bluuebunny/crossref_metadata_2025 huggingface dataset:
«WHIRLWIND» A.K. GEYM AND K.S. NOVOSELOV TO THE NOBEL PRIZE
Authors: Смолеговский А М
Published: September 2024

«Крутой маршрут» А.К. Гейма и К.С. Новосёлова к завоеванию Нобелевской премии включает события их жизни. Рассмотрены исследования ученых на родине и за границей. В центре повествования – графеновая эпопея. Подчеркнуто, что быстрый выход на мировой исследовательский уровень и пионерские работы по графену обусловлены фундаментальной подготовкой в Московском физико-техническом институте. Это предопределило уникальные результаты их исследований. Отмечена ведущая роль М.И. Кацнельсона в группе Гейма–Новоселова. Показана реакция соотечественников и иностранцев на присуждение Нобелевской премии выходцам из России.

Сonsidered «cool rout» A.K. Geim and K.S. Novoselov to winning the Nobel prize. It includes events of their life and scientific activity before and after the departure abroad. It is said about the problems of their research to their homeland and went abroad. In the centre of the narrative – graphen epic. It was stressed that a quick exit to the world level of research and pioneering work on graphene is due to the fundamental training in MIPT. A similar situation holds S.V. Morozov and M.I. Katsnelson (capital obrazovanies).It determined the unique results of their work and role in the Heim Group – Novoselov. It is shown that thе reaction countrymen and foreigners jn prizhdenie Nobelevskoy natives of Russia award.
IMAGE OF GOD OF THE THUNDER AND LIGHTNING SHHYBLJE
Authors: Гучева А В
Published: September 2024

Статья посвящена образу Щыблэ а также основным концептам культово-обрядового религиозного де́йства «Щыблэ удж» (Удж в честь Бога грома и молнии). Данный обряд, это поклонение богу грома и молнии Щыблэ, который повелевал жизнью и смертью людей и совершался независимо от пола, возраста и социального положения. Обращение к божественной силе, наделённой могуществом и обладавшее высшей эффективностью в общении с божеством, осуществлялось посредством танца, песен-молений и жертвоприношения. Через воззвание осуществлялось приобщение к божественному и на него накладывались запреты и табу связанные с введением «запретного дня», невыполнение которых являлось опасным для человека. Щыблэ не персонифицировано-зримое божество, не имеет завершённого визуально-определённого образа или символа, а олицетворение таинственной силы стихии и природы, получившим, лишь словесное описание в песнях-молениях обращенных к нему, в которых, мы встречаем не только мифологический образ его двойника Ела, но и имя Ильи-пророка.

The article is devoted to the image of Shhyblje and also to the main concepts of the cult-ritual religious action «Shhyblje Udzh» (Uj in honor of the God of Thunder and Lightning). This ceremony, this worship of the god of thunder and lightning Shhyblje, who ordered the life and death of people and was committed regardless of gender, age and social status. The appeal to the divine power, endowed with power and possessing the highest effectiveness in dealing with the deity, was realized through dance, song-praying and sacrifi ce. Through the appeal, accession to the divine was carried out, and prohibitions and taboos associated with the introduction of the «forbidden day» were imposed on him, the non-fulfi llment of which was dangerous to man. Shhyblje is not a personifi ed-visible deity, does not have a completed visual-defi nite image or symbol, but the personifi cation of the mysterious strength of nature and elements, received only a verbal description in songs-prayers addressed to him, in which we meet not only the mythological image of his counterpart Ela, but also the name of Il'ja the prophet.
TRANSFORMATION OF THE NOGAI STATE TRADITION IN A NEW HISTORICAL PARADIGM OF THE 18TH CENTURY
Authors: Кидирниязов Д С , Абдусаламов М-П Б
Published: September 2024

В статье, на основе анализа и использования разнообразных источников, рассматривается специфика административного управления ногайцев в ХVIII в. По мнению авторов, после вхождения ногайцев в состав Российской империи происходит модификация их государственно-политического развития. При этом, на последующее развитие «политической традиции» оказал тот факт, что во главе ногайского государства никогда не стояли чингизиды. Высшим сословием в ногайском обществе являлись мурзы; их происхождение от хана Едигея – создателя суверенитета мангытов-ногайцев, заложившего основы их государственности в XV в., оправдывало сословные привилегии мурз. Это, в свою очередь, давало им исключительные, наследуемые права на политическое доминирование. Из сословия мурз выдвигался на пожизненное правление глава Ногайской Орды - бий. Но, не будучи чингизидами в глазах других тогдашних правящих династий ногайские бии, безусловно, уступали ханам в уровне легитимности своей власти. Однако, как считают авторы статьи, это в то же время внутри ногайского общества усиливало традицию выборного делегирования «благородным сословием» верховных властных прав своему лидеру - и она оказалась весьма стойкой.

In article, on the basis of the analysis and use of various sources, the specifi cs of administrative management of Nogais in the 18th century are considered. According to authors, after entry of Nogais into structure of the Russian Empire there is a modification of their state and political development. At the same time, I have rendered the fact that chingizida were never at the head of the Nogai state on the subsequent development of «political tradition». The highest estate in the Nogai society were murza; their origin from the khan Edigey – the creator of the sovereignty of mangytov-Nogai which has laid the foundation of their statehood in the 15th century justified class privileges мурз. It, in turn, granted him the exclusive, inherited rights for political domination. From estate мурз the head of the Nogai Horde – biya moved forward on lifelong board. But, without being chingizida in the opinion of other ruling dynasties of that time Nogai Biya, certainly, conceded to khans in the level of legitimacy of the power. However, as authors of article consider, it at the same time in the Nogai society enhanced tradition of elective delegation by «noble estate» of the Supreme imperious rights to the leader – and she was very firm.
“Frenchmen in Cannabis”: A Folklore Motif in Ethnolinguistic Perspective
Authors: Белова О.В.
Published: September 2024

В статье рассматриваются варианты русских и белорусских исторических преданий о борьбе с воинственными противниками (литовцы, шведы, татары, турки, французы). Среди локальных вариантов данного сюжета, зафиксированных в  Смоленской области, встречается неординарное упоминание о том, что завоеватели боялись конопли, и это обеспечивало местным жителям возможность укрытия и спасения в зарослях этого растения. Анализ данного фольклорного мотива в этнолингвистическом ракурсе (стереотипный образ этнического «чужака» как возможной ипостаси демонического персонажа; представления о конопле как растении-обереге; диалектная лексика, связанная с аграрной обрядностью и магическими апотропейными ритуалами) позволяет наметить возможные пути становления мотива, его обусловленность локальной системой народных верований и подкрепленность диалектной лексикой и фразеологией (паремиологией). Основной массив фольклорных, языковых и этнографических данных, послуживших базой для исследования, содержится в архивных материалах начала XX в. и полевых записях конца XX в. В статье также представлены результаты текстологического анализа ряда книжных источников, содержащих сведения о фольклорном «тексте конопли», и показано, как в ходе заимствования информации из одного источника в другой и ее интерпретации могут создаваться мифологемы, относящиеся к символам языка культуры.

This article examines variants of Russian and Belarusian historical legends about the struggle against military opponents including Lithuanians, Swedes, Tatars, Turks, and Frenchmen. In one story recorded in the Smolensk region, there is the surprising statement that the invaders were afraid of cannabis, and that this provided residents with the opportunity to escape from them by hiding among these plants. This article analyzes this folklore motif from an ethnolinguistic perspective. It considers the stereotypical image of an ethnic “alien” as a demonic character; ideas about cannabis as a talismanic plant; and the dialect associated with agrarian rituals and magical apotropaic rituals. This suggests possible ways the motif originated, as well as how it was conditioned by the local system of folk beliefs and reinforced by dialect and phraseology (paremiology). The main body of folklore, linguistic and ethnographic data which served as the basis for the study consists of archival materials from the early twentieth century and field records of the late twentieth century. The article also presents textual analysis of several literary sources that contain information about the folkloric “cannabis text,” and shows how, during the process of borrowing and interpretation, mythologems related to a culture’s linguistic symbols may be generated.
The Territorial Transformation of Tampuk Pinang Pura Housing Complex in Pangkalpinang, Indonesia
Authors: Putra Hadi Jaya , Pratiwi Wiwik D. , Syafrina Andina
Published: September 2024

Situated on Dealova Hill in Pangkalpinang City, the Tampuk Pinang Pura (TPP) territory has faced longstanding challenges associated with juvenile delinquency, encompassing issues such as drug abuse, illegal street racing, promiscuity, and alcohol consumption. Responding to these issues, the Pangkalpinang City Government initiated the construction of Dealova Park in early 2020, envisioning a Green Open Space (GOS) to counteract negative stigmas and foster a positive environment. Through a deductive-rationalistic qualitative study, this research explores the transformation of TPP territory, emphasizing the pivotal role of the governing authority in this process. The research illuminates that successful development necessitates meticulous consideration and the effective utilization of crucial public infrastructure elements such as electricity, water, drainage, and public circulation. The introduction of Taman Dealova signifies not only a physical transformation but also a paradigm shift in governance practices, highlighting the influential role of the city government in territorial changes. Beyond physical alterations, the study reveals the dynamic interplay between spatial development and governance, providing nuanced insights into urban spatial planning complexities and the transformative impact of governing bodies on spatial landscapes.
Pyrolytic Carbon: An Inexpensive, Robust, and Versatile Electrode for Synthetic Organic Electrochemistry
Authors: Ewing Tamara , Kurig Nils , Yamaki Yoshio , Sun Jiawei , Knowles Timothy , Gollapudi Asha , Kawamata Yu , Baran Phil
Published: September 2024

Synthetic organic electrochemistry is recognized as one of the most sustainable forms of redox chemistry that can enable a wide variety of useful transformations. In this study, readily prepared pyrolytic carbon electrodes are explored in several powerful rAP transformations as well as C–C and C–N bond forming reactions. Pyrolytic carbon provides an alternative to classic amorphous carbon-based materials that are either expensive or ill-suited to large-scale flow reactions.
In Situ pH-Controlled Electrochemical Sensors for Glucose and pH Detection in Saliva
Authors: Adib MD Ridwan , Barrett Colm , O'Sullivan Shane , Flynn Anna , McFadden Marie , Kennedy Emer , O'Riordan Alan
Published: September 2024

Electrochemical biosensors have been extensively researched and employed across diverse fields from environmental monitoring to clinical diagnostics. The determination of biomarkers such as glucose and pH, which are crucial for the health and well-being of animals, has led to a widespread use of these specific biosensors. Herein, we introduced a highly sensitive and stable electrochemical non-invasive detection of glucose and pH biosensors in artificial and real saliva utilizing an effective in-situ pH control method by interdigitated microelectrodes. Utilizing the on-chip platinum reference and gold counter electrodes, glucose oxidase (GOx) was immobilized onto a platinum black modified, gold interdigitated electrode through an electrodeposition process, which involved a mixture of o-phenylenediamine (o-PD) and β-cyclodextrin (β-CD). The fabricated electrodes were then examined using various techniques including optical microscopy, electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), and atomic force microscopy (AFM). An electrochemical in-situ pH control technique was utilized for accurate detection of glucose in artificial and real saliva. This method provides an opportunity for localized pH adjustment at the detection point, eliminating the requirement for extra reagents. To assist with experimental design concerning both electroanalysis and in-situ pH control of the solution, COMSOL simulations were conducted on interdigitated electrodes. Glucose and pH detection were performed in a multiplexed fashion utilizing GOx modified and gold interdigitated array electrodes, respectively. The enzymatic based glucose sensor showed an exceptional sensitivity of -0.46 nA.mM-1 in artificial saliva at a wide range of concentrations from 0.02 mM to 7 mM, with a LOD of 0.3 µM. Simultaneously, a sensitivity of -0.20 nA.pH⁻¹ was recorded for the pH sensor within the pH range of 5 to 8. The multiplexed sensors were utilized to noninvasively detect glucose and pH levels in real saliva, effectively demonstrating their successful application. This capability is particularly significant for meeting the frequent and continuous monitoring requirements of biomarkers (glucose, pH) associated with Bovine respiratory disease (BRD) and diarrhoetic calves.
Controlled Growth of Phase-Pure α-Fe2O3 Nanoparticles on g-C3N4 for the Construction of High-Performance Direct Z-Scheme Heterojunction Photocatalysts
Authors: Galán-González Alejandro , Galindo-Callén Juan G. , Fernández Isaías , Zaluzec Nestor J. , Cambré Sofie , Arenal Raúl , Benito Ana M. , Maser Wolfgang K.
Published: September 2024

This work presents an innovative two-step approach for constructing efficient direct Z-scheme heterojunction photocatalysts, involving the direct growth of hematite (α-Fe2O3) nanoparticles on graphitic carbon nitride (g-C3N4). The key to this strategy lies in an initial ultrasound-assisted impregnation step that induces the cleavage of g-C3N4 sheets in the presence of FeCl3 precursors while simultaneously promoting the effective anchoring of Fe-N and C-O/C-N species. Interestingly, conversion into hematite nanoparticles is easily achieved in a subsequent short and mild microwave-treatment step, eliminating the need for conventional high-temperature processes. The hematite phase-purity of the nanoparticles, critically controlled by the initial FeCl3 precursor concentration, directly impacts the photocatalytic activity of the g-C3N4@Fe nanohybrid heterojunction. A two-fold enhancement in the photocatalytic degradation of methylene blue compared to α-Fe2O3 and g-C3N4 is achieved for nanohybrids with highest hematite phase-purity. This significant improvement is attributed to the successful formation of a direct Z-scheme g-C3N4/α-Fe2O3 heterojunction photocatalyst as confirmed by electron spin resonance (ESR) analysis. Our two-step approach offers a facile, efficient and scalable route for the development of highly active heterojunction photocatalyst, of promise for the sustainable degradation of contaminants in environmental remediation technologies.
Eu4Pd4Ge3 with the Nd4Rh4Ge3 Structure type: A Class of Transition metal Zintl phase with metal–metal bonding following the 18-n rule?
Authors: Ponou Simeon , Mudring Anja-Verena
Published: September 2024

The ternary phase Eu4Pd4Ge3 was obtained from the reaction of element mixtures at high temperature, using small silver additive and, its crystal structure was refined from single crystal diffraction data. It adopts the predicted Nd4Rh4Ge3 type structure (monoclinic space group C2/c, No 15) with unit cell parameters a = 21.474(7) Å; b = 5.869(2) Å, (β = 110.15(1)°), c = 8.100(3) Å and, V= 958.5(4) Å3 (Z = 4). This structure type is characterized by remarkable noble metal pairs that strongly interact with the surrounding tetrel elements (Si or Ge), and has been reported so far with the noble metals Rh or Pd only, in combination with either rare-earth or calcium as electropositive ‘active’ metals, respectively. Thus, the crystal structure of ternary phase Eu4Pd4Ge3 may be best viewed as a 1:1 intergrowth of fragments cut from the La3Ni2Ga2 type of the hypothetical “Eu3Pd2Ge2” and the YPd2Si type of the EuPd2Ge parent structures. All previously reported Pd (d10) based compounds are obtained with divalent Ca, while Rh (d9) based phases are with trivalent rare-earth. At first glance, the Nd4Rh4Ge3 type structures form a unique class of electron precise ‘transition metal Zintl phases’ featuring metal–metal bonding according to the 18-n rule. Therefore, Pd phase with divalent Europium could be anticipated to comply with the 18-n rule as well with formally cationic Pd+ (d9), according to the formulation (Eu2+)4{(Pd2)2+}2(Ge4–)3 in close analogy with the prototype with neutral Rh pairs and trivalent rare-earth (Nd3+)4{(Rh2)0}2(Ge4–)3.
Quasi-liquid grain boundary conductivity in solid electrolyte candidate lithium imide
Authors: Lowen Jeremy , Insinna Teresa , Beatriceveena Tharigopala , Stockham Mark , Dong Bo , Day Sarah , Grey Clare , Kendrick Emma , Slater Peter , Anderson Paul , Makepeace Joshua
Published: September 2024

All-solid-state batteries utilising a Li-metal anode have long promised to be the next-generation of high-performance energy storage device, with a step-change in energy density, cycling stability and cell safety touted as potential advantages compared to conventional Li-ion battery cells. A key to enabling this technology is the development of solid-state electrolytes with the elusive combination of high ionic conductivity, wide electrochemical stability and the ability to form a conductive and stable interface with Li metal. Presently, oxide and sulfide-based materials, particularly garnet and argyrodite-type structures, have proved most promising for this application. However, these still suffer from a number of challenges, including resistive lithium metal interfaces, poor lithium dendrite suppression (at high current density) and low voltage stability. Here we report the first application of lithium imide, an antifluorite-structured material, as a solid electrolyte in a Li-metal battery. Low-temperature synthesis of lithium imide produces promising Li-ion conductivity, reaching > 1 mS cm-1 at 30 ˚C using a modest post-synthetic mechanochemical treatment, as well as displaying at least 5 V stability vs Li+/Li. In situ electrochemical operation of lithium imide with Li-metal electrodes reveals a 1000-fold increase in its measured ionic conductivity, whilst appearing to remain an electronic insulator. It is postulated that stoichiometry variation at the grain boundary leads to a highly disordered quasi-liquid state, facilitating this conductivity improvement. Furthermore, the material is shown to possess impressive stability under high current density conditions (70 mA cm-2) as well as the ability to operate in Li-metal battery cells. These results not only highlight the promising performance of lithium imide, but also its potential to be the basis for a new family of antifluorite based solid electrolytes.
Hydrate-based Carbon Capture via Pressure Swing in a Packed Bed of Ice
Authors: Eder Elias , Kadinger Miriam , Hiller Sandro , Arzbacher Stefan
Published: September 2024

The formation of mixed gas hydrates for pre- or post-combustion capture of carbon dioxide is considered a promising alternative to conventional carbon capture technologies. Yet, to keep up with conventional technologies or even reduce the cost of capture associated with them, a hydrate-based technology must have (1) a short induction time, (2) fast formation kinetics, and (3) moderate process conditions. To date, these requirements can only be met by adding promoters to the system, which comes at its own cost and disadvantages. Here, we show that the requirements can also be met without promoters by forming mixed gas hydrates in a packed bed of ice stabilized by fumed silica. While the high specific surface area of the packed bed warrants short induction times and fast kinetics, low temperatures ensure both moderate formation pressures and a high CO2 selectivity. The favorable properties can be maintained and even improved upon over many capture/regeneration cycles when operated at temperatures lower than 253 K, as this ensures a continuous formation of pores in the ice. We demonstrate the advantages of this route for carbon capture on a bench scale through batch, semi-batch, and continuous experiments. In semi-batch operation at 233 K and 40 bar, the mole fraction of CO2 in a synthetic flue gas is reduced from 15 mol% to 2.5 mol%. At the same thermodynamic conditions, a split fraction of 70% and a specific energy consumption below 3.0 GJ/tCO2 are achieved in continuous operation. The inherent advantages and simplicity of this process, a specific energy consumption comparable with the state of the art even though entirely based on the bench-scale experiment, as well as environmental harmlessness, emphasize the potential of this hydrate-based process to meet the demands of the industry at a minimal cost of capture.
An overview on drug delivery system using nanosponges
Authors: Alfiya Sudheer F. , Abhishek B. Vijayan , Jerlin Bosco J. S. , Prashobh G. R. , Arya B. S. , Daniel Xavier Prasad
Published: September 2024

Advancements in nanotechnology have ushered in nanosponges, biodegradable polyester structures with nanometersized cavities, designed for targeted drug delivery. Initially developed for topical applications, these nanosponges have evolved to be administered orally and intravenously. They exhibit a porous structure for controlled drug release, addressing issues like toxicity and poor bioavailability. Capable of carrying both hydrophilic and lipophilic drugs, nanosponges serve as versatile carriers for substances like enzymes, proteins, vaccines, and antibodies. Their characteristics include size and polarity control, crystalline forms, non-toxicity, stability in various conditions, suspension and regeneration capabilities, and a 3D structure for targeted capture and release. The composition involves a polymer, a cross-linking agent, and specific drug criteria. Advantages encompass targeted delivery, flavor masking, reduced side effects, water solubility, adjustable particle size, and easy commercial production. Disadvantages include limited encapsulation for larger molecules. The mechanism involves an open structure allowing prolonged release. Various types based on cyclodextrin offer unique properties. Factors affecting nanosponges include polymer nature, drug characteristics, complexation temperature, and degree of substitution. Preparation methods include solvent, ultrasound-assisted, melt, bubble electrospinning, and emulsion solvent diffusion methods. Comprehensive characterization includes drug entrapment efficiency, saturation state interaction, in vitro release studies, porosity measurement, and spectroscopic techniques. Applications span solubility enhancement, sustained delivery, oral and topical systems, protein delivery, protection from degradation, pollutant removal from water, cancer treatment, antiviral applications, enzyme immobilization, and modulation of drug release.
EFFECT OF CAPITAL MARKET ON THE ECONOMIC DEVELOPMENT OF EMERGING ECONOMIES; THE NIGERIA EXPERIENCE
Authors: Njoku Charles Odinakachi , Ugwu Kelechi Enyinna , Nwaimo Chilaka Emmanuel , Kekeocha Mary Ezinne , Nwoko Nnenna Mercy , Onyechere Patricia Onyinyechi , Chukwu Oluchi Ebere , Obieche Nkechi Precious
Published: September 2024

Purpose: This study examined the effect of Nigeria's capital market on the economic development the country. The aim of this study is to determine how much the capital market has contributed to Nigeria's Human Development and Unemployment Reduction in the country. The specific objectives are to determine the effect of: Market Capitalization, All Shares Index, Volume of market Transactions, Value of market Transactions affect both Unemployment rate and Human Development Index.
 
Methodology: The secondary data for this study came from the World Bank report for the period 1991 to 2022 and the CBN statistical bulletin. The Augmented Dickey-Fuller Unit Root test was conducted to check for the stationarity of the data set, the Johansen co-integration test was used to determine if the relationship in the models exists in either the short run or long run, and the Granger Causality was also conducted. The dependent variables were the Unemployment Rate and the Human Development Index, whereas the independent variables were Market Capitalization, All Shares Index, Transaction Volume, and Transaction Value.
 
Findings and Conclusion: Market capitalization and the All-Shares Index are significantly correlated with the Human Development Index, although there is no correlation between the Human Development Index and Transaction Volume or Value, according to a review of the regression data. In the second model, the correlations between market capitalization, the All Shares Index, the quantity and value of transactions, and the unemployment rate are not statistically significant. The study's conclusions indicate that while the capital market has a small effect on unemployment, it has a large impact on the Human Development Index. Therefore, in order to eliminate fraud and other unethical actions that breach investor trust, we implore the regulatory authorities to take regulatory measures that tend to improve and maintain the market's Market Capitalization and All Share Index.
 
Originality: This study contributes to the existing literature by examining how capital market affects economic development in Nigeria. This research has also successfully developed a model that could be used to predict the effect of Capital Market on both Human Development Index and Unemployment Reduction in Nigeria.
PENGGUNAAN MEDIA TEKS CERITA BERBAHASA ARAB DALAM MENINGKATKAN MAHARAH KALAM PADA SISWA KELAS VIII MADRASAH TSANAWIYAH SABRUN JAMIL
Authors: Mooduto Dzulkifli M , Kau Nabilah Rifqiyah
Published: September 2024

The research aims to improve Maharatul Kalam using Arabic story text media for Class VIII Madrasah Tsanawiyah Sabrun Jamil students using the classroom action research (PTK) method. The term PTK in English is called Classroom Action Research (PTK), which is a research activity carried out in class. This research was carried out according to PTK steps starting from the planning, implementation, observation, and reflection stages. This research shows an increase in student Maharatul Kalam using Arabic story text media in class VIII Madrasah Tsanawiyah Sabrun Jamil. The improvement can be seen from the pre-test, cycle 1, and cycle 2 results. Completeness in the pre-test was 26.67% or 4 students and incomplete was 73.33% or 11 students. So it continues with the actions of cycle 1. After the compiler uses the text, the students' Maharatul Kalam experience increases. Completeness in cycle 1 rose to 53.33% or 8 students and incomplete 46.67% or 7 students. Meanwhile, in cycle 2, students experienced an increase in Maharatul Kalam. Completion in cycle 2 rose to 86.67% or 13 students and incomplete 13.33% or 2 students. Therefore, this research was stopped until cycle 2 because the completion target reached 86.67. This research shows that Arabic texts can improve the Maharatul kalam of class VIII Madrasah Tsanawiyah Sabrun Jamil students.
PARENTING MANAGEMENT TO PREVENT TOXIC PARENTS
Authors: El-Faradis Fayruzah , Amuzaqiah Anik
Published: September 2024

Abstract this research described the implementation of parenting  that has big role in children improvement. The wrong parenting style could made toxic parenting. Toxic parenting will influence children improvement such as their emotional- less self-confidence, anxiety, etc that impacts the children in their early childhood or their future. This research aim to describe how was the toxic parenting and what are causes and effects of toxic parenting at Ketapang.  This research used qualitative, case studies. The sample used simple random sampling and used interview, observation. Data analyzed by triangulation. The result shows that many parents hope the best for their children but delivered in wrong way, in this case they compared their children to others, also disrespect their children and and less of reward from parents of children as their abilities and achievement. So the effect of toxic parents make the children have not enough self-esteem, less confidence, inferior to reach their self-objectives.
DFT Analysis of Salicylideneaniline Derivatives as Corrosion Inhibitors for Mild Steel
Authors: Mert Mehmet Erman , Doğru Mert Başak
Published: September 2024

Schiff bases are important in corrosion inhibition due to their ability to form stable complexes with metal ions and create protective layers on metal surfaces, thereby extending the lifespan of structural materials in various industrial applications. In this study the Salicylideneaniline and its derivatives were analyzed as corrosion inhibitor versus mild steel corrosion via DFT analysis. The eight molecules were chosen; salicylideneaniline, 2-(benzylideneamino)phenol, 4-(benzylideneamino)phenol, 2-phenyldiazenylphenol, 2-Phenylazo-4-methylphenol, 3-methyl-2-phenyldiazenyl phenol, 2-[(2-methylphenyl)diazenyl]phenol, 4-phenyldiazenylbenzene-1,3-diol), for this purpose. The Gaussian 03 program and the 6-311++G (d, p) basis set was used. Electronic properties such as the energy of the highest occupied molecular orbital (EHOMO), energy of the lowest unoccupied molecular orbital (ELUMO), energy gap (∆E) between LUMO and HOMO, dipole moment, and charges on the backbone atoms, ESP were determined.
Tenbilal antsetik / Mujeres olvidadas de Susi Bentzulul
Authors: Ruiz Mikel
Published: September 2024

El presente texto es una breve muestra de la propuesta temática en la obra poética Tenbilal antsetik / Mujeres olvidadas, de Susi Bentzulul, publicada por una editorial de amplio alcance. El libro, en tsotsil / español, emerge con una fuerza capaz de remover aquellas “bisagras” sostenidas por imaginarios construidos socialmente: el hermano, el padre, la familia.
EXPERIMENTAL INVESTIGATION ON THE FLEXURAL BEHAVIORS OF PIERS CAPS WITH VARIOUS CONCRETE AND REINFORCEMENT TYPES
Authors: A Al-Hussainy Hajir
Published: September 2024

This paper investigated the flexural behavior of six piers caps samples incorporating various reinforcement and concrete mix types. Four pier caps with similar steel reinforcement were cast using different mixes, including normal concrete (NC), high strength concrete (AHSC), and green concrete (GC) with 50% recycled concrete aggregate (RCA), and green concrete with a 2% volumetric ratio of recycled steel fiber (ARSF)). The remaining two piers caps were reinforced using CFRP and GFRP bars. Experimental tests were conducted to examine the behavior of piers regarding the loading at which the first cracks occur, deflection, and failure load. The results indicated that GC pier caps exhibited a decrease in failure load of 2.4% compared to a higher deflection of approximately one-fifth when compared with the NC pier cap. The findings also indicated that incorporating recycled steel fibers enhanced the failure load and decreased the deflection by 9% and 32.5%, respectively, when compared to the GC pier. In addition, AHSC pier caps exhibited failure load by nearly 36.8% than that of GC. The behavior of CFRP and GFRP was opposite when comparing steel-reinforced pier caps regarding failure load.
ABORDAGEM MULTIDISCIPLINAR EM CARDIOPATIAS CONGÊNITAS: DESAFIOS, ESTRATÉGIAS INTEGRADAS E PERSPECTIVAS FUTURAS
Authors: CRUZ FABIANA SANTOS DA , RODRIGUES LUIZ MÁRIO PARÁ , MAGALHÃES CLAUDIA CHRISTINA RIBEIRO GUIMARÃES NERI DE , SCHIAVON ISABEL CRISTINA ADÃO , LIMA LÍGIA XAVIER DE , ZUCCOLOTTO LORENZO LUCHINE , MIRANDA THIAGO CAPISTRANO , CARNEIRO DIRLEI SANDRA , SILVA ANA CLAUDIA RODRIGUES DA , DUARTE LUCAS DOS SANTOS
Published: September 2024

Introdução: As cardiopatias congênitas, destacam sua relevância como uma das principais causas de mortalidade neonatal
afetando milhões de crianças globalmente. A complexidade dessas condições é influenciada por fatores genéticos,
ambientais e exposição a drogas durante a gestação. A classificação das patologias em cianogênicas e acianogênicas é
crucial para o diagnóstico e encaminhamento clínico. A abordagem multidisciplinar é essencial para oferecer cuidados
completos, abordando não apenas as necessidades cardíacas, mas também aspectos como desenvolvimento, alimentação e
suporte emocional. Objetivo: Examinar a abordagem multidisciplinar em cardiopatias congênitas, explorando tanto os
desafios enfrentados quanto as estratégias integradas adotadas, além de investigar as perspectivas futuras nesse campo.
Metodologia: Trata-se de uma abrangente revisão integrativa da literatura, conduzida em 2024 mediante consulta às
respectivas bases de dados AcervoMais e PubMed. Resultados e Discussão: O estudo sobre abordagem multidisciplinar
em cardiopatias congênitas revela uma série de desafios e estratégias integradas. Os desafios incluem a complexidade das
condições, a importância do diagnóstico precoce, intervenção imediata em casos graves e acesso limitado aos cuidados de
saúde. Estratégias integradas abrangem desde o pré-natal com consultas regulares até a colaboração entre especialidades
médicas para tratamento preciso. Além disso, destaca-se a importância do apoio emocional, avanços tecnológicos na
avaliação cardíaca e coordenação de cuidados multidisciplinares. Considerações Finais: Desafios são apontados na
abordagem multidisciplinar das cardiopatias congênitas, como acesso e desigualdades sociais. Estratégias integradas, como
o programa LAUNCH, mostram melhorias. Tecnologias avançadas, como imagens 3D, revolucionam diagnóstico e
tratamento. Futuramente, reformular modelos de cuidado e investir em tecnologia são essenciais.
MARCADORES CARDÍACOS PRECOCES PARA DIAGNÓSTICO DE DOENÇA DE CHAGAS LATENTE
Authors: OLIVEIRA EDUARDA GABRIELLY KRYNSKI DE , OLIVEIRA MARIA EMÍLIA DANTAS , BRITO ANA CAROLINE DE CERQUEIRA , GOMES LAIS SETTE , MACHADO KEYLA LIANA BEZERRA , PALÚ ALÉXIA PRESTES DO NASCIMENTO , SILVA ADRIELY DE LIMA , MELLO PRISCILA GOMES DE , LIMA ELAYNNE JEYSSA ALVES
Published: September 2024

Introdução: A Doença de Chagas é uma doença causada pelo Trypanosoma Cruzi, um inseto mais conhecido como
‘‘barbeiro''. É um agravo na saúde pública e tem maior prevalência em países subdesenvolvidos ou em desenvolvimento e
caracterizando-se como uma enfermidade negligenciada e endêmica na América Latina. Objetivo: Analisar os marcadores
cardíacos precoces para diagnóstico de Doença de Chagas latente. Metodologia: Trata-se de uma revisão integrativa da
literatura no qual foram utilizadas as bases de dados MEDLINE e LILACS, via BVS. Resultados: Os microRNAs
(miRNAs), como miR-21, miR-146b, e miR-155, são biomarcadores precoces promissores na Doença de Chagas,
associados a processos inflamatórios e fibrose cardíaca. Eles oferecem uma visão detalhada da patogênese da doença e
podem ajudar na detecção precoce de alterações cardíacas. O BNP e NT-proBNP são particularmente eficazes na avaliação
da gravidade da cardiomiopatia chagásica, com alta sensibilidade e especificidade para a detecção de insuficiência cardíaca.
Esses biomarcadores podem melhorar a detecção prematura e o acompanhamento da doença, facilitando a intervenção
ainda na fase inicial e o monitoramento da resposta ao tratamento, e potencialmente aprimorando o manejo clínico da
Doença de Chagas. Conclusão: Os biomarcadores relatados nestes estudos apresentaram uma associação positiva com o
estado de progressão da doença e por isso, podem ser considerados promissores no estabelecimento do diagnóstico da
Doença de Chagas latente.
COMPARAÇÃO DE ESTRATÉGIAS INTERVENCIONISTAS PARA DOENÇA VALVAR MITRAL: REPARO CIRÚRGICO, SUBSTITUIÇÃO E INTERVENÇÕES
Authors: SILVA MARIVALDO DE MORAES E , COELHO LARA EMANUELY RESENDE , ELEUTÉRIO FRANCIS TÚLHIO VENTURA , WOOD LUCIANA CRISTINA PEREIRA , MORAIS FABIANA DE , SCHENK FERNANDA SANTOS , VELOSO MOISÉS DE SOUSA , AMORIM JONATHAN SOUSA , SOUSA RAFAEL BEZE , SANTOS THIAGO LÚCIO DOS
Published: September 2024

Introdução: A doença valvar mitral é uma condição prevalente que impacta significativamente a saúde cardiovascular
globalmente. Com o avanço das técnicas intervencionistas, como o reparo cirúrgico, a substituição valvar e outras
intervenções menos invasivas, surgem oportunidades para melhorar os resultados clínicos e a qualidade de vida dos
pacientes. Objetivo: Realizar uma revisão das comparações entre diferentes estratégias intervencionistas disponíveis para
o tratamento da doença valvar mitral. Metodologia: Compete a uma ampla revisão integrativa da literatura, conduzida em
2024 mediante consulta às bases de dados LILACS, MEDLINE, IBECS e WPRIM. Resultados e Discussão: O reparo
cirúrgico da válvula mitral demonstra ser seguro e eficaz, especialmente em casos de endocardite infecciosa, regurgitação
mitral isquêmica e degenerativa, com menor mortalidade a curto prazo comparado à substituição da válvula mitral. Em
comparação com intervenções percutâneas como o TEER, o reparo cirúrgico também oferece benefícios em termos de
durabilidade do resultado, embora as intervenções percutâneas sejam preferidas por pacientes devido à menor invasividade,
apesar de desafios como alta taxa de exclusão e potenciais complicações a longo prazo. A escolha entre os métodos deve
considerar a anatomia valvar específica e o perfil de risco do paciente para otimizar os desfechos clínicos. Considerações
Finais: A escolha entre reparo cirúrgico e intervenções percutâneas para a doença valvar mitral deve ser guiada pela
avaliação cuidadosa da anatomia valvar e perfil de risco do paciente, visando melhorar os desfechos clínicos e a qualidade
de vida a longo prazo. A individualização do tratamento é essencial para maximizar os benefícios terapêuticos e minimizar
as complicações associadas.
IMPACTO DA EDUCAÇÃO EM SAÚDE CARDIOVASCULAR NA ERA MODERNA
Authors: MESQUITA JOSÉ GABRIEL DE SOUZA , TOMAZ FRANCISCA NOBERTO , SILVA JAQUELINE ALESSANDRA CASTRO DA , SCANTAMBURLO GUILHERME PIMENTEL , MENDONÇA MARIANA MALTA DE , SOUSA MIRNA RIBEIRO FREITAS DE , ABREU LAÍS LIMA DE CASTRO , REGO MARIA CAROLINA DIAS , MENDONÇA MARIANA MALTA DE , SOARES LÍVIA DE PAULA
Published: September 2024

Introdução: Doenças cardiovasculares (DCV) representam um desafio global de saúde, com fatores de risco variados. A
integração da educação em saúde promove a participação ativa e influencia positivamente os comportamentos relacionados
à saúde cardiovascular. Essa abordagem também incentiva mudanças no estilo de vida e contribui para reduzir a incidência
de eventos cardiovasculares. Objetivo: Analisar o impacto da educação em saúde cardiovascular na contemporaneidade.
Metodologia: Compete a uma ampla revisão integrativa da literatura, conduzida em 2024 mediante consulta às bases de
dados LILACS e MEDLINE. Resultados e Discussão: A educação em saúde cardiovascular desempenha um papel crucial
na redução das DCV na era moderna. Estratégias educativas, como campanhas de conscientização e programas de
prevenção, têm sido eficazes na promoção de hábitos saudáveis e na redução dos fatores de risco das DCV. Iniciativas
como a Estratégia de Saúde Cardiovascular na Atenção Primária à Saúde (APS) e o modelo HEARTS nas Américas buscam
fortalecer a gestão e prevenção das DCV. Modelos de predição de risco, como o Modelo de Crenças em Saúde (MCS), têm
sido empregados com sucesso para promover mudanças comportamentais e nutricionais. Intervenções voltadas para a
modificação do estilo de vida, como a prática regular de exercícios físicos e a educação sobre os riscos do tabagismo,
desempenham um papel significativo na redução da incidência de DCV. Portanto, a educação em saúde cardiovascular
oferece oportunidades promissoras para a melhoria da saúde cardiovascular em nível global. Considerações Finais: A
educação em saúde cardiovascular é fundamental para reduzir as doenças cardiovasculares na era moderna, através de
estratégias educativas eficazes, como campanhas de conscientização e programas de prevenção, e intervenções para
modificar o estilo de vida, como exercícios físicos e educação sobre tabagismo, contribuindo significativamente para a
melhoria da saúde cardiovascular em nível global.
IMPACTO DOS EFEITOS CARDÍACOS INDUZIDOS POR SALBUTAMOL EM PACIENTES PEDIÁTRICOS: UMA REVISÃO INTEGRATIVA
Authors: GOMES ROOSEVELT ALBUQUERQUE , SOARES CAIO VICTOR DANTAS , LAGO CLEBER MENDES PEREIRA DO , NÓBREGA HAYANNE OLIVEIRA DA SILVA , SILVA JOANDA PAOLLA RAIMUNDO E , MEDEIROS MARINA ROQUE DE , SOUTO GUSTAVO PEREIRA DE , BARBOZA ISABELA DE ARAÚJO , FREIRE MARIA LARISSA PEREIRA DA COSTA , SOARES RENATA ALCANTARA
Published: September 2024

Introdução: A asma brônquica é uma doença inflamatória crônica das vias aéreas, caracterizada por episódios de dispneia,
sibilância, aperto no peito e tosse. O salbutamol, introduzido em 1968, é um agonista ß2-adrenérgico de curta duração usado
para alívio sintomático de broncoespasmos em condições asmáticas. No entanto, sua absorção sistêmica pode resultar em
efeitos hemodinâmicos adversos, como taquicardia e palpitações. Objetivo: Analisar e compilar dados da literatura
científica disponível sobre os efeitos cardíacos induzidos por salbutamol em pacientes pediátricos, com foco na
identificação dos tipos de efeitos cardíacos, sua prevalência e implicações clínicas. Metodologia: Trata-se de uma revisão
integrativa da literatura. O referido estudo envolveu pesquisa nas bases BVS-BIREME e PubMed, selecionando estudos de
metanálise e ensaios clínicos randomizados dos últimos cinco anos, que investigaram a relação entre o uso de salbutamol e
efeitos cardíacos em crianças. Resultados e Discussão: Os principais achados indicam que o salbutamol está associado a
uma incidência significativa de taquicardia e outros efeitos adversos cardiovasculares. Comparações entre levosalbutamol
e salbutamol racêmico sugerem que o levosalbutamol pode ter um perfil de segurança mais favorável, enquanto alternativas
como o l-isoproterenol mostraram menos efeitos adversos. Adicionalmente, outros estudos abordaram diferentes aspectos
dos efeitos cardíacos dos agonistas beta-2 em crianças, em especial o salbutamol, com a taquicardia sendo o efeito colateral
mais frequentemente relatado, seguida de arritmias e alterações na pressão arterial. Considerações Finais: A taquicardia é
o efeito colateral mais comum associado ao uso de salbutamol em crianças. Portanto, é essencial um monitoramento
rigoroso durante o tratamento, especialmente em doses elevadas ou prolongadas, para minimizar os riscos de efeitos
adversos graves. A busca por alternativas terapêuticas mais seguras continua sendo relevante para melhorar o manejo da
asma em pacientes pediátricos.
The Operation Mechanism of an Agile Organization in the Digital Era: A case Study from the Social Media Perspective
Authors: Tong Xiaoping
Published: September 2024

There is a need to deeply summarize the operating mechanism of organizations that fought against the COVID-19 pandemic. During the outbreak of the pandemic, a large number of non-profit organizations coordinated the donations of medical materials needed badly by frontline medical professionals. However, how did these organizations operate in the emergent situation after all? Summary of their practical mechanism needs to be deepened. Taking the Gu Dian organization that fought against the COVID-19 outbreak as a case, as the organization coordinated medical material donations, the present study is directed by the framework of an agile organization in the digital era. The research summarizes the agile management mechanism of the non-profit organization that served during the pandemic, and analyzes the effect of digital tools on the non-profit organization. The results show: 1) the operation of Gu Dian organization can be explained quite well by the framework of an agile organization in the digital era, and the case supplements important information for the framework; 2) social media affordances supported the establishment and operation of Gu Dian organization. The results summarize the agile management mechanism of organizations that coordinated the donations during the pandemic, which provide professional implications for organizations to operate fast and effectively in face of emergent disasters.
Examination of the effectiveness of ward tribunals in mediating land disputes in Tanzania: A case study of Kibaha District Council
Authors: Ruti Johnson Mwamfupe  , Cornel K inanila Mtaki  , Benedict Thomas Mapunda
Published: September 2024

Tanzania has established a separate system for dealing with land disputes, which is less formal than ordinary civil courts and more accessible to citizens with less formal education. The Village Land Act and the Land Dispute Courts Act provide the institutional framework for land dispute settlement, including the Ward Tribunal, District Land and Housing Tribunal, High Court, and Court of Appeal of Tanzania. Ward Tribunals are established by the Ward Tribunal Act in 1985 to secure peace and harmony in their areas by obtaining justice and amicable settlement of land disputes. However, some cases have been decided without considering customary principles of mediation, as seen in Cosmas Matimila v John Cosmas Matimilia and Fredrick Leonald v Ezekiel Maganga. This study aims to examine the effectiveness of Ward Tribunals in dealing with land disputes in Tanzania through the application of customary principles of mediation using Kibaha District as a case study. The research methodology was a qualitative approach, employing documentary and field research methodologies, primary and secondary sources of data, and non-probability sampling. A sample size of fifteen respondents was selected, including seven respondents from Kibaha District Ward Tribunals, five respondents from mediation practitioners and experts, and five respondents who was beneficiaries of mediation through customary principle from Kibaha District. The data analysis was content analysis, interpreting canons of statutory interpretation, including inductive reasoning and deductive reasoning. The Findings of this study shows that; l that although Ward tribunals are very important in disputes mediations through customarily principles face ineffective application in land disputes mediations in Tanzanian context. The study recommends deliberate intervention by the judiciary system to ensure enforceability of customarily principles in land disputes mediations.
Enforceability of the principle of party autonomy in the conduct of court-annexed mediation in mainland tanzania
Authors: Nyambilila Samson Ndoboka  , Cornel K inanila Mtaki  , Benedict Thomas Mapunda
Published: September 2024

The Study intends to examine the Enforceability of the Principle of Party Autonomy in the Conduct of Court-Annexed Mediation in Mainland Tanzania. Specifically, to identify reasons that hinder the enforceability of the principle of party autonomy in the conduct of court-annexed mediation in Mainland Tanzania also to examine why enforceability of the principle of party autonomy in Mainland Tanzania is confined to Judges and Magistrates. The study review literatures on the development of mediation as well as Principle of Party Autonomy. Its findings are drawn from the literature review and similarly from Doctrinal Legal Research and Qualitative Legal Research; a survey of judicial officers and interviews with selected interviewers from Dar es Salaam. The findings shows that the compliance of Principle of Party Autonomy in court-annexed mediation has been focused on effectiveness in reducing backlog of the cases in court, maintaining good relation to the parties, increasing knowledge of Principle of Party Autonomy in court-annexed mediation. The findings also identified to the factors contributing to its enforceability and factors that hinders the success of Principle of Party Autonomy in the Mainland Tanzania.