bluuebunny/crossref_metadata_2025 huggingface dataset:
Ceramic-Based Piezoelectric Material for Energy Harvesting Using Hybrid Excitation
Authors: Ambrożkiewicz Bartłomiej , Czyż Zbigniew , Karpiński Paweł , Stączek Paweł , Litak Grzegorz , Grabowski Łukasz
Published: October 2021

This paper analyzes the energy efficiency of a Micro Fiber Composite (MFC) piezoelectric system. It is based on a smart Lead Zirconate Titanate material that consists of a monolithic PZT (piezoelectric ceramic) wafer, which is a ceramic-based piezoelectric material. An experimental test rig consisting of a wind tunnel and a developed measurement system was used to conduct the experiment. The developed test rig allowed changing the air velocity around the tested bluff body and the frequency of forced vibrations as well as recording the output voltage signal and linear acceleration of the tested object. The mechanical vibrations and the air flow were used to find the optimal performance of the piezoelectric energy harvesting system. The performance of the proposed piezoelectric wind energy harvester was tested for the same design, but of different masses. The geometry of the hybrid bluff body is a combination of cuboid and cylindrical shapes. The results of testing five bluff bodies for a range of wind tunnel air flow velocities from 4 to 15 m/s with additional vibration excitation frequencies from 0 to 10 Hz are presented. The conducted tests revealed the areas of the highest voltage output under specific excitation conditions that enable supplying low-power sensors with harvested energy.
Durability Properties of Ultra-High Performance Lightweight Concrete (UHPLC) with Expanded Glass
Authors: Umbach Cristin , Wetzel Alexander , Middendorf Bernhard
Published: October 2021

It is important to ensure the durability and safety of structures. In the case of newly developed materials that are outside the current rules, it is important to investigate all aspects of structural safety. The material studied in the following is a structural lightweight concrete with an ultra-high-performance matrix and expanded glass as a lightweight aggregate. The material, with a compressive strength of 60–100 MPa and a bulk density of 1.5–1.9 kg/dm3, showed high capillary porosities of 12 vol% (ultra-high-performance concretes (UHPC) < 5 vol%). Since the capillary porosity basically enables transport processes into the concrete, the material had to be examined more closely from the aspect of durability. Freeze-thaw resistance (68 g/m2) and chemical attack with sulfate at pH 3.5 for 12 weeks (16 g/m2) showed no increase in concrete corrosion. Targeted carbonation (0.53 mm/year0.5) and chloride penetration resistance (6.0 × 10−13 to 12.6 × 10−13 m2/s) also showed good results against reinforcement corrosion. The results show that most of the measured capillary pores resulted from the lightweight aggregate and were not all present as a pore system. Thus, the durability was only slightly affected and the concrete can be compared to an UHPC. Only the abrasion resistance showed an increased value (22,000 mm3/5000 mm2), which, however, only matters if the material is used as a screed.
Nutrients Recovery from Dairy Wastewater by Struvite Precipitation Combined with Ammonium Sorption on Clinoptilolite
Authors: Numviyimana Claver , Warchoł Jolanta , Ligas Bartosz , Chojnacka Katarzyna
Published: October 2021

Struvite precipitation from Wastewater involves an excess of ammonium to create a supersaturated initial solution. The remaining fraction can be a threat to the environment. This work combined struvite precipitation and ammonium sorption using natural zeolite to decrease the ammonium level in the effluent. Two approaches of estimation of feed sample doses were used. One consisted of gradient experiments for ammonium precipitation to the asymptotic level and was combined with clinoptilolite to lower the ammonium level in the effluent. This approach used doses of 0.05:1.51:0.61:1 of Ca:Mg:NH4+:PO43− mole ratios, respectively. In contrast, three level design with narrowed NH4+:PO43− range reached 0.25:1.51:0.8:1 for Ca:Mg:NH4+:PO43− mole ratios. The addition of zeolite decreased effluent ammonium concentration. In both ways, the P and N recoveries were higher than 94% and 72%, respectively. The complexity of the precipitation mixture decreased the ammonium sorption capacity (Qe) of clinoptilolite from Qe of 0.52 to 0.10 meq∙g−1 in single and complex solutions, respectively. Thermodynamically, the addition of 1.5 % of clinoptilolite changed the struvite precipitation spontaneity from ∆G of −5.87 to −5.42 kJ·mol−1 and from 9.66 to 9.56 kJ·mol−1 for gradient and three level experimental procedures, respectively. Thus, clinoptilolite demonstrated a positive effect on the struvite precipitation process and its environmental impact.
Characteristics of Mortars with Blast Furnace Slag Powder and Mixed Fine Aggregates Containing Ferronickel-Slag Aggregate
Authors: Bae Sung-Ho , Lee Jae-In , Choi Se-Jin
Published: October 2021

Recently, interest in environmentally friendly development has increased worldwide, especially in the construction industry. In this study, blast furnace slag powder (BFSP) and mixed steel fine aggregates were applied to cement mortars to reduce the environmental damage caused by the extraction of natural aggregate and to increase the recycling rate of steel by-products in the construction industry. We investigated the fluidity, compressive strength, tensile strength, accelerated carbonation depth, and chloride ion penetration resistance of mortars with steel slag aggregate and their dependence on the presence or absence of BFSP. Because the recycling rate of ferronickel slag is low and causes environmental problems, we considered mortar samples with mixed fine aggregates containing blast furnace slag fine aggregate (BSA) and ferronickel slag fine aggregate (FSA). The results showed that the 7-day compressive strength of a sample containing both 25% BSA and 25% FSA was nearly 14.8% higher than that of the control sample. This trend is likely due to the high density and angular shape of steel slag particles. The 56-day compressive strength of the sample with BFSP and 50% FSA was approximately 64.9 MPa, which was higher than that of other samples with BFSP. In addition, the chloride ion penetrability test result indicates that the use of BFSP has a greater effect than the use of steel slag aggregate on the chloride ion penetration resistance of mortar. Thus, the substitute rate of steel slag as aggregate can be substantially enhanced if BFSP and steel slag aggregate are used in an appropriate combination.
Mechanical Properties of Aramid/Carbon Hybrid Fiber-Reinforced Concrete
Authors: Li Yeou-Fong , Wang Hsin-Fu , Syu Jin-Yuan , Ramanathan Gobinathan Kadagathur , Tsai Ying-Kuan , Lok Man Hoi
Published: October 2021

In this study, aramid fiber (Kevlar® 29 fiber) and carbon fiber were added into concrete in a hybrid manner to enhance the static and impact mechanical properties. The coupling agent presence on the surface of carbon fibers was spotted in Scanning Electron Microscope (SEM) and energy-dispersive X-ray spectroscopy (EDS) graphs. The carbon fiber with a coupling agent affected the mechanical strength of the reinforced concrete. At 1% fiber/cement weight percentage, the hybrid fiber-reinforced concrete (HFRC) prepared using Kevlar fiber and carbon fiber of 12 and 24 mm in length under different mix proportions was investigated to determine the maximum mechanical strengths. From the test results, the mechanical strength of the HFRC attained better performance than that of the concrete with only Kevlar or carbon fibers. Foremost, the mix proportion of Kevlar/carbon fiber (50–50%) significantly improved the compressive, flexural, and splitting tensile strengths. Under different impact energies, the impact resistance of the HFRC specimen was much higher than that of the benchmark specimen, and the damage of the HFRC specimens was examined with an optical microscope to identify slippage or rupture failure of the fiber in concrete.
Modelling of Friction Phenomena Existed in Drawbead in Sheet Metal Forming
Authors: Trzepieciński Tomasz , Kubit Andrzej , Fejkiel Romuald , Chodoła Łukasz , Ficek Daniel , Szczęsny Ireneusz
Published: October 2021

The article presents the results of friction tests of a 0.8 mm-thick DC04 deep-drawing quality steel sheet. A special friction simulator was used in the tests, reflecting friction conditions occurring while pulling a sheet strip through a drawbead in sheet metal forming. The variable parameters in the experimental tests were as follows: surface roughness of countersamples, lubrication conditions, sample orientation in relation to the sheet rolling direction as well as the sample width and height of the drawbead. Due to many factors that affect the value of the coefficient of friction coefficient, artificial neural networks (ANNs) were used to build and analyse the friction model. Four training algorithms were used to train the ANNs: back propagation, conjugate gradients, quasi-Newton and Levenberg–Marquardt. It was found that for all analysed friction conditions and sheet strip widths, increasing the drawbead height increases the COF value. The chlorine-based Heavy Draw 1150 compound provides a more effective friction reduction compared to a LAN-46 machine oil.
Micropipes in SiC Single Crystal Observed by Molten KOH Etching
Authors: Wang Hejing , Yu Jinying , Hu Guojie , Peng Yan , Xie Xuejian , Hu Xiaobo , Chen Xiufang , Xu Xiangang
Published: October 2021

Micropipe, a “killer” defect in SiC crystals, severely hampers the outstanding performance of SiC-based devices. In this paper, the etching behavior of micropipes in 4H-SiC and 6H-SiC wafers was studied using the molten KOH etching method. The spectra of 4H-SiC and 6H-SiC crystals containing micropipes were examined using Raman scattering. A new Raman peak accompanying micropipes located near −784 cm−1 was observed, which may have been induced by polymorphic transformation during the etching process in the area of micropipe etch pits. This feature may provide a new way to distinguish micropipes from other defects. In addition, the preferable etching conditions for distinguishing micropipes from threading screw dislocations (TSDs) was determined using laser confocal microscopy, scanning electron microscopy (SEM) and optical microscopy. Meanwhile, the micropipe etching pits were classified into two types based on their morphology and formation mechanism.
A Brief Photocatalytic Study of ZnO Containing Cerium towards Ibuprofen Degradation
Authors: Sá Alexandro S. , Feitosa Rodrigo P. , Honório Luzia , Peña-Garcia Ramón , Almeida Luciano C. , Dias Juliana S. , Brazuna Lorena P. , Tabuti Thiago G. , Triboni Eduardo R. , Osajima Josy A. , da Silva-Filho Edson C.
Published: October 2021

Ibuprofen (IBU) is one of the most-sold anti-inflammatory drugs in the world, and its residues can reach aquatic systems, causing serious health and environmental problems. Strategies are used to improve the photocatalytic activity of zinc oxide (ZnO), and thosethat involvethe inclusion of metalhave received special attention. The aim of this work was to investigate the influence of the parameters and toxicity of a photoproduct using zinc oxide that contains cerium (ZnO-Ce) for the photodegradation of ibuprofen. The parameters include the influence of the photocatalyst concentration (0.5, 0.5, and 1.5 g L−1) as well as the effects of pH (3, 7, and 10), the effect of H2O2, and radical scavengers. The photocatalyst was characterized by Scanning Electron Microscopy-Energy Dispersive Spectroscopy, Transmission electron microscopy, Raman, X-Ray Diffraction, surface area, and diffuse reflectance. The photocatalytic activity of ibuprofen was evaluated in an aqueous solution under UV light for 120 min. The structural characterization by XRD and SEM elucidated the fact that the nanoparticle ZnO contained cerium. The band gap value was 3.31 eV. The best experimental conditions for the photodegradation of IBU were 60% obtained in an acidic condition using 0.50 g L−1 of ZnO-Ce in a solution of 20 ppm of IBU. The presence of hydrogen peroxide favored the photocatalysis process. ZnO-Ce exhibited good IBU degradation activity even after three photocatalytic cycles under UV light. The hole plays akey role in the degradation process of ibuprofen. The toxicity of photolyzed products was monitored against Artemia salina (bioindicator) and did not generate toxic metabolites. Therefore, this work provides a strategic design to improve ZnO-Ce photocatalysts for environmental remediation.
The Numerical Modelling Approach with a Random Distribution of Mechanical Properties for a Mismatched Weld
Authors: Starčevič Luka , Gubeljak Nenad , Predan Jožef
Published: October 2021

The aim of this work was to include a local variation in material properties to simulate the fracture behaviour in a multi-pass mis-matched X-weld joint. The base material was welded with an over and under-match strength material. The local variation was represented in a finite element model with five material groups in the weld and three layers in the heat-affected zone. The groups were assigned randomly to the elements within a region. A three-point single edge notch bending (SENB) fracture mechanics specimen was analysed for two different configurations where either the initial crack is in the over or under-matched material side to simulate experimentally obtained results. The used modelling approach shows comparable crack propagation and stiffness behaviour, as well as the expected, scatter and instabilities of measured fracture behaviour in inhomogeneous welds.
Structure-Property Relationships of Polyamide 12 Grades Exposed to Rapid Crack Extension
Authors: Messiha Mario , Frank Andreas , Heimink Jan , Arbeiter Florian , Pinter Gerald
Published: October 2021

Thermoplastic materials have established a reputation for long-term reliability in low-pressure gas and water distribution pipe systems. However, occasional Slow Crack Growth (SCG) and Rapid Crack Propagation (RCP) failures still occur. SCG may initiate only a small leak, but it has the potential to trigger RCP, which is much rarer but more catastrophic and destructive. RCP can create a long, straight or meandering axial crack path at speeds of up to hundreds of meters per second. It is driven by internal (residual) and external (pressure) loads and resisted by molecular and morphological characteristics of the polymer. The safe installation and operation of a pipe throughout its service lifetime therefore requires knowledge of its resistance to RCP, particularly when using new materials. In this context, the RCP resistance of five different polyamide (PA) 12 grades was investigated using the ISO 13477 Small-Scale Steady State (S4) test. Since these grades differed not only in molecular weight but also in their use of additives (impact modifiers and pigments), structure-property relationships could be deduced from S4 test results. A new method is proposed for correlating these results more efficiently to evaluate each grade using the crack arrest lengths from individual S4 test specimens.
Lightweight Concretes with Improved Water and Water Vapor Transport for Remediation of Damp Induced Buildings
Authors: Pokorný Jaroslav , Ševčík Radek , Šál Jiří , Zárybnická Lucie , Žák Jaroslav
Published: October 2021

Most of the historical and old building stock in Europe are constructed from masonry, when brick, stones, or their combination are bound with traditional mortars. Rising damp, due to accompanying effects, is the main factor influencing the quality of indoor climate as well as having an important impact on the durability of masonry structures. In this study, new types of lightweight concrete with waste aggregate content as a suitable material for remediation of damp damaged masonries were designed and tested. Alternative aggregate served as silica sand substitution in the range of 0–100 vol.%. Basic structural properties, mechanical resistance, water, and water vapor transport properties were measured after 28 days of water curing and were compared with dense reference concrete and with traditional masonry materials as well. Moreover, the porous structure of produced concretes and changes caused by usage of alternative aggregate usage were evaluated with the mercury intrusion porosimetry (MIP) technique. Obtained experimental data showed the suitability of modified concretes with 25–50 vol.% of waste aggregate content to ensure acceptable strength and hydric properties, and these properties were found to be comparable with masonry structures and materials used in the past.
Improving the Properties of Composite Titanium Nitride Layers on the AZ91D Magnesium Alloy Using Hydrothermal Treatment
Authors: Tacikowski Michał , Kamiński Janusz , Rożniatowski Krzysztof , Pisarek Marcin , Jakieła Rafał , Marchlewski Paweł , Wierzchoń Tadeusz
Published: October 2021

Coating magnesium alloys with nitride surface layers is a prospective way of improving their intrinsically poor surface properties; in particular, their tribological and corrosion resistance. These layers are usually produced using PVD methods using magnetron sputtering or arc evaporation. Even though the thus-produced layers significantly increase the wear resistance of the alloys, their effects on corrosion resistance are unsatisfactory because of the poor tightness, characteristic of PVD-produced products. Tightness acquires crucial significance when the substrate is a highly-active magnesium alloy, hence our idea to tighten the layers by subjecting them to a post-deposition chemical-hydrothermal-type treatment. This paper presents the results of our experiments with a new hybrid surface engineering method, using a final tightening pressure hydrothermal gas treatment in overheated steam of the composite titanium nitride layers PVD, produced on AZ91D magnesium alloy. The proposed method resulted in an outstanding improvement of the performance properties, in particular resistance to corrosion and wear, yielding values that exceed those exhibited by commercially anodized alloys and austenitic stainless 316L steel. The developed hybrid method produces new, high-performance corrosion and wear resistant, lightweight magnesium base materials, suitable for heavy duty applications.
Synthesis of Magnetite Nanoparticles through a Lab-On-Chip Device
Authors: Chircov Cristina , Bîrcă Alexandra Cătălina , Grumezescu Alexandru Mihai , Vasile Bogdan Stefan , Oprea Ovidiu , Nicoară Adrian Ionuț , Yang Chih-Hui , Huang Keng-Shiang , Andronescu Ecaterina
Published: October 2021

Magnetite nanoparticles (MNPs) represent one of the most intensively studied types of iron oxide nanoparticles in various fields, including biomedicine, pharmaceutics, bioengineering, and industry. Since their properties in terms of size, shape, and surface charge significantly affects their efficiency towards the envisaged application, it is fundamentally important to develop a new synthesis route that allows for the control and modulation of the nanoparticle features. In this context, the aim of the present study was to develop a new method for the synthesis of MNPs. Specifically, a microfluidic lab-on-chip (LoC) device was used to obtain MNPs with controlled properties. The study investigated the influence of iron precursor solution concentration and flowed onto the final properties of the nanomaterials. The synthesized MNPs were characterized in terms of size, morphology, structure, composition, and stability. Results proved the formation of magnetite as a single mineral phase. Moreover, the uniform spherical shape and narrow size distribution were demonstrated. Optimal characteristics regarding MNPs crystallinity, uniformity, and thermal stability were obtained at higher concentrations and lower flows. In this manner, the potential of the LoC device is a promising tool for the synthesis of nanomaterials by ensuring the necessary uniformity for all final applications.
Synthesis of Metal Matrix Composites Based on CrxNiy-TiN for Additive Technology
Authors: Matveev Alexey , Promakhov Vladimir , Schultz Nikita , Vorozhtsov Alexander
Published: October 2021

The novelty of this work consists of obtaining original fundamental data on the laws of synthesis of new metal matrix composite materials for additive technologies. CrN + TiNi composites were obtained using the method of self-propagating high-temperature synthesis. In this work, analysis of the parameters of the synthesis of composite materials as well as their structure and phase composition were carried out. A scheme for the formation of a composite structure is established; it is shown that the phase composition is represented by 54.6 wt.% CrN and 45.4 wt.% TiNi. It was shown that composites based on the system are suitable for machines that make use of direct laser deposition to grow layers of materials. Sample structure and phase parameters were studied. It is shown that titanium nitride particles are uniformly distributed in the CrNi intermetallic matrix, the TiN particle size ranges from 0.3 to 9 μm and the average particle size is 2.8 μm. The results obtained indicate the possibility of synthesizing promising metal matrix composite materials for additive technologies. Such materials may have increased hardness, operating temperature and strength.
Analytical Compliance Equations of Generalized Elliptical-Arc-Beam Spherical Flexure Hinges for 3D Elliptical Vibration-Assisted Cutting Mechanisms
Authors: Wang Han , Wu Shilei , Shao Zhongxi
Published: October 2021

Elliptical vibration-assisted cutting technology has been widely applied in complicated functional micro-structured surface texturing. Elliptical-arc-beam spherical flexure hinges have promising applications in the design of 3D elliptical vibration-assisted cutting mechanisms due to their high motion accuracy and large motion ranges. Analytical compliance matrix formulation of flexure hinges is the basis for achieving high-precision positioning performance of these mechanisms, but few studies focus on this topic. In this paper, analytical compliance equations of spatial elliptic-arc-beam spherical flexure hinges are derived, offering a convenient tool for analysis at early stages of mechanism design. The mechanical model of a generalized flexure hinge is firstly established based on Castigliano’s Second Theorem. By introducing the eccentric angle as the integral variable, the compliance matrix of the elliptical-arc-beam spherical flexure hinge is formulated. Finite element analysis is carried out to verify the accuracy of the derived analytical compliance matrix. The compliance factors calculated by the analytical equations agree well with those solved in the finite element analysis for the maximum error; average relative error and relative standard deviation are 8.25%, 1.83% and 1.78%, respectively. This work lays the foundations for the design and modeling of 3D elliptical vibration-assisted cutting mechanisms based on elliptical-arc-beam spherical flexure hinges.
New Titanium Alloys, Promising Materials for Medical Devices
Authors: Baltatu Madalina Simona , Vizureanu Petrica , Sandu Andrei Victor , Florido-Suarez Nestor , Saceleanu Mircea Vicentiu , Mirza-Rosca Julia Claudia
Published: October 2021

Titanium alloys are used in medical devices due to their mechanical properties, but also for their corrosion resistance. The natural passivation of titanium-based biomaterials, on the surface of which a dense and coherent film of nanometric thickness is formed, composed mainly of TiO2, determines an apparent bioactivity of them. In this paper, the method of obtaining new Ti20MoxSi alloys (x = 0.0, 0.5, 0.75, and 1.0) is presented, their microstructure is analyzed, and their electrochemical responses in Ringer´s solution were systematically investigated by linear polarization, cyclic potential dynamic polarization, and electrochemical impedance spectroscopy (EIS). The alloys corrosion resistance is high, and no evidence of localized breakdown of the passive layer was observed. There is no regularity determined by the composition of the alloys, in terms of corrosion resistance, but it seems that the most resistant is Ti20Mo1.0Si.
Effect of Fly Ash on Leaching Characteristics of Cement-Stabilized Macadam Base
Authors: Lun Dian , Yuan Taiping , Yang Xiaolong , Rong Hongliu , Shi Junjie , Pan Minqiang
Published: October 2021

To study the leaching characteristics of a cement-stabilized macadam base with fly ash, a calcium leaching test, using varying cement and fly ash dosages in an ammonium chloride solution, was designed to obtain the rate of calcium ion leaching, porosity, and permeability coefficient of cement-stabilized macadam with leaching time. The results showed that the number of leached calcium ions increased with the cement dosage in the leaching of cement-stabilized macadam. With an increase in the cement dosage, the leaching rate of calcium ions decreased, and the leaching process of the material was delayed. The incorporation of fly ash could effectively slow down the degree of calcium ion leaching. The permeability coefficient increased gradually with the extension of leaching time, and the increase in fly ash content had a more significant effect on the improvement of the permeability coefficient than the increase in cement dosage did.
Low Sintering Temperature Nano-Silver Pastes with High Bonding Strength by Adding Silver 2-Ethylhexanoate
Authors: Hsu Steve Lien-Chung , Chen Yen-Ting , Chen Meng-Liang , Chen In-Gann
Published: October 2021

A silver precursor (silver 2-ethylhexanoate) and silver nanoparticles were synthesized and used to prepare a low sintering temperature nano-silver paste (PM03). We optimized the amount of silver 2-ethylhexanoate added and the sintering temperature to obtain the best performance of the nano-silver paste. The relationship between the microstructures and properties of the paste was studied. The addition of silver 2-ethylhexanoate resulted in less porosity, leading to lower resistivity and higher shear strength. Thermal compression of the paste PM03 at 250 °C with 10 MPa pressure for 30 min was found to be the proper condition for copper-to-copper bonding. The resistivity was (3.50 ± 0.02) × 10−7 Ω∙m, and the shear strength was 57.48 MPa.
Surface Roughness Analysis of H13 Steel during Electrical Discharge Machining Process Using Cu–TiC Sintered Electrode
Authors: Walia Arminder Singh , Srivastava Vineet , Garg Mayank , Somani Nalin , Gupta Nitin Kumar , Prakash Chander , Bhargava Cherry , Kotecha Ketan
Published: October 2021

In electrical discharge machining (EDM), the machined surface quality can be affected by the excessive temperature generation during the machining process. To achieve a longer life of the finished part, the machined surface quality plays a key role in maintaining its overall integrity. Surface roughness is an important quality evaluation of a material’s surface that has considerable influence on mechanical performance of the material. Herein, a sintered cermet tooltip with 75% copper and 25% titanium carbide was used as tool electrode for processing H13 steel. The experiments have been performed to investigate the effects of EDM parameters on the machined surface roughness. The findings show that, as the pulse current, pulse length, and pulse interval are increased, the surface roughness tends to rise. The most significant determinant for surface roughness was found to be pulse current. A semi-empirical surface roughness model was created using the characteristics of the EDM technique. Buckingham’s theorem was used to develop a semi-empirical surface roughness prediction model. The semi-empirical model’s predictions were in good agreement with the experimental studies, and the built empirical model based on physical features of the cermet tooltip was tested using dimensional analysis.
3D Printing of Macro Porous Sol-Gel Derived Bioactive Glass Scaffolds and Assessment of Biological Response
Authors: Bento Ricardo , Gaddam Anuraag , Oskoei Párástu , Oliveira Helena , Ferreira José M. F.
Published: October 2021

3D printing emerged as a potential game-changer in the field of biomedical engineering. Robocasting in particular has shown excellent capability to produce custom-sized porous scaffolds from pastes with suitable viscoelastic properties. The materials and respective processing methods developed so far still need further improvements in order to obtain completely satisfactory scaffolds capable of providing both the biological and mechanical properties required for successful and comprehensive bone tissue regeneration. This work reports on the sol-gel synthesis of an alkali-free bioactive glass and on its characterization and processing ability towards the fabrication of porous scaffolds by robocasting. A two-fold increase in milling efficiency was achieved by suitably adjusting the milling procedures. The heat treatment temperature exerted a profound effect on the surface area of mesoporous powders. Robocasting inks containing 35 vol.% solids were prepared, and their flow properties were characterized by rheological tests. A script capable of preparing customizable CAD scaffold geometries was developed. The printing process was adjusted to increase the technique’s resolution. The mechanical properties of the scaffolds were assessed through compressive strength tests. The biomineralization ability and the biological performance were assessed by immersing the samples in simulated body fluid (SBF) and through MTT assays, respectively. The overall results demonstrated that scaffolds with macro porous features suitable for bone ingrowth (pore sizes of ~340 μm after sintering, and a porosity fraction of ~70%) in non-load-bearing applications could be successfully fabricated by 3D printing from the bioactive glass inks. Moreover, the scaffolds exhibited good biomineralization activity and good biocompatibility with human keratinocytes, suggesting they are safe and thus suited for the intended biomedical applications.
Experimental Study on the Correlation between Crack Width and Crack Depth of RC Beams
Authors: Li Yue , Zhang Juhui , Guan Zhongguo , Chen Youliang
Published: October 2021

The depth of cracks propagating inside reinforcement concrete (RC) components is barely able to be detected by visual inspection. Without any help from facilities, crack width can provide us with a proper way to explore the depth of cracks developing. Therefore, this paper tried to explore the correlation between crack width on the surface and crack depth. A static loading test was conducted on eight RC beams, considering the variation of concrete strength, cover, and reinforcement ratio. The test results indicate that concrete strength has a certain impact on cracking load and the propagation of cracks is mainly related to reinforcement ratio. The linear changes in load and crack width can be found. Originally, crack depth markedly increased with loading, but when restricted by compression zone of concrete and the height of beams, crack depth stopped extending finally. The correlation between crack width and crack depth was analyzed by studying work phases of a cross-section and experimental data. The fitting function achieved in this paper was determined to be a good agreement between the theoretical and the experimental relationship.
Characterization of Spatter and Sublimation in Alloy 718 during Electron Beam Melting
Authors: Raza Ahmad , Hryha Eduard
Published: October 2021

Due to elevated temperatures and high vacuum levels in electron beam melting (EBM), spatter formation and accumulation in the feedstock powder, and sublimation of alloying elements from the base feedstock powder can affect the feedstock powder’s reusability and change the alloy composition of fabricated parts. This study focused on the experimental and thermodynamic analysis of spatter particles generated in EBM, and analyzed sublimating alloying elements from Alloy 718 during EBM. Heat shields obtained after processing Alloy 718 in an Arcam A2X plus machine were analyzed to evaluate the spatters and metal condensate. Comprehensive morphological, microstructural, and chemical analyses were performed using scanning electron microscopy (SEM), focused ion beam (FIB), and energy dispersive spectroscopy (EDS). The morphological analysis showed that the area coverage of heat shields by spatter increased from top (<1%) to bottom (>25%), indicating that the spatter particles had projectile trajectories. Similarly, the metal condensate had a higher thickness of ~50 μm toward the bottom of the heat shield, indicating more significant condensation of metal vapors at the bottom. Microstructural analysis of spatters highlighted that the surfaces of spatter particles sampled from the heat shields were also covered with condensate, and the thickness of the deposited condensate depended on the time of landing of spatter particles on the heat shield during the build. The chemical analysis showed that the spatter particles had 17-fold higher oxygen content than virgin powder used in the build. Analysis of the metalized layer indicated that it was formed by oxidized metal condensate and was significantly enriched with Cr due to its higher vapor pressure under EBM conditions.
UV-LED Combined with Small Bioreactor Platform (SBP) for Degradation of 17α-Ethynylestradiol (EE2) at Very Short Hydraulic Retention Time
Authors: Fradkin Oran , Mamane Hadas , Kaplan Aviv , Menashe Ofir , Kurzbaum Eyal , Betzalel Yifaat , Avisar Dror
Published: October 2021

Degradation of 17α-ethynylestradiol (EE2) and estrogenicity were examined in a novel oxidative bioreactor (OBR) that combines small bioreactor platform (SBP) capsules and UV-LED (ultraviolet light emission diode) simultaneously, using enriched water and secondary effluent. Preliminary experiments examined three UV-LED wavelengths—267, 279, and 286 nm, with (indirect photolysis) and without (direct photolysis) H2O2. The major degradation wavelength for both direct and indirect photolysis was 279 nm, while the major removal gap for direct vs. indirect degradation was at 267 nm. Reduction of EE2 was observed together with reduction of estrogenicity and mineralization, indicating that the EE2 degradation products are not estrogens. Furthermore, slight mineralization occurred with direct photolysis and more significant mineralization with the indirect process. The physical–biological OBR process showed major improvement over other processes studied here, at a very short hydraulic retention time. The OBR can feasibly replace the advanced oxidation process of UV-LED radiation with catalyst in secondary sedimentation tanks with respect to reduction ratio, and with no residual H2O2. Further research into this OBR system is warranted, not only for EE2 degradation, but also to determine its capabilities for degrading mixtures of pharmaceuticals and pesticides, both of which have a significant impact on the environment and public health.
Experimental Study on Tensile Mechanical Properties and Reinforcement Ratio of Steel–Plastic Compound Geogrid-Reinforced Belt
Authors: Wang Qingbiao , Li Yue , Song Hongxu , Duan Jianing , Hu Zhongjing , Wang Fuqiang , Xu Haolin , Liu Zhengyin , Zhang Mingjing , Wang Liming , Wu Yeming , Shi Zhenyue
Published: October 2021

The steel–plastic compound geogrid has been widely used as a new reinforcement material in geotechnical engineering and other fields. Therefore, it is essential to fully understand the mechanical properties of steel–plastic compound geogrid-reinforced belts to utilize steel–plastic compound geogrids efficiently. In this study, tensile mechanical tests of steel wire, polyethylene geogrid belt, and steel–plastic compound geogrid-reinforced belt were conducted with respect to the tensile mechanical properties of steel–plastic compound geogrid-reinforced belts. In addition, the minimum reinforcement and optimal reinforcement ratios of steel–plastic compound geogrid-reinforced belts were summarized. The results showed that the steel–plastic compound geogrid-reinforced belts possessed an incongruent force of the internal steel wire during the tensile process. The tensile stress–strain curve of the steel–plastic compound geogrid-reinforced belt can be divided into the composite adjustment, steel wire breaking, and residual deformation stages. The tensile strength of the steel–plastic compound geogrid-reinforced belt is proportional to the diameter and number of steel wires in the reinforced belt. The minimum and optimum reinforcement ratios of steel wire in the steel–plastic compound geogrid-reinforced belt were 0.63% and 11.92%, respectively.
Local Interactions of Atmospheric Oxygen with MoS2 Crystals
Authors: Szoszkiewicz Robert
Published: October 2021

Thin and single MoS2 flakes are envisioned to contribute to the flexible nanoelectronics, particularly in sensing, optoelectronics and energy harvesting. Thus, it is important to study their stability and local surface reactivity. Their most straightforward surface reactions in this context pertain to thermally induced interactions with atmospheric oxygen. This review focuses on local and thermally induced interactions of MoS2 crystals and single MoS2 flakes. First, experimentally observed data for oxygen-mediated thermally induced morphological and chemical changes of the MoS2 crystals and single MoS2 flakes are presented. Second, state-of-the-art mechanistic insight from computer simulations and arising open questions are discussed. Finally, the properties and fate of the Mo oxides arising from thermal oxidation are reviewed, and future directions into the research of the local MoS2/MoOx interface are provided.
Study on the Effect of Geometrical Parameters of a Hexagonal Trigger on Energy Absorber Performance Using ANN
Authors: Rogala Michał , Gajewski Jakub , Górecki Marcin
Published: October 2021

Thin-walled structures are commonly used as energy absorbers in motor vehicles. Their function is to protect the structural components of vehicles and to absorb energy completely during collisions up to 20 km/h. This paper focuses on maintaining crush axiality during research. To verify the numerical analyses, physical specimens were made and then subjected to dynamic crushing. Force and shortening values as well as high-speed camera images were used for data analysis. Through time-lapse shots, plastic deformation within the crush initiator was observed. Such detailed analysis allowed the determination of the influence of hexagonal triggers in the form of notches on the post-buckling progressive analysis. In this paper, neural networks were used to examine the importance of each variable. Data from numerical analyses were used for this purpose. Based on the analyses performed, the effects of both the width and height of the triggers on the crush load efficiency (CLE) and total efficiency (TE) ratios can be seen. The width of the crush initiator has the greatest influence on Crash-box performance. Nevertheless, increasing both the height and the width of the initiator can result in crush non-axiality and underperformance of the energy absorber.
Mesoscopic Computational Fluid Dynamics Modelling for the Laser-Melting Deposition of AISI 304 Stainless Steel Single Tracks with Experimental Correlation: A Novel Study
Authors: Ur Rehman Asif , Mahmood Muhammad , Pitir Fatih , Salamci Metin , Popescu Andrei , Mihailescu Ion
Published: October 2021

For laser-melting deposition (LMD), a computational fluid dynamics (CFD) model was developed using the volume of fluid and discrete element modeling techniques. A method was developed to track the flow behavior, flow pattern, and driving forces of liquid flow. The developed model was compared with experimental results in the case of AISI 304 stainless steel single-track depositions on AISI 304 stainless steel substrate. A close correlation was found between experiments and modeling, with a deviation of 1–3%. It was found that the LMD involves the simultaneous addition of powder particles that absorb a significant amount of laser energy to transform their phase from solid to liquid, resulting in conduction-mode melt flow. The bubbles within the melt pool float at a specific velocity and escape from the melt pool throughout the deposition process. The pores are generated if the solid front hits the bubble before escaping the melt pool. Based on the simulations, it was discovered that the deposited layer’s counters took the longest time to solidify compared to the overall deposition. The bubbles strived to leave through the contours in an excess quantity, but became stuck during solidification, resulting in a large degree of porosity near the contours. The stream traces showed that the melt flow adopted a clockwise vortex in front of the laser beam and an anti-clockwise vortex behind the laser beam. The difference in the surface tension between the two ends of the melt pool induces “thermocapillary or Benard–Marangoni convection” force, which is insignificant compared to the selective laser melting process. After layer deposition, the melt region, mushy zone, and solidified region were identified. When the laser beam irradiates the substrate and powder particles are added simultaneously, the melt adopts a backwards flow due to the recoil pressure and thermocapillary or Benard–Marangoni convection effect, resulting in a negative mass flow rate. This study provides an in-depth understanding of melt pool dynamics and flow pattern in the case of LMD additive manufacturing technique.
Assessment of Dislocation Density by Various Techniques in Cold Rolled 1050 Aluminum Alloy
Authors: Sidor Jurij J. , Chakravarty Purnima , Bátorfi János Gy. , Nagy Péter , Xie Qingge , Gubicza Jenő
Published: October 2021

This study examines the evolution of dislocation density in cold rolled 1050 Al alloy. Various techniques such as numerical approaches, indentation techniques, X-ray diffraction line profile analysis, and electron backscattering diffraction were employed for the characterization of the deformed state. These methods allowed us to determine the nature of the evolution of the dislocation substructure during cold rolling. The investigated material was subjected to thickness reductions varying from 5% to 47%, which resulted in a continuous increase in hardness while the estimated dislocation density showed a tendency towards a less intense increase after a ~30% straining level. The numerical approaches employed, such as the Kubin–Estrin and a modified version of this model, are capable of ensuring a reasonable estimation of dislocation density at low and moderate deformation levels (~5–30%), while the discrepancy between the measured and simulated data is negligible when the material has been exposed to more severe rolling reductions.
Enhancement of Medium-Carbon Steel Corrosion and Wear Resistance by Plasma Electrolytic Nitriding and Polishing
Authors: Apelfeld Andrey , Borisov Anatoly , Dyakov Ilya , Grigoriev Sergey , Krit Boris , Kusmanov Sergei , Silkin Sergey , Suminov Igor , Tambovskiy Ivan
Published: October 2021

The influence of technological parameters of plasma electrolytic nitriding and polishing on the wear resistance and corrosion resistance of medium-carbon steel is considered. The morphology and roughness of the surface, phase composition and microhardness of the modified layer have been investigated. Wear resistance was studied under dry friction conditions with bearing steel as counter-body. It was found that plasma electrolytic polishing removes the loose part of the oxide layer and provides a two-fold decrease in surface roughness compared with untreated steel, and 2.8 times compared with the nitrided one. Combined processing at optimal technological parameters leads to an increase in microhardness up to 1130 HV, an increase in wear resistance by 70 times, and a decrease in the corrosion current density by almost 3 times in comparison with untreated steel.
The Role of Selenium on the Formation of Spheroidal Graphite in Cast Iron
Authors: Alonso Gorka , Stefanescu Doru Michael , Aguado Edurne , Suarez Ramon
Published: October 2021

Sulfur, an element that belongs to group 16 (chalcogens) of the periodic table, is an excellent promoter of nucleation substrates for graphite in cast iron. In ductile iron, sulfur favors a higher nodule count, which inhibits the risk of carbides and of microporosity. It is reasonable to expect that other elements from group 16, such as selenium or tellurium, play similar roles in the nucleation of graphite. The objective of this paper was to investigate the effect of selenium on the process of graphite formation. Thermal analysis cups were poured to evaluate the nodule count and size distribution. Some of the cups were not inoculated, while others were inoculated with a Ce-bearing inoculant, or with the Ce inoculant and additions of Se. Cross-shaped castings were also poured to quantify the microporosity regions by tomography. It appears that selenium additions modify the number and size of graphite particles, as well as the volume of microshrinkage. Direct correlations between these three parameters were found. Advanced Extensive Field Emission Gun Scanning Electron Microscope (FEG-SEM) techniques were used to identify the nature of the main nucleation compounds. Selenides, combined with Mg and rare earths, were observed to serve as nuclei for graphite. Their presence was justified by thermodynamics calculations.
Detectable Depth of Copper, Steel, and Aluminum Alloy Plates with Pulse-Echo Laser Ultrasonic Propagation Imaging System
Authors: Kim Dong-Il , Jung Ku-Rak , Jung Yoon-Soo , Kim Jae-Yeol
Published: October 2021

Pulse-echo laser ultrasonic propagation imaging is a nondestructive testing technique developed for composite materials and aluminum alloys used in aerospace. Although this method has been in usage for a considerable time, information of the detectable depth and the relationship between ultrasonic frequencies and the acoustic properties of metals is not readily available. Therefore, we investigate the A-scan and C-scan ultrasonic testing data of aluminum alloy, hot rolled steel, stainless steel, and copper alloy, which are used in aircraft bodies, frameworks, and gas pipelines. Experiments are performed with the pulse-width and excitation laser power fixed at 32 ns and approximately 4 W, respectively. The metal specimens include 24 artificial cylindrical defects with a diameter of 5 mm, located at depths of 1–12 mm on the front surface. The A-scan and C-scan data obtained at room temperature indicate the detectable depth for metals via the pulse-echo laser ultrasonic propagation imaging technique.
Ultra-High Temperature Creep of Ni-Based SX Superalloys at 1250 °C
Authors: Utada Satoshi , Despres Lucille , Cormier Jonathan
Published: October 2021

Very high temperature creep properties of twelve different Ni-based single crystal superalloys have been investigated at 1250 °C and under different initial applied stresses. The creep strength at this temperature is mainly controlled by the remaining γ′ volume fraction. Other parameters such as the γ′ precipitate after microstructure evolution and the γ/γ′ lattice parameter mismatch seem to affect the creep strength to a lesser degree in these conditions. The Norton Law creep exponent lies in the range 6–9 for most of the alloys studied, suggesting that dislocation glide and climb are the rate limiting deformation mechanisms. Damage mechanisms in these extreme conditions comprise creep strain accumulation leading to pronounced necking and to recrystallization in the most severely deformed sections of the specimens.