bluuebunny/crossref_metadata_2025 huggingface dataset:
Environmentally Friendly Polymer Blends Based on Post-Consumer Glycol-Modified Poly(Ethylene Terephthalate) (PET-G) Foils and Poly(Ethylene 2,5-Furanoate) (PEF): Preparation and Characterization
Authors: Paszkiewicz Sandra , Irska Izabela , Piesowicz Elzbieta
Published: June 2020

Environmentally friendly polymer blends between post-consumer PET-G and bio-based poly(ethylene 2,5 furanoate) (PEF) have been prepared. The PET-G granules were obtained from the post-consumer glycol-modified poly(ethylene terephthalate) PET-G foils from Nicrometal S.A. as a result of materials recycling. PEF was synthesized from dimethyl furan-2,5-dicarboxylate and 1,2-ethylene glycol (BioUltra) by a two-stage melt polycondensation process. According to the calculations followed by Hoy’s method, one has studied the miscibility of the components in the blend. The molecular structure of PET-G/PEF blends was analyzed by Fourier Transform Infrared Spectroscopy (FTIR) spectroscopy, while the morphology of the blends was determined by Scanning Electron Microscopy (SEM). To evaluate phase transition temperatures, as well as the thermal effects in PET-G/PEF blends, Differential Scanning Calorimetry (DSC), Dynamic Mechanical Thermal Analysis (DMTA), and Thermogravimetric Analysis (TGA), were performed. Tensile tests revealed that along with an increase in the amount of PEF, an increase in Young’s modulus was observed. Besides, the existence of interfacial interactions between polymers, especially in the case of PET-G/PEF 80/20, enabling the PET-G chains to form a network structure with the PEF by reacting with their functional groups, allows observation of a synergistic effect in the improvement of thermal stability and water absorption.
Efficiency Enhanced Grating Coupler for Perfectly Vertical Fiber-to-Chip Coupling
Authors: Zhang Zan , Shan Xiaotao , Huang Beiju , Zhang Zanyun , Cheng Chuantong , Bai Bing , Gao Tianxi , Xu Xiaobo , Zhang Lin , Chen Hongda
Published: June 2020

In this work, a bidirectional grating coupler for perfectly vertical coupling is proposed. The coupling efficiency is enhanced using a silicon nitride (Si3N4) layer above a uniform grating. In the presence of Si3N4 layer, the back-reflected optical power into the fiber is diminished and coupling into the waveguide is increased. Genetic algorithm (GA) is used to optimize the grating and Si3N4 layer simultaneously. The optimal design obtained from GA shows that the average in-plane coupling efficiency is enhanced from about 57.5% (−2.5 dB) to 68.5% (−1.65 dB), meanwhile the average back-reflection in the C band is reduced from 17.6% (−7.5 dB) to 7.4% (−11.3 dB). With the help of a backside metal mirror, the average coupling efficiency and peak coupling efficiency are further increased to 87% (−0.6 dB) and 89.4% (−0.49 dB). The minimum feature size of the designed device is 266 nm, which makes our design easy to fabricate through 193 nm deep-UV lithography and lowers the fabrication cost. In addition, the coupler proposed here shows a wide-band character with a 1-dB bandwidth of 64 nm and 3-dB bandwidth of 96 nm. Such a grating coupler design can provide an efficient and cost-effective solution for vertical fiber-to-chip optical coupling of a Wavelength Division Multiplexing (WDM) application.
Wear Behavior of Ductile Iron Wheel Material Used for Rail-Transit Vehicles under Dry Sliding Conditions
Authors: Tong Lifeng , Zou Qingchuan , Jie Jinchuan , Li Tingju , Wang Zhixin
Published: June 2020

A ductile iron wheel used for a rail-transit vehicle was treated with a recommended heat-treatment process. The ductile iron wheel after heat treatment was composed of graphite nodules and tempered sorbite with an area fraction of 98%. A friction test of the ductile iron and carbon steel wheel materials was systematically performed under different normal loads and sliding velocities. The results indicated that the wear mechanism of the ductile iron wheel changed from adhesion to abrasion with an increase in the normal load level. Adhesion was the main wear mechanism at different sliding velocities and normal load level. The impact of the normal load on the wear mechanism was greater than that of the sliding velocity. Since the ductile iron wheel material had excellent thermal property and higher carbon content, it exhibited a lower wear rate, a smaller difference value of the friction coefficient, and plastic deformation on the worn surface than those of the carbon steel wheel material. This indicates that ductile iron wheels may have a longer wear life, greater traction, and higher stability during operation than carbon steel wheels. The iron wheels have the potential for being applied in rail-transit vehicles.
Minimizing the Micro-Edge Damage at Each Constituent Layer of the Clad Composite during AWJM
Authors: Ishfaq Kashif , Ahmed Naveed , Rehman Ateekh Ur , Hussain Amjad , Umer Usama , Al-Zabidi Ayoub
Published: June 2020

The development of layered/clad composites with a blend of desired characteristics has emerged as a valuable substitute for expensive materials. The inherent heterogeneity offers challenges whenever the cutting of cladded plates/sheets is to be done. The conventional means of cutting such as gas/plasma arc yield a poor cut quality and heat-affected zones. Abrasive waterjet machining (AWJM) is a valuable alternative to mitigate the aforesaid cutting issues. However, the intrinsic attribute of edge damage during AWJM poses a limitation on its use, especially for precision applications. Specifically, it is challenging to control the edge damage in terms of pit depth at both the constituent clad layers and addressing this challenge is the novelty of this work. The said cutting accuracy issues have been thoroughly investigated herein. Four key control parameters of AWJM have been selected for evaluating their impact during machining of stainless-clad steel using L18 Taguchi design. Experimental results have been thoroughly examined using statistical and microscopical evidence. The optimal parametric combination resulting in the minimum magnitude of pit depth at both the clad layers has been developed and experimentally validated. The magnitude of pits depth realized at stainless steel layer (SSL) and mild steel layer (MSL) significantly reduced to 5 µm and 4 µm respectively, at the optimal parametric combination.
The Influence of Laser Surface Remelting on the Tribological Behavior of the ECAP-Processed AZ61 Mg Alloy and AZ61–Al2O3 Metal Matrix Composite
Authors: Ballóková Beáta , Falat Ladislav , Puchý Viktor , Molčanová Zuzana , Besterci Michal , Džunda Róbert , Abbas Aqeel , Huang Song-Jeng
Published: June 2020

This paper deals with the tribological study of the laser remelted surfaces of the ECAP-processed AZ61 magnesium alloy and AZ61–Al2O3 metal matrix composite with 10 wt.% addition of Al2O3 nanoparticles. The study included the experimental optimization of the laser surface remelting conditions for the investigated materials by employing a 400 W continual wave fiber laser source. Tribological tests were performed in a conventional “ball-on-disc” configuration with a ceramic ZrO2 ball under a 5 N normal load and a sliding speed of 100 mm/s. The results showed that both the incorporation of Al2O3 nanoparticles and the applied laser treatments led to recognizable improvements in the tribological properties of the studied AZ61–Al2O3 composites in comparison with the reference AZ61 alloy. Thus, the best improvement has been obtained for the laser modified AZ61–10 wt.% Al2O3 nanocomposite showing about a 48% decrease in the specific wear rate compared to the laser untreated AZ61 base material.
Frictional Heating during Braking of the C/C Composite Disc
Authors: Yevtushenko Aleksander , Kuciej Michal , Topczewska Katarzyna
Published: June 2020

An analytical model to determine temperature in a single brake disc of multi-disc system is proposed. The model considers the convective cooling on the lateral surfaces of the disc and structure of composite friction material. Calculations were carried out for a disc made of carbon friction composites material Termar-ADF. The influence of heat transfer with environment, length of bundles with fibers, and concentration of fibers in composite on the temperature of the disc was investigated during single braking with constant deceleration.
Sirolimus-Eluting Electrospun-Produced Matrices as Coatings for Vascular Stents: Dependence of Drug Release on Matrix Structure and Composition of the External Environment
Authors: Nazarkina Zhanna K. , Chelobanov Boris P. , Chernonosova Vera S. , Romanova Irina V. , Karpenko Andrey A. , Laktionov Pavel P.
Published: June 2020

Although a number of drug-eluting coatings for vascular stents (VSs) have been developed and are in commercial use, more efficient stent coatings and drug delivery systems are needed. Sirolimus (SRL) is a clinically important drug with antiproliferative and immunosuppressive activities that is widely used for coating stents. Here, we characterized SRL-enriched matrices, intended for coating vascular stents, that were produced by electrospinning (ES) on a drum collector from a solution of polycaprolactone (PCL) and human serum albumin (HSA), 1,1,1,3,3,3-hexafluoroisopropanol (HFIP), dimethyl sulfoxide (DMSO), and SRL. The release of tritium-labeled SRL (3H-SRL) from matrices in phosphate-buffered saline (PBS) or human blood plasma (BP) was studied. The introduction of DMSO in the ES blend decreased SRL release. The use of BP significantly accelerated SRL release through binding with serum biomolecules. The exchange of PBS or BP after every time point also increased SRL release. The maximum SRL release in BP was observed at 3 days. The matrices produced from the ES solution with DMSO and HSA released no more than 80% SRL after 27 days in BP, even under medium exchange conditions. Therefore, PCL-based matrices containing HSA, SRL, and DMSO can be used for coating VSs with prolonged SRL delivery.
Development of a 3-D Physical Dynamics Monitoring System Using OCM with DVC for Quantification of Sprouting Endothelial Cells Interacting with a Collagen Matrix
Authors: Kang Yong Guk , Jang Hwanseok , Park Yongdoo , Kim Beop-Min
Published: June 2020

The extracellular matrix (ECM) plays a key role during cell migration, proliferation, and differentiation by providing adhesion sites and serving as a physical scaffold. Elucidating the interaction between the cell and ECM can reveal the underlying mechanisms of cellular behavior that are currently unclear. Analysis of the deformation of the ECM due to cell–matrix interactions requires microscopic, three-dimensional (3-D) imaging methods, such as confocal microscopy and second-harmonic generation microscopy, which are currently limited by phototoxicity and bleaching as a result of the point-scanning approach. In this study, we suggest the use of optical coherence microscopy (OCM) as a live-cell, volumetric, fast imaging tool for analyzing the deformation of fibrous ECM. We optimized such OCM parameters as the sampling rate to obtain images of the best quality that meet the requirements for robust digital volume correlation (DVC) analysis. Visualization and analysis of the mechanical interaction between collagen ECM and human umbilical vein endothelial cells (HUVECs) show that cellular adhesion during protrusion can be analyzed and quantified. The advantages of OCM, such as fine isotropic spatial resolution, fast time resolution, and low phototoxicity, make it the ideal optic tool for 3-D traction force microscopy.
Effect of MWCNTs on Wear Behavior of Epoxy Resin for Aircraft Applications
Authors: Mucha Mateusz , Krzyzak Aneta , Kosicka Ewelina , Coy Emerson , Kościński Mikołaj , Sterzyński Tomasz , Sałaciński Michał
Published: June 2020

The aim of the study is to assess the effect of multi-walled carbon nanotubes (MWCNTs) on the wear behavior of MWCNT-doped epoxy resin. In this study, a laminating resin system designed to meet the standards for motor planes was modified with MWCNTs at mass fractions from 0.0 wt.% to 2.0 wt.%. The properties of the carbon nanotubes were determined in Raman spectroscopy and HR-TEM. An examination of wear behavior was conducted on a linear abraser with a visual inspection on an optical microscope and SEM imaging, mass loss measurement, and evaluation of the wear volume on a profilometer. Moreover, the mechanical properties of MWCNTs/epoxy nanocomposite were evaluated through a tensile test and Shore D hardness test. The study shows that the best wear resistance is achieved for the mass percentage between 0.25 wt.% and 0.5 wt.%. For the same range, the tensile strength reaches the highest values and the hardness the lowest values. Together with surface imaging and a topography analysis, this allowed describing the wear behavior in the friction node and the importance of the properties of the epoxy nanocomposite.
Influence of Micro-Pore Connectivity and Micro-Fractures on Calcium Leaching of Cement Pastes—A Coupled Simulation Approach
Authors: Perko Janez , Ukrainczyk Neven , Šavija Branko , Phung Quoc Tri , Koenders Eddie A. B.
Published: June 2020

A coupled numerical approach is used to evaluate the influence of pore connectivity and microcracks on leaching kinetics in fully saturated cement paste. The unique advantage of the numerical model is the ability to construct and evaluate a material with controlled properties, which is very difficult under experimental conditions. Our analysis is based on two virtual microstructures, which are different in terms of pore connectivity but the same in terms of porosity and the amount of solid phases. Numerical fracturing was performed on these microstructures. The non-fractured and fractured microstructures were both subjected to chemical leaching. Results show that despite very different material physical properties, for example, pore connectivity and effective diffusivity, the leaching kinetics remain the same as long as the amount of soluble phases, i.e., buffering capacity, is the same. The leaching kinetics also remains the same in the presence of microcracks.
3D-Printing for Transformation Optics in Electromagnetic High-Frequency Lens Applications
Authors: Poyanco Jose-Manuel , Pizarro Francisco , Rajo-Iglesias Eva
Published: June 2020

This article presents the design, construction and analysis of a 3D-printed transformed hyperbolic flat lens working on the 30 GHz band. The transformed lens was printed using only one ABS dielectric filament of relative permittivity of 12, varying the infill percentage of each transformed lens section in order to achieve the permittivity values obtained with the transformation optics. The 3D-printed hyperbolic transformed lens exhibits good radiation performance compared to the original canonical lens.
Poly(2-oxazoline) Matrices with Temperature-Dependent Solubility—Interactions with Water and Use for Cell Culture
Authors: Oleszko-Torbus Natalia , Bochenek Marcelina , Utrata-Wesołek Alicja , Kowalczuk Agnieszka , Marcinkowski Andrzej , Dworak Andrzej , Fus-Kujawa Agnieszka , Sieroń Aleksander L. , Wałach Wojciech
Published: June 2020

In this work, we studied the stability of matrices with temperature-dependent solubility and their interactions with water at physiological temperature for their application in cell culture in vitro. Gradient copolymers of 2-isopropyl- with 2-n-propyl-2-oxazoline (P(iPrOx-nPrOx)) were used to prepare the matrices. The comonomer ratio during polymerization was chosen such that the cloud point temperature (TCP) of the copolymer was below 37 °C while the glass transition (Tg) was above 37 °C. The role of the support for matrices in the context of their stability in aqueous solution was examined. Therefore, matrices in the form of both self-supported bulk polymer materials (fibrillar mats and molds) and polymer films supported on the silica slides were examined. All of the matrices remained undissolved when incubated in water at a temperature above TCP. For the self-supported mats and molds, we observed the loss of shape stability, but, in the case of films supported on silica slides, only slight changes in morphology were observed. For a more in-depth investigation of the origin of the shape deformation of self-supported matrices, we analyzed the wettability, thickness, and water uptake of films on silica support because the matrices remained undeformed under these conditions. It was found that, above the TCP of P(iPrOx-nPrOx), the wettability of the films decreased, but at the same time the films absorbed water and swelled. We examined how this specific behavior of the supported films influenced the culture of fibroblasts. The temperature-dependent solubility of the matrices and the possibility of noninvasive cell separation were also examined.
Superplastic Deformation Mechanisms in Fine-Grained 2050 Al-Cu-Li Alloys
Authors: Li Hongping , Liu Xiaodong , Sun Quan , Ye Lingying , Zhang Xinming
Published: June 2020

The deformation behavior and microstructural evolution of fine-grained 2050 alloys at elevated temperatures and slow strain rates were investigated. The results showed that significant dynamic anisotropic grain growth occurred at the primary stage of deformation. Insignificant dislocation activity, particle-free zones, and the complete progress of grain neighbor switching based on diffusion creep were observed during superplastic deformation. Quantitative calculation showed that diffusion creep was the dominant mechanism in the superplastic deformation process, and that grain boundary sliding was involved as a coordination mechanism. Surface studies indicated that the diffusional transport of materials was accomplished mostly through the grain boundary, and that the effect of the bulk diffusion was not significant.
Experimental Assessment of Time-Limited Operation and Rectification of a Bridge Crane
Authors: Frankovský Peter , Delyová Ingrid , Sivák Peter , Kurylo Piotr , Pivarčiová Elena , Neumann Vojtech
Published: June 2020

This paper describes a problem related to a casting bridge crane with a combined load of 200/50/12.5 t and a span of 18.6 m, working in a heavy metallurgical operation. Due to the specific stress of the structure after its long-term operation, longitudinal fillet welds between the upper flange and the web of the main box beam on the rail side of the 200 t trolley were irreparably damaged. As a result, the cross-section of the main beam had opened, thereby substantially reducing its strength and stiffness. This resulted in a disproportionate increase and undesirable redistribution of stresses in the beam and, at the same time, an increase in the probability of acute fatigue or the loss of stability of the elastic beam shape. Therefore, the rectification of the damaged load-bearing structure was carried out by specific structural modifications. Critical load-bearing elements were subjected to complicated strength and fatigue life analyses before and after rectification. These analyses were supported by experimental measurements. The applied modifications resulted in a partial strengthening of the lifting device with the possibility of its further operation, but only in a limited mode, with a limited period of operation with a time limit of 2 years and a reduced total load capacity of 150 t. The applied methods are also applicable for the fatigue analysis of load-bearing elements and equipment for bridge, gantry and tower cranes, crane tracks, road and railway bridges and support structures under machinery and other devices with a dominant transverse and rotating effect.
Using Environmental Simulations to Test the Release of Hazardous Substances from Polymer-Based Products: Are Realism and Pragmatism Mutually Exclusive Objectives?
Authors: Bandow Nicole , Aitken Michael D. , Geburtig Anja , Kalbe Ute , Piechotta Christian , Schoknecht Ute , Simon Franz-Georg , Stephan Ina
Published: June 2020

The potential release of hazardous substances from polymer-based products is currently in the focus of environmental policy. Environmental simulations are applied to expose such products to selected aging conditions and to investigate release processes. Commonly applied aging exposure types such as solar and UV radiation in combination with water contact, corrosive gases, and soil contact as well as expected general effects on polymers and additional ingredients of polymer-based products are described. The release of substances is based on mass-transfer processes to the material surfaces. Experimental approaches to investigate transport processes that are caused by water contact are presented. For tailoring the tests, relevant aging exposure types and release quantification methods must be combined appropriately. Several studies on the release of hazardous substances such as metals, polyaromatic hydrocarbons, flame retardants, antioxidants, and carbon nanotubes from polymers are summarized exemplarily. Differences between natural and artificial exposure tests are discussed and demonstrated for the release of flame retardants from several polymers and for biocides from paints. Requirements and limitations to apply results from short-term artificial environmental exposure tests to predict long-term environmental behavior of polymers are presented.
Effects of Different Ions and Temperature on Corrosion Behavior of Pure Iron in Anoxic Simulated Groundwater
Authors: Li Teng , Huang Guokai , Feng Yanpeng , Yang Miao , Wang Lingyu , Cui Daqing , Zhang Xian
Published: June 2020

As a typical material of the insert in high-level radioactive waste (HLW) geological disposal canisters, iron-based materials will directly contact with groundwater after the failure of a metallic canister, acting as a chemical barrier to prevent HLW leaking into groundwater. In this paper, anoxic groundwater was simulated by mixing 10 mM NaCl and 2 mM NaHCO3 purged by Ar gas (containing 0.3% CO2) with different added ions (Ca2+, CO32− and SiO32−) and operation temperatures (25, 40 and 60 °C). An electrochemical measurement, immersion tests and surface characterization were carried out to study the corrosion behavior of pure iron in the simulated groundwater. The effects of Ca2+ on the corrosion behavior of iron is negligible, however, Cl− plays an important role in accelerating the corrosion activity with the increased concentration and temperature. With increased concentrations of CO32− and SiO32−, the corrosion resistance of iron is largely improved, which is attributed to the formation of a uniform passivation film. The independent effects of temperature on the corrosion behavior of iron are resulted from the repeated passivation–dissolution processes in the formation of the passivation film, resulting from the synergistic effects of CO32−/SiO32− and Cl−. The formation of ferric silicate is dominant in the passivation film with the addition of SiO32−, which effectively protects the iron surface from corrosion.
Utilization of Ethylcellulose Microparticles with Rupatadine Fumarate in Designing Orodispersible Minitablets with Taste Masking Effect
Authors: Wasilewska Katarzyna , Ciosek-Skibińska Patrycja , Lenik Joanna , Srčič Stanko , Basa Anna , Winnicka Katarzyna
Published: June 2020

Minitablets in orodispersible form constitute a flexible drug delivery tool for paediatric and geriatric population as they eliminate the risk of chocking and do not require drinking water in the application. Due to their direct contact with taste buds, taste sensation is an important factor. Preparing microparticles with taste masking polymers utilizing spray drying is an efficient technique for reducing the bitterness of drugs. Ethylcellulose is a hydrophobic polymer widely used as a taste masking material. Rupatadine fumarate, one of the newest antihistamines, features an intensive bitter taste, hence in designing orodispersible formulations, achieving an acceptable taste is a crucial issue. The main objective of this work was to formulate orodispersible minitablets containing taste masked ethylcellulose-based microparticles with rupatadine fumarate and evaluation of their quality, especially in terms of taste masking efficacy. The accessed data indicated that all obtained minitablets were characterized by beneficial pharmaceutical properties. Three independent methods: in vivo with healthy volunteers, in vitro drug dissolution, and “electronic tongue” confirmed that all designed formulations provided satisfactory taste masking rate and that formulation F15 (prepared with Pearlitol® Flash and Surelease® microparticles with rupatadine fumarate) was characterized by the lowest bitterness score.
Microstructure Characterisation and Identification of the Mechanical and Functional Properties of a New PMMA-ZnO Composite
Authors: Rudolf Rebeka , Popović Danica , Tomić Sergej , Bobovnik Rajko , Lazić Vojkan , Majerič Peter , Anžel Ivan , Čolić Miodrag
Published: June 2020

In this research work, we synthesised poly(methyl methacrylate) (PMMA) enriched with 2 wt.% zinc oxide nanoparticles (ZnO) through conventional heat polymerisation and characterised its microstructure. It was found that the distribution of ZnO nanoparticles was homogeneous through the volume of the PMMA. The mechanical testing of the PMMA-ZnO composite primarily included the determination of the compressive properties on real dentures, while density measurements were performed using a pycnometer. The testing of functional properties involved the identification of the colour of the new PMMA-ZnO composite, where pure PMMA acted as a control. In the second step, the PMMA-ZnO cytotoxicity assays were measured in vitro, which were shown to be similar to the control PMMA. Based on this, it could be concluded that the newly formed PMMA-ZnO composite did not induce direct or indirect cytotoxic effects in L929 cell cultures; therefore, according to ISO/DIN 10993-5:2009, this composite was categorised as non-cytotoxic.
Taguchi Optimization of Parameters for Feedstock Fabrication and FDM Manufacturing of Wear-Resistant UHMWPE-Based Composites
Authors: Dontsov Yury V. , Panin Sergey V. , Buslovich Dmitry G. , Berto Filippo
Published: June 2020

It is believed that the structure and properties of parts fabricated by additive (i.e., non-stationary) manufacturing are slightly worse compared to hot pressing. To further proceed with improving the quality of Fused Deposition Modeling 3D-printed parts, the ‘UHMWPE + 17 wt.% HDPE-g-SMA + 12 wt.% PP’ composite feedstock fabrication parameters, by the twin-screw extruder compounding and 3D printing (the Fused Deposition Modeling (FDM) process), were optimized using the Taguchi method. The optimization was carried out over the results of mechanical tests. The obtained results were interpreted in terms of (1) the uniformity of mixing of the polymer components upon compounding and (2) the homogeneity of the structure formed by the 3D printing. The values of the main factors (the processing parameters) were determined using the Taguchi method. Their application made it possible to improve the physical, mechanical, and tribological properties of the samples manufactured by the FDM method at the level of neat UHMWPE as well as the UHMWPE-based composites fabricated by compression sintering. A comparative analysis of the structure, as well as the mechanical and tribological properties of the composite obtained by the FDM method, and the hot pressing from ‘optimized’ feedstock was performed. The ‘UHMWPE + 17 wt.% HDPE-g-SMA + 12 wt.% PP’ composites fabricated by the optimal compounding and 3D printing parameters can be implemented for the additive manufacturing of complex shape products (including medical implants, transport, mining, and processing industries; in particular, in the Far North).
Preparation and Characterization of Novel Polymer-Based Gel Electrolyte for Dye-Sensitized Solar Cells Based on poly(vinylidene fluoride-co-hexafluoropropylene) and poly(acrylonitrile-co-butadiene) or poly(dimethylsiloxane) bis(3-aminopropyl) Copolymers
Authors: Bogdanowicz Krzysztof Artur , Augustowski Dariusz , Dziedzic Justyna , Kwaśnicki Paweł , Malej Wacław , Iwan Agnieszka
Published: June 2020

Polymer gel electrolytes based on poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) and poly(acrylonitrile-co-butadiene) (PAB) or poly(dimethylsiloxane) bis(3-aminopropyl)-terminated (PDES-bAP) copolymers were prepared and investigated in dye-sensitized solar cells (DSSCs). Selected optical and electrochemical properties of all compositions with various ratio from 9:1 to 6:4 were investigated towards DSSC applications. The highest value of power conversion efficiency equal to 5.07% was found for DSSCs containing a PVDF-HPF:PAB (9:1) gel electrolyte. Compositions of electrolytes were additionally tested by electrochemical impedance spectroscopy. The influence of the ratio and type of polymers used as an additive to PVDF-HPF on absorption wavelengths, energy gap, and Highest Occupied Molecular Orbital (HOMO) and Lowest Unoccupied Molecular Orbital (LUMO) levels were investigated. Individual components of DSSCs, such as the TiO2 layer and platinum nanoparticles, were imaged by scanning electron microscope. Finally, a DSSC module with six electrically separated solar cells with a 7 × 80 mm2 active area was constructed based on gel electrolytes and tested.
Improved Performance of Ternary Solar Cells by Using BODIPY Triads
Authors: Wanwong Sompit , Sangkhun Weradesh , Kumnorkaew Pisist , Wootthikanokkhan Jatuphorn
Published: June 2020

Two boron dipyrromethene (BODIPY) triads, namely BODIPY-1 and BODIPY-2, were synthesized and incorporated with poly-3-hexyl thiophene: (6,6)-phenyl-C61-butyric acid methyl ester (PCBM) P3HT:PCBM. The photovoltaic performance of BODIPY:P3HT:PCBM ternary solar cells was increased, as compared to the control binary solar cells (P3HT:PCBM). The optimized power conversion efficiency (PCE) of BODIPY-1:P3HT:PCBM was improved from 2.22% to 3.43%. The enhancement of PCE was attributed to cascade charge transfer, an improved external quantum efficiency (EQE) with increased short circuit current (Jsc), and more homogeneous morphology in the ternary blend.
Effects of Dwell Time on the Deformation and Fatigue Behaviour of A356-T7 Cast Aluminium Alloys Used in High Specific Power IC Engine Cylinder Heads
Authors: Natesan Elanghovan , Meyer Knut Andreas , Eriksson Stefan , Ahlström Johan , Persson Christer
Published: June 2020

The electrification of automotive powertrains in recent years has been driving the development of internal combustion engines towards reduced volumes with higher power outputs. These changes place extreme demands on engine materials. Engineers employ the computer-aided engineering approach to design reliable and cost-effective engines. However, this approach relies on accurate knowledge of the material deformation and fatigue characteristics during service-like loading. The present study seeks to investigate the effect of dwell times on the deformation and fatigue behaviour of the A356-T7 + 0.5 wt.% Cu alloy used to cast cylinder heads. In particular, we study the effect of dwell time duration at various temperatures. A combined fatigue-dwell testing procedure, with the dwell at the maximum compressive strain, replicates the service conditions. It is found that the material exhibits a stress relaxation behaviour with a decreasing relaxation rate. At lower temperatures, the load level influences the relaxation more than at elevated temperatures. However, the dwell does not significantly affect the hardening behaviour or the life of the tested alloy. Finally, we model the time-dependent material behaviour numerically. The Chaboche model, combined with a Cowper–Symonds power-law, is found to capture the visco-plastic deformation behaviour accurately.
Acute Effects of a Heat-Not-Burn Tobacco Product on Pulmonary Function
Authors: Pataka Athanasia , Kotoulas Seraphim , Chatzopoulos Evangelos , Grigoriou Ioanna , Sapalidis Konstantinos , Kosmidis Christoforos , Vagionas Anastasios , Perdikouri Εleni-Isidora , Drevelegas Konstantinos , Zarogoulidis Paul , Argyropoulou Paraskevi
Published: June 2020

Background and objectives: During the last decade, conventional tobacco smoking is experiencing a decline and new smoking products have been introduced. IQOS (“I-Quit-Ordinary-Smoking”) is a type of “heat-not-burn” (HNB) tobacco product. The impact of IQOS on respiratory health is currently not defined. The objectives of this study were to evaluate the acute effects of IQOS on pulmonary function in non-smokers and current smokers. Materials and Methods: Fifty male healthy non-smokers and current smokers with no known co-morbidity underwent an exhaled CO measurement, oximetry (SaO2%), pulmonary function tests (flows, volumes and diffusion capacity), and a measurement of respiratory resistances with an impulse oscillometry system (IOS) before and immediately after IQOS use. Results: In the whole group of 50 participants, SaO2%, forced expiratory flow at 25% and 50% of vital capacity (FEF 25%, FEF 50%, respectively), peak expiratory flow (PEF), and diffusion lung capacity for carbon monoxide/VA (KCO) decreased significantly after IQOS use, whereas exhaled CO and airway resistance (R5 Hz, R10 Hz, r15 Hz, R20 Hz, R25 Hz, R35 Hz) increased. When the groups of smokers and non-smokers were compared, in both groups (all males, 25 smokers and 25 non-smokers), exhaled CO increased and SaO2% decreased after IQOS use (p < 0.001). In the group of non-smokers, PEF (pre 8.22 ± 2.06 vs. post 7.5 ± 2.16, p = 0.001) and FEF 25% (pre 7.6 ± 1.89 vs. 7.14 ± 2.06, p = 0.009) decreased significantly; respiratory resistances R20 Hz (pre 0.34 ± 0.1 vs. post 0.36 ± 0.09, p = 0.09) and R25 Hz (pre 0.36 ± 0.1 vs. post 0.38 ± 0.09, p = 0.08) increased almost significantly. In smokers, PEF (pre 7.69 ± 2.26 vs. post 7.12 ± 2.03, p = 0.007) and expiratory reserve volume (ERV) (pre 1.57 ± 0.76 vs. post1.23 ± 0.48, p = 0.03) decreased and R35 Hz (pre 0.36 ± 0.11 vs. post 0.39 ± 0.11, p = 0.047) increased. The differences in the changes after the use of IQOS did not differ between groups. Conclusions: IQOS had an impact on exhaled CO, SaO2%, and airways function immediately after use. Even though these changes were rather small to be considered of major clinical importance, they should raise concerns regarding the long-term safety of this product. Further research is needed for the short- and long-term effects of IQOS, especially in patients with respiratory disease.
Optimal Control of Colloidal Trajectories in Inertial Microfluidics Using the Saffman Effect
Authors: Rühle Felix , Schaaf Christian , Stark Holger
Published: June 2020

In inertial microfluidics colloidal particles in a Poiseuille flow experience the Segré-Silberberg lift force, which drives them to specific positions in the channel cross section. An external force applied along the microchannel induces a cross-streamline migration to a new equilibrium position because of the Saffman effect. We apply optimal control theory to design the time protocol of the axial control force in order to steer a single particle as precisely as possible from a channel inlet to an outlet at a chosen target position. We discuss the influence of particle radius and channel length and show that optimal steering is cheaper than using a constant control force. Using a single optimized control-force protocol, we demonstrate that even a pulse of particles spread along the channel axis can be steered to a target and that particles of different radii can be separarted most efficiently.
Evolution of Metakaolin Thermal and Chemical Activation from Natural Kaolin
Authors: Sánchez Isabel , de Soto Isabel Sonsoles , Casas Marina , Vigil de la Villa Raquel , García-Giménez Rosario
Published: June 2020

In the present paper, we study the combined effect of thermal activation (600 °C/2 h and 750 °C/2 h) and chemical activation with 1% ZnO on the reactivity of metakaolinite (MK) obtained from natural kaolin. The phases are identified by chemical (ICP/MS), mineralogical (XRD), and morphological (SEM/EDX) characterization of all products, as well as the evolution and stability over time of the hydrated phases generated during the reaction, to determine their use as pozzolan in the manufacture of cements. The stability analysis for the kaolin/lime system activated chemically and thermally at 600 °C/2 h shows that the C-S-H gels are thermodynamically stable after one day of reaction, evolving the system to the stability field of stratlingite for the other analyzed times. At 750 °C/2 h, the thermodynamically stable reaction phases are C-S-H gels. Calcination at 600 °C/2 h and the addition of 1% ZnO are the optimal conditions for thermal and chemical activation, to improve the pozzolanic reaction and promote the replacing part of the cement for developing secondary reaction products.
The Vesuvianite Gems of the Val d’Ala (Piedmont, Italy)
Authors: Caucia Franca Piera , Marinoni Luigi , Scacchetti Maurizio , Riccardi Maria Pia , Bartoli Omar
Published: June 2020

In Val d’Ala (Western Alps in Piedmont, Italy), the most interesting rocks for mineralogical research are represented by rodingite (rich in mineralized veins and fractures) associated with serpentinite in the eclogitized oceanic crust of Piedmont Zone, south of Gran Paradiso Massif. Among the vein-filling minerals, vesuvianite is well appreciated for its potential as gem-quality materials, even though it has never been characterized in detail. This study provides a gemological characterization of eleven vesuvianite crystals from different localities of the Val d’Ala. The refractive index (1.717–1.708) and density (1.705–1.709) values of our vesuvianite are in the range of those in the literature. Scanning electron microscopy with energy-dispersive spectroscopy (SEM/EDS) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) established that the samples are pretty compositionally homogeneous in terms of major elements, while trace and rare earth elements (REE) contents are more variable. All REE patterns are characterized by pronounced positive Eu anomalies. The variations in color (from olive green to dark green with chocolate (reddish-brown color shades and polychrome bands) are due to the relevant presence of Fe and, to a lesser extent, Ti and Cr. The X-ray powder diffraction (XRPD) analyses and SEM/EDS quantitative study indicate that the other phases associated with vesuvianite are represented by diopside, garnet, clinochlore.
Reexamining the Role of Ammonium Ions in the Sulfidization, Xanthate-Flotation of Malachite
Authors: Liu Ruizeng , Liu Zhicheng , Li Jianmin , Ao Shunfu , Pei Bin , Liu Dianwen , Li Jialei
Published: June 2020

Ammonium ions have positive effects on the sulfidization flotation of malachite; however, the underlying mechanisms remain poorly understood. In the present work, micro-flotation tests, field emission scanning electron microscopy (FESEM), energy dispersive spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and solution analysis for ammonium nitrogen were carried out. The flotation results showed positive effects of ammonium on the sulfidization flotation of malachite. Macroscopically, the sulfidized malachite produced with ammonium exhibited a darker color than that without ammonium, whereas the opposite appeared to be true for their corresponding residual liquids. FESEM images highlighted the larger particle size and higher converge density of the sulfidization product when the presence of ammonium. Furthermore, XPS results indicated a higher sulfur concentration on malachite surfaces when the presence of ammonium. XRD results showed that Cu31S16 (djurleite) and Cu7S4 (anilite) comprised the sulfidization products, regardless of the presence or absence of ammonium. However, neither EDS nor XPS analysis showed nitrogen on malachite surfaces; moreover, the residual-ratio results for ammonium nitrogen clearly demonstrated that most ammonium continued to be held in solution before and after malachite sulfidization. Based on these findings, we inferred that ammonium ions may mediate the nucleation and growth of sulfidization product during malachite sulfidization, rendering larger sulfidization product particles. The larger size of sulfidization products may result in a darker, stabler and denser sulfidization product coating layer, and then may reduce the generation of colloidal copper sulfide in the residual liquids. Ultimately, ammonium facilitates better performance of sulfidization flotation of malachite.
Comprehensive Electrostatic Modeling of Exposed Quantum Dots in Graphene/Hexagonal Boron Nitride Heterostructures
Authors: Quezada-López Eberth A. , Ge Zhehao , Taniguchi Takashi , Watanabe Kenji , Joucken Frédéric , Velasco Jairo
Published: June 2020

Recent experimental advancements have enabled the creation of tunable localized electrostatic potentials in graphene/hexagonal boron nitride (hBN) heterostructures without concealing the graphene surface. These potentials corral graphene electrons yielding systems akin to electrostatically defined quantum dots (QDs). The spectroscopic characterization of these exposed QDs with the scanning tunneling microscope (STM) revealed intriguing resonances that are consistent with a tunneling probability of 100% across the QD walls. This effect, known as Klein tunneling, is emblematic of relativistic particles, underscoring the uniqueness of these graphene QDs. Despite the advancements with electrostatically defined graphene QDs, a complete understanding of their spectroscopic features still remains elusive. In this study, we address this lapse in knowledge by comprehensively considering the electrostatic environment of exposed graphene QDs. We then implement these considerations into tight binding calculations to enable simulations of the graphene QD local density of states. We find that the inclusion of the STM tip’s electrostatics in conjunction with that of the underlying hBN charges reproduces all of the experimentally resolved spectroscopic features. Our work provides an effective approach for modeling the electrostatics of exposed graphene QDs. The methods discussed here can be applied to other electrostatically defined QD systems that are also exposed.
Thermal and Physical Characterization of PEG Phase Change Materials Enhanced by Carbon-Based Nanoparticles
Authors: Cabaleiro David , Hamze Samah , Fal Jacek , Marcos Marco A. , Estellé Patrice , Żyła Gaweł
Published: June 2020

This paper presents the preparation and thermal/physical characterization of phase change materials (PCMs) based on poly(ethylene glycol) 400 g·mol−1 and nano-enhanced by either carbon black (CB), a raw graphite/diamond nanomixture (G/D-r), a purified graphite/diamond nanomixture (G/D-p) or nano-Diamond nanopowders with purity grades of 87% or 97% (nD87 and nD97, respectively). Differential scanning calorimetry and oscillatory rheology experiments were used to provide an insight into the thermal and mechanical changes taking place during solid-liquid phase transitions of the carbon-based suspensions. PEG400-based samples loaded with 1.0 wt.% of raw graphite/diamond nanomixture (G/D-r) exhibited the lowest sub-cooling effect (with a reduction of ~2 K regarding neat PEG400). The influences that the type of carbon-based nanoadditive and nanoparticle loading (0.50 and 1.0 wt.%) have on dynamic viscosity, thermal conductivity, density and surface tension were also investigated in the temperature range from 288 to 318 K. Non-linear rheological experiments showed that all dispersions exhibited a non-Newtonian pseudo-plastic behavior, which was more noticeable in the case of carbon black nanofluids at low shear rates. The highest enhancements in thermal conductivity were observed for graphite/diamond nanomixtures (3.3–3.6%), while nano-diamond suspensions showed the largest modifications in density (0.64–0.66%). Reductions in surface tension were measured for the two nano-diamond nanopowders (nD87 and nD97), while slight increases (within experimental uncertainties) were observed for dispersions prepared using the other three carbon-based nanopowders. Finally, a good agreement was observed between the experimental surface tension measurements performed using a Du Noüy ring tensiometer and a drop-shape analyzer.
Black Sorghum Phenolic Extract Modulates Platelet Activation and Platelet Microparticle Release
Authors: Ed Nignpense Borkwei , Chinkwo Kenneth A , Blanchard Christopher L , Santhakumar Abishek B
Published: June 2020

Platelet hyper-activation and platelet microparticles (PMPs) play a key role in the pathogenesis of cardiovascular diseases. Dietary polyphenols are believed to mimic antiplatelet agents by blunting platelet activation receptors via its antioxidant phenomenon. However, there is limited information on the anti-platelet activity of grain-derived polyphenols. The aim of the study is to evaluate the effects of sorghum extract (Shawaya short black 1 variety), an extract previously characterised for its high antioxidant activity and reduction of oxidative stress-related endothelial dysfunction, on platelet aggregation, platelet activation and PMP release. Whole blood samples collected from 18 healthy volunteers were treated with varying non-cytotoxic concentrations of polyphenol-rich black sorghum extract (BSE). Platelet aggregation study utilised 5 µg/mL collagen to target the GPVI pathway of thrombus formation whereas adenine phosphate (ADP) was used to stimulate the P2Y1/P2Y12 pathway of platelet activation assessed by flow cytometry. Procaspase-activating compound 1 (PAC-1) and P-selectin/CD62P were used to evaluate platelet activation- related conformational changes and degranulation respectively. PMPs were isolated from unstimulated platelets and quantified by size distribution and binding to CD42b. BSE treatment significantly reduced both collagen-induced platelet aggregation and circulatory PMP release at 40 µg/mL (p < 0.001) when compared to control. However, there was no significant impact of BSE on ADP-induced activation-dependent conformational change and degranulation of platelets. Results of this study suggest that phenolic rich BSE may confer cardio-protection by modulating specific signalling pathways involved in platelet activation and PMP release.
The Central Role of Iron in Human Nutrition: From Folk to Contemporary Medicine
Authors: Briguglio Matteo , Hrelia Silvana , Malaguti Marco , Lombardi Giovanni , Riso Patrizia , Porrini Marisa , Perazzo Paolo , Banfi Giuseppe
Published: June 2020

Iron is a fundamental element in human history, from the dawn of civilization to contemporary days. The ancients used the metal to shape tools, to forge weapons, and even as a dietary supplement. This last indication has been handed down until today, when martial therapy is considered fundamental to correct deficiency states of anemia. The improvement of the martial status is mainly targeted with dietary supplements that often couple diverse co-factors, but other methods are available, such as parenteral preparations, dietary interventions, or real-world approaches. The oral absorption of this metal occurs in the duodenum and is highly dependent upon its oxidation state, with many absorption influencers possibly interfering with the intestinal uptake. Bone marrow and spleen represent the initial and ultimate step of iron metabolism, respectively, and the most part of body iron circulates bound to specific proteins and mainly serves to synthesize hemoglobin for new red blood cells. Whatever the martial status is, today’s knowledge about iron biochemistry allows us to embrace exceedingly personalized interventions, which however owe their success to the mythical and historical events that always accompanied this metal.