bluuebunny/crossref_metadata_2025 huggingface dataset:
Persistent Organic Pollutants in Tagus Estuary Salt Marshes: Patterns of Contamination and Plant Uptake
Authors: Cruz de Carvalho Ricardo , Cardoso João , Carreiras João Albuquerque , Santos Paula , Palma Carla , Duarte Bernardo
Published: September 2024

The presence of anthropogenic compounds, including organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs), was studied in three salt marshes within the Tagus estuary, Portugal, along an anthropogenic pressure gradient. Results revealed differences in OCPs and PCBs among the marshes, with differing concentration levels. Specifically, one marsh, with surrounding agricultural activity, showed the highest OCP concentrations, while another, with a historical industrial past, exhibited elevated PCB levels. In contrast, a third marsh, part of a natural reserve, displayed comparatively lower concentrations of both substances. Sediment concentrations, likely influenced by agricultural practices, were found to be comparable to or higher than those observed in other Portuguese estuaries. The halophyte Spartina maritima was found to absorb OCPs, particularly in its aboveground tissues, suggesting bioaccumulation within the plant. Additionally, PCB levels appeared to be influenced by industrial history, with one marsh displaying notably higher concentrations. In conclusion, the persistence of organochlorine compounds in the salt marsh ecosystems notwithstanding the regulatory prohibitions implemented in the 1990s highlights the need for continuous monitoring and study of such sites and the necessity of remediation practices, which are imperative to mitigate ecological and health risks in these polluted salt marshes.
Forecasting the Evolution of the Digital Economy in the Industry of the European Union
Authors: Karavasilis Iordanis , Vrana Vasiliki , Karavasilis George
Published: September 2024

The wide use of telecommunications, computers and the internet, especially over the last four decades, has formed a new economic phenomenon, the “Digital Economy”. As a matter of facts, the development of digitalization has raised questions about its contribution to official economic indicators. This research examines the evolution of the information and communication industry (ICI) and its contribution to the national Gross Domestic Product (GDP) of six European entities. Time series and auto-ARIMA models are employed to process the data. Moreover, this study forecasts the development of the ICI in the future. The results demonstrate a clear stable growth in the variable under examination over time, showing an increasingly greater contribution of the ICI to the national GDP in most cases with the exception of Greece, which has a high provisional risk.
Impact of China’s Permanent Basic Farmland Protection Redline and Ecological Protection Redline on Water Conservation in the Loess Gully Region
Authors: Liu Jie , Zhou Jizhe , He Qin
Published: September 2024

Water conservation is crucial for sustainable ecosystem development in loess gully regions. The redlines of permanent basic farmland protection and ecological protection are key land use control zones in China, yet their impact on water conservation is understudied. The study focuses on Yan’an and constructs three scenarios: natural development (NDS), farmland protection (FPS), and ecological protection (EPS). Then, land use simulation for the three scenarios in 2025, 2030, and 2035 is carried out using the patch-generating land use simulation model. Finally, the integrated valuation of ecosystem services and trade-offs model is combined to calculate water conservation. The findings suggest the following: (1) From the temporal perspective, the water conservation of the three scenarios exhibits an incremental trend by period from 2025 to 2035, with an annual growth rate of approximately 0.65‰ for the NDS, 0.60‰ for the FPS, and 0.64‰ for the EPS. (2) From the scenario perspective, from 2025 to 2035, the annual water conservation under the FPS is 0.35‰ less than that under the NDS, while the impact of the EPS is weak at only ±0.1‰. (3) Across all scenarios, the average water conservation depth of grassland surpasses that of forestland. This study provides scientific evidence to help optimize China’s land space governance policy as well as methodological and theoretical support for related studies.
Maintenance of Lexical Pitch Accent in Heritage Lithuanian: A Study of Perception and Production
Authors: Kantarovich Jessica
Published: September 2024

This study investigates how the unique circumstances of heritage language acquisition impact prosody, an understudied aspect of heritage speech. I examine the perception and production of lexical pitch accent by two generations of heritage Lithuanian speakers in Chicago (n = 13), with a qualitative comparison to one normative native speaker also living in Chicago. The speakers participated in the following: (1) a perception task requiring them to identify meaning distinctions between pairs of words that differ only by accent; and (2) a production task in which they produced sentences containing nine nominal declensions, where pitch accent plays a morphological role. In task (1), speakers across the board were not able to identify meaning distinctions in accent-based minimal pairs, irrespective of their frequency, and were more accurate at perceiving pairs that differed on the basis of segmental phonological features. However, HSs with more education perceived more accent-based distinctions, as did HSs who were more engaged in the Chicago community. Older HSs maintained more distinctions than either the NS or the younger HSs, which suggests a change in progress in the language or the Chicago Lithuanian community. In task (2), none of the speakers consistently used pitch to signal word-level prominence. Instead, all speakers relied on changes in duration and vowel quality to signal word-level prominence, suggesting that, for these speakers, there has been a shift to a stress-accent system. The older HSs also patterned more like the NS in their retention of the expected stress in the nominal declensions. Dialect was also determined to play a role in the retention of standard accent patterns in both perception and production.
Genetic Variants in RANK and OPG Could Influence Disease Severity and Bone Remodeling in Patients with Early Arthritis
Authors: Triguero-Martínez Ana , Pardines Marisa , Montes Nuria , Ortiz Ana María , de la Iglesia-Cedeira Alba , Valero-Martínez Cristina , Martín Javier , González-Álvaro Isidoro , Castañeda Santos , Lamana Amalia
Published: September 2024

The aim of this study was to identify single-nucleotide polymorphisms (SNPs) in bone remodeling-related genes associated with disease severity and bone mineral density (BMD) in early arthritis (EA) patients. For this purpose, the genotyping of 552 SNPs located in gene regions of semaphorins 4b, 4d, 4f, DKK1, 2 and 3, sclerostin, OPG, RANK and RANKL was performed using Immunochip from Illumina Inc. in 268 patients from the Princesa Early Arthritis Register Longitudinal (PEARL) study. Measurements of BMD and disease activity were chosen as outcome variables to select SNPs of interest. The relationships of SNPs with the BMD of the forearm, lumbar spine and hip (Hologic-4500 QDR) were analyzed by linear regression adjusted for age, sex, body mass index and presence of anti-citrullinated peptide antibodies (ACPAs). The association of each SNP with activity variables was analyzed by linear regression, logistic regression or ordered logistic regression according to the variable, and multivariate models were adjusted for potentially confounding variables, such as age, sex and presence of ACPAs. These analyses showed that four SNPs located in the genes coding for RANK (TNFRSF11A) and OPG (TNFRSF11B) were significantly associated with clinical variables of severity. SNP rs1805034 located in exon 6 of TNFRSF11A, which causes a non-synonymous (A/V) mutation, showed significant association with BMD and therefore may be considered as a possible biomarker of severity in RA patients. SNPs in the OPG gene showed an association with serum OPG levels and predicted disease activity after two years of follow-up.
Impact of Nebulized BromAc® on Mucus Plug Clearance in a Mechanically Ventilated Ex Vivo Ovine Lung Model of Obstructive Respiratory Conditions
Authors: Valle Nicole , Eapen Mathew Suji , Pillai Krishna , Morris Richard , Akhter Javed , Mekkawy Ahmed H. , Morris David L. , Valle Sarah J.
Published: September 2024

Mucus plugging of the respiratory tract occurs in airway diseases, including asthma, chronic obstructive pulmonary disease, and cystic fibrosis. It can cause blockage of the airways, leading to breathlessness and lung failure. Here, we used a ventilatory setup to demonstrate the effect of BromAc® in dissolving mucus plugs in a novel ex vivo ovine obstructive lung model. Mucus simulant was filled into the trachea of freshly slaughtered ovine lungs and ventilated via an endotracheal tube (ETT) using Continuous Mandatory Ventilation. Predetermined single or repeated doses of Bromelain, Acetylcysteine (Ac), BromAc®, and saline control were administered via an Aerogen® vibrating nebulizer and ventilated for 30 or 60 min. Ventilatory recording of resistance, compliance, and tidal volume was conducted, and rheology pre- and post-treatment were measured. A significant decline in airway resistance (p < 0.0001) compared to the saline control was observed when treated with Bromelain, Ac, and BromAc®, with the latter showing a stronger mucolytic effect than single agents. The decline in resistance was also effective in shorter time points (p < 0.05) at lower doses of the drugs. Changes in compliance, peak pressure, and tidal volume were not observed after administration of the drugs. Rheology measurements revealed that BromAc®TM significantly reduced the viscosity of the mucin at the end of 30 min and 60 min time points (p < 0.001) compared to the saline control. BromAc® showed complete dissolution of the respiratory mucus simulant and improved ventilatory airflow parameters in the ex vivo ovine model.
Challenging Voices: Listening to Australian Women Writers across Time to Understand the Dynamics Shaping Creative Expression for Women Writing Today
Authors: Kelada Odette
Published: September 2024

This article argues for the critical need to value the voices and creative work of contemporary women writers in Australia. Historically, women writing in Australia have endured erasure, dismissal, and suppression. I argue that there is still, in the modern period, a continued lack of awareness, recognition and education on Australian women’s writing despite targeted awards and the achievements of the feminist movement. This piece reflects back across time, drawing on interviews I conducted and PhD thesis research with women writers in Australia at the turn of the twenty-first century, and maps how the legacies of gendered notions of writers impacted women at this pivotal era to consider what this may mean for women writing today. It also explores how feminist theories such as écriture féminine are helpful for framing and understanding the responses of Australian women writers to the shifting notions of sexual difference and agency in writing. This article aims to provide insights into the complexities of liberation for women from the past to modern times, and the impact of gender on creative expression in Australia across changing social periods.
In Vitro Drug Delivery through the Blood–Brain Barrier Using Cold Atmospheric Plasma
Authors: Alam Md Jahangir , Sadiq Abubakar Hamza , Kristof Jaroslav , Rimi Sadia Afrin , Hasan Mahedi , Tomoki Yamano , Shimizu Kazuo
Published: September 2024

This study explores the potential of cold atmospheric plasma (CAP) to facilitate the delivery of large-molecule drugs to the brain. The blood–brain barrier (BBB) restricts the passage of most drugs, hindering treatment for neurological disorders. CAP generates reactive oxygen and nitrogen species (RONS) that may disrupt the BBB’s tight junctions, potentially increasing drug permeability. An in vitro BBB model and an immortalized cell line (bEND.3) were used in this experiment. Fluorescein isothiocyanate dextran (FD-4), a model drug, was added to the cells to determine drug permeability. Custom microplasma was used to produce reactive oxygen species (ROS). Trans-endothelial electrical resistance (TEER) measurements assessed the integrity of the BBB after the CAP treatment. A decrease in TEER was observed in the CAP-treated group compared to the controls, suggesting increased permeability. Additionally, fluorescence intensity measurements from the basal side of the trans-well plate indicated higher drug passage in the CAP-treated group. Moreover, the higher presence of ROS in the plasma-treated cells confirmed the potential of CAP in drug delivery. These findings suggest that CAP may be a promising approach for enhancing brain drug delivery.
Bayesian Methods for Step-Stress Accelerated Test under Gamma Distribution with a Useful Reparametrization and an Industrial Data Application
Authors: Bakouch Hassan S. , Moala Fernando A. , Alghamdi Shuhrah , Albalawi Olayan
Published: September 2024

This paper presents a multiple step-stress accelerated life test using type II censoring. Assuming that the lifetimes of the test item follow the gamma distribution, the maximum likelihood estimation and Bayesian approaches are used to estimate the distribution parameters. In the Bayesian approach, new parametrizations can lead to new prior distributions and can be a useful technique to improve the efficiency and effectiveness of Bayesian modeling, particularly when dealing with complex or high-dimensional models. Therefore, in this paper, we present two sets of prior distributions for the parameters of the accelerated test where one of them is based on the reparametrization of the other. The performance of the proposed prior distributions and maximum likelihood approach are investigated and compared by examining the summaries and frequentist coverage probabilities of intervals. We introduce the Markov Chain Monte Carlo (MCMC) algorithms to generate samples from the posterior distributions in order to evaluate the estimators and intervals. Numerical simulations are conducted to examine the approach’s performance and one-sample lifetime data are presented to illustrate the proposed methodology.
Reply to Birch et al. Comment on “Takakura et al. Acupuncture for Japanese Katakori (Chronic Neck Pain): A Randomized Placebo-Controlled Double-Blind Study. Medicina 2023, 59, 2141”
Authors: Takakura Nobuari , Takayama Miho , Kaptchuk Ted J. , Kong Jian , Yajima Hiroyoshi
Published: September 2024

We are writing in response to the comment [...]
Current Challenges in Coronary Bifurcation Interventions
Authors: Panayotov Panayot , Mileva Niya , Vassilev Dobrin
Published: September 2024

Coronary bifurcation lesions account for a significant proportion of all percutaneous coronary interventions (PCIs). Interventional treatment of coronary bifurcations is related to significant technical challenges, high complication rates, and worse angiographic and long-term clinical outcomes. This review covers the specific features and structure of coronary bifurcation and explores the main challenges in the interventional treatment of these lesions. This review evaluates various methodologies designed to address these lesions, considering factors such as plaque distribution and bifurcation geometry. It also emphasizes the limitations associated with current techniques. A novel combined optimization approach applied in the interventional treatment of coronary bifurcation may offer superior procedural and long-term outcomes. This combined technique could potentially address the drawbacks of each method, providing a more effective solution for optimizing stent placement in bifurcation lesions. Refining and evaluating these combined techniques is essential for improving clinical outcomes in patients with bifurcation lesions.
Intraocular Pressure-Lowering Effect of Intraocular Lens Refixation in Patients with Elevated Intraocular Pressure Due to Intraocular Lens Subluxation
Authors: Iwasaki Kentaro , Komori Ryohei , Arimura Shogo , Takamura Yoshihiro , Inatani Masaru
Published: September 2024

Background and Objectives: To evaluate the surgical outcomes of intraocular lens (IOL) refixation with vitrectomy in patients with elevated intraocular pressure (IOP) due to IOL subluxation. Materials and Methods: Patients with elevated IOP due to IOL subluxation who had undergone IOL refixation with vitrectomy between 1 June 2013 and 31 December 2023 were retrospectively evaluated. The primary outcome measure was surgical success or failure. Surgical success was defined as a reduction of ≥20% in the preoperative IOP or IOP ≤ 21 mmHg (criterion A), IOP ≤ 18 mmHg (criterion B), or IOP ≤ 15 mmHg (criterion C). Reoperation, loss of light perception, and hypotony were considered as surgical failure. The IOP, number of glaucoma medications used, postoperative complications, and visual acuity were evaluated as the secondary outcomes. The surgical outcomes were compared between the glaucoma and ocular hypertension (OH) groups. Results: At 12 months postoperatively, the probability of success was 72.5%, 54.1%, and 28.4% using criterion A, B, and C, respectively, and the mean IOP and mean number of glaucoma medications used had decreased significantly (p < 0.01 and p = 0.03, respectively). Furthermore, the cumulative success rate was significantly higher in the OH group than in the glaucoma (100% vs. 47.4%; p < 0.01) when using criterion A. Additional glaucoma surgery was required only in the glaucoma group. Conclusions: IOL refixation surgery significantly decreases the IOP and number of glaucoma medications required in patients with elevated IOP due to IOL subluxation. Thus, IOL refixation surgery alone without glaucoma surgery might be effective as the primary procedure in such patients.
Clinical Presentations and Outcomes of Pediatric Rhegmatogenous Retinal Detachment: 11 Years’ Experience at a Tertiary Eye Center
Authors: Alabbasi Omar , Magliyah Moustafa S. , Albalawi Hani Basher , Alsharif Heba M. , Alsharif Eman M. , Abu El-Asrar Ahmed
Published: September 2024

Background and Objectives: Pediatric rhegmatogenous retinal detachment (RRD) represents a challenge for ophthalmologists and vitreoretinal surgeons. In this study, we aim to review the clinical features, and surgical and visual outcomes of pediatric RRD in a tertiary referral center. Materials and Methods: This is a retrospective study using the review of charts for all patients who presented to King Abdul-Aziz University Hospital, Riyadh, Saudi Arabia, from 2005 to 2016. This study included patients 18 years old or younger, had undergone surgical repairs for RRD, and were followed up for 1 year or more. Results: Eighty-nine eyes of 70 children who underwent surgical repair for RRD were included in the current retrospective study. A previous history of intraocular surgeries was present in 31.5%. The majority of cases had known ocular disease or syndromes (n = 58, 65.2%). The majority of eyes which had a primary surgical intervention achieved anatomical success (n = 88). Corneal complications accounted for the majority of complications following primary and secondary surgical interventions. Forty-two percent of the eyes had vision better than 20/200, while thirty-five percent had vision of hand motion or worse. Conclusions: In conclusion, despite the variability in causes of RRD in children, successful anatomical outcomes can be achieved with the proper surgical approach. Visual outcomes are less predictable due to other ocular complications.
All-Polyethylene Tibial Component in Unicompartmental Knee Arthroplasty Offers Excellent Survivorship and Clinical Outcomes at Short-Term Follow-Up: A Multicenter Retrospective Clinical Study
Authors: Bonanzinga Tommaso , Adravanti Federico Maria , Vitale Umberto , Anzillotti Giuseppe , Iacono Francesco , Marcacci Maurilio
Published: September 2024

Background and Objectives: The ten-year survivorship of unicompartmental knee arthroplasty (UKA) is up to 96%, varying from implants and hospitals; however, most of registry studies do not distinguish between metal-back (MB) tibial implants and all-polyethylene (AP) tibial implants. The aim of the present retrospective clinical study was to analyze the clinical outcomes and survivorship of medial and lateral UKA with a newly designed all-polyethylene tibial plateau at short-term follow-up. Materials and Methods: A retrospective analysis of prospectively collected consecutive patients who underwent medial or lateral UKA with AP tibial plateau was conducted, with a minimum follow-up of 1 year. Primary outcomes were clinical score (VAS, OKS, and KOOS) variations from baseline up to the latest follow-up. Secondary outcomes were Likert scale variations from baseline to the follow-up, evaluation of the influence of demographic factors (age and BMI) at the time of surgery on the clinical outcomes, and evaluation of revision rate up to the last follow-up. Results: The final study population included 99 knees. The mean VAS score for the medial group significantly decreased from 7.61 ± 1.65 (pre-intervention) to 2.74 ± 2.26 (post-intervention). Similar improvements were registered for the OKS as well, for both the medial group (from 22.5 ± 12.6 to 36.6 ± 10.6, with a delta of 14.11 (10.05 to 18.17)) and the lateral group (from 22.6 ± 12.6 to 36.9 ± 11.8, with a delta of 14.24 (8.65 to 19.83)). Moreover, all the KOOS subscales reported an amelioration, both in medial UKA and lateral UKA. Furthermore, a logistic regression of delta VAS was performed in relation to the other clinical questionnaires and the demographic factors. For both medial and lateral UKAs, no statistically significant correlation was found between the VAS scale regression and the demographic factors. The survival rate free from any revision of the cohort at the latest follow-up was 96.32%. Conclusions: All-polyethylene tibial component in unicompartmental knee arthroplasty demonstrates significant improvements in clinical scores and a low failure rate at short-term follow-up.
Effect of Heat Treatment on the Microstructure and Corrosion Resistance of Al0.75CoCr1.25FeNi High-Entropy Alloys
Authors: Han Jianyang , Zhang Huan , Yuan Hongtao , Zhuo Xiaoru , Cai Xiang , Qiao Yanxin
Published: September 2024

In this work, heat treatment of three different temperatures (600 °C, 800 °C, and 1000 °C) was applied to as-cast Al0.75CoCr1.25FeNi high-entropy alloys (HEAs) to investigate the influence of heat treatment on their corrosion properties. Open circuit potential (OCP) and cyclic polarization tests reveal that the 1000 °C heat-treated HEA possesses excellent corrosion resistance, as indicated by the low corrosion tendency and corrosion current density. Electrochemical impedance spectroscopy (EIS) and potentiostatic polarization analyses imply the presence of a superior passive film on the 1000 °C heat-treated HEA. X-ray photoelectron spectroscopy (XPS) analysis demonstrates that the passive film formed on the 1000 °C heat-treated HEA during potentiostatic polarization tests is most corrosion-resistant since it possesses the highest ratio of Al2O3/Al(OH)3 and Cr2O3/Cr(OH)3.
Investigation on the Solidification Structure of Q355 in 475 mm Extra-Thick Slabs Adopting Cellular Automaton-Finite Element Model
Authors: Yu Kezai , Wang Minglin , Fan Haihan , Zhan Zhonghua , Ren Zixiang , Xu Lijun
Published: September 2024

The solidification structure characteristics are decisive for the production of extra-thick slabs. This study developed a solidification heat transfer model and a cellular automaton–finite element coupled model to investigate the solidification behavior and structure characteristics of a 475 mm extra-thick slab. The models were applied under various continuous casting process parameters and different alloy element content. The simulation results reveal that casting speed has the most significant effect on the solidification behavior of extra-thick slabs, surpassing the impact of specific water flow and superheat. The solidification structure characteristics of the 475 mm extra-thick slabs were investigated under various conditions. The findings indicate that at higher casting speeds and superheats, the average grain size increases and the grain number decreases. The average grain size initially decreases and then increases with the rise in specific water flow, reaching its minimum at approximately 0.17 L·kg−1. Additionally, the average grain radius first decreases and then slightly increases with an increase in carbon content, achieving the minimum value of about 0.17% carbon. Compared with carbon and manganese, silicon has a greater impact on the solidification structure of ultra-thick slabs, and a moderate increase in silicon content can effectively refine the grain size. This study provides a theoretical foundation for understanding the changes in solidification structure characteristics and optimizing continuous casting process parameters for 475 mm extra-thick slabs.
Advances in 3D Bioprinting for Neuroregeneration: A Literature Review of Methods, Bioinks, and Applications
Authors: Islam Abrar , Vakitbilir Nuray , Almeida Nátaly , França Rodrigo
Published: September 2024

Recent advancements in 3D-bioprinting technology have sparked a growing interest in its application for brain repair, encompassing tissue regeneration, drug delivery, and disease modeling. This literature review examines studies conducted over the past five years to assess the current state of research in this field. Common bioprinting methods and key parameters influencing their selection are explored, alongside an analysis of the diverse types of bioink utilized and their associated parameters. The extrusion-based 3D-bioprinting method emerged as the most widely studied and popular topic, followed by inkjet-based and laser-based bioprinting and stereolithography. Regarding bioinks, fibrin-based and collagen-based bioinks are predominantly utilized. Furthermore, this review elucidates how 3D bioprinting holds promise for neural tissue repair, regeneration, and drug screening, detailing the steps involved and various approaches employed. Neurovascular 3D printing and bioscaffold 3D printing stand out as the top two preferred methods for brain repair. The recent studies’ shortcomings and potential solutions to address them are also examined and discussed. Overall, by synthesizing recent findings, this review provides valuable insights into the potential of 3D bioprinting for advancing brain repairment strategies.
Synthesis and Kinetics of CO2-Responsive Gemini Surfactants
Authors: Li Yao , Tang Xinyu , Yang Pujiang , Zhang Yuhui , Liu Jinhe
Published: September 2024

Surfactants are hailed as “industrial monosodium glutamate”, and are widely used as emulsifiers, demulsifiers, water treatment agents, etc., in the petroleum industry. However, due to the unidirectivity of conventional surfactants, the difficulty in demulsifying petroleum emulsions generated after emulsification with such surfactants increases sharply. Therefore, it is of great significance and application value to design and develop a novel switchable surfactant for oil exploitation. In this study, a CO2-switchable Gemini surfactant of N,N′-dimethyl-N,N′-didodecyl butylene diamine (DMDBA) was synthesized from 1, 4-dibromobutane, dodecylamine, formic acid, and formaldehyde. Then, the synthesized surfactant was structurally characterized by infrared (IR) spectroscopy, hydrogen nuclear magnetic resonance (1H NMR) spectroscopy, and electrospray ionization mass spectrometry (ESI-MS); the changes in conductivity and Zeta potential of DMDBA before and after CO2/N2 injection were also studied. The results show that DMDBA had a good CO2 response and cycle reversibility. The critical micelle concentration (CMC) of cationic surfactant obtained from DMDBA by injecting CO2 was 1.45 × 10−4 mol/L, the surface tension at CMC was 33.4 mN·m−1, and the contact angle with paraffin was less than 90°, indicating that it had a good surface activity and wettability. In addition, the kinetic law of the process of producing surfactant by injecting CO2 was studied, and it was found that the process was a second-order reaction. The influence of temperature and gas velocity on the reaction dynamics was explored. The calculated values from the equation were in good agreement with the measured values, with a correlation coefficient greater than 0.9950. The activation energy measured during the formation of surfactant was Ea = 91.16 kJ/mol.
Trade-Off between Degradation Efficiency and Recyclability: Zeolite-Enhanced Ni3−xCoxS4 Catalyst for Photocatalytic Degradation of Methylene Blue
Authors: Lagunay Rachel Anne E. , Adalim Ritche Roi B. , Tleubekova Aruzhan , Suleimenova Diana , Fernandez Marvin Jose F. , O’Reilly Robert J. , Balanay Mannix P.
Published: September 2024

We herein report successful syntheses of both nickel cobalt sulfide (NCS) and its composite with zeolite (NCS@Z) using a solvothermal method. Techniques such as EDX analysis, SEM, and molar ratio determination were used for product characterization. The incorporation of NCS significantly changed the surface roughness and active sites of the zeolite, improving the efficiency of methylene blue degradation and its reusability, especially under UV irradiation. In comparing the pseudo-first order rates, the highest degradation efficiency of methylene blue was achieved with NCS-2@Z, having a degradation extent of 91.07% under UV irradiation. This environmentally friendly approach offers a promising solution for the remediation of methylene blue contamination in various industries.
Cashew Nut Shell Waste Derived Graphene Oxide
Authors: Arrieta Alvaro , Nuñez de la Rosa Yamid E. , Pestana Samuel
Published: September 2024

The particular properties of graphene oxide (GO) make it a material with great technological potential, so it is of great interest to find renewable and eco-friendly sources to satisfy its future demand sustainably. Recently, agricultural waste has been identified as a potential raw material source for producing carbonaceous materials. This study explores the potential of cashew nut shell (CNS), a typically discarded by-product, as a renewable source for graphene oxide synthesis. Initially, deoiled cashew nut shells (DCNS) were submitted to pyrolysis to produce a carbonaceous material (Py-DCNS), with process optimization conducted through response surface methodology. Optimal conditions were identified as a pyrolysis temperature of 950 °C and a time of 1.8 h, yielding 29.09% Py-DCNS with an estimated purity of 82.55%, which increased to 91.9% post-washing. Using a modified Hummers method, the Py-DCNS was subsequently transformed into graphene oxide (GO-DCNS). Structural and functional analyses were carried out using FTIR spectroscopy, revealing the successful generation of GO-DCNS with characteristic oxygen-containing functional groups. Raman spectroscopy confirmed the formation of defects and layer separations in GO-DCNS compared to Py-DCNS, indicative of effective oxidation. The thermogravimetric analysis demonstrated distinct thermal decomposition stages for GO-DCNS, aligning with the expected behavior for graphene oxide. Scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX) further corroborated the morphological and compositional transformation from DCNS to GO-DCNS, showcasing reduced particle size, increased porosity, and significant oxygen functional groups. The results underscore the viability of cashew nut shells as a sustainable precursor for graphene oxide production, offering an environmentally friendly alternative to conventional methods. This innovative approach addresses the waste management issue associated with cashew nut shells and contributes to developing high-value carbon materials with broad technological applications.
Extraction of Pyrrole from Its Mixture with n-Hexadecane Using Protic Ionic Liquids
Authors: Amran Sorfina , Mat Salleh Muhammad Zulhaziman , Hizaddin Hanee Farzana , Indera Luthfi Abdullah Amru , Md Saleh Noorashikin , Hadj-Kali Mohamed Kamel
Published: September 2024

The removal of nitrogen compounds from fuel via the conventional method, which is hydrodenitrogenation, is costly and involves catalysts and energy-intensive conditions (600 K and 300 atm). Recently, ionic liquids (ILs) have emerged as a promising alternative solvent for the denitrogenation of fuel oil. However, certain ILs are expensive and challenging to synthesize, prompting the exploration of protic ionic liquid (PIL) substitutes, which offer similar advantages to ILs. This study utilized the conductor-like screening model for real solvents (COSMO-RS) to predict the phase equilibria for three PILs—triethylammonium p-toluenesulfonate (TEA-TSA), triethylammonium salicylate (TEA-SA) and triethylammonium benzoate (TEA-BZ)—which were subsequently validated through experimental investigations. Liquid–liquid extraction experiments were conducted at 298 K and 1 atm, with pyrrole (serving as the model nitrogen compound) concentrations in n-hexadecane (representing the model fuel) ranging from 10 to 50 wt%. Additionally, the NRTL model effectively correlated the experimental tie lines. The obtained data indicated that TEA-TSA exhibited superior selectivity and distribution ratio compared to TEA-SA and TEA-BZ. All the ternary systems tested displayed positive slopes, suggesting a higher affinity of nitrogen compounds for the PIL. Supporting this observation, interaction energy (ΔE) and excess enthalpy (HE) were employed. The predicted outcomes revealed that TEA-TSA had high ΔE, and all PILs exhibited negative values of HE. The HE calculation underscored the significance of strong hydrogen bond interactions between pyrrole and the PIL for successful extraction.
Maximizing Upconversion Luminescence of Co-Doped CaF₂:Yb, Er Nanoparticles at Low Laser Power for Efficient Cellular Imaging
Authors: Dubey Neha , Gupta Sonali , Shelar Sandeep B. , Barick K. C. , Chandra Sudeshna
Published: September 2024

Upconversion nanoparticles (UCNPs) are well-reported for bioimaging. However, their applications are limited by low luminescence intensity. To enhance the intensity, often the UCNPs are coated with macromolecules or excited with high laser power, which is detrimental to their long-term biological applications. Herein, we report a novel approach to prepare co-doped CaF2:Yb3+ (20%), Er3+ with varying concentrations of Er (2%, 2.5%, 3%, and 5%) at ambient temperature with minimal surfactant and high-pressure homogenization. Strong luminescence and effective red emission of the UCNPs were seen even at low power and without functionalization. X-ray diffraction (XRD) of UCNPs revealed the formation of highly crystalline, single-phase cubic fluorite-type nanostructures, and transmission electron microscopy (TEM) showed co-doped UCNPs are of ~12 nm. The successful doping of Yb and Er was evident from TEM–energy dispersive X-ray analysis (TEM-EDAX) and X-ray photoelectron spectroscopy (XPS) studies. Photoluminescence studies of UCNPs revealed the effect of phonon coupling between host lattice (CaF2), sensitizer (Yb3+), and activator (Er3+). They exhibited tunable upconversion luminescence (UCL) under irradiation of near-infrared (NIR) light (980 nm) at low laser powers (0.28–0.7 W). The UCL properties increased until 3% doping of Er3+ ions, after which quenching of UCL was observed with higher Er3+ ion concentration, probably due to non-radiative energy transfer and cross-relaxation between Yb3+-Er3+ and Er3+-Er3+ ions. The decay studies aligned with the above observation and showed the dependence of UCL on Er3+ concentration. Further, the UCNPs exhibited strong red emission under irradiation of 980 nm light and retained their red luminescence upon internalization into cancer cell lines, as evident from confocal microscopic imaging. The present study demonstrated an effective approach to designing UCNPs with tunable luminescence properties and their capability for cellular imaging under low laser power.
VRChances: An Immersive Virtual Reality Experience to Support Teenagers in Their Career Decisions
Authors: Holly Michael , Weichselbraun Carina , Wohlmuth Florian , Glawogger Florian , Seiser Maria , Einwallner Philipp , Pirker Johanna
Published: September 2024

In this paper, we present a tool that offers young people virtual career guidance through an immersive virtual reality (VR) experience. While virtual environments provide an effective way to explore different experiences, VR offers users immersive interactions with simulated 3D environments. This allows the realistic exploration of different job fields in a virtual environment without being physically present. The study investigates the extent to which performing occupational tasks in a virtual environment influences the career perceptions of young adults and whether it enhances their understanding of professions. In particular, the study focuses on users’ expectations of an electrician’s profession. In total, 23 teenagers and eight application experts were involved to assess the teenager’s expectations and the potential of the career guidance tool.
Hip Muscle Strength Ratios Predicting Groin Injury in Male Soccer Players Using Machine Learning and Multivariate Analysis—A Prospective Cohort Study
Authors: Kekelekis Afxentios , Musa Rabiu Muazu , Nikolaidis Pantelis T. , Clemente Filipe Manuel , Kellis Eleftherios
Published: September 2024

Despite ongoing efforts, the relationship between groin strength and injury remains unclear. The challenge of accurately predicting injuries presents an opportunity for researchers to develop prevention strategies to reduce the occurrence of such injuries. Consequently, this issue requires further investigation to obtain insights into effective mitigation strategies. In 120 male soccer players, the maximum isometric strength of the hip muscle groups was measured, and the strength ratios were calculated. Previous injury and anthropometric data were registered. Injury data were collected following the FIFA/UEFA consensus. k-nearest neighbor (k-NN) was used to predict the incidence of injury, while the significant predictive variables of the k-NN algorithm were fitted into a multivariate logistic regression model (LR) to analyze the likelihood of players sustaining a groin injury. The LR model determined two variables as significant predictors of groin injury. Players were less likely to sustain a groin injury by 76% for each decrease of the adductor/abductor isometric strength ratio in the non-dominant limb (OR = 0.238, CI 95% = [(0.098–0.572]). Players with a history of previous injury had a 67% greater risk of sustaining an injury (OR = 0.333, CI 95% = [(0.1068–1.038]). Isometric hip adductor and abductor strength imbalances of the non-dominant lower limb and a history of previous injury were risk factors for groin injury in soccer players.
Improved UV Photoresponse Performance of ZnO Nanowire Array Photodetector via Effective Pt Nanoparticle Coupling
Authors: Wang Nan , Li Jianbo , Wang Chong , Zhang Xiaoqi , Ding Song , Guo Zexuan , Duan Yuhan , Jiang Dayong
Published: September 2024

Ultraviolet (UV) photodetectors (PDs) based on nanowire (NW) hold significant promise for applications in fire detection, optical communication, and environmental monitoring. As optoelectronic devices evolve towards lower dimensionality, multifunctionality, and integrability, multicolor PDs have become a research hotspot in optics and electronic information. This study investigates the enhancement of detection capability in a light-trapping ZnO NW array through modification with Pt nanoparticles (NPs) via magnetron sputtering and hydrothermal synthesis. The optimized PD exhibits superior performance, achieving a responsivity of 12.49 A/W, detectivity of 4.07 × 1012 Jones, and external quantum efficiency (EQE) of 4.19 × 103%, respectively. In addition, the Pt NPs/ZnO NW/ZnO PD maintains spectral selectivity in the UV region. These findings show the pivotal role of Pt NPs in enhancing photodetection performance through their strong light absorption and scattering properties. This improvement is associated with localized surface plasmon resonance induced by the Pt NPs, leading to enhanced incident light and interfacial charge separation for the specialized configurations of the nanodevice. Utilizing metal NPs for device modification represents a breakthrough that positively affects the preparation of high-performance ZnO-based UV PDs.
Exploring the Impact of Swimming on Body Mass Index and Body Fat in Individuals with Down Syndrome: A Meta-Analysis
Authors: Kuo Hou-Ting , Yang Ciao-Ci
Published: September 2024

The aim of this study is to assess the effectiveness of swimming training in reducing body mass index (BMI) and body fat percentage among individuals with Down syndrome (DS), utilizing a meta-analysis approach. We conducted a systematic search for studies examining the clinical impact of swimming training on individuals with DS. Inclusion criteria encompassed studies involving DS patients who underwent swimming training for a minimum duration of 4 weeks. The primary focus was to compare changes in BMI and body fat percentage from baseline to post-training. Our analysis incorporated four studies comprising a total of 48 participants. The results demonstrated that swimming training lasting from 8 to 36 weeks did not significantly decrease BMI among DS patients, with a weighted mean difference (WMD) post-training of −0.428 (95% confidence interval (CI): −1.721–0.865) and an I2 of 0%. Subgroup analysis based on age or duration (≥33 weeks or 8 weeks) also showed no notable decrease in BMI. Conversely, the analysis of body fat percentage demonstrated a significant decrease, with a WMD of −2.946 (95% CI: −5.056–−0.837). Subgroup analysis indicated a consistent reduction in body fat percentage across all duration groups. Swimming training does not lead to a significant reduction in BMI among individuals with DS. This outcome may be attributed to concurrent muscle gain alongside decreased body fat, resulting in a notable decrease in body fat percentage.
Heartworm (Dirofilaria immitis) Prevalence in Dogs Determined by In-House ELISA Based on Filaria-Specific Antibodies in Tropical and Temperate Regions of Mexico
Authors: Villa-Mancera Abel , Castillo-Barojas Miguel , Trejo-Campos Alma , Fernández-Meneses Erick , Robles-Robles Manuel , Olivares-Pérez Jaime , Olmedo-Juárez Agustín , Utrera-Quintana Fernando , González-Garduño Roberto , Pérez-Mendoza Noemi , Campos-García Huitziméngari , Ortega-Vargas Samuel
Published: September 2024

Dirofilaria immitis is a mosquito-borne nematode of dogs, other carnivores and, occasionally, humans. Globally, D. immitis infection (which causes heartworm) is typically more prevalent in tropical than temperate regions. In this study, the seroprevalence of D. immitis was determined from a sample of 335 non-stray dogs from four municipalities, two each from the states of Puebla and Guerrero in Mexico, using polyclonal antibodies to detect serum antigens using an enzyme-linked immunosorbent assay (ELISA). The accuracy of the assay was compared with the modified Knott’s test. The polyclonal antibody used in the direct ELISA had a high sensitivity (100%) with variable specificity (98.2–98.8%) in the municipalities of Puebla and Guerrero. The area under the curve for the four municipalities was 1.0, indicating a high accuracy test, with a cut-off value ranging from 0.45 to 0.50. The overall prevalence of D. immitis infection was 17.56% (59 out of 335). The highest prevalence was in Acapulco (24.78%), followed by Chilpancingo (20.93%), Tecamachalco (10.81%) and Quecholac (8.06%). The highest percentage of positive samples was detected in tropical regions (23.12%) and the lowest in temperate regions (9.56%). This study demonstrates that polyclonal anti-D. immitis antibodies can successfully diagnose heartworm-infected dogs and be used to monitor prevalence effectively and develop prevention strategies against Dirofilaria infection.
An Efficient Hybrid Method for Calculating the Focal Field of a Cassegrain Antenna
Authors: Lian Hongfei , Jiang Yanwen , Lu Dawei , Xiao Huaitie , Fan Hongqi
Published: September 2024

The evaluation of the focal field of Cassegrain antennas is crucial for the design and optimization of the complex feeds in quasi-optical systems. However, employing traditional physical optics methods generates high computational complexity and is inefficient. An accurate and efficient calculation method of Cassegrain antennas’ focal fields that involves a range of incidence angles is proposed, which integrates ray tracing and vector diffraction integration (RT-VDI) theories. It can calculate the focal field in any given or predefined incident direction, not limited to the case of axial incidence. In addition, the use of the equivalent parabolic theory greatly simplifies the process of integral calculation. Moreover, ray tracing and integration operations are executed upon the calculation of the reflector to further improve efficiency. Numerical examples are presented to demonstrate the accuracy and efficiency of the proposed method.
A Microwave Photonic Channelized Receiver Based on Polarization-Division Multiplexing of Optical Signals
Authors: Chen Bo , Wang Jingyi , Li Yankun , Tan Jiajun , Liang Changhui , Dong Qunfeng
Published: September 2024

Aimed at the problems of optical frequency combs, such as their large number of comb lines, their high flatness, and their lack of ease in generating, as well as the fact that the channelization efficiency of the scheme based on optical frequency combs is low, we proposed a microwave photonic channelization receiver based on signal polarization multiplexing. Using two-line local optical frequency combs with different frequencies to demodulate the RF signal in the orthogonal polarization state, 16 sub-channels with a bandwidth of 1 GHz can be received simultaneously. The experimental results show that the image rejection ratio can reach 28 dB, and the third-order spurious-free dynamic range of the system can reach 96.8 dB·Hz2∕3. This scheme has the advantages of a large number of sub-channels and a high channelization efficiency; it has great application potential in broadband wireless communication, radar, and electronic warfare systems.