bluuebunny/crossref_metadata_2025 huggingface dataset:
Computer-Aided Intracranial EEG Signal Identification Method Based on a Multi-Branch Deep Learning Fusion Model and Clinical Validation
Authors: Wang Yiping , Dai Yang , Liu Zimo , Guo Jinjie , Cao Gongpeng , Ouyang Mowei , Liu Da , Shan Yongzhi , Kang Guixia , Zhao Guoguang
Published: May 2021

Surgical intervention or the control of drug-refractory epilepsy requires accurate analysis of invasive inspection intracranial EEG (iEEG) data. A multi-branch deep learning fusion model is proposed to identify epileptogenic signals from the epileptogenic area of the brain. The classical approach extracts multi-domain signal wave features to construct a time-series feature sequence and then abstracts it through the bi-directional long short-term memory attention machine (Bi-LSTM-AM) classifier. The deep learning approach uses raw time-series signals to build a one-dimensional convolutional neural network (1D-CNN) to achieve end-to-end deep feature extraction and signal detection. These two branches are integrated to obtain deep fusion features and results. Resampling is employed to split the imbalanced epileptogenic and non-epileptogenic samples into balanced subsets for clinical validation. The model is validated over two publicly available benchmark iEEG databases to verify its effectiveness on a private, large-scale, clinical stereo EEG database. The model achieves high sensitivity (97.78%), accuracy (97.60%), and specificity (97.42%) on the Bern–Barcelona database, surpassing the performance of existing state-of-the-art techniques. It is then demonstrated on a clinical dataset with an average intra-subject accuracy of 92.53% and cross-subject accuracy of 88.03%. The results suggest that the proposed method is a valuable and extremely robust approach to help researchers and clinicians develop an automated method to identify the source of iEEG signals.
Immobilization of TiO2 Nanoparticles in Hydrogels Based on Poly(methyl acrylate) and Succinamide Acid for the Photodegradation of Organic Dyes
Authors: You Xiaomeng , Huang Hailong , Zhang Ran , Yang Zhongli , Xu Min , Wang Xuelu , Yao Yefeng
Published: May 2021

Hydrogels have excellent properties that make them ideally suited as host matrices for the immobilization of photoreactive materials such as TiO2 nanoparticles that serve as catalysts in the photodegradation of organic dyes, which is of great importance in practical water pollution treatment applications. However, the application of hydrogels for this purpose remains poorly studied. The present study addresses this issue by developing two types of hydrogels based on poly(methyl acrylate) and succinamide acid with embedded TiO2 nanoparticles for use as photocatalysts in the photodegradation of organic dyes. The results of the analysis demonstrate that the TiO2 nanoparticles are distributed uniformly in the hydrogel matrices, and the hydrogels maintain their original structures after use. The photodegradation efficiencies of the developed TiO2-hydrogels are demonstrated to be reasonably close to that of freely distributed TiO2 nanoparticles in solution for four different organic dyes. In addition, the results of degradation-regeneration cycling tests demonstrate that immobilizing the TiO2 nanoparticles into the hydrogels greatly reduces their loss during utilization, and the photocatalysts can be easily reused. In fact, the two TiO2-hydrogels retain reasonably high photocatalytic degradation performance after four degradation-regeneration cycles.
Ex-LDH-Based Catalysts for CO2 Conversion to Methanol and Dimethyl Ether
Authors: Mureddu Mauro , Lai Sarah , Atzori Luciano , Rombi Elisabetta , Ferrara Francesca , Pettinau Alberto , Cutrufello Maria Giorgia
Published: May 2021

CO2-derived methanol and dimethyl ether can play a very important role as fuels, energy carriers, and bulk chemicals. Methanol production from CO2 and renewable hydrogen is considered to be one of the most promising pathways to alleviate global warming. In turn, methanol could be subsequently dehydrated into DME; alternatively, one-step CO2 conversion to DME can be obtained by hydrogenation on bifunctional catalysts. In this light, four oxide catalysts with the same Cu and Zn content (Cu/Zn molar ratio = 2) were synthesized by calcining the corresponding CuZnAl LDH systems modified with Zr and/or Ce. The fresh ex-LDH catalysts were characterized in terms of composition, texture, structure, surface acidity and basicity, and reducibility. Structural and acid–base properties were also studied on H2-treated samples, on which specific metal surface area and dispersion of metallic Cu were determined as well. After in situ H2 treatment, the ex-LDH systems were tested as catalysts for the hydrogenation of CO2 to methanol at 250 °C and 3.0 MPa. In the same experimental conditions, CO2 conversion into dimethyl ether was studied on bifunctional catalysts obtained by physically mixing the ex-LDH hydrogenation catalysts with acid ferrierite or ZSM-5 zeolites. For both processes, the effect of the Al/Zr/Ce ratio on the products distribution was investigated.
Insights into the Structural Dynamics of Pt/CeO2 Single-Site Catalysts during CO Oxidation
Authors: Dolcet Paolo , Maurer Florian , Casapu Maria , Grunwaldt Jan-Dierk
Published: May 2021

Despite their high atomic dispersion, single site catalysts with Pt supported on CeO2 were found to have a low activity during oxidation reactions. In this study, we report the behavior of Pt/CeO2 single site catalyst under more complex gas mixtures, including CO, C3H6 and CO/C3H6 oxidation in the absence or presence of water. Our systematic operando high-energy resolution-fluorescence-detected X-ray absorption near-edge structure (HERFD-XANES) spectroscopic study combined with multivariate curve resolution with alternating least squares (MCR-ALS) analysis identified five distinct states in the Pt single site structure during CO oxidation light-off. After desorption of oxygen and autoreduction of Pt4+ to Pt2+ due to the increase of temperature, CO adsorbs and reduces Pt2+ to Ptδ+ and assists its migration with final formation of PtxΔ+ clusters. The derived structure–activity relationships indicate that partial reduction of Pt single sites is not sufficient to initiate the conversion of CO. The reaction proceeds only after the regrouping of several noble metal atoms in small clusters, as these entities are probably able to influence the mobility of the oxygen at the interface with ceria.
Steel Slag as New Catalyst for the Synthesis of Fames from Soybean Oil
Authors: Casiello Michele , Losito Onofrio , Aloia Andrea , Caputo Daniela , Fusco Caterina , Attrotto Rosella , Monopoli Antonio , Nacci Angelo , D’Accolti Lucia
Published: May 2021

For the first time, secondary steel slag, the material directly coming from ladle treatments, is used as a catalyst for the biodiesel production without undergoing any preliminary chemical or thermal modifications. Catalytic material 1, which has been pre-ground to sizes below 230 mesh, has been characterized for the surface textural properties and used as a catalyst in the transesterification of triglycerides of soybean oil to produce biodiesel. Reaction conditions were optimized by DOE method, revealing no interdependence between reaction parameters and results, and showed a catalytic activity comparable with that of an analogous slag-deriving catalyst reported in the literature.
The Power of Stress: The Telo-Hormesis Hypothesis
Authors: Jacome Burbano Maria Sol , Gilson Eric
Published: May 2021

Adaptative response to stress is a strategy conserved across evolution to promote survival. In this context, the groundbreaking findings of Miroslav Radman on the adaptative value of changing mutation rates opened new avenues in our understanding of stress response. Inspired by this work, we explore here the putative beneficial effects of changing the ends of eukaryotic chromosomes, the telomeres, in response to stress. We first summarize basic principles in telomere biology and then describe how various types of stress can alter telomere structure and functions. Finally, we discuss the hypothesis of stress-induced telomere signaling with hormetic effects.
Th17 Cells in Viral Infections—Friend or Foe?
Authors: Paiva Iury Amancio , Badolato-Corrêa Jéssica , Familiar-Macedo Débora , de-Oliveira-Pinto Luzia Maria
Published: May 2021

Th17 cells are recognized as indispensable in inducing protective immunity against bacteria and fungi, as they promote the integrity of mucosal epithelial barriers. It is believed that Th17 cells also play a central role in the induction of autoimmune diseases. Recent advances have evaluated Th17 effector functions during viral infections, including their critical role in the production and induction of pro-inflammatory cytokines and in the recruitment and activation of other immune cells. Thus, Th17 is involved in the induction both of pathogenicity and immunoprotective mechanisms seen in the host’s immune response against viruses. However, certain Th17 cells can also modulate immune responses, since they can secrete immunosuppressive factors, such as IL-10; these cells are called non-pathogenic Th17 cells. Here, we present a brief review of Th17 cells and highlight their involvement in some virus infections. We cover these notions by highlighting the role of Th17 cells in regulating the protective and pathogenic immune response in the context of viral infections. In addition, we will be describing myocarditis and multiple sclerosis as examples of immune diseases triggered by viral infections, in which we will discuss further the roles of Th17 cells in the induction of tissue damage.
Mycobacterial Populations Partly Change the Proportions of the Cells Undergoing Asymmetric/Symmetric Divisions in Response to Glycerol Levels in Growth Medium
Authors: Pradhan Atul , Mukkayyan Nagaraja , Jakkala Kishor , Ajitkumar Parthasarathi
Published: May 2021

Twenty to thirty percent of the septating mycobacterial cells of the mid-log phase population showed highly deviated asymmetric constriction during division (ACD), while the remaining underwent symmetric constriction during division (SCD). The ACD produced short-sized cells (SCs) and normal/long-sized cells (NCs) as the sister–daughter cells, but with significant differential susceptibility to antibiotic/oxidative/nitrite stress. Here we report that, at 0.2% glycerol, formulated in the Middlebrook 7H9 medium, a significantly high proportion of the cells were divided by SCD. When the glycerol concentration decreased to 0.1% due to cell-growth/division, the ACD proportion gradually increased until the ACD:SCD ratio reached ~50:50. With further decrease in the glycerol levels, the SCD proportion increased with concomitant decrease in the ACD proportion. Maintenance of glycerol at 0.1%, through replenishment, held the ACD:SCD proportion at ~50:50. Transfer of the cells from one culture with a specific glycerol level to the supernatant from another culture, with a different glycerol level, made the cells change the ACD:SCD proportion to that of the culture from which the supernatant was taken. RT-qPCR data showed the possibility of diadenosine tetraphosphate phosphorylase (MSMEG_2932), phosphatidylinositol synthase (MSMEG_2933), and a Nudix family hydrolase (MSMEG_2936) involved in the ACD:SCD proportion-change in response to glycerol levels. We also discussed its physiological significance.
Physiological Fitness and the Pathophysiology of Chronic Lymphocytic Leukemia (CLL)
Authors: Sitlinger Andrea , Deal Michael A. , Garcia Erwin , Thompson Dana K. , Stewart Tiffany , MacDonald Grace A. , Devos Nicolas , Corcoran David , Staats Janet S. , Enzor Jennifer , Weinhold Kent J. , Brander Danielle M. , Weinberg J. Brice , Bartlett David B.
Published: May 2021

Chronic lymphocytic leukemia (CLL) is associated with physical dysfunction and low overall fitness that predicts poor survival following the commencement of treatment. However, it remains unknown whether higher fitness provides antioncogenic effects. We identified ten fit (CLL-FIT) and ten less fit (CLL-UNFIT) treatment-naïve CLL patients from 144 patients who completed a set of physical fitness and performance tests. Patient plasma was used to determine its effects on an in vitro 5-day growth/viability of three B-cell cell lines (OSU-CLL, Daudi, and Farage). Plasma exosomal miRNA profiles, circulating lipids, lipoproteins, inflammation levels, and immune cell phenotypes were also assessed. CLL-FIT was associated with fewer viable OSU-CLL cells at Day 1 (p = 0.003), Day 4 (p = 0.001), and Day 5 (p = 0.009). No differences between the groups were observed for Daudi and Farage cells. Of 455 distinct exosomal miRNAs identified, 32 miRNAs were significantly different between the groups. Of these, 14 miRNAs had ≤−1 or ≥1 log2 fold differences. CLL-FIT patients had five exosomal miRNAs with lower expression and nine miRNAs with higher expression. CLL-FIT patients had higher HDL cholesterol, lower inflammation, and lower levels of triglyceride components (all p < 0.05). CLL-FIT patients had lower frequencies of low-differentiated NKG2+/CD158a/bneg (p = 0.015 and p = 0.014) and higher frequencies of NKG2Aneg/CD158b+ mature NK cells (p = 0.047). The absolute number of lymphocytes, including CD19+/CD5+ CLL-cells, was similar between the groups (p = 0.359). Higher physical fitness in CLL patients is associated with altered CLL-like cell line growth in vitro and with altered circulating and cellular factors indicative of better immune functions and tumor control.
Transient Receptor Potential Channel Ankyrin 1: A Unique Regulator of Vascular Function
Authors: Alvarado Michael G. , Thakore Pratish , Earley Scott
Published: May 2021

TRPA1 (transient receptor potential ankyrin 1), the lone member of the mammalian ankyrin TRP subfamily, is a Ca2+-permeable, non-selective cation channel. TRPA1 channels are localized to the plasma membranes of various cells types, including sensory neurons and vascular endothelial cells. The channel is endogenously activated by byproducts of reactive oxygen species, such as 4-hydroxy-2-noneal, as well as aromatic, dietary molecules including allyl isothiocyanate, a derivative of mustard oil. Several studies have implicated TRPA1 as a regulator of vascular tone that acts through distinct mechanisms. First, TRPA1 on adventitial sensory nerve fibers mediates neurogenic vasodilation by stimulating the release of the vasodilator, calcitonin gene-related peptide. Second, TRPA1 is expressed in the endothelium of the cerebral vasculature, but not in other vascular beds, and its activation results in localized Ca2+ signals that drive endothelium-dependent vasodilation. Finally, TRPA1 is functionally present on brain capillary endothelial cells, where its activation orchestrates a unique biphasic propagation mechanism that dilates upstream arterioles. This response is vital for neurovascular coupling and functional hyperemia in the brain. This review provides a brief overview of the biophysical and pharmacological properties of TRPA1 and discusses the importance of the channel in vascular control and pathophysiology.
Is It Possible to Reduce the Relative Age Effect through an Intervention on Motor Competence in Preschool Children?
Authors: Mecías-Calvo Marcos , Arufe-Giráldez Víctor , Cons-Ferreiro Miguel , Navarro-Patón Rubén
Published: May 2021

The purpose of the study was to find out whether a short 6-week intervention on motor competence can reduce the Relative Age Effect (RAE) of preschool children born in the first quarter, compared to those born in the fourth quarter of the same year. Seventy-six preschool children (5.20 ± 0.54 years) from Lugo (Spain) participated. A quasi-experimental pre-post-test design was used with an intervention group (n = 32) and a control group (n = 44). The Movement Assessment Battery for Children-2 (MABC-2) was used to collect data before and after the intervention. The data show that, before the intervention, there are significant differences between the control and the intervention group in favor of the former (born in the first quarter of the year) in manual dexterity (p = 0.011), balance (p = 0.002), total test score (p = 0.008), and total percentile score (p = 0.010). After the application of the specific intervention, statistically significant differences were found in aiming and catching (p < 0.001), balance (p = 0.022), total test score (p = 0.001), and total percentile score (p < 0.001) in favor of the intervention group (born in the last quarter of the year). The results obtained suggest that the application of a specific intervention on MC could positively influence the improvement of MC in preschool children (boys and girls) and reduce the differences produced by the RAE.
A Systematic Review of Father–Child Play Interactions and the Impacts on Child Development
Authors: Robinson Erin Louise , StGeorge Jennifer , Freeman Emily Elsa
Published: May 2021

Father–child play engagement has been linked to a variety of child developmental outcomes. However, the most prevalent types of play and child developmental outcomes utilised in research remains unclear. The aim of this study was to systematically review the literature on father–child play interactions and the association with child developmental outcomes for children aged 0–10 years. Database searches generated 1622 abstracts that matched the specified search criteria. Abstract screening and full-text review resulted in 39 included publications. The systematic review revealed that while some paternal play behaviours resulted in different impacts across play types, others reported similar impacts. The findings of this review have implications for potential interventions and parenting resources.
Recommendations for a Pediatric Pain Education Curriculum for Physical and Occupational Therapists: Scoping Review and Survey
Authors: Laekeman Marjan , Schäfer Axel , Moog Martina Egan , Kuss Katrin
Published: May 2021

Specialization training for physiotherapists, occupational therapists, and sports therapists involved in pediatric pain is scarce and curricula are rarely published. The objectives of this study are twofold: firstly, to perform a scoping review to derive important contents for a pediatric pain education curriculum for specialized pain therapists. Secondly, to conduct a survey on specific contents in curricula currently used by pain experts and to obtain their evaluation regarding the importance of such contents for a specialized curriculum. The review substantiated the importance of a specific curriculum in pediatric pain education, but provided little information on adequate contents. In the survey, 45 experts in pediatric pain education confirmed that specific curricula and specialized contents for pediatric pain education are missing. Their answers give a well-defined picture of the specifics needed in the interaction with a pediatric population. The most important items they classified were e.g., the biopsychosocial framework and the impact of pediatric pain on daily life. Those expert ratings were in line with the recommendations of pediatric pain management guidelines. Further curriculum work in an interdisciplinary, international network is highly recommended.
Effect of Target Sintering Temperature on the Morphological and Optical Properties of Pulsed Laser Deposited TiO2 Thin Films
Authors: Kadri Laid , Bulai Georgiana , Carlescu Aurelian , George Stoian , Gurlui Silviu , Leontie Liviu , Doroftei Corneliu , Adnane Mohamed
Published: May 2021

In this paper, we report on the effect of titanium dioxide (TiO2) target sintering temperature on the morphological and optical properties of amorphous titanium dioxide thin films synthesized by pulsed laser deposition (PLD) on indium tin oxide (ITO) glass substrate and subsequently heat-treated in air at low temperature (150 °C). Three types of targets were used, unsintered (pressed at room temperature), sintered at 500 °C and sintered at 1000 °C. The surface morphology of the samples was investigated by scanning electron microscopy (SEM), and profilometry was used for thickness measurements. The structural properties of the films were examined by X-ray diffraction (XRD), while their optical properties were studied by UV‒vis spectroscopy. The obtained TiO2 thin films have an amorphous nature, as shown by XRD analysis. Profilometer showed that sintered target samples have more reliable thicknesses than unsintered ones. The SEM studies revealed the sufficient structural homogeneity of sintered target nanosized TiO2 films and agglomerates in the case of unsintered target film. The UV‒vis transmittance spectra showed high transparency in the visible range of PLD films, proportional to the target sintering temperature. The optical band gaps of the films deposited using the 500 °C and 1000 °C sintered targets are closer to those of anatase and rutile phases, respectively, which provides a promising approach to the challenges of amorphous TiO2-based nanostructures.
Exploring the Effect of NiO Addition to La0.99Ca0.01NbO4 Proton-Conducting Ceramic Oxides
Authors: Yuan Kaili , Liu Xuehua , Bi Lei
Published: May 2021

To improve the performance and overcome the processing difficulties of La0.99Ca0.01NbO4 proton-conducting ceramic oxide, external and internal strategies were used, respectively, to modify La0.99Ca0.01NbO4 with NiO. The external strategy refers to the use of the NiO as a sintering aid. The NiO was added to the synthesized La0.99Ca0.01NbO4 powder as a secondary phase, which is the traditional way of using the NiO sintering aid. The internal strategy refers to the use of NiO as a dopant for the La0.99Ca0.01NbO4. Both strategies improve the sinterability and conductivity, but the effect of internal doping is more significant in enhancing both grain growth and conductivity, making it more desirable for practical applications. Subsequently, the influences of different concentrations of NiO were compared to explore the optimal ratio of the NiO as the dopant. It was found that the sample with 1 or 2 wt.% NiO had similar performance, while with 5 wt.%, NiO doping content hampered the grain growth. In addition, the inhomogeneous distribution of the element in the high-NiO content sample was found to be detrimental to the electrochemical performance, suggesting that the moderate doping strategy is suitable for La0.99Ca0.01NbO4 proton-conducting electrolyte with improved performance. Furthermore, first-principle calculations indicate the origin of the enhanced performance of the internally modified sample, as it lowers both oxygen formation energy and hydration energy compared with the un-modified one, facilitating proton migration.
Carbon Aerogel Based Waterborne Ultra-Black Coatings with High Light Absorption
Authors: Xu Jie , Shi Yifan , Li Jiangling , Cui Guangzhen , Gu Guangxin
Published: May 2021

In this paper, we wish to report the preparation of ultra-black films via spraying coatings composed of waterborne binders and low-cost carbon aerogels on pre-treated tinplate. The CAs were prepared by annealing resorcinol-formaldehyde resin (RF resin) and the following CO2 activation, of which the reflectance was less than 0.4% in a wide wavelength range. The reflectance of different coatings, which using CAs as functional pigments, ranged from 1.8% to 4.3% in the visible light region (400−760 nm), while it ranged from 1.9% to 4.2% in the near-infrared region (760–1100 nm). Further studies revealed the relationship between the pigment-to-binder ratio and reflectance and found the best ratio to be 0.96, and the minimum reflection was less than 1.8%. Outstanding adhesion to the tinplate substrate was also achieved using a two-component polyurethane binder after the thermal cycling test carried out from −100 °C to 100 °C. The fabrication process of ultra-black coatings is particularly convenient to remove the constraints of high costs and complex processes, making it instructive guidance for industrial production.
CHCl3-Dependent Emission Color and Jumping Behavior of Cyclic Chalcone Single Crystals: The Halogen Bond Network Effect
Authors: Tan Zeqing , Zhao Jian , Sun Jingzhi , Zhao Jiaxin , He Xinrui , Liu Zhe , Zhu Lin , Cheng Xiao , Zhou Chuanjian
Published: May 2021

As a conventional strategy to modulate the structure and properties of inorganic single crystals, hydration/solvation is rarely found to function in pure organic single crystal. Herein, we report chalcone single crystals with CHCl3-dependent emission color and jumping behavior. Two crystals: a pure crystal phase (1) with green-yellow emission and a CHCl3-containing co-crystal phase (1•2CHCl3) with orange-red emission were constructed by fine-controlling the crystallization conditions. The special halogen bond network in the crystal packing structure effectively narrows the bandgap and thereby redshift the emission of 1•2CHCl3. 1•2CHCl3 would revert to 1 together with emission color change when losing CHCl3. These findings are similar to the effect of H2O in hydrated inorganic crystals. Notably, owing to a special pre-organized “molecular pair” structure for [2 + 2] cycloaddition, the pure crystal phase 1 exhibits violently photo-induced jumping phenomenon, indicating large potentials in intelligent devices. This work would overturn the previous perception that the structurally simple solvent molecules without conjugation cannot greatly affect the structure and properties of pure organic single crystals and provide a new strategy to construct multi-colored organic fluorescent crystals.
X-ray Natural Circular Dichroism Imaging of Multiferroic Crystals
Authors: Platunov Mikhail S. , Gudim Irina A. , Ovchinnikova Elena N. , Kozlovskaya Ksenia A. , Wilhelm Fabrice , Rogalev Andrei , Hen Amir , Ivanov Vsevolod Y. , Mukhin Alexander A. , Dmitrienko Vladimir E.
Published: May 2021

The polarizing spectroscopy techniques in visible range optics have been used since the beginning of the 20th century to study the anisotropy of crystals based on birefringence and optical activity phenomena. On the other hand, the phenomenon of X-ray optical activity has been demonstrated only relatively recently. It is a selective probe for the element-specific properties of individual atoms in non-centrosymmetric materials. We report the X-ray Natural Circular Dichroism (XNCD) imaging technique which enables spatially resolved mapping of X-ray optical activity in non-centrosymmetric materials. As an example, we present the results of combining micro-focusing X-ray optics with circularly polarized hard X-rays to make a map of enantiomorphous twinning in a multiferroic SmFe3(BO3)4 crystal. Our results demonstrate the utility and potential of polarization-contrast imaging with XNCD as a sensitive technique for multiferroic crystals where the local enantiomorphous properties are especially important. In perspective, this brings a novel high-performance method for the characterization of structural changes associated with phase transitions and identification of the size and spatial distribution of twin domains.
High-Pressure Crystal Structure and Unusual Magnetoresistance of a Single-Component Molecular Conductor [Pd(dddt)2] (dddt = 5,6-dihydro-1,4-dithiin-2,3-dithiolate)
Authors: Cui Hengbo , Yeung Hamish H.-M. , Kawasugi Yoshitaka , Minamidate Takaaki , Saunders Lucy K. , Kato Reizo
Published: May 2021

A single-component molecular crystal [Pd(dddt)2] has been shown to exhibit almost temperature-independent resistivity under high pressure, leading theoretical studies to propose it as a three-dimensional (3D) Dirac electron system. To obtain more experimental information about the high-pressure electronic states, detailed resistivity measurements were performed, which show temperature-independent behavior at 13 GPa and then an upturn in the low temperature region at higher pressures. High-pressure single-crystal structure analysis was also performed for the first time, revealing the presence of pressure-induced structural disorder, which is possibly related to the changes in resistivity in the higher-pressure region. Calculations based on the disordered structure reveal that the Dirac cone state and semiconducting state coexist, indicating that the electronic state at high pressure is not a simple Dirac electron system as previously believed. Finally, the first measurements of magnetoresistance on [Pd(dddt)2] under high pressure are reported, revealing unusual behavior that seems to originate from the Dirac electron state.
Dataset on the Effects of Anti-Insect Nets of Different Porosity on Mineral and Organic Acids Profile of Cucurbita pepo L. Fruits and Leaves
Authors: Formisano Luigi , Ciriello Michele , El-Nakhel Christophe , De Pascale Stefania , Rouphael Youssef
Published: May 2021

The growing interest in healthy foods has driven the agricultural sector towards eco-friendly implementation to manage biotic and abiotic factors in protected environments. In this perspective, anti-insect nets are an effective tool for controlling harmful insect populations concomitantly with reducing chemicals’ interference. However, the low porosity of nets necessary to ensure high exclusion efficiency for a designated insect leads to reduced airflow, impacting the productivity and quality attributes of vegetables. The evidence presented in this dataset pertains to the content of total nitrogen, minerals (i.e., NO3, K, PO4, SO4, Ca, Mg, Cl, and Na), and organic acids (i.e., malate and citrate) of zucchini squash (Cucurbita pepo L. cv. Zufolo F1) in leaves and fruits grown with two anti-insect nets with different porosities (Biorete® 50 mesh and Biorete® 50 mesh AirPlus), is and analyzed by the Kjeldahl method and ion chromatography (ICS3000), respectively. Data of total nitrogen concentration, macronutrients, and organic acids provide in-depth information about plants’ physiological response to microclimate changes induced by anti-insect nets.
Evaluation of Diversity Programs in Higher Education Training Contexts in Spain
Authors: Pérez-Jorge David , Ariño-Mateo Eva , González-Contreras Ana Isabel , del Carmen Rodríguez-Jiménez María
Published: May 2021

Measures adopted by educational systems to improve and adapt the educational response of pupils with disability or diversity conditions arising from their personal and social conditions, have enabled them to gain tenure throughout the various stages of education. Educational institutions have been progressively adapting and responding to the educational needs of students who start university, and this fact highlights the lack of inclusive culture in university institutions. The lack of training of university teachers in the educational response to the needs of students with disabilities is evidenced by the high dropout rates of this group and in successive complaints of teachers who do not have the skills or tools to cope with this situation successfully. The review of a set of 75 programs developed by different Spanish universities to meet the needs of these students shows an insufficient institutional and administrative response while reflecting the lack of unity of jointly developed criteria.
Scenario-Based Instruction: The Case of Foreign Language Training at Multidisciplinary University
Authors: Almazova Nadezhda , Rubtsova Anna , Kats Nora , Eremin Yuri , Smolskaia Natalia
Published: May 2021

Strong communication skills, in varied professional settings, have become an absolute necessity for young professionals. Therefore, university educators are challenged to provide novice specialists with the effective foreign language training that could bring the real professional world into the classroom. This study suggests an innovative method for teaching communication skills to students, through the use of real-life scenarios, drawn from the professional context. The core objective of the research was to define whether the scenario-based instruction could effectively enhance the development of professional communication skills of students in the context of university foreign language training. The data were collected through active observation and critical incidents technique, analyzed and summarized by means of descriptive statistics. The results of the study indicate the efficacy of scenario-based communication training in higher education. However, scenario-based instruction requires careful assessment of learners’ needs and expectations, thoughtful selection and design of teaching materials, and the development of an active learning environment.
The Strategy of Active Grid Frequency Support for Virtual Synchronous Generator
Authors: Yang Lingfang , Ma Junpeng , Wang Shunliang , Liu Tianqi , Wu Zihao , Wang Ruogu , Tang Lutian
Published: May 2021

Virtual synchronous generator (VSG) control is a promising control approach for voltage source converters as an interface between new energy sources and the power grid. VSG is a grid-friendly control scheme, which can imitate the mechanical inertia of the synchronous generator (SG) and the power droop characteristics. Yet, the droop characteristics imitation of SG induces the frequency variation of the grid-connected inverter along with the droop characteristic curve, which will deteriorate the performance of the grid frequency support during the transient process. In this paper, a control scheme, which shapes the droop curve during the disturbance, is proposed for active grid frequency support. First, a load disturbance extraction strategy with a high-pass filter is applied in the proposed method, and the disturbance component is effectively extracted to compensate for the frequency reference variation in traditional VSG control. The grid frequency is actively supported by shaping the droop curve of active power to the frequency of VSG during the disturbance. Afterward, H∞ and H2 norms are used as the objective function to quantify the control performance of the proposed method, and the particle swarm optimization (PSO) algorithm is applied to optimize the control parameters of the proposed method. With a well-optimized high-pass filter, the active support performance is further improved. Finally, the simulation results and hardware in the loop (HIL) tests verify the effectiveness of the proposed method.
Hybrid Cross Coupled Differential Pair and Colpitts Quadrature Digitally Controlled Oscillator Architecture
Authors: Butryn Igor , Siwiec Krzysztof , Pleskacz Witold Adam
Published: May 2021

Growing importance of wireless communication systems forces reduction of power consumption of the designed integrated circuits. The paper focuses on minimization of power consumption in a digitally controlled oscillator (DCO) that can be employed as oscillator in GPS/Galileo receiver. The new hybrid architecture of DCO combines good phase noise performance of a Colpitts oscillator and relaxed startup conditions of a cross-coupled differential pair oscillator. The proposed new DCO generates a quadrature signal in a current reused frequency divider. Such solution allows of the dissipated power to be reduced. The DCO has been implemented in 110 nm CMOS technology. It generates output signal in frequency range from 1.52 GHz to 1.6 GHz and consumes 1.1 mW from 1.5 V supply voltage. The measured phase noise equals −116 dBc/Hz at 1 MHz offset from 1.575 GHz output signal.
Routing Algorithm Based on User Adaptive Data Transmission Scheme in Opportunistic Social Networks
Authors: Lu Yu , Chang Liu , Luo Jingwen , Wu Jia
Published: May 2021

With the rapid popularization of 5G communication and internet of things technologies, the amount of information has increased significantly in opportunistic social networks, and the types of messages have become more and more complex. More and more mobile devices join the network as nodes, making the network scale increase sharply, and the tremendous amount of datatransmission brings a more significant burden to the network. Traditional opportunistic social network routing algorithms lack effective message copy management and relay node selection methods, which will cause problems such as high network delay and insufficient cache space. Thus, we propose an opportunistic social network routing algorithm based on user-adaptive data transmission. The algorithm will combine the similarity factor, communication factor, and transmission factor of the nodes in the opportunistic social network and use information entropy theory to adaptively assign the weights of decision feature attributes in response to network changes. Also, edge nodes are effectively used, and the nodes are divided into multiple communities to reconstruct the community structure. The simulation results show that the algorithm demonstrates good performance in improving the information transmission’s success rate, reducing network delay, and caching overhead.
Virtual Router Design and Modeling for Future Networks with QoS Guarantees
Authors: Beshley Mykola , Kryvinska Natalia , Beshley Halyna , Yaremko Oleg , Pyrih Julia
Published: May 2021

A virtual router model with a static and dynamic resource reconfiguration for future internet networking was developed. This technique allows us to create efficient virtual devices with optimal parameters (queue length, queue overflow management discipline, number of serving devices, mode of serving devices) to ensure the required level of quality of service (QoS). An analytical model of a network device with virtual routers is proposed. By means of the mentioned mathematical representation, it is possible to determine the main parameters of the virtual queue system, which are based on the first in, first out (FIFO) algorithm, in order to analyze the efficiency of network resources utilization, as well as to determine the parameters of QoS flows, for a given intensity of packets arrival at the input interface of the network element. In order to research the guaranteed level of QoS in future telecommunications networks, a simulation model of a packet router with resource virtualization was developed. This model will allow designers to choose the optimal parameters of network equipment for the organization of virtual routers, which, in contrast to the existing principle of service, will provide the necessary quality of service provision to end users in the future network. It is shown that the use of standard static network device virtualization technology is not able to fully provide a guaranteed level of QoS to all present flows in the network by the criterion of minimum delay. An approach for dynamic reconfiguration of network device resources for virtual routers has been proposed, which allows more flexible resource management at certain points in time depending on the input load. Based on the results of the study, it is shown that the dynamic virtualization of the network device provides a guaranteed level of QoS for all transmitted flows. Thus, the obtained results confirm the feasibility of using dynamic reconfiguration of network device resources to improve the quality of service for end users.
The Persistence of Glyphosate in Vegetation One Year after Application
Authors: Edge Christopher B. , Brown Marika I. , Heartz Shane , Thompson Dean , Ritter Len , Ramadoss Madhi
Published: May 2021

Glyphosate-based herbicides are the most widely used herbicides in the world, including in Canadian forestry. In general, glyphosate-based herbicides are considered relatively non-toxic to wildlife species due, in part, to rapid breakdown of the chemical in the environment. However, recent work has shown that glyphosate can persist for at least one year after application at low concentrations leading to concern over the persistence of trace levels in the environment. Using two independent studies we characterize the short- (18 days) and long-term (1 year) persistence of glyphosate in vegetation which are commonly, but differentially, browsed by WhiteiTailed Deer (Odocoileus virginianus), Moose (Alces alces), and Black Bear (Ursus americanus), or used as traditional medicines by Indigenous people and compare the residues to exposure thresholds. In the short-term study, glyphosate concentrations within the application block exceeded the general and maximum residue level (MRL) for fresh fruit set by Health Canada (0.1 ppm) for up to 18 days after application. In the long-term study, glyphosate concentrations were above the MRL one week after application and below the MRL one month and one year after application. Under the assumptions that all vegetation contained glyphosate at the highest observed concentration, animals only consume vegetation from herbicide treated areas, and animals consume the physiological maximum level of vegetation daily, Moose, White-Tailed Deer, and Black Bears could exceed the Acceptable Daily Intake for glyphosate (0.3 mg/kg/day) for up to 18 days after application. Subsequently, given dissipation of residues in vegetative matrices as observed in this study, we consider it highly unlikely that the species considered herein could consume enough vegetation throughout their lives to pose a risk to their health. Overall, our two independent studies demonstrate that trace levels of glyphosate persist in vegetation for up to one year after application, however, observed concentrations are unlikely to pose risk to wildlife. We caution that operational practices as typically imposed in Canadian forestry are very important and effective in minimizing risk.
Decline in Aboveground Biomass Due to Fragmentation in Subtropical Forests of China
Authors: Shen Chunyu , Shi Nannan , Fu Shenglei , Ye Wanhui , Ma Lei , Guan Dongsheng
Published: May 2021

Fragmentation has long been considered the primary cause for ecosystem degradation and biodiversity loss worldwide. Forest fragmentation affects ecosystem functioning and biodiversity in multiple ways. Here, we ask how forest fragmentation influences aboveground biomass storage (AGB) in sub-tropical forests in China. We established 207 20 m × 20 m plots within 69 forest fragments of varying size. Forest fragmentation process simulation was carried out via repeated quadrat sampling using different sized quadrats in two non-fragmented stands. AGB was estimated and compared across forest fragments and quadrats with different sizes within two non-fragmented stands. Our results indicate that AGB is significantly lower in forest fragments than in quadrats within two non-fragmented forests. In addition, species richness and abundance were lower in fragmented stands, respectively. In fragmented forests, the average diameter at breast height (DBH) increased with decreasing patch size, while declined for non-fragmented plots. Species richness, abundance, and mean DBH have strongly positive effects on AGB. This was the case both in forest fragments and quadrats within two non-fragmented forests. Forest fragmentation leads to lower richness, lower abundance, and higher mean DBH in forest fragments than in the two non-fragmented forests. Our results suggest that forest fragmentation increases edge habitats, which drastically decreases forests aboveground biomass storage. These results show that land degradation not only reduces the area of forests, but also reduces the aboveground biomass carbon density of forests.
Thermo-Environmental Performance of Four Different Shapes of Solar Greenhouse Dryer with Free Convection Operating Principle and No Load on Product
Authors: Villagran Edwin , Henao-Rojas Juan Camilo , Franco German
Published: May 2021

Solar drying using greenhouse dryers is a viable method from the technical, economic, and environmental perspectives, allowing the drying of agricultural products for conservation purposes in different regions of the world. In Colombia, the drying of aromatic plants such as mint (Mentha spicata) is usually done directly and in open fields, which exposes the product to contamination and loss of quality. Therefore, the objective of this research was to use a three-dimensional computational fluid dynamics (CFD-3D) model previously successfully validated and implemented in this work to study the performance of air flow patterns, temperature, and humidity inside four greenhouse-type dryers contemplated for a region with hot and humid climatic conditions. The results found allowed us to observe that the spatial distribution of temperature and relative humidity are related to the air flows generated inside each dryer, therefore, there were differences of up to 7.91 °C and 23.81% for the same evaluated scenario. The study also allowed us to conclude that the CFD methodology is an agile and precise tool that allows us to evaluate prototypes that have not been built to real scale, which allows us to generate useful information for decision-making regarding the best prototype to build under a specific climate condition.
Association between the FTO A/T Polymorphism and Elite Athlete Status in Caucasian Swimmers
Authors: Zmijewski Piotr , Leońska-Duniec Agata
Published: May 2021

The FTO A/T polymorphism (rs9939609) has been strongly associated with body mass-related traits in nonathletic populations, but rarely with elite athletic performance. The aim of the study was to investigate the association between the A/T polymorphism and athlete status in elite swimmers. Polish swimmers (n = 196) who competed in national and international competition at short- (SDS; 50–200 m; n = 147) and long-distance events (LDS; ≥400 m; n = 49) were recruited. The control group included 379 unrelated, sedentary young participants. The participants were all Caucasians. Genotyping was carried out using real-time PCR. It was found that the chance of being an elite swimmer was lower in carriers of the AT and AA genotype compared with TT homozygotes (1.5 and 2.0 times, respectively). These findings were confirmed in an allelic association; the A allele was less frequent in the swimmers compared with controls (p = 0.004). However, when SDS were compared against LDS, no significant differences were observed in genotypic and allelic distribution. The results of our experiment suggest that the variation within the FTO gene can affect elite athlete status. It was demonstrated that harboring the T allele may be beneficial for achieving success in a sport such as swimming.
Knowledge, Protective Behaviors and Risk Perception of COVID-19 among Dental Students in India: A Cross-Sectional Analysis
Authors: Batra Kavita , Urankar Yashashri , Batra Ravi , Gomes Aaron F. , S Meru , Kaurani Pragati
Published: May 2021

Objective: This study’s objective was to examine the knowledge, performance in practicing protective behaviors, and risk perception of Coronavirus disease-19 (COVID-19) among dental students of India. Methods: A web-based cross-sectional survey was conducted from 10–30 August 2020, involving 381 dental students that were enrolled at the Uttaranchal Dental and Medical Research Institute in India. A web-based structured questionnaire assessed the COVID-19 related knowledge, protective behaviors, and risk perception performance. The independent-samples-t and analysis of variance tests were used to analyze the differences in knowledge, protective behaviors, and perception across the groups. Results: Of the dental students surveyed, 83% had adequate knowledge of COVID-19, and nearly 80% followed appropriate practices regarding COVID-19. The COVID-19 related risk perception was higher among females as compared to males. COVID-19 related knowledge was significantly correlated with preventive behaviors (r = 0.18; p < 0·01) and risk perception (r = 0.10; p < 0.05). We found a high score of COVID-19 related knowledge and precautionary behaviors and moderate risk perception among students. Conclusions: Knowledge and protective behaviors towards infectious diseases, such as COVID-19, have clinical applications in developing educational and formal training programs to promote adherence to the infection control practices among dental students. Clinical significance: The findings of this study will inform policymakers to emphasize on effective risk communication. Dental institutions can incorporate infection control modules in the current curriculum, thereby making future dental professionals capable of performing effective infection control management in the clinical settings. This is critical in improving their knowledge of infection control practices to minimize the risk of nosocomial infections.