bluuebunny/crossref_metadata_2025 huggingface dataset:
A Systematic Review of the Effectiveness of Non-Invasive Brain Stimulation Techniques to Reduce Violence Proneness by Interfering in Anger and Irritability
Authors: Romero-Martínez Ángel , Bressanutti Sara , Moya-Albiol Luis
Published: March 2020

The field of neurocriminology has proposed several treatments (e.g., pharmacological, brain surgery, androgen-deprivation therapy, neurofeedback) to reduce violence proneness, but unfortunately, their effectiveness has been limited due to their side-effects. Therefore, it is necessary to explore alternative techniques to improve patients’ behavioural regulation with minimal undesirable effects. In this regard, non-invasive brain stimulation techniques, which are based on applying changing magnetic fields or electric currents to interfere with cortical excitability, have revealed their usefulness in alleviating the symptomatology of several mental disorders. However, to our knowledge, there are no reviews that assess whether these techniques are useful for reducing violence proneness. Therefore, we conducted a systematic review following Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) criteria using the following databases: PsycINFO, PubMed, Dialnet, Psicodoc, Web of Knowledge, and the Cochrane Library. We initially identified 3746 entries, and eventually included 56 publications. Most of the studies were unanimous in concluding that the application of these techniques over the prefrontal cortex (PFC) was not sufficient to promote anger and irritability reductions in euthymic individuals of both genders. Nevertheless, the application of non-invasive brain stimulation techniques, especially transcranial direct current stimulation, over the right PFC seemed to reduce violent reactions in these individuals by interfering with the interpretation of the unfavourable situations (e.g., threating signals) or inner states that evoked anger. In antisocial and pathological populations, the conclusions were provided by a few pilot studies with important methodological weaknesses. The main conclusion of these studies was that bilateral stimulation of the PFC satisfactorily reduced anger and irritability only in inmates, patients with autism spectrum disorders (ASD), people who suffered a closed-head injury, and agitated patients with Alzheimer’s disease. Moreover, combining these techniques with risperidone considerably reduced aggressiveness in these patients. Therefore, it is necessary to be cautious about the benefits of these techniques to control anger, due the methodological weaknesses of these studies. Nonetheless, they offer valuable opportunities to prevent violence by designing new treatments combining brain stimulation with current strategies, such as psychotherapy and psychopharmacology, in order to promote lasting changes.
Changes in the Retinal Microvasculature Measured Using Optical Coherence Tomography Angiography According to Age
Authors: Park Seung Hun , Cho Heeyoon , Hwang Sun Jin , Jeon Beomseo , Seong Mincheol , Yeom Hosuck , Kang Min Ho , Lim Han Woong , Shin Yong Un
Published: March 2020

In this cross-sectional study, we examined age-related changes in the retinal vessels of 100 healthy participants, aged from 5 to 80 years, and divided into four groups (G1, under 20 years of age; G2, from 20 to 39 years of age; G3, from 40 to 59 years of age; G4, age 60 years or older). All subjects underwent swept-source optical coherence tomography (SS-OCT) and OCT angiography (OCTA). The vascular density (VD) of the superficial (SCP) and deep capillary plexus (DCP), and choriocapillaris (CCP) were measured using OCTA. The vascular density of each capillary layer, foveal avascular zone (FAZ) area, ganglion cell-inner plexiform layer (GC-IPL) thickness, retinal thickness (RT), and choroidal thickness (CT) were compared between age groups. Most OCT variables were correlated with OCTA variables. The FAZ area; VD of the SCP, DCP, and CCP; GC-IPL thickness; RT; and CT showed significant difference (p < 0.001) between G1 + G2 and G3 + G4, except for central GC-IPL thickness (p = 0.14) and central RT (p = 0.25). Density of the retinal capillary vasculature reduced and FAZ area increased after age 40, which represents the onset of middle age.
Novel Biomarkers in Patients with Chronic Kidney Disease: An Analysis of Patients Enrolled in the GCKD-Study
Authors: Mirna Moritz , Topf Albert , Wernly Bernhard , Rezar Richard , Paar Vera , Jung Christian , Salmhofer Hermann , Kopp Kristen , Hoppe Uta C. , Schulze P. Christian , Kretzschmar Daniel , Schneider Markus P. , Schultheiss Ulla T. , Sommerer Claudia , Paul Katharina , Wolf Gunter , Lichtenauer Michael , Busch Martin
Published: March 2020

Background: Chronic kidney disease (CKD) and cardiovascular diseases (CVD) often occur concomitantly, and CKD is a major risk factor for cardiovascular mortality. Since some of the most commonly used biomarkers in CVD are permanently elevated in patients with CKD, novel biomarkers are warranted for clinical practice. Methods: Plasma concentrations of five cardiovascular biomarkers (soluble suppression of tumorigenicity (sST2), growth differentiation factor 15 (GDF-15), heart-type fatty acid-binding protein (H-FABP), insulin-like growth factor-binding protein 2 (IGF-BP2), and soluble urokinase plasminogen activator receptor) were analyzed by means of enzyme-linked immunosorbent assay (ELISA) in 219 patients with CKD enrolled in the German Chronic Kidney Disease (GCKD) study. Results: Except for sST2, all of the investigated biomarkers were significantly elevated in patients with CKD (2.0- to 4.4-fold increase in advanced CKD (estimated glomerular filtration rate (eGFR) < 30 mL/min/1.73 m² body surface area (BSA)) and showed a significant inverse correlation with eGFR. Moreover, all but H-FABP and sST2 were additionally elevated in patients with micro- and macro-albuminuria. Conclusions: Based on our findings, sST2 appears to be the biomarker whose diagnostic performance is least affected by decreased renal function, thus suggesting potential viability in the management of patients with CVD and concomitant CKD. The predictive potential of sST2 remains to be proven in endpoint studies.
Mitophagy in Cardiovascular Diseases
Authors: Morciano Giampaolo , Patergnani Simone , Bonora Massimo , Pedriali Gaia , Tarocco Anna , Bouhamida Esmaa , Marchi Saverio , Ancora Gina , Anania Gabriele , Wieckowski Mariusz R. , Giorgi Carlotta , Pinton Paolo
Published: March 2020

Cardiovascular diseases are one of the leading causes of death. Increasing evidence has shown that pharmacological or genetic targeting of mitochondria can ameliorate each stage of these pathologies, which are strongly associated with mitochondrial dysfunction. Removal of inefficient and dysfunctional mitochondria through the process of mitophagy has been reported to be essential for meeting the energetic requirements and maintaining the biochemical homeostasis of cells. This process is useful for counteracting the negative phenotypic changes that occur during cardiovascular diseases, and understanding the molecular players involved might be crucial for the development of potential therapies. Here, we summarize the current knowledge on mitophagy (and autophagy) mechanisms in the context of heart disease with an important focus on atherosclerosis, ischemic heart disease, cardiomyopathies, heart failure, hypertension, arrhythmia, congenital heart disease and peripheral vascular disease. We aim to provide a complete background on the mechanisms of action of this mitochondrial quality control process in cardiology and in cardiac surgery by also reviewing studies on the use of known compounds able to modulate mitophagy for cardioprotective purposes.
Model Structures and Identification for Fully Embedded Thrusters: 360-Degrees-Steerable Steering-Grid and Four-Channel Thrusters
Authors: Peeters Gerben , Afzal Muhammad Raheel , Vanierschot Maarten , Boonen René , Slaets Peter
Published: March 2020

The European Watertruck + project introduced a new fleet of self-propelled inland cargo barges to the European waters, in order to induce more sustainable freight transport in the European hinterland. An augmentation of the automation level of this fleet could further advance their competitiveness and potentially pave the way for unmanned inland cargo vessels. The motion control of such a vessel forms a key component in this envisaged automation chain and benefits from the knowledge of the capabilities of the propulsion system, which here envelops a 360-degrees-steerable steering-grid thruster in conjunction with a 360-degrees-steerable four-channel thruster. Therefore, this study details the mechanical design of both thrusters and lists their experimental towing-tank data. Furthermore, two different modelling methods are offered, one theoretically based and one using a multilayer neural network. A model structure comparison, based on a bias-variance trade-off, verifies the adequacy of the theoretical model which got expended with an angle-dependent thrust deduction coefficient. In addition, several multilayer feedforward neural network architectures exemplify their inherent capability to model the complex, nonlinear, flow phenomena inside the thrusters. These identified model structures can additionally improve thrust allocation algorithms and offer better plant models to study more advanced control strategies.
Potential Hydrodynamic Impacts and Performances of Commercial-Scale Turbine Arrays in the Strait of Larantuka, Indonesia
Authors: Orhan Kadir , Mayerle Roberto
Published: March 2020

The Strait of Larantuka, with highly energetic tidal stream currents reaching speeds of up to 3–4 m/s, is a promising site for renewable electricity production from the ocean. This paper presents the results of an assessment regarding the potential hydrodynamic impacts, wake characteristics, and the performances of large scale turbine arrays in the strait. A high-resolution, three-dimensional baroclinic model is developed using the FLOW module of the Delft3D modeling system to simulate tidal currents. The energy of currents is assumed to be extracted by horizontal-axis tidal turbines, which can harness strong bi-directional flow, positioned on sequential rows and alternating downstream arrangements. Enhanced momentum sinks are used to represent the influence of energy extraction by the tidal turbines. Four different array layouts with rated capacities of up to 35 MW are considered. We find that, in the Strait of Larantuka, array layout significantly affects the flow conditions and the power output, mainly due to the geometric blockage effect of the bounded channel. With respect to undisturbed flow conditions in the strait, decreases in current speeds of up to about 0.6 m/s, alongside increases in the order of 80% near-shore are observed. While operating efficiency rates of turbines reaching around 50%–60% resulted during the spring tide in the arrays with smaller rated capacities, the power output of the devices was negligible during the neap tide.
Land Use Change, Spatial Interaction, and Sustainable Development in the Metropolitan Urban Areas, South Sulawesi Province, Indonesia
Authors: Surya Batara , Ahmad Despry Nur Annisa , Sakti Harry Hardian , Sahban Hernita
Published: March 2020

Metropolitan Urban Mamminasata South Sulawesi, Indonesia as the object of study is explored in the core-peripheral spatial interaction towards the formation of suburban service centers. The problems raised in this study are (i) is there a relationship/correlation between spatial integration, spatial interaction, and urban agglomeration to the formation of urban activity systems and (ii) how the formation of urban activity systems works as a determinant of economic growth, land use change and environmental quality degradation towards sustainable development in the metropolitan city of Mamminasata. Comparative studies of suburban areas have been carried out over three time periods (2001, 2015 and 2019). Data elaboration on observations, surveys and documentation is done to describe urban dynamics in terms of economic, social and environmental aspects. Path analysis is used to address direct effects, indirect effects, differences, and dependencies between urban elements. The gravity model is used to analyze the spatial interactions of the core city with the periphery. The study results show that spatial integration, spatial interaction and urban agglomeration have a positive effect on the system of urban activity and economic growth in the outskirts of the Mamminasata Metropolitan area. The results of this study recommend policy makers and urban planners that land use change, spatial integration and urban spatial interactions on the spatial scale of metropolitan cities to require the implementation of sustainable development concepts oriented towards saving the environment, ensuring fairness in economic access and creating social cohesion, in line with meeting national Metropolitan city development targets by 2030.
Editorial: Special Issue “Laser-Induced Periodic Surface Nano- and Microstructures for Tribological Applications”
Authors: Bonse Jörn , Spaltmann Dirk
Published: March 2020

Laser material processing is an innovative technology that generates surface functionalities on the basis of optical, mechanical, or chemical properties [...]
Neutron Diffraction and Diffraction Contrast Imaging for Mapping the TRIP Effect under Load Path Change
Authors: Polatidis Efthymios , Morgano Manuel , Malamud Florencia , Bacak Michael , Panzner Tobias , Van Swygenhoven Helena , Strobl Markus
Published: March 2020

The transformation induced plasticity (TRIP) effect is investigated during a load path change using a cruciform sample. The transformation properties are followed by in-situ neutron diffraction derived from the central area of the cruciform sample. Additionally, the spatial distribution of the TRIP effect triggered by stress concentrations is visualized using neutron Bragg edge imaging including, e.g., weak positions of the cruciform geometry. The results demonstrate that neutron diffraction contrast imaging offers the possibility to capture the TRIP effect in objects with complex geometries under complex stress states.
The New Technologies Developed from Laser Shock Processing
Authors: Wu Jiajun , Zhao Jibin , Qiao Hongchao , Hu Xianliang , Yang Yuqi
Published: March 2020

Laser shock processing (LSP) is an advanced material surface hardening technology that can significantly improve mechanical properties and extend service life by using the stress effect generated by laser-induced plasma shock waves, which has been increasingly applied in the processing fields of metallic materials and alloys. With the rapidly development of modern industry, many new technologies developed from LSP have emerged, which broadens the application of LSP and enriches its technical theory. In this work, the technical theory of LSP was summarized, which consists of the fundamental principle of LSP and the laser-induced plasma shock wave. The new technologies, developed from LSP, are introduced in detail from the aspect of laser shock forming (LSF), warm laser shock processing (WLSP), laser shock marking (LSM) and laser shock imprinting (LSI). The common feature of LSP and these new technologies developed from LSP is the utilization of the laser-generated stress effects rather than the laser thermal effect. LSF is utilized to modify the curvature of metal sheet through the laser-induced high dynamic loading. The material strength and the stability of residual stress and micro-structures by WLSP treatment are higher than that by LSP treatment, due to WLSP combining the advantages of LSP, dynamic strain aging (DSA) and dynamic precipitation (DP). LSM is an effective method to obtain the visualized marks on the surface of metallic materials or alloys, and its critical aspect is the preparation of the absorbing layer with a designed shape and suitable thickness. At the high strain rates induced by LSP, LSI has the ability to complete the direct imprinting over the large-scale ultrasmooth complex 3D nanostructures arrays on the surface of crystalline metals. This work has important reference value and guiding significance for researchers to further understand the LSP theory and the new technologies developed from LSP.
Correlation between Magnetic Properties and Chemical Composition of Non-Oriented Electrical Steels Cut through Different Technologies
Authors: Paltanea Gheorghe , Manescu (Paltanea) Veronica , Stefanoiu Radu , Nemoianu Iosif Vasile , Gavrila Horia
Published: March 2020

Due to worldwide regulations on electric motor manufacturing, the energy efficiency of these devices has to be constantly improved. A solution may reside in the fact that high quality materials and adequate cutting technologies should be carefully chosen. The magnetic properties of non-oriented electrical steels are affected by the cutting methods, through induced plastic, and thermal stresses. There is also an important correlation between chemical composition and different magnetic properties. In this paper, we analyze different industrial grades of non-oriented electrical steels, used in electrical machines’ core manufacturing as M800-65A, M800-50A, M400-65A, M400-50A, M300-35A, and NO20. The influence of the cutting methods on the normal magnetization curve, total energy loss and its components, and relative magnetic permeability is investigated in alternating currents using a laboratory single sheet tester. The chemical composition and grain size influence are analyzed and correlated with the magnetic properties. Special attention is devoted to the influence of the increased cutting perimeter on the energy losses and to the way it relates to each chemical alloy constituent. The final decision in what concerns the choice of the proper magnetic material and the specific cutting technology for the motor magnetic cores is imposed by the desired efficiency class and the specific industrial applications.
Effect of the Formation of Amorphous Networks on the Structure and Hydration Characteristics of Granulated Blast Furnace Slag
Authors: Yao Yuhan , Wang Yali , Wei Qi , Cui Suping , Hao Liwei
Published: March 2020

The slag obtained in the process of pig iron smelting has been widely used, but the variational hydration activity always is a significant factor affecting its quality. In this experiment, the laboratory simulated slag was prepared by adjusting the chemical composition and cooling method. The experiment primary characterized the structure and hydration process with different types of slag by using MAS NMR, XRD, compressive strength, ICP, SEM, and hydration heat, then obtained the influence of the composition of the network former S/A (the mass ratio of SiO2 and Al2O3 in chemical composition) and amorphous phase content on its structure and hydration activity. The result shows that lowering the S/A value can reduce the degree of vitreous polymerization in the slag; reducing the S/A value of the slag can make the slag hydration time advance, and consequently, the cumulative exotherm increases, the liquid phase Ca/Si and Al/Si ionic ratio increases, and the hydration product changes from C–S–H gel to C–A–S–H gel, which ultimately leads to an increase in compressive strength. In the high S/A value slag, the formation of the trace crystal phase of gehlenite is beneficial to reduce the degree of polymerization of the amorphous.
Prediction of Strain Fatigue Life of HRB400 Steel Based on Meso-Deformation Inhomogeneity
Authors: Jin Lili , Zeng Bin , Lu Damin , Gao Yingjun , Zhang Keshi
Published: March 2020

The relationship between strain fatigue life and evolution of meso-deformation inhomogeneity was studied, through the cyclic process of numerical simulation of crystal plasticity compared with the fatigue test of steel hot-rolled ribbed-steel bar 400 (HRB400). The statistical characterization parameters at grain level, including the standard deviation of the dot product of longitudinal stress and strain, the product of the macro stress and the standard deviation of the longitudinal strain, and the product of the macro stress ratio and the standard deviation of the longitudinal strain, were proposed and respectively applied to measure the meso-deformation inhomogeneity of materials. These parameters take the effect of peak stress into account, distinct from the pure strain statistical parameters. The numerical results demonstrate that the low-cycle fatigue life curves of materials are predictable using the new parameters as FIPs (fatigue indicator parameters), and the predictions are more rational than by utilizing the FIPs without considering the peak stress effect.
Effect of Organics on Heavy Metal-Contaminated River Sediment Treated with Electro-Osmosis and Solidification/Stabilization Methods
Authors: Pan Chonggen , Chen Keyu , Chen Danting
Published: March 2020

This study focuses on the treatment of heavy metal ions and achieving enhancement of river sediment, which is rich in organics. Fulvic acid was used as the main representative of organics in which to study the transfer of Cu2+, Zn2+ ions in the electroosmotic system, in both the absence and presence of organics. In addition, the effects of the experiment parameters (i.e., voltages, displacement, and water content), heavy metal ion content (0.19% and 0.38%, respectively), and the concentration of organics (1.5%, 3%, and 4.5%) acting on migration of ions and physiochemical properties of sediment, before and after electro-osmosis treatment were investigated. Mineral composition of the soil and its microscopic characteristics were analyzed by scanning electron microscopy. The results show that the 4.5% fulvic acid added in the sediment can enhance the migration ability of Cu2+ and Zn2+ ions through complexation, and simultaneously effectively reduce the formation of colloids with the average reductions of Cu2+ ions and Zn2+ ions being 28 and 11 mg/kg, respectively. While the dewatering capacity of the sediment with higher fulvic acid content is weaker, fulvic acid can effectively reduce the corrosion of the electrode during the electro-osmosis process, due to the film formed on the metal surface. Moreover, the fulvic acid in the organics can be combined with the aluminum and calcium produced by the hydration of the cement, delaying the hydration of the cement, while simultaneously decomposing the hydration product and hindering the hardening of the cement, thereby affecting and destroying the formation of the sediment’s structure and its strength.
Effect of Rare Earth Ce on Deep Stamping Properties of High-Strength Interstitial-Free Steel Containing Phosphorus
Authors: Wang Hao , Bao Yanping , Duan Chengyi , Lu Lu , Liu Yan , Zhang Qi
Published: March 2020

The influence of rare earth Ce on the deep stamping property of high-strength interstitial-free (IF) steel containing phosphorus was analyzed. After adding 120 kg ferrocerium alloy (Ce content is 10%) in the steel, the inclusion statistics and the two-dimensional morphology of the samples in the direction of 1/4 thickness of slab and each rolling process were observed and compared by scanning electron microscope (SEM). After the samples in each rolling process were treated by acid leaching, the three-dimensional morphology and components of the second phase precipitates were observed by SEM and energy dispersive spectrometer (EDS). The microstructure of the sample was observed by optical microscope, and the grain size was compared. Meanwhile, the content and strength of the favorable texture were analyzed by X-ray diffraction (XRD). Finally, the mechanical properties of the product were analyzed. The results showed that: (1) The combination of rare earth Ce with activity O and S in steel had lower Gibbs free energy, and it was easy to generate CeAlO3, Ce2O2S, and Ce2O3. The inclusions size was obviously reduced, but the number of inclusions was increased after adding rare earth. The morphology of inclusions changed from chain and strip to spherical. The size of rare earth inclusions was mostly about 2–5 μm, distributed and dispersed, and their elastic modulus was close to that of steel matrix, which was conducive to improving the structure continuity of steel. (2) The rare earth compound had a high melting point. As a heterogeneous nucleation point, the nucleation rate was increased and the solidification structure was refined. The grade of grain size of products was increased by 1.5 grades, which is helpful to improve the strength and plasticity of metal. (3) Rare earth Ce can inhibit the segregation of P element at the grain boundary and the precipitation of Fe(Nb+Ti)P phase. It can effectively increase the solid solution amount of P element in steel, improve the solid solution strengthening effect of P element in high-strength IF steel, and obtain a large proportion of {111} favorable texture, which is conducive to improving the stamping formability index r90 value.
Effective Parameters for 1D Photonic Crystals with Isotropic and Anisotropic Magnetic Inclusions: Coherent Wave Homogenization Theory
Authors: Méndez J. Flores , Reyes A. C. Piñón , Moreno M. Moreno , Morales-Sánchez A. , Minquiz Gustavo M. , Lázaro R. C. Ambrosio , Leal H. Vázquez , García F. Candia
Published: March 2020

A homogenization theory that can go beyond the regime of long wavelengths is proposed, namely, a theory that is still valid for vectors of waves near the edge of the first zone of Brillouin. In this paper, we consider that the displacement vector and the magnetic induction fields have averages in the volume of the cell associated with the values of the electric and magnetic fields in the edges of the cell, so they satisfy Maxwell’s equations. Applying Fourier formalism, explicit expressions were obtained for the case of a photonic crystal with arbitrary periodicity. In the case of one-dimensional (1D) photonic crystals, the expressions for the tensor of the effective bianisotropic response (effective permittivity, permeability and crossed magneto-electric tensors) are remarkably simplified. Specifically, the effective permittivity and permeability tensors are calculated for the case of 1D photonic crystals with isotropic and anisotropic magnetic inclusions. Through a numerical calculation, the dependence of these effective tensors upon the filling fraction of the magnetic inclusion is shown and analyzed. Our results show good correspondence with the approach solution of Rytov’s effective medium. The derived formulas can be very useful for the design of anisotropic systems with specific optical properties that exhibit metamaterial behavior.
3D Printing of ABS Barium Ferrite Composites
Authors: Hanemann Thomas , Syperek Diana , Nötzel Dorit
Published: March 2020

In this work, a process for the realization of new polymer matrix composites with nanosized barium ferrite (BaFe12O19) as ferrimagnetic filler, acryl butadiene styrene (ABS) as polymer matrix and an extrusion-based method, namely fused filament fabrication (FFF), as 3D printing method will be described comprehensively. The whole process consists of the individual steps material compounding, rheological testing, filament extrusion, 3D-printing via FFF and finally a widespread specimen characterization regarding to appearance, mechanical properties like tensile and bending behavior as well as the aspired magnetic properties. Increasing ferrite amounts up to 40 vol.% (equal 76 wt.%) cause a reduction of the ultimate stress and an increase of the magnetic polarization as well as of the energy product (BH)max in comparison to the pure polymer matrix. In addition, an extensive discussion of typical printing defects and their consequences on the device properties will be undertaken.
An Optimization Model for the Temporary Locations of Mobile Charging Stations
Authors: Răboacă Maria-Simona , Băncescu Irina , Preda Vasile , Bizon Nicu
Published: March 2020

A possible solution with which to alleviate the range anxiety of electric vehicle (EV) drivers could be a mobile charging station which moves in different places to charge EVs, having a charging time of even half an hour. A problem that arises is the impossibility of charging in any location due to heavy traffic or limited space constraints. This paper proposes a new operational mode for the mobile charging station through temporarily stationing it at different places for certain amounts of time. A mathematical model, in the form of an optimization problem, is built by modeling the mobile charging station as a queuing process, the goal of the problem being to place a minimum number of temporary service centers (which may have one or more mobile charging stations) to minimize operating costs and the charger capacity of the mobile charging station so that the service offered is efficient. The temporary locations obtained are in areas with no or few fixed charging stations, making the mobile station infrastructure complementary to the fixed charging station infrastructure. The temporary location operational mode, compared to current moving operational mode, is more efficient, having a small miss ratio, short mean response time and short mean queuing time.
Effect of Chitosan’s Degree of Deacetylation on the Performance of PES Membrane Infused with Chitosan during AMD Treatment
Authors: Mathaba Machodi , Daramola Michael Olawale
Published: March 2020

Acid mine drainage is an environmental problem associated with mining operations and activities. Its treatment is essential to achieving environmental sustainability. In this study, a polyethersulphone (PES) membrane infused with chitosan is proposed as a point-of-use material for treating acid mine drainage (AMD). The composite material explored the synergetic effect between chitosan and polymer, particularly considering the effect of the degree of deacetylation (DD) of chitosan on the performance of membrane. Chitosan was produced from chitin under various synthesis process conditions and infused within polyethersulphone membrane. The results obtained show that chitosan with the highest degree of deacetylation was achieved with a temperature of 100 °C and NaOH concentration of 40 wt%. Increasing the temperature above 100 °C started degrading already formed or exposed amine groups, thus, reducing the DD of the chitosan sample. The contact angle and porosity analysis indicated that the hydrophilic nature of the membrane was enhanced with increasing DD of the chitosan. The performance of the membranes was conducted on a Dead-end filtration cell using synthetic acid mine drainage. The results showed that the flux and rejection of the membrane was enhanced with increasing degree of deacetylation. PES 5 and PES 1 were blended with chitosan having the highest (95.97%) and lowest (33.93%) degree of deacetylation, respectively. PES 5 reported pure water flux of 123 L/m2·h and PES 1 was recorded as 104 L/m2·h. Similarly, the rejection of the membrane was improved with increasing chitosan’s degree of deacetylation. PES 5 had higher rejection and PES 1 had the least rejection. Maximum rejection for the contaminants was determined as 98.05, 97.39, 96.25, 95.24 and 80.34% for Mn2+, Fe2+, Mg2+ and Ca2+ and SO42−, respectively. The results obtained show that chitosan’s degree of deacetylation has a positive effect on the performance of polyethersulphone membrane during the treatment of acid mine drainage.
Exploring the Operation Factors that Influence Performance of a Spiral-Wound Forward Osmosis Membrane Process for Scale-up Design
Authors: Lee Sungyun
Published: March 2020

Forward osmosis (FO) technology has increasingly attracted attention owing to its low operational energy and low fouling propensity. Despite extensive investigations on FO, very few module-scale FO studies on the operation and design of the FO process have been conducted. In this paper, a simple and practical FO process design parameter called normalized membrane area is suggested based on a performance analysis of spiral-wound FO elements. The influence of operation factors on operating pressures and water recovery was investigated using 8-inch spiral wound elements in the continuous operation mode. The membrane area was adjusted by series connection of FO elements to a maximum value of 46 m2 (three elements). The feed and draw flow rates were varied between 5 and 15 LPM under various feed (10, 20, and 30 g/L) and draw (58.4 and 233.8 g/L) concentration combinations. The analysis of flow rates (feed, draw, and permeate flow rates) indicated not only high flow channel resistance on the draw side but also high permeate flow rates can induce higher operating pressures owing to strong mutual interaction of the feed and the draw streams. Feed water recovery was focused on as a key performance index, and the experimental recovery (RExp) and theoretical maximum recovery (RTh) values were compared. The results revealed the significance of the feed flow rate and the membrane area in terms of enhancing the water recovery performance. In addition, a clear relationship was observed between the membrane area normalized by the initial feed flow rates and the water recovery ratio (RExp/RTh), even though the applied operation conditions were different. Finally, an empirical equation to estimate the required membrane area of spiral-wound FO was proposed for the FO process design. The equation can be used to predict water recovery of FO systems as well, for example, if an FO system is operated at 0.08 m2L−1h of the normalized membrane area, the system is expected to offer 78% of the RTh value.
Effect of Loading and Functionalization of Carbon Nanotube on the Performance of Blended Polysulfone/Polyethersulfone Membrane during Treatment of Wastewater Containing Phenol and Benzene
Authors: Rameetse Mabusha S. , Aberefa Oluseyi , Daramola Michael O.
Published: March 2020

In this study, a carbon nanotube (CNT)-infused blended polymer membrane was prepared and evaluated for phenol and benzene removal from petroleum industry wastewater. A 25:75 (by weight %) blended polysulfone/polyethersulfone (PSF/PES) membrane infused with CNTs was prepared and tested. The effect of functionalization of the CNTs on the quality and performance of the membrane was also investigated. The membranes were loaded with CNTs at different loadings: 0.5 wt. %, 1 wt. %, 1.5 wt. % pure CNTs (pCNTs) and 1 wt. % functionalized CNTs (fCNTs), to gain an insight into the effect of the amount of CNT on the quality and performance of the membranes. Physicochemical properties of the as-prepared membranes were obtained using scanning electron microscopy (SEM) for morphology, Raman spectroscopy for purity of the CNTs, Fourier transform infrared (FTIR) for surface chemistry, thermogravimetric analysis (TGA) for thermal stability, atomic force microscopy (AFM) for surface nature and nano-tensile analysis for the mechanical strength of the membranes. The performance of the membrane was tested with synthetic wastewater containing 20 ppm of phenol and 20 ppm of benzene using a dead-end filtration cell at a pressure ranging from 100 to 300 kPa. The results show that embedding CNTs in the blended polymer (PSF/PES) increased both the porosity and water absorption capacity of the membranes, thereby resulting in enhanced water flux up to 309 L/m2h for 1.5 wt. % pCNTs and 326 L/m2h for 1 wt. % functionalized CNT-loaded membrane. Infusing the polysulfone/polyethersulfone (PSF/PES) membrane with CNTs enhanced the thermal stability and mechanical strength. Results from AFM indicate enhanced hydrophilicity of the membranes, translating in the enhancement of anti-fouling properties of the membranes. However, the % rejection of membranes with CNTs decreased with an increase in pCNTs concentration and pressure, while it increased the membrane with fCNTs. The % rejection of benzene in the pCNTs membrane decreased with 13.5% and 7.55% in fCNT membrane while phenol decreased with 55.6% in pCNT membrane and 42.9% in the FCNT membrane. This can be attributed to poor CNT dispersion resulting in increased pore sizes observed when CNT concentration increases. Optimization of membrane synthesis might be required to enhance the separation performance of the membranes.
Adsorption Processing for the Removal of Toxic Hg(II) from Liquid Effluents: Advances in the 2019 Year
Authors: Alguacil Francisco J. , López Félix A.
Published: March 2020

Mercury is a toxic metal, thus, it is an element which has more and more restrictions in its uses, but despite the above, the removal of this metal, from whatever the form in which it is encountered (zero valent metal, inorganic, or organic compounds), and from different sources, is of a widespread interest. In the case of Hg(II), or Hg2+, the investigations about the treatment of Hg(II)-bearing liquid effluents (real or in most cases synthetic solutions) appear not to end, and from the various separation technologies, adsorption is the most popular among researchers. In this topic, and in the 2019 year, more than 100 publications had been devoted to this field: Hg(II)-removal-adsorption. This work examined all of them.
Silicon Nitride Whisker-Reinforced Aluminum Matrix Composites: Twinning and Precipitation Behavior
Authors: Qu Shoujiang , Feng Aihan , Geng Lin , Shen Jun , Chen Daolun
Published: March 2020

Aluminum composites reinforced with ceramic whiskers exhibited a unique combination of high specific strength and superior specific modulus. A 20 vol.% Si3N4w/Al-11.5Si-1.0Mg-0.5Cu-0.5Ni (wt.%) composite was fabricated via squeeze casting in the present study. It was observed that the addition of silicon nitride (Si3N4) whiskers in the Al-Si cast alloy promoted extensive twinning in the eutectic silicon particles due to a coupled role of thermal stresses between the matrix and silicon and residual stresses present in the composite. Double aging peaks were present in the age-hardening curves. The precipitation mechanism involved the formation of Mg2Si and Al2CuMg phases. The presence of Si3N4 whiskers in the composite retarded the nucleation process of Mg2Si precipitate while enhancing its growth rate.
Powder Filling and Sintering of 3D In-chip Solenoid Coils with High Aspect Ratio Structure
Authors: Huang Yujia , Li Haiwang , Sun Jiamian , Zhai Yanxin , Li Hanqing , Xu Tiantong
Published: March 2020

In this study, a 3D coil embedded in a silicon substrate including densely distributed through-silicon vias (TSVs) was fabricated via a rapid metal powder sintering process. The filling and sintering methods for microdevices were evaluated, and the effects of powder types were compared. The parameters influencing the properties and processing speed were analyzed. The results showed that the pre-alloyed powder exhibited the best uniformity and stability when the experiment used two or more types of powders to avoid the segregation effect. The smaller the particle diameter, the better the inductive performance will be. The entire structure can be sintered near the melting point of the alloy, and increasing the temperature increases strength, while resulting in low resistivity. Finally, an 800-µm-high coil was fabricated. This process does not need surface metallization and seed layer formation. The forming process involves only sintering instead of slowly growing copper with a tiny current. Therefore, this process has advantages, such as a process time of 7 h, corresponding to an 84% reduction compared to current electroplating processes (45 h), and a 543% efficiency improvement. Thus, this process is more efficient, controllable, stable, and suitable for mass production of devices with flexible dimensions.
Fabrication of Random Microlens Array for Laser Beam Homogenization with High Efficiency
Authors: Xue Li , Pang Yingfei , Liu Wenjing , Liu Liwei , Pang Hui , Cao Axiu , Shi Lifang , Fu Yongqi , Deng Qiling
Published: March 2020

The miniaturized and integrated microlens array (MLA) can effectively achieve the beam homogenization, compactness and miniaturization of laser systems. When the high-coherence laser beam is homogenized by means of using the MLA, interference fringes will occur in the homogenized light spot due to the periodicity of the MLA, which seriously affects the uniformity of the homogenized light spot. To solve this problem, a novel random microlens array (rMLA) structure was proposed for the purpose of achieving beam homogenization. The coherence in the homogenization process is suppressed by means of breaking the periodicity of the MLA. The homogenized light spot with a high energy utilization is then obtained accordingly. In the fabrication process, a clever method of combining chemical etching with lithography technology is performed to fabricate a honeycomb rMLA and a rectangular rMLA. The experimental results show that the energy utilization rate of the two types of the rMLAs is about 90%, and the uniformity of the homogenized light spots generated by the honeycomb rMLA and the rectangular rMLA are more than 80% and 85%, respectively. Meanwhile, fully cost-effective fabrication is possible to be realized.
Unlocking the Microbiome Communities of Banana (Musa spp.) under Disease Stressed (Fusarium wilt) and Non-Stressed Conditions
Authors: Kaushal Manoj , Swennen Rony , Mahuku George
Published: March 2020

We assessed the diversity, structure, and assemblage of bacterial and fungal communities associated with banana plants with and without Fusarium oxysporum f. sp. cubense (Foc) symptoms. A total of 117,814 bacterial and 17,317 fungal operational taxonomy units (OTUs) were identified in the rhizosphere, roots, and corm of the host plant. Results revealed that bacterial and fungal microbiota present in roots and corm primarily emanated from the rhizosphere. The composition of bacterial communities in the rhizosphere, roots, and corm were different, with more diversity observed in the rhizosphere and less in the corm. However, distinct sample types i.e., without (asymptomatic) and with (symptomatic) Fusarium symptoms were the major drivers of the fungal community composition. Considering the high relative abundance among samples, we identified core microbiomes with bacterial and fungal OTUs classified into 20 families and colonizing distinct plant components of banana. Our core microbiome assigned 129 bacterial and 37 fungal genera to known taxa.
Do Foliar Endophytes Matter in Litter Decomposition?
Authors: Wolfe Emily R. , Ballhorn Daniel J.
Published: March 2020

Litter decomposition rates are affected by a variety of abiotic and biotic factors, including the presence of fungal endophytes in host plant tissues. This review broadly analyzes the findings of 67 studies on the roles of foliar endophytes in litter decomposition, and their effects on decomposition rates. From 29 studies and 1 review, we compiled a comprehensive table of 710 leaf-associated fungal taxa, including the type of tissue these taxa were associated with and isolated from, whether they were reported as endo- or epiphytic, and whether they had reported saprophytic abilities. Aquatic (i.e., in-stream) decomposition studies of endophyte-affected litter were significantly under-represented in the search results (p < 0.0001). Indicator species analyses revealed that different groups of fungal endophytes were significantly associated with cool or tropical climates, as well as specific plant host genera (p < 0.05). Finally, we argue that host plant and endophyte interactions can significantly influence litter decomposition rates and should be considered when interpreting results from both terrestrial and in-stream litter decomposition experiments.
Does the Methylene Blue Test Give Equally Satisfactory Results in All Studied Igneous Rocks Relative to the Identification of Swelling Clay Minerals?
Authors: Giannakopoulou Panagiota P. , Petrounias Petros , Rogkala Aikaterini , Lampropoulou Paraskevi , Gianni Eleni , Papoulis Dimitrios , Koutsovitis Petros , Tsikouras Basilios , Hatzipanagiotou Konstantin
Published: March 2020

The presence or the absence of swelling clay minerals in rocks, which are used in various construction applications, constitutes a determinant factor for their strength, and consequently, in their general behavior in various construction applications, as they have the ability to swell up to 400 times of their usual volume, causing failures to any application in which they participate. The aim of this study is to respond to the question of whether the empirical method of methylene blue yields equally safe and correct results in different types of igneous rocks and if not, which is the determining factor affecting the results. The answer to this complex question is feasible by investigating the microscopic structure and the mineralogy of the studied rocks, and particularly, using the content of specific phyllosilicate minerals which may be related or not with the methylene blue values. According to the results, the methylene blue test seems to work correctly for the intermediate (Group I) and mafic (Group II) examined rocks, but it seems to be wrong for the highly serpentinized ultramafic rocks (up to 70% of serpentine) (Group III).
In Situ Hyperspectral Raman Imaging of Ternesite Formation and Decomposition at High Temperatures
Authors: Böhme Nadine , Hauke Kerstin , Neuroth Manuela , Geisler Thorsten
Published: March 2020

Knowledge of the high-temperature properties of ternesite (Ca5(SiO4)2SO4) is becoming increasingly interesting for industry in different ways. On the one hand, the high-temperature product has recently been observed to have cementitious properties. Therefore, its formation and hydration characteristics have become an important field of research in the cement industry. On the other hand, it forms as sinter deposits in industrial kilns, where it can create serious problems during kiln operation. Here, we present two highlights of in situ Raman spectroscopic experiments that were designed to study the high-temperature stability of ternesite. First, the spectra of a natural ternesite crystal were recorded from 25 to 1230 °C, which revealed a phase transformation of ternesite to the high-temperature polymorph of dicalcium silicate (α’L-Ca2SiO4), while the sulfur is degassed. With a heating rate of 10 °C/h, the transformation started at about 730 °C and was completed at 1120 °C. Using in situ hyperspectral Raman imaging with a micrometer-scale spatial resolution, we were able to monitor the solid-state reactions and, in particular, the formation properties of ternesite in the model system CaO-SiO2-CaSO4. In these multi-phase experiments, ternesite was found to be stable between 930 to 1020–1100 °C. Both ternesite and α’L-Ca2SiO4 were found to co-exist at high temperatures. Furthermore, the results of the experiments indicate that whether or not ternesite or dicalcium silicate crystallizes during quenching to room temperature depends on the reaction progress and possibly on the gas fugacity and composition in the furnace.
Rheological Properties of Cemented Paste Backfill with Alkali-Activated Slag
Authors: Kou Yunpeng , Jiang Haiqiang , Ren Lei , Yilmaz Erol , Li Yuanhui
Published: March 2020

This study investigates the time-dependent rheological behavior of cemented paste backfill (CPB) that contains alkali-activated slag (AAS) as a binder. Rheological measurements with the controlled shear strain method have been conducted on various AAS-CPB samples with different binder contents, silicate modulus (Ms: SiO2/Na2O molar ratio), fineness of slag and curing temperatures. The Bingham model afforded a good fit to all of the CPB mixtures. The results show that AAS-CPB samples with high binder content demonstrate a more rapid rate of gain in yield stress and plastic viscosity. AAS-CPB also shows better rheological behavior than CPB samples made up of ordinary Portland cement (OPC) at identical binder contents. It is found that increasing Ms yields lower yield stress and plastic viscosity and the rate of gain in these parameters. Increases in the fineness of slag has an adverse effect on rheological behavior of AAS-CPB. The rheological behavior of both OPC- and AAS-CPB samples is also strongly enhanced at higher temperatures. AAS-CPB samples are found to be more sensitive to the variation in curing temperatures than OPC-CPB samples with respect to the rate of gain in yield stress and plastic viscosity. As a result, the findings of this study will contribute to well understand the flow and transport features of fresh CPB mixtures under various conditions and their changes with time.