bluuebunny/crossref_metadata_2025 huggingface dataset:
Ultralight Industrial Bamboo Residue-Derived Holocellulose Thermal Insulation Aerogels with Hydrophobic and Fire Resistant Properties
Authors: Huang Hanxiao , Yu Yunshui , Qing Yan , Zhang Xiaofeng , Cui Jia , Wang Hankun
Published: January 2020

In this study, water-soluble ammonium polyphosphate- (APP) and methyl trimethoxysilane (MTMS)-modified industrial bamboo residue (IBR)-derived holocellulose nanofibrils (HCNF/APP/MTMS) were used as the raw materials to prepare aerogels in a freeze-drying process. Synthetically modified aerogels were confirmed by Fourier transform infrared spectroscopy, X-ray diffraction, and thermal stability measurements. As-prepared HCNF/APP/MTMS aerogels showed themselves to be soft and flexible. The scanning electron microscopy (SEM) analysis showed that the foam-like structure translates into a 3D network structure from HCNF aerogels to HCNF/APP/MTMS aerogels. The compressive modules of the HCNF/APP/MTMS aerogels were decreased from 38 kPa to 8.9 kPa with a density in the range of 12.04–28.54 kg/m3, which was due to the structural change caused by the addition of APP and MTMS. Compared with HCNF aerogels, HCNF/APP/MTMS aerogels showed a high hydrophobicity, in which the water contact angle was 130°, and great flame retardant properties. The peak of heat release rate (pHRR) and total smoke production (TSP) decreased from 466.6 to 219.1 kW/m2 and 0.18 to 0.04 m2, respectively, meanwhile, the fire growth rate (FIGRA) decreased to 8.76 kW/s·m2. The thermal conductivity of the HCNF/APP/MTMS aerogels was 0.039 W/m·K. All results indicated the prepared aerogels should be expected to show great potential for thermally insulative materials.
Influence of Annealing on the Damping Behavior of Ni-Cu-Mn-Ga Ferromagnetic Shape Memory Alloys
Authors: Liao Xiaoqi , Xu Xin , Gao Lumei , Khan Muhammad Tahir , Hao Chunxi , Cheng Fei , He Yuewei , Wang Yu
Published: January 2020

Damping materials have attracted much attention for wide potential applications in the industry. Previous research shows that annealing treatment is an effective and costless way of improving the functional properties of conventional shape memory alloys. However, there are few investigations concerning the annealing effect of the ambient-temperature damping behavior. In this paper, we present the influence of annealing treatment on the martensitic transformation and damping behaviors of Ni 55 − x Cu x Mn 25 Ga 20 (x = 0, 2, 4, 6) alloys within the ambient-temperature range. With increasing annealing time, the martensitic transformation temperature and the temperature span of martensitic transformation decrease. Moreover, annealing treatment greatly enhances the twin boundary damping peak of martensite. The X-ray diffraction (XRD) measurement demonstrates that annealing can improve the degree of L2 1 atomic order, which relieves the pinning effects for the twin boundary motion and thus leads to the enhancement of the twin boundary damping of these alloys.
Magnetic and Golden Yogurts. Food as a Potential Nanomedicine Carrier
Authors: Garcés Víctor , González Ana , Sabio Laura , Sánchez-Arévalo Carmen M. , Gálvez Natividad , Dominguez-Vera José M.
Published: January 2020

Yogurt is one of the most emblematic and popular fermented foods. It is produced by the fermentation of milk lactose by bacteria such as Streptococcus thermophilus and Lactobacillus acidophilus. Magnetic (MNPs) and gold nanoparticles (AuNPs) were incorporated into the exopolysaccharides (EPSs) of these bacteria. The functionalized bacteria were characterized by UV-vis spectroscopy and transmission electron microscopy. A large number of MNPs and AuNPs were bound to the bacterial EPS. Interestingly, the nanoparticles’ (NPs) presence did not affect the bacteria’s capacity to ferment milk and to produce magnetic and golden yogurts. Magnetic and golden yogurts represent the perfect combination of emblematic food and nanoparticles and have a range of potential biomedical applications: use in iron-deficiency anemia, diagnosis and hyperthermia treatment of appropriate digestive diseases, and interest in glamour cuisine.
Modification of Ordinary Concrete Using Fly Ash from Combustion of Municipal Sewage Sludge
Authors: Rutkowska Gabriela , Wichowski Piotr , Franus Małgorzata , Mendryk Michał , Fronczyk Joanna
Published: January 2020

This article focuses on the impact of fly ash from the combustion of municipal sewage sludge (FAMSS) as a cement additive in the amounts of 5%, 10%, 15%, 20% and 25% (by mass) on selected concrete properties. In the course of the experimental work, water penetration depth and compressive strength measurements were made at various periods of curing (from 2 to 365 days). In addition, the potential impact of FAMSS on the natural environment was examined by determining the leachability of heavy metals. FAMSS-modified concretes showed small values of water penetration depth (lower than 50 mm), as well as good compressive strength (reaching minimum class C30/37 after 130 days of maturing)—similar to the compressive strength obtained for conventional concrete. In addition, the partial replacement of cement with FAMSS has environmental benefits, expressed as a reduction in CO2 emissions. In addition, study has shown that compliance with environmental requirements is associated with heavy metal leaching.
Venture Capital Contracting with Ambiguity Sharing and Effort Complementarity Effect
Authors: Chang Jiajia , Hu Zhijun , Yang Hui
Published: January 2020

In this paper, we established a continuous-time agency model in which an ambiguity-averse venture capitalist (VC) employs an ambiguity-neutral entrepreneur (EN) to manage an innovative project. We analyzed the connection between ambiguity sharing and incentives under double moral hazard. Applying a stochastic dynamic programming approach, we solved the VC’s maximization problem and obtained the Hamilton–Jacobi–Bellman (HJB) equation under a special form of the value function. We showed that the optimal pay-performance sensitivity was a fixed point of a nonlinear equation. The model ambiguity on the probability measure induced a tradeoff between ambiguity sharing and the incentive compensation that improved the EN’s pay-performance sensitivity level. Besides, we simulated the model and showed that when two efforts were complementary, the VC’s effort did not monotonically decrease with respect to the pay-performance sensitivity, while the EN’s effort did not monotonically increase in the pay-performance sensitivity level. More importantly, we found that as efforts tended to be more complementary, the optimal pay-performance sensitivity tended to approach those that maximized the efforts exerted by the EN and the VC.
Altertoxins with Quorum Sensing Inhibitory Activities from The Marine-Derived Fungus Cladosporium sp. KFD33
Authors: Zhang Fei , Zhou Liman , Kong Fandong , Ma Qingyun , Xie Qingyi , Li Jiuhui , Dai Haofu , Guo Lei , Zhao Youxing
Published: January 2020

Five new perylenequinone derivatives, altertoxins VIII–XII (1–5), as well as one known compound cladosporol I (6), were isolated from the fermentation broth of the marine-derived fungus Cladosporium sp. KFD33 from a blood cockle from Haikou Bay, China. Their structures were determined based on spectroscopic methods and ECD spectra analysis along with quantum ECD calculations. Compounds 1–6 exhibited quorum sensing inhibitory activities against Chromobacterium violaceum CV026 with MIC values of 30, 30, 20, 30, 20 and 30 μg/well, respectively.
Acknowledgement to Reviewers of Medicina in 2019
Authors: Medicina Editorial Office
Published: January 2020

The editorial team greatly appreciates the reviewers who have dedicated their considerable time and expertise to the journal’s rigorous editorial process over the past 12 months[...]
Accuracy of the qSOFA Score and RED Sign in Predicting Critical Care Requirements in Patients with Suspected Infection in the Emergency Department: A Retrospective Observational Study
Authors: Park Jong Eun , Hwang Sung Yeon , Jo Ik Joon , Sim Min Seob , Cha Won Chul , Yoon Hee , Kim Tae Rim , Lee Gun Tak , Kim Hye Seung , Sohn InSuk , Shin Tae Gun
Published: January 2020

Background and objectives: We aimed to compare the accuracy of positive quick sequential organ failure assessment (qSOFA) scores and the RED sign in predicting critical care requirements (CCRs) in patients with suspected infection who presented to the emergency department (ED). Materials and Methods: In this retrospective observational study, we examined adult patients with suspected infection in the ED from June 2018 to September 2018. A positive qSOFA (qSOFA+) was defined as the presence of ≥2 of the following criteria: altered mental status (AMS), systolic blood pressure (SBP) < 100 mmHg, and respiratory rate (RR) ≥ 22 breaths/min. A positive RED sign (RED sign+) was defined as the presence of at least one of the RED sign criteria: AMS, skin mottling, SBP < 90 mmHg, heart rate >130 beats/min, or RR > 30 breaths/min. A qSOFA/RED+ was defined as the presence of qSOFA+ or RED+. We applied these tools twice using the initial values upon ED arrival and all values within 2 h after ED arrival. The accuracy of qSOFA+, RED+, and qSOFA/RED+ in predicting CCR was assessed. Results: Data from 5353 patients with suspected infection were analyzed. The area under the receiver operating characteristic curve (AUC) of RED+ (0.67, 95% confidence interval [CI]: 0.65–0.70) and that of qSOFA/RED+ (0.68, 95% CI: 0.66–0.70, p < 0.01) were higher than the AUC of qSOFA+ (0.59, 95% CI: 0.57–0.60) in predicting CCR on ED arrival. The qSOFA/RED+ within 2 h showed the highest accuracy (AUC 0.72, 95% CI: 0.70–0.75, p < 0.001). Conclusions: The accuracy of the RED sign in predicting CCR in patients with suspected infection who presented at ED was better than that of qSOFA. The combined use of the RED sign and qSOFA (positive qSOFA or RED sign) showed the highest accuracy.
Acknowledgement to Reviewers of Membranes in 2019
Authors:   Membranes Editorial Office
Published: January 2020

The editorial team greatly appreciates the reviewers who have dedicated their considerable time and expertise to the journal’s rigorous editorial process over the past 12 months, regardless of whether the papers are finally published or not [...]
Welding Metallurgy and Weldability of Superalloys
Authors: Andersson Joel
Published: January 2020

Fabrication and welding of structural superalloy components for aero-engines, land-based gas turbines as well as for the energy sector (i [...]
Microstructures Evolution in Refill Friction Stir Spot Welding of Al-Zn-Mg-Cu Alloy
Authors: Zhao Yunqiang , Dong Chunlin , Wang Chungui , Miao Shu , Tan Jinhong , Yi Yaoyong
Published: January 2020

In this study, Al-Zn-Mg-Cu alloy was refill friction spot welded, and the precipitates, dislocation, recovery, and recrystallization characteristics were focused. In the stir zone (SZ), continues dynamic recrystallization occurs under the intense plastic deformation. All the original GP (II) zones and η’ precipitates dissolved into the aluminum matrix under the welding heat input, and the stable η and E precipitates remained. In the thermo-mechanically affected zone (TMAZ), high-density dislocations and subgrains boundaries can be observed. The continued dynamic recrystallization was not activated and only dynamic recovery occurs. Sub-boundaries and high-density dislocations in this zone can be observed. In this zone, the η precipitates are coarsened and dissolution is the main evolution mechanism for the GP (II) zones and η’ precipitates. In the heat-affected zone (HAZ), no dislocation was induced and all the initial precipitates were coarsened under the welding heat input. The HAZ, the TMAZ, and the SZ constitute a soft region in the refill friction stir spot welding (RFSSW) joint, and the minimum value located at the interface between the HAZ and the TMAZ.
Distribution of Arsenic Inclusions in Rare Earth Steel Ingots
Authors: Wang Hongpo , Jiang Silu , Yu Peng , Bai Bin , Sun Lifeng , Wang Yu
Published: January 2020

Trace element arsenic is detrimental to the quality and properties of steel products. We used lanthanum to modify the distribution of arsenic by the formation of arsenic rare earth inclusions and investigated all inclusions on the full profile of the ingots prepared in the laboratory. The results show that the addition of lanthanum has dramatically influenced the distribution of arsenic in the ingots by the formation of arsenic inclusions. The arsenic inclusions turn out to be mainly the cluster-shaped La-S-As, as well as its composite inclusions combined with LaS and La-As. La-S-As can be considered a solid solution of LaS and LaAs. They distribute mainly at the top surface of the ingots within 3 mm, at the side and bottom surfaces within 1.5 mm, leading to a dramatic decrease of arsenic concentration at the inner part of the ingots. This distribution characteristic of La-S-As can be used to manufacture steel ingots with very low arsenic concentration by peeling off these (La-S-As)-containing layers. On the contrary, the distribution of composite inclusions (La-S-As)-(La-As) and single-phase La-As, is uniform. Except for the reaction with arsenic, lanthanum can also react with phosphorous and antimony to modify the existing state of these trace elements.
Corrosion Behaviour of Mg98.5Nd1Zn0.5 (at. %) Alloy in Phosphate Buffered Saline Solution
Authors: Cabeza Sandra , Pérez Zubiaur Pablo , Garcés Gerardo , Andrade Carmen , Adeva Paloma
Published: January 2020

The corrosion behaviour of Mg98.5-Nd1-Zn0.5 (at. %) alloy was studied in phosphate buffered saline (PBS) solution to evaluate its degradation performance as a potential candidate for biomedical applications. The alloy, produced by casting and hot extrusion, consists of a fine-grained magnesium matrix with an average grain size of 3.8 μm embedding a high volume fraction of (Mg, Zn)12Nd precipitates. Hydrogen release tests revealed a stable low corrosion rate of 0.6 mm/year after 24 h of immersion. Electrochemical testing data proved good correlation with the data from hydrogen evolution, with the corrosion rate stabilizing below 1 mm/year.
Quarter Century Development of Laser Peening without Coating
Authors: Sano Yuji
Published: January 2020

This article summarizes the development of laser peening without coating (LPwC) during the recent quarter century. In the mid-1990s, the study of LPwC was initiated in Japan. The objective at that time was to mitigate stress corrosion cracking (SCC) of structural components in operating nuclear power reactors (NPRs) by inducing compressive residual stresses (RSs) on the surface of susceptible components. Since the components in NPRs are radioactive and cooled underwater, full-remote operation must be attained by using lasers of water-penetrable wavelength without any surface preparation. Compressive RS was obtained on the top-surface by reducing pulse energy less than 300 mJ and pulse duration less than 10 ns, and increasing pulse density (number of pulses irradiated on unit area). Since 1999, LPwC has been applied in NPRs as preventive maintenance against SCC using frequency-doubled Q-switched Nd:YAG lasers (λ = 532 nm). To extend the applicability, fiber-delivery of intense laser pulses was developed in parallel and has been used in NPRs since 2002. Early first decade of the 2000s, the effect extending fatigue life was demonstrated even if LPwC increased surface roughness of the components. Several years ago, it was confirmed that 10 to 20 mJ pulse energy is enough to enhance fatigue properties of weld joints of a structural steel. Considering such advances, the development of 20 mJ-class palmtop-sized handheld lasers was initiated in 2014 in a five-year national program, ImPACT under the cabinet office of the Japanese government. Such efforts would pave further applications of LPwC, for example maintenance of infrastructure in the field, beyond the horizons of the present laser systems.
Smart Tactile Sensing Systems Based on Embedded CNN Implementations
Authors: Alameh Mohamad , Abbass Yahya , Ibrahim Ali , Valle Maurizio
Published: January 2020

Embedding machine learning methods into the data decoding units may enable the extraction of complex information making the tactile sensing systems intelligent. This paper presents and compares the implementations of a convolutional neural network model for tactile data decoding on various hardware platforms. Experimental results show comparable classification accuracy of 90.88% for Model 3, overcoming similar state-of-the-art solutions in terms of time inference. The proposed implementation achieves a time inference of 1.2 ms while consuming around 900 μ J. Such an embedded implementation of intelligent tactile data decoding algorithms enables tactile sensing systems in different application domains such as robotics and prosthetic devices.
Waddlia chondrophila and Male Infertility
Authors: Baud David , Vulliemoz Nicolas , Morales Zapata Maria Verónica , Greub Gilbert , Vouga Manon , Stojanov Milos
Published: January 2020

Waddlia chondrophila, a Chlamydia-like bacterium, has been previously associated with adverse pregnancy outcomes. Analogously to Chlamydia trachomatis, W. chondrophila also negatively impacts human semen and may be a source of impaired male fertility. In this study, we analyzed W. chondrophila seroprevalence in a population of male patients of infertile couples and the impact of past exposition to this bacterium on semen parameters. Our results show a surprisingly high seroprevalence of W. chondrophila, which contrasts with a previous study focusing on a population of healthy men. Nevertheless, we did not observe any significant association between positive serology and abnormal sperm parameters. This may suggest that a negative impact on semen is observed only during an ongoing infection. Alternatively, W. chondrophila may have an immune impact on male fertility, as previously postulated for women with adverse pregnancy outcomes.
A Comprehensive Study on the Occurrence of Mycotoxins and Their Producing Fungi during the Maize Production Cycle in Spain
Authors: García-Díaz Marta , Gil-Serna Jéssica , Vázquez Covadonga , Botia María Nieves , Patiño Belén
Published: January 2020

Mycotoxin contamination is one of the main problems affecting corn production, due to its significant risk to human and animal health. The Fusarium and Aspergillus species are the main producers of mycotoxins in maize, infecting both pre-harvest and during storage. In this work, we evaluated the presence of mycotoxins and their producing species along maize production cycles in three different stages (anthesis, harvest, and storage) during three consecutive seasons (2016–2018). Fungal occurrences were studied using species-specific PCR protocols, whereas mycotoxin levels were determined by LC-MS/MS. Fumonisin-producing Fusarium species (F. verticillioides and F. proliferatum), as well as the aflatoxin producer Aspergillus flavus, were the most predominant species at all stages; although, during some seasons, the presence of F. graminearum and A. niger aggregate species were also identified. Contrastingly, fumonisins were the only mycotoxins detected and levels were always under legal regulations. The results presented here demonstrate that even when fungal contamination occurs at the early stages of the maize production cycle, the application of good agricultural and storage practices might be crucial to ensure mycotoxin-free grains.
Riesite, a New High Pressure Polymorph of TiO2 from the Ries Impact Structure
Authors: Tschauner Oliver , Ma Chi , Lanzirotti Antonio , Newville Matthew G.
Published: January 2020

This paper describes riesite, a new high-pressure polymorph of TiO2 from the Ries impact structure, Germany. Riesite occurs in shock-induced melt veins within xenoliths of bedrock in suevite. It is structurally closely related to srilankite from which it differs by having two distinct cation sites rather than one and through its monoclinic symmetry. It is indicative that riesite forms only upon release from the shock state upon back transformation from akaogiite.
Geochemical and Sr-Nd-Pb-Hf Isotopic Characteristics of Muchen Pluton in Southeast China, Constrain the Petrogenesis of Alkaline A-Type Magma
Authors: Yan Haiyang , Wang Fangyue , Gu Hai-Ou , Sun He , Ge Can
Published: January 2020

We present comprehensive petrological, major-trace element, in situ zircon U-Pb dating and Sr-Nd-Pb isotopic data for Muchen granitoid (western Zhejiang Province, Southeast China), to constrain the petrogenesis of alkaline A-type granites and the geodynamic setting of Southeast China in the Early Cretaceous. The Early Cretaceous Muchen quartz monzonite yielded zircon U-Pb crystallization ages of 111.3 ± 0.7 Ma and is metaluminous to weakly peraluminous with SiO2 contents ranging from 59 to 69 wt.%, and can be classified as alkaline A-type granitoid. The quartz monzonites have low (87Sr/86Sr)i values (0.7052 to 0.7061) and high εNd(t) values (−2.6 to −2.0), similar to nearby coeval mafic rocks that have been proposed to be derived from the enriched lithospheric mantle. The high Nb/Ta ratios (16.7 to 30.1, average 21.8) and low Nb/U ratios (as low as 3.5) indicate the involvement of slab-derived melt and fluids in this mantle. These geochemical properties of the Muchen quartz monzonites indicated that they might be from a phlogopite-bearing and rutile-rich subduction-modified subcontinental lithospheric mantle, and underwent strong fractional crystallization of olivine + orthopyroxene + plagioclase during magma ascent. The low Mg# values of these alkaline rocks (<30 mostly) may indicate a low-pressure source in a back-arc setting. The early Cretaceous alkaline granitoids in Southeast China are related to the continental back-arc setting caused by deep angle subduction of the paleo-Pacific plate.
Surface Subsidence Prognosis above an Underground Longwall Excavation and Based on 3D Point Cloud Analysis
Authors: Pal Andrej , Rošer Janez , Vulić Milivoj
Published: January 2020

Impacts of underground mining have been reduced by continuous environmental endeavors, scientific, and engineering research activities, whose main object is the behavior and control of the undermined rock mass and the subsequent surface subsidence. In the presented Velenje case of underground sublevel longwall mining where coal is being exploited both horizontal and vertical, backfilling processes and accompanying fracturing in the coal layer, and rock mass are causing uncontrolled subsidence of the surface above. 3D point clouds of the study were acquired in ten epochs and at excavation heights on the front were measured at the same epochs. By establishing a sectors layout in the observational area, smaller point clouds were obtained, to which planes were fitted and centroids of these planes then calculated. Centroid heights were analyzed with the FNSE model to estimate the time of consolidation and modified according to excavation parameters to determine total subsidence after a certain period. Proposed prognosis approaches for estimating consolidation of active subsidence and long term surface environmental protection measures have been proposed and presented. The C2C analysis of distances between acquired 3D point clouds was used for identification of surface subsidence, reclamation areas and sink holes, and for validation of feasibility and effectiveness of the proposed prognosis.
Electrochemically Deposited NiO Films as a Blocking Layer in p-Type Dye-Sensitized Solar Cells with an Impressive 45% Fill Factor
Authors: Bonomo Matteo , Di Girolamo Diego , Piccinni Marco , Dowling Denis P. , Dini Danilo
Published: January 2020

The enhancement of photoelectrochemical conversion efficiency of p-type dye-sensitized solar cells (p-DSSCs) is necessary to build up effective tandem devices in which both anode and cathode are photoactive. The efficiency of a p-type device (2.5%) is roughly one order of magnitude lower than the n-type counterparts (13.1%), thus limiting the overall efficiency of the tandem cell, especially in terms of powered current density. This is mainly due to the recombination reaction that occurs especially at the photocathode (or Indium-doped Tin Oxide (ITO))/electrolyte interface. To minimize this phenomenon, a widely employed strategy is to deposit a compact film of NiO (acting as a blocking electrode) beneath the porous electrode. Here, we propose electrodeposition as a cheap, easy scalable and environmental-friendly approach to deposit nanometric films directly on ITO glass. The results are compared to a blocking layer made by means of sol-gel technique. Cells embodying a blocking layer substantially outperformed the reference device. Among them, BL_1.10V shows the best photoconversion efficiency (0.166%) and one of the highest values of fill factor (approaching 46%) ever reported. This is mainly due to an optimized surface roughness of the blocking layer assuring a good deposition of the porous layer. The effectiveness of the implementation of the blocking layer is further proved by means of Electrochemical Impedance Spectroscopy.
Cellulose Nanofibril/Carbon Nanomaterial Hybrid Aerogels for Adsorption Removal of Cationic and Anionic Organic Dyes
Authors: Yu Zhencheng , Hu Chuanshuang , Dichiara Anthony B. , Jiang Weihui , Gu Jin
Published: January 2020

Advances in nanoscale science and engineering are providing new opportunities to develop promising adsorbents for environmental remediation. Here, hybrid aerogels are assembled from cellulose nanofibrils (CNFs) and carbon nanomaterials to remove cationic dye methylene blue (MB) and anionic dye Congo red (CR) in single and binary systems. Two classes of carbon nanomaterials, carbon nanotubes (CNTs) and graphene nanoplates (GnPs), are incorporated into CNFs with various amounts, respectively. The adsorption, mechanics and structure properties of the hybrid aerogels are investigated and compared among different combinations. The results demonstrate CNF–GnP 3:1 hybrid exhibits the best performance among all composites. Regarding a single dye system, both dye adsorptions follow a pseudo-second-order adsorption kinetic and monolayer Langmuir adsorption isotherm. The maximal adsorption capacities of CNF–GnP aerogels for MB and CR are 1178.5 mg g−1 and 585.3 mg g−1, respectively. CNF–GnP hybrid show a superior binary dye adsorption capacity than pristine CNF or GnP. Furthermore, nearly 80% of MB or CR can be desorbed from CNF–GNP using ethanol as the desorption agent, indicating the reusability of this hybrid material. Hence, the CNF–GnP aerogels show great promise as adsorption materials for wastewater treatment.
Cationic Dye Removal Using Novel Magnetic/Activated Charcoal/β-Cyclodextrin/Alginate Polymer Nanocomposite
Authors: Yadav Sushma , Asthana Anupama , Chakraborty Rupa , Jain Bhawana , Singh Ajaya Kumar , Carabineiro Sónia A. C. , Susan Md. Abu Bin Hasan
Published: January 2020

New magnetic iron oxide (Fe3O4)/activated charcoal (AC)/β-cyclodextrin (CD)/sodium alginate (Alg) polymer nanocomposite materials were prepared by direct mixing of the polymer matrix with the nanofillers. The obtained materials were utilized as nano-adsorbents for the elimination of methylene blue (MB), a hazardous water-soluble cationic dye, from aqueous solutions, and showed excellent regeneration capacity. The formation of the nanocomposites was followed by high-resolution transmission electron microscopy (HRTEM), scanning electron microscopy (SEM) equipped with energy dispersive X-ray spectrometry (EDX), Fourier-transform infrared spectroscopy (FTIR), vibrating sample magnetometer (VSM), X-ray diffraction (XRD) and adsorption of N2 at −196 °C. The rate of adsorption was investigated varying several factors, namely contact time, pH, amount of adsorbent and MB concentration on the adsorption process. Studies dealing with equilibrium and kinetics were carried out in batch conditions. The obtained results indicated that the removal rate of MB was 99.53% in 90 min. Langmuir’s isotherm fitted better to the equilibrium data of MB. Fe3O4/AC/CD/Alg polymer beads shows amazing adsorption capacities in the elimination of cationic dyes (2.079 mg/g for polymer gel beads and 10.63 mg g−1 for dry powder beads), in comparison to other adsorbent materials. The obtained adsorbent is spherical with hydrophobic cross-linked surface properties that enable an easy recovery without any significant weight loss of in the adsorbent used.
PbE (E = S, Se) Colloidal Quantum Dot-Layered 2D Material Hybrid Photodetectors
Authors: Nakotte Tom , Luo Hongmei , Pietryga Jeff
Published: January 2020

Hybrid lead chalcogenide (PbE) (E = S, Se) quantum dot (QD)-layered 2D systems are an emerging class of photodetectors with unique potential to expand the range of current technologies and easily integrate into current complementary metal-oxide-semiconductor (CMOS)-compatible architectures. Herein, we review recent advancements in hybrid PbE QD-layered 2D photodetectors and place them in the context of key findings from studies of charge transport in layered 2D materials and QD films that provide lessons to be applied to the hybrid system. Photodetectors utilizing a range of layered 2D materials including graphene and transition metal dichalcogenides sensitized with PbE QDs in various device architectures are presented. Figures of merit such as responsivity (R) and detectivity (D*) are reviewed for a multitude of devices in order to compare detector performance. Finally, a look to the future considers possible avenues for future device development, including potential new materials and device treatment/fabrication options.
Sustainable Biomass Glucose-Derived Porous Carbon Spheres with High Nitrogen Doping: As a Promising Adsorbent for CO2/CH4/N2 Adsorptive Separation
Authors: Li Yao , Wang Shiying , Wang Binbin , Wang Yan , Wei Jianping
Published: January 2020

Separation of CO2/CH4/N2 is significantly important from the view of environmental protection and energy utilization. In this work, we reported nitrogen (N)-doped porous carbon spheres prepared from sustainable biomass glucose via hydrothermal carbonization, CO2 activation, and urea treatment. The optimal carbon sample exhibited a high CO2 and CH4 capacity, as well as a low N2 uptake, under ambient conditions. The excellent selectivities toward CO2/N2, CO2/CH4, and CH4/N2 binary mixtures were predicted by ideal adsorbed solution theory (IAST) via correlating pure component adsorption isotherms with the Langmuir−Freundlich model. At 25 °C and 1 bar, the adsorption capacities for CO2 and CH4 were 3.03 and 1.3 mmol g−1, respectively, and the IAST predicated selectivities for CO2/N2 (15/85), CO2/CH4 (10/90), and CH4/N2 (30/70) reached 16.48, 7.49, and 3.76, respectively. These results should be attributed to the synergistic effect between suitable microporous structure and desirable N content. This report introduces a simple pathway to obtain N-doped porous carbon spheres to meet the flue gas and energy gas adsorptive separation requirements.
Applications of Electrospun Nanofibers with Antioxidant Properties: A Review
Authors: Vilchez Ariel , Acevedo Francisca , Cea Mara , Seeger Michael , Navia Rodrigo
Published: January 2020

Antioxidants can be encapsulated to enhance their solubility or bioavailability or to protect them from external factors. Electrospinning has proven to be an excellent option for applications in nanotechnology, as electrospun nanofibers can provide the necessary environment for antioxidant encapsulation. Forty-nine papers related to antioxidants loaded onto electrospun nanofibers were categorized and reviewed to identify applications and new trends. Medical and food fields were commonly proposed for the newly obtained composites. Among the polymers used as a matrix for the electrospinning process, synthetic poly (lactic acid) and polycaprolactone were the most widely used. In addition, natural compounds and extracts were identified as antioxidants that help to inhibit free radical and oxidative damage in tissues and foods. The most recurrent active compounds used were tannic acid (polyphenol), quercetin (flavonoid), curcumin (polyphenol), and vitamin B6 (pyridoxine). The incorporation of active compounds in nanofibers often improves their bioavailability, giving them increased stability, changing the mechanical properties of polymers, enhancing nanofiber biocompatibility, and offering novel properties for the required field. Although most of the polymers used were synthetic, natural polymers such as silk fibroin, chitosan, cellulose, pullulan, polyhydroxybutyrate, and zein have proven to be proper matrices for this purpose.
The Application of Indium Oxide@CPM-5-C-600 Composite Material Derived from MOF in Cathode Material of Lithium Sulfur Batteries
Authors: Han Guodong , Wang Xin , Yao Jia , Zhang Mi , Wang Juan
Published: January 2020

Due to the “shuttle effect”, the cycle performance of lithium sulfur (Li-S) battery is poor and the capacity decays rapidly. Replacing lithium-ion battery is the maximum problem to be overcome. In order to solve this problem, we use a cage like microporous MOF(CPM-5) as a carbon source, which is carbonized at high temperature to get a micro-mesoporous carbon composite material. In addition, indium oxide particles formed during carbonization are deposited on CPM-5 structure, forming a simple core-shell structure CPM-5-C-600. When it is used as the cathode of Li-S battery, the small molecule sulfide can be confined in the micropores, while the existence of large pore size mesopores can provide a channel for the transmission of lithium ions, so as to improve the conductivity of the material and the rate performance of the battery. After 100 cycles, the specific capacity of the battery can be still maintained at 650 mA h·g−1 and the Coulombic efficiency is close to 100%. When the rate goes up to 2 C, the first discharge capacity not only can reach 1400 mA h·g−1, but also still provides 500 mA h·g−1 after 200 cycles, showing excellent rate performance.
Folic Acid Fortification and Neural Tube Defect Risk: Analysis of the Food Fortification Initiative Dataset
Authors: Murphy Michaela E. , Westmark Cara J.
Published: January 2020

The United States implemented mandatory fortification of cereal grains with folic acid in 1998 to prevent neural tube defects (NTDs) during pregnancy. The health benefits of folate (vitamin B9) are well documented; however, there are potential risks of exceeding the upper tolerable limit, particularly in vulnerable populations. We conducted a population-based analysis of the Food Fortification Initiative dataset to determine the strength of the evidence regarding reports of decreased NTDs at the national level in response to mandatory folic acid fortification of cereal grains. We found a very weak correlation between NTD prevalence and the level of folic acid fortification, irrespective of the cereal grain fortified (wheat, maize or rice). Stratification of the data based on socioeconomic status (SES) indicated a strong linear relationship between reduced NTDs and better SES. We conclude that national fortification with folic acid is not associated with a significant decrease in the prevalence of NTDs at the population level.
The Effects of Trifolium pratense L. Sprouts’ Phenolic Compounds on Cell Growth and Migration of MDA-MB-231, MCF-7 and HUVEC Cells
Authors: Zakłos-Szyda Małgorzata , Budryn Grażyna
Published: January 2020

Uncontrolled growth and migration and invasion abilities are common for cancer cells in malignant tumors with low therapeutic effectiveness and high mortality and morbidity. Estrogen receptor β (ERβ), as a member of the nuclear receptor superfamily, shows potent tumor suppressive activities in many cancers. Phytoestrogens’ structural resemblance to 17 β-estradiol allows their binding to ERβ isoform predominantly, and therefore, expression of genes connected with elevated proliferation, motility and invasiveness of cancer cells may be downregulated. Among polyphenolic compounds with phytoestrogenic activity, there are isoflavones from Trifolium pratense L. (red clover) sprouts, containing high amounts of formononetin and biochanin A and their glycosides. To determine the source of the most biologically active isoflavones, we obtained four extracts from sprouts before and after their lactic fermentation and/or β-glucosidase treatment. Our previous results of ITC (isothermal titration calorimetry) modelling and a docking simulation showed clover isoflavones’ affinity to ERβ binding, which may downregulate cancer cell proliferation and migration. Thus, the biological activity of T. pratense sprouts’ extracts was checked under in vitro conditions against highly invasive human breast cancer cell line MDA-MB-231 and non-invasive human breast cancer cell line MCF-7 cells. To compare extracts’ activities acquired for cancer cells with those activities against normal cells, as a third model we choose human umbilical vein endothelial cells (HUVEC), which, due to their migration abilities, are involved in blood vessel formation. Extracts obtained from fermented sprouts at IC0 dosages were able to inhibit migration of breast cancer cells through their influence on intracellular ROS generation; membrane stiffening; adhesion; regulation of MMP-9, N-cadherin and E-cadherin at transcriptional level; or VEGF secretion. Simultaneously, isolated phenolics revealed no toxicity against normal HUVEC cells. In the manuscript, we proposed a preliminary mechanism accounting for the in vitro activity of Trifolium pratense L. isoflavones. In this manner, T. pratense sprouts, especially after their lactic fermentation, can be considered a potent source of biological active phytoestrogens and a dietary supplement with anti-cancer and anti-invasion properties.
Potential Role of Tocotrienols on Non-Communicable Diseases: A Review of Current Evidence
Authors: Wong Sok Kuan , Kamisah Yusof , Mohamed Norazlina , Muhammad Norliza , Masbah Norliana , Mohd Fahami Nur Azlina , Mohamed Isa Naina , Shuid Ahmad Nazun , Mohd Saad Qodriyah , Abdullah Azman , Mohamad Nur-Vaizura , Ibrahim Nurul’ Izzah , Pang Kok-Lun , Chow Yoke Yue , Thong Benjamin Ka Seng , Subramaniam Shaanthana , Chan Chin Yi , Ima-Nirwana Soelaiman , Chin Kok-Yong
Published: January 2020

Tocotrienol (T3) is a subfamily of vitamin E known for its wide array of medicinal properties. This review aimed to summarize the health benefits of T3, particularly in prevention or treatment of non-communicable diseases (NCDs), including cardiovascular, musculoskeletal, metabolic, gastric, and skin disorders, as well as cancers. Studies showed that T3 could prevent various NCDs, by suppressing 3-hydroxy-3-methylglutaryl-coenzyme A reductase (HMGCR) in the mevalonate pathway, inflammatory response, oxidative stress, and alternating hormones. The efficacy of T3 in preventing/treating these NCDs is similar or greater compared to tocopherol (TF). TF may lower the efficacy of T3 because the efficacy of the combination of TF and T3 was lower than T3 alone in some studies. Data investigating the effects of T3 on osteoporosis, arthritis, and peptic ulcers in human are limited. The positive outcomes of T3 treatment obtained from the preclinical studies warrant further validation from clinical trials.
Staphylococcus saprophyticus Proteomic Analyses Elucidate Differences in the Protein Repertories among Clinical Strains Related to Virulence and Persistence
Authors: Silva Karla Christina Sousa , Silva Lana O’Hara Souza , Silva Guilherme Algusto Alves , Borges Clayton Luiz , Novaes Evandro , Paccez Juliano Domiraci , Fontes Wagner , Giambiagi-deMarval Marcia , Soares Célia Maria de Almeida , Parente-Rocha Juliana Alves
Published: January 2020

Staphylococcus saprophyticus is a Gram-positive and coagulase negative cocci that composes the skin microbiota and can act as an opportunistic agent causing urinary tract infections, being more frequent in sexually active young women. The ability of a pathogen to cause infection in the host is associated to its ability to adhere to host cells and to survive host immune defenses. In this work, we presented the comparative proteomic profile of three S. saprophyticus strains. It was possible to characterize differences in the proteome content, specially related to expression of virulence factors. We compiled this data and previous data and we detected one strain (9325) possessing higher production and secretion of proteins related to virulence. Our results show that phenotypic, genotypic, and proteomic differences reflect in the ability to survive during interaction with host cells, since the 9325 strain presented a higher survival rate after macrophage interaction. In counterpart, the 7108 strain that possesses lower content of proteins related to virulence presented higher ability to form biofilm suggesting that this strain can be better adapted to persist in the host and in the environment. Our work describes, for the first time, proteomic flexibility among S. saprophyticus strains, reflecting in virulence and persistence.
Electron Microscopy of In-Plaque Phage T3 Assembly: Proposed Analogs of Neurodegenerative Disease Triggers
Authors: Serwer Philip , Hunter Barbara , Wright Elena T.
Published: January 2020

Increased knowledge of virus assembly-generated particles is needed for understanding both virus assembly and host responses to virus infection. Here, we use a phage T3 model and perform electron microscopy (EM) of thin sections (EM-TS) of gel-supported T3 plaques formed at 30 °C. After uranyl acetate/lead staining, we observe intracellular black particles, some with a difficult-to-see capsid. Some black particles (called LBPs) are larger than phage particles. The LBP frequency is increased by including proflavine, a DNA packaging inhibitor, in the growth medium and increasing plaque-forming temperature to 37 °C. Acidic phosphotungstate-precipitate (A-PTA) staining causes LBP substitution by black rings (BRs) that have the size and shape expected of hyper-expanded capsid containers for LBP DNA. BRs are less frequent in liquid cultures, suggesting that hyper-expanded capsids evolved primarily for in-gel (e.g., in-biofilm) propagation. BR-specific A-PTA staining and other observations are explained by α-sheet intense structure of the major subunit of hyper-expanded capsids. We hypothesize that herpes virus triggering of neurodegenerative disease occurs via in-gel propagation-promoted (1) generation of α-sheet intense viral capsids and, in response, (2) host production of α-sheet intense, capsid-interactive, innate immunity amyloid protein that becomes toxic. We propose developing viruses that are therapeutic via detoxifying interaction with this innate immunity protein.
The Perception of Organisational Nepotism Depending on the Membership in Selected Christian Churches
Authors: Ignatowski Grzegorz , Sułkowski Łukasz , Stopczyński Bartłomiej
Published: January 2020

Nepotism, just like any other form of favouratism in the workplace, is a phenomenon that is basically evaluated negatively. It adversely influences social and economic development and it has not been considered in relation to the membership of a given Christian denomination. This article reviews the literature on nepotism and takes into account the religious perspective on nepotism while the research part focuses on the analysis of nepotism taking into consideration both Catholic and Protestant perspectives. Thus, the article falls within the discussion initiated by Max Weber, who found that religious membership had an influence on economic development because business leaders, capital owners, and a highly qualified workforce and well-trained enterprise employees were, by and large, Protestants. The article is aimed at analyzing the effects of nepotism and evaluating this phenomenon from the perspective of the abovementioned Christian denominations. Qualitative and quantitative methods were included in the conducted research. As far as the qualitative method is concerned, an individual in-depth interview, conducted with two Catholic and two Protestant clerics, was applied. Within the second stage, i.e., the quantitative surveys, information received in the interviews was verified and the way of understanding and accepting the phenomenon of nepotism depending on the religious membership was learnt. This research demonstrated that Protestants regard the phenomenon of nepotism as negative more frequently than Catholics and the phenomenon is more common among Catholics than Protestants.
Luther, Same-Sex Marriage, and the Evangelical-Lutheran Church of Finland: A Gender-Sensitive Historical Analysis
Authors: Mikkola Sini
Published: January 2020

The issue of whether to accept same-sex relationships as marriages has been under discussion worldwide in recent years, including in the Nordic countries, such as Finland. While in other Nordic countries, the Lutheran churches officiate same-sex marriages, the Evangelical Lutheran Church of Finland (ELCF) has rejected it on theological grounds that are largely based on Reformation Era sources. This article examines the constitution committee report that was used as the basis of the decision made by the General Synod of the ELCF in May 2018 to not accept same-sex marriages. Through close reading of the report and performing content analysis from a gender-sensitive historical perspective, the article claims that the validity of the arguments of the report can be called into question, due to the lack of a hermeneutical awareness of the differences between the sixteenth and the twenty-first centuries, and the highly selective use of the sources from the Reformation Era in the document. The article concludes by pointing out that making use of the Reformation heritage in theology, instead of replicating the arguments of the sixteenth century, would have produced a theologically and historically more solid report, which could well have been in favor of extending the view on marriage in the ELCF.
The Role of the Spiritual Meaning System in Coping with Cancer
Authors: Visser Anja , Uwland-Sikkema Nicoline , Westerhof Gerben J. , Garssen Bert
Published: January 2020

Spirituality can support the adjustment process of people with cancer, by forming a meaning system that supports understanding of the cause and implications of the experience and that provides coping strategies. The different ways in which spiritual meaning systems might fulfill these roles were examined among 20 people who were treated for cancer with curative intent. Narrative interviews were held on average 16 months after cancer diagnosis. The interviews were analyzed in a two-stage process, based on a holistic content approach. The first stage led to the identification of various roles and outcomes of the meaning system. The second stage involved a comparison of these roles and outcomes between previously defined types of meaning systems. The roles identified were discrepancy, legitimation and continuation. Legitimation was associated with the outcome of integration, whereas continuation was associated with an outcome of a positive outlook toward the future. Several differences were found between types of meaning systems, regarding the extent to which and ways in which these roles and outcomes occurred. This study underscores recommendations that healthcare professionals should be aware of the different ways in which the patient’s previous beliefs and experiences influence their current adaptation to serious life events.
Non-Affiliated Believers and Atheists in the Very Secular Uruguay
Authors: Da Costa Nestor
Published: January 2020

In recent years, literature in the field of religion has presented attempts to understand and characterize people who define themselves as believers but are not affiliated with any religious institution, along with those who define themselves as non-believers, or “nones”. Several quantitative studies covering this phenomenon in Latin America show clear disparities between the countries of the region. This article draws on a qualitative investigation into the way in which individuals relate to the transcendental, or live as non-believers, in the city of Montevideo, Uruguay. The objective of the article is to know and analyze those who define themselves as religiously unaffiliated. In doing so, the analysis takes into account the cultural framework of Uruguay—a country that moved the religion from the public to the private sphere a century ago, establishing a model similar to French secularism and unique within Latin America.