bluuebunny/crossref_metadata_2025 huggingface dataset:
Functional Mapping of Genes Modulating Plant Shade Avoidance Using Leaf Traits
Authors: Zhang Han , Cao Yige , Wang Zijian , Ye Meixia , Wu Rongling
Published: January 2023

Shade avoidance syndrome (SAS) refers to a set of plant responses that increases light capture in dense stands. This process is crucial for plants in natural and agricultural environments as they compete for resources and avoid suboptimal conditions. Although the molecular, biochemical, and physiological mechanisms underlying the SAS response have been extensively studied, the genetic basis of developmental variation in leaves in regard to leaf area, petiole length, and leaf length (i.e., their allometric relationships) remains unresolved. In this study, with the recombinant inbred line (RIL) population, the developmental traits of leaves of Arabidopsis were investigated under two growth density conditions (high- and low-density plantings). The observed changes were then reconstructed digitally, and their allometric relationships were modelled. Taking the genome-wide association analysis, the SNP genotype and the dynamic phenotype of the leaf from both densities were combined to explore the allometry QTLs. Under different densities, leaf change phenotype was analyzed from two core ecological scenarios: (i) the allometric change of the leaf area with leaf length, and (ii) the change of the leaf length with petiole length. QTLs modulating these two scenarios were characterized as ‘leaf shape QTLs’ and ‘leaf position QTLs’. With functional mapping, results showed a total of 30 and 24 significant SNPs for shapeQTLs and positionQTLs, respectively. By annotation, immune pathway genes, photosensory receptor genes, and phytohormone genes were identified to be involved in the SAS response. Interestingly, genes modulating the immune pathway and salt tolerance, i.e., systemic acquired resistance (SAR) regulatory proteins (MININ-1-related) and salt tolerance homologs (STH), were reported to mediate the SAS response. By dissecting and comparing QTL effects from low- and high-density conditions, our results elucidate the genetic control of leaf formation in the context of the SAS response. The mechanism with leaf development × density interaction can further aid the development of density-tolerant crop varieties for agricultural practices.
Global Status of Vegetable Soybean
Authors: Nair Ramakrishnan M. , Boddepalli Venkata Naresh , Yan Miao-Rong , Kumar Vineet , Gill Balwinder , Pan Rabi S. , Wang Chansen , Hartman Glen L. , Silva e Souza Renan , Somta Prakit
Published: January 2023

Vegetable soybean, popularly known as edamame in Japan and mao dou in China is a specialty soybean. Green pods with physiologically mature beans are harvested, and whole pods or shelled beans are used as a fresh or frozen vegetable. Vegetable soybeans are prepared in diverse ways, and they are highly nutritious, with excellent taste properties. Unlike grain soybeans, it is perishable. In this review, the chronological progression of area, production, export, import, and expansion of vegetable soybeans and potential for further expansion is discussed. Available information on current ongoing research and development activities in various countries around the world are presented, and their relevance is discussed. At present, the production and consumption of vegetable soybeans are mainly in East and Southeast Asia, with Japan as the largest importing country that dictates the global market. However, interest and trend in cultivation of this crop in other regions has increased significantly. Lack of germplasm or suitable varieties is a major constraint in vegetable soybean production and expansion in countries outside East and Southeast Asia. Most of the vegetable soybean varieties are genetically related and are susceptible to biotic and abiotic stresses. Extensive research and breeding of vegetable soybeans are still restricted in a few countries such as China, Japan, Taiwan and the USA. The need for focused research and development activities with concern for the environment, farmers’ and processors’ profit, consumers’ preference, quality, and nutrition are emphasized.
Exploring the Medicinal Potential of Achillea grandifolia in Greek Wild-Growing Populations: Characterization of Volatile Compounds, Anti-Inflammatory and Antioxidant Activities of Leaves and Inflorescences
Authors: Tsiftsoglou Olga S. , Atskakani Maria-Eleni , Krigas Nikos , Stefanakis Michalis K. , Gounaris Christos , Hadjipavlou-Litina Dimitra , Lazari Diamanto
Published: January 2023

Various species of the genus Achillea L. (Asteraceae) are traditionally used worldwide for wound healing against diarrhea, flatulence, and abdominal pains, as diuretic and emmenagogue agents. In the present study, the essential oils (EOs) obtained separately from the leaves and inflorescences of wild-growing Achillea grandifolia Friv. from Mt. Menoikio and Mt. Pelion (Greece) were analyzed by Gas Chromatography–Mass Spectrometry. The major compounds found in EOs of A. grandifolia inflorescences from Mt. Menoikio were as follows: cis-thujone (36.9%), 1,8-cineole (11.9%), camphor (10.0%), ascaridole (7.3%), α-terpinene (6.4%), sabinene (4.1%), trans-thujone (3.6%), and cis-jasmone (3.4%). In leaves from Mt. Menoikio, they were as follows: cis-thujone (50.8%), 1,8-cineole (20.0%), trans-thujone (5.5%), camphor (5.5%), borneol (3.6%), and α-terpineol (3.1%). In inflorescences from Mt. Pelion, they were as follows: camphor (70.5%), camphene (5.9%), cis-jasmone (3.2%), bornyl acetate (3.2%). In leaves from Mt. Pelion, they were as follows: camphor (83.2%), camphene (3.9%), and borneol (3.7%). Subsequently, the samples were first time tested for their antioxidant activities with the interaction of EOs with DPPH (2,2-diphenyl-1-picrylhydrazyl) and their inhibition of lipid peroxidation, as well as for their anti-inflammatory activity through the soybean LOX (lipoxygenase) inhibition. All of the examined samples were found effective. A. grandifolia leaves presented the highest antioxidant potential according to the DPPH method, and the highest percentage of LOX inhibition. The study herein investigated for the first time the leaves and the inflorescences of A. grandifolia separately, and the results generally align with similar studies from neighboring countries (Turkey and Serbia) in terms of the yields and categorization of main EO compounds (oxygenated monoterpenes). However, the findings were not in agreement with previously studied Greek material, as a higher amount of cis-thujone and lower antioxidant activity are reported herein. Both the EOs of inflorescences and the leaves of the wild-growing population collected from Mt. Menoikio were characterized by a high quantity of cis-thujone (36.9% and 50.8%, respectively).
Ecological and Geographical Structure of the Plant Cover of the East Asian Boreal–Nemoral Ecotone (the Lower Amur Region, Far East Russia)
Authors: Kryukova Maria V.
Published: January 2023

The study of the biodiversity of vegetation cover in the context of its genesis and development is an important task. The results of these studies are the basis for the development of ecological, biogeographical, evolutionary, and sociological research, such as modelling the dynamic processes of natural ecosystems, understanding the consequences of natural and anthropogenic changes for biodiversity, solving problems of biodiversity conservation, etc. Of particular interest from this point of view is the biodiversity of ecotones, which can serve as a model for studying the factors of the genesis of the plant cover structure in a dynamic environment. In this paper, we analyze the taxonomic structure of the flora of vascular plants and the spatial structure of the plant cover in the East Asian boreal–nemoral ecotone (of the Lower Amur region). The botanical research was conducted through the application of traditional techniques for floristic and geobotanical studies. The material for this article was drawn from over 15,000 herbarium samples and 1400 floristic and geobotanical descriptions made between 1993 and 2021 in the Lower Amur region. The analyzed flora includes 2240 species from 760 genera and 158 families, which constitute 80% of the species composition of the Russian part of the Amur River basin. The native flora comprises 1801 species from 602 genera and 152 families. The species diversity and quantitative characteristics of the natural and adventive flora of vascular plants in the Lower Amur region are comparable to those of the southern limit of the distribution of taiga ecosystems in the Holarctic. The spectrum of the leading families and genera in terms of the number of species corresponds to the geographical position of the territory (the family spectrum is led by Asteraceae, Cyperaceae, Poaceae, Ranunculaceae, Rosaceae and Polygonaceae and in the generic spectrum, Carex, Artemisia, Salix, Viola, Saxifraga, Poa and Saussurea). The specificity of the flora is determined by a combination of elements in the boreal and sub-boreal flora of East Asia. Seven floristic complexes are defined for the Lower Amur region flora: forest (41.4% of the native flora), meadow (19.2%), mire (4.1%), mountain tundra (12.5%), rocky scree (8.9%), aquatic–semiaquatic (7.8%) and floodplain–estuarine shallow (6.2%). The regularity of some floristic complexes is defined by the landscape’s ecological conditions, and the variety in the edaphic, orographic and climatic parameters within the region. The spatial structure of the plant cover of the boreal–nemoral ecotone is described.
Physical Properties of Plasma-Activated Water
Authors: Shaji Mobish , Rabinovich Alexander , Surace Mikaela , Sales Christopher , Fridman Alexander
Published: January 2023

Recent observations of plasma-activated water (PAW)’s surfactant behavior suggest that the activation of water with non-equilibrium plasma can decrease the surface tension of the water. This suggested change to the surface tension also indicates that the addition of plasma can lead to changes in the physical properties of the water, knowledge of which can expand existing PAW applications and open new ones. While the chemical behavior of PAW has been extensively analyzed, to the best of our knowledge the physical properties of PAW have not been investigated. This study focuses on the need for experimental determination of PAW’s physical properties—namely, surface tension, viscosity, and contact angle. The experimental results of this study show that the addition of plasma lowers the surface tension of water at room temperature, increases the viscosity of water at high temperatures, and lowers the contact angle of droplets on glass surfaces at room temperatures. Potential factors influencing these changes include plasma alteration of the mesoscopic structure of water at low temperatures and plasma additives acting as foreign particles in water at higher temperatures. Ultimately, this investigation demonstrates that the physical properties of water change due to plasma activation, which could lead to potential industrial applications of PAW as a surfactant or as a washing-out and cleaning agent.
Fully Flexible Covalent Organic Frameworks for Fluorescence Sensing 2,4,6-Trinitrophenol and p-Nitrophenol
Authors: Zhu Hai , Geng Tong-Mou , Tang Kai-Bin
Published: January 2023

Nitrophenols are important nitroaromatic compounds, both important environmental pollutants and dangerous explosives, posing a devastating danger and pollution threat to humans. It is vital to detect efficiently trace nitrophenols in the environment. In this contribution, a series of fully flexible cyclotriphosphazene-based COFs (FFCP COFs: HDADE, HBAPB, and HBPDA), prepared with both a flexible knot and flexible linkers of different lengths, were used for sensing 2,4,6-trinitrophenol (TNP) and p-nitrophenol (p-NP) in real time with excellent sensitivity and selectivity. The quenching constants of HDADE by TNP, HBAPB, and HBPDA by p-NP are 6.29 × 104, 2.17 × 105, and 2.48 × 105 L·mol–1, respectively. The LODs of TNP and p-NP are 1.19 × 10−11, 6.91 × 10−12, and 6.05 × 10−12 mol·L−1. Their sensitivities increase with the linker length, which is better than the corresponding COFs composed of rigid linkers. There is only a photoinduced electron transfer mechanism in the fluorescence quenching of HBPDA by p-NP. Meanwhile, the mechanisms of photoinduced charge transfer and resonance energy transfer exist in the fluorescence quenching of HDADE by TNP and the fluorescence quenching of HBAPB by p-NP.
Isolation and Characterization of Cellulose Microfibers from Colombian Cocoa Pod Husk via Chemical Treatment with Pressure Effects
Authors: Hozman-Manrique Ana Sofia , Garcia-Brand Andres J. , Hernández-Carrión María , Porras Alicia
Published: January 2023

One of the current challenges is to add value to agro-industrial wastes, and the cocoa industry generates about 10 tons of cocoa pod husks in Colombia for each ton of cocoa beans, which are incinerated and cause environmental damage. This study characterized the Colombian cocoa pod husk (CPH) and to isolate and characterize cellulose microfibers (tCPH) extracted via chemical treatment and pressure. Chemical and physical analyses of CPH were performed, and a pretreatment method for CPH fibers was developed, which is followed by a hydrolysis method involving high pressure in an autoclave machine with an alkaline medium (6% NaOH), and finally, bleaching of the fiber to obtain tCPH. The tCPH cellulose microfibers were also chemically and physically analyzed and characterized by infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), and thermo-gravimetric analysis (TGA). Chemical and physical characterization showed a decrease in lignin content in tCPH. FTIR analysis showed the absence of some peaks in tCPH with respect to the CPH spectrum; XRD results showed an increase in crystallinity for tCPH compared to CPH, due to a higher presence of crystalline cellulose in tCPH. SEM images included a control fiber treated without high pressure (tCPHnpe), and agglomerated fibers were observed, whereas cellulose microfibers with a mean diameter of 10 ± 2.742 μm were observed in tCPH. Finally, with TGA and DTGA it was confirmed that in tCPH, the hemicellulose and lignin were removed more successfully than in the control fiber (tCPHnpe), showing that the treatment with pressure was effective at isolating the cellulose microfibers from cocoa pod husk.
Recent Advances in Poly(Ionic Liquid)-Based Membranes for CO2 Separation
Authors: Bernardo Gabriel , Gaspar Hugo
Published: January 2023

Poly(ionic liquid)-based membranes have been the subject of intensive research in the last 15 years due to their potential for the separation of CO2 from other gases. In this short review, different types of PIL-based membranes for CO2 separation are described (neat PIL membranes; PIL-IL composite membranes; PIL-polymer blend membranes; PIL-based block copolymer membranes, and PIL-based mixed matrix membranes), and their state-of-the-art separation results for different gas pairs (CO2/N2, CO2/H2, and CO2/CH4) are presented and discussed. This review article is focused on the most relevant research works performed over the last 5 years, that is, since the year 2017 onwards, in the field of poly(ionic liquid)-based membranes for CO2 separation. The micro- and nano-morphological characterization of the membranes is highlighted as a research topic that requires deeper study and understanding. Nowadays there is an array of advanced structural characterization techniques, such as neutron scattering techniques with contrast variation (using selective deuteration), that can be used to probe the micro- and nanostructure of membranes, in length scales ranging from ~1 nm to ~15 μm. Although some of these techniques have been used to study the morphology of PIL-based membranes for electrochemical applications, their use in the study of PIL-based membranes for CO2 separation is still unknown.
Additively-Manufactured High-Concentration Nanocellulose Composites: Structure and Mechanical Properties
Authors: Latif Muhammad , Jiang Yangxiaozhe , Song Jongmin , Kim Jaehwan
Published: January 2023

Additive manufacturing technology (AMT) has transformed polymer composites’ manufacturing process with its exceptional ability to construct complex products with unique materials, functions, and structures. Besides limiting studies of manufacturing arbitrarily shaped composites using AMT, printed structures with a high concentration of nanocellulose face adhesion issues upon drying, resulting in shape fidelity issues and low mechanical strength. This research demonstrates an economical approach to printing a high-concentration (25.46 wt%) nanocellulose (NC) layer-wise pattern to fabricate structures. Two different composites are fabricated: (1) 3D-printed pure and high-concentration (10, 15, and 20 wt%) polyvinyl-alcohol (PVA)-blended NC structures followed by freeze-drying and impregnation of Epofix resin by varying hardener contents; (2) 3D-printed PVA-blended NC green composites dried at cleanroom conditions (Relative humidity 45%; Temperature 25 °C). Different contents (10, 15, and 20 wt%) of PVA as a crosslinker were blended with NC to assist the printed layers’ adhesions. An optimum PVA content of 15 wt% and an Epofix resin with 4 wt% hardener cases showed the highest bending strength of 55.41 ± 3.63 MPa and elastic modulus of 4.25 ± 0.37 GPa. In contrast, the 15 wt% PVA-blended NC cleanroom-dried green composites without resin infusion showed bending strength and elastic modulus of 94.78 ± 3.18 MPa and 9.00 ± 0.27 GPa, reflecting high interface adhesions as confirmed by scanning electron microscope. This study demonstrated that AMT-based nanocellulose composites could be scaled up for commercial use.
Optimization of Cellulose Nanofiber Loading and Processing Conditions during Melt Extrusion of Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) Bionanocomposites
Authors: Shazleen Siti Shazra , Sabaruddin Fatimah Athiyah , Ando Yoshito , Ariffin Hidayah
Published: January 2023

This present study optimized the cellulose nanofiber (CNF) loading and melt processing conditions of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) P(HB-co-11% HHx) bionanocomposite fabrication in twin screw extruder by using the response surface methodology (RSM). A face-centered central composite design (CCD) was applied to statistically specify the important parameters, namely CNF loading (1–9 wt.%), rotational speed (20–60 rpm), and temperature (135–175 °C), on the mechanical properties of the P(HB-co-11% HHx) bionanocomposites. The developed model reveals that CNF loading and temperature were the dominating parameters that enhanced the mechanical properties of the P(HB-co-11% HHx)/CNF bionanocomposites. The optimal CNF loading, rotational speed, and temperature for P(HB-co-11% HHx) bionanocomposite fabrication were 1.5 wt.%, 20 rpm, and 160 °C, respectively. The predicted tensile strength, flexural strength, and flexural modulus for these optimum conditions were 22.96 MPa, 33.91 MPa, and 1.02 GPa, respectively, with maximum desirability of 0.929. P(HB-co-11% HHx)/CNF bionanocomposites exhibited improved tensile strength, flexural strength, and modulus by 17, 6, and 20%, respectively, as compared to the neat P(HB-co-11% HHx). While the crystallinity of P(HB-co-11% HHx)/CNF bionanocomposites increased by 17% under the optimal fabrication conditions, the thermal stability of the P(HB-co-11% HHx)/CNF bionanocomposites was not significantly different from neat P(HB-co-11% HHx).
Designing a Coupling Agent with Aliphatic Polyether Chain and Exploring Its Effect on Silica/Natural Rubber Nanocomposites under the Action of Non-Rubber Contents
Authors: Zhai Xiaobo , Chen Xin , Zheng Fangyuan , Han Dongli , Zheng Junchi , Ye Xin , Li Xiaolin , Zhang Liqun
Published: January 2023

In order to prepare engineering tires with lower rolling resistance and better wet slip resistance in a more environmentally friendly way. In this study, a series of low volatile organic compound (VOC) Mx–Si69 coupling agents (x = 1, 2, 3, 4, 5, 6, which means the number of ethoxy group in bis-(γ-triethoxysilylpropyl)-tetrasulfide (Si69) substituted by the aliphatic polyether chain) were applied to silica/NR nanocomposites to prepare tire tread with excellent performance. Firstly, M1–Si69 was substantiated as the best choice of Mx–Si69 and Si69 to achieve comprehensive optima in the mechanical properties of silica/NR nanocomposites characterized by dynamic and static mechanical properties. Afterwards, the modification of silica with M1–Si69 induced by Non-Rubber Contents (NRCs) in silica/NR nanocomposites was revealed by comparing the filler network, micromorphology, and mechanical properties of isoprene rubber (IR) and NR nanocomposites. Furthermore, compared with Si69, the M1–Si69 coupling agent was found to conspicuously reduce the energy loss and improve the safety performance of engineering tires according to evaluations of the rolling resistance and dynamic thermomechanical properties of the silica/NR nanocomposites. Finally, the critical function of M1–Si69 in reducing ethanol (a kind of volatile organic compound (VOC)) emissions from the reaction of coupling agent and silica was disclosed by gas chromatography–mass spectrometry.
Radiation-Grafting on Polypropylene Copolymer Membranes for Using in Cadmium Adsorption
Authors: Khedr Rania F.
Published: January 2023

Graft copolymerization has been a popular technique in recent years for adding different functional groups to polymers. In our research, polypropylene (PP) films are grafted with acrylonitrile (An) and acrylic acid (AAc) monomers to make them hydrophilic while retaining their mechanical qualities. Gamma radiation is used in this approach to establish active spots on an inert polymer that are appropriate for adding monomers radicals to form grafts, a procedure that is extremely difficult to perform using normal chemical processes. The graft parameters are investigated in order to acquire the highest percentage of graft. FTIR (Fourier transform infrared spectroscopy) spectra are used to analyze the grafting of AAc and An. SEM (scanning electron microscopy) and XRD (X-ray diffraction) micrographs are used to validate them. The specimens’ tensile strength and hardness are measured and contrasted with blank PP films. Measurements are made of the effects of grafting on the tensile strength and elongation of the films, and a crucial grafting degree is established in order to preserve these properties. Water uptake is measured to adapt the copolymer to water treatment, and thermal behavior TGA (thermal gravimetric analysis) and DSC (diffraction scanning calorimeter) of the produced copolymer were performed. The elimination of cadmium was verified by an atomic absorption spectrophotometer (AAS) under different conditions of pH, time, and degree of grafting.
The Role of Dissolution Time on the Properties of All-Cellulose Composites Obtained from Oil Palm Empty Fruit Bunch
Authors: Jaafar Mohd Zaim , Mohd Ridzuan Farah Fazlina , Mohamad Kassim Mohamad Haafiz , Abu Falah
Published: January 2023

All-cellulose composite (ACC) films from oil palm empty fruit bunches (OPEFBs) were successfully fabricated through the surface selective dissolution of cellulose fibers in 8 wt% LiCl/DMAc via the solution casting method. The effect of dissolution time on the properties of the ACC films was assessed in the range of 5–45 min. The results showed that under the best conditions, there were sufficiently dissolved fiber surfaces that improved the interfacial adhesion while maintaining a sizable fraction of the fiber cores, acting as reinforcements for the material. The ACC films have the highest tensile strength and modulus of elasticity of up to 35.78 MPa and 2.63 GPa after 15 min of dissolution. Meanwhile, an X-ray diffraction analysis proved that cellulose I and II coexisted, which suggests that the crystallite size and degree of crystallinity of the ACC films had significantly declined. This is due to a change in the cellulose structure, which results in fewer voids and enhanced stress distribution in the matrix. Scanning electron microscopy revealed that the interfacial adhesion improved between the reinforcing fibers and matrices as the failure behavior of the film composite changed from fiber pullout to fiber breakage and matrix cracking. On the other hand, the thermal stability of the ACC film showed a declining trend as the dissolution time increased. Therefore, the best dissolution time to formulate the ACC film was 15 min, and the obtained ACC film is a promising material to replace synthetic polymers as a green composite.
Mechanical and Tribological Performances of Thermoplastic Polymers Reinforced with Glass Fibres at Variable Fibre Volume Fractions
Authors: Zaghloul Moustafa Mahmoud Yousry , Steel Karen , Veidt Martin , Heitzmann Michael T.
Published: January 2023

High wear rates and frictional coefficients have always been the primary reasons for limiting the service life of critical elements such as pumps, couplings, bushings, bearings and gears. The premature and erratic failures are costing the industries extensive amounts of money every year. Additionally, under severe service conditions, the wear resistance requirements are higher, which greatly hinders the application of neat thermoplastics in different sectors. Hence, it is vital to enhance the tribological characteristics of thermoplastics. The mechanical and tribological properties of Polyamide 6, Thermoplastic Polyurethane, and glass fibre reinforced (GFR) Polyadmide 6 Composites of variable fibre volume fractions were investigated. Pin specimens of Polyamide 6 reinforced with (25%, 33%, and 50%) by volume of fibres were fabricated by an injection moulding process. The specimens were tested for tensile, compression, hardness, and wear under dry abrasive conditions using a pin-on-disc setup. Furthermore, the samples were scanned using micro-computed tomography (micro-CT), and the worn-out samples were analysed using field emission scanning electron microscopy. The experimental results showed that the fibre volume fraction was inversely proportional to the wear resistance of the prepared composite materials. This research will enable the industry partners to supply cutting-edge technologies to the global oil and gas industry that not only minimizes the well running cost but also improves the well resilience.
One-Step Oxidation of Orange Peel Waste to Carbon Feedstock for Bacterial Production of Polyhydroxybutyrate
Authors: Davaritouchaee Maryam , Mosleh Imann , Dadmohammadi Younas , Abbaspourrad Alireza
Published: January 2023

Orange peels are an abundant food waste stream that can be converted into useful products, such as polyhydroxyalkanoates (PHAs). Limonene, however, is a key barrier to building a successful biopolymer synthesis from orange peels as it inhibits microbial growth. We designed a one-pot oxidation system that releases the sugars from orange peels while eliminating limonene through superoxide (O2• −) generated from potassium superoxide (KO2). The optimum conditions were found to be treatment with 0.05 M KO2 for 1 h, where 55% of the sugars present in orange peels were released and recovered. The orange peel sugars were then used, directly, as a carbon source for polyhydroxybutyrate (PHB) production by engineered Escherichia coli. Cell growth was improved in the presence of the orange peel liquor with 3 w/v% exhibiting 90–100% cell viability. The bacterial production of PHB using orange peel liquor led to 1.7–3.0 g/L cell dry weight and 136–393 mg (8–13 w/w%) ultra-high molecular weight PHB content (Mw of ~1900 kDa) during a 24 to 96 h fermentation period. The comprehensive thermal characterization of the isolated PHBs revealed polymeric properties similar to PHBs resulting from pure glucose or fructose. Our one-pot oxidation process for liberating sugars and eliminating inhibitory compounds is an efficient and easy method to release sugars from orange peels and eliminate limonene, or residual limonene post limonene extraction, and shows great promise for extracting sugars from other complex biomass materials.
Diffusion-Enhanced Förster Resonance Energy Transfer in Flexible Peptides: From the Haas-Steinberg Partial Differential Equation to a Closed Analytical Expression
Authors: Jacob Maik H. , D’Souza Roy N. , Lazar Alexandra I. , Nau Werner M.
Published: January 2023

In the huge field of polymer structure and dynamics, including intrinsically disordered peptides, protein folding, and enzyme activity, many questions remain that cannot be answered by methodology based on artificial intelligence, X-ray, or NMR spectroscopy but maybe by fluorescence spectroscopy. The theory of Förster resonance energy transfer (FRET) describes how an optically excited fluorophore transfers its excitation energy through space to an acceptor moiety—with a rate that depends on the distance between donor and acceptor. When the donor and acceptor moiety are conjugated to different sites of a flexible peptide chain or any other linear polymer, the pair could in principle report on chain structure and dynamics, on the site-to-site distance distribution, and on the diffusion coefficient of mutual site-to-site motion of the peptide chain. However, the dependence of FRET on distance distribution and diffusion is not defined by a closed analytical expression but by a partial differential equation (PDE), by the Haas-Steinberg equation (HSE), which can only be solved by time-consuming numerical methods. As a second complication, time-resolved FRET measurements have thus far been deemed necessary. As a third complication, the evaluation requires a computationally demanding but indispensable global analysis of an extended experimental data set. These requirements have made the method accessible to only a few experts. Here, we show how the Haas-Steinberg equation leads to a closed analytical expression (CAE), the Haas-Steinberg-Jacob equation (HSJE), which relates a diffusion-diagnosing parameter, the effective donor–acceptor distance, to the augmented diffusion coefficient, J, composed of the diffusion coefficient, D, and the photophysical parameters that characterize the used FRET method. The effective donor–acceptor distance is easily retrieved either through time-resolved or steady-state fluorescence measurements. Any global fit can now be performed in seconds and minimizes the sum-of-square difference between the experimental values of the effective distance and the values obtained from the HSJE. In summary, the HSJE can give a decisive advantage in applying the speed and sensitivity of FRET spectroscopy to standing questions of polymer structure and dynamics.
Polycaprolactone with Glass Beads for 3D Printing Filaments
Authors: Kováčová Mária , Vykydalová Anna , Špitálský Zdenko
Published: January 2023

At present, 3D printing is experiencing a great boom. The demand for new materials for 3D printing is also related to its expansion. This paper deals with manufacturing innovative polymer composite filaments suitable for the Fused Filament Fabrication method in 3D printing. As a filler, common and uncostly glass beads were used and mixed with biocompatible and biodegradable poly (ε-caprolactone), as a polymer matrix. This material was characterized via several physical-chemical methods. The Youngs modulus was increasing by about 30% with 20% loading of glass beads, and simultaneously, brittleness and elongations were decreased. The glass beads do not affect the shore hardness of filaments. The rheological measurement confirmed the material stability in a range of temperatures 75–120 °C. The presented work aimed to prepare lightweight biocompatible, cheap material with appropriate mechanical properties, lower printing temperature, and good printing processing. We can assess that the goal was fully met, and these filaments could be used for a wide range of applications.
Study on Demulsification Technology of Heavy Oil Blended in Xinjiang Oilfield
Authors: Zou Jungang , Patiguli Yaermaimaiti , Chen Jun , Alimila Awan , Zhao Bin , Hou Junwei
Published: January 2023

HYW (Hong Yi Wu line) heavy oil emulsion in Xinjiang Oilfield (Karamay, China) is a kind of heavy oil with high viscosity and high emulsification. Its viscosity reaches 120,000 mPa·s at 40 °C. The emulsion has no demulsification. Even if the demulsification temperature reaches 90 degrees, the concentration of demulsifier reaches 260 mg/L. In this paper, a new process of thermochemical demulsification of heavy oil after blending is studied. First, SE low-viscosity oil with viscosity of 640 mPa·s and water cut of 90% was selected as blended oil. Study the viscosity of SE line and HYW line at different temperatures after fully blended. The results show that the heavy oil blended model conforms to Bingham model. When the temperature is 40 °C and the content of SE line is 30%, the viscosity is less than 10,000 mPa·s. With the increase of temperature, the viscosity continues to decline. When the temperature exceeds 80 °C, the viscosity is less than 1000 mPa·s. The final design SE line content is 30%, the demulsification temperature is 70 °C, and the demulsifier concentration is 160 mg/L as the best demulsification parameter. The field results show that the demulsification rate of heavy oil in this process reaches more than 90%. This experiment lays a foundation for demulsification of high emulsified crude oil developed by heavy oil in Xinjiang oilfield.
Assessment of Heavy Metal Pollution in Water Sediment and Study on Pollution Mechanism—Taking the Weihe River Basin in China as an Example
Authors: Xu Yuxia , Liao Xin , Guo Bei
Published: January 2023

To ensure the ecological security of the basin, data on the heavy metal content in the sediments of the Weihe River Basin were collected to analyze the spatial distribution characteristics of heavy metals based on descriptive statistics and geostatistics. The geoaccumulation index and potential ecological risk assessment were conducted, and the number of pollution sources and the contribution rate were determined by combining correlation analysis, principal component analysis, and APCS-MLR. The results showed that the mean values of As, Pb, Zn, Ni, Cr, Hg, Cu, and Cd were 15.42, 27.27, 88.05, 31.05, 75, 0.13, 29.47, and 1.05 mg·kg−1, respectively. Igeo is in the order of Cd > Hg > As > Cu > Pb > Zn > Cr > Ni. Cd had the highest potential ecological risk factor, followed by Hg with a critical risk proportion of 12.6%. The traceability analysis showed that the heavy metals come from mixed, industrial, and agricultural sources, among which Pb, Zn, Ni, Cr, and Cu are affected by soil-forming parent materials and industrial comprehensive sources, As is affected by agricultural sources, and Hg and Cd are affected by industrial sources. Industrial and living sources are the main sources of the heavy metals. The results of the study can provide a basis for formulating relevant pollution prevention and control measures in the Weihe River Basin.
Evaluating Research Impact Based on Semantic Scholar Highly Influential Citations, Total Citations, and Altmetric Attention Scores: The Quest for Refined Measures Remains Illusive
Authors: Dardas Latefa Ali , Sallam Malik , Woodward Amanda , Sweis Nadia , Sweis Narjes , Sawair Faleh A.
Published: January 2023

Background: The evaluation of scholarly articles’ impact has been heavily based on the citation metrics despite the limitations of this approach. Therefore, the quest for meticulous and refined measures to evaluate publications’ impact is warranted. Semantic Scholar (SS) is an artificial intelligence-based database that allegedly identifies influential citations defined as “Highly Influential Citations” (HICs). Citations are considered highly influential according to SS when the cited publication has a significant impact on the citing publication (i.e., the citer uses or extends the cited work). Altmetrics are measures of online attention to research mined from activity in online tools and environments. Aims: The current study aimed to explore whether SS HICs provide an added value when it comes to measuring research impact compared to total citation counts and Altmetric Attention Score (AAS). Methods: Dimensions was used to generate the dataset for this study, which included COVID-19-related scholarly articles published by researchers affiliated to Jordanian institutions. Altmetric Explorer was selected as an altmetrics harvesting tool, while Semantic Scholar was used to extract details related to HICs. A total of 618 publications comprised the final dataset. Results: Only 4.57% (413/9029) of the total SS citations compiled in this study were classified as SS HICs. Based on SS categories of citations intent, 2626 were background citations (29.08%, providing historical context, justification of importance, and/or additional information related to the cited paper), 358 were result citations (3.97%, that extend on findings from research that was previously conducted), and 263 were method citations (2.91%, that use the previously established procedures or experiments to determine whether the results are consistent with findings in related studies). No correlation was found between HICs and AAS (r = 0.094). Manual inspection of the results revealed substantial contradictions, flaws, and inconsistencies in the SS HICs tool. Conclusions: The use of SS HICs in gauging research impact is significantly limited due to the enigmatic method of its calculation and total dependence on artificial intelligence. Along with the already documented drawbacks of total citation counts and AASs, continuous evaluation of the existing tools and the conception of novel approaches are highly recommended to improve the reliability of publication impact assessment.
Trends in Extraction of Rare Earth Elements from Coal Ashes: A Review
Authors: Dodbiba Gjergj , Fujita Toyohisa
Published: January 2023

The demand for novel, cost-effective, and environmentally friendly rare earth element and yttrium (REY) sources is essential. The recovery of REY and other valuable components from coal fly ash (CFA) may result in securing alternative resources, decreased disposal costs, and environmental protection, all of which may have positive effects. However, research on the recovery of REY from CFA is underway, and it is still necessary to assess its viability from an economic and environmental standpoint. The authors have reviewed some of the most recent advances in extracting rare earth elements from CFA. However, most techniques reported for the treatment of CFA are still at the laboratory scale. Nevertheless, there are several pathways for industrial-scale applications. Therefore, CFA treatment and the extraction of valuable products from it have considerable potential for reducing both its carbon footprint and environmental burden.
Between Buddhist ‘Self-Enlightenment’ and ‘Artificial Intelligence’: South Korea Emerging as a New Balancer
Authors: Uttam Jitendra
Published: January 2023

As artificial intelligence (AI) outpaces the human brain, it is invoking wide-spread fear that men and machines are moving into a conflicting zone. Some even suspect that AI machines may one day consider human beings as slow and sloppy, and thus worthy of subordination or elimination. A growing challenge to mitigate the looming crisis requires science to expand its artificially augmented intelligence by incorporating elements from the ethical–spiritual and human universe. Our endeavor to bridge the prevailing gap between science and spirituality focuses on Buddhism, which stands out in its ability to achieve a rare fusion between natural, spiritual and human worlds. This unique synthesis is specifically mediated by Buddhist ‘causality’, where one aspect explains reality based on a scientifically proven cause and effect paradigm, but the other aspect interprets it by compassionate humanism. It argues that the missing human–spiritual dimension in artificial intelligence can be remedied by the Buddhist concept of ‘causally’ linked to the idea of ‘self-enlightenment’. Being an integral part of Buddhist heritage and a leading player in cutting-edge science, Korea demonstrates abilities to emerge as a new balancer to incorporate the best of science, spiritually and humanism to build next-generation AI machines with distinct human qualities.
When the ‘Buddha’s Tree Itself Becomes a Rhizome’: The Religious Itinerant, Nomad Science and the Buddhist State
Authors: Taylor James
Published: January 2023

This paper considers the political, geo-philosophical musings of Deleuze and Guattari on spatialisation, place and movement in relation to the religious nomad (wandering ascetics and reclusive forest monks) inhabiting the borderlands of Thailand. A nomadic science involves improvised ascetic practices between the molar lines striated by modern state apparatuses. The wandering ascetics, inhabiting a frontier political ecology, stand in contrast to the appropriating, sedentary metaphysics and sanctifying arborescence of statism and its corollary place-making, embedded in rootedness and territorialisation. It is argued that the religious nomads, residing on the endo-exteriorities of the state, came to represent a rhizomatic and politico-ontological threat to centre-nation and its apparatus of capture. The paper also theorises transitions and movement at the borderlands in the context of the state’s monastic reforms. These reforms, and its pervasive royal science, problematised the interstitial zones of the early ascetic wanderers in their radical cross-cutting networks and lines, moving within and across demarcated frontiers. Indeed, the ascetic wanderers and their allegorical war machine were seen as a source of wild, free-floating charisma and mystical power, eventually appropriated by the centre-nation in it’s becoming unitary and fixed.
Will, Original Teleology and the Divine Entelechy in Husserl’s Thought
Authors: Zeng Yun
Published: January 2023

The central intention of this paper is to explore original teleology and to solve the riddle of matter based on the analysis of the flow of absolute consciousness. The paper unfolds in four steps. Firstly, it analyzes the origin of teleology in terms of Husserl’s theory of intentional acts. Since Husserl’s phenomenology itself contains teleological ideas, the creativity and goal-direction of the will reveals the intrinsic connection between will and teleology. Secondly, the relationship between the will and original teleology is discussed around the riddle of matter raised by Husserl, and the reason why teleology originates in the act of will is explained. Thirdly, the paper reinterprets the divine entelechy from the perspective of the creativity of the divine will, and points out that Husserl’s concept of God is not only the idea of the highest good, but also an entelechy that is constantly engaged in creating and becoming. Finally, in order to further argue for the important role of the will in solving the problem of teleology, this paper discusses the intrinsic relationship between transcendental reduction and the will.
The Efficacy and Limits of Pilgrimage as Therapy for Depression
Authors: Hilario Rozheanne Cruz , Sy Su Chadwick Co
Published: January 2023

Western notions of pilgrimage produce images of religious adherence to known beliefs and their ritual expressions. Definitions of pilgrimage have expanded in recent decades to embrace treks to sites unattached to the sacred landscapes of traditional faith groups. Along with this expansion of meanings and practices has come a wider acceptance of travel for psychological transformation. Tourism can be argued as a modulated form of pilgrimage and traditional journeys of faith overlapping with instances of entirely secular tourism. Another purpose of pilgrimage can be as a therapeutic practice for those suffering from depressive disorders and related conditions. Its efficacy as therapy, along with its limits, are discussed in clinical and personal contexts with a view to including religious as well as secular perspectives. The pragmatics of such therapy are mapped against current trends in treatment.
Screening Out Their Own: Muslim Gatekeepers of Jewish Spaces in Morocco
Authors: Levy André
Published: January 2023

The literature on ethnic groups that were formed following migration reveals how symbolic and socioeconomic boundaries are manipulated by veteran groups to keep out the unwanted immigrants. It shows how these boundaries are to maintain and preserve the veterans’ dominant position. The case of the tiny Jewish minority living nowadays in Morocco reveals a seemingly contradictory mechanism: Muslim gatekeepers, who are part of the huge majority in Morocco, screen out their coreligionists from Jewish spaces. This gatekeeping fortifies the Jewish notion of exclusive spaces within which they feel safe as a tiny and fragile community. A close ethnographic gaze reveals that screening out Muslims is enabled due to a shared “cultural intimacy” that permits the minority to control access to their spaces. This paper sheds light on a deep level of cultural understanding that allows Jews to maintain bearable life as a dwindling minority in Morocco—despite their motivations to be separated—by appointing Muslim gatekeepers.
Analysing Quantiles in Models of Forward Term Rates
Authors: McWalter Thomas A. , Schlögl Erik , van Appel Jacques
Published: January 2023

The class of forward-LIBOR market models can, under certain volatility structures, produce unrealistically high long-dated forward rates, particularly for maturities and tenors beyond the liquid market calibration instruments. This paper presents a diagnostic tool for analysing the quantiles of distributions for forward term rates in a displaced lognormal forward-LIBOR model (DLFM). In particular, we provide a quantile approximation that can be used to assess whether the modelled term rates remain within realistic bounds with a high probability. Applying this diagnostic tool (verified using Quasi-Monte Carlo (QMC) simulations), we show that realised forward term rates for long time horizons may be kept within realistic limits by appropriately damping the tail of the DLFM volatility function.
A Trajectory Compensation Method Considering the Car-Following Behavior for Data Missing of Millimeter-Wave Radar in Roadside Detection Applications
Authors: Zhang Rui , Liu Haiqing , Teng Kunmin
Published: January 2023

Concerning roadside traffic detection applications, and to address the millimeter-wave radar’s missing data problem caused by target occlusion or the absence of features in low-speed conditions, this paper proposes a trajectory compensation method regarding car-following behavior. Referring to the installation scheme of the detector, a coordinate transformation method is presented to unify the radar spatial coordinates with the road coordinates. Considering the driver’s car-following behavior, the optimal velocity model (OV), full velocity difference model (FVD), and the full velocity difference and acceleration (FVDA) model are applied for tracking the vehicle’s trajectory related to the movement of the vehicle ahead. Finally, a data compensation scheme is presented. Taking actual trajectory data as samples, the proposed methods are verifiably useful for compensating for missing data and reconstructing target trajectories. Statistical results of different missing data trajectories demonstrate the rationality of the application of car-following models for the missing data compensation, and the FVDA model performs well compared with the OV and FVD models.