bluuebunny/crossref_metadata_2025 huggingface dataset:
Microgel Modified UV-Cured Methacrylic-Silica Hybrid: Synthesis and Characterization
Authors: Corcione Carola , Striani Raffaella , Frigione Mariaenrica
Published: September 2013

An innovative photopolymerizable microgel modified UV-cured acrylic-silica hybrid formulation was developed and characterized for possible use as protective coating for different substrates. A deep investigation, aiming at providing a strong scientific basis for the production of organic-inorganic (O-I) hybrids exhibiting phase co-continuity, was firstly carried out. The O-I hybrid first proposed in this study was obtained from organic precursors with a high siloxane content, which are mixed with tetraethoxysilane (TEOS) in such a way to produce co-continuous silica nanodomains dispersed within the crosslinked organic phase, as a result of the sol-gel process. The first part of the research deals with the selection and optimization of suitable systems through appropriate chemical modifications, in order to ensure that curing reactions can be carried out at room temperature and in the presence of UV radiation. Firstly, the silica domains are formed, followed by crosslinking reactions of the acrylic groups in the oligomer via a free radical polymerization. The crosslinking reaction was controlled with the use of a suitable photoinitiator. Most of the experimental work was devoted to understanding the morphology of the hybrid system, both in uncured and cured states, and to assess its final thermal and optical properties, using different experiential techniques.
Dopamine-Mediated Sclerotization of Regenerated Chitin in Ionic Liquid
Authors: Oh Dongyeop , Shin Sara , Lim Chanoong , Hwang Dong
Published: September 2013

Chitin is a promising structural material for biomedical applications, due to its many advantageous properties and abundance in nature. However, its usage and development in the biomedical field have been stagnant, because of chitin’s poor mechanical properties in wet conditions and the difficulties in transforming it into an applicable form. To overcome these challenges, we created a novel biomimetic chitin composite. This regenerated chitin, prepared with ionic liquid, showed improved mechanical properties in wet conditions by mimicking insect cuticle and squid beak sclerotization, i.e., catechol-meditated cross-linking. By ionic liquid-based heat treatment, dopamine oxidation produced melanin-like compounds and dopamine-meditated cross-links without any solvent evaporation and oxidant utilization. The dopamine-meditated sclerotization increased the ultimate tensile strength (UTS) of the regenerated chitin by 2.52-fold, measured after six weeks of phosphate-buffered saline (PBS) submersion. In addition, the linear swelling ratio (LSR) of the chitin film was reduced by about 22%. This strategy raises a possibility of using regenerated chitin as an artificial hard tissue in wet conditions.
Cephalopods as Vectors of Harmful Algal Bloom Toxins in Marine Food Webs
Authors: Lopes Vanessa , Lopes Ana , Costa Pedro , Rosa Rui
Published: September 2013

Here we summarize the current knowledge on the transfer and accumulation of harmful algal bloom (HAB)-related toxins in cephalopods (octopods, cuttlefishes and squids). These mollusks have been reported to accumulate several HAB-toxins, namely domoic acid (DA, and its isomers), saxitoxin (and its derivatives) and palytoxin (and palytoxin-like compounds) and, therefore, act as HAB-toxin vectors in marine food webs. Coastal octopods and cuttlefishes store considerably high levels of DA (amnesic shellfish toxin) in several tissues, but mainly in the digestive gland (DG)—the primary site of digestive absorption and intracellular digestion. Studies on the sub-cellular partitioning of DA in the soluble and insoluble fractions showed that nearly all DA (92.6%) is found in the cytosol. This favors the trophic transfer of the toxins since cytosolic substances can be absorbed by predators with greater efficiency. The available information on the accumulation and tissue distribution of DA in squids (e.g., in stranded Humboldt squids, Dosidicus gigas) is scarcer than in other cephalopod groups. Regarding paralytic shellfish toxins (PSTs), these organisms accumulate them at the greatest extent in DG >> kidneys > stomach > branchial hearts > posterior salivary glands > gills. Palytoxins are among the most toxic molecules identified and stranded octopods revealed high contamination levels, with ovatoxin (a palytoxin analogue) reaching 971 μg kg−1 and palytoxin reaching 115 μg kg−1 (the regulatory limit for PlTXs is 30 μg kg−1 in shellfish). Although the impacts of HAB-toxins in cephalopod physiology are not as well understood as in fish species, similar effects are expected since they possess a complex nervous system and highly developed brain comparable to that of the vertebrates. Compared to bivalves, cephalopods represent a lower risk of shellfish poisoning in humans, since they are usually consumed eviscerated, with exception of traditional dishes from the Mediterranean area.
Coordinating Metabolite Changes with Our Perception of Plant Abiotic Stress Responses: Emerging Views Revealed by Integrative—Omic Analyses
Authors: Radomiljac Jordan , Whelan James , Van der Merwe Margaretha
Published: September 2013

Metabolic configuration and adaptation under a range of abiotic stresses, including drought, heat, salinity, cold, and nutrient deprivation, are subjected to an intricate span of molecular pathways that work in parallel in order to enhance plant fitness and increase stress tolerance. In recent years, unprecedented advances have been made in identifying and linking different abiotic stresses, and the current challenge in plant molecular biology is deciphering how the signaling responses are integrated and transduced throughout metabolism. Metabolomics have often played a fundamental role in elucidating the distinct and overlapping biochemical changes that occur in plants. However, a far greater understanding and appreciation of the complexity in plant metabolism under specific stress conditions have become apparent when combining metabolomics with other—omic platforms. This review focuses on recent advances made in understanding the global changes occurring in plant metabolism under abiotic stress conditions using metabolite profiling as an integrated discovery platform.
Hybrid, Nanoscale Phospholipid/Block Copolymer Vesicles
Authors: Lim Seng , De Hoog Hans-Peter , Parikh Atul , Nallani Madhavan , Liedberg Bo
Published: September 2013

Hybrid phospholipid/block copolymer vesicles, in which the polymeric membrane is blended with phospholipids, display interesting self-assembly behavior, incorporating the robustness and chemical versatility of polymersomes with the softness and biocompatibility of liposomes. Such structures can be conveniently characterized by preparing giant unilamellar vesicles (GUVs) via electroformation. Here, we are interested in exploring the self-assembly and properties of the analogous nanoscale hybrid vesicles (ca. 100 nm in diameter) of the same composition prepared by film-hydration and extrusion. We show that the self-assembly and content-release behavior of nanoscale polybutadiene-b-poly(ethylene oxide) (PB-PEO)/1-palmitoyl-2-oleoyl-sn-glycero-3-phosphatidylcholine (POPC) hybrid phospholipid/block copolymer vesicles can be tuned by the mixing ratio of the amphiphiles. In brief, these hybrids may provide alternative tools for drug delivery purposes and molecular imaging/sensing applications and clearly open up new avenues for further investigation.
Trends in the Start of the Growing Season in Fennoscandia 1982–2011
Authors: Høgda Kjell , Tømmervik Hans , Karlsen Stein
Published: September 2013

Global temperature is increasing, and this is affecting the vegetation phenology in many parts of the world. In Fennoscandia, as well as Northern Europe, the advances of phenological events in spring have been recorded in recent decades. In this study, we analyzed the start of the growing season within five different vegetation regions in Fennoscandia using the 30-year Global Inventory Modeling and Mapping Studies (GIMMS) NDVI3g dataset. We applied a previously developed pixel-specific Normalized Difference Vegetation Index (NDVI) threshold method, adjusted it to the NDVI3g data and analyzed trends within the different regions. Results show a warming trend with an earlier start of the growing season of 11.8 ± 2.0 days (p < 0.01) for the whole area. However, there are large regional differences, and the warming/trend towards an earlier start of the growing season is most significant in the southern regions (19.3 ± 4.7 days, p < 0.01 in the southern oceanic region), while the start was stable or modest earlier (two to four days; not significant) in the northern regions. To look for temporal variations in the trends, we divided the 30-year period into three separate decadal time periods. Results show significantly more change/trend towards an earlier start of the growing season in the first period compared to the two last. In the second and third period, the trend towards an earlier start of the growing season slowed down, and in two of the regions, the trend towards an earlier start of the growing season was even reversed during the last decade.
Theoretical Analysis of Interferometer Wave Front Tilt and Fringe Radiant Flux on a Rectangular Photodetector
Authors: Smith Robert , Fuss Franz
Published: September 2013

This paper is a theoretical analysis of mirror tilt in a Michelson interferometer and its effect on the radiant flux over the active area of a rectangular photodetector or image sensor pixel. It is relevant to sensor applications using homodyne interferometry where these opto-electronic devices are employed for partial fringe counting. Formulas are derived for radiant flux across the detector for variable location within the fringe pattern and with varying wave front angle. The results indicate that the flux is a damped sine function of the wave front angle, with a decay constant of the ratio of wavelength to detector width. The modulation amplitude of the dynamic fringe pattern reduces to zero at wave front angles that are an integer multiple of this ratio and the results show that the polarity of the radiant flux changes exclusively at these multiples. Varying tilt angle causes radiant flux oscillations under an envelope curve, the frequency of which is dependent on the location of the detector with the fringe pattern. It is also shown that a fringe count of zero can be obtained for specific photodetector locations and wave front angles where the combined effect of fringe contraction and fringe tilt can have equal and opposite effects. Fringe tilt as a result of a wave front angle of 0.05° can introduce a phase measurement difference of 16° between a photodetector/pixel located 20 mm and one located 100 mm from the optical origin.
A Naturally Occurring Defective DNA Satellite Associated with a Monopartite Begomovirus: Evidence for Recombination between Alphasatellite and Betasatellite
Authors: Huang Changjun , Xie Yan , Zhao Liling , Ren He , Li Zhenghe
Published: September 2013

Monopartite begomoviruses and their associated satellites form unique disease complexes that have emerged as a serious threat to agriculture worldwide. It is well known that frequent recombination contributes to the diversification and evolution of geminiviruses. In this study, we identified a novel defective satellite molecule (RecSat) in association with Tobacco leaf curl Yunnan virus (TbLCYNV) in a naturally infected tobacco plant. Sequence analysis showed that Recsat comprises 754 nucleotides in size and is a chimera involving alphasatellite and betasatellite sequences, containing both betasatellite-conserved region and alphasatellite stem-loop structure. Recombination analysis revealed that RecSat has arisen from three independent recombination events likely involving Tomato yellow leaf curl China betasatellite, Ageratum yellow vein China betasatellite and Tobacco curly shoot alphasatellite. Co-inoculation of RecSat with TbLCYNV induced symptoms indistinguishable from those induced by TbLCYNV alone in Nicotiana benthamiana. Southern blot hybridization showed that RecSat could be trans-replicated stably in N. benthamiana plants by TbLCYNV, and impaired the accumulation of helper virus and co-inoculated alphasatellite. Our results provide the first evidence for recombination between two distinct types of satellites among geminivirus complex and highlight recombination as a driving force for geminivirus evolution.
Management of cranial cruciate ligament rupture in small dogs: A questionnaire study
Authors: Forster K. , Gorton K. , Maddox T. , Comerford E.
Published: September 2013

Objectives: To survey the current management of cranial cruciate ligament rupture in small dogs (<15 kg) by veterinarians.

Methods: A questionnaire was distributed to veterinarians attending the British Veterinary Orthopaedic Association Spring meeting and British Small Animal Veterinary Association Annual Congress which took place in April 2010. Respondents were surveyed on their management of small dogs with cranial cruciate ligament rupture

Results: Immediate surgical management was chosen by 15.5% of the respondents. Following that, 77.6% of respondents suggested that case management would depend on severity of lameness (81%), age (72.6%), bodyweight (70.4%), degree of instability (64.8%), and duration of lameness (64.0%). Conservative management included non- steroidal antiinflammatory drugs (91.1%), short leash walks (91.1%), weight loss (89.0%), hydrotherapy (53.6%), physiotherapy (41.9%), and cage rest (24.2%). Where surgical management was chosen, 71.4% would perform the procedure rather than refer it to another practice. Surgical techniques included extra-capsular stabilisation (63.4%), corrective osteotomies (32.9%), and intra-articular stabilisation (6.8%). The demographic characteristics of the responding veterinarians had no effect on their initial management of the case. General practice veterinarians were less likely to perform a corrective osteotomy than to refer the case, but were no less likely to perform an extracapsular technique.

Clinical significance: Conservative management is still widely used for treatment of cranial cruciate ligament rupture in dogs weighing less than 15 kg; this is in agreement with previous publications on the management of this condition in small dogs.
Effect of pelvic inclination and torsional deformity on canine acetabular morphology with computed tomography
Authors: Volta A. , Palumbo Piccionello A. , Salvaggio A. , Dini F. , Bonazzi M. , Manfredi S. , Tambella A. M. , Gnudi G.
Published: September 2013

Objectives: To evaluate how the inclination and torsional deformity of the hemipelvis using extra-rotation as a model affect acetabular angle (AA) and dorsal acetabular rim angle (DARA) assessment with computed tomography (CT).

Methods: A normal canine hemipelvis positioned in dorsal recumbency was scanned with a 16-slice multidetector CT scanner, with different degrees of torsional deformity, using extra-rotation around the long axis (0–5–10–15°) of the hemipelvis. Each degree of extra-rotation was acquired at 0°, +20° and –20° of gantry tilt, to mimic different pelvic inclinations on its transverse axis. Cranial and central individual acetabular angles (IAA) and central DARA were calculated and correlated with inclination and torsional deformity.

Results: A very strong negative correlation was found between cranial and central IAA, pelvic inclination, and torsional deformity. A very strong positive correlation was found between DARA, pelvic inclination, and torsional deformity.

Clinical significance: Pelvic inclination and torsional deformity affect acetabular angles assessment with CT. The greater the inclination (ilia far from the tabletop in dorsal recumbency) and torsional deformity of the pelvis, the worse the acetabulum appeared. A standardized scanning protocol for acetabular morphology assessment is needed and it should consider pelvic inclination. The actual relevance of pelvic torsional deformity is not well known and it should be investigated more thoroughly.
A Systematic Review on the Role of Adjunctive Corticosteroids in Herpes Simplex Virus Encephalitis: Is Timing Critical for Safety and Efficacy?
Authors: Ramos-Estebanez Ciro , Lizarraga Karlo J , Merenda Amedeo
Published: September 2013

Background

Most herpes simplex virus encephalitis (HSVE) patients become disabled despite antiviral therapy. Adjunctive corticosteroid therapy may improve outcomes.

Methods

This was a systematic review of the literature addressing the use of corticosteroids in HSVE.

Results

Data suggesting that steroids decrease the immunological response and enhance viral replication originated from non-neural microenvironments. Early steroid administration might be harmful because initial damage in HSVE is mediated by viral replication. Steroid treatment improves outcomes in animal models by inhibiting the subsequent inflammatory response. Clinical observations support a similar benefit in symptomatic HSVE patients. Cerebrospinal fluid inflammatory markers might guide appropriate timing in future clinical practice.

Conclusions

Experimental and clinical observations suggest a benefit from adjunctive steroid therapy in HSVE. Nevertheless, current evidence is not yet sufficient to endorse this approach as a standard of practice.
Telaprevir in a Patient with Chronic Hepatitis C and Cryoglobulinemic Glomerulonephritis
Authors: De Nicola Stella , Aghemo Alessio , Campise Maria Rosaria , D'Ambrosio Roberta , Rumi Maria Grazia , Messa Piergiorgio , Colombo Massimo
Published: September 2013

Mixed cryoglobulinemia (MC), the most common extra-hepatic manifestation of HCV, may lead to renal involvement ranging from mild urinary abnormalities to nephritic syndrome, eventually evolving to renal failure requiring renal replacement therapy. HCV eradication with pegylated interferon (PEG-IFN) and ribavirin (RBV) is the only curative treatment for MC-related membranoproliferative glomerulonephritis. The addition of directly acting antivirals (DAAs) to PEG-IFN and RBV has significantly improved sustained virological response rates in HCV genotype 1 patients. Safety and efficacy of this regimen in patients with membranoproliferative glomerulonephritis has not been proved yet. Here, we report the case of a woman with HCV-1-related cryoglobulinemic membranoproliferative glomerulonephritis presenting with severe nephritic syndrome and rapidly progressive renal failure, who received successful treatment with the DAA telaprevir in conjunction with PEG-IFN and RBV. Triple therapy was safe and effective, leading to HCV eradication and complete resolution of acute renal failure.
«Solitarios refugios de efemérides viejas». Monumentos y ciudades históricas como símbolos nacionales en la prensa gráfica (1918-1930)
Authors: Hernández Cano Eduardo
Published: September 2013

Siguiendo una tradición que se remontaba a mediados del siglo XIX, la prensa gráfica española del primer tercio del XX hizo circular extensamente representaciones de ciudades y monumentos históricos como símbolos de la nación. Partiendo de los trabajos de Benedict Anderson sobre el papel de la prensa en la constitución de imaginarios de comunidades nacionales, y de George L. Mosse sobre la nacionalización de masas a través de los monumentos, este artículo analiza el modo en que estas representaciones formaron una idea cultural de la nación para las clases medias a las que la prensa gráfica estaba destinada.
«Vergüenza y ludibrio de las ciudades modernas»: los nacionalistas catalanes ante el flamenco en la Barcelona de 1900-1936
Authors: Holguín Sandie
Published: September 2013

Este artículo analiza el flamenco, el anti-flamenquismo y las identidades nacionales en Barcelona durante las tres décadas anteriores a la Guerra Civil. Así, estudia los significados de los espacios musicales impugnados por los nacionalistas catalanes. A través de los ataques a los cafés cantantes y de la promoción de la sardana y los orfeones, los catalanistas promovieron una identidad que negaba el sistema industrial creado en Cataluña y trataba de eliminar los problemas que venían con él. Al final, sin embargo, los intentos de los nacionalistas catalanes para que pasaran de moda los intérpretes e interpretaciones del flamenco fracasaron a causa de su éxito. Tanto los extranjeros como los catalanes y andaluces en busca de lucro contribuyeron a mantener viva la llama de una Barcelona exótica.
The Moderating Roles of Income and Age in Mobile Commerce Application
Authors: Eze Uchenna Cyril , Poong Yew Siang
Published: September 2013

Mobile commerce is becoming a major aspect of our human endeavors with the advancements in wireless technology and services. This article examines key factors that influence mobile commerce adoption, and the moderating roles of age and income. The conceptual framework is underpinned on an extended technology acceptance model. The survey data was collected from participants selected from Malaysia. The analysis was based on 260 valid responses, and the findings reveal that age and income moderate perceptions on behavioral intention to adopt mobile commerce. Different age groups exhibit different perceptions. Further, cost and social influence become more important as age increases, while perceived usefulness becomes more significant as age decreases. In addition, perceived usefulness emerges as the most important factor for participants earning low income, and social influence is the most important factor for participants earning high income. Surprisingly, high-income earners indicate that cost is an important factor. The contributions to research and practice including suggestions for future studies are discussed.
Induction of Complement C3a Receptor Responses by Kallikrein-Related Peptidase 14
Authors: Oikonomopoulou Katerina , DeAngelis Robert A. , Chen Hui , Diamandis Eleftherios P. , Hollenberg Morley D. , Ricklin Daniel , Lambris John D.
Published: September 2013

Activation of the complement system is primarily initiated by pathogen- and damage-associated molecular patterns on cellular surfaces. However, there is increasing evidence for direct activation of individual complement components by extrinsic proteinases as part of an intricate crosstalk between physiological effector systems. We hypothesized that kallikrein-related peptidases (KLKs), previously known to regulate inflammation via proteinase-activated receptors, can also play a substantial role in innate immune responses via complement. Indeed, KLKs exemplified by KLK14 were efficiently able to cleave C3, the point of convergence of the complement cascade, indicating a potential modulation of C3-mediated functions. By using in vitro fragmentation assays, mass spectrometric analysis, and cell signaling measurements, we pinpointed the generation of the C3a fragment of C3 as a product with potential biological activity released by the proteolytic action of KLK14. Using mice with various complement deficiencies, we demonstrated that the intraplantar administration of KLK14 results in C3-associated paw edema. The edema response was dependent on the presence of the receptor for C3a but was not associated with the receptor for the downstream complement effector C5a. Our findings point to C3 as one of the potential substrates of KLKs during inflammation. Given the wide distribution of the KLKs in tissues and biological fluids where complement components may also be expressed, we suggest that via C3 processing, tissue-localized KLKs can play an extrinsic complement-related role during activation of the innate immune response.
A contribution to the knowledge of Euphorinae (Hymenoptera: Braconidae), with six new records from Iran
Authors: Farahani S. , Talebi A.A. , Rakhshani E.
Published: September 2013

A survey was conducted for identification of Euphorinae (Hymenoptera: Braconidae) in the northern provinces of Iran. The specimens were collected using Malaise traps during 2010-2011. In all, 9 species in four genera consisting of Allurus Förster, Dinocampus Förster, Peristenus Nees and Perilitus Nees were collected and identified. The genus Allurus is recorded for the first time from Iran. Six species are newly recorded for the Iranian fauna including Allurus muricatus (Haliday), Peristenus pallipes Curtis, Peristenus relictus (Ruthe), Perilitus (Townesilitus) bicolor (Wesmael), Perilitus foveolatus Reinhard and Perilitus rutilus (Nees). Morphological diagnostic characters and geographical distribution of the species are briefly discussed. A key is presented for identification of the genera and species in the studied area.
‘Forming identity through Song’: How our songs in worship shape our theological identity: A study of Lutheran hymns and how they shaped German descendent Lutheran congregations
Authors: Tönsing Gertrud
Published: September 2013

How do songs and Christian hymns shape the identity and theology of Christian communities? How does the identity and theology of a Christian community shape the hymns that are written, sung and collected in song books and hymnals? This article explores these questions from the point of view of the author’s community, the German-descendent Lutheran communities in South Africa, and studies their main hymn book, the Lutheran hymnal from Germany (Evangelisches Kirchengesangbuch [EKG]) which was used from the 1950s until the early 1990s in the congregations. It shows up the strengths and the gaps of these hymns which come from a theology with a strong focus on faith and trust, but a rather narrow personal morality, with the social ethics restricted to doing one’s Christian duty and praying for the government. Comparing this hymnal to the later hymnal published in 1990, the article shows, that some of the blind spots of one generation can be filled in by the next generation of songwriters.
Drie verlanges
Authors: Viljoen Hein
Published: September 2013

No abstract available.
RP-LC and TLC Densitometric Determination of Paracetamol and Pamabrom in Presence of Hazardous Impurity of Paracetamol and Application to Pharmaceuticals
Authors: El-Houssini Ola Mohamed
Published: September 2013

Two simple, accurate and reproducible methods were developed and validated for the simultaneous determination of paracetamol (PARA) and pamabrom (PAMB) in pure form and in tablets. The first method was based on reserved-phase high-performance liquid chromatography, on a Thermo Hypersil ODS column using methanol:0.01 M sodium hexane sulfonate:formic acid (67.5:212.5:1 v/v/v) as the mobile phase. The flow rate was 2 mL/min and the column temperature was adjusted to 35 °C. Quantification was achieved with UV detection at 277 nm over concentration range of 100-600 and 4-24 μg/mL, with mean percentage recoveries were found to be 99.90 ± 0.586 and 99.26 ± 0.901 for PARA and PAMB, respectively. The second method was based on thin-layer chromatography separation of PARA and PAMB followed by densitometric measurement of the spots at 254 nm and 277 nm for PARA and PAMB respectively. Separation was carried out on aluminum sheet of silica gel 60F254 using dichloromethane:methanol:glacial acetic acid (7.5:1:0.5 v/v/v) as the mobile phase over concentration range of 1-10 and 0.32-3.20 μg per spot, with mean percentage recovery of 100.52 ± 1.332 and 99.71 ± 1.478 for PARA and PAMB, respectively. The methods retained their accuracy in presence of up to 50% of P-aminophenol and could be successfully applied in tablets.
Forage yield of simple and complex grass–legume mixtures under two management strategies
Authors: Foster A. , Vera C. L. , Malhi S. S. , Clarke F. R.
Published: September 2013

Foster, A., Vera, C. L., Malhi, S. S. and Clarke, F. R. 2014. Forage yield of simple and complex grass–legume mixtures under two management strategies. Can. J. Plant Sci. 94: 41–50. Limited information is available on the dry matter production, protein content and species composition of complex mixtures of introduced perennial forage crop species for hay and pasture in the moister regions of Saskatchewan. A field experiment was sown on 2008 May 27 at Melfort, Saskatchewan, Canada, on a thick Black Chernozem (Udic Boroll) silty clay soil, to compare the effects on dry matter yield (DMY), protein content and species composition of perennial forage crop monocultures and mixtures, under a two-cut and a three-cut management system, in 2009, 2010, 2011 and 2012. Eleven treatments consisted of monocultures of hybrid bromegrass (Bromus riparius Rehm.×Bromus inermis Leyss.), smooth bromegrass (Bromus inermis Leyss.), crested wheatgrass [Agropyron cristatum (L.) Gaertn], intermediate wheatgrass [Agropyron intermedium (Host.) Beauv.] and alfalfa (Medicago sativa L.); simple mixtures of each of these individual grass species with alfalfa; a more complex mixture of all these grass species and alfalfa, and a very complex mixture consisting of the complex mixture plus meadow bromegrass (Bromus riparius Rehm.), orchardgrass (Dactylis glomerata L.), tall fescue [Festuca arundinacea (Schreb.) Wimm.], timothy (Phleum pratense L.) and slender wheatgrass [Elymus trachycaulus (Link) Gould ex Shinners]. The alfalfa was inoculated with rhizobium, and no fertilizer was added to any treatment during the course of the study. The two-cut system yielded higher than the three-cut system in all years. In 2009, the first cutting year, all treatments, especially under the two-cut system, produced similar forage DMY, with monoculture grasses yielding as much as that of their mixture with alfalfa. In 2010, 2011 and 2012, however, monoculture alfalfa and grass–alfalfa treatments had higher DMY than the monoculture grasses. Monoculture alfalfa also showed superior DMY than most grass–alfalfa mixtures, especially during the last 2 yr of the study. In conclusion, the inclusion of alfalfa in forage mixtures, grown in unfertilized soil, significantly increased forage yield, especially after the first production year, and these grass–alfalfa mixtures yielded almost as much as monoculture alfalfa. Also, the inclusion of alfalfa significantly increased the forage protein content over the grass alone treatments. Hybrid bromegrass, grown alone or in mixture with alfalfa, yielded similar to the other grasses tested, while crested wheatgrass did not compete as well as other main grasses, grown alone or in mixture with alfalfa. In this study, the use of complex or very complex mixtures of introduced grasses with alfalfa did not increase DMY over the simple grass–alfalfa mixtures.
Effects of long-term protection from grazing on phenotypic expression in geographically separated mountain rough fescue populations
Authors: Thompson D. J. , Willms W. D.
Published: September 2013

Thompson, D. J. and Willms, W. D. 2014. Effects of long-term protection from grazing on phenotypic expression in geographically separated mountain rough fescue populations. Can. J. Plant Sci. 94: 33–39. Whether or not long-term grazing or protection from grazing alters the genetic makeup of grass populations has been debated. Mountain rough fescue [(Festuca campestris (Rydb.)], which is highly sensitive to summer grazing, and becomes dominant in plant communities with long-term protection, was chosen to address this question. Plants from three geographic sites (Stavely in AB, Milroy in the Kootenay trench, BC and Goose Lake on the BC interior plateau) with divergent grazing histories were vegetatively propagated from tillers. Daughter plants were planted into two field nurseries (at Kamloops, BC, and Stavely, AB) and morphological measurements were taken in two field seasons post-establishment. Plants from all three populations were taller, flowered earlier, and were more productive at the Kamloops nursery site. Of the three geographic sources, plants from the Goose Lake site were most distinct with narrower leaves, later flowering, and greater yield. Plants with a long history of grazing had slightly shorter fertile tillers and leaves than plants with a history of long-term protection.
AAC Bravo flax
Authors: Duguid S. D. , Rashid K. Y. , Busch H. , Schaupp H.
Published: September 2013

Duguid, S. D., Rashid, K. Y., Busch, H. and Schaupp, H. 2014. AAC Bravo flax. Can. J. Plant Sci. 94: 153–156. Bravo, a medium maturing oilseed flax (Linum usitatissimum L.) was released in 2012 by Agriculture and Agri-Food Canada, Morden Research Station, Morden, Manitoba. Developed from the Flanders/Pacific made in 1995, AAC Bravo was evaluated in the Flax Cooperative Trials (2008–2010) before being registered in 2012. AAC Bravo's desirable combination of agronomic traits, particularly its significantly large seed size as compared with other commercially available cultivars, seed quality and disease resistance, should make it a useful cultivar for producers and the flax industry.
Aerosol extinction-to-backscatter ratio derived from passive satellite measurements
Authors: Bréon F.-M.
Published: September 2013

Abstract. Spaceborne reflectance measurements from the POLDER instrument are used to study the specific directional signature close to the backscatter direction. The data analysis makes it possible to derive the extinction-to-backscatter ratio (EBR), which is related to the inverse of the scattering phase function for an angle of 180° and is needed for a quantitative interpretation of lidar observations (active measurements). In addition, the multidirectional measurements are used to quantify the scattering phase function variations close to backscatter, which also provide some indication of the aerosol particle size and shape. The spatial distributions of both parameters show consistent patterns that are consistent with the aerosol type distributions. Pollution aerosols have an EBR close to 70, desert dust values are on the order of 50 and EBR of marine aerosols is close to 25. The scattering phase function shows an increase with the scattering angle close to backscatter. The relative increase ∂lnP/∂γ is close to 0.01 for dust and pollution type aerosols and 0.06 for marine type aerosols. These values are consistent with those retrieved from Mie simulations.
Icehouse-greenhouse variations in marine denitrification
Authors: Algeo T. J. , Meyers P. A. , Robinson R. S. , Rowe H. , Jiang G. Q.
Published: September 2013

Abstract. Long-term secular variation in the isotopic composition of seawater fixed nitrogen (N) is poorly known. Here, we document variation in the N-isotopic composition of marine sediments (δ15Nsed) since 660 Ma (million years ago) in order to understand major changes in the marine N cycle through time and their relationship to first-order climate variation. During the Phanerozoic, greenhouse climate modes were characterized by low δ15Nsed (∼ −2 to +2‰) and icehouse climate modes by high δ15Nsed (∼ +4 to +8‰). Shifts toward higher δ15Nsed occurred rapidly during the early stages of icehouse modes, prior to the development of major continental glaciation, suggesting a potentially important role for the marine N cycle in long-term climate change. Reservoir box modeling of the marine N cycle demonstrates that secular variation in δ15Nsed was likely due to changes in the dominant locus of denitrification, with a shift in favor of sedimentary denitrification during greenhouse modes owing to higher eustatic (global sea-level) elevations and greater on-shelf burial of organic matter, and a shift in favor of water-column denitrification during icehouse modes owing to lower eustatic elevations, enhanced organic carbon sinking fluxes, and expanded oceanic oxygen-minimum zones. The results of this study provide new insights into operation of the marine N cycle, its relationship to the global carbon cycle, and its potential role in modulating climate change at multimillion-year timescales.
Technical Note: Disturbance of soil structure can lead to release of methane entrapped in glacier forefield soils
Authors: Nauer P. A. , Chiri E. , Zeyer J. , Schroth M. H.
Published: September 2013

Abstract. Investigations of sources and sinks of atmospheric CH4 are needed to understand the global CH4 cycle and climate-change mitigation options. Glaciated environments might play a critical role due to potential feedbacks with global glacial meltdown. In an emerging glacier forefield, an ecological shift occurs from an anoxic, potentially methanogenic subglacial sediment to an oxic proglacial soil, in which soil-microbial consumption of atmospheric CH4 is initiated. The development of this change in CH4 turnover can be quantified by soil-gas profile analysis. We found evidence for CH4 entrapped in glacier forefield soils when comparing two methods for the collection of soil-gas samples: a modified steel rod (SR) designed for one-time sampling and rapid screening (samples collected ~ 1 min after hammering the SR into the soil), and a novel multi-level sampler (MLS) for repetitive sampling through a previously installed access tube (samples collected weeks after access-tube installation). In glacier forefields on siliceous bedrock, sub-atmospheric CH4 concentrations were observed with both methods. Conversely, elevated soil-CH4 concentrations were observed in calcareous glacier forefields, but only in samples collected with the SR, while MLS samples all showed sub-atmospheric CH4 concentrations. Time-series SR soil-gas sampling (additional samples collected 2, 3, 5, and 7 min after hammering) confirmed the transient nature of the elevated soil-CH4 concentrations, which were decreasing from ~ 100 μL L−1 towards background levels within minutes. This hints towards the existence of entrapped CH4 in calcareous glacier forefield soil that can be released when sampling soil-gas with the SR. Laboratory experiments with miniature soil cores collected from two glacier forefields confirmed CH4 entrapment in these soils. Treatment by sonication and acidification resulted in a massive release of CH4 from calcareous cores (on average 0.3–1.8 μg CH4 (g d.w.)−1); release from siliceous cores was 1–2 orders of magnitude lower (0.02–0.03 μg CH4 (g d.w.)−1). Clearly, some form of CH4 entrapment exists in calcareous glacier forefield soils, and to a much lesser extent in siliceous glacier forefield soils. Its nature and origin remain unclear and will be subject of future investigations.
Ensemble meteorological reconstruction using circulation analogues of 1781–1785
Authors: Yiou P. , Boichu M. , Vautard R. , Vrac M. , Jourdain S. , Garnier E. , Fluteau F. , Menut L.
Published: September 2013

Abstract. This paper uses a method of atmospheric flow analogues to reconstruct an ensemble of atmospheric variables (namely sea-level pressure, surface temperature and wind speed) between 1781 and 1785. The properties of this ensemble are investigated and tested against observations of temperature. The goal of the paper is to assess whether the atmospheric circulation during the Laki volcanic eruption (in 1783) and the subsequent winter were similar to the conditions that prevailed in the winter 2009/2010 and during spring 2010. We find that the three months following the Laki eruption in June 1783 barely have analogues in 2010. The cold winter of 1783/1784 yields circulation analogues in 2009/2010. Our analysis suggests that it is unlikely that the Laki eruption was responsible for the cold winter of 1783/1784, of the relatively short memory of the atmospheric circulation.
Atmospheric inverse modeling with known physical bounds: an example from trace gas emissions
Authors: Miller S. M. , Michalak A. M. , Levi P. J.
Published: September 2013

Abstract. Many inverse problems in the atmospheric sciences involve parameters with known physical constraints. Examples include non-negativity (e.g., emissions of some urban air pollutants) or upward limits implied by reaction or solubility constants. However, probabilistic inverse modeling approaches based on Gaussian assumptions cannot incorporate such bounds and thus often produce unrealistic results. The atmospheric literature lacks consensus on the best means to overcome this problem, and existing atmospheric studies rely on a limited number of the possible methods with little examination of the relative merits of each. This paper investigates the applicability of several approaches to bounded inverse problems and is also the first application of Markov chain Monte Carlo (MCMC) to estimation of atmospheric trace gas fluxes. The approaches discussed here are broadly applicable. A common method of data transformations is found to unrealistically skew estimates for the examined example application. The method of Lagrange multipliers and two MCMC methods yield more realistic and accurate results. In general, the examined MCMC approaches produce the most realistic result but can require substantial computational time. Lagrange multipliers offer an appealing alternative for large, computationally intensive problems when exact uncertainty bounds are less central to the analysis. A synthetic data inversion of US anthropogenic methane emissions illustrates the strengths and weaknesses of each approach.
Investigating the spatio-temporal variability in groundwater and surface water interactions: a multi-technique approach
Authors: Unland N. P. , Cartwright I. , Andersen M. S. , Rau G. C. , Reed J. , Gilfedder B. S. , Atkinson A. P. , Hofmann H.
Published: September 2013

Abstract. The interaction between groundwater and surface water along the Tambo and Nicholson rivers, southeast Australia, was investigated using 222Rn, Cl, differential flow gauging, head gradients, electrical conductivity (EC) and temperature profiles. Head gradients, temperature profiles, Cl concentrations and 222Rn activities all indicate higher groundwater fluxes to the Tambo River in areas of increased topographic variation where the potential to form large groundwater–surface water gradients is greater. Groundwater discharge to the Tambo River calculated by Cl mass balance was significantly lower (1.48 × 104 to 1.41 × 103 m3 day−1) than discharge estimated by 222Rn mass balance (5.35 × 105 to 9.56 × 103 m3 day−1) and differential flow gauging (5.41 × 105 to 6.30 × 103 m3 day−1) due to bank return waters. While groundwater sampling from the bank of the Tambo River was intended to account for changes in groundwater chemistry associated with bank infiltration, variations in bank infiltration between sample sites remain unaccounted for, limiting the use of Cl as an effective tracer. Groundwater discharge to both the Tambo and Nicholson rivers was the highest under high-flow conditions in the days to weeks following significant rainfall, indicating that the rivers are well connected to a groundwater system that is responsive to rainfall. Groundwater constituted the lowest proportion of river discharge during times of increased rainfall that followed dry periods, while groundwater constituted the highest proportion of river discharge under baseflow conditions (21.4% of the Tambo in April 2010 and 18.9% of the Nicholson in September 2010).
ASSESSING FAÇADE VISIBILITY IN 3D CITY MODELS FOR CITY MARKETING
Authors: Albrecht F. , Moser J. , Hijazi I.
Published: September 2013

Abstract. In city marketing, different applications require the evaluation of the visual impression of displays in the urban environment on people that visit the city. Therefore, this research focuses on the way how visual displays on façades for movie performances are perceived during a cultural event triggered by city marketing. We describe the different visibility analysis methods that are applicable to the analysis of façades. The methods advanced from the domains of Geographic Information Science, architecture and computer graphics. A detailed scenario is described in order to perform a requirements analysis for identifying the requirements to visibility information. This visibility information needs to describe the visual perception of displays on façades adequately. The requirements are compared to the visibility information that can be provided by the visibility methods. A discussion of the comparison summarizes the advantages and disadvantages of existing visibility analysis methods for describing the visibility of façades. The results show that part of the researched approaches is able to support the requirements to visibility information. But they also show that for a complete support of the entire analysis workflow, there remain unsolved workflow integration issues.
CALCULATING LEAST RISK PATHS IN 3D INDOOR SPACE
Authors: Vanclooster A. , De Maeyer Ph. , Fack V. , Van de Weghe N.
Published: September 2013

Abstract. Over the last couple of years, research on indoor environments has gained a fresh impetus; more specifically applications that support navigation and wayfinding have become one of the booming industries. Indoor navigation research currently covers the technological aspect of indoor positioning and the modelling of indoor space. The algorithmic development to support navigation has so far been left mostly untouched, as most applications mainly rely on adapting Dijkstra's shortest path algorithm to an indoor network. However, alternative algorithms for outdoor navigation have been proposed adding a more cognitive notion to the calculated paths and as such adhering to the natural wayfinding behaviour (e.g. simplest paths, least risk paths). These algorithms are currently restricted to outdoor applications. The need for indoor cognitive algorithms is highlighted by a more challenged navigation and orientation due to the specific indoor structure (e.g. fragmentation, less visibility, confined areas…). As such, the clarity and easiness of route instructions is of paramount importance when distributing indoor routes. A shortest or fastest path indoors not necessarily aligns with the cognitive mapping of the building. Therefore, the aim of this research is to extend those richer cognitive algorithms to three-dimensional indoor environments. More specifically for this paper, we will focus on the application of the least risk path algorithm of Grum (2005) to an indoor space. The algorithm as proposed by Grum (2005) is duplicated and tested in a complex multi-storey building. The results of several least risk path calculations are compared to the shortest paths in indoor environments in terms of total length, improvement in route description complexity and number of turns. Several scenarios are tested in this comparison: paths covering a single floor, paths crossing several building wings and/or floors. Adjustments to the algorithm are proposed to be more aligned to the specific structure of indoor environments (e.g. no turn restrictions, restricted usage of rooms, vertical movement) and common wayfinding strategies indoors. In a later stage, other cognitive algorithms will be implemented and tested in both an indoor and combined indoor-outdoor setting, in an effort to improve the overall user experience during navigation in indoor environments.