bluuebunny/crossref_metadata_2025 huggingface dataset:
Management of Stable Vitiligo—A Review of the Surgical Approach
Authors: Grochocka Małgorzata , Wełniak Adam , Białczyk Aleksandra , Marek-Jozefowicz Luiza , Tadrowski Tadeusz , Czajkowski Rafał
Published: March 2023

At present, vitiligo is the most common depigmenting skin disorder, characterized by clearly demarcated discolored patches of various shapes and sizes. Depigmentation results from the initial dysfunction and subsequent destruction of melanin-producing cells, called melanocytes, which are located in the basal layer of the epidermis and in hair follicles. This review concludes that the extent of repigmentation, regardless of the treatment method, is greatest in stable localized vitiligo patients. The aim of this review is to provide an overview of the clinical evidence for which the vitiligo treatment method (cellular or tissue) is more effective. The treatment relies on multiple factors, ranging from patient skin predisposition for repigmentation to the experience of the facility performing the procedure. Vitiligo is a significant problem in modern society. Although it is a typically asymptomatic and not life-threatening disease, it may have significant psychological and emotional impacts. Standard treatment relies on pharmacotherapy and phototherapy; however, the treatment of patients with stable vitiligo varies. The stability of vitiligo more than often implies the exhaustion of the potential for skin self-repigmentation. Thus, the surgical methods that distribute normal melanocytes into the skin are crucial elements of these patients’ therapy. The most commonly used methods are described in the literature, with an indication of their recent progress and changes. In addition, information on the efficiency of the individual methods at specific locations is compiled in this study, and the prognostic factors indicating repigmentation are presented. Cellular methods are the best therapeutic option for large-sized lesions; although they are more exorbitant than tissue methods, they benefit from more rapid healing times and presenting fewer side effects. Dermoscopy is a valuable tool used to assess the further course of repigmentation, where it is of great value to evaluate the patient prior to and following an operation.
A Comparison between Two Intervals of Daily Total End Range Time for Treatment of Proximal Interphalangeal Joint Flexion Contracture Using an Elastic Tension Digital Neoprene Orthosis
Authors: Punsola-Izard Vicenç , Casado Aroa , Carnicero Nuria , Ozaes-Lara Elena , Mendieta-Zamora Judit , Romera-Orfila Gemma , Schultz Karen S. , Llusà Manuel
Published: March 2023

Focusing on fingers with proximal interphalangeal joint flexion contractures, this study seeks to determine whether significant differences exist between the joint passive range of motion PROM improvement when receiving higher doses of daily total end range time (TERT) compared to those that receive lower doses. The study randomized a parallel group of fifty-seven fingers in fifty patients with concealed allocation and assessor blinding. Divided into two groups receiving different doses of daily total end range time with an elastic tension digital neoprene orthosis, they also participated in an identical exercise program. Patients reported orthosis wear time, and the researchers performed goniometric measurements at every session during the three-week period. The primary outcome related the time patients wore the orthosis to the degrees of improvement in PROM extension. Compared to group B (daily TERT of twelve hours), group A (TERT, twenty+ hours) showed a statistically significant greater improvement in PROM after three weeks of treatment. Group A improved by a mean of 29° compared to group B’s mean of 19° improvement. This study provides evidence that a higher dose of daily TERT can generate better results in the treatment of the proximal interphalangeal joint flexion contractures.
Copper and Nickel Induce Changes in the Lipid and Fatty Acid Composition of Anodonta cygnea
Authors: Fokina Natalia
Published: March 2023

The effect of copper and nickel ions on the lipid composition of freshwater mussels Anodonta cygnea was investigated using an aquarium experiment. The contents of the main lipid classes were determined using thin layer chromatography and spectrophotometry, and the fatty acid composition was analysed using gas–liquid chromatography. The results indicated that copper and nickel had different effects on the mussels’ lipid composition, with copper producing less effect on the composition of lipids and fatty acids than nickel. On the first experiment day, excessive copper content in the organism caused oxidative stress and modifications in membrane lipids, which returned to their initial level by the end of the experiment. Nickel accumulated predominantly in gills; however, significant modifications in lipids and fatty acids were seen also in the digestive gland from the first day of the experiment. This indicated the activation of nickel-induced lipid peroxidation processes. Moreover, this study revealed a dose-dependent effect of nickel on lipid composition, which was likely related to the development of compensatory biochemical mechanisms in response to nickel-induced oxidative stress. A comparative study of the lipid composition alteration in mussels in response to copper and nickel action revealed the consequences of the toxic impact of metal ions and the defensive mechanisms that organisms employ to detoxify and remove xenobiotics.
A Novel Representation of Audiological and Subjective Findings for Acoustical, Bone Conduction and Direct Drive Hearing Solutions
Authors: Sprinzl Georg Mathias , Magele Astrid , Schoerg Philipp , Hagen Rudolf , Rak Kristen , Kurz Anja , Van de Heyning Paul , Calvino Miryam , Lassaletta Luis , Gavilán Javier
Published: March 2023

Background: The benefit of hearing rehabilitation is often measured using audiological tests or subjective questionnaires/interviews. It is important to consider both aspects in order to evaluate the overall benefits. Currently, there is no standardized method for reporting combined audiological and patient reported subjective outcome measures in clinical practice. Therefore, this study focuses on showing the patient’s audiological, as well as subjective outcomes in one graph using data from an existing study. Method: The present paper illustrated a graph presenting data on four quadrants with audiological and subjective findings. These quadrants represented speech comprehension in quiet (unaided vs. aided) as WRS% at 65 dB SPL, speech recognition in noise (unaided vs. aided) as SRT dB SNR, sound field threshold (unaided vs. aided) as PTA4 in dB HL, wearing time and patient satisfaction questionnaire results. Results: As an example, the HEARRING graph in this paper represented audiological and subjective datasets on a single patient level or a cohort of patients for an active bone conduction hearing implant solution. The graph offered the option to follow the user’s performance in time. Conclusion: The HEARRING graph allowed representation of a combination of audiological measures with patient reported outcomes in one single graph, indicating the overall benefit of the intervention. In addition, the correlation and consistency between some results (e.g., aided threshold and aided WRS) can be better visualized. Those users who lacked performance benefits on one or more parameters and called for further insight could be visually identified.
Using the C-Read as a Portable Device to Evaluate Reading Ability in Young Chinese Adults: An Observational Study
Authors: Cheng Tian , Yao Taikang , Xu Boxuan , Dai Wanwei , Qin Xuejiao , Ye Juan , Suo Lingge , Zhang Chun
Published: March 2023

We evaluated the reading characteristics of normal-sighted young adults using C-Read to provide baseline healthy population values. We also investigated the relationship between the National Eye Institute’s Visual Functioning Questionnaire (VFQ-25) score and reading ability, myopia, and hours of screen use, focusing on the extent to which these factors affect participants’ visual function and, ultimately, their vision-related quality of life (QoL). Overall, 207 young, healthy participants (414 eyes) aged 18–35 years were tested for reading speed using C-Read connected to a smartphone-based application between December 2022 and January 2023. Each participant received a VFQ-25 questionnaire to evaluate vision-related QoL. Data on daily e-screen usage hours were collected. Among the participants, 91 (44.0%) were women; their mean (SD) age was 22.45 (4.01) years. The mean (SD) reading acuity (RA) was 0.242 (0.124), 0.249 (0.120), and 0.193 (0.104) logarithmic minimum angle of resolution (logMAR) for the right, left, and both eyes, respectively. The mean (SD) maximum reading speed (MRS) was 171.65 (46.27), 168.59 (45.68), and 185.16 (44.93) words per minute (wpm) with the right, left, and both eyes, respectively. The mean (SD) critical print size (CPS) was 0.412 (0.647), 0.371 (0.229), and 0.419 (1.05) logMAR per the right, left, and both eyes, respectively. The RA and CPS were significantly different between sexes (p = 0.002 and p = 0.001). MRS was significantly different between the education level (p = 0.005) and myopia level groups (p = 0.010); however, it was not clear whether this difference was confounded by age. The myopic power in diopters significantly affected RA (coefficient, −0.012; 95% CI, −0.018 to −0.006; p = 0.001); screen time significantly affected MRS (coefficient, 0.019; 95% CI, 0.57 to 6.33; p = 0.019). RA (coefficient, −21.41; 95% CI, −33.74 to −9.08; p = 0.001) and duration of screen use (coefficient, -0.86; 95% CI, −1.29 to −0.43; p < 0.001) independently had a significantly negative correlation with VFQ-25 scores. Our findings provide a baseline value for C-Read in normal-sighted young adults. Refractive status significantly affected RA, while screen time significantly affected MRS. Interventions aimed at enhancing RA may have the potential to maximize vision-related QoL and enable older adults with impaired vision to achieve greater outcomes. Future, larger-scale, C-Read experiments will help provide newer, more optimal methods for the early diagnosis of visual impairment.
The Effect of Proximity to Universities on House Prices after the COVID Outbreak
Authors: Wang Bingbing
Published: March 2023

COVID-19 has made virtual interactions an integral part of learning modes. This made it possible for college students to live further away from school than before, which might change the house price neighboring universities. This article studies the effect of proximity to school on house prices after the COVID-19 outbreak using a non-parametric difference-in-differences approach with property-level transaction data surrounding 128 universities in the U.S. The results show that house prices within 0.5 miles of universities experienced a maximum decrease of approximately 7% after three months of the outbreak. The effects vary for universities that implemented different teaching modes of in-person, hybrid, and online. Since house prices are important indicators for local economic conditions, the results help local homeowners, investors, and governments in their decision-making processes.
Assessment of Determinants of Paediatric Diarrhoea Case Management Adherence in Pakistan
Authors: Khaliq Asif , Holmes-Stahlman River , Ali Danish , Karatela Shamshad , Lassi Zohra S.
Published: March 2023

Worldwide, diarrhoea in children under five years of age is the second leading cause of death. Despite having high morbidity and mortality, diarrhoeal diseases can be averted by simple and cost-effective interventions. The Integrated Management of Childhood Illness (IMCI) has proposed the use of Oral Rehydration Salt (ORS) and zinc together with adequate food and fluid intake for the management of acute non-dysenteric watery diarrhoea in children. In the past, few studies examined the determinants of adherence to diarrhoea case management. Therefore, this study measured the determinants of therapeutic and dietary adherence to diarrhoea case management using the third and fourth wave of Pakistan Demographics and Health Surveys (PDHS) datasets. Data from 4068 children between 0 to 59.9 months with positive history of diarrhoea were included, while data on children with dysentery, severe dehydration, and co-morbid condition was excluded. This study reported therapeutic adherence in less than 10% of children in Pakistan, while dietary adherence was reported in 39.2% of children (37.7% in 2012–2013 and 40.7% in 2017–2018). A significant improvement in therapeutic (0.8% in 2012–2013 and 8.1% in 2017–2018) and dietary adherence (37.7% in 2012–2013 and 40.7% in 2017–2018) was reported in the 2017–2018 survey compared to the 2012–2013 survey. In general, children over the age of one year (compared to children <1 year) and of the richer/richest socioeconomic class (compared to poorest/poorer socioeconomic class) showed higher therapeutic and dietary adherence. Therapeutic and dietary adherence among diarrhoeal children can be improved by increasing the awareness and accessibility of ORS, zinc, and essential foods.
Synthesis, Characterization and Chemistry of Tetrakis(Propargylisocyanide) Copper(I) Complex
Authors: Quelhas Alexandre , Roisnel Thierry , Guillemin Jean-Claude , Trolez Yann
Published: March 2023

The kinetically unstable propargylisocyanide was reacted with the tetrakis(acetonitrile) copper(I) hexafluorophosphate and the formed complex was then involved in a copper-catalyzed alkyne-azide cycloaddition reaction (CuAAC). After the decomplexation of the adduct, the isocyanide was engaged in a Ugi reaction. By such a complexation, reactions can be carried out on the CC triple bond without the constraint of the instability of the free compound or the competitive reactivity of the isocyanide group.
Manufacture of SiC: Effect of Carbon Precursor
Authors: Ramos-Fernández Enrique V. , Narciso Javier
Published: March 2023

SiC is one of the most important ceramics at present due to its excellent properties and wide range of applications. The industrial production method, known as the Acheson method, has not changed in 125 years. Because the synthesis method in the laboratory is completely different, laboratory optimisation may not be extrapolated to the industrial level. In the present study, the results at the industrial level and at the laboratory level of the synthesis of SiC are compared. These results show that it is necessary to make a more detailed analysis of the coke than the traditional one; therefore, the Optical Texture Index (OTI) should be included, as well as the analysis of the metals that form the ashes. It has been found that the main influencing factors are OTI and the presence of Fe and Ni in the ashes. It has been determined that the higher the OTI, as well as the Fe and Ni content, the better the results obtained. Therefore, the use of regular coke is recommended in the industrial synthesis of SiC.
Numerical and Experimental Analysis of Lap Joints Made of Grade 2 Titanium and Grade 5 Titanium Alloy by Resistance Spot Welding
Authors: Piotr Lacki , Judyta Niemiro-Maźniak
Published: March 2023

The paper presents the evaluation of the load capacity of lap joints and the distribution of plastic deformations. The influence of the number and arrangement of welds on the load capacity of the joints and the method of their failure was investigated. The joints were made using resistance spot welding technology (RSW). Two combinations of joined titanium sheets were analyzed: Grade 2–Grade 5 and Grade 5–Grade 5. Non-destructive and destructive tests were carried out in order to verify the correctness of the welds within the given parameters. All types of joints were subjected to a uniaxial tensile test on a tensile testing machine, using digital image correlation and tracking (DIC). The results of the experimental tests of the lap joints were compared with the results of a numerical analysis. The numerical analysis was performed using the ADINA System 9.7.2 and was based on the finite element method (FEM). The conducted tests showed that the initiation of cracks in the lap joints occurred in the place as the maximum plastic deformations. This was determined numerically and confirmed experimentally. The number of welds and their arrangement in the joint affected the load capacity of the joints. Depending on their arrangement, Gr2–Gr5 joints with two welds reached from approximately 149 to 152% of the load capacity of joints with a single weld. The load capacity of the Gr5–Gr5 joints with two welds ranged from approximately 176 to 180% of the load capacity of joints with a single weld. Observations of the microstructure of RSW welds in the joints did not show any defects or cracks. The microhardness test in the Gr2–Gr5 joint showed that the average hardness of the weld nugget decreased by approximately 10–23% when compared to a Grade 5 titanium alloy and increased by approximately 59–92% compared to Grade 2 titanium.
Evaluation of Plastic Deformation Considering the Phase-Mismatching Phenomenon of Nonlinear Lamb Wave Mixing
Authors: Sun Maoxun , Xiang Yanxun , Shen Wei , Liu Hongye , Xiao Biao , Zhang Yue , Deng Mingxi
Published: March 2023

Nonlinear guided elastic waves have attracted extensive attention owing to their high sensitivity to microstructural changes. However, based on the widely used second harmonics, third harmonics and static components, it is still difficult to locate the micro-defects. Perhaps the nonlinear mixing of guided waves can solve these problems since their modes, frequencies and propagation direction can be flexibly selected. Note that the phenomena of phase mismatching usually occur due to the lack of precise acoustic properties for the measured samples, and they may affect the energy transmission from the fundamental waves to second-order harmonics as well as reduce the sensitivity to micro-damage. Therefore, these phenomena are systematically investigated to more accurately assessing the microstructural changes. It is theoretically, numerically, and experimentally found that the cumulative effect of difference- or sum-frequency components will be broken by the phase mismatching, accompanied by the appearance of the beat effect. Meanwhile, their spatial periodicity is inversely proportional to the wavenumber difference between fundamental waves and difference- or sum-frequency components. The sensitivity to micro-damage is compared between two typical mode triplets that approximately and exactly meet the resonance conditions, and the better one is utilized for assessing the accumulated plastic deformations in the thin plates.
Proportioning Factors of Alkali-Activated Materials and Interaction Relationship Revealed by Response Surface Modeling
Authors: Zhao Jun , Wang Aiguo , Lyu Bangcheng , Liu Kaiwei , Chu Yingjie , Ma Rui , Xu Haiyan , Jing Yan , Sun Daosheng
Published: March 2023

Alkali-activated fly-ash–slag blending materials (AA-FASMs) are gradually being studied and applied more because of their good performance. There are many factors affecting the alkali-activated system, and the effect of single-factor variation on the performance of AA-FASM has been mostly reported; however, there is a lack of unified understanding of the mechanical properties and microstructure of AA-FASM under curing conditions and multiple-factor interaction. Therefore, this study investigated the compressive strength development and reaction products of alkali-activated AA-FASM under three curing conditions including seal (S), dry (D) and water saturation (W). Based on the response surface model, the relationship between the interaction of slag content (WSG), activator modulus (M) and activator dosage (RA) on its strength was established. The results showed that the maximum compressive strength of AA-FASM after 28 days of sealed curing was about 59 MPa, while the strengths of dry- and water-saturation-cured specimens decreased by 9.8% and 13.7%, respectively. The seal-cured samples also had the smallest mass change rate and linear shrinkage and the most compact pore structure. Due to the adverse effects from a too-high or too-low modulus and dosage of the activators, the shapes of upward convex, slope and inclined convex were under the interaction of WSG/M, WSG/RA and M/RA, respectively. The correlation coefficient R2 > 0.95 and p-value < 0.05 indicated that the proposed model could be used to predict strength development given the complex factors. Optimal proportioning and curing conditions were found to be WSG = 50%, M = 1.4, RA = 50% and sealed curing.
Studying the Wettability and Bonding Properties of Acetylated Hornbeam Wood Using PVAc and PUR Adhesives
Authors: Fodor Fanni , Bak Miklós
Published: March 2023

The present study aimed to determine how acetylation affected the bonding properties of European hornbeam wood. The research was supplemented with the investigation of wetting properties, wood shear strength, and microscopical studies of bonded wood, as these all have strong relationships with wood bonding. Acetylation was carried out on an industrial scale. Acetylated hornbeam showed a higher contact angle and lower surface energy than untreated hornbeam. Although the adhesion of the acetylated wood surface is lower due to its lower polarity and porosity, the bonding strength of acetylated hornbeam was similar to that of untreated hornbeam when bonded with PVAc D3 adhesive, and it was higher in the case of PVAc D4 and PUR adhesives. Microscopical studies proved these findings. After acetylation, hornbeam could be used in applications where it is exposed to moisture, as its bonding strength after soaking or boiling in water was significantly higher than that of untreated hornbeam.
A Review on Porosity Formation in Aluminum-Based Alloys
Authors: Samuel Agnes M. , Samuel Ehab , Songmene Victor , Samuel Fawzy H.
Published: March 2023

The main objective of this review is to analyze the equations proposed for expressing the effect of various parameters on porosity formation in aluminum-based alloys. These parameters include alloying elements, solidification rate, grain refining, modification, hydrogen content, as well as the applied pressure on porosity formation in such alloys. They are used to establish as precisely as possible a statistical model to describe the resulting porosity characteristics such as the percentage porosity and pore characteristics, as controlled by the chemical composition of the alloy, modification, grain refining, and the casting conditions. The measured parameters of percentage porosity, maximum pore area, average pore area, maximum pore length, and average pore length, which were obtained from statistical analysis, are discussed, and they are supported using optical micrographs, electron microscopic images of fractured tensile bars, as well as radiography. In addition, an analysis of the statistical data is presented. It should be noted that all alloys described were well degassed and filtered prior to casting.
TiO2 Nanorod-Coated Polyethylene Separator with Well-Balanced Performance for Lithium-Ion Batteries
Authors: Chen Zhanjun , Wang Tao , Yang Xianglin , Peng Yangxi , Zhong Hongbin , Hu Chuanyue
Published: March 2023

The thermal stability of the polyethylene (PE) separator is of utmost importance for the safety of lithium-ion batteries. Although the surface coating of PE separator with oxide nanoparticles can improve thermal stability, some serious problems still exist, such as micropore blockage, easy detaching, and introduction of excessive inert substances, which negatively affects the power density, energy density, and safety performance of the battery. In this paper, TiO2 nanorods are used to modify the surface of the PE separator, and multiple analytical techniques (e.g., SEM, DSC, EIS, and LSV) are utilized to investigate the effect of coating amount on the physicochemical properties of the PE separator. The results show that the thermal stability, mechanical properties, and electrochemical properties of the PE separator can be effectively improved via surface coating with TiO2 nanorods, but the degree of improvement is not directly proportional to the coating amount due to the fact that the forces inhibiting micropore deformation (mechanical stretching or thermal contraction) are derived from the interaction of TiO2 nanorods directly “bridging” with the microporous skeleton rather than those indirectly “glued” with the microporous skeleton. Conversely, the introduction of excessive inert coating material could reduce the ionic conductivity, increase the interfacial impedance, and lower the energy density of the battery. The experimental results show that the ceramic separator with a coating amount of ~0.6 mg/cm2 TiO2 nanorods has well-balanced performances: its thermal shrinkage rate is 4.5%, the capacity retention assembled with this separator was 57.1% under 7 C/0.2 C and 82.6% after 100 cycles, respectively. This research may provide a novel approach to overcoming the common disadvantages of current surface-coated separators.
Enhancing Removal of Pollutants by Combining Photocatalysis and Photo-Fenton Using Co, Fe-Doped Titanate Nanowires
Authors: Barrocas B. T. , Osawa R. , Oliveira M. Conceição , Monteiro O. C.
Published: March 2023

Aiming to improve their photocatalytic performance, titanate nanowires (TNW) were modified by Fe and Co (co)-doping, FeTNW, CoTNW and CoFeTNW samples, using a hydrothermal methodology. XRD characterization agrees with the existence of Fe and Co in the lattice structure.and the existence of Co2+ together with the presence of Fe2+ and Fe3+ in the structure was confirmed by XPS. The optical characterization of the modified powders shows the impact of the d–d transitions of both metals in the absorption properties of TNW, mainly in the creation of additional 3d energetic levels within the prohibited zone. The effect of the doping metal(s) in the recombination rate of photo-generated charge carriers suggests a higher impact of Fe presence when compared to Co. The photocatalytic characterization of the prepared samples was evaluated via the removal of acetaminophen. Furthermore, a mixture containing both acetaminophen and caffeine, a well-known commercial combination, was also tested. CoFeTNW sample was the best photocatalyst for the degradation of acetaminophen in both situations. A mechanism for the photo-activation of the modified semiconductor is discussed and a model proposed. It was concluded that both Co and Fe are essential, within the TNW structure, for the successful removal of acetaminophen and caffeine.
An Investigation of Compressive Creep Aging Behavior of Al-Cu-Li Alloy Pre-Treated by Compressive Plastic Deformation and Artificial Aging
Authors: Liu Jinqiu , Guo Fuqiang , Matsuda Kenji , Wang Tao , Zou Yong
Published: March 2023

In this paper, the effects of compressive pre-deformation and successive pre-artificial aging on the compressive creep aging behavior and microstructure evolution of the Al-Cu-Li alloy have been studied. Severe hot deformation mainly occurs near the grain boundaries during the compressive creep initially, which steadily extends to the grain interior. After that, the T1 phases will obtain a low radius–thickness ratio. The secondary T1 phases in pre-deformed samples usually only nucleate on dislocation loops or Shockley incomplete dislocations induced by movable dislocations during creep, which are especially prevalent in low plastic pre-deformation. For all pre-deformed and pre-aged samples, two precipitation situations exist. When pre-deformation is low (3% and 6%), solute atoms (Cu and Li) can be consumed prematurely during pre-aging at 200 °C, with dispersed coherent Li-rich clusters in the matrix. Then, the pre-aged samples with low pre-deformation no longer have the ability to form secondary T1 phases in large quantities during subsequent creep. When dislocation entangles seriously to some extent, a large quantity of stacking faults, together with a “Suzuki atmosphere” containing Cu and Li, can provide the nucleation sites for the secondary T1 phase, even when pre-aged at 200 °C. The sample, pre-deformed by 9% and pre-aged at 200 °C, displays excellent dimensional stability during compressive creep because of the mutual reinforcement of entangled dislocations and pre-formed secondary T1 phases. In order to decrease the total creep strain, increasing the pre-deformation level is more effective than pre-aging.
Investigation of Gamma-Ray Shielding Properties of Bismuth Oxide Nanoparticles with a Bentonite–Gypsum Matrix
Authors: Abbas Mahmoud I. , El-Khatib Ahmed M. , Elsafi Mohamed , El-Shimy Sarah N. , Dib Mirvat F. , Abdellatif Hala M. , Baharoon Raqwana , Gouda Mona M.
Published: March 2023

Due to the present industrial world, the risk of radioactivity is notably increasing. Thus, an appropriate shielding material needs to be designed to protect humans and the environment against radiation. In view of this, the present study aims to design new composites of the main matrix of bentonite–gypsum with a low-cost, abundant, and natural matrix. This main matrix was intercalated in various amounts with micro- and nanosized particles of bismuth oxide (Bi2O3) as the filler. Energy dispersive X-ray analysis (EDX) recognized the chemical composition of the prepared specimen. The morphology of the bentonite–gypsum specimen was tested using scanning electron microscopy (SEM). The SEM images showed the uniformity and porosity of a cross-section of samples. The NaI (Tl) scintillation detector was used with four radioactive sources (241Am, 137Cs, 133Ba, and 60Co) of various photon energies. Genie 2000 software was used to determine the area under the peak of the energy spectrum observed in the presence and absence of each specimen. Then, the linear and mass attenuation coefficients were obtained. After comparing the experimental results of the mass attenuation coefficient with the theoretical values from XCOM software, it was found that the experimental results were valid. The radiation shielding parameters were computed, including the mass attenuation coefficients (MAC), half-value layer (HVL), tenth-value layer (TVL), and mean free path (MFP), which are dependent on the linear attenuation coefficient. In addition, the effective atomic number and buildup factors were calculated. The results of all of these parameters provided the same conclusion, which confirms the improvement of the properties of γ-ray shielding materials using a mixture of bentonite and gypsum as the main matrix, which is much better than using bentonite alone. Moreover, bentonite mixed with gypsum is a more economical means of production. Therefore, the investigated bentonite–gypsum materials have potential uses in applications such as gamma-ray shielding materials.
Degradation and Protection of Materials from Cavitation Erosion: A Review
Authors: Krella Alicja Krystyna
Published: March 2023

The phenomena of cavitation and cavitation erosion affect hydraulic machines, increasing their maintenance costs. Both these phenomena and also the methods of preventing the destruction of materials are presented. The compressive stress in the surface layer created from the implosion of cavitation bubbles depends on the aggressiveness of the cavitation, which in turn depends on the test device and test conditions, and also affects the erosion rate. Comparing the erosion rates of different materials tested using different tests devices, the correlation with material hardness was confirmed. However, no one simple correlation was obtained but rather several were achieved. This indicates that in addition to hardness, cavitation erosion resistance is also affected by other properties, such as ductility, fatigue strength and fracture toughness. Various methods such as plasma nitriding, shot peening, deep rolling and coating deposition used to increase resistance to cavitation erosion by increasing the hardness of the material surface are presented. It is shown that the improvement depends on the substrate, coating material and test conditions, but even using the same materials and test conditions large differences in the improvement can be sometimes gained. Moreover, sometimes a slight change in the manufacturing conditions of the protective layer or coating component can even contribute to a deterioration in resistance compared with the untreated material. Plasma nitriding can improve resistance by even 20 times, but in most cases, the improvement was about two-fold. Shot peening or friction stir processing can improve erosion resistance up to five times. However, such treatment introduces compressive stresses into the surface layer, which reduces corrosion resistance. Testing in a 3.5% NaCl solution showed a deterioration of resistance. Other effective treatments were laser treatment (an improvement from 1.15 times to about 7 times), the deposition of PVD coatings (an improvement of up to 40 times) and HVOF coatings or HVAF coatings (an improvement of up to 6.5 times). It is shown that the ratio of the coating hardness to the hardness of the substrate is also very important, and for a value greater than the threshold value, the improvement in resistance decreases. A thick, hard and brittle coating or alloyed layer may impair the resistance compared to the untreated substrate material.
Green Synthesis of Iridium Nanoparticles from Winery Waste and Their Catalytic Effectiveness in Water Decontamination
Authors: Mergola Lucia , Carbone Luigi , Stomeo Tiziana , Del Sole Roberta
Published: March 2023

An environmentally friendly procedure was adopted for the first time to prepare green iridium nanoparticles starting from grape marc extracts. Grape marcs, waste of Negramaro winery production, were subjected to aqueous thermal extraction at different temperatures (45, 65, 80, and 100 °C) and characterized in terms of total phenolic contents, reducing sugars, and antioxidant activity. The results obtained showed an important effect of temperature with higher amounts of polyphenols and reducing sugars and antioxidant activity in the extracts with the increase of temperature. All four extracts were used as starting materials to synthesize different iridium nanoparticles (Ir-NP1, Ir-NP2, Ir-NP3, and Ir-NP4) that were characterized by Uv-Vis spectroscopy, transmission electron microscopy, and dynamic light scattering. TEM analysis revealed the presence of very small particles in all samples with sizes in the range of 3.0–4.5 nm with the presence of a second fraction of larger nanoparticles (7.5–17.0 nm) for Ir-NPs prepared with extracts obtained at higher temperatures (Ir-NP3 and Ir-NP4). Since the wastewater remediation of toxic organic contaminants on catalytic reduction has gained much attention, the application of the prepared Ir-NPs as catalysts towards the reduction of methylene blue (MB), chosen as the organic dye model, was evaluated. The efficient catalytic activity of Ir-NPs in the reduction of MB by NaBH4 was demonstrated and Ir-NP2 was prepared using the extract obtained at 65 °C, showing the best catalytic performance, with a rate constant of 0.527 ± 0.012 min−1 and MB reduction of 96.1% in just six min, with stability for over 10 months.
Common Fixed Point Results in Bicomplex Valued Metric Spaces with Application
Authors: Albargi Amer Hassan , Shammaky Amnah Essa , Ahmad Jamshaid
Published: March 2023

The purpose of this paper is to establish common fixed points of six mappings in the context of bicomplex valued metric spaces. In this way, we generalize some previous well-known results from the literature. Moreover, we provide a non-trivial example to demonstrate the authenticity of established outcomes. As an application, we investigate the solution of an Urysohn integral equation by applying our results.
An Algorithm for Real-Time Aluminum Profile Surface Defects Detection Based on Lightweight Network Structure
Authors: Tang Junlong , Liu Shenbo , Zhao Dongxue , Tang Lijun , Zou Wanghui , Zheng Bin
Published: March 2023

Surface defects, which often occur during the production of aluminum profiles, can directly affect the quality of aluminum profiles, and should be monitored in real time. This paper proposes an effective, lightweight detection method for aluminum profiles to realize real-time surface defect detection with ensured detection accuracy. Based on the YOLOv5s framework, a lightweight network model is designed by adding the attention mechanism and depth-separable convolution for the detection of aluminum. The lightweight network model improves the limitations of the YOLOv5s framework regarding to its detection accuracy and detection speed. The backbone network GCANet is built based on the Ghost module, in which the Attention mechanism module is embedded in the AC3Ghost module. A compression of the backbone network is achieved, and more channel information is focused on. The model size is further reduced by compressing the Neck network using a deep separable convolution. The experimental results show that, compared to YOLOv5s, the proposed method improves the mAP by 1.76%, reduces the model size by 52.08%, and increases the detection speed by a factor of two. Furthermore, the detection speed can reach 17.4 FPS on Nvidia Jeston Nano’s edge test, which achieves real-time detection. It also provides the possibility of embedding devices for real-time industrial inspection.
Erythroprotective Potential of Phycobiliproteins Extracted from Porphyridium cruentum
Authors: Peña-Medina Rubria Lucía , Fimbres-Olivarría Diana , Enríquez-Ocaña Luis Fernando , Martínez-Córdova Luis Rafael , Del-Toro-Sánchez Carmen Lizette , López-Elías José Antonio , González-Vega Ricardo Iván
Published: March 2023

There are multiple associations between the different blood groups (ABO and RhD) and the incidence of oxidative stress-related diseases, such as certain carcinomas and COVID-19. Bioactive compounds represent an alternative to its prevention and treatment. Phycobiliproteins (PBP) are bioactive compounds present in the microalga Porphyridium cruentum and, despite its antioxidant activity, their inhibitory effect on hemolysis has not been reported. The aim of this work was to evaluate the erythroprotective potential of phycobiliproteins from P. cruentum in different blood groups. The microalga was cultured in F/2 medium under controlled laboratory conditions. Day 10 of culture was determined as the harvest point. The microalgal biomass was lyophilized and a methanolic (MetOH), Tris HCl (T-HCl), and a physiological solution (PS) ultrasound-assisted extraction were performed. Extract pigments were quantified by spectrophotometry. The antioxidant activity of the extracts was evaluated with the ABTS+•, DPPH•, and FRAP methods, finding that the main antioxidant mechanism on the aqueous extracts was HAT (hydrogen atom transfer), while for MetOH it was SET (single electron transfer). The results of the AAPH, hypotonicity, and heat-induced hemolysis revealed a probable relationship between the different antigens (ABO and RhD) with the antihemolytic effect, highlighting the importance of bio-directed drugs.
Evaluating the Relationship between Circadian Rhythms and Sleep, Metabolic and Cardiovascular Disorders: Current Clinical Evidence in Human Studies
Authors: Mentzelou Maria , Papadopoulou Sousana K. , Papandreou Dimitrios , Spanoudaki Maria , Dakanalis Antonios , Vasios Georgios K. , Voulgaridou Gavriela , Pavlidou Eleni , Mantzorou Maria , Giaginis Constantinos
Published: March 2023

Circadian rhythms are generated by the circadian clock, a self-sustained internal timing system that exhibits 24-h rhythms in the body. Many metabolic, cellular, behavioral and physiological processes are regulated by the circadian clock in coordination with environmental cues. The present study is a comprehensive review of the currently existing evidence concerning the relationship between circadian rhythms and sleep, metabolic, and cardiovascular disorders. We thoroughly searched the online databases PubMed, Scopus, and Web of Science to find the existing clinical studies from the last twenty-three years (2000–2023). Circadian misalignment was found to be associated with an increase in the risk of metabolic disorders, cardiovascular diseases, and obesity, as well as inadequate sleep quality. In this review article, all the included studies had a strength protocol design and all of them were conducted on humans. However, the most common limitations of them were the small sample size and the short time of the intervention. In conclusion, managing the factors that disrupt the optimal function of central and peripheral clocks can help to reduce the risk of metabolic and cardiovascular diseases, improving also sleep quality. Future studies should further explore the underlying mechanisms of the interconnections between circadian clocks and sleep, metabolic, and cardiovascular disorders. This may provide new opportunities for advance chronotherapy approach.
Geological Significance of Neoproterozoic Intrusive Rocks in the South Section of the Ailaoshan Orogenic Belt, SW China: Insights from Petrology, Geochemistry, and Geochronology
Authors: Zhang Yaoyao , Zhang Da , Liu Kai , Mo Xuanxue , Wang Shuxun , Zhao Zenan , He Xiaolong , Yu Tingxi
Published: March 2023

The Ailaoshan orogenic belt is one of the most significant orogenic belts in the southeastern margin of the Qinghai–Tibet Plateau. The widely developed magmatic rocks in this belt preserve the multi-stage tectonic evolution records of the South China Plate. As an important response to the Rodinia breakup tectonic event, the study of Neoproterozoic magmatic rocks in the area is of great significance for reconstructing the Neoproterozoic tectonic process of the Ailaoshan orogenic belt and the tectonic evolution of the South China Plate. Petrology, geochemistry, zircon U-Pb, and Lu-Hf isotopes of the Daping pluton in the Ailaoshan orogenic belt are studied in this paper. The Daping pluton is mainly divided into gabbros and granites. Gabbros and granites belong to the sub-alkaline series, which are relatively enriched in large ion lithophilic elements and depleted in high-field strength elements. The ΣREE contents of the gabbro are low with enrichment in LREEs and depletion in HREEs, and the degree of differentiation of light and heavy rare earth is low, with positive δEu and weak negative δCe anomalies. The ΣREE contents of the granite are low with enrichment in LREEs and depletion in HREEs, and the degree of light and heavy rare earth differentiation is high, with medium–weak negative δEu and weak positive δCe anomalies, suggesting an A2-type granite with A1-A2 transition characteristics. The weighted average age of the gabbro is 816.1 ± 4.1 Ma (MSWD = 0.11), with zircon εHf(t) values of −7.5–5.5. The magma source is a mixture of an ancient crust source and a new mantle source; the weighted average age of the syenogranite is 783.7 ± 8.1 Ma (MSWD = 1.4), with zircon εHf(t) values of −4.3–0.4. The magma source is mainly ancient crustal material (Ailaoshan Group), mixed with a small amount of mantle-derived material; the weighted average age of the monzogranite is 754.8 ± 6.1 Ma (MSWD = 3.0), with positive zircon εHf(t) values of 1.65–10.36. The magma source is a mixture of a large number of mantle-derived materials and a small number of crust-derived materials (Ailaoshan Group). The Daping pluton was formed in the transitional tectonic environment from post-collision to intraplate continental margin rift, corresponding to the Rodinia breakup process in the western margin of the South China Plate.
Investigation on the Fragmentation and Outburst Mechanism of Coal Sample with Pore Gas Using CDEM
Authors: Zhang Qunlei , Wang Zhiming , Feng Chun , Zhu Xinguang , Zhou Jun
Published: March 2023

In this paper, using the continuum-discontinuum element method (CDEM), the fragmentation and outburst process of coal specimen are simulated, and the main factors affecting coal breaking and outburst are explored. The results show that after the coal seam is uncovered, coal generates obvious failure and outburst trend. Near coal-free surface, the fracture coal blocks generate significant displacement, resulting in larger opening widths of coal cracks. Coal deep generates the cracks without an obvious opening width. The crack density of coal with pore gas is larger than those of coal without gas, and it is larger than those of coal without pores. However, in the early stage of coal failure, the obvious separation and outburst ranges of coal with gas are smaller than those of coal without gas, and are smaller than those of coal without pores. The numbers of fracture coal blocks show an increase with the growth of in situ stress, pore ratio and gas pressure. The effect of in situ stress on fracture coal block number (517–10,203) is larger than the effect (7589–15,170) of pore ratio and is larger than the effect (5803–6836) of gas pressure. The effect of in situ stress on a maximum size (0.0387–0.138 m) of fracture blocks is larger than the effect (0.0342–0.0733 m) of pore ratio and is larger than the effect (0.0454–0.0578 m) of gas pressure. The coal outburst velocity and range show an increase with the growth of gas pressure and in situ stress (3.77–5.65 m/s); however, the coal outburst shows a slow decrease with a growth of pore ratio. The effect of gas pressure on the coal outburst velocity (11.51–21.9 m/s) is larger than the effect (3.77–5.65 m/s) of in situ stress and is larger than the effect (4.52–5.23 m/s) of pore ratio. This investigation is beneficial to understand the mechanisms of coal–gas outburst in coal mining and roadway excavation.
Bending Improvement of CO2-Activated Materials through Crosslinking of Oligomers
Authors: Zhang Yunhua , Wang Qing , Zhang Zhipeng , Lei Pengxiang
Published: March 2023

Calcium carbonate is the main carbonation product of most CO2-activated materials (CAMs); however, its brittle nature usually leads to low bending, which represents the major drawback of CAM in its application as a construction material. Herein, the bending of CAM was greatly improved by the addition of triethylamine (TEA) in the carbonation process. Both the grain size of the carbonation product, i.e., calcite, and the intensity ratio of the crystal planes from (104) to (113) obviously increased with the addition of TEA, as shown by the scanning electron microscopy (SEM) and X-ray diffraction (XRD) measurements, suggesting the crosslinking of oligomers. Compared with the CAM without TEA, the flexural strength of CAM was significantly improved under optimized curing conditions, which was attributed to the crosslinking of oligomers formed with TEA addition. The present work may provide a promising strategy for improving the bending of CAM materials.
β-Bi2O3 Nanosheets Functionalized with Bisphenol A Synthetic Receptors: A Novel Material for Sensitive Photoelectrochemical Platform Construction
Authors: Yang Jing-Jing , Shen Ying-Zhuo , Wang Zheng , Zhou Bo , Hu Xiao-Ya , Xu Qin
Published: March 2023

In this study, β-Bi2O3 nanosheets functionalized with bisphenol A (BPA) synthetic receptors were developed by a simple molecular imprinting technology and applied as the photoelectric active material for the construction of a BPA photoelectrochemical (PEC) sensor. BPA was anchored on the surface of β-Bi2O3 nanosheets via the self-polymerization of dopamine monomer in the presence of a BPA template. After the elution of BPA, the BPA molecular imprinted polymer (BPA synthetic receptors)-functionalized β-Bi2O3 nanosheets (MIP/β-Bi2O3) were obtained. Scanning electron microscopy (SEM) of MIP/β-Bi2O3 revealed that the surface of β-Bi2O3 nanosheets was covered with spherical particles, indicating the successful polymerization of the BPA imprinted layer. Under the best experimental conditions, the PEC sensor response was linearly proportional to the logarithm of BPA concentration in the range of 1.0 nM to 1.0 μM, and the detection limit was 0.179 nM. The method had high stability and good repeatability, and could be applied to the determination of BPA in standard water samples.