bluuebunny/crossref_metadata_2025 huggingface dataset:
Design for an Art Therapy Robot: An Explorative Review of the Theoretical Foundations for Engaging in Emotional and Creative Painting with a Robot
Authors: Cooney Martin Daniel , Menezes Maria Luiza Recena
Published: September 2018

Social robots are being designed to help support people’s well-being in domestic and public environments. To address increasing incidences of psychological and emotional difficulties such as loneliness, and a shortage of human healthcare workers, we believe that robots will also play a useful role in engaging with people in therapy, on an emotional and creative level, e.g., in music, drama, playing, and art therapy. Here, we focus on the latter case, on an autonomous robot capable of painting with a person. A challenge is that the theoretical foundations are highly complex; we are only just beginning ourselves to understand emotions and creativity in human science, which have been described as highly important challenges in artificial intelligence. To gain insight, we review some of the literature on robots used for therapy and art, potential strategies for interacting, and mechanisms for expressing emotions and creativity. In doing so, we also suggest the usefulness of the responsive art approach as a starting point for art therapy robots, describe a perceived gap between our understanding of emotions in human science and what is currently typically being addressed in engineering studies, and identify some potential ethical pitfalls and solutions for avoiding them. Based on our arguments, we propose a design for an art therapy robot, also discussing a simplified prototype implementation, toward informing future work in the area.
Royal Jelly Delays Motor Functional Impairment During Aging in Genetically Heterogeneous Male Mice
Authors: Okumura Nobuaki , Toda Toshihiko , Ozawa Yusuke , Watanabe Kenji , Ikuta Tomoki , Tatefuji Tomoki , Hashimoto Ken , Shimizu Takahiko
Published: September 2018

Aging is associated with motor disorders that decrease the quality of life (QOL). Royal jelly (RJ), used as a dietary supplement, has shown various health benefits and, therefore, it has the potential to improve the QOL during aging. We have previously developed protease enzyme-treated RJ to avoid the anaphylactic response induced by RJ supplementation. However, the effects of a lifelong treatment with RJ on normal aging have not been fully clarified. In this study, we investigated the effects of enzyme-untreated RJ (NRJ) and enzyme-treated RJ (ERJ) on the aging process focusing on motor functions, by using a genetically heterogeneous (HET) mouse model experimentally endowed with genetic diversity. We performed four different physical performance tests (grip strength, wire hang, horizontal bar, and rotarod). We showed that the age-related impairment of the motor functions was significantly delayed in RJ-treated mice. Both NRJ and ERJ were similarly effective against these types of aging-associated declines. Histological analyses revealed that the RJ treatment affected the muscle fiber size at an advanced age. We also demonstrated that age-related changes in muscle satellite cell markers and catabolic genes were affected in RJ-treated mice. These results suggest that non-protein components of RJ improved the motor function in aging mice. These findings indicate that RJ has the potential to change the QOL during aging by regulating the motor function.
Fatty Acid Profiles of Various Vegetable Oils and the Association between the Use of Palm Oil vs. Peanut Oil and Risk Factors for Non-Communicable Diseases in Yangon Region, Myanmar
Authors: Aung Wai Phyo , Bjertness Espen , Htet Aung Soe , Stigum Hein , Chongsuvivatwong Virasakdi , Soe Pa Pa , Kjøllesdal Marte Karoline Råberg
Published: September 2018

The majority of vegetable oils used in food preparation in Myanmar are imported and sold non-branded. Little is known about their fatty acid (FA) content. We aimed to investigate the FA composition of commonly used vegetable oils in the Yangon region, and the association between the use of palm oil vs. peanut oil and risk factors for non-communicable disease (NCD). A multistage cluster survey was conducted in 2016, and 128 oil samples from 114 households were collected. Data on NCD risk factors were obtained from a household-based survey in the same region, between 2013 and 2014. The oils most commonly sampled were non-branded peanut oil (43%) and non-branded palm oil (19%). Non-branded palm oil had a significantly higher content of saturated fatty acids (36.1 g/100 g) and a lower content of polyunsaturated fatty acids (9.3 g/100 g) than branded palm oil. No significant differences were observed regarding peanut oil. Among men, palm oil users had significantly lower mean fasting plasma glucose levels and mean BMI than peanut oil users. Among women, palm oil users had significantly higher mean diastolic blood pressure, and higher mean levels of total cholesterol and triglycerides, than peanut oil users. Regulation of the marketing of non-branded oils should be encouraged.
Sex-Specific Human Milk Composition: The Role of Infant Sex in Determining Early Life Nutrition
Authors: Galante Laura , Milan Amber M. , Reynolds Clare M. , Cameron-Smith David , Vickers Mark H. , Pundir Shikha
Published: September 2018

Male and female infants respond differentially to environmental stimuli, with different growth and neurodevelopmental trajectories. Male infants are more likely to be disadvantaged when subjected to adversity and show a higher risk of perinatal complications. However, the underlying causes of this sex-bias are not well defined and optimising the early life nutritional care may be necessary to minimise the “male disadvantage” that may be experienced early in life. Experimental models have demonstrated that animal milk composition differs according to offspring sex, suggesting that the tailoring of early life nutrition may be one mechanism to maximise health protection and development to infants of both sexes. However, evidence for a sex-specificity in human milk composition is limited and conflicting, with studies documenting higher milk energy content for either male or female infants. These data show sex differences, however, there has been limited compositional analysis of the current data nor strategies proposed for how sex-specific compositional differences in early life nutrition may be used to improve infant health. The present narrative review highlights that an improved understanding of sex-specific human milk composition is essential for promoting optimal infant growth and development.
Muscle Loss in Chronic Liver Diseases: The Example of Nonalcoholic Liver Disease
Authors: De Bandt Jean-Pascal , Jegatheesan Prasanthi , Tennoune-El-Hafaia Naouel
Published: September 2018

Recent publications highlight a frequent loss of muscle mass in chronic liver diseases, including nonalcoholic fatty liver disease (NAFLD), and its association with a poorer prognosis. In NAFLD, given the role of muscle in energy metabolism, muscle loss promotes disease progression. However, liver damage may be directly responsible of this muscle loss. Indeed, muscle homeostasis depends on the balance between peripheral availability and action of anabolic effectors and catabolic signals. Moreover, insulin resistance of protein metabolism only partially explains muscle loss during NAFLD. Interestingly, some data indicate specific alterations in the liver–muscle axis, particularly in situations such as excess fructose/sucrose consumption, associated with increased hepatic de novo lipogenesis (DNL) and endoplasmic reticulum stress. In this context, the liver will be responsible for a decrease in the peripheral availability of anabolic factors such as hormones and amino acids, and for the production of catabolic effectors such as various hepatokines, methylglyoxal, and uric acid. A better understanding of these liver–muscle interactions could open new therapeutic opportunities for the management of NAFLD patients.
Metabolically Healthy versus Unhealthy Morbidly Obese: Chronic Inflammation, Nitro-Oxidative Stress, and Insulin Resistance
Authors: Cӑtoi Adriana Florinela , Pârvu Alina Elena , Andreicuț Andra Diana , Mironiuc Aurel , Crӑciun Alexandra , Cӑtoi Cornel , Pop Ioana Delia
Published: September 2018

Metabolically heathy obesity is characterised by the presence of obesity in the absence of metabolic disturbances. The aim of our study was to analyse pro-inflammatory, nitro-oxidative stress, and insulin-resistance (IR) markers in metabolically healthy morbidly obese (MHMO) with respect to metabolically unhealthy morbidly obese (MUHMO) with metabolic syndrome (MS) and to identify the potential predictors of MS in the MHMO group. Two groups of MHMO and MUHMO with MS were analysed. We evaluated serum high sensitivity C reactive protein (hsCRP), tumor necrosis factor alpha (TNF-α), chemerin, nitrite and nitrate (NOx), total oxidant status (TOS), total antioxidant response (TAR), fasting blood glucose, insulin, and homeostasis model assessment of insulin resistance (HOMA-IR.) MHMO have similar hsCRP and TNF-α values as the MUHMO with MS, while chemerin was significantly lower in MHMO. NOx was higher in MUHMO with MS patients, while no difference regarding TOS and TAR was found between the two groups. HOMA-IR and insulin values were lower in MHMO as compared to the MUHMO with MS group. Insulin, HOMA-IR, and chemerin were identified predictors of MS in MHMO. In conclusion, MHMO and MUHMO display similarities and differences in terms of chronic inflammation, nitro-oxidative stress, and IR. Markers of IR and chemerin are possible predictors of MS in MHMO.
Green Tea, Coffee, and Caffeine Consumption Are Inversely Associated with Self-Report Lifetime Depression in the Korean Population
Authors: Kim Jiwon , Kim Jihye
Published: September 2018

This study investigated the associations of green tea, coffee, and caffeine consumption with self-report lifetime depression in the Korean population using data from the Korean National Health and Nutrition Examination Survey. In total, 9576 participants (3852 men and 5724 women) aged 19 years or older were selected for the present study. Green tea, coffee, and caffeine consumption levels were assessed with a validated food frequency questionnaire. Multivariate logistic regression analysis was used to determine the odds ratios (OR) and 95% confidence intervals (CIs) for depression according to green tea, coffee, and caffeine consumption. Frequent green tea consumers (≥3 cups/week) had 21% lower prevalence of depression (OR = 0.79, 95% CI = 0.63–0.99, p for trend = 0.0101) than green tea non-consumers after adjustment for potential confounders. Likewise, frequent coffee drinkers (≥2 cups/day) had 32% lower prevalence of depression (OR = 0.68, 95% CI = 0.55–0.85, p for trend = 0.0026) than coffee non-drinkers after adjustment for potential confounders. Also, participants in the highest quartile of caffeine consumption had 24% lower prevalence of depression than those in the lowest quartile (OR = 0.76, 95% CI = 0.62–0.92, p for trend = 0.0032). Frequent consumption of green tea, coffee, or caffeine was associated with a reduced prevalence of self-report lifetime depression in Korean adults. A prospective study and randomized clinical trials should be conducted to confirm the inverse relationships of green tea and coffee consumption with risk of depression.
Anti-Atopic Properties of Gracillin Isolated from Dioscorea quinqueloba on 2,4-Dinitrochlorobenzene-Induced Skin Lesions in Mice
Authors: Jegal Jonghwan , Park No-June , Jo Beom-Geun , Bong Sim-Kyu , Jegal Hyun , Yang Min Hye , Kim Su-Nam
Published: September 2018

Naturally occurring saponins have been reported to have anti-inflammatory and immunomodulatory effects. However, the effects of gracillin, a main saponin component of Dioscorea quinqueloba (D. quinqueloba), on atopic dermatitis (AD), have not been previously studied. The aim of this study was to determine whether gracillin isolated from D. quinqueloba has an anti-AD effect on 2,4-dinitrochlorobenzene (DNCB)-induced AD-like skin lesions in SKH-1 hairless mice. Topical co-treatment of gracillin and DNCB for two weeks markedly reduced symptoms typical of AD (redness, itching, swelling and skin lichenification), decreased transepidermal water loss (TEWL) and increased skin hydration. In addition, gracillin strongly inhibited PI-induced IL-4 expression in RBL-2H3 cells and in the skins of AD mice. Our results suggest gracillin is a potential candidate for the prevention and treatment of AD and other inflammatory skin disorders.
Fermented Dessert with Whey, Ingredients from the Peel of Jabuticaba (Myrciaria cauliflora) and an Indigenous Culture of Lactobacillus plantarum: Composition, Microbial Viability, Antioxidant Capacity and Sensory Features
Authors: Almeida Neta Maria Carmélia , Rocha de Queiroga Anna Paula , Almeida Raphael Lucas Jacinto , Caetano Soares Anderson , Marinho Gonçalves Jade , Soares Fernandes Suenia , De Sousa Marina Cínthia , Olbrich dos Santos Karina Maria , Alonso Buriti Flávia Carolina , Rolim Florentino Eliane
Published: September 2018

The use of agro-industrial wastes in combination with indigenous lactic acid bacteria is an interesting option to confer functional potential to food products. The microbial viability, chemical composition, antioxidant capacity, texture and sensory acceptability of a fermented dairy dessert containing the indigenous culture Lactobacillus plantarum CNPC003, whey and ingredients obtained from the jabuticaba (Myrciaria cauliflora) peel were compared with formulations without lactobacilli (control) or containing a commercial probiotic culture (Lactobacillus rhamnosus LR32). L. plantarum presented viability higher than 7 log CFU g−1 in the dessert, as did the commercial probiotic, for 21 days at 4 ± 1 °C. Total phenolic contents (45–60 mg gallic acid equivalents, GAE, 100 g−1) were comparable to those of other studies evaluating dairy products containing plant sources. The formulations were low in fat, presenting as acceptable for overall consumption, with attractive color and appreciable texture. Considering the total antioxidant capacity, 200–250 g of dessert would be necessary to capture 1 g of 1,1-diphenyl-2-picrylhydrazyl (DPPH) radicals. The dessert with Lactobacillus plantarum CNPC003 is seen as a viable alternative for the use of whey and jabuticaba peel, as well as a potential functional food due to the concentration of lactobacilli reached, besides the presence of antioxidant phenolic compounds.
Comparison of Inductively Coupled Plasma Optical Emission Spectrometry with an Ion Selective Electrode to Determine Sodium and Potassium Levels in Human Milk
Authors: Lai Ching Tat , Gardner Hazel , Geddes Donna
Published: September 2018

Sodium (Na), potassium (K), and the ratio Na:K in human milk (HM) may be useful biomarkers to indicate secretory activation or inflammation in the breast. Previously, these elements have been measured in a laboratory setting requiring expensive equipment and relatively large amounts of HM. The aim of this study was to compare measurements of Na and K in HM using inductively coupled plasma optical emission spectrometry (ICP-OES) with small portable ion selective electrode probes for Na and K. Sixty-five lactating women donated 5 mL samples of HM. Samples were analyzed with two ion selective probes (Na and K) and also ICP-OES. The data were analyzed using paired t-test and Bland–Altman plots. Na concentrations were not significantly different when measured with ion selective electrode (6.18 ± 2.47mM; range: 3.59–19.8) and ICP-OES (5.91 ± 3.37 mM; range: 2.59–21.5) (p = 0.20). K concentrations measured using the ion selective electrode (11.7 ± 2.21 mM: range: 7.69–18.1) and ICP-OES (11.1 ± 1.55 mM: range: 7.91–15.2) were significantly different (p = 0.01). However, the mean differences of 0.65 mM would not be clinically relevant when testing at point of care. Compared to ICP-OES, ion selective electrode is sufficiently accurate to detect changes in concentrations of Na and K in HM associated with secretory activation and inflammation in the mammary gland.
Sleep Duration and Excessive Daytime Sleepiness Are Associated with Obesity Independent of Diet and Physical Activity
Authors: Maugeri Andrea , Medina-Inojosa Jose R. , Kunzova Sarka , Agodi Antonella , Barchitta Martina , Sochor Ondrej , Lopez-Jimenez Francisco , Geda Yonas E. , Vinciguerra Manlio
Published: September 2018

In the European Union, Czech Republic ranks 3rd and 6th for the incidence of obesity and cardiovascular diseases, respectively. Worldwide, short sleep duration and excessive daytime sleepiness (EDS) characterize obese subjects, which in turn exhibit scarce physical activity and unhealthy diet. We aimed to understand the relationship between irregular sleep patterns, obesity and lifestyle factors, such as diet and physical activity, in a vulnerable Czech population. 1482 members of the Kardiovize cohort, a random sample of the Czech urban population, were included in a cross-sectional study. Exposure variables included self-reported sleep duration and EDS, assessed by the Epworth Sleepiness Scale. Primary outcomes were BMI and waist-to-hip ratio or prevalence of obesity and central obesity. Covariates included physical activity and diet. Associations and interactions between variables were evaluated using logistic regression analyses. After adjustment for covariates, short sleep duration (<7 h) was associated with greater odds of overweight (BMI > 25; OR = 1.42; 95%CI = 1.06–1.90; p = 0.020) and obesity (BMI > 30; OR = 1.40; 95%CI = 1.02–1.94; p = 0.047), while EDS was associated with greater odds of central obesity (OR = 1.72; 95%CI = 1.06–2.79; p = 0.030), independent of diet and physical activity. However, due to the cross-sectional nature of our study, further prospective, large-scale studies are needed to evaluate the etiological link and causality between sleep disturbances and obesity.
Anti-Obesity Activities of Chikusetsusaponin IVa and Dolichos lablab L. Seeds
Authors: Yin Jun , Seo Chang-Seob , Hwang In Hyeok , Lee Min Won , Song Kwang Hoon
Published: September 2018

Obesity, a condition where excess body fat accumulates to the extent, causes a negative effect on health. Previously, we reported the extract of Dolichos lablab L. (DLL-Ex) inhibited high-fat diet (HFD)-induced increases in body weight and body fat mass and ameliorated increases in body weight. In the present work, we studyed the molecular mechanism for the inhibitory effect of DLL-Ex or Chikusetsusaponin IVa (CS-IVa), as isolated from Dolichos lablab L. (DLL) seeds extract, on adipocyte differentiation. We evaluated the effect of DLL-Ex, an anti-obesity agent, and CS-IVa, an active component of DLL-Ex, on 3T3-L1 cell differentiation via Oil red O assay and Q-PCR, along with their effects on CCAAT element binding protein alpha (C/EBPα), peroxisome proliferator-activated receptor gamma (PPARγ), fatty acid synthase (FAS), and fatty acid-binding protein 4 (FABP4) mRNA transcriptions. FAS and FABP4 protein expression levels after exposure to CS-IVa were also tested. The results showed that DLL-Ex and CS-IVa have potent inhibitory activity on adipocyte differentiation. Therefore, DLL and CS-IVa may be developed as a functional food material to treat obesity.
Modulation of Iron Metabolism in Response to Infection: Twists for All Tastes
Authors: Gomes Ana Cordeiro , Moreira Ana C. , Mesquita Gonçalo , Gomes Maria Salomé
Published: September 2018

Iron is an essential nutrient for almost all living organisms, but is not easily made available. Hosts and pathogens engage in a fight for the metal during an infection, leading to major alterations in the host’s iron metabolism. Important pathological consequences can emerge from the mentioned interaction, including anemia. Several recent reports have highlighted the alterations in iron metabolism caused by different types of infection, and several possible therapeutic strategies emerge, based on the targeting of the host’s iron metabolism. Here, we review the most recent literature on iron metabolism alterations that are induced by infection, the consequent development of anemia, and the potential therapeutic approaches to modulate iron metabolism in order to correct iron-related pathologies and control the ongoing infection.
Eating Disorders in Relationship with Dietary Habits among Pharmacy Students in Romania
Authors: Iorga Magdalena , Manole Isabela , Pop Lavinia , Muraru Iulia-Diana , Petrariu Florin-Dumitru
Published: September 2018

Changing dietary habits of university students is due to personal, social, educational or religious factors. The relationship between dietary habits and presence of eating disorders among university students is less known in Romania. Material and Methods: Ninety-one pharmacy students (91.21% women) were included in the research. Socio-demographic, anthropometric, medical, and psychological data were collected. Dietary self-declared habits were registered. The analysis of data was done using SPSS, v23. Results: A total of 69.2% of students had normal weight, 64.84% preferred to have lunch, and 23.08% eat during nights. The majority of subjects (95.6%), stated that they eat snacks daily. More than one-third of students keep diets to reduce their weight. Younger students tend to eat more main meals per week, snack more, and eat later after getting up in the morning. Subjects with high body dissatisfaction tended to have fewer main meals (r = −0.265, p = 0.011) and to skip breakfasts (−0.235, p = 0.025) and dinners (r = −0.303, p < 0.001). Pharmacy students that presented higher rate of emotional problems tend to sleep less and skip breakfast. Conclusions: Female pharmacy students had higher mean scores on all subscales than those found among Romanian women. A strong relationship between dietary habits and eating disorders was identified.
Designing the Slide-Ring Polymer Network with both Good Mechanical and Damping Properties via Molecular Dynamics Simulation
Authors: Zhang Zhiyu , Hou Guanyi , Shen Jianxiang , Liu Jun , Gao Yangyang , Zhao Xiuying , Zhang Liqun
Published: September 2018

Through coarse-grained molecular dynamics simulation, we have successfully designed the chemically cross-linked (fixed junction) and the slide-ring (SR) systems. Firstly, we examine the dynamic properties such as the mean-square displacement, the bond, and the end-to-end autocorrelation functions as a function of the cross-linking density, consistently pointing out that the SR system exhibits much lower mobility compared with the fixed junction one at the same cross-linking density. This is further validated by a relatively higher glass transition temperature for the SR system compared with that of the fixed junction one. Then, we calculated the effect of the cross-linking density on the stretch-recovery behavior for the SR and fixed junction systems. Although the chain orientation of the SR system is higher than that of the fixed-junction system, the tensile stress is smaller than the latter. We infer that much greater chain sliding can occur during the stretch, because the movable ring structure homogeneously sustains the external force of the SR system, which, therefore, leads to much larger permanent set and higher hysteresis during the recovery process compared with the fixed-junction one. Based on the stretch-recovery behavior for various cross-linking densities, we obtain the change of the hysteresis loss, which is larger for the SR system than that of the fixed junction system. Lastly, we note that the relatively bigger compressive stress for the SR system results from the aggregation of the rigid rings compared with the fixed junction system. In general, compared with the traditionally cross-linked system, a deep molecular-level insight into the slide-ring polymer network is offered and thus is believed to provide some guidance to the design and preparation of the slide-ring polymer network with both good mechanical and damping properties.
Static-Aligned Piezoelectric Poly (Vinylidene Fluoride) Electrospun Nanofibers/MWCNT Composite Membrane: Facile Method
Authors: Shehata Nader , Elnabawy Eman , Abdelkader Mohamed , Hassanin Ahmed H. , Salah Mohamed , Nair Remya , Ahmad Bhat Sameer
Published: September 2018

Polyvinylidene Fluoride (PVDF) piezoelectric electrospun nanofibers have been intensively used for sensing and actuation applications in the last decade. However, in most cases, random PVDF piezoelectric nanofiber mats have moderate piezoelectric response compared to aligned PVDF nanofibers. In this work, we demonstrate the effect of alignment conducted by a collector setup composed of two-metal bars with gab inside where the aligned fiber can be formed. That is what we called static aligned nanofibers, which is distinct from the dynamic traditional technique using a high speed rotating drum. The two-bar system shows a superior alignment degree for the PVDF nanofibers. Also, the effect of added carbon nanotubes (CNTs) of different concentrations to PVDF nanofibers is studied to observe the enhancement of piezoelectric response of PVDF nanofibers. Improvement of β-phase content of aligned (PVDF) nanofibers, as compared to randomly orientated fibers, is achieved. Significant change in the piezoelectricity of PVDF fiber is produced with added CNTs with saturation response in the case of 0.3 wt % doping of CNTs, and piezoelectric sensitivity of 73.8 mV/g with applied masses down to 100 g.
Experimentally Verified Mathematical Model of Polymer Plasticization Process in Injection Molding
Authors: Iwko Jacek , Steller Ryszard , Wróblewski Roman
Published: September 2018

The mathematical model of the polymer plasticization in the reciprocating screw injection moulding machine is presented in this paper. Methods of calculation of the most important flow characteristics, such as the solid bed profile, the pressure and temperature profiles, the mass flow rate, the power demand, the screw torque and the energy consumption were analysed. According to the mathematical model, a computer program was developed. Based on the computer program, simulation studies of the injection moulding process were conducted. Thereafter, the experimental studies, evaluating the theoretical model from the accuracy and usefulness point of view, were carried out. Important output quantities, such as the temperature and pressure profiles, the power demand by the screw, the torque on the screw and the screw rotation time were measured. The studies were performed on a specially made research office. The simulation results were compared with the experimental data measured for the most popular polymers and different operating parameters of the injection machine. The experimental studies have indicated the need to introduce some corrections to the mathematical model. Several modifications have been made to the model, mainly related to the methods of stress determining in the polymer layer. Finally, the output characteristics of the plasticization process in the injection moulding are now correctly determined by the model with an average error less than 10%.
Characterization of Irradiation Crosslinked Polyamides for Solar Thermal Applications—Basic Thermo-Analytical and Mechanical Properties
Authors: Bradler Patrick R. , Fischer Joerg , Wallner Gernot M. , Lang Reinhold W.
Published: September 2018

Polyamide 66 (PA 66) and short glass fiber reinforced versions of PA 66 are widely used for solar-thermal applications, in which thermal and environmental loading of components is from high importance. In this study, the influence of crosslinking via electronic beam irradiation on the morphology and mechanical behavior of unreinforced PA 66 and two types of short glass fiber reinforced PA 66 (30 wt % glass fiber content, 35 wt % glass fiber content) was investigated. In total, five different electronic beam irradiation doses in the range of 0 and 200 kGy were applied. Besides experiments with unconditioned specimens, also preconditioned specimens saturated with water at 80 °C for seven days were investigated. It was found that irradiation causes a shift to lower melting temperatures and lower melting enthalpies, while simultaneously leading to higher glass transition temperatures (TG), increasing small strain modulus values and higher tensile strengths. Also, as expected, preconditioning samples in water at 80 °C to water uptake saturation leads to a shift to lower TG values (‘plasticization’ effect). In terms of tensile behavior at room temperature, water saturated specimens (being above TG at room temperature) exhibited lower modulus and tensile strength values compared to quasi-dry specimens (being below TG at room temperature).
Influence of Network Structure on the Crystallization Behavior in Chemically Crosslinked Hydrogels
Authors: Zhang Zhenfang , Li Qian , Yesildag Cigdem , Bartsch Christoph , Zhang Xiaoyuan , Liu Wei , Loebus Axel , Su Zhiqiang , Lensen Marga C.
Published: September 2018

The network structure of hydrogels is a vital factor to determine their physical properties. Two network structures within hydrogels based on eight-arm star-shaped poly(ethylene glycol)(8PEG) have been obtained; the distinction between the two depends on the way in which the macromonomers were crosslinked: either by (i) commonly-used photo-initiated chain-growth polymerization (8PEG–UV), or (ii) Michael addition step-growth polymerization (8PEG–NH3). The crystallization of hydrogels is facilitated by a solvent drying process to obtain a thin hydrogel film. Polarized optical microscopy (POM) results reveal that, while in the 8PEG–UV hydrogels only nano-scaled crystallites are apparent, the 8PEG–NH3 hydrogels exhibit an assembly of giant crystalline domains with spherulite sizes ranging from 100 to 400 µm. Scanning electron microscopy (SEM) and atomic force microscopy (AFM) analyses further confirm these results. A model has been proposed to elucidate the correlations between the polymer network structures and the crystallization behavior of PEG-based hydrogels.
An Investigation of the Compressive Behavior of Polymer Electrode Membrane Fuel Cell’s Gas Diffusion Layers under Different Temperatures
Authors: Chen Yanqin , Jiang Chao , Cho Chongdu
Published: September 2018

In this paper, a commercial gas diffusion layer is used, to quantitatively study the correlation between its compressive characteristics and its operating temperature. In polymer electrode membrane fuel cells, the gas diffusion layer plays a vital role in the membrane electrode assembly, over a wide range of operating temperatures. Therefore, understanding the thermo-mechanical performance of gas diffusion layers is crucial to design fuel cells. In this research, a series of compressive tests were conducted on a commercial gas diffusion layer, at three different temperatures. Additionally, a microscopical investigation was carried out with the help of a scanning electron microscope, to study the evolution and development of the microstructural damages in the gas diffusion layers which is caused by the thermo-mechanical load. From the obtained results, it could be concluded that the compressive stiffness of the commercial gas diffusion layer depends, to a great extent, on its operational temperature.
Viscoelastic Properties of Unentangled Multicyclic Polystyrenes
Authors: Yan Zhi-Chao , Hossain Md. D. , Monteiro Michael J. , Vlassopoulos Dimitris
Published: September 2018

We report on the viscoelastic properties of linear, monocyclic, and multicyclic polystyrenes with the same low molecular weight. All polymers investigated were found to exhibit unentangled dynamics. For monocyclic polymers without inner loops, a cyclic-Rouse model complemented by the contribution of unlinked chains (whose fraction was determined experimentally) captured the observed rheological response. On the other hand, multicyclic polymers with inner loops were shown to follow a hierarchical cyclic-Rouse relaxation with the outer loops relaxing first, followed by the inner loop relaxation. The influence of unlinked linear chains was less significant in multicyclic polymers with inner loops. The isofrictional zero-shear viscosity decreased with increasing number of constrained segments on the coupling sites, which was attributed to the decreasing loop size and the dilution effect due to the hierarchical relaxation.
Phase Separation Driven On-Demand Debondable Waterborne Pressure-Sensitive Adhesives
Authors: Mehravar Ehsan , Gross Michael A. , Leal Gracia Patricia , Reck Bernd , Leiza Jose R. , Asua José M.
Published: September 2018

A waterborne pressure-sensitive adhesive (PSA) that shows high adhesive performance and easy debondability on demand without leaving residues on the substrate (adhesive failure) has been developed. A key component of the PSA is a semicrystalline phase that is beneficial for the adhesive properties and that becomes fluid when heated above the melting temperature. Migration of this liquid-like polymer to the substrate-adhesive interface and hardening upon cooling results in a hard non-tacky interface that facilitates debonding. The effect of the particle morphology on the debonding ability is discussed.
Supported Ionic Liquid Membranes for Separation of Lignin Aqueous Solutions
Authors: Abejón Ricardo , Rabadán Javier , Lanza Silvia , Abejón Azucena , Garea Aurora , Irabien Angel
Published: September 2018

Lignin valorization is a key aspect to design sustainable management systems for lignocellulosic biomass. The successful implementation of bio-refineries requires high value added applications for the chemicals derived from lignin. Without effective separation processes, the achievement of this purpose is difficult. Supported ionic liquid membranes can play a relevant role in the separation and purification of lignocellulosic components. This work investigated different supported ionic liquid membranes for selective transport of two different types of technical lignins (Kraft lignin and lignosulphonate) and monosaccharides (xylose and glucose) in aqueous solution. Although five different membrane supports and nine ionic liquids were tested, only the system composed by [BMIM][DBP] as an ionic liquid and polytetrafluoroethylene (PTFE) as a membrane support allowed the selective transport of the tested solutes. The results obtained with this selective membrane demonstrated that lignins were more slowly transferred from the feed compartment to the stripping compartment through the membrane than the monosaccharides. A model was proposed to calculate the effective mass transfer constants of the solutes through the membrane (values in the range 0.5–2.0 × 10−3 m/h). Nevertheless, the stability of this identified selective membrane and its potential to be implemented in effective separation processes must be further analyzed.
Simulation and Test Bed of a Low-Power Digital Excitation System for Industry 4.0
Authors: Huh Jun-Ho , Lee Hoon-Gi
Published: September 2018

Since modeling and simulation are the two most effective tools that can be used in the design or analysis process, they play a vital role in developing such system. In many cases, they are the only possible means of making a safe engineering decision for a new concept of process for a large-scale system. Elsewhere, they are used as a critical element in the analysis of energy systems or to suggest a method of developing a novel and effective energy system model. Thus, in this study, simulations and test bed experiment were carried out to assess a low-power digital excitation system in order to validate its effectiveness. The excitation systems currently used by most of the power stations in the Republic of Korea were installed during the 1970s or 1980s. Unfortunately, it is difficult to seek technical assistance for them as they depend on foreign technologies, requiring a large sum to be paid when requesting one or more engineers to be dispatched. As such, technical updates have always been made by foreign companies, since it is not easy to make modifications to the system without the help of the original system developer. The technology developed in this study was designed to address such problem. The inability to conduct a test for an actual system can be solved by using a power system analysis program to analyze the characteristics of the controller. The study confirmed the system’s effectiveness, and the Test Bed was proven to be flexible and adequate for the experiment. The proposed excitation system is expected to increase the stability and economic effect of the system by optimizing existing systems. In the future, the authors plan to focus on student education by establishing an education system that allows students to learn about the digital excitation system and its simulation.
A Numerical Study of Stress Distribution and Fracture Development above a Protective Coal Seam in Longwall Mining
Authors: Zhang Chunlei , Yu Lei , Feng Ruimin , Zhang Yong , Zhang Guojun
Published: September 2018

Coal and gas outbursts are serious safety concerns in the Chinese coal industry. Mining of the upper or lower protective coal seams has been widely used to minimize this problem. This paper presents new findings from longwall mining-induced fractures, stress distribution changes in roof strata, strata movement and gas flow dynamics after the lower protective coal seam is extracted in a deep underground coal mine in Jincheng, China. Two Flac3D models with varying gob loading characteristics as a function of face advance were analyzed to assess the effect of gob behavior on stress relief in the protected coal seam. The gob behavior in the models is incorporated by applying variable force to the floor and roof behind the longwall face to simulate gob loading characteristics in the field. The influence of mining height on the stress-relief in protected coal seam is also incorporated. The stress relief coefficient and relief angle were introduced as two essential parameters to evaluate the stress relief effect in different regions of protected coal seam. The results showed that the rock mass above the protective coal seam can be divided into five zones in the horizontal direction, i.e. pre-mining zone, compression zone, expansion zone, recovery zone and re-compacted zone. The volume expansion or the dilation zone with high gas concentration is the best location to drill boreholes for gas drainage in both the protected coal seam and the protective coal seam. The research results are helpful to understand the gas flow mechanism around the coal seam and guide industry people to optimize borehole layouts in order to eliminate the coal and gas outburst hazard. The gas drainage programs are provided in the final section.
Quantitative Estimates of Nonlinear Flow Characteristics of Deformable Rough-Walled Rock Fractures with Various Lithologies
Authors: Yin Qian , He Lixin , Jing Hongwen , Zhu Dong
Published: September 2018

The existence of surface roughness, various contact conditions and the occurrence of flow nonlinearity make the flow process in natural rock fractures more complicated. To evaluate the fluid flow regimes in deformable rough-walled rock fractures, a great many hydromechanical tests were conducted on nine real fractures artificially produced from a wide range of lithological diversity. For fractures with a certain JRC (fracture roughness coefficient) value, the confining pressure varied from 5 to 20 MPa, and the hydraulic pressure was increased from 0.4 to 6.0 MPa. The experimental results display that (i) regression analyses of the raw experimental data indicate that the Forchheimer’s law provides a perfect description for flow process through the fractures. The coefficients of viscous and inertial pressure drops undergo a growth of 2–3 orders of magnitude with an increase in the confining pressure; (ii) the hydraulic aperture decreases by approximately 87.41–92.81% as the confining pressure increases, and experiences a decrease of 1.52–2.96 times with the JRC values. A power-law function is used to evaluate the hydraulic aperture as a function of the nonlinear coefficient. The nonlinear coefficient decreases with increasing hydraulic aperture; (iii) using Forchheimer equation, the critical Reynolds number Rec was successfully assessed by choosing E percentage (generally 10%) of the nonlinear effect as the critical value between the linear and nonlinear flow regimes. The obtained Rec steadily increases with increasing confining pressure, while it diminishes with the JRC values; and (v) the transmissivity decreases as the pressure gradient increases. Additionally, transmissivity also exhibits a decreasing trend with both the confining pressures and JRC values due to fracture closure and tortuous and channeling flow paths in rougher fractures, and the rate of its decrease for a smaller confining pressure (5, 10 MPa) is more significant.
Energy and Exergy Analysis of the S-CO2 Brayton Cycle Coupled with Bottoming Cycles
Authors: Siddiqui Muhammad , Taimoor Aqeel , Almitani Khalid
Published: September 2018

Supercritical carbon dioxide (S-CO2) Brayton cycles (BC) are soon to be a competitive and environment friendly power generation technology. Progressive technological developments in turbo-machineries and heat exchangers have boosted the idea of using S-CO2 in a closed-loop BC. This paper describes and discusses energy and exergy analysis of S-CO2 BC in cascade arrangement with a secondary cycle using CO2, R134a, ammonia, or argon as working fluids. Pressure drop in the cycle is considered, and its effect on the overall performance is investigated. No specific heat source is considered, thus any heat source capable of providing temperature in the range from 500 °C to 850 °C can be utilized, such as solar energy, gas turbine exhaust, nuclear waste heat, etc. The commercial software ‘Aspen HYSYS version 9’ (Aspen Technology, Inc., Bedford, MA, USA) is used for simulations. Comparisons with the literature and simulation results are discussed first for the standalone S-CO2 BC. Energy analysis is done for the combined cycle to inspect the parameters affecting the cycle performance. The second law efficiency is calculated, and exergy losses incurred in different components of the cycle are discussed.
Detection of Functional Overreaching in Endurance Athletes Using Proteomics
Authors: Nieman David C. , Groen Arnoud J. , Pugachev Artyom , Vacca Gianmarco
Published: September 2018

No reliable biomarkers exist to identify athletes in various training states including functional overreaching (FOR), non-functional overreaching (NFOR), and overtraining syndrome (OTS). Participants (N = 10, age 38.3 ± 3.4 years) served as their own controls and in random, counterbalanced order either ran/cycled 2.5 h (70.0 ± 3.7% VO2max) three days in a row (FOR) or sat in the lab (rest) (separated by three weeks; 7:00–9:30 am, overnight fasted state). Participants provided fingerprick samples for dried blood spot samples (DBS) pre- and post-exercise/rest, and then during two recovery days. DBS proteins were measured with nanoLC-MS in data-independent acquisition (DIA) mode, and 593 proteins were identified and quantified. Proteins were considered for the FOR cluster if they were elevated during one of the two recovery days but not more than one of the exercise days (compared to rest). The generalized estimating equation (GEE) was used to identify proteins linked to FOR. A total of 13 proteins was linked to FOR and most were associated with the acute phase response and innate immune system activation. This study used a system-wide proteomics approach to define a targeted panel of blood proteins related to FOR that could form the basis of future NFOR- and OTS-based studies.
Mean Field Game with Delay: A Toy Model
Authors: Fouque Jean-Pierre , Zhang Zhaoyu
Published: September 2018

We study a toy model of linear-quadratic mean field game with delay. We “lift” the delayed dynamic into an infinite dimensional space, and recast the mean field game system which is made of a forward Kolmogorov equation and a backward Hamilton-Jacobi-Bellman equation. We identify the corresponding master equation. A solution to this master equation is computed, and we show that it provides an approximation to a Nash equilibrium of the finite player game.
Can Multispectral Information Improve Remotely Sensed Estimates of Total Suspended Solids? A Statistical Study in Chesapeake Bay
Authors: DeLuca Nicole M. , Zaitchik Benjamin F. , Curriero Frank C.
Published: September 2018

Total suspended solids (TSS) is an important environmental parameter to monitor in the Chesapeake Bay due to its effects on submerged aquatic vegetation, pathogen abundance, and habitat damage for other aquatic life. Chesapeake Bay is home to an extensive and continuous network of in situ water quality monitoring stations that include TSS measurements. Satellite remote sensing can address the limited spatial and temporal extent of in situ sampling and has proven to be a valuable tool for monitoring water quality in estuarine systems. Most algorithms that derive TSS concentration in estuarine environments from satellite ocean color sensors utilize only the red and near-infrared bands due to the observed correlation with TSS concentration. In this study, we investigate whether utilizing additional wavelengths from the Moderate Resolution Imaging Spectroradiometer (MODIS) as inputs to various statistical and machine learning models can improve satellite-derived TSS estimates in the Chesapeake Bay. After optimizing the best performing multispectral model, a Random Forest regression, we compare its results to those from a widely used single-band algorithm for the Chesapeake Bay. We find that the Random Forest model modestly outperforms the single-band algorithm on a holdout cross-validation dataset and offers particular advantages under high TSS conditions. We also find that both methods are similarly generalizable throughout various partitions of space and time. The multispectral Random Forest model is, however, more data intensive than the single band algorithm, so the objectives of the application will ultimately determine which method is more appropriate.
Estimation of Rice Height and Biomass Using Multitemporal SAR Sentinel-1 for Camargue, Southern France
Authors: Ndikumana Emile , Ho Tong Minh Dinh , Dang Nguyen Hai Thu , Baghdadi Nicolas , Courault Dominique , Hossard Laure , El Moussawi Ibrahim
Published: September 2018

The research and improvement of methods to be used for crop monitoring are currently major challenges, especially for radar images due to their speckle noise nature. The European Space Agency’s (ESA) Sentinel-1 constellation provides synthetic aperture radar (SAR) images coverage with a 6-day revisit period at a high spatial resolution of pixel spacing of 20 m. Sentinel-1 data are considerably useful, as they provide valuable information of the vegetation cover. The objective of this work is to study the capabilities of multitemporal radar images for rice height and dry biomass retrievals using Sentinel-1 data. To do this, we train Sentinel-1 data against ground measurements with classical machine learning techniques (Multiple Linear Regression (MLR), Support Vector Regression (SVR) and Random Forest (RF)) to estimate rice height and dry biomass. The study is carried out on a multitemporal Sentinel-1 dataset acquired from May 2017 to September 2017 over the Camargue region, southern France. The ground in-situ measurements were made in the same period to collect rice height and dry biomass over 11 rice fields. The images were processed in order to produce a radar stack in C-band including dual-polarization VV (Vertical receive and Vertical transmit) and VH (Vertical receive and Horizontal transmit) data. We found that non-parametric methods (SVR and RF) had a better performance over the parametric MLR method for rice biophysical parameter retrievals. The accuracy of rice height estimation showed that rice height retrieval was strongly correlated to the in-situ rice height from dual-polarization, in which Random Forest yielded the best performance with correlation coefficient R 2 = 0.92 and the root mean square error (RMSE) 16% (7.9 cm). In addition, we demonstrated that the correlation of Sentinel-1 signal to the biomass was also very high in VH polarization with R 2 = 0.9 and RMSE = 18% (162 g·m − 2 ) (with Random Forest method). Such results indicate that the highly qualified Sentinel-1 radar data could be well exploited for rice biomass and height retrieval and they could be used for operational tasks.