bluuebunny/crossref_metadata_2025 huggingface dataset:
Assessment of the Post-Cracking Fatigue Behavior of Steel and Polyolefin Fiber-Reinforced Concrete
Authors: Enfedaque Alejandro , Alberti Marcos G. , Gálvez Jaime C. , Proaño Jhonatan Santiago
Published: December 2021

Some types of fiber-reinforced concrete (FRC) such as steel fiber-reinforced concrete (SFRC) or polyolefin fiber-reinforced concrete (PFRC) are suitable for structural uses but there is still scarce knowledge regarding their flexural fatigue behavior. This study aimed to provide some insight into the matter by carrying out flexural fatigue tests in pre-cracked notched specimens that previously reached the Service Limit State (SLS) or the Ultimate Limit State (ULS). The fatigue cycles applied between 30% and 70% of the pre-crack load at 5 Hz until the collapse of the material or until 1,000,000 cycles were reached. The results showed that the fatigue life of PFRC both at SLS or ULS was remarkably higher than the correspondent of SFRC. The fracture surface analysis carried out found a linear relation between the fibers present in the fracture surface and the number of cycles that both SFRC and PFRC could bear.
New Insights into the Application of 3D-Printing Technology in Hernia Repair
Authors: Pérez-Köhler Bárbara , Benito-Martínez Selma , Gómez-Gil Verónica , Rodríguez Marta , Pascual Gemma , Bellón Juan Manuel
Published: December 2021

Abdominal hernia repair using prosthetic materials is among the surgical interventions most widely performed worldwide. These materials, or meshes, are implanted to close the hernial defect, reinforcing the abdominal muscles and reestablishing mechanical functionality of the wall. Meshes for hernia repair are made of synthetic or biological materials exhibiting multiple shapes and configurations. Despite the myriad of devices currently marketed, the search for the ideal mesh continues as, thus far, no device offers optimal tissue repair and restored mechanical performance while minimizing postoperative complications. Additive manufacturing, or 3D-printing, has great potential for biomedical applications. Over the years, different biomaterials with advanced features have been successfully manufactured via 3D-printing for the repair of hard and soft tissues. This technological improvement is of high clinical relevance and paves the way to produce next-generation devices tailored to suit each individual patient. This review focuses on the state of the art and applications of 3D-printing technology for the manufacture of synthetic meshes. We highlight the latest approaches aimed at developing improved bioactive materials (e.g., optimizing antibacterial performance, drug release, or device opacity for contrast imaging). Challenges, limitations, and future perspectives are discussed, offering a comprehensive scenario for the applicability of 3D-printing in hernia repair.
Titanium Nitride as a Plasmonic Material from Near-Ultraviolet to Very-Long-Wavelength Infrared Range
Authors: Judek Jarosław , Wróbel Piotr , Michałowski Paweł Piotr , Ożga Monika , Witkowski Bartłomiej , Seweryn Aleksandra , Struzik Michał , Jastrzębski Cezariusz , Zberecki Krzysztof
Published: December 2021

Titanium nitride is a well-known conductive ceramic material that has recently experienced resumed attention because of its plasmonic properties comparable to metallic gold and silver. Thus, TiN is an attractive alternative for modern and future photonic applications that require compatibility with the Complementary Metal-Oxide-Semiconductor (CMOS) technology or improved resistance to temperatures or radiation. This work demonstrates that polycrystalline TiNx films sputtered on silicon at room temperature can exhibit plasmonic properties continuously from 400 nm up to 30 μm. The films’ composition, expressed as nitrogen to titanium ratio x and determined in the Secondary Ion Mass Spectroscopy (SIMS) experiment to be in the range of 0.84 to 1.21, is essential for optimizing the plasmonic properties. In the visible range, the dielectric function renders the interband optical transitions. For wavelengths longer than 800 nm, the optical properties of TiNx are well described by the Drude model modified by an additional Lorentz term, which has to be included for part of the samples. The ab initio calculations support the experimental results both in the visible and infra-red ranges; particularly, the existence of a very low energy optical transition is predicted. Some other minor features in the dielectric function observed for the longest wavelengths are suspected to be of phonon origin.
Impact of Li3BO3 Addition on Solid Electrode-Solid Electrolyte Interface in All-Solid-State Batteries
Authors: Il’ina Evgeniya , Pershina Svetlana , Antonov Boris , Pankratov Alexander
Published: December 2021

All-solid-state lithium-ion batteries raise the issue of high resistance at the interface between solid electrolyte and electrode materials that needs to be addressed. The article investigates the effect of a low-melting Li3BO3 additive introduced into LiCoO2- and Li4Ti5O12-based composite electrodes on the interface resistance with a Li7La3Zr2O12 solid electrolyte. According to DSC analysis, interaction in the studied mixtures with Li3BO3 begins at 768 and 725 °C for LiCoO2 and Li4Ti5O12, respectively. The resistance of half-cells with different contents of Li3BO3 additive after heating at 700 and 720 °C was studied by impedance spectroscopy in the temperature range of 25–340 °C. It was established that the introduction of 5 wt% Li3BO3 into LiCoO2 and heat treatment at 720 °C led to the greatest decrease in the interface resistance from 260 to 40 Ω cm2 at 300 °C in comparison with pure LiCoO2. An SEM study demonstrated that the addition of the low-melting component to electrode mass gave better contact with ceramics. It was shown that an increase in the annealing temperature of unmodified cells with Li4Ti5O12 led to a decrease in the interface resistance. It was found that the interface resistance between composite anodes and solid electrolyte had lower values compared to Li4Ti5O12|Li7La3Zr2O12 half-cells. It was established that the resistance of cells with the Li4Ti5O12/Li3BO3 composite anode annealed at 720 °C decreased from 97.2 (x = 0) to 7.0 kΩ cm2 (x = 5 wt% Li3BO3) at 150 °C.
Porous Nanostructured Gadolinium Aluminate for High-Sensitivity Humidity Sensors
Authors: Doroftei Corneliu , Leontie Liviu
Published: December 2021

This paper presents the synthesis of gadolinium aluminate (GdAlO3), an oxide compound with a perovskite structure, for applications as a capacitive and/or resistive humidity sensor. Gadolinium aluminate was synthesized by the sol-gel self-combustion method. This method allowed us to obtain a highly porous structure in which open pores prevail, a structure favorable to humidity sensors. Most of the materials studied as capacitive/resistive humidity sensors have significant sensitivities only with respect to one of these types of sensors. In the case of the studied gadolinium aluminate with p-type electric conductivity, the relative humidity of the air has a significant influence on both capacitive and resistive types of electric humidity sensors. The capacity increases about 10,000 times, and the resistance decreases about 8000 times as the relative humidity increases from 0 to 98%. The investigated gadolinium aluminate can be used successfully to obtain high-sensitivity capacitive and/or resistive humidity sensors.
Graphene and Other 2D Layered Nanomaterials and Hybrid Structures: Synthesis, Properties and Applications
Authors: Scarano Domenica , Cesano Federico
Published: December 2021

The field of two-dimensional (2D) layered nanomaterials, their hybrid structures, and composite materials has been suddenly increasing since 2004, when graphene—almost certainly the most known 2D material—was successfully obtained from graphite via mechanical exfoliation [...]
Temporal Evolution of Pressure Generated by a Nanosecond Laser Pulse Used for Assessment of Adhesive Strength of the Tungsten–Zirconium–Borides Coatings
Authors: Radziejewska Joanna , Kaczmarek Agata , Mościcki Tomasz , Hoffman Jacek
Published: December 2021

The article presents theoretical and experimental study of shock waves induced by a nanosecond laser pulse. Generation of surface plasma pressure by ablation of the graphite absorption layer in water medium and shock wave formation were analyzed theoretically and experimentally. The amplitude and temporal variation of the shock wave pressure was determined basing on a proposed hydrodynamic model of nanosecond laser ablation and experimentally verified with use of a polyvinylidene fluoride (PVDF) piezoelectric-film sensor. The determined pressure wave was used for examination of adhesive strength of tungsten–zirconium–boride coatings on steel substrate. The magnetron sputtered (MS) W–Zr–B coatings show good adhesion to the steel substrate. The obtained experimental results prove the correctness of the proposed model as well as the suitability of the procedure for assessment of adhesive strength.
Evolution of Chemical Composition and Modeling of Growth Nonmetallic Inclusions in Steel Containing Yttrium
Authors: Kalisz Dorota , Żak Paweł L. , Semiryagin Sergey , Gerasin Sergey
Published: December 2021

The programs WYK_Stal and Bi-Growth, developed at AGH-UST, Kraków, Poland, were used for simulating the refining process, the formation of non-metallic inclusions, and their growth. The Fe-Y-Al-O-S-Ca system in pre-oxidized steel was analyzed, where yttrium formed precipitates from both O and S. When first Al and second Y were added to steel, the proportion of Al2O3 inclusions remained constant. This resulted in higher yttrium losses for oxide formation, whereas the sulfur content promoted sulfide phase formation. The introduction of yttrium at the end of refining contributed to reducing the consumption of this element in the non-metallic phase formation. The addition of aluminum and then calcium were sufficient to achieve a high degree of deoxidation and desulfurization. Calculations performed with WYK_Stal for both (a) and (c) versions of the model showed that the sulfide phase was constituted by CaS and FeS (model c) and CaS (model (a)). The participation of the calcium sulfide phase turned out to be dominant in the inclusions. Their presence was also identified in the slag phase. Simulations of the growth of complex oxide and oxo-sulfide inclusions using the Bi_Growth program showed that the yttrium content of the steel has a decisive role in the formation of complex oxide inclusions and the final oxygen content of the steel. In contrast, for the growth of oxide-sulfide inclusions, the character of growth is determined by the sulfur content of steel.
Visible Light Trapping against Charge Recombination in FeOx–TiO2 Photonic Crystal Photocatalysts
Authors: Pylarinou Martha , Toumazatou Alexia , Sakellis Elias , Xenogiannopoulou Evangelia , Gardelis Spiros , Boukos Nikos , Dimoulas Athanasios , Likodimos Vlassis
Published: December 2021

Tailoring metal oxide photocatalysts in the form of heterostructured photonic crystals has spurred particular interest as an advanced route to simultaneously improve harnessing of solar light and charge separation relying on the combined effect of light trapping by macroporous periodic structures and compositional materials’ modifications. In this work, surface deposition of FeOx nanoclusters on TiO2 photonic crystals is investigated to explore the interplay of slow-photon amplification, visible light absorption, and charge separation in FeOx–TiO2 photocatalytic films. Photonic bandgap engineered TiO2 inverse opals deposited by the convective evaporation-induced co-assembly method were surface modified by successive chemisorption-calcination cycles using Fe(III) acetylacetonate, which allowed the controlled variation of FeOx loading on the photonic films. Low amounts of FeOx nanoclusters on the TiO2 inverse opals resulted in diameter-selective improvements of photocatalytic performance on salicylic acid degradation and photocurrent density under visible light, surpassing similarly modified P25 films. The observed enhancement was related to the combination of optimal light trapping and charge separation induced by the FeOx–TiO2 interfacial coupling. However, an increase of the FeOx loading resulted in severe performance deterioration, particularly prominent under UV-Vis light, attributed to persistent surface recombination via diverse defect d-states.
Highly Active Co3O4-Based Catalysts for Total Oxidation of Light C1–C3 Alkanes Prepared by a Simple Soft Chemistry Method: Effect of the Heat-Treatment Temperature and Mixture of Alkanes
Authors: Sanchis Rut , García Adrián , Ivars-Barceló Francisco , Taylor Stuart H. , García Tomás , Dejoz Ana , Vázquez María Isabel , Solsona Benjamín
Published: December 2021

In the present work, a simple soft chemistry method was employed to prepare cobalt mixed oxide (Co3O4) materials, which have shown remarkably high activity in the heterogeneously catalyzed total oxidation of low reactive VOCs such as the light alkanes propane, ethane, and methane. The optimal heat-treatment temperature of the catalysts was shown to depend on the reactivity of the alkane studied. The catalytic activity of the Co3O4 catalysts was found to be as high as that of the most effective catalysts based on noble metals. The physicochemical properties, from either the bulk (using XRD, TPR, TPD-O2, and TEM) or the surface (using XPS), of the catalysts were investigated to correlate the properties with the catalytic performance in the total oxidation of VOCs. The presence of S1 low-coordinated oxygen species at the near surface of the Co3O4-based catalysts appeared to be linked with the higher reducibility of the catalysts and, consequently, with the higher catalytic activity, not only per mass of catalyst but also per surface area (enhanced areal rate). The co-presence of propane and methane in the feed at low reaction temperatures did not negatively affect the propane reactivity. However, the co-presence of propane and methane in the feed at higher reaction temperatures negatively affected the methane reactivity.
Heat Treatment of Cast and Cold Rolled Al–Yb and Al–Mn–Yb–Zr Alloys
Authors: Kodetová Veronika , Vlach Martin , Bajtošová Lucia , Leibner Michal , Kudrnová Hana , Málek Jaroslav , Mára Vladimír , Cieslar Miroslav , Zikmund Sebastien
Published: December 2021

The microstructure, electrical properties and microhardness of as-cast and cold rolled AlYb and AlMnYbZr alloys were investigated. The addition of Mn, Yb and Zr has a positive influence on grain size. A deformed structure of the grains with no changes of their size was observed after cold rolling. The Al3Yb particles coherent with the matrix were observed in the AlYb alloys. The size of the particles was about 20 nm in the initial state; after isochronal treatment up to 540 °C the particles coarsen, and their number density was lower. The deformation has a massive effect on the microhardness behavior until treatment at 390 °C, after which the difference in microhardness changes between as-cast and cold rolled alloys disappeared. Relative resistivity changes show a large decrease in the temperature interval of 330–540 °C which is probably caused by a combination of recovery of dislocations and precipitation of the Al3(Yb,Zr) particles. Precipitation hardening was observed between 100 and 450 °C in the AlYb alloy after ageing at 625 °C/24 h and between 330 and 570 °C in the AlMnYbZr alloy after ageing at 625 °C/24 h.
A Comparative Analysis of the Physical Modelling of Two Methods of Balls Separation
Authors: Wójcik Łukasz , Pater Zbigniew , Bulzak Tomasz , Tomczak Janusz , Lis Konrad
Published: December 2021

The article presents the results of model tests with which a comparative analysis of two methods of ball separation during the skew rolling process was carried out. A verification of the results obtained in the physical modelling process with the results obtained in the real process of skew ball rolling was also carried out. During the physical modelling, the effect of changing the ball separation method on the quality of the products obtained, variations in maximum torque values and maximum radial forces were analyzed. In the case of real tests, the results were verified with the results of physical modelling, in which the surface quality and torque values for one of the tool sets were compared. Physical modelling was used to verify the differences between the two methods of ball separation. Commercial plasticine based on synthetic wax from the manufacturer PRIMO was used as a model material for physical analysis. The plasticine used for testing was cooled to 0 °C and the cooling process took 24 h. The tools used for the physical modelling were 3D printed and the material used was ABS. The method of physical modelling using plasticine as a model material allows for a correct analysis of hot metal forming processes.
Deformation Behaviors and Energy Absorption of Composite Re-Entrant Honeycomb Cylindrical Shells under Axial Load
Authors: Ma Nanfang , Deng Qingtian , Li Xinbo
Published: December 2021

Composite materials and re-entrant honeycomb structures have superior mechanical performance in energy absorption capacity. Inspired by laminate composite layers, single-layer re-entrant honeycomb cylindrical shells (RHCSs) with different orientations were established, and composite RHCSs were proposed by combining the single-layer RHCSs with different orientations. The deformation behaviors of single layer RHCSs under quasi-static compression were studied by experimentation, and single-layer RHCSs with varying orientations did not show negative Poisson’s ratio effects. The energy absorption capacity of single-layer and composite RHCSs was researched using simulation. To analyze the energy absorption capacity, we determined the plateau stress, the mean force and specific energy absorption of single-layer and multi-layer composite RHCSs under different impact velocities; the following conclusions were obtained: compared with the single-layer RHCSs, the multi-layer composite RHCSs, which had the same size, the energy absorption capacity improved significantly under the same impact velocities. The energy absorption capacity of the multi-layer composite RHCSs improved with increasing number of layers under low velocity.
Forecasting Strength of CFRP Confined Concrete Using Multi Expression Programming
Authors: Ilyas Israr , Zafar Adeel , Javed Muhammad , Farooq Furqan , Aslam Fahid , Musarat Muhammad , Vatin Nikolai
Published: December 2021

This study provides the application of a machine learning-based algorithm approach names “Multi Expression Programming” (MEP) to forecast the compressive strength of carbon fiber-reinforced polymer (CFRP) confined concrete. The suggested computational Multiphysics model is based on previously reported experimental results. However, critical parameters comprise both the geometrical and mechanical properties, including the height and diameter of the specimen, the modulus of elasticity of CFRP, unconfined strength of concrete, and CFRP overall layer thickness. A detailed statistical analysis is done to evaluate the model performance. Then the validation of the soft computational model is made by drawing a comparison with experimental results and other external validation criteria. Moreover, the results and predictions of the presented soft computing model are verified by incorporating a parametric analysis, and the reliability of the model is compared with available models in the literature by an experimental versus theoretical comparison. Based on the findings, the valuation and performance of the proposed model is assessed with other strength models provided in the literature using the collated database. Thus the proposed model outperformed other existing models in term of accuracy and predictability. Both parametric and statistical analysis demonstrate that the proposed model is well trained to efficiently forecast strength of CFRP wrapped structural members. The presented study will promote its utilization in rehabilitation and retrofitting and contribute towards sustainable construction material.
Screen Printed Copper and Tantalum Modified Potassium Sodium Niobate Thick Films on Platinized Alumina Substrates
Authors: Kmet Brigita , Kuščer Danjela , Dutta Soma , Uršič Hana , Matavž Aleksander , Levassort Franck , Bobnar Vid , Malič Barbara , Benčan Andreja
Published: December 2021

We show how sintering in different atmospheres affects the structural, microstructural, and functional properties of ~30 μm thick films of K0.5Na0.5NbO3 (KNN) modified with 0.38 mol% K5.4Cu1.3Ta10O29 and 1 mol% CuO. The films were screen printed on platinized alumina substrates and sintered at 1100 °C in oxygen or in air with or without the packing powder (PP). The films have a preferential crystallographic orientation of the monoclinic perovskite phase in the [100] and [−101] directions. Sintering in the presence of PP contributes to obtaining phase-pure films, which is not the case for the films sintered without any PP notwithstanding the sintering atmosphere. The latter group is characterized by a slightly finer grain size, from 0.1 μm to ~2 μm, and lower porosity, ~6% compared with ~13%. Using piezoresponse force microscopy (PFM) and electron backscatter diffraction (EBSD) analysis of oxygen-sintered films, we found that the perovskite grains are composed of multiple domains which are preferentially oriented. Thick films sintered in oxygen exhibit a piezoelectric d33 coefficient of 64 pm/V and an effective thickness coupling coefficient kt of 43%, as well as very low mechanical losses of less than 0.5%, making them promising candidates for lead-free piezoelectric energy harvesting applications.
Microgalvanic Corrosion of Mg–Ca and Mg–Al–Ca Alloys in NaCl and Na2SO4 Solutions
Authors: Yang Peixu , Ye Songbo , Feng Baojing , Liu Jinhui , Huang Sensen , Liu Guonan , Zhang Weidong , Tang Weineng , Zhu Shijie , Zhang Shaojun
Published: December 2021

As a kind of potential biomedical material, Mg–Ca alloy has attracted much attention. However, the role of Ca-containing intermetallics in microgalvanic corrosion is still controversial. In 0.6 mol/L NaCl and Na2SO4 solutions, the microgalvanic corrosion behavior of the second phase and Mg matrix of Mg–Ca and Mg–Al–Ca alloys was examined. It was confirmed that the Mg2Ca phase acts as a microanode in microgalvanic corrosion in both NaCl and Na2SO4 solutions, with the Mg matrix acting as the cathode and the Al2Ca phase acting as the microcathode to accelerate corrosion of the adjacent Mg matrix. It was also found that Cl− and SO42− have different sensibilities to microgalvanic corrosion.
The Influence of Specimen Geometry and Loading Conditions on the Mechanical Properties of Porous Brittle Media
Authors: Bragov Anatoly M. , Lomunov Andrey K. , Igumnov Leonid A. , Belov Aleksandr A. , Eremeyev Victor A.
Published: December 2021

Dynamic tests of fine-grained fired dioxide-zirconia ceramics under compression under uniaxial stress conditions were carried out. The influence of the specimen length on the obtained strength and deformation properties of ceramics is investigated. The thickness of the specimen has a significant impact on the course of the obtained dynamic stress–strain diagrams: short specimens have a much more sloping area of active loading branch. The main contribution to the modulus of the load branch resulting from tests of brittle porous media is made by the geometry of the specimens and the porosity of the material. When choosing the length of specimens for dynamic tests, the optimal geometry of the tested specimens is preferable in accordance with the Davies–Hunter criterion, when the contributions of axial and radial inertia are mutually compensated, and the contribution of the effects of friction in the resulting diagram is minimal. When choosing the geometry of specimens of brittle porous media, the structure of the material should be taken into account so that the size of the specimen (both length and diameter) exceeds the size of the internal fractions of the material by at least five times.
Effect of Al Content on Microstructure Evolution and Mechanical Properties of As-Cast Mg-11Gd-2Y-1Zn Alloy
Authors: Fu Yuanke , Wang Liping , Zhao Sicong , Feng Yicheng , Wang Lei
Published: December 2021

In the present paper, the Mg-11Gd-2Y-1Zn alloys with different Al addition were fabricated by the gravity permanent mold method. The effect of Al content on microstructure evolution and mechanical properties of as-cast Mg-11Gd-2Y-1Zn alloy was studied by metallographic microscope, scanning electron microscope, XRD and tensile testing. The experimental results showed that the microstructure of as-cast Mg-11Gd-2Y-1Zn alloy consisted of α-Mg phase and island-shaped Mg3 (RE, Zn) phase. When Al element was added, Al2RE phase and lamellar Mg12REZn (LPSO) phase were formed in the Mg-11Gd-2Y-1Zn alloy. With increasing Al content, LPSO phase and Mg3 (RE, Zn) phase gradually decreased, while Al2RE phase gradually increased. There were only α-Mg and Al2RE phases in the Mg-11Gd-2Y-1Zn-5Al alloy. With the increase of Al content, the grain size decreased firstly and then increased. When the Al content was 1 wt.%, the grain size of the alloy was the minimum value (28.9 μm). The ultimate tensile strength and elongation increased firstly and then decreased with increasing Al addition. And the fracture mode changed from intergranular fracture to transgranular fracture with increasing addition. When Al addition was 1 wt.%, the maximum ultimate tensile strength reached 225.6 MPa, and the elongation was 7.8%. When the content of Al element was 3 wt.%, the maximum elongation reached 10.2% and the ultimate tensile strength was 207.7 MPa.
Architectural Glazed Tiles Used in Ancient Chinese Screen Walls (15th–18th Century AD): Ceramic Technology, Decay Process and Conservation
Authors: Shen Jingyi , Li Li , Wang Ji-Peng , Li Xiaoxi , Zhang Dandan , Ji Juan , Luan Ji-Yuan
Published: December 2021

The glazed tile is an important building material used throughout the history of traditional Chinese architecture. Architectural glazed tiles used to decorate the screen walls of ancient China are studied scientifically for the first time. More than 30 glazed tile samples from the screen walls of the 15th to 18th century AD of the Hancheng Confucian Temple and Town God’s Temple in Shaanxi Province were carefully investigated using SEM–EDS and XRD. Microstructure and chemistry indicated the raw materials, the recipes and the technological choices used to produce the paste and glaze of the glazed tile samples studied. The causes for the key degradation processes of these glazed tiles used as building materials in the screen walls have also been discussed. This work has clear implications for the restoration and conservation treatments on these kinds of ancient Chinese building materials.
Preparation of Electrode Materials Based on Carbon Cloth via Hydrothermal Method and Their Application in Supercapacitors
Authors: Wang Xiaonan , Xu Peiquan , Zhang Pengyu , Ma Shuyue
Published: December 2021

Supercapacitors have the unique advantages of high power density, fast charge and discharge rates, long cycle life, high safety, and reliability, and are increasingly being used for applications including automobiles, rail transit, communication equipment, digital electronics, and aerospace equipment. The supercapacitor industry is currently in a stage of rapid development; great breakthroughs have also been made in improving the performance of supercapacitors and the expansion of their application. Electrode technology is the core of supercapacitors. Transition-metal compounds have a relatively high theoretical capacity and have received widespread attention as electrode materials for supercapacitors. In addition, there is a synergistic effect between the different components of various electrode composite materials. Due to their superior electrochemical performance, supercapacitors are receiving increasing research attention. Flexible supercapacitors have been hailed for their good plasticity, resulting in a development boom. This review article mainly outlines the development process of various electrode materials, including carbon materials, conductive polymers, metal compounds, and composite materials, as well as flexible electrode materials based on carbon cloth.
Interpretation of Specific Strength-Over-Resistivity Ratio in Cu Alloys
Authors: Li Hongming , Zhang Shuang , Zhao Yajun , Li Xiaona , Jiang Fushi , Dong Chuang
Published: December 2021

Reaching simultaneously high mechanical strength and low electrical resistivity is difficult as both properties are based on similar microstructural mechanisms. In our previous work, a new parameter, the tensile strength-over-electrical resistivity ratio, is proposed to evaluate the matching of the two properties in Cu alloys. A specific ratio of 310 × 108 MPa·Ω−1·m−1, independent of the alloy system and thermal history, is obtained from Cu-Ni-Mo alloys, which actually points to the lower limit of prevailing Cu alloys possessing high strength and low resistivity. The present paper explores the origin of this specific ratio by introducing the dual-phase mechanical model of composite materials, assuming that the precipitate particles are mechanically mixed in the Cu solid solution matrix. The strength and resistivity of an alloy are respectively in series and parallel connections to those of the matrix and the precipitate. After ideally matching the contributions from the matrix and the precipitate, the alloy should at least reach half of the resistivity of pure Cu, i.e., 50%IACS, which is the lower limit for industrially accepted highly conductive Cu alloys. Under this condition, the specific 310 ratio is related to the precipitate-over-matrix ratios for strength and resistivity, which are both two times those of pure Cu.
Analysis of Fiber-Reinforced Concrete Slabs under Centric and Eccentric Load
Authors: Marcalikova Zuzana , Bilek Vlastimil , Sucharda Oldrich , Cajka Radim
Published: December 2021

Research on the interaction between slabs and subsoil involves the field of materials engineering, concrete structures, and geotechnics. In the vast majority of cases, research focuses on only one of these areas, whereas for advanced study and computer simulations, detailed knowledge of the whole task is required. Among the new knowledge and information upon which this article focuses is the evaluation of subsoil stress using specialized pressure cells, along with detailed measurements of the deformation of a fiber-reinforced concrete slab. From a design point of view, this research is focused on the issue of the center of the cross section and the influence of eccentricity. Knowledge in this area is not yet comprehensively available for fiber-reinforced concrete slabs, where 2D deformation sections of the slab and 3D deformation surfaces of the slab are used in experiments. The experimental program includes a centrically and eccentrically loaded slab. These are structural elements that were tested on a specialized device. Both slabs had the same concrete recipe, with a dispersed reinforcement content of 25 kg/m3. The dimensions of the slab were 2000 × 2000 × 150 mm. Laboratory tests assessed compressive strength, the modulus of elasticity, splitting tensile strength, and bending tensile strength. Based on approximate data from the 3D deformation surfaces, an evaluation of the load-displacement diagrams for the center of the slab and for the center of eccentricity was performed. In conclusion, an overall evaluation and discussion of the results relies on experiments and the mechanical properties of fiber-reinforced concrete.
Precipitation Hardening at Elevated Temperatures above 400 °C and Subsequent Natural Age Hardening of Commercial Al–Si–Cu Alloy
Authors: Li Ruoqi , Takata Naoki , Suzuki Asuka , Kobashi Makoto , Okada Yuji , Furukawa Yuichi
Published: December 2021

The precipitation of intermetallic phases and the associated hardening by artificial aging treatments at elevated temperatures above 400 °C were systematically investigated in the commercially available AC2B alloy with a nominal composition of Al–6Si–3Cu (mass%). The natural age hardening of the artificially aged samples at various temperatures was also examined. A slight increase in hardness (approximately 5 HV) of the AC2B alloy was observed at an elevated temperature of 480 °C. The hardness change is attributed to the precipitation of metastable phases associated with the α-Al15(Fe, Mn)3Si2 phase containing a large amount of impurity elements (Fe and Mn). At a lower temperature of 400 °C, a slight artificial-age hardening appeared. Subsequently, the hardness decreased moderately. This phenomenon was attributed to the precipitation of stable θ-Al2Cu and Q-Al4Cu2Mg8Si6 phases and their coarsening after a long duration. The precipitation sequence was rationalized by thermodynamic calculations for the Al–Si–Cu–Fe–Mn–Mg system. The natural age-hardening behavior significantly varied depending on the prior artificial aging temperatures ranging from 400 °C to 500 °C. The natural age-hardening was found to strongly depend on the solute contents of Cu and Si in the Al matrix. This study provides fundamental insights into controlling the strength level of commercial Al–Si–Cu cast alloys with impurity elements using the cooling process after solution treatment at elevated temperatures above 400 °C.
Transition Metals (Cr3+) and Lanthanides (Eu3+) in Inorganic Glasses with Extremely Different Glass-Formers B2O3 and GeO2
Authors: Kowalska Karolina , Kuwik Marta , Polak Justyna , Pisarska Joanna , Pisarski Wojciech A.
Published: December 2021

Glasses containing two different network-forming components and doped with optically active ions exhibit interesting properties. In this work, glass systems based on germanium dioxide and boron trioxide singly doped with lanthanides (Eu3+) and transition metals (Cr3+) ions are research subjects. Optical spectroscopy was the major research tool used to record excitation and emission spectra in a wide spectral range for studied systems. The emitted radiation of glasses doped with Cr3+ ions is dominated by broadband luminescence centered at 770 nm and 1050 nm (4T2 → 4A2). Interestingly, the increase of concentration of one of the oxides contributed to the detectable changes of the R-line (2E → 4A2) of Cr3+ ions. Moreover, EPR spectroscopy confirmed the paramagnetic properties of the obtained glasses. The influence of molar ratio GeO2:B2O3 on spectroscopic properties for Eu3+ ions is discussed. The intensity of luminescence bands due to transitions of trivalent europium ions as well as the ratio R/O decrease with the increase of B2O3. On the other hand, the increase in concentration B2O3 influences the increasing tendency of luminescence lifetimes for the 5D0 state of Eu3+ ions. The results will contribute to a better understanding of the role of the glass host and thus the prospects for new optical materials.
Study on Collapse Resistance of RC Frame under the Corner Column Removal Scenario
Authors: Xu Jin , Wang Sheliang , Liu Kangning , Quan Xiaoyi , Dong Fangfei
Published: December 2021

The progressive collapse of buildings induces a variety of catastrophic consequences, such as casualties and property loss over the past few decades. The corner column is more prone to abnormal load events compared to the inner column and outer column; thus, it is easier to trigger progressive collapse. By considering the effects of floor slabs and adjacent bays on progressive collapse behavior, the pseudo-static loading method was used to study the progressive collapse test of a 1/3 scaled, one story, 2 × 2-bay cast-in-place reinforced concrete frame substructure under the removal condition of a corner column. The test results show that the flexural deformation principally concentrates upon the components of a directly affected part (DAP), and compressive arch actions are observed in members of the indirectly affected part (IAP). Moreover, the slab adjacent to the removed column and periphery elements contributes great resistance to a progressive collapse.
Development of an Elastic, Electrically Conductive Coating for TPU Filaments
Authors: Grellmann Henriette , Bruns Mathis , Lohse Felix Michael , Kruppke Iris , Nocke Andreas , Cherif Chokri
Published: December 2021

Electrically conductive filaments are used in a wide variety of applications, for example, in smart textiles and soft robotics. Filaments that conduct electricity are required for the transmission of energy and information, but up until now, most electrically conductive fibers, filaments and wires offer low mechanical elongation. Therefore, they are not well suited for the implementation into elastomeric composites and textiles that are worn close to the human body and have to follow a wide range of movements. In order to overcome this issue, the presented study aims at the development of electrically conductive and elastic filaments based on a coating process suited for multifilament yarns made of thermoplastic polyurethane (TPU). The coating solution contains TPU, carbon nanotubes (CNT) and N-Methyl-2-pyrrolidone (NMP) with varied concentrations of solids and electrically conductive particles. After applying the coating to TPU multifilament yarns, the mechanical and electrical properties are analyzed. A special focus is given to the electromechanical behavior of the coated yarns under mechanical strain loading. It is determined that the electrical conductivity is maintained even at elongations of up to 100%.
Effect of Ground Granulated Blast Furnace Slag Replacement Ratio on Structural Performance of Precast Concrete Beams
Authors: Lee Yong-Jun , Kim Hyeong-Gook , Kim Kil-Hee
Published: December 2021

This study was conducted to investigate the effect of ground granulated blast furnace slag on the structural performance of precast concrete beams, evaluating the flexural, shear and bonding performance by using the replacement ratio of the ground granulated blast furnace slag as a variable. The design strength of the concrete was set at 45 MPa in consideration of the characteristics of precast concrete products, and the replacement ratio of the ground granulated blast furnace slag to replace cement was 30 to 70%. The experimental results showed that all specimens had similar behavioral characteristics regardless of the replacement ratio of the ground granulated blast furnace slag. Comparison of the prediction results obtained by ACI 318-19 and EC 2 showed that the mean flexural strength and shear strength were higher than 1.19 and 1.43, respectively, and the mean bond strength was 1.57, satisfying the required performance. Therefore, the experimental results showed that in using the ground granulated blast furnace slag as an admixture for precast concrete, the cement replacement ratio may be increased up to 70% without causing any problems in securing the structural performance. Summarizing the results of the present study, a ground granulated blast furnace slag replacement ratio of 50% or lower may be reasonably applied.
X-ray Emission Hazards from Ultrashort Pulsed Laser Material Processing in an Industrial Setting
Authors: Stolzenberg Ulf , Schmitt Rahner Mayka , Pullner Björn , Legall Herbert , Bonse Jörn , Kluge Michael , Ortner Andreas , Hoppe Bernd , Krüger Jörg
Published: December 2021

Interactions between ultrashort laser pulses with intensities larger than 1013 W/cm2 and solids during material processing can lead to the emission of X-rays with photon energies above 5 keV, causing radiation hazards to operators. A framework for inspecting X-ray emission hazards during laser material processing has yet to be developed. One requirement for conducting radiation protection inspections is using a reference scenario, i.e., laser settings and process parameters that will lead to an almost constant and high level of X-ray emissions. To study the feasibility of setting up a reference scenario in practice, ambient dose rates and photon energies were measured using traceable measurement equipment in an industrial setting at SCHOTT AG. Ultrashort pulsed (USP) lasers with a maximum average power of 220 W provided the opportunity to measure X-ray emissions at laser peak intensities of up to 3.3 × 1015 W/cm2 at pulse durations of ~1 ps. The results indicate that increasing the laser peak intensity is insufficient to generate high dose rates. The investigations were affected by various constraints which prevented measuring high ambient dose rates. In this work, a list of issues which may be encountered when performing measurements at USP-laser machines in industrial settings is identified.
Influence of Wood Fly Ash on Concrete Properties through Filling Effect Mechanism
Authors: Gabrijel Ivan , Jelčić Rukavina Marija , Štirmer Nina
Published: December 2021

This paper presents the results of an experimental study aimed at determining the influence of wood fly ash (WFA) from three Croatian power plants on the properties of concrete. First, the chemical and physical properties of WFA’s were determined. It was found that these properties are highly influenced by combustion technology, the type and parts of wood used as fuel, and the local operating conditions. Subsequently, workability, heat of hydration, stiffness development, 28-day compressive strength, apparent porosity, and capillary absorption were determined on concrete mixes prepared with WFA as cement replacement from 5–45% by weight. Cement replacement up to 15% with the finest WFA accelerated hydration, stiffness development, and increased compressive strength of concrete up to 18%, while replacement with coarser WFA’s led to a decrease in compressive strength of up to 5% and had more gradual heat liberation. The dominant effect that could explain these findings is attributed to the filler and filling effect mechanisms. At the same time replacement content of up to 45% had very little effect on capillary absorption and could give concrete with sufficiently high compressive strength to be suitable for construction purposes.
Preparation of Polystyrene Microsphere-Templated Porous Monolith for Wastewater Filtration
Authors: Ibadat Nur Faezah , Saallah Suryani , Ongkudon Clarence M. , Misson Mailin
Published: December 2021

Porous monoliths prepared using templates are highly sought after for filtration applications due to their good mass transport properties and high permeability. Current templates, however, often lead to the formation of dead-end pores and irregular pore distributions, which reduce the efficiency of the substrate flow across the monolith column. This study focused on the preparation of a microsphere-templated porous monolith for wastewater filtration. The optimal template/monomer ratio (50:50, 60:40, 70:30) was determined, and appropriate template removal techniques were assessed for the formation of homogenous pores. The physicochemical characteristics and pore homogeneity of the monoliths were examined. The 60:40 ratio was determined to result in monoliths with homogeneous pore distributions ranging from 1.9 μm to 2.3 μm. SEM and FTIR investigations revealed that solvent treatment was effective for removing templates from the resulting solid monolith. The water quality assessments revealed reductions in the turbidity and the total number of suspended particles in the tested wastewater of up to 96–99%. The findings of this study provide insightful knowledge regarding the fabrication of monoliths with homogenous pores that are beneficial for wastewater treatment.
Electroplating Deposition of Bismuth Absorbers for X-ray Superconducting Transition Edge Sensors
Authors: Chen Jian , Li Jinjin , Xu Xiaolong , Wang Zhenyu , Guo Siming , Jiang Zheng , Gao Huifang , Zhong Qing , Zhong Yuan , Zeng Jiusun , Wang Xueshen
Published: December 2021

An absorber with a high absorbing efficiency is crucial for X-ray transition edge sensors (TESs) to realize high quantum efficiency and the best energy resolution. Semimetal Bismuth (Bi) has shown greater superiority than gold (Au) as the absorber due to the low specific heat capacity, which is two orders of magnitude smaller. The electroplating process of Bi films is investigated. The Bi grains show a polycrystalline rhombohedral structure, and the X-ray diffraction (XRD) patterns show a typical crystal orientation of (012). The average grain size becomes larger as the electroplating current density and the thickness increase, and the orientation of Bi grains changes as the temperature increases. The residual resistance ratio (RRR) (R300 K/R4.2 K) is 1.37 for the Bi film (862 nm) deposited with 9 mA/cm2 at 40 °C for 2 min. The absorptivity of the 5 μm thick Bi films is 40.3% and 30.7% for 10 keV and 15.6 keV X-ray radiation respectively, which shows that Bi films are a good candidate as the absorber of X-ray TESs.
Wire Laser Metal Deposition Additive Manufacturing of Duplex Stainless Steel Components—Development of a Systematic Methodology
Authors: Baghdadchi Amir , Hosseini Vahid A. , Valiente Bermejo Maria Asuncion , Axelsson Björn , Harati Ebrahim , Högström Mats , Karlsson Leif
Published: December 2021

A systematic four-stage methodology was developed and applied to the Laser Metal Deposition with Wire (LMDw) of a duplex stainless steel (DSS) cylinder > 20 kg. In the four stages, single-bead passes, a single-bead wall, a block, and finally a cylinder were produced. This stepwise approach allowed the development of LMDw process parameters and control systems while the volume of deposited material and the geometrical complexity of components increased. The as-deposited microstructure was inhomogeneous and repetitive, consisting of highly ferritic regions with nitrides and regions with high fractions of austenite. However, there were no cracks or lack of fusion defects; there were only some small pores, and strength and toughness were comparable to those of the corresponding steel grade. A heat treatment for 1 h at 1100 °C was performed to homogenize the microstructure, remove nitrides, and balance the ferrite and austenite fractions compensating for nitrogen loss occurring during LMDw. The heat treatment increased toughness and ductility and decreased strength, but these still matched steel properties. It was concluded that implementing a systematic methodology with a stepwise increase in the deposited volume and geometrical complexity is a cost-effective way of developing additive manufacturing procedures for the production of significantly sized metallic components.
Survivability of Suddenly Loaded Arrays of Micropillars
Authors: Derda Tomasz , Domanski Zbigniew
Published: December 2021

When a multicomponent system is suddenly loaded, its capability of bearing the load depends not only on the strength of components but also on how a load released by a failed component is distributed among the remaining intact ones. Specifically, we consider an array of pillars which are located on a flat substrate and subjected to an impulsive and compressive load. Immediately after the loading, the pillars whose strengths are below the load magnitude crash. Then, loads released by these crashed pillars are transferred to and assimilated by the intact ones according to a load-sharing rule which reflects the mechanical properties of the pillars and the substrate. A sequence of bursts involving crashes and load transfers either destroys all the pillars or drives the array to a stable configuration when a smaller number of pillars sustain the applied load. By employing a fibre bundle model framework, we numerically study how the array integrity depends on sudden loading amplitudes, randomly distributed pillar strength thresholds and varying ranges of load transfer. Based on the simulation, we estimate the survivability of arrays of pillars defined as the probability of sustaining the applied load despite numerous damaged pillars. It is found that the resulting survival functions are accurately fitted by the family of complementary cumulative skew-normal distributions.