bluuebunny/crossref_metadata_2025 huggingface dataset:
Controlled Drug Release from Nanoengineered Polysaccharides
Authors: Bayer Ilker S.
Published: April 2023

Polysaccharides are naturally occurring complex molecules with exceptional physicochemical properties and bioactivities. They originate from plant, animal, and microbial-based resources and processes and can be chemically modified. The biocompatibility and biodegradability of polysaccharides enable their increased use in nanoscale synthesis and engineering for drug encapsulation and release. This review focuses on sustained drug release studies from nanoscale polysaccharides in the fields of nanotechnology and biomedical sciences. Particular emphasis is placed on drug release kinetics and relevant mathematical models. An effective release model can be used to envision the behavior of specific nanoscale polysaccharide matrices and reduce impending experimental trial and error, saving time and resources. A robust model can also assist in translating from in vitro to in vivo experiments. The main aim of this review is to demonstrate that any study that establishes sustained release from nanoscale polysaccharide matrices should be accompanied by a detailed analysis of drug release kinetics by modeling since sustained release from polysaccharides not only involves diffusion and degradation but also surface erosion, complicated swelling dynamics, crosslinking, and drug-polymer interactions. As such, in the first part, we discuss the classification and role of polysaccharides in various applications and later elaborate on the specific pharmaceutical processes of polysaccharides in ionic gelling, stabilization, cross-linking, grafting, and encapsulation of drugs. We also document several drug release models applied to nanoscale hydrogels, nanofibers, and nanoparticles of polysaccharides and conclude that, at times, more than one model can accurately describe the sustained release profiles, indicating the existence of release mechanisms running in parallel. Finally, we conclude with the future opportunities and advanced applications of nanoengineered polysaccharides and their theranostic aptitudes for future clinical applications.
The Evolution Characteristics of Twisted Hermite–Gaussian Schell-Model Beams Propagating in a Uniaxial Crystal
Authors: Lin Rong , Sun Hongyan , Zhang Hui , Liu Yonglei , Wu Jidong , Yu Jiayi , Cai Yangjian , Zhu Xinlei
Published: April 2023

In this paper, we study the propagation properties of twisted Hermite–Gaussian Schell- model (THGSM) beams propagating in a uniaxial crystal orthogonal to the optical axis. We derive the concrete analytical expression of the cross-spectral density (CSD) function in the crystal and simulate the evolution characteristics of such beams, including normalized spectral intensity, the spectral degree of coherence (DOC), and effective beam width. We find that the spectral intensity distribution exhibits a non-circular symmetric self-splitting while rotating, and the distribution of the spectral DOC is non-circular symmetric rotationally distorted, which is quite different from that in an isotropic medium. The initial beam parameters and crystal parameters both affect the distribution of spectral intensity and DOC. Furthermore, increasing the twist factor and adjusting the ratio of the extraordinary light refractive index and the ordinary light refractive index ne/no of the uniaxial crystal can suppress the beam expansion as propagating in the crystal. Our results show that the uniaxial crystal can be used to determine whether light beams carry a twist phase or not, and to modulate the characteristics of light beams.
Surface-Emitting Lasers with Surface Metastructures
Authors: Liu Anjin , Zhang Jing , Hao Chenxi , Wang Minglu , Zheng Wanhua
Published: April 2023

Vertical-cavity surface-emitting lasers (VCSELs) have been widely used in consumer electronics, light detection and ranging, optical interconnects, atomic sensors, and so on. In this paper, a VCSEL with the surface metastructure like one-dimensional high-contrast grating (HCG), based on the HCG-DBR vertical cavity, was first designed and fabricated. The polarization characteristic of the HCG-VCSEL were experimentally studied. The p-doped top 4-pair DBR for the current spreading and the direction shift between the HCG and the elliptical oxide aperture may result in a low orthogonal polarization suppression ratio in the HCG-VCSEL. Then, the Bloch surface wave surface-emitting laser (BSW-SEL), based on the HCG-DBR metastructure, is proposed for single-mode, high-efficiency, and high-power output with a low divergence angle. The mode field and the far field profile of the BSW-SEL are calculated for verification. The surface-emitting lasers with surface metastructures are useful for the sensing applications and optical interconnects.
Downtaper on Multimode Fibers towards Sustainable Power over Fiber Systems
Authors: Fresno-Hernández Alicia , Rodríguez-Guerra Marta , Rodríguez-Garrido Roberto , Vázquez Carmen
Published: April 2023

This paper presents a transition taper for coupling light between optical fibers with different geometries and refractive index profiles used in Power over Fiber (PoF) systems. Global energy efficiency and costs are critical parameters when delivering high power to remote areas. High-power lasers have maximum coupling for large core fibers, while widespread multimode optical (OM1) fibers used in optical communications are cheaper. We study the optical losses between large core fibers (200 µm) and OM1 fibers (62.5 µm) theoretically and experimentally. We demonstrate that improvements of 2 dB can be obtained by adding the new tapered structure to the system, compared to the direct splice between both fibers. There is good agreement between measured and calculated loss values using a new Gaussian loss model to describe splices between tapered and straight fibers. The fabrication of the transition taper is also described. We also measure the numerical aperture (NA) changes in the downtaper zone and demonstrate that the lower the NA of the input light, the higher the efficiency improvement.
Self-Luminous Wood Coatings with Carbon Dots/TiO2 Grafted Afterglow SrAl2O4: Eu, Dy Core-Shell Phosphors for Long-Lasting Formaldehyde Removal
Authors: Zhang Longfei , Wang Ying , Peng Limin , Chen Zhilin , Lyu Shaoyi , Wang Siqun
Published: April 2023

Long-term relief of indoor volatile pollution has become a competitive issue worldwide in both visible and dark environments. A novel self-luminous wood coating with carbon dots (CDs)/titanium dioxide (TiO2) nanomaterial coated SrAl2O4: Eu2+, Dy3+ (CDs/TiO2@SAO) composite was prepared for the long-term degradation of formaldehyde through a simple sol-gel method. The microstructure, chemical composition, ultraviolet-visible (UV-vis) spectra, and long-lasting fluorescence of the CDs/TiO2@SAO photocatalyst were analyzed to illustrate the mechanism for degrading formaldehyde. The obtained CDs with a particle size of ~2–7 nm have a good graphite structure and presented good absorption in visible light. In addition, owing to the synergistic effect of the CDs/TiO2 nanomaterial coating layer and the long-afterglow luminescence of the SAO phosphor, the CDs/TiO2@SAO composite can absorb a part of the visible light for photocatalytic degradation and store luminous energy efficiently at daytime so as to give out visible luminescence continuously for a few hours in the darkness. Furthermore, the functional wood coatings with CDs/TiO2@SAO composite presented continuous and efficient photocatalytic activity in the presence and absence of light exposure. The current research could provide a new strategy for designing an efficient photocatalyst for degrading formaldehyde pollution in the daytime with a visible light supply and in an indoor dark environment without an external light source.
Amidated Pectic Polysaccharides (Pectin) as Methane Hydrate Inhibitor at Constant Cooling and Isobaric Condition
Authors: Effendi Adam Daniel , Md Yusof Muhammad Aslam , Abd Mutalib Nor Fariza , Sia Chee Wee
Published: April 2023

This study aims to address the environmental impact of using common commercial hydrate inhibitors such as Methanol (MeOH) in extremely cold oil and gas environments. As a greener alternative, Pectic Polysaccharides (pectin) can act as a kinetic hydrate inhibitor (KHI) to delay hydrate formation. We evaluated the performance of amidated pectin (AMP), a type of pectin with higher electronegative functional groups, using a high-pressure micro-differential scanning calorimeter (HP µ-DSC) under isobaric conditions with constant cooling. We compared AMP to low-methoxylated pectin (LMP) and high-methoxylated pectin (HMP) and found that AMP was the best KHI among the tested pectin types. At a concentration of 1.0 wt.%, the AMP Relative Inhibitor Performance (RIP) was 0.10, and at 0.1 wt.%, it had an RIP of 0.07, which were the only positive RIPs obtained amongst the tested KHIs. The results suggest that AMP can be a sustainable KHI option in extremely cold environments where the KHI effectiveness typically declines.
Antimicrobial Activity and Crystallization Features in Bio-Based Composites of PLLA and MCM-41 Particles Either Pristine or Functionalized with Confined Ag Nanowires
Authors: Díez-Rodríguez Tamara M. , Blázquez-Blázquez Enrique , Fernández-García Marta , Muñoz-Bonilla Alexandra , Pérez Ernesto , Cerrada María L.
Published: April 2023

Composites based on an L-rich poly(lactic acid) (PLLA) and MCM-41, either neat or modified with a silver (MCM-41@Ag), are achieved by solvent casting, being next processed by compression molding. Ag is mainly embedded as nanowires within the hybrid MCM-41@Ag particles, enabling its antimicrobial character. In these composites, the PLLA thermal stability, nucleation efficiency, and mechanical response are dependent on the MCM-41 nature and, to a lesser extent, on its content. Thus, differences in transitions of the PLLA matrix are noticed during cooling at 10 °C/min and in the subsequent heating when composites with neat or modified MCM-41 are compared. A very remarkable nucleation effect is played by pristine MCM-41, being inferior when MCM-41@Ag is incorporated into the PLLA. Wide angle X-ray scattering (WAXS) measurements using synchrotron radiation and performed under variable-temperature conditions in the composites containing MCM-41@Ag indicate that during cold crystallization, the disordered α′ polymorph is initially formed, but it rapidly transforms into ordered α crystals. A long spacing peak, clearly seen in pure PLLA, appears as a small shoulder in PLLAMCM@Ag4 and is undetectable in PLLAMCM@Ag9 and PLLAMCM@Ag20. Furthermore, an increase in MH with the silica content is found in the two sets of composites, the higher MH values being observed in the family of PLLA and MCM-41@Ag. Finally, remarkable antimicrobial features are noticeable in the composites with MCM-41@Ag since this modified silica transfers its biocidal characteristics into the PLLA composites.
Green Approaches on Modification of Xylan Hemicellulose to Enhance the Functional Properties for Food Packaging Materials—A Review
Authors: Nechita Petronela , Roman (Iana Roman) Mirela Roman (Iana Roman) , Năstac Silviu Marian
Published: April 2023

Based on the environmental concerns, the utilisation of hemicelluloses in food packaging has become a sustainable alternative to synthetic polymers and an important method for the efficient utilisation of biomass resources. After cellulose, hemicellulose is a second component of agricultural and forestry biomass that is being taken advantage of given its abundant source, biodegradability, nontoxicity and good biocompatibility. However, due to its special molecular structure and physical and chemical characteristics, the mechanical and barrier properties of hemicellulose films and coatings are not sufficient for food packaging applications and modification for performance enhancement is needed. Even though there are many studies on improving the hydrophobic properties of hemicelluloses, most do not meet environmental requirements and the chemical modification of these biopolymers is still a challenge. The present review examines emerging and green alternatives to acetylation for xylan hemicellulose in order to improve its performance, especially when it is used as biopolymer in paper coatings or films for food packaging. Ionic liquids (ILs) and enzymatic modification are environmentally friendly methods used to obtain xylan derivatives with improved thermal and mechanical properties as well as hydrophobic performances that are very important for food packaging materials. Once these novel and green methodologies of hemicellulose modifications become well understood and with validated results, their production on an industrial scale could be implemented. This paper will extend the area of hemicellulose applications and lead to the implementation of a sustainable alternative to petroleum-based products that will decrease the environmental impact of packaging materials.
Reinforcement of Injectable Hydrogel for Meniscus Tissue Engineering by Using Cellulose Nanofiber from Cassava Pulp
Authors: Jeencham Rachasit , Tawonsawatruk Tulyapruek , Numpaisal Piya-on , Ruksakulpiwat Yupaporn
Published: April 2023

Injectable hydrogels can be applied to treat damaged meniscus in minimally invasive conditions. Generally, injectable hydrogels can be prepared from various polymers such as polycaprolactone (PCL) and poly (N-isopropylacrylamide) (PNIPAAm). Poly (ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) block copolymer-diacrylate (PEO-PPO-PEO-DA) is an interesting polymer due to its biodegradability and can be prepared as water-insoluble injectable hydrogel after curing with UV light at low intensity. However, mechanical and cell adhesion properties are not optimal for these hydrogels. For the improved mechanical performance of the injectable hydrogel, cellulose nanofiber (CNF) extracted from cassava pulp was used as a reinforcing filler in this study. In addition, gelatin methacrylate (GelMA), the denatured form of collagen was used to enhance cell adhesion. PEO-PPO-PEO-DA/CNF/GelMA injectable hydrogels were prepared with 2-hydroxy-1-(4-(hydroxy ethoxy) phenyl)-2-methyl-1-propanone as a photoinitiator and then cured with UV light, 365 nm at 6 mW/cm2. Physicochemical characteristics of the hydrogels and hydrogels with CNF were studied in detail including morphology characterization, pore size diameter, porosity, mechanical properties, water uptake, and swelling. In addition, cell viability was also studied. CNF-reinforced injectable hydrogels were successfully prepared after curing with UV light within 10 min with a thickness of 2 mm. CNF significantly improved the mechanical characteristics of injectable hydrogels. The incorporation of GelMA into the injectable hydrogels improved the viability of human cartilage stem/progenitor cells. At optimum formulation, 12%PEO-PPO-PEO-DA/0.5%CNF/3%GelMA injectable hydrogels significantly promoted cell viability (>80%) and also showed good physicochemical properties, which met tissue engineering requirements. In summary, this work shows that these novel injectable hydrogels have the potential for meniscus tissue engineering.
A Flexible and Highly Sensitive Pressure Sense Electrode Based on Cotton Pulp for Wearable Electronics
Authors: Jia Mengying , Wang Meng , Zhou Yucheng
Published: April 2023

Flexible pressure sensors with high sensitivity have great potential applications in wearable electronics. However, it is still a great challenge to prepare sense electrodes with high flexibility, high sensitivity, and high electrochemical performance. Here, we propose a novel and simple method for carbonizing cotton fibers as excellent electrically conductive materials. Moreover, carbonized cotton fiber (CCF) and polydimethylsiloxane (PDMS) were assembled into a flexible sense electrode. The CCF/PDMS electrode shows a high sensitivity of 10.8 kPa−1, a wide response frequency from 0.2–2.0 Hz, and durability over 900 cycles. The combined CCF/PDMS sensors can monitor human movement and pulse vibration, showing the enormous potential for use in wearable device technology. Additionally, the CCF/PDMS can be used as electrodes with a specific capacitance of 332.5 mF cm−2 at a current density of 5 mA cm−2, thanks to their high electrical conductivity and hydrophilicity, demonstrating the promising prospect of flexible supercapacitors.
Photooxidative Behavior of Polystyrene Nanocomposites Filled with Two-Dimensional Molybdenum Disulfide
Authors: Angulo Aurianny Lima , Rodriguez Camila Laura Celis , Fechine Guilhermino José Macedo
Published: April 2023

This study aimed to investigate how an ultralow content of a molybdenum disulfide (MoS2) two-dimensional particle affects the photodegradation mechanism of polystyrene (PS). Here, an accelerated weathering study was presented on neat polystyrene and its nanocomposites produced with 0.001, 0.002, 0.003 and 0.005 wt% of molybdenum disulfide (MoS2) exposed for various irradiation intervals (up to 8 weeks). The polymer photo-transformations were monitored using size exclusion chromatography (SEC), infrared spectroscopy (FTIR), and UV-Vis spectroscopy. The FTIR and UV/Vis results indicate that the PS degradation mechanism was not altered by the presence of MoS2 particles; however, the degradation reactions were slowed down at higher MoS2 contents (>0.003%). The SEC results proved the stabilizer effect due to MoS2 particles, where M¯n, M¯w, and M¯w/M¯n values after 8 weeks were less modified when compared with the neat PS results. The MoS2 acted as a UV stabilizer, and these two-dimensional particles acted by deactivating the free radicals generated by the PS matrix, even considering the low amount of the filler (<0.005 wt%).
Thermal and Viscoelastic Responses of Selected Lignocellulosic Wastes: Similarities and Differences
Authors: Ionita Daniela , Cristea Mariana , Cosmulescu Susana Felicia , Predeanu Georgeta , Harabagiu Valeria , Samoila Petrisor
Published: April 2023

Woody lignocellulosic biomasses comprise the non-edible parts of fruit trees. In recent years, the exploitation of this biomass has been widening in order to mitigate environmental issues. At the same time, this waste could be transformed into a value-added product (active carbon by pyrolysis, isolation of nanocellulose, oils or proteins). For either valorization path, a complete thermo-mechanical characterization is required. A detailed thermo-mechanical study (TGA, DSC, DMA) was performed on two types of lignocellulosic wastes, with and without kernels: on one side, the walnut shells (WS) and the pistachio shells (PsS) and, in the second category, the apricot seeds (AS), the date seeds (DS), and the plum seeds (PS). The results of the sample-controlled thermal analyses (HiRes TGA) evidenced a better resolution of the degradation steps of WS. Kinetic studies conducted also by conventional TGA (Flynn–Wall–Ozawa) and modulated TGA (MTGA) allowed us to make comparative reasonings concerning the degradation of the investigated biomasses. The DMA results revealed the effect of water traces and oil kernels on relaxation and supported the atypical DSC endotherm emphasized in the freezing temperature domain.
Electromagnetic Shielding Enhancement of Butyl Rubber/Single-Walled Carbon Nanotube Composites via Water-Induced Modification
Authors: Guo Xin , Liu Guangye
Published: April 2023

Electromagnetic properties of polymer composites strongly depend on the loading amount and the completeness of the filler’s dispersive structure. Improving the compatibility of single-walled carbon nanotubes (SWCNTs) with isobutylene butyl rubber (IIR) is a good solution to mitigate aggregation. The change in configuration of poly-oxyethylene octyl phenol ether (OP-10) was induced using water as the exposed hydrophilic groups linking with water molecules. The SWCNT and IIR/SWCNT composites were then prepared via wetly-melt mixing at a relatively high temperature to remove water, and they were then mixed with other agents after vacuum drying and cured. The SWCNTs were dispersed uniformly to form a good network for a lower percolation threshold of the wave-absorbing property to 2 phr from 8 phr. With 8 phr SWCNTs, the tensile strength of the material improved significantly from 7.1 MPa to 15.1 MPa, and the total electromagnetic shielding effectiveness of the material was enhanced to 23.8 dB, a 3-fold increase compared to the melt-mixed material. It was demonstrated that water-induced modification achieved good dispersion of SWCNTs for electromagnetic shielding enhancement while maintaining a wide damping temperature range from −55 °C to 40 °C with a damping factor over 0.2.
In Vitro Fermentation of Hyaluronan with Different Molecular Weights by Human Gut Microbiota: Differential Effects on Gut Microbiota Structure and Metabolic Function
Authors: Zhao Ruohan , Zhang Chuan , Yu Leilei , Zhang Chengcheng , Zhao Jianxin , Narbad Arjan , Zhai Qixiao , Tian Fengwei
Published: April 2023

Hyaluronan (HA) has various biological functions and is used extensively as a dietary supplement. Previous studies have shown that the probiotic effects of polysaccharides are closely associated with their molecular properties. The intestinal microbiota has been demonstrated to degrade HA; however, the regulatory effects of different molecular weights (MW) of HA on gut microbiota and metabolites are unknown. In the present study, we performed in vitro fermentation of human-derived feces for three MWs of HA (HA1, 32.3 kDa; HA2, 411 kDa; and HA3, 1510 kDa) to investigate the differences in the fermentation properties of HA with different MWs. We found that gut microbiota can utilize all HAs and, consequently, produce large amounts of short-chain fatty acids (SCFAs). In addition, we showed that all three HA MWs promoted the growth of Bacteroides, Parabacteroides, and Faecalibacterium, with HA1 being more effective at promoting the growth of Bacteroides. HAs have various regulatory effects on the structure and metabolites of the gut microbiota. Spearman’s correlation analysis revealed that alterations in gut microbiota and their metabolites were significantly correlated with changes in metabolic markers. For instance, HA1 enriched α-eleostearic acid and DL-3-aminoisobutyric acid by regulating the abundance of Bacteroides, and HA3 enriched Thymidin by regulating Faecalibacterium. Collectively, the fermentation properties of HA vary across MW, and our results provide insights into the potential association between the MW of HA and its fermentation characteristics by the gut microbiota. These findings provide insights into the influence of the gut microbiota and HAs on the health of the host.
Co-Plasticization of Starch with Glycerol and Isosorbide: Effect on Retrogradation in Thermo-Plastic Cassava Starch Films
Authors: Gómez-López Rudy A. , Montilla-Buitrago Camilo E. , Villada-Castillo Héctor S. , Sáenz-Galindo Aidé , Avalos-Belmontes Felipe , Serna-Cock Liliana
Published: April 2023

Thermoplastic starch (TPS) has emerged as an essential alternative to produce environmentally friendly packaging; however, retrogradation is a disadvantage that affects its shelf life. This study analyzed the co-plasticizing effect of isosorbide on the mechanical, thermal, physicochemical, and microstructural properties and the retrogradation of films obtained by blown film extrusion from thermoplasticized starch with mixtures of glycerol and isosorbide in different ratios (3:0, 2:1, 1:2, and 0:3, respectively). The results showed that the higher concentration of isosorbide significantly increased the tensile strength; however, it reduced the elongation. Retrogradation modeled using the Avrami equation showed that the presence of isosorbide reduced the retrogradation rate (k) and modified the recrystallization mechanism (n). The relative crystallinity in the plasticized TPS films was reduced to 89%, and the adsorption significantly decreased. Isosorbide was very important in reducing the retrogradation of TPS. The best performance was obtained with the 2:1 ratio of glycerol/isosorbide due to the synergistic effect between the plasticizers. The results would allow tuning the properties of TPS films by combining glycerol/isosorbide in different ratios, which enables the design of materials tailored to potential application requirements.
Pyroresistive Properties of Composites Based on HDPE and Carbon Fillers
Authors: Mamunya Yevgen , Maruzhenko Oleksii , Kolisnyk Roman , Iurzhenko Maksym , Pylypenko Andrii , Masiuchok Olha , Godzierz Marcin , Krivtsun Igor , Trzebicka Barbara , Pruvost Sébastien
Published: April 2023

Electrothermal processes were studied in pyroresistive composites based on high-density polyethylene (HDPE) containing 8 vol.% carbon black (CB), 8 vol.% carbon fibers (CF), and their mixture 4 vol.% CB + 4 vol.% CF. It is shown that the kinetic heating curves of composites are well described by an exponential dependence with a certain heating rate constant k for each type of composite. After a short heating time, the equilibrium temperature Te is reached in the sample. When the applied voltage exceeds a certain value, the Te value decreases due to the presence of the positive temperature coefficient of resistance (PTC) effect. Due to the PTC effect, the composites exhibit a self-regulating effect relative to the Te. Relations between the applied voltage, electric power, and equilibrium temperature are found, the Te value depends on the applied voltage according to the quadratic law whereas there is a linear relationship between the Te and electric power. A possible application of such pyroresistive composites is resistance welding of plastics using a heating element (HE) made of a pyroresistive material. The use of HDPE-CB composite to create HE for resistance welding is demonstrated and the welded joint of HDPE parts obtained using HE is shown.
Advances in Molecular Imprinting Technology for the Extraction and Detection of Quercetin in Plants
Authors: Ye Kexi , Xu Shufang , Zhou Qingqing , Wang Sitao , Xu Zhigang , Liu Zhimin
Published: April 2023

Quercetin is a kind of flavonoid compound, which has antioxidative, anti-aging and anti-cancer effects, so it is of great importance to study the efficient extraction and highly sensitive detection of quercetin. Molecular imprinting technology has remarkable selectivity and resistance to complex matrix interference, which is often used for extracting quercetin. The methods of molecular imprinted solid phase extraction, molecularly imprinted microsphere extraction, molecularly imprinted electrochemical sensor recognition and molecularly imprinted composite material extraction of quercetin from plant samples were discussed in detail. This review provides valuable information on efficient and sensitive methods for separating and purifying quercetin in plants. It also provides a technical reference for further investigation of the separation and analysis of active ingredients in natural products.
Sulfonated PAM/PPy Cryogels with Lowered Evaporation Enthalpy for Highly Efficient Photothermal Water Evaporation
Authors: Hou Shi-Chang , Zhang Dao-Wei , Chen Jun , Guo Xiao-Xiao , Haleem Abdul , He Wei-Dong
Published: April 2023

Because of the increasing scarcity of water resources, the desalination of seawater by photothermal evaporation with harvested solar energy has gradually become a popular research topic. The interconnected macroporous cryogel prepared from polymerization and crosslinking below the freezing temperature of the reactant solution has an excellent performance in photothermal water evaporation after loading photothermal materials. In this study, polyacrylamide (PAM) cryogels were prepared by cryo-polymerization and sulfonated in an alkaline solution containing formaldehyde and Na2SO3. Importantly, the evaporation enthalpy of water in sulfonated PAM cryogel was reduced to 1187 J·g−1 due to the introduction of sulfonate groups into PAM, which was beneficial to increase the photothermal evaporation rate and efficiency. The sulfonated PAM cryogels loaded with polypyrrole and the umbrella-shaped melamine foam substrate were combined to form a photothermal evaporation device, and the evaporation rate was as high as 2.50 kg·m−2·h−1 under one-sun radiation. Meanwhile, the evaporation rate reached 2.09 kg·m−2·h−1 in the 14 wt% high-concentration saline solution, and no salt crystals appeared on the surface of the cryogel after 5 h of photothermal evaporation. Therefore, it was evidenced that the presence of sulfonate groups not only reduced the evaporation enthalpy of water but also prevented salting-out from blocking the water delivery channel during photothermal evaporation, with a sufficiently high evaporation rate, providing a reliable idea of matrix modification for the design of high-efficiency photothermal evaporation materials.
Preserving the Ephemeral: A Micro-Invasive Study on a Set of Polyurethane Scenic Objects from the 1960s and 1970s
Authors: Costantini Rosa , Nodari Luca , La Nasa Jacopo , Modugno Francesca , Bonasera Lucia , Rago Sara , Zoleo Alfonso , Legnaioli Stefano , Tomasin Patrizia
Published: April 2023

Among the innovative materials used by 20th-century artists, polyurethane (PUR) has been shown to be highly unstable, and therefore artworks made of it are now in need of careful conservation strategies. This study presents a multi-analytical investigation of PUR foam scenic objects originally made between the 1960s and 1970s during the Italian Arte Viva movement. The main components in the foam and additives were characterized through micro attenuated total reflectance infrared spectroscopy (μ-ATR-FTIR) and pyrolysis coupled with gas chromatography and mass spectrometry (Py-GC/MS). Painted samples were further investigated through μ-FTIR and Raman spectroscopy to define binders and pigments. The use of μ-ATR-FTIR in combination with evolved gas analysis-mass spectrometry (EGA-MS) allowed the variable conditions of the artworks to be assessed and attained some insights into the chemical processes responsible for aging. At the same time, morphological changes due to the degradation phenomena were recorded through optical (OM) and scanning electron microscopy (SEM). The detailed characterization of the PUR foam and painting materials was helpful in attaining some insights into harmful environmental parameters for the artworks, thus informing preventive conservation.
Design of Suspended Slot Racetrack Microring Refractive Index Sensor Based on Polymer Nanocomposite
Authors: Wu Xihan , Wang Jiajun , Han Jiachen , Xie Yuqi , Ge Xuyang , Liao Jianzhi , Yi Yunji
Published: April 2023

Recently, polymer nanocomposites have attracted great interest due to their remarkable characteristics of high performance and enabling production of low-cost devices. This article explores the reflective index sensing application of the polymer nanocomposite IOC-133, which is a TiOx/polymer nanocomposite with a reflective index between 1.8 and 1.9. Considering the material properties of high reflective index, low absorption loss, and compatibility with nanoimprint lithography, a microring-based reflective index sensor with a suspended slot waveguide structure is proposed. We combined the sensing mechanism of slot waveguides with high reflective index polymer nanocomposites and designed the suspended structure to address the problem of decreasing sensitivity caused by residual layers. The sensing device was adopted as a microring resonator, which is conducive to large-scale integration. The finite-difference time-domain (FDTD) method was employed to analyze the effects of several key parameters. The results showed that the racetrack microring sensor we propose can achieve a high sensitivity of 436 nm/RIU (Refractive Index Units), about six times higher than the microring sensor with a ridge waveguide. The Q factor of the microring reaches 1.42 × 104, and the detection limit is 1.38 × 10−4 RIU. The proposed suspended slot microring sensor has potential value in the field of nanoprinted photonic integrated circuits.
On the Fractionation and Physicochemical Characterisation of Self-Assembled Chitosan–DNA Polyelectrolyte Complexes
Authors: Sajid Ayesha , Castronovo Matteo , Goycoolea Francisco M.
Published: April 2023

Chitosan is extensively studied as a carrier for gene delivery and is an attractive non-viral gene vector owing to its polycationic, biodegradable, and biocompatible nature. Thus, it is essential to understand the chemistry of self-assembled chitosan–DNA complexation and their structural and functional properties, enabling the formation of an effective non-viral gene delivery system. In this study, two parent chitosans (samples NAS-032 and NAS-075; Mw range ~118–164 kDa) and their depolymerised derivatives (deploy nas-032 and deploy nas-075; Mw range 6–14 kDa) with degrees of acetylation 43.4 and 4.7%, respectively, were used to form polyelectrolyte complexes (PECs) with DNA at varying [–NH3+]/[–PO4−] (N/P) molar charge ratios. We investigated the formation of the PECs using ζ-potential, asymmetric flow field-flow fractionation (AF4) coupled with multiangle light scattering (MALS), refractive index (RI), ultraviolet (UV) and dynamic light scattering (DLS) detectors, and TEM imaging. PEC formation was confirmed by ζ-potential measurements that shifted from negative to positive values at N/P ratio ~2. The radius of gyration (Rg) was determined for the eluting fractions by AF4-MALS-RI-UV, while the corresponding hydrodynamic radius (Rh), by the DLS data. We studied the influence of different cross-flow rates on AF4 elution patterns for PECs obtained at N/P ratios 5, 10, and 20. The determined rho shape factor (ρ = Rg/Rh) values for the various PECs corresponded with a sphere morphology (ρ ~0.77–0.85), which was consistent with TEM images. The results of this study represent a further step towards the characterisation of chitosan–DNA PECs by the use of multi-detection AF4 as an important tool to fractionate and infer aspects of their morphology.
Control Mechanism of Microbial Degradation on the Physical Properties of a Coal Reservoir
Authors: Xia Daping , Gu Pengtao , Chen Zhenhong , Chen Linyong , Wei Guoqin , Wang Zhenzhi , Cheng Song , Zhang Yawei
Published: April 2023

This study addressed the effect of microbial methane production on the physical properties of a coal reservoir. Two kinds of coal samples before and after anaerobic degradation were tested by a low-temperature liquid nitrogen adsorption test and an isothermal adsorption and diffusion coefficient test. The influence of the characteristics of microbial gas production on the coal physical properties was analyzed. Due to the differences in the physical properties of the coal samples, the effect of microbial production is different. Coal is a macromolecular organic compound, mainly aromatic and lignin derivatives, containing carbon and nitrogen sources that can be used by microorganisms. Microorganisms secrete extracellular enzymes to decompose covalent bonds and functional groups of macromolecules in coal and eventually produce methane, which will change the physical properties of coal. It was found that microbial anaerobic degradation could increase the content of coalbed methane, change the pore structure of coal, reduce the fractal dimension of the coal surface and smooth the coal surface. At the same time, microbial degradation has changed the physical properties of coal reservoirs to some extent, increased the diffusion of coal reservoirs and improved the pore connectivity of coal reservoirs, which provides more of a scientific basis for the development of coalbed methane.
Experimental Study on Ratio Optimization of Similar Materials for Underground Mining of Shendong Coalfield: A Case Study of Shangwan Coal Mine
Authors: Yang Yingming , Yue Hao , Zhao Yongqiang , Zhang Shen , Zhang Jian , Wang Zhaohui , Yang Wenqiang
Published: April 2023

Physical simulation is one of the effective methods to study mining problems, but the selection and proportion of simulation materials are greatly affected by the regional environment. This paper is based on a multilevel orthogonal design test scheme using sand, lime, and gypsum as the materials in the Shangwan coal mine in the Shendong coalfield, with the sand to cement ratio, paste to ash ratio, and maintenance days as variables. The effect of the polar difference method on the strength and density of gypsum was used as a reference for physical simulation in the Shendong coalfield. The sensitivity analysis of each factor was carried out by the polar difference method, and the influencing factors on density were, in descending order, sand to mortar ratio, mortar to ash ratio, and the number of maintenance days; the influencing factors on strength were, in descending order, mortar to ash ratio, maintenance days, and sand to mortar ratio. The sand cement ratio was negatively correlated with strength and density, the paste to ash ratio was positively correlated with strength and density, and the number of maintenance days was positively correlated with strength and negatively correlated with density. The multivariate non-linear regression analysis of sand to cement ratio and paste to ash ratio identified similar material proportioning test equations for the Shendong coalfield, which can improve the accuracy of physical simulation and be used to guide physical simulation experiments in the Shendong coalfield.
Highly Dispersed and Stable Ni/SiO2 Catalysts Prepared by Urea-Assisted Impregnation Method for Reverse Water–Gas Shift Reaction
Authors: Liu Ning , Cui Sha , Jin Zheyu , Cao Zhong , Liu Hui , Yang Shuqing , Zheng Xianmin , Wang Luhui
Published: April 2023

The nickel-based catalyst was more active in the reverse water-gas shift reaction, but it is easy to sinter and deactivate in high temperature reaction (≥600 °C). A urea-assisted impregnation method was utilized to create a Ni/SiO2-N catalyst to increase the catalytic stability of Ni-based catalysts. For at least 20 h, the Ni/SiO2-N catalyst in the reverse water-gas shift process at 700 °C remained stable, and in the high temperature RWGS reaction, the conversion rate of CO2 of the catalyst is close to the equilibrium conversion rate. The catalysts were characterized by BET, XRD, H2-TPR, and TEM, and the results demonstrate that the Ni particles had a small particle size and exhibited strong interaction with the SiO2 support in the Ni/SiO2-N catalyst, which led to the catalyst’s good activity and stability. Urea-assisted impregnation is a facile method to prepare stable Ni/SiO2 catalysts with high Ni dispersion.
Anti-Overturning Capability and Fuzzy PID Speed Control for Four-Way Shuttle Vehicles in Processed Grain Storage
Authors: Li Li , Wu Zhaoyun , Zhang Zhongwei , Zhang Yulan
Published: April 2023

As the four-way shuttle vehicle is prone to overturning in finished grain storage during acceleration and deceleration, an overturning mechanical model is constructed. The design factors analyzed include grain bag height, vehicle and grain bag mass, and the type of grain’s effect on the vehicle’s anti-overturning stability. The critical overturning condition of the shuttle vehicle during operation is also determined as a result of this analysis. With the critical overturning condition, the speed control of the shuttle vehicle based on the fuzzy PID method is carried out to improve the anti-overturning stability. Significant details are made about the fuzzification of input and output variables, determination of membership function, establishment of the fuzzy rule base, fuzzy reasoning, and defuzzification. Finally, the comparative simulation model of fuzzy PID and conventional PID in the MATLAB/Simulink platform showed that the fuzzy PID control method had the advantages of fast convergence and quick response to the speed control of the four-way shuttle vehicle.
Exploring Approaches for Estimating Parameters in Cognitive Diagnosis Models with Small Sample Sizes
Authors: Sorrel Miguel A. , Escudero Scarlett , Nájera Pablo , Kreitchmann Rodrigo S. , Vázquez-Lira Ramsés
Published: April 2023

Cognitive diagnostic models (CDMs) are increasingly being used in various assessment contexts to identify cognitive processes and provide tailored feedback. However, the most commonly used estimation method for CDMs, marginal maximum likelihood estimation with Expectation–Maximization (MMLE-EM), can present difficulties when sample sizes are small. This study compares the results of different estimation methods for CDMs under varying sample sizes using simulated and empirical data. The methods compared include MMLE-EM, Bayes modal, Markov chain Monte Carlo, a non-parametric method, and a parsimonious parametric model such as Restricted DINA. We varied the sample size, and assessed the bias in the estimation of item parameters, the precision in attribute classification, the bias in the reliability estimate, and computational cost. The findings suggest that alternative estimation methods are preferred over MMLE-EM under low sample-size conditions, whereas comparable results are obtained under large sample-size conditions. Practitioners should consider using alternative estimation methods when working with small samples to obtain more accurate estimates of CDM parameters. This study aims to maximize the potential of CDMs by providing guidance on the estimation of the parameters.
The Open Systems View and the Everett Interpretation
Authors: Cuffaro Michael E. , Hartmann Stephan
Published: April 2023

It is argued that those who defend the Everett, or ‘many-worlds’, interpretation of quantum mechanics should embrace what we call the general quantum theory of open systems (GT) as the proper framework in which to conduct foundational and philosophical investigations in quantum physics. GT is a wider dynamical framework than its alternative, standard quantum theory (ST). This is true even though GT makes no modifications to the quantum formalism. GT rather takes a different view, what we call the open systems view, of the formalism; i.e., in GT, the dynamics of systems whose physical states are fundamentally represented by density operators are represented as fundamentally open as specified by an in general non-unitary dynamical map. This includes, in principle, the dynamics of the universe as a whole. We argue that the more general dynamics describable in GT can be physically motivated, that there is as much prima facie empirical support for GT as there is for ST, and that GT could be fully in the spirit of the Everett interpretation—that there might, in short, be little reason for an Everettian not to embrace the more general theoretical landscape that GT allows one to explore.
Doing Dialogue Differently: Queer Interfaith Perspective
Authors: Aye Inatoli
Published: April 2023

This paper attempts to bring queer perspectives to interfaith dialogue in India. It will first consider what is interfaith dialogue and will situate interfaith dialogue within the framework of a theology of religions and a theology of missions. It will then offer an evaluation of some works accomplished by National Council of Churches in India with regard to the question of interfaith dialogue and sexuality. Finally, it will look at whether Christians in interfaith dialogue can learn anything from a queer reading of Hindu sacred texts.
Female Apostle(s) at the Roots of Christianity
Authors: Thorsteinsson Runar M.
Published: April 2023

There is an increasing demand for the ordination of women as priests within the Roman Catholic Church. The Vatican’s primary argument against priestly ordination of women is biblical, appealing to certain historical events, specifically Jesus’ (alleged) choice of male apostles only. This article calls for a rethinking and rephrasing of such appeal to history. Due to the nature of our sources, the historically responsible question should not be whom Jesus appointed as apostles, but who were apostles in first-century Christianity. The article points out flaws in the Vatican’s reasoning in this respect and brings attention to evidence from earliest Christianity that does indeed speak in favor of women as priests, if an appeal is to be made to history in the first place. The evidence is Junia, a first-century female apostle, described as “prominent among the apostles” by the apostle Paul in his Letter to the Romans.
Research Progress, Hotspots, and Evolution of Nighttime Light Pollution: Analysis Based on WOS Database and Remote Sensing Data
Authors: Huang Chenhao , Ye Yang , Jin Yanhua , Liang Bangli
Published: April 2023

With the rapid development of the global economy, the over-expansion of outdoor artificial light at night (ALAN) in cities has led to increasingly severe light pollution worldwide. More and more studies have paid attention to the problem of light pollution, but there is still a lack of systematic literature review on nighttime light pollution in terms of research progress, hotspots, and its evolutions. For this purpose, this study firstly analyzed current research actuality and trends about nighttime light pollution via a comprehensive retrospect of pertinent literature and summarized the adverse effects and monitoring technologies of light pollution by VOSviewer-based keyword co-occurrence technique. Additionally, the study explored the variation tendency of nighttime light pollution in typical countries from 2013 to 2021 based on remote-sensing data and further proposed management suggestions to protect the nighttime environment. The results indicate that the research popularity of nighttime light pollution has been increasing recently, especially after the opening of diversified remote-sensing data in 2012; the main research topics are dominated by adverse effects and monitoring technologies, where the latter is represented by ground survey and remote-sensing observation; the total levels of ALAN intensity are relatively high in most developed countries, but the mean and per capita values are decreasing, and the above phenomenon in developing countries show the opposite trend. This study expects to integrate the literature analysis method and remote-sensing data to demonstrate the research status and variation trends of nighttime light pollution systematically so as to provide scientific references for the assessment and management of the nighttime light environment.