bluuebunny/crossref_metadata_2025 huggingface dataset:
Developing Healthy Lifestyle Behaviors in Early Age—An Intervention Study in Kindergartens
Authors: Jakobovich Ronit , Berry Elliot M. , Levita Asia , Levin-Zamir Diane
Published: June 2023

Childhood obesity prevention is a leading public health challenge requiring the adoption of healthy lifestyles at an early age. We examined how the kindergarten environment can promote eating sensibly, drinking water and becoming physically active. The effects of an intervention program among 42 Israeli kindergartens (1048 children, aged 4–6) whose teachers participated in a health education training program were compared to 32 kindergartens (842 children) whose teachers did not undergo this training program. An eight-month intervention program focused on knowledge/mathematical/logical/critical thinking, self-regulation/control acquisition, and sensible decision-making abilities. We hypothesized that nutrition and physical-exercise-oriented intervention programs, combining knowledge/mathematical logical thinking, would positively impact the quality of children’s mid-morning snack and water consumption, their ability to express feelings following physical exercise, and the adoption of healthy lifestyles at home. The quality of mid-morning snacks and water consumption were observed in both groups pre- and post-intervention. Qualitative interviews documented children’s subjective feelings following physical exercise. A significant improvement (p < 0.001) was observed in the mid-morning snacks composition and in water drinking habits in the intervention group; 80% of children offered a physiological explanation regarding energy expenditure processes following intense physical exercise. In conclusion, kindergarten interventions implemented by trained teachers can promote adoption of health behaviors necessary for obesity prevention.
Post-Effects of Time-Restricted Feeding against Adipose Tissue Inflammation and Insulin Resistance in Obese Mice
Authors: Yun Narae , Nah Jiyeon , Lee Mi Nam , Wu Dayong , Pae Munkyong
Published: June 2023

Time-restricted feeding (TRF) has been shown to improve the disordered metabolic and immunologic functions associated with obesity, however little is known about its post-effects after the cessation of TRF practice. In the current study, we determined how long the effects of TRF persist, and whether the effects are tissue-dependent. There were four groups of mice in this study: overweight and obese mice were randomized into (1) TRF group (TRF for 6 weeks), (2) post-TRF group (TRF for 4 weeks and later ad libitum), (3) continuous ad libitum of high-fat diet (HFD-AL), and (4) the lean control-fed low-fat diet ad libitum. Blood, liver, and adipose tissues were collected to measure the metabolic, inflammatory, and immune cell parameters. The results showed that TRF withdrawal quickly led to increased body weight/adiposity and reversed fasting blood glucose. However, fasting insulin and insulin resistance index HOMA-IR remained lower in the post-TRF than in the HFD-AL group. In addition, TRF-induced reduction in blood monocytes waned in the post-TRF group, but the TRF effects on mRNA levels of proinflammatory immune cells (macrophages Adgre1 and Itgax) and cytokine (Tnf) in adipose tissue remained lower in the post-TRF group than in the HFD-AL group. Furthermore, the TRF group was protected from the down-regulation of Pparg mRNA expression in adipose tissue, which was also observed in the post-TRF group to a lesser extent. The post-TRF animals displayed liver mass similar to those in the TRF group, but the TRF effects on the mRNA of inflammation markers in the liver vanished completely. Together, these results indicate that, although the lasting effects of TRF may differ by tissues and genes, the impact of TRF on adipose tissue inflammation and immune cell infiltration could last a couple of weeks, which may, in part, contribute to the maintenance of insulin sensitivity even after the cessation of TRF.
A Critical Review on Vasoactive Nutrients for the Management of Endothelial Dysfunction and Arterial Stiffness in Individuals under Cardiovascular Risk
Authors: da Silva Davi Vieira Teixeira , Baião Diego dos Santos , Almeida Cristine Couto , Paschoalin Vania Margaret Flosi
Published: June 2023

Pathophysiological conditions such as endothelial dysfunction and arterial stiffness, characterized by low nitric oxide bioavailability, deficient endothelium-dependent vasodilation and heart effort, predispose individuals to atherosclerotic lesions and cardiac events. Nitrate (NO3−), L-arginine, L-citrulline and potassium (K+) can mitigate arterial dysfunction and stiffness by intensifying NO bioavailability. Dietary compounds such as L-arginine, L-citrulline, NO3− and K+ exert vasoactive effects as demonstrated in clinical interventions by noninvasive flow-mediated vasodilation (FMD) and pulse-wave velocity (PWV) prognostic techniques. Daily L-arginine intakes ranging from 4.5 to 21 g lead to increased FMD and reduced PWV responses. Isolated L-citrulline intake of at least 5.6 g has a better effect compared to watermelon extract, which is only effective on endothelial function when supplemented for longer than 6 weeks and contains at least 6 g of L-citrulline. NO3− supplementation employing beetroot at doses greater than 370 mg promotes hemodynamic effects through the NO3−-NO2-/NO pathway, a well-documented effect. A potassium intake of 1.5 g/day can restore endothelial function and arterial mobility, where decreased vascular tone takes place via ATPase pump/hyperpolarization and natriuresis, leading to muscle relaxation and NO release. These dietary interventions, alone or synergically, can ameliorate endothelial dysfunction and should be considered as adjuvant therapies in cardiovascular diseases.
The Effect of a Low-Carbohydrate High-Fat Diet on Laboratory Parameters in Women with Lipedema in Comparison to Overweight/Obese Women
Authors: Jeziorek Małgorzata , Szuba Andrzej , Sowicz Monika , Adaszyńska Agnieszka , Kujawa Krzysztof , Chachaj Angelika
Published: June 2023

The aim of this study was to evaluate alterations in blood parameters after a low-carbohydrate high-fat (LCHF) diet in women with lipedema in comparison to overweight or obese women. A total of 115 women were classified into two groups: the lipedema group and the overweight/obesity group. Both study groups followed the caloric-restricted LCHF diet for 7 months. A total of 48 women completed the study. A reduction in body weight was observed in both study groups. A significant decrease in triglycerides and an increase in HDL-C concentrations were observed in both study groups. Despite the increase in the concentration of LDL-C observed in the lipedema group, changes in LDL-C differed between individual patients. Improvements in liver parameters, glucose tolerance, and a decrease in fasting insulin levels were observed, although they were less pronounced in the lipedema group than in the overweight/obesity group. Kidney and thyroid functions were similar before and after the LCHF diet in both groups. The LCHF diet may be a valuable nutritional strategy for lipedema and overweight/obese women, with a beneficial effect on weight, glucose profile, liver function, the concentration of triglycerides, and HDL-C and with no effect on kidney and thyroid function.
Toward the System Size Dependence of Anisotropic Flow in Heavy-Ion Collisions at sNN= 2–5 GeV
Authors: Mamaev Mikhail , Taranenko Arkadiy
Published: June 2023

The study of the high-density equation of state (EOS) and the search for a possible phase transition in dense baryonic matter is the main goal of beam energy scan programs with relativistic heavy ions at energies sNN= 2–5 GeV. The most stringent constraints currently available on the high-density EOS of symmetric nuclear matter come from the present measurements of directed (v1) and elliptic flow (v2) signals of protons in Au + Au collisions. In this energy range, the anisotropic flow is strongly affected by the presence of cold spectators due to the sizable passage time. The system size dependence of anisotropic flow may help to study the participant–spectator contribution and improve our knowledge of the EOS of symmetric nuclear matter. In this work, we discuss the layout of the upgraded BM@N experiment and the anticipated performance for differential anisotropic flow measurements of identified hadrons at Nuclotron energies: sNN= 2.3–3.5 GeV.
Investigating Non-Pharmacological Stress Reduction Interventions in Pediatric Patients Confirmed with Salivary Cortisol Levels: A Systematic Review
Authors: Grigoropoulou Maria , Kapetanakis Emmanouil I. , Attilakos Achilleas , Charalampopoulos Anestis , Dimopoulou Anastasia , Vamvakas Efstratios , Mavrigiannaki Eleftheria , Zavras Nikolaos
Published: June 2023

For many children, hospitalization can lead to a state of increased anxiety. Being away from home, the invasive procedures undertaken, and the uncertainty of the outcome cause an uncomfortable situation in anticipation of real or imagined hazards. This systematic review aims to assess current evidence on the types of non-pharmacological interventions used and their impact on children’s anxiety or distress levels when they visit the hospital for planned or unplanned admissions. The Databases PubMed, Psych INFO, and Google Scholar were queried for papers published from January 2000 to March 2023 reporting the use of non-pharmacological interventions interacting with children in hospital or clinical environments and confirmed with saliva cortisol levels. A total of nine studies were retrieved. Across these studies, four different strategies of non-pharmacological interventions were used. Anxiety and distress were found to be reduced in the majority of the studies as confirmed with salivary cortisol. Overall, there is evidence that non-pharmacological interventions hold a promising role in reducing levels of anxiety or distress in children as confirmed with saliva cortisol. However, research on saliva cortisol as a tool of anxiety measurement requires higher quality studies to strengthen the evidence base.
Carbon Dots–Biomembrane Interactions and Their Implications for Cellular Drug Delivery
Authors: Mavroidi Barbara , Kaminari Archontia , Sakellis Elias , Sideratou Zili , Tsiourvas Dimitris
Published: June 2023

The effect of carbon dots (CDs) on a model blayer membrane was studied as a means of comprehending their ability to affect cell membranes. Initially, the interaction of N-doped carbon dots with a biophysical liposomal cell membrane model was investigated by dynamic light scattering, z-potential, temperature-modulated differential scanning calorimetry, and membrane permeability. CDs with a slightly positive charge interacted with the surface of the negative-charged liposomes and evidence indicated that the association of CDs with the membrane affects the structural and thermodynamic properties of the bilayer; most importantly, it enhances the bilayer’s permeability against doxorubicin, a well-known anticancer drug. The results, like those of similar studies that surveyed the interaction of proteins with lipid membranes, suggest that carbon dots are partially embedded in the bilayer. In vitro experiments employing breast cancer cell lines and human healthy dermal cells corroborated the findings, as it was shown that the presence of CDs in the culture medium selectively enhanced cell internalization of doxorubicin and, subsequently, increased its cytotoxicity, acting as a drug sensitizer.
Plant Extracts as a Source of Natural Products with Potential Antimalarial Effects: An Update from 2018 to 2022
Authors: Ribeiro Giovane de Jesus Gomes , Rei Yan Sun Liu , Palmisano Giuseppe , Wrenger Carsten
Published: June 2023

Malaria kills more than 500,000 people yearly, mainly affecting Africa and Southeast Asia. The disease is caused by the protozoan parasite from the genus Plasmodium, with Plasmodium vivax and Plasmodium falciparum being the main species that cause the disease in humans. Although substantial progress has been observed in malaria research in the last years, the threat of the spread of Plasmodium parasites persists. Artemisinin-resistant strains of this parasite have been reported mainly in Southeast Asia, highlighting the urgent need to develop more effective and safe antimalarial drugs. In this context, natural sources, mainly from flora, remain underexplored antimalarial spaces. The present mini-review explores this space focusing on plant extracts and some of their isolated natural products with at least in vitro antiplasmodial effects reported in the literature comprising the last five years (2018–2022).
Extracellular Vesicles and Intercellular Communication: Challenges for In Vivo Molecular Imaging and Tracking
Authors: Petroni Debora , Fabbri Costanza , Babboni Serena , Menichetti Luca , Basta Giuseppina , Del Turco Serena
Published: June 2023

Extracellular vesicles (EVs) are a heterogeneous class of cell-derived membrane vesicles released by various cell types that serve as mediators of intercellular signaling. When released into circulation, EVs may convey their cargo and serve as intermediaries for intracellular communication, reaching nearby cells and possibly also distant organs. In cardiovascular biology, EVs released by activated or apoptotic endothelial cells (EC-EVs) disseminate biological information at short and long distances, contributing to the development and progression of cardiovascular disease and related disorders. The significance of EC-EVs as mediators of cell–cell communication has advanced, but a thorough knowledge of the role that intercommunication plays in healthy and vascular disease is still lacking. Most data on EVs derive from in vitro studies, but there are still little reliable data available on biodistribution and specific homing EVs in vivo tissues. Molecular imaging techniques for EVs are crucial to monitoring in vivo biodistribution and the homing of EVs and their communication networks both in basal and pathological circumstances. This narrative review provides an overview of EC–EVs, trying to highlight their role as messengers of cell–cell interaction in vascular homeostasis and disease, and describes emerging applications of various imaging modalities for EVs visualization in vivo.
Targeted Anticancer Agent with Original Mode of Action Prepared by Supramolecular Assembly of Antibody Oligonucleotide Conjugates and Cationic Nanoparticles
Authors: Lehot Victor , Neuberg Patrick , Ripoll Manon , Daubeuf François , Erb Stéphane , Dovgan Igor , Ursuegui Sylvain , Cianférani Sarah , Kichler Antoine , Chaubet Guilhem , Wagner Alain
Published: June 2023

Despite their clinical success, Antibody-Drug Conjugates (ADCs) are still limited to the delivery of a handful of cytotoxic small-molecule payloads. Adaptation of this successful format to the delivery of alternative types of cytotoxic payloads is of high interest in the search for novel anticancer treatments. Herein, we considered that the inherent toxicity of cationic nanoparticles (cNP), which limits their use as oligonucleotide delivery systems, could be turned into an opportunity to access a new family of toxic payloads. We complexed anti-HER2 antibody-oligonucleotide conjugates (AOC) with cytotoxic cationic polydiacetylenic micelles to obtain Antibody-Toxic-Nanoparticles Conjugates (ATNPs) and studied their physicochemical properties, as well as their bioactivity in both in vitro and in vivo HER2 models. After optimising their AOC/cNP ratio, the small (73 nm) HER2-targeting ATNPs were found to selectively kill antigen-positive SKBR-2 cells over antigen-negative MDA-MB-231 cells in serum-containing medium. Further in vivo anti-cancer activity was demonstrated in an SKBR-3 tumour xenograft model in BALB/c mice in which stable 60% tumour regression could be observed just after two injections of 45 pmol of ATNP. These results open interesting prospects in the use of such cationic nanoparticles as payloads for ADC-like strategies.
Synthesis, Biophysical Properties, and Antitumor Activity of Antisense Oligonucleotides Conjugated with Anisamide
Authors: Zhang Zhe , Chen Zuyi , Li Cheng , Xiao Zhenyu , Luo Yuan , Pan Xiaochen , Xu Liang , Feng Xuesong
Published: June 2023

Antisense oligonucleotides (ASONs) have proven potential for the treatment of various diseases. However, their limited bioavailability restricts their clinical application. New structures with improved enzyme resistance stability and efficient drug delivery are needed. In this work, we propose a novel category of ASONs bearing anisamide conjugation at phosphorothioate sites for oncotherapy. ASONs can be conjugated with the ligand anisamide very efficiently and flexibly in a solution. The conjugation sites and the ligand amount both influence anti-enzymatic stability and cellular uptake, resulting in changes in antitumor activity that are detectable by cytotoxicity assay. The conjugate with double anisamide (T6) was identified as the optimal conjugate, and its antitumor activity and the underlying mechanism were examined further in vitro and in vivo. This paper presents a new strategy for the design of nucleic acid-based therapeutics with improved drug delivery and biophysical and biological efficacy.
Quantum Light Source Based on Semiconductor Quantum Dots: A Review
Authors: Li Rusong , Liu Fengqi , Lu Quanyong
Published: June 2023

Quantum light sources that generate single photons and entangled photons have important applications in the fields of secure quantum communication and linear optical quantum computing. Self-assembled semiconductor quantum dots, also known as “artificial atoms”, have discrete energy-level structures due to electronic confinement in all three spatial dimensions. It has the advantages of high stability, high brightness, deterministic, and tunable emission wavelength, and is easy to integrate into an optical microcavity with a high-quality factor, which can realize a high-performance quantum light source. In this paper, we first introduce the generation principles, properties, and applications of single-photon sources in the field of quantum information and then present implementations and development of quantum light sources in self-assembled semiconductor quantum dot materials. Finally, we conclude with an outlook on the future development of semiconductor quantum dot quantum light sources.
Self-Starting Soliton–Comb Regimes in χ(2) Microresonators
Authors: Smirnov Sergey , Podivilov Evgeni , Sturman Boris
Published: June 2023

The discovery of stable and broad frequency combs in monochromatically pumped high-Q optical Kerr microresonators caused by the generation of temporal solitons can be regarded as one of the major breakthroughs in nonlinear optics during the last two decades. The transfer of the soliton–comb concept to χ(2) microresonators promises lowering of the pump power, new operation regimes, and entering of new spectral ranges; scientifically, it is a big challenge. Here we represent an overview of stable and accessible soliton–comb regimes in monochromatically pumped χ(2) microresonators discovered during the last several years. The main stress is made on lithium niobate-based resonators. This overview pretends to be rather simple, complete, and comprehensive: it incorporates the main factors affecting the soliton–comb generation, such as the choice of the pumping scheme (pumping to the first or second harmonic), the choice of the phase matching scheme (natural or artificial), the effects of the temporal walk off and dispersion coefficients, and also the influence of frequency detunings and Q-factors. Most of the discovered nonlinear regimes are self-starting—they can be accessed from noise upon a not very abrupt increase in the pump power. The soliton–comb generation scenarios are not universal—they can be realized only under proper combinations of the above-mentioned factors. We indicate what kind of restrictions on the experimental conditions have to be imposed to obtain the soliton–comb generation.
Dual-Parameter Sensor for Temperature and Strain Measurement Based on Antiresonance Effect and Few-Mode Fiber
Authors: Jiang Shaocui , Yang Peng , Wang Zenghui , Zhang Yujuan , Bao Wangge , Peng Baojin
Published: June 2023

A simple and novel hybrid interferometer based on the antiresonance (AR) effect and Mach–Zehnder interference (MZI), which enables simultaneous measurement of temperature and strain, is proposed and investigated. The sensor is made by cascading a 30 cm section of a few-mode fiber (FMF) and a 3.376 mm hollow-core fiber (HCF) through a single-mode fiber (SMF). The FMF and SMF are fused without misalignment to excite two stable modes, thereby forming a Mach–Zehnder interferometer. Concurrently, the introduction of HCF can effectively excite the AR effect, which is manifested in the transmission spectrum as two different dips at the same time caused by the difference in the two physical mechanisms, showing diverse responses to both external temperature and strain. This difference can be used to construct a cross-coefficient matrix to implement the simultaneous measurement of temperature and strain. The experimental results demonstrate that the AR effect and MZI correspond to strain sensitivities of –0.87 and –2.29 pm/µε, respectively, and temperature sensitivities of 15.68 and –13.93 pm/°C, respectively. Furthermore, the sensor is also tested for repeatability, and the results show that it has good repeatability and great potential in sensing applications.
Tunable Random Fiber Laser Based on Dual-Grating Structure
Authors: Niu Yanan , Jia Pinggang , Su Jianhui , Wang Jingyi , An Guowen , Ren Qianyu , Xiong Jijun
Published: June 2023

In order to reduce the pumping threshold and achieve a short-cavity single-mode transmission with a narrow-linewidth random fiber laser, we propose a tunable random fiber laser based on the combination of random grating and highly reflective fiber Bragg grating (FBG). Theoretical modeling of a random refractive index-modulated fiber grating was carried out. Random grating is regarded as a linear combination of uniform fiber gratings with different periods. Simulation calculations were performed using the transfer matrix method to determine the preparation parameters. Under the premise of satisfying light localization, a point-by-point method was used to write a random grating in a single-mode fiber using a femtosecond laser according to the simulated parameters. We constructed a random fiber laser with a linewidth of 1.68 kHz and a threshold of 29.2 mW using a random grating and a highly reflective FBG combined with an erbium-doped fiber. Due to the broad scattered wavelength range of the random grating, by changing the central wavelength of the high-reflection FBG, the tunable wavelength of the output laser was realized, and the tunable range was 0.847 nm (1549.110–1549.957 nm). Moreover, the laser’s central wavelength and output power are stable for a long time. Compared with other lasers, the proposed laser has the advantages of a lower threshold, shorter cavity length, narrower linewidth, and a relatively simple structure.
Improving the Mechanical Properties of CCFRPLA by Enhancing the Interface Binding Energy and Strengthening the Anti-Separation Ability of a PLA Matrix
Authors: Li Hongbin , Li Zhihua , Wang Na , Peng Yubao , Jiang Zhuang , Zhang Qiushuang
Published: June 2023

Additive manufacturing (AM) can produce almost any product shape through layered stacking. The usability of continuous fiber-reinforced polymers (CFRP) fabricated by AM, however, is restricted owing to the limitations of no reinforcing fibers in the lay-up direction and weak interface bonding between the fibers and matrix. This study presents molecular dynamics in conjunction with experiments to explore how ultrasonic vibration enhances the performance of continuous carbon fiber-reinforced polylactic acid (CCFRPLA). Ultrasonic vibration improves the mobility of PLA matrix molecular chains by causing alternative fractures of chains, promoting crosslinking infiltration among polymer chains, and facilitating interactions between carbon fibers and the matrix. The increase in entanglement density and conformational changes enhanced the density of the PLA matrix and strengthened its anti-separation ability. In addition, ultrasonic vibration shortens the distance between the molecules of the fiber and matrix, improving the van der Waals force and thus promoting the interface binding energy between them, which ultimately achieves an overall improvement in the performance of CCFRPLA. The bending strength and interlaminar shear strength of the specimen treated with 20 W ultrasonic vibration reached 111.5 MPa and 10.16 MPa, respectively, 33.11% and 21.5% higher than those of the untreated specimen, consistent with the molecular dynamics simulations, and confirmed the effectiveness of ultrasonic vibration in improving the flexural and interlaminar properties of the CCFRPLA.
Pore Structure Tuning of Poly-EGDMA Biomedical Material by Varying the O-Quinone Photoinitiator
Authors: Yudin Vladimir V. , Shurygina Margarita P. , Egorikhina Marfa N. , Aleynik Diana Ya. , Linkova Daria D. , Charykova Irina N. , Kovylin Roman S. , Chesnokov Sergey A.
Published: June 2023

Porous polymer monoliths with thicknesses of 2 and 4 mm were obtained via polymerization of ethylene glycol dimethacrylate (EGDMA) under the influence visible-light irradiation in the presence of a 70 wt% 1-butanol porogenic agent and o-quinone photoinitiators. The o-quinones used were: 3,5-di-tret-butyl-benzoquinone-1,2 (35Q), 3,6-di-tret-butyl-benzoquinone-1,2 (36Q), camphorquinone (CQ), and 9,10-phenanthrenequinone (PQ). Porous monoliths were also synthesized from the same mixture but using 2,2′-azo-bis(iso-butyronitrile) (AIBN) at 100 °C instead o-quinones. According to the results of scanning electron microscopy, all the resulting samples were conglomerates of spherical, polymeric particles with pores between them. Use of mercury porometry showed that the interconnected pore systems of all the polymers were open. The average pore size, Dmod, in such polymers strongly depended on both the nature of the initiator and the method of initiation of polymerization. For polymers obtained in the presence of AIBN, the Dmod value was as low as 0.8 μm. For polymers obtained via photoinitiation in the presence of 36Q, 35Q, CQ, and PQ, the Dmod values were significantly greater, i.e., 9.9, 6.4, 3.6, and 3.7 μm, respectively. The compressive strength and Young’s modulus of the porous monoliths increased symbatically in the series PQ < CQ < 36Q < 35Q < AIBN with decreasing proportions of large pores (over 12 μm) in their polymer structures. The photopolymerization rate of the EGDMA and 1-butanol, 30:70 wt% mixture was maximal for PQ and minimal for 35Q. All polymers tested were non-cytotoxic. Based on the data from MTT testing, it can be noted that the polymers obtained via photoinitiation were characterized by their positive effect on the proliferative activity of human dermal fibroblasts. This makes them promising osteoplastic materials for clinical trials.
Evaluating the Effect of Iron(III) in the Preparation of a Conductive Porous Composite Using a Biomass Waste-Based Starch Template
Authors: Rodríguez-Quesada Laria , Ramírez-Sánchez Karla , León-Carvajal Sebastián , Sáenz-Arce Giovanni , Vásquez-Sancho Fabián , Avendaño-Soto Esteban , Montero-Rodríguez Juan José , Starbird-Perez Ricardo
Published: June 2023

In this work, the effect of iron(III) in the preparation of a conductive porous composite using a biomass waste-based starch template was evaluated. Biopolymers are obtained from natural sources, for instance, starch from potato waste, and its conversion into value-added products is highly significant in a circular economy. The biomass starch-based conductive cryogel was polymerized via chemical oxidation of 3,4-ethylenedioxythiophene (EDOT) using iron(III) p-toluenesulfonate as a strategy to functionalize porous biopolymers. Thermal, spectrophotometric, physical, and chemical properties of the starch template, starch/iron(III), and the conductive polymer composites were evaluated. The impedance data of the conductive polymer deposited onto the starch template confirmed that at a longer soaking time, the electrical performance of the composite was improved, slightly modifying its microstructure. The functionalization of porous cryogels and aerogels using polysaccharides as raw materials is of great interest for applications in electronic, environmental, and biological fields.
Development of BioPolyurethane Coatings from Biomass-Derived Alkylphenol Polyols—A Green Alternative
Authors: Silva Tiago A. R. , Marques Ana C. , dos Santos Rui G. , Shakoor Rana A. , Taryba Maryna , Montemor Maria Fátima
Published: June 2023

Bio-based polyols were obtained from the thermochemical liquefaction of two biomass feedstocks, pinewood and Stipa tenacissima, with conversion rates varying between 71.9 and 79.3 wt.%, and comprehensively characterized. They exhibit phenolic and aliphatic moieties displaying hydroxyl (OH) functional groups, as confirmed by attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR) and nuclear magnetic resonance spectroscopy (NMR) analysis. The biopolyols obtained were successfully employed as a green raw material to produce bio-based polyurethane (BioPU) coatings on carbon steel substrates, using, as an isocyanate source, a commercial bio-based polyisocyanate—Desmodur® Eco N7300. The BioPU coatings were analyzed in terms of chemical structure, the extent of the reaction of the isocyanate species, thermal stability, hydrophobicity, and adhesion strength. They show moderate thermal stability at temperatures up to 100 °C, and a mild hydrophobicity, displaying contact angles between 68° and 86°. The adhesion tests reveal similar pull-off strength values (ca. 2.2 MPa) for the BioPU either prepared with pinewood and Stipa-derived biopolyols (BPUI and BPUII). Electrochemical impedance spectroscopy (EIS) measurements were carried out on the coated substrates for 60 days in 0.05 M NaCl solution. Good corrosion protection properties were achieved for the coatings, with particular emphasis on the coating prepared with the pinewood-derived polyol, which exhibited a low-frequency impedance modulus normalized for the coating thickness of 6.1 × 1010 Ω cm at the end of the 60 days test, three times higher than for coatings prepared with Stipa-derived biopolyols. The produced BioPU formulations show great potential for application as coatings, and for further modification with bio-based fillers and corrosion inhibitors.
Flame-Retardance Functionalization of Jute and Jute-Cotton Fabrics
Authors: Begum Most Setara , Kader Abdul , Milašius Rimvydas
Published: June 2023

Jute is a ligno-cellulosic natural fiber that ranks second in terms of the volume of cellulosic fibers and is extensively utilized for technical textile applications. The goal of this study is to determine the flame-retardance (FR) properties of pure Jute and Jute-Cotton fabrics treated with Pyrovatex CP New at concentrations of 90% (owf), M:L: 1:7. Both fabrics exhibited a substantial improvement in flame-retardancy. After the ignition period, the recorded flame spread time in both FR treated fabrics was zero seconds; whereas for untreated Jute and Jute-Cotton fabrics, the flame spread time was measured 21 s and 28 s, respectively, to burn their entire length (15 cm). Within these flame-spread times, the length of the char was 2.1 cm and 2.57 cm in the Jute and Jute-Cotton fabrics, respectively. After FR finishing, on both fabrics in the warp and weft directions, the physico-mechanical properties significantly decreased. The deposition of flame-retardant finishes on the fabric surface was determined by Scanning Electron Microscope (SEM) images. According to Fourier Transform Infra-Red Spectroscopy (FTIR) analysis, the flame-retardant chemical had no effect on the inherent properties of the fibers. Thermogravimetric analysis (TGA) analysis revealed that FR treated fabrics had early degradation, resulting in the formation of more char than in the untreated samples. After FR treatment, both fabrics showed a significant improvement in residual mass (more than 50%). Although the formaldehyde content observed in the FR treated samples was significantly greater, it was still within the permitted limit formaldehyde content in textiles intended for outerwear and not worn next to the skin. The results of this investigation demonstrate the potential use of Pyrovatex CP New in jute-based materials.
Catechol-Based Porous Organic Polymers for Effective Removal of Phenolic Pollutants from Water
Authors: Zhao Xiaoxiao , Liu Yiqiong , Zhu Qimeng , Gong Weitao
Published: June 2023

Phenolic pollutants released from industrial activities seriously damage natural freshwater resources, and their elimination or reduction to safe levels is an urgent challenge. In this study, three catechol-based porous organic polymers, CCPOP, NTPOP, and MCPOP, were prepared using sustainable lignin biomass-derived monomers for the adsorption of phenolic contaminants in water. CCPOP, NTPOP, and MCPOP showed good adsorption performance for 2,4,6-trichlorophenol (TCP) with theoretical maximum adsorption capacities of 808.06 mg/g, 1195.30 mg/g, and 1076.85 mg/g, respectively. In addition, MCPOP maintained a stable adsorption performance after eight consecutive cycles. These results indicate that MCPOP is a potential material for the effective treatment of phenol pollutants in wastewater.
Elastocaloric Waste/Natural Rubber Materials with Various Crosslink Densities
Authors: Candau Nicolas , Zimny Adele , Vives Eduard , Maspoch Maria Lluïsa
Published: June 2023

The characterization of the mechanical behavior of elastocaloric materials is essential to identify their viability in heating/cooling devices. Natural rubber (NR) is a promising elastocaloric (eC) polymer as it requires low external stress to induce a wide temperature span, ΔT. Nonetheless, solutions are needed to further improve DT, especially when targeting cooling applications. To this aim, we designed NR-based materials and optimized the specimen thickness, the density of their chemical crosslinks, and the quantity of ground tire rubber (GTR) used as reinforcing fillers. The eC properties under a single and cyclic loading conditions of the resulting vulcanized rubber composites were investigated via the measure of the heat exchange at the specimen surface using infrared thermography. The highest eC performance was found with the specimen geometry with the lowest thickness (0.6 mm) and a GTR content of 30 wt.%. The maximum temperature span under single interrupted cycle and multiple continuous cycles were equal to 12 °C and 4 °C, respectively. These results were assumed to be related to more homogeneous curing in these materials and to a higher crosslink density and GTR content which both act as nucleating elements for the strain-induced crystallization at the origin of the eC effect. This investigation would be of interest for the design of eC rubber-based composites in eco-friendly heating/cooling devices.
Stability Studies, Biodegradation Tests, and Mechanical Properties of Sodium Alginate and Gellan Gum Beads Containing Surfactant
Authors: Stachowiak Natalia , Kowalonek Jolanta , Kozlowska Justyna , Burkowska-But Aleksandra
Published: June 2023

The excessive presence of single-use plastics is rapidly degrading our natural environment on a global scale due to their inherent resistance to decomposition. Wet wipes used for personal or household purposes contribute significantly to the accumulation of plastic waste. One potential solution to address this problem involves developing eco-friendly materials that possess the ability to degrade naturally while retaining their washing capabilities. For this purpose, the beads from sodium alginate, gellan gum, and a mixture of these natural polymers containing surfactant were produced using the ionotropic gelation method. Stability studies of the beads by observing their appearance and diameter were performed after incubation in solutions of different pH values. The images showed that macroparticles were reduced in size in an acidic medium and swelled in solution of pH-neutral phosphate-buffered saline. Moreover, all the beads first swelled and then degraded in alkaline conditions. The beads based on gellan gum and combining both polymers were the least sensitive to pH changes. The compression tests revealed that the stiffness of all macroparticles decreased with the increasing pH of the solutions in which they were immersed. The studied beads were more rigid in an acidic solution than in alkaline conditions. The biodegradation of macroparticles was assessed using a respirometric method in soil and seawater. It is important to note that the macroparticles degraded more rapidly in soil than in seawater.
Numerical Simulation of Dynamic Variation Characteristics of Particles in a Rolling Fluidized Bed
Authors: Huang Jiale , Wang Ruojin , Xu Rongsheng , Wu Banghua , Wang Dewu , Liu Yan , Zhang Shaofeng
Published: June 2023

When transplanting the gas–solid fluidized bed technology to the offshore floating platform, the gas–solid flow characteristics in the bed will be affected by the rolling of the platform. In this paper, the flow field, especially the dynamic variation characteristics of the particles, in a two-dimensional rolling fluidized bed, is investigated using the numerical simulation method. The results show that when the bed is in an inclined position, the gas/particle phases gather in the upper/lower wall region of the inclined bed. During the rolling process of the bed, this behavior results in a periodic change in the gas–solid flow state near the wall region, forming an overall particle internal circulation flow mode of ‘upward flow rate in the upper wall region and downward flow rate in the lower wall region’. The solid holdup in the lower wall region fluctuates at a low amplitude around high values, with a corresponding downward solid flow rate. Meanwhile, the upper wall region has a high frequency and amplitude of solid holdup fluctuations and a corresponding upward solid flow rate. In addition, affected by the Coriolis force, a ‘lag phenomenon’ appears when the inclination angle decreases, compared with the instantaneous inclination angle increase stage. It is anticipated that this paper will provide theoretical guidance for the engineering application of the fluidized bed on the offshore floating platform.
A Novel Model Prediction and Migration Method for Multi-Mode Nonlinear Time-Delay Processes
Authors: Yuan Ping , Zhou Tianhong , Zhao Luping
Published: June 2023

Most industrial processes have nonlinear and time-delay characteristics leading to difficulty in prediction modeling. In addition, the working conditions of most industrial processes are complex, which results in multiple modes. Testing and modeling for each mode is a waste of time and resources. Therefore, it is urgent to complete model migration between different modes. In this work, a new prediction model, a nonlinear autoregressive model with exogenous inputs and back propagation neural network (NARX-BP), is proposed for the nonlinear and time-delay processes, where the input data order of the model is determined by the feedforward neural network (FNN) method, and the nonlinear relation is realized by the BP neural network. For the multi-mode characteristic, a new migration optimization algorithm, input–output slope/bias correction and differential evolution (IOSBC-DE), is provided for using a small amount of data under a new mode to correct the slope and bias of the relationship between the input and output variables through DE. The modeling and migration methods are applied to a wind tunnel system, and the simulation result shows the effectiveness of the proposed method.
Research on Pore-Fracture Characteristics and Adsorption Performance of Main Coal Seams in Lvjiatuo Coal Mine
Authors: Li Wu , Li Jin , Hu Changqing , Xiao Qianlong
Published: June 2023

Gas prevention and control have always been the focus of coal mine safety. The pore structure characteristics and gas adsorption characteristics of coal seams are the key factors affecting gas adsorption and diffusion in coal seams. Lvjiatuo Mine has the characteristics of a high gas content when it enters deep mining. In order to clarify the influence of the pore-fracture structure characteristics of main coal seams in the research area on coal seam gas adsorption and diffusion, and to study the differences in gas adsorption and diffusion ability in different coal seams, low-temperature nitrogen adsorption (LT-N2GA), high-pressure mercury intrusion (MIP) and computerized tomography (μ-CT) were used as characterization methods, and methane isothermal adsorption experiments were carried out to systematically study the pore structure characteristics of five groups of coal samples, and the pore-fracture structure characteristics and gas adsorption characteristics of each main coal seam were obtained. The results show that: (1) in the LT-N2GA experiment, the adsorption–desorption curves of all coal samples are of type III, and mainly develop cone-shaped pores or wedge-shaped semi-closed pores, with an average pore size of 1.84~4.84 nm, a total pore volume of 0.0010~0.0023 mL/g, a total specific surface area of 0.16~0.24 m2/g, and a fractal dimension D1 of 1.39~1.87 and D2 of 2.44~2.60. The micropores of L12 are more developed, and the mesopores and macropores of L9 are more developed. (2) In the MIP experiment, the porosity of coal samples is 3.79~6.94%. The porosity of L9 is the highest, the macropore ratio is the highest, and the gas diffusion ability is also the strongest. (3) In the μ-CT experiment, the porosity of L8-2 and L12 is 12.12% and 10.41%, the connectivity is 51.22% and 61.59%, and the Df is 2.39 and 2.30, respectively. The fracture of L12 is more developed, the connectivity is better, and the heterogeneity of the pore of L8-2 is higher. (4) In the isothermal adsorption experiment of methane, the gas adsorption capacity basically increases with the increase in the buried depth of the coal seam, and the gas adsorption capacity of the No.12 coal seam is the highest. Based on the pore-fracture structure characteristics and gas adsorption characteristics of the main coal seams in the research area, the gas outburst risk of each coal seam is ranked as follows: No.12 coal seam > No.8 coal seam > No.7 coal seam > No.9 coal seam. The experimental results provide important help for researching the structural characteristics of coal seam pore fractures and preventing gas outbursts during deep coal seam mining.
Theoretical and Experimental Analysis of Grinding Stability of Beam Workpiece
Authors: Wu Han , Yao Zhenqiang
Published: June 2023

Grinding chatter is a kind of self-excited vibration in which the grinding system continuously absorbs energy from the grinding machine, increasing the mechanical energy of the system. Grinding chatter can damage the surface of the workpiece and accelerate the abrasion of the grinding wheel. The theoretical analysis of the grinding chatter for the beam surface was launched based on the behavior of a single abrasive grain, whose cutting thickness is a key factor affecting grinding stability. The dynamic grinding force model has been developed, which is the interaction interface between the grinding wheel and the workpiece. In this paper, rail beam grinding was taken as an example. The vibration performance of the rail beam was described with the Timoshenko beam. The characteristics of the frequency domain of the grinding wheel-workpiece system were observed, and the condition of the stability at any position in the longitudinal direction of the beam was gained, which could be quantitatively characterized with the stability limit curve. The grinding experiments of the rail beam surface demonstrated that as chatter developed, the chatter marks could be investigated on the surface of the rail, and the energy of the chatter signal was mainly concentrated around the chatter frequency, which was higher than the natural frequency of the grinding wheel.
Generalized Functional Observer for Descriptor Nonlinear Systems—A Takagi-Sugeno Approach
Authors: Ríos-Ruiz C. , Osorio-Gordillo G.-L. , Astorga-Zaragoza C.-M. , Darouach M. , Souley-Ali H. , Reyes-Reyes J.
Published: June 2023

This paper concerns the design of a generalized functional observer for Takagi–Sugeno descriptor systems. Furthermore, a generalized structure is herein introduced for purposes of estimating linear functions of the states of descriptor nonlinear systems represented into a Takagi–Sugeno descriptor form. The originality of the functional generalized observer structure is that it provides additional degrees of freedom in the observer design, which allows for improvements in the estimation against parametric uncertainties. The effectiveness of the developed design is illustrated by a nonlinear model of a single link robotic arm with a flexible link. A comparison between the functional generalized observer and the functional proportional observer is given to demonstrate the observer performances.
Influence of Inorganic Salt Additives on the Surface Tension of Sodium Dodecylbenzene Sulfonate Solution
Authors: Zhu Biyong , Liu Yan , Wang Pengfei , Liu Ronghua , Jiang Yidan
Published: June 2023

In order to study the effect of inorganic salt additives on the surface tension of a sodium dodecylbenzene sulfonate (SDBS) solution, the surface tension of the mixed system of six common inorganic salt additives, NaCl, CaCl2, AlCl3, Na2SO4, Na2CO3, and NaHCO3, and SDBS was measured, and the effects of the inorganic salt types, surfactant concentrations and inorganic salt concentrations on the surface tension of the SDBS solution were studied. On this basis, three inorganic salts, NaCl, CaCl2 and Na2SO4, were selected, and their effects on the critical micelle concentration (CMC) of the SDBS solution were studied. The experimental results showed that different inorganic salts had different effects on the surface tension of the SDBS solution. The order of effect of the six inorganic salts on the surface tension of the SDBS solution was CaCl2 > NaCl > Na2SO4 > NaHCO3 > Na2CO3 > AlCl3; when the mass fraction of the SDBS solution is high, the influence of the inorganic salts on the surface tension of the SDBS solution is relatively small; with an increase in the concentration of the preferred inorganic salt additives, the surface tension of the SDBS solution decreases first, then tends to be stable, and then increases; a reduction in the critical micelle concentration by the three selected inorganic salt additives shows the trend of 0.7% NaCl > 0.5% CaCl2 > 0.5% Na2SO4.