bluuebunny/crossref_metadata_2025 huggingface dataset:
The Source Areas and Migratory Pathways of the Fall Armyworm Spodoptera frugiperda (Smith) in Sichuan Province, China
Authors: Jiang Chunxian , Zhang Xueyan , Wu Jiaqi , Feng Chuanhong , Ma Li , Hu Gao , Li Qing
Published: October 2022

The Sichuan Province, located in Southwest China, is one of China’s main maize-producing areas, and is also an important node along the north-south migratory pathways that pests follow within China. After its invasion, the fall armyworm (FAW), Spodoptera frugiperda (Smith), was found in 70.81% of all counties in Sichuan. However, FAW source areas and their migratory pathways into Sichuan remain unclear. This study simulated FAW sources and their migratory pathways into Sichuan during 2020 and 2021 using the trajectory simulation platform HYSPLIT with flight behavior parameters. Additionally, the seasonal horizontal wind field was also analyzed with the meteorological graphics processing software GrADS. The results showed that sporadic FAW migration into Sichuan began in April. By May, FAWs were found in much of the Sichuan Basin and moved further north and west in June. Except for year-round breeding areas, FAW sources varied monthly and expanded northward and eastward. The source areas were concentrated in Yunnan, Guizhou, Chongqing, and Myanmar on the western pathway of national migration and also in Vietnam, Guangxi, and Hunan of the eastern pathway. At various times, parts of Sichuan have also served as sources for other parts of Sichuan. FAWs migrated to Sichuan from the source areas via 6 potential pathways, 1 pathway into southwest Sichuan and 5 pathways into the Sichuan basin. The southwestern airflow from the Bay of Bengal, the southeastern airflow controlled by the western Pacific subtropical high, and the local topographically influenced airflow could provide the airflow needed for FAW migration. This work provides new information that can assist the monitoring and warning of the presence of FAW and support integrated management strategies for this pest in Sichuan and throughout China.
The Transcription of Flight Energy Metabolism Enzymes Declined with Aging While Enzyme Activity Increased in the Long-Distance Migratory Moth, Spodoptera frugiperda
Authors: Fu Yan , Wu Ting , Yu Hong , Xu Jin , Zhang Jun-Zhong , Fu Da-Ying , Ye Hui
Published: October 2022

Of all the things that can fly, the flight mechanisms of insects are possibly the least understood. By using RNAseq, we studied the aging-associated gene expression changes in the thorax of Spodoptera frugiperda females. Three possible flight energy metabolism pathways were constructed based on 32 key metabolic enzymes found in S. frugiperda. Differential expression analysis revealed up to 2000 DEGs within old females versus young ones. Expression and GO and KEGG enrichment analyses indicated that most genes and pathways related to energy metabolism and other biological processes, such as transport, redox, longevity and signaling pathway, were downregulated with aging. However, activity assay showed that the activities of all the five tested key enzymes increased with age. The age-associated transcriptional decrease and activity increase in these enzymes suggest that these enzymes are stable. S. frugiperda is a long-distance migrator, and a high activity of enzymes may be important to guarantee a high flight capacity. The activity ratio of GAPDH/HOAD ranged from 0.594 to 0.412, suggesting that lipid is the main fuel of this species, particularly in old individuals. Moreover, the expression of enzymes in the proline oxidation pathway increased with age, suggesting that this energy metabolic pathway also is important for this species or linked to some aging-specific processes. In addition, the expression of immunity- and repair-related genes also increased with age. This study established the overall transcriptome framework of the flight muscle and aging-associated expression change trajectories in an insect for the first time.
Temporal and Spatial Distribution Patterns of Spodoptera frugiperda in Mountain Maize Fields in China
Authors: He Yanyan , Wang Kun , Du Guangzu , Zhang Qiong , Li Bin , Zhao Lin , He Ping , Chen Bin
Published: October 2022

Spodoptera frugiperda (Lepidoptera: Noctuidae) is a major pest of maize worldwide. This pest colonized maize in Shizong, Qujing, Yunnan, China in 2019. To explore the temporal and spatial distribution of S. frugiperda in local fields, “W” type 5-point sampling was performed from 2020 to 2021. The spatial distribution was analyzed using the aggregation index, Iwao’s regression, and Taylor’s power law. The temporal distribution showed two peaks for both 2020 and 2021 when the density of eggs, larvae, and adults was high throughout the maize growth period. Additionally, 1st and 3rd instar larvae were higher in number during the maize seedling, jointing, and spinning stages. Fourth to 6th instar larvae were higher in number after the tasseling stage. Additionally, the spatial distribution results showed that 1st to 3rd instar larvae were aggregated, while 4th to 6th instar larvae were uniformly distributed in mountain maize fields. This study provides monitoring data for S. frugiperda and clarifies the temporal and spatial distribution characteristics for larvae in mountain maize fields. Further, it also provides guidance for investigation into population dynamics and the development of predictive models for integrated S. frugiperda management.
Latent Genetic Effects of Past Selection on Blood Feeding: History Matters
Authors: Bradshaw William E. , Kizziar Piper , Borowczak Rudyard J. , Kirsch Ethan , Holzapfel Christina M.
Published: October 2022

Conventional wisdom is that selection decreases genetic variation in populations, variation that should enable and be essential for population persistence in an ever-changing world. Basically, we find the opposite. Response to selection on biting in the pitcher-plant mosquito, Wyeomyia smithii, increases from 20 to 80% in 19 generations, but reverts back to the original 20% after seven generations of relaxed (not reversed) selection. At the same time, biting in the control line remains at the original 20% through 30 generations without blood feeding. Imposition of selection on biting in both lines elicits a rapid response in the previously selected line, but, importantly, not in the control line. Genetic variation for biting has increased, not decreased, as a consequence of long-term directional selection, contrary to expectations. Convergent phenotypes belie the underlying difference in future adaptive potential. Selection events over time in the background of individuals or populations will determine outcomes of applied research, be it in the fields of medicine, agriculture, or conservation. In short, history matters.
The Impact of Zinc Oxide Micro-Powder Filler on the Physical and Mechanical Response of High-Density Polyethylene Composites in Material Extrusion 3D Printing
Authors: Vidakis Nectarios , Petousis Markos , Maniadi Athena , Papadakis Vassilis , Moutsopoulou Amalia
Published: October 2022

The scope of this work was to develop novel polymer composites via melt extrusion and 3D printing, incorporating High-Density Polyethylene filled with zinc oxide particles in various wt. percentages. For each case scenario, a filament of approximately 1.75 mm in diameter was fabricated. Samples for tensile and flexural testing were fabricated with 3D printing. They were then evaluated for their mechanical response according to ASTM standards. According to the documented testing data, the filler increases the mechanical strength of pure HDPE at specific filler concentrations. The highest values reported were a 54.6% increase in the flexural strength with HDPE/ZnO 0.5 wt.% and a 53.8% increase in the tensile strength with 10 wt.% ZnO loading in the composite. Scanning Electron Microscopy (SEM), Raman, and thermal characterization techniques were used. The experimental findings were evaluated in other research areas where they were applicable.
Effects of Feedback-Supported Online Training during the Coronavirus Lockdown on Posture in Children and Adolescents
Authors: Ludwig Oliver , Dindorf Carlo , Schuh Torsten , Haab Thomas , Marchetti Johannes , Fröhlich Michael
Published: October 2022

(1) Background. The coronavirus pandemic had a serious impact on the everyday life of children and young people with sometimes drastic effects on daily physical activity time that could have led to posture imbalances. The aim of the study was to examine whether a six-week, feedback-supported online training programme could improve posture parameters in young soccer players. (2) Methods. Data of 170 adolescent soccer players (age 15.6 ± 1.6 years) were analyzed. A total of 86 soccer players of a youth academy participated in an online training program that included eight exercises twice per week for 45 min (Zoom group). The participants’ exercise execution could be monitored and corrected via smartphone or laptop camera. Before and after the training intervention, participants’ posture was assessed using photographic analysis. The changes of relevant posture parameters (perpendicular positions of ear, shoulder and hips, pelvic tilt, trunk tilt and sacral angle) were statistically tested by robust mixed ANOVA using trimmed means. Postural parameters were also assessed post hoc at 8-week intervals in a control group of 84 participants of the same age. (3) Results. We found a statistically significant interaction (p < 0.05) between time and group for trunk tilt, head and shoulder protrusion and for hip anteversion in the Zoom group. No changes were found for these parameters in the control group. For pelvic tilt no significant changes were found. (4) Conclusions. Feedback-based online training with two 45 min sessions per week can improve postural parameters in adolescent soccer players over a period of six weeks.
Robustness Analysis of Pin Joining
Authors: Römisch David , Zirngibl Christoph , Schleich Benjamin , Wartzack Sandro , Merklein Marion
Published: October 2022

The trend towards lightweight design, driven by increasingly stringent emission targets, poses challenges to conventional joining processes due to the different mechanical properties of the joining partners used to manufacture multi-material systems. For this reason, new versatile joining processes are in demand for joining dissimilar materials. In this regard, pin joining with cold extruded pin structures is a relatively new, two-stage joining process for joining materials such as high-strength steel and aluminium as well as steel and fibre-reinforced plastic to multi-material systems, without the need for auxiliary elements. Due to the novelty of the process, there are currently only a few studies on the robustness of this joining process available. Thus, limited statements on the stability of the joining process considering uncertain process conditions, such as varying material properties or friction values, can be provided. Motivated by this, the presented work investigates the influence of different uncertain process parameters on the pin extrusion as well as on the joining process itself, carrying out a systematic robustness analysis. Therefore, the methodical approach covers the complete process chain of pin joining, including the load-bearing capacity of the joint by means of numerical simulation and data-driven methods. Thereby, a deeper understanding of the pin joining process is generated and the versatility of the novel joining process is increased. Additionally, the provision of manufacturing recommendations for the forming of pin joints leads to a significant decrease in the failure probability caused by ploughing or buckling effects.
Spatial Genetic Structure and Pathogenic Race Composition at the Field Scale in the Sunflower Downy Mildew Pathogen, Plasmopara halstedii
Authors: Elameen Abdelhameed , de Labrouhe Denis Tourvieille , Bret-Mestries Emmanuelle , Delmotte Francois
Published: October 2022

Yield losses in sunflower crops caused by Plasmopara halstedii can be up to 100%, depending on the cultivar susceptibility, environmental conditions, and virulence of the pathogen population. The aim of this study was to investigate the genetic and phenotypic structure of a sunflower downy mildew agent at the field scale. The genetic diversity of 250 P. halstedii isolates collected from one field in southern France was assessed using single-nucleotide polymorphisms (SNPs) and single sequence repeats (SSR). A total of 109 multilocus genotypes (MLG) were identified among the 250 isolates collected in the field. Four genotypes were repeated more than 20 times and spatially spread over the field. Estimates of genetic relationships among P. halstedii isolates using principal component analysis and a Bayesian clustering approach demonstrated that the isolates are grouped into two main genetic clusters. A high level of genetic differentiation among clusters was detected (FST = 0.35), indicating overall limited exchange between them, but our results also suggest that recombination between individuals of these groups is not rare. Genetic clusters were highly related to pathotypes, as previously described for this pathogen species. Eight different races were identified (100, 300, 304, 307, 703, 704, 707, and 714), with race 304 being predominant and present at most of the sites. The co-existence of multiple races at the field level is a new finding that could have important implications for the management of sunflower downy mildew. These data provide the first population-wide picture of the genetic structure of P. halstedii at a fine spatial scale.
Treatment Results of Endoscopic Transnasal Orbital Decompression for Graves’ Orbitopathy—A Single-Center Retrospective Analysis in 28 Orbits of 16 Patients
Authors: Poślednik Krzysztof B. , Czerwaty Katarzyna , Ludwig Nils , Molińska-Glura Marta , Jabłońska-Pawlak Anna , Miśkiewicz Piotr , Kantor Ireneusz , Dżaman Karolina , Cyran Anna M. , Szczepański Mirosław J.
Published: October 2022

Graves’ orbitopathy (GO) is an extrathyroidal manifestation of Graves’ disease (GD), which can be associated with corneal ulcerations or optic neuropathy in severe forms. Transnasal endoscopic orbital decompression (TEOD) is a surgical procedure performed in order to decrease the intraorbital pressure by removing part of its bony borders in cases with excessive mass in orbit. The aim of this study was to present the results and evaluate the efficacy of TEOD for GO. The retrospective study included 28 orbits (16 patients) who underwent TEOD from 2017 to 2020. Outcome was evaluated based on visual acuity improvement, clinical activity score (CAS) decrease, proptosis, and intraocular pressure (IOP) reduction. A preoperative best-corrected visual acuity (BCVA) increased from 0.69 ± 0.385 (mean ± standard deviation) to 0.74 ± 0.332 (p = 0.17) postoperatively. CAS decreased in 15 orbits postoperatively. Proptosis decreased from 22.89 ± 1.873 mm to 21.25 ± 2.053 mm (p < 0.05). IOP decreased from a preoperative 16.11 ± 3.93 mmHg to 14.40 ± 3.27 mmHg (p < 0.05) postoperatively. In addition, postoperative relief of exposure keratitis was observed. The analysis of development of iatrogenic diplopia revealed increasing in degree of diplopia. TEOD shows rare complications, but significant improvements in BCVA, CAS, proptosis, and IOP.
Effect of Dialysis Modalities on All-Cause Mortality and Cardiovascular Mortality in End-Stage Kidney Disease: A Taiwan Renal Registry Data System (TWRDS) 2005–2012 Study
Authors: Su Po-Cheng , Zheng Cai-Mei , Chen Chien-Chou , Chiu Li-Yun , Chang Hao-Yun , Tsai Meng-Hsu , Liao Chia-Te , Kao Chih-Chin , Hsu Yung-Ho , Shen Che-Chou , Hsu Chih-Cheng , Wu Mai-Szu , Lin Yen-Chung
Published: October 2022

Introduction: End-stage kidney disease (ESKD) patients who need renal replacement therapy need to face a dialysis modality decision: the choice between hemodialysis (HD) and peritoneal dialysis (PD). Although the global differences in HD/PD penetration are affected by health-care policies, these two modalities may exert different effects on survival in patients with ESKD. Although Taiwan did not implicate PD as first policy, we still need to compare patients’ outcomes using two modalities in a nation-wise database to determine future patients’ care and health policies. Methods: We used the nationwide Taiwan Renal Registry Data System (TWRDS) database from 2005 to 2012 and included 52,900 patients (48,371 on HD and 4529 on PD) to determine all-cause and cardiovascular mortality among ESKD patients. Results: Age-matched survival probability from all-cause mortality was significantly lower in patients on PD than in those on HD (p < 0.05). The adjusted hazard ratios of 3-year and 5-year all-cause and cardiovascular mortality were significantly higher in PD compared with HD. The presence of comorbid conditions including myocardial infarction, coronary artery disease (CAD), diabetes mellitus (DM), hypoalbuminemia, hyperferritinemia and hypophosphatemia was related with significantly higher all-cause and CV mortality in PD patients. No significant difference was noted among younger patients <45 years of age regardless of DM and/or comorbid conditions. Conclusion: Although PD did not have the survival advantage compared to HD in all dialysis populations, PD was related with superior survival in younger non-DM patients, regardless of the presence of comorbidities. Similarly, for younger ESKD patients without the risk of CV disease, both PD and HD would be suitable dialysis modalities.
Pricing Cat Bonds for Cloud Service Failures
Authors: Mastroeni Loretta , Mazzoccoli Alessandro , Naldi Maurizio
Published: October 2022

The use of the cloud to store personal/company data and to run programs is gaining wide acceptance as it is more efficient and cost-effective. However, cloud services may not always be available, which could lead to losses for customers and the cloud provider (the provider is typically obligated to compensate its customers). It can protect itself from such losses through insurance, which transfers the risk to the insurer. In the case of poor cloud availability, the amount that the insurer has to pay back to the cloud provider may become so high that it endangers the insurer’s financial solvency. We propose the use of cat bonds as reinsurance tools as well as the Nowak–Romaniuk pricing scheme. The outage frequency was described by the Poisson process and the loss severity was described by a Pareto random variable; we derived a closed formula for the price of a cat bond in a stochastic interest rate environment, using both one-factor and two-factor short-rate models. We demonstrated the applicability of our pricing formula in a real context.
Evolution and Ecological Implications of Land Development and Conservation Patterns on the Qinghai-Tibet Plateau
Authors: Wang Yafei , Liao Jinfeng , He Yao , Chen Peipei
Published: October 2022

The Qinghai-Tibet Plateau serves as an important ecological security shelter in China and across Asia. During the past two decades, the patterns of land development and conservation on the Qinghai-Tibet Plateau have undergone significant changes under the impacts of global climate change and human expansion. This paper analyzes the evolution of land development and conservation patterns and potential ecological implications on the Tibetan Plateau from 2000 to 2020 based on urbanization, agricultural and pastoral patterns with multi-source data, such as long-term time series land use data, ecological indices, environmental pollution, and population and economics. It was found that: (1) Coinciding with the agglomeration of population and economy, the urban development pattern on the Qinghai-Tibet Plateau has spatial-temporal differentiation. Urban development in the 2010s was more significant than that in the 2000s, with the intensity increased by 63.31%, and the development pattern varies spatially, which can be seen from the finding that central Tibet (the Yarlung Tsangpo, Lhasa river, and Nyangchu basins) and Huangshui River Basin in Qinghai Province were developed in a planar pattern, while other node cities and border towns in a dotted pattern. (2) The agricultural production pattern is relatively stable, the grain yields have increased by 34.68% in the past 20 years, but the total amount of arable land is shrinking, and the degree of fragmentation has increased. The pattern of pastoralism has changed greatly, showing a migration trend from west to east spatially, and there is a serious problem of pasture overload, with an increase of 18.4% in livestock products. Regardless of the pattern of urbanization or agricultural and livestock development, the intensity of human activities on the Qinghai-Tibet Plateau has shown an intensified trend in the past. (3) It shows that Lhasa City area and the middle and lower reaches of Huangshui show a trend of diffusion of atmospheric and water environmental pollution. The western part of the Ali region and the northern foothills of the Himalayas and other regions, under the combined impact of climate change and human activities, have undergone significant ecological degradation. Accordingly, this paper proposes policy recommendations for optimizing production and living space, advancing the establishment of national park clusters and nature reserve systems, and the integrated recovery of mountain, water, forest, lake, grass, sand, and ice with ecological value achievement.
Diagnosis and Prioritization of Vulnerable Areas of Urban Ecosystem Regulation Services
Authors: Lee Dongwoo , Oh Kyushik , Suh Jungeun
Published: October 2022

Rapid urbanization and population growth have led to drastic degradation of urban ecosystem regulation services (ERS). Urgently needed is the identification of vulnerable areas where ERS are being intensively deteriorated, and preparation of measures to respond to them. This study developed a framework to diagnose and prioritize vulnerable areas of urban ERS. The vulnerability of urban ERS that include carbon storage capacity, flood-risk mitigation capacity, and heat stress reduction capacity was diagnosed with a resolution of 100 m × 100 m grid. Priority areas to improve urban ERS were delineated using hot spot analysis, and the diagnosed results of the urban ERS were categorized by eight combination types including exposure, sensitivity, and adaptability. The spatial and societal problems included in the priority areas were further investigated by overlaying hot spot areas with eight combination maps. Finally, spatial management measures for the priority areas were suggested based on the analysis results. From the detailed diagnosis results of the vulnerable ERS areas, this study provides a framework to link the concept of ERS vulnerability with urban planning. Furthermore, effective spatial planning guidelines can be prepared to improve urban ERS by spatially delineating priority areas to improve urban ERS vulnerability.
Rhombencephalitis in Pregnancy—A Challenging Case of Probable Listeria Infection
Authors: Ho Alison E. P. , Rasheed Zahirrah B. M. , Norman James , Gabriel Carolyn , Dixon Luke , Ashworth Simon , Frise Charlotte , Yu Christina K. H. , Sykes Lynne
Published: October 2022

Rhombencephalitis refers to inflammation of the brainstem and cerebellum, and can be caused by infections, autoimmune disorders or paraneoplastic syndromes. The most common infective cause is the bacterium Listeria monocytogenes. Listeria monocytogenes is the predominant species to cause human listeriosis, and is commonly due to the ingestion of contaminated foods. Symptoms include a mild gastroenteritis, fever (often with extreme temperature variations), headache, and myalgia. In more severe cases, invasive disease may lead to bacteraemia and neurolisteriosis. Pregnant women are more susceptible to listeriosis, which is believed to be due to pregnancy-related immune modulation. Maternal-neonatal infection with adverse pregnancy outcomes include neonatal listeriosis, spontaneous miscarriage and intrauterine fetal demise. Diagnosis may be challenging due to initial nonspecific symptoms and low sensitivity and specificity of confirmatory diagnostic laboratory tests. Here, we describe a case of rhombencephalitis in pregnancy, attributed to Listeria, and review the clinical features, diagnosis and multidisciplinary management. Lastly, we describe the immunological response to Listeria monocytogenes and show in vitro pro-inflammatory effects of Listeria monocytogenes on peripheral blood mononuclear cells and placental explants.
Current Understanding of Aortic Dissection
Authors: Yuan Xun , Mitsis Andreas , Nienaber Christoph A.
Published: October 2022

The aorta is the largest artery in the body, delivering oxygenated blood from the left ventricle to all organs. Dissection of the aorta is a lethal condition caused by a tear in the intimal layer of the aorta, followed by blood loss within the aortic wall and separation of the layers to full dissection. The aorta can be affected by a wide range of causes including acute conditions such as trauma and mechanical damage; and genetic conditions such as arterial hypertension, dyslipidaemia, and connective tissue disorders; all increasing the risk of dissection. Both rapid diagnostic recognition and advanced multidisciplinary treatment are critical in managing aortic dissection patients. The treatment depends on the severity and location of the dissection. Open surgical repair is the gold standard of treatment for dissections located to the proximal part of the aorta and the arch, while endovascular interventions are recommended for most distal or type B aortic dissections. In this review article, we examine the epidemiology, pathophysiology, contemporary diagnoses, and management of aortic dissection.
Evaluation of DDGS as a Low-Cost Feed Ingredient for Common Carp (Cyprinus carpio Linneus) Cultivated in a Semi-Intensive System
Authors: Barbacariu Cristian-Alin , Rimbu Cristina Mihaela , Dirvariu Lenuta , Burducea Marian , Boiangiu Razvan Stefan , Todirascu-Ciornea Elena , Dumitru Gabriela
Published: October 2022

Distillers dried grains with solubles (DDGS), a coproduct from the ethanol production industry, is successfully used as an ingredient in feeding cattle and pigs due to its relatively high protein and nutrient content and low price compared to cereals. The aim of this study was to establish the optimal DDGS concentration that can be included in the diet of common carp. A seven-week experiment was performed on common carp with an initial weight of 86 g feed with three experimental diets D0 (DDGS 0%), D1 (DDGS 25%) and D2 (DDGS 35%). The chemical composition of DDGS analyzed by Fourier Transform Near-Infrared (FT-NIR) spectroscopy showed a protein content of 27.56% and oil at 6.75%. Diets with DDGS did not produce significant changes in growth parameters, flesh quality, and blood biochemical profile. Regarding the oxidative status in the muscle tissue, D1 and D2 significantly reduced, in a dose-dependent manner, the specific activity of SOD and GSH, while CAT and GPX were left unaffected. In the liver tissue, CAT, GSH, MDA and carbonylated proteins were reduced in the DDGS diets. The microbiological analysis of the intestinal contents revealed a variation in microbial density depending on the diet used. The total number of aerobic germs was between 224.2 × 104 and 69.84 × 106 (D2 > D1 > D0) and the total number of anaerobic germs was between 15.2 × 102 and 28.2 × 102 (D2 > D0 > D1).
Fluoride Exposure from Ready-To-Drink Coffee Consumption
Authors: Alejandro-Vega Samuel , Suárez-Marichal Daniel , Niebla-Canelo Daniel , Gutiérrez-Fernández Ángel J. , Rubio-Armendáriz Carmen , Hardisson Arturo , Paz-Montelongo Soraya
Published: October 2022

Fluoride is present in various foods ingested daily. It has been demonstrated that the intake of high concentrations of fluoride, both in adults and children, can cause pathologies, among which dental fluorosis, osteoporosis and damage to the central nervous system stand out. The objective of this study was to determine the fluoride concentrations in 60 samples of ready-to-drink cold brewed coffee of different brands and types (expresso, cappuccino, macchiato and decaffeinated) by the fluoride ion-selective potentiometric method. A statistical analysis was also performed to discern the existence of differences between these categories. The highest fluoride concentration (1.465 mg/L) was found in espresso coffee followed by Macchiato (1.254 mg/L). Decaffeinated coffee is the one that presented the lowest fluoride concentration with 0.845 mg/L. The risk assessment was conducted considering different consumption scenarios (250, 500 and 750 mL/day). The UL (upper level) established by the EFSA (European Food Safety Authority) at 7 mg/day was used. The consumption of three servings poses no health risk; however, it confers a significant value of fluoride contribution to the diet.
Compaction Curves and Strength of Clayey Soil Modified with Micro and Nano Silica
Authors: Alshami Abeer W. , Ismael Bashar H. , Aswad Mohammed F. , Majdi Ali , Alshijlawi Murtatha , Aljumaily Mustafa Mohammed , AlOmar Mohamed Khalid , Aidan Ibraheem A. , Hameed Mohammed Majeed
Published: October 2022

Some Clayey soils are generally categorized as weak soils, and structures lying on such soils have been exposed to severe damage. Therefore, the central thesis of this paper is the impact of a waste material known as a silica fume as nano and micro material on soil’s behaviour. To evaluate the effects of those additives on Atterberg limits, compaction characteristics and unconfined compressive strength, clayey soil samples have been transformed using micro and nano silica fume (by-product materials). In the current investigation, silica fume is used at four different percentages: 0, 2, 4, and 7%. The results show that the plasticity index of soil decreases with the addition of micro silica and increases with the addition of nano-silica. Increasing nano silica percentage improves the dry density of the compacted soil and reduces the optimum moisture content. An opposite behavior is observed with adding micro silica to compacted soil. Finally, 4% of silica fume is found to be the optimum dosage to improve the unconfined compressive strength of the treated soil with both additives. As a result, treating the weak clay soil with micro and/or nano-silica fume has the potential to be impactful.
On As(III) Adsorption Characteristics of Innovative Magnetite Graphene Oxide Chitosan Microsphere
Authors: Shan Huimei , Liu Yunquan , Zeng Chunya , Peng Sanxi , Zhan Hongbin
Published: October 2022

A magnetite graphene oxide chitosan (MGOCS) composite microsphere was specifically prepared to efficiently adsorb As(III) from aqueous solutions. The characterization analysis of BET, XRD, VSM, TG, FTIR, XPS, and SEM-EDS was used to identify the characteristics and adsorption mechanism. Batch experiments were carried out to determine the effects of the operational parameters and to evaluate the adsorption kinetic and equilibrium isotherm. The results show that the MGOCS composite microsphere with a particle size of about 1.5 mm can be prepared by a straightforward method of dropping FeCl2, graphene oxide (GO), and chitosan (CS) mixtures into NaOH solutions and then drying the mixed solutions at 45 °C. The produced MGOCS had a strong thermal stability with a mass loss of <30% below 620 °C. The specific surface area and saturation magnetization of the produced MGOCS was 66.85 m2/g and 24.35 emu/g, respectively. The As(III) adsorption capacity (Qe) and removal efficiency (Re) was only 0.25 mg/g and 5.81% for GOCS, respectively. After 0.08 mol of Fe3O4 modification, more than 53% of As(III) was efficiently removed by the formed MGOCS from aqueous solutions over a wide pH range of 5–10, and this was almost unaffected by temperature. The coexisting ion of PO43− decreased Qe from 3.81 mg/g to 1.32 mg/g, but Mn2+ increased Qe from 3.50 mg/g to 4.19 mg/g. The As(III) adsorption fitted the best to the pseudo-second-order kinetic model, and the maximum Qe was 20.72 mg/g as fitted by the Sips model. After four times regeneration, the Re value of As(III) slightly decreased from 76.2% to 73.8%, and no secondary pollution of Fe happened. Chemisorption is the major mechanism for As(III) adsorption, and As(III) was adsorbed on the surface and interior of the MGOCS, while the adsorbed As(III) was partially oxidized to As(V) accompanied by the reduction of Fe(III) to Fe(II). The produced As(V) was further adsorbed through ligand exchange (by forming Fe–O–As complexes) and electrostatic attraction, enhancing the As(III) removal. As an easily prepared and environmental-friendly composite, MGOCS not only greatly adsorbs As(III) but also effectively removes Cr(VI) and As(V) (Re > 60%) and other metals, showing a great advantage in the treatment of heavy metal-contaminated water.
Approximation Model Development and Dynamic Characteristic Analysis Based on Spindle Position of Machining Center
Authors: Kim Ji-Wook , Kim Dong-Yul , Won Hong-In , Noh Yoo-Jeong , Ko Dae-Cheol , Jang Jin-Seok
Published: October 2022

To evaluate the dynamic characteristics at all positions of the main spindle of a machine tool, an experimental point was selected using a full factorial design, and a vibration test was conducted. Based on the measurement position, the resonant frequency was distributed from approximately 236 to 242 Hz. The approximation model was evaluated based on its resonant frequencies and dynamic stiffness using regression and interpolation methods. The accuracy of the resonant frequency demonstrated by the kriging method was approximately 89%, whereas the highest accuracy of the dynamic stiffness demonstrated by the polynomial regression method was 81%. To further verify the approximation model, its dynamic characteristics were measured and verified at additional experimental points. The maximum errors yielded by the model, in terms of the resonant frequency and dynamic stiffness, were 1.6% and 7.1%, respectively.
Comparison Study of PVD Coatings: TiN/AlTiN, TiN and TiAlSiN Used in Wood Machining
Authors: Kucharska Beata , Czarniak Paweł , Kulikowski Krzysztof , Krawczyńska Agnieszka , Rożniatowski Krzysztof , Kubacki Jerzy , Szymanowski Karol , Panjan Peter , Sobiecki Jerzy Robert
Published: October 2022

In this paper, we analyze the possibilities of the protection of tools for wood machining with PVD (Physical Vapor Deposition) hard coatings. The nanolayered TiN/AlTiN coating, nanocomposite TiAlSiN coatings, and single layer TiN coating were analyzed in order to use them for protection of tools for wood machining. Both nanostructured coatings were deposited in an industrial magnetron sputtering system on the cutting blades made of sintered carbide WC-Co, while TiN single layer coating was deposited by evaporation using thermionic arc. In the case of TiN/AlTiN nanolayer coatings the thickness of the individual TiN and AlTiN layer was in the 5–10 nm range, depending on the substrate vertical position. The microstructure and chemical composition of coatings were studied by scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) method. Additionally, in the case of the TiN/AlTiN coating, which was characterized by the best durability characteristics, the transmission electron microscope (TEM) and X-ray photoelectron spectroscopy (XPS) methods were applied. The coatings adhesion to the substrate was analyzed by scratch test method combined with optical microscopy. Nano-hardness and durability tests were performed with uncoated and coated blades using chipboard. The best results durability characteristics were observed for TiN/AlTiN nanolayered coating. Performance tests of knives protected with TiN and TiAlSiN hard coatings did not show significantly better results compared to uncoated ones.
Exploring the Absorption Spectra of an Ultra-Wideband Metamaterial Absorber in the Visible and Near-Infrared Regions
Authors: Tharwat Marwa M. , Alsulami Abdulaziz R. , Mahros Amr M.
Published: October 2022

This paper investigates the absorption spectra of a plasmonic metamaterial absorber in the visible and near-infrared regimes by utilizing a metal-dielectric-metal (MDM) functional stack. A periodic metal-dielectric cap is introduced on top of a metallic substrate to excite surface plasmon modes. The shape of this cap and the glass coating modifies the absorbance bandwidth. Although the circular cap exhibits less broadening in the absorbance than the square one, the circular cap’s glass coating boosts the bandwidth’s expansion in the near-infrared region to about 1.65 µm. In the visible and near-infrared regimes, absorption bandwidth and spectral ratio can be tailored by modifying four distinct structural parameters. The finding shows that one can achieve an ultra-broad bandwidth that extends from 0.3 µm to 1.65 µm at 90% absorbance. The thickness of the top titanium layer, the silicon dioxide spacer thickness, the Ti-SiO2 cap diameter, and the sliver substrate pitch are selected to be 20 nm, 60 nm, 215 nm, and 235 nm, respectively. Furthermore, the influence of using various metals on absorption spectra has been explored in the visible and near-infrared regimes. The d metals considered for the top layer are titanium, nickel, chromium, silver, copper, gold, aluminum, and gold.
Biocomposites with Epoxy Resin Matrix Modified with Ingredients of Natural Origin
Authors: Szatkowski Piotr , Szatkowska Martyna , Gralewski Jacek , Czechowski Leszek , Kedziora Slawomir
Published: October 2022

This study aims to present various forms of cellulose, whose shape depends on the source of origin, and to demonstrate the differences in the influence on the properties of materials produced with its participation. For this purpose, composites with various plant additives have been designed and obtained. Some of them have undergone chemical and pyrolytic modifications. The results of the mechanical, physicochemical and microscopic tests showed differences in cellulose structure, even in the case of very similar sources, and its diversified influence on the characteristics of the obtained materials. The research shows the effect of the use of natural additives and their modified versions on the mechanical properties of the composite based on epoxy resin. It turns out that cellulose modifiers are not only fillers that reduce the price of the final product but can also increase some mechanical properties, e.g., compressive strength, which is an additional advantage and a reason for wider use. The potential of natural resources is not yet fully understood. Relatively recently, people have started to be interested in cellulose on a nanometric scale, as it turns out that it can exist in several different forms with interesting properties.
Electronic Band Structure and Surface States in Dirac Semimetal LaAgSb2
Authors: Rosmus Marcin , Olszowska Natalia , Bukowski Zbigniew , Starowicz Paweł , Piekarz Przemysław , Ptok Andrzej
Published: October 2022

LaAgSb2 is a Dirac semimetal showing charge density wave (CDW) order. Previous angle-resolved photoemission spectroscopy (ARPES) results suggest the existence of the Dirac-cone-like structure in the vicinity of the Fermi level along the Γ–M direction. This paper is devoted to a complex analysis of the electronic band structure of LaAgSb2 by means of ARPES and theoretical studies within the ab initio method as well as tight binding model formulation. To investigate the possible surface states, we performed the direct DFT slab calculation and the surface Green function calculation for the (001) surface. The appearance of the surface states, which depends strongly on the surface, points to the conclusion that LaSb termination is realized in the cleaved crystals. Moreover, the surface states predicted by our calculations at the Γ and X points are found by ARPES. Nodal lines, which exist along the X–R and M–A paths due to crystal symmetry, are also observed experimentally. The calculations reveal other nodal lines, which originate from the vanishing of spin–orbit splitting and are located at the X–M–A–R plane at the Brillouin zone boundary. In addition, we analyze the band structure along the Γ–M path to verify whether Dirac surface states can be expected. Their appearance in this region is not confirmed.
Stochastic Reliability-Based Design Optimization Framework for the Steel Plate Girder with Corrugated Web Subjected to Corrosion
Authors: Sokołowski Damian , Kamiński Marcin
Published: October 2022

This paper proposes the framework for reliability-based design optimization (RBDO) of structural elements with an example based on the corrugated web I-girder. It tackles the problem of topological optimization of corroding structures with uncertainties. Engineering restrictions follow a concept of the limit states (LS) and extend it for stability and eigenfrequency assessment. The reliability constraints include all the LS; they are computed according to first- and second-order reliability methods. The RBDO example minimizes the bridge girder cross-section while satisfying the structural reliability level for the ultimate and the serviceability limit states, stability, and eigenfrequency. It takes into consideration two uncorrelated random effects, i.e., manufacturing imperfection and corrosion. They are both Gaussian; the first of them is applied at assembly time, while the second is applied according to the time series. The example confronts three independent FEM models with an increasing level of detailing, and compares RBDO results for three concurrent probabilistic methods, i.e., the iterative stochastic perturbation technique (ISPT), the semi-analytical method, and the Monte Carlo simulation. This study proves that the RBDO analysis is feasible even for computationally demanding structures, can support automation of structural design, and that the level of detailing in the FEM models influences its results. Finally, it exemplifies that reliability restrictions for LS are much more rigorous than for their deterministic counterparts, and that the fastest ISPT method is sufficiently accurate for probabilistic calculations in this RBDO.
Improved Enamel Acid Resistance Using Biocompatible Nano-Hydroxyapatite Coating Method
Authors: Satou Ryouichi , Iwasaki Miyu , Kamijo Hideyuki , Sugihara Naoki
Published: October 2022

In this study, we attempted to develop a dental caries prevention method using a bioapatite (BioHap), an eggshell-derived apatite with nanoparticle size and biocompatibility, with a high-concentration fluoride tooth surface application method. The enamel acid resistance after the application of the proposed method was compared with that of a conventional topical application of fluoride using bovine tooth enamel as an example. The tooth samples were divided into three groups based on the preventive treatment applied, and an acid challenge was performed. The samples were evaluated for acid resistance using qualitative and quantitative analytical methods. The BioHap group demonstrated reduced enamel loss and improved micro-Vickers hardness, along with a thick coating layer, decreased reaction area depth, and decreased mineral loss value and lesion depth. The combination of BioHap with high-concentration fluoride led to the formation of a thick coating layer on the enamel surface and better suppression of demineralization than the conventional method, both qualitatively and quantitatively. The proposed biocompatible nano-hydroxyapatite coating method is expected to become a new standard for providing professional care to prevent dental caries.
Remineralization of Artificially Demineralized Human Enamel and Dentin Samples by Zinc-Carbonate Hydroxyapatite Nanocrystals
Authors: Kranz Stefan , Heyder Markus , Mueller Stephan , Guellmar André , Krafft Christoph , Nietzsche Sandor , Tschirpke Caroline , Herold Volker , Sigusch Bernd , Reise Markus
Published: October 2022

(1) Background: Decalcified enamel and dentin surfaces can be regenerated with non-fluoride-containing biomimetic systems. This study aimed to investigate the effect of a zinc carbonate-hydroxyapatite-containing dentifrice on artificially demineralized enamel and dentin surfaces. (2) Methods: Human enamel and dentin discs were prepared and subjected to surface demineralization with 30% orthophosphoric acid for 60 s. Subsequently, in the test group (n = 20), the discs were treated three times a day for 3 min with a zinc carbonate-hydroxyapatite-containing toothpaste (biorepair®). Afterwards, all samples were gently rinsed with PBS (5 s) and stored in artificial saliva until next use. Samples from the control group (n = 20) received no dentifrice-treatment and were stored in artificial saliva, exclusively. After 15 days of daily treatment, specimens were subjected to Raman spectroscopy, energy-dispersive X-ray micro-analysis (EDX), white-light interferometry, and profilometry. (3) Results: Raman spectroscopy and white-light interferometry revealed no significant differences compared to the untreated controls. EDX analysis showed calcium phosphate and silicon dioxide precipitations on treated dentin samples. In addition, treated dentin surfaces showed significant reduced roughness values. (4) Conclusions: Treatment with biorepair® did not affect enamel surfaces as proposed. Minor mineral precipitation and a reduction in surface roughness were detected among dentin surfaces only.
Inverse Identification of a Constitutive Model for High-Speed Forming Simulation: An Application to Electromagnetic Metal Forming
Authors: Kang Dayoung , Noh Hak-Gon , Kim Jeong , Lee Kyunghoon
Published: October 2022

Forming simulation requires a constitutive model whose parameters are typically determined with tensile tests assumed static. However, this conventional approach is impractical for high-speed forming simulation characterized by high strain rates inducing transient effects. To identify constitutive parameters in relation to high-speed forming simulation, we formulated the problem of constitutive modeling as inverse parameter estimation addressed by regularized nonlinear least squares. Regarding the proposed inverse constitutive modeling, we adopted the L-curve method for proper regularization and model order reduction for rapid simulation. For demonstration, we corroborated the proposed strategy by identifying the modified Johnson–Cook model in the context of a free bulge test with electromagnetic metal forming simulation. The L-curve method allowed us to systematically choose a regularization parameter, and model order reduction brought enormous computational savings. After identifying constitutive parameters, we successfully verified and validated the reduced and original simulation models, respectively, with a manufactured workpiece. In addition, we validated the numerically identified constitutive model with a dynamic material test using a split Hopkinson pressure bar. Overall, we showed that inverse constitutive modeling for high-speed forming simulation can be effectively tackled by regularized nonlinear least squares with the help of an L-curve and a reduced-order model.
The Effect of Molten Salt Infiltration on 2D SiCf/SiC Composite by Chemical Vapour Infiltration
Authors: Gao Yantao , Tang Hui , Li Ke , Yan Hao
Published: October 2022

The SiCf/SiC composite manufactured by chemical vapour infiltration (CVI) is a kind of porous material. Liquid molten salt in a Molten Salt Reactor (MSR) may enter into the porous composites and affect their performance. Through the study of the internal pores in the material, the permeability behaviour of the material can be investigated, which is of great significance to the analysis of the properties of the material itself. However, there is less investigation on effects of molten salt infiltration on the internal pore structure of SiCf/SiC composites. In this paper, a molten salt infiltration experiment of 2D woven SiCf/SiC composites was implemented at 650 °C, 3 atm. SEM, CT and XRD were used to characterize it. The results indicated that the microstructure could be affected by partial molten salt infiltration and temperature change. The distribution of porosity of the composite showed an obvious transformation. The lattice spacing of SiC showed an increased tendancy of stress relaxation.