bluuebunny/crossref_metadata_2025 huggingface dataset:
Crystallographic identification of a novel 2,4,5-tri(N-methyl-4-pyridinium)-1,3-thiazole with a complex network of polyiodide/iodine counter ions and co-crystallized cyclododecasulfur (S12)
Authors: Shotonwa Ibukun Oluwaseun , Boere Rene T.
Published: June 2021

The crystals of an unprecedented 2,4,5-tri(N-methylpyridinium)-1,3-thiazole are monoclinic and belong to the space group P21/c as determined by single-crystal XRD. Crystal data for C21H21I13N4S5.98: monoclinic, a = 7.5627(5) Å, b = 30.6764(19) Å, c = 20.8848(15) Å, β = 91.632(6)°, V = 4843.2(6) Å3, Z = 4, T = 100.01(10) K, μ(Cu Kα) = 67.840 mm-1, Dcalc = 2.977 g/cm3, 17906 reflections measured (7.152° ≤ 2Θ ≤ 162.94°), 17906 unique (Rsigma = 0.0607) which were used in all calculations. The final R1 was 0.1366 (I > 2σ(I)) and wR2 was 0.3926 (all data). The crystal lattice contains 2,4,5-tri(N-methylpyridinium)-1,3-thiazole, molecular iodine and triiodide counterions which interact with one another to coordinatively form polyiodides, as well as a surprising co-crystallized neutral molecule of cyclododecasulfur (S12). Close monitoring of the synthetic procedure reveals chemical condensation and decomposition of the thioamide reagent to be the impetus for the formation of individual components of the crystal lattice. Analysis of the XRD, including a Hirshfeld surface analysis, shows that (a) the crystal lattice has a number of stabilizing Coulombic short contacts such as I∙∙∙I, I∙∙∙S, I∙∙∙C, and C∙∙∙S and non-classical C-H∙∙∙I and C-H∙∙∙S hydrogen bond interactions (b) the iodine/iodide network are major determinants in the stability of its crystal lattice despite the reduced occupancies of sulfur and (c) the Hirshfeld analysis in comparison with the conventional Mercury visualization program was able to simplify, identify and quantify complex atom-atom interactions such as H∙∙∙H and N∙∙∙I in its crystal lattice. Herein, it is reported, for the first time, the formation of co-crystallized, neutral cyclododecasulfur (S12) from thioamide as the sulfur source. S12 displays a consistent geometry and comparable average S-S distances, S-S-S angles and torsion angles with previously reported crystal structures of S12. The complex network facilitated by the formation of polyiodides via the interaction of symmetric and asymmetric triiodides and iodine has resulted in quite strong interactions that are less than the sums of the van der Waals radii of two connected atoms as well as an array of fascinating geometrical alignments such as T-shape, trigonal pyramidal and L-shape.
Synthesis, crystal structure with free radical scavenging activity and theoretical studies of Schiff bases derived from 1-naphthylamine, 2,6-diisopropylaniline, and substituted benzaldehyde
Authors: Oladipo Segun Daniel , Yusuf Tunde Lewis , Zamisa Sizwe Joshua , Tolufashe Gideon Femi , Olofinsan Kolawole Ayodapo , Tywabi-Ngeva Zikhona , Mabuba Nonhlangabezo
Published: June 2021

Three Schiff bases 1-(4-chlorophenyl)-N-(naphthalen-1-yl)methanimine (1), 1-(4-methoxy phenyl)-N-(naphthalen-1-yl)methanimine (2), and 1-(4-chlorophenyl)-N-(2,6-diisopropyl phenyl)methanimine (3) were synthesized and characterized by elemental analysis, 1H and 13C NMR, FT-IR and UV-Visible spectroscopic techniques. The crystal structure of compound 3 was obtained and it revealed that the compound crystallized in a monoclinic space group P21/n and there exists an intermolecular hydrogen bond in a phenyl-imine form with C-H⋯N. Crystal data for C19H22ClN: a = 7.28280(10) Å, b = 9.94270(10) Å, c = 24.0413(2) Å, β = 97.0120(10)°, V = 1727.83(3) Å3, Z = 4, μ(Mo Kα) = 0.215 mm-1, Dcalc = 1.1526 g/cm3, 14038 reflections measured (12.42° ≤ 2Θ ≤ 52.74°), 3448 unique (Rint = 0.0223, Rsigma = 0.0182) which were used in all calculations. The final R1 was 0.0337 (I≥2u(I)) and wR2 was 0.0927 (all data). The free radical scavenging activities of all three compounds were assayed using DPPH, FRAP, and OH assays. According to results obtained, compound 2 shows effective DPPH- (IC50 = 22.69±0.14 μg/mL), FRAP+ (IC50 = 28.44±0.12 μg/mL), and OH- (IC50 = 27.97±0.16 μg/mL) scavenging activities compared with compounds 1 and 3 but less than standard antioxidant compound Trolox (TRO). Additionally, theoretical calculations for the three complexes were performed by using density functional theory (DFT) calculations at the B3LYP/6-31++G(2d,2p) level in the ground state to obtain an optimized geometrical structure and to perform an electronic, molecular electronic potential surface and natural bond orbital (NBO) analysis. The geometrical calculation obtained was found to be consistent with the experimental geometry. Further analysis was conducted using the in silico technique to predict the drug likeness, molecular and ADME properties of these molecules.
Synthesis and characterization of Ti(IV), Zr(IV) and Al(III) salen-based complexes
Authors: Hipolito Joana , Alves Luis , Martins Ana
Published: June 2021

New Ti(IV), Zr(IV) and Al(III) salen-based complexes of formulae [(L)TiCl2], 2, [(L)ZrCl2], 3, and [(L){Al(CH2CH(CH3)2)2}2], 4, where L = meso-(R,S)-diphenylethylene-salen, were synthesized in high yields. [(L){Al(CH2CH(CH3)2)2}2] is a bimetallic complex that results from the reaction of H2L with either 1 or 2 equivalent of Al(CH2CH(CH3)2)3. The solid-state molecular structures of compounds 2 and 4·(C7H8) were obtained by single-crystal X-ray diffraction. Crystal data for C44H54Cl2N2O2Ti, (2a): monoclinic, space group C2/c (no. 15), a = 27.384(1) Å, b = 12.1436(8) Å, c = 28.773(2) Å, β = 112.644(2)°, V = 8830.6(9) Å3, Z = 8, μ(MoKα) = 0.350 mm-1, Dcalc = 1.146 g/cm3, 26647 reflections measured (5.204° ≤ 2Θ ≤ 50.7°), 8072 unique (Rint = 0.0967, Rsigma = 0.1241) which were used in all calculations. The final R1 was 0.0640 (I > 2σ(I)) and wR2 was 0.1907 (all data). Crystal data for C62H72Cl2N2O2Ti (2b): monoclinic, space group P21/c (no. 14), a = 19.606(1) Å, b = 12.793(1) Å, c = 23.189(2) Å, β = 105.710(4)°, V = 5599.0(7) Å3, Z = 4, μ(MoKα) = 0.291 mm-1, Dcalc = 1.182 g/cm3, 37593 reflections measured (3.65° ≤ 2Θ ≤ 50.928°), 10304 unique (Rint = 0.0866, Rsigma = 0.1032) which were used in all calculations. The final R1 was 0.0593 (I > 2σ(I)) and wR2 was 0.1501 (all data). Crystal data for C67H97Al2N2O2 (4·(C7H8)): triclinic, space group P-1 (no. 2), a = 10.0619(9) Å, b = 16.612(2) Å, c = 21.308(2) Å, α = 67.193(5)°, β = 78.157(6)°, γ = 77.576(5)°, V = 3176.8(6) Å3, Z = 2, μ(MoKα) = 0.088 mm-1, Dcalc = 1.063 g/cm3, 42107 reflections measured (5.382° ≤ 2Θ ≤ 51.624°), 12111 unique (Rint = 0.0624, Rsigma = 0.0706) which were used in all calculations. The final R1 was 0.0568 (I > 2σ(I)) and wR2 was 0.1611 (all data). The solid-state molecular structure of [(L){Al(CH2CH(CH3)2)2}2] reveals that both metal centres display a slightly distorted tetrahedral geometry bridged by the salen ligand. Both [(L)TiCl2] and [(L)ZrCl2] complexes display octahedral geometry with trans-chlorido ligands.
The scientific community in COVID-19 global pandemic: A systematic update on recent progress and challenges
Authors: Firdaus Zeba , Singh Sushil Kumar , Singh Tryambak Deo , Singh Meenakshi
Published: June 2021

The novel coronavirus, which emerged in China in late December 2019, is officially named as Severe Acute Respiratory Syndrome Coronavirus 2 (SARS-CoV-2). The rapid spread of the virus across the continent has disrupted human life in every aspect leading to health and economic crises. The World Health Organization (WHO) declared the novel coronavirus outbreak as a global pandemic on March 11, 2020. In spite of complete lockdown and quarantine efforts in many countries, the occurrence of infections continues to rise, with more than 88 million laboratory-confirmed cases and over 1.9 million deaths worldwide as on January 10, 2021. Since the beginning of the outbreak, lot of intriguing studies about the phylogenetic evolution, epidemiology, pathogenesis, transmission, clinical characteristics, and possible treatment of Corona Virus Disease 2019 (COVID-19) have been published. This review aims to provide an insight into the progress in this regard and provides a reference for future studies including general awareness. We have discussed the origin, transmission, and infection mechanism of coronaviruses in host cells as well as available treatment options with relevant case studies. Furthermore, the stages of vaccine development, types of vaccines, and candidate vaccines with their phases of clinical trial are also incorporated. In a nutshell, the article is an attempt to retrieve the latest information available on virus behavior, efficacy of the available drugs, and development of candidate vaccines on SARS-CoV-2.
HUKUK YARGILAMASINDA TARAF VEKİLİ AVUKATIN TANIKLIĞI
Authors: Çiçekli Ali Fuat
Published: June 2021

Tanıklık, taraflar arasında çekişmeli olan olaylar hakkında bilgi sahibi olan taraflar haricindeki bir kimsenin, bildiklerini mahkemeye sunmasıdır. Davada vekâlet ise tarafın mahkemede temsilidir. Vekillik rolü ile tanıklık rolü birbirinden ayrı olarak konumlanır. Vekilin tarafla ilişkisi ve onun yargılamadaki konumu da tanıklık rolüne etki edecek niteliktedir. Taraf vekili, kural olarak avukat olmak zorundadır. Çalışmada tanıklık yapma zorunluluğu ve tanıklıktan çekinme hakkına sahip bulunan kimseler açıklanmıştır. Ardından davada iradi-kanuni temsil kurumu ve avukatın temsil yetkisi incelenmiştir. Tanıklık üzerinden taraf vekili avukatın, hem taraf vekili olmasından hem de mesleki konumundan kaynaklanan çeşitli nitelikleri bulunmaktadır. Taraf vekili olması, adil yargılanma hakkı, silahların eşitliği ilkesi ve hukuki dinlenilme haklarını ilgilendirmektedir. Mesleki konumu ise onun yargının kurucu unsurlarından bağımsız savunma görevi ve hukukun yerine getirilmesi işlevine işaret etmektedir. Çalışma, tüm bu ihtimaller dâhilinde karşılaştırmalı hukuktaki örneklerine de değinerek taraf vekili avukatın tanık olup olamayacağını incelemektedir.
UÇUŞ PERSONELİNİN ÇALIŞMA YAŞAMINDAKİ BAŞLICA SORUNLARI
Authors: Şimşek Kuzpınar Hatice Ebru
Published: June 2021

4857 sayılı İş Kanunu’nda birtakım iş ve iş ilişkileri kanunun kapsamı dışında bırakılmıştır. İlgili Kanun’un 4. maddesinin a bendinde ‘‘hava taşıma işleri’’ kanun kapsamı dışında bırakılan istisnai işlerden birisidir. Bir bütün olarak değerlendirilmesi gereken havacılık sektörü, yine aynı maddede ‘‘havacılığın bütün yer tesislerinde yürütülen işleri’’ fıkrası altında İş Kanunu hükümlerine tabi tutulmuştur. Kanun kapsamında sayılmayan ve uçucu personel olarak adlandırılan pilot, uçuş hostesi, kabin memuru ve hava taşıma anında görevli olarak çalışan kişilerin hakları özel bir İş Kanunu’yla korunmayıp Borçlar Kanunu’nun hizmet sözleşmesi hükümlerine tabi tutulmaktadır. Tehlikeli ve Çok Tehlikeli Sınıfta Yer Alan İşlere Dair Yönetmelikte sayılan ve bu işler için mesleki eğitim alınması gereken işlere ait çizelgede, uçaklarda yapılan bütün işler için mesleki eğitimin şart tutulması da göz önüne alındığında hali hazırda kendi özel Hava İş Kanunları olmayan ve İş Kanunu’na tabi tutulmayan uçucu personel, eğer ki sendika üyesi değilse veya toplu iş sözleşmesiyle İş Kanunu’na tabi kılınmamışsa kıdem tazminatında ciddi sıkıntı yaşayabiliyor. Uçuş personelinin çalışma yaşamında karşılaştığı sorunlar, Yargıtay içtihatları ışığında ve işçilere tanınan yasal haklar çerçevesinde incelenmiştir.
TASARRUFUN İPTALİ SEBEPLERİ
Authors: Sezgin Sedat
Published: June 2021

Tasarrufun iptali sebepleri İcra-İflas Kanunu’nda ivazsız tasarrufların butlanı, acizden dolayı butlan ve zarar verme kastından dolayı iptal başlıkları altında düzenlenmiştir. Lakin tasarrufun iptali sebepleri sınırlı sayıda değildir. Borçlandırıcı işlemler tasarrufun iptali sebebi oluşturmaz. Tasarruf kelimesi yalnızca hukuki tasarrufları değil hukuki fiileri de kapsar. 2018 yılında Anayasa Mahkemesi kan hısımları arasında yapılan ivazlı tasarrufların ivazsız tasarruf olarak kabul edilmesini iptal edilmiştir. İptal kararı ile kanun koyucu tarafından ivazlı tasarruflar olarak kabul edilen altsoy ve üstsoy, karı ve koca ve sıhri hısımlar arasındaki ivazsız tasarruflar hakkında hangi hükümlerin uygulanması gerektiği belirsizdir. İcra-İflas Kanunu madde 279 başlığında geçen aciz kelimesinin kullanılmasıyla bir terminolojik hata yapılmıştır. İcra-İflas Kanunu madde 279’da belirtilen aciz başlığında anlatılmak istenen husus borca batıklığa ilişkindir. Zira borçlunun aktifinin pasiflerine oranla miktaren yeterli düzeyde bulunmaması borca batıklık halidir.
SENEDİN YAĞMASI SUÇU
Authors: Taş Burak
Published: June 2021

Senedin yağması suçu, yağma suçunun özel bir şekli olarak 5237 sayılı Türk Ceza Kanunu’nun 148. maddesinin ikinci fıkrasında malvarlığına karşı bir suç olarak düzenlenmiştir. Cebir veya tehdit kullanılarak mağdurun, kendisini veya başkasını borç altına sokabilecek bir senedi veya var olan bir senedin hükümsüz kaldığını açıklayan bir vesikayı vermeye, böyle bir senedin alınmasına karşı koymamaya, ilerde böyle bir senet haline getirilebilecek bir kağıdı imzalamaya veya var olan bir senedi imha etmeye veya imhasına karşı koymamaya mecbur edilmesi halinde yağma suçu için öngörülen altı yıldan on yıla kadar hapis cezası bu suç bakımından da öngörülmüştür. Bu çalışmada senedin yağması suçu, tahlilci yöntemle suç genel teorisi bağlamında incelemeye tabi tutulmuştur. Yağma suçu ile benzer hukuki değeri koruyan senedin yağması suçunun yağma suçundan farklı tarafları odak alınarak incelenmiştir. Bileşik bir suç niteliğinde olan bu suçla ilgili özellik arz eden hususlar ile genel olarak söz konusu suçla ilgili doktrin ve Yargıtay uygulamaları değerlendirilerek sonuca ulaşılmıştır.
The CORRECT-19 Model: Eight Desired Roles of Religious Leaders during the COVID-19 Pandemic
Authors: Wijesekara N.W.A.N.Y. , Jayasinghe Dimantha
Published: June 2021

Religious leaders support communities in multiple ways during challenges such as disasters, emergencies, conflicts, and outbreaks. The COVID-19 Pandemic, too, has demonstrated the contribution of religious leaders in assisting communities across the world. On the other hand, a minority of religious leaders also have contributed to the aggravation of the outbreak, for example, by organizing religious mass gatherings, neglecting the warning given by health authorities. Thus, it is evident that the religious leaders have had both positive and negative roles during the Pandemic. The Resilience Research, Training and Consulting is implementing a project titled COmmunity Resilience through Religious Engagement for Community Trust during Covid-19 (CORRECT-19) through a grant supported by the Awareness with Human Action (AHA) project funded by the European Union. As a part of the CORRECT-19 project, we are conducting a series of focus group discussions and key informant interviews with the religious leaders from multiple religions, faiths, and spiritual traditions in Sri Lanka on their contributions during the COVID-19 Pandemic. We used content analysis to identify undesired behaviors, desired behaviors, and desired roles, using the evidence from the mainstream western medical and epidemiological systems as the point of reference in determining what is desired and undesired. The CORRECT-19 Model enlists eight desired roles of religious leaders during the Pandemic, namely the Faith-Setter, Health Promoter, Be-Friender, Social Worker, Community Mobilizer, Networker, Peacebuilder, and Advocate. We designed eight representative infographics to communicate the desired roles of religious leaders during the Pandemic. The CORRECT-19 Model depicting the eight desired roles is a helpful communication and advocacy tool in the active and meaningful engagement of religious leaders in managing the COVID-19 Pandemic.
Uso de sugammadex en un paciente con insuficiencia renal crónica
Authors: Erazo Vaca Gabriel Alonso , Calderón Jaime Christian Raúl
Published: June 2021

Los pacientes con enfermedad renal crónica poseen distintos tipos de factores, tanto fisiológicos como farmacológicos, que alteran la farmacocinética y farmacodinámica de los relajantes musculares no despolarizantes (RMND) lo que hace que la función neuromuscular sea impredecible. La Administración de Alimentos y Medicamentos de los Estados Unidos (FDA) determina como una contraindicación el uso del sugammadex en aquellos pacientes que presenten falla renal crónica asegurando que el aclaramiento de sugammadex se reduce y la vida media se prolonga en estos pacientes; es por este motivo la importancia de su estudio. En el Ecuador, el sugammadex ingresó al Cuadro Nacional de Medicamentos Básicos en el año 2019 para determinados casos especiales.  Presentamos el caso de un paciente masculino de 47 años con insuficiencia renal crónica en terapia restitutiva renal que fue sometido a una gastroduodeno anastomosis en Y de Roux más antrectomía laparoscópica, en quien se utilizó exitosamente sugammadex para reversión completa del bloqueo neuromuscular profundo.
Pancreatitis aguda por hipertrigliceridemia. Uso de plasmaféresis: reporte de caso
Authors: Silva Cevallos Danny Fernando , Barrera Rivera Mirella , Evangelista Barragán Diana Stefania , Arreaga Pérez César Enrique
Published: June 2021

La pancreatitis aguda por hipertrigliceridemia (PATG) se describe como una causa poco común de pancreatitis, con una incidencia que oscila entre el 2 al 4% de los casos; genera una morbilidad y mortalidad importante de aproximadamente 40 por cada 100.000 personas. Varios son los mecanismos fisiopatológicos que explican la aparición de pancreatitis causada por hipertrigliceridemia; uno de ellos es el papel tóxico directo de los ácidos grasos libres sobre el tejido pancreático y, otro mecanismo ampliamente acogido, es la obstrucción vascular mediada por los quilomicrones, dada la disminución de la expresión genética de la lipoprotein lipasa. La Sociedad Americana de Aféresis (ASFA) indica el uso de plasmaféresis en casos de pancreatitis severa, cuando los niveles de triglicéridos exceden los 2000 mg/dl y cuando no hay respuesta satisfactoria al tratamiento de primera línea. El objetivo del uso de plasmaféresis y éxito del tratamiento se basa en un descenso de los triglicéridos por debajo de 500 mg/dl. En este caso se demostró que la valoración oportuna de la paciente y la instauración del tratamiento con plasmaféresis en el tiempo adecuado fue fundamental para la resolución de su patología.
Editorial
Authors: Bhat G M
Published: June 2021

Is Nuclear Energy the Answer to India’s Growing Energy Needs?
VISION OF THE PHENOMENON OF THE NATIONAL COLLECTIVE MEMORY IN THE CONTEXT OF HISTORICAL PERSONALISM
Authors:   Professor.DoctorofHistory.ENUnamedafterL.N.Gumilevacity,Nur-Sultan,Kazakhstan, Аlpysbes M. , Yerisheva T. ,   PhDdoctoralcandidate,ENUnamedafterL.N.Gumilevacity,Nur-Sultan,Kazakhstan
Published: June 2021

In the historical memory of the Kazakh people, the image of historical figures - fair rulers - the khans, heroic batyrs guarding their country from enemies, and wise bias who cared for their people are well preserved. In modern science they are called national, state, political and public figures. Through the centuries, people have kept their memory from generation to generation, and historical memory has become a tool of such an archive. The main historical characters were presented and described in epic poems, historical legends, legends, making up a set of names and generations of prominent personalities of the legendary country of the Great Steppe. The purpose of the article is to consider the phenomenon of historical memory as a specific phenomenon of memorizing historical figures.
SOME ASPECTS OF PSYCHOLOGICAL CHARACTERISTICS OF MEDIATION STUDENTS
Authors:   Kazakh national pedagogical University named after Abai Almaty, Kazakhstan, Nietbayeva G.B. , Kulzhabayeva S.F. ,   Kazakh national pedagogical University named after Abai Almaty, Kazakhstan
Published: June 2021

This article will examine the basic views on the psychological characteristics of students-psychologists studying in the field of "mediation." The main concepts will be considered: personality traits, neurodynamic features and their stress resistance
SOCIAL ENVIRONMENT FACTORS INFLUENCING THE EMOTIONAL STATE OF STUDENTS WITH SPECIAL EDUCATIONAL NEEDS
Authors:   Zhetysu State University named after I.Zhansugurov, Taldykorgan, Kazakhstan, Almukhambetova B.Zh.
Published: June 2021

The change in the paradigm of education and its new vector –the emergence of inclusive education based on the principle of accessibility of education, covers the category of persons with special educational needs. One of the urgent problems of this direction is the successful socialization of people who have a special need for education in a dynamic modern social environment, ensuring their full participation in society, effective self-realization. In our opinion, the establishment of factors of the socialenvironment that affect the psychological health of students with special educational needs will contribute to the settlement of psycho-emotional state, increasing the degree of success of self-realization. After all, as practice shows, social factors arenot isolated and act in complex interaction with biological and hereditary factors.
TRAINING FUTURE TEACHERS TO USE INNOVATIVE EDUCATIONAL TECHNOLOGIES IN THE CONTEXT OF DIGITALIZATION OF EDUCATION
Authors:   H. Dosmukhamedov Atyrau state University Atyrau, Kazakhstan, Syrbayeba Sh.Zh. , Adilshinova Z.U. ,   Zhubanov Aktove regionalstate University Aktobe, Kazakhstan, Zhangozieva M.S. ,   Sh.Esenov Caspian state University of Technology and Engineering, Turniyazov R.K. ,   H. Dosmukhamedov Atyrau state University Atyrau, Kazakhstan
Published: June 2021

The article is devoted to preparing future teachers to use innovative educational technologies in the context of digitalization of education. The authors reveal the main goal of innovative educational technologies, conduct a comparative analysis of traditional and innovative teaching methods. Also, based on the research work carried out , it reveals the main features that distinguish innovative activity from innovation-oriented activity: the level of significance of new ideas, the level of changes made; the level of adjustment of its actions. It is stated that in the modern global information society, the most important quality and one of the competitiveness criteria for any specialist is the level of readiness for innovation
ON THE ISSUE OF MODERN UNIVERSITY MANAGEMENT: OPTIMIZATION OF THE MANAGEMENT PROCESS
Authors:   Ağrı İbrahim Çeçen Üniversitesi (Ağrı,Turkey), Nurgaliyeva S. , Mailybaeva G.S. ,   I. Zhansugurov Zhetysu State University (Taldykorgan, Khazakhstan), Koishibaev M. N. ,   Korkyt Ata Kyzylorda University (Korkyt Ata,Khazakhstan), Azanbekova G.T. ,   I. Zhansugurov Zhetysu State University (Taldykorgan, Khazakhstan), Isabayeva Z.M. ,   I. Zhansugurov Zhetysu State University (Taldykorgan, Khazakhstan)
Published: June 2021

The authors study an urgent problem of our time-the transformation of University management in modern conditions in the context of modernization of higher education. The relevance of the research is caused by the need for further modernization of higher education in Kazakhstan, along with the development of the quality of education, the problems of University management become important.The purpose of the study: to determine the features of optimizing the management process of a modern University.The empirical base consists of research results analysis of a large number of qualitative and quantitative data collected in 2014-2016 by participants ofthe scientific project "Development of models of best practices of academic management and management in higher educational institutions of Kazakhstan" on the basis of which recommendations for improving the management system in Kazakhstan universities were developed.The results of the study will allow us to take a new look at the activities of universities in modern reality, and systematization of the observed changes in the business processes of universities will require the development of measures to create conditions for the transformation of higher education in the country in order to optimize the quality of the management process
PROBLEMS OF PSYCHOLOGICAL AND PEDAGOGICAL ADAPTATION OF REPATRIATED STUDENTS IN THE LEARNING PROCESS
Authors:   Caspian State University of Technology and Engineering named after Sh. Yessenov (Yessenov University) Aktau, Kazakhstan, Tajibayeva Zh. A. , Saparbay Sh. S. ,   Caspian State University of Technology and Engineering named after Sh. Yessenov (Yessenov University) Aktau, Kazakhstan
Published: June 2021

The article provides an overview of the study of adaptation problems, theoretical approaches and practical research. Adaptation of the individual is considered in relation to socialization and adaptation of the individual in society. The content, characteristics, and features of the adaptation process are also described. Various aspects of adaptation and the specifics of adaptive entry of students-repatriates into the educational space of the University are considered. The methodological foundations and research tools are presented, and a model of the process of psychological and pedagogical adaptation of repatriated students in higher education is developed. Special attention is paid to the personal development and psychological and pedagogical adaptation of repatriated students in the process of studying in a new educational environment
DIAGNOSTICS OF SPECIAL EDUCATIONAL NEEDS AS A CONDITION FOR INCLUDING PRESCHOOL CHILDREN IN THE GENERAL EDUCATION ENVIRONMENT
Authors:   Abai Kazakh National Pedagogical university , Kazakhstan, Almaty, Zavalishina O.V. , Rakhym Zh. ,   Abai Kazakh National Pedagogical university , Kazakhstan, Almaty
Published: June 2021

The article reveals the theoretical foundations and practical procedures for identifying and evaluating special educational needs of preschool children. Diagnostics with special educational needs is a necessary condition for including preschool children in the General education environment and is aimed at improving the system of providing them with comprehensive psychological and pedagogical support in the process of education and training.The content of the article describes a step-by-step procedure for conducting a diagnostic study and the corresponding methodological tools.Attention is focused on the need for a comprehensive analysis of the mechanisms and causes of difficulties in learning and development of a preschool child.The diagnostic results are the basis for the development of an individual program of psychological and pedagogical support, which determines the overall strategy and specific steps in the organization of training and psychological and pedagogical support for a preschool child with special educational needs
PECULIARITIES OF THE FORMATION OF A MULTICONFESSIONAL SOCIETY IN THE SOUTH OF KAZAKHSTAN IN THE PRE-REVOLUTIONARY PERIOD
Authors:   Candidate of Historical Sciences, Senior Lecture, Shymkent UniversityShymkent, Kazakhstan, Abdikhanova A.Zh.
Published: June 2021

The violent interference of tsarist Russia in the centuries-old way of life in Kazakhstan violates the existing order in all spheres of life, including religion. The colonial policy of Russia was accompanied, first of all, by the eradication of the achievements of indigenous peoples in the field of religion and culture and the establishment of their own order and adaptation of the local population to the imperial reality. After the end of the conquest of the southern regions, Tsarist Russia embarked on a plan for the gradual transition of religious policy from laissez-faire to strict regulation. This was due to fears that Islam could become an ideological weapon against successful colonization, so the tsarist plans pinned great hopes on the Christianization of the region.
ADAPTATION OF KAZAKHS ZHETYSU TO A NEW LIFE (II half of the 19th - early 20th centuries)
Authors:   Kazakh National Women's Pedagogical University, Senior Lecturer at the Department of History, PhD.Kazakhstan, Almaty, Bissembayeva L.A.
Published: June 2021

The article examines the problems of life of Kazakhs of Zhetysu in the second half of the 19th - early 20th centuries - changes in clothing, food, housing, utensils, furniture, adaptation of the population to a new life. Changing the way of life and way of life of the Kazakhs in Zhetysu in the second half of the 19th - early 20th centuries is one of the most important topics in national history. Because the political, economic and social changes that took place between 1867-1917, along with social relations, deeply penetrated the inner life of the population and began to radically change the way of life and customs, which for a long time were formed in accordance with the ancient way of life.
DEMOGRAPHIC DEVELOPMENT OF THE INDEPENDENT COUNTRIES OF CENTRAL ASIA
Authors:   Doctor of Historical Sciences, Professor of KazNPU named after AbaiKazakhstan, Almaty, Tulekova М.К.
Published: June 2021

The article describes the demographic development of the new independent countries of Central Asia, its specificity and similarity. Analyzing the direct impact of the political, economic and social development of Central Asia on the demographic situation in the country after the collapse of the USSR, the factors influencing the stabilization of migration processes in the country as a result. . Analysis of social conditions affected by the growth of wages, with a description of the factors influencing the demographic development of modern Central Asia. Keywords: demography, migration, exile, promil.
HISTORY OF COMMERCE DEVELOPMENT ABROAD AND IN KAZAKHSTAN
Authors:   Senior Lecturer, Rustemova А.I. , Baymuratova I. A. ,   Candidate of Philological Sciences, Orazbekova I. G. ,   Candidate of Philological Sciences of Al-Farabi Kazakh National University, Almaty, Kazakhstan
Published: June 2021

This article is devoted to the history of commerce development in foreign countries and in Kazakhstan. Studying the history of commerce development will help us successfully organize activities in the field of commodity circulation. The experience of the past allows us to find ways to apply it in the present, to avoid some mistakes. Understand why some countries get rich and what we need for successful trade. The study of the past allows us to identify some patterns of development and predict possible options for the future. Understand the main factors for promoting trade as geographical location, development of handicraft production. Knowledge of the history of Commerce development makes it possible to better understand the market situation in our own country and in the world. Another advantage is that knowledge of the history of the origin and development of Commerce and entrepreneurship will make it possible to support or justify decisions in further commercial or entrepreneurial activities, based not only on economic knowledge, but also on historical background. It is necessary to know the history of cross-border and international trade, which has contributed to the development of both culture and the economy of Kazakhstan.
ROLE OF TRUST IN KAZAKHSTAN SOCIETY
Authors:   PhD student, AlFarabi University, Almaty, Kazakhstan, Atabayeva G.K. , Abdikerova G.O. ,   doctor of sociological sciences, professor,AlFarabi UniversityAlamty city, Kazakhstan
Published: June 2021

Trust is the basis of self-knowledge and the realization of a person in a complex system of social relations. Therefore, it is necessary that all people understand the essence of this phenomenon. The purpose of the study is to reveal the potentials of trust as a social phenomenon, and to substantiate its role in improving the quality of social relations in Kazakhstani society. The main problem is the insufficiently high level of trust among people in the interpersonal and institutional aspects. Problems arise due to the low level of development of civic values, and the emergence of behavioral patterns that do not comply with the social norms of civil society. Trusting relationships between social actors can develop by improving the basic aspects of successful socialization in the process of creating a competitive nation, such as education, healthcare, culture and social Security. The main tasks of the problem under study are directly related to the disclosure of the essence of social trust, its role in harmonizing social and social relations, in improving the social capital of modern Kazakhstan. Studies of foreign and domestic scientists allow us to understand the conceptual foundations of trust, the interaction strategy of social groups, the prospects for the development of civil society, as well as the features and specifics of the social capital of modern societies, models of civil behavior of the population. Trust plays an important role in building a civil society, is its main institution, as well as the main component of social capital and effective social relations. Today, quality information is reflected in the human mind and affects its social behavior. Therefore, great attention must be paid to the quality of the information provided, and their usefulness to citizens. Types of trust are also characterized by the quality of social relations. The study of trust in modern society is primarily due to the need to disclose its potential resources; secondly, the substantiation of its important role as a structural element of interpersonal and institutional social relations of a particular society. The need to reduce poverty growth in society, distrust and social risks are important challenges facing modern societies
A PRAGMATIC LIFESTYLE IN THE CONTEXT OF SPIRITUAL REVIVAL
Authors:   candidate of historical sciences, associate professor of the Department of World History,Kazakh National Pedagogical University Abay, Yermukanov Y. , Suteeva Kh. ,   Doctor of Historical Sciences, Professor, Department of World History, Kazakh National Pedagogical University Abay, Akylbekova N. ,   Master teacher
Published: June 2021

The article analyzes what kind of pragmatic way of life we should follow in order to become a modern nation. To do this, everyone, the team, and even the state must be as thrifty, content, compact as possible, to pay attention to the good traditions and bright examples of our ancestors, not to allow vain pride, waste and lavishness. It is not for nothing that our people pay special attention to the education of the next generation. The importance of educating the younger generation to the appropriate skills, while striving to establish a healthy and virtuous lifestyle for the formation of spiritual values in the younger generation, is also highlighted.
FORMATION STAGES OF UZBEK-KAZAKH RELATIONS
Authors:   PhD Student, Department of Regional Studies, Faculty of International Relations, L.N. Gumilyov Eurasian National University, Nur-Sultan city, Kazakhstan, Izteleuova Ye.А. , Ospanova А.N. ,   Professor, Department of Regional Studies, Faculty of International Relations, L.N. Gumilyov Eurasian National University, Nur-Sultan city, Kazakhstan
Published: June 2021

Bilateral cooperation between the Republics of Uzbekistan and Kazakhstan are discussed in the article. The Republic of Uzbekistan and the Republic of Kazakhstan are on the threshold of a new relationship, which will be aimed at creating a stable economic situation throughout Central Asia, which will make us an economically powerful region of the world. Also, in the article the economic and human potential of both states are analyzed, common historical roots and long-standing friendship are examined. The authors come to the conclusion that the main task of the Republic of Uzbekistan is to maximize the potential of Kazakh-Uzbek cooperation to achieve strategic benefits for the two countries
FORMATION OF A CULTURE OF INTER-ETHNIC RELATIONS IN THE CONDITIONS OF MODERNIZATION OF PUBLIC CONSCIOUSNESS (ON THE EXAMPLE OF THE MODERN TURKESTAN REGION)
Authors:   Doctoral student of the 1st course of the Eurasian National University after L.N.Gumilyov, Astana, Kazakhstan, Kashkinbayeva А.Т. , Korganova S.S. ,   Ph.D., associate professor of the South Kazakhstan State University named after M.Auezov, employee of the Center for Research of Kazakhstan atDUIA (PRCh) Shymkent, Kazakhstan, Gabdulina B.А. ,   Ph.D., Associate Professor of Eurasian National University after L.N.Gumilyov, Astana, Kazakhstan
Published: June 2021

This article is devoted to the analysis of the factors contributing to the formation of the culture of interethnic relations in the conditions of modernization of public consciousness. To reveal the topic, the statistical data of Turkestan region on ethnic composition were used, the role and importance of the Assembly of people of Kazakhstan and ethno-cultural associations in strengthening interethnic harmony in the region were considered. At the end of the conclusions and suggestions. This article is devoted to the study of the role of ethno-cultural associations of Shymkent and Turkestan region in strengthening interethnic harmony. Ethno-cultural contacts and interethnic communications are shown, which are designed to explain the mechanism of development and functioning of modern ethnic processes, forms of translation and preservation of their ethno-cultural experience. The conclusion that the history and national traditions must be taken into account in the Ethnopolitics of the state is substantiated. Ethno-cultural associations and houses of Friendship should conduct coordinated work in the field of culture, language, traditions, implementing the national policy of the Republic of Kazakhstan
IRONY IN THE STYLE OF OSPANHAN AUBAKIROV
Authors:   Caspian University of Technology and Engineering named after Sh.Yessenov, Aktau, Kazakhstan, Kabylov A.
Published: June 2021

In connection with the prevailing trends of anthropocentrism in modern science, the importance of the problem of idiostyle increases in focusing on increasingly complex phenomena in human psychology and its aesthetic and philosophical cognition. Irony is one of the most important stylistic components that emphasize the individuality of the artist. One of the most effectively used critical and evaluative artistic means in the satirical and humorous stories of the outstanding Kazakh humorist Ospankhan Aubakirov is irony. The article deals with the implementation of irony in the works of the writer as an important tool in the aesthetic and artistic system of satirical works. Types of author's irony and irony from the character in humorous stories of the writer are proved by concrete examples. The author analyzes the nature and features of ironic statements conveyed by the author and characters in works of art. The author also examines the manifestations of irony at the plot level in some of the author's stories, as well as the peculiarities of linguistic and textual types of ironic meaning.
YERIMBET KOLDEYBEKULY'S ROLE IN AITYS
Authors:   Korkyt ATA Kyzylorda University, Kyzylorda, Kazakhstan, Oralova G.
Published: June 2021

The article analyzes the role of Yerimbet Kuldeybekuly in aitys. The individual character of the poet, the essence and art of execution in the written aitys of Yerimbet Akyn were determined. The genre and cognitive nature of Yerimbet Kuldeibekuly's works in the field of letters is studied. Yerimbet Kuldeibekuly's contribution to the literature, culture and spirituality of the nation is determined through written aitys.The worldview of Yerimbet's creativity, performing aitys according to the system of riddles and answers, is analyzed. The peculiarities of Yerimbet Kuldeibekuly's enigmatic aitys, which show the continuity of a certain literary and creative environment, are analyzed, the nature of the tradition of the leading poets in the creation and solution of the enigmatic aitys is confirmed. In the ideological and compositional network of written aitys the description of the tradition of glorification of pedagogical personalities of the enlightened persons in the Zhyrau-poetic, oratory tradition of the Kazakh people is described.The aesthetic meaning of the poetic linguistic use of the aitys of Yerimbet akyn, the semantic meaning of the figurative word usage are highlighted. The nature of the creative individuality of the poet Yerimbet as a literary critic of the epoch in which he lived, the essence of the use of poetic language was determined. The examples of folk wisdom used to expand the poetic thought were considered in the context of the continuation of the tradition of skillful use of proverbs in combination with skill.
DEVELOPMENT OF WORLD CHI LDREN'S LI TERATURE
Authors:   S.Amanzholov East Kazakhstan Uni versi ty, Ust-Kamenogorsk, Kazakhstan, Saganaeva А. , Shakhanova R. ,   Kazakh Nati onal Pedagogi cal Uni versi ty named after Abai , Almaty, Kazakhstan
Published: June 2021

The arti cle exami nes the stages of development of world chi ldren's li terature i n accordance wi th the trends of the formati on of “uni versal li terature”. Chi ldren's li terature i s extremely di verse i n genre and subject matter. The best wri ters around the world devote thei r talent to i t, because they understand that the future of humani ty i s i n the hands of the younger generati on. Wi th the development of reali sti c tendenci es, the deepeni ng of psychologi sm i n the li terature for chi ldren, a volumi nous, multi faceted i mage of chi ldhood i s confi rmed. I n thi s wri ters reveal the ori gi ns of human development, penetrate i nto the i nner world of the chi ld, comprehendi ng the complexi ty and depth of character of young people, show how personali ty i s formed i n the struggle between li ght and dark began as i t percei ves the joy and sorrow of the world, i ts harmony and contradi cti ons. The mai n thi ng that determi nes the creati vi ty of the best wri ters i s trust i n chi ldhood, respect for a growi ng person, the abi li ty to see i n i t potenti al opportuni ti es and maki ngs, development prospects.
FEATURES OF THE USE OF METHODS AND TECHNOLOGIES IN TEACHING THE SUBJECT OF LITERATURE
Authors:   Kazakh National Women's Pedagogical University, Almaty, Kazakhstan, Baltabayeva N. , Yerkinbekova A. ,   Kazakh National Women's Pedagogical University, Almaty, Kazakhstan
Published: June 2021

In this article, there is a need for a new study and teaching of modern Kazakh literature in the science of Kazakh literature. We know that the teaching of Kazakh literature is analyzed and studied in a new way, as the task is to examine it in detail. However, over time, each area of education has not yet been fully studied from the point of view of systematic scientific and methodological training. The relevance of the research lies in the artistic features of Kazakh literature, with a broad focus on current social problems and the topics covered in it, the selection of information, the formation of one's own scientific and methodological approach, effective methods of technology. Systematization, comprehensive analysis of modern effective technologies and methods of teaching Kazakh literature. The goal is to determine the consistency of teaching technologies, the specifics of teaching, and methodological relevance.
MEDIA IMPACT TYPOLOGY IN SCIENTIFIC DISCOURSE
Authors:   JSC “Information and Analytical Center” under the MES RK, Nur-Sultan, Kazakhstan, Ospanova U. , Shakenova M. ,   JSC “Information and Analytical Center” under the MES RK, Nur-Sultan, Kazakhstan
Published: June 2021

This article provides a theoretical overview of existing research with particular focus on the types and models of media impact on the individual and society. The analysis of scientific literature has revealed that despite popularity and extensity of exploration of the issue in the scientific discourse some major inconsistencies are still observed. It should be noted that in most cases the studies are fragmentary, the influence of the media on various social groups is mostly considered from one specific position, and the lack of clearly developed criteria for the typology of media impact. Summarizing the accumulated knowledge in this area, we tried, despite the complexity of identifying and systematizing the classification of media impact, to present a complex typology of media influence on the individual and society.
Street children during COVID-19 pandemic in India
Authors: Pietkiewicz-Pareek Beata
Published: June 2021

The article highlights the impact of the COVID-19 pandemic on street children in India. Children living on the streets during lockdown are severely affected by poor access to food and water, lack of employment, increased likelihood of mistreatment, and a reduction in support services that could help them to change their situation. The pandemic also increases violence and early marriages, which will effectively prevent boys and girls from continuing their remedial programs.
Hygroscopicity of organic compounds as a function of organic functionality, water solubility, molecular weight and oxidation level
Authors: Han Shuang , Hong Juan , Luo Qingwei , Xu Hanbing , Tan Haobo , Wang Qiaoqiao , Tao Jiangchuan , Zhou Yaqing , Peng Long , He Yao , Shi Jingnan , Ma Nan , Cheng Yafang , Su Hang
Published: June 2021

Abstract. Hygroscopic properties of 23 organics including carboxylic acids, amino acids, sugars and alcohols were characterized using a Hygroscopicity Tandem Differential Mobility Analyzer (HTDMA). We show that hygroscopicity of organics varies widely with different functional groups and organics with additional functional groups are more hygroscopic. However, some compounds sharing the same molecular formula or functionality show quite different hygroscopicity, demonstrating that other physico-chemical properties may contribute to their hygroscopicity as well. If the organics are fully dissolved in water (solubility > 7× 10−1 g/ml), we found that their hygroscopicity is mainly controlled by their molecular weight. For the organics that are not fully dissolved in water (slightly soluble: 5 × 10−4 g/ml < solubility < 7 × 10−1 g/ml), we observed that some of them show no obvious water uptake, which probably due to that they may not deliquesce under our studied conditions up to 90 % RH. The other type of slightly soluble organics is moderate hygroscopic and the larger their solubility the higher their hygroscopicity. Moreover, the hygroscopicity of organics generally increased with O : C ratios, although this relationship is not linear. Hygroscopicity of organic compounds were also predicted by two thermodynamic models using the Extended Aerosol Inorganics Model (E-AIM) and UManSysProp. Both models do not consider phase transition and intermolecular interactions in the simulations and show poor representation of the hygroscopicity for most of the organics.
On the use of satellite observations to fill gaps in the Halley station total ozone record
Authors: Zhang Lily N. , Solomon Susan , Stone Kane A. , Shanklin Jonathan D. , Eveson Joshua D. , Colwell Steve , Burrows John P. , Weber Mark , Levelt Pieternel F. , Kramarova Natalya A. , Haffner David P.
Published: June 2021

Abstract. Measurements by the Dobson ozone spectrophotometer at the
British Antarctic Survey's (BAS) Halley research station form a record of
Antarctic total column ozone that dates back to 1956. Due to its location,
length, and completeness, the record has been, and continues to be, uniquely
important for studies of long-term changes in Antarctic ozone. However, a
crack in the ice shelf on which it resides forced the station to abruptly
close in February of 2017, leading to a gap of two ozone hole seasons in its
historic record. We develop and test a method for filling in the record of
Halley total ozone by combining and adjusting overpass data from a range of
different satellite instruments. Comparisons to the Dobson suggest that our
method reproduces monthly ground-based total ozone values with an average
difference of 1.1 ± 6.2 DU for the satellites used to fill in the
2017–2018 gap. We show that our approach more closely reproduces the Dobson
measurements than simply using the raw satellite average or data from a
single satellite instrument. The method also provides a check on the
consistency of the provisional data from the automated Dobson used at Halley
after 2018 with earlier manual Dobson data and suggests that there were
likely inconsistencies between the two. The filled Halley dataset provides
further support that the Antarctic ozone hole is healing, not only during
September but also in January.