bluuebunny/crossref_metadata_2025 huggingface dataset:
Photoluminescence Quenching of a Novel Electroconductive Poly(propylene thiophenoimine)-co-Poly(ethylenedioxy thiophene) Star Copolymer
Authors: Djoumessi Yonkeu Anne Lutgarde , Ndipingwi Miranda Mengwi , Ikpo Chinwe , Nwambaekwe Kelechi , Yussuf Sodiq , Tesfay Hayelom , Iwuoha Emmanuel
Published: December 2020

A generation 1 poly(propylene thiophenoimine)-co-poly(ethylenedioxy thiophene) (G1PPT-co-PEDOT) star copolymer, which exhibits a strong optical absorption over a broad range in the ultraviolet–visible (UV-Vis) region and with good electro/conductive properties, was chemically prepared for the first time. Synthesis of the star copolymer, G1PPT-co-PEDOT was confirmed by spectroscopic studies. Indeed, the disappearance of the very high intensity bands, C–H bending at α-position (687 cm−1), and C=N stretching (1620 cm−1) in the Fourier transform infrared spectroscopy (FTIR) of G1PPT-co-PEDOT, which were initially present in the spectrum of the thiolated starting material, G1PPT, confirmed copolymerization. Furthermore, a large bathochromic shift in the onset wavelength of the UV-Vis absorbance spectra from 367 nm in G1PPT to 674 nm in G1PPT-co-PEDOT further attests of successful copolymerization. The electrochemical analysis of G1PPT-co-PEDOT achieved a highest occupied molecular orbital (HOMO) energy level value of 5.3 eV, which is reminiscent of the value for an ideal electron-donor material. Photoluminescence quenching of up to 82% was observed in solution blends of the G1PPT-co-PEDOT star copolymer and N,N′-diisopropyl naphthalene diimide (NDI). This demonstrates the occurrence of photoinduced intermolecular charge transfer (PICT) from the electron-donating G1PPT-co-PEDOT to the electron accepting NDI, a good property, beneficial for optoelectronic and photovoltaic applications.
Effect of Chemical Treatment and Length of Raffia Fiber (Raphia vinifera) on Mechanical Stiffening of Polyester Composites
Authors: Oliveira Filho Edwillson , Luz Fernanda , Fujiyama Roberto , Silva Alisson , Candido Verônica , Monteiro Sergio
Published: December 2020

In recent decades, the unique characteristics of natural fibers have promoted their use as reinforcement in polymeric composites. This is verified in several industrial sectors, from packaging to automotive and civil construction. Among the natural fibers, the raffia fiber extracted from the palm tree Raphia vinifera and introduced in the Amazon region a long time ago; started to be considered for the production of polymeric composites only in recent years. For the first time, the effect of raffia fiber length and its alkali treatment on the mechanical properties of a polymer composite was disclosed. Tensile tests were performed in composites with raffia fibers randomly dispersed into terephthalate-based unsaturated polyester resin. The results showed an increase in the Young’s moduli, confirmed by ANOVA, for the composite with both untreated and alkali-treated fibers in comparison to the plain polyester, which characterizes a stiffening effect. The composites with alkali treated fibers exhibited similar tensile strength values for all lengths; however, their strengths are lower than those for the untreated condition due to a weak raffia fiber/polyester matrix adhesion. Therefore, this work fills the current knowledge gap on raffia fiber incorporation in polyester matrix and valorizes this abundant Brazilian resource, providing additional information towards the use of raffia fiber in polymer composites.
Effect of Over-Etching and Prolonged Application Time of a Universal Adhesive on Dentin Bond Strength
Authors: Burrer Phoebe , Dang Hoang , Par Matej , Attin Thomas , Tauböck Tobias T.
Published: December 2020

This study investigated the effect of over-etching and prolonged application time of a universal adhesive on dentin bond strength. Ninety extracted human molars were ground to dentin and randomly allocated into nine groups (G1–9; n = 10 per group), according to the following acid etching and adhesive application times. In the control group (G1), phosphoric acid etching was performed for 15 s followed by application of the universal adhesive Scotchbond Universal (3M) for 20 s, as per manufacturer’s instructions. In groups G2–5, both the etching and adhesive application times were either halved, doubled, quadrupled, or increased eightfold. In groups G6–9, etching times remained the same as in G2–5 (7.5 s, 30 s, 60 s, and 120 s, respectively), but the adhesive application time was set at 20 s as in the control group (G1). Specimens were then restored with a nanofilled composite material and subjected to microtensile bond strength testing. Bond strength data were statistically analyzed by ANOVA and Tukey’s post-hoc tests (α = 0.05). The relationship of bond strength with etching and adhesive application time was examined using linear regression analysis. Treatment of dentin with halved phosphoric acid etching and adhesive application times (G2) resulted in a significant bond strength decrease compared to the control group (G1) and all other test groups, including the group with halved acid etching, but 20 s of adhesive application time (G6). No significant differences in bond strength were found for groups with multiplied etching times and an adhesive application time of 20 s or more, when compared to the control group (G1). In conclusion, a universal adhesive application time of at least 20 s is recommended when bonding to over-etched dentin.
Development and Evaluation of Polymeric Nanosponge Hydrogel for Terbinafine Hydrochloride: Statistical Optimization, In Vitro and In Vivo Studies
Authors: Ghose Aditee , Nabi Bushra , Rehman Saleha , Md Shadab , Alhakamy Nabil A. , Ahmad Osama A. A. , Baboota Sanjula , Ali Javed
Published: December 2020

Terbinafine hydrochloride, although one of the prominent antifungal agents, suffers from low drug permeation owing to its hydrophobic nature. The approach of nanosponge formulation may thus help to resolve this concern. Thus, the present research was envisioned to fabricate the nanosponge hydrogel of terbinafine hydrochloride for topical delivery since nanosponge augments the skin retentivity of the drug. The optimized formulation was obtained using Box Behnken Design. The dependent and independent process parameters were also determined wherein polyvinyl alcohol (%), ethylcellulose (%), and tween 80 (%) were taken as independent process parameters and particle size, polydispersity index (PDI), and entrapment efficiency (EE) were the dependent parameters. The nanosponge was then incorporated into the hydrogel and characterized. In-vitro drug release from the hydrogel was 90.20 ± 0.1% which was higher than the drug suspension and marketed formulation. In vitro permeation potential of the developed formulation through rat skin showed a flux of 0.594 ± 0.22 µg/cm2/h while the permeability coefficient was 0.059 ± 0.022 cm/s. Nanosponge hydrogel was evaluated for non-irritancy and antifungal activity against C. albicans and T. rubrum confirming the substantial outcome. Tape stripping studies exhibited ten times stripping off the skin quantified 85.6 ± 0.21 μg/cm2. The confocal analysis justified the permeation potential of the prepared hydrogel. The mean erythemal score was 0.0, confirming that the prepared hydrogel did not cause erythema or oedema. Therefore, based on results obtained, nanosponge hydrogel formulation is a potential carrier for efficient topical delivery of terbinafine hydrochloride.
An Investigation of the Influence of PEG 400 and PEG-6-Caprylic/Capric Glycerides on Dermal Delivery of Niacinamide
Authors: Zhang Yanling , Lane Majella E. , Moore David J.
Published: December 2020

Polyethylene glycols (PEGs) and PEG derivatives are used in a range of cosmetic and pharmaceutical products. However, few studies have investigated the influence of PEGs and their related derivatives on skin permeation, especially when combined with other solvents. Previously, we reported niacinamide (NIA) skin permeation from a range of neat solvents including propylene glycol (PG), Transcutol® P (TC), dimethyl isosorbide (DMI), PEG 400 and PEG 600. In the present work, binary and ternary systems composed of PEGs or PEG derivatives combined with other solvents were investigated for skin delivery of NIA. In vitro finite dose studies were conducted (5 μL/cm2) in porcine skin over 24 h. Higher skin permeation of NIA was observed for all vehicles compared to PEG 400. However, overall permeation for the binary and ternary systems was comparatively low compared with results for PG, TC and DMI. Interestingly, values for percentage skin retention of NIA for PEG 400:DMI and PEG 400:TC were significantly higher than values for DMI, TC and PG (p < 0.05). The findings suggest that PEG 400 may be a useful component of formulations for the delivery of actives to the skin rather than through the skin. Future studies will expand the range of vehicles investigated and also look at skin absorption and residence time of PEG 400 compared to other solvents.
Production of Polyhydroxybutyrate (PHB) and Factors Impacting Its Chemical and Mechanical Characteristics
Authors: McAdam Blaithín , Brennan Fournet Margaret , McDonald Paul , Mojicevic Marija
Published: December 2020

Plastic pollution is fueling the grave environmental threats currently facing humans, the animal kingdom, and the planet. The pursuit of renewable resourced biodegradable materials commenced in the 1970s with the need for carbon neutral fully sustainable products driving important progress in recent years. The development of bioplastic materials is highlighted as imperative to the solutions to our global environment challenges and to the restoration of the wellbeing of our planet. Bio-based plastics are becoming increasingly sustainable and are expected to substitute fossil-based plastics. Bioplastics currently include both, nondegradable and biodegradable compositions, depending on factors including the origins of production and post-use management and conditions. Among the most promising materials being developed and evaluated is polyhydroxybutyrate (PHB), a microbial bioprocessed polyester belonging to the polyhydroxyalkanoate (PHA) family. This biocompatible and non-toxic polymer is biosynthesized and accumulated by a number of specialized bacterial strains. The favorable mechanical properties and amenability to biodegradation when exposed to certain active biological environments, earmark PHB as a high potential replacement for petrochemical based polymers such as ubiquitous high density polyethylene (HDPE). To date, high production costs, minimal yields, production technology complexities, and difficulties relating to downstream processing are limiting factors for its progression and expansion in the marketplace. This review examines the chemical, mechanical, thermal, and crystalline characteristics of PHB, as well as various fermentation processing factors which influence the properties of PHB materials.
Influence of Fluorine Substitution on the Optical, Thermal, Electrochemical and Structural Properties of Carbazole-Benzothiadiazole Dicarboxylic Imide Alternate Copolymers
Authors: R. Murad Ary , Iraqi Ahmed , Aziz Shujahadeen B. , Hi Hunan , N. Abdullah Sozan , Brza M. A. , Abdulwahid Rebar T.
Published: December 2020

In this work four novel donor-acceptor copolymers, PCDTBTDI-DMO, PCDTBTDI-8, P2F-CDTBTDI-DMO and P2F-CDTBTDI-8, were designed and synthesised via Suzuki polymerisation. The first two copolymers consist of 2,7-carbazole flanked by thienyl moieties as the electron donor unit and benzothiadiazole dicarboxylic imide (BTDI) as electron acceptor units. In the structures of P2F-CDTBTDI-DMO and P2F-CDTBTDI-8 copolymers, two fluorine atoms were incorporated at 3,6-positions of 2,7-carbazole to investigate the impact of fluorine upon the optoelectronic, structural and thermal properties of the resulting polymers. P2F-CDTBTDI-8 possesses the highest number average molecular weight (Mn = 24,200 g mol−1) among all the polymers synthesised. PCDTBTDI-DMO and PCDTBTDI-8 show identical optical band gaps of 1.76 eV. However, the optical band gaps of fluorinated copolymers are slightly higher than non-fluorinated counterparts. All polymers have deep-lying highest occupied molecular orbital (HOMO) levels. Changing the alkyl chain substituents on BTDI moieties from linear n-octyl to branched 3,7-dimethyloctyl groups as well as substituting the two hydrogen atoms at 3,6-positions of carbazole unit by fluorine atoms has negligible impact on the HOMO levels of the polymers. Similarly, the lowest unoccupied molecular orbital (LUMO) energy levels are almost comparable for all polymers. Thermogravimetric analysis (TGA) has shown that all polymers have good thermal stability and also confirmed that the fluorinated copolymers have higher thermal stability relative to those non-fluorinated analogues. Powder X-ray diffraction (XRD) studies proved that all polymers have an amorphous nature in the solid state.
Effect of Iron Oxide Nanoparticles on the Physical Properties of Medium Density Fiberboard
Authors: Gul Waheed , Alrobei Hussein , Shah Syed Riaz Akbar , Khan Afzal
Published: December 2020

This paper investigates the influence of iron oxide (Fe2O3) nanoparticles on the physical properties of medium density fiberboard (MDF). In this study, three different nano iron oxide loadings, i.e., 0.5, 1.5 and 2.5 wt %, and untreated poplar fibers were used. The iron oxide (Fe2O3) nanoparticles were initially dispersed into urea formaldehyde resin using a high-vacuum mechanical stirrer before being incorporated into natural fibers. The untreated poplar fibers were wound onto metal frames to produce dry mat layers. Twenty different composite samples were made. All composite samples were tested for physical properties, i.e., thickness swelling, water absorption, moisture content and density in accordance with standards EN-317, ASTM D570, EN-322 and EN-323 respectively. Based on the results, it was found that the incorporation of homogeneously dispersed iron oxide nanoparticles significantly improved thickness swelling (Ts). Moreover, water absorption (WA) improved by up to 49.18 and 34.54%, respectively, at the highest loading of 2.5 wt %. Microstructure was investigated and characterized with scanning electron microscopy (SEM), x-ray diffraction (XRD) and energy dispersive spectroscopy (EDS) and we examined whether iron oxide nanoparticles exhibit good interactions with urea formaldehyde and poplar wood fibers. Heat and mass transfer investigation in the form of differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) was carried out due to the impact of Fe2O3 nanoparticles. The curing temperature and thermal stability of the resin were enhanced due to the addition of Fe2O3 nanoparticles. A one-way ANOVA statistical analysis was established to effectively control the use of Fe2O3 nanoparticles. Therefore, the presence of iron oxide nanoparticles in an epoxy polymer contributes to a stiffer matrix that, effectively, enhances the capability of improving the physical properties of nano MDF.
Probing Effect of Papirindustriens Forskningsinstitut (PFI) Refining on Aggregation Structure of Cellulose: Crystal Packing and Hydrogen-Bonding Network
Authors: Li Kunpeng , Zhao Lihong , He Beihai
Published: December 2020

Supramolecular structure is the critical factor that affects the properties of cellulosic fibers. This article studied the action of Papirindustriens forskningsinstitut (PFI) refining on the molecular aggregation and hydrogen bonding network, and tried to explore the relationship between the crystal packing and hydrogen-bonding network in cellulosic fibers. The results showed that the polymorph, H-bonding distance, and H-bonding energy of various H-bonds remained almost unchanged, while the crystalline index, crystallite size, and content of various H-bonds changed with refining. Therein, the content of the inter-molecular O(6)H⋯O(3′) H-bonds was significantly correlated with the crystalline index that was obtained in intensities of the XRD peaks. The Pearson correlation coefficient between them was 0.888 (p < 0.05) for softwood fibers and 0.889 (p < 0.05) for hardwood fibers, respectively. It can be concluded that the variations of accessibility, swelling, and fibrillation were closely related to the supramolecular structure and the intermolecular H-bonds play an important role in the crystal packing of cellulose.
Recyclable Organocatalyzed Poly(Thiourethane) Covalent Adaptable Networks
Authors: Gamardella Francesco , Muñoz Sara , De la Flor Silvia , Ramis Xavier , Serra Angels
Published: December 2020

A new type of tetraphenylborate salts derived from highly basic and nucleophilic amines, namely 1,5-diazabicyclo[4.3.0]non-5-ene (DBN), 1,8-diazabicyclo(5.4.0)undec-7-ene (DBU) and triazabicyclodecene (TBD), was applied to the preparation of networked poly(thiourethane)s (PTUs), which showed a vitrimer-like behavior, with higher stress-relaxation rates than PTUs prepared by using dibutyl thin dilaurate (DBTDL) as the catalyst. The use of these salts, which release the amines when heated, instead of the pure amines, allows the formulation to be easily manipulated to prepare any type of samples. The materials prepared from stoichiometric mixtures of hexamethylene diisocyanate (HDI), trithiol (S3) and with a 10% of molar excess of isocyanate or thiol were characterized by FTIR, thermomechanical analysis, thermogravimetry, stress-relaxation tests and tensile tests, thus obtaining a complete thermal and mechanical characterization of the materials. The recycled materials obtained by grinding the original PTUs and hot-pressing the small pieces in the optimized time and temperature conditions were fully characterized by mechanical, thermomechanical and FTIR studies. This allowed us to confirm their recyclability, without appreciable changes in the network structure and performance. From several observations, the dissociative interchange trans-thiocarbamoylation mechanism was evidenced as the main responsible of the topological rearrangements at high temperature, resulting in a vitrimeric-like behavior.
Arundo donax Refining to Second Generation Bioethanol and Furfural
Authors: De Bari Isabella , Liuzzi Federico , Ambrico Alfredo , Trupo Mario
Published: December 2020

Biomass-derived sugars are platform molecules that can be converted into a variety of final products. Non-food, lignocellulosic feedstocks, such as agroforest residues and low inputs, high yield crops, are attractive bioresources for the production of second-generation sugars. Biorefining schemes based on the use of versatile technologies that operate at mild conditions contribute to the sustainability of the bio-based products. The present work describes the conversion of giant reed (Arundo donax), a non-food crop, to ethanol and furfural (FA). A sulphuric-acid-catalyzed steam explosion was used for the biomass pretreatment and fractionation. A hybrid process was optimized for the hydrolysis and fermentation (HSSF) of C6 sugars at high gravity conditions consisting of a biomass pre-liquefaction followed by simultaneous saccharification and fermentation with a step-wise temperature program and multiple inoculations. Hemicellulose derived xylose was dehydrated to furfural on the solid acid catalyst in biphasic media irradiated by microwave energy. The results indicate that the optimized HSSF process produced ethanol titers in the range 43–51 g/L depending on the enzymatic dosage, about 13–21 g/L higher than unoptimized conditions. An optimal liquefaction time before saccharification and fermentation tests (SSF) was 10 h by using 34 filter paper unit (FPU)/g glucan of Cellic® CTec3. C5 streams yielded 33.5% FA of the theoretical value after 10 min of microwave heating at 157 °C and a catalyst concentration of 14 meq per g of xylose.
Distributed Model Predictive Control Applied to a Sewer System
Authors: Cembellín Antonio , Francisco Mario , Vega Pastora
Published: December 2020

In this work, a Distributed Model Predictive Control (MPC) methodology with fuzzy negotiation among subsystems has been developed and applied to a simulated sewer network. The wastewater treatment plant (WWTP) receiving this wastewater has also been considered in the methodology by means of an additional objective for the problem. In order to decompose the system into interconnected local subsystems, sectorization techniques have been applied based on structural analysis. In addition, a dynamic setpoint generation method has been added to improve system performance. The results obtained with the proposed methodology are compared to those obtained with standard centralized and decentralized model predictive controllers.
Theology of Supernatural
Authors: Nosachev Pavel
Published: December 2020

The main research issues of the article are the determination of the genesis of theology created in Supernatural and the understanding of ways in which this show transforms a traditional Christian theological narrative. The methodological framework of the article, on the one hand, is the theory of the occulture (C. Partridge), and on the other, the narrative theory proposed in U. Eco’s semiotic model. C. Partridge successfully described modern religious popular culture as a coexistence of abstract Eastern good (the idea of the transcendent Absolute, self-spirituality) and Western personified evil. The ideal confirmation of this thesis is Supernatural, since it was the bricolage game with images of Christian evil that became the cornerstone of its popularity. In the 15 seasons of its existence, Supernatural, conceived as a story of two evil-hunting brothers wrapped in a collection of urban legends, has turned into a global panorama of world demonology while touching on the nature of evil, the world order, theodicy, the image of God, etc. In fact, this show creates a new demonology, angelology, and eschatology. The article states that the narrative topics of Supernatural are based on two themes, i.e., the theology of the spiritual war of the third wave of charismatic Protestantism and the occult outlooks derived from Emmanuel Swedenborg’s system. The main topic of this article is the role of monotheistic mythology in Supernatural. The author concludes that the case of Supernatural shows how the classical monotheistic narrative, in its orthodox and heterodox formats, is hugely attractive for the modern audience. A wide distribution of the occulture that has become a basis of modern mass culture and easily combines, by virtue of historical specifics of its genesis, with monotheism makes the classical monotheistic mythology more flexible and capable of meeting the audience’s different demands.
Starting a Participative Approach to Develop Local Green Infrastructure; from Boundary Concept to Collective Action
Authors: Smets Jasmien , De Blust Geert , Verheyden Wim , Wanner Saskia , Van Acker Maarten , Turkelboom Francis
Published: December 2020

Flanders (Belgium) is one of the most densely populated regions in Europe. Intensive land use, widespread suburbanization, inadequate environmental qualities, and fragmentation everywhere deteriorate living conditions and put pressure on species and natural habitats. In the past, several governmental initiatives were launched to establish a coherent ecological network to improve the situation. Despite the set objectives, only a little progress was made. Therefore, to establish green infrastructure, a new approach that moves away from previous top-down and one-sided strategies is developed. Making use of Green Infrastructure as a boundary concept, interpretation was given through an open and participatory process. The core is the identification of common objectives (ecosystem services or other objectives/services), the selection of appropriate green infrastructure elements to support the services, and the co-design of a network taking the local socio-ecological realm into account. By applying the methodology in concrete urban and rural projects, we learned that establishing strong coalitions of stakeholders, obtaining and sharing reliable knowledge of the systems are key to an effective realization of green infrastructure.
Post Energy Audit of Two Mosques as a Case Study of Intermittent Occupancy Buildings: Toward more Sustainable Mosques
Authors: EL Fouih Younness , Allouhi Amine , Abdelmajid Jamil , Kousksou Tarik , Mourad Youssef
Published: December 2020

Mosques are buildings with a unique occupancy schedule and special energy and water consumption scheme. Generally, this type of buildings lacks the application of energy efficiency solutions and sustainable guidelines during the conception, construction and the operation phase. Interestingly, these iconic edifices can play a key role in raising awareness for sustainability and promoting cleaner energy technologies. The first aim of this work is to present energy audit results, recommended energy savings solutions for two historical mosques in Marrakech (Morocco). A detailed discussion of the adopted solutions is presented and an economic assessment was performed. Then, a two-year energy savings evaluation was conducted for the two mosques. Conclusions about the adequacy of the proposed solutions is presented. The second part is dedicated to outline some guidelines and sustainable criteria to consider for establishing an international sustainable mosques label. The creation of a such sustainable label will encourage spreading sustainable best practices in mosques and other types of buildings. It will also help to compare sustainable performances of different mosques around the world by establishing an adapted sustainable rating system.
A Review of Funding Mechanisms for US Floodplain Buyouts
Authors: Peterson Kelsey , Apadula Emily , Salvesen David , Hino Miyuki , Kihslinger Rebecca , BenDor Todd K.
Published: December 2020

Increases in extreme weather events have caused extensive flooding across the United States. In response, federal, state, and local governments have broadened their flood mitigation strategies to include acquisition and demolition of flood-damaged homes (“buyouts”). Little work has documented or analyzed the range of strategies for funding buyouts. Federal programs provide the bulk of funding, but these programs are often slow. Also, state and local governments struggle to meet cost-match requirements. We present and analyze a nationwide census of buyout funding programs (n = 34), which draw on five primary funding mechanisms. We find that state and local governments are using a range of traditional and innovative financial mechanisms, including municipal/green bonds, revolving loan funds, local option sales taxes, and stormwater utility fees, as viable tools for funding buyouts. These tools may promote more autonomy from federal government mitigation programs, and ultimately, faster buyout processes.
Development and Validation of a Roadmap to Assist the Performance-Based Early-Stage Design Process of Adaptive Opaque Facades
Authors: Juaristi Miren , Konstantinou Thaleia , Gómez-Acebo Tomás , Monge-Barrio Aurora
Published: December 2020

Adaptive Opaque Facades (AOF) is an innovative concept with potential to achieve low carbon energy buildings. However, so far AOF are not integrated in the construction industry. One remarkable issue that designers have when dealing with alternative low-carbon technologies, such as AOF, is the absence of previous built experiences and the lack of specialised technical knowledge. Design roadmaps can be convenient solutions to guide pioneer low carbon technology applications. This work presents a roadmap to assist the performance-based early-stage design process of Adaptive Opaque Facades. Previous research developed new approaches and tools to assist on the construction definition of AOF, so that their adaptive thermal performance was considered when specific design decisions needed to be made. The roadmap presented in this paper organises the implementation sequence of each methodological approach and tools in different design stages, which aims to provide a holistic design approach for AOF. The usability of the roadmap was validated in a workshop called “Performance-based Design and Assessment of Adaptive Facades” with master students representing the target group of this roadmap. Even though these students had never heard about AOF before, they could successfully design, define the early-stage characteristics of an AOF and quantify the thermal performance of their AOF designs. The roadmap was proven to be a useful support, which might make the implementation of AOF more approachable in the future.
The Indoor Microclimate of Prefabricated Buildings for Housing: Interaction of Environmental and Construction Measures
Authors: Kubečková Darja , Kraus Michal , Šenitková Ingrid Juhásová , Vrbová Magdaléna
Published: December 2020

The current knowledge shows that the interior microclimate of residential buildings that were constructed between 1950 and 1990 using panel construction, not only in the Czech Republic but also in Europe, and were renovated in accordance with applicable legislation related to thermal comfort and energy is significantly affected by gaseous pollutants. At increased concentrations and exposure times, these pollutants negatively affect the interior microclimate and at the same time have a negative effect on the health of users. After the implementation of remediation measures, which are mainly focused on improving the thermal technical parameters of the building envelope, the concentration of CO2 in the indoor environment increases. Carbon dioxide is one of the most important active factors and in terms of the quality of the interior microclimate, it is considered a reliable indicator of whether the interior microclimate can be considered a healthy and favorable environment. It is thus clear that the set and de facto systematized measures in the renovation of the housing stock from the second half of the 20th century has led to energy savings on the one hand, but on the other hand, this has contributed to the hygienic damage of housing units and an unhealthy interior microclimate. The paper aims to define the interaction of interdisciplinary contexts that have led to an increase in the indoor air quality (IAQ) of renovated residential panel buildings.
Self-Perception of the Digital Competence of Educators during the COVID-19 Pandemic: A Cross-Analysis of Different Educational Stages
Authors: Portillo Javier , Garay Urtza , Tejada Eneko , Bilbao Naiara
Published: December 2020

The objective of this research is to measure the perception that teachers had about their own performance when they were forced to carry out Emergency Remote Teaching due to the COVID-19 pandemic. A questionnaire was provided to teachers of every educational stage in the Basque Country (Pre-school, Primary and Secondary Education, Professional Training, and Higher Education) obtaining a total of 4586 responses. The statistical analysis of the data shows that the greatest difficulties reported by educators are shortcomings in their training in digital skills, which has made them perceive a higher workload during the lockdown along with negative emotions. Another finding is the existing digital divide between teachers based on their gender, age, and type of school. A further worrying result is the lower technological competence at lower educational levels, which are the most vulnerable in remote teaching. These results invite us to reflect on the measures to be taken to improve equity, social justice, and the resilience of the educational system, which align with some of the Sustainable Development Goals.
Towards Sustainable Mining in the Didactic Process—MEITIM Project as an Opportunity to Increase the Attractiveness of Mining Courses (A Case Study of Poland)
Authors: Adach-Pawelus Karolina , Gogolewska Anna , Górniak-Zimroz Justyna , Herrera Herbert Juan , Hidalgo Arturo , Kiełczawa Barbara , Krupa-Kurzynowska Joanna , Lampinen Matti , Mamelkina Maria A. , Paszkowska Gabriela , Szyszka Danuta , Tuunila Ritva , Worsa-Kozak Magdalena , Woźniak Justyna
Published: December 2020

Mining has been embedded in the public consciousness as a dirty, non-innovative, outdated and environmentally harmful industry. Proper education, especially the academic one, becomes crucial to successfully change this image. This article depicts the initial assumptions of the international project Master in Entrepreneurship, Innovation and Technology Integration in Mining (MEITIM), co-financed by EIT Raw Materials, that aims to diagnose the current state of Polish higher education in the field of mining at, among others, the Wroclaw University of Science and Technology (WUST), concerning the experience of the Technical University of Madrid (UPM) and Lappeenranta University of Technology (LUT). The MEITIM project allowed identifying the directions of necessary changes in the didactic process as an indispensable set of skills and knowledge for a future mining graduate. Such activities are dictated by many guidelines and arrangements, among others, at the level of the European Commission or key industry institutions such as the International Council on Mining and Metals. These are key competencies that require significant changes in university curricula supporting sustainable development goals in innovative mining. The authors show that there is a link between the condition of the mining industry in Poland, its reputation, and the number of people who want to study mining.
Optimal Transport with Dimensionality Reduction for Domain Adaptation
Authors: Li Ping , Ni Zhiwei , Zhu Xuhui , Song Juan , Wu Wenying
Published: December 2020

Domain adaptation manages to learn a robust classifier for target domain, using the source domain, but they often follow different distributions. To bridge distribution shift between the two domains, most of previous works aim to align their feature distributions through feature transformation, of which optimal transport for domain adaptation has attract researchers’ interest, as it can exploit the local information of the two domains in the process of mapping the source instances to the target ones by minimizing Wasserstein distance between their feature distributions. However, it may weaken the feature discriminability of source domain, thus degrade domain adaptation performance. To address this problem, this paper proposes a two-stage feature-based adaptation approach, referred to as optimal transport with dimensionality reduction (OTDR). In the first stage, we apply the dimensionality reduction with intradomain variant maximization but source intraclass compactness minimization, to separate data samples as much as possible and enhance the feature discriminability of the source domain. In the second stage, we leverage optimal transport-based technique to preserve the local information of the two domains. Notably, the desirable properties in the first stage can mitigate the degradation of feature discriminability of the source domain in the second stage. Extensive experiments on several cross-domain image datasets validate that OTDR is superior to its competitors in classification accuracy.
Anthropometric Landmarks Extraction and Dimensions Measurement Based on ResNet
Authors: Wang Xun , Liu Baohua , Dong Yukun , Pang Shanchen , Tao Xixi
Published: December 2020

Anthropometric dimensions can be acquired in 2D images by landmarks. Body shape variance causes low accuracy and bad robustness of landmarks extracted, and it is difficult to determine the position of axis division point when dimensions are calculated by the ellipse model. In this paper, landmarks are extracted from images by convolutional neural network instead of the gradient of body outline. A general multi-ellipse model is proposed, the anthropometric dimensions are obtained from the length of different elliptical segments and the position of axis division point is determined by thickness–width ratio of body parts. Finally, an evaluation is completed based on 87 subjects, in which it turns out that the average accuracy of our method for identifying landmarks is 96.6%, when the number of rotation angles is 2, the three main dimensional errors calculated by our model are smaller than existing method, and the errors of other dimensions are also within the margin of error for garment measuring.
Rational Approximation on Exponential Meshes
Authors: Amato Umberto , Della Vecchia Biancamaria
Published: December 2020

Error estimates of pointwise approximation, that are not possible by polynomials, are obtained by simple rational operators based on exponential-type meshes, improving previous results. Rational curves deduced from such operators are analyzed by Discrete Fourier Transform and a CAGD modeling technique for Shepard-type curves by truncated DFT and the PIA algorithm is developed.
Multi-Mycotoxin Occurrence in Dairy Cattle and Poultry Feeds and Feed Ingredients from Machakos Town, Kenya
Authors: Kemboi David Chebutia , Ochieng Phillis E. , Antonissen Gunther , Croubels Siska , Scippo Marie-Louise , Okoth Sheila , Kangethe Erastus K. , Faas Johannes , Doupovec Barbara , Lindahl Johanna F. , Gathumbi James K.
Published: December 2020

Mycotoxins are common in grains in sub-Saharan Africa and negatively impact human and animal health and production. This study assessed occurrences of mycotoxins, some plant, and bacterial metabolites in 16 dairy and 27 poultry feeds, and 24 feed ingredients from Machakos town, Kenya, in February and August 2019. We analyzed the samples using a validated multi-toxin liquid chromatography-tandem mass spectrometry method. A total of 153 mycotoxins, plant, and bacterial toxins, were detected in the samples. All the samples were co-contaminated with 21 to 116 different mycotoxins and/or metabolites. The commonly occurring and EU regulated mycotoxins reported were; aflatoxins (AFs) (70%; range 0.2–318.5 μg/kg), deoxynivalenol (82%; range 22.2–1037 μg/kg), ergot alkaloids (70%; range 0.4–285.7 μg/kg), fumonisins (90%; range 32.4–14,346 μg/kg), HT-2 toxin (3%; range 11.9–13.8 μg/kg), ochratoxin A (24%; range 1.1–24.3 μg/kg), T-2 toxin (4%; range 2.7–5.2 μg/kg) and zearalenone (94%; range 0.3–910.4 μg/kg). Other unregulated emerging mycotoxins and metabolites including Alternaria toxins, Aspergillus toxins, bacterial metabolites, cytochalasins, depsipeptides, Fusarium metabolites, metabolites from other fungi, Penicillium toxins, phytoestrogens, plant metabolites, and unspecific metabolites were also detected at varying levels. Except for total AFs, where the average contamination level was above the EU regulatory limit, all the other mycotoxins detected had average contamination levels below the limits. Ninety-six percent of all the samples were contaminated with more than one of the EU regulated mycotoxins. These co-occurrences may cause synergistic and additive health effects thereby hindering the growth of the Kenyan livestock sector.
Development of Genotype-Specific Anti-Bovine Rotavirus A Immunoglobulin Yolk Based on a Current Molecular Epidemiological Analysis of Bovine Rotaviruses A Collected in Japan during 2017–2020
Authors: Odagiri Koki , Yoshizawa Nobuki , Sakihara Hisae , Umeda Koji , Rahman Shofiqur , Nguyen Sa Van , Suzuki Tohru
Published: December 2020

Bovine rotavirus A (RVA), a major causative pathogen of diarrhea in dairy and Japanese beef calves, has led to severe economic losses in numerous countries. A dual genotyping system based on genomic segments encoding VP7 (G genotype) and VP4 (P genotype), comprising the outer layer of the virion, has been used to understand the epidemiological dynamics of RVAs at the national and global levels. This study aimed to investigate occurrence frequency of G and P genotypes for multiple bovine RVAs from calf diarrheic samples collected in Japan from 2017 to 2020. After we produced anti-bovine RVA immunoglobulin yolks (IgYs) from hens immunized with the two RVAs with different genotypes (G6P[5] and G10P[11]) selected on the basis of the current epidemiological survey, we investigated cross-reactivity against bovine RVAs with different G and P combinations owing to establish a useful strategy to protect calves from RVA infections using the two IgYs. Consequently, the two produced anti-bovine IgYs showed strong cross-reactivity against bovine RVAs with the same G and/or P genotypes in neutralization assay, respectively. Therefore, our data suggest the possibility of a passive immunization to protect calves from a bovine RVA infections epidemic in Japan via oral administration of the two IgYs into calves. The findings presented herein will provide important information that IgY is one of the effective tools to prevent infections of various pathogens.
Highly Pathogenic Avian Influenza Clade 2.3.4.4b Subtype H5N8 Virus Isolated from Mandarin Duck in South Korea, 2020
Authors: Jeong Sol , Lee Dong-Hun , Kwon Jung-Hoon , Kim Yu-Jin , Lee Sun-Hak , Cho Andrew Y. , Kim Tae-Hyeon , Park Jung-Eun , Lee Song-I , Song Chang-Seon
Published: December 2020

In October 2020, a highly pathogenic avian influenza (HPAI) subtype H5N8 virus was identified from a fecal sample of a wild mandarin duck (Aix galericulata) in South Korea. We sequenced all eight genome segments of the virus, designated as A/Mandarin duck/Korea/K20-551-4/2020(H5N8), and conducted genetic characterization and comparative phylogenetic analysis to track its origin. Genome sequencing and phylogenetic analysis show that the hemagglutinin gene belongs to H5 clade 2.3.4.4 subgroup B. All genes share high levels of nucleotide identity with H5N8 HPAI viruses identified from Europe during early 2020. Enhanced active surveillance in wild and domestic birds is needed to monitor the introduction and spread of HPAI via wild birds and to inform the design of improved prevention and control strategies.
Efficacy of Whole Cell Inactivated Vibrio harveyi Vaccine against Vibriosis in a Marine Red Hybrid Tilapia (Oreochromis niloticus × O. mossambicus) Model
Authors: Abu Nor Nadirah , Zamri-Saad Mohd , Md Yasin Ina-Salwany , Salleh Annas , Mustaffa-Kamal Farina , Matori Mohd Fuad , Azmai Mohd Noor Amal
Published: December 2020

Vibrio harveyi causes vibriosis in various commercial marine fish species. The infection leads to significant economic losses for aquaculture farms, and vaccination is an alternative approach for the prevention and control of fish diseases for aquaculture sustainability. This study describes the use of formalin-killed Vibrio harveyi (FKVh) strain Vh1 as a vaccine candidate to stimulate innate and adaptive immunities against vibriosis in a marine red hybrid tilapia model. Tilapia are fast growing; cheap; resistant to diseases; and tolerant to adverse environmental conditions of fresh water, brackish water, and marine water and because of these advantages, marine red hybrid tilapia is a suitable candidate as a model to study fish diseases and vaccinations against vibriosis. A total of 180 healthy red hybrid tilapias were gradually adapted to the marine environment before being divided into two groups, with 90 fish in each group and were kept in triplicate with 30 fish per tank. Group 1 was vaccinated intraperitoneally with 100 µL of FKVh on week 0, and a booster dose was similarly administered on week 2. Group 2 was similarly injected with PBS. Skin mucus, serum, and gut lavage were collected weekly for enzyme-linked immunosorbent assay (ELISA) and a lysozyme activity assay from a total of 30 fish of each group. On week 4, the remaining 60 fish of Groups 1 and 2 were challenged with 108 cfu/fish of live Vibrio harveyi. The clinical signs were monitored while the survival rate was recorded for 48 h post-challenge. Vaccination with FKVh resulted in a significantly (p < 0.05) higher rate of survival (87%) compared to the control (20%). The IgM antibody titer and lysozyme activities of Group 1 were significantly (p < 0.05) higher than the unvaccinated Groups 2 in most weeks throughout the experiment. Therefore, the intraperitoneal exposure of marine red hybrid tilapia to killed V. harveyi enhanced the resistance and antibody response of the fish against vibriosis.
Degradation of Losartan in Fresh Urine by Sonochemical and Photochemical Advanced Oxidation Processes
Authors: Guateque-Londoño John F. , Serna-Galvis Efraím A. , Ávila-Torres Yenny , Torres-Palma Ricardo A.
Published: December 2020

In this work, the degradation of the pharmaceutical losartan, in simulated fresh urine (which was considered because urine is the main excretion route for this compound) by sonochemistry and UVC/H2O2 individually, was studied. Initially, special attention was paid to the degrading action of the processes. Then, theoretical analyses on Fukui function indices, to determine electron-rich regions on the pharmaceutical susceptible to attacks by the hydroxyl radical, were performed. Afterward, the ability of the processes to mineralize losartan and remove the phyto-toxicity was tested. It was found that in the sonochemical treatment, hydroxyl radicals played the main degrading role. In turn, in UVC/H2O2, both the light and hydroxyl radical eliminated the target contaminant. The sonochemical system showed the lowest interference for the elimination of losartan in the fresh urine. It was established that atoms in the imidazole of the contaminant were the moieties most prone to primary transformations by radicals. This was coincident with the initial degradation products coming from the processes action. Although both processes exhibited low mineralizing ability toward losartan, the sonochemical treatment converted losartan into nonphytotoxic products. This research presents relevant results on the elimination of a representative pharmaceutical in fresh urine by two advanced oxidation processes.
Prediction of Water Level and Water Quality Using a CNN-LSTM Combined Deep Learning Approach
Authors: Baek Sang-Soo , Pyo Jongcheol , Chun Jong Ahn
Published: December 2020

A Convolutional Neural Network (CNN)-Long Short-Term Memory (LSTM) combined with a deep learning approach was created by combining CNN and LSTM networks simulated water quality including total nitrogen, total phosphorous, and total organic carbon. Water level and water quality data in the Nakdong river basin were collected from the Water Resources Management Information System (WAMIS) and the Real-Time Water Quality Information, respectively. The rainfall radar image and operation information of estuary barrage were also collected from the Korea Meteorological Administration. In this study, CNN was used to simulate the water level and LSTM used for water quality. The entire simulation period was 1 January 2016–16 November 2017 and divided into two parts: (1) calibration (1 January 2016–1 March 2017); and (2) validation (2 March 2017–16 November 2017). This study revealed that the performances of both of the CNN and LSTM models were in the “very good” range with above the Nash–Sutcliffe efficiency value of 0.75 and that those models well represented the temporal variations of the pollutants in Nakdong river basin (NRB). It is concluded that the proposed approach in this study can be useful to accurately simulate the water level and water quality.