Strongly Peraluminous Granites across the Archean–Proterozoic Transition
Authors: Bucholz Claire E , Spencer Christopher J 
Published: June 2019

Strongly peraluminous granites (SPGs) form through the partial melting of metasedimentary rocks and therefore represent archives of the influence of assimilation of sedimentary rocks on the petrology and chemistry of igneous rocks. With the aim of understanding how variations in sedimentary rock characteristics across the Archean–Proterozoic transition might have influenced the igneous rock record, we compiled and compared whole-rock chemistry, mineral chemistry, and isotope data from Archean and Paleo- to Mesoproterozoic SPGs. This time period was chosen as the Archean–Proterozoic transition broadly coincides with the stabilization of continents, the rise of subaerial weathering, and the Great Oxidation Event (GOE), all of which left an imprint on the sedimentary rock record. Our compilation of SPGs is founded on a detailed literature review of the regional geology, geochronology, and inferred origins of the SPGs, which suggest derivation from metasedimentary source material. Although Archean and Proterozoic SPGs are similar in terms of mineralogy or major-element composition owing to their compositions as near-minimum melts in the peraluminous haplogranite system, we discuss several features of their mineral and whole-rock chemistry. First, we review a previous analysis of Archean and Proterozoic SPGs biotite and whole-rock compositions indicating that Archean SPGs, on average, are more reduced than Proterozoic SPGs. This observation suggests that Proterozoic SPGs were derived from metasedimentary sources that on average had more oxidized bulk redox states relative to their Archean counterparts, which could reflect an increase in atmospheric O2 levels and more oxidized sedimentary source rocks after the GOE. Second, based on an analysis of Al2O3/TiO2 whole-rock ratios and zircon saturation temperatures, we conclude that Archean and Proterozoic SPGs formed through partial melting of metasedimentary rocks over a similar range of melting temperatures, with both ‘high-’ and ‘low-’temperature SPGs being observed across all ages. This observation suggests that the thermo-tectonic processes resulting in the heating and melting of metasedimentary rocks (e.g. crustal thickening or underplating of mafic magmas) occurred during generation of both the Archean and Proterozoic SPGs. Third, bulk-rock CaO/Na2O, Rb/Sr, and Rb/Ba ratios indicate that Archean and Proterozoic SPGs were derived from partial melting of both clay-rich (i.e. pelites) and clay-poor (i.e. greywackes) source regions that are locality specific, but not defined by age. This observation, although based on a relatively limited dataset, indicates that the source regions of Archean and Proterozoic SPGs were similar in terms of sediment maturity (i.e. clay component). Last, existing oxygen isotope data for quartz, zircon, and whole-rocks from Proterozoic SPGs show higher values than those of Archean SPGs, suggesting that bulk sedimentary 18O/16O ratios increased across the Archean–Proterozoic boundary. The existing geochemical datasets for Archean and Proterozoic SPGs, however, are limited in size and further work on these rocks is required. Future work must include detailed field studies, petrology, geochronology, and constraints on sedimentary source ages to fully interpret the chemistry of this uniquely useful suite of granites.