bluuebunny/crossref_metadata_2025 huggingface dataset:
Ultra-Broadband Plasmon Resonance in Gold Nanoparticles Precipitated in ZnO-Al2O3-SiO2 Glass
Authors: Shakhgildyan Georgiy , Avakyan Leon , Atroshchenko Grigory , Vetchinnikov Maxim , Zolikova Alexandra , Ignat’eva Elena , Ziyatdinova Mariam , Subcheva Elena , Bugaev Lusegen , Sigaev Vladimir
Published: May 2024

Optical materials with a tunable localized surface plasmon resonance (LSPR) are of great interest for applications in photonics and optoelectronics. In the present study, we explored the potential of generating an LSPR band with an ultra-broad range of over 1000 nm in gold nanoparticles (NPs), precipitated through a thermal treatment in ZnO-Al2O3-SiO2 glass. Using optical absorption spectroscopy, we demonstrated that the LSPR band’s position and shape can be finely controlled by varying the thermal treatment route. Comprehensive methods including Raman spectroscopy, X-ray diffraction, and high-resolution transmission electron microscopy were used to study the glass structure, while computational approaches were used for the theoretical description of the absorption spectra. The obtained results allowed us to suggest a scenario responsible for an abnormal LSPR band broadening that includes a possible interparticle plasmonic coupling effect taking place during the liquid–liquid phase separation of the heat-treated glass. The formation of gold NPs with an ultra-broad LSPR band in glasses holds promise for sensitizing rare earth ion luminescence for new photonics devices.
Experimental Design of the Adhesion between a PEI/Glass Fiber Composite and the AA1100 Aluminum Alloy with Oxide Coating Produced via Plasma Electrolytic Oxidation (PEO)
Authors: Lucas Rafael Resende , Marques Luis Felipe Barbosa , Hein Luis Rogerio de Oliveira , Botelho Edson Cocchieri , Mota Rogério Pinto
Published: May 2024

In this study, the AA1100 aluminum alloy underwent the plasma electrolytic oxidation (PEO) process to enhance its adhesion to a thermoplastic composite of polyetherimide (PEI) reinforced with glass fiber, following ASTM D1002:10 standards. A 23 factorial design was employed, varying three parameters in the oxidation process: immersion time, applied electric potential, and electrolyte concentration (Na2B4O7). The joining of aluminum and thermoplastic composite samples was achieved through oxy-fuel welding (OFW), using oxygen and acetylene gases. For the characterization of the joined samples, a universal tensile testing machine was utilized with a displacement speed of 1.5 mm/min. The analysis of the oxide coating involved scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and Fourier transform infrared spectroscopy (FT-IR). Through variance analysis, it was determined that the statistical model encompasses approximately 80% of the variability in the adhesion process between materials. An improvement of up to 104% in adhesion between the materials was observed with the process, indicating an effective bond due to the presence of the thermoplastic matrix in the treated aluminum sample. This improvement is attributed to the morphology of the oxide coating, resembling corals, with micro-pores and recesses that facilitated mechanical anchoring.
Research Progress on Molecularly Imprinted Materials for the Screening and Identification of Organic Pollutants
Authors: Song Jialing , Lin Xuanhao , Ee Liang Ying , Li Sam F. Y.
Published: May 2024

Organic pollutants, distinguished by their persistence and bioaccumulation in the environment, pose significant ecological and health threats that surpass those of traditional pollutants. Crucial to understanding their environmental behavior, health risks, and mitigation strategies, is the screening and identification of these pollutants. This process indispensably employs functional materials, among which molecularly imprinted polymers (MIPs) prove to be particularly advantageous because of their specific recognition capabilities and extensive application range. This review presents cutting-edge techniques and strategies for the fabrication of MIPs, including surface imprinting techniques and dummy molecular strategies. It encapsulates the last five years’ advancements in MIP research within the domains of sample pretreatment, as well as optical and electrochemical sensing analysis. The objective of this discourse is to potentially foster the evolution of MIP technology and establish the groundwork for its transition from lab-scale to commercial production.
Investigating Road Ice Formation Mechanisms Using Road Weather Information System (RWIS) Observations
Authors: Jin Menglin , McBroom Douglas G.
Published: May 2024

Ice formation on roads leads to a higher incidence of accidents and increases winter de-icing/anti-icing costs. This study analyzed 3 years (2019–2021) of Road Weather Information System (RWIS) sub-hourly measurements collected by the Montana Department of Transportation (MDT) to understand the first-order factors of road ice formation and its mechanisms. First, road ice is formed only when the road pavement surface temperature is equal to or below the freezing point (i.e., 32 °F (i.e., 0 °C)), while the corresponding 2 m air temperature could be above 32 °F. Nevertheless, when the road pavement was below 32 °F ice often did not form on the roads. Therefore, one challenge is to know under what conditions road ice forms. Second, the pavement surface temperature is critical for road ice formation. The clear road (i.e., with no ice or snow) surface pavement temperature is generally warmer than the air temperature during both day and night. This feature is different from a natural land surface, where the land skin temperature is lower than the air temperature on cloud-free nights due to radiative cooling. Third, subsurface temperature, measured using a RWIS subsurface sensor below a road surface, did not vary as much as the pavement temperature and, thus, may not be a good index for road ice formation. Fourth, urban heat island effects lead to black ice formation more frequently than roads located in other regions. Fifth, evaporative cooling from the water surface near a road segment further reduces the outlying air temperature, a mechanism that increases heat loss for bridges or lake-side roads in addition to radiative cooling. Additionally, mechanical lifting via mountains and hills is also an efficient mechanism that makes the air condense and, consequently, form ice on the roads. Forecasting road ice formation is in high demand for road safety. These observed features may help to develop a road ice physical model consisting of functions of hyper-local weather conditions, local domain knowledge, the road texture, and geographical environment.
Study on the Characteristics and Mechanism of Shield Tunnel Mud Cake Disintegration in Complex Red-Bed Geology
Authors: Yan Jinshuo , Xue Xingwei , Gong Chaofan , Zhang Kexin
Published: May 2024

The complex red-bed geology is primarily composed of iron-rich sedimentary rock layers with clay minerals as a major component. The soil water content exceeds 30%, and its high viscosity and water content lead to the easy formation of mud cake on the cutterhead, endangering the safety and progress of construction, which poses a significant challenge for tunnel boring machines (TBMs). The use of dispersants to eliminate mud cake is a common method in engineering projects. This paper presents an improved disintegration experiment instrument to study the disintegration characteristics of mud cake from the red-bed geology under different dispersant solutions, proposing a dispersant formulation suitable for the red-bed geology of the Haizhu Bay Tunnel project. The results indicate that mud cake samples exhibit a moderate disintegration effect in pure water. Furthermore, it has been observed that the disintegration effect decreases as the thickness of mud cake increases. Sodium silicate solution was not suitable for treating the red-bed geological mud cake, while sodium hexametaphosphate and oxalic acid solutions had a good promoting effect on the disintegration of red-bed geological mud cake. However, there was a threshold for the dispersant concentration; exceeding this threshold actually worsened the disintegration effect. Ultimately, the engineering application of a 10% oxalic acid solution, which proved effective in disintegrating the mud cake, significantly enhanced the excavation efficiency in the Haizhu Bay Tunnel project.
An Archaeometric Study of the Iron Age Ceramics from Quinta do Almaraz Archaeologic Site (8th to 5th Centuries BC)—Colour and Mineralogical Characterization
Authors: Ferreira Luis Filipe Vieira , Olaio Ana , Pereira Manuel Francisco Costa , Machado Isabel Luisa Ferreira
Published: May 2024

The ceramic pastes of ca. 31 samples recovered from the Almaraz archaeological site, located in the south bench of Tagus River, were studied in detail using XRF, micro-Raman and GSDR spectroscopies, as well as the XRD technique. The ceramic sherds could be grouped into six categories, red slip tableware, decorated tableware, yellow slip tableware, grey tableware, common tableware, and handmade pottery. Our studies of the mineralogic composition of the sherds’ body indicate all ceramics were produced locally, using siliceous clays in most cases and calcareous clays in a few ones. Micro-Raman and ground state diffuse reflectance absorption spectroscopy provided useful information regarding the materials used to produce the coloured ceramics: hematite and brookite for the red slip and decorated ceramics, jacobsite or carbon black for the black decoration or grey ceramics. For the yellow slip tableware, a simple engobe rich in yellow clay was used. XRF spectroscopic studies provided the elemental composition of all samples, and biplots of the potassium (K) versus calcium (Ca) contents, normalized to the silicon content of each ceramic paste, clearly show Pliocene and Miocene local clays sources were used to produce most ceramics. Only one sherd can be considered a Lisbon production.
The Influence of the Banking Sector on Economic Growth and Commodity Prices: A Panel Data Analysis of Spain, France, and Romania
Authors: Hamdaoui Houssem Eddine , Cancelo Maite
Published: May 2024

This study aims to investigate the impact of the banking sector on economic growth and commodity prices. Through panel data analysis, the research explores the relationship between the banking sector and economic growth in Spain, France, and Romania from 2000 to 2020. The findings reveal a positive correlation between the strength of the banking sector and economic growth across these nations, underscoring its pivotal role in fostering economic expansion and subsequently improving commodity prices. Additionally, this study evaluates various regulatory measures crucial ensuring the banking sector’s sustainability and preventing financial crises, including credit risk management, lending policies, liquidity constraints, and international financing and investment strategies. By analyzing the interplay between regulatory measures and banking sector performance, incorporating variables such as non-performing loans, household debt, liquid liabilities, government consumption expenditure, foreign investments, and trade openness, this research provides policymakers with valuable insights to formulate effective strategies for promoting economic stability and ensuring the sustainability and growth of the banking sector.
First Lactation Milk Yield Predicted by the Heifer’s Growth Curve Derivatives
Authors: Guevara-Escobar Aurelio , Cervantes-Jiménez Mónica , Lemus-Ramírez Vicente , García-Muñiz José Guadalupe , Yabuta Osorio Adolfo Kunio
Published: May 2024

Replacement heifers are regularly weighed to assess their health. These data also predict the milk yield in their first lactation (L). The first derivative of the growth curve represents the weight change rate at a given time. It is interesting to use the higher-order derivatives of one biological process, such as growth, to predict the outcome of another process, like lactation. With 78 records of grazing heifers, machine learning was used to predict the L based on variables calculated during the rearing period, from 3 to 21 months of age, every 3 months: body weight (P), first (1D), and second derivative (2D) of an individually modeled Fourier function. Other variables were the age at effective insemination (AI) and the season of the year when the heifer was born (E). The average deviance of the fitted models represented the goodness of fit. The models were trained using 85% of the records, and the fit was evaluated using the remaining data. The deviance was lower for the models including both derivatives in comparison to the models where the derivatives were not included (p = 0.022). The best models predicted the L using data of heifers at six months of age (r2 = 0.62) and the importance of the variables in the model was 35, 28, 21, and 16% for 1D, AI, 2D, and P, respectively. By utilizing this type of model, it would be possible to select and eliminate excess heifers early on, thereby reducing the financial and environmental costs.
A Series Production Data Set for Five-Axis CNC Milling
Authors: Schmitt Anna-Maria , Engelmann Bastian
Published: May 2024

The described data set contains features from the machine control of a five-axis milling machine. The features were recorded during thirteen series productions. Each series production includes a changeover process in which the machine was set up for the production of a different product. In addition to the timestamps and the twenty recorded features derived from Numerical Control (NC) variables, the data set also contains labels for the different production phases. For this purpose, up to 23 phases were assigned, which are based on a generalized milling process. The data set consists of thirteen .csv files, each representing a series production. The data set was recorded in a production company in the contract manufacturing sector for components with real series orders in ongoing industrial production.
Unusual Presentation of Acrodermatitis Chronica Atrophicans Resulting in Delay of Diagnosis and Inappropriate Treatment in Three Cases
Authors: Gambichler Thilo , Jridi Rim , Bernd Heinz-Wolfram , von Stemm Andrea , Boms Stefanie
Published: May 2024

Acrodermatitis chronica atrophicans (ACA) is not an infrequent condition in Europe. However, the characteristic skin lesions are often confused by non-dermatologists with other conditions. We report three unusual cases in which we made a definitive diagnosis of ACA complicated by cutaneous marginal zone lymphoma, juxta-articular fibrotic nodules, or bilateral sensory polyneuropathy. In all cases, correct diagnosis and adequate treatment was delayed over a period of at least 12 months. We initiated systemic antibiotics resulting in full recovery in these patients. The present case reports underscore that ACA may be associated with unusual clinical presentation which potentially result in delay of correct diagnosis and treatment. Hence, ACA diagnosis may be considerably delayed leading to inappropriate therapy exposure, prolonged patients’ suffering, and causing unnecessary cost. Thus, physicians who are not familiar with skin conditions should seek a timely dermatologist consultation.
Case Ascertainment of Measles during a Large Outbreak—Laboratory Compared to Epidemiological Confirmation
Authors: Stein-Zamir Chen , Abramson Nitza , Sokolov Irina , Mor-Shimshi Lia , Shoob Hanna
Published: May 2024

Measles is a highly contagious viral disease, and hence, sufficient herd immunity is obligatory to prevent infection transmission. Measles is still a cause of considerable disease burden globally, mainly in children. During a national measles outbreak in Israel in 2018–2019, the peak incidence rates occurred in the Jerusalem district. Most measles cases in the Jerusalem district (75.5%, 1702) were observed in children younger than 15 years of age, 49.2% (1109) were in children under 5 years of age, and 18.9% (425) were in infants under 1 year of age. The routine measles vaccination schedule includes two doses at 1 and 6 years of age. Most cases (1828, 81.1%) were unvaccinated (zero measles vaccine doses). These cases comprised the 425 affected infants under 1 year of age, who were ineligible for vaccination, along with the 1403 children over 1 year of age, who were otherwise unvaccinated. This study aimed to describe the epidemiologic and laboratory features of this measles outbreak, and to investigate case ascertainment (laboratory confirmed compared to epidemiologically confirmed cases). The study population included 2254 measles cases notified during the period spanning June 2018 to May 2019 in the Jerusalem district (incidence rate 176 per 10,000 population). Of the 2254 cases, 716 (31.8%) were laboratory confirmed, and 1538 (68.2%) were confirmed as epidemiologically linked. Most laboratory confirmed cases (420, 58.7%) underwent real-time PCR tests. Serological tests (measles IgM and IgG) were used in 189 (26.4%) cases, and a combination of RT-PCR and serology was used in 107 (14.9%) cases. In a multivariate model analysis, the variables significantly associated (after adjustment) with higher odds for laboratory confirmation included month of disease onset (late), additional measles cases in the household (single case), place of medical treatment (hospital; either emergency department, or hospitalization) and vaccination status (at least one prior vaccine dose). The measles outbreak described demonstrates the urgency of addressing vaccination gaps with appropriate outbreak prevention programs. The road to measles elimination needs to be paved with robust public health infrastructure, excellent field epidemiology for outbreak surveillance, investigation, and control, and laboratory proficiency.
Evaluation of the Effects of Consumption of Portuguese Walnuts (Juglans regia L.) on the Risk Factors Related to Cardiovascular Diseases
Authors: Soares Ana , Costa Céu , Barbosa Benvinda , Gomes Lígia Rebelo , Neves José
Published: May 2024

(1) Background: Walnut consumption has been associated with having a positive effect on controlling and/or reducing the co-morbidities associated with cardiovascular disease (CVD). The effects of consuming walnuts of Portuguese origin on risk factors related to CVD were evaluated by measuring glucose, urea, TC, HDL-C, LDL-C, TG, AST, and ALT levels, anthropometric profiles, and blood pressure. (2) Methods: This trial study involved 24 volunteers, both female (n = 15) and male (n = 9), from Fernando Pessoa University, Porto. It consisted of a daily intake of 25 g of walnut kernels over a period of 45 days. Before and after intake, biochemical parameters, BMI and BP were measured. (3) Results: Despite the intake of nuts revealing a reduction in mean values of most of the parameters assessed, a significant drop was only observed in AST (p = 0.04).There was also a significant reduction in the mean values for Glu (p = 0.01), UR (p = 0.01) and HDL-C (p = 0.02) for women but not for men. (4) Conclusions: The dose and the period of intake were not effective in lowering the lipid profile but may have had a protective effect on liver function. The benefits were greater in women than in men.
Surgical Treatment of Lithiasis of the Main Pancreatic Duct: A Challenging Case and a Literature Review
Authors: Brebu Dan , Prodan-Bărbulescu Cătălin , Braicu Vlad , Pașca Paul , Borcean George , Florea Sabrina , Bîrlog Clarisa , Dobrescu Amadeus , Cornianu Mărioara , Lazăr Fulger , Totolici Bogdan , Duță Ciprian , Faur Flaviu Ionuț
Published: May 2024

Pancreaticolithiasis represents a rare phenomenon, being superimposed most of the time on a form of chronic pancreatitis of multifactorial etiology. Pancreaticolithiasis is a late complication of the phenomenon of chronic pancreatitis. The reverberant inflammatory process, followed by the fibrotic degeneration of the pancreatic parenchyma, and pancreatic fluid stasis at the ductal level are factors that contribute to the phenomenon of calcium precipitation. This article describes the case of a patient with a diagnosis of pancreaticolithiasis (Wirsung duct lithiasis), a phenomenon superimposed on chronic pancreatitis of ethanolic cause (Rosemont classification). It was decided to perform surgery via the classical approach with the perfection of corporeo-caudal pancreatectomy and preservation of the splenic vessels (Kimura procedure) with pancreatico-jejunal anastomosis on the Roux-en-Y loop. The aim of this study is to identify the best method of treatment for pancreaticolithiasis. To enhance the case and provide a basis for standardization, a literature review was carried out, which included a total of six articles. The results of this study highlight that, currently, the management of symptomatic pancreaticolithiasis encompasses medical therapy (enzyme replacement therapy), interventional therapy (ESWL (extracorporeal shock wave lithotripsy) ± ERCP (endoscopic retrograde cholangiopancreatography), ERCP + sphincterotomy + stent insertion, and POP (oral pancreatoscopy)), and surgical treatment. In conclusion, based on the analysis conducted in this study, the size of the calculi present determines which is the suitable therapeutic care. Unlike stones over 0.5 cm, when surgery is explicitly advised for therapeutic purposes in the absence of endoscopic techniques, stones under 0.5 cm should be treated using endoscopic procedures.
Meningococcal Disease Presenting with Acute Myopericarditis and Concurrent Acute Meningitis
Authors: Singh Amandeep
Published: May 2024

Emergency department physicians uncommonly associate myopericarditis with bacterial infection and, even more rarely, encounter myopericarditis caused by meningococcal infection. This case report describes a 38-year-old man who presented with chest pain, electrocardiographic changes, and cardiac biomarkers consistent with acute myopericarditis and rapidly developed central nervous system symptoms that were concerning for acute bacterial meningitis. The diagnosis of Neisseria meningitidis infection was confirmed by blood cultures. Once identified, the patient made a full recovery following a course of intravenous antibiotic therapy. This case underscores the difficulty of diagnosing this rare, but potentially life-threatening, condition in the emergency department.
Procedural Sedation in Emergency Department: A Narrative Review
Authors: Cappellini Iacopo , Bavestrello Piccini Gaia , Campagnola Lorenzo , Bochicchio Cristina , Carente Rebecca , Lai Franco , Magazzini Simone , Consales Guglielmo
Published: May 2024

Procedural sedation and analgesia (PSA) in the emergency department (ED) presents a crucial aspect of emergency medicine, enabling the execution of painful or distressing procedures with minimal patient discomfort. This narrative review delineates the pharmacological framework, methodologies, and clinical considerations integral to optimizing PSA, with a particular focus on pediatric and geriatric populations. Through a comprehensive review and analysis of current practices, this work evaluates the pharmacokinetics and pharmacodynamics of widely utilized sedatives and analgesics, including propofol, ketamine, dexmedetomidine, fentanyl, midazolam, etomidate, nitrous oxide, and remimazolam. Special attention is dedicated to the selection criteria based on patient-specific risk factors, procedural requirements, and the management of potential adverse effects. The manuscript also explores innovative sedation techniques and the integration of new pharmacological agents, emphasizing evidence-based approaches to enhance patient safety and outcome. The results underscore the significance of tailored sedation strategies, especially for vulnerable groups such as pediatric and geriatric patients, highlighting the need for meticulous pre-procedural assessment and monitoring to mitigate risks. The conclusions drawn advocate for a nuanced application of PSA, guided by current evidence and clinical guidelines, to improve the quality of care in emergency settings. This research reinforces the imperative for ongoing education, skill development, and the adaptation of new evidence into clinical practice to advance procedural sedation and analgesia in the ED.
Modelling Prospects of Bio-Electrochemical Immunosensing Platforms
Authors: Gandhi Mansi
Published: May 2024

Electrochemistry is a hotspot in today’s research arena. Many different domains have been extended for their role towards the Internet of Things, digital health, personalized nutrition, and/or wellness using electrochemistry. These advances have led to a substantial increase in the power and popularity of electroanalysis and its expansion into new phases and environments. The recent COVID-19 pandemic, which turned our lives upside down, has helped us to understand the need for miniaturized electrochemical diagnostic platforms. It also accelerated the role of mobile and wearable, implantable sensors as telehealth systems. The major principle behind these platforms is the role of electrochemical immunoassays, which help in overshadowing the classical gold standard methods (reverse transcriptase polymerase chain reaction) in terms of accuracy, time, manpower, and, most importantly, economics. Many research groups have endeavoured to use electrochemical and bio-electrochemical tools to overcome the limitations of classical assays (in terms of accuracy, accessibility, portability, and response time). This review mainly focuses on the electrochemical technologies used for immunosensing platforms, their fabrication requirements, mechanistic objectives, electrochemical techniques involved, and their subsequent output signal amplifications using a tagged and non-tagged system. The combination of various techniques (optical spectroscopy, Raman scattering, column chromatography, HPLC, and X-ray diffraction) has enabled the construction of high-performance electrodes. Later in the review, these combinations and their utilization will be explained in terms of their mechanistic platform along with chemical bonding and their role in signal output in the later part of article. Furthermore, the market study in terms of real prototypes will be elaborately discussed.
Adaptive PMSM Control of Ship Electric Propulsion with Energy-Saving Features
Authors: Zwierzewicz Zenon , Tarnapowicz Dariusz , Nerć Arkadiusz
Published: May 2024

Electric ship propulsion is considered one of the most promising alternatives to conventional combustion systems. Its goal is to reduce the carbon footprint and increase a ship’s maneuverability, operational safety, and reliability. The high requirements for ship propulsion make permanent magnet synchronous motors (PMSMs) an attractive solution due to their characteristics. This paper discusses the control problem of a PMSM based on the input–output feedback linearization method combined with the optimal and adaptive control techniques. The method presented here integrates the parameter tuning process with the optimal design of the baseline controller. Since the load disturbances are treated as an additional unknown parameter, there is no need to introduce an integral action to deal with the resulting steady-state error. An important feature of the designed controller is the so-called energetic optimization of the system; i.e., in addition to the aforementioned adaptive and optimal controller, it has a feature of ensuring zero reactive power consumed by the system. The performed simulations of the machine speed stabilization process confirmed the high efficiency of the proposed controller despite the assumed uncertainty of the system parameters and environmental (load) disturbances. Besides achieving high-quality control, an essential feature of this approach is the elimination of the tuning problem.
Minimisation of the Energy Expenditure of Electric Vehicles in Municipal Service Companies, Taking into Account the Uncertainty of Charging Point Operation
Authors: Izdebski Mariusz , Jacyna Marianna , Bogdański Jerzy
Published: May 2024

This article presents an original method for minimising the energy expenditure of electric vehicles used in municipal service undertakings, taking into account the uncertainty in the functioning of their charging points. The uncertainty of the charging points’ operation was presented as the probability of the occurrence of an emergency situation hindering a point’s operation, e.g., a breakdown or lack of energy supply. The problem is how to calculate the driving routes of electric vehicles so that they will arrive at charging points at times at which there is a minimal probability of breakdowns. The second aspect of this problem to be solved is that the designated routes are supposed to ensure the minimum energy expenditure that is needed for the vehicles to complete the tasks assigned. The developed method is based on two heuristic algorithms, i.e., the ant algorithm and genetic algorithms. These algorithms work in a hybrid combination, i.e., the ant algorithm generates the initial population for the genetic algorithm. An important element of this method is the decision-making model for defining the driving routes of electric vehicles with various restrictions, e.g., their battery capacity or the permissible risk of charging point breakdown along the routes of the vehicles. The criterion function of the model was defined as the minimisation of the energy expenditure needed by the vehicles to perform their transport tasks. The method was verified against real-life data, and its effectiveness was confirmed. The authors presented a method of calibrating the developed optimisation algorithms. Theoretical distributions of the probability of charging point failure were determined based on the Statistica 13 program, while a graphical implementation of the method was carried out using the PTV Visum 23 software.
Pesticide: A Contemporary Cultural Object
Authors: Fusar Poli Elena , Fontefrancesco Michele Filippo
Published: May 2024

The article provides a narrative review of the social and cultural interpretation of pesticides in contemporary society. In so doing, it highlights the main fields of exploration investigated by social scientists concerning the perception and role played by these products among farmers and consumers. Following the WHO definition, pesticides are chemical compounds used to kill pests, including insects, rodents, fungi, and unwanted plants. They are contemporary cultural artefacts that social sciences explore in synergy with other disciplines to highlight their socio-cultural connections at both local and global levels. Specifically, the use of these products is connected with power relations, which are embedded in and reflect imbalances and inequalities in access to rights and resources, as well as specific articulation of the perception of risk arising from environmental contamination in terms of individual and collective psychophysical health. Furthermore, pesticides fit into various environmental conceptions and multiple local knowledge systems, representing the intersection of different cultural heritages, worldviews, and rationales that make the tradition–modernity dichotomy complex and dynamic. In this respect, therefore, pesticides can be understood not just as mere tools for agricultural practice but as vital windows through which to investigate multiple layers of meaning to support transitions towards sustainable pest management systems, both environmentally and socio-culturally.
Preliminary Envelope for Large Transport Aircrafts Operating with Non-Primary Fuels AVGAS, MOGAS and F76-Dieso
Authors: Palencia José Luis Díaz
Published: May 2024

This study explores the operational implications and safety considerations of using non-primary fuels—AVGAS, MOGAS, and F76 Dieso—in military transport aircraft, against the backdrop of standard aviation fuels. Through an analysis of fuel properties such as vapor pressure, density, viscosity, freeze temperature, water solubility, and thermal conductivity, this work outlines the operational envelopes for the mentioned non-primary fuels, highlighting the temperature and altitude limitations inherent to their use. The evaluation underscores the necessity of relevant testing, certification, and adherence to operational guidelines and constrains to ensure aircraft safety and reliability when standard fuels are unavailable, and hence, non-primary fuels may be required in special missions under emergency. Key findings include the specific altitude and temperature limitations for AVGAS and MOGAS to prevent fuel freezing and boiling, as well as the operational challenges posed by F76 Dieso due to its higher density and viscosity. The study also addresses the importance of managing water content in the fuel system, the flammability range of the non-primary fuels, and the considerations for fuel mixing to maintain aircraft performance and safety standards. This analysis aims to enhance the understanding of non-primary fuel usage in military transport aircraft, providing insights for system design, performance assessment, and the development of operational procedures to support military aviation in diverse operational scenarios.
Searching for the Profitability of Energy Crops: An Agroecological–Economic Land Use Suitability (AE-landUSE) Model
Authors: Viccaro Mauro , Romano Severino , Rosalia Immacolata , Cozzi Mario
Published: May 2024

The current geopolitical and energy market instability calls for speeding up the EU clean energy transition to increase energy security in all the European regions and make Europe the first climate-neutral continent by 2050. Among renewable energies, modern bioenergy is a promising near-zero-emission fuel for increasing energy security in the heating, electricity and transport sectors while promoting growth and job creation, especially in rural areas. In such a context, energy crops will continue to play a key role. Since agricultural planning is a complex issue, especially when energy crops could compete with food ones, we propose an agroecological–economic land use suitability model (AE-landUSE model) to promote the sustainable use of land resources. The AE-landUSE model was developed by integrating cost–benefit analysis (CBA) and land use suitability analysis (LSA) within geographic information systems (GISs). Tested in the Basilicata region (Southern Italy), comparing two different energy crops (rapeseed and cardoon), the results show the model’s utility in identifying suitable areas for energy crops where the investments will be cost-effective. The proposed model will help decision-makers in energy-agricultural planning to increase energy security sustainably.
The Association between Antenatal Tea Drinking and Hypertensive Disorders of Pregnancy: A Systematic Review and Meta-Analysis
Authors: Arafa Ahmed , Sheerah Haytham A. , Alzaydan Omar Khaled , Sabr Yasser
Published: May 2024

Several adverse maternal outcomes have been linked to the excessive consumption of caffeine during pregnancy. Tea is an important source of caffeine. Hypertensive disorders of pregnancy (HDP) are common pregnancy complications with unfavorable maternal and fetal complications. This study aimed to investigate the relationship between antenatal tea drinking and HDP using a meta-analysis of available evidence. We systematically retrieved eligible studies before computing the pooled odds ratio (OR) and 95% confidence interval (CI) of HDP for women who reported the highest versus the lowest frequencies of antenatal tea drinking. We used the I2 statistic to measure heterogeneity across studies and the test for funnel plot asymmetry to evaluate publication bias. The results showed that the highest frequencies of antenatal tea drinking were associated with increased odds of HDP (pooled OR = 1.16, 95% CI: 1.01, 1.33). We identified no signs of heterogeneity across studies (I2 = 0.0% and p-heterogeneity = 0.498) or publication bias (z = 0.791 and p-publication bias = 0.429). When the outcome was limited to (pre-)eclampsia, the association became statistically non-significant (pooled OR = 1.28, 95% CI: 0.86, 1.89, I2 = 0.0%, and p-heterogeneity = 0.751). In conclusion, our results indicated that the highest frequency of antenatal tea drinking was positively associated with HDP. Pregnant women should be advised against excessive tea consumption. Still, future prospective cohort studies, considering the effects of different tea types and caffeine content, are needed to confirm our conclusions.
Dynamic Gastrointestinal Digestion of Bovine, Caprine and Ovine Milk Reconstituted from Commercial Whole Milk Powders
Authors: Li Siqi , Ye Aiqian , Cui Jian , Zhang Yu , Ware Lara , Miller Jody C. , Abbotts-Holmes Holly , Roy Nicole C. , Singh Harjinder , McNabb Warren
Published: May 2024

The global dairy market has been increasingly diversified with more dairy product offerings of milk products from different animal species. Meanwhile, milk powders remain the main exported dairy product format due to their ease of transportation. In this work, we studied the structural changes, protein hydrolysis and nutrient delivery during dynamic gastric digestion and small intestinal digestion of cow, goat and sheep milk reconstituted from commercial whole milk powders. The results show that the reconstituted milks digest similarly to processed fresh milk. The digestion behaviors of the three reconstituted ruminant milks are broadly similar (gastric coagulation, kinetics of gastric emptying of protein and fat and the high digestibility in the small intestine) with some differences, which are likely contributed by the processing history of the milk powders. The delivery of individual amino acids to the small intestine differed between the early and late stages of gastric digestion, which were primarily affected by the abundance of amino acids in caseins and whey proteins but also by the difference between milk types associated with their gastric coagulation behaviors. This work showed that powdered milk is similar to fresh processed milk in digestion behavior, and the inherent differences between ruminant milks can be modified by processing treatments.
OnyxTMGel or Coil versus Hydrogel as Embolic Agents in Endovascular Applications: Review of the Literature and Case Series
Authors: Perri Paolo , Sena Giuseppe , Piro Paolo , De Bartolo Tommaso , Galassi Stefania , Costa Davide , Serra Raffaele
Published: May 2024

This review focuses on the use of conventional gel or coil and “new” generation hydrogel used as an embolic agent in endovascular applications. In general, embolic agents have deep or multidistrict vascular penetration properties as they ensure complete occlusion of vessels by exploiting the patient’s coagulation system, which recognises them as substances foreign to the body, thus triggering the coagulation cascade. This is why they are widely used in the treatment of endovascular corrections (EV repair), arteriovenous malformations (AVM), endoleaks (E), visceral aneurysms or pseudo-aneurysms, and embolisation of pre-surgical or post-surgical (iatrogenic) lesions. Conventional gels such as Onyx or coils are now commercially available, both of which are frequently used in endovascular interventional procedures, as they are minimally invasive and have numerous advantages over conventional open repair (OR) surgery. Recently, these agents have been modified and optimised to develop new embolic substances in the form of hydrogels based on alginate, chitosan, fibroin and other polymers to ensure embolisation through phase transition phenomena. The main aim of this work was to expand on the data already known in the literature concerning the application of these devices in the endovascular field, focusing on the advantages, disadvantages and safety profiles of conventional and innovative embolic agents and also through some clinical cases reported. The clinical case series concerns the correction and exclusion of endoleak type I or type II appeared after an endovascular procedure of exclusion of aneurysmal abdominal aortic (EVAR) with a coil (coil penumbra released by a LANTERN microcatheter), the exclusion of renal arterial malformation (MAV) with a coil (penumbra coil released by a LANTERN microcatheter) and the correction of endoleak through the application of Onyx 18 in the arteries where sealing by the endoprosthesis was not guaranteed.
Geospatial Insights into Greece’s Desertification Vulnerability: A Composite Indicator Approach
Authors: Kalogeropoulos Kleomenis , Tsesmelis Dimitrios , Tsatsaris Andreas , Zervas Efthimios , Karavitis Christos , Vasilakou Constantia , Barouchas Pantelis
Published: May 2024

The Environmentally Sensitive Areas Index (ESAI) is a comprehensive tool for assessing the susceptibility of areas to desertification. This index analyzes various parameters that are vital for environmental health. Through this index, factors such as human activities, geology, soil quality, vegetation and climate patterns are scrutinized. The analysis assigns weights to each participating factor. Thus, the index is derived from the aggregation of four categories (vegetation, climate, soil quality and management practices), and each of them is independently assessed to understand ecological health. In this way, the level of vulnerability to desertification is effectively measured. The application of the index in Greece (for a period of 20 years, 1984–2004) showed signs of environmental degradation and identified many areas with a high risk of desertification. Notably, there was a substantial increase in cultivated land within rural areas, contributing to shifts in the environmental landscape. Furthermore, this period is distinguished as the driest in the last century, with a peak between 1988 and 1993. The consequential rise in irrigation demand, driven by the simultaneous growth of crops and the intensification of agricultural practices, underscores the intricate interplay between human activities and environmental vulnerability.
Updating Exercise Testing Strategies and Exercise Prescription Protocols
Authors: Oliveira Rafael , Brito João Paulo
Published: May 2024

Exercise testing and prescription is still a hot topic [...]
Institutional Surgical Setting and Volume Effects of Certified Arthroplasty Centers in Germany: Evaluation of the Quality of Care in a 5-Year Comparison
Authors: Osmanski-Zenk Katrin , Klinder Annett , Pingsmann Andreas , Lohmann Christoph H. , Bail Hermann Josef , Kladny Bernd , Mittelmeier Wolfram
Published: May 2024

To improve arthroplasty care quality, the EndoCert initiative focuses on structural, processual, and surgeon-related quality assurance. The aim of this study was to assess the impact of a surgeon’s case load in certified centers on quality of care, distinguished by different types of surgeons. Data from the annual reports of EndoCert certified centers for the years 2017 to 2021 were analyzed. The study revealed reduced numbers of cases, while the number of surgeons remained constant. Since 2020, the decrease in the average case load per surgeons has become more pronounced. There were also differences between senior (sECrs) and EndoCert-registered surgeons (ECrs). Before the 2020 pandemic, over half of surgeons exceeded minimum annual case requirements, while, afterwards, this number declined, especially for the ECrs. Affiliated surgeons, who are also sECrs or ECrs, performed predominantly lower numbers of arthroplasties. However, a higher percentage of affiliated surgeons in a center correlated with faster surgeries and lower mortality rates. High numbers of arthroplasties per center or surgeon were not necessarily associated with better quality indicators, especially in the knee. While the comprehensive quality standards may offset volume effects, EndoCert should reconsider minimum volume regulations based on surgeon, but also on each joint.
Hazard Flagging as a Risk Mitigation Strategy for Violence against Emergency Medical Services
Authors: Mausz Justin , Piquette Dan , Bradford Robert , Johnston Mandy , Batt Alan M. , Donnelly Elizabeth A.
Published: May 2024

Paramedics are increasingly being subjected to violence, creating the potential for significant physical and psychological harm. Where a patient has a history of violent behavior, hazard flags—applied either to the individual, their residential address, or phone number—can alert paramedics to the possibility of violence, potentially reducing the risk of injury. Leveraging a novel violence reporting process embedded in the electronic patient care record, we reviewed violence reports filed over a thirteen-month period since its inception in February 2021 to assess the effectiveness of hazard flagging as a potential risk mitigation strategy. Upon reviewing a report, paramedic supervisors can generate a hazard flag if recurrent violent behavior from the patient is anticipated. In all, 502 violence reports were filed, for which paramedic supervisors generated hazard flags in 20% of cases (n = 99). In general, cases were not flagged either because the incident occurred at a location not amenable to flagging or because the supervisors felt that a hazard flag was not warranted based on the details in the report. Hazard flagging was associated with an increased risk of violence during subsequent paramedic attendance (Odds Ratio [OR] 6.21, p < 0.001). Nevertheless, the process appears to reliably identify persons who may be violent towards paramedics.
Sexual Orientation, Health, and Well-Being in Spanish People
Authors: Matías Roberto , Matud M. Pilar
Published: May 2024

Although several studies have found disparities in health outcomes between heterosexual and lesbian, gay, and bisexual (LGB)-identifying individuals, few studies have focused on subjective well-being and protective factors for health and well-being. The purpose of this work is twofold: (1) to examine the relevance of sexual orientation to health and well-being in women and men; (2) to identify protective and risk factors for psychological distress, self-rated health, and well-being for gay men, lesbian women, bisexual women and men, and heterosexual women and men. The sample consisted of 908 women and 586 men from the general Spanish population aged 16–64, half of whom identified themselves as LGB and half as heterosexual. All were assessed using eight questionnaires and inventories. The results showed that differences varied depending on the health indicator considered. In general, bisexuals had the poorest health, with lower self-rated health and lower self-esteem. In all groups, self-esteem was a protective factor against psychological distress and was associated with better health and well-being. To a lesser extent, social support served as a protective factor against psychological distress and was associated with greater well-being in all groups. It is concluded that although sexual orientation is relevant to the health and well-being of individuals, there are differences among sexual minorities, with bisexuals having lower self-esteem than homosexuals.