bluuebunny/crossref_metadata_2025 huggingface dataset:
Characteristics of the Supersonic Combustion Coherent Jet for Electric Arc Furnace Steelmaking
Authors: Zhao Fei , Zhu Rong , Wang Wenrui
Published: October 2019

Herein, a supersonic combustion coherent jet is proposed based on current coherent jet technology to improve the impact capacity of a coherent jet and increase the stirring intensity of the electric arc furnace (EAF) bath. Further, numerical simulations and an experimental analysis are combined to study the supersonic combustion coherent jet characteristics, including the Mach number, dynamic pressure, static temperature, vorticity, and turbulence intensity, in the EAF steelmaking environment. The results show that the supersonic combustion coherent jet exhibits stable combustion in a high-temperature EAF steelmaking environment. The supersonic combustion flame generated by the supersonic shrouding fuel gas can envelop the main oxygen jet more effectively than current coherent jets. Furthermore, the velocity attenuation, vorticity, and turbulence intensity performances of the supersonic combustion coherent jet are better when compared with those of the current coherent jet. The velocity core length of the main oxygen jet for the supersonic combustion coherent jet is 30% longer than that of the current coherent jet, resulting in an improved impact capacity and stirring intensity of the molten bath.
Iterative Methods for Finding Solutions of a Class of Split Feasibility Problems over Fixed Point Sets in Hilbert Spaces
Authors: Suantai Suthep , Petrot Narin , Suwannaprapa Montira
Published: October 2019

We consider the split feasibility problem in Hilbert spaces when the hard constraint is common solutions of zeros of the sum of monotone operators and fixed point sets of a finite family of nonexpansive mappings, while the soft constraint is the inverse image of a fixed point set of a nonexpansive mapping. We introduce iterative algorithms for the weak and strong convergence theorems of the constructed sequences. Some numerical experiments of the introduced algorithm are also discussed.
Direct and Inverse Fractional Abstract Cauchy Problems
Authors: AL Horani Mohammed , Favini Angelo , Tanabe Hiroki
Published: October 2019

We are concerned with a fractional abstract Cauchy problem for possibly degenerate equations in Banach spaces. This form of degeneration may be strong and some convenient assumptions about the involved operators are required to handle the direct problem. Moreover, we succeeded in handling related inverse problems, extending the treatment given by Alfredo Lorenzi. Some basic assumptions on the involved operators are also introduced allowing application of the real interpolation theory of Lions and Peetre. Our abstract approach improves previous results given by Favini–Yagi by using more general real interpolation spaces with indices θ , p, p ∈ ( 0 , ∞ ] instead of the indices θ , ∞. As a possible application of the abstract theorems, some examples of partial differential equations are given.
Surface Treatment Technology of Metals and Alloys
Authors: Rokosz Krzysztof
Published: October 2019

In recent decades, metals and new alloys with modified surface properties have experienced steady development [...]
Reliable Nanofabrication of Single-Crystal Diamond Photonic Nanostructures for Nanoscale Sensing
Authors: Radtke Mariusz , Nelz Richard , Slablab Abdallah , Neu Elke
Published: October 2019

In this manuscript, we outline a reliable procedure to manufacture photonic nanostructures from single-crystal diamond (SCD). Photonic nanostructures, in our case SCD nanopillars on thin (<1 μ m) platforms, are highly relevant for nanoscale sensing. The presented top-down procedure includes electron beam lithography (EBL) as well as reactive ion etching (RIE). Our method introduces a novel type of inter-layer, namely silicon, that significantly enhances the adhesion of hydrogen silsesquioxane (HSQ) electron beam resist to SCD and avoids sample charging during EBL. In contrast to previously used adhesion layers, our silicon layer can be removed using a highly-selective RIE step, which is not damaging HSQ mask structures. We thus refine published nanofabrication processes to ease a higher process reliability especially in the light of the advancing commercialization of SCD sensor devices.
Characterizing the Potential of the Non-Conventional Yeast Saccharomycodes ludwigii UTAD17 in Winemaking
Authors: Esteves Marcos , Barbosa Catarina , Vasconcelos Isabel , Tavares Maria João , Mendes-Faia Arlete , Pereira Mira Nuno , Mendes-Ferreira Ana
Published: October 2019

Non-Saccharomyces yeasts have received increased attention by researchers and winemakers, due to their particular contributions to the characteristics of wine. In this group, Saccharomycodes ludwigii is one of the less studied species. In the present study, a native S. ludwigii strain, UTAD17 isolated from the Douro wine region was characterized for relevant oenological traits. The genome of UTAD17 was recently sequenced. Its potential use in winemaking was further evaluated by conducting grape-juice fermentations, either in single or in mixed-cultures, with Saccharomyces cerevisiae, following two inoculation strategies (simultaneous and sequential). In a pure culture, S. ludwigii UTAD17 was able to ferment all sugars in a reasonable time without impairing the wine quality, producing low levels of acetic acid and ethyl acetate. The overall effects of S. ludwigii UTAD17 in a mixed-culture fermentation were highly dependent on the inoculation strategy which dictated the dominance of each yeast strain. Wines whose fermentation was governed by S. ludwigii UTAD17 presented low levels of secondary aroma compounds and were chemically distinct from those fermented by S. cerevisiae. Based on these results, a future use of this non-Saccharomyces yeast either in monoculture fermentations or as a co-starter culture with S. cerevisiae for the production of wines with greater expression of the grape varietal character and with flavor diversity could be foreseen.
Bacterial and Fungal Endophytes: Tiny Giants with Immense Beneficial Potential for Plant Growth and Sustainable Agricultural Productivity
Authors: Omomowo Olawale Israel , Babalola Olubukola Oluranti
Published: October 2019

The conventional means of achieving enhanced agricultural productivity are not ecologically balanced and sustainable. The excessive use of synthetic agrochemicals, declining soil nutrients, and water-use issues, amongst others, are threats to the ecosystem. Additionally, environmental degradation and an increasing global population that will reach 9 billion by 2030 are further considerations. These issues mean a decline in the volume of food resources available to feed the world. Therefore, sustainably increasing agricultural productivity is a necessity for restoring soil fertility, feeding the populace, and improving the ecosystem. A way to achieve this is by using eco-friendly microbial inoculants. Endophytes inhabit the tissues of plants asymptomatically without causing adverse effects. Bacterial and fungal endophytes benefit plants by promoting growth, suppressing pathogens, and improving the stress tolerance and immunity of plants. Despite this vital role played by endophytes in their interactions with host plants, there is still a paucity of relevant review data. More importantly, the prospective use of endophytes as an alternative to synthetic agrochemicals to ensure agro-ecological crop productivity has not been well reviewed in the literature. Therefore, this review sought to highlight the potential use of endophytic microbial resources to achieve enhancements in agro-food system crops in a sustainable manner.
Characteristics of Carbapenem-Resistant and Colistin-Resistant Escherichia coli Co-Producing NDM-1 and MCR-1 from Pig Farms in China
Authors: Peng Zhong , Li Xiaosong , Hu Zizhe , Li Zugang , Lv Yujin , Lei Minggang , Wu Bin , Chen Huanchun , Wang Xiangru
Published: October 2019

The emergence of carbapenem-resistant and colistin-resistant Enterobacteriaceae represents a great risk for public health. In this study, the phenotypical and genetic characteristics of eight carbapenem-resistant and colistin-resistant isolates from pig farms in China were determined by the broth microdilution method and whole genome sequencing. Antimicrobial susceptibility testing showed that the eight carbapenem-resistant and colistin-resistant strains were resistant to three aminoglycosides, twelve β-lactams, one of the phenicols, one of the tetracyclines, and one of the fluoroquinolones tested, simultaneously. The prediction of acquired resistant genes using the whole genome sequences revealed the co-existence of blaNDM-1 and mcr-1 as well as the other genes that were responsible for the multidrug-resistant phenotypes. Bioinformatics analysis also showed that the carbapenem-resistant gene blaNDM-1 was located on a putative IncFII-type plasmid, which also carried the other acquired resistant genes identified, including fosA3, blaTEM-1B and rmtB, while the colistin-resistant gene mcr-1 was carried by a putative IncX4-type plasmid. Finally, we found that these resistant genes/plasmids were conjugative, and they could be co-conjugated, conferring resistance to multiple types of antibiotics, including the carbapenems and colistin, to the recipient Escherichia coli strains.
Reanalysis of Lactobacillus paracasei Lbs2 Strain and Large-Scale Comparative Genomics Places Many Strains into Their Correct Taxonomic Position
Authors: Ghosh Samrat , Sarangi Aditya Narayan , Mukherjee Mayuri , Bhowmick Swati , Tripathy Sucheta
Published: October 2019

Lactobacillus paracasei are diverse Gram-positive bacteria that are very closely related to Lactobacillus casei, belonging to the Lactobacillus casei group. Due to extreme genome similarities between L. casei and L. paracasei, many strains have been cross placed in the other group. We had earlier sequenced and analyzed the genome of Lactobacillus paracasei Lbs2, but mistakenly identified it as L. casei. We re-analyzed Lbs2 reads into a 2.5 MB genome that is 91.28% complete with 0.8% contamination, which is now suitably placed under L. paracasei based on Average Nucleotide Identity and Average Amino Acid Identity. We took 74 sequenced genomes of L. paracasei from GenBank with assembly sizes ranging from 2.3 to 3.3 MB and genome completeness between 88% and 100% for comparison. The pan-genome of 75 L. paracasei strains hold 15,945 gene families (21,5232 genes), while the core genome contained about 8.4% of the total genes (243 gene families with 18,225 genes) of pan-genome. Phylogenomic analysis based on core gene families revealed that the Lbs2 strain has a closer relationship with L. paracasei subsp. tolerans DSM20258. Finally, the in-silico analysis of the L. paracasei Lbs2 genome revealed an important pathway that could underpin the production of thiamin, which may contribute to the host energy metabolism.
Improved Access to Chiral Tetranaphthoazepinium-Based Organocatalysts Using Aqueous Ammonia as Nitrogen Source
Authors: Manaprasertsak Auraya , Tharamak Sorachat , Schedl Christina , Roller Alexander , Widhalm Michael
Published: October 2019

The class of 3,3′-diaryl substituted tetranaphthobisazepinium bromides has found wide application as highly efficient C2-symmetrical phase-transfer catalysts (PTCs, Maruoka type catalysts). Unfortunately, the synthesis requires a large number of steps and hampers the build-up of catalyst libraries which are often desired for screening experiments. Here, we present a more economic strategy using dinaphthoazepine 7 as the common key intermediate. Only at this stage various aryl substituents are introduced, and only two individual steps are required to access target structures. This protocol was applied to synthesize ten tetranaphthobisazepinium compounds 1a–1j. Their efficiency as PTCs was tested in the asymmetric substitution of tert-butyl 2-((diphenylmethylene)amino)acetate. Enantioselectivities up to 92% have been observed with new catalysts.
Fabrication of Cellulose Nanocrystal/Silver/Alginate Bionanocomposite Films with Enhanced Mechanical and Barrier Properties for Food Packaging Application
Authors: Yadav Mithilesh , Liu Yu-Kuo , Chiu Fang-Chyou
Published: October 2019

Eco-friendly cellulose nanocrystal/silver/alginate (CNC/Ag/Alg) bionanocomposite films were successfully prepared by blending of CNC with Ag/Alg solution. The CNC was fabricated from cellulose microcrystal (CMC) by acid hydrolysis method. The Ag nanoparticles (AgNPs) were generated by using Alg as a reducing agent through hydrothermal process. AgNPs-included composite films showed characteristic plasmonic effect of the AgNPs with the maximum absorption at 491 nm and they also showed high ultraviolet (UV) barrier properties. The CNC/Ag/Alg composite films were analyzed by using scanning electron microscopy, transmission electron microscopy, optical microscopy, Fourier transform infrared spectroscopy, and X-ray diffraction technique. Depending on the type of nanofillers, tensile strength of the composite films increased by 39–57% and water vapor permeation decreased by 17–36% compared with those of the neat Alg films. The Ag/Alg and CNC/Ag/Alg films showed brown color as detected from the increase of both ‘b’ and ‘a’ parameters by colorimeter. The UV and water barrier properties of Alg based composite films were found higher than the Alg films. The obtained results suggested that the prepared composite films can be used in food packaging applications.
Ubiquinol Supplementation Alters Exercise Induced Fatigue by Increasing Lipid Utilization in Mice
Authors: Chen Huan-Chieh , Huang Chi-Chang , Lin Tien-Jen , Hsu Mei-Chich , Hsu Yi-Ju
Published: October 2019

Ubiquinol (QH), a reduced form of coenzyme Q10, is a lipid antioxidant that is hydro-soluble and is commonly formulated in commercial supplements. Ubiquinol has been increasingly reported to exert antioxidant functions, in addition to its role in the cell energy-producing system of mitochondria and adenosine triphosphate (ATP) production. The aim of this study was to assess the potential beneficial effects of QH on anti-fatigue and ergogenic functions following physiological challenge. Forty 8-week-old male Institute of Cancer Research (ICR) mice were divided into four groups (n = 10 for each group): Group 1 (vehicle control or oil only); Group 2 (1X QH dose or 102.5 mg/kg); Group 3 (2X QH dose or 205 mg/kg); Group 4 (6X QH dose or 615 mg/kg). Anti-fatigue activity and exercise performance were studied using the forelimb grip strength experiment and exhaustive weight-loaded swimming time, and levels of serum lactate, ammonia, glucose, BUN (blood urea nitrogen), creatine kinase (CK), and free fatty acids (FFA) after an acute exercise challenge. The forelimb grip strength and exhaustive weight-loaded swimming time of the QH-6X group were significantly higher than those of the other groups. QH supplementation dose-dependently reduced serum lactate, ammonia, and CK levels and increased the FFA concentration after acute exercise. In addition, QH increased the liver and muscle glycogen content, an important energy source during exercise. Therefore, the results suggest that QH formulation is a safe dietary supplement for amelioration of fatigue and for promoting exercise performance.
Multifactorial Etiology of Anemia in Celiac Disease and Effect of Gluten-Free Diet: A Comprehensive Review
Authors: Martín-Masot Rafael , Nestares Maria Teresa , Diaz-Castro Javier , López-Aliaga Inmaculada , Alférez Maria Jose Muñoz , Moreno-Fernandez Jorge , Maldonado José
Published: October 2019

Celiac disease (CD) is a multisystemic disorder with different clinical expressions, from malabsorption with diarrhea, anemia, and nutritional compromise to extraintestinal manifestations. Anemia might be the only clinical expression of the disease, and iron deficiency anemia is considered one of the most frequent extraintestinal clinical manifestations of CD. Therefore, CD should be suspected in the presence of anemia without a known etiology. Assessment of tissue anti-transglutaminase and anti-endomysial antibodies are indicated in these cases and, if positive, digestive endoscopy and intestinal biopsy should be performed. Anemia in CD has a multifactorial pathogenesis and, although it is frequently a consequence of iron deficiency, it can be caused by deficiencies of folate or vitamin B12, or by blood loss or by its association with inflammatory bowel disease (IBD) or other associated diseases. The association between CD and IBD should be considered during anemia treatment in patients with IBD, because the similarity of symptoms could delay the diagnosis. Vitamin B12 deficiency is common in CD and may be responsible for anemia and peripheral myeloneuropathy. Folate deficiency is a well-known cause of anemia in adults, but there is little information in children with CD; it is still unknown if anemia is a symptom of the most typical CD in adult patients either by predisposition due to the fact of age or because biochemical and clinical manifestations take longer to appear.
Metabolic Cytokines at Fasting and During Macronutrient Challenges: Influence of Obesity, Female Androgen Excess and Sex
Authors: Martínez-García M. Ángeles , Moncayo Samuel , Insenser María , Álvarez-Blasco Francisco , Luque-Ramírez Manuel , Escobar-Morreale Héctor F.
Published: October 2019

Scope: Cytokines have pleiotropic functions within the organism and their levels may be influenced by obesity, visceral adiposity and sex hormones. Diet composition may also affect their systemic concentrations during fasting and in the postprandial period. Hence, we studied the influence of sex steroids and obesity on the circulating levels of a panel of metabolic cytokines in the fasting state and after single macronutrient challenges. Methods: On alternate days we submitted 17 women with polycystic ovary syndrome (PCOS) (9 non-obese, 8 obese), 17 non-hyperandrogenic control women (9 non-obese, 8 obese) and 19 control men (10 non-obese, 9 obese) to isocaloric oral glucose, lipid and protein loads. Serum levels of omentin-1, vaspin, lipocalin-2, adipsin, PAI-1, chemerin, FGF-21 and FGF-23 were determined by Luminex multiplex technology. Results: During fasting, obese patients presented higher levels of PAI-1, chemerin and adipsin but decreased FGF-23 and omentin-1 compared with non-obese subjects. Vaspin showed sexual dimorphism with lower levels in men than women with PCOS and female controls. Following macronutrient ingestion, most metabolic cytokines presented a similar physiological response consisting of a decrease in circulating concentrations, which was inversely associated with the fasting levels of these molecules. Protein intake caused the major postprandial decrease whereas glucose did not significantly reduce PAI-1, FGF-23 and vaspin, and even increased FGF-21. Regardless of the macronutrient administered, vaspin levels showed a larger reduction in non-obese individuals while the decrease in PAI-1 was particularly noticeable in the obese subgroup. The postprandial reductions of omentin-1 and FGF-23 after glucose and protein loads were influenced by obesity. No major differences were found between patients with PCOS and male and female controls. Conclusions: Obesity, but not PCOS or sex, markedly influences metabolic cytokine levels at fasting and after macronutrient ingestion. The observed postprandial decrease in their circulating concentrations might represent a physiological compensatory mechanism against food-induced inflammation and oxidative stress. This mechanism is altered by obesity and is differently modulated by macronutrients, suggesting a larger contribution of glucose to stressful postprandial responses.
The Joint Role of Thyroid Function and Iodine Status on Risk of Preterm Birth and Small for Gestational Age: A Population-Based Nested Case-Control Study of Finnish Women
Authors: Purdue-Smithe Alexandra C. , Männistö Tuija , Bell Griffith A. , Mumford Sunni L. , Liu Aiyi , Kannan Kurunthachalam , Kim Un-Jung , Suvanto Eila , Surcel Heljä-Marja , Gissler Mika , Mills James L.
Published: October 2019

Normal maternal thyroid function during pregnancy is essential for fetal development and depends upon an adequate supply of iodine. Little is known about how iodine status is associated with preterm birth and small for gestational age (SGA) in mildly iodine insufficient populations. Our objective was to evaluate associations of early pregnancy serum iodine, thyroglobulin (Tg), and thyroid-stimulating hormone (TSH) with odds of preterm birth and SGA in a prospective, population-based, nested case-control study from all births in Finland (2012–2013). Cases of preterm birth (n = 208) and SGA (n = 209) were randomly chosen from among all singleton births. Controls were randomly chosen from among singleton births that were not preterm (n = 242) or SGA (n = 241) infants during the same time period. Women provided blood samples at 10–14 weeks’ gestation for serum iodide, Tg and TSH measurement. We used logistic regression to estimate odds ratios (ORs) and 95% confidence intervals (CIs) for preterm birth and SGA. Each log-unit increase in serum iodide was associated with higher odds of preterm birth (adjusted OR = 1.19, 95% CI = 1.02–1.40), but was not associated with SGA (adjusted OR = 1.01, 95% CI = 0.86–1.18). Tg was not associated with preterm birth (OR per 1 log-unit increase = 0.87, 95% CI = 0.73–1.05), but was inversely associated with SGA (OR per log-unit increase = 0.78, 95% CI = 0.65–0.94). Neither high nor low TSH (versus normal) were associated with either outcome. These findings suggest that among Finnish women, iodine status is not related to SGA, but higher serum iodide may be positively associated with preterm birth.
Coffee Ingestion Improves 5 km Cycling Performance in Men and Women by a Similar Magnitude
Authors: Clarke Neil D. , Kirwan Nicholas A. , Richardson Darren L.
Published: October 2019

Caffeine is a well-established ergogenic aid, although research to date has predominantly focused on anhydrous caffeine, and in men. The primary aim of the present study was to investigate the effect of coffee ingestion on 5 km cycling time trial performance, and to establish whether sex differences exist. A total of 38 participants (19 men and 19 women) completed a 5 km time trial following the ingestion of 0.09 g·kg-1 coffee providing 3 mg·kg-1 of caffeine (COF), a placebo (PLA), in 300 mL of water, or control (CON). Coffee ingestion significantly increased salivary caffeine levels (p < 0.001;

η
P
2

= 0.75) and, overall, resulted in improved 5 km time trial performance (p < 0.001;

η
P
2

= 0.23). Performance following COF (482 ± 51 s) was faster than PLA (491 ± 53 s; p = 0.002; d = 0.17) and CON (487 ± 52 s; p =0.002; d = 0.10) trials, with men and women both improving by approximately 9 seconds and 6 seconds following coffee ingestion compared with placebo and control, respectively. However, no differences were observed between CON and PLA (p = 0.321; d = 0.08). In conclusion, ingesting coffee providing 3 mg·kg-1 of caffeine increased salivary caffeine levels and improved 5 km cycling time trial performance in men and women by a similar magnitude.
Excessive Fructose Intake Impairs Baroreflex Sensitivity and Led to Elevated Blood Pressure in Rats
Authors: Chen Hsin-Hung , Chu Chih-Hsun , Wen Shu-Wei , Lai Chi-Cheng , Cheng Pei-Wen , Tseng Ching-Jiunn
Published: October 2019

Hypertension development with an increased intake of added sugar, especially excessive fructose intake, was shown in the National Health and Nutrition Examination Survey (NHANES) data. However, the mechanism underlying blood pressure (BP) elevation with increased fructose intake is still unclear. First, the present study showed that in rats fed 10% fructose for one week, BP and fructose/glucose levels increased in the central and peripheral nervous system. Furthermore, increased fructose intake resulted in an upregulation of fructose concentration in the cerebrospinal fluid. Second, consumption of excess fructose increased serum triglycerides. However, the inhibition of triglyceride production did not mitigate sympathetic nerve hyperactivity, but contributed to an insignificant decrease in BP. Finally, increased fructose intake reduced nitric oxide (NO) levels in the nucleus tractus solitarii (NTS) and reduced baroreflex sensitivity within a week. Collectively, the data suggested that fructose intake reduced NO levels in the NTS and caused baroreflex dysfunction, which further stimulated sympathetic nerve activity and induced the development of high BP.
Doxorubicin and Varlitinib Delivery by Functionalized Gold Nanoparticles Against Human Pancreatic Adenocarcinoma
Authors: Coelho Sílvia Castro , Reis Daniel Pires , Pereira Maria Carmo , Coelho Manuel A. N.
Published: October 2019

The aim of this study was to develop drug delivery nanosystems based on pegylated gold nanoparticles (PEGAuNPs) for a combination against pancreatic cancer cells. Doxorubicin and varlitinib, an anthracycline and a tyrosine kinase inhibitor respectively, were conjugated with gold nanoparticles. The systems were characterized, after synthesis, regarding their size, stability and morphology. An efficient conjugation of doxorubicin and varlitinib with PEGAuNPs was revealed. The cytotoxicity effect induced by the combination of the nanoconjugates was investigated in pancreatic cancer cell lines. Doxorubicin and varlitinib conjugated with PEGAuNPs revealed a combined effect to decrease the cell survival of the cancer line S2-013s, while reducing the drugs’ toxicity for the healthy pancreatic cells hTERT-HPNE. This study highlights the promising potential of PEGAuNPs for targeted delivery of therapeutic drugs into human cells, enhancing the antitumor growth-inhibition effect on cancer cells, and decreasing the toxicity against normal cells. In cancer therapy, the present approach based on PEGAuNP functionalization can be further explored to increase drug targeting efficiency and to reduce side effects.
Synthesis of a Smart Conductive Block Copolymer Responsive to Heat and Near Infrared Light
Authors: Bongiovanni Abel Silvestre , Riberi Kevin , Rivarola Claudia , Molina Maria , Barbero Cesar
Published: October 2019

A method for the synthesis of a linear block copolymer (PNIPAM-b-PANI), containing a thermoresponsive block (poly(N-isopropylacrylamide), PNIPAM) and a Near Infrared (NIR) light-absorbing block (polyaniline, PANI), is reported. The synthetic approach involves a two-step successive polymerization reaction. First, the radical polymerization of NIPAM is done using 4-aminothiophenol as a chain transfer agent for the obtention of thermosensitive block terminated with an aniline (ANI) moiety. Second, the oxidative polymerization of ANI is initiated in ANI moiety of thermosensitive block to grow the second conductive PANI block. 1H nuclear magnetic resonance (NMR) and FT-IR spectroscopy shows the characteristics peaks of both polymeric blocks revealing the successful copolymerization process. Static Light Scattering (SLS) and UV-Visible combined measurements allowed the determination of the Mw for PNIPAM-b-PANI macromolecule: 5.5 × 105 g mol−1. The resulting copolymer is soluble in water (8.3 g L−1) and in non-aqueous solvents, such as ethanol, formic acid, acetonitrile, and others. Both polymer blocks chains show the properties of the polymer chains. The block copolymer shows a lower critical solution temperature (LCST) at the same temperature (32–34 °C) than PNIPAM, while the copolymer shows pH dependent UV-vis-NIR absorption similar to PANI. The PNIPAM block suffers a coil to globule transition upon NIR light irradiation (785 nm, 100 mW), as shown by turbidimetry and Atomic Force Microscopy (AFM), due to local heating (more than 9 °C in 12 min) induced by the NIR absorption at the PANI block. Furthermore, the electrical conductivity of PNIPAM-b-PANI thin films is demonstrated (resistivity of 5.3 × 10−4 Ω−1 cm−1), indicating that the PANI block is present in its conductive form.
Effects of Bilayer Nanofibrous Scaffolds Containing Curcumin/Lithospermi Radix Extract on Wound Healing in Streptozotocin-Induced Diabetic Rats
Authors: Yang Bo-Yin , Hu Chung-Hsuan , Huang Wei-Chien , Ho Chien-Yi , Yao Chun-Hsu , Huang Chiung-Hua
Published: October 2019

Impaired growth factor production, angiogenic response, macrophage function, and collagen accumulation have been shown to delay wound healing. Delayed wound healing is a debilitating complication of diabetes that leads to significant morbidity. In this study, curcumin and Lithospermi radix (LR) extract, which are used in traditional Chinese herbal medicine, were added within nanofibrous membranes to improve wound healing in a streptozotocin (STZ)-induced diabetic rat model. Gelatin-based nanofibers, which were constructed with curcumin and LR extract at a flow rate of 0.1 mL/hour and an applied voltage of 20 kV, were electrospun onto chitosan scaffolds to produce bilayer nanofibrous scaffolds (GC/L/C). The wounds treated with GC/L/C exhibited a higher recovery rate and transforming growth factor-beta (TGF-β) expression in Western blot assays. The decreased levels of pro-inflammatory markers, interleukin-6 (IL-6) and tumor necrosis factor-α (TNF-α), provided evidence for the anti-inflammatory effects of GC/L/C treatment. Chronic wounds treated with GC/L/C achieved better performance with a 58 ± 7% increase in recovery rate on the seventh day. Based on its anti-inflammatory and wound-healing effects, the GC/L/C bilayer nanofibrous scaffolds can be potential materials for chronic wound treatment.
Effect of Dip Coating Polymer Solutions on Properties of Thermoplastic Cassava Starch
Authors: Jantanasakulwong Kittisak , Homsaard Nattagarn , Phengchan Phanurot , Rachtanapun Pornchai , Leksawasdi Noppol , Phimolsiripol Yuthana , Techapun Charin , Jantrawut Pensak
Published: October 2019

Thermoplastic starch (TPS) was prepared by melt-mixing cassava starch with glycerol. Polyethylene (PE), polyethylene-grafted-maleic anhydride (PE-MAH) and poly(lactic acid) (PLA) solutions at 2% (w/v) were used to coat TPS using the dip coating process. The tensile strength of TPS increased with the dip coating solution technique, especially for PLA coating. Swelling index, water-soluble matter and water droplet contact angle confirmed the water resistant improvement of TPS by PE-MAH and the PLA dip coating solution. Plasticizer bleeding was found in uncoated TPS after storage, but not in the coated TPS. Coating TPS with PE-MAH and PLA improved the tensile properties, water resistance and conquered plasticizer bleeding problems in TPS.
Strengthening and Toughening of Polylactide/Sisal Fiber Biocomposites via in-situ Reaction with Epoxy-Functionalized Oligomer and Poly (butylene-adipate-terephthalate)
Authors: Wu Hongwu , Hao Mingyang
Published: October 2019

With the addition of poly (butylene-adipate-terephthalate) (PBAT) and a commercial grade epoxy-functionalized oligomer Joncryl ADR@-4368 (ADR), a blend of polylactic acid (PLA) and sisal fibers (SF) were melt-prepared via in-situ reactive process to improve the toughness and interfacial bonding of polylactide/sisal fiber composites. Fourier Transform infrared spectroscopy (FTIR) analysis demonstrated chemical bonding between sisal fibers and matrix, and scanning electron microscope characterization indicated the enhancement of interfacial adhesion between PLA matrix and sisal fibers. The micro-debonding test proved that the interfacial adhesion between PLA and SF was improved because of ADR. The presence of ADR behaved like a hinge among sisal fibers and matrix via an in-situ interfacial reaction, and compatibility between PLA and PBAT was also augmented. The introduction of PBAT exerted a plasticization effect on composites. Therefore, the toughness of PLA/SF composites was significantly elevated, while the tensile strength of composites could be well preserved. The paper focused on the demonstration of interfacial interaction and structure–properties relationship of the composites.
A Quarterthiophene-Based Dye as an Efficient Interface Modifier for Hybrid Titanium Dioxide/Poly(3-hexylthiophene)(P3HT) Solar Cells
Authors: Pirashanthan Arumugam , Murugathas Thanihaichelvan , Robertson Neil , Ravirajan Punniamoorthy , Velauthapillai Dhayalan
Published: October 2019

This work focused on studying the influence of dyes, including a thiophene derivative dye with a cyanoacrylic acid group ((E)-2-cyano-3-(3′,3′′,3′′′-trihexyl-[2,2′:5′,2′′:5′′,2′′′- quaterthiophene]-5-yl) acrylicacid)(4T), on the photovoltaic performance of titanium dioxide (TiO2)/poly(3-hexyl thiophene)(P3HT) solar cells. The insertion of dye at the interface improved the efficiency regardless of the dye used. However, 4T dye significantly improved the efficiency by a factor of three when compared to the corresponding control. This improvement is mainly due to an increase in short circuit current density (JSC), which is consistent with higher hole-mobility reported in TiO2/P3HT nanocomposite with 4T dye. Optical absorption data further revealed that 4T extended the spectral response of the TiO2/P3HT nanocomposite, which could also enhance the JSC. The reduced dark current upon dye insertion ensured the carrier recombination was controlled at the interface. This, in turn, increased the open circuit voltage. An optimized hybrid TiO2/P3HT device with 4T dye as an interface modifier showed an average efficiency of over 2% under-simulated irradiation of 100 mWcm−2 (1 sun) with an Air Mass 1.5 filter.
Improving the Accuracy of Fine-Grained Population Mapping Using Population-Sensitive POIs
Authors: Zhao Yuncong , Li Qiangzi , Zhang Yuan , Du Xin
Published: October 2019

Many methods have been used to generate gridded population maps by downscaling demographic data. As one of these methods, the accuracy of the dasymetric model depends heavily on the covariates. Point-of-interest (POI) data, as important covariates, have been widely used for population estimation. However, POIs are often used indiscriminately in existing studies. A few studies further used selected categories of POIs identified based only on the nonspatial quantitative relationship between the POIs and population. In this paper, the spatial association between the POIs and population distribution was considered to identify the POIs with a strong spatial correlation with the population distribution, i.e., population-sensitive POIs. The ability of population-sensitive POIs to improve the fine-grained population mapping accuracy was explored by comparing the results of random forest dasymetric models driven by population-sensitive POIs, all POIs, and no POIs, along with the same sets of multisource remote sensing and social sensing data. The results showed that the model driven by population-sensitive POI had the highest accuracy. Population-sensitive POIs were also more effective in improving the population mapping accuracy than were POIs selected based only on their quantitative relationship with the population. The model built using population-sensitive POIs also performed better than the two popular gridded population datasets WorldPop and LandScan. The model we proposed in this study can be used to generate accurate spatial population distribution information and contributes to achieving more reliable analyses of population-related social problems.
A Multi-Scale Approach for Remote Sensing Scene Classification Based on Feature Maps Selection and Region Representation
Authors: Zhang Jun , Zhang Min , Shi Lukui , Yan Wenjie , Pan Bin
Published: October 2019

Scene classification is one of the bases for automatic remote sensing image interpretation. Recently, deep convolutional neural networks have presented promising performance in high-resolution remote sensing scene classification research. In general, most researchers directly use raw deep features extracted from the convolutional networks to classify scenes. However, this strategy only considers single scale features, which cannot describe both the local and global features of images. In fact, the dissimilarity of scene targets in the same category may result in convolutional features being unable to classify them into the same category. Besides, the similarity of the global features in different categories may also lead to failure of fully connected layer features to distinguish them. To address these issues, we propose a scene classification method based on multi-scale deep feature representation (MDFR), which mainly includes two contributions: (1) region-based features selection and representation; and (2) multi-scale features fusion. Initially, the proposed method filters the multi-scale deep features extracted from pre-trained convolutional networks. Subsequently, these features are fused via two efficient fusion methods. Our method utilizes the complementarity between local features and global features by effectively exploiting the features of different scales and discarding the redundant information in features. Experimental results on three benchmark high-resolution remote sensing image datasets indicate that the proposed method is comparable to some state-of-the-art algorithms.
Biochar Enhances Nitrous Oxide Reduction in Acidic but Not in Near-Neutral pH Soil
Authors: Pujol Pereira Engil Isadora , Léchot Jérôme , Feola Conz Rafaela , da Silva Cardoso Abmael , Six Johan
Published: October 2019

We quantified nitrous oxide (N2O) fluxes and total denitrification (N2O + N2) in an acidic (Ferralsol) and a near-neutral pH soil (Cambisol) to determine whether biochar’s alkalinization effect could be the mechanism inducing potential reductions in N2O fluxes. In Ferralsol, decreases in N2O emissions and in the N2O to N2O + N2 ratio were observed in both biochar and lime treatments. In Cambisol, neither biochar nor lime decreased N2O emissions, despite significantly increasing soil pH. The abundance and community structure of nosZ gene-bearing microorganisms indicated that gene abundances did not explain biochar effects, but a higher diversity of nosZ gene-bearing microorganisms correlated to lower total denitrification. Overall, our results suggest that biochar’s potential to decrease N2O emissions, through soil alkalinization, may be more effective in acidic soils.
Evaluation of the Criteria for Designating Maintenance Districts in Low-Rise Residential Areas: Urban Renewal Projects in Seoul
Authors: Bae Woongkyoo , Kim UnHyo , Lee Jeongwoo
Published: October 2019

Since the 1970s, the South Korean government has been redeveloping blighted residential environments and adopting large-scale redevelopment policies to solve urban housing-related problems. However, it is difficult to designate areas for redevelopment and identify areas where redevelopment is currently unfeasible. This study establishes a framework to support decision-making in a selection of housing renewal districts. The proposed Residential Environment Maintenance Index (REMI) overcomes the limitations of existing indicators, which are often biased toward physical requirements. Using this, we rationalize the designation of maintenance areas by considering both physical and social requirements and outline the renewal district designation procedure. To derive REMI, we used an analytic hierarchy process analysis and estimated the index’s reliability by clarifying the relative importance and priority of the indicators based on surveys of 300 subject matter experts. We analyzed various simulations by applying REMI at sites where maintenance is currently planned or discharged in Seoul. These reveal that the total number of urban renewal projects can be adjusted by adjusting the number of renewal district designations through the proposed REMI according to the economic situation. The results have implications for understanding REMI’s possible application and flexible management at the administrative level to pursue long-term sustainable development.
Investigating Perceptions of Land Issues in a Threatened Landscape in Northern Cambodia
Authors: Beauchamp Emilie , Clements Tom , Milner-Gulland E. J.
Published: October 2019

Land governance highly affects rural communities’ well-being in landscapes where land and its access are contested. This includes sites with high land pressures from development, but also from conservation interventions. In fact, local people’s motivations for sustainably managing their resources is highly tied to their perceptions of security, trust and participation in land management regimes. Understanding these perceptions is essential to ensure the internal legitimacy and sustainability of conservation interventions, especially in areas where development changes are fast paced. This paper presents an analysis of household perceptions of land issues in 20 villages across different conservation and development contexts in Northern Cambodia. We assess whether conservation and development interventions, as economic land concessions, influence perceptions of land issues in control and treatment sites by modelling five key perception indicators. We find that household characteristics rather than village contexts are the main factors influencing the perceptions of land issues. Interventions also affect perceptions, especially with regards to the negative effect of development pressures and population growth. While large-scale protected areas do not calm insecurity about land issues, some village-based payment for environmental services projects do. Ultimately, evidence from perception studies can help address current concerns and shape future conservation activities sustainably.
In situ Conservation Assessment of Forage and Fodder CWR in Spain Using Phytosociological Associations
Authors: Rubio Teso María Luisa , Iriondo José
Published: October 2019

Crop wild relatives (CWR) can be used to mitigate the negative effects of climate change on crops, but their genetic diversity conservation has not been properly addressed. We propose a new target unit for conservation (Asso-EcoU) based on the occurrence of phytosociological associations in different environments. This approach involves using ecogeographical information and distribution data of associations to identify an optimized set of locations for in situ genetic diversity conservation. Thirty-nine CWR species, grouped in 15 associations, generated 165 Asso-EcoUs. Using the Sites of Community Importance (SCI) of Natura 2000 in Spain, we performed three analyses: (1) gap analysis, (2) coverage of the network, and (3) complementarity analysis. Analyses were performed with both target conservation units, associations, or Asso-EcoUs. The SCI network includes 100% of the associations and 69% of the Asso-EcoUs. The coverage assessment showed that 8.8% of the network is enough to encompass all the networks’ target conservation units. Complementarity analysis showed that seven and 52 SCI areas are needed to contain at least one site of the 15 associations and the 114 Asso-EcoUs, respectively. These results highlight the value of Asso-EcoUs to potentially incorporate the genetic diversity component into conservation plans, while increasing the number of species covered.
Towards a Discourse-Based Understanding of Sustainability Education and Decision Making
Authors: Meisert Anke , Böttcher Florian
Published: October 2019

Based on the indeterminate character of the sustainability concept, a procedural and discursive understanding of sustainability decision making and corresponding approaches for education for sustainability (EFS) is proposed. A set of criteria for teaching strategies to promote sustainability decision making, taking into account the demands of deliberative democracy theory, are presented. These criteria (such as reason, complexity management, critical thinking, etc.) are used to argue for an educational approach that involves the development, justification, and weighting of arguments in combination with an instructional tool called Target-Mat. According to a consequent process orientation, structures for arguing or defining sustainability are not given as authorized standards. Suggestions from previous social discourse are only introduced as controversial pairings—for example, different definitions of sustainability. Examples of student decision-making processes are given to demonstrate the potential of the approach to encourage student reflection and cooperative negotiation that engenders a successive deepening of their argumentation.
Sustainability Assessment of Combined Cooling, Heating, and Power Systems under Carbon Emission Regulations
Authors: Chu Xiaolin , Yang Dong , Li Jia
Published: October 2019

The combined cooling, heating, and power (CCHP) system, which is a sustainable distributed energy system, has attracted increasing attention due to the associated economic, environmental, and energy benefits. Currently, the enforcement of carbon emission regulations has become an increasingly concerning issue globally. In this paper, a multi-objective optimization model is established to evaluate the CCHP system under two different carbon emission regulation policies in terms of economic benefit, environmental sustainability, and energy advantage. A nonlinear programming optimization model is formulated and solved by using the particle swarm optimization (PSO) algorithm. The results from the case studies demonstrate that when considering carbon tax regulation, the cost savings of the optimal CCHP system strategy were on average 10.0%, 9.1%, 17.0%, 22.1%, and 20.9% for the office, supermarket, hotel, school, and hospital in China, respectively, compared with the conventional energy supply system. On the other hand, when considering carbon trading regulation, the optimal CCHP system strategy can lead to a 10.0%, 8.9%, 16.8%, 21.6%, and 20.5% cost-saving for the five different building categories, respectively. Furthermore, the optimal CCHP system strategy for the five buildings, i.e., an average of 39.6% carbon dioxide emission (CDE) reduction and 26.5% primary energy consumption (PEC) saving, can be achieved under carbon emission regulations.
Forecasting Japan’s Solar Energy Consumption Using a Novel Incomplete Gamma Grey Model
Authors: Zhang Peng , Ma Xin , She Kun
Published: October 2019

Energy consumption is an essential basis for formulating energy policy and programming, especially in the transition of energy consumption structure in a country. Correct prediction of energy consumption can provide effective reference data for decision-makers and planners to achieve sustainable energy development. Grey prediction method is one of the most effective approaches to handle the problem with a small amount of historical data. However, there is still room to improve the prediction performance and enlarge the application fields of the traditional grey model. Nonlinear grey action quantity can effectively improve the performance of the grey prediction model. Therefore, this paper proposes a novel incomplete gamma grey model (IGGM) with a nonlinear grey input over time. The grey input of the IGGM model is a revised incomplete gamma function of time in which the nonlinear coefficient determines the performance of the IGGM model. The WOA algorithm is employed to seek for the optimal incomplete coefficient of the IGGM model. Then, the validations of IGGM are performed on four real-world datasets, and the results exhibit that the IGGM model has more advantages than the other state-of-the-art grey models. Finally, the IGGM model is applied to forecast Japan’s solar energy consumption in the next three years.