bluuebunny/crossref_metadata_2025 huggingface dataset:
Chelate Complexes of 3d Transition Metal Ions – A Challenge for Electronic-Structure Methods?
Authors: Hehn Lukas , Deglmann Peter , Kühn Michael
Published: December 2023

Different electronic-structure methods were assessed for their ability to predict two important properties of the industrially relevant chelating agent nitrilotriacetic acid (NTA): its selectivity with respect to six different first-row transition metal ions and the spin-state energetics of its complex with Fe(III). The investigated methods encompassed density functional theory (DFT), the random phase approximation (RPA), coupled cluster (CC) theory, the auxiliary-field quantum Monte-Carlo (AFQMC) method, as well as the complete active space self-consistent field (CASSCF) method and the respective on-top methods second-order N-electron valence state perturbation theory (NEVPT2) and multiconfiguration pair-density functional theory (MC-PDFT). Different strategies for selecting active spaces were explored and the density matrix renormalization group (DMRG) approach was used to solve the largest active spaces. Despite somewhat ambiguous multi-reference diagnostics, most methods gave relatively good agreement with experimental data for the chemical reactions connected to the selectivity, which only involved transition-metal complexes in their high-spin state. CC methods yielded the highest accuracy followed by range-separated DFT and AFQMC. We discussed in detail that even higher accuracies can be obtained with NEVPT2, under the prerequisite that consistent active spaces along the entire chemical reaction can be selected, which was not the case for reactions involving Fe(III). A bigger challenge for electronic-structure methods was the prediction of the spin-state energetics, which additionally involved lower spin states that exhibited larger multi-reference diagnostics. Conceptually different, typically accurate methods ranging from CC theory via DMRG-NEVPT2 in combination with large active spaces to AFQMC agreed well that the high-spin state is energetically significantly favored over the other spin states. This was in contrast to most DFT functionals and RPA which yielded a smaller stabilization and some common DFT functionals and MC-PDFT even predicting the low-spin state to be energetically most favorable.
Elucidating the lithiation process in Fe3–δO4 nanoparticles by correlating magnetic and structural properties
Authors: Ulusoy Seda , Feygenson Mikhail , Thersleff Thomas , Uusimäki Toni , Valvo Mario , Gomez Roca Alejandro , Nogues Josep , Svedlindh Peter , Salazar-Alvarez German
Published: December 2023

Due to their high potential energy storage magnetite (Fe3O4) nanoparticles have become appealing for anode materials in lithium-ion batteries. However, the details of the lithiation process are still not completely understood. Here, we investigate chem- ical lithiation in 70 nm cubic shaped magnetite nanoparticles with varying degree of lithiation x = 0, 0.5, 1, 1.5. The induced changes on the structural and magnetic properties were investigated by using X-ray techniques along with electron microscopy and magnetic measurements. The results indicate that a structural transformation from spinel to rock salt phase occurs above a critical limit for the lithium concentra- tion (xc), which is determined to be between 0.5< xc≤1 for Fe3–δO4. Magnetization measurements clearly shows the formation of the LiFeO2 phase with its distinct anti- ferromagnetic behaviour below its Need temperature. Upon lithiation, magnetization measurements reveal exchange bias in the hysteresis loops with an asymmetry, which can be attributed to the formation of mosaic-like LiFeO2 subdomains. The combined characterization techniques enabled us to unambiguously identify the phases and their distribution involved in the lithiation process. Correlating magnetic and structural properties opens the path to increase the understanding of the processes involved in a variety of non-magnetic applications of magnetic materials.
Recent Advances in Sustainable Catalysts and Catalysis with Non-noble Metals
Authors: Ganesan Magesh , Krogman Jeremy , Konovalova Tatyana , Lotti Diaz Leilani , Hsu Chia-Wei
Published: December 2023

This report displays bibliometric data analysis pertaining to the recent development of non-noble metal catalysts and their application in catalysis with a focus on sustainability. Using the CAS Content Collection, we discuss the annual publication trends from 2012 to 2022 in four subfields: electrocatalysts, homogeneous catalysts, photocatalysts, and biocatalysts. Herein we reveal the top concepts that appeared associated with non-noble metal catalyst publications, along with the top substances and categorized concepts in each of the four sub-field. The global participation data is broken down and discussed for the topic of interest.
Stability of the protactinium(V) mono-oxo cation probed by first-principle calculations
Authors: Shaaban Tamara , Réal Florent , Maurice Rémi , Vallet Valérie
Published: December 2023

This study explores the distinctive behavior of Protactinium (Z = 91) within the actinide series. In contrast to neighboring elements like uranium or plutonium, Protactinium in the pentavalent state diverges by not forming the typical dioxo pro- tactinyl moiety PaO2^{+}. Instead, it manifests as a monooxo PaO^{3+} cation. Employing first-principle calculations with implicit and explicit solvation, we investigate two sto- ichiometrically equivalent neutral complexes: PaO(OH)2(X)(H2O) and Pa(OH)4(X), where X represents various monodentate and bidentate ligands. Calculating the Gibbs’ free energy for the reaction PaO(OH)2(X)(H2O) −−→ Pa(OH)4(X), we find that the PaO(OH)2(X)(H2O) complex is stabilized with Cl– , Br– , I– , NCS– , NO3 – , and SO42– ligands, while it is not favored with OH–, F–, and C2O42– ligands. Quantum Theory of Atoms in Molecules (QTAIM) and Natural Bond Orbital (NBO) methods reveal the Pa mono-oxo bond as a triple bond, with significant contributions from the 5f and 6d shells. Covalency of the Pa mono-oxo bond increases with certain ligands, such as Cl–, Br–, I–, NCS–, and NO3–. These findings elucidate Protactinium’s unique chemical 1 attributes and provide insights into the conditions supporting the stability of relevant complexes.
Study on physicochemical and sensory characteristics of peanut yoghurt
Authors: Lubna M.H. , Rifda N. , Erminawati M. , Triana S. , Ibrahim A.I.
Published: December 2023

This present investigation aimed to study the influence of incubation temperature and
skimmed milk ratio on the physicochemical properties, microbiological and sensory
characteristics of peanut yoghurt. The methods of the Association of Official Analytical
Chemistry International (AOAC) and the Indonesian National Standard (SNI) were used
to analyse the physicochemical properties of peanut yoghurt. Analysis of one variance
(ANOVA) was performed to evaluate the difference between the data via SPSS Version
17 and Microsoft Excel 2016. Yoghurt was made by using different incubation
temperatures (37 and 45°C), incubation times (18 and 24 hrs) and skimmed milk ratios (3
and 5%). The results showed no significant differences (P>0.05) between the
physicochemical of peanut yoghurt samples in colour, culture cells and total solids, whilst
there were significant differences (P≤0.05) between each peanut yoghurt sample in pH
(3.89, 41.17, 33.76, 4.29, 3.88, 3.86, 3.62, and 4.20) and viscosity (5.40, 5.40, 5.50, 5.10,
4.80, 4.10, 4.90, and 4.50). General results from this present study established that
producing yoghurt from peanut milk by incubation temperature at 37ᵒC for 18 hrs and
skimmed milk ratio of 3%, increased the physicochemical and sensory properties of
peanut yoghurt based on reducing the aroma of peanut.
A Study on the Problems Faced by Graduates’Employability and Strategies for Improvement
Authors: Guo Mengke
Published: December 2023

The study of employability in modern societies is important because it concerns individuals, the education system, employers, and society. This article analyzes the employability of graduates from the perspective of soft skills, hard skills, interpersonal skills, creativity and innovation, and leadership skills. Graduates face numerous issues and challenges in terms of employability. Therefore, schools and educational institutions, governments, and enterprises need to work together to enhance their competitiveness and chances of success in the workplace.
Gramática de la lengua española: clases de palabras
Authors: Mungía Zatarain Irma
Published: December 2023

Esta gramática no es un texto más sobre el estudio morfosintáctico del español, tampoco es una obra que se oriente hacia la discusión puramente teórica de temas gramaticales; es ante todo, un libro que responde –de manera clara, original, sin rodeos, con abundantes ejemplos y con un enfoque contemporáneo– a la necesidad que tienen muchos lectores de conocer la estructura del español, de aclarar dudas sobre su empleo, de atravesar la frontera que los ha mantenido fuera del conocimiento consciente de su lenguaje, para convertirse en hablantes dueños de su lengua. En este libro, el lector podrá conocer las nuevas descripciones y clasificaciones de las palabras, así como explicaciones acerca del funcionamiento de las diferentes categorías gramaticales que se emplean en español, incluyendo sus propiedades morfológicas y sintácticas. El libro puede utilizarse como texto de autoinstrucción debido a que contiene respuestas a los ejercicios al final del volumen, lo que le permite al lector comparar y corregir sus prácticas. Además, puede usarse como libro de consulta por el índice analítico que la autora atinadamente ha conformado en beneficio del lector. Así pues, el presente libro es un material de consulta con una intención claramente didáctica al hacer inteligibles nociones y procesos gramaticales abstractos sumamente complejos.
СУЧАСНА МІЛІТАРНА ПСИХОЛОГІЯ : РІЗНОВЕКТОРНІСТЬ ДОСЛІДЖЕНЬ
Authors: Гошовська Дарія , Гошовський Ярослав
Published: December 2023

Мета. У статті здійснено узагальнений огляд поліваріантності висвітлення особливостей мілітарної психології, зокрема типові тематичні вектори й ракурси вивчення мілітарно-психологічної проблематики.Методи. Для реалізації дослідницької мети нами було задіяно методи науково-теоретичного вивчення: аналіз, синтез, абстрагування, узагальнення, що дало змогу встановити специфіку сучасних різновекторних досліджень у галузі мілітарної психології. Результати. Огляд науково-психологічної джерелознавчої бази з проблем мілітарної психології дав підстави констатувати широку тематичну розімкнутість досліджень. Активними науковими студіями охоплено розлогий спектр мілітарно-психологічної тематики : від особливостей гібридної та реальної війни до специфіки бойового стресу, травми, психічного здоров’я, психореабілітації тощо. Здійснено аналітичний огляд типових тематичних домінант, які висвітлюються у сучасній мілітарній психології.Висновки. Мілітарна психологія набуває все більшої актуальності насамперед у зв’язку з необхідністю психологічного обгрунтування і пояснення зростаючої геополітичної настабільності у світі і збільшення кількості воєнних конфліктів. В Україні збільшення кількості науково-психологічних досліджень відбувається насамперед через російсько-українську війну. Психологічне вивчення людини мілітарної постає одним з домінуючих векторів наукового пошуку. Сучасні науково-психологічні дослідження в царині мілітарної психології відзначаються різновекторністю тематики: від психогенези мілітарної ідентичності до організованої допомоги військових під час пандемії COVID-19, від проблем надання психологічної допомоги учасникам бойових дій до особливостей вживання алкоголю молоддю, яка йде на службу в армію, від негативних наслідків для військових, зумовлених депривацією сну, до психології віртуальної кіберзлочинності.
Tourism suitability and community perception on development of the Cengklik Reservoir tourism, Boyolali Regency
Authors: Firdaus Nur Salsabila , Purwanti Frida , Ayuningrum Diah , Sulardiono Bambang
Published: December 2023

Cengklik Reservoir is one of the water and waterfront tourism destinations in the Boyolali Regency which has an area of 327,44 ha. The condition of Cengklik Reservoir is currently undergoing revitalization and tourism development. The purpose of this study was to analyse the suitability of reservoir waters as a tourist attraction based on the Tourism Suitability Index, to determine the perceptions of tourists’ potential in the reservoir, and community perceptions of tourism development in the reservoir. The research was conducted in March - April 2023. The research methods used a case study with quantitative analysis to calculate the value of the Tourism Suitability Index and qualitative analysis to determine the perception of tourism potential from 30 tourist respondents and tourism development from 30 community respondents. Results of the TSI calculation of the Cengklik Reservoir for boat tours amounted to 2.40 (suitable) and fishing amounted to 3.00 (very suitable). The tourists’ perception of the Cengklik Reservoir as well as the community’s perception of tourism development were rated positively. These results indicate that the Cengklik Reservoir is suitable for tourism which is supported by the community’s perception of the tourist developmentKeywords: Cengklik Reservoir; Tourism Development; Tourism Potential; Tourism Suitability Index.
Cyber-geography of languages
Authors: Pimienta Daniel , Müller de Oliveira Gilvan
Published: December 2023

Part 1 of this study explains the methodology, sources, biases, and results of the recent study on the presence on the Internet of the 330 languages with more than one million L1 speakers, and the reality of the place of English on the Internet. This part analyzes the results in terms of cyber-geography for the other languages. It appears that the languages of Europe, especially English, are still dominating the Internet but that the languages of Asia and the Arabic world are in a strong progression and will take the lead, in terms of connected speakers. The languages of Africa are suffering from the difficulty of many African countries to overcome the digital divide: however, demographic long-term future clearly will favor in the long run African languages and the European languages with a notable presence in Africa (by order of importance: English, French and Portuguese).
Is ethics evaporating in the cyber era?
Authors: Ronchi Alfredo M.
Published: December 2023

This paper provides a brief history of evolution of digital technologies and its impact on human societies. Further, it emphasizes on cyber ethical issues that include the pervasive use of cyber devices and technologies, including the evolving use of intelligent algorithms and machine learning to manage companies and support governments. This paper also discusses the protection of freedom of expression and mainstream information potential biases and information oversupply. It also focuses on the relevant role of “platforms” and how these are being monopolized by some countries. Finally, this paper summarizes the key aspects of The UNESCO IFAP Code of Ethics for the Information Society and related follow-ups.
Emerging Technologies from a psychological perspective
Authors: Willem de Graaf Jan
Published: December 2023

Technology has always been a very distinctive feature of human existence. Technology is to humans what nature is to other organisms: our host. Man is nature, but through technology – humans came to stand against nature and its biodiversity; technology is now a global enterprise, advancing on a scale and pace that has never been seen before. The paper argues that this poses a threat not only to the planet and biodiversity but above all to humans themselves. A psychological perspective is chosen, that of the thinking and feeling person, which is contrasted with emerging (smart) technologies. It is concluded that man is not a rational “machine”, but a small-scale storyteller, a provider of meaning, especially emotionally involved with each other. Systems and standardization stand in the way. But as globalized humanity faces the dangers of diminishing (bio- and cultural) diversity, we need the unifying power of technology to restore balance.
PELATIHAN PETANI KELAPA DALAM MELAKUKAN PENGOLAHAN LIMBAH AIR KELAPA MENJADI KECAP MANIS GUNA PENINGKATAN EKONOMI MASYARAKAT DESA TOARI KABUPATEN KOLAKA
Authors: Handayani Fitrianti , Tojang Djurnarlin , Adelina Fitrah , Bulawan Juniaty Arruan , Adi Qadaruddin Fajri , Saparuddin  , Mustafa Mustafa R , Rahim Abdul , Maretik Maretik , Erfina Erfina
Published: December 2023

Desa Toari adalah desa penghasil kelapa terbesar di Kabupaten Kolaka. Masyarakatnya hanya mengolah kelapa sebagai kopra sementara airnya menjadi limbah sehingga menimbulkan masalah karena aromanya yang kuat setelah dibuang. Olehnya itu, sangat penting dilakukan pelatihan kepada Masyarakat Desa Toari dalam mengolah limbah air kelapa. Salah satu produk yang dihasilkan adalah kecap manis. Kecap manis merupakan salah satu jenis tambahan makanan yang digemari kerena memberikan cita rasa makanan menjadi lebih enak. Tujuan pengabdian ini menciptakan kemandirian masyarakat dalam mengolah air kelapa menjadi produk bernilai ekonomi tinggi serta mendapatkan keterampilan dalam pengolahan air kelapa agar dapat dimanfaatkan oleh masyarakat untuk meningkatkan perekonomian. Metode pengabdian ini dilakukan pada beberapa tahap meliputi tahap observasi, tahap persiapan, tahap pelaksanaan kegiatan, tahap pelatihan dan pendampingan, serta tahap evaluasi. Hasil dari kegiatan ini adalah masyarakat sangat antusias mengikuti pelatihan sehingga produk kecap manis yang dihasilkan sangat baik, rasanya enak dan higienis. Tingkat keterampilan dan pengetahuan masyarakat setelah melakukan kegiatan pelatihan dan pendampingan mengalami peningkatan sebesar 100% serta tercapainya beberapa luaran pengabdian.
The Influence of an Integrated STEM Project-Based Learning toward Science Literacy Abilities Students in Elementary School
Authors: Karimah Fuadatul , Wulandari Fitria
Published: December 2023

The purpose of this research is to prove the influence of an integrated STEM project-based learning toward science literacy abilities students, given the low science literacy skills among elementary school students. A quasi-experimental quantitative approach was used to collect data on literacy abilities, using a test questionnaire as an instrument for data collection. The data was analyzed using independent sample t-tests and paired sample t-tests. The results of the independent sample t-test showed a significance value of 0.00 < 0.05, which means that the null hypothesis (H0) was rejected and the alternative hypothesis (Ha) was accepted. This indicates that students' science literacy abilities were better when they learned using the integrated STEM project-based learning model compared to the conventional model. Furthermore, the results of the paired sample t-test showed a significance value of 0.00 < 0.05, which means that Ha was accepted and H0 was rejected, indicating that the implementation of the integrated STEM project-based learning model can improve students' science literacy abilities. Based on these findings, it can be concluded that the implementation of the integrated STEM project-based learning model is effective in improving students' science literacy abilities.
Elements of Metamorphic Rocks (Marble and Quartzite) of Bukit Cinta Gunung Gajah, Klaten
Authors: Hiryanto  , Sujarwo  , Tristanti  , Santi Fitta Ummaya
Published: December 2023

Rocks such as metamorphic and sedimentary are natural constructions. Rocks in natural construction become elementary materials that form the landscape of the area, including in nature-based tourism objects, Bukit Cinta in Gunung Gajah, Klaten, Central Java. The purpose of this research is to describe the elements of rocks in the place. The study method used is descriptive qualitative method and tends to use analysis. The theoretical basis is used as a basic reference in preparing the study report to match the conditions in the field. In addition, the theoretical basis can also provide an overview of the background of the study as material for discussion. The ability to collect data is an important factor in determining the validation of the study conducted. Data collection in this case is obtained secondarily, namely through documents or literature studies. The results of the study found that there are 3 main supporters for the strong landscape in the tourist ojek of Gunung Gajah love hill. The three are metamorphic rocks observed there are fillic metamorphic relief, marble metamorphic rocks, and quartzite metamorphic rocks; limestone sedimentary rocks. Limestone can be used for building materials, road paving, and house foundations; and Diorte igneous rocks. Diorte igneous rocks can be used as home decoration.
Impact of Learning Basic Science Concepts Using the Ethno-Setsar Approach to Improve Communication Skills of Prospective Teachers
Authors: Jhoni M , Hasbi M. , Winarto Winarto
Published: December 2023

Communication skills really need to be provided to prospective teachers. Success This research aims to analyze the impact of Ethno-SETSaR science learning on prospective teacher communication. The research method used was an experiment with a non-equivalent group design. The sample of this research is 120 prospective teacher students. The data collection technique used is observation. The data analysis technique used is ANOVA. Hypothesis testing is that there are differences in communication skills between the experimental group and the control group. The research results obtained by the science learning program using the E-SETSAR approach can improve communication skills. Eight student communication indicators with scores greater than ≥ 65 for the experimental class. Conduct investigations, prepare investigation reports, discussions and presentations which are learning activities. Learning basic science concepts involves scientific investigation activities to find community problems related to the culture of the surrounding community to be studied from the SETSaR aspect to train communication skills. Therefore, learning is designed to facilitate students to think and convey their ideas.
Implementation of Computer-Based Summative Assessment
Authors: Yulianti Yuli
Published: December 2023

In this current condition, SMK Negeri 1 Tanjungpandan has utilized a paper-based test as the main method of carrying out academic exams and evaluations. Nevertheless, through the rapid development of information and communication technology, various schools and educational institutions have started to switch the evaluation process using computer-based tests as a much more efficient and effective alternative. This also applies to SMKN 1 Tanjungpandan, that expect to implement a computer-based test as the substitute for paper-based tests. This study aims to describe the implementation of computer-based summative assessment at SMK Negeri 1 Tanjungpandan. The subjects in this study were school principals, vice principals for curriculum, the school management team and proctors and technicians in charge of assessment activities. The object of this study is the use of computers based tests in the implementation of summative assessments. This research is a descriptive type using a qualitative approach with the best practice method. The research data were collected by observation and interview methods. Data analysis included data presentation and drawing conclusions. The results of the research conducted shows that the computer-based summative assessment has been running well. This can be seen from the process of preparation, implementation, monitoring, evaluation, and reporting of the assessment results that proceeded smoothly. This is also supported by the readiness of human resources in performing duties as proctors and technicians, as well as adequate infrastructure for the implementation of computer-based summative assessments.
TINJAUAN YURIDIS PERLINDUNGAN HUKUM TERHADAP BADAN HUKUM KOPERASI SIMPAN PINJAM TERHADAP DEBITUR WANPRESTTASI
Authors: Aryani Saraswati Dewi Ni Made , Djumardin H. Djumardin
Published: December 2023

Penelitian ini bertujuan untuk mengetahui faktor-faktor penyebab debitur wanprestasi dan untuk mengetahui dan memahami bentuk perlindungan badan hukum koperasi simpan pinjam serta bentuk penyelesaian yang dilakukan pihak Koperasi Simpan Pinjam Sejahtera apabila debitur wanprestasi. Berdasarkan hasil penelitian ini akhirnya dapat disimpulkan bahwa penyebab debitur wanprestasi terhadap Koperasi Simpan Pinjam Sejahtera yaitu faktor internal, faktor eksternal dan nilai agunan yang tidak sebanding. Bentuk perlindungan hukum koperasi simpan pinjam yaitu melalui Standar Operasional Managemen, Tim Satuan Tugas, dan bentuk perlindungan Koperasi Simpan Pinjam Sejahtera apabila debitur wanprestasi yaitu melalui bentuk perjanjian yang sudah disepakati oleh koperasi dan anggota melalui barang atau jaminan debitur yang diberikan kepada koperasi. Bentuk penyelesaiannya yaitu melalui dua cara yaitu non litigasi dan litigasi, yaitu secara musyawarah atau kekeluargaan dan yang terakhir jalur pidana atau hukum.
IMPLEMENTASI PERLINDUNGAN PEKERJA MIGRAN INDONESIA (PMI) PASCA PENEMPATAN DI LUAR NEGERI MENURUT PP NO. 59 TAHUN 2021
Authors: Maturrahmah Muttami , Suryani Hamzah Any
Published: December 2023

Penelitian ini bertujuan untuk mengetahui Implementasi Perlindungan Pekerja Migran Indonesia Pasca Penempatan di Luar Negeri menurut PP No.59 Tahun 2021 di Kabupaten Lombok Tengah, yang membahas tentang bagaimana pengaturan Pekerja Migran Indonesia Pasca Penempatan di Luar Negeri menurut PP No.59 Tahun 2021 Tentang Pelaksanaan Perlindungan Pekerja Migran Indonesia. Serta faktor apa saja yang menjadi hambatan atau kendala perlindungan pasca penempatan buruh Migran Indonesia di kabupaten Lombok Tengah. Jenis penelitian yang digunakan adalah penelitian hukum Normatif–Empiris. Berdasarkan hasil penelitian di ketahui bahwa Pelaksanaan Perlindungan Pekerja Migran Indonesia pasca penempatan menurut Peraturan Pemerintah Nomor 59 Tahun 2021 Tentang Pelaksanaan Perlindungan Pekerja Migran Indonesia telah dilaksanakan secara maksimal sesuai dengan yang diamanatkan oleh Peraturan Pemerintah Nomor 59 Tahun 2021. Adapun faktor yang menjadi hambatan atau kendala dalam pelaksanaan perlindungan pasca penempatan buruh Migran Indonesia yaitu kurangnya sosialisasi dari perangkat yang terkait, status Pekerja Migran Indonesia yang ilegal, dan rendahnya pengetahuan pekerja Migran Indonesia sehingga mereka dapat ditipu oleh pihak lain.
WANPRESTASI PERJANJIAN UTANG PIUTANG
Authors: Rizki Utami Elsa , HS Salim
Published: December 2023

Tujuan penelitian ini adalah untuk mengetahui pertimbangan hakim dan akibat hukum wanprestasi. Jenis penelitian ini adalah hukum normatif bahwa pertimbangan hakim menyatakan Tergugat telah melakukan wanprestasi perjanjian hutang piutang pada surat autentik/tertulis tangan yang tidak dibantah karena Tergugat melalaikan kewajibannya sebagai debitur yang melakukan wanprestasi/cidera janji dengan pertimbangan hukum yang tegas dan jelas serta memenuhi Pasal 332 Rv, dan pokok sengketa mengenai bezitsrecht. Wanprestsi yang terjadi antara pihak Penggugat dan Tergugat proses penyelesaian perkara yang diselesaikan melelui pengadilan yang dimenangkan oleh pihak Penggugat karena pihak Tergugat menyatakan bahwa Tergugat telah melakukan wanprestasi/cidera janji dengan tidak memenuhi prestasi sesuai isi perjanjian yang telah disepakati pada tanggal 5 Mei 2021. Penelitian ini berjudul “Wanprestasi Perjanjian Utang Piutang (Studi Putusan Pengadilan Negeri Mataram Nomor 176/Pdt.G/2021/PN.Mtr)”.
O IMPACTO DO DIAGNÓSTICO DO AUTISMO NA DINÂMICA FAMILIAR: UMA REVISÃO INTEGRATIVA
Authors: Meneses Luci Souza de , Barbosa Lucília Maria da Silva Soares , BARROS BETIJANE SOARES DE
Published: December 2023

O Transtorno do Espectro Autista cada vez mais tem despertado interesse no campo da saúde mental, uma vez que se percebeu a necessidade de compreendê-lo, diagnosticando-o precocemente, a fim de desenvolver intervenções eficazes para melhorar a qualidade de vida das pessoas afetadas. Com isso, o presente artigo se inseriu nesse contexto com o objetivo de evidenciar o impacto do autismo na dinâmica familiar. Para tanto foi adotada uma abordagem exploratória qualitativa, fundamentada em revisão integrativa da literatura. A análise dos dados obtidos resultou na elaboração de duas categorias principais: (1) "Impacto do Diagnóstico do TEA na Família e a Necessidade de Apoio", que examina as mudanças na estrutura familiar e nas relações interpessoais, bem como a demanda por suporte emocional e psicológico; e (2) "Adaptação e Resiliência Familiar Frente ao Diagnóstico do TEA", que explora as estratégias desenvolvidas pelas famílias para enfrentar os desafios e promover o bemestar diante do diagnóstico. Desse modo, este estudo contribui para um entendimento mais profundo acerca do impacto do TEA na dinâmica familiar, ressaltando a importância de abordagens sensíveis e de suporte multidimensional. A atuação do psicólogo emerge como um pilar fundamental para auxiliar as famílias a lidar com os desafios do autismo. Além disso, o delineamento das categorias ressalta a complexidade desse cenário e a necessidade de intervenções que considerem suas múltiplas dimensões. Futuras pesquisas devem continuar explorando esse tema, considerando as diferentes características culturais, etárias e socioeconômicas que permeiam as famílias impactadas pelo TEA.
INTERAÇÃO ENTRE A INTERNET E O METAVERSO
Authors: Silva Anderson Ricardo Barros , Barros Cleidejane Soares de
Published: December 2023

A evolução da internet e o surgimento do mundo virtual representam um marco na história da tecnologia e da sociedade. O tema do presente trabalho é “Interação entre a internet e o Metaverso”. Além de livros e sites jornalísticos, a pesquisa investigou publicações científicas disponíveis nos sites Scielo e Science Direct, no período de 2012 a 2023. O objetivo geral deste estudo é avaliar as principais características da internet contemporânea que estão impulsionando a interconexão com o Metaverso. Foi selecionado para análise de artigos científicos que abordam a relação entre a Internet e o Metaverso, excluindo-se aqueles que não tratam do assunto de forma direta. Assim, conclui-se que o Metaverso tem potencial importante na vida das pessoas, e com o avanço tecnológico será mais acessível e realista, podendo, inclusive, evoluir para o mundo virtual 3D.
Environmental Sustainability at Destination Level: The Role of Tourist Citizenship Behavior
Authors: Sancho-esper Franco , Rodriguez-sanchez Carla , Torres-moraga Eduardo
Published: December 2023

Tourist citizenship behavior (TCB) has become a key part of tourist destination management. This study explores how TCB can help tourist destination sustainability. A model is proposed to analyze the relationship between TCB and tourist environmentally responsible behavior. The study also examines which factors are part of this process. Specifically, the influence of the perceived sustainability of a destination on TCB is analyzed, with mediation by destination identification (DI) and perceived value (DPV). According to our findings, perceived sustainability is positively associated with DI and DPV. These two variables are associated with greater TCB. TCB is positively related to environmentally responsible behavior. Accordingly, TCB could encourage tourists to care for the environment by acting as if they were more than just tourists. Implications for destination management organizations are provided to improve destination sustainability and promote both TCB and environmentally responsible behavior among tourists.
TARİKATTA VERASET (“Nazmu’s-Silsile” Adlı Eser Örneğinde)
Authors: MUHITDINOVA Badıa
Published: December 2023

XIX. yüzyılın ikinci yarısı ile XX. yüzyılın başlarında yaşamış bilim adamı Seyidahmed Vesli Semerkandî'nin "Nazmu’s-silsile" adlı eseri, içerik açısından felsefî-teolojik, manevî-eğitimsel ve ahlakî-eğitimsel konuları kapsamaktadır. Bu nedenle onun çalışması zamanımız için büyük önem taşımaktadır. Daha sonraki yıllarda tasavvuf konulu pek çok eserde tasavvuf şeyhlerinin hayatı ve faaliyetlerini konu alan tarihi eserler araştırılıp tahlil edilse de, tasavvuf ilminin gelişmesi, öncesi ve sonrası, dönemlerin birbirine bağlandığı sistemsel şekilde ele alınmadı ve tasavvuf zincirlerinin bütüncül bir çalışması yapılmadı. "Nazmu’s-silsile" adlı eser, bu alanda araştırma yapmak için uygun bir fırsat olarak hizmet edecektir.

Bu makalede, “Nazmu’s-silsile” eserinin yanı sıra başta Maveraünnehir olmak üzere tüm Turan diyarının derin ilmiyle aydınlanmış, yüksek ahlaklı ve yüksek mertebeli, kâmil insanların pirlik müridlik (üstadlık şakirtlik) bağları bağlamında tarikatta veraset gelenekleri hususunda ayrıntılı bilgiler verilmektedir. "Nazmu’s-silsile" eserindeki felsefî-ilahî, manevî-eğitimsel, ahlakî-eğitimsel konular da analiz edilmektedir. Ayrıca Nakşibendilik silsilesinin temsilcilerinin hayatlarının anlatılmasının yanı sıra, onlar hakkında tarihî bilgiler, tasavvuftaki payları ve tarikat şubeleri anlatılmaktadır.
GAP VA SO‘Z KENGAYTIRUVCHILARIDA MARKAZ QURSHOVLILIK MUNOSABATI
Authors: KURBANOVA Mukhabbat , SULAYMANOVA Dilobar
Published: December 2023

Ushbu maqolada gapning semantik-struktur munosabatida so‘zlar bog‘lashuvi, ularning amaliy va noamaliy mavqeyi masalasi, gapning qurilish ashyosi bo‘lgan so‘zning gap qurilishiga bevosita yoki bilvosita ta’siri, ya’ni markaz sifatida o‘z atrofida ma’lum bir leksemalarni birlashtirishi yoki kengaytiruvchi sifatida qurshov vazifasini bajarish masalasi tahlilga tortiladi. Sintaksisning fundamental muammolaridan biri pog‘onali sintaktik tahlil, sintaktik aloqalar tushunchalari, gap bo‘laklarining iyerarxiyasi, markaz qurshovlilik munosabatining sintaktik sathda namoyon bo‘lishi, sodda gaplarda markaz va qurshov munosabatining voqelanishi, gapning LSQida so‘zlar bog‘lashuvini tahlil qilish orqali aktantlarning gap qurilish sathidagi vaziyatini aniqlashtirish, gapning til bosqichidagi lisoniy gap bo‘laklari (takibiy qismlari) o‘rtasidagi semantik, grammatik bog‘lanishni oydinlashtirish gap va so‘z kengaytiruvchisining iyerxiyadagi maqomi masalasi yoritiladi.
Lessons Learned From Covid-19 Pandemia: Pregnancy Anxiety Level Increases During A Life Threatening Period
Authors: KÖLE Emre , AKSOY Lale , GÖRGÜLÜ Gökşen , DEMİR Hakan , ÇAKIR KÖLE Merve , ASLAN Erdoğan
Published: December 2023

Aim: We aimed to highlight the psychological effects of the disease in the pandemic process along with the epidemiological data in pregnant women with COVID 19 infection, and the effects of increased anxiety in pandemic on pregnancy outcomes.

Material and methods: This study was performed in 100 women of 15 to 49 years of reproductive age who applied to the Gynecology and Obstetrics Outpatient Clinic, Pandemic Outpatient Clinic and the Pregnant Outpatient Clinic. Fourty-six pregnant women with positive COVID 19 PCR test were compared with negative COVID 19 PCR test as control group. Patients were administered a questionnaire and Beck Anxiety Inventory.

Results: An evaluation using the Beck Anxiety Scale revealed that anxiety levels were significantly higher in the COVID-19 positive pregnant group compared to the COVID-19 negative pregnant group (p=0.001). When comparing the groups in terms of becoming pregnant and giving birth during the pandemic, it was found that "severe anxiety" significantly increased in the COVID-19 negative pregnant group (p=0.032)

Conclusion: We found that being COVID-19 positive, based on the Beck Anxiety Inventory, significantly increased the anxiety levels during pregnancy when compared to negative groups.
Custom-made anterior cruciate ligament
Authors: Y. EL QADIRI  , M. FARGOUCH  , Y. ELANDALOUSSI  , AR. HADDOUN  , O. EL ANDAOUI  , D. BENNOUNA  , M. FADILI
Published: December 2023

Rupture of the anterior cruciate ligament (ACL) of the knee is one of the most common ligament injuries. It is most common in young, athletic patients, and its short- and long-term repercussions result in functional disability. The increasing development of ligamentoplasty using the crow's foot tendons: the medial rectus and the semitendinosus (DIDT), compared with ligamentoplasty using the patellar tendon, considered to be the "Gold Standard", and the quadricipital tendon, has led the various surgical and rehabilitation teams to compare these three techniques. Our work is a retrospective study of 66 patients with chronic knee instability secondary to ACL rupture. 33 patients underwent ligamentoplasty using a semitendinosus medial rectus graft (DIDT), 21 patients were treated with a patellar tendon graft using the Kenneth-Jones (KJ) technique and 12 patients were treated using the quadricipital tendon technique.Rehabilitation was started at 24 hours post-operatively, with support allowed, according to a well-coded protocol. Comparing these 3 techniques, patients in the DIDT and TQ group showed a less marked pain profile than those in the "patellar tendon" group. In all three groups, there was a significant improvement in the postoperative Lysholm and Tegner scores compared with the preoperative scores; this improvement was significantly greater in the DIDT group than in the KJ group (94.6 vs. 86.2). The three techniques (QT, KJ and DIDT) gave comparable long-term results, although the early postoperative effects, which differed from one technique to another, could be an interesting criterion in choosing the type of ligamentoplasty. In summary, in sensory terms QT > DIDT > KJ, in aesthetic terms QT= DIDT > KJ, and in functional terms QT= DIDT = KJ. Measurement of preoperative and postoperative laximetry using a laximeter (KT-1000) represents an objective assessment of the outcome of surgery, which is necessary to demonstrate the superiority of one technique over another.
ORIENTASI BRANDING DAN PEMASARAN ONLINE BERSAMA PKK, KARANGTARUNA, DAN UMKM DESA SIDOMULYO KEC. MANTUP KAB. LAMONGAN
Authors: Rizqi Akhmad Wasiur , Rahim Andi Rahmad , Sukaris Sukaris , Widiharti Widiharti
Published: December 2023

Desa Sidomulyo adalah Desa yang terletak di wilayah Kabupaten Lamongan tepatnya di Kecamatan Mantup. Lokasi Desa Sidomulyo di sebelah utara berbatasan dengan Desa Mojosari Kecamatan Mantup. Di sebelah selatan berbatasan dengan Desa Jombang Delik Kecamatan Balongpanggang, di sebelah timur berbatasan dengan Desa Rumpuk Kecamatan Mantup, dan di sebelah barat berbatasan dengan Desa Kedungsoko Kecamatan Mantup. Desa Sidomulyo terdiri dari enam dusun yang tersebar yaitu; Dusun Ngaglik, Dusun Grogol, Dusun Sembung, Dusun Semampir, Dusun Sugihwaras, Dusun Sidomoro. Dusun Ngaglik merupakan Dusun yang menjadi sentra Desa yang dijadikan pusat pendidikan dan kegiatan Desa dikarenakan Balai Desa terletak di Ngaglik. Salah satu hasil pertanian Desa Sidomulyo adalah pisang yang saat ini semakin luas ladang yang di tanam pohon pisang yang tersebar di Dusun Ngaglik dan Dusun Semampir. Selain itu rempah – rempah di Desa Sidomulyo sangat menghasilkan tumbuhan yang baik, dengan ini ada salah satu warga yang memanfaatkan tumbuhan tersebut yaitu menjadi Jamu Khas Sidomulyo. Dengan banyaknya UMKM di Sidomulyo Tim KKN Universitas Muhammadiyah Gresik mau mengadakan progam yang relevan dengan keadaan wilayah. Progam Sosialisasi Branding dan Pemasaran Online menurut Tim KKN Kelompok delapan sangat tepat untuk dilaksanakan agar tumbuhnya rasa untuk memperbaiki UMKM menjadi lebih baik lagi sesuai dengan perkembangan zaman dan teknologi. Kegiatan ini melibatkan BUMDES, PKK, Karangtaruna, Pelaku UMKM Desa Sidomulyo.
PENINGKATAN KOMPETENSI PAGUYUBAN KELOMPOK SADAR WISATA (POKDARWIS) MELALUI METODE DESIGN THINKING UNTUK KESEJAHTERAAN BERBASIS WISATA DI KABUPATEN GRESIK
Authors: Sukaris Sukaris , Suwardana Hendra , Anugerah Indra Gita , Sukaris Sukaris
Published: December 2023

Saat ini keberlanjutan dalam pengembangan pariwisata berbasis desa menjadi sangat penting, sehingga mampu menjadikan desa wisata  baik dari segi daya tarik juga dari dampak positif ekonomi, lingkungan dan dampak sosial bagi masyarakat. Tujuan dalam kegiatan pengabdian ini adalah menyelesaikan permasalahan  yang terjadi pada pengelola desa wisata mitra adalah  pengetahuan kewirausahan para pengelola masih minim sehingga belum percaya diri dalam mengembangkan potensi wisata desanya, pemasaran masih konvensional dari mulut kemulut, kemampuan berinovasi warga masih rendah, dan pendapatan warga berbasis kewirausahaan masih rendah. Metode penyelesaian masalah adalah dengan metode pelatihan perbaikan pada proses berinovasi atas potensi wisata desa dengan penyuluhan model inovasi dengan ketrampilan design thinking, pelatihan kewirausahaan berbasis internet of think (digitalisasi pemasaran). Hasil kegiatan pengabdian ini adalah setelah dilakukan tahapan pelatihan dihasilakan bahwa peserta memiliki pengetahuan dan akan bisa menerapkan metode design thingking, dapat menerapkan pengembangan wisata yang berbasis internet of think, dan mampu memvalidasi produk wisata yang layak jual. Demikian juga kompetensi lain dalam melakukan  manajemen usaha sangat baik. Dengan demikian pelatihan-pelatihan metode design thinking yang telah dilaksanakan dapat meningkatkan kompetensi Paguyuban Kelompok Sadar Wisata untuk kesejahteraan berbasis wisata di Kabupaten Gresik
Strategi Guru dalam Meningkatkan Kemampuan Membaca Peserta Didik
Authors: Anisah Rintan Wanti , Rakhman Patra Aghtiar , Rokhmanah Siti
Published: December 2023

Abstrak: Penelitian ini bertujuan untuk mengidentifikasi strategi yang digunakan oleh guru dan dampak strategi tersebut dalam meningkatkan kemampuan membaca peserta didik kelas 1 di SD Negeri Curuglanglang 1. Penelitian ini menggunakan pendekatan kualitatif dan metode deskriptif dengan teknik triangulasi berupa data hasil observasi, wawancara, dan dokumentasi, yang diperkuat dengan hasil literatur. Hasil penelitian menunjukkan bahwa guru menggunakan strategi yang efektif dalam meningkatkan kemampuan membaca peserta didik, termasuk penggunaan bahan bacaan yang sesuai dengan tingkat kecerdasan peserta didik, penerapan metode pembelajaran yang interaktif, dan penciptaan lingkungan belajar yang mendukung. Temuan ini memberikan kontribusi penting dalam upaya meningkatkan kemampuan membaca di tingkat SD, dengan penekanan pada strategi yang dapat diterapkan oleh guru untuk mencapai hasil yang lebih baik dalam pembelajaran membaca kelas 1.

Kata Kunci: Strategi, guru, kemampuan membaca, peserta didik, sekolah dasar.
EFEKTIFITAS PENGGUNAAN MODEL DISCOVERY LEARNING BERBANTUAN ALAT PERAGA SEDERHANA UNTUK MENINGKATKAN KEMAMPUAN KOGNITIF PESERTA DIDIK
Authors: Latuhaimallo Elsa , Tamaela Elsina Sarah , Sahetapy Mariana , Aswaly Felicia , Unawekla Lentji
Published: December 2023

Abstrak. Penggunaan alat peraga yang dibuat oleh guru merupakan salah satu cara yang dapat dipakai untuk mengatasi kendala dalam mengajarkan kosep fisika. Alat peraga menjadi alat bantu untuk menyampaikan informasi pengetahuan kepada peserta didik. Proses transfer informasi tersebut menjadi lebih mudah diterima dengan penggunaan model Discovery Learning. Model yang bersifat konstruktivis akan membantu peserta untuk membentuk konsep sehingga memberikan dampak pada kemampuan kognitif mereka. Penelitian ini merupakan jenis penelitian deskriptif kuantitatif dengan desain One-Group Pretest-Posttest Design. Sekolah yang menjadi lokasi penelitian adalah SMA Negeri 41 Maluku Tengah, dengan subjek peserta didik kelas XI IPA sebanyak 11 orang. Data dikumpulkan melalui instrumen tes yang dilaksanakan sebelum pembelajaran dan setelah pembelajaran. Data yang dikumpulkan selanjutnya dianalisis secara deskriptif. Hasil penelitian memperlihatkan bahwa: 1). Kemampuan kognitif sebelum pembelajaran dimulai memperlihatkan secara keseluruhan gagal untuk mencapai ketuntasan; 2) Kemampuan kognitif setelah proses pembelajaran memperlihatkan bahwa 9,09% sangat baik; 18,82% baik dan 9,09% cukup dengan rerata 83,95; 3) Hasil uji peningkatan kemampuan kognitif ada pada kategori tinggi dengan nilai 0,8. Model Discovery Learning dengan bantuan alat peraga sederhana efektif mampu meningkatkan kemampuan kognitif peserta didik untuk materi fluida ststis.
PENERAPAN MODEL PEMBELAJARAN DISCOVERY LEARNING DALAM MENINGKATKAN HASIL BELAJAR PPKN PADA SISWA KELAS V SD NEGERI 44 MALUKU TENGAH
Authors: Khalis Nela Amalia , Ritiauw Samuel Patra , Johannes Nathalia Yohana
Published: December 2023

Based on the results of initial observations at SD Negeri 44 Central Maluku on February 14 2023, the researchers found a problem, namely in the PPKn learning process for class V students at SD Negeri 44 Central Maluku. The picture was obtained that the learning process was still taking place in one direction, namely from the teacher to the students. . Teachers still deliver material directly, so students cannot experience the knowledge themselves

This research aims to determine the application of the discovery learning model in improving PPKn learning outcomes in class V students at SD Negeri 44 Central Maluku. The type of research used is classroom action research. The subjects in this research were all class V students with a total of 38 students. The data obtained was analyzed using SPSS 24 to determine improvements in learning outcomes. The results of the research show that before using the discovery learning learning model, the results of the initial test with a total of 38 students who reached the KKM were 7 people and 31 others had not succeeded in reaching the KKM. And after carrying out further tests in cycle II, the final test showed an increase in learning outcomes with the results of the final test in cycle II showing that the number of students who scored > 70 was 34 students and 4 students who scored < 70 were in the medium category. This can be seen based on the normalization-gain calculation with the average pre-test value being 49.47, and the average post-test value being 0.78 and the average n-gain value being 78.22. Thus, it can be concluded that the application of the discovery learning model can improve learning outcomes for class V students at SD Negeri 44 Central Maluku.
Is It Difficult to Launch a Pioneering Master’s Program in Translation?
Authors: Kokanova Elena , Lyutyanskaya Maya , Epimakhova Aleksandra
Published: December 2023

As translation technology becomes a part of everyday life, translation students use it not in the same way as professionals do. The teachers’ aim often shifts from introducing Machine Translation (MT) to correcting habits of its use. Moreover, MT literacy and awareness of MT´s possibilities and limitations become an integral part of professional translation competence. Teaching professional translation in this context is a challenge. This paper presents the case of launching a pioneering Master's program “Computer-Assisted and Machine Translation Technology” at Northern (Arctic) Federal University (Russia) in 2021.
Adozioni internazionali e adozioni straniere
L'ambito di competenza del tribunale per i minorenni
Authors: Parenzo Beniamino , Rigotti Beatrice
Published: December 2023

With respect to a foreign adoption measure, the crucial question arises as to whether it is a “foreign adoption” or an “international adoption” measure. While in the first case the rule of automatic recognition applies and, in the event of a dispute, the Court of Appeal is competent to recognize the measure; in the second case, the Juvenile Court is competent for recognition. If looking at the “black letter of the law” the distinction appears clear, in practice there are many “uncertain” cases. The aim of the study was a reconnaissance of these “problematic” cases and to provide a reasoned response to the question of their qualification.