bluuebunny/crossref_metadata_2025 huggingface dataset:
Europese harmonisatie van online en op afstand verkoop van zaken en de levering van digitale inhoud (II)
Authors: Loos M.B.M.
Published: May 2016

Europese harmonisatie van online en op afstand verkoop van zaken en de levering van digitale inhoud (II)

Op 9 december 2015 heeft de Europese Commissie een voorstel ingediend voor een richtlijn voor de levering van digitale inhoud. Het richtlijnvoorstel kent een ruim toepassingsgebied en is onder voorwaarden ook van toepassing op overeenkomsten waarbij de consument niet met geld, maar met de verstrekking van persoonsgegevens betaalt. Naast een bespreking van dit toepassingsgebied wordt vooral aandacht besteed aan de conformiteit van digitale inhoud en de remedies bij non-conformiteit.

Voorstel voor een Richtlijn van het Europees Parlement en de Raad betreffende bepaalde aspecten van overeenkomsten voor de online-verkoop en andere verkoop op afstand van goederen, COM(2015)635 final

Voorstel voor een Richtlijn van het Europees Parlement en de Raad betreffende bepaalde aspecten van overeenkomsten voor de levering van digitale inhoud, COM(2015)634 final
“Blackout” - A Extinção das Cooperativas de Eletrificação Rural do Brasil pela ANEEL
Authors: Dos Anjos Júnior Eufrásio Vieira , Da Silva Ricardo Moreira , Cavalcante Carlos Eduardo
Published: May 2016

Objetivou-se analisar a luz da Teoria da Ecologia Populacional o fenômeno de desaparecimento das cooperativas de eletrificação rural (CER) no Brasil. A Teoria da Ecologia introduz o ambiente externo como um dos aspectos determinantes do (in)sucesso das organizações. Trata-se de uma pesquisa-ação, longitudinal abrangendo o período 2004 até 2013. Teve como unidades de estudo quinze CER’s, caracterizando-se como pesquisa intervencionista-experimental, visto que os pesquisadores participaram das reuniões na Câmara Federal dos Deputados, Senado, ANEEL, MME e Agências Reguladoras Estaduais, inclusive emitindo relatórios conjuntos. Conclui-se que durante o processo de encerramento das CER as normativas e ações exigidas pela ANEEL para sua regularização, já carregavam a intenção de extinção, o que direcionou o setor elétrico brasileiro para um ambiente econômico de monopólio das grandes concessionárias de distribuição de energia.
Primary meningococcal conjunctivitis: an unusual case of transmission by saliva
Authors: Dryden Alexander W.S. , Rana Mrinal , Pandey Pravin
Published: May 2016

A 49-year-old diabetic man presented with a 2-day history of a painful right eye associated with a purulent discharge. Prior to becoming symptomatic, he reported that someone spat at him, resulting in direct contact between the saliva and his affected eye. Gram stain revealed numerous leucocytes with Gram-negative diplococci, and culture yielded Neisseria meningitidis (serogroup C). There was no evidence of any systemic infection, and blood cultures were negative for any growth. He was treated for primary meningococcal conjunctivitis (PMC) with intensive topical antibiotic eyedrops as well as systemic antibiotics. One week after commencing treatment he remained systemically well and his symptoms had fully resolved.
Recherche-action, ou connaissance pour l’action ? Quelques points de repère et trois positions de principe
Authors: Franck Robert
Published: May 2016

Il existe diverses manières de relier la recherche et l’action. On doit à ce propos poser au moins deux questions :

Il faut commencer par envisager les allégeances du chercheur en vue de déterminer à quelles conditions les intérêts et les préoccupations du chercheur ne porteront pas préjudice à ceux qui ont affaire à lui. Il faut ensuite que s’établisse un rapport contractuel entre le chercheur et les gens auprès desquels est menée une recherche-action et que ces derniers puissent exercer un contrôle démocratique sur le déroulement de la recherche.

Action et recherche peuvent-elles fusionner ? Que devient alors le savoir ? Sans la constitution d’un savoir disposant d’une relative autonomie par rapport à chaque situation particulière, on se prive des armes de la critique que sont la raison et l’expérience. Ce sont là les repères contre l’arbitraire de la recherche et du chercheur.
Savoir scientifique, politiques gouvernementales et démocratie
Authors: Nelkin Dorothy , Huston Lorne
Published: May 2016

L’effet du savoir scientifique sur un ensemble de valeurs, définies de façon plutôt vague, que l’on désigne sous le nom de « démocratie », continue de susciter des passions et des analyses, comme en témoignent les revendications populaires en faveur d’une plus grande participation de la population aux processus de prises de décision relatives aux dossiers scientifiques. De telles revendications soulignent l’importance du débat politique dans des domaines qui furent jusqu’ici réservés à la recherche scientifique.

Cependant, un débat éclairé ne peut avoir lieu que dans la mesure où les participants ont une certaine compétence dans le domaine technique, ne serait-ce que pour pouvoir évaluer les « impératifs techniques » des choix réels qui se posent. Le savoir scientifique — tout comme la terre, la force de travail et le capital — constitue une ressource, voire une marchandise. La possibilité d’utiliser et de contrôler cette ressource a des conséquences importantes sur la distribution du pouvoir politique dans les sociétés démocratiques.
Les relations de guichet : interactions de classes et classements sociaux
Authors: Siblot Yasmine
Published: May 2016

Cet article examine la pertinence d’une analyse en termes d’interactions de classes pour l’étude des relations entre des agents d’institutions publiques et la population d’un quartier populaire, à partir d’une enquête menée dans les permanences d’un centre social. La caractérisation des positions sociales relatives est complexe, du fait de la disparité des trajectoires des agents, et de la différenciation interne à la population. Une gamme de relations, allant de l’entraide à la mise à distance, s’instaure ainsi entre les employées et leur public. Des processus de cristallisation de positionnements sociaux se déroulent néanmoins au sein des permanences, pour les agents comme pour les habitants. En particulier, la distance entre employées et habitants les plus précaires s’accuse, confortant la perception des clivages entre fractions de la population.
Phénomène d’acculturation et santé du migrant
Authors: Alfatli Jacqueline , Alfatli Nazim
Published: May 2016

Le migrant traduit dans son corps les difficultés de son acculturation. C’est à partir de cette compréhension de la dimension culturelle des maladies du migrant que l’équipe médicale peut intervenir. La Maison médicale de GRACE-HOLLOGNE, quartier populaire de Liège composé à 40 % d’habitants immigrés vise à intégrer ceux-ci dans un processus de prise en charge collective, à l’intérieur du quartier et d’une communauté. Autogestion, conseils de patients, travail de groupe, approche culturelle de la maladie physique et mentale caractérisent le fonctionnement de cette maison médicale.
La ville continue. Montréal et l’expérience transculturelle de Vice Versa
Authors: Tassinari Lamberto
Published: May 2016

Vice Versa est un magazine original lancé au Québec en 1983 par un groupe d’intellectuels italiens. Ce projet de magazine transculturel (plutôt qu’ethnique) est porteur de tous les dilemmes, frustrations et espoirs des auteurs qui y participent et de leur condition d’immigrés, mais surtout il véhicule, à travers une critique de l’ethnicité, l’ambition d’un nouvel humanisme. La nouveauté de cet humanisme découle de l’idée du déclin des cultures majoritaires, et Montréal, par ses caractéristiques, pourrait en être le creuset privilégié.
Les réseaux familiaux transnationaux supports aux initiatives en matière de santé chez les Gitans catalans
Authors: Missaoui Lamia
Published: May 2016

L’article relate comment les Gitans catalans sont à même de développer des initiatives en matière de santé. Alors même que les services médico-sociaux signalent unanimement leur grande difficulté à gérer leurs missions auprès de ces populations et que les comportements collectifs tsiganes en matière de consultation et de suivi médical sont désignés comme anarchiques, ignorants de l’organisation territorialisée des institutions de santé, alors même que le sida, lié à de fortes consommations d’héroïne injectée, décimerait des clans gitans. La cartographie des déplacements pour soins suggère que, si les traditionnels nomadismes ont disparu, de vastes réseaux territoriaux transfrontaliers sont toujours activés et permettent des mobilisations inconnues parmi les autres populations.
Impact of embedded Mn nanodots on resistive switching characteristics of Si-rich oxides as measured in Ni-electrode metal–insulator–metal diodes
Authors: Arai Takashi , Ohta Akio , Makihara Katsunori , Miyazaki Seiichi
Published: May 2016

We studied the formation of high-density Mn nanodots (NDs) by remote H2 plasma (H2-RP) treatment and investigated how the embedding of Mn NDs affects the resistive switching properties of Si-rich oxides (SiO
x
) because it is expected that NDs will trigger the formation of the conductive filament path in SiO
x
. We fabricated Mn NDs with different ND areal densities by exposing an ultrathin Mn layer on the SiO
x
/Ni bottom electrode to H2-RP without external heating. After the deposition of SiO
x
as a resistive switching layer and the fabrication of Ni top electrodes, resistive switching behaviors of metal–insulator–metal (MIM) diodes were characterized from current–voltage (I–V) curves and compared with the results obtained from samples of SiO
x
without Mn NDs and with an ultrathin Mn layer instead. The embedding of Mn NDs in SiO
x
was found to be effective in increasing the ON/OFF ratio in resistance and reducing the variation in operation voltage.
Oxidation of CuSn alloy nanotree and application for gas sensors
Authors: Kaneko Naoto , Shimizu Tomohiro , Tada Yoshihiro , Shingubara Shoso
Published: May 2016

The CuSn alloy nanotree formed by DC electroplating is a true three-dimensional (3D) structure with many branches that separate the trunk perpendicularly. We carried out the oxidation of CuSn nanotrees in atmosphere in order to study the possibility of such nanotrees for application to sensors. It was confirmed that the oxygen concentration in the CuSn nanotree oxide increased with temperature and reached 40 at. % at 350 °C. The optical reflectance spectra of the CuSn nanotree oxide formed at 250 °C showed a 3–4% reflectance in the wavelength range between 400 and 900 nm, and its behavior differed from those of Cu and Sn oxides formed at 250 °C. The temperature dependence of electrical resistivity for the CuSn nanotree oxide showed a typical semiconductor behavior. By the introduction of H2, O2, N2, and CO gases into the chamber, the resistance of the CuSn nanotree oxide responded against H2 most sensitively, as well as against O2 and CO gases. From the resistance change tendency, it is strongly suggested that the CuSn nanotree oxide is a p-type semiconductor, because it shows an increase in conductivity caused by the adsorption of a negative charge such as O−. However, the conductivity decreases with the adsorption of a positive charge such as H+. The present study suggests the high potential of the CuSn nanotree oxide as a gas sensor, since it has a very high surface-to-volume ratio.
Thermal reliability of a bilayer of Ni(P)/Cu as a diffusion barrier for Cu/Sn/Cu bonding
Authors: Lee Byunghoon , Jeon Haseok , Gan Chee Lip , Lee Hoo-Jeong
Published: May 2016

This study examines the effects of barrier layers on the aging behavior of Cu/Sn bonding for three-dimensional (3D) integration. We compare the behavior of different bonding structures [Cu/Sn with no barrier, Ni(P) barrier, and Ni(P)/Cu bilayer barrier] after aging samples at 150 °C for long durations (up to 900 h). While the samples with no barrier allowed extensive Cu diffusion and the formation of Kirkendall voids, the Ni(P) barrier samples broke down as Ni outdiffused into the Sn layer. The bilayer barrier samples demonstrated excellent aging stability with the thin Ni(P)/Cu bilayer effectively suppressing Ni outdiffusion.
The impact of horizontal resolution of density field on the calculation of the Atlantic meridional overturning circulation at 34°S
Authors: Stepanov Vladimir N. , Iovino Doroteaciro , Masina Simona , Storto Andrea , Cipollone Andrea
Published: May 2016

The Atlantic meridional overturning circulation and meridional heat transport (hereafter the AMOC and MHT) at 34°S as simulated by global 1/16° eddy‐rich (henceforth GLOB16) and ¼° eddy‐permitting (GLOB4) models are compared with observational estimates. Three different methods are used for calculating the modeled AMOC: the first method (MOCmod) is based on simulated velocity fields, while the second (MOCob) relies on the same assumptions as available observed‐derived estimates. The third method (MOCob2) is also based on hydrostatic and geostrophic relationships, but relative to a barotropic circulation instead of the definition of velocity at a specific reference depth. All methods correctly reproduce the time‐mean GLOB16 AMOC strength, but the value of the non‐Ekman component of the GLOB16 AMOC is only about 75% of the observed‐derived estimate. The GLOB16 MHT is also significantly less than observation value (slightly more than 60% of the observed). However, the mean AMOC and MHT values at 34°S obtained with coarser resolution GLOB4 model are comparable with the observed‐derived estimates. Possible causes for the differences between the eddy‐rich model and observational data are studied. It is shown that the density field from the eddy‐rich model has high temporal variability along 34°S with spatial scale of about two hundred km that can be due to mesoscale variations, caused by Agulhas “leakage.” This results in the decrease of the mean meridional geostrophic velocity, which leads to smaller values of the AMOC and MHT in GLOB16: subsampling GLOB16 density on ¼° or ½° longitude grid along 34°S for MOCob calculation significantly increases the AMOC values. The findings in this paper provide guidance in understanding AMOC and MHT dissimilarities between observation‐based estimates and eddy‐rich ocean models at 34°S.
Cantor dielectric resonators for microwave waveguide applicators
Authors: Chiadini Francesco , Diovisalvi Annunziata , Fiumara Vincenzo , Scaglione Antonio
Published: May 2016

Dielectric resonators are structures consisting of a stack of two (or more) different dielectric materials arranged in a certain sequence. The present paper is focused on Cantor dielectric resonators whose construction is determined according to the fractal Cantor scheme. Cantor microwave applicators can be realized by inserting a Cantor resonator in a metallic rectangular waveguide. This applicator can be useful for processing low loss materials due to the field localization occurring in the Cantor resonator. Investigations for different dielectric materials constituting the resonator have been done. Experimental results obtained using a prototype of the Cantor applicator show a good agreement between measured and theoretically calculated field amplitude profiles.
Electron scale structures and magnetic reconnection signatures in the turbulent magnetosheath
Authors: Yordanova E. , Vörös Z. , Varsani A. , Graham D. B. , Norgren C. , Khotyaintsev Yu. V. , Vaivads A. , Eriksson E. , Nakamura R. , Lindqvist P.‐A. , Marklund G. , Ergun R. E. , Magnes W. , Baumjohann W. , Fischer D. , Plaschke F. , Narita Y. , Russell C. T. , Strangeway R. J. , Le Contel O. , Pollock C. , Torbert R. B. , Giles B. J. , Burch J. L. , Avanov L. A. , Dorelli J. C. , Gershman D. J. , Paterson W. R. , Lavraud B. , Saito Y.
Published: May 2016

Collisionless space plasma turbulence can generate reconnecting thin current sheets as suggested by recent results of numerical magnetohydrodynamic simulations. The Magnetospheric Multiscale (MMS) mission provides the first serious opportunity to verify whether small ion‐electron‐scale reconnection, generated by turbulence, resembles the reconnection events frequently observed in the magnetotail or at the magnetopause. Here we investigate field and particle observations obtained by the MMS fleet in the turbulent terrestrial magnetosheath behind quasi‐parallel bow shock geometry. We observe multiple small‐scale current sheets during the event and present a detailed look of one of the detected structures. The emergence of thin current sheets can lead to electron scale structures. Within these structures, we see signatures of ion demagnetization, electron jets, electron heating, and agyrotropy suggesting that MMS spacecraft observe reconnection at these scales.
Ring Oscillators Based on ZnO Channel JFETs and MESFETs
Authors: Klüpfel Fabian J. , von Wenckstern Holger , Grundmann Marius
Published: May 2016

Ring oscillator circuits based on junction field‐effect transistors as well as metal–semiconductor field‐effect transistors with ZnO channels are presented. Single stage delay times down to 110 ns are observed. The experimental oscillation frequencies are related to easily measurable device properties by a simple analytical model. This work proves the feasibility of low power oxide based circuits with Schottky diode and bipolar (pn‐) diode gates since both approaches provide significantly lower operation voltages at similar frequencies compared to previously reported oxide thin film transistors based on insulating gates.
Microcephalic primordial dwarfism in an Emirati patient with PNKP mutation
Authors: Nair Pratibha , Hamzeh Abdul Rezzak , Mohamed Madiha , Saif Fatima , Tawfiq Nafisa , El Halik Majdi , Al‐Ali Mahmoud Taleb , Bastaki Fatma
Published: May 2016

Microcephaly is a rare neurological condition, both in isolation and when it occurs as part of a syndrome. One of the syndromic forms of microcephaly is microcephaly, seizures and developmental delay (MCSZ) (OMIM #613402), a rare autosomal recessive neurodevelopmental disorder with a range of phenotypic severity, and known to be caused by mutations in the polynucleotide kinase 3′ phosphatase (PNKP) gene. The PNK protein is a key enzyme involved in the repair of single and double stranded DNA breaks, a process which is particularly important in the nervous system. We describe an Emirati patient who presented with microcephaly, short stature, uncontrollable tonic‐clonic seizures, facial dysmorphism, and developmental delay, while at the same time showing evidence of brain atrophy and agenesis of the corpus callosum. We used whole exome sequencing to identify homozygosity for a missense c.1385G > C (p.Arg462Pro) mutation in PNKP in the patient and heterozygosity for this mutation in her consanguineous parents. The Arg 462 residue forms a part of the lid subdomain helix of the P‐loop Kinase domain. Although our patient's phenotype resembled that of MCSZ, the short stature and evidence of brain atrophy distinguished it from other classic cases of the condition. The report raises the question of whether to consider this case as an atypical variant of MCSZ or as a novel form of microcephalic primordial dwarfism. © 2016 Wiley Periodicals, Inc.
Epoxidized dimeric acid methyl ester derived from rubber seed oil and its application as secondary plasticizer
Authors: Chen Jie , Li Xiaoying , Wang Yigang , Huang Jinrui , Li Ke , Nie Xiaoan , Jiang Jianchun
Published: May 2016

A novel plasticizer epoxidized dimeric acid methyl ester (EDAMe) based on rubber seed oil was synthesized. Chemical structure of EDAMe was characterized by Fourier transform infrared (FTIR) and gel permeation chromatography (GPC). Effects of EDAMe as secondary plasticizer and its substitution of commercial plasticizer dioctyl terephthalate (DOTP) in soft poly(vinyl chloride) (PVC) films were studied. The thermal properties, mechanical properties and migration stabilities of PVC films were explored with DMA, TG, TG–FTIR, dynamic thermal stability analysis, tensile and migration tests. The results indicated that the epoxidized rubber seed oil based ester has significantly higher thermal stability than DOTP. When DOTP was substituted with 20% (m/m) EDAMe, the results of initial decomposition temperature (Ti), 10% and 50% mass loss temperatures (T10 and T50), and the first maximum weight‐loss temperature rate (TP1) reached 267.2  °C, 263.5 °C, 307.3 °C and 298.9 °C, respectively. Furthermore, flexibility of the obtained PVC films enhanced significantly with the adding of EDAMe. The migration stabilities of EDAMe was also investigated and showed good migration resistance. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43668.
Thermoplastic rubber/PP elastomers toward extremely low thermal expansion
Authors: Zhang Kun , Zhang Dongge , Su Lili , Jiang Lili , Jiang Jiandi , Wu Guozhang
Published: May 2016

Fine regulation of the microstructure of rubber/polypropylene (PP) alloys could remarkably reduce the coefficient of linear thermal expansion (CLTE) while retaining the mechanical properties similar to those of thermoplastic elastomers. Rubber/PP elastomers with different morphologies were successfully prepared by controlling the appropriate rubber type, viscosity ratio, and processing method. The CLTE of the polymer alloy parallel to the microlayer directions was considerably reduced when the rubber domains were deformed into microlayers and co‐continuous with plastic domains. The thickness of the PP layers played a crucial role on CLTE reduction. The CLTE considerably decreased with reduced thickness of the PP layer. The sample with a co‐continuous microlayer structure exhibited good flexibility, high elongation, low hardness, and permanent deformation. Thus, low‐thermal‐expansion elastomer materials may have wide applications. Stress relaxation and strain recovery of the ethylene–propylene–diene terpolymer/PP (70/30 wt %) blend were investigated to further clarify the influence of co‐continuous microlayer structure on mechanical properties. Anisotropic mechanical properties were consistent with the morphology. Results of the stress relaxation behavior test would provide further support to the mechanism of the low thermal expansion of blends with co‐continuous microlayer structure. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43902.
Exploring eye movements of experienced and novice readers of medical texts concerning the cardiovascular system in making a diagnosis
Authors: Vilppu Henna , Mikkilä‐Erdmann Mirjamaija , Södervik Ilona , Österholm‐Matikainen Erika
Published: May 2016

This study used the eye‐tracking method to explore how the level of expertise influences reading, and solving, two written patient cases on cardiac failure and pulmonary embolus. Eye‐tracking is a fairly commonly used method in medical education research, but it has been primarily applied to studies analyzing the processing of visualizations, such as medical images or patient video cases. Third‐year medical students (n = 39) and residents (n = 13) read two patient case texts in an eye‐tracking laboratory. The analysis focused on the diagnosis made, the total visit duration per text slide, and eye‐movement indicators regarding task‐relevant and task‐redundant areas of the patient case text. The results showed that almost all participants (48/52) made the correct diagnosis of the first patient case, whereas all the residents, but only 17 students, correctly diagnosed the second case. The residents were efficient patient‐case‐solvers: they reached the correct diagnoses, and processed the cases faster and with a lower number of fixations than did the students. Further, the students and residents demonstrated different reading patterns with regard to which slides they proportionally paid most attention. The observed differences could be utilized in medical education to model expert reasoning and to teach the manner in which a good medical text is constructed. Eye‐tracking methodology appears to have a great deal of potential in evaluating performance and growing diagnostic expertise in reading medical texts. However, further research using medical texts as stimuli is required. Anat Sci Educ 10: 23–33. © 2016 American Association of Anatomists.
Lineage‐specific genomics: Frequent birth and death in the human genome
Authors: Young Robert S.
Published: May 2016

Frequent evolutionary birth and death events have created a large quantity of biologically important, lineage‐specific DNA within mammalian genomes. The birth and death of DNA sequences is so frequent that the total number of these insertions and deletions in the human population remains unknown, although there are differences between these groups, e.g. transposable elements contribute predominantly to sequence insertion. Functional turnover – where the activity of a locus is specific to one lineage, but the underlying DNA remains conserved – can also drive birth and death. However, this does not appear to be a major driver of divergent transcriptional regulation. Both sequence and functional turnover have contributed to the birth and death of thousands of functional promoters in the human and mouse genomes. These findings reveal the pervasive nature of evolutionary birth and death and suggest that lineage‐specific regions may play an important but previously underappreciated role in human biology and disease.
Engineering of nanoparticle size via electrohydrodynamic jetting
Authors: Rahmani Sahar , Ashraf Sumaira , Hartmann Raimo , Dishman Acacia F. , Zyuzin Mikhail V. , Yu Chris K. J. , Parak Wolfgang J. , Lahann Joerg
Published: May 2016

Engineering the physical properties of particles, especially their size, is an important parameter in the fabrication of successful carrier systems for the delivery of therapeutics. Here, various routes were explored for the fabrication of particles in the nanosize regime. It was demonstrated that the use of a charged species and/or solvent with high dielectric constant can influence the size and distribution of particles, with the charged species having a greater effect on the size of the particles and the solvent a greater effect on the distribution of the particles. In addition to the fabrication of nanoparticles, their fractionation into specific size ranges using centrifugation was also investigated. The in vitro particle uptake and intracellular transport of these nanoparticles was studied as a function of size and incubation period. The highest level of intralysosomal localization was observed for the smallest nanoparticle group (average of 174 nm), followed by the groups with increasing sizes (averages of 378 and 575 nm), most likely due to the faster endosomal uptake of smaller particles. In addition, the internalization of nanoparticle clusters and number of nanoparticles per cell increased with longer incubation periods. This work establishes a technological approach to compartmentalized nanoparticles with defined sizes. This is especially important as relatively subtle differences in size can modulate cell uptake and determine intercellular fate. Future work will need to address the role of specific targeting ligands on cellular uptake and intracellular transport of compartmentalized nanoparticles.
ChemInform Abstract: Catalytic Oxidation of NO to NO2 Over a H‐Mordenite Catalyst.
Authors: BRANDIN J. G. M. , ANDERSSON L. H. , ODENBRAND C. U. I.
Published: May 2016

The kinetics of the catalytic oxidation of NO is found to be first order with respect to the NO partial pressure.
ChemInform Abstract: Importance of Surface Reactions in the Photochemistry of ZnS Colloids.
Authors: DUNSTAN D. E. , HAGFELDT A. , ALMGREN M. , SIEGBAHN H. O. G. , MUKHTAR E.
Published: May 2016

The time‐dependence of the photocorrosion of colloidal ZnS is studied by time‐resolved and static fluorescence spectroscopy, and ESCA.
ChemInform Abstract: Spectroscopical and Electrochemical Behavior of New Mixed‐Ligand Cyclometalated Rh(III) Complexes.
Authors: SANDRINI D. , MAESTRI M. , CIANO M. , MAEDER U. , VON ZELEWSKY A.
Published: May 2016

The absorption spectra, luminescence spectra, excited‐state lifetimes, and electrochemical behavior of the title complexes (I) and (II) are investigated.
ChemInform Abstract: N‐Amination of 3‐Amino‐1,2,4‐triazole with Hydroxylamine‐O‐sulfonic Acid: Synthesis of 1,5‐Diamino‐1,2,4‐triazole.
Authors: SALAZAR L. , ESPADA M. , AVENDANO C. , ELGUERO J.
Published: May 2016

Treatment of the triazole (I) with the sulfonic acid (II) at 0 °C (45 min) increases the regioselectivity with respect to the desired product (III), but the yield is increased.
ChemInform Abstract: Dimroth Rearrangement of Pyrimido(4′,5′:4,5)thieno(2,3‐b)quinolines.
Authors: RAJ T. T. , AMBEKAR S. Y.
Published: May 2016

Reaction of the 3‐amino‐2‐thiophenecarbonitrile (I) with triethyl orthoformate (II) gives the derivative (III) which is further coupled with amines such as (IV) to form the pyrimidine derivative (V).
ChemInform Abstract: Reactions of Cyclic Halo Ketones with Trivalent Phosphorus Compounds.
Authors: GRISHINA L. N. , GAIFULLINA O. E. , DUBININA N. P. , SHAIDULLINA V. G. , BAYANDINA E. V.
Published: May 2016

7,7‐Dichlorobicyclo(3.2.0)hept‐2‐en‐6‐one (I) reacts with the dialkyl phosphites (II) to give the phosphonates (III), which are O‐acylated with acetic anhydride (IV), producing the acetates (V).
ChemInform Abstract: Recent Work on the Synthesis of Phosphonate‐Containing, Bone‐Active Heterocycles.
Authors: EBETINO F. H. , DEGENHARDT C. R. , JAMIESON L. A. , BURDSALL D. C.
Published: May 2016

The diol ditosylates (I) undergo ring closure reaction with tetraisopropyl methylenebisphosphonate (II) in toluene to give the tetraisopropyl cycloalkane‐1,1‐bisphosphonates (III) which are hydrolyzed with hydrochloric acid to form the cycloalkane‐1,1‐bisphosphonic acids (IV).
ChemInform Abstract: Synthesis, Structure, and Reactivity of Metallacycle‐Carbene and ‐Bis(carbene) Complexes. A New Intramolecular Carbene‐Carbene Coupling Process.
Authors: O'CONNOR J. M. , PU L. , RHEINGOLD A. L.
Published: May 2016

The cationic chloride abstraction product (III) from (I) reacts with 3‐butyn‐1‐ol (IVa) or 4‐pentyn‐2‐ol (IVb) to give the iridiacyclopentadiene‐carbene complexes (Va) and (Vb).
ChemInform Abstract: Structure of L‐1‐Benzyl‐4‐hydroxymethyl‐2‐azetidinone.
Authors: LEE C. H. , CHO S.‐I. , KIM E. , SHIN H.‐S. , RUBLE J. R. , CRAVEN B. M.
Published: May 2016

The X‐ray structure of the title compound (I) (space group P212121, Z=4) is reported.
ChemInform Abstract: Ab initio MO Study on Adsorption of a Hydrogen Molecule onto MgO(100) Surface
Authors: KOBAYASHI H. , YAMAGUCHI M. , ITO T.
Published: May 2016

is carried out using a Mg4O4 cluster model.
ChemInform Abstract: Outer‐Sphere and Inner‐Sphere Processes in Reductive Elimination. Direct and Indirect Electrochemical Reduction of Vicinal Dibromoalkanes.
Authors: LEXA D. , SAVEANT J.‐M. , SCHAEFER H. J. + , SU K.‐B. , VERING B. , WANG D. L.
Published: May 2016

Vicinal dibromides such as (I) and (III)‐(V) are reduced by outer‐sphere reagents such as carbon electrodes or aromatic anion radicals according to an "ET" mechanism.
ChemInform Abstract: Synthesis and Properties of Aminoarylsulfonanilide‐3′,5′‐dicarboxylic Acids.
Authors: BLUS K. , KRASKA J.
Published: May 2016

The sulfonanilides (IV) and (VI) are synthesized as outlined in the reaction scheme.
ChemInform Abstract: Synthesis of Fluorescent 2,3‐Fused Coumarin Derivatives.
Authors: RAJAGOPAL R. , SHENOY V. U. , PADMANABHAN S. , SEQUERIA S. , SESHADRI S.
Published: May 2016

Reaction of the iminobenzopyrancarboxamides (IIIa) and (IIIb) with the phosphorochloridothioate (IV) gives the anellated diazaphosphorines (V) which form yellow shades on polyester and give average tinctorial power and low light fastness.
ChemInform Abstract: Chelation Control by Phosphite Esters in Rhodium‐Catalyzed Hydroformylation.
Authors: JACKSON W. R. , PERLMUTTER P. , TASDELEN E. E.
Published: May 2016

Hydroformylation of the unsaturated phosphites (I), (VI), or (IX) in the presence of a rhodium(II) catalyst yields the aldehydes (IV), (VII), or (X) and (XI).
ChemInform Abstract: The Proton‐Catalyzed Transformation of a Cobaltacyclopentadiene into a η4‐Cyclobutadiene Cobalt Complex.
Authors: BRANDT L. , GREEN M. , PARKINS A. W.
Published: May 2016

H+ addition to the diene system of (I) gives the cationic complex (II), isolated at ‐30 °C, which rearranges to the unusual isomer (III), stabilized by intramolecular phosphine addition.
ChemInform Abstract: Some Novel Heptamethine Pyrylium Dyes. Structure and Photostability.
Authors: LUO W. , ZHU Z. , YAO Z. , HE M.
Published: May 2016

A series of new heptamethine pyrylium dyes such as (III) is prepared.
ChemInform Abstract: RbV3P4O17+x (x = 0.14): A Novel Mixed‐Valence Vanadium Pyrophosphate.
Authors: LII K. H. , LEE C. S.
Published: May 2016

The nonstoichiometric title compound is prepared by reaction of Rb4V2O7, V2O5, and P2O5 (1:5:8, 650 °C, sealed silica tube, 2 d and 700 °C, air, 2 d).
ChemInform Abstract: Palladium(0)‐ and Nickel(0)‐Catalyzed “Metallo‐Ene‐Type” Cyclizations: Stereodirecting Resident Chirality.
Authors: OPPOLZER W. , KELLER T. H. , KUO D. L. , PACHINGER W.
Published: May 2016

The acetoxymethyl 1,6‐dienes (I) and (III) undergo nickel‐mediated ring closure, forming the methylene vinyl pentacycles (II) or (IV) with predominance of the trans‐isomers.
ChemInform Abstract: Bicyclo(3.1.0)hex‐1(6)‐enes: Reactivity of the 3‐Oxa Derivative.
Authors: HALTON B. , BRIDLE J. H. , LOVETT E. G.
Published: May 2016

The dichlorooxabicyclo(3.1.0)hexane (Ia) and the thia analogue (Ib) react with tert‐butoxide to form the bridgehead olefins (II) which are trapped by cycloaddition reaction with diphenylisobenzofuran (III) or furan (V), forming the polycycles (IV) or (VI).
ChemInform Abstract: A Claisen Rearrangement Route to (.+‐.)‐α‐Cuparenone.
Authors: SRIKRISHNA A. , KRISHNAN K.
Published: May 2016

Key step in the construction of the cyclopentenone ring in (V) is a Claisen rearrangement in the step (I) → (III).
ChemInform Abstract: Characterization of Vanadium Oxide Catalysts Supported on SnO2 by 51V and 1H Solid‐State NMR Spectroscopy
Authors: NARSIMHA K. , REDDY B. M. , RAO P. K. , MASTIKHIN V. M.
Published: May 2016

is carried out as a function of V2O5 loading.
ChemInform Abstract: Electrocatalytic Oxidation of Allylic Ethers, Dihydropyran, and Phenol Using a Polypyridyl Complex of Ruthenium(IV).
Authors: CAMPOS J. L. , DE GIOVANI W. F. , ROMERO J. R.
Published: May 2016

The electrocatalytic oxidation of the allylic ethers (I), dihydropyran (IV), and phenol gives the corresponding oxidation products as shown in the reaction scheme.
ChemInform Abstract: Synthetic Application of the Alder‐Bong Reaction: Stereoselective Construction of the Methanohydroazulene Framework.
Authors: GIGUERE R. J. , HARRAN P. G. , LOPEZ B. O.
Published: May 2016

The combined Diels‐Alder/ene reaction of the dienone acetal (I) with the acetylenedicarboxylate (II) produces the regioisomeric cycloadducts (III) and (IV).
ChemInform Abstract: Preparation of Optically Pure p‐(1‐Hydroxy‐2,2,2‐trifluoroethyl)benzoic Acid.
Authors: KITAZUME T. , YAMAZAKI T. , ITO K.
Published: May 2016

The key step in the synthesis of the optically active title compound (+)‐(X) is the enzymatically mediated stereoselective hydrolysis of the racemic isobutyrate (±)‐(VI).
ChemInform Abstract: Addition of Phosphinous Acid Trimethylsilyl Esters to Cumulated Double Bond Systems.
Authors: WELL M. , SCHMUTZLER R.
Published: May 2016

The reaction of (I) with the dienes (II), (IV), (VI) and (VIII) is found to occur with 1,3‐trimethylsilyl migration yielding the corresponding derivatives (III), (V) and (VII).
ChemInform Abstract: Alkyl Exchange Between Organo‐Tellurium Compounds: Synthesis of Mixed Alkyl Tellurides of the Type RTeR′.
Authors: MCQUEEN A. E. D. , PARKER M. B. , MULLIN J. B. , COLE‐HAMILTON D. J.
Published: May 2016

Alkyl exchange reaction between the symmetrical telluride (I) and the symmetrical ditellurides (II) leads to the formation of the unsymmetrical tellurides (III) and ditellurides (IV).
ChemInform Abstract: The Novel Redox Reaction and Thiolato Ligand Transfer Between Cp2Ti(SCMe3)2 and CpCo(CO)2. Preparation and Structure of (CpCo(μ‐SCMe3))2.
Authors: SHAVER A. , MORRIS S. , TURRIN R. , DAY V. W.
Published: May 2016

(III), crystallizing in P21/n with Z=4, is the first structurally characterized Co complex of this type.
ChemInform Abstract: Carbene Ligand Insertion into a Metallacycle Ring: A Metallacyclopentadiene to Metallacyclobutene Conversion.
Authors: O'CONNOR J. M. , PU L. , WOOLARD S. , CHADHA R. K.
Published: May 2016

Kinetics of the reaction are given, the mechanism is discussed.
ChemInform Abstract: A One‐Pot Procedure for the Deoxygenation of α,β‐Unsaturated Ketones and a Synthesis of the Mealybug Pheromone.
Authors: BAECKSTROEM P. + , LI L.
Published: May 2016

Isopropenyl methyl ketone (I) is coupled with methacrolein (II) to generate the hydroxy dienone (III).
ChemInform Abstract: New Ternary Representatives of the ThCr2Si2‐ and CaZn2Al2‐Type Structures in the Systems A‐M‐X and Ln‐M‐X (A: Ca, Sr, Ba; Ln: La, Ce, Pr; M: Cu, Ag, Au; X: Al, Ga).
Authors: CORDIER G. , DOERSAM G. + , ROEHR C. +
Published: May 2016

Twelve compounds of the title systems of general formula A(Ln)MxX4‐x (0.2 ≦ x ≦ 0.8) are prepared (from the elements at 1470 K) and found to crystallize in the tetragonal space group I4/mmm with Z=2.
ChemInform Abstract: Palladium‐Catalyzed Condensation of Aryl Halides with Phenylsulfonylacetonitrile and Diethyl Cyanomethylphosphonate.
Authors: SAKAMOTO T. , KATOH E. , KONDO Y. , YAMANAKA H.
Published: May 2016

The bromobenzenes (I) or the bromohetarenes (IV) undergo palladium‐catalyzed coupling with phenylsulfonylacetonitrile (II), producing the α‐sulfonyl nitriles (III) or (V).
ChemInform Abstract: Bromination of 2‐Methoxy‐5‐formylphenyl 3′,4′‐Methylenedioxy‐6′‐formylphenyl Ether.
Authors: BARATOV N. U. , VINOGRADOVA V. I. , YUNUSOV M. S.
Published: May 2016

Bromination of the title compound (I) unexpectedly affords the product (II).
ChemInform Abstract: Catalytic Iron‐Mediated Ene Carbocyclizations: Formal (4 + 4)‐Ene Reactions of Triene Esters.
Authors: TAKACS J. M. , NEWSOME P. W. , KUEHN C. , TAKUSAGAWA F.
Published: May 2016

The 2‐substituted decatrienoate (I) undergoes an iron‐catalyzed carbocyclization to give the trans‐cyclopentane (II) as a result of a (4 + 4)‐ene reaction in which cis‐propenyl and 2‐acroyl functionalities are introduced as appendages to the newly formed cyclopentane ring by the cyclization.
ChemInform Abstract: Difluoromethanesulfonic Acid. Part 2. A Two‐Step Route to the Free Acid from Monohydrated Sodium Difluoromethanesulfonate.
Authors: LANGLOIS B. R.
Published: May 2016

Anhydrous difluoromethanesulfonic acid (III) is produced from the stable sodium salt (I) in two steps.
ChemInform Abstract: Synthesis and Properties of 5‐Phenylethynylfuran‐2‐carboxaldehyde.
Authors: ZAVODNOV V. S. , KUL'NEVICH V. G. , ZINOV'EV V. D.
Published: May 2016

Copper phenylacetylide (I) reacts with 5‐iodofurfural (II) to give the aldehyde (III) mentioned in the title which is converted to the amide (V) via Beckmann rearrangement of the oxime.
ChemInform Abstract: Highly Stereoselective Addition of Alkylcopper Reagents to N‐Acyliminium Ions. Enantioselective Synthesis of trans‐2‐Butyl‐5‐heptylpyrrolidine.
Authors: SKRINJAR M. , WISTRAND L.‐G.
Published: May 2016

The methoxypyrrolidinedicarboxylate (I) reacts with the organocuprates (II) in the presence of BF3 to give the substitution products (III) and (IV) with predominance of the trans‐isomers (III).
ChemInform Abstract: Rhodium Carbenoid Mediated Cyclizations. Part 5. Synthesis and Rearrangement of Cyclic Sulfonium Ylides; Preparation of 6‐ and 7‐Membered Sulfur Heterocycles.
Authors: MOODY C. J. , TAYLOR R. J.
Published: May 2016

The Rh2(O‐Ac)4‐catalyzed cyclization of diazo mercaptans and diazo sulfides leads to sulfur heterocycles, e.g. (IV), (VII) and (XI).
ChemInform Abstract: Purines. Part 41. An Alternative Synthesis and the Chemical Behavior of 7,9‐Dialkyladeninium Salts.
Authors: SAITO T. , INOUE I. , FUJII T.
Published: May 2016

The adeninium salts (V) are prepared by N‐alkylation of the imidazolecarboxamidines (I) and subsequent ring closure upon hydrogenolysis.
ChemInform Abstract: The Synthesis and Antilipid Peroxidation Activity of 4,4‐Diarylbutylamines and 4,4‐Diarylbutanamides.
Authors: MIYANO S. , TATSUOKA T. , SUZUKI K. , IMAO K. , SATOH F. , ISHIHARA T. , HIROTSU I. , KIHARA T. , HATTA M. , HORIKAWA Y. , SUMOTO K.
Published: May 2016

Starting with the phenylbutyrolactone (I), the 4,4‐diarylbutanamides (V) and (XI) are prepared either via treatment of the activated ester derived from the butyric acid (III) with amines, e.g. (IV), or by cleavage of the benzo‐fused tetrahydrooxepinone (VIII) with the amines (X).
ChemInform Abstract: Reactions of Ammonium Sulfide and 4‐Chloro‐3,5‐dinitrobenzotrifluoride and Its Derivatives. Synthesis of 1,6‐Dinitro‐3,8‐bis(trifluoromethyl)phenothiazine, 2,2‐Dimethyl‐5‐trifluoromethyl‐7‐nitrobenzothiazoline, and Related Compounds.
Authors: CHEN M.‐J. , CHI C.‐S. , CHEN Q.‐Y.
Published: May 2016

4‐Chloro‐3,5‐dinitrobenzotrifluoride (I) reacts with ammonium sulfide (II) to give 1,6‐dinitro‐3,8‐bis(trifluoromethyl)phenothiazine (III).
ChemInform Abstract: Heteroadamantanes and Their Derivatives. Part 9. Synthesis of 1,5‐Dinitro‐3,7‐diazabicyclo(3.3.1)nonane and 2,2‐Disubstituted 5,7‐Dinitro‐1,3‐diazaadamantanes Therefrom.
Authors: KUZNETSOV A. I. , ROMANOVA K. I. , BASARGIN E. B. , MOSKOVKIN A. S. , UNKOVSKII B. V.
Published: May 2016

Treatment of the 3,7‐di‐tert‐butyldiazabicyclononane (I) with hydrobromic acid gives the ammonium salt (II) which is converted to free amine (III).
ChemInform Abstract: Organometallic Host‐Guest Systems as Novel Charge‐Transfer Ion Pairs with Three‐Dimensional Donor Network.
Authors: ELLER S. , ADAM M. , FISCHER R. D.
Published: May 2016

Polymeric compounds of (Me3Sn)4M(CN)6 (M: Fe, Ru, Os) react with guest ions such as methyl‐ and benzylviologen by ion exchange to yield in high yield (82‐87%) the polymeric title systems.
ChemInform Abstract: New Ferroelastic K2Sr(MoO4)2: Synthesis, Phase Transitions, Crystal and Domain Structures, Ionic Conductivity.
Authors: Tsyrenova Galina D. , Pavlova Erzhena T. , Solodovnikov Sergey F. , Popova Nadezhda N. , Kardash Tatyana Yu. , Stefanovich Sergey Yu. , Gudkova Irina A. , Solodovnikova Zoya A. , Lazoryak Bogdan I.
Published: May 2016

Polycrystalline K2Sr(MoO4)2 is prepared by solid state reaction of a stoichiometric mixture of K2CO3, SrCO3 and MoO3 (573—923 K, 80 h).
ChemInform Abstract: La1‐xBi1+xS3 (x ≈ 0.08): An n‐Type Semiconductor.
Authors: Han Fei , Liu Huimei , Malliakas Christos D. , Sturza Mihai , Chung Duck Young , Wan Xiangang , Kanatzidis Mercouri G.
Published: May 2016

The new compound of title is prepared by solid state reaction of La2S3 and Bi2S3 (alumina crucible, 1000 °C, 10 h).
ChemInform Abstract: Synthesis, Crystal Structure and High‐Temperature Transport Properties of the New Cluster Compound Rb2Mo15Se19.
Authors: Daigre Gilles , Gougeon Patrick , Gall Philippe , Gautier Regis , Guillou Olivier , Vaney Jean‐Baptiste , Candolfi Christophe , Dauscher Anne , Lenoir Bertrand
Published: May 2016

Polycrystalline Rb2Mo15Se19 is prepared by solid state reaction of a stoichiometric mixture of Mo, MoSe2, and Rb2Mo6Se6 (Mo crucible, 1300 °C, 40 h).
ChemInform Abstract: Enantioselectivity Switch in Copper‐Catalyzed Conjugate Addition Reactions under the Influence of a Chiral N‐Heterocyclic Carbene—Silver Complex.
Authors: Matsumoto Keitaro , Nakano Yuki , Shibata Naoatsu , Sakaguchi Satoshi
Published: May 2016

The asymmetric 1,4‐addition of diethylzinc to 2‐cycloalken‐1‐ones in presence of a copper catalyst with a chiral ligand affords 3‐ethylcycloalkanones.
ChemInform Abstract: Nazarov Cyclization of 1,4‐Pentadien‐3‐ols: Preparation of Cyclopenta[b]indoles and Spiro[indene‐1,4′‐quinoline]s.
Authors: Wang Zhiming , Xu Xingzhu , Gu Zhanshou , Feng Wei , Qian Houjun , Li Zhengyi , Sun Xiaoqiang , Kwon Ohyun
Published: May 2016

New Lewis acid‐catalyzed cascade reactions based on Nazarov cyclization of pentadienols are developed.
ChemInform Abstract: Thioamination of Alkenes with Hypervalent Iodine Reagents.
Authors: Mizar Pushpak , Niebuhr Rebecca , Hutchings Matthew , Farooq Umar , Wirth Thomas
Published: May 2016

The thioamination of alkenes mediated by iodine(III) reagents is investigated.
ChemInform Abstract: Catalyst‐Controlled Switch in Chemo‐ and Diastereoselectivities: Annulations of Morita—Baylis—Hillman Carbonates from Isatins.
Authors: Zhan Gu , Shi Ming‐Lin , He Qing , Lin Wei‐Jia , Ouyang Qin , Du Wei , Chen Ying‐Chun
Published: May 2016

A catalyst‐controlled switch in chemo‐ and diastereodivergent annulation reactions of Morita—Baylis—Hillman carbonates, derived from isatins and 2‐alkylidene‐1H‐indene‐1,3(2H)‐diones, is presented.
ChemInform Abstract: Carbocyclic Amino Ketones by Bredt′s Rule‐Arrested Kulinkovich—de Meijere Reaction.
Authors: Finn Paul B. , Derstine Brenden P. , Sieburth Scott McN.
Published: May 2016

The direction of the Ti‐mediated intramolecular reaction of amide with alkene depends on the structure of the substrate.
ChemInform Abstract: Boronic Acid—DMAPO Cooperative Catalysis for Dehydrative Condensation Between Carboxylic Acids and Amines.
Authors: Ishihara Kazuaki , Lu Yanhui
Published: May 2016

A broad variety of carboxylic acids as well as amines are efficiently converted into the corresponding amides in high yields.
ChemInform Abstract: Asymmetric Synthesis of Cyclopentanes Bearing Four Contiguous Stereocenters via an NHC‐Catalyzed Michael/Michael/Esterification Domino Reaction.
Authors: Shu Tao , Ni Qijian , Song Xiaoxiao , Zhao Kun , Wu Tianyu , Puttreddy Rakesh , Rissanen Kari , Enders Dieter
Published: May 2016

In the described approach two C—C bonds are formed via Michael addition and one C—O bond through a terminating ethanolysis step.
ChemInform Abstract: Cobalt(III)‐Catalyzed Alkenylation of Arenes and 6‐Arylpurines with Terminal Alkynes: Efficient Access to Functional Dyes.
Authors: Wang Shan , Hou Ji‐Ting , Feng Mei‐Lin , Zhang Xiao‐Zhuan , Chen Shan‐Yong , Yu Xiao‐Qi
Published: May 2016

Inexpensive Co(III)‐catalyzed direct addition of unactivated arenes and 6‐arylpurines to terminal alkynes under mild conditions is developed.
ChemInform Abstract: Photosensitizer‐Free Visible‐Light‐Mediated Gold‐Catalyzed 1,2‐Difunctionalization of Alkynes.
Authors: Huang Long , Rudolph Matthias , Rominger Frank , Hashmi A. Stephen K.
Published: May 2016

A variety of α‐aryl ketones are obtained under mild reaction conditions through this gold‐catalyzed process which shows broad functional‐group tolerance.
ChemInform Abstract: Phosphorous Acid Promoted Hydration—Condensation of Aromatic Alkynes with Aldehydes Affording Chalcones in an Oil/Water Two‐Phase System.
Authors: Zhou Yongbo , Li Zhongwen , Yang Xiao , Chen Xiulin , Li Mei , Chen Tieqiao , Yin Shuang‐Feng
Published: May 2016

The reaction proceeds stereoselectively affording only the E isomers with terminal arylacetylenes.
ChemInform Abstract: A Palladium‐Catalyzed Coupling Reaction of Aryl Nonaflates, Sulfur Dioxide, and Hydrazines
Authors: An Yuanyuan , Xia Hongguang , Wu Jie
Published: May 2016

leading to N‐aminosulfonamides
ChemInform Abstract: Synthesis and Photophysical Properties of Tetra and Pentaarylated Fluorobenzenes.
Authors: Maalik Aneela , Sharif Muhammad , Abbas Naeem , Spannenberg Anke , Villinger Alexander , Langer Peter
Published: May 2016

The palladium‐catalyzed exhaustive Suzuki‐Miyaura cross‐coupling reaction gives access to various multiarylated fluorobenzenes with interesting optical properties.
ChemInform Abstract: A General Protocol for the Efficient Synthesis of Polyarylated Benzenes by Multiple Suzuki‐Miyaura Reactions of Polychlorinated Benzenes.
Authors: Reimann Sebastian , Ehlers Peter , Sharif Muhammad , Spannenberg Anke , Langer Peter
Published: May 2016

A highly efficient and simple protocol for the synthesis of multiarylated benzenes by palladium‐catalyzed Suzuki‐Miyaura reaction of chlorobenzenes is presented.