bluuebunny/crossref_metadata_2025 huggingface dataset:
Photonic Angular Momentum in Intense Light–Matter Interactions
Authors: Schimmoller Alex , Walker Spencer , Landsman Alexandra S.
Published: September 2024

Light contains both spin and orbital angular momentum. Despite contributing equally to the total photonic angular momentum, these components derive from quite different parts of the electromagnetic field profile, namely its polarization and spatial variation, respectively, and therefore do not always share equal influence in light–matter interactions. With the growing interest in utilizing light’s orbital angular momentum to practice added control in the study of atomic systems, it becomes increasingly important for students and researchers to understand the subtlety involved in these interactions. In this article, we present a review of the fundamental concepts and recent experiments related to the interaction of beams containing orbital angular momentum with atoms. An emphasis is placed on understanding light’s angular momentum from the perspective of both classical waves and individual photons. We then review the application of these beams in recent experiments, namely single- and few-photon transitions, strong-field ionization, and high-harmonic generation, highlighting the role of light’s orbital angular momentum and the atom’s location within the beam profile within each case.
Comparative Study on the Interest in Non-Uniform Rational B-Splines Representation versus Polynomial Surface Description in a Freeform Three-Mirror Anastigmat
Authors: Freslier Clément , Druart Guillaume , Fontbonne Alice , Lépine Thierry , Buisset Christophe , Agocs Tibor , Heliere Arnaud , Keller Fanny , Volatier Jean-Baptiste , Beaussier Stéphane , Jougla Paul
Published: September 2024

Novel freeform optical design methods can be classified in two categories, depending on whether they focus on the generation of a starting point or the development of new optimization tools. In this paper, we design a freeform three-mirror anastigmat (TMA) and compare different surface representations using either a differential ray tracer as a new optimization tool or a commercial ray tracer (ANSYS-ZEMAX OpticStudio). For differential ray tracing, we used FORMIDABLE (Freeform Optics Raytracer with Manufacturable Imaging Design cApaBiLitiEs), an optical design library with differential ray tracing and Non-Uniform Rational B-Splines (NURBS) optimization capabilities, available under the European Software Community License (ESCL). NURBS allow a freeform surface to be represented without needing any prior knowledge of the surface, such as the polynomial degree in polynomial descriptions. OpticStudio and other commercial optical design software are designed to optimize polynomial surfaces but are not well-suited to optimize NURBS surfaces, requiring a custom optical design library. In order to demonstrate the interest in using NURBS representation, we designed and independently optimized two freeform telescopes over different iteration cycles; with NURBS using FORMIDABLE or with XY polynomials using OpticStudio. We then compared the resulting systems using their root mean square field maps to assess the optimization quality of each surface representation. We also provided a full-system comparison, including mirror freeform departures. This study shows that NURBS can be a relevant alternative to XY polynomials for the freeform optimization of reflective three-mirror telescopes as it achieves more a uniform imaging quality in the field of view.
Nuclear Magnetic Resonance (NMR) Assessment of Bio and Crude Oil-Based Rejuvenation
Authors: Herndon Rebecca M. , Balasubramanian Jay , Abdelrahman Magdy , Woelk Klaus
Published: September 2024

Asphalt binders in pavements lose their stability through aging and eventually fail in the field. Using nuclear magnetic resonance (NMR) to monitor the primary longitudinal relaxation time of asphalt samples and the ratio of material that carries this primary relaxation time has been shown to indicate the impact of ultraviolet (UV) radiation on the aging of asphalt pavements. Longitudinal NMR relaxation was used to investigate two types of proposed asphalt rejuvenators, a bio-oil-based rejuvenator and a crude-oil-based rejuvenator. Two different binders with the performance grades (PG) 64-22 and 76-22 were considered for their interactions with the rejuvenators. After 72 h of exposure to intense UV radiation, specifically designed NMR relaxometry experiments were applied to compare the rejuvenation capabilities of the two rejuvenator samples. The crude oil-based rejuvenator was found to exhibit relaxation times similar to the binder samples while the bio-based material showed relaxation times that pointed to different nuclear hydrogen environments. Both rejuvenators reduced the primary relaxation time of the PG 76-22 binder, which indicates that their stiffness was reduced. Both types of rejuvenators also seemed to prevent the effects of UV aging. Two mechanisms of rejuvenation were identified by NMR relaxometry. The primary relaxation time can be used to indicate a change in stiffness while the primary ratio of the material is tied to oxidative aging. Oxidative aging creates distinct hydrogen environments due to asphaltene aggregation. The bio-based rejuvenator only reduced the binder’s stiffness, while the crude oil-based rejuvenator also reduced the aggregation of asphaltenes. Consequently, the bio-based rejuvenator could be classified as an asphalt softener, while the oil-based material acted like a true rejuvenator.
Targeted Metabolites and Transcriptome Analysis Uncover the Putative Role of Auxin in Floral Sex Determination in Litchi chinensis Sonn.
Authors: Chen Zhe , Yan Tingting , Abbas Farhat , Yang Mingchao , Wang Xianghe , Deng Hao , Zhang Hongna , Hu Fuchu
Published: September 2024

Litchi exhibits a large number of flowers, many flowering batches, and an inconsistent ratio of male and female flowers, frequently leading to a low fruit-setting rate. Floral sexual differentiation is a crucial phase in perennial trees to ensure optimal fruit production. However, the mechanism behind floral differentiation remains unclear. The objective of the study was to identify the role of auxin in floral differentiation at the transcriptional level. The results showed that the ratio of female flowers treated with naphthalene acetic acid (NAA) was significantly lower than that of the control stage (M0/F0). The levels of endogenous auxin and auxin metabolites were measured in male and female flowers at different stages of development. It was found that the levels of IAA, IAA-Glu, IAA-Asp, and IAA-Ala were significantly higher in male flowers compared to female flowers. Next-generation sequencing and modeling were employed to perform an in-depth transcriptome analysis on all flower buds in litchi ‘Feizixiao’ cultivars (Litchi chinensis Sonn.). Plant hormones were found to exert a significant impact on the litchi flowering process and flower proliferation. Specifically, a majority of differentially expressed genes (DEGs) related to the auxin pathway were noticeably increased during male flower bud differentiation. The current findings will enhance our comprehension of the process and control mechanism of litchi floral sexual differentiation. It also offers a theoretical foundation for implementing strategies to regulate flowering and enhance fruit production in litchi cultivation.
Occurrence of Yam Mosaic Virus and Yam Mild Mosaic Virus on Dioscorea spp. Germplasm Collection in Cuba—Epidemiology of Associated Diseases
Authors: González Ramírez José Efraín , Cabrera Mederos Dariel , Ventura Chávez Vaniert , González Vázquez Rosa Elena , Ojito-Ramos Katia , García Romero Liset , Salazar-Garcés Luis Fabián , Velastegui-Hernández Diana Catalina , Hernández Navarro Elena Vicenta , Leiva-Mora Michel , Giolitti Fabián , Portal Orelvis
Published: September 2024

Potyvirus diseases are one of the main challenges facing the production of yam (Dioscorea spp.). The objective of this study was to identify the potyviruses present in the Dioscorea spp. germplasm collection at Instituto de Investigaciones de Viandas Tropicales (INIVIT) to establish methodologies for the characterization of the associated diseases. For this purpose, immunochemical and molecular methods were used to identify the potyviruses present. The symptomatology of Dioscorea spp. at INIVIT’s germplasm collection was described. In addition, the severity and incidence in the germplasm collection and production areas were evaluated. As a result, the first report of yam mosaic virus (Potyvirus yamtesselati) and yam mild mosaic virus (Potyvirus yamplacidum) in Cuba is presented. The existence of resistant, tolerant, and susceptible cultivars to potyvirus-associated diseases in the germplasm collection was detected, and the incidence of these diseases was higher than 64% in the production areas evaluated. This study represents a step forward in the establishment of certification programs for propagating material of Dioscorea spp. in Cuba.
Koliella bifissiva sp. nov (Chlorellaceae, Chlorophyta) and Analysis of Its Organelle Genomes
Authors: Song Huiyin , Peng Hai , Fang Zhiwei , Zhang Baolong , Zhu Zhaolu , Xiao Zilan , Liu Guoxiang , Hu Yuxin
Published: September 2024

Chlorellacean members are common in aquatic or subaerial habitats, and many of them have significant economic value. Taxonomic reports and organelle genome data for the Nannochloris clade, an important subgroup within this family, are limited, hindering the understanding and exploitation of this clade. In this study, a fusiform-celled strain, FACHB-3607, was isolated from a pond in China. Through examination of morphological characteristics and phylogenetic analyses of rbcL, 18S rDNA, and ITS, it was identified as a new species within the Nannochloris clade, named Koliella bifissiva sp. nov. In addition, this study provided a first insight into the organellar genomes of the genus Koliella. The K. bifissiva chloroplast had a 99.8 kb genome, and the mitochondrion had a 40.8 kb genome, which are moderate sizes within the Nannochloris clade. Phylogenomic analysis showed that K. bifissiva is most closely related to Nannochloris sp. “desiccata”, followed by Marvania. In contrast, Picochlorum was the most distantly related species. The organelle genomes of the Nannochloris clade display dynamic evolution, reflected in variations in genome size, gene content and order, and selection pressure. This research enhances our knowledge of species diversity and evolutionary history in the Nannochloris clade.
Exploring Thinopyrum spp. Group 7 Chromosome Introgressions to Improve Durum Wheat Performance under Intense Daytime and Night-Time Heat Stress at Anthesis
Authors: Giovenali Gloria , Di Romana Maria Lia , Capoccioni Alessandra , Riccardi Vinicio , Kuzmanović Ljiljana , Ceoloni Carla
Published: September 2024

Durum wheat (DW) is one of the major crops grown in the Mediterranean area, a climate-vulnerable region where the increase in day/night (d/n) temperature is severely threatening DW yield stability. In order to improve DW heat tolerance, the introgression of chromosomal segments derived from the wild gene pool is a promising strategy. Here, four DW-Thinopyrum spp. near-isogenic recombinant lines (NIRLs) were assessed for their physiological response and productive performance after intense heat stress (IH, 37/27 °C d/n) had been applied for 3 days at anthesis. The NIRLs included two primary types (R5, R112), carriers (+) of a differently sized Th. ponticum 7el1L segment on the DW 7AL arm, and two corresponding secondary types (R69-9/R5, R69-9/R112), possessing a Th. elongatum 7EL segment distally inserted into the 7el1L ones. Their response to the IH stress was compared to that of corresponding non-carrier sib lines (−) and the heat-tolerant cv. Margherita. Overall, the R112+, R69-9/R5+ and R69-9/R112+ NIRLs exhibited a tolerant behaviour towards the applied stress, standing out for the maintenance of leaf relative water content but also for the accumulation of proline and soluble sugars in the flag leaf and the preservation of photosynthetic efficiency. As a result, all the above three NIRLs (R112+ > R69-9/R5+ > R69-9/R112+) displayed good yield stability under the IH, also in comparison with cv. Margherita. R112+ particularly relied on the strength of spike fertility/grain number traits, while R69-9/R5+ benefited from efficient compensation by the grain weight increase. This work largely confirmed and further substantiated the value of exploiting the wild germplasm of Thinopyrum species as a useful source for the improvement of DW tolerance to even extreme abiotic stress conditions, such as the severe heat treatment throughout day- and night-time applied here.
Enzymatic Characterization of SpPAL Genes in S. polyrhiza and Overexpression of the SpPAL3
Authors: Li Xiaoxue , Zhang Yinxing , Zhu Chunfeng , Zheng Pufan , Chen Cunkun , Zhang Na , Ji Haipeng , Dong Chenghu , Yu Jinze , Ren Jie , Zhu Yerong , Wang Yong
Published: September 2024

Phenylalanine ammonia-lyase (PAL, EC 4.3.1.5) catalyzes the deamination of phenylalanine, which is the initial step in the biosynthesis of phenylpropanoids. It serves as a crucial enzyme that facilitates the transfer of carbon from primary to secondary metabolism in plants. Duckweed is regarded as a promising chassis plant in synthetic biology research and application, due to its being rich in secondary metabolites and other advantages. The genes encoding PAL in Spirodela polyrhiza (L.) Schleid, the giant duckweed, were investigated in this study. Three SpPAL genes (SpPAL1–SpPAL3) were identified and cloned. All of them were successfully expressed in E. coli, and their recombinant proteins all showed PAL activity. In addition, SpPAL1 and SpPAL2 proteins could also utilize tyrosine as substrate, although the activity was low. A qRT-PCR analysis demonstrated that the expression of SpPAL3 was most pronounced in young fronds. It was found that the expression of SpPAL1 and SpPAL3 was significantly induced by MeJA treatment. Overexpression of SpPAL3 in Lemna turionifera inhibited the growth of fronds and adventitious roots in the transgenic plants, indicating the importance of SpPAL3 in duckweed besides its involvement in the secondary metabolism.
Innovative Application of Salophen Derivatives in Organic Electronics as a Composite Film with a Poly(3,4-Ethylenedioxythiophene)-poly(styrenesulfonate) Matrix
Authors: Sánchez Vergara María Elena , Jimenez Correa Omar , Ballinas-Indilí Ricardo , Cosme Ismael , Álvarez Bada José Ramón , Álvarez-Toledano Cecilio
Published: September 2024

In this work, we present the innovative synthesis of salophen (acetaminosalol) derivatives in a solvent-free environment by high-speed ball milling, using a non-conventional activation method, which allowed obtaining compounds in a shorter time and with a better yield. Furthermore, for the first time, the salophen derivatives were deposited as composite films, using a matrix of poly 3,4-ethylene dioxythiophene:polystyrene sulfonate (PEDOT:PSS) polymer. Significant findings include the transformation from the benzoid to the quinoid form of PEDOT post-IPA treatment, as evidenced by Raman spectroscopy. SEM analysis revealed the formation of homogeneous films, and AFM provided insights into the changes in surface roughness and morphology post-IPA treatment, which may be crucial for understanding potential applications in electronics. The optical bandgap ranges between 2.86 and 3.2 eV for PEDOT:PSS-salophen films, placing them as organic semiconductors. The electrical behavior of the PEDOT:PSS-salophen films undergoes a transformation with the increase in voltage, from ohmic to space charge-limited conduction, and subsequently to constant current, with a maximum of 20 mA. These results suggest the possible use of composite films in organic electronics.
Flexible Ti3C2Tx-Polyurethane Electrodes for Versatile Wearable Applications
Authors: Guo Qiaohang , Chen Kepei , Yu Wei , Peng Man , Yi Nuozhou , Wang Zhen , Zhou Peidi , Yang Kaihuai , Han Fei , Weng Mingcen
Published: September 2024

With the development of science and technology, wearable electronics are increasingly widely used in medical, environmental monitoring, and other fields. Thus, the demand for flexible electrodes is increasing. The two-dimensional material Ti3C2Tx has attracted much attention in the manufacture of flexible electrodes due to its excellent mechanical and electrical properties. However, the brittleness of pure Ti3C2Tx films has become a major obstacle for their use as flexible electrodes in wearable devices. Therefore, solving the brittleness problem of flexible electrodes based on Ti3C2Tx while maintaining the excellent performance of Ti3C2Tx has become an urgent problem. To solve this problem, Ti3C2Tx was compounded with waterborne polyurethane (WPU), and a Ti3C2Tx-WPU composite film with a hierarchical structure was constructed by evaporation-assisted self-assembly. The Ti3C2Tx-WPU composite film not only retains the excellent electrical conductivity of Ti3C2Tx (100 S m−1) but also has flexibility (20 MJ m−3). Furthermore, the Ti3C2Tx-WPU composite film is applied to functional devices such as contact pressure sensors and non-contact proximity sensors. Finally, the Ti3C2Tx-WPU composite film wearable device demonstrates its practical application potential in the field of wearable devices.
Comprehensive Study of Mechanical, Electrical and Biological Properties of Conductive Polymer Composites for Medical Applications through Additive Manufacturing
Authors: Paari-Molnar Emese , Kardos Kinga , Told Roland , Simon Imre , Sahai Nitin , Szabo Peter , Bovari-Biri Judit , Steinerbrunner-Nagy Alexandra , Pongracz Judit E. , Rendeki Szilard , Maroti Peter
Published: September 2024

Conductive polymer composites are commonly present in flexible electrodes for neural interfaces, implantable sensors, and aerospace applications. Fused filament fabrication (FFF) is a widely used additive manufacturing technology, where conductive filaments frequently contain carbon-based fillers. In this study, the static and dynamic mechanical properties and the electrical properties (resistance, signal transmission, resistance measurements during cyclic tensile, bending and temperature tests) were investigated for polylactic acid (PLA)-based, acrylonitrile butadiene styrene (ABS)-based, thermoplastic polyurethane (TPU)-based, and polyamide (PA)-based conductive filaments with carbon-based additives. Scanning electron microscopy (SEM) was implemented to evaluate the results. Cytotoxicity measurements were performed. The conductive ABS specimens have a high gauge factor between 0.2% and 1.0% strain. All tested materials, except the PA-based conductive composite, are suitable for low-voltage applications such as 3D-printed EEG and EMG sensors. ABS-based and TPU-based conductive composites are promising raw materials suitable for temperature measuring and medical applications.
Photo-Crosslinked Polyurethane—Containing Gel Polymer Electrolytes via Free-Radical Polymerization Method
Authors: Uyumaz Fatmanur , Yerkinbekova Yerkezhan , Kalybekkyzy Sandugash , Kahraman Memet Vezir
Published: September 2024

Using a novel technique, crosslinked gel polymer electrolytes (GPEs) designed for lithium-ion battery applications have been created. To form the photo crosslink via free-radical polymerization, a mixture of polyurethane acrylate (PUA), polyurethane methacrylate (PUMA), vinyl phosphonic acid (VPA), and bis[2-(methacryloyloxy)ethyl] phosphate (BMEP) was exposed to ultraviolet (UV) radiation during the fabrication process. The unique crosslinked configuration of the membrane increased its stability and made it suitable for use with liquid electrolytes. The resulting GPE has a much higher ionic conductivity (1.83 × 10−3 S cm−1) than the commercially available Celgrad2500 separator. A crosslinked structure formed by the hydrophilic properties of the PUA-PUMA blend and the higher phosphate content from BMEP reduced the leakage of the electrolyte solution while at the same time providing a greater capacity for liquid retention, significantly improving the mechanical and thermal stability of the membrane. GPP2 shows electrochemical stability up to 3.78 V. The coin cell that was assembled with a LiFePO4 cathode had remarkable cycling characteristics and generated a high reversible capacity of 149 mA h g−1 at 0.1 C. It also managed to maintain a consistent Coulombic efficiency of almost 100%. Furthermore, 91.5% of the original discharge capacity was maintained. However, the improved ionic conductivity, superior electrochemical performance, and high safety of GPEs hold great promise for the development of flexible energy storage systems in the future.
Effect of Different Porous Size of Porous Inorganic Fillers on the Encapsulation of Rosemary Essential Oil for PLA-Based Active Packaging
Authors: Cerdá-Gandia Raúl , Agüero Ángel , Arrieta Marina Patricia , Fenollar Octavio
Published: September 2024

Essential oils are interesting active additives for packaging manufacturing as they can provide the final material with active functionalities. However, they are frequently volatile compounds and can be degraded during plastic processing. In this work Rosmarinus officinalis (RO) essential oil was encapsulated into Diatomaceous earth (DE) microparticles and into Halloysite nanotubes (HNTs) and further used to produce eco-friendly active packaging based on polylactic acid (PLA). PLA-based composites and nanocoposites films based on PLA reinforced with DE + RO and HNTs + RO, respectively, were developed by melt extrusion followed by cast-film, simulating the industrial processing conditions. As these materials are intended as active food packaging films, the obtained materials were fully characterized in terms of their mechanical, thermal and structural properties, while migration of antioxidant RO was also assessed as well as the compostability at laboratory scale level. Both DE and HNTs were able to protect the Rosmarinus officinalis (RO) from thermal degradation during processing, allowing to obtain films with antioxidant properties as demonstrated by the antioxidant assays after the materials were exposed for 10 days to a fatty food simulant. The results showed that incorporating Rosmarinus officinalis encapsulated in either DE or HNTs and the good dispersion of such particles into the PLA matrix strengthened its mechanical performance and sped up the disintegration under composting conditions of PLA, while allowing to obtain films with antioxidant properties of interest as antioxidant active food packaging materials.
Hydrothermal Carbonization of Biomass for Electrochemical Energy Storage: Parameters, Mechanisms, Electrochemical Performance, and the Incorporation of Transition Metal Dichalcogenide Nanoparticles
Authors: Prieto Manuel , Yue Hangbo , Brun Nicolas , Ellis Gary J. , Naffakh Mohammed , Shuttleworth Peter S.
Published: September 2024

Given the pressing climate and sustainability challenges, shifting industrial processes towards environmentally friendly practices is imperative. Among various strategies, the generation of green, flexible materials combined with efficient reutilization of biomass stands out. This review provides a comprehensive analysis of the hydrothermal carbonization (HTC) process as a sustainable approach for developing carbonaceous materials from biomass. Key parameters influencing hydrochar preparation are examined, along with the mechanisms governing hydrochar formation and pore development. Then, this review explores the application of hydrochars in supercapacitors, offering a novel comparative analysis of the electrochemical performance of various biomass-based electrodes, considering parameters such as capacitance, stability, and textural properties. Biomass-based hydrochars emerge as a promising alternative to traditional carbonaceous materials, with potential for further enhancement through the incorporation of extrinsic nanoparticles like graphene, carbon nanotubes, nanodiamonds and metal oxides. Of particular interest is the relatively unexplored use of transition metal dichalcogenides (TMDCs), with preliminary findings demonstrating highly competitive capacitances of up to 360 F/g when combined with hydrochars. This exceptional electrochemical performance, coupled with unique material properties, positions these biomass-based hydrochars interesting candidates to advance the energy industry towards a greener and more sustainable future.
Facile Synthesis of Bis-Diphenylphosphine Oxide as a Flame Retardant for Epoxy Resins
Authors: Li Yan , Tian Chong , Cheng Guiqing , Li Chunhui , Wang Zhongwei
Published: September 2024

A phosphorus-containing compound, (oxybis(4,1-phenylene))bis(phenylphosphine oxide) (ODDPO), was successfully synthesized and used as a flame retardant for epoxy resin (EP). The results demonstrated that EP/ODDPO, containing 1.2 wt% phosphorus, achieved a vertical burning V-0 rating, with a limited oxygen index value of 29.2%, indicating excellent flame retardancy. Comprehensive evaluations revealed that ODDPO exhibited both gas-phase and condensed-phase flame-retardant effects on EP, with a particularly notable barrier effect. In addition, the incorporation of ODDPO had a minimal negative impact on the glass transition temperature (Tg) and thermal stability of the EP matrix. Compared to unmodified EP (EP-0), the Tg value and initial decomposition temperature of EP/ODDPO-1.2 decreased by only 7.6 °C and 10.0 °C, respectively. Moreover, the introduction of ODDPO significantly improved the hydrophobicity and water absorption resistance of epoxy materials, which is attributed to ODDPO’s rigidity and symmetric structure, reducing water molecule permeation. Furthermore, the dielectric properties of ODDPO-modified EP samples were strengthened compared to EP-0, due to the ODDPO’s symmetric structure reducing the polarity of the matrix. The above results indicated that ODDPO serves as an excellent flame retardant while enhancing other properties of the EP matrix, thereby contributing to the preparation and application of high-performance epoxy materials.
Fault Intelligent Diagnosis for Distribution Box in Hot Rolling Based on Depthwise Separable Convolution and Bi-LSTM
Authors: Guo Yonglin , Zhou Di , Chen Huimin , Yue Xiaoli , Cheng Yuyu
Published: September 2024

The finishing mill is a critical link in the hot rolling process, influencing the final product’s quality, and even economic efficiency. The distribution box of the finishing mill plays a vital role in power transmission and distribution. However, harsh operating conditions can frequently lead to distribution box damage and even failure. To diagnose faults in the distribution box promptly, a fault diagnosis network model is constructed in this paper. This model combines depthwise separable convolution and Bi-LSTM. Depthwise separable convolution and Bi-LSTM can extract both spatial and temporal features from signals. This structure enables comprehensive feature extraction and fully utilizes signal information. To verify the diagnostic capability of the model, five types of data are collected and used: the pitting of tooth flank, flat-headed sleeve tooth crack, gear surface crack, gear tooth surface spalling, and normal conditions. The model achieves an accuracy of 97.46% and incorporates a lightweight design, which enhances computational efficiency. Furthermore, the model maintains approximately 90% accuracy under three noise conditions. Based on these results, the proposed model can effectively diagnose faults in the distribution box, and reduce downtime in engineering.
Process Optimization in a Condiment SME through Improved Lean Six Sigma with a Surface Tension Neural Network
Authors: Vargas Manuel , Mosquera Rodolfo , Fuertes Guillermo , Alfaro Miguel , Perez Vergara Ileana Gloria
Published: September 2024

This study offers an innovative solution to address performance issues in the manufacturing process of garlic salt within a condiment-producing SME. A hybrid Lean/Six Sigma model utilizing a Surface Tension Neural Network (STNN) was implemented to control temperature and relative humidity in real-time. The model follows the Define, Measure, Analyze, Improve, Control (DMAIC) methodology to identify root causes and correlate them with waste. By integrating statistical tools, artificial intelligence, and engineering design principles, alternative solutions were evaluated to minimize waste. This document contributes to existing knowledge by demonstrating the integration of an STNN with the Lean/Six Sigma framework in condiment production, an area with limited empirical research. It underscores the benefits of advanced AI technologies in enhancing traditional process optimization methods. The STNN model achieved 97.31% accuracy for temperature classification and 97.37% for humidity, outperforming a Naive Bayes model, which attained 90% accuracy for both. The results showed a 3.15% increase in yield, saving 39.7 kg of waste per batch. Additionally, a 2.13-point improvement at the Six Sigma level was achieved, reducing defects per million opportunities by 551.722. These improvements resulted in significant cost savings, with a reduction in waste-related losses amounting to USD 1585 per batch. The study demonstrates that incorporating artificial intelligence into the Lean/Six Sigma methodology effectively addresses the limitations of traditional statistical methods. Significant improvements in yield and waste reduction highlight the potential of this approach, enhancing operational efficiency and profitability, and fostering sustainable manufacturing practices critical for SMEs’ competitiveness and sustainability in the global market.
A Numerical Simulation Study of the Dynamic Instability of Gas Swirling Flows in Cyclones
Authors: Sun Liqiang , Li Jiangfei , Xie Ming , Man Maoli , Zhao Jianqiang , Song Jianfei
Published: September 2024

The gas–phase flow field within a cyclone plays a critical role in the particle separation process. While previous research has primarily focused on the steady–state, time–averaged characteristics of this flow field, there has been limited investigation into its dynamic instability. This study seeks to address this gap by examining the dynamic instability of gas swirling flows in cyclones, offering new insights into their spatial and temporal dimensions. Numerical simulations were performed via large eddy simulation (LES) for the gas swirling flow in a reverse cyclone and tangential velocity was measured with a hot–wire anemometer (HWA). The model’s accuracy was validated against experimental data. The results demonstrate that the distributions of instantaneous tangential velocity and pressure exhibit spatial asymmetry and temporal instability across different sections of the cyclone. The dynamic instability of the gas swirling flow in the cyclone is the superposition of the spatial asymmetry and the temporal instability. These instabilities are more pronounced in the internal regions than the outer regions. Dynamic instability arises from the combined effects of rotational dynamics and wall curvature, leading to an eccentric rotation of the swirling center, particularly evident in the lower sections of the cyclone cone. This instability increases fluctuations in the instantaneous parameters, enhancing turbulence intensity and fine particle diffusion, and ultimately impairing both separation efficiency and particle size efficiency.
Efficient Biosynthesis of Monacolin J through Enzymatic Hydrolysis Using a Recombinant Lovastatin Hydrolase
Authors: He Wei , Chen Benshun , Yin Bin , Ye Jianren , He Yucai
Published: September 2024

Simvastatin is a widely used statin medication that is commonly prescribed to lower cholesterol levels and reduce the risk of cardiovascular events. It is marketed under the brand name Zocor and is known for its effectiveness in treating high cholesterol and managing cardiovascular disease. Monacolin J is an important precursor used to synthesize simvastatin and is mainly produced by chemical methods in industry. Here, monacolin J was synthesized through an enzymatic method under optimized reaction conditions. One recombinant Escherichia coli BL21 (DE3) strain containing lovastatin hydrolase (encoded by CDV55_102090) from Aspergillus turcosus was constructed, which effectively transformed 100 g/L of lovastatin to monacolin J within 3.5 h at pH 8.0 and 30 °C, with a conversion rate of >99.8%. Furthermore, the T5010, the temperature at which the residual activity was half of the initial enzymatic activity after 10 min of heat treatment, was >50 °C, indicating the tremendous potential of this bioprocess for synthesizing monacolin J at an industrial scale.
Parents’ Perspectives of Children with PKU: Assessing Parental Stress and Psychological Adjustment
Authors: Cazzorla Chiara , Di Riso Daniela , Gaiga Giacomo , De Cusatis Antonia , Spaggiari Silvia , Gragnaniello Vincenza , Loro Christian , Gueraldi Daniela , Schiavo Rossana , Burlina Alessandro P. , Burlina Alberto B.
Published: September 2024

Phenylketonuria (PKU) is an inborn error of metabolism resulting from a deficiency of phenylalanine hydroxylase enzyme activity. Diagnosis in the first days of life allows early initiation of dietary therapy. The maintenance of this treatment raises demanding management issues in everyday life, often resulting in a psychological burden for patients and families. In this brief report, we aimed to investigate parenting stress and parents’ perceptions of their child’s adjustment, focusing on correlations between the perspectives of mothers and fathers. We conducted an observational study, enrolling parents of pediatric patients (aged 2–18) diagnosed with PKU and treated from birth. A total of 20 parenting couples of 20 PKU-affected children were included. The mean Phe level was 301.60 µmol/L (SD = 128.39). Most PSI-SF and SDQ-P scores were below the clinically relevant threshold. Significant correlations emerged between paternal parenting stress and the child’s Phe level and, additionally, between mothers’ and fathers’ scores. Parents of PKU-affected children reported acceptable levels of parenting stress and their children’s psychological adjustment. However, fathers perceived greater stress in maintaining adequate Phe levels for their children. Our results suggest a similar perspective of both parents in relation to their child’s psychological adjustment. Therefore, the psychological well-being of PKU patients and their parents must be monitored to provide family-centered care and psychological support in the process of accepting a rare disease.
Upcycling Mill Scale and Aluminum Dross for Sustainable Materials Processing: Synthesis of Hercynite via Fe2O3-Al2O3-C Combustion
Authors: Kongkajun Nuntaporn , Cherdhirunkorn Benya , Kongkarat Somyote
Published: September 2024

This study investigates the potential of utilizing industrial by-products—mill scale (MS) and aluminum dross (AD)—as sources of Fe2O3 and Al2O3, respectively, for hercynite (FeAl2O4) production. Through combustion of MS-AD-graphite systems at 1550 °C under air atmosphere, hercynite-based refractory materials were synthesized. Results confirm the viability of this upcycling approach for hercynite synthesis. During the formation of hercynite, the development of a dendritic structure can be observed, which subsequently fuses into a grain shape. XRD phase analysis using the Rietveld method revealed that the major components of the product with a C/O ratio of 1 were 85.11% FeAl2O4, 10.99% Al2O3, and 3.9% C. For the product with a C/O ratio of 2, the composition was 82.4% FeAl2O4, 13.0% Al2O3, and 4.6% C. The combustion of raw pellets with a C/O ratio of 1 at 1550 °C for 1 h in a normal air atmosphere is economically viable for producing hercynite, yielding 85.11 wt%. This approach presents a sustainable and eco-friendly alternative to using commercial raw materials, potentially eliminating the need for virgin alumina and iron ore. By repurposing waste materials from the steel and aluminum industries, this study contributes to the circular economy and aligns with the goal of zero waste.
Modernity and Caste in Khatri and High-Caste Men’s Auto/Biographies
Authors: Malhotra Anshu
Published: September 2024

This paper studies the auto/biographies of high-caste middle-class Punjabi Khatri men, and those of cognate castes like Arora and Baniya, written in the first half of the twentieth century: men who were born in the second half of the nineteenth century or early twentieth century. While the discourse on caste under the colonial regime exploded, there was also an embarrassment about caste, or re-thinking its place in society among the upper-caste groups who invested in ideas of progress, improvement and scientism. It is argued that caste was referenced in the memoirs, life stories and self-reflexive writing when these men spoke of their familial backgrounds and admired the deep religiosity and devotionalism of their fathers even though some paternal practices were incongruent with the reformism of the sons. Caste is also in play when one traces the advantages of literacy, education, professional accomplishments, mobility, and reformist activities of men who came to have an important presence in public life. A number of these men had similar life trajectories, indicative of how some aspects of colonial educational and administrative structures could be utilized by them.
On the Ethics of Mediating Embodied Vulnerability to Violence
Authors: Durham Meenakshi Gigi
Published: September 2024

Media ethics has long been haunted by the question of representing human beings’ vulnerability to violence. While journalism and photojournalism have an obligation to report on the realities of violence and suffering in the world, the “spectacle of suffering” is fraught with ethical dilemmas. In this essay, I seek to theorize the ethics of vulnerability to violence in media representation. As a starting point, I argue for the politics of embodiment as a generative process that constitutes differential vulnerabilities. I move then to consider the way embodied vulnerabilities play out in the media, as exemplified by recent events such as the Black Lives Matter and MeToo movements as well as in times of war, from Vietnam to, more recently, Ukraine and Israel/Palestine. This leads to considerations of spectatorship: who looks and who is looked at? How are these relations of gazing related to the vectors of social and geopolitical power? Are images of embodied vulnerability simply media spectacles that reinforce power hierarchies, or are they powerful prosocial messages that might mobilize humanitarian activism? To address these epistemic questions, I propose that the feminist ethics of care encompasses an invitational rhetoric that can guide media praxis. Care ethics is aligned with various religious epistemologies, and because of that, I argue for it as an umbrella framework that has application in a variety of national and cultural contexts.
Airway Management and General Anesthesia in Pediatric Patients with Special Needs Undergoing Dental Surgery: A Retrospective Study
Authors: Ciccozzi Alessandra , Lupi Ettore , Necozione Stefano , Giovannetti Filippo , Oliva Antonio , Ciuffini Roberta , Angeletti Chiara , Marinangeli Franco , Piroli Alba
Published: September 2024

Background: The definition of patients with special needs (SNs) is used in the literature to refer to individuals with mental and physical disorders for whom the usual perioperative pathways are not applicable due to lack of cooperation, regardless of age. Studies in the literature recognize the appropriateness of general anesthesia for performing day surgery dental care in this type of patient. Objectives: The main objective was to assess the possible incidence of difficult airway management, understood as difficulty ventilating and/or intubating the patient. A secondary objective was to highlight the influence of general anesthesia on patient outcomes by testing the incidence of perioperative complications. Methods: The present retrospective, single-center, observational study involved 41 uncooperative patients aged between 3 and 17 undergoing dental surgery under general anesthesia. Data relating to airway management and general anesthesia present in the medical records were analyzed. Results: Tracheal intubation was successfully completed in all of the patients considered, and in no case did the patient have to be woken up because of difficulty in airway management. No perioperative complications attributable to anesthesia were found in any patients. Conclusions: From the present experience, it can be concluded that general anesthesia is a suitable option for performing dental care in pediatric subjects with special needs, and that although the peculiar perioperative management of these patients might increase the risk of possible anesthesia-related side effects, no complications have been encountered in any case.
A Systematic Literature Review of Existing Methods and Tools for the Criticality Assessment of Raw Materials: A Focus on the Relations between the Concepts of Criticality and Environmental Sustainability
Authors: Perossa Daniele , Rosa Paolo , Terzi Sergio
Published: September 2024

Critical raw materials have significant economic and social impacts across numerous sectors. Numerous artifacts have been developed to assess their criticality. However, there is no univocity around the factors determining criticality. A systematic literature review was conducted to consider all academic works and official reports on criticality assessment. The review aimed to classify these artifacts to provide a clear picture of the heterogenous literature, with a focus on the relationship between criticality and environmental sustainability. Works proposing or updating criticality assessment artifacts were included according to the eligibility criteria. Academic sources were drawn from the Scopus Database in 2023. Official reports included those considered seminal by academic literature. The risk of bias in the selection and classification of the 162 works was low, as the review sought to be comprehensive. The included artifacts are systematically classified. A mapping of the identified criticality assessment tools and methods has been developed. The review found that while environmental impacts are considered in several works, the theoretical connection between criticality and environmental sustainability is weak. Three perspectives on this relationship are identified and discussed. The main limitation of this study is the inability to analyze undisclosed artifacts. It was conducted under the Horizon Europe Programme (Grant Number 101091490).
SMALE: Hyperspectral Image Classification via Superpixels and Manifold Learning
Authors: Liao Nannan , Gong Jianglei , Li Wenxing , Li Cheng , Zhang Chaoyan , Guo Baolong
Published: September 2024

As an extremely efficient preprocessing tool, superpixels have become more and more popular in various computer vision tasks. Nevertheless, there are still several drawbacks in the application of hyperspectral image (HSl) processing. Firstly, it is difficult to directly apply superpixels because of the high dimension of HSl information. Secondly, existing superpixel algorithms cannot accurately classify the HSl objects due to multi-scale feature categorization. For the processing of high-dimensional problems, we use the principle of PCA to extract three principal components from numerous bands to form three-channel images. In this paper, a novel superpixel algorithm called Seed Extend by Entropy Density (SEED) is proposed to alleviate the seed point redundancy caused by the diversified content of HSl. It also focuses on breaking the dilemma of manually setting the number of superpixels to overcome the difficulty of classification imprecision caused by multi-scale targets. Next, a space–spectrum constraint model, termed Hyperspectral Image Classification via superpixels and manifold learning (SMALE), is designed, which integrates the proposed SEED to generate a dimensionality reduction framework. By making full use of spatial context information in the process of unsupervised dimension reduction, it could effectively improve the performance of HSl classification. Experimental results show that the proposed SEED could effectively promote the classification accuracy of HSI. Meanwhile, the integrated SMALE model outperforms existing algorithms on public datasets in terms of several quantitative metrics.
Error Analysis of Non-Time-Synchronized Lightning Positioning Method
Authors: Wang Yanhui , Yao Lijie , Min Yingchang , Liu Yali , Zhao Guo
Published: September 2024

Since the non-time-synchronized lightning positioning method does not rely on the time synchronization of the stations in the positioning system, it eliminates the errors arising from the pursuit of time synchronization and potentially achieves higher positioning accuracy. This paper provides a comprehensive overview of the errors present in the three-dimensional lightning positioning system. It compares the results of traditional positioning methods with those of non-time-synchronized lightning positioning algorithms. Subsequently, a simulation analysis of the positioning errors is conducted specifically for the non-time-synchronized lightning positioning method. The results show that (1) the non-time-synchronized lightning positioning method exhibits greater errors when utilizing two randomly positioned radiation sources for location determination. Consequently, the resulting positioning outcomes only provide a general overview of the lightning discharge. (2) The positioning outcomes resemble those of the traditional method when employing a fixed-coordinate beacon point. However, the errors in the three-dimensional positional coordinates of these fixed-coordinate beacon points significantly impact the deviations in the positioning results. This impact is positively correlated with the positional error of the beacon point, considering both the orientation and magnitude. (3) Similarly to the traditional method, the farther away from the center of the positioning network, the larger the radial error. (4) The spatial position of the selected fixed-coordinate beacon point has little influence on the error.
Two-Dimensional Legendre Polynomial Method for Internal Tide Signal Extraction
Authors: Zhang Yunfei , Luo Cheng , Chen Haibo , Cui Wei , Lv Xianqing
Published: September 2024

This study employs the two-dimensional Legendre polynomial fitting (2-D LPF) method to fit M2 tidal harmonic constants from satellite altimetry data within the region of 53°E–131°E, 34°S–6°N, extracting internal tide signals acting on the sea surface. The M2 tidal harmonic constants are derived from the sea surface height (SSH) data of the TOPEX/Poseidon (T/P), Jason-1, Jason-2, and Jason-3 satellites via t-tide analysis. We validate the 2-D LPF method against the 300 km moving average (300 km smooth) method and the one-dimensional Legendre polynomial fitting (1-D LPF) method. Through cross-validation across 42 orbits, the optimal polynomial orders are determined to be seven for 1-D LPF, and eight and seven for the longitudinal and latitudinal directions in 2-D LPF, respectively. The 2-D LPF method demonstrated superior spatial continuity and smoothness of internal tide signals. Further single-orbit correlation analysis confirmed generally higher correlation with topographic and density perturbations (correlation coefficients: 0.502, 0.620, 0.245; 0.420, 0.273, −0.101), underscoring its accuracy. Overall, the 2-D LPF method can use all regional data points, overcoming the limitations of single-orbit approaches and proving its effectiveness in extracting internal tide signals acting on the sea surface.