bluuebunny/crossref_metadata_2025 huggingface dataset:
Nonlinear Dynamics of Mid-Infrared Interband Cascade Lasers Subject to Variable-Aperture Optical Feedback
Authors: Zhao Maorong , Xia Guangqiong , Yang Ke , Liu Shuman , Liu Junqi , Wang Qiupin , Liu Jianglong , Wu Zhengmao
Published: June 2022

In this work, we experimentally investigate the nonlinear dynamics of an interband cascade laser (ICL) under variable-aperture optical feedback implemented by a gold mirror combining with a ring-actuated iris diaphragm (RAID). By continuously varying the diameter of RAID (DR), the evolution of the dynamical state of ICL with the aperture of the optical feedback can be inspected. The characteristics of each dynamical state are characterized by time series, power spectra, phase portraits, and Lyapunov exponents. The results show that, with the decrease of DR, the dynamical state of the ICL under variable-aperture optical feedback presents an evolution from complex, simple to stable. Diverse dynamical states including period one state (P1), period two state (P2), multi-period state (MP), quasi-period state (QP), low-frequency fluctuation (LFF), chaotic state (C), and hyperchaos have been observed. Through mapping the evolution of dynamical states with DR for the ICL biased at different currents, different evolved routes of the dynamical states are revealed.
Design of Fuzzy Logic Motion Detection Algorithm for the Bracelet Type Sensor Consisting of Conductive Layer-Polymer Composite Film
Authors: Park Kiwon
Published: June 2022

To improve the motion detection performance of a bracelet-type sensor that uses only two tiny sensor modules developed using carbon-based conductive polymer composite films, a fuzzy-logic algorithm was developed in this study. A polyethylene terephthalate polymer film with a conductive layer composed of carbon paste was used as the integral material utilized for the composite film; a small sensor module composed of mechanical parts mounted on the film was developed to effectively detect the surface resistance variations of the film. A participant wore a bracelet sensor, which consisted of two sensor modules, on their forearm, and the resistance variations of the contact area between the forearm and the sensor modules corresponding to the flexion changes of the surface of the body due to muscle contraction and relaxation were detected. The surface resistance variations of the film were converted to voltage signals, which were used as inputs to the fuzzy logic algorithm to detect four consecutive motions of the forearm. The results demonstrated that the fuzzy-logic algorithm attained an accuracy of 94%. The fuzzy algorithm successfully detected four motions and the resting state of the forearms; moreover, it showed improved performance compared to previous research.
Mechanistic Approach of Nano Carriers for Targeted in Cancer Chemotherapy: A Newer Strategy for Novel Drug Delivery System
Authors: Dey Niladri Shekhar
Published: June 2022

The application of nanomedicine represents an innovative approach for the treatment in the modern field of cancer chemotherapy. In the present research work, tamoxifen citrate loaded nanolipid vesicles were prepared conjugated with phosphoethanolamine as the linker molecule, and the specific antibody was tagged with the linker molecule on the bilayer surface of the vesicles. The main objective of this study is to determine the efficacy and biological behavior of antibody conjugated nanoliposome in breast cancer cell lines. Percentage of drug loading and loading efficiency was done and their results were compared to theoretical drug loading. The average diameter of those vesicles was within the 100 nm range, which is revealed in FESEM and TEM images and their lamellarity was observed in cryo-TEM images. The hydrodynamic diameter was done by particle size analysis and the surface charge was determined by the zeta potential parameter. Predominant cellular uptake was observed for antibody conjugated nanolipid vesicles in MCF-7 and MDA-MB-453 human breast cancer cell lines. A cellular apoptosis assay was conducted by flow cytometer (FACS). All experimental data would be more beneficial for the treatment of breast cancer chemotherapy. Further studies are warranted to investigate the efficacy and safety of antibody conjugated nanolipid vesicles in vivo for breast cancer animal model.
Theoretical and Experimental Substantiation of the Efficiency of Combined-Reinforced Glass Fiber Polymer Composite Concrete Elements in Bending
Authors: Meskhi Besarion , Beskopylny Alexey , Stel’makh Sergey , Shcherban’ Evgenii , Mailyan Levon , Beskopylny Nikita , Dotsenko Natal’ya
Published: June 2022

An essential problem of current construction engineering is the search for ways to obtain lightweight building structures with improved characteristics. The relevant way is the use of polymer composite reinforcement and concrete with high classes and prime characteristics. The purpose of this work is the theoretical and experimental substantiation of the effectiveness of combined-reinforced glass fiber polymer composite concrete (GFPCC) bending elements, and new recipe, technological and design solutions. We theoretically and experimentally substantiated the effectiveness of GFPCC bending elements from the point of view of three aspects: prescription, technological and constructive. An improvement in the structure and characteristics of glass fiber-reinforced concrete and GFPCC bending elements of a new type has been proven: the compressive strength of glass fiber-reinforced concrete has been increased up to 20%, and the efficiency of GFPCC bending elements is comparable to the concrete bending elements with steel reinforcement of class A1000 and higher. An improvement in the performance of the design due to the synergistic effect of fiber reinforcement of bending elements in combination with polymer composite reinforcement with rods was revealed. The synergistic effect with optimal recipe and technological parameters is due to the combined effect of dispersed fiber, which strengthens concrete at the micro level, and polymer composite reinforcement, which significantly increases the bearing capacity of the element at the macro level. Analytical dependences of the type of functions of the characteristics of bent concrete structures on the arguments—the parameters of the combined reinforcement with fiber and polymer composite reinforcement—are proposed. The synergistic effect of such a development is described, a new controlled significant coefficient of synergistic efficiency of combined reinforcement is proposed. From an economic point of view, the cost of the developed elements has been reduced and is economically more profitable (up to 300%).
Batch Fabrication of a Polydimethylsiloxane Based Stretchable Capacitive Strain Gauge Sensor for Orthopedics
Authors: Sheeja Prakash Karthika , Mayr Hermann Otto , Agrawal Prachi , Agarwal Priyank , Seidenstuecker Michael , Rosenstiel Nikolaus , Woias Peter , Comella Laura Maria
Published: June 2022

Polymer-based capacitive strain gauges are a novel and promising concept for measuring large displacements and strains in various applications. These novel sensors allow for high strain, well above the maximum values achieved with state-of-the-art strain gauges (Typ. 1%). In recent years, a lot of interest in this technology has existed in orthopedics, where the sensors have been used to measure knee laxity caused by a tear of the anterior cruciate ligament (ACL), and for other ligament injuries. The validation of this technology in the field has a very low level of maturity, as no fast, reproducible, and reliable manufacturing process which allows mass production of sensors with low cost exists. For this reason, in this paper, a new approach for the fabrication of polymer-based capacitive strain gauges is proposed, using polydimethylsiloxane (PDMS) as base material. It allows (1) the fast manufacturing of sensor batches with reproducible geometry, (2) includes a fabrication step for embedding rigid electrical contacts on the sensors, and (3) is designed to produce sensor batches in which the size, the number, and the position of the sensors can be adapted to the patient’s anatomy. In the paper, the process repeatability and the robustness of the design are successfully proven. After 1000 large-strain elongation cycles, in the form of accelerated testing caused much higher strains than in the above-mentioned clinical scenario, the sensor’s electrical contacts remained in place and the functionalities were unaltered. Moreover, the prototype of a patient customizable patch, embedding multiple sensors, was produced.
Rheology and Processing of Polymers
Authors: Lamnawar Khalid , Maazouz Abderrahim
Published: June 2022

I am so glad to share with you our Special Issue entitled ‘Rheology and Processing of Polymers’, which covers the latest developments in the field of rheology and polymer processing, highlighting cutting-edge research focusing on the processing of advanced polymers and their composites [...]
Flow Behaviors of Polymer Solution in a Lid-Driven Cavity
Authors: Bui Cuong Mai , Ho Anh-Ngoc Tran , Nguyen Xuan Bao
Published: June 2022

In this work, a numerical study of polymer flow behaviors in a lid-driven cavity, which is inspired by the coating process, at a broad range of Oldroyd numbers (0≤Od≤50), is carried out. The Reynolds number is height-based and kept at Re=0.001. The fluid investigated is of Carbopol gel possessing yield stress and shear-thinning properties. To express rheological characteristics, the Herschel–Bulkley model cooperated with Papanastasiou’s regularization scheme is utilized. Results show that the polymer flow characteristics, i.e., velocity, viscosity, and vortex distributions, are considerably influenced by viscoplastic behaviors. Additionally, there exist solid-like regions which can be of either moving rigid or static dead types in the flow patterns; they become greater and tend to merge together to construct larger ones when Od increases. Furthermore, various polymer flow aspects in different cavity configurations are discussed and analyzed; the cavity width/aspect ratio and skewed angle are found to have significant impacts on the vortex structures and the formation of solid-like regions. Moreover, results for the critical aspect ratio at which the static dead zone is broken into two parts and the characteristic height of this zone are also reported in detail.
Fabrication of Biocompatible Electrospun Poly(ε-caprolactone)/Gelatin Nanofibers Loaded with Pinus radiata Bark Extracts for Wound Healing Applications
Authors: Borges-Vilches Jessica , Unalan Irem , Fernández Katherina , Boccaccini Aldo R.
Published: June 2022

In this study, poly(ε-caprolactone) (PCL)/gelatin (GEL) electrospun nanofibers loaded with two different concentrations of Pinus radiata bark extracts (PEs) were fabricated via electrospinning for wound healing applications. The effects of incorporating PE into PCL/GEL electrospun nanofibers were investigated regarding their physicochemical properties and in vitro biocompatibility. All electrospun nanofibers showed smooth, uniform, and bead-free surfaces. Their functional groups were detected by ATR-FTIR spectroscopy, and their total phenol content was measured by a Folin–Ciocalteu assay. With PE addition, the electrospun nanofibers exhibited an increase in their wettability and degradation rates over time and a decrease in their tensile stress values from 20 ± 4 to 8 ± 2 MPa for PCL/GEL and PCL/GEL/0.36%PE samples, respectively. PE was also released from the fibrous mats in a rather controlled fashion. The PCL/GEL/0.18%PE and PCL/GEL/0.36%PE electrospun nanofibers inhibited bacterial activity at around 6 ± 0.1% and 23 ± 0.3% against E. coli and 14 ± 0.1% and 18 ± 0.2% against S. aureus after 24 h incubation, respectively. In vitro cell studies showed that PE-loaded electrospun nanofibers enhanced HaCaT cell growth, attachment, and proliferation, favoring cell migration towards the scratch area in the wound healing assay and allowing a complete wound closure after 72 h treatment. These findings suggested that PE-loaded electrospun nanofibers are promising materials for antibiotic-free dressings for wound healing applications.
Faraday Instability in Viscous Fluids Covered with Elastic Polymer Films
Authors: Liu Junxiu , Song Wenqiang , Ma Gan , Li Kai
Published: June 2022

Faraday instability has great application value in the fields of controlling polymer processing, micromolding colloidal lattices on structured suspensions, organizing particle layers, and conducting cell culture. To regulate Faraday instability, in this article, we attempt to introduce an elastic polymer film covering the surface of a viscous fluid layer and theoretically study the behaviors of the Faraday instability phenomenon and the effect of the elastic polymer film. Based on hydrodynamic theory, the Floquet theory is utilized to formulate its stability criterion, and the critical acceleration amplitude and critical wave number are calculated numerically. The results show that the critical acceleration amplitude for Faraday instability increases with three increasing bending stiffness of the elastic polymer film, and the critical wave number decreases with increasing bending stiffness. In addition, surface tension and viscosity also have important effects on the critical acceleration amplitude and critical wave number. The strategy of controlling Faraday instability by covering an elastic polymer film proposed in this paper has great application potential in new photonic devices, metamaterials, alternative energy, biology, and other fields.
Laser Sintering Approaches for Bone Tissue Engineering
Authors: DiNoro Jeremy N. , Paxton Naomi C. , Skewes Jacob , Yue Zhilian , Lewis Philip M. , Thompson Robert G. , Beirne Stephen , Woodruff Maria A. , Wallace Gordon G.
Published: June 2022

The adoption of additive manufacturing (AM) techniques into the medical space has revolutionised tissue engineering. Depending upon the tissue type, specific AM approaches are capable of closely matching the physical and biological tissue attributes, to guide tissue regeneration. For hard tissue such as bone, powder bed fusion (PBF) techniques have significant potential, as they are capable of fabricating materials that can match the mechanical requirements necessary to maintain bone functionality and support regeneration. This review focuses on the PBF techniques that utilize laser sintering for creating scaffolds for bone tissue engineering (BTE) applications. Optimal scaffold requirements are explained, ranging from material biocompatibility and bioactivity, to generating specific architectures to recapitulate the porosity, interconnectivity, and mechanical properties of native human bone. The main objective of the review is to outline the most common materials processed using PBF in the context of BTE; initially outlining the most common polymers, including polyamide, polycaprolactone, polyethylene, and polyetheretherketone. Subsequent sections investigate the use of metals and ceramics in similar systems for BTE applications. The last section explores how composite materials can be used. Within each material section, the benefits and shortcomings are outlined, including their mechanical and biological performance, as well as associated printing parameters. The framework provided can be applied to the development of new, novel materials or laser-based approaches to ultimately generate bone tissue analogues or for guiding bone regeneration.
In Service Performance of Toughened PHBV/TPU Blends Obtained by Reactive Extrusion for Injected Parts
Authors: Samaniego-Aguilar Kerly , Sánchez-Safont Estefanía , Arrillaga Alex , Anakabe Jon , Gamez-Perez Jose , Cabedo Luis
Published: June 2022

Moving toward a more sustainable production model based on a circular economy, biopolymers are considered as one of the most promising alternatives to reduce the dependence on oil-based plastics. Polyhydroxybutyrate-co-valerate (PHBV), a bacterial biopolyester from the polyhydroxialkanoates (PHAs) family, seems to be an attractive candidate to replace commodities in many applications such as rigid packaging, among others, due to its excellent overall physicochemical and mechanical properties. However, it presents a relatively poor thermal stability, low toughness and ductility, thus limiting its applicability with respect to other polymers such as polypropylene (PP). To improve the performance of PHBV, reactive blending with an elastomer seems to be a proper cost-effective strategy that would lead to increased ductility and toughness by rubber toughening mechanisms. Hence, the objective of this work was the development and characterization of toughness-improved blends of PHBV with thermoplastic polyurethane (TPU) using hexamethylene diisocyanate (HMDI) as a reactive extrusion agent. To better understand the role of the elastomer and the compatibilizer, the morphological, rheological, thermal, and mechanical behavior of the blends were investigated. To explore the in-service performance of the blends, mechanical and long-term creep characterization were conducted at three different temperatures (−20, 23, 50 °C). Furthermore, the biodegradability in composting conditions has also been tested. The results showed that HMDI proved its efficiency as a compatibilizer in this system, reducing the average particle size of the TPU disperse phase and enhancing the adhesion between the PHBV matrix and TPU elastomer. Although the sole incorporation of the TPU leads to slight improvements in toughness, the compatibilizer plays a key role in improving the overall performance of the blends, leading to a clear improvement in toughness and long-term behavior.
Eco-Composites from Silkworm Meal and Polycaprolactone: Effect of Formulation and Processing Conditions
Authors: López-Castejón María Luisa , Reviriego María Luisa , Álvarez-Castillo Estefanía , Aguilar José M. , Bengoechea Carlos
Published: June 2022

The production of green plastic materials from defatted silkworm meal (SW) through a scalable technique (e.g., injection moulding) would permit the revalorization of a by-product of the textile industry. The textile by-product contains an estimable protein content (~50%) which can justify its applicability in the field of eco-materials. Thus, SW-based materials have been processed and characterized, sometimes requiring the addition of another biodegradable polymer, such as polycaprolactone (PCL), in the formulation. Thermomechanical, tensile and water uptake properties have been assessed at different PCL contents (from 0 to 20%). The viscoelasticity of the plastic composites when heated was greatly affected by the melting point of PCL, which also led generally to an increase in their extensibility and resistance. However, this effect of PCL was diminished when composites were processed at higher moulding temperatures. As PCL possesses a hydrophobic character, a decrease in the water uptake was generally detected as PCL content increased, which could also be related to the lower plasticizer content in the formulation. Silkworm meal is an adequate ingredient to consider in the production of green plastic materials that would eventually add value to a main by-product of the sericulture industry.
The Role of Roller Rotation Pattern in the Spreading Process of Polymer/Short-Fiber Composite Powder in Selective Laser Sintering
Authors: Cheng Tan , Chen Hui , Wei Qingsong
Published: June 2022

In this study, for the first time, a forward-rotating roller is proposed for the spreading of CF/PA12 composite powder in the selective laser sintering (SLS) process. The mesoscopic kinetic mechanism of composite particle spreading is investigated by utilizing the “multi-spherical” element within the discrete element method (DEM). The commercial software EDEM and the open-source DEM particle simulation code LIGGGHTS-PUBLIC are used for the simulations in this work. It is found that the forward-rotating roller produces a strong compaction on the powder pile than does the conventional counter-rotating roller, thus increasing the coordination number and mass flow rate of the particle flow, which significantly improves the powder bed quality. In addition, the forward-rotating pattern generates a braking friction force on the particles in the opposite direction to their spread, which affects the particle dynamics and deposition process. Therefore, appropriately increasing the roller rotation speed to make this force comparable to the roller dragging force could result in faster deposition of the composite particles to form a stable powder bed. This mechanism allows the forward-rotating roller to maintain a good powder bed quality, even at a high spreading speed, thus providing greater potential for the industry to improve the spreading efficiency of the SLS process.
Emulgels Containing Perilla frutescens Seed Oil, Moringa oleifera Seed Oil, and Mixed Seed Oil: Microemulsion and Safety Assessment
Authors: Tunit Prakairat , Chittasupho Chuda , Sriyakul Kusuma , Tungsuruthai Parunkul , Chakkavittumrong Panlop , Na-Bangchang Kesara , Kietinun Somboon
Published: June 2022

P. frutescens seed oil and M. oleifera seed oil consist of fatty acids and sterols that are beneficial for skin. Mixing of these oils at 1:1 ratio has shown to increase antioxidant activity of oils. This study aims to formulate emulgels containing microemulsions of P. frutescens seed oil, M. oleifera seed oil, and mixed P. frutescens and M. oleifera seed oils. The chemical constituents of P. frutescens seed oil, M. oleifera seed oil, and mixed seed oil are analyzed by gas chromatography/mass spectrometry (GC/MS). The microemulsions are formulated by a phase titration method and characterized for the droplet size, polydispersity index, and zeta potential value using a dynamic light scattering technique. The physical and chemical stability of the microemulsions are investigated using a rheometer and UV-Visible spectrophotometer, respectively. The safety of microemulsion is evaluated on PBMC and human subjects. Emulgels containing three different types of microemulsion are formulated. The results show that P. frutescens seed oil is mainly composed of alpha-linolenic acid, linoleic acid, and oleic acid, whereas M. oleifera seed oil contains a high proportion of oleic acid. Mixed seed oil contains a comparable amount of alpha-linolenic acid and oleic acid. All types of oils are composed of β-sitosterol as the major plant sterol. Microemulsions of all types of oils are successfully prepared by using Tween 80 as a surfactant due to the largest transparent region of pseudoternary phase diagram. The size, polydispersity index, and zeta potential values of all types of microemulsion are in the acceptable range upon storage at 30 °C for 1 month. Microemulsions exhibit pseudoplastic flow behavior. The percent of remaining oils in all types of microemulsion is more than 90% after storage at 30 °C for 1 month. Emulgels containing three types of microemulsions exhibit good characteristics and no change in viscosity after storage at 4, 30, and 45 °C for 1 month. The safety results reveal that three types of microemulsion do not induce cytotoxicity to PBMC nor induce skin irritation and allergic reactions. Emulgels containing microemulsions developed in this study can be used to safely deliver P. frutescens seed oil, M. oleifera seed oil, and mixed seed oil to human skin.
Development of Olive Oil and α-Tocopherol Containing Emulsions Stabilized by FucoPol: Rheological and Textural Analyses
Authors: Baptista Sílvia , Pereira João R. , Gil Cátia V. , Torres Cristiana A. V. , Reis Maria A. M. , Freitas Filomena
Published: June 2022

Biobased raw materials like natural polysaccharides are increasingly sought by the cosmetic industry for their valuable properties. Such biodegradable and usually non-cytotoxic biopolymers are commonly used in skin-care products as rheological modifiers, bioemulsifiers and/or bioactive ingredients. FucoPol is a natural polysaccharide with reported biocompatibility, emulsion-forming and stabilizing capacity, shear-thinning behavior and bioactivity (e.g., antioxidant capacity, wound healing ability) that potentiate its utilization in skin-care products. In this study, olive oil and α-tocopherol containing emulsions were stabilized with FucoPol. Although the presence of α-tocopherol negatively impacted the emulsions’ stability, it increased their emulsification index (EI). Moreover, FucoPol outperformed the commercial emulsifier Sepigel® 305, under the tested conditions, with higher EI and higher stability under storage for 30 days. The formulation of FucoPol-based emulsions with olive oil and α-tocopherol was studied by Response Surface Methodology (RSM) that allowed the definition of the ingredients’ content to attain high emulsification. The RSM model established that α-tocopherol concentration had no significant impact on the EI within the tested ranges, with optimal emulsification for FucoPol concentration in the range 0.7–1.2 wt.% and olive oil contents of 20–30 wt.%. Formulations with 25 wt.% olive oil and either 0.5 or 2.0 wt.% α-tocopherol were emulsified with 1.0 wt.% or 0.7 wt.% FucoPol, respectively, resulting in oil-in-water (O/W) emulsions. The emulsions had similar shear-thinning behavior, but the formulation with higher FucoPol content displayed higher apparent viscosity, higher consistency, as well as higher firmness, adhesiveness and cohesiveness, but lower spreadability. These findings show FucoPol’s high performance as an emulsifier for olive oil/α-tocopherol, which are supported by an effective impact on the physicochemical and structural characteristics of the emulsions. Hence, this natural polysaccharide is a potential alternative to other emulsifiers.
Characterization and Optimization of Real-Time Photoresponsive Gelatin for Direct Laser Writing
Authors: Murić Branka D. , Pantelić Dejan V. , Radmilović Mihajlo D. , Savić-Šević Svetlana N. , Vasović Vesna O.
Published: June 2022

There is an abundance of plastic materials used in the widest range of applications, such as packaging, machine parts, biomedical devices and components, etc. However, most materials used today are non-decomposable in the environment, producing a huge burden on ecosystems. The search for better, safer alternatives is still on. Here we present a detailed analysis of a simple, cheap, non-toxic, even edible, eco-friendly material, which can be easily manufactured, laser patterned and used for the fabrication of complex structures. The base substance is gelatin which is made photoresponsive by adding plasticizers and sensitizers. The resulting films were analyzed with respect to their optical, thermal and mechanical properties, which can be modified by a slight variation of chemical composition. The material is optimized for rapid laser-manufacturing of elastic microstructures (lenses, gratings, cantilevers, etc.) without any waste or residues. Overall, the material properties were tailored to increase photothermal responsivity, improve the surface quality and achieve material homogeneity, transparency and long-term stability (as verified using electron microscopy, infrared spectroscopy and differential scanning calorimetry).
Size Prediction and Electrical Performance of Knitted Strain Sensors
Authors: Liang Xinhua , Cong Honglian , Dong Zhijia , Jiang Gaoming
Published: June 2022

Benefitting from the multifunctional properties of knitted fabrics with elasticity, flexibility, and high resilience, knitted strain sensors based on structure and strain performance are widely utilized in sports health due to their adaptability to human movements. However, the fabrication process of common strain sensors mainly relies on experienced technicians to determine the best sensor size through repeated experiments, resulting in significant size errors and a long development cycle. Herein, knitted strain sensors based on plain knit were fabricated with nylon/spandex composite yarn and silver-plated nylon yarn using a flat knitting process. A size prediction model of knitted strain sensors was established by exploring the linear relationship between the conductive area size of samples and knitting parameters via SPSS regression analysis. Combined with stable structures and high performance of good sensitivity, stability, and durability, the knitted strain sensors based on size prediction models can be worn on human skin or garments to monitor different movements, such as pronunciation and joint bending. This research indicated that the reasonable size control of the knitted strain sensor could realize its precise positioning in intelligent garments, exhibiting promising potential in intelligent wearable electronics.
Effect of Transglutaminase Pre-Crosslinking Treatment Incorporated with Glucono-δ-lactone on the Physicochemical and Digestive Properties of Tofu
Authors: Hui Tianran , Xing Guangliang
Published: June 2022

This study evaluated the effect of transglutaminase (TGase) pre-crosslinking treatment on the physicochemical and digestive characteristics of tofu coagulated by glucono-δ-lactone (GDL). Results showed that certain TGase pre-crosslinking times (0.5, 1, 2 and 3 h) could promote the colloidal stability of soymilk with increased particle average sizes and absolute values of zeta potential. Particularly, the water holding capacity and gel strength of tofu pre-crosslinked by TGase for 2 h were 6.8% and 47.7% enhancement, respectively, compared to the control, and exhibited the highest score of overall acceptability. However, extensive pre-crosslinking by TGase for 3 h had an adverse impact on the sensory of tofu with poor firmness, rough structure and whey separation. Hence, the tofu gel pre-crosslinked by TGase for 2 h and then coagulated by GDL was recommended which showed a “slow release” mode of soluble proteins during the in vitro digestion phase, and had more chances to release bioactive peptides than soymilk.
Polyethylene Terephthalate (PET) Bottle-to-Bottle Recycling for the Beverage Industry: A Review
Authors: Benyathiar Patnarin , Kumar Pankaj , Carpenter Gregory , Brace John , Mishra Dharmendra K.
Published: June 2022

Disposal of plastic waste has become a widely discussed issue, due to the potential environmental impact of improper waste disposal. Polyethylene terephthalate (PET) packaging accounted for 44.7% of single-serve beverage packaging in the US in 2021, and 12% of global solid waste. A strategic solution is needed to manage plastic packaging solid waste. Major beverage manufacturers have pledged to reduce their environmental footprint by taking steps towards a sustainable future. The PET bottle has several properties that make it an environmentally friendly choice. The PET bottle has good barrier properties as its single-layer, mono-material composition allows it to be more easily recycled. Compared to glass, the PET bottle is lightweight and has a lower carbon footprint in production and transportation. With modern advancements to decontamination processes in the recycling of post-consumer recycled PET (rPET or PCR), it has become a safe material for reuse as beverage packaging. It has been 30 years since the FDA first began certifying PCR PET production processes as compliant for production of food contact PCR PET, for application within the United States. This article provides an overview of PET bottle-to-bottle recycling and guidance for beverage manufacturers looking to advance goals for sustainability.
Organosilicone Compounds in Supercritical Carbon Dioxide
Authors: Sizov Victor E. , Zefirov Vadim V. , Gallyamov Marat O. , Muzafarov Aziz M.
Published: June 2022

This review considers the key advantages of using supercritical carbon dioxide as a solvent for systems with organosilicon compounds. Organosilicon polymeric materials synthesis as well as the creation and modification of composites based on them are discussed. Polydimethylsiloxane and analogues used as polymerization stabilizers and nucleation promoters in pore formation processes are analyzed as well.
Synergistic Effects of DOPO-Based Derivative and Organo-Montmorillonite on Flame Retardancy, Thermal Stability and Mechanical Properties of Polypropylene
Authors: Huang Weijiang , Wang Kui , Tu Chunyun , Xu Xiaolu , Tian Qin , Ma Chao , Fu Qiuping , Yan Wei
Published: June 2022

Polypropylene (PP), as a general thermoplastic polymer, is broadly used in different fields. However, the high flammability, melt dripping and poor mechanical properties of PP are a constraint to the expansion of its applications. In this paper, PP composites containing a combination of a phenethyl-bridged DOPO derivative (PN-DOPO) and organic montmorillonite (OMMT) were prepared via melt blending. The synergistic effects of PN-DOPO and OMMT on the flame retardancy, thermal stability and mechanical properties of PP composites were investigated systematically. The results showed that 20 wt% addition of PN-DOPO with OMMT improved the flame retardancy of PP composites. In particular, the introduction of 17 wt% PN-DOPO and 3 wt% OMMT increased the LOI values of the PP matrix from 17.2% to 23.6%, and the sample reached the V-0 level and reduced the heat release rate and total heat release. TGA indicated that OMMT could improve the thermal stability of the PP/PN-DOPO blends and promote the char residues of PP systems. Rheological behaviour showed a higher storage modulus, loss modulus and complex viscosity of PP/PN-DOPO/OMMT composites, suggesting a more effective network structure. In addition, the tensile strength, flexural properties and impact strength of the PP/PN-DOPO/OMMT composites actually increased for a good dispersion effect. Combined with the char layer analysis, the introduction of OMMT promoted more continuous and compact structural layers containing an aluminium–silicon barrier and phosphorus-containing carbonaceous char in the condensed phase. OMMT can improve the flame retardancy, thermal stability and mechanical properties of PP, and, thus, PN-DOPO/OMMT blends can serve as an efficient synergistic system for flame-retarded PP composites.
Polymer Composite with Enhanced Thermal Conductivity and Insulation Properties through Aligned Al2O3 Fiber
Authors: Wang Sijiao , Chen Mengmeng , Cao Kaiming
Published: June 2022

Thermoplastic polyolefins, such as polyethylene (PE), are traditionally one of the most widely used polymer classes with applications in the electric industry, and their nanocomposites have caught the interest of researchers. The linear filler is shown to be beneficial in decreasing the charge injection and hindering the formation of charge packs. So, we demonstrate a novel composite with excellent properties. The low-density polyethylene (LDPE) composite with aligned aluminum oxide (Al2O3) fiber has been prepared in electric field conditions. The direction of the Al2O3 fiber was parallel to the thickness direction of the LDPE composite. The breakdown strength of the Al2O3/LDPE composite with 0.2% aligned Al2O3 fiber was 498 kV/mm, which is higher than other fillers induced. The aligned Al2O3 fiber has effect on preventing accumulation of space charge and reducing the amount of free electron in the material. In addition, the thermal conductivity of the LDPE composite (0.22 W/m·K) was increased to 0.85 W/m·K when doped with 0.5 wt% aligned Al2O3 fiber. The present structure provides a new possibility for mass new nanocomposites with excellent microstructures and remarkable functionality.
Facile Construction of Polypyrrole Microencapsulated Melamine-Coated Ammonium Polyphosphate to Simultaneously Reduce Flammability and Smoke Release of Epoxy Resin
Authors: Wang Feiyue , Liao Jiahao , Yan Long , Cai Mengtao
Published: June 2022

A unique mono-component intumescent flame retardant, named PPy-MAPP, of which melamine-coated ammonium polyphosphate (MAPP) was microencapsulated by polypyrrole (PPy), was synthesized and carefully characterized. The obtained PPy-MAPP was applied to epoxy resin (EP) for obtaining flame-retarded EP composites. The results show that PPy-MAPP imparts better flame retardancy and smoke suppression properties to EP compared to the same addition of MAPP. The EP composite with 15 wt% PPy-MAPP easily passes the UL94 V-0 rating and achieves an LOI value of 42.4%, accompanied by a 61.9% reduction in total heat release (THR) and a 73.9% reduction in total smoke production (TSP) when compared with pure EP. The char residue analysis shows that PPy-MAPP can promote a generation of more phosphorus-rich structures in the condensed phase that improve the integrity and intumescence of char against fire. The mechanical test indicates that PPy-MAPP has a less negative effect on the tensile strength and elastic modulus of epoxy resin due to the good compatibility between PPy-MAPP and the EP matrix, as supported by differential scanning calorimetry (DSC) analyses. In this paper, these attractive features of PPy-MAPP provide a new strategy to prepare satisfactory flame retardant and super flame retarding EP composites.
Dual Block Copolymer Morphologies in Ultrathin Films on Topographic Substrates: The Effect of Film Curvature
Authors: Michman Elisheva , Oded Meirav , Shenhar Roy
Published: June 2022

The ability to create mixed morphologies using easily controlled parameters is crucial for the integration of block copolymers in advanced technologies. We have previously shown that casting an ultrathin block copolymer film on a topographically patterned substrate results in different deposited thicknesses on the plateaus and in the trenches, which leads to the co-existence of two patterns. In this work, we highlight the dependence of the dual patterns on the film profile. We suggest that the steepness of the film profile formed across the plateau edge affects the nucleation of microphase-separated domains near the plateau edges, which influences the morphology that develops on the plateau regions. An analysis of the local film thicknesses in multiple samples exhibiting various combinations of plateau and trench widths for different trench depths enabled the construction of phase diagrams, which unraveled the intricate dependence of the formed patterns not only on the curvature of the film profile but also on the fraction of the film that resides in the trenches. Our analysis facilitates the prediction of the patterns that would develop in the trenches and on the plateaus for a given block copolymer film of known thickness from the dimensions of the topographic features.
Double-Decker-Shaped Polyhedral Silsesquioxanes Reinforced Epoxy/Bismaleimide Hybrids Featuring High Thermal Stability
Authors: Chen Wei-Cheng , Chen Zih-Yu , Ba Yuxia , Wang Bingyang , Chen Guofei , Fang Xingzhong , Kuo Shiao-Wei
Published: June 2022

In this study, we synthesized bismaleimide into a functionalized double-decker silsesquioxane (DDSQ) cage. This was achieved by hydrosilylation of DDSQ with nadic anhydride (ND), reacting it with excess p-phenylenediamine to obtain DDSQ-ND-NH2, and treating with maleic anhydride (MA), which finally created a DDSQ-BMI cage structure. We observed that the thermal decomposition temperature (Td) and char yield were both increased upon increasing the thermal polymerization temperature, and that these two values were both significantly higher than pure BMI without the DDSQ cage structure since the inorganic DDSQ nanoparticle could strongly enhance the thermal stability based on the nano-reinforcement effect. Based on FTIR, TGA, and DMA analyses, it was found that blending epoxy resin with the DDSQ-BMI cage to form epoxy/DDSQ-BMI hybrids could also enhance the thermal and mechanical properties of epoxy resin due to the organic/inorganic network formation created by the ring-opening polymerization of the epoxy group and the addition polymerization of the BMI group due to the combination of the inorganic DDSQ cage structure and hydrogen bonding effect. The epoxy/DDSQ-BMI = 1/1 hybrid system displayed high Tg value (188 °C), Td value (397 °C), and char yield (40.4 wt%), which was much higher than that of the typical DGEBA type epoxy resin with various organic curing agents.
Strengthening Timber Structural Members with CFRP and GFRP: A State-of-the-Art Review
Authors: Saad Khaled , Lengyel András
Published: June 2022

The application of fibre-reinforced polymers (FRP) for strengthening timber structures has proven its efficiency in enhancing load-bearing capacity and, in some cases, the stiffness of structural elements, thus providing cost-effective and competitive alternatives both in new design and retrofitting existing historical buildings. Over the last few decades, several reinforcing materials and techniques evolved, and considerable progress was made in numerical modelling, especially using the finite element method. As this field of research has become extensive and diversified, as well as numerous contradicting results have emerged, a thorough review is necessary. This manuscript covers the topics of historical preliminaries, reinforcing with carbon and glass fibre composites, bond characteristics, main reinforcing techniques, modelling of knots, and the effects of the fibre waviness on the composite behaviour. A detailed overview is given on the experimental and numerical investigation of mechanics of strengthened beams. A one-of-a-kind table is presented that compares the stiffness improvement observed in several studies with analytical estimates. Attention is drawn to a number of challenges that have arisen, e.g., the moderate stiffness enhancement, composite-to-wood interface, modelling of knots, and strengthening of defected timber members. This paper can be used as a starting point for future research and engineering projects.
Parametric Design Studies of Mass-Related Global Warming Potential and Construction Costs of FRP-Reinforced Concrete Infrastructure
Authors: Preinstorfer Philipp , Huber Tobias , Reichenbach Sara , Lees Janet M. , Kromoser Benjamin
Published: June 2022

Fibre-reinforced polymers (FRPs) are a promising corrosion-resistant alternative to steel reinforcement. FRPs are, however, generally costly and have a high energy demand during production. The question arises whether the high performance of FRPs and possible savings in concrete mass can counterbalance initial costs and environmental impact. In this paper, a parametric design study that considers a broad range of concrete infrastructure, namely a rail platform barrier, a retaining wall and a bridge, is conducted to assess the mass-related global warming potential and material costs. Design equations are parametrised to derive optimum reinforced concrete cross-sectional designs that fulfil the stated requirements for the serviceability limit state and ultimate limit state. Conventional steel reinforcement, glass and carbon FRP reinforcement options are evaluated. It is observed that the cross-sectional design has a significant influence on the environmental impact and cost, with local extrema for both categories determinable when the respective values become a minimum. When comparing the cradle-to-gate impact of the different materials, the fibre-reinforced polymer-reinforced structures are found to provide roughly equivalent or, in some cases, slightly more sustainable solutions than steel-reinforced structures in terms of the global warming potential, but the material costs are higher. In general, the size of the structure determines the cost competitiveness and sustainability of the FRP-reinforced concrete options with the rail platform barrier application showing the greatest potential.
Prosthodontic Treatment in Patients with Temporomandibular Disorders and Orofacial Pain and/or Bruxism: A Review of the Literature
Authors: Minervini Giuseppe , Fiorillo Luca , Russo Diana , Lanza Alessandro , D’Amico Cesare , Cervino Gabriele , Meto Aida , Di Francesco Fabrizio
Published: June 2022

Temporomandibular disorders are a group of conditions affecting the temporomandibular joints, the jaw muscles, and related structures. Patients with temporomandibular signs and/or symptoms frequently present with indications for prosthetic treatment. The management of these patients aims to achieve patient comfort, occlusal stability, and the complex restoration of the teeth. The goal of this review is to provide an overview of the relationship between prosthodontics and temporomandibular disorders and/or bruxism with a focus on the cause-and-effect implications and the strategies for planning prosthetic treatments in patients with temporomandibular disorders and/or bruxism.
The Challenging Future of Pilgrimage after the Pandemic: New Trends in Pilgrimage to Compostela
Authors: Roszak Piotr , Huzarek Tomasz
Published: June 2022

During the COVID-19 period, many authors observed changes occurring in pilgrimage along the Way of Saint James. Pandemics have appeared many times in the history of this route, causing changes in the behavior of pilgrims and their environment, such as improvements in healthcare. In this paper, we begin by examining the new contributions that the pandemic has made to the contemporary religious experience of the Camino. The pandemic can be read in a twofold manner: as an attempt to “verify” the motives and as an “opportunity” to preserve the essence of pilgrimage; it also seems to be capable of changing the attitudes of the residents living along the Camino towards the pilgrims. Next, we point to several phenomena that appear on the horizon of the post-pandemic Camino, such as the isolationism of pilgrims, the dominance of individualism, the medicalization of pilgrimage and the restrictions on access to religious practices. This opens up the question of new forms of asceticism with which the Camino has been associated and new trends in pilgrimage to Compostela.
Applying Religious Studies Discourse during Wartime: On Katō Totsudō’s Discussion of Religious War
Authors: Nishimura Akira
Published: June 2022

This paper argues how the study of religion in Japan influenced the nation’s conduct during the Asia-Pacific War (1931–1945). Specifically, the paper addresses the wartime national indoctrination texts of Katō Totsudō 加藤咄堂 (a.k.a. Katō Yūichirō 加藤熊一郎, 1870–1949). Although Katō was not strictly a religious scholar, analyzing Katō’s texts is significant in understanding the influence of religious theory and religious studies discourse on Japanese society during the war. To illustrate this point, this paper introduces previous studies that have discussed the movements of religious scholars during the war. It then clarifies the significance of discussing Katō’s texts, followed by an introduction to what has been revealed about Katō so far. The paper then examines Katō’s wartime texts that discuss the relationship between war, faith and the readiness to die. The East–West comparison of views of life and death used by Katō was characterized as a wartime application of comparative religion. It was intended to emphasize Japan’s superiority over other countries. Such features agitated Japanese readers to proactively enter the fight to the death through spiritual mobilization in a total war system.
Muslim-Jewish Harmony: A Politically-Contingent Reality
Authors: Ahmed Mohammed Ibraheem
Published: June 2022

This paper argues that Muslim-Jewish relations are largely contingent upon politics. Through the examination of Muslim and Jewish populations and their interaction with the state, this article demonstrates that at times of constructive political engagement, day-to-day Muslim-Jewish encounters are positive. Likewise, at times of political conflict, Muslim-Jewish harmony ceases. This article juxtaposes two distinct eras, along with two opposite case studies within them: Islamic Spain in the eleventh century and Israel in the twentieth/twenty-first century. In this manner, both eras demonstrate that the political reality between Muslims and Jews is the contingent factor that determines Muslim-Jewish relations in general.