bluuebunny/crossref_metadata_2025 huggingface dataset:
FORMAÇÃO E PROFISSIONALIZAÇÃO DOCENTE: PONDERAÇÕES CONTEMPORÂNEAS
Authors: Do Nascimento Bruna Gonçalo , De Oliveira Francisca Fabiana Bento , Andrade Beatriz de Pontes Medeiros , Bôto Anne Heide Vieira , Gomes Maria de Fátima Cavalcante , De Sousa Maria Fabilene Bento Oliveira , E Sales Maria Julieta Fai Serpa , Cavalcante Maria Marina Dias
Published: August 2023

O presente artigo discute acerca de aspectos históricos acerca da formação e profissionalização docente no Brasil, que se delineia a partir de uma linha cronológica do século XVI, abordando seus reflexos na sociedade contemporânea. Diante disso, o objetivo geral consiste em analisar o processo histórico de formação e profissionalização docente no Brasil e suas reverberações na atualidade. O percurso metodológico constitui-se de abordagem qualitativa, tendo como método um estudo de caráter bibliográfico, que se respalda em um levantamento de obras científicas publicadas, com aporte teórico de Nóvoa (1999), Saviani (2008) e Vicentini e Lugli (2009). Nesse decurso, observa-se avanços e retrocessos, vivenciados no seio da sociedade capitalista no Brasil. Ademais, percebe-se a intensidade da luta dos professores por melhorias, bem como o reconhecimento de sua profissão ao longo do período analisado. Conclui-se que o processo de formação e profissionalização docente é marcado por desafios e conquistas ao longo da História, com reverberações na educação e na formação de seres humanos.
Consequências de relações destrutivas
Authors: Ally Elizabeth Zamerul
Published: August 2023

As relações destrutivas são aquelas que ultrapassam os limites e acabam deixando uma marca profunda nos envolvidos. Geralmente elas são causadas por ciúme excessivo, descontrole emocional, obsessão ou até mesmo por gostar demais do outro. Quando esses fatores saem do controle podem gerar inúmeras consequências como ansiedade, depressão, violência e outros problemas físicos e psiquiátricos mais graves. E este tipo de relação gera consequências nas outras áreas da vida, prejudicando muito a qualidade de vida dos envolvidos e, por isso, merece atenção.
Using E-Module in Guidance Lessons to Enhance Multicultural Self-Efficacy of Islamic and Public High School Students
Authors: Yosef Yosef , Rozzaqyah Fadhlina , Rahmi Rahmi , Marwah Alika S , Vilala Vin
Published: August 2023

The implication of multiculturally Islamic and public high schools for guidance and counseling was how to help students enhance multicultural self-efficacy using self-learning electronic based-materials. The current study examined the effect of using an e-module of guidance lessons on students' multicultural self-efficacy. It constituted 10th graders of an Islamic High School (IHS) and a Public High School (PHS) as its samples. A Multicultural Self-Efficacy Scale (MSES) was employed to measure students' multicultural self-efficacy before and after completing the self-instruction of the guidance lesson comprising five units of an e-module. The study analyzed the data sets employing a paired sample t-test, independent t-tests, and N-gain techniques to test the hypotheses. The results revealed the significant effect of using the e-module on the multicultural self-efficacy of Islamic and public high school students, no significant differences between the multicultural self-efficacy of IHS and PBS students, and the value of using the e-module was at a moderate level for both groups. In conclusion, using the e-module could provide a functional account of guidance lessons to increase multicultural self-efficacy among students of IHS and PHS.
Exploring the Influence of a Single Bout of Tahajjud Prayer on Acute Blood Pressure Response in Normotensive Young Adult Males with Varied Regularity of Tahajjud Practice
Authors: Yusni Yusni , Yusuf Hanifah , Yahya Mustanir
Published: August 2023

Tahajjud, a type of sunnah worship for Muslims, involves standard rules and complex movements that contribute to cardiovascular health and blood pressure regulation. Aims and scope: This study aimed to analyze the effect of a single bout of tahajud, on systolic (SBP) and diastolic blood pressure (DBP) in normotensive young men. The study employed an experimental design with healthy men aged 18-25 and normal blood pressure (normotensive). It included a control group (n = 12) that did not perform Tahajjud and a trial group (n = 12) that regularly practiced Tahajjud for over six weeks. The treatment involved performing Tahajjud consisting of 11 raka'at from 3:30-4:30 a.m., lasting 25-35 minutes. Blood pressure was measured using a sphygmomanometer before and after Tahajjud, and data analysis utilized a t-test (p < .05). These findings indicate that there is a non-significant difference in the mean of SBP and DBP after midnight between the control and trial groups, SBP (mmHg): 110.42±9.16 and 114.58±4.98 vs 120±6.03, p = .11 and 115±6.74, p = .08. DBP (mmHg): 76.77±4.92 and 77.50±4.52, p = .58 vs. 81.67±8.35 and 79.17±5.15, p = .19, SBP and DBP decreased by 5 mmHg and 2.5 mmHg in the trial group. Tahajjud, regardless of regularity, can elicit a modest but non-significant reduction in both SBP and DBP. These results indicate that Tahajjud may have a potential role in promoting cardiovascular health. Further research is warranted to examine the long-term effects and underlying mechanisms of Tahajjud on BP regulation.
THE FIRST REPORT ON HOVER-FLIES (DIPTERA, SYRPHIDAE) FROM THE ANYUY NATIONAL PARK (KHABAROVSKY KRAI)
Authors:   Amur State University of Humanities and Pedagogy, Komsomolsk-na-Amure, Russia, Mutin V.A.
Published: August 2023

A list of 105 species of hover-flies from 39 genera discovered in the Anyuy National Park is given. All species are new for this territory. Portevinia dispar (Hervé-Bazin, 1929) is recorded from Khabarovsky krai for the first time. The taxonomic status, distribution and ecology of some species are discussed.
TO THE FAUNA OF THE DIGGER WASPS FAMILY SPHECIDAE (HYMENOPTERA: APOIDEA) OF THE KHINGAN NATURE RESERVE, AMURSKAYA OBLAST
Authors:   Khingan State Nature Reserve, Arkhara, Amurskaya oblast, Russia, Kochetkov D.N.
Published: August 2023

Ten species in five genera of the digger wasps family Sphecidae are found in the Khingan Nature Reserve, of them six species are new for this restricted area. Sphex funerarius Gussakovskij, 1934 and Prionyx subfuscatus (Dahlbom, 1845) are reported from Amurskaya oblast for the first time and Podalonia hirsuta (Scopoli, 1763) is new for the fauna of Russian Far East. The genera Prionyx Vander Linden, 1827 and Sphex Linnaeus, 1758 are reported for Amurskaya oblast for the first time. The taxonomic composition of the fauna of Sphecidae is briefly discussed. Majority of species founded in the Khingan Reserve are Transpalaearctic.
RESISTANCE OF PROMISING POTATO VARIETIES TO THE MOST IMPORTANT BEETLE PESTS IN THE CONDITIONS OF THE NORTHWEST OF THE EUROPEAN PART OF RUSSIA AND THE SOUTH OF THE FAR EAST
Authors:   Federal State Budget Scientific Institution «All-Russian Research Institute for Plant Protection», Saint-Petersburg, Russia, Fasulati S.R. , Ivanova О.V. ,   Federal State Budget Scientific Institution «All-Russian Research Institute for Plant Protection», Saint-Petersburg, Russia, Ermak М.V. ,   Federal State Budget Scientific Institution «Federal Scientific Center of Agricultural Biotechnology of the Far East named after A.K. Chaikа», Primorsky Krai, Ussuriysk, Russia
Published: August 2023

The article provides the results of evaluation of 10 promising potato varieties for the group resistance to the Colorado potato beetle Leptinotarsa decemlineata Say and to the Potato ladybird Henosepilachna vigintiomaculata Motsch. The researches were performed by field methods with artificial colonization of plants of the studied varieties in 1st instar, in the quantity of 30–100 larvae for each potato variety, and were held: according to the Colorado beetle – on experimental field of the All-Russian Research Institute for Plant Protection (Saint-Petersburg – Pushkin); according to the potato ladybird – on experimental field of the Federal Scientific Center of Agricultural Biotechnology of the Far East named after A.K. Chaikа (Primorsky Krai, Ussuriysk). Examples of potato varieties from the new assortment confirm the significant similarity (parallelism of developing) of the trophic reactions of both species, which have the same type of nutrition and many similar features of development biology. As the first result, it has shown that the Severnyi and Smak varieties have a group resistance to both phytophages with a survival of 10–20% of larvae before pupation. In other side, the Avgustin and Dalnevostochnyi varieties noted as a favourable for the development of these pests with a survival of 45–75% of larvae.
FAUNA AND SPATIAL DISTRIBUTION OF GROUND BEETLES (COLEOPTERA: CARABIDAE) ON THE CHEKHOV MOUNTAIN, SAKHALIN ISLAND
Authors:   The Sakhalin Regional Museum of Local Lore, Yuzhno-Sakhalinsk, Russia, Vertyankin A.V.
Published: August 2023

Totally 61 species of ground beetles are known from the Chekhov Mountain (Susunai Range, Sakhalin Island), of which 21 species are recorded from here for the first time. The results of collecting ground beetles in 9 model plots in 2021-2022 are analyzed. Three complexes of ground beetle communities are identified: I – floodplain low-mountain; II – low-mountain forest and meadow; III – alpine.
THE GROUND BEETLES (COLEOPTERA, CARABIDAE) OF THE ANYUY NATIONAL PARK, KHABAROVSKY KRAI
Authors:   Federal State-Funded Institution «Zapovednoye Priamurye», Komsomolsk-na-Amure, Russia, Kuberskaya O.V. , Sundukov Yu.N. ,   Federal Scientific Center of the East Asia Terrestrial Biodiversity, Far Eastern Branch of the Russian Academy of Sciences, Vladivostok 690022, Russia
Published: August 2023

An annotated list of 123 species from 36 genera, 21 tribes and 10 subfamilies of Carabidae collected in the Anyuy National Park (Khabarovsky krai, Russia) is given. Fore species, Bembidion lissonotum, B. lucillum, B. shimoyamai, and Tachyura exarata, are recorded from Khabarovsky krai for the first time and 65 species are new for the fauna of Anyuy Park.
DIGITALIZATION OF PROCEDURES IN SPATIAL PLANNING AND CONSTRUCTION LAW IN CROATIA
Authors: Held Mateja
Published: August 2023

Spatial planning and construction are interdisciplinary areas in which various factors interweave, such as sociological, cultural, economic, environmental, etc. In the process of spatial planning, green and digital transformation has an indispensable role. Spatial plans’ developers should take into account protection of the environment, which is emphasized in the soft law mechanisms of the European Union (such as the European Green Deal) and the national spatial planning legislation. The aim of the paper is to present the EU legislation on the digitalization of spatial planning which reflects principles of the good administration as laid out in the Charter of the European Union on Fundamental Rights (effective, efficient and transparent public administration) and to research whether Croatia has suitable legislative framework for the digitalization in the area of spatial planning and construction. An additional goal is to research whether the legislative framework is functional and whether obstacles occur in practice. The paper is therefore divided in five chapters. After the introduction, the paper presents EU legislation, namely the so-called INSPIRE directive which serves as a basic tool for the harmonization of EU Member State’s policies regarding environmental questions and as a basis for the national spatial data infrastructures. The next chapter analyzes Croatian response to the INSPIRE directive after the accession of Croatia into the EU in 2013, till the recently adopted Digital Strategy of Croatia in 2023. After the insight into the context of the digitalization of Croatian public administration sector, research is focused on the Regulatory Framework of the Physical Planning Information System and on the reflection of the digitalization in procedures of the protection of the objective legality and subjective rights of the citizens. In those procedures, citizens are considered as collaborators who participate in the process of the spatial plan development. In the final part of the paper, recommendations are given for a better functioning of the digitalized procedures in the area of spatial planning and construction law in Croatia.
Innovation and Challenges in Male Contraception
Authors: Sahu Aastha , Sharma Harish , Nema Rajesh Kumar , Sahu Gyanesh Kumar
Published: August 2023

The unwanted cases of pregnancy have increased resulting in improper family planning and cases of depression or stillbirth. The decision regarding reproduction is shared equivalently by men and women. Although the contraception methods result in effectiveness, they have more complications than effective results. Hormonal disbalance and endometriosis are a few such examples. Contraception for males is limited, yet has more effective results and fewer complications. The development of male contraception is vastly researched over the past few decades. Various hormonal and non-hormonal methods are being developed to provide better contraception with minimum or no disadvantage. The basic advantage of developing a male contraceptive includes its availability, low cost, no side effects, and ease of use.
Tıp Eğitiminde Program Çıktılarının UÇEP-2020 Yeterliklerine Göre Güncellenmesi: Akdeniz Üniversitesi Tıp Fakültesi Deneyimi
Authors: GÜRPINAR Erol , ŞENOL Yeşim , BOSTANCI TOPTAŞ Aslı , BOZTUĞ Neval , SARIKÇIOĞLU Levent , ALİMOĞLU Mustafa Kemal , ÇETİNKAYA Ramazan , TURHAN Murat , ÖZKAN Özlenen
Published: August 2023

Amaç: Çalışmanın amacı UÇEP-2020 doğrultusunda Akdeniz Üniversitesi Tıp Fakültesi, program çıktılarının revizyon sürecinin tanıtılmasıdır.
Yöntem: UÇEP-2020’nin yayınlanması ile birlikte, Akdeniz Üniversitesi Tıp Fakültesi Program çalışmalarının güncellenmesi işlemi 2020-2021 eğitim döneminde iç paydaşların geniş katılımı ile başlatılmıştır.
Bulgular: UÇEP-2020’ye göre programın yeterlikleri ve kazanımları yeniden düzenlenmiş, dönem, ders kurulu/staj ve derslerin çıktıları gözden geçirildi. Bazı eksik yeterlikler ve kazanımlar Fakülte yeterlik listesine eklendi. Hazırlanan yeterlik listeleri soru bankasına girildi.
Sonuç: Akdeniz Üniversitesi tıp fakültesi mezuniyet çıktıları iç paydaşların geniş katılımı ile gözden geçirilmiştir. Bu sürecin eğitimde hesap verilebilirlik ve kalite güvencesi sürecine katkı sağlayacağı düşünülmektedir. Deneyimlerimiz, benzer süreci kurumlarında başlatmak isteyen diğer tıp fakülteleri için yol gösterici olabilir.
Opinions of the Families of Nursing Students on Distance Education During the Covid-19 Pandemic
Authors: ŞEN Yağmur , ULUPINAR Sevim , ULUPINAR Sevim , GÜNGÖR BEKE Merve , KAYA Prof.dr.hülya
Published: August 2023

Aim: Distance education is an interdisciplinary field that aims to remove the limitation between educator, learner, and learning resources and of uses existing information and communication technologies for this purpose. Maintaining social distance, especially during the pandemic, has been instrumental in protecting and maintaining the health of both students and educators. However, distance education's entry into our lives as a necessity during the pandemic has brought many problems. The fact that the education environment left the classroom and came into the home, and that time shared with family members is now used for education, makes it necessary to conduct studies to determine families' experiences, attitudes, and opinions about distance
education. This study aimed at determining families’ opinions of undergraduate and graduate nursing students on distance education during the Covid-19 pandemic.
Methods: This is a descriptive and cross-sectional study. The study was conducted with 407 participants. The data were collected between the 9th and 10th months of the pandemic, with the data collection tool developed by the researchers.
Results: The families have a negative opinion on distance education, and these opinions were affected by their negative experiences and problems. The families found the low costs and the increased time the students spent with their families to be positive aspects of distance education. The families complained about connection problems, the student spending too much time on the computer and about the home environment needing to be more suitable for education. However, negative opinions of the families included that distance education is insufficient in conveying professional skills and that distance education is not suitable for nursing education. The opinions of Y-generation family members, those with graduate education, and those with a permanent internet connection at home had more positive opinions than the others.
Conclusions: Distance education has become an integral part of our lives. Therefore, it is essential to unearth problems regarding distance education and develop solutions. Study results on the opinions, attitudes, and experiences of all distance education stakeholders will contribute to distance education practices.
PENGARUH CORPORATE SOCIAL RESPONSIBILITY TERHADAP CORPORATE FINANCIAL PERFORMANCE ( ROA DAN ROE ) (Studi Kasus Pada Perusahaan Perbankan Yang terdaftar Di Bursa Efek Indonesia)
Authors: B11212100 FEBRIANAWATI
Published: August 2023

Tujuan dari penelitian ini adalah untuk menganalisis pengaruh Corporate Social Responsibility terhadap Corporate Financial Performance. Obyek penelitian yang digunakan adalah industri perbankan dengan total 60 perusahaan yang terdaftar (listing) di Bursa Efek Indonesia (BEI) pada tahun 2010 – 2012. Variabel independen dalam penelitian ini adalah corporate social responsibility, variabel dependennya adalah return on equity (ROE) dan Return on Asset (ROA) sementara variabel kontrol dalam penelitian ini adalah firm size. Analisis data yang digunakan adalah analisis regresi sederhana. Hasil penelitian ini menunjukkan bahwa Corporate Social Responsibility tidak memiliki pengaruh positif terhadap ROA. Selanjutnya  hasil penelitian ini menunjukkan Corporate Social Responsibility memiliki pengaruh positif  terhadap ROE. Kata kunci : Corporate Social Responsibility, ROA, ROE, Firm Size.
MANAJEMEN PEMBERDAYAAN MASYARAKAT SEKITAR HUTAN DAN PERAN KELOMPOK KADER MASYARAKAT PEDULI API (MPA) TERHADAP TINGKAT KEBERHASILAN DALAM PENCEGAHAN KEBAKARAN HUTAN DAN LAHAN DI KECAMATAN SIMPANG HILIR KABUPATEN KAYONG UTARA
Authors: B2042132004 ASLINDA
Published: August 2023

Penelitian ini untuk mendeskripsikan manajemen pemberdayaan masyarakat sekitar hutan dan untuk mengetahui peran kelompok kader MPA terhadap tingkat keberhasilan dalam pencegahan kebakaran hutan dan lahan serta menggunakan metode kualitatif dengan lokasi penelitian Desa Nipah Kuning, Desa Pemangkat, Desa Pulau Kumbang dan Desa Padu Banjar Kecamatan Simpang Hilir Kabupaten Kayong Utara. Informan ditentukan dengan teknik non probabilitas dan teknik pengumpulan data menggunakan observasi dan wawancara. Saran yang dapat direkomendasikan yaitu Perencanaan dengan menyusun peta sketsa desa secara partisipatif, peta tata kelola lahan, penyiapan dan penggalian informasi terkait dengan kearifan lokal/hukum adat/aturan desa/aturan adat dalam menjaga hutan dan lahan, inventarisasi kelompok-kelompok desa baik berhubungan dengan sumberdaya manusia atau lembaga-lembaga secara partisipatif serta menyusun aturan desa dan aturan kelompok. Pengorganisasian dengan menginventarisasi kelompok-kelompok dan sumberdaya manusia kelompok yang ada dimasyarakat. Pelaksanaan dengan informan kunci seperti Kepala Desa, Sekretaris Desa, Kepala Dusun, BPD, tokoh-tokoh agama/masyarakat dan mengidentifikasi serta analisis kelompok. Pengawasan dengan melibatkan berbagai pihak mulai perencanaan sampai pelaksanaan akhir kegiatan, membuat laporan secara terbuka, pembagian waktu yaitu awal dimana kegiatan sebelum dan baru akan dimulai, pertengahan sebagai pembanding dari hasil awal sampai pertengahan dan akhir untuk mengetahui tingkat keberhasilan dari proses pemberdayaan masyarakat dalam pencegahan kebakaran hutan dan lahan. Pengendalian dilakukan perminggu ditahap awal dan perbulan ditahap pertengahan, dan alur waktu sesuai kesepakatan. Evaluasi dilakukan dari pusat, propinsi, kabupaten, kecamatan dan desa atau tim evaluasi melakukan kunjungan kelapangan dari tahap awal, bulanan, kemajuan kegiatan dan akhir kegiatan pada organisasi kelompok di desa, meningkatnya kontrol sosial, berkembang dan meningkatnya perekonomian, meningkatnya produktivitas lahan, berkurangnya jumlah kebakaran hutan dan lahan atau menurunnya jumlah titik api serta meningkatnya kesejahteraan dan pendapatan petani. Kata kunci : Manajemen Pemberdayaan Masyarakat, Peran Kader MPA, Perencanaan, Pengorganisasian, Pelaksanaan, Pengawasan, Evaluasi
PENGARUH KEADILAN ORGANISASIONAL TERHADAP ORGANIZATIONAL CITIZENSHIP BEHAVIOR DAN KINERJAPEGAWAI PADA PUSKESMAS MATANG SURI KABUPATEN SAMBAS
Authors: B2042142013 RAJIMIN
Published: August 2023

Research conducted at the health center Suri Mature Sambas district pertaining about the influence of organizational justice on organizational citizenship behavior and performance. This relates to terselengaranya good health services also depends on the adequacy of health resources. With healthcare resources in accordance with established standards, the health service is expected to run well and in the end produce quality health services and satisfy all parties. This has an impact on improving the performance of employees working in the field of health care.The purpose of this study was to examine and analyze the influence of organizational justice on organizational citizenship behavior and performance of employees Mature Suri Sambas district health center. Forms of this research is to use Causal research. Collecting data using primary data in the form of questionnaires and interviews and secondary data sourced from the Office of the District Perindagkoptamben Mempawah. Sample using a sample census. The sample in this study is overall employee at the health center Matang Suri in Sambas district as many as 46 people.The results of this study showed that organizational justice a significant positive effect on organizational citizenship behavior of employees health center Matang Suri in Sambas district. Both organizational fairness significant positive effect on employee health center kenerja Mature Suri in Sambas district. The third organizational citizenship behavior significantly positive effect on employee health center kenerja Mature Suri in Sambas district. Keywords: Organizational Justice, Organizational Citizenship Behavior And Performance.
From Particle-in-a-Box Thought Experiment to a Complete Quantum Theory?
Authors: Chen Jixin
Published: August 2023

Einstein: God does not play dice and nothing travels faster than the speed of light. Schrödinger: My cat cannot be both dead and alive. Dirac: The existing quantum theory should not be considered to be the final solution. Feynman: How does it work? de Broglie: My matter wave has an imaginary part. Me: Great! This could be the missing piece the others have been looking for. In this report, I present an innovative modification to the Schrödinger equation, which yields wavefunctions capable of accurately describing quantum phenomena. Concurrently, this modification introduces an alternative interpretation to the widely recognized Copenhagen interpretation within the realm of quantum theory.
Electron transfer reaction of TEMPO-based organic radical batteries in different solvent environments: comparing quantum and classical approaches
Authors: Mitra Souvik , Heuer Andreas , Diddens Diddo
Published: August 2023

In this study, we delve into the complex electron transfer reactions associated with the redox-active (2,2,6,6-tetramethylpiperidin-1-yl)oxyl (TEMPO), a common component in organic radical batteries (ORBs). Our approach estimates quantum electron-transfer (ET) energies using Density Functional Theory (DFT) calculations by sampling from structures simulated classically. This work presents a comparative study of reorganization energies in ET reactions across different solvents. Furthermore, we investigate how changes in the electrolyte environment can modify the reorganization energy and, consequently, impact ET dynamics. We also explore the relationship between classical and quantum ET energies using linear regression models. Importantly, this comparison between quantum and classical ET energies underscores the role of quantum effects, like charge delocalization, in offering added stabilization post-redox reactions. These effects are not adequately represented by the classical ET energy distribution. Our study shows that, although we find a significant correlation between the ET energies computed by DFT and the classical force field, the regression parameters depend on the solvent, highlighting that classical methods should be benchmarked by DFT before applying them to novel electrolyte materials.
Decarboxylative Halogenation of Indoles by Vanadium Haloperoxidases
Authors: Harstad Lauren J. , Wells Clare E. , Lee Hyung Ji , Ramos Lauren P.T. , Sharma Manik , Pascoe Cameron A. , Biegasiewicz Kyle F.
Published: August 2023

Halogenated heteroarenes are key building blocks across numerous chemical industries. Here, we report that vanadium haloperoxidases are capable of producing 3-haloindoles through decarboxylative halogenation of 3-carboxyindoles. This biocatalytic method is applicable to decarboxylative chlorination, bromination, and iodination in moderate to high yields and with excellent chemoselectivity.
Three-Dimensional Covalent Organic Framework with “the” Topology
Authors: Das Saikat , Mabuchi Haruna , Irie Tsukasa , Sasaki Koki , Nozaki Mika , Tomioka Rina , Wen Dan , Zhao Yu , Ben Teng , Negishi Yuichi
Published: August 2023

Discovery of new topology covalent organic frameworks (COFs) is a mainstay in reticular chemistry and materials research because it not only serves as a stepwise guide to the designed construction of covalent-organic architectures but also helps to comprehend function from structural design point-of-view. Proceeding on this track, we have constructed the first three-dimensional (3D) COF, TUS-38, with the topology by reticulating a planar triangular 3-c node of D3h symmetry with a tetragonal prism 8-c node of D2h symmetry via [3+8] reversible imine condensation reaction. TUS-38 represents a 2-fold interpenetrated multidirectional pore network with a high degree of crystallinity and structural integrity. Interestingly, stemming from the nitrogen-rich s-triazine rings with electron-deficient character and -C=N- linkages composing the TUS-38 framework which benefit to the charge transfer and hence dipole-dipole electrostatic interactions between the framework and iodine in addition to exclusive topological characteristics of the exotic the net, TUS-38 achieves an exemplary capacity for iodine vapor uptake reaching 6.3 g g-1, thereby qualifying as top-level adsorbent for radioactive iodine capture. Recyclability studies evidence that TUS-38 could be reused at least five times retaining 95% of its initial adsorption capacity; while density functional theory (DFT) calculations have heightened our understanding of the interactions between iodine molecules and the framework. This study, therefore, stretches the topological boundaries of COFs with the brand new the net and we envision the widespread adoption of such unique topological configurations in combatting the environmental, climate and energy crises.
Desymmetrization of Heterocyclic Sulfonimidamides via Asymmetric Tsuji-Trost Asymmetric Alkylation
Authors: Gutierrez David , Toth-Williams Garrett , Yasuda Michael , Di Maso Michael , Shaw Jared
Published: August 2023

Methodologies enabling the synthesis of enantioenriched sulfonimidamides containing a stereogenic sulfur center are scarce, often relying on diastereomeric crystallization or the use of chiral auxiliaries. The prototropic tautomerization exhibited by sulfonimidamides makes them uniquely suited for resolution processes. In the case where both nitrogen substituents of a disubstituted sulfonimidamide are the same, the two tautomers are also enantiomers, allowing deprotonation to generate a prochiral anion. Herein we report the first transition metal-catalyzed approach to the desymmetrization of sulfonimidamides relying on commercially available palladium catalysts and ligands. The reaction leads to functionalized, enantioenriched products in high yields.
Cooperative Fe Sites on Transition Metal (Oxy)hydroxides for High Oxygen Evolution Activity
Authors: Ou Yingqing , Twight Liam , Samanta Bipasa , Liu Lu , Biswas Santu , Fehrs Jessica , Sagui Nicole , Villalobos Javier , Morales-Santelices Joaquín , Antipin Denis , Risch Marcel , Caspary Toroker Maytal , Boettcher Shannon
Published: August 2023

Fe-containing transition-metal (oxy)hydroxides are record-activity oxygen-evolution reaction (OER) electrocatalysts in alkaline media and ubiquitously form as the active surface phase across many materials systems. The complexity, heterogeneity, and dynamics of the Fe sites within the (oxy)hydroxide has slowed mechanistic understanding of how and where the Fe-based active sites form—information critical for designing catalysts and electrolytes with higher activity and stability. We show that where Fe species in the electrolyte incorporate into host Ni or Co (oxy)hydroxides depends on the electrochemical history and the structural properties of host material. Substantially less Fe is incorporated from Fe-spiked electrolyte into Ni (oxy)hydroxide at anodic potentials, past the nominally Ni2+/3+ redox wave, compared to during potential cycling. The Fe adsorbed under constant anodic potentials leads to high OER activity which we attribute to under-coordinated “surface” Fe. By systematically controlling the concentration of surface Fe, we discover that the per-Fe OER turn-over frequency (TOF-Fe) increases linearly with the Fe concentration, suggesting a changing OER mechanism with increased Fe concentration. We propose a mechanism involving multiple, cooperative Fe sites in FeOx clusters. The magnitude of TOF-Fe depends on the host material, with new Fe:NiOxHy showing record-high TOF-Fe of ~ 40 s-1 at 350 mV overpotential.
الاغراق الاقتصادي : الآثار والمعالجات مع اشارة خاصة لأقليم كوردستان العراق
Authors: نورالدين شلير
Published: August 2023

أن ظاهرة الاغراق الاقتصادي هي أحدى التحديات التي تواجه أقتصاد أقليم كوردستان _العراق ، نتيجة لتحرر التجارة والانفتاح على العالم الخارجي بعد عام 2003 والذي كان له الاثر السلبي على أقتصاد الاقليم ،ومن هنا جاء أهمية البحث في تسليط الضوء على مفهوم الاغراق الاقتصادي وأنواعه المختلفة التي يتخذها سواء من حيث الدوافع التي تدفع الدول أو الشركات لممارستها، أو من حيث الفترة التي تستغرقها ،الآثار المترتبة لممارسة الاغراق على أقتصاديات الدول التي تمارس هذه السياسة  والدول التي تمارس فيها  الاغراق مع اشارة خاصة للاغراق الاقتصادي في أقليم كوردستان والاجراءات والمعالجات لمكافحتها في أسواق الاقليم ،وتوصل البحث الى مجموعة من الاستنتاجات والمقترحات كان أهمها : الاغراق الاقتصادي في الاقليم هو أختراق لأسواق الاقليم والسيطرة عليها من قبل الدول الاجنبية. و الذي أدى الى ضعف القدرة الانتاجية والتنافسية للمنتج المحلي وأغلاق العديد من المشاريع الكبيرة والمتوسطة والصغيرة ، وتهديد منظومة الامن القومي  والتنمية الاقتصادية  في الاقليم بشكل عام وهذا يعود الى عدم تفعيل القوانين والتشريعات التي تنظم الاستيراد و ضعف الاجهزة الرقابية على حدود الاقليم .أما اهم المقترحات لمعالجة آثار الاغراق فهي أن تتبنى حكومة الاقليم سياسات زراعية تهدف الى خلق ميزة نسبية في أنتاج المحاصيل الزراعية الاستراتيجية .والعمل على تطوير الانتاج الزراعي كما ونوعا بأستخدام التكنولوجيا الحديثة وكذلك وضع آليات عملية لمراقبة السلع والبضائع والمنتجات الواردة ، وأجراء الفحوصات اللازمةعليها وفق المؤشرات والمقاييس الفنية العالمية للسماح لها بالدخول الى الاسواق لحماية المواطنين في الاقليم،وفيما يخص القطاع الصناعي لابد من دعم وتشجيع الصناعات الوطنية في الاقليم عن طريق توفير البيئة الاقتصادية المناسبة لهذه الصناعات .
A simulation model for the electrical rotary-wing aircraft (eVTOL) performance estimation for the urban air mobility purposes
Authors: Myasnikov M. I. , Ilyin I. R.
Published: August 2023

The present paper presents a simulation model description developed for the aircraft performance estimation of the most popular electric vertical takeoff and landing aircraft (eVTOL) aerodynamic configurations with the electric (hybrid) power plant for the urban air mobility purposes. It focuses on the quadcopter-type eVTOL aircraft aerodynamic configurations using the unshrouded-propellers or ducted fans driven by electric motors. The aircraft performance analysis for aerodynamic configurations of the quadcopter and tilt rotor-quadcopters with the tilt rotors and wing with the all-electric (EP) or hybrid power plant (HP) is given. To compare aircraft performance, the estimation results for a conventional single-rotor helicopter with EP or HP are given. Based on the numerical solution equation of the aircraft existence, feasible structural components mass distributions for various types of eVTOL configurations were obtained. eVTOL aircraft performance, including the estimation of apparent and drag power for the airspeed range, from hovering to the maximum airspeed, as well as for the transition modes (tilt rotor aircraft and quadcopters) were estimated. The eVTOL aircraft flight range and duration with EP and HP at the straight and level flight mode were calculated. Specific mass characteristics of EP and HP components (batteries, generators, electric motors, etc.) to ensure acceptable eVTOL aircraft performance were identified. A comparative evaluation of considered eVTOL configurations for the purpose of their efficiency was performed. Aerodynamic calculations were carried out based on the known analytical techniques of the lifting propeller momentum theory with the data correction capability according to test results. The simulation model, obtained in this paper, can be considered in the phase of the preliminary choice as the first approach of structural parameters and aerodynamic configurations of prospective electric (hybrid) eVTOLs designed for the use as an urban air taxi.
Motivación académica y expectativas profesionales en estudiantes: Una revisión sistemática
Authors: Rojas Virijivich Rodolfo Franco
Published: August 2023

La motivación es el motor de toda acción humana. Es uno de los factores más importantes para elegir y estudiar exitosamente una carrera profesional. El momento de la elección de la vocación en la vida de un joven es determinante y se realiza en base a limitada información y experiencia. En ese sentido, determinar las motivaciones académicas y expectativas profesionales en estudiantes resulta sumamente interesante ya que implican factores personales, sociales y contextuales sobre los individuos y las carreras. El presente trabajo tiene como objetivo desarrollar una revisión sistemática de la bibliografía que estudia la motivación académica y las expectativas profesionales. Sin embargo, es a su vez la extensión y desarrollo de una revisión sistemática ya existente: Factors Related to University Students’ Motivation and Instruments for Its Evaluation: A Systematic Review (Sánchez y Martínez, 2022). Para el análisis se realizó la búsqueda en las bases de datos de Web of Science, Scopus, Scielo y RedALyC, de los términos (en español e inglés) “motivación académica” y “expectativas profesionales”. Se encontraron 79 artículos que cumplían con los criterios propuestos para la investigación. Estos artículos fueron publicados entre los años 2009 y 2022.
The characteristic of whole wheat bread supplemented with roselle (Hibiscus
sabdariffa) powder
Authors: M.N. Nor Qhairul Izzreen , A. Noor Syafiqah , M. Hasmadi , J. Nurul Hanisah , W. Pindi , M.A. Siti Faridah
Published: August 2023

Roselle (Hibiscus sabdariffa) has many health benefits and all parts of the roselle,
including calyx, seeds, leaves, fruits and roots. Over the years, high demand for wholegrain products has been observed worldwide due to their high nutritional values and
protective effects against several chronic diseases. Whole wheat bread is one of the most
consumed whole-grain products. However, products of whole wheat flour had lower
consumer acceptability than refined flour. The objective of this study was to investigate
the effects of the addition of roselle powder (1, 2, or 3%) on the characteristics and
composition of whole wheat dough and whole wheat bread. Bread quality is determined
by sensory evaluation, bulk density, texture profile analysis (TPA), colour and moisture
content, ash, protein, fat, crude fibre, and carbohydrates. The sensory analysis showed the
2% roselle powder was the best bread formulation with 6.65±1.00 of panel acceptance
compared to the other formulations. By incorporating roselle powder, the height of the
dough was similar to any commercial bread (10 cm) and could shorten the fermentation
time from 60 to 45 mins. Sensory-wise, the bread colour was lighter and reddish, which
was appealing with the values of 53.92±0.02 for ∆E*. The firmness of roselle bread was
reduced from 4.60±o.42 to 2.55±0.46 with a decreasing amount of roselle powder from
3% to 1% but increased to 5.19±0.15 during 4 days of storage. Interestingly, roselle bread
has the potential to reduce staling of bread during storage with a value of 6.29±0.35 in
control bread to 5.19±0.15 in F2 roselle bread after certain days of storage.
TWITTER COMMUNICATION OF FRENCH POLITICIANS AS A REACTION TO RUSSIAN FULL-SCALE INVASION OF UKRAINE (BASED ON THE ACCOUNTS OF VALÉRIE PÉCRESSE, ÉRIC ZEMMOUR AND MARINE LE PEN)
Authors: Сідень О. І.
Published: August 2023

Nowadays the civilized world is in the process of instant developing, scientific progress and active implementation of modern technologies. New media as a part of modern technologies can be a tool for preventing wars or media coverage of them. Starting February 24, 2022, social networks were flooded with information about Russian full-scale invasion of Ukraine coming from Ukrainian and foreign political actors who used social media to communicate with their target audience. In this article Twitter has been explored as a means of political communication, Twitter accounts of French politicians (Valérie Pécresse, Éric Zemmour and Marine Le Pen) and their reaction to the Russian full-scale invasion of Ukraine over a period of January-April 2022 has been analyzed. Due to the versatility of the topic our research has been conducted using quantitative content, qualitative content, and thematic analysis, as well as elements of critical discourse analysis. The article concludes that despite belonging to right wing political parties, French politicians instrumentalise the Russian full-scale invasion of Ukraine differently. Center-right Valérie Pécresse supports Ukraine, approves sanctions against Russia, calls for help and decisive action from the EU and NATO, does not approve of EU expansion, referring to Ukraine's accession to the EU, and the end of cooperation of French industries with Russia. Whereas far-right Éric Zemmour and Marine Le Pen demonstrate an ambiguous attitude: they respect the sovereignty of Ukraine, call for humanitarian aid and condemn the Russian invasion, but at the same time they demonstrate a pro-Russian position, continue Russian narratives about the responsibility of the USA and NATO, use Russian transliteration of Ukrainian cities and territories, oppose sanctions, and call for peace, avoiding the direct nomination of war.
ІНТЕРТЕКСТУАЛЬНІСТЬ ТА ІНТЕРДИСКУРСИВНІСТЬ РОСІЙСЬКОГО ВОЄННОГО НАРАТИВУ: ПРОПАГАНДА VS ЛІНГВІСТИКА
Authors: Левченко О. П. , Гриців Н. М.
Published: August 2023

Статтю присвячено дослідженню основних аспектів ідеологічно маркованих інтертекстем та проаналізовано їх з погляду пропагандистського дискурсу і маніпуляції воєнним наративом. Показано, як інтертекстуальність у медійному дискурсі слугує інструментом ідеологічної пропаганди під час російсько-української війни. Пропагандистські інтертексти можна розпізнати та виокремити через формальний аспект мови. Доказово, що добір лексем і текстем актуалізує пропагандистський наратив, створений автором з наміром вплинути на адресата. Розвідка унаочнює способи творення інтертекстуальності в інтердискурсі шляхом перетягування маркованих мовних композитів різних дискурсів з наміром ввести їх у новий контекст для пропагандистського ефекту. Творці медіа та наукового (інтер) дискурсу послуговуються низкою стратегій з метою маніпулювання та дезінформації. Висвітлено, якою мірою вони використовують природну мову, зокрема інтертексти як інструмент маніпулювання. Дослідження поєднує кількісні і якісні характеристики аналізованої теми. Інтертекстуальність у просторі російської пропаганди розглядають як поєднання мовних і позамовних чинників, що замасковано руйнують правдиву картину світу, водночас зосереджуються на бажаному (хибному) повідомленні, яке потрібно донести і розповсюдити. Основна мета пропагандистів/маніпуляторів – нав'язати очікувану модель мислення; спонукати реципієнта думати та поводитися так, як цього прагнуть творці (інтер)дискурсу. З’ясовано, що ідеологічно орієнтований добір мовних засобів творців пропагандистського продукту підпадає під певні закономірності, серед них: спроба псевдонаукового обґрунтування підтримки неподільності росії та України і заперечення суверенітету України; деструктивна риторика щодо мовної політики України; безпідставне звеличення радянських пережитків; обрядовість; критика країн Заходу, США та ЄС; вживання пейоративних політичних евфемізмів; знецінення всього спорідненого з Україною; виправдання і схвалення російської агресії; маніпуляція в межах наукового дискурсу. Перелічені закономірності покликані прищепити негласні ідеї в інформаційне поле, а отже, і у свідомість обраних адресатів. Дослідження можна продовжити та доповнити аналізом інших внутрішньомовних й іншомовних ресурсів за принципом типологізації, запропонованим у цій статті.
The Effects of Paternal Figures’ Parenting Style and Involvement on Masculinity and Coping Styles for Sons
Authors: Burns Matthew
Published: August 2023

Of the three parenting styles created by Baumrind (1966), the authoritarian style has been largely associated with fathers due to previously reinforced unhealthy masculine norms. However, there has been a change in masculine behaviors and ideology in which fathers have taken on a more nurturing role (Lin & Billingham, 2014). Specifically, the son's coping style and masculinity will vary greatly depending on the paternal figures’ behavior during childhood and further (Addis & Cohane, 2005; Cherry & Gerstein, 2021). One hundred and fifty participants were recruited to take part in this study that is examining paternal gender role conflict and parenting styles on different outcomes for the son. ANOVAs were used to examine the effects of the paternal parenting style on the son’s coping style and gender role conflict. Regressions and correlations were used to examine the effects of paternal involvement and gender role conflict of the paternal figure in addition to the son's conflict and coping styles. The results did not support the hypothesis that parenting styles make a difference, but that gender role conflict and paternal engagement did appear to have an impact on the son's gender role conflict and coping style. The implications of how the father-son relationship should be examined in future research are discussed due to the contradicting results compared to the past literature.
¿Reconoce esta clave diagnóstica?
Authors: Moreno Catalina , Wolff Juan Carlos , Ospina Juan Pablo , Ruiz Juan David , Correa Luis Alfonso
Published: August 2023

Los cambios ungulares pueden ser el reflejo de trastornos sistémicos o locales, por lo que siempre deben alertar al médico tratante, el cual debe interesarse en encontrar la causa de sus hallazgos. Los pliegues ungulares y la piel que rodean laplaca ungular también deben ser evaluados con cautela. Los pacientes con inmunosupresión tienen un mayor riesgo de presentar cualquier cáncer de piel no melanoma y, también, neoplasias malignas de la unidad ungular; el más frecuentede ellos es el carcinoma de células espinosas de la uña.La papulosis bowenoide se caracteriza por múltiples lesiones papulosas lisas o verrugosas localizadas en la zona genito-inguinal y, menos frecuentemente, en zonas diferentes a las genitales. En la evaluación histopatológica es difícil diferenciarla de la enfermedad de Bowen. Lo más característico en la papulosis bowenoide son las mitosis nucleares en la misma fase, particularmente en metafase, y en la enfermedad de Bowen, es la maduración desordenada de los queratinocitos; sin embargo, estos hallazgos no son constantes.Muchas de estas lesiones permanecen in situ o se resuelven espontáneamente.No obstante, debido al riesgo existente (aunque sea poco) de transformación a carcinoma espinocelular invasor, siempre se debe brindar un tratamiento conservador, pero con intención curativa y hacer seguimiento de las lesiones residuales,especialmente en los pacientes con inmunosupresión en quienes presuntamente esta transformación puede ocurrir con más facilidad.
DOCUMENT OF THE KNOWN? SELF-FULING PROPHET? PRESENTATION OF PUBLIC RESEARCH IN THE MEDIA
Authors: ÜZÜMLÜ Aytuğ MERMER
Published: August 2023

Kamuoyu araştırması, en dar haliyle bir topluluğun belli bir konudaki eğilimlerini ortaya koymak amacıyla yapılan saha çalışması olarak tanımlanabilmektedir. Tanımından da anlaşılabileceği üzere kamuoyu araştırmalarının temel iddiası,
var olanı nesnel olarak gözler önüne sermektir. Araştırmaların sonuçlarına göre ticari kurumlar özelinde ürün ya da hizmetler, toplumsal kurumlar özelinde ise verilen mesajlar, izlenen politikalar ve yürütülen icraatlar tekrar
gözden geçirilmekte, hedef kitle ile en uygun noktada buluşma şansı yakalanmaktadır. Kamuoyu araştırmalarının ideal işlevi bu yöndeyken pratikte bazı kamuoyu araştırmalarının mevcudu ortaya koymak yerine, ortaya konanı mevcut hale
getirebilmekte olduğuna dair eleştirilere maruz kalmaktadır. Bu iki uç arasında salınan kamuoyu araştırmalarının tümü benzer ya da aynı yöntemlerle yapılmakta ve özünde bilimsellik iddiası taşımaktadır. Bu çalışma ilkin kamuoyu
araştırmalarına dair kavramsal düzeyde bilgi vermekte, bu araştırmaların misyon ve işlevleri hakkında genel bir çerçeve çizmekte, ardından araştırmaların gerçeği ortaya koyma ve ortaya koyduklarını gerçeğe dönüştürme etkilerini
ele almaktadır.
A CLAIMING ISSUE IN ADMINISTRATIVE JURISDICTION
Authors: SARUHAN Haluk
Published: August 2023

Bekletici mesele bir davanın yargılanması sırasında ortaya çıkan ve davanın incelenmesi veya sonuçlandırılması için başka bir yetkili makam tarafından çözülmesi gereken bir konudur. Kural olarak, anlaşmazlığı dinleyen mahkeme anlaşmazlığı
kendisi çözecektir. İdari usul hukukuna hakim olan resen soruşturma ilkesi gereği uyuşmazlığı duyan mahkeme, söz konusu uyuşmazlıkla ilgili tüm sorunları çözerek karara varacaktır. Bir ön soru, bir davaya devam edilmeden veya karar
verilmeden önce çözülmesi gereken sorunları ifade eder. Ancak "bekletme sorunu" olarak anılan kavram bu durumun istisnasıdır. Hem hukuk muhakemesinde hem de idari muhakemede kullanılan önleyici madde kurumu; Uyuşmazlıkla ilgilenen
mahkemenin davanın duruşmasını durdurması (veya ertelemesi) ve ortaya çıkan sorunun çözümünü beklemesi anlamına gelir, çünkü sırayla çözülmesi gereken başka bir konu anlaşmazlık hakkında karar vermek kendi yetki alanı içinde değildir.
Duruşma sırasında bir ön sorun ortaya çıkarsa, ilgili taraf dilekçe ile veya duruşma sırasında sözlü olarak gündeme getirebilir. Hakim, taraflarca ileri sürülen ön soruyu incelemeye değer görürse, tespit edilecek süre içinde cevabı
varsa delillerle birlikte bildirmek üzere karşı tarafa tebligat veya tebligat yapar.