bluuebunny/crossref_metadata_2025 huggingface dataset:
Stability and Electronic Properties of Mixed Rare-Earth Tri-Metallofullerenes YxDy3-x@C80 (x = 1 or 2)
Authors: Wu Yabei , Zhou Zhonghao , Wang Zhiyong
Published: January 2024

Tri-metallofullerenes, specifically M3@C80 where M denotes rare-earth metal elements, are molecules that possess intriguing magnetic properties. Typically, only one metal element is involved in a given tri-metallofullerene molecule. However, mixed tri-metallofullerenes, denoted as M1xM23-x@C80 (x = 1 or 2, M1 and M2 denote different metal elements), have not been previously discovered. The investigation of such mixed tri-metallofullerenes is of interest due to the potential introduction of distinct properties resulting from the interaction between different metal atoms. This paper presents the preparation and theoretical analysis of mixed rare-earth tri-metallofullerenes, specifically YxDy3−x@C80 (x = 1 or 2). Through chemical oxidation of the arc-discharge produced soot, the formation of tri-metallofullerene cations, namely Y2Dy@C80+ and YDy2@C80+, has been observed. Density functional theory (DFT) calculations have revealed that the tri-metallofullerenes YxDy3−x@C80 (x = 1 or 2) exhibit a low oxidation potential, significantly lower than other fullerenes such as C60 and C70. This low oxidation potential can be attributed to the relatively high energy level of a singly occupied orbital. Additionally, the oxidized species demonstrate a large HOMO-LUMO gap similar to that of YxDy3−xN@C80, underscoring their high chemical stability. Theoretical investigations have uncovered the presence of a three-center two-electron metal–metal bond at the center of Y2DY@C80+ and YDy2@C80+. This unique multi-center bond assists in alleviating the electrostatic repulsion between the metal ions, thereby contributing to the overall stability of the cations. These mixed rare-earth tri-metallofullerenes hold promise as potential candidates for single-molecule magnets.
Super Bolus—A Remedy for a High Glycemic Index Meal in Children with Type 1 Diabetes on Insulin Pump Therapy?—A Randomized, Double-Blind, Controlled Trial
Authors: Kowalczyk-Korcz Emilia , Dymińska Magdalena , Szypowska Agnieszka
Published: January 2024

Background: This study aimed to compare whether a super bolus (SB) is a more efficient strategy than a normal bolus (NB) for high glycemic index (h-GI) meals in children with type 1 diabetes (T1D). Methods: A randomized, double-blind, crossover trial with an allocation ratio of 1:1, registered at ClinicalTrials.gov (NCT04019821). 72 children aged 10–18 years with T1D > 1 year, and on insulin pump therapy > 3 months were included. As an intervention, they ate a h-GI breakfast for the two following days and receive a prandial insulin bolus either in the form of SB or NB. Results: The SB group had lower glucose values during the observation time and lower glucose levels in 90th min (primary end point). The median time in range was also higher after SB. At the same time, more hypoglycemic episodes and a higher time below range were noted in this group. Almost 90% of them were the threshold value for initiating treatment for hypoglycemia and occurred near the end of observation period. More hyperglycemic episodes and over twice as much time in hyperglycemia were noted after NB. Conclusions: Super bolus is an effective strategy to avoid postprandial hyperglycemia but the basal insulin suspension should be longer to avoid hypoglycemia (f.ex. 3 h).
Ukrainian Consensus on Diagnosis and Management of Vitamin D Deficiency in Adults
Authors: Grygorieva Nataliia , Tronko Mykola , Kovalenko Volodymir , Komisarenko Serhiy , Tatarchuk Tetiana , Dedukh Ninel , Veliky Mykola , Strafun Serhiy , Komisarenko Yulia , Kalashnikov Andrii , Orlenko Valeria , Pankiv Volodymyr , Shvets Oleg , Gogunska Inna , Regeda Svitlana
Published: January 2024

Vitamin D deficiency (VDD) is a global problem, however, there were no Ukrainian guidelines devoted to its screening, prevention, and treatment, which became the reason for the Consensus creation. This article aimed to present the Consensus of Ukrainian experts devoted to VDD management. Following the creation of the multidisciplinary Consensus group, consent on the formation process, drafting and fine-tuning of key recommendations, and two rounds of voting, 14 final recommendations were successfully voted upon. Despite a recent decrease in VDD prevalence in Ukraine, we recommend raising awareness regarding VDD’s importance and improving the strategies for its decline. We recommend screening the serum 25-hydroxyvitamin D (25(OH)D) level in risk groups while maintaining a target concentration of 75–125 nmol/L (30–50 ng/mL). We recommend prophylactic cholecalciferol supplementation (800–2000 IU/d for youthful healthy subjects, and 3000–5000 IU/d for subjects from the risk groups). For a VDD treatment, we recommend a short-term administration of increased doses of cholecalciferol (4000–10,000 IU/d) with 25(OH)D levels monitored after 4–12 weeks of treatment, followed by the use of maintenance doses. Additionally, we recommend assessing serum 25(OH)D levels before antiosteoporotic treatment and providing vitamin D and calcium supplementation throughout the full course of the antiosteoporotic therapy.
Regular and Irregular Use and Reasons for Discontinuation of Solifenacin Therapy in Patients with Overactive Bladder Managed by Urologists
Authors: Małkowski Mateusz , Almgren-Rachtan Agnieszka , Olszanecka-Glinianowicz Magdalena , Chudek Jerzy , Chłosta Piotr
Published: January 2024

Solifenacin, a selective muscarinic receptor antagonist, is one of the best-tolerated and most effective medicines that relieve storage symptoms in patients with an overactive bladder (OAB). However, the persistence of solifenacin in daily clinical practice remains far below that reported in clinical trials. This study aimed to analyze the adherence of patients to the therapy and the reasons for solifenacin discontinuation and non-regular use in OAB patients managed by urologists. Data concerning non-compliance and the discontinuation of solifenacin, along with the reasons, were collected during two consecutive visits for 64,049 OAB outpatients. Over the two visits, 81.6% of the patients continued therapy, and 88.6% were taking solifenacin regularly. An age ≥ 75 yrs., the male sex, a rural or small-city dwelling, and a prescription of ≥10 mg predicted therapy continuation. The female sex, a higher education, a short or long duration of an OAB, and a non-idiopathic OAB predicted regular use. The persistence of nycturia and urinary incontinence during therapy predicted both discontinuation and non-regular use. Dissatisfaction with therapy was the most frequent reason for discontinuation. In conclusion, an initial prescription of solifenacin at a low dose reduces the chance of OAB symptom improvement and results in more frequent discontinuation. A high rate of discontinuation related to dissatisfaction suggests unrealistic expectations for OAB patients and insufficient education by urologists.
Assessment of Patient-Reported Outcomes at 48 Months of Treatment with Dupilumab for Severe Atopic Dermatitis: A Single-Center Real-Life Experience with 126 Patients
Authors: Barei Francesca , Zussino Martina , Tavecchio Simona , Angileri Luisa , Rizzo Arianna , Calzari Paolo , Marzano Angelo V. , Ferrucci Silvia
Published: January 2024

Background: The main objective was to analyze patient-reported outcomes (PRO) trends over a four-year period in severe atopic dermatitis (AD) patients treated with dupilumab. Methods: data from 126 severe patients receiving dupilumab for at least 48 months were collected. The clinical scores assessed included the Eczema Area and Severity Index (EASI), Pruritus Numerical Rating Scale (NRS), Sleep NRS, Patient-Oriented Eczema Measure (POEM), Dermatology Life Quality Index (DLQI), and Atopic Dermatitis Control Tool (ADCT). Results: the study compellingly demonstrates dupilumab’s effectiveness in reducing EASI and improving PROs, with sustained enhancements observed beyond the initial twelve months of treatment. Univariate and multivariate regression analyses show that baseline factors do not significantly increase the risk of adverse outcomes related to Pruritus NRS, POEM, or ADCT at T48. The robust correlation between ADCT and other PROs suggests closely aligned changes. Conclusion: Dupilumab’s benefits endure beyond the first year, emphasizing its long-term efficacy, and consistently improves AD outcomes regardless of individual characteristics or clinical variables. ADCT appears to be a practical and versatile tool for the streamlined assessment of AD treatment outcomes.
Burst Release from In Situ Forming PLGA-Based Implants: 12 Effectors and Ways of Correction
Authors: Bakhrushina Elena O. , Sakharova Polina S. , Konogorova Polina D. , Pyzhov Victor S. , Kosenkova Svetlana I. , Bardakov Alexander I. , Zubareva Irina M. , Krasnyuk Ivan I. , Krasnyuk Ivan I.
Published: January 2024

In modern pharmaceutical technology, modified-release dosage forms, such as in situ formed implants, are gaining rapidly in popularity. These dosage forms are created based on a configurable matrix consisting of phase-sensitive polymers capable of biodegradation, a hydrophilic solvent, and the active substance suspended or dissolved in it. The most used phase-sensitive implants are based on a biocompatible and biodegradable polymer, poly(DL-lactide-co-glycolide) (PLGA). Objective: This systematic review examines the reasons for the phenomenon of active ingredient “burst” release, which is a major drawback of PLGA-based in situ formed implants, and the likely ways to correct this phenomenon to improve the quality of in situ formed implants with a poly(DL-lactide-co-glycolide) matrix. Data sources: Actual and relevant publications in PubMed and Google Scholar databases were studied. Study selection: The concept of the review was based on the theory developed during literature analysis of 12 effectors on burst release from in situ forming implants based on PLGA. Only those studies that sufficiently fully disclosed one or another component of the theory were included. Results: The analysis resulted in development of a systematic approach called the “12 Factor System”, which considers various constant and variable, endogenous and exogenous factors that can influence the nature of ‘burst release’ of active ingredients from PLGA polymer-based in situ formed implants. These factors include matrix porosity, polymer swelling, LA:GA ratio, PLGA end groups, polymer molecular weight, active ingredient structure, polymer concentration, polymer loading with active ingredients, polymer combination, use of co-solvents, addition of excipients, and change of dissolution conditions. This review also considered different types of kinetics of active ingredient release from in situ formed implants and the possibility of using the “burst release” phenomenon to modify the active ingredient release profile at the site of application of this dosage form.
Genome-Wide Association Study for Agronomic Traits in Gamma-Ray-Derived Mutant Kenaf (Hibiscus cannabinus L.)
Authors: Kim Woon Ji , Yang Baul , Lee Ye-jin , Kim Jae Hoon , Kim Sang Hoon , Ahn Joon-Woo , Kang Si-Yong , Kim Seong-Hoon , Ryu Jaihyunk
Published: January 2024

Kenaf (Hibiscus cannabinus L.), in the Malvaceae family, is an important crop for not only fiber production, but also various other industrial materials. We performed phylogenetic analysis and a genome-wide association study (GWAS) of seven agronomic traits: days to flowering, plant height, fresh weight, dry weight, flower color, stem color, and leaf shape, using 96 kenaf genotypes, including gamma-irradiation-derived mutant lines. Genotypes were determined by genotyping-by-sequencing (GBS) and a total of 49,241 single-nucleotide polymorphisms (SNPs) were used in the analysis. Days to flowering, plant height, fresh weight, and dry weight were positively correlated with each other, and stem color was also correlated with fresh weight and dry weight. The phylogenetic analysis divided the 96 lines into nine related groups within two independent groups, and the GWAS analysis detected a total of 49 SNPs for days to flowering, plant height, fresh weight, dry weight, flower color, stem color, and leaf shape with −log10(P) ≥ 4, of which 22 were located in genic regions. The detected SNPs were located in genes with homology ranging from 45% to 96% to plants of the Malvaceae and Betulaceae, and these genes were found to be involved in plant growth and development via various pathways. Our identification of SNP markers related to agronomic traits is expected to help improve the quality of selective breeding programs for kenaf.
Clinopodium L. Taxa from the Balkans—Are There Unique Leaf Micromorphological and Phytochemical Patterns?
Authors: Janković Smiljana , Alimpić Aradski Ana , Dodoš Tanja , Novaković Jelica , Ivanović Stefan , Vujisić Ljubodrag , Marin Petar D. , Rajčević Nemanja
Published: January 2024

The concept of the genus Clinopodium L. has changed considerably since its first description. Most of the currently accepted species of the genus have traditionally been treated as separate genera in the group Satureja sensu lato: Clinopodium L., Calamintha sensu Miller or Moench, and Acinos sensu Miller or Moench. This study aimed to gain a better insight into the species diversity of Clinopodium L. from the Balkans by analyzing the taxa that have traditionally been placed in separate genera. The alkane profile and the micromorphological characteristics of the leaves are analyzed. The leaves are visualized using scanning electron microscopy, and alkanes are isolated using n-hexane as a solvent and analyzed using gas chromatography/mass spectrometry. The alkane profile showed the differentiation of the Acinos-group from the other taxa based on the dominant n-C31, while most of the other taxa contained n-C33 as the dominant alkane. The micromorphological features also showed clear differences between the previously recognized genera, especially in the capitate trichomes. The results showed that micromorphological patterns are highly variable in certain groups of the genus Clinopodium.
Evaluation of Five Chrysanthemum morifolium Cultivars against Leaf Blight Disease Caused by Alternaria alternata at Rooting and Seedling Growth Stages
Authors: Seliem Mayada K. , Taha Naglaa A. , El-Feky Nahla I. , Abdelaal Khaled , El-Ramady Hassan , El-Mahrouk Mohammed E. , Bayoumi Yousry A.
Published: January 2024

During the winter of 2018, leaf blight on florist’s daisy (Chrysanthemum morifolium L.) was noticed in Egypt. The disease, which was identified as caused by Alternaria alternata, was widely spread and led to serious damage for the exportation sector of this crop. Therefore, a study was conducted to better understand what can be conducted to minimize the problem in the future. Isolates were gathered and evaluated on five chrysanthemum cultivars (i.e., ‘Feeling Green Dark’, ‘Talitha’, ‘Chrystal Regan’, ‘Arctic queen’, and ‘Podolsk Purple’) grown in a greenhouse. The objectives were to isolate and identify the phytopathogen and detect the resistant degree of these cultivars with emphasis on the early growth stages of the crop. The results showed that ‘Podolsk Purple’ was the most resistant cultivar against the different isolates during the rooting and seedling growth stages. ‘Chrystal Regan’ was very susceptible to the different isolates. In addition, the isolate from ‘Feeling Green Dark’ was the strongest, which negatively affected the chlorophyll content and its fluorescence parameters besides other measured vegetative and anatomical features. The findings indicated that the best anatomical characters of the stem and leaf, like the thickness of cuticle and cortex, stem diameter, xylem vessel diameter, and thickness of epidermis as well as lamina thickness were recorded in the ‘Podolsk Purple’ cultivar. This study highlighted that by using the right cultivars, chrysanthemum can be cultivated during the winter season under Egyptian conditions. These results can be a part of solution to overcome the leaf blight caused by A. alternata on chrysanthemum during the early growing stages.
Polystyrene (PS) Degradation Induced by Nanosecond Electric Discharge in Air in Contact with PS/Water
Authors: Zamo Aurélie , Rond Catherine , Hamdan Ahmad
Published: January 2024

Water pollution with microplastics has become a significant concern. Conventional treatment methods have proven ineffective, and alternatives are being explored. Herein, we assess the degradation efficiency of polystyrene (PS) by measuring its nanosecond discharge in air in contact with water. Its discharge is characterized during processing, and a transition from streamer-like to spark-like discharge occurs due to the increased electrical conductivity of water. Experiments are conducted at different frequencies, and the highest degradation is achieved at 10 kHz; an 83% polystyrene weight loss is recorded after 5 min of processing. The optical spectra of the discharge show no evidence of C-species, and an FTIR analysis of the processed polystyrene reveals no structural modifications. An NMR analysis shows the presence of ethylbenzene in water. Finally, a mechanism of PS degradation is proposed.
Experimental Studies and Application of Fiber-Reinforced Polymers (FRPs) in Civil Infrastructure Systems: A State-of-the-Art Review
Authors: Albuja-Sánchez Jorge , Damián-Chalán Andreina , Escobar Daniela
Published: January 2024

The application of FRPs in civil infrastructure has increased, particularly in the last 20 years. FRPs have gained importance because of their resistance to harsh environments, high strength-to-weight ratio, and good corrosion resistance, and they are faster and easier to apply than other traditional methods. The rehabilitation of structures is the main area in which FRPs have been developed, because they have allowed for compliance with architectural restraints in historic structures. This review is a compilation of the research conducted on the laboratory and field applications of FRPs, highlighting the different applied methods, installation difficulties, and failure modes of FRPs. Moreover, this review compares studies on the types of fibers such as CFRPs, GFRPs, and AFRPs, and their effects would affect the mechanical properties of civil infrastructure and the durability characteristics of civil infrastructure in challenging environmental conditions. In addition, this review focuses on the modification of the mechanical properties of structural elements using different methods of installing FRPs, including externally bonded reinforcement (EBR), and their main problem: debonding failure before the ultimate load.
Synthesis and Properties of Semicrystalline Poly(ether nitrile ketone) Copolymers
Authors: Zhu Jiang , Mo Chao , Tong Lifen , Liu Xiaobo
Published: January 2024

As a high-performance engineering plastic, polyarylene ether nitrile (PEN) is widely used in many fields. The presence of cyano groups of PEN ensures its good adhesion to other substrates, but the inherent low crystallinity of PEN limits its application. In this work, the poly(aryl ether ketone) segment was introduced into PEN via copolymerization using both 2,6-Dichlorobenzonitrile and 4,4′-Difluorobenzophenone as the starting reagents to prepare poly (ether nitrile ketone) (BP-PENK). The effect of composition and thermal treatment on the crystallization behavior and properties of poly (ether nitrile ketone) were systematically studied. It was found that when the content of DFBP is 30%, the copolymer BP-PENK30 had the best mechanical properties, with a tensile strength of 109.9 MPa and an elongation at a break value of 45.2%. After thermal treatment at 280 °C for 3 h, BP-PENK30 had the highest crystallinity with a melting point of 306.71 °C, a melting enthalpy of 5.02 J/g, and crystallinity of 11.83%. Moreover, with the increase in crystallinity, the dielectric constant and energy density increased after thermal treatment. Therefore, the introduction of poly(aryl ether ketone) chain segments and thermal treatment can effectively improve the crystallization and the comprehensive properties of PEN.
Facile Preparation of Polyacrylonitrile-Based Activated Carbon Fiber Felts for Effective Adsorption of Dipropyl Sulfide
Authors: Zhang Tianhao , He Yafang , Hu Shiqi , Ge Jianlong , Chen Tianye , Shan Haoru , Ji Tao , Yu Decheng , Liu Qixia
Published: January 2024

Activated carbon fibers (ACFs) derived from various polymeric fibers with the characteristics of a high specific surface area, developed pore structure, and good flexibility are promising for the new generation of chemical protection clothing. In this paper, a polyacrylonitrile-based ACF felt was prepared via the process of liquid phase pre-oxidation, along with a one-step carbonization and chemical activation method. The obtained ACF felt exhibited a large specific surface area of 2219.48 m2/g and pore volume of 1.168 cm3/g, as well as abundant polar groups on the surface. Owing to the developed pore structure and elaborated surface chemical property, the ACF felt possessed an intriguing adsorption performance for a chemical warfare agent simulant dipropyl sulfide (DPS), with the highest adsorption capacity being 202.38 mg/g. The effects of the initial concentration of DPS and temperature on the adsorption performance of ACF felt were investigated. Meanwhile, a plausible adsorption mechanism was proposed based on the kinetic analysis and fitting of different adsorption isotherm models. The results demonstrated that the adsorption process of DPS onto ACF felt could be well fitted with a pseudo-second-order equation, indicating a synergistic effect of chemical adsorption and physical adsorption. We anticipate that this work could be helpful to the design and development of advanced ACF felts for the application of breathable chemical protection clothing.
Polylactide-Based Nonisocyanate Polyurethanes: Preparation, Properties Evaluation and Structure Analysis
Authors: Białkowska Anita , Kucharczyk Wojciech , Zarzyka Iwona , Hanulikova Barbora , Masař Milan , Bakar Mohamed
Published: January 2024

This study investigated the successful synthesis and characterization of nonisocyanate polyurethanes (NIPUs) based on polylactide. The NIPUs were synthesized by a condensation reaction of oligomers with hard segments (HSs) and synthesized carbamate-modified polylactic acid containing flexible segments (FSs). The oligomers with HSs were prepared from phenolsulfonic acid (PSA) or a mixture of PSA and hydroxynaphthalenesulfonic acid (HNSA), urea and formaldehyde. The mixing of oligomeric compounds with different amounts of formaldehyde was carried out at room temperature. Obtained NIPU samples with different hard segment content were tested for their mechanical and thermal properties. The tensile strength (TS) of all NIPU samples increased with an increasing amount of HSs, attaining the maximum value at an HS:FS ratio of 1:3. Samples prepared from PSA and HNSA showed higher tensile strength (TS) without significant change in elongation at break compared to the samples based only on PSA. Thermogravimetric analysis data indicated an absence of weight loss for all samples below 100 °C, which can be considered a safe temperature for using NIPU materials. Maximum degradation temperatures reached up to 385 °C. Fourier transform infrared spectroscopy results confirmed the existence of expected specific groups as well as the chemical structure of the prepared polyurethanes. DSC analysis showed the existence of two characteristic phase transitions attributed to the melting and crystallization of hard segments in the NIPU samples.
Polymeric Binder Design for Sustainable Lithium-Ion Battery Chemistry
Authors: Yoon Juhee , Lee Jeonghun , Kim Hyemin , Kim Jihyeon , Jin Hyoung-Joon
Published: January 2024

The design of binders plays a pivotal role in achieving enduring high power in lithium-ion batteries (LIBs) and extending their overall lifespan. This review underscores the indispensable characteristics that a binder must possess when utilized in LIBs, considering factors such as electrochemical, thermal, and dispersion stability, compatibility with electrolytes, solubility in solvents, mechanical properties, and conductivity. In the case of anode materials, binders with robust mechanical properties and elasticity are imperative to uphold electrode integrity, particularly in materials subjected to substantial volume changes. For cathode materials, the selection of a binder hinges on the crystal structure of the cathode material. Other vital considerations in binder design encompass cost effectiveness, adhesion, processability, and environmental friendliness. Incorporating low-cost, eco-friendly, and biodegradable polymers can significantly contribute to sustainable battery development. This review serves as an invaluable resource for comprehending the prerequisites of binder design in high-performance LIBs and offers insights into binder selection for diverse electrode materials. The findings and principles articulated in this review can be extrapolated to other advanced battery systems, charting a course for developing next-generation batteries characterized by enhanced performance and sustainability.
Grafting Starch with Acrylic Acid and Fenton’s Initiator: The Selectivity Challenge
Authors: Noordergraaf Inge-Willem , Witono Judy R. , Heeres Hero J.
Published: January 2024

Through the graft polymerization of acrylic monomers onto starch, materials with interesting new properties can be synthesized. Fenton’s chemistry, Fe2+/H2O2, is considered to be attractive for the initiation of graft polymerization with the monomer acrylic acid since it is cheap and reacts quickly at ambient conditions and should therefore be easy to scale up. However, the selectivity of the grafting versus the homopolymerization reaction poses a challenge with this monomer and this type of initiator. In the present review paper, we investigate why data from the literature on grafting systems with other monomers and initiation systems tend to show higher graft selectivity. A scheme is presented, based on reaction engineering principles, that supports an explanation for these observed differences. It is found that more selective activation of starch is a factor, but perhaps even more important is a low monomer-to-starch ratio at the starting sites of graft reactions. Since water is the most common solvent, monomers that are less water-soluble have an advantage in this respect. Based on the proposed scheme, methods to improve the graft selectivity with Fenton’s initiator and acrylic acid are evaluated. Most promising appears to be a method of gradual monomer dosage. With gelatinized cassava starch in a batch reactor, both the grafting percentage (17 => 29%) and graft selectivity (18 => 31%) could be improved. This can be considered a principal breakthrough. Still, more research and development would be needed to refine the method and to implement the idea in a continuous reactor at a larger scale.
Synthesis of Vinyl-Containing Polydimethylsiloxane in An Active Medium
Authors: Khmelnitskaia Alina G. , Kalinina Aleksandra A. , Meshkov Ivan B. , Tukhvatshin Rinat S. , Cherkaev Georgii V. , Ponomarenko Sergey A. , Muzafarov Aziz M.
Published: January 2024

This research deals with the synthesis of copoly(methylvinyl)(dimethyl)siloxanes by the copolycondensation of dimethyldiethoxy- and methylvinyldimethoxysilane in an active medium, followed by thermal condensation in a vacuum. We achieved a range of copolymers exhibiting finely tuned molecular weights spanning between 1500 and 20,000 with regulated functional methylvinylsiloxane units. Analysis of the microstructure showed that the copolymerization predominantly formed products demonstrating a random distribution of units (R~1). However, an increase in the content of vinyl-containing monomers increases the R parameter, indicating an enhanced tendency towards alternating linkages within the copolymer matrix.
Elaboration of Thermally Performing Polyurethane Foams, Based on Biopolyols, with Thermal Insulating Applications
Authors: De Hoyos-Martinez Pedro Luis , Mendez Sebastian Barriga , Martinez Eriz Corro , Wang De-Yi , Labidi Jalel
Published: January 2024

In this work, biobased rigid polyurethane foams (PUFs) were developed with the aim of achieving thermal and fireproofing properties that can compete with those of the commercially available products. First, the synthesis of a biopolyol from a wood residue by means of a scaled-up process with suitable yield and reaction conditions was carried out. This biopolyol was able to substitute completely the synthetic polyols that are typically employed within a polyurethane formulation. Different formulations were developed to assess the effect of two flame retardants, namely, polyhedral oligomeric silsesquioxane (POSS) and amino polyphosphate (APP), in terms of their thermal properties and degradation and their fireproofing mechanism. The structure and the thermal degradation of the different formulations was evaluated via Fourier Transformed Infrared Spectroscopy (FTIR) and thermogravimetric analysis (TGA). Likewise, the performance of the different PUF formulations was studied and compared to that of an industrial PUF. From these results, it can be highlighted that the addition of the flame retardants into the formulation showed an improvement in the results of the UL-94 vertical burning test and the LOI. Moreover, the fireproofing performance of the biobased formulations was comparable to that of the industrial one. In addition to that, it can be remarked that the biobased formulations displayed an excellent performance as thermal insulators (0.02371–0.02149 W·m−1·K−1), which was even slightly higher than that of the industrial one.
The Role of African Spirituality in the Provision of Kinship Care in the South African Context
Authors: Mshayisa Langa , Bhagwan Raisuyah , Dewan Fathima
Published: January 2024

This article focuses on understanding the role played by African spirituality in the provision of kinship care in the South African context. African traditional spirituality was found to be an important factor underpinning kinship care and its provision, especially in rural African communities. The study was conducted using a qualitative research methodology. Twenty-one (21) participants, who were kinship caregivers, were recruited using purposive non-probability sampling methods. The study found that African spirituality helped them to preserve both their cultural and personal identity. Furthermore, through African spirituality, children and youth in kinship care receive psychosocial support and experienced a positive upbringing through their kinship caregivers and tribal community. African kinship caregivers were found to offer kinship care as a spiritual duty to help children and youth who need care and protection in the absence of their birth parents.
The Abu Dhabi Document: A Potential Cornerstone for Islamic-Christian Dialogue in Italian Educational Contexts
Authors: Cuciniello Antonio
Published: January 2024

In Italy, the migratory phenomenon has also had an impact on the school system, becoming an interesting potential field for intercultural and inter-religious encounters. As regards, for instance, the presence of pupils and students and their families of Islamic faith, very frequently, emphasis is placed almost exclusively on specific issues and requests, such as exemption from the teaching of the Catholic religion or specific diet. On the other hand, we rarely discuss how the presence of diverse faiths can create a unique opportunity for mutual knowledge to spread and promote the “culture of encounter”. In fact, engagement with religious others is an unavoidable duty, both pedagogical and civic. Therefore, starting from an analysis of pedagogical-educational aspects of the Document on Human Fraternity for World Peace and Living Together, the aim of this article is to outline a rethinking of the concept of intercultural/inter-religious dialogue, above all as a pedagogical challenge and a preventive measure against extremism, within the broad framework of inclusive citizenship.
Harmony Justesse Analogia Linguae: Literature as a “First Language of God” in the Thought of Hans Urs von Balthasar
Authors: Polanco Rodrigo
Published: January 2024

Balthasar is, first and foremost, a Germanist. His theology is internally related to literature. This article shows how deep this link is, starting from three aspects: the literary coordinates that appear to be integrated in the theological structure of his thought, the theological language that Balthasar discovers in the literature, and the use of some literary instruments to engage with theology. Overall, Balthasar bases this profound and internal use of literature on the harmony/harmonization (Zum-stimmen-bringen/justesse/analogia linguae) he discovers between literary form or style and theological content. This harmony, justesse, or analogia is mediated by the free creativity of the author of the literary text under the power of the Spirit and sustained by the analogia entis and Christological analogia entis.
Mapping Compound Flooding Risks for Urban Resilience in Coastal Zones: A Comprehensive Methodological Review
Authors: Sun Hai , Zhang Xiaowei , Ruan Xuejing , Jiang Hui , Shou Wenchi
Published: January 2024

Coastal regions, increasingly threatened by floods due to climate-change-driven extreme weather, lack a comprehensive study that integrates coastal and riverine flood dynamics. In response to this research gap, we conducted a comprehensive bibliometric analysis and thorough visualization and mapping of studies of compound flooding risk in coastal cities over the period 2014–2022, using VOSviewer and CiteSpace to analyze 407 publications in the Web of Science Core Collection database. The analytical results reveal two persistent research topics: the way to explore the return periods or joint probabilities of flood drivers using statistical modeling, and the quantification of flood risk with different return periods through numerical simulation. This article examines critical causes of compound coastal flooding, outlines the principal methodologies, details each method’s features, and compares their strengths, limitations, and uncertainties. This paper advocates for an integrated approach encompassing climate change, ocean–land systems, topography, human activity, land use, and hazard chains to enhance our understanding of flood risk mechanisms. This includes adopting an Earth system modeling framework with holistic coupling of Earth system components, merging process-based and data-driven models, enhancing model grid resolution, refining dynamical frameworks, comparing complex physical models with more straightforward methods, and exploring advanced data assimilation, machine learning, and quasi-real-time forecasting for researchers and emergency responders.
Analysis of Lava from the Cumbre Vieja Volcano Using Remote Sensing Data from DESIS and Sentinel-2
Authors: De Los Reyes Raquel , Richter Rudolf , Plank Simon , Marshall David
Published: January 2024

On 19th September 2021, a protracted eruption of the Cumbre Vieja Volcano on the Canary Island of La Palma commenced and continued for a duration of 12 weeks. Lava flows starting from the rift zone at the mid-western flank of Cumbre Vieja advanced toward the western coast of the island. The eruption was monitored by different remote sensing satellites, including the Copernicus Sentinel missions and DESIS. The Sentinel-2 Copernicus satellites acquired multispectral data from 15th September onward. On September 30th, and with a difference of ∼2 h with respect to Sentinel-2 A, the DESIS hyperspectral sensor also acquired data from the volcano and then again on 15th October 2021. Typically, mid-infrared (around 3.8 μm) data are used for the thermal analysis of active lava flows. However, neither Sentinel-2 nor DESIS possesses mid-infrared bands and the Sentinel-2 high-wavelengths bands (∼2 μm) have some limitations. Nevertheless, the hyperspectral character of DESIS enables the analysis of active erupting volcanoes in near-infrared wavelengths. The results of this analysis find fluid lava temperatures of about 1100–1200 K but there are problems associated with the high-temperature lava spectral emissivity.
Adaptive Basis Function Method for the Detection of an Undersurface Magnetic Anomaly Target
Authors: Liu Xingen , Yuan Zifan , Du Changping , Peng Xiang , Guo Hong , Xia Mingyao
Published: January 2024

The orthogonal basis functions (OBFs) method is a prevailing choice for the detection of undersurface magnetic anomaly targets. However, it requires the detecting platform or target to move uniformly along a straight path. To circumvent the restrictions, a new adaptive basis functions (ABFs) approach is proposed in this article. It permits the detection platform to search for a possible target at different speeds along any course. The ABFs are constructed using the real-time data of the onboard triaxial fluxgate, GPS module, and attitude gyro. Based on the pseudo-energy of an apparent target signal, the constant false alarm rate (CFAR) method is employed to judge whether a target is present. Moreover, by defining the pixel as a relative possibility for a target at a geographic location, a magnetic anomaly target imaging scheme is introduced by displaying the pixels onto the searching area. On-site experimental data are utilized to demonstrate the proposed approach. Compared with the traditional OBFs method, the present ABFs approach can substantially improve the detection possibility and reduce false alarms.
Low-Coherence Homodyne Interferometer for Sub-Megahertz Fiber Optic Sensor Readout
Authors: Volkov Petr , Lukyanov Andrey , Goryunov Alexander , Semikov Daniil , Vyazankin Oleg
Published: January 2024

This study proposes a method for interferometric fiber optic sensor readouts. The method utilizes the advantages of the active homodyne demodulation technique and low-coherence interferometry. The usage of the tandem low-coherence interferometer enables modulating the reference interferometer without any changes to the sensor. This achieves high sensitivity, high stability, and a wide frequency band. A sensitivity of up to 0.1 nm (RMS) in the frequency range of 5 kHz is demonstrated by detecting acoustic signals with a fiber Michelson interferometer as a sensor.
Performance Enhancement of the Polarimetric Fibre Optical Current Sensor at JET Using Polarisation Optimisation
Authors: Gusarov Andrei , Beaumont Perry , Siren Paula ,   JET Contributors
Published: January 2024

To achieve optimal operation of the polarimetry-based FOCS, the light polarisation state at the input of the sensing fibre part must be close to a linear one. In the case of a FOCS deployed on a tokamak, the Joint European Torus (JET) in the present work, the long fibre optics link between the laser source and the sensing fibre modifies the polarisation in an unpredictable way, making it unclear which source polarisation state is to be set. A method for performing the necessary polarisation adjustment in a systematic way is proposed based on the FOCS analysis. The method requires performing data acquisition at two different input polarisations. Based on these measurements, the optimal laser source polarisation can be found. The method was experimentally verified using laboratory set-up and then successfully demonstrated with the FOCS installed at JET.
Improved LEACH Protocol Based on Underwater Energy Propagation Model, Parallel Transmission, and Replication Computing for Underwater Acoustic Sensor Networks
Authors: Tian Kun , Zhou Chang , Zhang Jun
Published: January 2024

Underwater acoustic sensor networks (UASNs) are critical to a range of applications from oceanographic data collection to submarine surveillance. In these networks, efficient energy management is critical due to the limited power resources of underwater sensors. The LEACH protocol, a popular cluster-based protocol, has been widely used in UASNs to minimize energy consumption. Despite its widespread use, the conventional LEACH protocol faces challenges such as an unoptimized cluster number and low transmission efficiency, which hinder its performance. This paper proposes an improved LEACH protocol for cluster-based UASNs, where the cluster number is optimized with an underwater energy propagation model to reduce energy consumption, and a transmission scheduling algorithm is also employed to achieve conflict-free parallel data transmission. Replication computing is introduced to the LEACH protocol to reduce the signaling in the clustering and data transmission phases. The simulation results show that the proposed protocol outperforms several conventional methods in terms of normalized average residual energy, average number of surviving nodes, average round when the first death node occurs, and the number of packets received by the base station.
Convolutional Neural Network (CNN) Model for the Classification of Varieties of Date Palm Fruits (Phoenix dactylifera L.)
Authors: Rybacki Piotr , Niemann Janetta , Derouiche Samir , Chetehouna Sara , Boulaares Islam , Seghir Nili Mohammed , Diatta Jean , Osuch Andrzej
Published: January 2024

The popularity and demand for high-quality date palm fruits (Phoenix dactylifera L.) have been growing, and their quality largely depends on the type of handling, storage, and processing methods. The current methods of geometric evaluation and classification of date palm fruits are characterised by high labour intensity and are usually performed mechanically, which may cause additional damage and reduce the quality and value of the product. Therefore, non-contact methods are being sought based on image analysis, with digital solutions controlling the evaluation and classification processes. The main objective of this paper is to develop an automatic classification model for varieties of date palm fruits using a convolutional neural network (CNN) based on two fundamental criteria, i.e., colour difference and evaluation of geometric parameters of dates. A CNN with a fixed architecture was built, marked as DateNET, consisting of a system of five alternating Conv2D, MaxPooling2D, and Dropout classes. The validation accuracy of the model presented in this study depended on the selection of classification criteria. It was 85.24% for fruit colour-based classification and 87.62% for the geometric parameters only; however, it increased considerably to 93.41% when both the colour and geometry of dates were considered.
Evaluation of a Machine Learning Algorithm to Classify Ultrasonic Transducer Misalignment and Deployment Using TinyML
Authors: Brennan Des , Galvin Paul
Published: January 2024

The challenge for ultrasonic (US) power transfer systems, in implanted/wearable medical devices, is to determine when misalignment occurs (e.g., due to body motion) and apply directional correction accordingly. In this study, a number of machine learning algorithms were evaluated to classify US transducer misalignment, based on data signal transmissions between the transmitter and receiver. Over seven hundred US signals were acquired across a range of transducer misalignments. Signal envelopes and spectrograms were used to train and evaluate machine learning (ML) algorithms, classifying misalignment extent. The algorithms included an autoencoder, convolutional neural network (CNN) and neural network (NN). The best performing algorithm, was deployed onto a TinyML device for evaluation. Such systems exploit low power microcontrollers developed specifically around edge device applications, where algorithms were configured to run on low power, restricted memory systems. TensorFlow Lite and Edge Impulse, were used to deploy trained models onto the edge device, to classify signals according to transducer misalignment extent. TinyML deployment, demonstrated near real-time (<350 ms) signal classification achieving accuracies > 99%. This opens the possibility to apply such ML alignment algorithms to US arrays (capacitive micro-machined ultrasonic transducer (CMUT), piezoelectric micro-machined ultrasonic transducer (PMUT) devices) capable of beam-steering, significantly enhancing power delivery in implanted and body worn systems.
Experimental Investigation and Damage Identification of High-Pile Wharf Framed Bents under Horizontal Impact Loads
Authors: Zheng Yonglai , Xiao Fei , Zhang Ruxue , Pan Tanbo , Lan Xin , Xu Xubing , Hou Chenyu
Published: January 2024

This study investigates damage characteristics, dynamic structural performance changes, and quantitative damage assessment of high-pile wharf framed bents exposed to horizontal impact loads. Through extensive testing of wharf framed bents under such loads, a damage identification approach based on stiffness, natural vibration period, and acceleration data derived from experiments is presented. The findings reveal that under horizontal impact loads, framed bents initially exhibit tensile damage and leaning piles, followed by short straight piles. Additionally, structural damage results in a reduced self-oscillation frequency and an increased amplitude decay rate. Both stiffness-based and cycle-based damage indicators effectively track the cumulative damage progression of the structure. However, the cycle-based damage indicators demonstrate superior stability and accuracy, while acceleration-based indicators precisely identify the moment of damage mutation. This research contributes to enhancing local components, implementing damage identification methods, and advancing health monitoring practices in high-pile wharf projects, aligning with the standards of scientific publications in the field.
Lightweight Transformer Model for Mobile Application Classification
Authors: Gwak Minju , Cha Jeongwon , Yoon Hosun , Kang Donghyun , An Donghyeok
Published: January 2024

Recently, realistic services like virtual reality and augmented reality have gained popularity. These realistic services require deterministic transmission with end-to-end low latency and high reliability for practical applications. However, for these real-time services to be deterministic, the network core should provide the requisite level of network. To deliver differentiated services to each real-time service, network service providers can classify applications based on traffic. However, due to the presence of personal information in headers, application classification based on encrypted application data is necessary. Initially, we collected application traffic from four well-known applications and preprocessed this data to extract encrypted application data and convert it into model input. We proposed a lightweight transformer model consisting of an encoder, a global average pooling layer, and a dense layer to categorize applications based on the encrypted payload in a packet. To enhance the performance of the proposed model, we determined hyperparameters using several performance evaluations. We evaluated performance with 1D-CNN and ET-BERT. The proposed transformer model demonstrated good performance in the performance evaluation, with a classification accuracy and F1 score of 96% and 95%, respectively. The time complexity of the proposed transformer model was higher than that of 1D-CNN but performed better in application classification. The proposed transformer model had lower time complexity and higher classification performance than ET-BERT.