bluuebunny/crossref_metadata_2025 huggingface dataset:
Ileum Proteomics Identifies Distinct Pathways Associated with Different Dietary Doses of Copper–Fructose Interactions: Implications for the Gut–Liver Axis and MASLD
Authors: Xu Manman , Li Ming , Benz Frederick , Merchant Michael , McClain Craig J. , Song Ming
Published: July 2024

The interactions of different dietary doses of copper with fructose contribute to the development of metabolic dysfunction-associated steatotic liver disease (MASLD) via the gut–liver axis. The underlying mechanisms remain elusive. The aim of this study was to identify the specific pathways leading to gut barrier dysfunction in the ileum using a proteomics approach in a rat model. Male weanling Sprague Dawley rats were fed diets with adequate copper (CuA), marginal copper (CuM), or supplemented copper (CuS) in the absence or presence of fructose supplementation (CuAF, CuMF, and CuSF) for 4 weeks. Ileum protein was extracted and analyzed with an LC-MS. A total of 2847 differentially expressed proteins (DEPs) were identified and submitted to functional enrichment analysis. As a result, the ileum proteome and signaling pathways that were differentially altered were revealed. Of note, the CuAF is characterized by the enrichment of oxidative phosphorylation and ribosome as analyzed with the KEGG; the CuMF is characterized by an enriched arachidonic acid metabolism pathway; and focal adhesion, the regulation of the actin cytoskeleton, and tight junction were significantly enriched by the CuSF. In conclusion, our proteomics analysis identified the specific pathways in the ileum related to the different dietary doses of copper–fructose interactions, suggesting that distinct mechanisms in the gut are involved in the development of MASLD.
Taste Preference for Salt Predicts Salt Intake in a Chinese Population
Authors: He Qingfang , Du Xiaofu , Wang Lixin , Fang Yujia , Zhong Jieming , Hu Ruying
Published: July 2024

Objective: This study describes the association between taste preference for salt and actual salt intake, thus guiding and refining personal and public health campaigns designed to lower salt intake in China. Methods: A cross-sectional survey of 1489 residents aged 18 to 69 years was conducted in 2017 in China. A multistage random sampling strategy was used, and a combination of questionnaires and physical and laboratory measurements were conducted to collect baseline characteristics and knowledge, attitudes, and behavior (KAB) related to salt. A 24 h urine collection was obtained for sodium and potassium excretion analysis. Participants were divided into two groups, light taste preference and salty taste preference, according to their answer to the question “Compared to others, how do you think your taste preference is for salt?”. Results: The mean age of the 1489 participants was 46.26 years, 48.9% were males, over 1/3 (35.7%) were identified as hypertensive, and 317 (21.3%) self-reported a salty taste preference. The mean of 24 h urinary sodium excretion was 167.32 mmol/24 h, corresponding to 9.79 g salt/d intake, and the sodium-to-potassium ratio (Na/K) was 4.90. The 24 h urinary sodium excretion of salty taste preference (177.06 mmol/24 h) was significantly higher than that of light taste preference (164.69 mmol/24 h). The multiple logistic regression analysis showed that the salty taste preference group had significantly higher 24 h urinary sodium (ORa(95%CI) = 1.004(1.002–1.006)), diastolic blood pressure (DBP), proportion of greasy food preference, and drinking levels, but lower potassium excretion, response levels to most KAB questions, and regular physical activity compared to the light taste preference group. Conclusion: Self-reported taste preference for salt predicted actual salt intake, which was verified by 24 h urinary sodium monitoring. Taste preference for salt could be used as a proxy for intake in terms of targeted salt intake, nutrition, and health education.
Association of Sleep Quality and General, Mental, and Oral Health with Lifestyle Traits (Dietary Intake, Smoking Status) in Arthritis: A Cross-Sectional Study from the Canadian Community Health Survey (CCHS)
Authors: Gheisary Zohre , Hoja Ibrahim , Liu Juxin , Papagerakis Petros , Weber Lynn P. , Fenton Mark , Katselis George S. , Lieffers Jessica R. L. , Papagerakis Silvana
Published: July 2024

Arthritis is associated with health challenges. Lifestyle traits are believed to influence arthritis development and progression; however, data to support personalized treatment regimens based on holistic lifestyle factors are missing. This study aims to provide a comprehensive list of associations between lifestyle traits and the health status of individuals with arthritis in the Canadian population, using binary logistic regression analysis on data from the Canadian Community Health Survey, which includes 104,359 respondents. Firstly, we explored the association between arthritis and various aspects of health status including self-reported lifestyle factors. Secondly, we examined the associations between self-reported dietary intake and smoking status with general, mental, and oral health, and sleep disturbance among individuals both with and without arthritis. Our analysis revealed that individuals with arthritis reported considerably poorer general, mental, and oral health, and poorer sleep quality compared to those without arthritis. Associations were also found between self-reported dietary intake and various measures of health status in individuals with arthritis. Smoking and exposure to passive smoking were associated not only with arthritis but also with compromised sleep quality and poorer general, mental, and oral health in people with and without arthritis. This study highlights the need for personalized and holistic approaches that may include a combination of dietary interventions, oral health improvements, sleep therapies, and smoking cessation for improved arthritis prevention and care.
A Mediation Analysis of Obesity and Adiponectin Association with Postmenopausal Breast Cancer Risk: A Nested Cohort Study in the International Breast Cancer Intervention Study II (IBIS-II) Prevention Trial
Authors: Macis Debora , Bellerba Federica , Aristarco Valentina , Johansson Harriet , Guerrieri-Gonzaga Aliana , Lazzeroni Matteo , Sestak Ivana , Cuzick Jack , DeCensi Andrea , Bonanni Bernardo , Gandini Sara
Published: July 2024

Obesity is a risk factor for postmenopausal breast cancer (BC), and evidence suggests a role for adiponectin in the relationship between obesity and BC. We investigated whether adiponectin or other biomarkers mediate the effect of body mass index (BMI) on postmenopausal BC risk in a cohort study nested in the IBIS-II Prevention Trial. We measured adiponectin, leptin, IGF-I, IGFBP-1, high-sensitivity C-reactive protein, glycemia, insulin, HOMA-IR index, and SHBG in baseline and 12-month serum samples from 123 cases and 302 matched controls in the placebo arm of the IBIS-II Prevention trial. We conducted the main mediation analysis considering baseline BMI as an exposure and the 12-month adiponectin increase as a mediator after adjustment for the Tyrer–Cuzick score and the lipid-lowering medications/supplements use. In the multivariable Cox model, both the 12-month adiponectin increase (HR, 0.60; 95%CI, 0.36–1.00) and BMI were associated with BC risk (HR, 1.05; 95%CI, 1.00–1.09), with a 40% reduction in women with a 12-month increase in adiponectin. A significantly higher cumulative hazard of BC events was observed in obese women (BMI > 30) with decreased adiponectin (p = 0.0087). No mediating effect of the adiponectin increase on the total effect of BMI on BC risk was observed (natural indirect effect: HR, 1.00; 95%CI, 0.98–1.02). Raising adiponectin levels might be an attractive target for postmenopausal BC prevention.
Optimization of Laminated Bio-Polymer Fabrication for Food Packaging Application: A Sustainable Plasma-Activated Approach
Authors: Foli Giacomo , Capelli Filippo , Grande Mariachiara , Tagliabue Stefano , Gherardi Matteo , Minelli Matteo
Published: July 2024

The current level of packaging consumption imposes a need to fabricate single-use food packaging with renewable and compostable materials, such as bio-polyesters (e.g., polylactic acid, PLA and polybutylene succinate, PBS) or cellulose, but their use is still problematic. Fabrication of bio-compostable composites can specifically address impeding challenges, and adhesive lamination, achieved with compostable glue, is becoming more and more popular with respect to the less versatile hot lamination. In this context, plasma activation, a chemical-free oxidation technique of a material’s surface, is used to increase the affinity of three different biomaterials (cellulose, PLA and PBS) toward a compostable polyurethane adhesive to decrease its amount by gluing bio-polyesters to cellulose. Optical Microscopy reveals activation conditions that do not affect the integrity of the materials, while Water Contact Analyses confirm the activation of the surfaces, with contact angles decreased to roughly 50 deg in all cases. Unexpectedly, ζ-potential analyses and subtractive infrared spectroscopy highlight how the activation performed superficially etches cellulose, while for both PLA and PBS, a general decrease in surface potential and an increase in superficial hydroxyl group populations confirm the achievement of the desired oxidation. Thus, we rationalize continuous activation conditions to treat PLA and PBS and to glue them to neat cellulose. While no beneficial effect is observed with activated PLA, bi-laminate composites fabricated with activated PBS fulfill the benchmark for adhesion strength using less than before, while oxygen permeation analyses exclude plasma-induced etching even at a nanoscale.
Investigation on the Biaxial Flexural Strength of Universal Shade Resin-Based Composites
Authors: Sakuma Keiko , Horie Taku , Kishimoto Takafumi , Maesako Mayumi , Tomoda Shigetaka , Fujitani Morioki , Tsujimoto Akimasa
Published: July 2024

The biaxial flexural strength of universal shade and conventional dental resin-based composites before and after alkaline degradation was investigated. Disk samples were prepared from these resin-based composites, and some of the specimens were immersed in 0.1 M NaOH solution to create deteriorated samples. The biaxial flexural strength of the samples before and after the alkaline degradation test was measured and statistically tested. The fracture surfaces after the biaxial flexural test were observed using a scanning electron microscope. The results showed that the biaxial flexural strength of the paste-type universal shade resin-based composite before alkaline degradation was significantly (19%) higher than that of the conventional type, but no difference was observed between the materials after alkaline degradation. On the other hand, the biaxial flexural strength of the flowable universal shade resin-based composites was significantly (around 35%) lower than that of the conventional composite, with or without degradation. Although, for paste-type materials, the biaxial flexural strength of universal shade resin-based composites was higher than that of conventional resin-based composites before alkaline degradation, after degradation the two materials showed similar values. For flowable materials, the biaxial flexural strength of universal shade resin-based composites was lower than that of conventional resin-based composites regardless of the presence or absence of degradation processes. These results suggest that some caution should be used when deciding whether to use flowable universal shade resin-based composite to fill a cavity.
Ion Release and Apatite Formation of Resin Based Pit and Fissure Sealants Containing 45S5 Bioactive Glass
Authors: Choi Ji-Won , Han A Ruem , Yang Song-Yi
Published: July 2024

The purpose of this study was to evaluate a resin based pit and fissure sealant containing 45S5 bioactive glass (BAG) by examining its ion release, pH variation, and apatite-forming properties. To prepare the experimental materials, 45S5 BAG, used as a filler, was incorporated into the light curable resin matrix at concentrations of 0 (control), 12.5, 37.5, and 50.0 wt.%. Ion release, pH variation, and apatite formation (Raman spectrometer and scanning electron microscopy-energy-dispersive X-ray spectrometry measurements) were performed. While no ions were released from the control group, the experimental groups containing 45S5 BAG showed an increased release of Ca and P ions with increasing amounts of 45S5 BAG (p < 0.05). The pH of the experimental group remained high and was significantly different from the control group (p < 0.05). Unlike the control group, it was confirmed that the apatite peak was formed in the 50.0 wt.% BAG group for 90 days, and the apatite layer consisting of Ca and P was deposited on the surface. Thus, a resin based pit and fissure sealant containing 45S5 BAG is a promising material for preventing secondary caries by releasing ions and forming apatite.
Nanostructured Carbon Fibres (NCF): Fabrication and Application in Supercapacitor Electrode
Authors: Oyedotun Kabir O. , Makgopa Katlego , Nkambule Thabo T. , Mathe Mkhulu K. , Otun Kabir O. , Mamba Bhekie B.
Published: July 2024

A facile interconnected nanofibre electrode material derived from polybenzimidazol (PBI) was fabricated for a supercapacitor using a centrifugal spinning technique. The PBI solution in a mixture of dimethyl acetamide (DMA) and N, N-dimethylformamide (DMF) was electrospun to an interconnection of fine nanofibres. The as-prepared material was characterised by using various techniques, which include scanning electron microscopy (SEM), X-ray diffractometry (XRD), Raman, X-ray photoelectron spectroscopy (XPS), and Brunauer–Emmett–Teller (BET) among others. The specific surface area of the interconnected NCF material was noticed to be around 49 m2 g−1. Electrochemical properties of the material prepared as a single-electrode are methodically studied by adopting cyclic voltammetry, electrochemical impedance spectroscopy, and constant-current charge–discharge techniques. A maximum specific capacitance of 78.4 F g−1 was observed for the electrode at a specific current of 0.5 A g−1 in a 2.5 M KNO3 solution. The electrode could also retain 96.7% of its initial capacitance after a 5000 charge–discharge cycles at 5 A g−1. The observed capacitance and good cycling stability of the electrode are supported by its specific surface area, pore volume, and conductivity. The results obtained for this material indicate its potential as suitable candidate electrode for supercapacitor application.
Research on the Performance and Modification Mechanism of Gutta-Percha-Modified Asphalt
Authors: Yan Simeng , Cui Shichao , Guo Naisheng , Chu Zhaoyang , Zhang Jun , Yan Sitong , Jin Xin
Published: July 2024

Presently, there is a significant focus on the investigation and advancement of polymer-modified asphalt that is both high-performing and environmentally sustainable. This study thoroughly examined the performance and modification mechanism of gutta-percha (GP) as a novel asphalt modifier. The investigation was conducted using a combination of macro- and microscopic testing, as well as molecular dynamics simulations. This work primarily examined the compatibility of GP with asphalt molecular modeling. This paper used molecular dynamics to identify the most suitable mixing temperature. Next, the gray correlation theory was used to discuss the most effective method for preparing gutta-percha-modified asphalt (GPMA). The macro-rheological tests and microscopic performance analysis provided a full understanding of the impact of GP on asphalt properties and the process of alteration. The findings indicate that eucommia ulmoides gum (EUG) exhibits good compatibility with asphalt, while sulfur-vulcanized eucommia ulmoides gum (SEUG) does not demonstrate compatibility with asphalt. Both EUG and SEUG enhance the thermal stability and resistance to deformation of asphalt at high temperatures, with SEUG having a particularly notable effect. However, both additives do not improve the resistance of asphalt to cracking at low temperatures. The manufacturing method for EUG-modified asphalt (EUGMA) involves physical mixing, whereas sulfur-vulcanized eucommia ulmoides gum-modified asphalt (SEUGMA) involves physical mixing together with certain chemical processes. This research establishes a theoretical foundation for the advancement of GP as a novel environmentally friendly and highly effective asphalt modification.
Fabrication of Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate)/ZnO Nanocomposite Films for Active Packaging Applications: Impact of ZnO Type on Structure–Property Dynamics
Authors: Vanheusden Chris , Samyn Pieter , Vackier Thijs , Steenackers Hans , D’Haen Jan , Peeters Roos , Buntinx Mieke
Published: July 2024

Bio-based and biodegradable polyhydroxyalkanoates (PHAs) have great potential as sustainable packaging materials. The incorporation of zinc oxide nanoparticles (ZnO NPs) could further improve their functional properties by providing enhanced barrier and antimicrobial properties, although current literature lacks details on how the characteristics of ZnO influence the structure–property relationships in PHA/ZnO nanocomposites. Therefore, commercial ZnO NPs with different morphologies (rod-like, spherical) and silane surface modification are incorporated into poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBHHx) via extrusion and compression molding. All ZnO NPs are homogeneously distributed in the PHBHHx matrix at 1, 3 and 5 wt.%, but finer dispersion is achieved with modified ZnO. No chemical interactions between ZnO and PHBHHx are observed due to a lack of hydroxyl groups on ZnO. The fabricated nanocomposite films retain the flexible properties of PHBHHx with minimal impact of ZnO NPs on crystallization kinetics and the degree of crystallinity (53 to 56%). The opacity gradually increases with ZnO loading, while remaining translucent up to 5 wt.% ZnO and providing an effective UV barrier. Improved oxygen barrier and antibacterial effects against S. aureus are dependent on the intrinsic characteristics of ZnO rather than its morphology. We conclude that PHBHHx retains its favorable processing properties while producing nanocomposite films that are suitable as flexible active packaging materials.
The Influence of Different Sera on the Anti-Infective Properties of Silver Nitrate in Biopolymer Coatings
Authors: Nonhoff Melanie , Puetzler Jan , Hasselmann Julian , Fobker Manfred , Niemann Silke , Gosheger Georg , Schulze Martin
Published: July 2024

The widespread prevalence of periprosthetic joint infections (PJIs) poses significant challenges in orthopedic surgeries, with pathogens such as Staphylococcus epidermidis being particularly problematic due to their capability to form biofilms on implants. This study investigates the efficacy of an innovative silver nitrate-embedded poly-L-lactide biopolymer coating designed to prevent such infections. The methods involved applying varying concentrations of silver nitrate to in vitro setups and recording the resultant bacterial growth inhibition across different serum environments, including human serum and various animal sera. Results highlighted a consistent and significant inhibition of S. epidermidis growth at all tested concentrations in each type of serum without adverse interactions with serum proteins, which commonly compromise antimicrobial efficacy. This study concludes that the silver nitrate-embedded biopolymer coating exhibits potent antibacterial properties and has potential for use in clinical settings to reduce the incidence of PJIs. Furthermore, the findings underscore the importance of considering serum interactions in the design and testing of antimicrobial implants to ensure their effectiveness in actual use scenarios. These promising results pave the way for further research to validate and refine this technology for clinical application, focusing on optimizing silver ion release and assessing biocompatibility in vivo.
Effects of Nozzle Temperature on Mechanical Properties of Polylactic Acid Specimens Fabricated by Fused Deposition Modeling
Authors: Rivera-López Fernando , Pavón María M. Laz , Correa Eduardo Cabello , Molina María Hernández
Published: July 2024

This paper investigates the effect of nozzle temperature, from 180 to 260 °C, on properties of polylactic acid (PLA) samples manufactured by fused deposition modeling (FDM) technology. The main objective of this research is to determinate an optimum nozzle temperature relative to tensile, flexural and compressive properties of printed specimens. After manufacturing, the samples exhibit an amorphous structure, without crystallization effects, independently of the fabrication temperature. In order to determine the influence of printing temperature on mechanical properties, uniaxial tensile, three-point flexural and compression strength tests were carried out. The obtained results suggest that a relative low printing temperature could reduce the material flow and decrease the density of the final prototype, with a negative effect on both the quality and the mechanical properties of the pieces. If temperature increases up to 260 °C, an excess of material can be deposited, but with no significant negative effect on mechanical parameters. There is an optimum nozzle temperature interval, depending on the considered piece and test, for which mechanical values can be optimized. Taking into account all tests, a recommended extruder temperature interval may be identified as 220–240 °C. This range encompasses all mechanical parameters, avoiding the highest temperature where an excess of material was observed. For this printing temperature interval, no significant mechanical variations were appreciated, which corresponds to a stable behavior of the manufactured specimens.
Injectable Hydrogels in Cardiovascular Tissue Engineering
Authors: Patel Raj , Patel Dhruvi
Published: July 2024

Heart problems are quite prevalent worldwide. Cardiomyocytes and stem cells are two examples of the cells and supporting matrix that are used in the integrated process of cardiac tissue regeneration. The objective is to create innovative materials that can effectively replace or repair damaged cardiac muscle. One of the most effective and appealing 3D/4D scaffolds for creating an appropriate milieu for damaged tissue growth and healing is hydrogel. In order to successfully regenerate heart tissue, bioactive and biocompatible hydrogels are required to preserve cells in the infarcted region and to bid support for the restoration of myocardial wall stress, cell survival and function. Heart tissue engineering uses a variety of hydrogels, such as natural or synthetic polymeric hydrogels. This article provides a quick overview of the various hydrogel types employed in cardiac tissue engineering. Their benefits and drawbacks are discussed. Hydrogel-based techniques for heart regeneration are also addressed, along with their clinical application and future in cardiac tissue engineering.
In-Plane Compression Properties of Continuous Carbon-Fiber-Reinforced Composite Hybrid Lattice Structures by Additive Manufacturing
Authors: Jin Lingqi , Shi Jun , Chen Zhixin , Wang Zhiyang , Zhi Yangfan , Yang Lei , Xiao Xinyi
Published: July 2024

Continuous-fiber-reinforced composite lattice structures (CFRCLSs) have garnered attention due to their lightweight and high-strength characteristics. Over the past two decades, many different topological structures including triangular, square, hexagonal, and circular units were investigated, and the basic mechanical responses of honeycomb structures under various load conditions, including tension, compression, buckling, shear, and fatigue were studied. To further improve the performance of the honeycombs, appropriate optimizations were also carried out. However, the mechanical properties of a single lattice often struggle to exceed the upper limit of its structure. This paper investigates the effect of permutation and hybrid mode on the mechanical properties of CFRCLSs by comparing five structures: rhomboid (R-type), octagon orthogonal array (OOA-type), octagon hypotenuse array (OHA-type), octagon nested array (ONA-type), and rhomboid circle (RC-type), with the conventional hexagonal structure (H-type). CFRCLS samples are fabricated using fused filament fabrication (FFF), with carbon-fiber-reinforced polylactic acid (PLA) as the matrix. The in-plane compression properties, energy absorption characteristics, and deformation behaviors of the hybrid structures were studied by experimental tests. The results demonstrate that different permutation and hybrid modes alter the deformation behaviors and mechanical properties of the structures. Taking elastic modulus as an example, the values of H-type, R-type, OOA-type, OHA-type, ONA-type, and RC-type are, respectively, 6.08 MPa, 5.76 MPa, 19.0 MPa, 10.3 MPa, 31.7 MPa, and 73.2 MPa, while the ratio of their masses is 1:1:1.10:1.52:1.66. Furthermore, hybrid lattice structures exhibit significantly improved mechanical properties compared to single lattice structures. Compared to the single structure R-type, the RC-type increases elastic modulus, yield strength, and energy absorption, respectively, by 12.7 times, 5.4 times, and 4.4 times.
Characterization of Melt-Spun Recycled PA 6 Polymer by Adding ZnO Nanoparticles during the Extrusion Process
Authors: Ludaš Dujmić Anja , Radičić Rafaela , Ercegović Ražić Sanja , Cingesar Ivan Karlo , Glogar Martinia , Jurov Andrea , Krstulović Nikša
Published: July 2024

With recent technological advances and the growing interest in environmentally friendly fiber production processes, the textile industry is increasingly turning to the spinning of filaments from recycled raw materials in the melt spinning process as the simplest method of chemical spinning of fibers. Such processes are more efficient because the desired active particles are melt-spun together with the polymer. The study investigates the melt spinning of recycled polyamide 6 (PA 6) fibers modified with zinc oxide nanoparticles (ZnO NPs) in concentrations ranging from 0.1 to 2.0 wt% of the polymer. The extrusion process was optimized under laboratory conditions. An analysis of the effectiveness of the nanoparticle distribution and chemical composition was performed using scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy (EDS), differential scanning calorimetry (DSC), and Fourier transform infrared spectroscopy (FTIR). The results of the thermal analysis show an increase in the glass transition temperature of the extruded material from 50.97 °C (raw polymer) to 51.40 °C to 57.98 °C (polymer modified with ZnO NPs) and an increase in the crystallization point from 148.19 °C to a temperature between 175.61 °C and 178.16 °C, while the molar enthalpy (ΔHm) shows a decreasing trend from 65.66 Jg−1 (raw polymer) to 48.23 Jg−1 (PA 6 2.0% ZnO). The FTIR spectra indicate PA 6 polymer, with a characteristic peak at the wavelength 1466 cm−1, but pure ZnO and PA 6 blended with ZnO show a characteristic peak at 2322 cm−1. The distribution of nanoparticles on the fiber surface is more or less randomly distributed and the different size of NPs is visible. These results are confirmed by the EDS results, which show that different concentrations of Zn are present. The mechanical stability of the extruded polymer modified with NPs is not affected by the addition of ZnO NPs, although the overall results of strength (2.56–3.22 cN/tex) and modulus of elasticity of the polymer (28.83–49.90 cN/tex) are lower as there is no drawing process at this stage of the experiment, which certainly helps to increase the final strength of the fibers. The results indicate the potential of modification with ZnO NPs for further advances in sustainable fiber production.
Sequential Cascade Doping of Conjugated-Polymer-Wrapped Carbon Nanotubes for Highly Electrically Conductive Platforms
Authors: Lee Da Young , Choi Da Eun , Ahn Yejin , Kye Hyojin , Kim Min Seon , Kim Bong-Gi
Published: July 2024

To explore a highly conductive flexible platform, this study develops PIDF-BT@SWCNT by wrapping single-walled carbon nanotubes (SWCNTs) with a conjugated polymer, PIDF-BT, known for its effective doping properties. By evaluating the doping behaviors of various dopants on PIDF-BT, appropriate dopant combinations for cascade doping are selected to improve the doping efficiency of PIDF-BT@SWCNT. Specifically, using F4TCNQ or F6TCNNQ as the first dopant, followed by AuCl3 as the second dopant, demonstrates remarkable doping efficiency, surpassing that of the individual dopants and yielding an exceptional electrical conductivity exceeding 6000 S/cm. Characterization using X-ray photoelectron spectroscopy and Raman spectroscopy elucidates the doping mechanism, revealing an increase in the proportion of electron-donating atoms and the ratio of quinoid structures upon F4TCNQ/AuCl3 cascade doping. These findings offer insights into optimizing dopant combinations for cascade doping, showcasing its advantages in enhancing doping efficiency and resulting electrical conductivity compared with single dopant processes.
Advances in Natural Polymers: Extraction Methods and Applications
Authors: Vasile Cornelia , Aguirre-Álvarez Gabriel , Sun Xiao-Feng
Published: July 2024

Biomass-based alternatives for the manufacturing of bioplastic materials are important aspects of a more sustainable future; their physicochemical properties need to be able to compete with the existing market to establish them as a viable alternative [...]
Management of Production Processes in a Heating Company
Authors: Garbier Milan , Corejova Tatiana
Published: July 2024

This paper is focused on researching the behaviour of heating companies in connection with current developments in the electricity market and flexibility in the context of market behaviour. The work assesses the increase in profitability through the creation of a technical–economic model using an objective function with profit maximization. The objective of the paper is to present the procedure and methodology for creating a model using the basic scheme of production processes integrated into the system platform. The result of the work is a comparative analysis of modelled cases of implemented operation deployment according to a defined period and modelling modes on selected time series. The description of individual outputs demonstrates the economic advantage of using combinations of modes of combined electricity and heat production, and non-combined electricity and heat production, including the use of heat-suppression mode because of overproduction of electricity.
Microwave-Assisted Solvent- and Cu(I)-Free Sonogashira C-C Cross-Coupling Catalysed by Pd Ionanofluids
Authors: Matias Inês A. S. , Ribeiro Ana P. C. , Martins Luísa M. D. R. S.
Published: July 2024

The microwave-assisted Sonogashira C-C cross-coupling reaction catalysed by Pd ionanofluids based on bis(trifluoromethane-sulfonyl)imide (NTf2) ionic liquids, [Cnmim][NTf2] (n = 4, 6 or 8), is described here. An organic solvent- and Cu(I)-free methodology running under very mild conditions was established by creating in situ catalysts from Pd(II) salts and [Cnmim][NTf2]. The microwave-irradiated catalytic systems quickly yielded almost quantitative conversions of 4-bromoanisole and phenylacetylene (model reaction) into the desired 1-methoxy-4-(phenylethynyl)benzene as a single product, and a good recyclability of the Pd ionanofluids.
Cupuassu Fruit, a Non-Timber Forest Product in Sustainable Bioeconomy of the Amazon—A Mini Review
Authors: Rosa Jeane Santos da , Oliveira Moreira Paula Isabelle , Carvalho Ana Vânia , Freitas-Silva Otniel
Published: July 2024

This study examines the importance of cupuassu, a tropical fruit native to the Amazon, to Brazil’s biodiversity, the Amazon biome, and its potential for economic development. Cupuassu is a Non-Timber Forest Product and a fruit of the Theobroma genus, which also includes cocoa. Just in the state of Pará alone, cupuassu production in 2019 was over 4100 t with a gross value of 2.6 million USD produced. However, cupuassu cultivation still needs investment through technological advances to overcome threats such as witches’ broom disease and mycotoxin contamination. Cupuassu fruit is composed of pulp, seeds, and a shell; all these parts have a chemical composition with numerous bioactive compounds, especially the seeds, which also contain stimulant compounds, besides lipids and proteins. The processing of the whole cupuassu fruit has its economic value in the commercialization of the pulp, the extraction of cupuassu butter, and a product called Cupulate®. However, in this process, the cake resulting from the oil pressing, often considered a waste product, has potential as a source of proteins, peptides, lipids, and bioactive molecules with functional and nutritional properties. Recycling this fruit processing waste can create high-value-added products for various industries and promote a circular economy.
Enhanced Management of Unified Energy Systems Using Hydrogen Fuel Cell Combined Heat and Power with a Carbon Trading Scheme Incentivizing Emissions Reduction
Authors: Wang Yuelong , Wang Weiqing , Li Xiaozhu , Yu Weiwei
Published: July 2024

In the quest to achieve “double carbon” goals, the urgency to develop an efficient Integrated Energy System (IES) is paramount. This study introduces a novel approach to IES by refining the conventional Power-to-Gas (P2G) system. The inability of current P2G systems to operate independently has led to the incorporation of hydrogen fuel cells and the detailed investigation of P2G’s dual-phase operation, enhancing the integration of renewable energy sources. Additionally, this paper introduces a carbon trading mechanism with a refined penalty–reward scale and a detailed pricing tier for carbon emissions, compelling energy suppliers to reduce their carbon footprint, thereby accelerating the reduction in system-wide emissions. Furthermore, this research proposes a flexible adjustment mechanism for the heat-to-power ratio in cogeneration, significantly enhancing energy utilization efficiency and further promoting conservation and emission reductions. The proposed optimization model in this study focuses on minimizing the total costs, including those associated with carbon trading and renewable energy integration, within the combined P2G-Hydrogen Fuel Cell (HFC) cogeneration system. Employing a bacterial foraging optimization algorithm tailored to this model’s characteristics, the study establishes six operational modes for comparative analysis and validation. The results demonstrate a 19.1% reduction in total operating costs and a 22.2% decrease in carbon emissions, confirming the system’s efficacy, low carbon footprint, and economic viability.
A Study on Fault Localization Method of Three-Terminal Multi-Section Overhead Line–Cable Hybrid Line Using MEEMD Combined with Teager Energy Operator Algorithm
Authors: Cao Wensi , Zhang Fuqian , Chen Xi , Zhang Bin , Li Jifang , Xu Mingming
Published: July 2024

An improved fault localization method combining total aggregate empirical modal decomposition (MEEMD) and Teager energy operator (TEO) is proposed to address the fault localization issue of three-terminal multi-segment overhead line–cable hybrid transmission lines. This method solves the fault localization problem caused by wave impedance discontinuity in hybrid lines. First, the MEEMD algorithm, which improves modal aliasing, and the Teager energy operator, which reflects transient energy changes, are combined for the accurate detection of faulty traveling wave heads. The fault line section determination condition within the fault branch is used to determine the overhead line section or cable section where the fault is located after determining the faulty branch line. This condition is based on the time difference between the initial traveling wave of the fault arriving at each end measurement point and the T-node. Ultimately, the fault distance is determined using the double-ended traveling wave technique. By combining PSCAD and MATLAB for simulation verification, the accuracy of the ranging method is compared and analyzed, and the results show that the method is able to ensure the accuracy of ranging at different fault locations and transition resistances. Additionally, the localization error is basically kept within 30 m, which significantly improves the accuracy of fault localization.
Experimental Study on Edge Water Invasion of Strongly Heterogeneous Carbonate Gas Reservoirs Based on NMR Technology
Authors: Hu Jiangtao , Yang Shenglai , Jiang Yi , Deng Hui , Wang Mengyu , You Li , Li Qinyi , Bai Haoyan , Shen Bin
Published: July 2024

Controlling the extent of water invasion in the reservoir and mitigating its detrimental effects on gas well production and natural gas recovery have long been a challenging task in the efficient development of strongly heterogeneous edge water gas reservoirs. To elucidate the edge water invasion mechanism of strongly heterogeneous carbonate gas reservoirs, this study investigates the pore throat characteristics and fluid mobility from both qualitative and quantitative aspects, leveraging natural core observations, cast thin sections, scanning electron microscopy (SEM), and nuclear magnetic resonance (NMR) tests with centrifuge experiments. A core-scale edge water invasion simulation experiment was conducted under online NMR monitoring to examine the dynamic gas production characteristics of the three types of reservoirs during the water invasion process and to elucidate the formation mechanism and distribution pattern of water-sealed gas. Research findings indicate that carbonate reservoirs typically exhibit a diverse range of pore types, including various types of fractures and cavities. Fractures significantly enhance reservoir connectivity, thereby increasing fluid mobility, but also lead to strong non-uniform water invasion. In contrast, cavities substantially improve the storage capacity of the reservoir and can retard the advancement of the water invasion front, thereby alleviating the adverse effects of water invasion. The ultimate recovery rates of fracture-type, cavity-type, and fracture-cavity cores in the water invasion simulation experiment were 29.81%, 64.87%, and 53.03%, respectively. Premature water breakthroughs in the reservoir can result in a large number of gases in matrix pores and even cavities being sealed by formation water, rendering them unrecoverable, which seriously impacts the gas recovery rate of the reservoir.
Analysis of Bubble-Flow Characteristics in Scavenge Pipe and Establishment of a Flow-Prediction Model
Authors: Liang Xiaodi , Wang Suofang , Shen Wenjie
Published: July 2024

In the modern aerospace industry, the importance of a lubrication system is self-evident for aero-engines, and the aero-engine bearing chamber return line is an even more challenging environment, as it involves a complex two-phase flow. The designer of the scavenge pipe needs to have an accurate understanding of the flow conditions in the scavenge pipe. This paper establishes a visual scavenge pipe test system. The flow direction was vertical flow, the test temperature was 370 k, and a high-speed camera was used to take high-definition flow photographs, which can observe the three main flow types: bubble flow, slug flow, and annular flow. Code program was created to analyze many pictures taken to obtain the apparent flow rate and perimeter of bubbles in the pipe under different flow conditions and to explore the gas–liquid two-phase flow in the scavenge pipe. A support vector machine (SVM) was used for data regression prediction, and the converted velocities of the gas–oil phases were inputted as eigenvalues to obtain the predicted values of bubble-flow velocity. The bubble-flow analysis prediction model established in this paper has a good prediction effect with root mean square error RMSE = 0.0172, which can more objectively and accurately describe the bubble-flow characteristics in the scavenge pipe.
Shear-Wave Velocity Prediction Based on the CNN-BiGRU Integrated Network with Spatiotemporal Attention Mechanism
Authors: Liu Yaqi , Gao Chuqiao , Zhao Bin
Published: July 2024

Shear wave velocity is one of the important parameters reflecting the lithological and physical properties of reservoirs, and it is widely used in the fields of lithology and fluid property identification, reservoir evaluation, seismic data processing, and interpretation. However, due to the high cost and challenge of obtaining shear wave velocity, only a few key wells are measured. Considering the intricate nonlinear mapping relationship between shear wave velocity and conventional logging data, an integrated network incorporating an attention mechanism, a convolutional neural network, and a bidirectional gated recurrent unit (STACBiN) is proposed for predicting shear wave velocity. The impact of conventional logging data on shear wave velocity is analyzed, thus employing the attention mechanism to focus on data correlated with shear wave velocity, which can enable the prediction results of the method proposed superior to those of conventional methods. Additionally, the prediction results of this method are compared with the prediction results of the two-dimensional convolutional neural network (2DCNN) and bidirectional gated recurrent unit (BiGRU). It is verified that the network proposed can effectively predict the shear wave velocity, with minimal error between predicted and true values.
Utilizing Date Palm Leaf Biochar for Simultaneous Adsorption of Pb(II) and Iodine from Aqueous Solutions
Authors: Mahmoud Essam R. I. , Aly Hesham M. , Hassan Noura A. , Aljabri Abdulrahman , Khan Asim Laeeq , El-Labban Hashem F.
Published: July 2024

This study addresses the environmental and health hazards posed by Pb(II) and iodine, two significant contaminants. The objective was to explore the adsorption of these substances from aqueous solutions using biochar derived from the leaf midribs of the date palm through a slow pyrolysis process. The pyrolysis was conducted in two stages within a vacuum furnace: initially at 300 °C for 1 h followed by overnight cooling, and then at 600 °C with a similar cooling process. The resulting biochar was characterized for its microstructural features and functional groups using scanning electron microscopy (SEM) and Fourier transform infrared (FT-IR) spectroscopy. It exhibited a porous structure with large numbers of pores (20 to 50 μm in size) and functional groups including O-H, C-H, and C=C, which are integral to its adsorption capabilities. For the adsorption studies, a 100 ppm Pb(II) ion solution was treated with varying amounts of biochar (20, 40, 60, and 80 mg) for 24 h. In parallel, iodine adsorption was tested, with biochar quantities ranging from 0.1 to 0.4 g/50 mL. Both treatments were followed by filtration and analysis using atomic absorption spectroscopy to determine the remaining concentrations of Pb(II) and iodine. The study also explored the effect of varying incubation periods (up to 30 h) on iodine adsorption. The results were significant; 100% adsorption of Pb(II) was achieved with the addition of 60 mg of biochar per 10 mL of solution. In contrast, for iodine, a maximum adsorption of 39.7% was observed with 30 mg or 40 mg of biochar per 50 mL. These findings demonstrate the potential of date palm-derived biochar as an effective and sustainable material for the removal of Pb(II) and iodine from contaminated water, offering valuable insights for environmental remediation strategies.
Computational Fluid Dynamics Modeling of Multiphase Flows in a Side-Blown Furnace: Effects of Air Injection and Nozzle Submerged Depth
Authors: Long Peng , Chen Zhuo , Song Yan-Po
Published: July 2024

The side-blown smelting process is becoming popular in the modern metallurgical industry due to its large potential for dealing with complex materials. To further enhance its efficiency, it is essential to comprehensively understand the complex gas–liquid flow behavior in the smelting bath. In this study, the volume-of-fluid method is employed to establish computational fluid dynamics modeling on a 1:5 scaled model of a side-blown furnace. The simulation was validated against the experimental results. Notably, the influences of the nozzle’s submerged depth, injection velocity, and angle were systematically investigated. The results show that increasing the injection velocity from 29.44 to 58.88 m/s resulted in 52.97%, 116.67%, 500.00%, and 5.88% increases in the interface area, liquid velocity, liquid turbulent kinetic energy, and gas penetration depth, respectively. The maximum gas–liquid interface area, gas penetration depth, velocity, and turbulence of the liquid were found at an injection angle of 30°. Furthermore, increasing the submerged depth increased the interface area and the velocity of the liquid but decreased the turbulent kinetic energy of the liquid. Overall, increasing the injection velocity is considered a more effective measure to strengthen the smelting intensity.
Evolution and Spatiotemporal Response of Ecological Environment Quality to Human Activities and Climate: Case Study of Hunan Province, China
Authors: Hui Jiawei , Cheng Yongsheng
Published: July 2024

Human beings are facing increasingly serious threats to the ecological environment with industrial development and urban expansion. The changes in ecological environmental quality (EEQ) and their driving factors are attracting increased attention. As such, simple and effective ecological environmental quality monitoring processes must be developed to help protect the ecological environment. Based on the RSEI, we improved the data dimensionality reduction method using the coefficient of variation method, constructing RSEI-v using Landsat and MODIS data. Based on RSEI-v, we quantitatively monitored the characteristics of the changes in EEQ in Hunan Province, China, and the characteristics of its spatiotemporal response to changes in human activities and climate factors. The results show the following: (1) RSEI-v and RSEI perform similarly in characterizing ecological environment quality. The calculated RSEI-v is a positive indicator of EEQ, but RSEI is not. (2) The high EEQ values in Hunan are concentrated in the eastern and western mountainous areas, whereas low values are concentrated in the central plains. (3) A total of 49.40% of the area was experiencing substantial changes in EEQ, and the areas with significant decreases (accounting for 2.42% of the total area) were concentrated in the vicinity of various cities, especially the Changsha–Zhuzhou–Xiangtan urban agglomeration. The areas experiencing substantial EEQ increases (accounting for 16.97% of the total area) were concentrated in the eastern and western forests. (4) The areas experiencing substantial EEQ decreases, accounting for more than 60% of the area, were mainly affected by human activities. The areas surrounding Changsha and Hengyang experienced noteworthy decreases in EEQ. The areas where the EEQ was affected by precipitation and temperature were mainly concentrated in the eastern and western mountainous areas. This study provides a valuable reference for ecological environment quality monitoring and environmental protection.