bluuebunny/crossref_metadata_2025 huggingface dataset:
Heterocycles 48. Synthesis, Characterization and Biological Evaluation of Imidazo[2,1-b][1,3,4]Thiadiazole Derivatives as Anti-Inflammatory Agents
Authors: Cristina Anamaria , Leonte Denisa , Vlase Laurian , Bencze László Csaba , Imre Silvia , Marc Gabriel , Apan Bogdan , Mogoșan Cristina , Zaharia Valentin
Published: September 2018

Non-steroidal anti-inflammatory drugs (NSAIDs) are an important pharmacological class of drugs used for the treatment of inflammatory diseases. They are also characterized by severe side effects, such as gastrointestinal damage, increased cardiovascular risk and renal function abnormalities. In order to synthesize new anti-inflammatory and analgesic compounds with a safer profile of side effects, a series of 2,6-diaryl-imidazo[2,1-b][1,3,4]thiadiazole derivatives 5a–l were synthesized and evaluated in vivo for their anti-inflammatory and analgesic activities in carrageenan-induced rat paw edema. Among all compounds, 5c showed better anti-inflammatory activity compared to diclofenac, the standard drug, and compounds 5g, 5i, 5j presented a comparable antinociceptive activity to diclofenac. None of the compounds showed ulcerogenic activity. Molecular docking studies were carried out to investigate the theoretical bond interactions between the compounds and target, the cyclooxygenases (COX-1/COX-2). The compound 5c exhibited a higher inhibition of COX-2 compared to diclofenac.
Research Progress of NiMn Layered Double Hydroxides for Supercapacitors: A Review
Authors: Yan Ai-Lan , Wang Xin-Chang , Cheng Ji-Peng
Published: September 2018

The research on supercapacitors has been attractive due to their large power density, fast charge/discharge speed and long lifespan. The electrode materials for supercapacitors are thus intensively investigated to improve the electrochemical performances. Various transition metal layered double hydroxides (LDHs) with a hydrotalcite-like structure have been developed to be promising electrode materials. Earth-abundant metal hydroxides are very suitable electrode materials due to the low cost and high specific capacity. This is a review paper on NiMn LDHs for supercapacitor application. We focus particularly on the recent published papers using NiMn LDHs as electrode materials for supercapacitors. The preparation methods for NiMn LDHs are introduced first. Then, the structural design and chemical modification of NiMn LDH materials, as well as the composites and films derived from NiMn LDHs are discussed. These approaches are proven to be effective to enhance the performance of supercapacitor. Finally, the reports related to NiMn LDH-based asymmetric supercapacitors are summarized. A brief discussion of the future development of NiMn LDHs is also provided.
Effects of Al3+ Substitution on Structural and Magnetic Behavior of CoFe2O4 Ferrite Nanomaterials
Authors: Lin Qing , He Yun , Xu Jianmei , Lin Jinpei , Guo Zeping , Yang Fang
Published: September 2018

A sol-gel autocombustion method was used to synthesize Al3+ ion-substituted cobalt ferrite CoAlxFe2−xO4 (x = 0–1.5). According to X-ray diffraction analysis (XRD), cobalt ferrite was in a single cubic phase after being calcined at 1000 °C for 3 h. Moreover, the lattice constant decreased with increase in aluminum substituents. When the sample was analyzed by Scanning Electron Microscopy (SEM), we found that uniformly sized, well-crystallized grains were distributed in the sample. Furthermore, we confirmed that Al3+ ion-substituted cobalt ferrite underwent a transition from ferrimagnetic to superparamagnetic behavior; the superparamagnetic behavior was completely correlated with the increase in Al3+ ion concentration at room temperature. All these findings were observed in Mössbauer spectra. For the cobalt ferrite CoAlxFe2−xO4, the coercivity and saturation magnetization decrease with an increase in aluminum content. When the annealing temperature of CoAl0.1Fe1.9O4 was steadily increased, the coercivity and saturation magnetization initially increased and then decreased.
Interactions between Bitter Taste, Diet and Dysbiosis: Consequences for Appetite and Obesity
Authors: Turner Alexandria , Veysey Martin , Keely Simon , Scarlett Christopher , Lucock Mark , Beckett Emma L.
Published: September 2018

The type 2 family of taste receptors (T2Rs) detect and respond to bitter tastants. These receptors are expressed throughout the gastrointestinal (GI) tract, with location dependant roles. In the oral cavity, T2Rs are involved in the conscious perception of bitter tastants, while in the lower GI tract they have roles in chemoreception and regulation of GI function. Through these diverse roles, these receptors may be involved in modulating appetite and diet, with consequences for weight regulation and obesity. Interestingly, the concentration of T2Rs in the GI tract is greatest in the large intestine, the organ with the densest colonisation of bacteria. The gut microbiome has been the subject of intense research, as a plethora of roles linking microbiota to human health continue to be uncovered. Of particular interest is the microbial signature associated with obesity. Obesity is a leading health concern, and advances in our understanding of this disease are needed. Diet is a known modifiable factor in the development of obesity. However, diet only partially explains disease risk. Changes in microbial energy harvesting by the microbiota plays a role in obesity, and the composition of these energy harvesting populations may be controlled by taste receptors. This review explores T2Rs as a potential link between obesity and the human GI microbiome.
Effect of Tourism Pressure on the Mediterranean Diet Pattern
Authors: Rodríguez-Mireles Silvia , López-Valcárcel Beatriz G. , Serra-Majem Lluís , Hernández-Yumar Aránzazu , Barber-Pérez Patricia , Pinilla-Domínguez Jaime , Rodríguez-Feijoo Santiago , Rodríguez-Caro Alejandro
Published: September 2018

Despite proposed conceptual frameworks of eating behaviors, little is known about environmental factors contributing to changes in food habits. Few studies have reported the external influence of tourism on the inhabitants’ eating patterns. The present study aimed to investigate whether tourism pressure affects Canary Islands inhabitants’ adherence to the Mediterranean diet pattern. Data were obtained from a health and lifestyle population-based survey conducted in 2009 and 2015. From the reported intake frequency, a Mediterranean diet score was defined (0 to 11 points). Tourist overnight stays, which were stratified by nationality and area of destination, were used as a proxy variable to measure tourism pressure. A multilevel linear regression analysis by restricted maximum likelihood estimation was performed to examine the relationship between tourism pressure and the Mediterranean diet score. A significant negative association between the Mediterranean diet score and British tourism pressure was observed (β = −0.0064, p = 0.010), whereas German tourism pressure increased inhabitants’ adherence (β = 0.0092, p = 0.042). The socioeconomic level of tourists seems to play a role in differences in the tourism pressure effect by nationality. Further investigation of other highly touristic destinations is needed to confirm these findings that could contribute to a shift in tourism and public health nutrition policies.
Analysis of Nutritional Supplements Consumption by Squash Players
Authors: Ventura Comes Anna , Sánchez-Oliver Antonio J. , Martínez-Sanz José Miguel , Domínguez Raúl
Published: September 2018

The aim of the present study is to analyse nutritional supplements (NS) consumption by squash players of different levels (international vs. national). A total of 14 international players and 28 national ones answered a NS consumption frequency questionnaire that had been previously validated. A T-Student test was used for independent samples and a χ2 test was used in the comparative analysis among athletes of different levels. International level players consume NS in greater proportion vs. national level players (100% vs. 67.9% p = 0.017), with differences in the consumption of bicarbonate of soda, glutamine, branched-chain amino acids, and flaxseed oil (p < 0.05). Even though international level athletes show a greater total number of NS, as well as of the total of NS of each of the categories based on scientific evidence level (sports food, medical supplements, and ergogenic aids of groups A, B, C, and D) in relation to the national level athletes, no statistically significant differences were detected (p > 0.05). With regard to nutritional advice, there are also differences among performance levels (p = 0.003), being personal trainers (28.6%) and dietitians-nutritionists (21.4%) the greatest prescribers when it comes to international-level players, whereas 55.6% of the national-level players do not receive nutritional advice. The pattern of NS consumption, based on evidence level, is unbalanced and its performance could be favored if the dietitian-nutritionist were included as a nutritional advisor for these athletes.
Glycaemic Index of Maternal Dietary Carbohydrate Differentially Alters Fto and Lep Expression in Offspring in C57BL/6 Mice
Authors: Sideratou Theodora , Atkinson Fiona , Campbell Grace J. , Petocz Peter , Bell-Anderson Kim S. , Brand-Miller Jennie
Published: September 2018

Maternal diet and gestational hyperglycaemia have implications for offspring health. Leptin (LEP) and fat mass and obesity-associated (FTO) alleles are known to influence body fat mass in humans, potentially via effects on appetite. We hypothesized that expression of Fto, Lep, and other appetite-related genes (Argp, Npy, Pomc, Cart, Lepr) in the offspring of female mice are influenced by the glycaemic index (GI) of carbohydrates in the maternal diet. C57BL/6 mice were randomly assigned to low or high GI diets and mated with chow-fed males at eight weeks of age. Male pups were weaned at four weeks and randomly divided into two groups, one group following their mother’s diet (LL and HH), and one following the standard chow diet (LC and HC) to 20 weeks. Fto expression was 3.8-fold higher in the placenta of mothers fed the high GI diet (p = 0.0001) and 2.5-fold higher in the hypothalamus of 20-week old offspring fed the high GI (HH vs. LL, p < 0.0001). By contrast, leptin gene (Lep) expression in visceral adipose tissue was 4.4-fold higher in four-week old offspring of low GI mothers (LC vs. HC, p < 0.0001) and 3.3-fold higher in visceral adipose tissue of 20-week old animals (LL vs. HH, p < 0.0001). Plasma ghrelin and leptin levels, and hypothalamic appetite genes were also differentially regulated by maternal and offspring diet. These findings provide the first evidence in an animal model that maternal high GI dietary carbohydrates that are digested and absorbed faster may contribute to programming of appetite in offspring.
The Impact of Adding Sugars to Milk and Fruit on Adiposity and Diet Quality in Children: A Cross-Sectional and Longitudinal Analysis of the Identification and Prevention of Dietary- and Lifestyle-Induced Health Effects in Children and Infants (IDEFICS) Study
Authors: Dello Russo Marika , Ahrens Wolfgang , De Henauw Stefaan , Eiben Gabriele , Hebestreit Antje , Kourides Yannis , Lissner Lauren , Molnar Denes , Moreno Luis , Pala Valeria , Veidebaum Toomas , Siani Alfonso , Russo Paola ,   On behalf of the IDEFICS Consortium
Published: September 2018

Sugar, particularly as free sugars or sugar-sweetened beverages, significantly contributes to total energy intake, and, possibly, to increased body weight. Excessive consumption may be considered as a proxy of poor diet quality. However, no previous studies evaluated the association between the habit of adding sugars to “healthy” foods, such as plain milk and fresh fruit, and indicators of adiposity and/or dietary quality in children. To answer to these research questions, we Panalysed the European cohort of children participating in the IDEFICS study. Anthropometric variables, frequency of consumption of sugars added to milk and fruit (SAMF), and scores of adherence to healthy dietary pattern (HDAS) were assessed at baseline in 9829 children stratified according to age and sex. From this cohort, 6929 children were investigated again after two years follow-up. At baseline, a direct association between SAMF categories and adiposity indexes was observed only in children aged 6–<10 years, while the lower frequency of SAMF consumption was significantly associated with a higher HDAS. At the two year follow-up, children with higher baseline SAMF consumption showed significantly higher increases in all the anthropometric variables measured, with the exception of girls 6–<10 years old. The inverse association between SAMF categories and HDAS was still present at the two years follow-up in all age and sex groups. Our results suggest that the habit to adding sugars to foods that are commonly perceived as healthy may impact the adherence to healthy dietary guidelines and increase in adiposity risk as well.
Endogenous Omega (n)-3 Fatty Acids in Fat-1 Mice Attenuated Depression-Like Behavior, Imbalance between Microglial M1 and M2 Phenotypes, and Dysfunction of Neurotrophins Induced by Lipopolysaccharide Administration
Authors: Gu Minqing , Li Yuyu , Tang Haiting , Zhang Cai , Li Wende , Zhang Yongping , Li Yajuan , Zhao Yuntao , Song Cai
Published: September 2018

n-3 polyunsaturated fatty acids (PUFAs) have been reported to improve depression. However, PUFA purities, caloric content, and ratios in different diets may affect the results. By using Fat-1 mice which convert n-6 to n-3 PUFAs in the brain, this study further evaluated anti-depressant mechanisms of n-3 PUFAs in a lipopolysaccharide (LPS)-induced model. Adult male Fat-1 and wild-type (WT) mice were fed soybean oil diet for 8 weeks. Depression-like behaviors were measured 24 h after saline or LPS central administration. In WT littermates, LPS reduced sucrose intake, but increased immobility in forced-swimming and tail suspension tests. Microglial M1 phenotype CD11b expression and concentrations of interleukin (IL)-1β, tumor necrosis factor (TNF)-α, and IL-17 were elevated, while M2 phenotype-related IL-4, IL-10, and transforming growth factor (TGF)-β1 were decreased. LPS also reduced the expression of brain-derived neurotrophic factor (BDNF) and tyrosine receptor kinase B (Trk B), while increasing glial fibrillary acidic protein expression and pro-BDNF, p75, NO, and iNOS levels. In Fat-1 mice, LPS-induced behavioral changes were attenuated, which were associated with decreased pro-inflammatory cytokines and reversed changes in p75, NO, iNOS, and BDNF. Gas chromatography assay confirmed increased n-3 PUFA levels and n-3/n-6 ratios in the brains of Fat-1 mice. In conclusion, endogenous n-3 PUFAs may improve LPS-induced depression-like behavior through balancing M1 and M2-phenotypes and normalizing BDNF function.
The Role of Genetics in Moderating the Inter-Individual Differences in the Ergogenicity of Caffeine
Authors: Southward Kyle , Rutherfurd-Markwick Kay , Badenhorst Claire , Ali Ajmol
Published: September 2018

Caffeine use is widespread among athletes following its removal from the World Anti-Doping Agency banned list, with approximately 75% of competitive athletes using caffeine. While literature supports that caffeine has a small positive ergogenic effect for most forms of sports and exercise, there exists a significant amount of inter-individual difference in the response to caffeine ingestion and the subsequent effect on exercise performance. In this narrative review, we discuss some of the potential mechanisms and focus on the role that genetics has in these differences. CYP1A2 and ADORA2A are two of the genes which are thought to have the largest impact on the ergogenicity of caffeine. CYP1A2 is responsible for the majority of the metabolism of caffeine, and ADORA2A has been linked to caffeine-induced anxiety. The effects of CYP1A2 and ADORA2A genes on responses to caffeine will be discussed in detail and an overview of the current literature will be presented. The role of these two genes may explain a large portion of the inter-individual variance reported by studies following caffeine ingestion. Elucidating the extent to which these genes moderate responses to caffeine during exercise will ensure caffeine supplementation programs can be tailored to individual athletes in order to maximize the potential ergogenic effect.
Magnesium Intake and Sleep Disorder Symptoms: Findings from the Jiangsu Nutrition Study of Chinese Adults at Five-Year Follow-Up
Authors: Cao Yingting , Zhen Shiqi , Taylor Anne W. , Appleton Sarah , Atlantis Evan , Shi Zumin
Published: September 2018

(1) Background: In clinical trials, dietary magnesium use can improve insomnia symptoms. However, little is known about the association between dietary magnesium consumption and sleep disorder symptoms including daytime falling asleep, sleepiness and snoring at the population level. (2) Methods: We used data from 1487 adults aged 20 and above attending the Jiangsu Nutrition Study. At baseline in 2002, dietary magnesium was assessed by 3-day weighed food records. At follow-up in 2007, sleep disorder symptoms, including daytime falling asleep, sleepiness and snoring at night, were gathered using a sleep questionnaire. (3) Results: The mean intake of magnesium was 332.5 mg/day. In total, 5.3%, 13.2% and 35.7% of the subjects reported daytime falling asleep, daytime sleepiness, and snoring during sleep, respectively. Compared with the lowest quartile of magnesium intake, the highest quartile was associated with decreased likelihood of falling asleep (odds ratio (OR) 0.12 (0.02, 0.57)) in women but not in men after adjusting for demographic, anthropometric, lifestyle factors, hypertension, and overall dietary patterns. No associations were found between dietary magnesium intake and daytime sleepiness nor night snoring in either gender. (4) Conclusions: Dietary magnesium intake may have long-term benefits in reducing the likelihood of daytime falling asleep in women.
Human Breast Milk NMR Metabolomic Profile across Specific Geographical Locations and Its Association with the Milk Microbiota
Authors: Gómez-Gallego Carlos , Morales Jose Manuel , Monleón Daniel , Du Toit Elloise , Kumar Himanshu , Linderborg Kaisa M. , Zhang Yumei , Yang Baoru , Isolauri Erika , Salminen Seppo , Collado Maria Carmen
Published: September 2018

The composition of human breast milk is highly variable, and it can be influenced by genetics, diet, lifestyle, and other environmental factors. This study aimed to investigate the impact of geographical location and mode of delivery on the nuclear magnetic resonance spectroscopy (NMR) metabolic profile of breast milk and its relationship with the milk microbiome. Human milk metabolic and microbiota profiles were determined using NMR and 16S rRNA gene sequencing, respectively, in 79 healthy women from Finland, Spain, South Africa, and China. Up to 68 metabolites, including amino acids, oligosaccharides, and fatty acid-associated metabolites, were identified in the milk NMR spectra. The metabolite profiles showed significant differences between geographical locations, with significant differences (p < 0.05) in the levels of galactose, lacto-N-fucopentaose III, lacto-N-fucopentaose I and 2-fucosyllactose, 3-fucosyllactose, lacto-N-difucohexaose II, lacto-N-fucopentaose III, 2-hydroxybutyrate, 3-hydroxybutyrate, proline, N-acetyl lysine, methyl-histidine, dimethylamine, kynurenine, urea, creatine and creatine phosphate, formate, lactate, acetate, phosphocholine, acetylcholine, LDL, VLDL, ethanolamine, riboflavin, hippurate, spermidine, spermine and uridine. Additionally, the effect of caesarean section on milk metabolome was dependent on the geographical region. Specific interrelations between human milk metabolites and microbiota were also identified. Proteobacteria, Actinobacteria, and Bacilli were most significantly associated with the milk metabolites, being either positively or negatively correlated depending on the metabolite. Our results reveal specific milk metabolomic profiles across geographical locations and also highlight the potential interactions between human milk’s metabolites and microbes.
Combined Use of N-Palmitoyl-Glycine-Histidine Gel and Several Penetration Enhancers on the Skin Permeation and Concentration of Metronidazole
Authors: Dahlizar Sabrina , Futaki Mika , Okada Akie , Yatomi Chihiro , Todo Hiroaki , Sugibayashi Kenji
Published: September 2018

N-Palmitoyl-Glycine-Histidine (Pal-GH) is a novel low molecular weight gelator. In our previous report, ivermectin, a lipophilic drug, was effectively delivered to skin tissue after topical application with Pal-GH as a spray gel formulation, and a much higher skin concentration was confirmed than with the administration of a conventional oral formulation. The objective of this study was to increase the skin permeation of metronidazole (MTZ), a hydrophilic drug, after the topical application of Pal-GH gel. An evaluation of the combined effect of chemical penetration enhancers (CPEs), such as isopropyl myristate (IPM), propylene glycol (PG), ethanol, diethylene glycol monoethyl ether, and dimethyl sulfoxide (DMSO), on skin permeation was also conducted. We found that a 5% Pal-GH gel containing 1% MTZ (F5MTZ) exhibited a 2.7-fold higher MTZ permeation through excised hairless rat skin than its solution. Furthermore, F5PG-MTZ and F5IPM-MTZ further increased the skin permeation of MTZ when compared to F5MTZ. Interestingly, F5PG-MTZ enhanced the skin penetration of MTZ, although no enhancement effect was observed for an MTZ solution containing PG. Thus, a Pal-GH formulation containing PG and IPM may enhance the skin permeation of MTZ.
The Utterly Prosaic Connection between Physics and Mathematics
Authors: Visser Matt
Published: September 2018

Eugene Wigner famously argued for the “unreasonable effectiveness of mathematics” as applied to describing physics and other natural sciences in his 1960 essay. That essay has now led to some 58 years of (sometimes anguished) philosophical soul searching—responses range from “So what? Why do you think we developed mathematics in the first place?”, through to extremely speculative ruminations on the existence of the universe (multiverse) as a purely mathematical entity—the Mathematical Universe Hypothesis. In the current essay I will steer an utterly prosaic middle course: Much of the mathematics we develop is informed by physics questions we are trying to solve; and those physics questions for which the most utilitarian mathematics has successfully been developed are typically those where the best physics progress has been made.
Human Cognition, Patterning and Deacon’s Absentials: The Value of Absent-Mindedness in the Sense of Minding What Is Absent
Authors: Tandoc Marlie , Logan Robert K.
Published: September 2018

Important aspects of human cognition are considered in terms of patterning, which we claim represents a shift from focusing on what is present to what is absent. We make use of Deacon’s notion of absentials and apply it to the patterning that underscores human cognition. Several important aspects of human cognition are considered that represent a shift from focusing on what is present to what is absent, namely, language as representing the transition from percept to concept-based thinking, mathematical grouping and patterning of items into sets that gave rise to verbal language, as well as imaginative thinking which is so critical for the development of the arts, mathematics and science. The connection between information and absence is also examined, in which we claim that information is an absential, paralleling an idea of Deacon’s.
Fruit Decay to Diseases: Can Induced Resistance and Priming Help?
Authors: Pétriacq Pierre , López Ana , Luna Estrella
Published: September 2018

Humanity faces the challenge of having to increase food production to feed an exponentially growing world population, while crop diseases reduce yields to levels that we can no longer afford. Besides, a significant amount of waste is produced after fruit harvest. Fruit decay due to diseases at a post-harvest level can claim up to 50% of the total production worldwide. Currently, the most effective means of disease control is the use of pesticides. However, their use post-harvest is extremely limited due to toxicity. The last few decades have witnessed the development of safer methods of disease control post-harvest. They have all been included in programs with the aim of achieving integrated pest (and disease) management (IPM) to reduce pesticide use to a minimum. Unfortunately, these approaches have failed to provide robust solutions. Therefore, it is necessary to develop alternative strategies that would result in effective control. Exploiting the immune capacity of plants has been described as a plausible route to prevent diseases post-harvest. Post-harvest-induced resistance (IR) through the use of safer chemicals from biological origin, biocontrol, and physical means has also been reported. In this review, we summarize the successful activity of these different strategies and explore the mechanisms behind. We further explore the concept of priming, and how its long-lasting and broad-spectrum nature could contribute to fruit resistance.
Progress toward Understanding the Molecular Basis of Fruit Response to Hypoxia
Authors: Cukrov Dubravka
Published: September 2018

Oxygen has shaped life on Earth as we know it today. Molecular oxygen is essential for normal cellular function, i.e., plants need oxygen to maintain cellular respiration and for a wide variety of biochemical reactions. When oxygen levels in the cell are lower than levels needed for respiration, then the cell experiences hypoxia. Plants are known to experience root hypoxia during natural environmental conditions like flooding. Fruit, on the other hand, is known to be hypoxic under normal oxygen conditions. This observation could be explained (at least partially) as a consequence of diffusional barriers, low tissue diffusivity, and high oxygen consumption by respiration. From the physiological point of view, hypoxia is known to have a profound impact on fruit development, since it is well documented that a low oxygen environment can significantly delay ripening and senescence of some fruit. This effect of a low-oxygen environment is readily used for optimizing storage conditions and transport, and for prolonging the shelf life of several fruit commodities. Therefore, further understanding of the complex relationship between oxygen availability within the cell and fruit development could assist postharvest management.
Electrospun Cellulose Nanocrystals/Chitosan/Polyvinyl Alcohol Nanofibrous Films and their Exploration to Metal Ions Adsorption
Authors: Wang Dong , Cheng Wanli , Yue Yiying , Xuan Lihui , Ni Xiaohui , Han Guangping
Published: September 2018

Cellulose nanocrystals/chitosan/polyvinyl alcohol (CNC/CS/PVA) composite nanofibrous films were prepared while using an electrospinning technique and successfully thiol-functionalized. Then, the modified films were used for the sorption-desorption of Cu(II) and Pb(II) ions. Subsequently, the adsorption capacity of the films was investigated by changing the CNC loading level, solution pH, and adsorption time. Results showed that the adsorption of metal ions by the films was the best with CNC loading level of 5 wt %, pH of 6, and adsorption time of 4 h. The adsorption behavior of the films was agreed with the Freundlich model. The adsorption equation of metal ions could be described while using a pseudo-second order model. Based on the Langmuir model, the maximum adsorption capacities of Cu(II) and Pb(II) ions were estimated to be 484.06 and 323.49 mg/g, respectively. The Cu(II) and Pb(II) ions adsorption efficiencies of the films after 4 adsorption-desorption cycles were 90.58% and 90.21%, respectively. This study may provide a feasible approach for the application of functional CNC/CS/PVA nanofibrous films in the treatment of water.
Effect of Content and Surface Modification of Fique Fibers on the Properties of a Low-Density Polyethylene (LDPE)-Al/Fique Composite
Authors: Muñoz-Vélez Mario Fernando , Hidalgo-Salazar Miguel Angel , Mina-Hernández Jose Herminsul
Published: September 2018

This work presents the physical-thermal and mechanical characterization of a low-density polyethylene (LDPE)-Al matrix composite material that was obtained from reinforcing recycled (post-consumer) long-life Tetra Pak packages with fique natural fibers from southwestern Colombia. The fique was subjected to three chemical treatments to modify its surface (alkalinization, silanization and pre-impregnation with polyethylene) to increase the quality of its interfaces. Additionally, panels with 10%, 20%, and 30% v/v of fiber were manufactured by the hot compression molding. The mechanical properties of the different composite materials showed that the pre-impregnation treatment promoted a significant increase in the tensile and flexural properties with respect to the fiber-reinforced composite without surface modification. Additionally, in materials with 30% fibers that were treated with pre-impregnation, there was a decrease in the water absorption capacity of 53.15% when compared to composites made with 30% native fibers. Finally, increases in the fiber content mainly caused better mechanical performances, which increased as a direct function of the amount of fique incorporated.
Synthesis of Polystyrene-Coated Superparamagnetic and Ferromagnetic Cobalt Nanoparticles
Authors: Tan Li , Liu Bing , Siemensmeyer Konrad , Glebe Ulrich , Böker Alexander
Published: September 2018

Polystyrene-coated cobalt nanoparticles (NPs) were synthesized through a dual-stage thermolysis of cobalt carbonyl (Co2(CO)8). The amine end-functionalized polystyrene surfactants with varying molecular weight were prepared via atom-transfer radical polymerization technique. By changing the concentration of these polymeric surfactants, Co NPs with different size, size distribution, and magnetic properties were obtained. Transmission electron microscopy characterization showed that the size of Co NPs stabilized with lower molecular weight polystyrene surfactants (Mn = 2300 g/mol) varied from 12–22 nm, while the size of Co NPs coated with polystyrene of middle (Mn = 4500 g/mol) and higher molecular weight (Mn = 10,500 g/mol) showed little change around 20 nm. Magnetic measurements revealed that the small cobalt particles were superparamagnetic, while larger particles were ferromagnetic and self-assembled into 1-D chain structures. Thermogravimetric analysis revealed that the grafting density of polystyrene with lower molecular weight is high. To the best of our knowledge, this is the first study to obtain both superparamagnetic and ferromagnetic Co NPs by changing the molecular weight and concentration of polystyrene through the dual-stage decomposition method.
Preparation and Physicochemical Properties of Blend Films of Feather Keratin and Poly(vinyl alcohol) Compatibilized by Tris(hydroxymethyl)aminomethane
Authors: Chen Xunjun , Wu Shufang , Yi Minghao , Ge Jianfang , Yin Guoqiang , Li Xinming
Published: September 2018

Blend films of feather keratin (FK) and synthetic poly(vinyl alcohol) (PVA) that were compatibilized by tris(hydroxymethyl)aminomethane (Tris) were successfully prepared by a solution-casting method. The scanning electron microscopy (SEM) results showed that a phase separation occurred in the FK/PVA/Tris blended system. Analysis by Fourier transform infrared spectroscopy indicated that the main interactions between the three components were hydrogen bonds. In addition, X-ray diffraction analysis showed that the FK/PVA/Tris blend films were partially crystalline. The barrier properties, mechanical properties, and contact angles of the FK/PVA/Tris films were investigated to determine the effects of the PVA and Tris concentrations. More specifically, upon increasing the PVA content, the elongation at break, the hydrophilicity, and the oxygen barrier properties were enhanced. However, at a constant PVA content, an increase in the Tris content caused the oxygen permeability and the contact angle to decrease, while the tensile strength, elongation at break, and oxygen barrier properties were enhanced. These results indicated that the mechanical properties and gas resistance of the FK/PVA/Tris blend films could be successfully improved using the method described herein, confirming that this route provided a convenient and promising means to prepare FK plastics for practical applications.
Flexible Biocomposites with Enhanced Interfacial Compatibility Based on Keratin Fibers and Sulfur-Containing Poly(urea-urethane)s
Authors: Aranberri Ibon , Montes Sarah , Azcune Itxaso , Rekondo Alaitz , Grande Hans-Jürgen
Published: September 2018

Feathers are made of keratin, a fibrous protein with high content of disulfide-crosslinks and hydrogen-bonds. Feathers have been mainly used as reinforcing fiber in the preparation of biocomposites with a wide variety of polymers, also poly(urea-urethane)s. Surface compatibility between the keratin fiber and the matrix is crucial for having homogenous, high quality composites with superior mechanical properties. Poly(urea-urethane) type polymers are convenient for this purpose due to the presence of polar functionalities capable of forming hydrogen-bonds with keratin. Here, we demonstrate that the interfacial compatibility can be further enhanced by incorporating sulfur moieties in the polymer backbone that lead to new fiber-matrix interactions. We comparatively studied two analogous thermoplastic poly(urea-urethane) elastomers prepared starting from the same isocyanate-functionalized polyurethane prepolymer and two aromatic diamine chain extenders, bis(4-aminophenyl) disulfide (TPUU-SS) and the sulfur-free counterpart bis(4-aminophenyl) methane (TPUU). Then, biocomposites with high feather loadings (40, 50, 60 and 75 wt %) were prepared in a torque rheometer and hot-compressed into flexible sheets. Mechanical characterization showed that TPUU-SS based materials underwent higher improvement in mechanical properties than biocomposites made of the reference TPUU (up to 7.5-fold higher tensile strength compared to neat polymer versus 2.3-fold). Field Emission Scanning Electron Microscope (FESEM) images also provided evidence that fibers were completely embedded in the TPUU-SS matrix. Additionally, density, thermal stability, and water absorption of the biocomposites were thoroughly characterized.
Spiritual Distress in Cancer Patients: A Synthesis of Qualitative Studies
Authors: Martins Helga , Caldeira Sílvia
Published: September 2018

Cancer affects individuals in all human dimensions. Cancer patients are more susceptible to spiritual distress. Several studies have addressed spiritual distress using quantitative designs; however, a qualitative approach to the experience of spiritual distress could provide a deeper understanding of the phenomenon. This study aims to synthesis the experience of spiritual distress as lived by cancer patients in qualitative primary studies. This is a literature review based on electronic databases search. A total of 4075 citations was identified and 23 studies were included. The most frequent qualitative research method was phenomenology (n = 15), and interviews were the main data collection method (n = 20). Two major themes have been identified related to the experience of spiritual distress: suffering and coping. Spiritual distress is an intimate, deep and suffering experience in life, which requires coping strategies and involves spiritual values and beliefs. Healthcare providers should be aware of this experience and recognize spiritual distress in cancer patients, as it is critical in providing holistic nursing care.
Are Unidentified Terrorist Suspects Always Muslims? How Terrorism News Shape News Consumers’ Automatic Activation of Muslims as Perpetrators
Authors: Schmuck Desirée , Matthes Jörg , Von Sikorski Christian , Materne Nicole , Shah Ekata
Published: September 2018

Two experimental studies investigated how news reports about terrorist attacks committed by unidentified perpetrators influence beliefs about the perpetrators and Muslims in general. In Study 1, a quota-based sample of 354 Germans was exposed to terror news coverage describing either non-Muslim or Muslim victims with no reference to the perpetrators of the attacks. Upon stimulus exposure, participants were asked the likelihood that the perpetrators were either Islamist extremists, far-right extremists, or lone operators. In Study 2, no information about the victims was provided, but the perpetrators were either Muslims or unidentified. In addition, we measured news consumers’ Islamophobic attitudes in both studies. Results from Study 1 revealed that participants attributed perpetrator-unidentified attacks to Islamist perpetrators when the victims were non-Muslims. In contrast, terrorist attacks directed against Muslim victims were more likely to be attributed to far-right extremists. Additionally, Study 2 revealed that news consumers associated perpetrator-unidentified terrorist attacks with Islamist extremists to an equal degree as terrorist attacks that were committed by Muslim perpetrators. Attributing the attack to Islamists was in turn significantly related to Islamophobic attitudes in both studies. Implications of these findings for journalism practice and society at large are discussed.
Franciscan Spirituality and Economics
Authors: Zsolnai Laszlo
Published: September 2018

St. Francis was hostile to money and material wealth. He was also against exploitation or misuse of natural creatures and promoted voluntary poverty, sharing, and universal brotherhood. This paper examines the implications of St. Francis’s views for economics. It is argued that St. Francis’s views imply the substantive notion of the term “economic” and favor material sufficiency instead of financial efficiency. Pope Francis’s encyclical letter “Laudato si’” is consistent with and supports St. Francis’s views, which emphasize the frugality of consumption and acknowledging the intrinsic value of nature. The overall vision of St. Francis can be characterized as “The Commonwealth of Life” based on a God-centered, spiritual way of living and acting. The paper suggests that the models of a sufficiency-oriented community economy are relevant for realizing St. Francis’s legacy in today’s reality of climate change described by climate scientists as the “Hothouse Earth” pathway.
Fisheries-Based Ecotourism in Bangladesh: Potentials and Challenges
Authors: Mozumder Mohammad Mojibul Hoque , Uddin Mohammad Muslem , Schneider Petra , Islam Mohammad Mahmudul , Shamsuzzaman Md. Mostafa
Published: September 2018

Recreational fishing trips constitute a significant part of the tourism business in many countries. Linking fisheries to tourism can be both a response to the need to create innovative tourism products and the need to find new sources of income for fisheries to make them more profitable and sustainable. This leads to the question of whether Bangladesh can be developed as a Fisheries-Based Ecotourism (FbE) destination. Though several types of research have been done concerning the prospects of ecotourism in Bangladesh, the feasibility of FbE specifically remains under-studied. Based on a literature review and stakeholder interviews, this study explores the concept of FbE in a Bangladeshi context and its potential impacts on socio-economic community life as well as on the environment. This paper makes the case that the diversified topography of Bangladesh—including the riverine flat alluvial plains, hills and valleys, deciduous and evergreen forests, lakes, seashores, and beaches—is ripe with potential for FbE development. With its focus on the prospects and challenges of FbE development in Bangladesh, this paper could provide a useful reference point for future discourse on these sorts of cultural and economic strategies.
Optimization of Airborne Antenna Geometry for Ocean Surface Scatterometric Measurements
Authors: Nekrasov Alexey , Khachaturian Alena , Abramov Evgeny , Popov Dmitry , Markelov Oleg , Obukhovets Viktor , Veremyev Vladimir , Bogachev Mikhail
Published: September 2018

We consider different antenna configurations, ranging from simple X-configuration to multi-beam star geometries, for airborne scatterometric measurements of the wind vector near the ocean surface. For all geometries, track-stabilized antenna configurations, as well as horizontal transmitter and receiver polarizations, are considered. The wind vector retrieval algorithm is generalized here for an arbitrary star geometry antenna configuration and tested using the Ku-Band geophysical model function. Using Monte Carlo simulations for the fixed total measurement time, we show explicitly that the relative wind speed estimation accuracy barely depends on the chosen antenna geometry, while the maximum wind direction retrieval error reduces moderately with increasing angular resolution, although at the cost of increased retrieval algorithm computational complexity, thus, limiting online analysis options with onboard equipment. Remarkably, the simplest X-configuration, while the simplest in terms of hardware implementation and computational time, appears an outlier, yielding considerably higher maximum retrieval errors when compared to all other configurations. We believe that our results are useful for the optimization of both hardware and software design for modern airborne scatterometric measurement systems based on tunable antenna arrays especially, those requiring online data processing.
Using Window Regression to Gap-Fill Landsat ETM+ Post SLC-Off Data
Authors: Brooks Evan B. , Wynne Randolph H. , Thomas Valerie A.
Published: September 2018

The continued development of algorithms using multitemporal Landsat data creates opportunities to develop and adapt imputation algorithms to improve the quality of that data as part of preprocessing. One example is de-striping Enhanced Thematic Mapper Plus (ETM+, Landsat 7) images acquired after the Scan Line Corrector failure in 2003. In this study, we apply window regression, an algorithm that was originally designed to impute low-quality Moderate Resolution Imaging Spectroradiometer (MODIS) data, to Landsat Analysis Ready Data from 2014–2016. We mask Operational Land Imager (OLI; Landsat 8) image stacks from five study areas with corresponding ETM+ missing data layers, using these modified OLI stacks as inputs. We explored the algorithm’s parameter space, particularly window size in the spatial and temporal dimensions. Window regression yielded the best accuracy (and moderately long computation time) with a large spatial radius (a 7 × 7 pixel window) and a moderate temporal radius (here, five layers). In this case, root mean square error for deviations from the observed reflectance ranged from 3.7–7.6% over all study areas, depending on the band. Second-order response surface analysis suggested that a 15 × 15 pixel window, in conjunction with a 9-layer temporal window, may produce the best accuracy. Compared to the neighborhood similar pixel interpolator gap-filling algorithm, window regression yielded slightly better accuracy on average. Because it relies on no ancillary data, window regression may be used to conveniently preprocess stacks for other data-intensive algorithms.
Suspended Sediment Concentration Estimation from Landsat Imagery along the Lower Missouri and Middle Mississippi Rivers Using an Extreme Learning Machine
Authors: Peterson Kyle , Sagan Vasit , Sidike Paheding , Cox Amanda , Martinez Megan
Published: September 2018

Monitoring and quantifying suspended sediment concentration (SSC) along major fluvial systems such as the Missouri and Mississippi Rivers provide crucial information for biological processes, hydraulic infrastructure, and navigation. Traditional monitoring based on in situ measurements lack the spatial coverage necessary for detailed analysis. This study developed a method for quantifying SSC based on Landsat imagery and corresponding SSC data obtained from United States Geological Survey monitoring stations from 1982 to present. The presented methodology first uses feature fusion based on canonical correlation analysis to extract pertinent spectral information, and then trains a predictive reflectance–SSC model using a feed-forward neural network (FFNN), a cascade forward neural network (CFNN), and an extreme learning machine (ELM). The trained models are then used to predict SSC along the Missouri–Mississippi River system. Results demonstrated that the ELM-based technique generated R2 > 0.9 for Landsat 4–5, Landsat 7, and Landsat 8 sensors and accurately predicted both relatively high and low SSC displaying little to no overfitting. The ELM model was then applied to Landsat images producing quantitative SSC maps. This study demonstrates the benefit of ELM over traditional modeling methods for the prediction of SSC based on satellite data and its potential to improve sediment transport and monitoring along large fluvial systems.
The Role of Earth Observation, with a Focus on SAR Interferometry, for Sinkhole Hazard Assessment
Authors: Theron Andre , Engelbrecht Jeanine
Published: September 2018

Sinkholes are global phenomena with significant consequences on the natural- and built environment. Significant efforts have been devoted to the assessment of sinkhole hazards to predict the spatial and temporal occurrence of future sinkholes as well as to detect small-scale deformation prior to collapse. Sinkhole hazard maps are created by considering the distribution of past sinkholes in conjunction with their geomorphic features, controlling conditions and triggering mechanisms. Quantitative risk assessment then involves the statistical analysis of sinkhole events in relation to these conditions with the aim of identifying high risk areas. Remote sensing techniques contribute to the field of sinkhole hazard assessment by providing tools for the population of sinkhole inventories and lend themselves to the monitoring of precursory deformation prior to sinkhole development. In this paper, we outline the background to sinkhole formation and sinkhole hazard assessment. We provide a review of earth observation techniques, both for the compilation of sinkhole inventories as well as the monitoring of precursors to sinkhole development. We discuss the advantages and limitations of these approaches and conclude by highlighting the potential role of radar interferometry in the early detection of sinkhole-induced instability resulting in a potential decrease in the risk to human lives and infrastructure by enabling proactive remediation.