bluuebunny/crossref_metadata_2025 huggingface dataset:
ИСТОКИ ФОРМИРОВАНИЯ АГРАРНО-ЭКОНОМИЧЕСКОЙ НАУКИ И ОБРАЗОВАНИЯ В ЯКУТИИ
Authors: А.А. ПАХОМОВ , В.Р. ДАРБАСОВ , Е.Я. ФЕДОРОВА
Published: November 2024

В статье рассмотрено начало заложения аграрноэкономической науки в историческом аспекте, этапы его формирования и развития в Якутии. Представлены некоторые известные ученыеэкономисты аграрники, внесшие заметную лепту в науку и образование республики. Авторы пришли к мнению, что необходимо усилить региональную науку, направленную на создание местной продовольственной базы в условиях Крайнего Севера.

The article considers the beginning of the foundation of the agro economic science in a historical aspect, the stages of its formation and development in Yakutia. Some wellknown agricultural economists agrarians who have made a significant contribution to the science and education of the republic are presented. The authors agreed that it is necessary to strengthen regional science aimed at creating a local food base in the conditions of the Far North.
95 ЛЕТ ЗОЛОТОДОБЫВАЮЩЕЙ ОТРАСЛИ ЯКУТИИ: ЗАБЫТЫЕ СТРАНИЦЫ ИСТОРИИ
Authors: А.П. ЕФИМОВ
Published: November 2024

В текущем году отмечается 95 летний юбилей золотодобывающей промышленности Якутии. В статье автор поднимает историю разработок южноякутских и вилюйских россыпей начала 20 века, не вошедших в официальную историю золотодобычи Якутии. Приведены опубликованные архивные материалы и публикации научных статей, по историческим данным начала золотодобычи в Якутии.

This year the 95th anniversary of goldmining industry of Yakutia is celebrated. In the article author recalls the history of the development of South Yakutian and Viliuisky placers in the beginning of the 20th century, not included in the official history of gold mining of Yakutia. The published archival materials and publications of scientific articles are given, according to historical data of the beginning of gold mining in Yakutia.
ПРАВОВЫЕ АСПЕКТЫ ЖИЗНЕОБЕСПЕЧЕНИЯ И УСТОЙЧИВОГО РАЗВИТИЯ СЕВЕРНЫХ И АРКТИЧЕСКИХ ТЕРРИТОРИЯ: РЕГИОНАЛЬНЫЕ ПРАКТИКИ
Authors: С.М. ЯМКИН
Published: November 2024

приведены тезисы выступления Председателя Законодательного Собрания Ямало-Ненецкого автономного округа, в котором раскрыты основы проводимой в субъекте законодательной политики с учетом особенностей региона. Отмечаются такие элементы законодательной политики региона, как региональные нормы налоговых преференций хозяйствующим субъектам, правовое регулирование промышленных парков регионального значения, обеспечение устойчивого развития коренных малочисленных народов Севера, закрепление региональных социальных льгот для института семьи и другие.

the thesis of the Chairman of the Legislative Assembly of Yamalo-Nenets Autonomous Okrug speech is presented. The speech reveals the principles of the region legislative policy, which are based on the region`s specific features. Such elements of the regional legislative policy as regional norms for the tax preferences for business entities, legal regulation of the regional industrial parks, sustainable development of indigenous people of the North, security of the regional social benefits for families as well as other elements are noted.
ЛУЧШИЕ ЗАКОНОДАТЕЛЬНЫЕ ПРАКТИКИ УСТОЙЧИВОГО РАЗВИТИЯ СЕВЕРНЫХ ТЕРРИТОРИЙ
Authors: С.М. ДУБОВОЙ
Published: November 2024

в статье приведены примеры создания территорий опережающего социально-экономического развития в Мурманской области, приводится обзор практики законодательного регулирования инвестиционной деятельности на данных территориях в части применения налоговых и неналоговых преференций резидентами ТОР.

The paper focuses on the examples of the territories of advanced social and economic development organization in Murmansk region and overviews the investment regulating legislation in these territories, specifically tax and non-tax preferences applied to the advanced development territories resident companies.
УСТОЙЧИВОСТЬ ПРИРОДНЫХ СИСТЕМ И ИНЖЕНЕРНЫХ СООРУЖЕНИЙ В АРКТИКЕ И СУБАРКТИКЕ
Authors: М.Н. ЖЕЛЕЗНЯК , А.Н. ФЕДОРОВ
Published: November 2024

в последние три десятилетия в связи с современными изменениями климата и антропогенными нарушениями на территории Якутии происходит активизация криогенных процессов, которые негативно отражаются в ландшафтах и социально-экономической сфере в области вечной мерзлоты. Оценка современного состояния и тенденций развития мерзлотных ландшафтов Якутии в условиях глобального изменения климата и их влияние на устойчивость инженерных сооружений являются важной задачей для развивающихся районов Арктики и Субарктики России. Сильнольдистые криогенные ландшафты, занимающие около 30 % территории Якутии, в условиях современного потепления климата находятся в критическом состоянии. Результаты полевых наблюдений показывают, что любое антропогенное воздействие может привести к деградации вечной мерзлоты и ухудшению социально-экономической ценности этих ландшафтов. С этими ландшафтами в Якутии связаны наиболее населенные территории – аласные районы. Поэтому проблема изучения тенденций развития криогенных ландшафтов имеет не только экологическую, но и социально-экономическую, культурную и историческую актуальность.

Current climatic changes and anthropogenic disturbances have intensified the development of permafrost-related processes in Yakutia during the last two decades, adversely affecting the landscapes and socio-economic conditions in this permafrost region. The main purpose of this paper is to assess the current state and trends in permafrost landscapes in Yakutia under global climate change. It provides a review of the current scientific literature, as well as analysis of field observations at monitoring sites of the Melnikov Permafrost Institute. The ice-rich permafrost landscapes which occupy about 25 % of Yakutia are in a critical condition under the current climate warming. The results of field observations show that any anthropogenic impact can lead to permafrost degradation and deterioration of the socio-economic value of these landscapes. Alases, which are related to these landscapes, are the most populated areas in Yakutia. Understanding the trends in permafrost-landscape dynamics has therefore not only ecological, but also socio-economic, cultural and historical importance. KEY WORDS: global warming, air temperature, permafrost landscape, engineering structures, Yakutia.
О СОВЕРШЕНСТВОВАНИИ ГОСУДАРСТВЕННОЙ ПОДДЕРЖКИ ПРЕДПРИНИМАТЕЛЬСТВА В АРКТИЧЕСКОЙ ЗОНЕ
Authors: В.Ф. НОВОЖИЛОВ
Published: November 2024

приведены тезисы выступления сенатора, представителя от законодательной (представительной) власти Архангельской области, на Парламентской сессии II Международного Северного форума по устойчивому развитию «Правовые аспекты жизнеобеспечения и устойчивого развития северных и арктических территорий». Обсуждается возможность совершенствования законодательства Российской Федерации по поддержке предпринимательской деятельности в Арктической зоне в части изменения требований к организации – резиденту Арктической зоны по отсутствию обособленных подразделений.

the thesis of the speech of Senator, the representative of the legislative (representative) powers from Arkhangelsk region at the Parliamentary Session of the 2nd Northern Sustainable Development Forum «Legislative aspects of life sustenance and sustainable development of the Northern and Arctic territories» is given. The possibility of improving the legislation of the Russian Federation on the state supportive measures of entrepreneurial activity in the Arctic zone in terms of dismissing the requirements to the Arctic zone resident organizations not to have separate divisions to apply lower taxation rates on them is being discussed.
ОЦЕНКА КРЕАТИВНОГО РАЗВИТИЯ
Authors: И.К. ГАЕВАЯ , С.И. МАЛЬЦЕВА
Published: November 2024

В статье приведена информация о креативной экономике или креативных индустриях, ее значимости. Представлено предложение по разработке статистических показателей, характеризующих ее развитие.

The article provides information about the creative economy or creative industries, its importance. A proposal for the development of statistical indicators characterizing its development is presented.
ОЦЕНКА КАЧЕСТВА ЖИЗНИ НАСЕЛЕНИЯ В МЕСТАХ ТРАДИЦИОННОГО ПРОЖИВАНИЯ И ТРАДИЦИОННОЙ ХОЗЯЙСТВЕННОЙ ДЕЯТЕЛЬНОСТИ КОРЕННЫХ МАЛОЧИСЛЕННЫХ НАРОДОВ СЕВЕРА ПОСРЕДСТВОМ РЕАЛИЗАЦИИ ПРОЕКТА
Authors: Т.И. СТЕПАНОВА , А.С. ТАРСКАЯ
Published: November 2024

В статье представлены итоги реализации проекта «Человек в Арктике» в Республике Саха (Якутия) и на отдельных территориях Дальнего Востока. Потребность в реализации проекта вызвана необходимостью мониторинга и статистического наблюдения за индикаторами, учитывающими территориальные особенности и специфику социально-экономического развития и динамики качества жизни населения в местах традиционного проживания и традиционной хозяйственной деятельности коренных малочисленных народов Севера. Проводимые в Республике Саха (Якутия) социологические исследования направлены на оценку качества жизни населения с охватом территорий традиционного проживания и традиционной хозяйственной деятельности коренных малочисленных народов Севера.

The article presents the results of the implementation of the project «Man in the Arctic» in the Republic of Sakha (Yakutia) and certain territories of the Far East. The main reason behind this project is to monitor and observe the indexes that take into consideration territorial characteristics and specifics of socio-economic development of the quality of life of the population living in traditional areas and traditional economic activities of the indigenous peoples of the North. Annual sociological research assesses the quality of life of the population, covering the territories of traditional residence and traditional economic activities ofthe indigenous peoples ofthe North.
ОЦЕНКА ВЛИЯНИЯ СОЦИАЛЬНО-ЭКОНОМИЧЕСКОЙ ДИФФЕРЕНЦИАЦИИ РЕГИОНОВ НА ЭКОНОМИЧЕСКИЙ РОСТ В СУБЪЕКТАХ ДАЛЬНЕВОСТОЧНОГО ФЕДЕРАЛЬНОГО ОКРУГА
Authors: Е.В. КОЧЕВА , А.А. СО
Published: November 2024

В статье выполнен анализ и оценка уровня социально-экономической дифференциации регионов Дальневосточного федерального округа (ДФО), который является стратегически важным для России, т.к. значится форпостом на Тихом океане, а уровень его экономического развития определяет роль России на важнейшем экономическом пространстве мира – в Азиатско-Тихоокеанском регионе; приводится классификация субъектов ДФО по уровню социально-экономического развития с помощью кластерного анализа; показано, что между регионами наблюдается дифференциация по уровню социально-экономического развития. Для построения моделей экономического роста были применены методы описательной и аналитической статистики.

The article analyzes and evaluates the level of socio-economic differentiation of the regions of the Far Eastern Federal District (FEFD), which is strategically important for Russia, since is listed as an outpost in the Pacific Ocean and the level of its economic development determines the role of Russia in the most important economic space of the world the Asia-Pacific region, a classification of the subjects of the Far Eastern Federal District by the level of socio-economic development using cluster analysis is shown, it is shown that there is indeed differentiation between the regions in terms of social -economic development. Methods of descriptive and analytical statistics were used to build models of economic growth.
АНАЛИЗ ЭФФЕКТИВНОСТИ ФУНКЦИОНИРОВАНИЯ СИСТЕМЫ ПСИХОЛОГИЧЕСКОЙ ПОМОЩИ НАСЕЛЕНИЮ РЕСПУБЛИКИ САХА (ЯКУТИЯ)
Authors: Т.И. СТЕПАНОВА , Т.В. ФЕДОРОВА
Published: November 2024

В статье выполнен анализ действующей системы психологической помощи населению Республики Саха (Якутия), в ходе которого выявлены основные проблемы и разобщенность деятельности психологических служб, отношение населения к психологическим услугам, изучены процессы оказания данных услуг, уровень и оценка деятельности психологов государственных учреждений Республики Саха (Якутия).

The article analyzes current state of system of psychological assistance to the population of the Republic of Sakha (Yakutia). As a result of this study, authors identified main problems and disunity of psychological services activities, assessed theattitude of the population to psychological services, studied processes of providing these services, level and activities assessment of psychologists of state institutions of the Republic of Sakha (Yakutia).
УСТОЙЧИВОЕ РАЗВИТИЕ РЕСПУБЛИКИ САХА (ЯКУТИЯ): ИТОГИ 2022 ГОДА
Authors: А.Ц. ДОЛГУНОВА
Published: November 2024

Концепция устойчивого развития и ESG-повестка сохраняют свою актуальность в Российской Федерации. В статье дано описание результатов исследования, проведенного Центром стратегических исследований при Главе Республики Саха (Якутия) в рамках подготовки Доклада об уровне благополучия населения и деятельности в области устойчивого развития Республики Саха (Якутия) – 2023: рассмотрены практика управления устойчивым развитием в Республике Саха (Якутия), вклад корпоративного сектора в продвижение ESG-повестки, восприятие концепции устойчивого развития населением республики, основные итоги по отдельным целям устойчивого развития. КЛЮЧЕВЫЕ СЛОВА: устойчивое развитие, цели устойчивого развития, Повестка-2030, Республика Саха (Якутия).

The Concept of Sustainable Development and the ESG agenda remain relevant in the Russian Federation. The article describes the results of a study conducted by the Strategic Research Center under the Head of the Republic of Sakha (Yakutia), as part of the preparation of the Report on the level of well-being of the population and activities in the field of sustainable development of the Republic of Sakha (Yakutia) – 2023: the practice of managing sustainable development in the Republic of Sakha (Yakutia) is considered ( Yakutia), the contribution of the corporate sector to promoting the ESG agenda, the perception of the concept of sustainable development by the population of the republic, the main results on individual sustainable development goals. KEY WORDS: sustainable development, sustainable development goals, 2030 Agenda, Republic of Sakha (Yakutia).
СТАТИСТИКЕ ЯКУТИИ – 170 ЛЕТ
Authors: И.К. ГАЕВАЯ
Published: November 2024

Статья посвящена 170-летию со дня образования якутской статистики. 23 сентября 1853 г. по предписанию председателя совета Главного управления Восточной Сибири был создан Якутский статистический комитет под председательством Якутского гражданского губернатора, действительного статского советника Константина Никифоровича Григорьева. В материале приведены все этапы становления и развития органов государственной статистики Якутии за более чем двухвековой период (XIX-XXI вв.).

IAbstract: The article is dedicated to the 170th anniversary of the formation of Yakut statistics. On September 23, 1853, by ordinance of the chairman of the council of the Eastern Siberia Main Administration, the Yakut Statistical Committee was established under the chairmanship of the Yakut Civil Governor, the actual state councilor Konstantin Nikiforovich Grigoryev. The material presents all stages of the formation and development of the state statistics bodies in Yakutia over a period of more than two centuries (XIX-XXI centuries).
ИНСТИТУЦИОНАЛЬНЫЕ АСПЕКТЫ ТРАНСФОРМАЦИИ СОЦИАЛЬНОЙ СТРУКТУРЫ ПРЕДПРИНИМАТЕЛЬСТВА (НА ПРИМЕРЕ Г. ЯКУТСКА)
Authors: А.И. ДАНИЛОВ , В.Е. ОХЛОПКОВ
Published: November 2024

В статье авторы освещают специфику особенностей, влияющих на организацию социальной структуры предпринимателей на примере г. Якутска. Теоретически обосновывается модель институционального регулирования социальной структуры городского предпринимательства. Приведен пример снижения трансакционных издержек на примере институционального регулирования формирования общественных организаций предпринимателей.

In the article, the authors cover the specifics of the features influencing the organization of the social structure of entrepreneurs on the example of the city of Yakutsk. Theoretically, the model of institutional regulation of the social structure of urban entrepreneurship is substantiated. An example of reducing transaction costs is given on the example of institutional regulation of the formation of public organizations of entrepreneurs.
АНАЛИЗ СОСТАВА ТРУДОВЫХ РЕСУРСОВ РЕСПУБЛИКИ САХА (ЯКУТИЯ) (ПО ИТОГАМ ВСЕРОССИЙСКОЙ ПЕРЕПИСИ НАСЕЛЕНИЯ 2020 ГОДА)
Authors: Т.И. СТЕПАНОВА
Published: November 2024

Встатье представлен анализ состава иструктуры региональной рабочей силы по уровню занятости, полу и возрастным группам населения с учетом территориальной специфики различных групп муниципальных районов и городских округов на основе данных Всероссийской переписи населения 2020 года.

The article presents an analysis of the composition and structure of the regional workforce by employment level, gender and age groups of the population, taking into account the territorial specifics of various groups of municipal districts and urban districts based on data from the 2020 All-Russian Population Census.
АДАПТАЦИЯ МАССОВОГО СОЗНАНИЯ К РОССИЙСКОМУ «РАЗВОРОТУ НА ВОСТОК»
Authors: С.В. ЛЬВОВ
Published: November 2024

В 2022 году российское массовое сознание столкнулось не только с новыми темами в общественной повестке, но и со сменой приоритетов во внешней политике и международном экономическом сотрудничестве. Вплоть до 2014 года наиболее сильным культурным аттрактором для россиян являлся Запад. С появлением первых признаков противостояния с западными странами и альянсами, с началом санкций и других ограничений возникли условия для замещения этого источника, но это произошло не сразу. Длительное время Запад сохранял свою привлекательность в глазах россиян. С началом СВО ситуация изменилась – российское руководство четко определилось с выбором внешнеполитического курса, в котором Восток занимает приоритетную позицию. Но Восток не стал таким же эмоциональным и декларативно-рациональным аттрактором для россиян, каковым был в свое время Запад. Целью сотрудничества с восточными странами россияне видят прежде всего равноправное партнерство в экономической сфере, но в то же время усматривают культурные ограничения. В статье анализируются признаки и причины изменений в массовом сознании по вопросу о переориентации приоритетов внешней политики в сторону Востока, зафиксированные в ходе исследований общественного мнения в России в разные периоды современной истории страны.

In 2022, Russia’s mass consciousness faced not only new topics on the public agenda, but also a change of priorities in foreign policy and international economic cooperation. Until 2014, the strongest cultural attraction for Russians was the West. With the first signs of confrontation with Western countries and alliances, with the beginning of sanctions and other restrictions, conditions were created to replace this source, but this did not happen immediately. For a long time, the West remained attractive to Russians. With the start of the SMO, the situation has changed, and the Russian government has clearly determined the choice of foreign policy, in which the East takes a priority position. But the East has not become the emotional and declaratory-rational attractor for Russians that the West once was. Russians see the goal of cooperation with the East primarily as equal partnership in the economic sphere, but at the same time see cultural limitations. The article analyses signs and causes of changes in mass consciousness on the issue of reorientation of foreign policy priorities towards the East, recorded in the course of research of public opinion in Russia in different periods of modern history of the country.
СОЦИАЛЬНЫЙ МЕГАПРОЕКТ XXI ВЕКА «ЕДИНАЯ ЕВРАЗИЯ: ТРАНС-ЕВРАЗИЙСКИЙ
Authors: О.И. КАРАСЕВ , Т.В. ХОЛОДОВА
Published: November 2024

В статье рассмотрены актуальностьи перспективы крупномасштабных проектов по созданию транспортных коридоров с участием России. Представлен проект, разработанный под эгидой Межведомственного координационного совета РАН «Транснациональное развитие Евразийского континента», дана характеристика направлений и ожидаемых эффектов его реализации. Показана важность данной инициативы как инструмента развития российских регионов.

The article discusses the relevance and prospects of large-scale projects to create transport corridors with the participation of Russia. A project developed under the auspices of the Interdepartmental Coordinating Council of the Russian Academy of Sciences «Transnational Development of the Eurasian Continent» is presented, and the directions and expected effects of its implementation are characterized. The importance of this initiative as a tool for the development of Russian regions is shown.
Visible light-mediated synthesis of 1,3-benzothiazoles: A comprehensive review
Authors: Palchykov Vitalii
Published: November 2024

Photoredox catalysis has emerged as a powerful tool in organic synthesis, revolutionizing how chemists approach challenging bond-forming reactions. The importance of 1,3-benzothiazoles lies in their diverse roles in medicinal chemistry, materials science, and industrial applications, due to their stability, bioactivity, and versatility as building blocks. This review represents the most comprehensive work to date on photochemical methods for synthesizing 1,3-benzothiazoles, covering developments in this field from 2009 to 2024. It is organized by the types of starting compounds and discusses synthetic strategies for the target compounds alongside proposed reaction mechanisms. Notably, many established light-driven methods are photocatalyst-free and typically conducted under visible light (CFL, white, green, or blue LED) at room temperature. By exploring a range of synthetic methods, this review not only deepens our understanding of benzothiazole synthesis but also inspires possibilities for future advancements. We hope this review will motivate chemists to pursue new, environmentally friendly methods for synthesizing these and related biologically significant sulfur heterocycles.
Anions in corrosion: Influence of polymer electrolytes on the interfacial ion transfer kinetics of Cu at Au(111) surfaces
Authors: Thurman Kira , Cannan Caitlyn , Shekhar Raj , Zhao Yang , Boettcher Shannon , Kempler Paul
Published: November 2024

The corrosion kinetics of metals in the presence of polymer electrolytes—which are frequently used in devices for the electrochemical production of hydrogen, hydrocarbons, and alcohols—is convoluted by transport and ill-defined reactive interfaces which mask the fundamental reaction kinetics. Underpotential-deposited monolayers of Cu at Au(111) surfaces provide a structurally well-defined active site for interfacial ion transfer, with a fixed number of sites available for adsorption. Here, we investigate the adsorption behavior of Cu at Au(111) surfaces across a series of sulfate and sulfonate electrolytes, to understand how anion structure influences the kinetics of elementary interfacial ion-transfer reactions. The influence of anion structure is most significant at high adsorbate coverage, with similar adsorption isotherms and kinetics observed for all three molecular sulfates and sulfonates. In contrast, a suspended perfluorosulfonic acid ionomer reduced both the equilibrium coverage of Cu as well as the standard exchange rate at Au(111) at low coverages of Cu. These results suggest that electrocatalyst corrosion is inhibited for metal nanoparticles supported at polymer electrolytes due to changes in adsorbate coverage as well as suppressed kinetics for interfacial ion transfer.
Dissolved Oxygen Redox as the Source of Hydrogen Peroxide and Hydroxyl Radical in Sonicated Emulsive Water Microdroplets
Authors: Asserghine Abdelilah , Baby Aravind , N’Diaye Jeanne , I. B. Romo Adolfo , Das Supriya , Rodríguez-López Joaquín
Published: November 2024

Sonicated emulsive water microdroplets (SEWMs) accelerate and enable a variety of catalyst-free chemical transformations. However, significant unanswered questions remain regarding the chemical intermediates they form and their possible redox origin. In this study, we identified dissolved O2 as the primary originator of reactive oxygen species (ROS) such as OH• and H2O2. We uncovered the role of dissolved O2 redox by using a combination of microelectrochemical methods to detect H2O2, isotopic methods to identify the source of H2O2, and a combination of electron spin resonance and the DMPO spin trap to detect radicals such as OH•. Notably, we found that H2O2 production is correlated with O2 content via a reduction pathway enabled by a sufficiently large reducing power that can additionally generate H2 and even perform Pb electroless deposition on Au and Cu metal substrates. Building on our findings, continuous O2 bubbling of SEWMs showed accumulation of H2O2 up to ~88 mM in the aqueous phase within one hour of sonication, demonstrating the scale-up promise of this method. Distinct to sonochemistry of a single phase, this study advances our understanding of the confluence of redox and chemical reaction mechanisms within SEWMs, paving the way to improving their kinetics, yield, and selectivity, positioning these attractive redox microreactors as alternatives to traditional electrolyzers.
Density Functional Theoretical method for modelling Cobalt-doped g-C3N4 sensor for detecting aniline - a cancer biomarker
Authors: Mohanan K Sneha , V. N Dhilshada. , Chattopadhyaya Mausumi
Published: November 2024

Using DFT calculations, we investigated the sensitivity of the lung cancer biomarkers, such as acetone, ethanol, and aniline - on pristine and Cobalt (Co)-doped g-C3N4 systems. The adsorption energy calculations reveal that these biomarkers undergo chemisorption on pristine g-C3N4, resulting in long recovery times, which restricts the suitability of pristine g-C3N4 as a sensor. Alternatively, the band gap of Co-g-C3N4 (0.98 eV) is lower than that of pristine g-C3N4 (1.33 eV), which increases the conductivity of Co-g-C3N4 (5.11 × 10⁻⁹ S/m) compared to pristine g-C3N4 (5.714 × 10⁻¹² S/m) - suggesting obvious selective sensitivity towards the biomarkers. Our results indicate that acetone adsorbs on the Co-g-C3N4 surface via chemisorption process, aniline undergoes physisorption, and ethanol exhibits an intermediate adsorption behaviour. Recovery time analysis revealed that aniline (0.09 s) and ethanol (3.64 s) can be recovered quickly at 398 K, which further accelerates under UV irradiation at 298 K. However, the conductivity calculations revealed that aniline exhibits the highest conductivity of 1.72 × 10-7 and the work function calculations manifested stronger sensitivity of Co-g-C3N4 towards aniline compared to acetone and ethanol. These results predict, Co-g-C3N4 as a superior sensor for aniline biomarker due to its physisorption behaviour, lower recovery time, higher conductivity and significant change in work function. The state-of-the-art analysis of Co-g-C3N4 as a promising reusable sensor for detecting aniline in exhaled breath is hitherto unknow to date.
The Chemistry of Henna: A Module for High School Students
Authors: Williams Shoshana , Appel Eric
Published: November 2024

Here we present a hands-on module for high school students to explore the chemistry of henna dye. This lesson is affordable, accessible, adaptable, and engaging for students. In this lesson, students are shown how henna paste is derived from the henna shrub, discuss the chemical structure of the main dye component lawsone (2-hydroxy-1,4-napthoquinone), apply the henna paste to their skin, and discuss the darkening of the dye over time as a result of lawsone oxidation. Through understanding the chemistry of henna, students are encouraged to consider the influence of chemical reactions in their daily lives. This module also promotes diversity and inclusion in science by increasing the representation of non-Western cultures in the chemistry curriculum. In this work, the module is presented in detail, and student reactions are discussed.
Examining proton conductivity of metal-organic frameworks by means of machine learning
Authors: Dudakov Ivan , Savelev Sergei , Nevolin Iurii , Mitrofanov Artem , Korolev Vadim , Gorbunova Yulia
Published: November 2024

The tunable structure of metal–organic frameworks (MOFs) is an ideal platform to meet contradictory requirements for proton exchange membranes: a key component of fuel cells. Nonetheless, rational design of proton-conducting MOFs remains a challenge owing to the intricate structure–property relationships that govern the target performance. In the present study, the modeling of quantities available for hundreds of MOFs was scaled up to many thousands of entities using supervised machine learning. The experimental dataset was curated to train multimodal transformer-based networks, which integrated crystal-graph, energy grid, and global-state embeddings. Uncertainty-aware models revealed superprotonic conductors among synthesized MOFs that have not been previously investigated for the application in question, thus highlighting magnesium-containing frameworks with aliphatic linkers as high-confidence candidates for experimental validation. Furthermore, classifiers trained on the activation energy threshold effectively discriminated between well-known proton conduction mechanisms, thereby providing physical insights beyond the black-box routine. Thus, our findings prove high potential of data-driven materials design, which is becoming a valuable addition to experimental studies on proton-conducting MOFs.
Elastic frustration affecting multi-step spin crossover behaviour in two differently interpenetrated FeII-dicyanoargentate 3D Hofmann coordination polymers
Authors: GUPTA ARINDAM , PAUL ABHIK , MONDAL DIBYA JYOTI , KONAR SANJIT
Published: November 2024

The effect of elastic frustration on the multi-step SCO behaviour has been investigated in two differently interpenetrated [Fe(DPyN){Ag(CN)2}2] Hofmann coordination polymers (CPs) (DPyN = 2,6-di(pyridin-4-yl)naphthalene), influenced by argentophilic, ionic and non-covalent interactions.
El territorio y la memoria como significados temáticos en Sonidos vecinos (2012)
Authors: Núñez-Alberca Alejandro
Published: November 2024

En el presente artículo se analiza el proceso de tematización fílmica presente en la película Sonidos vecinos (2012) del director brasileño Kleber Mendonça Filho. El objetivo fue identificar los distintos elementos de la puesta en escena y de la narrativa que manifiestan continuamente los sentidos asociados al territorio y a la memoria para establecerlos como ejes centrales en la construcción de los personajes del relato en la película. El enfoque fue cualitativo y se empleó el análisis textual como principal metodología de estudio para señalar los principales elementos del lenguaje audiovisual y sus asociaciones semánticas. Se concluye que la película utiliza el montaje y la puesta en escena para asociar la presencia de ciertos personajes con los diferentes espacios y temporalidades de la diégesis, y marcar una relación semántica entre los unos y los otros. De este modo, el filme convierte el espacio territorial y la memoria en elementos de vital importancia para entender a los personajes, lo que se asocia temáticamente con una de las tendencias actuales del cine latinoamericano como lo es el estudio de la memoria.
Competencias en comunicación y periodismo: una base común latinoamericana
Authors: Roveda Hoyos Antonio , Aguaded-Gómez José Ignacio
Published: November 2024

Esta investigación devela las competencias comunes del componente disciplinar de los programas académicos profesionales en Comunicación o Periodismo en América Latina en los casos de universidades de Argentina, Colombia y México. Su relevancia radica en contribuir al diseño de herramientas, métodos e indicadores que mejoren la calidad de la educación superior en América Latina, a partir del estudio de los procesos de formación y evaluación por competencias. Además, proporciona pautas para la homologación y convalidación de estudios a nivel nacional e internacional. La metodología incluyó cinco pasos: selección de instituciones de educación superior (IES), elección de programas académicos, identificación de competencias declaradas por los programas, categorización de competencias en los sílabos de asignaturas disciplinares y caracterización de competencias comunes en asignaturas disciplinares. A través de ellos, se halló (1) la ruptura de la prevalencia de la competencia cognitiva tradicional y (2) el diálogo entre dimensiones del profesional integral. Finalmente, se concluyó que se requiere de una base sólida para evaluar la calidad de la formación y de la necesidad del fomento del diálogo entre pares, el autoconocimiento y la autorregulación.
A review on the case report of significant effects of antibiotics-induced lingua villosa nigra
Authors: Shaik Dr Salma , Chamundeswari P. , Jyothi J. , Jyosthna S. , Kumari T. Rathna , Nivedhitha Dr. S
Published: November 2024

Antibiotics are commonly used to treat various bacterial and fungal infections. While effective, prolonged antibiotic use can lead to side effects, such as gastrointestinal ulcerations affecting the stomach, small intestine, and large intestine. Rarely, unusual reactions like "black hairy tongue" can occur. This condition results from the overgrowth of papillae on the tongue's surface, giving it a dark, furry appearance.Here, we present a case involving a female patient with Type II diabetes mellitus and a perirenal abscess who developed black hairy tongue as a rare side effect of extended antibiotic use. Her diabetes and infection complicated both the management of her primary condition and her antibiotic treatment. This case study explores the onset of this adverse reaction, its impact on the patient, and the duration of her recovery. Additionally, we will discuss the preventive measures taken to treat the condition and outline strategies to prevent similar complications in future antibiotic therapies.
STABILIZATION EXERCISE VERSUS McConnell TAPING ON PAIN, FUNCTION, AND RANGE OF MOTION IN PATIENTS WITH PATELLO FEMORAL PAIN SYNDROME
Authors: Naidu P Harshitha , K Pearlson
Published: November 2024

Background: Patellofemoral pain syndrome (PFPS) is characterized by anterior knee pain or retro-patellar pain (pain behind the patella). It is one of the most common knee issues, particularly affecting women. PFPS typically presents as diffuse discomfort with a gradual onset in the anterior knee, primarily affecting young athletes. The prevalence of PFPS ranges from 8.75% to 17%, with females being more affected (12.7%) than males (1.1%).Methods: Thirty subjects with PFPS, aged 15-45 years, were recruited based on inclusion and exclusion criteria. They were randomly divided into two groups. Demographic and clinical characteristics were recorded. Pain and function were evaluated using the Visual Analog Scale (VAS) and Anterior Knee Pain Scale (AKPS), while knee range of motion (ROM) was measured with a goniometer. Group A received stabilization exercises and conventional therapy, while Group B received McConnell taping with conventional treatment. Sessions were held thrice weekly for 30-45 minutes over four weeks.Results: Both interventions significantly improved pain, function, and ROM. Group A showed greater improvement in pain reduction and function (p<0.05), while ROM improvement was comparable between the two groups (p>0.05).Conclusion: While both treatments were effective, stabilization exercises provided more significant benefits in pain reduction and functional improvement.
NEUROPATHY IN DIABETIC MELLITUS: CAUSES, DIAGNOSIS AND THERAPEUTIC MODELS
Authors: Chakra Dr. R Gautham , Priya B Chandana , Bhuvaneswari D , Gowsalya P , Likhitha K , Gowtham K Pavan
Published: November 2024

Diabetic neuropathy (DN) is the most common and severe side effect of diabetes mellitus, associated with high morbidity and mortality rates, significantly straining diabetes care. Modern definitions describe diabetic neuropathy as a symmetric, length-dependent sensory polyneuropathy resulting from metabolic changes and microvascular damage due to prolonged hyperglycemia and cardiovascular risk factors. The management and clinical assessment of DN are complex. Patients with DN should be evaluated for autonomic neuropathy, as these conditions often coexist. Currently, duloxetine and pregabalin are the primary medications prescribed for neuropathic pain, yet neither offers complete relief, even when combined. This study reviews the available treatments and current guidelines for managing diabetic neuropathy, focusing on pain management and diabetic autonomic neuropathy. There remains a critical need to investigate medication combinations that may more effectively reduce or even reverse the progression of the disease while enhancing pain relief. Addressing these gaps could lead to improved outcomes for patients suffering from this debilitating condition.
The Nature of Technological Change 1960-2016
Authors: Cavounidis Costas , Dicandia Vittoria , Lang Kevin , Malhotra Raghav
Published: November 2024

We present a unified technological explanation of both the movement of workers across jobs using different skills and the changes in skill use within jobs. An envelope-theorem approach allows us to estimate relative skill-productivity growth from worker mobility using OLS while making minimal assumptions on each occupation's production function. Using six decades of data, we conclude that routine-cognitive- and finger-dexterity-skill productivity grew rapidly and abstract- and social-skill productivity grew slowly - a form of "skill bias." These effects, along with our estimated relationships between skill inputs, also explain changes in skill use within occupations.
Going with the Grain of the Landscape: rethinking our approach to environmental policy
Authors: Upton Simon , Simmons Geoff , Lanari Nora , Paterson Matt
Published: November 2024

There are doubts about whether the current approach to regulating the impacts of land use in rural Aotearoa is making a difference. This article starts by outlining four challenges policymakers face when designing policies to protect the environment while balancing social, cultural and economic interests. We then discuss some of the barriers landowners encounter when contemplating land use change to address environmental degradation. Finally, we sketch out an adaptive approach to rethinking how we do environmental policy, including by devolving some decision making to communities, providing better environmental information, being explicit about the costs and trade-offs, and reforming the New Zealand Emissions Trading Scheme.
Application of Zhao Shi Lei-huo-jiu Based on ERAS Concept in Managing Postoperative Gastrointestinal Symptom Cluster in Rectal Cancer
Authors: Lili Bu  , Long Peng
Published: November 2024

This study explores the application value of Zhao Shi Lei-huo-jiu in managing common postoperative gastrointestinal symptom clusters following rectal cancer surgery, under the framework of the Enhanced Recovery After Surgery (ERAS) concept. By detailing the development, core elements, and application of ERAS in colorectal surgery, combined with the historical origins, unique techniques, and mechanisms of Zhao Shi Lei-huo-jiu, this paper highlights the innovation of integrating traditional Chinese medicine treatments with modern surgical recovery principles. Through a rigorously designed research process, rectal cancer postoperative patients were selected as research subjects, and the data collection and implementation steps were explicitly outlined. The study results provide scientific evidence for the practical efficacy and advantages of Zhao Shi Lei-huo-jiu in postoperative rehabilitation for rectal cancer, offering significant practical implications for guiding clinical practice and promoting early patient recovery.
The Effect of Ginger Slice Acupoint Application Combined with Moxibustion on Chemotherapy-Induced Vomiting in Postoperative Breast Cancer Patients
Authors: Guo Xiangyu
Published: November 2024

Objective: To investigate the effect of ginger slice acupoint application combined with moxibustion on chemotherapy-induced vomiting in postoperative breast cancer patients. Methods: Sixty postoperative breast cancer patients undergoing chemotherapy were randomly divided into an observation group and a control group, with 30 patients in each group. The control group received antiemetic treatment with dolasetron, while the observation group received ginger slice acupoint application combined with moxibustion in addition to antiemetic treatment to address chemotherapy-induced vomiting. The vomiting response on days 1–3 was compared between the two groups, along with R-INVR retching scores and patient satisfaction with the intervention methods. Results: On days 2 and 3 of chemotherapy, the observation group showed significantly less vomiting than the control group, with differences reaching a highly significant level (P < 0.001). On day 3, the R-INVR score in the observation group was significantly lower than that of the control group, with a highly significant difference (P < 0.001). The satisfaction score in the observation group was 8.38 ± 0.81, higher than the control group’s 7.65 ± 0.71, with a statistically significant difference (P < 0.05). Conclusion: Ginger slice acupoint application combined with moxibustion effectively alleviates chemotherapy-induced vomiting in postoperative breast cancer patients, improves quality of life, and is worth promoting clinically.
Risk Factors Associated with Rupture of Multiple Intracranial Aneurysms
Authors: Dong Yanhua , Xu Wenjuan , Liu Aihua
Published: November 2024

Objective: To identify risk factors associated with multiple intracranial aneurysm (MIA) rupture. Methods: This retrospective study included patients with MIAs diagnosed at the center between February 2010 and December 2015. Patients were grouped based on their history of aneurysmal subarachnoid hemorrhage (aSAH) into ruptured and unruptured categories. In the ruptured group, aneurysms were further classified as ruptured MIAs (R-MIAs) and unruptured MIAs (U-MIAs). Patient- and aneurysm-related factors were analyzed using univariate analysis to determine their significance in rupture risk. Receiver operating characteristic (ROC) analysis was employed to calculate the area under the curve (AUC) and identify optimal thresholds for five morphological parameters distinguishing R-MIAs from U-MIAs. Results: Of 368 enrolled patients, 327 (86 with ruptured aneurysms and 241 unruptured) were included in the analysis. Among the ruptured group, 66 patients had R-MIAs and 96 had U-MIAs. Univariate analysis identified statistically significant factors associated with rupture, including BMI, irregular aneurysm shape, size, aspect ratio, size ratio, and bottleneck (P < 0.05). Size, size ratio, and bottleneck exhibited high AUC values (AUC > 0.7). ROC analysis determined an optimal threshold of 4.6 mm for MIA rupture size. Conclusions: Lower BMI, irregular aneurysm shape, larger size, larger size ratio, and bottleneck are associated with an increased risk of MIA rupture. Notably, MIAs may rupture at smaller sizes compared to single intracranial aneurysms.
UNEMPLOYMENT OF VOCATIONAL HIGH SCHOOL GRADUATES: THE EFFECT OF WORK SKILLS, FAMILY SOCIO-ECONOMIC STATUS, AND ENTREPRENEURIAL ATTITUDES ON WORK READINESS
Authors: Agussalim Agussalim , Mukhlis Imam , Rohayati Suci , Wahyuni Wahyuni , Said Sitaman
Published: November 2024

The aim of this research is to examine the impact of work skills and family socio-economic status on work readiness, with entrepreneurial attitude as an intervening variable for Vocational High School graduates. A total of 179 graduates of Bima State Vocational School were the research sample, using a non-probability sampling approach, specifically for graduates from 2015 to 2022 who had not worked in their field of expertise for more than one year. The questionnaire instrument was designed based on research variables to collect research data. Data analysis uses Structural Equation Modeling (SEM). The results indicate that both work skills and family socioeconomic status do not play a substantial role in determining work readiness. On the other hand, having an entrepreneurial mindset has a noteworthy and positive effect on work readiness. Furthermore, it was observed that job skills and family socioeconomic status indeed influence work readiness, with entrepreneurial attitude serving as a key factor. The entrepreneurial mindset heavily shapes the work readiness of vocational high school graduates. Hence, the vocational education curriculum must emphasize the development of entrepreneurial attitudes and work readiness.
INVESTIGATING THE ROLE OF ENTREPRENEURIAL LITERACY AND DIGITAL ECONOMY LITERACY ON THE SUCCESS OF MSMES IN THE CULINARY SECTOR: WHY DOES ENTREPRENEURIAL MOTIVATION MATTER?
Authors: Ahmad Muh. Ihsan Said , Rahmi  , Rijal Syamsu , Supatminingsih Tuti , Hasan Muhammad
Published: November 2024

The aim of this research is to gain knowledge and understanding regarding the influence of Entrepreneurial Literacy and Digital Economic Literacy on the Success of MSMEs in the Culinary Sector in Makassar City with Entrepreneurial Motivation as a Moderator Variable. The method used is quantitative research techniques with descriptive research type. The sample in the research was 100 Culinary MSME Business Actors. Data analysis uses the Partial Least Square Structural Equation Model (PLS- SEM). The research results obtained are, 1. Entrepreneurial literacy and digital economic literacy have an influence on entrepreneurial motivation; 2. Entrepreneurial literacy and digital economic literacy have a significant effect on business success; 3. Entrepreneurial motivation has a significant influence on business success; 4. Entrepreneurial motivation is able to mediate the relationship between entrepreneurial literacy and business success; 5. Entrepreneurial motivation is able to mediate the relationship between entrepreneurial literacy and business success.
DO HUMAN RESOURCES ACCOUNTING DISCLOSURE DETER INVESTORS' DECISIONS IN THE BANKING SECTOR?
Authors: Sundari Siti , Hidayat Widi , Isnalita  , Nuswantara Dian Anita , Run Pharatt
Published: November 2024

A different perspective of management and shareholders may cause conflict that hampers long-term organizational objectives. Human Resources Accounting (HRA) as an element of long-term investment has become more prevalent as information that deters investor decisions. This study enlarges shareholder theory that focuses on HRA disclosure as voluntary disclosure. The quantitative approach using PLS-SEM provides empirical evidence that HRA disclosure mediates the relationship between firm size-firm value and profitability-firm size in a negative direction. The mediation form of HRA disclosure on profitability's effect on firm value is full mediation. Q2 of 25.2% indicates that the Firm's Size, profitability, and HRA disclosure can explain the variation in the firm's value change by 25.2%. Therefore, future research should include other variables that affect the firm's value, including NPL, CAR, and company age. This finding contributes to revisiting voluntary disclosure theory by questioning the theory. And give additional evidence from the signaling theory perspective that the voluntary one failed to send a good signal to the receiver.
Más allá de la luz: revolución, sensorialidad y experiencia estética en El águila y la serpiente
Authors: Abreu Mendoza Carlos
Published: November 2024

A partir de un análisis de El águila y la serpiente (1928), este ensayo propone una apertura de la recepción de la obra de Martín Luis Guzmán a los estudios de la percepción sensible, los sentidos y el afecto. Para ello, examino la manera en Guzmán reproduce y cuestiona la ideología estético-política del Ateneo de la Juventud y las metáforas ocularcéntricas que le dan forma. A partir de un enfoque en la percepción y los afectos que emergen en el paisaje nocturno de la novela, profundizo en aquellas instancias que apelan a una sensorialidad alternativa para confrontar y dar forma literaria a la Revolución como un momento de ruptura, crisis cultural y cambio social.