bluuebunny/crossref_metadata_2025 huggingface dataset:
Community College Student Retention and Completion based on Financial Expenditures and Hispanic-Serving Status
Authors:   , Da Silva Jose E.
Published: February 2025

Despite declining community college funding being allocated increasingly on the basis of student success, U.S. community college student retention and completion rates over the past decade have either remained steady or decreased, especially for Latino students. Using descriptive statistics and multiple regression models with secondary data procured from the Integrated Postsecondary Education Data System (IPEDS), I analyzed student success rates—full time student retention and completion rates—based on community college financial allocations and Hispanic-serving institution (HSI) status. To equitably analyze community colleges in the sample (n = 909), I separated them into four groups based on institutional size as defined by the Carnegie Classification. Descriptive results indicated that instructional divisions spent an average of 43% of the college's total allocated budget—often more than three times the allocated budget of any other division. Regression results indicated that instructional expenditures had the most consistent impact on student success regardless of college size and that scholarship expenditures and academic support expenditures generally had a negative impact on student retention and completion rates. Regarding Latino student success in particular, findings indicated that the manner in which colleges allocated their funds impacted only small and medium-sized community colleges. Of the nine different types of institutional expenditures, only student services expenditures and public services expenditures had a statistically significant impact on Latino student success. Additionally regression analysis indicated that community college HSI status did not have a large impact on overall full-time student retention and completion rates but did have a significant impact on full-time Hispanic student retention and completion rates for all institution sizes. Findings of this study confirmed that HSI status does impact Latino student success in public community colleges. This finding is consistent with prior studies on the positive impact of instructional expenditures on student success rates. Further research on the specific elements within these expenditure areas is needed to capture how or why they are having this impact on student success. Current and prospective Latino students and their parents seeking to identify higher education institutions conducive to students' academic success should be aware of such findings as they conduct the college search process.
Recidivism among Determinately Sentenced Juvenile Homicide Offenders in Texas
Authors:   , Vaughn Sydney J.
Published: February 2025

Juvenile homicide offenders pose a significant risk to society considering the severity of the crime, yet this population of delinquents receives little attention in terms of recidivism research. This study examined the recidivism outcomes of a group of 256 determinately sentenced homicide offenders in Texas. Each of these juveniles had be confined to and subsequently release from the Texas Youth Commission, and were followed for three years following release. The aim of this research study was to distinguish recidivists from non-recidivists across demographic, delinquent history, and risk factor measures. These same measures were then used to predict recidivism among the entire sample. Overall, the measures of race, gender, and previous delinquent adjudications emerged significant. First, Black youth were significantly more likely to recidivate than both Hispanic and White youth. Additionally, recidivism among males was significantly greater than non-recidivism among males. In contrast, there were fewer females in recidivist group than the non-recidivist group. Finally, youth with a greater number of previous delinquent adjudications were significantly more likely to recidivate, and the risk of recidivism increased as the number of previous adjudications increased. These findings are consistent with previous literature and indicate that these factors are prevalent in analyzing the recidivist behavior of determinately sentenced juvenile homicide offenders.
Sexual Identity and Social Anxiety in Emerging Adulthood
Authors:   , Akibar Alvin
Published: February 2025

Elevated social anxiety (SA) is linked to issues with emotional distress, substance use, and social anxiety disorder (SAD). Notwithstanding concerns of how sexuality has been defined in the extant literature, emerging evidence suggests that the prevalence of SA and related challenges may be disproportionately present among sexual minorities, including lesbians, gay men, and bisexuals (LGBs). This trend may be especially relevant within the developmental context of emerging adulthood, an important period for development of sexual identity, and a time when individuals are already predisposed to heightened feelings of SA. The present study examined the relationship between sexual orientation (measured using sexual identity, sexual attraction, and past romantic and sexual behavior) and social anxiety (related to social interaction and social performance) among emerging adults. minority sexual identities [Welch's F(5,48.08) = 5.56, p = .002, ηp2 = .02.], same-sex attraction [Welch's F(4,108.06) = 11.27, p < .001, ηp2 = .04], and same-sex romantic [Welch's F(5,85.91) = 6.88, p < .001, ηp2 = .03] and sexual experiences[F(5,61.95) = 8.88, p < .001, ηp2 = .04], particularly among those who indicated attraction to multiple sexes. Findings support research that indicates that sexual minority adults experience higher levels of SA than majority (i.e., heterosexual, opposite-sex oriented) adults, and that assessment of sexuality may reflect number of sexual minorities identified. Future directions including intersections of race/ethnicity and gender are discussed.
Application of High Entropy Alloys in Stent Implants
Authors:   , Alagarsamy Karthik
Published: February 2025

High entropy alloys (HEAs) are alloys with five or more principal elements. Due to these distinct concept of alloying, the HEA exhibits unique and superior properties. The outstanding properties of HEA includes higher strength/hardness, superior wear resistance, high temperature stability, higher fatigue life, good corrosion and oxidation resistance. Such characteristics of HEA has been significant interest leading to researches on these emerging field. Even though many works are done to understand the characteristic of these HEAs, very few works are made on how the HEAs can be applied for commercial uses. This work discusses the application of High entropy alloys in biomedical applications. The coronary heart disease, the leading cause of death in the United States kills more than 350,000 persons/year and it costs $108.9 billion for the nation each year in spite of significant advancements in medical care and public awareness. A cardiovascular disease affects heart or blood vessels (arteries, veins and capillaries) or both by blocking the blood flow. As a surgical interventions, stent implants are deployed to cure or ameliorate the disease. However, the high failure rate of stents has lead researchers to give special attention towards analyzing stent structure, materials and characteristics. Many works related to alternate material and/or design are carried out in recent time. This paper discusses the feasibility of CoCrFeNiMn and Al0.1CoCrFeNi HEAs in stent implant application. This work is based on the speculation that CoCrFeNiMn and Al0.1CoCrFeNi HEAs are biocompatible material. These HEAs are characterized to determine the microstructure and mechanical properties. Computational modeling and analysis were carried out on stent implant by applying CoCrFeNiMn and Al0.1CoCrFeNi HEAs as material to understand the structural behavior.
Reinforcing Variability Produces Stereotypic Behavior
Authors:   , Kieta Andrew R.
Published: February 2025

Behaving in novel ways is essential to the development of the types of complex performances described by the term creativity, problem solving, and perseverance. Some research suggests that response variability is an operant and a critical component of novel behavior. However, other account of novel behavior may be more parsimonious. Topographical variability has rarely been examined, nor has operant variability with organisms with baselines featuring stereotypic responding. This study examined the effects of a variability-specifying contingency on the cumulative novel responses of undergraduate students. Using the PORTL apparatus, participants interacted with a ball with a single hand. When the variability-specifying contingency was in effect, novel topographies were reinforced. When a reinforce every response condition was implemented, the participants did not emit any novel responses. When variability-specifying contingencies were in effect, novel responses were rarely followed by subsequent novel responses. They were mostly followed by repeated emission of the same topography, or by other previously emitted topographies. Novel responding did not persist long, although the variability-specifying contingency remained in effect and the potential for novel responding was great. The variability-specifying contingency often resulted in stereotypic response chains. Each of these findings call into the question the assertion that variability is an operant and suggests other possible explanations for the observed novelty.
Integrative Technology-Enhanced Physical Education: An Exploratory Study with Elementary School Students
Authors:   , Barbee Stephanie S.
Published: February 2025

Wearable technology has made a positive impact in the consumer industry with its focus on adult fitness. Devices and applications are pervasive, inexpensive and are in high demand. Our nation struggles with obesity and health concerns related to poor fitness. However, the research on such technology has been more focused on adults. Therefore, the need to investigate wearable technology for fitness improvement with children is essential. Children lead increasingly sedentary lifestyles through TV watching, technology-use and a reduction in physical activities. Further, our society is exposed to quick food loaded with calories. These factors contribute to the growing epidemic of childhood obesity. The need to educate students early, on their ability to monitor their fitness, is the focus of this research. This dissertation investigated the impact of an integrated technology-enhanced physical education model with 127 fifth grade students over an 11-week period. A detailed analysis, looking at theoretical perspectives across multiple data collections was conducted. This study answered the questions, 1. To what extent can students improve their performance with technology-enhanced physical education? 2. To what extent can students learn to self-monitor their performance levels? How do affective components impact teaching and learning with a technology-enhanced physical education model? Results showed that technology-enhanced physical education does improve performance measures, does improve students' ability to self-regulate and positively impacts student and teachers' affective states. However long term results were inconclusive, stimulating multiple, potential opportunities for continued research.
The Effects of Defensiveness and Social Desirability on the Reporting of Personality Traits
Authors:   , Williams Margot M.
Published: February 2025

Psychological assessment relies on accurate and forthright reporting to determine valid clinical presentations. However, it has long been recognized that examinees may be motivated to present a "better picture" through Positive Impression Management (PIM). Within the PIM domain, two distinct motivations (i.e., defensiveness and social desirability) emerge that have not been clearly differentiated in empirical literature. This thesis addressed the research gap for detecting PIM distortion of personality pathology, utilizing the Personality Inventory for DSM-5 (PID-5). In this investigation, 106 psychiatric inpatients were recruited from the adult Co-Occurring Disorders and Trauma Programs at University Behavioral Health. Using a mixed within- and between-subjects design, participants engaged in simulation via scenarios to be considered for a highly valued rehabilitation program (defensiveness) or employment (social desirability). As expected, inpatients showed elevated levels of problematic personality traits when reporting genuinely, but suppressed them under PIM conditions. These findings highlight that the PID-5, like all multiscale inventories, is highly vulnerable to intentional PIM distortion. Interestingly, respondents in the social desirability condition generally engaged in more total denial than those in the defensiveness condition. Empirically- and theoretically-based validity scales were developed to identify simulators and differentiate between conditions. Besides PIM, higher levels of experienced stigma were associated with more personality pathology, particularly the domain of Detachment. In addition, ancillary analyses showed strong convergence of the PID-5 with its hierarchical trait model to the DSM-IV categorical model. Continued research to detect PIM distortion, and more importantly to differentiate between PIM motivations, is essential for accurate clinical assessment of personality disorder traits and effective treatment planning.
"Off Main Street": Stories
Authors:   , Yanowski Amanda
Published: February 2025

"Off Main Street" is a collection of short stories concerned, primarily, with the expression of womanhood in the American Midwest.
A Content Analysis of Medical School Problem-Based Learning Cases
Authors:   , Kinkade Scott
Published: February 2025

Problem-based learning (PBL) was developed for use in medical education to incorporate more active, learner-centered instruction. Central to problem-based learning is the problem, which in medical education is usually case a case presentation, revealed in stages to allow learners to form and research learning objectives. The purpose of this study was to identify themes present across the PBL cases, including the patient-centeredness of the cases. Content analysis was used to examine 62 PBL cases that comprised the first and second years' core curriculum at a public medical school. The cases included a patient population similar to the local population, but care was more hospital-centric than would be expected from the actual patterns of medical utilization in the United States. Analyzing along two axes of patient-centeredness, the PBL cases demonstrated a good understanding of the patient (knowing the patient), but other qualities such as shared decision making was not as exemplified. Medical educators can use the results to understand elements that contribute to patient-centeredness and apply the analysis framework to evaluate future cases.
Practical Evaluation of a Software Defined Cellular Network
Authors:   , Agbogidi Oghenetega
Published: February 2025

This thesis proposes a design of a rapidly deployable cellular network prototype that provides voice and data communications and it is interoperable with legacy devices and the existing network infrastructure. The prototype is based on software defined radio and makes use of IEEE 802.11 unlicensed wireless radio frequency (RF) band for backhaul link and an open source GSM implementation software. The prototype is also evaluated in environments where there is limited control of the radio frequency landscape, and using Voice Over Internet Protocol (VoIP) performance metrics to measure the quality of service. It is observed that in environments where the IEEE 802.11 band is not heavily utilized, a large number of calls are supported with good quality of service. However, when this band is heavily utilized only a few calls can be supported as the quality of service rapidly degrades with increasing number of calls, which is due to interference. It is concluded that in order to achieve tolerable voice quality, unused licensed spectrum is needed for backhaul communication between base stations.
Sustainable Ecofriendly Insulation Foams for Disaster Relief Housing
Authors:   , Chitela Yuvaraj Reddy
Published: February 2025

Natural disasters are affecting a significant number of people around the world. Sheltering is the first step in post-disaster activities towards the normalization of the affected people's lives. Temporary housing is being used in these cases until the construction of permanent houses are done. Disposal of temporary housing after use is leading to a significant environmental impact because most of them are filled with thermally insulative polymer foams that do not degrade in a short period. To reduce these problems this work proposes to use foams made with compostable thermoplastic polylactic acid (PLA) and degradable kenaf core as filler materials; these foams are made using CO2 as blowing agent for insulation purposes. Foams with PLA and 5%, 10% and 15% kenaf core were tested. Different properties and their relations were examined using differential scanning calorimetry (DSC), thermal conductivity, mechanical properties, scanning electron microscopy (SEM), x-ray μ-computed tomography (μ-CT) and building energy simulations were done using Energy Plus by NREL. The results show that mechanical properties are reduced with the introduction of kenaf core reinforcement while thermal conductivity display a noticeable improvement.
Automated GUI Tests Generation for Android Apps Using Q-learning
Authors:   , Koppula Sreedevi
Published: February 2025

Mobile applications are growing in popularity and pose new problems in the area of software testing. In particular, mobile applications heavily depend upon user interactions and a dynamically changing environment of system events. In this thesis, we focus on user-driven events and use Q-learning, a reinforcement machine learning algorithm, to generate tests for Android applications under test (AUT). We implement a framework that automates the generation of GUI test cases by using our Q-learning approach and compare it to a uniform random (UR) implementation. A novel feature of our approach is that we generate user-driven event sequences through the GUI, without the source code or the model of the AUT. Hence, considerable amount of cost and time are saved by avoiding the need for model generation for generating the tests. Our results show that the systematic path exploration used by Q-learning results in higher average code coverage in comparison to the uniform random approach.
Probabilistic Analysis of Contracting Ebola Virus Using Contextual Intelligence
Authors:   , Gopalakrishnan Arjun
Published: February 2025

The outbreak of the Ebola virus was declared a Public Health Emergency of International Concern by the World Health Organisation (WHO). Due to the complex nature of the outbreak, the Centers for Disease Control and Prevention (CDC) had created interim guidance for monitoring people potentially exposed to Ebola and for evaluating their intended travel and restricting the movements of carriers when needed. Tools to evaluate the risk of individuals and groups of individuals contracting the disease could mitigate the growing anxiety and fear. The goal is to understand and analyze the nature of risk an individual would face when he/she comes in contact with a carrier. This thesis presents a tool that makes use of contextual data intelligence to predict the risk factor of individuals who come in contact with the carrier.
Extending the Apprenticeship through Informal Learning on Facebook: An Interpretative Phenomenological Analysis of the Lived Experiences of Music Faculty
Authors:   , Meredith Tamara R.
Published: February 2025

Facebook studio groups/pages are commonly used by applied music faculty to communicate with current students, recruit new students, share students' activities, and promote faculty members' professional performances and academic endeavors. However, the blurred lines between academic, professional performance, and social activities in the field have led to a wide variety of approaches to Facebook use by music faculty. This dissertation documents the first generation of music faculty social media users and investigates the beliefs, intent, and lived experiences of music faculty who use Facebook studio groups/pages to communicate with their students. Four music faculty were interviewed and a semester's Facebook studio group/page data collected for each faculty member. Interviews and Facebook data were analyzed using Interpretative phenomenological analysis (IPA) to identify emergent, and ultimately super-ordinate, themes from the data. The three super-ordinate themes that emerged were: Impact of Social Media on Studio Teaching and Learning, Learning through Enculturation, and Faculty Lived Experiences with Facebook Studio Groups/Pages. Findings of the study included: faculty concerns about personal and professional risk; the observation that teaching and learning are occurring through these Facebook studio groups/pages by way of the process of enculturation, but without evidence of a Virtual Community of Practice; and, a multitude of group/page management practices developed in isolation that suggest a need for discussion/debate and training in the field to determine best practices for using Facebook studio groups/pages as an extension of the physical studio. Recommendations include training for music faculty that situates Facebook studio groups/pages within the enculturation process of students pursuing careers in music, music department development of guidelines for Facebook group/page creation and management based upon their institutions' rules and oversight procedures, and the sharing of exemplar Facebook studio groups/pages by professional music education organizations to encourage discussion of best practices for teaching and learning in informal environments.
Adequacy and Equity: How the Texas Supreme Court's Perceptions Have Changed Over the Past 50 Years
Authors:   , Ford Daniel William
Published: February 2025

The purpose of this study identifies state court cases involving public school finance specifically related to adequacy and equity in funding. Results address how state court cases have challenged the constitutionality of school finance in the United States, including Texas, over the last 50 years. The study further shows how the decisions from previous cases have influenced the Supreme Court of Texas decision in the Texas Taxpayer & Student Fairness litigation.
Elucidation of Photoinduced Energy and Electron Transfer Mechanisms in Multimodular Artificial Photosynthetic Systems
Authors:   , Lim Gary Lloyd
Published: February 2025

Multimodular designs of electron donor-acceptor systems are the ultimate strategy in fabricating antenna-reaction center mimics for artificial photosynthetic applications. The studied photosystems clearly demonstrated efficient energy transfer from the antenna system to the primary electron donor, and charge stabilization of the radical ion pair achieved with the utilization of secondary electron donors that permits either electron migration or hole transfer. Moreover, the molecular arrangement of the photoactive components also influences the route of energy and electron transfer as observed from the aluminum(III) porphyrin-based photosystems. Furthermore, modulation of the photophysical and electronic properties of these photoactive units were illustrated from the thio-aryl substitution of subphthalocyanines yielding red-shifted Q bands of the said chromophore; hence, regulating the rate of charge separation and recombination in the subphthalocyanine-fullerene conjugates. These multicomponent photosystems has the potential to absorb the entire UV-visible-NIR spectrum of the light energy allowing maximum light-harvesting capability. Furthermore, it permits charge stabilization of the radical ion pair enabling the utilization of the transferred electron/s to be used by water oxidizing and proton reducing catalysts in full-scale artificial photosynthetic apparatuses.
Effects of Student-Created Question Process on Learning Biomedical Statistics in a Specialized Master's in Medical Sciences
Authors:   , Bashet AbuZafar M.
Published: February 2025

This study explored the effectiveness of a student question creation process engaging students actively in self, peer, and instructor interaction in development of affective, cognitive, and meta-cognitive skills. Employing a mixed-methods sequential explanatory design assigning both treatment and control activities sequentially in an alternating pattern over a six week period, students' performance on exams as well as their perceptions of various aspects of the student question creation process were used to evaluate the effectiveness of student-created questions (SCQs) activities as a cognitive strategy and to identify factors contributing to the effectiveness of question creation activities on students' learning. Subjects of this study were high performing and highly motivated graduate students in an 8-week online biomedical statistics course, part of a specialized master's program designed for medical school preparation. Survey findings and focus groups strongly supported the student question creation process as a facilitator of higher order thinking. However, the relatively short study duration, comparison of student question creation with another competing method for facilitating learning (discussion board) and not a pure control group, and availability of a common study guide course with student-created questions on all course topics may have muted assessment of the full impact of the strategy on learning. Although practically difficult in an education environment, further research to assess fully the impact of the student question creation strategy is desirable especially if these confounding factors can be greatly minimized, if not eliminated.
Spectral Evidence
Authors:   , Edwards Trista
Published: February 2025

Spectral Evidence is a collection of poems that instigates a variety of omens, signs, divinations, and folktales to explore the concept of wish fulfillment. They arise in obedience to the compulsion to repeat past dramas brought on by failed love, the nostalgia of childhood, the damning legacy of language, the restriction of gender roles, death, etc. In order to quell these anxieties, the speaker looks beyond the self to both history and mythology, often invented mythologies as an attempt to control or recast the story-to give shape to the obscurities of life by creating a system of belief in order to forge meaning or confuse oneself into believing. In many ways this collection is all about belief or in wanting to believe. Through language, God is written into existence. God is the name of the blanket we put over the mystery to give it shape. Here, in this collection, God is an ant's egg. a cherry pit, a colony of white moths, a severed hand, the color red, a little bird. This collection explores these vehicles of meaning, the words that provide the shell of meaning, and the power of invention in hopes to gain control over what is deemed uncontrollable. While the speaker may be casting omens as "pre-ordained" entities outside of her power, it is her convictions in these signs that her own psychological and associative link between their meaning and their appearance that she conjures and creates because the existing systems of language, religion, and belief do not serve her. This creation is what is powerful. It is healing. It is birth. It is not involuntary wish fulfillment. It is the deliberative satisfaction of desire-on of the most insurrectionary acts a woman can execute.
Factors Affecting Faculty Acceptance and Use of Institutional Repositories in Thailand
Authors:   , Ammarukleart Sujira
Published: February 2025

Institutional repositories have been introduced as an innovative and alternative technology for scholarly communication and have received considerable attention from scholars across disciplines and around the globe. While some universities in Thailand have developed and implemented institutional repositories for nearly a decade, knowledge of the acceptance and use of institutional repositories on the individual level in the country remains limited. As an insufficient knowledge of technology acceptance and adoption at the individual level is considered partially responsible for the underutilization of innovation or of information system implementation, this study seeks to uncover knowledge regarding the level of institutional repository acceptance and use. This study applied the unified theory of acceptance and use of technology (UTAUT) model and the model of faculty members' self-archiving behavior to investigate factors affecting faculty acceptance and use of university-based institutional repositories. The study employed a mixed methods approach involving a survey followed by semi-structured, one-to-one interview. This study confirms that the success of university-based institutional repositories depends not on a single factor but on multiple factors. The results of the study show that performance expectancy, social influence, and resistance to change were direct determinants of faculty members' intention to use institutional repositories. Additionally, behavioral intention and altruism were found to be the main determinants of actual usage behavior. The findings of this study imply that education in and promotion of open access and institutional repositories are essential and can play an important role in the adoption of institutional repositories. Finally, this study suggests that sustained dialogue and collaborative efforts among faculty members (as contributors and users), libraries/librarians (as institutional repository developers and managers), and other stakeholders within communities are essential for the adoption and success of university-based institutional repositories.
Simplification and Octavation in Double Bass Performance: An Overview of Historical and Contemporary Practices
Authors:   , Shih Wen-Ling
Published: February 2025

Two important performance practices in the modern orchestral performance are discussed in this document: simplification and octavation. Due to the differing opinions and common practices which bass players have around these two performance practices, simplification and octavation have become two of the most complex issues faced by orchestral sections. The first part of the document will provide a brief history of simplification and octavation. The second part of the document will offer recommendation for double bass orchestral practice in the 21st century and examine key works of the bass repertoire in which simplification and octavation occur. The research and practice of leading pedagogues and major orchestral players and the solutions they have developed to reduce the discrepancy inherent within section playing will be discussed. This document will propose several empirical solutions to major excerpts in the bass repertoire, demonstrating how it is to achieve the most uniformed playing, and offer applicable and suggestive guidelines for contemporary orchestral double bass performers.
Reductive Functionalization of 3D Metal-Methyl Complexes and Characterization of a Novel Dinitrogen Dicopper (I) Complex
Authors:   , Fallah Hengameh
Published: February 2025

Reductive functionalization of methyl ligands by 3d metal catalysts and two possible side reactions has been studied. Selective oxidation of methane, which is the primary component of natural gas, to methanol (a more easily transportable liquid) using organometallic catalysis, has become more important due to the abundance of domestic natural gas. In this regard, reductive functionalization (RF) of methyl ligands in [M(diimine)2(CH3)(Cl)] (M: VII (d3) through CuII (d9)) complexes, has been studied computationally using density functional techniques. A SN2 mechanism for the nucleophilic attack of hydroxide on the metal-methyl bond, resulting in the formation of methanol, was studied. Similar highly exergonic pathways with very low energy SN2 barriers were observed for the proposed RF mechanism for all complexes studied. To modulate RF pathways closer to thermoneutral for catalytic purposes, a future challenge, paradoxically, requires finding a way to strengthen the metal-methyl bond. Furthermore, DFT calculations suggest that for 3d metals, ligand properties will be of greater importance than metal identity in isolating suitable catalysts for alkane hydroxylation in which reductive functionalization is used to form the C—O bond. Two possible competitive reactions for RF of metal-methyl complexes were studied to understand the factors that lower the selectivity of C—O bond forming reactions. One of them was deprotonation of the methyl group, which leads to formation of a methylene complex and water. The other side reaction was metal-methyl bond dissociation, which was assessed by calculating the bond dissociation free energies of M3d—CH3 bonds. Deprotonation was found to be competitive kinetically for most of the 1st row transition metal-methyl complexes (except for CrII, MnII and CuII), but less favorable thermodynamically as compared to reductive functionalization for all of the studied 1st row transition metal complexes. Metal-carbon bond dissociation was found to be less favorable than the RF reactions for most 3d transition metal complexes studied. The first dinitrogen dicopper (I) complex has been characterized using computational and experimental methods. Low temperature reaction of the tris(pyrazolyl)borate copper(II) hydroxide {iPr2TpCu}2(µ-OH)2 with triphenylsilane under a dinitrogen atmosphere gives the µ -N2 complex, {iPr2TpCu}2(µ -N2). X-ray crystallography reveals an only slightly activated N2 ligand (N-N: 1.111(6) Å) that bridges between two iPr2TpCuI fragments. While DFT studies of mono- and dinuclear copper dinitrogen complexes suggest a weak µ-backbonding between the d10 CuI centers and the N2 ligand, they reveal a degree of cooperativity in the dinuclear Cu-N2-Cu interaction.
A Selection of Nineteenth Century Trumpet Literature for Low F Trumpet: A Performance Edition of F.G.A. Dauverné's Variations op. 3 and Amilcare Ponchielli's Concerto per Tromba e Banda op. 123
Authors:   , Monroe Jonathan
Published: February 2025

This dissertation presents a performance guide of two solos for early valved trumpet, as well as an appraisal of their historical significance. The first of these solos is F. G. A. Dauverné's Variations pour trompette à pistons avec accompagnement de Piano-forte, op. 3 (1833). The second solo examined is Amilcare Ponchielli's Concerto per Tromba e Banda, op. 123 (1866). Although Ponchielli's work dates from only the middle of the century, by time of its composition the valved trumpet had already been developed enough to have attained true artistic value. This dissertation provides evidence concerning the evolution of nineteenth solo literature for the Romantic trumpet by means of formal analysis in regard to form, harmony, and historical performance practice.
Microstructural Evolution and Mechanical Response of Materials by Design and Modeling
Authors:   , Dutt Aniket Kumar
Published: February 2025

Mechanical properties of structural materials are highly correlated to their microstructure. The relationship between microstructure and mechanical properties can be established experimentally. The growing need for structural materials in industry promotes the study of microstructural evolution of materials by design using computational approaches. This thesis presents the microstructural evolution of two different structural materials. The first uses a genetic algorithm approach to study the microstructural evolution of a high-temperature nickel-based oxide-dispersion-strengthened (ODS) alloy. The chosen Ni-20Cr ODS system has nano Y2O3 particles for dispersion strengthening and submicron Al2O3 for composite strengthening. Synergistic effects through the interaction of small dispersoids and large reinforcements improved high-temperature strength. Optimization considered different weight factors on low temperature strength, ductility, and high temperature strength. Simulation revealed optimal size and volume fraction of dispersoids and reinforced particles. Ni-20Cr-based alloys were developed via mechanical alloying for computational optimization and validation. The Ni-20Cr-1.2Y2O3-5Al2O3 alloy exhibited significant reduction in the minimum creep rate (on the order of 10-9 s-1) at 800oC and 100 MPa. The second considers the microstructural evolution of AA 7050 alloy during friction stir welding (FSW). Modeling the FSW process includes thermal, material flow, microstructural and strength modeling. Three-dimensional material flow and heat transfer model was developed for friction stir welding process of AA 7050 alloy to predict thermal histories and extent of deformation. Peak temperature decreases with the decrease in traverse speed at constant advance per revolution, while the increase in tool rotation rate enhances peak temperature. Shear strain is higher than the longitudinal and transverse strain for lower traverse speed and tool rotation rate; whereas for higher traverse speed and tool rotation rate, shear and normal strain acquire similar values. Precipitation distribution simulation using TC-PRISMA predicts the presence of η' and η in the as-received AA 7050-T7451 alloy and mostly η in the friction stir welded AA7050 alloy, which results in the lower predicted strength of friction stir welded alloy. Further, development of modeling assists in process optimization and innovation, and enhances the progression rate. Accelerating the development process requires coupling experimental methods with predictive modeling. The overall purpose of this work was to develop an integrated computational model with predictive capabilities. In the present work, an application tool to predict thermal histories during FSW of AA7050 was developed using COMSOL software.
Investigation of a Novel Vapor Chamber for Efficient Heat Spreading and Removal for Power Electronics in Electric Vehicles
Authors:   , Patel Anand Kishorbhai
Published: February 2025

This work investigated a novel vapor chamber for efficient heat spreading and heat removal. A vapor chamber acting as a heat spreader enables for more uniform temperature distribution along the surface of the device being cooled. First, a vapor chamber was studied and compared with the traditional copper heat spreader. The thickness of vapor chamber was kept 1.35 mm which was considered to be ultra-thin vapor chamber. Then, a new geometrical model having graphite foam in vapor space was proposed where the graphite foam material was incorporated in vapor space as square cubes. The effects of incorporating graphite foam in vapor space were compared to the vapor chamber without the embedded graphite foam to investigate the heat transfer performance improvements of vapor chamber by the high thermal conductivity graphite foam. Finally, the effects of various vapor chamber thicknesses were studied through numerical simulations. It was found that thinner vapor chamber (1.35 mm thickness) had better heat transfer performance than thicker vapor chamber (5 mm thickness) because of the extreme high effective thermal conductivities of ultra-thin vapor chamber. Furthermore, the effect of graphite foam on thermal performance improvement was very minor for ultra-thin vapor chamber, but significant for thick vapor chamber. The GF could help reduce the junction temperature by 15-30% in the 5-mm thick vapor chamber. Use of GF embedded vapor chamber could achieve 250-400 Watt per Centimeter square local heat removal for power electronics. The application of this is not only limited to electronic devices but actuator and avionics cooling in aircrafts, thermal management of electronics in directed energy weapon systems, battery thermal management for electric and hybrid vehicles, smart phones cooling, thus covering a wide gamut of heat flux applications.
Recent Approaches to Real-Time Notation
Authors:   , Shafer Seth
Published: February 2025

This paper discusses several compositions that use the computer screen to present music notation to performers. Three of these compositions, Law of Fives (2015), Polytera II (2016), and Terraformation (2016–17), employ strategies that allow the notation to change during the performance of the work as the product of composer-regulated algorithmic generation and performer interaction. New methodologies, implemented using Cycling74's Max software, facilitate performance of these works by allowing effective control of generation and on-screen display of notation; these include an application called VizScore, which delivers notation and conducts through it in real-time, and a development environment for real-time notation using the Bach extensions and graphical overlays around them. These tools support a concept of cartographic composition, in which a composer maps a range of potential behaviors that are mediated by human or algorithmic systems or some combination of the two. Notational variation in performance relies on computer algorithms that can both generate novel ideas and be subject to formal plans designed by the composer. This requires a broader discussion of the underlying algorithms and control mechanisms in the context of algorithmic art in general. Terraformation, for viola and computer, uses a model of the performer's physical actions to constrain the algorithmic generation of musical material displayed in on-screen notation. The resulting action-based on-screen notation system combines common practice notation with fingerboard tablature, color gradients, and abstract graphics. This hybrid model of dynamic notation puts unconventional demands on the performer; implications of this new performance practice are addressed, including behaviors, challenges, and freedoms of real-time notation.
Results in Algebraic Determinedness and an Extension of the Baire Property
Authors:   , Caruvana Christopher
Published: February 2025

In this work, we concern ourselves with particular topics in Polish space theory. We first consider the space A(U) of complex-analytic functions on an open set U endowed with the usual topology of uniform convergence on compact subsets. With the operations of point-wise addition and point-wise multiplication, A(U) is a Polish ring. Inspired by L. Bers' algebraic characterization of the relation of conformality, we show that the topology on A(U) is the only Polish topology for which A(U) is a Polish ring for a large class of U. This class of U includes simply connected regions, simply connected regions excluding a relatively discrete set of points, and other domains of usual interest. One thing that we deduce from this is that, even though C has many different Polish field topologies, as long as it sits inside another Polish ring with enough complex-analytic functions, it must have its usual topology. In a different direction, we show that the bounded complex-analytic functions on the unit disk admits no Polish topology for which it is a Polish ring. We also study the Lie ring structure on A(U) which turns out to be a Polish Lie ring with the usual topology. In this case, we restrict our attention to those domains U that are connected. We extend a result of I. Amemiya to see that the Lie ring structure is determined by the conformal structure of U. In a similar vein to our ring considerations, we see that, again for certain domains U of usual interest, the Lie ring A(U) has a unique Polish topology for which it is a Polish Lie ring. Again, the Lie ring A(U) imposes topological restrictions on C. That is, C must have its usual topology when sitting inside any Polish Lie ring isomorphic to A(U). In the last chapter, we introduce a new ideal of subsets of Polish spaces consisting of what we call residually null sets. From this ideal, we introduce an algebra consisting of what we call R-sets which is consistently a strict extension of the algebra of Baire property sets. We show that the algebra of R-sets is closed under the Alexandrov-Suslin operation and generalize Pettis' Theorem. From this, we provide new automatic continuity results and give a generalization of a result of D. Montgomery which shows that minimal assumptions on the continuity of group operations of an abstract group G with a Polish topology imply that G is actually a Polish group. We also see that many results pertaining to the algebra of Baire property sets generalize to the context of R-sets.
Transformative Learning and Teacher Beliefs: A Comparative Study of International Teacher Experiences
Authors:   , Barnes Valerie Rose
Published: February 2025

This project aims to explore the beliefs of international teachers regarding the students with whom they work, and the change in those beliefs over time. Participant observation, interviews, and questionnaires were used as tools of collection to address the following research questions: How did teachers' beliefs about students change over time? What variables were significantly associated with the rate of change in teacher beliefs about students? What types of challenges did teaches face while living and working in Thailand? Over the course of four months, I shadowed twenty-two U.S. teachers in thirteen different locations throughout Thailand. Participants were enrolled in an international teaching program in Thailand that provided a cultural orientation and teacher training. Participants were then assigned to teaching jobs throughout the country. Qualitative and quantitative data was analyzed using SPSS and NVivo software. This project contributes to the scholarship of teaching and learning, and anthropological and education research dedicated to exploring teachers' beliefs about students. Results of the study provide vital information about what variables or experiences may influence a critical analysis of beliefs among teachers working with students who they perceive as different from themselves. Due to some of the parallels between this study population and that of teachers in public schools within the United States, findings may also be applicable to preservice teacher training contexts that consider ways to help teachers critically reflect on their beliefs and worldviews in preparation for working with students whom they may perceive as different from themselves.
The Use of Classic Musical Theatre Repertoire for Training Bel Canto Techniques in the Undergraduate Baritone Voice
Authors:   , Johnson Brock
Published: February 2025

For applied teachers of the bel canto method of singing, classical musical theatre repertoire provides an abundant resource of material for teaching the undergraduate baritone voice. Select classic musical theatre repertoire, fitting within the parameters of suitable range, tessitura, duration, and thematic material for an undergraduate baritone, will be used to demonstrate the application of bel canto techniques such as: glottal onsets, the connection between the speaking voice and singing voice, suitable vowels in building the upper range, and teaching sostenuto and legato. This dissertation serves as a guide for teaching sound vocalism through classic musical theatre repertoire.