Comparative analysis of electrical models of lith-ium-ion batteries in electric vehicles
Authors: Smyrnov Oleh , Borysenko Anna 
Published: December 2023

Problem. This article addresses the challenge of enhancing the environmental friendliness and energy efficiency of vehicles. It does so by conducting a comparative analysis and identifying ways to improve the electrical models of lithium-ion batteries used in electric vehicles. The study includes an examination of well-known electrical models of lithium-ion rechargeable batteries, such as the Rint model, the RC model, the Thevenin model, and the PNGV model. It identifies key characteristics of lithium-ion batteries in electric vehicles, including state of charge, mass, actual voltage, energy required for recharging, among others. The study also explores models of battery degradation, focusing on capacity reduction and the increase in active resistance. It substantiates directions for improving electrical models of lithium-ion batteries in electric vehicles by considering changes in capacity, internal resistance, polarization resistance, and both calendar and cyclic degradation. Goal. The aim of this work is to enhance the environmental friendliness and energy efficiency of vehicles through a comparative analysis and by determining ways to improve the electrical models of lithium-ion batteries in electric vehicles. Methodology. Our approach to achieving this goal involves using electrical models of lithium-ion batteries in electric vehicles, which describe various parameters such as state of charge, actual voltage during charge/discharge processes, and energy required for recharging. The study encompasses an investigation into the degradation of electric vehicle batteries, including their use in Vehicle to Grid (V2G) technology. Results. The analysis of electrical models of lithium-ion batteries in electric vehicles, aiming to increase their accuracy, considers the following aspects: changes in internal resistance and polarization resistance; capacity variation; and battery degradation. The change in internal resistance and polarization resistance should be considered based on two factors: the state of charge of the battery and the degree of its degradation. While the first factor is relevant primarily when the battery is deeply discharged (SoC<30%), the second factor must be considered at any state of charge. Capacity changes should be accounted for based on calendar and cyclic degradation. It has been determined that the primary causes of degradation in electric vehicle batteries are calendar aging (service life) and aging due to charge/discharge cycles. Contrarily, it is argued that using Vehicle to Grid (V2G) technology can reduce battery degradation by 10%. Originality. The results of this study provide a comprehensive understanding of the electrical models of lithium-ion batteries in electric vehicles and contribute to the improvement of existing models. Practical value. This research enhances the accuracy of current electrical models of lithium-ion batteries in electric vehicles by considering the variable nature of internal resistance and capacity during vehicle operation. It may be valuable in assessing the residual parameters of electric vehicle batteries during their secondary use, such as in the residential sector for solar energy support. The findings can be recommended to scientific and technical professionals involved in developing energy storage systems for electric vehicles.