Morphology and Properties of the Laser-Irradiated Composition “Chrome Coating — Copper Substrate”
Authors: Brover G. I. , Shcherbakova E. E. , Borisenko E. B. 
Published: November 2024

Introduction. During pulsed laser processing and modification of the surface of non-ferrous alloys and coatings based on them, several still unresolved issues arise. In particular, the extreme thermal deformation conditions of laser processing are not linked to the peculiarities of structure formation and formation of properties in irradiated “coating — copper substrate” compositions. A metal physical analysis of the possibility and reasons for increasing the adhesion strength of coatings to a metal (copper) substrate during high-speed laser processing is insufficiently substantiated and evidence-based. To make a reasonable choice of technological parameters for the surface hardening mode of non-ferrous alloy products, as well as for obtaining high-quality workable composite layers on their surface, it is necessary to solve the above issues and tasks. The aim of this article is to determine the possibility and conditions for increasing the adhesion strength of a chrome coating to a copper substrate under laser irradiation of the composition.Materials and Methods. Metal physical studies in the work were carried out on samples of non-ferrous alloys of the Cu–Zn system with a chrome electrochemical coating with a thickness of 20 μm. The “copper substrate — chrome coating” composition was irradiated at a Kvant-16 installation with a radiation power density of 70–250 MW/m2. Metallographic structural analysis, scanning probe microscopy, and durometric studies were used in the work.Results. It has been calculated that the dynamic and thermal stresses arising in the laser-irradiated compositions “chrome coating — copper substrate” were about 320 MPa. Metal physical studies revealed that, in extreme thermal deformation conditions of laser treatment, the effect of contact melting was manifested at the boundary of the coating with the copper base. Dynamic recrystallization occurred in the surface layers of the irradiated L62 copper alloy, resulting in the formation of grains with a size of 4.5–5.0 μm on the surface of the alloy with an initial grain size of 25 μm.Discussion and Conclusion. It has been found that the adhesion strength of a chrome coating to a copper alloy substrate increased laser irradiation at a radiation power density of 150 MW/m2. This was due to the formation of a transition region 2–4 μm deep in the contact zone with a structure consisting of sections of mutually insoluble solid solutions based on chromium and copper. Based on the analysis of the copper —chromium state diagram and the model of the temperature field under laser irradiation of the chromium coating, it was suggested that contact melting occurred in the transition zone from the coating to the copper substrate. It was shown that thermostrictive stresses, the calculated quantitative values of which were about 320 MPa, had an initiating effect on the observed processes of structure formation in the laser irradiation zones. It was found that such a level of stresses arising in copper alloys under laser irradiation was sufficient for plastic deformation and dynamic recrystallization of the metal and contributed to the formation of a fine-grained structure (4.5–5.0 μm) with an initial grain size of 25 μm. An analysis of the results of studies of irradiated compositions "coating — copper substrate" allowed us to conclude that they expanded the technological capabilities of the laser method of hardening materials and ensure guaranteed high performance of irradiated products with coatings