Combining Visible/Infrared Spectroscopy and Transmission-Electron-Microscopy To Investigate Space-Weathering Induced Changes In Hydrated Silicates
Authors: Rubino Stefano , Lantz Cateline , Aléon-Toppani Alice , Baklouti Donia , Djouadi Zahia , Troadec David , Palomba Ernesto , Borondics Ferenc , Leroux Hugues , Brunetto Rosario 
Published: February 2023

The study of small bodies in our solar system is fundamental for understanding its youth and evolution. These "primitive" bodies are "undifferentiated" (their components did not separate according to their density, irreversibly altering their mineralogy). They have evolved very little since their birth, spurring a composition relatively close to that of the primordial proto-planetary disk (Scott et al. 2018). However, other processes such as thermal alteration, aqueous alteration, shocks, or space weathering can affect these bodies&#8217; surfaces. This may introduce certain compositional biases in remote-sensed data focusing on the surface of these bodies. Therefore, it is paramount to understand the processes affecting the surface of primitive asteroids to correctly assess their composition.There are several ways to study the surface of primitive asteroids, such as remotely, by acquiring spectroscopic data (gaining access to surface chemical and mineralogical composition). It is also possible to study these bodies in a laboratory environment, by working on analogous materials such as certain classes of "primitive" meteorites (Greenwood et al. 2020) (carbonaceous chondrites), on terrestrial analogues such as hydrated silicates - which dominates the mineral composition of &#8220;primitive&#8221; bodies (Usui et al. 2018), or directly on extra-terrestrial materials brought back by sample return missions (Yokoyama et al. 2022, Nakalura et al. 2022, Noguchi et al. 2022).In this work, we replicate in a laboratory environment the effects of space weathering (SpWe) on the surface of primitive asteroids. We focus on the effects of solar wind, the dominant SpWe process on "young" surfaces (Brunetto et al. 2015, Clark et al. 2002). We have chosen three terrestrial minerals analogous to a "primitive" surface - three hydrated minerals (two serpentines and one saponite) - of which we have produced several pellets which have been bombarded using He and Ar ions. In doing so, we made analogous materials of weathered primitive surface matter. These analogues were then characterized by infrared spectroscopy, from the visible to the far-infrared range, to study chemical changes prompted by ion bombardment. This was done by investigating how certain spectroscopic features &#8211; characteristic of hydrated silicates &#8211; changed upon ion-bombardment. We detected several effects, such as darkening in the visible range, visible slope reddening and bluing as well as a systematic shift towards longer wavelength affecting the position of several spectroscopic features.This was followed by a study at a smaller scale, using electron microscopy. We first characterized the surface of our weathered analogues using scanning electron microscopy, and then investigated the morphological and physicochemical changes taking place in the bombarded layer, at a nanometre scale, using transmission electron microscopy. Strong vesiculation effects of various kinds were identified in the ion bombarded amorphized layers, as well as textural changes and some elemental concentration evolution (such as the loss of oxygen in the utmost top surfaces, preferential amorphization of magnesium, etc.).The coupling between these two techniques, Vis/IR spectroscopy and electron microscopy, has allowed us to start probing the relations between SpWe induced effects seen at different scales.