bluuebunny/crossref_metadata_2025 huggingface dataset:
Biological Control of Celery Powdery Mildew Disease Caused by Erysiphe heraclei DC In Vitro and In Vivo Conditions
Authors: Ahmed Hamada F. A. , Seleiman Mahmoud F. , Al-Saif Adel M. , Alshiekheid Maha A. , Battaglia Martin L. , Taha Ragab S.
Published: November 2021

The present study aimed to investigate the potentiality of certain biocontrol agents, namely Bacillus subtilis, B. pumilus, B. megaterium, Pseudomonas fluorescens, Serratia marcescens, Trichoderma album, T. harzianum and T. viride, as well as the synthetic fungicide difenoconazole to control celery powdery mildew caused by Erysiphe heraclei DC, in vitro (against conidia germination and germ tube length of E. heraclei) and in vivo (against disease severity and AUDPC). In vitro, it was found that the antifungal activity of the tested biocontrol agents significantly reduced the germination percentage of the conidia and germ tube length of the pathogen. The reduction in conidia germination ranged between 88.2% and 59.6% as a result of the treatment with B. subtilis and T. album, respectively compared with 97.1% by the synthetic fungicide difenoconazole. Moreover, the fungicide achieved the highest reduction in germ tube length (92.5%) followed by B. megaterium (82.0%), while T. album was the least effective (62.8%). Spraying celery plants with the tested biocontrol agents in the greenhouse significantly reduced powdery mildew severity, as well as the area under the disease progress curve (AUDPC), after 7, 14, 21 and 28 days of application. In this regard, B. subtilis was the most efficient followed by B. pumilus, S. marcescens and B. megaterium, with 80.1, 74.4, 73.2 and 70.5% reductions in disease severity, respectively. In AUDPC, reductions of those microorganisms were 285.3, 380.9, 396.7 and 431.8, respectively, compared to 1539.1 in the control treatment. On the other hand, the fungicide difenoconazole achieved maximum efficacy in reducing disease severity (84.7%) and lowest AUDPC (219.3) compared to the other treatments. In the field, all the applied biocontrol agents showed high efficiency in suppressing powdery mildew on celery plants, with a significant improvement in growth and yield characteristics. In addition, they caused an increase in the concentration of leaf pigments, and the activities of defense-related enzymes such as peroxidase (PO) and polyphenol oxidase (PPO) and total phenol content (TPC). In conclusion, the results showed the possibility of using tested biocontrol agents as eco-friendly alternatives to protect celery plants against powdery mildew.
Extremophilic Microalgae Galdieria Gen. for Urban Wastewater Treatment: Current State, the Case of “POWER” System, and Future Prospects
Authors: di Cicco Maria Rosa , Iovinella Manuela , Palmieri Maria , Lubritto Carmine , Ciniglia Claudia
Published: November 2021

Over the past decades, wastewater research has increasingly focused on the use of microalgae as a tool to remove contaminants, entrapping nutrients, and whose biomass could provide both material and energy resources. This review covers the advances in the emerging research on the use in wastewater sector of thermoacidophilic, low-lipid microalgae of the genus Galdieria, which exhibit high content of protein, reserve carbohydrates, and other potentially extractable high-value compounds. The natural tolerance of Galdieria for high toxic environments and hot climates recently made it a key player in a single-step process for municipal wastewater treatment, biomass cultivation and production of energetic compounds using hydrothermal liquefaction. In this system developed in New Mexico, Galdieria proved to be a highly performing organism, able to restore the composition of the effluent to the standards required by the current legislation for the discharge of treated wastewater. Future research efforts should focus on the implementation, in the context of wastewater treatment, of more energetically efficient cultivation systems, potentially capable of generating water with increasingly higher purity levels.
Cornus mas and Cornus officinalis—A Comparison of Antioxidant and Immunomodulatory Activities of Standardized Fruit Extracts in Human Neutrophils and Caco-2 Models
Authors: Czerwińska Monika E. , Bobińska Agata , Cichocka Katarzyna , Buchholz Tina , Woliński Konrad , Melzig Matthias F.
Published: November 2021

Fruits of Cornus mas and Cornus officinalis are representative plant materials traditionally used in Europe and Asia, respectively, in the treatment of diabetes and diabetes-related complications, which are often mediated by pathogenic inflammatory agents. Additionally, due to the fact of mutual infiltration of Asian and European medicines, the differentiation as well as standardization of traditional prescriptions seem to be crucial for ensuring the quality of traditional products. The objective of this study was a comparison of biological activity of extracts from fruits of C. mas and C. officinalis by an assessment of their effect on reactive oxygen species (ROS) generation in human neutrophils as well as cytokines secretion both in neutrophils (tumor necrosis factor α, TNF- α; interleukin 8, IL-8; interleukin 1β, IL-1β) and in human colon adenocarcinoma cell line Caco-2 (IL-8). To evaluate the phytochemical differences between the studied extracts as well as to provide a method for standardization procedures, a quantitative analysis of iridoids, such as loganin, sweroside, and loganic acid, found in extracts of Cornus fruits was performed with HPLC-DAD. All standardized extracts significantly inhibited ROS production, whereas the aqueous-alcoholic extracts were particularly active inhibitors of IL-8 secretion by neutrophils. The aqueous-methanolic extract of C. officinalis fruit, decreased IL-8 secretion by neutrophils to 54.64 ± 7.67%, 49.68 ± 6.55%, 50.29 ± 5.87% at concentrations of 5, 50, and 100 µg/mL, respectively, compared to LPS-stimulated control (100%). The aqueous extract of C. officinalis fruit significantly inhibited TNF-α release by neutrophils at concentrations of 50 and 100 µg/mL. On the other hand, the aqueous-ethanolic extract of C. mas fruit showed the propensity to increase TNF-α and IL-1β secretion. The modulatory activity of the Cornus extracts was noted in the case of secretion of IL-8 in Caco-2 cells. The effect was comparable with dexamethasone. The content of loganin in aqueous and aqueous-methanolic extract of C. officinalis fruit was higher than in the aqueous-ethanolic extract of C. mas fruit, which was characterized by a significant quantity of loganic acid. In conclusion, the immunomodulatory effect observed in vitro may partially confirm the traditional use of Cornus fruits through alleviation of the development of diabetes-derived inflammatory complications. Loganin and loganic acid are significant markers for standardization of C. mas and C. officinalis fruit extracts, respectively.
Compositional Characteristics of Glucuronide Conjugates in Regional Glechoma hederacea var. longituba Herbal Extracts Using a Set of Polyphenolic Marker Compounds
Authors: Hahm Young Hye , Cho Kun , Ahn Yeong Hee
Published: November 2021

Glechoma hederacea var. longituba (GHL) is one of many herbal plants widely used in hot herbal teas and in oriental prescriptions to treat various diseases. Although the beneficial effects of GHL may be influenced by differences in the composition of active constituents in the herbal extracts, there are few reports on the compositional characteristics of GHL herbal extracts to date. In this study, liquid chromatography–mass spectrometry technology was used for comparative analysis of constituents in hot-water extracts of GHL samples obtained from various cultivating provinces in South Korea. A set of marker panel consisting of nine polyphenolic compounds, including glucuronide conjugates in particular, was constructed and used to monitor the compositional characteristics in each GHL extract. Our findings show that some of the marker compounds, including rosmarinic acid, were persistently observed as major constituents in the analyses of the 22 GHL sample extracts, whereas, interestingly, other marker compounds such as polyphenol-glucuronic acid conjugates displayed dramatic differences in compositional ratios. This chromatographic approach using the marker compound panel can be applied to qualitatively and quantitatively evaluate compositional characteristics in the GHL extracts, and can also be useful for quality assays of the GHL herbal plant in medicinal and industrial fields.
Seed Paternity Analysis Using SSR Markers to Assess Successful Pollen Donors in Mixed Olive Orchards
Authors: Vuletin Selak Gabriela , Baruca Arbeiter Alenka , Cuevas Julián , Perica Slavko , Pujic Petar , Raboteg Božiković Marina , Bandelj Dunja
Published: November 2021

The olive tree (Olea europaea L.) is a wind-pollinated crop that exhibits an extreme alternate bearing habit. To improve fruit set, several methods have been used to determine the most successful compatible combinations of cultivars. In this study, priority is given to seed paternity analysis based on simple sequence repeats (SSRs), microsatellite markers used for the identification of potential pollen donors of cultivar ‘Oblica’ in a mixed olive orchard during two consecutive years. Seven microsatellite primers were successfully used to examine the paternity of olive embryos from ‘Oblica’ mother trees. Embryos were considered as a product of self-fertilization if only maternal alleles were present, but not a single case of self-fertilization was found among all the embryos analyzed. Two dominant pollen donors were not the closest nor the cultivars with the highest number of trees in the orchard, suggesting that cross-compatibility may have a key role in determining pollen donor success. In our earlier studies, pollen tube growth and fertilization success correlated with fruit set when controlled crosses between cultivars were performed; however, some discrepancy might appear compared to paternity analyses when mother trees have a free choice among different pollen sources from cultivars growing in their surroundings.
Effect of Elevated Temperature on Tomato Post-Harvest Properties
Authors: Thole Vera , Vain Philippe , Martin Cathie
Published: November 2021

The fleshy fruit of tomato (Solanum lycopersicum) is a commodity used worldwide as a fresh or processed product. Like many crops, tomato plants and harvested fruits are susceptible to the onset of climate change. Temperature plays a key role in tomato fruit production and ripening, including softening, development of fruit colour, flavour and aroma. The combination of climate change and the drive to reduce carbon emission and energy consumption is likely to affect tomato post-harvest storage conditions. In this study, we investigated the effect of an elevated storage temperature on tomato shelf life and fungal susceptibility. A collection of 41 genotypes with low and high field performance at elevated temperature, including different growth, fruit and market types, was used to assess post-harvest performances. A temperature increase from 18–20 °C to 26 °C reduced average shelf life of fruit by 4 days ± 1 day and increased fungal susceptibility by 11% ± 5% across all genotypes. We identified tomato varieties that exhibit both favourable post-harvest fruit quality and high field performance at elevated temperature. This work contributes to efforts to enhance crop resilience by selecting for thermotolerance combined with traits suitable to maintain and improve fruit quality, shelf life and pathogen susceptibility under changing climate conditions.
Modelling and Investigation of Crack Growth for 3D-Printed Acrylonitrile Butadiene Styrene (ABS) with Various Printing Parameters and Ambient Temperatures
Authors: Alshammari Yousef Lafi A. , He Feiyang , Khan Muhammad A.
Published: November 2021

Three-dimensional (3D) printing is one of the significant industrial manufacturing methods in the modern era. Many materials are used for 3D printing; however, as the most used material in fused deposition modelling (FDM) technology, acrylonitrile butadiene styrene (ABS) offers good mechanical properties. It is perfect for making structures for industrial applications in complex environments. Three-dimensional printing parameters, including building orientation, layers thickness, and nozzle size, critically affect the crack growth in FDM structures under complex loads. Therefore, this paper used the dynamic bending vibration test to investigate their influence on fatigue crack growth (FCG) rate under dynamic loads and the Paris power law constant C and m. The paper proposed an analytical solution to determine the stress intensity factor (SIF) at the crack tip based on the measurement of structural dynamic response. The experimental results show that the lower ambient temperature, as well as increased nozzle size and layer thickness, provide a lower FCG rate. The printing orientation, which is the same as loading, also slows the crack growth. The linear regression between these parameters and Paris Law’s coefficient also proves the same conclusion.
Rheological and Morphological Properties of Oil Palm Fiber-Reinforced Thermoplastic Composites for Fused Deposition Modeling (FDM)
Authors: Ahmad Mohd Nazri , Ishak Mohamad Ridzwan , Taha Mastura Mohammad , Mustapha Faizal , Leman Zulkiflle
Published: November 2021

Fused deposition modelling (FDM) is a filament-based rapid prototyping technology that allows new composite materials to be introduced into the FDM process as long as they can be manufactured in feedstock filament form. The purpose of this research was to analyze the rheological behavior of oil palm fiber-reinforced acrylonitrile butadiene styrene (ABS) composites when used as a feedstock material, as well as to determine the best processing conditions for FDM. The composite’s shear thinning behavior was observed, and scanning electron microscopy was used to reveal its composition. The morphological result found that there was a good fiber/matrix adhesion with a 3 wt% fiber loading, as no fiber pullouts or gaps developed between the oil palm fiber and ABS. However, some pores and fiber pullouts were found with a 5 and 7 wt% fiber loading. Next, the rheological results showed that the increment of fiber content (wt%) increased the viscosity. This discovery can definitely be used in the extrusion process for making wire filament for FDM. The shear thinning effect was increased by adding 3, 5, or 7 wt% of oil palm fiber. The non-Newtonian index (n) of the composites increased as the number of shear rates increased, indicating that the fiber loading had a significant impact on the rheological behavior. As the fiber loading increased, the viscosity and shear stress values increased as well. As a result, oil fiber reinforced polymer composites can be used as a feedstock filament for FDM.
Effect of Service Temperature on Mechanical Properties of Adhesive Joints after Hygrothermal Aging
Authors: Tan Wei , Na Jingxin , Zhou Zhaofeng
Published: November 2021

Polyurethane adhesive and aluminum alloy were selected to make adhesive joints. Butt joints tested at different loading angles (0°, 45°, and 90°) using a modified Arcan fixture were selected to represent three stress states (normal stress, normal/shear combined stress, and shear stress, respectively). Firstly, the accelerated aging tests were carried out on the joints in a hygrothermal environment (80 °C/95% RH). The quasi-static tests were carried out at different temperatures (−40 °C, 20 °C, and 80 °C) for the joints after hygrothermal aging for different periods. The variation rules of the joints’ mechanical properties and failure modes with different aging levels were studied. The results show that the failure load of the joints was obviously affected by stress state and temperature. In the low-temperature test, the failure load of the joints decreased most obviously, and the BJ was the most sensitive to temperature, indicating that the failure load decreased more with the increase of the normal stress ratio in the joint. Through macroscopic and SEM analysis of the failure section, it was found that the hydrolysis reaction of polyurethane adhesive itself and the interface failure of the joints were the main reasons for the decrease of joint strength. The failure models were established to characterize the adhesive structure with different aging levels at service temperature.
Assessment of Toxicity and Biodegradability of Poly(vinyl alcohol)-Based Materials in Marine Water
Authors: Alonso-López Olalla , López-Ibáñez Sara , Beiras Ricardo
Published: November 2021

Due to the continuous rise in conventional plastic production and the deficient management of plastic waste, industry is developing alternative plastic products made of biodegradable or biobased polymers. The challenge nowadays is to create a new product that combines the advantages of conventional plastics with environmentally friendly properties. This study focuses on the assessment of the potential impact that polyvinyl alcohol (PVA)-based polymers may have once they are released into the marine environment, in terms of biodegradation in seawater (assessed by the percentage of the Theoretical Oxygen Demand, or % ThOD, of each compound) and aquatic toxicity, according to the standard toxicity test using Paracentrotus lividus larvae. We have tested three different materials: two glycerol-containing PVA based ones, and another made from pure PVA. Biodegradation of PVA under marine conditions without an acclimated inoculum seems to be negligible, and it slightly improves when the polymer is combined with glycerol, with a 5.3 and 8.4% ThOD achieved after a period of 28 days. Toxicity of pure PVA was also negligible (<1 toxic units, TU), but slightly increases when the material included glycerol (2.2 and 2.3 TU). These results may contribute to a better assessment of the behavior of PVA-based polymers in marine environments. Given the low biodegradation rates obtained for the tested compounds, PVA polymers still require further study in order to develop materials that are truly degradable in real marine scenarios.
A Review on Electrospun Nanofibers Based Advanced Applications: From Health Care to Energy Devices
Authors: Reddy Vundrala Sumedha , Tian Yilong , Zhang Chuanqi , Ye Zhen , Roy Kallol , Chinnappan Amutha , Ramakrishna Seeram , Liu Wei , Ghosh Rituparna
Published: November 2021

Electrospun nanofibers have been exploited in multidisciplinary fields with numerous applications for decades. Owing to their interconnected ultrafine fibrous structure, high surface-to-volume ratio, tortuosity, permeability, and miniaturization ability along with the benefits of their lightweight, porous nanofibrous structure, they have been extensively utilized in various research fields for decades. Electrospun nanofiber technologies have paved unprecedented advancements with new innovations and discoveries in several fields of application including energy devices and biomedical and environmental appliances. This review article focused on providing a comprehensive overview related to the recent advancements in health care and energy devices while emphasizing on the importance and uniqueness of utilizing nanofibers. A brief description regarding the effect of electrospinning techniques, setup modifications, and parameters optimization on the nanofiber morphology was also provided. The article is concluded with a short discussion on current research challenges and future perspectives.
Multifunctional, Robust, and Porous PHBV—GO/MXene Composite Membranes with Good Hydrophilicity, Antibacterial Activity, and Platelet Adsorption Performance
Authors: Wu Yuandong , Zheng Weishuang , Xiao Yinan , Du Beining , Zhang Xingru , Wen Min , Lai Chen , Huang Yi , Sheng Liyuan
Published: November 2021

The limitations of hydrophilicity, strength, antibacterial activity adsorption performance of the biobased and biocompatible polymer materials, such as polyhydroxyalkanoates (PHAs), significantly restrict their wider applications especially in medical areas. In this paper, a novel composite membrane with high antibacterial activity and platelet adsorption performance was prepared based on graphene oxide (GO), MXene and 3-hydroxybutyrate-co-hydroxyvalerate (PHBV), which are medium-chain-length-copolymers of PHA. The GO/MXene nanosheets can uniformly inset on the surface of PHBV fibre and give the PHBV—GO/MXene composite membranes superior hydrophilicity due to the presence of hydroxyl groups and terminal oxygen on the surface of nanosheets, which further provides the functional site for the free radical polymerization of ester bonds between GO/MXene and PHBV. As a result, the tensile strength, platelet adsorption, and blood coagulation time of the PHBV—GO/MXene composite membranes were remarkably increased compared with those of the pure PHBV membranes. The antibacterial rate of the PHBV—GO/MXene composite membranes against gram-positive and gram-negative bacteria can reach 97% due to the antibacterial nature of MXene. The improved strength, hydrophilicity, antibacterial activity and platelet adsorption performance suggest that PHBV—GO/MXene composite membranes might be ideal candidates for multifunctional materials for haemostatic applications.
Highly Efficient Piezoelectrets through Ultra-Soft Elastomeric Spacers
Authors: von Seggern Heinz , Zhukov Sergey , Dali Omar Ben , Hartmann Claas , Sessler Gerhard M. , Kupnik Mario
Published: November 2021

Piezoelectrets are artificial ferroelectrics that are produced from non-polar air-filled porous polymers by symmetry breaking through high-voltage-induced Paschen breakdown in air. A new strategy for three-layer polymer sandwiches is introduced by separating the electrical from the mechanical response. A 3D-printed grid of periodically spaced thermoplastic polyurethane (TPU) spacers and air channels was sandwiched between two thin fluoroethylene propylene (FEP) films. After corona charging, the air-filled sections acted as electroactive elements, while the ultra-soft TPU sections determined the mechanical stiffness. Due to the ultra-soft TPU sections, very high quasi-static (22,000 pC N−1) and dynamic (7500 pC N−1) d33 coefficients were achieved. The isothermal stability of the d33 coefficients showed a strong dependence on poling temperature. Furthermore, the thermally stimulated discharge currents revealed well-known instability of positive charge carriers in FEP, thereby offering the possibility of stabilization by high-temperature poling. The dependences of the dynamic d33 coefficient on seismic mass and acceleration showed high coefficients, even at accelerations approaching that of gravity. An advanced analytical model rationalizes the magnitude of the obtained quasi-static d33 coefficients of the suggested structure indicating a potential for further optimization.
Biodegradable PGA/PBAT Blends for 3D Printing: Material Performance and Periodic Minimal Surface Structures
Authors: Zhang Zihui , He Fengtai , Wang Bo , Zhao Yiping , Wei Zhiyong , Zhang Hao , Sang Lin
Published: November 2021

Biodegradable polymers have been rapidly developed for alleviating excessive consumption of non-degradable plastics. Additive manufacturing is also a green energy-efficiency and environment-protection technique to fabricate complicated structures. Herein, biodegradable polyesters, polyglycolic acid (PGA) and poly (butyleneadipate-co-terephthalate) (PBAT) were blended and developed into feedstock for 3D printing. Under a set of formulations, PGA/PBAT blends exhibited a tailored stiffness-toughness mechanical performance. Then, PGA/PBAT (85/15 in weight ratio) with good thermal stability and mechanical property were extruded into filaments with a uniform wire diameter. Mechanical testing clearly indicated that FDM 3D-printed exhibited comparable tensile, flexural and impact properties with injection-molded samples of PGA/PBAT (85/15). Furthermore, uniform and graded Diamond-Triply Periodic Minimal Surfaces (D-TPMS) structures were designed and successfully manufactured via the fused deposition modeling (FDM) technique. Computer tomography (CT) was employed to confirm the internal three-dimensional structures. The compressive test results showed that PGA/PBAT (85/15) D-surface structures bear better load-carrying capacity than that of neat PGA, giving an advantage of energy absorption. Additionally, typical industrial parts were manufactured with excellent dimension-stability, no-wrapping and fine quality. Collectively, biodegradable PGA/PBAT material with good printability has great potentials in application requiring stiffer structures.
Efficacy of Caffeine Treatment for Wood Protection—Influence of Wood and Fungi Species
Authors: Pánek Miloš , Borůvka Vlastimil , Nábělková Jana , Šimůnková Kristýna , Zeidler Aleš , Novák David , Černý Robert , Kobetičová Klára
Published: November 2021

In the future, we can expect increased requirements to the health and ecological integrity of biocides used for the protection of wood against bio-attacks, and it is therefore necessary to search for and thoroughly test new active substances. Caffeine has been shown to have biocidal efficacy against wood-destroying fungi, moulds and insects. The aim of the research was to determine whether the effectiveness of caffeine, as a fungicide of natural origin, is affected by a different type of treated wood. Norway spruce mature wood (Picea abies), Scots pine sapwood (Pinus sylvestris), and European beech wood (Fagus sylvatica) were tested in this work. The samples were treated using long-term dipping technology or coating (according to EN 152:2012) and then tested against selected wood-destroying brown rot fungi according to the standard EN 839:2015, wood-staining fungi according to EN 152:2012, and against mould growth according to EN 15457:2015. The penetration of caffeine solution into wood depth was also evaluated using liquid extraction chromatography, as well as the effect of the treatment used on selected physical and mechanical properties of wood. The test results showed that the type of wood used and the specific type of wood-degrading agent had a significant effect on the effectiveness of caffeine protection. The most resistant wood was the treated spruce, whereas the most susceptible to deterioration was the treated white pine and beech wood. The results of the work showed that caffeine treatment is effective against wood-destroying fungi at a concentration of 2%, and at 1% in some of the tested cases. It can be used as an ecologically acceptable short-term protection alternative against wood-staining fungi in lumber warehouses and is also partially effective against moulds. It also does not have negative effects on changes in the physical and mechanical properties of the tested wood species.
Cationic Peptide-Modified Gold Nanostars as Efficient Delivery Platform for RNA Interference Antitumor Therapy
Authors: Chen Si , Li Jiguang , Ma Xiaoyu , Liu Fan , Yan Guoping
Published: November 2021

siRNA interference therapy can silence tumor cell target genes and specifically regulate tumor cell behavior and function, which is an effective antitumor therapy. However, in somatic circulation, naked siRNAs are not only susceptible to degrade, but it is also difficult to realize the tumor cells’ internalization. Therefore, novel siRNA delivery vectors that could promote efficacy need to be developed urgently. Here, we designed high-surface gold nanostars (GNS-P) which are decorated with cationic tumor-targeting peptide as an efficient and functional siRNA delivery nanoplatform for tumor therapy. The positively charged amino acid sequence and huge surface area enabled the vector to load a large amount of siRNA, while the tumor-targeting peptide sequence and nano size enabled it to rapidly and precisely target the tumor regions for fast and effective siRNA delivery. This tumor-targeting nanoplatform, GNS-P, displayed good biocompatibility, low toxicity and an extraordinary tumor accumulation capability.
Experimental Verification of the Elastic Response in a Numeric Model of a Composite Propeller Blade with Bend Twist Deformation
Authors: Rokvam Sondre Østli , Vedvik Nils Petter , Mark Lukas , Rømcke Eivind , Ølnes Jon Schawlann , Savio Luca , Echermeyer Andreas
Published: November 2021

Adaptive composite propeller blades showing bend twist behaviour have received increasing interest from hydrodynamic and structural engineers. When exposed to periodic loading conditions, such propellers can be designed to have higher energy efficiency and emit less noise and vibration than conventional propellers. This work describes a method to produce an adaptive composite propeller blade and how a point load experiment can verify the predicted elastic response in the blade. A 600 mm-long hollow full-size blade was built and statically tested in the laboratory. Finite element modelling predicted a pitch angle change under operational load variable loads of 0.55°, a geometric change that notably compensates for the load cases. In the laboratory experiment, the blade was loaded at two points with increasing magnitude. The elastic response was measured with digital image correlation and strain gauges. Model predictions and experimental measurements showed the same deformation patterns, and the twist angle agreed within 0.01 degrees, demonstrating that such propellers can be successfully built and modelled by finite element analysis.
Mono–Material 4D Printing of Digital Shape–Memory Components
Authors: Niazy Dalia , Elsabbagh Ahmed , Ismail Mostafa R.
Published: November 2021

Dynamic shading systems in buildings help reduce solar gain. Actuated systems, which depend on renewable energy with reduced mechanical parts, further reduce building energy consumption compared to traditional interactive systems. This paper investigates stimuli-responsive polymer application in architectural products for sustainable energy consumption, complying with sustainable development goals (SDGs). The proposed research method posits that, by varying the infill percentage in a pre-determined manner inside a 3D-printed mono-material component, directionally controlled shape change can be detected due to thermal stimuli application. Thus, motion behavior can be engineered into a material. In this study, PLA+, PETG, TPU and PA 6 printed components are investigated under a thermal cycle test to identify a thermally responsive shape-memory polymer candidate that actuates within the built environment temperature range. A differential scanning calorimetry (DSC) test is carried out on TPU 95A and PA 6 to interpret the material shape response in terms of transitional temperatures. All materials tested show an anisotropic shape-change reaction in a pre-programmed manner, complying with the behavior engineered into the matter. Four-dimensional (4D)-printed PA6 shows shape-shifting behavior and total recovery to initial position within the built environment temperature range.
Identification of Potential Migrants in Polyethylene Terephthalate Samples of Ecuadorian Market
Authors: Marín-Morocho Karina , Domenek Sandra , Salazar Rómulo
Published: November 2021

Polyethylene terephthalate (PET) is the plastic packaging material most widely used to produce bottles intended for contact with food and beverages. However, PET is not inert, and therefore, some chemical compounds present in PET could migrate to food or beverages in contact, leading to safety issues. To evaluate the safety of PET samples, the identification of potential migrants is required. In this work, eight PET samples obtained from the Ecuadorian market at different phases of processing were studied using a well-known methodology based on a solvent extraction followed by gas chromatography–mass spectrometry analysis and overall migration test. Several chemical compounds were identified and categorized as lubricants (carboxylic acids with chain length of C12 to C18), plasticizers (triethyl phosphate, diethyl phthalate), thermal degradation products (p-xylene, benzaldehyde, benzoic acid), antioxidant degradation products (from Irgafos 168 and Irganox), and recycling indicator compounds (limonene, benzophenone, alkanes, and aldehydes). Additionally, overall migration experiments were performed in PET bottles, resulting in values lower than the overall migration limit (10 mg/dm2); however, the presence of some compounds identified in the samples could be related to contamination during manufacturing or to the use of recycled PET-contaminated flakes. In this context, the results obtained in this study could be of great significance to the safety evaluation of PET samples in Ecuador and would allow analyzing the PET recycling processes and avoiding contamination by PET flakes from nonfood containers.
Poly-ε-Caprolactone/Halloysite Nanotube Composites for Resorbable Scaffolds: Effect of Processing Technology on Homogeneity and Electrospinning
Authors: Józó Muriel , Várdai Róbert , Hegyesi Nóra , Móczó János , Pukánszky Béla
Published: November 2021

Polycaprolactone (PCL)/halloysite composites were prepared to compare the effect of homogenization technology on the structure and properties of the composites. Halloysite content changed from 0 to 10 vol% in six steps and homogeneity was characterized by various direct and indirect methods. The results showed that the extent of aggregation depends on technology and on halloysite content; the size and number of aggregates increase with increasing halloysite content. Melt mixing results in more homogeneous composites than the simple compression of the component powders or homogenization in solution and film casting. Homogeneity and the extent of aggregation determines all properties, including functionality. The mechanical properties of the polymer deteriorate with increasing aggregation; even stiffness depends on homogeneity. Strength and deformability decreases drastically as the number and size of aggregates increase. Not only dispersed structure, but also the physical state and crystalline structure of the polymer influence homogeneity and properties. The presence of the filler affects the preparation of electrospun fiber scaffolds as well. A part of the filler is excluded from the fibers while another part forms aggregates that complicates fiber spinning and deteriorates properties. The results indicate that spinning is easier and the quality of the fibers is better if a material homogenized previously by melt mixing is used for the production of the fibers.
Edible Biopolymers-Based Materials for Food Applications—The Eco Alternative to Conventional Synthetic Packaging
Authors: Gheorghita Puscaselu Roxana , Besliu Irina , Gutt Gheorghe
Published: November 2021

The problem of waste generated by packaging obtained from conventional synthetic materials, often multilayer, has become more and more pressing with increasing consumption. In this context, nature and humanity have suffered the most. In order to address this phenomenon, global and European organizations have launched and promoted programs and strategies. Replacing petroleum-based packaging with biopolymer packaging has proven to be a real alternative. Thus, the substitution of plastics with biodegradable, non-toxic, edible materials, which can be obtained from marine or agro-industrial waste, is of interest. In the present study, we aimed to develop natural edible materials, obtained entirely from biopolymers such as agar and sodium alginate and plasticized with glycerol and water. Designed to be used for food and food supplements packaging, they can be completely solubilized before consumption. The films were developed through a casting method and were tested in order to identify the physical, optical, and solubility properties. According to the results, the most suitable composition for use as a hydrosoluble packaging material contains agar:alginate:glycerol in a 2:1:1 ratio. The microstructure indicates a homogeneous film, with low roughness values (Rz = 12.65 ± 1.12 µm), high luminosity (92.63), above-average transmittance (T = 51.70%), and low opacity (6.30 A* mm−1). The obtained results are of interest and highlight the possibility of substituting intensely polluting materials with those based on biopolymers.
An Insight into a Sustainable Removal of Bisphenol A from Aqueous Solution by Novel Palm Kernel Shell Magnetically Induced Biochar: Synthesis, Characterization, Kinetic, and Thermodynamic Studies
Authors: Katibi Kamil Kayode , Yunos Khairul Faezah , Man Hasfalina Che , Aris Ahmad Zaharin , Mohd Nor Mohd Zuhair , Azis Rabaah Syahidah
Published: November 2021

Recently Bisphenol A (BPA) is one of the persistent trace hazardous estrogenic contaminants in the environment, that can trigger a severe threat to humans and environment even at minuscule concentrations. Thus, this work focused on the synthesis of neat and magnetic biochar (BC) as a sustainable and inexpensive adsorbent to remove BPA from aqueous environment. Novel magnetic biochar was efficiently synthesized by utilizing palm kernel shell, using ferric chloride and ferrous chloride as magnetic medium via chemical co-precipitation technique. In this experimental study, the influence of operating factors comprising contact time (20–240 min), pH (3.0–12.0), adsorbent dose (0.2–0.8 g), and starting concentrations of BPA (8.0–150 ppm) were studied in removing BPA during batch adsorption system using neat biochar and magnetic biochar. It was observed that the magnetically loaded BC demonstrates superior maximum removal efficiency of BPA with 94.2%, over the neat biochar. The functional groups (FTIR), Zeta potential, vibrating sample magnetometer (VSM), surface and textural properties (BET), surface morphology, and mineral constituents (FESEM/EDX), and chemical composition (XRD) of the adsorbents were examined. The experimental results demonstrated that the sorption isotherm and kinetics were suitably described by pseudo-second-order model and Freundlich model, respectively. By studying the adsorption mechanism, it was concluded that π-π electron acceptor–donor interaction (EAD), hydrophobic interaction, and hydrogen bond were the principal drives for the adsorption of BPA onto the neat BC and magnetic BC.
Redox/pH-Responsive Biodegradable Thiol-Hyaluronic Acid/Chitosan Charge-Reversal Nanocarriers for Triggered Drug Release
Authors: Xia Dandan , Wang Feilong , Pan Shuo , Yuan Shenpo , Liu Yunsong , Xu Yongxiang
Published: November 2021

Biodegradable nanoparticles and micelles are promising nanosystems for the targeted delivery of potent anticancer drugs. By using specialized polymers as nanocarriers, targeted drug delivery and release can be developed. We developed thiol-hyaluronic acid (HA-SH)/chitosan (CS) nanoparticles with redox/pH dual-responsiveness via electrostatic self-assembly followed by spontaneous chemical cross-linking. The nanoparticle surface charges were reversible through different HA-SH and CS mass ratios. Doxorubicin (DOX) was used as a model drug. Dual cross-linked nanoparticles with diameters of approximately 300 nm exhibited superior stability under physiological conditions compared with nanoparticles without disulfide cross-linking. DOX was loaded more efficiently into negative nanoparticles (45.7 wt%) than positive nanoparticles (14.2 wt%). Drug release from negative nanoparticles (ζ potential of approximately −20) was higher (87.8 wt%) at pH 4.5 and in the presence of 10 mM glutathione. Positive nanoparticles (ζ potential of approximately +20) showed the same trend, but the release rate was slower than that of negative nanoparticles. DOX-loaded HA-SH/CS particles were taken up by human breast cancer cells (SKBR3), and the loaded drug was released, exhibiting potential antitumor efficacy. The HA-SH/CS nanoparticles in this study were stable under physiological conditions and are promising candidates for the targeted delivery and release of anticancer drugs.
Axial Compression Behavior of Ferrocement Geopolymer HSC Columns
Authors: El-Sayed Taha Awadallah
Published: November 2021

Geopolymer concrete (GC) is a substantial sort that is created by utilizing metakaolin, ground granulated blast furnace slag (GGBS), silica fumes, fly ash, and other cementitious materials as binding ingredients. The current study concentrated on the structural behavior of the ferrocement geopolymer HSC-columns subjected to axial loading and produced using rice straw ash (RSA). The major goal of this research was to use the unique features of the ferrocement idea to manufacture members that function as columns bearing members. As they are more cost-effective and lower in weight, these designed elements can replace traditional RC members. The study also intended to reduce the cost of producing new parts by utilizing low-cost materials such as light weight expanded and welded wire meshes, polyethylene mesh (Tensar), and fiber glass mesh. For this purpose, an experimental plan was conducted and a finite element prototype with ANSYS2019-R1 was implemented. Nine geopolymer ferrocement columns of dimensions of 150 mm × 150 mm × 1600 mm with different volume-fraction and layers as well as a number of metallic and nonmetallic meshes were examined under axial compression loading until failure. The performance of the geopolymer columns was examined with consideration to the mid-span deflection, ultimate failure load, first crack load with various phases of loading, the cracking patterns, energy absorption and ductility index. Expanded or welded ferrocement geopolymer columns showed greater ultimate failure loads than the control column. Additionally, using expanded or welded columns had a considerable effect on ultimate failure loads, where the welded wire mesh exhibited almost 28.10% compared with the expanded wire mesh. Columns reinforced with one-layer of nonmetallic Tensar-mesh obtained a higher ultimate failure load than all tested columns without concrete cover spalling. The analytical and experimental results were in good agreement. The results displayed an accepted performance of the ferrocement geopolymer HSC-columns.
Wound Healing with Electrical Stimulation Technologies: A Review
Authors: Cheah Yt Jun , Buyong Muhamad Ramdzan , Mohd Yunus Mohd Heikal
Published: November 2021

Electrical stimulation (ES) is an attractive field among clinicians in the topic of wound healing, which is common yet complicated and requires multidisciplinary approaches. The conventional dressing and skin graft showed no promise on complete wound closure. These urge the need for the exploration of electrical stimulation to supplement current wound care management. This review aims to provide an overview of electrical stimulation in wound healing. The mechanism of galvanotaxis related to wound repair will be reviewed at the cellular and molecular levels. Meanwhile, different modalities of externally applied electricity mimicking a physiologic electric field will be discussed and compared in vitro, in vivo, and clinically. With the emerging of tissue engineering and regenerative medicine, the integration of electroconductive biomaterials into modern miniaturised dressing is of interest and has become possible with the advancing understanding of smart biomaterials.
Development of Antibacterial Biocomposites Based on Poly(lactic acid) with Spice Essential Oil (Pimpinella anisum) for Food Applications
Authors: Noori Negin , Khanjari Ali , Rezaeigolestani Mohammadreza , Karabagias Ioannis K. , Mokhtari Sahar
Published: November 2021

Among the main biodegradable food packaging materials, poly-lactic acid (PLA) is a commercially successful polymer used notably in the food packaging industry. In this study, active PLA films containing different percentage of anise essential oil (AE) (0, 0.5, 1 and 1.5% v/v) were developed, and characterized by physical, mechanical and antibacterial analysis. Based on physical examinations, thermal stability of PLA/AE films was greater than the neat PLA film, and the minimum water vapor permeability (WVP) was recorded for PLA/0.5AE film (1.29 × 10 11 g/m s), while maximum WVP was observed for PLA/1.5AE (2.09 × 1011 g/m s). Moreover, the lightness and yellowness of the composites were decreased by the addition of AE. For the PLA composites with 1.5% AE, the tensile strength decreased by 35% and the elongation break increased by 28.09%, comparing to the pure PLA. According to the antibacterial analysis, the minimum inhibitory concentrations of PLA/AE film were 5 to 100 mg/mL and the active composite could create visible inhibition zones of 14.2 to 19.2 mm. Furthermore, the films containing AE inhibited L. monocytogenes and V. parahaemolyticus in a concentration-dependent manner. The confirmation of the success of the incorporation of EOs into the PLA films was further evaluated using principal component analysis, where positive results were obtained. In this context, our findings suggest the significant potency of AE to be used as an antibacterial agent in active food packaging.
Design and Implementation of Integral Backstepping Sliding Mode Control for Quadrotor Trajectory Tracking
Authors: Tsai Shun-Hung , Chang Yi-Ping , Lin Hung-Yi , Chang Luh-Maan
Published: November 2021

A robust trajectory tracking control scheme for quadrotor unmanned aircraft vehicles under uncertainties is proposed herein. A tracking controller combined with the sliding mode and integral backstepping is performed for position and attitude tracking. The stability of the trajectory tracking controller of the quadrotor is investigated via Lyapunov stability analysis. By incorporating force and torque disturbances into numerical simulations, the results demonstrate the effectiveness of the proposed quadrotor trajectory controller. Finally, the experiments validate the feasibility of the proposed controller.
Positioning Religion in International Relations: The Performative, Discursive, and Relational Dimension of Religious Soft Power
Authors: Yang Zikun , Li Li
Published: November 2021

Amidst the global religious resurgence in the post-secular world, the field of international relations finds itself unwilling or unable to situate religion back to theoretical paradigms subject to the Westphalian–Enlightenment prejudice. Advocates of religion’s theoretical and empirical significance often turn to religious soft power, a burgeoning theory that gradually becomes the anchorage of discussion but still suffers from conceptual ambiguity and limited explanatory capacity. This essay endeavors to fill in this lacuna by presenting the interdisciplinary attempt to integrate soft power in IR with the three dimensions of power in sociology, which results in a typology of performative, discursive, and relational dimensions of religious soft power. The explanatory and predictive capacity of this model is tested in the empirical case of the evangelical group’s influence on US foreign policy of the post 9/11 Global War on Terror. A process-level historical account based on archival sources furthers scholars’ knowledge of transnational religious actors’ ability to seize both systematic transformations at the international level and contentious dynamics in the domestic environment, which generates a reorientation in norms, identities, and values that contributes to the outcome of foreign policy, thereby answering the un-addressed question of how religion influences domestic and international politics. The bridging of IR, sociology, and historical sociology, three fields often intertwined, suggests a future direction for not only the religious return to IR but also the overcoming of the “intellectual autism” of this discipline, which needs to be better prepared for continuous challenges of soaring populism, nationalism, and clash of civilizations in the twenty-first century.