bluuebunny/crossref_metadata_2025 huggingface dataset:
Muntingia calabura Leaves Mediated Green Synthesis of CuO Nanorods: Exploiting Phytochemicals for Unique Morphology
Authors: Selvanathan Vidhya , Aminuzzaman Mohammod , Tey Lai-Hock , Razali Syaza Amira , Althubeiti Khaled , Alkhammash Hend Ibraheem , Guha Samar Kumar , Ogawa Sayaka , Watanabe Akira , Shahiduzzaman Md. , Akhtaruzzaman Md.
Published: October 2021

In this study, phytochemical assisted nanoparticle synthesis was performed using Muntingia calabura leaf extracts to produce copper oxide nanoparticles (CuO NPs) with interesting morphology. Scanning electron microscope (SEM) and transmission electron microscope (TEM) analysis of the biosynthesized CuO NPs reveal formation of distinct, homogeneous, and uniform sized CuO nanorods structure with thickness and length of around 23 nm and 79 nm, respectively. Based on Fourier-transform infrared (FTIR) analysis, the unique combinations of secondary metabolites such as flavonoid and polyphenols in the plant extract are deduced to be effective capping agents to produce nanoparticles with unique morphologies similar to conventional chemical synthesis. X-ray diffraction (XRD) analysis verified the monoclinical, crystalline structure of the CuO NPs. The phase purity and chemical identity of the product was consolidated via X-Ray photoelectron spectroscopy (XPS) and Raman spectroscopic data which indicate the formation of a single phase CuO without the presence of other impurities. The direct and indirect optical band gap energies of the CuO nanorods were recorded to be 3.65 eV and 1.42 eV.
Effects of the Manufacturing Methods on the Mechanical Properties of a Medical-Grade Copolymer Poly(L-lactide-co-D,L-lactide) and Poly(L-lactide-co-ε-caprolactone) Blend
Authors: Rodriguez Reinoso Mariana , Civera Marco , Burgio Vito , Chiappone Annalisa , Grimaldo Ruiz Oliver , D’Anna Alessandra , Riccio Carmela , Roppolo Ignazio , Frache Alberto , Antonaci Paola , Surace Cecilia
Published: October 2021

Biocompatible and biodegradable polymers represent the future in the manufacturing of medical implantable solutions. As of today, these are generally manufactured with metallic components which cannot be naturally absorbed within the human body. This requires performing an additional surgical procedure to remove the remnants after complete rehabilitation or to leave the devices in situ indefinitely. Nevertheless, the biomaterials used for this purpose must satisfy well-defined mechanical requirements. These are difficult to ascertain at the design phase since they depend not only on their physicochemical properties but also on the specific manufacturing methods used for the target application. Therefore, this research was focused on establishing the effects of the manufacturing methods on both the mechanical properties and the thermal behavior of a medical-grade copolymer blend. Specifically, Injection and Compression Molding were considered. A Poly(L-lactide-co-D,L-lactide)/Poly(L-lactide-co-ε-caprolactone) blend was considered for this investigation, with a ratio of 50/50 (w/w), aimed at the manufacturing of implantable devices for tendon repair. Interesting results were obtained.
Mesophase Pitch-Based Carbon Fibers: Accelerated Stabilization of Pitch Fibers under Effective Plasma Irradiation-Assisted Modification
Authors: Peng Yuanshuo , Tan Ruixuan , Liu Yue , Yang Jianxiao , Li Yanfeng , Li Jun , Fan Zheqiong , Shi Kui
Published: October 2021

Stabilization is the most complicated and time-consuming step in the manufacture of carbon fibers (CFs), which is important to prepare CFs with high performance. Accelerated stabilization was successfully demonstrated under effective plasma irradiation-assisted modification (PIM) of mesophase pitch fibers (PFs). The results showed that the PIM treatment could obviously introduce more oxygen-containing groups into PFs, which was remarkably efficient in shortening the stabilization time of PFs with a faster stabilization heating rate, as well as in preparing the corresponding CFs with higher performance. The obtained graphitized fiber (GF-5) from the PF-5 under PIM treatment of 5 min presented a higher tensile strength of 2.21 GPa, a higher tensile modulus of 502 GPa, and a higher thermal conductivity of 920 W/m·K compared to other GFs. Therefore, the accelerated stabilization of PFs by PIM treatment is an efficient strategy for developing low-cost pitch-based CFs with high performance.
Induced Superconducting Transition in Ultra-Thin Iron-Selenide Films by a Mg-Coating Process
Authors: Cao Zhiqiang , Chen Longqing , Cheng Zhenxiang , Qiu Wenbin
Published: October 2021

Binary Iron selenide (FeSe) thin films have been widely studied for years to unveil the high temperature superconductivity in iron-based superconductors. However, the origin of superconducting transition in this unconventional system is still under debate and worth deep investigations. In the present work, the transition from insulator to superconductor was achieved in non-superconducting FeSe ultrathin films (~8 nm) grown on calcium fluoride substrates via a simple in-situ Mg-coating by a pulsed laser deposition technique. The Mg-coated FeSe film with an optimized amount of Mg exhibited a superconducting critical temperature as 9.7 K and an upper critical field as 30.9 T. Through systematic characterizations on phase identification, carrier transport behavior and high-resolution microstructural features, the revival of superconductivity in FeSe ultrathin films is mostly attributed to the highly crystallized FeSe and extra electron doping received from external Mg-coating process. Although the top few FeSe layers are incorporated with Mg, most FeSe layers are intact and protected by a stable magnesium oxide layer. This work provides a new strategy to induce superconductivity in FeSe films with non-superconducting behavior, which might contribute to a more comprehensive understanding of iron-based superconductivity and the benefit to downstream applications such as magnetic resonance imaging, high-field magnets and electrical cables.
A Contemporary Review of Aluminium MMC Developed through Stir-Casting Route
Authors: Yadav Poonam , Ranjan Alok , Kumar Harish , Mishra Abhishek , Yoon Jonghun
Published: October 2021

The growing demand for composite materials with improved properties is attracting a lot of attention from industries such as automotive, aerospace, military, aviation, and other manufacturing. Aluminium metal matrix composites (AMMCs), with various reinforcements such as continuous/discontinuous fibers, whiskers, and particulates, have captured the attention due to their superior tribological, mechanical, and microstructural characteristics as compared to bare Al alloy. AMMCs have undergone extensive research and development with different reinforcements in order to obtain the materials with the desired characteristics. In this paper, we present a review on AMMCs produced through stir casting routes. This review focuses on the following aspects: (i) different reinforcing materials in AMMCs; (ii) microstructural study of reinforced metal matrix composites (MMCs) through stir casting. Both reinforcing micro- and nanoparticles are focused. Micro- and nanoreinforced AMMCs have the attractive properties of combination such asthe low-weight-to-high-strength rati and, low density; (iii) various tribological and mechanical properties with the consideration of different input parameters; (iv) outlook and perspective.
The Electrospray (ESI) and Flowing Atmosphere-Pressure Afterglow (FAPA) Mass Spectrometry Studies of Nitrophenols (Plant Growth Stimulants) Removed Using Strong Base-Functionalized Materials
Authors: Pawlaczyk Mateusz , Cegłowski Michał , Frański Rafał , Kurczewska Joanna , Schroeder Grzegorz
Published: October 2021

The functional silica-based materials functionalized with a strong nitrogen base TBD (SiO2-TBD) deposited via a linker or with a basic poly(amidoamine) dendrimer containing multiple terminal amine groups -NH2 (SiO2-EDA) and functional polymers containing a strong phosphazene base (Polymer-Phosphazene) or another basic poly(amidoamine) dendrimer (PMVEAMA-PAMAM) were tested as sorbents dedicated to a mixture of nitrophenols (p-nitrophenol and 2-methoxy-5-nitrophenol), which are analogs of nitrophenols used in plant growth biostimulants. The adsorptive potential of the studied materials reached 0.102, 0.089, 0.140, and 0.074 g of the nitrophenols g−1, for SiO2-TBD, SiO2-EDA, polymer-phosphazene, and PMVEAMA-PAMAM, respectively. The sorptive efficiency of the analytes, i.e., their adsorption on the functional materials, the desorption from the obtained [(sorbent)H+ − nitrophenolates–] complexes, and interactions with the used soil, were monitored using mass spectrometry (MS) technique with electrospray (ESI) and flowing atmosphere-pressure afterglow (FAPA) ionizations, for the analysis of the aqueous solutions and the solids, respectively. The results showed that the adsorption/desorption progress is determined by the structures of the terminal basic domains anchored to the materials, which are connected with the strength of the proton exchange between the sorbents and nitrophenols. Moreover, the conducted comprehensive MS analyses, performed for both solid and aqueous samples, gave a broad insight into the interactions of the biostimulants and the presented functional materials.
Strength, Carbonation Resistance, and Chloride-Ion Penetrability of Cement Mortars Containing Catechol-Functionalized Chitosan Polymer
Authors: Choi Se-Jin , Bae Sung-Ho , Lee Jae-In , Bang Eun-Ji , Ko Haye-Min
Published: October 2021

There have been numerous recent studies on improving the mechanical properties and durability of cement composites by mixing them with functional polymers. However, research into applying modified biopolymer such as catechol-functionalized chitosan to cement mortar or concrete is rare to the best of our knowledge. In this study, catechol-functionalized chitosan (Cat-Chit), a well-known bioinspired polymer that imitates the basic structures and functions of living organisms and biological materials in nature, was synthesized and combined with cement mortar in various proportions. The compressive strength, tensile strength, drying shrinkage, accelerated carbonation depth, and chloride-ion penetrability of these mixes were then evaluated. In the ultraviolet–visible spectra, a maximum absorption peak appeared at 280 nm, corresponding to catechol conjugation. The sample containing 7.5% Cat-Chit polymer in water (CPW) exhibited the highest compressive strength, and its 28-day compressive strength was ~20.2% higher than that of a control sample with no added polymer. The tensile strength of the samples containing 5% or more CPW was ~2.3–11.5% higher than that of the control sample. Additionally, all the Cat-Chit polymer mixtures exhibited lower carbonation depths than compared to the control sample. The total charge passing through the samples decreased as the amount of CPW increased. Thus, incorporating this polymer effectively improved the mechanical properties, carbonation resistance, and chloride-ion penetration resistance of cement mortar.
The Study of Magnetoimpedance Effect for Magnetoelectric Laminate Composites with Different Magnetostrictive Layers
Authors: Chen Lei , Wang Yao , Luo Tianhong , Zou Yongkang , Wan Zhongjie
Published: October 2021

The rectangular magnetoelectric (ME) composites of Metglas/PZT and Terfenol-D/PZT are prepared, and the effects of a magnetostrictive layer’s material characteristics on the magnetoimpedance of ME composite are discussed and experimentally investigated. The theoretical analyses show that the impedance is not only dependent on Young’s modulus and the magnetostrictive strain of magnetostrictive material but is also influenced by its relative permeability. Compared with Terfenol-D, Metglas possesses significantly higher magnetic permeability and larger magnetostrictive strain at quite low Hdc due to the small saturation field, resulting in the larger magnetoimpedance ratio. The experimental results demonstrate that the maximum magnetoimpedance ratios (i.e., ΔZ/Z) of Metglas/PZT composite are about 605.24% and 239.98% at the antiresonance and resonance, respectively. Specifically, the maximum ΔZ/Z of Metglas/PZT is 8.6 times as high as that of Terfenol-D/PZT at the antiresonance. Such results provide the fundamental guidance in the design and fabrication of novel multifunction devices based on the magnetoimpedance effect of ME composites.
The Use of Calcium Phosphates in Cosmetics, State of the Art and Future Perspectives
Authors: Carella Francesca , Degli Esposti Lorenzo , Adamiano Alessio , Iafisco Michele
Published: October 2021

Calcium phosphates (CaPs) belong to a class of biomimetic materials widely employed for medical applications thanks to their excellent properties, such as biodegradability, biocompatibility and osteoinductivity. The recent trend in the cosmetics field of substituting potentially hazardous materials with natural, safe, and sustainable ingredients for the health of consumers and for the environment, as well as the progress in the materials science of academics and chemical industries, has opened new perspectives in the use of CaPs in this field. While several reviews have been focused on the applications of CaP-based materials in medicine, this is the first attempt to catalogue the properties and use of CaPs in cosmetics. In this review a brief introduction on the chemical and physical characteristics of the main CaP phases is given, followed by an up-to-date report of their use in cosmetics through a large literature survey of research papers and patents. The application of CaPs as agents in oral care, skin care, hair care, and odor control has been selected and extensively discussed, highlighting the correlation between the chemical, physical and toxicological properties of the materials with their final applications. Finally, perspectives on the main challenges that should be addressed by the scientific community and cosmetics companies to widen the application of CaPs in cosmetics are given.
Flexural Strength Design of Hybrid FRP-Steel Reinforced Concrete Beams
Authors: Zhou Binbin , Wu Ruo-Yang , Liu Yangqing , Zhang Xiaohui , Yin Shiping
Published: October 2021

Through proper arranging of a hybrid combination of longitudinal fiber reinforced polymer (FRP) bars and steel bars in the tensile region of the beam, the advantages of both FRP and steel materials can be sufficiently exploited to enhance the flexural capacity and ductility of a concrete beam. In this paper, a methodology for the flexural strength design of hybrid FRP-steel reinforced concrete (RC) beams is proposed. Firstly, based on the mechanical features of reinforcement and concrete and according to the latest codified provisions of longitudinal reinforcement conditions to ensure ductility level, the design-oriented allowable ranges of reinforcement ratio corresponding to three common flexural failure modes are specified. Subsequently, the calculation approach of nominal flexural strength of hybrid FRP-steel RC beams is established following the fundamental principles of equilibrium and compatibility. In addition to the common moderately-reinforced beams, the proposed general calculation approach is also applicable to lightly-reinforced beams and heavily-reinforced beams, which are widely used but rarely studied. Furthermore, the calculation process is properly simplified and the calculation accuracy is validated by the experimental results of hybrid FRP-steel RC beams in the literature. Finally, with the ductility analysis, a novel strength reduction factor represented by net tensile steel strain and reinforcement ratio is proposed for hybrid FRP-steel RC beams.
Recent Progress in Carbon Fiber Reinforced Polymers Recycling: A Review of Recycling Methods and Reuse of Carbon Fibers
Authors: Butenegro José Antonio , Bahrami Mohsen , Abenojar Juana , Martínez Miguel Ángel
Published: October 2021

The rapid increase in the application of carbon fiber reinforced polymer (CFRP) composite materials represents a challenge to waste recycling. The circular economy approach coupled with the possibility of recovering carbon fibers from CFRP waste with similar properties to virgin carbon fibers at a much lower cost and with lower energy consumption motivate the study of CFRP recycling. Mechanical recycling methods allow the obtention of chopped composite materials, while both thermal and chemical recycling methods aim towards recovering carbon fibers. This review examines the three main recycling methods, their processes, and particularities, as well as the reuse of recycled carbon fibers in the manufacture of new composite materials.
Contact Dynamics: Legendrian and Lagrangian Submanifolds
Authors: Esen Oğul , Lainz Valcázar Manuel , de León Manuel , Marrero Juan Carlos
Published: October 2021

We are proposing Tulczyjew’s triple for contact dynamics. The most important ingredients of the triple, namely symplectic diffeomorphisms, special symplectic manifolds, and Morse families, are generalized to the contact framework. These geometries permit us to determine so-called generating family (obtained by merging a special contact manifold and a Morse family) for a Legendrian submanifold. Contact Hamiltonian and Lagrangian Dynamics are recast as Legendrian submanifolds of the tangent contact manifold. In this picture, the Legendre transformation is determined to be a passage between two different generators of the same Legendrian submanifold. A variant of contact Tulczyjew’s triple is constructed for evolution contact dynamics.
Association Rules Mining for Hospital Readmission: A Case Study
Authors: Miswan Nor Hamizah , Sulaiman ‘Ismat Mohd , Chan Chee Seng , Ng Chong Guan
Published: October 2021

As an indicator of healthcare quality and performance, hospital readmission incurs major costs for healthcare systems worldwide. Understanding the relationships between readmission factors, such as input features and readmission length, is challenging following intricate hospital readmission procedures. This study discovered the significant correlation between potential readmission factors (threshold of various settings for readmission length) and basic demographic variables. Association rule mining (ARM), particularly the Apriori algorithm, was utilised to extract the hidden input variable patterns and relationships among admitted patients by generating supervised learning rules. The mined rules were categorised into two outcomes to comprehend readmission data; (i) the rules associated with various readmission length and (ii) several expert-validated variables related to basic demographics (gender, race, and age group). The extracted rules proved useful to facilitate decision-making and resource preparation to minimise patient readmission.
On the Oscillation of Solutions of Differential Equations with Neutral Term
Authors: Mofarreh Fatemah , Almutairi Alanoud , Bazighifan Omar , Aiyashi Mohammed A. , Vîlcu Alina-Daniela
Published: October 2021

In this work, new criteria for the oscillatory behavior of even-order delay differential equations with neutral term are established by comparison technique, Riccati transformation and integral averaging method. The presented results essentially extend and simplify known conditions in the literature. To prove the validity of our results, we give some examples.
Mathematical Models with Nonlocal Initial Conditions: An Exemplification from Quantum Mechanics
Authors: Sytnyk Dmytro , Melnik Roderick
Published: October 2021

Nonlocal models are ubiquitous in all branches of science and engineering, with a rapidly expanding range of mathematical and computational applications due to the ability of such models to capture effects and phenomena that traditional models cannot. While spatial nonlocalities have received considerable attention in the research community, the same cannot be said about nonlocality in time, in particular when nonlocal initial conditions are present. This paper aims at filling this gap, providing an overview of the current status of nonlocal models and focusing on the mathematical treatment of such models when nonlocal initial conditions are at the heart of the problem. Specifically, our representative example is given for a nonlocal-in-time problem for the abstract Schrödinger equation. By exploiting the linear nature of nonlocal conditions, we derive an exact representation of the solution operator under assumptions that the spectrum of Hamiltonian is contained in the horizontal strip of the complex plane. The derived representation permits us to establish the necessary and sufficient conditions for the problem’s well-posedness and the existence of its solution under different regularities. Furthermore, we present new sufficient conditions for the existence of the solution that extend the existing results in this field to the case when some nonlocal parameters are unbounded. Two further examples demonstrate the developed methodology and highlight the importance of its computer algebra component in the reduction procedures and parameter estimations for nonlocal models. Finally, a connection of the considered models and developed analysis is discussed in the context of other reduction techniques, concentrating on the most promising from the viewpoint of data-driven modelling environments, and providing directions for further generalizations.
Urothelial Cell Carcinoma of the Renal Pelvis Misdiagnosed as Ureteropelvic Junction Obstruction: A Case Report
Authors: Choi Jeong-Hyouk , Choi Tae-Soo , Lee Dong-Gi , Min Gyeong-Eun
Published: October 2021

Urothelial tumors are typically a disease affecting elderly individuals and are rare in young patients. Moreover, upper urinary tract urothelial carcinoma is extremely rare in the young age group. In this study, we present a case of urothelial cell carcinoma of the renal pelvis and ureter in a young man without risk factors of urothelial carcinoma, which was misdiagnosed as ureteropelvic junction obstruction and treated with a laparoscopic pyeloplasty.
Prediction of Insufficient Beta-Lactam Concentrations in Extracorporeal Membranous Oxygenation Patients
Authors: Polain Amandine , Gorham Julie , Romeo Immacolata , Belliato Mirko , Peluso Lorenzo , Partipilo Francesco , Njimi Hassane , Brasseur Alexandre , Jacobs Frederique , Creteur Jacques , Hites Maya , Taccone Fabio Silvio
Published: October 2021

Background: The aim of this study was to identify predictors of insufficient beta-lactam concentrations in patients undergoing extracorporeal membrane oxygenation (ECMO). Methods: Retrospective analysis of all patients receiving ECMO support and treated with ceftazidime or cefepime (CEF), piperacillin/tazobactam (TZP), or meropenem (MEM). Trough drug concentrations (Cmin) were measured before the subsequent dose, according to the decision of the attending physician. Insufficient drug concentrations were identified if Cmin was below the clinical breakpoint of Pseudomonas aeruginosa. Results: A total of 222 Cmin (CEF, n = 41; TZP, n = 85; MEM, n = 96) from 110 patients were included; insufficient concentrations were observed in 26 (12%) antibiotic assessments; 21 (81%) of those occurred during MEM therapy. Insufficient Cmin were associated with a shorter time from initiation of antibiotics to measurement, a lower single dose of antibiotic, a higher creatinine clearance (CrCL), lower sequential organ failure assessment (SOFA) scores, and less use of continuous renal replacement therapy (CRRT) when compared to others. Conclusions: Insufficient broad-spectrum beta-lactam concentrations were observed in 12% of drug measurement during ECMO therapy. Higher than recommended drug regimens could be considered in the very early phase of therapy and in those patients with augmented renal clearance and with less severe organ dysfunction.
Theoretical Study on Metasurfaces for Transverse Magneto-Optical Kerr Effect Enhancement of Ultra-Thin Magnetic Dielectric Films
Authors: Chen Jing , Wu Guohua , Gu Ping , Tang Yumei , Yang Chun , Yan Zhendong , Tang Chaojun , Liu Zhengqi , Gao Fan , Cai Pinggen
Published: October 2021

We study how to enhance the transverse magneto-optical Kerr effect (TMOKE) of ultra-thin magnetic dielectric films through the excitation of strong magnetic resonances on metasurface with a metal nanowire array stacked above a metal substrate with an ultra-thin magnetic dielectric film spacer. The plasmonic hybridizations between the Au nanowires and substrate result in magnetic resonances. The periodic arrangement of the Au nanowires can excite propagating surface plasmon polaritons (SPPs) on the metal surface. When the SPPs and the magnetic resonances hybridize, they can strongly couple to form two strong magnetic resonances, which are explained by a coupled oscillator model. Importantly, benefitting from the strong magnetic resonances, we can achieve a large TMOKE signal up to 26% in the ultra-thin magnetic dielectric film with a thickness of only 30 nm, which may find potential applications in nanophotonics, magnonics, and spintronics.
Differential Allelic Expression among Long Non-Coding RNAs
Authors: Heskett Michael B. , Spellman Paul T. , Thayer Mathew J.
Published: October 2021

Long non-coding RNAs (lncRNA) comprise a diverse group of non-protein-coding RNAs >200 bp in length that are involved in various normal cellular processes and disease states, and can affect coding gene expression through mechanisms in cis or in trans. Since the discovery of the first functional lncRNAs transcribed by RNA Polymerase II, H19 and Xist, many others have been identified and noted for their unusual transcriptional pattern, whereby expression from one chromosome homolog is strongly favored over the other, also known as mono-allelic or differential allelic expression. lncRNAs with differential allelic expression have been observed to play critical roles in developmental gene regulation, chromosome structure, and disease. Here, we will focus on known examples of differential allelic expression of lncRNAs and highlight recent research describing functional lncRNAs expressed from both imprinted and random mono-allelic expression domains.
The Cohesin Complex and Its Interplay with Non-Coding RNAs
Authors: Kuru-Schors Merve , Haemmerle Monika , Gutschner Tony
Published: October 2021

The cohesin complex is a multi-subunit protein complex initially discovered for its role in sister chromatid cohesion. However, cohesin also has several other functions and plays important roles in transcriptional regulation, DNA double strand break repair, and chromosome architecture thereby influencing gene expression and development in organisms from yeast to man. While most of these functions rely on protein–protein interactions, post-translational protein, as well as DNA modifications, non-coding RNAs are emerging as additional players that facilitate and modulate the function or expression of cohesin and its individual components. This review provides a condensed overview about the architecture as well as the function of the cohesin complex and highlights its multifaceted interplay with both short and long non-coding RNAs.
Energy Metabolism in Relation to Diet and Physical Activity: A South Asian Perspective
Authors: Wulan Siti N. , Raza Qaisar , Prasmita Hera S. , Martati Erryana , Maligan Jaya M. , Mageshwari Uma , Fatima Itrat , Plasqui Guy
Published: October 2021

The prevalence of overweight and obesity is on the rise around the world, not only in the West, but also in Asian countries. South Asian countries in particular are experiencing a rapid increase in overweight and obesity, that coexists with the rapid increase in non-communicable diseases linked to obesity such as diabetes and cardiovascular disease than any other country in Asia. The phenomena observed in South Asian countries are due to the size of the population, the ageing of the population, the high degree of urbanization and the lifestyle changes in favor of increased energy consumption and reduced physical activity. The imbalance between energy consumption and energy expenditure results in the development of a positive energy balance that, over time, accumulates in higher body fat. South Asians were reported to have a more unfavorable body composition with a higher percentage of body fat than Caucasians with an equivalent BMI. Body composition is a major determinant of resting energy expenditure. It has been reported that South Asians have a lower resting energy expenditure than Caucasians with the same BMI. Resting energy expenditure accounts for the majority of total daily energy expenditure and, therefore, plays a crucial role in achieving the balance between energy intake and expenditure.
Association between Milk Intake and Incident Stroke among Japanese Community Dwellers: The Iwate-KENCO Study
Authors: Tanno Kozo , Yonekura Yuki , Okuda Nagako , Kuribayashi Toru , Yabe En , Tsubota-Utsugi Megumi , Omama Shinichi , Onoda Toshiyuki , Ohsawa Masaki , Ogasawara Kuniaki , Tanaka Fumitaka , Asahi Koichi , Itabashi Ryo , Ito Shigeki , Ishigaki Yasushi , Takahashi Fumiaki , Koshiyama Makoto , Sasaki Ryohei , Fujimaki Daisuke , Takanashi Nobuyuki , Takusari Eri , Sakata Kiyomi , Okayama Akira
Published: October 2021

We aimed to evaluate the association between the milk consumption and incident stroke in a Japanese population, where milk consumption is lower than that of Western countries. In total, 14,121 participants (4253 men and 9868 women) aged 40–69 years, free from cardiovascular diseases (CVD) were prospectively followed for 10.7 years. Participants were categorized into four groups according to the milk intake frequency obtained from a brief-type self-administered diet questionnaire. The adjusted HRs of total stroke, ischemic stroke and haemorrhagic stroke associated with milk intake frequency were calculated using the Cox proportional hazards model. During the follow-up, 478 stroke cases were detected (208 men and 270 women). Compared to women with a milk intake of <2 cups/week, those with an intake of 7 to <12 cups/week had a significantly low risk of ischemic stroke in a model adjusting CVD risk factors; the HR (95% CI) was 0.53 (0.32–0.88). No significant associations were found in men. This study suggested that milk intake of 7 to <12 cups/week decreased the risk of ischemic stroke in Japanese women. Milk intake of about 1 to <2 cups/day may be effective in the primary prevention of ischemic stroke in a population with low milk intake.
Coherent Random-Modulated Continuous-Wave LiDAR Based on Phase-Coded Subcarrier Modulation
Authors: Xu Zhongyang , Yu Fengxi , Qiu Bowen , Zhang Yawei , Xiang Yu , Pan Shilong
Published: October 2021

A coherent random-modulated continuous-wave (RMCW) LiDAR transmits a lightwave modulated by a pseudo-random binary sequence (PRBS). The lightwave backscattered from targets is received and used to reconstruct the PRBS. Then, the time-of-flight is extracted by correlating the reconstructed PRBS and the original PRBS. We propose a coherent RMCW LiDAR based on phase-coded subcarrier modulation, in which the impacts of internal reflection and optical Doppler frequency shift (DFS) are mitigated. A continuous lightwave is amplitude-modulated by an RF signal which is phase-coded with a PRBS. Coherent detection is used in the receiver. A beat signal that consisted of a low-frequency signal and a high-frequency signal is obtained by a single balanced photodetector (BPD). The optical DFS can be directly extracted from the low-frequency signal. It is used to compensate for the frequency offset of PRBS, which is extracted from the high-frequency signal. In addition, the background noise caused by internal reflection is suppressed by averaging over successive measurement spots. In this paper, the performance of a coherent RMCW LiDAR is firstly analyzed by numeric simulations and demonstration experiments. Then, line-scanning measurements for moving targets are implemented to demonstrate the 3D imaging capability of the proposed coherent RMCW LiDAR.
Mechanical Performance of 3D-Printed Biocompatible Polycarbonate for Biomechanical Applications
Authors: Gómez-Gras Giovanni , Abad Manuel D. , Pérez Marco A.
Published: October 2021

Additive manufacturing has experienced remarkable growth in recent years due to the customisation, precision, and cost savings compared to conventional manufacturing techniques. In parallel, materials with great potential have been developed, such as PC-ISO polycarbonate, which has biocompatibility certifications for use in the biomedical industry. However, many of these synthetic materials are not capable of meeting the mechanical stresses to which the biological structure of the human body is naturally subjected. In this study, an exhaustive characterisation of the PC-ISO was carried out, including an investigation on the influence of the printing parameters by fused filament fabrication on its mechanical behaviour. It was found that the effect of the combination of the printing parameters does not have a notable impact on the mass, cost, and manufacturing time of the specimens; however, it is relevant when determining the tensile, bending, shear, impact, and fatigue strengths. The best combinations for its application in biomechanics are proposed, and the need to combine PC-ISO with other materials to achieve the necessary strengths for functioning as a bone scaffold is demonstrated.
Waste-to-Energy: Production of Fuel Gases from Plastic Wastes
Authors: Chow Cheuk-Fai , Lam Chow-Shing , Lau Kai-Chung , Gong Cheng-Bin
Published: October 2021

A new mechanochemical method was developed to convert polymer wastes, polyethylene (PE), polypropylene (PP), and polyvinyl chloride (PVC), to fuel gases (H2, CH4, and CO) under ball-milling with KMnO4 at room temperature. By using various solid-state characterizations (XPS, SEM, EDS, FTIR, and NMR), and density functional theory calculations, it was found that the activation followed the hydrogen atom transfer (HAT) mechanism. Two metal oxidant molecules were found to abstract two separate hydrogen atoms from the α–CH and β–CH units of substrates, [–βCH2–αCH(R)–]n, where R = H in PE, R = γCH3 in PP, and R = Cl in PVC, resulting in a di-radical, [–βCH•–αC•(R)–]. Subsequently, the two unpaired electrons of the di-radical were recombined into an alkene intermediate, [–βCH = αC(R)–], which underwent further oxidation to produce H2, CH4, and CO gases.
Effective End-Group Modification of Star-Shaped PNVCL from Xanthate to Trithiocarbonate Avoiding Chemical Crosslinking
Authors: Cortez-Lemus Norma A. , Hermosillo-Ochoa Eduardo , Licea-Claverie Ángel
Published: October 2021

In this study, six-arm star-shaped poly(N-vinylcaprolactam) (PNVCL) polymers prepared by reversible addition–fragmentation chain transfer (RAFT) polymerization were subjected to aminolysis reaction using hexylamine. Chemically crosslinked gels or highly end-functionalized star polymers can be obtained depending mainly on the type of solvent used during the transformation of the RAFT functional group. An increase in the viscosity of the solution was observed when the aminolysis was carried out in THF. In contrast, when the reaction was conducted in dichloromethane, chain-end thiol (PNVCL)6 star polymers could be obtained. Moreover, when purified (PNVCL-SH)6 star polymers are in contact with THF, the gelation occurs in just a few minutes, with an obvious increase in viscosity, to form physical gels that become chemically crosslinked gels after 12 h. Interestingly, when purified (PNVCL-SH)6 star polymers were stirred in distilled water, even at high aqueous solution concentration (40 mg/mL), there was no increase in the viscosity or gelation, and no evident gels were observed. The analysis of the hydrodynamic diameter (Dh) by dynamic light scattering (DLS) did not detect quantifiable change even after 4 days of stirring in water. On the other hand, the thiol groups in the (PNVCL-SH)6 star polymers were easily transformed into trithiocarbonate groups by addition of CS2 followed by benzyl bromide as demonstrated by UV-Vis spectroscopical analysis and GPC. After the modification, the (PNVCL)6 star polymers exhibit an intense yellow color typical of the absorption band of trithiocarbonate group at 308 nm. To further demonstrate the highly effective new trithiocarbonate end-functionality, the PNVCL polymers were successfully chain extended with N-isopropylacrylamide (NIPAM) to form six-arm star-shaped PNIPAM-b-PNVCL block copolymers. Moreover, the terminal thiol end-functionality in the (PNVCL-SH)6 star polymers was linked via disulfide bond formation to l-cysteine to further demonstrate its reactivity. Zeta potential analysis shows the pH-responsive behavior of these star polymers due to l-cysteine end-functionalization. By this using methodology and properly selecting the solvent, various environment-sensitive star polymers with different end-groups could be easily accessible.
Flows of Linear Polymer Solutions and Other Suspensions of Rod-like Particles: Anisotropic Micropolar-Fluid Theory Approach
Authors: Shelukhin Vladimir
Published: October 2021

We formulate equations governing flows of suspensions of rod-like particles. Such suspensions include linear polymer solutions, FD-virus, and worm-like micelles. To take into account the particles that form and their rotation, we treat the suspension as a Cosserat continuum and apply the theory of micropolar fluids. Anisotropy of suspensions is determined through the inclusion of the microinertia tensor in the rheological constitutive equations. We check that the model is consistent with the basic principles of thermodynamics. In addition to anisotropy, the theory also captures gradient banding instability, coexistence of isotropic and nematic phases, sustained temporal oscillations of macroscopic viscosity, shear thinning and hysteresis. For the flow between two planes, we also establish that the total flow rate depends not only on the pressure gradient, but on the history of its variation as well.
A Suitable Shape of the Suction Head for a Cleaning Process in a Factory Developed by Computational Fluid Dynamics
Authors: Thongsri Jatuporn , Tangsopa Worapol , Khongsin Jirawat
Published: October 2021

The previous shape of the suction head (SH) employed in a cleaning process in a factory had a low performance, removed fewer particles, and generated an annoying noise. Therefore, new shapes of SH have been proposed to solve the issues and the cleaning performance was investigated by the Shear Stress Transport (SST) k-ω turbulence, Discrete Phase (DP), Large Eddy Simulation (LES), and Ffowcs Williams and Hawkings (FW–H) models in a transient state of computational fluid dynamics (CFD). The SST k-ω and DP models were applied to determine the airflow, suspension velocity, cleaning region, and particle trace. In addition, the LES and FW–H models were used to evaluate the noise, sound pressure level, and frequency generated from the proposed shapes. All simulation results were validated with the air velocity and noise measurements and were analyzed to find a suitable shape. The simulation and experimental results revealed that the shapes of the SH affected the cleaning performance and noise generation. The higher the air velocity, the higher the noise generation. The suitable shape delivered a 4.37% better particle removing performance and 11.1 dB less noise generation than the previous shape. The outcomes of this research are the suitable shape of the SH and the research methodology which enabled the application of both CFD and experiments to solve the issue to help enhance the efficiency of the cleaning process in an actual factory.
The Blessing of Whiteness in the Curse of Ham: Reading Gen 9:18–29 in the Antebellum South
Authors: Park Wongi
Published: October 2021

This essay examines the antebellum history of interpretation surrounding the curse of Ham in Gen 9:18–29. It explores how modern notions of scientific racism were read into the story as a de facto justification for the transatlantic slave trade and the institution of slavery in the antebellum South. However, more than simply being used as a prooftext for racist agendas, the curse of Ham provided a biblical foil for circumscribing a racial hierarchy where whiteness was positioned as superior in the figure of Japheth. By considering key features of the racist antebellum interpretation, I argue that the proslavery rationalization of Christian antebellum writers is rooted in a deracialized whiteness that was biblically produced and blessed with divine authority.
Comparison of Low-Cost Commercial Unpiloted Digital Aerial Photogrammetry to Airborne Laser Scanning across Multiple Forest Types in California, USA
Authors: Lamping James E. , Zald Harold S. J. , Madurapperuma Buddhika D. , Graham Jim
Published: October 2021

Science-based forest management requires quantitative estimation of forest attributes traditionally collected via sampled field plots in a forest inventory program. Three-dimensional (3D) remotely sensed data such as Light Detection and Ranging (lidar), are increasingly utilized to supplement and even replace field-based forest inventories. However, lidar remains cost prohibitive for smaller areas and repeat measurements, often limiting its use to single acquisitions of large contiguous areas. Recent advancements in unpiloted aerial systems (UAS), digital aerial photogrammetry (DAP) and high precision global positioning systems (HPGPS) have the potential to provide low-cost time and place flexible 3D data to support forest inventory and monitoring. The primary objective of this study was to assess the ability of low-cost commercial off the shelf UAS DAP and HPGPS to create accurate 3D data and predictions of key forest attributes, as compared to both lidar and field observations, in a wide range of forest conditions in California, USA. A secondary objective was to assess the accuracy of nadir vs. off-nadir UAS DAP, to determine if oblique imagery provides more accurate 3D data and forest attribute predictions. UAS DAP digital terrain models (DTMs) were comparable to lidar DTMS across most sites and nadir vs. off-nadir imagery collection (R2 = 0.74–0.99), although model accuracy using off-nadir imagery was very low in mature Douglas-fir forest (R2 = 0.17) due to high canopy density occluding the ground from the image sensor. Surface and canopy height models were shown to have less agreement to lidar (R2 = 0.17–0.69), with off-nadir imagery surface models at high canopy density sites having the lowest agreement with lidar. UAS DAP models predicted key forest metrics with varying accuracy compared to field data (R2 = 0.53–0.85), and were comparable to predictions made using lidar. Although lidar provided more accurate estimates of forest attributes across a range of forest conditions, this study shows that UAS DAP models, when combined with low-cost HPGPS, can accurately predict key forest attributes across a range of forest types, canopies densities, and structural conditions.
A Safety Warning Algorithm Based on Axis Aligned Bounding Box Method to Prevent Onsite Accidents of Mobile Construction Machineries
Authors: Wang Cynthia Changxin , Wang Mudan , Sun Jun , Mojtahedi Mohammad
Published: October 2021

Mobile construction machineries are accident-prone on a dynamic construction site, as the site environment is constantly changing and continuous safety monitoring by human beings is impossible. These accidents usually happen in the form of machinery overturning or collapsing into risk areas, including the foundation pit, slopes, or soft soil area. Therefore, preventing mobile construction machineries from entering risk areas is the key. However, currently, there is a lack of practical safety management techniques to achieve this. Utilizing a wireless sensor device to collect the location information of mobile construction machineries, this research develops a safety warning algorithm to prevent the machineries moving into risk area and reduces onsite overturning or collapsing accidents. A modified axis aligned bounding box method is proposed according to the movement patterns of mobile construction machineries, and the warning algorithm is developed based on the onsite safety management regulations. The algorithm is validated in a real case simulation when machinery enters the warning zone. The simulation results showed that the overall algorithm combining the location sensing technology and the modified bounding box method could detect risk and give warnings in a timely manner. This algorithm can be implemented for the safety monitoring of mobile construction machineries in daily onsite management.
Immigration Policy and State Power
Authors: Maccanico Yasha Daniel
Published: October 2021

An analysis of 20 years of official documents (1995–2014) and legislative acts at national and EU levels using Jessop’s Strategic Relational Approach (SRA) offers insights into inherent structural flaws in the Justice and Home Affairs aspects of European and member state migration policies. Focusing on two triptychs (hierarchy, governance and government; state power(s), strategic selectivities and structures) and tracking their development clarifies that this policy field’s purposes stray beyond migration management. In fact, the EU migration policy model was set up to be inherently expansive and is intimately linked to EU institutions and national governments striving to enhance their power(s). This is why apparent aberrations and unlawful acts by states amounting to a power grab have developed into an attack against normative frameworks including human rights. This article investigates whether European approaches to immigration policy at the EU and national levels currently pose a problem in terms of state power and authoritarianism due to inherently expansive tendencies and the serial production of problems and hierarchies. It offers a methodological, state-theoretical contribution to address a policy fix in which the EU and its member states appear caught, with harmful effects that spread beyond EU borders through externalisation.
Gum Arabic Production and Population Status of Senegalia senegal (L.) Britton in Dryland Forests in South Omo Zone, Ethiopia
Authors: Zeleke Gizachew , Dejene Tatek , Tadesse Wubalem , Martín-Pinto Pablo
Published: October 2021

Senegalia senegal (L.) Britton is a multi-purpose dryland tree species that produces gum arabic, a commercially valuable product. However, this resource is underused in Ethiopian dryland areas. The aim of this study was to evaluate the population status and potential gum yield of S. senegal growing in natural stands in South Omo Zone, Ethiopia. Forty-five sample plots, each measuring 20 × 20 m, were established at 500 m intervals along transects, with 1 m2 subplots located within the main plots to determine regeneration. S. senegal trees with a diameter at breast height of between 2 and 12 cm were most prevalent. Forty-two tree species were associated with S. senegal, of which 16 were gum- and resin-producing species. S. senegal was positively associated with Vachellia tortilis, Senegalia mellifera, Vachellia nilotica, Commiphora edulis, and Dobera glabra. Senegalia senegal comprised approximately 35% of regenerating trees. The maximum gum arabic yield obtained was 3948 g tree−1. Linear models of dendrometric variables indicated that gum arabic yield is better predicted by tree diameter than by height. Despite the limitations of this pioneer survey, the population status and yield potential suggest that gum arabic could be sustainably produced and commercialized in natural stands of S. senegal in the studied dryland areas, providing local communities with supplementary seasonal incomes.