bluuebunny/crossref_metadata_2025 huggingface dataset:
Preparation and Photocatalytic Property of Ag Modified Titanium Dioxide Exposed High Energy Crystal Plane (001)
Authors: Zhang Li-Yuan , You Jia , Li Qian-Wen , Dong Zhi-Hong , Zhong Ya-Jie , Han Yan-Lin , You Yao-Hui
Published: January 2020

TiO2 exposed high energy crystal plane (001) was prepared by the sol-gel process using butyl titanate as the titanium source and hydrofluoric acid as the surface control agent. Ag-TiO2 was prepared by depositing Ag on the crystal plane of TiO2 (101) with a metal halide lamp. The surface morphology, interplanar spacing, crystal phase composition, ultraviolet absorption band, element composition, and valence state of the samples were characterized by using field emission scanning electron microscopy (FESEM), transmission electron microscope (TEM), X-ray diffraction (XRD), ultraviolet-visible absorption spectrum (UV-Vis-Abs), and X-ray photoelectron spectroscopy (XPS), respectively. The formation mechanism of high energy crystal plane (001) was discussed, and the photocatalytic activities were evaluated by following degradation of methyl orange. The results show that TiO2 exposed the (001) crystal plane with a ratio of 41.8%, and Ag can be uniformly deposited on the crystal plane of TiO2 (101) by means of metal halide lamp deposition. Under the same conditions, the degradation rate of methyl orange by deposited Ag-TiO2 reaches as much as 93.63% after 60 min using the metal halide lamp (300 W) as an illuminant, 81.89% by non-deposited samples and 75.20% by nano-TiO2, causing a certain blue shift in the light absorption band edge of TiO2. Ag-TiO2 has the best photocatalytic performance at a pH value of 2.
Fabrication of Coatings with Structural Color on a Wood Surface
Authors: Liu Yi , Hu Jing , Wu Zhihui
Published: January 2020

A facile method for the fabrication of colloidal photonic crystal coatings with tunable structural color on a wood surface was presented. The photonic crystal coatings were formed from monodisperse latex spheres composed of poly(styrene-methyl methacrylate-acrylic acid) (P(St-MMA-AA)). The latex spheres with a hard PSt core and elastomeric P(MMA-AA) shell were prepared using the emulsion polymerization method. The sessile drop method, a rapid single-step self-assembly method through simple evaporation of emulsion, was used to form three-dimensional colloidal crystals. Coatings with brilliant colors and uniform Bragg’s diffraction covering the entire visible region were fabricated by controlling the sphere size. This simple method provided new insight into the development of wood color embellishment.
Using Annealing Treatment on Fabrication Ionic Liquid-Based PVDF Films
Authors: Ting Yung , Suprapto  , Bunekar Naveen , Sivasankar Kulandaivel , Aldori Yopan Rahmad
Published: January 2020

In this study, a simple method to obtain pure β-phase directly from the melt process is proposed. A series of PVDF and ionic liquid (IL) was prepared by a solvent casting method with appropriate associated with the subsequent annealing treatment. IL plays a role of filler, which can create strong electrostatic interaction with PVDF matrix and directly induce β-phase crystallization on the PVDF during the melt. PVDF film sample is immersed in hot water for annealing treatment at different temperatures (25 °C to 70 °C). We found that annealing in high temperatures especially can not only increase more IL inserted into the amorphous region of polymer matrix to make more phase transformation, but also accelerate IL removal. Characteristics and performance of the PVDF films were investigated by use of FTIR, XRD, SEM, and AFM. Piezoelectric coefficient d33 as well as d31, degree of crystallinity, and sensitivity are measured in experiment to verify the performance of PVDF film.
Potentiodynamic Polarization Performance of a Novel Composite Coating System of Al2O3/Chitosan-Sodium Alginate, Applied on an Aluminum AA6063 Alloy for Protection in a Chloride Ions Environment
Authors: Gallegos-Melgar A. , Serna Sergio A. , Lázaro I. , Gutiérrez-Castañeda E.-J. , Mercado-Lemus V. H. , Arcos-Gutierrez H. , Hernández-Hernández M. , Porcayo-Calderón J. , Mayen Jan , Monroy M. Del Angel
Published: January 2020

In this research work, a preliminary potentiodynamic polarization performance testing was carried out on a new environmentally friendly proposed composite coating. The proposed composite coating was developed by: (a) hot sulfuric anodizing to produce an Al2O3 conversion film followed by an (b) organic electrodeposited chitosan–sodium alginate blended film. Posteriorly, the conversion and organic films were microstructurally characterized by scanning electron microscopy. Finally, the polarization resistance technique was used to measure the corrosion resistance of the uncoated and coated AA6063 alloy in a simulated marine environment and the polarization tests were compared to samples immersed during 30 days in same electrolyte solution. The obtained inhibition corrosion efficiency of the proposed coating system was measured comparing the Rp of the uncoated alloy to the coated samples, showing an efficiency about 99% for a 3% NaCl electrolyte for some of the samples. Therefore, the experimental results obtained during this research demonstrates the feasibility of using the developed anticorrosive composite coating to protect aluminum alloys against chloride corrosive ions species and to further continue with the corresponding research.
Zooplankton Community Response to Seasonal Hypoxia: A Test of Three Hypotheses
Authors: Keister Julie E. , Winans Amanda K. , Herrmann BethElLee
Published: January 2020

Several hypotheses of how zooplankton communities respond to coastal hypoxia have been put forward in the literature over the past few decades. We explored three of those that are focused on how zooplankton composition or biomass is affected by seasonal hypoxia using data collected over two summers in Hood Canal, a seasonally-hypoxic sub-basin of Puget Sound, Washington. We conducted hydrographic profiles and zooplankton net tows at four stations, from a region in the south that annually experiences moderate hypoxia to a region in the north where oxygen remains above hypoxic levels. The specific hypotheses tested were that low oxygen leads to: (1) increased dominance of gelatinous relative to crustacean zooplankton, (2) increased dominance of cyclopoid copepods relative to calanoid copepods, and (3) overall decreased zooplankton abundance and biomass at hypoxic sites compared to where oxygen levels are high. Additionally, we examined whether the temporal stability of community structure was decreased by hypoxia. We found evidence of a shift toward more gelatinous zooplankton and lower total zooplankton abundance and biomass at hypoxic sites, but no clear increase in the dominance of cyclopoid relative to calanoid copepods. We also found the lowest variance in community structure at the most hypoxic site, in contrast to our prediction. Hypoxia can fundamentally alter marine ecosystems, but the impacts differ among systems.
Comparative Analysis of Seasonal Landsat 8 Images for Forest Aboveground Biomass Estimation in a Subtropical Forest
Authors: Li Chao , Li Mingyang , Liu Jie , Li Yingchang , Dai Qianshi
Published: January 2020

To effectively further research the regional carbon sink, it is important to estimate forest aboveground biomass (AGB). Based on optical images, the AGB can be estimated and mapped on a regional scale. The Landsat 8 Operational Land Imager (OLI) has, therefore, been widely used for regional scale AGB estimation; however, most studies have been based solely on peak season images without performance comparison of other seasons; this may ultimately affect the accuracy of AGB estimation. To explore the effects of utilizing various seasonal images for AGB estimation, we analyzed seasonal images collected using Landsat 8 OLI for a subtropical forest in northern Hunan, China. We then performed stepwise regression to estimate AGB of different forest types (coniferous forest, broadleaf forest, mixed forest and total vegetation). The model performances using seasonal images of different forest types were then compared. The results showed that textural information played an important role in AGB estimation of each forest type. Stratification based on forest types resulted in better AGB estimation model performances than those of total vegetation. The most accurate AGB estimations were achieved using the autumn (October) image, and the least accurate AGB estimations were achieved using the peak season (August) image. In addition, the uncertainties associated with the peak season image were largest in terms of AGB values < 25 Mg/ha and >75 Mg/ha, and the quality of the AGB map depicting the peak season was poorer than the maps depicting other seasons. This study suggests that the acquisition time of forest images can affect AGB estimations in subtropical forest. Therefore, future research should consider and incorporate seasonal time-series images to improve AGB estimation.
Moderate Diversity in Forest Structure and Its Low Dynamics Are Favored by Uneven-Aged Silviculture—The Lesson from Medium-Term Experiment
Authors: Szmyt Janusz , Barzdajn Władysław , Kowalkowski Wojciech , Korzeniewicz Robert
Published: January 2020

For several decades, there has been growing interest in highly diversified forests as a result of their management using the so-called uneven-aged silviculture. Such management and forests resulting from its application fulfil the purpose of forest ecosystem protection without significant limitation of the other forest functions and services. The usefulness of such silvicultural system depends largely on the species composition of the stand. In Poland, this system has been used primarily in silver fir (Abies alba Mill.)-dominated forests with an admixture of other shade-tolerant tree species and rather small admixture of light-demanding species. In our study, we analyzed the structure of fir-dominated uneven-aged forest consisting of a certain mix of eight tree species with different light-requirements, in which uneven-aged silviculture was performed for over two decades. The analysis of stand structure concerned three aspects of the forest structure: species diversity, spatial pattern of tree distribution, and tree size diversity. On the basis of three stand inventories, we captured the mid-term dynamics of the stand structure under moderate human pressure conditions. The results showed that the stand was characterized by high growing stock, with stable growth over the entire period. The silver fir was the dominant tree species, but the Scots pine and pedunculate oak also played an important role. However, the silver fir was abundant in the ingrowth class, whereas the pine and oak were absent or very rare in this stand strata. Noteworthy is the increasing importance of the European hornbeam, which is particularly evident in the ingrowth class; its abundance was twice that of the silver fir. The results clearly demonstrated that within 24 years, the share of light-demanding tree species in the forest clearly decreased, while that of shade-tolerant species clearly increased. Structural parameters showed a moderate tree-size diversity, despite the high species richness of the forest. This was mainly the result of selection cuttings, which clearly decreased tree-size variability after the second period of study. However, selection cuttings did not favor regeneration establishment, especially that of light-demanding tree species, whose role in the stand is assumed to be only minor in the future. The relatively high level of volume growth indicated that cutting intensity may be increased. More intense selection cuttings would also improve the stand structure by providing better light conditions for potential regeneration of different tree species, also light-adapted ones.
Parametric Identification of Nonlinear Fractional Hammerstein Models
Authors: Prasad Vineet , Kothari Kajal , Mehta Utkal
Published: January 2020

In this paper, a system identification method for continuous fractional-order Hammerstein models is proposed. A block structured nonlinear system constituting a static nonlinear block followed by a fractional-order linear dynamic system is considered. The fractional differential operator is represented through the generalized operational matrix of block pulse functions to reduce computational complexity. A special test signal is developed to isolate the identification of the nonlinear static function from that of the fractional-order linear dynamic system. The merit of the proposed technique is indicated by concurrent identification of the fractional order with linear system coefficients, algebraic representation of the immeasurable nonlinear static function output, and permitting use of non-iterative procedures for identification of the nonlinearity. The efficacy of the proposed method is exhibited through simulation at various signal-to-noise ratios.
Consensify: A Method for Generating Pseudohaploid Genome Sequences from Palaeogenomic Datasets with Reduced Error Rates
Authors: Barlow Axel , Hartmann Stefanie , Gonzalez Javier , Hofreiter Michael , Paijmans Johanna L. A.
Published: January 2020

A standard practise in palaeogenome analysis is the conversion of mapped short read data into pseudohaploid sequences, frequently by selecting a single high-quality nucleotide at random from the stack of mapped reads. This controls for biases due to differential sequencing coverage, but it does not control for differential rates and types of sequencing error, which are frequently large and variable in datasets obtained from ancient samples. These errors have the potential to distort phylogenetic and population clustering analyses, and to mislead tests of admixture using D statistics. We introduce Consensify, a method for generating pseudohaploid sequences, which controls for biases resulting from differential sequencing coverage while greatly reducing error rates. The error correction is derived directly from the data itself, without the requirement for additional genomic resources or simplifying assumptions such as contemporaneous sampling. For phylogenetic and population clustering analysis, we find that Consensify is less affected by artefacts than methods based on single read sampling. For D statistics, Consensify is more resistant to false positives and appears to be less affected by biases resulting from different laboratory protocols than other frequently used methods. Although Consensify is developed with palaeogenomic data in mind, it is applicable for any low to medium coverage short read datasets. We predict that Consensify will be a useful tool for future studies of palaeogenomes.
Empirical Study on the Factors Affecting Individuals’ Switching Intention to Augmented/Virtual Reality Content Services Based on Push-Pull-Mooring Theory
Authors: Kim Sanghyun , Choi Moon Jong , Choi Jae Sung
Published: January 2020

New technologies are driving rapid change and innovation in the industrial structure. In this environment, individuals’ use of contents also changes remarkably. This study aims to empirically prove why individuals switch from traditional to augmented/virtual reality (AR/VR) content services. We propose a research model and hypotheses based on data collected from existing research and AR/VR users. To explain individuals’ switch, we include three constructs for the push effects (low usefulness, functional simplicity, and perceived inefficiency) and three constructs for the pull effects (interactivity, experienceability, and amplified enjoyment) in our proposed model based on the most valid push-pull-mooring. Furthermore, we propose personal innovativeness as a mooring effect on the relationships between push/pull effects and switching intention to AR/VR content services. The data (n = 465) from actual AR/VR users were collected and analyzed using structural equation modeling with AMOS 22.0. Results empirically prove that all push/pull constructs, with the exception of perceived inefficiency, have a significant impact on switching intention. Moreover, a mooring effect—personal innovativeness—strengthens all paths in the research model, except that between perceived inefficiency and switching intention. The findings of this study would provide theoretical and practical implications for understanding individuals’ perceptions regarding AR/VR content services.
Influence of Forest Disturbance on La Crosse Virus Risk in Southwestern Virginia
Authors: Hopkins M. Camille , Zink Steven D. , Paulson Sally L. , Hawley Dana M.
Published: January 2020

Forest disturbance effects on La Crosse virus (LACV) are currently unknown. We determined the abundance of three LACV accessory vectors (Aedes albopictus, Ae. canadensis, and Ae. vexans) and the primary amplifying host (Eastern chipmunk; Tamias striatus), and tested for LACV prevalence in both vectors and chipmunks, across a gradient of experimental forest disturbance treatments in southwest Virginia. Forest disturbance significantly affected the abundance of LACV accessory vectors, with a higher abundance on disturbed sites for Ae. canadensis and Ae. vexans. However, there was no significant disturbance effect on chipmunk abundance. Forest disturbance significantly affected LACV prevalence in mosquito vectors, with most (80%) detections on unlogged control sites, which past work showed harbor the highest abundance of the two most common LACV vectors (the primary vector Aedes triseriatus, and Ae. japonicus). Interestingly, LACV nucleic acid was only detected in Ae. japonicus and Culex pipiens/restuans, with no detections in the primary vector, Ae. triseriatus. In contrast to the vector results, antibodies were only found in chipmunks on logged sites, but this result was not statistically significant. Overall, our results suggest that human LACV risk should generally decline with logging, and reveal the potential importance of accessory vectors in LACV maintenance in Appalachian forests.
Comparing Parameter Estimation of Random Coefficient Autoregressive Model by Frequentist Method
Authors: Araveeporn Autcha
Published: January 2020

This paper compares the frequentist method that consisted of the least-squares method and the maximum likelihood method for estimating an unknown parameter on the Random Coefficient Autoregressive (RCA) model. The frequentist methods depend on the likelihood function that draws a conclusion from observed data by emphasizing the frequency or proportion of the data namely least squares and maximum likelihood methods. The method of least squares is often used to estimate the parameter of the frequentist method. The minimum of the sum of squared residuals is found by setting the gradient to zero. The maximum likelihood method carries out the observed data to estimate the parameter of a probability distribution by maximizing a likelihood function under the statistical model, while this estimator is obtained by a differential parameter of the likelihood function. The efficiency of two methods is considered by average mean square error for simulation data, and mean square error for actual data. For simulation data, the data are generated at only the first-order models of the RCA model. The results have shown that the least-squares method performs better than the maximum likelihood. The average mean square error of the least-squares method shows the minimum values in all cases that indicated their performance. Finally, these methods are applied to the actual data. The series of monthly averages of the Stock Exchange of Thailand (SET) index and daily volume of the exchange rate of Baht/Dollar are considered to estimate and forecast based on the RCA model. The result shows that the least-squares method outperforms the maximum likelihood method.
Synthesis of Bioactive Silver Nanoparticles by a Pseudomonas Strain Associated with the Antarctic Psychrophilic Protozoon Euplotes focardii
Authors: John Maria Sindhura , Nagoth Joseph Amruthraj , Ramasamy Kesava Priyan , Mancini Alessio , Giuli Gabriele , Natalello Antonino , Ballarini Patrizia , Miceli Cristina , Pucciarelli Sandra
Published: January 2020

The synthesis of silver nanoparticles (AgNPs) by microorganisms recently gained a greater interest due to its potential to produce them in various sizes and morphologies. In this study, for AgNP biosynthesis, we used a new Pseudomonas strain isolated from a consortium associated with the Antarctic marine ciliate Euplotes focardii. After incubation of Pseudomonas cultures with 1 mM of AgNO3 at 22 °C, we obtained AgNPs within 24 h. Scanning electron (SEM) and transmission electron microscopy (TEM) revealed spherical polydispersed AgNPs in the size range of 20–70 nm. The average size was approximately 50 nm. Energy dispersive X-ray spectroscopy (EDS) showed the presence of a high intensity absorption peak at 3 keV, a distinctive property of nanocrystalline silver products. Fourier transform infrared (FTIR) spectroscopy found the presence of a high amount of AgNP-stabilizing proteins and other secondary metabolites. X-ray diffraction (XRD) revealed a face-centred cubic (fcc) diffraction spectrum with a crystalline nature. A comparative study between the chemically synthesized and Pseudomonas AgNPs revealed a higher antibacterial activity of the latter against common nosocomial pathogen microorganisms, including Escherichia coli, Staphylococcus aureus and Candida albicans. This study reports an efficient, rapid synthesis of stable AgNPs by a new Pseudomonas strain with high antimicrobial activity.
Tumor Microenvironment
Authors: Arneth Borros
Published: January 2020

Background and Objectives: The tumor microenvironment has been widely implicated in tumorigenesis because it harbors tumor cells that interact with surrounding cells through the circulatory and lymphatic systems to influence the development and progression of cancer. In addition, nonmalignant cells in the tumor microenvironment play critical roles in all the stages of carcinogenesis by stimulating and facilitating uncontrolled cell proliferation. Aim: This study aims to explore the concept of the tumor microenvironment by conducting a critical review of previous studies on the topic. Materials and Methods: This review relies on evidence presented in previous studies related to the topic. The articles included in this review were obtained from different medical and health databases. Results and Discussion: The tumor microenvironment has received significant attention in the cancer literature, with a particular focus on its role in tumor development and progression. Previous studies have identified various components of the tumor microenvironment that influence malignant behavior and progression. In addition to malignant cells, adipocytes, fibroblasts, tumor vasculature, lymphocytes, dendritic cells, and cancer-associated fibroblasts are present in the tumor microenvironment. Each of these cell types has unique immunological capabilities that determine whether the tumor will survive and affect neighboring cells. Conclusion: The tumor microenvironment harbors cancer stem cells and other molecules that contribute to tumor development and progression. Consequently, targeting and manipulating the cells and factors in the tumor microenvironment during cancer treatment can help control malignancies and achieve positive health outcomes.
Dynamic Error Correction of Filament Thermocouples with Different Structures of Junction based on Inverse Filtering Method
Authors: Zhao Chenyang , Zhang Zhijie
Published: January 2020

Since filament thermocouple is limited by its junction structure and dynamic characteristics, the actual heat conduction process cannot be reproduced during the transient thermal shock. In order to solve this problem, we established a thermocouple dynamic calibration system with laser pulse as excitation source to transform the problem of the restoring excitation source acting on the surface temperature of thermocouple junction into the problem of solving the one-dimensional (1D) inverse heat conduction process, proposed a two-layer domain filtering kernel regularization method for double conductors of thermocouple, analyzed the factors causing unstable two-layer domain solution, and solved the regular solution of two-layer domain by the filtering kernel regularization strategy. By laser narrow pulse calibration experiment, we obtained experimental samples of filament thermocouples with two kinds of junction structures, butt-welded and ball-welded; established error estimation criterion; and obtained the optimal filtering kernel parameters by the proposed regularization strategy, respectively. The regular solutions solved for different thermocouples were very close to the exact solution under the optimal strategy, indicating that the proposed regularization method can effectively approach the actual surface temperature of the thermocouple junction.
Gold Nanowires/Fibrin Nanostructure as Microfluidics Platforms for Enhancing Stem Cell Differentiation: Bio-AFM Study
Authors: Hashemzadeh Hadi , Allahverdi Abdollah , Ghorbani Mohammad , Soleymani Hossein , Kocsis Ágnes , Fischer Michael Bernhard , Ertl Peter , Naderi-Manesh Hossein
Published: January 2020

Organ-on-a-chip technology has gained great interest in recent years given its ability to control the spatio-temporal microenvironments of cells and tissues precisely. While physical parameters of the respective niche such as microchannel network sizes, geometric features, flow rates, and shear forces, as well as oxygen tension and concentration gradients, have been optimized for stem cell cultures, little has been done to improve cell-matrix interactions in microphysiological systems. Specifically, detailed research on the effect of matrix elasticity and extracellular matrix (ECM) nanotopography on stem cell differentiation are still in its infancy, an aspect that is known to alter a stem cell’s fate. Although a wide range of hydrogels such as gelatin, collagen, fibrin, and others are available for stem cell chip cultivations, only a limited number of elasticities are generally employed. Matrix elasticity and the corresponding nanotopography are key factors that guide stem cell differentiation. Given this, we investigated the addition of gold nanowires into hydrogels to create a tunable biointerface that could be readily integrated into any organ-on-a-chip and cell chip system. In the presented work, we investigated the matrix elasticity (Young’s modulus, stiffness, adhesive force, and roughness) and nanotopography of gold nanowire loaded onto fibrin hydrogels using the bio-AFM (atomic force microscopy) method. Additionally, we investigated the capacity of human amniotic mesenchymal stem cells (hAMSCs) to differentiate into osteo- and chondrogenic lineages. Our results demonstrated that nanogold structured-hydrogels promoted differentiation of hAMSCs as shown by a significant increase in Collagen I and II production. Additionally, there was enhanced calcium mineralization activity and proteoglycans formation after a cultivation period of two weeks within microfluidic devices.
Recent Progress of Miniature MEMS Pressure Sensors
Authors: Song Peishuai , Ma Zhe , Ma Jing , Yang Liangliang , Wei Jiangtao , Zhao Yongmei , Zhang Mingliang , Yang Fuhua , Wang Xiaodong
Published: January 2020

Miniature Microelectromechanical Systems (MEMS) pressure sensors possess various merits, such as low power consumption, being lightweight, having a small volume, accurate measurement in a space-limited region, low cost, little influence on the objects being detected. Accurate blood pressure has been frequently required for medical diagnosis. Miniature pressure sensors could directly measure the blood pressure and fluctuation in blood vessels with an inner diameter from 200 to 1000 μm. Glaucoma is a group of eye diseases usually resulting from abnormal intraocular pressure. The implantable pressure sensor for real-time inspection would keep the disease from worsening; meanwhile, these small devices could alleviate the discomfort of patients. In addition to medical applications, miniature pressure sensors have also been used in the aerospace, industrial, and consumer electronics fields. To clearly illustrate the “miniature size”, this paper focuses on miniature pressure sensors with an overall size of less than 2 mm × 2 mm or a pressure sensitive diaphragm area of less than 1 mm × 1 mm. In this paper, firstly, the working principles of several types of pressure sensors are briefly introduced. Secondly, the miniaturization with the development of the semiconductor processing technology is discussed. Thirdly, the sizes, performances, manufacturing processes, structures, and materials of small pressure sensors used in the different fields are explained in detail, especially in the medical field. Fourthly, problems encountered in the miniaturization of miniature pressure sensors are analyzed and possible solutions proposed. Finally, the probable development directions of miniature pressure sensors in the future are discussed.
Raman Spectroscopy and Single-Crystal High-Temperature Investigations of Bentorite, Ca6Cr2(SO4)3(OH)12·26H2O
Authors: Juroszek Rafał , Krüger Biljana , Galuskina Irina , Krüger Hannes , Tribus Martina , Kürsten Christian
Published: January 2020

The crystal structure of bentorite, ideally Ca6Cr2(SO4)3(OH)12·26H2O, a Cr3+ analogue of ettringite, is for the first time investigated using X-ray single crystal diffraction. Bentorite crystals of suitable quality were found in the Arad Stone Quarry within the pyrometamorphic rock of the Hatrurim Complex (Mottled Zone). The preliminary semi-quantitative data on the bentorite composition obtained by SEM-EDS show that the average Cr/(Cr + Al) ratio of this sample is >0.8. Bentorite crystallizes in space group P31c, with a = b = 11.1927(5) Å, c =21.7121(10) Å, V = 2355.60(18) Å3, and Z = 2. The crystal structure is refined, including the hydrogen atom positions, to an agreement index R1 = 3.88%. The bentorite crystal chemical formula is Ca6(Cr1.613Al0.387)Σ2[(SO4)2.750(CO3)0.499]Σ3.249(OH)11.502·~25.75H2O. The Raman spectra of bentorite from two different localities exhibit the presence of the main stretching and bending vibrations related to the sulfate group at 983 cm−1 (ν1), 1109 cm−1 (ν3), 442 cm−1 (ν2), and 601 cm−1 (ν4). Moreover, the presence of bands assigned to the symmetric Cr(OH)63− stretching mode and hydroxyl deformation vibrations of Cr–OH units at ~540 cm−1 and ~757 cm−1, respectively, may be used to distinguish between ettringite and bentorite. In situ high temperature single crystal XRD experiments show that the decomposition of bentorite starts at ca. 45 °C and that a dehydroxylation product similar to metaettringite is formed.
Enhanced Mechanical and Thermal Properties of Stereolithography 3D Printed Structures by the Effects of Incorporated Controllably Annealed Anatase TiO2 Nanoparticles
Authors: Mubarak Suhail , Dhamodharan Duraisami , Divakaran Nidhin , Kale Manoj B. , Senthil T. , Wu Lixin , Wang Jianlei
Published: January 2020

Fabrication of low-cost, durable and efficient metal oxide nanocomposites were successfully synthesized and reinforced with photo-resin via 3-dimensional printing. Here, we put forward a novel approach to enhance the mechanical and thermal behaviors of stereolithography (SLA) 3D printed architecture by adding TiO2 nanoparticles (TNPs) in different crystalline phases (anatase and rutile), which were obtained at different annealing temperatures from 400 °C to 1000°C. The heat-treated anatase TNPs were scrutinized by X-ray diffraction(XRD), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, diffusive reflectance spectroscopy (DRS), and transmission electron microscopy (TEM) analysis. Among all the samples, at 800 °C, annealed anatase TNPs exposed a highly crystalline anatase phase, having a low energy bandgap and a comparably high tensile strength (47.43 MPa) and high elastic modulus (2.261 GPa) for the 3D printed samples, showing improvement by 103% and 32%, respectively, compared with the printed pristine stereolithography resin (SLR) sample. Moreover, enhanced storage modulus and tan δ values were achieved via the better interfacial interactions between the incorporated nanofillers and the SLR matrix. In addition to this, enhanced thermal conductivity and thermal stability of the SLR matrix were also noted. The low energy bandgap and nanoscale size of the fillers helped to achieve good dispersion and allowed the UV light to penetrate at a maximum depth through the photo resin.
Hybrid ZnO Electron Transport Layer by Down Conversion Complexes for Dual Improvements of Photovoltaic and Stable Performances in Polymer Solar Cells
Authors: Bu Fanchen , Shen Wenfei , Zhang Xiaolin , Wang Yao , Belfiore Laurence A. , Tang Jianguo
Published: January 2020

Polymer solar cells (PSCs) have shown excellent photovoltaic performance, however, extending the spectral response range to the ultraviolet (UV) region and enhancing the UV light stability remain two challenges to overcome in the development of PSCs. Lanthanide down-conversion materials can absorb the UV light and re-emit it at the visible region that matches well with the absorption of the active layer material PTB7-Th (poly[[2,6′-4,8-di(5-ethylhexylthienyl)benzo[1,2-b;3,3-b]dithiophene][3-fluoro-2[(2-ethylhexyl)carbony]thieno[3,4-b]thiophenediyl]]) and PBDB-T-2F, thus helping to enhance the photovoltaic performance and UV light stability of PSCs. In this research, a down-conversion material Eu(TTA)3phen (ETP) is introduced into the cathode transport layer (ZnO) in PSCs to manipulate its nanostructure morphology for its application in hyperfine structure of PSCs. The device based on the ZnO/ETP electron transport layer can obtain power conversion efficiencies (PCEs) of 9.22% (PTB7-Th–PC71BM ([6,6]-phenylC71-butyric acid methyl ester) device) and 13.12% (PBDB-T-2F–IT-4F device), respectively. Besides, in the research on PTB7-Th-PC71BM device, the stability of the device based on ZnO/ETP layer is prolonged by 70% compared with the ZnO device. The results suggest that the ZnO/ETP layer plays the role of enhanced photovoltaic performance and prolonged device stability, as well as reducing photo-loss and UV degradation for PSCs.
Emphasizing the Operational Role of a Novel Graphene-Based Ink into High Performance Ternary Organic Solar Cells
Authors: Stylianakis Minas M. , Kosmidis Dimitrios M. , Anagnostou Katerina , Polyzoidis Christos , Krassas Miron , Kenanakis George , Viskadouros George , Kornilios Nikolaos , Petridis Konstantinos , Kymakis Emmanuel
Published: January 2020

A novel solution-processed, graphene-based material was synthesized by treating graphene oxide (GO) with 2,5,7-trinitro-9-oxo-fluorenone-4-carboxylic acid (TNF-COOH) moieties, via simple synthetic routes. The yielded molecule N-[(carbamoyl-GO)ethyl]-N′-[(carbamoyl)-(2,5,7-trinitro-9-oxo-fluorene)] (GO-TNF) was thoroughly characterized and it was shown that it presents favorable highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energy levels to function as a bridge component between the polymeric donor poly({4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl}{3-fluoro-2-[(2-ethylhexyl)carbonyl] thieno[3,4-b]thiophenediyl}) (PTB7) and the fullerene derivative acceptor [6,6]-phenyl-C71-butyric-acid-methylester (PC71BM). In this context, a GO-TNF based ink was prepared and directly incorporated within the binary photoactive layer, in different volume ratios (1%–3% ratio to the blend) for the effective realization of inverted ternary organic solar cells (OSCs) of the structure ITO/PFN/PTB7:GO-TNF:PC71BM/MoO3/Al. The addition of 2% v/v GO-TNF ink led to a champion power conversion efficiency (PCE) of 8.71% that was enhanced by ~13% as compared to the reference cell.
Calculations of Some Doping Nanostructurations and Patterns Improving the Functionality of High-Temperature Superconductors for Bolometer Device Applications
Authors: Verde Jose C. , Viz Alberto S. , Botana Martín M. , Montero-Orille Carlos , Ramallo Manuel V.
Published: January 2020

We calculate the effects of doping nanostructuration and the patterning of thin films of high-temperature superconductors (HTS) with the aim of optimizing their functionality as sensing materials for resistive transition-edge bolometer devices (TES). We focus, in particular, on spatial variations of the carrier doping into the CuO 2 layers due to oxygen off-stoichiometry, (that induce, in turn, critical temperature variations) and explore following two major cases of such structurations: First, the random nanoscale disorder intrinsically associated to doping levels that do not maximize the superconducting critical temperature; our studies suggest that this first simple structuration already improves some of the bolometric operational parameters with respect to the conventional, nonstructured HTS materials used until now. Secondly, we consider the imposition of regular arrangements of zones with different nominal doping levels (patterning); we find that such regular patterns may improve the bolometer performance even further. We find one design that improves, with respect to nonstructured HTS materials, both the saturation power and the operating temperature width by more than one order of magnitude. It also almost doubles the response of the sensor to radiation.
Eating Competence Is Associated with Lower Prevalence of Obesity and Better Insulin Sensitivity in Finnish Adults with Increased Risk for Type 2 Diabetes: The StopDia Study
Authors: Tilles-Tirkkonen Tanja , Aittola Kirsikka , Männikkö Reija , Absetz Pilvikki , Kolehmainen Marjukka , Schwab Ursula , Lindström Jaana , Lakka Timo , Pihlajamäki Jussi , Karhunen Leila
Published: January 2020

A healthy diet prevents type 2 diabetes but is often difficult to adhere to. This cross-sectional study aimed to investigate whether eating competence is associated with diet or risk factors and prevalence of type 2 diabetes in individuals screened for type 2 diabetes risk. Eating competence is an indicator of food acceptance, positive attitudes, internal regulation and contextual skills related to food and eating. In total, 3147 Finnish adults aged 18–74 at an increased risk for type 2 diabetes identified via online risk screening participated in the baseline examinations of the Stop Diabetes (StopDia) study. The participants filled out the digital questionnaire on food intake, physical activity and sleep, and the Satter Eating Competence Inventory 2.0TM (ecSI 2.0TM). In addition, anthropometric and laboratory measurements were performed at primary healthcare centres. Eating competent individuals (37%, classified by ecSI 2.0TM) had a better quality of diet (p < 0.05 for all). Additionally, eating competence was associated with a lower prevalence of previously undiagnosed type 2 diabetes, abdominal obesity, metabolic syndrome and hypertriglyceridaemia, and with better insulin sensitivity (p < 0.05 for all). However, these associations, except for metabolic syndrome, were at least partly mediated by body mass index. Eating competence is associated with a healthy diet and could, thus, in the long term, support the prevention of type 2 diabetes.
Subclinical Mastitis in a European Multicenter Cohort: Prevalence, Impact on Human Milk (HM) Composition, and Association with Infant HM Intake and Growth
Authors: Samuel Tinu Mary , De Castro Carlos Antonio , Dubascoux Stephane , Affolter Michael , Giuffrida Francesca , Billeaud Claude , Picaud Jean-Charles , Agosti Massimo , Al-Jashi Isam , Pereira Almerinda Barroso , Costeira Maria Jose , Silva Maria Gorett , Marchini Giovanna , Rakza Thameur , Haaland Kirsti , Stiris Tom , Stoicescu Silvia-Maria , Martínez-Costa Cecilia , Vanpee Mireilla , Domellöf Magnus , Castañeda-Gutiérrez Eurídice , Thakkar Sagar Kiran , Silva-Zolezzi Irma
Published: January 2020

Background: Subclinical mastitis (SCM) is an inflammatory condition of the mammary gland. We examined the effects of SCM on human milk (HM) composition, infant growth, and HM intake in a mother–infant cohort from seven European countries. Methods: HM samples were obtained from 305 mothers at 2, 17, 30, 60, 90, and 120 days postpartum. SCM status was assessed using HM Sodium (Na): Potassium (K) ratio >0.6. Levels of different macro- and micronutrients were analyzed in HM. Results: SCM prevalence in the first month of lactation was 35.4%. Mean gestational age at delivery was lower and birth by C-section higher in SCM mothers (p ≤ 0.001). HM concentrations of lactose, DHA, linolenic acid, calcium, and phosphorous (p < 0.05 for all) was lower, while total protein, alpha-lactalbumin, lactoferrin, albumin, arachidonic acid to DHA ratio, n-6 to n-3 ratio and minerals (iron, selenium, manganese, zinc, and copper) were higher (p < 0.001 for all) in mothers with SCM. There were no differences in infant growth and HM intake between non-SCM and SCM groups. Conclusion: We document, for the first time, in a large European standardized and longitudinal study, a high prevalence of SCM in early lactation and demonstrate that SCM is associated with significant changes in the macro- and micronutrient composition of HM. Future studies exploring the relation of SCM with breastfeeding behaviors and developmental outcomes are warranted.
Validity of Absolute Intake and Nutrient Density of Protein, Potassium, and Sodium Assessed by Various Dietary Assessment Methods: An Exploratory Study
Authors: Trijsburg Laura , Geelen Anouk , Hulshof Paul J.M. , van’t Veer Pieter , Boshuizen Hendriek C. , Hollman Peter C.H. , van Dijk Gertjan , Feskens Edith J.M. , de Vries Jeanne H.M.
Published: January 2020

It is suggested that nutrient densities are less affected by measurement errors than absolute intake estimates of dietary exposure. We compared the validity of absolute intakes and densities of protein (kJ from protein/total energy (kJ)), potassium, and sodium (potassium or sodium (in mg)/total energy (kJ)) assessed by different dietary assessment methods. For 69 Dutch subjects, two duplicate portions (DPs), five to fifteen 24-h dietary recalls (24 hRs, telephone-based and web-based) and two food frequency questionnaires (FFQs) were collected and compared to duplicate urinary biomarkers and one or two doubly labelled water measurements. Multivariate measurement error models were used to estimate validity coefficients (VCs) and attenuation factors (AFs). This research showed that group bias diminished for protein and sodium densities assessed by all methods as compared to the respective absolute intakes, but not for those of potassium. However, the VCs and AFs for the nutrient densities did not improve compared to absolute intakes for all four methods; except for the AF of sodium density (0.71) or the FFQ which was better than that of the absolute sodium intake (0.51). Thus, using nutrient densities rather than absolute intakes does not necessarily improve the performance of the DP, FFQ, or 24 hR.
Plasma Oxidative Status in Preterm Infants Receiving LCPUFA Supplementation: A Pilot Study
Authors: Ramiro-Cortijo David , López de Pablo Ángel Luis , López-Giménez Mᵃ Rosario , Martin Camilia R. , Brown Joanne , Saenz de Pipaón Miguel , Arribas Silvia M.
Published: January 2020

After birth, preterm infants are deficient in arachidonic acid (ARA), docosahexaenoic acid (DHA), and antioxidants, increasing their risk of oxidative stress-related pathologies. The principal aim was to evaluate if supplementation with long-chain polyunsaturated fatty acids (LCPUFAs) improves antioxidant defenses. In total, 21 preterm infants were supplemented with ARA and DHA in a 2:1 ratio (ARA:DHA-S) or with medium-chain triglycerides (MCT-S). Plasma n-3 and n-6 LCPUFAs were measured at birth, postnatal day 28, and 36 weeks of postmenstrual age (36 WPA) by gas chromatography–mass spectroscopy. Plasma antioxidants (glutathione (GSH), catalase, and thiols) and oxidative damage biomarkers (malondialdehyde (MDA), carbonyls) were analyzed at the same time points by spectrophotometry, and scores of antioxidant status (Antiox-S) and oxidative damage (Proxy-S) were calculated. At 36 WPA, linoleic acid (LA) and dihomo-γ-linolenic acid (DGLA) were decreased in ARA:DHA-S compared to the MCT-S group (LA: ARA:DHA-S = 18.54 ± 1.68, MCT-S = 22.80 ± 1.41; p = 0.018; DGLA: ARA:DHA-S = 1.68 ± 0.38, MCT-S = 2.32 ± 0.58; p = 0.018). Furthermore, α-linolenic acid (ALA) was increased in ARA:DHA-S (ARA:DHA-S = 0.52 ± 0.33, MCT-S = 0.22 ± 0.10; p = 0.018). Additionally, LA:DHA ratio was decreased in the ARA:DHA-S compared to control group (ARA:DHA-S = 6.26 ± 2.35, MCT-S = 8.21 ± 2.65; p = 0.045). By the end of supplementation (36 WPA), catalase, thiol groups, and Antiox-S were significantly higher in neonates receiving ARA:DHA-S compared to those receiving MCT-S, with no differences in oxidative stress biomarkers. In conclusion, ARA:DHA supplementation in preterm neonates resulted in an overall improvement in antioxidant to oxidant balance and a decrease in early fatty acid precursors of the n-6 relative to the n-3 pathway. These effects may reduce oxidative stress and inflammation.
Effects of Caffeine and Coffee on Human Functioning
Authors: Del Coso Juan , Salinero Juan José , Lara Beatriz
Published: January 2020

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Health-Promoting Properties of Proanthocyanidins for Intestinal Dysfunction
Authors: González-Quilen Carlos , Rodríguez-Gallego Esther , Beltrán-Debón Raúl , Pinent Montserrat , Ardévol Anna , Blay M Teresa , Terra Ximena
Published: January 2020

The intestinal barrier is constantly exposed to potentially harmful environmental factors, including food components and bacterial endotoxins. When intestinal barrier function and immune homeostasis are compromised (intestinal dysfunction), inflammatory conditions may develop and impact overall health. Evidence from experimental animal and cell culture studies suggests that exposure of intestinal mucosa to proanthocyanidin (PAC)-rich plant products, such as grape seeds, may contribute to maintaining the barrier function and to ameliorating the pathological inflammation present in diet-induced obesity and inflammatory bowel disease. In this review, we aim to update the current knowledge on the bioactivity of PACs in experimental models of intestinal dysfunction and in humans, and to provide insights into the underlying biochemical and molecular mechanisms.
Efficacy of Isomaltulose Compared to Sucrose in Modulating Endothelial Function in Overweight Adults
Authors: de Groot Eric , Schweitzer Lisa , Theis Stephan
Published: January 2020

Hyperglycemia is linked to impaired arterial endothelial function (EF), an early sign of cardiovascular disease. We compared the efficacy of low-glycemic index isomaltulose (Palatinose™) with that of sucrose in modulating EF, as assessed by flow-mediated dilation (FMD). In this double-blinded cross-over study, 80 overweight mildly hypertensive subjects were randomized to receive 50 g of either isomaltulose or sucrose. On two non-consecutive days, brachial artery ultrasound FMD scans were obtained prior to and hourly (T0–T3) after carbohydrate load. Blood was drawn immediately after scanning. Glucose and insulin levels were analyzed. Overall, the FMD decrease was attenuated by isomaltulose compared to sucrose (ΔFMD = −0.003% and −0.151%; p > 0.05 for the interaction treatment x period). At T2, FMD was significantly higher after isomaltulose administration compared to that after sucrose administration (FMD = 5.9 ± 2.9% and 5.4 ± 2.6%, p = 0.047). Pearson correlations between FMD and blood glucose showed a trend for a negative association at T0 and T2 independently of the carbohydrate (r-range = −0.20 to −0.23, p < 0.1). Sub-analysis suggested a lower FMD in insulin-resistant (IR) compared to insulin-sensitive subjects. Isomaltulose attenuated the postprandial decline of FMD, particularly in IR persons. These data support the potential of isomaltulose to preserve the endothelial function postprandially and consequently play a favorable role in cardiovascular health.