bluuebunny/crossref_metadata_2025 huggingface dataset:
A Multi-metal Approach for the Reticulation of Iridium into Metal-Organic Framework Building Units
Authors: Vasile Raluca Loredana , Borrallo-Aniceto Mari Carmen , Esteban-Betegón Fátima , Gutiérrez-Puebla Enrique , Monge M Angeles , Iglesias Marta , Gándara Felipe
Published: October 2023

Noble metals (Ag, Au, Pt, Rh, Ir, Pd, Ru and Os) are ubiquitous in our everyday life, from medical applications to electronic devices and synthetic chemistry. Iridium is one of the least abundant elements, and despite its scarcity, it remains essential for efficient and active catalytic processes. Consequently, the development of heterogeneous catalysts with presence of active iridium sites is of enormous interest as it leads to the improvement of their recyclability and reusability. Here, we demonstrate a strategy to incorporate iridium atoms into metal-organic frameworks (MOFs), as part of their secondary building units (SBUs), resulting in robust and reusable materials with heterogeneous photocatalytic activity.
Chiral Carbene Zinc(II) Dithiolates: Efficient TADF Emitters Showing Circularly Polarized Luminescence
Authors: Mitra Mousree , Mrózek Ondřej , Putscher Markus , Guhl Jasper , Hupp Benjamin , Belyaev Andrey , Marian Christel , Steffen Andreas
Published: October 2023

Luminescent metal complexes based on earth abundant elements are a valuable target to substitute 4d/5d transition metal complexes as triplet emitters in advanced photonic applications. Whereas Cu(I) complexes have been thoroughly investigated in the last two decades for this purpose, no structure-property-relationships for efficient luminescence involving triplet excited states from ZnII complexes are established. Herein, we report on the design of monomeric carbene zinc(II) dithiolates (CZT) featuring a donor-acceptor-motif that leads to highly efficient thermally activated delayed fluorescence (TADF) with for Zn(II) compounds unprecedented radiative rate constants k(TADF) = 1.2x10^6 s^-1 at 297 K. Our high-level DFT/MRCI calculations revealed that the relative orientation of the ligands involved in the ligand-to-ligand charge transfer (1/3^LLCT) states is paramount to control the TADF process. Specifically, a dihedral angle of 36-40° leads to very efficient reverse intersystem-crossing (rISC) on the order of 10^9 s^-1 due to spin–orbit coupling (SOC) mediated by the sulfur atoms in combination with a small E(S1-T1) of ca. 56 meV (calc. 20 meV). In addition, the chiral carbene ligand leads to the generation of circularly polarized luminescence (CPL) with high dissymmetry values g(lum) of up to 3.3x10^-2 in polystyrene (PS).
Flipping the GPCR Switch: Structure–Based Development of Selective Cannabinoid Receptor 2 Inverse Agonists
Authors: Carreira Erick , Kosar Miroslav , Sarott Roman , Sykes David , Viray Alexander , Vitale Rosa Maria , Tomasevic Natasa , Li Xiaoting , Ganzoni Rudolf , Kicin Bilal , Reichert Lisa , Patej Kacper , Gomez-Bouzo Uxia , Guba Wolfgang , McCormick Peter , Hua Tian , Gruber Christian , Veprintsev Dmitry , Frank James , Grether Uwe
Published: October 2023

We report the structure-based design of cannabinoid receptor type 2 (CB2R)-selective inverse agonists (S)-1 and (R)-1, which were derived from privileged agonist HU-308 by introduction of a phenyl group at the gem-dimethylheptyl sidechain. Epimer (R)-1 exhibits high affinity for CB2R with Kd = 39 nM and serves as a platform for the synthesis of a wide variety of probes. Notably, the fluorescent probes, for the first time, retain their inverse agonist functionality, high affinity, and selectivity for CB2R independent of linker and fluorophore substitution. Ligands (S)-1, (R)-1, and their derivatives act as inverse agonists in CB2R-mediated cAMP as well as G protein recruitment assays, and do not trigger β-arrestin–receptor association. Furthermore, no receptor activation was detected in live cell ERK1/2 phosphorylation and Ca2+-release assays. Confocal fluorescence imaging experiments with (R)-7 (Alexa488) and (R)-9 (Alexa647) probes employing BV-2 microglial cells visualized CB2R expressed at endogenous levels. Finally, molecular dynamics simulations corroborate the initial docking data in which inverse agonists restrict movement of toggle switch, Trp2586.48, and thereby stabilize CB2R in its inactive state. The present study serves as a blueprint for the rational design of GPCR ligands beyond CB2R with a tailored functional response.
Poacic Acid, a Plant-Derived Stilbenoid, Augments Cell-Wall Chitin Production, but Its Antifungal Activity Is Hindered by this Polysaccharide and by Fungal Essential Metals
Authors: Yona Adi , Fridman Micha
Published: October 2023

Climate and environmental changes have modified the habitats of fungal pathogens, inflicting devastating effects on livestock and crop production. Additionally, drug-resistant fungi are increasing worldwide, driving the urgent need to identify new molecular scaffolds for development of antifungal agents for humans, animals, and plants. Poacic acid (PA), a plant-derived stilbenoid, was recently discovered to be a novel molecular scaffold that inhibits the growth of several fungi. Its antifungal activity has been associated with perturbation of the production/assembly of fungal cell wall β-1,3-glucan, but its mode of action is not resolved. In this study, we investigated the antifungal activity of PA and its derivatives on a panel of yeast. PA had a fungistatic effect on S. cerevisiae and a fungicidal effect on plasma membrane-damaged Candida albicans mutants. Live cell fluorescent microscopy experiments revealed that PA increases chitin production and modifies its cell wall distribution. Chitin production and cell growth returned to normal after prolonged incubation. The antifungal activity of PA was reduced in the presence of exogenous chitin, suggesting that potentiation of chitin production is a stress response that helps the yeast cell overcome the effect of this antifungal stilbenoid. Growth inhibition was also reduced by metal ions, indicating that PA affects metal homeostasis. These findings suggest that PA has a complex antifungal mechanism of action that involves perturbation of cell wall β-1,3-glucan production/assembly, chitin production, and metal homeostasis.
ڕەنگدانەوەی مێژووی میرانی کورد له شیعری حاجی قادری کۆییدا
Authors: پەشابادی یەدوڵڵا
Published: October 2023

حاجی قادری کۆیی (١٨١٧-١٨٩٧) وەکوو شاعیرێکی نەتەوەیی و ڕۆشنبیر له نێو بازنەی ئەدەبی کوردی له سەدەی نۆزدەدا، گرنگایەتییەکی زۆری به مێژوو و وێژه و زانست داوه. له نیوەی دووهەمی تەمەنی ئەدەبی و فیکریی خۆیدا ئاوڕی له زانیاران و میران و شاعیران و ناودارانی کورد داوەتەوه و خاڵە گرنگەکانی کارنامەیانی به کورتی تۆمارکردووه. ئەم لێکۆڵینەوەیه به شێوازی وەسفی-شیکاری دەیهەوێ ئاماژه و لایەنه مێژووییەکانی پەیوەندیدار به ماڵەمیرانی کوردەوه له شیعری حاجی قادردا لێکبداتەوه و به هەڵێنجان و دەرخستنی نموونە شیعرەکانی، دەست بداتە بەراوردکارییەکی زانستی لەگەڵ ئەوەیدا که لە سەرچاوە مێژووییەکانی وەکوو شەرەفنامەدا هاتووه. بەو نیازەی بتوانێ هەندێک له سەرچاوەکانی فیکر و هزری قووڵی حاجی بدۆزێتەوه. حاجی قادر جگە له لایەنی ئەدەبی و هونەری که یەکێک له ڕەهەندەکانی شیعری ئەم شاعیرەیه، بۆ هەر بوارێک له مێژووی میران و تۆمارکردنی ناو و یادی شاعیران و گەورە مرۆڤانی کورد هەوڵی­داوە و تایبەتمەندییەکی گرنگی ئەو میر و شاعیر و ئەدیبانەی تۆمارکردووه. له گرنگترین ئاکامەکانی ئەم توێژینەوەیه دەتوانین پەنجه بۆ ئەوە ڕابکێشین که کتێبی شەرەفنامەی بەدلیسی و هەندێ له دەسنووسەکانی تر، له کەنار ڕۆژنامە و گۆڤاری تورکی و ئەورووپیدا که له ئەستەمووڵ دەستی کەوتووه، سەرچاوەی ڕۆشنبیری و ئاگاداریی بوون و توانیویەتی زۆرێک له بارودۆخی سەردەم و ناوونیشانی میران له شیعری خۆیدا به چاوێکی ڕەخنەگرانەوه تۆماربکات.
Recent seismicity on the Kerguelen islands
Authors: Lengliné Olivier , Rimpôt Joachim , Maggi Alessia , Zigone Dimitri
Published: October 2023

The Kerguelen archipelago, one of the largest oceanic archipelagos in the world, was built by an active hotspot interacting with a ridge between 110 and 40 million years ago; since then, the ridge has migrated over 1000~km away and the archipelago's volcanic activity has been steadily decreasing. Despite the lack of recent active tectonics and the quiescent volcanism of the Kerguelen archipelago, there have been several observations of seismic events of unknown origin in its vicinity. The only seismic instrument within 1000~km of the archipelago was installed on Kerguelen's main island in the 1980's. In this study we apply modern earthquake detection techniques to the continuous waveforms recorded by this seismometer over the past 20 years. We reveal that the Kerguelen archipelago islands hosts an abundant seismicity. This seismicity exhibits swarm-like characteristics in several clusters while at other locations the earthquakes appear more steady over time. We locate most events near the largest icecap of the main island. We speculate that the origin of the earthquakes can be linked to residual volcanic, magmatic, or hydrothermal activity at depth, all of which can be favored by flexural stress caused by the documented fast retreat of icecap. This seismicity may also indicate that the Kerguelen hotspot shows signs of unrest.
The Effects of The Vertical Cooperation Strategy Between Airports and Airlines on The Operating Performance of Airlines
Authors: MACİT Armağan , BASAR Mehmet
Published: October 2023

It is aimed to determine the effects of the strategic cooperation between airport operators and airlines on the operational performance of airlines. In addition, it is also among the other aims of the study to deal with all aspects of airport-airline strategic cooperation, which is rare, to develop the relevant literature and to make suggestions to airlines. In the research, cooperation of Pegasus Airlines, the largest private airline company of Turkey, with Istanbul Sabiha Gökçen Airport, which is the fastest growing airport in Europe, is discussed. In the research, in which the mixed method was used, the dimensions of cooperation were revealed primarily through interviews with middle-level managers. Panel regression analysis was used as a quantitative analysis method in the study. It was tried to determine the effect of vertical cooperation on performance with 3 different models established. The impact of the Covid-19 pandemic and the cooperation dummy variables were added to the models and the effects of the cooperation, and the pandemic were revealed. As a result of the study, even though the Covid-19 pandemic has created a structural break on airline performance, the positive effect of cooperation shows that vertical cooperation is an important strategy that can be preferred by airlines. It has been understood that with the airport-airline vertical cooperation strategy, competitive advantage can be created, costs can be kept under control, the activities of idle airports can be increased, and an advantage can be created in providing passenger guarantees given in projects in which the public-private sector cooperates.
Kitchen Staff's Intention to Use Geographical Indication Food Products in the Context of Theory of Planned Behavior
Authors: KAYA Deniz , AKDEMİR Nihan
Published: October 2023

The purpose of this study is to determine the intentions of kitchen staff working in hotels to use geographical indication (GI) food products and the factors affecting their intentions within the scope of the Theory of Planned Behavior. Within the research framework, the relationship between staff’s familiarity with GI food products and their intention to use these products has been examined. The study was conducted in 4 and 5-star hotels located in Istanbul. Data were collected from a total of 423 participants by questionnaire technique by interviewing the kitchen staff of the food and beverage departments of these enterprises. The data obtained were analyzed using descriptive statistics, regression analysis and difference tests. As a result of the research, it was determined that the most important factor affecting the intention to use these products among the participants was familiarity with the products. It was observed that individuals with knowledge of GI food products and those who have previously worked with these products exhibit a notably positive attitude towards using them. In addition, it has been determined that the reason for the negative attitudes of the decision-making managers in the enterprises where the participants work towards the use of GI food products is the high purchasing costs and seasonality of the products. Finally, it was observed that the positive attitude towards GI food products increased from the lower to the higher positions in the kitchen hierarchy, and this was due to the knowledge of recognizing and using the product correctly gained with professional experience.
Afet döneminde kurumsal sosyal sorumluluk faaliyetlerinin marka denkliği ve müşteri tatminine etkisi
Authors: BEĞENDİK Behiye , KARADENİZ Serhan
Published: October 2023

İşletmeler, faaliyet gösterdikleri toplumun birer parçası olarak, sadece tüketicinin ihtiyaçları ekseninde örgütlenmekle kalmayıp, sosyal pazarlama anlayışı doğrultusunda toplumda yaşanan gelişmelere de duyarlı davranmaktadır. Kurumsal sosyal sorumluluk (KSS) faaliyetlerinin kollarından biri olan hayırseverlik boyutu doğrultusunda işletmeler planlı olarak topluma katkı sunmaktadır. Bu planlı çalışmalar, tüketici algılarını etkilemektedir. Planlı KSS faaliyetlerinin yanı sıra, deprem, sel gibi afet dönemlerinde de işletmeler büyük rol üstlenmektedir. Yüzyılın felaketi olarak adlandırılan Kahramanmaraş depreminde 10 ilde büyük yıkımlar sonrasında, devletin yanı sıra, vatandaş ve işletmeler de olanaklarını seferber etmiştir. Bu çalışmada afet döneminde KSS çalışmalarının marka denkliği ve müşteri tatmini üzerine etkileri incelenmiştir. Araştırmada 429 katılımcıdan online olarak toplanan veriler, Yapısal Eşitlik Modeli ile analiz edilmiştir. Analiz ile, KSS’nin marka denkliği üzerinde pozitif anlamlı bir etkisi olduğu sonucuna ulaşılmıştır. Bunun yanı sıra, marka denkliğinin de müşteri tatmini üzerinde pozitif ve anlamlı bir etkisi olduğu doğrulanmıştır. Araştırma, aynı zamanda, KSS değişkeninin müşteri tatmini üzerinde doğrudan anlamlı bir etkisi olduğu sonucuna işaret etmektedir. Son olarak, KSS müşteri tatmini ilişkisinde marka denkliğinin tam aracı etkisi olduğu görülmüştür.
Editorial
Authors: Monti Ednardo Monteiro Gonzaga do , Silva Alexandra Lima da
Published: October 2023

É com muita satisfação que a Revista Caminhos da Educação apresenta seu segundo número do ano de 2023. Nesta edição, destacamos diversos estudos acadêmicos e pesquisas realizadas no Brasil e no México, que abordam questões cruciais relacionadas à educação, inclusão, formação de professores e diversidade. A parceria acadêmica entre esses dois países é fundamental para uma compreensão mais ampla das dinâmicas educacionais em toda a América Latina. Através de artigos e ensaios criteriosamente selecionados, mergulhamos em um oceano de investigações e reflexões.
O dossiê temático deste número intitulado México em foco: caminhos da pesquisa foi organizado pelas professoras Alexandra Lima da Silva, da Universidade do Estado do Rio de Janeiro – UERJ, e pela professora Blanca Susana Veja, da Universidad Autonoma de San Luis Potosi. O dossiê traz quatro artigos, de especialistas em temáticas relacionadas aos desafios da pesquisa em educação no México.
Ainda neste número, há vinte e um artigos da livre demanda de fluxo contínuo. Temos a certeza de que os leitores encontrarão conteúdos relevantes e atuais, que estabelecem conexão com o foco e escopo deste periódico acadêmico. Os temas abordados nos artigos são diversos e versam sobre assuntos como inclusão, diversidade, artes, cultura e educação. Acreditamos que esses artigos estimulam o debate acadêmico e incentivam a reflexão sobre as questões educacionais numa perspectiva ética e social.
Os textos reunidos neste número são fruto de pesquisas, experiências e reflexões sobre como a diversidade se manifesta nas salas de aula, nos currículos, nas políticas educacionais e nas comunidades.
Para a equipe editorial é motivo de grande satisfação poder contribuir para o avanço do conhecimento científico na área de educação. Agradecemos aos autores por compartilharem suas pesquisas e reflexões conosco e os parabenizamos pelo excelente trabalho. Agradecemos também aos avaliadores que se dedicam com rigor e excelência à avaliação dos artigos aprovados à revista.
Enfim, desejamos ao nosso público tenha uma ótima leitura e que este número sensibilize para os valores educativos, humanos e sociais. Que possamos seguir juntos, confiantes para o avanço do conhecimento científico na área de educação e para a construção de uma sociedade mais justa e igualitária.
 
Ednardo Monteiro Gonzaga do Monti
Alexandra Lima da Silva
Editores
Pengembangan Permainan Tradisional Boy-Boyan Untuk Meningkatkan Kemampuan Motorik Kasar Kelompok B di TK Rinjani Unram Tahun 2023
Authors: Saputra Wahyudi Maulida , Nurhasanah Nurhasanah , Rachmayani Ika , Astini Baik Nilawati
Published: October 2023

Penelitian ini bertujuan untuk mengembangkan pengembangan permainan tradisional boy-boyan untuk meningkatkan kemampuan motorik kasar anak di kelompok usia lima sampai enam tahun. Jenis penelitian ini menggunakan penelitian pengembangan Research and Development. Subyek penelitian berjumlah 17 orang anak yang terdiri dari 11 orang anak laki-laki dan 6 orang anak perempuan yang ada di TK Rinjani Unram. Metode pengumpulan data yang digunakan adalah metode observasi dan dokumentasi. Analisis data menggunakan analisis kuantitatif deskriptif. Adapun tahapan dalam permainan boy-boyan adalah:1. Membentuk kelompok, 2. kelompok yang menang akan bermain dan kelompok kalah akan berjaga, 3. menyusun kepingan di tengah lapang, 4. Anak-anak diberikan 1 kali kesempatan melempar, 5. jarak pelempar bola 5 langkah dari menara, 6. Jika semua terkena lemparan maka selanjutnya main bergantian. Hasil penelitian ini menunjukkan bahwa media boy-boyan yang dihasilkan dinyatakan layak digunakan dalam pembelajaran dengan persentase 85,7% berdasarkan uji produk oleh ahli. Kemampuan motorik kasar anak di TK Rinjani Unram mengalami pengembangan dengan persentase yang dihasilkan pada tahap pengembangan 1 sebesar 26,7%, sedangkan tahap pengembangan 2 sebesar 57,7%, dan tahap pengembangan 3 sebesar 77,8%. hasil penelitian. Dapat disimpulkan bahwa permainan tradisional boy-boyan yang dikembangkan dapat meningkatkan kemampuan motorik kasar anak TK B di Rinjani Unram Tahun 2023.
The Effect of Practicum Tools with Differentiated Learning Strategies on Student Learning Outcomes
Authors: Goldberd H D Sinaga  , Mariana Br Surbakti  , Morianus Gowasa  , Juliper Nainggolan  , Hebron Pardede  , Parlindungan Sitorus
Published: October 2023

This study aims to determine the effect of using practicum tools with diferentiated learning strategies on student learning outcomes. The research method used is quasi-experimental design. The population in this study was all of class X MIA, totaling 212 students, of SMA Negeri 8 Medan. The research sampling technique is purposive sampling technique. Non-equivalent control group design is the type of the research design. The sample in the study consisted of an experimental class, namely class X MIA 6, and a control class, namely class X MIA 5. The experimental class was treated with differentiated learning strategies, while the control class was treated with conventional learning. The research instruments used were multiple-choice questions and student observation sheets. The average score of the posttest for the experimental class was 76.28 with a standard deviation of 6.9, and that of the control class was 72.08 with a standard deviation of 6.7. The pretest and posttest data obtained have been analyzed and met the prerequisites for testing the hypothesis, namely, the data is normally distributed and is homogeneous. The result of the right-tailed t-test on the hypothesis obtained the value of tcount > ttable, namely 2.608 > 2.002 whit = 0.05. Based on the testing criteria, the accepted hypothesis is H, which means that there is an effect of the treatment that is the use of practicum tool with different learning strategies on student learning outcomes at SMA Negeri 8 Medan for the 2022/2023 academic year. The result of the simple linear regression equation is Y = 65.9 + 0.34X.
Optimizing Irrigation Scheduling and Land Configurations of Furrow Irrigated Aerobic Rice
Authors:   Department of Agronomy, Agricultural College and Research Institute, Killikulam, Tamil Nadu Agricultural University, Tamil Nadu, India
Published: October 2023

Field experiments were conducted during pishanam 2015 and 2016 at Central Farm, Agricultural College and Research Institute, Killikulam. The experiment was laid out in a factorial randomized block design with three replications. Experimental treatments comprised of three irrigation scheduling and three bed widths. Rice crop was raised under furrow furrow-irrigated raised bed system (FIRB) system. Response of the crop to the different treatments indicated that growth parameters viz., plant height and Dry Matter Production (DMP) were highest in crop raised in bed width of 1.0 m accommodating five rows per bed and irrigating the crop daily. Raised bed of 1.0 m bed width accommodating five rows per bed and irrigating crop daily resulted in higher grain yield (3874 and 3789 kg ha-1 during 2015 and 2016, respectively) and Water use Efficiency (4.39 and 4.24 kg ha-1 mm-1 during 2015 and 2016, respectively) than other irrigation scheduling and land configurations
Comparing Research Articles in Englishand Portuguese: An Intercultural Approach
Authors: Oliveira Neto José Belém de
Published: October 2023

Entender como a organização retórica funciona em diferentes gêneros acadêmicos (Swales, 1990), por exemplo, Artigos Científicos (ACs), em inglês e outras línguas, pode ajudar a compreender alguns dos desafios enfrentados por autores de países periféricos (Monteiro & Hirano, 2020), como o Brasil. Este estudo apresenta o método utilizado para comparar a escrita de ACs em inglês americano e em português brasileiro, utilizando a Retórica Intercultural (Connor, 2011) como abordagem teórica. Foi adotado no estudo método misto que analisou os dados tanto qualitativamente quanto quantitativamente. O método adotado possibilitou obter dados relacionados à macroestrutura e microestrutura dos ACs e também ajudou a desenvolver material que pode ser utilizado em sala de aula por professores de escrita acadêmica.

Palavras-chave: Retórica Intercultural, Linguistica Aplicada, Gênero Textual, Artigos.
DIREITO DO TRABALHO: DA RELEVÂNCIA DA PROTEÇÃO AOS DESAFIOS CONTEMPORÂNEOS
Authors: Almeida Bernard Pereira
Published: October 2023

O presente estudo trata do desenvolvimento inicial do Direito do Trabalho em nível internacional, pelas mãos da OIT e sua consequente absorção pelos ordenamentos jurídicos da maioria dos países ocidentais. Destaca ainda a relevância do direito laboral para os trabalhadores, no sentido em que lhes fornecem garantias normativas mínimas.
RISCO E PLANEJAMENTO URBANO E SUA ABORDAGEM NOS PERIÓDICOS CIENTÍFICOS
Authors: RAFFAELLI CRISTINA BOGGI DA SILVA , MORETTI RICARDO DE SOUSA
Published: October 2023

O presente trabalho tem por objetivo apresentar uma
análise das publicações realizadas em periódicos no
período de 2010 a 2018, na temática que aborda a interface entre riscos geológicos e hidrológicos e planejamento urbano. Os artigos foram selecionados em duas
bases de dados, Capes e Scopus, a partir de algumas
palavras-chaves. Também foram analisadas as publicações recentes em periódicos com foco em riscos e
desastres, buscando-se os textos que abordam o tema
do planejamento urbano. Os resultados foram sistematizados e analisados, buscando-se caracterizar os
principais temas tratados e identificar os tópicos que
se mostraram ausentes. Os resultados encontrados demonstram que, se por um lado, existem diversas pesquisas abordando o risco de forma multidisciplinar no
contexto do planejamento urbano, por outro lado, as
publicações na temática ainda apresentam várias lacunas de abordagem e temas de investigação que precisam ser aprofundados.
MAPEAMENTOS DE RISCO PARA REGULARIZAÇÃO FUNDIÁRIA
Authors: CORSI ALESSANDRA CRISTINA , MACEDO EDUARDO SOARES DE
Published: October 2023

A dificuldade do acesso à moradia digna é um problema que atinge todas as cidades brasileiras. Atualmente, o aumento do número de pessoas vivendo em áreas
de risco de escorregamentos, enchentes e inundações
tem sido uma das características negativas do processo
de urbanização e crescimento das cidades brasileiras.
A regularização fundiária é um processo que visa legalizar a permanência de moradias que foram instaladas
de forma irregular, clandestina ou quando não foi possível a titulação de seus ocupantes, mesmo que atendessem à legislação em vigor à época de sua implantação ou regularização. No artigo 39 da Lei 13.465/2017,
em núcleos urbanos informais, ou de parcelas deles,
situados em áreas de risco geológico-geotécnicos, somente é admitida a regularização fundiária por meio
de aprovação do projeto, contendo estudos técnicos
que possibilitem a eliminação, correção ou administração de riscos. Dentro deste contexto é de suma importância a utilização do tipo de mapeamento correto no
processo de regularização fundiária. O mapeamento
deve ser realizado casa a casa e conter a indicação da
intervenção estrutural e não estrutural necessária para
a redução do grau de risco.

Palavras-Chave – Mapeamento de risco; Setorização
de risco; Regularização fundiária; escorregamento.
ASSÉDIO MORAL NO LOCAL DE TRABALHO: UM ESTUDO SOBRE A GARANTIA DOS DIREITOS DO TRABALHADOR E SUA DIGNIDADE
Authors:   , Almeida Liliane Fonseca
Published: October 2023

O presente artigo objetivou mostrar algumas facetas do que se entende por assédio
moral e suas qualificações, bem como alguns traumas causados no cidadão que
busca o emprego como uma forma de sustento próprio e para seus familiares. Há
muitas discussões sobre esse tipo de crime contra a pessoa que trabalha; são
debates jurídicos, definições e fundamentações para fortalecer o direito do
trabalhador de não ser molestado em sua dignidade pessoal e psicológica.
Apresentamos, aqui, uma análise sobre as principais obras do mercado jurídico
sobre o assédio moral, direito do trabalhador e a natureza jurídica do crime cometido
pelos que empregam pessoas e que deveriam respeitar a integridade moral e
humana. Desse modo, problematizamos como se apresenta o assédio moral e o
modo como ele cria uma situação vexatória para o trabalhador perante seus
colegas.
Simulação econômica dos impactos do enfraquecimento da união europeia: uma análise de equilíbrio geral computável
Authors:   , Espanhol Bruno Kops
Published: October 2023

A saída do Reino Unido da União Europeia causou o advento do debate sobre a globalização e até onde este processo de integração pode avançar. Nos últimos anos, diversos eventos, como a guerra comercial entre Estados Unidos da América e China, a saída do Reino Unido da União Europeia, a pandemia de Covid-19 e até mesmo a recente guerra da Ucrânia, fizeram-nos questionar até que ponto estamos dispostos a avançar com processos de integração e globalização. Neste contexto, este trabalho propõe a simulação de uma nova saída da União Europeia, através do aumento das barreiras não tarifárias entre os países envolvidos, a fim de analisar os possíveis efeitos nos países e regiões envolvidos em termos econômicos: produção, bem-estar e comércio internacional. Utilizando o modelo de equilíbrio geral computável (GTAP 10), são simuladas cinco possibilidades de saída da União Europeia: Polônia, Cooperação Nórdica, Itália, Grécia e Holanda. Nos cenários propostos, as regiões envolvidas na desintegração regional tendem a ter perda de bem-estar, em especial pela piora dos termos de troca e eficiência tecnológica, causado pela redução ao acesso às importações dos países membros da União Europeia. Ocorre uma diminuição do comércio internacional e um aumento de produção local, com foco na produção daquilo que cada região tem vantagem competitiva. Os países mais afetados negativamente pela desintegração tendem a ser aqueles que a economia tem mais dependência do comércio internacional. Não obstante, os países de fora do bloco europeu tendem a ter aumentos de bem-estar, causados por melhora de termos de troca pela equalização de condições com o país que sai da União Europeia.
Strategies and representations used by early childhood education students in a functional thinking task: A case study
Authors: Morales Rodolfo , Pizarro Fernanda , Díaz-Levicoy Danilo , García-García Jaime I.
Published: October 2023

This article presents a study that addressed the functional relationships that two early childhood education students (five-six years old) evidenced, as well as the representations they used when solving a functional thinking task. The proposed task involved the function f(x)=2x, with six questions on particular cases and one on generalization. The data was collected through a semi-structured interview to each of the students and a qualitative analysis of their answers was carried out in each of the questions of the task. The results suggest that the two students are capable of approaching the proposed task through different strategies, such as additive and multiplicative correspondence relationship, and covariation. Also, it was found that they use systems of varied representations, being the verbal representation to express the generalization of the functional relationship one that stands out. It is concluded that early childhood education students may be able to tackle tasks that involve algebraic notions that focus on functional thinking.
Higher precision in initial rates may be achievable: A test of a pseudo-statistical method
Authors: Ikechukwu Iloh Udema
Published: October 2023

There has been a concerted effort at establishing the best method for the measurement of initial rates for various purposes, including the calculation of kinetic parameters, the maximum velocity (Vmax), and the Michaelis-Menten constant (KM). The objectives of this research are: 1) to derive equations without KM for the determination of the Vmax in particular and vice versa; 2) to determine the KM and Vmax with other equations other than the Michaelian equation; and 3) to subject the calculated and extrapolated kinetic parameters to pseudo-statistical remediation where necessary as a test of their viability and usefulness. The study was experimental and theoretical. It is supported by the Bernfeld method of enzyme assay. By graphical means, the Vmax and KM values for galactosidase respectively range between 163 and 185 mM/min and between 2.07 and 2.77 mg/L; the range by calculations is 177 and 214 mM/min and 2.45 and 3.311 mg/L, subject to pseudo-statistical remediation. Overall, the ranges of Vmax and KM values for alpha-amylase from both the graphical method and calculation are, respectively, 1.095 to 1.018 mM/min and 18.15 to 20.554 g/L. The equations for the determination of the KM and Vmax, which are respectively invariant with respect to each other, were rederived. The initial rates must not be characterised by a mixture of conditions that validate different quasi-steady-state assumptions if the true KM and Vmax are of interest. The new pseudo-statistical method for the remediation of error in all measurements, if necessary, is viable, useful, and robust.
PENDAMPINGAN BELAJAR DENGAN PERMAINAN EDUKATIF ULAR TANGGA UNTUK MENINGKATKAN KEAKTIFAN BELAJAR SISWA SMP NEGERI 2 TEHORU
Authors: Rambe Nana Ronawan , Daulay Fenny Adnina
Published: October 2023

Teaching and learning is an integral process of providing education. In carrying out learning activities it is expected that students can play an active role during the implementation of activities taking place. However, the fact that passive students participate in teaching and learning activities has a direct impact on student learning outcomes. monotonous teaching. Therefore this community service activity aims to increase student learning activeness in learning. The method used is the PAIKEM method (active, innovative, creative, effective and fun learning). The results of the community service activities carried out at SMP Negeri 2 Tehoru in class VIII showed significant results, namely that 27 students had scores above the KKM (70.0) while 3 students had scores below the KKM. So it can be concluded that community service activities carried out in class VIII SMP Negeri 2 Tehoru by conducting learning using the snakes and ladders learning model are said to be able to increase the effectiveness of student learning.
Perbandingan Hasil Belajar Sepak Bola Menggunakan Model Pembelajaran Kooperatif Tipe Jigsaw Pada Siswa Kelas XI SMK Negeri 8 Seram Bagian Barat
Authors: Sahetapy Cristo Jessen Agustinus , Rumahlewang Emma , Hattu Mesak
Published: October 2023

This is comparative research, The variable was the comparison result of learning for Passing in the Football Game using the TGT and Jigsaw Learning Models for 25 students in class XI SMK Negeri 8 West Seram, Data sources come from teachers, students and researcher. Data collection techniques using observation, tests, and documentation or archives. the good results, and Very Good criteria (89-100), the TGT learning model amount to 4 students and the TGT Jigsaw learning model amount to 1. Explained in Figure 4.3. For obtain good criteria (77-88) the TGT learning model, were 13 students and the Jigsaw learning model, were 14 students. The sufficient criteria (65-76) for the TGT learning model are 6 students and the Jigsaw learning model is 10 students. Meanwhile (<=64) is only found in TGT with 2 students.
Tax Contribution to Regional Original Income (PAD) Tanah Datar District
Authors: Hidayat Feby , Frinaldi Aldri , Asnil Asnil
Published: October 2023

Regional taxes are mandatory contributions from individuals or entities to the regions in accordance with applicable laws and regulations and are used in running the government with the aim of accelerating development and people's welfare. This study aims to determine the level of contribution of local taxes to PAD. This type of research is descriptive quantitative. The data collection technique used documentation techniques sourced from the 2020-2022 Tanah Datar Regency PAD documents. The results of this study indicate that the contribution of local taxes to PAD in 2020 is 14.57%, in 2021 it is 16.17% and in 2022 it is 17.22%. In general, the contribution of local taxes to PAD has increased every year, but based on the classification criteria, the contribution is included in the less category. The Tanah Datar District Government through the Regional Revenue Management Agency should maximize human resources and infrastructure in maximizing revenue from the local tax sector.
SATISFACTION OF CPNS LATSAR PARTICIPANTS DURING THE COVID-19 PANDEMIC AT THE HUMAN RESOURCES DEVELOPMENT CENTER REGIONAL BUKITTINGGI
Authors: Dwi Utami Andari
Published: October 2023

This study examines the satisfaction of CPNS Latsar training during the Covid-19 pandemic at the Bukittinggi Regional Human Resources Development Center (PPSDM). The research method used in this study was a literature review with the topic of CPNS latsar training during the Covid-19 pandemic. The purpose of this study was to measure Latsar's training satisfaction. Information is obtained from official websites, academic articles and other sources deemed relevant. Based on this description, it can be concluded that the analysis of participant satisfaction greatly affects the training of latsar during the covid-19 period which is still less effective in carrying out online training.especially the Bukittinggi Regional PPSDM to be able to improve and increase participant satisfaction because this can support the success of the implementation of the latsar training organized by the Bukittinggi Regional PPSDM itself.And tolatsar training participants, in order to be able to read the training module that has been provided as a guide and be serious in participating in the latsar training in a more proactive way during discussions.
The influence of E-Commerce on the function of space and the environment in the Home Industry area (Case Study: Home industry in Rw.03 , Kel. Cibaduyut , Bandung City)
Authors: Yulistian Saldi , Metra Pol
Published: October 2023

Digital information technology is developing quite rapidly in Indonesia, opening up new opportunities as well as challenges in various fields of daily life, because in the era of development of digital information technology it touches various aspects of life. One aspect is the cottage industry sector. The use of digital information technology in the home industry can facilitate buying and selling activities and promotions in E-Commerce stalls without having to meet face-to-face between sellers and buyers. For most business actors, production, distribution, sales, and promotion activities are carried out in the same place, namely at home/production workshop. Activities carried out in the same place cause changes in the space and environment for both the business actors themselves and the surrounding environment. In addition, these activities will also affect socio-economic changes and environmental changes, considering that the location of this research is in a dense village with almost no distance between houses. The research is located in Rw. 03 Cibaduyut sub-district, Bandung City with the majority of respondents having businesses made from leather such as; shoes and sandals. This study uses an approach through direct observation, interviews and surveys. The results of the study reveal the effect of E-Commerce on space and the environment in the cottage industry area. So that this research can be used to see the behavior of the community and the needs of industry players in structuring a dense village environment.
Analysis of the Effect of Natural Resources on the Quality of Human Development through Jambi Province Capital Expenditures
Authors: Ramli Fauzan , Safitri Yuliana
Published: October 2023

The natural resources owned by each Regency/City in Jambi Province are different, this has an impact on regional progress, especially the level of human development. The important role of local governments in improving human development through spending in the field of education and health in particular. This study aims to analyze; (1) How natural resource revenue-sharing funds contribute maximally to Regency/City capital expenditures in Jambi Province (2) The effect of general mining revenue-sharing and oil-gas revenue-sharing funds on capital expenditures in Jambi Province, (3) Effect of mining revenue-sharing funds general and oil and gas revenue-sharing funds to the Human Development Index through capital expenditures in Jambi Province. This study uses quantitative descriptive analysis methods and path analysis,(2) The results of the multiple linear regression equation are general mining revenue sharing (X1) and shared funds. The results of oil and gas (X2) on capital expenditure show that the independent variable has a simultaneous effect with an R-Squared value of 0.7521 or 75.21% while the remaining 24.79% is influenced by other variables, (3) General mining revenue sharing directly had a significant effect on HDI was 2.92% and had an indirect effect of 0.29%, meanwhile the oil and gas profit sharing funds had no significant effect on HDI.
Students' motivation and engagement in the learning process of literature teaching using imaginative re-creation technique
Authors: Rifqi Muhammad
Published: October 2023

This article investigates the influence of imaginative re-creation techniques on students' motivation and engagement within the context of literature teaching. Traditional pedagogical methods often struggle to maintain high student involvement in literature classes. This single-case research employed a mixed-methods approach combining observation and questionnaire data to assess students' motivation and engagement. A total of forty-five participants were involved in the study. Quantitative analysis of the questionnaires revealed an average level of motivation and engagement. However, a qualitative analysis of observations demonstrated that students exhibit a heightened sense of enthusiasm and engagement during class sessions that incorporate imaginative re-creation techniques. The findings suggest that while questionnaire responses might not fully capture the extent of students' enthusiasm, the classroom atmosphere is positively affected by the implementation of imaginative re-creation techniques. This implies that students' active participation and emotional connection with the literature are better reflected in their in-class behaviors than in self-reported questionnaire responses. In conclusion, this article highlights the complex relationship between students' self-reported motivation and engagement and their observable behavior during literature classes incorporating imaginative re-creation techniques. It underscores the need for a comprehensive assessment considering quantitative and qualitative data to understand students' educational experiences better. By integrating imaginative re-creation techniques into literature teaching, educators can foster a dynamic and engaging learning environment that goes beyond average questionnaire results and cultivates a genuine passion for literary exploration among students.
Piloting film-based intervention on santri’s perception towards striving for academic success: findings from Kampung Santri, Kudus Regency
Authors: Muna Nailil , Widiyati Elok , Wulandari Diyah Fitri
Published: October 2023

This study is performed based on concerns that knowledge dichotomy in traditional Islamic boarding schools has not received the serious attention it deserves. In contrast to modern pesantren where santri receives both religious and non-religious knowledge, most traditional pesantren in Jekulo, Kudus regency only emphasizes religious knowledge as their core curriculum. Our preliminary study in 2022 suggested that the majority of student santri in Jekulo, Kudus regency showed unfavorable perceptions towards pursuing higher education despite being offered financial aid and academic mentorship. Our current task is to introduce film-based intervention and document its effect on santri’s perception change towards academic success. Although the use of film-based intervention to change perception and reduce stigma has been profound in the field of clinical psychology, its application in a nonclinical setting is still understudied. Using Social Comparison Theory (Festinger, 1954) as our analytical framework, we propose that historical film can be introduced as an alternative point of reference for our subject. Respondents were selected using purposive sampling (n=20). Pre- and post-studies are provided to document santri’s perception change toward striving for academic success. The results of this study confirm that film intervention can act as positive stimuli in the process of perception changes among santri by presenting relatable cinematic historical experiences as an alternative social reference. However, a lack of a role model and a shared perception toward academic success in santri’s immediate environment can hinder the process
Critical discourse analysis of Fajriatun Nurhidayati’s Nyadran-Belajar Toleransi pada Tradisi
Authors: Chamalah Evi , Nuryyati Reni , Azizah Aida
Published: October 2023

Critical Discourse Analysis is a form of analysis that aims to reveal ideology, power, political attitudes, and gender. In this study, Critical Discourse Analysis is used to reveal the ideology and power contained in the language used by the author in Nyadran's book. Every discourse that discusses a topic of ideology and power always contains prejudice. This is what makes language expressions contain symbolic meanings. The critical discourse analysis that has been carried out in Nyadran-Belajar Toleransi pada Tradisi by Fajriyatun Nurhidayati can be concluded that to express ideology in a literary text, language cannot be placed in a closed manner. Nonetheless, the context within a literary text serves as a crucial factor in shaping discourse ideology. Furthermore, literary works are inherently intertwined with the author's creative circumstances, thereby rendering the interpretation of textual meaning inseparable from the employed language. Within this examination, it's evident that ideology in literary compositions and language itself defies rigid categorization, underscoring the significance of the contextual backdrop as a fundamental influencer on the ideology woven into the discourse.
PowToon software’s impact on EFL students’ writing of narrative text
Authors: Muniroh Rima Zahrotul , Maharani Mega Mulianing , Anwar Choiril , Ekaningsih Nur
Published: October 2023

The development of technology brings challenges for teachers to be more innovative and creative in delivering materials. Teachers need to explore currently medium for teaching. To assist teachers and students in overcoming their difficulties, PowToon Software was chosen. The goal of this study was to find out whether PowToon as a learning media was effective in improving the narrative text writing ability of grade XI students at SMA Negeri 1 Pegandon in the 2023/2024 academic year. This study used a quasi-experimental method. The sample consisted of grade XI 1 students as the control group and XI 2 as the experimental group. The control group and experimental group completed the pre-test and post-test. Data analysis in the study used SPSS. The results showed a significance improvement in students' writing achievement. This was evidenced by the significance value of 0.003. The value was smaller than 0.05 and this means that H0 was rejected and H1 was accepted. It can be summarized that the use of PowToon Software as a learning media was effective to improve students' narrative text writing ability.
Conventional gingivectomy for chronic gingival enlargement in orthodontic treatment: a case report
Authors: Ratnawati Irma Dewi , Pratiwi Rosa
Published: October 2023

Background: Gingival enlargement, also known as gingival overgrowth, is an enlargement of the gum tissue. There are many possible causes for enlarged gums. Gingival enlargement is general feature of gingival diseases. It is common note to chronic inflammatory gingival enlargement was caused by poor of oral hygiene. Orthodontic braces can interfere with good oral hygiene, contributing to the development of the inflammatory process. One of the most common soft tissue problems related to fixed orthodontic appliances is gingival hypertrophy or hyperplasia. Maintaining oral hygiene is hindered in cases of gingival hypertrophy due to orthodontic appliances. The most widely used surgical method to treat gingival hypertrophy is gingivectomy.
Case Report : A 27-year-old patient was referred to the periodontal clinic of Airlangga University Dental Hospital because of primary gingival swelling with gingival bleeding during brushing in the anterior mandibular region. On intra oral examination showed excessive gingival with probing depth was range 4 mm on teeth 42-32, revealing the presence of pseudopockets. Clinical examination revealed generalized gingival enlargement as well as generalized bleeding on examination. After explaining the condition and treatment to the patient, he was registered for phase I treatment. After evaluating phase I therapies, phase II treatment with gingivectomy and gingivoplasty were required using a scalpel.
Conclusion: Conventional gingivectomy gives satisfactory result in treating the inflammatory gingival enlargement.