bluuebunny/crossref_metadata_2025 huggingface dataset:
MENATAP TUHAN DALAM HARMONI SATYAM, SIVAM, SUNDARAM: TELAAH FILOSOFIS ATAS METAFORA KOSMIK
Authors: Krishnanandayani Jyothi Devi , Maheswari Prasanthy Devi
Published: December 2024

Upanisad, salah satu literatur suci dalam filsafat Hindu yang memuat berbagai metafora alam untuk menjelaskan konsep ketuhanan yang tidak terpikirkan dan transendental. Metafora alam ini menjadi jembatan yang memungkinkan manusia memahami Tuhan sebagai Satyam (kebenaran), Sivam (kebaikan), dan Sundaram (keindahan). Penelitian ini dilatarbelakangi oleh eksplorasi mendalam pada teks-teks Upanisad yang menggambarkan dimensi ketuhanan dengan menggunakan unsur-unsur alam semesta, yang mana dimensi ini tidak hanya bersifat spiritual tetapi juga relevan dalam kehidupan manusia. Tujuan dari penelitian ini adalah untuk mengidentifikasi dan menganalisis metafora alam dalam Upanisad dengan memahami bagaimana metafora tersebut menggambarkan sifat Tuhan dalam tiga aspek utama: kebenaran, kebaikan, dan keindahan. Penelitian ini menggunakan metode kualitatif dengan pendekatan hermeneutik untuk menafsirkan teks-teks Upanisad secara kontekstual, disertai dengan analisis filosofis untuk memahami implikasi simbolisme alam terhadap konsep ketuhanan. Hasil penelitian menunjukkan bahwa metafora alam digunakan untuk menggambarkan unsur keabadian, kemurnian, dan universalitas Tuhan. Metafora alam dalam Upanisad bukan hanya sebuah ekspresi estetika, tetapi juga medium filosofis yang mendalam untuk menggambarkan Tuhan sebagai Satyam, Sivam, Sundaram. Simbolisme ini memperkuat pemahaman bahwa Tuhan tidak hanya hadir dalam dimensi spiritual tetapi juga terwujud dalam harmoni alam semesta, sehingga dapat memberikan inspirasi bagi manusia untuk menjalani hidup yang selaras dengan prinsip-prinsip ilahi.
Selain itu, hasil penelitian ini diharapkan mampu menjadi referensi bagi kajian lintas disiplin antara filsafat, teologi, dan ekologi spiritual, terutama dalam mengaitkan hubungan antara manusia, alam, dan Tuhan.
UMA BREVE ANÁLISE SOBRE A INTERPRETAÇÃO DO STF E OS CONTORNOS DADOS À ADI 6298: UMA NOVA POLÍTICA CRIMINAL?
Authors: Arruda Ana Julia Pozzi , Rigacci Mariana Delgado Britez
Published: December 2024

No presente trabalho, tem-se como paradigma a Ação Direta de Inconstitucionalidade 6298, que trata acerca do instituto do Juiz das Garantias. Tal instituto é um importante conquista para um Estado Democrático de Direito, já que confere visa aperfeiçoar o Sistema Acusatório, ao contribuir para que o haja uma separação entre aquele que irá julgar o processo e aquele que tomará decisões na fase do Inquérito. O presente trabalho visa discutir o posicionamento do Supremo Tribunal Federal no caso a partir do que seria a política criminal. Assim, de forma bastante sintética, primeiro buscou-se esclarecer o que é a política criminal e como ela deve ser considerada no âmbito do Direito Processual Penal; a partir de tais marcos teóricos, confronta-se como o juiz de garantias foi concebido como medida de política criminal; e, por fim, contrastando a previsão legal do instituto com a interpretação dada pelo Supremo na referida ADI, buscou-se verificar se houve adequada observância aos valores constitucionais. A partir de tais objetivos buscou-se delinear se é possível verificar no posicionamento do Supremo Tribunal Federal frente ao instituto do juiz de garantias, uma postura ativa na construção da política criminal, incumbência que, constitucionalmente, não lhe seria dada.
DIREITO AO ESQUECIMENTO NA INTERNET: A EXPOSIÇÃO DE CRIADORES DE CONTEÚDO NA PLATAFORMA DIGITAL DO TIKTOK
Authors: Pinto Yanka dos Santos , Ferreira Rafael Fonseca
Published: December 2024

O avanço das redes sociais provocou mudanças na produção audiovisual, considerando sua capacidade de compartilhar e interagir com diversas pessoas espalhadas no espaço virtual. Este artigo analisou o desenvolvimento das mídias digitais nas atividades de entretenimento, bem como o impacto das ações executadas pelos criadores de conteúdo e seu direito ao esquecimento nestes ambientes on-line. Utilizou-se o método indutivo, por meio de revisão de literatura, sendo aplicada a técnica de pesquisa de documentação indireta. Discutiram-se as inovações apresentadas pelos novos meios de comunicação e informação no contexto sociodigital e a exposição constante das pessoas nas redes como forma de rendimento. Também foram analisados os riscos da mercantilização dos indivíduos enquanto criadores de conteúdo, além do direito ao esquecimento das ações passadas exercidas por estes produtores audiovisuais. Concluiu-se pela necessidade de uma regulamentação específica sobre o direito ao esquecimento para garantia da dignidade humana e dos direitos da personalidade destes sujeitos, propondo também uma atuação mais efetiva dos provedores das plataformas digitais.
Dynamics of Collective Memory in Political Rebranding in the Digital Era
Authors: Ratna Puspita  , Budiharjo Slamet , Shenthya Winarty
Published: December 2024

This study investigates the usage of the term “gemoy” in the political context, particularly in relation to Prabowo Subianto, and how this term emerged and evolved in conversations on social media platform X, from post-2019 Election to the lead-up to the 2024 Election. Qualitative content analysis method is employed to comprehend the public’s response to the usage of the term “gemoy” as part of Prabowo’s political rebranding, as well as the criticisms that surfaced in the context of society’s collective memory regarding Prabowo’s controversial track record, especially concerning past human rights violations. Findings indicate that while there is a positive response to these rebranding efforts, particularly from Generation Z, criticisms regarding the use of “gemoy” as an attempt to divert attention from more fundamental substantive issues, and resistance to Prabowo’s political rebranding, remain significant, particularly from X users. However, it’s noteworthy that X users do not dominate the population in Indonesia, and the popularity of platform X is influenced by various factors, including its ability to meet its users’ preferences in terms of fast and concise communication.
Keywords: political rebranding, collective memory, Prabowo Subianto, 2024 election.
Construction Of Kompakers Jogja's Identity Through Food Photography Challenge
Authors: Ariantini Tiyas , Wibowo Arif Ardy , Samsudin Mat Redhuan
Published: December 2024

The gradual evolution of media alters the manner in which humans engage with one another. The media now serves as a tool for constructing one's identity. Instagram is one of the media platforms utilized. Instagram, a social media platform, is no longer solely utilized for personal purposes, but now serves as a community tool for disseminating information to its audience. One community that made use of this amenity is the Kompakers Jogja. This study examines the process by which members of the Kompakers Jogja develop their identities on the social media platform Instagram. The analysis is based on Gauntlett's theory of identity formation. The research methodology employed is qualitative, specifically utilizing the phenomenological approach to investigate the production of social reality. Through the utilization of observation and interview methodologies. This study utilizes seven informants as sources. The findings of this study indicate that individuals are actively shaping their identities on the social media platform Instagram by posting photos accompanied by captions. Three types of identity constructs are formed: professional and expertise identity, connection identity, and character identity.
Дослідження методів штучного інтелекту для створення інтелектуальних ігрових агентів
Authors:   Державний університет «Житомирська політехніка», Марчук Галина , Коротун Ольга ,   Державний університет «Житомирська політехніка», Левківський Віталій ,   Державний університет «Житомирська політехніка», Українець Микола ,   Державний університет «Житомирська політехніка»
Published: December 2024

Постійний розвиток технологій машинного навчання значно впливає на ігрову індустрію. Штучний інтелект дозволяє створювати все більш складних і розумних ботів, які здатні до навчання та самовдосконалення, що відкриває нові перспективи для розробників ігор, дозволяючи їм створювати більш інтерактивні та захоплюючі ігрові світи. Це дослідження спрямоване на створення інтелектуального шахового агента, який за допомогою методів машинного навчання та алгоритмів пошуку зможе самостійно вдосконалювати свої шахові навички та адаптуватися до різноманітних стилів гри супротивників. Представлена в статті інформація має науково-методичний характер. Очікується, що розглянуті алгоритми можуть бути використані не лише у шахах, а й у інших галузях, що вимагають прийняття рішень в умовах невизначеності. Було проведено дослідження різних алгоритмів машинного навчання, включаючи традиційні методи, і такі як глибинне навчання (зокрема, згорткові та рекурентні нейронні мережі). За результатами аналізу було визначено, що глибинне навчання є найперспективнішим методом для розпізнавання складних шахових патернів та автоматичного формування ефективних стратегій. З метою оптимізації процесу прийняття рішень ботом було обрано систему штучного інтелекту AlphaZero, розроблену компанією DeepMind, яка базується на засадах глибинного навчання. AlphaZero є потужним інструментом для гри в шахи завдяки своїй здатності до самонавчання, глибинним нейронним мережам та ефективному алгоритму пошуку в дереві ходів. Вона відкриває нові горизонти в галузі штучного інтелекту й демонструє, що машини можуть не тільки перевершувати людей у складних інтелектуальних задачах, а й робити це принципово новими способами. AlphaZero не спеціалізується тільки на шахах, вона може бути адаптована для будь-якої гри, в якій ходи гравців чергуються. Це робить її дуже універсальним інструментом для дослідження штучного інтелекту.
Дослідження сучасних напрямів моделювання процесів реагування на надзвичайні ситуації
Authors:   Національний університет «Чернігівська політехніка», Прищепа Владислав , Задорожній Артем ,   Національний університет «Чернігівська політехніка»
Published: December 2024

Стаття надає огляд сучасних підходів до моделювання процесів реагування на надзвичайні ситуації. Описані основні тенденції в застосуванні різних видів моделей для забезпечення моделювання процесів реагування на надзвичайні ситуації. Зокрема, досліджено агентне моделювання, моделі на основі теорії ігор, використання системної динаміки та моделювання на основі машинного навчання. Стаття включає аналіз можливостей розвитку та ймовірних напрямків майбутніх досліджень у цій сфері, що можуть сприяти оптимізації роботи рятувальних служб та підвищення швидкості й точності реагування.
Багатошарові леговані нітридні покриття системи TiAlN
Authors:   Інститут надтвердих матеріалів ім. В.М. Бакуля НАН України, Клименко Сергій , Манохін Андрій ,   Інститут надтвердих матеріалів ім. В.М. Бакуля НАН України, Клименко Сергій ,   Інститут надтвердих матеріалів ім. В.М. Бакуля НАН України, Мельнійчук Юрій ,   Інститут надтвердих матеріалів ім. В.М. Бакуля НАН України, Чумак Анатолій ,   Інститут надтвердих матеріалів ім. В.М. Бакуля НАН України, Копєйкіна Марина ,   Інститут надтвердих матеріалів ім. В.М. Бакуля НАН України, Береснєв В’ячеслав ,   Харківський національний університет імені В. Н. Каразіна
Published: December 2024

Наведено результати досліджень гами багатошарових наноструктурних покриттів на основі системи TiAlN – стру-ктурного стану, морфології, складу, мікрогеометрії інтерфейсу. Покриття загальною товщиною 7–8 мкм з товщиною ша-рів (TiAlN/СrN) 20–30 нм, нанесене вакуумно-дуговим методом на основу з надтвердої кераміки на основі кубічного нітриду бору. Розглянуто вплив на показники стану інтерфейсу покриттів легування їхніх матеріалів Y та Si, комплексом елементів – Y, Zr, Nb. На основі аналізу результатів вивчення інтерфейсу покриттів методом скетч-тестування встановлено агезійний і когезійний механізми руйнування покриттів залежно від рівня легування їхніх матеріалів, запропоновано перспективні напрями використання покриттів для застосування в різальному інструменті з PcBN
Трансформація понять і завдань функціонального зонування території
Authors:   Київський національний університет будівництва і архітектури, Петраковська Ольга , Михальова Марія ,   Київський національний університет будівництва і архітектури
Published: December 2024

Функціональне зонування дозволяє оптимізувати використання територій, забезпечуючи збалансоване поєднання різних функцій; допомагає уникнути хаотичної забудови, яка може призводити до конфліктів між різними ти-пами землекористування; сприяє ефективній організації міського простору та мінімізує витрати на будівництво й обслуговування інфраструктури тощо. У статті досліджено трансформацію понятійного апарату та завдань фу-нкціонального зонування в Україні та їх взаємозв’язок з підходами до просторового планування. Проведене дослідження дозволило структурувати етапи трансформації понять і завдань функціонального зонування територій в Україні Трансформації функціонального зонування території відбулася у відповідь на зміни в економічних умовах, суспільних потребах і технологічних можливостях. Результати дослідження ілюструють, що в Україні цей процес ускладнений неврегульованістю нормативно-правової бази й інерційністю структур, у повноваженнях яких є різні складові цього комплексного процесу. Стаття є науково-методичною.
Аналітичні дослідження силового навантаження привода натискної плити у штанцювальному пресі
Authors:   Національний університет «Львівська політехніка», Регей Іван , Книш Олег ,   Національний університет «Львівська політехніка», Бегень Петро ,   Національний університет «Львівська політехніка», Михайлів Юрій ,   Національний університет «Львівська політехніка»
Published: December 2024

Відповідальною і важконавантаженою є штанцювальна техніка, призначена для виготовлення розгорток пако-вань із картону. Наголошено на актуальності завдання з дослідження силового навантаження привода натискної плити. Наведено аналітичні залежності для геометричного синтезу ланок розклинювального механізму її привода. Встановлено, що процес штанцювання картонних заготовок натискною плитою включає дві фази. Наведено аналі-тичні залежності для розрахунку складових сил навантаження ланок розклинювального механізму та моменту сили на приводному валу. Встановлено, що протягом початкової фази силове навантаження привода суттєво менше за навантаження протягом основної фази. Розкрито реальну картину характеру навантаження привода натискної плити у процесі штанцювання картонних розгорток.
Minimally invasive glaucoma surgery: A comprehensive review
Authors: Dubey Suneeta , Drishti C.
Published: December 2024

Minimally Invasive Glaucoma Surgery (MIGS) has emerged as a major advancement in the management of glaucoma, providing a less invasive and safer alternative to traditional surgeries. Conventional glaucoma surgeries are typically reserved for patients with advanced glaucoma who are on “maximally tolerated medical therapy” or those with advanced disease. However, there is often a tendency to delay surgery because of the risk of potential complications of these invasive surgeries. MIGS is characterized by a high safety profile, with a lower risk of severe complications compared to traditional glaucoma surgeries. It is particularly suitable for patients with mild-to-moderate open-angle glaucoma. MIGS tends to bridge the therapeutic gap between medical management and traditional invasive surgeries. MIGS encompasses a variety of techniques and devices, such as Trabectome, iStent, Kahook Dual Blade, Gonioscopy-Assisted Transluminal Trabeculotomy (GATT), Hydrus, and minimally invasive bleb surgeries like PreserFlo Microshunt and Xen Implant. Post-operative recovery is generally quicker, with many patients experiencing improvements in their quality of life due to reduced medication dependence and faster healing.However, like all other interventions, MIGS is not without potential complications. Transient hyphema, IOP spikes, and device-related issues can occur. This review classifies MIGS procedures based on their anatomical targets, which include trabecular meshwork bypass, suprachoroidal space, and subconjunctival filtration.It explores the mechanisms, approaches, and clinical outcomes associated with different types of MIGS. A comprehensive literature search using PubMed was conducted, studies published between January 2000 and March 2023 were thoroughly read to gather insights into the evolving terminology, indications, contraindications, and classification of MIGS procedures. In conclusion, MIGS offers a promising alternative for glaucoma management, especially for patients with mild-to-moderate disease. Its safety, rapid recovery, and ability to reduce medication burdens make it a valuable addition to glaucoma armamentarium. However, further research and long-term studies are needed to fully establish the efficacy and safety of these innovative techniques.
A Study on the Direction of Art Education from the Cases of AI-based Art Classes in Posthumanism Focusing on Art Education in Middle School
Authors:   Society for Art Education of Korea, AN Sangeun , SIM Youngok
Published: December 2024

This study aims to explore the direction of art education that can foster post-humanistic thinking by analyzing learners' reflections after implementing an AI-based art education program for middle school students. To this end, 3rd grade students at S Middle School participated in both traditional art expression methods and AI-assisted classes on topics such as pottery making, portraiture, and landscape painting. Students' views on these two teaching methods were surveyed and analyzed. This led to the following implications: First, AI was seen as an efficient and straightforward tool for creativity. Second, it was confirmed that there are limitations in expressing the artist's inner self during the AI-based image generation process. These findings suggest that, despite the limitations of AI-based art activities in accurately expressing students' inner selves, AI holds significant potential as an innovative tool and paves the way for a new educational approach centered on the collaborative relationship between humans and AI.
A Case Study of Design Classes Based on Mixed Reality(MR) Focusing on the interaction between humans and technology
Authors:   Society for Art Education of Korea, LEE Sunhye
Published: December 2024

This study aimed to analyze the impact of design classes based on mixed reality (MR) on the learning experiences and outcomes of elementary school students and to explore the characteristics of human-technology interactions in the MR environment. The research was conducted with 24 sixth-grade students at S Elementary School in Seoul, allowing learners to experience creative learning in an immersive environment where virtual and real worlds are combined through MR technology. The results show that MR-based design education significantly enhanced students' spatial understanding and problem-solving abilities, and positively influenced collaborative learning and creative interaction. Additionally, human-technology interaction in the MR environment provided students with the experience of handling both virtual and physical objects simultaneously, contributing to the improvement of digital literacy and collaborative problem-solving skills. These findings suggest the potential of MR technology as an innovative educational method suitable for the digital age, highlighting its applicability in future educational settings.
An Action Research on Philanthropy Design Project for Practicing Social Justice in Middle School Art Classes
Authors:   Society for Art Education of Korea, LEE Jeongmin , SUNG Youlkwan
Published: December 2024

This study aims to reflect on the results of the operation of the philanthropy design project for practicing social justice and to provide implications for practicing social justice through art education. Art education as a practice of social justice is not an exploration of beautiful colors or shapes, but a practice linked to life that continuously communicates and solves problems that can become social issues. Accordingly, through the philanthropy design project, problems are found in socio-cultural aspects, public interests are pursued, and problems are solved with novel and original designs. In particular, this study was designed to provide in-depth education by organically linking the content elements of knowledge and understanding, process and function, and value and attitude in the 2022 revised curriculum, ‘Teaching and Learning in School Curriculum Design and Operation.’ In the first stage (emotion), the class was developed as a student- participatory class, which provided students with a deep experience related to life. In the second stage (cognitive) area, the procedural knowledge of process and function enhanced cooperation and creative problem-solving skills, and in the third stage (behavioral) area, the ability to practice social justice linked to life was demonstrated by internalizing it in terms of values and attitudes.
Investigation of Physical Performance of Young Elite Football Players: "Positional Comparison"
Authors: İleri Mehmet , Gündüz Kerem , Badur Kadir İrem , Bektaş Merve
Published: December 2024

This study aims to compare the positional physical performances of young elite A league football players. A total of 38 players from MKE Ankaragücü's U17 and U19 categories, competing in the young elite league during the 2023-2024 season, participated in the research. A Shapiro-Wilk normality test was applied to the data obtained in the study, and based on the results of the normality test, the Spearman test was used for correlation analysis. The Kruskal-Wallis test was used to determine the differences between groups, and the Mann-Whitney U test was used to define these differences. Additionally, Spearman correlation analysis was used to examine the relationship between the participants' physical performance data. When the vertical jump variable was examined, it was found that defenders performed better than goalkeepers in vertical jump (p<0.05), midfielders performed better than goalkeepers (p<0.01), and forwards also performed better than goalkeepers (p<0.05). Regarding the long jump variable, it was found that midfielders performed better in vertical jump than goalkeepers (p<0.01). When the 20-meter sprint variable was examined, it was found that defenders performed better than goalkeepers in the 20m sprint (p<0.01), midfielders performed better than goalkeepers (p<0.01), and forwards also performed better than goalkeepers (p<0.05). For the 40m sprint performance variable, it was found that defenders performed better than goalkeepers in the 40m sprint (p<0.05), midfielders performed better than goalkeepers (p<0.01), and forwards also performed better than goalkeepers (p<0.05). In conclusion, the findings of the study reveal that defenders, midfielders, and forwards exhibit significant superiority in vertical jump, long jump, and sprint performances compared to goalkeepers.
Linnett is back: understanding chemical bonds through the lens of Born maxima
Authors: Menéndez-Herrero María , Francisco Evelio , Martín Pendás Angel
Published: December 2024

The classical Lewis-Langmuir electron pair model remains central to chemical bonding theories, despite its inherent contradictions with quantum mechanical principles such as antisymmetry. This paper revisits the long-forgotten Linnett’s Double Quartet (LDQ) model, which integrates spin considerations into chemical bonding. We demonstrate that the distribution of electrons at the maxima of the square of the wavefunction (Born maxima) highlight the rigidity of same-spin electron blocks and validate the LDQ framework in atoms and molecules. A generalized LDQ model accounts for all bond types --- including covalent, polar-covalent, ionic, dative, and electron-deficient --- and directly incorporates electron correlation effects, providing a rigorous yet intuitive approach to bonding. This perspective also reveals fundamental flaws in conventional mean-field descriptions that ignore the correlated motion of electrons. By bridging traditional and quantum paradigms, the generalized LDQ model offers a robust tool for understanding chemical bonding, with implications for education, experimental design, and theoretical advancements.
Discovery of de novo Macrocycle Inhibitors of Histone Deacetylase 11
Authors: Danková Daniela , Nielsen Alexander , Zarda Anna , Hansen Tobias , Hesse Marie , Benová Michaela , Tsiris Athanasios , Bartling Christian R. O. , Will Edward J. , Strømgaard Kristian , Moreno-Yruela Carlos , Heinis Christian , Olsen Christian Adam
Published: December 2024

Histone deacetylase (HDAC) enzymes are epigenetic regulators that affect diverse protein function by removing acyl groups from lysine side chains throughout the proteome. The most recently discovered human isozyme, HDAC11, differs from other HDACs in substrate preference and tissue expression profile. Elucidation of the biological function of this enzyme has been scarce and only a few chemical probes to help advance this insight have been developed thus far. Here we discovered macrocyclic inhibitors that exhibit selectivity for HDAC11 and penetrate the cytoplasmic membrane in cultured cells as determined by the chloroalkane penetration assay. Our work establishes the combination of de novo macrocycle synthesis with incorporation of N-alkylated hydroxamic acid moieties as a viable strategy for targeting HDAC11. Further, this study demonstrates the potential of applying macrocyclic peptide-based library synthesis to directly furnish high-affinity, cell-permeating ligands. The discovered inhibitors comprise tool compounds for the investigation of the biological function of HDAC11.
Recycling of Polyolefins Using Recycled PVC under Sunlight
Authors: Liu Heng , Ji Ding-Wei , Xu Su-Yang , Wang Zhi-Hui , Guo Shi-Yu , Chen Qing-An
Published: December 2024

The recycling of polyolefin plastics is often hindered by high energy consumption and low economic efficiency. In particular, the recycling of poly(vinyl chloride) (PVC) is especially challenging. Here, we present an innovative protocol to recycle discarded PVC into a photothermal catalyst for the depolymerization of polyolefins under sunlight. By dechlorinating the PVC, we harness its unique ability to converts sunlight into the energy required to break C-C bonds in polyolefins. This protocol allows for the transformation of low-density polyethylene (LDPE), high-density polyethylene (HDPE), and polypropylene (PP) into waxes enriched with terminal olefins, which can be further utilized for the synthesis of surfactant. Furthermore, this protocol enables the conversion of polystyrene, poly(methyl methacrylate), poly(α-methyl styrene), styrene-acrylonitrile copolymer, and acrylonitrile-butadiene-styrene (ABS) into their respective monomers. This broad applicability makes our protocol suitable for the recycling of a wide range of real-life plastic products and their mixtures under ambient environment. Notably, with the aid of just 0.1 wt% catalyst, a successful depolymerization of kilogram-scale PS waste, such as plastic cups, using solar energy has been achieved. Additionally, the catalysts derived from PVC can be reused, thereby enhancing the sustainability and cost-effectiveness of the depolymerization of polyolefins. Our study presents a promising solution to the recycling of PVC and polyolefin plastics, leveraging solar energy to create a sustainable and efficient recycling process.
Coherent Vibrational Dynamics in an Isolated Peptide Captured with 2D IR Spectroscopy
Authors: Ma Zifan , McCaslin Laura , Fournier Joseph
Published: December 2024

Quantum mechanical vibrational coherence transfer processes play important roles in energy relaxation, charge transfer, and reaction dynamics in chemical and biological systems, but are difficult to directly measure using traditional condensed-phase nonlinear spectroscopies. Recently, we developed a new experimental capability to obtain two-dimensional infrared (2D IR) spectra of molecular systems in the gas phase that enables the direct measurement of coherence pathways. Herein, we report ultrafast 2D IR spectroscopy of the peptide glutathione (GSH) isolated and cryogenically cooled in the gas phase. Six vibrational modes were simultaneously excited within the amide I and II region. The spectral dynamics of both diagonal and off-diagonal cross peak features exhibit long-lived oscillatory behavior consistent with the presence of coherent vibrational dynamics. The oscillatory signatures deviate significantly from the expected quantum beating pathways predicted from standard nonlinear response theories. These deviations indicate the presence of additional nonlinear pathways, including coherence transfer processes. Quantum chemistry calculations indicate large anharmonic couplings between the excited vibrational modes in GSH and, critically, strong coupling between the excited modes and numerous low-frequency modes that act as a bath to mediate coherence transfer. The data provide important new benchmarks for modeling coherence transfer dynamics and system bath interactions in open quantum systems free from solvent effects.
Distributional impact of tax and welfare policies: Budget 2025
Authors: Doorley Karina , Dunne Shane , Keane Claire , Sándorová Simona , Simon Agathe
Published: December 2024

In this Special Article we analyse the distributional impact of Budget 2025. Similar to last year, many reforms in this Budget were temporary measures specifically aimed at combatting cost of living pressures. Compared to a baseline pegged to wage growth, the permanent measures, such as increases in the tax band, tax credits and social welfare rates, are broadly progressive, with households in the bottom quintile of income expected to see an increase of around 0.9% of equivalised disposable income, and those in the top quintile to see increases of 0.5%. When accounting for temporary measures, the average household is estimated to see an increase of just 0.2% in their equivalised disposable income, and the broadly progressive effect of the permanent measures becomes less clear. These results are driven by the fact that many temporary measures have either been frozen (and therefore reduced in real terms) or have been explicitly reduced, such as the reduction in energy credits. We show that from 2020 to 2025 permanent changes to the tax and welfare system have resulted in small average income losses (-0.3% of disposable income) compared to policy changes pegged to wage growth. While temporary measures have been successful in helping households deal with rising prices, their inevitable phasing out will cause issues if headline welfare payments fail to keep pace with income growth. We also find that households with children tended to benefit more from the Budget 2025 measures, such as the double Child Benefit payment, but that the measures have little anticipated downward effect on child poverty rates, suggesting a targeting issue.
Entre proie et prédateur : un récit de chasse dans la littérature québécoise ?
Authors: Defraeye Julien , Powers Scott M.
Published: December 2024

Introduction au dossier "Entre proie et prédateur : le récit de chasse dans la littérature québécoise"
Le discours de la chasse à l’épreuve du genre viatique (XVIe-XVIIe siècles)
Authors: Hebbinckuys Nicolas
Published: December 2024

Cet article explore le discours cynégétique dans les récits de voyage des débuts de la Nouvelle-France (seizième au dix-septième siècles). Confrontant les témoignages de chroniqueurs emblématiques (Lescarbot, Champlain, Leclercq), il souligne l’importance de la chasse tant pour la survie des premiers explorateurs que dans la mise en place d’un système économique basé sur l’exploitation faunique. Il soutient que l’activité cynégétique du Canada s’est cristallisée dans l’imaginaire collectif des Européens, à la fin de la Renaissance, avec un discours sur l’abondance des ressources animales et l’espoir d’en tirer profit. Dans une perspective plus ethnographique, il examine comment les relationnaires développent – alors qu’ils décrivent les outils, les techniques et les croyances autochtones en lien avec la chasse – une rhétorique de la singularité pour relater l’altérité américaine. Enfin, il met en relief comment le récit de chasse est à l’origine d’une réflexion critique sur la contestation des privilèges de caste, la chasse étant l’apanage des seigneurs dans la société de l’Ancien Régime.
Repenser l’éthique de la chasse à l’aune des pratiques autochtones dans deux récits de Julien Gravelle
Authors: Powers Scott M.
Published: December 2024

Cet article présente la perspective ambivalente sur la chasse qui ressort des textes littéraires de Julien Gravelle. Dans Musher (2014), un conducteur de traîneau à neige prône une pratique cynégétique éthique pour le bien-être des animaux, humains et non humains. Tout en décriant les maux de l’élevage industriel, le musher propose que le respect des animaux dans le monde occidental passe par un retour à la chasse. Son argument s’appuie sur des perceptions exogènes communes de la pratique cynégétique chez les Autochtones du Québec. En parallèle, sur le registre de l’ironie, le cas de Musher ainsi que la nouvelle « L’homme de vers » (2015) dramatisent la putative invraisemblance d’un retour à une culture fondée sur la chasse dans le monde occidental, d’autant plus qu’aux yeux des narrateurs les cultures autochtones sont elles-mêmes vouées à l’extinction. Alors que l’écrivain d’origine française souscrit au mythe de « la disparition de l’Indien », un dialogue entre Blancs et Autochtones sur l’importance du rôle de la chasse pour l’avenir des rapports éthiques entre les humains et l’écosystème – rôle prématurément exclu dans les textes de Gravelle – se développe par d’autres auteurs contemporains, blancs et autochtones, européens et québécois.
Le regard impérialiste de la voyageuse : Catherine de Bourboulon au dix-neuvième siècle
Authors: Meng Qingya
Published: December 2024

Cet article est consacré au voyage de Catherine de Bourboulon (1827-1865) avec son mari, diplomate français, à travers le nord de la Chine, la Mongolie et la Russie, au cours duquel elle rédige un journal qui sera publié à titre posthume, après son retour en France, en 1866. L’étude analyse deux types de discours, d’une part, l’expression d’un très fort enthousiasme qui semble traduire un désir de liberté ; d’autre part, l’expression d’une foi inébranlable dans la supériorité présumée de la civilisation occidentale.
Le « véritable Orient » de Cristina Belgiojoso, si loin et pourtant si proche
Authors: El Kettani Soundouss
Published: December 2024

La princesse Cristina Trivulzio di Belgiojoso a été une romancière, une essayiste, une salonnière parisienne et une partisane enflammée de l’unité italienne. Son engagement politique la mènera à l’exil pendant plusieurs années de sa vie, dont cinq où elle s’installera dans une vallée en Turquie et durant lesquels elle fera un long voyage jusqu’en Syrie. Sa correspondance de l’époque, ses récits de voyages et ses contes orientaux sont le reflet d’un regard complexe porté sur cet ailleurs qu’elle découvre, et sur les êtres qu’elle rencontre. À ces yeux d’Européenne catholique érudite, ces femmes et ces hommes de l’Orient sont souvent l’incarnation de l’Autre, un inférieur inassimilable à la civilisation qui est la sienne, mais Belgiojoso n’est pas imperméable aux moments d’une possible identification à cet Autre et à la reconnaissance de soi et des siens dans certaines de ses manifestations.
Vivre et écrire à la frontière : Isabelle Eberhardt, entre Orient et Occident, entre masculin et féminin
Authors: Bouvet Rachel , Charbonneau Chloé
Published: December 2024

Isabelle Eberhardt a incarné son statut de transfuge en Algérie de façon ambiguë. Elle revendique une posture intellectuelle nomade dont l’ambivalence identitaire manifeste et volontaire est le reflet. Le regard qu’elle porte sur ses consœurs algériennes et européennes, échappe aux normes de son époque et à l’horizon d’attente actuel qui voudrait en faire une figure féministe. D’une part, elle méprise la féminité occidentale étriquée et mondaine, et de l’autre, son costume masculin la prive d’un accès aux milieux féminins en Algérie, rendant leur présence moindre dans le paysage social qu’elle décrit. Néanmoins, les portraits de figures féminines marginales sont légion dans ses écrits et une finesse et une tendresse caractéristiques en émanent, malgré qu’ils ne soient pas toujours délivrés des clichés orientaux et de certains propos racistes et sexistes. Difficile donc de la considérer comme modèle d’émancipation féminine sans prendre en compte ces nuances. Notons cependant que certaines autrices du corpus algérien évoquent la figure d’Eberhardt dans le cadre d’une filiation intellectuelle nomade, relevant ainsi la part de complexité et d’opacité dans ses œuvres et sa pensée, ce qui fait parfois défaut, notamment dans les lectures biographiques qui ont souvent limité sa réception critique.
A comparative evaluation of physical characteristics, bioactive compounds, and
antioxidant capacity of Rhodomyrtus tomentosa berry by different drying
methods
Authors: Dingjin L. , Qiuxia D. , Yipeng G. , M. Nor Afizah , Zhenhua D. , Yingjian L. , Jiao D.
Published: December 2024

The Rhodomyrtus tomentosa berry (RTB) has attracted the attention of researchers for its
medicinal and nutritional characteristics. However, there is limited research on the
influence of different drying methods on RTB quality. The objective of this work was to
evaluate the effect of vacuum microwave drying (VMD), heat pump drying (HPD), and
sun drying (SD) on the quality characteristics, microstructure, and antioxidant capacity of
RTB. Results indicated that compared with HPD and SD, VMD enhanced the quality of
RTB and could complete the drying process in a shorter time (3.6 hrs). In addition, VMD
was able to retain a higher level of bioactive compounds and antioxidant capacity with an
improved rehydration ratio. The microscopic images showed that the VMD had an
obvious porous structure, facilitating the water evaporation. This suggested that VMD is
an efficient drying technology for producing high-quality dried products.
Analysis of Ophthalmology Drug Clinical Trial Institutions in China: Challenges and Opportunities Under the Registration System
Authors: Rui Xu  , Yurong Zhang  , Yongxia Zhao  , Li Wang
Published: December 2024

Objective: To analyze the status of ophthalmology drug clinical trial institutions in China following the implementation of the registration system and provide a reference for their development. Methods: An analysis was conducted using data from the Drug Clinical Trial Institution Registration Management Information Platform and the Drug Clinical Trial Registration and Information Publicity Platform of the National Medical Products Administration. The search period was up to April 19, 2024. Results: As of April 19, 2024, 314 ophthalmology-specific institutions were registered nationwide, comprising 274 comprehensive medical institutions and 40 specialized ophthalmology institutions, representing a 245% increase compared to the qualification certification phase. There were 965 major researchers in ophthalmology, accounting for 6.3% of the total number of researchers across all registered ophthalmology institutions. These institutions were predominantly located in economically developed areas such as Guangdong, Zhejiang, and Jiangsu Provinces, with the top five provinces and cities comprising 39.8% of the total registered institutions. Beijing had the highest number of major researchers (126), with their distribution positively correlated with the geographic spread of registered institutions. Furthermore, as of April 19, 2024, there were 216 clinical drugs related to eye diseases, with the top three provinces conducting 77.8% of national clinical trial projects. The number of institutions was directly proportional to the volume of clinical trials conducted. Conclusion: The implementation of the registration system has facilitated the release of ophthalmic medical resources. However, regional disparities remain in the number of ophthalmology-specific institutions, the availability of major investigators, and the distribution of clinical trial projects.
Konya ili tarım topraklarında mikroplastik kirlilik yükünün araştırılması
Authors: Aydın Senar , Ulvi Arzu , Bedük Fatma , Aydın Mehmet Emin
Published: December 2024

Mikroplastikler (MP) toprakta yeni bir tür toprak kirleticisidir. Bu çalışmada Konya İli ve yakın çevresinden rastgele seçilmiş olan 20 noktada, 0-20 cm derinlikten alınan toprak örneklerinde mikroplastik miktarı, renkleri ve morfolojileri tespit edilmiştir. Topraklarda mikroplastik kirliliğinin risk seviyesi, kirlilik faktörü (CF) ve kirlilik yük endeksi (PLI) değerleri ile belirlenmiştir. Çalışma sonucunda toprak örneklerinde 80-340 MP/kg arasında MP tespit edilmiştir. Numunelerde %45 fiber (1300 MP); %25 pellet (720 MP) tespit edilirken %51 oranla en fazla şeffaf renkli mikroplastiğe rastlanmıştır. Üç örnekleme noktasında CF değerinin önemli ekolojik risk (3 ≤ CF < 6) oluşturduğu, diğer numuneler için orta seviyede (1 ≤ CF < 3) ekolojik risk olduğu tespit edilmiştir. PLI değerine göre numunelerin tümü için düşük risk (PLI < 10) olduğu tespit edilmiştir. Toprak pH, EC ve organik madde muhtevası ile mikroplastik sayıları arasında anlamlı bir korelasyon tespit edilmezken, fosfor ile orta düzeyli (r=0.56), potasyum ile zayıf düzeyli (r=0.36) korelasyon tespit edilmiştir.
LEGAL NATURE AND TYPES OF CORPORATE SECURITIES OF FOREIGN ISSUERS
Authors:   Russian State University of the Humanities, Levushkin Anatoly N.
Published: December 2024

It is necessary to recognize that today investments are an integral part of developed market economies and are implemented within the
framework of investment legal relations. Especially relevant in the last decade
is the issue of investing in foreign financial instruments in the form of securities. Russian investors are seeking to diversify their portfolio, increasingly
preferring financial instruments of foreign issuers. The current legal regulation
allows purchasing the securities on global financial markets, but servicing outside the Russian legal framework entails serious risks for potential investors.
It should be noted that among the many varieties of securities, corporate
securities play a special role, they “complement” the purpose and essence of securities with another aspect – managerial, in other words, the acquisition, possession and sale of corporate securities, for example, shares, are a mechanism
for managing a legal entity as a corporate organization.
It should also be noted that corporate securities of foreign issuers play an
important role in the economic system, since their turnover acts as a means of
involving free funds of citizens and organizations in financial life, prevents
the “stagnation” of capital.
The presented article defines the legal nature and legal characteristics of
certain types of corporate securities of foreign issuers, and formulates the author’s conclusions and individual proposals for reforming Russian legislation
Организация менеджмента риска с учетом требований ГОСТ ISO/IEC 17025-2019 с применением ЛИМС
Authors: Константин Сергеевич Вараксин , Дарья Александровна Соколова , Дмитрий Владимирович Фалкин , Александр Юрьевич Ляпин
Published: December 2024

В соответствии с ГОСТ ISO/IEC 17025-2019 от испытательных лабораторий требуется обеспечить процесс идентификации, оценки и разработки мер по контролю рисков, а также расширению возможностей для достижения своих целей и задач. Стандарт требует от лабораторий планирования и реализации действий по управлению рисками. В статье рассматривается организация системы менеджмента в части управления рисками с применением лабораторной информационной менеджмент-системы (ЛИМС). Описана модель управления рисками с соблюдениями требований ГОСТ ISO/IEC 17025-2019, на основании разделов ГОСТ Р ИСО 31000-2019, ГОСТ Р 51901.22-2012, ГОСТ Р 51901.23-2012, ГОСТ Р ИСО 9000-2015. Показана имплементация модели в ежедневную деятельность лабораторий: от этапа идентификации риска, его анализа и сравнительной оценки, установления причин с применением диаграммы Исикавы, до процесса сопровождения: обработки, мониторинга и регулярного пересмотра риска. Применение указанного комбинированного подхода управления рисками на основе ГОСТ Р ИСО 31000-2019 позволило обеспечить полноценный и прозрачный процесс управления рисками в лабораториях в соответствии с положениями ГОСТ ISO/IEC 17025-2019, автоматизировать процедуры по работе с несоответствующими работами, подготовки отчетности, создать набор данных для применения машинного обучения.

In accordance with the State Standard GOST ISO/IEC 17025-2019, a testing laboratory is required to provide a process for identifying, assessing, and developing risk control activities, as well as expanding opportunities to achieve its goals and objectives. The Standard requires the laboratory to plan and implement risk management activities. The paper considers the organization of a management system in terms of risk management using a Laboratory Information Management System (LIMS). It describes a risk management model subject to the requirements of GOST ISO/IEC 17025-2019, based on the sections of GOST R ISO 31000-2019, GOST R 51901.22-2012, GOST R 51901.23-2012, GOST R ISO 9000-2015. We have shown the model implementation in the laboratory routine: from risk identification, analysis, and comparative assessment, establishing the root causes using the Ishikawa diagram until the supporting process: processing, monitoring, and regular risk reviews. The application of the above combined risk management approach based on GOST R ISO 31000-2019 can ensure a full-fledged and transparent risk management process in laboratories in accordance with the provisions of GOST ISO/IEC 17025-2019, to automate the procedures for dealing with non-conforming activities and drawing up reports, to create a dataset for the application of machine learning
Pest survey card on Fusarium oxysporum f. sp. albedinis
Authors:   European Food Safety Authority (EFSA), Novak Adrijana , Ivić Dario , Vloutoglou Irene , Culot Alicia , Carotti Laura , Mattion Giulia , Vos Sybren
Published: December 2024

Abstract
This document provides the conclusions of the pest survey card that was prepared in the context of the EFSA mandate on plant pest surveillance (M‐2020‐0114) at the request of the European Commission. The full pest survey card for Fusarium oxysporum f. sp. albedinis is published and available online in the EFSA Pest Survey Card gallery at the following link and will be updated whenever new information becomes available: https://efsa.europa.eu/plants/planthealth/monitoring/surveillance/fusarium-oxysporum-albedinis
THE NEED FOR REPRODUCTIVE HEALTH EDUCATION ABOUT MENARCHE IN PRIMARY SCHOOL STUDENTS IN MOJOKERTO CITY
Authors: Dewi Catur Prasastia lukita , Wahyuni Lutfi
Published: December 2024

The onset of menstruation will be a traumatic event for some children who do not prepare themselves in advance. School-aged children need information about the menstrual process and health during menstruation. Children will have difficulty facing their first menstruation if they have never known about it before. This shows that school age children need reproductive health education in facing menarche. However, in reality, many school-aged children still have relatively low knowledge of reproductive health. The aim of this research is to identify the need for reproductive education regarding menarche among elementary school students in Mojokerto City. This research method uses a descriptive analytical research design with a case sectional approach. Samples were taken based on purposive sampling. Data collection was carried out through interviews using a reproductive education needs questionnaire. From the research results, it was found that the high level of need for reproductive health education, especially information on menarche, was due to the absence of a curriculum in elementary schools that discussed this issue.