bluuebunny/crossref_metadata_2025 huggingface dataset:
Analisis Fiqih Siyasah Terhadap Optimalisasi Fungsionalitas BPD (Badan Permusyawaratan Desa) Dalam Peningkatan Kesejahteraan Masyarakat Di Desa Sibiruang
Authors: Mustafid Mustafid
Published: May 2023

AbstractThis article discusses Siyasah Fiqh Analysis of Optimizing the Functionality of the BPD (Village Consultative Body) in Improving Community Welfare in Sibiruang Village, this type of research is a field with a qualitative approach, the primary data source is the chairman and members of the Sibiruang Village BPD, while the secondary data source is a book. , journals and documents that are considered related to this paper, data collection techniques are interviews and documentation, while the data analysis technique uses descriptive qualitative. The results of this paper, that the function of the BPD has been regulated in the Kampar Regency Regional Regulation Number 6 of 2018. In general, the Sibiruang BPD has carried out its functions well, although they still have not been carried out effectively, but for the welfare of the BPD community. Sibiruang has tried according to its function. In the analysis of Fiqh Siyasah, BPD Sibiruang has carried out its function to improve the welfare of the community and ensure order in world affairs and religion by the concept of Ahlu al-Halli wa al-Aqdi.Keywords: Fiqh Siyasah, BPD, Community WelfareAbstrakArtikel ini membahas tentang Analisis Fiqih Siyasah Terhadap Optimalisasi Fungsionalitas BPD (Badan Permusyawaratan Desa) Dalam Peningkatan Kesejahteraan Masyarakat Di Desa Sibiruang, jenis penelitian ini adalah lapangan dengan pendekatan kualitatif, sumber data primernya adalah ketua dan anggota BPD desa Sibiruang, sedangkan sumber data sekunder berupa buku, jurnal dan dokumen yang di anggap berkaitan dengan tulisan ini,teknik pengumpulan data adalah wawancara dan dokumentasi, sedangkan teknik analisis data menggunakan deskriptif kualitatif. Hasil dari tulisan ini, bahwa fungsi dari BPD sudah di atur di dalam Peraturan Daerah Kabupaten Kampar Nomor 6 tahun 2018. Secara umum BPD Sibiruang telah menjalankan fungsinya dengan baik, walaupun masih ada fungsi yang belum dijalankan oleh mereka secara efektif, tetapi untuk mensejahterakan masyarakat BPD Sibiruang telah berusaha sesuai dengan fungsinya. Dalam analisa Fiqh Siyasah BPD Sibiruang telah menjalankan fungsinya untuk mensejahterakan masyarakat, menjamin ketertiban urusan dunia dan juga agama sesuai dengan konsep Ahlu al-Halli wa al-Aqdi.Kata Kunci: Fiqh Siyasah, BPD, Kesejahteraan Masyarakat
LARANGAN MELAUT PADA HARI JUM’AT DI DESA SINGKUANG DITINJAU DARI PERSPKTIF MAQASID SYARI’AH
Authors: MA Hendra Gunawan
Published: May 2023

This paper explains the prohibition of going to sea on Fridays in Singkuang village from the perspective of maqasid sharia, because basically fishing activity is a suggestion from Allah SWT to meet the needs of human life, fulfill the nutrition of children's growth. However, in the village of Singkuang, a Village Regulation (Perdes) regarding the Prohibition of Fishing on Fridays appeared.The question here is what is the background, objectives, formulation of sanctions, and the implementation of the Village Regulation on the Prohibition of Going to Sea on Fridays, and how it is viewed from the perspective of maqasid sharia.This research is a qualitative research, where the author uses data collection methods with observations and interviews with local people regarding the prohibition of going to sea on Fridays, then the data is analyzed with the concept of maqasid sharia.The findings in this study, that the prohibition to go to sea on Fridays was motivated by the number of fishermen in Singkuang village who neglected Friday prayers due to fishing, this is according to the belief of the local community if left unchecked will be able to invite harm (disaster) to the village, then According to the local community, this village regulation was made to remind fishermen to perform Friday prayers. This prohibition from going to sea when viewed from the perspective of maqasid sharia is very relevant, namely to maintain worship.
Larangan Penggunaan Telepon Saat Mengemudi
Authors: Panggabean Lisa Alawiyah
Published: May 2023

Highway safety is a state of mind. An accident is not a lack of thought but a loss of concentration while driving. Concentrating is very important in driving to get a safe ride. Traffic is a process that occurs on the highway. One of the problems regarding the use of mobile phone communication devices (hand phones) by motorcyclists when driving. The use of mobile phone communication devices while driving is very dangerous if these activities are not stopped immediately. This activity also harms other road users, maybe the driver who uses a mobile phone is not disturbed but for other road users it is very disturbing. From these problems, the writer wants to know how the role of the traffic police in the implementation of Law No. 22 of 2009 Article 106 Paragraph (1) regarding the prohibition of using mobile phones while driving a motorized vehicle is in the city of Padangsidimpuan, as well as how the fiqh siyasah review of the role of the traffic police in Implementation of Law No. 22 of 2009 concerning the Prohibition of Using Mobile Phones While Driving a Motorized Vehicle in Padangsidimpuan City. The result of this research is that the role of the traffic police in the implementation of Law no. 22 of 2009 article 106 paragraph (1) concerning the prohibition of using mobile phones while driving in Padangsidimpuan City in general has played a good role, especially in violations of article 106. However, it is necessary to increase the enforcement of traffic violations in providing sanctions that deter perpetrators from committing violations. . As for the fiqh siyasa review of the role of the traffic police in implementing the law, the importance of the role of a leader is to oblige the public to obey and obey the rules that have been set.
Penanggulangan dan Pencegahan Narkotika
Authors: Saputra Riki
Published: May 2023

The problem in this research is the Prevention and Countermeasures Against Abuse and Illicit Trafficking of Narcotics, Psychotropics and other Addictive Substances. Kenagarian Ranah Sungai Magelang is one of the Kenagarians in Gunung Tuleh District, West Pasaman Regency which has the highest level of abuse and circulation cases. The purpose of this study was to find out how the Effectiveness of the Regional Regulation of West Pasaman Regency No. 2 of 2017 Article 12 concerning the prevention and control of illicit trafficking of narcotics or other addictive substances in West Pasaman District, Gunung Tuleh Kenagarian District, Magelang River Region and to find out how Siyasah's Fiqh reviews the effectiveness of this local regulation. The role of the community in the Magelang River Realm in accordance with Article 12 Number 2 of 2017 Regional Regulation of West Pasaman Regency is to participate in carrying out campaigns and disseminating information regarding the dangers of abuse and illicit trafficking of Narcotics, Psychotropics, and other Addictive Substances. The community in the Magelang River Realm Kenagarian is actively involved in campaigning and disseminating information about the dangers of abuse and illicit trafficking of Narcotics, Psychotropics, and other Addictive Substances, in the form of counseling. This counseling is in collaboration with the Head of Drug Research at the West Pasaman Police. However, in Kenagarian Ranah Sungai Magelang, prevention from the community is only a form of counseling without any activities aimed at avoiding the dangers of Narcotics such as community organizations, such as community empowerment. There is no forum for the community to actively participate in this drug prevention action.
Pola Kemitraan Bagi Hasil Plasma Antara PT. Sago Nauli Dengan KUD Hemat Di Kecamatan Sinunukan
Authors: Siregar Syahria , Gunawan Hendra
Published: May 2023

This article discusses the Sharia Economic Law Compilation (KHES) for the production sharing of oil palm plasma land in the village unit cooperative Sinunukan IV, Sinunukan District, Mandailing Natal District. This research is a field research with a qualitative approach, the primary data source comes from the Chairperson of the Cooperative Village Unit for Savings (KUD Hemat), the Management of KUD Hemat, and members of the plasma land owners. Then the secondary data from this research are books, journals, field documents and other sources related to this research. Data collection techniques by interviews, observation, and documentation and data analysis techniques using qualitative descriptive techniques. The results of this study explain that the implementation of profit sharing carried out by the Efficient Village Unit Cooperative (KUD Hemat) is to use a percentage system, namely 80% for community members as owners of oil palm plasma land, commonly referred to as SHP (Harvest Remaining). 20% for the PT, and cooperative management get 1.5% of the 20% given by the company, Muzara'ah and Mukhabarah in KHES are made in 1 CHAPTER namely in CHAPTER IX the first part of Article 255 regarding the pillars and regarding the conditions contained in article 256 -261. In KHES namely in CHAPTER IX the first part of Article 255 regarding pillars are: land owner, cultivator, cultivated land, and contract. In terms of pillars, it is appropriate both in terms of KHES (Compilation of Sharia Economic Law) and from Islamic law. However, in terms of the conditions it has not met, namely related to the land planted, that is, the land to be cultivated must be clearly known, so as not to cause disputes between the parties making the contract. This is what causes these conditions to be less than perfect because according to the observations it was found that the people who got the plasma land did not know the exact location. Based on KHES, in terms of profit sharing, it is in accordance with mukhabarah in the form of a percentage where it is appropriate (not gharar), namely in the form of 80% for community members as owners of oil palm plasma land, commonly referred to as SHP (Remaining Harvest) every month. 20% for the PT, and cooperative management gets 1.5% of the 20% given by the company.
Optimalisasi Pemda Palas Dalam Menanggulangi Tingkat Volume Sampah Di Kec. Barumun
Authors: Hasibuan Pardamean
Published: May 2023

This research examines the role of DLHK in the implementation of article 21 of Padang Lawas District Regulation No. 2 of 2014 concerning Garbage from the perspective of Fiqh Siyasah. This research is a field research and was compiled using an empirical normative approach, the primary data source comes from Padang Lawas District Regulation No. 2 of 2014 concerning Trash Cans and secondary data comes from books and journals related to this research. While the data collection techniques used in this study consisted of interviews, observation and documentation and data analysis techniques using qualitative descriptive techniques. The results of this study state that the role of DLHK Padang Lawas Regency in implementing article 21 of Regional Regulation of Padang Lawas Regency Number 02 of 2014 concerning Trash Cans has not been implemented effectively. Because the socialization that has been carried out has not been evenly distributed and the distribution of trash cans that are not on target. Then from a review of siyasa dusturiyah studies. The role of DLHK in implementing Article 21 of Regional Regulation Number 2 of 2014 has not been implemented properly.
Pemberdayaan Masyarakat Melalui BUMDes di desa Janji Manahan Sil Kecamatan Dolok Kabupaten Padang Lawas Utara.
Authors: Ritonga Maulidan Taufik
Published: May 2023

This research examines community empowerment through the Village Owned Enterprise program which is being developed in Janji Silangge Village, Dolok District, North Padang Lawas Regency. This type of research is field research with a Juridical Empirical approach. The primary data sources are the Village Head, Village Officials, Community. Secondary data sources are books, data and documents. Data collection techniques used Observation, Interview and Documentation methods. The data analysis technique is qualitative and descriptive. The results of this study explain that the development process in which the people of Janji Manahan Silangge Village, Dolok District, North Padang Lawas Regency took the initiative to start a process of social activities to improve their own situation and condition. on the edge of tourist attractions. Village-owned enterprise programs, namely water tourism, stalls, lubukban, the process of profit sharing from the village-owned enterprise program of 20%, The supporting factors in the development program for village-owned enterprises are appropriate and running well because Janjimanahan village Silangge is between two regencies, namely Labuhan Batu Selatan and Labuhan Batu regencies, before the dam was made into a tourist spot, this dam has been around for a long time and before this tourist spot existed, this dam was often visited by local and foreign people to visit . The inhibiting factors for the BUM Desa program in Janjimanahan Village, Dolok District, North Padang Lawas Regency, where the village community is envious in running this program and human resources are far different from those in urban areas.
ANALISIS IMAM IBNU QUDAMAH TENTANG KEPEMILIKAN BAHAN GALIAN TAMBANG KONTINUITAS
Authors: Habibi Siregar Anwar , Gunawan Hendra
Published: May 2023

This paper discusses about the concept of Imam Ibn Qudamah who has made important innovations in the ownership of mining minerals. It’s formulated in the concepts of al-ma'adin al-jariyah and al-ma'adin al-jamidah. the first part is included in the general ownership, while the second part is in the individual ownership. This research is a qualitative research (library research) that requires researchers to explore primary, secondary, and complementary sources according to research needs. The method used in the study is the exploratory-analytic-comparative method. This paper supports the opinion of Muhammad Baqir al-Sadr (2003) and Muhammad Sholahuddin (2007). According to them, if someone tries and works hard to find mining minerals, then he has the right to own it as private property. however, if the mining material has a large quantity of reserves, it is included in the category of public or common property and must be managed by the government (state).
AKTUALISASI KEBIJAKAN HUKUM BAZNAS KOTA PADANG TERHADAP PENINGKATAN EKONOMI MUSTAHIK DI KOTA PADANG
Authors: Sobhan Sobhan , Burhanuddin Burhanuddin , Kholidah Kholidah , M. Ridho M. Ridho
Published: May 2023

BAZNAS Padang City has compiled several programs to achieve its mission, including Padang Sejahtera by providing business capital assistance to small traders with the aim of improving their welfare. The plan to manage, collect, and invest zakat funds has been carried out properly and professionally by BAZNAS Padang City. Based on the initial survey, it was found that three small traders who received assistance from the Padang City Baznas did not increase their wares from before, even one of them went out of business. The purpose of this study is as an advocacy material related to the management of zakat distribution in an effort to improve the mustahik economy, namely those who are members of the Padang Sejahtera program.This study uses descriptive qualitative analysis methods and data sources to obtain information related to zakat in BAZNAS Padang City. Techniques for collecting data on observing, interviewing, and documenting activities. In order to obtain research results that can be carried out, there is a responsibility that can be carried out by triangulation. Referring to the research activities carried out, the results of the distribution of zakat from BAZNAS Padang City can have a mustahik effect, although not optimal. The zakat assistance given from the Padang City Baznas is very large, so the opportunity for advancement for mustahik is not optimal. Finding funds for the mustahik funding proposal is slow, creating a disappointed attitude towards the mustahik. There is no assistance to mustahik. The Padang City BAZNAS has less than optimal monitoring efforts for mustahik who get a loan from zakat, because there are still mustahik who have fixed assets.
Keçinin İnadı: Tunceli Belediyesi’nin Sosyal Medyada Halkla İlişkiler Uygulaması
Authors: ÖZGER Onur , YAĞMURLU Aslı
Published: May 2023

Dijital söylem alanlarının toplumsal gerçekliklerin içine yerleşmesiyle birlikte, örgütlerin halkla ilişkiler stratejileri de yeni medyayla ilişkilenmeye başlamıştır. Bu durum aynı zamanda, kamuların da örgütlerle olan etkileşim biçimlerini dönüştürmüştür. Kamular bir yandan örgütler için daha ulaşılabilir olmuş, diğer yandan kriz yaratabilme potansiyellerini arttırmıştır. Bu durumu göz önünde bulundurarak yerel yönetimlerin sosyal medya mecraları aracılığıyla gerçekleştirdiği halkla ilişkiler stratejilerine bakmak, örgüt ve kamu arasındaki ilişkinin politik kodlarını görünür kılabilmek açısından önemli veriler sunmaktadır. Bu çalışma, Dersim’deki dağ keçilerinin avlanmaması için Tunceli Belediyesi’nin yürüttüğü halkla ilişkiler stratejilerini, belediyenin ve belediye başkanının Twitter hesaplarına yansıyan ilgili söylemler üzerinden analiz etmektedir. Amaçlanan, bir kamu kurumunun sistemle hegemonik karşıtlık barındıran halkla ilişkiler pratiğinin ideolojik bağlamını açığa çıkarmak ve tartışmaktır. Bu bağlamda, Laclau ve Mouffe’un söylem kuramı ile Manuel Castells’in ağ toplumu kavramsallaştırması çalışmanın metodolojisini beslemektedir. Bu teorisyenlere yaslanmanın temel sebebi, kamuların halkla ilişkiler stratejilerinde inşa edici ya da yıkıcı aktör olarak konumlanışlarını anlama gayesidir.
Türkiye’de Mobil İletişim Çalışmalarına Dair Bir Değerlendirme: 1994-2022
Authors: DEDE ÖZDEMİR Yeliz
Published: May 2023

Bu çalışmada, mobil telefonların Türkiye’de kullanılmaya başlandığı 1994 yılından günümüze mobil iletişim alanında yapılmış yüksek lisans ve doktora tezlerinin, alandaki durumu tanımlamak ve yeni araştırmalara yol göstermek amacıyla genel bir değerlendirilmesinin yapılması amaçlanmaktadır. Bu amaç çerçevesinde Yükseköğretim Kurulu (YÖK) Ulusal Tez Merkezi veri tabanından “mobil iletişim”, “mobil medya”, “mobil telefon”, “cep telefonu”, “akıllı telefon”, “mobil habercilik”, “mobil gazetecilik”, “mobil uygulamalar” ve “kablosuz iletişim” anahtar kelimeleri kullanılarak tarama yapılmış ve 1994-2022 yılları arasında iletişim bilimleri altında yazılan 38 tez çalışması, gerçekleştirilen araştırmanın konusu, amacı, bağlamı ve yöntemi de dikkate alınarak araştırmaların yoğunlaştığı temalar altında değerlendirilmiştir. Bulgular, son yıllarda mobil iletişim alanıyla ilgili çalışmaların sayısında bir artış olduğunu göstermektedir. Araştırmacılar mobil iletişimi, genellikle mesleki dönüşüm, satın alma, pazarlama, kullanım motivasyonları, bağımlılık, mobil uygulamalar ve kullanıcı pratikleri gibi konular etrafında ele almışlardır. İncelenen çalışmalarda çoğunlukla nicel ya da karma yöntemler kullanılırken nitel araştırma yöntemlerine daha az başvurulmuştur. Buna paralel olarak yine eleştirel iletişim çalışmalarının sağladığı teorik perspektiften faydalanan az sayıda tez çalışmasına rastlanmıştır. Ayrıca; son yıllarda dünyada yapılan mobil iletişim çalışmalarındaki çeşitlilikle kıyaslandığında, Türkiye’nin hala bu araştırma çeşitliliğinin oldukça gerisinde kaldığı gözlemlenmiştir.
Video Spotlight: University Meditation Program, 2007-Present
Authors: Grace Fran
Published: May 2023

This video spotlights the diverse learning environments of the University of Redlands' pioneering meditation program in its first 16 years of academic classes and community offerings. As reported in places such as Inside Higher Ed (Redden, 2007, December 18) and books published from the UCLA Higher Education Research Institute (Astin et al., Cultivating the Spirit: How College Can Enhance Students’ Inner Lives, 2011), our contemplative classroom was one of the first of its kind at any college or university when it opened in 2007. We were inspired by the call for more holistic and “interior” learning in the Association of American Colleges and Universities’ document, College Learning for the New Global Century (2007). As described in the book, Meditation and the Classroom (Simmer-Brown & Grace, eds., 2011), the college students in our contemplative classes are exposed to inner practices that deepen their self-knowledge and cultivate disciplined habits of mind. Ultimately, through practices such as tonglen, students' capacity for compassion expands to include others and also the Earth. The Meditation Program has grown to include intergenerational classes, free community offerings such as a weekly virtual meditation, and large-scale public events across a wide spectrum of contemplative practices. Our faculty have published books and articles on the effects of contemplative education, as observed in our program. For example, an interdisciplinary team of professors from fields of religion, psychology, and biology published a study of our Compassion Course in The Journal of American College Health, demonstrating the positive effect of meditation, mindfulness, and compassion education on college students’ well-being (Ko et.al., 2018, March).. Since the Meditation Program began in 2007, we have received many inquiries and on-site visits from faculty and administrators of other institutions, seeking information about the "how" of establishing a place for inner learning. This video gives a helpful visual introduction to our practices.
Finance-induced Innovation: A New Mechanism Explaining Finance-Inequality Relationship
Authors: Zhu Xiaoyang , Kuo Ying-Min
Published: May 2023

This paper uncovers a new mechanism through which financial development affects in- come inequality. We first revisit the effect of financial development on inequality using a panel of 94 countries from 1980 to 2017. The results show that both credit and equity markets development are positively related to different measurements of inequality, and the results are robust to endogeneity tests and other specifications. We then show empirically that this positive finance-inequality relationship can be explained by finance-induced innova- tion, especially by the finance-induced high-technology innovation. We further find that this mechanism seems to be more important than other innovation-related factors in explaining the finance-inequality relationship in low- and middle-income countries.
A unique case of agenesis of corpus callosum with concomitant midline teratoma and dorsal interhemispheric cyst
Authors: Bagchi Namrata , Gupta Jyoti , Chauhan Bhanu Pratap Singh , Jamwal Rupi
Published: May 2023

Midline interhemispheric cyst with corpus callosal agenesis is a well recognized condition and has been associated with various genetic conditions. Associated extraaxial tumors are uncommon with no proven genetic association. We describe a rare case of corpus callosal agenesis with a dorsal interhemispheric cyst and an extraaxial teratoma in the basifrontal region and review its imaging features along with the etiopathogenesis of concurrence of such condition.
Survival rates for invasive cutaneous malignant melanoma in South Korea in accordance with the Eighth edition AJCC Cancer Staging Manual: A retrospective single center study
Authors: Hwa Lee Seon , Ung Ha Gi , Ji Lee Hyun , Yun Chung Ho , Huh Seung , Ha Dae-Lyong , Duck Park Kyung , Hyun Jang Yong , Ju Lee Weon , Lee Seok-Jong , Young Kim Jun
Published: May 2023

Background

Cutaneous malignant melanoma is known to have a poorer prognosis in Asian patients as compared to Caucasians. Few studies have analysed the overall survival rate (OS) and melanoma-specific survival rate (MSS) of patients with cutaneous malignant melanoma in South Korea.

Aim

This study aims to analyse the OS, MSS and prognostic factors of patients with invasive cutaneous malignant melanoma in South Korea.

Methods

The medical records of patients diagnosed with invasive cutaneous malignant melanoma from July 2006 to June 2016 at Kyungpook National University Hospital were reviewed retrospectively. The OS/MSS of these patients were calculated in accordance with the Eighth American Joint Committee on Center staging system and the prognostic factors affecting MSS were analysed.

Results

A total of 202 patients with a mean age of 61.5 years were included. The 5-year OS/MSS was 64.4%/70.7% in the patients. The 5-year OS/MSS was 94.7%/97.1% for stage I, 67.2%/76.3% for stage II, 54.4%/59.1% for stage III, and 0%/0% for stage IV. On univariate analysis, the age, sex, Breslow thickness, ulceration, microsatellites, satellites, locally recurrent or in-transit metastasis, tumour metastasis in sentinel lymph nodes and clinicopathological stage were all significantly associated with the MSS, but not with acral distribution or BRAF mutation status. However, on multivariate analysis only the Breslow thickness, ulceration and stage IV were significantly associated with the MSS.

Limitations

This study was conducted retrospectively in a relatively small number of patients at a single tertiary center in South Korea.

Conclusions

The OS/MSS of patients with invasive cutaneous malignant melanoma in South Korea was lower than those in Caucasians. In addition to the Breslow thickness and ulceration, the impact of tumour location and sentinel nodal metastasis on cutaneous malignant melanoma should be reevaluated to better understand the disease prognosis in these patients.
Computed tomography-guided stereotactic surgery in the management of brain lesions: A single-center experience
Authors: Salah Mohamed , Shalaby Ahmed
Published: May 2023

Background:

The present study presents our experience with computed tomography (CT)-guided stereotactic surgery in managing deep-seated brain lesions and provides a background in the expanding fields of morphological stereotactic neurosurgery.

Methods:

We conducted this retrospective cohort study on 80 patients managed at the Department of Neurosurgery, Zagazig University Hospitals, Zagazig, Egypt, between January 2019 to January 2021. We targeted patients with morphological stereotactic surgeries performed as the primary management modality of their treatment.

Results:

A total of 80 patients, with a mean age of 44.3 years, were included in the study. The stereotactic targets were supratentorial in 71 patients (88.75%), infratentorial in seven patients (8.75%), and both supraand infratentorial in two patients (2.5%). The lesions showed enhancements with IV contrast in 55 patients (68.75%). Stereotactic procedures were performed under local anesthesia in 64 patients and general anesthesia in 16 patients. Of the 80 stereotactic procedures, 52 were biopsies (65%). We observed a significant improvement in the postoperative Karnofsky performance score compared to the postoperative score (63.4 ± 19.8 vs. 56.7 ± 15.4, P = 0.001). The level of agreement between clinical, radiological, and final pathological diagnosis was assessed; it was complete in 47.5% of the patients. The postprocedural CT scan demonstrated intracranial hemorrhage in five patients (6.25%); four (5%) were silent with no neurological complications.

Conclusion:

This study provided evidence that the stereotactic procedure is easy to perform, accurate in targeting the lesion, and spares patients from undergoing major surgical procedures. Stereotactic applications of spontaneous intracerebral hemorrhage, deep-seated abscesses, encysted tumors, or medically refractory benign intracranial hypertension can improve the outcome even in medically high-risk patients.
Molecular Geometry and Electronic Structure of Copper Corroles
Authors: Bhowmick Rina , Roy Chowdhury Sabyasachi , Vlaisavljevich Bess
Published: May 2023

Copper corroles are known for their unique multiconfigurational electronic structures in the ground state, which arise from the transfer of electrons from the π orbitals of the corrole to the d orbital of copper. While density functional theory (DFT) provides reasonably good molecular geometries, the determination of the ground spin state and the associated energetics is heavily influenced by functional choice, particularly the percentage of Hartree-Fock exchange. Using extended multireference perturbation theory methods (XMS-CASPT2), functional choice can be eliminated. The molecular geometries and electronic structures of both the unsubstituted and meso-triphenyl copper corroles were investigated. A minimal active space was employed for structural characterization, while larger active spaces are required to examine the electronic structure. The XMS-CASPT2 investigations conclusively identify the ground electronic state as a multiconfigurational singlet (S0) with three dominant electronic configurations, in its lowest energy and characteristic saddled structure. In contrast, the planar geometry corresponds to the triplet state (T0), which is approximately 5 kcal/mol higher in energy compared to the S0 state for both the bare and substituted copper corroles. Notably, the planarity of the T0 geometry is reduced in the substituted corrole compared to the unsubstituted one. By analyzing the potential energy surface (PES) between the S0 and T0 geometries using XMS-CASPT2, the multiconfigurational electronic structure is shown to transition towards a single electron configuration as the saddling angle decreases (i.e., as one approaches the planar geometry). Despite the ability of the functionals to reproduce the minimum energy structures, only the TPSSh-D3 PES is reasonably close to the XMS-CASPT2 surface. Significant deviations along the PES are observed with other functionals.
Matrix of Orthogonalized Atomic Orbital Coefficients Representation for Radicals and Ions
Authors: Llenga Stiv , Gryn'ova Ganna
Published: May 2023

Chemical (molecular, quantum) machine learning relies on representing molecules in unique and informative ways. Here, we present matrix of orthogonalized atomic orbital coefficients (MAOC) as a quantum-inspired molecular and atomic representation containing both structural (composition and geometry) and electronic (charge and spin multiplicity) information. MAOC is based on a cost-effective localization scheme that represents localized orbitals via a predefined set of atomic orbitals. The latter can be constructed from such small atom-centered basis sets as pcseg-0 and STO-3G in conjunction with guess (non-optimized) electronic configuration of the molecule. Importantly, MAOC is suitable for representing monatomic, molecular, and periodic systems, and can distinguish compounds with identical compositions and geometries but distinct charges and spin multiplicities. Using principal component analysis, we constructed a more compact but equally powerful version of MAOC – PCX-MAOC. To test the performance of full and reduced MAOC and several other representations (CM, SOAP, SLATM, and SPAHM), we used a kernel ridge regression machine learning model to predict frontier molecular orbital energy levels and ground state single-point energies for chemically diverse neutral and charged, closed- and open-shell molecules from an extended QM7b dataset, as well as two new datasets, N-HPC-1 (N-heteropolycycles) and REDOX (nitroxyl and phenoxyl radicals, carbonyl and cyano compounds). MAOC affords accuracy that is either similar or superior to other representations for a range of chemical properties and systems.
A modular flow platform enables selective and fast SuFEx ligation of small molecules, peptides, and proteins
Authors: Bernus Miguel , Mazzarella Daniele , Stanic Jelena , Zhai Ziran , Yeste Vazquez Alejandro , Boutureira Omar , Gargano Andrea , Grossmann Tom , Noel Timothy
Published: May 2023

SuFEx click chemistry has established itself as a formidable tool to rapidly and effectively link chemical structures. Despite tremendous advancements in the field in recent years, the installment of the crucial -SO2F handle still requires the use of purposely designed, expensive, and non-atom economical reagents. However, the use of the most obvious reagent, SO2F2, has been twarthed by the difficulties associated with the manipulation and dosage of this toxic gas, as well as its apparent low reactivity with amino functionalities. Herein, we disclose a modular flow platform, which is able to generate on demand, and safely dose, gaseous SO2F2. Due to the use of flow technology, many lingering limitations of this transformation could be overcome, resulting in significantly reduced reaction times, high reactivity and exceptional reaction scope. The effectiveness of the process was demonstrated by the successful synthesis of a diverse set of fluorosulfates and sulfamoyl fluorides, including those derived from biorelevant compounds, peptides, and proteins.
Facile One-pot Reduction of Nitrostyrenes to Phenethylamines using Sodium Borohydride and Copper(II) chloride
Authors: d'Andrea Laura , Jademyr Simon , Kristensen Jesper
Published: May 2023

The preparation of phenethylamines and phenylisoproylamines of scientific relevance can be achieved with a NaBH4/CuCl2 system in 10 to 30 minutes via reduction of substituted β-nitrostyrenes. The method also reduces nitrobenzene and methyl benzoate in 92 to 97% yields, while has no effect on benzoic acid, benzaldehyde, and aromatic halides. This inexpensive and facile one-pot procedure allows the isolation of the products in good to excellent yields under mild conditions, without the need for special precautions and time-consuming purification techniques.
Participación política, educación superior y construcción de ciudadanías críticas en Colombia: entre la reflexividad y el (des) aprendizaje
Authors: Montealegre Alexander
Published: May 2023

Este capítulo promueve una serie de reflexiones sobre el carácter ambivalente de ciertas prácticas políticas y de la producción de conocimiento generado tras la incorporación masiva de las nuevas tecnologías al mundo del trabajo y de la vida cotidiana. A través de un panorama general enmarcado en la participación política, la educación superior y la alfabetización mediática e informacional (AMI) como elemento de construcción de ciudadanías críticas en Colombia, se busca comprender los riesgos implícitos para la supervivencia de la democracia contemporánea. Mediante un ejercicio de interpretación crítico y reflexivo como elemento metodológico principal, se discuten las herramientas centrales que deben orientarse hacia la apropiación y construcción de nuevas subjetividades que estén en condiciones de desaprender las tendencias hegemónicas de la sociedad contemporánea. El escrito concluye con una síntesis de los elementos más importantes de cada apartado.
La Aldea: una estrategia para acercar a los niños a la realidad nacional
Authors: Neisa Emmanuel
Published: May 2023

¿Cómo hablar a los niños de temas difíciles de tratar? Esta ha sido la pregunta clave que ha llevado a ClickArte a construir un conjunto de herramientas pedagógicas para responderla. En este escrito se explica la metodología y el fundamento teórico de las actividades y proyectos que motivan e inspiran las ideas creativas que nacen en ClickArte, y en particular, el proyecto La Aldea, una estrategia pedagógica que busca que niños y adultos entablen conversaciones acerca de las noticias del país, incluyendo temas difíciles. La construcción teórica y crítica detrás del proyecto se resume en un enfoque social, analítico y reflexivo que considera las nuevas formas de comunicación, sus impactos en el desarrollo cognitivo de los jóvenes y su forma de reestructurar las relaciones humanas. De esta manera, ClickArte espera contribuir a la construcción de diálogos sociales más comprensivos, más empáticos, más colaborativos.
Rough set theory and its applications
Authors: Pawlak Zdzisław
Published: May 2023

In this paper rudiments of the theory will be outlined, and basic concepts of the theory will be illustrated by a simple tutorial example, concerning churn modeling in telecommunications. Real life applications require more advanced extensions of the theory but we will not discuss these extensions here. Rough set theory has an overlap with many other theories dealing with imperfect knowledge, e.g., evidence theory, fuzzy sets, Bayesian inference and others. Nevertheless, the theory can be regarded as an independent, complementary, not competing, discipline in its own rights.
Western region: features of the incidence and prevalence of chronic cystitis
Authors: Saidakova N.O. , Stus V.P. , Gavva N.V. , Tverdokhlib V.V. , Nesteruk S.A. , Banadyga A.I. , Grodzinsky V.I.
Published: May 2023

The paper presents the results of a ten-year (2008–2017) analysis of morbidity, prevalence of chronic cystitis among both sexes of the adult population of the Western region in terms of regions, as well as in terms of all-Ukrainian data. The primary material was the official statistical reports of medical institutions of the Ministry of Health of Ukraine. Two five-year periods were allocated to clarify the dynamics and nature of its changes. It was found that in contrast to the increase in registered patients in Ukraine as a whole at the expense of women, in the region there is a steady decrease in both women and men with a stable preservation of third place in the overall structure. The number of newly diagnosed patients in the region increased by 5.4% in 2013–2017 (by 11.6 and 5,7% among women and men, respectively), while in Ukraine by 2.1% only among women (by 12.4%) to 2992 and 15112 in 2017, respectively. Interregional peculiarities in the region have been traced and it has been established that the situation in it is formed by Lviv, Ivano-Frankivsk and Chernivtsi regions. The nature of changes in absolute values †and intensity is similar.
Activation of persistent pathogenic microflora after ascending pyelolithotripsy and the recurrence rate of nephrolithiasis
Authors: Ukhal M.I. , Pustovoit I.P. , Semaniv O.M. , Diulher V.I. , Yerhiieva T.S.
Published: May 2023

We’ve studied the activation of persistent pathogenic microflora in 28 patients after retrograde pyelolithotripsy and the frequency of recurrence of kidney stones during the year under the conditions of traditional drug treatment in the early and late postoperative periods. We’ve studied the recurrence of kidney stones during the year under conditions of use in another group of patients (26 patients), in addition to traditional drug treatment, phytouroantiseptic (herbal extract BNO 1045). It has been confirmed that persistent pathogenic microflora is found in the structures of urinary stones, which is released after operative crushing of stones and reverses into active forms that are insensitive to the main groups of antibiotics, which long-term support a chronic inflammatory process in the kidneys, and is the cause of exacerbation of chronic pyelonephritis and relapse. It has been proven that the use of a phytouroantiseptic (herbal extract BNO 1045) in the complex treatment is the effective method for eliminating the infectious and inflammatory process in the kidneys caused by persistent pathogenic microflora, for decreasing the level of uric acid in the blood and normalization of urine’s pH, which leads to effective prevention of stone relapse.
Adenomatoid Odontogenic Tumor in Mandible
Authors: Azevedo Roberto de A , Junior Braulio C , Andrade Lucio CS , HS de Castro Carlos
Published: May 2023

The adenomatoid odontogenic tumor is a relatively infrequent lesion that mainly affects females in the second decade of life, and its predicted site is the anterior region of the mandible with the lesion usually associated with the crown of the tooth. In this study, a case of adenomatoid odontogenic tumor in the anterior region of the mandible is reported together with its clinical, radiological, and histological findings and surgical treatment.
Correlation Between Administrative Personnel Competency And Madrasah Administrative Personnel Performance
Authors: Badrudin Badrudin , Muslihah Eneng , Komala Devita , Hamat Mohd Fauzi Bin
Published: May 2023

The success of madrasas in achieving goals is strongly influenced by the madrasa climate, one of which is effective madrasa administration. To support the effective administration of madrasas, administrative staff are needed who have competence in accordance with the administrative staff standards set by the government. Therefore, the fulfillment of the qualification and competency standards for school/madrasah administrative staff must be met by school/madrasah administrators. Adequate competence of madrasah administrative staff will result in high performance of administrative staff. This study aims to describe the relationship between the Competence of Administrative Personnel and the Performance of Madrasah Administrative Personnel in Madrasah Tsanawiyah Negeri Bekasi City. This research is descriptive, using a quantitative approach to the type of correlation. Data collection techniques using a questionnaire questionnaire. Based on the results of the study, it is known that the competence of administrative staff has a significant relationship with the performance of madrasa administrative staff at Madrasah Tsanawiyah Negeri Bekasi City. Calculation of the correlation coefficient analysis shows the number 0.888, which means that there is a relationship with the "Very High" category.
The Efficacy of Social Media as an Online Learning Medium during the COVID-19 Period
Authors: Nadeak Bernadetha , Halomoan Lumbantoruan Jitu
Published: May 2023

The goal of this study was to determine the efficacy of social media as an alternative to using Online Learning Media to add new knowledge and information and assist with assignments, particularly for technical matters, at Allodia Vocational High School Bekasi City during the COVID-19 pandemic, which is currently underway. This study employs a research and development strategy, with research instruments consisting of a validation questionnaire and a product attractiveness rating questionnaire delivered in the form of a Google form. The findings revealed that students' use of social media as a learning medium was quite beneficial. This could be because practically all students have social media profiles and are therefore highly familiar with them. According to the study findings, the practicality of teaching materials uploaded on social media is very possible, according to 75% of media presentation experts, 82% of material experts, and 70% of linguists. As a result, adopting social media as a learning medium throughout the COVID-19 period is highly beneficial.
School Commitment with Collaboration from a Cultural and Personality Perspective
Authors: Sihotang Hotmaulina , Purba Leony Sanga Lamsari , Ernawati Renatha
Published: May 2023

This study aims to reveal the commitment of school organizational management in the perspective of organizational management culture and the Big Five personality through trust. This variable needs to be analyzed in order to see the impact of how much influence the school organization has in the cultural perspective of educational management with the personality of the Big Five. This research method is quantitative with a path analysis strategy. The population of all teachers and a sample of 227 teachers. Data was obtained using a questionnaire and circulated using the Google form. The results of the study (1) the relationship between organizational culture and personality and vice versa is positive and very strong, (2) the influence of organizational culture on trust is weak, positive and significant, (3) the influence of personality on trust. Trust is positive, very strong, and significant, (4) the effect of organizational culture on organizational commitment is positive, very strong and significant, (5) the effect of personality on organizational commitment is very weak and not significant, (6) the effect of trust on organizational commitment is positive, very weak, (7) the effect of organizational culture on organizational commitment through low trust, and (8) the influence of personality on organizational commitment through low trust.
Development of an Integrated Curriculum Based on the Pyramid of Learning in Improving Student Learning Activities at the Darul Ma’arif Surakarta Integrated Islamic Elementary School
Authors: Supriyanto Joko
Published: May 2023

This study aims to describe and reveal the foundation, management and impact of implementing an integrated curriculum based on the Pyramid of Learning at the Darul Ma'arif Integrated Islamic Elementary School. This research uses a qualitative approach, the type of research is descriptive using a case study model design. The data collection techniques were obtained based on the results of observations, interviews and documentation. Checking the validity of the data using triangulation. This study found the following: (1) The foundation for implementing an integrated curriculum based on the Pyramid of learning is the foundation of religion, philosophy, psychology, social and culture, and science and technology (2) Curriculum management includes planning, implementation and evaluation starting with designing , carry out and evaluate observation activities, learning activities, stimulation activities, and habituation activities. (3) The impact of applying the Pyramid-based curriculum of learning is to make students' knowledge more meaningful, students read with understanding, students are independent in everyday life, students' emotions are stable so that they are ready to accept learning well, and make students' abilities run according to completeness stages and development.
Sanksi Pidana Bagi Pelaku Perambah Hutan di Desa Gapit, Kecamatan Empang, Kabupaten Sumbawa
Authors: Rodliyah Rodliyah , Parman Lalu , Ufran Ufran
Published: May 2023

Tujuan kegiatan penyuluhan hukum ini, adalah untuk mengetahui (1) faktor-faktor yang menyebabkan masyarakat yang berada di Desa Gapit, Kecamatan Empang, Kabupaten Sumbawa banyak melakukan perambahan hutan, dan (2) Upaya-upaya  yang harus dilakukan untuk mengurangi masyarakat untuk melakukan perambahan hutan.  Metode yang digunakan dalam kegiatan penyuluhan hukum ini adalah metode ceramah dan dialog. Metode ceramah digunakan untuk menyampaikan materi penyuluhan kepada peserta penyuluhan. Sedangkan metode dialog adalah metode untuk memberikan kesempatan kepada peserta untuk menyampaikan hal-hal yang kurang lengkap dan kurang jelas tentang materi penyuluhan hukum. Hasil penyuluhan, disajikan penyampaian materi penyuluhan hukum yang terdiri atas manfaat kawasan hutan, dan sanksi pidana bagi pelaku kejahatan dibidang kehutanan serta melakukan penyuluhan dalam meningkatakan pemahaman masyarakat tentang manfaat kawasan hutan serta mengedukasi masyarakat agar tidak melakukan penebangan pohon secara tidak sah.
EFEITOS DO FOGO NA RIQUEZA DE FORMIGAS EM CERRADO STRICTO SENSU NA RESERVA ECOLÓGICA DO IBGE
Authors:   , Ferreira Pedro Eduardo , Vieira Jésica
Published: May 2023

Formicidae em termos de biodiversidade e biomassa é o grupo mais relevante no Cerrado, constituindo-se um bom modelo biológico para o estudo do fogo como manejo e conservação. Este trabalho tem como objetivo avaliar o efeito do fogo na riqueza de espécies de formigas de solo antes e depois de um incêndio não planejado. O estudo foi realizado na Reserva Ecológica do IBGE em Brasília, em uma área de Cerrado stricto senso. A coleta foi realiza utilizando-se armadilhas do tipo pitfall. Para avaliar as diferenças na riqueza entre os anos de 2011 (antes do incêndio) e 2012 (após o incêndio) nos tratamentos modal e precoce utilizou-se a Análise de Variância em que ano e os tratamentos são os fatores. Um total de 95 morfoespécies ou espécies foram coletadas nos anos de 2011 e 2012, as quais pertencem a 7 subfamílias e a 26 gêneros e nos dois estudos os gêneros mais abundantes foram Camponotus e Pheidole. Apesar da riqueza de formigas no ano de 2011 tenha sido maior não houve diferença significativa. Entretanto, nas parcelas do controle o número de espécies aumentou em 2012 enquanto nos tratamentos modal e precoce diminuíram. O estudo contribuiu para demonstrar a importância do fogo em ecossistemas que esteve naturalmente presente, pois, provavelmente pela abertura do habitat ocasionado por uma queimada acidental no grupo controle (suspenção do fogo) propiciou um aumento na riqueza das formigas de solo.