bluuebunny/crossref_metadata_2025 huggingface dataset:
Isolation of Bacteria with Antifungal Activity against the Phytopathogenic Fungi Stenocarpella maydis and Stenocarpella macrospora
Authors: Petatán-Sagahón Iván , Anducho-Reyes Miguel Angel , Silva-Rojas Hilda Victoria , Arana-Cuenca Ainhoa , Tellez-Jurado Alejandro , Cárdenas-Álvarez Isabel Oyuki , Mercado-Flores Yuridia
Published: August 2011

Stenocarpella maydis and Stenocarpella macrospora are the causal agents of ear rot in corn, which is one of the most destructive diseases in this crop worldwide. These fungi are important mycotoxin producers that cause different pathologies in farmed animals and represent an important risk for humans. In this work, 160 strains were isolated from soil of corn crops of which 10 showed antifungal activity against these phytopathogens, which, were identified as: Bacillus subtilis, Pseudomonas spp., Pseudomonas fluorescens, and Pantoea agglomerans by sequencing of 16S rRNA gene and the phylogenetic analysis. From cultures of each strain, extracellular filtrates were obtained and assayed to determine antifungal activity. The best filtrates were obtained in the stationary phase of B. subtilis cultures that were stable to the temperature and extreme pH values; in addition they did not show a cytotoxicity effect against brine shrimp and inhibited germination of conidia. The bacteria described in this work have the potential to be used in the control of white ear rot disease.
Spectroscopic Behavior of Some A3B Type Tetrapyrrolic Complexes in Several Organic Solvents and Micellar Media
Authors: Boscencu Rica , Ilie Mihaela , Socoteanu Radu
Published: August 2011

The paper presents spectral studies of some unsymmetrical A3B tetrapyrrolic, porphyrin-type complexes with Cu(II) and Zn(II) in different solvents and micellar media aimed at estimating their properties in connection with the living cell. The results indicate that the position of the absorption and emission peaks is mostly influenced by the central metal ion and less by the environmental polarity or the peripheric substituents of the porphyrinic core. The comparison between the overall absorption and emission spectra of the compounds in methanol or cyclohexane vs. direct and reverse Triton X micellar systems, respectively, suggests for all compounds the localization at the interface between the polyethylene oxide chains and the tert-octyl-phenyl etheric residue of the Triton X-100 molecules. These findings could be important when testing the compounds embedded in liposomes or other delivery systems to the targeted cell.
New Dye-Sensitized Solar Cells Obtained from Extracted Bracts of Bougainvillea Glabra and Spectabilis Betalain Pigments by Different Purification Processes
Authors: Hernandez-Martinez Angel Ramon , Estevez Miriam , Vargas Susana , Quintanilla Fracisco , Rodriguez Rogelio
Published: August 2011

The performance of a new dye-sensitized solar cell (DSSC) based in a natural dye extracted from the Bougainvillea spectabilis’ bracts, is reported. The performance of this solar cell was compared with cells prepared using extract of the Bougainvillea glabra and mixture of both extracts; in both cases the pigments were betalains, obtained from Reddish-purple extract. These dyes were purified to different extents and used for the construction of solar cells that were electrically characterized. The materials were characterized using FTIR and UV-Vis. Solar cells were assembled using TiO2 thin film on indium tin oxide (ITO)-coated glass; a mesoporous film was sensitized with the Bougainvillea extracts. The obtained solar energy conversion efficiency was of 0.48% with a current density JSC of 2.29 mA/cm2 using an irradiation of 100 mW/cm2 at 25 °C.
New User-Friendly Approach to Obtain an Eisenberg Plot and Its Use as a Practical Tool in Protein Sequence Analysis
Authors: Keller Rob C.A.
Published: August 2011

The Eisenberg plot or hydrophobic moment plot methodology is one of the most frequently used methods of bioinformatics. Bioinformatics is more and more recognized as a helpful tool in Life Sciences in general, and recent developments in approaches recognizing lipid binding regions in proteins are promising in this respect. In this study a bioinformatics approach specialized in identifying lipid binding helical regions in proteins was used to obtain an Eisenberg plot. The validity of the Heliquest generated hydrophobic moment plot was checked and exemplified. This study indicates that the Eisenberg plot methodology can be transferred to another hydrophobicity scale and renders a user-friendly approach which can be utilized in routine checks in protein–lipid interaction and in protein and peptide lipid binding characterization studies. A combined approach seems to be advantageous and results in a powerful tool in the search of helical lipid-binding regions in proteins and peptides. The strength and limitations of the Eisenberg plot approach itself are discussed as well. The presented approach not only leads to a better understanding of the nature of the protein–lipid interactions but also provides a user-friendly tool for the search of lipid-binding regions in proteins and peptides.
Uniaxial Tension Test of Slender Reinforced Early Age Concrete Members
Authors: Mimura Yoichi , Yoshitake Isamu , Zhang Wenbo
Published: August 2011

The present study aims to obtain the tensile properties of early age concrete based on a uniaxial tension test employing RC slender members. First, the paper shows that concrete strain is equal to the strain of rebar at the mid-span of the RC member. The tensile Young’s modulus and the strain capacity of early age concrete are estimated using strain measurements. The experiment indicated that the tensile Young’s modulus at an early age is higher than the compressive modulus. This observation was similar to one found in a previous investigation which used a direct tension test of early age concrete. Moreover, the paper describes how an empirical equation for mature concrete can be applied to the relation between uniaxial tensile strength and splitting tensile strength even in early age concrete. Based on a uniaxial tension test, the paper proposes an empirical equation for the relationship between standard bond stresses and relative slip.
Functionality in Electrospun Nanofibrous Membranes Based on Fiber’s Size, Surface Area, and Molecular Orientation
Authors: Matsumoto Hidetoshi , Tanioka Akihiko
Published: August 2011

Electrospinning is a versatile method for forming continuous thin fibers based on an electrohydrodynamic process. This method has the following advantages: (i) the ability to produce thin fibers with diameters in the micrometer and nanometer ranges; (ii) one-step forming of the two- or three-dimensional nanofiber network assemblies (nanofibrous membranes); and (iii) applicability for a broad spectrum of molecules, such as synthetic and biological polymers and polymerless sol-gel systems. Electrospun nanofibrous membranes have received significant attention in terms of their practical applications. The major advantages of nanofibers or nanofibrous membranes are the functionalities based on their nanoscaled-size, highly specific surface area, and highly molecular orientation. These functionalities of the nanofibrous membranes can be controlled by their fiber diameter, surface chemistry and topology, and internal structure of the nanofibers. This report focuses on our studies and describes fundamental aspects and applications of electrospun nanofibrous membranes.
Expeditious Entry to Novel 2-Methylene-2,3-dihydrofuro[3,2-c] chromen-2-ones from 6-Chloro-4-hydroxychromen-2-one and Propargylic Alcohols
Authors: Nebra Noel , Díaz-Álvarez Alba E. , Díez Josefina , Cadierno Victorio
Published: August 2011

A catalytic system consisting of the ruthenium(II) complex [Ru(η3-2-C3H4Me)(CO)(dppf)][SbF6] (dppf = 1,1’-bis(diphenylphosphino)ferrocene) and trifluoroacetic acid has been used to promote the coupling of secondary propargylic alcohols with 6-chloro-4-hydroxychromen-2-one. The reactions afforded unusual 2-methylene-2,3-dihydrofuro[3,2-c]chromen-2-ones in good yields.
Chirality and Numbering of Substituted Tropane Alkaloids
Authors: Humam Munir , Shoul Tarik , Jeannerat Damien , Muñoz Orlando , Christen Philippe
Published: August 2011

The strict application of IUPAC rules for the numbering of tropane alkaloids is not always applied by authors and there is hence a lot of confusion in the literature. In most cases, the notation of 3, 6/7-disubstituted derivatives has been chosen arbitrarily, based on NMR and MS data, without taking into account the absolute configuration of these two carbons. This paper discusses the problem and the relevance of CD and NMR to determine molecular configurations. We report on the use of 1H-NMR anisochrony (Δd) induced by the Mosher’s chiral auxiliary reagents (R)-(-)- and (S)-(+)-α-methoxy-α-trifluoromethyl-phenylacetyl chlorides (MTPA-Cl), to determine the absolute configuration of (3R,6R)-3α-hydroxy-6b-senecioyloxytropane, a disubstituted tropane alkaloid isolated from the aerial parts of Schizanthus grahamii (Solanaceae). These analytical tools should help future works in correctly assigning the configuration of additional 3, 6/7 disubstituted tropane derivatives.
Use of Graphite Oxide and Graphene Oxide as Catalysts in the Synthesis of Dipyrromethane and Calix[4]pyrrole
Authors: Singh Chauhan Shive Murat , Mishra Sweta
Published: August 2011

Graphite oxide and graphene oxides have been used as solid catalysts for the synthesis of 5,5-dialkyldipyrromethanes and calix[4]pyrroles in organic and aqueous solutions at room temperature.
Development of a Process for Separation of Mogroside V from Siraitia grosvenorii by Macroporous Resins
Authors: Zhang Min , Yang Huihua , Zhang Hongyang , Wang Yuerong , Hu Ping
Published: August 2011

A separation method was developed for the preparative separation and enrichment of the non-caloric sweetener mogroside V from Siraitia grosvenorii. The adsorption properties of six macroporous resins were evaluated. Results showed that HZ 806 resin offered the best adsorption and desorption capacities. Based on the adsorption experiments on HZ 806, the adsorption data were found to fit the Freundlich model well. The pseudo-second-order kinetic model showed the highest correlation with the experimental results. Separation was performed with deionized water and 40% aqueous ethanol solution as mobile phases. In a typical run, 100 g of herb was processed and 3.38 g of mogroside V with a purity of 10.7% was harvested. This separation method provided a 15.1-fold increase in the purification factor from 0.5% to 10.7%. The present study showed that HZ 806 resins were effective for the separation and enrichment of mogroside V from S. grosvenorii.
Toxicity of Rhododendron anthopogonoides Essential Oil and Its Constituent Compounds towards Sitophilus zeamais
Authors: Yang Kai , Zhou Yu Xin , Wang Cheng Fang , Du Shu Shan , Deng Zhi Wei , Liu Qi Zhi , Liu Zhi Long
Published: August 2011

The screening of several Chinese medicinal plants for insecticidal principles showed that essential oil of Rhododendron anthopogonoides flowering aerial parts possessed significant toxicity against maize weevils, Sitophilus zeamais. A total of 37 components were identified in the essential oil and the main constituents of the essential oil were 4-phenyl-2-butanone (27.22%), nerolidol (8.08%), 1,4-cineole (7.85%), caryophyllene (7.63%) and γ-elemene (6.10%), followed by α-farnesene (4.40%) and spathulenol (4.19%). Repeated bioactivity-directed chromatographic separation on silica gel columns led us to isolate three compounds, namely 4-phenyl-2-butanone, 1,4-cineole, and nerolidol. 4-Phenyl-2-butanone shows pronounced contact toxicity against S. zeamais (LD50 = 6.98 mg/adult) and was more toxic than either 1,4-cineole or nerolidol (LD50 = 50.86 mg/adult and 29.30 mg/adult, respectively) against the maize weevils, while the crude essential oil had a LD50 value of 11.67 mg/adult. 4-Phenyl-2-butanone and 1,4-cineole also possessed strong fumigant toxicity against the adults of S. zeamais (LC50 = 3.80 mg/L and 21.43 mg/L) while the crude essential oil had a LC50 value of 9.66 mg/L.
Evaluation of the Effects of Mitragyna speciosa Alkaloid Extract on Cytochrome P450 Enzymes Using a High Throughput Assay
Authors: Kong Wai Mun , Chik Zamri , Ramachandra Murali , Subramaniam Umarani , Aziddin Raja Elina Raja , Mohamed Zahurin
Published: August 2011

The extract from Mitragyna speciosa has been widely used as an opium substitute, mainly due to its morphine-like pharmacological effects. This study investigated the effects of M. speciosa alkaloid extract (MSE) on human recombinant cytochrome P450 (CYP) enzyme activities using a modified Crespi method. As compared with the liquid chromatography-mass spectrometry method, this method has shown to be a fast and cost-effective way to perform CYP inhibition studies. The results indicated that MSE has the most potent inhibitory effect on CYP3A4 and CYP2D6, with apparent half-maximal inhibitory concentration (IC50) values of 0.78 µg/mL and 0.636 µg/mL, respectively. In addition, moderate inhibition was observed for CYP1A2, with an IC50 of 39 µg/mL, and weak inhibition was detected for CYP2C19. The IC50 of CYP2C19 could not be determined, however, because inhibition was < 50%. Competitive inhibition was found for the MSE-treated CYP2D6 inhibition assay, whereas non-competitive inhibition was shown in inhibition assays using CYP3A4, CYP1A2 and CYP2C19. Quinidine (CYP2D6), ketoconazole (CYP3A4), tranylcypromine (CYP2C19) and furafylline (CYP1A2) were used as positive controls throughout the experiments. This study shows that MSE may contribute to an herb-drug interaction if administered concomitantly with drugs that are substrates for CYP3A4, CYP2D6 and CYP1A2.
Antibacterial Activity of Aristolochia brevipes against Multidrug-Resistant Mycobacterium tuberculosis
Authors: Navarro-García Víctor Manuel , Luna-Herrera Julieta , Rojas-Bribiesca Ma. Gabriela , Álvarez-Fitz Patricia , Ríos María Yolanda
Published: August 2011

The increased incidence of Multidrug-Resistant Mycobacterium tuberculosis (MDR-MT) requires the search for alternative antimycobacterial drugs. The main aim of this study was to evaluate the dichloromethane extract from Aristolochia brevipes (Rhizoma) and the compounds isolated from this extract against several mycobacterial strains, sensitive, resistant (monoresistant), and clinical isolates (multidrug-resistant), using the alamarBlue™ microassay. The extract was fractionated by column chromatography, yielding the following eight major compounds: (1) 6α-7-dehydro-N-formylnornantenine; (2) E/Z-N-formylnornantenine; (3) 7,9-dimethoxytariacuripyrone; (4) 9-methoxy-tariacuripyrone; (5) aristololactam I; (6) β-sitosterol; (7) stigmasterol; and (8) 3-hydroxy-α-terpineol. The structures of these compounds were elucidated by 1H- and 13C- (1D and 2D) Nuclear Magnetic Resonance (NMR) spectroscopy. This study demonstrates that the dichloromethane extract (rhizome) of A. brevipes possesses strong in vitro antimycobacterial activity against Mycobacterium tuberculosis H37Rv (Minimum Inhibitory Concentration value [MIC], 12.5 µg/mL). The most active compound against all mycobacterial strains tested was the compound aristolactam I (5), with MIC values ranging between 12.5 and 25 µg/mL. To our knowledge, this the first report of antimycobacterial activity in this plant.
An Emulsion Based Microarray Method to Detect the Toxin Genes of Toxin-Producing Organisms
Authors: Wang Ying , Lu Jiafeng , Yang Qi , Bai Yunfei , Ge Qinyu
Published: August 2011

Toxins produced by bacteria and fungi are one of the most important factors which may cause food contamination. The study of detection methods with high sensitivity and throughput is significant for the protection of food safety. In the present study, we coupled microarray with emulsion PCR and developed a high throughput detection method. Thirteen different gene sites which encode the common toxins of several bacteria and fungi were assayed in parallel in positive and maize samples. Conventional PCR assays were carried out for comparison. The results showed that the developed microarray method had high specificity and sensitivity. Two zearalenone-related genes were investigated in one of the ten maize samples obtained with this present method. The results indicated that the emulsion based microarray detection method was developed successfully and suggested its potential application in multiple gene site detection.
A Practical Approach to New (5Z) 2-Alkylthio-5-arylmethylene-1-methyl-1,5-dihydro-4H-imidazol-4-one Derivatives
Authors: Bourahla Khadidja , Paquin Ludovic , Lozach Olivier , Meijer Laurent , Carreaux François , Bazureau Jean Pierre
Published: August 2011

A practical protocol for the preparation of (5Z)-2-alkylthio-5-arylmethylene-1-methyl-1,5-dihydro-4H-imidazol-4-one derivatives is reported. The new compounds were obtained in good yield and stereoselectivity in two steps, namely a solvent-free Knoevenagel condensation under microwave irradiation, followed by an S-alkylation reaction with various halogenoalkanes.
The Application of Microencapsulation Techniques in the Treatment of Endodontic and Periodontal Diseases
Authors: Álvarez Asteria Luzardo , Espinar Francisco Otero , Méndez José Blanco
Published: August 2011

In the treatment of intracanal and periodontal infections, the local application of antibiotics and other therapeutic agents in the root canal or in periodontal pockets may be a promising approach to achieve sustained drug release, high antimicrobial activity and low systemic side effects. Microparticles made from biodegradable polymers have been reported to be an effective means of delivering antibacterial drugs in endodontic and periodontal therapy. The aim of this review article is to assess recent therapeutic strategies in which biocompatible microparticles are used for effective management of periodontal and endodontic diseases. In vitro and in vivo studies that have investigated the biocompatibility or efficacy of certain microparticle formulations and devices are presented. Future directions in the application of microencapsulation techniques in endodontic and periodontal therapies are discussed.
Synthesis of Stimuli-responsive, Water-soluble Poly[2-(dimethylamino)ethyl methacrylate/styrene] Statistical Copolymers by Nitroxide Mediated Polymerization
Authors: Zhang Chi , Maric Milan
Published: August 2011

2-(Dimethylamino)ethyl methacrylate/styrene statistical copolymers (poly(DMAEMA-stat-styrene)) with feed compositions fDMAEMA = 80–95 mol%, (number average molecular weights Mn = 9.5–11.2 kg mol−1) were synthesized using succinimidyl ester-functionalized BlocBuilder alkoxyamine initiator at 80 °C in bulk. Polymerization rate increased three-fold on increasing fDMAEMA = 80 to 95 mol%. Linear Mn increases with conversion were observed up to about 50% conversion and obtained copolymers possessed monomodal, relatively narrow molecular weight distributions (polydispersity = 1.32–1.59). Copolymers with fDMAEMA = 80 and 90 mol% were also cleanly chain-extended with DMAEMA/styrene mixtures of 95 and 90 mol% DMAEMA, respectively, confirming the livingness of the copolymers. Copolymer phase behavior in aqueous solutions was examined by dynamic light scattering and UV-Vis spectroscopy. All copolymers exhibited lower critical solution temperature (LCST)-type behavior. LCST decreased with increasing styrene content in the copolymer and with increasing solution concentration. All copolymers were completely water-soluble and temperature insensitive at pH 4 but were more hydrophobic at pH 10, particularly copolymers with fDMAEMA = 80 and 85 mol%, which were water-insoluble. At pH 10, LCST of copolymers with fDMAEMA = 90 and 95 mol% were more than 10 °C lower compared to their solutions in neutral, de-ionized water. Block copolymers with two statistical blocks with different DMAEMA compositions exhibited a single LCST, suggesting the block segments were not distinct enough to exhibit separate LCSTs in water.
Microscopic and Spectroscopic Investigation of Poly(3-hexylthiophene) Interaction with Carbon Nanotubes
Authors: Giulianini Michele , Waclawik Eric R. , Bell John M. , Scarselli Manuela , Castrucci Paola , De Crescenzi Maurizio , Motta Nunzio
Published: August 2011

The inclusion of carbon nanotubes in polymer matrix has been proposed to enhance the polymer’s physical and electrical properties. In this study, microscopic and spectroscopic techniques are used to investigate the interaction between poly(3-hexylthiophene) (P3HT) and nanotubes and the reciprocal modification of physical properties. The presence of P3HT-covered nanotubes dispersed in the polymer matrix has been observed by atomic force microscopy and transmission electron microscopy. Then, the modification of P3HT optical properties due to nanotube inclusion has been evidenced with spectroscopic techniques like absorption and Raman spectroscopy. The study is completed with detailed nanoscale analysis by scanning probe techniques. The ordered self assembly of polymer adhering on the nanotube is unveiled by showing an example of helical wrapping of P3HT. Scanning tunneling spectroscopy study provides information on the electronic structure of nanotube-polymer assembly, revealing the charge transfer from P3HT to the nanotube.
Soil Heat Flux Modeling Using Artificial Neural Networks and Multispectral Airborne Remote Sensing Imagery
Authors: Canelón Dario J. , Chávez José L.
Published: August 2011

The estimation of spatially distributed crop water use or evapotranspiration (ET) can be achieved using the energy balance for land surface algorithm and multispectral imagery obtained from remote sensing sensors mounted on air- or space-borne platforms. In the energy balance model, net radiation (Rn) is well estimated using remote sensing; however, the estimation of soil heat flux (G) has had mixed results. Therefore, there is the need to improve the model to estimate soil heat flux and thus improve the efficiency of the energy balance method based on remote sensing inputs. In this study, modeling of airborne remote sensing-based soil heat flux was performed using Artificial Neural Networks (ANN). Soil heat flux was modeled using selected measured data from soybean and corn crop covers in Central Iowa, U.S.A. where measured values were obtained with soil heat flux plate sensors. Results in the modeling of G indicated that the combination Rn with air temperature (Tair) and crop height (hc) better reproduced measured values when three independent variables were considered. The combination of Rn with leaf area index (LAI) from remote sensing, and Rn with surface aerodynamic resistance (rah) yielded relative larger overall correlation coefficient values when two independent variables were included using ANN. In addition, air temperature (Tair) may be a key variable in the modeling of G as suggested by the ANN application (r of 0.83). Therefore, it is suggested that Rn, LAI, rah and hc and potentially Tair be considered in future modeling studies of G.
Mapping Infrared Data on Terrestrial Laser Scanning 3D Models of Buildings
Authors: Alba Mario Ivan , Barazzetti Luigi , Scaioni Marco , Rosina Elisabetta , Previtali Mattia
Published: August 2011

A new 3D acquisition and processing procedure to map RGB, thermal IR and near infrared images (NIR) on a detailed 3D model of a building is presented. The combination and fusion of different data sources allows the generation of 3D thermal data useful for different purposes such as localization, visualization, and analysis of anomalies in contemporary architecture. The classic approach, which is currently used to map IR images on 3D models, is based on the direct registration of each single image by using space resection or homography. This approach is largely time consuming and in many cases suffers from poor object texture. To overcome these drawbacks, a “bi-camera” system coupling a thermal IR camera to a RGB camera has been setup. The second sensor is used to orient the “bi-camera” through a photogrammetric network also including free-handled camera stations to strengthen the block geometry. In many cases the bundle adjustment can be executed through a procedure for automatic extraction of tie points. Terrestrial laser scanning is adopted to retrieve the 3D model building. The integration of a low-cost NIR camera accumulates further radiometric information on the final 3D model. The use of such a sensor has not been exploited until now to assess the conservation state of buildings. Here some interesting findings from this kind of analysis are reported. The paper shows the methodology and its experimental application to a couple of buildings in the main Campus of Politecnico di Milano University, where IR thermography has previously been carried out for conservation and maintenance purposes.
Stress Wave Signal Denoising Using Ensemble Empirical Mode Decomposition and an Instantaneous Half Period Model
Authors: Fang Yi-Ming , Feng Hai-Lin , Li Jian , Li Guang-Hui
Published: August 2011

Stress-wave-based techniques have been proven to be an accurate nondestructive test means for determining the quality of wood based materials and they been widely used for this purpose. However, the results are usually inconsistent, partially due to the significant difficulties in processing the nonlinear, non-stationary stress wave signals which are often corrupted by noise. In this paper, an ensemble empirical mode decomposition (EEMD) based approach with the aim of signal denoising was proposed and applied to stress wave signals. The method defined the time interval between two adjacent zero-crossings within the intrinsic mode function (IMF) as the instantaneous half period (IHP) and used it as a criterion to detect and classify the noise oscillations. The waveform between the two adjacent zero-crossings was retained when the IHP was larger than the predefined threshold, whereas the waveforms with smaller IHP were set to zero. Finally the estimated signal was obtained by reconstructing the processed IMFs. The details of threshold choosing rules were also discussed in the paper. Additive Gaussian white noise was embedded into real stress wave signals to test the proposed method. Butterworth low pass filter, EEMD-based low pass filter and EEMD-based thresholding filter were used to compare filtering performance. Mean square error between clean and filtered stress waves was used as filtering performance indexes. The results demonstrated the excellent efficiency of the proposed method.
Semantically-Enabled Sensor Plug & Play for the Sensor Web
Authors: Bröring Arne , Maué Patrick , Janowicz Krzysztof , Nüst Daniel , Malewski Christian
Published: August 2011

Environmental sensors have continuously improved by becoming smaller, cheaper, and more intelligent over the past years. As consequence of these technological advancements, sensors are increasingly deployed to monitor our environment. The large variety of available sensor types with often incompatible protocols complicates the integration of sensors into observing systems. The standardized Web service interfaces and data encodings defined within OGC’s Sensor Web Enablement (SWE) framework make sensors available over the Web and hide the heterogeneous sensor protocols from applications. So far, the SWE framework does not describe how to integrate sensors on-the-fly with minimal human intervention. The driver software which enables access to sensors has to be implemented and the measured sensor data has to be manually mapped to the SWE models. In this article we introduce a Sensor Plug & Play infrastructure for the Sensor Web by combining (1) semantic matchmaking functionality, (2) a publish/subscribe mechanism underlying the SensorWeb, as well as (3) a model for the declarative description of sensor interfaces which serves as a generic driver mechanism. We implement and evaluate our approach by applying it to an oil spill scenario. The matchmaking is realized using existing ontologies and reasoning engines and provides a strong case for the semantic integration capabilities provided by Semantic Web research.
Indoor Pedestrian Navigation Using Foot-Mounted IMU and Portable Ultrasound Range Sensors
Authors: Girard Gabriel , Côté Stéphane , Zlatanova Sisi , Barette Yannick , St-Pierre Johanne , Van Oosterom Peter
Published: August 2011

Many solutions have been proposed for indoor pedestrian navigation. Some rely on pre-installed sensor networks, which offer good accuracy but are limited to areas that have been prepared for that purpose, thus requiring an expensive and possibly time-consuming process. Such methods are therefore inappropriate for navigation in emergency situations since the power supply may be disturbed. Other types of solutions track the user without requiring a prepared environment. However, they may have low accuracy. Offline tracking has been proposed to increase accuracy, however this prevents users from knowing their position in real time. This paper describes a real time indoor navigation system that does not require prepared building environments and provides tracking accuracy superior to previously described tracking methods. The system uses a combination of four techniques: foot-mounted IMU (Inertial Motion Unit), ultrasonic ranging, particle filtering and model-based navigation. The very purpose of the project is to combine these four well-known techniques in a novel way to provide better indoor tracking results for pedestrians.
Enhanced Precision Time Synchronization for Wireless Sensor Networks
Authors: Cho Hyuntae , Kim Jongdeok , Baek Yunju
Published: August 2011

Time synchronization in wireless sensor networks (WSNs) is a fundamental issue for the coordination of distributed entities and events. Nondeterministic latency, which may decrease the accuracy and precision of time synchronization can occur at any point in the network layers. Specially, random back-off by channel contention leads to a large uncertainty. In order to reduce the large nondeterministic uncertainty from channel contention, we propose an enhanced precision time synchronization protocol in this paper. The proposed method reduces the traffic needed for the synchronization procedure by selectively forwarding the packet. Furthermore, the time difference between sensor nodes increases as time advances because of the use of a clock source with a cheap crystal oscillator. In addition, we provide a means to maintain accurate time by adopting hardware-assisted time stamp and drift correction. Experiments are conducted to evaluate the performance of the proposed method, for which sensor nodes are designed and implemented. According to the evaluation results, the performance of the proposed method is better than that of a traditional time synchronization protocol.
A Study on Group Key Agreement in Sensor Network Environments Using Two-Dimensional Arrays
Authors: Jang Seung-Jae , Lee Young-Gu , Lee Kwang-Hyung , Kim Tai-Hoon , Jun Moon-Seog
Published: August 2011

These days, with the emergence of the concept of ubiquitous computing, sensor networks that collect, analyze and process all the information through the sensors have become of huge interest. However, sensor network technology fundamentally has wireless communication infrastructure as its foundation and thus has security weakness and limitations such as low computing capacity, power supply limitations and price. In this paper, and considering the characteristics of the sensor network environment, we propose a group key agreement method using a keyset pre-distribution of two-dimension arrays that should minimize the exposure of key and personal information. The key collision problems are resolved by utilizing a polygonal shape’s center of gravity. The method shows that calculating a polygonal shape’s center of gravity only requires a very small amount of calculations from the users. The simple calculation not only increases the group key generation efficiency, but also enhances the sense of security by protecting information between nodes.
An Inter-Networking Mechanism with Stepwise Synchronization for Wireless Sensor Networks
Authors: Yamamoto Hiroshi , Wakamiya Naoki , Murata Masayuki
Published: August 2011

To realize the ambient information society, multiple wireless networks deployed in the region and devices carried by users are required to cooperate with each other. Since duty cycles and operational frequencies are different among networks, we need a mechanism to allow networks to efficiently exchange messages. For this purpose, we propose a novel inter-networking mechanism where two networks are synchronized with each other in a moderate manner, which we call stepwise synchronization. With our proposal, to bridge the gap between intrinsic operational frequencies, nodes near the border of networks adjust their operational frequencies in a stepwise fashion based on the pulse-coupled oscillator model as a fundamental theory of synchronization. Through simulation experiments, we show that the communication delay and the energy consumption of border nodes are reduced, which enables wireless sensor networks to communicate longer with each other.
Determination of the NOx Loading of an Automotive Lean NOx Trap by Directly Monitoring the Electrical Properties of the Catalyst Material Itself
Authors: Fremerey Peter , Reiß Sebastian , Geupel Andrea , Fischerauer Gerhard , Moos Ralf
Published: August 2011

Recently, it has been shown that the degree of loading of several types of automotive exhaust aftertreatment devices can be directly monitored in situ and in a contactless way by a microwave-based method. The goal of this study was to clarify whether this method can also be applied to NOx storage and reduction catalysts (lean NOx traps) in order to obtain further knowledge about the reactions occurring in the catalyst and to compare the results with those obtained by wirebound NOx loading sensors. It is shown that both methods are able to detect the different catalyst loading states. However, the sensitivity of the microwave-based method turned out to be small compared to that previously observed for other exhaust aftertreatment devices. This may limit the practical applicability of the microwave-based NOx loading detection in lean NOx traps.
A Biosensor for Urea from Succinimide-Modified Acrylic Microspheres Based on Reflectance Transduction
Authors: Ulianas Alizar , Heng Lee Yook , Ahmad Musa
Published: August 2011

New acrylic microspheres were synthesised by photopolymerisation where the succinimide functional group was incorporated during the microsphere preparation. An optical biosensor for urea based on reflectance transduction with a large linear response range to urea was successfully developed using this material. The biosensor utilized succinimide-modified acrylic microspheres immobilized with a Nile blue chromoionophore (ETH 5294) for optical detection and urease enzyme was immobilized on the surface of the microspheres via the succinimide groups. No leaching of the enzyme or chromoionophore was observed. Hydrolysis of the urea by urease changes the pH and leads to a color change of the immobilized chromoionophore. When the color change was monitored by reflectance spectrophotometry, the linear response range of the biosensor to urea was from 0.01 to 1,000 mM (R2 = 0.97) with a limit of detection of 9.97 mM. The biosensor response showed good reproducibility (relative standard deviation = 1.43%, n = 5) with no interference by major cations such as Na+, K+, NH4+ and Mg2+. The use of reflectance as a transduction method led to a large linear response range that is better than that of many urea biosensors based on other optical transduction methods.
A Fusion-Spliced Near-Field Optical Fiber Probe Using Photonic Crystal Fiber for Nanoscale Thermometry Based on Fluorescence-Lifetime Measurement of Quantum Dots
Authors: Fujii Takuro , Taguchi Yoshihiro , Saiki Toshiharu , Nagasaka Yuji
Published: August 2011

We have developed a novel nanoscale temperature-measurement method using fluorescence in the near-field called Fluorescence Near-field Optics Thermal Nanoscopy (Fluor-NOTN). Fluor-NOTN enables the temperature distributions of nanoscale materials to be measured in vivo/in situ. The proposed method measures temperature by detecting the temperature dependent fluorescence lifetimes of Cd/Se Quantum Dots (QDs). For a high-sensitivity temperature measurement, the auto-fluorescence generated from a fiber probe should be reduced. In order to decrease the noise, we have fabricated a novel near-field optical-fiber probe by fusion-splicing a photonic crystal fiber (PCF) and a conventional single-mode fiber (SMF). The validity of the novel fiber probe was assessed experimentally by evaluating the auto-fluorescence spectra of the PCF. Due to the decrease of auto-fluorescence, a six- to ten-fold increase of S/N in the near-field fluorescence lifetime detection was achieved with the newly fabricated fusion-spliced near-field optical fiber probe. Additionally, the near-field fluorescence lifetime of the quantum dots was successfully measured by the fabricated fusion-spliced near-field optical fiber probe at room temperature, and was estimated to be 10.0 ns.
A Novel Method to Increase LinLog CMOS Sensors’ Performance in High Dynamic Range Scenarios
Authors: Martínez-Sánchez Antonio , Fernández Carlos , Navarro Pedro J. , Iborra Andrés
Published: August 2011

Images from high dynamic range (HDR) scenes must be obtained with minimum loss of information. For this purpose it is necessary to take full advantage of the quantification levels provided by the CCD/CMOS image sensor. LinLog CMOS sensors satisfy the above demand by offering an adjustable response curve that combines linear and logarithmic responses. This paper presents a novel method to quickly adjust the parameters that control the response curve of a LinLog CMOS image sensor. We propose to use an Adaptive Proportional-Integral-Derivative controller to adjust the exposure time of the sensor, together with control algorithms based on the saturation level and the entropy of the images. With this method the sensor’s maximum dynamic range (120 dB) can be used to acquire good quality images from HDR scenes with fast, automatic adaptation to scene conditions. Adaptation to a new scene is rapid, with a sensor response adjustment of less than eight frames when working in real time video mode. At least 67% of the scene entropy can be retained with this method.
Revisiting System Paradigms from the Viewpoint of Manufacturing Sustainability
Authors: Bi Zhuming
Published: August 2011

A system paradigm is an abstract representation of system; it includes system architecture used to determine the types and numbers of components and their relations in the system. The design of system paradigm relies on customers’ requirements and the characteristics of the manufacturing environment. Many system paradigms and design guidelines have been proposed for a variety of customers’ needs including functions, cost, quality, personalization, and lead time of products. However, the consideration of sustainability becomes essential to today’s manufacturing systems; a new challenge is how to evolve existing paradigms to accommodate the requirements of sustainability. In contrast to ample research activities on system paradigms in past decades, recent studies on system paradigms have been restricted, partially due to unclear research directions. Limited works can be found on conceiving new manufacturing system paradigms from the perspective of sustainability; most of the related literature concerns the new requirements of sustainability. The objectives of this work are (i) to examine the requirements of manufacturing systems in a wider scope; (ii) to revisit existing paradigms to clarify their limitations and bottlenecks; and eventually (iii) to identify some research directions, which will lead to a solution of sustainable manufacturing. To achieve these objectives, firstly, a brief description of today’s manufacturing environment is provided. Secondly, the requirements of sustainability are discussed, and the relevant researches on system sustainability are surveyed. Thirdly, the reconfigurable system paradigm is focused, and the gaps between a reconfigurable manufacturing system and a sustainable manufacturing system are discussed. Finally, the future endeavors towards to the next-generation manufacturing system paradigms are discussed.
Accounting for Sustainability: A Dissenting Opinion
Authors: Cairns Robert D.
Published: August 2011

Discounted-utilitarian welfare, the commonest social objective studied by economists, is the basis for the theory of green accounting in terms of social utility. Sustainability is a different type of social objective. Consequently, green accounting as derived in many empirical models is not appropriate for studying sustainability. Maximin is a consistent foundation for the analysis of sustainability, both weak and strong, that provides conceptually correct accounting prices. These prices are not yet practicable for real economies, however, and must await further advances. Sustainable development is a generalization of the notion of sustainability and can be analyzed using a generalization of maximin.
Undergraduate Sustainable Learning: Effects of Sustainable Soilless Media on Production and Sensory Evaluation of Cucumbers, Basil, Parsley, and Lettuce
Authors: Anderson Neil O. , Annis Joey , Buchholz Mark , Cutting Jared , Heuring Eric , Jankila Emily , McCrumb Megan , Nelson Nicole , Pehoski Myra , Piepho Karl , Price Valerie , Russell Victoria
Published: August 2011

Modern greenhouse production has been ~100% reliant on fossil fuels for all inputs (glazing, heating, fertilization, lighting, post-harvest). Recent innovations may reduce fossil fuel dependence but their effectiveness may not be thoroughly tested. To promote education in sustainable production, undergraduate students in Greenhouse Management class (Hort 3002W; University of Minnesota) tested the effectiveness of two organic or ‘sustainable’ soilless media (Sunshine Natural and Organic Growing Mix, Sungro Metro-Mix Special Blend) with a control (Sunshine LC8 Professional) for crop production (height, leaf/flower number, yield) and sensory evaluations (appearance, texture, taste, purchase) of cucumbers (‘Big Burpless Hybrid’, ‘Sweet Burpless Hybrid’), basil (‘Opal Purple’, ‘Redleaf’), parsley (‘Green River’, ‘Extra Curled Dwarf’, ‘Hamburg’), and lettuce (Flying Saucer ‘Green’, ‘Red’). Significant differences between sustainable vs. control soils occurred for plant growth, depending on vegetative or reproductive traits, crops, and cultivars. These differences occasionally disappeared for sensory evaluation of edible components. In most crops, however, cultivars were highly significant factors. Undergraduate research can be used to provide directionality for future vegetable and herb plant breeding to focus on creating cultivars with increased yield and high consumer acceptance when grown in sustainable greenhouse soilless mixes.
Expression Profiling of Non-Aflatoxigenic Aspergillus parasiticus Mutants Obtained by 5-Azacytosine Treatment or Serial Mycelial Transfer
Authors: Wilkinson Jeffrey R. , Kale Shubha P. , Bhatnagar Deepak , Yu Jiujiang , Ehrlich Kenneth C.
Published: August 2011

Aflatoxins are carcinogenic secondary metabolites produced by the fungi Aspergillus flavus and Aspergillus parasiticus. Previous studies found that repeated serial mycelial transfer or treatment of A. parasiticus with 5-azacytidine produced colonies with a fluffy phenotype and inability to produce aflatoxins. To understand how these treatments affect expression of genes involved in aflatoxin production and development, we carried out expressed sequence tag (EST)-based microarray assays to identify genes in treated clones that are differentially expressed compared to the wild-type. Expression of 183 genes was significantly dysregulated. Of these, 38 had at least two-fold or lower expression compared to the untreated control and only two had two-fold or higher expression. The most frequent change was downregulation of genes predicted to encode membrane-bound proteins. Based on this result we hypothesize that the treatments cause changes in the structure of cellular and organelle membranes that prevent normal development and aflatoxin biosynthesis.
Le taux de change réel d'équilibre : une introduction
Authors: Joly Hervé , Prigent Céline , Sobczak Nicolas
Published: August 2011

Le taux de change réel d'équilibre : une introduction par Hervé Joly, Céline Prigent, Nicolas Sobczak

Cet article présente les deux principales théories du taux de change réel d'équilibre. La première approche repose sur un modèle d'équilibre général intertemporel à deux secteurs; elle définit le taux de change réel comme le prix relatif des biens échangeables par rapport aux biens non-échangeables. Elle est la plus achevée d'un point de vue théorique mais est complexe à mettre en oeuvre empiriquement. La seconde approche est plus "macro-économique". Le change réel y est défini comme un indicateur de compétitivité; son niveau d'équilibre permet d'atteindre l'équilibre externe tout en étant compatible avec l'équilibre interne. Le calcul empirique est plus aisé et s'appuie les mécanismes les plus robustes inscrits dans les modèles macro-économétriques. Ces deux approches présentent des points communs, en particulier une définition intertemporelle de l'équilibre extérieur. Elles paraissent par ailleurs largement complémentaires dans la mesure où elles se réfèrent implicitement à des horizons temporels différents.
Les modèles monétaires de taux de change : un examen empirique
Authors: Jondeau Éric
Published: August 2011

Monetary Exchange Rate Models: A New Empirical Study by Éric Jondeau

This paper makes an empirical study of the two main monetary exchange rate models, which assume perfectly flexible or short-run prices. In view of the non-stationarity of exchange rates and their determinants, the testable specifications normally from these models should be interpreted as long-run relations and the tests carried out using a multivariate error correction The monetary models are therefore estimated for the yen-dollar and the deutschemark-dollar over the 1973-1994 period. The induce a virtually systematic rejection of the flexible-prices model and appear considerably more favourable to the rigid-prices model.
Dette publique et taux de change dans les pays du G7 sur les deux dernières décennies
Authors: Paraponaris Alain
Published: August 2011

Dette publique et taux de change dans les pays du G7 sur les deux dernières décennies

par Alain Paraponaris

Les travaux empiriques sur le taux de change se divisent grossièrement en modèles univariés et modèles macro-économiques en économie ouverte. Les premiers n'ont aucun fondement particulier de théorie macro-économique mais présentent les meilleures performances prédictives dans le court terme. Les seconds donnent des prévisions de court terme moins bonnes, mais aident à la compréhension de l'évolution des taux de change à long terme. Ce papier présente rapidement quelques faits stylisés pour les pays du G7 en essayant de relier l'évolution récente des taux de change avec celle de la dette publique. L'étude empirique s'appuie sur des tests de cointégration, des tests de causalité au sein de modèles à correction d'erreur, des simulations de chocs sur variables et la décomposition de la variance d'erreurs de prévision. Elle permet de distinguer les pays où la relation causale va de la dette publique au taux de change (Canada, États-Unis) de ceux où la relation est inversée (Allemagne, France). La relation est bidirectionnelle pour la Grande-Bretagne et l'Italie, tandis que les résultats obtenus pour le Japon ne permettent pas de conclure.