bluuebunny/crossref_metadata_2025 huggingface dataset:
Long-Term Isothermal Phase Transformation in Lead Zirconate
Authors: Kajewski Dariusz , Jankowska-Sumara Irena , Ko Jae-Hyeon , Lee Jeong Woo , Naqvi Syed Furqan Ul Hassan , Sitko Rafał , Majchrowski Andrzej , Roleder Krystian
Published: June 2022

Lead zirconate PbZrO3 has been the subject of research interest for several dozen years. Recently, even its antiferroelectric properties have started to be questioned, and many researchers still deal with the so-called intermediate phase below Curie temperature (TC), whose existence is not fully understood. It turns out that PbZrO3 doped with Nb exhibits below TC phases with complex domain structures. One of them undergoes self-organization taking place at a constant temperature, and transforms, after several minutes, into a lower phase. This isothermal transition was investigated through dielectric, pyroelectric current and Raman scattering measurements. Discontinuities accompanied it in the permittivity and pyroelectric current. The obtained Raman spectra proved that those discontinuities are strictly linked with the isothermal transition between two intermediate phases. The ordering process in lead sublattice stimulated by thermal fluctuations is discussed as a driving force for this peculiar phenomenon.
The Reuse of Biomass and Industrial Waste in Biocomposite Construction Materials for Decreasing Natural Resource Use and Mitigating the Environmental Impact of the Construction Industry: A Review
Authors: Ryłko-Polak Iwona , Komala Wojciech , Białowiec Andrzej
Published: June 2022

The construction industry is the world’s largest emitter of greenhouse gases. The CO2 emission levels in the atmosphere are already reaching a tipping point and could cause severe climate change. An important element is the introduction of a technology that allows for the capture and sequencing of carbon dioxide levels, reducing both emissions and the carbon footprint from the production of Portland cement and cement-based building materials. The European Union has started work on the European Climate Law, establishing the European Green Deal program, which introduces the achievement of climate neutrality in the European Union countries. This includes a new policy of sustainable construction, the aim of which is to develop products with a closed life cycle through proper waste management. All efforts are being made to create generated waste and thus to support their production and/or use as substitutes for raw materials to produce biocomposites. This article reviews environmental issues and characterizes selected waste materials from the agri-food, mineral, and industrial sectors with specific properties that can be used as valuable secondary raw materials to produce traditional cements and biocomposite materials, while maintaining or improving their mechanical properties and applications.
The Gd2−xMgxZr2O7−x/2 Solid Solution: Ionic Conductivity and Chemical Stability in the Melt of LiCl-Li2O
Authors: Anokhina Irina , Pavlenko Olga , Proskurnina Natal’ya , Dedyukhin Alexander , Animitsa Irina
Published: June 2022

Materials with pyrochlore structure A2B2O7 have attracted considerable attention owing to their various applications as catalysts, sensors, electrolytes, electrodes, and magnets due to the unique crystal structure and thermal stability. At the same time, the possibility of using such materials for electrochemical applications in salt melts has not been studied. This paper presents the new results of obtaining high-density Mg2+-doped ceramics based on Gd2Zr2O7 with pyrochlore structure and comprehensive investigation of the electrical properties and chemical stability in a lithium chloride melt with additives of various concentrations of lithium oxide, performed for the first time. The solid solution of Gd2−xMgxZr2O7−x/2 (0 ≤ x ≤ 0.10) with the pyrochlore structure was obtained by mechanically milling stoichiometric mixtures of the corresponding oxides, followed by annealing at 1500 °C. The lattice parameter changed non-linearly as a result of different mechanisms of Mg2+ incorporation into the Gd2Zr2O7 structure. At low dopant concentrations (x ≤ 0.03) some interstitial positions can be substituted by Mg2+, with further increasing Mg2+-content, the decrease in the lattice parameter occurred due to the substitution of host-ion sites with smaller dopant-ion. High-density ceramics 99% was prepared at T = 1500 °C. According to the results of the measurements of electrical conductivity as a function of oxygen partial pressure, all investigated samples were characterized by the dominant ionic type of conductivity over a wide range of pO2 (1 × 10–18 ≤ pO2 ≤ 0.21 atm) and T < 800 °C. The sample with the composition of x = 0.03 had the highest oxygen-ion conductivity (10−3 S·cm−1 at 600 °C). The investigation of chemical stability of ceramics in the melt of LiCl with 2.5 mas.% Li2O showed that the sample did not react with the melt during the exposed time of one week at the temperature of 650 °C. This result makes it possible to use these materials as oxygen activity sensors in halide melts.
Plasmochemical Modification of Crofer 22APU for Intermediate-Temperature Solid Oxide Fuel Cell Interconnects Using RF PA CVD Method
Authors: Januś Marta , Kyzioł Karol , Kluska Stanisława , Jastrzębski Witold , Adamczyk Anna , Grzesik Zbigniew , Zimowski Sławomir , Potoczek Marek , Brylewski Tomasz
Published: June 2022

The results of plasmochemical modification on Crofer 22APU ferritic stainless steel with a SiCxNy:H layer, as well as the impact of these processes on the increase in usability of the steel as intermediate-temperature solid oxide fuel cell (IT-SOFC), interconnects, are presented in this work. The layer was obtained using Radio-Frequency Plasma-Activated Chemical Vapor Deposition (RF PA CVD, 13.56 MHz) with or without the N+ ion modification process of the steel surface. To determine the impact of the surface modification on the steel’s resistance to high-temperature corrosion and on its mechanical properties, the chemical composition, atomic structure, and microstructure were investigated by means of IR spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). Microhardness, Young’s modulus, wear rate, as well as electrical resistance, were also determined. Micromechanical experiments showed that the plasmochemical modification has a positive influence on the surface hardness and Young’s modulus of the investigated samples. High-temperature oxidation studies performed for the samples indicate that N+ ion modification prior to the deposition of the SiCxNy:H layer improves the corrosion resistance of Crofer 22APU steel modified via CVD. The area-specific resistance of the studied samples was 0.01 Ω·cm2, which is lower than that of bare steel after 500 h of oxidation at 1073 K. It was demonstrated that the deposition of the SiCxNy:H layer preceded by N+ ion modification yields the best properties.
Assessment of Hot Corrosion in Molten Na2SO4 and V2O5 of Inconel 625 Fabricated by Selective Laser Melting versus Conventional Technology
Authors: Badea Teodor Adrian , Batalu Dan , Constantin Nicolae , Paraschiv Alexandru , Pătroi Delia , Ceatra Laurentiu Constantin
Published: June 2022

Inconel 625 samples, obtained by Selective Laser Melting (SLM) and conventional technology, were tested for hot corrosion resistance against a molten mixture of Na2SO4 and V2O5. The assessments were performed in air, at 900 °C with exposure time of up to 96 h, and at 1000 °C for 8 h. Weight gain was higher for samples obtained by SLM, with 37.4% after 8 h, 3.98% after 24 h, 4.46% after 48 h, and 5.8% after 96 h at 900 °C (22.6% at 1000 °C, 8 h). Three stages of corrosion were observed, the first and last with a high corrosion rate, while the second one showed a slower corrosion rate. Corrosion behaviour depends on the morphology of the grain boundary, which can influence the infiltration of corrosive salts, and on the formation of Cr2NiO4 compound, which acts as a temporary barrier.
Surface Modification of Synthetic Zeolites with Ca and HDTMA Compounds with Determination of Their Phytoavailability and Comparison of CEC and AEC Parameters
Authors: Łach Michał , Grela Agnieszka , Pławecka Kinga , Guigou Martin Duarte , Mikuła Janusz , Komar Norbert , Bajda Tomasz , Korniejenko Kinga
Published: June 2022

Zeolites obtained from fly ash are characterized by very good anion- and cation-exchange properties and a developed porous structure. This paper presents the results of surface modification studies of synthetic zeolites obtained from calcined coal shale (clay materials). Calcium compounds and hexadecyltrimethylammonium bromide (HDTMA) were used as modifying substances. The characteristics of the raw material and the zeolite obtained as a result of its synthesis are presented. The surface modification method is described. Furthermore, the results of sorption and desorption of NO3, PO4, and SO4 from raw and modified samples are presented. The results of anion- and cation-exchange capacities for other zeolite types were also compared. Modification of the materials with Ca ions and HDTMA surfactant only improved the sorption of sulfates. The 90% desorption of nitrates, phosphates, and sulphates from the zeolite material without modification indicates a good release capacity of these compounds and their potential use as fertilizer additives.
Preparation of Fly Ash-Ladle Furnace Slag Blended Geopolymer Foam via Pre-Foaming Method with Polyoxyethylene Alkyether Sulphate Incorporation
Authors: Hui-Teng Ng , Cheng-Yong Heah , Yun-Ming Liew , Abdullah Mohd Mustafa Al Bakri , Rojviriya Catleya , Razi Hasniyati Md , Garus Sebastian , Nabiałek Marcin , Sochacki Wojciech , Abidin Ilham Mukriz Zainal , Yong-Sing Ng , Śliwa Agata , Sandu Andrei Victor
Published: June 2022

This paper uses polyoxyethylene alkyether sulphate (PAS) to form foam via pre-foaming method, which is then incorporated into geopolymer based on fly ash and ladle furnace slag. In the literature, only PAS-geopolymer foams made with single precursor were studied. Therefore, the performance of fly ash-slag blended geopolymer with and without PAS foam was investigated at 29–1000 °C. Unfoamed geopolymer (G-0) was prepared by a combination of sodium alkali, fly ash and slag. The PAS foam-to-paste ratio was set at 1.0 and 2.0 to prepare geopolymer foam (G-1 and G-2). Foamed geopolymer showed decreased compressive strength (25.1–32.0 MPa for G-1 and 21.5–36.2 MPa for G-2) compared to G-0 (36.9–43.1 MPa) at 29–1000 °C. Nevertheless, when compared to unheated samples, heated G-0 lost compressive strength by 8.7% up to 1000 °C, while the foamed geopolymer gained compressive strength by 68.5% up to 1000 °C. The thermal stability of foamed geopolymer was greatly improved due to the increased porosity, lower thermal conductivity, and incompact microstructure, which helped to reduce pressure during moisture evaporation and resulted in lessened deterioration.
Parametric Study and Optimization of End-Milling Operation of AISI 1522H Steel Using Definitive Screening Design and Multi-Criteria Decision-Making Approach
Authors: Abas Muhammad , Alkahtani Mohammed , Khalid Qazi Salman , Hussain Ghulam , Abidi Mustufa Haider , Buhl Johannes
Published: June 2022

End-milling operation of steel grade material is a challenging task as it is hard-to-cut material. Proper selection of cutting tools, cutting conditions, and cutting process parameters is important to improve productivity, surface quality, and tool life. Therefore, the present study investigated the end-milling operation of AISI 1522H steel grade under minimum-quantity lubrication (MQL) conditions using a novel blend of vegetable oils, namely canola and olive oil. Cutting process parameters considered were spindle speed (s), feed rate (f), depth of cut (d), width of cut (w), and cutting conditions (c), while responses were average surface roughness (Ra), cutting forces (Fc), tool wear (TW), and material removal rate (MRR). Experimental runs were designed based on the definitive screening design (DSD) method. Analysis of variance (ANOVA) results show that feed rate significantly affects all considered responses. Nonlinear prediction models were developed for each response variable, and their validity was also verified. Finally, multi-response optimization was performed using the combinative distance-based assessment (CODAS) method coupled with criteria importance through inter-criteria correlation (CRITIC). The optimized parameters found were: s = 1200 rpm, f = 320 mm/min, d = 0.6 mm, w = 8 mm, and c = 100 mL/h. Further, it was compared with other existing multi-response optimization methods and induced good results.
Optimizing the Thermomechanical Process of Nickel-Based ODS Superalloys by an Efficient Method
Authors: He Wuqiang , Liu Feng , Tan Liming , Tian Zhihui , Qin Zijun , Huang Lan , Xiao Xiangyou , Wang Guowei , Chen Pan , Liu Baogang
Published: June 2022

Thermo-mechanical process of nickel-based oxide dispersion strengthened (ODS) superalloys is critical to produce desired components. In this study, an efficient method of consolidating powder is introduced to optimize the preparation process, microstructure and properties of nickel-based ODS superalloys. The influences of consolidation temperature, strain rate and ball milling time on the hardness of nickel-based superalloys were studied. The relationship among process, microstructure and hardness was established, the nanoparticles strengthening and grain boundary strengthening in nickel-based ODS superalloys were discussed. The results indicate that long ball milling time, moderately low consolidation temperature and high strain rates are beneficial to improving properties of nickel-based superalloys. Moreover, dispersion strengthening of nanoparticles and grain boundary strengthening play important roles in enhancing nickel-based ODS superalloys.
Effect of Annealing Heat Treatment on the Composition, Morphology, Structure and Mechanical Properties of the W-S-N Coatings
Authors: Yaqub Talha Bin , Al-Rjoub Abbas , Khalid Hafiza Ayesha , Yaqoob Khurram , Fernandes Filipe , Cavaleiro Albano
Published: June 2022

Alloyed-transition metal dichalcogenide (TMD) coatings have been under investigation as multi-environment lubricants for the past few decades. These coatings display very low coefficient of friction properties at elevated temperatures. Studies on the annealing of these low-friction coatings are missing in the literature. For the first time, in this study, the annealing of the W-S-N dry lubricant coatings was carried out to study its effects on the composition, morphology, crystal structure and hardness of the coatings. The W-S-N coatings were deposited by direct current (DC) reactive magnetron sputtering. The analysis was carried out for as-deposited, 200 °C and 400 °C annealed coatings. The as-deposited coatings have N content in the range of 0–25.5 at. %. The coatings are compact and the densification increased with the increase in N-alloying. All the coatings are crystalline except the highest N-alloyed coating which is X-ray amorphous. A maximum hardness of 8.0 GPa was measured for the coating alloyed with 23 at. % N. Annealing did not affect the composition and morphology of the coatings, while some variations were observed in their crystal structure and hardness. The maximum hardness increased from 8 GPa to 9.2 GPa after 400 °C annealing of the 23 at. % N-alloyed coating.
Corrosion Resistance of L120G13 Steel Castings Zone-Reinforced with Al2O3
Authors: Medyński Daniel , Chęcmanowski Jacek
Published: June 2022

The aim of the study was to determine the effect of zone reinforcement of cast steel L120G13 with Al2O3 macro-particles on the corrosion resistance of the composite obtained in this way. The obtained results allow us to conclude that strengthening of cast steel with corundum, the aim of which was to significantly increase the abrasive wear resistance, did not significantly deteriorate corrosion resistance. SEM tests show that a permanent diffusion layer interface is formed at the boundary between cast steel and corundum. In this area, simple manganese segregation and reverse iron and chromium segregation were found. These elements pass from the liquid alloy to the surface layer of the corundum particles, causing the aluminium and oxygen to be pushed deep into the corundum grains. Corrosion tests indicate comparable corrosion resistance of cast steel L120G13 and the composite L120G13 + Al2O3. Moreover, no intergranular corrosion was found in the matrix of the composite and no signs of pitting corrosion were found in the areas of the interface between the phases of the composite. This information is extremely important from the point of view of the material’s service life. Observations of breakthrough of both materials obtained during fracture after potentiodynamic corrosion tests, immediately after freezing in liquid nitrogen, indicate cracking with plastic features and increased resistance to dynamic forces of cast steel L120G13 and the composite L120G13 + Al2O3.
Conventional Meso-Scale and Time-Efficient Sub-Track-Scale Thermomechanical Model for Directed Energy Deposition
Authors: Nain Vaibhav , Engel Thierry , Carin Muriel , Boisselier Didier
Published: June 2022

Thermally-induced distortion and residual stresses in parts fabricated by the additive manufacturing (AM) process can lead to part rejection and failure. Still, the understanding of thermo–mechanical behavior induced due to the process physics in AM process is a complex task that depends upon process and material parameters. In this work, a 3D thermo-elasto-plastic model is proposed to predict the thermo–mechanical behavior (thermal and distortion field) in the laser-directed energy deposition (LDED) process using the finite element method (FEM). The predicted thermo–mechanical responses are compared to stainless steel 316L (SS 316L) deposition, with single and double bead 42-layer wall samples subject to different inter-layer dwell times, which govern the thermal response of deposited parts in LDED. In this work, the inter-layer dwell times used in experiments vary from 0 to 10 s. Based on past research into the LDED process, it is assumed that fusion and thermal cycle-induced annealing leads to stress relaxation in the material, and is accounted for in the model by instantaneously removing stresses beyond an inversely calibrated relaxation temperature. The model predicts that, for SS 316L, an increase in dwell time leads to a decrease in in situ and post-process distortion values. Moreover, increasing the number of beads leads to an increase in in situ and post-process distortion values. The calibrated numerical model’s predictions are accurate when compared with in situ and post-process experimental measurements. Finally, an elongated ellipsoid heat source model is proposed to speed up the simulation.
Effect of Magnesium Powder Application on the Microstructure and Properties of Rods Extruded by the Forward-Backward Rotating Die Extrusion Method
Authors: Olszówka-Myalska Anita , Wrześniowski Patryk , Ostachowski Paweł , Godzierz Marcin , Kuc Dariusz
Published: June 2022

The effects of severe plastic deformation (SPD) with a forward-backward rotating die (KOBO extrusion) on pure magnesium, in the form of cold-compacted powder, sintered powder, or cast ingots as reference, were examined. This method is known to reinforce metals, but the role of the initial form of magnesium applied in the fabrication of metal-based rods, as well as related phenomena, has not been characterized until now. The problem is important in the potential processing of commercial metal powders, the recycling of metal shavings, and the fabrication of metal matrix composites with discontinuous reinforcing phases. In the presented experiments, rods of 8 mm in diameter and 400 mm in length were obtained, and the structural effects induced by KOBO that occurred on a macro- and microscale on the surface and cross sections were characterized. Changes in the size and orientation of α-Mg crystallites were determined by XRD. The porosity, hardness, tensile strength, and compressive strength were measured, and the mechanisms of decohesion dependent on starting metal form were analyzed. After KOBO extrusion, significant differences were observed in the microstructure and properties between the materials derived from cold-compacted powder, sintered powder, and reference cast magnesium. Due to the application of KOBO, apart from α-Mg grain refinement, the MgO derived from the initial powder’s surface was refined to fine regular particles surrounded by magnesium. Their bands curved in the perpendicular plane and were oriented with the extrusion direction of the formed network, which augmented some mechanical properties and changed the decohesion mechanism. The conducted experiments revealed that before extrusion by KOBO, the magnesium powder required sintering under pressure.
Investigation of Electrical Transitions in the First Steps of Spark Plasma Sintering: Effects of Pre-Oxidation and Mechanical Loading within Copper Granular Media
Authors: Aliouat Anis , Antou Guy , Rat Vincent , Pradeilles Nicolas , Geffroy Pierre -Marie , Maître Alexandre
Published: June 2022

Spark Plasma Sintering (SPS) has become a conventional and promising sintering method for powder consolidation. This study aims to well understand the mechanisms of densification encountered during SPS treatments, especially in the early stages of sintering. The direct current (DC) electrical behavior of copper granular medium is characterized. Their properties are correlated with their microstructural evolutions through post-mortem scanning electron microscope (SEM) observations to allow a thorough understanding of the involved Branly effect that is suspected to occur in SPS. The electrical response is studied by modifying the initial thickness of the oxide layer on particles surfaces and applying various mechanical loads on the granular medium. Without load and at low current, the measured quasi-reversible behavior is connected to the formation of spots at the microcontacts between the particles. By increasing the current, the Branly transition from an insulating to a conductive state suddenly occurs. The insulating oxide layer is destroyed, and micro-bridges are created. The application of a mechanical pressure strongly modifies the DC Branly effect. Increasing low stress leads to a strong decrease in the breakdown field. For high-applied pressure, successive drops in the electric field are detected during the electrical transition. These successive drops are induced by microcracking of the insulating oxide layer.
Production of Synthetic Lightweight Aggregates from Industrial Sludge
Authors: Chen How-Ji , Chen Pen-Chou , Peng Ching-Fang , Huang Chien-Wei
Published: June 2022

Industrial sludge continues to increase in quantity with the development of industry. Therefore, how to effectively treat industrial sludge continues to be an environmental focus around the world. Due to the high calorie content of industrial sludge in Taiwan, most of the sludge is incinerated for simplicity and convenience. However, this incineration causes environmental pollution and cannot effectively reuse the industrial sludge. In this study, we investigated the feasibility of lightweight aggregates produced from water treatment sludge (WTS) mixed with industrial sludge. The industrial sludge was obtained from three industrial zones in Taiwan. The lightweight aggregate materials were prepared by mixing WTS with 7.5%, 15.0%, or 22.5% of industrial sludge as a secondary ingredient. The chemical composition analyses revealed that the ternary phase diagrams of the chemical components were within the range recommended by C.M. Moreover, Riley indicated that the ingredients could expand. The sintering experiments were conducted in two stages. Stage I served to determine the optimal sintering temperature, while Stage II produced lightweight aggregates at the optimal sintering temperatures after 5, 10, or 15 min of preheating. The results indicated that an increase in preheating time increased the particle density of the lightweight aggregates but decreased the water absorption ratio, because increasing preheating time causes more gases to escape, resulting in aggregates that could not produce sufficient gas to support expansion during the sintering stage. The sintering results of the lightweight aggregates showed that their particle density was between 0.5 and 1.4 g/cm3, which met the requirements of the specification. Their water absorption rate was below 21%, which was roughly in line with the recommendations of the specification. When the amount of industrial sludge added was less than 22.5%, the lightweight aggregate was sintered successfully, which is suitable for engineering applications. The industrial sludge experienced a loss of between 50% and 70% on ignition, resulting in pores and cracks that were observed on the surfaces of the lightweight aggregate. Based on the energy required to sinter lightweight aggregates, a greater loss on ignition indicates the conversion of more materials into heat energy. Therefore, the use of industrial sludge in lightweight aggregates not only provides ways to reuse industrial sewage waste but also reduces the consumption requirements for sintering lightweight aggregates, thereby achieving energy-saving and carbon-reduction goals.
A New Wire Electrode for Improving the Machining Characteristics of High-Volume Fraction SiCp/Al Composite in WEDM
Authors: Chen Zhi , Zhou Hongbing , Wu Cheng , Zhang Guojun , Yan Hongzhi
Published: June 2022

In wire electrical discharge machining, due to the random distribution of the insulating SiC particles, frequent wire rupture, low machining efficiency and surface quality when the common brass wire electrode (BWE) is used to process high-volume content SiCp/Al composite often appears. To address this issue, this paper proposes a new preparation method of zinc coating and surface microstructure on wire electrodes (ZCSMWE). The preparation process of ZCSMWE includes casting, coating, annealing and plastic processing. The experimental results show that, compared with BWE, ZCSMWE can increase material removal rate (MRR) by 16.67%, reduce surface roughness (Ra) by 21.18% and reduce wire rupture under the same discharge parameters. The analysis of workpiece surface topography shows that ZCSMWE can significantly decrease the recast layer and microcrack on the machined surface. The improvement mechanism of ZCSMWE main includes: The low work function zinc can promote the forming of the discharge channel. The vaporization of low boiling temperature zinc can reduce the temperature of the discharge gap and promote the ejecting of workpiece material. In addition, the surface microstructure on ZCSMWE can make the discharge spark more uniformly distributed and increase the proportion of the effective discharge, which contributes to making the discharge crater on the workpiece and wire electrode shallower and more uniform. The surface microstructure on ZCSMWE can also effectively improve the dielectric circulation, which can promote discharge debris to be expelled out and reduce the temperature in the discharge gap. Then, the wire rupture and microcracks on the workpiece surface can be reduced.
Study on Characteristics of the Light-Initiated High Explosive-Based Pulse Laser Initiation
Authors: Wang Dengwang , Li Jinglun , Zhang Yunfeng , Li Hao , Wang Sheng
Published: June 2022

The silver acetylene silver nitrate loading technology of the light initiated high explosive, as one of important means to simulate the structural response of powerful pulsed X-ray, adopts the pulse laser initiation. It has advantages of improvement of practical control, heterogenous loading realization and simultaneous loading timeliness. In this paper, the physical and mathematical models of hot spot initiation and photochemical initiation of energetic materials under the action of laser are firstly established, and then the laser initiation mechanism of the light initiated high explosive is specifically analyzed, and the laser initiation experiment is conducted based on the optical adsorption property of the light initiated high explosive. From this study, the laser initiation thresholds of 193 nm, 266 nm, 532 nm, 1064 nm wavelengths are given, and they are 5.07 mJ/mm2, 6.77 mJ/mm2, 7.21 mJ/mm2 and 10.61 mJ/mm2, respectively, and the complete detonation process is verified by detonation velocity. This work technically supports the study of pulse laser initiation process, mechanism and explosion loading rule as well as the loading technology of the light initiated high explosive to simulate the structural response of X ray.
Study on the Conventional Performance and Microscopic Properties of PPA/SBS-Modified Bio-Mixed Asphalt
Authors: Liu Guiyong , Zhang Wei , Yang Xiaolong , Ning Zhikang
Published: June 2022

To promote the construction of environmentally friendly, sustainable pavements and solve the impact of the scarcity of asphalt resources on highway development, bio-mixed asphalt (BMA) modified by SBS and polyphosphoric acid (PPA) was prepared, and the influence of the ratio of bio-asphalt (BA) replacing petroleum asphalt on different PPA/SBS blending schemes was explored through conventional property tests. According to each PPA/SBS blending scheme, the optimal replacement ratio of bio-asphalt was optimized, and the microstructure and distribution morphology of different PPA/SBS-modified BMA were evaluated. Conventional property test results show that with the same PPA/SBS content, the replacement ratio of bio-asphalt has a significant impact on the conventional performance of composite-modified asphalt, but the appropriate replacement ratio of bio-asphalt can improve the storage stability and conventional performance of composite-modified asphalt; in micromorphological analysis, it was found that the number of bee-like structures on the surface of the modified BMA decreased significantly, which indicated that the molecular heterogeneity of various components in the asphalt was reduced. In addition, bio-asphalt changed the particle morphology and improved the dispersity of SBS in asphalt. The composite-modified BMA had a lower SBS content, but its conventional performance was still excellent—so it has significant application prospects in road engineering.
Numerical Model for Flexural Analysis of Precast Segmental Concrete Beam with Internal Unbonded CFRP Tendons
Authors: Yan Wutong , Chen Liangjiang , Han Bing , Xie Huibing , Sun Yue
Published: June 2022

A new construction scheme was recently developed for precast segmental concrete beams by replacing steel tendons with internal unbonded carbon-fiber-reinforced polymer tendons. The discontinuous behaviors of the opening joints and unbonded phenomenon of tendons made their flexural behaviors more complicated than those of monolithic beams and members with bonded tendons. Currently, the knowledge on the structural performance of precast segmental concrete beams with internal unbonded carbon-fiber-reinforced polymer tendons is still limited. An efficient numerical model is urgently needed for the structural analysis and performance evaluation of this new construction scheme. In this paper, a new beam–cable hybrid model was proposed accounting for the mechanical behaviors of open joints and unbonded tendons. The numerical model was implemented in the OpenSees software with the proposed modeling method for joint elements and a newly developed element class for internal unbonded tendons. The effectiveness of the proposed model was verified by comparisons against two simply supported experimental tests. Then, the numerical model was employed to evaluate the flexural performance of a full-scale bridge with a span of 37.5 m. Compared with the precast segmental concrete beam with external steel tendons, the scheme with internal unbonded carbon-fiber-reinforced polymer tendons significantly improved the flexural capacity and ductility by almost 54.6% and 8.9%, respectively. The span-to-depth ratio and prestressing reinforcement ratio were the main factors affecting the flexural behaviors. With the span-to-depth ratio increasing by 23%, the flexural capacity decreased by approximately 38.6% and the tendon stress increment decreased by approximately 15.7%. With the prestressing reinforcement ratio increasing by 65.4%, the flexural capacity increased by 88.7% and the tendon stress increment decreased by approximately 25.2%.
A Review of Irradiation Damage and Effects in α-Uranium
Authors: Seshadri Arunkumar , Jokisaari Andrea M. , Sun Cheng
Published: June 2022

Understanding irradiation damage and effects in α-uranium (α-U) is critical to modeling the behavior of U-based metallic fuels. The aim of this review is to address the renewed interest in U-based metallic fuels by examining the state-of-the-art knowledge associated with the effect of irradiation on the microstructure, dimensional changes, and properties of α-U. We critically review the research progress on irradiation-induced growth and swelling, the enhancement of plastic flow and superplasticity by irradiation, and the effect of irradiation on thermal and electrical properties of α-U. Finally, we outline the research directions that require advancements, specifically the need to carry out fundamental research on several of the less understood mechanisms of irradiation damage and effects in α-U.
First-Principles Study of Silicon–Tin Alloys as a High-Temperature Thermoelectric Material
Authors: Huang Shan , Ning Suiting , Xiong Rui
Published: June 2022

Silicon–germanium (SiGe) alloys have sparked a great deal of attention due to their exceptional high-temperature thermoelectric properties. Significant effort has been expended in the quest for high-temperature thermoelectric materials. Combining density functional theory and electron–phonon coupling theory, it was discovered that silicon–tin (SiSn) alloys have remarkable high-temperature thermoelectric performance. SiSn alloys have a figure of merit above 2.0 at 800 K, resulting from their high conduction band convergence and low lattice thermal conductivity. Further evaluations reveal that Si0.75Sn0.25 is the best choice for developing the optimum ratio as a thermoelectric material. These findings will provide a basis for further studies on SiSn alloys as a potential new class of high-performance thermoelectric materials.
Exploring the Use of Waste Marble Powder in Concrete and Predicting Its Strength with Different Advanced Algorithms
Authors: Khan Kaffayatullah , Ahmad Waqas , Amin Muhammad Nasir , Ahmad Ayaz , Nazar Sohaib , Alabdullah Anas Abdulalim , Arab Abdullah Mohammad Abu
Published: June 2022

Recently, the high demand for marble stones has progressed in the construction industry, ultimately resulting in waste marble production. Thus, environmental degradation is unavoidable because of waste generated from quarry drilling, cutting, and blasting methods. Marble waste is produced in an enormous amount in the form of odd blocks and unwanted rock fragments. Absence of a systematic way to dispose of these marble waste massive mounds results in environmental pollution and landfills. To reduce this risk, an effort has been made for the incorporation of waste marble powder into concrete for sustainable construction. Different proportions of marble powder are considered as a partial substitute in concrete. A total of 40 mixes are prepared. The effectiveness of marble in concrete is assessed by comparing the compressive strength with the plain mix. Supervised machine learning algorithms, bagging (Bg), random forest (RF), AdaBoost (AdB), and decision tree (DT) are used in this study to forecast the compressive strength of waste marble powder concrete. The models’ performance is evaluated using correlation coefficient (R2), root mean square error, and mean absolute error and mean square error. The achieved performance is then validated by using the k-fold cross-validation technique. The RF model, having an R2 value of 0.97, has more accurate prediction results than Bg, AdB, and DT models. The higher R2 values and lesser error (RMSE, MAE, and MSE) values are the indicators for better performance of RF model among all individual and ensemble models. The implementation of machine learning techniques for predicting the mechanical properties of concrete would be a practical addition to the civil engineering domain by saving effort, resources, and time.
Biodegradation of a Magnesium Alloy Fixation Screw Used in a Guided Bone Regeneration Model in Beagle Dogs
Authors: Rider Patrick , Kačarević Željka Perić , Elad Akiva , Rothamel Daniel , Sauer Gerrit , Bornert Fabien , Windisch Peter , Hangyási Dávid , Molnar Balint , Hesse Bernhard , Assad Michel , Witte Frank
Published: June 2022

Nowadays, the most commonly used fixation systems are non-resorbable, but new resorbable magnesium alloy fixation screws have been introduced recently. Therefore, the aim of this study was to compare the magnesium fixation screw and the commonly used non-resorbable titanium screw in an animal model. Four 3-wall defect sites were covered with collagen membranes in the mandible of twenty beagle dogs (two sites on the left and two on the right). Each membrane was fixed with either four magnesium screws or four titanium screws. Post-operative follow-up revealed the expected observations such as transient inflammation and pain. Both groups showed a good healing response, with no differences between groups. Micro-CT analysis showed no significant difference between groups in terms of BV/TV or soft tissue volume. The void volume in the magnesium fixation screw group continued to decrease on average between the different timepoints, but not significantly. Furthermore, a gradual progression of the degradation process of the magnesium screws was observed in the same group. Magnesium screws and titanium screws showed equal performance in tissue regeneration according to GBR principles. An additional advantage of magnesium screws is their resorbable nature, which eliminates the need for a second surgical step to remove the screws.
Influence of Sample Wetting Method on ESC-Behavior of PMMA under Dynamic Fatigue Crack Propagation
Authors: Bubmann Tobias , Shi Simon , Brueckner Alexander , Menzel Teresa , Ruckdäschel Holger , Schlarb Alois K. , Altstädt Volker
Published: June 2022

Environmental stress cracking (ESC) is one of the most prominent failure mechanisms for polymer components. The high sensitivity of plastics in regard to environmental influences has always meant that plastics as materials have been viewed very critically in outdoor applications. Recently, the massive occurrence of microplastics in the environment means that questions about the long-term stability of plastic parts and the studies of plastic fragmentation are of great scientific interest. ESC behavior also plays an important role in connection with the formation of microplastics. In this work, the influence of two different sample wetting methods on ESC behavior was investigated. In case A, the sample was in situ wetted with the medium during the measurement by using a sponge. In case B, the sample was wetted by storage in the medium prior to measurement. Different stress cracking agents (SCA) were examined for polymethylmethacrylate (PMMA). Fracture-mechanical fatigue crack propagation (FCP) tests were carried out to quantitatively determine the sensitivity to ESC. Correlations between the absorption behavior and the ESC behavior of the SCA and the resulting morphological phenomena were established. Depending on the wetting method, significant differences in FCP were observed. The in situ wetting of the samples (case A) during the FCP measurement with ethylene glycol (EG) and with deionized water (DI) led to a significant shift in the crack propagation curves to higher ∆K—compared to the PMMA reference. In the case of n-heptane (NH), a more brittle crack propagation behavior was observed due to the chemical interaction with PMMA. The previously immersed samples (case B) give different results. Storage in NH and EG showed no influence on the crack propagation behavior. Samples immersed in DI showed a completely different course of crack growth. At a certain load, a sudden deceleration of the crack propagation and thus a horizontal curve could be seen. Above a certain ∆K value, crack growth began again. Depending on the immersion time (14, 30, or 60 days), this so-called stepped behavior shifted to lower da/dN values.
Comparison of Constitutive Models and Microstructure Evolution of GW103K Magnesium Alloy during Hot Deformation
Authors: Yin Lan , Wu Yunxin
Published: June 2022

The characteristics of constitutive behavior and microstructure evolution of GW103K magnesium alloy were investigated via hot compression tests at a strain rate of 0.001–1 s−1 and a temperature of 623–773 K. The rheological stress of GW103K alloy decreased with increasing temperature or decreasing strain rate during hot deformation. Three models including the Johnson Cook (JC) model, the strain-compensated Arrhenius (SCA) model and back-propagation neural networks (BPNN) were applied to describe the constitutive relationships. Subsequently, the predictability and precision of the models were compared by evaluating the correlation coefficient (R), root mean square errors (RMSE), and relative errors (RE). Compared with the JC and SCA models, the BPNN model was more efficient and had higher prediction accuracy in describing flow stress behavior. Furthermore, EBSD maps confirmed that magnesium alloy easily causes dynamic recrystallization (DRX) during hot deformation. The volume fraction and size of DRX grains increased with decreasing strain rate and/or increasing temperature.
Lightweight Design of Variable-Stiffness Cylinders with Reduced Imperfection Sensitivity Enabled by Continuous Tow Shearing and Machine Learning
Authors: dos Santos Rogério R. , Castro Saullo G. P.
Published: June 2022

The present study investigates how to apply continuous tow shearing (CTS) in a manufacturable design parameterization to obtain reduced imperfection sensitivity in lightweight, cylindrical shell designs. The asymptotic nonlinear method developed by Koiter is applied to predict the post-buckled stiffness, whose index is constrained to be positive in the optimal design, together with a minimum design load. The performance of three machine learning methods, namely, Support Vector Machine, Kriging, and Random Forest, are compared as drivers to the optimization towards lightweight designs. The new methodology consists of contributions in the areas of problem modeling, the selection of machine learning strategies, and an optimization formulation that results in optimal designs around the compromise frontier between mass and stiffness. The proposed ML-based framework proved to be able to solve the inverse problem for which a target design load is given as input, returning as output lightweight designs with reduced imperfection sensitivity. The results obtained are compatible with the existing literature where hoop-oriented reinforcements were added to obtain reduced imperfection sensitivity in composite cylinders.
Role of Cr Doping on the Structure, Electronic Structure, and Electrochemical Properties of BiFeO3 Nanoparticles
Authors: Kumar Shalendra , Ahmed Faheem , Ahmad Naushad , Shaalan Nagih M. , Kumar Rajesh , Alshoaibi Adil , Arshi Nishat , Dalela Saurabh , Albossed Mohammed , Chae Keun Hwa , Alvi Parvez Ahmad , Kumari Kavita
Published: June 2022

BiFe1−xCrxO3, (0 ≤ x ≤ 10) nanoparticles were prepared through the sol–gel technique. The synthesized nanoparticles were characterized using various techniques, viz., X-ray diffraction, high-resolution field emission scanning electron microscopy (HRFESEM), energy dispersive spectroscopy (EDS), UV–Vis absorption spectroscopy, photoluminescence (PL), dc magnetization, near-edge X-ray absorption spectroscopy (NEXAFS) and cyclic voltammetry (CV) measurements, to investigate the structural, morphological, optical, magnetic and electrochemical properties. The structural analysis showed the formation of BiFeO3 with rhombohedral (R3c) as the primary phase and Bi25FeO39 as the secondary phase. The secondary phase percentage was found to reduce with increasing Cr content, along with reductions in crystallite sizes, lattice parameters and enhancement in strain. Nearly spherical shape morphology was observed via HRFESEM with Bi, Fe, Cr and O as the major contributing elements. The bandgap reduced from 1.91 to 1.74 eV with the increase in Cr concentration, and PL spectra revealed emissions in violet, blue and green regions. The investigation of magnetic field (H)-dependent magnetization (M) indicated a significant effect of Cr substitution on the magnetic properties of the nanoparticles. The ferromagnetic character of the samples was found to increase with the increase in the Cr concentration and the increase in the saturation magnetization. The Fe (+3/+4) was dissolved in mixed-valence states, as found through NEXAFS analysis. Electrochemical studies showed that 5%-Cr-doped BFO electrode demonstrated outstanding performance for supercapacitors through a specific capacitance of 421 F g−1 measured with a scan rate of 10 mV s−1. It also demonstrated remarkable cyclic stability through capacitance retention of >78% for 2000 cycles.
Theoretical Prediction of the Monolayer Hf2Br4 as Promising Thermoelectric Material
Authors: Fan Qiang , Yang Jianhui , Wang Ning
Published: June 2022

The stability, electronic structure, electric transport, thermal transport and thermoelectric properties of the monolayer Hf2Br4 are predicted by using first principle calculations combined with Boltzmann transport theory. The dynamic stability of the monolayer Hf2Br4 is verified by phonon band dispersion, and the thermal stability is revealed by ab initio molecular dynamics simulations. The electronic structure calculation indicates that the monolayer Hf2Br4 is an indirect band gap semiconductor with a band gap of 1.31 eV. The lattice thermal conductivity of the monolayer Hf2Br4 is investigated and analyzed on phonon mode level. The calculation results of the electric transport explore the excellent electric transport properties of the monolayer Hf2Br4. The thermoelectric transport properties as a function of carrier concentration at three different temperatures are calculated. The study indicates that the monolayer Hf2Br4 can be an alternative, stable two-dimensional material with potential application in the thermoelectric field.
Structure, Mechanical and Magnetic Properties of Selective Laser Melted Fe-Si-B Alloy
Authors: Sufiiarov Vadim , Erutin Danil , Kantyukov Artem , Borisov Evgenii , Popovich Anatoly , Nazarov Denis
Published: June 2022

Original 1CP powder was studied and it was founded that powder material partially consists of the amorphous phase, in which crystallization begins at 450 °C and ends at 575 °C. Selective laser melting parameters were investigated through the track study, and more suitable ones were found: laser power P = 90, 120 W; scanning speed V = 1200 mm/s. Crack-free columnar elements were obtained. The sample obtained with P = 90 W, contains a small amount of amorphous phase. X-ray diffraction of samples shows the presence of α-Fe(Si) and Fe2B. SEM-image analysis shows the presence of ordered Fe3Si in both samples. Annealed samples show 40% less microhardness; an annealed sample containing amorphous phase shows higher soft-magnetic properties: 2.5% higher saturation magnetization, 35% higher residual magnetization and 30% higher rectangularity coefficient.