bluuebunny/crossref_metadata_2025 huggingface dataset:
Biphenylene: A Two−Dimensional Graphene−Based Coating with Superior Anti−Corrosion Performance
Authors: Ke Ke , Meng Kun , Rong Ju , Yu Xiaohua
Published: August 2022

Metal corrosion can potentially cause catastrophic engineering accidents threatening personal safety; thus, coating protection is a tremendously valuable anti-corrosion initiative. Recently, biphenylene, a novel two-dimensional (2D) graphene-based material, has achieved a remarkable synthetic breakthrough; the anti-corrosion properties of biphenylene, with its specific pore structure, are predicted to be beneficial in applications of metal corrosion resistance. In this study, the anti-corrosion mechanism of biphenylene is deciphered utilizing first principles and molecular dynamics. The results suggest that biphenylene with tetragonal, hexagonal, and octagonal carbon rings supplies adequate sites for stable O atom adsorption. The charge transfer amounts of +0.477 and +0.420 e facilitate the formation of a compact oxygen-rich layer on the material surface to acquire outstanding anti-corrosion properties. The moderate wettability of biphenylene prevents the water-based solution from encroaching on the biphenylene coating and substrate. In addition, the intensive binding between biphenylene and the aluminum substrate strengthens the integration of the two heterogeneous structures with −413.7 and 415.5 eV, which guarantees the durable application of biphenylene coating.
Microwave Absorption Properties of Multi-Walled Carbon Nanotubes/Carbonyl Iron Particles/Polyurethane Foams
Authors: Huang Xuegong , Yu Danping , Wang Simin
Published: August 2022

In order to improve the microwave absorption performance of absorbing materials, the composite foam absorbing materials with different multi-walled carbon nanotube (MWCNT) contents were prepared using polyurethane foam as the substrate and MWCNTs and flaked carbonyl iron powder as absorbers. The electromagnetic properties of the materials were characterized and analyzed. Then, CST electromagnetic simulation software was used to simulate the electromagnetic shielding effect of absorbing materials on mechatronics products under a strong electromagnetic irradiation environment, and, finally, it was verified by irradiation experiment. The results show that the materials have good microwave absorption properties, in which the composites containing 1.5 wt.% MWCNTs exhibit good microwave absorption properties. The minimum reflectivity reaches −29 dB when the thickness is 3 mm and −15.6 dB when the thickness is 1.5 mm, with a bandwidth of 5.7 GHz for reflectivity less than −10 dB. The good microwave absorption performance of the material is due to the synergistic effect of MWCNTs particles and good impedance matching. The simulation and experimental results show that the mechatronics product with absorbing materials can protect against strong electromagnetic interference and ensure the normal operation of the mechatronics product circuits.
Investigations on the Interaction Behavior between Direct Reduced Iron and Various Melts
Authors: Pfeiffer Andreas , Wimmer Gerald , Schenk Johannes
Published: August 2022

Since the European Union defined ambitious CO2 emission targets, low-carbon-emission alternatives to the widespread integrated blast furnace (BF)—basic oxygen furnace (BOF) steelmaking strategy—are demanded. Direct reduction (DR) with natural gas as the reducing agent, already an industrially applied technology, is such an alternative. Consequently, the melting behavior of its intermediate product, i.e., direct reduced iron (DRI), in either an electric arc furnace (EAF) or a submerged arc furnace (SAF), is of great interest. Based on the conditions in these aggregates, a test series to experimentally simulate the first few seconds after charging DRI was defined. DRI samples with different carbon contents and hot briquetted iron (HBI) were immersed in high- and low-carbon melts as well as high- and low-iron oxide slags. The reacted samples were quenched in liquid nitrogen. The specimens were qualitatively evaluated by investigating their surfaces and cross sections. The dissolution of carbon-free DRI progressed relatively slowly and was driven by heat transfer. However, carbon, present either in the DRI sample or in the melt, not only accelerated the dissolution process, but also reacted with residual iron oxide in the pellet or the slag.
Research on Linear Actuators for Active Foil Bearings
Authors: Breńkacz Łukasz , Kędra Rafał , Janicki Waldemar , Maurin Artur , Bagiński Paweł , Andrearczyk Artur , Zima Beata
Published: August 2022

Active foil bearings are a kind of gas foil bearing. They contain actuators which allow for modification of the bearing sleeve size and the shape of the lubrication gap. Rotor vibrations can be actively controlled by these changes. It is possible, among other things, to reduce the starting torque, control the vibration amplitude at different speeds and improve operational safety. Prototypes of active foil bearings are being developed based on different mechanical concepts. This paper provides an analysis of the linear mechanisms that are the base, and they are crucial for such developments. In the literature, there is a lack of characteristics of these actuators tested under real operating conditions of an active foil bearing. This article aims to fill this gap. New test rigs have been developed and used to precisely investigate the possibility of using actuators in active foil bearings. Since their geometry and control methods differ, the measurement systems have been adapted accordingly. The actuators studied were piezoelectrics, shape-memory alloys (SMAs) and stepper motors. Each of them was characterized by different operating characteristics. The results obtained allow for a comparison of the actuators. This approach is especially useful for the design and analysis of active foil bearings.
Optical Properties and Fluence Distribution in Rabbit Head Tissues at Selected Laser Wavelengths
Authors: Shanshool Alaa Sabeeh , Lazareva Ekaterina Nikolaevna , Hamdy Omnia , Tuchin Valery Victorovich
Published: August 2022

The accurate estimation of skin and skull optical properties over a wide wavelength range of laser radiation has great importance in optogenetics and other related applications. In the present work, using the Kubelka–Munk model, finite-element solution of the diffusion equation, inverse adding-doubling (IAD), and Monte-Carlo simulation, we estimated the refractive index, absorption and scattering coefficients, penetration depth, and the optical fluence distribution in rabbit head tissues ex vivo, after dividing the heads into three types of tissues with an average thickness of skin of 1.1 mm, skull of 1 mm, and brain of 3 mm. The total diffuse reflectance and transmittance were measured using a single integrating sphere optical setup for laser radiation of 532, 660, 785, and 980 nm. The calculated optical properties were then applied to the diffusion equation to compute the optical fluence rate distribution at the boundary of the samples using the finite element method. Monte-Carlo simulation was implemented for estimating the optical fluence distribution through a model containing the three tissue layers. The scattering coefficient decreased at longer wavelengths, leading to an increase in optical fluence inside the tissue samples, indicating a higher penetration depth, especially at 980 nm. In general, the obtained results show good agreement with relevant literature.
Simulation Research on Continuous Concrete Beams Reinforced with External Prestressed CFRP Tendons
Authors: Duan Ning , Zhang Ji-Wen , Cheng Jun
Published: August 2022

This paper examines the effects of different loading patterns on the static characteristics of continuous concrete beams reinforced with external prestressed carbon fiber-reinforced polymer tendons (EPCFRPT) and qualitatively analyzes the results for two continuous concrete beams: SB-1 under symmetrical loading, and SB-2 under asymmetrical loading. Then, a finite element analysis model is introduced and calibrated by tests conducted at Southeast University and data collected from a literature review. Based on the FEA model, the initial prestress, cross-section area, and eccentricity of CFRP tendons as well as the steel reinforcement configuration were selected by a parametric study. The results indicated that the initial prestress and tendon cross-section area had the most influence on the tendon stress increment and the secondary bending moment of the middle support, while the reinforcement distribution and eccentricity of the tendons had little effect. The secondary bending moment had a linear positive correlation with the stress increment of tendons. These results allow a simplified equation for calculating the external load bending moment amplitude coefficient at ultimate to be proposed.
Viscosity Deviation Modeling for Binary and Ternary Mixtures of Benzyl Alcohol-N-Hexanol-Water
Authors: Bîrgăuanu Iuliana , Danu Maricel , Lisa Cătălin , Leon Florin , Curteanu Silvia , Ibanescu Constanta , Lisa Gabriela
Published: August 2022

Knowing the thermodynamic and transport properties of liquid systems is very important in engineering for the development of theoretical models and for the design of new technologies. Models that allow accurate predictions of thermodynamic and transport properties are needed in chemical engineering calculations involving fluid, heat, and mass transfer. In this study, the modeling of viscosity deviation for binary and ternary systems containing benzyl alcohol, n-hexanol, and water, less studied in the literature, was carried out using Redlich and Kister (R-L) models, multiple linear regression (MLR) models and artificial neural networks (ANN). The viscosity of the binary and ternary systems was experimentally determined at the following temperatures: 293.15, 303.15, 313.15, and 323.15 K. Viscosity deviation was calculated and then correlated with mole fractions, normalized temperature, and refractive index. The neural model that led to the best performance in the testing and validation stages contains 4 neurons in the input layer, 12 neurons in the hidden layer, and one neuron in the output layer. In the testing stage for this model, the standard deviation is 0.0067, and the correlation coefficient is 0.999. In the validation stage, a deviation of 0.0226 and a correlation coefficient of 0.996 were obtained. The MLR model led to worse results than those obtained with the neural model and also with the R-L models. The standard deviation for this model is 0.099, and the correlation coefficient is 0.898. Its advantage over the R-L type models is that the influence of both composition and temperature are included in a single equation.
Toxicological Evaluation of Silver Nanoparticles Synthesized with Peel Extract of Stenocereus queretaroensis
Authors: Padilla-Camberos Eduardo , Juárez-Navarro Karen J. , Sanchez-Hernandez Ivan Moises , Torres-Gonzalez Omar Ricardo , Flores-Fernandez Jose Miguel
Published: August 2022

Silver nanoparticles (AgNPs) synthesized with plants are widely used in different industries, such as the medical, industrial, and food industries; however, their hazards and risks remain unclear. Here, we aimed to evaluate the toxicological effects of AgNPs in both in vitro and in vivo models. Previously, we developed and characterized green synthesized AgNPs based on Stenocereus queretaroensis (S. queretaroensis). The present study evaluates the toxicity of these AgNPs through cytotoxicity and mutagenicity tests in vitro, as well as genotoxicity tests, including the evaluation of acute oral, dermal, and inhalation toxicity, along with dermal and ocular irritation, in vivo, according to guidelines of The Organization for Economic Co-operation and Development (OECD). We evaluated cell cytotoxicity in L929 cells, and the half-maximal inhibitory concentration was 134.76 µg/mL. AgNPs did not cause genotoxic or mutagenic effects. Furthermore, in vivo oral, dermal, and acute inhalation toxicity results did not show any adverse effects or mortality in the test animals, and after the dermal and ocular irritation assessments, the in vivo models did not exhibit irritation or corrosion. Therefore, the results show that these previously synthesized S. queretaroensis AgNPs do not represent a risk at the tested concentrations; however, little is known about the effects that AgNPs induce on physiological systems or the possible risk following long-term exposure.
Influence of High-Pressure Die Casting Parameters on the Cooling Rate and the Structure of EN-AC 46000 Alloy
Authors: Kowalczyk Wojciech , Dańko Rafał , Górny Marcin , Kawalec Magdalena , Burbelko Andriy
Published: August 2022

The paper presents the results of the research on the impact of process parameters of high-pressure, cold-chamber die casting of an industrial casting made of aluminium alloy on the casting properties assessed macroscopically by measuring the casting average density and microscopically through the characteristics of the casting microstructure. The analysis covers the influence of three selected velocity settings of the pressing plunger, which determine the filling time, and three values of the compression pressure setting characteristic of the third phase of the casting process. The cooling and solidification simulations of the casting were performed using the ProCAST software. During the simulation tests, the impact of the filling rate of the alloy into the die cavity on the cooling rate and the alloy solidification path at selected points were determined. The conducted research allowed linking the process parameters with the parameters of the casting structure with different wall thicknesses. Metallographic examinations of the castings were carried out using a light microscopy, SEM, and EDS analysis. The fraction of the phases α(Al), the size of dendritic cells, and the size of silicon particles, in the cross-sections of the castings with wall thickness of 3, 6, and 11 mm, respectively, were determined.
First-Principles Study of Cu-Based Inorganic Hole Transport Materials for Solar Cell Applications
Authors: Pecoraro Adriana , Maddalena Pasqualino , Pavone Michele , Muñoz García Ana B.
Published: August 2022

Perovskite solar cells (PSCs) and dye-sensitized solar cells (DSCs) both represent promising strategies for the sustainable conversion of sunlight into electricity and fuels. However, a few flaws of current devices hinder the large-scale establishment of such technologies. On one hand, PSCs suffer from instabilities and undesired phenomena mostly linked to the perovskite/hole transport layer (HTL) interface. Most of the currently employed organic HTL (e.g., Spiro-OMeTAD) are supposed to contribute to the perovskite decomposition and to be responsible for charge recombination processes and polarization barriers. On the other hand, power conversion efficiencies (PCEs) of DSCs are still too low to compete with other conversion technologies. Tandem cells are built by assembling p-type and n-type DSCs in a cascade architecture and, since each dye absorbs on a different portion of the solar spectrum, the harvesting window is increased and the theoretical efficiency limit for a single chromophore (i.e., the Shockley–Queisser limit) is overcome. However, such a strategy is hindered by the lack of a p-type semiconductor with optimal photocathode features. Nickel oxide has been, by far, the first-choice inorganic p-type semiconductor for both PV technologies, but its toxicity and non-optimal features (e.g., too low open circuit voltage and the presence of trap states) call for alternatives. Herein, we study of three p-type semiconductors as possible alternative to NiO, namely CuI, CuSCN and Cu2O. To this aim, we compare the structural and electronic features of the three materials by means of a unified theoretical approach based on the state-of-the art density functional theory (DFT). We focus on the calculation of their valence band edge energies and compare such values with those of two widely employed photo-absorbers, i.e., methylammonium lead iodide (MAPI) and the triple cation MAFACsPbBrI in PSCs and P1 and Y123 dyes in DSCs, given that the band alignment and the energy offset are crucial for the charge transport at the interfaces and have direct implications on the final efficiency. We dissect the effect a copper vacancy (i.e., intrinsic p-type doping) on the alignment pattern and rationalize it from both a structural and an electronic perspective. Our data show how defects can represent a crucial degree of freedom to control the driving force for hole injection in these devices.
Bacterial Growth on Three Non-Resorbable Polytetrafluoroethylene (PTFE) Membranes—An In Vitro Study
Authors: Zelikman Helena , Slutzkey Gil , Rosner Ofir , Levartovsky Shifra , Matalon Shlomo , Beitlitum Ilan
Published: August 2022

GBR (Guided Bone Regeneration) procedure is challenged by the risk of membrane exposure to the oral cavity and contamination. The barrier quality of these membranes serve as a mechanical block from bacterial penetration into the GBR site. The purpose of this in vitro study was to evaluate the antibacterial effect of three commercial non-resorbable polytetrafluoroethylene membranes. (Two d-PTFE membranes and one double layer e-PTFE +d-PTFE membrane). A validated in vitro model with two bacterial species (Streptococcus sanguinis and Fusobacterium nucleatum) was used. Eight samples from membrane each were placed in a 96-well microtiter plate. The experimental and positive control groups were exposed to a bacterial suspension which involved one bacterial species in each plate. Bacterial growth was monitored spectrophotometrically at 650 nm for 24 h in temperature controlled microplate spectrophotometer under anaerobic conditions. One- Sample Kolmogorov–Smirnov Normal test and the Kruskal–Wallis test was used for the statistical analysis. As shown by the bacterial growth curves obtained from the spectrophotometer readings, all three membranes resulted in bacterial growth. We have not found a statistical difference in F. nucleatum growth between different membrane samples and the positive control group. However, S. sanguinis growth was reduced significantly in the presence of two membranes (CYTOPLAST TXT-200 and NeoGenTM) when compared to the control (p < 0.01). The presence of Permamem® had no significant influence on S. sanguinis growth. Some types of commercial non-resorbable PTFE membranes may have an impact on the growth dynamics of specific bacterial species.
Impact of WO3-Nanoparticles on Silicone Rubber for Radiation Protection Efficiency
Authors: Al-Ghamdi Hanan , Hemily Hanaa M. , Saleh I. H. , Ghataas Z. F. , Abdel-Halim A. A. , Sayyed M. I. , Yasmin Sabina , Almuqrin Aljawhara H. , Elsafi Mohamed
Published: August 2022

Silicone rubbers are a good choice for shielding materials because of having elastic and attenuating properties as well as cost-effectiveness. Thus, the aim of this study was to prepare ground-breaking silicone rubber samples by adding WO3-nanoparticles and testing the performance of their radiation shielding ability against Cs-137, Co-60, and Am-241 gamma energy. Increasing the concentration of WO3 nanoparticles in silicone rubber (SR) led to decreasing the half-value layer (HVL) and mean free path (MFP) values determined for the samples tested. Furthermore, the values of MFP and HVL upsurged according to the enhancement of the photon energy. It is noteworthy that the prepared silicone rubber (SR) systems with 50 and 60 wt% concentrations of WO3-nanoparticles displayed lower HVL than the Bi2O3-containing silicone rubber (SR) systems. In the same way, studied silicone rubber SR-W60 represented the lowest HVL comprising iron ore containing silicone rubber.
Uniaxial Compression Failure and Size Effect of Recycled Aggregate Concrete Based on Meso-Simulation Analysis
Authors: Zhuo Jingbo , Zhang Yamin , Ma Mei , Zhang Yu , Zheng Yuanxun
Published: August 2022

Recycled aggregate concrete (RAC) is a kind of five-phase composite material at the meso-level. It has a more complex interfacial transition zone (ITZ) than ordinary aggregate concrete (NAC), which is an important factor affecting the meso-failure of RAC. In addition, the maximum aggregate size plays an important role in the nonlinear mechanical behavior of concrete, which is closely related to the size effect. In this paper, a 2D random aggregate model of RAC is established based on meso-mechanics. The mechanical properties and failure modes of RAC under uniaxial compression are simulated using a plastic damage constitutive model. Through variable parameter analysis, the effects of the properties and thickness of ITZ on the elastic modulus and peak stress of RAC are studied, and the effect of the maximum aggregate size on the size effect of the compressive strength of RAC is discussed. The results show that the ITZ strength has a positive linear correlation with the peak stress and elastic modulus of RAC, while the ITZ thickness has a negative linear correlation with the peak stress and elastic modulus of RAC. Under the same specimen size (D = 100 mm, 150 mm, 200 mm, 300 mm), with an increase in the maximum aggregate size (dmax =20 mm, 25 mm, 30 mm, 35 mm), the nominal compressive strength of RAC increases by 6–10%, and the size effect is gradually weakened. When the maximum aggregate size reaches 30 mm, a decrease in the size effect tends to slow down compared with the maximum aggregate size of 20 mm. The classical Bažant size effect law is applicable to describe the compressive properties of RAC under different maximum aggregate sizes, and has a certain guiding significance for the prediction of the size effect of RAC in practical engineering.
Enhancing the Transferability of Adversarial Examples with Feature Transformation
Authors: Xu Hao-Qi , Hu Cong , Yin He-Feng
Published: August 2022

The transferability of adversarial examples allows the attacker to fool deep neural networks (DNNs) without knowing any information about the target models. The current input transformation-based method generates adversarial examples by transforming the image in the input space, which implicitly integrates a set of models by concatenating image transformation into the trained model. However, the input transformation-based methods ignore the manifold embedding and hardly extract intrinsic information from high-dimensional data. To this end, we propose a novel feature transformation-based method (FTM), which conducts feature transformation in the feature space. FTM can improve the robustness of adversarial example by transforming the features of data. Combining with FTM, the intrinsic features of adversarial examples are extracted to generate transferable adversarial examples. The experimental results on two benchmark datasets show that FTM could effectively improve the attack success rate (ASR) of the state-of-the-art (SOTA) methods. FTM improves the attack success rate of the Scale-Invariant Method on Inception_v3 from 62.6% to 75.1% on ImageNet, which is a large margin of 12.5%.
Improper Integrals Involving Powers of Inverse Trigonometric and Hyperbolic Functions
Authors: Li Chunli , Chu Wenchang
Published: August 2022

Three classes of improper integrals involving higher powers of arctanh, arctan, and arcsin are examined using the recursive approach. Numerous explicit formulae are established, which evaluate these integrals in terms of π, ln2, the Riemann zeta function, and the Dirichlet beta function.
Developing a Variable Speed Limit Control Strategy for Mixed Traffic Flow Based on Car-Following Collision Avoidance Theory
Authors: Yuan Chen , Shi Yuntao , Pan Bin , Li Ye
Published: August 2022

Variable speed limit (VSL) control is an effective technology to improve safety near freeway bottlenecks. This study aims to develop a control strategy for mixed traffic flow consisting of both human-driven vehicles (HDVs) and connected and automated vehicles (CAVs) based on collision avoidance theory. A microscopic simulation platform is first established, and four vehicle longitudinal dynamic models including Cruising model, Intelligent Driver Model (IDM), Adaptive Cruise Control model (ACC), Cooperative Cruise Control model (CACC) and one vehicle lateral dynamic model Minimizing Overall Braking Induced by Lane Changes model (MOBIL) are incorporated into the simulation platform. Then, a new VSL control strategy derived from collision avoidance theory is proposed for mixed traffic flow at the initial stage of CAVs’ popularization. Extensive simulation experiments are conducted, and surrogate safety measures and total travel time indicators are utilized to evaluate the safety and efficiency performances of the proposed VSL control. Results indicate that the proposed VSL control strategy can effectively improve the safety performance near freeway bottlenecks with an acceptable efficiency level.
Confidence Intervals Based on the Difference of Medians for Independent Log-Normal Distributions
Authors: Tian Weizhong , Yang Yaoting , Tong Tingting
Published: August 2022

In this paper, we study the inferences of the difference of medians for two independent log-normal distributions. These methods include traditional methods such as the parametric bootstrap approach, the normal approximation approach, the method of variance estimates recovery approach, and the generalized confidence interval approach. The simultaneous confidence intervals for the difference in the median for more than two independent log-normal distributions are also discussed. Our simulation studies evaluate the performances of the proposed confidence intervals in terms of coverage probabilities and average lengths. We find that the parametric bootstrap approach would be a suitable choice for smaller sample sizes for the two independent distributions and multiple independent distributions. However, the method of variance estimates recovery and normal approximation approaches are alternative competitors for constructing simultaneous confidence intervals, especially when the populations have large variance. We also include two practical applications demonstrating the use of the techniques on observed data, where one data set works for the PM2.5 mass concentrations in Bangkapi and Dindaeng in Thailand and the other data came from the study of nitrogen-bound bovine serum albumin produced by three groups of diabetic mice. Both applications show that the confidence intervals from the parametric bootstrap approach have the smallest length.
Immunosuppressive Cytochalasins from the Mangrove Endophytic Fungus Phomopsis asparagi DHS-48
Authors: Feng Zhao , Zhang Xuexia , Wu Jingwan , Wei Chengwen , Feng Ting , Zhou Dongdong , Wen Zhenchang , Xu Jing
Published: August 2022

Three new cytochalasins, phomoparagins A-C (1–3), along with five known analogs (4–8), were isolated from Phomopsis asparagi DHS-48, a mangrove-derived endophytic fungus. Their structures, including their absolute configurations, were elucidated using a combination of detailed HRESIMS, NMR, and ECD techniques. Notably, 1 possessed an unprecedented 5/6/5/8/5-fused pentacyclic skeleton. These compounds were tested for their inhibitory activity against concanavalin A (ConA)/lipopolysaccharide (LPS)-induced spleen lymphocyte proliferation and calcineurin (CN) enzyme. Several metabolites (2 and 4–6) exhibited fascinating inhibitory activities with a relatively low toxicity. Furthermore, 2 was demonstrated to inhibit ConA-stimulated activation of NFAT1 dephosphorylation and block NFAT1 translocation in vitro, subsequently inhibiting the transcription of interleukin-2 (IL-2). Our results provide evidence that 2 may, at least partially, suppress the activation of spleen lymphocytes via the CN/NFAT signaling pathway, highlighting that it could serve as an effective immunosuppressant that is noncytotoxic and natural.
Marine-Bioinspired Nanoparticles as Potential Drugs for Multiple Biological Roles
Authors: Jeong Geum-Jae , Khan Sohail , Tabassum Nazia , Khan Fazlurrahman , Kim Young-Mog
Published: August 2022

The increased interest in nanomedicine and its applicability for a wide range of biological functions demands the search for raw materials to create nanomaterials. Recent trends have focused on the use of green chemistry to synthesize metal and metal-oxide nanoparticles. Bioactive chemicals have been found in a variety of marine organisms, including invertebrates, marine mammals, fish, algae, plankton, fungi, and bacteria. These marine-derived active chemicals have been widely used for various biological properties. Marine-derived materials, either whole extracts or pure components, are employed in the synthesis of nanoparticles due to their ease of availability, low cost of production, biocompatibility, and low cytotoxicity toward eukaryotic cells. These marine-derived nanomaterials have been employed to treat infectious diseases caused by bacteria, fungi, and viruses as well as treat non-infectious diseases, such as tumors, cancer, inflammatory responses, and diabetes, and support wound healing. Furthermore, several polymeric materials derived from the marine, such as chitosan and alginate, are exploited as nanocarriers in drug delivery. Moreover, a variety of pure bioactive compounds have been loaded onto polymeric nanocarriers and employed to treat infectious and non-infectious diseases. The current review is focused on a thorough overview of nanoparticle synthesis and its biological applications made from their entire extracts or pure chemicals derived from marine sources.
Seawater Reverse Osmosis Performance Decline Caused by Short-Term Elevated Feed Water Temperature
Authors: Altmann Thomas , Buijs Paulus J. , Farinha Andreia S. F. , Borges Vitor R. Proença , Farhat Nadia M. , Vrouwenvelder Johannes S. , Das Ratul
Published: August 2022

The shortage of fresh water resources has made the desalination of seawater a widely adopted technology. Seawater reverse osmosis (SWRO) is the most commonly used method for desalination. The SWRO process is energy-intensive, and most of the energy in SWRO is spent on pressurizing the seawater to overcome the osmotic barrier for producing fresh water. The pressure needed depends on the salinity of the seawater, its temperature, and the membrane surface properties. Membrane compaction occurs in SWRO due to hydraulic pressure application for long-term operations and operating temperature fluctuations due to seasonal seawater changes. This study investigates the effects of short-term feed water temperature increase on the SWRO process in a full-scale pilot with pretreatment and a SWRO installation consisting of a pressure vessel which contains seven industrial-scale 8” diameter spiral wound membrane elements. A SWRO feed water temperature of 40 °C, even for a short period of 7 days, caused a permanent performance decline illustrated by a strong specific energy consumption increase of 7.5%. This study highlights the need for membrane manufacturer data that account for the water temperature effect on membrane performance over a broad temperature range. There is a need to develop new membranes that are more tolerant to temperature fluctuations.
Experimental Investigations on the Performance of a Hollow Fiber Membrane Evaporative Cooler (HFMEC) in Hot–Dry Regions
Authors: Li Nanfeng , Zhong Tao , Zhou Lu , Huang Simin , Zeng Si , Liang Caihang
Published: August 2022

The applicability of a hollow fiber membrane evaporative cooler in hot–dry regions was investigated by experimental studies. To better understand the actual operating environment of the hollow fiber membrane evaporative cooler, the outdoor air design conditions for summer air conditioning in five cities were simulated by an enthalpy difference laboratory. Subsequently, the effects of water and air flow rates on outlet air parameters and performance parameters were investigated by setting-up a hollow fiber membrane evaporative cooling experimental rig. It was found that the hollow fiber membrane evaporative cooler has good application prospects in hot–dry regions such as Lanzhou, Xi’an, Yinchuan, Urumqi, and Karamay. Among them, the hollow fiber membrane evaporative cooler has higher applicability in regions with higher air temperatures and lower humidity such as Urumqi and Karamay. The results indicate that the air outlet temperature and relative humidity ranged from 26.5 °C to 30.8 °C and 63.5% to 82.8%, respectively. The outlet air temperature and relative humidity of the HFMEC can meet the thermal comfort requirements of hot–dry regions in the summer at an appropriate air flow rate. The maximum air temperature drop, wet-bulb efficiency, cooling capacity, and COP were 7.5 °C, 62.9%, 396.4 W, and 4.81, respectively. In addition, the effect of the air flow rate on the performance parameters was more significant than that of the water flow rate.
Bubble-Enhanced Mixing Induced by Standing Surface Acoustic Waves (SSAWs) in Microchannel
Authors: Zhang Jingjing , Zheng Tengfei , Tang Lin , Qi Hui , Wu Xiaoyu , Zhu Linlong
Published: August 2022

BAW-based micromixers usually achieve mixing enhancement with acoustic-induced bubbles, while SAW-based micromixers usually enhance mixing efficiency by varying the configuration of IDTs and microchannels. In this paper, bubble-enhanced acoustic mixing induced by standing surface acoustic waves (SSAWs) in a microchannel is proposed and experimentally demonstrated. Significant enhancement in the mixing efficiency was achieved after the bubbles were stimulated in our acoustofluidic microdevice. With an applied voltage of 5 V, 50 times amplified, the proposed mixing microdevice could achieve 90.8% mixing efficiency within 60 s at a flow rate of 240 μL/h. The bubbles were generated from acoustic cavitation assisted by the temperature increase resulting from the viscous absorption of acoustic energy. Our results also suggest that a temperature increase is harmful to microfluidic devices and temperature monitoring. Regulation is essential, especially in chemical and biological applications.
Controlled Continuous Patterning of Spherical Stainless Steel by Multi-Axis Linkage Laser Milling
Authors: Li He , Zhang Junjie , Ma Wenqi , Liu Yuan , Zhao Xuesen , Hu Zhenjiang , Wang Xiaohui , Sheng Min , Sun Tao
Published: August 2022

While laser surface texturing is promising for the fabrication of planar surface microstructures, the continuously patterning with micrometer accuracy of non-planar surface on miniature parts with large curvature by laser ablation is challenging. In the present work, we demonstrate the feasibility of applying the proposed multi-axis laser milling in continuous patterning of 25 mm diameter spherical stainless steel with high uniformity and precision, based on a strategy of simultaneously adjusting the position and the posture of laser-surface interaction point for enabling the constant coincidence of laser beam with ablated surface normal. Specifically, a miniaturized five-axis platform for controlling workpiece motion with high degree-of-freedom is designed and integrated with a fixed nanosecond pulsed laser beam operating at 1064 nm. The precise path of laser-surface interaction point is derived based on the projection and transformation of pre-determined planar pattern on spherical surface. Meanwhile, a virtual prototype of the multi-axis laser milling with embedded interpolation algorithm is established, which enables the generation of NC codes for subsequent laser milling experiments. Furthermore, the sampling of laser processing parameters particularly for spherical surface is carried out. Finally, complex patterns are continuously structured on the spherical surface by employing the proposed multi-axis laser milling method, and subsequent characterization demonstrates both long range uniformity and local high accuracy of the fabricated patterns. Current work provides a feasible method for the continuous laser surface texturing of non-planar surfaces for miniature parts with large curvature.
Unconventional Rashba Spin-Orbit Coupling on the Charge Conductance and Spin Polarization of a Ferromagnetic/Insulator/Ferromagnetic Rashba Metal Junction
Authors: Jantayod Aek
Published: August 2022

A ferromagnetic/insulator/ferromagnetic Rashba metal junction (FM/I/FRM) with both Rashba spin–orbit coupling (RSOC) and exchange energy splitting was studied theoretically. Two kinds of interactions in FRM generate the three metallic states in a FRM; the Rashba ring metal (RRM) state, the anomalous Rashba metal (ARM) state and the normal Rashba metal (NRM) state. The scattering method and the free-electron model are used to describe the transport properties of particles and to calculate the conductance spectrum and the spin polarization of current in the junction. The conductance spectrum in the applied voltage shows the prominent features at the boundaries not only for the three states of the FRM but also in the ARM state. In addition, the conductance in the RRM and ARM states is strongly influenced by both the thickness and barrier height of the insulator layer. We also found that the spin polarization obtains a high value in the ARM state and is not affected by the qualities of the insulator, unlike the RRM and NRM states. Obtaining high-spin polarization from FRM material can be useful to produce spintronic devices in future devices.
Visualization and Heat Transfer Performance of Mini-Grooved Flat Heat Pipe Filled with Different Working Fluids
Authors: Xin Fei , Lyu Qiang , Tian Wenchao
Published: August 2022

Mini-grooved flat heat pipe (MGFHP) possesses the advantages of high compactness, no mechanical component, super thermal conductivity, and excellent temperature uniformity, which can meet the demand for electronic devices efficiently cooling. In this research, visual and heat transfer experiments were performed to investigate the flow and thermal characteristics inside the MGFHP. Fluid flow and distribution are observed to be quite different in the MGFHP containing different working fluids, which is affected by the physical properties of working fluid, the surface state of the grooved wick, and limited working space. Additionally, the input heat, working fluid type, filling ratio, and wettability obviously affect the thermal conductivity and temperature uniformity of the MGFHP. The deionized water-filled MGFHP possesses lower thermal resistance and higher heat transfer capacity than anhydrous ethanol or hexane filled MGFHP, especially for the copper oxide MGFHP filled with deionized water with a filling ratio of 1.0. Thermal resistance, maximum temperature, and temperature nonuniformity at the condensation section of deionized water-filled copper oxide MGFHP are lower than those of the original copper MGFHP by 31.1%, 3.7 °C, and 0.11 °C for the anhydrous ethanol filled MGFHP and 34.4%, 3.1 °C, and 0.13 °C for the hexane filled MGFHP, respectively.
A Novel Design Nomogram for Optimization of Micro Search Coil Magnetometer for Energy Monitoring in Smart Buildings
Authors: Tavakkoli Hadi , Song Kui , Zhao Xu , Duan Mingzheng , Lee Yi-Kuen
Published: August 2022

In this paper, a new analytical method to achieve the maximum signal-to-noise ratio (SNR) of a micro search coil magnetometer (µSCM) is presented. A planar spiral inductor was utilized to miniaturize conventional bulky search coil magnetometers. First, dimensional analysis was applied to identify three dimensionless parameters for the µSCM’s key performance indices (sensitivity (Se), noise, and SNR). The effect of the parameters on the µSCM’s performance was carefully investigated, and a novel 4D nomogram was developed. Furthermore, an SNR analysis considering noise sources of a low-noise amplifier was performed. By combining the results from the nomogram and the effect of the noise sources from the amplifier circuit, optimum values for the dimensionless parameters were calculated. According to the calculation results, the dominant noise source varied with an increase in the track width ratio to the outer diameter. Seven different samples were fabricated by a single-mask lithography process. The sensitivity of 1612 mV/mT was demonstrated at a 50 Hz input magnetic field, which was better than the previous µSCM (Se = 6.5 mV/mT) by more than 2 orders of magnitude. Finally, one of the fabricated µSCMs was employed to measure the online power consumption of a personal computer while different types of software were running.
Recyclization of Maleimides by Binucleophiles as a General Approach for Building Hydrogenated Heterocyclic Systems
Authors: Vandyshev Dmitriy Yu. , Shikhaliev Khidmet S.
Published: August 2022

The building of heterocyclic systems containing hydrogenated fragments is an important step towards the creation of biologically-active compounds with a wide spectrum of pharmacological activity. Among the numerous methods for creating such systems, a special place is occupied by processes using N-substituted maleimides as the initial substrate. This molecule easily reacts in Diels-Alder/retro-Diels-Alder reactions, Michael additions with various nucleophiles, and co-polymerization processes, as have been described in numerous detailed reviews. However, information on the use of maleimides in cascade heterocyclization reactions is currently limited. This study is devoted to a review and analysis of existing literature data on the processes of recyclization of N-substituted maleimides with various C,N-/N,N-/S,N-di- and polynucleophilic agents, such as amidines, guanidines, diamines, aliphatic ketazines, aminouracils, amino- and mercaptoazoles, aminothiourea, and thiocarbomoyl pyrazolines, among others. The significant structural diversity of the recyclization products described in this study illustrates the powerful potential of maleimides as a building block in the organic synthesis of biologically-active compounds with hydrogenated heterocyclic fragments.
Multiple Fingerprints and Spectrum-Effect Relationship of Polysaccharides from Saposhnikoviae Radix
Authors: Yu Mengqi , Xu Guang , Qin Ming , Li Yanling , Guo Yuying , Ma Qun
Published: August 2022

PMP-HPLC, FT-IR, and HPSEC fingerprints of 10 batches of polysaccharides from Saposhnikoviae Radix with different production areas and harvest times have been prepared, and the chemometrics analysis was performed. The anti-allergic activity of 10 batches of Saposhnikoviae Radix polysaccharide (SP) was evaluated, and the spectrum-effect relationship of the 10 batches of SP was analyzed by gray correlation degree with the chromatographic fingerprint as the independent variable. The results showed that the PMP-HPLC, HPSEC, and FT-IR fingerprints of 10 batches of SP had a high similarity. Two monosaccharides (rhamnose and galactose), the polysaccharide fragment Mn = 8.67 × 106~9.56 × 106 Da, and the FT-IR absorption peak of 892 cm−1 can be used as the quality control markers of SPs. All 10 batches of SP could significantly inhibit the release of β-HEX in RBL-231 cells, and the polysaccharides harvested from Inner Mongolia in the winter had the best anti-allergic activity. The spectrum-effect relationship model showed that the monosaccharide composition and molecular weight were related to the anti-allergic activity of the SPs. Multiple fingerprints combined with spectrum-effect relationship analysis can evaluate and control the quality of SPs from the aspects of overall quality and efficacy, which has more application value.
Two New Nonaborates with {B9} Cluster Open-Frameworks and Short Cutoff Edges
Authors: Chen Chong-An , Yang Guo-Yu
Published: August 2022

Two new nonaborates, Na2Ba0.5[B9O15]·H2O (1) and Na4Ca1.5[B9O16(OH)2] (2), have been solvothermally made with mixed alkali and alkaline-earth metal cationic templates. 1 and 2 are constructed by two different types of nonaborate clusters. In 1, the [B9O19]11− cluster is composed of three corner-sharing [B3O7]5− clusters, of which two of them interconnect to the 1D B3O7-based chains and are further bridged to the 3D framework with 7 types of 10-MR channels by another [B3O7]5− bridging cluster. The [B9O18(OH)2]11− cluster in 2 is made of four BO4-sharing [B3O8]7− clusters. As a 4-connected node, the interconnections of [B9O18(OH)2]11− construct the unpreceded 2D layer with large 14-MR windows, which are further joined by H-bonds to the 3D supramolecular framework. UV–Vis absorption spectra reveal that both 1 and 2 have short cutoff edges below 190 nm, exhibiting bandgaps of 6.31 and 6.39 eV, respectively, indicating their potential applications in deep UV (DUV) regions.
Hybrid Nanofluid Thermal Conductivity and Optimization: Original Approach and Background
Authors: Wohld Jake , Beck Joshua , Inman Kallie , Palmer Michael , Cummings Marcus , Fulmer Ryan , Vafaei Saeid
Published: August 2022

The focus of this paper was to develop a comprehensive nanofluid thermal conductivity model that can be applied to nanofluids with any number of distinct nanoparticles for a given base fluid, concentration, temperature, particle material, and particle diameter. For the first time, this model permits a direct analytical comparison between nanofluids with a different number of distinct nanoparticles. It was observed that the model’s average error was ~5.289% when compared with independent experimental data for hybrid nanofluids, which is lower than the average error of the best preexisting hybrid nanofluid model. Additionally, the effects of the operating temperature and nanoparticle concentration on the thermal conductivity and viscosity of nanofluids were investigated theoretically and experimentally. It was found that optimization of the operating conditions and characteristics of nanofluids is crucial to maximize the heat transfer coefficient in nanofluidics and microfluidics. Furthermore, the existing theoretical models to predict nanofluid thermal conductivity were discussed based on the main mechanisms of energy transfer, including Effective Medium Theory, Brownian motion, the nanolayer, aggregation, Molecular Dynamics simulations, and enhancement in hybrid nanofluids. The advantage and disadvantage of each model, as well as the level of accuracy of each model, were examined using independent experimental data.
Food Away from Home Frequency, Diet Quality, and Health: Cross-Sectional Analysis of NHANES Data 2011–2018
Authors: Nagao-Sato Sayaka , Reicks Marla
Published: August 2022

The consumption of meals prepared away from home (FAFH) in the U.S. has been commonly linked to overall poorer diet quality; however, less is known about the relationship with health parameters. The aim of this cross-sectional study was to assess the diet quality and health parameters of adults who reported the frequency of obtaining or eating FAFH using a combination of four 2-year cycles of National Health and Nutrition Examination Survey (NHANES, 2011–2018) data. Data from 14,999 adults aged 20 to 65 years were used to examine the associations between diet and health outcomes and the weekly frequency of FAFH. Multivariable regression models were used to compare Healthy Eating Index-2015 (HEI-2015) scores by FAFH frequency, adjusting for sociodemographic variables. Adults with more frequent FAFH meals were more likely to be younger, male, lower-income, and unmarried. Total HEI-2015 scores and component scores for greens and beans, total and whole fruits, whole grains, saturated fats, and added sugars were significantly lower in those consuming >2 FAFH meals/week vs. ≤2 FAFH meals/week. BMI and waist circumference tended to be higher for women having more frequent FAFH meals. More frequent FAFH meals among adults were associated with poorer diet quality and weight outcomes, building on results from earlier studies.
Comment on Huțanu et al. Low Serum Vitamin D in COVID-19 Patients Is Not Related to Inflammatory Markers and Patients’ Outcomes—A Single-Center Experience and a Brief Review of the Literature. Nutrients 2022, 14, 1998
Authors: Chambers Patrick
Published: August 2022

The article by Huțanu et al. [...]
Reply to Chambers, P. Comment on “Huțanu et al. Low Serum Vitamin D in COVID-19 Patients Is Not Related to Inflammatory Markers and Patients’ Outcomes—A Single-Center Experience and a Brief Review of the Literature. Nutrients 2022, 14, 1998”
Authors: Huțanu Adina , Georgescu Anca Meda , Voidăzan Septimiu , Andrejkovits Akos Vince , Negrea Valentina , Dobreanu Minodora
Published: August 2022

We thank Patrick Chambers for his interest [...]