bluuebunny/crossref_metadata_2025 huggingface dataset:
How Intention to Use Mobile Payment in Indonesia Formed? The Role of Innovativeness, Usefulness, Risk, and User Stress
Authors: Indarini  , Permatasari Angelia Putri , Anandya Dudi
Published: April 2024

Purpose: This study aims to examine the effect of perceived satisfaction, perceived usefulness, perceived risk, and perceived trust variables on the intention to use mobile payment in Indonesia.
 
Method: This study is causal research that was tested empirically by using questionnaire data of 300 respondents who have used Gopay mobile payment (largest mobile payment in Indonesia) at least 3 times in the last 3 months. The analysis of this study used Structural Equation Modeling (SEM) with SPSS and AMOS software.
 
Results and Conclusion: The results show that innovativeness and perceived ease of use has a positive and significant effect on perceived usefulness, stress has a negative and significant effect on perceived usefulness, while perceived satisfaction, perceived usefulness, and perceived trust have a positive and significant effect on the intention to use mobile payment Gopay in Indonesia.
 
Originality/value: This study tries to close the gap between the research of Cabanilas et al. (2020) and Leiva et al. (2017) by replicating the model using the largest mobile payment in Indonesia. The study drew a large sample up to cover 15 provinces in Indonesia. University of Surabaya, Surabaya, Indonesia.
The Reconstruction of Religious Court Decision Execution on the Fulfilment of Children’s Rights Post-Divorce in Indonesia
Authors: Haris Ahmad , Lisdiyono Edy , Setiyowati
Published: April 2024

Purpose: The aim of this study is to examine the reconstruction of Religious Court decision execution on the fulfilment of children’s rights post-divorce in Indonesia.
 
Theoretical Framework: This research is based on the postulate that court decisions ideally aimed to guarantee justice and legal certainty for the parties, but in reality, not all judge’s decisions can be implemented as well. This can be seen in the implementation of religious court decisions in Indonesia regarding children's maintenance rights post-divorce.
 
Design/Methodology/Approach: This research uses a juridical-normative method. The sources and techniques of data collection were obtained from documentation studies, literature, and interviews with informants. The data analysis technique uses a deductive approach to formulate a conclusion.
 
Findings: The results of this research show that on the one hand, the regulation of the father's obligations towards child support post-divorce in the judge's decision at the Religious Courts refers more to the positive laws that implemented in Indonesia. On the other hand, positive law in Indonesia has not yet effective in regulating the execution of judges' decisions regarding the children's rights post-divorce because it is only voluntary and lacks coercive power.
 
Research, Practical & Social Implications: As the implication of the research, family law in Indonesia needs to be reconstructed through conducting special regulations regarding the execution mechanism regarding the fulfillment of children's rights post-divorce to be more regulatory, binding, and coercive.
 
Originality/Value: The value of the research originality became an explanatory method for the conceptual development of the reconstruction of Religious Court decision execution on the fulfilment of children’s rights post-divorce in Indonesia.
PENGARUH EFISIENSI MODAL INTELEKTUAL TERHADAP KINERJA PERUSAHAAN DENGAN UKURAN PERUSAHAAN SEBAGAI MODERASI
Authors: Krisyadi Robby , Hendi Hendi , Chairika Saltycia
Published: April 2024

This study aims to investigate the impact of intellectual capital on the performance of companies listed on the Indonesia Stock Exchange with the moderation of company size. The research focuses on the use of quantitative data, including the annual reports of companies listed on the IDX from 2018 to 2022. The sample was collected using purposive sampling method, comprising a total of 166 company samples. The analytical methods employed include classic assumption testing, multiple linear regression analysis, and hypothesis testing using the F-test (for overall influence) and the t-test (for partial influence) at a significance level of 0.05. The results of this study reveal an insignificant relationship between intellectual capital (MVAIC) and company performance (ROA) as well as company size gives insignificant to the relationship. This finding provides valuable insights for stakeholders in the Indonesian stock market and companies listed on the Indonesia Stock Exchange in managing their intellectual capital.
FAKTOR-FAKTOR YANG MEMPENGARUHI NIAT PERILAKU PEMBAYARAN DIGITAL DIMEDIASI SIKAP TERHADAP PENGGUNAAN DI KOTA BATAM
Authors: Juniarty Shely , Zai Immanuel
Published: April 2024

Penelitian ini bertujuan untuk menguji persepsi kemudahan penggunaan, persepsi kegunaan, persepsi risiko terhadap niat perilaku yang dimediasi oleh variabel sikap terhadap penggunaan. Teknik pengambilan sample dengan metode purposive sampling, kuesioner yang disebarkan sebanyak 270 responden. Pengolahan data yang dilakukan menggunakan aplikasi SmartPLS. Hasil penelitian membuktikan bahwa persepsi kemudahan penggunaan dan persepsi kegunaan berpengaruh signfikan terhadap variabel sikap terhadap penggunaan, namun, persepsi risiko tidak berpengaruh signifikan terhadap variabel sikap terhadap penggunaan. Kemudian sikap terhadap penggunaan mampu memediasi hubungan antara persepsi kemudahan kegunan, persepsi kegunaan terhadap niat perilaku, namun,  sikap terhadap penggunaan tidak mampu memediasi hubungan antara persepsi risko terhadap niat perilaku.
HUBUNGAN EKSPOR, IMPOR, INFLASI, DAN JUMLAH UANG BEREDAR TERHADAP PERTUMBUHAN EKONOMI INDONESIA DENGAN NILAI TUKAR SEBAGAI MEDIASI
Authors: Budiman Johny , Arifin Supriyadi
Published: April 2024

The economic level of a country can be identified by looking at its economic growth. Economic growth in each period will not be consistent all the time, but will experience periodic fluctuations.The aim of this research is to examine the connection between exports, imports, inflation, the amount of money in circulation and economic growth through the exchange rate in Indonesia. This research uses multiple linear regression analysis methods with secondary data. The data used consists of information regarding exports, imports, inflation, money supply, exchange rates and Indonesia's economic growth. In terms of data collection time, this type of data study uses time series data collected from the years 2018-2022 with SPSS 21. Based on the results of research that has been carried out, direct influence shows that exports & imports do not have a significant effect on economic growth, while inflation & money supply has a significant positive effect on economic growth. Apart from that, the indirect effect shows that exports through the exchange rate have a positive and insignificant effect on economic growth, money supply through the exchange rate has a positive and significant effect on economic growth, while imports & inflation through the exchange rate have no significant effect on economic growth.
Distorção idade-série
Authors: Mussato Solange , Voltolini Luzia , Da Motta Salles Barreto Mônica
Published: April 2024

This article, which has the theme of age-grade distortion, presents the results of a documentary research and a qualitative approach, with the aim of analyzing the age-grade distortion rates of students in the final years of elementary school in the state network of Roraima and the actions implemented by the Department of Education and Sports (SEED) to meet this demand. The collection of data on school flow indicators was carried out in documents published by INEP and QEdu, with an analysis of the historical series of the School Census of the years 2017, 2018 and 2019 and information on the actions implemented by SEED, to assist students that make up this group, were obtained from publications on the official websites linked to that body. Results show that, although the age-grade distortion indicator shows a reduction, it is still present in both urban and rural state schools in the 15 municipalities of Roraima. Notwithstanding, the collection of data on the actions implemented by SEED has been limited to electronic media disclosures, it was found that actions are developed to reduce dropout, repetition and dropping out of school, such as the active search of students, the realization workshops and training courses for teachers working in flow correction classes.
Adulteração, conformidades de envasamento e rotulagem de méis vendidos nas feiras-livres da cidade de Boa Vista, Roraima, Brasil
Authors: Alves Fabíola Cristina Gibson , Silva Silvio , Cabral Gardênia Holanda
Published: April 2024

O mel contém açúcares em alta concentração provenientes do néctar das flores, de nectários extraflorais ou de exsudados de inseto. No entanto, o mel pode apresentar adulterações variadas relacionados à adição de ingredientes de baixo valor comercial. Este trabalho teve como objetivo verificar possíveis adulterações em amostras de mel comercializadas em feiras livres na cidade de Boa Vista, estado de Roraima, por meio da análise polínica, sensorial e pela precipitação de proteínas na reação de Lund. Também foram avaliados o acondicionamento e a rotulagem. Foram adquiridas 31 amostras comerciais de mel de Apis mellifera em 06 feiras livres. Das amostras analisadas 20 (64,5%) apresentaram resultado negativo para reação de Lund, ou seja, consideradas adulteradas e 11 (35,5%) mostraram resultado positivo, não adulteradas. Onze amostras de mel não continham pólen. Seis amostras foram consideradas melato de Acacia mangium, sete como mel silvestre e duas como um mix de mel silvestre e melato de A. mangium,. Quanto a embalagem, três amostras estavam acondicionadas em frascos de vidro, as demais em garrafas plásticas, na maioria tipo PET. Somente 11 embalagens possuiam rótulo, mas nenhuma atendeu as exigências da legislação em vigor. Seis amostras rotuladas foram consideradas adulteradas. Com um elevado percentual de adulteração determinado pela reação de Lund. Um percentual tão alto de adulteração serve de alerta aos órgãos fiscalizadores para combate esse tipo de fraude.
Diagnóstico nas operações de adição e subtração num estudante com Síndrome de Downs do 3º ano do ensino fundamental
Authors: Loureiro Luciana Lyra , Sousa Clemildo Silva , Mendoza Héctor José García
Published: April 2024

A pesquisa tem como objetivo analisar o diagnóstico por meio da Atividade de Situações Problema Discente fundamentada na teoria Histórico – Cultural da atividade na perspectiva dos autores Galperin, Talízina e Majmutov na aprendizagem nas operações de adição e subtração num estudante com Síndrome de Down no 3° ano de Ensino Fundamental. A pesquisa tem enfoque qualitativa e a produção de informação é realizada através da observação e tarefas problematizadoras. Conclui-se que o nível a partida não é adequado e propõe-se uma sequência didática a fim desenvolver as habilidades do raciono lógico matemático dentro da zona de desenvolvimento proximal.
Padrões alométricos de indivíduos arbóreos em áreas públicas da cidade de Boa Vista, Roraima
Authors: Silva Williamar Rodrigues , Oliveira Rodrigo Leonardo Costa de , Barbosa Reinaldo Imbrózio
Published: April 2024

Esta errata se refere à seguinte publicação: Padrões alométricos de indivíduos arbóreos em áreas públicas da cidade de Boa Vista, Roraima. Boletim do Museu Integrado de Roraima (Online), Brasil, v. 15, n. 1, p. 20–28, 2023. DOI: 10.24979/bmirr.v15i1.981. Disponível em: https://periodicos.uerr.edu.br/index.php/bolmirr/article/view/981.. Acesso em: 26 mar. 2024.
O defeito está localizado na filiação dos autores e na definição das palavras-chave. Esta modificação não altera a interpretação dos resultados.
A equipe editorial lamenta o erro.
A arborização urbana consiste nos elementos vegetais arbóreos presentes na cidade e tem importância fundamental na qualidade de vida dos cidadãos. O estudo da área verde urbana tem por finalidade embasar um melhor planejamento de uma cidade buscando um equilíbrio ambiental para que futuramente minimize os efeitos causados pela urbanização. Entender os padrões alométricos que regem o crescimento das árvores inseridas em áreas públicas fazem parte do planejamento urbano moderno. O objetivo do estudo foi determinar os padrões alométricos de árvores situadas em áreas verdes públicas da cidade de Boa Vista, Roraima. O estudo foi realizado com base em indivíduos adultos que apresentaram diâmetro à altura do peito (DAP) maior ou igual à 10 cm, dispersos em três praças públicas e canteiros centrais de duas avenidas.No levantamento florístico houve maior frequência relativa das espécies Licania tomentosa com 45,10%, Handroanthus impetiginosus com 26,65% e Pachira aquatica com 7,51% dos indivíduos. As melhores relações alométricas tomando como base os locais de coleta foram entre diâmetro do caule e área da copa (R² = 0,63 ) e altura total e altura do fuste (R² = 0,50). Nossos resultados refletem padrões alométricos distintos entre as áreas públicas amostradas porque cada um dos locais é provido por cultivos de árvores de diferentes espécies, idades de plantio e formas de manejo, gerando modelos de crescimento discrepantes entre si. Nosso estudo é inédito e se configura com uma das bases discussões sobre a importância da arborização dentro dos conceitos de serviços ambientais providos por áreas verdes urbanas.
Semiología y no-saber
Authors: Bucher Gérard
Published: April 2024

Resumen
The beginning of ensuring the safety of water transport (based on the materials of acts of Ancient Russia)
Authors: Stashkov Ruslan Sabitovich
Published: April 2024

The relevance of the theme of the study is due to the fact that an objective study of the history of formation of legal norms governing the provision of transport safety on water in ancient Russia in the period from the IX – XII centuries, allows to understand the practical significance of this problem to improve the safety of people on water transport. To find out in which documents legal norms regulating safety on water first appeared. The purpose of research is carrying out of the complex analysis of occurrence of the legal norms regulating maintenance of transport safety on water in Ancient Russia, on the basis of objective studying of documentary, archival and scientific materials, using a principle of objectivity and historicism. Object of research are legal documents of Ancient Russia. Subject of research are the legal norms regulating maintenance of transport safety on water in Ancient Russia. When writing the article historical, ideographic, comparative-legal methods have been used. Scientific novelty of article consists in occurrence in Ancient Russia written normative documents containing the norms regulating questions of transport safety on water. For the first time in Russia the written legal document in the form of the international contract regulating various aspects of public relations of Ancient Russia and Byzantium in which the norm regulating transport safety on water objects contains. In addition, the collection of legal norms, Russkaya Pravda, enshrines in writing requirements that did not exist before concerning the need to observe safety on water transport.
Daily leisure activities of provincial townspeople of Kazan and Vyatka provinces at the turn of the XIX – early XX century: balls, masquerades, dance evenings
Authors: Shabalina Serafima Sergeevna
Published: April 2024

Everyday life is a problem that requires detailed study. It is in the way people's leisure activities were organized that the prerequisites for the formation of the worldview and worldview of the people are revealed. Women's daily life at the turn of the XIX – early XX century is worthy of a separate study, because during this period there is a rethinking of the gender issue, which allowed a woman to be on an equal footing with a man in a difficult period of national history. The purpose of the research is to study the leisure everyday life of provincial townspeople at the turn of the XIX – early XX century on the example of archival materials of the Kazan and Vyatka provinces. Leisure activities are often determined by how representatives of the upper classes spend their free time. They are the ones who lay the foundations of etiquette, fashion, rules of summing up, places to visit and much more. The following methods were used in the study: analysis of historical literature in the aspect of the problem under study; comparative method, which is an analysis of various sources from the point of view of their comprehensive consideration; selective method used for a more detailed study of the issue under consideration. Scope of the results: the research material can be used for a more in-depth study of women's everyday life, the study of the evolution of the gender issue, in the process of a comprehensive study of the history of the Kazan and Vyatka provinces, as well as the history of Russia as a whole. The daily life of the townspeople of the Kazan and Vyatka provinces is an issue that has not been fully studied, a lot of archival materials were out of the field of view of researchers. The author focuses on how girls occupied themselves at the turn of the century. It is noted that balls, dance evenings and masquerades were a favorite form of leisure. During these events, an unspoken hierarchy in society was established, deals were made, etc. Women had to carefully select their toilet when attending such events, which took place in various clubs. Clubs have become the center of public life not only in the capital, but also in provincial cities.
Markers of social status in Polish printers' signatures (1501-1545)
Authors: Basov Ivan Mikhailovich
Published: April 2024

The article raises the problem of status representation in the signatures of book printers of the Kingdom of Poland. First of all, the study concerns the identified features in the publications of I. Vietor and J. Haller; to a lesser extent - S. Giber, K. Hochfeder, F. Ungler and M. Scharfenberg. Although the publisher's signature form did not undergo significant changes during the 1st half of the 16th century, we find specific markers of social status among the listed printers. These markers are not characteristic of previous and subsequent Polish book publishers, but are characteristic, firstly, of a certain circle of printers outside the Kingdom of Poland, and secondly, of the social environment that existed at that time, in which certain epithets conveyed information about a person’s place in the hierarchy. The focus on the readership demand of intellectuals and connections with the University of Krakow were also reflected in the publishing signatures: printers classified their activities in the field of sciences and arts ("ars"), and also presented themselves in terms accepted in the scientific community ("egregius vir", "spectabilis vir dominus"). This part of the self-representation of entrepreneurs once again testifies to their involvement in the structure of European humanist printers, who, like their Polish colleagues, sought to declare in their signatures their connections with the scientific community and Renaissance culture. At the same time, the appearance of the epithets identified in the structure of the publisher's signature has not only a linguistic connection, but also a chronological one: the concepts under study disappear in the middle of the 16th century from Polish publications and is reduced to a minimum in publications of other European lands.
Non-political propaganda directions of the Stalingrad (Volgograd) regional branch of the All-Union Society "Znanie" (1948-1980)
Authors: Knyazeva Anna Sergeevna
Published: April 2024

The object of the study is the non-political propaganda of the Volgograd (Stalingrad) branch of the All-Union Society "Znanie" (Knowledge) during the Soviet period of the organization's existence (1948 - to the end of the 1980s). The subject of the study was such areas of work of the regional branch of the society "Knowledge" as propaganda in the field of education, pedagogy, disease control, healthy lifestyle. The source base for this study was archival documents of the Center for Documentation of the Modern History of the Volgograd region (CDNIVO), namely, minutes of meetings of the organizing committee of the regional branch, annual reports on the main activities of the regional branch, minutes of the work of various sections within the department, minutes of the meeting of the Presidium of the Board of the regional branch, minutes of meetings of the Plenum of the Board of the regional branch, lecture plans, etc. These documents are of particular value, since today they are the only sources that cover the work of the Volgograd branch of the All-Union Society "Znanie". The principles of historicism, subjectivism, and system analysis of regional archival sources of the Center for Documentation of the Modern History of the Volgograd Region were applied in the methodology of the work. The novelty lies in the fact that for the first time an analysis of the work of the regional office is being carried out, especially since the narrower and non-core areas of work of the Znanie society are affected. The results of the study allow us to conclude that the Volgograd regional branch of the Znanie Society has implemented quite important tasks in matters of education, disease prevention, organization of cultural leisure for city residents, for this the society used various methods of work: parent lectures, radio lectures, national universities, meeting evenings, printing articles in periodicals, etc. Attention to the sections of pedagogy and psychology, medical knowledge, literature and art increased. The audience coverage of the above sections also grew, thousands of residents of the city passively or actively participated in the life of these sections.
A method to design contact-separation triboelectric nanogenerators (CS-TENG) for efficient vibration energy harvesting
Authors: Khelifa Meriam , Iranzo Audrey
Published: April 2024

The necessity of self-powered electronic devices for sensing and communication (IoT) has led to the development of methods for energy harvesting. Triboelectric Nanogenerators (TENG) are promising for harvesting mechanical energy from the environment, in particular energy from vibrations. The optimization of the efficiency of energy transfer from vibration energy into electrical energy is a crucial problem. This paper deals with a contact-separation TENG (CS-TENG) devoted to vibration harvesting. Optimization was carried out taking into account all the parameters of the TENG connected to a load resistance. The moving electrode of the CS-TENG was supposed to be sinusoidal. After transformation into dimensionless parameters and variables intervening in the problem, it appeared that the electrical dynamics of the TENG are intrinsically determined by only two dimensionless parameters. Consequently, the optimization of efficiency can be conducted in a two-dimensional space. It is shown that the maximum efficiency of a TENG permanently connected to the load resistance cannot be greater than 25%. However, the efficiency can be increased to nearly 100%, provided that a switch is used in series with the load resistance which opens and closes in synchronization with the electrode motion. The optimization method presented could be extended to design TENG energy harvesters operating in other modes and for arbitrary vibrations.
Wprowadzenie do problematyki szpiegostwa we francuskim kodeksie karnym.
Authors: Mariański Michał
Published: April 2024

Przedmiotem analizy w ramach niniejszego artykułu są regulacje prawne zawarte we francuskim kodeksie karnym w zakresie odnoszącym się do przestępstwa szpiegostwa. W ramach niniejszego opracowania, które stanowi jedynie wstępny etap i impuls dla dalszych poszerzonych badań w tej materii, autor poza zagadnieniami dotyczącymi przestępstwa szpiegostwa, przedstawia również systematykę i specyfikę francuskiego kodeksu karnego, co w sposób znaczny wpływa na lepsze zrozumienie charakteru analizowanych regulacji. Waga prowadzenia badań porównawczych w tym zakresie wynika również z sytuacji geopolitycznej, jaka nastąpiła po rozpoczęciu w 2022 roku przez Federację Rosyjską inwazji na Ukrainę. Opis i charakterystyka regulacji prawnych w zakresie przestępstwa szpiegostwa w prawie francuskim, jako element badań nad szeroko rozumianym bezpieczeństwem państwa, może być ciekawym impulsem do refleksji nad stanem polskich regulacji w tej materii.
XXII Doroczna Konferencja Naukowa Stowarzyszenia Edukacji Administracji Publicznej pt.: Administracja wobec współczesnych zagrożeń, 14-16 czerwca 2023 r.
Authors: Śwital Paweł
Published: April 2024

W dniach 14-16 czerwca w Serocku, odbyła się zorganizowana wspólnie przez Wydział Prawa i Administracji Uniwersytetu Kardynała Stefana Wyszyńskiego w Warszawie XXII Doroczna Konferencja Naukowa Stowarzyszenia Edukacji Administracji Publicznej pt. Administracja wobec współczesnych zagrożeń. Celem konferencji była identyfikacja zagrożeń oraz ustalenie ich źródeł i specyfiki, co umożliwiło podjęcie dyskusji nad koniecznymi działaniami zapobiegającymi lub niwelującymi ich negatywne skutki społeczne, gospodarczo-ekonomiczne czy ekologiczne, zarówno na poziomie lokalnym, jak i centralnym. Aktywność administracji publicznej w sferze przeciwdziałania współczesnym zagrożeniom to jedno z podstawowych jej zadań.
Gwarancyjny charakter zasady kolegialności
Authors: Kościelniak-Marszał Miłosz
Published: April 2024

Wymiar sprawiedliwości w Rzeczypospolitej Polskiej sprawują Sąd Najwyższy, sądy powszechne, sądy administracyjne oraz sądy wojskowe. Swoje zadania orzecznicze sprawują poprzez sędziów orzekających w składach sądzących, kolegialnych lub jednoosobowych, tworzonych na podstawie właściwych norm prawnych. Na przestrzeni dziejów można zaobserwować przemienność w dominacji idei kolegialności orzekania oraz koncepcji jednoosobowego rozstrzygania. W Polsce od połowy lat 90-tych ubiegłego wieku wyraźna jest wizja profesjonalizacji orzecznictwa, która wpływa również na kwestię kolegialności składów. Zmiany w tym zakresie przyspieszyły zwłaszcza w związku z pandemią COVID-19, chociaż ustawodawca nie krył się w zasadzie z tym, że zagrożenie wirusem było raczej pretekstem, a nie przyczyną do wprowadzania zmian. Faktycznie bowiem chodziło o ułatwienie możliwości kontrolowania poszczególnych sędziów, aby zniechęcić ich do podejmowania prób sądowej weryfikacji prawidłowości nominacji osób powołanych na urząd sędziego w wadliwych procedurach, których zasiadanie w składach orzekających, oznacza, że nie jest to niezawisły i bezstronny sąd ustanowiony ustawą w rozumieniu Europejskiej Konwencji Praw Człowieka. W tym aspekcie zasada kolegialności składu orzekającego oraz ściśle z nią powiązana bezwzględna tajemnica narady sędziowskiej, posiadają kluczowe znaczenie gwarancyjne, gdyż tylko razem są w stanie utworzyć pancerz, który będzie skutecznie chronił sędziego przed presją czynników politycznych, a w efekcie – ingerowaniem przez nie w sferę orzecznictwa.
A Just Energy Transition Through the lens of Third World Approaches in International Law
Authors: ALFRED LOVE
Published: April 2024

The transition to green energy requires an all-hands-on-deck approach because of the effects of climate change on all. However, the nature and type of commitment or responsibilities required towards the transition are to be differentiated due to ‘countries’ different socioeconomic challenges and starting positions. This is the underpinning understanding of the United Nations Framework Convention on Climate Change (UNFCCC)’s energy transition strategy under the framework of the Paris Agreement (PA). Whether PA’s ‘differentiation’ representation and strategies, contributes to a ‘just’ energy transition is the goal of this paper. Arguably, embedded in the current UNFCCC energy transition strategy is the concept of a ‘just’ transition which recognises the importance of ‘a fair and equitable energy transition process’ (D Mccauley et al 2018:2). However, this paper, using the Third World Approaches to International Law (TWAIL), demonstrates how PA’s differentiation representations and soft approaches do not completely eliminate the problem of unjust energy transition (ET), or capture the multifaceted challenges of developing African contexts’ capacity towards the transition. The paper argues that the current international law ET initiative and strategy, in a bid to exact more diversity, blurs the understanding of responsibility and accountability, when it comes to finances and investments towards the current transition as well as countries' economic capacities. Based on this background, the paper uses the Nigerian social context to exemplify what a just transition would mean for a developing context, particularly in sub-Saharan Africa (SSA). The paper is divided into three sections. The first section is the introduction, and the second, unpacks the ET. The third section addresses the legal and policy framework of the ET - PA 2015, and finally problematises ET’s strategy using the TWAIL lens. It concludes by offering recommendations for a ‘just’ transition that balances the socioeconomic development of developing contexts.
Glosa do uchwały SN z dnia 15 lutego 2019 r., III CZP 85/18, Legalis
Authors: Rzewuska Magdalena
Published: April 2024

Publikację poświęcono analizie uchwały SN z dnia 15 lutego 2019 r., III CZP 85/18, w której sąd za niedopuszczalne uznał nabywanie przez rodziców dla dziecka znajdującego się pod ich władzą rodzicielską bez zezwolenia sądu opiekuńczego nieruchomości wskutek zawarcia umowy sprzedaży również w przypadku, gdy finanse na kupno uzyskane zostały z darowizny celowej przez nich dokonanej.
On the possibilities of recruiting minors as confidential personal sources of information
Authors: Herbowski Piotr
Published: April 2024

Polski ustawodawca nie uregulował w żaden sposób możliwości współpracy Policji z nieletnimi jako poufnymi osobowymi źródłami informacji. W związku z tym od wielu lat pojawiają się opinie o braku przeszkód prawnych do takiej współpracy. Zapomina się jednak, że może się ona wiązać z licznymi zagrożeniami dla małoletnich, a decyzja ustawodawcy wynika raczej z braku świadomości trudnych wyborów, przed jakimi mogą stanąć np. policjanci rozpracowujący grupy przestępcze.  Konieczne jest szersze przedstawienie własnego spojrzenia na tę kwestię, opartego zarówno na praktycznych doświadczeniach, jak i wynikającego z pogłębionej analizy przepisów konstytucyjnych, ustawowych i umów międzynarodowych. Wszystko to pozwala na sformułowanie szeregu postulatów, które ułatwią służbom policyjnym działanie w granicach prawa.
The substantive right to environment and the procedural environmental rights under the Aarhus Convention – Part I
Authors: Jendrośka Jerzy
Published: April 2024

Niniejszy artykuł stanowi część I artykułu, którego celem jest zbadanie wzajemnych relacji między materialnymi i proceduralnymi prawami do środowiska na tle typologii materialnych praw do środowiska i wyzwań napotykanych przy projektowaniu prawa do zdrowego środowiska. Część I zawiera analizę kontekstu w tym zakresie. Przedstawiono w niej pochodzenie terminu "prawo do środowiska" oraz różne podejścia do jego znaczenia, w szczególności różnice pomiędzy "prawem do dostępu do środowiska naturalnego" a "prawem do zdrowego środowiska". Następnie przedstawiono dwa możliwe podejścia do znaczenia terminu "prawo do zdrowego środowiska" i ich konsekwencje. Na tej podstawie artykuł przedstawia trzy główne metody rozwiązywania problemów dotyczących jakości środowiska w ramach systemu praw człowieka oraz relację między podejściem antropocentrycznym i ekocentrycznym. Następnie w artykule przedstawiono główne wyzwania napotykane przy tworzeniu "prawa do zdrowego środowiska", w szczególności kwestię dopasowania tego prawa do istniejącego systemu ochrony praw człowieka oraz ograniczenia związane z "zazielenianiem" innych praw człowieka. Niniejszy artykuł zawiera też krótki przegląd rozwoju odpowiednich przepisów prawnych dotyczących praw środowiskowych, w tym zarówno praw człowieka, jak i praw przyrody. Część I kończy się kilkoma uwagami na temat tendencji do rozwijania proceduralnych praw środowiskowych i oczekiwań wobec Konwencji EKG ONZ z Aarhus oraz jej roli w ochronie materialnych praw środowiskowych i demokracji uczestniczącej - co jest łącznikiem z częścią II, w której szczegółowo omówiono te kwestie i stwierdzono, że przepisy dotyczące dostępu do wymiaru sprawiedliwości w ramach Konwencji z Aarhus ani nie zapewniają wystarczających środków ochrony praw środowiskowych, ani - w świetle koncepcji leżących u podstaw Konwencji - nie powinny być traktowane jako pełniące jedynie taką rolę.
Non-surgical treatment of a severe deep bite with aligners and miniscrew: A hybrid approach
Authors: Arveda Niki , Colonna Anna , Siciliani Giuseppe , Lombardo Luca
Published: April 2024

This case report describes an orthodontic treatment combining aesthetic aligners with miniscrews and auxiliaries in an adult patient with Class II skeletal pattern and severe deep bite. A 38-year-old hypodivergent male patient with skeletal class II and severe deep bite presented for orthodontic treatment. The patient refused orthognathic surgery and conventional fixed multibracket treatment in favor of aligners in association with the use of miniscrews. The entire treatment was completed within nine months. Smile line and facial profile were improved, and post-treatment panoramic radiography showed good root parallelism, no sign of crestal bone height reduction, and no evidence of apical root resorption. The patient was satisfied with the aesthetic and functional outcomes. This case report illustrates that aligners associated with miniscrews and auxiliaries may be used to treat severe deep bite in certain cases.
Protagonisme LGBT et muséologie sociale : une approche affirmative appliquée à l’identité de genre et à l’orientation sexuelle
Authors: Baptista Jean , Boita Tony
Published: April 2024

À partir d’un certain nombre d’interrogations survenues à l’occasion du décès de Giuseppe Campuzano, fondateur du Musée Travesti du Pérou, la présente étude cherche à problématiser l’absence de débat muséologique sur la question LGBT (lesbiennes, gays, bisexuels et transsexuels). Dans cette optique, elle procède à l’inventaire d’un certain nombre d’expériences muséologiques consacrées à la thématique de l’identité de genre en Occident, en Amérique latine et au Brésil. L’objectif est de réaliser une synthèse des thèmes et des expériences muséales s’appliquant à surmonter l’extermination de la population LGBT et son invisibilité. Sur la base des données présentées, on tentera de définir les caractéristiques d’une muséologie dans laquelle le protagonisme LGBT puisse apporter sa contribution au processus de démocratisation entrepris par la muséologie sociale.
L’Écomusée de l’Amazonie : une expérience au service du développement communautaire dans la municipalité de Belém du Pará
Authors: Resende Martins Maria Terezinha
Published: April 2024

L’Écomusée de l’Amazonie (Ecomuseu da Amazônia) a pour antécédent et point de départ la création du Sous-système d’Éducation et de Culture pour un Développement durable dans la municipalité de Belém du Pará (1995/6). Il est né en 2007, sous la direction du Secrétariat municipal d’Éducation de Belém, avec le défi d’intégrer les différents segments de la société à « l’ensemble de son environnement », à partir de la connaissance et de la valorisation de son histoire, de son patrimoine naturel et culturel. En 2008, il a été intégré au Centre de Référence en Éducation environnementale – Fondation École Bosque Professeur Eidorfe Moreira (Fundação Escola Bosque Professor Eidorfe Moreira), sous la tutelle de la municipalité de Belém. Il opère dans quatre zones comprenant les communautés suivantes : le District d’Icoaraci (Cruzeiro et Vicentinos) ; l’Île de Caratateua (quartiers de São João do Outeiro, Fama, Tucumaeira, Curuperé et Nova República) ; l’Île de Cotijuba (communautés de Poção et Faveira) ; et l’Île de Mosqueiro (communautés de Caruaru et de Castanhal do Mari-Mari, et les agglomérations rurales de Paulo Fonteles et de Mari Mari). Les actions développées par l’écomusée ont pour but de promouvoir le développement d’activités régionales, et la méthodologie adoptée tient compte des communautés en tant que matière première endogène. Dans ce contexte, les résultats de ces activités développées par les communautés ont déjà commencé à montrer que celles-ci suscitent des réflexions et des changements dans les attitudes des personnes. L’écomusée contribue donc à la mobilisation populaire de la région, afin de réaffirmer les processus historiques et culturels, et favorise également le développement de pratiques durables.
From Home to Museum: Renata Crespi and the institutionalisation of a private collection
Authors: Dos Santos Tamira Naia
Published: April 2024

The Crespi Prado Foundation was created in 1975 by the initiative of Renata Crespi, widow of Fábio da Silva Prado (mayor of São Paulo between 1934 and 1938), to promote the arts and culture and to safeguard the couple’s collection. Renata Crespi was the daughter of an important Italian industrialist who immigrated to Brazil, and her husband belonged to one of the oldest and wealthiest families of the state of São Paulo. This article aims to discuss gender issues related to feminine collecting (specially regarding the creation of house museums) that underline the work of Renata Crespi as collector and creator of the Foundation in question.
Oxygen-tolerant, Eosin Y mediated synthesis of protein-polymer biohybrids and protein-coated polymer nanoparticles
Authors: Voutyritsa Errika , Lazou Thomai , Bushi Jonida , Margaritaki Stavroula , Charitaki Myrto , Christensen Sune M. , Hatzakis Nikos , Velonia Kelly
Published: April 2024

To avoid the use of metal catalysts used in conventional approaches, an Eosin Y/TEMED mediated, photoinduced polymerization of vinyl monomers was optimized for the synthesis of protein-polymer conjugates. This oxygen tolerant, photoinduced approach allowed to graft a series of hydrophobic, hydrophilic and responsive polymers with quantitative protein macroinitiator consumption. CALB bioconjugates were also synthesized and found to retain part of the parent protein activity for extended periods of time. Notably, when BSA was used in the absence of initiator, protein-coated nanoparticles were shown to form during emulsion polymerization.
Methoxide-Enabled Zirconium-Catalyzed Migratory Alkene Hydrosilylation
Authors: Luongo Orsola A. , Lemmerer Miran , Albers Sanne L. , Streuff Jan
Published: April 2024

A Cp2ZrCl2-catalyzed alkene hydrosilylation is reported that can be applied to non-activated and conjugated terminal and internal alkenes. It involves a catalytic Zr-walk process and leads to a selective conversion to the linear product. Lithium methoxide serves as mild catalyst activating agent, which significantly increases the applicability and operational simplicity in comparison to earlier zirconium(II)-based protocols. Supported by additional experiments, a mechanism via zirconium(IV) intermediates is proposed. Due to the benign nature and ready-availability of the zirconium catalyst, the reaction is an attractive alternative to established alkene hydrosilylation methods.
Extracting Structured Data from Organic Synthesis Procedures Using a Fine-Tuned Large Language Model
Authors: Ai Qianxiang , Meng Fanwang , Shi Jiale , Pelkie Brenden , Coley Connor W.
Published: April 2024

The popularity of data-driven approaches and machine learning (ML) techniques in the field of organic chemistry and its various subfields has increased the value of structured reaction data. Most data in chemistry is represented by unstructured text, and due to the vastness of the organic chemistry literature (papers, patents), manual conversion from unstructured text to structured data remains a largely manual endeavor. Software tools for this task would facilitate downstream applications such as reaction prediction and condition recommendation. In this study, we leverage the power of fine-tuned large language models (LLMs) to extract reaction information from organic synthesis procedure text into structured data following the Open Reaction Database (ORD) schema, a comprehensive data structure designed for organic reactions. The fine-tuned model produces syntactically correct ORD records with an average accuracy of 91.25% for ORD “messages” (e.g., full compound, workups, or condition definitions) and 92.25% for individual data fields (e.g., compound identifiers, mass quantities), with the ability to recognize compound-referencing tokens and to infer reaction roles. We investigate its failure modes and evaluate performance on specific subtasks such as reaction role classification.
Site-Selective Electrochemical C–H Silylations of Pyridines Enabled by Temporary Reductive Dearomatization
Authors: Yang Zhihao , Liu Xuan , Zhang Tianyuan , Maekawa Hirofumi , Hao Xin-Qi , Song Mao-Ping
Published: April 2024

Site-selective pyridine C–H silylation chemistry is of significant value but remains underdeveloped. In this study, we demonstrated that electron-deficient pyridines are highly selectively reductively silylated at the C4-position under electrochemical reduction conditions. A diverse array of C4-silylated pyridines was synthesized in good-to-excellent yields using common chlorosilanes as activating agents. Additionally, the use of bulky chlorotriisopropylsilane led to the formation of the C5-silylated products, albeit in moderate yields. This method is noteworthy due to its mild reaction conditions, simplicity, and excellent site selectivity for a diverse range of pyridines. Mechanistic studies revealed that the reaction involves temporary dearomatization to yield a 1,4-disilylated compound, which is quickly converted into the final C4-silylated pyridine through hydrolysis and air-driven rearomatization.
Electrocatalytic CO2 Reduction on Amorphous Cu Surfaces: Unveiling Structure-Activity Relationships
Authors: Muthuperiyanayagam Akshayini , Di Tommaso Devis
Published: April 2024

Amorphous materials hold significant promise for enhancing electrocatalytic CO2 reduction (CO2R) performance, but their intricate structures present challenges in understanding their behaviour. We present a computational investigation combining machine learning force fields and DFT calculations to explore amorphous copper (Cu) as a potential catalyst for the CO2R to C1 and C2 products. Our study reveals that amorphous Cu surfaces, compared to crystalline counterparts, offer a wider range of coordination sites, leading to a multitude of active centres for CO2 adsorption. Notably, some investigated surfaces spontaneously activate CO2, demonstrating their potential for efficient conversion. Furthermore, the intermediates of the CO2R on these surfaces exhibit enhanced stability, translating to lower overpotentials and improved selectivity. This work paves the way for further research and development in using amorphous Cu-based catalysts for sustainable CO2 conversion technologies, offering significant potential for mitigating climate change.
Photoswitchable arylazopyrazoles surfactants at the water-air interface: a microscopic perspective
Authors: Özcelik Gökberk , Bienek David , Hardt Michael , Glikman Dana , Braunschweig Björn , Heuer Andreas
Published: April 2024

Surfactants play an important role in modifying the properties of water-air interfaces. However, information on the microscopic behavior of the mechanisms is scarce. Here, we combine information from molecular dynamics simulations, surface tensiometry, and vibrational sum frequency generation spectroscopy to study the behavior of arylazopyrazole (AAP) as a surfactant. This combination of the experimental techniques allows a direct relation between surface tension and surface excess rather than just bulk concentration. Specifically, we compare the case with (O-AAP) and without (H-AAP) the addition of an octyl carbon chain, as well as for two different isomers (E and Z). From the simulations of these four systems, we see that a stronger cluster formation is accompanied by a weaker reduction of the surface tension for intermediate surface excesses. In some cases, even a small but noticeable maximum in the surface tension isotherm is observed. This correlation is expected from the general properties of the Frumkin isotherm. Both the addition of the carbon chain and the consideration of the E isomer compared to the Z isomer increase this effect. Although the experimental data of the surface tension vs. surface excess do not show a maximum, the general features of the surface tension isotherm are consistent between experiment and simulation. Evidence is also provided that it is primarily the interaction of the aromatic benzene rings that determines the strength of the surfactant interactions.
Efficient Access to β-Branched Noncanonical Amino Acids via Transaminase-Catalyzed Dynamic Kinetic Resolutions Driven by a Lysine Amine Donor
Authors: Dunham Noah , Ray Ritwika , Eberle Claire , Winston Matthew , Newman Justin , Gao Qi , Cao Yang , Barrientos Rodell , Ji Yining , Reibarkh Mikhail , Silverman Steven
Published: April 2024

Transaminases are choice biocatalysts for the synthesis of chiral primary amines, including amino acids bearing contiguous stereocenters. In this study, we employ lysine as a “smart” amine donor in transaminase-catalyzed dynamic kinetic resolution reactions to access β-branched noncanonical arylalanines. Our mechanistic investigation demonstrates that, upon transamination, the lysine-derived ketone byproduct readily cyclizes to a six-membered imine, driving the equilibrium in the desired direction and thus alleviating the need to load superstoichiometric quantities of the amine donor or deploy a multi-enzyme cascade. Lysine also shows good overall compatibility with a panel of wild-type transaminases, a promising hint of its application as a smart donor more broadly. Indeed, with this discovery in hand, we furnished a broad scope of β-branched arylalanines, including some bearing hitherto intractable cyclopropyl and isopropyl substituents, with high yields and excellent selectivities.
Ring-Opening Copolymerizations of a CO2-derived δ-Valerolactone with ε-Caprolactone and L-Lactide
Authors: Anderson Ryan , Fine Rachel , Rapagnani Rachel , Tonks Ian
Published: April 2024

Ring-opening random, gradient, and block copolymerizations of the CO2¬-derived δ-valerolactone 3-ethyl-6-vinyltetrahydro-2H-pyran-2-one (EtVP) with ε-caprolactone (ε-CL) and L-lactide (LLA) are reported. By employing both concurrent and sequential addition strategies, a variety of thermal and physical properties could be accessed. Concurrent copolymerization of EtVP with ε-CL yielded gradient copolymers with low glass transition temperatures, while block copolymerizations via sequential addition led to semi-crystalline materials regardless of monomer feed ratios. For LLA copolymerizations, glass transition temperatures increased with LLA incorporation regardless of addi-tion method, but higher Tg values were observed in block copolymerizations from sequential addition. Tensile testing of a poly(EtVP-b-LLA) with molar ratio of 40:60 EtVP:LLA resulted in σ = 0.8 MPa, E = 5.6 MPa and 83% elongation at break. The chemical recyclability of EtVP-based copolymers was explored as an end-of-life option. Both ε-CL and LLA copolymers could be recycled, with block copolymers giving higher yields of recycled monomers than random copolymers.