bluuebunny/crossref_metadata_2025 huggingface dataset:
Religious Coping and Life Satisfaction during the COVID-19 Pandemic among Polish Catholics. The Mediating Effect of Coronavirus Anxiety
Authors: Dobrakowski Paweł Piotr , Skalski Sebastian , Surzykiewicz Janusz , Muszyńska Jolanta , Konaszewski Karol
Published: October 2021

Recent data have indicated that people may have experienced fear during the COVID-19 pandemic. This study aims to deepen our understanding of the relationship between religious coping and life satisfaction by analysing the indirect effects of fear of COVID-19. Methods: This study included 365 people (75% women) aged 18–78 years. The procedure consisted of completing questionnaires to measure religious coping, COVID-19 anxiety, satisfaction with life, and satisfaction with social support. Results: Structural equation modelling showed that positive religious coping was related to greater life satisfaction and greater satisfaction with social support during the pandemic. Moreover, fear of COVID-19 mediated the relationship between negative religious coping and life satisfaction and social support satisfaction. Conclusions: The data suggest a need for practitioners to focus on interventions that enhance positive religious coping to improve life satisfaction during the spread of infectious diseases.
Exploring the Social Networks of Women Bereaved by Stillbirth: A Descriptive Qualitative Study
Authors: Popoola Tosin , Skinner Joan , Woods Martin
Published: October 2021

The loss of a baby to stillbirth is a traumatic experience and can lead to secondary losses, such as the loss of social relationships. In Nigeria, stillbirths are a common public health problem. However, limited attention has been given to the social ramifications of stillbirths. This study describes the social networks of women who have experienced a stillbirth and the factors influencing their social networks. Interviews and social network diagrams were used to collect data from 20 women about their social networks before and after stillbirth. Findings suggest that the experience of shame, unmet expectation of support, and a lack of trust led to relationship changes after stillbirth. Most participants met bereavement needs with their existing social networks before stillbirth, but many participants also experienced relationship losses (even among family networks). Information from social network analysis can reveal the risks and strengths inherent in social networks, which can be helpful for the provision of tailored/personalized bereavement care.
Identification of Rare Mutations of Two Presynaptic Cytomatrix Genes BSN and PCLO in Schizophrenia and Bipolar Disorder
Authors: Chen Chia-Hsiang , Huang Yu-Shu , Liao Ding-Lieh , Huang Cheng-Yi , Lin Chia-Heng , Fang Ting-Hsuan
Published: October 2021

Schizophrenia and bipolar disorder are severe mental disorders with a major component of genetic factors in their etiology. Rare mutations play a significant role in these two disorders, and they are highly heterogeneous and personalized. Identification of personalized mutations is essential for the establishment of molecular diagnosis, providing insight into pathogenesis and guiding the personalized treatment for each affected patient. We conducted whole-genome sequencing analysis of families with schizophrenia and bipolar disorder to search for their genetic underpinnings. This report identified a rare missense mutation Arg1087Gln of BSN (bassoon presynaptic cytomatrix protein) co-segregating with schizophrenia in a family with multiple affected members. Furthermore, we identified the rare missense mutation Ser1535Leu of PCLO (piccolo presynaptic cytomatrix protein) in two sisters with bipolar disorder and another rare missense mutation, His5142Arg in PCLO, in a patient with schizophrenia. These three missense mutations were very rare and were predicted to be pathogenic. The BSN and PCLO genes encode two structurally related proteins of the presynaptic cytomatrix at the active zone that regulates neurotransmission at the presynaptic neuronal terminal. Our findings suggest the involvement of the presynaptic matrix in the pathogenesis of schizophrenia and bipolar disorder, and BSN and PCLO are the risk genes for schizophrenia and bipolar disorder.
Influence of Smallanthus sonchifolius (Yacon) on the Activity of Antidepressant Drugs in Mice
Authors: Wośko Sylwia , Serefko Anna , Szopa Aleksandra , Kardaś Sylwia , Widelski Jarosław , Mroczek Tomasz , Rostkowska Ewelina , Szymańska Jolanta , Poleszak Ewa
Published: October 2021

Depression is one of the most common mental disorders in the world that negatively affects the daily functioning of patients. Numerous studies are currently being conducted to examine the antidepressant potential of innovative synthetic compounds and herbal substances. Yacon, Smallantchus sonchifolius, belongs to plants with numerous health-beneficial properties. Yacon-based products are regarded as a functional food. In our study, we attempted to check whether administration of Yacon tuber extract would have an antidepressant effect in the forced swim test (FST) in mice and whether its intake could influence the activity of conventional antidepressant drugs with different mechanisms of action, i.e., imipramine hydrochloride, fluoxetine hydrochloride, and reboxetine mesylate. The spontaneous locomotor activity of the tested mice was also investigated to eliminate any false-positive results. We demonstrated that an intragastric administration of the Yacon tuber extract at a dose of 100 mg/kg induced the antidepressant-like behavior in the FST in mice and that a combined administration of the sub-effective doses of the Yacon extract (50 mg/kg) with imipramine hydrochloride (7.5 mg/kg), fluoxetine hydrochloride (20 mg/kg), or reboxetine mesylate (5 mg/kg) significantly reduced the immobility time of animals in this behavioral test. The obtained results were not affected by the increased locomotor activity of the tested subjects. In conclusion, our findings suggest that Yacon tuber extract is promising as an alternative mood-improving product since it possesses an antidepressant potential and it can acts synergistically with conventional antidepressant drugs.
Metabolism in Retinopathy of Prematurity
Authors: Tomita Yohei , Usui-Ouchi Ayumi , Nilsson Anders K. , Yang Jay , Ko Minji , Hellström Ann , Fu Zhongjie
Published: October 2021

Retinopathy of prematurity is defined as retinal abnormalities that occur during development as a consequence of disturbed oxygen conditions and nutrient supply after preterm birth. Both neuronal maturation and retinal vascularization are impaired, leading to the compensatory but uncontrolled retinal neovessel growth. Current therapeutic interventions target the hypoxia-induced neovessels but negatively impact retinal neurons and normal vessels. Emerging evidence suggests that metabolic disturbance is a significant and underexplored risk factor in the disease pathogenesis. Hyperglycemia and dyslipidemia correlate with the retinal neurovascular dysfunction in infants born prematurely. Nutritional and hormonal supplementation relieve metabolic stress and improve retinal maturation. Here we focus on the mechanisms through which metabolism is involved in preterm-birth-related retinal disorder from clinical and experimental investigations. We will review and discuss potential therapeutic targets through the restoration of metabolic responses to prevent disease development and progression.
Morphology of Models Manufactured by SLM Technology and the Ti6Al4V Titanium Alloy Designed for Medical Applications
Authors: Gogolewski Damian , Kozior Tomasz , Zmarzły Paweł , Mathia Thomas G.
Published: October 2021

This paper presents the results of an experimental study to evaluate the possibility of using SLM additive technology to produce structures with specific surface morphological features. Qualitative and quantitative tests were conducted on samples fabricated by 3D printing from titanium (Ti6Al4V)-powder-based material and analysed in direct relation to the possibility of their use in medicine for the construction of femoral stem and models with a specific degree of porosity predicted by process-control in the self-decision-making 3D printing machine. This paper presents the results of the study, limitations of the method, recommendations that should be used in the design of finished products, and design proposals to support the fabrication process of 3D printers. Furthermore, the study contains an evaluation of how the printing direction affects the formation of certain structures on the printed surface. The research can be used in the development of 3D printing standardization, particularly in the consideration of process control and surface control.
Apical Extrusion of Debris during Root Canal Preparation with ProTaper Next, WaveOne Gold and Twisted Files
Authors: Eliasz Wojciech , Czarnecka Beata , Surdacka Anna
Published: October 2021

(1) Background: Apical extrusion of debris is an example of a complication that may arise during root canal treatment, and it has been proven to be an unavoidable occurrence during endodontic treatment by numerous authors. Even though it may not hinder the long-term outcome of treatment, it may lead directly to increased levels of postoperative pain and, therefore, lower levels of patient acceptance and satisfaction. The aim of the study was to assess the weight of apically extruded debris during root canal preparation with instruments that use different movement kinematics (rotary, reciprocating, and adaptive motion); (2) Methods: The study was performed using the Myers and Montgomery model. Sixty human premolar teeth were inserted into preweighed Eppendorf tubes and randomly classified into three groups. After manual glide-path preparation, teeth in each group were instrumented to working length set 1 mm short of the anatomical apex using the standard sequence provided by the manufacturers (for Group 1: ProTaper Next X1 & X2; for Group 2: WaveOne Gold Primary, for Group 3: Twisted Files SM1-SM3). Root canals were irrigated with 1 mL of 0.9% NaCl solution between each file insertion. The tubes with collected debris were stored in an incubator at 70 °C for 5 days in order to evaporate the liquid component. Measurement of the weight of extruded debris was performed by subtracting the preinstrumentation from the postinstrumentation weight of the tubes. The results were analyzed with Kruskal–Wallis ANOVA, with significance level set at 0.05; (3) Results: The weight of extruded debris was 0.337 mg (SD = 0.148) for Group 1, 0.305 mg (SD = 0.201) for Group 2, and 0.348 mg (SD = 0.135) for Group 3. (4) Conclusions: Engine-driven root canal preparation with the use of instruments ProTaper Next, WaveOne Gold and Twisted Files that use different movement kinematics (rotary, reciprocating, and adaptive motion) was associated with apical extrusion of debris to a similar extent.
Effect of Nanostructures on the Properties of Glass Ionomer Dental Restoratives/Cements: A Comprehensive Narrative Review
Authors: Amin Faiza , Rahman Sehrish , Khurshid Zohaib , Zafar Muhammad Sohail , Sefat Farshid , Kumar Naresh
Published: October 2021

Overall perspective of nanotechnology and reinforcement of dental biomaterials by nanoparticles has been reported in the literature. However, the literature regarding the reinforcement of dental biomaterials after incorporating various nanostructures is sparse. The present review addresses current developments of glass ionomer cements (GICs) after incorporating various metallic, polymeric, inorganic and carbon-based nanostructures. In addition, types, applications, and implications of various nanostructures incorporated in GICs are discussed. Most of the attempts by researchers are based on the laboratory-based studies; hence, it warrants long-term clinical trials to aid the development of suitable materials for the load bearing posterior dentition. Nevertheless, a few meaningful conclusions are drawn from this substantial piece of work; they are as follows: (1) most of the nanostructures are likely to enhance the mechanical strength of GICs; (2) certain nanostructures improve the antibacterial activity of GICs against the cariogenic bacteria; (3) clinical translation of these promising outcomes are completely missing, and (4) the nanostructured modified GICs could perform better than their conventional counterparts in the load bearing posterior dentition.
Special Issue: The Science and Technology of 3D Printing
Authors: Mukherjee Tuhin
Published: October 2021

Additive manufacturing, commonly known as three-dimensional printing (3D printing), is becoming an increasingly popular method for making components that are difficult to fabricate using traditional manufacturing processes [...]
Performance of Concrete Mixes Containing TBM Muck as Partial Coarse Aggregate Replacements
Authors: Taqa Ala Abu , Al-Ansari Mohamed , Taha Ramzi , Senouci Ahmed , Al-Zubi Ghaleb M. , Mohsen Mohamed O.
Published: October 2021

This study investigated the potential utilization of the TBM muck obtained from the Gold Line of the Doha Metro Project as a partial replacement of coarse aggregates in concrete mixes. First, the TBM muck particles were screened to coarse aggregate standard sizes. Then, concrete mixes were prepared using 0%, 25%, 50%, and 75% TBM muck replacement of coarse aggregates. The compressive and flexural strengths were determined for all mixes at 28 and 56 days. Moreover, the results obtained were validated using EDX analysis and SEM images. A t-statistical analysis did not show a significant impact of TBM muck usage on the compressive strength results of the concrete mixes. However, another t-statistical analysis showed that TBM muck replacement of coarse aggregates had adversely affected the flexural strength results. The EDX analysis indicated the presence of Na+ ions, which can replace the Ca2+ ions in the C-S-H gel, cause discontinuities of it, and hence reduce the strength at later ages. Finally, the SEM images showed that the ettringite and carbon hydroxide (C-H) contents in the mixes with TBM muck were higher than that of the control mix, while the C-S-H gel was less in such mixes.
Analysis of the Failure Process of Elements Subjected to Monotonic and Cyclic Loading Using the Wierzbicki–Bai Model
Authors: Janus-Galkiewicz Urszula , Galkiewicz Jaroslaw
Published: October 2021

This article presents the results of a simulation in which smooth cylindrical and ring-notched samples were subjected to monotonic and fatigue loads in an ultra-short-life range, made of Inconel 718 super alloy. The samples displayed different behaviors as a result of different geometries that introduced varying levels of stress triaxiality and loading methods. The simulations used the Wierzbicki–Bai model, which took into account the influence of stress tensors and stress-deviator invariants on the behavior of the material. The difference in the behaviors of the smoothed and notched specimens subjected to tensile and fatigue loads were identified and described. The numerical results were qualitatively supported by the results of the experiments presented in the literature.
The Effect of Different Dietary and Therapeutic Solutions on the Color Stability of Resin-Matrix Composites Used in Dentistry: An In Vitro Study
Authors: Lopes-Rocha Lígia , Mendes José Manuel , Garcez Joana , Sá Ana Góis , Pinho Teresa , Souza Júlio C. M. , Torres Orlanda
Published: October 2021

The purpose of this study was to evaluate the color stability of aesthetic restorative resin-matrix materials after their immersion in different dietary and therapeutic solutions. Thirty disc-shaped specimens (10 × 2 mm) were prepared from three different types of resin-matrix composites used in dentistry (BE, FS, AF). The color coordinates (L*a*b*, ΔL*, Δa*, Δa*, Δb* and ΔE*) were measured using a VITA Easyshade 3D-Master (VITA Zahnfabrik, Bad Säckingen, Germany) before and after the immersion of the specimens in coffee, red wine, Coca-Cola®, Eludril Care®, and distilled water solutions for 40 h. The color change (ΔE*) was calculated and analyzed by the Kolmogorov -Smirnov test and the Kruskal -Wallis multiple-comparison test. All the restorative materials showed significant color (ΔE*) changes after their exposure to red wine, followed by coffee and Coca-Cola®; however, one nanohybrid resin-matrix composite showed a high color stability in such colored test solutions. The chemical composition and content of the organic matrix played a key role in the color stability of the resin-matrix composites. Clinicians should advise their patients about the chemical interaction between dietary substances and different resin-matrix composites.
Optical Quality of InAs/InP Quantum Dots on Distributed Bragg Reflector Emitting at 3rd Telecom Window Grown by Molecular Beam Epitaxy
Authors: Smołka Tristan , Posmyk Katarzyna , Wasiluk Maja , Wyborski Paweł , Gawełczyk Michał , Mrowiński Paweł , Mikulicz Monika , Zielińska Agata , Reithmaier Johann Peter , Musiał Anna , Benyoucef Mohamed
Published: October 2021

We present an experimental study on the optical quality of InAs/InP quantum dots (QDs). Investigated structures have application relevance due to emission in the 3rd telecommunication window. The nanostructures are grown by ripening-assisted molecular beam epitaxy. This leads to their unique properties, i.e., low spatial density and in-plane shape symmetry. These are advantageous for non-classical light generation for quantum technologies applications. As a measure of the internal quantum efficiency, the discrepancy between calculated and experimentally determined photon extraction efficiency is used. The investigated nanostructures exhibit close to ideal emission efficiency proving their high structural quality. The thermal stability of emission is investigated by means of microphotoluminescence. This allows to determine the maximal operation temperature of the device and reveal the main emission quenching channels. Emission quenching is predominantly caused by the transition of holes and electrons to higher QD’s levels. Additionally, these carriers could further leave the confinement potential via the dense ladder of QD states. Single QD emission is observed up to temperatures of about 100 K, comparable to the best results obtained for epitaxial QDs in this spectral range. The fundamental limit for the emission rate is the excitation radiative lifetime, which spreads from below 0.5 to almost 1.9 ns (GHz operation) without any clear spectral dispersion. Furthermore, carrier dynamics is also determined using time-correlated single-photon counting.
The Low-Cycle Fatigue Behavior, Failure Mechanism and Prediction of SLM Ti-6Al-4V Alloy with Different Heat Treatment Methods
Authors: Xi Jiangjing , Hu Yun , Xing Hui , Han Yuanfei , Zhang Haiying , Jiang Jun , Nikbin Kamran
Published: October 2021

Selective laser melting (SLM) is a promising additive manufacturing (AM) process for high-strength or high-manufacturing-cost metals such as Ti-6Al-4V widely applied in aeronautical industry components with high material waste or complex geometry. However, one of the main challenges of AM parts is the variability in fatigue properties. In this study, standard cyclic fatigue and monotonic tensile testing specimens were fabricated by SLM and subsequently heat treated using the standard heat treatment (HT) or hot isostatic pressing (HIP) methods. All the specimens were post-treated to relieve the residual stress and subsequently machined to the same surface finishing. These specimens were tested in the low-cycle fatigue (LCF) regime. The effects of post-process methods on the failure mechanisms were observed using scanning electron microscopy (SEM) and optical microscopy (OM) characterization methods. While the tensile test results showed that specimens with different post-process treatment methods have similar tensile strength, the LCF test revealed that no significant difference exists between HT and HIP specimens. Based on the results, critical factors influencing the LCF properties are discussed. Furthermore, a microstructure-based multistage fatigue model was employed to predict the LCF life. The results show good agreement with the experiment.
Preparation of Isotropic Carbon Fibers from Kerosene-Purified Coal Tar Pitch by Co-Carbonization with Pyrolysis Fuel Oil
Authors: Lee Seon Ho , Lee Song Mi , Park Seungjoo , Yoon Seong-Ho , Han Haksoo , Jung Doo-Hwan
Published: October 2021

An inexpensive and general-purpose carbon fiber was prepared using coal tar pitch. In contrast to the solvent extraction process employing expensive solvents, a low-cost centrifugal separation method facilitated the reduction of loss due to the pitch purification and an overall yield increase. The coal tar pitch purified by centrifugation and subsequently co-carbonized with pyrolysis fuel oil improved in spinnability. Moreover, the resulting spinnable pitch had a softening point of 250 °C. The obtained carbon fibers were heat-treated at 1000 °C for 5 min, resulting in a tensile strength of approximately 1000 MPa and an average diameter of 9 μm. In this study, we present an effective method for obtaining low-cost general-purpose isotropic carbon fibers.
Thermoplastic Intumescent Coatings Modified with Pentaerythritol-Occluded Carbon Nanotubes
Authors: Tomczak Michał , Łopiński Jakub , Kowalczyk Agnieszka , Kowalczyk Krzysztof
Published: October 2021

A thermoplastic intumescent coating system (IC) based on poly(vinyl acetate) was modified by two forms of multiwalled carbon nanotubes (CNTs), i.e., by a nanofiller powder and its solid dispersions in pentaerythritol (PER-CNTs). It was revealed that only the PER-CNTs modifier allows us to obtain solvent-borne ICs with a relatively high CNTs concentration (1–3 wt. parts of CNTs/100 wt. parts of paint solids) and acceptable application viscosity. Thermal insulation time (TIT) and intumescent factor (IF) of the ICs on a steel substrate (a fire test according to a cellulosic fire curve), as well as morphology, chemical structure (by the FT-IR technique) and mechanical strength of the charred systems, were investigated. It was found that the CNTs powder decreases TIT and IF values while PER-occluded CNTs improve these parameters (e.g., +4.6 min and +102% vs. an unmodified sample, respectively). Compressive strength of the charred ICs was improved by the PER-CNTs modifier as well.
New Organophilic Montmorillonites with Lactic Acid Oligomers and Other Environmentally Friendly Compounds and Their Effect on Mechanical Properties of Polylactide (PLA)
Authors: Rucińska Katarzyna , Florjańczyk Zbigniew , Dębowski Maciej , Gołofit Tomasz , Malinowski Rafał
Published: October 2021

New organophilic montmorillonites with oligomers of lactic acid and other compounds such as citric acid, stearic acid, maleic anhydride, pentaerythritol and ε-caprolactone were synthesized. They were characterized by Fourier Transform Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), Thermogravimetric Analysis (TGA), Scanning Electron Microscopy (SEM), elemental analysis and swelling capacity in water. In all tested composites, an increase in the montmorillonite interlayer distance resulting from intercalation of the modifying substance in the montmorillonite was found by means of XRD. Elemental analysis and FTIR showed that all of the tested samples contained an organic segment in the montmorillonite structure. TGA studies revealed that composites modified with lactic acid oligomers, stearic acid or ε-caprolactone had the highest thermal stability. They also exhibited the lowest swelling capacity which was 2–3 times lower than that for unmodified sodium montmorillonite. Some preliminary studies on the mechanical properties of PLA/modified montmorillonite are also presented and discussed.
On the Hardness and Elastic Modulus of Phases in SiC-Reinforced Al Composite: Role of La and Ce Addition
Authors: Du Andong , Lattanzi Lucia , Jarfors Anders Wollmar Eric , Zheng Jinchuan , Wang Kaikun , Yu Gegang
Published: October 2021

The use of silicon carbide particles (SiCp) as reinforcement in aluminium (Al)-based composites (Al/SiCp) can offer high hardness and high stiffness. The rare-earth elements like lanthanum (La) and cerium (Ce) and transition metals like nickel (Ni) and copper (Cu) were added into the matrix to form intermetallic phases; this is one way to improve the mechanical property of the composite at elevated temperatures. The α-Al15(Fe,Mn)3Si2, Al20(La,Ce)Ti2, and Al11(La,Ce)3, π-Al8FeMg3Si6 phases are formed. Nanoindentation was employed to measure the hardness and elastic modulus of the phases formed in the composite alloys. The rule of mixture was used to predict the modulus of the matrix alloys. The Halpin–Tsai model was applied to calculate the elastic modulus of the particle-reinforced composites. The transition metals (Ni and Cu) and rare-earth elements (La and Ce) determined a 5–15% increase of the elastic modulus of the matrix alloy. The SiC particles increased the elastic modulus of the matrix alloy by 10–15% in composite materials.
Energy Retention in Thin Graphite Targets after Energetic Ion Impact
Authors: Iveković Damjan , Žugec Petar , Karlušić Marko
Published: October 2021

High energy ion irradiation is an important tool for nanoscale modification of materials. In the case of thin targets and 2D materials, which these energetic ions can pierce through, nanoscale modifications such as production of nanopores can open up pathways for new applications. However, materials modifications can be hindered because of subsequent energy release via electron emission. In this work, we follow energy dissipation after the impact of an energetic ion in thin graphite target using Geant4 code. Presented results show that significant amount of energy can be released from the target. Especially for thin targets and highest ion energies, almost 40% of deposited energy has been released. Therefore, retention of deposited energy can be significantly altered and this can profoundly affect ion track formation in thin targets. This finding could also have broader implications for radiation hardness of other nanomaterials such as nanowires and nanoparticles.
Investigation and Optimization of Mxene Functionalized Mesoporous Titania Films as Efficient Photoelectrodes
Authors: Iqbal Anum , Hamdan Nasser M.
Published: October 2021

Three-dimensional mesoporous TiO2 scaffolds of anatase phase possess inherent eximious optical behavior that is beneficial for photoelectrodes used for solar energy conversion applications. In this regard; substantial efforts have been devoted to maximizing the UV and/or visible light absorption efficiency; and suppressing the annihilation of photogenerated charged species; in pristine mesoporous TiO2 structures for improved solar illumination conversion efficiency. This study provides fundamental insights into the use of Mxene functionalized mesoporous TiO2 as a photoelectrode. This novel combination of Mxene functionalized TiO2 electrodes with and without TiCl4 treatment was successfully optimized to intensify the process of photon absorption; charge segregation and photocurrent; resulting in superior photoelectrode performance. The photocurrent measurements of the prepared photoelectrodes were significantly enhanced with increased contents of Mxene due to improved absorption efficiency within the visible region; as verified by UV–Vis absorption spectroscopy. The anatase phase of TiO2 was significantly augmented due to increased contents of Mxene and postdeposition heat treatments; as evidenced by structural analysis. Consequently; an appreciable coverage of well-developed grains on the FTO surface was observed in SEM images. As such; these newly fabricated conductive mesoporous TiO2 photoelectrodes are potential candidates for photoinduced energy conversion and storage applications.
Phosphorous and Silica Recovery from Rice Husk Poultry Litter Ash: A Sustainability Analysis Using a Zero-Waste Approach
Authors: Fiameni Laura , Fahimi Ario , Marchesi Claudio , Sorrentino Giampiero Pasquale , Zanoletti Alessandra , Moreira Karen , Valentim Bruno , Predeanu Georgeta , Depero Laura Eleonora , Bontempi Elza
Published: October 2021

Phosphate rocks are a critical resource for the European Union, and alternative sources to assure the future production of a new generation of fertilizers are to be assessed. In this study, a statistical approach, combined with a sustainability evaluation for the recovery of materials from waste containing phosphorus (P), is presented. This work proposes a strategy to recover P and silica (SiO2) from rice husk poultry litter ash (RHPLA). The design of experiment (DoE) method was applied to maximize the P extraction using hydrochloric acid (HCl), with the aim to minimize the contamination that can occur by leachable heavy metals present in RHPLA, such as zinc (Zn). Two independent variables, the molar concentration of the acid, and the liquid-to-solid ratio (L/S) between the acid and RHPLA, were used in the experimental design to optimize the operating parameters. The statistical analysis showed that a HCl concentration of 0.34 mol/L and an L/S ratio of 50 are the best conditions to recover P with low Zn contamination. Concerning the SiO2, its content in RHPLA is too low to consider the proposed recovery process as advantageous. However, based on our analysis, this process should be sustainable to recover SiO2 when its content in the starting materials is more than 80%.
Microstructure of CEM II/B-S Pastes Modified with Set Accelerating Admixtures
Authors: Pizoń Jan , Łaźniewska-Piekarczyk Beata
Published: October 2021

The presented paper aims to describe the influence of accelerating admixtures on the properties and microstructure of cement pastes and mortars. Blended slag cement CEM II/B-S containing two different clinkers (differing amounts of siliceous and aluminous phases) and four types of accelerators (calcium nitrate, sodium hydroxide, cement kiln dust, and crystal seeds) were used in research. Compressive strength tests (after 12, 24, 48 h of curing), Scanning Electron Microscope (SEM) observations together with an Energy Dispersive Spectroscopy (EDS) analysis, Mercury Intrusion Porosimetry (MIP) tests, and X-ray diffraction (XRD) analysis were conducted. Results have shown that SEM and EDS examination of the microstructure of cement pastes modified with accelerating admixtures at the observed points did not reveal differences that would be sufficient to explain the changes in compressive strength. Still, the increase in amorphous phase content indicates a faster hydration reaction rate for all pastes modified with accelerating admixture. It is backed up also by lower non-hydrated compounds content. All admixtures accelerate the hydration reaction of calcium silicate phases of cement, but only NaOH and cement kiln dust (CKD) influence the aluminate phase reaction rate. The pore volume is independent of the clinker type, while the pore size distribution is not.
Computer-Aided Reengineering towards Plastic Part Failure Minimization
Authors: Pinho Tiago , Zhiltsova Tatiana , Oliveira Mónica , Costa Andreia
Published: October 2021

The work reported here intends to identify and mitigate the causes for failure in a plastic faucet holder, a part of an integral float faucet with a well-documented history of fracture occurrence. A methodology for the identification of hidden internal defects in plastic parts and the elaboration of the required corrective actions towards quality improvement is, therefore, presented. Firstly, part defects were identified via injection moulding process numerical simulation. The latter has enabled the prediction of an excessive volumetric shrinkage at the core of the faucet holder, highlighting the presence of internal voids and, hence, the possible deterioration of the load-bearing capacity. The supposition was later confirmed by X-ray topography scans. Part reengineering, consisting of localized thickness reduction, was the option chosen for decreasing the high shrinkage at the core. For validation purposes, structural analyses were carried out, with and without accounting for the injection moulding processing history. The results obtained during part structural analysis have enabled us to conclude that, when taking into account the residual stresses generated during injection moulding, the analysis more closely reflects the experimental data and allows us to implicitly envisage the propensity to fracture. Moreover, the part modifications, undertaken during the faucet holder reengineering, led to the reduction of the cumulative (processing and imposed by load) stresses by 50%, when compared to the original design analysed.
New Progress on Fiber-Based Thermoelectric Materials: Performance, Device Structures and Applications
Authors: Shen Yanan , Wang Chunyang , Yang Xiao , Li Jian , Lu Rui , Li Ruiyi , Zhang Lixin , Chen Haisheng , Zheng Xinghua , Zhang Ting
Published: October 2021

With the rapid development of wearable electronics, looking for flexible and wearable generators as their self-power systems has proved an extensive task. Fiber-based thermoelectric generators (FTEGs) are promising candidates for these self-powered systems that collect energy from the surrounding environment or human body to sustain wearable electronics. In this work, we overview performances and device structures of state-of-the-art fiber-based thermoelectric materials, including inorganic fibers (e.g., carbon fibers, oxide fibers, and semiconductor fibers), organic fibers, and hybrid fibers. Moreover, potential applications for related thermoelectric devices are discussed, and future developments in fiber-based thermoelectric materials are also briefly expected.
External Surface Quality of the Graphite Crystallizer as a Factor Influencing the Temperature of the Continuous Casting Process of ETP Grade Copper
Authors: Kwaśniewski Paweł , Strzępek Paweł , Kiesiewicz Grzegorz , Kordaszewski Szymon , Franczak Krystian , Sadzikowski Michał , Ściężor Wojciech , Brudny Anna , Kulasa Joanna , Juszczyk Barbara , Wycisk Romuald , Śliwka Michał
Published: October 2021

Today’s world is a place where lack of electrical energy would be unimaginable for most of society. All the conductors in the world, both aluminum and copper, have their origin in various types of casting lines where the liquid metal after crystallization is being processed into the form of wires and microwires. However, the efficiency of the continuous casting processes of metals and the final quality of the manufactured product strictly depend on the design of the used crystallizers, the materials used during its production and its quality. Research conducted in this paper focuses on the latter, i.e., external surface quality of the graphite crystallizer at the place of contact with the primary cooling system. In order to quantify its influence on the continuous casting process numerical analyses using the finite element method has been conducted, which results have been further confirmed during empirical tests in laboratory conditions. It has been proven with all of the proposed methods that the temperature of the obtained cast rod is closely linked to the aforementioned surface quality, as when its roughness coefficient surpasses a certain value the temperature of the obtained product increases almost twofold from approx. 150–170 °C to 300–320 °C. These values might influence the quality and final properties of the cast rod, the susceptibility to wire drawing process and possible formation of wire drawing defects and therefore be of much importance to the casting and processing industry.
Deep-Learning-Based Segmentation of Fresh or Young Concrete Sections from Images of Construction Sites
Authors: Mesfin Woldeamanuel Minwuye , Cho Soojin , Lee Jeongmin , Kim Hyeong-Ki , Kim Taehoon
Published: October 2021

The objective of this study is to evaluate the feasibility of deep-learning-based segmentation of the area covered by fresh and young concrete in the images of construction sites. The RGB images of construction sites under various actual situations were used as an input into several types of convolutional neural network (CNN)–based segmentation models, which were trained using training image sets. Various ranges of threshold values were applied for the classification, and their accuracy and recall capacity were quantified. The trained models could segment the concrete area overall although they were not able to judge the difference between concrete of different ages as professionals can. By increasing the threshold values for the softmax classifier, the cases of incorrect prediction as concrete became almost zero, while some areas of concrete became segmented as not concrete.
Location-Optoelectronic Property Correlation in ZnO:Al Thin Film by RF Magnetron Sputtering and Its Photovoltaic Application
Authors: Lai Fang-I , Yang Jui-Fu , Hsu Yu-Chao , Kuo Shou-Yi
Published: October 2021

In this study, a radio-frequency magnetron sputter system was used to deposit Al2O3 doped ZnO (AZO) thin films at room temperature, and the soda lime glass (SLG) substrates were placed at different zones relative to the center of the sample holder under the target. The samples were then analyzed using an X-ray diffractometer, Hall-effect measurement system, UV-visible spectrophotometer, and X-ray photoelectron spectroscopy. It was found that the electrical, structural, and optical properties of AZO films strongly depend on the target racetrack. The AZO thin film grown at a location outside the racetrack not only has the most suitable figure of merit for transparent conductive films, but also retains the least residual stress, which makes it the most suitable candidate for use as a CZTSe transparent conductive layer. When applied to CZTSe solar cells, the photoelectric efficiency is 3.56%.
Tribological Behavior of Ionic Liquid with Nanoparticles
Authors: Ta Thi-Na , Chern Shin-Yuh , Horng Jeng-Haur
Published: October 2021

This research aims to formulate a new lubricant containing oxide nanoparticles for enhancing anti-wear ability and reducing friction. Different concentrations of copper oxide (CuO) and zinc oxide (ZnO) nanoparticles were separately added to an ionic liquid, methyltrioctylammonium bis(trifluoromethylsulfonyl)imide [N1888] [NTf2], to formulate the tested lubricants. The tribological properties of the lubricants were tested by performing ball-on-disc wear tests on a tribotester (MTM, PCS Instruments). The results show that both the CuO and ZnO nanoparticles can increase the friction reduction ability of the ionic liquid when used as a neat lubricant. The anti-wear characteristic of the ionic liquid is increased by adding ZnO nanoparticles but decreased by adding CuO nanoparticles. The best tribological performance observed for the concentration of 0.2 wt% ZnO, with the wear scar diameter is reduced by 32% compared to the pure ionic liquid. The results of SEM/EDX analysis on the worm morphologies show different lubrication mechanisms of the nanoparticles in the [N1888] [NTf2], which are tribo-sintering for CuO nanoparticles, and third body with pure rolling effect for ZnO nanoparticles.
Generation of Two Correlated Stationary Gaussian Processes
Authors: Cai Guo-Qiang , Huan Ronghua , Zhu Weiqiu
Published: October 2021

Since correlated stochastic processes are often presented in practical problems, feasible methods to model and generate correlated processes appropriately are needed for analysis and simulation. The present paper systematically presents three methods to generate two correlated stationary Gaussian processes. They are (1) the method of linear filters, (2) the method of series expansion with random amplitudes, and (3) the method of series expansion with random phases. All three methods intend to match the power spectral density for each process but use information of different levels of correlation. The advantages and disadvantages of each method are discussed.
Expression and Characterization of a Novel Cold-Adapted Chitosanase from Marine Renibacterium sp. Suitable for Chitooligosaccharides Preparation
Authors: Zhang Lin-Lin , Jiang Xiao-Hua , Xiao Xin-Feng , Zhang Wen-Xiu , Shi Yi-Qian , Wang Zhi-Peng , Zhou Hai-Xiang
Published: October 2021

(1) Background: Chitooligosaccharides (COS) have numerous applications due to their excellent properties. Chitosan hydrolysis using chitosanases has been proposed as an advisable method for COS preparation. Although many chitosanases from various sources have been identified, the cold-adapted ones with high stability are still rather rare but required. (2) Methods: A novel chitosanase named CsnY from marine bacterium Renibacterium sp. Y82 was expressed in Escherichia coli, following sequence analysis. Then, the characterizations of recombinant CsnY purified through Ni–NTA affinity chromatography were conducted, including effects of pH and temperature, effects of metal ions and chemicals, and final product analysis. (3) Results: The GH46 family chitosanase CsnY possessed promising thermostability at broad temperature range (0–50 °C), and with optimal activity at 40 °C and pH 6.0, especially showing relatively high activity (over 80% of its maximum activity) at low temperatures (20–30 °C), which demonstrated the cold-adapted property. Common metal ions or chemicals had no obvious effect on CsnY except Mn2+ and Co2+. Finally, CsnY was determined to be an endo-type chitosanase generating chitodisaccharides and -trisaccharides as main products, whose total concentration reached 56.74 mM within 2 h against 2% (w/v) initial chitosan substrate. (4) Conclusions: The results suggest the cold-adapted CsnY with favorable stability has desirable potential for the industrial production of COS.
Functional Feeds to Tackle Meagre (Argyrosomus regius) Stress: Physiological Responses under Acute Stressful Handling Conditions
Authors: Monteiro Marta , Sousa Carla , Coutinho Filipe , Castro Carolina , Fontinha Filipa , Guerreiro Inês , Pousão Pedro , Matos Elisabete , Díaz-Rosales Patrícia , Oliva-Teles Aires , Enes Paula , Couto Ana
Published: October 2021

Marine algae are recognised sources of bioactive compounds that have attracted great interest as nutritional supplements for aquaculture fish. Intensive rearing conditions often expose fish to husbandry-related stressors, rendering fish more susceptible to disease and reducing production yields. The present work evaluated the potential of two marine algae extracts (Fucus vesiculosus and Nannochloropsis gaditana) as nutritional supplements to mitigate stress effects in meagre (Argyrosomus regius) exposed to an acute handling stress (AS). A plant-based diet was used as a control, and three other diets were prepared, which were similar to the control diet but supplemented with 1% of each algal extract or a combination of the two extracts (0.5% each). The effects of supplemented diets on stress biomarkers, antioxidant enzyme activities, and immune response were analysed in fish exposed to AS after 4 weeks of feeding. Supplemented diets did not affect growth performance but the inclusion of F. vesiculosus promoted higher feed efficiency, as compared to the control group. Dietary algal extracts supplementation reduced plasma glucose levels, increased white blood cell counts, and reduced the expression of pro-inflammatory genes when compared with the control. N. gaditana supplementation led to a reduction in hepatic antioxidant enzyme activity and glutathione levels, while F. vesiculosus supplementation increased muscle glutathione reductase activity and reduced lipid peroxidation. These findings support the potential of algal extracts as nutraceuticals in aquafeeds to enhance the ability of fish to cope with husbandry-related stressful conditions and ultimately improve fish health and welfare.
Reviewing Bone Marrow Edema in Athletes: A Difficult Diagnostic and Clinical Approach
Authors: Tarantino Umberto , Greggi Chiara , Cariati Ida , Manenti Guglielmo , Primavera Matteo , Ferrante Paolo , Iundusi Riccardo , Gasbarra Elena , Gatti Andrea
Published: October 2021

Bone marrow edema (BME) is defined as an area of low signal intensity on T1-weighted (T1W) MRI images and associated with intermediate or high signal intensity findings on T2-weighted (T2W) MRI images. BME represents a typical imaging finding that characterizes common stress-related bone injuries of professional and amateur athletes. The etiology of stress-related injuries is influenced by numerous factors, including the initiation of a new sports activity or changes in an existing training protocol. The clinical significance of BME remains unclear. However, a correlation between the imaging pattern of BME, the clinical history of the patient and the type of sports activity practiced is essential for correct diagnosis and adequate therapeutic treatment. It is also important to clarify whether there is a specific threshold beyond which exercise can adversely affect the bone remodeling process, as the clinical picture may degenerate into the presence of BME, pain and, in the most severe cases, bone loss. In our review, we summarize the current knowledge on the etiopathogenesis and treatment options for BME and highlight the main aspects that make it difficult to formulate a correct diagnosis and establish an adequate therapeutic treatment.
Assessment of Forward Osmosis in PRO Mode during Desalination of a Local Oil Refinery Effluent
Authors: Ezugbe Elorm Obotey , Kweinor Tetteh Emmanuel , Rathilal Sudesh , Asante-Sackey Dennis
Published: October 2021

In this study, the performance of a forward osmosis system was assessed over a 30-h period during desalination of a local oil refinery effluent using NaCl as the draw solute. The study was conducted with the active layer of the membrane facing the draw solution. Assessment was done based on the water flux, salt rejection (SO42− and CO32−), membrane fouling and fouling reversal after membrane cleaning. Critical to this study was the performance of manual scrubbing of the membrane after each run and the application of chemically enhanced osmotic backwash. Scanning electron microscope (SEM) analysis of the cellulose triacetate (CTA) membrane was conducted before and after cleaning to ascertain the degree of fouling and fouling reversal after membrane cleaning. The results showed an average water flux of 3.78 ± 0.13 L/m2 h, reverse solute flux (RSF) of 1.56 ± 0.11 g/m2·h, SO42− rejection of 100%, CO32− rejection of 95.66 ± 0.32% and flux recovery of 95% after membrane cleaning. This study identifies that intermittent manual scrubbing of the membrane plays a major role in overall membrane performance. It also provides a practical basis for further research and decision making in the use of FO and CTA membranes for oil refinery effluent desalination.
Gut Microbiota, Microbial Metabolites and Human Physical Performance
Authors: Lensu Sanna , Pekkala Satu
Published: October 2021

Trillions of microbes inhabiting the gut modulate the metabolism of the host. Cross-sectional studies have reported associations between physical performance and the gut microbiota (GM). Physical activity seems to increase GM diversity and the abundance of certain health-beneficial microbes. We reviewed the evidence from longitudinal studies on the connection between physically active lifestyle or long-term exercise interventions and the GM. We made literature searches using databases of Web of Science and PubMed Medline to collect human studies showing or not the associations between the GM and exercise. Many controversies exist in the studies. However, the longitudinal studies show that frequently, medium-intensity endurance exercise has yielded most beneficial effects on the GM, but the results vary depending on the study population and exercise protocol. In addition, the literature shows that certain microbes own the potency to increase physical activity and performance. Generally, a physically active lifestyle and exercise associate with a “healthy” GM. However, in previously sedentary subjects, the exercise-induced improvements in the GM seem to disappear unless the active lifestyle is continued. Unfortunately, several studies are not controlled for the diet. Thus, in the future, more longitudinal studies on the GM and physical performance are needed, with detailed dietary information.