bluuebunny/crossref_metadata_2025 huggingface dataset:
The reduction of chromate ions by Fe(II) layered hydroxides
Authors: Loyaux-Lawniczak S. , Refait Ph. , Lecomte P. , Ehrhardt J.-J. , Génin J.-M. R.
Published: April 2010

Abstract. The reduction of chromate ions by Fe(OH)2 and the iron (II)-iron (III) hydroxysulphate green rust, GR(SO42-), was studied to evaluate whether such synthetic layered hydroxides and the corresponding natural green rust mineral could be involved in the natural attenuation of contaminated environments. The resulting Cr (III) bearing phases, which would govern the subsequent behaviour of chromium, were clearly characterised. Both compounds proved to be very reactive and oxidised instantaneously while chromate ions were reduced to Cr (III) as evidenced by X-ray photoelectron spectroscopy. Mass balance (ICP-AES) demonstrated that the Fe/Cr ratio inside the solid end product was equal to the initial Fe/Cr ratio. The solid phases, analysed by X-ray diffraction, Raman and Mossbauer spectroscopies were identified as Cr-substituted poorly crystallised iron (III) oxyhydroxides in both cases, more precisely δ-FeOOH when starting with Fe(OH)2 and ferrihydrite when starting with GR(SO42-).
A coupled dual source GCM SVAT
Authors: Blyth E. M. , Harding R. J. , Essery R.
Published: April 2010

Abstract. The single source SVAT scheme (MOSES) used in the UK Meteorological Office GCM is modified to include two sources. The performances of the original and the new scheme are compared with minimal calibration against data from sparse vegetation taken from the HAPEX-Sahel experiment. Both schemes perform well; in particular the dual source SVAT successfully simulates the different temperatures of the sparse vegetation and soil. It is demonstrated that the two sources need to be coupled, rather than acting independently, for an accurate result. Some components of the single and dual source schemes are driven offline by measured surface temperature. In this case a dual source SVAT scheme performs significantly better than a single source scheme.
Comparative analysis of some methods for deriving the expected flood reduction curve in the frequency domain
Authors: Franchini M. , Galeati G.
Published: April 2010

Abstract. This article compares the results of three different models, namely empirical, geomorphoclimatic and stochastic, proposed in the literature for synthesising the reduction curve of average river discharges, of given frequency, over different durations. The analysis used observed reduction ratios inferred for twelve recording gauge stations with known rating curves, situated on central Italian watercourses all of which flow into the Adriatic sea. Particular emphasis was laid on the difficulties encountered in the parameterisation of the models, on the relations between the different formulations and on the existence of a link between the model parameters and the characteristic response times of the basins.
Longitudinal dispersion in natural channels: l. Experimental results from the River Severn, U.K.
Authors: Atkinson T. C. , Davis P. M.
Published: April 2010

Abstract. Abstract: A tracer experiment using Rhodamine WT dye was carried out to measure longitudinal dispersion in a 14-km reach of the River Severn in Wales, U.K. The river’s discharge was measured at six points and the depth, width and cross-sectional area were measured at 86 points along the test reach. The channel geometry was close to being statistically uniform. Discharge and velocity were both nearly constant. Dye concentrations were recorded at stations between 210 and 13775 m downstream of injection. Dye was injected over a short interval as a near-uniform line source across the channel. These conditions make the data useful for testing mathematical theories of dispersion. They are presented in full. Keywords: Channels; dispersion; tracers; River Severn
Spatial and temporal variations in the occurrence of low flow events in the UK
Authors: Young A. R. , Round C. E. , Gustard A.
Published: April 2010

Abstract. Information on the magnitude and variability of low river flows at the river reach scale is central to most aspects of water resource and water quality management. Within the UK, river stretches with permanent gauging stations represent less than one percent of the total number of river stretches mapped at a scale of 1:50,000 and fewer that 20% of gauged catchments can be regarded as having natural flow regimes. This has led to the development of simple, multivariate models for predicting average annual natural flow duration statistics through relationships with catchment characteristics. One assumption within these models is that low flows occur at the same time at all points within a catchment, irrespective of the hydrogeological nature and climatic condition of the catchment. This paper discusses the implications of spatial variations in the timing of low flow events for this type of model. Differences in the timing of the mean day of occurrence of the annual Q95 flow in UK catchments can be identified with low flows occurring earlier in the year within impermeable dry catchments and later in the year for wet permeable catchments. However, any differences in the mean day of occurrence between different catchments are generally masked by the magnitude of the inter-year variability in the day of occurrence. From analysis of linear combinations of flow statistics from nearest-neighbour gauged catchments, the paper demonstrates that the assumption of temporal coherence of low flows will generally result in an under-estimate of Q95; these underestimates are more significant for pairs of impermeable catchments than for combinations of permeable catchments and impermeable-permeable catchments.
Response of a first-order stream in Maine to short-term in-stream acidification
Authors: Norton S. A. , Wagai R. , Navratil T. , Kaste J. M. , Rissberger F. A.
Published: April 2010

Abstract. An experimental short-term acidification with HCl at a first-order stream in central Maine, USA was used to study processes controlling the changes in stream chemistry and to assess the ability of stream substrate to buffer pH. The streambed exerted a strong buffering capacity against pH change by ion exchange during the 6-hour acidification. Streambed substrates had substantial cation and anion exchange capacity in the pH range of 4.1 to 6.5. The ion exchange for cations and SO42- were rapid and reversible. The speed of release of cations from stream substrates was Na1+> Ca2+ > Mg2+ > Aln+ > Be2+, perhaps relating to charge density of these cations. Ca2+ desorption dominated neutralisation of excess H+ for the first 2 hr. As the reservoir of exchangeable Ca diminished, desorption (and possibly dissolution) of Al3+ became the dominant neutralising mechanism. The exchangeable (and possibly soluble) reservoir of Al was not depleted during the 6-hour acidification. Sulphate adsorption during the acidification reduced the concentration of SO42- in stream water by as much as 20 μeq L-1 (from 70 μeq L-1). Desorption of SO42- and adsorption of base cations after the artificial acidification resulted in a prolongation of the pH depression. The streambed had the capacity to buffer stream water chemistry significantly during an acidifying event affecting the entire upstream catchment. Keywords: stream acidification; ion exchange; sediment; sulfate exchange; aluminium; beryllium
Spatial-temporal rainfall fields: modelling and statistical aspects
Authors: Wheater H. S. , Isham V. S. , Cox D. R. , Chandler R. E. , Kakou A. , Northrop P. J. , Oh L. , Onof C. , Rodriguez-Iturbe I.
Published: April 2010

Abstract. The HYREX experiment has provided a data set unique in the UK, with a dense network of raingauges available for studying the rainfall at a fine local scale and a network of radar stations allowing detailed examination of the spatial and temporal structure of rainfall at larger scales. In this paper, the properties and characteristics of the rainfall process, as measured by the HYREX recording network of rainguages and radars, are studied from a statistical perspective. The results of these analyses are used to develop various models of the rainfall process, for use in hydrological applications. Some typical results of these various modelling exercises are presented. Keywords: Rainfall statistics, rainfall models, hydrological design
A geostatistical approach to multisensor rain field reconstruction and downscaling
Authors: Fiorucci P. , La Barbera P. , Lanza L.G. , Minciardi R.
Published: April 2010

Abstract. A rain field reconstruction and downscaling methodology is presented, which allows suitable integration of large scale rainfall information and rain-gauge measurements at the ground. The former data set is assumed to provide probabilistic indicators that are used to infer the parameters of the probability density function of the stochastic rain process at each pixel site. Rain-gauge measurements are assumed as the ground truth and used to constrain the reconstructed rain field to the associated point values. Downscaling is performed by assuming the a posteriori estimates of the rain figures at each grid cell as the a priori large-scale conditioning values for reconstruction of the rain field at finer scale. The case study of an intense rain event recently observed in northern Italy is presented and results are discussed with reference to the modelling capabilities of the proposed methodology. Keywords: Reconstruction, downscaling, remote sensing, geostatistics, Meteosat
Influence of parameter estimation uncertainty in Kriging: Part 1 - Theoretical Development
Authors: Todini E.
Published: April 2010

Abstract. This paper deals with a theoretical approach to assessing the effects of parameter estimation uncertainty both on Kriging estimates and on their estimated error variance. Although a comprehensive treatment of parameter estimation uncertainty is covered by full Bayesian Kriging at the cost of extensive numerical integration, the proposed approach has a wide field of application, given its relative simplicity. The approach is based upon a truncated Taylor expansion approximation and, within the limits of the proposed approximation, the conventional Kriging estimates are shown to be biased for all variograms, the bias depending upon the second order derivatives with respect to the parameters times the variance-covariance matrix of the parameter estimates. A new Maximum Likelihood (ML) estimator for semi-variogram parameters in ordinary Kriging, based upon the assumption of a multi-normal distribution of the Kriging cross-validation errors, is introduced as a mean for the estimation of the parameter variance-covariance matrix. Keywords: Kriging, maximum likelihood, parameter estimation, uncertainty
Influence of parameter estimation uncertainty in Kriging: Part 2 - Test and case study applications
Authors: Todini E. , Pellegrini F. , Mazzetti C.
Published: April 2010

Abstract. The theoretical approach introduced in Part 1 is applied to a numerical example and to the case of yearly average precipitation estimation over the Veneto Region in Italy. The proposed methodology was used to assess the effects of parameter estimation uncertainty on Kriging estimates and on their estimated error variance. The Maximum Likelihood (ML) estimator proposed in Part 1, was applied to the zero mean deviations from yearly average precipitation over the Veneto Region in Italy, obtained after the elimination of a non-linear drift with elevation. Three different semi-variogram models were used, namely the exponential, the Gaussian and the modified spherical, and the relevant biases as well as the increases in variance have been assessed. A numerical example was also conducted to demonstrate how the procedure leads to unbiased estimates of the random functions. One hundred sets of 82 observations were generated by means of the exponential model on the basis of the parameter values identified for the Veneto Region rainfall problem and taken as characterising the true underlining process. The values of parameter and the consequent cross-validation errors, were estimated from each sample. The cross-validation errors were first computed in the classical way and then corrected with the procedure derived in Part 1. Both sets, original and corrected, were then tested, by means of the Likelihood ratio test, against the null hypothesis of deriving from a zero mean process with unknown covariance. The results of the experiment clearly show the effectiveness of the proposed approach. Keywords: yearly rainfall, maximum likelihood, Kriging, parameter estimation uncertainty
Trends in nitrogen deposition and leaching in acid-sensitive streams in Europe
Authors: Wright R. F. , Alewell C. , Cullen J. M. , Evans C. D. , Marchetto A. , Moldan F. , Prechtel A. , Rogora M.
Published: April 2010

Abstract. Long-term records of nitrogen in deposition and streamwater were analysed at 30 sites covering major acid sensitive regions in Europe. Large regions of Europe have received high inputs of inorganic nitrogen for the past 20 - 30 years, with an approximate 20% decline in central and northern Europe during the late 1990s. Nitrate concentrations in streamwaters are related to the amount of N deposition. All sites with less than 10 kgN ha-1 yr-1 deposition have low concentrations of nitrate in streamwater, whereas all sites receiving > 25 kgN ha-1 yr-1 have elevated concentrations. Very few of the sites exhibit significant trends in nitrate concentrations; similar analyses on other datasets also show few significant trends. Nitrogen saturation is thus a process requiring many decades, at least at levels of N deposition typical for Europe. Declines in nitrate concentrations at a few sites may reflect recent declines in N deposition. The overall lack of significant trends in nitrate concentrations in streams in Europe may be the result of two opposing factors. Continued high deposition of nitrogen (above the 10 kgN ha-1 yr-1 threshold) should tend to increase N saturation and give increased nitrate concentrations in run-off, whereas the decline in N deposition over the past 5 – 10 years in large parts of Europe should give decreased nitrate concentrations in run-off. Short and long-term variations in climate affect nitrate concentrations in streamwater and, thus, contribute "noise" which masks long-term trends. Empirical data for geographic pattern and long-term trends in response of surface waters to changes in N deposition set the premises for predicting future contributions of nitrate to acidification of soils and surface waters. Quantification of processes governing nitrogen retention and loss in semi-natural terrestrial ecosystems is a scientific challenge of increasing importance. Keywords: Europe, acid deposition, nitrogen, saturation, recovery, water
Recovery from acidification of lakes in Finland, Norway and Sweden 1990–1999
Authors: Skjelkvåle B. L. , Mannio J. , Wilander A. , Andersen T.
Published: April 2010

Abstract. Sulphate deposition has decreased by about 60% in the Nordic countries since the early 1980s. Nitrogen deposition has been roughly constant during the past 20 years, with only a minor decrease in the late 1990s. The resulting changes in the chemistry of small lakes have been followed by national monitoring programmes initiated in the 1980s in Finland (163 lakes), Norway (100 lakes) and Sweden (81 lakes). These lakes are partly a subset from the survey of 5690 lakes in the Northern European lake survey of 1995. Trend analyses on data for the period 1990-1999 show that the non-marine sulphate concentrations in lakes have decreased significantly in 69% of the monitored lakes. Changes were largest in lakes with the highest mean concentrations. Nitrate concentrations, on the other hand, were generally low and showed no systematic changes. Concentrations of non-marine base cations decreased in 26% of the lakes, most probably an ionic-strength effect due to the lower concentrations of mobile strong-acid anions. Acid neutralising capacity increased in 32% of the lakes. Trends in recovery were in part masked by large year-to-year variations in sea-salt inputs and by increases in total organic carbon concentrations. These changes were most probably the result of climatic variations. Nordic lakes, therefore, show clear signs of recovery from acidification. Recovery began in the 1980s and accelerated in the 1990s. Reductions in sulphur deposition are the major "driving force" in the process of recovery from acidification. Further recovery can be expected in the next 10 years if the Gothenburg protocol on emissions of acidifying pollutants is implemented. Keywords: Nordic countries, sulphur deposition, lakes, recovery
Chemical trends at lakes and streams in the UK Acid Waters Monitoring Network, 1988-2000: Evidence for recent recovery at a national scale
Authors: Evans C. D. , Monteith D. T.
Published: April 2010

Abstract. A detailed trend analysis of 12 years of data (1988-2000) for 22 surface waters in acid-sensitive regions of the United Kingdom, in which individual site data have been combined to identify national-scale trends, has shown strong common patterns of temporal variation. Results suggest a widespread reduction in sulphate concentrations, hydrogen ion and inorganic aluminium species, and increases in acid neutralising capacity. Many chemical changes have not been linear. However, the first five years were characterised by high concentrations of marine ions and relatively stable pollutant sulphate concentrations and the remaining period by lower concentrations of marine ions and declining sulphate. Genuine "recovery", in terms of declining acidity in response to reduced anthropogenic sulphur deposition is only apparent, therefore, for the latter part of the monitoring period. Reductions in calcium concentrations appear to have partially offset the influence of sulphate reductions on acidity, as have increases in organic acidity associated with strong and widespread rising trends in dissolved organic carbon. Fluctuations in a number of climatic factors over the monitoring period have led to significant inter-annual variability in nitrate, which exhibits little long-term trend, marine ions and acidity, emphasising the need for long monitoring periods if underlying trends are to be correctly identified. Keywords: acidification, recovery, long-term trends, climate, Dissolved Organic Carbon, United Kingdom Acid Waters Monitoring Network
Interpretation of trends in acidic deposition and surface water chemistry in Scotland during the past three decades
Authors: Harriman R. , Watt A. W. , Christie A. E. G. , Collen P. , Moore D. W. , McCartney A. G. , Taylor E. M. , Watson J.
Published: April 2010

Abstract. Trends in major ionic components of bulk precipitation were analysed for two sites, Faskally and Loch Ard forest in Scotland, for the period 1972-2000. The pattern of change was not linear. Large reductions in sulphur deposition occurred in the early 1980s and, to a lesser extent, during 1995-2000, with a period of relative stability between 1988-95. pH increased significantly at both sites but nitrate and ammonia only increased significantly at Loch Ard forest. Long-term chemical data from a total of 37 streams and lochs in four selected regions of Scotland were analysed over three time periods (all available data (mostly 1978-2000), 1988-98 and 1995-2000) to match the deposition patterns. For the whole study period a significant decline in non-marine sulphate was found at all sites while the most consistent increases in pH and alkalinity were recorded at all the high elevation loch sites in the Galloway area. Significant reductions in toxic forms of aluminium were also recorded, mostly at sites where pH had increased. Nitrate trends were equivocal except for catchments with clear-felling operations. For these sites, negative trends were found where felling occurred in the 1980s, while positive trends were found at sites with felling in the 1990s. With the exception of one site, dissolved organic carbon concentrations increased significantly with moorland sites showing smaller increases than forested sites. Associated with this change was a significant increase in complexed forms of aluminium. Trends for the 1988-98 period were much smaller than those for the whole study period and in many cases were insignificant. This contrasts with the 1995-2000 period when large and significant reductions in sulphate and nitrate were recorded along with increases in marine salts, probably as a result of climatically related events. Qualitative, experimental and monitoring data from lochs in the Galloway area revealed evidence of recovery of fish populations. Interpretation of chemical and biological trends was clearly influenced by the choice of the time series, especially in relation to deposition and climatic changes. Nevertheless, all the fresh waters included in this study are currently in the best ecological condition since the 1970s in the context of recovery from acidification. Keywords: deposition, trends, acidification, forestry, recovery, fish, climate
Seasonality, water quality trends and biological responses in four streams in the Cairngorm Mountains, Scotland
Authors: Soulsby C. , Malcolm R. , Gibbins C. , Dilks C.
Published: April 2010

Abstract. The chemical composition and invertebrate communities found in four streams in the Cairngorms, Scotland, were monitored between 1985-1997. Stream waters were mildly acidic (mean pH ca. 6.5), with low alkalinity (mean acid neutralising capacity varying from 35-117 meq l-1) and low ionic strength. Subtle differences in the chemistry of each stream were reflected in their invertebrate faunas. Strong seasonality in water chemistry occurred, with the most acid, low alkalinity waters observed during the winter and early spring. This was particularly marked during snowmelt between January and April. In contrast, summer flows were usually groundwater dominated and characterised by higher alkalinity and higher concentrations of most other weathering-derived solutes. Seasonality was also clear in the invertebrate data, with Canonical Correspondence Analysis (CCA) separating seasonal samples along axes related to water temperature and discharge characteristics. Inter-annual hydrological and chemical differences were marked, particularly with respect to the winter period. Invertebrate communities found in each of the streams also varied from year to year, with spring communities significantly more variable (P<0.01) than other seasons (quantified using Euclidean distance on CCA ordinations). Hydrochemical trends over the study period were analysed using a seasonal Kendall test, LOcally WEighted Scatterplot Smoothing (LOWESS) and graphical techniques. These indicated that a reduction in sulphate concentrations in stream water is occurring, consistent with declining levels of atmospheric deposition. This may be matched by increases in pH and declining calcium concentrations, though available evidence is inconclusive. Other parameters, such as chloride, total organic carbon and zinc, reveal somewhat random patterns, probably reflecting irregular variations in climatic factors and/or atmospheric deposition. Previous studies have shown that the stream invertebrate communities have remained stable over this period (i.e. no significant linear trends) and show no evidence of acid-related impoverishment. Thus, over longer timescales invertebrates in these streams appear robust to the short-term (seasonal and inter-annual) environmental variability and long-term (decadal) chemical changes identified. Keywords: hydrochemistry, hydrology, trends, macroinvertebrates, uplands, Cairngorms, acidification
Land use influences on acidification and recovery of freshwaters in Galloway, south-west Scotland
Authors: Helliwell R. C. , Ferrier R. C. , Johnston L. , Goodwin J. , Doughty R.
Published: April 2010

Abstract. The long term response of surface waters to changes in sulphur deposition and afforestation is investigated for three upland river systems in the Galloway region of south-west Scotland. From 1984-1999, these rivers exhibited a statistically significant decline in non-marine sulphate concentrations in response to reduced acid deposition. This reduction in non-marine sulphate was, however, insufficient to induce a pH recovery over the period. A statistically significant increase in river pH was observed between 1956-1970 (0.05 yr-1) when subsidised agricultural lime payments were at a maximum. In 1976, this subsidy ceased and surface waters have progressively acidified. In addition, climatic change is found to influence long-term trends in pH. Mean annual pH was greatest during a dry period between 1969-1973 when total annual discharge was low. Thereafter, pH declined gradually in response to higher rainfall and increased total annual discharge. Overall, surface waters draining the afforested catchments of the Rivers Cree and Bladnoch are more acid than those draining the moorland catchment of the Luce. These results indicate that in afforested catchments, current reductions in sulphur emissions have not led to an observed improvement in the acid status of surface waters. Forestry, therefore, represents a confounding factor with regard to chemical recovery from acidification in this region. Keywords: acidification, afforestation, deposition, rivers, lochs, non-marine sulphate, pH
Modelling the effects of acid deposition: refinements, adjustments and inclusion of nitrogen dynamics in the MAGIC model
Authors: Cosby B. J. , Ferrier R. C. , Jenkins A. , Wright R. F.
Published: April 2010

Abstract. The MAGIC model of the responses of catchments to acidic deposition has been applied and tested extensively over a 15 year period at many sites and in many regions around the world. Overall, the model has proven to be robust, reliable and useful in a variety of scientific and managerial activities. Over the years, several refinements and additions to MAGIC have been proposed and/or implemented for particular applications. These adjustments to the model structure have all been included in a new version of the model (MAGIC7). The log aluminium – pH relationship now does not have to be fixed to aluminium trihydroxide solubility. Buffering by organic acids using a triprotic analog is now included. Dynamics of nitrogen retention and loss in catchments can now be linked to soil nitrogen and carbon pools. Simulation of short-term episodic response by mixing fractions of different water types is also possible. This paper presents a review of the conceptual structure of MAGIC7 relating to long-term simulation of acidification and recovery, describes the conceptual basis of the new nitrogen dynamics and provides a comprehensive update of the equations, variables, parameters and inputs for the model. Keywords: process-based model, acid deposition, recovery
The HYDROMED model and its application to semi-arid Mediterranean catchments with hill reservoirs 3: Reservoir storage capacity and probability of failure model
Authors: Ragab R. , Austin B. , Moidinis D.
Published: April 2010

Abstract. This paper addresses the issue of "what reservoir storage capacity is required to maintain a yield with a given probability of failure?". It is an important issue in terms of construction and cost. HYDROMED offers a solution based on the modified Gould probability matrix method. This method has the advantage of sampling all years data without reference to the sequence and is therefore particularly suitable for catchments with patchy data. In the HYDROMED model, the probability of failure is calculated on a monthly basis. The model has been applied to the El-Gouazine catchment in Tunisia using a long rainfall record from Kairouan together with the estimated Hortonian runoff, class A pan evaporation data and estimated abstraction data. Generally, the probability of failure differed from winter to summer. Generally, the probability of failure approaches zero when the reservoir capacity is 500,000 m3. The 25% probability of failure (75% success) is achieved with a reservoir capacity of 58,000 m3 in June and 95,000 m3 in January. The probability of failure for a 240,000 m3 capacity reservoir (closer to storage capacity of El-Gouazine 233,000 m3), is approximately 5% in November, December and January, 3% in March, and 1.1% in May and June. Consequently there is no high risk of El-Gouazine being unable to meet its requirements at a capacity of 233,000 m3. Subsequently the benefit, in terms of probability of failure, by increasing the reservoir volume of El-Gouazine to greater than the 250,000 m3 is not high. This is important for the design engineers and the funding organizations. However, the analysis is based on the existing water abstraction policy, absence of siltation rate data and on the assumption that the present climate will prevail during the lifetime of the reservoir. Should these conditions change, a new analysis should be carried out. Keywords: HYDROMED, reservoir, storage capacity, probability of failure, Mediterranean
Raindrop size distributions and radar reflectivity–rain rate relationships for radar hydrology
Authors: Uijlenhoet R.
Published: April 2010

Abstract. The conversion of the radar reflectivity factor Z(mm6m-3) to rain rate R(mm h-1 ) is a crucial step in the hydrological application of weather radar measurements. It has been common practice for over 50 years now to take for this conversion a simple power law relationship between Z and R. It is the purpose of this paper to explain that the fundamental reason for the existence of such power law relationships is the fact that Z and R are related to each other via the raindrop size distribution. To this end, the concept of the raindrop size distribution is first explained. Then, it is demonstrated that there exist two fundamentally different forms of the raindrop size distribution, one corresponding to raindrops present in a volume of air and another corresponding to those arriving at a surface. It is explained how Z and R are defined in terms of both these forms. Using the classical exponential raindrop size distribution as an example, it is demonstrated (1) that the definitions of Z and R naturally lead to power law Z–R relationships, and (2) how the coefficients of such relationships are related to the parameters of the raindrop size distribution. Numerous empirical Z–R relationships are analysed to demonstrate that there exist systematic differences in the coefficients of these relationships and the corresponding parameters of the (exponential) raindrop size distribution between different types of rainfall. Finally, six consistent Z–R relationships are derived, based upon different assumptions regarding the rain rate dependence of the parameters of the (exponential) raindrop size distribution. An appendix shows that these relationships are in fact special cases of a general Z–R relationship that follows from a recently proposed scaling framework for describing raindrop size distributions and their properties. Keywords: radar hydrology, raindrop size distribution, radar reflectivity–rain rate relationship
Evaluation of regional acid sensitivity predictions using field data: issues of scale and heterogeneity
Authors: Reynolds B. , Neal C. , Norris D.A.
Published: April 2010

Abstract. An acid waters sensitivity map has been widely used as a background resource for assessing potential impacts of forest management on stream water acidity within Wales. The validity of this approach has been explored by comparing predicted acid sensitivity with the observed acid neutralisation capacity (ANC) in stream runoff using data sets from two regional surveys of a major area of acidification concern in Wales. For catchments in excess of 20 ha, the acid sensitivity predictions are generally upheld, although biologically important extremes of acidity are not predicted. For smaller catchments of 2 to 5 ha area, the large observed variations in ANC are poorly predicted from the acid sensitivity map; there is no statistically significant relationship between predicted sensitivity and measured baseflow and stormflow ANC values for the catchments. This reflects the high degree of heterogeneity within catchments and the complexity of soil and groundwater interactions. The maps offer a starting point for assessing sensitivity. However, they provide no more than a very crude indication at the scale of interest to forestry managers. It is concluded that a more appropriate route for assessing sensitivity is via field measurement and the direct use of water quality and biological information. Keywords: streams, forestry, acidification, acid sensitivity mapping, ANC, Wales
Long-term and seasonal variations in CO2: linkages to catchment alkalinity generation
Authors: Norton S.A. , Cosby B.J. , Fernandez I.J. , Kahl J.S. , Robbins Church M.
Published: April 2010

Abstract. As atmospheric emissions of S have declined in the Northern Hemisphere, there has been an expectation of increased pH and alkalinity in streams believed to have been acidified by excess S and N. Many streams and lakes have not recovered. Evidence from East Bear Brook in Maine, USA and modelling with the groundwater acid-base model MAGIC (Cosby et al. 1985a,b) indicate that seasonal and yearly variations in soil PCO2 are adequate to enhance or even reverse acid-base (alkalinity) changes anticipated from modest decreases of SO4 in surface waters. Alkalinity is generated in the soil by exchange of H+ from dissociation of H2CO3, which in turn is derived from the dissolving of soil CO2. The variation in soil PCO2 produces an alkalinity variation of up to 15 meq L-1 in stream water. Detecting and relating increases in alkalinity to decreases in stream SO4 are significantly more difficult in the short term because of this effect. For example, modelled alkalinity recovery at Bear Brook due to a decline of 20 meq SO4 L-1 in soil solution is compensated by a decline from 0.4 to 0.2% for soil air PCO2. This compensation ability decays over time as base saturation declines. Variable PCO2 has less effect in more acidic soils. Short-term decreases of PCO2 below the long-term average value produce short-term decreases in alkalinity, whereas short-term increases in PCO2 produce short-term alkalization. Trend analysis for detecting recovery of streams and lakes from acidification after reduced atmospheric emissions will require a longer monitoring period for statistical significance than previously appreciated. Keywords: CO2 , alkalinity, acidification, recovery, soils, climate change
A multi-level approach to flood frequency regionalisation
Authors: De Michele C. , Rosso R.
Published: April 2010

Abstract. A multi-level approach to flood frequency regionalisation is given. Based on observed flood data, it combines physical and statistical criteria to cluster homogeneous groups in a geographical area. Seasonality analysis helps identify catchments with a common flood generation mechanism. Scale invariance of annual maximum flood, as parameterised by basin area, is used to check the regional homogeneity of flood peaks. Homogeneity tests are used to assess the statistical robustness of the regions. The approach is based on the appropriate use of the index flood method (Dalrymple, 1960) in regions with complex climate and topography controls. An application to north-western Italy is presented. Keywords: homogeneity, multi-level approach, regionalisation, seasonality, scale invariance, similarity, tests
Climatic impacts on the runoff generation processes in British Columbia, Canada
Authors: Loukas A. , Vasiliades L. , Dalezios N.R.
Published: April 2010

Abstract. The potential impact of future climate change on runoff generation processes in two southern British Columbia catchments was explored using the Canadian Centre for Climate Modelling Analysis General Circulation Model (CGCMa1) to estimate future changes in precipitation, temperature and cloud cover while the U.B.C. Watershed Model was used to simulate discharges and quantify the separate runoff components, i.e. rainfall, snowmelt, glacier melt and groundwater. Changes, not only in precipitation and temperature but also in the spatial distribution of precipitation with elevation, cloud cover, glacier extension, altitude distribution of vegetation, vegetation biomass production and plant physiology were considered. The future climate of the catchments would be wetter and warmer than the present. In the maritime rain-fed catchment of the Upper Campbell, runoff from rainfall is the most significant source of flow for present and future climatic conditions in the autumn and winter whereas runoff from groundwater generates the flow in spring and summer, especially for the future climate scenario. The total runoff, under the future climatic conditions, would increase in the autumn and winter and decrease in spring and summer. In contrast, in the interior snow-covered Illecillewaet catchment, groundwater is the most significant runoff generation mechanism in the autumn and winter although, at present, significant flow is generated from snowmelt in spring and from glacier runoff in summer. In the future scenario, the contribution to flow from snowmelt would increase in winter and diminish in spring while the runoff from the glacier would remain unchanged; groundwater would then become the most significant source of runoff, which would peak earlier in the season. Keywords: climatic change, hydrological simulation, rainfall, snowmelt, runoff processes
The prediction and management of aquatic nitrogen pollution across Europe: an introduction to the Integrated Nitrogen in European Catchments project (INCA)
Authors: Wade A. J. , Whitehead P. G. , O’Shea L. C. M.
Published: April 2010

Abstract. Excess nitrogen in soils, fresh water, estuarine and marine systems contributes to nutrient enrichment in key ecosystems throughout Europe, often leading to detrimental environmental impacts, such as soil acidification or the eutrophication of water bodies. The Integrated Nitrogenmodel for European Catchments (INCA) project aims to develop a generic version of the Integrated Nitrogen in Catchments (INCA) model to simulate the retention and transport of nitrogen within river systems, thereby providing a tool to aid the understanding of nitrogen dynamics and for river-basin management/policy-making. To facilitate the development of the model, 10 partners have tested the INCA model with data collected in study sites located in eight European countries as part of the INCA project. This paper summarises the key nitrogen issues within Europe, describes the main aims and methodology of the INCA project, and sets the project in the context of the current major research initiatives at a European level. Keywords: Europe, European Union, nitrogen, nitrate, ammonium, river basin management, modelling, water chemistry, acidification, eutrophication, Water Framework Directive, INCA.
European nitrogen policies, nitrate in rivers and the use of the INCA model
Authors: Skeffington R.
Published: April 2010

Abstract. This paper is concerned with nitrogen inputs to European catchments, how they are likely to change in future, and the implications for the INCA model. National N budgets show that the fifteen countries currently in the European Union (the EU-15 countries) probably have positive N balances – that is, N inputs exceed outputs. The major sources are atmospheric deposition, fertilisers and animal feed, the relative importance of which varies between countries. The magnitude of the fluxes which determine the transport and retention of N in catchments is also very variable in both space and time. The most important of these fluxes are parameterised directly or indirectly in the INCA Model, though it is doubtful whether the present version of the model is flexible enough to encompass short-term (daily) variations in inputs or longer-term (decadal) changes in soil parameters. As an aid to predicting future changes in deposition, international legislation relating to atmospheric N inputs and nitrate in rivers is reviewed briefly. Atmospheric N deposition and fertiliser use are likely to decrease over the next 10 years, but probably not sufficiently to balance national N budgets. Keywords: nitrogen deposition, nitrogen fertilisers, nitrogen budgets, nitrogen balance, nitrate leaching, INCA Model, environmental legislation, EU directives, air pollution, water pollution
Spatial variability of throughfall water and chemistry and forest floor water content in a Douglas fir forest stand
Authors: Raat K. J. , Draaijers G. P. J. , Schaap M. G. , Tietema A. , Verstraten J. M.
Published: April 2010

Abstract. This study focuses on spatial variability of throughfall water and chemistry and forest floor water content within a Douglas fir (Pseudotsuga menziesii, Franco L.) forest plot. Spatial patterns of water and chemistry (NH4+, NO3‾, SO42-, Cl‾, Mg2+, Ca2+, Na+ and K+) were compared and tested for stability over time. The spatial coefficient of variation (CV) was between 18 and 26% for amounts of throughfall water and ions, and 17% for forest floor water content. Concentrations and amounts of all ions were correlated significantly. Ion concentrations were negatively correlated with throughfall water amounts, but, except for NH4+, there was no such relation between throughfall water and ion amounts. Spatial patterns of throughfall water fluxes and forest floor water contents were consistent over time; patterns of ion fluxes were somewhat less stable. Because of the spatial variability of forest floor thickness and drainage, it was not possible to relate patterns in throughfall water directly to patterns in water content. The spatial variability of throughfall nitrogen and forest floor water contents can cause significant variability in NO3‾ production within the plot studied. Keywords: nutrient throughfall, forest floor water, spatial variability, time-stability, nitrogen
Assessing environmental impacts on stream water quality: the use of cumulative flux and cumulative flux difference approaches to deforestation of the Hafren Forest, mid-Wales
Authors: Neal C.
Published: April 2010

Abstract. A method for examining the impacts of disturbance on stream water quality based on paired catchment "control" and "response" water quality time series is described in relation to diagrams of cumulative flux and cumulative flux difference. The paper describes the equations used and illustrates the patterns expected for idealised flux changes followed by an application to stream water quality data for a spruce forested catchment, the Hore, subjected to clear fell. The water quality determinands examined are sodium, chloride, nitrate, calcium and acid neutralisation capacity. The anticipated effects of felling are shown in relation to reduction in mist capture and nitrate release with felling as well as to the influence of weathering and cation exchange mechanisms, but in a much clearer way than observed previously using other approaches. Keywords: Plynlimon, stream, Hore, acid neutralisation capacity, calcium, chloride, nitrate, sodium, cumulative flux, flux
Modelling nitrogen dynamics and distributions in the River Tweed, Scotland: an application of the INCA model
Authors: Jarvie H. P. , Wade A. J. , Butterfield D. , Whitehead P. G. , Tindall C. I. , Virtue W. A. , Dryburgh W. , McGraw A.
Published: April 2010

Abstract. The INCA (Integrated Nitrogen in Catchments) model was applied to the River Tweed in the Scottish Borders, a large-scale (4400km2), spatially heterogeneous catchment, draining a wide range of agricultural land-use types, and which contributes approximately 20% of UK river flows to the North Sea. The model was calibrated for the first four years' data record (1994 to 1997) and tested over the following three years (1998 to 2000). The model calibration and testing periods incorporated a high degree of variability in climatic conditions and river flows within the Tweed catchment. The ability of the INCA model to reproduce broad-scale spatial patterns and seasonal dynamics in river flows and nitrate concentrations suggests that the processes controlling first order variability in river water nitrate concentrations have been represented successfully within the model. The tendency of the model to overestimate summer/early autumn baseflow nitrate concentrations during dry years may be linked to the operation of aquatic plant uptake effects. It is, therefore, suggested that consideration be given to incorporating a spatially and temporally variable in-stream plant uptake term for the application of INCA to lowland eutrophic rivers. Scenarios to examine possible impacts of environmental change on nitrate concentrations on the Tweed are examined. These include the effects of (i) implementing different recommendations for fertiliser use and land use change under the Nitrate Sensitive Areas (NSA) Scheme and the Scottish Code of Good Agricultural Practice, (ii) worst case scenario changes linked to a dramatic reduction in livestock numbers as a result of a crisis in UK livestock farming and (iii) changes in atmospheric nitrogen deposition. Keywords: Nitrate, nitrogen, modelling, Tweed, INCA
Effect on nitrate concentration in stream water of agricultural practices in small catchments in Brittany: I. Annual nitrogen budgets
Authors: Ruiz L. , Abiven S. , Durand P. , Martin C. , Vertès F. , Beaujouan V.
Published: April 2010

Abstract. The hydrological and biogeochemical monitoring of catchments has become a common approach for studying the effect of the evolution of agricultural practices on water resources. In numerous studies, the catchment is used as a "mega-lysimeter" to calculate annual input-output budgets. However, the literature reflects two opposite interpretations of the trends of nitrate concentration in streamwater. For some authors, essentially in applied studies, the mean residence time of leached nitrate in shallow groundwater systems is much less than one year and river loads reflect annual land use while for others, nitrate is essentially transport limited, independent of soil nitrate supply in the short term and annual variations reflect changes in climatic conditions. This study tests the effect of agricultural land-use changes on inter-annual nitrate trends on stream water of six small adjacent catchments from 0.10 to 0.57 km2 in area, on granite bedrock, at Kerbernez, in Western Brittany (France). Nitrate concentrations and loads in streamwater have been monitored for nine years (1992 to 2000) at the outlet of the catchments. An extensive survey of agricultural practices from 1993 to 1999 allowed assessment of the nitrogen available for leaching through nitrogen budgets. For such small catchments, year-to-year variations of nitrate leaching can be very important, even when considering the 'memory effect' of soil, while nitrate concentrations in streamwater appear relatively steady. No correlation was found between the calculated mean nitrate concentration of drainage water and the mean annual concentration in streams, which can even exhibit opposite trends in inter-annual variations. The climatic conditions do not affect the mean concentration in streamwater significantly. These results suggest that groundwater plays an important role in the control of streamwater nitrate concentration. Keywords: nitrate, diffuse pollution, agricultural catchment, nitrogen budget, leaching, Kerbernez catchments