bluuebunny/crossref_metadata_2025 huggingface dataset:
A Voltage-Controlled Strategy for Modular Shono-Type Amination
Authors: Su Siyuan , Guo Yahui , Parnitzke Bryan , Derosa Joseph
Published: June 2024

Shono-type oxidation to generate functionalized heterocycles is a powerful method for late-stage diversification of relevant pharmacophores; how-ever, development beyond oxygen-based nucleophiles remains underdeveloped. The limited scope can often be ascribed to constant current electrolysis resulting in potential drifts that oxidize a desired nucleophilic partner. Herein, we report a voltage-controlled strategy to selectively oxidize a broad scope of substrates, enabling modular C–N bond formation from protected amine nucleophiles. We implement an electroanalytically-guided workflow using cyclic voltammetry (CV) and differential pulse voltammetry (DPV) to identify oxidation potentials across a range of heterocyclic substrates. Controlled potential electrolysis (CPE) selectively generates -functionalized C–N products in moderate to good yields using carbamate-, sulfonamide-, and benzamide-derived nucleophiles. The importance of voltage control is further exemplified in two cases: (1) change in selectivity at different potentials with a morpholine substrate and (2) analysis of reaction outcomes between Celecoxib and an N-Boc or N-Ns-pyrrolidine substrate; the latter requires a potential more anodic than Celecoxib and does not yield desired product. Lastly, sequential voltage-controlled C–N and C–O functionalization of a model substrate generates difunctionalized pyrrolidines further broadening the utility of this reaction.
Unified, Biosynthesis-Inspired, Completely Stereocontrolled Total Synthesis of All Highest-Order [n+1] Oligocyclotryptamine Alkaloids
Authors: Scott Tony , Movassaghi Mohammad
Published: June 2024

We describe the unified enantioselective total synthesis of the polycyclotryptamine natural products (+)-quadrigemine H, (+)-isopsychotridine C, (+)-oleoidine, and (+)-caledonine. Inspired by our hypothesis for the biogenesis of these alkaloids via an iterative concatenative addition of homochiral cyclotryptamines to a meso-chimonanthine headcap, we leverage the modular, diazene-directed assembly of stereodefined cyclotryptamines to introduce successive C3a−C7' quaternary stereocenters on a heterodimeric meso-chimonanthine surrogate with full stereochemical control at each quaternary linkage. We developed a new strategy for iterative aryl-alkyl diazene synthesis using increasingly complex oligomeric hydrazide nucleophiles and a bifunctional cyclotryptamine bearing a C3a leaving group and a pendant C7 pronucleophile. The utility of this strategy is demonstrated by the first total synthesis of heptamer (+)-caledonine and hexamer (+)-oleoidine. Enabled by our completely stereoselective total syntheses and expanded characterization data sets, we provide the first complete stereochemical assignment of pentamer (+)-isopsychotridine C, provide evidence that it is identical to the alkaloid known as (+)-isopsychotridine B, and report that tetramer (+)-quadrigemine H is identical to the alkaloid called (+)-quadrigemine I, resolving longstanding questions about the structures of the highest-order [n+1] oligocyclotryotamine alkaloids.
Chemoselective placement of unsaturated phosphorus electrophiles into ubiquitin for proximity-induced protein targeting
Authors: Stieger Christian , Schwagerus Sergej , Dornan Gillian , Armstrong Lee , Kemnitz-Hassanin Kristin , Nadler-Holly Michal , Stephanowitz Heike , Liu Fan , Haucke Volker , Kulathu Yogesh , Hackenberger Christian
Published: June 2024

Mildly reactive electrophiles have emerged as powerful functional groups for developing chemical probes to target pharmacologically important proteins and study key biological mechanisms. With the current manuscript, we introduce unsaturated N-alkyl-phosphonamidates as a new and powerful class of chemical warheads that enable proximity-induced labeling and the specific targeting of protein-protein interactions. In contrast to many other electrophilic warheads, these cysteine-selective electrophiles can be incorporated into specific amino acid side on the protein level by a chemoselective Staudinger-phosphonite reaction using unsaturated phosphonites as chemical reactants with azido-containing ubiquitins obtained by auxotrophic expression. Following this protocol, we prepared several ethynyl-N-alkyl-phosphonamidate-containing ubiquitins, which undergo proximity-induced labeling with deubiquitinases (DUBs) and other ubiquitin-interacting proteins, even in the presence of high thiol concentrations and cell lysates. Furthermore, we demonstrate that changing the position of the electrophile allows selective targeting, enrichment and distinct functional regulation of DUBs via covalent binding to individual distinct ubiquitin binding pockets as highlighted in the functional regulation of USP5, a DUB that contains multiple ubiquitin binding sites. Our study highlights the prospect of targeting proteinprotein interactions with electrophilic protein-based probes by simultaneously enlarging the repertoire of chemical probes beyond purely synthetically derived warheads.
Photosensitizer-Free Singlet Oxygen Generation via Charge Transfer Transition involving Molecular O2 toward Highly Efficient Oxidative Coupling of Arylamines to Azoaromatics
Authors: Singh Shivendra , Mukherjee Tushar Kanti
Published: June 2024

Photosensitizer (PS)‐mediated generation of singlet oxygen, O2 (a1Δg) is a well‐explored phenomenon in chemistry and biology. However, the requirement of appropriate PS with optimum excited state properties is a prerequisite of this approach which limits its widespread application. Herein, we report the generation of O2 (a1Δg) via direct charge-transfer (CT) excitation of solvent‐O2 (X3Σ_g^-) collision complex without any PS and utilize it for the catalyst-free oxidative coupling of arylamines to azoaromatics under ambient conditions in aqueous medium. The electron paramagnetic resonance (EPR) spectroscopy revealed the formation of O2 (a1Δg) upon direct excitation with 370 nm light. The present approach shows broad substrate scope, fast reaction kinetics (90 min), high selectivity (100%), excellent yields (up to 100%), and works well for both homo‐ and hetero‐coupling of arylamines. The oxidative coupling of arylamines was found to proceed through the generation of amine radicals via electron transfer (ET) from amines to O2 (a1Δg). Notably, electron‐rich amines show higher yields of azo products compared to electron‐deficient amines. Detailed mechanistic investigations using various spectroscopic tools revealed the formation of hydrazobenzene as an intermediate along with superoxide radicals which subsequently transform to hydrogen peroxide. The present study is unique in a way that molecular O2 simultaneously acts as a light absorbing chromophore (solvent‐O2 complex) as well as an efficient oxidant (O2 (a1Δg)) in the same reaction. This is the first report for the efficient, selective, and sustainable synthesis of azo compounds in aqueous medium under an ambient atmosphere without any PCs/PSs and paves the way for further in-depth understanding of the chemical reactivity of O2 (a1Δg) generated directly via CT excitation of solvent‐O2 complex toward various photochemical and photobiological transformations.
Importunação Sexual
Authors: Santos Júnior Cristóvão
Published: June 2024

Soneto de denúncia.
Há espaço para a redução de danos em políticas antidrogas?
Authors: Costa Pedro Henrique Antunes da
Published: June 2024

O artigo objetiva responder a pergunta-título: Há espaço para a Redução de Danos nas atuais Políticas Antidrogas brasileiras? Para isso, conjuga uma parte documental, analisando como a Redução de Danos (RD) comparece nas “novas” Política sobre Drogas (Decreto 9.761/2019) e Lei de Drogas (Lei 13.840/2019), e uma revisão sobre o histórico e desenvolvimento da RD no Brasil. Como um movimento social e uma racionalidade orientadora do cuidado na área, não serão as limitações impostas pelas políticas que suprimirão a importância da RD. Com as recentes mudanças, ela se torna ainda mais necessária - mesmo que mais obstaculizada. Concebê-la como sinônimo de Estado e políticas ou dependente deles, é descaracterizá-la, juntamente de sua origem, história, potencial e sentido na realidade brasileira.
Direito ao Território Quilombola na Amazônia e a Pandemia
Authors: DE CARVALHO LUCIANA , Dias Vercilene , Cardoso Nascimento Raimundo Magno , Martins Pedro
Published: June 2024

O presente artigo apresenta análise a partir da Antropologia do Direito sobre a relação entre o Direito ao território e a experiência da Malungu para defesa dos quilombos do Pará durante a pandemia a partir de situações e casos específicos. A pergunta de pesquisa utilizada foi “Quais noções de direito ao território foram evidenciadas na atuação política da Malungu na defesa dos quilombos durante a pandemia?”. As autoras estiveram diretamente envolvidas em processos de resistência da Malungu.  A pesquisa se baseou em levantamento de dados sobre covid19 nos quilombos, relatos de experiências levados ao público e atuações concretas em face ao Estado. As referências bibliográficas são basicamente da Antropologia e do Direito.
Plano Diretor e as ZEIS: cidade em disputa e os impactos da COVID-19 nos territórios periféricos do Recife
Authors: Neves Samir Cruz Julia Clariane , Albuquerque Clara , Soares Paula , Santos Vitória , Cordeiro Yasmin
Published: June 2024

Este artigo objetiva apresentar uma análise acerca do Plano Diretor da cidade do Recife, capital de Pernambuco, sua revisão e os impactos trazidos por ele nas ZEIS, assim como os efeitos que a pandemia do Coronavírus carrega nesse contexto. Para tanto, foi desenvolvida uma pesquisa quali-quantitativa a partir de fontes documentais de artigos científicos, obras, dados de pesquisas e estatísticas, além da legislação sobre os impactos do COVID-19 nesses espaços, assim como a mercantilização dessas áreas, mais especificamente na cidade do Recife. Discute-se, portanto, a dimensão socioespacial da cidade, a ausência de políticas públicas, a precarização de moradia, as condições de habitabilidade e como isso fez e faz com que as comunidades sejam mais atingidas, principalmente no contexto de pandemia, partindo do princípio que são todos direitos assegurados pela Constituição Cidadã de 1988. Além disso, buscará traçar uma reflexão, partindo do contexto histórico, sobre como esses espaços têm sido cada vez mais mercantilizados, como os efeitos da pandemia são mais presentes nesses locais e a maneira que isso impacta no processo de construção da cidade através do Plano Diretor.
Ninguém solta a mão de ninguém
Authors: Alfonsin Betania de Moraes , Pereira Pedro Prazeres Fraga , Segat Flávia , Berni Paulo Eduardo , Lopes Debora Carina , Oliveira Pedro Acosta , Montanari Vitória Alvarez , Guimarães Fernanda Madalosso
Published: June 2024

O artigo analisa a construção de processos de resistência comunitária ao desmonte da política urbana e à  COVID-19 em territórios de baixa renda no município de Porto Alegre. Em um ambiente que promove a necropolítica e acentua a precarização da vida das populações de periferia, busca-se verificar a que recursos recorrem, que alianças constroem, que bandeiras de lutas defendem, que inovações organizativas experimentam e que resultados alcançam tais comunidades de Porto Alegre em seus processos de resistência aos ataques ao direito à  cidade, bem como no enfrentamento da pandemia. Utilizando-se da técnica de produção de dados por meio da realização de entrevistas semiestruturadas, bem como da realização de etnografias, o grupo de pesquisa se esforça por imprimir uma perspectiva analítica descolonial à  investigação. Como achados provisórios da pesquisa, constata-se uma notável renovação dos repertórios organizativos das comunidades de baixa renda no período.
On Covering of Cylindrical and Conical Surfaces with Equal Balls
Authors:   Matrosov Institute for System Dynamics and Control Theory SB RAS, Lempert A. A. , Kazakov A. L. ,   Matrosov Institute for System Dynamics and Control Theory SB RAS,   Irkutsk National Research Technical University, Nguyen D. M. ,   Irkutsk National Research Technical University
Published: June 2024

The article concerns the problem of covering the lateral surface of a right circular cylinder or a cone with equal balls. The surface is required to belong to their union, and the balls’ radius is minimal. The centers of the balls must lie on the covered surface. The problem is relevant for mathematics and for applications since it arises in security and communications. We develop heuristic algorithms for covering construction based on a geodesic Voronoi diagram. The construction of a covering is a non-trivial task since the line of intersection of a cylinder or a cone with a sphere is a closed curve of the fourth order. To compare the numerical results with the known ones, we unroll the surface of revolution onto a plane. Another feature is that, we use both Euclidean distance and a special non-Euclidean metric, which can describe the speed of signal propagation in a heterogeneous medium. We also perform a numerical experiment and discuss its results. Meanwhile, it is shown that with a small number of circles covering a planification of the cylindrical surface, their radius is significantly less than for a similar rectangle.
A Comparative Analysis on Virus Mutation with Fibonacci Numbers
Authors: Rexma Sherine V  , Gerly TG  , Britto Antony Xavier G  , Abisha M
Published: June 2024

In our research, we have derived the fibonacci numbers from the virus mutation. For example, if a virus is first mutated, the fibonacci numbers are capable of identifying the splitting ratio between the parent and first mutant virus. Likewise, the second mutant can be predicted using the Tribonacci numbers, and so on. Here, we compare the fibonacci numbers with the virus spread of each mutant virus to get the transmission ratio for each mutation. This will help prevent the spread of the virus before it reaches a critical level.
A Study on A Solution Approach to Fuzzy Linear Frctional Programming Problems
Authors: SN Mohamed Assarudeen , M Devi
Published: June 2024

In this paper, we propose a method of solving the fully fuzzy linear fractional programming problems, Express all the parameters and variables are triangular fuzzy numbers. Convert all the triangular fuzzy numbers in their parametric form, we convert the fractional programming problem in to a single objective linear programming problem in parametric form. We put new fuzzy arithmetic and fuzzy ranking, we obtain the optimal solution the given fully fuzzy linear fractional programming problem without converting to its equivalent crisp linear programming problem. A numerical example is provided to illustrate the efficiency of the proposed method.
A Study on Different Types of Edge Sequence in Pseudo Regular Fuzzy Graphs
Authors: Sudhakar VJ  , Agila S  , Narayini R
Published: June 2024

The concept of connectivity plays an important role in both theory and applications of fuzzy graphs. Depending on the strength of an edge, this paper classifies edge sequence of a fuzzy graph in to different types. We analyze the relation between different types of edge sequence in both pseudo regular and totally pseudo regular fuzzy graphs. Also we identify strong edge sequence in pseudo regular fuzzy graph.
The Study of Plithogenic Intuitionistic fuzzy sets and its implementation in Insurance Sector
Authors: Priyadharshini SP  , Nirmala Irudayam F
Published: June 2024

The core objective of the course is to gain knowledge of the basic concepts of Plithogenic intuitionistic fuzzy sets(PIFS) for single valued which deals with the components characterized by the features with many trait values. The accumulation operatives such as intersection, union, complement, inclusion of PIFS were introduced. Moreover, an application of PIFS in the field of Insurance is provided to validate the benefit of the optimization technique.
Lucky Labeling for Extended Triplicate Graph of Star
Authors: Bala S  , Saraswathy S  , Thirusangu K
Published: June 2024

In this paper, we investigate the existence of lucky labeling in the context of extended triplicate graph of star.
Mental health support app with mood tracking and resources
Authors: Pempho Jimu , Melvin Mwakiseghire
Published: June 2024

In our increasingly digitized society, prioritizing mental health support has become imperative for overall well-being. This abstract outlines the development and core features of an innovative mental health support app aimed at empowering individuals to navigate their mental health journey effectively. This cutting-edge mobile application integrates mood tracking with a plethora of mental health resources, providing users with comprehensive support tailored to their needs. Amidst a landscape where mental well-being is paramount, this app serves as a digital ally, aiding users in understanding, monitoring, and enhancing their emotional health. Leveraging artificial intelligence, the app discerns patterns in users' mood data, offering personalized suggestions and interventions. These recommendations encompass mindfulness exercises, journal prompts, and connections to friends and support networks. Beyond personalized support, the app boasts an extensive library of mental health resources, including articles, videos, and audio content spanning stress management to mindfulness techniques. Moreover, it facilitates access to local mental health professionals and support groups, ensuring users can seek assistance as needed. This app represents a pivotal step towards democratizing mental health support and empowering individuals to foster their well-being proactively.
Rural well water management and monitoring system
Authors: Ephraim Bwanausi , Pempho Jimu
Published: June 2024

This paper aims to transform rural communities' use of water resources. Modern sensor technologies are integrated into an all-inclusive system to enable real-time monitoring and prompt identification of anomalies and contamination. Well water information is more accurate and reliable when entered automatically, providing solid groundwork for informed decision-making. The technology combines user-friendly interfaces with a proactive maintenance schedule to enable communities to maintain the longevity of their wells and the quality of their water. This work not only tackles the difficulties associated with managing well water in rural areas but also improves the general well-being and environmental preservation of these communities by endorsing sustainable water management techniques.
Contesting Silences: Traces of the Holocaust and Vergangenheitsbewältigung in West German Cinema, 1949-1969
Authors:   , Ryan Tarryn
Published: June 2024

Heimatfilm played an important role in reconstructing a new identity for citizens of the Federal Republic of Germany, however, representations of the Jewish experience were non-existent. This research interrogates the alleged silences around the Holocaust in West German cinema through the fifties and sixties, by analysing films that have been previously overlooked or disregarded as ‘Holocaust films,’ and in doing so, challenge preconceived ideas about what Vergangenheitsbewältigung means.
Internal Control Management and Risk Prevention Measures of State-Owned Enterprises
Authors: Liu Bing
Published: June 2024

As an important pillar of national economic development, state-owned enterprises, their operational efficiency, and risk management ability are directly related to the stability and security of the national economy. As an important part of enterprise management, internal control management plays an irreplaceable role. Especially in the current domestic and international economic situation is complex and changeable, market competition is increasingly fierce environment, to strengthen the internal control management of state-owned enterprises and risk prevention measures is particularly important. This paper starts with the importance of internal control management and risk prevention for state-owned enterprises, and analyzes the problems and strategies in the internal control management and risk prevention of state-owned enterprises, in order to build a more comprehensive and efficient risk management system for state-owned enterprises to adapt to the ever-changing market environment and realize sustainable development.
Edukasi tentang HIV/AIDS pada Siswa SMA Negeri 1 Ternate
Authors: Armaijn Liasari , Darmayanti Dewi
Published: June 2024

Human Immunodeficiency Virus (HIV) was a virus who infected white blood cells caused human immune system deficiency. Acquired Immune Deficiency Syndrome (AIDS) was a disease with syndrome caused by Immunodeficiency Virus (HIV). Even fluctuative but Indonesian data of HIV/AIDS keep increase every year. In the past eleven years, cases of HIV in Indonesia been in the highest cases at 2019 with 50.282 cases. In North Maluku, new cases of HIV/AIDS on September become 140 cases and cumulative data was 1.325 cases. In Ternate, there were 641 cases of HIV/AIDS which 135 people died. Data shows that HIV/AIDS cases increase on household and productive ages. If the incubation of HIV/AIDS was 8-10 years than infection must be on school ages. Therefore, education on school period become a determinant factor to prevent HIV/AIDS.
Pelatihan Penyusunan Asesmen Diagnostik dalam Kurikulum Merdeka bagi Guru di MTs dan MA Sekolah Cinta Ilmu
Authors: Mukhibin Ahmad , Rusyid Husnul Khatimah , Lutfi Ahmad , Mardliyah Syifa , Dahlan Jarnawi Afgani , Jupri Al
Published: June 2024

Merdeka curriculum was developed by the Government in order to improve the quality of education in Indonesia. Merdeka Curriculum, introduced by the Ministry of Education, Culture, Research and Technology (Kemendikbud Ristek), is a new curriculum that allows schools to adapt learning to the needs and characteristics of students. However, in its implementation, teachers experience several obstacles in implementing the independent curriculum, one of which is in designing assessments and evaluations. Teachers have difficulty in managing classroom conditions due to the lack of clarity in diagnostic assessments. This research aims to provide training in preparing diagnostic assessments to determine students' initial abilities before learning. The method used in this community service is Participatory Action Research (PAR). The subjects in this study were MTs and MA teachers at Cinta Ilmu School, totaling 18 people. Based on the data obtained during the training, the teachers felt enthusiastic and satisfied with the presentation of material that was in accordance with the needs and professional presenters so that the material provided could be easily understood by the participants. It is indicated by the average score index of overall participant satisfaction reaching 3.54, which is in the very satisfying category. While the satisfaction index in the reliability aspect reached a score of 3.7, the tangible evidence aspect reached 3.5, the responsiveness aspect reached 3.4, the guarantee aspect reached 3.5, and the service aspect reached 3.6.
Effects of Tabata Training on Fitness and Health of Sports Coaching Education Students
Authors: Azizah Nisa Hamidah Nur , Pramono Bayu Agung , Muhammad Muhammad , Fajar Muhammad Kharis , Azriddin Adlina Dayana Binti
Published: June 2024

Sports physical training is a physical activity that has a good effect on health, fitness and performance. Currently, many physical exercises have been developed, especially physical exercises using high intensity. The purpose of this study was to see the effects of high-intensity training on fitness and health in Sports Coaching Education students. In this study, the experimental pre-test post-test method was used involving seven untraining men and nine training men who are students majoring Sports Coaching Education (SCE). This study was conducted in four weeks, with frequency three times a week. The test used is the Shapiro-Wilk for normality check and Wilcoxon test to see the difference in pre-test and post-test after the sample gets high-intensity training treatment for four weeks. The results of this study showed differences in post HR Max, post bodyweight, post BMI, post sum recovery, and post HR rest (p<0.05). On the results of N-gain, tabata training was quite effective given to the group of training students than the untraining group. The conclusion in this study shows that the application of high-intensity training requires an adaptation process in the unfit student group to have a positive effect on the health and fitness of SCE students.
Communicating vessels: the influence of Luis Buñuel’s early films on the belgian avant-garde cinema
Authors: Rubín de Celis Pastor Santiago
Published: June 2024

La perla y Monsieur Fantômas, obras tempranas del cine de ficción en Bélgica, son dos ejemplos poco estudiados dentro del cine de vanguardia del primer tercio del siglo XX. Obras singulares, en primer lugar, dado que fueron los únicos filmes realizados por sus autores, Henri d’Ursel y Ernst Moerman, respectivamente, pero también por su adhesión a los principios discursivos y a la estética del cine surrealista desarrollado en las décadas de los 20 y 30 del pasado siglo. El presente artículo las contextualiza dentro del cine de vanguardia y del cine nacional belga, ahonda en su relación con la cultura de dicho país y, por último, también examina la huella en ellas de la obra de notables representantes del movimiento artístico como René Magritte o Luis Buñuel.
El deseo, la frustración y el crimen: un diálogo entre Luis Buñuel y Carlos Saura
Authors: Duprat de Montero Arnaud
Published: June 2024

Luis Buñuel y Carlos Saura se conocieron personalmente durante el festival de Cannes de 1960. A partir de Belle de Jour y Peppermint Frappé en 1967, las dos filmografías se desarrollaron paralelamente, poniendo de manifiesto una correspondencia espiritual e incluso un diálogo en la medida en que cada filmografía parecía influir en la otra. Se puede analizar este fenómeno gracias al eje temático del deseo –amoroso y/o sexual– frustrado que provoca la violencia y lleva al crimen. Esta temática típicamente buñueliana se convirtió con el tiempo en sauriana, y permitió a este joven cineasta revelar su propia poética. El desarrollo de esta temática sitúa la relación artística Buñuel-Saura entre el modelo del maestro con su discípulo y el de un intercambio igualitario entre dos autores, mientras que cada cineasta está involucrado en una colaboración que tiene una importancia autoral indudable en sus obras: el coguionista Jean-Claude Carrière en el caso de Buñuel, la actriz Geraldine Chaplin en el caso de Saura.
Obra literaria reunida. Le chien andalou et autres textes poétiques
Authors: Girona Ramon
Published: June 2024

Reseña de: Buñuel, L., Obra literaria reunida, Madrid, Cátedra, col. “Letras Hispánicas”, ed. de Jordi Xifra, 2022, 552 pp. Y: Buñuel, L., Le chien andalou et autres textes poétiques, París, Gallimard, col. “Poésies”, ed. de Jordi Xifra, 2023, 416 pp.
Trend of Using ChatGPT in Learning Process and Character Education: A Systematic Literature Review
Authors: Mahsun Mahsun , Ali Mudzakkir , Ekaningrum Ifada Retno , Ibda Hamidulloh
Published: June 2024

Generative pre-trained transformers (ChatGPTs) have become an increasingly interesting topic in education, particularly in student character development. However, the use of ChatGPT in learning and character education faces significant challenges. This systematic literature review article utilized the PRISMA protocol by using current literature from PubMed, IEEE, Xplore, and Scopus from 2017-2023 that presents an analysis of the challenges, opportunities, and solutions related to the use of ChatGPT in the context of character education. The results showed that the challenges include limited context, reliance on baseline data, and lack of direct supervision. However, there were also significant opportunities, such as creativity in designing learning scenarios, scalability in learning from large amounts of data, and the potential use of ChatGPT as a personal assistant for students. Several solutions were proposed to address these challenges, including developing specialized models, implementing filters or supervision mechanisms, and user education. Understanding these challenges, opportunities, and solutions has been essential to harness the full potential of ChatGPT in improving learning and character education.
ROMANTICISM AND CONSTRUCTIVISM IN THE POLISH THEATRE OF 1920-1930S
Authors:   Russian State Institute of Performing Arts, Popova Alexandra V.
Published: June 2024

In the 1920-1930s, Polish theatre was experiencing a turn to new comprehension of the practice of stage space organization – the art of scenography was developing. It replaced the practice of creating theatrical decorations for garnishing the play and constituting the background for the action. The new scenography declared itself to be an art of the stage space composing. The development of new theatrical practice was influenced by constructivist spatial and rhythmical perception of environment, which Polish artists were improving in close cooperation with avant-garde architects. A similar approach to the stage design is common for the whole European theatre in the first decades of XX century, however the distinction of theatrical avant-garde in Poland came out as a special reference of the culture to its past and in particular to the romanticism heritage. Polish theatrical avant-garde, which came at restoration of independence time, was developing on overlap of the national myth and new unexplored freedom. Artists of the first half of XX century managed to disengage from the romantic myth only in some measure, but instead of resetting the national heroes and their heritage from the ship of modernity they turned to search for the new forms to embody that matter. The article reviews Polish theatre of the 1920-1930-s in the context of Polish romantic tradition on the one hand and constructivism, promoted by new avant-garde artist collectives – on the other. As an example of integration of two movements, a brief description of the unique project of Simultaneous theatre, created by stage designer Andrzej Pronaszko and architect Szymon Syrkus is given.
THE REPRESENTATION OF POSTHUMAN SUBJECTIVITY IN MODERN SCIENCE-FICTION ON THE EXAMPLE OF THE TV SERIES “LOVE. DEATH & ROBOTS”
Authors:   Russian State University for the Humanities, Kruvko Tatiana V.
Published: June 2024

Today, the conversation about the impact of technology on humans is a common place. In humanitarian theory, there is a growing number of approaches that develop new ways to describe a person in a technologized culture. Special attention is paid to it by posthumanism, based on the experience of critical analysis of culture, it offers a description of alternative, posthuman subjectivity. Where is also a reflection on changing human relations with the environment in visual art. Although mass screen culture has transformed and moved away from big screens to gadgets for private viewing, it has not lost its ability to respond sensitively to cultural trends and offers examples of images of posthuman subjectivity. The theory of posthumanism turns out to be a relevant tool for analyzing posthuman images in modern science fiction films. The article will examine representations of posthuman subjectivity in the genre of modern fiction on the example of the TV series “Love. Death. Robots.” The focus of the analysis will be on the images of the main characters and the peculiarities of plot development in relation to traditional cultural constructs.
RSE: De la Teoría integrativa a los stakeholders
Authors: Valencia Sandoval Karina
Published: June 2024

Las empresas han comenzado a reconocerse como entes sociales capaces de influir pero también de ser influidas por el entorno en el que se desenvuelven; esta toma de conciencia da paso a la introducción de la Responsabilidad Social Empresarial en las actividades de las organizaciones; con ello, la teoría integrativa que indica que la empresa debe considerer las necesidades de sus grupos de interés o stakeholders para seguir desarrollándose en mercados con nuevas visiones e inquietudes. Por lo anterior, la teoría integrativa y con ella, los grupos de interés han llamado la atención de investigadores y empresarios cambiando la vision tradicional de las unidades económicas incorporándo el quehacer social como parte de su día a día
Impacto del nitrógeno líquido en la textura y calidad del helado de aguacate
Authors: Vázquez Hernández Alexia , Ávila Cid Alejandra , Vega Serrano Flor Viridiana
Published: June 2024

La cocina molecular y su popularización en el ámbito gastronómico han permitido la aplicación de técnicas de vanguardia a los alimentos para mejorar los resultados en los platos. Un ejemplo de ello es el uso de nitrógeno en la preparación culinaria, el cual permite realzar características que no se lograrían con elaboraciones tradicionales, especialmente en lo que respecta a la congelación de alimentos.
Ibuprofeno y tramadol: una opción para contrarrestar el dolor pulpar
Authors: López González Wendy P. , Fernández Barrera Miguel Á. , Bazán Suárez Ana K. , Balderas Delgadillo Carmen , Monjarás Ávila Ana J.
Published: June 2024

El dolor es uno de los síntomas que se trata con más frecuencia al margen de los profesionales de la salud. A menudo el paciente recurre a la automedicación con antiinflamatorios, analgésicos y antibióticos, lo que puede perpetuar y agravar problemas que hubieran podido tener un fácil tratamiento. Incluso puede lograr una dependencia de la medicación. Si el dolor en la odontología se maneja mal y no se investigan y tratan sus causas de forma adecuada, es posible que el cuadro clínico evolucione a estadios de mayor gravedad. Hoy en día no se puede hablar de un manejo estandarizado, cada caso es independiente y debe ser tratado de manera particular para todo tipo de pacientes, además, la investigación en la búsqueda del mejor tratamiento farmacológico es continua y se actualiza día a día.
Educación para la salud: concepto y sus relaciones con la pedagogía crítica, la promoción, la alfabetización y la atención primaria en salud
Authors: Nassar Tobón Andrea C.
Published: June 2024

Este artículo aborda la Educación para la Salud desde una perspectiva histórica y conceptual. Se explora su evolución a través de diferentes enfoques, luego, se analiza desde el modelo de la pedagogía crítica, resaltando la construcción activa del conocimiento para transformar realidades. Además, se estudian sus conexiones existentes con la promoción en salud, la alfabetización en salud y la atención primaria en salud. Se concluye que la Educación para la Salud es un campo interdisciplinario que, desde la pedagogía crítica, puede empoderar individuos y comunidades, fundando estrategias enfocadas en modificar entornos y conductas, desarrollar competencias para usar la información disponible sobre la salud, así, como la construcción de un trabajo mancomunado entre la educación y la salud que logre dar respuesta a los desafíos actuales.
La ensoñación excesiva como una respuesta al estrés en adolescentes
Authors: Reyes Chávez José E.
Published: June 2024

La adolescencia es una etapa de cambios en el sujeto, los cuales son tanto físicos como psicológicos. También, en esta etapa se suele experimentar un nivel de estrés elevado por los distintos retos que esta ofrece, y por lo tanto, los jóvenes pueden desarrollar ansiedad, depresión u otros trastornos. Por otro lado, la ensoñación excesiva es un trastorno relativamente nuevo, el cual, consiste en la creación de mundos de fantasía, que afecta al funcionamiento en áreas significativas para el sujeto. El objetivo de esta investigación es exponer la relación entre la adolescencia, el estrés y la ensoñación excesiva. En conclusión, los adolescentes que experimentan un alto nivel de estrés, pueden desarrollar diversas afecciones, entre las que se puede encontrar la ensoñación excesiva. Aun así, hay cierta dificultad a la hora de poder intervenir en cuando ya está presente este trastorno, ya que a veces no se le pone la suficiente atención y puede ser confundida como un síntoma de otro trastorno. De esta manera, es importante que los adolescentes busquen estrategias para afrontar el estrés, como puede ser la meditación o acudir a terapia psicológica.
Selladores de fosetas y fisuras en pacientes con HIM
Authors: Bautista Almaraz Angélica , Monroy Islas Arislandy , Gómez Juárez Blanca A. , Vertiz Marin Lesly X. , Monjaras Ávila Ana J.
Published: June 2024

El uso de selladores de fosetas y fisuras como opción de tratamiento en órganos dentales con hipomineralización resulta de gran utilidad para impedir el desarrollo de lesiones cariosas, especialmente en casos de molares completamente erupcionados con defectos leves, no sensibles y sin ruptura, pero para asegurar la supervivencia y éxito de dicho material, es necesario que sean supervisados regularmente y reemplazados cuando se pierdan. Teniendo en cuenta esto, se ha realizado una investigación con la finalidad de compartir las diferentes utilidades de los selladores de fosetas y fisuras, así como su clasificación, permitiendo la elección del mejor material restaurador preventivo en aquellos pacientes infantiles que presenten hipomineralización incisivo-molar. Pues el manejo temprano de manera adecuada, nos permitirá una conservación mayor de estos dientes en la arcada.
La ceguera del ser: individualidad y la verdad en Saramago
Authors: Balderas Islas Rodrigo
Published: June 2024

En su destacada obra literaria Ensayo sobre la ceguera, José Saramago, reconocido autor portugués, ofrece una profunda reflexión sobre la naturaleza humana frente a la adversidad política y la incertidumbre. Utilizando la metáfora de la ceguera blanca, Saramago invita a examinar la fragilidad de la existencia y a cuestionar en torno a aquellas convicciones arraigadas. Su mensaje, trasciende las barreras del tiempo y es revelado como una poderosa exploración existencialista sobre la libertad individual y la responsabilidad frente a los desafíos de la vida. A través de su narrativa perspicaz y penetrante, el autor insta a enfrentar las dificultades con claridad mental y fortaleza emocional, proporcionando una valiosa guía para el bienestar interior en medio de la turbulencia exterior.
De Centro minero a ciudad, el proceso de urbanización de la villa de Pachuca 1700-1821
Authors: Gómez Lucio Josué Alonso
Published: June 2024

La investigación que se plantea en las líneas subsecuentes, propone estudiar el proceso de urbanización demográfica existente en la estructura poblacional de la villa de Pachuca, a partir de los registros de bautizo parroquiales de la iglesia de Nuestra Señora de La Asunción; los cuales permiten observar periodos diferenciados de crecimiento poblacional, a partir de los repuntes en la estructura demográfica patentes en la primera y segunda mitad del siglo XVIII respectivamente. En dicha tónica, la hipótesis central de este trabajo sostiene que, la villa de Pachuca observó de forma diferencial un proceso de auge demográfico basado en la actividad minera durante la primera mitad del siglo XVIII (1725-1735), y de urbanización demográfica a finales del mismo siglo y principios del siglo XIX (1768-1807). Esto, con fundamento en el análisis de tres variables tomadas de la teoría de Jan De Vries (urbanización demográfica, crecimiento económico y urbanización estructural), a fin de estudiar dicho proceso, verificado a finales del periodo de estudio, el cual da cuenta del alcance e impacto de la implementación de las reformas borbónicas, las cuales establecieron un nuevo orden, el cual impactó al binomio población - estructura urbana, objeto de este estudio.
Transhumanismo y educación: reflexiones sobre la intervención biotecnológica en la práctica educativa
Authors: Garzón Tejada Juan Fernando
Published: June 2024

Se presenta, en primer lugar, una aproximación al posthumanismo y transhumanismo, considerando lo humano como elemento de referencia de lo (post – trans) humano, trazando una concepción en clave del humanismo y la ilustración. En segundo momento, se aborda el transhumanismo bosquejando sus modos de ejecución (químico, genético, integración biología -máquina), las posturas subyacentes (científica y cultural) y las críticas que se le plantean (política, filosófica y práctica). Finalmente, se desarrolla una reflexión de las comprensiones biotecnológicas del transhumanismo en la educación, teniendo como objeto de análisis la práctica educativa.
Representación sustantiva de las mujeres en el congreso de Guanajuato: tres legislaturas en contexto de paridad
Authors: Chávez Arteaga Leyla
Published: June 2024

Los resultados que se presentan en este trabajo de investigación, provienen de estudiar la representación sustantiva de las mujeres en el congreso de Guanajuato. Esto durante dos legislaturas posteriores a la reforma político-electoral de paridad de 2014. Se realiza un análisis de las iniciativas aprobadas mediante dictamen por tipo de promoventes (diputadas, diputados o grupo parlamentario), para con ello, identificar los asuntos a favor de las mujeres y lo que se prioriza en las agendas legislativas. Se encontró que los intereses de las mujeres no son prioridad en el Congreso de Guanajuato. Además de que ninguna de las iniciativas aprobadas tuvo como propósito trastocar el régimen de género, sobre el que se construyen las instituciones, incluido el propio Congreso. Finalmente, se concluye que, además de las diputadas, los grupos parlamentarios también representan los intereses de las mujeres.
Recent Books and Journal Articles in Public Opinion, Survey Methods, Survey Statistics, Big Data, Data Science, and User Experience Research. 2023 Update
Authors: Callegaro Mario
Published: June 2024

Welcome to the 16th edition of this column on recent books and journal articles in the field of public opinion, survey methods, survey statistics, Big Data, data science, and user experience research. Special issues of journals have a space in this article because, in our view, they are like edited books. We also added review papers from the journal series of Annual Reviews because these papers are seminal state of the art write ups, a mini book, if you wish on a specific subject. This article is an update of the books and journals published in the 2022 article. Like the previous year, the books are organized by topic; this should help the readers to focus on their interests. You will note that we use very broad definitions of public opinion, survey methods, survey statistics, Big Data, data science, and user experience research. This is because there are many books published in different outlets that can be very useful to the readers of Survey Practice, even if they do not come from traditional sources of survey content. It is unlikely we have exhaustively listed all new books in each subcategory; we did our best scouting different resources and websites, but we take full responsibility for any omissions. The list is also focused only on books published in the English language and available for purchase (as an ebook or in print) at the time of this review (April 2024) and with the printed copyright year of 2023. Books are listed based on the relevance to the topic, and no judgment is made in terms of quality of the content. We let the readers do so. If you want to send information for the next issue, please send it to surveypractice.new.books@gmail.com.
CULTURE AS COMMODITY: VISUAL RHETORIC OF TEA ADVERTISEMENT IN COLONIAL INDIA
Authors: Chakraborty Nabanita
Published: June 2024

This paper examines the popular rhetoric in printed tea advertisements in late nineteenth and early twentieth-century colonial India. The ethos of politeness, refinement and urban sociability of England was mapped onto the Indian culture through advertising campaigns. In the early nineteenth century, tea brands like Brook Bond and Lipton featured images of white European women drinking tea promoting it as a luxury item. However, a decisive shift is noticed in the visual iconography of the early twentieth-century advertisements where urban elite Indian women replaced white women. The visual imagery of the Indian ‘subaltern’ women plucking tea leaves with their nimble fingers in the tea plantation constructed a narrative of feminine care and oriental delicacy crafted for male fantasy. Thus the promotional campaigns for Indian-grown British-branded tea have to be studied within a complex discursive narrative where the woman simultaneously positioned as both the consumer and the producer of the exotic drink remains a signifier within the economy of male desire.
Prediksi Performa Akademik Mahasiswa untuk Kelulusan Predikat Cum Laude dengan Pendekatan Machine Learning
Authors: Indra Kusuma Budiyanto Firgiawan , Hermadi Irman , Hardhienata Medria Kusuma Dewi
Published: June 2024

Penelitian ini bertujuan untuk mengembangkan model yang dapat memprediksi jumlah mahasiswa yang lulus dengan predikat cum laude pada perguruan tinggi. Penelitian ini menggunakan algoritma machine learning untuk klasifikasi sehingga dapat dilakukan prediksi. Hasil dari penelitian ini menunjukkan efektivitas model dalam memprediksi kelulusan cum laude agar dapat memberikan kesempatan bagi universitas untuk meningkatkan kualitas lulusan secara keseluruhan dan mengatasi penurunan standar kelulusan yang mungkin terjadi. Prediksi jumlah mahasiswa cum laude dilakukan pada penelitian ini, untuk membantu proses pengambilan keputusan oleh pemangku kebijakan pada perguruan tinggi. Dengan memanfaatkan teknik machine learning, institusi dapat mengantisipasi dan mendukung mahasiswa dalam mencapai predikat cum laude, sehingga diharapkan dapat meningkatkan kualitas lulusan secara keseluruhan. Dalam penelitian ini, dibandingkan tiga algoritma machine learning yakni algoritma Naïve Bayes, Random Forest, dan C4.5 untuk melakukan prediksi kelulusan mahasiswa dengan predikat cum laude. Hasil penelitian menunjukkan bahwa dalam kasus ini kinerja terbaik dicapai oleh algoritma Naïve Bayes dengan nilai akurasi 87.60%, precision 86.70%, recall 92.10% dan F1-score 89.30%. Selain itu, algoritma Naïve Bayes juga menghasilkan nilai waktu komputasi terendah pada kasus yang diujikan dibandingkan dengan algoritma lainnya.
Perancangan Arsitektur Sistem Informasi Pelayanan Pengujian Benih pada (Balai Besar PPMBTPH) Menggunakan TOGAF ADM
Authors: Mulus Rachmat Tauffan , Yani Nurhadryani  , Hari Agung Adrianto
Published: June 2024

Pengujian mutu benih berperan besar dalam menyajikan hasil uji yang tepat dan akurat, sesuai dengan peraturan. Balai Besar Pengembangan Pengujian Mutu Benih Tanaman Pangan dan Hortikultura (BBPPMBTPH) memiliki peran dalam pelaksanaan pelayanan dan sebagai laboratorium acuan nasional dalam pengujian mutu benih. Penelitian ini bertujuan untuk merancang arsitektur sistem manajemen informasi pelayanan pengujian benih dengan menggunakan kerangka kerja TOGAF ADM. Tahapan penelitian dimulai dengan preliminary, arsitektur visi dan arsitektur bisnis menganalisis identifikasi tujuan, kebutuhan pengguna, pemetaan proses bisnis, dan identifikasi risiko. Kemudian, dilakukan perancangan arsitektur sistem informasi yang mencakup arsitektur data dan arsitektur aplikasi. Hasil penelitian menunjukkan bahwa TOGAF ADM dapat digunakan dalam perancangan arsitektur sistem informasi pengujian laboratorium BBPPMBTPH. Berdasarkan gap analysis, peningkatan kualitas pelayanan berkaitan dengan aspek efisiensi, efektivitas, akurasi, transparansi, dan akuntabilitas. Aspek-aspek tersebut menjadi proses bisnis yang diinginkan dalam bentuk sistem informasi manajemen. Arsitektur sistem informasi menghasilkan 5 kandidat modul aplikasi yaitu manajemen permohonan, manajemen pengujian, manajemen data, manajemen pelaporan, dan manajemen laporan, modul aplikasi tersebut saling terintegrasi membentuk sistem informasi manajemen pengujian laboratorium.