Air Quality of the Black Sea Region: Local and Long Range Transported Pollutants
Authors: Elagha Omar , Tuncel Gudral , Tusun Suat 
Published: July 2017

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</xml><![endif]--><p class="MsoNormal" style="margin-bottom: .0001pt; text-align: justify; line-height: normal; mso-layout-grid-align: none; text-autospace: none;"><span style="font-size: 12.0pt; font-family: 'Times New Roman','serif'; mso-ansi-language: EN-US;" lang="EN-US">Catalysis has manifested its role as a fundamental tool in pollution prevention. While catalysis has long been utilized in increasing efficiency, yield, and selectivity, it is now also recognized as accomplishing a wide range of green chemistry goals. Air pollutants produced by industrial and man-made emissions possesses a unique property that it could affect regional and global receptors. Measuring and defining the levels of pollutants and its sources whether it is local, regional or global should precede the precautions and measures that should be taken to reduce the levels of a particular pollutant. In this article the air quality at the Black Sea region of Turkey is being discussed. Moreover, it endeavors to locate the possible sources of the different pollutants at local, regional and long range transported scales. About 196 rainwater samples were collected over the Black Sea region of Amasra between 1995-1999 and analyzed for major and trace ions. Although statistical tools do provide information on the type of sources and processes affecting the site, they do not provide information on where these sources are located. A back trajectory has to be included in the evaluation to incorporate geographical information in analytical results. To compute the PSCF for each ion the back trajectories were computed using ECMWF model, which is an isentropic 3-D model. Then number of 1 hour-long segment of the 3.5 daylong trajectories in each defined sub-region is determined. This study shows that, the Black Sea region receives different amounts and types of anthropogenic pollutants via long-range transport according to trajectory models. The highest PSCF values for H<sup>+</sup> are calculated for central Europe and Russia have fairly high contribution to observed free acidity in our samples. The main source areas for SO<sub>4</sub><sup>2-</sup> were found to be central Europe and Northwestern Turkey (Marmara region or Istanbul–Kocaeli industrial area).</span></p><!--[if gte mso 9]><xml>

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Name="Note Heading"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Body Text 2"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Body Text 3"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Body Text Indent 2"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Body Text Indent 3"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Block Text"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Hyperlink"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="FollowedHyperlink"/>

<w:LsdException Locked="false" Priority="22" QFormat="true" Name="Strong"/>

<w:LsdException Locked="false" Priority="20" QFormat="true" Name="Emphasis"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Document Map"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Plain Text"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="E-mail Signature"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="HTML Top of Form"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="HTML Bottom of Form"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Normal (Web)"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="HTML Acronym"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="HTML Address"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="HTML Cite"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="HTML Code"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="HTML Definition"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="HTML Keyboard"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="HTML Preformatted"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="HTML Sample"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="HTML Typewriter"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="HTML Variable"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Normal Table"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="annotation subject"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="No List"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Outline List 1"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Outline List 2"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Outline List 3"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Simple 1"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Simple 2"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Simple 3"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Classic 1"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Classic 2"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Classic 3"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Classic 4"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Colorful 1"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Colorful 2"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Colorful 3"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Columns 1"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Columns 2"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Columns 3"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Columns 4"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Columns 5"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Grid 1"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Grid 2"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Grid 3"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Grid 4"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Grid 5"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Grid 6"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Grid 7"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Grid 8"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table List 1"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table List 2"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table List 3"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table List 4"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table List 5"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table List 6"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table List 7"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table List 8"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table 3D effects 1"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table 3D effects 2"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table 3D effects 3"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Contemporary"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Elegant"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Professional"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Subtle 1"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Subtle 2"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Web 1"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Web 2"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Web 3"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Balloon Text"/>

<w:LsdException Locked="false" Priority="39" Name="Table Grid"/>

<w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true"

Name="Table Theme"/>

<w:LsdException Locked="false" SemiHidden="true" Name="Placeholder Text"/>

<w:LsdException Locked="false" Priority="1" QFormat="true" Name="No Spacing"/>

<w:LsdException Locked="false" Priority="60" Name="Light Shading"/>

<w:LsdException Locked="false" Priority="61" Name="Light List"/>

<w:LsdException Locked="false" Priority="62" Name="Light Grid"/>

<w:LsdException Locked="false" Priority="63" Name="Medium Shading 1"/>

<w:LsdException Locked="false" Priority="64" Name="Medium Shading 2"/>

<w:LsdException Locked="false" Priority="65" Name="Medium List 1"/>

<w:LsdException Locked="false" Priority="66" Name="Medium List 2"/>

<w:LsdException Locked="false" Priority="67" Name="Medium Grid 1"/>

<w:LsdException Locked="false" Priority="68" Name="Medium Grid 2"/>

<w:LsdException Locked="false" Priority="69" Name="Medium Grid 3"/>

<w:LsdException Locked="false" Priority="70" Name="Dark List"/>

<w:LsdException Locked="false" Priority="71" Name="Colorful Shading"/>

<w:LsdException Locked="false" Priority="72" Name="Colorful List"/>

<w:LsdException Locked="false" Priority="73" Name="Colorful Grid"/>

<w:LsdException Locked="false" Priority="60" Name="Light Shading Accent 1"/>

<w:LsdException Locked="false" Priority="61" Name="Light List Accent 1"/>

<w:LsdException Locked="false" Priority="62" Name="Light Grid Accent 1"/>

<w:LsdException Locked="false" Priority="63" Name="Medium Shading 1 Accent 1"/>

<w:LsdException Locked="false" Priority="64" Name="Medium Shading 2 Accent 1"/>

<w:LsdException Locked="false" Priority="65" Name="Medium List 1 Accent 1"/>

<w:LsdException Locked="false" SemiHidden="true" Name="Revision"/>

<w:LsdException Locked="false" Priority="34" QFormat="true"

Name="List Paragraph"/>

<w:LsdException Locked="false" Priority="29" QFormat="true" Name="Quote"/>

<w:LsdException Locked="false" Priority="30" QFormat="true"

Name="Intense Quote"/>

<w:LsdException Locked="false" Priority="66" Name="Medium List 2 Accent 1"/>

<w:LsdException Locked="false" Priority="67" Name="Medium Grid 1 Accent 1"/>

<w:LsdException Locked="false" Priority="68" Name="Medium Grid 2 Accent 1"/>

<w:LsdException Locked="false" Priority="69" Name="Medium Grid 3 Accent 1"/>

<w:LsdException Locked="false" Priority="70" Name="Dark List Accent 1"/>

<w:LsdException Locked="false" Priority="71" Name="Colorful Shading Accent 1"/>

<w:LsdException Locked="false" Priority="72" Name="Colorful List Accent 1"/>

<w:LsdException Locked="false" Priority="73" Name="Colorful Grid Accent 1"/>

<w:LsdException Locked="false" Priority="60" Name="Light Shading Accent 2"/>

<w:LsdException Locked="false" Priority="61" Name="Light List Accent 2"/>

<w:LsdException Locked="false" Priority="62" Name="Light Grid Accent 2"/>

<w:LsdException Locked="false" Priority="63" Name="Medium Shading 1 Accent 2"/>

<w:LsdException Locked="false" Priority="64" Name="Medium Shading 2 Accent 2"/>

<w:LsdException Locked="false" Priority="65" Name="Medium List 1 Accent 2"/>

<w:LsdException Locked="false" Priority="66" Name="Medium List 2 Accent 2"/>

<w:LsdException Locked="false" Priority="67" Name="Medium Grid 1 Accent 2"/>

<w:LsdException Locked="false" Priority="68" Name="Medium Grid 2 Accent 2"/>

<w:LsdException Locked="false" Priority="69" Name="Medium Grid 3 Accent 2"/>

<w:LsdException Locked="false" Priority="70" Name="Dark List Accent 2"/>

<w:LsdException Locked="false" Priority="71" Name="Colorful Shading Accent 2"/>

<w:LsdException Locked="false" Priority="72" Name="Colorful List Accent 2"/>

<w:LsdException Locked="false" Priority="73" Name="Colorful Grid Accent 2"/>

<w:LsdException Locked="false" Priority="60" Name="Light Shading Accent 3"/>

<w:LsdException Locked="false" Priority="61" Name="Light List Accent 3"/>

<w:LsdException Locked="false" Priority="62" Name="Light Grid Accent 3"/>

<w:LsdException Locked="false" Priority="63" Name="Medium Shading 1 Accent 3"/>

<w:LsdException Locked="false" Priority="64" Name="Medium Shading 2 Accent 3"/>

<w:LsdException Locked="false" Priority="65" Name="Medium List 1 Accent 3"/>

<w:LsdException Locked="false" Priority="66" Name="Medium List 2 Accent 3"/>

<w:LsdException Locked="false" Priority="67" Name="Medium Grid 1 Accent 3"/>

<w:LsdException Locked="false" Priority="68" Name="Medium Grid 2 Accent 3"/>

<w:LsdException Locked="false" Priority="69" Name="Medium Grid 3 Accent 3"/>

<w:LsdException Locked="false" Priority="70" Name="Dark List Accent 3"/>

<w:LsdException Locked="false" Priority="71" Name="Colorful Shading Accent 3"/>

<w:LsdException Locked="false" Priority="72" Name="Colorful List Accent 3"/>

<w:LsdException Locked="false" Priority="73" Name="Colorful Grid Accent 3"/>

<w:LsdException Locked="false" Priority="60" Name="Light Shading Accent 4"/>

<w:LsdException Locked="false" Priority="61" Name="Light List Accent 4"/>

<w:LsdException Locked="false" Priority="62" Name="Light Grid Accent 4"/>

<w:LsdException Locked="false" Priority="63" Name="Medium Shading 1 Accent 4"/>

<w:LsdException Locked="false" Priority="64" Name="Medium Shading 2 Accent 4"/>

<w:LsdException Locked="false" Priority="65" Name="Medium List 1 Accent 4"/>

<w:LsdException Locked="false" Priority="66" Name="Medium List 2 Accent 4"/>

<w:LsdException Locked="false" Priority="67" Name="Medium Grid 1 Accent 4"/>

<w:LsdException Locked="false" Priority="68" Name="Medium Grid 2 Accent 4"/>

<w:LsdException Locked="false" Priority="69" Name="Medium Grid 3 Accent 4"/>

<w:LsdException Locked="false" Priority="70" Name="Dark List Accent 4"/>

<w:LsdException Locked="false" Priority="71" Name="Colorful Shading Accent 4"/>

<w:LsdException Locked="false" Priority="72" Name="Colorful List Accent 4"/>

<w:LsdException Locked="false" Priority="73" Name="Colorful Grid Accent 4"/>

<w:LsdException Locked="false" Priority="60" Name="Light Shading Accent 5"/>

<w:LsdException Locked="false" Priority="61" Name="Light List Accent 5"/>

<w:LsdException Locked="false" Priority="62" Name="Light Grid Accent 5"/>

<w:LsdException Locked="false" Priority="63" Name="Medium Shading 1 Accent 5"/>

<w:LsdException Locked="false" Priority="64" Name="Medium Shading 2 Accent 5"/>

<w:LsdException Locked="false" Priority="65" Name="Medium List 1 Accent 5"/>

<w:LsdException Locked="false" Priority="66" Name="Medium List 2 Accent 5"/>

<w:LsdException Locked="false" Priority="67" Name="Medium Grid 1 Accent 5"/>

<w:LsdException Locked="false" Priority="68" Name="Medium Grid 2 Accent 5"/>

<w:LsdException Locked="false" Priority="69" Name="Medium Grid 3 Accent 5"/>

<w:LsdException Locked="false" Priority="70" Name="Dark List Accent 5"/>

<w:LsdException Locked="false" Priority="71" Name="Colorful Shading Accent 5"/>

<w:LsdException Locked="false" Priority="72" Name="Colorful List Accent 5"/>

<w:LsdException Locked="false" Priority="73" Name="Colorful Grid Accent 5"/>

<w:LsdException Locked="false" Priority="60" Name="Light Shading Accent 6"/>

<w:LsdException Locked="false" Priority="61" Name="Light List Accent 6"/>

<w:LsdException Locked="false" Priority="62" Name="Light Grid Accent 6"/>

<w:LsdException Locked="false" Priority="63" Name="Medium Shading 1 Accent 6"/>

<w:LsdException Locked="false" Priority="64" Name="Medium Shading 2 Accent 6"/>

<w:LsdException Locked="false" Priority="65" Name="Medium List 1 Accent 6"/>

<w:LsdException Locked="false" Priority="66" Name="Medium List 2 Accent 6"/>

<w:LsdException Locked="false" Priority=