bluuebunny/crossref_metadata_2025 huggingface dataset:
Integrated deep drilling, coring, downhole logging, and data management in the Chicxulub Scientific Drilling Project (CSDP), Mexico
Authors: Wohlgemuth Lothar , Bintakies Eckhard , Kück Jochem , Conze Ronald , Harms Ulrich
Published: January 2010

Abstract— Impact structures in the solar system are mainly recognized and explored through remote sensing and, on Earth, through geophysical deep sounding. To date, a continuous scientific sampling of large impact craters from cover rocks to target material has only seldom been performed. The first project to deep‐drill and core into one of the largest and well‐preserved terrestrial impact structures was executed in the winter of 2001/2002 in the 65 Myr‐old Chicxulub crater in Mexico using integrated coring sampling and in situ measurements. The combined use of different techniques allows a three‐dimensional insight and a better understanding of impact processes.

Here, we report the integration of conventional rotary drilling techniques with wireline mining coring technology that was applied to drill the 1510 m‐deep Yaxcopoil‐1 (Yax‐1) well about 40 km southwest of Mérida, Yucatán, Mexico. During the course of the project, we recovered approximately 900 m of intact core samples including the transitions of reworked ejecta to post‐impact sediments, and that one from large blocks of tilted target material to impact‐generated rocks, i.e., impact melt breccias and suevites. Coring was complemented by wireline geophysical measurements to obtain a continuous set of in situ petrophysical data of the borehole walls. The data acquired is comprised of contents of a natural radioactive element, velocities of compressional sonic waves, and electrical resistivity values. All the digital data sets, including technical drilling parameters, initial scientific sample descriptions, and 360° core pictures, were distributed during the course of the operations via Internet and were stored in the ICDP Drilling Information System (http:www.icdp‐online.org), serving the global community of cooperating scientists as a basic information service.
High resolution temperature measurements in the borehole Yaxcopoil‐1, Mexico
Authors: Wilhelm H. , Heidinger P. , Šafanda J. , Čermák V. , Burkhardt H. , Popov Yu.
Published: January 2010

Abstract— Within the frame of the International Continental Deep Drilling Program (ICDP) and as a part of the Chicxulub Scientific Drilling Project (CSDP), high resolution temperature measurements were performed in the borehole Yaxcopoil‐1 (Yax‐1). The temperature was logged to the depth of 858 m seven times between March 6–19, 2002, starting 10 days after the hole was shut in and mud circulation ceased. Successive logs revealed only small temperature variations in time and space, indicating a fast temperature recovery to almost undisturbed conditions prior to the first log. From these logs, a mean temperature gradient of ∼37 mK/m was determined below the uppermost 250 m. Another temperature log was recorded on May 24, 2003 (15 months after the shut in) to a depth of 895 m. The obtained temperature profile is very similar to the 2002 profile, with an insignificantly higher mean gradient below 250 m that may indicate a long‐term return to the pre‐drilling temperature. The temperature in the uppermost part of the hole bears signs of considerable influence of a convective contribution to the vertical thermal heat transfer. The depth extent of the convection seems to have deepened from 150 m in March 2002 to 230 m in May 2003. Based on the observed temperature gradient and the rock types encountered in the borehole above 670 m, the conducted heat flow is expected to be in the range 65–80 mW/m2.
Impact lithologies and their emplacement in the Chicxulub impact crater: Initial results from the Chicxulub Scientific Drilling Project, Yaxcopoil, Mexico
Authors: Kring David A. , Hörz Friedrich , Zurcher Lukas , Fucugauchi Jaime Urrutia
Published: January 2010

Abstract— The Chicxulub Scientific Drilling Project (CSDP), Mexico, produced a continuous core of material from depths of 404 to 1511 m in the Yaxcopoil‐1 (Yax‐1) borehole, revealing (top to bottom) Tertiary marine sediments, polymict breccias, an impact melt unit, and one or more blocks of Cretaceous target sediments that are crosscut with impact‐generated dikes, in a region that lies between the peak ring and final crater rim. The impact melt and breccias in the Yax‐1 borehole are 100 m thick, which is approximately 1/5 the thickness of breccias and melts exposed in the Yucatán‐6 exploration hole, which is also thought to be located between the peak ring and final rim of the Chicxulub crater. The sequence and composition of impact melts and breccias are grossly similar to those in the Yucatán‐6 hole. Compared to breccias in other impact craters, the Chicxulub breccias are incredibly rich in silicate melt fragments (up to 84% versus 30 to 50%, for example, in the Ries). The melt in the Yax‐1 hole was produced largely from the silicate basement lithologies that lie beneath a 3 km‐ thick carbonate platform in the target area. Small amounts of immiscible molten carbonate were ejected with the silicate melt, and clastic carbonate often forms the matrix of the polymict breccias. The melt unit appears to have been deposited while molten but brecciated after solidification. The melt fragments in the polymict breccias appear to have solidified in flight, before deposition, and fractured during transport and deposition.
Impact‐related dike breccia lithologies in the ICDP drill core Yaxcopoil‐1, Chicxulub impact structure, Mexico
Authors: Wittmann A. , Kenkmann T. , Schmitt R. T. , Hecht L. , Stöffler D.
Published: January 2010

Abstract— Petrographic descriptions of three dike breccia lithologies from drill core Yaxcopoil‐1 (Yax‐1) are presented. They occur within allochthonous units of displaced sedimentary megablocks of the Chicxulub impact structure. The suevitic dike breccias are the uppermost dike lithology. They contain melt rock particles and melt injections into the dike groundmass. Shock features occur ubiquitously and indicate a strong thermal annealing. Flow textures suggest a highly energetic emplacement process, possibly during the excavation stage as a ground‐surge related deposit. The impact melt rock dikes are present in a strongly brecciated megablock interval as flow textured, anastomozing veinlets of impact melt rock that were altered to clay minerals. The melt impregnated a dolomitic host rock, indicating a low viscosity and, thus, high initial temperatures. Brecciation of the impact melt rock dikes occurred while they were still below the glass transition temperature, suggesting that dynamic conditions prevailed shortly after the emplacement process. Major element data indicates that the impact melt rock dikes differ in composition from the homogenized impact melt rock of Chicxulub. This could point to an emplacement during the late compression or early excavation stages of cratering. The clastic polymict dike breccias are coeval with pervasive brittle fracturing of the host rocks. They bear clasts including some crystalline basement and possible melt rock particles in a fine‐grained dolomite matrix with turbulent flow textures. Fabric and texture indicate a granular flow at ambient pressures. Such conditions could be envisaged for the excavation phase while the transient cavity grew and fractures opened.
Geochemistry of drill core samples from Yaxcopoil‐1, Chicxulub impact crater, Mexico
Authors: Schmitt Ralf T. , Wittmann Axel , Stöffler Dieter
Published: January 2010

Abstract— The chemical composition of suevites, displaced Cretaceous target rocks, and impact‐generated dikes within these rocks from the Yaxcopoil‐1 (Yax‐1) drill core, Chicxulub impact crater, Mexico, is reported and compared with the data from the Yucatán 6 (Y6) samples. Within the six suevite subunits of Yax‐1, four units with different chemical compositions can be distinguished: a) upper/lower sorted and upper suevite (depth of 795–846 m); b) middle suevite (depth of 846–861 m); c) brecciated impact melt rock (depth of 861–885 m); and d) lower suevite (depth of 885–895 m). The suevite sequence (a), (b), and (d) display an increase of the CaO content and a decrease of the silicate basement component from top to bottom. In contrast, the suevite of Y6 shows an inverse trend. The different distances of the Yax‐1 and Y6 drilling sites from the crater center (∼60, and ∼47 km, respectively) lead to different suevite sequences. Within the Cretaceous rocks of Yax‐1, a suevitic dike (depth of ∼916 m) does not display chemical differences when compared with the suevite, while an impact melt rock dike (depth of ∼1348 m) is significantly enriched in immobile elements. A clastic breccia dike (depth of ∼1316 m) is dominated by material derived locally from the host rock, while the silicate‐rich component is similar to that found in the suevite. Significant enrichments of the K2O content were observed in the Yax‐1 suevite and the impact‐generated dikes. All impactites of Yax‐1 and Y6 are mixtures of a crystalline basement and a carbonate component from the sedimentary cover. An anhydrite component in the impactites is missing (Yax‐1) or negligible (Y6).
Platinum group elements in impactites of the ICDP Chicxulub drill core Yaxcopoil‐1: Are there traces of the projectile?
Authors: Tagle Roald , Erzinger Jörg , Hecht Lutz , Schmitt Ralf Thomas , Stöffler Dieter , Claeys Philippe
Published: January 2010

Abstract— This study presents results of platinum group element (PGE) analyses of impactites from the Yaxcopoil‐1 (Yax‐1) and Yucatán 6 drill cores of the 180 km‐diameter Chicxulub crater. These are the main elements used for projectile identification. They were determined by nickel sulfide fire assay combined with inductively coupled plasma mass spectrometry. The concentration of PGE in the samples are low. The concentration patterns of the suevite samples resemble the pattern of the continental crust. We conclude that any meteoritic fraction in these samples is below 0.05%. A syn‐ and post‐impact modification of the PGE pattern from meteoritic toward a continental crust pattern is very unlikely. The globally distributed fallout at the Cretaceous‐Tertiary (K/T) boundary, however, has high PGE concentrations. Therefore, the lack of a significant meteoritic PGE signature in the crater is not an argument for a PGE‐poor impactor. Taking the results of three‐dimensional numerical simulations of the Chicxulub event into account, the following conclusions are drawn: 1) The main fraction of the impactor was ejected into and beyond the stratosphere, distributed globally, and deposited in the K/T boundary clay; and 2) the low amount of projectile contamination in the Yax‐1 lithologies may reflect an oblique impact. However, the role of volatiles in the mixing process between projectile and target is not well‐understood and may also have played a fundamental role.
Oxygen isotopic alteration in Ca‐Al‐rich inclusions from Efremovka: Nebular or parent body setting?
Authors: Fagan T. J. , Krot A. N. , Keil K. , Yurimoto H.
Published: January 2010

Abstract— In situ SIMS oxygen isotope data were collected from a coarse‐grained type B1 Ca‐Al‐rich inclusion (CAI) and an adjacent fine‐grained CAI in the reduced CV3 Efremovka to evaluate the timing of isotopic alteration of these two objects. The coarse‐grained CAI (CGI‐10) is a sub‐spherical object composed of elongate, euhedral, normally‐zoned melilite crystals ranging up to several hundreds of Pm in length, coarse‐grained anorthite and Al, Ti‐diopside (fassaite), all with finegrained (∼10 μm across) inclusions of spinel. Similar to many previously examined coarse‐grained CAIs from CV chondrites, spinel and fassaite are 16O‐rich and melilite is 16O‐poor, but in contrast to many previous results, anorthite is 16O‐rich. Isotopic composition does not vary with textural setting in the CAI: analyses of melilite from the core and mantle and analyses from a variety of major element compositions yield consistent 16O‐poor compositions. CGI‐10 originated in an 16O‐rich environment, and subsequent alteration resulted in complete isotopic exchange in melilite. The fine‐grained CAI (FGI‐12) also preserves evidence of a 1st‐generation origin in an 16O‐rich setting but underwent less severe isotopic alteration. FGI‐12 is composed of spinel ± melilite nodules linked by a mass of Al‐diopside and minor forsterite along the CAI rim. All minerals are very fine‐grained (<5 μm) with no apparent igneous textures or zoning. Spinel, Al‐diopside, and forsterite are 16O‐rich, while melilite is variably depleted in 16O (δ17,18O from ∼‐40‰ to −5‰).

The contrast in isotopic distributions in CGI‐10 and FGI‐12 is opposite to the pattern that would result from simultaneous alteration: the object with finer‐grained melilite and a greater surface area/ volume has undergone less isotopic exchange than the coarser‐grained object. Thus, the two CAIs were altered in different settings. As the CAIs are adjacent to each other in the meteorite, isotopic exchange in CGI‐10 must have preceded incorporation of this CAI in the Efremovka parent body. This supports a nebular setting for isotopic alteration of the commonly observed 16O‐poor melilite in coarse‐grained CAIs from CV chondrites.
Infrared, Raman, and cathodoluminescence studies of impact glasses
Authors: Gucsik Arnold , Koeberl Christian , Brandstätter Franz , Libowitzky Eugen , Zhang Ming
Published: January 2010

Abstract— We studied the infrared reflectance (IR), Raman, and cathodoluminescence (CL) spectroscopic signatures and scanning electron microscope‐cathodoluminescence (SEM‐CL) images of three different types of impact glasses: Aouelloul impact glass, a Muong Nong‐type tektite, and Libyan desert glass.

Both backscattered electron (BSE) and CL images of the Muong Nong‐type tektite are featureless; the BSE image of the Libyan desert glass shows only weak brightness contrasts. For the Aouelloul glass, both BSE and CL images show distinct brightness contrast, and the CL images for the Libyan desert glass show spectacular flow textures that are not visible in any other microscopic method. Compositional data show that the SiO2 composition is relatively higher and the Al2O3 content is lower in the CL‐bright areas than in the CL‐dark regions. The different appearance of the three glass types in the CL images indicates different peak temperatures during glass formation: the tektite was subjected to the highest temperature, and the Aouelloul impact glass experienced a relatively low formation temperature, while the Libyan desert glass preserves a flow texture that is only visible in the CL images, indicating a medium temperature.

All IR reflectance spectra show a major band at around 1040 to 1110 cm−1 (antisymmetric stretching of SiO4 tetrahedra), with minor peaks between 745 and 769 cm−1 (Si‐O‐Si angle deformation). Broad bands at 491 and 821 cm−1 in the Raman spectra in all samples are most likely related to diaplectic glass remnants, indicating early shock amorphization followed by thermal amorphization. The combination of these spectroscopic methods allows us to deduce information about the peak formation temperature of the glass, and the CL images, in particular, show glass flow textures that are not preserved in other more conventional petrographic images.
High‐calcium pyroxene as an indicator of igneous differentiation in asteroids and meteorites
Authors: Sunshine Jessica M. , Bus Schelte J. , McCoy Timothy J. , Burbine Thomas H. , Corrigan Catherine M. , Binzel Richard P.
Published: January 2010

Abstract— Our analyses of high quality spectra of several S‐type asteroids (17 Thetis, 847 Agnia, 808 Merxia, and members of the Agnia and Merxia families) reveal that they include both low‐ and high‐calcium pyroxene with minor amounts of olivine (<20%). In addition, we find that these asteroids have ratios of high‐calcium pyroxene to total pyroxene of >∼0.4. High‐calcium pyroxene is a spectrally detectable and petrologically important indicator of igneous history and may prove critical in future studies aimed at understanding the history of asteroidal bodies. The silicate mineralogy inferred for Thetis and the Merxia and Agnia family members requires that these asteroids experienced igneous differentiation, producing broadly basaltic surface lithologies. Together with 4 Vesta (and its smaller “Vestoid” family members) and the main‐belt asteroid 1489 Magnya, these new asteroids provide strong evidence for igneous differentiation of at least five asteroid parent bodies. Based on this analysis of a small subset of the near‐infrared asteroid spectra taken to date with SpeX at the NASA IRTF, we expect that the number of known differentiated asteroids will increase, consistent with the large number of parent bodies inferred from studies of iron meteorites.
Chicxulub central crater structure: Initial results from physical property measurements and combined velocity and gravity modeling
Authors: VERMEESCH P. M. , MORGAN J. V.
Published: January 2010

Abstract The Chicxulub crater in Mexico is a nearly pristine example of a large impact crater. Its slow burial has left the central impact basin intact, within which there is an apparently uneroded topographic peak ring. Its burial, however, means that we must rely on drill holes and geophysical data to interpret the crater form. Interpretations of crater structures using geophysical data are often guided by numerical modeling and observations at other large terrestrial craters. However, such endeavors are hindered by uncertainties in current numerical models and the lack of any obvious progressive change in structure with increasing crater size. For this reason, proposed structural models across Chicxulub remain divergent, particularly within the central crater region, where the deepest well is only ˜1.6 km deep. The shape and precise location of the stratigraphic uplift are disputed. The spatial extent and distribution of the allogenic impact breccias and melt rocks remain unknown, as do the lithological nature of the peak ring and the mechanism for its formation.

The objective of our research is to provide a well‐constrained 3D structural and lithological model across the central region of the Chicxulub crater that is consistent with combined geophysical data sets and drill core samples. With this in mind, we present initial physical property measurements made on 18 core samples from the Yaxcopoil‐1 (Yax‐1) drill hole between 400 and 1500 m deep and present a new density model that is in agreement with both the 3D velocity and gravity data. Future collation of petrophysical and geochemical data from Yax‐1 core, as well as further seismic surveys and drilling, will allow us to calibrate our geophysical models—assigning a suite of physical properties to each lithology. An accurate 3D model of Chicxulub is critical to our understanding of large craters and to the constraining of the environmental effects of this impact.
Stratigraphic and sedimentological observations from seismic data across the Chicxulub impact basin
Authors: BELL C. , MORGAN J. V. , HAMPSON G. J. , TRUDGILL B.
Published: January 2010

AbstractSeismic data across the offshore half of the Chicxulub impact crater reveal a 145 km‐diameter post‐impact basin to be a thickening of Tertiary sediment, which thickens by ˜0.7 sec from the basin margin to the basin center. The basin existed long after the impact and was gradually infilled to its current flat surface. A suite of seismic horizons within the impact basin have been picked on four reflection lines across the crater. They reveal that the western and northwestern parts of the impact basin were filled first. Subsequently, there was a dramatic change in the depositional environment, indicated by an unconformable surface that can be mapped across the entire basin. A prograding shelf sequence downlaps onto this unconformity in the eastern basin. The seismic stratigraphic relationships suggest a marine regression, with sedimentation becoming gradually more passive as sediments fill the eastern part of the impact basin. The central and northeastern parts of the basin are filled last.

The onshore hole Yaxcopoil‐1 (Yax‐1), which was drilled on the flanks of the southern basin, has been projected onto the offshore seismic data to the west of the crater center. Using dates obtained from this onshore well and regional data, approximate ages have been placed on the most significant horizons in the offshore seismic data. Our preliminary interpretation is that the western and northwestern basins were almost entirely filled by 40 Ma and that the marine regression observed in the eastern basin is early Miocene in age. Offshore seismic stratigraphic analyses and onshore data within Yax‐1 suggest that the early Paleocene is highly attenuated across the impact basin. The Mesozoic section appears to be ˜1 km thicker offshore than onshore. We calculate that, given this offshore thickening, the volume of Mesozoic rocks that have been excavated, melted, or vaporized during impact is around 15% larger than expected from calculations that assume the offshore thickness is equal to that onshore. This has significant consequences for any environmental calculations. The current offset between the K‐T boundary outside and inside the crater is ˜700 m. However, infilling of basins with sediments is usually accompanied by subsidence, and immediately following the impact, the difference would have been smaller. We calculate the original topographic offset on the K‐T boundary to have been between 450 and 700 m, which is in agreement with depth‐diameter scaling laws for a mixed target.
Foraminiferal biostratigraphy and paleoenvironmental reconstruction at the Yaxcopoil‐1 drill hole, Chicxulub crater, Yucatán Peninsula
Authors: ARZ José A. , ALEGRET Laia , ARENILLAS Ignacio
Published: January 2010

Abstract The Yaxcopoil‐1 (Yax‐1) drill hole comprises Cretaceous limestones and calcarenites, the K/P boundary cocktail unit (including impact breccia), and a Danian marly clay layer overlain by calcareous marls. The biostratigraphy, paleobathymetry, and environmental turnover across the K/P interval were inferred after analyzing the planktic and benthic foraminiferal assemblages. The Cretaceous samples only contain a few poorly preserved planktic foraminifera of a middle Campanian to Maastrichtian age, while low‐diversity benthic foraminiferal assemblages suggest a sufficient nutrient supply to the sea floor and a shallow neritic, occasionally stressed environment. The impact breccia and the redeposited suevite are overlain by a 46 cm‐thick dolomitic calcareous sandstone unit that contains scarce, reworked planktic foraminiferal specimens. This unit probably represents the uppermost part of the initial infill of the crater. The uppermost centimeters of this unit are bioturbated, and its top represents a hiatus that spans at least the G. cretacea, Pv. eugubina, and part of the P. pseudobulloides biozones. This unit is overlain by a 3–4 cm‐thick marly clay layer that represents a condensed layer. Benthic foraminiferal assemblages suggest a low food supply to the sea floor and environmental instability during the deposition of the marly clay layer. The increase in diversity of the assemblages indicates that the environmental conditions improved and stabilized from the G. compressa biozone toward the A. uncinata (P2) biozone. The Danian planktic and benthic foraminiferal assemblages indicate a deeper, probably bathyal environment.
More evidence that the Chicxulub impact predates the K/T mass extinction
Authors: KELLER Gerta , ADATTE Thierry , STINNESBECK Wolfgang , STüBEN Doris , BERNER Zsolt , KRAMAR Utz , HARTING Markus
Published: January 2010

Abstract Yaxcopoil‐1 (Yax‐1), drilled within the Chicxulub crater, was expected to yield the final proof that this impact occurred precisely 65 Myr ago and caused the mass extinction at the Cretaceous‐Tertiary (K/T) boundary. Instead, contrary evidence was discovered based on five independent proxies (sedimentologic, biostratigraphic, magnetostratigraphic, stable isotopic, and iridium) that revealed that the Chicxulub impact predates the K/T boundary by about 300,000 years and could not have caused the mass extinction. This is demonstrated by the presence of five bioturbated glauconite layers and planktic foraminiferal assemblages of the latest Maastrichtian zone CF1 and is corroborated by magnetostratigraphic chron 29r and characteristic late Maastrichtian stable isotope signals. These results were first presented in Keller et al. (2004). In this study, we present more detailed evidence of the presence of late Maastrichtian planktic foraminifera, sedimentologic, and mineralogic analyses that demonstrate that the Chicxulub impact breccia predates the K/T boundary and that the sediments between the breccia and the K/T boundary were deposited in a normal marine environment during the last 300,000 years of the Cretaceous.
Cooling of the Kärdla impact crater: I. The mineral paragenetic sequence observation
Authors: VERSH Evelin , KIRSIMÄE Kalle , JÕELEHT Argo , PLADO Jüri
Published: January 2010

Abstract— The impact‐induced hydrothermal system in the well‐preserved, 4 km‐diameter Kärdla impact crater on Hiiumaa Island, western Estonia, was investigated by means of mineralogical, chemical, and stable C and O isotope studies. The mineralization paragenetic sequence, with gradually decreasing temperature, reveals at least three evolutionary stages in the development of the post‐impact hydrothermal system: 1) an early vapor‐dominated stage (>300 °C) with precipitation of submicroscopic adularia type K‐feldspar; 2) the main stage (300 to 150/100 °C) with the development of a two‐phase (vapor to liquid) zone leading to precipitation of chlorite/corrensite, (idiomorphic) euhedral K‐feldspar, and quartz; and 3) a late liquid‐dominated stage (<100 °C) with calcite I, dolomite, quartz, calcite II, chalcopyrite/pyrite, Fe‐oxyhydrate, and calcite III precipitation.
Fragmentation model of meteoroid motion, mass loss, and radiation in the atmosphere
Authors: CEPLECHA Zdeněk , REVELLE Douglas O.
Published: January 2010

Abstract— We present the basic differential equations of meteor physics (the single body equations). We solve them numerically including two possible types of fragmentation: into large pieces and into a cluster of small fragments. We have written a Fortran code that computes the motion, ablation and light intensity of a meteoroid at chosen heights, and allows for the ablation and shape density coefficients σ and K, as well as the luminous efficiency τ, to be variable with height/time. We calibrated our fragmentation model (FM) by the best fit to observational values for the motion, ablation, radiation, fragmentation and the terminal masses (recovered meteorites) for the Lost City bolide. The FM can also handle multiple and overlapping meteor flares. We separately define both the apparent and intrinsic values of σ, K, and τ. We present in this paper values of the intrinsic luminous efficiency as function of velocity, mass, and normalized air density. Detailed results from the successful application of the FM to the Lost City, Innisfree, and Benesov bolides are also presented. Results of applying the FM to 15 bolides with very precise observational data are presented in a survey mode (Table 7). Standard deviations of applying our FM to all these events correspond to the precision of the observed values. Typical values of the intrinsic ablation coefficient are low, mostly in the range from 0.004 to 0.008 s2 km−2, and do not depend on the bolide type. The apparent ablation coefficients reflect the process of fragmentation. The bolide types indicate severity of the fragmentation process. The large differences of the “dynamic” and “photometric” mass from numerous earlier studies are completely explained by our FM. The fragmentation processes cannot be modeled simply by large values of the apparent ablation coefficient and of the apparent luminous efficiency. Moreover, our new FM can also well explain the radiation and full dynamics of very fast meteoroids at heights from 200 km to 130 km.
Northwest Africa 011: A “eucritic” basalt from a non‐eucrite parent body
Authors: Floss Christine , Taylor Larry A. , Promprated Prinya , Rumble Douglas
Published: January 2010

Abstract— We have carried out a detailed petrographic, mineralogical, and trace element study of Northwest Africa (NWA) 011. This meteorite bears many similarities to the eucrites it was initially identified with, although oxygen isotopic compositions rule out a genetic relationship. Like many eucrites, NWA 011 crystallized from a source with approximately chondritic proportions of REE, although a slightly LREE‐enriched bulk composition with a small positive Eu anomaly, as well as highly fractionated Fe/Mg ratios and depleted Sc abundances (Korotchantseva et al. 2003), suggest that the NWA 011 source experienced some pyroxene and/or olivine fractionation. Thermal metamorphism resulted in homogenization of REE abundances within grains, but NWA 011 did not experience the intergrain REE redistribution seen in some highly metamorphosed eucrites. Despite a similarity in oxygen isotopic compositions, NWA 011 does not represent a basaltic partial melt from the acapulcoite/lodranite parent body. The material from which NWA 011 originated may have been like some CH or CB chondrites, members of the CR chondrite clan, which are all related through oxygen isotopic compositions. The NWA 011 parent body is probably of asteroidal origin, possibly the basaltic asteroid 1459 Magnya.
Evidence of space weathering in regolith breccias I: Lunar regolith breccias
Authors: Noble Sarah K. , Keller Lindsay P. , Pieters Carlé M.
Published: January 2010

Abstract— We have analyzed a suite of lunar regolith breccias in order to assess how well space weathering products can be preserved through the lithification process and therefore whether or not it is appropriate to search for space weathering products in asteroidal regolith breccia meteorites. It was found that space weathering products, vapor/sputter deposited nanophase‐iron‐bearing rims in particular, are easily identified in even heavily shocked/compacted lunar regolith breccias. Such rims, if created on asteroids, should thus be preserved in asteroidal regolith breccia meteorites. Two additional rim types, glass rims and vesicular rims, identified in regolith breccias, are also described. These rims are common in lunar regolith breccias but rare to absent in lunar soils, which suggests that they are created in the breccia‐forming process itself. While not “space weathering products” in the strictest sense, these additional rims give us insight into the regolith breccia formation process. The presence or absence of glass and/or vesicular rims in asteroidal regolith breccias will likewise tell us about environmental conditions on the surface of the asteroid body on which the breccia was created.
Raman spectroscopy of olivine in dunite experimentally shocked to pressures between 5 and 59 GPa
Authors: Farrell‐Turner S. , Reimold W. U. , Nieuwoudt M. , Erasmus R. M.
Published: January 2010

Abstract— Previous Raman investigations on experimentally shocked ingle‐crystal olivine indicated that the olivine Raman bands seemingly shift to a higher wave number with increasing shock pressure. If this effect could be confirmed, Raman analysis of natural shock‐metamorphosed minerals could potentially provide an important shock barometric tool. We carried out a Raman spectroscopic study on olivine in a series of natural dunite samples experimentally shocked to pressures between 5 and 59 GPa. In addition, we analyzed olivine grains in a sample of the Cold Bokkeveld C1 meteorite. We studied samples of several dunites with olivine of 90.64–92.00 mole% Fo to determine Raman effects in the region from 200 to 900 cm−1. Several olivine grains per sample/shock pressure stage were analyzed. Raman analysis, however, showed little or no shift with increasing shock pressure. The shifts to higher or lower frequencies observed were not specific for a given pressure stage, with some grains within a sample showing more shift than others. This finding is unrelated to the crystallographic orientation of analyzed grains and cannot be related systematically to the different degrees of optically determined shock metamorphism of the analyzed grains. We identified an increase in full width at half maximum (FWHM) for the 824 cm−1 band with increased shock pressure in the shocked Åheim samples above 45 GPa and, to a lesser extent, for the 856 cm−1 band. Evaluation of band broadening of olivine in the Cold Bokkeveld meteorite showed FWHM values that were much greater (9–20 cm−1) than those of olivine in the shocked dunite samples (7–12 cm−1). We concluded that these differences in FWHM are due to differences in chemical composition between the meteoritic and the experimentally shocked olivine. Therefore, using Raman spectroscopy to detect small shifts in wave numbers to higher frequencies with increased shock pressure does not yield consistent effects for polycrystalline dunite. An extra band at 650 cm−1 was identified in the Raman spectra of the unshocked Mooihoek dunite and the Åheim dunite samples shocked to 5, 29.3, and 59 GPa, as well as another at 696 cm−1 in all the spectra of the 59 GPa Åheim sample. The cause of these extra bands is not known. Comparison of these results with Raman spectra of olivine from the Cold Bokkeveld C1 meteorite did not allow us to determine shock pressures for the meteoritic olivine.
Weathering features in shocked quartz from the Ries impact crater, Germany
Authors: Leroux Hugues
Published: January 2010

Abstract— Shocked quartz from the ejecta of the Ries impact structure has been investigated by analytical transmission electron microscopy (ATEM). Quartz grains display numerous planar fractures (PFs) and planar deformation features (PDFs). Both are partly or fully replaced by a mineral of the kaolinite group (likely halloysite). Its formation involves fluid circulation into the dense fracture networks, dissolution and removal of the amorphous phase initially present in PDFs, and finally, precipitation and crystallization of the kaolinite group mineral from solutions resulting from the chemical alteration of adjacent minerals (feldspars and biotite). Kaolinite group minerals are typical of hydrothermal alteration at low temperature, in humid climate, and under moderately acid conditions and, thus, this alteration may not be directly related to the impact event itself. However, the weathering features were strongly enhanced by the shock‐generated microstructure, in particular by fractures that provided pathways for fluid circulation.
40Ar/39Ar dating and cosmic‐ray exposure time of desert meteorites: Dhofar 300 and Dhofar 007 eucrites and anomalous achondrite NWA 011
Authors: Korochantseva Ekaterina V. , Trieloff Mario , Buikin Alexei I. , Hopp Jens , Meyer Hans‐Peter
Published: January 2010

Abstract— We performed high‐resolution 40Ar‐39Ar dating of mineral separates and whole‐rock samples from the desert meteorites Dhofar 300, Dhofar 007, and Northwest Africa (NWA) 011. The chronological information of all samples is dominated by plagioclase of varying grain size. The last total reset age of the eucrites Dhofar 300 and Dhofar 007 is 3.9 ± 0.1 Ga, coeval with the intense cratering period on the Moon. Some large plagioclase grains of Dhofar 007 possibly inherited Ar from a 4.5 Ga event characteristic for other cumulate eucrites. Due to disturbances of the age spectrum of NWA 011, only an estimate of 3.2–3.9 Ga can be given for its last total reset age. Secondary events causing partial 40Ar loss ≤3.4 Ga ago are indicated by all age spectra. Furthermore, Ar extractions from distinct low temperature phases define apparent isochrons for all samples. These isochron ages are chronologically irrelevant and most probably caused by desert alterations, in which radiogenic 40Ar and K from the meteorite and occasionally K induced by weathering are mixed, accompanied by incorporation of atmospheric Ar. Additional uptake of atmospheric Ar by the alteration phase(s) was observed during mineral separation (i.e., crushing and cleaning in ultrasonic baths). Consistent cosmic‐ray exposure ages were obtained from plagioclase and pyroxene exposure age spectra of Dhofar 300 (25 ± 1 Ma) and Dhofar 007 (13 ± 1 Ma) using the mineral's specific target element chemistry and corresponding 38Ar production rates.
The prospect of high‐precision Pb isotopic dating of meteorites
Authors: Amelin Yuri
Published: January 2010

Abstract— The radiogenic 207Pb/206Pb ratio is the only extant nuclide chronometer with sufficient time resolution for studies of the solar nebula accretion and early asteroidal differentiation and metamorphism. Pb isotopic dates can be used to link the dates obtained from extinct nuclide chronometers to the absolute time scale. The factors that control precision and accuracy of Pb isotopic dates of meteorites: instrumental mass fractionation in isotopic analysis, mass spectrometer sensitivity, removal of common Pb, multi‐stage evolution of U‐Pb systems, disturbances caused by diffusion, alteration, and shock metamorphism, and uncertainties in decay constants and the natural ratio of the U isotopes are reviewed. The precision of Pb isotopic dates of meteorites attained with currently available techniques and methodology is ±0.5–1.0 Myr in favorable cases. The accuracy of time interval measurements is approximately the same. The most serious limitation on precision and accuracy of Pb isotopic dates is placed by the presence of common Pb of uncertain and/or variable isotopic composition. Improvement in precision and accuracy of Pb isotopic dates would be possible through combined advancement of techniques of isotopic analysis (most importantly, better control over instrumental mass fractionation) and more effective techniques for the removal of common Pb, together with a better understanding of the effects of thermal metamorphism, shock metamorphism, and aqueous alteration on the U‐Pb system in meteorites.
The I‐Xe chronometer and the early solar system
Authors: Gilmour J. D. , Pravdivtseva O. V. , Busfield A. , Hohenberg C. M.
Published: January 2010

Abstract— We review the development of the I‐Xe technique and how its data are interpreted, and specify the best current practices. Individual mineral phases or components can yield interpretable trends in initial 129I/127I ratio, whereas whole‐rock I‐Xe ages are often hard to interpret because of the diversity of host phases, many of which are secondary. Varying standardizations in early work require caution; only samples calibrated against Shallowater enstatite or Bjurböle can contribute reliably to the emerging I‐Xe chronology of the early solar system.

Although sparse, data for which I‐Xe and Mn‐Cr can be compared suggest that the two systems are concordant among ordinary chondrite samples. We derive a new age for the closure of the Shallowater enstatite standard of 4563.3 ± 0.4 Myr from the relationship between the I‐Xe and Pb‐Pb systems. This yields absolute I‐Xe ages and allows data from this and other systems to be tested by attempting to construct a common chronology of events in the early solar system.

Absolute I‐Xe dates for aqueous and igneous processes are consistent with other systems. Consideration of the I‐Xe host phases in CAIs and dark inclusions demonstrates that here the chronometer records aqueous alteration of pre‐existing material. The ranges of chondrule ages deduced from the Al‐Mg and I‐Xe systems in Semarkona (LL3.0) and Chainpur (LL3.4) are consistent. Chainpur I‐Xe data exhibit a greater range of ages than Semarkona, possibly reflecting a greater degree of parent body processing. However individual chondrules show little or no evidence of such processing. Determining the host phase(s) responsible for high temperature correlations may resolve the issue.
Maximal size of chondrules in shock wave heating model: Stripping of liquid surface in a hypersonic rarefied gas flow
Authors: Kato Takaaki , Nakamoto Taishi , Miura Hitoshi
Published: January 2010

Abstract— We examined partially molten dust particles that have a solid core and a surrounding liquid mantle, and estimated the maximal size of chondrules in a framework of the shock wave heating model for chondrule formation. First, we examined the dynamics of the liquid mantle by analytically solving the hydrodynamics equations for a core‐mantle structure via a linear approximation. We obtained the deformation, internal flow, pressure distribution in the liquid mantle, and the force acting on the solid core. Using these results, we estimated conditions in which liquid mantle is stripped off from the solid core. We found that when the particle radius is larger than about 1–2 mm, the stripping is expected to take place before the entire dust particle melts. So chondrules larger than about 1–2 mm are not likely to be formed by the shock wave heating mechanism. Also, we found that the stripping of the liquid mantle is more likely to occur than the fission of totally molten particles. Therefore, the maximal size of chondrules may be determined by the stripping of the liquid mantle from the partially molten dust particles in the shock waves. This maximal size is consistent with the sizes of natural chondrules.
Conditions in the protoplanetary disk as seen by the type B CAIs
Authors: Richter Frank M. , Mendybaev Ruslan A. , Davis Andrew M.
Published: January 2010

Abstract— Type B coarse‐grained calcium‐aluminum‐rich inclusions (CAIs) are the oldest known materials to have formed in the solar system and are a unique source of information regarding conditions and processes in the protoplanetary disk around the young sun. Recent experimental results on the crystallization and evaporation of type B‐like silicate melts allow us to place the following constraints on the conditions in the protoplanetary disk during the formation of type B CAIs. 1) Once type B CAIs precursors have been condensed from a solar composition gas, they were reheated at 1250–1450 °C, as is indicated by their igneous texture. 2) The melilite mantles characteristic of type B1 CAIs could be formed by crystallization of magnesium‐ and silicon‐depleted melt in the outer part of the partially molten droplets. Such depletion can arise when evaporation is fast compared to chemical diffusion in the melt. This requires the pressure of the surrounding solar composition gas to be at least 10−4 bars during the initial crystallization of melilite mantle. Type B2 CAIs with uniform distribution of melilite are expected to form at pressures less than 10−5 bars. 3) Evaporation calculations are used to place bounds on the thermal history of the type B CAIs. Observed compositional zoning in melilite suggests that the temperatures in the protoplanetary disk where the type B CAIs resided after crystallization could not have exceeded ˜1000 °C for more than a few tens of thousands of years. A recent calculation of the physical conditions associated with nebular shocks produced transient temperatures and gas pressures very much like what we find is required to melt reasonable CAI precursors and evaporate these sufficiently quickly to make a type B1 CAI.
Petrography and geochemistry of five new Apollo 16 mare basalts and evidence for post‐basin deposition of basaltic material at the site
Authors: Zeigler Ryan A. , Korotev Randy L. , Haskin Larry A. , Jollif Bradley L. , Gillis Jeffrey J.
Published: January 2010

Abstract— We present the petrography and geochemistry of five 2–4 mm basalt fragments from the Apollo 16 regolith. These fragments are 1) a high‐Ti vitrophyric basalt compositionally similar to Apollo 17 high‐Ti mare basalts, 2) a very high‐Ti vitrophyric basalt compositionally similar to Apollos 12 and 14 red‐black pyroclastic glass, 3) a coarsely crystalline high‐Al basalt compositionally similar to group 5 Apollo 14 high‐Al mare basalts, 4) a very low‐Ti (VLT) crystalline basalt compositionally similar to Luna 24 VLT basalts, and 5) a VLT basaltic glass fragment compositionally similar to Apollo 17 VLT basalts. High‐Ti basalt has been reported previously at the Apollo 16 site; the other basalt types have not been reported previously. As there are no known cryptomaria or pyroclastic deposits in the highlands near the Apollo 16 site (ruling out a local origin), and scant evidence for basaltic material in the Apollo 16 ancient regolith breccias or Apollo 16 soils collected near North Ray Crater (ruling out a basin ejecta origin), we infer that the basaltic material in the Apollo 16 regolith originated in maria near the Apollo 16 site and was transported laterally to the site by small‐ to medium‐sized post‐basin impacts. On the basis of TiO2 concentrations derived from the Clementine UVVIS data, Mare Tranquillitatis (˜300 km north) is the most likely source for the high‐Ti basaltic material at the Apollo 16 site (craters Ross, Arago, Dionysius, Maskelyne, Moltke, Sosigenes, Schmidt), Mare Nectaris/Sinus Asperitatis (˜220 km east) is the most likely source for the low‐Ti and VLT basaltic material (craters Theophilus, Madler, Torricelli), and a large regional pyroclastic deposit near Mare Vaporum (˜600 km northwest) is the most likely source region for pyroclastic material (although no source craters are apparent in the region).
An atmospheric blast/thermal model for the formation of high‐latitude pedestal craters
Authors: Wrobel Kelly , Schultz Peter , Crawford David
Published: January 2010

Abstract— Although tenuous, the atmosphere of Mars affects the evolution of impact‐generated vapor. Early‐time vapor from a vertical impact expands symmetrically, directly transferring a small percentage of the initial kinetic energy of impact to the atmosphere. This energy, in turn, induces a hemispherical shock wave that propagates outward as an intense airblast (due to high‐speed expansion of vapor) followed by a thermal pulse of extreme atmospheric temperatures (from thermal energy of expansion). This study models the atmospheric response to such early‐time energy coupling using the CTH hydrocode written at Sandia National Laboratories. Results show that the surface surrounding a 10 km diameter crater (6 km “apparent” diameter) on Mars will be subjected to intense winds (˜200 m/s) and extreme atmospheric temperatures. These elevated temperatures are sufficient to melt subsurface volatiles at a depth of several centimeters for an ice‐rich substrate. Ensuing surface signatures extend to distal locations (˜4 apparent crater diameters for a case of 0.1% energy coupling) and include striations, thermally armored surfaces, and/or ejecta pedestals—all of which are exhibited surrounding the freshest high‐latitude craters on Mars. The combined effects of the atmospheric blast and thermal pulse, resulting in the generation of a crater‐centered erosion‐resistant armored surface, thus provide a new, very plausible formation model for high‐latitude Martian pedestal craters.