bluuebunny/crossref_metadata_2025 huggingface dataset:
Lahars in Java: Initiations, Dynamics, Hazard Assessment And Deposition Processes
Authors: Lavigne Franck , Thouret Jean-Claude , Hadmoko Danang Sri , Sukatja Bambang
Published: January 2017

Lahar has been applied as a general term for rapidly flowing, high-concentration, poorly sorted sediment-laden mixtures of rock debris and water (other than normal streamflow) from a volcano. Lahars are one of the most destructive phenomena associated with composite volcanoes, which are dominant in Java Island. Resulting deposits of lahar are poorly sorted, massive, made up of clasts (chiefly of volcanic composition), that generally include a mud-poor matrix. The aim of this research is threefold: to discuss the initiation of lahars occurrences, their dynamics, to assess the hazard and to analyse the deposition. Lahars are either a direct result of eruptive activity or not temporally related to eruptions. Syn-eruptive lahars may result from the transformation on pyroclastic flows or debris avalanches which transform to aqueous flows (e.g. at Papandayan in November 2002); They may be also generated through lake outburst or breaching (e.g. at Kelut in 1909 or 1966), and through removal of pyroclastic debris by subsequent heavy rainstorms. Post-eruptive lahar occurs during several years after an eruption. At Merapi, lahars are commonly rain-triggered by rainfalls having an average intensity of about 40 mm in 2 hours. Most occur during the rainy season from November to April. Non-eruptive lahars are flows generated without eruptive activity, particularly in the case of a debris avalanche or a lake outburst (e.g., Kelut). A lahar may include one or more discrete flow processes and encompass a variety of rheological flow types and flow transformations. As such, lahars encompass a continuum between debris flows and hyperconcentrated flows, as observed at Merapi, Kelut and Semeru volcanoes. Debris flows, with water contents ranging from 10 to no more than about 25% weight, are non-newtonian fluids that move as fairly coherent masses in what is thought to be predominantly laminar fashion. However, the relative importance of laminar versus turbulent regime is still debatable. Hyperconcentrated streamflows contain 25- to about 40%-weight-water; these flows possess some yield stress, but they are characteristically turbulent. Hazard-zone maps for lahar were produced for most of the the Javanese volcanoes, but these maps are on too small-scale to meet modern zoning requirements. More recently, a few large-scale maps (1/10,000 and 1/2,000-scale) and risk assessments have been completed for a few critical river systems at Merapi.
Earthquake Disaster of Yogyakarta and Central Java, and Disaster Reduction, Indonesia
Authors: Sutikno Sutikno
Published: January 2017

This paper discussed on earthquake disaster and its reduction of Yogyakarta and Central Java, Indonesia. The study area is located at relatively a short distance from subduction zone of India-Australian and Eurasian plates. Geologically this area is characterized by fault and graben structure, and geomorphologically is composed of block mountain, karsts topography and fluvio-volcanic plain. Aim of this paper is to evaluate the spatial distribution of the damage area, the environmental impacts, and to discuss the risk reduction of earthquake disaster scientifically and practically. In this paper to determine the hazard susceptibility zone and their environmental impact used geologic, geomorphologic, land use map, remote sensing image interpretation, and field observation. Discussion on the earthquake disaster risk reduction based on the hazard susceptibility and the characteristic of the human settlement and facilities. The result of this study shows that: i).the high damage area associate with distribution of the fault structures and the lithology; ii). mass-movement, lowering of groundwater, rising new springs, liquefaction, cracking of rocks and land surface; iii). structural non structural efforts are used for earthquake disaster reduction.
Kajian Peran Waduk Sebagai Pengendali Kualitas Air Secara Alami
Authors: Supangat Agung B. , Paimin Paimin
Published: January 2017

In Indonesia it was identified that there were much of polluted stream flow which cause improper consumed water. One of the rivers which has low of water qualities is Citarum River, West Java. However, along the Citarum river, there were built three reservoir dams (Saguling, Cirata and Jatiluhur) that can control the condition of river water regime. Research was conducted in Citarum watershed to determine the role of those reservoirs on water quality control. Seven stations along the river were selected as observation posts of water samples. Based on the observation results it was indicated that water pollutants within Citarum river was very high. However, those pollutants could be purified or reduced by those reservoirs, hence water discharge from the reservoirs has better quality. In the future, deposition of those pollutants within the dam may has negative environment impact. Therefore, to sustain that function of the dam, comprehensive efforts on reducing pollutants from the catchment area is urgently required.
Urang Cave Karst Environmental Development, as Tourism Object
Authors: Srijono Srijono , Nadia Nisa
Published: January 2017

Karst environment become an alternative tourist destination as well as to boost local revenues. In karst environments in Grobogan District, Central Java Province, formed Urang Cave, with an interesting endokarst phenomenon. This study aims to do zoning district Urang Cave as tourist sites. The research method is using contour maps as a base map of Urang Cave karst environment geomorphological mapping. Geomorphological data processing is using ArcView GIS 3.3 program. Land use map refers to RBI, scale 1:25.000. Geomorphological analysis refers to the Ministry of Energy and Mineral Resources No. 1456.K/20/MEM/2000, and petrography. Each development zone is analyzed its geophysical environmental element, then set scoring and value summation. For comprehensive environmental element analysis, chemical analysis of rocks, and water-soil chemistry. In reference to Minister of Energy Mineral Resource decrees No. 1456/K/20/MEM/2000, Urang Cave zoning defined into 3 (three) zone, as follow: the Protected Zone, Cultivation Zone 1, and Cultivation Zone 2. Protected Zone, consists of Urang Cave tunnel/hallway with a unique spheleothem in it. This zone as a cave tracking site tourism, potential to produce karst water as a decent drinking water while maintaining hardness. Cultivation Zone 1 is spreading about 200 m in distance from outer appearance of spring around the cave hallway. In this zone mining of cave sediments may be done in the inactive form caves, without changing the state of the existing major exokarst morphology. Cultivation Zone 2, an outer zone, located farthest from the tunnel/hallway Urang Cave. Utilization of this zone as a limestone mining quarry, although only on a small scale.
Characteristics of Urban Heat Island Condition in DKI Jakarta
Authors: Rushayati Siti Badriyah , Hermawan Rachmad
Published: January 2017

DKI Jakarta area with high CO2 emission and 84,95 % of  built-up areas (year of 2009) cause urban heat island (UHI).  To overcome UHI problems, its characteristics must be known.  Trend analysis of surface temperature areas was conducted by comparison of surface temperature  spatial distribution of 2006 with 2010.  UHI analysis based on geograpical coordinates were also conducted.  High surface temperature of > 34 ºC was on inner city and decreasing to sub urban area.  High surface temperature were especially on high density bulit-up areas. Priority of  solving UHI problems are conducted on high surface temperature areas.
Spatial Analysis of Existing Public Open Space for Evacuation Area During Secondary Earthquake; A Case Study: Sukahaji Village, Bandung
Authors: Sagala Saut , Saraswati Sari
Published: January 2017

Population living in highly densed settlements in urban area is considered vulnerable to earthquake risk due to limited space exists in the area. To reduce population risks to aftershock earthquake in highly dense settlements, this paper applied simple simulation based on supply-demand concepts in order to understand carrying capacity of current open space for people to evacuate. The case study takes place in one of the most densed populated areas in Bandung City under aftershock earthquake.. The research integrates multi-sources of data: sattelite image, building footprint and GPS field survey to produce detailed landuse. The results show that open spaces that exist in the study area is not able to contain all residents when an aftershock occurs. Finally, this paper recommends some strategies that are necessary to reduce the risks in highly densed urban areas.
Study on The Physical Characteristics and Hydrology of 15 Watershed in East Java
Authors: Indarto Indarto
Published: January 2017

The study demonstrated the application of statistical method to describe physical and hydro-meteorological characteristics by means of time series analysis.  Fifteen(15) watersheds in East Java were selected for this study. Data input for the analysis include: physical data, rainfall and discharge. Physical data of the watershed (topography, river network, land use, and soil type) are extracted from existing database and treated using GIS Software. Daily rainfall data were collected from existing pluviometers around the region. Daily discharge data were obtained from measurement station located at the outlet of each watershed. Areal Rainfall for each watershed was determined using average value of existing pluviometers around the watershed and determined using simple arithmetic method. These time series data are then imported to RAP (River Analysis Package).  Analysis on the RAP, include: general statistical, flow duration curve (FDC), and baseflow analysis. The result then presented in graphic and tables. Research shows that among the watersheds have different physical and hydrological characteristics.
Changes in Land Cover Analysis in The Gulf Coast Kendari Using High Resolution Satellite Image (Period: 2003-2009)
Authors: Jaya Laode Muh. Golok
Published: January 2017

This research was aimed to indentify land cover change in coastal area of Kendari Bay in period 2003 to 2009. The satellite imagery data (Ikonos and Quick Bird) collected in 2003 and 2009 were used in this research to obtain the land cover change. The method used in this research was comparing the classification of satellite imagery. Field survey was conducted using handheld GPS for ground truth.  The result of this research showed us the land use change in period 2003-2009. Mangrove vegetation decreased 56.57 Ha and the fishpond also decreased 205.5 Ha. The primary forest decreased into 3.28 Ha in year 2009. The secondary forest also decreases 124.84 Ha. In the same time the urban area increased from 382.37 Ha in year 2003 to 674.37 Ha in 2009. The land use change also occured for the public space which increased from 6.49 Ha in 2003 to 18.46 Ha in 2009 or increased 11,97 Ha.
Behavior and Preparedness to Fire Hazard in High Density Settlements in Bandung
Authors: Sagala Saut , Wimbardana Ramanditya , Pratama Ferdinand Patrick
Published: January 2017

Fire is one of the hazards that may affect urban areas with high density settlements. Thus, research on fire mitigation is important to be conducted. This paper examines the behavior and preparedness of occupants in high density settlements towards fire risks in urban area. The case study is located at Kelurahan Sukahaji, Kecamatan Babakan Ciparay, Bandung that has very high density settlement as well as prone to fire hazards. This study assess 232 respondents in the study areas on information related to demography, understanding about fire, behavior and preparedness. The respondents understanding on the types of fire sources are still low. Similarly, the behavior related to the activites using fire are still dangerous because some activities are conducted with other activities which make people less aware of the fire hazards. Nevertheless, their knowledge on how to extinguish fires are quite good. This paper recommends more trainings on knowledge of fire source and behavior to be conducted to occupants living in high density settlements in order to reduce fire disaster risk.
Outburst Flood Simulation Model for Optimizing the Solo River Floods Emergency Response Activities
Authors: Priyana Yuli , Priyono Priyono , Anna Alif Noor , Sigit Agus Anggoro
Published: January 2017

This study aims to develop flood inundation based on several flood level. The results of this study are: (a) land use in the study area is divided into (1) urban area (the Business Area) which includes regional administrative center, shopping area, and office area, (2) residential areas (single home region, the region multi- unit house (residence), settlement areas and apartments), (3) industrial estate (industrial estates are less dense and dense industrial area), (4) the surface area covered with vegetation (forest - thicket, meadow area, and the area of land productive rice fields and fields), (5) the area of open land and vacant land that is intended (the city park , cemetery and park area, and (6) transportation area and the pavement surface area (area train station and bus terminal region), (b) the preparation of spatial database in this study in the form of data or data vector altitude of Digital Elevation Model (DEM). District of Jebres there are 56 points of elevation and District of Pasar Kliwon there are 48 points of elevation. Elevation of the study area ranged from 88,9 mpdal up to 127.65 mdpal and (c) the higher the flood inundation scenarios impact on land use in the study area are also getting bigger. Most obvious impact under scenario 2 m area of 296 601 m , while the smallest impact under scenario 1 m with an area of 77 693 m 2 2 impact. Extensive simulation results based on the total impact amounts to 544 756 m.
Study of Local People Perception Related to Landslide Hazard: A Case of Tawangmangu Sub-District Karanganyar Regency Indonesia
Authors: Setiawan Heru , Hizbaron Dyah R
Published: January 2017

In 2007, a series of landslides occurred at Tawangmangu, resulting in the collapse of several houses and the death of dozens of people. One essential pathway to reduce the vulnerability of communities goes through an increased preparedness. The present contribution aims to determine existing level of preparedness by analysing the people perception and knowledgeof landslides. Survey method with random sampling technique was applied to assess the level of people perception and to analysis local people knowledge regarding with landslide. The number of respondents was spread proportionally across five sub-villages; Plalar, Guyon, Sodong, Salere and Ngledoksari. The respondents were interviewed using questionnaires with open and closed questions. Statistical analysis with multiple linear regressions was applied to identify the influencing factors of local people perception related to landside. The result show that people in the area have good knowledge and perception about landslide. This condition is commonly influenced by age and education.
Potential Economic Losses Due to Tidal Inundation and Flood at Semarang City
Authors: Suhelmi Ifan R , Fahrudin Achmad , Triwibowo Ferdinand Hariyanto
Published: January 2017

Coastal city of Semarang is susceptible to the impact of coastal hazard due to its flat topographic condition. Various environmental problems are faced by Semarang involve tidal inundation, land subsidence, and floods during rainy season. This study was conducted to examine the potential economic losses caused by the sea level rise phenomenon. Distribution of inundated area mapped using Digital Elevation Model and Land Subsidence data. The Scenarios of International Panel on Climate Change (2007) sea level rises used to build a model of inundated area that notes by 2030 the rise of sea level rise at 13.4 cm. The inundated map was overlayed with landuse map to calculate the potential economic losses. The results show that the inundated area that occurred in 2030 was 1,718.2 ha with the potential economic losses Rp. 6,130 trillion. With the land subsidence scenario that happen at the area, inundated area increased to 5,171.3 ha with the eonomic potential loss about Rp. 28,724 trillion.
Community Response to Government Policies at The Potential Landslide Area: The Case in Kuloprogo Regency
Authors: Donie Syahrul
Published: January 2017

The study examined the extent of community appreciation or response to government policies at the potential lanslide areas and the influencing reasons. By interviewing 35 representative informants, men and women, and divided into old, young and adult, then the data are analyzed and interpreted using the theory of action and the theory of symbolic. The results showed, the community, dominated by the farmer, were able to respond and deeply understood the government policies, particularly policies of spatial planning. This was indicated by the increasing knowledge of the community against areas that were prone to landslide and other sign that the region was going to experience a landslide. Almost all respondents said that they live in hilly areas prone to landslides, and they knew how to cope with and respond to these signs. However, government policy declaring that the community were expected to move from the area considered as dangerous was still lack of community’s attention. This was due to the undersired experiences of the community in the new area which did not make their lives better, both in terms of livelihood as well as in terms of their social-culture life.
Conceptual Reflections on Ethics for International Research Collaborations in Disaster Impacted Areas from the Experiences in Indonesia, New Zealand and Japan
Authors: Gomez Christopher
Published: January 2017

The present contribution is by no means a first attempt at considering the ethics in human activities, interactions in disaster impacted areas, but it is more the case of looking at 'international research' that present a very particular difficulty for ethics: the notion of trans-boundary, multi-dimensional idea of one group not really belonging within another, but which will perform functions inside this second group and eventually alter, modify some of the original organs. This paper explain the reflections of the ethical consideration of international research collaboration in disaster impacted areas which are emerged from the experiences in Indonesia, New Zealand and Japan.
Perkembangan Ekonomi, Sektor Informal, dan Kemiskinan di Kota
Authors: Effendi Tadjuddin Noer
Published: January 2017

Kota-kota mengalami perkembangan yang sukup pesat. Perkembangan ini akan terus berlanjut di masa datang. Perwujudan perkembangan kota tercermin dari tingginya tingkat urbanisasi, peningkatan perkembangan ekonomi yang ditandai dengan konsentrasi berbagai macam kegiatan ekonomi, terutama industri, jasa-jasa modern, dan perdagangan skala besar. Namun, dalam proses perkembangan kota itu senantiasa dihadapkan dengan berbagai macam persoalan. Saha satunya adalah terbatasnya kemampuan kota untuk menyediakan peluang kerja bagi penghuni yang terus bertambah dengan pesat. Upaya peningkatan ekonomi kota dengan modernisasi infrastruktur kota (perbaikan jalan, sarana perkantoran, listrik, telpon, dan sebagainya) dalam rangka menarik investor terus dilakukan, tetapi upaya tersebut kurang menunjukkan hasil yang memuaskan, khususnya dalam penciptaan peluang kerja di sektor formal (modern). Sehingga angka pengangguran di kota cenderung naik. Bersamaan dengan itu, muncullah gejala sektor informal dan kemiskinan di kota.
Mis derechos y los derechos del otro. Reflexiones fenomenológicas en torno al problema del fundamento de los derechos humanos
Authors: Niel Luis Ignacio
Published: January 2017

Recibido: 28/06/15 • Aceptado: 5/10/16

En la primera parte del artículo se analizarán algunas de las posiciones filosóficas (en especial iusfilosóficas) contemporáneas más importantes, sólo en relación a su posición con respecto a los DDHH. En la segunda presentaremos nuestra propuesta. Ofreceremos una caracterización jurídico-conceptual del concepto de ‘derecho’, siguiendo la dogmática de Carlos Nino: a fin de mostrar que los DDHH no se pueden justificar desde la ciencia jurídica. Presentaremos un intento de aproximación fenomenológica al problema de los DDHH que se realizará en diferentes dimensiones que van de la esfera de constitución genética-intersubjetiva de la propia subjetividad, a la dimensión histórica, trans-generacional.

 
Unexpected Hazards with Dental High Speed Drill
Authors: Hailu Kassahun , Lawoyin David , Glascoe Alison , Jackson Andrea
Published: January 2017

An expected accident can happen at any time during a routine practice in the dental office due to the types of instruments used. One of the instruments used in routine dental practice is a high speed drill and a bur. If Personal Protective Equipment (PPE) is not practiced at any time in the dental office, very serious injuries could easily happen to the clinician, staff or to the patient.
A Fast Algorithm for the Computation of HAC Covariance Matrix Estimators
Authors: Heberle Jochen , Sattarhoff Cristina
Published: January 2017

This paper considers the algorithmic implementation of the heteroskedasticity and autocorrelation consistent (HAC) estimation problem for covariance matrices of parameter estimators. We introduce a new algorithm, mainly based on the fast Fourier transform, and show via computer simulation that our algorithm is up to 20 times faster than well-established alternative algorithms. The cumulative effect is substantial if the HAC estimation problem has to be solved repeatedly. Moreover, the bandwidth parameter has no impact on this performance. We provide a general description of the new algorithm as well as code for a reference implementation in R.
A Multi-Faceted Debris-Flood Hazard Assessment for Cougar Creek, Alberta, Canada
Authors: Jakob Matthias , Weatherly Hamish , Bale Stephanie , Perkins Ashley , MacDonald Brent
Published: January 2017

A destructive debris flood occurred between 19 and 21 June 2013 on Cougar Creek, located in Canmore, Alberta. Cougar Creek fan is likely the most densely developed alluvial fan in Canada. While no lives were lost, the event resulted in approximately $40 M of damage and closed both the Trans-Canada Highway (Highway 1) and the Canadian Pacific Railway line for a period of several days. The debris flood triggered a comprehensive hazard assessment which is the focus of this paper. Debris-flood frequencies and magnitudes are determined by combining several quantitative methods including photogrammetry, dendrochronology, radiometric dating, test pit logging, empirical relationships between rainfall volumes and sediment volumes, and landslide dam outburst flood modeling. The data analysis suggests that three distinct process types act in the watershed. The most frequent process is normal or “clearwater” floods. Less frequent but more damaging are debris floods during which excessive amounts of bedload are transported on the fan, typically associated with rapid and extensive bank erosion and channel infilling and widening. The third and most destructive process is interpreted to be landslide dam outbreak floods. This event type is estimated to occur at return periods exceeding 300 years. Using a cumulative magnitude frequency technique, the data for conventional debris floods were plotted up to the 100–300s year return period. A peak-over-threshold approach was used for landslide dam outbreak floods occurring at return periods exceeding 300 years, as not all such events were identified during test trenching. Hydrographs for 6 return period classes were approximated by using the estimated peak discharges and fitting the hydrograph shape to integrate to the debris flood volumes as determined from the frequency-magnitude relationship. The fan volume was calculated and compared with the integrated frequency-magnitude curve to check of the validity of the latter. A reasonable match was accomplished, verifying the overall relationship. The findings from this work were later used as input to a risk assessment seeking to quantify risk to loss of life and economic losses. The risk assessment then formed the basis for design of debris-flood mitigation structures.
GGCX-Associated Phenotypes: An Overview in Search of Genotype-Phenotype Correlations
Authors: De Vilder Eva , Debacker Jens , Vanakker Olivier
Published: January 2017

Gamma-carboxylation, performed by gamma-glutamyl carboxylase (GGCX), is an enzymatic process essential for activating vitamin K-dependent proteins (VKDP) with important functions in various biological processes. Mutations in the encoding GGCX gene are associated with multiple phenotypes, amongst which vitamin K-dependent coagulation factor deficiency (VKCFD1) is best known. Other patients have skin, eye, heart or bone manifestations. As genotype–phenotype correlations were never described, literature was systematically reviewed in search of patients with at least one GGCX mutation with a phenotypic description, resulting in a case series of 47 patients. Though this number was too low for statistically valid correlations—a frequent problem in orphan diseases—we demonstrate the crucial role of the horizontally transferred transmembrane domain in developing cardiac and bone manifestations. Moreover, natural history suggests ageing as the principal determinant to develop skin and eye symptoms. VKCFD1 symptoms seemed more severe in patients with both mutations in the same protein domain, though this could not be linked to a more perturbed coagulation factor function. Finally, distinct GGCX functional domains might be dedicated to carboxylation of very specific VKDP. In conclusion, this systematic review suggests that there indeed may be genotype–phenotype correlations for GGCX-related phenotypes, which can guide patient counseling and management.
Identifying the Long-Term Role of Inducible Nitric Oxide Synthase after Contusive Spinal Cord Injury Using a Transgenic Mouse Model
Authors: Maggio Dominic , Singh Amanpreet , Iorgulescu J. , Bleicher Drew , Ghosh Mousumi , Lopez Michael , Tuesta Luis , Flora Govinder , Dietrich W. , Pearse Damien
Published: January 2017

Inducible nitric oxide synthase (iNOS) is a potent mediator of oxidative stress during neuroinflammation triggered by neurotrauma or neurodegeneration. We previously demonstrated that acute iNOS inhibition attenuated iNOS levels and promoted neuroprotection and functional recovery after spinal cord injury (SCI). The present study investigated the effects of chronic iNOS ablation after SCI using inos-null mice. iNOS−/− knockout and wild-type (WT) control mice underwent a moderate thoracic (T8) contusive SCI. Locomotor function was assessed weekly, using the Basso Mouse Scale (BMS), and at the endpoint (six weeks), by footprint analysis. At the endpoint, the volume of preserved white and gray matter, as well as the number of dorsal column axons and perilesional blood vessels rostral to the injury, were quantified. At weeks two and three after SCI, iNOS−/− mice exhibited a significant locomotor improvement compared to WT controls, although a sustained improvement was not observed during later weeks. At the endpoint, iNOS−/− mice showed significantly less preserved white and gray matter, as well as fewer dorsal column axons and perilesional blood vessels, compared to WT controls. While short-term antagonism of iNOS provides histological and functional benefits, its long-term ablation after SCI may be deleterious, blocking protective or reparative processes important for angiogenesis and tissue preservation.
Phenylarsine Oxide Can Induce the Arsenite-Resistance Mutant PML Protein Solubility Changes
Authors: Jiang Yu , Chen Ye , Wang Chao , Lan Yong , Yang Chang , Wang Qian , Hussain Liaqat , Maimaitiying Yasen , Islam Khairul , Naranmandura Hua
Published: January 2017

Arsenic trioxide (As2O3) has recently become one of the most effective drugs for treatment of patient with acute promyelocytic leukemia (APL), and its molecular mechanism has also been largely investigated. However, it has been reported that As2O3 resistant patients are frequently found in relapsed APL after consolidation therapy, which is due to the point mutations in B-box type 2 motifs of promyelocytic leukemia (PML) gene. In the present study, we for the first time establish whether organic arsenic species phenylarsine oxide (PAO) could induce the mutant PML-IV (A216V) protein solubility changes and degradation. Here, three different PML protein variants (i.e., PML-IV, PML-V and mutant PML-A216V) were overexpressed in HEK293T cells and then exposed to PAO in time- and dose-dependent manners. Interestingly, PAO is found to have potential effect on induction of mutant PML-IV (A216V) protein solubility changes and degradation, but no appreciable effects were found following exposure to high concentrations of iAsIII, dimethylarsinous acid (DMAIII) and adriamycin (doxorubicin), even though they cause cell death. Our current data strongly indicate that PAO has good effects on the mutant PML protein solubility changes, and it may be helpful for improving the therapeutic strategies for arsenic-resistant APL treatments in the near future.
Potential Hybridization between Two Invasive Termite Species, Coptotermes formosanus and C. gestroi (Isoptera: Rhinotermitidae), and Its Biological and Economic Implications
Authors: Su Nan-Yao , Chouvenc Thomas , Li Hou-Feng
Published: January 2017

The Asian subterranean termite, Coptotermes gestroi, is a tropical species but has increasingly been collected from the subtropics in recent years, making it sympatric to the Formosan subterranean termite, C. formosanus in at least three areas, Taiwan, Hawaii, and Florida. Simultaneous flights by these two species were observed since 2013 in South Florida, during which interspecies tandems were observed. Laboratory mating of C. formosanus and C. gestroi alates produced hybrid incipient colonies of larger population size. Studies are underway to examine the presence in the field of hybrid colonies in sympatric areas of Taiwan and Florida. Other biological characteristics of C. formosanus × C. gestroi hybrids being studied include temperature tolerance and preference, colony growth rate, wood-consumption rate, and reproductive fertility. This current research aims to determine the potential establishment of a hybrid termite population in south Florida and Taiwan. It investigates the risk of introgressive hybridization in field populations, with an emphasis on its potential ecological, evolutionary, and economic consequences.
Au3+/Au0 Supported on Chromium(III) Terephthalate Metal Organic Framework (MIL-101) as an Efficient Heterogeneous Catalystfor Three-Component Coupling Synthesis of Propargylamines
Authors: Liu Lili , Tai Xishi , Zhou Xiaojing
Published: January 2017

Post-synthesis modification is a useful method for the functionalization of metal–organic frameworks (MOFs). A novel catalyst Au@MIL-101-ED-SA (ED = ethylenediamine, SA = salicylaldehyde), containing coexisting Au3+ ions and Au0 nanoparticles, was prepared successfully by post-synthesis modification with ethylenediamine, salicylaldehyde and gold. Gold nanoparticles supported on MIL-101 (Au@MIL-101) were prepared successfully by the impregnation method. Au@MIL-101-ED-SA and Au@MIL-101 were characterized by N2 adsorption–desorption, X-ray diffraction, infrared spectroscopy, thermogravimetric analysis, X-ray photoelectron spectroscopy, and inductively coupled plasma-optical emission spectrometry. Au@MIL-101-ED-SA and Au@MIL-101 were applied as environmentally friendly catalysts in the three-component coupling reaction of aldehydes, amines, and alkynes for the preparation of diverse propargylamines. Au@MIL-101-ED-SA contained a fraction of cationic gold (Au3+/Au0 = 0.9) and showed higher catalytic activity than Au@MIL-101, which was prepared by the impregnation method. Furthermore, the reactions were performed under heterogeneous conditions and the novel catalyst was successfully recycled for four consecutive runs.
First-Principles Study of Vacancies in Ti3SiC2 and Ti3AlC2
Authors: Wang Hui , Han Han , Yin Gen , Wang Chang-Ying , Hou Yu-Yang , Tang Jun , Dai Jian-Xing , Ren Cui-Lan , Zhang Wei , Huai Ping
Published: January 2017

MAX phase materials have attracted increased attention due to their unique combination of ceramic and metallic properties. In this study, the properties of vacancies in Ti3AlC2 and Ti3SiC2, which are two of the most widely studied MAX phases, were investigated using first-principles calculations. Our calculations indicate that the stabilities of vacancies in Ti3SiC2 and Ti3AlC2 differ greatly from those previously reported for Cr2AlC. The order of the formation energies of vacancies is VTi(a) > VTi(b) > VC > VA for both Ti3SiC2 and Ti3AlC2. Although the diffusion barriers for Ti3SiC2 and Ti3AlC2 are similar (~0.95 eV), the properties of their vacancies are significantly different. Our results show that the vacancy–vacancy interaction is attractive in Ti3AlC2 but repulsive in Ti3SiC2. The introduction of VTi and VC vacancies results in the lattice constant c along the [0001] direction increasing for both Ti3SiC2 and Ti3AlC2. In contrast, the lattice constant c decreases significantly when VA are introduced. The different effect of VA on the lattice constants is explained by enhanced interactions of nearby Ti layers.
Energy Donor Effect on the Sensing Performance for a Series of FRET-Based Two-Photon Fluorescent Hg2+ Probes
Authors: Zhang Yujin , Hu Wei
Published: January 2017

Nonlinear optical properties of a series of newly-synthesized molecular fluorescent probes for Hg2+ containing the same acceptor (rhodamine group) are analyzed by using time-dependent density functional theory in combination with analytical response theory. Special emphasis is placed on evolution of the probes’ optical properties in the absence and presence of Hg2+. These compounds show drastic changes in their photoabsorption and photoemission properties when they react with Hg2+, indicating that they are excellent candidates for ratiometric and colorimetric fluorescent chemosensors. Most importantly, the energy donor moiety is found to play a dominant role in sensing performance of these probes. Two-photon absorption cross sections of the compounds are increased with the presence of Hg2+, which theoretically suggests the possibility of the probes to be two-photon fluorescent Hg2+ sensors. Moreover, analysis of molecular orbitals is presented to explore responsive mechanism of the probes, where the fluorescence resonant energy transfer process is theoretically demonstrated. Our results elucidate the available experimental measurements. This work provides guidance for designing efficient two-photon fluorescent probes that are geared towards biological and chemical applications.
A Rapid Magnetofluidic Micromixer Using Diluted Ferrofluid
Authors: Hejazian Majid , Nguyen Nam-Trung
Published: January 2017

Effective and rapid mixing is essential for various chemical and biological assays. The present work describes a simple and low-cost micromixer based on magnetofluidic actuation. The device takes advantage of magnetoconvective secondary flow, a bulk flow induced by an external magnetic field, for mixing. A superparamagnetic stream of diluted ferrofluid and a non-magnetic stream are introduced to a straight microchannel. A permanent magnet placed next to the microchannel induced a non-uniform magnetic field. The magnetic field gradient and the mismatch in magnetic susceptibility between the two streams create a body force, which leads to rapid and efficient mixing. The micromixer reported here could achieve a high throughput and a high mixing efficiency of 88% in a relatively short microchannel.
Recent Advances in Macrocyclic Fluorescent Probes for Ion Sensing
Authors: Wong Joseph , Todd Matthew , Rutledge Peter
Published: January 2017

Small-molecule fluorescent probes play a myriad of important roles in chemical sensing. Many such systems incorporating a receptor component designed to recognise and bind a specific analyte, and a reporter or transducer component which signals the binding event with a change in fluorescence output have been developed. Fluorescent probes use a variety of mechanisms to transmit the binding event to the reporter unit, including photoinduced electron transfer (PET), charge transfer (CT), Förster resonance energy transfer (FRET), excimer formation, and aggregation induced emission (AIE) or aggregation caused quenching (ACQ). These systems respond to a wide array of potential analytes including protons, metal cations, anions, carbohydrates, and other biomolecules. This review surveys important new fluorescence-based probes for these and other analytes that have been reported over the past five years, focusing on the most widely exploited macrocyclic recognition components, those based on cyclam, calixarenes, cyclodextrins and crown ethers; other macrocyclic and non-macrocyclic receptors are also discussed.
Light Emission Intensities of Luminescent Y2O3:Eu and Gd2O3:Eu Particles of Various Sizes
Authors: Adam Jens , Metzger Wilhelm , Koch Marcus , Rogin Peter , Coenen Toon , Atchison Jennifer , König Peter
Published: January 2017

There is great technological interest in elucidating the effect of particle size on the luminescence efficiency of doped rare earth oxides. This study demonstrates unambiguously that there is a size effect and that it is not dependent on the calcination temperature. The Y2O3:Eu and Gd2O3:Eu particles used in this study were synthesized using wet chemistry to produce particles ranging in size between 7 nm and 326 nm and a commercially available phosphor. These particles were characterized using three excitation methods: UV light at 250 nm wavelength, electron beam at 10 kV, and X-rays generated at 100 kV. Regardless of the excitation source, it was found that with increasing particle diameter there is an increase in emitted light. Furthermore, dense particles emit more light than porous particles. These results can be explained by considering the larger surface area to volume ratio of the smallest particles and increased internal surface area of the pores found in the large particles. For the small particles, the additional surface area hosts adsorbates that lead to non-radiative recombination, and in the porous particles, the pore walls can quench fluorescence. This trend is valid across calcination temperatures and is evident when comparing particles from the same calcination temperature.
Needleless Melt-Electrospinning of Biodegradable Poly(Lactic Acid) Ultrafine Fibers for the Removal of Oil from Water
Authors: Li Haoyi , Li Yi , Yang Weimin , Cheng Lisheng , Tan Jing
Published: January 2017

As environmentally friendly and degradable material, Poly(lactic acid) (PLA) ultrafine fibers are promising candidates for the removal of oil from water. In this work, a self-established needleless melt-electrospinning process was used to produce PLA ultrafine fibers with diameters in the range of 800 nm–9 µm. In order to obtain ultrafine fibers, three types of hyperbranched polymers were respectively added into the melt for electrospinning. Effects of amount and molecular weight of the added hyperbranched polymers on average fiber diameter and its distribution, and contact angle were investigated. The prepared PLA ultrafine fibers exhibited superhydrophobicity with the contact angle as high as 156°, making it a potential candidate in marine oil spill recovery. The oil sorption capability of these fibers is as high as 159, 118, and 96 g/g for motor oil, crude oil, and diesel, respectively. Even after seven cycles of reuse, the fiber still maintained about 60% of its initial capacity of sorption. The kinetics of oil sorption in the film agrees very well with the pseudo-second-order kinetic model. This work is expected to promote the mass production and application of biodegradable PLA fibers in the treatment of marine oil spill pollution.
On the Pseudo Phase Diagram of Single Semi-Flexible Polymer Chains: A Flat-Histogram Monte Carlo Study
Authors: Werlich Benno , Taylor Mark , Shakirov Timur , Paul Wolfgang
Published: January 2017

Local stiffness of polymer chains is instrumental in all structure formation processes of polymers, from crystallization of synthetic polymers to protein folding and DNA compactification. We present Stochastic Approximation Monte Carlo simulations—a type of flat-histogram Monte Carlo method—determining the density of states of a model class of single semi-flexible polymer chains, and, from this, their complete thermodynamic behavior. The chains possess a rich pseudo phase diagram as a function of stiffness and temperature, displaying non-trivial ground-state morphologies. This pseudo phase diagram also depends on chain length. Differences to existing pseudo phase diagrams of semi-flexible chains in the literature emphasize the fact that the mechanism of stiffness creation matters.
Isoelectric Point Separations of Peptides and Proteins
Authors: Pergande Melissa , Cologna Stephanie
Published: January 2017

The separation of ampholytic components according to isoelectric point has played an important role in isolating, reducing complexity and improving peptide and protein detection. This brief review outlines the basics of isoelectric focusing, including a summary of the historical achievements and considerations in experimental design. Derivative methodologies of isoelectric focusing are also discussed including common detection methods used. Applications in a variety of fields using isoelectric point based separations are provided as well as an outlook on the field for future studies.
Why Organic Farming Should Embrace Co-Existence with Cisgenic Late Blight–Resistant Potato
Authors: Gheysen Godelieve , Custers René
Published: January 2017

The EU regulation on organic farming does not allow the use of genetically modified organisms (GMOs) which are subject to Directive 2001/18/EC. Mutagenesis using irradiation or chemicals is genetic modification, but the organisms obtained through these techniques are not subject to the provisions of the GMO directive. Such mutants can therefore be used in organic agriculture. Derived from its basic principles, organic farming can only use natural substances to control disease and crops should be resilient, which, in the case of disease resistance, means that durable (horizontal) resistance is preferred to vertical (single gene) resistance. Cisgenesis can achieve such a durable resistance by introducing multiple resistance genes in one step. These multiple-resistant plants only contain natural genes that can also be introduced by breeding. In case cisgenic plants are not subject to the provisions of the GMO legislation, they can even be legally used in organic agriculture. In case they are not exempted from the GMO regulation, the question is: why obstruct a cisgenic potato crop that can hardly be distinguished from a potato crop that is the result of conventional breeding? Among the reasons why organic agriculture does not allow the use of GMOs it is mentioned that genetic engineering is unpredictable, it causes genome disruption and it is unnatural. However, our knowledge of plant genome evolution and breeding has increased dramatically. We now know that breeding is more unpredictable and causes more genome disruption than genetic engineering. Recent field trials have shown the efficacy of cisgenic late blight–resistant potatoes carrying multiple resistance genes. Large-scale growing of such durably resistant potatoes would not only be environmentally beneficial by it would strongly reducing the need for fungicide sprays in conventional potato cultivation and it would also reduce the disease pressure in organic potato cultivation.
Mapping and Monitoring the Akagera Wetland in Rwanda
Authors: Ndayisaba Felix , Nahayo Lamek , Guo Hao , Bao Anming , Kayiranga Alphonse , Karamage Fidele , Nyesheja Enan
Published: January 2017

Wetland maps are a prerequisite for wetland development planning, protection, and restoration. The present study aimed at mapping and monitoring Rwanda’s Akagera Complex Wetland by means of remote sensing and geographic information systems (GIS). Landsat data, spanning from 1987 to 2015, were acquired from different sensor instruments, considering a 5-year interval during the dry season and the shuttle radar topographic mission (SRTM) digital elevation model (30-m resolution) was used to delineate the wetland. The mapping and delineation results showed that the wetland narrowly extends along the Rwanda-Tanzania border from north to south, following the course of Akagera River and the total area can be estimated at 100,229.76 ha. After waterbodies that occupy 30% of the wetland’s surface area, hippo grass and Cyperus papyrus are also predominant, representing 29.8% and 29%, respectively. Floodplain and swamp forest have also been inventoried in smaller proportions. While the wetland extent has apparently remained stable, the inhabiting waterbodies have been subject to enormous instability due to invasive species. Lakes, such as Mihindi, Ihema, Hago and Kivumba have been shrinking in extent, while Lake Rwanyakizinga has experienced a certain degree of expansion. This study represents a consistent decision support tool for Akagera wetland management in Rwanda.
Household Livelihood Strategy Choices, Impact Factors, and Environmental Consequences in Miyun Reservoir Watershed, China
Authors: Peng Wenjia , Zheng Hua , Robinson Brian , Li Cong , Wang Fengchun
Published: January 2017

Household livelihood strategies are embedded in the natural and socioeconomic contexts in which people live. Analyzing the factors that influence household livelihood choice and defining their consequences can be beneficial for informing rural household policies. In turn, this has great significance for fostering sustainable livelihood strategies. We grouped household livelihood strategies based on the income distribution of 756 households and analyzed their influencing factors and possible livelihood consequences in the watershed of Miyun Reservoir, the only source of surface water currently available for domestic use in Beijing, China. Local farmers’ livelihood strategies can be grouped into three types: farming, local off-farm, and labor-migrant. Farming households have the lowest livelihood capitals, other than natural capital, compared with labor-migrant households and off-farm households, the latter having better livelihood capital status. Geographical location, natural capital, household structure, labor quality, and ecological policies are the main factors affecting farmers’ choice of livelihood strategy. Local off-farm households have a significantly lower dependency on firewood, land resources, and investment than that of farming and labor-migrant households, and have the highest reliance on fossil fuel. This household classification can help us understand the livelihood characteristics, impact factors, and consequences of different types of household strategies, which also suggest tailored policy and management options to promote sustainable livelihoods based on different household types.