bluuebunny/crossref_metadata_2025 huggingface dataset:
Gel Polymer Electrolytes Based on Silica-Added Poly(ethylene oxide) Electrospun Membranes for Lithium Batteries
Authors: Navarra Maria , Lombardo Lucia , Bruni Pantaleone , Morelli Leonardo , Tsurumaki Akiko , Panero Stefania , Croce Fausto
Published: December 2018

Solid polymer electrolytes, in the form of membranes, offering high chemical and mechanical stability, while maintaining good ionic conductivity, are envisaged as a possible solution to improve performances and safety in different lithium cell configurations. In this work, we designed and prepared systems formed using innovative nanocomposite polymer membranes, based on high molecular weight poly(ethylene oxide) (PEO) and silica nanopowders, produced by the electrospinning technique. These membranes were subsequently gelled with solutions based on aprotic ionic liquid, carbonate solvents, and lithium salt. The addition of polysulfide species to the electrolyte solution was also considered, in view of potential applications in lithium-sulfur cells. The morphology of the electrospun pristine membranes was evaluated using scanning electron microscopy. Stability and thermal properties of pristine and gelled systems were investigated uisng differential scanning calorimetry and thermal gravimetric analysis. Electrochemical impedance spectroscopy was used to determine the conductivity of both swelling solutions and gelled membranes, allowing insight into the ion transport mechanism within the proposed composite electrolytes.
Resistance of Thermally Aged DSS 2304 against Localized Corrosion Attack
Authors: Zanotto Federica , Grassi Vincenzo , Balbo Andrea , Monticelli Cecilia , Zucchi Fabrizio
Published: December 2018

In this paper, the effects of thermal aging in the 650–850 °C range on the localized corrosion behaviour of duplex stainless steel (DSS) 2304 was investigated. Pitting corrosion resistance was assessed by pitting potential (Epitt) and critical pitting temperature (CPT) determination, while the degree of sensitisation (DOS) to intergranular corrosion (IGC) was evaluated by double loop electrochemical potentiokinetic reactivation (DL-EPR). The susceptibility to stress corrosion cracking (SCC), evaluated in standard NACE TM-0177 solution at pH 2.7 and 25 °C, with the addition of S2O32− at 10−3 M, resulted in general good agreement with pitting and IGC behaviour. In fact, as-received DSS 2304 aged for 5 min at 650 °C or 750 °C presented a high resistance to localized corrosion. The alloy corrosion behaviour was severely impaired with an aging time of 60 min at 650 °C and of 10 or 60 min at 750 °C, due to the precipitation of finely distributed M23C6-type chromium carbides at ferrite/austenite interphases, which determined the formation of chromium and molybdenum depleted areas. The behaviour of samples aged at 850 °C also depended on the aging time, but, at 60 min, the rediffusion of passivating elements produced a recovery of the alloy resistance to pitting, IGC and SCC.
Fabrication and Characteristics of SnAgCu Alloy Nanowires for Electrical Connection Application
Authors: Chen Jung-Hsuan , Lo Shen-Chuan , Hsu Shu-Chi , Hsu Chun-Yao
Published: December 2018

As electronic products become more functional, the devices are required to provide better performances and meet ever smaller form factor requirements. To achieve a higher I/O density within the smallest form factor package, applying nanotechniques to electronic packaging can be regarded as a possible approach in microelectronic technology. Sn-3.0 wt% Ag-0.5 wt% Cu (SAC305) is a common solder material of electrical connections in microelectronic devices. In this study, SAC305 alloy nanowire was fabricated in a porous alumina membrane with a pore diameter of 50 nm by the pressure casting method. The crystal structure and composition analyses of SAC305 nanowires show that the main structure of the nanowire is β-Sn, and the intermetallic compound, Ag3Sn, locates randomly but always appears on the top of the nanowire. Furthermore, differential scanning calorimetry (DSC) results indicate the melting point of SAC305 alloy nanowire is around 227.7 °C. The melting point of SAC305 alloy nanowire is significantly higher than that of SAC305 bulk alloy (219.4 °C). It is supposed that the non-uniform phase distribution and composite difference between the nanowires causes the change of melting temperature.
A Kinetic Approach of DPPH Free Radical Assay of Ferulate-Based Protic Ionic Liquids (PILs)
Authors: Ahmad Nur Afiqah , Jumbri Khairulazhar , Ramli Anita , Abd Ghani Noraini , Ahmad Haslina , Lim Jun Wei
Published: December 2018

The antiradical efficiency (AE) and kinetic behavior of a new ferulate-based protic ionic liquids (PILs) were described using 2,2-diphenyl-1-picrylhydrazyl (DPPH) free radical assay. The reduction of the DPPH free radical (DPPH•) was investigated by measuring the decrease in absorbance at 517 nm. The time to reach steady state for the reaction of parent acid (ferulic acid) and synthesized PILs with DPPH• was continuously recorded for 1 h. Results revealed that the AE of 2-butylaminoethanol ferulate (2BAEF), 3-dimethylaminopropanol ferulate (3DMAPF) and 3-diethylaminopropanol ferulate (3DEAPF) PILs have improved compared to ferulic acid (FA) as the reaction class changes from low to medium. This attributed to the strong hydrogen abstraction occurred in the PILs. Furthermore, these PILs were found to have a good kinetic behavior compared to FA due to the high rate constant (k2) (164.17, 242.84 and 244.73 M−1 s−1, respectively). The alkyl chain length and more alkyl substituents on the nitrogen atom of cation were believed to reduce the cation-anion interaction and speed up the hydrogen atom transfer (HAT) and electron transfer (ET) mechanisms; hence, increased rate constant was observed leading to a strong antioxidant activity of the synthesized PILs.
Comparative Reduction of Egg Yolk Cholesterol Using Anionic Chelating Agents
Authors: Bautista Villarreal Minerva , Gallardo Rivera Claudia T. , García Márquez Eristeo , Rodríguez Rodríguez José , Núñez González María Adriana , Chávez Montes Abelardo , Báez González Juan G.
Published: December 2018

Egg yolk is used as an emulsifying agent. Nevertheless, its high concentration of cholesterol is linked to chronic degenerative diseases that cause cardiovascular disease. In this study, three methods for reducing the level of cholesterol in egg yolks were studied. The first method consisted of physical separation of the granules contained in the yolk (NaG). The second method applied was the use of anionic chelating biopolymers, such as arabic gum solution (AG) and mesquite gum solution (MG), and the third method was extraction with a solvent (SA). For this purpose, the cholesterol present in egg yolks, the microstructure, particle size, zeta potential, and its emulsifying capacity were determined. The amount of cholesterol removed was 97.24% using 1% mesquite gum (MG1%), and 93.26% using 1% Arabic gum (AG1%). The zeta potential was determined, and the isoelectric point (ζ = 0) of egg yolk was identified as pH 4.6. While, at this pH, the zeta potential of mesquite gum was −14.8 mV, the zeta potential for the arabic gum was −16 mV. The emulsifying capacity of MG1% was 62.95%, while the emulsifying capacity of AG1% was 63.57%. The complex obtained can be used in the development of functional foods reduced in cholesterol.
SugarSketcher: Quick and Intuitive Online Glycan Drawing
Authors: Alocci Davide , Suchánková Pavla , Costa Renaud , Hory Nicolas , Mariethoz Julien , Vařeková Radka Svobodová , Toukach Philip , Lisacek Frédérique
Published: December 2018

SugarSketcher is an intuitive and fast JavaScript interface module for online drawing of glycan structures in the popular Symbol Nomenclature for Glycans (SNFG) notation and exporting them to various commonly used formats encoding carbohydrate sequences (e.g., GlycoCT) or quality images (e.g., svg). It does not require a backend server or any specific browser plugins and can be integrated in any web glycoinformatics project. SugarSketcher allows drawing glycans both for glycobiologists and non-expert users. The “quick mode” allows a newcomer to build up a glycan structure having only a limited knowledge in carbohydrate chemistry. The “normal mode” integrates advanced options which enable glycobiologists to tailor complex carbohydrate structures. The source code is freely available on GitHub and glycoinformaticians are encouraged to participate in the development process while users are invited to test a prototype available on the ExPASY web-site and send feedback.
Quantification of VOC Emissions from Carbonized Refuse-Derived Fuel Using Solid-Phase Microextraction and Gas Chromatography-Mass Spectrometry
Authors: Białowiec Andrzej , Micuda Monika , Szumny Antoni , Łyczko Jacek , Koziel Jacek A.
Published: December 2018

In this work, for the first time, the volatile organic compound (VOC) emissions from carbonized refuse-derived fuel (CRDF) were quantified on a laboratory scale. The analyzed CRDF was generated from the torrefaction of municipal waste. Headspace solid-phase microextraction (SPME) and gas chromatography-mass spectrometry (GC-MS) was used to identify 84 VOCs, including many that are toxic, e.g., derivatives of benzene or toluene. The highest emissions were measured for nonanal, octanal, and heptanal. The top 10 most emitted VOCs contributed to almost 65% of the total emissions. The VOC mixture emitted from torrefied CRDF differed from that emitted by other types of pyrolyzed biochars, produced from different types of feedstock, and under different pyrolysis conditions. SPME was a useful technology for surveying VOC emissions. Results provide an initial database of the types and relative quantities of VOCs emitted from CRDF. This data is needed for further development of CRDF technology and comprehensive assessment of environmental impact and practical storage, transport, and potential adoption of CRDF as means of energy and resource recovery from municipal waste.
Measurements of Microstructural, Chemical, Optical, and Electrical Properties of Silicon-Oxygen-Nitrogen Films Prepared by Plasma-Enhanced Atomic Layer Deposition
Authors: Ma Hong-Ping , Lu Hong-Liang , Yang Jia-He , Li Xiao-Xi , Wang Tao , Huang Wei , Yuan Guang-Jie , Komarov Fadei F. , Zhang David Wei
Published: December 2018

In this study, silicon nitride (SiNx) thin films with different oxygen concentration (i.e., SiON film) were precisely deposited by plasma enhanced atomic layer deposition on Si (100) substrates. Thus, the effect of oxygen concentration on film properties is able to be comparatively studied and various valuable results are obtained. In detail, x-ray reflectivity, x-ray photoelectron spectroscopy, atomic force microscopy, and spectroscopic ellipsometry are used to systematically characterize the microstructural, optical, and electrical properties of SiON film. The experimental results indicate that the surface roughness increases from 0.13 to 0.2 nm as the oxygen concentration decreases. The refractive index of the SiON film reveals an increase from 1.55 to 1.86 with decreasing oxygen concentration. Accordingly, the band-gap energy of these films determined by oxygen 1s-peak analysis decreases from 6.2 to 4.8 eV. Moreover, the I-V tests demonstrate that the film exhibits lower leakage current and better insulation for higher oxygen concentration in film. These results indicate that oxygen affects microstructural, optical, and electrical properties of the prepared SiNx film.
Effects of Protonation, Hydroxylamination, and Hydrazination of g-C3N4 on the Performance of Matrimid®/g-C3N4 Membranes
Authors: Soto-Herranz María , Sánchez-Báscones Mercedes , Hérnandez-Giménez Antonio , Calvo-Díez José I. , Martín-Gil Jesús , Martín-Ramos Pablo
Published: December 2018

One of the challenges to continue improving polymeric membranes properties involves the development of novel chemically modified fillers, such as nitrogen-rich 2-D nanomaterials. Graphitic carbon nitride (g-C3N4) has attracted significant interest as a new class of these fillers. Protonation is known to afford it desirable functionalities to form unique architectures for various applications. In the work presented herein, doping of Matrimid® with protonated g-C3N4 to yield Matrimid®/g-C3N4 mixed matrix membranes was found to improve gas separation by enhancing the selectivity for CO2/CH4 by up to 36.9% at 0.5 wt % filler doping. With a view to further enhancing the contribution of g-C3N4 to the performance of the composite membrane, oxygen plasma and hydrazine monohydrate treatments were also assayed as alternatives to protonation. Hydroxylamination by oxygen plasma treatment increased the selectivity for CO2/CH4 by up to 52.2% (at 2 wt % doping) and that for O2/N2 by up to 26.3% (at 0.5 wt % doping). Hydrazination led to lower enhancements in CO2/CH4 separation, by up to 11.4%. This study suggests that chemically-modified g-C3N4 may hold promise as an additive for modifying the surface of Matrimid® and other membranes.
Clostridium butyricum MIYAIRI 588 Increases the Lifespan and Multiple-Stress Resistance of Caenorhabditis elegans
Authors: Kato Maiko , Hamazaki Yumi , Sun Simo , Nishikawa Yoshikazu , Kage-Nakadai Eriko
Published: December 2018

Clostridium butyricum MIYAIRI 588 (CBM 588), one of the probiotic bacterial strains used for humans and domestic animals, has been reported to exert a variety of beneficial health effects. The effect of this probiotic on lifespan, however, is unknown. In the present study, we investigated the effect of CBM 588 on lifespan and multiple-stress resistance using Caenorhabditis elegans as a model animal. When adult C. elegans were fed a standard diet of Escherichia coli OP50 or CBM 588, the lifespan of the animals fed CBM 588 was significantly longer than that of animals fed OP50. In addition, the animals fed CBM588 exhibited higher locomotion at every age tested. Moreover, the worms fed CBM 588 were more resistant to certain stressors, including infections with pathogenic bacteria, UV irradiation, and the metal stressor Cu2+. CBM 588 failed to extend the lifespan of the daf-2/insulin-like receptor, daf-16/FOXO and skn-1/Nrf2 mutants. In conclusion, CBM 588 extends the lifespan of C. elegans probably through regulation of the insulin/IGF-1 signaling (IIS) pathway and the Nrf2 transcription factor, and CBM 588 improves resistance to several stressors in C. elegans.
Water Intake, Water Balance, and the Elusive Daily Water Requirement
Authors: Armstrong Lawrence E. , Johnson Evan C.
Published: December 2018

Water is essential for metabolism, substrate transport across membranes, cellular homeostasis, temperature regulation, and circulatory function. Although nutritional and physiological research teams and professional organizations have described the daily total water intakes (TWI, L/24h) and Adequate Intakes (AI) of children, women, and men, there is no widespread consensus regarding the human water requirements of different demographic groups. These requirements remain undefined because of the dynamic complexity inherent in the human water regulatory network, which involves the central nervous system and several organ systems, as well as large inter-individual differences. The present review analyzes published evidence that is relevant to these issues and presents a novel approach to assessing the daily water requirements of individuals in all sex and life-stage groups, as an alternative to AI values based on survey data. This empirical method focuses on the intensity of a specific neuroendocrine response (e.g., plasma arginine vasopressin (AVP) concentration) employed by the brain to regulate total body water volume and concentration. We consider this autonomically-controlled neuroendocrine response to be an inherent hydration biomarker and one means by which the brain maintains good health and optimal function. We also propose that this individualized method defines the elusive state of euhydration (i.e., water balance) and distinguishes it from hypohydration. Using plasma AVP concentration to analyze multiple published data sets that included both men and women, we determined that a mild neuroendocrine defense of body water commences when TWI is ˂1.8 L/24h, that 19–71% of adults in various countries consume less than this TWI each day, and consuming less than the 24-h water AI may influence the risk of dysfunctional metabolism and chronic diseases.
Larger Food Portion Sizes Are Associated with Both Positive and Negative Markers of Dietary Quality in Irish Adults
Authors: Lyons Jacqueline , Walton Janette , Flynn Albert
Published: December 2018

Reduction in portion size, particularly for energy-dense foods, is increasingly addressed in healthy eating guidelines in a bid to tackle the obesity epidemic. The effect of portion size on other aspects of dietary quality, such as nutrient intakes, is less studied. The aim of the current work was to investigate associations between food portion sizes and key indicators of dietary quality, namely energy-adjusted intakes of saturated fat, dietary fibre, sodium, calcium, iron, folate and vitamin D, and dietary energy density (DED), in Irish adults on the days the foods were consumed. Data from the Irish National Adult Nutrition Survey (2008–2010) (n = 1274, 18–64 years, 4-day semi-weighed record) were used for the analysis. DED was lower on the days larger portions of boiled potatoes, fruit, vegetables and baked beans were consumed, and higher on the days larger portions of white bread, ready-to-eat breakfast cereals (RTEBCs), frying meats, cheese, butter, biscuits, chocolate and sugar-sweetened beverages were consumed. Micronutrient intakes were higher on the days larger portions of brown bread, RTEBCs, vegetables and low-fat spreads were consumed, and lower on the days larger portions of white bread, butter, biscuits, chocolate, sugar-sweetened beverages and beer/cider were consumed, with the exception of folate. The study identifies foods for which larger portion sizes may be associated with positive dietary attributes, as well as the opposite. It provides an important evidence base from which more specific dietary guidance on food portion sizes might be developed for Irish adults.
Calcium Intake in Bone Health: A Focus on Calcium-Rich Mineral Waters
Authors: Vannucci Letizia , Fossi Caterina , Quattrini Sara , Guasti Leonardo , Pampaloni Barbara , Gronchi Giorgio , Giusti Francesca , Romagnoli Cecilia , Cianferotti Luisella , Marcucci Gemma , Brandi Maria Luisa
Published: December 2018

Calcium is an essential element that plays numerous biological functions in the human body, of which one of the most important is skeleton mineralization. Bone is a mineralized connective tissue in which calcium represents the major component, conferring bone strength and structure. Proper dietary calcium intake is important for bone development and metabolism, and its requirement can vary throughout life. The mineral composition of drinking water is becoming relevant in the modulation of calcium homeostasis. In fact, calcium present in mineral drinking waters is an important quantitative source of calcium intake. This, together with its excellent bioavailability, contributes to the maintenance of the bone health. This article aims to examine studies that assessed the bioavailability of the calcium contained in calcium-rich mineral waters and their impact on bone health, including original data collected in a recent study in humans.
Lisosan G Protects the Retina from Neurovascular Damage in Experimental Diabetic Retinopathy
Authors: Amato Rosario , Rossino Maria Grazia , Cammalleri Maurizio , Locri Filippo , Pucci Laura , Dal Monte Massimo , Casini Giovanni
Published: December 2018

Lisosan G (LG), a fermented powder obtained from whole grains, is a recognized antioxidant compound that improves the bioactivity and survival of different cell types. The purpose of this study was to investigate whether LG ameliorates both the neural and the vascular damage characterizing early stages of diabetic retinopathy (DR). The effects of LG were studied in cultured explants of mouse retinas challenged with oxidative stress (OS) or in retinas of streptozotocin (STZ)-treated rats. Apoptosis, vascular endothelial growth factor (VEGF) expression, OS markers, blood-retinal barrier (BRB) integrity, and inflammation were assessed, while retinal function was evaluated with electroretinogram (ERG). LG extensively inhibited apoptosis, VEGF expression, and OS both in retinal explants and in STZ rats. In addition, STZ rats treated with LG displayed an almost total BRB integrity, reduced levels of inflammatory markers and a partially restored visual function as evaluated with ERG. In summary, we demonstrated that LG exhibits antioxidant and anti-inflammatory effects that exert powerful protective actions against neural and vascular defects characteristic of DR. Therefore, LG-containing foods or supplements may be considered to implement DR treatments.
Biodistribution of a Radiolabeled Antibody in Mice as an Approach to Evaluating Antibody Pharmacokinetics
Authors: Allen Kevin J. H. , Jiao Rubin , Malo Mackenzie E. , Frank Connor , Dadachova Ekaterina
Published: December 2018

(1) Background: Monoclonal antibodies are used in the treatment of multiple conditions including cancer, autoimmune disorders, and infectious diseases. One of the initial steps in the selection of an antibody candidate for further pre-clinical development is determining its pharmacokinetics in small animal models. The use of mass spectrometry and other techniques to determine the fate of these antibodies is laborious and expensive. Here we describe a straightforward and highly reproducible methodology for utilizing radiolabeled antibodies for pharmacokinetics studies. (2) Methods: Commercially available bifunctional linker CHXA” and 111Indium radionuclide were used. A melanin-specific chimeric antibody A1 and an isotype matching irrelevant control A2 were conjugated with the CHXA”, and then radiolabeled with 111In. The biodistribution was performed at 4 and 24 h time points in melanoma tumor-bearing and healthy C57BL/6 female mice. (3) The biodistribution of the melanin-binding antibody showed the significant uptake in the tumor, which increased with time, and very low uptake in healthy melanin-containing tissues such as the retina of the eye and melanized skin. This biodistribution pattern in healthy tissues was very close to that of the isotype matching control antibody. (4) Conclusions: The biodistribution experiment allows us to assess the pharmacokinetics of both antibodies side by side and to make a conclusion regarding the suitability of specific antibodies for further development.
Super-Oscillatory Metalens at Terahertz for Enhanced Focusing with Reduced Side Lobes
Authors: Legaria Santiago , Pacheco-Peña Victor , Beruete Miguel
Published: December 2018

In this paper, we design and numerically demonstrate an ultra-thin super-oscillatory metalens with a resolution below the diffraction limit. The zones of the lens are implemented using metasurface concepts with hexagonal unit cells. This way, the transparency and, hence, efficiency is optimized, compared to the conventional transparent–opaque zoning approach that introduces, inevitably, a high reflection in the opaque regions. Furthermore, a novel two-step optimization technique, based on evolutionary algorithms, is developed to reduce the side lobes and boost the intensity at the focus. After the design process, we demonstrate that the metalens is able to generate a focal spot of 0.46λ0 (1.4 times below the resolution limit) at the design focal length of 10λ0 with reduced side lobes (the side lobe level being approximately −11 dB). The metalens is optimized at 0.327 THz, and has been validated with numerical simulations.
Effect of Aging on Chemical and Rheological Properties of Bitumen
Authors: Yang Zhen , Zhang Xiaoning , Zhang Zeyu , Zou Bingjie , Zhu Zihan , Lu Guoyang , Xu Wei , Yu Jiangmiao , Yu Huayang
Published: December 2018

Engineering performance of asphalt pavement highly depends on the properties of bitumen, the bonding material to glue aggregates and fillers together. During the service period, bitumen is exposed to sunlight, oxygen and vehicle loading which in turn leads to aging and degradation. A comprehensive understanding of the aging mechanism of bitumen is of critical importance to enhance the durability of asphalt pavement. This study aims to determine the relations between micro-mechanics, chemical composition, and macro-mechanical behavior of aged bitumen. To this end, the effect of aging on micro-mechanics, chemical functional groups, and rheological properties of bitumen were evaluated by atomic force microscope, Fourier transform infrared spectroscopy and dynamic shear rheometer tests, respectively. Results indicated that aging obviously increased the micro-surface roughness of bitumen. A more discrete distribution of micromechanics on bitumen micro-surface was noticed and its elastic behavior became more significant. Aging also resulted in raised content of carbonyl, sulfoxide, and aromatic ring functional groups. In terms of rheological behavior, the storage modulus of bitumen apparently increased after aging due to the transformation of viscous fractions to elastic fractions, making it stiffer and less viscous. By correlation analysis, it is noted that the bitumen rheological behavior was closely related to its micro-mechanics.
Molecular Simulation on the Thermal Stability of Meta-Aramid Insulation Paper Fiber at Transformer Operating Temperature
Authors: Tang Chao , Li Xu , Li Zhiwei , Tian Wenxin , Zhou Qu
Published: December 2018

The influence of the thermal field of a transformer during operation on the thermal stability of meta-aramid insulation paper was studied through molecular dynamics simulations. Models of the crystalline and amorphous regions of meta-aramid fibers were constructed using known parameters. The model of the crystalline area was verified by comparing X-ray diffraction results with experimental data. The reasonableness of the simulation results was judged by the variation of energy, temperature, density, and cell size in relation to the dynamic time. The molecular dynamics simulations revealed that the modulus values in the crystalline regions were two to three times higher than those in the amorphous regions at various temperatures. In addition, the incompressibility, rigidity, deformation resistance, plasticity, and toughness of the crystalline regions were obviously higher than those of amorphous regions, whereas the toughness of the amorphous regions was better than that of the crystalline regions. The mechanical parameters of both the crystalline and amorphous regions of meta-aramid fibers were affected by temperature, although the amorphous regions were more sensitive to temperature than the crystalline regions. The molecular chain motion in the crystalline regions of meta-aramid fibers increased slightly with temperature, whereas that of the amorphous regions was more sensitive to temperature. Analyzing hydrogen bonding revealed that long-term operation at high temperature may destroy the structure of the crystalline regions of meta-aramid fibers, degrading the performance of meta-aramid insulation paper. Therefore, increasing the crystallinity and lowering the transformer operating temperature may improve the thermal stability of meta-aramid insulation paper. However, it should be noted that increasing the crystallinity of insulation paper may lower its toughness. These study results lay a good foundation for further exploration of the ways to improve the performance of meta-aramid insulation paper.
Improved Energy Storage Performance of Linear Dielectric Polymer Nanodielectrics with Polydopamine coated BN Nanosheets
Authors: Wang Jian , Xie Yunchuan , Liu Jingjing , Zhang Zhicheng , Zhuang Qiang , Kong Jie
Published: December 2018

Polymer-based nanodielectrics have been intensively investigated for their potential application as energy storage capacitors. However, their relatively low energy density (Ue) and discharging efficiency (η) may greatly limit their practical usage. In present work, high insulating two-dimensional boron nitride nanosheets (BNNS), were introduced into a linear dielectric polymer (P(VDF-TrFE-CTFE)-g-PMMA) matrix to enhance the energy storage performance of the composite. Thanks to the surface coating of polydopamine (PDA) on BN nanosheets, the composite filled with 6 wt% coated BNNS (mBNNS) exhibits significantly improved breakdown strength (Eb) of 540 MV/m and an energy density (Ue) of 11 J/cm3, which are increased by 23% and 100%, respectively as compared with the composite filled with the same content of pristine BNNS. Meanwhile, η of both composites is well retained at around 70% even under a high voltage of 400 MV/m, which is superior to most of the reported composites. This work suggests that complexing polymer matrix with linear dielectric properties with surface coated BNNS fillers with high insulating 2D structure might be a facile strategy to achieve composite dielectrics with simultaneously high energy density and high discharging efficiency.
Hyperspectral Mixed Denoising via Spectral Difference-Induced Total Variation and Low-Rank Approximation
Authors: Sun Le , Zhan Tianming , Wu Zebin , Xiao Liang , Jeon Byeungwoo
Published: December 2018

Exploration of multiple priors on observed signals has been demonstrated to be one of the effective ways for recovering underlying signals. In this paper, a new spectral difference-induced total variation and low-rank approximation (termed SDTVLA) method is proposed for hyperspectral mixed denoising. Spectral difference transform, which projects data into spectral difference space (SDS), has been proven to be powerful at changing the structures of noises (especially for sparse noise with a specific pattern, e.g., stripes or dead lines present at the same position in a series of bands) in an original hyperspectral image (HSI), thus allowing low-rank techniques to get rid of mixed noises more efficiently without treating them as low-rank features. In addition, because the neighboring pixels are highly correlated and the spectra of homogeneous objects in a hyperspectral scene are always in the same low-dimensional manifold, we are inspired to combine total variation and the nuclear norm to simultaneously exploit the local piecewise smoothness and global low rankness in SDS for mixed noise reduction of HSI. Finally, the alternating direction methods of multipliers (ADMM) is employed to effectively solve the SDTVLA model. Extensive experiments on three simulated and two real HSI datasets demonstrate that, in terms of quantitative metrics (i.e., the mean peak signal-to-noise ratio (MPSNR), the mean structural similarity index (MSSIM) and the mean spectral angle (MSA)), the proposed SDTVLA method is, on average, 1.5 dB higher MPSNR values than the competitive methods as well as performing better in terms of visual effect.
Precision Downward-Looking 3D Synthetic Aperture Radar Imaging with Sparse Linear Array and Platform Motion Parameters Estimation
Authors: Liu Qiyong , Luo Ying , Zhang Qun , Hong Wen , Yeo Tat Soon
Published: December 2018

The downward-looking sparse linear array three-dimensional synthetic aperture radar (DLSLA 3D SAR) has attracted a great deal of attention, due to the ability to obtain three-dimensional (3D) images. However, if the velocity and the yaw rate of the platform are not measured with enough accuracy, the azimuth signal cannot be compressed and then the 3D image of the scene cannot be obtained. In this paper, we propose a method for platform motion parameter estimation, and downward-looking 3D SAR imaging. A DLSLA 3D SAR imaging model including yaw rate was established. We then calculated the Doppler frequency modulation, which is related to the cross-track coordinates rather than the azimuth coordinates. Thus, the cross-track signal reconstruction was realized. Furthermore, based on the minimum entropy criterion (MEC), the velocity and yaw rate of the platform were accurately estimated, and the azimuth signal compression was also realized. Moreover, a deformation correction procedure was designed to improve the quality of the image. Simulation results were given to demonstrate the validity of the proposed method.
Core Temperature Responses in Elite Cricket Players during Australian Summer Conditions
Authors: Stay Sharon , Cort Michelle , Ward David , Kountouris Alex , Orchard John , Holland Justin , Saw Anna
Published: December 2018

This study aimed to observe core temperature responses in elite cricket players under match conditions during the summer in Australia. Thirty-eight Australian male cricketers ingested capsule temperature sensors during six four-day first-class matches between February 2016 and March 2017. Core temperature (Tc) was recorded during breaks in play. Batters showed an increase in Tc related to time spent batting of approximately 1 °C per two hours of play (p < 0.001). Increases in rate of perceived exertion (RPE) in batters correlated with smaller elevations in Tc (0.2 °C per one unit of elevation in RPE) (p < 0.001). Significant, but clinically trivial, increases in Tc of batters were found related to the day of play, wet bulb globe temperature (WBGT), air temperature, and humidity. A trivial increase in Tc (p < 0.001) was associated with time in the field and RPE when fielding. There was no association between Tc and WBGT, air temperature, humidity, or day of play in fielders. This study demonstrates that batters have greater rises in Tc than other cricket participants, and may have an increased risk of exertional heat illness, despite exposure to similar environmental conditions.
Evaluation of Efficiency in Selected Areas of Public Services in European Union Countries
Authors: Halaskova Martina , Halaskova Renata , Prokop Viktor
Published: December 2018

Over the past 40 years, the service sector has become the dominant area of market economies. The public sector and services financed from public financing represent a specific group within the services sector. This paper aims to evaluate the efficiency of EU countries and find the extent to which the volume of public services (and the respective financial allocations) can have an impact on selected economic indicators. To this end, the efficiency of public expenditure in five areas of public services (general public services; health; education; social protection; and recreation, culture, and religion) in 2009 and 2016 was evaluated in relation to selected economic indicators (GDP per capita and employment in services). In addition, the efficiency of public expenditure in EU countries was evaluated in relation to the size of the public sector and traditions of public administration. For cross-country analyses within the 27 European countries, data envelopment analysis and the input-oriented variable returns to scale (VRS) model were applied. The results demonstrated that in 2009, 13 out of 27 countries were efficient as opposed to 2016, where only seven countries were efficient. In countries with bigger size of public sector, the efficiency of public expenditure on services was not established. However, there was a similarity in the efficiency of public expenditure on services between groups of EU countries regarding the tradition of public administration.
Spatial Assessment of Degraded Lands for Biofuel Production in Indonesia
Authors: Jaung Wanggi , Wiraguna Edi , Okarda Beni , Artati Yustina , Goh Chun Sheng , Syahru Ramdhoni , Leksono Budi , Prasetyo Lilik Budi , Lee Soo Min , Baral Himlal
Published: December 2018

This study spatially estimated degraded lands in Indonesia that have limited functions for food production, carbon storage, and conservation of biodiversity and native vegetation and examined their suitability to grow biodiesel species (Calophyllum inophyllum, Pongamia pinnata, and Reutealis trisperma) and biomass species (Calliandra calothyrsus and Gliricidia sepium). Results showed ~3.5 million ha of degraded lands potentially suitable for these species in Indonesia. With the all-five-species scenario, these lands had the potential to produce 1105 PJ year−1 of biomass and 3 PJ year−1 of biodiesel. With the biodiesel-only-species scenario, these lands showed the potential to produce 10 PJ year−1 of biodiesel. Despite this energy potential, however, the land sizes were too small to support economies of scale for biofuel production. The study findings contribute to identifying lands with limited functions, modeling the growth of biofuel species on regional lands, and estimating carbon stocks of restored degraded lands in Indonesia.
Environmental Impact Associated with the Supply Chain and Production of Grounding and Roasting Coffee through Life Cycle Analysis
Authors: Giraldi-Díaz Mario R. , De Medina-Salas Lorena , Castillo-González Eduardo , León-Lira Rosario
Published: December 2018

Coffee is the beverage resulting from the infusion of roasted and ground seeds of the coffee fruit. It is one of the most commercialized products in the world and represents a high interest agro-industrial product in Mexico. The demand for this product has grown in great measure in the last decade, thus it is becoming more important to make environmental and energetic evaluations of its manufacturing process. In this sense, life cycle assessment (LCA) is a useful tool for the purposes of this study, as it quantifies the wake of environmental impacts associated to the production and supply chain from its inputs and outputs of the product system. Therefore, the impact categories studied were carbon, energetic, and water footprints. The cultivation phase led to global contributions between 61% and 67% in magnitude for energy and carbon footprints, respectively; meanwhile, the coffee benefit process was the phase with the most contributions to the water footprint (54%). The residual biomass from the product system used as the energy supply within the coffee drying sub-phase represented energy savings of around 41% in comparison to the use of conventional fossil fuels, thus reducing the global impact associated to the system’s product.
Accelerated Exploration for Long-Term Urban Water Infrastructure Planning through Machine Learning
Authors: Zhang Junyu , Fu Dafang , Urich Christian , Singh Rajendra Prasad
Published: December 2018

In this study, the neural network method (Multi-Layer Perceptron, MLP) was integrated with an explorative model, to study the feasibility of using machine learning to reduce the exploration time but providing the same support in long-term water system adaptation planning. The specific network structure and training pattern were determined through a comprehensive statistical trial-and-error (considering the distribution of errors). The network was applied to the case study in Scotchman’s Creek, Melbourne. The network was trained with the first 10% of the exploration data, validated with the following 5% and tested on the rest. The overall root-mean-square-error between the entire observed data and the predicted data is 10.5722, slightly higher than the validation result (9.7961), suggesting that the proposed trial-and-error method is reliable. The designed MLP showed good performance dealing with spatial randomness from decentralized strategies. The adoption of MLP-supported planning may overestimate the performance of candidate urban water systems. By adopting the safety coefficient, a multiplicator or exponent calculated by observed data and predicted data in the validation process, the overestimation problem can be controlled in an acceptable range and have few impacts on final decision making.
Impact of Technology Habitual Domain on Ambidextrous Innovation: Case Study of a Chinese High-Tech Enterprise
Authors: Ye Xinwei , Ma Lei , Feng Junwen , Cheng Yang , Liu Zheng
Published: December 2018

To obtain a sustainable competitive advantage in the dynamic environment, it is necessary for Chinese high-tech enterprises to focus on their technology habitual domains in formulating ambidextrous innovation strategy. This study integrates technology habitual domain, exploratory innovation and exploitative innovation within a framework and explores the influence mechanism among them. Based on an in-depth case study on KTE, representing a high-tech enterprise in China, we have several findings. Firstly, we depict the evolution mechanism of technology habitual domain; secondly, we find that the high-tech enterprise’s technology habitual domain will cultivate and develop the firms’ dynamic capabilities; and thirdly, the expansion of technology habitual domain will promote exploitative innovation, while the transformation of technology habitual domain will promote exploratory innovation. These findings can be useful guidance for high-tech enterprises in China who are aiming to achieve ambidextrous innovation to better adapt to the turbulent environment, and thus achieving sustainability.
Spatial-Temporal Changes of Soil Respiration across China and the Response to Land Cover and Climate Change
Authors: Wen Jiqun , Chuai Xiaowei , Li Shanchi , Song Song , Li Jiasheng , Guo Xiaomin , Yang Lei
Published: December 2018

Soil respiration (Rs) plays an important role in the carbon budget of terrestrial ecosystems. Quantifying the spatial and temporal variations in Rs in China at the regional scale helps improve our understanding of the variations in terrestrial carbon budgets that occur in response to global climate and environmental changes and potential future control measures. In this study, we used a regional-scale geostatistical model that incorporates gridded meteorological and pedologic data to evaluate the spatial Rs variations in China from 2000 to 2013. We analysed the relationship between Rs and environmental factors, and suggest management strategies that may help to keep the terrestrial carbon balance. The simulated results demonstrate that the mean annual Rs value over these 14 years was 422 g/m2/year, and the corresponding total amount was 4.01 Pg C/year. The Rs estimation displayed a clear spatial pattern and a slightly increasing trend. Further analysis also indicated that high Rs values may occur in areas that show a greater degree of synchronicity in the timing of their optimal temperature and moisture conditions. Moreover, cultivated vegetation exhibits higher Rs values than native vegetation. Finally, we suggest that specific conservation efforts should be focused on ecologically sensitive areas where the Rs values increase significantly.
I Ke Ēwe ʻĀina o Ke Kupuna: Hawaiian Ancestral Crops in Perspective
Authors: Kagawa-Viviani Aurora , Levin Penny , Johnston Edward , Ooka Jeri , Baker Jonathan , Kantar Michael , Lincoln Noa Kekuewa
Published: December 2018

Indigenous crops, tremendously valuable both for food security and cultural survival, are experiencing a resurgence in Hawaiʻi. These crops have been historically valued by agricultural researchers as genetic resources for breeding, while cultural knowledge, names, stories and practices persisted outside of formal educational and governmental institutions. In recent years, and following conflicts ignited over university research on and patenting of kalo (Hāloa, Colocasia esculenta), a wave of restoration activities around indigenous crop diversity, cultivation, and use has occurred through largely grassroots efforts. We situate four crops in Hawaiian cosmologies, review and compare the loss and recovery of names and cultivars, and describe present efforts to restore traditional crop biodiversity focusing on kalo, ʻuala (Ipomoea batatas), kō (Saccharum officinarum), and ʻawa (Piper methysticum). The cases together and particularly the challenges of kalo and ‘awa suggest that explicitly recognizing the sacred role such plants hold in indigenous worldviews, centering the crops’ biocultural significance, provides a foundation for better collaboration across multiple communities and institutions who work with these species. Furthermore, a research agenda that pursues a decolonizing approach and draws from more participatory methods can provide a path forward towards mutually beneficial exchange among research, indigenous, and farmer communities. We outline individual and institutional responsibilities relevant to work with indigenous crops and communities and offer this as a step towards reconciliation, understanding, and reciprocity that can ultimately work to create abundance through the restoration of ancestral crop cultivar diversity.
Economic Value of Building a Firefighter Training Academy for Urban Disaster Management in Seoul, South Korea
Authors: Kim Ju-Hee , Kim Hyo-Jin , Yoo Seung-Hoon
Published: December 2018

The Seoul Metropolitan Government plans to build a new firefighter training academy (FTA) for urban disaster management. The Government needs information about its economic value to determine whether building a FTA is socially desirable. This paper aims to estimate the economic value of the FTA by applying a choice experiment (CE) method through a survey of firefighters who do on-site fire prevention activities in Seoul. The annual economic values of six training centers were estimated using the data from a total of 1658 firefighters who responded to the CE survey questionnaire, with a 1% statistical significance level. The economic value of the FTA amounts to KRW 10.04 billion (USD 8.80 million) annually. Given the 30-year operating period, the present value is KRW 129.86 billion, which can be seen as the economic benefit of building the FTA. The present value of the costs for the construction and operation of the FTA is KRW 54.66 billion (USD 48.30 million). As the benefits outweigh the costs, it can be concluded that it is socially profitable to build the FTA.
Assessing the Sustainability of Decentralized Wastewater Treatment Systems in Rwanda
Authors: Kazora Amos Shyaka , Mourad Khaldoon A.
Published: December 2018

Kigali city, the capital of Rwanda, relies on decentralized, on-site, wastewater systems due to the absence of central sewerage systems and the limited finances to construct sustainable sanitation infrastructures. However, the city has increasingly shown failures in managing these on-site systems either at individual or collective levels. This study aims at assessing the sustainability of the operated collective public semicentralized sewage systems in Kigali city. To fully cover the sustainability assessment of such collective systems, the methods used were field observation, questionnaires, interviews, and laboratory tests. The study also reviewed the influence of national ruling sanitation legal instruments in addressing development, operation and management of such decentralized wastewater systems. The results showed that the sustainability levels of these systems were low in the technical, socioeconomic status, institutional, and legal dimensions. While the sustainability level was fair for the environmental quality. In conclusion, the research highlighted that the improved sanitation coverage does not mean coverage in terms of sewerage connection proportions for wastewater collection as these connections do not imply safe and sustainable treatment before being discharged into the environment.