bluuebunny/crossref_metadata_2025 huggingface dataset:
Hybrid Carbon Nanotubes–Graphene Nanostructures: Modeling, Formation, Characterization
Authors: Gerasimenko Alexander Yu. , Kuksin Artem V. , Shaman Yury P. , Kitsyuk Evgeny P. , Fedorova Yulia O. , Murashko Denis T. , Shamanaev Artemiy A. , Eganova Elena M. , Sysa Artem V. , Savelyev Mikhail S. , Telyshev Dmitry V. , Pavlov Alexander A. , Glukhova Olga E.
Published: August 2022

A technology for the formation and bonding with a substrate of hybrid carbon nanostructures from single-walled carbon nanotubes (SWCNT) and reduced graphene oxide (rGO) by laser radiation is proposed. Molecular dynamics modeling by the real-time time-dependent density functional tight-binding (TD-DFTB) method made it possible to reveal the mechanism of field emission centers formation in carbon nanostructures layers. Laser radiation stimulates the formation of graphene-nanotube covalent contacts and also induces a dipole moment of hybrid nanostructures, which ensures their orientation along the force lines of the radiation field. The main mechanical and emission characteristics of the formed hybrid nanostructures were determined. By Raman spectroscopy, the effect of laser radiation energy on the defectiveness of all types of layers formed from nanostructures was determined. Laser exposure increased the hardness of all samples more than twice. Maximum hardness was obtained for hybrid nanostructure with a buffer layer (bl) of rGO and the main layer of SWCNT—rGO(bl)-SWCNT and was 54.4 GPa. In addition, the adhesion of rGO to the substrate and electron transport between the substrate and rGO(bl)-SWCNT increased. The rGO(bl)-SWCNT cathode with an area of ~1 mm2 showed a field emission current density of 562 mA/cm2 and stability for 9 h at a current of 1 mA. The developed technology for the formation of hybrid nanostructures can be used both to create high-performance and stable field emission cathodes and in other applications where nanomaterials coating with good adhesion, strength, and electrical conductivity is required.
Temperature-Driven Transformation of the Crystal and Magnetic Structures of BiFe0.7Mn0.3O3 Ceramics
Authors: Karpinsky Dmitry V. , Silibin Maxim V. , Latushka Siarhei I. , Zhaludkevich Dmitry V. , Sikolenko Vadim V. , Svetogorov Roman , Sayyed M. I. , Almousa Nouf , Trukhanov Alex , Trukhanov Sergei , Belik Alexei А.
Published: August 2022

The compound BiFe0.7Mn0.3O3 consisting at room temperature of coexistent anti-polar orthorhombic and polar rhombohedral phases has a metastable structural state, which has been studied by laboratory X-ray, synchrotron and neutron diffraction, magnetometry, differential thermal analysis, and differential scanning calorimetry. Thermal annealing of the sample at temperatures above the temperature-driven phase transition into the single phase rhombohedral structure (~700 K) causes an increase of the volume fraction of the rhombohedral phase at room temperature from ~10% up to ~30%, which is accompanied by the modification of the magnetic state, leading to strengthening of a ferromagnetic component. A strong external magnetic field (~5 T) applied to the sample notably changes its magnetic properties, as well as provides a reinforcement of the ferromagnetic component, thus leading to an interaction between two magnetic subsystems formed by the antiferromagnetic matrix with non-collinear alignment of magnetic moments and the nanoscale ferromagnetic clusters coexisting within it. The modification of the structural state and magnetic properties of the compounds and a correlation between different structural and magnetic phases are discussed focusing on the effect of thermal annealing and the impact of an external magnetic field.
Fabrication, Thermal Conductivity, and Mechanical Properties of Hexagonal-Boron-Nitride-Pattern-Embedded Aluminum Oxide Composites
Authors: Yun Hyesun , Kwak Min-Gi , Park KeumHwan , Kim Youngmin
Published: August 2022

As electronics become more portable and compact, the demand for high-performance thermally conductive composites is increasing. Given that the thermal conductivity correlates with the content of thermally conductive fillers, it is important to fabricate composites with high filler loading. However, the increased viscosity of the composites upon the addition of these fillers impedes the fabrication of filler-reinforced composites through conventional methods. In this study, hexagonal-boron-nitride (h-BN)-pattern-embedded aluminum oxide (Al2O3) composites (Al/h-BN/Al composites) were fabricated by coating a solution of h-BN onto a silicone-based Al2O3 composite through a metal mask with square open areas. Because this method does not require the dispersion of h-BN into the Al2O3 composite, composites with high filler loading could be fabricated without the expected problems arising from increased viscosity. Based on the coatability and thixotropic rheological behaviors, a composite with 85 wt.% Al2O3 was chosen to fabricate Al/h-BN/Al composites. The content of the Al2O3 and the h-BN of the Al/h-BN/Al-1 composite was 74.1 wt.% and 12.8 wt.%, respectively. In addition to the increased filler content, the h-BN of the composite was aligned in a parallel direction by hot pressing. The in-plane (kx) and through-plane (kz) thermal conductivity of the composite was measured as 4.99 ± 0.15 Wm−1 K−1 and 1.68 ± 0.2 Wm−1 K−1, respectively. These results indicated that the method used in this study is practical not only for increasing the filler loading but also for achieving a high kx through the parallel alignment of h-BN fillers.
Trans Fatty Acids Content in Whole-Day Diets Intended for Pregnant and Breastfeeding Women in Gynaecological and Obstetric Wards: Findings from the Study under the “Mum’s Diet” Pilot Program in Poland
Authors: Jasińska-Melon Edyta , Mojska Hanna , Przygoda Beata , Stoś Katarzyna
Published: August 2022

Trans fatty acids (TFAs) have been proven to have an adverse effect on human health by interfering with n-3 long-chain polyunsaturated fatty acids (n-3 LC-PUFA) synthesis. LC-PUFA n-3 are necessary for the development and maturation of the nervous system and retina during the prenatal period and infancy. TFAs are not synthesized de novo in the human body. Their presence in body fluids arises from the diet. The aim of our study was to determine the content of TFAs in individual meals and in a whole-day hospital diet intended for pregnant and breastfeeding women. Samples were collected from six different hospitals in Poland which voluntarily applied to the “Mum’s Diet” Pilot Program. The content of fatty acids, including TFAs, was determined by gas chromatography coupled with mass spectrometry (GC-MS). The TFAs content in the whole-day hospital diets ranged from 3.86 to 8.37% of all fatty acids (% wt/wt). Food products served for elevenses and afternoon snacks contributed the highest amounts of TFAs. These mainly included dairy products containing TFAs of natural origins. The estimated average intake of TFAs with the hospital diet was 0.72 g/person/day (range: 0.34–1.16 g/person/day) and did not exceed the maximum level of 1% of dietary energy recommended by the World Health Organization.
Association between Legume Consumption and Risk of Hypertension in the European Prospective Investigation into Cancer and Nutrition (EPIC)-Norfolk Cohort
Authors: Hartley Michael , Fyfe Claire L. , Wareham Nicholas J. , Khaw Kay-Tee , Johnstone Alexandra M. , Myint Phyo K.
Published: August 2022

Hypertension is a significant and preventable cardiovascular disease risk factor. Growing evidence suggests legumes have blood-pressure (BP) lowering properties. However, there is little population-based research on legume intake and hypertension risk in Western populations. The objective was to investigate the relationship between legume intake and blood pressure by using data from the European Prospective Investigation into Cancer and Nutrition (EPIC) Norfolk cohort. Further, to identify any potential legume intake that confers benefits in relation to blood pressure. We included participants who completed both 7-day food diaries to assess legume intake and undertook a first (1993–1997) and second (1998–2000) health check from the EPIC-Norfolk prospective study. Legume consumption was categorized using percentile cut off values. We used multivariate logistic regression models to calculate the odds ratio of hypertension (defined as >140 mmHg systolic and/or >90 mmHg diastolic blood pressure) at the second health check, stratified by legume intake, adjusting for antihypertensive medication use and demographic, socioeconomic and lifestyle covariates. A total of 7522 participants were included with mean age (± SD) of 58.0 ± 8.9 years. The follow-up time was 3.7 years (range: 2.1–6.6 years). Mean legume consumption was 17.3 ± 16.3 g/day. Participants in the 97th percentile of legume intake had the lowest odds of subsequent hypertension (OR: 0.71; 95% CI: 0.52, 0.96). Legume consumption between 55–70 g/day was associated with reduced odds of hypertension (OR: 0.57; 95% CI: 0.37, 0.88); sex-specific values for men and women were 0.64 (0.38, 1.03) and 0.32 (0.12, 0.88), respectively. In this UK population, legume intake of 55–70 g/day was associated with a lower subsequent risk of hypertension. Given the low legume intake in the UK and Western countries, dietary guidance to increase intake above 55 g/day may lower the burden of hypertension and associated diseases.
Synthesis and Biological Evaluation of Indole-2-Carboxamides with Potent Apoptotic Antiproliferative Activity as EGFR/CDK2 Dual Inhibitors
Authors: Al-Wahaibi Lamya H. , Mostafa Yaser A. , Abdelrahman Mostafa H. , El-Bahrawy Ali H. , Trembleau Laurent , Youssif Bahaa G. M.
Published: August 2022

The apoptotic antiproliferative actions of our previously reported CB1 allosteric modulators 5-chlorobenzofuran-2-carboxamide derivatives VIIa–j prompted us to develop and synthesise a novel series of indole-2-carboxamide derivatives 5a–k, 6a–c, and 7. Different spectroscopic methods of analysis were used to validate the novel compounds. Using the MTT assay method, the novel compounds were examined for antiproliferative activity against four distinct cancer cell lines. Compounds 5a–k, 6a–c, and 7 demonstrated greater antiproliferative activity against the breast cancer cell line (MCF-7) than other tested cancer cell lines, and 5a–k (which contain the phenethyl moiety in their backbone structure) demonstrated greater potency than 6a–c and 7, indicating the importance of the phenethyl moiety for antiproliferative action. Compared to reference doxorubicin (GI50 = 1.10 µM), compounds 5d, 5e, 5h, 5i, 5j, and 5k were the most effective of the synthesised derivatives, with GI50 ranging from 0.95 µM to 1.50 µM. Compounds 5d, 5e, 5h, 5i, 5j, and 5k were tested for their inhibitory impact on EGFR and CDK2, and the results indicated that the compounds tested had strong antiproliferative activity and are effective at suppressing both CDK2 and EGFR. Moreover, the studied compounds induced apoptosis with high potency, as evidenced by their effects on apoptotic markers such as Caspases 3, 8, 9, Cytochrome C, Bax, Bcl2, and p53.
Alginate/Chitosan-Based Hydrogel Film Containing α-Mangostin for Recurrent Aphthous Stomatitis Therapy in Rats
Authors: Milanda Tiana , Cindana Mo’o Faradila Ratu , Mohammed Ahmed Fouad Abdelwahab , Elamin Khaled M. , Wilar Gofarana , Suharyani Ine , Wathoni Nasrul
Published: August 2022

Recurrent aphthous stomatitis (RAS) is a prevalent clinical disorder that causes mouth ulcers. Furthermore, corticosteroid treatment has been widely utilized for RAS therapy; however, it has side effects on the oral mucosa that limit its application. This study aimed to develop a novel RAS therapy with the natural ingredient α-mangostin, delivered by alginate and chitosan polymers-based hydrogel film (α-M Alg/Chi-HF). To prepare α-M Alg/Chi-HF, the solvent evaporation and casting methods were used, then characterized by using SEM, FTIR, and XRD. Based on the characterization studies, the α-M in α-M/EtOH Alg/Chi-HF with ethanol (EtOH) was found to be more homogenous compared to α-M in Alg/Chi-HF with distilled water (H2O) as a casting solvent. The in vitro viability study using NIH3T3 cells showed 100% viability of α-M Alg/Chi-HF (EtOH) and Alg/Chi-HF after 24 h incubation, indicating well tolerability of these hydrogel films. Interestingly, the in vivo studies using male white rats (Rattus norvegicus Berkenhout) proved that α-M/EtOH Alg/Chi-HF with a recovery of 81.47 ± 0.09% in seven days significantly more effective RAS therapy compared to control. These results suggest that α-M/EtOH Alg/Chi-HF has the potential as an alternative for RAS therapy.
1 W High Performance LED-Array Based Optical Wireless Power Transmission System for IoT Terminals
Authors: Zhao Mingzhi , Miyamoto Tomoyuki
Published: August 2022

Optical wireless power transmission (OWPT) is a promising technology for remote energy supply, especially for powering Internet of things (IoT) terminals. Light-emitting diode (LED)-based power sources of OWPT are attractive for the development of high-performance systems without the constraints of safety issues. In this paper, the electricity output of a near-infrared LED-OWPT is significantly improved. The saturation output caused by the small lens aperture in the LED array collimation scheme was analyzed. The experiment achieved a maximum electricity output of more than 1 W from a 50 × 50 mm2 GaAs solar cell at 1 m transmission distance. In addition, the thermal features also proved the feasibility of a high-output LED-OWPT system for practical applications.
Filler Models Revisited: Extension of the Nielson Model with Respect to the Geometric Arrangements of Fillers
Authors: Macher Johannes , Golestaneh Pouyan , Macher Astrid E. , Morak Matthias , Hausberger Andreas
Published: August 2022

Models describing how fillers affect the barrier properties of polymers remain an important research topic to improve applications such as hydrogen storage or food preservation. The Nielsen model, one of the earliest models for such predictions, is still one of the most widely used in the literature. However, it does not provide quantitative information on arrangements of fillers inside a polymer matrix, which is crucial for the definition of suitable filler distributions in barrier materials. Therefore, the channel model was developed in this work, which extends the Nielsen model by determining the relative distances between the fillers in regular filler arrangements in polymer matrices. This allows us to relate the permeation properties of filled polymer membranes to the geometric properties of the filler arrangement in simulations and experimental measurements. Simulations with geometries defined according to the channel model showed good agreement with the predictions of the Nielsen model. This demonstrated that the channel model can be a valuable tool for predicting at least mean geometric distances in studied polymer membranes. The validity range of the channel model was limited to a value range of the filler volume fraction 0.01≤ϕf≤0.5 based on theoretical considerations.
Advanced Face Mask Filters Based on PCL Electrospun Meshes Dopped with Antimicrobial MgO and CuO Nanoparticles
Authors: Ferreira Carolina A. M. , Guerreiro Sara F. C. , Valente Joana F. A. , Patrício Tatiana M. F. , Alves Nuno , Mateus Artur , Dias Juliana R.
Published: August 2022

The pandemic situation caused by coronavirus clearly demonstrated the need for alternatives able to protect the respiratory tract and inactivate the infectious agents. Based on this, antibacterial face-mask filters of polycaprolactone (PCL) dopped with magnesium oxide (MgO) and copper oxide (CuO) nanoparticles (NPs) were produced using an electrospinning technique. A morphological analysis of electrospun meshes evaluated the success of nanoparticles’ incorporation as well as the average fibers’ diameters (481 ± 272 nm). The performance of electrospun nanofibers was also assessed in terms of tensile strength (0.88 ± 0.25 MPa), water vapor permeability (11,178.66 ± 35.78 g·m−2·day−1), stability under wet conditions and antibacterial activity according to the standard guidelines. The filters showed structural stability up to 2 h of washing and improved antibacterial activity against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) for optimized concentrations of MgO and CuO NPs. Overall, electrospun meshes with antibacterial activity were successfully developed for advanced filtering applications.
Enhanced Simulation of Infrared Heating of Thermoplastic Composites Prior to Forming under Consideration of Anisotropic Thermal Conductivity and Deconsolidation by Means of Novel Physical Material Models
Authors: Längauer Manuel , Zitzenbacher Gernot , Stadler Hannes , Hochenauer Christoph
Published: August 2022

In recent years, thermoplastic composites have found their place in large business sectors and are in direct rivalry to thermoset matrix composites. In order to ensure efficient and lean processes, process modeling gains ever-growing attention. This work shows the computational fluid dynamics (CFD)-modeling of a typical heating step in a thermoforming process of a thermoplastic composite sheet. When heating thermoplastic composites, the heat conduction proceeds anisotropic, and the sheets are subject to thermal deconsolidation when heated above the melting temperature of the polymer matrix adding to the anisotropic effect. These effects are neglected in known process models and this study shows the first successful attempt at introducing them into CFD-modeling of the heating of thermoplastic composite sheets. Thus, the simulation requires temperature dependent values for the anisotropic thermal conductivity and the coefficient of linear thermal expansion, which are calculated with novel physical models which were developed solely for this cause. This alters the behavior of an isotropic CFD-model and allows the successful validation via laboratory experiments using glass fiber reinforced polypropylene (PP/GF) sheets with embedded thermocouples to check the internal temperature distribution when the sheet is heated to the designated forming temperature in a composite thermoforming press. The incorporation of this newly developed process model reduces the error in the core temperature prediction from close to 70 °C to 3 °C at the forming temperature.
Anti-Wrinkle and Dyeing Properties of Silk Fabric Finished with 2,4,6-Trichloropyrimidine
Authors: Li Minhua , Dong Xue , Xing Tieling , Chen Guoqiang
Published: August 2022

Silk, a natural protein fiber, is widely used in the textile industry and biomedical materials for its excellent properties. However, its application in some fields is seriously restricted due to its poor anti-wrinkle behavior. In this study, 2,4,6-trichloropyrimidine (TLP) was used in the production of anti-wrinkle silk fabrics. The optimum finishing conditions were as follows: 3-g/L 2,4,6-trichloropyrimidine, 6-g/L NaHCO3, 8-g/L Na2SO4, finishing temperature of 65 °C, and finishing time of 40 min. The crease recovery angle of the finished fabric is 16–20% higher than the unfinished fabric, and the finishing process has a small effect on the whiteness of silk while achieving some degree of washing resistance. The morphology and chemical structures of the finished silk fabric were characterized by scanning electron microscopy and Fourier transform infrared spectroscopy. The K/S value of the finished silk fabric dyed with reactive dyes increased compared with the silk fabric only dyed, indicating that the dyeability of the finished fabric was improved. This technology provides a new method for fabricating silk color crease-resistant fabrics.
Non-Viral Delivery of Gene Therapy to the Tendon
Authors: Jin Jing , Yang Qian Qian , Zhou You Lang
Published: August 2022

The tendon, as a compact connective tissue, is difficult to treat after an acute laceration or chronic degeneration. Gene-based therapy is a highly efficient strategy for diverse diseases which has been increasingly applied in tendons in recent years. As technology improves by leaps and bounds, a wide variety of non-viral vectors have been manufactured that attempt to have high biosecurity and transfection efficiency, considered to be a promising treatment modality. In this review, we examine the unwanted biological barriers, the categories of applicable genes, and the introduction and comparison of non-viral vectors. We focus on lipid-based nanoparticles and polymer-based nanoparticles, differentiating between them based on their combination with diverse chemical modifications and scaffolds.
The Incorporation of Low-Molecular Weight Poly(Mannitol Sebacate)s on PLA Electrospun Fibers: Effects on the Mechanical Properties and Surface Chemistry
Authors: Hevilla Víctor , Sonseca Águeda , Gimenez Enrique , Echeverría Coro , Muñoz-Bonilla Alexandra , Fernández-García Marta
Published: August 2022

We offer a report on the synthesis of low-molecular weight biobased poly(mannitol sebacate) (PMS) and its functionalization with acrylate groups (PMSAc). These synthesized polyesters were blended at a low level (10 wt%) with poly (lactic acid) PLA to prepare aligned fibers by electrospinning, coupled with a rotatory collector. The obtained fibers were extensively studied by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), differential scanning calorimetry (DSC), and wide-angle X-ray diffraction (WAXS), employing synchrotron radiation. The incorporation of the PMSs on the PLA fibers did not significantly affect the fiber diameters, whereas the alignment was almost maintained. The crystallinity and thermal properties were also slightly modified with the addition of PMSs, and an increase in the degree of crystallinity and in the glass transition temperature of the blend compared to PLA was observed. Remarkably, the PLA/PMSs fibers were more ductile due to the elastomeric character of PMS, with higher values of elongation at break and tensile strengths, and a smaller Young modulus in comparison with the PLA fibers. These modifications of the properties were more noticeable in the case of the acrylated PMS, which also provided readily available functional groups at the surface for further chemical reactions, such as the Michael addition or crosslinking processes.
A Comparative Study on Bio-Based PU Foam Reinforced with Nanoparticles for EMI-Shielding Applications
Authors: Selvaraj Vinoth Kumar , Subramanian Jeyanthi
Published: August 2022

Today, most commercial polyols used to make polyurethane (PU) foam are produced from petrochemicals. A renewable resource, castor oil (CO), was employed in this study to alleviate concerns about environmental contamination. This study intends to fabricate a bio-based and low-density EMI-defending material for communication, aerospace, electronics, and military appliances. The mechanical stirrer produces the flexible bio-based polyurethane foam and combines it with nanoparticles using absorption and hydrothermal reduction processes. The nanoparticles used in this research are graphite nanoplates (GNP), zirconium oxide (ZrO2), and bamboo charcoal (BC). Following fabrication, the samples underwent EMI testing using an EMI test setup with model number N5230A PNA-L. The EMI experimental results were compared with computational simulation using COMSOL Multiphysics 5.4 and an optimization tool using response surface methodology. A statistical design of the experimental approach is used to design and evaluate the experiments systematically. An experimental study reveals that a 0.3 weight percentage of GNP, a 0.3 weight percentage of ZrO2, and a 2.5 weight percentage of BC depict a maximum EMI SE of 28.03 dB in the 8–12 GHz frequency band.
CAD/CAM Abutments versus Stock Abutments: An Update Review
Authors: Gallo Simone , Pascadopoli Maurizio , Pellegrini Matteo , Pulicari Federica , Manfredini Mattia , Zampetti Paolo , Spadari Francesco , Maiorana Carlo , Scribante Andrea
Published: August 2022

With the evolution of CAD/CAM technology, custom titanium and/or zirconia abutments are increasingly being used, leading to several comparisons in the literature, both mechanical and aesthetic, to evaluate performance differences between these two types of abutments. Therefore, the aim of this comprehensive review is to present the most recent data on the latest comparisons between CAD/CAM and stock abutment applications. The PICO model was used to perform this review, through a literature search of the PubMed (MEDLINE) and Scopus electronic databases. CAD/CAM abutments allow individualization of abutment parameters with respect to soft tissue, allow increased fracture toughness, predict the failure mode, show no change in the fracture toughness over time, reduce the prosthetic steps, and reduce the functional implant prosthesis score and pain perceived by patients in the early stages. The advantages associated with the use of stock abutments mainly concern the risk of corrosion, time spent, cost, and fit, evaluated in vitro, in the implant–abutment connection. Equal conditions are present regarding the mechanical characteristics during dynamic cycles, screw loss, radiographic fit, and degree of micromotion. Further randomized controlled clinical trials should be conducted to evaluate the advantages reported to date, following in vitro studies about titanium and/or zirconia stock abutments.
Civil War Secularity Talk
Authors: Gutkowski Stacey
Published: August 2022

Despite important advances in the study of war and religion, the role of the secular remains under-analyzed. This article develops a theory of secularity talk in civil wars, examining two instances where actors have made religion and sect salient. In comparing patterns of secularity talk among non-elites found in oral history sources from the Syrian civil war and the Northern Irish Troubles, this article contributes to the recent peace turn in the religion-and-conflict literature. Greater attention to religion’s borderlands, to how actors distinguish religion from other arenas of human life can tell us more about what happens to the secular when people are under extreme pressure, including during war. This approach also sheds light on non-elite ambivalence towards elite mobilization of religion to fuel conflict, a common but as-yet under-theorized phenomenon.
Learning from Elders about Autonomy, Meaningfulness, and Relationships
Authors: Stumpf Andrew , McKenzie Erin , Nguyen Vivian
Published: August 2022

In this essay, we appeal to conceptual and empirical research to establish that autonomy and meaningfulness, when understood concretely and realistically, remain possible for frail and dependent elders. Contrary to ageist cultural attitudes, relationships render frailty and dependence compatible with the exercise of autonomous agency and with a life of meaning. This conclusion is important not only for the goal of supporting frail elders but also for developing a realistic understanding of the way relationships and spirituality are required for autonomy and meaning in the life of any human person, regardless of what state of dependence or independence they may be in. Each of us develops and continues to exist in radical dependence on others. Seeing the way autonomy and meaning manifest in the context of frailty and dependence thus helps us better appreciate what these crucial aspects of being human mean for all of us. In other words, we can learn important lessons about autonomy, meaningfulness, and relationship from the experience of our elders, and in particular from those who experience significant frailty and dependence.
Evaluating Satellite Soil Moisture Datasets for Drought Monitoring in Australia and the South-West Pacific
Authors: Bhardwaj Jessica , Kuleshov Yuriy , Chua Zhi-Weng , Watkins Andrew B. , Choy Suelynn , Sun Qian (Chayn)
Published: August 2022

Soil moisture (SM) is critical in monitoring the time-lagged impacts of agrometeorological drought. In Australia and several south-west Pacific Small Island Developing States (SIDS), there are a limited number of in situ SM stations that can adequately assess soil-water availability in a near-real-time context. Satellite SM datasets provide a viable alternative for SM monitoring and agrometeorological drought provision in these regions. In this study, we investigated the performance of Soil Moisture Active Passive (SMAP), Soil Moisture and Ocean Salinity (SMOS), Soil Moisture Operational Products System (SMOPS), SM from the Advanced Microwave Scanning Radiometer 2 (AMSR-2) and SM from the Advanced Scatterometer (ASCAT) over Australia and south-west Pacific SIDS. Products were first evaluated in Australia, given the presence of several in-situ SM monitoring stations and a state-of-the-art hydrological model—the Australian Water Resources Assessment Landscape modelling system (AWRA-L). We further investigated the accuracy of SM satellite datasets in Australia and the south-west Pacific through Triple Collocation analysis with two other SM reference datasets—ERA5 reanalysis SM data and model data from the Global Land Data Assimilation System (GLDAS) dataset. All datasets have differing observation periods ranging from 1911-now, with a common period of observations between 2015–2021. Results demonstrated that ASCAT and SMOS were consistently superior in their performance. Analysis in the six south-west Pacific SIDS indicated reduced performance for all products, with ASCAT and SMOS still performing better than others for most SIDS with median R values ranging between 0.3–0.9. We conducted a case study of the 2015 El Niño and Positive Indian Ocean Dipole-induced drought in Papua New Guinea. It was shown that ASCAT is a valuable dataset indicative of agrometeorological drought for the nation, highlighting the value of using satellite SM products to provide early warning of drought in data-sparse regions in the south-west Pacific.
Sentinel-2 Poplar Index for Operational Mapping of Poplar Plantations over Large Areas
Authors: Hamrouni Yousra , Paillassa Eric , Chéret Véronique , Monteil Claude , Sheeren David
Published: August 2022

Poplar (Populus spp.) is a fast-growing tree planted to meet the growing global demand for wood products. In France, the country with the largest area planted with poplar in Europe, accurate and up-to-date maps of its spatial distribution are not available at the national scale. This makes it difficult to estimate the extent and location of the poplar resource and calls for the development of a robust and timely stable approach for mapping large areas in order to ensure efficient monitoring. In this study, we investigate the potential of the Sentinel-2 time series to map the diversity of poplar plantations at the French countrywide scale. By comparing multiple configurations of spectral features based on spectral bands and indices over two years (2017 and 2018), we identify the optimal spectral regions with their respective time periods to distinguish poplar plantations from other deciduous species. We also define a novel poplar detection index (PI) with four variants that combine the best discriminative spectral bands. The results highlight the relevance of SWIR followed by red edge regions, mainly in the growing season, to accurately detect poplar plantations, reflecting the sensitivity of poplar trees to water content throughout their phenological cycle. The best performances with stable results were obtained with the PI2 poplar index combining the B5, B11, and B12 spectral bands. The PI2 index was validated over two years with an average producer’s accuracy of 92% in 2017 and 95% in 2018. This new index was used to produce the national map of poplar plantations in 2018. This study provides an operational approach for monitoring the poplar resource over large areas for forest managers.
Nemo: An Open-Source Transformer-Supercharged Benchmark for Fine-Grained Wildfire Smoke Detection
Authors: Yazdi Amirhessam , Qin Heyang , Jordan Connor B. , Yang Lei , Yan Feng
Published: August 2022

Deep-learning (DL)-based object detection algorithms can greatly benefit the community at large in fighting fires, advancing climate intelligence, and reducing health complications caused by hazardous smoke particles. Existing DL-based techniques, which are mostly based on convolutional networks, have proven to be effective in wildfire detection. However, there is still room for improvement. First, existing methods tend to have some commercial aspects, with limited publicly available data and models. In addition, studies aiming at the detection of wildfires at the incipient stage are rare. Smoke columns at this stage tend to be small, shallow, and often far from view, with low visibility. This makes finding and labeling enough data to train an efficient deep learning model very challenging. Finally, the inherent locality of convolution operators limits their ability to model long-range correlations between objects in an image. Recently, encoder–decoder transformers have emerged as interesting solutions beyond natural language processing to help capture global dependencies via self- and inter-attention mechanisms. We propose Nemo: a set of evolving, free, and open-source datasets, processed in standard COCO format, and wildfire smoke and fine-grained smoke density detectors, for use by the research community. We adapt Facebook’s DEtection TRansformer (DETR) to wildfire detection, which results in a much simpler technique, where the detection does not rely on convolution filters and anchors. Nemo is the first open-source benchmark for wildfire smoke density detection and Transformer-based wildfire smoke detection tailored to the early incipient stage. Two popular object detection algorithms (Faster R-CNN and RetinaNet) are used as alternatives and baselines for extensive evaluation. Our results confirm the superior performance of the transformer-based method in wildfire smoke detection across different object sizes. Moreover, we tested our model with 95 video sequences of wildfire starts from the public HPWREN database. Our model detected 97.9% of the fires in the incipient stage and 80% within 5 min from the start. On average, our model detected wildfire smoke within 3.6 min from the start, outperforming the baselines.
Impacts of Arc Length and ECOM Solar Radiation Pressure Models on BDS-3 Orbit Prediction
Authors: Li Ran , Zhao Chunmei , Wu Jiatong , Ma Hongyang , Zhang Yang , Yang Guang , Yuan Hong , Zhao Hongyu
Published: August 2022

The BeiDou global navigation satellite system (BDS-3) has already provided worldwide navigation and positioning services for which the high-precision BDS-3-predicting orbit is the foundation. The arc length of the observed orbits and the solar radiation pressure (SRP) are two important factors for producing precise orbit predictions. The contribution studies the influences of these factors on BDS-3 orbit prediction. Three-month data from 1 July 2021 to 30 September 2021 are used to analyze optimal arc lengths and different ECOM SRP models for obtaining precise BDS-3 orbit predictions. The results show that the best-fitting arc length for the BDS-3 MEO/IGSO satellite is 42–48 h by comparing the final precise ephemeris and SLR validation. Furthermore, the ECOM9 SRP model shows improved orbit-prediction accuracy than that of the ECOM5 SRP model when the satellites move in and out of the eclipse season. As for the ECOM9 SRP model, the user range error (URE) accuracy of 6 h orbit predictions when satellites are in and outside of the eclipse season is 0.036 m and 0.030 m, respectively. In addition, the orbit prediction accuracy of the BDS-3 satellites does not decrease significantly since BDS-3 satellites apply the continuous yaw-steering (CYS) attitude mode during the eclipse season.
On the Classification of Polyhedral Links
Authors: Wakayama Naohiro , Shimokawa Koya
Published: August 2022

Knots and links are ubiquitous in chemical systems. Their structure can be responsible for a variety of physical and chemical properties, making them very important in materials development. In this article, we analyze the topological structures of interlocking molecules composed of metal-peptide rings using the concept of polyhedral links. To that end, we discuss the topological classification of alternating polyhedral links.
Physico-Chemical and Ecotoxicological Evaluation of Marine Sediments Contamination: A Case Study of Rovinj Coastal Area, NE Adriatic Sea, Croatia
Authors: Pelikan Jadranka , Majnarić Nina , Maurić Maljković Maja , Pikelj Kristina , Hamer Bojan
Published: August 2022

Comprehensive spatial and temporal data on sediment quality in the Adriatic Sea are lacking. Therefore, prior to planned anthropogenic interventions in the local marine environment, such as deepening of the Rovinj harbour, the results of physicochemical and ecotoxicological analyses of five local coastal sediments were compared with regional averages and SQGs of neighbouring countries. Analyses of sediment grain size, content of metals and heavy metals, PAHs and PCBs were performed according to standard protocols. Sediment quality was classified according to French legislation (N1 and N2 level) and sediment guidelines. The phytotoxicity of the eluates was studied by flax seed germination tests. The logistic regression models Pmax and Pavg were used to estimate the probability of toxic effects. Except for the open sea (S5), all other sediments had concentrations slightly higher than the N1 for some metals (Cu, Ni, Hg, Cr) or ΣPAHs, while the Rovinj harbour (S1) reached the N2 value for mercury. The phytotoxicity assay with sediment eluates showed inhibition of germination, root length and root biomass production, with an average phytotoxicity index (PI) ranging from 6.06% to 42.00%. Significant correlations of Pavg and Pmax values with phytotoxicity and other specific parameters were found. In general, according to the applied SQGs, there are no potential ecological impacts on the marine environment at any of the investigated sites, with the exception of site S1.
Basiliximab vs. Antithymocyte Globulin as Initial Induction Therapy for Lung Transplantation: A National Two Years Review
Authors: Mendes Bruno , Figueiredo Carlos , Cabral Mariana , Borba Alexandra , Mineiro Alexandra , Cardoso João , Calvinho Paulo , Semedo Luísa , Fragata José
Published: August 2022

Basiliximab (BAS) is an interleukin-2 monoclonal antibody initially used as induction therapy after liver and kidney transplantation. BAS use after lung transplantation (LTx) has supplanted antithymocyte globulin (ATG) as the main induction immunosuppression over the years, but few studies have compared them. In this study, we aimed to compare the efficacy and safety between BAS and ATG in LTx. We performed a retrospective analysis of all LTx done in Portugal between January 2016 and December 2019. Three groups were made according to the initial induction status: BAS, ATG or no induction (NI). The occurrences of cytomegalovirus (CMV) infection, pneumonia, side effects, primary graft dysfunction (PGD), acute rejection, chronic allograft disfunction (CLAD) and death episodes were assessed during two years after LTx. A total of 124 patients were divided in 3 groups: 61 (49.2%) BAS; 43 (34.7%) ATG; 20 (16.1%) NI. The incidences of pneumonia and CMV were similar between induction groups. Additionally, there was no difference between the induction groups in PGD, acute rejection, CLAD, deaths and two-year survival. Side effects were reported only in ATG group (n = 20; 46.5%). In our study, BAS had a better safety profile than ATG in LTx with a similar efficacy.
Global Prevalence of Antifungal-Resistant Candida parapsilosis: A Systematic Review and Meta-Analysis
Authors: Yamin Dina , Akanmu Mutiat Hammed , Al Mutair Abbas , Alhumaid Saad , Rabaan Ali A. , Hajissa Khalid
Published: August 2022

A reliable estimate of Candida parapsilosis antifungal susceptibility in candidemia patients is increasingly important to track the spread of C. parapsilosis bloodstream infections and define the true burden of the ongoing antifungal resistance. A systematic review and meta-analysis (SRMA) were conducted aiming to estimate the global prevalence and identify patterns of antifungal resistance. A systematic literature search of the PubMed, Scopus, ScienceDirect and Google Scholar electronic databases was conducted on published studies that employed antifungal susceptibility testing (AFST) on clinical C. parapsilosis isolates globally. Seventy-nine eligible studies were included. Using meta-analysis of proportions, the overall pooled prevalence of three most important antifungal drugs; Fluconazole, Amphotericin B and Voriconazole resistant C. parapsilosis were calculated as 15.2% (95% CI: 9.2–21.2), 1.3% (95% CI: 0.0–2.9) and 4.7% (95% CI: 2.2–7.3), respectively. Based on study enrolment time, country/continent and AFST method, subgroup analyses were conducted for the three studied antifungals to determine sources of heterogeneity. Timeline and regional differences in C. parapsilosis prevalence of antifungal resistance were identified with the same patterns among the three antifungal drugs. These findings highlight the need to conduct further studies to assess and monitor the growing burden of antifungal resistance, to revise treatment guidelines and to implement regional surveillance to prevent further increase in C. parapsilosis drug resistance emerging recently.
Hydrological Regime and Fish Predation Regulate the Zooplankton Community Size Structure in a Tropical Floodplain Lake
Authors: Toruan Reliana Lumban , Dina Rahmi , Coggins Liah X. , Ghadouani Anas
Published: August 2022

Floodplain ecosystems are characterised by alternating flood and drought periods that can affect the structure of the aquatic community. Dynamic changes in the hydrological regimes from flooding to dry periods influence the migration and dispersal of aquatic fauna and the exchange of particulate matter and nutrients. Riverine floodplains are among the most productive ecosystems; however, increasing pressure from anthropogenic activities has altered the hydrological regimes, threatening aquatic biodiversity. In this study, we examined the temporal patterns of zooplankton community size structure and fish density during three distinct hydrological events in a tropical floodplain lake, Lake Tempe, Indonesia. We included fish density data and three contrasting hydrological conditions, moderate-, high-, and low-water periods, as the environmental factors regulating zooplankton community structure. In high- and low-water conditions, the ecosystem heterogeneity was characterised by high chlorophyll-a, total nitrogen, and total phosphorus concentrations; high fish density; and high zooplankton abundance and biomass. During the early flood period, the ecosystem was characterised by lower concentrations of trophic indicators and significant decreases in zooplankton abundance and biomass, as well as decreased fish density. While there was no clear association between hydrological conditions and zooplankton size structure, our findings indicate that fish predation probably suppressed zooplankton size diversity in Lake Tempe, shown by the dominant contribution of small-sized zooplankton towards total abundance and biomass under all hydrological conditions. Our results indicate that the patterns of environmental variables, zooplankton community, and fish density are affected by hydrological conditions, highlighting the role of water level fluctuation as the driving factor for zooplankton community structure. Our results also indicated that fish predation led to the development of a small-sized population of zooplankton in Lake Tempe.
A Proposal to Use Determinants of Annoyance in Wind Farm Planning and Management
Authors: van den Berg Frits (G. P.)
Published: August 2022

Wind energy in Europe is expected to grow at a steady, high pace, but opposition from residents to local wind farm plans is one of the obstacles to further growth. A large body of evidence shows that local populations want to be involved and respected for their concerns, but in practice, this is a complex process that cannot be solved with simple measures, such as financial compensation. The visual presence and the acoustic impact of a wind farm is an important concern for residents. Generally, environmental noise management aims to reduce the exposure of the population, usually based on acoustics and restricted to a limited number of sources (such as transportation or industry) and sound descriptors (such as Lden). Individual perceptions are taken into account only at an aggregate, statistical level (such as percentage of exposed, annoyed or sleep-disturbed persons in the population). Individual perceptions and reactions to sound vary in intensity and over different dimensions (such as pleasure/fear or distraction). Sound level is a predictor of the perceived health effects of sound, but explains only part of the reaction. The positive or negative perception of and attitude to the source of the sound is a better predictor of its effects. This article aims to show how the two perspectives (based on acoustics and on perception) can lead to a combined approach in the management of a wind farm aimed to reduce annoyance, not only on a sound level. An important aspect in this approach is what the sound means to people, leading to the following questions: is it associated with the experience of having no say in plans, does it lead to anxiety or worry and is it appropriate? The available knowledge will be applied to wind farm management, including planning as well as operation.
The shaping of a monocultural mindset through an Internationalised Curriculum. An ethnographic study
Authors: Pérez-Mendoza Marcos , Cuevas-Álvarez María Cruz , Arias-Moguel Gerardo Ulises
Published: August 2022

The following ethnographic study was carried out in a public HEI located in southeast Mexico. The aim of the study was to verify the assumption that students enrolled in a second language course can change their monocultural mindset into an intercultural one. For this ethnographic study, four groups of 35 students each, belonging to four different knowledge areas: administration, accounting, economics, and marketing, were observed with a moderated level of observation. The categories obtained were problem-solving, dress code, personal space, accent, and colloquialism. The findings reveal that Marketing students are more prone than their peers to make a mindset change due to specific aspects of their career: if they want to sell products or services in another culture, they have to think of the host culture in order for products or services to be accepted. The internationalized curriculum is a suggested strategy in order to become a host university.
Molecular and serological investigation of Lawsonia intracellularis in weanling foals in Türkiye
Authors: METİNER Kemal , METE Alper , EROL Erdal
Published: August 2022

Equine proliferative enteropathy caused by Lawsonia intracellularis has been described in weanlings in many different countries including the USA, Western Europe, Israel, Korea and Brazil but not investigated in Türkiye and Eastern Europe. The objective of the study was to determine the seroprevalence and fecal shedding of L. intracellularis in weanling foals. A cross-sectional study was designed in randomly selected 97 weanling foals with or without clinical signs from 3 different provinces of Türkiye. Total protein and albumin levels in serum samples from 97 foals were measured using automated biochemistry analyser. Serum samples and fecal samples were also tested by bELISA and real-time PCR to detect L. intracellularis-specific antibodies and -DNA, respectively. Seropositivity was found to be 25.8% by bELISA. However, none of the fecal samples were positive by real-time PCR. Statistically, no significant associations were found between seropositivity and clinical signs or serum ALB/TP levels. Seropositivity indicated the exposure of weanling foal population to L. intracellularis for the first time in Türkiye. Further investigations are needed to better understand the epidemiology of the disease in the weanlings as well as adult horse populations and potential wildlife resorvoirs in the country/region.