bluuebunny/crossref_metadata_2025 huggingface dataset:
Civics Education Teaching Materials with Balinese Cultural Perspective for Enhancing Learning Achievement and Love of Balinese Culture Attitude at Elementary School
Authors: Adijaya Made Aryawan
Published: May 2023

This study aimed at developing civics education teaching materials with Balinese cultural perspective. This study was development research using the ADDIE (Analysis, Design, Development, Implementation, Evaluation) model. The subjects of this research were a third-grade teacher and twenty-three third grade students. To measure the validity of the teaching materials an expert’s evaluation sheet was used and to evaluate the implementation of the civics materials   teachers’ and students’ responses questionnaires were used. The results of of the study were: 1) one civics teaching material, seven lesson plans, and 7 student worksheets which have been developed with Balinese cultural perspective. The material that was developed was under the topic “Bangga Menjadi Anak Indonesia” (Proud to become Indonesian children). 2) This product has been validated by an expert in civics education, an instructional design expert, a Balinese culture expert, and an evaluation expert and an education expert, yielding CVR of 1.00 and CVI of 1.00, categorized as valid and feasible to be tried out. 3) This product has been tried out on a limited scale in the third grade and the result showed that the produce could enhance learning achievement of the students with the averages of    81.04, 86.83, and 90.22, in the first, second and third meetings respectively, and love of Balinese culture attitude of the students with the averages of 86.90, 88.46 and 91.42.
Efecto de las Estrategias Financieras en la Competitividad y la Innovación de empresas
Authors: Mata Zamores Silvia , García Vidales Miguel Alejandro , Montejano-García Salomón , Landa Suárez Luis Fernando , Campos-García Rocío Montserrat
Published: May 2023

La planificación financiera ha incrementado la dependencia sobre la administración estratégica y la planificación financiera para responder a las constantes externas del mercado (Altay et al., 2023; Rådberg y Löften, 2022). Por lo tanto, se determinó el efecto del control financiero, el control de riesgo y la planeación de inversión sobre la competitividad y la innovación de empresas manufactureras en el estado de Aguascalientes, mediante la metodología de Troise et al. (2022) para la medición de variables y la de Pinto et al. (2023) para la correlación lineal. La metodología consistió en el análisis correlacional de variables y rotación varimax de información recolectada mediante un cuestionario tipo Likert, encontrándose que las estrategias financieras tienen una correlación de 0.948 con la competitividad y de 0.927 con la innovación, lo que indica la existencia de planificación financiera mediante un proceso de estructuración en sus modelos de negocio a través de incentivos financieros para operar de forma activa y permanente en el mercado. Estos hallazgos limitan la brecha del conocimiento entre la capacidad financiera y las capacidades aprehendidas, ya que, a mayor desarrollo de las estrategias financieras, habrá más nivel de competitividad e innovación, mejorando las estrategias financieras y los modelos de negocios.
PENGEMBANGAN MEDIA PEMBELAJARAN SPINNING WHEEL MATERI PERUBAHAN WUJUD BENDA PADA MATA PELAJARAN IPA DI KELAS III SDN PENGADEGAN 07 JAKARTA SELATAN
Authors: Fransis Kurnianingsih Monika , Amelia Winda
Published: May 2023

ABSTRACT

This study aims to determine the feasibility of spinning wheel learning media, and determine the effectiveness of spinning wheel learning media. This study uses the RnD (Research and Development) research method with the Borg and Gall model. The test subjects in this study were 30 grade III students at SDN Pengadegan 07 South Jakarta. The media developed was declared feasible and valid based on the results of several experts: design experts with a score of 100.00%, linguists with a score of 80.00%, and material experts with a score of 84.00%. The product trial on 9 students received a score of 92.22% in the very feasible and effective category and the shared use trial of 30 students scored 91.2% in the very feasible and effective category to be applied to students when learning in class and can add interest in learning for students.

Keywords: Learning Media, spinning wheel, Development.

ABSTRAK

Penelitian ini bertujuan untuk mengetahui kelayakan media pembelajaran spinning wheel, dan mengetahui keefektifan media pembelajaran spinning wheel. Penelitian ini menggunakan metode penelitian RnD (Research and Development) dengan model Borg and Gall. Subjek uji coba pada penelitian ini yaitu siswa kelas III SDN Pengadegan 07 Jakarta Selatan yang berjumlah 30. Media yang dikembangkan dinyatakan layak dan valid berdasarkan hasil dari beberapa ahli : ahli media dengan nilai 100,00%, ahli bahasa dengan nilai 80,00%, dan ahli materi dengan nilai 84,00%. Uji coba produk terhadap 9 siswa mendapatkan nilai 92.22% kategori sangat layak dan efektif dan uji coba pemakaian bersama 30 siswa mendapatkan nilai 91,2% kategori sangat layak dan efektif untuk di aplikasikan kepada siswa saat pembelajaran di kelas dan bisa menambah minat belajar untuk siswa.

 

Kata Kunci: Media Pembelajaran, spinning wheel, Pengembangan
INTEGRASI PENDIDIKAN KARAKTER DALAM PEMBELAJARAN IPA DI SEKOLAH DASAR
Authors: Taher Rahma , Murni Irda , Yarni Nevi
Published: May 2023

Education in schools is the development of the potential of students, with this a person will become a human being who has the skills to carry out his life optimally character education, namely; forming the child's personality, so that he becomes a good human being, a citizen, and a good citizen, so that he is able to anticipate symptoms of a moral crisis and play a role in fostering the younger generation. Character education is the main key that must be applied to learning so that students have good morals. Good morals really have a big role in the survival of each individual. This character education is a bridge to manage and control the emotions of students. Natural Sciences (IPA) is one of the fields of study taught in elementary schools (SD). By learning Science, students can get to know the surrounding environment and everything in it, through various activities carried out by students in learning activities. Through learning Science, students can be included the values of character education by integrating the material in the science learning. This study aims to find out how the integration of character education in learning science in elementary schools.
MENINGKATKAN KEAHLIAN MEMAHAMI BACAAN DENGAN MENGGUNAKAN METODE PQ4R PESERTA DIDIK KELAS IV SEKOLAH DASAR
Authors: Atmawati Devi Rika , Ma’rufah Rohmanurmeta Fauzatul , Arimurti Lindu
Published: May 2023

This action research aims to provide solutions to the problem of low reading comprehension levels among fourth-grade students at SD Negeri Manuk Ponorogo. The researched solution is the use of the PQ4R method (Preview, Question, Read, Reflect, Recite, Review) to improve students' reading comprehension skills. This research collaborated with teachers in adopting the Hopkins Research Model, which consisted of two action cycles. The research subjects were five female and three male students in the fourth grade of SD Negeri Manuk. Data collection techniques for analysis in this research used both test and non-test methods. Meanwhile, the data analysis techniques used by the researchers were quantitative and qualitative descriptive analysis techniques. After conducting this research using the PQ4R method, it was found that the subject students' understanding of a reading had significantly increased. The pre-action initial test results showed an average score of 63.75, gradually increasing to an average score of 69.60 in cycle I, and an average score of 74.60 in cycle II. Furthermore, the percentage of students who were able to pass the threshold score of 70 also showed a significant improvement. In the initial pre-action, only 25% of students passed the threshold score, while in cycle I, it was 63%, and in cycle II, 88% of students had passed the threshold score.
PENINGKATAN HASIL BELAJAR BAHASA INDONESIA MENGGUNAKAN MODEL PBL BERBANTUAN BOOKLET PADA SISWA KELAS 1 SDN PURWANTORO 2
Authors: Dikna Putri Cantika , Rohman Wahid Abdur , Sunaryo Hari
Published: May 2023

The low learning outcomes of Indonesian students are due to the fact that the learning that is implemented still applies teacher-centered learning. Student involvement in learning Indonesian is still minimal, so a form of learning is needed that is able to make students more active in participating in learning activities and can improve the learning outcomes of the Indonesian language. This classroom action research aims to improve Indonesian language learning outcomes through a booklet-assisted problem based learning (PBL) learning model for grade 1 students at SDN Purwantoro 2, Blimbing District, Malang City. This research was conducted in two cycles, each cycle consisting of four stages, namely planning, implementing, observing, and reflecting. The research subjects were class 1B students at SDN Purwantoro 2 which consisted of 23 students. Data collection in this study was carried out using the test method, with the type of test being an essay. The study experienced an increase in achievement in each aspect of the indicators from cycle one to cycle two. The results showed that the application of the booklet-assisted PBL model in the second cycle was able to significantly improve students' Indonesian learning outcomes. This can be seen from the comparison before and after the action is taken. In the early stages, cycle I showed 15 students or 65% who successfully completed learning. But in cycle II, the number of students who passed increased to 21 students or 91%. In addition, the results of class observations showed that students were more involved, motivated, and active in the learning process during the booklet-assisted PBL activities. Overall, this study also emphasizes the importance of integrating problem-solving activities and collaborative learning in the classroom to improve student learning outcomes.
Pengaruh Citra Merek, Kualitas Layanan, dan Digital Banking Terhadap Loyalitas Nasabah Melalui Kepuasan Nasabah Sebagai Variabel Intervening Pada PT Bank Syariah Indonesia Cabang Pekalongan Pemuda
Authors: Yusuf Mochamad , Syafi'i Muhammad Aris , Tammamudin Tamamudin
Published: May 2023

Customer loyalty is a commitment to using the product. Customer loyalty is achieved through satisfaction, brand image, service quality, and digital banking. This study aims to determine the effect of brand image, service quality, and digital banking on customer loyalty through customer satisfaction as an intervening variable at Bank Syariah Indonesia Pekalongan Pemuda. This research is quantitative research. The population amounted to 48,200. Sample of 100 respondents with the slovin formula, standard error 10%. Accidental sampling technique using a questionnaire. Data analysis techniques in the form of instrument tests, classical assumption tests, path analysis, hypothesis testing and coefficient of determination tests. The results showed that brand image significantly affects satisfaction with a beta value of 0.421 and a significance of 0.00. Service quality has no effect and is not significant to customer satisfaction with a beta value of -0.029 and a significance of 0.545. Digital banking has no effect and is not significant to customer satisfaction with a beta value of -0.002 and a significance of 0.964. Brand image significantly affects customer loyalty with a beta value of 0.436 and a significance of 0.001. Service quality has no effect and is not significant to customer loyalty with a beta value of 0.091 and a significance of 0.194. Digital banking has a significant effect on customer loyalty with a beta value of 0.392 and a significance of 0.00. Customer satisfaction significantly affects customer loyalty with a beta value of 0.504 and a significance value of 0.001. Customer satisfaction mediates the effect of brand image on customer loyalty with a t value = 2.178. Customer satisfaction does not mediate the effect of service quality on customer loyalty with a t value of -0.454. Customer satisfaction does not mediate the effect of digital banking on customer loyalty with a t value of 0.037.Keywords: Brand Image, Service Quality, Digital Banking, Customer Satisfaction, and Customer Loyalty.
Peningkatan Pengetahuan Siswa Tentang Makanan Jajanan Sehat
Authors: Wilda Welis  , Darni  , Nuridin Widya Pranoto
Published: May 2023

Gambaran tentang status gizi anak sekolah tersebut menunjukkan bahwa masih terdapat masalah gizi dan kesehatan  yang belum terselesaikan.  Kondisi ini diperparah oleh kebiasaan jajanan pada anak sekolah yang belum dapat diarahkan secara baik.  masih banyak orangtua dan guru yang belum memberikan arahan yang tepat tentang makanan jajanan sehat yang boleh dibeli oleh anak, bahkan masih banyak pedagang makanan jajanan di sekitar sekolah yang belum memperhatikan keamanan makanan jajanan yang dijual.Identifikasi dan permasalahan sebagai berikut : a. Masih banyak sekolah dasar yang belum menyediakan kantin sekolah yang sehat dan dapat menyediakan kebutuhan makanan bagi siswanya. b. Belum tersedia kantin sehat yang dapat menyediakan makanan sehat bagi siswanya menyebabkan banyak pedagang yang memanfaatkan peluang untuk berjualan makanan jajanan di sekolah-sekolah. c. Masih banyak pedagang menjual makanan dengan pewarna dan pemanis buatan serta kondisi yang kurang higienis. Calon peserta siswa untuk kegiatan pengabdian masyarakat ini di rekrut dan di rekomendasikan oleh kepala sekolah.   Jumlah peserta direncanakan berjumlah 50 orang. Dalam menyampaikan materi kepada para peserta akan dipakai beberapa macam metode dan penggunaan media yang relevan antara lain dengan metode ceramah, diskusi dan demonstrasi sesuai dengan bidang keamanan pangan dan gizi. Berdasarkan hasil kegiatan sosialisasi dan penyuluhan tentang pengetahuan makanan jajanan sehat bagi siswa, Sebagian besar pengetahuan gizi makanan jajanan yang sehat pada siswa termasuk kategori rendah hingga sedang, belum banyak yang memiliki pengethauan gizi makanan jajanan yang baik. Pengetahuan siswa tentang bahan tambahan makanan jajanan masih rendah sehingga banyak yang masih berperilaku membeli makanan jajanan yang diproduksi dengan bahan tambahan makanan jajanan yang tidak sehat.
Program Pengembangan Usaha Produk Intelektual Kampus Pusat Sport Entrepreneur
Authors: Sazeli Rifki Muhamad , Hermanzoni  , Eval Edmizal  , Ariando Ariston  , Fair Muda
Published: May 2023

Tujuan utama dalam program PPUPIK pusat sport entrepreneur ini adalah untuk mendorong Fakultas Ilmu Keolahragaan menghasilkan jasa berupa peralatan dalam aktivitas olahraga dan kebugaran olahraga bagi semua kalangan. Pada pelaksanaanya dikelola oleh kelompok dosen yang tergabung dalam pusat sport entrepreneur dari Fakultas Ilmu Keolahragaan. Pada pelaksanaanya dikelola oleh kelompok dosen yang tegabung dalam pusat sport entrepreneur dari Fakultas Ilmu Keolahragaan. Didirikannya pusat sport entrepreneur ini diharapkan nantinya dapat berkembang secara baik dengan menampung instansi olahraga, kalangan umum yang membutuhkan barang dan jasa yang berkaitan dengan peralatan olahraga dan kebugaran serta menjadi satu-satunya pusat sport entrepreneur di Sumatera Barat. Target utama dari klien yang akan menggunakan jasa dari sport entrepreneur adalah seluruh cabang olahraga yang nantinya akan disosialisasikan dalam program kegiatan berjalan. Kegiatan yang akan dikembangkan adalah kegiatan berupa jasa pembuatan peralatan olahraga, souvenir olahraga dan kebugaran terdiri dari: a) Media elektronik atau media cetak, b) event organizer c) Sewa peralatan outdoor
Pelatihan fundamental coaching bagi pelatih bola voli di klub Badak Muda Gunung Kidul
Authors: Sujarwo
Published: May 2023

Pengabdian kepada masyarakat ini dilaksanakan untuk memberikan informasi kepada pelatih di Klub bola voli Badak Muda Gunung Kidul tentang dasar-dasar dalam melatih bola voli. Dimana pelatih di klub Badak Muda ini masih belum banyak jumlahnya dan masih sedikit yang memiliki lisensi kepelatihan bola voli, sehingga sangat butuh informasi tentang kepelatihan bola voli. Metode pengabdian dalam kegiatan ini adalah pelatihan sehari, dimana dilakukan teori dan praktek, mulai dari jam 08.00 s.d 12.00 wib, materi teori bertempat di Aula Balai Desa Warak, Gunung Kidul, dan kemudian dilanjutkan jam 15.00 s.d 17.00 wib di Lapangan Bola Voli Klub Badak Muda di Warak, Gunung Kidul. Peserta pelatihan 11 orang pelatih di klub Badak Muda. Instrumen penilaian pengetahuan baik sebelum dan sesudah pengabdian dengan menggunakan soal pretest dan posttest. Hasil pengabdian sebagai berikut: hasil rerata mean pre test pengetahuan pelatih tentang dasar kepelatihan adalah: 61.81; untuk rerata mean pengetahuan setelah diadakan pelatihan adalah: 86.36. Terjadi peningkatan pengetahuan sebesar 0.25% pengetahuan pelatih tentang fundamental coaching setelah diadakan pelatihan. Kesimpulan pengabdian masyarakat kali ini adalah pengetahuan pelatih dalam dasar-dasar kepelatihan harus terus di update atau diperbarui dengan adanya kursus kepelatihan maupun seminar khusus bola voli. Mengingat perkembangan aturan dan permainan bola voli yang amat pesat.
The debate on philosophical sufism: Dynamics and dialectics in Aceh
Authors: Latif Mukhlis
Published: May 2023

This research aims to explain the philosophy of tasawuf Hamzah Fansri in Nusantara Islam. The textual research method was employed to interpret the contents in the manuscripts of tasawuf falsafi in Aceh, especially regarding tasawuf falsafi, which Hamzah Fansūrī developed. The study findings confirm that Hamza Fansūrī's philosophical tasawuf thought is "symbolic-comtemplative" and attempts to locate the exploration of the symbols that are highlighted as the essence and substance of the teachings of philosophical tasawuf. There is a misunderstanding about philosophical Sufism, especially by other parties who try to observe and assess the substance of the teachings of philosophical Sufism, which is a natural thing. Criticism of Hamzah Fansurī's philosophical tasawuf thoughts, especially those made by Nūr al-Dīn al-Ranīrī, is commonplace and reasonable in the scientific realm of Islam. However, the accusation of slander and the opinion that Hamzah Fansurī has gone astray and deviated from Islamic principles is something common sense cannot accept. Hamzah Fansurī's thoughts related to Wujudiyah's views are widespread and have not only developed in Aceh. The originality of this study is that it confirms that philosophical Sufism has a symbolic and implicit aspect and characteristics that are difficult to understand. Therefore, if one is trapped in a narrow understanding of symbols, then philosophical Sufism is only a "skin" which is different from the substance or "content" inside.
Me and My Secrets: A Phenomenological Study of Communication Privacy Management of Atheists in the Indonesian Context Regarding Their Identity
Authors: Santika Azzumar Adhitia , Sukandar Rudi
Published: May 2023

Being an Atheist is always an unpopular choice in the middle of high religious context society. The stigma and pressure from religious groups forced Atheists in Indonesia to hide their identity in public generally and when taking care of the affairs of state administration. This research utilized Communication Privacy Management and Dramaturgy Theory alongside the phenomenology perspective to reveal how Atheists in Indonesia live their "beliefs" in their not-so-friendly environment. The results showed that they generally presented themselves as religious in front of their family by pretending to practice religious rituals, contributing to their special personal branding for the families. Meanwhile, in other social environments, such as friendship, they could be freer to present themselves as they were, although they still had to manage private information about their Atheist identity.
CONVERSION OF PROPANE TO FORMALDEHYDE ON IRON PHOSPHATE
Authors: Dzyamko V.M.
Published: May 2023

Phosphates represent diverse complex systems, whose basic structural unit is tetrahedron. They are widely applied as catalysts, carriers of catalytic active substances, adsorbents and ion exchangers. Phosphoric acid and phosphates act as catalyst for reactions of alkylation, cracking, izomerization, polymerization, hydrogenation and dehydrogenation. Phosphates of some metals promote oxidation of normal alkanes with derivation of aldehydes, acids, spirits and maleic anhydride.

The process of propane and propylene oxidation on iron phosphate is investigated, as well as the influence of such factors as temperature, contact time of the reacting mixture with the catalyst t, the ratio of oxygen and hydrocarbon concentration in a mixture, and the influence of hydrogen concentration on the given process is shown.

It is demonstrated that the optimum conditions for the realization of propane oxidation process is the temperature of 973 K and t = 0.17 s. It is established that with excess  propane in the reaction mixture propylene is the predecessor of formaldehyde. On the contrary, at small concentration of propane in the mixture formaldehyde will be derived immediately from propane. The schemes of propane and propylene oxidation  in formaldehyde are offered.

Keywords: catalyst; oxidatio; рhosphates; propane; propylene; formaldehyde.
PREPARATION AND PROPERTIES OF CERAMIC MATERIALS IN THE Ag6PS5I‒Ag7GeS5I SYSTEM
Authors: Malakhovska T.O. , Pogodin A.I. , Filep M.J. , Pop M.M. , Shender I.O. , Kokhan O.P. , Zhukova Yu.P. , Studenyak Ya.I. , Suslikov L.M.
Published: May 2023

This work is devoted to the preparation of dense Ag+ conductive ceramic solid electrolytes in the Ag6PS5I‒Ag7GeS5I system and to the study of their electrical and optical properties. Using the non-destructive and simple method of optical diffuse reflectance spectroscopy, the value of the optical pseudogap energy of the Ag6+x(P1-xGex)S5I (x=0, 0.25, 0.5, 0.75, 1.0) solid solutions was obtained using the Kubelka-Munk function with the application of Tauc's graphic method. As a result of the performed mathematical analysis and graphic processing, it was established that the quaternary chalcohalogenides Ag6PS5I, Ag7GeS5I and solid solutions Ag6+x(P1-xGex)S5I (x=0.25, 0.5, 0.75) belong to direct-band semiconductors characterized by a forbidden optical transition . The study of electrical conductivity of Ag6+x(P1-xGex)S5I solid solutions (x=0, 0.25, 0.5, 0.75, 1.0) was carried out by the method of impedance spectroscopy, in the frequency 1×101–3×105 Hz and temperature 293–383 K ranges. For all ceramic materials prepared on the basis of Ag6+x(P1-xGex)S5I (x=0, 0.25, 0.5, 0.75, 1.0) solid solutions, an increase in the values of total electrical conductivity was observed, which is characteristic of materials with ionic electrical conductivity in the solid state.

Keywords: argyrodites; solid solutions; ceramic; impedance spectroscopy; conductivity; optical properties; optical pseudogap.
EFFECT OFTHE SUBSTITUTION OF Bi→Sb ON THE STRUCTURE CHANGES WITHIN THE AgBi1-xSbxS2 (x = 0 - 1) SOLID SOLUTION
Authors: О.V. О.V. , Marchuk О.V.
Published: May 2023

The work is devoted to study effect of the isovalent substitution on the parameter of structure elements of the crystal structure of the AgBi1-xSbxS2 (x = 0 – 1) solid solution. The limited isostructural phases of the solid solution have a cubic system with space group Fm-3m. The samples of individual composition of the AgBi1-xSbxS2 (x = 0 – 1) solid solution were obtained in quartz vacuumed ampoules in an electric muffle furnace with MP-30 software control of technological processes. The X-ray powder diffractograms that were recorded with using the DRON 4-13 diffractometer have been analyzed using WinCSD software package. The visualization of the crystal structure has been made with VESTA program. It is worth noting that the method of solid phase reactions allows synthesizing sufficiently pure materials, which are suitable for the measure of physical properties. The change of cell parameters within a solid solution is described by a positive deviation from the Vegard’s law. Only all octahedral voids are filled in the structure. It is important to see the prospect of possible alloying by atoms with small atomic radii, which may be localized in tetrahedral voids. The change of volume of the octahedral voids is linear.

Keywords: crystal structure; solid solution; unit cell.
SYNTHESIS AND CHEMICAL PROPERTIES OF 2-HEPTADECYL-[1,3]THIAZOLO[3,2-b][1,2,4]TRIAZOL-7-IUM CATION
Authors: Hryhorka H.V. , Fizer М.М. , Fizer О.І. , Kryvoviaz A.O. , Slivka M.V.
Published: May 2023

Functional and condensed derivatives of 1,2,4-triazoles are mostly used as biologically active compounds, and modern studies increasingly report their successful use as surfactants, stabilizers for the formation of nanoparticles, components of hybrid perovskites, which are promising materials for opto-electronics.

Synthesis of new [1,3]thiazolo[3,2-b][1,2,4]triazol-7-ium salts containing a long-chain heptadecyl substituent was proposed within our research. The production of the starting compounds (2-heptadecyl-4-methyl-1,2,4-triazole-3-thione and methallyl thioether of 2-heptadecyl-3-mercapto-4-methyl-1,2,4-triazole) was carried out according to a modified method annelating of the triazole ring to combined hybrid polyheterocyclic systems and a novel technique for the alkylation of symmetrical triazoles, as a result of which model compounds were obtained in high yields. The method of intramolecular electrophilic heterocyclization was used to quaternize the nitrogen atom of the triazole heterocycle. The study of the chemical properties of the obtained salt [1,3]thiazolo[3,2-b][1,2,4]triazol-7-ium was carried out on the example of anion exchange reactions, the results of which indicate the stability of the studied cation [1,3] thiazolo[3,2-b][1,2,4]triazol-7-ium upon heating in the presence of various anions. The obtained new heterocyclic salts are promising in terms of their further study as surfactants.

Keywords: 1,2,4-triazole; heptadecyl; [1,3]thiazolo[3,2-b][1,2,4]triazol-7-ium salts; surfactant.
TELLURO-INDUCED CYCLISATION 2-(BUT-2-ENYLTHIO)QUINOLINECARBALDEHYDE AND QUINOLINE-4-ONE
Authors: Sabo T. , Kut D. , Kut M. , Onysko M. , Lendel V.
Published: May 2023

Aryltellurium trichlorides have proven themselves as good cyclizing reagents in electrophilic intramolecular cyclization reactions, mainly of propenyl derivatives of heterocycles. On the other hand, information on the use of butenyl derivatives in reactions with p-alkoxyphenyltellurtrichlorides is limited. In this work, the regioselectivity of the process of electrophilic intramolecular cyclization of but-2-enyl thioethers of quinoline-3carbaldehyde and quinazolin-4-one with p-methoxyphenyltellurium trichloride was investigated.

It was established that, as a result of the tellurium-induced cyclization with p-methoxyphenyltellurium trichloride of but-2-enyl thioethers of quinoline and quinazoline, angular tricyclic chlorides – 2-(dichloro(4-methoxyphenyl)-tellanyl)-1-methyl-5-formyl-2,3- dihydro-1H-[1,3]thiazino[3,2-a]quinolin-11-ium and 2-(dichloro(4-methoxyphenyl)-tellanyl)-1-methyl-6-oxo-5-phenyl-2, 3,5,6-tetrahydro-1H-[1,3]thiazino[3,2-a]quinazolin-11-ium, respectively, with an annealed six-membered ring in the form of complexes with p-methoxyphenyltellurium trichloride. Optimal conditions for the electrophilic intramolecular cyclization reaction were selected.

Keywords: electrophilic heterocyclization; p-methoxyphenyltellurium trichloride; organotellurium compounds; chloride 2-(dichloro(4-methoxyphenyl)-tellanyl)-1-methyl-5-formyl-2,3-dihydro-1H-[1,3]thiazino[3,2 -a]quinolin-11-ium, chloride 2-(dichloro(4-methoxyphenyl)-tellanyl)-1-methyl-6-oxo-5-phenyl-2,3,5,6-tetrahydro-1H-[1,3]thiazino[3,2-a]quinazolin-11-ium
SYNTHESIS OF TERMINAL 2-ALKENYL(ALKYNYL)THIO-5-CYANO-6-(p-DIMETHYLAMINOPHENYL)PYRIMIDIN-4-ONES
Authors: Povidaichyk M. , Onysko О. , Onysko M.
Published: May 2023

Functionalized pyrimidines possess a wide spectrum of biological activity. In particular, they have antitumor, antiviral, and anticonvulsant activities, exhibit anti-inflammatory and analgesic effects, and they are inhibitors of aldose reductase, SecA ATPase, azide, and plant growth. The search for methods of synthesis of new functionalized and condensed pyrimidine derivatives is an urgent problem.

Alkenyl-functionalized mono- and polycyclic pyrimidines are promise substrates for studying the regioselectivity of electroph  ilic heterocyclization reactions under the influence of halogen-containing electrophilic agents, and halogen- and chalcogen-functionalized cyclization products showed high antibacterial, antifungal, and antimalarial activity. The introduction of new functional groups capable to modification into such alkenylpyrimidines can significantly affect their reactivity and change/enhance the biological activity of the halocyclization products. We proposed the synthesis of 2-alkenyl(alkynyl)thio derivatives of 5-cyano-6-(p-dimethylaminophenyl)-pyrimidin-4-one containing a cyano group labile to functionalization. As a result of alkylation of 2-thioxo-5-cyano-6-(p-dimethylaminophenyl)pyrimidin-4-one with unsaturated alkyl halides in an alkaline medium, the terminal alkenyl (allyl, methallyl) and alkynyl (propargyl) thioethers of cyanopyrimidine were obtained, promising for heterocyclization with halogen-containing electrophilic reagents .

Keywords: 2-thioxo-5-cyano-pyrimidin-4-one; alkylation; alkenylthiopyrimidinone; alkynylthiopyrimidinone.
THE ROLE OF TEACHING ASSIGNMENTS IN CHEMISTRY IN THE CONTEXT OF PERSONALLY ORIENTED EDUCATIONAL ACTIVITY
Authors: Dzyamko V.M. , Dzyamko Yo. , Stercho I.P. , Batko A.V.
Published: May 2023

Today requires modernization of the education system. The main attention in the state doctrine of education development is focused on the personality, and this requires the implementation of certain changes and even a complete restructuring of classical methodological approaches to raising. In the today's realities conditions, it is necessary to take into account the decreasing of the skills and knowledge level of students on all school subjects, including chemistry. Educational tasks play an important role in the education system. However, in distant learning, the role of each type of educational tasks increases significantly. The method of using educational tasks during the study of chemistry in a secondary school was analyzed, and the disadvantages of traditional methods were revealed. Ways to solve this problem are proposed.

The main criteria and indicators were determined, according to which the pedagogical effectiveness of the designed methodology was checked, including the self-reflection of personal educational achievements. Better academic performance and motivation of the experimental class was established, as the vast majority of students have achieved a high and sufficient level of knowledge quality. The growth of the comfort index and the level of self-assessment of personal educational achievements in the experimental class compared to the control class was shown. It has been demonstrated that such indicators as the ability to self-reflect personal educational achievements, the ability to solve chemistry assignments for students of the experimental class are also higher than in the control class.

Keywords: educational assignments; questions; exercises; problems; chemistry; educational activity.
PEMANFAATAN MEDIA MULTIMEDIA SEBAGAI PENYAMPAIAN INFORMASI JURNALISTIK DI MEDIA ONLINE KUMPARAN
Authors: Prasetyo Adimas Abram Gusti
Published: May 2023

Kebutuhan manusia akan informasi yang tinggi, serta perkembangan teknologi informasi yang terus berkembang, mendorong terbentuknya media baru, yaitu media online yang memanfaatkan internet untuk menyebarkan informasi. Dengan munculnya media baru tersebut mengakibatkan terjadinya pergeseran media lama ke media baru, media online muncul karena penggunaan social media yang semakin banyak digunakan masyarakat. Hal ini dimanfaatkan media online untuk menyebarkan informasi dengan memanfaatkan media sosial, akses internet yang semakin terjangkau oleh siapa saja, juga menjadi faktor pendorong transisi media lama ke media baru ini, bahkan bermunculan media online baru. Kumparan merupakan media baru yang berdiri pada Januari 2017, Kumparan hadir dengan misi yang unggul dalam bercerita. Dengan menggabungkan elemen-elemen multimedia seperti text, graphic, picture, slide shows, dan audio. Elemen multimedia ini dipilih karena dalam mengirimkan informasinya dinilai lebih efektif, dan meminimalisir miskomunikasi dalam menyampaikan informasi. Maka dari itu dalam penelitian ini akan membahas bagaimana pemanfaatan media multimedia ­dalam penyampaian informasi jurnalistik di media online Kumparan. Penelitian ini menggunakan metode analisis kualitatif dengan pendekatan deskriptif.
PENGGUNAAN SITUS BELAJAR ONLINE BRAINLY DALAM MENUNJANG PROSES PEMBELAJARAN DAN PENGERJAAN TUGAS SEKOLAH PADA SISWA SMA BODHISATTVA DI BANDAR LAMPUNG
Authors: Frelisia Anastasia Luliani , Waskito Budhi
Published: May 2023

Terjadinya pandemi covid-19 menyisakan beberapa kebiasaan baru bagi masyarakat salah satunya pada sektor pendidikan. Pembelajaran jarak jauh atau daring yang sempat diberlakukan mengharuskan para pelajar lebih mandiri lagi dalam melakukan proses pembelajaran dan pengerjaan tugas sekolah. Salah satu perilaku yang timbul pada para pelajar ialah melibatkan situs pembelajaran berbasis online atau daring seperti Brainly. Setelah era normal baru diberlakukan dan aktivitas belajar mengajar kembali pada sistem tatap muka, nyatanya kebiasaan penggunaan situs belajar belajar online Brainly dalam menunjang proses pembelajaran dan pengerjaan tugas sekolah tidak dapat langsung ditinggalkan begitu saja. Penelitian ini bertujuan untuk mengetahui secara mendalam penggunaan situs belajar online Brainly.co.id dalam menunjang proses pembelajaran dan pengerjaan tugas sekolah siswa SMA Bodhisattva di Bandar Lampung. Penelitian ini menggunakan metode pendekatan deskriptif kualitatif. Hasil penelitian ini menunjukkan bahwa dalam menggunakan situs belajar online Brainly dalam menunjang proses pembelajaran dan pengerjaan tugas, ada yang melakukan pengecekan ulang sebelum menggunakan informasi yang ada namun ada juga yang langsung menggunakan informasi yang ada tanpa melakukan pemeriksaan ulang meskipun menyadari bahwa informasi yang didapat belum tentu terjamin kredibilitasnya.
HEC-RAS 2B Modeli Kullanılarak Yazılıkaya Deresi (Nallıhan Ankara) Sel Tehlike Haritalarının Hazırlanması ve Sel Kontrol Yapısının Etkinliği
Authors: Akkuş Hüseyin , Yıldız Engin , Bulut İsmail
Published: May 2023

Sel, aşırı yağışlar ve karların hızla erimesi gibi meteorolojik koşulların değişim göstermesi sonucu oluşan doğa kaynaklı afetlerden birisidir. Bölgenin topoğrafyası, jeolojik yapısı, iklim koşulları, akarsu veya derelerin doğal yapılarında meydana gelen bozulmalar ve kontrolsüz kentleşme gibi faktörler sellerin oluşumunda büyük rol oynamaktadır. Bu çalışma kapsamında, Ankara İli Nallıhan İlçesi sınırları içerisinde bulunan ve Yazılıkaya deresinin su toplama havzası sınırları içerinde sel tehlikesine karşı dere içi ıslah çalışmaları yapılmış, 78.8 hektar (Ha) alan içerisinde bir adet harçlı ıslah sekisi projelendirilmesi ve uygulaması gerçekleştirilmiştir. Ankara İli Nallıhan İlçesi Yazılıkaya deresi dere içi ıslah çalışmasında elde edilen veriler (dere haritaları, debileri ve sanat yapısı en kesitleri) ve DSİ Sentetik Yöntemi ile Q10 ve Q100 debi değerleri kullanılarak HEC-RAS (Hydrologic Engineering Centers River Analysis System) programı yardımıyla Yazılıkaya deresinde iki boyutlu sel modellemesi yapılmıştır. Yapılan analizler sonucunda Yazılıkaya deresi üzerinde yapılan harçlı ıslah sekisinin, olası şiddetli ve anlık yağışlarda Q10 ve Q100 debi değerlerinin kullanıldığı analizlerde suyun hızı sırası ile yapısız durumda sırası ile 2 m/s – 3.2 m/s iken yapı yapıldıktan sonra 0.5 m/s – 0.75 m/s değerlerine düştüğü gözlemlenmiştir. Sırasıyla Q10 ve Q100 debi değerlerine göre yapılan yerleşim yerlerindeki su derinliği analizlerinde, harçlı ıslah sekisi yapımı tamamlandıktan sonra 2 cm (Q10) ve 8 cm (Q100) kadar su azalmalarının olduğu hesaplanmıştır. Genel olarak bu çalışmada, yukarı havza sel kontrol yapılarının (harçlı ıslah sekisi) yağış sularının akış rejimlerinin düzenlenmesinde (su enerjisi, hızı, derinliği, vb.), nüfusun yoğunlaştığı yerleşim yerlerinde ve karayolunda sel tehlikesine karşı etkileri araştırılmıştır.
6 Şubat 2023 Kahramanmaraş Depremlerinin Etkilediği İllerdeki Bina Stokunun Özellikleri
Authors: Eroğlu Azak Tuba , Ay Bekir Özer
Published: May 2023

6 Şubat 2023 tarihinde Kahramanmaraş’ın Pazarcık ve Elbistan ilçelerinde yaklaşık 9 saat arayla sırasıyla Mw 7.7 ve Mw 7.6 büyüklüğünde iki deprem meydana gelmiştir. Birbirinden bağımsız meydana gelen iki deprem geniş bir alanda hissedilmiş, deprem merkezinde ve çevre illerde büyük hasara sebep olmuştur. Çok sayıda binanın yıkıldığı ve resmi kayıtlara göre 50 binden fazla can kaybının yaşandığı 6 Şubat 2023 depremlerinin en çok etkilediği şehirler Adana, Adıyaman, Diyarbakır, Gaziantep, Hatay, Kahramanmaraş, Kilis, Malatya, Osmaniye ve Şanlıurfa’dır. Bu çalışmada depremde en çok yıkımın ve büyük can kayıplarının olduğu bu illerdeki bina stoku derlenmiştir. İncelenen bina stoku bina taşıyıcı sistemine, kullanım amacına, kat sayısına ve deprem şartnamesi zaman dilimlerine göre ilçe bazında bir araya getirilmiştir. Depremler sırasında yıkılan, ağır hasar alan ve deprem sonrasında yıkımına karar verilen binalar artık derlenen yapı stoku içerisinde yer almamaktadır. Ancak, meydana gelen depremlere ait birçok kuvvetli yer hareketi istasyonunda kaydedilen yer ivmesi kayıtları ve yaşanan depremler nedeniyle hasar gören binaların bilgisi deprem çalışmaları açısından önemli bir veri seti oluşturmaktadır. Bu bağlamda, deprem öncesi yapı stoku için deprem risk çalışmalarının yapılarak yapı stokunda yer alan bina tiplerine uygun kırılganlık eğrilerinin test edilmesi ve iyileştirilmesi mümkündür. Çalışmada sunulan verilerin deprem risklerinin gerçekçi hesaplanmasında ve bu sayede deprem risklerinin azaltılmasında alınacak önlemler konusunda önemli bir katkı sağlayacağı düşünülmektedir. Bununla beraber, derlenen yapı stoku kullanılarak farklı bölgelerde deprem tehlikesi altındaki benzer yapı stokları için kayıp hesaplarının yapılması da mümkündür.
Arquitectura y urbanismo: nociones desde la sustentabilidad
Authors: Gesto Rodríguez José
Published: May 2023

La arquitectura y el urbanismo sustentable son ramas del quehacer científico que han cobrado auge en los últimos años, orientando su práctica hacia la idealización de construcciones que se traduzcan en la edificación de ambientes saludables diseñados bajo el seguimiento de criterios ecológicos y con un uso eficiente de los recursos. En virtud de ello, existe una creciente necesidad de repensar la importancia de la arquitectura de las ciudades desde la perspectiva del desarrollo sostenible, donde la economía, el bienestar social y la conser- vación ambiental estén articulados sinérgicamente para minimizar la huella y los impactos de las intervenciones humanas en la naturaleza. Mediante una revisión documental, en este artículo se hace una examinación del paradigma de la sustentabilidad dentro de la disciplina arquitectónica y urbanística, así como una breve exposición de las tendencias y desafíos actuales. Se concluye principalmente que la arquitectura y el urbanismo sustentable se enfocan en la reducción de los impactos de los edificios en particular y del hábitat construido en general.
A fresh look at sports PSM-systems
Authors: Savostyanov Vladimir , Kobelev Alexander , Govorin Anton
Published: May 2023

The aim of the proposed study is to reveal the correlations between the dynamics of Respiratory Rate (RR) and Heart Rate (HR) during intermittent physical work at maximum power on a cycle ergometer. The stage of investigating the General functional athlete readiness (GFAR) was conducted using the sports standard “R-Engine” and the cycle ergometer in 16 volunteers (10 men, 6 women) whose average age was 21±1.17 years. To determine the athletic potential of the volunteers in this study, we used our own Coefficient of Anaerobic Capacity (CANAC Q, beats). Continuous registration of the heart rate and respiratory rate of volunteers in the maximum power sports test was performed by the “RheoCardioMonitor” system with a module of the athlete functional readiness based on the method of Transthoracic electrical impedance rheography (TEIRG). The degree of correlation of functional indicators (M, HRM, GFAR) with CANAC Q in all experimental series of the study group as a whole (n=80) was at a very high level, which confirmed the effectiveness of using the Coefficient of Anaerobic Capacity (CANAC Q) in assessing the general functional athlete readiness of the volunteers. CANAC Q is measured in “beats” of the heart and is recorded very accurately using the method of transthoracic electrical impedance rheography (TEIRG). For this reason, as a promising sports PSM-system, CANAC Q can replace the methods for determining the functional athlete readiness by blood lactate concentration and maximum oxygen consumption.
Tradycje i współczesność włoskiej geopolityki
Authors:   Uniwersytet Pedagogiczny w Krakowie, Bielański Stefan
Published: May 2023

The paper presents the traditions of reflection on the functioning of States and Reasons of State, starting from the classics of Political Thought: Niccolò Machiavelli, Francesco Guicciardini and Giovanni Botero, through the creators of Italian Geopolitical Thought in the era of Risorgimento (Carlo Cattaeno, Giacomo Durando) to contemporary reflections on Geopolitics in Italy. Contemporary issues are shown against the background of the most important historical events: Italy of the fascist period and the World War II (1922–1945), as well as the „Cold War” (1945–1989) and the period of transformation in Central and Eastern Europe (1989–1991) and their impact for a new European Geopolitics. In conclusion, it was stated that Italian Geopolitics, having the possibility of referring to various traditions of Italian thought, dating back not only to the 20th century, concerning broadly understood international issues, History, Political Science and Geography, demonstrates the versatility of the undertaken research topics.
Działalność Wojsk Obrony Terytorialnej w Polsce w ramach wspierania systemu bezpieczeństwa lokalnego
Authors: Olszak Marta , Rus Paulina ,   Uniwersytet Pedagogiczny w Krakowie
Published: May 2023

This article aims to present and discuss the activities of the Territorial Defense Forces in Poland. The aim of the authors is to indicate the position of Territorial Defense brigades in local security system. In order to present the situation in the best possible way, the work began with the description of the process of forming the Territorial Defense Forces in Poland. In the next section, the information on the functioning of the local security system in our country has been extended. The article presents the statutory tasks and describes examples of tasks that were performed by soldiers of the Territorial Defense Forces from the beginning of their operation. The authors also describes the cooperation of selected Territorial Defense brigades with other services, inspections and guards. The ending contains the most important conclusions regarding the possibility of using the Territorial Defense Forces, especially as part of supporting the local security system.
Zakat Fitri Diuangkan Analisis Nilai Intrekonektif
Authors: Siregar Dame
Published: May 2023

Based on the existing arguments, zakat fitri can be cashed or local food ingredients. Which is best, which is easy to use, does not make it difficult for the amil, does not harm the devotee and mustahik of zakat. All worship related to food has a choice, namely, freeing the pest, fasting, feeding or clothing. Violating the obligatory pilgrimage to pay hadyu, may be paid with money, the Hajj committee is looking for the animal. The implementation of the Hajj tamattu 'and qiron pays hadyu 1 goat, so that pilgrims are not difficult to find it and pay with money. Pilgrims who are surrounded by headaches have lice, paying hadyu can also be cashed. Hunting halal or haram animals during ihram, pay the amount of the animal being hunted or the price with money. Zakat on various types of trade, then the nisob is calculated all, for 1 haul 354 days, zakat is in the form of money, not every type of sale is issued zakat. Money is a legal medium of exchange, it is easy to carry it, to exchange it. Mustahiq zakat fitri when asked prefers the form of money, even the requester himself prefers alms in the form of money. The phenomenon is that some of the amil, receive zakat fitri in the form of rice, but after buying and selling with worshipers at the mosque. The rice was bought and sold by some of the devotees, finally a lot of money was received. It has not been reviewed yet, the argument for buying and selling at the mosque is whether the rice can be sold by amyl or not. The disadvantage is that all the rice brought by the pemuzkki is expensive, the intermediate is cheap, mixed it all up, in the end it is considered cheap rice.
Faktor-Faktor Pendukung Dan Penghambat Dalam Menghafal Al-Qur’an
Authors: Simanjuntak Dahliati
Published: May 2023

In this life, there is no achievement without trials and tribulations. With these tests and trials will be found and determined who wins and who loses. Similarly, in memorizing the Qur'an, it becomes a necessity that there are tests and trials that will distinguish the achievements of one person from another and determine the final results achieved by each of them. The problems of students in memorizing can be distinguished into problems that come from within (internal) and problems that come from outside (external). Internal problems in the form of many disobediences, feeling lazy, impatient, hopeless, memorized verses forgetting again, difficulty managing time, physical and spiritual fatigue. Meanwhile, external problems are related to the relationship between students and the physical and social environment. The physical environment of the pesantren such as room conditions, lighting, air circulation and cleanliness. While the social environment such as relationships  with  friends,  parents,  teachers  and  caregivers.  Problems  that  can  often hinder someone from memorizing the Qur'an include problems that come from within (internal factors) and problems that come from outside (external factors).
Pembacaan Wahbah Az-Zuhaili Terhadap Term Mubazir Dalam Kitab al-Tafsir al-Munir
Authors: Enghariano Desri Ari
Published: May 2023

Islam does not forbid its adherents to enjoy the life of the world. They are allowed and given the freedom to enjoy all the sustenance that Allah has given them. However, the behavior in expressing pleasure should not cross the predetermined line, such as excessive, extravagant and wasteful. But, the reality of the living habits of Indonesian Muslims shows that there are still many who commit wasteful acts, especially in the matter of food. Food that is not spent becomes wasted and wasted, resulting in a very large amount of waste, even up to hundreds of trillions of rupiah per year.Based on the reality of the wasteful behavior of Indonesian Muslims, the author is interested in researching this issue by describing Wahbah Az-Zuhaili's reading of wasteful terms in the book of al-Tafsir al-Munir. This research includes the description of Wahbah Az-Zuhaili regarding the meaning of the word wasteful, the causes of wasteful attitudes, threats to wasteful perpetrators, and solutions to eliminate wasteful attitudes. Thematic method is the choice in completing this research. The results of this research explain that the meaning of redundant is to manage and spend wealth or money not in the right place and not wise in its use. The cause of the emergence of wasteful behavior is not caring about religious teachings and following their lusts. The threat to the wasteful perpetrator is that he will become a brother of Satan and become a disbelief in Allah. The solution to eliminating wasteful nature is to be moderate in the use of wealth, not to distribute wealth in immoral cases, and to distribute wealth to people in need.