bluuebunny/crossref_metadata_2025 huggingface dataset:
Search for New Participants in the Pathogenesis of High-Grade Serous Ovarian Cancer with the Potential to Be Used as Diagnostic Molecules
Authors: Timofeeva Angelika V. , Asaturova Aleksandra V. , Sannikova Maya V. , Khabas Grigory N. , Chagovets Vitaliy V. , Fedorov Ivan S. , Frankevich Vladimir E. , Sukhikh Gennady T.
Published: December 2022

Recent studies have attempted to develop molecular signatures of epithelial ovarian cancer (EOC) based on the quantitation of protein-coding and non-coding RNAs to predict disease prognosis. Due to the heterogeneity of EOC, none of the developed prognostic signatures were directly applied in clinical practice. Our work focuses on high-grade serous ovarian carcinoma (HGSOC) due to the highest mortality rate relative to other types of EOC. Using deep sequencing of small non-coding RNAs in combination with quantitative real-time PCR, we confirm the dualistic classification of epithelial ovarian cancers based on the miRNA signature of HGSOC (type 2), which differs from benign cystadenoma and borderline cystadenoma—precursors of low-grade serous ovarian carcinoma (type 1)—and identified two subtypes of HGSOC, which significantly differ in the level of expression of the progesterone receptor in the tumor tissue, the secretion of miR-16-5p, miR-17-5p, miR-93-5p, miR-20a-5p, the level of serum CA125, tumor size, surgical outcome (optimal or suboptimal cytoreduction), and response to chemotherapy. It was found that the combined determination of the level of miR-16-5p, miR-17-5p, miR-20a-5p, and miR-93-5p circulating in blood plasma of patients with primary HGSOC tumors makes it possible to predict optimal cytoreduction with 80.1% sensitivity and 70% specificity (p = 0.022, TPR = 0.8, FPR = 0.3), as well as complete response to adjuvant chemotherapy with 77.8% sensitivity and 90.9% specificity (p = 0.001, TPR = 0.78, FPR = 0.09). After the additional verification of the obtained data in a larger HGSOC patient cohort, the combined quantification of these four miRNAs is proposed to be used as a criterion for selecting patients either for primary cytoreduction or neoadjuvant chemotherapy followed by interval cytoreduction.
Ecophysiological and Biochemical Responses Depicting Seed Tolerance to Osmotic Stresses in Annual and Perennial Species of Halopeplis in a Frame of Global Warming
Authors: Rasheed Aysha , Rasool Sarwat Ghulam , Soriano Pilar , Estrelles Elena , Gul Bilquees , Hameed Abdul
Published: December 2022

Plant abundance and distribution are regulated by subtle changes in ecological factors, which are becoming more frequent under global climate change. Species with a higher tolerance to such changes, especially during early lifecycle stages, are highly likely to endure climate change. This study compared the germination adaptability of Halopeplis amplexicaulis and H. perfoliata, which differ in life-form and grow in different environments. Optimal conditions, tolerances and the biochemical responses of seeds to osmotic stresses were examined. Seeds of H. perfoliata germinated in a wider range of temperature regimes and were more tolerant to osmotic stresses than H. amplexicaulis seeds. Neither NaCl nor PEG treatment invoked the H2O2 content in germinating seeds of the tested species. Consequently, unaltered, or even decreased activities of H2O2 detoxification enzymes and non-enzymatic antioxidants were observed in germinating seeds in response to the aforementioned stresses. High and comparable levels of recovery from isotonic treatments, alongside a lack of substantial oxidative damage indicated that the osmotic stress, rather than the ionic toxicity, may be responsible for the germination inhibition. Hence, rainy periods, linked to water availability, may act as a key determinant for germination and H. perfoliata could be less affected by global warming owing to better germinability under high temperatures compared with H. amplexicaulis. Such studies involving biochemical analysis coupled with the germination ecology of congeneric species, which differ in life-form and occurrence are scarce, therefore are important in understanding the impacts of global changes on species abundance/distribution.
Factors Associated with the Uptake of Genetic Testing for Cancer Risks: A Pathway Analysis Using the Health Information National Trends Survey Data
Authors: Dong Xiangning , Huang Jingxian , Yi Yanze , Zhang Lanwei , Li Tenglong , Chen Ying
Published: December 2022

Our study aimed to identify pathways from the source of information to the uptake of cancer genetic testing, with consideration of intermediate variables including perceptional, attitudinal and psychosocial factors. We used the Health Information National Trends Survey (2020 database) and constructed a structural equation model for pathway analysis (using SPSS version 24). Variables for socio-demographic, lifestyle and health information were also collected and used for confounding adjustment. A total of 2941 participants were analyzed (68.5%, non-Hispanic white; 59.7%, females; 58 years, median age; and 142 (4.8%) had undertaken genetic testing for cancer risk previously). Our pathway analysis found that only information from particular sources (i.e., healthcare providers and genetic counsellors) had positive and significant effects on people’s perceptions of cancer regarding its prevention, detection and treatment (standardized β range, 0.15–0.31, all p-values < 0.01). Following the paths, these perceptional variables (cancer prevention, detection and treatment) showed considerable positive impacts on the uptake of genetic testing (standardized β (95% CIs): 0.25 (0.20, 0.30), 0.28 (0.23, 0.33) and 0.12 (0.06, 0.17), respectively). Pathways involving attitudinal and psychosocial factors showed much smaller or insignificant effects on the uptake of genetic testing. Our study brings several novel perspectives to the behavior model and may underpin certain issues regarding cancer risk genetic testing.
Content of Cadmium and Nickel in Soils and Assimilatory Organs of Park Woody Species Exposed to Polluted Air
Authors: Pivková Ivica , Kukla Ján , Hniličková Helena , Hnilička František , Krupová Danica , Kuklová Margita
Published: December 2022

The rising level of pollutant emissions is becoming one of the most pressing environmental problems of our time. Therefore, this work is focused on evaluating Cd and Ni contamination of soils and assimilatory organs of two native (Acer platanoides L., Taxus baccata L.) and two non-native (Negundo aceroides Moench, Thuja occidentalis L.) woody species in urban parks of SW Slovakia. The contents of Cd and Ni in soils were determined by the AAS method and, in the assimilatory organs of trees, by the AAS-ETA method. The studied soils (Fluvisol, Phaeozem) have neutral soil reactions and a moderate organic matter content. Cadmium soil contamination is considerable to very high; in the case of Ni, it is moderate to low. Cadmium levels detected in leaves were 31% higher than in needles, while Ni levels were 27% lower. Significant ecological factors in relation to the studied woody species were evaluated using PCA. The first three principal components of PCA significantly correlated with Cd (PC1) and Ni (PC3) contents in soils and Cd content in assimilatory organs (PC2), thus suggesting that these elements could especially originate from industrial and vehicular sources. Knowledge of the factors affecting the accumulation of risk elements in the assimilatory organs of park woody species can be successfully used, especially in the assessment of the quality of the urban environment and the selection of suitable cultivars for planting in areas with air pollution.
Multiphase Computational Fluid Dynamics of Rotary Shaft Seals
Authors: Grün Jeremias , Feldmeth Simon , Bauer Frank
Published: December 2022

The primary task of rotary shaft seals is to prevent an unwanted fluid transfer between two areas. In shaft passages of gearboxes, for example, rotary shaft seals avoid the leakage of transmission oil to ambient air. This means the flow in the lubricant film in the sealing gap between the sealing edge and the shaft surface consists of at least two phases. Taking the phenomenon of cavitation into account, the flow consists of three phases. This study aims to provide an in-depth understanding of the multiphase flow in the lubricant film of rotary shaft seals. As experimental studies of the flow processes on a microscale have proven to be quite difficult, a simulation-based approach is applied. Computational fluid dynamics (CFD) serves to compute the transient multiphase flows in the lubricant film in the sealing gap. The computational domain is a three-dimensional microscale model of the lubricant film. The results show the transient hydrodynamic pressure buildup and the dynamic phase interactions during operation. This study provides far-reaching insights into the multiphase flow processes in the lubricant film in the sealing gap and simulation-based evidence of the lubrication and sealing mechanism of rotary shaft seals.
4-Methoxyphenethyl (E)-3-(o-tolyl)acrylate
Authors: Santoso Mardi , Pamela Egar , Ramadhani Ersya Yanu , Ilfahmi Yan Alamanda , Aijijiyah Nur Pasca , Purnomo Adi Setyo , Putra Surya Rosa
Published: December 2022

4-Methoxyphenethyl (E)-3-(o-tolyl)acrylate (1) was obtained in a good yield by the reaction of 2-methylcinnamic acid, 4-methoxyphenethyl alcohol, 2-methyl-6-nitrobenzoic anhydride, 4-dimethylaminopyridine, and triethylamine at room temperature for 40 min. The structure of 4-methoxyphenethyl (E)-3-(o-tolyl)acrylate (1) was established by FTIR, NMR, and the high resolution of mass spectroscopies. 4-Methoxyphenethyl (E)-3-(o-tolyl)acrylate (1) showed higher α-glucosidase inhibition activity than standard drug acarbose. The molecular docking study exhibited that the title compound 1 had a good affinity for α-glucosidase (PDB ID: 3W37) and formed some interactions with the α-glucosidase active site residue.
Investigations on the Characterization of Various Adhesive Joints by Means of Nanoindentation and Computer Tomography
Authors: Bernaczyk Arkadiusz , Wagenführ André , Zboray Robert , Flisch Alexander , Lüthi Thomas , Vetter Birgit , Rentsch Mario , Terfloth Christian , Lincke Jörg , Krystofiak Tomasz , Niemz Peter
Published: December 2022

The mechanical properties of cured wood adhesive films were tested in a dry state by means of nanoindentation. These studies have found that the application of adhesives have an effect on the accuracy of the hardness and elastic modulus determination. The highest values of hardness among the tested adhesives at 20 °C have condensation resins: MF (0.64 GPa) and RPF (0.52 GPa). Then the decreasing EPI (0.43 GPa), PUR (0.23 GPa) and PVAc (0.14 GPa) adhesives. The values of the elastic modulus look a little bit different. The highest values among the tested adhesives at 20 °C have EPI (11.97 GPa), followed by MF (10.54 GPa), RPF (7.98 GPa), PVAc (4.71 GPa) and PUR (3.37 GPa). X-ray micro-computed tomography was used to evaluate the adhesive joint by the determination of the voids. It has been proven that this value depends on the type of adhesive, glue quantity and reactivity. The highest values of the void ratio achieve the PUR (17.26%) adhesives, then PVAc (13.97%), RRF (6.88%), MF (1.78%) and EPI (0.03%). The ratio of the gaps increases with the higher joint thickness. A too high proportion of voids may weaken the adhesive joint.
Mechanical Performance of AlCrSiN and AlTiSiN Coatings on Inconel and Steel Substrates after Thermal Treatments
Authors: Liang Jing , Almandoz Eluxka , Ortiz-Membrado Laia , Rodríguez Rafael , de Ara Jonathan Fernández , Fuentes Gonzalo G. , Llanes Luis , Jiménez-Piqué Emilio
Published: December 2022

The objective of this study was to explore the mechanical properties of AlCrSiN and AlTiSiN coatings deposited on Inconel and steel substrates after thermal treatments of 500 °C and 800 °C. Nanoindentation was used to measure the hardness and elastic modulus of the coatings, and microindentation was used for observing the contact damage with Hertzian contact loadings. Microscratch and Mercedes tests were used to evaluate the adhesive strength between coating and substrate with both progressive and static loads, respectively. The surface damage was inspected by optical microscopy and scanning electron microscopy (SEM). Focus ion beams (FIB) were used to mill the cross-sections in order to detect the extent and mode of failure. The results show that AlCrSiN coatings and Inconel substrates exhibit better mechanical performance, even after thermal treatments.
Study on Health Monitoring and Fatigue Life Prediction of Aircraft Structures
Authors: Zhang Yanjun , Wang Bintuan , Ning Yu , Xue Haifeng , Lei Xiaoxin
Published: December 2022

In this paper, some progress and achievements in aircraft integrity requirements, structural health monitoring, load spectrum measurement and life assessment research were presented. Several concepts of structural health monitoring were analyzed and compared, and the basic flow chart for health monitoring and life prediction of an aircraft structure was given. The selection of control points, construction of load/strain equations and stress calculation of control points were also described. Reliable IAT (Individual Aircraft Tracking) and life monitoring methods and software for IAT were developed for a certain type of aircraft, and fatigue life prediction of an aging aircraft was conducted based on actual measurement of load spectrum. The main features such as damage calculation, life evaluation and result output were discussed, and the future research focuses relating to intelligent structural health monitoring were finally explored.
Printability, Thermal and Compressive Strength Properties of Cementitious Materials: A Comparative Study with Silica Fume and Limestone
Authors: Srinivas Dodda , Dey Dhrutiman , Panda Biranchi , Sitharam Thallak G.
Published: December 2022

Over the past decade, 3D printing in the construction industry has received worldwide attention and developed rapidly. The research and development of cement and concrete products has also become quite well-established over the years, while other sustainable materials receive considerably lower attention in comparison. This study aims to investigate the influence of the two most commonly used sustainable cementitious materials i.e., silica fume and limestone powder, on printability, thermal and mechanical properties of fly ash–Portland cement blends. Ternary blends containing Portland cement, fly ash and silica fume or limestone powder are prepared, whereas phase change material (PCM) is introduced to improve the thermal behavior. Based on the rheological properties and concurrent 3D concrete printing, improved buildability of the modified mixtures is linked to their static yield stress. Anisotropic mechanical properties are observed for 3D printed specimens, while cast specimens exhibit a maximum 41% higher compressive strength due to better material compaction. It is clear from the results that addition of silica fume and limestone powder ranged from 5% to 10%, reducing the anisotropic mechanical properties (maximum 71% and 68% reduction in anisotropic factor, respectively) in the printed specimens. The PCM addition ranged from 5% to 10% and improved thermal performance of the mixtures, as measured by a decrease in thermal conductivity (9% and 13%) and an increase in volumetric heat capacity (9% and 10%), respectively. However, the PCM-containing mixtures show around 29% reduction in compressive strength, compared to the control specimen, which necessitates new material design considering matrix strengthening methods.
Experimental Study on Properties of Modified City Wall Soil
Authors: Pan Wei , Yue Jianwei , Yang Xue , Wang Zifa
Published: December 2022

Due to the special geographical location, climatic characteristics, special soil properties and the flood zone of the Yellow River in Kaifeng, the groundwater level in the lower reaches of the river basin is high and contains much salt. The matrix suction and surface free energy of the Kaifeng city wall earthen site changed under capillary action, resulting in cracking, peeling and efflorescence to varying degrees. In order to reduce the deterioration of the Kaifeng city wall caused by environmental erosion, a select lime with excellent mechanical properties and waterproof methanesiliconic acid sodium salt with excellent water resistance were chosen to reinforce the earthen sites. In this paper, 0%, 3%, 5% and 7% lime, and 0%, 1%, 2% and 3% waterproof materials were selected to determine four types of imitation site soil with 16 different mix proportion samples. Further, samples with different mixing ratios were subjected to direct shear, a disintegration test, and a microscopic scanning electron microscope test. The results show that under different normal stresses, with the increase in waterproof material content, the growth rate of shear strength of imitation site soil ranges from 1.82% to 10.81%. With the increase in lime content, the shear strength of imitation site soil increases rapidly, up to 38.16%. Both materials can improve the shear strength of the soil site. Under reinforcement with the two materials, the cohesive force of the imitation site soil can be improved at a maximum rate of 59.23%, and the internal friction angle changes in the range of 36.72°–41.61°. Compared with the sample without waterproof material, the mass water absorption rate of the sample with waterproof material decreases in the range of 2.76–27.77, and with the increase in waterproof material, the mass water absorption rate of the sample gradually decreases. The chemical reaction products of the waterproof materials and lime can play a filling role in silty clay; filling micro-pores and micro-cracks between soil particles.
Test on Compressive Performance of Concrete Filled Circular Steel Tube Connected by Thread through Inner Lining Tube
Authors: Wang Qingli , Zhang Yijing , Peng Kuan
Published: December 2022

The connection method of lengthening the steel tube of concrete filled circular steel tubes by inner lining tube and threaded connection is proposed. Taking the length, depth, and position of the thread as the basic parameters, 12 concrete filled circular steel tubes connected by thread through inner lining tube were designed and manufactured, and an axial compressive test was carried out. The axial compressive loading-longitudinal compressive displacement curves, axial compressive loading-strain of steel tube curves, and failure mode of the specimens were analyzed, and the effects of different parameters on the axial compressive bearing capacity and stiffness of the specimens were studied. The results show that the axial compressive loading-longitudinal compressive displacement curves of the specimen can be divided into the elastic stage, elasto-plastic stage, and plastic reinforcement stage in the range of parameters studied in this paper. The bearing capacity and stiffness of the specimens connected by thread through inner lining tube are no worse than those of the unconnected specimen or the specimen connected by weld. Bearing capacity and stiffness of the specimen increase with the increase of thread length. The calculation method of the axial compressive bearing capacity of concrete filled circular steel tubes connected by thread through inner lining tube are suggested.
Study of Metakaolinite Geopolymeric Mortar with Plastic Waste Replacing the Sand: Effects on the Mechanical Properties, Microstructure, and Efflorescence
Authors: Soares Ivana , Nobre Francisco X. , Vasconcelos Raimundo , Ramírez Miguel A.
Published: December 2022

In this study, the production of a mortar was proposed in which plastic waste replaced sand by 0%, 50%, and 100% in order to create a sustainable alternative for construction. The performance of the mortars was tested with two types of activators, one with NaOH, as a simple activator, and the other with NaOH and Na2SiO3, as a compound activator. The effects of the LDPE plastic bag waste and the activators on compressive strength, porosity, microstructure analysis, and efflorescence formation were correlated and discussed. The results showed that the replacement of sand with plastic waste at 50% and 100% proportionally reduced the compressive strength due to the increase in porosity caused by the waste, especially in the group of mortars with the simple activator, and included the formation of efflorescence. On the other hand, the compound activator increased the packing of the particles in the mortar, as observed in the images of the microstructure. This reduced porosity inhibited efflorescence and resulted in higher resistances that reached a maximum value of 22.68 MPa at 28 days in the group of 50% mortars with the compound activator. Therefore, the study showed that there is potential for the replacement of sand with plastic waste for the production of mortars, which can be considered a more sustainable building material.
Surface Texturing of Cylinder Liners: A Review
Authors: Pawlus Pawel , Koszela Waldemar , Reizer Rafal
Published: December 2022

The effect of cylinder liners on engine performance is substantial. Typically, the cylinder surfaces were plateau honed. However, recently additional dimples or grooves were created on them. This work discusses the tribological impacts of textured cylinder liner surfaces based on a review of the literature. The results of the experimental research obtained using test rigs and fired engines were critically reviewed. In addition, the results of the modeling are shown. Circular oil pockets and grooves perpendicular to the sliding direction of piston rings of small depths were typically used. Surface texturing of the cylinder liners governs lubrication between the cylinder liner and the piston ring by an increase in oil film thickness near the reversal points leading to reductions in friction force and wear and in the fired engine to a decrease in fuel consumption and to an increase in power or torque. The correct texturing pattern ensures a decrease in the oil consumption, blow-by, and emissions of the internal combustion engine compared to plateau-honed surfaces. Considerations of future challenges are also addressed. The volume of lubricant reservoir in surface topography, called oil capacity, should be a substantial parameter characterizing textured surfaces.
Probabilistic Structural Model Updating with Modal Flexibility Using a Modified Firefly Algorithm
Authors: Feng Zhouquan , Wang Wenzan , Zhang Jiren
Published: December 2022

Structural model updating is one of the most important steps in structural health monitoring, which can achieve high-precision matching between finite element models and actual engineering structures. In this study, a Bayesian model updating method with modal flexibility was presented, where a modified heuristic optimization algorithm named modified Nelder–Mead firefly algorithm (m-NMFA) was proposed to find the most probable values (MPV) of model parameters for the maximum a posteriori probability (MAP) estimate. The proposed m-NMFA was compared to the original firefly algorithm (FA), the genetic algorithm (GA), and the particle swarm algorithm (PSO) through the numerical illustrative examples of 18 benchmark functions and a twelve-story shear frame model. Then, a six-story shear frame model test was performed to identify the inter-story stiffness of the structure in the original and the damage states, respectively. By comparing the two, the position and extent of damage were accurately found and quantified in a probabilistic manner. In terms of optimization, the proposed m-NMFA was powerful to find the MPVs much faster and more accurately. In the incomplete measurement case, only the m-NMFA achieved target damage identification results. The proposed Bayesian model updating method has the advantages of high precision, fast convergence, and strong robustness in MPV finding and the ability of parameter uncertainty quantification.
Sustainable Hybrid Manufacturing of AlSi5 Alloy Turbine Blade Prototype by Robotic Direct Energy Layered Deposition and Subsequent Milling: An Alternative to Selective Laser Melting?
Authors: Dugar Jaka , Ikram Awais , Klobčar Damjan , Pušavec Franci
Published: December 2022

Additive technologies enable the flexible production through scalable layer-by-layer fabrication of simple to intricate geometries. The existing 3D-printing technologies that use powders are often slow with controlling parameters that are difficult to optimize, restricted product sizes, and are relatively expensive (in terms of feedstock and processing). This paper presents the development of an alternative approach consisting of a CAD/CAM + combined wire arc additive-manufacturing (WAAM) hybrid process utilizing the robotic MIG-based weld surfacing and milling of the AlSi5 aluminum alloy, which achieves sustainably high productivity via structural alloys. The feasibility of this hybrid approach was analyzed on a representative turbine blade piece. SprutCAM suite was utilized to identify the hybrid-manufacturing parameters and virtually simulate the processes. This research provides comprehensive experimental data on the optimization of cold metal transfer (CMT)–WAAM parameters such as the welding speed, current/voltage, wire feed rate, wall thickness, torch inclination angle (shift/tilt comparison), and deposit height. The multi-axes tool orientation and robotic milling strategies, i.e., (a) the side surface from rotational one-way bottom-up and (b) the top surface in a rectangular orientation, were tested in virtual CAM environments and then adopted during the prototype fabrication to minimize the total fabrication time. The effect of several machining parameters and robotic stiffness (during WAAM + milling) were also investigated. The mean deviation for the test piece’s tolerance between the virtual processing and experimental fabrication was −0.76 mm (approx.) at a standard deviation of 0.22 mm assessed by 3D scanning. The surface roughness definition Sa in the final WAAM pass corresponds to 36 µm, which was lowered to 14.3 µm after milling, thus demonstrating a 55% improvement through the robotic comminution. The tensile testing at 0° and 90° orientations reported fracture strengths of 159 and 161.3 MPa, respectively, while the yield stress and reduced longitudinal (0°) elongations implied marginally better toughness along the WAAM deposition axes. The process sustainability factors of hybrid production were compared with Selective Laser Melting (SLM) in terms of the part size freedom, processing costs, and fabrication time with respect to tight design tolerances. The results deduced that this alternative hybrid-processing approach enables an economically viable, resource/energy feasible, and time-efficient method for the production of complex parts in contrast to the conventional additive technologies, i.e., SLM.
Effect of Basalt Powder on Hydration, Rheology, and Strength Development of Cement Paste
Authors: Li Jiaming , Che Dehao , Liu Zhihao , Yu Lan , Ouyang Xiaowei
Published: December 2022

Basalt materials (e.g., basalt powder, aggregate, and fiber) are commonly used in cement-based materials. To understand the mechanism of the influence of basalt on the properties of cement-based materials (i.e., fluidity, hydration, and strength), zeta potential tests with different Ca2+ concentrations were carried out using basalt powder (BP). It is found that BP has a weaker absorption for Ca2+ compared to cement and quartz particles, which is directly related to its surface chemical properties. This weak absorption has a significant influence on the rheology and early-age hydration of cement paste. Moreover, the morphology of hydrate on the surface of the material observed by scanning electron microscope (SEM) also shows that the growth of CSH on the surface of BP particles is smaller than that of cement particles, indicating that BP delays the formation of CSH. Rheological tests showed that the reduction of BP’s adsorption of calcium ions weakened the electrostatic repulsion between particles, which led to the reduction of rheological properties. The influence of BP on the strength of cement paste was studied through crack characterization and fracture observation. The results show that the interfacial strength between BP and hydration products is very weak and does not increase with the hydration process, and the chemical reaction of BP is not obvious. In addition, the substitution of BP for cement leads to a dilution effect. These factors cause the strength of cement paste to decrease.
Thermal Plasma Synthesis of Different Alloys and Intermetallics from Ball Milled Al-Mo and Al-Ni Powder Systems
Authors: Khanlari Khashayar , Achouri Inès Esma , Gitzhofer Francois
Published: December 2022

Lightweight alloys have great importance for car manufacturers that aim to produce safer, lighter, and more environmentally friendly vehicles. As a result, it is essential to develop new lightweight alloys, with superior properties to conventional ones, respecting the demands of the market. Al and its alloys are good candidates for reducing the overall weight of vehicles. The objective of this research was to understand the possibility to synthesize different Al alloys and intermetallics by implementing the plasma system and using two different Al-Ni and Al-Mo powder systems. This was done by separately injecting non-reacted raw Al-Ni and Al-Mo composite powder systems into the plasma reactor. In the first step, the milling parameters were optimized to generate Al-Ni and Al-Mo composite powders, with sizes over about 30 µm, having, respectively, a homogeneous mixture of elemental Al and Ni, and Al and Mo in their particles. Each of the composite powders was then injected separately into the plasma system to provide conditions for the reaction of their elements together. The obtained Al-Ni and Al-Mo powders were then studied using different methods such as scanning electron microscopy, X-ray diffractometry, and energy dispersive X-ray analysis. Regardless of the initially used powder system, the obtained powders were consisting of large spherical particles surrounded by a cloud of fine porous particles. Different phases such as Al, AlNi3, Al3Ni2, and AlNi were detected in the particles of the Al-Ni powder system and Al, Mo, AlMo3, MoO3, and MoO2 in the Al-Mo powder system.
Effect of Hot Isostatic Pressing Process Parameters on Properties and Fracture Behavior of Tungsten Alloy Powders and Sintered Bars
Authors: Hu Biao , Cai Gaoshen
Published: December 2022

In order to investigate the effect of hot isostatic pressing (HIP) process parameters on the properties and fracture behavior of tungsten alloy, HIP experiments with different process parameters were carried out, and the relative density, Rockwell hardness, tensile properties, and tensile fracture behavior were analyzed. The results show that after HIP, the tungsten alloy samples obtained further densification, higher relative density and hardness, and lower dispersity. At 1300 °C and 140 MPa, the sintered bar achieved excellent mechanical properties: yield strength increased by 16.5%, tensile strength increased by 16.1%, and fracture strength increased by 85.3%. Comparing the two processes, the mechanical properties of tungsten alloy powders formed directly via HIP were not as good as those of the sintered bars. In addition, after HIP, the fracture mode of the tungsten alloy sintered bar samples was mainly ductile tear, and that of the tungsten alloy powder samples was mainly a full brittle fracture.
In-Composition Graded Quantum Barriers for Polarization Manipulation in InGaN-Based Yellow Light-Emitting Diodes
Authors: Cui Siyuan , Tao Guoyi , Gong Liyan , Zhao Xiaoyu , Zhou Shengjun
Published: December 2022

Highly efficient indium gallium nitride (InGaN)-based yellow light-emitting diodes (LEDs) with low efficiency droop have always been pursued for next-generation displays and lighting products. In this work, we report an InGaN quantum barrier (QB) with linear-increase In-composition along [0001] direction for InGaN-based yellow LEDs. With the In-composition in QBs systematically engineered, three QB structures including linear-increase QB (LIQB), linear-decrease QB (LDQB) and commonly used flat QB (FQB) were investigated by simulation. The results show that the LIQB not only yields enhanced electron confinement, but also contributes to suppressed polarization field. Consequently, the yellow LED incorporated with LIQBs demonstrates improved radiative recombination rates and the efficiency droop is alleviated. Under a current density of 100 A/cm2, the efficiency droop ratios of LEDs with FQBs, LDQBs and LIQBs are 58.7%, 62.2% and 51.5%, respectively. When current density varies from 1 A/cm2 to 60 A/cm2, the blueshift values of peak emission wavelength for LEDs with FQBs, LDQBs and LIQBs are 14.4 nm, 16.5 nm and 13.0 nm, respectively. This work is believed to provide a feasible solution for high-performance InGaN-based LEDs in long-wavelength spectral region.
Kinetic Mechanisms and Emissions Investigation of Torrefied Pine Sawdust Utilized as Solid Fuel by Isothermal and Non-Isothermal Experiments
Authors: Liu Xiaorui , Li Dong , Yang Jiamin , Yuan Longji
Published: December 2022

This study comprehensively investigated the utilization of torrefied pine sawdust (PS) as solid fuels, involving the characterization of torrefied PS properties, the investigation of combustion behaviors and kinetic mechanisms by non-isothermal experiments, and the evaluation of emissions during isothermal experiments. Results show that torrefaction significantly improved the quality of the solids. The upgradation of torrefied PS properties then further enhanced its combustion performance. For the kinetics mechanisms, degradation mechanisms and diffusion mechanisms were respectively determined for the volatile combustion and the char combustion by using both Coats–Redfern (CR) and Freeman–Carroll (FC) methods. Further, after torrefaction, the emission of NO for volatile combustion reduced while it increased for char combustion. An inverse relationship was found between the conversion of fuel-N to NO and the nitrogen content in the torrefied samples. This study provided comprehensive insights for considering torrefaction as a pretreatment technique for PS utilization as a solid fuel.
Advanced Eco-Friendly Wood-Based Composites
Authors: Reh Roman , Kristak Lubos , Antov Petar
Published: December 2022

In collaboration with the MDPI publishing house, we are pleased to introduce the reader to our new project, the Special Issue entitled “Advanced Eco-friendly Wood-Based Composites” [...]
Various Substitute Aggregate Materials for Sustainable Concrete
Authors: Choi Se-Jin , Oh Jae-Eun , Yoon Se-Yoon
Published: December 2022

Concrete is one of the most widely used structural construction materials and has significantly influenced industrial development [...]
Non-Isothermal Dynamic Mechanical Analysis of Ribbon Metallic Glasses and Its Thermodynamic Description
Authors: Berezner Arseniy , Fedorov Victor
Published: December 2022

In this work, derivation of the main thermodynamic relationships is realized together with the applied calculation of some parameters, providing the systematized description of non-linear thermo-mechanical deformation at dynamic mechanical analysis (DMA). Obtained equations and values agree well with experiments on different ribbon metallic glasses. We generalize the main initial conditions (i.e., experimental and numerical parameters) by that the proposed model can be used for the investigation of DMA in different materials. The further opportunities of the found approach are also discussed in frames of phase transitions in metallic glass.
Low Core Losses of Fe-Based Soft Magnetic Composites with an Zn-O-Si Insulating Layer Obtained by Coupling Synergistic Photodecomposition
Authors: Wang Siyuan , Zheng Jingwu , Zheng Danni , Qiao Liang , Ying Yao , Tang Yiping , Cai Wei , Li Wangchang , Yu Jing , Li Juan , Che Shenglei
Published: December 2022

The major method used to reduce the magnetic loss of soft magnetic composites (SMCs) is to coat the magnetic powder with an insulating layer, but the permeability is usually sacrificed in the process. In order to achieve a better balance between low losses and high permeability, a novel photodecomposition method was used in this study to create a ZnO insulating layer. The effect of the concentration of diethyl zinc on the formation of a ZnO insulating film by photodecomposition was studied. The ZnO film was best formed with a diethyl zinc n-hexane solution at a concentration of around 0.40 mol/L. Combined with conventional coupling treatment processes, a thin and dense insulating layer was coated on the surface of iron powder in situ. Treating the iron powder before coating by photodecomposition led to a synergistic effect, significantly reduced core loss, and the effective permeability only decreased slightly. An iron-based soft magnetic composite with a loss value of 124 kW/m3 and an effective permeability of 107 was obtained at the frequency of 100 kHz and a magnetic field intensity of 20 mT.
The Biomechanical Impact of Loss of an Implant in the Treatment with Mandibular Overdentures on Four Nonsplinted Mini Dental Implants: A Finite Element Analysis
Authors: Teodorescu Cristian , Preoteasa Elena , Preoteasa Cristina Teodora , Murariu-Măgureanu Cătălina , Teodorescu Ioana Monica
Published: December 2022

The aim of this study was to evaluate the biomechanical impact, in terms of stress and displacement, at the level of a mandibular overdenture, on four mini dental implants (MDIs) after the loss of an implant. A three-dimensional virtual model was obtained by scanning the overdenture, and a biomechanical analysis was carried out, using the finite element method (FEM). The displacements of the overdenture and the equivalent von Mises stresses were evaluated using logarithmic scales. In the case of a mandibular overdenture on four MDIs inserted in the interforaminal area, the frontal loading generated the lowest values for the von Mises stresses, and the bilateral loading generated the least displacement when two implants were inserted in the canine area and two in the molar area. The highest von Mises stress was observed during frontal loading in the situation of the mandibular overdenture on four MDIs, two of which were inserted in the canine area and two in the molar area, following the loss of an implant in the canine area. The largest displacement was noted in the mandibular overdenture on four interforaminal MDIs during unilateral loading, following the loss of a distally inserted implant. The FEM analysis showed aspects that correlated with clinical observations, with predictive value. The concentration of von Mises stresses, and the occurrence of some displacements of the prosthodontic restoration, can explain the emergence of some complications in the overdenture’s biodynamics, and the increased risk of fracture. Complications can be prevented by choosing a certain number of implants and a topographical distribution correlated with biomechanical aspects, and by proposing a correct occlusal scheme with optimal functional loading.
Multi-Level Support Technology and Application of Deep Roadway Surrounding Rock in the Suncun Coal Mine, China
Authors: Chu Hengbin , Li Guoqing , Liu Zhijun , Liu Xuesheng , Wu Yunhao , Yang Shenglong
Published: December 2022

To solve these problems of poor supporting effect and serious deformation and failure of surrounding rock of mining roadway under deep mining stress, a FLAC-3D numerical calculation model is established with −800 m level no. 2424 upper roadway in the Suncun Coal Mine as the background to compare the stress, deformation, and failure law of surrounding rock of mining roadway under once support and multi-level support with the same support strength. It is found that the multi-level support technology has obvious advantages in the surrounding rock of the horizontal roadway on the 2424 working face. From this, the key parameters of multi-level support are determined, and the field industrial test is carried out. The results show that the overall deformation of the surrounding rock is obviously reduced after multi-level support. The displacement of the two sides is reduced by about 40%, the displacement of the roof and floor is reduced by about 30%, and the plastic zone of the roadway is reduced by about 75%. The peak value of concentrated stress decreases from 98.7 MPa to 95.8 MPa, which decreases slightly. The integrity and stability of the surrounding rock are excellent, and the support effect is satisfactory. The research can provide reference and technical support for surrounding rock control of deep high-stress mining roadways.
New Pressure-Sensitive Acrylic Adhesives for Low Energy Substrates Prepared via UV-Induced Telomerization with a Fluorine-Based Telogen
Authors: Kowalczyk Agnieszka , Kraśkiewicz Agata , Kowalczyk Krzysztof
Published: December 2022

Novel pressure-sensitive adhesives (PSA) for low energy substrates were prepared by a solvent-free UV-initiated telomerization process using n-butyl acrylate, butyl methacrylate, and lauryl methacrylate (LMA), with trifluoroethanol (TFEtOH) as a telogen, and acylphosphine oxide (APO) as a radical photoinitiator. A crosslinking monomer (an aliphatic urethane acrylate, L9033) and a radical UV-photoinitiator (α-hydroxyalkylphenone) were also tested as components of the adhesive compositions. The influence of LMA and TFEtOH on the UV-phototelomerization process kinetics and the physicochemical features of the obtained fluorotelomers, as well as the concentration of L9033 on the PSA adhesion to a polyethylene surface, were investigated. FT-IR results indicated that the fluorine groups were successfully introduced into the telomer structure. The highest adhesion relative to a polyethylene substrate (12.3 N/25 mm), and the highest hydrophobicity (with a contact angle of 95° for a water/PSA system) were observed for adhesives based on a telomer syrup containing 5 wt. parts of TFEtOH and 30 wt. parts of LMA (per 100 wt. parts of the monomer mixture). Additionally, it was revealed that a higher aliphatic urethane acrylate content and a higher UV dose increased the adhesion feature.
The Influence of Oxidation on the Magnetic, Electrical, and Mechanical Properties of Co40Fe40Yb20 Films
Authors: Liu Wen-Jen , Chang Yung-Huang , Chiang Chia-Chin , Chen Yuan-Tsung , Chen Ying-Hsuan , You Hui-Jun , Wu Te-Ho , Lin Shih-Hung , Chi Po-Wei
Published: December 2022

A typical body-centered cubic (BCC) CoFe(110) peak was discovered at approximately 2θ = 44.7°. At 2θ = 46°, 46.3°, 47.7°, 55.4°, 54.6°, and 56.4°, the Yb2O3 and Co2O3 oxide peaks were visible in all samples. However, with a heat treatment temperature of 300 °C, there was no typical peak of CoFe(110). Electrical characteristics demonstrated that resistivity and sheet resistance reduced dramatically as film thickness and annealing temperatures increased. At various heat treatments, the maximum hardness was 10 nm. The average hardness decreased as the thickness increased, and the hardness trend decreased slightly as the annealing temperature was higher. The highest low-frequency alternative-current magnetic susceptibility (χac) value was discovered after being annealed at 200 °C with 50 nm, and the optimal resonance frequency (fres) was discovered to be within the low-frequency range, indicating that the Co40Fe40Yb20 film can be used in low-frequency applications. The maximum saturation magnetization (Ms) was annealed at 200 °C for 50 nm. Thermal disturbance caused the Ms to decrease as the temperature reached to 300 °C. The results show that when the oxidation influence of as-deposited and thinner films is stronger than annealing treatments and thicker thickness, the magnetic and electrical properties can be enhanced by the weakening peak of the oxide, which can also reduce interference.
The Synergistic Effect of Polyphosphates Acid and Different Compounds of Waste Cooking Oil on Conventional and Rheological Properties of Modified Bitumen
Authors: Wang Wentong , Li Jin , Wang Di , Liu Pengfei , Li Xinzhou
Published: December 2022

In order to conserve non-renewable natural resources, waste cooking oil (WCO) in bitumen can help lower CO2 emissions and advance the environmental economy. In this study, three different components of WCO were isolated and then, together with polyphosphoric acid (PPA), used separately as bitumen modifiers to determine the suitability of various substances in WCO with PPA. Conventional tests, including penetration, softening point temperature, and ductility, and the dynamic shear rheology (DSR) test, including temperature sweep and frequency sweep, were used to evaluate the influence of WCO/PPA on the traditional performance and rheological properties at high and low temperatures. The results indicate that WCO reduced the ductility and penetration value, when the use of PPA increased the softening point temperature and high-temperature performance. Compared to reference bitumen, the rutting factor and viscous activation energy (Ea) of bitumen modified with 4% WCO and 2% PPA has the most significant increase by 18.6% and 31.5, respectively. All components of WCO have a significant impact on improving the low-temperature performance of PPA-modified bitumen. The performance of the composite-modified bitumen at low temperatures is negatively affected by some waxy compounds in WCO, such as methyl palmitate, which tends to undergo a solid–liquid phase change as the temperature decreases. In conclusion, the inclusion of WCO/PPA in bitumen offers a fresh approach to developing sustainable pavement materials.
Study of Internal Stress in Conductive and Dielectric Thick Films
Authors: Hlina Jiri , Reboun Jan , Janda Martin , Hamacek Ales
Published: December 2022

This paper is focused on the study of internal stress in thick films used in hybrid microelectronics. Internal stress in thick films arises after firing and during cooling due to the differing coefficients of thermal expansion in fired film and ceramic substrates. Different thermal expansions cause deflection of the substrate and in extreme cases, the deflection can lead to damage of the substrate. Two silver pastes and two dielectric pastes, as well as their combinations, were used for the experiments, and the internal stress in the thick films was investigated using the cantilever method. Further experiments were also focused on internal stress changes during the experiment and on the influence of heat treatment (annealing) on internal stress. The results were correlated with the morphology of the fired thick films. The internal stress in the thick films was in the range of 8 to 21 MPa for metallic films and in the range from 12 to 16 MPa for dielectric films. It was verified that the cantilever method can be successfully used for the evaluation of internal stress in thick films. It was also found that the values of deflection and internal stress are not stable after firing, and they can change over time, mainly for metallic thick films.