bluuebunny/crossref_metadata_2025 huggingface dataset:
Monolithic Stirrer Reactors for the Sustainable Production of Dihydroxybenzenes over 3D Printed Fe/γ-Al2O3 Monoliths: Kinetic Modeling and CFD Simulation
Authors: López Pablo , Quintanilla Asunción , Salazar-Aguilar Alma D. , Vega-Díaz Sofía M. , Díaz-Herrezuelo Irene , Belmonte Manuel , Casas Jose A.
Published: January 2022

The aim of this work is to evaluate the performance of the stirring 3D Fe/Al2O3 monolithic reactor in batch operation applied to the liquid-phase hydroxylation of phenol by hydrogen peroxide (H2O2). An experimental and numerical investigation was carried out at the following operating conditions: CPHENOL,0 = 0.33 M, CH2O2,0 = 0.33 M, T = 75–95 °C, P = 1 atm, ω = 200–500 rpm and WCAT ~ 1.1 g. The kinetic model described the consumption of the H2O2 by a zero-order power-law equation, while the phenol hydroxylation and catechol and hydroquinone production by Eley–Rideal model; the rate determining step was the reaction between the adsorbed H2O2, phenol in solution with two active sites involved. The 3D CFD model, coupling the conservation of mass, momentum and species together with the reaction kinetic equations, was experimentally validated. It demonstrated a laminar flow characterized by the presence of an annular zone located inside and surrounding the monoliths (u = 40–80 mm s−1) and a central vortex with very low velocities (u = 3.5–8 mm s−1). The simulation study showed the increasing phenol selectivity to dihydroxybenzenes by the reaction temperature, while the initial H2O2 concentration mainly affects the phenol conversion.
A Leucine Zipper Dimerization Strategy to Generate Soluble T Cell Receptors Using the Escherichia coli Expression System
Authors: Zhang Angela , Piechocka-Trocha Alicja , Li Xiaolong , Walker Bruce D.
Published: January 2022

T cell-mediated adaptive immunity plays a key role in immunological surveillance and host control of infectious diseases. A better understanding of T cell receptor (TCR) recognition of pathogen-derived epitopes or cancer-associated neoantigens is the basis for developing T cell-based vaccines and immunotherapies. Studies on the interaction between soluble TCR α:β heterodimers and peptide-bound major histocompatibility complexes (pMHCs) inform underlying mechanisms driving TCR recognition, but not every isolated TCR can be prepared in soluble form for structural and functional studies using conventional methods. Here, taking a challenging HIV-specific TCR as a model, we designed a general leucine zipper (LZ) dimerization strategy for soluble TCR preparation using the Escherichia coli expression system. We report details of TCR construction, inclusion body expression and purification, and protein refolding and purification. Measurements of binding affinity between the TCR and its specific pMHC using surface plasmon resonance (SPR) verify its activity. We conclude that this is a feasible approach to produce challenging TCRs in soluble form, needed for studies related to T cell recognition.
Innate Immune Responses in Pediatric Patients with Gastritis—A Trademark of Infection or Chronic Inflammation?
Authors: Meliț Lorena Elena , Mărginean Cristina Oana , Săsăran Maria Oana , Mocanu Simona , Ghiga Dana Valentina , Crișan Adriana , Bănescu Claudia
Published: January 2022

The aim of this study was to define the relationship between several environmental, laboratory, and genetic factors, i.e., TLR2 and NLRP3 polymorphisms, and Helicobacter pylori (H. pylori) infection in children, by comparing three different groups of pediatric subjects: H. pylori-induced gastritis, non-H. pylori gastritis, and healthy controls. Our final study sample included 269 children, which were divided into three groups according to the histopathological exam: group 1 with 51 children with H. pylori-induced gastritis, group 2 with 103 children with H. pylori-negative gastritis, and group 3 (control group) with 115 children without any histopathological changes. All children underwent a thorough anamnesis, clinical exam, laboratory tests, and upper digestive endoscopy with gastric biopsy for rapid urease test, histopathological exam, and genetic analysis of TLR2 rs3804099, TLR2 rs3804100, and NLRP3 rs10754558 gene polymorphisms. We noticed a significant association between living conditions and the type of gastritis (p < 0.0001). Both rapid urease and serological tests were significantly associated with the presence of H. pylori (p < 0.0001). The CT variant genotype of TLR2 rs380499 was significantly associated with neutrophil count (p = 0.0325). We noticed a significant association between the CC variant genotype of NLRP3 rs10754558 and leucocytes, neutrophils, eosinophils, as well as ALT (p = 0.0185, p = 0.0379, p = 0.0483, p = 0.0356). Based on these findings, we state that poor living conditions and rural areas represent risk factors for H. pylori infection. The rapid urease test is a reliable diagnostic tool for this infection. CT and TT carriers of TLR2 rs3804099, as well as CC carriers of NLRP3 rs10754558, might display a more severe degree of systemic inflammation.
Impact of Cardiac Injury on the Clinical Outcome of Children with Convulsive Status Epilepticus
Authors: Ibrahim Ahmed , Megahed Ahmed , Salem Ahmed , Zekry Osama
Published: January 2022

Objectives: the aim of this study was to determine the impact of cardiac injury on clinical profile, cardiac evaluation and outcome in patients hospitalized with convulsive status epilepticus (CSE). Materials and methods: this prospective observational study included 74 children with CSE. Cardiac injury was evaluated and defined using combination of cardiac troponin, electrocardiography (ECG) and echocardiography. Clinical outcome and mortality rates were compared in patients with and without cardiac injury. Results: A total of 74 patients with CSE were included in the study. Thirty-six (48.6%) patients demonstrated markers of cardiac injury. ECG changes occurred in 45.9% and echocardiographic signs of left ventricular systolic and diastolic dysfunction reported in 5.4% and 8.1%, respectively. The mean length of hospital stays and need for ICU admission were significantly higher in patients with cardiac injury compared to others. One third of patients with cardiac injury needed mechanical ventilation and this was significantly higher than patients without (p = 0.042). hypotension and/or shock developed in 25% of cardiac injury patients and most of them required inotropic support; this was significantly higher than others without markers of cardiac injury. The overall mortality in cardiac injury group was higher (13.9% vs. 2.6%); however, this difference was not statistically significant. Conclusion: Markers of cardiac injury were common and associated with poor clinical outcome and higher risk of mortality in patients with CSE, so extensive routine cardiovascular evaluation is essential in these patients.
Suitability Assessment of Weather Networks for Wind Data Measurements in the Athabasca Oil Sands Area
Authors: Deshmukh Dhananjay , Ahmed M. Razu , Dominic John Albino , Gupta Anil , Achari Gopal , Hassan Quazi K.
Published: January 2022

The Athabasca Oil Sands Area (AOSA) in Alberta, Canada, is considered to have a high density of weather stations. Therefore, our objective was to determine an optimal network for the wind data measurement that could sufficiently represent the wind variability in the area. We used available historical data records of the weather stations in the three networks in AOSA, i.e., oil sands monitoring (OSM) water quantity program (WQP) and Wood Buffalo Environmental Association (WBEA) edge sites (ES) and meteorological towers (MT) of the air program. Both graphical and quantitative methods were implemented to find the correlations and similarities in the measurements between weather stations in each network. The graphical method (wind rose diagram) was found as a functional tool to understand the patterns of wind directions, but it was not appropriate to quantify and compare between wind speed data of weather stations. Therefore, we applied the quantitative method of the Pearson correlation coefficient (r) and absolute average error (AAE) in finding a relationship between the wind data of station pairs and the percentage of similarity (PS) method in quantifying the closeness/similarity. In the correlation analyses, we found weak to strong correlations in the wind data of OSM WQP (r = 0.04–0.69) and WBEA ES (r = 0.32–0.77), and a strong correlation (r = 0.33–0.86) in most of the station pairs of the WBEA MT network. In the case of AAE, we did not find any acceptable value within the standard operating procedure (SOP) threshold when logically combining the values of the u and v components together. In the similarity analysis, minor similarities were identified between the stations in the three networks. Hence, we presumed that all weather stations would be required to measure wind data in the AOSA.
Microstructure and Wear Resistance of a Cr7C3 Reinforced Ni3Al Composite Coating Prepared by Laser Cladding
Authors: Liu Zhenbo , Yin Fuxing , Chen Cuixin , Zhao Lin , Fu Lihua , Feng Yingkai , Cao Yang , Peng Yun , Tian Zhiling , Li Changhai
Published: January 2022

Using Cr7C3/Ni3Al alloyed powder and Cr3C2/Ni3Al mixed powder, laser cladding was carried out to prepare a Cr7C3 reinforced Ni3Al composite cladding layer. The microstructure and tribological properties of the cladding materials were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), transmission electron microscopy (TEM), and wear tests. The results indicate that the microstructure of the Cr7C3/Ni3Al alloyed powder cladding layer contains mainly Ni3Al, NiAl, and in situ-formed Cr7C3, whereas Cr3C2 occurs in the Cr3C2/Ni3Al mixed powder cladding layer. The friction coefficient and wear loss of the alloyed powder cladding layer are about 0.1 and 0.75 mg, respectively, which are less than those of the mixed powder cladding layer (0.12 and 0.8 mg). Moreover, the alloyed powder cladding layer is much friendlier to its counterpart. The counterpart’s loss weight of the alloyed powder cladding layer decreases 42.2% than the mixed powder cladding layer. The reason can be attributed to the homogeneous distribution of fine in situ-formed Cr7C3 in the alloyed powder cladding materials, which can effectively separate the friction pair, improving the wear resistance of the cladding materials.
Magnetic Properties of FeNiCoAlTiNb Shape Memory Alloys
Authors: Tsai Chau-Yi , Tseng Li-Wei , Tzeng Yu-Chih , Lee Po-Yu
Published: January 2022

The magnetic properties of the new Fe41Ni28Co17Al11.5(Ti+Nb)2.5 (at. %) shape memory alloy system were studied in this work. The magnetic properties were characterized by thermo-magnetization and a vibrating sample magnetometer (VSM). In iron-based shape memory alloys, aging heat treatment is crucial for obtaining the properties of superelasticity and shape memory. In this study, we focus on the magnetization, martensitic transformation temperatures, and microstructure of this alloy during the aging process at 600 °C. From the X-ray diffraction (XRD) results, the new peak γ’ is presented during the aging process. The intensity of this new peak (γ’) increases with the aging time, while the intensity of the FCC (111) austenite peak decreases with aging time. Transmission electron microscope (TEM) results show that the size of the precipitate increases with increasing the aging times from 24 to 72 h. Thermo-magnetization results show that: (1) phase transformation is observed when the aging time is at least 24 h, (2) the transformation temperature increases with the aging time, (3) transformation temperatures tend to increase while the magnetic field increases from 0.05 to 7 Tesla, and (4) the magnetization saturates after aging time reaches 24 h. Vibrating sample magnetometer (VSM) results show that thermal process was found to significantly affect the magnetic properties of this alloy, especially on saturated magnetic magnetization and magnetic moment reversal behavior.
The Chemical Composition of Trapiche-like Quartz from Huanggangliang Area, Inner Mongolia, China
Authors: Jiang Ling , Chen Zhu , Liu Yingxin
Published: January 2022

Trapiche-like quartz, which is found in Huanggangliang area, Chifeng City, Inner Mongolia, China, has a short columnar euhedral shape. Arms of trapiche-like phenomena are formed by six radial dark bands located along the a-axis of crystals, and their cores are formed by color zones. Various methods were used to investigate the conventional gemological characteristics, trapiche pattern features, chemical compositions, and spectral characteristics of the trapiche-like quartz. CL images and EPMA results reveal they were formed at high temperature conditions and originated from pegmatite. The hexagonal darker zones with high FeO and very little TiO2 contents indicate the trapiche-like patterns are due to spatial distribution of color-inducing elements. According to the position and interpenetration relationship between inclusions, fibrous and spherical inclusions are identified as protogenetic inclusions, which were respectively identified to be ferro-actinolite and iron oxide by EPMA and Raman spectra.
Crystal Structure and Theoretical Analysis of Cs2Ca3(SO4)4
Authors: Fang Penglin , Tang Wenyue , Shen Yaoguo , Hong Jinquan , Li Yongming , Jia Junrong
Published: January 2022

Using the homovalent cation substitution strategy, a new sulfate, Cs2Ca3(SO4)4, was successfully prepared using the spontaneous crystallization technique. A single-crystal structure measurement suggested that it crystallizes in space group P21/c, with lattice parameters and molecules per unit cell of a = 9.9153(8), b = 9.3760(6), c = 9.8044(9), β = 118.365(3)°, V = 802.04(11), and Z = 2. In the structure of Cs2Ca3(SO4)4, CaO6 octahedra and SO4 tetrahedra are interconnected via a corner-sharing mode to form a three-dimensional framework comprising large cavities filled with Cs+ cations. First-principles calculations and diffuse reflectance spectra indicated that Cs2Ca3(SO4)4 has a large energy band gap. Moreover, structural comparisons with similar compounds were conducted to explain the role of cations in tuning structural symmetry and birefringence. This paper helps to explain the size effect of cations on structural evolution.
The Evaluation of the Four-Chamber Cardiac Dissection Method of the Fetal Heart as an Alternative to Conventional Inflow–Outflow Dissection in Small Gestational-Age Fetuses
Authors: Albu Camelia , Staicu Adelina , Popa-Stanilă Roxana , Bondor Cosmina , Pop Bogdan , Chiriac Liviu , Gheban Dan , Micu Romeo , Turcu Romulus Valeriu Flaviu , Simon Simion , Crișan Doinița , Stamatian Florin
Published: January 2022

The examination of very small fetal hearts requires special equipment and a specialist that are not available in many general pathology laboratories. Compared to conventional examination, the four-chamber cardiac dissection (4CCD) method can be performed by any pathologist using instruments generally available in pathology services. The aim of this study is to evaluate the efficiency of the 4CCD method in the examination of small fetal hearts using post-mortem magnetic resonance imaging (pm-MRI) at 7T as the standard. Twelve fetuses with gestational ages between 13 and 19 weeks have been included in this study. All fetuses underwent pm-MRI examination prior to pathologic examination. The 4CCD method was used for the cardiac examination in all cases following the same guidelines for cardiac sectioning. The 4CCD was able to identify all cardiac anatomic structures as compared to pm-MRI at 7T, demonstrating a sensibility of 95.8% (95% CI, 94.5–95.8) and specificity of 100% (95% CI, 32.3–100). The overall accuracy in identifying cardiac anatomic structures was 95.8% (95% CI, 93.4–95.8). Additionally, the 4CCD method was able to detect cardiac anomalies with an overall diagnostic accuracy of 91% (95% CI, 85.8–94.2), sensibility of 67.6% (95% CI, 54.5–75.3), and specificity of 97% (95% CI, 93.7–99) as compared to pm-MRI at 7T. The four-chamber view dissection method can be considered as an alternative to the conventional inflow–outflow dissection method in selected cases.
PSMA-Positive Low Malignant Gastrointestinal Stromal Tumor in the Stomach on F-18-PSMA-1007 PET/CT
Authors: Iversen Peter , Hansen Allan Kjeldsen , Hubeck-Graudal Thorbjørn , Medrud Lise , Bouchelouche Kirsten
Published: January 2022

A 76-year-old man with newly diagnosed high-risk prostate cancer was referred for primary staging with F-18-PSMA-1007 PET/CT. The PET/CT scan showed no lymph node or bone metastases, only localized disease within the prostate gland. Additionally, the F-18-PSMA PET/CT scan showed a PSMA-positive lesion correlating to a polyp located in the body of the stomach on the greater curvature. A prior F-18-FDG PET/CT showed low FDG uptake in the polyp, but this was not reported initially in the written report. The patient had no upper gastrointestinal symptoms. A gastroscopy with biopsies was performed, and the histopathology results showed chronic unspecific inflammation with no granulomas, dysplastic or malignant changes in three out of three biopsies. A repeated gastroscopy with biopsy showed an epithelioid variant of a gastrointestinal stromal tumor (Ki-67 index 2%). A laparoscopic tumor extirpation was planned after radiation treatment in combination with endocrine therapy of the localized prostate cancer. To our knowledge, this is one of very few reported cases of a PSMA-positive gastrointestinal stromal tumor (GIST), and can be added to the list of malignant pitfalls of PSMA PET/CT in prostate cancer patients.
Elevated Lipoprotein(a) Level Influences Familial Hypercholesterolemia Diagnosis
Authors: Chubykina Uliana V. , Ezhov Marat V. , Afanasieva Olga I. , Klesareva Elena A. , Pokrovsky Sergei N.
Published: January 2022

Familial hypercholesterolemia (FH) and elevated lipoprotein(a) [Lp(a)] level are the most common inherited disorders of lipid metabolism. This study evaluated the impact of high Lp(a) level on accuracy Dutch Lipid Clinic Network (DLCN) criteria of heterozygous FH diagnosis. A group of 206 individuals not receiving lipid-lowering medication with low-density lipoprotein cholesterol (LDL-C) >4.9 mmol/L was chosen from the Russian FH Registry. LDL-C corrected for Lp(a)-cholesterol was calculated as LDL-C − 0.3 × Lp(a). DLCN criteria were applied before and after adjusting LDL-C concentration. Of the 206 patients with potential FH, a total of 34 subjects (17%) were reclassified to less severe FH diagnosis, 13 subjects of them (6%) were reclassified to “unlike” FH. In accordance with Receiver Operating Characteristic curve, Lp(a) level ≥40 mg/dL was associated with FH re-diagnosing with sensitivity of 63% and specificity of 78% (area under curve = 0.7, 95% CI 0.7–0.8, p < 0.001). The reclassification was mainly observed in FH patients with Lp(a) level above 40 mg/dL, i.e., 33 (51%) with reclassified DLCN criteria points and 22 (34%) with reclassified diagnosis, compared with 21 (15%) and 15 (11%), respectively, in patients with Lp(a) level less than 40 mg/dL. Thus, LDL-C corrected for Lp(a)-cholesterol should be considered in all FH patients with Lp(a) level above 40 mg/dL for recalculating points in accordance with DLCN criteria.
Quantum Switchboard with Coupled-Cavity Array
Authors: Mok Wai-Keong , Kwek Leong-Chuan
Published: January 2022

The ability to control the flow of quantum information is deterministically useful for scaling up quantum computation. In this paper, we demonstrate a controllable quantum switchboard which directs the teleportation protocol to one of two targets, fully dependent on the sender’s choice. Importantly, the quantum switchboard also acts as a optimal quantum cloning machine, which allows the receivers to recover the unknown quantum state with a maximal fidelity of 56. This protects the system from the complete loss of quantum information in the event that the teleportation protocol fails. We also provide an experimentally feasible physical implementation of the proposal using a coupled-cavity array. The proposed switchboard can be utilized for the efficient routing of quantum information in a large quantum network.
Modelling of the Electrical Membrane Potential for Concentration Polarization Conditions
Authors: Batko Kornelia M. , Ślęzak-Prochazka Izabella , Ślęzak Andrzej , Bajdur Wioletta M. , Ščurek Radomir
Published: January 2022

Based on Kedem–Katchalsky formalism, the model equation of the membrane potential (Δψs) generated in a membrane system was derived for the conditions of concentration polarization. In this system, a horizontally oriented electro-neutral biomembrane separates solutions of the same electrolytes at different concentrations. The consequence of concentration polarization is the creation, on both sides of the membrane, of concentration boundary layers. The basic equation of this model includes the unknown ratio of solution concentrations (Ci/Ce) at the membrane/concentration boundary layers. We present the calculation procedure (Ci/Ce) based on novel equations derived in the paper containing the transport parameters of the membrane (Lp, σ, and ω), solutions (ρ, ν), concentration boundary layer thicknesses (δl, δh), concentration Raileigh number (RC), concentration polarization factor (ζs), volume flux (Jv), mechanical pressure difference (ΔP), and ratio of known solution concentrations (Ch/Cl). From the resulting equation, Δψs was calculated for various combinations of the solution concentration ratio (Ch/Cl), the Rayleigh concentration number (RC), the concentration polarization coefficient (ζs), and the hydrostatic pressure difference (ΔP). Calculations were performed for a case where an aqueous NaCl solution with a fixed concentration of 1 mol m−3 (Cl) was on one side of the membrane and on the other side an aqueous NaCl solution with a concentration between 1 and 15 mol m−3 (Ch). It is shown that (Δψs) depends on the value of one of the factors (i.e., ΔP, Ch/Cl, RC and ζs) at a fixed value of the other three.
Boltzmann Configurational Entropy Revisited in the Framework of Generalized Statistical Mechanics
Authors: Scarfone Antonio Maria
Published: January 2022

As known, a method to introduce non-conventional statistics may be realized by modifying the number of possible combinations to put particles in a collection of single-particle states. In this paper, we assume that the weight factor of the possible configurations of a system of interacting particles can be obtained by generalizing opportunely the combinatorics, according to a certain analytical function f{π}(n) of the actual number of particles present in every energy level. Following this approach, the configurational Boltzmann entropy is revisited in a very general manner starting from a continuous deformation of the multinomial coefficients depending on a set of deformation parameters {π}. It is shown that, when f{π}(n) is related to the solutions of a simple linear difference–differential equation, the emerging entropy is a scaled version, in the occupational number representation, of the entropy of degree (κ,r) known, in the framework of the information theory, as Sharma–Taneja–Mittal entropic form.
Social Connectedness in Physical Isolation: Online Teaching Practices That Support Under-Represented Undergraduate Students’ Feelings of Belonging and Engagement in STEM
Authors: Thacker Ian , Seyranian Viviane , Madva Alex , Duong Nicole T. , Beardsley Paul
Published: January 2022

The COVID-19 outbreak spurred unplanned closures and transitions to online classes. Physical environments that once fostered social interaction and community were rendered inactive. We conducted interviews and administered surveys to examine undergraduate STEM students’ feelings of belonging and engagement while in physical isolation, and identified online teaching modes associated with these feelings. Surveys from a racially diverse group of 43 undergraduate students at a Hispanic Serving Institution (HSI) revealed that interactive synchronous instruction was positively associated with feelings of interest and belonging, particularly for students of color, while noninteractive instruction reduced social belonging, but was related to more cognitive engagement. Small group and one-on-one interviews with 23 of these students suggest that students derived feelings of connectedness from their instructors, peers, and prior experiences and relied on their sense of competency to motivate themselves in the course and feel a sense of belonging. Two embedded cases of students in physics classrooms are compared to highlight the range of student feelings of connectedness and competency during the lockdown. Findings reaffirm that social interaction tends to support belonging and engagement, particularly for under-represented (Black or African American and Hispanic) racial groups in STEM. STEM instructors who aim to support feelings of belonging and engagement in virtual learning environments should consider increasing opportunities for student–student and student–teacher interactions, as well as taking a flexible approach that validates and integrates student voice into instruction. Future research is needed to further explore the themes of relatedness and competency that emerged as aspects of course belonging.
An Empirical Study of Mobile Commerce and Customers Security Perception in Saudi Arabia
Authors: Gull Hina , Saeed Saqib , Iqbal Sardar Zafar , Bamarouf Yasser A. , Alqahtani Mohammed A. , Alabbad Dina A. , Saqib Madeeha , Al Qahtani Saeed Hussein , Alamer Albandary
Published: January 2022

Digital transformation of businesses has seen tremendous growth recently, moreover, COVID-19 has increased online shopping. However, it is important for businesses that customers’ online shopping experience is secure and joyful. In this paper, customers’ security perception regarding some leading mobile commerce applications in Saudi Arabia is explored. Our survey questions focused on three aspects, namely: Consumer rating, trustworthiness, and credit card security. The results highlight that consumers perceive that mobile commerce applications in Saudi Arabia need further improvement in security. In this work, a model to improve customers’ security perception in Saudi Arabia is presented. This model can be generalized to other geographical regions as well. The model outlines different actions for practitioners and policymakers that help in improving security infrastructure, authentication mechanisms, and trustworthiness.
A Path Planning Method for Underground Intelligent Vehicles Based on an Improved RRT* Algorithm
Authors: Wang Hao , Li Guoqing , Hou Jie , Chen Lianyun , Hu Nailian
Published: January 2022

Path planning is one of the key technologies for unmanned driving of underground intelligent vehicles. Due to the complexity of the drift environment and the vehicle structure, some improvements should be made to adapt to underground mining conditions. This paper proposes a path planning method based on an improved RRT* (Rapidly-Exploring Random Tree Star) algorithm for solving the problem of path planning for underground intelligent vehicles based on articulated structure and drift environment conditions. The kinematics of underground intelligent vehicles are realized by vectorized map and dynamic constraints. The RRT* algorithm is selected for improvement, including dynamic step size, steering angle constraints, and optimal tree reconnection. The simulation case study proves the effectiveness of the algorithm, with a lower path length, lower node count, and 100% steering angle efficiency.
Prototype Verification of Self-Interference Suppression for Constant-Amplitude Full-Duplex Phased Array with Finite Phase Shift
Authors: Zhang Jie , Zheng Jiudong
Published: January 2022

In view of the strong self-interference problem when the practical phased array system is simultaneously applied for transmission and reception, under the constraints including limited quantization number, constant envelope amplitude, scanning mode, wideband signal mode, etc., this work studies it and proposes the amplitude-phase joint adjustment method and the phase-only method for beamforming optimization. Through digital simulation design, electromagnetic simulation evaluation and principle test verification, under the actual array system conditions, including 6-bit phase quantization or phase step size of 5.625° and amplitude 0.5 dB quantization step, when the transmitting beam is pointing (0°, 0°), the research has achieved a performance of 11.9~14.4 dB for self-interference suppression; at the same time, the optimized beam shape is maintained well, and the ratio of the main lobe to the side lobes does not change significantly, but the beam gain has a loss of about 2~3 dB. In addition, we studied the interference suppression performance and beam feature retention performance of the optimized beamforming weights in the case of array scanning and broadband signals, and analyzed the influence of the changes in the mutual coupling characteristics between elements caused by scanning and frequency changes on the cancellation performance. This provides a reference for the application research of the simultaneous transmitting and receiving self-interference suppression technology in the actual array system state.
Review of Carnot Battery Technology Commercial Development
Authors: Novotny Vaclav , Basta Vit , Smola Petr , Spale Jan
Published: January 2022

Carnot batteries are a quickly developing group of technologies for medium and long duration electricity storage. It covers a large range of concepts which share processes of a conversion of power to heat, thermal energy storage (i.e., storing thermal exergy) and in times of need conversion of the heat back to (electric) power. Even though these systems were already proposed in the 19th century, it is only in the recent years that this field experiences a rapid development, which is associated mostly with the increasing penetration of intermittent cheap renewables in power grids and the requirement of electricity storage in unprecedented capacities. Compared to the more established storage options, such as pumped hydro and electrochemical batteries, the efficiency is generally much lower, but the low cost of thermal energy storage in large scale and long lifespans comparable with thermal power plants make this technology especially feasible for storing surpluses of cheap renewable electricity over typically dozens of hours and up to days. Within the increasingly extensive scientific research of the Carnot Battery technologies, commercial development plays the major role in technology implementation. This review addresses the gap between academia and industry in the mapping of the technologies under commercial development and puts them in the perspective of related scientific works. Technologies ranging from kW to hundreds of MW scale are at various levels of development. Some are still in the stage of concepts, whilst others are in the experimental and pilot operations, up to a few commercial installations. As a comprehensive technology review, this paper addresses the needs of both academics and industry practitioners.
Designing the Business Ecosystem of a Decentralised Energy Datahub
Authors: Küfeoğlu Sinan , Açıkgöz Eray , Taşcı Yunus Emre , Arslan Taha Yasin , Priesmann Jan , Praktiknjo Aaron
Published: January 2022

Datahubs step forth as convenient test beds for innovative solutions to create value from the energy data. There are numerous pilots and early trials for establishing energy Datahubs, especially in northern Europe. These are all centralised models, and the centralisation of data control and value creation can be regarded as contradictory to the decentralisation trend in the energy sector. This paper attempts to design the first decentralised energy Datahub ecosystem’s business ecosystem, with the name DenHub, using Blockchain technology. This model enables easy access to transparent and flexible energy data and new business models that will emerge upon its use. All data produced, distributed, used, and curated will help researchers and entrepreneurs study this field and propose new business models to make the energy ecosystem more efficient, clean, and inclusive. The paper also presents the differences between centralised and decentralised methods by underlining the advantages and disadvantages of both approaches.
The Comparison of Microwave Reflectance of Graphite and Reduced Graphene Oxide Used for Electronic Devices Protection
Authors: Kubacki Roman , Lipińska Ludwika , Przesmycki Rafał , Laskowski Dariusz
Published: January 2022

This work presents the investigation of graphite and reduced graphene oxide (RGO) reflectance as an important parameter for electronic devices’ protection. These materials should protect electronic circuits against external as well as internal reflected radiation. The investigation was focused on comparing the reflectance of both materials on the metal layers. The measurements of constant electromagnetic parameters, such as permittivity and permeability, were carried out on pure materials without any additives, such as polystyrene foam, resin, wax, etc. The measurements were implemented in a coaxial line within the microwave frequency range from 100 MHz to 10 GHz. The measurements show a high value of reflected power, over 90% for graphite while RGO reflects only 80% of incident power. In addition, due to the half-wavelength effect in reduced graphene oxide, the reflection coefficient is reduced to 70%.
Effects of Cofiring Coal and Biomass Fuel on the Pulverized Coal Injection Combustion Zone in Blast Furnaces
Authors: Kim Gyeong-Min , Choi Jae Hyung , Jeon Chung-Hwan , Lim Dong-Ha
Published: January 2022

CO2 emissions are a major contributor to global warming. Biomass combustion is one approach to tackling this issue. Biomass is used with coal combustion in thermal power plants or with blast furnaces (BFs) because it is a carbon-neutral fuel; therefore, biomass provides the advantage of reduced CO2 emissions. To examine the effect of co-firing on pulverized coal injection (PCI) in BFs, two coals of different ranks were blended with the biomass in different proportions, and then their combustion behaviors were examined using a laminar flow reactor (LFR). The PCI combustion primarily functions as a source of heat and CO to supply the upper part of the BF. To create a similar PCI combustion environment, the LFR burner forms a diffusion flat flame with an oxygen concentration of 26% with a flame temperature of ~2000–2250 K at a heating rate of 105 K/s. The combustion characteristics, such as the flame structure, burning coal particle temperature, unburned carbon (UBC), and CO and CO2 emissions were measured to evaluate their effect on PCI combustion. With the increase in the biomass blending ratio, the brightness of the volatile cloud significantly increased, and the particle temperature tended to decrease. The fragmentation phenomenon, which was observed for certain coal samples, decreased with the increase in the biomass blending ratio. In particular, with an increase in the biomass blending ratio, the optimum combustion point occurred, caused by the fragmentation of coal and volatile gas combustion of biomass.
Prediction of Oil Recovery Factor in Stratified Reservoirs after Immiscible Water-Alternating Gas Injection Based on PSO-, GSA-, GWO-, and GA-LSSVM
Authors: Andersen Pål Østebø , Nygård Jan Inge , Kengessova Aizhan
Published: January 2022

In this study, we solve the challenge of predicting oil recovery factor (RF) in layered heterogeneous reservoirs after 1.5 pore volumes of water-, gas- or water-alternating-gas (WAG) injection. A dataset of ~2500 reservoir simulations is analyzed based on a Black Oil 2D Model with different combinations of reservoir heterogeneity, WAG hysteresis, gravity influence, mobility ratios and WAG ratios. In the first model MOD1, RF is correlated with one input (an effective WAG mobility ratio M*). Good correlation (Pearson coefficient −0.94), but with scatter, motivated a second model MOD2 using eight input parameters: water–oil and gas–oil mobility ratios, water–oil and gas–oil gravity numbers, a reservoir heterogeneity factor, two hysteresis parameters and water fraction. The two mobility ratios exhibited the strongest correlation with RF (Pearson coefficient −0.57 for gas-oil and −0.48 for water-oil). LSSVM was applied in MOD2 and trained using different optimizers: PSO, GA, GWO and GSA. A physics-based adaptation of the dataset was proposed to properly handle the single-phase injection. A total of 70% of the data was used for training, 15% for validation and 15% for testing. GWO and PSO optimized the model equally well (R2 = 0.9965 on the validation set), slightly better than GA and GSA (R2 = 0.9963). The performance metrics for MOD1 in the total dataset were: RMSE = 0.050 and R2 = 0.889; MOD2: RMSE = 0.0080 and R2 = 0.998. WAG outperformed single-phase injection, in some cases with 0.3 units higher RF. The benefits of WAG increased with stronger hysteresis. The LSSVM model could be trained to be less dependent on hysteresis and the non-injected phase during single-phase injection.
Different Fuzzy Control Configurations Tuned by the Bees Algorithm for LFC of Two-Area Power System
Authors: Shouran Mokhtar , Anayi Fatih , Packianather Michael , Habil Monier
Published: January 2022

This study develops and implements a design of the Fuzzy Proportional Integral Derivative with filtered derivative mode (Fuzzy PIDF) for Load Frequency Control (LFC) of a two-area interconnected power system. To attain the optimal values of the proposed structure’s parameters which guarantee the best possible performance, the Bees Algorithm (BA) and other optimisation tools are used to accomplish this task. A Step Load Perturbation (SLP) of 0.2 pu is applied in area one to examine the dynamic performance of the system with the proposed controller employed as the LFC system. The supremacy of Fuzzy PIDF is proven by comparing the results with those of previous studies for the same power system. As the designed controller is required to provide reliable performance, this study is further extended to propose three different fuzzy control configurations that offer higher reliability, namely Fuzzy Cascade PI − PD, Fuzzy PI plus Fuzzy PD, and Fuzzy (PI + PD), optimized by the BA for the LFC for the same dual-area power system. Moreover, an extensive examination of the robustness of these structures towards the parametric uncertainties of the investigated power system, considering thirteen cases, is carried out. The simulation results indicate that the contribution of the BA tuned the proposed fuzzy control structures in alleviating the overshoot, undershoot, and the settling time of the frequency in both areas and the tie-line power oscillations. Based on the obtained results, it is revealed that the lowest drop of the frequency in area one is −0.0414 Hz, which is achieved by the proposed Fuzzy PIDF tuned by the BA. It is also divulged that the proposed techniques, as was evidenced by their performance, offer a good transient response, a considerable capability for disturbance rejection, and an insensitivity towards the parametric uncertainty of the controlled system.
Development of Photovoltaic Energy in EU Countries as an Alternative to Fossil Fuels
Authors: Wolniak Radosław , Skotnicka-Zasadzień Bożena
Published: January 2022

The aim of the article is to present the development of photovoltaic energy in the EU countries as one of the alternatives to fossil fuels. The article was prepared on the basis of secondary information and statistical data on the photovoltaic energy market in EU countries, and three hypotheses were formulated: H1—There is a statistically significant correlation between a country’s long-term orientation and its use of photovoltaic energy in European Union countries; H2—There is a statistically significant correlation between GDP per capita and photovoltaic energy use in European Union countries; and H3—There is a relationship between climate and photovoltaic energy use in European Union countries. Correlation coefficients and the Guilford classification were used to analyse the data. Data analysis has shown that photovoltaic energy is the second fastest-growing energy source in the EU, after wind energy. In 2020, 134 TWh of solar energy was produced in the EU countries. Based on the analysis, it can be concluded that there is a statistically significant correlation between the production of photovoltaic energy per person and the level of GDP per capita in the EU countries (Hypothesis 2). Germany and the Netherlands produce the most solar energy. The studies did not confirm Hypothesis 3; however, it can be seen that countries such as Germany, Belgium and the Netherlands have the highest PV energy efficiency compared to average temperature values. A data analysis showed statistically significant correlations between the country’s long-term orientation in the use of photovoltaic energy (Hypothesis 1). In the case of Germany and Belgium, the long-term orientation indicator is very high above 80, while Portugal, Poland and Finland have the lowest indicator, from 30 to 40.
An Analysis-Supported Design of a Single Active Bridge (SAB) Converter
Authors: Jha Rupesh , Forato Mattia , Prakash Satya , Dashora Hemant , Buja Giuseppe
Published: January 2022

Currently, due to its various applications, the high-performance isolated dc-dc converter is in demand. In applications where unidirectional power transfer is required, the single active bridge (SAB) is the most suitable one due to its simplicity and ease of control. The general schematic of the SAB converter consists of an active bridge and a passive bridge, which are connected through a high-frequency transformer thus isolated. The paper summarizes the behavior of this converter in its three operation modes, namely the continuous, discontinuous, and boundary modes. Later, the features of this converter, such as its input-to-output and external characteristics are discussed. Input-to-output characteristics include the variation of converter output power, voltage, and current with an input control variable i.e., phase-shift angle, whereas the external characteristic is the variation of the output voltage as a function of output current. In this discussion, the behavior of this converter in its extreme operating conditions is also examined. The features of the characteristics are elucidated with the help of suitable plots obtained in the MATLAB environment. Afterward, the specifications of a SAB converter are given and, based on the results of the analysis, a detailed design of its electrical elements is carried out. To validate the features and the design procedures presented in this paper, a prototype is developed. An element-wise loss estimation is also carried out and the efficiency of the converter has been found to be approximately equal to 93%. Lastly, the test was executed on this prototype, confirming the theoretical findings concerning this converter.
Elliptical-Shaped Fresnel Lens Design through Gaussian Source Distribution
Authors: Garcia Dário , Liang Dawei , Almeida Joana , Tibúrcio Bruno D. , Costa Hugo , Catela Miguel , Vistas Cláudia R.
Published: January 2022

A novel three-dimensional elliptical-shaped Fresnel lens (ESFL) analytical model is presented to evaluate and maximize the solar energy concentration of Fresnel-lens-based solar concentrators. AutoCAD, Zemax and Ansys software were used for the ESFL design, performance evaluation and temperature calculation, respectively. Contrary to the previous modeling processes, based on the edge-ray principle with an acceptance half-angle of ±0.27° as the key defining parameter, the present model uses, instead, a Gaussian distribution to define the solar source in Zemax. The results were validated through the numerical analysis of published experimental data from a flat Fresnel lens. An in-depth study of the influence of several ESFL factors, such as focal length, arch height and aspect ratio, on its output performance is carried out. Moreover, the evaluation of the ESFL output performance as a function of the number/size of the grooves is also analyzed. Compared to the typical 1–16 grooves per millimeter reported in the previous literature, this mathematical parametric modeling allowed a substantial reduction in grooves/mm to 0.3–0.4, which may enable an easy mass production of ESFL. The concentrated solar distribution of the optimal ESFL configuration was then compared to that of the best flat Fresnel lens configuration, under the same focusing conditions. Due to the elliptical shape of the lens, the chromatic aberration effect was largely reduced, resulting in higher concentrated solar flux and temperature. Over 2360 K and 1360 K maximum temperatures were found for ESFL and flat Fresnel lenses, respectively, demonstrating the great potential of the three-dimensional curved-shaped Fresnel lens on renewable solar energy applications that require high concentrations of solar fluxes and temperatures.
An Improved Charge-Based Method Extended to Estimating Appropriate Dead Time for Zero-Voltage-Switching Analysis in Dual-Active-Bridge Converter
Authors: Zhang Haoyu , Isobe Takanori
Published: January 2022

This paper presents a comprehensive analysis of zero-voltage-switching (ZVS) realization with an improved charge-based method by considering both voltage dependency parasitic capacitance and dead time in dual-active-bridge (DAB) converters, when the voltage ratio between the primary and secondary sides does not match the turn ratio of the transformer. For this purpose, a unified equivalent circuit is proposed to represent the switching motions at all possible switching instances under the condition of one-leg manipulation. The combinations of switching cases can be presented in a table to build the corresponding equivalent circuit for ZVS analysis. Combined with the improved charge-based method, the common solutions of the minimum required switching current and the appropriate dead-time range for each equivalent circuit to realize ZVS are deduced. The allowable range of the dead time for ZVS as a function of the switching current is analyzed to determine the appropriate dead time. Once the switching current and dead-time range are derived, the model-based lowest switching current control method can be used to achieve ZVS by using the appropriate amount of both factors. Experiments using a 4 kW DAB prototype were conducted to verify the theoretical analyses.
Forest Products and Circular Economy Strategies: A Canadian Perspective
Authors: Gagnon Bruno , Tanguay Xavier , Amor Ben , Imbrogno Anthony F.
Published: January 2022

The Government of Canada has embraced circular economy and is supporting an increasing number of initiatives in the field. However, implementation examples remain scattered and certain stakeholders are eager to see a greater level of commitment from policy makers. The purpose of this study is to provide a Canadian perspective on how, and to what extent, forest products are compatible with circular economy strategies. This topic was investigated through interviews with 16 Canadian experts in eco-design, circular economy, forest products and/or waste management, with a focus on construction and packaging. Efforts made by forest industries at the manufacturing stage to reduce resource consumption were acknowledged, but the implementation of other circular economy strategies, such as reuse, recycling and energy recovery, is uneven. While there is low-hanging fruit for incremental improvements, such as the processing of recovered lumber in wood panels and not mixing cardboard fibres with other paper streams to avoid downcycling, several barriers to the widespread adoption of the most promising strategies were identified. The experts consulted proposed several solutions to accelerate the deployment of circular economy strategies for forest products, for which government interventions would need to be tailored to the different policy readiness levels (PRLs) observed in the construction and packaging sectors. With circularity having economy-wide implications, setting a clear policy direction at the national level, with a circular economy roadmap for Canada for example, could accelerate coordinated implementation within and across sectors, including forest industries.