bluuebunny/crossref_metadata_2025 huggingface dataset:
Picometer-Sensitivity Surface Profile Measurement Using Swept-Source Phase Microscopy
Authors: Yue Jinyun , Cui Jinze , Zheng Zhaobo , Liu Jianjun , Zhao Yu , Cui Shiwei , Yu Yao , Wang Yi , Zhao Yuqian , Luan Jingmin , Liu Jian , Ma Zhenhe
Published: October 2024

In recent years, the Swept-Source Phase Microscope (SS-PM) has gained more attention due to its greater robustness to sample motion and lower signal decay with depth. However, the mechanical wavelength tuning of the swept source creates small variations in the wavenumber sampling of spectra that introduce serious phase noise. We present a software post-processing method to eliminate phase noise in SS-PM. This method does not require high-quality swept light sources or high-precision synchronization devices and achieves ~72 pm displacement sensitivity using a conventional SS-PM system. We compare the performance of this method with traditional software-based methods by measuring phase fluctuations. The phase fluctuations in the traditional software-based method are five times those of the proposed method, which means the proposed method has better sensitivity. Using this method, we reconstructed phase images of air wedges and resolution plates to demonstrate the SS-PM’s potential for high-sensitivity surface profiling measurement. Finally, we discuss the advantages of SS-PM over traditional Spectral-Domain PM techniques.
Thomson Scattering and Radiation Reaction from a Laser-Driven Electron
Authors: Pastor Ignacio , Roso Luis , Álvarez-Estrada Ramón F. , Castejón Francisco
Published: October 2024

We investigate the dynamics of electrons initially counter-propagating to an ultra-fast ultra-intense near-infrared laser pulse using a model for radiation reaction based on the classical Landau–Lifshitz–Hartemann equation. The electrons, with initial energies of 1 GeV, interact with laser fields of up to 1023 W/cm2. The radiation reaction effects slow down the electrons and significantly alter their trajectories, leading to distinctive Thomson scattering spectra and radiation patterns. It is proposed to use such spectra, which include contributions from harmonic and Doppler-shifted radiation, as a tool to measure laser intensity at focus. We discuss the feasibility of this approach for state-of-the-art and near-future laser technologies. We propose using Thomson scattering to measure the impact of radiation reaction on electron dynamics, thereby providing experimental scenarios for validating our model. This work aims to contribute to the understanding of electron behavior in ultra-intense laser fields and the role of radiation reaction in such extreme conditions. The specific properties of Thomson scattering associated with radiation reaction, shown to be dominant at the intensities of interest here, are highlighted and proposed as a diagnostic tool, both for this phenomenon itself and for laser characterization in a non-intrusive way.
Quantitative Analysis of Acquisition Speed of High-Precision FLIM Technologies via Simulation and Modeling
Authors: Lu Jinzheng , Miao Ling , Wen Jiaxing , Li Qiang , Chen Jingwei , Yang Qiang , Zhang Xing , Li Jin , Wu Yuchi , Yang Yue , Wu Sixin , Mo Wenbo , Xiang Qiang
Published: October 2024

In practical applications such as cancer diagnosis and industrial detection, there is a critical demand for fast fluorescence lifetime imaging (Fast-FLIM). The Fast-FLIM systems suitable for complex environments are typically achieved by enhancing the hardware performance of time-correlated single-photon counting (TCSPC), with an acquisition speed of about a few frames per second (fps). However, due to the limitation of single-photon acquisition, the imaging speed is still far from the demand of practical application. The synchroscan streak camera (SC) maps signals from the temporal dimension to the spatial dimension, effectively overcoming the long acquisition time caused by single-photon acquisition. This paper constructs a method to calculate the acquisition time for the TCSPC-FLIM and SC-FLIM systems, and it quantitatively compares the speed. The research demonstrates that the main factors limiting the acquisition speed of the FLIM systems are the photon emission rate, the photon counting rate, the required SNR, the dwell time, and the number of parallel channels. In high-quality and large-scale lifetime imaging, the acquisition speed of the SC-FLIM is at least 104 times faster than that of the TCSPC-FLIM. Therefore, the synchroscan streak camera has more significant potential to promote Fast-FLIM.
Bioactivity Screening of Extracts from Icelandic Seaweeds for Potential Application in Cosmeceuticals
Authors: Jensen Sophie , Helgadóttir Júlía Karítas , Jónsdóttir Rósa
Published: October 2024

Seaweed is a great source of biologically active metabolites which could prove interesting in cosmeceutical applications. In this study, seven Icelandic seaweed species (Ascophyllum nodosum, Alaria esculenta, Laminaria hyperborea, Laminaria digitata, Saccharina latissima, Palmaria palmata, and Schizymenia jonssonii) were screened for total polyphenol content, antioxidant properties, and inhibition of skin-degrading enzymes. Antioxidant assays included DPPH (2,2-diphenyl-1-picrylhydrazyl), reducing power, and ORAC (oxygen radical absorbance capacity). In most assays, A. nodosum extracts were the most active. A. nodosum extracts also showed the strongest inhibition of the skin-degrading enzymes elastase and collagenase at low concentrations, demonstrating its skin-protective qualities. To further investigate the activity, A. nodosum was subsequently extracted with solvents with increasing polarity into seven different extracts. Compared to other extracts, the extracts obtained by extraction with acetone and methanol showed the highest activity in all assays. Extracts obtained with room-temperature water and 85 °C water also demonstrated moderate to high activities. The outcomes of this study support the potential utilization of the brown seaweed A. nodosum as a source of natural ingredients in cosmeceuticals.
Circulating Extracellular Mitochondria in Cardiometabolic Disease: Harnessing the Potential for Diagnosis, Prognosis, and Treatment
Authors: Spanos Michail , Gokulnath Priyanka , Whittaker Olivia Rosina , Azzam Christopher , Chatterjee Emeli , Singh Aarush , Varrias Dimitrios , Kladas Michail , Vulugundam Gururaja , Raptis Dimitrios , Sabir Hamza , Sabir Zainab , Zarghom Saman , Aljareh Amr , Kong Steve , Brown Donclair , Li Guoping , Das Saumya
Published: October 2024

Mitochondria are crucial for cellular functioning, serving as both an intracellular energy source and a signaling organelle. Recent evidence also highlights their existence outside of cells, where they participate in cell-to-cell communication. Cardiometabolic disease (CMD) has a complex pathogenesis closely associated with mitochondrial dysregulation, inflammation, and metabolic abnormalities. This review explores the roles of circulating extracellular mitochondria (CEMI) in CMD, detailing how their various forms, whether as intact structures or within vesicles, contribute to CMD pathogenesis. We classify different forms of CEMIs and discuss their potential as biomarkers and therapeutic agents in CMDs. We also describe mitochondrial transplantation as an emerging therapy for restoring cellular function in damaged tissues. Finally, to standardize CEMI assessment, we propose the Universal CEMI Assessment Protocol (UCAP), a framework aimed at enhancing comparability and reproducibility across studies.
Decoupling Distribution of n-Alkanes in Aeolian Sand and Vegetation of the Northern Ulan Buh Desert, China: Insight into Organic Matter Preservation in Arid Regions
Authors: Zhou Shangzhe , Xi Lei , Cui Mengchun , Cui Guipeng , Gao Pan , Zhu Jinlei , Kong Weiyuan , Jia Yufu , Lu Qi
Published: October 2024

Fallen leaves and their decomposition directly deposit leaf wax n-alkanes into sediments, which can be used to identify local flora. These n-alkanes are important for studying past vegetation and climate, but their distribution in sediments must be known. Aeolian sand n-alkanes are particularly important for understanding paleoclimates in arid regions, despite the challenges of extraction due to their extremely low abundance. To investigate the preservation of plant leaf wax n-alkanes in deserts, we analyzed n-alkanes in aeolian sands from the Northern Ulan Buh Desert (UBD), China, and compared them to the surrounding vegetation. We calculated the total n-alkane concentration (ΣALK), average chain length (ACL21–35), and carbon preference index (CPI21–35). In the Northern UBD, aeolian sand n-alkanes have lower ΣALK, indicating microbial degradation. The eastern aeolian sand has lower CPI21–35 and ACL21–35 than the adjacent vegetation, whereas the western sand values are consistent with the plants, likely due to the transport of plant-derived materials by wind and water from the nearby mountains. Our study shows that sedimentary n-alkane signatures are not only determined by local vegetation but also influenced by environmental factors like temperature and precipitation. Additionally, local deposition processes play a significant role in determining the properties of these n-alkanes.
Assessing a “Least-Concern” Red List Tree Species from Madagascar Used in Traditional Medicine: Morella spathulata (Myricaceae) Phyto-Compounds and Anti-Inflammatory Properties
Authors: Fioccardi Annachiara , Donno Dario , Razafindrakoto Zoarilala Rinah , Tombozara Nantenaina , Henintsoa Sylvia , Mahitasoa Elyna , Torti Valeria , Solofoniaina Marcellin , Rosso Lorenzo , Gamba Giovanni , Andrianjara Charles , Ramanitrahasimbola David , Beccaro Gabriele Loris
Published: October 2024

Morella spathulata (Myricaceae family) is a common plant from Madagascar and is present on the IUCN Red List of threatened species classified at the ’least concern’ level, used by the local population to treat numerous illnesses and pain. Despite its frequent use, comprehensive phytochemical and pharmacological research on the species is limited. This study evaluated the antioxidant, analgesic, and anti-inflammatory properties, as well as the toxicity of methanol extracts from the leaves (MS_L) and bark (MS_B) of M. spathulata. The research involved the analysis of nutritional traits such as sugars, organic acids, vitamin C, polyphenolic content (TPC) and the main phytochemicals by HPLC analysis. Antioxidant capacity was assessed through DPPH and FRAP assays. Analgesic and anti-inflammatory activities were evaluated using acetic acid-induced writhing and carrageenan-induced paw oedema tests in mice. The results showed a high content of phenolic and bioactive components in the leaf and bark extracts, associated with antioxidant, analgesic and anti-inflammatory properties. The interaction of key compounds such as ferulic acid and ellagic acid with proteins involved in pH regulation and immune modulation provides clues to the mechanisms underlying the therapeutic effects. However, conservation efforts are crucial due to habitat loss and illegal logging, and further studies are needed to fully explore the plant’s therapeutic potential.
ZmLSD1 Enhances Salt Tolerance by Regulating the Expression of ZmWRKY29 in Maize
Authors: Li Qiaolu , Hu Rongrong , Jiang Min , Zhang Wei , Gao Xinyi , Zhang Binglin , Liu Weijuan , Wu Zhongyi , Zou Huawen
Published: October 2024

Salt stress significantly impairs plant growth, presenting a challenge to agricultural productivity. Exploring the regulatory mechanisms underlying salt stress responses is critically important. Here, we identified a significant role for the maize LESION-SIMULATING DISEASE transcription factor, ZmLSD1, in enhancing salt stress response. Subcellular localization analysis indicated that ZmLSD1-GFP was localized in the nucleus in the maize protoplast. Overexpressing ZmLSD1 in maize obviously enhanced the tolerance of plants to salt stress. Physiological analysis indicated that overexpressed ZmLSD1 in maize could mitigate the accumulation of H2O2 and MDA content exposed to salt stress. RNA-seq and qPCR-PCR analyses showed that ZmLSD1 positively regulated ZmWRKY29 expression. ChIP-qPCR and EMSA experiments demonstrated that ZmLSD1 could directly bind to the promoter of ZmWRKY29 through the GTAC motif both in vitro and in vivo. Overall, our findings suggest that ZmLSD1 plays a positive role in enhancing the tolerance of maize to salt by affecting ZmWRKY29 expression.
Transcriptome Remodeling in Arabidopsis: A Response to Heterologous Poplar MSL-lncRNAs Overexpression
Authors: Mao Jinyan , Tang Qianhua , Wu Huaitong , Chen Yingnan
Published: October 2024

Stamens are vital reproductive organs in angiosperms, essential for plant growth, reproduction, and development. The genetic regulation and molecular mechanisms underlying stamen development are, however, complex and varied among different plant species. MSL-lncRNAs, a gene specific to the Y chromosome of Populus deltoides, is predominantly expressed in male flower buds. Heterologous expression of MSL-lncRNAs in Arabidopsis thaliana resulted in an increase in both stamen and anther count, without affecting pistil development or seed set. To reveal the molecular regulatory network influenced by MSL-lncRNAs on stamen development, we conducted transcriptome sequencing of flowers from both wild-type and MSL-lncRNAs-overexpressing Arabidopsis. A total of 678 differentially expressed genes were identified between wild-type and transgenic Arabidopsis. Among these, 20 were classified as transcription factors, suggesting a role for these regulatory proteins in stamen development. GO enrichment analysis revealed that the differentially expressed genes were significantly associated with processes such as pollen formation, polysaccharide catabolic processes, and secondary metabolism. KEGG pathway analysis indicated that MSL-lncRNAs might promote stamen development by upregulating genes involved in the phenylpropanoid biosynthesis pathway. The top three upregulated genes, all featuring the DUF295 domain, were found to harbor an F-box motif at their N-termini, which is implicated in stamen development. Additionally, in transgenic Arabidopsis flowers, genes implicated in tapetum formation and anther development were also observed to be upregulated, implying a potential role for MSL-lncRNAs in modulating pollen development through the positive regulation of these genes. The findings from this study establish a theoretical framework for elucidating the genetic control exerted by MSL-lncRNAs over stamen and pollen development.
The Application of a Foliar Spray Containing Methylobacterium symbioticum Had a Limited Effect on Crop Yield and Nitrogen Recovery in Field and Pot-Grown Maize
Authors: Rodrigues Manuel Ângelo , Correia Carlos Manuel , Arrobas Margarida
Published: October 2024

In this study, the effectiveness of an inoculant containing a nitrogen (N)-fixing microorganism (Methylobacterium symbioticum) was evaluated on maize (Zea mays L.) grown both in the field (silage maize) and in pots over two years (2021 and 2022). The field trial included the following two treatments: with (Yes) and without (No) the inoculant. The pot experiment was designed as a factorial arrangement with two factors: the application of the inoculant (Yes and No) and N applied to the soil (0, 0.4, 0.8, and 1.6 g pot−1). In the field, total dry matter yield (DMY) did not differ significantly between treatments, although the average DMY was higher in the inoculant treatment. In pots, the total DMY varied significantly across all N rates but was only significantly affected by the inoculant application in 2022. N fixation estimates in the field were 58.8 and 14.5 kg ha−1 for 2021 and 2022, respectively, representing 23.7% and 9.1% of the N recovered in the aboveground plant parts. In pots, the estimated fixed N values were −49.2 and 199.2 mg pot−1 in 2021 and 2022, respectively, which corresponded to −5.2% and 18.5% of the N found in the aboveground plant parts. Considering the average values obtained across the four cultivation conditions, there was a positive outcome for the treated plants. However, these values cannot be considered significant when compared to nitrogen removal in maize crops. A commercial product should provide an unequivocal and quantitatively relevant contribution to plant nutrition, which did not appear to be the case. Thus, for this inoculant to provide reliable guarantees of positive outcomes for farmers and become a useful tool in promoting more sustainable agriculture, further studies appear necessary. These studies should aim to determine in which crops and under what cultivation conditions the application of the inoculant is truly effective in enhancing N fixation and improving crop productivity.
Nutrient Use Efficiency and Cucumber Productivity as a Function of the Nitrogen Fertilization Rate and the Wood Fiber Content in Growing Media
Authors: Čepulienė Rita , Butkevičienė Lina Marija , Steponavičienė Vaida
Published: October 2024

A peat substrate is made from peat from drained peatlands, which is a limited resource. A realistic estimate is that 50% of the world’s wetlands have been lost. Peat is used in horticulture, especially for the cultivation of vegetables in greenhouses. The consequences of peatland exploitation are an increase in the greenhouse effect and a decrease in carbon stocks. Wood fiber can be used as an alternative to peat. The chemical properties of growing media interact and change continuously due to the small volume of growing media, which is limited by the growing container. This study aims to gain new knowledge on the impact of nutrient changes in the microbial degradation of carbon compounds in wood fiber and mixtures with a peat substrate on the content and uptake of nutrients required by plants. The cucumber (Cucumis sativus L.) variety ‘Dirigent H’ developed in the Netherlands was cultivated in growing media of a peat substrate and wood fiber: (1) peat substrate (PS); (2) wood fiber (WF); (3) wood fiber and peat substrate 50/50 v/v (WF/PS 50/50); (4) wood fiber and peat substrate 25/75 v/v (WF/PS 25/75). The rates of fertilization were the following: (1) conventional fertilization (CF); (2) 13 g N per plant (N13); (3) 23 g N per plant (N23); (4) 30 g N per plant (N30). The experiment was carried out with three replications. As the amount of wood fiber increased, the humidity and pH of the growing media increased. The fertilization of the cucumbers with different quantities of nitrogen influenced the nutrient uptake. The plants grown in the 50/50 and 25/75 growing media had the best Cu uptake when fertilized with N23. When the plants grown in the wood fiber media and the 50/50 media were fertilized with N13, N23, and N30, the Mn content in the growing media at the end of the growing season was significantly lower than the Mn content in the media with conventional fertilization. Thus, nitrogen improved the uptake of Mn by the plants grown not only in the wood fiber, but also in the combinations with a peat substrate. Growing plants in wood fiber and fertilizing them with N13 can result in the optimum uptake of micronutrients. The number and biomass of cucumber fruits per plant were influenced by the amount of wood fiber in the growing media and the application of nitrogen fertilizer. The highest number of fruits and biomass of fruits per plant obtained were significantly higher when the cucumbers were grown in WF/PS 50/50 growing media with additional N13 fertilization.
Polishing Ceramic Samples with Fast Argon Atoms at Different Angles of Their Incidence on the Sample Surface
Authors: Grigoriev Sergey N. , Metel Alexander S. , Volosova Marina A. , Mustafaev Enver S. , Melnik Yury A.
Published: October 2024

Mechanical polishing of a product makes it possible to decrease the roughness of its surface to Ra = 0.001 µm by rubbing it with a fine abrasive contained in a fabric or other soft material. This method takes too much time and is associated with abrasive particles and microscopic scratches remaining after the processing. As such, a non-contact treatment with plasma and accelerated particles has been chosen in the present work to study polishing of ceramic samples. The small angular divergence of fast argon atoms made it possible to obtain the dependence of the sample roughness on the angle α of the atom’s incidence on its surface. It was found that the roughness weakly depends on the angle α, if not exceeding the threshold value αo ~ 50°, and rapidly decreases with increasing α > αo. Polishing with fast argon atoms leads to a noticeable decrease in friction of ceramic samples.
Sublingual Fast-Dissolving Thin Films of Loratadine: Characterization, In Vitro and Ex Vivo Evaluation
Authors: Alhamhoom Yahya , Said Ashitha Kakarlapudi , Kumar Avichal , Nanjappa Shivakumar Hagalavadi , Wali Divya , Rahamathulla Mohamed , Farhana Syeda Ayesha , Ahmed Mohammed Muqtader , Shivanandappa Thippeswamy Boreddy
Published: October 2024

Loratadine (LOR) is a second-generation antihistamine that exhibits a low and variable oral bioavailability (10–40%) and delayed onset owing to poor solubility and an extensive first-pass effect. Therefore, in light of the clinical need, the main goal of the present study was to develop sublingual fast-dissolving thin films of LOR–citric acid co-amorphous systems (LOR-CAs) with the aim of eliciting a faster onset and improving the bioavailability. We formulated sublingual fast-dissolving thin films of LOR by a film-casting technique using hydrophilic polymers like hydroxypropyl methylcellulose (HPMC E15), polyvinyl pyrrolidone K30 (PVP K30), and hydroxypropyl cellulose EL (HPC-EF) and citric acid as a pH modulator, while glycerin served as a plasticizer. The sublingual fast-dissolving thin films were characterized by FTIR, SEM, DSC, and XRD and evaluated for in vitro dissolution and ex vivo mucoadhesion. The best formulation (F1) developed using HPMC E15 as a polymer, glycerin as a plasticizer, and citric acid as a pH modulator was found to be the optimized formulation as it was smooth, clear, flexible, and displayed good mucoadhesion (11.27 ± 0.418 gm/cm2) and uniform thickness (0.25 ± 0.02 mm). The formulation F1 was found to display a significantly shorter DT (30.30 ± 0.6 s) and rapid release of LOR (92.10 ± 2.3% in 60 min) compared to other formulations (ANOVA, p < 0.001). The results indicated that the prepared sublingual films are likely to elicit a faster therapeutic effect, avoid first-pass metabolism, and improve the bioavailability.
Assessment of Physical and Mechanical Parameters of Spun-Bond Nonwoven Fabric
Authors: Lasenko Inga , Sanchaniya Jaymin Vrajlal , Kanukuntla Sai Pavan , Viluma-Gudmona Arta , Vasilevska Sandra , Vejanand Sanjay Rajni
Published: October 2024

The selection of an appropriate fabric for technical applications, such as protective masks, hinges on a thorough understanding of the fabric’s physical and mechanical properties. This study addresses the challenge of selecting the optimal material structure for the upper layer of a protective mask, aiming to ensure adequate breathability while providing effective filtration against airborne particles and contaminants. We assessed and compared the physical–mechanical properties of five polymer spun-bond nonwoven fabrics from different suppliers. Our comprehensive evaluation included, as follows: a visual inspection; light permeability analysis; mass and thickness measurements; elongation and tensile strength tests; breathing resistance assessments; and filter penetration tests with paraffin oil. The results revealed significant variations in performance among the samples, with one fabric consistently outperforming the others across multiple parameters. Notably, this top-performing fabric met or exceeded the EN 149:2001+A1:2009 standard for breathing resistance and filtration efficiency and, in combination with additional filter layers, met the requirements or exceeded class FFP2 (filtering face piece). This study underscores the importance of meticulous material selection and quality control in optimizing PPE (personal protective equipment) performance and user safety, providing valuable insights for mask manufacturers and healthcare professionals.
CFD Simulation of Mixing Forest Biomass to Obtain Cellulose
Authors: Casarez-Duran Adolfo Angel , Paredes-Rojas Juan Carlos , Torres-San Miguel Christopher René , Méndez-García Sergio Rodrigo , Ortiz-Hernández Fernando Eli , Urriolagoitia Calderón Guillermo Manuel
Published: October 2024

Obtaining cellulose from forest residues develops sustainable processes in the biotechnology industry, especially in producing biopolymers, which could replace or add petroleum-derived polymers. This research seeks to optimize the ideal conditions of the mixing process to maximize the efficiency in obtaining cellulose through a process consisting of two treatment media for pine sawdust, specifically evaluating the impact of three types of impellers (propeller, flat blades, and 45° inclined flat blades) at speeds of (150, 250 and 350 rpm). DIN 28131 was used for the design of stirred tanks. Simulations were carried out with a volume of 50 L. CFD and FSI simulations of the agitation behavior of forest biomass in a stirred tank reactor were performed. The ALE method was applied, and the models were solved using the LS-DYNA computer program. The results indicate that agitation with propellers and flat blades inclined at 150 and 250 rpm was the most efficient, minimizing cell damage and optimizing energy consumption. The impeller with flat blades inclined at 45° proved to be the best option for cellulose extraction. The novelty of this research is that not only the flow fields and the agitation behavior were found, but also the stresses in the impellers were found, and the force, moment, and power required by the motor in each simulation were revealed at a different speed. The power curves shown help to understand how energy consumption varies under different conditions.
Multi-Timescale Reactive Power Optimization and Regulation Method for Distribution Networks Under a Multi-Source Interaction Environment
Authors: Zhou Hanying , Liang Junyu , Du Xiao , Wu Mengtong
Published: October 2024

In the context of constructing new power systems, distribution networks are increasingly incorporating distributed resources such as distributed photovoltaic (PV) systems, decentralized wind turbines (WTs), and new types of energy storage system (ESS), which may lead to prominent issues such as voltage overruns and reverse heavy overloads in the distribution network. While distributed resources are valuable for voltage regulation, their regulation characteristics vary with their operation means, and the randomness and volatility of renewable power generation will also influence the optimization and regulation of voltage in the distribution network. This paper proposes a multi-timescale reactive power optimization and regulation method for distribution networks in a multi-source interactive environment. Firstly, the voltage regulation characteristics of distributed PV systems, decentralized ESSs, and distributed WTs are analyzed. Based on this analysis, a multi-timescale voltage optimization scheme for distribution networks using the MPC method is proposed, which optimizes the voltage regulation strategies for each distributed resource in a rolling manner. Furthermore, an event-triggered real-time voltage zoning control strategy based on voltage sensitivity is proposed to address the real-time sudden voltage overlimit problems. The modified IEEE 33-node system is used to verify the performance of the proposed method. Simulation results indicate that the issue of voltage overruns at distribution network nodes has been improved, and the intraday rolling optimization yields results are more realistic compared with the day-ahead optimization method.
Enhanced Interfaces for High-Temperature Purposes—Practical Methodology and Characterization
Authors: Pereira José , Souza Reinaldo , Moreira António , Moita Ana
Published: October 2024

The current study is focused on devising treated diatomite interfaces with the robustness and boiling water resistance necessary for high-temperature purposes. This work describes the synthesis methodology of the diatomite-based coatings, which followed the production of a composite formulation composed by treated diatomite powder dispersed in an epoxy resin matrix. After its preparation, the suspension was applied via the dip-coating technique over AISI-304 stainless-steel foils, which, after being air dried, underwent a post-curing treatment. Also, the interfaces were characterized by diverse techniques such as scanning electron microscopy and optical tensiometry. Apart from this, their thermophysical properties like thermal conductivity were also determined. Further, the physical and chemical durability of the interfaces was also evaluated via the elaboration of robustness tests including abrasion resistance, adhesion strength, solid impact resistance, and solvent resistance. The results showed satisfactory resistant interfaces, and with a wettability characterized by contact angles superior to 150°. Also, the interfaces confirmed improved durability when immersed in boiling water at 1 atm, since their wetting characteristics and durability remained nearly unaltered after 762 h of testing. Additionally, the synthesized interfaces possessed self-cleaning ability and chemical and thermal shock aging resistance. Generally, the fundamental outcomes of this work point out the suitability of the produced diatomite-based interfaces to be explored in high-temperature applications like flow boiling, pool boiling, and condensation. In terms of practicality, the method of preparation of the interfaces was a relatively easy and rapid approach to obtaining enhanced wettability and resilient interfaces, and with the required adaptations like the ratios between the raw materials, its suitability for large-scale applications makes this an appealing option.
Bioremediation of Smog: Current Trends and Future Perspectives
Authors: Isha  , Ali Shakir , Khalid Ammara , Naseer Ifrah Amjad , Raza Hassan , Chang Young-Cheol
Published: October 2024

Air pollution has become one of the biggest problems throughout the world. Smog has a severe effect on the pulmonary and circulatory systems, which causes a significant number of deaths globally. Therefore, the remediation of air pollutants to maintain ecosystem processes and functions and to improve human health is a crucial problem confronting mankind today. This review aims to discuss the health effects of smog on humans. This review will also focus on the bioremediation of air pollution (smog) using bacteria, fungi, phytoremediation, nanotechnology, and phylloremediation (using plants and microbes). Phylloremediation is the most effective technology for removing air pollution naturally. The future perspective presents a great need to produce an ecosystem where microbes, plants, and nanoparticles synergistically control smog. In addition, further advancements would be needed to modify the genetic makeup of microbes and plants. Biotechnological approaches like CRISPR-Cas9 can be applied to the editing and cutting of specific genes responsible for the bioremediation of VOCs, NOx, SOx, and harmful hydrocarbons. The extracted genes can then be expressed in biologically modified microorganisms and plants for the enhanced bioremediation of smog.
Regulation of Reactivity of Calcined Ultrafine Kaolin Products
Authors: Yin Hui , Liu Huajie , Bu Yuhuan , Chen Weiqing , Ding Fuquan , Lin Wenxiang , Zhang Yuwei
Published: October 2024

This study explored the potential of ultrafine kaolin as a geopolymer raw material, focusing on the reactivity of calcined kaolin products and its influencing factors. Through a series of analytical techniques, including thickening experiments, particle size analysis, SEM, XRD, and FT-IR, the effects of calcination temperature, time, and Si-Al ratio were evaluated. The results indicated that calcination temperature significantly impacts reactivity, with optimal conditions found between 600 °C and 800 °C, yielding metakaolin with thickening times of 12 to 43 min. Temperatures above 900 °C led to the formation of low-reactivity phases like mullite. The Si-Al ratio also influenced thickening time, with durations varying from 97 min at 0.85 to 43 min at 0.9 and increasing to 157 min at 0.95. Calcination time had the smallest effect, with thickening times ranging from 10 to 25 min over 4 to 8 h. Additionally, calcination altered particle size, initially expanding due to thermal expansion and later shrinking due to lattice distortion above 700 °C. By adjusting these parameters, the reactivity of calcined kaolin could be tailored to suit specific needs. This research provides a theoretical foundation for metakaolin’s application in construction materials and offers novel insights into geopolymer preparation.
Experimental Evaluation of Blockage Resistance and Position Caused by Microparticle Migration in Water Injection Wells
Authors: Yu Jifei , Chen Huan , Cao Yanfeng , Wen Min , Zhai Xiaopeng , Zhang Xiaotong , Hao Tongchuan , Peng Jianlin , Zhu Weitao
Published: October 2024

Offshore oil field loose sandstone reservoirs have high permeability. However, during the water injection process, water injection blockage occurs, causing an increase in injection pressure, making it impossible to continue injecting water on site. Current research mainly focuses on the factors causing water injection blockage, with less attention given to the blockage locations and the pressure increase caused by water injection. There is a lack of research on the change in the law of injection capacity. This paper establishes a simulation experiment for water injection blockage that can accommodate both homogeneous and heterogeneous cores. The experimental core is 1 m long and capable of simulating the blockage conditions in the near-well zone during water injection, thereby analyzing the core blockage position and blockage pressure. The study clarifies the influence of water quality indicators, heterogeneity, and core length on the blockage patterns in reservoirs during water injection. The research findings are as follows: I. The reservoir blockage samples were characterized using scanning electron microscopy (SEM), casting thin sections, and X-ray diffraction (XRD) analysis. The results indicate that the main factors causing blockage are clay, silt, and fine particulate suspensions, with the fine particles mainly consisting of hydrated silicates and alkali metal oxides. The primary cause of blockage in loose sandstone is identified as the mechanism of migration and accumulation of clay, fine rock particles, and suspended matter in the injected water. II. By monitoring pressure and permeability changes in the core flooding experiments, the impact of reservoir heterogeneity on water injection capacity was evaluated. The evaluation results show that the blockage locations and lengths in heterogeneous cores are twice those in homogeneous cores. III. For heterogeneous reservoirs, if the initial permeability at the inlet is lower than in other segments of the core, significant blockage resistance occurs, with the final resistance being 1.27 times that of homogeneous cores. If the initial permeability at the inlet is higher than in other parts, the final blockage resistance is close to that of homogeneous cores. This study provides theoretical support for the analysis of blockage locations and pressures in loose sandstone water injection and offers technical support for the design of unplugging ranges and pressures after blockage in heterogeneous formations. At the same time, it provides a theoretical basis for selecting the direction of acidizing after blockage occurs in loose sandstone.
Efficacy of Atmospheric Pressure Plasma Jet-Induced Surface Treatment on Wettability, Surface Topography, and Shear Bond Strength of Ceramic Surfaces for CAD-On Assembly
Authors: Alalawi Haidar , Al Mutairi Ziyad , Al Abbasi Omar , Al Dossary Fatima , Husain Manayer , Al Ghubari Faleh , Akhtar Sultan , Abdalla Moamen A.
Published: October 2024

This study evaluated the effectiveness of atmospheric pressure plasma jet (APPJ) treatment on the surface characteristics and bond strength of zirconia and lithium disilicate ceramics for CAD-on restorations. A total of 70 cylindrical-shaped specimens of lithium disilicate and 70 disc-shaped specimens of Y-TZP zirconia were machined, thermally processed, surface-treated, and then resin-bonded. The specimens were grouped according to the following surface treatments: no surface treatment, sandblasting, plasma, sandblasting followed by plasma, sandblasting followed by universal adhesive, plasma followed by universal adhesive, and sandblasting and plasma treatment followed by universal adhesive. The treated surfaces were subjected to a wettability assessment via contact angle measurement and a topography assessment using scanning electron microscopy (SEM). The cemented assembly was subjected to shear bond strength testing with a universal testing machine, and the results were imported to SPSS 23.0 for statistical analysis. The results show that APPJ treatment induced a significantly low contact angle for both ceramics with no surface alteration upon scanning. Moreover, APPJ treatment produced a bonded assembly with a shear bond strength comparable to sandblasting. In conclusion, APPJ treatment should be considered an efficient surface treatment with a non-destructive nature that surpasses sandblasting with the provision of a high shear bond strength between CAD-on ceramics.
Outcomes, Complications, and Eradication Rates of Two-Stage Revision Surgery for Periprosthetic Shoulder, Elbow, Hip, and Knee Infections: A Systematic Review
Authors: Mercurio Michele , Cofano Erminia , Colace Stefano , Piro Federico , Cerciello Simone , Galasso Olimpio , Gasparini Giorgio
Published: October 2024

Background/Objectives: Periprosthetic joint infection (PJI) is one of the most common complications after joint replacement. Two-stage revision remains the standard of care in chronic infections. The aim of this systematic review was to investigate the outcomes, complications, and eradication rates of two-stage revision surgery to treat PJI of the shoulder, elbow, hip, and knee. Methods: A total of 36 studies were included. Patient demographics, follow-up, the visual analog scale (VAS) for pain, the Constant–Murley score (CMS) for shoulder, the Harris Hip Score (HHS) for hip, the Knee Society Score (KSS) for knee, the range of motion (ROM), number and types of complications, and eradication rate were recorded. Results: A total of 2484 patients were identified, of whom 145, 29, 1269, and 1041 underwent two-stage revision surgery for shoulder, elbow, hip, and knee infections, respectively. The overall mean follow-up was 5.7 ± 4.5 years. The overall mean time of re-implantation was 20.8 ± 21.3 weeks. The most common causative bacteria were Cutibacterium acnes (32.7%) for shoulder, Methicillin-Sensitive Staphylococcus aureus (44.4%) for elbow, and Staphylococcus coagulase negative (CNS) (31.3% and 23%) for hip and knee infection, respectively. The mean overall preoperative VAS score was 6.7 ± 2.3, while, postoperatively, the mean score was 4.5 ± 2.7 (p < 0.001). A total of 2059 out of 2484 patients (82.9%) experienced eradication. Conclusions: Two-stage revision is an effective procedure to treat PJI with an overall eradication rate of 83%. A significant recovery of functionality and a decrease in residual pain can be achieved after surgery. Aseptic loosening and re-infection were the most common complications in shoulder and hip infections. Death rate was high in knee infections.
The Identification of Synthetic Impurities in a Vape Pen Containing Δ9-Tetrahydrocannabiphorol Using Gas Chromatography Coupled with Mass Spectrometry
Authors: Schirmer Willi , Schürch Stefan , Weinmann Wolfgang
Published: October 2024

Δ9-Tetrahydrocannabiphorol (Δ9-THCP, THCP) a psychoactive cannabinoid recently found in Cannabis sativa L., is widely used as a legal marijuana substitute. THCP is encountered in sprayed Cannabis, edibles, and vape liquids. The distributors of such products claim that the THCP in use originates from a natural source. The legal status of this substance varies from country to country. THCP and similar cannabinoids with a dibenzoyprane structure have been banned in Switzerland since October 2023. A vape liquid, which contains 90% THCP and 10% terpenes according to the distributor, was analyzed by gas chromatography coupled with mass spectrometry (GC-MS). Besides CBP, CBDP, Δ9-THCP and Δ8-THCP and some terpenes, other compounds were found which probably result from a synthetic procedure. This sample contained 5-heptylresorcinol, the heptyl homologue of olivetol, a common precursor for the synthesis of tetrahydrocannabinol (THC). Bisalkylated compounds (m/z 476) were found as a result of the reaction of one equivalent of 5-heptylresorcinol with two equivalents of (+)-p-mentha-1,8-dien-4-ol or another precursor. Similar bisalkylated compounds are known as undesired side products of the synthesis of THC. The sample contained unidentified isomers of Δ9-THCP, presumably abnormal cannabinoids (abn-Δ9-THCP; abn-Δ8-THCP) and iso-cannabinoids (iso-THCP). Chiral derivatization with Mosher acid chlorides revealed that the Δ9-THCP in the sample was enantiopure.
Punching up the Fun: A Comparison of Enjoyment and In-Task Valance in Virtual Reality Boxing and Treadmill Running
Authors: Greene Daniel R. , Rougeau Kathryn M.
Published: October 2024

Given the overwhelming literature on the beneficial effects of exercise, it is surprising that many individuals do not meet current physical activity guidelines. Among the most often cited reasons for nonadherence to exercise are a lack of time and lack of enjoyment. However, recent technology has provided a new mode of exercise that could change an individual’s perception of exercise. Purpose: Compare in-task valance during and enjoyment after a bout of moderate-intensity continuous exercise (MICE) and virtual reality boxing (VRB). Methods: Participants [N = 20, 8 females; age (M ± SD); 26.1 ± 7.2 yrs; BMI (M ± SD); 26.4 ± 5.8] completed a 5 min warm-up, 20 min MICE and VRB workout, and a 5 min cool-down. The in-task valance, heart rate, and rating of perceived exertion (RPE) were assessed during, and enjoyment was assessed immediately after each condition. Results: Participants reported more positive in-task valence [Cohen’s d = 0.59] and greater post-exercise enjoyment [Cohen’s d = 1.76] during VRB relative to MICE. Further, participants reported higher RPE [Cohen’s d = 0.53] and heart rates [Cohen’s d = 0.52] during VRB. Conclusion: Virtual reality boxing resulted in significantly greater in-task valence and post-exercise enjoyment relative to traditional cardio. As both in-task valence and enjoyment have been linked to exercise adherence, virtual reality exercise should be considered as a means to increase exercise adherence.
Strength and Absorption Study on Eco-Efficient Concrete Using Recycled Powders as Mineral Admixtures under Various Curing Conditions
Authors: Herki Bengin M. A.
Published: October 2024

Durable building materials are essential for sustainability in construction projects, aiming to reduce environmental damage from the start to the end of a building’s life. Reducing the use of Portland cement in concrete production is essential because of the significant CO2 emissions generated globally during its production process. This study investigates the workability, compressive strength, and water absorption of concrete when Portland cement is partially substituted with waste glass powder (WGP) and recycled concrete powder (RCP). These two waste powders can be used to partially substitute Portland cement in order to produce environmentally friendly concrete. The activity of the particles in concrete made from these two waste powders is mostly determined by the type and rate of the powders, as well as the curing methods. Therefore, the current research examines how different curing conditions impact the workability, compressive strength, and water absorption characteristics of this innovative eco-friendly concrete that includes the abovementioned waste powders. According to the experimental results obtained, adequate strength can be achieved using an appropriate replacement level of the powders and curing methods. Therefore, the application of these two recycled mineral admixtures in concrete can save Portland cement and has certain environmental and economic benefits.
Employment Rights of Teachers in Faith Schools: Maximising the Religious Rights of Schools and Staff
Authors: Vickers Lucy
Published: October 2024

This paper considers the legacy of the historic contribution of faith communities to education for the employment rights of teachers in schools with a religious character. The contribution of faith communities to state education was originally reflected in a settlement by which staffing could reflect the religious foundations of the school. This paper traces the development of the legal framework covering employment by religious ethos employers, in particular the introduction of more generous protection for religious equality at work. As a result, the position of teachers in faith schools in England has diverged significantly from that of staff employed by other religious ethos organisations. The anomalous position of teachers in faith schools arises because the legal position is dependent on the historical foundations of the school rather than on the current religious practice of the school. This situation is at odds with the wider legal framework in which protection against religious discrimination and the protection for freedom of religion must be justified with reference to the genuine and current religious needs of the organisation. The paper concludes with proposals for reform that maximise the rights of both teachers and communities of faith, without unduly restricting the rights of either.
Typhoon Early Warning and Monitoring Based on the Comprehensive Characteristics of Oceanic and Ionospheric Echoes from HFSWR: The Case of Typhoon Muifa
Authors: Jiang Menghua , Ji Yonggang , Qu Ruozhao , Zhang Hao , Du Jianqiang
Published: October 2024

As devastating natural disasters, typhoons pose a tremendous threat to human society, making effective typhoon early warning and monitoring crucial. To address this challenge, High Frequency Surface Wave Radar (HFSWR), which can observe oceanic parameters such as typhoon wind fields in real time and even capture the dynamic changes in the ionosphere, has become an effective tool for typhoon monitoring. This paper investigates the interaction mechanisms about Typhoon-Acoustic Gravity Waves (AGWs)-Ionosphere, as well as Typhoon-Ocean Waves for HFSWR, and simulates these interaction processes within HFSWR. Then a typhoon early warning and monitoring scheme for HFSWR has been proposed: In the first stage, the S-shaped ionospheric disturbances observed by HFSWR are utilized as precursor signals for early typhoon warnings. In addition, the second stage involves analyzing changes in first-order oceanic echo spectral peak ratio to pinpoint when the typhoon eye enters the radar detection range, thus initiating the typhoon monitoring phase. Subsequently, the measured data from HFSWR collected during Typhoon “Muifa” (2212) in conjunction with the proposed scheme are evaluated in detail. The results indicate that AGWs generated by typhoons can propagate into non-typhoon areas within the detection range, causing S- shaped ionospheric disturbances and providing approximately 6 h of early warning. At around 8:05 (UTC+8), an increasing trend in the first-order spectral peak ratio was noted, indicating the entry of the typhoon eye into the detection range, which closely aligns with the official typhoon path and marks the transition to the monitoring phase. The proposed scheme is expected to enhance the capability for typhoon early warning and real-time monitoring in specific sea areas and mitigate the risks associated with typhoon-related disasters.