bluuebunny/crossref_metadata_2025 huggingface dataset:
An Approach for the Optimization of Thermal Conductivity and Viscosity of Hybrid (Graphene Nanoplatelets, GNPs: Cellulose Nanocrystal, CNC) Nanofluids Using Response Surface Methodology (RSM)
Authors: Yaw Chong Tak , Koh Siaw Paw , Sandhya Madderla , Ramasamy Devarajan , Kadirgama Kumaran , Benedict Foo , Ali Kharuddin , Tiong Sieh Kiong , Abdalla Ahmed N. , Chong Kok Hen
Published: May 2023

Response surface methodology (RSM) is used in this study to optimize the thermal characteristics of single graphene nanoplatelets and hybrid nanofluids utilizing the miscellaneous design model. The nanofluids comprise graphene nanoplatelets and graphene nanoplatelets/cellulose nanocrystal nanoparticles in the base fluid of ethylene glycol and water (60:40). Using response surface methodology (RSM) based on central composite design (CCD) and mini tab 20 standard statistical software, the impact of temperature, volume concentration, and type of nanofluid is used to construct an empirical mathematical formula. Analysis of variance (ANOVA) is applied to determine that the developed empirical mathematical analysis is relevant. For the purpose of developing the equations, 32 experiments are conducted for second-order polynomial to the specified outputs such as thermal conductivity and viscosity. Predicted estimates and the experimental data are found to be in reasonable arrangement. In additional words, the models could expect more than 85% of thermal conductivity and viscosity fluctuations of the nanofluid, indicating that the model is accurate. Optimal thermal conductivity and viscosity values are 0.4962 W/m-K and 2.6191 cP, respectively, from the results of the optimization plot. The critical parameters are 50 °C, 0.0254%, and the category factorial is GNP/CNC, and the relevant parameters are volume concentration, temperature, and kind of nanofluid. From the results plot, the composite is 0.8371. The validation results of the model during testing indicate the capability of predicting the optimal experimental conditions.
Regulation of Insulin Resistance, Lipid Profile and Glucose Metabolism Associated with Polycystic Ovary Syndrome by Tinospora cordifolia
Authors: Rani Ritu , Chitme Havagiray R. , Kukreti Neha , Pant Pankaj , Abdel-Wahab Basel A. , Khateeb Masood Medleri , Habeeb Mohammed Shafiuddin , Bakir Marwa B.
Published: May 2023

Background: The plant Tinospora cordifolia (TC), traditionally known as guduchi or giloy, is used for a number of health conditions as a nutritional supplement and rejuvenation medicine. Its nutritional supplementary products are traditionally recommended for a wide range of health issues, including diabetes, menstruation discomfort, fever, obesity, inflammation, and more. Unfortunately, there has not been extensive research into its effectiveness in treating or managing insulin resistance, lipid and carbohydrate metabolism, hormonal imbalance, and metabolic syndrome-associated polycystic ovary syndrome (PCOS). Methods: Consequently, the present study was designed to induce insulin resistance, dyslipidemia, hormonal abnormality, hyperglycemia, and menstrual disturbance of PCOS using dehydroepiandrosterone (DHEA) in mice and study the effect of oral TC extracts on these factors by using ancient and modern technologies. During the 21-day study, 6 mg/100 g/day of DHEA was given to female mice. Levels of glucose, insulin, lipids, and hormones were estimated. In addition to being seen with the naked eye, the morphological and microscopic changes were also observed on histology slides. Results: The study outcomes show that pretreatment with TC preparations significantly improved biochemical and histological abnormalities in female mice. Diestrus phase was only observed in DHEA-treated animals, while cornified epithelial cells were present in TC-treated mice. Pretreatment with TC satva showed significant (p < 0.001) reductions in body weight compared to placebo. Fasting blood glucose, 1-h OGTT, and 2-h OGTT levels were all significantly lower in TC satva- and oil-treated animals in comparison to the disease control group (p < 0.001). Treatment with TC extracts resulted in a normalization of estradiol, progesterone, and testosterone levels (p < 0.05). Treatment with TC extract improved lipid profiles (p < 0.001), LH/FSH ratios (p < 0.01), fasting insulin levels (p < 0.001), HOMA-IR (p < 0.001), HOMA-Beta (p < 0.001), and QUICKI (p < 0.001). Both macroscopic and microscopic alterations were seen to be restored after TC extract treatment. After being treated with TC satva, oil, and hydroalcoholic extract, the severity of PCOS decreased by 54.86%. Conclusions: These findings lead us to the conclusion that TC extracts and satva as nutritional supplements are useful for treating PCOS and associated symptoms. It is recommended that additional research be conducted to determine the molecular mechanism of action of TC nutritional supplements on PCOS-related changes in metabolic profiles. We also recommend further clinical studies to explore the clinical efficacy and effectiveness of TC nutritional supplements in treating and/or managing PCOS.
Effect of Curcumin Consumption on Inflammation and Oxidative Stress in Patients on Hemodialysis: A Literature Review
Authors: D’andurain Javiera , López Vanessa , Arazo-Rusindo Migdalia , Tiscornia Caterina , Aicardi Valeria , Simón Layla , Mariotti-Celis María Salomé
Published: May 2023

Advanced chronic kidney disease (CKD) stages lead to exacerbated inflammation and oxidative stress. Patients with CKD in stage 5 need renal hemodialysis (HD) to remove toxins and waste products. However, this renal replacement therapy is inefficient in controlling inflammation. Regular curcumin consumption has been shown to reduce inflammation and oxidative stress in subjects with chronic pathologies, suggesting that the daily intake of curcumin may alleviate these conditions in HD patients. This review analyzes the available scientific evidence regarding the effect of curcumin intake on oxidative stress and inflammation in HD patients, focusing on the mechanisms and consequences of HD and curcumin consumption. The inclusion of curcumin as a dietary therapeutic supplement in HD patients has shown to control the inflammation status. However, the optimal dose and oral vehicle for curcumin administration are yet to be determined. It is important to consider studies on curcumin bioaccessibility to design effective oral administration vehicles. This information will contribute to the achievement of future nutritional interventions that validate the efficacy of curcumin supplementation as part of diet therapy in HD.
Racing Experiences of Recreational Distance Runners following Omnivorous, Vegetarian, and Vegan Diets (Part B)—Results from the NURMI Study (Step 2)
Authors: Wirnitzer Katharina , Tanous Derrick , Motevalli Mohamad , Wagner Karl-Heinz , Raschner Christian , Wirnitzer Gerold , Leitzmann Claus , Rosemann Thomas , Knechtle Beat
Published: May 2023

The potential running or endurance performance difference based on following different general types of diets, such as omnivorous, vegetarian, or vegan, remains questionable. Several underlying modifiable factors of long-distance running performance, especially runner training behaviors and experience, diminish the clarity of results when analyzing dietary subgroups. Based on the cross-sectional design (survey), the NURMI Study Step 2 aimed to investigate a plethora of training behaviors among recreational long-distance running athletes and the relationship of general diet types with best time race performance. The statistical analysis was based on Chi-squared and Wilcoxon tests. The final sample (n = 245) included fit recreational long-distance runners following an omnivorous diet (n = 109), a vegetarian diet (n = 45), or a vegan diet (n = 91). Significant differences were found between the dietary subgroups in body mass index (p = 0.001), sex (p = 0.004), marital status (p = 0.029), and running-related motivations for well-being (p < 0.05) but not in age (p = 0.054). No significant difference was found for best time half-marathon, marathon, and/or ultra-marathon race performance based on diet type (p > 0.05). Whether the vegan diet is associated with enhanced endurance performance remains unclear. Although, the present results are suggestive that 100% plant-based (vegan) nutrition is compatible with distance running performance at the least.
Iodine Deficiency, Maternal Hypothyroxinemia and Endocrine Disrupters Affecting Fetal Brain Development: A Scoping Review
Authors: Grossklaus Rolf , Liesenkötter Klaus-Peter , Doubek Klaus , Völzke Henry , Gaertner Roland
Published: May 2023

This scoping review critically discusses the publications of the last 30 years on the impact of mild to moderate iodine deficiency and the additional impact of endocrine disrupters during pregnancy on embryonal/fetal brain development. An asymptomatic mild to moderate iodine deficiency and/or isolated maternal hypothyroxinemia might affect the development of the embryonal/fetal brain. There is sufficient evidence underlining the importance of an adequate iodine supply for all women of childbearing age in order to prevent negative mental and social consequences for their children. An additional threat to the thyroid hormone system is the ubiquitous exposure to endocrine disrupters, which might exacerbate the effects of iodine deficiency in pregnant women on the neurocognitive development of their offspring. Ensuring adequate iodine intake is therefore essential not only for healthy fetal and neonatal development in general, but it might also extenuate the effects of endocrine disruptors. Individual iodine supplementation of women of childbearing age living in areas with mild to moderate iodine deficiency is mandatory as long as worldwide universal salt iodization does not guarantee an adequate iodine supply. There is an urgent need for detailed strategies to identify and reduce exposure to endocrine disrupters according to the “precautional principle”.
Retrospective Analysis of Real-World Data for the Treatment of Obstructive Sleep Apnea with Slow Maxillary Expansion Using a Unique Expansion Dental Appliance (DNA)
Authors: Dao Nhi , Cozean Colette , Chernyshev Oleg , Kushida Clete , Greenburg Jonathan , Alexander Jonathan S.
Published: May 2023

In addition to mandibular advancement devices, dental expansion appliances are an important clinical approach for achieving an increased intra-oral space that promotes airflow and lessens the frequency or severity of apneic events in patients diagnosed with obstructive sleep apnea (OSA). It has been thought that dental expansion in adults must be preceded by oral surgery; however, in this paper, we examine the results of a new technique for slow maxillary expansion without any surgical procedures. The palatal expansion device, DNA (Daytime-Nighttime Appliance), was reviewed in this retrospective study, particularly regarding its effects on measurements of transpalatal width, airway volume, and apnea-hypopnea indices (AHI) as well as its common modalities and complications. The DNA effectively reduced AHI by 46% (p = 0.00001) and significantly increased both airway volume and transpalatal width (p < 0.00001). After DNA treatment, 80% of patients showed some improvement in AHI scores with 28% of patients having their OSA symptoms completely resolved. Compared to the use of mandibular appliances, this approach is intended to create a sustained improvement in airway management that can reduce or eliminate dependence on continuous positive airway pressure (CPAP) or other OSA treatment devices.
PUFAs and Their Derivatives as Emerging Players in Diagnostics and Treatment of Male Fertility Disorders
Authors: Rodak Kamil , Kratz Ewa Maria
Published: May 2023

About 15% of couples worldwide are affected by infertility, with the male factor responsible for approximately 50% of reproductive failures. Male fertility can be influenced by various factors, including an unhealthy lifestyle and diet, often associated with oxidative stress. These changes are frequently the reason for spermatozoan dysfunction, malformations, and lowered count. However, sometimes even with proper semen parameters, fertilization does not occur, and this is referred to as idiopathic infertility. Of particular importance may be molecules contained in the spermatozoan membrane or seminal plasma, such as polyunsaturated fatty acids, including omega-3 (docosahexaenoic and eicosapentaenoic acids) and omega-6 (arachidonic acid) fatty acids and their derivatives (prostaglandins, leukotrienes, thromboxanes, endocannabinoids, isoprostanes), which are vulnerable to the effects of oxidative stress. In the present review, we discuss the influence of these molecules on human male reproductive health and its possible causes, including disrupted oxidative–antioxidative balance. The review also discusses the potential use of these molecules in the diagnostics and treatment of male infertility, with a particular focus on the innovative approach to isoprostanes as biomarkers for male infertility. Given the high occurrence of idiopathic male infertility, there is a need to explore new solutions for the diagnosis and treatment of this condition.
Improvement in Skin Penetration Capacity of Linalool by Using Microemulsion as a Delivery Carrier: Formulation Optimization and In Vitro Evaluation
Authors: Tsai Ming-Jun , Chang Wen-Yu , Chiu I-Hui , Lin I-Ling , Wu Pao-Chu
Published: May 2023

Linalool is an aromatic oil with analgesic, anti-inflammatory and anti-UVB-induced skin damage effects. The aim of this study was to develop a linalool-loaded microemulsion formulation for topical application. In order to quickly obtain an optimal drug-loaded formulation, statistical tools of the response surface methodology and a mixed experimental design with four independent variables of oil (X1), mixed surfactant (X2), cosurfactant (X3) and water (X4) were used to design a series of model formulations in order to analyze the effect of the composition on the characteristics and permeation capacity of linalool-loaded microemulsion formulations and to obtain an appropriate drug-loaded formulation. The results showed that the droplet size, viscosity and penetration capacity of linalool-loaded formulations were significantly affected by formulation component proportions. The skin deposition amount of the drug and flux of such formulations expressively increased about 6.1-fold and 6.5-fold, respectively, when compared to the control group (5% linalool dissolved in ethanol). After 3 months of storage, the physicochemical characteristics and drug level did not show a significant change. The linalool formulation-treated rat skin showed non-significant irritation compared to skin treatments in the distilled-water-treated group. The results showed that specific microemulsion applications might be considered as potential drug delivery carriers for essential oil topical application.
Bulk Flow Optimisation of Amorphous Solid Dispersion Excipient Powders through Surface Modification
Authors: Suhaidi Danni , Dong Yao-Da , Wynne Paul , Hapgood Karen P. , Morton David A. V.
Published: May 2023

Particulate amorphous solid dispersions (ASDs) have been recognised for their potential to enhance the performance of various solid dose forms, especially oral bioavailability and macromolecule stability. However, the inherent nature of spray-dried ASDs leads to their surface cohesion/adhesion, including hygroscopicity, which hinders their bulk flow and affects their utility and viability in terms of powder production, processing, and function. This study explores the effectiveness of L-leucine (L-leu) coprocessing in modifying the particle surface of ASD-forming materials. Various contrasting prototype coprocessed ASD excipients from both the food and pharmaceutical industries were examined for their effective coformulation with L-leu. The model/prototype materials included maltodextrin, polyvinylpyrrolidone (PVP K10 and K90), trehalose, gum arabic, and hydroxypropyl methylcellulose (HPMC E5LV and K100M). The spray-drying conditions were set such that the particle size difference was minimised, so that it did not play a substantial role in influencing powder cohesion. Scanning electron microscopy was used to evaluate the morphology of each formulation. A combination of previously reported morphological progression typical of L-leu surface modification and previously unreported physical characteristics was observed. The bulk characteristics of these powders were assessed using a powder rheometer to evaluate their flowability under confined and unconfined stresses, flow rate sensitivities, and compactability. The data showed a general improvement in maltodextrin, PVP K10, trehalose and gum arabic flowability measures as L-leu concentrations increased. In contrast, PVP K90 and HPMC formulations experienced unique challenges that provided insight into the mechanistic behaviour of L-leu. Therefore, this study recommends further investigations into the interplay between L-leu and the physico-chemical properties of coformulated excipients in future amorphous powder design. This also revealed the need to enhance bulk characterisation tools to unpack the multifactorial impact of L-leu surface modification.
A Metabolome Analysis and the Immunity of Phlomis purpurea against Phytophthora cinnamomi
Authors: Neves Dina , Figueiredo Andreia , Maia Marisa , Laczko Endre , Pais Maria Salomé , Cravador Alfredo
Published: May 2023

Phlomis purpurea grows spontaneously in the southern Iberian Peninsula, namely in cork oak (Quercus suber) forests. In a previous transcriptome analysis, we reported on its immunity against Phytophthora cinnamomi. However, little is known about the involvement of secondary metabolites in the P. purpurea defense response. It is known, though, that root exudates are toxic to this pathogen. To understand the involvement of secondary metabolites in the defense of P. purpurea, a metabolome analysis was performed using the leaves and roots of plants challenged with the pathogen for over 72 h. The putatively identified compounds were constitutively produced. Alkaloids, fatty acids, flavonoids, glucosinolates, polyketides, prenol lipids, phenylpropanoids, sterols, and terpenoids were differentially produced in these leaves and roots along the experiment timescale. It must be emphasized that the constitutive production of taurine in leaves and its increase soon after challenging suggests its role in P. purpurea immunity against the stress imposed by the oomycete. The rapid increase in secondary metabolite production by this plant species accounts for a concerted action of multiple compounds and genes on the innate protection of Phlomis purpurea against Phytophthora cinnamomi. The combination of the metabolome with the transcriptome data previously disclosed confirms the mentioned innate immunity of this plant against a devastating pathogen. It suggests its potential as an antagonist in phytopathogens’ biological control. Its application in green forestry/agriculture is therefore possible.
Genetic Divergence and Population Structure of Xanthomonas albilineans Strains Infecting Saccharum spp. Hybrid and Saccharum officinarum
Authors: Hu Zhong-Ting , Ntambo Mbuya Sylvain , Zhao Jian-Ying , Javed Talha , Shi Yang , Fu Hua-Ying , Huang Mei-Ting , Gao San-Ji
Published: May 2023

Leaf scald caused by Xanthomonas albilineans (Xa) is a major bacterial disease in sugarcane that represents a threat to the global sugar industry. Little is known about the population structure and genetic evolution of this pathogen. In this study, 39 Xa strains were collected from 6 provinces in China. Of these strains, 15 and 24 were isolated from Saccharum spp. hybrid and S. officinarum plants, respectively. Based on multilocus sequence analysis (MLSA), with five housekeeping genes, these strains were clustered into two distinct phylogenetic groups (I and II). Group I included 26 strains from 2 host plants, Saccharum spp. hybrid and S. officinarum collected from 6 provinces, while Group II consisted of 13 strains from S. officinarum plants in the Zhejiang province. Among the 39 Xa strains, nucleotide sequence identities from 5 housekeeping genes were: ABC (99.6–100%), gyrB (99.3–100%), rpoD (98.4–100%), atpD (97.0–100%), and glnA (97.6–100%). These strains were clustered into six groups (A–F), based on the rep-PCR fingerprinting, using primers for ERIC2, BOX A1R, and (GTG)5. UPGMA and PCoA analyses revealed that group A had the most strains (24), followed by group C with 11 strains, while there was 1 strain each in groups B and D–F. Neutral tests showed that the Xa population in S. officinarum had a trend toward population expansion. Selection pressure analysis showed purification selection on five concatenated housekeeping genes from all tested strains. Significant genetic differentiation and infrequent gene flow were found between two Xa populations hosted in Saccharum spp. hybrids and S. officinarum. Altogether, these results provide evidence of obvious genetic divergence and population structures among Xa strains from China.
Comparative Microscopic, Transcriptome and IAA Content Analyses Reveal the Stem Growth Variations in Two Cultivars Ilex verticillata
Authors: Qin Sini , Fu Siyi , Yang Ying , Sun Qiumin , Wang Jingqi , Dong Yanling , Gu Xinyi , Wang Tao , Xie Xiaoting , Mo Xiaorong , Jiang Hangjin , Yu Youxiang , Yan Jijun , Chu Jinfang , Zheng Bingsong , He Yi
Published: May 2023

Ilex verticillata is not only an excellent ornamental tree species for courtyards, but it is also a popular bonsai tree. ‘Oosterwijk’ and ‘Red sprite’ are two varieties of Ilex verticillata. The former has a long stem with few branches, while the latter has a short stem. In order to explain the stem growth differences between the two cultivars ‘Oosterwijk’ and ‘Red sprite’, determination of the microstructure, transcriptome sequence and IAA content was carried out. The results showed that the xylem thickness, vessel area and vessel number of ‘Oosterwijk’ were larger than in ‘Red sprite’. In addition, our analysis revealed that the differentially expressed genes which were enriched in phenylpropanoid biosynthesis; phenylalanine metabolism and phenylalanine, tyrosine and tryptophan biosynthesis in the black and tan modules of the two varieties. We found that AST, HCT and bHLH 94 may be key genes in the formation of shoot difference. Moreover, we found that the IAA content and auxin-related DEGs GH3.6, GH3, ATRP5, IAA27, SAUR36-like, GH3.6-like and AIP 10A5-like may play important roles in the formation of shoot differences. In summary, these results indicated that stem growth variations of ‘Oosterwijk’ and ‘Red sprite’ were associated with DEGs related to phenylpropanoid biosynthesis, phenylalanine metabolism and phenylalanine, tyrosine and tryptophan biosynthesis, as well as auxin content and DEGs related to the auxin signaling pathway.
Shear Thickening Fluid and Its Application in Impact Protection: A Review
Authors: Liu Haiqing , Fu Kunkun , Cui Xiaoyu , Zhu Huixin , Yang Bin
Published: May 2023

Shear thickening fluid (STF) is a dense colloidal suspension of nanoparticles in a carrier fluid in which the viscosity increases dramatically with a rise in shear rate. Due to the excellent energy absorption and energy dissipation of STF, there is a desire to employ STFs in a variety of impact applications. In this study, a comprehensive review on STFs’ applications is presented. First, several common shear thickening mechanisms are discussed in this paper. The applications of different STF impregnated fabric composites and the STF’s contributions on improving the impact, ballistic and stab resistance performance have also been presented. Moreover, recent developments of STF’s applications, including dampers and shock absorbers, are included in this review. In addition, some novel applications (acoustic structure, STF-TENG and electrospun nonwoven mats) based on STF are summarized, to suggest the challenges of future research and propose some more deterministic research directions, e.g., potential trends for applications of STF.
Functional Materials Made by Combining Hydrogels (Cross-Linked Polyacrylamides) and Conducting Polymers (Polyanilines)—A Critical Review
Authors: Barbero Cesar
Published: May 2023

Hydrogels made of cross-linked polyacrlyamides (cPAM) and conducting materials made of polyanilines (PANIs) are both the most widely used materials in each category. This is due to their accessible monomers, easy synthesis and excellent properties. Therefore, the combination of these materials produces composites which show enhanced properties and also synergy between the cPAM properties (e.g., elasticity) and those of PANIs (e.g., conductivity). The most common way to produce the composites is to form the gel by radical polymerization (usually by redox initiators) then incorporate the PANIs into the network by oxidative polymerization of anilines. It is often claimed that the product is a semi-interpenetrated network (s-IPN) made of linear PANIs penetrating the cPAM network. However, there is evidence that the nanopores of the hydrogel become filled with PANIs nanoparticles, producing a composite. On the other hand, swelling the cPAM in true solutions of PANIs macromolecules renders s-IPN with different properties. Technological applications of the composites have been developed, such as photothermal (PTA)/electromechanical actuators, supercapacitors, movement/pressure sensors, etc. PTA devices rely on the absorption of electromagnetic radiation (light, microwaves, radiofrequency) by PANIs, which heats up the composite, triggering the phase transition of a thermosensitive cPAM. Therefore, the synergy of properties of both polymers is beneficial.
Enhancing Pullulan Soft Capsules with a Mixture of Glycerol and Sorbitol Plasticizers: A Multi-Dimensional Study
Authors: Zhou Kecheng , Yang Yucheng , Zheng Bingde , Yu Qiqi , Huang Yayan , Zhang Na , Rama Shriram Mourougane , Zhang Xueqin , Ye Jing , Xiao Meitian
Published: May 2023

The plasticizer is crucial in the plant-based soft capsule. However, meeting the quality requirements of these capsules with a single plasticizer is challenging. To address this issue, this study first investigated the impact of a plasticizer mixture containing sorbitol and glycerol in varying mass ratios and the performance of the pullulan soft film and capsule. The multiscale analysis demonstrates that the plasticizer mixture exhibits superior effectiveness in enhancing the performance of the pullulan film/capsule compared to a single plasticizer. Furthermore, thermogravimetric analysis, Fourier transform infrared spectroscopy, X-ray diffraction, and scanning electron microscopy indicate that the plasticizer mixture enhances the compatibility and thermal stability of the pullulan films without altering their chemical composition. Among the different mass ratios examined, a 15:15 ratio of sorbitol to glycerol (S/G) is identified as the most optimal, leading to superior physicochemical properties and meeting the requirements for brittleness and disintegration time set by the Chinese Pharmacopoeia. This study provides significant insights into the effect of the plasticizer mixture on the performance of pullulan soft capsules and offers a promising application formula for future use.
Estimation and Validation of Sub-Pixel Needleleaf Cover Fraction in the Boreal Forest of Alaska to Aid Fire Management
Authors: Badola Anushree , Panda Santosh K. , Thompson David R. , Roberts Dar A. , Waigl Christine F. , Bhatt Uma S.
Published: May 2023

Wildfires, which are a natural part of the boreal ecosystem in Alaska, have recently increased in frequency and size. Environmental conditions (high temperature, low precipitation, and frequent lightning events) are becoming favorable for severe fire events. Fire releases greenhouse gasses such as carbon dioxide into the environment, creating a positive feedback loop for warming. Needleleaf species are the dominant vegetation in boreal Alaska and are highly flammable. They burn much faster due to the presence of resin, and their low-lying canopy structure facilitates the spread of fire from the ground to the canopy. Knowing the needleleaf vegetation distribution is crucial for better forest and wildfire management practices. Our study focuses on needleleaf fraction mapping using a well-documented spectral unmixing approach: multiple endmember spectral mixture analysis (MESMA). We used an AVIRIS-NG image (5 m), upscaled it to 10 m and 30 m spatial resolutions, and applied MESMA to all three images to assess the impact of spatial resolution on sub-pixel needleleaf fraction estimates. We tested a novel method to validate the fraction maps using field data and a high-resolution classified hyperspectral image. Our validation method produced needleleaf cover fraction estimates with accuracies of 73%, 79%, and 78% for 5 m, 10 m, and 30 m image data, respectively. To determine whether these accuracies varied significantly across different spatial scales, we used the McNemar statistical test and found no significant differences between the accuracies. The findings of this study enhance the toolset available to fire managers to manage wildfire and for understanding changes in forest demography in the boreal region of Alaska across the high-to-moderate resolution scale.
Lake Turbidity Mapping Using an OWTs-bp Based Framework and Sentinel-2 Imagery
Authors: Li Sijia , Kutser Tiit , Song Kaishan , Liu Ge , Li Yong
Published: May 2023

Lake turbidity, representing a general indicator of water ‘cloudiness’, is a key parameter in many monitoring programs. It is not possible to cover all lakes with frequent in situ monitoring. Sentinel-2 MultiSpectral Imager (MSI) can help to fill the gaps if a robust turbidity retrieval methodology is developed. Previously published results demonstrated the usefulness of MSI at a limited regional scale, while our aim was to develop methodology that allows monitoring turbidity over the whole of China. We proposed methodology with a reflectance that can be classified into optical water types (OWTs), and then a back propagation neural network model (BP-TURB) is used to estimate turbidity. The reflectance of in situ lake samples extracted from MSI imagery was clustered as three OWTs, and validation performance was satisfactory: R2 > 0.81, RMSE < 17.54, and MAE < 11.20. This allowed us to map turbidity in all Chinese lakes, of which the area is larger than 1 km2. A larger percentage of clear lakes (53.26%) with low turbidity levels (<10 NTU) was found in 2020 than in 2015 (37.43%). Lakes in the plateau regions generally exhibited lower turbidity than those situated in the plains regions, for which the turbidity patterns were determined by lake volume, averaged depth, and elevation. We demonstrated that the Sentinel-2 MSI data with the novel approach proposed by us allows for mapping lake turbidity over a large variety of lakes and extensive geographic conditions, as well as for revealing temporal changes in these lakes and their links to lake abiotic characteristics.
H-RNet: Hybrid Relation Network for Few-Shot Learning-Based Hyperspectral Image Classification
Authors: Liu Xiaoyong , Dong Ziyang , Li Huihui , Ren Jinchang , Zhao Huimin , Li Hao , Chen Weiqi , Xiao Zhanhao
Published: May 2023

Deep network models rely on sufficient training samples to perform reasonably well, which has inevitably constrained their application in classification of hyperspectral images (HSIs) due to the limited availability of labeled data. To tackle this particular challenge, we propose a hybrid relation network, H-RNet, by combining three-dimensional (3-D) convolution neural networks (CNN) and two-dimensional (2-D) CNN to extract the spectral–spatial features whilst reducing the complexity of the network. In an end-to-end relation learning module, the sample pairing approach can effectively alleviate the problem of few labeled samples and learn correlations between samples more accurately for more effective classification. Experimental results on three publicly available datasets have fully demonstrated the superior performance of the proposed model in comparison to a few state-of-the-art methods.
Land Use and Land Cover Mapping with VHR and Multi-Temporal Sentinel-2 Imagery
Authors: Cuypers Suzanna , Nascetti Andrea , Vergauwen Maarten
Published: May 2023

Land Use/Land Cover (LULC) mapping is the first step in monitoring urban sprawl and its environmental, economic and societal impacts. While satellite imagery and vegetation indices are commonly used for LULC mapping, the limited resolution of these images can hamper object recognition for Geographic Object-Based Image Analysis (GEOBIA). In this study, we utilize very high-resolution (VHR) optical imagery with a resolution of 50 cm to improve object recognition for GEOBIA LULC classification. We focused on the city of Nice, France, and identified ten LULC classes using a Random Forest classifier in Google Earth Engine. We investigate the impact of adding Gray-Level Co-Occurrence Matrix (GLCM) texture information and spectral indices with their temporal components, such as maximum value, standard deviation, phase and amplitude from the multi-spectral and multi-temporal Sentinel-2 imagery. This work focuses on identifying which input features result in the highest increase in accuracy. The results show that adding a single VHR image improves the classification accuracy from 62.62% to 67.05%, especially when the spectral indices and temporal analysis are not included. The impact of the GLCM is similar but smaller than the VHR image. Overall, the inclusion of temporal analysis improves the classification accuracy to 74.30%. The blue band of the VHR image had the largest impact on the classification, followed by the amplitude of the green-red vegetation index and the phase of the normalized multi-band drought index.
Rural–Urban, Gender, and Digital Divides during the COVID-19 Lockdown: A Multi-Layered Study
Authors: Mathrani Anuradha , Umer Rahila , Sarvesh Tarushikha , Adhikari Janak
Published: May 2023

This study explores digital divide issues that influenced online learning activities during the COVID-19 lockdown in five developing countries in South Asia. A multi-layered and interpretive analytical lens guided by three interrelated perspectives—structure, cultural practices, and agency—revealed various nuanced aspects across location-based (i.e., rural vs. urban) and across gendered (i.e., male vs. female) student groups. A key message that emerged from our investigation was the subtle ways in which the digital divide is experienced, specifically by female students and by students from rural backgrounds. Female students face more structural and cultural impositions than male students, which restricts them from fully availing digital learning opportunities. Rich empirical evidence shows these impositions are further exacerbated at times of crisis, leading to a lack of learning (agency) for women. This research has provided a gendered and regional outlook on digital discriminations and other inequalities that came to the forefront during the COVID-19 lockdown. This study is especially relevant as online learning is being touted as the next step in digitization; therefore, it can inform educational policymaking and help build inclusive digital societies and bridge current gender and regional divisions.
Contamination and Ecological Risk Evaluation of Metals in Sediments from a Wetland of International Importance (Ramsar Site)
Authors: Ahmed Md. Moudud , Nur As-Ad Ujjaman , Jolly Yeasmin N. , Islam Md. Rakeb Ul , Rahman Mohammad Saifur , Akter Shirin , Yu Jimmy , Albeshr Mohammed Fahad , Arai Takaomi , Hossain Mohammad Belal
Published: May 2023

Wetlands are highly productive and diverse ecosystems providing home to thousands of organisms. These ecosystems reduce water pollution, sequester carbon, support livelihoods, and increase food security. However, these ecological functions are being impeded due to increased levels of metals in the environment. Therefore, the primary objective of this study was to evaluate the degree of metal contamination in the surface sediment of a wetland, Tanguar Haor, for the first time. The result demonstrated that the mean concentrations of Fe, Cu, Zn, As, Pb and Hg varied from 13140.39 to 45675, 40.07 to 46.29, 47.60 to 57.15, 18.89 to 35.23, 1.24 to 2.64, and 0.35 to 0.42, respectively. The concentration of As was found to be higher than the average shale value. The concentration of Cu (44.19 μg/g) and Hg (0.38 μ/g) was very close to the shale value (45 μg/g and 0.40 μg/g, respectively), indicating a moderate level of contamination. The contamination level was further evaluated by multi-indices, e.g., the contamination factor (CF), the enrichment factor (EF), and the geo-accumulation index (Igeo). The average EF values for As (115.41), Cu (57.68), and Hg (55.47) were >50, indicating a high degree of contamination (extremely severe enrichment). However, CF values showed varied levels of pollution; for example, the majority of the area was only somewhat contaminated with As, Cu, and Hg, but less contaminated with Fe, Zn, and Pb. According to Igeo, sampling sites were found to be unpolluted or less polluted by heavy metals. Based on potential ecological risk assessment (PERI), the degree of risk from the six heavy metals decreased in the following sequence: As > Cu > Zn > Pb > Cr > Ni. PERI values indicated the study area has been exposed to moderate risk to As and low risk to other metals. This study provides an opportunity for frequent monitoring of heavy metals in this ecologically critical environment, and thus curbing heavy metal pollution.
Strategies to Control Industrial Emissions: An Analytical Network Process Approach in East Java, Indonesia
Authors: Muryani Muryani , Nisa’ Khoirun , Esquivias Miguel Angel , Zulkarnain Siti Hafsah
Published: May 2023

This study identified the main agents, problems, solutions, and strategies for lowering industrial carbon dioxide (CO2) emissions in the cement industry in East Java, Indonesia, by applying an analytical network process. Respondents included government officials, industrial representatives, and environmental experts. This study revealed that (1) regulators are the critical agents controlling emissions; (2) the three major problems faced when aiming to reduce industrial emissions are limited environmental knowledge, inadequate infrastructure, and unsound regulations; (3) the main solutions are education, socialization, and infrastructure improvement; and (4) the institutional approach is preferable to command-and-control and economic incentives. This suggests that policymakers should collaborate closely with regulators, firms, and communities to more effectively control emissions and encourage environmentally friendly industrial practices. Economic incentives are not preferable strategies, most likely because of insufficient environmental knowledge, market distortion due to subsidies, and low viability. However, the institutional approach incurs higher costs due to political, administrative, and legal processes. Parties may agree on achieving socioeconomic demands but not environmental output. The institutional approach also requires extra investment in education and socialization as well as government support for infrastructure development and a better regulatory framework.
Analysis of the Coordination of Built-Up Area Expansion and Population Growth in the Shandong Peninsula Urban Agglomeration
Authors: Pan Fang , Sun Yingjun , Jiang Na , Jian Zhen , Mei Yuang , Liu Qinghao
Published: May 2023

Exploring the coordinated relationship between built-up area expansion and population growth in the urbanization process is important for the planning and sustainable development of cities. The article took Shandong Peninsula urban agglomeration as the study area, which was divided into the Provincial Capital Economic Circle, Jiaodong Economic Circle, and Lunan Economic Circle according to the plan named the Implementation Plan for Implementing the Opinions of the CPC Central Committee and the State Council on Establishing a New Mechanism for More Effective Regional Co-ordinated Development. The people–land coordination relationship in the region was analyzed from the perspective of spatio-temporal integration through indices such as fractal dimension, spatial autocorrelation, population sprawl, and city land expansion and population growth coordination index (CPI) The results showed that (1) the relationship between built-up area expansion and population growth in the Shandong Peninsula urban agglomeration was uncoordinated. The three economic circles mainly changed from rapid population growth to significant expansion of built-up areas. (2) The development patterns of the three economic circles were different. The Provincial Capital and Jiaodong showed a pattern with Jinan and Qingdao as the core, driving the periphery area. Lunan showed a multi-point scattered development; there was no central city, but Linyi City was developing faster. (3) Jiaodong had the biggest changes in terms of population and built-up area. This study provides a scientific reference for the urban planning and sustainable development of the Shandong Peninsula urban agglomeration.
Hydrodeoxygenation of Pyrolysis Oil in Supercritical Ethanol with Formic Acid as an In Situ Hydrogen Source over NiMoW Catalysts Supported on Different Materials
Authors: Zhang Mingyuan , Han Xue , Wang Huanang , Zeng Yimin , Xu Chunbao Charles
Published: May 2023

Hydrodeoxygenation (HDO) is one of the most promising approaches to upgrading pyrolysis oils, but this process normally operates over expensive noble metal catalysts (e.g., Ru/C, Pt/Al2O3) under high-pressure hydrogen gas, which raises processing costs and safety concerns. In this study, a wood-derived pyrolysis oil was upgraded in supercritical ethanol using formic acid as an in situ hydrogen source at 300 °C and 350 °C, over a series of nickel–molybdenum-tungsten (NiMoW) catalysts supported on different materials, including Al2O3, activated carbon, sawdust carbon, and multiwalled nanotubes (MWNTs). The upgrading was also conducted under hydrogen gas (an ex situ hydrogen source) for comparison. The upgrading process was evaluated by oil yield, degree of deoxygenation (DOD), and oil qualities. The NiMoW/MWNT catalyst showed the best HDO performance among all the catalysts tested at 350 °C, with 74.8% and 70.9% of oxygen in the raw pyrolysis oil removed under in situ and ex situ hydrogen source conditions, respectively, which is likely owing to the large pore size and volume of the MWNT support material, while the in situ hydrogen source outperformed the ex situ hydrogen source in terms of upgraded oil yields and qualities, regardless of the catalysts employed.
Study of Turbulent Kinetic Energy and Dissipation Based on Fractal Impeller
Authors: Li Hongjun , Li Xingzhang , Zhan Jin , Chen Wei , Zong Wangyuan
Published: May 2023

Turbulent kinetic energy and turbulent dissipation are important aspects of the flow field characteristics, which can affect the wear and energy loss in mixing equipment. In order to increase equipment wear and energy loss in the mixing process, a series of fractal impellers were designed based on the fractal iteration method, and the effects of the fractal dimension and the number of iterations on the flow field characteristics were investigated. Firstly, the distribution characteristics of turbulent kinetic energy and its uniformity were studied. Then, the distribution characteristics of the turbulent dissipation rate were studied and interpreted using vortex analysis, and the mixing power of the device was further investigated. The results showed that: for the turbulent kinetic energy of the flow field, an increase in the fractal dimension and the number of iterations makes the turbulent kinetic energy intensity of the flow field decrease and the distribution more uniform, compared to the non-iterative impeller, specifically the rectangular secondary iterative impeller caused a 30% reduction in the turbulent kinetic energy intensity and a 50% increase in the uniformity; for the turbulent dissipation of the flow field, in general an increase in the fractal dimension reduces the turbulent dissipation in the flow field, and an increase in the number of iterations increases it slightly, this influence law is due to a change in the trailing vortex caused by the blade structure; and a change in the law of turbulent dissipation also causes a corresponding change in the stirring power, from the non-iterative impeller to a rectangular one iteration impeller, the power decreases by 20% while the average speed decreases by only 5%. In conclusion, the special boundary of the fractal iterative impeller can reduce the turbulent kinetic energy and turbulent dissipation of the flow field to a large extent, and its two characteristics, the fractal dimension and the number of iterations, affect the reduction effect. The results of the study can be used as a reference for the design of mixing equipment to reduce turbulent kinetic energy and turbulent dissipation.
Representations of the Smart Green Concept and the Intention to Implement IoT in Romanian Real Estate Development
Authors: Cuc Lavinia Denisia , Rad Dana , Manațe Daniel , Szentesi Silviu Gabriel , Dicu Anca , Pantea Mioara Florina , Trifan Vanina Adoriana , Joldeș Cosmin Silviu Raul , Bâtcă-Dumitru Graziella Corina
Published: May 2023

Sustainable urban development has come to play an essential role in establishing and growing future sustainable cities, or smart cities, which are urban areas that have an optimum carbon footprint, are nature-friendly, and are smart enough to enhance energy efficiency. This study is based on qualitative research in which data were collected from interviews with real estate development specialists. The interviews were addressed to a total of 30 real estate developers from Romania between July and December 2022 and were conducted using the Zoom interface. The aim of this research was to analyze whether familiarity with the smart green concept influences the decision to implement the IoT on a large scale at the organizational level through the perception of specific determining factors in choosing the development of green building projects considering the operational costs. The results revealed a significant indirect effect of green building knowledge on large-scale IoT implementation through the mediator of the perception of operating cost factors, supporting our hypothesis. The direct effect in the presence of the mediator was not found to be significant anymore. Hence, there is full complementary mediation by the perception of operating cost factors on the relationship between green building knowledge and large-scale IoT implementation.
Evaluation of Spatial-Temporal Variation of Soil Loss and Best Conservation Measures in an East Africa Catchment
Authors: Hailu Melese Baye , Mishra Surendra Kumar , Jain Sanjay K.
Published: May 2023

Soil conservation (SC) is essential to maintain the reservoir service life and increase the yield since soil erosion is a major global concern that adversely affects not only the storage capacity but also the land fertility. This study evaluates the spatio-temporal variation of soil erosion using the popular SWAT model and identifies the best SC practice for Tekeze watershed located in the Northern part of Ethiopia. To accomplish this, four soil conservation management scenarios involving baseline, terracing, contouring, and grassed waterway scenarios are selected for soil loss evaluation. The SWAT model was calibrated and validated with R2 values of 0.7 and 0.9 and NSE values of 0.8 and 0.7, respectively, indicating satisfactory model performance. Five sub-basins of the catchment were found to be more susceptible to erosion with an average annual soil loss of 25.15 tons/ha/yr. Employment of the proposed SC measures in the sub-watershed erosion was reduced by 35.18%, 27.11%, and 18.76%, respectively, which is significant when compared with the baseline scenario. Since the investment cost of execution of an SC measure in a large watershed is very high, priority areas are also identified for cost savings as well as improved work efficiency.