bluuebunny/crossref_metadata_2025 huggingface dataset:
Key Words and Political Parties in the 2020 Pre-Election Campaign on Facebook
Authors: Kolenčíková Natália
Published: January 2022

The research paper analyses key words found in pre-election communication of electorally successful political parties, based on which the main communication differences among those parties and the specifics of pre-election communication, as well as the pre-election discourse as a whole, are identified. Research material consists of political parties’ microblogs published on individual political parties’ Facebook profiles in the period from January 1, 2020 to February 28, 2020, with a reference corpus formed by the total of these microblogs. The analysis showed professionalization of political communication, the use of new, but also traditional ways of interaction with the electorate, pre-election communication based on the presentation of candidates, offensive and combative tone of the most successful parties, self-presentation, hints of persuasive and manipulative techniques, topic points of electoral programmes, but also thematic neutrality and non-specificity that suggest smaller electoral success.
Framing and Agenda Setting of the Day of Republika Srpska and its 2016 Referendum
Authors: Beglerović Nađa , Becker Matthew T.
Published: January 2022

The purpose of this article is to explore broadsheet newspaper framing and agenda-setting of two events using the five-frame model developed by Semetko and Valkenburg (2000). This article provides insight into how the leading broadsheet newspaper within BiH’s Republika Srpska frames relationships between the three main ethnic groups and is the first such study to occur in BiH. By identifying and exploring the most common frames in Glas Srpske during the five-year period (from 31 December 2015 to 30 December 2020), the research is meant to answer the following research questions: How does Glas Srpske frame the conversation about it and portray the Day of Republika Srpska (RS) and Referendum of the RS Day? The results, which find Attribution of Responsibility and Conflict frames to be the more prevalent in Glas Srpske, illustrate contentious politics that reinforce differences between ethnic groups in BiH. These events and the controversial narrative surrounding them are relevant more than ever in the light of the recent non-paper ‘Western Balkans – A Way Forward’.
Asphalt mixture and its time delay of stress after strain at change of temperature and frequency
Authors: Mandula Ján , Bokomlaško Jakub
Published: January 2022

Materials in pavement construction are used due to their material properties. Asphalt mixtures, which are today most used during building pavement construction, have a significant place. Asphalt mixtures are classified as viscoelastic materials due to their material properties. This article focuses on the time delay of the stress behind the strain, which is a specific property for viscoelastic materials. It is particularly focused on one type of asphalt mixture, which is used in the binder course and in the upper base layer. The selected asphalt mixture was tested on a four-bending machine and the samples had a beam shape. The sample was tested at four temperatures and seven frequencies. In the discussion, the article focuses on the comparison of the time delay of the stress Δt behind the strain during the change of temperature and frequency. It is clear from the results that the selected asphalt mixture is significantly affected by the change in temperature as well as the change in frequency. The conclusion is devoted to a summary of the acquired knowledge and observation, which is focused on examples in practice.
Revenue House - architectural typology to be valorised
Authors: Ouafa Boumaza , Abdelhak Bordjiba
Published: January 2022

This research was carried out on the state of degradation of the historic core of Annaba city, Algeria. This degradation is caused by multiple factors, the most important of which is the absence of shared responsibility of public actors. The number of collapses multiplied which became a source for the creation of large office buildings with modernist tendencies, but without any architectural identity. The real estate park in downtown Annaba brings together urban entities according to various principles and logics of composition, structuring the urban image of the city of Annaba. The objective of this study is to build a complete catalogue summarizing the structures and fundamental characteristics of old buildings. Initially, this study defines all the notions linked to urban morphology and the typologies of housing. Secondly, an architectural study will be carried out on the “income house”, which represents the basic unit for the development of this historic nucleus. The typological analysis was applied to 44 buildings from the 19th and early 20th centuries located on the boulevard named “Revolution Square” in order to identify a set of common and specific criteria for the classification of “house income”.
Project Info Water
Authors: Hlinková Mária , Zeleňáková Martina
Published: January 2022

The main goal of Project Info Water is to raise awareness about water management and water resources in the Slovak republic. The target groups of the project are kindergarten students, primary school students, citizens of the affected area, and the government. The project contains four groups of activities – informal, media, online, and presentation activities. Informal activities include thematic brochures with a brief description of the topics Water of Eastern Slovakia, Household water, Flood, Flood protection, Water structures of Eastern Slovakia, Water in the landscape. The presentation activities include the description of webinars, the media, and social activities include print advertisement and access to social media fun pages.
Aesthetic perception of the Russian sound speech by Germans (a case study of German internet forums)
Authors: Shesterina E. A.
Published: January 2022

The article is devoted to the aesthtic assessment of the sound of Russian speech as reflected in German Internet forums. Segmental and suprasegmental features of Russian pronunciation which evoke in native speakers of German empathy and / or antipathy towards Russian sounding speech, are described. The ordinary Germans' naive assessment of Russian souding speech differs from that by professional linguists. Germans who are not familiar with the theoretical basis of the phonetic structure of the Russian language pay attention, first of all, to those pronunciation features that are not characteristic of the phonetic basis of the German language. Among them on segmental level are the following: trembling sonant [r̥], vowel [ᵻ] and back-lingual slit [ɣ] after vowels [e], [i] and consonants [lʲ], [nʲ], [j], the pronunciation of which in German in this position is pronounced as ich-Laut [ç]. The Germans also seem to dislike clusters of consonants that are absent in the German language, for example, -рск-, -здр- etc. The presence of these sounds in the Russian language allows ordinary Germans to characterize Russian sounding speech as rude, despite the remarks of the Germans that there are many “soft” sounds i.e. palatalized consonants in the Russian language. The main difference at the suprasegmental level, which in the scientific literature is designated as the opposition of the German “staccato” and Russian “legato”, finds its confirmation in the statements of German members of the forum. The rhythmic organization of Russian speech is assessed by common Germans as discordant and indistinct, since, unlike German speech, Russian speech is characterized by relaxed articulation, non-forced vocalization, an extended melodic range and an irregular rhythmic patterns. In addition, the use of different pitch movements in friendly and aggressive communication encourages Germans to qualify the speech of Russian speakers in obvious situations of friendly communication as confrontational.
The cognitive discourse analysis of evidentiality category in Russian exclamatory sentences
Authors: Hosseini A. , Kahnamouei T. K.
Published: January 2022

The aims of the article are to examine the meanings of indirect evidentiality: inference, goal, desire and to search the manifestation of direct evidentiality in Russian exclamatory sentences. We attempt to prove that this category of evidentiality can be found in exclamatory sentences to express the speaker’s emotional attitude to the described situation, and, also, by using the cognitive discourse analysis, we are going to search the ways of realization of the speaker’s and his interlocutor’s intentions in any statement. In our study we analyzed the exclamatory sentences containing certain lexical or grammatical language tools used to express the meanings of direct and indirect evidentiality. The relevance of this work is determined by the necessity of studying the reliable and unreliable sources of information expressed in Russian exclamatory sentences. By means of cognitive discourse analysis, we revealed that the availability of some of introductory words, particles, exclamatory pronouns and etc. according to the context, can contextually point to the personal experience of the speaker or to the unreliable and incomplete information he gets. In these situations the subject of the speech act in relation to what he sees or hears, renders feelings of wonder, happiness and sadness.
On introducing free indirect speech in Russian translation despite the absence of corresponding structures in the English original
Authors: Alimova A. D.
Published: January 2022

The article analyzes the most typical cases of introducing free indirect speech in the Russian translation where there are no corresponding structures in the English original. Typical non-free-indirectspeech structures and contexts in the source text are explored, such as may materialize as free indirect speech in the target text. The study employs qualitative methods including lexical-semantic, contextual and comparative analysis of the source text and the target text. As for the structure, this paper has been divided into two parts. First, a theoretical background for the problem is established, involving the theories by Ia. I. Retsker and D. V. Psurtsev. The paper then goes on to examine translators’ choices to generate new interference of the narrator’s text and the character’s text. The cases when free indirect speech may arise in the Russian translation are typically based on kindred forms of the character’s speech representation in the English original, long descriptions of a situation where the character acts, complex sentences with content clauses, containing the character’s thoughts and emotions. The analysis suggests that the decision to introduce free indirect speech patterns into translation can be based on the typological differences between the languages in question, or on logical and stylistic “inclinations” of a given fragment. Therefore, the decisions to introduce free indirect speech fall into two groups, obligatory and possible respectively. If such choices by Russian translators constitute a tendency, a certain correlation of syntactic patterns and contexts may be established. The results obtained in the study may be used by translators of literary texts.
Atwater Village Cable-Stayed Equestrian Bridge
Authors: Fitzwilliam Dan
Published: January 2022

This will be the second cable-stayed bridge in the city of Los Angeles. In order to mitigate the potential for resonant vibrations during passage of groups of equestrians, a system of tuned mass dampers was designed for the bridge. High-stressed cables are incrementally attached to the 38-meter-tall mast and configured in a fan pattern.
VIVIR Y MORIR EN LA GRAN ALDEA: RALPH HERNE (1888), LA NOVELA PORTEÑA DE W. H. HUDSON
Authors: Lencina Eva
Published: January 2022

Ralph Herne (1888) is the only work set in the city of Buenos Aires written by W. H. Hudson, the Angloargentine naturalist better known for his rural settings. The story is interesting because of this distinctive feature, but also because it provides a unique historic perspective, since it unfolds during the yellow fever epidemic of 1871. This article examines the representation of the porteño space through the places staged in Hudson’s text.
Prototyping Feed-Forward Artificial Neural Network on Spartan 3S1000 FPGA for Blood Type Classification
Authors: Priramadhi Rizki Ardianto , Darlis Denny
Published: January 2022

In this research, a Feed-Forward Artificial Neural Network design was implemented on Xilinx Spartan 3S1000 Field Programable Gate Array using XSA-3S Board and prototyped blood type classification device. This research uses blood sample images as a system input. The system was built using VHSIC Hardware Description Language to describe the feed-forward propagation with a backpropagation neural network algorithm. We use three layers for the feed-forward ANN design with two hidden layers. The hidden layer designed has two neurons. In this study, the accuracy of detection obtained for four-type blood image resolutions results from 86%-92%, respectively.
МАТЕМАТИЧНЕ МОДЕЛЮВАННЯ ПІКОВИХ СТРУМІВ ПРИ ВКЛЮЧЕННІ СВІТЛОДІОДНИХ ДЖЕРЕЛ СВІТЛА
Authors: Bodunov Vadim , Dihtyaruk Ihor , Krasnozhon Andrey
Published: January 2022

Включення блоків живлення, які зазвичай використовуються у однофазних електроприймачів з нелінійним навантаженням супроводжується імпульсом струму, який може в декілька разів перевищувати струм спрацювання апаратів захисту, і приводити до їх відключення. збільшенням кількості офісних приміщень з комп’ютерним обладнанням, а також однофазних електроприймачів з нелінійним навантаженням або імпульсними блоками живлення, виникає проблема зниження ефективності електропостачання, яка заключається у некоректному спрацюванні захисних апаратів.
МОНІТОРИНГ ЕКОЛОГІЧНОГО СТАНУ РІЧОК ДЕСНЯНСЬКОГО БАСЕЙНУ
Authors: Movenko Victor
Published: January 2022

В даній роботі, на основі матеріалів Деснянського басейнового управління водних ресурсів Держводагенства України та Департаменту екології та природних ресурсів Чернігівської обласної державної адміністрації був проведений аналіз моніторингу водокористування та водовідведення в Чернігівській області за 30 років, побудований графік водокористування та водовідведення, який показав динаміку змін в цій галузі. Також були визначені основні речовини забруднювачі та підприємства, які скидають забруднені стоки у відкриті водойми. Запропоновані шляхи поліпшення екологічного стану водних ресурсів Чернігівського регіону.
A new species of the genus Caenorhinus Thomson, 1859 (Coleoptera: Rhynchitidae) from Vietnam
Authors:   Institute of Systematic and Ecology of Animals, Siberian Branch, Russian Academy of Sciences, Frunze street-11, Novosibirsk 630091, Russia, Legalov A.A. ,   Altai State University, Lenina-61, Barnaul 656049, Russia,   Tomsk State University, Lenina Prospekt 36, Tomsk 634050, Russia
Published: January 2022

Caenorhinus (Flavodeporaus) belokobylskii sp. n. is described and illustrated from Northwest Vietnam. The new species is similar to C. (F.) lobanovi Legalov, 2021 from Laos but differs in the protibiae of males with mucro, longer and thinner rostrum, slender antennae, densely punctate head and pronotum, convex elytral interstriae, brownish-yellow elytra, slightly tapered aedeagus, and armament of the endophallus.
The long-legged flies (Diptera: Dolichopodidae) from Kurile Islands, with description of a new species of the genus Sciapus Zeller, 1842
Authors:   Institute of Plant Protection, Podbelskogo 3, St. Petersburg-Pushkin, 189620, Russia, Grichanov I.Ya. , Selivanova O.O. ,   Voronezh State University, Universitetskaya Sq. 1, Voronezh, 394006, Russia
Published: January 2022

An annotated list of dolichopodid species recorded from Kurile Archipelago (Russia) is given for the first time. Sciapus basarukini sp. n. from Kunashir Island is described and illustrated. New records for 26 species, including 8 species new for the Kurile Islands, are presented. Long-legged flies are recorded for the first time from the Anuchina, Tanfilyeva, Polonskogo, Urup, Chirpoy, Brat-Chirpoyev, Simushir, Ushishir, Matua, Raikoke, Paramushir, Kharimkotan, Makanrushi, Atlasov, and Onekotan islands. Two species are excluded from the fauna of Kurils. In total, 54 species are recorded from the Kurile Archipelago that appa¬rently makes up 50–60% of the actual dolichopodid fauna in this region. The trends discovered on the Kurile Islands for plant species, i.e. the landscape diversity and the number of plant species increase from small to large islands, and decrease from southern islands northward, are generally supported by the case of flies of the family Dolichopodidae.
A new species of the genus Tocama Reitter, 1902 (Coleoptera: Scarabaeidae, Melolonthinae) from China
Authors:   Engineering Research Center for Forest and Grassland Disaster Prevention and Reduction, Mianyang Normal University, 166 Mianxing West Road, Mianyang, Sichuan 400000, P. R. China, Wang F.L.
Published: January 2022

Tocama huangjianbini sp. n. is described from Fujian province, China. The new species differs from its known congeners by apex of parameres of male genitalia rounded and without setae.
Opportunities for sustainable development of the Russian economy and social sphere through the use of carbon-free technologies
Authors: ПОПОВ В.В.
Published: January 2022

В данной статье рассматриваются актуальные вопросы перехода мировой и российской экономики на низкоуглеродные и безуглеродные технологии. Отмечается влияние стран и отраслей экономики на эмиссию парниковых газов. Приведены основные факторы парниковых газов в Российской экономике, крупные отрасли-эмитенты использования парниковых газов в энергетике горно-химического, нефтехимического производства, машиностроения и др., а также в отраслях сельского хозяйства. Определены основные угрозы для российской экономики в связи с переходом на низкоуглеродные и безуглеродные технологии. Подчеркивается значимость рынков стран и регионов для российских товаров, и как следствие потери для экономики страны с переходом стран – партнеров на сокращение выбросов углеводорода. В долгосрочной перспективе приводятся данные как отражение объемов непосредственных финансовых потерь российский компаний – экспортеров по отдельным отраслям в условиях реализации основных направлений развития безуглеродных технологий в стране. Богатая ресурсная база страны дает определенные преимущества. Одним из возможностей для российской экономики является учет и признание на мировом уровне поглощающей способности лесов. Отмечается необходимость разработки и реализации мероприятий по постепенному переходу на низкоуглеродные технологии в отраслях экономики.

The article examines topical issues of the transition of the global and Russian economies to low-carbon and carbon-free technologies. The influence of countries and sectors of the economy on the emission of greenhouse gases is noted. The main factors of greenhouse gases in the Russian economy, large industries that emit greenhouse gases – energy, mining and chemical, petrochemical production, mechanical engineering, etc., as well as agriculture – were listed. The main threats to the Russian economy in connection with the transition to low-carbon and carbon-free technologies were identified. The importance of the markets of countries and regions for Russian goods and, as a consequence, losses for the country’s economy with the transition of partner countries to reducing hydrocarbon emissions is emphasized. It shows both the size of the direct financial losses of Russian exporting companies by industry and in the long term. The main directions for the development of carbon-free technologies in the country were determined, relying on a rich resource base, which gives Russia certain advantages. One of the opportunities for the Russian economy is the accounting and recognition at the world level of the absorbing capacity of forests. The need to develop and implement measures for the gradual transition to low-carbon technologies in the sectors of the economy is noted.
Managing accounts receivable and accounts payable
Authors: СОЛОВЬЕВА А.П. , СКРЯБИНА А.В. , ЭВЕРСТОВА Л.А. , ПЕТРОВА Ф.Н.
Published: January 2022

Предприятие обязано контролировать дебиторскую и кредиторскую задолженность, следить за сроками погашения, не позволять необоснованного роста суммы дебиторской задолженности, особое внимание уделять по истребованию просроченной задолженности, вести активную работу с контрагентами. Крайне внимательно относиться к расчетам с кредиторами, вовремя погашать им долги, в противном случае предприятие будут иметь штрафные санкции по расчетам с контрагентами – все это объясняет актуальность этой проблемы. Для повышения эффективности использования дебиторской и кредиторской задолженности нами разработаны мероприятия по управлению дебиторской задолженностью.

A company must control accounts receivable and accounts payable, be sure to monitor repayment rates, not allow unreasonable growth of debtors and the amount of their debts, take timely measures to recover overdue debts, and actively work with debtors. It is also necessary to be extremely attentive to settlements with creditors, repay their debts on time, otherwise the company may lose the trust of its suppliers, banks and other creditors, will have penalties for settlements with counterparties – all this explains the relevance of this issue. To improve the efficiency of the use of accounts receivable and accounts receivable, we developed measures on managing accounts receivable.
Heterogeneous Iron Catalyst Fe/SBA-15 towards sp3 C-O bond activation in the absence of base and additive
Authors: Rajendran Chandran , G Satish Kumar
Published: January 2022

A heterogeneous iron-catalyzed (8wt%Fe/SBA-15) mediated direct alkylation of benzyl alcohol with aryl boronic acid in the absence of base and additive via C-O bond activation is demonstrated. This catalyst system led to an efficient Friedel-crafts alkylation reaction. The acidic site in the catalyst system had been confirmed by NH3-TPD, which shows the presence of three different acidic sites viz., weak, moderated, and strong acid sites. The catalyst showed five times recyclable ability.
Biocompatibility and Physiological Thiolytic Degradability of Radically-made Thioester-functional Copolymers
Authors: Bingham Nathaniel , Nisa Qamar , Gupta Priyanka , Young Neil , Velliou Eirini , Roth Peter
Published: January 2022

Being non-degradable, vinyl polymers have limited biomedical applicability. Unfortunately, backbone esters incorporated through conventional radical ring-opening methods do not undergo appreciable abiotic hydrolysis under physiologically relevant conditions. Here, PEG acrylate and di(ethylene glycol) acrylamide-based copolymers containing backbone thioesters were prepared through the radical ring-opening copolymerization of the thionolactone dibenzo[c,e]oxepin-5(7H)-thione. The thioesters degraded fully in the presence of 10 mM cysteine at pH 7.4, with the mechanism presumed to involve an irreversible S–N switch. Degradations with N-acetylcysteine and glutathione were reversible through the thiol–thioester exchange polycondensation of R–SC(=O)–polymer–SH fragments with full degradation relying on an increased thiolate:thioester ratio. Treatment with 10 mM glutathione at pH 7.2 (mimicking intracellular conditions) triggered an insoluble–soluble switch of a temperature-responsive copolymer at 37 °C and the release of encapsulated Nile Red (as a drug model) from core-degradable diblock copolymer micelles. Copolymers and their cysteinolytic degradation products were found to be non-cytotoxic, making thioester backbone-functional polymers promising for drug delivery applications.
Molecular Inhibition for Selective CO2 Conversion
Authors: Creissen Charles , Guillermo Rivera de la Cruz José , Karapinar Dilan , Taverna Dario , Schreiber Moritz , Fontecave Marc
Published: January 2022

Electrochemical CO2 reduction presents a sustainable route to the production of chemicals and fuels. Achieving a narrow product distribution with copper catalysts is challenging and conventional material modifications offer limited control over selectivity. Here, we show that the mild cathodic potentials required to reach high currents in an alkaline gas-fed flow cell permits retention of a surface-bound thiol (4-mercaptopyridine), enabling molecule-directed selective formate generation at high reaction rates. Combined experimental and computational results showed that formate production is favoured due to the inhibition of a CO producing pathway caused by destabilising interactions with the anchored molecule. The immobilisation of molecules to inhibit specific carbon-based products therefore offers a novel approach to rationally tune the selectivity of heterogeneous catalysts.
Isolated Neutral [4]Helicene Radical Provides Insight into Consecutive Two-Photon Excitation Photocatalysis
Authors: Shaikh Aslam C. , Hossain Md Mubarak , Kaur Ramandeep , Moutet Jules , Kumar Anshu , Thompson Benjamin , Huxter Vanessa M. , Gianetti Thomas L.
Published: January 2022

Direct activation of strong bonds in readily available, benchtop substrates offer a straightforward simplification, albeit in most cases existing catalytic systems are limited to unlock such activation. In recent years, a surge of in-situ generated organic radicals that can act as potent photoinduced electron transfer (PET) agents have proved to be a powerful manifold for the activation of remarkably stable bonds. Herein we document the use of N,N′-di-n-propyl-1,13-dimethoxyquinacridine (nPr-DMQA•), an isolated and stable neutral helicene radical, as a highly photoreducing species. This isolable doublet state open shell radical offers a unique opportunity to shed light on the mechanism behind PET reactions of organic radicals. Experimental and spectroscopic studies revealed that this doublet radical has a long lifetime of 4.6 ± 0.2 ns, an estimated excited state oxidation potential of -3.31 V vs SCE, and can undergoes PET with organic substrates. The strongly photoreducing nature of the nPr-DMQA• was experimentally confirmed by the demonstration of photo activation of electron rich aryl bromides and chlorides. We further demonstrated that nPr-DMQA• can be photochemically generated from its cation analog (nPr-DMQA+) allowing catalytic functionalization of aryl halide via a consecutive photoexcitation mechanism (ConPET). Dehalogenation, photo-Arbuzov, photo-borylation and C-C bond formation reactions with aryl chlorides and bromides are reported herein, as well as the α-arylation of carbonyl using cyclic ketones. The latter transformation exhibits the facile synthesis of α-arylated cyclic ketones as critical feedstock chemical for diverse useful molecules, especially in the biomedical enterprises.
Insertion of Degradable Thioester Linkages into Styrene and Methacrylate Polymers
Authors: Rix Matthew , Higgs Samuel , Dodd Eleanor , Coles Simon , Bingham Nathaniel , Roth Peter
Published: January 2022

The thionolactone 3,3-dimethyl-2,3-dihydro-5H-benzo[e][1,4]dioxepine-5-thione (DBT) is shown to homopolymerize and, for the first time, copolymerize with styrene and methacrylates, introducing degradable thioester backbone functionality. The rapid copolymerization with styrene was exploited to produce copolymers through free-radical polymerization in a starve-fed semi-batch setup. The copolymerization of DBT with tert-butyl methacrylate under RAFT conditions was hypothesized to involve selective retardation of DBT-terminal chains that led to a more uniform distribution of degradable thioester linkages between chains. Surprisingly, the aminolysis of DBT homopolymers was accompanied by the intramolecular ether cleavage within the primary degradation product leading to the formation of 2,2-dimethylthiirane and salic-ylamides.
Machine Learning as a Tool for Specific Capacity Prediction of Prospective Potassium Battery Electrodes
Authors: Manna Souvik , Roy Diptendu , Das Sandeep , Pathak Biswarup
Published: January 2022

Application of data science and machine learning (ML) techniques in the domain of materials science has been increasing by leaps and bounds recently. With the help of ML, through input features derived from available databases we can rapidly screen materials based on our desired output. Capacity is one of the important parameters for choosing suitable electrode materials for high energy storage metal ion battery. Exploration of suitable electrode materials for metal ion batteries other than Li ion batteries (LIBs) has been deficient, though there is a need to develop alternative battery technologies with higher energy storage characteristics and environmental safety. In this work, we have considered Li, Na and K-ion electrode materials and their available battery data from Materials Project database to predict specific capacity of prospective K-ion battery electrode materials. Suitable features have been considered and developed to train the various ML algorithms. Mean Absolute Percentage Error has been considered as the performance metrics for assessment of different ML algorithms and among them, kernel ridge regression has been adopted as the most useful to predict the capacity of unknown electrode materials for K-ion battery. Using the value of specific capacity, the number of intercalated K ions in the formula unit of the non-intercalated electrode material compounds have also been calculated. DFT calculations have also been performed to verify the results obtained through ML. Our result shows ML is an encouraging alternative to computationally demanding DFT process as it can screen electrode materials rapidly for battery.
Local Phonon Environment as a Design Element for Long-lived Excitonic Coherence: Dithia-anthracenophane Revisited
Authors: Sidhardh Govind , Ajith Adithi , Sebastian Ebin , Hariharan Mahesh , Shaji Anil
Published: January 2022

Excitonic energy transfer in light harvesting complexes, the primary process of photosynthesis, operates with near-unity efficiency. Experimental and theoretical studies suggest that quantum mechanical wave-like motion of excitons in the pigment-protein complex may be responsible for this quantum efficiency. Observed coherent exciton dynamics can be modelled completely only if we consider the interaction of the exciton with its complex environment. While it is known that the relative orientation of the chromophore units and reorganisation energy are important design elements, the role of a structured phonon environment is often not considered. The purpose of this study is to investigate the role of a structured immediate phonon environment in determining the exciton dynamics and the possibility of using it as an optimal design element. Through the case study of dithia-anthracenophane, a bichromophore using the Hierarchical Equations Of Motion formalism, we show that the experimentally observed coherent exciton dynamics can be reproduced only by considering the actual structure of the phonon environment. While the slow dephasing of quantum coherence in dithia-anthracenophane can be attributed to strong vibronic coupling to high-frequency modes, vibronic quenching is the source of long oscillation periods in population transfer. This study sheds light on the crucial role of the structure of the immediate phonon environment in determining the exciton dynamics. We conclude by proposing some design principles for sustaining long-lived coherence in molecular systems.
La teoría de la sustentabilidad
Authors: Borner Joachin
Published: January 2022

Actualmente, la creciente industrialización está generando gran cantidad de derechos industriales que no son fáciles de  eliminar porque las  técnicas requeridas para esto no han avanzado tanto como las de producción. A esta situación se le agrega el inconveniente de que a  veces, no hay suficiente dinero para resolver los problemas que puedan presentarse  en las industrias, o lo que obliga a privilegiar la solución de este aspecto, dejando de lado el tema del medio ambiente. Se trata entonces, de llevar adelante a prgramas destinados a investigar los impactos  de la creciente industrialización sobre el medio ambiente como contribución al desarrollo sustentable.
Tecnología, información y administración de datos
Authors: Bullón-Salazar Luis-Alberto
Published: January 2022

El gran adelanto de las comunicaciones  ha originado una mayor disponibilidad  de información. Por ello, las empresas deben crear un ambiente  de administración de datos en donde ubique la información como un instrumento  clave que puede ser comercializado. Esto implica identificar los datos importantes para la organización, así como aquellos para otras organizaciones.
Issue of Compliance Control Efficiency at Nuclear Industry Enterprises in Economic Crisis Conditions
Authors: Golovko M. V. , Lapkis A. A. , Myasoedov S. A.
Published: January 2022

The article considers the features of the uranium mining industry development in the context of market fluctuations. The economic factors contributing to the spread of nuclear energy and causing the demand for the products of the uranium mining industry are presented. The competitive advantages of countries in the production and supply of fuel for nuclear power plants are revealed. The conclusion is made about the significant development potential of the Russian Federation (SC "Rosatom") at all stages of the nuclear fuel cycle associated with high-tech repartition of uranium raw materials and nuclear generation. The problem of high capital investments and a long-time lag from the moment of exploration of the deposit to the commissioning of production facilities of the uranium mining industry enterprises is noted. The most profitable investment schemes in the industry are considered taking into account government support.
НАПРЯМИ ТА ФОРМИ ОРГАНІЗАЦІЇ ПРИРОДООХОРОННОЇ РОБОТИ УЧНІВСЬКОЇ МОЛОДІ (ДРУГА ПОЛОВИНА ХХ – ПОЧАТОК ХХІ СТОЛІТТЯ)
Authors: Турбар Т. В.
Published: January 2022

Стаття присвячена теоретичному дослідженню напрямів та форм організації природоохоронної роботи учнів загальноосвітньої школи в Україні у другій половині ХХ – на початку ХХІ століття та визначенню їх значення для сучасності. Аналіз науково-педагогічної та методичної літератури дає можливість стверджувати, що основні форми та методи організації природоохоронної роботи учнів загальноосвітньої школи у досліджуваний період були спрямовані на формування у школярів практичних умінь та навичок раціонального природокористування та відповідального ставлення до природи. Виділено та охарактеризовано такі напрями природоохоронної роботи учнівської молоді: теоретичний, просвітницький та практичний, що реалізовувались через різні види і форми природоохоронної роботи. Доведено, що особливе значення для організації природоохоронної роботи у школі мали різні форми позакласної роботи: індивідуальні, групові та масові, участь школярів у яких давала можливість для практичної реалізації теоретичних природоохоронних знань, отриманих на уроках. Природоохоронна робота в школах у досліджуваний період здійснювалася через організацію різних видів діяльності, таких як: озеленення шкіл та населених пунктів, лісовідновлення, охорона і догляд за лісами, боротьба з ерозією ґрунтів, рекультивація і догляд за ландшафтами, охорона водойм і річкових запасів, корисних комах, птахів і звірів. Природоохоронна робота організовувалася в різноманітних формах, зміст яких визначався її практичною спрямованістю. Аналіз досвіду організації природоохоронної роботи учнів загальноосвітньої школи у другій половині ХХ – на початку ХХІ століття переконав нас у тому, що він містить у собі великий педагогічний потенціал, уміле використання якого дозволить уже сьогодні ефективно вирішувати екологічні проблеми.
ФОРМУВАННЯ НАВИЧОК ЧИТАННЯ У ЗДОБУВАЧІВ ВИЩОЇ ОСВІТИ НА ОНЛАЙН-ЗАНЯТТЯХ З ІНОЗЕМНОЇ МОВИ
Authors: Голощук С. Л.
Published: January 2022

Стаття присвячена питанням упровадження сучасних дистанційних освітніх технологій під час вивчення англійської мови студентами вищих навчальних закладів. Це дослідження спрямоване на виявлення впливу онлайн-навчання на формування навичок читання. У процесі дослідження конкретизується понятійний апарат навчання в форматі онлайн та офлайн; виокремлюються позитивні і негативні сторони навчання із застосуванням електронних технологій для навчального процесу в закладах вищої освіти; аналізується ефективність дистанційних технологій у контексті розвитку навичок читання. Детально охарактеризовані педагогічні шляхи впровадження мультимедійних засобів навчання під час вивчення іноземної мови як ключової умови фундаментальної підготовки кваліфікованого фахівця, орієнтованого на задоволення потреб сучасності. Вдосконалення навичок читання базується на ретельно продуманих і підібраних вправах, кожна з яких має на меті вдосконалення окремого аспекту навички читання. Автор статті пропонує план проведення онлайн-заняття із детальним роз’ясненням його елементів. Такий підхід допоможе викладачам створити структуру заняття, яка може бути адаптована до будь-якої теми та рівня знань студентів. Ще одним важливим елементом для проведення онлайн-занять є способи відображення та обміну матеріалами для читання. Автор наводить практичні рекомендації та пропозиції передачі інформації, які були апробовані на заняттях зі студентами. Досвід показує, що навички читання активно вдосканалюються із застосуванням сучасних онлайн-платформ. У дослідженні запропоновано окремі онлайн-ресурси з детальним описом їх особливостей. Це дасть змогу освітянам вибрати ті, які найбільше відповідають їхнім потребам. У зв’язку з цим розвиток навичок читання під час вивчення іноземної мови розглядається як шлях до творчості, роботи в новому середовищі та з людьми різних культур.
ИННОВАЦИОННОЕ ПРОСТРАНСТВО РЕСПУБЛИКИ ТАДЖИКИСТАН: АНАЛИЗ СОСТОЯНИЯ И ВОЗМОЖНОСТИ РАЗВИТИЯ
Authors: Зоидов Кобилжон , Урунов Асрор , Харчилава Гоча , Джабаров Абдуфаттох
Published: January 2022

Цель. Проанализировать общее состояние, обосновать необходимость формирования и перспективы развития таджикской модели инновационного пространства. Задачи. Исследовать проблемы формирования национального инновационного пространства в таджикской экономике и обосновать перспективы его развития как ключевого фактора социально-экономического прогресса на современном этапе технологической цивилизации. Методология. Методологической базой работы послужили методы эволюционно-институциональной теории, системного анализа, теории производственно-технологический сбалансированности как совокупность ключевых принципов и методов, реализация и использование которых позволит научно-обоснованно подойти к созданию инновационного пространства в национальной экономике. Результаты. Анализ состояния экономики страны показывает неготовность экономической системы к инновациям. Существует барьеры, тормозящие данный процесс. Доказано, что главной особенностью инновационного пространства на современном этапе развития является сложность, многофункциональность, определяющая необходимость принципиально новых подходов к управлению процессами его создания. Выводы. Теоретическая и практическая значимость работы заключается в обосновании приоритетов и перспектив развития инновационного пространства страны. Результаты работы могут служить основой для разработки стратегических планов технолого-инновационного развития республики, а также для формирования более совершенных механизмов технологической политики, включая инновационную политику.
Fluctuations in willingness to communicate of an EFL lecturer: An observation study in Indonesia
Authors: Putri Marhamah Ika
Published: January 2022

Despite the growing number of research on Willingness to Communicate (WTC) in English students, research of teachers’ WTC in English is still scarce. At the same time, the fluctuations of WTC in English in authentic classroom interactions are still under research. This study aims to observe the fluctuations in WTC of the English lecturer in the Indonesian context. The data were collected through video recordings during an online classroom learning session where participants were teaching their students. The data were then transcribed, coded, and analyzed thematically by drawing from MacIntyre et al.’s (1998) Heuristic Model. From the results of the analysis, WTC fluctuations in English are divided into four factors: (1) modeling the use of English in the classroom, (2) the power of affirmation, (3) focusing on the message, and (4) showing language similarity. The implication of this study is also discussed.  DOI: 10.26905/enjourme.v6i2.5983
Students’ attitudes toward the internet usage for learning
Authors: Prasetyo Dodi Erwin
Published: January 2022

This paper examined students’ attitudes toward the use of internet for their learning and measured the differences between male and female students on the usage of internet-assisted in their learning. The participants of this study were 27 senior high school students in East Java, Indonesia, consisted of 6 male and 21 female. The data was gathered through questionnaire. The findings proved that majorities of students felt positive attitudes toward the use of internet for their learning. There were no differences between male and female students on their attitude of internet usage. Suggestions are for pedagogical as well as future researches.   DOI: 10.26905/enjourme.v6i2.6583
Unveiling students’ writing argumentative essays barriers in online learning
Authors: Suhartoyo Eko , Heriyawati Dwi Fita , Ismiatun Febti
Published: January 2022

Due to the closure of Schools and Higher Education Institutions (HEIs), HEIs had shifted the teaching and learning method from face-to-face to Screen-based learning, such as the use of Learning Management System or Moodle, and other applications. Moreover, screen-based learning, such as the use of Learning Management System or Moodle, and other applications the EFL students’ writing argumentative essays barriers in online learning as well as their learning strategies as alternative solutions to cope with them. The research employed descriptive qualitative design. The participants were six EFL students from the fifth semester who experienced writing argumentative essays during pandemic. The instrument used to gather the data was depth interviews about the issue of research. After analysis, it exposed three barriers in writing argumentative essays made by the participants, namely unusualness on the implementation of e-learning for writing, low bandwidth while learning, and students’ discouragement on writing argumentative essays. To overcome the barriers, students must be given a brief simulation previously before attending the real-time class, making classification and analogy for the complex materials up to the simple one, and get a relaxation during the argumentations class. So, it becomes a crystal clear that teacher must assist students to be aware of their weaknesses in writing argumentative essay class so that they can be more creative in writing. Besides, students are expected to be able to solve their barriers by maintaining well communication among the teachers and classmates to sharpen their understanding and implement the best learning styles individually.
HUBUNGAN KEGIATAN LATIHAN KHITOBAH DAN KETERAMPILAN BERBICARA BAHASA ARAB
Authors: Rohelah Sitti
Published: January 2022

Institut Dirosat Islamiyah Al-Amien (IDIA) adalah sebuah lembaga perguruan tinggi yang berada di bawah naungan pondok pesantren Al-Amien Prenduan. Terdapat dua bahasa yakni Arab dan Inggris yang dijadikan sebagai bahasa komunikasi di lembaga ini. Dan demi mengembangkan kemampuan berbahasa asing tersebut, maka IDIA menyelenggarakan beberepa kegiatan seperti kegiatan “latihan khitobah”, yang mana bertujuan untuk melatih kemampuan berbicara (retorika) santri di depan massa. Berangkat dari fenomena yang terjadi, bahwa beberapa santri di lembaga IDIA memiliki kemampuan berbicara bahasa Arab karena dipengaruhi oleh kegiatan “latihan khitobah ” yang rutin dilaksanakan dua kali dalam satu minggu. Maka peneliti tertarik untuk meneliti adakah hubungan  antara dua hal tersebut, serta seberapa besar hubungan  antara keduanya. Adapun jenis penelitian yang digunakan dalam artikel ini adalah penelitian korelasi, dengan pendekatan kuantitatif. Sesuai dengan namanya, maka kegiatan pengumpulan dan penafsiran data, penampilan hasil penelitian, serta pemahaman akan kesimpulan, membutuhkan menggunakan angka-angka. Penggunaan metode pengumpulan data adalah angket dan tes. Angket yang digunakan untuk mencari data tentang kegiatan “latihan khitobah”, sedangkan tes digunakan untuk mencari data tentang kemampuan berbicara bahasa arab. Metode analisis data yang digunakan adalah rumus product moment. Adapun hasil dari penelitian ini adalah rendahnya  hubungan antara kegiatan latihan khitobah dan keterampilan bicara berbahasa Arab mahasantri  semester II dan IV Institut Dirosat Islamiyah Al- Amien Prenduan (IDIA) Tahun 2020/2021. Hal ini terbukti dengan angka peneliti dapatkan setelah melakukan penelitian dengan angka 0,055 (interpretasi rendah) karena mendakati antara 0,200 sampai dengan 0,0400.
KECERDASAN EKSISTENSIAL : Pemahaman Materi Fiqih Tentang Salat Jenazah Dengan Praktik
Authors: Halim Alfin
Published: January 2022

Tingkat kecerdasan anak didik biasanya diukur oleh tingkat kematangan berpikir anak didik. Salah satu kecerdasan yang dibutuhkan siswa adalah kecerdasan eksistensial. Kecerdasan eksistensial ditandai dengan kemampuan berfikir sesuatu yang benar. Tujuan penelitian ini adalah untuk mengetahui adanya pengaruh serta seberapa besar pengaruh kecerdasan eksistensial terhadap pemahaman materi fiqih tentang shalat jenazah pada siswa dan untuk mendiskripsikan apakah praktek dapat memoderasi pengaruh kecerdasan eksistensial terhadap pemahaman materi fiqih tentang shalat jenazah pada siswa. Penelitian ini dirancang dengan menggunakan pendekatan kuantitatif dengan jenis korelatif. Variabel bebas (X) adalah kecerdasan eksistensial, sementara variabel terikat (Y) adalah pemahaman materi fiqih tentang shalat jenazah dan Variabel moderasi (Z) adalah praktek. Penelitan ini menggunakan jenis populasi sebesar 18 responden. Teknik pengumpulan data mempergunakan metode angket, dan metode dokumentasi. Teknik analisis data adalah uji regresi linear dengan bantuan Statictical Package For Social Science (SPSS) For Windows Versi 24.0. Kesimpulan penelitian adalah ada pengaruh kecerdasan eksistensial terhadap pemahaman materi fiqih tentang shalat jenazah pada siswa kelas VII MTs. Nurulhuda. Hal ini dibuktikan dengan nilai sig 0,001 berada dibawah 0,05. Besar pengaruh kecerdasan eksistensial terhadap pemahaman materi fiqih tentang shalat jenazah pada siswa kelas VII MTs. Nurulhuda adalah 73,2%. Hal ini sesuai nilai pada kolom R adalah 0,732. Semnatara praktek dapat memoderasi pengaruh kecerdasan eksistensial terhadap pemahaman materi fiqih tentang shalat jenazah pada siswa kelas VII MTs. Nurulhuda Pakandangan Barat Sumenep tahun pelaaran 2020/2021, hal ini  dapat dilihat dari nilai R2 pada regresi pertama sebesar 0,536 atau 53,6 % sementara setelah ada persamaan regresi kedua nilai R2 naik 0,602 atau 60,2%.