bluuebunny/crossref_metadata_2025 huggingface dataset:
Quest for New Data: Ionizing Radiation Metrology in the Presence of Laser-Assisted Scattering Processes
Authors: Bianco Davide , Loffredo Filomena , Quarto Maria , Santamaria Amato Luigi
Published: March 2021

Radiation metrology is crucial in space, for instance in monitoring the conditions on-board space vehicles. The energy released in matter by ionizing radiation is due to the atomic and molecular ionization processes, which have been investigated for several decades from both a theoretical and an experimental point of view. Electronic excitation and ionization cross-section are of particular interest in radiation physics, because of their role in the radiation–matter interaction process. Recently, experimental findings have shown that the interplay with a laser field can strongly modify the electronic interaction probabilities and emission spectra. These phenomena are still not completely understood from a theoretical point of view, and the available empirical data concern a few, simple atomic species. We represent a possible dosimetric effect of the interaction with laser light, inferring from experiments the characteristics of laser-assisted cross-sections. Using a Monte-Carlo calculation for simulating the micro-dosimetric aspects of the irradiation of a simple geometry, we show the need of new experimental data and more detailed theoretical approaches to these phenomena in complex molecular systems.
Physiological, Biochemical and Yield-Component Responses of Solanum tuberosum L. Group Phureja Genotypes to a Water Deficit
Authors: Diaz-Valencia Paula , Melgarejo Luz Marina , Arcila Ivon , Mosquera-Vásquez Teresa
Published: March 2021

Water deficits are the major constraint in some potato-growing areas of the world. The effect is most severe at the tuberization stage, resulting in lower yield. Therefore, an assessment of genetic and phenotypic variations resulting from water deficits in Colombia germplasm is required to accelerate breeding efforts. Phenotypic variations in response to a water deficit were studied in a collection of Solanum tuberosum Group Phureja. A progressive water deficit experiment on the tuberization stage was undertaken using 104 genotypes belonging to the Working Collection of the Potato Breeding Program at the Universidad Nacional de Colombia. The response to water deficit conditions was assessed with the relative chlorophyll content (CC), maximum quantum efficiency of PSII (Fv/Fm), relative water content (RWC), leaf sugar content, tuber number per plant (TN) and tuber fresh weight per plant (TW). Principal Component Analysis (PCA) and cluster analysis were used, and the Drought Tolerance Index (DTI) was calculated for the variables and genotypes. The soluble sugar contents increased significantly under the deficit conditions in the leaves, with a weak correlation with yield under both water treatments. The PCA results revealed that the physiological, biochemical and yield-component variables had broad variation, while the yield-component variables more powerfully distinguished between the tolerant and susceptible genotypes than the physiological and biochemical variables. The PCA and cluster analysis based on the DTI revealed different levels of water deficit tolerance for the 104 genotypes. These results provide a foundation for future research directed at understanding the molecular mechanisms underlying potato tolerance to water deficits.
Soil and Regulated Deficit Irrigation Affect Growth, Yield and Quality of ‘Nero d’Avola’ Grapes in a Semi-Arid Environment
Authors: Barbagallo Maria Gabriella , Vesco Giuseppe , Di Lorenzo Rosario , Lo Bianco Riccardo , Pisciotta Antonino
Published: March 2021

The present work studied the effect of two consecutive years of regulated deficit irrigation (RDI) compared to rain fed management on the vegetative growth, yield, and quality of ‘Nero d’Avola’ grapes. The trial was conducted separately in two soils (vertisol and entisol) located at the top and bottom hillside of the same vineyard. Vertisol was characterized by greater depth, organic matter, exchangeable K2O, and total N than entisol. RDI was based on an irrigation volume at 25% of estimated crop evapotranspiration (ETc) up to end of veraison and 10% of estimated ETc up to 15 days before harvest. Predawn water potential (PDWP) was used as indicator of plant water status and irrigation timing. No difference in irrigation management was evident between vertisol and entisol. Under Mediterranean climate conditions, RDI was able to enhance grape yield and vegetative growth, especially in vertisol, but it reduced berry titratable acidity and total anthocyanins. ‘Nero d’Avola’ showed to adapt to drought conditions in the open field. Both soil type and irrigation regimes may provide opportunities to obtain different ‘Nero d’Avola’ wine quality and boost typicality.
Plant Biostimulants from Cyanobacteria: An Emerging Strategy to Improve Yields and Sustainability in Agriculture
Authors: Santini Gaia , Biondi Natascia , Rodolfi Liliana , Tredici Mario R.
Published: March 2021

Cyanobacteria can be considered a promising source for the development of new biostimulants as they are known to produce a variety of biologically active molecules that can positively affect plant growth, nutrient use efficiency, qualitative traits of the final product, and increase plant tolerance to abiotic stresses. Moreover, the cultivation of cyanobacteria in controlled and confined systems, along with their metabolic plasticity, provides the possibility to improve and standardize composition and effects on plants of derived biostimulant extracts or hydrolysates, which is one of the most critical aspects in the production of commercial biostimulants. Faced with these opportunities, research on biostimulant properties of cyanobacteria has undergone a significant growth in recent years. However, research in this field is still scarce, especially as regards the number of investigated cyanobacterial species. Future research should focus on reducing the costs of cyanobacterial biomass production and plant treatment and on identifying the molecules that mediate the biostimulant effects in order to optimize their content and stability in the final product. Furthermore, the extension of agronomic trials to a wider number of plant species, different application doses, and environmental conditions would allow the development of tailored microbial biostimulants, thus facilitating the diffusion of these products among farmers.
Anxiolytic and Antidepressant-Like Effects of Conyza canadensis Aqueous Extract in the Scopolamine Rat Model
Authors: El-Akhal Jamila , Humulescu Ioana , Ionita Radu , Postu Paula Alexandra , Ungureanu Eugen , Hancianu Monica , Bencheikh Rachid , Robu Silvia , Cioanca Oana , Hritcu Lucian
Published: March 2021

Conyza canadensis is a plant widely used in traditional medicine in Morocco for the treatment of varied health challenges. However, to the best of our knowledge, there is no scientific study justifying the traditional use of Conyza extract as an anxiolytic and antidepressant agent. Moreover, data regarding the polyphenolic fraction is limited. Therefore, the present study was conducted to investigate the chemical composition of an aqueous extract obtained from the aerial parts of Conyza, its antioxidant potential, and the anxiolytic and antidepressant-like effects of the sample (100 and 200 mg/kg body weight (bw)) in the scopolamine (Sco) (0.7 mg/kg bw) rat model. To achieve this purpose, a variety of antioxidant tests (including free radical-scavenging activity and lipoxygenase-inhibitory potential assays) and behavioral procedures, such as the elevated plus-maze and forced swimming tests, were performed. The results demonstrated that the aqueous extract of Conyza canadensis is rich in catechins and flavonoids which possess good antioxidant activity. Additionally, concentrations of 100 and 200 mg/kg of the extract exhibited significant anxiolytic and antidepressant-like profiles following scopolamine treatment. Therefore, we propose that the use of Conyza canadensis could be a new pharmacological target for the amelioration of major depression.
New Cross-Talks between Pathways Involved in Grapevine Infection with ‘Candidatus Phytoplasma solani’ Revealed by Temporal Network Modelling
Authors: Škrlj Blaž , Novak Maruša Pompe , Brader Günter , Anžič Barbara , Ramšak Živa , Gruden Kristina , Kralj Jan , Kladnik Aleš , Lavrač Nada , Roitsch Thomas , Dermastia Marina
Published: March 2021

Understanding temporal biological phenomena is a challenging task that can be approached using network analysis. Here, we explored whether network reconstruction can be used to better understand the temporal dynamics of bois noir, which is associated with ‘Candidatus Phytoplasma solani’, and is one of the most widespread phytoplasma diseases of grapevine in Europe. We proposed a methodology that explores the temporal network dynamics at the community level, i.e., densely connected subnetworks. The methodology offers both insights into the functional dynamics via enrichment analysis at the community level, and analyses of the community dissipation, as a measure that accounts for community degradation. We validated this methodology with cases on experimental temporal expression data of uninfected grapevines and grapevines infected with ‘Ca. P. solani’. These data confirm some known gene communities involved in this infection. They also reveal several new gene communities and their potential regulatory networks that have not been linked to ‘Ca. P. solani’ to date. To confirm the capabilities of the proposed method, selected predictions were empirically evaluated.
Chiral Recognition of Homochiral Poly (amidoamine) Dendrimers Substituted with R- and S-Glycidol by Keratinocyte (HaCaT) and Squamous Carcinoma (SCC-15) Cells In Vitro
Authors: Malinga-Drozd Małgorzata , Uram Łukasz , Wróbel Konrad , Wołowiec Stanisław
Published: March 2021

The generation 2 and 3 poly(amidoamine) dendrimers (PAMAM G2 and G3) were converted into N-(2,3-dihydroxy)propyl derivatives by the addition of enantiomerically pure S- and R-glycidol. The homochiral dendrimers bind to HaCaT and SCC-15 cell membranes with an R/S glycidol enantioselectivity ratio of 1.5:1, as was quantitatively determined by fluorescence microscopy and visualized by confocal microscopy. Fully substituted G2 and G3 dendrimers were equipped with 32 and 64 N-(2,3-dihydroxy)propyl residues and showed effectively radial symmetry for homochiral derivatives in 13C NMR spectrum in contrary to analogs obtained by reaction with rac-glycidol. The sub-stoichiometric derivatives of G2 and G3 were also obtained in order to characterize them spectroscopically. The homochiral dendrimers were labeled with two different fluorescent labels, fluorescein, and rhodamine B, using their isothiocyanates to react with G2 and G3 followed by the addition of S- and R-glycidol. Obtained fluorescent derivatives were deficiently filled with N-(2,3-dihydroxy)propyl substituents due to steric hindrance imposed by the attached label. Nevertheless, these derivatives were used to determine their ability to bind to the cell membrane of human keratinocytes (HaCaT) and squamous carcinoma cells (SCC-15). Confocal microscopy images obtained from cells treated with variously labeled conjugates and fluorescence analysis with fluorescence reader allowed us to conclude that R-glycidol derivatives were bound and entered the cells preferentially, with higher accumulation in cancer cells. The G3 polyamidoamine (PAMAM)-based dendrimers were taken up more efficiently than G2 derivatives. Moreover, S- and R-glycidol furnished dendrimers were highly biocompatible with no toxicity up to 300 µM concentrations, in contrast to the amine-terminated PAMAM analogs.
Chloroaluminate Gel Electrolytes Prepared with Copolymers Based on Imidazolium Ionic Liquids and Deep Eutectic Solvent AlCl3:Urea
Authors: Pablos Jesús L. , Tiemblo Pilar , Ellis Gary , Corrales Teresa
Published: March 2021

Polymer gel electrolytes (PGEs) have been prepared with copolymers based on imidazolium ionic liquids and the deep eutectic mixture of AlCl3:urea (uralumina) as liquid electrolyte. The copolymers were synthesized by photopolymerization of vinylpirrolidone or methylmethacrylate with imidazolium bis (trifluoromethane sulfonyl) imide (TFSI) ionic liquid monomer and mixed in an increasing range of wt.% with uralumina. The rheology and electrochemical activity of PGEs were highly dependent on the molar ratio of charged groups and copolymer content. Structure of the PGEs was studied by FTIR and Raman spectroscopy and a correlation between interactions polymer/uralumina and changes in speciation of uralumina was established. Despite the low molecular weight of the copolymers, the resulting polymer electrolytes develop elastomeric character associated with the binding ionic species. Although there is room to improve the electrochemical activity, in this study these new gels provide sufficient electroactivity to make them feasible alternatives as electrolytes in secondary aluminum batteries.
Non-Destructive Detection of Pentachlorophenol Residues in Historical Wooden Objects
Authors: Kraševec Ida , Nemeček Nataša , Lozar Štamcar Maja , Kralj Cigić Irena , Prosen Helena
Published: March 2021

Wood is a natural polymeric material that is an important constituent of many heritage collections. Because of its susceptibility to biodegradation, it is often chemically treated with substances that can be harmful to human health. One of the most widely used wood preservatives was pentachlorophenol (PCP), which is still present in museum objects today, although its use has been restricted for about forty years. The development of non-destructive methods for its determination, suitable for the analysis of valuable objects, is therefore of great importance. In this work, two non-destructive solid-phase microextraction (SPME) methods were developed and optimized, using either headspace or contact mode. They were compared with a destructive solvent extraction method and found to be suitable for quantification in the range of 7.5 to 75 mg PCP/kg wood at room temperature. The developed semi-quantitative methods were applied in the wooden furniture depot of National Museum of Slovenia. PCP was detected inside two furniture objects using headspace mode. The pesticide lindane was also detected in one object. The indoor air of the depot with furniture was also sampled with HS SPME, and traces of PCP were found. According to the results, SPME methods are suitable for the detection of PCP residues in museum objects and in the environment.
New Trends in the Use of Volatile Compounds in Food Packaging
Authors: Beltrán Sanahuja Ana , Valdés García Arantzazu
Published: March 2021

In the last years, many of the research studies in the packaging industry have been focused on food active packaging in order to develop new materials capable of retaining the active agent in the polymeric matrix and controlling its release into food, which is not easy in many cases due to the high volatility of the chemical compounds, as well as their ease of diffusion within polymeric matrices. This review presents a complete revision of the studies that have been carried out on the incorporation of volatile compounds to food packaging applications. We provide an overview of the type of volatile compounds used in active food packaging and the most recent trends in the strategies used to incorporate them into different polymeric matrices. Moreover, a thorough discussion regarding the main factors affecting the retention capacity and controlled release of volatile compounds from active food packaging is presented.
Oxygen Plasma Treated-Electrospun Polyhydroxyalkanoate Scaffolds for Hydrophilicity Improvement and Cell Adhesion
Authors: Esmail Asiyah , Pereira João R. , Zoio Patrícia , Silvestre Sara , Menda Ugur Deneb , Sevrin Chantal , Grandfils Christian , Fortunato Elvira , Reis Maria A. M. , Henriques Célia , Oliva Abel , Freitas Filomena
Published: March 2021

Poly(hydroxyalkanoates) (PHAs) with differing material properties, namely, the homopolymer poly(3-hydroxybutyrate), P(3HB), the copolymer poly(3-hydroxybutyrate-co-3-hydroxyvalerate), P(3HB-co-3HV), with a 3HV content of 25 wt.% and a medium chain length PHA, and mcl-PHA, mainly composed of 3-hydroxydecanoate, were studied as scaffolding material for cell culture. P(3HB) and P(3HB-co-3HV) were individually spun into fibers, as well as blends of the mcl-PHA with each of the scl-PHAs. An overall biopolymer concentration of 4 wt.% was used to prepare the electrospinning solutions, using chloroform as the solvent. A stable electrospinning process and good quality fibers were obtained for a solution flow rate of 0.5 mL h−1, a needle tip collector distance of 20 cm and a voltage of 12 kV for P(3HB) and P(3HB-co-3HV) solutions, while for the mcl-PHA the distance was increased to 25 cm and the voltage to 15 kV. The scaffolds’ hydrophilicity was significantly increased under exposure to oxygen plasma as a surface treatment. Complete wetting was obtained for the oxygen plasma treated scaffolds and the water uptake degree increased in all treated scaffolds. The biopolymers crystallinity was not affected by the electrospinning process, while their treatment with oxygen plasma decreased their crystalline fraction. Human dermal fibroblasts were able to adhere and proliferate within the electrospun PHA-based scaffolds. The P(3HB-co-3HV): mcl-PHA oxygen plasma treated scaffold highlighted the most promising results with a cell adhesion rate of 40 ± 8%, compared to 14 ± 4% for the commercial oxygen plasma treated polystyrene scaffold AlvetexTM. Scaffolds based on P(3HB-co-3HV): mcl-PHA blends produced by electrospinning and submitted to oxygen plasma exposure are therefore promising biomaterials for the development of scaffolds for tissue engineering.
Controlled SrR Delivery by the Incorporation of Mg Particles on Biodegradable PLA-Based Composites
Authors: Ferrández-Montero Ana , Eguiluz Alvaro , Vazquez Elena , Guerrero Joab David , Gonzalez Zoilo , Sanchez-Herencia Antonio Javier , Ferrari Begoña
Published: March 2021

Among several ions playing a vital role in the body, Sr2+ and Mg2+ are involved in the mechanism of bone formation, making them especially useful for bone tissue engineering applications. Recently, polylactic acid (PLA)/Mg composites have emerged as a promising family of biomaterials due to their inherent biocompatibility and biodegradability properties. In these composites, polymer and bio-metal have a synergetic effect—while the PLA inhibits the Mg fast reactivity, Mg provides bioactivity to the inert polymer buffering the medium pH during degradation. Meanwhile, the typical form of administrating Sr2+ to patients is through the medication strontium ranelate (SrR), which increases the bone mineral density. Following this interesting research line, a new group of composites, which integrates Mg particles and SrR charged onto halloysite nanotubes (HNT) in a polymeric matrix, was proposed. PLA/Mg/SrR–HNT composites have been processed following a colloidal route, obtaining homogenous composites granulated and film-shaped. The drug delivery profile was evaluated in terms of in vitro lixiviation/dissolution paying special attention to the synergism of both ions release. The combination of two of the most reported ions involved in bone regeneration in the composite biomaterial may generate extra interest in bone healing applications.
Doxycycline-Doped Polymeric Membranes Induced Growth, Differentiation and Expression of Antigenic Phenotype Markers of Osteoblasts
Authors: Toledano-Osorio Manuel , Manzano-Moreno Francisco J. , Toledano Manuel , Medina-Castillo Antonio L. , Costela-Ruiz Victor J. , Ruiz Concepción , Osorio Raquel
Published: March 2021

Polymeric membranes are employed in guided bone regeneration (GBR) as physical barriers to facilitate bone in-growth. A bioactive and biomimetic membrane with the ability to participate in the healing and regeneration of the bone is necessary. The aim of the present study was to analyze how novel silicon dioxide composite membranes functionalized with zinc or doxycycline can modulate the osteoblasts’ proliferation, differentiation, and expression of selected antigenic markers related to immunomodulation. Nanostructured acrylate-based membranes were developed, blended with silica, and functionalized with zinc or doxycycline. They were subjected to MG63 osteoblast-like cells culturing. Proliferation was assessed by MTT-assay, differentiation by evaluating the alkaline phosphatase activity by a spectrophotometric method and antigenic phenotype was assessed by flow cytometry for selected markers. Mean comparisons were conducted by one-way ANOVA and Tukey tests (p < 0.05). The blending of silica nanoparticles in the tested non-resorbable polymeric scaffold improved the proliferation and differentiation of osteoblasts, but doxycycline doped scaffolds attained the best results. Osteoblasts cultured on doxycycline functionalized membranes presented higher expression of CD54, CD80, CD86, and HLA-DR, indicating a beneficial immunomodulation activity. Doxycycline doped membranes may be a potential candidate for use in GBR procedures in several challenging pathologies, including periodontal disease.
Hypomyelinating Leukodystrophy 15 (HLD15)-Associated Mutation of EPRS1 Leads to Its Polymeric Aggregation in Rab7-Positive Vesicle Structures, Inhibiting Oligodendroglial Cell Morphological Differentiation
Authors: Sawaguchi Sui , Goto Mizuki , Kato Yukino , Tanaka Marina , Tago Kenji , Oizumi Hiroaki , Ohbuchi Katsuya , Mizoguchi Kazushige , Miyamoto Yuki , Yamauchi Junji
Published: March 2021

Pelizaeus–Merzbacher disease (PMD), also known as hypomyelinating leukodystrophy 1 (HLD1), is an X-linked recessive disease affecting in the central nervous system (CNS). The gene responsible for HLD1 encodes proteolipid protein 1 (plp1), which is the major myelin structural protein produced by oligodendroglial cells (oligodendrocytes). HLD15 is an autosomal recessive disease affecting the glutamyl-prolyl-aminoacyl-tRNA synthetase 1 (eprs1) gene, whose product, the EPRS1 protein, is a bifunctional aminoacyl-tRNA synthetase that is localized throughout cell bodies and that catalyzes the aminoacylation of glutamic acid and proline tRNA species. Here, we show that the HLD15-associated nonsense mutation of Arg339-to-Ter (R339X) localizes EPRS1 proteins as polymeric aggregates into Rab7-positive vesicle structures in mouse oligodendroglial FBD-102b cells. Wild-type proteins, in contrast, are distributed throughout the cell bodies. Expression of the R339X mutant proteins, but not the wild-type proteins, in cells induces strong signals regulating Rab7. Whereas cells expressing the wild-type proteins exhibited phenotypes with myelin web-like structures bearing processes following the induction of differentiation, cells expressing the R339X mutant proteins did not. These results indicate that HLD15-associated EPRS1 mutant proteins are localized in Rab7-positive vesicle structures where they modulate Rab7 regulatory signaling, inhibiting cell morphological differentiation. These findings may reveal some of the molecular and cellular pathological mechanisms underlying HLD15.
Preparation and Characterization of CCTO/PDMS Dielectric Elastomers with High Dielectric Constant and Low Dielectric Loss
Authors: Wang Wenqi , Ren Guanguan , Zhou Ming , Deng Wei
Published: March 2021

Dielectric elastomer (DE) is a type of electric field type electroactive polymer material that can produce greater deformation under the action of an electric field and has a faster recovery speed. It has the advantages of high energy density, large strain, low quality, and commercialization, and has become the most widely concerned and researched electroactive polymer material. In this study, copper calcium titanate (CCTO) particles with a large dielectric constant were selected as the filling phase, and a silicone rubber (PDMS) with better biocompatibility and lower elastic modulus was used as the matrix to prepare CCTO/PDMS, which is a new type of dielectric elastomer material. The structure of the dielectric elastomer is analyzed, and its mechanical properties, dielectric properties, and driving deformation are tested. Then, KH550, KH560, and KH570 modified CCTO is used in order to improve the dispersibility of CCTO in PDMS, and modified particles with the best dispersion effect are selected to prepare dielectric elastomer materials. In addition, mechanical properties, dielectric properties, and driving deformation are tested and compared with the dielectric elastomer material before modification. The results show that as the content of CCTO increases, the dielectric constant and elastic modulus of the dielectric elastomer also increase, and the dielectric loss remains basically unchanged at a frequency of 100 Hz. When the filling amount reaches 20 wt%, the dielectric constant of the CCTO/PDMS dielectric elastomer reaches 5.8 (100 Hz), an increase of 120%, while the dielectric loss at this time is only 0.0038 and the elastic modulus is only 0.54 MPa. When the filling amount is 5 wt%, the dielectric elastomer has the largest driving deformation amount, reaching 33.8%. Three silane coupling agents have been successfully grafted onto the surface of CCTO particles, and the KH560 modified CCTO has the best dispersibility in the PDMS matrix. Based on this, a modified CCTO/PDMS dielectric elastomer was prepared. The results show that the improvement of dispersibility improves the dielectric constant. Compared with the unmodified PDMS, when the filling content is 20 wt%, the dielectric constant reaches 6.5 (100 Hz). Compared with PDMS, it has increased by 150%. However, the improvement of dispersion has a greater increase in the elastic modulus, resulting in a decrease in its strain parameters compared with CCTO/PDMS dielectric elastomers, and the electromechanical conversion efficiency has not been significantly improved. When the filling amount of modified CCTO particles is 5 wt%, the dielectric elastomer has the largest driving deformation, reaching 27.4%.
Bamboo Fiber Based Cellulose Nanocrystals/Poly(Lactic Acid)/Poly(Butylene Succinate) Nanocomposites: Morphological, Mechanical and Thermal Properties
Authors: Rasheed Masrat , Jawaid Mohammad , Parveez Bisma
Published: March 2021

The purpose of this work was to investigate the effect of cellulose nanocrystals (CNC) from bamboo fiber on the properties of poly (lactic acid) (PLA)/poly (butylene succinate) (PBS) composites fabricated by melt mixing at 175 °C and then hot pressing at 180 °C. PBS and CNC (0.5, 0.75, 1, 1.5 wt.%) were added to improvise the properties of PLA. The morphological, physiochemical and crystallinity properties of nanocomposites were analysed by field emission scanning electron microscope (FESEM), Fourier-transform infrared spectroscopy (FTIR) and X-ray diffractometry (XRD), respectively. The thermal and tensile properties were analysed by thermogravimetic analysis (TGA), Differential scanning calorimetry (DSC) and Universal testing machine (UTM). PLA-PBS blend shows homogeneous morphology while the composite shows rod-like CNC particles, which are embedded in the polymer matrix. The uniform distribution of CNC particles in the nanocomposites improves their thermal stability, tensile strength and tensile modulus up to 1 wt.%; however, their elongation at break decreases. Thus, CNC addition in PLA-PBS matrix improves structural and thermal properties of the composite. The composite, thus developed, using CNC (a natural fiber) and PLA-PBS (biodegradable polymers) could be of immense importance as they could allow complete degradation in soil, making it a potential alternative material to existing packaging materials in the market that could be environment friendly.
Integrated Conductive Hybrid Electrode Materials Based on PPy@ZIF-67-Derived Oxyhydroxide@CFs Composites for Energy Storage
Authors: Yang Shuaishuai , An Xianhui , Qian Xueren
Published: March 2021

Due to excellent flexibility and hydrophilicity, cellulose fibers (CFs) have become one of the most potential substrate materials in flexible and wearable electronics. In previous work, we prepared cobalt oxyhydroxide with crystal defects modified polypyrrole (PPy)@CFs composites with good electrochemical performance. In this work, we redesigned the crystalline and nanoscale cobalt oxyhydroxide with zeolitic imidazolate frameworks-67 (ZIF-67) as precursor. The results showed that the PPy@ZIF-67 derived cobalt oxyhydroxide@CFs (PZCC) hybrid electrode materials possess far better capacitance of 696.65 F·g−1 than those of PPy@CFs (308.75 F·g−1) and previous PPy@cobalt oxyhydroxide@CFs (571.3 F·g−1) at a current density of 0.2 A·g−1. The PZCC delivers an excellent cyclic stability (capacitance retention of 92.56%). Moreover, the PZCC-supercapacitors (SCs) can provide an energy density of 45.51 mWh cm−3 at a power density of 174.67 mWh·cm−3, suggesting the potential application in energy storage area.
Enhancement of Chloroprene/Natural/Butadiene Rubber Nanocomposite Properties Using Organoclays and Their Combination with Carbon Black as Fillers
Authors: Castaño-Rivera Patricia , Calle-Holguín Isabel , Castaño Johanna , Cabrera-Barjas Gustavo , Galvez-Garrido Karen , Troncoso-Ortega Eduardo
Published: March 2021

Organoclay nanoparticles (Cloisite® C10A, Cloisite® C15) and their combination with carbon black (N330) were studied as fillers in chloroprene/natural/butadiene rubber blends to prepare nanocomposites. The effect of filler type and load on the physical mechanical properties of nanocomposites was determined and correlated with its structure, compatibility and cure properties using Fourier Transformed Infrared (FT-IR), X-ray Diffraction (XRD), Thermogravimetric Analysis (TGA) and rheometric analysis. Physical mechanical properties were improved by organoclays at 5–7 phr. Nanocomposites with organoclays exhibited a remarkable increase up to 46% in abrasion resistance. The improvement in properties was attributed to good organoclay dispersion in the rubber matrix and to the compatibility between them and the chloroprene rubber. Carbon black at a 40 phr load was not the optimal concentration to interact with organoclays. The present study confirmed that organoclays can be a reinforcing filler for high performance applications in rubber nanocomposites.
Adjustment of Olive Fruit Temperature before Grinding for Olive Oil Extraction. Experimental Study and Pilot Plant Trials
Authors: Plasquy Eddy , García Martos José María , Florido Fernández María del Carmen , Sola-Guirado Rafael Rubén , García Martín Juan Francisco
Published: March 2021

Harvesting at high temperatures and bulk transport can negatively influence the quality of olives and lead to undesirable alterations in the extracted oil. Cooling the fruit in the field would be the most logical solution, but it means that the olives arrive too cold at the mill for immediate processing. In this work, the use of warm water in the washing tub to warm up the fruit before grinding instead of flash heat treatment on the paste was assessed in two experiments. In the first one, at the laboratory level, the temperature after milling was determined in three olive cultivars, previously stored at 5 or 10 °C, and then submerged at different water temperatures (25, 30, and 35 °C) for 15, 30, 45, and 60 s. In the second one, two batches of olives were cooled in the field at 5 °C and then conditioned with washing water to obtain a paste at the entrance of the pilot plant malaxer at 27 °C. The temperature of the olives was measured at five points from the discharging up to their entering, as paste, into the malaxer. The results demonstrated the feasibility of the method as the temperature of the ground olives was kept at the desired temperature (28 ± 1 °C). The trials highlight the potential for automating an even more precise adjustment of the temperature of the olives before milling once the washing tub is equipped with a safe heating system.
Understanding the Relationship between Religiosity and Marital Commitment to Marital Stability: An Investigation on Indonesian Female Journalists
Authors: Latifa Rena , Salsabila Salsabila , Yulianto Heri
Published: March 2021

The complete understanding of marital stability is hindered by limitations of theory and method, especially investigation on female journalists. The purpose of the current study was to test the effect of religiosity and marital commitment on the marital stability, by assessing Indonesian female journalists. This research used a quantitative approach with multiple regression analysis methods. The sample of this study involved 200 married female journalists residing in Jakarta and were taken using non-probability sampling techniques, specifically purposive sampling. The measurements used in this study were adaptations of the (1) Marital Stability Scale; (2) Centrality of Religiosity Scale (CRS-15); and (3) Inventory of Marital Commitments. Confirmatory factor analysis (CFA) was used to test the validity of each scale. The results of the F-test showed a p-value = 0.000 (significant), and a total variance explained (R2 value) of 0.224. This finding indicated that religiosity and marital commitment have a significant effect on marital stability (sig < 0.05). The direction of the coefficient regression of the religiosity variable and marital commitment is positive, indicating that the higher the religiosity and marital commitment, the higher the marital stability.
The Lutheran Military Chaplaincy in the Finnish Defence Forces’ Organisation Today. A Multi-Method Approach
Authors: Liuski Tiia , Ubani Martin
Published: March 2021

The Finnish military chaplains’ work focuses on supporting the conscripts’ ethical functioning ability as well as overall wellbeing of the people in the Finnish Defence Forces. This article gives the military chaplains an opportunity to tell in their own words what kind of issues relate to their perceptions working as a successful religious professional in this unique context. The research was carried out with a multi-method data, that includes an electronic questionnaire and an interview data. The results show that as the military chaplains commit and integrate well to their operational environment, they are also a heterogenous occupational group and manage their work very self-directedly. They appear to be more chaplains than soldiers or special officers, but it does not cause significant professional conflicts. The military chaplains’ profession should be described more as contrasting than conflicting overall. The intensity of their personal vocation and religiosity varies, but it affects considerably to their work motivation. It can be interpreted that military chaplains hold, in a sense, a double vocation towards their work where there is a clerical calling and a mission to work in a military environment.
Spiritual Heritage of Europe in the Light of Personalistic Universalism of Karol Wojtyla—John Paul II
Authors: Modrzejewski Arkadiusz
Published: March 2021

The article is devoted to the philosophical and theological thought of Karol Wojtyła, i.e., John Paul II, who in his considerations gave a lot of attention to European issues, including the spiritual heritage of Europe, to European Christianity in its two varieties, i.e., Latin and Byzantine, and to the relationship between European unity and the pluralism of national cultures. We discover the proper sense of Wojtyła’s European thought by referring to his inspiration with the theology of spirituality, which was the future Pope’s first research experience. His vision of Europe is based on personalistic philosophy, thanks to which these considerations take a universal form. The key to understanding universalism is personalistic hermeneutics, owing to which we perceive the source of universality in man understood as a person. However, Wojtyła’s universalism has two faces. It is universalism in the literal sense, thanks to the personalistic perspective. In the axiological layer it also takes the form of Christian or European and in a way also Eurocentric universalism, which is related to the perception of Europe as a depositary and promoter of universal values of Christianity.
Selection of Industrial Trade Waste Resource Recovery Technologies—A Systematic Review
Authors: Elliott Jake A. K. , Ball Andrew S.
Published: March 2021

Industrial wastewater and other trade wastes are often sources of pollution which can cause environmental damage. However, resource recovery approaches have the potential to lead to positive environmental outcomes, profits, and new sources of finite commodities. Information on these waste sources, and the valuable components which may be contained in such waste is increasingly being made available by public, academic and commercial stakeholders (including companies active in meat processing, dairy, brewing, textile and other sectors). Utilising academic and industry literature, this review evaluates several methods of resource recovery (e.g., bioreactors, membrane technologies, and traditional chemical processes) and their advantages and disadvantages in a trade waste setting. This review lays the groundwork for classification of waste and resource recovery technologies, in order to inform process choices, which may lead to wider commercial application of these technologies. Although each waste source and recovery process is unique, membrane bioreactors show promise for a wide range of resource recovery applications. Despite interest, uptake of resource recovery technologies remains low, or not widely championed. For this to change, knowledge needs to increase in several key areas including: availabilities and classification of trade wastes, technology choice processes, and industrial viability.
A Crown Morphology-Based Approach to Individual Tree Detection in Subtropical Mixed Broadleaf Urban Forests Using UAV LiDAR Data
Authors: Xu Wenbing , Deng Susu , Liang Dan , Cheng Xiaojun
Published: March 2021

Owing to the complex forest structure and large variation in crown size, individual tree detection in subtropical mixed broadleaf forests in urban scenes is a great challenge. Unmanned aerial vehicle (UAV) light detection and ranging (LiDAR) is a powerful tool for individual tree detection due to its ability to acquire high density point cloud that can reveal three-dimensional crown structure. Tree detection based on a local maximum (LM) filter, which is applied on a canopy height model (CHM) generated from LiDAR data, is a popular method due to its simplicity. However, it is difficult to determine the optimal LM filter window size and prior knowledge is usually needed to estimate the window size. In this paper, a novel tree detection approach based on crown morphology information is proposed. In the approach, LMs are firstly extracted using a LM filter whose window size is determined by the minimum crown size and then the crown morphology is identified based on local Gi* statistics to filter out LMs caused by surface irregularities contained in CHM. The LMs retained in the final results represent treetops. The approach was applied on two test sites characterized by different forest structures using UAV LiDAR data. The sensitivity of the approach to parameter setting was analyzed and rules for parameter setting were proposed. On the first test site characterized by irregular tree distribution and large variation in crown size, the detection rate and F-score derived by using the optimal combination of parameter values were 72.9% and 73.7%, respectively. On the second test site characterized by regular tree distribution and relatively small variation in crown size, the detection rate and F-score were 87.2% and 93.2%, respectively. In comparison with a variable-size window tree detection algorithm, both detection rates and F-score values of the proposed approach were higher.
Lithology Discrimination Using Sentinel-1 Dual-Pol Data and SRTM Data
Authors: Lu Yi , Yang Changbao , Meng Zhiguo
Published: March 2021

Compared to various optical remote sensing data, studies on the performance of dual-pol Synthetic aperture radar (SAR) on lithology discrimination are scarce. This study aimed at using Sentinel-1 data to distinguish dolomite, andesite, limestone, sandstone, and granite rock types. The backscatter coefficients VV and VH, the ratio VV–VH; the decomposition parameters Entropy, Anisotropy, and Alpha were firstly derived and the Kruskal–Wallis rank sum test was then applied to these polarimetric derived matrices to assess the significance of statistical differences among different rocks. Further, the corresponding gray-level co-occurrence matrices (GLCM) features were calculated. To reduce the redundancy and data dimension, the principal component analysis (PCA) was carried out on the GLCM features. Due to the limited rock samples, before the lithology discrimination, the input variables were selected. Several classifiers were then used for lithology discrimination. The discrimination models were evaluated by overall accuracy, confusion matrices, and the area under the curve-receiver operating characteristics (AUC-ROC). Results show that (1) the statistical differences of the polarimetric derived matrices (backscatter coefficients, ratio, and decomposition parameters) among different rocks was insignificant; (2) texture information derived from Sentinel-1 had great potential for lithology discrimination; (3) partial least square discrimination analysis (PLSDA) had the highest overall accuracy (0.444) among the classification models; (4) though the overall accuracy is unsatisfactory, according to the AUC-ROC and confusion matrices, the predictive ability of PLSDA model for limestone is high with an AUC value of 0.8017, followed by dolomite with an AUC value of 0.7204. From the results, we suggest that the dual-pol Sentinel-1 data are able to correctly distinguish specific rocks and has the potential to capture the variation of different rocks.
Convective Boundary Layer Clouds as Observed with Ground-Based Lidar at a Mid-Latitude Plain Site
Authors: Zhan Yifan , Yi Fan , Liu Fuchao , Zhang Yunpeng , Yu Changming , Zhou Jun
Published: March 2021

A total of 3047 individual shallow cumuli were identified from 9 years of polarization lidar measurements (2011–2019) at Wuhan, China (30.5°N, 114.4°E). These fair-weather shallow cumuli occurred at the top edge of the convective boundary layer between April and October with the maximum occurrence in July over the 30°N plain site. They persisted mostly (>92%) for a short period of ~1–10 min and had a geometrical thickness of ~50–600 m (a mean of 209 ± 138 m). The majority (>94%) of the cloud bases of these cumuli were found to appear ~50–560 m (a mean of 308 ± 254 m) above the lifting condensation level (LCL). In this height range from the LCL to the cloud base, the lidar volume depolarization ratio (δδV) slightly decreased with increasing height, showing gradually increasing condensation in this sub-cloud region due to penetrative thermals. Most of the observed shallow cumuli (79%) formed under the conditions of high near-surface air temperature (>30 °C) and water vapor mixing ratio (>15 g kg−1).
Prediction of Forest Aboveground Biomass Using Multitemporal Multispectral Remote Sensing Data
Authors: Naik Parth , Dalponte Michele , Bruzzone Lorenzo
Published: March 2021

Forest aboveground biomass (AGB) is a prime forest parameter that requires global level estimates to study the global carbon cycle. Light detection and ranging (LiDAR) is the state-of-the-art technology for AGB prediction but it is expensive, and its coverage is restricted to small areas. On the contrary, spaceborne Earth observation data are effective and economical information sources to estimate and monitor AGB at a large scale. In this paper, we present a study on the use of different spaceborne multispectral remote sensing data for the prediction of forest AGB. The objective is to evaluate the effects of temporal, spectral, and spatial capacities of multispectral satellite data for AGB prediction. The study was performed on multispectral data acquired by Sentinel-2, RapidEye, and Dove satellites which are characterized by different spatial resolutions, temporal availability, and number of spectral bands. A systematic process of least absolute shrinkage and selection operator (lasso) variable selection generalized linear modeling, leave-one-out cross-validation, and analysis was accomplished on each satellite dataset for AGB prediction. Results point out that the multitemporal data based AGB models were more effective in prediction than the single-time models. In addition, red-edge and short wave infrared (SWIR) channel dependent variables showed significant improvement in the modeling results and contributed to more than 50% of the selected variables. Results also suggest that high spatial resolution plays a smaller role than spectral and temporal information in the prediction of AGB. The overall analysis emphasizes a good potential of spaceborne multispectral data for developing sophisticated methods for AGB prediction especially with specific spectral channels and temporal information.
Ocean-Surface Heterogeneity Mapping (OHMA) to Identify Regions of Change
Authors: Scarrott Rory Gordon , Cawkwell Fiona , Jessopp Mark , Cusack Caroline , O’Rourke Eleanor , de Bie C.A.J.M.
Published: March 2021

Mapping heterogeneity of the ocean’s surface waters is important for understanding biogeographical distributions, ocean surface habitat mapping, and ocean surface stability. This article describes the Ocean-surface Heterogeneity MApping (OHMA) algorithm—an objective, replicable approach that uses hypertemporal, satellite-derived datasets to map the spatio-temporal heterogeneity of ocean surface waters. The OHMA produces a suite of complementary datasets—a surface spatio-temporal heterogeneity dataset, and an optimised spatio-temporal classification of the ocean surface. It was demonstrated here using a hypertemporal Sea Surface Temperature image dataset of the North Atlantic. Validation with Underway-derived temperature data showed higher heterogeneity areas were associated with stronger surface temperature gradients, or an increased presence of locally extreme temperature values. Using four exploratory case studies, spatio-temporal heterogeneity values were related to a range of region-specific surface and sub-surface characteristics including fronts, currents and bathymetry. The values conveyed the interactions between these parameters as a single metric. Such over-arching heterogeneity information is virtually impossible to map from in-situ instruments, or less temporally dense satellite datasets. This study demonstrated the OHMA approach is a useful and robust tool to explore, examine, and describe the ocean’s surface. It advances our capability to map biologically relevant measures of ocean surface heterogeneity. It can support ongoing efforts in Ocean Surface Partitioning, and attempts to understand marine species distributions. The study highlighted the need to establish dedicated spatio-temporal ocean validation sites, specifically measured using surface transits, to support advances in hypertemporal ocean data use, and exploitation. A number of future research avenues are also highlighted.