bluuebunny/crossref_metadata_2025 huggingface dataset:
On the Stability of PtIV Pro‐Drugs with Haloacetato Ligands in the Axial Positions
Authors: Wexselblatt Ezequiel , Raveendran Raji , Salameh Sawsan , Friedman‐Ezra Aviva , Yavin Eylon , Gibson Dan
Published: December 2014

The design of PtIV pro‐drugs as anticancer agents is predicated on the assumption that they will not undergo substitution reactions before entering the cancer cell. Attempts to improve the cytotoxic properties of PtIV pro‐drugs included the use of haloacetato axial ligands. Herein, we demonstrate that PtIV complexes with trifluoroacetato (TFA) or dichloroacetato (DCA) ligands can be unstable under biologically relevant conditions and readily undergo hydrolysis, which results in the loss of the axial TFA or DCA ligands. The half‐lives for PtIV complexes with two TFA or DCA ligands at pH 7 and 37 °C range from 6 to 800 min, which is short relative to the duration of cytotoxicity experiments that last 24–96 h. However, complexes with two monochloroacetato (MCA) or acetato axial ligands are stable under biologically relevant conditions. The loss of the axial ligands depends primarily on the electron‐withdrawing strength of the axial ligands, but also upon the nature of the equatorial ligands. We were unable to find obvious correlations between the structures of the PtIV complexes and the rates of decay of the parent compounds. The X‐ray crystal structures of the bis‐DCA and bis‐MCA PtIV derivatives of oxaliplatin did not reveal any significant structural differences that could explain the observed differences in stability.
ChemInform Abstract: Experimental and Theoretical Investigations for Site Preference and Anisotropic Size Change of RE11Ge4In6‐xMx (RE: La, Ce; M: Li, Ge; x = 1, 1.96).
Authors: Jeon Beom‐Yong , Jeon Jieun , Lee Junseong , Kim Jongsik , You Tae‐Soo
Published: December 2014

La11Ge4In5.00Li1.00 and Ce11Ge5.96In4.04 are prepared from the elements (Nb tubes, 1080 °C for 5 h and 750 °C for 2 d) and characterized by powder and single crystal XRD, and TB‐LMTO‐ASA computations.
ChemInform Abstract: MgSrP3N5O2 — A Novel Oxonitridophosphate.
Authors: Pucher Florian J. , Schnick Wolfgang
Published: December 2014

Single crystals of MgSrP3N5O2 are grown by hot isostatic pressing of a mixture of Mg3N2, Sr(N3)2, P3N5, PON, and catalytic amounts of NH4Cl (multianvil press, BN crucible, 1000 °C, 6 GPa, 1 h).
ChemInform Abstract: Speciation of Molybdates under Hydrothermal Conditions.
Authors: Noack Johannes , Rosowski Frank , Schloegl Robert , Trunschke Annette
Published: December 2014

In situ Raman spectroscopy is applied to investigate the speciation of molybdates under hydrothermal conditions in 0.2 M aqueous solution of (NH4)6Mo7O24 (autoclave, 20—200 °C, pH 1—7).
ChemInform Abstract: A Chameleon Catalyst for Nonheme Iron‐Promoted Olefin Oxidation.
Authors: Iyer Shyam R. , Javadi Maedeh Moshref , Feng Yan , Hyun Min Young , Oloo Williamson N. , Kim Cheal , Que Lawrence Jr.
Published: December 2014

furnishing nearly exclusively cis‐dihydroxylation or exclusively epoxidation products (no yields given)
ChemInform Abstract: C3‐Symmetric Chiral Trisimidazoline‐Catalyzed Friedel—Crafts (FC)‐Type Reaction.
Authors: Takizawa Shinobu , Hirata Shuichi , Murai Kenichi , Fujioka Hiromichi , Sasai Hiroaki
Published: December 2014

The first imidazoline‐mediated highly enantioselective Friedel—Crafts‐type reaction between aldimines and naphthols is reported.
ChemInform Abstract: Asymmetric Organocatalytic Desymmetrization of 4,4‐Disubstituted Cyclohexadienones at High Pressure: A New Powerful Strategy for the Synthesis of Highly Congested Chiral Cyclohexenones.
Authors: Miyamae Naomu , Watanabe Naruhisa , Moritaka Maya , Nakano Keiji , Ichikawa Yoshiyasu , Kotsuki Hiyoshizo
Published: December 2014

A diastereo‐ and enantioselective method for the asymmetric desymmetrization of 4,4‐disubstituted cyclohexadienones using the Michael addition of malonate (II) under catalysis with primary amine‐thiourea conjugate catalyst and pyrrolidino‐pyridine (PPY) is reported.
ChemInform Abstract: Enantioselective Palladium Catalyzed Conjugate Additions of ortho‐Substituted Arylboronic Acids to β,β‐Disubstituted Cyclic Enones: Total Synthesis of Herbertenediol, Enokipodin A and Enokipodin B.
Authors: Buter Jeffrey , Moezelaar Renee , Minnaard Adriaan J.
Published: December 2014

The title reaction affords products (II) and (V) in good to high enantiomeric excesses, though the obtained yields are low to moderate.
ChemInform Abstract: Solvent‐Free Asymmetric Conjugate Addition of Malonates to Enones Using a Diaminomethylenemalononitrile Organocatalyst.
Authors: Hirashima Shin‐ichi , Sakai Takaaki , Nakashima Kosuke , Watanabe Nana , Koseki Yuji , Mukai Kanako , Kanada Yohei , Tada Norihiro , Itoh Akichika , Miura Tsuyoshi
Published: December 2014

The optically active diamine title catalyst efficiently promotes the conjugate addition of malonates to enones to give the corresponding addition products in good yields with excellent enantioselectivities.
ChemInform Abstract: Synthesis of Novel Cinchona‐Amino Acid Hybrid Organocatalysts for Asymmetric Catalysis.
Authors: Barrulas Pedro , Benaglia Maurizio , Burke Anthony J.
Published: December 2014

Several amino acids and dipeptides are coupled in good overall yields to furnish chinchonidine derivatives.
ChemInform Abstract: Palladium‐Catalyzed Dearomative Trimethylenemethane Cycloaddition Reactions.
Authors: Trost Barry M. , Ehmke Veronika , O'Keefe B. Michael , Bringley Dustin A.
Published: December 2014

The title reaction proceeds without subsequent rearomatization and can be applied on a broad range of heterocyclic and benzoid substrates.
ChemInform Abstract: Enantiospecific Intramolecular Heck Reactions of Secondary Benzylic Ethers.
Authors: Harris Michael R. , Konev Mikhail O. , Jarvo Elizabeth R.
Published: December 2014

A protocol for preparation of methylenecyclopentanes from ε‐unsaturated secondary benzylic ethers is presented.
ChemInform Abstract: Acyloxylation of Cyclic Enones: Synthesis of Densely Oxygenated Guaianolides.
Authors: Marin‐Barrios Ruben , Garcia‐Cabeza Ana Leticia , Moreno‐Dorado F. Javier , Guerra Francisco M. , Massanet Guillermo M.
Published: December 2014

The optimized conditions found for the title reaction can be applied to various substrates.
ChemInform Abstract: A Cooperative Allylic Fluorination: Combination of Nucleophilic and Electrophilic Fluorine Sources.
Authors: Bloom Steven , Knippel James Levi , Holl Maxwell Gargiulo , Barber Ross , Lectka Thomas
Published: December 2014

Optimized reaction conditions are developed for the regioselective allylic fluorination of alkenes via a tandem fluoroselenation‐deselenation process.
ChemInform Abstract: Mild Pd‐Catalyzed Aminocarbonylation of (Hetero)Aryl Bromides with a Palladacycle Precatalyst.
Authors: Friis Stig D. , Skrydstrup Troels , Buchwald Stephen L.
Published: December 2014

This aminocarbonylation tolerates a broad variety of functional groups and different heteroaryl moieties giving aryl and heteroaryl amides in good to excellent yields, including compounds which are otherwise difficult to access.
ChemInform Abstract: Taming the Carboxyl Group for Directed Carbometalation: Observations on the Use of Anions, Dianions and Ester Enolates.
Authors: Desrat Sandy , Gray Philip J. , Penny Matthew R. , Motherwell William B.
Published: December 2014

The copper‐mediated directed metalation of allenic acid (I) and ester (XIV) is investigated to yield β,γ‐unsaturated products (III) and (XV) regioselectively.
ChemInform Abstract: DABCO‐Based Ionic Liquids: Recyclable Catalysts for Aza‐Michael Addition of α,β‐Unsaturated Amides under Solvent‐Free Conditions.
Authors: Ying Anguo , Li Zhifeng , Yang Jianguo , Liu Shuo , Xu Songlin , Yan Hua , Wu Chenglin
Published: December 2014

Four derivatives of the ionic liquid (anion: O‐Ac, O‐Tf, BF4, PF6) are prepared and the acetate is found to be the most efficient one.
ChemInform Abstract: Nucleophilic Addition/Double Cyclization Cascade Processes Between Enynyl Fischer Carbene Complexes and Alkynyl Malonates.
Authors: Alvarez‐Fernandez Ana , Suarez‐Rodriguez Tatiana , Suarez‐Sobrino Angel L.
Published: December 2014

The procedure leads to formation of different types of angular tricyclic systems in a regio‐ and stereoselective manner.
ChemInform Abstract: The Synthesis of α‐Azidoesters and Geminal Triazides.
Authors: Klahn Philipp , Erhardt Hellmuth , Kotthaus Andreas , Kirsch Stefan F.
Published: December 2014

Monoesters of type (I) and (III) are suitable substrates for the preparation of the α‐azidoesters, precursors of amino acids.
ChemInform Abstract: Palladium‐Catalyzed Double Substitution of 3‐Aryl‐2‐fluoroallyl Acetates with Phenols via C—F Bond Activation.
Authors: Nomada Eito , Watanabe Hirotaka , Yamamoto Mitsuaki , Udagawa Takumi , Zhou Biao , Kobayashi Akiko , Minakawa Maki , Kawatsura Motoi
Published: December 2014

Alkyl‐substituted 2‐fluoroallyl acetates do not provide the desired products.
ChemInform Abstract: Trading N and O. Part 2: Exploiting Aziridinium Intermediates for the Synthesis of β‐Hydroxy‐α‐Amino Acids.
Authors: Davies Stephen G. , Fletcher Ai M. , Frost Aileen B. , Roberts Paul M. , Thomson James E.
Published: December 2014

The β‐hydroxy‐α‐amino acids (S,S)‐allo‐threonine, (S,S)‐β‐hydroxyleucine and a range of aryl substituted (S,S)‐β‐hydroxyphenylalanines are prepared from the corresponding enantiopure anti‐α‐hydroxy‐β‐amino esters via a rearrangement protocol, which proceeds via the intermediacy of the corresponding aziridinium ions.
ChemInform Abstract: Energy‐Efficient Green Catalysis: Supported Gold Nanoparticle‐Catalyzed Aminolysis of Esters with Inert Tertiary Amines by C—O and C—N Bond Activations.
Authors: Bao Yong‐Sheng , Baiyin Menghe , Agula Bao , Jia Meilin , Zhaorigetu Bao
Published: December 2014

It is demonstrated for the first time, that Al2O3‐supported gold nanoparticles catalyze the aminolysis of activated aryl esters with inert tertiary amines to yield tertiary amides.
ChemInform Abstract: Hydrazone—Palladium‐Catalyzed Allylic Arylation of Cinnamyloxyphenylboronic Acid Pinacol Esters.
Authors: Watanabe Kohei , Mino Takashi , Abe Taichi , Kogure Taketo , Sakamoto Masami
Published: December 2014

The catalytic system is found to be optimal for the preparation of various 1,3‐diarylpropene derivatives bearing a phenolic hydroxyl group.
ChemInform Abstract: Greener Approach for the Synthesis of Substituted Alkenes by Direct Coupling of Alcohols with Styrenes Using Recyclable Broensted Acidic [NMP]+HSO4‐ Ionic Liquid
Authors: Wagh Kishor V. , Bhanage Bhalchandra M.
Published: December 2014

the ionic liquid, which acts both as a catalyst and solvent, is recyclable and reusable up to 5 times with only a slight decline in yield
ChemInform Abstract: Asymmetric Epoxidation of Olefins with Hydrogen Peroxide by an in situ‐Formed Manganese Complex.
Authors: Dai Wen , Shang Sensen , Chen Bo , Li Guosong , Wang Lianyue , Ren Lanhui , Gao Shuang
Published: December 2014

Ligands (I) and an acid additive are highly efficient in the process.
ChemInform Abstract: Ru‐Catalyzed Branched versus Linear Selective C3‐Alkylation of 2‐Aroylbenzofurans with Acrylates via C—H Activation.
Authors: Kommagalla Yadagiri , Srinivas Kolluru , Ramana Chepuri V.
Published: December 2014

The carbonyl‐directed C3—H activation and alkylation of benzo[b]furans with acrylates occurs selectively either in a linear or branched fashion, depending on the catalyst employed; [Ru(p‐cymene)Cl2]2 or Ru(PPh3)3Cl2, respectively.
ChemInform Abstract: An Efficient One‐Pot Three‐Component Synthesis and Antimicrobial Evaluation of Tetra Substituted Thiophene Derivatives.
Authors: Sable Pravinkumar N. , Ganguly Swastika , Chaudhari Pravin D.
Published: December 2014

The synthesized thiophene derivatives exhibit good to excellent activity against Gram‐negative microorganism (P.
ChemInform Abstract: Synthesis of Substituted 3‐Indolylimines and Indole‐3‐carboxaldehydes by Rhodium(II)‐Catalyzed Annulation.
Authors: Rajagopal Basker , Chou Chih‐Hung , Chung Ching‐Cheng , Lin Po‐Chiao
Published: December 2014

A Rh‐catalyzed denitrogenative annulation synthesis of 3‐indolylimines from sulfonyltriazoles is described.
ChemInform Abstract: Nano CuO‐Catalyzed C—H Functionalization of 1,3‐Azoles with Bromoarenes and Bromoalkenes.
Authors: Zhang Wu , Tian Yujie , Zhao Na , Wang Yuanyuan , Li Jia , Wang Zhenghua
Published: December 2014

Compound (Ia) does not react with phenylchloride instead of phenylbromide (II).
ChemInform Abstract: Investigation of Oxidopyrylium—Alkene [5 + 2] Cycloaddition Conjugate Addition Cascade (C3) Sequences.
Authors: Simanis Justin A. , Law C. Marshall , Woodall Erica L. , Hamaker Christopher G. , Goodell John R. , Mitchell T. Andrew
Published: December 2014

A series of bridged tetracyclic ethers is prepared with high diastereoselectivity via a novel oxidopyrylium—alkene cycloaddition—conjugate addition cascade reaction of readily accessible acetoxypyranone‐alkenes.
ChemInform Abstract: Substituted 3‐E‐Styryl‐2H‐chromenes and 3‐E‐Styryl‐2H‐thiochromenes: Synthesis, Photophysical Studies, Anticancer Activity, and Exploration to Tricyclic Benzopyran Skeleton.
Authors: Roy Rimi , Rakshit Soumyadipta , Bhowmik Tanmoy , Khan Sagar , Ghatak Avishek , Bhar Sanjay
Published: December 2014

Treatment of various cyclopropane‐containing substrates according to A) allows the access to the title compounds.
ChemInform Abstract: Pyridine‐Phosphinimine Ligand‐Accelerated Cu(I)‐Catalyzed Azide—Alkyne Cycloaddition for Preparation of 1‐(Pyridin‐2‐yl)‐1,2,3‐triazole Derivatives.
Authors: Sun Ranfeng , Wang Huangdong , Hu Jianfeng , Zhao Jiudong , Zhang Hao
Published: December 2014

A series of phosphinimine ligands is designed and applied in the Cu(I)‐catalyzed cycloaddition of tetrazolo[1,5‐a]pyridines (II) and alkynes (I).
ChemInform Abstract: Access to 1,2‐Dihydroisoquinolines Through Gold‐Catalyzed Formal [4 + 2] Cycloaddition.
Authors: Xin Zhuo , Kramer Soeren , Overgaard Jacob , Skrydstrup Troels
Published: December 2014

A new method to synthesize dihydroisoquinolines is reported which relies on a gold‐catalyzed formal [4 + 2] cycloaddition between ynamides and imines.
ChemInform Abstract: 1‐Aryl‐1,2,3,4‐tetrahydroisoquinolines as Potential Antimalarials: Synthesis, in vitro Antiplasmodial Activity and in silico Pharmacokinetics Evaluation.
Authors: Hanna Joelle Ngo , Ntie‐Kang Fidele , Kaiser Marcel , Brun Reto , Efange Simon M. N.
Published: December 2014

3‐Hydroxyphenethylamine derived from substrate (I) undergoes Pictet—Spengler reaction with a wide variety of aldehydes and cyclohexanone to form the title compounds (III) and (V).
ChemInform Abstract: A Cascade Alkylarylation Reaction of 2‐Isocyanobiphenyls with Simple Alkanes for 6‐Alkyl Phenanthridines via Dual C(sp3)—H/C(sp2)—H Functionalizations.
Authors: Zhu Zhi‐Qiang , Wang Tian‐Tian , Bai Peng , Huang Zhi‐Zhen
Published: December 2014

The synthetic method has the advantages of high yields and good functional group tolerance although very unreactive alkanes are applied in the reaction.
ChemInform Abstract: Exploration of Uracils: Pot and Step Economic Production of Pyridine Core Containing Templates by Multicomponent Aza‐Diels—Alder Reaction.
Authors: Sarmah Manas M. , Prajapati Dipak
Published: December 2014

Dienophiles generated in situ from aldehydes and acetophenones undergo aza‐Diels—Alder reaction with uracil derivative (I) followed by oxidative aromatization to give pyridopyrimidines.
ChemInform Abstract: Regioselective Alkylation Reactions of 2,4‐Diphenyl‐3H‐1‐benzazepine Give Either 3‐Alkyl‐3H‐1‐benzazepines or 1‐Alkyl‐1H‐1‐benzazepines.
Authors: Ko Allen , Lam Aaron , Li Jeffrey , Greer Edyta M. , Szalda David J. , Karimi Sasan , Subramaniam Gopal , Ramig Keith
Published: December 2014

Deprotonation of benzazepine (I) followed by reaction with alkyl halides or tosylates give either products of alkylation at C3 or at the nitrogen as well as mixtures of both types of products.
ChemInform Abstract: One‐Pot and Highly Regio‐Selective 1,3‐Dipole Cycloaddition of Azomethine Ylide Generated in situ to Tetraethyl Vinylidenebisphosphonate (VBP) Catalyzed by Cerium(IV) Oxide.
Authors: Li Guozhu , Wu Mingshu , Kong Dulin , Liu Rendie , Zhou Xueming , Liu Fengjiao
Published: December 2014

Azomethine ylides generated in situ from L‐proline (II) and aryl aldehydes (III) add regioselectively to VBP (I) to give the corresponding heterocyclic bisphosphonates (IV) as a mixture of diastereomers.
ChemInform Abstract: Absolute Configuration of Scopadulane Diterpenes from Calceolaria Species
Authors: Munoz Marcelo A. , Chamy Cristina , Bucio Maria A. , Hernandez‐Barragan Angelina , Joseph‐Nathan Pedro
Published: December 2014

determination of the absolute configuration of 13‐acetoxyscopadulane (I)
ChemInform Abstract: Ceriponol P, the First Example of Monocyclic Tremulane Sesquiterpene Produced by Ceriporia lacerate a Fungal Endophyte of Huperzia serrata.
Authors: Ying You‐Min , Tong Cui‐Ping , Wang Jian‐Wei , Shan Wei‐Guang , Zhan Zha‐Jun
Published: December 2014

isolation, structure elucidation, and biological evaluation
ChemInform Abstract: A New Stereoisomeric Acetogenic Glycoside from the Flower Buds of Buddleja officinalis.
Authors: Lee Chul , Hwang Kwang‐Woo , Park So‐Young
Published: December 2014

isolation, structure determination and hydrolysis of the new acetogenic glycoside (I)
ChemInform Abstract: Solvent Effects in the Nucleophilic Substitutions of Tetrahydropyran Acetals Promoted by Trimethylsilyl Trifluoromethanesulfonate: Trichloroethylene as Solvent for Stereoselective C‐ and O‐Glycosylations.
Authors: Kendale Joanna C. , Valentin Elizabeth M. , Woerpel K. A.
Published: December 2014

The stereochemical outcome of glycosylations of tetrahydropyran O‐acetals depends strongly on the solvent polarity.
ChemInform Abstract: Tuberostemonine O from the Roots of Stemona tuberosa
Authors: Kil Yun‐Seo , Han Ah‐Reum , Seo Eun Kyoung
Published: December 2014

isolation and structure elucidation of tuberostemonine O (I)
ChemInform Abstract: α‐ and β‐Lipomycin: Total Syntheses by Sequential Stille Couplings and Assignment of the Absolute Configuration of All Stereogenic Centers.
Authors: Hofferberth Max L. , Brueckner Reinhard
Published: December 2014

The absolute configurations of the polyenoyl chain stereocenters in α‐lipomycin (Ia) and its aglycon β‐lipomycin (Ib) are established by total synthesis.
ChemInform Abstract: Concise Total Synthesis of Honokiol via Kumada Cross Coupling.
Authors: Srinivas Jada , Singh Parvinder Pal , Varma Yogesh Kumar , Hyder Irfan , Kumar Halmuthur M. Sampath
Published: December 2014

The short synthesis of honokiol (VII) involves two Pd‐catalyzed Kumada coupling reactions as the key steps.
ChemInform Abstract: Low‐Temperature Sol—Gel Synthesis of Crystalline Materials
Authors: Vinogradov Alexandr V. , Vinogradov Vladimir V.
Published: December 2014

Review: 163 refs.
ChemInform Abstract: Studies on Icosahedral Ag—In—Yb: A Prototype for Tsai‐Type Quasicrystals
Authors: Cui Can , Shimoda Masahiko , Tsai An Pang
Published: December 2014

Review: 81 refs.
ChemInform Abstract: Structure and Spin Dynamics of Multiferroic BiFeO3
Authors: Park Je‐Geun , Le Manh Duc , Jeong Jaehong , Lee Sanghyun
Published: December 2014

Review: 190 refs.
ChemInform Abstract: Magnetic Properties of Perovskite Manganites and Their Modifications
Authors: Markovich V. , Wisniewski A. , Szymczak H.
Published: December 2014

Review: 635 refs.
ChemInform Abstract: [60]Fullerenyl Amino Acids and Peptides: A Review of their Synthesis and Applications
Authors: Jennepalli Sreenu , Pyne Stephen G. , Keller Paul A.
Published: December 2014

Review: [55 refs.
ChemInform Abstract: Substrate‐Selective Catalysis
Authors: Lindbaeck Emil , Dawaigher Sami , Waernmark Kenneth
Published: December 2014

Review: [129 refs.
ChemInform Abstract: Organometallic Approaches to Conjugated Polymers for Plastic Solar Cells: From Laboratory Synthesis to Industrial Production
Authors: Marzano Giuseppe , Ciasca Cosimo V. , Babudri Francesco , Bianchi Gabriele , Pellegrino Andrea , Po Riccardo , Farinola Gianluca M.
Published: December 2014

Review: [172 refs.
ChemInform Abstract: Recent Advances in Transition‐Metal‐Catalyzed C—CN Bond Activations
Authors: Wen Qiaodong , Lu Ping , Wang Yanguang
Published: December 2014

Review: [43 refs.
ChemInform Abstract: Recent Progress in the Chemistry of Endohedral Metallofullerenes
Authors: Lu Xing , Bao Lipiao , Akasaka Takeshi , Nagase Shigeru
Published: December 2014

Review: 81 refs.
ChemInform Abstract: Reaction Mechanisms: Radical and Radical Ion Reactions
Authors: Haidasz Evan A. , Li Bo , Pratt Derek A.
Published: December 2014

Review: 66 refs.
ChemInform Abstract: Recent Advances in the Use of Glycerol as Green Solvent for Synthetic Organic Chemistry
Authors: Diaz‐Alvarez Alba E. , Francos Javier , Croche Pascale , Cadierno Victorio
Published: December 2014

Review: 110 refs.
ChemInform Abstract: Challenges in the Large Scale Production of Peptides
Authors: Thundimadathil Jyothi
Published: December 2014

Review: 6 refs.
ChemInform Abstract: Unprecedented Aromatics: Metallapentalynes
Authors: Zheng QiYu
Published: December 2014

Review: 7 refs.
ChemInform Abstract: Total Synthesis and Structure‐Activity Relationship of Glycoglycerolipids from Marine Organisms
Authors: Zhang Jun , Li Chunxia , Yu Guangli , Guan Huashi
Published: December 2014

Review: 110 refs.
ChemInform Abstract: Recent Extensions to Native Chemical Ligation for the Chemical Synthesis of Peptides and Proteins
Authors: Malins Lara R. , Payne Richard J.
Published: December 2014

Review: 59 refs.
ChemInform Abstract: State of the Art in the Synthesis of Complex Natural Marine Peptides
Authors: Albericio Fernando , Alvarez Mercedes , Bruno Pablo , Canedo Librada , Cuevas Carmen , Francesch Andres , Garcia‐Ramos Yesica , Just Xavier , Martin Jesus , Munt Simon , et al. et al.
Published: December 2014

Review: 4 refs.
ChemInform Abstract: Recent Advances in the Synthesis of Heterocycles from Oximes
Authors: Abele Edgars , Abele Ramona
Published: December 2014

Review: 262 refs.
ChemInform Abstract: 4‐Oxothiazolidines with Exocyclic C=C Double Bond(s): Synthesis, Structure, Reactions and Biological Activity
Authors: Stojanovic Milovan , Dzambaski Zdravko , Bondzic Bojan , Aleksic Jovana , Baranac‐Stojanovic Marija
Published: December 2014

Review: 183 refs.
ChemInform Abstract: Synthetic Approaches to Dexmedetomidine (Review)
Authors: Bobosikova Maria , Mathia Frantisek , Vegh Daniel , Marchalin Stefan , Halinkovicova Michaela
Published: December 2014

Review: 11 refs.
ChemInform Abstract: Spin Fluctuation and Fermi Surface Instability in Ferromagnetic Superconductors
Authors: Aoki Dai , Gourgout Adrien , Pourret Alexandre , Bastien Gael , Knebel Georg , Flouquet Jacques
Published: December 2014

Review: emphasis on UGe2, URhGe and UCoGe; 45 refs.
ChemInform Abstract: Antibody—Drug Conjugates — A New Wave of Cancer Drugs
Authors: Bouchard Herve , Viskov Christian , Garcia‐Echeverria Carlos
Published: December 2014

Review: [21 refs.
ChemInform Abstract: Radiolabeled Bioactive Benzoheterocycles for Imaging β‐Amyloid Plaques in Alzheimer′s Disease
Authors: Yang Yanping , Cu Mengchao
Published: December 2014

Review: 122 refs.
ChemInform Abstract: Synthetic Derivatives of Aromatic Abietane Diterpenoids and Their Biological Activities
Authors: Gonzalez Miguel A.
Published: December 2014

Review: 87 refs.
ChemInform Abstract: Recent Advances in Porous Graphene Materials for Supercapacitor Applications
Authors: Zhang Xiong , Zhang Haitao , Li Chen , Wang Kai , Sun Xianzhong , Ma Yanwei
Published: December 2014

Review: 224 refs.
ChemInform Abstract: Application of Magnetic Nanoparticles for Magnetic Solid‐Phase Extraction in Preparing Biological, Environmental and Food Samples
Authors: Wierucka Marta , Biziuk Marek
Published: December 2014

Review: 88 refs.
ChemInform Abstract: The Extended Stability Range of Phosphorus Allotropes.
Authors: Bachhuber Frederik , von Appen Joerg , Dronskowski Richard , Schmidt Peer , Nilges Tom , Pfitzner Arno , Weihrich Richard
Published: December 2014

A complete stability range of known and new crystalline allotropes of phosphorus including recently discovered tubular modifications and not‐yet‐known crystal structures of [P12] nanorods, and not‐yet‐isolated [P14] nanorods is given using quantum chemical DFT calculations.
ChemInform Abstract: Electronic Structure, Chemical Bonding and Electrochemical Characterization of Li2CuSn2 and Li2AgSn2.
Authors: Schirmer Niels , Winter Florian , Matar Samir F. , Balducci Andrea , Poettgen Rainer
Published: December 2014

The title compounds are characterized by DFT electronic structure calculations and electrochemical measurements.
ChemInform Abstract: Ternary Bismuthides Li3REBi2 (RE: Ce, Pr, Sm, Gd) with Li3LaSb2‐Type Structure.
Authors: Winter Florian , Poettgen Rainer
Published: December 2014

The title compounds are prepared from the elements (Nb tubes, 1273 K for 6 h and 923 K for 72 h) and characterized by powder XRD.
ChemInform Abstract: An Oxysulfate Fe2O(SO4)2 Electrode for Sustainable Li‐Based Batteries.
Authors: Sun Meiling , Rousse Gwenaelle , Abakumov Artem M. , Van Tendeloo Gustaaf , Sougrati Moulay‐Tahar , Courty Matthieu , Doublet Marie‐Liesse , Tarascon Jean‐Marie
Published: December 2014

The title oxysulfate is synthesized by keeping FeSO4OH pellets (obtained by heating FeSO4·7H2O in air at 280 °C for 7 d) in air at 465 °C for 4 days.
ChemInform Abstract: Synthesis and Crystal Structure of InFeO3(ZnO)4.
Authors: v. Erichsen Svante Carl , Assenmacher Wilfried , Schnakenburg Gregor , Mader Werner
Published: December 2014

Polycrystalline InFeO3(ZnO)4 is obtained from a pelletized 1:1:8 mixture of In2O3, Fe2O3, and ZnO (Pt tubes, 1350 °C, 5 d).
ChemInform Abstract: Metal‐Centered Zintl Ions Isolated by Direct Extraction from Endohedral Intermetallic Precursor: [Co1‐x@Sn9]4‐ (x ≈ 0.32) and [Co2@Sn17]5‐.
Authors: He Haiyan , Klein Wilhelm , Jantke Laura‐Alice , Faessler Thomas F.
Published: December 2014

Single crystals of the new compounds K[K([2.2.2]crypt)]3[Co0.68@Sn9] (I) and [K([2.2.2]crypt)]5 [Co2@Sn17]·en·Tol (II) are prepared from solutions of K4.79Co0.79Sn9, and Kryptofix 222 in en and layered with toluene.
ChemInform Abstract: A 3‐D Framework Based on Mono‐CopperII Substituted Silicotungstate Units [Cu(dap)2(H2O)]2[Cu(dap)2] [α‐SiW11CuO39]·2H2O.
Authors: Luo Jie , Li Hailou , Chen Xinxin , Ma Jianru , Chen Lijuan , Zhao Junwei
Published: December 2014

The title compound (dap: 1,2‐diaminopropane) is hydrothermally synthesized from a mixture of Na10[A‐α‐SiW9O34], CuCl2, LaCl3, dap, and H2O (autoclave, 160 °C, 6 d, 33% yield).
ChemInform Abstract: La3Ir2 with Rhombohedral Er3Ni2‐Type Structure.
Authors: Schaefer Konrad , Poettgen Rainer
Published: December 2014

The title compound is synthesized by reaction of a 5:3 mixture of La and Ir (evacuated silica ampule, 1273 K, 96 h).
ChemInform Abstract: Highly Enantioselective Aza‐Henry Reaction with Isatin N‐Boc Ketimines.
Authors: Holmquist Melireth , Blay Gonzalo , Pedro Jose R.
Published: December 2014

The asymmetric aza‐Henry reaction of isatin N‐Boc‐ketimines (I) with nitromethane in the presence of a Cu‐Ph‐box complex leads to a series of N‐Boc‐protected nitroamines (III) with high enantioselectivity in most cases.
ChemInform Abstract: Another Role of Copper in the Simmons—Smith Reaction: Copper‐Catalyzed Nucleophilic Michael‐Type Cyclopropanation of α,β‐Unsaturated Ketones.
Authors: Fujii Kanami , Misaki Tomonori , Sugimura Takashi
Published: December 2014

Cyclopropanation of unsaturated ketones [(I), (IV), and (VI)] using the Furukawa procedure in the presence of Cu(OTf)2 leads to better product yields than Simmons—Smith conditions in some cases.
ChemInform Abstract: Reduction of Thiocarbonyl Compounds with Lithium Diisopropylamide.
Authors: Gebert Andreas , Jasinski Marcin , Mloston Grzegorz , Heimgartner Heinz
Published: December 2014

Reduction of 4,4‐disubstituted 1,3‐thiazole‐5(4H)‐1,3‐thiones and non‐enolizable thioketones to the corresponding thiols is achieved via an unexpected hydride transfer of LDA.
ChemInform Abstract: Nitrogen‐Centered Radical‐Mediated C—H Imidation of Arenes and Heteroarenes via Visible Light Induced Photocatalysis.
Authors: Kim Hyejin , Kim Taehoon , Lee Dong Gil , Roh Sang Weon , Lee Chulbom
Published: December 2014

The photocatalytic imidation of simple arenes and pyridines is reported.
ChemInform Abstract: Copper‐Catalyzed One‐Pot Trifluoromethylation/Aryl Migration/Carbonyl Formation with Homopropargylic Alcohols.
Authors: Liu Xue‐Yuan , et al. et al.
Published: December 2014

This reaction proceeds with high regioselectivity.
ChemInform Abstract: Novel Isoxazoline Ligand with Ferrocene Backbone: Preparation and Application in Heck Reaction with Water as Solvent.
Authors: Yu Shuyan , Zhang Zhiqin , Yu Zhiyu , Shang Yongjia
Published: December 2014

The developed catalytic system is even suitable for 1,2‐disubstituted alkenes [cf.
ChemInform Abstract: The Vicinal Functionalization of Olefins: A Facile Route to the Direct Synthesis of β‐Chlorohydrins and β‐Chloroethers.
Authors: Swamy Peraka , Kumar Macharla Arun , Reddy Marri Mahender , Naresh Mameda , Srujana Kodumuri , Narender Nama
Published: December 2014

1,4‐Naphthoquinone as well as strongly deactivated olefins such as β‐nitrostyrene or 1,3‐diphenylprop‐2‐en‐1‐one do not react to the corresponding β‐chlorohydrins.
ChemInform Abstract: Pd‐Catalyzed Tandem Homocoupling—Aldol—Dehydration of ortho‐Acylphenyl Iodides.
Authors: Fu Meiqin , Lin Dongen , Deng Yuanfu , Zhang Xiao‐Qi , Liu Yanchu , Lai Chunsong , Zeng Wei
Published: December 2014

The presented approach can be considered as Ullmann coupling‐aldol‐dehydration reaction.
ChemInform Abstract: A 2,6‐Bis(phenylamino)pyridinato Titanium Catalyst for the Highly Regioselective Hydroaminoalkylation of Styrenes and 1,3‐Butadienes.
Authors: Doerfler Jaika , Preuss Till , Schischko Alexandra , Schmidtmann Marc , Doye Sven
Published: December 2014

The reaction of various aromatic and aliphatic amines with styrene in the presence of TIC proceeds with high regioselectivity to give the desired linear products (nearly) exclusively.
ChemInform Abstract: Monohydrocyanation of Symmetrical Azines Using Potassium Hexacyanoferrate(II) as an Environmentally Friendly Cyanide Source.
Authors: Hu Xiaochun , Li Hongbo , Yang Jingya , Li Zheng
Published: December 2014

The monohydrocyanation of unsymmetrical aryl‐substituted azines yields two regioisomeric monohydrocyanation products in almost equal amounts.
ChemInform Abstract: Microwave Assisted, Ca(II)‐Catalyzed Ritter Reaction for the Green Synthesis of Amides.
Authors: Yaragorla Srinivasarao , Singh Garima , Lal Saini Pyare , Reddy M. Kesava
Published: December 2014

An efficient solvent‐free synthesis of various primary amides from alcohols and nitriles through Cu‐catalyzed Ritter reaction is presented.
ChemInform Abstract: Mild Gold‐Catalyzed Aerobic Dehydrogenative Coupling of Amines and Phenylglyoxal Derivatives.
Authors: Shao Ying , Wu Zhuhong , Miao Chunbao , Liu Li
Published: December 2014

The procedure can be applied to various arylglyoxals and some amines to afford the desired substructures with good to excellent yield.
ChemInform Abstract: Utilization of a Copper on Iron Catalyst for the Synthesis of Biaryl Systems and Benzoxazines via Oxidative Arylation of Anilide Derivatives.
Authors: Szekely Anna , Sinai Adam , Toth Edina B. , Novak Zoltan
Published: December 2014

The transformation of (VIa) with (mesityl)(4‐nitrophenyl)iodonium triflate does not afford the desired product.
ChemInform Abstract: A Green and Efficient Access to Aryl Nitriles via an Electrochemical Anodic Oxidation.
Authors: Ye Jia‐Qian , Zhang Zhen‐Lei , Zha Zheng‐Gen , Wang Zhi‐Yong
Published: December 2014

The new and efficient electrochemical synthesis of nitriles (II) (14 examples) is more environmentally friendly and easier to handle compared to conventional synthetic methods.
ChemInform Abstract: Sevelamer as an Efficient and Reusable Heterogeneous Catalyst for the Knoevenagel Reaction in Water.
Authors: Zhao Xian‐Liang , Yang Ke‐Fang , Zhang Yan‐Ping , Zhu Ju , Xu Li‐Wen
Published: December 2014

Sevelamer, a phosphate‐binding drug, is successfully used as catalyst in Knoevenagel reaction.
ChemInform Abstract: Iron‐Catalyzed Tetrasubstituted Alkene Formation from Alkynes and Sodium Sulfinates.
Authors: Liu Saiwen , Tang Lichang , Chen Hui , Zhao Feng , Deng Guo‐Jun
Published: December 2014

An iron‐catalyzed addition of aromatic sodium sulfinates to internal alkynes is developed.
ChemInform Abstract: Palladium/Sulfoxide—Phosphine‐Catalyzed Highly Enantioselective Allylic Etherification and Amination.
Authors: Feng Bin , Cheng Hong‐Gang , Chen Jia‐Rong , Deng Qiao‐Hui , Lu Liang‐Qiu , Xiao Wen‐Jing
Published: December 2014

The new catalyst system can be applied for the synthesis of allylic ethers and amines with high enantioselectivities.
ChemInform Abstract: The Baylis—Hillman Acetates in Organic Synthesis: Unprecedented Sodium Nitrite Induced Intramolecular Friedel—Crafts Cyclization of Secondary Nitro Compounds.
Authors: Basavaiah Deevi , Reddy Daggula Mallikarjuna
Published: December 2014

The presented facile protocol delivers naphthalenes, phenanthrenes, and carbazoles.
ChemInform Abstract: A Bioinspired Catalytic Oxygenase Cascade to Generate Complex Oxindoles.
Authors: Wang Yao , Bauer Jonathan O. , Strohmann Carsten , Kumar Kamal
Published: December 2014

Copper(I)‐catalyzed oxidation of the allylic methyl group of 3‐methylidene oxindoles and subsequent coupling with β‐oxo esters gives oxindole derivatives.
ChemInform Abstract: Photocatalytic Aerobic Oxidation/Semipinacol Rearrangement Sequence: A Concise Route to the Core of Pseudoindoxyl Alkaloids.
Authors: Ding Wei , Zhou Quan‐Quan , Xuan Jun , Li Tian‐Ren , Lu Liang‐Qiu , Xiao Wen‐Jing
Published: December 2014

A wide variety of indoles is converted into synthetically useful 2,2‐disubstituted indolin‐3‐ones through visible light induced photocatalyzed aerobic oxidation/semipinacol rearrangement.
ChemInform Abstract: Highly Efficient and Stereoselective Construction of Bispirooxindole Derivatives via a Three‐Component 1,3‐Dipolar Cycloaddition Reaction.
Authors: Xu Qin , Wang De , Wei Yin , Shi Min
Published: December 2014

The title reaction is investigated with isatins, various types of electron‐deficient alkenes derived from pyrrole structures and L‐proline.
ChemInform Abstract: Silver‐Mediated Radical Trifluoromethylarylation of Activated Alkenes for the Synthesis of Oxindoles Bearing a CF3 Group.
Authors: Wang Yao‐Feng , Qiu Jiashen , Kong Dejie , Chen Fu‐Xue
Published: December 2014

No reaction occurs with the N‐unprotected N‐phenylmethacrylamide, the non‐terminal alkene β‐methylacrylamide, esters and thioesters such as phenylmethacrylate and phenylthiomethacrylate.
ChemInform Abstract: Generation of Aryl(2‐lithiophenyl)methanone O‐Methyl Oximes and Their Use for the Synthesis of N‐(3‐Alkyl‐1‐aryl‐ or 1,3‐diaryl‐1H‐isoindol‐1‐yl)‐O‐methylhydroxylamines via the Reaction with Nitriles.
Authors: Kobayashi Kazuhiro , Matsumoto Kota , Shirai Yuu , Ishikawa Hiroaki , Inouchi Hiroki , Tanmatsu Miyuki
Published: December 2014

The title compounds (V) are efficiently obtained in a two‐step procedure starting from readily available aryl(2‐bromophenyl)methanones (I).
ChemInform Abstract: An Efficient Approach for the Synthesis of Spirooxindole Derivatives Catalyzed by Novel Sulfated Choline Based Heteropolyanion at Room Temperature.
Authors: Satasia Shailesh P. , Kalaria Piyush N. , Avalani Jemin R. , Raval Dipak K.
Published: December 2014

The catalyst can be recycled and reused at least 5 times with only a marginal decrease in yield.
ChemInform Abstract: Benzimidazoles as New Scaffold of Sirtuin Inhibitors: Green Synthesis, in vitro Studies, Molecular Docking Analysis and Evaluation of Their Anticancer Properties.
Authors: Yoon Yeong Keng , Ali Mohamed Ashraf , Wei Ang Chee , Shirazi Amir Nasrolahi , Parang Keykavous , Choon Tan Soo
Published: December 2014

New benzimidazole derivative (Ve) displays equipotent inhibitory activities for sirtuin‐1 as well as better inhibitory activities for sirtuin‐2 compared to standard controls cambinol and tenovin‐6.
ChemInform Abstract: Synthesis of 5‐Functionalized‐1,2,3‐triazoles via a One‐Pot Aerobic Oxidative Coupling Reaction of Alkynes and Azides.
Authors: Li Ling‐Jun , Zhang Yu‐Qin , Zhang Yang , Zhu An‐Lian , Zhang Gui‐Sheng
Published: December 2014

A simple, efficient and ligand free synthesis of 5‐functionalized‐1,2,3‐triazoles (III) is developed.
ChemInform Abstract: One‐Pot Sequential 1,4‐ and 1,2‐Reductions of α,β‐Unsaturated δ‐Lactones to the Corresponding δ‐Lactols with CuCl and NaBH4 in Methanol.
Authors: Matsumoto Yasunobu , Yonaga Masahiro
Published: December 2014

The 5‐ and 7‐membered ring analogues of (Ia) form the corresponding saturated lactones instead of the lactols.
ChemInform Abstract: Unprecedented Strong Lewis Bases‐Synthesis and Methyl Cation Affinities of Dimethylamino‐Substituted Terpyridines.
Authors: Hommes Paul , Fischer Christina , Lindner Christoph , Zipse Hendrik , Reissig Hans‐Ulrich
Published: December 2014

A convenient method for the synthesis of dimethylamino functionalized terpyridines by assembling of the terminal pyridine units using 2,6‐pyridinedicarboxylic acids as starting materials is presented.
ChemInform Abstract: Ruthenium‐Catalyzed ortho‐Selective Aromatic C—H Alkenylation with Alkenyl Carbonates.
Authors: Ogiwara Yohei , Kochi Takuya , Kakiuchi Fumitoshi
Published: December 2014

Title reaction of aromatic compounds [(I) and (IV)] gives regioselectively alkenylated products [(III) or (V), resp.], whereas, on using harsh refluxing conditions, the corresponding alkylation product, e.g. (VII), becomes the major product.
ChemInform Abstract: Synthetic and Mechanistic Aspects of the Regioselective Base‐Mediated Reaction of Perfluoroalkyl‐ and Perfluoroarylsilanes with Heterocyclic N‐Oxides.
Authors: Stephens David E. , Chavez Gabriel , Valdes Martin , Dovalina Monica , Arman Hadi D. , Larionov Oleg V.
Published: December 2014

The synthetic utility of a reaction of heterocyclic N‐oxides and perfluoroalkylsilanes that affords 2‐perfluoroalkyl/aryl‐substituted nitrogenous heterocycles in good to excellent yields is reported.
ChemInform Abstract: 9‐Alkylacridine Synthesis Using 2,2‐Dimethoxypropane as Water Scavenger.
Authors: Bratulescu George
Published: December 2014

The best results are obtained by using a (I)/(II)/Me2C(OMe)2/ZnCl2 = 1:1:2:2 ratio.
ChemInform Abstract: Broensted Acidic Ionic Liquid Catalyzed Tandem Reaction of 4‐Hydroxy‐1‐methyl‐2‐quinolone with Chalcone: Regioselective Synthesis of Pyrano[3,2‐c]quinolin‐2‐ones.
Authors: Bagdi Avik Kumar , Hajra Alakananda
Published: December 2014

A facile protocol using an acidic ionic liquid as the catalyst allows the synthesis of pyranoquinoline derivatives through tandem cyclization of substrate (I) with chalcones.
ChemInform Abstract: Synthesis of Annulated Heterocyclic Systems Based on 4‐CF3‐ or 4‐CHF2‐3‐cyano‐(1H)‐pyridine‐2‐thiones.
Authors: Rodinovskaya L. A. , Fedorov A. E. , Shestopalov A. M. , Belyakov P. A. , Nikishin K. G.
Published: December 2014

3‐Cyano‐4‐difluoro‐ and trifluoromethylpyridine‐2(1H)‐thiones are synthesized by a simple and convenient method and used for the synthesis of a number of annulated heterocyclic systems.
ChemInform Abstract: A Convenient Palladium‐Catalyzed Carbonylative Synthesis of 4(3H)‐Quinazolinones from 2‐Bromoformanilides and Organo Nitros with Mo(CO)6 as a Multiple Promoter.
Authors: He Lin , Sharif Muhammad , Neumann Helfried , Beller Matthias , Wu Xiao‐Feng
Published: December 2014

The reagent Mo(CO)6 acts not only as a CO source but also as a nitro compound reducing agent as well as a cyclization promoter.
ChemInform Abstract: Three‐Component Synthesis of 4‐Amino‐2‐aryl‐2H‐pyrimido‐[1,2‐b][1,3]benzazole‐3‐carbonitriles and 4H‐Pyrimido‐[2,1‐b][1,3]benzazoles in the Presence of Magnesium Oxide and 12‐Tungstophosphoric Acid as Catalysts.
Authors: Sheibani H. , Babaie M.
Published: December 2014

The title compounds are obtained by three‐component reactions of 2‐aminobenzimidazole or 2‐aminobenzothiazole (I) with aldehydes and malononitrile or β‐ketoesters using high surface area MgO as catalyst.
ChemInform Abstract: Novel Heterocyclization of 3‐(2‐Aminophenylamino)‐5,5‐dimethyl‐2‐cyclohexen‐1‐one.
Authors: Ukhin Lev Yu. , Orlova Zhanna I. , Suponitsky Kyrill Yu. , Shepelenko Eugenii N. , Belousova Lyudmila V.
Published: December 2014

furnishing a new type of phenazine derivative (III) containing a C‐conjugated phenolic substituent with space‐hindered fragments
ChemInform Abstract: An Efficient Approach to the Synthesis of Alkyl 7‐Hydroxy‐1‐oxo‐1,2,3,4‐ tetrahydropyrrolo[1,2‐a]pyrazine‐8‐carboxylates via a One‐Pot, Three‐Component Reaction.
Authors: Alizadeh Abdolali , Hossein Abadi Marziyeh , Ghanbaripour Rashid
Published: December 2014

No reaction occurs if o‐phenylenediamine instead of (I) is transformed.
ChemInform Abstract: Synthesis and Biological Evaluation of Papain‐Family Cathepsin L‐Like Cysteine Protease Inhibitors Containing a 1,4‐Benzodiazepine Scaffold as Antiprotozoal Agents.
Authors: Ettari Roberta , et al. et al.
Published: December 2014

In the course of optimization studies around previously developed papain‐family cathepsin L‐like cysteine protease inhibitors, the novel compounds (I)—(IV) are designed and synthesized.
ChemInform Abstract: Polycyclic N‐Heterocyclic Compounds. Part 80. Synthesis and Evaluation of Effects on in vitro Pentosidine Formation of 5,6‐Dihydro[1]benzothieno[3′,2′:2,3]thiepino[4,5‐d]pyrimidine and Related Compounds.
Authors: Okuda Kensuke , Itsuji Yutaka , Hirota Takashi , Sasaki Kenji
Published: December 2014

A series of title compounds are synthesized (< 45 examples).
ChemInform Abstract: Polycyclic N‐Heterocyclic Compounds. Part 82. Synthesis and Evaluation of anti‐Platelet Aggregation Activity of 2,4‐Disubstituted 5,6‐Dihydro[1]benzothiepino[5,4‐d]pyrimidine and Related Compounds.
Authors: Okuda Kensuke , Hirota Takashi , Sasaki Kenji
Published: December 2014

A large number of title compounds are synthesized (< 60 examples).
ChemInform Abstract: A Highly Modular One‐Pot Multicomponent Approach to Functionalized Benzo[b]phosphole Derivatives.
Authors: Wu Bin , Santra Mithun , Yoshikai Naohiko
Published: December 2014

Based on the coupling of an arylzinc reagent, an internal alkyne, and dichlorophenylphosphine a new synthesis of benz[b]phosphole derivatives is presented.
ChemInform Abstract: Total Synthesis of Taiwaniadducts B, C, and D.
Authors: Deng Jun , Zhou Shupeng , Zhang Wenhao , Li Jian , Li Ruofan , Li Ang
Published: December 2014

The first total syntheses of terpenoids taiwaniadducts B (I), C (II) and D (III) are described.
ChemInform Abstract: Synthesis of Marine Natural Product (‐)‐Pericosine E.
Authors: Mizuki Koji , Iwahashi Kaoru , Murata Naoko , Ikeda Mayuko , Nakai Yutaka , Yoneyama Hiroki , Harusawa Shinya , Usami Yoshihide
Published: December 2014

The first synthesis of (‐)‐pericosine E is described.
ChemInform Abstract: Spiroalkaloids and Coumarins from the Stem Bark of Pauridiantha callicarpoides.
Authors: Tatuedom Ostend K. , Kouam Simeon F. , Yapna Diane Beatrice , Ngadjui Bonaventure T. , Green Ivan R. , Choudhary M. Iqbal , Lantovololona Jeanne E. R. , Spiteller Michael
Published: December 2014

isolation and structure elucidation of a new spiroalkaloid, 7‐epi‐javaniside (I), along with seven known compounds
ChemInform Abstract: Amarusine A, a New Dioxaspiro[4.4]nonane Derivative with a Butyrolactone Ring from Pleioblastus amarus.
Authors: Sun Jia , Zhang Peicheng , Wei Qi , Xun Hang , Tang Feng , Yue Yongde , Li Li , Guo Xuefeng , Zhang Rong
Published: December 2014

The title compound shows good antioxidant activity and is able to scavenge the diphenyl picrylhydrazyl radical with an EC50 of 20.6 μg/ml.
ChemInform Abstract: Promoting 2D Growth in Colloidal Transition Metal Sulfide Semiconductor Nanostructures via Halide Ions.
Authors: Wu Wen‐Ya , Chakrabortty Sabyasachi , Chang Corina K. L. , Guchhait Asim , Lin Ming , Chan Yinthai
Published: December 2014

Halide ions play a decisive role in determining the morphology of Ni9S8 nanostructures, and the use of sufficiently large molar equivalents of halides results in the formation of nanoplates that exhibit an unusual cross‐like structure filled with steplike edges.
ChemInform Abstract: Enhancing Luminescence in Lanthanide‐Doped Upconversion Nanoparticles
Authors: Han Sanyang , Deng Renren , Xie Xiaoji , Liu Xiaogang
Published: December 2014

Review: [87 refs.
ChemInform Abstract: Controllable Fabrication of Nanostructured Materials for Photoelectrochemical Water Splitting via Atomic Layer Deposition
Authors: Wang Tuo , Luo Zhibin , Li Chengcheng , Gong Jinlong
Published: December 2014

Review: 54 refs.
ChemInform Abstract: Mesoporous Materials for Clean Energy Technologies
Authors: Linares Noemi , Silvestre‐Albero Ana M. , Serrano Elena , Silvestre‐Albero Joaquin , Garcia‐Martinez Javier
Published: December 2014

Review: 352 refs.
ChemInform Abstract: Some Important Features of Manganites
Authors: Singh R. J.
Published: December 2014

Review: 26 refs.
ChemInform Abstract: From Clusters to Unorthodox Pnictogen Sources: Solution‐Phase Reactivity of [E7]3‐ (E: P—Sb) Anions
Authors: Turbervill Robert S. P. , Goicoechea Jose M.
Published: December 2014

Review: 217 refs.
ChemInform Abstract: MgO/CoFeB/Ta/CoFeB/MgO Recording Structure with Low Intrinsic Critical Current and High Thermal Stability
Authors: Sato H. , Yamanouchi M. , Ikeda S. , Fukami S. , Matsukura F. , Ohno H.
Published: December 2014

Review: 36 refs.
ChemInform Abstract: Impact of Structural and Magnetic Anisotropies on Microwave Ferrites
Authors: Chen Yajie , Harris Vincent G.
Published: December 2014

Review: 29 refs.
ChemInform Abstract: Metal Complexes of Biological Active 2‐Aminothiazole Derived Ligands
Authors: Manju Manju , Joshi P. , Kumar D.
Published: December 2014

Review: synthesis, spectral, structural characterization and biological applications ometal complexes with thiazole‐derived ligands; 116 refs.
ChemInform Abstract: Coordination and Organometallic Compounds in the Functionalization of Carbon Nanotubes
Authors: Kharisov Boris I. , Kharissova Oxana V.
Published: December 2014

Review: 83 refs.
ChemInform Abstract: Electrochemical and Photochemical Routes to Semiconducting Transition Metal‐Tetracyanoquinodimethane Coordination Polymers
Authors: Nafady Ayman , O'Mullane Anthony P. , Bond Alan M.
Published: December 2014

Review: 105 refs.
ChemInform Abstract: Catalytic C—C Bond Forming Transformations via Direct β‐C—H Functionalization of Carbonyl Compounds
Authors: Huang Zhongxing , Dong Guangbin
Published: December 2014

Review: [60 refs.
ChemInform Abstract: Dehydration, Dehydrogenation, and Condensation of Alcohols on Supported Oxide Catalysts Based on Cyclic (WO3)3 and (MoO3)3 Clusters
Authors: Rousseau Roger , Dixon David A. , Kay Bruce D. , Dohnalek Zdenek
Published: December 2014

Review: 129 refs.
ChemInform Abstract: Review of Old Chemistry and New Catalytic Advances in the On‐Purpose Synthesis of Butadiene
Authors: Makshina Ekaterina V. , Dusselier Michiel , Janssens Wout , Degreve Jan , Jacobs Pierre A. , Sels Bert F.
Published: December 2014

Review: 246 refs.
ChemInform Abstract: Efficient anti‐Markovnikov‐Selective Catalysts for Intermolecular Alkyne Hydroamination: Recent Advances and Synthetic Applications
Authors: Yim Jacky C. ‐H. , Schafer Laurel L.
Published: December 2014

Review: [53 refs.
ChemInform Abstract: Heterogeneous Catalysis of CO2 Conversion to Methanol on Copper Surfaces
Authors: Behrens Malte
Published: December 2014

Review: 16 refs.
ChemInform Abstract: Recent Advances in the Production of Polyols from Lignocellulosic Biomass and Biomass‐Derived Compounds
Authors: Liu Xiaoran , Wang Xicheng , Yao Shengxi , Jiang Yijun , Guan Jing , Mu Xindong
Published: December 2014

Review: 136 refs.
ChemInform Abstract: Synthetic Applications of .Gamma.‐Hydroxybutenolides
Authors: Miles William H.
Published: December 2014

Review: 209 refs.
ChemInform Abstract: Binaphthyl Based Molecules for Asymmetric Organocatalytic Aldol Reactions: Recent Developments from a Successful Record
Authors: Almeida Ana R. , Neves Angela C. B. , Abreu Artur R. , Calvete Mario J. F. , Pereira Mariette M.
Published: December 2014

Review: 82 refs.