bluuebunny/crossref_metadata_2025 huggingface dataset:
The variation of surface propensity of halides with droplet size and temperature; The planar interface limit
Authors: Kwan Victor , Consta Styliani , Malek Shahrazad
Published: December 2023

The radial number density profiles of halide and alkali ions in aqueous clusters with equimolar radius $\lessapprox 1.4$~nm, that correspond to $\lessapprox$255~\ce{H2O} molecules, have been extensively studied by computations. However, the surface abundance of \ce{Cl-}, \ce{Br-} and \ce{I-} relative to the bulk interior in these smaller clusters may not be representative of the larger systems. Indeed, here we show that the larger the cluster is, the lower the relative surface abundance of chaotropic halides is. In droplets with equimolar radius of $\approx 2.45$~nm that corresponds to $\approx 2000$~H2O molecules, the polarizable halides show a number density maximum in the droplet's bulk-like interior. A similar pattern is observed in simulations of the aqueous planar interface with halide salts at room temperature. At elevated temperature the surface propensity of \ce{Cl-} decreases gradually, while that of \ce{I-} is partially preserved. The change of the chaotropic halide location at higher temperatures relative to room temperature may considerably affect photochemical reactivity in atmospheric aerosols, vapor-liquid nucleation and growth mechanisms, and salt crystallization via solvent evaporation. We argue that the commonly used approach of nullifying parameters in a force field in order to find the factors that determine the ion location does not provide transferable insight to other force fields.
Three-Component Friedel–Crafts Alkenylation of Arenes and Heteroarenes with Ynamides and Iodine(III) Electrophile
Authors: Kikuchi Jun , Nagata Toya , Ito Shingo , Yoshikai Naohiko
Published: December 2023

The three-component Friedel–Crafts type functionalization of an arene using an alkyne and an electrophile can offer a strategy for rapidly increasing the molecular complexity of aromatic compounds. While conceptually straightforward, the implementation of this reaction manifold has been largely limited to unfunctionalized alkynes and electrophiles such as iodine(I) reagents. Here, we report the development of a three-component Friedel–Crafts alkenylation that utilizes a mix of ynamides and a cationic iodine(III) electrophile (benziodoxole triflate). The reaction proceeds quickly under mild conditions across diverse arenes and heteroarenes, producing α-aryl- β-iodanyl enamides in a regio- and stereocontrolled manner. The robust trans-selectivity of this iodo(III)arylation process is attributed to the reactivity of a highly distorted keteniminium species generated from the ynamide and the iodine(III) electrophile. The iodanyl moiety in these reaction products is amenable to a variety of transition metal- mediated coupling, thus offering access to densely functionalized enamides.
State-Sponsored Abduction to Enforce British Law for Aotearoa New Zealand Pre-Annexation
Authors: Scoular Spencer
Published: December 2023

Prior to the annexation of Aotearoa New Zealand in 1840, British authorities sponsored and practised the abduction of suspects from the islands of New Zealand to New South Wales and Van Diemen's Land, where they could be charged and tried before British courts for infringing laws for New Zealand passed by the British Parliament, as well as orders for New Zealand issued by governors of New South Wales. The sponsorship and practice of state-sponsored abduction occurred in two distinct periods: between 1814 and 1823, governors of New South Wales sponsored "magistrates" to practise abduction; and, between 1833 and 1840, the British Government sponsored British Residents to practise abduction. Specific cases are examined where the sponsorship of abduction was put into practice. The unlawful, expensive and impractical nature of state-sponsored abduction contributed to the ineffectiveness of the British system of law and order for New Zealand pre-annexation, which ultimately influenced Britain's decision to annex New Zealand after first signing a treaty with Māori. With the arrival of Hobson, the signing of te Tiriti o Waitangi/the Treaty of Waitangi and Britain's annexation of New Zealand in 1840, state-sponsored abduction became unnecessary and was quietly discontinued.
Studying the Growth Course of Rough Elm (Ulmus Glabra Huds) in the Bayrachny Oak Grove of the Kashar Forestry of the Rostov Region
Authors: Puzankov A. A. , Baboshko O. A.
Published: December 2023

Rough elm is one of the main forest-forming species of Kashar forestry of the Rostov region. The aim of the research is to study the changes in the main inventory indicators (height, diameter, volume, increments, etc.) of the rough elm at different age periods. The study of the growth course of the rough elm in the dry bayrachny oak grove is of scientific and practical significance, since this tree species is used for the needs of the national economy not only in the Rostov region, but also in other regions of the Russian Federation. During the study of the growth course of the trunk of the rough elm, the methods generally accepted in forest inventory were applied. Enumerative inventory was carried out on the established trial area and the estimated inventory indicators (height and diameter) of the model tree were determined. After cutting down the model tree, its height, the length of the crown and the branchless trunk were measured, the places of taking cuts were marked in the middle of 2 m sections, at the base of the trunk, at a height of 1.3 m, and at the base of the vertex. In the course of the office processing, the tables of the growth course in diameter, height, volume and increment were compiled, as well as the graphs of the changes of the main inventory indicators in absolute values. The analysis of the data obtained showed that the rough elm has grown steadily over 34 years according to the main inventory indicators (height, diameter, volume), the values of increments vary. The reliability and correctness of the obtained regression equations of the growth course of rough elm (in height, diameter, volume) in the dry bayrachny oak grove is confirmed by the high value of the approximation coefficient (R2 = 0.99).
РОЛЬ ДИСФУНКЦІЙНИХ КОГНІТИВНИХ СХЕМ У ПАТОГЕНЕЗІ КОМОРБІДНИХ АФЕКТИВНИХ ПОРУШЕНЬ В ОСІБ З СОЦІАЛЬНОЮ ТРИВОГОЮ ТА СОЦІАЛЬНОЮ ФОБІЄЮ
Authors: Аврамчук Олександр
Published: December 2023

Мета: емпірично дослідити вплив когнітивних дисфункційних схем на вираженість коморбідної афективної патології, на прикладі симптомів депресивного стану в осіб з соціальною фобією.

Методи. Пошук попередніх досліджень здійснювався за допомогою сервісів  PubMed, Web-of-Science та Research Gate з фокусом уваги на дослідження соціальної фобії та коморбідних до неї депресивних станів. Емпіричне дослідження охопило показники вибірок з клінічно значущими ознаками депресивної симптомів згідно критеріїв DSM-5 – основна група: 737 осіб з вираженою соціальною тривогою та 582 особи, контрольна група, без ознак соціальної фобії. Результати оцінювалися за методиками YSQ-S, SPIN,  PHQ-9 та відповідними субшкалами методики SCL-90-R.

Результати. Продемонстровано, що рівень вираженості симптомів депресивних порушень й станів в осіб з соціальним тривожним розладом вищий за контрольну групу. Суттєву відмінність також продемонстрували показники загальної тяжкості симптомів та індекс симптомологічного дистресу. Аналіз актуальних ранніх дисфункційних схем продемонстрував суттєві відмінності (p<0,05) у порівнянні з контрольною групою для наступних категорій: соціальної ізоляції/відчуження, емоційної депривації, дефективності/сорому, емоційна інгібіція, самопожертви, надвисоких стандартів, очікування неминучих невдач/некомпетентності. Внесок дисперсії у показники соціальної тривоги та депресивної симптоматики можуть бути пояснені когнітивним, емоційним та поведінковим реагуванням відповідно до схем: соціальної ізоляції/відчуження, надвисоких стандартів, дефективності/сорому та неминучих невдач/некомпетентності. Типові переконання, які є характерними для соціальної фобії та пов'язані з очікуванням негативної оцінки від інших, підсилюються негативними думками, які є характерними для депресивного настрою. Уникаючи прямих соціальних контактів через страх покинення, людина обирає непродуктивні стратегії захисної поведінки, такі як емоційна депривація та соціальне відсторонення, а також раціоналізує порушене почуття соціальної приналежності.

Висновки. Аналіз результатів емпіричного дослідження підтверджує тісний зв'язок між дисфункційними переконаннями та вираженістю ключової депресивної психопатології в осіб з соціальним тривожним розладом. Подальші дослідження можуть бути скеровані на розширення ролі ранніх дисфункційних схем у патогенезі коморбідних станів завдяки медіаційному аналізу ролі механізмів уникнення когнітивного, емоційного (негативного) чи поведінкового у здобутті коригуючого досвіду як аспекту психологічної негнучкості та порушень адаптації.
PELATIHAN PEMBUATAN IKLAN PENYULUHAN BERBASIS APLIKASI CANVA DI KECAMATAN SAKO PALEMBANG
Authors: Aprilyanti Selvia , Faritzie Hariman Al , Azhari Azhari
Published: December 2023

Sebuah media dalam penyuluhan iklan suatu kegiatan atau barang  salah satunya berbasis aplikasi canva. Canva merupakan salah satu aplikasi dibidang desain grafis. Berdasarkan survey dilapangan staf dan masyarakat diKecamatan  Sako Kota Palembang belum memahami tentang media promosi secara mandiri menggunakan  digital advertising berbasis aplikasi canva untuk mendesain dan membuat media promosi atau penyuluhan kegiatan. Untuk itu pelaksanaan kegiatan pengabdian kepada masyarakat ini dilaksanakan melalui penyuluhan dan pelatihan penggunaan aplikasi Canva. Dengan tujuan memberikan edukasi kepada staf kantor dalam membuat media penyuluhan atau promosi menggunakan digital advertising. Kegiatan ini diharapkan dapat membantu masyarakat dalam menyebarkan atau promosi kegiatannya melalaui media digital. Kegiatan  pengabdian   ini   dilaksanakan   di   Kantor   Lurah Kelurahan Sialang Kecamatan Sako Kota Palembang  kepada  mitra yang berjumlah 30 orang warga. Metode   pelaksanaan terdiri atas beberapa tahapan antara lain Koordinasi dengan mitra, Penyuluhan Materi dan Pelatihan. Adapun hasil pelatihan ini adanya tingkat pemahaman mitra yang mengikuti kegiatan. Para peserta mempraktikkan langsung sesuai arahan materi pelatihan. Evaluasi kegiatan yang dilakukan yaitu pembagian kuisioner dengan beberapa indikator yaitu kemudahan penggunaan, kejelasan materi yang disampaikan, dan manfaat yang dirasakan oleh peserta. Darii total 30 peserta yang terdiri atas 33% peserta telah memahami sedikit materi dari penyuluhan dan 67% peserta sudah sangat paham dengan materi penyuluhan tentang pemanfaatan dan penggunaan aplikasi Canva.  Evaluasi kegiatan yang dilakukan yaitu pembagian kuisioner dengan beberapa indikator yaitu kemudahan penggunaan, kejelasan materi yang disampaikan, dan manfaat yang dirasakan oleh peserta. Peningkatan signifikan terjadi pada pengetahuan mitra. Aplikasi Canva akan membantu mitra dalam membuat media penyuluhan yang menarik dan persuasif.
PENDAMPINGAN BERBASIS COLLABORATIVE LEARNING UNTUK PENINGKATAN KETERAMPILAN REFLEKSI KRITIS GURU-GURU DI GUGUS 5 KECAMATAN BOAWAE
Authors: Bhoke Wilibaldus , Wewe Melkior , Wangge Maria Carmelita Tali , Kedhi Katarina
Published: December 2023

Penggunaan metode yang sesuai oleh guru merupakan salah satu cara untuk memastikan bahwa suatu unit pengajaran berjalan lancar dan siswa belajar sebagaimana mestinya. Dengan kata lain, kita harus selalu merenungkan proses pembelajaran kita untuk mengidentifikasi kesalahan kita dan bagaimana cara memperbaikinya. Dengan cara ini, kami dapat memastikan bahwa metode kami efektif. Dalam pembelajaran kolaboratif, sikap guru harus berpusat pada dua hal: memberikan contoh perilaku yang diperlukan untuk kolaborasi yang efektif dan menetapkan tujuan yang jelas untuk dicapai oleh kelas. Tujuan penelitian ini adalah untuk mengetahui mampu tidaknya guru-guru di Gugus 5 Kabupaten Boawae meningkatkan keterampilan refleksi kritisnya melalui pendampingan berbasis pembelajaran kolaboratif setelah mengikuti seluruh kegiatan kelas. Metode deskriptif kualitatif berdasarkan pendekatan studi kasus digunakan dalam penelitian ini. Data penelitian ini berasal dari kombinasi observasi dan diskusi bersama. Enam orang pendidik dari enam sekolah berbeda di Gugus 5 Kabupaten Boawae berpartisipasi sebagai subjek. Mengenai kemampuan guru untuk merefleksikan praktik pengajaran mereka sendiri, sebuah isu telah diangkat. Pendidik dapat menemukan jawaban atau jalan keluar dari permasalahan tersebut dengan melakukan refleksi kritis terhadap dirinya sendiri terhadap permasalahan tersebut. Kemampuan guru untuk melakukan refleksi kritis terhadap praktik mereka sendiri meningkat setelah menggunakan strategi pembelajaran kolaboratif, menurut penelitian ini. Kemampuan guru dalam membimbing siswa melalui proses pembelajaran dapat ditingkatkan melalui penerapan strategi pembelajaran kolaboratif ini. Rata-rata persentase hasil yang dicapai guru setelah melakukan kegiatan pendampingan ini adalah 70,0% yang membuktikannya. Kemampuan menerapkan pengetahuan secara efektif ditunjukkan oleh para pendidik ini. Pendidik yang mahir dalam refleksi kritis dapat mempelajari proses belajar siswanya dan menggunakan pengetahuan tersebut untuk menginformasikan keputusan pedagogis mereka sendiri. Pilihan pedagogi guru mempunyai dampak yang signifikan terhadap prestasi siswanya. Hasilnya, 70,0% lebih banyak guru di Distrik Boawae kini terlibat dalam refleksi kritis berkat kegiatan pendampingan berbasis Collaborative Learning.
Pengembangan Media MAGENTA (Magnet Bilangan Matematika) Pada Pembelajaran Matematika di Kelas III SDN Karang Anyar 03 Pagi Jakarta Pusat
Authors: Urfiyah Nur Camila , Ritonga Rudi
Published: December 2023

Penelitian ini dilatar belakangi karena kurangnya siswa kelas III SDN Karang Anyar 03 Pagi Jakarta Pusat dalam pemahaman perkalian pada pembelajaran matematika. Penelitian dilakukan dengan tujuan untuk menghasilkan media pembelajaran papan lipat MAGENTA (Magnet Bilangan Matematika) yang valid dan efektif. Media pembelajaran papan lipat MAGENTA (Magnet Bilangan Matematika) mendapatkan nilai dari ahli desain 94%, ahli materi 94%, ahli pelaksana pembelajaran 96% dengan kategori sangat valid untuk digunakan. Penilaian yang diberikan oleh siswa saat uji coba lapangan mendapatkan nilai 92% dengan kategori sangat valid. Penggunaan media pembelajaran papan lipat MAGENTA (Magnet Bilangan Matematika) pada materi satuan waktu dengan perkalian terbukti memenuhi kevalidan produk dan efektif untuk digunakan saat proses pembelajaran di kelas III SDN Karang Anyar 03 Pagi Jakarta Pusat. Hasil nilai siswa mengalami peningkatan sebanyak 25,17% yaitu nilai pretest sebelum penggunaan produk sebesar 60% dan siswa saat posttest atau setelah menggunakan produk sebesar 85,17%.
Effects of Teaching Materials on Learning Salt Factory Topics Based on Ethnoscience to Improve Mastery of Students Concepts and Life Skills
Authors: Sarwi Sarwi , Fathonah Siti , Anis Meutia , Rozi Fahrur , Wardani Sri , Winarto Winarto
Published: December 2023

Understanding concepts and life skills is important for students to develop. This study aims to analize effects of teaching materials on learning salt factory topics based on ethnoscience to improve mastery of concepts and life skills. This research is a quasi-experimental study using a non-equivalent design. Data collection techniques in this study used tests to measure concepts and questionnaires to measure life skills. The research instruments were multiple choice tests and a Likert scale questionnaire. The instrument meets the validity and reliability. The sample in this study was 77 elementary school students. Data analysis technique used  paired t-tests, and one ways ANOVA. The application of ethnoscience-based thematic learning tools in experimental 1 and experiment 2 showed higher concept understanding posttest results compared to control groups with conventional learning. This was proved by the sig value. < 0.05 and the average posttest score in experiment class 1 was 80.32 and experiment 2 was 83.37 higher than the control class of 75.25. learning physics salt factory materials sourced from local wisdom can increase mastery of concepts and increase understanding of life skills. This teaching effective enough in improving the mastery of concepts and developing students' life skills.
PENYELESAIAN SENGKETA PEMBAGIAN HARTA WARISAN OLEH KEPALA DESA SEBAGAI HAKIM PERDAMAIAN DESA
Authors: Ruhmana Hentika , Basniwati AD
Published: December 2023

Penelitian ini bertujuan untuk mengetahui pelaksanaan penyelesaian sengketa warisan oleh kepala desa sebagai hakim perdamaian desa dan untuk mengetahui faktor penghambat dan pendukung penyelesaian sengketa warisan oleh kepala desa sebagai hakim perdamaian desa. Penelitian ini dilaksanakan dengan mengaplikasikan metode penelitian hukum empiris yang menggunakan Pendekatan Conseptual, Pendekatan Perundang-Undangan, Pendekatan Sosiologis dan Pendekatan Kasus. Hasil penelitian terungkap bahwa pelaksanaan sengketa dapat diselesaikan dengan cara penyelesaian non litigasi serta menggunakan sistem hukum Islam/hukum Fara’id mengedepankan cara kekeluargaan ataupun mediasi para pihak agar terciptanya musyawarah mufakat untuk mencapai kesepakatan.
TANGGUNGJAWAB PENGUSAHA TAMBANG TERHADAP KESEHATAN MASYARAKAT AKIBAT DARI POLUSI YANG DITIMBULKAN
Authors: YANI AHMAD , Suryani Hamzah Any
Published: December 2023

Penelitian ini  bertujuan  untuk  mengetahui  pengaturan  tanggungjawab  sosial perusahaan  tambang menurut undang-undang, faktor-faktor penyebab dari dampak  yang ditimbulkan serta tanggungjawab perusahaan atas dampak polusi yang ditimbulkan. Penelitian ini menggunakan jenis penelitian hukum empiris dengan metode analisis kualitatif melalui pendekatan perundang-undangan, konseptual dan sosiologis. Hasil penelitian menunjukkan bahwa undang-undang yang mengatur tanggungjawab sosial perusahaan tambang yaitu UU No 20/2020 Tentang Minerba, UU No 32/2009 Tentang lingkungan hidup, UU No 36/2009 Tentang kesehatan, UU No 17/2019 Tentang sumber daya air, PMK No 61/2013 Tentang  Kesehatan Matra dan PP No 22/2021 Tentang lingkungan hidup. Adapun faktor penyebab dari dampak yang ditimbulkan yaitu berasal dari kegiatan pertambangan yang terbuka, minimnyanya drainase, lalu lintas kendaraan pengangkut hasil pertambangan serta pengolahaan hasil tambang yang terbuka tanpa penyiraman. Dampak yang ditimbulkan antara lain pencemaran udara, rusaknya jalan, berpotensi terjadinya erosi tanah dan penurunan kualitas air. Pertanggungjawaban perusahaan tambang atas dampak yang ditimbulkan yaitu dengan melakukan penyiraman dan penutupan bak kendaraan tambang, memberikan CSR, ganti rugi terhadap masyarakat yang lahan pertaniannya terkena dampak, melakukan reklamsi lahan bekas tambang serta pembuatan drainase.
Understanding the Warburg Effect Yields New Insights into the Metabolic Control of Cancer
Authors: Bahrami Hassan , Tafrihi Majid
Published: December 2023

Human cells may use either aerobic or anaerobic cellular respiration processes to produce energy, depending on cellular conditions. When there is enough oxygen, cells respire aerobically, but in case of oxygen deficiency, anaerobic cellular respiration is used, which leads to lactic acidosis and an increased risk of cancer according to Warburg's hypothesis.

This paper reviews key aspects related to the historical evolutionary origins of metabolic pathways in cancer cells and compares similarities between cancer cells and ancient unicellular organisms to address the origins of metabolic change in cancer cells and provide new insights into the metabolic control of cancer.

Understanding the main causes of cancer and the biological origin of their behavioral abnormalities is essential for the metabolic control of cancer. Environmental stressors to cells may include lack of essential nutrients, poor oxygenation, excess acids, viruses, infections, and exposure to chemicals, toxins, and radiation. These cellular stressors can cause normal cells to mutate and become cancerous in an attempt to survive in the harsh conditions.

According to the research findings, creating appropriate conditions at the cellular level in terms of pH, sufficient oxygenation and the availability of good sugars, essential vitamins, minerals, enzymes and coenzymes through a healthy diet can lead to a metabolic switch in cancer cells that controls mutations, which can help prevent and control cancer.
Trombólisis sistémica exitosa en el tromboembolismo pulmonar de alto riesgo tras cirugía de reparación de hernia inguinal. A propósito de un caso
Authors: Martinez Juan Pedro , Fong-Ruíz Fernando , Matesanz Laura , Mejuto Lucía , Muñoyerro Francisco , Suarez José , Díaz Ricardo
Published: December 2023

El tromboembolismo pulmonar masivo es una entidad potencialmente mortal si no es tratado de forma emergente. La trombólisis sistémica es una terapéutica adecuada para estos casos cuando se presenten con datos de shock obstructivo o fracaso respiratorio agudo severo. Presentamos el caso de un varón de 69 años con antecedente de reparación programada de una hernia inguinal diez días antes del evento que acude al servicio de urgencias y emergencias por síncope. A las cuatro horas de su estancia en el hospital sufre hipotensión y desaturación brusca y es diagnosticado de tromboembolismo pulmonar masivo requiriendo la administración de fármacos fibrinolíticos. En este caso, no hubo eventos adversos hemorrágicos y la reperfusión fue completa inmediatamente después a su administración. Se adjuntan imágenes del electrocardiograma (EKG) y la tomografía computarizada (CT) con contraste previo y posterior a la administración del fibrinolítico donde se objetivan reperfusión total de la arteria pulmonar y corrección de todos los cambios eléctricos secundarios a la sobrecargar del ventrículo derecho en un plazo menor a 24 horas. El paciente fue dado de alta a medicina interna a las 72 horas.
Sanando a nuestros médicos: una reflexión sobre nuestra salud
Authors: Robinson Davis Eugenia C.
Published: December 2023

Todos los médicos buscamos siempre apoyarnos en la evidencia científica y ampliar nuestros conocimientos para ponerlos al servicio de nuestros pacientes. Nuestros pacientes son nuestra razón   de   ser.   Sin embargo   es importante reflexionar sobre la vulnerabilidad de nuestra población médica con trastornos en  la salud física   y  mental   que van desde depresión, ansiedad, “burnout”, eventos  coronarios, cerebrovasculares,  neoplasias, demencia, suicidios y farmacodependencia  entre  otros. Es una morbilidad sentida a la cual no podemos seguir indiferentes.   
Estas situaciones no solo dependen de nuestra información genética, sino que también son desencadenados en gran medida por el estrés generado por las cargas depositadas en nosotros, las angustias y dolencias de nuestros pacientes, las presiones de las instituciones y del sistema de salud sumado a nuestros propios avatares internos. Como consecuencia se va deteriorando no solo nuestra salud sino también la empatía con el paciente la cual más allá del conocimiento científico es esencial para su recuperación. Esta situación no solo afecta a los médicos en ejercicio sino   también a los médicos en formación.
Este artículo les ofrece a mis queridos colegas una reflexión sobre algunas herramientas que están a nuestro alcance para reducir dicha vulnerabilidad y continuar ejerciendo esta maravillosa profesión.
Afiliación de la Asociación Colombiana de Neumología y Cirugía de Tórax a la Academia Nacional de Medicina de Colombia: palabras de la presidente de la asociación.
Authors: Blanquicett Barrios Ledys
Published: December 2023

Recuento histórico de la Asociación Colombiana de Neumología y Cirugía de Tórax, sus actividades y principales retos a futuro, así como su nueva vinculación como afiliada a la Academia Nacional de Medicina de Colombia.
The economic revolution of Alexander III: from free trade to protectionism
Authors: Nefedov Sergey
Published: December 2023

The article is devoted to the consideration of the circumstances of the transition to protectionism in the reign of Alexander III. In the 1860s and 1870s, the “free trade"policy of finance minister M.Kh. Reitern led to the stagnation of heavy industry and lagging behind western countries. The protest of Slavophile business circles against “free trade" was conveyed to the heir to the throne, Alexander Alexandrovich, through professor I.K. Babst. In 1881, the heir became the Emperor Alexander III, Pobedonostsev - his closest adviser, and Katkov -“the mouthpiece" of the new political course. The industrialists gained the right to vote, in 1882, a large Trade and Industrial Congress was convened, which demanded the introduction of protective duties. After a long period of pressure on the liberal minister of finance N.Kh. Bunge (and his resignation), duties were introduced that ensured the accelerated development of Russian heavy industry and partially overcome the backlog.
Spor Merkezlerine Giden Bireylerin Sağlıklı Yaşam Biçimi Davranışlarının Farklı Değişkenler Açısından İncelenmesi
Authors: ÇAKMAK Ayşe Büşra , ALINCAK Fikret
Published: December 2023

Bu çalışmanın amacı, spor merkezlerine giden bireylerin sağlıklı yaşam biçimi davranışlarının farklı değişkenler açısından incelenmesidir. Araştırmanın evrenini Gaziantep ilinde spor merkezlerine giden bireyler, örneklem grubunu ise gönüllülük esasına dayalı olarak seçilen 403 birey oluşturmaktadır. Araştırmada veri toplama aracı olarak; Bahar ve ark., (2008) tarafından geliştirilen “Sağlıklı Yaşam Biçimi Davranışları Ölçeği II” kullanılmıştır. Verilerin analizinde SPSS 22.0 programı kullanılmıştır. Normallik ve homojenlik sınamasının akabinde ikili gruplarda bağımsız gruplarda t testi, ikiden fazla grupların olduğu değişkenlerde ise tek yönlü varyans analizi ve LSD post-hoc test düzeltmesi yapılmıştır. Değerler ortalama ve standart sapma şeklinde sunulmuştur ve 0.05 anlamlılık düzeyinde incelenmiştir. Araştırma sonucunda; kilo değişkeni açısından farklılık olduğu ve 51-60 kilo arasındaki katılımcıların diğer kilo gruplarına göre daha fazla puan elde ettikleri tespit edilmiştir. Katılımcıların sağlıklı yaşam biçimi davranışları ölçeğinden elde ettikleri puanların eğitim durumu değişkeni açısından anlamlı farklılık olduğu ve eğitim düzeyi arttıkça sağlıklı yaşam becerilerinin de arttığı belirlenmiştir. Ayrıca katılımcıların sağlıklı yaşam biçimi davranışları ölçeğinden elde ettikleri puanların son kronik hastalıkları değişkeni açısından ölçeğin sağlık sorumluluğu alt boyutunda anlamlı bir farklılık olduğu tespit edilmiştir. Katılımcıların günlük çalışma süresi değişkenine göre ise ölçeğin fiziksel aktivite ve egzersiz alt boyutlarında anlamlı bir farklılık belirlenmiştir. Katılımcıların sağlıklı yaşam biçimi davranışları ölçeğinden elde ettikleri puanların lisanslı sporcu olma ölçeğinin beslenme alt boyutlarında anlamlı bir farklılık olduğu, sağlık durumu değişkenine göre; fiziksel aktivite, beslenme, manevi gelişim ve stres yönetimi alt boyutlarında anlamlı farklılık olduğu sonucuna ulaşılmıştır.
Analysis of nitrate and nitrite content in meat products without added additives
Authors: Agić Tea , Rečić Maja , Piškor Dorotea , Posavec Marina , Kreković Dubravka MArija
Published: December 2023

A food additive is any substance not consumed as a food ingredient but added to food for a specific purpose, for example inhibiting microorganism growth and maintaining sensory quality. Potassium and sodium nitrates and nitrites are among the most commonly used food additives in the meat industry due to their antimicrobial effect, in particular to prevent the growth of pathogenic bacteria Clostridium botulinum and its spores. Additionally, they provide specific sensory attributes, primarily the inherent pink color of meat products. Studies showed that excessive intake of nitrates and nitrites may pose a risk to human health. The object of this research was determination of nitrite and nitrate content in meat products without added additives or with those additives from natural sources. Samples were mortadella, cooked ham and bologna sausage as thermally proccessed (cured) meat products and fermented sausage. The statistical analysis of the results for mortadella, cooked ham and bologna sausage as thermally proccessed meat products showed a p-value <0.05 between recipes with added nitrite salt and new recipes. The values of the median mass concentration of sodium nitrite in the commercial recipes were from 3.50-40.50 mg/kg, whereas this value was below the limit of detection in new recipes. Also, for fermented sausage, the p-value below 0.05 between commercial recipe with nitrite and nitrate salt and new recipes confirmed the hypothesis for replacement of mentioned salts with new concepts. The value of the median mass concentration of sodium nitrate in the recipe with added nitrate salt was 268.52 mg/ kg, whereas this value was below the limit of detection in other recipes.
Immunohistochemical detection of p16INK4a proteins expression in paraffin embedded sections of colorectal cancer tissues.
Authors: Lelo Abdelameer K. , Abdulmohaimen Nidhal , Aftan Faeza
Published: December 2023

Background: Uncontrolled tumor cell proliferation is a reality in tumor cells, and the progression from a normal cell into a transformed cell probably includes genetic events affecting checkpoints in the cell cycle machinery.Materials and methods: This study investigated the immunoexpression of p16INK4a in the paraffin sections from 43-cancers of colorectal tissue (CRC),26-hyperplastic polyps and adenomas(CRHPA) and 35-normal tissues (CRN),using immunohistochemical assay. We correlated the expression patterns with tumor histopathological type, site of the tumor, distance metastasis according to the TNM system.Results: In colorectal cancer (CRC) patients’ p16INK4a,immunoexpression was detected in 32/43, there was significant association for p16INK4a, which showed high reaction with monoclonal antibodies in the distal colon and rectal area with P value < 0.001. There was no significant correlation between tissue invasion stage and p16INK4a. There was no significant difference in the immunoexpression of p16INK4a in relation to the two groups of patients with the stage of the disease.Conclusion: p16INK4a, expression have high level in CRHPA than in CRN tissue. Also, their expression in CRC is more than in CRN tissue. In addition, p16INK4a immunoexpression in CRC was significantly more than in CRHPA.
Infodynamics, a Review
Authors: Jaffe Klaus
Published: December 2023

A review of studies on the interaction of information with the physical world found no fundamental contradiction between the eighth authors promoting Infodynamics. Each one emphasizes different aspects. The fact that free energy and useful work require information, and that new information requires energy, may favor synergistic chain reactions producing increases of negentropy (increases in Useful Information or decreases in Information Entropy) in living systems. Infodynamics searches for feasible balances between energy and information using empirical studies of the effect of information on Free Energy and vice-versa. Getting information requires energy and so does separating useful information from noise. Producing energy requires information, but there is no direct proportionality between the energy required to produce the information and the energy unleashed by this information. Energy and information are parts of two separate realms of reality that are intimately entangled but follow different laws of nature. Infodynamics recognizes multiple forms and dimensions of information. Information can be the opposite of thermodynamic entropy (Negentropy), a trigger of Free Energy (Useful or Potentially Useful), a reserve (Redundant Information), Structural, Enformation, Intropy, Entangled, Encrypted Information or Noise. These are overlapping functional properties focusing on different aspects of Information. Studies on information entropy normally quantify only one of these dimensions. The challenge of Infodynamics is to design empirical studies to overcome these limitations. The working of sexual reproduction and its evolution through natural selection might teach us how.
The Impact of Leadership and Talent Management: The Case of Generation Z in The Lebanese Retail Sector
Authors: Harb Atef , Trad Mony
Published: December 2023

The current study’s objective is to understand the interplay between leadership and talent management. As a result, at every level of interactions between superiors and subordinates, leadership practices revolve around dimensions that positively affect the talent management of Generation Z employees. This paper addresses a main research question that asks about the extent to which leadership determinants enhance, the most, Generation Z’s1 talent management at the workplace. The answer to the research question came in a manner that demonstrates the four hypotheses expected toward the start of the study, specifically the role of leadership and intrinsic motivation in positively affecting talent management among employees. A conceptual framework is established to estimate leadership factors that can, probably, affect Generation Z employees’ talent management. It is feasible to validate or refute the pre-formulated hypotheses using the quantitative data that has been collected throughout the 218 surveys. Research variables explain Generation Z’s desire to evolve in retail corporate companies. It was judicious to start the empirical investigation by interviewing managers or HR experts. A correlation analysis, which found positive linear trends in the relationships between independent and dependent variables, was insufficient to support the four study hypotheses. As such, the four research hypotheses were investigated using a multiple regression model. In addition, for the results’ findings, the four research hypotheses have been validated. Such a phase, prior to the quantitative technique, can make research findings more valuable. Generation Z members will be enticed by being recruited by a company where they believe that their corporate expectations will be met. Talent management is a new conception for enhancing human capital evolution in contemporary organizations. Avoiding classical ways for managing employees is all the alternatives to promote, internally, talents and therefore gain a competitive advantage over counterparts.
Strategic Management In Agriculture
Authors: Nuralieva Nazgul Moldalievna
Published: December 2023

The most important task of strategic planning for the development of agricultural enterprises is the formation of a perspective sectoral structure of production, ensuring its sustainable development in a long term perspective.

The purpose of this work is to study the features of the formation of strategic management at the enterprises of the agricultural sector.

Methods or methodology of investigated work. The research is based on the fundamental works of native and foreign scientists, revealing the mechanism of strategic management at the level of an economic entity.

Results. Agriculture has already passed the boundary which the society is not ready to consume everything longer that it grows. In modern conditions, when there is competition with foreign producers, only those goods of native producers that are needed by society and correspond to its purchasing power are in demand.

This circumstance leads to a change in the combinations of economic sectors and the structure of each of them, which contribute to a significant increase in production efficiency, ensuring high profits for the enterprise as a whole, insuring one industry to another and one product to another in cases where unaccounted climatic, technological or market factors arise. Another internal factor of a comprehensive solution to the problem, which should be highlighted, is the on-farm reorganization of agricultural production and the widespread introduction of technologies and technological methods into it that ensure resource and energy conservation.

Sphere of usage the results. The results of the research can be used in the development of specific proposals related to the scientific substantiation of the formation and implementation of the strategic management system at the enterprises of the agricultural sector.

Conclusions. It is concluded that the peculiarities of enterprises in the agricultural sector that affect the content of strategic management should include: size, structure and potential of land; dependence on natural and climatic conditions and seasonality of production; availability and capabilities of fixed assets; the number, age structure and qualifications of the labor force; the state of the market for agro-industrial products, etc.
ECONOMIC AND ENERGY SECURITY OF UKRAINE IN CONDITIONS OF WAR
Authors: Кубатко Олександр , Ковальов Богдан , Яременко Анастасія , Півень Владислав
Published: December 2023

Economic and energy security has always played a big role in the well-being of the state, which is especially important in times of war. Developing mechanisms to counter internal and external threats, such as war, is a fundamental aspect of ensuring national security. The purpose of the study is to analyze the scale of threats in the economic and energy sectors of Ukraine and to explore the possibilities and ways of ensuring their stability in the conditions of war and in the post-war period. During the period of the full-scale invasion, the Russian Federation has already destroyed 30-40% of the sources of renewable energy in the southern and southeastern regions of Ukraine. On February 2023, Ukraine temporarily lost 44% of its nuclear generation, 75% of its thermal power plants capacity, and 33% of block cogeneration plants. Since the beginning of the war, 7,704 million Ukrainians have left abroad, millions of citizens have moved to Western Ukraine. The number of the working population is significantly reduced, due to which the purchasing power of the population has decreased by 12-15%, and at the same time the value of GDP has decreased and inflation has increased. Ensuring the independence of the national economy and energy industry, their stability and sustainability are one of the main functions of the state. Ukraine actively uses tools to ensure economic and energy security: maintaining unchanged tariffs for housing and communal services, partial tax reduction, fixing the exchange rate of the hryvnia and introducing currency restrictions, using renewable energy sources, etc. Public initiatives are also being formed to ensure security in the economic and energy sectors, which is an important factor for a successful outcome, because only the cooperation of the state, business and society as a whole will lead Ukraine to qualitative changes, including ensuring economic and energy security. PEST analysis demonstrates the existence of justified political, economic, social and technological prerequisites for the successful recovery of the national economy, taking into account the issues of economic and energy security. Specific, actionable recommendations on how to tackle economic security challenges directly during the war and in the post-war period were provided, including digitalization of public services, use of decarbonization strategies, and human capital development.
AURA project: enjoyment of the auralisation experience by different target groups
Authors: Bartalucci Chiara , Bellomini Raffaella , Busa Lucia , Pulella Paola , Delle Macchie Sara , Luzzi Sergio
Published: December 2023

Modern technologies have become a familiar feature in experiencing our cultural heritage. With the AURA (Auralisation of acoustic heritage sites using Augmented and Virtual Reality) project, music and opera houses in Berlin, Florence and Lviv opened up to the potentials of auralisation for music performing arts and establishments. AURA reached out to the European music community and offer a wide range of opportunities of building new audiences, new business models, new performance practices and exciting new aural experiences. Also, it aims to create a model for cross sectoral collaboration to foster creativity and to promote European heritage in new ways. The present article describes the procedures applied by Vie en.ro.se Ingegneria project partner to engage different target groups, make them experience auralised models of the three theatres and assess their perception through a questionnaire designed ad-hoc for each group and through the participation in round tables discussions. The main outcomes from the analysis of the collected data are reported, together with the structure of video tutorials implemented to ensure a wide dissemination of results.
Un libro infame e calunnioso. Ancora qualche nota su un'opera attribuita a Cristina di Belgiojoso
Authors: De Francesco Antonino
Published: December 2023

L'articolo analizza gli Studi intorno alla Lombardia negli ultimi trent'anni (Parigi, 1846), attribuiti a Cristina di Belgiojoso. Attraverso l'analisi delle sue edizioni si suggerisce che il vero autore fosse Carlo de Castillia, ritenuto il responsabile della condanna di Confalonieri. Si torna con nuove prospet- tive sulla giornata del 20 aprile 1814, che pose fine al Regno d'Italia. Il ruo- lo di Castillia, che accusava Confalonieri di essere l'involontario artefice del ritorno dell'Austria, suggerisce l'importanza degli anni napoleonici nella costruzione del movimento nazionale in Lombardia e getta nuova luce sul conflitto interno al patriottismo alla vigilia della rivoluzione del 1848.
Nascere tra le assenze. Esperienze di un gruppo di psicoterapia con adolescenti
Authors: Arzeno Monia , Carlini Gianluca
Published: December 2023

Le vicissitudini di un gruppo di psicoterapia con pazienti adolescenti, dalla sua fon-dazione a poco più di un anno di lavoro, portano all'attenzione del conduttore e dell'osservatrice del gruppo il tema sofferto dell'assenza dell'altro. A seconda del ma-teriale analizzato, e quindi a livelli diversi, in questo articolo essi ripercorrono, anche in ascolto del proprio controtransfert, la difficoltà e l'urgenza di confrontarsi con vis-suti depressivi e mortiferi legati all'assenza e alla perdita. Lungi dal considerare la questione come unicamente portata dai pazienti, il condutto-re e l'osservatrice si interrogano sulle forze che hanno sostenuto e influenzato la na-scita e il definirsi di questo gruppo, il quale manifesta caratteristiche di funzionamen-to proprie, che vengono qui descritte. Viene proposta allora l'ipotesi che un "incastro" fra diversi fattori (quali la mancanza di una cultura della gruppalità condivisa nell'istituzione dove il gruppo è nato, il nu-mero spesso esiguo di partecipanti, le storie dei pazienti costellate di abbandoni ed anche i compiti evolutivi propri dell'adolescenza) abbiano comportato e permesso al gruppo, se non di elaborare il tema dell'assenza dell'altro, almeno di continuare a ri-proporlo attraverso tempi e linguaggi differenti (interazioni fra partecipanti, agiti, nar-razioni di film,…), con il fine di sviluppare margini di pensabilità sempre più ampi.
ВИСВІТЛЕННЯ ТЕМИ БЕЗПІЛОТНИКІВ В ОНЛАЙН-МЕДІА ПІД ЧАС ВІЙНИ В КОНТЕКСТІ АВІАЦІЇ
Authors: Melnykova-Kurhanova O. , Vasylchenko V. , Lashkina M.
Published: December 2023

The purpose of the study is to determine the peculiarities of coverage of the topic of drones during the war in the context of aviation.

Research methodology. The research was carried out using the theoretical method to analyse the latest works of domestic and foreign researchers, the monitoring method (materials on the topic of our study were systematised), the content analysis method (news about drones from March to May 2023 were analysed), and the systematic approach (used to organise journalistic materials on drones in the context of the aerospace industry).

Results. The scientific achievements of modern domestic and foreign researchers on the role of drones in the media and during the war are summarized; the features of content about aviation and drones, in particular in online media, are identified; informational, analytical texts, journalistic, documentary films of 2022 and 2023 covering aviation topics presented in online media are analysed; a content analysis of the news discourse on drones during the war is carried out on the example of the Ukrainska Pravda website; monitoring of journalistic and documentary materials on aviation is carried out.

The novelty of the results is the identification of the peculiarities of content, presentation, and choice of journalism genre in materials on aviation topics, in particular, drones.

Practical significance. The findings can be used in teaching the courses Aviation Journalism, Publicistics and Documentary, and Social Media. Coverage of the topic of drones and unmanned aerial vehicles is an integral part of the analysis of the current Russian-Ukrainian war, so the study may be of interest to experts and military analysts.

Key words: online media, drones, aviation journalism, content, documentary.
Historical redlining impacts wildlife biodiversity across California
Authors: Estien Cesar , Fidino Mason , Wilkinson Christine , Morello-Frosch Rachel , Schell Christopher
Published: December 2023

Legacy effects describe the persistent, long-term impacts on an ecosystem following the removal of an abiotic or biotic feature. Redlining, a policy that codified racial segregation and disinvestment in minoritized neighborhoods, has produced legacy effects with profound impacts on urban ecosystem structure and health. These legacies have detrimentally impacted public health outcomes, socioeconomic stability, and environmental health. However, the collateral impacts of redlining on nonhuman species are uncertain. Here, we investigated whether faunal biodiversity was associated with redlining. We used home-owner loan corporation (HOLC) maps [grades A (i.e., “best” and “greenlined”), B, C, and D (i.e., “hazardous” and “redlined”)] across four cities in California and participatory science data (iNaturalist) to estimate alpha and beta diversity across six clades (mammals, birds, insects, arachnids, reptiles, and amphibians) as a function of HOLC grade. We found that greenlined neighborhoods were able to detect unique species with less sampling effort, with redlined neighborhoods needing over 8,000 observations to detect the same number of unique species. Historically redlined neighborhoods had lower native and nonnative species richness compared to greenlined neighborhoods across each city, with disparities remaining at the clade level. Further, community composition (i.e., beta diversity) consistently differed among HOLC grades for all cities, including large differences in species assemblage observed between green and redlined neighborhoods. Our work spotlights the lasting effects of social injustices on the community ecology of cities, additionally emphasizing that urban conservation and management efforts must incorporate an anti-racist, justice-informed lens to improve biodiversity in urban environments.