bluuebunny/crossref_metadata_2025 huggingface dataset:
The importance of chilblains as a diagnostic clue for mild Aicardi–Goutières syndrome
Authors: Yarbrough Kevin , Danko Calida , Krol Alfons , Zonana Jonathan , Leitenberger Sabra
Published: September 2016

Aicardi–Goutières syndrome (AGS) is classically characterized by early‐onset encephalopathy. However, in some cases, the presenting symptom of concern may actually be cutaneous rather than neurological, leading to the misdiagnosis of the condition. We report the case of three teenage siblings who presented with a lifetime history of chilblain lesions, only one of whom had notable neurologic deficits. Additional findings included acrocyanosis, Raynaud's phenomenon, low‐pitch hoarse voice, headache, and arthritis. They were found to have two pathogenic sequence variants in the SAMHD1 gene: a c.602T>A substitution resulting in p.Ile201Asn protein change, previously reported as a pathogenic mutation, as well as a deletion c.719delT which has not been previously reported but results in a predicted pathogenic frame shift mutation. It is important to consider the diagnosis of AGS in patients and families with chilblain lesions in the presence of unexplained neurologic and rheumatic symptoms. © 2016 Wiley Periodicals, Inc.
Bridging the Time Gap: A Copper/Zinc Oxide/Aluminum Oxide Catalyst for Methanol Synthesis Studied under Industrially Relevant Conditions and Time Scales
Authors: Lunkenbein Thomas , Girgsdies Frank , Kandemir Timur , Thomas Nygil , Behrens Malte , Schlögl Robert , Frei Elias
Published: September 2016

Long‐term stability of catalysts is an important factor in the chemical industry. This factor is often underestimated in academic testing methods, which may lead to a time gap in the field of catalytic research. The deactivation behavior of an industrially relevant Cu/ZnO/Al2O3 catalyst for the synthesis of methanol is reported over a period of 148 days time‐on‐stream (TOS). The process was investigated by a combination of quasi in situ and ex situ analysis techniques. The results show that ZnO is the most dynamic species in the catalyst, whereas only slight changes can be observed in the Cu nanoparticles. Thus, the deactivation of this catalyst is driven by the changes in the ZnO moieties. Our findings indicate that methanol synthesis is an interfacially mediated process between Cu and ZnO.
Polymerization under Hypersaline Conditions: A Robust Route to Phenolic Polymer‐Derived Carbon Aerogels
Authors: Yu Zhi‐Long , Li Guan‐Cheng , Fechler Nina , Yang Ning , Ma Zhi‐Yuan , Wang Xin , Antonietti Markus , Yu Shu‐Hong
Published: September 2016

Polymer‐derived carbon aerogels can be obtained by direct polymerization of monomers under hypersaline conditions using inorganic salts. This allows for significantly increased mechanical robustness and avoiding special drying processes. This concept was realized by conducting the polymerization of phenol–formaldehyde (PF) in the presence of ZnCl2 salt. Afterwards, the simultaneous carbonization and foaming process conveniently converts the PF monolith into a foam‐like carbon aerogel. ZnCl2 plays a key role, serving as dehydration agent, foaming agent, and porogen. The carbon aerogels thus obtained are of very low density (25 mg cm−3), high specific surface area (1340 m2 g−1), and have a large micro‐ and mesopore volume (0.75 cm3 g−1). The carbon aerogels show very promising potential in the separation/extraction of organic pollutants and for energy storage.
Deorphaning the Macromolecular Targets of the Natural Anticancer Compound Doliculide
Authors: Schneider Gisbert , Reker Daniel , Chen Tao , Hauenstein Kurt , Schneider Petra , Altmann Karl‐Heinz
Published: September 2016

The cyclodepsipeptide doliculide is a marine natural product with strong actin‐polymerizing and anticancer activities. Evidence for doliculide acting as a potent and subtype‐selective antagonist of prostanoid E receptor 3 (EP3) is presented. Computational target prediction suggested that this membrane receptor is a likely macromolecular target and enabled immediate in vitro validation. This proof‐of‐concept study demonstrates the in silico deorphanization of phenotypic screening hits as a viable concept for future natural‐product‐inspired chemical biology and drug discovery efforts.
Proton‐Coupled Reduction of an Iron Cyanide Complex to Methane and Ammonia
Authors: Rittle Jonathan , Peters Jonas C.
Published: September 2016

Nitrogenase enzymes mediate the six‐electron reductive cleavage of cyanide to CH4 and NH3. Herein we demonstrate for the first time the liberation of CH4 and NH3 from a well‐defined iron cyanide coordination complex, [SiPiPr3]Fe(CN) (where [SiPiPr3] represents a tris(phosphine)silyl ligand), on exposure to proton and electron equivalents. [SiPiPr3]Fe(CN) additionally serves as a useful entry point to rare examples of terminally‐bound Fe(CNH) and Fe(CNH2) species that, in accord with preliminary mechanistic studies, are plausible intermediates of the cyanide reductive protonation to generate CH4 and NH3. Comparative studies with a related [SiPiPr3]Fe(CNMe2) complex suggests the possibility of multiple, competing mechanisms for cyanide activation and reduction.
Alpha‐Helical Fragaceatoxin C Nanopore Engineered for Double‐Stranded and Single‐Stranded Nucleic Acid Analysis
Authors: Wloka Carsten , Mutter Natalie Lisa , Soskine Misha , Maglia Giovanni
Published: September 2016

Nanopores are used in single‐molecule DNA analysis and sequencing. Herein, we show that Fragaceatoxin C (FraC), an α‐helical pore‐forming toxin from an actinoporin protein family, can be reconstituted in sphingomyelin‐free standard planar lipid bilayers. We engineered FraC for DNA analysis and show that the funnel‐shaped geometry allows tight wrapping around single‐stranded DNA (ssDNA), resolving between homopolymeric C, T, and A polynucleotide stretches. Remarkably, despite the 1.2 nm internal constriction of FraC, double‐stranded DNA (dsDNA) can translocate through the nanopore at high applied potentials, presumably through the deformation of the α‐helical transmembrane region of the pore. Therefore, FraC nanopores might be used in DNA sequencing and dsDNA analysis.
Growth characteristics of the endangered thick‐shelled river mussel (Unio crassus) near the northern limit of its natural range
Authors: Helama Samuli , Valovirta Ilmari , Nielsen Jan Kresten
Published: September 2016

The thick‐shelled river mussel, Unio crassus (Bivalvia: Unionoida), is one of Europe's most‐threatened mussels. Finnish populations of U. crassus lie close to the northern limit of its natural distribution. Extirpation of these populations will reduce the range of this endangered species.

Growth characteristics of U. crassus were measured in a river running through the Helsinki metropolitan area. Shell dimensions (size‐at‐age data) and annual shell growth increments were used to reconstruct growth rate and its variation during the lifespan of individual mussels and to investigate the relationship between growth rate and longevity (age‐at‐death).

Reconstructed growth rates compared well with size‐at‐age data conventionally used to study individual growth in natural populations, and fitted von Bertalanffy growth functions very well. Based on the same function, reconstruction and size‐at‐age methods resulted in similar estimates of growth rate.

Shell weight explained the body size more reliably than age, suggesting that growth rate varied significantly among individuals. Comparison of individual growth histories revealed a negative correlation between age‐at‐death and growth rate, i.e. slow‐growing mussels lived longer, and vice versa.

In comparison with populations from central and southern Europe, U. crassus populations in the north of its range grew more slowly but lived longer, a phenomenon most likely explained by latitudinal changes in ambient temperature.

Although northern populations are expected to benefit from a relatively high number of reproductive periods and lower juvenile mortality, the individuals studied here died earlier and suffered higher mortality than expected and an elevated conservative status is identified. Any management programme should take into account the life‐history traits essential to the recognition of management units of U. crassus.

Copyright © 2016 John Wiley & Sons, Ltd.
The social responsiveness scale in relation to DSM IV and DSM5 ASD in Korean children
Authors: Cheon Keun‐Ah , Park Jee‐In , Koh Yun‐Joo , Song Jungeun , Hong Hyun‐Joo , Kim Young‐Kee , Lim Eun‐Chung , Kwon Hojang , Ha Mina , Lim Myung‐Ho , Paik Ki‐Chung , Constantino John N. , Leventhal Bennett , Kim Young Shin
Published: September 2016

The Social Responsiveness Scale (SRS) is an autism rating scales in widespread use, with over 20 official foreign language translations. It has proven highly feasible for quantitative ascertainment of autistic social impairment in public health settings, however, little is known about the validity of the reinforcement in Asia populations or in references to DSM5. The current study aims to evaluate psychometric properties and cross‐cultural aspects of the SRS‐Korean version (K‐SRS).The study subjects were ascertained from three samples: a general sample from 3 regular education elementary schools (n=790), a clinical sample (n=154) of 6–12‐year‐olds from four psychiatric clinics, and an epidemiological sample of children with ASD, diagnosed using both DSM IV PDD, DSM5 ASD and SCD criteria (n=151). Their parents completed the K‐SRS and the Autism Spectrum Screening Questionnaire(ASSQ). Descriptive statistics, correlation analyses and principal components analysis (PCA) were performed on the total population. Mean total scores on the K‐SRS differed significantly between the three samples. ASSQ scores were significantly correlated with the K‐SRS T‐scores. PCA suggested a one‐factor solution for the total population.Our results indicate that the K‐SRS exhibits adequate reliability and validity for measuring ASD symptoms in Korean children with DSM IV PDD and DSM5 ASD. Our findings further suggest that it is difficult to distinguish SCD from other child psychiatric conditions using the K‐SRS.This is the first study to examine the relationship between the SRS subscales and DSM5‐based clinical diagnoses. This study provides cross‐cultural confirmation of the factor structure for ASD symptoms and traits measured by the SRS. Autism Res 2016, 9: 970–980. © 2016 International Society for Autism Research, Wiley Periodicals, Inc.
Querkraftversuche an Spannbetonträgern mit carbontextilbewehrter Spritzmörtelverstärkung unter zyklischer Beanspruchung
Authors: Herbrand Martin , Claßen Martin , Hegger Josef
Published: September 2016

Viele Autobahnbrücken in Deutschland weisen rechnerische Defizite bezüglich der Querkrafttragfähigkeit auf. Dies betrifft sowohl den Nachweis unter statischen als auch unter zyklischen Lasten. Aufgrund des zusätzlich schlechten Zustands vieler Brücken werden daher zukünftig vermehrt Verstärkungsmaßnahmen erforderlich werden. Zur Querkraftverstärkung von Brücken existieren unterschiedliche Verfahren mit individuellen Vor‐ und Nachteilen. In zwei am Institut für Massivbau der RWTH Aachen durchgeführten Tastversuchen an Spannbetonträgern wurde die Wirksamkeit einer carbontextilbewehrten Spritzmörtelverstärkung auf den Stegen auf die Querkrafttragfähigkeit untersucht. Die Ergebnisse wurden mit Ermüdungsversuchen an zwei baugleichen, nicht verstärkten Trägern verglichen. Es stellte sich heraus, dass die Verstärkungsmaßnahme zu einem deutlich höheren Querkrafttrag widerstand, sowohl hinsichtlich der zyklischen Belastung als auch der statischen Resttragfähigkeit, führt.
Entwicklung von Hochleistungsaerogelbeton
Authors: Schnellenbach‐Held Martina , Welsch Torsten , Fickler Silvia , Milow Barbara , Ratke Lorenz
Published: September 2016

Aufgrund der Anforderungen an den Wärmeschutz ist die Ausführung einschaliger Außenwände aus Normalbeton bereits seit einigen Jahrzehnten nicht mehr praktikabel. Um den bauphysikalischen Anforderungen gerecht zu werden, sind in der Regel zusätzliche Maßnahmen wie die Anbringung von Wärmedämmverbundsystemen oder die Ausführung als zweischalige Wandkonstruktion mit Kerndämmung erforderlich, aus denen gestalterische, konstruktive oder wirtschaftliche Nachteile resultieren können. Bisherige Versuche, einschalige Außenwände aus Leichtbetonen herzustellen, erfordern wegen der verhältnismäßig geringen Druckfestigkeiten oder der im Vergleich zu anderen Außenwandkonstruktionen noch immer höheren Wärmeleitfähigkeiten stets sehr große Wanddicken. Das Institut für Massivbau (IfM) der Universität Duisburg‐Essen hat in Zusammenarbeit mit dem Institut für Werkstoff‐Forschung des Deutschen Zentrums für Luft und Raumfahrt (DLR) durch Einbettung von Quarzglas‐Aerogelgranulat in UHPC‐Matrizen einen Hochleistungsaerogelbeton entwickelt, der ein sehr günstiges Verhältnis zwischen Druckfestigkeit und Wärmeleitfähigkeit aufweist [1]. Nachfolgend werden die mechanischen und bauphysikalischen Eigenschaften des neuen Werkstoffs vorgestellt.
Synthesis, photophysics, electrochemistry, thermal stability and electroluminescent performances of a new europium complex with bis(β‐diketone) ligand containing carbazole group
Authors: Liu Jian , Liang Quan‐Bin , Wu Hong‐Bin
Published: September 2016

We synthesized a new europium complex [Eu(ecbpd)3(Phen)] with bis(β‐diketone) ligand containing a carbazole group, in which ecbpd and Phen are dehydro‐3,3′‐(9‐ethyl‐9H‐carbazole‐3,6‐diyl)bis(1‐phenylpropane‐1,3‐dione) and 1,10‐phenanthroline, respectively. Its UV/vis and photoluminescent spectra, quantum yield, luminescence lifetime, electrochemistry, thermal stability and electroluminescent performances were studied. This europium complex showed low efficiency luminescence, which is probably due to the mismatching energy levels of its ligand and Eu3+, as well as the double Eu3+ core resonance.
Significant difference in active metabolite levels of ginseng in humans consuming Asian or Western diet: The link with enteric microbiota
Authors: Wan Jin‐Yi , Wang Chong‐Zhi , Zhang Qi‐Hui , Liu Zhi , Musch Mark W. , Bissonnette Marc , Chang Eugene B. , Li Ping , Qi Lian‐Wen , Yuan Chun‐Su
Published: September 2016

After ingestion of ginseng, the bioavailability of its parent compounds is low and enteric microbiota plays an important role in parent compound biotransformation to their metabolites. Diet type can influence the enteric microbiota profile. When human subjects on different diets ingest ginseng, their different gut microbiota profiles may influence the metabolism of ginseng parent compounds. In this study, the effects of different diet type on gut microbiota metabolism of American ginseng saponins were investigated. We recruited six healthy adults who regularly consumed different diet types. These subjects received 7 days' oral American ginseng, and their biological samples were collected for LC‐Q‐TOF‐MS analysis. We observed significant ginsenoside Rb1 (a major parent compound) and compound K (a major active metabolite) level differences in the samples from the subjects consuming different diets. Subjects on an Asian diet had much higher Rb1 levels but much lower compound K levels compared with those on a Western diet. Since compound K possesses much better cancer chemoprevention potential, our data suggested that consumers on a Western diet should obtain better cancer prevention effects with American ginseng intake compared with those on an Asian diet. Ginseng compound levels could be enhanced or reduced via gut microbiota manipulation for clinical utility.
Molecular genetic improvements of cyanobacteria to enhance the industrial potential of the microbe: A review
Authors: Johnson Tylor J. , Gibbons Jaimie L. , Gu Liping , Zhou Ruanbao , Gibbons William R.
Published: September 2016

The rapid increase in worldwide population coupled with the increasing demand for fossil fuels has led to an increased urgency to develop sustainable sources of energy and chemicals from renewable resources. Using microorganisms to produce high‐value chemicals and next‐generation biofuels is one sustainable option and is the focus of much current research. Cyanobacteria are ideal platform organisms for chemical and biofuel production because they can be genetically engineered to produce a broad range of products directly from CO2, H2O, and sunlight, and require minimal nutrient inputs. The purpose of this review is to provide an overview on advances that have been or could be made to improve strains of cyanobacteria for industrial purposes. First, the benefits of using cyanobacteria as a platform for chemical and biofuel production are discussed. Next, an overview of cyanobacterial strain improvements by genetic engineering is provided. Finally, mutagenesis techniques to improve the industrial potential of cyanobacteria are described. Along with providing an overview on various areas of research that are currently being investigated to improve the industrial potential of cyanobacteria, this review aims to elucidate potential targets for future research involving cyanobacteria as an industrial microorganism. © 2016 American Institute of Chemical Engineers Biotechnol. Prog., 32:1357–1371, 2016
Antimetastatic activity of novel ruthenium (III) pyridine complexes
Authors: Gu Liwei , Li Xiaodong , Ran Qingsen , Kang Chen , Lee Canghai , Shen Jianying
Published: September 2016

Ruthenium‐based complexes have emerged as promising anticancer, especially antimetastatic agents. Among them, NAMI‐A (trans‐[Ru(III)Cl4 (DMSO)(Im)][ImH], Im = imidazole, DMSO = dimethyl sulfoxide) was well studied. In this study, we studied the antimetastatic activities of two novel NAMI‐A derivatives containing pyridine, G26b and G94a, using cultured cells and tumor‐bearing mice. Same to NAMI‐A, these two complexes displayed little direct cytotoxicity to the cancer cells in vitro and in vivo, but they, especially G26b, significantly reduced the occurrence and development of lung metastases in mice bearing the 4T1 mammary carcinoma. In vitro, these two complexes displayed significant suppressive effect on invasion and migration of cells and tube formation of human umbilical vein endothelial cell, to the same extent of NAMI‐A. The transcription of important molecules involved in metastasis, matrix metalloproteinase 2 and 9 (MMP‐2 and ‐9), and vascular endothelial growth factor, was suppressed by the two complexes, as well as NAMI‐A. Plasma atomic emission spectrometer showed G26b had a longer Ru‐elimination time in lung, which may be a reason for better antimetastatic effect of G26b than NAMI‐A. Our results have demonstrated that G26b is a more effective antimetastatic agent than NAMI‐A.
Reconstruction of massive full‐thickness abdominal wall defect: successful treatment with nonabsorbable mesh, negative pressure wound therapy, and split‐skin grafting
Authors: Aydin Dogu , Paulsen Ida Felbo , Bentzen Vibeke Egerup , Asadzadeh Sami , Hölmich Lisbet Rosenkrantz
Published: September 2016

Key Clinical Message

We demonstrate that it is possible to use a nonabsorbable mesh for abdominal wall reconstruction after total wound rupture and successfully split‐skin graft directly on the mesh. Sufficient granulation tissue formation prior to skin grafting was obtained with long‐term use of negative pressure wound therapy (NPWT).
Partial splenectomy for a giant epidermoid cyst of the spleen
Authors: Valverde Martinez Amparo , Roldan Ortiz Susana , Fornell Ariza Mercedes , Castro Santiago Maria Jesús
Published: September 2016

Key Clinical Message

The splenic epidermoid cysts are rare benign tumors, and a definitive treatment remains unclear. Although some spleen‐preserving approaches have been reportedly used, splenic cyst recurrence usually occurs in true cyst cases, wherein the cyst is incompletely removed. In our case, partial splenectomy was performed and the giant cyst was completely removed.
Marked ST‐segment elevation during permanent pacemaker implantation
Authors: Tobushi Tomoyuki , Kashihara Soichiro , Kadokami Toshiaki
Published: September 2016

Key Clinical Message

Some acute complications are known during permanent pacemaker implantation such as pneumothorax, lead perforation, lead dislodgement, and hemorrhage. ST‐segment elevation in electrocardiogram during implantation is rare, but it might indicate critical complication like myocardial ischemia or ventricular perforation. Physicians should pay attention about ST‐segment change during pacemaker implantation.
Ruthenium Complexes of 2,2′‐Bipyridine‐6,6′‐diphosphonate Ligands for Water Oxidation
Authors: Kamdar Jayneil M. , Marelius David C. , Moore Curtis E. , Rheingold Arnold L. , Smith Diane K. , Grotjahn Douglas B.
Published: September 2016

Two novel ruthenium complexes, [Ru(2,2′‐bipyridine‐6,6′‐diphosphonato)(pic)2] (2) (pic=4‐picoline) and [Ru(6,6′‐diisopropyl‐2,2′‐bipyridine‐6,6′‐diphosphonato)(pic)2] (3) bearing phosphonate groups have been synthesized and characterized by NMR spectroscopy, elemental analyses, X‐ray crystallography, cyclic voltammetry, and UV/Vis spectroscopy. Both complexes show catalytic water oxidation activity by electrochemistry. At pH 7, the RuII/III redox couple of 2 is observed at a lower potential than that of 3, yet significantly, 3 oxidizes water at a lower onset potential. At pH 1 however, 2 and 3 have comparable catalytic reactivity using sacrificial oxidant CeIV. We propose that water oxidation activities of 2 and 3 are influenced by overall charges. For example, in oxidizing from RuII to RuIII at pH 7, 2 acquires a −1 overall charge whereas 3 acquires a +1 charge. Charge‐dictated electrostatic effects may govern binding of a water molecule to the metal site.
Bicatalytic Multistep Reactions En Route to the One‐Pot Total Synthesis of Complex Molecules: Easy Access to Chromene and 1,2‐Dihydroquinoline Derivatives from Simple Substrates
Authors: Giorgi Pascal D. , Miedziak Peter J. , Edwards Jennifer K. , Hutchings Graham J. , Antoniotti Sylvain
Published: September 2016

By combining nanocatalysis with base catalysis, a novel one‐pot multistep process was found for the synthesis of substituted heterocycles of biological relevance from simple substrates. The process is based on the initial Au/O2 oxidation of allylic alcohols, which is followed by base‐catalyzed tandem hetero‐Michael/aldolization/crotonization with ortho‐hydroxy‐ or ortho‐aminobenzaldehydes. The flexibility of the reaction even allowed the benzaldehyde partner to be prepared in situ in an example of a one‐pot/five‐step process.
Computational Study of the Palladium‐Catalyzed Carbonylative Synthesis of Aromatic Acid Chlorides: The Synergistic Effect of PtBu3 and CO on Reductive Elimination
Authors: Quesnel Jeffrey S. , Moncho Salvador , Ylijoki Kai E. O. , Torres Gerardo Martin , Brothers Edward N. , Bengali Ashfaq A. , Arndtsen Bruce A.
Published: September 2016

We describe herein computational studies on the unusual ability of Pd(PtBu3)2 to catalyze formation of highly reactive acid chlorides from aryl halides and carbon monoxide. These show a synergistic role of carbon monoxide in concert with the large cone angle PtBu3 that dramatically lowers the barrier to reductive elimination. The tertiary structure of the phosphine is found to be critical in allowing CO association and the generation of a high energy, four coordinate (CO)(PR3)Pd(COAr)Cl intermediate. The stability of this complex, and the barrier to elimination, is highly dependent upon phosphine structure, with the tertiary steric bulk of PtBu3 favoring product formation over other ligands. These data suggest that even difficult reductive eliminations can be rapid with CO association and ligand manipulation. This study also represents the first detailed exploration of all the steps involved in palladium‐catalyzed carbonylation reactions with simple phosphine ligands, including the key rate‐determining steps and palladium(0) catalyst resting state in carbonylations.
Enantioselective Direct Alkynylation of Ketones Catalyzed by Chiral CCN Pincer RhIII Complexes
Authors: Ito Jun‐ichi , Ubukata Shino , Muraoka Shun , Nishiyama Hisao
Published: September 2016

A direct asymmetric alkynylation of ketones with new chiral CCN Rh catalysts containing N‐heterocyclic carbene and oxazoline hybrid ligands is described. The catalytic reaction of fluoroalkyl‐substituted ketones, ArCOCF2X (X=F, Cl, H), with aromatic and aliphatic alkynes yielded the corresponding chiral propargyl alcohols with high enantioselectivity. Control and kinetic experiments suggested a bis(alkynyl) Rh intermediate as the active species for the C−C bond‐forming step.
Synthesis of Cycloparaphenylenes Bearing Furan‐2,5‐diyl or 2,2’‐Bifuran‐5,5’‐diyl Units in the Macrocyclic Structures
Authors: Farajidizaji Behzad , Thakellapalli Haresh , Li Shuangjiang , Huang Changfeng , Baughman Notashia N. , Akhmedov Novruz G. , Popp Brian V. , Petersen Jeffrey L. , Wang Kung K.
Published: September 2016

Synthetic pathways to furan‐containing cycloparaphenylenes (CPPs) as molecular nanohoops bearing 10, 12, and 15 aromatic units including furan‐2,5‐diyl or 2,2’‐bifuran‐5,5’‐diyl units have been developed. The X‐ray structures of a partially hydrogenated bifuran‐containing CPP precursor and the corresponding fully aromatized bifuran‐containing CPP were obtained to allow the determination of their conformational arrangements in the crystal lattice. The optical and electrochemical properties of the furan‐containing CPPs were investigated.
Cobalt(III)‐Catalyzed Intramolecular Cross‐Dehydrogenative C−H/X−H Coupling: Efficient Synthesis of Indoles and Benzofurans
Authors: Ghorai Jayanta , Reddy Angula Chandra Shekar , Anbarasan Pazhamalai
Published: September 2016

An efficient cobalt(III)‐catalyzed intramolecular cross‐dehydrogenative C−H/N−H coupling of ortho‐alkenylanilines has been developed utilizing O2 as a terminal oxidant. The developed reaction tolerates various reactive functional groups and allows the synthesis of diverse indole derivatives in good to excellent yields. The method was successfully extended to the synthesis of benzofurans through the intramolecular cross‐dehydrogenative C−H/O−H coupling of ortho‐alkenylphenols.
Exceptionally High Rates of Biological Hydrogen Production by Biomimetic In Vitro Synthetic Enzymatic Pathways
Authors: Kim Eui‐Jin , Wu Chang‐Hao , Adams Michael W. W. , Zhang Y.‐H. Percival
Published: September 2016

Hydrogen production by water splitting energized by biomass sugars is one of the most promising technologies for distributed green H2 production. Direct H2 generation from NADPH, catalysed by an NADPH‐dependent, soluble [NiFe]‐hydrogenase (SH1) is thermodynamically unfavourable, resulting in slow volumetric productivity. We designed the biomimetic electron transport chain from NADPH to H2 by the introduction of an oxygen‐insensitive electron mediator benzyl viologen (BV) and an enzyme (NADPH rubredoxin oxidoreductase, NROR), catalysing electron transport between NADPH and BV. The H2 generation rates using this biomimetic chain increased by approximately five‐fold compared to those catalysed only by SH1. The peak volumetric H2 productivity via the in vitro enzymatic pathway comprised of hyperthermophilic glucose 6‐phosphate dehydrogenase, 6‐phosphogluconolactonase, and 6‐phosphogluconate dehydrogenase, NROR, and SH1 was 310 mmol H2/L h−1, the highest rate yet reported. The concept of biomimetic electron transport chains could be applied to both in vitro and in vivo H2 production biosystems and artificial photosynthesis.
ChemInform Abstract: Large‐Scale Synthesis of Highly Luminescent Perovskite‐Related CsPb2Br5 Nanoplatelets and Their Fast Anion Exchange.
Authors: Wang Kun‐Hua , Wu Liang , Li Lei , Yao Hong‐Bin , Qian Hai‐Sheng , Yu Shu‐Hong
Published: September 2016

Highly luminescent CsPb2Br5 nanoplatelets are prepared by a scalable precipitation reaction from mixtures of PbBr2, CsBr, hexylammonium bromide, DMF, and toluene (yield given in g).
ChemInform Abstract: BaCu2Sn(S,Se)4: Earth‐Abundant Chalcogenides for Thin‐Film Photovoltaics.
Authors: Shin Donghyeop , Saparov Bayrammurad , Zhu Tong , Huhn William P. , Blum Volker , Mitzi David B.
Published: September 2016

Polycrystalline BaCu2SnSexS4‐x (x = 0, 1, 2, 3, 4) samples are prepared by solid state reaction of stoichiometric amounts of BaS, SnS, CuS, BaSe, SnSe, and CuSe (evacuated quartz tubes, 650 °C10—15 h).
ChemInform Abstract: Combining Optimized Particle Morphology with a Niobium‐Based Coating for Long Cycling‐Life, High‐Voltage Lithium‐Ion Batteries.
Authors: Gabrielli Giulio , Axmann Peter , Diemant Thomas , Behm Rolf Juergen , Wohlfahrt‐Mehrens Margret
Published: September 2016

Morphologically tailored LiNi0.5Mn1.5O4 particles (obtained by a continuous co‐precipitation synthesis) are coated with a LiNbO3 film.
ChemInform Abstract: Scandium‐Substituted Na3Zr2(SiO4)2(PO4) Prepared by a Solution‐Assisted Solid‐State Reaction Method as Sodium‐Ion Conductors.
Authors: Ma Qianli , Guin Marie , Naqash Sahir , Tsai Chih‐Long , Tietz Frank , Guillon Olivier
Published: September 2016

Polycrystalline Na3+xScxZr2‐x(SiO4)2 (PO4) (NSZSPx, x = 0—0.6) are fabricated on a laboratory scale (10 g—1 kg) by precipitation from stoichiometric aqueous solutions of NaNO3, Sc2O3, ZrO(NO3)2, Si(O‐Ac)4, and NH4H2PO4 followed by calcination (800 °C, 3 h), ball milling (2 d), and final sintering (1250—1300 °C, 5 h).
ChemInform Abstract: [Ni(OH)3W6O18 (OCH2)3CCH2OH]4‐: The First Tris‐Functionalized Anderson‐Type Heteropolytungstate.
Authors: Gumerova Nadiia I. , Roller Alexander , Rompel Annette
Published: September 2016

The title compound, Na2(Me4N)2 [Ni(OH)3W6O18 (OCH2)3CCH2OH]·9H2O is synthesized from an aqueous solution of Na2WO4, Ni(NO3)2, and HNO3 (pH 6.5, 25 °C, 10 d) followed by addition of C(CH2‐OH)4 (reflux, 80 °C, 5 h), and Me4NCl (55% yield).
ChemInform Abstract: Difluorocarbene Addition to Alkenes and Alkynes in Continuous Flow.
Authors: Rulliere Pauline , Cyr Patrick , Charette Andre B.
Published: September 2016

A scalable difluorocyclopropanation of a broad range of alkenes is developed, including alkyl and aryl 1‐substituted, 1,1 and 1,2‐disubstituted as well as trisubstituted derivatives.
ChemInform Abstract: Direct Perfluoroalkylthiolation of Few Chalcogenols.
Authors: Glenadel Quentin , Billard Thierry
Published: September 2016

The reactivity of fluoroalkylsulfenamide homologs with chalcogenols is studied which furnishes fluoroalkylthiochalcogenides.
ChemInform Abstract: Trifluoroethylation of Alkynes: Synthesis of Allylic‐CF3 Compounds by Visible‐Light Photocatalysis.
Authors: Roh Geum‐bee , Iqbal Naeem , Cho Eun Jin
Published: September 2016

Two types of allylic trifluoromethylated compounds are synthesized.
ChemInform Abstract: N‐Heterocyclic Carbene‐Based Microporous Organic Polymer Supported Palladium Catalyst for Carbon—Carbon Coupling Reaction.
Authors: Wang Chang‐An , Li Yan‐Wei , Hou Xian‐Ming , Han Yin‐Feng , Nie Kun , Zhang Jian‐Ping
Published: September 2016

Highly dispersed Pd(0) nanoparticles are successfully immobilized into stable N‐heterocyclic carbene‐based microporous organic polymer via a simple post‐treatment.
ChemInform Abstract: 2‐(Phenylseleno)ethanesulfon‐amide as a Novel Protecting Group for Aniline That Can Be Deprotected by a Radical Reaction.
Authors: Kihara Nobuhiro , Mitsuhashi Yuji , Sato Makoto , Hirose Shun‐ichi , Goudo Erika , Uzawa Yoshinori , Shirai Natsumi , Hamamoto Sari , Iwasaki Ryo , Fujioka Akane
Published: September 2016

A novel sulfonamide, 2‐(phenylseleno) ethanesulfonamide as an effective protecting group for aniline derivatives is reported.
ChemInform Abstract: Grignard Reactions in Cyclopentyl Methyl Ether.
Authors: Kobayashi Shoji , Shibukawa Keisuke , Miyaguchi Yuta , Masuyama Araki
Published: September 2016

A number of Grignard reagents are prepared as homogeneous solutions in cyclopentyl methyl ether.
ChemInform Abstract: Catalytic One‐Pot Oxetane to Carbamate Conversions: Formal Synthesis of Drug Relevant Molecules.
Authors: Guo Wusheng , Laserna Victor , Rintjema Jeroen , Kleij Arjan W.
Published: September 2016

A new method for the formation of highly functionalized carbamates based on the coupling of oxetanes, primary/secondary amines, and CO2 in the presence of an Al‐based catalyst is reported.
ChemInform Abstract: Direct Decarboxylative Alkynylation of α,α‐Difluoroarylacetic Acids under Transition Metal‐Free Conditions.
Authors: Li Xiang , Li Siyu , Sun Suyan , Yang Fan , Zhu Weiguo , Zhu Yu , Wu Yusheng , Wu Yangjie
Published: September 2016

The decarboxylative coupling of the title acids with ethynylbenziodoxolone reagents in the presence of K2S2O8 as oxidant is described.
ChemInform Abstract: Copper‐Mediated Trifluoromethylation of Diaryliodonium Salts with Difluoromethyltriflate.
Authors: Yang Jing‐Yun , Xu Xiu‐Hua , Qing Feng‐Ling
Published: September 2016

affording trifluoromethylated arenes in short reaction time (5 min)
ChemInform Abstract: A General and Efficient Pd‐Catalyzed Rapid 2‐Fluoroethoxylation of Bromo‐Chalcones.
Authors: Rangarajan T. M. , Devi Kavita , Verma Akhilesh K. , Singh Rishi Pal , Singh Raj Pal
Published: September 2016

Two of six investigated ligands efficiently support the 2‐fluoroethoxylation of bromochalcones.
ChemInform Abstract: FeCl3‐Silica: A Green Approach for the Synthesis of Nitriles from Oximes.
Authors: Ghosh Pranab , Pariyar Gyan Chandra , Saha Bittu , Subba Raju
Published: September 2016

A solvent‐free and environmentally benign protocol for the single‐step formation of nitriles (II) from aldoximes (I) using FeCl3‐silica medium is given.
ChemInform Abstract: Radical—Radical Cross‐Coupling for C—S Bond Formation.
Authors: Huang Zhiliang , Zhang Dongchao , Qi Xiaotian , Yan Zhiyuan , Wang Mengfan , Yan Haiming , Lei Aiwen
Published: September 2016

The preliminary mechanism of this reaction is revealed by radical‐trapping experiments, DFT calculations and kinetics, indicating that the C—S bond is formed through cross‐coupling of a thiyl radical and an aryl radical cation.
ChemInform Abstract: Synthesis of β‐Hydroxysulfones from Sulfonyl Chlorides and Alkenes Utilizing Visible Light Photocatalytic Sequences.
Authors: Pagire Santosh K. , Paria Suva , Reiser Oliver
Published: September 2016

The visible light mediated atom transfer radical addition between alkenes and sulfonyl chlorides gives β‐hydroxysulfones in high yields.
ChemInform Abstract: A General and Mild Copper(I)‐Catalyzed Three‐Component Reaction of Cyanamides, Amines, and Diaryliodonium Triflates
Authors: Li Jihui , Wang Hongxing , Hou Yifeng , Yu Weiguang , Xu Shuying , Zhang Yucang
Published: September 2016

to give guanidines in good yields
ChemInform Abstract: Ligand‐ and Base‐Free Access to Diverse Biaryls by the Reductive Coupling of Diaryliodonium Salts.
Authors: Arun V. , Reddy P. O. Venkataramana , Pilania Meenakshi , Kumar Dalip
Published: September 2016

A broad spectrum of synthetically important biaryl structures is readily available under conditions A) starting from symmetrical or unsymmetrical iodonium triflates.
ChemInform Abstract: Practical Synthesis of β‐Isothiocyanato Ketones from Chalcones.
Authors: Fesenko Anastasia A. , Solovyev Pavel A. , Shutalev Anatoly D.
Published: September 2016

based on the reaction of chalcones with thiocyanic acid, generated in situ from ammonium thiocyanate with dilute sulfuric acid
ChemInform Abstract: Palladium‐Catalyzed Tandem Reaction of Alkyne‐Based Aryl Iodides and Salicyl N‐Tosylhydrazones to Construct the Spiro[benzofuran‐3,2′‐chromene] Skeleton.
Authors: Shang Xue Song , Li Nian Tai , Li Deng Yuan , Liu Pei Nian
Published: September 2016

Three new bonds are generated in one step by the combination of an alkyne‐based 5‐exo‐dig cyclization with a Pd(II) carbene migratory insertion and an intramolecular cyclization.
ChemInform Abstract: Enantioselective Synthesis of Spirocyclic Tetrahydrothiophene Derivatives Bearing a Benzofuran‐3(2H)‐one Scaffold. Unusual Supramolecular Crystal Structure with High Z′.
Authors: Kowalczyk Dorota , Wojciechowski Jakub , Albrecht Lukasz
Published: September 2016

An efficient and enantioselective approach to spirocyclic tetrahydrothiophene derivatives bearing a benzofuran‐3(2H)‐one scaffold is developed which utilizes 2‐arylidenebenzofuran‐3(2H)‐ones and 2‐thioacetaldehyde, generated in situ from 1,4‐dithiane‐2,5‐diol, as starting materials and proceeds in a cascade manner involving a thio‐Michael‐aldol reaction sequence.
ChemInform Abstract: From Heteroaromatic Acids and Imines to Azaspirocycles: Stereoselective Synthesis and 3D Shape Analysis.
Authors: Chambers Sarah J. , Coulthard Graeme , Unsworth William P. , O'Brien Peter , Taylor Richard J. K.
Published: September 2016

Starting from acetic acid substituted indole, azaindole as well as pyrrole derivatives and cyclic as well as acyclic imines a broad range of spiropolycycles is prepared.
ChemInform Abstract: Lewis Base and Broensted Base Dual‐Catalyzed Formal [4 + 3] Cycloaddition Reaction: Synthesis of Aza‐Spirocycloheptane Oxindole.
Authors: Liu Jin‐Yu , Lu Hong , Li Chen‐Guang , Liang Yong‐Min , Xu Peng‐Fei
Published: September 2016

A practical approach for the [4 + 3] cycloadditon of Morita—Baylis—Hillman carbonates and N‐(o‐chloromethyl)aryl amides is developed to give aza‐spirocycloheptane oxindoles in moderate to high yields.
ChemInform Abstract: A Novel Strategy for the Synthesis of Thermally Stable and Apoptosis‐Inducing 2,3‐Dihydroazetes.
Authors: Smetanin Ilia A. , Novikov Mikhail S. , Agafonova Anastasiya V. , Rostovskii Nikolai V. , Khlebnikov Alexander F. , Kudryavtsev Igor V. , Terpilowski Maxim A. , Serebriakova Maria K. , Trulioff Andrey S. , Goncharov Nikolay V.
Published: September 2016

The reaction of a diazoacetate‐derived rhodium carbenoid with azirines or isoxazoles followed by a cyclization‐hydrodebromination cascade provides dihydroazetes via formation of 2‐azabuta‐l,3‐dienes.
ChemInform Abstract: Asymmetric Conjugate Addition of Benzofuran‐2‐ones to Alkyl 2‐Phthalimidoacrylates: Modeling Structure—Stereoselectivity Relationships with Steric and Electronic Parameters.
Authors: Yang Chen , Zhang En‐Ge , Li Xin , Cheng Jin‐Pei
Published: September 2016

The 3,5‐bis(trifluoromethyl)benzyl substituted compound (THU) and the analogous methyl derivative are found to be suitable catalysts for the Michael addition of 3‐substituted benzofurans and alkyl 2‐phthalimidoacrylates.
ChemInform Abstract: Synthesis of 2‐Aryl‐Substituted Indole‐3‐acetic Acid Derivatives via Intramolecular Imino‐Stetter Reaction of Aldimines with Cyanide.
Authors: Lee Seong Jong , Seo Hong‐Ahn , Cheon Cheol‐Hong
Published: September 2016

A general method to generate umpolung of aldimines with cyanide is developed via the addition of cyanide to aldimines followed by a proton transfer from the carbon to the nitrogen atom in the resulting cyanide adducts.
ChemInform Abstract: Cu‐Catalyzed Intramolecular Amidation of Unactivated C(sp3)—H Bonds to Synthesize N‐Substituted Indolines.
Authors: Pan Fei , Wu Bin , Shi Zhang‐Jie
Published: September 2016

The reaction tolerates various functional groups.
ChemInform Abstract: Silica‐Supported Molybdic Acid: Preparation, Characterization, and Its Catalytic Application in Synthesis of Pyranocoumarins.
Authors: Karami Bahador , Kiani Mahtab
Published: September 2016

Silica‐supported molybdic acid appears to be a novel, recyclable and safe catalyst for the three‐component condensation of 4‐hydroxycoumarin with aldehydes and malononitrile furnishing pyranocoumarins (IV) (14 examples) in high yield.
ChemInform Abstract: Enantioselective Synthesis of Isoquinolines: Merging Chiral‐Phosphine and Gold Catalysis.
Authors: Gao Yu‐Ning , Shi Feng‐Chen , Xu Qin , Shi Min
Published: September 2016

This highly enantioselective synthesis of dihydroisoquinoline derivatives from aromatic sulfonated imines tethered with an alkyne moiety, through a one‐pot asymmetric relay catalysis of chiral‐phosphine and gold catalysts, is based on an asymmetric aza‐Morita—Baylis—Hillman reaction.
ChemInform Abstract: Synthesis and Antitubercular Activity of Fused Thieno‐/Furo‐quinoline Compounds.
Authors: Akula Mahesh , Yogeeswari P. , Sriram D. , Jha Mukund , Bhattacharya Anupam
Published: September 2016

The cyclocondensation reaction of 2‐(3‐thienyl)‐ or 2‐(3‐furyl)aniline with aromatic aldehydes afford 4‐arylated thieno‐ and furo[2,3‐c]quinolines.
ChemInform Abstract: Metal‐Free Synthesis of Quinazolinones Without Any Additives in Water.
Authors: Hu Ben‐Quan , Cui Jie , Wang Li‐Xia , Tang Ya‐Lin , Yang Luo
Published: September 2016

During the condensation of anthranilamides with aldehydes (especially aliphatic aldehydes), an excess of the aldehydes promotes the oxidation of an aminal intermediate to the target quinazolinones.
ChemInform Abstract: EGB‐Promoted Electrochemical Synthesis of 6‐Thioxo‐[1,3,5]‐triazinane‐2,4‐dione Derivatives.
Authors: Sbei Najoua , Haouas Baya , Boujlel Khaled , Batanero Belen , Benkhoud Mohamed Lamine
Published: September 2016

Electrogenerated cyanomethyl base, obtained from electroreduction of neat acetonitrile, assists the reaction between thiourea derivatives (I) and isocyanates (II) furnishing the title triazinone derivatives (III).
ChemInform Abstract: Synthesis of Novel Eight‐Membered Dibenzo[b,f][1,5]oxazocin‐6‐ones.
Authors: Sivaguru Paramasivam , Parameswaran Kandasamy , Lalitha Appaswami
Published: September 2016

A simple strategy is reported for the rapid synthesis of novel tricyclic azo group containing eight membered dibenzo[b,f][1,5]oxazocin‐6‐ones.
ChemInform Abstract: Copper‐Catalyzed Decarboxylative Hydroboration: Synthesis of Vinyl Boronic Esters
Authors: Irudayanathan Francis Mariaraj , Raja Gabriel Charles Edwin , Kim Han‐Sung , Na Kyungsu , Lee Sunwoo
Published: September 2016

starting from aryl alkynyl carboxylic acids and bis(pinacolato)diboron with good functional group tolerance
ChemInform Abstract: Copper‐Catalyzed Si—B Bond Activation in the Nucleophilic Substitution of Primary Aliphatic Triflates.
Authors: Scharfbier Jonas , Oestreich Martin
Published: September 2016

Tetraorganosilanes are prepared by displacement of the triflate leaving group attached to terminally functionalized alkyl groups with nucleophilic silicon released from Suginomes Si—B reagent.
ChemInform Abstract: Practical Way for the Synthesis of Phosphine Oxides and Phosphine Sulfides from Benzyl Alcohol Derivatives.
Authors: Ma Yutao , Chen Feng , Bao Jifeng , Wei Hao , Shi Min , Wang Feijun
Published: September 2016

Pentavalent phosphorus compounds are prepared by reaction of various benzyl alcohols with Ph2PI in situ generated from Ph2PCl and NaI.
ChemInform Abstract: Broensted Base‐Catalyzed Three‐Component Coupling Reaction of α‐Ketoesters, Imines, and Diethyl Phosphite Utilizing [1,2]‐Phospha‐Brook Rearrangement.
Authors: Kondoh Azusa , Terada Masahiro
Published: September 2016

The title reaction involves the generation of ester enolates via the umpolung process, i.e., the chemoselective addition of diethyl phosphite to α‐ketoesters followed by [1,2]‐phospha‐Brook rearrangement, and the trapping of the resulting enolates by imines preferentially over α‐ketoesters and protons.
ChemInform Abstract: Sesquiterpenes with Inhibitory Activity Against CDC25 Phosphatases from the Soft Coral Pseudopterogorgia rigida
Authors: Georgantea Panagiota , Ioannou Efstathia , Evain‐Bana Emilie , Bagrel Denyse , Martinet Nadine , Vagias Constantinos , Roussis Vassilios
Published: September 2016

isolation, structure elucidation, and antitumor activity of sesquiterpenes, such as bisabolanes, cadinanes, and the new tricyclic carbon skeleton of compound (III)
ChemInform Abstract: Resonant Energy Transfer in (Eu3+, Bi3+)‐Codoped CaZrO3 Red‐Emitting Phosphor.
Authors: Orihashi Takuya , Nakamura Toshihiro , Adachi Sadao
Published: September 2016

The title phosphor is synthesized by solid state reaction of CaCO3, ZrO2, Eu2O3, and Bi2O3 (alumina crucible, 300—1200 °C, 1 h in air).
ChemInform Abstract: Antibacterial Properties of Silver Dendrite Decorated Silicon Nanowires.
Authors: Alhmoud Hashim , Delalat Bahman , Ceto Xavier , Elnathan Roey , Cavallaro Alex , Vasilev Krasimir , Voelcker Nicolas H.
Published: September 2016

Silicon nanowires decorated with silver dendrites are prepared by etching Si wafers with aqueous solutions of HF and AgNO3 (25 °C, 30—90 min).
ChemInform Abstract: Origin and Progress in Inorganic Chemistry
Authors: Banerjea D.
Published: September 2016

Review: [398 refs.
ChemInform Abstract: Hollow Zeolite Structures: An Overview of Synthesis Methods
Authors: Pagis Celine , Morgado Prates Ana Rita , Farrusseng David , Bats Nicolas , Tuel Alain
Published: September 2016

Review: 105 refs.
ChemInform Abstract: Modified Iron Oxide Nanomaterials: Functionalization and Application
Authors: Bagheri Samira , Julkapli Nurhidayatullaili Muhd
Published: September 2016

Review: 167 refs.
ChemInform Abstract: Zika Virus Drug Targets: A Missing Link in Drug Design and Discovery — A Route Map to Fill the Gap
Authors: Ramharack Pritika , Soliman Mahmoud E. S.
Published: September 2016

Review: 84 refs.
ChemInform Abstract: A Review on the Advancement of Ether Synthesis from Organic Solvent to Water
Authors: Mandal Sangita , Mandal Swagata , Ghosh Sumanta K. , Sar Pintu , Ghosh Aniruddha , Saha Rumpa , Saha Bidyut
Published: September 2016

Review: 106 refs.
ChemInform Abstract: Recent Developments in Enantioselective Metal‐Catalyzed Domino Reactions
Authors: Pellissier Helene
Published: September 2016

Review: [152 refs.
ChemInform Abstract: New Prospects Toward the Synthesis of Difluoromethylated Phosphate Mimics
Authors: Ivanova Maria V. , Bayle Alexandre , Besset Tatiana , Pannecoucke Xavier , Poisson Thomas
Published: September 2016

Review: [40 refs.
ChemInform Abstract: 1,3‐Dien‐5‐ynes: Versatile Building Blocks for the Synthesis of Carbo‐ and Heterocycles
Authors: Aguilar Enrique , Sanz Roberto , Fernandez‐Rodriguez Manuel A. , Garcia‐Garcia Patricia
Published: September 2016

Review: 220 refs.
ChemInform Abstract: Modern Transition‐Metal‐Catalyzed Carbon‐Halogen Bond Formation
Authors: Petrone David A. , Ye Juntao , Lautens Mark
Published: September 2016

Review: 577 refs.
ChemInform Abstract: Ionic Liquids in Palladium‐Catalyzed Cross‐Coupling Reactions
Authors: Mastrorilli Piero , Monopoli Antonio , Dell'Anna Maria Michela , Latronico Mario , Cotugno Pietro , Nacci Angelo
Published: September 2016

Review: 180 refs.
ChemInform Abstract: Ionic Liquids in Transition Metal‐Catalyzed Enantioselective Reactions
Authors: Li Yong , He Yan‐Mei , Fan Qing‐Hua
Published: September 2016

Review: 80 refs.
ChemInform Abstract: The Development of Iron Catalysts for Cross‐Coupling Reactions
Authors: Bedford Robin B. , Brenner Peter B.
Published: September 2016

Review: 91 refs.
ChemInform Abstract: Iron‐Catalyzed Cross‐Dehydrogenative‐Coupling Reactions
Authors: Itazaki Masumi , Nakazawa Hiroshi
Published: September 2016

Review: 78 refs.
ChemInform Abstract: Hydrated Proton‐Conductive Metal—Organic Frameworks
Authors: Sadakiyo Masaaki , Yamada Teppei , Kitagawa Hiroshi
Published: September 2016

Review: [37 refs.
ChemInform Abstract: Development of Cu2SnS3 (CTS) Thin Film Solar Cells by Physical Techniques: A Status Review
Authors: Lokhande A. C. , Chalapathy R. B. V. , He Mingrui , Jo Eunjin , Gang Myengil , Pawar S. A. , Lokhande C. D. , Kim Jin Hyeok
Published: September 2016

Review: 86 refs.
ChemInform Abstract: Preparation of Pharmaceutical Co‐Crystals Through Sustainable Processes Using Supercritical Carbon Dioxide: A Review
Authors: Pando Concepcion , Cabanas Albertina , Cuadra Isaac A.
Published: September 2016

Review: [74 refs.