bluuebunny/crossref_metadata_2025 huggingface dataset:
The Influence of Plasma Treatment on the Corrosion and Biocompatibility of Magnesium
Authors: Kocijan Aleksandra , Kovač Janez , Junkar Ita , Resnik Matic , Kononenko Veno , Conradi Marjetka
Published: October 2022

In our study, plasma surface modification was employed to tailor the surface properties of magnesium in terms of surface chemistry, topography, and wettability. For two sets of samples, the plasma treatment involved two steps using two different gases (hydrogen and oxygen), while one set of samples was treated with one step only using oxygen. X-ray photoelectron spectroscopy (XPS) was applied to determine the surface composition, oxidation state of the elements, and the thickness of the surface oxide layer on the Mg samples after different plasma treatments. The surface morphology was characterised using atomic force microscopy (AFM) and scanning electron microscopy (SEM). The wettability was analysed by measuring the static water-contact angles and the corrosion was evaluated using potentiodynamic measurements. The interaction of the live cells with the differently modified Mg surfaces was evaluated in terms of biocompatibility using MG-63 cells (human bone osteosarcoma cells). We have shown that a plasma surface treatment significantly decreased the carbon content and the formation of a 15–20-nm-thick MgO layer was observed. This improves the corrosion resistance, while the biocompatibility was retained, compared to the untreated Mg. A plasma surface treatment is therefore an important step in the development of novel surfaces with improved corrosion resistance for magnesium in biomedical applications.
Corrosion Behavior of Ti3SiC2 in Flowing Liquid Lead–Bismuth Eutectic at 500 °C
Authors: Lyu Liangliang , Qiu Xi , Yue Huifang , Zhou Mingyang , Zhu Huiping
Published: October 2022

MAX phases are promising candidate structural materials for lead-cooled fast reactors (LFRs) and accelerator-driven sub-critical systems (ADSs) due to their excellent corrosion resistance in liquid LBE. In this work, one of the typical MAX phases, Ti3SiC2, was exposed to the flowing LBE with a saturated oxygen concentration at 500 °C for up to 3000 h. The corrosion behaviors, including the evolution of the corrosion layer, mechanical properties and wettability, were evaluated via X-ray diffraction, a scanning electron microscope equipped with an energy-dispersive X-ray, a microhardness test and contact angle measurement. The results reveal that a corrosion structure with a duplex layer was formed on the sample surfaces. The outer layer was a diffusion layer, which always remained thin (<3 μm) during the whole test due to the erosion effect caused by the flowing LBE. The inner layer was the stable protective oxide layer, and its thickness increased with exposure time. The growth of the corrosion structure improved the microhardness and reduced the wettability with regard to LBE, which was beneficial to inhibiting further surface corrosion of Ti3SiC2.
Effect of Pre-Existing Micro-Defects on Cutting Force and Machined Surface Quality Involved in the Ball-End Milling Repairing of Flawed KDP Crystal Surfaces
Authors: Lei Hongqin , Cheng Jian , Yang Dinghuai , Zhao Linjie , Chen Mingjun , Wang Jinghe , Liu Qi , Ding Wenyu , Chen Guang
Published: October 2022

When serving in extremely high-power laser conditions, KH2PO4 (KDP) surfaces are susceptible to incur laser damage points (also known as defects). Using micro-ball end milling cutters to repair and remove the pre-existing damage points on the flawed KDP crystal surface is the most effective method to control the growth of laser damage points on KDP crystal surfaces and prolong their service life. However, there are various forms of micro-defects (such as pits, scratches and brittle fractures) around the laser damage points on KDP crystal surfaces which possess remarkable effects on the micro-milling repair process and consequently deteriorate the repair quality. In this work, combined with nano-indentation experiments, elastic–plastic mechanics and fracture mechanics theory, a constitutive model considering the anisotropic property of KDP crystals and a three-dimensional (3D) finite element model (FEM) were established to simulate the cutting force and surface topography involved in the ball-end milling repairing of flawed KDP crystal surfaces. Besides, the micro-milling experiments were conducted to evaluate the change of cutting force and machined surface quality in the presence of micro-defects with various feed rates. The results show that micro-defects would induce the fluctuation of cutting force and a change of the undeformed cutting thickness (UCT) in the process of repairing the damage points on the crystal surface, which would lead to the brittle–ductile transition (BDT) and affect the machined surface quality. The machined surface quality was found to be deteriorated by the pre-existing micro-defects when the UCT was small (the UCT was less than 375 nm). On the contrary, brittle mode cutting in the local area can be transformed into ductile mode cutting, resulting in an improvement of repaired surface quality that is exhibited by the cutting force and microtopography. This work has great theoretical significance and engineering practical value for the promotion and application of micro-milling repairing technology in the practical manufacturing and operation of KDP optics applied to high-power laser systems.
Influence of Sintering Parameters on Spectroscopic Properties of BMW: Eu3+ Ceramic Materials Prepared by HPLT Technique
Authors: Miniajluk-Gaweł Natalia , Tomala Robert , Bondzior Bartosz , Dereń Przemysław Jacek
Published: October 2022

In this work, Ba2MgWO6: Eu3+ (BMW: Eu3+) ceramic materials with a double perovskite structure were sintered using the High-Pressure Low-Temperature sintering (HPLT) technique. As part of the research, the influence of pressure (CP), sintering temperature (CT), and sintering time (CTS) on the structure and luminescence of the doped BMW were determined. Structural analysis via XRD and SEM + EDS and spectroscopic analysis via emission and excitation spectra, decay time, and absorption spectra of the obtained ceramics were performed. Dense double perovskite ceramics were obtained with a cubic structure with optimal sintering parameters: T = 500 °C, p = 8 GPa, and t = 1 min. The increase in temperature caused an increased extinction of the luminescence due to the diffusion of carbon into the ceramics. The increase in pressure led to the formation of the amorphous phase, which increased the speed of non-radiative transitions and also led to the extinction of the luminescence. The increase in sintering time from 1 to 3 min enhanced the luminescence output, but when the ceramic was sintered for 5 min, the luminescence was quenched, most likely by increasing the rate of the non-radiative process, as evidenced by reduced decay time.
An Experimental Analysis of the High-Cycle Fatigue Fracture of H13 Hot Forging Tool Steels
Authors: Calvo-García Erik , Valverde-Pérez Sara , Riveiro Antonio , Álvarez David , Román Manuel , Magdalena César , Badaoui Aida , Moreira Pedro , Comesaña Rafael
Published: October 2022

In this study, the axial fatigue behaviour of hot forging tool steels at room temperature was investigated. Fatigue tests were performed on two steels within the same H13 specification. The fatigue tests were carried out in the high-cycle fatigue domain under normal conditions. These tests were also performed on specimens in contact with a corrosive medium, applying stress values that led to the high-cycle fatigue domain under normal conditions for the sake of comparison. Both materials showed similar fatigue strengths when they were tested under normal conditions. In contrast, corrosion fatigue lives were much lower than in normal tests and differed significantly between the two steels. Crack initiation was triggered by microstructural and surface defects in the normal tests, whereas the formation of corrosion pits caused crack initiation in the corrosion fatigue tests. Moreover, a fracture surface analysis revealed dissimilar crack propagation areas between both steels, which suggested that both steels had different fracture toughness. These results were in line with the differences observed between the carbide and grain sizes of both of the material microstructures.
Prediction of Autogenous Shrinkage of Concrete Incorporating Super Absorbent Polymer and Waste Materials through Individual and Ensemble Machine Learning Approaches
Authors: Qureshi Hisham Jahangir , Saleem Muhammad Umair , Javed Muhammad Faisal , Al Fuhaid Abdulrahman Fahad , Ahmad Jawad , Amin Muhammad Nasir , Khan Kaffayatullah , Aslam Fahid , Arifuzzaman Md
Published: October 2022

The use of superabsorbent polymers, sometimes known as SAP, is a tremendously efficacious method for reducing the amount of autogenous shrinkage (AS) that occurs in high-performance concrete. This study utilizes support vector regression (SVR) as a standalone machine-learning algorithm (MLA) which is then ensemble with boosting and bagging approaches to reduce the bias and overfitting issues. In addition, these ensemble methods are optimized with twenty sub-models with varying the nth estimators to achieve a robust R2. Moreover, modified bagging as random forest regression (RFR) is also employed to predict the AS of concrete containing supplementary cementitious materials (SCMs) and SAP. The data for modeling of AS includes water to cement ratio (W/C), water to binder ratio (W/B), cement, silica fume, fly ash, slag, the filer, metakaolin, super absorbent polymer, superplasticizer, super absorbent polymer size, curing time, and super absorbent polymer water intake. Statistical and k-fold validation is used to verify the validation of the data using MAE and RMSE. Furthermore, SHAPLEY analysis is performed on the variables to show the influential parameters. The SVM with AdaBoost and modified bagging (RF) illustrates strong models by delivering R2 of approximately 0.95 and 0.98, respectively, as compared to individual SVR models. An enhancement of 67% and 63% in the RF model, while in the case of SVR with AdaBoost, it was 47% and 36%, in RMSE and MAE of both models, respectively, when compared with the standalone SVR model. Thus, the impact of a strong learner can upsurge the efficiency of the model.
Surface Morphology and Spectroscopic Features of Homoepitaxial Diamond Films Prepared by MWPACVD at High CH4 Concentrations
Authors: Sierra Gómez Javier , Vieira José , Fraga Mariana Amorim , Corat Evaldo Jose , Trava-Airoldi Vladimir Jesus
Published: October 2022

Single crystal diamond (SCD) is a promising material to satisfy emerging requirements of high-demand fields, such as microelectronics, beta batteries and wide-spectrum optical communication systems, due to its excellent optical characteristics, elevated breakdown voltage, high hardness and superior thermal conductivity. For such applications, it is essential to study the optically active defects in as-grown diamonds, namely three-dimensional defects (such as stacking faults and dislocations) and the inherent defects arising from the cultivation method. This paper reports the growth of SCD films on a commercial HPHT single-crystal diamond seed substrate using a 2.45 GHz microwave plasma-assisted chemical vapor deposition (MWPACVD) technique by varying the methane (CH4) gas concentration from 6 to 12%, keeping the other parameters constant. The influence of the CH4 concentration on the properties, such as structural quality, morphology and thickness, of the highly oriented SCD films in the crystalline plane (004) was investigated and compared with those on the diamond substrate surface. The SCD film thickness is dependent on the CH4 concentration, and a high growth rate of up to 27 µm/h can be reached. Raman spectroscopy, high-resolution X-ray diffractometry (HRXRD), scanning electron microscopy (SEM), surface profilometry and optical microscopic analyses showed that the produced homoepitaxial SCD films are of good quality with few macroscopic defects.
Plasmon-Induced Enhanced Light Emission and Ultrafast Carrier Dynamics in a Tunable Molybdenum Disulfide-Gallium Nitride Heterostructure
Authors: Poudel Yuba , Seetharaman Sairaman , Kar Swastik , D’Souza Francis , Neogi Arup
Published: October 2022

The effect of localized plasmon on the photoemission and absorption in hybrid molybdenum disulfide-Gallium nitride (MoS2-GaN) heterostructure has been studied. Localized plasmon induced by platinum nanoparticles was resonantly coupled to the bandedge states of GaN to enhance the UV emission from the hybrid semiconductor system. The presence of the platinum nanoparticles also increases the effective absorption and the transient gain of the excitonic absorption in MoS2. Localized plasmons were also resonantly coupled to the defect states of GaN and the exciton states using gold nanoparticles. The transfer of hot carriers from Au plasmons to the conduction band of MoS2 and the trapping of excited carriers in MoS2 within GaN defects results in transient plasmon-induced transparency at ~1.28 ps. Selective optical excitation of the specific resonances in the presence of the localized plasmons can be used to tune the absorption or emission properties of this layered 2D-3D semiconductor material system.
Antiferromagnet–Ferromagnet Transition in Fe1−xCuxNbO4
Authors: Evaristo Diego S. , Jucá Raí F. , Soares João M. , Silva Rodolfo B. , Saraiva Gilberto D. , Matos Robert S. , Ferreira Nilson S. , Salerno Marco , Macêdo Marcelo A.
Published: October 2022

Iron niobates, pure and substituted with copper (Fe1−xCuxNbO4 with x = 0–0.15), were prepared by the solid-state method and characterized by X-ray diffraction, Raman spectroscopy, and magnetic measurements. The results of the structural characterizations revealed the high solubility of Cu ions in the structure and better structural stability compared to the pure sample. The analysis of the magnetic properties showed that the antiferromagnetic–ferromagnetic transition was caused by the insertion of Cu2+ ions into the FeNbO4 structure. The pure FeNbO4 structure presented an antiferromagnetic ordering state, with a Néel temperature of approximately 36.81K. The increase in substitution promoted a change in the magnetic ordering, with the state passing to a weak ferromagnetic order with a transition temperature (Tc) higher than the ambient temperature. The origin of the ferromagnetic ordering could be attributed to the increase in super-exchange interactions between Fe/Cu ions in the Cu2+-O-Fe3+ chains and the formation of bound magnetic polarons in the oxygen vacancies.
Catalytic Hydrogen Evolution from H2S Cracking over CrxZnS Catalyst in a Cylindrical Single-Layered Dielectric Barrier Discharge Plasma Reactor
Authors: Afzal Saba , Hussain Humaira , Naz Muhammad Yasin , Shukrullah Shazia , Ahmad Irshad , Irfan Muhammad , Mursal Salim Nasar Faraj , Legutko Stanislaw , Kruszelnicka Izabela , Ginter-Kramarczyk Dobrochna
Published: October 2022

The use of non-thermal plasma technology in producing green fuels is a much-appreciated environmentally friendly approach. In this study, an Al2O3-supported CrxZnS semiconductor catalyst was tested for hydrogen evolution from hydrogen sulfide (H2S) gas by using a single-layered dielectric barrier discharge (DBD) system. The Al2O3-supported CrxZnS catalyst (x = 0.20, 0.25, and 0.30) was produced by using a co-impregnation method and characterized for its structural and photocatalytic characteristics. The discharge column of the DBD system was filled with this catalyst and fed with hydrogen sulfide and argon gas. The DBD plasma was sustained with a fixed AC source of 10 kV where plasma produced species and UV radiations activated the catalyst to break H2S molecules under ambient conditions. The catalyst (hexagonal-cubic-sphalerite structure) showed an inverse relationship between the band gap and the dopant concentration. The hydrogen evolution decreased with an increase in dopant concentration in the nanocomposite. The Cr0.20ZnS catalyst showed excellent photocatalytic activity under the DBD exposure by delivering 100% conversion efficiency of H2S into hydrogen. The conversion decreased to 96% and 90% in case of Cr0.25ZnS and Cr0.30ZnS, respectively.
Adsorption and Surface Analysis of Sodium Phosphate Corrosion Inhibitor on Carbon Steel in Simulated Concrete Pore Solution
Authors: Mohamed Ahmed , Martin Ulises , Bastidas David M.
Published: October 2022

Corrosion of steel-reinforced concrete exposed to marine environments could lead to structural catastrophic failure in service. Hence, the construction industry is seeking novel corrosion preventive methods that are effective, cheap, and non-toxic. In this regard, the inhibitive properties of sodium phosphate (Na3PO4) corrosion inhibitor have been investigated for carbon steel reinforcements in 0.6 M Cl− contaminated simulated concrete pore solution (SCPS). Different electrochemical testing has been utilized including potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and Mott-Schottky plots to test Na3PO4 at different concentrations: 0.05, 0.1, 0.3, and 0.6 M. It was found that Na3PO4 adsorbs on the surface through a combined physicochemical adsorption process, thus creating insoluble protective ferric phosphate film (FePO4) and achieving an inhibition efficiency (IE) up to 91.7%. The formation of FePO4 was elucidated by means of Fourier-transform infrared spectroscopy (FT–IR) and X-ray photoelectron spectroscopy (XPS). Quantum chemical parameters using density functional theory (DFT) were obtained to further understand the chemical interactions at the interface. It was found that PO43− ions have a low energy gap (ΔEgap), hence facilitating their adsorption. Additionally, Mulliken population analysis showed that the oxygen atoms present in PO43− are strong nucleophiles, thus acting as adsorption sites.
Experimental Research and Optimization of Ti-6Al-4V Alloy Microgroove Machining Based on Waterjet-Guided High-Power Laser
Authors: Liu Qian , Zhao Yugang , Meng Jianbing , Zheng Zhilong , Cao Chen , Zhao Guoyong , Zhao Chuang , Liu Guangxin , Dai Di , Song Zhuang
Published: October 2022

In order to improve the tribological properties of Ti-6Al-4V alloy and further broaden the application scope of titanium alloy materials in the industrial field, a preparation method of a waterjet-guided high-power laser processing surface microgroove was studied. In this paper, a multifocus coupling lens was innovatively designed to replace the spherical lens in the traditional waterjet-guided laser coupling device, which avoids the gas explosion phenomenon in the coupling of the high-power laser and waterjet, and realizes the high-quality coupling of the high-power laser and water beam fiber. Then, with the microgroove morphology as the response target, the single-factor test and response surface test of the water-guided laser processing microgroove were carried out. Based on the experimental results, an approximate mathematical model of the response surface between the process parameters and the microgroove topography target was constructed, and the quantitative relationship between the waterjet-guided laser processing parameters and the target response was studied. At the same time, the optimal combination of process parameters was obtained by multiobjective optimization, so as to effectively improve the microgroove morphology. This technology provides method guidance and a decision-making reference for subsequent waterjet-guided laser processing of titanium alloy surface functional microstructures.
Prediction of Ecofriendly Concrete Compressive Strength Using Gradient Boosting Regression Tree Combined with GridSearchCV Hyperparameter-Optimization Techniques
Authors: Alhakeem Zaineb M. , Jebur Yasir Mohammed , Henedy Sadiq N. , Imran Hamza , Bernardo Luís F. A. , Hussein Hussein M.
Published: October 2022

A crucial factor in the efficient design of concrete sustainable buildings is the compressive strength (Cs) of eco-friendly concrete. In this work, a hybrid model of Gradient Boosting Regression Tree (GBRT) with grid search cross-validation (GridSearchCV) optimization technique was used to predict the compressive strength, which allowed us to increase the precision of the prediction models. In addition, to build the proposed models, 164 experiments on eco-friendly concrete compressive strength were gathered for previous researches. The dataset included the water/binder ratio (W/B), curing time (age), the recycled aggregate percentage from the total aggregate in the mixture (RA%), ground granulated blast-furnace slag (GGBFS) material percentage from the total binder used in the mixture (GGBFS%), and superplasticizer (kg). The root mean square error (RMSE) and coefficient of determination (R2) between the observed and forecast strengths were used to evaluate the accuracy of the predictive models. The obtained results indicated that—when compared to the default GBRT model—the GridSearchCV approach can capture more hyperparameters for the GBRT prediction model. Furthermore, the robustness and generalization of the GSC-GBRT model produced notable results, with RMSE and R2 values (for the testing phase) of 2.3214 and 0.9612, respectively. The outcomes proved that the suggested GSC-GBRT model is advantageous. Additionally, the significance and contribution of the input factors that affect the compressive strength were explained using the Shapley additive explanation (SHAP) approach.
Change in Selected Mechanical Properties of Beech Wood at the Contact Drying
Authors: Klement Ivan , Vilkovský Peter , Vilkovská Tatiana
Published: October 2022

The mechanical properties of wood have remarkable influence on its use in buildings. The improvement of the mechanical properties enables the reduction in the cross-sections of structural elements, particularly the increase in their load. The paper deals with the change in the mechanical properties of beech wood through the process of contact drying. Plate pressures of 1.0, 1.4, and 1.6 MPa at a temperature of 160 °C were used. It was found that contact drying increased the bending strength by more than 30% compared to convection drying. The value of Brinell’s hardness measured on the surface of the samples increased by 80 to 98% after contact drying, and the measured values of impact toughness were higher, about 31.1% compared to the samples dried by the convection drying method. As a result of contact drying, the density in the absolutely dry state increased for radial samples by 102.3 kg·m−3 and for tangential samples by 83.1 kg·m−3. The pressure of the plates also had an effect on the change in density.
Diagnostics of the RC Roofing Structure of the 100-Year-Old Municipal Theatre Facility
Authors: Kosior-Kazberuk Marta , Krentowski Janusz Ryszard , Wardach Maciej
Published: October 2022

Reinforced concrete has been a widely used material for the construction of buildings for many decades. However, with the passage of time, the material characteristics and connection of structural elements gradually degrade. Development in measurement technology makes it possible to efficiently obtain data on the current state of the structure and material characteristics using non-destructive methods, with limited or no destructive testing. The paper presents the analysis of the condition of the reinforced concrete roof of a 100-year-old theatre building in terms of its further use after planned modernisation. The tests carried out in situ as well as the computational analysis of structure are described. Based on the test results, the current load-bearing capacity was assessed and the limit state conditions were checked. Limitations on the accuracy of the non-destructive test results in relation to the destructive test results were formulated. Options for the strengthening reinforced concrete beams with regard to structural and technological considerations were analysed.
Effect of Pre-Oxidation on High-Temperature Oxidation Behavior of Al-Si Coating on Nickel-Based Superalloy
Authors: Li Yanmei , Lv Haishuang , Li Yabin , Fan Naiwen
Published: October 2022

Under the condition of long-time high-temperature oxidation, oxidation in Al-Si coating will lead to degradation of the coating. To solve this problem, the Al-Si coating was treated before the oxidation experiment at different pre-oxidation temperatures and times. The structure, morphology and element distribution of the oxide film were characterized by XRD, SEM and EPMA, and the oxidation kinetics curves were drawn. The results show that the oxidation resistance of the pre-oxidized samples is improved in the process of constant temperature oxidation at 1000 °C. When the pre-oxidation temperature is set at 950 °C, the mass gain of the samples is the lowest, and the accelerated decomposition of Cr2O3 caused by high pre-oxidation temperature is avoided. After oxidation for 300 h, the oxide film on the surface is still continuous and dense without peeling. The samples pre-oxidized at 950 °C for 7 h show the best oxidation resistance in a 1000 °C constant temperature oxidation process, more α-Al2O3 oxides are generated on the coating surface and the element diffusion between the matrix and the coating caused by overly long oxidation time is avoided.
Experimental Study on Seismic Performance of Precast Columns Repaired with CFRP Fabrics
Authors: Liu Laijun , Lei Song , Wu Fangwen , Lin Weiwei , Peng Kai , Fan Xiangyan
Published: October 2022

Earthquakes worldwide highlight the seismic vulnerability of reinforced concrete (RC) bridge columns. RC bridges are likely to collapse or lose service function due to damage to the bridge columns from strong earthquakes. Rapid repair of RC bridge columns is of great significance for maintaining traffic lines for emergency rescue work after earthquakes. In this study, an improved rapid repair method was developed to restore the bearing capacity of a damaged precast column after earthquake damage. A cyclic loading test was performed to simulate the seismic loading. The original column and the repaired column were both tested. The test results showed that the bearing capacity of the repaired columns was increased by 8%, and the energy dissipation capacity was 53% higher than that of the original column. The ductility decreased because the test for the repaired specimen ended in advance. The initial stiffness of the repaired columns was reduced, but the stiffness was significantly developed in the later loading stage. The rapid repair method proposed in this study exhibited an excellent effect on restoring the seismic resistance of the damaged columns.
Photovoltaic Electrochemically Driven Degradation of Calcon Dye with Simultaneous Green Hydrogen Production
Authors: Câmara Cardozo Jussara , da Silva Djalma R. , Martínez-Huitle Carlos A. , Quiroz Marco A. , Dos Santos Elisama V.
Published: October 2022

In this study, for the first time, the production of green hydrogen gas (H2) in the cathodic compartment, in concomitance with the electrochemical oxidation (EO) of an aqueous solution containing Calcon dye at the anodic compartment, was studied in a PEM-type electrochemical cell driven by a photovoltaic (PV) energy source. EO of Calcon was carried out on a Nb/BDD anode at different current densities (7.5, 15 and 30 mA cm−2), while a stainless steel (SS) cathode was used for green H2 production. The results of the analysis by UV-vis spectroscopy and total organic carbon (TOC) clearly showed that the electrochemical oxidation (EO) of the Calcon dye after 180 min of electrolysis time by applying 30 mA cm−2 reached up to 90% of degradation and 57% of TOC removal. Meanwhile, under these experimental conditions, a green H2 production greater than 0.9 L was achieved, with a Faradaic efficiency of 98%. The hybrid electrolysis strategy is particularly attractive in the context of a circular economy, as these can be coupled with the use of more complex water matrices to transform organic depollution into an energy resource to produce H2 as a chemical energy carrier.
The Wavelength-Dependent SERS Template Based on a Nanopillar Array
Authors: Li Jiayi , Li Rui , Xu Ying , Xue Xiaojun , Chen Xiaoming , Chui Hsiang-Chen
Published: October 2022

Surface-enhanced Raman spectroscopy (SERS) can be regarded as a powerful tool for probing chemical molecules by effectively enhancing Raman signals. However, the enhancement factors depend on the SERS template, the probed molecular structures, and the excitation laser wavelength. Herein, we proposed a simple and easily fabricated nanostructured template for SERS and analyzed the wavelength-dependent factors. Three types of golden nanopillar arrays on silicon wafers were designed and manufactured. The SERS signals of the Rhodamine 6G (R6G) molecules were extracted. Three laser sources, a blue 17 mW 458 nm diode laser, a green 20 mW 532 nm laser, and a red 6 mW 633 nm laser, were employed as the excitation laser sources. The 458 nm laser was located far from the resonate spectrum of R6G. The optical intensity distributions for the different SERS templates excited by three laser beams were also simulated. The enhancement factors (EFs) of R6G on the three nanostructured templates were measured and compared. The photoluminescence spectrum of the nanostructured templates and SERS signals of R6G were also measured. In addition, the experimental results concerned optical simulations. The analysis tool that was used was a convolution profile of multiple Lorentzian line shapes with a Gaussian profile. It is helpful to understand the SERS signals when the excitation laser wavelength is located out of the resonance region of molecules. It can also provide a new design approach to fabricate an SERS Template with a nanopillar array for different excitation wavelengths.
Structural Characterization of Phosphorous Slag Regarding Occurrence State of Phosphorus in Dicalcium Silicate
Authors: Wang Yu , Zhang Na , Xiao Huiteng , Zhao Jihan , Zhang Yihe , Liu Xiaoming
Published: October 2022

Phosphorous slag is a solid waste generated in the process of yellow phosphorus production. In order to deeply understand the structural and cementitious characteristics of phosphorous slag, comprehensive characterizations, including X-ray fluorescence spectrometry, X-ray diffraction, thermogravimetry, Fourier transform infrared spectrometry, Raman, scanning electron microscope, and inductively coupled plasma mass spectrometry were adopted to investigate the composition, thermal stability, microstructure, and cementitious activity of phosphorous slag. In addition, scanning electron microscope with energy dispersive X-ray spectroscopy, electron microprobe analysis, and solid-state nuclear magnetic resonance techniques were used to analyze the occurrence state of P in phosphorous slag. The results show that phosphorous slag is mostly vitreous with good thermal stability. Its chemical composition mainly comprises 43.85 wt % CaO, 35.87 wt % SiO2, and 5.57 wt % Al2O3, which is similar to that of blast furnace slag, but it presents lower cementitious activity than blast furnace slag. P is uniformly distributed in the phosphorous slag with P2O5 content of 3.75 wt %. The distribution pattern of P is extremely similar to that of Si. P is mainly existing in orthophosphate of 3CaO·P2O5, which forms solid solution with dicalcium silicate (2CaO·SiO2). This work specifically clarifies the occurrence state of P in dicalcium silicate within the phosphorous slag. It is theoretically helpful to solve the retarding problem of phosphorous slag in cement and concrete.
Point Defects Stability, Hydrogen Diffusion, Electronic Structure, and Mechanical Properties of Defected Equiatomic γ(U,Zr) from First-Principles
Authors: Huang Shasha , Ma Jiang-Jiang , Lai Kan , Zhang Cheng-Bin , Yin Wen , Qiu Ruizhi , Zhang Ping , Wang Bao-Tian
Published: October 2022

At present, many experimental fast reactors have adopted alloy nuclear fuels, for example, U-Zr alloy fuels. During the neutron irradiation process, vacancies and hydrogen (H) impurity atoms can both exist in U-Zr alloy fuels. Here, first-principles density functional theory (DFT) is employed to study the behaviors of vacancies and H atoms in disordered-γ(U,Zr) as well as their impacts on the electronic structure and mechanical properties. The formation energy of vacancies and hydrogen solution energy are calculated. The effect of vacancies on the migration barrier of hydrogen atoms is revealed. The effect of vacancies and hydrogen atom on densities of states and elastic constants are also presented. The results illustrate that U vacancy is easier to be formed than Zr vacancy. The H interstitial prefers the tetrahedral site. Besides, U vacancy shows H-trap ability and can raise the H migration barrier. Almost all the defects lead to decreases in electrical conductivity and bulk modulus. It is also found that the main effect of defects is on the U-5f orbitals. This work provides a theoretical understanding of the effect of defects on the electronic and mechanical properties of U-Zr alloys, which is an essential step toward tailoring their performance.
XPS Investigation on Improving Hydrogen Sorption Kinetics of the KSiH3 System by Using Zr-Based Catalysts
Authors: Tiwari Anish , Agarwal Shivani , Shrivastava Kriti , Ichikawa Takayuki , Jain Ankur , Singh Rini
Published: October 2022

The superior hydrogen storage properties makes the KSiH3 system a potential hydrogen storage material for practical applications. A theoretical capacity of 4.3 wt% bring this material to the front line of all the available hydrogen storage materials; however, the activation barrier of the reaction restricts the system to absorb and desorb hydrogen reversibly at elevated temperatures even if the thermodynamics suggest its room temperature operation. Several catalysts have already been tested to enhance its kinetic properties. In this work, the efforts were made to reduce the activation energy by using Zr-based catalysts to the KSi/KSiH3 system. The value of activation energy was found to be lowest (i.e., 87 kJ mol−1) for the ZrH2-added KSiH3 system. The mechanism of this improvement was investigated by using X-ray photoelectron spectroscopy (XPS).
Novel Apex Connection for Light Wood Frame Panelized Roof
Authors: Islam Md Saiful , Chui Ying Hei , Chen Zengtao
Published: October 2022

Panelized fabrication of light-frame wood buildings has higher productivity than the traditional stick-built method. However, the roof production process is not very efficient due to the structural system and construction method. This study proposes a novel apex connection that allows for a folding mechanism in a panelized light wood frame roof system. Proof of concept of the proposed connection assembly is presented by a 3D printout of the developed connection. Following the steel design code and timber code, the initial estimation of different parameters, such as the pinhole diameter and number screws, were established. A detailed finite element analysis (FEA) was performed to determine the connection strength requirement for different load case scenarios. The results of the FEA and 3D printout of the assembly show that the proposed connection can provide the required folding mechanism before roof installation and can withstand the load in the unfolding state at service.
Simulation of Inclusion Particle Motion Behavior under Interfacial Tension in Continuous Casting Mold
Authors: Siddiqui Md Irfanul Haque , Albaqami Ayidh , Arifudin Latif , Alluhydan Khalid , Alnaser Ibrahim Abdullah
Published: October 2022

Inclusions entrapped by the solidifying front during continuous casting adversely affect the properties of the final steel products. In this study, we investigated the effect of the interfacial tension due to surfactant concentration, particularly sulfur, on alumina inclusion motion behavior during molten steel solidification in a continuous casting mold. A two-dimensional numerical model was developed in Ansys Fluent software to simulate the inclusion motion in a continuous casting mold. Further, the impacts of different values of the alumina inclusion diameter, sulfur concentration, and melt temperature were studied to understand the inclusion motion behavior. The inclusion diameter affected the inclusion distribution throughout the domain. The alumina inclusion entrapment percentage varied in the case of sulfur mixing (using an empirical relationship for modeling). It was found that the removal percentage varied according to the sulfur concentration. The addition of sulfur at concentrations from 10 ppm to 70 ppm resulted in a 4% increase in the removal of alumina inclusions (trapped in the solidifying shell), except for the 100-ppm case. Smaller-sized inclusion particles had a 25% higher chance of entrapment at the top level of the mold. Under the effect of a higher surface tension gradient between inclusions and the melt, the predicted findings show that inclusions were vulnerable to engulfment by the solidification front.
Insights into the Effect of Lithium Doping on the Deep Eutectic Solvent Choline Chloride:Urea
Authors: de Araujo Lima e Souza Giselle , Di Pietro Maria Enrica , Castiglione Franca , Vanoli Valeria , Mele Andrea
Published: October 2022

Choline-based deep eutectic solvents (DESs) are potential candidates to replace flammable organic solvent electrolytes in lithium-ion batteries (LIBs). The effect of the addition of a lithium salt on the structure and dynamics of the material needs to be clarified before it enters the battery. Here, the archetypical DES choline chloride:urea at 1:2 mole fraction has been added with lithium chloride at two different concentrations and the effect of the additional cation has been evaluated with respect to the non-doped system via multinuclear NMR techniques. 1H and 7Li spin-lattice relaxation times and diffusion coefficients have been measured between 298 K and 373 K and revealed a decrease in both rotational and translational mobility of the species after LiCl doping at a given temperature. Temperature dependent 35Cl linewidths reflect the viscosity increase upon LiCl addition, yet keep track of the lithium complexation. Quantitative indicators such as correlation times and activation energies give indirect insights into the intermolecular interactions of the mixtures, while lithium single-jump distance and transference number shed light into the lithium transport, being then of help in the design of future DES electrolytes.
Influence of Nanoclay on the Thermo-Mechanical Properties of Silicone Pressure-Sensitive Adhesives
Authors: Antosik Adrian Krzysztof , Mozelewska Karolina
Published: October 2022

This research was carried on newly obtained innovative materials—self-adhesive one-sided tapes based on silicone pressure-sensitive adhesives. In order to obtain tapes, the stable adhesive composition was subjected to physical modification by incorporating into it various amounts of selected silicon fillers. The produced pressure-sensitive adhesives were tested for viscosity and thermogravimetric analysis, as well as the manufactured tapes; i.e., peel adhesion, tack, cohesion at room and elevated temperature, SAFT test (shear adhesive failure temperature), and shrinkage. The prepared self-adhesive tapes retained their self-adhesive properties at a level close to the initial level while increasing the thermal resistance by 70–75 °C, reaching the level of 220–225 °C. The new self-adhesive materials have application potential and can be used as a material for special applications in the field of electrical engineering and heavy industry.
Comparison between Genetic Programming and Dynamic Models for Compact Electrohydraulic Actuators
Authors: Bamshad Hamid , Jang Seongwon , Jeong Hyemi , Lee Jaesung , Yang Hyunseok
Published: October 2022

A compact electrohydraulic actuator (C-EHA) is an innovative hydraulic system with a wide range of applications, particularly in automation, robotics, and aerospace. The actuator provides the benefits of hydraulics without the expense and space requirements of full-sized hydraulic systems and in a much cleaner manner. However, this actuator is associated with some disadvantages, such as a high level of nonlinearity, uncertainty, and a lack of studies. The development of a robust controller requires a thorough understanding of the system behavior as well as an accurate dynamic model of the system; however, finding an accurate dynamic model of a system is not always straightforward, and it is considered a significant challenge for engineers, particularly for a C-EHA because the critical parameters inside cannot be accessed. Our research aims to evaluate and confirm the ability of genetic programming (GP) to model a nonlinear system for a C-EHA. In our paper, we present and develop a GP model for the C-EHA system. Furthermore, our study presents a dynamic model of the system for comparison with the GP model. As a result, by using this actuator in the 1-DOF arm system and conducting experiments, we confirmed that the GP model has a better performance with less positional error compared with the proposed dynamic model. The model can be used to conduct further studies, such as designing controllers or system simulations.
Electromagnetic Characteristics Analysis and Structure Optimization of High-Speed Fuel Solenoid Valves
Authors: Yang Liu , Gao Tianxiong , Du Xinming , Zhai Fugang , Lu Chang , Kong Xiangdong
Published: October 2022

High-speed fuel solenoid valves (HFSVs) are the key control elements of aero-engine vane regulators. A strong electromagnetic force generated from the HFSVs is essential to achieve precise control over timing and quantification for fuel supply. In this paper, the Taguchi method is adopted to improve the HFSV’s static electromagnetic characteristics. First, an electromagnetic model of the HFSV was established and experiments were conducted to modify and validate the model. Effects of key structural factors on the static electromagnetic characteristics of the HFSV are then investigated via the finite element method (FEM). Based on the optimization, an HFSV prototype is finally manufactured and tested. The experiment results are in good agreement with those of the simulations. It provides a significant guideline for the manufacturing process of such HFSVs.
Lattice Structure Design Method Aimed at Energy Absorption Performance Based on Bionic Design
Authors: He Gang , Yang Hu , Chen Tao , Ning Yuan , Zou Huatao , Zhu Feng
Published: October 2022

To obtain the lattice structure with excellent energy absorption performance, the structure of loofah inner fiber is studied to develop bionic design of lattice structure by experiment and simulation analysis method. From the compression experiment about the four bionic multi-cell lattice structures (bio-45, bio-60, bio-75, and bio-90) and VC lattice structures, we found that all are made of PLA and fabricated by the fused deposition modeling (FDM) 3D printer. The comprehensive performance of bio-90 lattice structure is the best in the performance of the specific volume energy absorption (SEAv), the effective energy absorption (EA), and the specific energy absorption (SEA). Based on the experimental result, the energy absorption performance of bio-90 lattice structure is then studied by the simulation analysis of influence on multiple parameters, such as the number of cells, the relative density, the impact velocity, and the material. The results can provide a reference for the design of highly efficient energy absorption structures.
Parametric Distributions for Survival and Reliability Analyses, a Review and Historical Sketch
Authors: Taketomi Nanami , Yamamoto Kazuki , Chesneau Christophe , Emura Takeshi
Published: October 2022

During its 330 years of history, parametric distributions have been useful for survival and reliability analyses. In this paper, we comprehensively review the historical backgrounds and statistical properties of a number of parametric distributions used in survival and reliability analyses. We provide encyclopedic coverage of the important parametric distributions, which is more extensive than the existing textbooks on survival and reliability analyses. We also explain how these distributions have been adopted in survival and reliability analyses with original and state-of-the-art references. We cover the exponential, Weibull, Rayleigh, lognormal, log-logistic, gamma, generalized gamma, Pareto (types I, II, and IV), Hjorth, Burr (types III and XII), Dagum, exponential power, Gompertz, Birnbaum-Saunders, exponential-logarithmic, piecewise exponential, generalized exponential, exponentiated Weibull, generalized modified Weibull, and spline distributions. We analyze a real dataset for illustration.
Modeling the Interplay between HDV and HBV in Chronic HDV/HBV Patients
Authors: Mhlanga Adequate , Zakh Rami , Churkin Alexander , Reinharz Vladimir , Glenn Jeffrey S. , Etzion Ohad , Cotler Scott J. , Yurdaydin Cihan , Barash Danny , Dahari Harel
Published: October 2022

Hepatitis D virus is an infectious subviral agent that can only propagate in people infected with hepatitis B virus. In this study, we modified and further developed a recent model for early hepatitis D virus and hepatitis B virus kinetics to better reproduce hepatitis D virus and hepatitis B virus kinetics measured in infected patients during anti-hepatitis D virus treatment. The analytical solutions were provided to highlight the new features of the modified model. The improved model offered significantly better prospects for modeling hepatitis D virus and hepatitis B virus interactions.
A Collision Reduction Adaptive Data Rate Algorithm Based on the FSVM for a Low-Cost LoRa Gateway
Authors: Wang Honggang , Pei Peidong , Pan Ruoyu , Wu Kai , Zhang Yu , Xiao Jinchao , Yang Jingfeng
Published: October 2022

LoRa (Long Range), a wireless communication technology for low power wide area networks (LPWANs), enables a wide range of IoT applications and inter-device communication, due to its openness and flexible network deployment. In the actual deployment and operation of LoRa networks, the static link transmission scheme does not make full use of the channel resources in the time-varying channel environment, resulting in a poor network performance. In this paper, we propose a more effective adaptive data rate (ADR) algorithm for low-cost gateways, we firstly analyze the impact of the different hardware parameters (RSSI, SNR) on the link quality and classify the link quality using the fuzzy support vector machine (FSVM). Secondly, we establish an end device (ED) throughput model and energy consumption model and design different adaptive rate algorithms, according to the different link quality considering both the link-level performance and the MAC layer performance. The proposed algorithm uses machine learning to classify the link quality, which can accurately classify the link quality using a small amount of data, compared to other adaptive rate algorithms, and the link parameter adaptation algorithm can maximize the throughput while ensuring the link stability, by considering the link-level performance and the MAC layer performance, compared to other algorithms. The results show that it outperforms the standard LoRaWAN ADR algorithm in both the single ED and the multi ED scenarios, in terms of the packets reception rate (PRR) and the network throughput. Compared to the LoRaWAN ADR in 32 multi-ED scenarios, the proposed algorithm improves the throughput by 34.12% and packets the reception rate by 26%, significantly improving the network throughput and the packets reception rate.
On the Regulated Nuclear Transport of Incompletely Spliced mRNAs by HIV-Rev Protein: A Minimal Dynamic Model
Authors: Ishizuka Jeffrey J. , Soble Delaney A. , Chang Tiffany Y. , Peacock-López Enrique
Published: October 2022

A kinetic model for the HIV-1 Rev protein is developed by drawing upon mechanistic information from the literature to formulate a set of differential equations modeling the behavior of Rev and its various associated factors over time. A set of results demonstrates the possibility of oscillations in the concentration of these factors. Finally, the results are analyzed, and future directions are discussed.