bluuebunny/crossref_metadata_2025 huggingface dataset:
Prey capture by the non‐native carnivorous pitcher plant Sarracenia purpurea across sites in Britain and Ireland
Authors: Whatmore Rebecca , Wood Paul J. , Dwyer Ciara , Millett Jonathan
Published: December 2022

The carnivorous pitcher plant Sarracenia purpurea is native to North America, but has been introduced into Europe, where it is now widespread. Understanding of how this species functions in its non‐native range is limited. We measured pitcher morphology and prey capture by S. purpurea in its non‐native range in Britain and Ireland. Pitchers were removed from different plants at each of six bogs covering the species range in Britain and Ireland (n = 10 pitchers per site). For each pitcher we counted and identified every prey item and took measurements of morphology. We also compiled prey capture data for existing studies in Europe and North America. Prey capture characteristics varied between sites in Britain and Ireland. The amount of prey captured varied 20‐fold between sites and was partially explained by differences in pitcher size; larger pitchers caught more prey. The primary prey was Formicidae, Diptera and Coleoptera. At the rank of order, prey composition varied between bogs, some contained mainly Formicidae, some mainly Diptera and some a mix. Prey capture was less evenly distributed at some bogs compared to others, suggesting more specialization. There was no overall difference in prey capture (composition or evenness) at the rank of order between plants in Europe compared to those in North America. At the rank of species, prey capture varied between populations even within the same order. This study demonstrates a large amount of variability between sites in prey capture characteristics. This may reflect different site characteristics and/or plant strategies, which will likely impact plant function, and may impact the inquiline community. In terms of prey capture at the rank of order, S. purpurea functions identically in its non‐native range. This supports its use as a model system in a natural experiment for understanding food webs.
eDNA metabarcoding reveals high soil fungal diversity and variation in community composition among Spanish cliffs
Authors: Krah Franz‐Sebastian , March‐Salas Martí
Published: December 2022

Environments characterized by physical extremes harbor unique species diversity with particular adaptations. Cliffs are harsh environments for organisms but host a great diversity of specialized plants with many endemics, rare and even endangered species. It is, however, less known which fungal diversity the cliff habitats contain and whether it differs among different cliff locations. We thus sampled soil from three separate cliff locations in the North, Centre, and South of Spain and used eDNA metabarcoding to determine fungal diversity. To better understand whether cliff specialist plants may promote particular fungal communities, we have sampled soil from crevices with cliff specialist plants and no apparent plants as controls. Major lifestyles found in cliff soils were saprotrophs, and major fungal orders were Dothideomycetes, Sordariomycetes, and Eurotiomycetes, while the amount of symbiotrophic fungi was relatively low. We found no significant differences in fungal amplicon sequence variant (ASV) richness among the three sampled locations, but the sites were significantly different in their community composition and their main indicator species. Overall, there were no significant differences in fungal ASV richness or composition between soils from cliff specialist plants and soils without plants, suggesting a unique fungal diversity in cliff soils independent from specialized plants. However, preliminary findings on soils of the specialist cliff plant Sedum dasyphyllum against control soils suggest that the presence of a specialist plant may be a relevant factor affecting the specificity of the fungal community in cliff soils. Our results indicate the existence of particular cliff fungal communities in each location, and that, despite limited and poorly developed soils and harsh conditions, cliffs can harbor a great diversity of fungal species, comparable to other ecosystems of Spain. This study points out that some fungi may be cliff‐specific, shaping particular communities that mediate plant adaptations to cliffs' extreme conditions.
Stemflow metazoan transport from common urban tree species (São Paulo, Brazil)
Authors: Lima Marcelle Teodoro , Urso‐Guimarães Maria Virginia , Van Stan John Toland , Tonello Kelly Cristina
Published: December 2022

For precipitation to reach the surface of vegetated ecosystems, it must first pass through the canopy. A portion of precipitation, stemflow, drains down branches to the stem. This stemflow may wash canopy‐dwelling animals (metazoans) into the litter and soils below; however, stemflow metazoans transport has typically been ignored in past research. In fact, the visual presence of metazoans in stemflow collection bins was reported as “contamination” in past research. Thus, we know little about these organisms' transfer from plant canopies to the surface. To investigate this topic, we monitored metazoan concentrations and composition within stemflow that drained from eight urban tree species (n = 3 per species) over 12 months. Annual (±SE) stemflow recorded from all 24 sampled trees was 19.6 (±3.3) mm (2.3% rainfall). Analysis of 288 samples found 1,307 individuals distributed into seven classes (16 orders) and one organism at phylum level. Considering all trees (n = 24), the annual mean metazoan density in stemflow was 8.6 individuals L−1. Among tree species, there were considerable variations, ranging from 1.0 to 17 individuals L−1. Annual metazoan transport per tree ranged from 20 to 376 individuals m−2y−1. The most common taxa observed in stemflow from this site included Arachnida (10%), Collembola (33%) and Insecta (56%). Variability in metazoan density within and across species was high, but individual trees with the highest metazoan stemflow density and flux were those with large diameter and exfoliating bark structure. This study demonstrates that stemflow can transport a substantial and diverse meso‐ and macro‐fauna to the surface of urban forests. Future work may be merited on the fate and/or role of these metazoans in litter and soil systems.
Turning up the heat: Long‐term water quality responses to wildfires and climate change in a hypereutrophic lake
Authors: De Palma‐Dow Angela , McCullough Ian M. , Brentrup Jennifer A.
Published: December 2022

Clear Lake (Lake County, CA, USA) is hypereutrophic and used for drinking water, tribal use, and supports a significant fishing economy. The Mendocino Complex (2018), one of the largest wildfires in California's post‐settlement history, burned 40% of the Clear Lake watershed, providing a timely opportunity to study the impacts of historical and current wildfires on this valuable aquatic resource. Using long‐term monthly monitoring data from 1968 to 2019, paired with historical watershed fire data, we found that for the three largest fire years in the watershed's history, 3‐year postfire median July–October epilimnetic total phosphorus (TP) concentrations were below or equal to 3‐year prefire TP concentrations. However, both median TP epilimnetic concentrations and deepwater temperature across the lake have increased since the late 1960s. Long‐term TP increases were more strongly correlated with monthly maximum air temperatures than precipitation, suggesting a potential role of warming‐induced water column stratification, dissolved oxygen (DO) depletion, and high potential for internal phosphorus loading. Hypoxic occurrences were correlated with higher hypolimnetic soluble reactive phosphorus and TP concentrations, but additional high‐frequency monitoring of DO will help determine the duration of anoxia and its contribution to internal phosphorus loading. These long‐term data suggest that for this large, hypereutrophic lake, wildfires did not significantly alter in‐lake TP concentrations based on long‐term, monthly monitoring and that other internal or external sources of TP may mask any wildfire effects. Nonetheless, our study underscores the value of synthesizing decades of water quality, watershed wildfire, and climate data to build a more comprehensive, nuanced picture of multiple long‐term threats to aquatic ecosystems under global change. Moreover, monitoring and studying fire effects across a wide range of lake types beyond this study will help promote more effective lake management during changing climates and increasingly frequent large wildfires.
Invasive rodent responses to experimental and natural hurricanes with implications for global climate change
Authors: Shiels Aaron B. , Ramírez de Arellano Gabriela E. , Shiels Laura
Published: December 2022

Hurricanes cause dramatic changes to forests by opening the canopy and depositing debris onto the forest floor. How invasive rodent populations respond to hurricanes is not well understood, but shifts in rodent abundance and foraging may result from scarce fruit and seed resources that follow hurricanes. We conducted studies in a wet tropical forest in Puerto Rico to better understand how experimental (canopy trimming experiment) and natural (Hurricane Maria) hurricane effects alter populations of invasive rodents (Rattus rattus [rats] and Mus musculus [mice]) and their foraging behaviors. To monitor rodent populations, we used tracking tunnels (inked and baited cards inside tunnels enabling identification of animal visitors' footprints) within experimental hurricane plots (arborist trimmed in 2014) and reference plots (closed canopy forest). To assess shifts in rodent foraging, we compared seed removal of two tree species (Guarea guidonia and Prestoea acuminata) between vertebrate‐excluded and free‐access treatments in the same experimental and reference plots, and did so 3 months before and 9 months after Hurricane Maria (2017). Trail cameras were used to identify animals responsible for seed removal. Rat incidences generated from tracking tunnel surveys indicated that rat populations were not significantly affected by experimental or natural hurricanes. Before Hurricane Maria there were no mice in the forest interior, yet mice were present in forest plots closest to the road after the hurricane, and their forest invasion coincided with increased grass cover resulting from open forest canopy. Seed removal of Guarea and Prestoea across all plots was rat dominated (75%–100% rat‐removed) and was significantly less after than before Hurricane Maria. However, following Hurricane Maria, the experimental hurricane treatment plots of 2014 had 3.6 times greater seed removal by invasive rats than did the reference plots, which may have resulted from rats selecting post‐hurricane forest patches with greater understory cover for foraging. Invasive rodents are resistant to hurricane disturbance in this forest. Predictions of increased hurricane frequency from expected climate change should result in forest with more frequent periods of grassy understories and mouse presence, as well as with heightened rat foraging for fruit and seed in preexisting areas of disturbance.
Spatial patterning of Wyoming big sagebrush indicates negative density dependence
Authors: Chenoweth Damaris A. , Burke Ingrid C. , Lauenroth William K.
Published: December 2022

Plants reflect resource use in their spatial patterning. Competition for limited resources—such as available soil water in a dryland ecosystem—drives establishment, growth, and mortality, resulting in shifts of spatial arrangement over time. We characterized the spatial patterning of two big sagebrush (Artemisia tridentata subspecies wyomingensis) communities in the upper Green River Basin of Wyoming, USA. We mapped big sagebrush canopies in two, 100‐m2 sites and calculated plant neighborhoods as the area closer to a target plant than to any other plant. We assumed that neighborhoods were areas in which the target plant dominates resource use. We found that plant neighborhoods had strong, positive correlations with plant size, indicating that larger neighborhoods may access more belowground resources. We also found that the relationships between experienced crowding, that is, crowding index (CI) by an average neighbor, and neighborhood size, were consistently negative regardless of calculation method. We also found that the residuals of a regression of target plant biomass and neighborhood area were strongly related to the CI calculated via all methods. This means that plants with smaller neighborhoods than expected also experience the greatest crowding by an average neighbor. These results are consistent with negative density dependence and show that greater static crowding predicts smaller neighborhoods in two, undisturbed, intermediate‐successional big sagebrush communities. In the future, similar studies of spatial patterning that include interspecific plant–plant interactions will be useful for understanding the relationship between spatial patterning and negative density dependence.
Multimodal pathogen transmission as a limiting factor in host distribution
Authors: Uricchio Lawrence H. , Bruns Emily L. , Hood Michael E. , Boots Mike , Antonovics Janis
Published: December 2022

Theoretical models suggest that infectious diseases could play a substantial role in determining the spatial extent of host species, but few studies have collected the empirical data required to test this hypothesis. Pathogens that sterilize their hosts or spread through frequency‐dependent transmission could have especially strong effects on the limits of species' distributions because diseased hosts that are sterilized but not killed may continue to produce infectious stages and frequency‐dependent transmission mechanisms are effective even at very low population densities. We collected spatial pathogen prevalence data and population abundance data for alpine carnations infected by the sterilizing pathogen Microbotryum dianthorum, a parasite that is spread through both frequency‐dependent (vector‐borne) and density‐dependent (aerial spore transmission) mechanisms. Our 13‐year study reveals rapid declines in population abundance without a compensatory decrease in pathogen prevalence. We apply a stochastic, spatial model of parasite spread that accommodates spatial habitat heterogeneity to investigate how the population dynamics depend on multimodal (frequency‐dependent and density‐dependent) transmission. We found that the observed rate of population decline could plausibly be explained by multimodal transmission, but is unlikely to be explained by either frequency‐dependent or density‐dependent mechanisms alone. Multimodal pathogen transmission rates high enough to explain the observed decline predicted that eventual local extinction of the host species is highly likely. Our results add to a growing body of literature showing how multimodal transmission can constrain species distributions in nature.
Exotic god fruit, persimmon (Diospyros kaki): Pharmacological importance and human health aspects
Authors: Choudhary Rita , Singh Anurag , Upadhyay Ashutosh , Singh Rakhi , Thangalakshmi S. , Dar Aamir H. , Bajpai Vivek K. , Shukla Shruti
Published: December 2022

The persimmon fruit (Diospyros kaki) belonging to the family Ebenaceae, is a famous conventional Korean medicinal herb. Calyx of persimmon has been used to prepare herbal drinks in Korea, China, and Japan due to its various functional ingredients, including fructose, glucose, and triterpenoid. In addition, persimmon is generally used as traditional medicine in Korea for the treatment of asthma, chronic bronchitis, and cough. Various useful constituents have been isolated and characterized from Diospyros species, including naphthaquinones, triterpenoids, and steroids. The fruit's nutritional composition comprising 80.3% water, 0.58% protein, 0.19% total lipids, 18.6% total carbohydrates and some minerals, and up to 1.48 g and 7.5 mg total dietary fiber, and ascorbic acid, respectively. Specifically, a flavonoid, fisetin, present in persimmon is associated with killing breast cancer cells without harming normal breast cells, thus contributing to the programmed eradication of colon and prostate cancer cells. Some other notable compounds reported from the various parts of the plant and their extracts have significant pharmaceutical values due to their antioxidant, anticancer, anti‐aging, and cytotoxic activities. It is, therefore, high time to promote the consumption of exotic fruits with a rich source of natural antioxidants as a functional supplement to the human diet, with a view to increase the disease protection efficacy.
BODIPY Immobilized MCM‐41 Based Multianalyte Sensor: Application in Detection and Removal of Trivalent (Al3+, Cr3+) and Divalent (Cu2+, Hg2+) Metal Ions in Aqueous Media
Authors: Chaudhary Garima , Pratap Singh Amit
Published: December 2022

In the present study, a novel p‐phenylcarboxylic acid BODIPY (L) immobilized MCM‐41 based solid chemosensor material L‐propylsilyl@MCM‐41 (MS4) was developed to detect multiple metal ions in a pure aqueous medium. The synthesized solid chemosensor material MS4 shows high sensitivity and removal ability towards trivalent (Al3+, Cr3+) and divalent (Cu2+, Hg2+) metal ions. The emission intensity of MS4 enhanced multifold selectively in the presence of trivalent (Al3+, Cr3+) metal ions and shows quenching in the presence of divalent (Cu2+, Hg2+) metal ions. The limit of detection was calculated to be in the nanomolar range with Al3+, Cr3+, Cu2+, and Hg2+ metal ions in the aqueous medium. The spectroscopic and analytical results suggest that MS4 selectively binds with Al3+ and Cr3+ through −NH functionality and with Hg2+ and Cu2+ through −COOH functionality of p‐phenylcarboxylic acid BODIPY (L). Further, MS4 selectively removes Al3+, Cr3+, Cu2+, and Hg2+ metal ions from the aqueous media with removal efficiency of 97.28 %, 96.34 %, 87.19 %, and 95.63 %, respectively. No noticeable change in the concentration was observed for other metal ions. The recycling potential of MS4 was evaluated using EDTA for up to seven cycles with no significant reduction in sensing capability.
Tandem Sulfonylation/Cyclization of Vinyl Azides with Aryldiazonium Tetrafluoroborates and SO2
Authors: Chen Fayun , Quan Li‐Xia , Zhou Anxi , Ji Congbin , Li Yanhong , Zhu Xianhong , Mao Liu‐Liang , Wan Jie‐Ping
Published: December 2022

An efficient and facile strategy for the synthesis of 6‐(sulfonylmethyl)phenanthridines and its derivatives has been developed via tandem sulfonylation cyclization of vinyl azides under mild conditions in the absence of any catalysts and additives. The reaction simply utilizes easily accessible and cheap K2S2O5as the sulfur dioxide source, delivering functionalized phenanthridines in moderate to excellent yields with operational simplicity and gram‐scale synthesis, as well as good functional‐group tolerance.
Simulating the response of buried structures to external blast loads: Methods, challenges, and advances
Authors: Keshavarz Mirza Mohammadi Payam , Khalilpour Seyed Hamed , Sareh Pooya
Published: December 2022

Various methods have been proposed to ensure the serviceability of buried structures such as road tunnels, urban utility tunnels, water conduits, underground shelters, and deposition chambers against extreme loads, the most common of which are experimental and computational methods. An external explosion in the vicinity of such structures is one of these extreme loads. In general, different types of external blasting for buried structures can be classified as surface blasting, coupled or uncoupled buried explosions, excavation by drilling and blasting near the structure, and the accidental detonation of explosive depositions. Laboratory or field tests for explosions are usually limited by financial and safety constraints; therefore, numerical simulations are often regarded as a vital tool in the study of such problems. Though computer software and hardware have improved rapidly in recent decades, and various numerical solvers have been developed, there is no universal method for solving all external explosion problems. Each numerical method can produce sensible results under certain conditions and assumptions, along with its limitations in computational cost. Consequently, these problems have been particularly difficult to investigate, and even in some cases, the results of different studies seem to be inconsistent. Besides providing an extensive review of the available literature in the field of numerical simulation of external explosions near buried structures and a discussion of the damage criteria associated with such explosions, this study also highlights some inconsistencies that may need further investigation.
A review on data‐centric decision tools for offshore wind operation and maintenance activities: Challenges and opportunities
Authors: Hadjoudj Yannis , Pandit Ravi
Published: December 2022

This paper reviews state‐of‐the‐art numerical tools for the operation and maintenance (O&M) of offshore wind farms, focusing on decision support models for maintenance scheduling and the consideration of human and environmental uncertainty. In this review, various factors that can influence the successful conduct of maintenance operations will be examined and special attention will be paid to the most significant ones. Data‐driven technologies for improved offshore asset management are also examined and the most used data‐driven methods for modeling and optimizing turbine operation and maintenance are presented. A focus will be placed on the choice of maintenance strategy, which is the basis for the planning of operations and thus the optimization problem discussed. As offshore maintenance is a complex operation whose efficiency and safety depend on human and environmental factors, special attention will be paid to the planning strategy that minimizes the risks involved while maximizing efficiency by considering these factors. The choice of planning technique for turbine maintenance and better consideration of uncertainties are crucial areas of improvement as they can lead to better overall efficiency, higher profit margins, better safety, and improved sustainability of offshore wind farms. The paper covers the application of digital technologies for offshore wind O&M planning and the associated challenges. The paper also highlights the various environmental and human factors to be considered for the operation and maintenance of wind turbines.
Heat transfer analysis in thermal energy storage—A comprehensive review‐based latent heat storage system
Authors: Kumar Alok , Kumar Arun
Published: December 2022

Thermal energy storage (TES) system is the most eminent storage method that aids in the power generation. Latent heat storage (LHS) is on the rapid mark‐up that fosters the TES with the utilization of the phase transition of a material to store the heat. Typically the phase change materials (PCM) are used in the LHS system to store the energy. During the material's phase transition, thermal energy is stored and released. Nevertheless, the low thermal conductivity of the PCM in the LHS is susceptible to deteriorate the charging and discharging of the thermal energy. Hence there is a necessity to enhance the thermal performance of the LHS system, on which various studies have been done. Therefore this paper aims in providing a review on the enhancements of the LHS system with improved heat transfer rate and heat transfer enhancement techniques in the PCM for better efficiency. A comprehensive review on the LHS system component is provided to make an emphasis on the heat transfer enhancement rate and storage time. Various characterizations and categories of the PCM are provided to intensify the outcomes of the review as PCMs are most viable materials for storing thermal energy. In addition the recent researches on the integration of PCM with other materials are also discussed that help in the improvements of the thermal conductivity of the PCM. The selection parameters of the PCM materials are also discussed in brief to avoid the poor performance of the PCMs. The heat transfer analysis methods are analyzed to improve the efficiency and reduce the heat loss. Finally, advancements in the future trends for the enhancement of heat transfer is provided.
Entropy‐based complex proportional assessment for efficient task scheduling in fog computing
Authors: Malathy Navaneetha Krishnan , Revathi Thiyagarajan
Published: December 2022

The tasks are offloaded to fog computing instead of cloud computing to enhance the quality of service (QoS) of internet of things (IoT) applications. Though it provides improved QoS the accessibility of unremitting computation properties of fog servers is one among the limitations of IoT applications as transmitting a huge quantity of data may induce more energy consumption, cost, and increased makespan. Much research has been made to build up an efficient technique to address the multi–objective task scheduling in fog computing. One such method used to solve multiple objective problems in different domains is multi–criteria decision–making methods (MCDM). The MCDM Method named complex proportional assessment (COPRAS) has risen in popularity due to simple and fast computation. In this paper, a task scheduling algorithm (ECOPRAS) based on the integration of the entropy weight method and COPRAS method is proposed. The proposed technique consists of two phases that is, Task prioritization, and Task assignment. In the first phase, the task is ordered based on the heuristic method, B‐level and in the second phase, the task will be assigned based on the ranking provided by the ECOPRAS method. The proposed method aims at minimizing energy consumption, price, and makespan and maximizing the reliability and utilization rate. The simulation results are compared with similar algorithms through various workflows and the proposed method outperforms well.
Influx of T cells into corpus callosum increases axonal injury, but does not change the course of remyelination in toxic demyelination
Authors: Yilmaz Elif Nur , Albrecht Stefanie , Groll Katharina , Thomas Christian , Wallhorn Lutz , Herold Martin , Hucke Stephanie , Klotz Luisa , Kuhlmann Tanja
Published: December 2022

Multiple sclerosis (MS) is a focal inflammatory and demyelinating disease. The inflammatory infiltrates consist of macrophages/microglia, T and B cells. Remyelination (RM) is an endogenous repair process which frequently fails in MS patients. In earlier studies, T cells either promoted or impaired RM. Here, we used the combined cuprizone/MOG‐EAE model to further dissect the functional role of T cells for RM. The combination of MOG immunization with cuprizone feeding targeted T cells to the corpus callosum and increased the extent of axonal injury. Global gene expression analyses demonstrated significant changes in the inflammatory environment; however, additional MOG immunization did not alter the course of RM. Our results suggest that the inflammatory environment in the combined model affects axons and oligodendrocytes differently and that oligodendroglial lineage cells might be less susceptible to T cell mediated injury.
In search of light in the darkness: What can we learn from ethical, sustainable and green investments?
Authors: Uddin Gazi Salah , Yahya Muhammad , Ahmed Ali , Park Donghyun , Tian Shu
Published: December 2022

We analyse time‐varying risk spillover and dependence to assess the systemic risk benefits of ethical, sustainable, and green investments. Our data comprise sustainable investments from ethical, environmental, social and governance (ESG), and green bonds. We investigate the link to major asset classes, including equity, commodity, and currency markets. We find evidence of close connection between the major asset classes and sustainable assets, except green bonds. We also explore the improvement in hedging efficiency from combining ethical and ESG investments with commodities and currencies over investment horizons. Our analysis based on systemic risk measures indicates that there is evidence of lower time‐scale systemic risk connectedness in the case of commodities and currencies combined with ethical and ESG assets. These findings have significant implications for portfolio managers, policymakers, and market participants.
Feasibility and impact of a postpartum hemorrhage emergency care package using a bundle approach in Migori County, Kenya
Authors: Gonte Madeleine R. , Peifer Hannah G. , Meara Grace , Otieno Brenda , Oguttu Monica , Burke Thomas F.
Published: December 2022

Objective

To investigate the impact of the PPH Emergency Care package (PPH EmC)—a holistic intervention that uses a bundle approach that has been implemented in Kenya, India, Nepal, Bangladesh, and Central America—in a low‐resource setting.

Methods

The feasibility and impact of PPH EmC implementation in Migori County, Kenya was studied using a qualitative research design. In March and April 2022 key informants were identified using purposive sampling. Semi‐structured interviews were conducted over Zoom from March to May 2022 until thematic saturation was reached. Interviews were transcribed, coded, and analyzed for emerging themes.

Results

PPH EmC has positively impacted facility and health system preparedness, referral coordination, teamwork and communication, and overall capacity to provide quality PPH emergency care. Participants reported that PPH EmC is sustainable because of its low cost and support from local partners.

Conclusion

Implementation of PPH EmC in Migori County, Kenya was feasible and positively impacted PPH emergency care.
Proton storage chemistry in aqueous zinc‐organic batteries: A review
Authors: Deng Xianming , Sarpong James Kumankuma , Zhang Guobin , Hao Jing , Zhao Xu , Li Linyuan , Li Hongfei , Han Cuiping , Li Baohua
Published: December 2022

Benefiting from the advantageous features of structural diversity and resource renewability, organic electroactive compounds are considered as attractive cathode materials for aqueous Zn‐ion batteries (ZIBs). In this review, we discuss the recent developments of organic electrode materials for aqueous ZIBs. Although the proton (H+) storage chemistry in aqueous Zn‐organic batteries has triggered an overwhelming literature surge in recent years, this topic remains controversial. Therefore, our review focuses on this significant issue and summarizes the reported electrochemical mechanisms, including pure Zn2+ intercalation, pure H+ storage, and H+/Zn2+ co‐storage. Moreover, the impact of H+ storage on the electrochemical performance of aqueous ZIBs is discussed systematically. Given the significance of H+ storage, we also highlight the relevant characterization methods employed. Finally, perspectives and directions on further understanding the charge storage mechanisms of organic materials are outlined. We hope that this review will stimulate more attention on the H+ storage chemistry of organic electrode materials to advance our understanding and further its application.

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Fast optical‐writing recognition based on two‐dimensional photothermoelectric effect assisted with deep learning
Authors: Zhong Yujia , Fang Haoyu , Ran Yutong , Zhu Hongwei
Published: December 2022

The photothermoelectric (PTE) effect enables a simple structure to construct a noncontact and self‐powered writing device. PTE detectors based on active materials and one‐dimensional (1D) position‐sensitive PTE effect have attracted considerable attentions. However, there is no research on applying the 1D position‐sensitive PTE effect to a two‐dimensional (2D) surface. Besides, flexible writing devices based on the PTE effect have not been reported. Here, we demonstrate a self‐powered flexible optical writing device based on the 2D position‐sensitive PTE effect of SnSe thin film. Laser positioning, tracking, and distinguishing of optically written characters have been realized by only measuring the bi‐directional output voltages during the writing process. A deep convolutional neural network has been introduced to recognize optically written numbers and characters with high recognition accuracy (92%) and fast processing speed (8.6 ms). The flexible optical‐writing device with a simple structure could rapidly and accurately recognize characters in a noncontact fashion using a small amount of training data.

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Oxygen‐modulated metal nitride clusters with moderate binding ability to insoluble Li2Sx for reversible polysulfide electrocatalysis
Authors: Cheng Menghao , Xing Zhenyu , Yan Rui , Zhao Zhenyang , Ma Tian , Zhou Mi , Liu Xikui , Li Shuang , Cheng Chong
Published: December 2022

Multiphase sulfur redox reactions with advanced homogeneous and heterogeneous electrochemical processes in lithium–sulfur (Li–S) batteries possess sluggish kinetics. The slow kinetics leads to significant capacity decay during charge/discharge processes. Therefore, electrocatalysts with adequate sulfur‐redox properties are required to accelerate reversible polysulfide conversion in cathodes. In this study, we have fabricated an oxygen‐modulated metal nitride cluster (C‐MoNx‐O) that has a moderate binding ability to the insoluble Li2Sx for reversible polysulfide electrocatalysis. A Li–S battery equipped with C‐MoNx‐O electrocatalyst displayed a high discharge capacity of 875 mAh g−1 at 0.5 C. The capacity decay rate of each cycle was only 0.10% after 280 cycles, which is much lower than the control groups (C‐MoOx: 0.16%; C‐MoNx: 0.21%). Kinetic studies and theoretical calculations suggest that C‐MoNx‐O electrocatalyst presents a moderate binding ability to the insoluble Li2S2 and Li2S when compared to the C‐MoOx and C‐MoNx surfaces. Thus, the C‐MoNx‐O can effectively immobilize and reversibly catalyze the solid–solid conversion of Li2S2–Li2S during charge–discharge cycling, thus promoting reaction kinetics and eliminating the shuttle effect. This study to design oxygen‐doped metal nitrides provides innovative structures and reversible solid–solid conversions to overcome the sluggish redox chemistry of polysulfides.

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Effect of near‐infrared and blue laser light on vero E6 cells SARS‐CoV‐2 infection model
Authors: Zupin Luisa , Clemente Libera , Fontana Francesco , Crovella Sergio
Published: December 2022

Photobiomodulation therapy (PBMT) employing laser light has been emerging as a safe strategy to challenge viruses. In this study the effect of blue and near‐infrared (NIR) laser light was assessed in an in vitro model of SARS‐CoV‐2 infection. PBMT at blue wavelength inhibited viral amplification when the virus was directly irradiated and then transferred to cell culture and when cells already infected were treated. The NIR wavelength resulted less efficacious showing a minor effect on the reduction of the viral load. The cells receiving the irradiated virus or directly irradiated rescued their viability to level comparable to not treated cells. Virion integrity and antigenicity were preserved after blue and NIR irradiation, suggesting that the PBMT antiviral effect was not correlated to viral lipidic envelope disruption. Our results suggested that PBMT can be considered a valid strategy to counteract SARS‐CoV‐2 infection, at least in vitro.
Miniature intravascular photoacoustic endoscopy with coaxial excitation and detection
Authors: Lin Riqiang , Zhang Qi , Lv Shengmiao , Zhang Jiaming , Wang Xiatian , Shi Dongliang , Gong Xiaojing , Lam Kwok‐ho
Published: December 2022

Recent research pointed out that the degree of inflammation in the adventitia could correlate with the severity of atherosclerotic plaques. Intravascular photoacoustic endoscopy can provide the information of arterial morphology and plaque composition, and even detecting the inflammation. However, most reported work used a noncoaxial configuration for the photoacoustic catheter design, which formed a limited light‐sound overlap area for imaging so as to miss the adventitia information. Here we developed a novel 0.9 mm‐diameter intravascular photoacoustic catheter with coaxial excitation and detection to resolve the aforementioned issue. A miniature hollow ultrasound transducer with a 0.18 mm‐diameter orifice in the center was successfully fabricated. To show the significance and merits of our design, phantom and ex vivo imaging experiments were conducted on both coaxial and noncoaxial catheters for comparison. The results demonstrated that the coaxial catheter exhibited much better photoacoustic/ultrasound imaging performance from the intima to the adventitia.
Intraoperative detection ofIDH‐mutant glioma using fluorescence lifetime imaging
Authors: Noble Anbunesan Silvia , Alfonso‐Garcia Alba , Zhou Xiangnan , Bec Julien , Lee Han Sung , Jin Lee‐Way , Bloch Orin , Marcu Laura
Published: December 2022

Identifying isocitrate dehydrogenase (IDH)‐mutation and glioma subtype during surgery instead of days later can aid in modifying tumor resection strategies for better survival outcomes. We report intraoperative identification of IDH‐mutant glioma (N = 12 patients) with a clinically compatible fluorescence lifetime imaging (FLIm) device (excitation: 355 nm; emission spectral bands: 390/40 nm, 470/28 nm, 542/50 nm). The fluorescence‐derived parameters were analyzed to study the optical contrast between IDH‐mutant tumors and surrounding brain tissue. IDH‐mutant oligodendrogliomas exhibited shorter lifetimes (3.3 ± 0.1 ns) than IDH‐mutant astrocytomas (4.1 ± 0.1 ns). Both IDH‐mutant glioma subtypes had shorter lifetimes than white matter (4.6 ± 0.4 ns) but had comparable lifetimes to cortex. Lifetimes also increased with malignancy grade within IDH‐mutant oligodendrogliomas (grade 2: 2.96 ± 0.08 ns, grade 3: 3.4 ± 0.3 ns) but not within IDH‐mutant astrocytomas. The current results support the feasibility of FLIm as a surgical adjuvant for identifying IDH‐mutant glioma tissue.
Beta 2 Adrenergic Receptor Selective Antagonist Enhances Mechanically Stimulated Bone Anabolism in Aged Mice
Authors: E. Worton Leah , Srinivasan Sundar , Threet DeWayne , Ausk Brandon J. , Huber Phillipe , Y. Kwon Ronald , Bain Steven D. , Gross Ted S. , M. Gardiner Edith
Published: December 2022

The anabolic response of aged bone to skeletal loading is typically poor. Efforts to improve mechanotransduction in aged bone have met with limited success. This study investigated whether the bone response to direct skeletal loading is improved by reducing sympathetic suppression of osteoblastic bone formation via β2AR. To test this possibility, we treated aged wild‐type C57BL/6 mice with a selective β2AR antagonist, butaxamine (Butax), before each of nine bouts of cantilever bending of the right tibia. Midshaft periosteal bone formation was assessed by dynamic histomorphometry of loaded and contralateral tibias. Butax treatment did not alter osteoblast activity of contralateral tibias. Loading alone induced a modest but significant osteogenic response. However, when loading was combined with Butax pretreatment, the anabolic response was significantly elevated compared with loading preceded by saline injection. Subsequent studies in osteoblastic cultures revealed complex negative interactions between adrenergic and mechanically induced intracellular signaling. Activation of β2AR by treatment with the β1, β2‐agonist isoproterenol (ISO) before fluid flow exposure diminished mechanically stimulated ERK1/2 phosphorylation in primary bone cell outgrowth cultures and AKT phosphorylation in MC3T3‐E1 pre‐osteoblast cultures. Expression of mechanosensitive Fos and Ptgs2 genes was enhanced with ISO treatment and reduced with flow in both MC3T3‐E1 and primary cultures. Finally, co‐treatment of MC3T3‐E1 cells with Butax reversed these ISO effects, confirming a critical role for β2AR in these responses. In combination, these results demonstrate that selective inhibition of β2AR is sufficient to enhance the anabolic response of the aged skeleton to loading, potentially via direct effects upon osteoblasts. © 2022 The Authors. JBMR Plus published by Wiley Periodicals LLC on behalf of American Society for Bone and Mineral Research.
Serum brain‐derived neurotrophic factor in coronary heart disease: Correlation with the T helper (Th)1/Th2 ratio, Th17/regulatory T (Treg) ratio, and major adverse cardiovascular events
Authors: Huo Yanfei , Feng Qiang , Fan Jie , Huang Jing , Zhu Yanling , Wu Yanqiang , Hou Aijun , Zhu Lin
Published: December 2022

Background

Brain‐derived neurotrophic factor (BDNF) exerts protective roles against dyslipidemia, atherosclerosis, and inflammation in cardiovascular diseases; meanwhile, it retards CD4+ T cell differentiation into T helper (Th)1 and Th17 cells. Hence, this study aimed to investigate the linkage of serum BDNF with Th1/Th2 ratio, Th17/regulatory T (Treg) ratio, and major adverse cardiovascular events (MACE) risk in the coronary heart disease (CHD) patients.

Methods

This prospective study detected serum BDNF in 210 CHD patients, 50 disease controls (DCs), and 50 healthy controls (HCs) using an enzyme‐linked immunosorbent assay. For CHD patients only, the proportion of Th1, Th2, Th17, and Treg cells in blood CD4+ T cells was calculated by flow cytometry.

Results

The BDNF varied among CHD patients, DC, and HC (p < 0.001). Specifically, BDNF was declined in CHD patients compared with DCs (p < 0.001) and HCs (p < 0.001). In CHD patients, BDNF was negatively related to Th1 cells (p = 0.031), Th1/Th2 ratio (p = 0.026), Th17 cells (p = 0.001), and Th17/Treg ratio (p = 0.002). Concerning the prognosis, BDNF was reduced in patients with MACE occurrence compared to patients without MACE occurrence (p = 0.006). Furthermore, BDNF showed a trend (lacked statistical significance) to relate to longer MACE‐free survival (p = 0.059). Besides, BDNF was related to the absence of obesity (p = 0.019), decreased total cholesterol (p = 0.043), low‐density lipoprotein cholesterol (p = 0.019), C‐reactive protein (p = 0.012), and Gensini score (p = 0.005).

Conclusion

Serum BDNF negatively correlates with Th1/Th2 ratio, Th17/Treg ratio, and estimates lower MACE risk in CHD patients.
Discounting of outcomes in which immediate gains are followed by delayed losses
Authors: Estle Sara J. , Green Leonard , Myerson Joel , Yeh Yu‐Hua
Published: December 2022

Previous discounting research has focused on relatively simple situations (e.g., choosing between immediate and delayed gains, or between immediate and delayed losses) and the relations among amount, delay, and subjective value in such situations are now well established. Many everyday choice situations, however, are more complex, involving alternatives that combine gains and losses. In two experiments, participants discounted a monetary outcome that combined an immediate gain with a delayed loss. Consistent with the discounting framework, the value of the combination was approximately equal to the difference between the (undiscounted) value of the immediate gain and the (discounted) value of the delayed loss. More precise predictions of the relative subjective value of the delayed loss component of a combination were given by the same hyperboloid function that describes discounting in simple choice situations where outcomes only involve gains or losses, not both. As in previous studies, when the outcome was a simple one consisting of only a delayed loss, discounting was not affected by the amount of that loss. Surprisingly, however, when the loss was preceded by a gain, the degree to which the combination was discounted was affected by the amount of the loss. Notably, discounting of the delayed loss component of the combination decreased with the amount of the loss in a fashion similar to that observed with simple delayed gains, where smaller amounts are discounted more steeply than larger amounts. Choice situations involving immediate gains followed by delayed losses pose iconic self‐control problems, and the present findings support the application of the discounting framework to these important everyday problems.
Excursions in Rorschachlandia: Surveying the scientific and philosophical landscape of Hermann Rorschach's Psychodiagnostics
Authors: Acklin Marvin W.
Published: December 2022

This article examines the milieu of Hermann Rorschach's Psychodiagnostics (1921/2021) under development between 1911 and his death in 1922 and explores new evidence about the direction Rorschach's test might have taken after publication of Psychodiagnostics. This includes direct and indirect influences from turn of the century continental philosophy and science and innovative colleagues in the Swiss psychiatric and psychoanalytic societies. The availability of newly translated scholarship, including the correspondence between Ludwig Binswanger and Hermann Rorschach following the 1921 publication of Psychodiagnostics, Binswanger's posthumous 1923 commentary in the International Journal of Psychoanalysis, and recent new translation of Psychodiagnostics, permits a fresh appraisal of the milieu and foundations of Rorschach's development. Understanding these sources and influences opens new vistas in reappraising the nature of Rorschach's “test theory” which Rorschach considered undeveloped at the time of his death. This paper presents new evidence that, under the influence of Rorschach's close colleague, Ludwig Binswanger, the Geisteswissenschaften and phenomenology might have figured prominently in future developments. The paper concludes that Rorschach, preoccupied with considerations of kinesthetic subjectivity in his innovative conceptualization of human movement responses, was a nascent phenomenologist whose untimely death cut short further developments in his theory of the test.
How do belowground bedrock fissures impact soil erosion on karst hillslopes under different rainfall intensity conditions?
Authors: Fang Qian , Zhao Longshan , Fan Chunhua , Fang Fayong , Zi Ruyi , Qian Xiaohe , Li Kaifeng
Published: December 2022

In karst regions, bedrock fissures are developed via karstification, which may cause belowground soil erosion (BSE). However, few studies have quantitatively assessed the effect of bedrock fissures on BSE because BSE measurement is difficult on karst hillslopes. The objective of this study was to investigate the differences in runoff and soil erosion at the surface and belowground on karst hillslopes with and without bedrock fissures (hereafter called HS1 and HS2, respectively) under different rainfall intensities (50, 75, and 100 mm hr−1). The slope gradient was 5°. In the rainfall process, surface runoff (SR), subsurface runoff (SBR), soil–rock interface flow (SRIF), and underground fissure flow (UFF) data were collected on HS1 and HS2. The results showed that the SR coefficients of HS1 and HS2 were negligible (less than 1%) under rainfall intensities of 50 and 75 mm hr−1, and UFF (56%–57%) of HS1 and SRIF (40%–44%) of HS2 dominated the runoff pattern. Under a rainfall intensity of 100 mm hr−1, the SR coefficient increased to approximately 30% under the two treatments, and the coefficients of UFF of HS1 and SRIF of HS2 decreased to 29% and 24%, respectively. Compared to HS2, UFF of HS1 increased by 18%–39%. The SBR coefficient was lower than 10% for all rainfall events. Because SR and SBR were low under rainfall intensities of 50 and 75 mm hr−1, the soil loss was dominated by UFF (99%–100% of the total sediment) of HS1 and by SRIF (86%–97% of the total sediment) of HS2. Under the 100 mm hr−1 rainfall intensity, almost all sediment was lost via SR under the two treatments, and the sediment loss of HS2 was 33% higher than that of HS1. Our results indicated that bedrock fissures caused more underground rainwater leakage at the SRI and further decreased surface soil erosion on karst hillslopes.
Existence of multiple solutions for a wide class of differential inclusions†
Authors: Cianciaruso Filomena , Pietramala Paolamaria
Published: December 2022

We give a unified approach to study the existence of multiple positive solutions of nonlinear differential inclusions of the form
subject to various nonlocal boundary conditions. We study these problems via a perturbed integral inclusion of the form .