bluuebunny/crossref_metadata_2025 huggingface dataset:
The Dar al Gani meteorite field (Libyan Sahara): Geological setting, pairing of meteorites, and recovery density
Authors: Schlüter J. , Schultz L. , Thiedig F. , Al‐Mahdi B. O. , Aghreb A. E. Abu
Published: January 2010

Abstract— As of July 2001, 1238 Libyan meteorites have been reported. Most were found in two areas called Dar al Gani and Hamadah al Hamra. Dar al Gani is located on a plateau of marine carbonate rocks with marly components. Eight‐hundred and sixty‐nine meteorites between 6 g and 95 kg totalling 687 kg have been found here but the calculated mean recovery density is comparatively low with one meteorite on 6.5 km2.

Dar al Gani is a perfect site for the recognition and preservation of meteorites. The existence of meteorites is the result of a combination of specific geological and geomorphological conditions: there is a bright‐colored, old limestone plateau (<2 Ma), under arid weather conditions over long periods of time, with rapid elimination of surface water if present and low erosion rates. The preservation of meteorites is guaranteed through the absence of quartz sand on the plateau, strongly reducing wind erosion and a basic environment emerging from the carbonate ground retards rusting of metallic meteorite components. A supposed soil cover during pluvial times has probably protected older meteorites and led to a concentration of meteorites of different periods.

An evaluation of Dar al Gani meteorites suggests the existence of at least 26 strewnfields and 26 meteorite pairs reducing the number of falls to, at most, 534. Shock and weathering grades as a tool for the recognition of pairings turned out to be problematic, as several strewnfields showed paired meteorites which had been classified to different shock and weathering grades.
Martian meteorite Dhofar 019: A new shergottite
Authors: Taylor L. A. , Nazarov M. A. , Shearer C. K. , McSween H. Y. , Cahill J. , Neal C. R. , Ivanova M. A. , Barsukova L. D. , Lentz R. C. , Clayton R. N. , Mayeda T. K.
Published: January 2010

Abstract— Dhofar 019 is a new martian meteorite found in the desert of Oman. In texture, mineralogy, and major and trace element chemistry, this meteorite is classified as a basaltic shergottite. Olivine megacrysts are set within a groundmass composed of finer grained olivine, pyroxene (pigeonite and augite), and maskelynite. Minor phases are chromite‐ulvöspinel, ilmenite, silica, K‐rich feldspar, merrillite, chlorapatite, and pyrrhotite. Secondary phases of terrestrial origin include calcite, gypsum, celestite, Fe hydroxides, and smectite.

Dhofar 019 is most similar to the Elephant Moraine (EETA) 79001 lithology A and Dar al Gani (DaG) 476/489 shergottites. The main features that distinguish Dhofar 019 from other shergottites are lack of orthopyroxene; lower Ni contents of olivine; the heaviest oxygen‐isotopic bulk composition; and larger compositional ranges for olivine, maskelynite, and spinel, as well as a wide range for pyroxenes. The large compositional ranges of the minerals are indicative of relatively rapid crystallization. Modeling of olivine chemical zonations yield minimum cooling rates of 0.5‐0.8 °C/h. Spinel chemistry suggests that crystallization took place under one of the most reduced conditions for martian meteorites, at an fO2 3 log units below the quartz‐fayalite‐magnetite (QFM) buffer.

The olivine megacrysts are heterogeneously distributed in the rock. Crystal size distribution analysis suggests that they constitute a population formed under steady‐state conditions of nucleation and growth, although a few grains may be cumulates. The parent melt is thought to have been derived from partial melting of a light rare earth element‐ and platinum group element‐depleted mantle source. Shergottites, EETA79001 lithology A, DaG 476/489, and Dhofar 019, although of different ages, comprise a particular type of martian rocks. Such rocks could have formed from chemically similar source(s) and parent melt(s), with their bulk compositions affected by olivine accumulation.
The sodium tail of Mercury
Authors: POTTER A. E. , KILLEN R. M. , MORGAN T. H.
Published: January 2010

Abstract— Mercury is difficult to observe because it is so close to the Sun. However, when the angle of the ecliptic is near maximum in the northern hemisphere, and Mercury is near its greatest eastern elongation, it can be seen against the western sky for about a half hour after sunset. During these times, we were able to map sodium D2 emission streaming from the planet, forming a long comet‐like tail. On 2001 May 26 (U.T.) we mapped the tail downstream to a distance of ˜40 000 km. Sodium velocities in the tail increased to ˜11 km s−1 at 40 000 km as the result of radiation pressure acceleration. On 2000 June 5 (U.T.) we mapped the cross‐sectional extent of the tail at a distance of ˜17 500 km downstream. At this distance, the half‐power full‐width of the emission was ˜20 000 km. We estimated the transverse velocity of sodium in the tail to range from 2 to 4 km s−1. The velocities we observed imply source velocities from the planet surface of the order of 5 km s−1, or 4 eV. Particle sputtering is a likely candidate for production of sodium atoms at these velocities. The total flux of sodium in the tail was ˜1 times 1023 atoms s−1, which corresponds to 1 to 10% of the estimated total production rate of sodium on the planet.
Source and maintenance of the argon atmospheres of Mercury and the Moon
Authors: KILLEN R. M.
Published: January 2010

Abstract— We propose that argon‐40 measured in the lunar atmosphere and that in Mercury's atmosphere is due to current diffusion into connected pore space within the crust. Higher temperatures at Mercury, along with more rapid loss from the atmosphere, will lead to a similar or smaller column abundance of argon at Mercury than at the Moon, given the same crustal abundance of potassium. Because the noble gas abundance in the mercurian atmosphere represents current effusion, it is a direct measure of the crustal potassium abundance. We assume a fractal distribution of distance to a connected pore space, with the shortest distance increasing with depth. Given this “rock size” distribution, we show that the diffusive flux is not a unique function of temperature. Even though the diffusion coefficient is an exponential function of temperature, the flux to the surface is fairly insensitive to the temperature.
Mercury: Mid‐infrared (3–13.5 μm) observations show heterogeneous composition, presence of intermediate and basic soil types, and pyroxene
Authors: SPRAGUE A. L. , EMERY J. P. , DONALDSON K. L. , RUSSELL R. W. , LYNCH D. K. , MAZUK A. L.
Published: January 2010

Abstract—The Aerospace Corporation's broadband array spectrograph system (BASS) mounted on the NASA infrared telescope facility (IRTF) on Mauna Kea, Hawaii was used to obtain spectral measurements of Mercury's thermal emission on 1998 March 21 (45–85° longitude), and on 1998 May 12 (68–108° longitude). The spectra show heterogeneous composition on Mercury's surface between longitudes 45–85° and about 68–108°. These observations include measurements from 3 to 6 μm, a spectral region not previously covered by mid‐infrared spectroscopy. Excellent quality data were obtained in the atmospheric windows between 3–4.2 and 4.6–5.5 μm. These wavelength regions exhibit high emissivity characteristic of a regolith with strong thermal gradients maintained in a vacuum environment with spectra dominated by grain sizes of ˜30 μm. Emission peaks are present at 3.5 and 5 μm in the 45–85° longitude data. The 5 μm peak has been tentatively attributed to clinopyroxene. Data were also obtained in the 7.5–13.5 μm spectral region. Spectra obtained during both observing periods show well‐defined emissivity maxima (EM) in the spectral vicinity (between 7.7 and 9.2 μm) of the Christiansen frequency of silicate soils. The location of the EM for longitudes 45–85° (7.9 μm) is consistent with a surface composition of intermediate SiO2content. The overall spectral shape is similar to that obtained previously at the same location with different instrumentation. In the region 68–108° longitude, three EM are observed at 7.8, 8.2, and 9.2 μm, indicating the presence of distinctly different surface composition from the other location. Comparisons of these data to other mid‐infrared spectra of Mercury's surface and asteroids, and of the different instrumentation used in observations are included.
The meteorite collection of the National Museum of Natural Sciences, Madrid, Spain: An updated catalog
Authors: MUÑOZ‐ESPADAS M. J. , MARTÍNEZ‐FRÍAS J. , LUNAR R. , SÁNCHEZ B. , SÁNCHEZ J.
Published: January 2010

Abstract— A catalog of the meteorite collection hosted by the National Museum of Natural Sciences of Madrid is presented. It includes 88 stony meteorites, 56 iron meteorites, and 13 stony‐iron meteorites, as well as 14 tektites.
The meteorite collection of the Civico Planetario and the Museo Civico di Storia Naturale in Milan, Italy
Authors: FOLCO Luigi , PERI Fabio , PEZZOTTA Federico
Published: January 2010

Abstract— The historical meteorite collection of Milan's Civico Planetario and Museo di Storia Naturale is presented in this catalogue. Started in 1838, the collection contains to date (March 2002) 231 samples of 77 individual falls, representing 118.935 kg (i.e., the total weight is 118 kg and 935 g) of extraterrestrial material, including 5 carbonaceous chondrites, 38 ordinary chondrites, 3 achondrites, 7 stony‐iron meteorites and 24 iron meteorites.
Combined noble gas and trace element measurements on individual stratospheric interplanetary dust particles
Authors: Kehm K. , Flynn G. J. , Sutton S. R. , Hohenberg C. M.
Published: January 2010

Abstract— The trace element compositions and noble gas contents of 32 individual interplanetary dust particles (IDPs) collected in the Earth's stratosphere were measured. Trace element compositions are generally similar to CI meteorites, with occasional depletions in Zn/Fe with respect to CI. Noble gases were detected in all but one of the IDPs. Noble gas elemental compositions are consistent with the presence of fractionated solar wind. A rough correlation between surface‐normalized He abundances and Zn/Fe ratios is observed; Zn‐poor particles generally have lower He contents than the other IDPs. This suggests that both elements were lost by frictional heating during atmospheric entry and confirms the view that Zn can serve as an entry‐heating indicator in IDPs.
Ejection ages from krypton‐81‐krypton‐83 dating and pre‐atmospheric sizes of martian meteorites
Authors: Eugster O. , Busemann H. , Lorenzetti S. , Terribilini D.
Published: January 2010

Abstract— Cosmic‐ray exposure (CRE) ages and Mars ejection times were calculated from the radionuclide 81Kr and stable Kr isotopes for seven martian meteorites. The following 81Kr‐Kr CRE ages were obtained: Los Angeles = 3.35 ± 0.70 Ma; Queen Alexandra Range 94201 = 2.22 ± 0.35 Ma; Shergotty = 3.05 ± 0.50 Ma; Zagami = 2.98 ± 0.30 Ma; Nakhla = 10.8 ± 0.8 Ma; Chassigny = 10.6 ± 2.0 Ma; and Allan Hills 84001 = 15.4 ± 5.0 Ma. Comparison of these ages with previously obtained CRE ages from the stable noble gas nuclei 3He, 21Ne, and 38Ar shows excellent agreement. This indicates that the method for the production rate calculation for the stable nuclei is reliable. In all martian meteorites we observe effects induced by secondary cosmic‐ray produced epithermal neutrons. Epithermal neutron fluxes, φn (30–300 eV), are calculated based on the reaction 79Br(n, γβ)80Kr. We show that the neutron capture effects were induced in free space during Mars‐Earth transfer of the meteoroids and that they are not due to a pre‐exposure on Mars before ejection of the meteoritic material. Neutron fluxes and slowing down densities experienced by the meteoroids are calculated and pre‐atmospheric sizes are estimated. We obtain minimum radii in the range of 22–25 cm and minimum masses of 150–220 kg. These results are in good agreement with the mean sizes reported for model calculations using current semiempirical data.
Size‐frequency distributions of chondrules and chondrule fragments in LL3 chondrites: Implications for parent‐body fragmentation of chondrules
Authors: Nelson Victoria E. , Rubin Alan E.
Published: January 2010

Abstract— We measured the sizes and textural types of 719 intact chondrules and 1322 chondrule fragments in thin sections of Semarkona (LL3.0), Bishunpur (LL3.1), Krymka (LL3.1), Piancaldoli (LL3.4) and Lewis Cliff 88175 (LL3.8). The mean apparent diameter of chondrules in these LL3 chondrites is 0.80 φ units or 570 μm, much smaller than the previous rough estimate of ∼900 μm. Chondrule fragments in the five LL3 chondrites have a mean apparent cross‐section of 1.60 φ units or 330 μm. The smallest fragments are isolated olivine and pyroxene grains; these are probably phenocrysts liberated from disrupted porphyritic chondrules. All five LL3 chondrites have fragment/ chondrule number ratios exceeding unity, suggesting that substantial numbers of the chondrules in these rocks were shattered. Most fragmentation probably occurred on the parent asteroid. Porphyritic chondrules (porphyritic olivine + porphyritic pyroxene + porphyritic olivine‐pyroxene) are more readily broken than droplet chondrules (barred olivine + radial pyroxene + cryptocrystalline). The porphyritic fragment/chondrule number ratio (2.0) appreciably exceeds that of droplet‐textured objects (0.9). Intact droplet chondrules have a larger mean size than intact porphyritic chondrules, implying that large porphyritic chondrules are fragmented preferentially. This is consistent with the relatively low percentage of porphyritic chondrules within the set of the largest chondrules (57%) compared to that within the set of the smallest chondrules (81%). Differences in mean size among chondrule textural types may be due mainly to parent‐body chondrule‐fragmentation events and not to chondrule‐formation processes in the solar nebula.
Gas‐melt interactions and their bearing on chondrule formation
Authors: Tissandeer Laurent , Libourel Guy , Robert François
Published: January 2010

Abstract— Interactions between nebular gas and molten silicates or oxides could have played a major role in the formation and differentiation of the first solids formed in the solar system. In order to simulate such interactions, we set up a new experimental device in which isothermal condensation experiments have been conducted. Partially molten chondrule‐like samples have been exposed to high SiO(g) partial pressures, for intervals between 80 and 300 s and at temperatures ranging from 1600 to 1750 K. Results show that silica entering from the gas phase could be responsible for several textural and mineralogical features observed in natural chondrules. For instance, these experiments reproduce not only the mineralogical zonation of porphyritic olivine‐pyroxene chondrules with the peripheral location of pyroxenes, but also olivine resorption textures and the common poikilitical enclosure of olivines in pyroxenes. In the light of these similarities, we advocate that gas‐melt interactions through condensation are viable mechanisms for chondrule formation and hence may place severe constraints on the history of these primitive objects. In the nebula, high SiO(g) partial pressures could have been established by the volatilization of regions with high dust/gas ratio. A possible scenario for this stochastic thermal activity is the intense activity of the protosun in its young stellar object phase.
Discovery of an asteroid and quasi‐satellite in an Earth‐like horseshoe orbit
Authors: Connors Martin , Chodas Paul , Mikkola Seppo , Wiegert Paul , Veillet Christian , Innanen Kimmo
Published: January 2010

Abstract— The newly discovered asteroid 2002 AA29 moves in a very Earth‐like orbit that relative to Earth has a unique horseshoe shape and allows transitions to a quasi‐satellite state. This is the first body known to be in a simple heliocentric horseshoe orbit, moving along its parent planet's orbit. It is similarly also the first true co‐orbital object of Earth, since other asteroids in 1:1 resonance with Earth have orbits very dissimilar from that of our planet. When a quasi‐satellite, it remains within 0.2 AU of the Earth for several decades. 2002 AA29 is the first asteroid known to exhibit this behavior. 2002 AA29 introduces an important new class of objects offering potential targets for space missions and clues to asteroid orbit transfer evolution.
Plagioclase‐rich chondrules in the reduced CV chondrites: Evidence for complex formation history and genetic links between calcium‐aluminum‐rich inclusions and ferromagnesian chondrules
Authors: KROT Alexander N. , HUTCHEON Ian D. , KEIL Klaus
Published: January 2010

Abstract— Plagioclase‐rich chondrules (PRCs) in the reduced CV chondrites Efremovka, Leoville, Vigarano and Grosvenor Mountains (GRO) 94329 consist of magnesian low‐Ca pyroxene, Al‐Ti‐Cr‐rich pigeonite and augite, forsterite, anorthitic plagioclase, FeNi‐metal‐sulfide nodules, and crystalline mesostasis composed of silica, anorthitic plagioclase and Al‐Ti‐Cr‐rich augite. The silica grains in the mesostases of the CV PRCs are typically replaced by hedenbergitic pyroxenes, whereas anorthitic plagioclase is replaced by feldspathoids (nepheline and minor sodalite). Some of the PRCs contain regions that are texturally and mineralogically similar to type I chondrules and consist of forsterite, low‐Ca pyroxene and abundant FeNi‐metal nodules. Several PRCs are surrounded by igneous rims or form independent compound objects. Twelve PRCs contain relic calcium‐aluminum‐rich inclusions (CAIs) composed of anorthite, spinel, high‐Ca pyroxene, ± forsterite, and ± Al‐rich low‐Ca pyroxene. Anorthite of these CAIs is generally more heavily replaced by feldspathoids than anorthitic plagioclase of the host chondrules. This suggests that either the alteration predated formation of the PRCs or that anorthite of the relic CAIs was more susceptible to the alteration than anorthitic plagioclase of the host chondrules. These observations and the presence of igneous rims around PRCs and independent compound PRCs suggest that the CV PRCs may have had a complex, multistage formation history compared to a more simple formation history of the CR PRCs.

Relatively high abundances of moderately‐volatile elements such as Cr, Mn and Si in the PRCs suggests that these chondrules could not have been produced by volatilization of ferromagnesian chondrule precursors or by melting of refractory materials only. We infer instead that PRCs in carbonaceous chondrites formed by melting of the reduced chondrule precursors (magnesian olivine and pyroxene, FeNi‐metal) mixed with refractory materials (relic CAIs) composed of anorthite, spinel, high‐Ca pyroxene, and forsterite. The mineralogical, chemical and textural similarities of the PRCs in several carbonaceous chondrite groups (CV, CO, CH, CR) and common presence of relic CAIs in these chondrules suggest that PRCs may have formed in the region(s) intermediate between the regions where CAIs and ferromagnesian chondrules originated.
Fine‐grained rims in the Allan Hills 81002 and Lewis Cliff 90500 CM2 meteorites: Their origin and modification
Authors: HUA Xin , WANG Jianhua , BUSECK Peter R.
Published: January 2010

Abstract— Antarctic CM meteorites Allan Hills (ALH) 81002 and Lewis Cliff (LEW) 90500 contain abundant fine‐grained rims (FGRs) that surround a variety of coarse‐grained objects. FGRs from both meteorites have similar compositions and petrographic features, independent of their enclosed objects. The FGRs are chemically homogeneous at the 10 μm scale for major and minor elements and at the 25 μm scale for trace elements. They display accretionary features and contain large amounts of volatiles, presumably water. They are depleted in Ca, Mn, and S but enriched in P. All FGRs show a slightly fractionated rare earth element (REE) pattern, with enrichments of Gd and Yb and depletion of Er. Gd is twice as abundant as Er.

Our results indicate that those FGRs are not genetically related to their enclosed cores. They were sampled from a reservoir of homogeneously mixed dust, prior to accretion to their parent body. The rim materials subsequently experienced aqueous alteration under identical conditions. Based on their mineral, textural, and especially chemical similarities, we conclude that ALH 81002 and LEW 90500 likely have a similar or identical source.
Active capture and anomalous adsorption: New mechanisms for the incorporation of heavy noble gases
Authors: HOHENBERG C. M. , THONNARD N. , MESHIK A.
Published: January 2010

Abstract—Active capture is a new process for the incorporation of large quantities of heavy noble gases into growing surfaces. Adsorption in the conventional sense involves surface bonding by polarization (Van der Waals forces). What is referred to as “anomalous adsorption” of heavy noble gases involves chemical bonds and can occur when other (more chemically active) species are not available to preempt sites with unfilled bonds. Anomalous adsorption has been observed under conditions of fracture, vacuum deposition and ionizing radiation. Active capture depends upon anomalous adsorption to retain noble gases on a surface long enough to be captured in a growing surface film as it is deposited. The fundamental principle may be the impingement onto the growing film with sufficient energy to liberate surface electrons (work function energy of a few electronvolts) so that they are retained by anomalous adsorption long enough to be entrapped in the growing surface. Trapping efficiencies of ˜1% have been observed for Kr and Xe in laboratory experiments, implying a fundamentally new mechanism for the incorporation of heavy noble gases onto surfaces. It may play a role in explaining the large concentrations of planetary noble gases contained in phase‐Q.
Campo del Cielo iron meteorite: Sample shielding and meteoroid's preatmospheric size
Authors: LIBERMAN R. G. , NIELLO J. O. FERNÁNDEZ , DI TADA M. L. , FIFIELD L. K. , MASARIK J. , REEDY R. C.
Published: January 2010

Abstract— Long‐lived cosmogenic radioisotopes, 10Be, 26Al, 36Cl, 41Ca and 59Ni, have been measured in five samples from the Campo del Cielo iron meteorite by accelerator mass spectrometry (AMS). The 36Cl activities were significantly above the background. For the concentrations of the other four radioisotopes, only upper limits were obtained that were, however, consistent with the 36Cl result. The measured 36Cl activity allowed an estimate of the meteoroid's preatmospheric size: a radius larger than 300 cm and a mass of at least 840 000 kg. We conclude that this meteorite might be one of the largest meteorites to have been recovered.
Europa's dynamic icy crust
Authors: Greenberg Richard , Geissler Paul
Published: January 2010

Abstract—Europa's icy crust records active resurfacing by tectonic and thermal processes over tens of millions of years, as rapidity demonstrated by a paucity of craters. Tidal working causes rotational torque, surface stress, internal heating, and orbital evolution, which can explain the formation of observed tectonic crack patterns, ridges, crustal displacement, and chaotic terrain by processes involving connections between the surface and the underlying ocean through cracks, melt sites, and occasional impacts. These processes were recent, and thus most likely continue today. The permeability of the crust allows exchange of materials, including oxidants and exogenic organics from the surface and endogenic substances from the ocean, such that a habitable biosphere might extend to within a few centimeters of the surface. Continual changes in environmental conditions in the ice crust, such as deactivation of individual cracks after thousands of years (due to non‐synchronous rotation) and crustal thawing (releasing any trapped organisms), could provide drivers for biological adaptation, as well as opportunity for evolution.
Kgagodi Basin: The first impact structure recognized in Botswana
Authors: Brandt D. , Holmes H. , Reimold W. U. , Paya B. K. , Koeberl C. , Hancox P. J.
Published: January 2010

Abstract— The 3.4 km wide, so‐called Kgagodi Basin structure, which is centered at longitude 27°34.4′ E and latitude 22°28.6′ S in eastern Botswana, has been confirmed as a meteorite impact structure. This crater structure was first recognized through geophysical analysis; now, we confirm its impact origin by the recognition of shock metamorphosed material in samples from a drill core obtained close to the crater rim. The structure formed in Archean granitoid basement overlain and intruded by Karoo dolerite. The crater yielded a gravity model consistent with a simple bowl‐shape crater form. The drill core extends to a depth of 274 m and comprises crater fill sediments to a depth of 158 m. Impact breccia was recovered only between 158 and 165 m depth, below which locally brecciated basement granitoids grade into fractured and eventually undeformed crystalline basement, from ∼250 m depth. Shock metamorphic effects were only found in granitoid clasts in the narrow breccia zone. This breccia is classified as suevitic impact breccia due to the presence of melt and glass fragments, at a very small abundance. The shocked grains are exclusively derived from granitoid target material. Shock effects include multiple sets of planar deformation features in quartz and feldspar; diaplectic quartz, and partially and completely isotropized felsic minerals, and rare melt fragments were encountered. Abundances of some siderophile elements and especially, Ir, in suevitic breccia samples are significantly elevated compared to the contents in the target rocks, which provides evidence for the presence of a small meteoritic component.

Kgagodi is the first impact structure recognized in the region of the Kalahari Desert in southern Africa. Based on lithological and first palynological evidence, the age of the Kgagodi structure is tentatively assigned to the upper Cretaceous to early Tertiary interval. Thus, the crater fill has the potential to provide a long record of paleoclimatic conditions.
Mineralogy and petrology of amoeboid olivine inclusions in CO3 chondrites: Relationship to parent‐body aqueous alteration
Authors: Chizmadia Lysa J. , Rubin Alan E. , Wasson John T.
Published: January 2010

Abstract— Petrographic and mineralogic studies of amoeboid olivine inclusions (AOIs) in CO3 carbonaceous chondrites reveal that they are sensitive indicators of parent‐body aqueous and thermal alteration. As the petrologic subtype increases from 3.0 to 3.8, forsteritic olivine (Fa0–1) is systematically converted into ferroan olivine (Fa60–75). We infer that the Fe, Si and O entered the assemblage along grain boundaries, forming ferroan olivine that filled fractures and voids. As temperatures increased, Fe+2 from the new olivine exchanged with Mg+2 from the original AOI to form diffusive haloes around low‐FeO cores. Cations of Mn+2, Ca+2 and Cr+3 were also mobilized.

The systematic changes in AOI textures and olivine compositional distributions can be used to refine the classification of CO3 chondrites into subtypes. In subtype 3.0, olivine occurs as small forsterite grains (Fa0–1), free of ferroan olivine. In petrologic subtype 3.2, narrow veins of FeO‐rich olivine have formed at forsterite grain boundaries. With increasing alteration, these veins thicken to form zones of ferroan olivine at the outside AOI margin and within the AOI interior. By subtype 3.7, there is a fairly broad olivine compositional distribution in the range Fa63–70, and by subtype 3.8, no forsterite remains and the high‐Fa peak has narrowed, Fa64–67. Even at this stage, there is incomplete equilibration in the chondrite as a whole (e.g., data for coarse olivine grains in Isna (CO3.8) chondrules and lithic clasts show a peak at Fa39). We infer that the mineral changes in AOI identified in the low petrologic types required aqueous or hydrothermal fluids whereas those in subtypes ?3.3 largely reflect diffusive exchange within and between mineral grains without the aid of fluids.
Clay mineral‐organic matter relationships in the early solar system
Authors: Pearson Victoria K. , Sephton Mark A. , Kearsley Anton T. , Bland Philip A. , Franchi Ian A. , Gilmour Iain
Published: January 2010

Abstract— As the solar system formed, it inherited and perpetuated a rich organic chemistry, the molecular products of which are preserved in ancient extraterrestrial objects such as carbonaceous chondrites. These organic‐rich meteorites provide a valuable and tangible record of the chemical steps taken towards the origin of life in the early solar system. Chondritic organic matter is present in the inorganic meteorite matrix which, in the CM and CI chondrites, contains evidence of alteration by liquid water on the parent asteroid. An unanswered and fundamental question is to what extent did the organic matter and inorganic products of aqueous alteration interact or display interdependence? We have used an organic labelling technique to reveal that the meteoritic organic matter is strongly associated with clay minerals. This association suggests that clay minerals may have had an important trapping and possibly catalytic role in chemical evolution in the early solar system prior to the origin of life on the early Earth.
Domenico Troili (1766): “The true cause of the fall of a stone in Albereto is a subterranean explosion that hurled the stone skyward”
Authors: Marvin Ursula B. , Cosmo Mario L.
Published: January 2010

Abstract—In mid‐July, 1766, a stone fell at Villa Albareto near Modena in northern Italy. A sudden explosion like a cannon shot followed by fierce whistling sounds frightened people over a wide area. Some saw a fiery body falling from the sky; others said it was dark and smoky. The ground shook when the stone plunged into the soil making a hole nearly a meter deep. The Abbé Domenico Troili collected eyewitness reports, examined the stone, and reported the presence of marchesita, an old name for pyrite. A century later, this mineral, which proved to be iron sulfide (FeS), was named “troilite” in his honor. Troili's description is unquestionably that of a meteorite fall, and therefore some scientists have argued that it is Troili, rather than Ernst F. F. Chladni, to whom we should give credit as the first person to record the fall of a stone from space. However, Troili, himself, had no such an idea; he wrote that a subterranean explosion had hurled the stone high into the sky from a vent in the Earth. He stoutly defended this explanation against his opponents, including the Bishop of Modena, who believed that the stone had been hurled aloft by a bolt of lightning. Both hypotheses reflect a conviction, held well into the nineteenth century, that any rocky objects that fall from the sky must originate on the Earth or in the atmosphere. In 1794, Chladni calculated that meteors and meteoritic fireballs course down the sky at such extremely high velocities that the bodies forming them must originate in space. He listed all the falls that he found credible in historic records. Partly through his efforts, meteorites had gained widespread acceptance by 1803, but the idea of their origin in space had not. For the next half century many scientists continued to argue that meteorites either consolidate in the upper atmosphere or are ejected by volcanoes on the Moon. Recent efforts to transfer honors from Chladni to Troili for being the first to describe meteorites as bodies falling from space are unwarranted.
First discovery of stishovite in an iron meteorite
Authors: Holtstam Dan , Broman Curt , Söderhielm Johan , Zetterqvist Anders
Published: January 2010

Abstract— The first occurrence of stishovite in an iron meteorite, Muonionalusta (group IVA), is reported. The mineral occurs intimately mixed with amorphous silica, forming tabular grains up to ˜3 mm wide, with a hexagonal outline. It was identified using X‐ray diffraction and Raman microspectroscopy. The unit‐cell parameters of stishovite are a = 4.165(3) Å and c = 2.661(6) Å, and its chemical composition is nearly pure SiO2. Raman spectra show relatively sharp bands at 231 and 754 cm−1 and a broad band with an asymmetric shape and a maximum around 500 cm−1. The rare grains are found within troilite nodules together with chromite, daubreelite, and schreibersite. From their composition and morphology, and by comparisons with silica inclusions in, e.g., the Gibeon IVA iron, we conclude that these rare grains represent pseudomorphs after tridymite. The presence of stishovite in Muonionalusta is suggested to reflect shock metamorphic conditions in the IVA parent asteroid during a cosmic impact event.
Noble gas isotopes and mineral assemblages of Antarctic micrometeorites collected at the meteorite ice field around the Yamato Mountains
Authors: Osawa Takahito , Nakamura Tomoki , Nagao Keisuke
Published: January 2010

Abstract— From November 1998 to January 1999, the 39th Japanese Antarctic Research Expedition (JARE) conducted a large‐scale micrometeorite collection at 3 areas in the meteorite ice field around the Yamato Mountains, Antarctica. The Antarctic micrometeorites (AMMs) collected were ancient cosmic dust particles. This is in contrast with the Dome Fuji AMMs, which were collected previously from fresh snows in 1996 and 1997 and which represent modern micrometeorites. To determine the noble gas concentrations and isotopic compositions of individual AMMs, noble gas analyses were carried out using laser‐gas extraction for 35 unmelted Yamato Mountains AMMs and 3 cosmic spherules. X‐ray diffraction analyses were performed on 13 AMMs before the noble gas measurement and mineral compositions were determined.

AMMs are classified into 4 main mineralogical groups, defined from the heating they suffered during atmospheric entry. Heating temperatures of AMMs, inferred from their mineral compositions, are correlated with 4He concentrations and reflect the effect of degassing during atmospheric entry. Jarosite, an aqueous alteration product, is detected for 4 AMMs, indicating the aqueous alteration during long‐time storage in Antarctic ice. Jarosite‐bearing AMMs have relatively low concentrations of 4He, which is suggestive of loss during the alteration.

High 3He/4He ratios are detected for AMMs with high 20Ne/4He ratios, showing both cosmogenic 3He and preferential He loss. SEP (solar energetic particles)‐He and Ne, rather than the solar wind (SW), were dominant in AMMs, presumably showing a preferential removal of the more shallowly implanted SW by atmospheric entry heating. The mean 20Ne/22Ne ratio is 11.27 ± 0.35, which is close to the SEP value of 11.2. Cosmogenic 21Ne is not detected in any of the particles, which is probably due to the short cosmic ray exposure ages. Ar isotopic compositions are explained by 3‐component mixing of air, Q, and SEP‐Ar. Ar isotopic compositions can not be explained without significant contributions of Q‐Ar. SEP‐Ne contributed more than 99% of the total Ne. As for 36Ar and 38Ar, the abundance of the Q component is comparable to that of the SEP component. 84Kr and 132Xe are dominated by the primordial component, and solar‐derived Xe is almost negligible.
Impact glasses in fallout suevites from the Ries impact structure, Germany: An analytical SEM study
Authors: Osinski Gordon R.
Published: January 2010

Abstract— t‐Impact‐generated glasses from fallout suevite deposits at the Ries impact structure have been investigated using analytical scanning electron microscopy. Approximately 320 analyses of glass clasts were obtained. Four glass types are distinguished on the basis of composition and microtextures. Type 1 glasses correspond to the aerodynamically shaped glass bombs studied previously by many workers. Major oxide concentrations indicate the involvement of granitic rocks, amphibolites, and minor Al‐rich gneisses during melting. Type 2 glasses are chemically heterogeneous, even within individual clasts, with variations of several wt% in most of the major oxides (e.g., 57–70 wt% SiO2). This suggests incomplete mixing of: 1) mineral‐derived melts or 2) whole rock melts from a wide range of lithologies. Aluminium‐rich clinopyroxene and Fe‐Mg‐rich plagioclase quench crystals are present in type 1 and 2 glasses, respectively. Type 3 glasses contain substantial amounts of H2O (˜12–17 wt%), low SiO2 (50–53 wt%), high Al2O3 (17–21 wt%), and high CaO (5–7 wt%) contents. This suggests an origin due to shock melting of part of the sedimentary cover. Type 4 glasses form a ubiquitous component of the suevites. Based on their high SiO2 content (˜85–100 wt%), the only possible protolith are sandstones in the lowermost part of the sedimentary succession. Calcite forms globules within type 1 glasses, with which it develops microtextures indicative of liquid immiscibility. Unequivocal evidence also exists for liquid immiscibility between what are now montmorillonite globules and type 1, 2, and 4 glasses, indicating that montmorillonite was originally an impact melt glass. Clearly, the melt zone at the Ries must have incorporated a substantial fraction of the sedimentary cover, as well as the underlying crystalline basement rocks. Impact melts were derived from different target lithologies and these separate disaggregated melts did not substantially mix in most cases (type 2, 3, and 4 glasses and carbonate melts).
Ordinary chondrite metallography: Part 1. Fe‐Ni taenite cooling experiments
Authors: Reisener R. J. , Goldstein J. I.
Published: January 2010

Abstract— Cooling rate experiments were performed on P‐free Fe‐Ni alloys that are compositionally similar to ordinary chondrite metal to study the taenite ŕ taenite + kamacite reaction. The role of taenite grain boundaries and the effect of adding Co and S to Fe‐Ni alloys were investigated. In P‐free alloys, kamacite nucleates at taenite/taenite grain boundaries, taenite triple junctions, and taenite grain corners. Grain boundary diffusion enables growth of kamacite grain boundary precipitates into one of the parent taenite grains. Likely, grain boundary nucleation and grain boundary diffusion are the applicable mechanisms for the development of the microstructure of much of the metal in ordinary chondrites. No intragranular (matrix) kamacite precipitates are observed in P‐free Fe‐Ni alloys. The absence of intragranular kamacite indicates that P‐free, monocrystalline taenite particles will transform to martensite upon cooling. This transformation process could explain the metallography of zoneless plessite particles observed in H and L chondrites. In P‐bearing Fe‐Ni alloys and iron meteorites, kamacite precipitates can nucleate both on taenite grain boundaries and intragranularly as Widmanstätten kamacite plates. Therefore, P‐free chondritic metal and P‐bearing iron meteorite/pallasite metal are controlled by different chemical systems and different types of taenite transformation processes.
A petrogenetic model for the origin and compositional variation of the martian basaltic meteorites
Authors: BORG Lars E. , DRAPER David S.
Published: January 2010

Abstract— The major element, trace element, and isotopic compositional ranges of the martian basaltic meteorite source regions have been modeled assuming that planetary differentiation resulted from crystallization of a magma ocean. The models are based on low to high pressure phase relationships estimated from experimental runs and estimates of the composition of silicate Mars from the literature. These models attempt to constrain the mechanisms by which the martian meteorites obtained their superchondritic CaO/Al2O3 ratios and their source regions obtained their parent/daughter (87Rb/86Sr, 147Sm/144Nd, and 176Lu/177Hf) ratios calculated from the initial Sr, Nd, and Hf isotopic compositions of the meteorites. High pressure experiments suggest that majoritic garnet is the liquidus phase for Mars relevant compositions at or above 12 GPa. Early crystallization of this phase from a martian magma ocean yields a liquid characterized by an elevated CaO/Al2O3 ratio and a high Mg#. Olivine‐pyroxene‐garnet‐dominated cumulates that crystallize subsequently will also be characterized by superchondritic CaO/Al2O3 ratios. Melting of these cumulates yields liquids with major element compositions that are similar to calculated parental melts of the martian meteorites. Furthermore, crystallization models demonstrate that some of these cumulates have parent/daughter ratios that are similar to those calculated for the most incompatible‐element‐depleted source region (i.e., that of the meteorite Queen Alexandra [QUE] 94201).

The incompatible‐element abundances of the most depleted (QUE 94201‐like) source region have also been calculated and provide an estimate of the composition of depleted martian mantle. The incompatible‐element pattern of depleted martian mantle calculated here is very similar to the pattern estimated for depleted Earth's mantle. Melting the depleted martian mantle composition reproduces the abundances of many incompatible elements in the parental melt of QUE 94201 (e.g., Ba, Th, K, P, Hf, Zr, and heavy rare earth elements) fairly well but does not reproduce the abundances of Rb, U, Ta and light rare earth elements. The source regions for meteorites such as Shergotty are successfully modeled as mixtures of depleted martian mantle and a late stage liquid trapped in the magma ocean cumulate pile. Melting of this hybrid source yields liquids with major element abundances and incompatible‐element patterns that are very similar to the Shergotty bulk rock.
Composition of the first bulk melt sample from a volcanic region of Mars: Queen Alexandra Range 94201
Authors: KRING David A. , GLEASON James D. , SWINDLE Timothy D. , NISHIIZUMI Kunihiko , CAFFEE Marc W. , HILL Dolores H. , JULL A. J. Timothy , BOYNTON William V.
Published: January 2010

Abstract— Antarctic meteorite Queen Alexandra Range (QUE) 94201 is a 12 g basaltic achondrite dominated by plagioclase (now maskelynite) and zoned low‐ and high‐Ca pyroxene. Petrologic, geochemical, and isotopic analyses indicate that it is related to previously described basaltic and Iherzolitic shergottites, which are a group of igneous meteorites that are believed to be from Mars. Unlike previous shergottites, however, QUE 94201 represents a bulk melt rather than a cumulate fraction, meaning it can be used to infer magmatic source regions and the compositions of other melts on Mars. This melt has much more Fe and P than basaltic melts produced on Earth and formed at a much lower oxygen fugacity. This has altered the crystallization sequence of the melt, removing olivine from the liquidus to produce a plagioclase and 2‐pyroxene assemblage. If the high‐phosphorus and low‐oxygen fugacity conditions represented by QUE 94201 are common in magmatic regions of Mars, then olivine may be rare in marrian basalts. No solar cosmic ray effects were seen in the concentrations of 10Be, 26A1, and 36C1 with depth in the meteorite, implying at least 3 cm of ablation during entry to Earth. Significant excesses of neutron capture noble gas isotopes (80,82Kr and 128,131Xe) suggest that the QUE 94201 sample came from a depth >22 cm in a meteoroid of at least that radius. The meteorite also has very low 21Ne/22Ne, which would often be interpreted to mean little ablation (contradicting above evidence) but, in this case, appears to reflect a very low abundance of Mg (the principal target element for Ne) in the meteorite, consistent with our bulk chemical analyses. The meteorite has a terrestrial 36C1 age of 0.29 ± 0.05 Myr and a 10Be exposure age of 2.6 ± 0.5 Myr in a 47π geometry, implying an ejection age of 2.9 ± 0.5 Myr.
KREEPy lunar meteorite Dhofar 287A: A new lunar mare basalt
Authors: Anand Mahesh , Taylor Lawrence A. , Misra Kula C. , Demidova Svetlana I. , Nazarov Mikhail A.
Published: January 2010

Abstract— Dhofar 287 (Dho 287) is a new lunar meteorite, found in Oman on January 14, 2001. The main portion of this meteorite (Dho 287A) consists of a mare basalt, while a smaller portion of breccia (Dho 287B) is attached on the side. Dho 287A is only the fourth crystalline mare basalt meteorite found on Earth to date and is the subject of the present study. The basalt consists mainly of phenocrysts of olivine and pyroxene set in a finer‐grained matrix, which is composed of elongated pyroxene and plagioclase crystals radiating from a common nucleii. The majority of olivine and pyroxene grains are zoned, from core to rim, in terms of Fe and Mg. Accessory minerals include ilmenite, chromite, ulvöspinel, troilite, and FeNi metal. Chromite is invariably mantled by ulvöspinel. This rock is unusually rich in late‐stage mesostasis, composed largely of fayalite, Si‐K‐Ba‐rich glass, fluorapatite, and whitlockite. In texture and mineralogy, Dho 287A is a low‐Ti mare basalt, with similarities to Apollo 12 (A‐12) and Apollo 15 (A‐15) basalts. However, all plagioclase is now present as maskelynite, and its composition is atypical for known low‐Ti mare basalts. The Fe to Mn ratios of olivine and pyroxene, the presence of FeNi metal, and the bulk‐rock oxygen isotopic ratios, along with several other petrological features, are evidence for the lunar origin for this meteorite.

Whole‐rock composition further confirms the similarity of Dho 287A with A‐12 and A‐15 samples but requires possible KREEP assimilation to account for its rare‐earth‐element (REE) contents. Cooling‐rate estimates, based on Fo zonation in olivine, yield values of 0.2–0.8°C/hr for the lava, typical for the center of a 10–20 m thick flow. The recalculated major‐element concentrations, after removing 10–15% modal olivine, are comparable to typical A‐15 mare basalts. Crystallization modeling of the recalculated Dho 287A bulk‐composition yields a reasonable fit between predicted and observed mineral abundances and compositions.
Lunar regolith breccia Dhofar 287B: A record of lunar volcanism
Authors: Demidova S. I. , Nazarov M. A. , Anand M. , Taylor L. A.
Published: January 2010

Abstract— Dhofar 287 (Dho 287), a recently found lunar meteorite, consists in large part (95%) of low‐Ti mare basalt (Dho 287A) and a minor, attached portion (˜5%) of regolith breccia (Dho 287B). The present study is directed mainly at the breccia portion of this meteorite. This breccia consists of a variety of lithic clasts and mineral fragments set in a fine‐grained matrix and minor impact melt. The majority of clasts and minerals appear to have been mainly derived from the low‐Ti basalt suite, similar to that of Dho 287A. Very low‐Ti (VLT) basalts are a minor lithology of the breccia. These are significantly lower in Mg# and slightly higher in Ti compared to Luna 24 and Apollo 17 VLT basalts. Picritic glasses constitute another minor component of the breccia and are compositionally similar to Apollo 15 green glasses. Dho 287B also contains abundant fragments of Mg‐rich pyroxene and anorthite‐rich plagioclase grains that are absent in the lithic clasts. Such fragments appear to have been derived from a coarse‐grained, Mg#‐rich, Na‐poor lithology. A KREEP component is apparent in chemistry, but no highlands lithologies were identified.

The Dho 287 basaltic lithologies cannot be explained by near‐surface fractionation of a single parental magma. Instead, magma compositions are represented by a picritic glass; a low‐Ti, Na‐poor glass; and a low‐Ti, Na‐enriched source (similar to the Dho 287A parental melt). Compositional differences among parent melts could reflect inhomogeneity of the lunar mantle. Alternatively, the low‐Ti, Na‐poor, and Dho 287A parent melts could be of hybrid compositions, resulting from assimilation of KREEP by picritic magma. Thus, the Dho 287B breccia contains lithologies from multiple magmatic eruptions, which differed in composition, formational conditions, and cooling histories. Based on this study, the Dho 287 is inferred to have been ejected from a region located distal to highlands terrains, possibly from the western limb of the lunar nearside, dominated by mare basalts and KREEP‐rich lithologies.