bluuebunny/crossref_metadata_2025 huggingface dataset:
Assessing Health Care Providers’ Knowledge and Practices of Nutrition during Pregnancy in Lebanon: A Cross-Sectional Study
Authors: Rizk Jessy , Andreou Eleni , Hileti Dona , Ghaddar Ali , Zampelas Antonis
Published: August 2023

Background and objectives: Health care professionals (HCPs) are well-positioned to discuss healthy behaviors during pregnancy, but the published research of prenatal healthcare providers’ knowledge about the significance of nutrition during pregnancy in Lebanon is scarce. The purpose of this study was to explore the knowledge, attitudes, and practices of Lebanese prenatal healthcare providers towards nutrition during pregnancy. Materials and Methods: A cross-sectional study using an online questionnaire was conducted. Health care providers were contacted by phone and email to participate in the online survey. A list of all clinics providing antenatal health services was obtained from the Order of Physicians and the Order of Midwives. A multistage random sample was selected. In the first stage, it was stratified per region (Beirut center or suburbs, and the southern region). In the second phase, it was stratified per clinic type (private, primary healthcare center, or hospital). Gynecologists and midwives who are members of the Order of Physicians and the Order of Midwives (n = 1333), were included. Results: Two-hundred and six responses (55% males) were obtained. Approximately 44% of the HCP were aged 50 and older, and 68.4% had more than 10 years of work experience. HCPs from Beirut represented 41.3% of the respondents. Eighty-eight percent of the HCPs were physicians, and 11% were midwives. The majority of the participants considered nutrition during pregnancy to be very important. Furthermore, half of these participants considered their position in delivering nutrition information as very significant. Most of the respondents reported that they provide nutrition advice to pregnant women, and they also received nutrition education during their profession. However, they perceived their nutrition knowledge as inadequate. Conclusion: Health care providers’ attitude towards the importance of maternal nutrition and their confidence in talking about nutrition-related topics with pregnant women were positive despite the lack of knowledge in several areas related to nutrition during pregnancy. Therefore, there is a need for continuing nutrition education for health care providers and the implementation of nutrition education programs to achieve better health outcomes.
Performance Analysis and Experimental Research of a Dual-Vibrator Traveling Wave Ultrasonic Motor
Authors: Dong Zhaopeng , Xu Liang
Published: August 2023

In order to facilitate the widespread application of ultrasonic motors, it is essential to conduct a quantitative study aimed at enhancing their performance. The present paper provides a comprehensive theoretical analysis of an ultrasonic motor equipped with dual vibrators, enabling operation in both the single-driven and dual-driven modes, thereby enhancing versatility in terms of performance adjustment. This study provides a detailed examination of the motor’s unique performance characteristics and its varying output responses to different driving signals. Experimental investigations are conducted in both the single-driven and dual-driven modes to validate theoretical predictions. The results demonstrate that the motor exhibits a maximum speed, torque, and power that are 1.59, 1.28, and 1.62 times higher than those of the single-driven stator, respectively. A conclusion can be drawn that the motor will attain the desired performance when operated in the appropriate driven mode.
A Highly Efficient Electromagnetic Wave Absorption System with Graphene Embedded in Hybrid Perovskite
Authors: Yu Haitao , Liu Hui , Yao Yao , Xiong Ziming , Gao Lei , Yang Zhiqian , Zhou Wenke , Zhang Zhi
Published: August 2023

To cope with the explosive increase in electromagnetic radiation intensity caused by the widespread use of electronic information equipment, high-performance electromagnetic wave (EMW)-absorbing materials that can adapt to various frequency bands of EMW are also facing great demand. In this paper, CH3NH3PbI3/graphene (MG) high-performance EMW-absorbing materials were innovatively synthesized by taking organic–inorganic hybrid perovskite (OIHP) with high equilibrium holes, electron mobility, and accessible synthesis as the main body, graphene as the intergranular component, and adjusting the component ratio. When the component ratio was 16:1, the thickness of the absorber was 1.87 mm, and MG’s effective EMW absorption width reached 6.04 GHz (11.96–18.00 GHz), achieving complete coverage of the Ku frequency band. As the main body of the composite, CH3NH3PbI3 played the role of the polarization density center, and the defects and vacancies in the crystal significantly increased the polarization loss intensity; graphene, as a typical two-dimensional material distributed in the crystal gap, built an efficient electron transfer channel, which significantly improved the electrical conductivity loss strength. This work effectively broadened the EMW absorption frequency band of OIHP and promoted the research process of new EMW-absorbing materials based on OIPH.
Antibacterial, Antibiofilm, and Anti-Inflammatory Activities of Ginger Extract against Helicobacter pylori
Authors: Elbestawy Mahmoud K. M. , El-Sherbiny Gamal M. , Moghannem Saad A. , Farghal Eman E.
Published: August 2023

The increased emergence of multidrug-resistant Helicobacter pylori is related to many health issues. Zingiber officinale (Z. officinale) is a plant usually used in folk medicine to treat a variety of diseases. This study was conducted to evaluate the ability of Z. officinale extract to combat resistant H. pylori. The disc diffusion, microdilution, and microplate assays were performed to evaluate the susceptibility to antibiotics and the antibacterial and antibiofilm activities of the Z. officinale extracts. Using the checkerboard method, the combined effects of gentamicin and Z. officinale extract were investigated. In addition, anti-inflammatory activity and GC-MS analysis were performed according to a modified protocol. According to the findings, H. pylori isolates exhibited resistance rates of 56.33, 50.0, and 45.85 against metronidazole, gentamicin, and tetracycline, respectively. The methanolic extract of Z. officinale showed the strongest effectiveness against resistant H. pylori isolates with MICs of 20.0 to 50.0 µg/mL, including both H. pylori isolates and the standard strain NCTC 11637. Z. officinale extract suppresses the biofilm formed by H. pylori isolates with a percentage of 92.96% at 50.0 µg/mL, compared with 97.19% for gentamicin at the same concentration. According to FICI values, the combination of methanolic Z. officinale extract with gentamicin increases bacterial sensitivity to such drugs. Moreover, the Z. officinale extract exhibits strong anti-inflammatory activity, with inhibition of red blood cell membrane stabilization increasing from 49.83% to 61.47% at a concentration of 4 to 32 µg/mL. The GC-MS analysis of Z. officinale extract exhibits 17 different chemical compounds. Besides showing antibacterial properties, the extract also contains the anti-inflammatory compound gingerol as the main constituent, which inhibits the growth of H. pylori and its biofilm and is a promising natural therapeutic alternative or enhances antibiotic activity.
Geochemical Characteristics and Geological Significance of Black Shale at the Bottom of the Mufushan Formation in the Lower Cambrian, Lower Yangtze Platform, South China
Authors: Li Jiaqi , Kang Zhihong , Kang Zhijiang , Zhang Xuemei
Published: August 2023

Black shale, as an important unconventional energy resource, has attracted significant attention in recent years. By studying its sedimentary and geochemical characteristics, it is possible to reconstruct ancient depositional environments and paleoclimatic conditions. The Lower Cambrian black shale is widely distributed in the Lower Yangtze region, but its tectonic background and provenance have been subject to debate. In this study, we conducted geochemical testing and analysis on samples collected from the basal black shale of the Mufushan Formation in the Mufushan section, Nanjing. The Th/Sc-Zr/Sc diagram indicates that the black shale of the Mufushan Formation has not undergone sedimentary recycling. Analysis of major element ratios, rare earth element (REE) distribution patterns, δEu, (La/Yb)N, and the La/Th-Hf and La/Yb-∑REE discrimination diagrams suggest that the source rocks of the black shale mainly consist of granites and sedimentary rocks rich in ferromagnesian minerals, representing felsic rocks derived from the upper crust, with some involvement of mafic rocks. Considering the provenance attributes, geological age relationships, and tectonic evolution of the South China continent, the granite component in the source rocks is inferred to have formed during Neoproterozoic magmatic activity, and the source area corresponds to the Jiangnan Orogenic Belt. Analysis of K2O + Na2O-SiO2, K2O/Na2O-SiO2/Al2O3, La-Th-Sc, Th-Co-Zr/10, and Th-Sc-Zr/10 diagrams suggests that the source area of the Mufushan Formation black shale was a passive continental margin.
A Meta-Analysis of Influencing Factors on the Activity of BiVO4-Based Photocatalysts
Authors: Che Ruijie , Zhu Yining , Tu Biyang , Miao Jiahe , Dong Zhongtian , Liu Mengdi , Wang Yupeng , Li Jining , Chen Shuoping , Wang Fenghe
Published: August 2023

With the continuous advancement of global industrialization, a large amount of organic and inorganic pollutants have been discharged into the environment, which is essential for human survival. Consequently, the issue of water environment pollution has become increasingly severe. Photocatalytic technology is widely used to degrade water pollutants due to its strong oxidizing performance and non-polluting characteristics, and BiVO4-based photocatalysts are one of the ideal raw materials for photocatalytic reactions. However, a comprehensive global analysis of the factors influencing the photocatalytic performance of BiVO4-based photocatalysts is currently lacking. Here, we performed a meta-analysis to investigate the differences in specific surface area, kinetic constants, and the pollutant degradation performance of BiVO4-based photocatalysts under different preparation and degradation conditions. It was found that under the loading condition, all the performances of the photocatalysts can be attributed to the single BiVO4 photocatalyst. Moreover, loading could lead to an increase in the specific surface area of the material, thereby providing more adsorption sites for photocatalysis and ultimately enhancing the photocatalytic performance. Overall, the construct heterojunction and loaded nanomaterials exhibit a superior performance for BiVO4-based photocatalysts with 136.4% and 90.1% improvement, respectively. Additionally, within a certain range, the photocatalytic performance increases with the reaction time and temperature.
Low-Cost Shadow Mask Fabrication for Nanoelectronics
Authors: Pucher Thomas , Bastante Pablo , Sánchez Viso Estrella , Castellanos-Gomez Andres
Published: August 2023

We present two approaches for fabricating shadow masks for the evaporation of electrodes onto nanomaterials. In the first one, we combine the use of a commercial fiber laser engraving system with readily available aluminum foil. This method is suitable for fabricating shadow masks with line widths of 50 µm and minimum feature separation of 20 µm, and using it to create masks with complex patterns is very straightforward. In the second approach, we use a commercially available vinyl cutting machine to pattern a vinyl stencil mask, and we use a glass fiber to define the separation between the electrodes. With this approach, we achieve well-defined electrodes separated by 15 µm, but this technique is less versatile in creating complex masks as compared with the laser-based one. We demonstrate the potential of these techniques by fabricating field-effect transistor devices based on MoS2. Our approach is a cost-effective and easily accessible method for fabricating shadow masks with high resolution and accuracy, making it accessible to a wider range of laboratories.
Effectiveness of a Smartphone Application for Dietary Sodium Intake Measurement
Authors: Jung Chan-Young , Kim Youngin , Kim Hyung Woo , Han Seung Hyeok , Yoo Tae-Hyun , Kang Shin-Wook , Park Jung Tak
Published: August 2023

Accurate estimation of sodium intake is a key requirement for evaluating the efficacy of interventional strategies to reduce salt intake. The effectiveness of a smartphone application in measuring dietary sodium intake was assessed. This study included 46 participants who consented to register in Noom’s food-logging program. All participants were followed up for six months from the day of enrollment. The mean age of the participants was 40.2 ± 12.3 years, and 22 (48%) participants were male. The average number of times/weeks the meals were logged was 16.2 ± 10.3. At baseline, the mean 24-h urine sodium was 124.3 mmol/24 h. The mean sodium intake measured by the smartphone application and calculated using the 24-h urine sodium was 2020.9 mg/24 h and 2857.6 mg/24 h, respectively. During the second visit, the mean 24-h urine sodium was 117.4 mmol/24 h. The mean sodium intake measured by the smartphone application and calculated using the 24-h urine sodium was 1456.0 mg/24 h and 2698.3 mg/24 h, respectively. Sodium intake measured using the smartphone application positively correlated with that calculated using the 24-h urine sodium at baseline (r = 0.464; p < 0.001) and follow-up (r = 0.334; p= 0.023). Dietary sodium intake measured using a smartphone application correlated well with that estimated using 24-h urine sodium level.
Evaluation of Junk Food Consumption and the Risk Related to Consumer Health among the Romanian Population
Authors: Mititelu Magdalena , Oancea Carmen-Nicoleta , Neacșu Sorinel Marius , Musuc Adina Magdalena , Gheonea Theodora Claudia , Stanciu Tiberius Iustinian , Rogoveanu Ion , Hashemi Fallah , Stanciu Gabriela , Ioniță-Mîndrican Corina-Bianca , Belu Ionela , Măru Nicoleta , Olteanu Gabriel , Cîrțu Alexandru-Tiberiu , Stoicescu Iuliana , Lupu Carmen Elena
Published: August 2023

Premature aging and degradative processes are mainly generated by unhealthy habits and an unbalanced diet. Quality of food and lifestyle are important factors in sano-genesis. Many imbalances and ailments have their origin in the adoption of an unbalanced diet and a disordered lifestyle. With the help of a transversal study carried out on the basis of a questionnaire, the consumption of junk food products among the population of Romania was evaluated; at the same time, an evaluation of the characteristics of the associated diet, as well as a series of lifestyle components (quality of rest, physical activity, evaluation of the state of health) was carried out. The data collected and processed indicate an increased tendency to consume junk food products in the 18–23 age group, and especially among obese respondents. Female respondents show a lower tendency toward an increased consumption of junk food products (OR = 0.703, 95% CI)—0.19–0.95, p = 0.011) compared to male respondents. The most consumed junk food products are fried potatoes (46.2%) and pastries (41.4%). Junk food products that show an increased tendency toward consumption addiction are fried potatoes (13.8%), sweets (12.4%), pastry products (11.1%), and sweetened drinks (11.2%). The poor quality of food from a nutritional point of view, and reduced physical activity, are reflected in the varied range of problems faced by the respondents: states of fatigue (62.4%), nervousness (37.5%), depression, anxiety, emotional eating, etc.
Eating Behavior and Factors of Metabolic Health in Primary Schoolchildren: A Cross-Sectional Study in Greek Children
Authors: Gioxari Aristea , Amerikanou Charalampia , Peraki Sevasti , Kaliora Andriana C. , Skouroliakou Maria
Published: August 2023

Childhood obesity has been associated with altered blood lipids and bad eating habits. In this cross-sectional study, we assessed cardiorespiratory fitness and metabolic health markers in regard to weight status and dietary habits in schoolchildren. In 134 children (6–11 years), we conducted: (1) Anthropometry, namely z-score BMI (z-BMI), waist-to-height ratio (WHtR), and body composition analysis. (2) Measurements of handgrip strength (HGS), resting metabolic rate (RMR) and VO2max. (3) Quantification of blood lipids and antioxidant vitamins A, E, C. (4) Eating breakfast assessment. About 35% of children were overweight/obese. The z-BMI positively correlated with WHtR (r = 0.637, p < 0.001), and adversely correlated with fat-free mass (r = −0.728, p < 0.001) and vitamin E (r = −0.286, p < 0.001). RMR and VO2max were greater in normal weight children compared to those with overweight/obesity (p < 0.001). HGS did not differ between these groups, but was negatively correlated with dyslipidemia as shown by TG/HDL-C ratio (r = −0.224, p = 0.037). According to regression analysis, eating breakfast routinely at home was positively associated with RMR and adversely associated with z-BMI. Hence, regular breakfast consumption at home may improve RMR in kids. Cardiorespiratory fitness and physical strength are key modulators of metabolic health in Greek children added to a social determinant of health i.e., eating breakfast at home.
Association of 25-Hydroxyvitamin D with Preterm Birth and Premature Rupture of Membranes: A Mendelian Randomization Study
Authors: Cheng Haoyue , Chi Peihan , Zhuang Yan , Alifu Xialidan , Zhou Haibo , Qiu Yiwen , Huang Ye , Zhang Libi , Ainiwan Diliyaer , Peng Zhicheng , Si Shuting , Liu Hui , Yu Yunxian
Published: August 2023

Low vitamin D (VitD) level is a risk factor for preterm birth (PTB), but the results of previous studies remained inconsistent, which may be influenced by the confounding factors and different types of PTB. We performed Mendelian randomization (MR) to uncover the association of 25-hydroxyvitamin D (25(OH)D) with PTB, premature rupture of membranes (PROM), and preterm premature rupture of membranes (PPROM). This study was conducted in Zhoushan Maternal and Child Health Hospital, Zhejiang, from August 2011 to March 2022. Plasma 25(OH)D levels in three trimesters of pregnancy were measured. We conducted an MR analysis utilizing a genetic risk score (GRS) approach, which was based on VitD-associated single-nucleotide polymorphisms. The prospective cohort study included 3923 pregnant women. The prevalence of PTB, PROM, and PPROM were 6.09%, 13.18%, and 1.33%, respectively. Compared to those without vitamin D deficiency (VDD), only vaginally delivering pregnant women with VDD had a 2.69 (1.08–6.68) times risk of PTB. However, MR analysis did not support the association. One-unit higher GRS was not associated with an increased risk of PTB, regardless of the trimesters (OR [95% CI]: 1.01 [0.93–1.10], 1.06 [0.96–1.18], and 0.95 [0.82–1.10], respectively). When further taking PROM and PPROM as the outcomes, the MR analysis also showed no consistent evidence of a causal effect of VitD levels on the risk of them. Our MR analyses did not support a causal effect of 25(OH)D concentrations in the three trimesters on PTB, PROM, and PPROM.
Narrow-Linewidth 852-nm DBR-LD with Self-Injection Lock Based on High-Finesse Optical Cavity Filtering
Authors: Hao Lili , Chang Rui , Hou Xiaokai , He Jun , Wang Junmin
Published: August 2023

Narrow-linewidth lasers have a high spectral purity, long coherent length, and low phase noise, so they have important applications in atomic clocks, precision measurement, and quantum computing. We inject a transmitted laser from a narrow-linewidth (∼15 kHz) flat-concave Fabry–Perot (F-P) cavity made from ultra-low expansion (ULE) optical glass into an 852 nm distributed Bragg reflector-type laser diode (DBR-LD), of which the comprehensive linewidth is 1.67 MHz for the free running case. With an increase in the self-injection power, the laser linewidth gradually narrows, and the injection locking current range gradually increases. The narrowest linewidth measured by the delayed frequency-shifted self-heterodyne (DFSSH) method is about 365 Hz, which is about 1/4500 of the linewidth for the free running case. Moreover, to characterize the laser phase noise, we use a detuned F-P cavity to measure the conversion signal from the laser phase noise to the intensity noise for both the free running case and the self-injection lock case. The laser phase noise for the self-injection lock case is significantly suppressed in the analysis frequency range of 0.1–10 MHz compared to the free running case. In particular, the phase noise is suppressed by more than 30 dB at an analysis frequency of 100 kHz.
Variation in the Drought Tolerance of Tropical Understory Plant Communities across an Extreme Elevation and Precipitation Gradient
Authors: Bravo-Avila Catherine H. , Feeley Kenneth J.
Published: August 2023

Little is known about how differences in water availability within the “super humid” tropics can influence the physiology of understory plant species and the composition of understory plant communities. We investigated the variation in the physiological drought tolerances of hundreds of understory plants in dozens of plant communities across an extreme elevation and precipitation gradient. Specifically, we established 58 understory plots along a gradient of 400–3600 m asl elevation and 1000–6000 mm yr−1 rainfall in and around Manu National Park in southeastern Peru. Within the plots, we sampled all understory woody plants and measured three metrics of physiological leaf drought tolerance—turgor loss point (TLP), cuticular conductance (Gmin), and solute leakage (SL)—and assessed how the community-level means of these three traits related to the mean annual precipitation (MAP) and elevation (along the study gradient, the temperature decreases linearly, and the vapor pressure deficit increases monotonically with elevation). We did not find any correlations between the three metrics of leaf drought tolerance, suggesting that they represent independent strategies for coping with a low water availability. Despite being widely used metrics of leaf drought tolerance, neither the TLP nor Gmin showed any significant relationships with elevation or the MAP. In contrast, SL, which has only recently been developed for use in ecological field studies, increased significantly at higher precipitations and at lower elevations (i.e., plants in colder and drier habitats have a lower average SL, indicating greater drought tolerances). Our results illustrate that differences in water availability may affect the physiology of tropical montane plants and thus play a strong role in structuring plant communities even in the super humid tropics. Our results also highlight the potential for SL assays to be efficient and effective tools for measuring drought tolerances in the field.
Effect Analysis of Hydrogen Peroxide Using Hyperspectral Reflectance in Sorghum [Sorghum bicolor (L.) Moench] under Drought Stress
Authors: Song Ki Eun , Hong Se Sil , Hwang Hye Rin , Hong Sun Hee , Shim Sang-in
Published: August 2023

Due to global climate change, adverse environments like drought in agricultural production are occurring frequently, increasing the need for research to ensure stable crop production. This study was conducted to determine the effect of artificial hydrogen peroxide treatment on sorghum growth to induce stress resistance in drought conditions. Hyperspectral analysis was performed to rapidly find out the effects of drought and hydrogen peroxide treatment to estimate the physiological parameters of plants related to drought and calculate the vegetation indices through PLS analysis based on hyperspectral data. The partial least squares (PLS) analysis collected chlorophyll fluorescence variables, photosynthetic parameters, leaf water potential, and hyperspectral reflectance during the stem elongation and booting stage. To find out the effect of hydrogen peroxide treatment in sorghum plants grown under 90% and 60% of field capacity in greenhouses, growth and hyperspectral reflectance were measured on the 10th and 20th days after foliar application of H2O2 at 30 mM from 1st to 5th leaf stage. The PLS analysis shows that the maximum variable fluorescence of the dark-adapted leaves was the most predictable model with R2 = 0.76, and the estimation model suitability gradually increased with O (R2 = 0.51), J (R2 = 0.73), and P (R2 = 0.75) among OJIP parameters of chlorophyll fluorescence analysis. However, the estimation suitability of predictions for moisture-related traits, vapor pressure deficit (VPD, R2 = 0.18), and leaf water potential (R2 = 0.15) using hyperspectral data was low. The hyperspectral reflectance was 10% higher at 20 days after treatment (DAT) and 3% at 20 DAT than the non-treatment in the far red and infra-red light regions under drought conditions. Vogelmann red edge index (VOG REI) 1, chlorophyll index red edge (CIR), and red-edge normalized difference vegetation index (RE-NDVI) efficiently reflected moisture stress among the vegetation indices. Photochemical reflectance index (PRI) can be used as an indicator for early diagnosis of drought stress because hydrogen peroxide treatment showed higher values than untreated in the early stages of drought damage.
A Model for the Determination of Potato Tuber Mass by the Measurement of Carbon Dioxide Concentration
Authors: Rumiantsev Boris , Dzhatdoeva Sofya , Sadykhov Elchin , Kochkarov Azret
Published: August 2023

The implementation of advanced precision farming systems, which are becoming relevant due to rapid technological development, requires the invention of new approaches to the diagnostics and control of the growing process of cultivated crops. This is especially relevant for potato, as it is one of the most demanded crops in the world. In the present work, an analytic model of the dependence of potato tubers mass on carbon dioxide concentration under cultivation in a closed vegetation system is presented. The model is based on the quantitative description of starch molecule synthesis from carbon dioxide under photosynthesis. In the frame of this work, a comprehensive description of the proposed model is presented, and the verification of this model was conducted on the basis of experimental data from a closed urban vertical farm with automated climate control. The described model can serve as a basis for the non-contact non-invasive real-time measurement of potato tuber mass under growth in closed vegetation systems, such as vertical farms and greenhouses, as well as orbital and space crop production systems.
Unraveling the Molecular Mechanisms of Tomatoes’ Defense against Botrytis cinerea: Insights from Transcriptome Analysis of Micro-Tom and Regular Tomato Varieties
Authors: Tian Shifu , Liu Bojing , Shen Yanan , Cao Shasha , Lai Yinyan , Lu Guodong , Wang Zonghua , Wang Airong
Published: August 2023

Botrytis cinerea is a devastating fungal pathogen that causes severe economic losses in global tomato cultivation. Understanding the molecular mechanisms driving tomatoes’ response to this pathogen is crucial for developing effective strategies to counter it. Although the Micro-Tom (MT) cultivar has been used as a model, its stage-specific response to B. cinerea remains poorly understood. In this study, we examined the response of the MT and Ailsa Craig (AC) cultivars to B. cinerea at different time points (12–48 h post-infection (hpi)). Our results indicated that MT exhibited a stronger resistant phenotype at 18–24 hpi but became more susceptible to B. cinerea later (26–48 hpi) compared to AC. Transcriptome analysis revealed differential gene expression between MT at 24 hpi and AC at 22 hpi, with MT showing a greater number of differentially expressed genes (DEGs). Pathway and functional annotation analysis revealed significant differential gene expression in processes related to metabolism, biological regulation, detoxification, photosynthesis, and carbon metabolism, as well as some immune system-related genes. MT demonstrated an increased reliance on Ca2+ pathway-related proteins, such as CNGCs, CDPKs, and CaMCMLs, to resist B. cinerea invasion. B. cinerea infection induced the activation of PTI, ETI, and SA signaling pathways, involving the modulation of various genes such as FLS2, BAK1, CERK1, RPM, SGT1, and EDS1. Furthermore, transcription factors such as WRKY, MYB, NAC, and AUX/IAA families played crucial regulatory roles in tomatoes’ defense against B. cinerea. These findings provide valuable insights into the molecular mechanisms underlying tomatoes’ defense against B. cinerea and offer potential strategies to enhance plant resistance.
Polyisobutylenes with Controlled Molecular Weight and Chain-End Structure: Synthesis and Actual Applications
Authors: Nifant’ev Ilya E. , Korchagina Sofia A. , Chinova Maria S. , Tavtorkin Alexander N.
Published: August 2023

The polymerization of isobutylene allows us to obtain a wide spectrum of polyisobutylenes (PIBs) which differ in their molecular weight characteristics and the chemical structure of chain-end groups. The bulk of the PIBs manufactured worldwide are highly reactive polyisobutylenes (HRPIBs) with –C(Me)=CH2 end-groups and low-molecular weights (Mn < 5 kDa). HRPIBs are feedstocks that are in high demand in the manufacturing of additives for fuels and oils, adhesives, detergents, and other fine chemicals. In addition, HRPIBs and CMe2Cl-terminated PIBs are intensively studied with the aim of finding biomedical applications and for the purpose of developing new materials. Both chain control (molecular weight and dispersity) and chemoselectivity (formation of exo-olefinic or –CMe2Cl groups) should be achieved during polymerization. This review highlights the fundamental issues in the mechanisms of isobutylene polymerization and PIB analysis, examines actual catalytic approaches to PIBs, and describes recent studies on the functionalization and applications of HRPIBs and halogen-terminated PIBs.
Flexible Sensor Film Based on Rod-Shaped SWCNT-Polypyrrole Nanocomposite for Acetone Gas Detection
Authors: Kang Hyo-Kyung , Byeon Jun-Ho , Hwang Hyun-Jun , Jang Yoon Hee , Kim Jin-Yeol
Published: August 2023

A nanocomposite rod-shaped structure with a single-walled carbon nanotube (SWCNT) embedded in polypyrrole (PPy) doped with nonafluorobutanesulfonic acid (C4F), SWCNT/C4F-PPy, was synthesized using emulsion polymerization. The hybrid ink was then directly coated on a polyimide film interdigitated with the Cu/Ni/Au electrodes via a screen-printing technique to create a flexible film sensor. The sensor film showed a response of 1.72% at 25 °C/atmospheric pressure when acetone gas of 5 ppm was injected, which corresponds to almost 95% compared to the Si wafer-based array interdigitated with the Au electrode. Additionally, C4F was used as a hydrophobic dopant of PPy to improve the stability of humidity and to produce a highly sensitive film-type gas sensor that provides stable detection even in humid conditions.
Optimization of 3D Printing Parameters for Enhanced Surface Quality and Wear Resistance
Authors: Portoacă Alexandra Ileana , Ripeanu Razvan George , Diniță Alin , Tănase Maria
Published: August 2023

In recent years, there has been a growing interest in the field of 3D printing technology. Among the various technologies available, fused deposition modeling (FDM) has emerged as the most popular and widely used method. However, achieving optimal results with FDM presents a significant challenge due to the selection of appropriate process parameters. Therefore, the objective of this research was to investigate the impact of process parameters on the tribological and frictional behavior of acrylonitrile butadiene styrene (ABS) and polylactic acid (PLA) 3D-printed parts. The design of experiments (DOE) technique was used considering the input design parameters (infill percentage and layer thickness) as variables. The friction coefficient values and the wear were determined by experimental testing of the polymers on a universal tribometer employing plane friction coupling. Multi-response optimization methodology and analysis of variance (ANOVA) were used to highlight the dependency between the coefficient of friction, surface roughness parameters, and wear on the process parameters. The optimization analysis revealed that the optimal 3D printing input parameters for achieving the minimum coefficient of friction and linear wear were found to be an infill percentage of 50% and layer thickness of 0.1 mm (for ABS material), and an infill percentage of 50%, layer thickness of 0.15 mm (for PLA material). The suggested optimization methodology (which involves minimizing the coefficient of friction and cumulative linear wear) through the optimized parameter obtained provides the opportunity to select the most favorable design conditions contributing to a more sustainable approach to manufacturing by reducing overall material consumption.
Next-Generation Water Treatment: Exploring the Potential of Biopolymer-Based Nanocomposites in Adsorption and Membrane Filtration
Authors: Kolya Haradhan , Kang Chun-Won
Published: August 2023

This review article focuses on the potential of biopolymer-based nanocomposites incorporating nanoparticles, graphene oxide (GO), carbon nanotubes (CNTs), and nanoclays in adsorption and membrane filtration processes for water treatment. The aim is to explore the effectiveness of these innovative materials in addressing water scarcity and contamination issues. The review highlights the exceptional adsorption capacities and improved membrane performance offered by chitosan, GO, and CNTs, which make them effective in removing heavy metals, organic pollutants, and emerging contaminants from water. It also emphasizes the high surface area and ion exchange capacity of nanoclays, enabling the removal of heavy metals, organic contaminants, and dyes. Integrating magnetic (Fe2O4) adsorbents and membrane filtration technologies is highlighted to enhance adsorption and separation efficiency. The limitations and challenges associated are also discussed. The review concludes by emphasizing the importance of collaboration with industry stakeholders in advancing biopolymer-based nanocomposites for sustainable and comprehensive water treatment solutions.
Cohesion and Adhesion Performance of Tannin-Glyoxal Adhesives at Different Formulations and Hardener Types for Bonding Particleboard Made of Areca (Areca catechu) Leaf Sheath
Authors: Anggini Awanda , Lubis Muhammad , Sari Rita , Papadopoulos Antonios , Antov Petar , Iswanto Apri , Lee Seng , Mardawati Efri , Kristak Lubos , Juliana Ika
Published: August 2023

The use of alternative raw materials, such as agricultural biomass and by-products, in particleboard (PB) production is a viable approach to address the growing global demand for sustainable wood-based materials. The purpose of this study was to investigate the effect of the type of hardener and tannin-glyoxal (TG) adhesive formulation on the cohesion and adhesion performance of TG adhesives for areca-based PB. Two types of hardeners were used, NH4Cl and NaOH, and three adhesive formulations with tannin:glyoxal ratios (i.e., F1 (1:2), F2 (1:1), and F3 (2:1)) were applied to improve the cohesion performance and adhesion for areca-based TG adhesive for PB. The basic, chemical, and mechanical properties of the TG adhesive were investigated using a Fourier transform infrared spectrometer, rotational rheometer, dynamic mechanical analyzer (DMA), and X-ray diffractometer. The results show that a high glyoxal percentage increases the percentage of crystallinity in the adhesive. This shows that the increase in glyoxal is able to form better polymer bonds. DMA analysis shows that the adhesive is elastic and the use of NH4Cl hardener has better mechanical properties in thermodynamic changes than the adhesive using NaOH hardener. Finally, the adhesion performance of the TG adhesives on various types of hardeners and adhesive formulations was evaluated on areca-based PB panels. Regardless of the type of hardener, the TG adhesive made with F1 had better cohesion and adhesion properties compared to F2 and F3. Combining F1 with NH4Cl produced areca-based PB panels with better physical and mechanical qualities than the adhesive formulations F2 and F3, and complied with Type 8 particleboard according to SNI 03-2105-2006 standard.
Determination of Correlations between Melt Quality and the Screw Performance Index in the Extrusion Process
Authors: Trienens Dorte , Schöppner Volker , Bunse Robin
Published: August 2023

For polymer-processing extruders, designing screws via analytical computational models is helpful for reducing experimental costs. However, the current simulation programs cannot predict the melt quality at the screw tip with sufficient accuracy. There are a number of definitions of melt quality in the literature. This paper will review some of these definitions and present how melt quality can be assessed in subsequent work. In this paper, both the thermal and material homogeneity of the melt quality are examined for correlations with the screw performance index. If correlations exist with the screw performance index determined from direct experimental measurement data, these can be used as target values for developing a melt quality prediction model.
Preparation and Characterization of Dopamine-Modified Carbon Fiber Paper Composites for Gas Diffusion Layers
Authors: Ma Jiahua , Chen Xiangyu , Sun Xiaoshuai , Zhao Chuanshan
Published: August 2023

Carbon fibers (CFs) cannot be directly used for the preparation of CF paper because of their chemically inert nature. Herein, the surface of CFs was modified using the spontaneous oxidative self-polymerization of dopamine. By taking full advantage of the spontaneous oxidation and self-polymerization properties of PD to maintain the maximum strength of CFs, a polydopamine-modified CF paper (PDA-CFP) with excellent performance was prepared using PD-modified CFs (PDA-CFs). This increased the proportion of hydrophilic functional groups on the surface of carbon fibers, increased the O/C ratio on the CF surface by 6 times, and improved the bond strength between the modified CF and the adhesive by making full use of the interaction force between polydopamine and PVA fibers. In this way, the primary properties of the CF paper were improved. Overall, the results showed that the dispersion of CF was considerably improved with dopamine modification. In addition, the primary physical properties of PDA-CFP were better than those of virgin CF paper (CFP-0). PDA-CFP exhibited a maximum tensile strength of 2.04 kN·m−1, a minimum resistivity of 0.06055 Ω·cm−1, and a minimum porosity of 72.4%. The tightness was increased by up to 12.1%.
Study of Chemical Additives for Optimization of Binary Systems Used for Downhole Thermochemical Treatment of Heavy Oil
Authors: Anikin Oleg V. , Bolotov Alexander V. , Minkhanov Ilgiz F. , Tazeev Aidar R. , Varfolomeev Mikhail A. , Demin Sergey V. , Pchela Konstantin V. , Dyrkin Sergey M. , Amirov Albert A. , Kozlov Sergey A. , Frolov Dmitriy A. , Smirnov Evgeniy A. , Abramov Vladimir V.
Published: August 2023

Currently, most explored oil fields in Russia are at a late stage of development, and in order to maintain high levels of oil production, it is rational to put into operation fields with hard-to-recover reserves. For complicated oil fields, in particular fields with high-viscosity oil, the known traditional methods of development are ineffective. Therefore, the search for new technologies for the development and operation of such fields to significantly increase oil recovery and intensify production is of fundamental importance. One such method of heat treatment of the bottomhole formation zone is the use of heat and gas generating systems on site. In this work, new results were obtained on physical modeling of thermochemical reaction initiation with delayed-action catalyst (2,2-bis(hydroxymethyl)butanoic acid) filtration tests on composite core models of sandstone and carbonate with foam heat generation and initiating additives of binary type. Using hydrodynamic modelling, the results of laboratory studies were reproduced, and the preliminary efficiency of the developed technology for thermochemical treatment of deposits in the Samara region (Russia) was evaluated.
The Analysis of Lithosphere–Atmosphere–Ionosphere Coupling Associated with the 2022 Luding Ms6.8 Earthquake
Authors: Liu Jiang , Zhang Xuemin , Yang Xianhe , Yang Muping , Zhang Tiebao , Bao Zhicheng , Wu Weiwei , Qiu Guilan , Yang Xing , Lu Qian
Published: August 2023

Taking the Luding Ms6.8 earthquake (EQ) on 5 September 2022 as a case study, we investigated the potential seismic anomalies of the ionosphere, infrared radiation, atmospheric electrostatic field (AEF), and hot spring ions in the seismogenic region. Firstly, we analyzed the multi-parameter anomalies in the ionosphere around the epicenter and found synchronous anomalous disturbances in the ground parameters, namely the global ionospheric map (GIM), GPS, TEC, and satellite parameters, such as the He+ and O+ densities on 26 August under relatively quiet solar–geomagnetic conditions (F10.7 < 120 SFU; Kp < 3; Dst > −30 nT; |AE| < 500 nT). Next, both the anomaly analysis of the infrared radiation and AEF, and the survey results of the Luding EQ scientific expedition on the hot spring ions showed pre-seismic anomalous variations at different time periods in the seismogenic region. The characteristics of Earth’s multi-sphere coupling anomalies in temporal evolution and spatial distribution were obvious, which validated the Lithosphere–Atmosphere–Ionosphere Coupling (LAIC) mechanism. Finally, combining the analysis results and the LAIC mechanism, we suggested that the multi-sphere coupling anomalies were more likely associated with the Luding Ms6.8 EQ, and that the differential motion and the regional crustal stress accumulation between the Chuandian block and the Bayan Har block might have led to this EQ. Furthermore, remote sensing and ground-based monitoring technologies can play an important role in corroborating and compensating each other, while further study of the multi-sphere coupling mechanism will provide a clearer understanding of the seismogenic process for major EQs.
Using the InVEST-PLUS Model to Predict and Analyze the Pattern of Ecosystem Carbon storage in Liaoning Province, China
Authors: Li Pengcheng , Chen Jundian , Li Yixin , Wu Wen
Published: August 2023

Studying the spatiotemporal distribution pattern of carbon storage, balancing land development and utilization with ecological protection, and promoting urban low-carbon sustainable development are important topics under China’s “dual carbon strategy” (Carbon emissions stabilize and harmonize with natural carbon absorption). However, existing research has paid little attention to the impact of land use changes under different spatial policies on the provincial-scale ecosystem carbon storage. In this study, we established a carbon density database for Liaoning Province and obtained the spatial and temporal distribution of carbon storage over the past 20 years. Then, based on 16 driving factors and multiple spatial policies in Liaoning Province, we predicted land use and land cover changes (LUCC) under three scenarios for 2050 and analyzed the spatiotemporal distribution characteristics and response mechanisms of carbon storage under different scenarios. The results showed that (1) LUCC directly affected carbon storage, with a 35.61% increase in construction land and a decrease in carbon storage of 0.51 Tg over the 20-year period. (2) From 2020 to 2050, the carbon storage varied significantly among the natural trend scenario (NTS), ecological restoration scenario (ERS), and economic priority scenario (EPS), with values of 2112.05 Tg, 2164.40 Tg, and 2105.90 Tg, respectively. Carbon storage in the ecological restoration scenario exhibited positive growth, mainly due to a substantial increase in forest area. (3) The spatial pattern of carbon storage in Liaoning Province was characterized by “low in the center, high in the east, and balanced in the west”. Therefore, Liaoning Province can consider rationally formulating and strictly implementing the spatial policy of ecological protection in the future land planning so as to control the disorderly growth of construction land, realize the growth of ecological land area, effectively enhance carbon storage, and ensure the realization of the goal of “dual carbon strategy”.
High-Resolution National-Scale Mapping of Paddy Rice Based on Sentinel-1/2 Data
Authors: Huang Chenhao , You Shucheng , Liu Aixia , Li Penghan , Zhang Jianhua , Deng Jinsong
Published: August 2023

Rice has always been one of the major food sources for human beings, and the monitoring and planning of cultivation areas to maintain food security and achieve sustainable development is critical for this crop. Traditional manual ground survey methods have been recognized as being laborious, while remote-sensing technology can perform the accurate mapping of paddy rice due to its unique data acquisition capabilities. The recently emerged Google Earth Engine (GEE) cloud-computing platform was found to be capable of storing and computing the resources required for the rapid processing of massive quantities of remote-sensing data, thereby revolutionizing traditional analysis patterns and offering unique advantages for large-scale crop mapping. Since the phenology of paddy rice depends on local climatic conditions, and considering the vast expanse of China with its outstanding geospatial heterogeneity, a zoning strategy was proposed in this study to separate the monsoon climate zone of China into two regions based on the Qinling Mountain–Huaihe River Line (Q-H Line), while discrepant basic data and algorithms have been adopted to separately map mid-season rice nationwide. For the northern regions, optical indices have been calculated based on Sentinel-2 images, growth spectral profiles have been constructed to identify phenological periods, and rice was mapped using One-Class Support Vector Machine (OCSVM); for the southern regions, microwave sequences have been constructed based on Sentinel-1 images, and rice was mapped using Random Forest (RF). By applying this methodological system, mid-season rice at 10 m spatial resolution was mapped on the GEE for the entire Chinese monsoon region in 2021. According to the accuracy evaluation coefficients and publicly released local statistical yearbook data, the relative error of the mapped areas in each province was limited to 10%, and the overall accuracy exceeded 85%. The results could indicate that mid-season rice can be mapped more accurately and efficiently on a China-wide scale with relatively few samples based on the proposed zoning strategy and mapping methods. By adjusting the parameters, the time interval for mapping could also be further extended. The powerful cloud-computing competence of the GEE platform was used to map rice on a large spatial scale, and the results can help governments to ascertain the distribution of mid-season rice across the country in a short-term period, which would be well suited to meeting the increasingly efficient and fine-grained decision-making and management requirements.