing.
Joining of Oxide-Dispersion-Strengthened Materials
Authors: O'Donnell David
Published: December 2018

Oxide - dispersion - strengthened (ODS) materials utilize extremely fine oxide dispersion for strengthening, such as nickel-base alloys or alumina. The processing techniques employed in the production of ODS alloys produce some entrapped gases, which tend to create porosity during welding that can be rectified by suitable designing considerations. This article discusses certain successful design strategies employed in joining ODS alloys in consideration with the grain structure. It further provides a brief discussion on different welding processes involved in joining ODS materials, namely, gas-tungsten arc welding, gas-metal arc welding, electron-beam and laser-beam welding, resistance welding, furnace brazing, friction welding, and explosion welding.
Composite-to-Metal Joining
Authors: Bohlmann Raymond E.
Published: December 2018

This article discusses the material combinations, design details, and fabrication processes considered in the adhesive bonding or melt-fuse interface (amorphous bond) bonding method of joining resin-matrix composites to metals.
Welding of Plastics
Authors: North Thomas H. , Ramarathnam Geetha
Published: December 2018

Polymeric materials that possess similar solubility parameters can be joined using a variety of polymer joining techniques. This article describes commonly available fusion-welding techniques such as joining methods, key joining parameters, and the application areas of each joining method. The techniques are hot-tool, hot-gas, extrusion, focused infrared, laser, friction, vibration, spin, ultrasonic, and electromagnetic welding techniques (resistance, induction, dielectric, and microwave welding). The article concludes with a discussion on welding evaluation methods.
Corrosion of Weldments
Authors: Wahid A. , Olson D.L. , Matlock D.K. , Cross C.E.
Published: December 2018

Weldments exhibit special microstructural features that need to be recognized and understood in order to predict acceptable corrosion service life of welded structures. This article describes some of the general characteristics associated with the corrosion of weldments. It emphasizes the role of macrocompositional and microcompositional variations to bring out differences that need to be realized in comparing corrosion of weldments to that of wrought materials. The article concludes with a discussion on important welding practices used to minimize corrosion in weldments.
Inspection of Welded Joints
Authors: Edwards G.R.
Published: December 2018

This article describes the applications, methods, and limitations of five principal nondestructive test methods, namely, penetrant testing, magnetic-particle testing, eddy current testing, radiographic testing, and ultrasonic testing. The article also provides guidance for the method selection for respective applications.
Weld Procedure Qualification
Authors: Castner Harvey R.
Published: December 2018

Welding codes and standards usually require the qualification of welding procedures prior to being used in production. This is to ensure that welds will meet the minimum quality and mechanical property requirements for the application. This article provides an overview of the welding procedure qualification guidelines and test methods. It also reviews the codes, standards, and specifications that govern the design and fabrication of welded structures for the procedure qualification details that are appropriate for a given application.
Residual Stresses and Distortion
Authors: Masubuchi Koichi
Published: December 2018

This article describes the formation of residual stresses and distortion, providing information on the techniques for measuring residual stresses. It presents a detailed discussion on the magnitude and distribution analysis of the residual stresses and distortion in weldments. The article briefly explains the effects of residual stresses and distortion on the brittle fracture and fatigue fracture of welded structures. It also provides information on the thermal treatments of weldments.
Plasma Arc Cutting
Authors: Landry Chuck
Published: December 2018

Plasma arc cutting (PAC) is an erosion process that utilizes a constricted arc in the form of a high-velocity jet of ionized gas to melt and sever metal in a narrow, localized area. This article discusses the process description, equipment, gases, operating sequence, process considerations, and applications of PAC. It concludes with a discussion on the safety measures associated with the PAC process.
Air-Carbon Arc Cutting
Authors: Strohl Robert L.
Published: December 2018

This article describes the principles of operation, operating techniques, equipment selection, and important process variables of air-carbon arc cutting. It also provides information on the safety practices to be followed during the air-carbon arc cutting process.
Introduction to Materials Characterization
Authors: Whan R.E.
Published: December 2018

This article provides an overview of how this volume is organized and structured. It describes the methods for analyzing the materials in simplified terms and emphasizes the most common applications and limitations of each method.
Sampling
Authors: Taylor John K. , Kratochvil Byron
Published: December 2018

This article primarily considers the problem of sampling bulk materials, including minerals, metals, environmentally important substances, and industrial raw materials and waste products. It provides useful information on sample types, sampling plan, optimizing sampling resources, practical aspects of sampling, and how to ensure the quality of sampling.
Atomic Absorption Spectrometry
Authors: Siemer Darryl D.
Published: December 2018

Atomic absorption spectrometry (AAS) is generally used for measuring relatively low concentrations of approximately 70 metallic or semimetallic elements in solution samples. This article describes several features that are common to three techniques, namely, AAS, atomic emission spectrometry (AES), and atomic fluorescence spectrometry (AFS). It discusses the reasons for the extreme differences in AAS sensitivities that affect AFS and AES. The article provides information on the advantages and disadvantages of the Smith/Hieftje system and two types of background correction systems, namely, the continuum-source background correction and Zeeman background correction. It also provides a list of applications of conventional AAS equipment, which includes most of the types of samples brought to laboratories for elemental analyses.
Ultraviolet/Visible Absorption Spectroscopy
Authors: Brabson G. Dana
Published: December 2018

Ultraviolet/visible (UV/VIS) absorption spectroscopy is a powerful yet cost-effective tool that is widely used to identify organic compounds and to measure the concentration of principal and trace constituents in liquid, gas, and solid test samples. This article emphasizes the quantitative analysis of elements in metals and metal-bearing ores. The instrumentation required for such applications consists of a light source, a filter or wavelength selector, and some type of visual or automated sensing mechanism. The article examines common sensing options and provides helpful information on how to set up and run a variety of UV/VIS absorption tests.
Molecular Fluorescence Spectroscopy
Authors: McGown Linda B.
Published: December 2018

This article provides an introduction to the molecular fluorescence spectroscopy, and discusses the theory of fluorescence and its application to chemical analysis. It provides information on fluorescence that occurs in organic compounds and inorganic atoms and molecules. The article describes the instruments used in the spectroscopy, namely, radiation sources, sample holders, wavelength selectors, detectors, computers, and ratiometric instruments. The practical considerations include solvent effects, corrected spectra, wavelength calibration, temperature, and scattered light. The article also discusses the uses of some special techniques used in molecular fluorescence spectroscopy.
X-Ray Spectrometry
Authors: Leyden Donald E.
Published: December 2018

This article provides an introduction to x-ray spectrometry, and discusses the role of electromagnetic radiation, x-ray emission, and x-ray absorption. It focuses on the instrumentation of wavelength-dispersive x-ray spectrometers, and energy dispersive x-ray spectrometers (EDS) that comprise x-ray tubes, the analyzing system, and detectors. The fundamentals of EDS operation are described. The article also provides useful information on preparation of various samples, explaining the qualitative and quantitative analyses of EDS. It reviews the applications of the x-ray spectrometry.
Particle-Induced X-Ray Emission
Authors: Cahill Thomas A.
Published: December 2018

Particle-induced x-ray emission (PIXE) is one of several quantitative analyses based on characteristic x-rays. This article provides a detailed account on the principles of PIXE, discussing the data-reduction codes used to identify, integrate, and reduce x-ray peaks into elemental concentrations. It provides information on the calibration of PIXE analysis, which is mostly performed using gravimetric standards to avoid serious absorption, refluorescence, or ion energy change corrections. A comparative study on PIXE and x-ray fluorescence is also included. Finally, the article discusses the applications of PIXE in three areas, namely, atmospheric physics and chemistry, external proton milliprobes and historical analysis, and PIXE microprobes.
Infrared Spectroscopy
Authors: Marcott Curtis
Published: December 2018

Infrared (IR) spectroscopy is a useful technique for characterizing materials and providing information on the molecular structure, dynamics, and environment of a compound. This article provides the basic principles and instrumentation of IR spectroscopy. It discusses the sampling techniques of IR spectroscopy, namely, attenuated total reflectance spectroscopy, diffuse reflectance spectroscopy, infrared reflection-absorption spectroscopy, emission spectroscopy, and photoacoustic spectroscopy, and chromatographic techniques. Explaining the qualitative analysis of IR spectroscopy, the article provides information on spectral absorbance-subtraction, analysis of components in spectral matrix mixture, and determination of exact peak location of broad profiles. It discusses the quantitative analysis that mainly includes Beer's law for single compound in single wave number. The article also exemplifies the applications of IR spectroscopy.
Spark Source Mass Spectrometry
Authors: Donohue D.L. , Carter J.A.
Published: December 2018

Spark source mass spectrometry (SSMS) is an analytical technique used for determining the concentration of elements in a wide range of solid samples, including metals, semiconductors, ceramics, geological and biological materials, and air and water pollution samples. This article discusses the basic principles of spark source technique; SSMS instrumentation such as ion source, electric sector, and magnetic sector; sample preparation; and test procedures of SSMS. Some of the related techniques to SSMS are laser ionization mass spectrometry and laser-induced resonance ionization mass spectrometry. The ions produced in SSMS are detected by either the photometric method or electrical detection method and quantitatively measured by techniques such as internal standardization techniques, isotope dilution, multi element isotope dilution, and dry spike isotope dilution. The detected spark source spectrum contains all the elemental data of the tested sample. Finally, the article exemplifies the applications of SSMS.
Gas Analysis by Mass Spectrometry
Authors: Grindstaff Q.G. , Franklin J.C. , Marshall J.L.
Published: December 2018

Gas analysis by mass spectrometry, or gas mass spectrometry, is a useful analytical tool for investigations performed in controlled atmospheres or in vacuum. This article provides sufficient information to determine if gas mass spectrometry can produce the data required and to determine the type of instrument necessary for a particular application. It discusses the working operations of gas mass spectrometer components, namely, the introduction system, ion sources, mass analyzers, and the ion detector. The article also provides information on resolution of a gas mass spectrometer determined by the width of the source slit and the collector slit. Finally, it describes the instrument set-up for gas mass spectrometry, and shows how to analyze the test results of gas mass spectrometry.
High-Temperature Combustion
Authors: Fricioni R.B. , Essig Loren
Published: December 2018

High-temperature combustion is primarily used to determine carbon and sulfur contained in a variety of materials. This article illustrates the principle of combustion and focuses on the characteristics of accelerators. It provides information on the process of separating oxide compounds formed in the combustion zone. The article provides information on infrared and thermal-conductive detectors, which are used for the detection of CO2 and SO2. Finally, it addresses the requirements of a sample to undergo total and selective combustion, and presents examples showing the applications of high-temperature combustion. .
Neutron Activation Analysis
Authors: Bunker M.E. , Minor M.M. , Garcia S.R.
Published: December 2018

Neutron activation analysis (NAA) is a highly sensitive and accurate method of assaying bulk materials for trace levels of many elements. This article provides a detailed account on several types of NAA, namely, nondestructive and radiochemical thermal neutron activation, delayed neutron counting, epithermal and 14-MeV fast neutron activation, and prompt gamma activation analysis. It also includes application examples, explaining where and how each method is used and the types of elements on which they are effective.
X-Ray Powder Diffraction
Authors: Goehner Raymond P. , Nichols Monte C.
Published: December 2018

X-ray powder diffraction (XRPD) techniques are used to characterize samples in the form of loose powders or aggregates of finely divided material that readily diffract x-rays in specified patterns. This article provides an introduction to XRPD, beginning with a review of sensing devices, including pinhole/Laue cameras, Debye-Scherrer/Gandolfi cameras, Guinier cameras, glancing angle cameras, conventional diffractometers, thin film diffractometers, Guinier diffractometers, and micro diffractometers. The article then describes several quantitative measurement methods, such as lattice parameter, absorption diffraction, spiking, and direct comparison, explaining where each may be used. It also identifies potential sources of error in XRPD measurements.
Radial Distribution Function Analysis
Authors: Konnert J.H. , Karle J. , D'Antonio P.
Published: December 2018

The diffraction pattern of any material contains structural and chemical property information that can be extracted using radial distribution function analysis. This article provides an introduction to the technique and presents several examples highlighting various ways in which it can be used. It begins with a discussion on the principles of diffraction and scattering and the effectiveness of x-ray, neutron, and electron energy sources for different types of measurements. It provides information on data collection and reduction and explains how to create atomic distribution plots from intensity and scattering angle data. The article also presents application parameters for defining short distances and background intensity and describes a procedure for generating pair distribution functions.
Neutron Diffraction
Authors: Yelon W.B. , Ross F.K. , Krawitz A.D.
Published: December 2018

Neutrons are a principal tool for the study of lattice vibrational spectra in materials. This article provides a detailed account of fission and spallation methods of neutron production that are capable of producing sufficient intensity to be useful in neutron scattering research. It describes the instrumentation required for, and advancements made in, neutron powder diffraction. The article further explains the texture and residual stress (macrostresses and microstresses) problems that are analyzed using the neutron powder diffraction method. It also outlines the single-crystal neutron diffraction technique, and provides examples of the applications of neutron diffraction.
Auger Electron Spectroscopy
Authors: Joshi A.
Published: December 2018

This article describes the principles and applications of Auger electron spectroscopy (AES). It provides information on the instrumentation typically used in the AES, including an electron gun, an electron spectrometer, a secondary electron detector, and an ion gun. The article also describes experimental methods and limitations of the AES, including elemental detection sensitivity, electron beam artifacts, sample charging, spectral peak overlap, high vapor pressure samples, and sputtering artifacts.
Field Ion Microscopy and Atom Probe Microanalysis
Authors: Smith G.D.W.
Published: December 2018

Field ion microscopy (FIM) can be used to study the three-dimensional structure of materials, such as metals and semiconductors, because successive atom layers can be ionized and removed from the surface by field evaporation. The ions removed from the surface by field evaporation can be analyzed chemically by coupling to the microscope a time-of-flight mass spectrometer of single-particle sensitivity, known as the atom probe (AP). This article describes the principles, sample preparation, and quantitative analysis of FIM. It also provides information on the principles, instrument design and operation, mass spectra and their interpretation, and applications of AP microanalysis.
Low-Energy Ion-Scattering Spectroscopy
Authors: Nelson G.C.
Published: December 2018

Low-energy ion-scattering spectroscopy (LEISS) is used extensively to analyze solid surfaces. The LEISS process relies on binary elastic collisions between an incident ion beam and the atoms in a sample to obtain information on the surface atoms. The velocity of the scattered ions is used to determine the mass of the atoms that are struck. This article introduces LEISS and its principles. It describes the use of LEISS spectra in qualitative and quantitative analyses, and reviews the instrumentation and applications of LEISS.
Liquid Chromatography
Authors: Kelly Michael J.
Published: December 2018

This article introduces the fundamental concepts and the essential components of liquid chromatography (LC). It discusses the different modes of LC, such as liquid-solid chromatography, liquid-liquid chromatography, bonded-phase chromatograph, normal-phase chromatography, reversed-phase chromatography, ion-exchange chromatography, ion-pair chromatography, and size-exclusion chromatography. The article also includes a discussion on the qualitative and quantitative analyses and the applications of LC.
Ion Chromatography
Authors: Merrill Raymond M.
Published: December 2018

Ion chromatography (IC) is an analytical technique that uses columns packed with ion exchange resins to separate ions in aqueous solutions and dynamically elute them to a detector. This article provides information on the different modes of detection, namely, eluent-suppressed conductivity detection, single-column ion chromatography with conductivity detection, ion chromatography with spectrophotometric detection, and amperometric electrochemical detection. It describes the modes of separation techniques in IC and reversed-phase IC. The article discusses the detection capabilities of IC, the procedures for preparing solid and liquid samples, as well as the applications of IC.