Use of Physics-Based Models for Different Applications of Electrochemical Energy Storage and Conversion Devices
Authors: Ramadesigan Venkatasailanathan 
Published: September 2023

This talk will present the application of physics-based models applied to two different electrochemical storage and conversion systems, viz. Li-ion batteries and Proton Exchange Membrane Fuel Cells (PEMFCs). Battery energy storage system (BESS) is becoming a crucial part of standalone renewable hybrid power systems due to the intermittent nature of power generation and for aiding in various operations like frequency regulation, voltage support, and peak shaving. The lithium-ion battery is a promising choice for BESS due to its high energy density, power density, operating voltage, negligible self-discharge, suitable operating temperature range, modularity, and reliability. A standalone renewable hybrid power system framework with lithium-ion battery energy storage is developed to investigate its performance using physics-based battery models. Power management and control strategies are developed for standalone renewable hybrid power systems. These control strategies can track the MPP of the solar cells and wind turbines while avoiding overcharging the battery and guaranteeing 0% dumping power under different ambient and working conditions. The battery is exposed to harsh ambient conditions in the real world, resulting in the dynamic and continuous capacity fade. A thermal management and control strategy is developed to analyze the effect of temperature on lithium-ion batteries' performance and degradation without using external cooling systems. Dynamic battery degradation analysis and life prediction are essential for better techno-economic estimation of renewable hybrid power systems. The impact of BESS size variation on degradation and the cost of energy generation is analyzed. The developed renewable hybrid power system framework is independent of location and system size and can be extended to incorporate other renewable energy generation sources and energy storage systems.

The second part of this talk will focus on using physics-based models to understand the water dynamics and degradation mechanisms inside PEMFC, which is necessary for water management, long-life operation, and cost reduction. PEMFCs have emerged as an alternative green energy technology in various applications such as automobiles, portable and stationary applications, and auxiliary power supplies for space exploration missions. The cost and durability targets remain unmet largely, which restrains the commercialization of the PEMFCs. The major difficulty in modeling lies in the wide scale of dimensions from the millimeter level (flow channel) to the micron level (catalyst layer (CL) thickness). The multi-scale physics-based model enables the life cycle analysis of PEMFC under various operating conditions. The mass transport limitation is the major hurdle in performance enhancement for higher current density operations. It arises from the liquid water generated during the electrochemical reactions, which hinders the reaction sites of CL and oxygen transport reaction sites in the gas diffusion layer, resulting in performance deterioration. Many experimental studies reported the two-phase flow visualization techniques in PEMFCs, viz. neutron imaging, optical visualization, and X-ray radiography. However, the difficulties in conducting experiments for flow visualization and related parameters such as liquid volume fraction have encouraged researchers to adopt numerical simulations that are less expensive and computationally efficient. Understanding liquid water movement inside the cell at the micro-scale help to improve the PEMFC performance at the stack level. Here, we develop a comprehensive 3-D, multiphase, non-isothermal, steady-state physics-based model of the PEMFC that can closely approximate the liquid water flooding and membrane drying. The findings from this work can be used to design an efficient flow configuration and to study membrane deformation due to the shrinking-swelling under humidification and thermal cycling. The ultimate goal of the multi-scale model is to enhance the PEMFC stack output with less degradation.