bluuebunny/crossref_metadata_2025 huggingface dataset:
Process Stability during Laser Beam Welding with Beam Oscillation and Wire Feed
Authors: Schultz Villads
Published: February 2019

Beam oscillation in laser material processing makes it possible to influence process behavior in terms of energy distribution, stability, melt pool dynamics and solidification. Within the setup presented here, the beam is oscillated transverse to the welding direction, and the filler wire is fed to the melt pool of a butt joint with an air gap. One advantage of this setup is the large gap bridging ability. Certain parameter sets lead to the so-called buttonhole welding method, which allows laser welding of smooth and nearly ripple-free seams. Observations showed a transition area between conventional keyhole and buttonhole welding in which the process is destabilized. Welds made with parameter sets from this area contain critical seam defects. Welding experiments with high-speed video recording and a simplified analytical model about the wire-beam interaction have helped to elucidate the mechanisms behind this. EN AW-6082 sheet material in 1.5 mm thickness and ML 4043 filler wire with 1.2 mm diameter were used. The investigations lead to the conclusion that partially melted wire segments result at certain parameter relations which hinder the formation of a buttonhole. If these segments are prevented, buttonhole welding occurs. In the transition area, these segments are very small and can lead to the detachment of a buttonhole, resulting in the named seam defects.
An Assessment of Thermoset Injection Molding for Thin-Walled Conformal Encapsulation of Board-Level Electronic Packages
Authors: Kulkarni Romit , Wappler Peter , Soltani Mahdi , Haybat Mehmet , Guenther Thomas , Groezinger Tobias , Zimmermann André
Published: February 2019

An ever-growing market demand for board (second) level packages (e.g., embedded systems, system-on-a-chip, etc.) poses newer challenges for its manufacturing industry in terms of competitive pricing, higher reliability, and overall dimensions. Such packages are encapsulated for various reasons including thermal management, protection from environmental conditions and dust particles, and enhancing the mechanical stability. In the due course of reducing overall sizes and material saving, an encapsulation as thin as possible imposes its own significance. Such a thin-walled conformal encapsulation serves as an added advantage by reducing the thermo-mechanical stresses occurring due to thermal-cyclic loading, compared to block-sized or thicker encapsulations. This paper assesses the encapsulation process of a board-level package by means of thermoset injection molding. Various aspects reviewed in this paper include the conception of a demonstrator, investigation of the flow simulation of the injection molding process, execution of molding trials with different encapsulation thicknesses, and characterization of the packages. The process shows a high dependence on the substrate properties, injection molding process parameters, device mounting tolerances, and device geometry tolerances. Nevertheless, the thermoset injection molding process is suitable for the encapsulation of board-level packages limiting itself only with respect to the thickness of the encapsulation material, which depends on other external aforementioned factors.
Strength–Durability Correlation of Osteosynthesis Devices Made by 3D Layer Manufacturing
Authors: Okazaki Yoshimitsu , Gotoh Emiko , Mori Jun
Published: February 2019

To develop orthopedic implants that are optimized for each patient’s needs or skeletal structure (custom-made implants), evaluations of the bending strength, bending stiffness, and durability of various types of conventional osteosynthesis devices have become important. Four-point bending tests and compression bending tests of osteosynthesis devices (bone plates, intramedullary nail rods, spinal rods, compression hip screws (CHSs), short femoral nails, and metaphyseal plates) were carried out to measure their bending stiffness, bending strength, and durability. The bending stiffness of bone plates, intramedullary nails, spinal rods, CHSs, short femoral nails, and metaphyseal plates increased with increasing bending strength. The durability limit of various types of osteosynthesis devices linearly increased with increasing bending strength. The relationship (durability limit at 106 cycles) = 0.67 × (bending strength) (N·m) (R2 = 0.85) was obtained by regression. The relationship for the highly biocompatible Ti-15Zr-4Nb-4Ta alloy was also linear. The mechanical strength and ductility of specimens that were cut from various osteosynthesis devices were excellent and their microstructures consisted of fine structures, which were considered to be related to the excellent durability. These results are expected to be useful for the development of implants suitable for the skeletal structure of patients using three-dimensional (3D) layer manufacturing technologies.
High-temperature Spin Crossover of a Solvent-Free Iron(II) Complex with the Linear Hexadentate Ligand [Fe(L2-3-2Ph)](AsF6)2 (L2-3-2Ph = bis[N-(1-Phenyl-1H-1,2,3-triazol-4-yl)methylidene-2-aminoethyl]-1,3-propanediamine)
Authors: Hagiwara Hiroaki
Published: February 2019

A novel mononuclear iron(II) complex with a linear hexadentate N6 ligand, containing two 1,2,3-triazole moieties, [Fe(L2-3-2Ph)](AsF6)2 (1), was synthesized (L2-3-2Ph = bis[N-(1-Phenyl-1H-1,2,3-triazol-4-yl)methylidene-2-aminoethyl]-1,3-propanediamine). Variable-temperature magnetic susceptibility measurements revealed a gradual one-step spin crossover (SCO) between the high-spin (HS, S = 2) and low-spin (LS, S = 0) states above room temperature (T1/2 = 468 K). The spin transition was further confirmed by differential scanning calorimetry (DSC). A single-crystal X-ray diffraction study showed that the complex was in the LS state (S = 0) at room temperature (296 K). In the crystal lattice, a three-dimensional (3D) supramolecular network was formed by intermolecular CH⋯π and π–π interactions of neighboring complex cations [Fe(L2-3-2Ph)]2+. AsF6− ions were located interstitially in the 3D network of complex cations, with no solvent-accessible voids. The crystal structure at 448 K (mixture of HS and LS species) was also successfully determined thanks to the thermal stability of the solvent-free crystal.
Fixed Point Results for Multi-Valued Contractions in b−Metric Spaces and an Application
Authors: Qawaqneh Haitham , Md Noorani Mohd Salmi , Shatanawi Wasfi , Aydi Hassen , Alsamir Habes
Published: February 2019

In this paper, by characterizing a weak contractive condition based on using C − functions and α − admissible multi-valued mapping of type S, we present some fixed point results for ( α , F ) − admissible multi-valued mappings in the setting of b − metric spaces. Some examples and an application are added in order to show the reliability of our obtained results. Our results amend, unify, and generalize some existing results in the literature. The scientific novelty of our main results is to take new contraction self-mappings in b − metric spaces for multi-valued mappings.
A Novel Bat Algorithm with Multiple Strategies Coupling for Numerical Optimization
Authors: Wang Yechuang , Wang Penghong , Zhang Jiangjiang , Cui Zhihua , Cai Xingjuan , Zhang Wensheng , Chen Jinjun
Published: February 2019

A bat algorithm (BA) is a heuristic algorithm that operates by imitating the echolocation behavior of bats to perform global optimization. The BA is widely used in various optimization problems because of its excellent performance. In the bat algorithm, the global search capability is determined by the parameter loudness and frequency. However, experiments show that each operator in the algorithm can only improve the performance of the algorithm at a certain time. In this paper, a novel bat algorithm with multiple strategies coupling (mixBA) is proposed to solve this problem. To prove the effectiveness of the algorithm, we compared it with CEC2013 benchmarks test suits. Furthermore, the Wilcoxon and Friedman tests were conducted to distinguish the differences between it and other algorithms. The results prove that the proposed algorithm is significantly superior to others on the majority of benchmark functions.
Effect of Oven-Drying on the Recovery of Valuable Compounds from Ulva rigida, Gracilaria sp. and Fucus vesiculosus
Authors: Silva Andreia F.R. , Abreu Helena , Silva Artur M.S. , Cardoso Susana M.
Published: February 2019

The effect of oven-drying at 25, 40 and 60 °C was evaluated on three macroalgae of relevance in Europe, namely Ulva rigida, Gracilaria sp. and Fucus vesiculosus, with respect to quality aspects, including their potential to be exploited as a source of valuable compounds. Notably, as compared to freeze-drying, oven-drying at 25 °C promoted the extraction of chlorophylls and carotenoids from U. rigida, as well as those of phycoerythrin and chlorophyll a from Gracilaria sp., while 40 °C favored the recovery of fucoxanthin and pheophytin a from F. vesiculosus. On the other hand, the use of oven-drying had a negative impact on the extraction of phenolic compounds from this alga, also diminishing the antioxidant activity of the resulting extracts. Instead, the impact of oven-drying of raw material on the recovery of specific polysaccharides differed among the macroalgae. While the amounts of ulvans and fucoidans obtained from macroalgae dried at higher temperatures tended to be superior, the recovery of agar was not affected with the drying temperatures applied to Gracilaria sp. The overall results showed that oven-drying might serve as a good alternative to stabilize Ulva rigida, Gracilaria sp. and Fucus vesiculosus, especially if extraction of pigments and polysaccharides is aimed, thought the appropriate temperature applied must be adapted for each macroalgae.
Pd-Based Membranes: Overview and Perspectives
Authors: Peters Thijs , Caravella Alessio
Published: February 2019

Palladium (Pd)-based membranes have received a lot of attention from both academia and industry thanks to their ability to selectively separate hydrogen from gas streams. Integration of such membranes with appropriate catalysts in membrane reactors allows for hydrogen production with CO2 capture that can be applied in smaller bioenergy or combined heat and power (CHP) plants, as well as in large-scale power plants. Pd-based membranes are, therefore, regarded as a Key Enabling Technology (KET) to facilitate the transition towards a knowledge-based, low carbon and resource-efficient economy. This Special Issue of the journal Membranes on “Pd-based Membranes: Overview and Perspectives” contains nine peer-reviewed articles. Topics include manufacturing techniques, understanding of material phenomena, module and reactor design, novel applications, and demonstration efforts and industrial exploitation.
Optimisation of Heat Treatment Process for Damping Properties of Mg-13Gd-4Y-2Zn-0.5Zr Magnesium Alloy Using Box–Behnken Design Method
Authors: Zhang Jun , Kou Ziming , Yang Yaqin , Li Baocheng , Li Xiaowen , Yi Ming , Han Zhongjian
Published: February 2019

High damping magnesium alloys have poor mechanical properties, so it is necessary to investigate the damping properties of high-strength wrought magnesium alloys to effectively reduce vibration and noise in mechanical engineering. The aim of this work is to improve the mechanical damping performance of a novel high-strength Mg-13Gd-4Y-2Zn-0.5Zr magnesium alloy by optimising the heat treatment process. The mechanical damping coefficient, considering not only damping capacity but also the yield strength, is selected as one of the evaluation indexes. The other evaluation index is the tensile strength. The solid solution and ageing treatment were optimised by Box-Behnken method, an efficient experimental design technique. Heat treatment experiments based on the optimal parameters verified that the best process is a solution at 520 °C for 10 h followed by ageing at 239 °C for 22 h. The damping coefficient reaches 0.296, which is 73.1% higher than that before heat treatment. There was a good agreement between the experimental and Box-Behnken predicted results. The microstructure, morphology and composition of the second phases after heat treatment were analysed by SEM, XRD and EDS. Due to the high content of alloying elements in Mg-13Gd-4Y-2Zn-0.5Zr alloy, there are a large number of second phases after heat treated. They mainly include layer, short rod-shaped, bulk long period stacking order (LPSO) Mg12YZn and granular Mg5Gd phases. It was found that the area fraction of the second phases has an extreme effect on the damping capacity and short rod-shaped LPSO can effectively improve the damping capacity of heat-treated Mg-13Gd-4Y-2Zn-0.5Zr alloy. The volume fraction of the second phases was analysed by ImageJ software. It was concluded that the smaller the area occupied by the second phases, the better the mobility of the dislocation, and the better the damping performance of the alloy. The statistical analysis results obtained using ImageJ software are consistent with the experimental results damping capacity.
Numerical Simulation for Elasto-Plastic Contact of Novel Ti-(SiCf/Al3Ti)-Laminated Composite with Double-Layered SiC Fiber Reinforcements
Authors: Liu Jingchuan , Zhang Mengqi , Jiang Fengchun , Zhang Lan , Wang Liquan , Yun Feihong
Published: February 2019

An innovative, high-strength metal–intermetallic-laminate (MIL) composite Ti-(SiCf/Al3Ti), reinforced by double or even several SiC fiber rows, was fabricated. A high-efficiency, semi-analytical model with a numerical equivalent inclusion method (NEIM) was employed to investigate the deformation behaviors, microscopic strengthening, and failure mechanisms of the composite during elasto-plastic sphere–plane contact. The microstructure and interface features were characterized by scanning electron microscopy (SEM) and energy dispersive spectrometer (EDS). The contact model for the Ti-(SiCf/Al3Ti) composite was validated via quasi-static compressive indentation tests with a spherical indenter. A series of in-depth parametric studies were conducted to quantify the effect of the microstructure. The results indicate that the as-fabricated laminated composite has a well-organized microstructure and a higher volume fraction of fibers. The SiC fiber rows effectively enhance the strength and toughness of the composite. The optimal diameter of the SiC fibers is 32 μm when the horizontal center distance between the adjacent fibers is 2.5 times that of the fiber diameter. The hole defects occurring above the fibers would damage the material strength most compared with those occurring in other positions. The optimal quantity of the SiC fiber rows is four when the thickness of the SiCf/Al3Ti layer is 400 μm and the fiber diameter is 8 μm.
RETRACTED: The OMICs Window into Nonalcoholic Fatty Liver Disease (NAFLD)
Authors: Carulli Lucia , Zanca Giulia , Schepis Filippo , Villa Erica
Published: February 2019

Nonalcoholic fatty liver disease (NAFLD) is a common cause of hepatic abnormalities worldwide. Nonalcoholic steatohepatitis (NASH) is part of the spectrum of NAFLD and leads to progressive liver disease, such as cirrhosis and hepatocellular carcinoma. In NASH patient, fibrosis represents the major predictor of liver-related mortality; therefore, it is important to have an early and accurate diagnosis of NASH. The current gold standard for the diagnosis of NASH is still liver biopsy. The development of biomarkers able to predict disease severity, prognosis, as well as response to therapy without the need for a biopsy is the focus of most up-to-date genomic, transcriptomic, proteomic, and metabolomic research. In the future, patients might be diagnosed and treated according to their molecular signatures. In this short review, we discuss how information from genomics, proteomics, and metabolomics contribute to the understanding of NAFLD pathogenesis.
Unravelling the Crustal Architecture of Cape Verde from the Seamount Xenolith Record
Authors: Barker Abigail K. , Hansteen Thor H. , Nilsson David
Published: February 2019

The Cape Verde oceanic plateau hosts 10 islands and 11 seamounts and provides an extensive suite of alkaline lavas and pyroclastic rocks. The volcanic rocks host a range of crustal and mantle xenoliths. These xenoliths provide a spectrum of lithologies available to interact with magma during transport through the lithospheric mantle and crust. We explore the origin and depth of formation of crustal xenoliths to develop a framework of magma-crust interaction and a model for the crustal architecture beneath the Cape Verde oceanic plateau. The host lavas are phononephelinites to phonolites and the crustal xenoliths are mostly mafic plutonic assemblages with one sedimentary xenolith. REE profiles of clinopyroxene in the host lavas are light rare-earth element (LREE) enriched whereas clinopyoxene from the plutonic xenoliths are LREE depleted. Modelling of REE melt compositions indicates the plutonic xenoliths are derived from mid-ocean ridge basalt (MORB)-type ocean crust. Thermobarometry indicates that clinopyroxene in the host lavas formed at depths of 17 to 46 km, whereas those in the xenoliths formed at 5 to 20 km. This places the depth of origin of the plutonic xenoliths in the oceanic crust. Therefore, the xenoliths trace magma-crust interaction to the MORB oceanic crust and overlying sediments located beneath the Cape Verde oceanic plateau.
Discovery of Three New Phytotoxins from the Fungus Aspergillus nidulans by Pathway Inactivation
Authors: Liao Lijuan , Zhang Xiaolei , Lou Yi , Zhou Chengzeng , Yuan Qianqian , Gao Jiangtao
Published: February 2019

Fungi are a source of novel phytotoxic compounds to be explored in the search for effective and environmentally safe herbicides. The genetic inactivation of the biosynthetic pathway of the new phytotoxin cichorine has led to the isolation of three novel phytotoxins from the fungus Aspergillus nidulans: 8-methoxycichorine (4), 8-epi-methoxycichorine (5), and N-(4’-carboxybutyl) cichorine (6). The structure of the new compounds was clearly determined by a combination of nuclear magnetic resonance (NMR) analysis and high-resolution electrospray ionization (HRESIMS). The phytotoxic bioassay was studied on leaves from Zea mays and Medicago polymorpha L. at the concentration of 5 × 10−3 M by using a moist chamber technique. Novel phytotoxins 8-methoxycichorine (4), 8-epi-methoxycichorine (5), and N-(4’-carboxybutyl) cichorine (6) exhibited a better phytotoxic effect than cichorine.
Licofelone-DPPC Interactions: Putting Membrane Lipids on the Radar of Drug Development
Authors: Pereira-Leite Catarina , Lopes-de-Campos Daniela , Fontaine Philippe , Cuccovia Iolanda M. , Nunes Cláudia , Reis Salette
Published: February 2019

(1) Background: Membrane lipids have been disregarded in drug development throughout the years. Recently, they gained attention in drug design as targets, but they are still disregarded in the latter stages. Thus, this study aims to highlight the relevance of considering membrane lipids in the preclinical phase of drug development. (2) Methods: The interactions of a drug candidate for clinical use (licofelone) with a membrane model system made of 1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC) were evaluated by combining Langmuir isotherms, Brewster angle microscopy (BAM), polarization-modulation infrared reflection-absorption spectroscopy (PM-IRRAS), and grazing-incidence X-ray diffraction (GIXD) measurements. (3) Results: Licofelone caused the expansion of the DPPC isotherm without changing the lipid phase transition profile. Moreover, licofelone induced the reduction of DPPC packing density, while increasing the local order of the DPPC acyl chains. (4) Conclusions: The licofelone-induced alterations in the structural organization of phosphatidylcholine monolayers may be related to its pharmacological actions. Thus, the combination of studying drug-membrane interactions with the pharmacological characterization that occurs in the preclinical stage may gather additional information about the mechanisms of action and toxicity of drug candidates. Ultimately, the addition of this innovative step shall improve the success rate of drug development.
Inhibition of Q235 Carbon Steel by Calcium Lignosulfonate and Sodium Molybdate in Carbonated Concrete Pore Solution
Authors: Lin Bing , Zuo Yu
Published: February 2019

The inhibition effect and mechanism of a compound calcium lignosulfonate (CLS) and sodium molybdate inhibitors for Q235 carbon steel in simulated carbonated concrete pore solution (pH 11.5) with 0.02 mol/L NaCl are studied using electrochemical and surface analysis techniques. The results show that in carbonated simulated concrete pore (SCP) solution CLS and Na2MoO4 show a synergistic inhibition effect. The compound inhibitor can be defined as mix-type inhibitor. With 400 ppm CLS plus 600 ppm Na2MoO4, the pitting potential moves positively about 200 mV, and the inhibition efficiency reaches 92.67%. After 24 h immersion, the IE% further increases up to 99.2%. The surface analysis results show that Na2MoO4 could promote stability of the passive film, and the insoluble molybdenum compounds and CaO/Ca(OH)2, together with adsorbed CLS, deposit on the steel surface, forming a complex film. The compounded film effectively inhibits corrosion of the steel.
Graphene-Like Porous ZnO/Graphene Oxide Nanosheets for High-Performance Acetone Vapor Detection
Authors: Wang Hongwu , Wang Ding , Tian Liang , Li Huijun , Wang Ping , Ou Nanquan , Wang Xianying , Yang Junhe
Published: February 2019

In order to obtain acetone sensor with excellent sensitivity, selectivity, and rapid response/recovery speed, graphene-like ZnO/graphene oxide (GO) nanosheets were synthesized using the wet-chemical method with an additional calcining treatment. The GO was utilized as both the template to form the two-dimensional (2-D) nanosheets and the sensitizer to enhance the sensing properties. Sensing performances of ZnO/GO nanocomposites were studied with acetone as a target gas. The response value could reach 94 to 100 ppm acetone vapor and the recovery time could reach 4 s. The excellent sensing properties were ascribed to the synergistic effects between ZnO nanosheets and GO, which included a unique 2-D structure, large specific surface area, suitable particle size, and abundant in-plane mesopores, which contributed to the advance of novel acetone vapor sensors and could provide some references to the synthesis of 2-D graphene-like metals oxide nanosheets.
Evaluation of Volatile Metabolites Emitted In-Vivo from Cold-Hardy Grapes during Ripening Using SPME and GC-MS: A Proof-of-Concept
Authors: Rice Somchai , Maurer Devin L. , Fennell Anne , Dharmadhikari Murlidhar , Koziel Jacek A.
Published: February 2019

In this research, we propose a novel concept for a non-destructive evaluation of volatiles emitted from ripening grapes using solid-phase microextraction (SPME). This concept is novel to both the traditional vinifera grapes and the cold-hardy cultivars. Our sample models are cold-hardy varieties in the upper Midwest for which many of the basic multiyear grape flavor and wine style data is needed. Non-destructive sampling included a use of polyvinyl fluoride (PVF) chambers temporarily enclosing and concentrating volatiles emitted by a whole cluster of grapes on a vine and a modified 2 mL glass vial for a vacuum-assisted sampling of volatiles from a single grape berry. We used SPME for either sampling in the field or headspace of crushed grapes in the lab and followed with analyses on gas chromatography-mass spectrometry (GC-MS). We have shown that it is feasible to detect volatile organic compounds (VOCs) emitted in-vivo from single grape berries (39 compounds) and whole clusters (44 compounds). Over 110 VOCs were released to headspace from crushed berries. Spatial (vineyard location) and temporal variations in VOC profiles were observed for all four cultivars. However, these changes were not consistent by growing season, by location, within cultivars, or by ripening stage when analyzed by multivariate analyses such as principal component analysis (PCA) and hierarchical cluster analyses (HCA). Research into aroma compounds present in cold-hardy cultivars is essential to the continued growth of the wine industry in cold climates and diversification of agriculture in the upper Midwestern area of the U.S.
Monte Carlo Wavefunction Approach to Singlet Fission Dynamics of Molecular Aggregates
Authors: Nakano Masayoshi , Okada Kenji , Nagami Takanori , Tonami Takayoshi , Kishi Ryohei , Kitagawa Yasutaka
Published: February 2019

We have developed a Monte Carlo wavefunction (MCWF) approach to the singlet fission (SF) dynamics of linear aggregate models composed of monomers with weak diradical character. As an example, the SF dynamics for a pentacene dimer model is investigated by considering the intermolecular electronic coupling and the vibronic coupling. By comparing with the results by the quantum master equation (QME) approach, we clarify the dependences of the MCWF results on the time step (Δt) and the number of MC trajectories (MC). The SF dynamics by the MCWF approach is found to quantitatively (within an error of 0.02% for SF rate and of 0.005% for double-triplet (TT) yield) reproduce that by the QME approach when using a sufficiently small Δt (~0.03 fs) and a sufficiently large MC (~105). The computational time (treq) in the MCWF approach also exhibits dramatic reduction with increasing the size of aggregates (N-mers) as compared to that in the QME approach, e.g., ~34 times faster at the 20-mer, and the size-dependence of treq shows significant reduction from N5.15 (QME) to N3.09 (MCWF). These results demonstrate the promising high performance of the MCWF approach to the SF dynamics in extended multiradical molecular aggregates including a large number of quantum dissipation, e.g., vibronic coupling, modes.
Antibacterial Activities of Herbal Toothpastes Combined with Essential Oils against Streptococcus mutans
Authors: Karadağlıoğlu Özgü İlkcan , Ulusoy Nuran , Başer Kemal Hüsnü Can , Hanoğlu Azmi , Şık İrem
Published: February 2019

In recent years, people have become more conscious about the side-effects of fluoride toothpastes and herbal products have drawn attention as alternatives in the struggle against caries. Studies have focused on the benefits of essential oils obtained from herbs because of their antibacterial effects. The aim of this study was to evaluate and compare the antibacterial activity of Origanum dubium and Cinnamomum cassia oils combined with herbal toothpastes against Streptococcus mutans. The antibacterial activity of the test materials was determined using the agar well diffusion method before and after the addition of essential oils. We tested the efficacy of Splat Organic and Splat Biocalcium against S. mutans (12 mm and 11 mm, respectively) doubled in combination with Origanum dubium (23 mm for both toothpastes) and tripled with Cinnamomum cassia (38 mm and 36 mm, respectively). Jack N’ Jill toothpaste, which did not initially show any antibacterial effect, exhibited the largest inhibition zones after the addition of the essential oils (38 mm for Origanum dubium and 39 mm for Cinnamomum cassia). The results of this study pointed out that herbal toothpastes exhibit statistically higher antibacterial activity against Streptococcus mutans (p < 0.05) than their initial forms after the addition of essential oils.
A Novel POSS-Based Copolymer Functionalized Graphene: An Effective Flame Retardant for Reducing the Flammability of Epoxy Resin
Authors: Li Min , Zhang Hong , Wu Wenqian , Li Meng , Xu Yiting , Chen Guorong , Dai Lizong
Published: February 2019

In this study, a novel copolymer, PbisDOPOMA-POSSMA-GMA (PDPG), containing methacryloisobutyl polyhedral oligomeric silsesquioxane (POSSMA), reactive glycidyl methacrylate (GMA), and bis-9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide methacrylate (bisDOPOMA) and derivative functionalized graphene oxide (GO) were synthesized by a one-step grafting reaction to create a hybrid flame retardant (GO-MD-MP). GO-MD-MP was characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), transmission electron microscopy (TEM), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), and thermogravimetric analysis (TGA). Flame-retardant epoxy resin (EP) composites were prepared by adding various amounts of GO-MD-MP to the thermal-curing epoxy resin of diglycidyl ether of bisphenol A (DGEBA, trade name E-51). The thermal properties of the EP composites were remarkably enhanced by adding the GO-MD-MP, and the residue char of the epoxy resin also increased greatly. With the incorporation of 4 wt % GO-MD-MP, the limiting oxygen index (LOI) value was enhanced to 31.1% and the UL-94 V-0 rating was easily achieved. In addition, the mechanical strength of the epoxy resin was also improved.
Seepage Characteristics and Its Control Mechanism of Rock Mass in High-Steep Slopes
Authors: Li Hong , Tian Hongyuan , Ma Ke
Published: February 2019

In Southwest China large-scale hydropower projects, the hydraulic conductivity and fracture aperture within the rock mass of a reservoir bank slope has dramatically undergone a time series of evolution during dam abutment excavation, reservoir impounding and fluctuation operation, and discharge atomization. Accordingly, seepage control measures by hydro-structures such as drainage or water insulation curtains should be guided by scientific foundation with a dynamic process covering life-cycle performance. In this paper, the up-to-date status of studying the evolution mechanism of seepage characteristics relating to fractured rock hydraulics from experimental samples to the engineering scale of the rock mass is reviewed for the first time. Then, the experimental findings and improved practice method on nonlinear seepage flow under intensive pressure drives are introduced. Finally, the scientific progress made in fractured rock seepage control theory and optimization of the design technology of high-steep slope engineering is outlined. The undertaken studies summarized herewith are expected to contribute to laying a foundation to guide the further development of effective geophysical means and integrated monitoring systems in hydropower station construction fields.
Citizen-Scholars: Social Media and the Changing Nature of Scholarship
Authors: Chapman Amy L. , Greenhow Christine
Published: February 2019

Research is rarely created for private use; researchers publish their work so that others can read and use it, to advance the collective understanding of a field and impact people’s lives. Yet traditional approaches to scholarship, which emphasize publication in subscription-based rather than open access journals, inhibit not only the dissemination of research but also its usefulness, particularly outside of academia. Across all fields, scholars, educators, and members of the public benefit from scholarship which is easily accessible. Open science and public, social scholarship can break down these barriers to accessibility and utility. In this age which calls for a more informed citizenry, the use of social media to share and promote discussion of research could change not only the nature of scholarly communication but also the nature of scholarship and scholars’ roles. In this conceptual article, we argue that practicing public, social scholarship and increasing the use of social media to promote scholarship are the civic responsibility of citizen-scholars, so that research becomes more widely accessible, shareable, and usable in the public sphere.
A Generic First-Order Radiative Transfer Modelling Approach for the Inversion of Soil and Vegetation Parameters from Scatterometer Observations
Authors: Quast Raphael , Albergel Clément , Calvet Jean-Christophe , Wagner Wolfgang
Published: February 2019

We present the application of a generic, semi-empirical first-order radiative transfer modelling approach for the retrieval of soil- and vegetation related parameters from coarse-resolution space-borne scatterometer measurements ( σ 0 ). It is shown that both angular- and temporal variabilities of ASCAT σ 0 measurements can be sufficiently represented by modelling the scattering characteristics of the soil-surface and the covering vegetation-layer via linear combinations of idealized distribution-functions. The temporal variations are modelled using only two dynamic variables, the vegetation optical depth ( τ ) and the nadir hemispherical reflectance (N) of the chosen soil-bidirectional reflectance distribution function ( B R D F ). The remaining spatial variabilities of the soil- and vegetation composition are accounted for via temporally constant parameters. The model was applied to series of 158 selected test-sites within France. Parameter estimates are obtained by using ASCAT σ 0 measurements together with auxiliary Leaf Area Index ( L A I ) and soil-moisture ( S M ) datasets provided by the Interactions between Soil, Biosphere, and Atmosphere (ISBA) land-surface model within the SURFEX modelling platform for a time-period from 2007–2009. The resulting parametrization was then used used to perform S M and τ retrievals both with and without the incorporation of auxiliary L A I and S M datasets for a subsequent time-period from 2010 to 2012.
Evaluation of the Effect of Urban Redevelopment on Surface Urban Heat Islands
Authors: Renard Florent , Alonso Lucille , Fitts Yasmin , Hadjiosif Adeline , Comby Jacques
Published: February 2019

Climate change is a global challenge with multiple consequences. One of its impacts is the increase in heatwave frequency and intensity. The risk is higher for populations living in urban areas, where the highest temperatures are generally identified, due to the urban heat island effect. This phenomenon has recently been taken into account by local elected officials. As a result, developers have decided to use solutions in redevelopment projects to combat high temperatures in urban areas. Consequently, the objective is to study the land-surface temperature evolution of six main urban redevelopments in Lyon, France, from 2000 to 2017. Three of them (the Confluence, Kaplan, and Museum sites) were composed of industrial areas that have undergone major transformations and are now tertiary or residential areas. Two sites have been more lightly transformed, particularly by increasing vegetation to reduce heat stress and urban flooding (Dock and Garibaldi Street). Finally, the Groupama Stadium has been built into agricultural and wooded areas. Changes in vegetation cover (NDVI), water (MNDWI), and moisture (NDMI) content, built areas (NDBI) and bare soil (NDBaI) are also monitored. The results show that the Confluence and Kaplan sites were accompanied by a decrease in surface temperature and an increase in vegetation and moisture, whereas the Groupama Stadium displayed a rise in surface temperature and a decrease in vegetation. On the other hand, the Museum, Dock, and Garibaldi sites did not exhibit clear and uniform trends, although an increase in surface temperature was shown in some statistical tests. The disparity of the results shows the necessity to include a significant amount of vegetation during redevelopment operations in order to reduce heat stress.
Integrating Temporal Evolution with Cellular Automata for Simulating Land Cover Change
Authors: Wang Cangjiao , Lei Shaogang , Elmore Andrew J. , Jia Duo , Mu Shouguo
Published: February 2019

Simultaneously considering the spatial and temporal processes is essential for land cover simulation models. A cellular automaton (CA) usually simulates the spatial conversion of land cover through post-classification comparisons between the beginning and the end of the training period. However, such an approach does not consider the temporal evolution of land cover. As a result, a CA model fails to explain the realistic land cover change. This paper proposes a temporal-dimension-extension CA (TDE-CA) by integrating the temporal evolution of land cover with a CA. In the TDE-CA, the Breaks for Additive Season and Trend (BFAST) monitor algorithm was employed in the temporal evolution simulation module (TESM) to simulate the gradual evolution of land cover, and an optimized random forest CA (optimized RF-CA) was used to simulate the spatial conversion driven by many spatial variables. Subsequently, the Ensemble Kalman Filter (EnKF) was employed to integrate the TESM with the optimized RF-CA. The TDE-CA was then tested in the land cover simulation of Shendong mining area during the period 2005–2015. The TDE-CA was compared with a Null model, with its sub-models, and with the traditional CA models, including the Logistic-CA and the MLP-CA (Multilayer Perceptron CA) models. The results show that the TDE-CA is superior to the Null model. Furthermore, the overall accuracy and the Kappa coefficient of the TDE-CA were 79.84% and 71.61%, respectively; compared with the TESM and the optimized RF-CA, the values showed 17.14% and 4.48% improvements in the overall accuracies and 0.2167 and 0.0512 improvements in the Kappa coefficients, respectively. When compared with the Logistic-CA and the MLP-CA, we measured 8.41% and 8.25% improvements in the overall accuracies and 0.0985 and 0.0964 improvements in the Kappa coefficients. These experiments indicate that the TDE-CA not only provides an effective model for the spatiotemporal dynamical simulation of land cover, but also enhances the development of the existing simulation theory.
Carrier-to-Noise-Threshold Filtering on Off-Shore Wind Lidar Measurements
Authors: Gryning Sven-Erik , Floors Rogier
Published: February 2019

Wind lidar observations are characterized by a Carrier-to-Noise-Ratio that is often used to filter the observations. The choice of the Carrier-to-Noise-Ratio threshold value for the wind lidar observations is found to have an effect on the climatological wind speed distribution in such a way that when the Carrier-to-Noise-Ratio (CNR) threshold value is increased the wind speed distribution is shifted to higher values. Based on one year of observations carried out with a wind lidar from 126 m to 626 m height at the FINO3 (Forschungsplattform in Nord- und Ostsee Nr. 3) research platform in the North Sea, the effect that the choice of the Carrier-to-Noise threshold value has on the climatology of the wind speed and direction as well as the wind power density in relation to wind energy is illustrated and discussed. In the one-year data set considered here it is found that for thresholds larger than −29 dB, the mean wind speed and wind rose measured by the wind lidar become a function of the threshold value, and for values smaller than ~ −29 dB further decrease of the Carrier-to-Noise-Ratio threshold has a minor effect on the estimated mean wind speed and wind rose. The analysis of the data set from the North Sea shows that the limit for the Carrier-to-Noise-Ratio of the observations should be −29 dB or less to obtain a threshold independent estimate of the mean wind speed and wind rose. Alternatively, all valid observations should be used for the analysis. Although this study is specific for the conditions in the North Sea, we suggest that for a representative estimation of the wind resource with wind lidars, the effect of the CNR threshold filtering on the wind distribution should be studied when the recovery rate is less than 100%.
Quality Assessment of Single-Channel EEG for Wearable Devices
Authors: Grosselin Fanny , Navarro-Sune Xavier , Vozzi Alessia , Pandremmenou Katerina , De Vico Fallani Fabrizio , Attal Yohan , Chavez Mario
Published: February 2019

The recent embedding of electroencephalographic (EEG) electrodes in wearable devices raises the problem of the quality of the data recorded in such uncontrolled environments. These recordings are often obtained with dry single-channel EEG devices, and may be contaminated by many sources of noise which can compromise the detection and characterization of the brain state studied. In this paper, we propose a classification-based approach to effectively quantify artefact contamination in EEG segments, and discriminate muscular artefacts. The performance of our method were assessed on different databases containing either artificially contaminated or real artefacts recorded with different type of sensors, including wet and dry EEG electrodes. Furthermore, the quality of unlabelled databases was evaluated. For all the studied databases, the proposed method is able to rapidly assess the quality of the EEG signals with an accuracy higher than 90%. The obtained performance suggests that our approach provide an efficient, fast and automated quality assessment of EEG signals from low-cost wearable devices typically composed of a dry single EEG channel.
An IoT-Based Solution for Intelligent Farming
Authors: Nóbrega Luís , Gonçalves Pedro , Pedreiras Paulo , Pereira José
Published: February 2019

Intelligent farming is one of the vast range of applications covered by the Internet of Things concept. Notwithstanding, such applications present specific requirements and constraints that are dependent on their purpose. A practical case on which that is particularly relevant is the SheepIT project, where an automated IoT-based system controls grazing sheep within vineyards, guaranteeing that they do not threaten cultures. Due to its rigid requirements, particularly regarding the deployment of the Wireless Sensor Network, Machine-2-Machine communications and necessary interactions with a computational platform available through the Internet, Internet Protocol-based solutions are not suitable. Consequently, a customized communication stack has been developed, that intends to meet the project requirements, from the physical to the Application Layers. Although it has been developed considering the SheepIT requirements, its use may be extended to more generic intelligent farming applications, since most of the requirements are directly related with the farming environment. This paper reviews the proposed stack and details the recent developments. Particularly, we focused on Internet of Things/Machine-2-Machine interaction, describing the design and deployment of a gateway that addresses the SheepIT service requirements. Additionally, and complementary to previously published results, we evaluate the gateway performance and show its feasibility and scalability in a real scenario.
Occluded-Object 3D Reconstruction Using Camera Array Synthetic Aperture Imaging
Authors: Pei Zhao , Li Yawen , Ma Miao , Li Jun , Leng Chengcai , Zhang Xiaoqiang , Zhang Yanning
Published: February 2019

With the three-dimensional (3D) coordinates of objects captured by a sequence of images taken in different views, object reconstruction is a technique which aims to recover the shape and appearance information of objects. Although great progress in object reconstruction has been made over the past few years, object reconstruction in occlusion situations remains a challenging problem. In this paper, we propose a novel method to reconstruct occluded objects based on synthetic aperture imaging. Unlike most existing methods, which either assume that there is no occlusion in the scene or remove the occlusion from the reconstructed result, our method uses the characteristics of synthetic aperture imaging that can effectively reduce the influence of occlusion to reconstruct the scene with occlusion. The proposed method labels occlusion pixels according to variance and reconstructs the 3D point cloud based on synthetic aperture imaging. Accuracies of the point cloud are tested by calculating the spatial difference between occlusion and non-occlusion conditions. The experiment results show that the proposed method can handle the occluded situation well and demonstrates a promising performance.
Towards Using the Instrumented Timed Up-and-Go Test for Screening of Sensory System Performance for Balance Control in Older Adults
Authors: Gerhardy Thomas , Gordt Katharina , Jansen Carl-Philipp , Schwenk Michael
Published: February 2019

Background: Decreasing performance of the sensory systems’ for balance control, including the visual, somatosensory and vestibular system, is associated with increased fall risk in older adults. A smartphone-based version of the Timed Up-and-Go (mTUG) may allow screening sensory balance impairments through mTUG subphases. The association between mTUG subphases and sensory system performance is examined. Methods: Functional mobility of forty-one community-dwelling older adults (>55 years) was measured using a validated mTUG. Duration of mTUG and its subphases ‘sit-to-walk’, ‘walking’, ‘turning’, ‘turn-to-sit’ and ‘sit-down’ were extracted. Sensory systems’ performance was quantified by validated posturography during standing (30 s) under different conditions. Visual, somatosensory and vestibular control ratios (CR) were calculated from posturography and correlated with mTUG subphases. Results: Vestibular CR correlated with mTUG total time (r = 0.54; p < 0.01), subphases ‘walking’ (r = 0.56; p < 0.01), and ‘turning’ (r = 0.43; p = 0.01). Somatosensory CR correlated with mTUG total time (r = 0.52; p = 0.01), subphases ‘walking’ (r = 0.52; p < 0.01) and ‘turning’ (r = 0.44; p < 0.01). Conclusions: Supporting the proposed approach, results indicate an association between specific mTUG subphases and sensory system performance. mTUG subphases ‘walking’ and ‘turning’ may allow screening for sensory system deterioration. This is a first step towards an objective, detailed and expeditious balance control assessment, however needing validation in a larger study.
A Highly Selective and Sensitive Fluorescent Chemosensor for Detecting Al3+ Ion in Aqueous Solution and Plant Systems
Authors: Li Chia-Lin , Lu Ping-Hsuan , Fu Shih-Feng , Wu An-Tai
Published: February 2019

The solubilized form of aluminum, Al3+, is present under acid soil conditions and toxic to both animals and plants. Detecting and quantifying Al3+ is vital for both chemistry and biology. A new Schiff-based fluorescent turn-on sensor (probe L) for the selective detection of the Al3+ ion was synthesized by coupling 2-hydroxy-1-naphthaldehyde and 2-aminoisoindoline-1,3-dione, and the structure was characterized by nuclear magnetic resonance spectra. The probe L exhibited an excellent selective and sensitive response to the Al3+ ion over other metal ions in DMSO-H2O (1:9 v/v). Fluorescence quantification revealed that probe L was promising for the detection and accumulation of Al3+. Treating rice seedlings with Al3+ at 25–200 μM inhibited their growth. Al3+ treatment produced reactive oxygen species in rice roots. Practical applications of the fluorescent probe for the quantification of Al3+ in water samples and rice seedlings are demonstrated. Detecting the Al3+ ion with the probe L is easy and a potential alternative to existing analytical methods. The method can be used for detecting the Al3+ content of aqueous solution and plant systems. The novel fluorescent probe L has good potential for monitoring Al3+ content in the environment and biological systems.
Making the Customer Orientation of Salespeople Unsustainable—The Moderating Effect of Emotional Exhaustion
Authors: Shu Lifang , Wei Haiying , Peng Leiqing
Published: February 2019

Customer orientation of salespeople usually leads to a sustainable positive effect on job performance, yet previous research has usually focused on the benefits of functional customer orientation, and less is known about its relational customer orientation’s outcomes. Based on conservation of resources theory, this research focuses on both types of customer orientation, functional and relational customer orientation, and investigates the moderating effect of emotional exhaustion on the relationship between customer orientation and adaptive selling behavior. We collected 282 valid questionnaires from frontline salespeople in China. Results showed that functional/relational customer orientation was positively correlated with salespeople’s adaptive selling behavior. Salespeople’s emotional exhaustion moderates the main effect: when emotional exhaustion is high, the relationship between functional/relational customer orientation and adaptive selling behavior is substantially weakened. This study contributes to a further understanding of the sustainable operation environment for customer orientation, and provides practical implications regarding the attainment of sustainable outcomes of customer orientation.