bluuebunny/crossref_metadata_2025 huggingface dataset:
Carbon (δ13C) and Nitrogen (δ15N) Stable Isotope Composition Provide New Insights into Phenotypic Plasticity in Broad Leaf Weed Rumex acetosa under Allelochemical Stress
Authors: Hussain M. Iftikhar , Reigosa Manuel J. , Muscolo Adele
Published: September 2018

Phenolic compounds, hydroquinone and cinnamic acid derivatives have been identified as major allelochemicals with known phytotoxicity from allelopathic plant Acacia melanoxylon R. Br. Several phenolic compounds such as ferulic acid (FA), p-hydroxybenzoic acid (pHBA) and flavonoid (rutin, quercetin) constituents occur in the phyllodes and flowers of A. melanoxylon and have demonstrated inhibitory effects on germination and physiological characteristics of lettuce and perennial grasses. However, to date, little is known about the mechanisms of action of these secondary metabolites in broad-leaved weeds at ecophysiological level. The objective of this study was to determine the response of Rumex acetosa carbon isotope composition and other physiological parameters to the interaction of plant secondary metabolites (PSM) (FA and pHBA) stress and the usefulness of carbon isotope discrimination (Δ13C) as indicative of the functional performance of intrinsic water use efficiency (iWUE) at level of plant leaf. R. acetosa plant were grown under greenhouse condition and subjected to PSM stress (0, 0.1, 0.5, 1.0, and 1.5 mM) for six days. Here, we show that FA and pHBA are potent inhibitors of Δ13C that varied from 21.0‰ to 22.9‰. Higher pHBA and FA supply enhanced/retard the Nleaf and increased the Cleaf while ratio of intercellular CO2 concentration from leaf to air (Ci/Ca) was significantly decreased as compared to control. Leaf water content and leaf osmotic potential were decreased following treatment with both PSM. The Ci/Ca decreased rapidly with higher concentration of FA and pHBA. However, iWUE increased at all allelochemical concentrations. At the whole plant level, both PSM showed pronounced growth-inhibitory effects on PBM and C and N concentration, root fresh/dry weight, leaf fresh/dry weight, and root, shoot length of C3 broad leaf weed R. acetosa. Carbon isotope discrimination (Δ) was correlated with the dry matter to transpiration ratio (transpiration efficiency) in this C3 species, but its heritability and relationship to R. acetosa growth are less clear. Our FA and pHBA compounds are the potent and selective carbon isotope composition (δ13C) inhibitors known to date. These results confirm the phytotoxicity of FA and pHBA on R. acetosa seedlings, the reduction of relative water content and the induction of carbon isotope discrimination (Δ) with lower plant biomass.
Synthesis of New 2-Arylbenzo[b]furan Derivatives via Palladium-Catalyzed Suzuki Cross-Coupling Reactions in Aqueous Media
Authors: Chen Qianqian , Jiang Panli , Guo Mengping , Yang Jianxin
Published: September 2018

A series of novel benzofuran derivatives containing biaryl moiety were designed and synthesized by the Suzuki cross-coupling reactions. The reactions, performed in the presence of K2CO3, EtOH/H2O and Pd(II) complex as catalyst, gave the corresponding products in good to excellent yields. The methodology allows the facile production of heterobiaryl compounds, a unique architectural motif that is ubiquitous in medicinal chemistry.
Oligosaccharides Derived from Red Seaweed: Production, Properties, and Potential Health and Cosmetic Applications
Authors: Cheong Kit-Leong , Qiu Hua-Mai , Du Hong , Liu Yang , Khan Bilal Muhammad
Published: September 2018

Because of their potential use as functional ingredients in human nutrition, oligosaccharides derived from natural sources are receiving paramount consideration. Red seaweed, a proven rich source of agar and carrageenan, is one of the most abundantly present sources of such oligosaccharides. Agaro-oligosaccharides (AOS) and carrageenan-oligosaccharides (COS) are produced from agar and carrageenan, respectively, through chemical and enzymatic hydrolyses. Enzymatic hydrolysis of agar and carrageenan into oligosaccharides is preferred in industrial production because of certain problems associated with chemical hydrolysis, including the release of high amounts of monosaccharides and undesirable toxic products, such as furfural. AOS and COS possess many biological activities, including prebiotic, immuno-modulatory, anti-oxidant, and anti-tumor activities. These activities are related to their chemical structure, molecular weight, degree of polymerization, and the flexibility of the glycosidic linkages. Therefore, the structure–function relationship and the mechanisms occurring during the specific biological applications of AOS and COS are discussed herein. Moreover, the chromatographic separation, purification, and characterization of AOS and COS are also part of this review. This piece of writing strives to create a new perspective on the potential applications of AOS and COS in the functional food and pharmaceutical industry.
Discovery of CNS-Like D3R-Selective Antagonists Using 3D Pharmacophore Guided Virtual Screening
Authors: Lee June Hyeong , Cho Sung Jin , Kim Mi-hyun
Published: September 2018

The dopamine D3 receptor is an important CNS target for the treatment of a variety of neurological diseases. Selective dopamine D3 receptor antagonists modulate the improvement of psychostimulant addiction and relapse. In this study, five and six featured pharmacophore models of D3R antagonists were generated and evaluated with the post-hoc score combining two survival scores of active and inactive. Among the Top 10 models, APRRR215 and AHPRRR104 were chosen based on the coefficient of determination (APRRR215: R2training = 0.80; AHPRRR104: R2training = 0.82) and predictability (APRRR215: Q2test = 0.73, R2predictive = 0.82; AHPRRR104: Q2test = 0.86, R2predictive = 0.74) of their 3D-quantitative structure–activity relationship models. Pharmacophore-based virtual screening of a large compound library from eMolecules (>3 million compounds) using two optimal models expedited the search process by a 100-fold speed increase compared to the docking-based screening (HTVS scoring function in Glide) and identified a series of hit compounds having promising novel scaffolds. After the screening, docking scores, as an adjuvant predictor, were added to two fitness scores (from the pharmacophore models) and predicted Ki (from PLSs of the QSAR models) to improve accuracy. Final selection of the most promising hit compounds were also evaluated for CNS-like properties as well as expected D3R antagonism.
Measuring Artificial Sweeteners Toxicity Using a Bioluminescent Bacterial Panel
Authors: Harpaz Dorin , Yeo Loo Pin , Cecchini Francesca , Koon Trish H. P. , Kushmaro Ariel , Tok Alfred I. Y. , Marks Robert S. , Eltzov Evgeni
Published: September 2018

Artificial sweeteners have become increasingly controversial due to their questionable influence on consumers’ health. They are introduced in most foods and many consume this added ingredient without their knowledge. Currently, there is still no consensus regarding the health consequences of artificial sweeteners intake as they have not been fully investigated. Consumption of artificial sweeteners has been linked with adverse effects such as cancer, weight gain, metabolic disorders, type-2 diabetes and alteration of gut microbiota activity. Moreover, artificial sweeteners have been identified as emerging environmental pollutants, and can be found in receiving waters, i.e., surface waters, groundwater aquifers and drinking waters. In this study, the relative toxicity of six FDA-approved artificial sweeteners (aspartame, sucralose, saccharine, neotame, advantame and acesulfame potassium-k (ace-k)) and that of ten sport supplements containing these artificial sweeteners, were tested using genetically modified bioluminescent bacteria from E. coli. The bioluminescent bacteria, which luminesce when they detect toxicants, act as a sensing model representative of the complex microbial system. Both induced luminescent signals and bacterial growth were measured. Toxic effects were found when the bacteria were exposed to certain concentrations of the artificial sweeteners. In the bioluminescence activity assay, two toxicity response patterns were observed, namely, the induction and inhibition of the bioluminescent signal. An inhibition response pattern may be observed in the response of sucralose in all the tested strains: TV1061 (MLIC = 1 mg/mL), DPD2544 (MLIC = 50 mg/mL) and DPD2794 (MLIC = 100 mg/mL). It is also observed in neotame in the DPD2544 (MLIC = 2 mg/mL) strain. On the other hand, the induction response pattern may be observed in its response in saccharin in TV1061 (MLIndC = 5 mg/mL) and DPD2794 (MLIndC = 5 mg/mL) strains, aspartame in DPD2794 (MLIndC = 4 mg/mL) strain, and ace-k in DPD2794 (MLIndC = 10 mg/mL) strain. The results of this study may help in understanding the relative toxicity of artificial sweeteners on E. coli, a sensing model representative of the gut bacteria. Furthermore, the tested bioluminescent bacterial panel can potentially be used for detecting artificial sweeteners in the environment, using a specific mode-of-action pattern.
Phytochemical Profile and Biological Activities of Satureja hortensis L.: A Review of the Last Decade
Authors: Fierascu Irina , Dinu-Pirvu Cristina Elena , Fierascu Radu Claudiu , Velescu Bruno Stefan , Anuta Valentina , Ortan Alina , Jinga Viorel
Published: September 2018

Satureja hortensis L. (summer savory) is an annual herbaceous crop, native to Europe and in our days spread and used all over the world. Although its use as spice and medicinal plant is known since ancient times, peer-reviewed studies presenting the scientific data are scarce. The natural products obtained from summer savory (extracts and essential oil) are dominated by polyphenols and flavonoids, responsible for their antioxidant, antimicrobial, antiparasitic, pesticidal, anti-inflammatory, analgesic, hepatoprotective and anticancer properties, among others. The current study presents the progress made in the last decade regarding the potential applications of summer savory, being the first review study focused on S. hortensis, in the same time suggesting future research opportunities, as they appear from the properties of other Satureja species. The available data presenting the properties of summer savory represents a scientific support for application in industry, for developing “clean label” food products.
Cytotoxic, Genotoxic, and Polymorphism Effects on Vanilla planifolia Jacks ex Andrews after Long-Term Exposure to Argovit® Silver Nanoparticles
Authors: Bello-Bello Jericó Jabín , Spinoso-Castillo José Luis , Arano-Avalos Samantha , Martínez-Estrada Eduardo , Arellano-García María Evarista , Pestryakov Alexey , Toledano-Magaña Yanis , García-Ramos Juan Carlos , Bogdanchikova Nina
Published: September 2018

Worldwide demands of Vanilla planifolia lead to finding new options to produce large-scale and contaminant-free crops. Particularly, the Mexican Government has classified Vanilla planifolia at risk and it subject to protection programs since wild species are in danger of extinction and no more than 30 clones have been found. Nanotechnology could help to solve both demands and genetic variability, but toxicological concerns must be solved. In this work, we present the first study of the cytotoxic and genotoxic effects promoted by AgNPs in Vanilla planifolia plantlets after a very long exposure time of six weeks. Our results show that Vanilla planifolia plantlets growth with doses of 25 and 50 mg/L is favored with a small decrease in the mitotic index. A dose-dependency in the frequency of cells with chromosomal aberrations and micronuclei was found. However, genotoxic effects could be considered as minimum due to with the highest concentration employed (200 mg/L), the total percentage of chromatic aberrations is lower than 5% with only three micronuclei in 3000 cells, despite the long-time exposure to AgNP. Therefore, 25 and 50 mg/L (1.5 and 3 mg/L of metallic silver) were identified as safe concentrations for Vanilla planifolia growth on in vitro conditions. Exposure of plantlets to AgNPs increase the polymorphism registered by inter-simple sequence repeat method (ISSR), which could be useful to promote the genetic variability of this species.
Synthesis and Characterization of Rh/B–TNTs as a Recyclable Catalyst for Hydroformylation of Olefin Containing –CN Functional Group
Authors: Su Penghe , Liu Xiaotong , Chen Ya , Liu Hongchi , Zhu Baolin , Zhang Shoumin , Huang Weiping
Published: September 2018

The TiO2-based nanotubes (TNTs, B–TNTs) of different surface acidities and their supported Rh catalysts were designed and synthesized. The catalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectrometer (XPS), tempera–ture–programmed desorption of ammonia (NH3–TPD), atomic emission spectrometer (ICP), and Brunauer–Emmett–Tellerv (BET) surface-area analyzers. Images of SEM and TEM showed that the boron-decorated TiO2 nanotubes (B–TNTs) had a perfect multiwalled tubular structure; their length was up to hundreds of nanometers and inner diameter was about 7 nm. The results of NH3-TPD analyses showed that B–TNTs had a stronger acid site compared with TNTs. For Rh/TNTs and Rh/B–TNTs, Rh nanoparticles highly dispersed on B–TNTs were about 2.79 nm in average diameter and much smaller than those on TNTs, which were about 4.94 nm. The catalytic performances of catalysts for the hydroformylation of 2-methyl-3-butennitrile (2M3BN) were also evaluated, and results showed that the existence of B in Rh/B–TNTs had a great influence on the catalytic performance of the catalysts. The Rh/B–TNTs displayed higher catalytic activity, selectivity for aldehydes, and stability than the Rh/TNTs.
Applications of SERS in the Detection of Stress-Related Substances
Authors: Du Shuyuan , Yu Chundi , Tang Lin , Lu Lixia
Published: September 2018

A wide variety of biotic and abiotic stresses continually attack plants and animals, which adversely affect their growth, development, reproduction, and yield realization. To survive under stress conditions, highly sophisticated and efficient tolerance mechanisms have been evolved to adapt to stresses, which consist of the variation of effector molecules playing vital roles in physiological regulation. The development of a sensitive, facile, and rapid analytical methods for stress factors and effector molecules detection is significant for gaining deeper insight into the tolerance mechanisms. As a nondestructive analysis technique, surface-enhanced Raman spectroscopy (SERS) has unique advantages regarding its biosensing applications. It not only provides specific fingerprint spectra of the target molecules, conformation, and structure, but also has universal capacity for simultaneous detection and imaging of targets owing to the narrow width of the Raman vibrational bands. Herein, recent progress on biotic and abiotic stresses, tolerance mechanisms and effector molecules is summarized. Moreover, the development and promising future trends of SERS detection for stress-related substances combined with nanomaterials as substrates and SERS tags are discussed. This comprehensive and critical review might shed light on a new perspective for SERS applications.
Protective Roles of Thymoquinone Nanoformulations: Potential Nanonutraceuticals in Human Diseases
Authors: El-Far Ali H. , Al Jaouni Soad K. , Li Weikun , Mousa Shaker A.
Published: September 2018

The focus on nanotechnology for improved bioavailability and drug delivery is of increasing importance for control of different human diseases. Therefore, numerous nanoformulations have been developed for the oral bioavailability of different drugs. This review introduces applications of nanomedicine to enhance the biological activities of thymoquinone (TQ) to control different diseases in several in vivo studies as a preliminary investigation for human disease treatment with nano-TQ. Nano-TQ effectively augments the anticancer roles of doxorubicin by upregulation of P53 and downregulation of Bcl2 and potentiates paclitaxel’s apoptosis in MCF-7 breast cancer cells. Moreover, nano-TQ protects against diabetes, inflammation, CNS, and hepatotoxicity, mainly by enhancement of organs’ antioxidant status. We summarize the pros and cons of several FDA approved nanoparticle-based therapeutics and discuss the roadblocks in clinical translation, along with potential nano-TQ strategies to overcome these roadblocks. From this review, we can conclude that nano-TQ may be considered as a promising nutraceutical for human health.
The Availability and Nutritional Adequacy of Gluten-Free Bread and Pasta
Authors: Allen Beatrice , Orfila Caroline
Published: September 2018

Management of coeliac disease (CD) requires the removal of gluten from the diet. Evidence of the availability, cost, and nutritional adequacy of gluten-free (GF) bread and pasta products is limited. GF flours are exempt from UK legislation that requires micronutrient fortification of white wheat flour. This study surveyed the number and cost of bread and pasta products available and evaluated the back-of-pack nutritional information, the ingredient content, and the presence of fortification nutrients of GF bread and pasta, compared to standard gluten-containing equivalent products. Product information was collected from four supermarket websites. Standard products were significantly cheaper, with more products available than GF (p < 0.05). GF bread products were significantly higher in fat and fiber (p < 0.05). All GF products were lower in protein than standard products (p < 0.01). Only 5% of GF breads were fortified with all four mandatory fortification nutrients (calcium, iron, nicotinic acid or nicotamide and thiamin), 28% of GF breads were fortified with calcium and iron only. This lack of fortification may increase the risk of micronutrient deficiency in coeliac sufferers. It is recommended that fortification legislation is extended to include all GF products, in addition to increased regulation of the nutritional content of GF foods.
Impact of Genetic Variability on Physiological Responses to Caffeine in Humans: A Systematic Review
Authors: Fulton Jacob L. , Dinas Petros C. , Carrillo Andres E. , Edsall Jason R. , Ryan Emily J. , Ryan Edward J.
Published: September 2018

Emerging research has demonstrated that genetic variation may impact physiological responses to caffeine consumption. The purpose of the present review was to systematically recognize how select single nucleotide polymorphisms (SNPs) impact habitual use of caffeine as well as the ergogenic and anxiogenic consequences of caffeine. Two databases (PubMed and EBSCO) were independently searched using the same algorithm. Selected studies involved human participants and met at least one of the following inclusion criteria: (a) genetic analysis of individuals who habitually consume caffeine; (b) genetic analysis of individuals who underwent measurements of physical performance with the consumption of caffeine; (c) genetic analysis of individuals who underwent measurements of mood with the consumption of caffeine. We included 26 studies (10 randomized controlled trials, five controlled trials, seven cross-sectional studies, three single-group interventional studies and one case-control study). Single nucleotide polymorphisms in or near the cytochrome P450 (CYP1A2) and aryl hydrocarbon receptor (AHR) genes were consistently associated with caffeine consumption. Several studies demonstrated that the anxiogenic consequences of caffeine differed across adenosine 2a receptor (ADORA2A) genotypes, and the studies that investigated the effects of genetic variation on the ergogenic benefit of caffeine reported equivocal findings (CYP1A2) or warrant replication (ADORA2A).
Porous Inorganic Carriers Based on Silica, Calcium Carbonate and Calcium Phosphate for Controlled/Modulated Drug Delivery: Fresh Outlook and Future Perspectives
Authors: Trofimov Alexey , Ivanova Anna , Zyuzin Mikhail , Timin Alexander
Published: September 2018

Porous inorganic nanostructured materials are widely used nowadays as drug delivery carriers due to their adventurous features: suitable architecture, large surface area and stability in the biological fluids. Among the different types of inorganic porous materials, silica, calcium carbonate, and calcium phosphate have received significant attention in the last decade. The use of porous inorganic materials as drug carriers for cancer therapy, gene delivery etc. has the potential to improve the life expectancy of the patients affected by the disease. The main goal of this review is to provide general information on the current state of the art of synthesis of the inorganic porous particles based on silica, calcium carbonate and calcium phosphate. Special focus is dedicated to the loading capacity, controllable release of drugs under internal biological stimuli (e.g., pH, redox, enzymes) and external noninvasive stimuli (e.g., light, magnetic field, and ultrasound). Moreover, the diverse compounds to deliver with silica, calcium carbonate and calcium phosphate particles, ranging from the commercial drugs to genetic materials are also discussed.
Investigation of the Effects of Non-Conjugated Co-Grafts on the Spectroelectrochemical and Photovoltaic Properties of Novel Conjugated Graft Copolymers Based on Poly(3-hexylthiophene)
Authors: Jarosz Tomasz , Gebka Karolina , Kepska Kinga , Lapkowski Mieczyslaw , Ledwon Przemyslaw , Nitschke Pawel , Stolarczyk Agnieszka
Published: September 2018

A new type of polysiloxane copolymers, with conjugated–regioregular poly(3-hexylthiophene) (P3HT) and non-conjugated-poly(ethylene glycol) (PEG)-grafts have been synthesised, and their properties have been studied alongside those of the parent conjugated polymer (P3HT). Spectroelectrochemical and conductometric analyses revealed an early rise of the conductance of the polymers. Once spectral changes begin taking place, the conductance is stable, implying a loss of mobility of charge carriers, even though standard doping/dedoping patterns are observed. Prototype bulk heterojunction solar cells have been fabricated, based on P3HT/[6,6]-Phenyl-C61-butyric acid methyl ester (PCBM), as well as by substituting P3HT for each of the copolymers. The prototype solar cells achieved PCEs of up to 2.11%. This is one of the highest reported power conversion efficiency (PCE) for devices based on P3HT with low average molecular weight Mn = 12 kDa. Strong correlation between the structure of the copolymer and its photovoltaic performance was found. Elongation of PEG copolymer chain and the use of methyl group instead of terminal hydroxyl groups significantly improved photovoltaic performance.
Reversible Protonic Doping in Poly(3,4-Ethylenedioxythiophene)
Authors: He Shuzhong , Mukaida Masakazu , Kirihara Kazuhiro , Lyu Lingyun , Wei Qingshuo
Published: September 2018

In this study, poly(3,4-ethylenedioxythiophene), a benchmark-conducting polymer, was doped by protons. The doping and de-doping processes, using protonic acid and a base, were fully reversible. We predicted possible doping sites along the polymer chain using density functional theory (DFT) calculations. This study sheds potential light and understanding on the molecular design of highly conductive organic materials.
Reconstruction of the Water Cultivation Paleoenvironment Dating Back to the Han and Tang Dynasties Surrounding the Yangguan Frontier Pass Using X- and L-Band SAR Data
Authors: Zhu Xiaokun , Chen Fulong , Guo Huadong
Published: September 2018

Supported by a shallow groundwater wetland ecosystem, the Nanhu oasis, which is the location of the Yangguan frontier pass, represents an important supply and defence station for the ancient Silk Road. The reconstruction of the evolution of the water cultivation environment is helpful for archaeological surveys and the protection of this well-known heritage site. This study proposes a workflow for reconstructing the water cultivation paleoenvironment-based primarily on X- and L-band spaceborne synthetic aperture radar (SAR) data. First, TerraSAR-X/TanDEM-X (TSX/TDX)-generated Digital Elevation Model (DEM) data were used for microrelief analyses, including a watershed analysis and drainage network extraction. Several dried-up paleochannels and the range of the Daze (a wetland dating back to the Tang Dynasty (618–907 A.D.)) were identified. Second, based on the hydrological sensitivity analysis of the multi-temporal L-band SAR data, arid land vegetation accompanying the emergence of groundwater was extracted to locate ancient arable areas using backscattering and coherence characteristics. Finally, reconstruction of the water cultivation paleoenvironment surrounding the Nanhu oasis dating back to the Han and Tang dynasties (202 B.C.–907 A.D.) was performed, referring to historical documents. New discoveries were validated by field campaigns, and the results of the SAR archaeological investigations conducted in this study indicated that the ancient arable area in the Nanhu oasis was nearly double the current dimensions.
Decadal Changes of Earth’s Outgoing Longwave Radiation
Authors: Dewitte Steven , Clerbaux Nicolas
Published: September 2018

The Earth Radiation Budget (ERB) at the top of the atmosphere quantifies how the earth gains energy from the sun and loses energy to space. Its monitoring is of fundamental importance for understanding ongoing climate change. In this paper, decadal changes of the Outgoing Longwave Radiation (OLR) as measured by the Clouds and Earth’s Radiant Energy System from 2000 to 2018, the Earth Radiation Budget Experiment from 1985 to 1998, and the High-resolution Infrared Radiation Sounder from 1985 to 2018 are analysed. The OLR has been rising since 1985, and correlates well with the rising global temperature. An observational estimate of the derivative of the OLR with respect to temperature of 2.93 +/− 0.3 W/m 2 K is obtained. The regional patterns of the observed OLR change from 1985–2000 to 2001–2017 show a warming pattern in the Northern Hemisphere in particular in the Arctic, as well as tropical cloudiness changes related to a strengthening of La Niña.
Real-Time Monitoring of Crop Phenology in the Midwestern United States Using VIIRS Observations
Authors: Liu Lingling , Zhang Xiaoyang , Yu Yunyue , Gao Feng , Yang Zhengwei
Published: September 2018

Real-time monitoring of crop phenology is critical for assisting farmers managing crop growth and yield estimation. In this study, we presented an approach to monitor in real time crop phenology using timely available daily Visible Infrared Imaging Radiometer Suite (VIIRS) observations and historical Moderate Resolution Imaging Spectroradiometer (MODIS) datasets in the Midwestern United States. MODIS data at a spatial resolution of 500 m from 2003 to 2012 were used to generate the climatology of vegetation phenology. By integrating climatological phenology and timely available VIIRS observations in 2014 and 2015, a set of temporal trajectories of crop growth development at a given time for each pixel were then simulated using a logistic model. The simulated temporal trajectories were used to identify spring green leaf development and predict the occurrences of greenup onset, mid-greenup phase, and maximum greenness onset using curvature change rate. Finally, the accuracy of real-time monitoring from VIIRS observations was evaluated by comparing with summary crop progress (CP) reports of ground observations from the National Agricultural Statistics Service (NASS) of the United States Department of Agriculture (USDA). The results suggest that real-time monitoring of crop phenology from VIIRS observations is a robust tool in tracing the crop progress across regional areas. In particular, the date of mid-greenup phase from VIIRS was significantly correlated to the planting dates reported in NASS CP for both corn and soybean with a consistent lag of 37 days and 27 days on average (p < 0.01), as well as the emergence dates in CP with a lag of 24 days and 16 days on average (p < 0.01), respectively. The real-time monitoring of maximum greenness onset from VIIRS was able to predict the corn silking dates with an advance of 9 days (p < 0.01) and the soybean blooming dates with a lag of 7 days on average (p < 0.01). These findings demonstrate the capability of VIIRS observations to effectively monitor temporal dynamics of crop progress in real time at a regional scale.
Detecting Areas Vulnerable to Sand Encroachment Using Remote Sensing and GIS Techniques in Nouakchott, Mauritania
Authors: Gómez Diego , Salvador Pablo , Sanz Julia , Casanova Carlos , Casanova Jose Luis
Published: September 2018

Sand dune advances poses a major threat to inhabitants and local authorities in the area of Nouakchott, Mauritania. Despite efforts to control dune mobility, accurate and adequate local studies are still needed to tackle sand encroachment. We have developed a Sand Dune Encroachment Vulnerability Index (SDEVI) to assess Nouakchott’s vulnerability to sand dune encroachment. Said index is based on the geo-physical characteristics of the area (wind direction and intensity, slope and surface height, land use, vegetation or soil properties) with Geographic Information System (GIS) techniques that can support local authorities and decision-makers in implementing preventive measures or reducing impact on the population and urban infrastructures. In order to validate this new index, we use two remote sensing approaches: optical-Sentinel 2 and Synthetic Aperture Radar (SAR)–Sentinel 1 data. Results show that the greatest vulnerability is located in the north-eastern part of Nouakchott, where local conditions favor the advance of sand in the city, although medium to high values are also found in the eastern part. Optical images enabled us to distinguish desert sand using the ratio between near infrared/blue bands, and SAR Coherence Change Detection (CCD) imagery was used to assess the degree of stability of those sand bodies. The nature of the SDEVI index allows us to currently assess which areas are vulnerable to sand encroachment since we use long data records. Nevertheless, optical and SAR remote sensing allow sand evolution to be monitored on a near real-time basis.
Impact of the Acquisition Geometry of Very High-Resolution Pléiades Imagery on the Accuracy of Canopy Height Models over Forested Alpine Regions
Authors: Piermattei Livia , Marty Mauro , Karel Wilfried , Ressl Camillo , Hollaus Markus , Ginzler Christian , Pfeifer Norbert
Published: September 2018

This work focuses on the accuracy estimation of canopy height models (CHMs) derived from image matching of Pléiades stereo imagery over forested mountain areas. To determine the height above ground and hence canopy height in forest areas, we use normalised digital surface models (nDSMs), computed as the differences between external high-resolution digital terrain models (DTMs) and digital surface models (DSMs) from Pléiades image matching. With the overall goal of testing the operational feasibility of Pléiades images for forest monitoring over mountain areas, two questions guide this work whose answers can help in identifying the optimal acquisition planning to derive CHMs. Specifically, we want to assess (1) the benefit of using tri-stereo images instead of stereo pairs, and (2) the impact of different viewing angles and topography. To answer the first question, we acquired new Pléiades data over a study site in Canton Ticino (Switzerland), and we compare the accuracies of CHMs from Pléiades tri-stereo and from each stereo pair combination. We perform the investigation on different viewing angles over a study area near Ljubljana (Slovenia), where three stereo pairs were acquired at one-day offsets. We focus the analyses on open stable and on tree covered areas. To evaluate the accuracy of Pléiades CHMs, we use CHMs from aerial image matching and airborne laser scanning as reference for the Ticino and Ljubljana study areas, respectively. For the two study areas, the statistics of the nDSMs in stable areas show median values close to the expected value of zero. The smallest standard deviation based on the median of absolute differences (σMAD) was 0.80 m for the forward-backward image pair in Ticino and 0.29 m in Ljubljana for the stereo images with the smallest absolute across-track angle (−5.3°). The differences between the highest accuracy Pléiades CHMs and their reference CHMs show a median of 0.02 m in Ticino with a σMAD of 1.90 m and in Ljubljana a median of 0.32 m with a σMAD of 3.79 m. The discrepancies between these results are most likely attributed to differences in forest structure, particularly tree height, density, and forest gaps. Furthermore, it should be taken into account that temporal vegetational changes between the Pléiades and reference data acquisitions introduce additional, spurious CHM differences. Overall, for narrow forward–backward angle of convergence (12°) and based on the used software and workflow to generate the nDSMs from Pléiades images, the results show that the differences between tri-stereo and stereo matching are rather small in terms of accuracy and completeness of the CHM/nDSMs. Therefore, a small angle of convergence does not constitute a major limiting factor. More relevant is the impact of a large across-track angle (19°), which considerably reduces the quality of Pléiades CHMs/nDSMs.
Support Vector Machine Optimized by Genetic Algorithm for Data Analysis of Near-Infrared Spectroscopy Sensors
Authors: Wang Di , Xie Lin , Yang Simon X. , Tian Fengchun
Published: September 2018

Near-infrared (NIR) spectral sensors deliver the spectral response of the light absorbed by materials for quantification, qualification or identification. Spectral analysis technology based on the NIR sensor has been a useful tool for complex information processing and high precision identification in the tobacco industry. In this paper, a novel method based on the support vector machine (SVM) is proposed to discriminate the tobacco cultivation region using the near-infrared (NIR) sensors, where the genetic algorithm (GA) is employed for input subset selection to identify the effective principal components (PCs) for the SVM model. With the same number of PCs as the inputs to the SVM model, a number of comparative experiments were conducted between the effective PCs selected by GA and the PCs orderly starting from the first one. The model performance was evaluated in terms of prediction accuracy and four parameters of assessment criteria (true positive rate, true negative rate, positive predictive value and F1 score). From the results, it is interesting to find that some PCs with less information may contribute more to the cultivation regions and are considered as more effective PCs, and the SVM model with the effective PCs selected by GA has a superior discrimination capacity. The proposed GA-SVM model can effectively learn the relationship between tobacco cultivation regions and tobacco NIR sensor data.
A Design of Overlapped Chunked Code over Compute-and-Forward for Multi-Source Multi-Relay Networks
Authors: Ngeth Rithea , Kurkoski Brian M. , Lim Yuto , Tan Yasuo
Published: September 2018

This paper investigates the design of overlapped chunked codes (OCC) for multi-source multi-relay networks where a physical-layer network coding approach, compute-and-forward (CF) based on nested lattice codes (NLC), is applied for the simultaneous transmissions from the sources to the relays. This code is called OCC/CF. In this paper, OCC is applied before NLC before transmitting for each source. Random linear network coding is applied within each chunk. A decodability condition to design OCC/CF is provided. In addition, an OCC with a contiguously overlapping, but non-rounded-end fashion is employed for the design, which is done by using the probability distributions of the number of innovative codeword combinations and the probability distribution of the participation factor of each source to the codeword combinations received for a chunk transmission. An estimation is done to select an allocation, i.e., the number of innovative blocks per chunk and the number of blocks taken from the previous chunk for all sources, that is expected to provide the desired performance. From the numerical results, the design overhead of OCC/CF is low when the probability distribution of the participation factor of each source is dense at the chunk size for each source.
A Gas Sensor Based on a Single SnO Micro-Disk
Authors: Masteghin Mateus , Orlandi Marcelo
Published: September 2018

In this study, individual nanofabricated SnO micro-disks, previously shown to exhibit exceptional sensitivity to NOx, are investigated to further our understanding of gas sensing mechanisms. The SnO disks presenting different areas and thickness were isolated and electrically connected to metallic electrodes aided by a Dual Beam Microscope (SEM/FIB). While single micro-disk devices were found to exhibit short response and recovery times and low power consumption, large interconnected arrays of micro-disks exhibit much higher sensitivity and selectivity. The source of these differences is discussed based on the gas/solid interaction and transport mechanisms, which showed that thickness plays a major role during the gas sensing of single-devices. The calculated Debye length of the SnO disk in presence of NO2 is reported for the first time.
A Novel Setup and Protocol to Measure the Range of Motion of the Wrist and the Hand
Authors: Nizamis Kostas , Rijken Noortje H. M. , Mendes Ana , Janssen Mariska M. H. P. , Bergsma Arjen , Koopman Bart F. J. M.
Published: September 2018

The human hand is important for the performance of activities of daily living which are directly related to quality of life. Various conditions, such as Duchenne muscular dystrophy (DMD) can affect the function of the human hand and wrist. The ability to assess the impairment in the hand and the wrist by measuring the range of motion (ROM), is essential for the development of effective rehabilitation protocols. Currently the clinical standard is the goniometer. In this study we explore the feasibility and reliability of an optical sensor (Leap motion sensor) in measuring active hand/wrist ROM. We measured the hand/wrist ROM of 20 healthy adults with the goniometer and the Leap motion sensor, in order to check the agreement between the two methods and additionally, we performed a test-retest of the Leap motion sensor with 12 of them, to assess its reliability. The results suggest low agreement between the goniometer and the leap motion sensor, yet showing a large decrease in measurement time and high reliability when using the later. Despite the low agreement between the two methods, we believe that the Leap motion sensor shows potential to contribute to the development of hand rehabilitation protocols and be used with patients in a clinical setting.
Fixed- and Variable-Temperature Kinetic Models to Predict Evaporation of Petroleum Distillates for Fire Debris Applications
Authors: McIlroy John W. , Smith Ruth Waddell , McGuffin Victoria L.
Published: September 2018

Forensic fire debris analysis focuses on the identification of a foreign ignitable liquid in debris collected from the scene of a suspected intentional fire. Chromatograms of the extracted debris are compared to a suitable reference collection containing chromatograms of unevaporated and evaporated ignitable liquids. However, there is no standardized method for the evaporation of ignitable liquids and the process itself can be time consuming, which limits the number of chromatograms of evaporated liquids included in the reference collection. This work describes the development and application of a variable-temperature kinetic model to predict evaporation rate constants and mathematically predict chromatograms corresponding to evaporated ignitable liquids. First-order evaporation rate constants were calculated for 78 selected compounds in diesel, which were used to develop predictive models of evaporation rates. Fixed-temperature models were developed to predict the rate constants at five temperatures (5, 10, 20, 30, 35 °C), yielding a mean absolute percent error (MAPE) of 10.0%. The variable-temperature model was then created from these data by multiple linear regression, yielding a MAPE of 16.4%. The model was applied to generate a reference collection of predicted chromatograms of diesel and kerosene corresponding to a range of evaporation levels. Using the modeled reference collection, successful identification of the liquid and level of evaporation in a test set of chromatograms was demonstrated.
Reverse Logistic Strategy for the Management of Tire Waste in Mexico and Russia: Review and Conceptual Model
Authors: Uriarte-Miranda Maria-Lizbeth , Caballero-Morales Santiago-Omar , Martinez-Flores Jose-Luis , Cano-Olivos Patricia , Akulova Anastasia-Alexandrovna
Published: September 2018

Management of tire waste is an important aspect of sustainable development due to its environmental, economical and social impacts. Key aspects of Reverse Logistics (RL) and Green Logistics (GL), such as recycling, re-manufacturing and reusable packaging, can improve the management of tire waste and support sustainability. Although these processes have been performed with a high degree of efficiency in other countries such as Japan, Spain and Germany, the application in Mexico and Russia has faced setbacks due to the absence of guidelines regarding legislation, RL processes, and social responsibility. Within this context, the present work aims to develop an integrated RL model to improve on these processes by considering the RL models from Russia and Mexico. For this, a review focused on RL in Mexico, Russia, Japan and the European Union (EU) was performed. Hence, the integrated model considers regulations and policies performed in each country to assign responsibilities regarding RL processes for the management of tire waste. As discussed, the implementation of efficient RL processes for the management of tire waste depends of different social entities such as the user (customer), private and public companies, and manufacturing and state-of-the-art approaches to transform waste into different products (diversification) to consider the RL scheme as a total economic system.
Planning Modes for Major Transportation Infrastructure Projects (MTIPs): Comparing China and Germany
Authors: Zhou Tianxiao , Tan Rong , Sedlin Thomas
Published: September 2018

Because major transportation infrastructure projects (MTIPs) have significant effects for a sustainable development, the planning modes used for these projects have been a popular topic among scholars and policy makers. However, detailed descriptions and comparisons of planning modes in different countries are still rare. Therefore, this paper first provides a simple analytical framework based on the elements of the planning goal, the planning process, the planning result and the evaluation criteria. Focusing on the hierarchic mode adopted in China, and the democratic participatory mode adopted in Germany, the governance practices used in MTIP planning are clearly shown. Furthermore, by using two airport cases, this paper compares the differences between China and Germany in the realms of preparation, review, coordination, final approval, and planning performance. The main conclusions are: (1) The analytical approach presented in this paper provides an appropriate standard for describing and comparing planning modes for MTIPs; (2) the planning modes in the two countries each have advantages and disadvantages, reflecting the trade-off between ex ante and ex post costs; (3) the comparison between China and Germany may be instructive for both of these countries and for other countries in terms of improving their planning performance in the future.
A Study of the Energy Efficiency Management in Green Standard for Energy and Environmental Design (G-SEED)-Certified Apartments in South Korea
Authors: Kim Hyemi , Park Wonjun
Published: September 2018

With an increase in the number of Green Standard for Energy and Environmental Design (G-SEED)-certified apartments in South Korea, people are receiving incentives from the government to purchase them. Since 2013, many benefits for G-SEED-certified buildings have been offered, such as tax reductions and deregulation of building codes/guidelines. As beneficial incentives are granted to G-SEED-certified buildings, follow-up management of the buildings is also necessary. However, to date, there are no appropriate follow-up management systems or legal regulations for G-SEED-certified buildings. Buildings that are certified by G-SEED in Korean housing buildings account for 6.25% of Korea’s total area. In addition, G-SEED certification has been obtained for more than 20% of the total completed housing area (2014–2017). Therefore, the energy efficiency-management of G-SEED certified buildings is also very important economically for reducing greenhouse gas emissions. In this study, domestic and foreign energy efficiency follow-up management systems were analyzed, and the amount of energy that is used by apartment houses with incentives was investigated. We have identified problems with the G-SEED system by analyzing evaluation methods, evaluation items, and points of G-SEED certification in related research studies. We also compared the energy consumption of an apartment building with G-SEED certification with that of adjacent complexes, thereby applying original research methods. The results show that energy use in G-SEED-certified buildings was not efficient. Accordingly, the study confirms that continuous management after G-SEED certification by establishing a follow-up management system is needed. In this study, domestic and foreign follow-up management systems were compared, problems with the apartment housing information management system run by the government were examined, and improvement measures were suggested.
Comparative Changes of Influence Factors of Rural Residential Area Based on Spatial Econometric Regression Model: A Case Study of Lishan Township, Hubei Province, China
Authors: Zhang Xuesong , He Ju , Deng Zhen , Ma Jiyue , Chen Guangping , Zhang Maomao , Li Deshou
Published: September 2018

The influencing factors of rural residential areas have always been a key research direction in addressing rural problems in China. By introducing a spatial regression model combined with Kernel Density Estimation and Buffer Analysis, this study made a comparative study on the quantification of the influencing factors of rural residential areas in 2009, 2012, and 2015 in Lishan Township, Hubei Province, China. The results showed that the elevation and slope of Lishan Township have always played a decisive role in the distribution of rural residential areas, that the influence of the water system is abnormal, and that the influence of roads and townships has been strengthened based on the spatial statistical analysis. Then, based on spatial econometric regression analysis, the coefficients of “Topographic indices” (CTI) were 0.666, 0.719, and 0.439 in 2009, 2012, and 2015, respectively. The coefficients of Road (CR) were 0.170, 0.112, and 0.108, respectively. The coefficients of Town (CT) were 0.120, 0.127, and 0.166, respectively. The coefficients of Water system (CWS) were 0.166, 0.124, and 0.173, respectively. With the change of time, the influence of road decreased and the influence of town increased gradually. Furthermore, the influence of the water system and topography showed volatility.