bluuebunny/crossref_metadata_2025 huggingface dataset:
Investigation of Focusing Wave Properties in a Numerical Wave Tank with a Fully Nonlinear Potential Flow Model
Authors: Wang Weizhi , Kamath Arun , Pakozdi Csaba , Bihs Hans
Published: October 2019

Nonlinear wave interactions and superpositions among the different wave components and wave groups in a random sea sometimes produce rogue waves with extremely large wave heights that appear unexpectedly. A good understanding of the generation and evolution of such extreme wave events is of great importance for the analysis of wave forces on marine structures. A fully nonlinear potential flow (FNPF) model is proposed in the presented paper to investigate the different factors that influence the wave focusing location, focusing time and focusing wave height in a numerical wave tank. Those factors include wave steepness, spectrum bandwidth, wave generation method, focused wave spectrum, and wave spreading functions. The proposed model solves the Laplace equation together with the boundary conditions on a σ -coordinate grid using high-order discretisation schemes on a fully parallel computational framework. The model is validated against the focused wave experiments and thereafter used to obtain insights into the effects of the different factors. It is found that the wave steepness contributes to changing the location and time of focus significantly. Spectrum bandwidth and directional spreading affect the focusing wave height and profile, for example, a wider bandwidth and a wider directional spread lead to a lower focusing wave height. A Neumann boundary condition represents the nonlinearity of the wave groups better than a relaxation method for wave generation.
Design and Experiment of a Plateau Data-Gathering AUV
Authors: Xu Hao , Zhang Guo-Cheng , Sun Yu-Shan , Pang Shuo , Ran Xiang-Rui , Wang Xiang-Bin
Published: October 2019

The design, control, and implementation of an autonomous underwater vehicle (AUV) for collecting hydrological information from plateau rivers and lakes are presented in this paper. The hardware and software structures of the control system were previously described. A novel sliding mode controller (SMC) with combinational reaching law of vertical hovering motion is proposed to improve the robustness and stability. The S-plane control, a nonlinear controller with little parameters, is used in the horizontal motion. Besides, the navigation strategy based on the dead-reckoning algorithm, a path tracking based on the light-of-sight (LOS) algorithm, and a control allocation strategy considering saturation are present. Finally, experiments were performed in a tank and in a river in the Qinghai–Tibet Plateau to prove the feasibility and reliability of the AUV system.
Challenges for Monitoring the Extent and Land Use/Cover Changes in Monarch Butterflies’ Migratory Habitat across the United States and Mexico
Authors: Moreno-Sanchez Rafael , Raines James , Diffendorfer Jay , Drummond Mark , Manko Jessica
Published: October 2019

This paper presents a synopsis of the challenges and limitations presented by existing and emerging land use/land cover (LULC) digital data sets when used to analyze the extent, habitat quality, and LULC changes of the monarch (Danaus plexippus) migratory habitat across the United States of America (US) and Mexico. First, the characteristics, state of the knowledge, and issues related to this habitat are presented. Then, the characteristics of the existing and emerging LULC digital data sets with global or cross-border coverage are listed, followed by the data sets that cover only the US or Mexico. Later, we discuss the challenges for determining the extent, habitat quality, and LULC changes in the monarchs’ migratory habitat when using these LULC data sets in conjunction with the current state of the knowledge of the monarchs’ ecology, behavior, and foraging/roosting plants used during their migration. We point to approaches to address some of these challenges, which can be categorized into: (a) LULC data set characteristics and availability; (b) availability of ancillary land management information; (c) ability to construct accurate forage suitability indices for their migration habitat; and (d) level of knowledge of the ecological and behavioral patterns of the monarchs during their journey.
Merging the Spectral Theories of Distance Estrada and Distance Signless Laplacian Estrada Indices of Graphs
Authors: Alhevaz Abdollah , Baghipur Maryam , Shang Yilun
Published: October 2019

Suppose that G is a simple undirected connected graph. Denote by D ( G ) the distance matrix of G and by T r ( G ) the diagonal matrix of the vertex transmissions in G, and let α ∈ [ 0 , 1 ] . The generalized distance matrix D α ( G ) is defined as D α ( G ) = α T r ( G ) + ( 1 − α ) D ( G ) , where 0 ≤ α ≤ 1 . If ∂ 1 ≥ ∂ 2 ≥ … ≥ ∂ n are the eigenvalues of D α ( G ) ; we define the generalized distance Estrada index of the graph G as D α E ( G ) = ∑ i = 1 n e ∂ i − 2 α W ( G ) n , where W ( G ) denotes for the Wiener index of G. It is clear from the definition that D 0 E ( G ) = D E E ( G ) and 2 D 1 2 E ( G ) = D Q E E ( G ) , where D E E ( G ) denotes the distance Estrada index of G and D Q E E ( G ) denotes the distance signless Laplacian Estrada index of G. This shows that the concept of generalized distance Estrada index of a graph G merges the theories of distance Estrada index and the distance signless Laplacian Estrada index. In this paper, we obtain some lower and upper bounds for the generalized distance Estrada index, in terms of various graph parameters associated with the structure of the graph G, and characterize the extremal graphs attaining these bounds. We also highlight relationship between the generalized distance Estrada index and the other graph-spectrum-based invariants, including generalized distance energy. Moreover, we have worked out some expressions for D α E ( G ) of some special classes of graphs.
Bureaucratic Reshuffling and Efficiency: Do n-Competing Bureaus Determine Inefficient Results?
Authors: Beqiraj Elton , Fedeli Silvia , Tancioni Massimiliano
Published: October 2019

Governments often support their preferences for decentralised (centralised) bureaucracies on the grounds of efficiency considerations (production side). Here, we consider the demand side, i.e., whether the government perception of citizens’ demand for differentiated goods/services might increase efficiency by simply reshuffling bureaucratic production activities. We represent the budgetary process—between an incumbent governing party and n-competing bureaus producing differentiated goods/services—as a simultaneous Nash-compliance game with complete information. On these grounds, we analyse—in terms of public production, players’ rents and payoffs—the effects of increasing competition (as for the number of bureaus) in the political–bureaucratic market. Moreover, we evaluate, ceteris paribus, the effects of bureaucratic reshuffling from the point of view of society, assumed to prefer those policies that approximate social efficiency by minimising bureaucratic and political rents.
Solving Nonholonomic Systems with the Tau Method
Authors: Gavina Alexandra , Matos José M. A. , Vasconcelos Paulo B.
Published: October 2019

A numerical procedure based on the spectral Tau method to solve nonholonomic systems is provided. Nonholonomic systems are characterized as systems with constraints imposed on the motion. The dynamics is described by a system of differential equations involving control functions and several problems that arise from nonholonomic systems can be formulated as optimal control problems. Applying the Pontryagins maximum principle, the necessary optimality conditions along with the transversality condition, a boundary value problem is obtained. Finally, a numerical approach to tackle the boundary value problem is required. Here we propose the Lanczos spectral Tau method to obtain an approximate solution of these problems exploiting the Tau toolbox software library, which allows for ease of use as well as accurate results.
Body of Evidence in Favor of Adopting 130/80 mm Hg as New Blood Pressure Cut-Off for All the Hypertensive Disorders of Pregnancy
Authors: Sisti Giovanni , Williams Belinda
Published: October 2019

The American College of Cardiology/American Heart Association (ACC/AHA) updated its guideline redefining the classification of hypertension and the blood pressure cut-off in 2017. The current cut-offs for stage 1 hypertension of 130 mm Hg systolic blood pressure or 80 mm Hg diastolic blood pressure replace the previous cut-offs of 140 mm Hg systolic blood pressure or 90 mm Hg diastolic blood pressure which were based on the ACC/AHA guidelines from 1988. However, the blood pressure cut-off for the obstetric population still remains as 140/90 mm Hg despite the scarcity of evidence for it. Recent American College of Obstetricians and Gynecologists (ACOG) bulletins for pregnant women have not reflected the new ACC/AHA change of guideline. We reviewed a mounting body of evidence prompting the implementation of the new ACC/AHA guidelines for the obstetric population. These studies examined maternal and fetal outcomes applying the new ACC/AHA guidelines during antepartum or postpartum care.
The Relationship between the Soluble Receptor for Advanced Glycation End Products and Oxidative Stress in Patients with Palmoplantar Warts
Authors: Mitran Cristina Iulia , Nicolae Ilinca , Tampa Mircea , Mitran Madalina Irina , Caruntu Constantin , Sarbu Maria Isabela , Ene Corina Daniela , Matei Clara , Ionescu Antoniu Cringu , Georgescu Simona Roxana , Popa Mircea Ioan
Published: October 2019

Background and objectives: Warts are the most common lesions caused by human papillomavirus (HPV). Recent research suggests that oxidative stress and inflammation are involved in the pathogenesis of HPV-related lesions. It has been shown that the soluble receptor for advanced glycation end products (sRAGE) may act as a protective factor against the deleterious effects of inflammation and oxidative stress, two interconnected processes. However, in HPV infection, the role of sRAGE, constitutively expressed in the skin, has not been investigated in previous studies. Materials and Methods: In order to analyze the role of sRAGE in warts, we investigated the link between sRAGE and the inflammatory response on one hand, and the relationship between sRAGE and the total oxidant/antioxidant status (TOS/TAS) on the other hand, in both patients with palmoplantar warts (n = 24) and healthy subjects as controls (n = 28). Results: Compared to the control group, our results showed that patients with warts had lower levels of sRAGE (1036.50 ± 207.60 pg/mL vs. 1215.32 ± 266.12 pg/mL, p < 0.05), higher serum levels of TOS (3.17 ± 0.27 vs. 2.93 ± 0.22 µmol H2O2 Eq/L, p < 0.01), lower serum levels of TAS (1.85 ± 0.12 vs. 2.03 ± 0.14 µmol Trolox Eq/L, p < 0.01) and minor variations of the inflammation parameters (high sensitivity-CRP, interleukin-6, fibrinogen, and erythrocyte sedimentation rate). Moreover, in patients with warts, sRAGE positively correlated with TAS (r = 0.43, p < 0.05), negatively correlated with TOS (r = −0.90, p < 0.01), and there was no significant correlation with inflammation parameters. There were no significant differences regarding the studied parameters between groups when we stratified the patients according to the number of the lesions and disease duration. Conclusions: Our results suggest that sRAGE acts as a negative regulator of oxidative stress and could represent a mediator involved in the development of warts. However, we consider that the level of sRAGE cannot be used as a biomarker for the severity of warts. To the best of our knowledge, this is the first study to demonstrate that sRAGE could be involved in HPV pathogenesis and represent a marker of oxidative stress in patients with warts.
Assessing the Association of Elevated Zonulin Concentration in Stool with Increased Intestinal Permeability in Active Professional Athletes
Authors: Hałasa Maciej , Maciejewska Dominika , Ryterska Karina , Baśkiewicz-Hałasa Magdalena , Safranow Krzysztof , Stachowska Ewa
Published: October 2019

Background and Objectives: The causative factors or conditions leading to increased intestinal permeability (IIP) have only been partly elucidated, suggesting excessive zonulin release to be a key factor among them. Likewise, it is known that athletic activity predisposes individuals towards the development of IIP; however, little is understood about the nature of this phenomenon. We decided to test the actual coincidence between IIP and increased stool zonulin (ISZ) in actively training athletes. Materials and Methods: We compared intestinal permeability tested with lactulose/mannitol differential absorption (lactulose/mannitol (L/M) test) and zonulin concentration in stool in 20 professional athletes (PRO), 9 amateur athletes (AMA), and 9 non-athletes (CTR). Results: The results confirmed that professional athletic activity showed significant positive association with intestinal permeability. ISZ was observed exclusively in athletes (CTR vs. AMA vs. PRO, respectively, 0% vs. 22% vs. 55%), and its prevalence was significantly higher in PRO than CTR. When we divided the participants into four categories related to exceeding the upper reference limits for both tested parameters (ISZ + or − and IIP + or −), significant differences were found between CTR and PRO; however, no significant differences were found between CTR and AMA or AMA and PRO. Conclusions: Our trial confirmed previous findings that professional athletic activity predisposes individuals to IIP. We also demonstrated that although ISZ was associated with intense training, there was no statistically significant association between ISZ and IIP in the tested group of professional athletes, which suggests the existence of additional mechanisms causing IIP.
Comprehensive Understanding of the Bacterial Populations and Metabolites Profile of Fermented Feed by 16S rRNA Gene Sequencing and Liquid Chromatography–Mass Spectrometry
Authors: Jin Wei , Zhang Zheng , Zhu Kun , Xue Yanfeng , Xie Fei , Mao Shengyong
Published: October 2019

The comprehensive bacterial populations and metabolites profile in fermented feed is unclear, which may have significant effects on the stability of fermented feed quality and animal gut health. In this study, 16S rRNA gene sequencing and liquid chromatography–mass spectrometry were used to explore the bacterial populations and metabolites profile in the fermented feed incubated with probiotics (MF) or without probiotics (SF). The probiotics were a combination of Lactobacillus salivarius, Bacillus subtilis, and Saccharomyces cerevisiae. The pH and lactic acid levels were higher in MF than in SF (P < 0.05), while the total volatile fatty acid content was lower (P < 0.05). Interestingly, after fermentation, the most abundant bacterial genus in MF was Enterococcus, rather than the added probiotics Lactobacillus or Bacillus. Weissella and a few potential pathogens (Enterobacter, Escherichia-Shigella, and Pantoea) were dominant in SF (P < 0.05). Metabolomics analysis identified 32 different metabolites in the two types of fermented feed. These metabolites enriched in MF, such as maleic acid, phenylacetic acid, ethyl linoleate, dihomo-gamma-linolenic acid, and L-theanine had potential antimicrobial activities. Conclusively, the addition of probiotics enriched a few potentially beneficial microbes and small molecular compounds with antimicrobial activities, and inhibited the potential pathogens in fermented feed.
Enhancement of Astaxanthin Biosynthesis in Oleaginous Yeast Yarrowia lipolytica via Microalgal Pathway
Authors: Tramontin Larissa Ribeiro Ramos , Kildegaard Kanchana Rueksomtawin , Sudarsan Suresh , Borodina Irina
Published: October 2019

Astaxanthin is a high-value red pigment and antioxidant used by pharmaceutical, cosmetics, and food industries. The astaxanthin produced chemically is costly and is not approved for human consumption due to the presence of by-products. The astaxanthin production by natural microalgae requires large open areas and specialized equipment, the process takes a long time, and results in low titers. Recombinant microbial cell factories can be engineered to produce astaxanthin by fermentation in standard equipment. In this work, an oleaginous yeast Yarrowia lipolytica was engineered to produce astaxanthin at high titers in submerged fermentation. First, a platform strain was created with an optimised pathway towards β-carotene. The platform strain produced 331 ± 66 mg/L of β-carotene in small-scale cultivation, with the cellular content of 2.25% of dry cell weight. Next, the genes encoding β-ketolase and β-hydroxylase of bacterial (Paracoccus sp. and Pantoea ananatis) and algal (Haematococcus pluvialis) origins were introduced into the platform strain in different copy numbers. The resulting strains were screened for astaxanthin production, and the best strain, containing algal β-ketolase and β-hydroxylase, resulted in astaxanthin titer of 44 ± 1 mg/L. The same strain was cultivated in controlled bioreactors, and a titer of 285 ± 19 mg/L of astaxanthin was obtained after seven days of fermentation on complex medium with glucose. Our study shows the potential of Y. lipolytica as the cell factory for astaxanthin production.
Phenolic Profile of Grape Canes: Novel Compounds Identified by LC-ESI-LTQ-Orbitrap-MS
Authors: Escobar-Avello Danilo , Lozano-Castellón Julián , Mardones Claudia , Pérez Andy J. , Saéz Vania , Riquelme Sebastián , von Baer Dietrich , Vallverdú-Queralt Anna
Published: October 2019

Grape canes (Vitis vinifera L.) are a viticulture industry by-product with an important content of secondary metabolites, mainly polyphenols with a broad spectrum of demonstrated health benefits. Grape canes, therefore, have considerable economic potential as a source of high-value phytochemicals. In this work, liquid chromatography coupled with electrospray ionization hybrid linear trap quadrupole-Orbitrap mass spectrometry (LC–LTQ-Orbitrap) was used for the comprehensive identification of polyphenolic compounds in grape canes. Identification of polyphenols was performed by comparing their retention times, accurate mass measured, and mass fragmentation patterns with those of reference substances or available data in the literature. A total of 75 compounds were identified, including phenolic acids, flavanols, flavonols, flavanonols, flavanones, and stilbenoids. The most abundant polyphenols were proanthocyanidins and stilbenoids and their oligomers. Moreover, the high-resolution mass spectrometry analysis revealed the occurrence of 17 polyphenols never described before in grape canes, thereby providing a more complete polyphenolic profile of this potentially valuable by-product.
Sciadopitys verticillata Resin: Volatile Components and Impact on Plant Pathogenic and Foodborne Bacteria
Authors: Yates David I. , Ownley Bonnie H. , Labbé Nicole , Bozell Joseph J. , Klingeman William E. , Batson Emma K. , Gwinn Kimberly D.
Published: October 2019

Sciadopitys verticillata (Sv) produces a white, sticky, latex-like resin with antimicrobial properties. The aims of this research were to evaluate the effects of this resin (Sv resin) on bacterial populations and to determine the impact of its primary volatile components on bioactivity. The impact of sample treatment on chemical composition of Sv resin was analyzed using Fourier transform infrared spectroscopy (FTIR) coupled with principal component analysis. The presence and concentration of volatiles in lyophilized resin were determined using gas chromatography/mass spectrometry (GC/MS). Changes in bacterial population counts due to treatment with resin or its primary volatile components were monitored. Autoclaving of the samples did not affect the FTIR spectra of Sv resin; however, lyophilization altered spectra, mainly in the CH and C=O regions. Three primary bioactive compounds that constituted >90% of volatiles (1R-α-pinene, tricyclene, and β-pinene) were identified in Sv resin. Autoclaved resin impacted bacterial growth. The resin was stimulatory for some plant and foodborne pathogens (Pseudomonas fluorescens, P. syringae, and Xanthomonas perforans) and antimicrobial for others (Escherichia coli, Bacillus cereus, Agrobacterium tumefaciens, and Erwinia amylovora). Treatment with either 1R-α-pinene or β-pinene reduced B. cereus population growth less than did autoclaved resin. The complex resin likely contains additional antimicrobial compounds that act synergistically to inhibit bacterial growth.
Practical N-Hydroxyphthalimide-Mediated Oxidation of Sulfonamides to N-Sulfonylimines
Authors: Wang Jian , Yi Wen-Jing
Published: October 2019

A new method to prepare sulfonylimines through the oxidation of sulfonamides mediated by N-hydroxyphthalimide under mild conditions has been developed. Compared to reported oxidation methods, broader substrates scope and milder conditions were achieved in our method. Importantly, this oxidation method can afford N-sulfonyl enaminones using Mannich products as starting materials. Additionally, the one-pot Friedel–Crafts arylation reaction of unseparated N-sulfonylimine formed in our system with 1,3,5-trimethoxybenzene was successful without any additional catalyst.
Synthesis and Thermophysical Characterization of Fatty Amides for Thermal Energy Storage
Authors: Canela-Xandri Anna , Villorbina Gemma , Balcells Mercè , Fernández-Francos Xavier , Cabeza Luisa F. , Canela-Garayoa Ramon
Published: October 2019

Nine monoamides were synthesized from carboxylic acids (C8–C18) and crude glycerol. The final monoamides were the result of a rearrangement of the acyl chain during the final hydrogenation process. The purity of the final compounds was determined by spectroscopic and mass spectrometry (MS) techniques. The thermophysical properties of solid monoamides were investigated to determine their capability to act as phase change materials (PCM) in thermal energy storage. Thermophysical properties were determined with a differential scanning calorimeter (DSC). The melting temperatures of the analyzed material ranged from 62.2 °C to 116.4 °C. The analyzed enthalpy of these monoamides ranged from 25.8 kJ/kg to 149.7 kJ/kg. Enthalpy values are analyzed considering the carbon chain and the formation of hydrogen bonds.
Insertion of Carbenes into Deprotonated nido-Undecaborane, B11H13(2-)
Authors: Pecyna Jacek , Rončević Igor , Michl Josef
Published: October 2019

We have examined the insertion of carbenes carrying leaving groups into the [nido-B11H13]2− dianion to form the [closo-1-CB11H12]− anion. The best procedure uses CF3SiMe3 and LiCl as the source of CF2. It is simple, convenient and scalable and proceeds with 70–90% yield. Density functional calculations have been used to develop a mechanistic proposal that accounts for the different behavior of CF2, requiring only one equivalent of base for successful conversion of Na[nido-B11H14]− to [closo-1-CB11H12]−, and CCl2 and CBr2, which require more.
Synthesis, Antiproliferative, and Antioxidant Evaluation of 2-Pentylquinazolin-4(3H)-one(thione) Derivatives with DFT Study
Authors: El-Sayed Amira A. , Ismail Mahmoud F. , Amr Abd El-Galil E. , Naglah Ahmed M.
Published: October 2019

The current study was chiefly designed to examine the antiproliferative and antioxidant activities of some novel quinazolinone(thione) derivatives 6–14. The present work focused on two main points; firstly, comparing between quinazolinone and quinazolinthione derivatives. Whereas, antiproliferative (against two cell lines namely, HepG2 and MCF-7) and antioxidant (by two methods; ABTS and DPPH) activities of the investigated compounds, the best quinazolinthione derivatives were 6 and 14, which exhibited excellent potencies comparable to quinazolinone derivatives 5 and 9, respectively. Secondly, we compared the activity of four series of Schiff bases which included the quinazolinone moiety (11a–d). In addition, the antiproliferative and antioxidant activities of the compounds with various aryl aldehyde hydrazone derivatives (11a–d) analogs were studied. The compounds exhibited potency that increased with increasing electron donating group in p-position (OH > OMe > Cl) due to extended conjugated systems. Noteworthy, most of antiproliferative and antioxidant activities results for the tested compounds are consistent with the DFT calculations.
Maternal Characteristics Affect Fetal Growth Response in the Women First Preconception Nutrition Trial
Authors: Hambidge K Michael , Bann Carla M. , McClure Elizabeth M. , Westcott Jamie E. , Garcés Ana , Figueroa Lester , Goudar Shivaprasad S. , Dhaded Sangappa M. , Pasha Omrana , Ali Sumera A. , Derman Richard J. , Goldenberg Robert L. , Koso-Thomas Marion , Somannavar Manjunath S. , Herekar Veena , Khan Umber , Krebs Nancy F.
Published: October 2019

The objective of this secondary analysis was to identify maternal characteristics that modified the effect of maternal supplements on newborn size. Participants included 1465 maternal–newborn dyads in Guatemala, India, and Pakistan. Supplementation commenced before conception (Arm 1) or late 1st trimester (Arm 2); Arm 3 received usual care. Characteristics included body mass index (BMI), stature, anemia, age, education, socio-economic status (SES), parity, and newborn sex. Newborn outcomes were z-scores for length (LAZ), weight (WAZ), and weight to length ratio-for-age (WLRAZ). Mixed-effect regression models included treatment arm, effect modifier, and arm * effect modifier interaction as predictors, controlling for site, characteristics, and sex. Parity (para-0 vs. para ≥1), anemia (anemia/no anemia), and sex were significant effect modifiers. Effect size (95% CI) for Arm 1 vs. 3 was larger for para-0 vs. ≥1 for all outcomes (LAZ 0.56 (0.28, 0.84, p < 0.001); WAZ 0.45 (0.20, 0.07, p < 0.001); WLRAZ 0.52 (0.17, 0.88, p < 0.01) but only length for Arm 2 vs. 3. Corresponding effects for para ≥1 were >0.02. Arm 3 z-scores were all very low for para-0, but not para ≥1. Para-0 and anemia effect sizes for Arm 1 were > Arm 2 for WAZ and WLRAZ, but not LAZ. Arm 1 and 2 had higher WAZ for newborn boys vs. girls. Maternal nulliparity and anemia were associated with impaired fetal growth that was substantially improved by nutrition intervention, especially when commenced prior to conception.
Monitoring of the Mechanism of Mn Ions Incorporation into Quantum Dots by Optical and EPR Spectroscopy
Authors: Galyametdinov Yuriy G. , Sagdeev Dmitriy O. , Sukhanov Andrey A. , Voronkova Violeta K. , Shamilov Radik R.
Published: October 2019

Synthesis of nanoparticles doped with various ions can significantly expand their functionality. The conditions of synthesis exert significant influence on the distribution nature of doped ions and therefore the physicochemical properties of nanoparticles. In this paper, a correlation between the conditions of synthesis of manganese-containing cadmium sulfide or zinc sulfide nanoparticles and their optical and magnetic properties is analyzed. Electron paramagnetic resonance was used to study the distribution of manganese ions in nanoparticles and the intensity of interaction between them depending on the conditions of synthesis of nanoparticles, the concentration of manganese, and the type of initial semiconductor. The increase of manganese concentration is shown to result in the formation of smaller CdS-based nanoparticles. Luminescent properties of nanoparticles were studied. The 580 nm peak, which is typical for manganese ions, becomes more distinguished with the increase of their concentration and the time of synthesis.
Kinetic Studies and Moisture Diffusivity During Cocoa Bean Roasting
Authors: Domínguez-Pérez Leydy Ariana , Concepción-Brindis Ignacio , Lagunes-Gálvez Laura Mercedes , Barajas-Fernández Juan , Márquez-Rocha Facundo Joaquín , García-Alamilla Pedro
Published: October 2019

Cocoa bean roasting allows for reactions to occur between the characteristic aroma and taste precursors that are involved in the sensory perception of chocolate and cocoa by-products. This work evaluates the moisture kinetics of cocoa beans during the roasting process by applying empirical and semi-empirical exponential models. Four roasting temperatures (100, 140, 180, and 220 °C) were used in a cylindrically designed toaster. Three reaction kinetics were tested (pseudo zero order, pseudo first order, and second order), along with 10 exponential models (Newton, Page, Henderson and Pabis, Logarithmic, Two-Term, Midilli, Verma, Diffusion Approximation, Silva, and Peleg). The Fick equation was applied to estimate the diffusion coefficients. The dependence on the activation energy for the moisture diffusion process was described by the Arrhenius equation. The kinetic parameters and exponential models were estimated by non-linear regression. The models with better reproducibility were the pseudo first order, the Page, and the Verma models (R2 ≥ 0.98). The diffusion coefficients that were calculated were in the order of 1.26 to 5.70 × 109 m s−2 and the energy activation for moisture diffusion obtained was 19.52 kJ mol−1.
Descriptions of Relativistic Dynamics with World Line Condition
Authors: Ciaglia Florio Maria , Di Cosmo Fabio , Ibort Alberto , Marmo Giuseppe
Published: October 2019

In this paper, a generalized form of relativistic dynamics is presented. A realization of the Poincaré algebra is provided in terms of vector fields on the tangent bundle of a simultaneity surface in R 4 . The construction of this realization is explicitly shown to clarify the role of the commutation relations of the Poincaré algebra versus their description in terms of Poisson brackets in the no-interaction theorem. Moreover, a geometrical analysis of the “eleventh generator” formalism introduced by Sudarshan and Mukunda is outlined, this formalism being at the basis of many proposals which evaded the no-interaction theorem.
Shifting Religious Identities and Sharia in Othello
Authors: Johanyak Debra
Published: October 2019

Despite twenty-first century research advances regarding the role of Islam in Shakespeare’s plays, questions remain concerning the extent of William Shakespeare’s knowledge of Muslim culture and his use of that knowledge in writing Othello. I suggest that the playwright had access to numerous sources that informed his depiction of Othello as a man divided between Christian faith and Islamic duty, a division which resulted in the Moor’s destruction. Sharia, a code of moral and legal conduct for Muslims based on the Qur’an’s teachings, appears to be a guiding force in Othello’s ultimate quest for honor. The advance of the Ottoman Empire into Europe with the threat of conquest and forced conversion to Islam was a source of fascination and fear to Elizabethan audiences. Yet, as knowledge increased, so did tolerance to a certain degree. But the defining line between Christian and Muslim remained a firm one that could not be breached without risking the loss of personal identity and spiritual sanctity. Denizens of the Middle East and followers of the Islamic faith, as well as travel encounters between eastern and western cultures, influenced Shakespeare’s treatment of this theme. His play Othello is possibly the only drama of this time period to feature a Moor protagonist who wavers between Christian and Muslim beliefs. To better understand the impetus for Othello’s murder of his wife, the influence of Islamic culture is considered, and in particular, the system of Sharia that governs social, political, and religious conventions of Muslim life, as well as Othello’s conflicting loyalties between Islam as the religion of his youth, and Christianity, the faith to which he had been converted. From Act I celebrating his marriage through Act V recording his death, Othello is overshadowed by fears of who he really is—uncertainty bred of his conversion to Christian faith and his potential to revert to Islamic duty. Without indicating Sharia directly, Shakespeare hints at its subtle influence as Othello struggles between two faiths and two theologies. In killing Desdemona and orchestrating Michael Cassio’s death in response to their alleged adultery, Othello obeys the Old Testament injunction for personal sanctification. But in reverting to Muslim beliefs, he attempts to follow potential Sharia influence to reclaim personal and societal honor.
Landsat-8, Advanced Spaceborne Thermal Emission and Reflection Radiometer, and WorldView-3 Multispectral Satellite Imagery for Prospecting Copper-Gold Mineralization in the Northeastern Inglefield Mobile Belt (IMB), Northwest Greenland
Authors: Beiranvand Pour Amin , S. Park Tae-Yoon , Park Yongcheol , Hong Jong Kuk , M Muslim Aidy , Läufer Andreas , Crispini Laura , Pradhan Biswajeet , Zoheir Basem , Rahmani Omeid , Hashim Mazlan , Hossain Mohammad Shawkat
Published: October 2019

Several regions in the High Arctic still lingered poorly explored for a variety of mineralization types because of harsh climate environments and remoteness. Inglefield Land is an ice-free region in northwest Greenland that contains copper-gold mineralization associated with hydrothermal alteration mineral assemblages. In this study, Landsat-8, Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER), and WorldView-3 multispectral remote sensing data were used for hydrothermal alteration mapping and mineral prospecting in the Inglefield Land at regional, local, and district scales. Directed principal components analysis (DPCA) technique was applied to map iron oxide/hydroxide, Al/Fe-OH, Mg-Fe-OH minerals, silicification (Si-OH), and SiO2 mineral groups using specialized band ratios of the multispectral datasets. For extracting reference spectra directly from the Landsat-8, ASTER, and WorldView-3 (WV-3) images to generate fraction images of end-member minerals, the automated spectral hourglass (ASH) approach was implemented. Linear spectral unmixing (LSU) algorithm was thereafter used to produce a mineral map of fractional images. Furthermore, adaptive coherence estimator (ACE) algorithm was applied to visible and near-infrared and shortwave infrared (VINR + SWIR) bands of ASTER using laboratory reflectance spectra extracted from the USGS spectral library for verifying the presence of mineral spectral signatures. Results indicate that the boundaries between the Franklinian sedimentary successions and the Etah metamorphic and meta-igneous complex, the orthogneiss in the northeastern part of the Cu-Au mineralization belt adjacent to Dallas Bugt, and the southern part of the Cu-Au mineralization belt nearby Marshall Bugt show high content of iron oxides/hydroxides and Si-OH/SiO2 mineral groups, which warrant high potential for Cu-Au prospecting. A high spatial distribution of hematite/jarosite, chalcedony/opal, and chlorite/epidote/biotite were identified with the documented Cu-Au occurrences in central and southwestern sectors of the Cu-Au mineralization belt. The calculation of confusion matrix and Kappa Coefficient proved appropriate overall accuracy and good rate of agreement for alteration mineral mapping. This investigation accomplished the application of multispectral/multi-sensor satellite imagery as a valuable and economical tool for reconnaissance stages of systematic mineral exploration projects in remote and inaccessible metallogenic provinces around the world, particularly in the High Arctic regions.
Assessing Legacy Effects of Wildfires on the Crown Structure of Fire-Tolerant Eucalypt Trees Using Airborne LiDAR Data
Authors: Karna Yogendra K. , Penman Trent D. , Aponte Cristina , Bennett Lauren T.
Published: October 2019

The fire-tolerant eucalypt forests of south eastern Australia are assumed to fully recover from even the most intense fires; however, surprisingly, very few studies have quantitatively assessed that recovery. The accurate assessment of horizontal and vertical attributes of tree crowns after fire is essential to understand the fire’s legacy effects on tree growth and on forest structure. In this study, we quantitatively assessed individual tree crowns 8.5 years after a 2009 wildfire that burnt extensive areas of eucalypt forest in temperate Australia. We used airborne LiDAR data validated with field measurements to estimate multiple metrics that quantified the cover, density, and vertical distribution of individual-tree crowns in 51 plots of 0.05 ha in fire-tolerant eucalypt forest across four wildfire severity types (unburnt, low, moderate, high). Significant differences in the field-assessed mean height of fire scarring as a proportion of tree height and in the proportions of trees with epicormic (stem) resprouts were consistent with the gradation in fire severity. Linear mixed-effects models indicated persistent effects of both moderate and high-severity wildfire on tree crown architecture. Trees at high-severity sites had significantly less crown projection area and live crown width as a proportion of total crown width than those at unburnt and low-severity sites. Significant differences in LiDAR -based metrics (crown cover, evenness, leaf area density profiles) indicated that tree crowns at moderate and high-severity sites were comparatively narrow and more evenly distributed down the tree stem. These conical-shaped crowns contrasted sharply with the rounded crowns of trees at unburnt and low-severity sites and likely influenced both tree productivity and the accuracy of biomass allometric equations for nearly a decade after the fire. Our data provide a clear example of the utility of airborne LiDAR data for quantifying the impacts of disturbances at the scale of individual trees. Quantified effects of contrasting fire severities on the structure of resprouter tree crowns provide a strong basis for interpreting post-fire patterns in forest canopies and vegetation profiles in Light Detection and Ranging (LiDAR) and other remotely-sensed data at larger scales.
Liquid Water Detection under the South Polar Layered Deposits of Mars—A Probabilistic Inversion Approach
Authors: Lauro Sebastian Emanuel , Soldovieri Francesco , Orosei Roberto , Cicchetti Andrea , Cartacci Marco , Mattei Elisabetta , Cosciotti Barbara , Di Paolo Federico , Noschese Raffaella , Pettinelli Elena
Published: October 2019

Liquid water was present on the surface of Mars in the distant past; part of that water is now in the ground in the form of permafrost and heat from the molten interior of the planet could cause it to melt at depth. MARSIS (Mars Advanced Radar for Subsurface and Ionosphere Sounding) has surveyed the Martian subsurface for more than fifteen years in search for evidence of such water buried at depth. Radar detection of liquid water can be stated as an inverse electromagnetic scattering problem, starting from the echo intensity collected by the antenna. In principle, the electromagnetic problem can be modelled as a normal plane wave that propagates through a three-layered medium made of air, ice and basal material, with the final goal of determining the dielectric permittivity of the basal material. In practice, however, two fundamental aspects make the inversion procedure of this apparent simple model rather challenging: (i) the impossibility to use the absolute value of the echo intensity in the inversion procedure; (ii) the impossibility to use a deterministic approach to retrieve the basal permittivity. In this paper, these issues are faced by assuming a priori information on the ice electromagnetic properties and adopting an inversion probabilistic approach. All the aspects that can affect the estimation of the basal permittivity below the Martian South polar cap are discussed and how detection of the presence of basal liquid water was done is described.
Fast and Robust Monocular Visua-Inertial Odometry Using Points and Lines
Authors: Zhang Ning , Zhao Yongjia
Published: October 2019

When the camera moves quickly and the image is blurred or the texture in the scene is missing, the Simultaneous Localization and Mapping (SLAM) algorithm based on point feature experiences difficulty tracking enough effective feature points, and the positioning accuracy and robustness are poor, and even may not work properly. For this problem, we propose a monocular visual odometry algorithm based on the point and line features and combining IMU measurement data. Based on this, an environmental-feature map with geometric information is constructed, and the IMU measurement data is incorporated to provide prior and scale information for the visual localization algorithm. Then, the initial pose estimation is obtained based on the motion estimation of the sparse image alignment, and the feature alignment is further performed to obtain the sub-pixel level feature correlation. Finally, more accurate poses and 3D landmarks are obtained by minimizing the re-projection errors of local map points and lines. The experimental results on EuRoC public datasets show that the proposed algorithm outperforms the Open Keyframe-based Visual-Inertial SLAM (OKVIS-mono) algorithm and Oriented FAST and Rotated BRIEF-SLAM (ORB-SLAM) algorithm, which demonstrates the accuracy and speed of the algorithm.
Practical and Durable Flexible Strain Sensors Based on Conductive Carbon Black and Silicone Blends for Large Scale Motion Monitoring Applications
Authors: Xia Yun , Zhang Qi , Wu Xue E. , Kirk Tim V. , Chen Xiao Dong
Published: October 2019

Presented is a flexible capacitive strain sensor, based on the low cost materials silicone (PDMS) and carbon black (CB), that was fabricated by casting and curing of successive silicone layers—a central PDMS dielectric layer bounded by PDMS/CB blend electrodes and packaged by exterior PDMS films. It was effectively characterized for large flexion-angle motion wearable applications, with strain sensing properties assessed over large strains (50%) and variations in temperature and humidity. Additionally, suitability for monitoring large tissue deformation was established by integration with an in vitro digestive model. The capacitive gauge factor was approximately constant at 0.86 over these conditions for the linear strain range (3 to 47%). Durability was established from consistent relative capacitance changes over 10,000 strain cycles, with varying strain frequency and elongation up to 50%. Wearability and high flexion angle human motion detection were demonstrated by integration with an elbow band, with clear detection of motion ranges up 90°. The device’s simple structure and fabrication method, low-cost materials and robust performance, offer promise for expanding the availability of wearable sensor systems.
Life-Cycle Modeling of Structural Defects via Computational Geometry and Time-Series Forecasting
Authors: Mohamadi Sara , Lattanzi David
Published: October 2019

The evaluation of geometric defects is necessary in order to maintain the integrity of structures over time. These assessments are designed to detect damages of structures and ideally help inspectors to estimate the remaining life of structures. Current methodologies for monitoring structural systems, while providing useful information about the current state of a structure, are limited in the monitoring of defects over time and in linking them to predictive simulation. This paper presents a new approach to the predictive modeling of geometric defects. A combination of segments from point clouds are parametrized using the convex hull algorithm to extract features from detected defects, and a stochastic dynamic model is then adapted to these features to model the evolution of the hull over time. Describing a defect in terms of its parameterized hull enables consistent temporal tracking for predictive purposes, while implicitly reducing data dimensionality and complexity as well. In this study, two-dimensional (2D) point clouds analogous to information derived from point clouds were firstly generated over simulated life cycles. The evolutions of point cloud hull parameterizations were modeled as stochastic dynamical processes via autoregressive integrated moving average (ARIMA) and vectorized autoregression (VAR) and compared against ground truth. The results indicate that this convex hull approach provides consistent and accurate representations of defect evolution across a range of defect topologies and is reasonably robust to noisy measurements; however, assumptions regarding the underlying dynamical process play a significant the role in predictive accuracy. The results were then validated on experimental data from fatigue testing with high accuracy. Longer term, the results of this work will support finite element model updating for predictive analysis of structural capacity.
Two-Wired Active Spring-Loaded Dry Electrodes for EEG Measurements
Authors: Lee Seungchan , Shin Younghak , Kumar Anil , Kim Kiseon , Lee Heung-No
Published: October 2019

Dry contact electrode-based EEG acquisition is one of the easiest ways to obtain neural information from the human brain, providing many advantages such as rapid installation, and enhanced wearability. However, high contact impedance due to insufficient electrical coupling at the electrode-scalp interface still remains a critical issue. In this paper, a two-wired active dry electrode system is proposed by combining finger-shaped spring-loaded probes and active buffer circuits. The shrinkable probes and bootstrap topology-based buffer circuitry provide reliable electrical coupling with an uneven and hairy scalp and effective input impedance conversion along with low input capacitance. Through analysis of the equivalent circuit model, the proposed electrode was carefully designed by employing off-the-shelf discrete components and a low-noise zero-drift amplifier. Several electrical evaluations such as noise spectral density measurements and input capacitance estimation were performed together with simple experiments for alpha rhythm detection. The experimental results showed that the proposed electrode is capable of clear detection for the alpha rhythm activation, with excellent electrical characteristics such as low-noise of 1.131 μVRMS and 32.3% reduction of input capacitance.
Dropping Counter: A Detection Algorithm for Identifying Odour-Evoked Responses from Noisy Electroantennograms Measured by a Flying Robot
Authors: Lan Bluest , Kanzaki Ryohei , Ando Noriyasu
Published: October 2019

The electroantennogram (EAG) is a technique used for measuring electrical signals from the antenna of an insect. Its rapid response time, quick recovery speed, and high sensitivity make it suitable for odour-tracking tasks employing mobile robots. However, its application to flying robots has not been extensively studied owing to the electrical and mechanical noises generated. In this study, we investigated the characteristics of the EAG mounted on a tethered flying quadcopter and developed a special counter-based algorithm for detecting the odour-generated responses. As the EAG response is negative, the algorithm creates a window and compares the values inside it. Once a value is smaller than the first one, the counter will increase by one and finally turns the whole signal into a clearer odour stimulated result. By experimental evaluation, the new algorithm gives a higher cross-correlation coefficient when compared with the fixed-threshold method. The result shows that the accuracy of this novel algorithm for recognising odour-evoked EAG signals from noise exceeds that of the traditional method; furthermore, the use of insect antennae as odour sensors for flying robots is demonstrated to be feasible.