bluuebunny/crossref_metadata_2025 huggingface dataset:
Artificially Intelligent Vehicle-to-Grid Energy Management: A Semantic-Aware Framework Balancing Grid Demands and User Autonomy
Authors: Elkhodr Mahmoud
Published: October 2024

As the adoption of electric vehicles increases, the challenge of managing bidirectional energy flow while ensuring grid stability and respecting user preferences becomes increasingly critical. This paper aims to develop an intelligent framework for vehicle-to-grid (V2G) energy management that balances grid demands with user autonomy. The research presents VESTA (vehicle energy sharing through artificial intelligence), featuring the semantic-aware vehicle access control (SEVAC) model for efficient and intelligent energy sharing. The methodology involves developing a comparative analysis framework, designing the SEVAC model, and implementing a proof-of-concept simulation. VESTA integrates advanced technologies, including artificial intelligence, blockchain, and edge computing, to provide a comprehensive solution for V2G management. SEVAC employs semantic awareness to prioritise critical vehicles, such as those used by emergency services, without compromising user autonomy. The proof-of-concept simulation demonstrates VESTA’s capability to handle complex V2G scenarios, showing a 15% improvement in energy distribution efficiency and a 20% reduction in response time compared to traditional systems under high grid demand conditions. The results highlight VESTA’s ability to balance grid demands with vehicle availability and user preferences, maintaining transparency and security through blockchain technology. Future work will focus on large-scale pilot studies, improving AI reliability, and developing robust privacy-preserving techniques.
Effects of OpenCL-Based Parallelization Methods on Explicit Numerical Methods to Solve the Heat Equation
Authors: Koics Dániel , Kovács Endre , Hornyák Olivér
Published: October 2024

In recent years, the need for high-performance computing solutions has increased due to the growing complexity of computational tasks. The use of parallel processing techniques has become essential to address this demand. In this study, an Open Computing Language (OpenCL)-based parallelization algorithm is implemented for the Constant Neighbors (CNe) and CNe with Predictor–Corrector (CpC) numerical methods, which are recently developed explicit and stable numerical algorithms to solve the heat conduction equation. The CPU time and error rate performance of these two methods are compared with the sequential implementation and Euler’s explicit method. The results demonstrate that the parallel version’s CPU time remains nearly constant under the examined circumstances, regardless of the number of spatial mesh points. This leads to a remarkable speed advantage over the sequential version for larger data point counts. Furthermore, the impact of the number of timesteps on the crossover point where the parallel version becomes faster than the sequential one is investigated.
The Utility of Immuno-Nutritional Scores in Patients with Testicular Germ Cell Tumors
Authors: Bumbasirevic Uros , Petrovic Milos , Coric Vesna , Lisicic Nikola , Obucina David , Zekovic Milica , Milojevic Bogomir , Vasilic Nenad , Vasic Vladimir , Zivkovic Marko , Bojanic Nebojsa , Janicic Aleksandar
Published: October 2024

Background: Hemoglobin, Albumin, Lymphocyte, and Platelet Score (HALP) is an accessible score that is easily reproducible from routine laboratory testing while also reflecting patients’ immune-nutritional status. Along with other immuno-nutritional scores, such as the Prognostic Nutrition Index (PNI), HALP has been associated with a number of clinical and pathological features. The goal of our study was to evaluate the prognostic utility of HALP and PNI scores in testicular germ cell cancer (GCT) patients. Methods: This case-only study included 203 testicular GCT patients who were classified according to the disease stage and HALP and PNI cut-offs. Complete blood count and albumin concentration were routinely determined. Results: The values of HALP and PNI significantly differed among different clinical stages (p < 0.05). Moreover, they clearly exposed a significantly higher risk of advanced clinical stage development for those testicular GCT patients with lower values of HALP and PNI (p < 0.05). Finally, lower score levels were associated with larger tumor size (p < 0.05). Conclusion: Our investigation could provide evidence that specific immune-nutritional scores can help distinguish individuals diagnosed with testicular GCT who are more likely to be identified with advanced disease stages.
Digital Active EMI Filter for Smart Electronic Power Converters
Authors: Darisi Michele , Caldognetto Tommaso , Biadene Davide , Stellini Marco
Published: October 2024

Electronic power converters are widespread and crucial components in modern energy scenarios. Beyond mere electrical energy conversion, their electronic structure allows several functionalities to be naturally embedded in them, including energy management, diagnosis, communication, etc. The operation of the converter itself, or the system interfaced by the same, commonly produces undesired electromagnetic interferences (EMIs) that should comply with prescribed limits. This paper presents a digital active EMI filter designed to mitigate such disturbances. The proposed hardware implementation can acquire and analyze the common-mode (CM) noise affecting the circuit and inject a compensation signal to attenuate the measured interference. A novel adaptive algorithm is introduced to compute the necessary signals for effective noise cancellation. The implementation is integrated within a single printed circuit board interfaced with a field-programmable gate array (FPGA) running the control algorithm. The digital filter’s efficacy in EMI reduction is demonstrated using a synchronous buck converter with gallium nitride (GaN) power devices, achieving significant noise reduction. Additionally, potential functionalities are envisioned to fully exploit the capabilities of the proposal beyond EMI filtering, like fault detection, predictive maintenance, smart converter optimization, and communication.
Extending More than One Week the Shelf Life of Fresh-Cut Lettuce Using Vinegar Enriched in Bioactive Compounds Encapsulated in α-Cyclodextrins
Authors: Martínez-Sánchez María de los Ángeles , Martínez-Hernández Ginés Benito , López-Gómez Antonio
Published: October 2024

Fresh-cut salads are highly appreciated by consumers due to their healthy and convenient nature. Fresh-cut (FC) lettuce is one of the best-selling FC products due to its freshness and low preparation time for salads. However, FC lettuce is very perishable and, in addition, has been recently associated with severe foodborne illness alerts. Alternative natural sanitizing treatments to conventional sodium hypochlorite are needed. The antimicrobial activity of vinegar has been well-known since ancient times. In addition, bioactive compounds from plant byproducts are widely recognized for their antioxidant properties. This work aimed to evaluate the use of a novel and encapsulated vinegar powder enriched with bioactive compounds from fruit byproducts with high antimicrobial and antioxidant properties to preserve the physicochemical (titratable acidity, total soluble solids, weight loss, and color), microbial (psychrophiles, enterobacteria, lactic-acid bacteria, molds, and yeasts), and sensory quality of FC lettuce at 4 °C for up to 10 days. Small to no differences were observed in terms of physicochemical quality (≈0.1% titratable acidity; 2.3–3.3% total soluble solids; <1% weight loss) in comparison to control samples through storage. Vinegar treatments reduced by 2–4 log CFU g−1 the microbial loads after 10 days. In addition, a synergistic sensory antibrowning effect (greener and less yellowish appearance, showing −a* and −b*) between organic acids and the released polyphenols from the encapsulated plant byproduct extracts was observed. Hence, the enriched encapsulated vinegar represents an effective green alternative to conventional sanitizers to maintain the quality of FC lettuce through storage time.
Molecular Interaction and Solubilization Efficiency of Neohesperidin in Ternary Systems with Hydroxypropyl-β-cyclodextrin and Meglumine
Authors: Xia Na , Liu Yanquan , Gao Dan , Zhu Siming
Published: October 2024

The solubilization of poorly water-soluble natural bioactive compounds remains a significant challenge. This study aims to design a ternary inclusion system to enhance the solubility of the poorly water-soluble compound Neohesperidin (NH). Soluble ternary cyclodextrin complexations (t-CDs) containing NH, 2-hydroxypropyl-β-cyclodextrin (HP-β-CD), and meglumine (MEG) were prepared and optimized. The optimized t-CDs were further characterized using Scanning Electron Microscopy (SEM), Powder X-ray Diffraction (PXRD), Differential Scanning Calorimetry (DSC), Fourier Transform Infrared Spectroscopy (FTIR), Nuclear Magnetic Resonance (NMR), and molecular docking (MD) techniques. The results suggested that NH formed was associated with MEG through hydrogen bonds with MEG, and was subsequently incorporated into the hydrophobic cavity of HP-β-CD, which may be a key factor in improving its solubility. The solubility of NH in water at 37 °C increased significantly from 0.16 mg/mL to 5.81 mg/mL in the optimized t-CDs (NH/MEG/HP-β-CD).
Transjugular Intrahepatic Portosystemic Shunt for Budd–Chiari Syndrome: A Single-Centre Experience
Authors: Joueidi Faisal , Alhanaee Amnah , Alsuhaibani Hamad , Albenmousa Ali , Joueidi Ahmad , Elhassan Ahmed , Nasir Abdallah Nabeel , Marquez Kris Ann Hervera , Alghamdi Saad , Al Hamoudi Waleed , Abualganam Saad , Broering Dieter , Bzeizi Khalid Ibrahim
Published: October 2024

Background: Despite several challenges in clinical management, there has been significant progress in understanding the aetiology, natural history and outcomes of Budd–Chiari syndrome (BCS) treatments. This study aims to evaluate the outcomes of transjugular intrahepatic portosystemic shunt (TIPS) using covered stent in management of BCS. Methods: We conducted a retrospective analysis of 70 BCS patients who underwent TIPS using covered stents between January 2010 and December 2022 at a single tertiary liver transplant centre. Patients’ clinical features, laboratory parameters, and imagine findings were collected before and after TIPS. The primary endpoint was overall survival. Results: TIPS was performed on 70 patients with BCS out of a total of 88 patients. The remaining patients (18) underwent liver transplantation. The mean age was 37.7 ± 11.2 years at time of diagnosis and the majority were female (64.35). The most common symptoms and signs at presentation were abdominal pain, jaundice, ascites, and variceal bleeding. Over a median followup of 76 months, the survival rates at 1, 3, and 5 years were 98.8%, 97.9%, and 97.7%, respectively. Patients who underwent TIPS alone had better survival that patients with BCS who required liver transplantation (LTx) (p = 0.003). Conclusions: In our study TIPS provided a highly effective treatment option for BCS patients. The long-term favourability of the outcome was not impacted by the need for repeated TIPS revision. Use of covered stents was instrumental in reducing shunt dysfunction rates. Prospective and larger studies are needed to further optimize therapeutic strategies in this challenging population.
Response of Circulating Free Cellular DNA to Repeated Exercise in Men with Type 1 Diabetes Mellitus
Authors: Walczak Konrad , Grzybowska-Adamowicz Julia , Stawski Robert , Brzezińska Olga , Zmysłowska Agnieszka , Nowak Dariusz
Published: October 2024

Background: Intense exercise leads to neutrophil extracellular traps (NETs) formation, which triggers cell disintegration. NET, as well as other processes of apoptosis, necrosis, and spontaneous secretion, result in increased levels of cell-free DNA (cf-DNA) in the circulation. An increment of cf-DNA is also observed in autoimmune diseases, such as type 1 diabetes mellitus (T1DM). Repeated exhaustive exercises are an impulse for physiological adaptation; therefore, in this case–control study, we compared the exercise-induced increase in cf-DNA in men with T1DM and healthy controls to determine the development of the tolerance to exercise. Methods: Volunteers performed a treadmill run to exhaustion at a speed matching 70% of their personal VO2 max at three consecutive visits, separated by a 72 h resting period. Blood was collected before and after exercise for the determination of plasma cell-free nuclear and mitochondrial DNA (cf n-DNA, cf mt-DNA) by real-time PCR, blood cell count and metabolic markers. Results: Each bout of exhaustive exercise induced a great elevation of cf n-DNA levels. An increase in cf mt-DNA was observed after each run. However, the significance of the increase was noted only after the second bout in T1DM participants (p < 0.02). Changes in cf-DNA concentration were transient and returned to baseline values during 72 h of resting. The exercise-induced increment in circulating cf n-DNA and cf mt-DNA was not significantly different between the studied groups (p > 0.05). Conclusions: Cf-DNA appears to be a sensitive marker of inflammation, with a lower post-exercise increase in individuals with T1DM than in healthy men.
Skin Barrier Function and Microtopography in Patients with Atopic Dermatitis
Authors: Pretel-Lara Carlota , Sanabria-de la Torre Raquel , Arias-Santiago Salvador , Montero-Vilchez Trinidad
Published: October 2024

Background: Atopic dermatitis (AD) is a chronic inflammatory skin disease whose incidence is increasing. Skin barrier dysfunction plays an important role in this disease. It has been observed that AD patients have higher transepidermal water loss (TEWL) and lower stratum corneum hydration (SCH); however, there is little information about skin microtopography in this pathology. The objective of this study is to evaluate skin barrier dysfunction and structural changes in patients with AD. Methods: A cross-sectional study was conducted including patients with AD. Parameters of skin barrier function were measured (TEWL, temperature, erythema, pH, skin hydration, elasticity) and also other topographical parameters (scaliness, wrinkles, smoothness, surface, contrast, variance) in both healthy skin and flexural eczematous lesions. Results: A total of 32 patients with AD were included in the study. Flexural eczematous lesions had higher erythema (369.12 arbitrary unit (AU) vs. 223.89 AU, p < 0.001), higher TEWL (27.24 g/h/m2 vs. 13.51 g/h/m2, p < 0.001), lower SCH (20.3 AU vs. 31.88 AU, p < 0.001) and lower elasticity (0.56% vs. 0.65%, p = 0.05). Regarding topographic parameters, flexural eczematous lesions presented greater scaliness (5.57 SEsc vs. 0.29 SEsc, p = 0.02), greater smoothness (316.98 SEsm vs. 220.95 SEsm p < 0.001), more wrinkles (73.33 SEw vs. 62.15 SEw p = 0.03), greater surface area (836.14% vs. 696.31%. p < 0.001), greater contrast (2.02 AU vs. 1.31 AU p = 0.01), greater variance (6.22 AU vs. 4.96 AU p < 0.001) and a lower number of cells (105.5 vs. 132.5 p < 0.001) compared to unaffected healthy skin, reflecting a decrease in skin quality in AD patients. Conclusions: Both skin barrier function and skin topography are damaged in patients with AD, with differences between healthy skin and flexural eczema.
Treatment of Geriatric Acetabular Fractures Using the Modified Stoppa Approach: A Review Article of Technique, Tips, and Pitfalls
Authors: Bartosik Mikolaj , Mayr Eckart , Culemann Ulf
Published: October 2024

The surgical treatment of geriatric acetabular fractures is becoming increasingly important due to a demographic change in age. While acetabular fractures used to occur more frequently in younger patients, they are currently more prevalent in geriatric patients. This change has also led to an increase in the frequency of anterior and combined anterior acetabular fractures. Surgery for geriatric acetabular fractures is very challenging, and surgeons need years of experience to be able to deal with the advantages and disadvantages of pelvic surgery. This is why a high level of surgical expertise is required. The aim of this article is to provide an insight into the topic of geriatric acetabular fractures with a critical narrative review of the current literature and a focus on minimally invasive surgical treatment using the modified Stoppa approach without patients’ own assessment. The modified Stoppa approach offers excellent visibility of the anterior structures of the acetabulum and can address the quadrilateral surface effectively. Pelvic surgery, in particular acetabular surgery, offers patients many advantages, such as rapid mobilization and the quick relief of pain symptoms. Total hip arthroplasty is currently being discussed as an alternative with good results for certain types of acetabular fractures in older patients, though it requires clarification of studies and recommendations.
The Therapeutic Efficacy of Abatacept for Rheumatoid Arthritis-Associated Interstitial Lung Disease: Insights from a 12-Month Trial Using Semi-Quantitative Chest High-Resolution Computed Tomography Imaging
Authors: Shoda Takeshi , Kotani Takuya , Koyama Mitsuhiro , Yoshikawa Ayaka , Wada Yumiko , Makino Hidehiko , Osuga Keigo , Takeuchi Tohru
Published: October 2024

Background: Rheumatoid arthritis-associated interstitial lung disease (RA-ILD) is a major complication of rheumatoid arthritis (RA), but effective treatment remains an unmet need in its management. Our aim was to evaluate the therapeutic efficacy of abatacept for RA-ILD. Methods: This observational retrospective study included patients with RA-ILD treated with abatacept between 2012 and 2021. Indices of RA disease activity and interstitial lung disease (Disease Activity Score in 28 joints using C-reactive Protein [DAS28-CRP], Simplified Disease Activity Index [SDAI], Clinical Disease Activity Index [CDAI], serum Krebs von den Lungen-6 levels, % forced vital capacity [%FVC], and semi-quantified chest high-resolution computed tomography scores) were evaluated before and 1 year after the start of abatacept administration. Results: Overall, 38 patients were included. DAS28-CRP, SDAI, and CDAI were significantly improved (all with p < 0.0001). Total ground-glass opacity scores were decreased in both patients with usual interstitial pneumonia (UIP)-like patterns and with non-UIP-like patterns (p = 0.008 and <0.002, respectively). Total fibrosis scores were also decreased in the UIP-like pattern group (p < 0.042). The %FVC remained stable. Conclusions: Abatacept significantly improves RA disease activity and reduces pulmonary inflammation in patients with RA-ILD.
Total Hip Arthroplasty in Hip Osteoarthritis with Subtrochanteric Localized Periosteal Thickening: Preoperative Planning Using Finite Element Analysis to Determine the Optimal Stem Length
Authors: Shimasaki Koshiro , Nishino Tomofumi , Yoshizawa Tomohiro , Watanabe Ryunosuke , Hirose Fumi , Yasunaga Shota , Mishima Hajime
Published: October 2024

Background: Owing to the risk of atypical femoral fractures, total hip arthroplasty presents unique challenges for patients with ipsilateral osteoarthritis and localized periosteal thickening in the femoral subtrochanteric region. Stem length selection is critical for minimizing stress concentration in the thickened cortex to avoid such fractures. Herein, we report the case of a 78-year-old woman with ipsilateral hip osteoarthritis and localized subtrochanteric periosteal thickening. Methods: Preoperative planning included a finite element analysis to assess the stress distribution across various stem lengths. A simulation was conducted to determine the optimal stem length to span the cortical thickening and reduce the risk of postoperative complications. Results: The finite element analysis indicated that a stem length of >150 mm was required to effectively reduce the stress at the site of cortical thickening. A 175 mm stem was selected for total hip arthroplasty, which provided a favorable stress distribution and avoided the risk of stress concentration. Conclusions: In cases of ipsilateral osteoarthritis with localized subtrochanteric periosteal thickening, finite element analysis can be valuable for preoperative planning to determine the optimal stem length, thereby reducing the risk of atypical femoral fractures. Further studies with multiple cases are recommended to validate these findings and improve surgical outcomes.
Dynamic Event-Triggered Control for Sensor–Controller–Actuator Networked Control Systems
Authors: Abdelrahim Mahmoud , Almakhles Dhafer
Published: October 2024

We consider the problem of output feedback stabilization of LTI systems under event-triggering implementation. In particular, we assume that both the plant output and the control input are both transmitted over the network in an asynchronous manner. To that end, two independent event-triggering rules are constructed to generate the transmission instants of the submitted signals. The proposed approach is dynamic in the sense that the triggering rules involve internal dynamical variables to allow for further reduction in the communication load. Moreover, the inter-transmission times for both sides of the channel are lower bound by enforced dwell times to prevent the occurrence of Zeno phenomena. The problem is challenging due to mutual interactions between the sampling errors of the plant output and the control input, which requires careful handling to ensure closed-loop stability. The triggering mechanisms are designed by emulation as we first ignore the effect of the network and stabilize the plant in continuous-time. Then, the communication constraints are taken into account to derive the triggering conditions such that the stability of the networked control system is preserved. The required conditions are formulated in terms of a linear matrix inequality. The effectiveness of the technique is demonstrated by numerical simulations.
Assessing Land-Cover Changes in the Natural Park ‘Fragas do Eume’ over the Last 25 Years: Insights from Remote Sensing and Machine Learning
Authors: Díaz-García Paula , Regos Adrián
Published: October 2024

The ‘Fragas do Eume’ Natural Park includes one of the best-preserved Atlantic forests in Europe. These forests are part of the Natura 2000 Network. This scientific study focuses on analysing land-cover changes in the ‘Fragas do Eume’ Natural Park (NW Spain) over a 25-year period, from 1997 to 2022, using machine learning techniques for the classification of satellite images. Several image processing operations were carried out to correct radiometry, followed by supervised classification techniques with previously defined training areas. Five multispectral indices were used to improve classification accuracy, and their correlation was evaluated. Land-cover changes were analysed, with special attention to the transitions between eucalyptus plantations and native deciduous forests. A significant increase in eucalyptus plantations (48.2%) (Eucalyptus globulus Labill.) was observed, while native deciduous forests experienced a decrease in their extent (17.6%). This transformation of the landscape affected not only these two habitats, but also cropland and scrubland areas, both of which increased. Our results suggest that the lack of effective conservation policies and the economic interest of fast-growing tree plantations could explain the loss of native deciduous forests. The results highlight the need to implement pro-active and sustainable management measures to protect these natural forest ecosystems in the ‘Fragas do Eume’ Natural Park.
Mechanisms of Germline Stem Cell Competition across Species
Authors: Hodge Rachel A. , Bach Erika A.
Published: October 2024

In this review, we introduce the concept of cell competition, which occurs between heterogeneous neighboring cell populations. Cells with higher relative fitness become “winners” that outcompete cells of lower relative fitness (“losers”). We discuss the idea of super-competitors, mutant cells that expand at the expense of wild-type cells. Work on adult stem cells (ASCs) has revealed principles of neutral competition, wherein ASCs can be stochastically lost and replaced, and of biased competition, in which a winning ASC with a competitive advantage replaces its neighbors. Germline stem cells (GSCs) are ASCs that are uniquely endowed with the ability to produce gametes and, therefore, impact the next generation. Mechanisms of GSC competition have been elucidated by studies in Drosophila gonads, tunicates, and the mammalian testis. Competition between ASCs is thought to underlie various forms of cancer, including spermatocytic tumors in the human testis. Paternal age effect (PAE) disorders are caused by de novo mutations in human GSCs that increase their competitive ability and make them more likely to be inherited, leading to skeletal and craniofacial abnormalities in offspring. Given its widespread effects on human health, it is important to study GSC competition to elucidate how cells can become winners or losers.
Four-Ingredient Blends of Poly(lactic acid) with Cottonseed Oil and Meal for Biocomposite Utilization
Authors: He Zhongqi , Cheng Huai N. , Ford Catrina V. , Nam Sunghyun , Fortier Chanel , Santiago Cintron Michael , Olanya Ocen Modesto , Uknalis Joseph
Published: October 2024

The development and characterization of agricultural byproduct-based biocomposites are an important part of green chemistry. In this work, four-ingredient blends were formulated with the melt blending method. The set of composites (named as CSO series) was made with poly(lactic acid) (PLA) as the major matrix, washed cottonseed meal (WCSM) as a filler, cottonseed oil (CSO) as a compatibilizer, and glycerol (GLY) as a plasticizer. The morphological analysis showed the homogenous dispersion of the cottonseed byproducts into the PLA matrix to some extent. The thermogravimetric analysis revealed that thermal stability was impacted by the ingredient’s addition. The functional group analysis of the sample and simulation by Fourier transform infrared spectra confirmed the chemical interactions of PLA with WCSM in the blend products. CSO was most likely subjected to physical blending into the products. The mechanical strengths of those composites were affected by the ratios of PLA-CSO. Generally, the tensile strengths were in the range of 0.74–2.1 MPa, which indicate its suitability for low-strength biodegradable plant container development. The blend products had a lower water absorption during the water soaking test. This work shows the feasibility of incorporating cottonseed WCSM and CSO into a PLA composite for sustainable agricultural applications.
Review of Metal Screw Extrusion: State of the Art and Beyond
Authors: Kvam-Langelandsvik Geir , Skorpen Kristian Grøtta , Werenskiold Jens Christofer , Roven Hans Jørgen
Published: October 2024

Metal screw extrusion (MSE) is a continuous, solid-state forming method utilizing an inherently high degree of deformation to consolidate fragmented input materials into a solid bulk by breaking their oxide skins. Severe plastic deformation with equivalent strain in the range of 10–20 can be achieved depending on set process parameters. Rigorous mixing can be employed to form sophisticated materials like bulk composites, nanocomposites, particle-reinforced metals, and fine-grained materials. Furthermore, the inherent solid-state processing is well suited for recovery of difficult-to-recycle materials. A range of non-ferrous materials has been manufactured by MSE and further characterized in terms of microstructural evolution and mechanical and functional properties. Furthermore, MSE has been studied in terms of flow, accumulated strain, and environmental impact. The following review aims to critically highlight the existing work performed on MSE, compare it to existing and emerging technologies as well as explore future development and possible applications. MSE has the potential to be utilized for numerous commercial applications. To realize industrial use of MSE, key aspects of the process and the influence of processing parameters on the resulting product must be understood.
Functionalisation of the Aluminium Surface by CuCl2 Chemical Etching and Perfluoro Silane Grafting: Enhanced Corrosion Protection and Improved Anti-Icing Behaviour
Authors: Rodič Peter , Može Matic , Golobič Iztok , Milošev Ingrid
Published: October 2024

This study aimed to prepare a facile hierarchical aluminium surface using a two-step process consisting of chemical etching in selected concentrations of CuCl2 solution and surface grafting through immersion in an ethanol solution containing 1H, 1H, 2H, 2H-perfluorodecyltriethoxysilane. The goal was to achieve superhydrophobic characteristics on the aluminium surface, including enhanced corrosion resistance, efficient self-cleaning ability, and improved anti-icing performance. The surface characterisation of the untreated aluminium and treated in CuCl2 solutions of different concentrations was performed using contact profilometry, optical tensiometry, and scanning electron microscopy coupled with energy dispersive spectroscopy to determine the surface topography, wettability, morphology, and surface composition. The corrosion properties were evaluated using potentiodynamic measurements in simulated acid rain solution and salt-spray test according to ASTM B117-22. In addition, self-cleaning and anti-icing tests were performed on superhydrophobic surfaces prepared under optimal conditions. The results showed that the nano-/micro-structured etched aluminium surface with an optimal 0.5 M concentration of CuCl2 grafted with a perfluoroalkyl silane film achieved superhydrophobic characteristics, with water droplets exhibiting efficient corrosion protection, self-cleaning ability, and improved anti-icing performance with decreased ice nucleation temperature and up to 545% increased freezing delay.
N-Oxide Coordination to Mn(III) Chloride
Authors: Saju Ananya , Crawley Matthew R. , MacMillan Samantha N. , Le Magueres Pierre , Del Campo Mark , Lacy David C.
Published: October 2024

We report on the synthesis and characterization of Mn(III) chloride (MnIIICl3) complexes coordinated with N-oxide ylide ligands, namely trimethyl-N-oxide (Me3NO) and pyridine-N-oxide (PyNO). The compounds are reactive and, while isolable in the solid-state at room temperature, readily decompose into Mn(II). For example, “[MnIIICl3(ONMe3)n]” decomposes into the 2D polymeric network compound complex salt [MnII(µ-Cl)3MnII(µ-ONMe3)]n[MnII(µ-Cl)3]n·(Me3NO·HCl)3n (4). The reaction of MnIIICl3 with PyNO forms varied Mn(III) compounds with PyNO coordination and these react with hexamethylbenzene (HMB) to form the chlorinated organic product 1-cloromethyl-2,3,4,5,6-pentamethylbenzene (8). In contrast to N-oxide coordination to Mn(III), the reaction between [MnIIICl3(OPPh3)2] and 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) resulted in electron transfer-forming d5 manganate of the [TEMPO] cation instead of TEMPO–Mn(III) adducts. The reactivity affected by N-oxide coordination is discussed through comparisons with other L–MnIIICl3 complexes within the context of reduction potential.
Hydrogen Separation Membranes: A Material Perspective
Authors: Bhalani Dixit V. , Lim Bogyu
Published: October 2024

The global energy market is shifting toward renewable, sustainable, and low-carbon hydrogen energy due to global environmental issues, such as rising carbon dioxide emissions, climate change, and global warming. Currently, a majority of hydrogen demands are achieved by steam methane reforming and other conventional processes, which, again, are very carbon-intensive methods, and the hydrogen produced by them needs to be purified prior to their application. Hence, researchers are continuously endeavoring to develop sustainable and efficient methods for hydrogen generation and purification. Membrane-based gas-separation technologies were proven to be more efficient than conventional technologies. This review explores the transition from conventional separation techniques, such as pressure swing adsorption and cryogenic distillation, to advanced membrane-based technologies with high selectivity and efficiency for hydrogen purification. Major emphasis is placed on various membrane materials and their corresponding membrane performance. First, we discuss various metal membranes, including dense, alloyed, and amorphous metal membranes, which exhibit high hydrogen solubility and selectivity. Further, various inorganic membranes, such as zeolites, silica, and CMSMs, are also discussed. Major emphasis is placed on the development of polymeric materials and membranes for the selective separation of hydrogen from CH4, CO2, and N2. In addition, cutting-edge mixed-matrix membranes are also delineated, which involve the incorporation of inorganic fillers to improve performance. This review provides a comprehensive overview of advancements in gas-separation membranes and membrane materials in terms of hydrogen selectivity, permeability, and durability in practical applications. By analyzing various conventional and advanced technologies, this review provides a comprehensive material perspective on hydrogen separation membranes, thereby endorsing hydrogen energy for a sustainable future.
Renewable Resources as Promising Materials for Obtaining Graphene Oxide-like Structures
Authors: Kuanyshbekov Tilek , Akatan Kydyrmolla , Guseinov Nazim , Nemkaeva Renata , Kurbanova Bayan , Tolepov Zhandos , Tulegenova Malika , Kabdrakhmanova Sana , Zhilkashinova Almira
Published: October 2024

Currently, one of the topical directions in the field of production and application of graphene-like nanostructures is the use of renewable natural raw materials, which have unlimited resources for an economically efficient large-scale yield of a product with environmental safety. In this regard, we present the production of graphene oxide (GO) from a renewable natural raw material of plant biomass, birch activated carbon (BAC), and a comparison of the obtained physicochemical, mechanical, and electrical properties of birch activated carbon–graphene oxide (BAC–GO) and graphite–graphene oxide (G–GO) synthesized from the initial materials, BAC and graphite (G). Results obtained from this study confirm the successful oxidation of BAC, which correlates well with the physical–chemical dates of the G–GO and BAC–GO samples. Change in data after the oxidation of graphite and BAC was facilitated by the structure of the starting materials and, presumably, the location and content of functional oxygen-containing groups in the G–GO and BAC–GO chains. Based on the results, the application of a cost-effective, eco-friendly colloidal solution of nanodispersed BAC–GO from a plant biomass-based high-quality resource for producing large-scale nanostructured graphene is validated which has potential applicability in nanoelectronics, medicine, and other fields.
Antimicrobial Susceptibility of Enterococci Isolated from Nestlings of Wild Birds Feeding in Supplementary Feeding Stations: The Case of the Canarian Egyptian Vulture
Authors: González-Martín Margarita Rosa , Suárez-Pérez Alejandro , Álamo-Peña Alejandro , Valverde Tercedor Carmen , Corbera Juan Alberto , Tejedor-Junco María Teresa
Published: October 2024

Antimicrobial resistance is a growing concern worldwide, requiring a holistic “One Health” strategy to address the interconnectedness of human, animal, and environmental health. This study focused on Enterococci isolated from Canary Island Egyptian vulture chicks, an endangered species that feeds at supplementary feeding stations in the Canary Islands. Sampling and identification revealed the presence of several Enterococcus species, with a predominance of E. faecalis. Antimicrobial susceptibility testing showed resistance patterns, especially to important antibiotics such as quinolones, vancomycin, and linezolid. The prevalence of multidrug-resistant profiles was lower than that in other wild bird species. This study underscores the need for further research to understand the dynamics of antimicrobial resistance in wildlife and its implications for public health and conservation efforts, emphasizing the importance of a “One Health” approach to address this pressing problem.
A Review of Nonhuman Primate Models of Rift Valley Fever Virus Infection: Progress, Challenge Strains, and Future Directions
Authors: Ebisine Kimimuepigha , Quist Darcy , Findlay-Wilson Stephen , Kennedy Emma , Dowall Stuart
Published: October 2024

Rift Valley fever (RVF) is a mosquito-borne viral disease that primarily affects animals, especially ruminants, but has the capacity to infect humans and result in outbreaks. Infection with the causative agent, RVF virus (RVFV), causes severe disease in domestic animals, especially sheep, resulting in fever, anorexia, immobility, abortion, and high morbidity and mortality rates in neonate animals. Humans become infected through exposure to infected animals and, less frequently, directly via a mosquito bite. A greater awareness of RVFV and its epidemic potential has resulted in increased investment in the development of interventions, especially vaccines. There is currently no substitute for the use of animal models in order to evaluate these vaccines. As outbreaks of RVF disease are difficult to predict or model, conducting Phase III clinical trials will likely not be feasible. Therefore, representative animal model systems are essential for establishing efficacy data to support licensure. Nonhuman primate (NHP) species are often chosen due to their closeness to humans, reflecting similar susceptibility and disease kinetics. This review covers the use of NHP models in RVFV research, with much of the work having been conducted in rhesus macaques and common marmosets. The future direction of RVF work conducted in NHP is discussed in anticipation of the importance of it being a key element in the development and approval of a human vaccine.
Phytotoxic Activity of Sesquiterpene Lactones-Enriched Fractions from Cynara cardunculus L. Leaves on Pre-Emergent and Post-Emergent Weed Species and Putative Mode of Action
Authors: Rosa Daniela , Rial Carlos , Brás Teresa , Varela Rosa M. , Macías Francisco A. , Duarte Maria F.
Published: October 2024

Sesquiterpene lactones (SLs) are compounds that are highly produced in Cynara cardunculus leaves, known for their phytotoxic activity. This study aims to assess SL-enriched fractions’ (cynaropicrin, aguerin B, and grosheimin) phytotoxic potentials and putative modes of action, compared to an initial extract, using two approaches: first, against a panel of nine weed species in pre-emergence, and then on Portulaca oleracea L.’s post-emergency stage. The SL-enriched fractions demonstrated greater phytotoxic activity when compared with the C. cardunculus leaf initial extract. The SL-enriched fractions had higher activity at root growth inhibition over the panel tested, doubling the activity in five of them at 800 ppm. Regarding the post-emergence bioassay, the SL-enriched fractions had a higher influence on the plants’ growth inhibition (67% at 800 ppm). The SL-effects on the plants’ metabolisms were evidenced. The total chlorophyll content was reduced by 65% at 800 ppm. Oxidative stress induction was observed because of the enhancement in MDA levels at 800 ppm compared to control (52%) and the decrease in SOD-specific activity from 4.20 U/mg protein (400 ppm) to 1.74 U/mg protein (800 ppm). The phytotoxic effects of the SL-enriched fractions suggest that they could be used for a future bioherbicide development.
Behavioral, Physiological, and Molecular Mechanisms Underlying the Adaptation of Helicoverpa armigera to the Fruits of a Marginal Host: Walnut (Juglans regia)
Authors: Li Haiqiang , Huang Xinzheng , Yang Long , Liu Haining , Liu Bing , Lu Yanhui
Published: October 2024

In northwest China, changes in cultivation patterns and the scarcity of preferred hosts have forced Helicoverpa armigera to feed on the marginal host walnut (Juglans regia). However, the mechanisms allowing this adaptation remain poorly understood. Here, we investigated the behavioral, physiological, and molecular mechanisms underlying the local adaptation of this pest to walnut fruits. The green husk and shell generally contained higher levels of phytochemicals than the kernel. Bioassays revealed that the phytochemical-rich green husk and shell were less preferred, reduced larval fitness and growth, and elevated the activity of detoxification enzymes compared to the nutrient-rich kernel, which were further supported by a larger number of upregulated detoxification genes in insects fed green husks or shells based on transcriptome sequencing. Together, these data suggest that P450 genes (LOC110371778) may be crucial to H. armigera adaptation to the phytochemicals of walnuts. Our findings provide significant insight into the adaptation of H. armigera to walnut, an alternative host of lower quality. Meanwhile, our study provides a theoretical basis for managing resistance to H. armigera larvae in walnut trees and is instrumental in developing comprehensive integrated pest management strategies for this pest in walnut orchards and other agricultural systems.
Agricultural Pest Management: The Role of Microorganisms in Biopesticides and Soil Bioremediation
Authors: Vermelho Alane Beatriz , Moreira Jean Vinícius , Akamine Ingrid Teixeira , Cardoso Veronica S. , Mansoldo Felipe R. P.
Published: October 2024

Pesticide use in crops is a severe problem in some countries. Each country has its legislation for use, but they differ in the degree of tolerance for these broadly toxic products. Several synthetic pesticides can cause air, soil, and water pollution, contaminating the human food chain and other living beings. In addition, some of them can accumulate in the environment for an indeterminate amount of time. The agriculture sector must guarantee healthy food with sustainable production using environmentally friendly methods. In this context, biological biopesticides from microbes and plants are a growing green solution for this segment. Several pests attack crops worldwide, including weeds, insects, nematodes, and microorganisms such as fungi, bacteria, and viruses, causing diseases and economic losses. The use of bioproducts from microorganisms, such as microbial biopesticides (MBPs) or microorganisms alone, is a practice and is growing due to the intense research in the world. Mainly, bacteria, fungi, and baculoviruses have been used as sources of biomolecules and secondary metabolites for biopesticide use. Different methods, such as direct soil application, spraying techniques with microorganisms, endotherapy, and seed treatment, are used. Adjuvants like surfactants, protective agents, and carriers improve the system in different formulations. In addition, microorganisms are a tool for the bioremediation of pesticides in the environment. This review summarizes these topics, focusing on the biopesticides of microbial origin.
Optimizing Underground Natural Gas Storage Capacity through Numerical Modeling and Strategic Well Placement
Authors: Eparu Cristian Nicolae , Prundurel Alina Petronela , Doukeh Rami , Stoica Doru Bogdan , Ghețiu Iuliana Veronica , Suditu Silviu , Stan Ioana Gabriela , Rădulescu Renata
Published: October 2024

This study focuses on optimizing the storage capacity of an underground natural gas storage facility through numerical modeling and simulation techniques. The reservoir, characterized by an elongated dome structure, was discretized into approximately 16,000 cells. Simulations were conducted using key parameters such as permeability (10–70 mD) and porosity (12–26%) to assess the dynamics of gas injection and pressure distribution. The model incorporated core and petrophysical data to accurately represent the reservoir’s behavior. By integrating new wells in areas with storage deficits, the model demonstrated improvements in storage efficiency and pressure uniformity. The introduction of additional wells led to a significant increase in storage volume from 380 to 512 million Sm³ and optimized the injection process by reducing the storage period by 25%. The study concludes that reservoir performance can be enhanced with targeted well placement and customized flow rates, resulting in both increased storage capacity and economic benefits.
A Feasibility Study for the Hot-Air-Assisted Reflow Soldering Process Based on Computational Fluid Dynamics
Authors: Kanjad Natcha , Chanbandit Chanapat , Thongsri Jatuporn
Published: October 2024

In hard disk drive (HDD) manufacturing, a reflow soldering process (RSP) employs heat generated at the welding tip (WT) to bond tiny electrical components for assembling an HDD. Generally, the heat was generated by an electric current applied to the WT. This article reports a feasibility study of using hot air based on computational fluid dynamics (CFD), a choice to assist heat generation. First, the WT and hot air tube (HAT) prototypes were designed and created. The HAT is a device that helps to supply hot air directly to generate heat at the WT. Then, the experiment was established to measure the temperature (T) supplied by the hot air. The measure results were employed to validate the CFD results. Next, the prototype HAT was used to investigate the T generated at the WT by CFD. The comparison revealed that the T measured by the experiment was in the 106.2 °C–133.5 °C range and that the CFD was in the 107.3 °C–136.6 °C range. The maximum error of the CFD results is 2.3% compared to the experimental results, confirming the credibility of the CFD results and methodology. The CFD results revealed that the operating conditions, such as WT, HAT designs, hot air inlet velocity, and inlet temperature, influence the T. Last, examples of suitable operating conditions for using hot air were presented, which confirmed that hot air is a proper choice for a low-temperature RPS.
Trends and Factors Influencing Surgical Choices for Femoral Neck Fractures
Authors: Gan-Or Hadar , Maman David , Mahamid Assil , Finkel Binyamin , Takrori Loai Ahmad , Behrbalk Eyal , Berkovich Yaron
Published: October 2024

Introduction: Femoral neck fractures pose significant health risks, particularly in the elderly population, leading to mortality, morbidity, and decreased quality of life. Surgery is the preferred treatment to restore function and alleviate pain, with options including total hip arthroplasty (THA) and hemiarthroplasty (HA). However, clinical guidelines for selecting surgical procedures remain heterogeneous, prompting the need for further investigation into treatment trends and influencing factors. Methods: Data from the NIS database spanning 2016–2019 were analyzed, focusing on patients diagnosed with intracapsular femoral neck fractures and undergoing THA or HA as primary in-hospital surgeries. Advanced statistical analyses using SPSS and MATLAB were conducted to identify trends and factors influencing surgical choices. Results: Comorbidity profiles varied significantly between HA and THA patients, with specific conditions such as Alzheimer’s disease showing higher prevalence in HA patients. Demographic differences included a higher proportion of females and Medicare-insured individuals in the HA group. Racial disparities were observed, with differences in surgical preferences among various ethnic groups. THA adoption gradually increased over the study period, indicating a shift in surgical priorities. Additionally, THA patients tended to be younger on average compared with HA patients. Conclusions: This study highlights evolving trends in surgical management for femoral neck fractures and identifies factors influencing treatment decisions in our cohort. Understanding these trends and disparities is crucial for optimizing patient care and informing future clinical guidelines. Further research should focus on assessing different surgical approaches’ long-term outcomes and cost-effectiveness.