bluuebunny/crossref_metadata_2025 huggingface dataset:
Evolving Cultural and Historical Landscapes of Northwestern Colchis during the Medieval Period: Physical Environment and Urban Decline Causes
Authors: Trebeleva Galina , Kizilov Andrey , Lobkovskiy Vasiliy , Yurkov Gleb
Published: December 2022

In Late Antiquity and the Early Middle Ages, both coastal and sub-mountainous parts of Colchis underwent rapid urbanization. In the 12th century, the processes of decline began: Large settlements were replaced by small farmsteads with light wooden buildings, and the economy transformed from commodity-based to subsistence-based. What caused this decline? Was it the social and political events linked to the decline of the Byzantine Empire and changes to world trade routes, or were there other reasons? This article provides the answer. The synergy of archaeological, folkloristic, historical cartographic, climatological, seismological, and hydrological data depicts a strong link between these processes and climate change, which occurred at the turn of the 12th–13th centuries. The beginning of cooling led to a crisis in agriculture. A decline in both farming and cattle breeding could not fail to affect demography. Seismic activity, noted in the same period, led to the destruction of many buildings, including temples, and fortresses, and changes in hydrological networks, which were directly linked to climate change and caused water logging, led to a loss of the functions of coastal areas and their disappearance.
On the Chemical Origin of Biological Cognition
Authors: Pascal Robert , Pross Addy
Published: December 2022

One of life’s most striking characteristics is its mental dimension, one whose very existence within a material system has long been a deep scientific mystery. Given the current scientific view that life emerged from non-life, how was it possible for ‘dead’ matter to have taken on mental capabilities? In this Perspective we describe the existence of a recently discovered non-equilibrium state of matter, an energized dynamic kinetic state, and demonstrate how particular chemical systems once activated into that kinetic state could manifest rudimentary cognitive behavior. Thus, contrary to a common view that biology is not reducible to physics and chemistry, recent findings in both chemistry and biology suggest that life’s mental state is an outcome of its physical state, and therefore may be explicable in physical/chemical terms. Such understanding offers added insight into the physico-chemical process by which life was able to emerge from non-life and the perennial ‘what is life?’ question. Most remarkably, it appears that Darwin, through his deep understanding of the evolutionary process, already sensed the existence of a connection between life’s physical and mental states.
Telerehabilitation in Older Thai Community-Dwelling Adults
Authors: Stonsaovapak Chernkhuan , Sangveraphunsiri Viboon , Jitpugdee Weerachai , Piravej Krisna
Published: December 2022

To investigate the impact on physical performance and walking abilities associated with fall risk and disability in the senior population, we created a telerehabilitation system. This is a multi-site, community setting, pre–post experimental study. We recruited participants from four rural areas in Thailand. All participants received eight weeks of tele-exercise, three sessions per week, via the telerehabilitation system. After the intervention, all participants underwent the Short Physical Performance Battery (SPPB), Timed Up and Go (TUG) test, and the six-minute walk test (6MWT) using a wearable sensor system. A total of 123 participants participated in the study and 2 participants dropped out while conducting the study, thus 121 participants were included in the analysis. In comparison to the baseline, we discovered a considerable improvement in the SPPB score (0.65 ± 0.22, p < 0.001), TUG (−1.70 ± 0.86, p < 0.001), and 6MWT (10.23 ± 7.33, p = 0.007). Our study demonstrates the benefits of telerehabilitation on SPPB, TUG, and 6MWT related to disabilities and fall risk. This telerehabilitation technology demonstrated its viability in the community environment and demonstrated its capacity to offer fundamental components of remote rehabilitation services within the healthcare system.
A Japanese Santa Claus: A Nikkei Subject and Lévi-Strauss’s Gift Theory in Through the Arc of the Rain Forest
Authors: Makino Rie
Published: December 2022

Japanese American writer Karen Tei Yamashita’s first novel, Through the Arc of the Rainforest (1990), portrays protagonist Kazumasa Ishimaru as “a Japanese Santa Claus”, depicted as having a plastic ball spinning in front of his face. Yamashita presents this magic realist hero as a satire of Japan in the 1990s, which became the developed nation needed to support the developing world under the new Marshall Plan. Focusing on Kazumaza’s participation in charity, this essay explores the gift economy embodied by this Japanese immigrant character. Inspired by Claude Lévi-Strauss’s 1952 essay “Burned-out Santa Claus”, Kazumasa’s Nikkei subject position not only criticizes American capitalism but also Brazil’s postcolonial mentality. Supporting the idea that Lévi-Strauss sympathizes with Jean-Jacques Rousseau’s concept of innocence, the last part of the essay probes the idea of Kazumasa as an innocent subject who challenges the dichotomy between American capitalism and postcolonial Brazil.
Three-Body Abrasive Wear Performance of High Chromium White Cast Iron with Different Ti and C Content
Authors: Huq Mohammad Jobayer , Shimizu Kazumichi , Kusumoto Kenta , Purba Riki Hendra
Published: December 2022

The need for better wear-resistant materials to reduce cost and save the environment is noteworthy. The striking wear resistance of high chromium white cast iron (HCCI) has made it industry’s predominant choice. The three-body abrasive wear resistance performance of HCCI was investigated based on combined Ti and C. The Ti and C content varied in different percentages. The addition of Ti resulted in refined M7C3 carbides and TiC crystallization. The hardness was significantly affected by the addition of Ti. The increment in Ti content resulted in a decrease in the hardness, leading to a higher wear rate. However, the individual contribution of C led to higher hardness and, hence, better wear resistance, which is contrary to Ti. Out of the three specimens with 3, 3.5, and 4 wt.% C content, the 4 wt.% C series showed the highest hardness but the lowest wear rate and depth. This study found that the combination of a lower percentage of Ti with a higher percentage of C in HCCI can have a worthwhile result in abrasive wear.
Structural Changes in Block-Shaped WEBAM’ed Ti6Al4V Samples after Friction Stir Processing
Authors: Kalashnikova Tatiana , Cheremnov Andrey , Eliseev Aleksander , Gurianov Denis , Knyazhev Evgeny , Moskvichev Evgeny , Beloborodov Vladimir , Chumaevskii Andrey , Zykova Anna , Kalashnikov Kirill
Published: December 2022

In this paper, the structure and mechanical properties of workpieces made of Ti6Al4V alloy in the shape of blocks manufactured by wire-feed electron beam additive manufacturing and processed by friction stir processing were investigated. Samples were cut from the upper and lower parts of the additive block and processed in the layer deposition direction using different tool loading forces. Studies have shown that the processing of such material forms a clearly defined thermomechanically affected zone represented by nanosized α-grains. In the stir zone, the material is characterized by a fine-dispersed structure with a content of α- and nanosized α″-phase plates. The material after processing demonstrates 24% higher values of the ultimate tensile strength as compared to the base metal in the as-built state.
Nonlocal Strain Gradient Theory for the Bending of Functionally Graded Porous Nanoplates
Authors: Alghanmi Rabab A.
Published: December 2022

Many investigators have become interested in nanostructures due to their outstanding mechanical, chemical, and electrical properties. Two-dimensional nanoplates with higher mechanical properties compared with traditional structural applications are a common structure of nanosystems. Nanoplates have a wide range of uses in various sectors due to their unique properties. This paper focused on the static analysis of functionally graded (FG) nanoplates with porosities. The nonlocal strain gradient theory is combined with four-variable shear deformation theory to model the nanoplate. The proposed model captures both nonlocal and strain gradient impacts on FG nanoplate structures by incorporating the nonlocal and strain gradient factors into the FG plate’s elastic constants. Two different templates of porosity distributions are taken into account. The FG porous nanoplate solutions are compared with previously published ones. The impact of nonlocal and strain gradient parameters, side-to-thickness ratio, aspect ratio, and porosity parameter, are analyzed in detail numerically. This paper presents benchmark solutions for the bending analysis of FG porous nanoplates. Moreover, the current combination of the nonlocal strain gradient theory and the four-variable shear deformation theory can be adapted for various nanostructured materials such as anisotropic, laminated composites, FG carbon nanotube reinforced composites, and so on.
Prediction of the Sound Absorption Coefficient of Three-Layer Aluminum Foam by Hybrid Neural Network Optimization Algorithm
Authors: Mi Han , Guo Wenlong , Liang Lisi , Ma Hongyue , Zhang Ziheng , Gao Yanli , Li Linbo
Published: December 2022

The combination of multilayer aluminum foam can have high sound absorption coefficients (SAC) at low and medium frequencies, and predicting its absorption coefficient can help the optimal structural design. In this study, a hybrid EO-GRNN model was proposed for predicting the sound absorption coefficient of the three-layer composite structure of the aluminum foam. The generalized regression neural network (GRNN) model was used to predict the sound absorption coefficient of three-layer composite structural aluminum foam due to its outstanding nonlinear problem-handling capability. An equilibrium optimization (EO) algorithm was used to determine the parameters in the neuronal network. The prediction results show that this method has good accuracy and high precision. The calculation result shows that this proposed hybrid model outperforms the single GRNN model, the GRNN model optimized by PSO (PSO-GRNN), and the GRNN model optimized by FOA(FOA-GRNN). The prediction results are expressed in terms of root mean square error (RMSE), absolute error, and relative error, and this method performs well with an average RMSE of only 0.011.
Corrosion of Stirred Electrochemical Nano-Crystalline Hydroxyapatite (HA) Coatings on Ti6Al4V
Authors: Ramaswamy Narayanan , Gopalan Venkatachalam , Kwon Tae Yub
Published: December 2022

Ti6Al4V substrates were electrochemically deposited with nano-crystalline hydroxyapatite (HA) from aqueous electrolytes. Cathodic HA coatings were obtained when the electrolyte was stirred using ultrasonic vibration. Two current densities of 20 mA/cm2 and 50 mA/cm2 were employed. Polarization and electrochemical impedance spectroscopy (EIS) were the techniques used to estimate the corrosion of coatings in simulated body fluid (SBF). The results indicate good corrosion resistance for the coating obtained at 50 mA/cm2 from ultrasonic stirring of the electrolyte.
Microstructure and Mechanical Properties of EK30 Alloy Synergistically Reinforced by Ag Alloying and Hot Extrusion for Aerospace Applications
Authors: Zhang Daohe , Zhao Sicong , Chen Hongtao , Feng Yicheng , Guo Erjun , Li Jingfang
Published: December 2022

Enhancing the mechanical properties of magnesium alloys to meet the urgent need for their lightweight applications in the aerospace field has always been a great challenge. Herein, the effect of Ag on the microstructure and tensile properties of the Mg−2.5Nd−1.0Sm−0.4Zn−0.1Ca−0.5Zr (EK30) alloy prepared by integrated extrusion and equal-channel angular pressing is studied. The microstructure of as-extruded alloys consists of α-Mg grains and the β phase. The addition of Ag increases the β-phase content. The β phase can promote dynamic recrystallization by inducing a particle-stimulated nucleation mechanism and inhibiting grain growth, which leads to grain refinement and texture weakening. At 250 °C, the ultimate tensile strength of the EK30–2.0Ag alloy (225.9 MPa) increased by 13.8% compared to the Ag-free alloy (198.4 MPa). When the tensile temperature increased from 25 °C to 250 °C, the ultimate tensile strength of the EK30–2.0Ag alloy decreased by 14.3%, from 263.7 MPa to 225.9 MPa. Notably, the addition of Ag slightly reduced the elongation of the alloy at 250 °C; the elongations of the EK30–2.0Ag alloy and the EK30 alloy are 41.5% and 37.0%, respectively. The elongation of the EK30–2.0Ag alloy increased from 22.7% at 25 °C to 52.7% at 275 °C. All alloy tensile fractures exhibited typical plastic fracture characteristics. This study provides an effective way to enhance the high-temperature mechanical properties of magnesium alloys by Ag alloying and a special severe plastic deformation method.
Research on Pavement Performance of Cement-Stabilized Municipal Solid Waste Incineration Bottom Ash Base
Authors: Shi Chenglin , Li Jia , Sun Shuang , Han Hong
Published: December 2022

In order to clarify the influence of the municipal solid waste incineration bottom ash (MSWI BA) content on the pavement performance of the cement-stabilized macadam, the MSWI BA with 0%, 25%, 38% and 50% content was used instead of fine aggregates. To explore the feasibility of building pavement base with cement stabilized MSWI BA, the cement-stabilized MSWI BA mixture was prepared by mixing the MSWI BA at the mass fraction of 50%, 75% and 100% with fine crushed stuff. Subsequently, the compaction test and 7 days unconfined compression test were conducted with 4%, 5% and 6% cement dosage. The compaction test, unconfined compressive strength test, splitting strength test, compressive resilient modulus test and frost resistance tests were carried out based on the long-age samples with an optimal cement dosage of 5%. Furthermore, the unconfined compressive constitutive model was established based on the test data. Afterwards, the test road was built to measure the practical effect of MSWI BA on road construction. Meanwhile, energy-saving and emission-reduction analyses were conducted on the MSWI BA road. The results showed that under 5% cement dosage, the mechanical properties and frost resistance of the mixture with different MSWI BA content both satisfied the specification requirements; during the construction, the appropriate MSWI BA content could be selected according to the requirements of different highway grades in the specification. The established segmented constitutive model could well simulate the stress–strain relationship of the mixture in the compressive process. Using cement-stabilized MSWI BA to build the pavement base was feasible, which provided not only an important reference for the engineering design but also had positive significance for promoting carbon peaking, carbon neutrality and sustainable development of highway engineering construction.
Poling of Glasses Using Resistive Barrier Discharge Plasma
Authors: Scherbak Sergey A. , Kaasik Vladimir P. , Zhurikhina Valentina V. , Lipovskii Andrey A.
Published: December 2022

A technique for poling of glasses using a resistive barrier discharge plasma in the atmosphere in a gap of hundreds of microns is presented. Measurements of the polarization current, second harmonic generation, and IR spectra of poled soda-lime glass slides show that voltage sufficient to ignite plasma discharge provides efficient poling, whereas for lower voltages the poling effect is close to zero. We attributed this to the large number of hydrogen/hydronium ions generated from atmospheric water vapor by the plasma discharge in the gap, which penetrate into the glass. We also developed a simple model of poling according to Ohm’s law, analyzed the temporal dependencies of the polarization current and, basing on the model, estimated mobilities of hydrogen/hydronium and sodium ions in the glass: μH = (2.4 ± 0.8) × 10−18 m2V−1s−1 and μNa = (4.8 ± 1.8) × 10−15 m2V−1s−1. The values obtained are very close to the known literature data.
A Sustainable Alternative for Green Structural Lightweight Concrete: Performance Evaluation
Authors: Alqahtani Fahad K.
Published: December 2022

The use of structural lightweight concrete in the construction industry is on the rise in the last few decades mainly because of the higher strength per unit density, as it reduces the total deal load of the structural elements as compared with normal strength concrete. In addition, the environmental concerns of the concrete industry have gained supreme importance in recent times, demanding vital and effectual steps. In this regard, the current study was carried out to formulate an alternative approach for producing a sustainable lightweight structural concrete. The study followed two stages: initially, the selection of optimized manmade plastic aggregates based on trial concrete mixes, and finally, to gauge the physical-, mechanical- and durability related properties of the concretes integrating optimized manmade aggregate series at different replacement fractions. As a result of the first phase: two aggregate series out of eight were selected based on the compressive strength and durability properties of their concretes. In the next stage, all the properties for the optimized aggregate concrete were analyzed in terms of compressive strength. It was noted that the physical, mechanical and chloride penetration resistances have generally displayed a decreasing trend, with an increase in the manmade plastic aggregate replacement fractions as compared with reference lightweight concrete. However, the two aggregates, i.e., 70% DS-30% LLDPE and 50% QF-50% PET at the replacement fractions of 25% and 100%, were found to be the best two contenders that fulfilled the criteria for structural lightweight concrete, i.e., ASTMC330/C330M-14, and were proposed for structural lightweight purposes with low and relatively high strength and chloride resistance-based durability requirements, respectively. In addition, the brittleness ratios and structural efficiency parameters for the concretes of the 70% DS-30% LLDPE and 50% QF-50% PET also supplemented the aforementioned findings. Overall, this study presents a sustainable approach for the effective utilization of plastic waste for producing structural lightweight concrete.
The Use of Various Measurement Methods for Estimating the Fracture Energy of PLA (Polylactic Acid)
Authors: Gao Luyao , Drozdov Aleksey D.
Published: December 2022

The essential work of fracture (EWF) and Izod/Charpy impact tests have been used to investigate the fracture toughness in the plane stress of brittle polymers. In this paper, we had three goals: first, we aimed to employ how to estimate PLA toughness in different geometries; then, we proposed to compare Izod and Charpy Impact toughness in the same geometry; finally, we intended to determine the difference between EWF toughness and dynamic toughness. The results showed that the EWF method could be applied to evaluate PLA fracture behavior with small ligaments (2–4 mm), while the dynamic test could be employed with larger ligaments (5–7 mm). A comparison of the two impact test results obtained the following conclusions: Charpy impact toughness was higher than Izod impact toughness in the same geometry, and the impact toughness under a notch angle of 90° was larger than that of an angle of 45°. Both EWF and dynamic tests can be used to explore PLA toughness with small ligaments. The fracture energy decreases with ligament size in the EWF test, but it increases in the dynamic test.
Paramagnetic Defects and Thermoluminescence in Irradiated Nanostructured Monoclinic Zirconium Dioxide
Authors: Ananchenko Daria V. , Nikiforov Sergey V. , Sobyanin Konstantin V. , Konev Sergey F. , Dauletbekova Alma K. , Akhmetova-Abdik Gulzhanat , Akilbekov Abdirash T. , Popov Anatoli I.
Published: December 2022

The ESR spectra of nanostructured samples of monoclinic ZrO2 irradiated by electrons with energies of 130 keV, 10 MeV, and by a beam of Xe ions (220 MeV) have been studied. It has been established that irradiation of samples with electrons (10 MeV) and ions leads to the formation of radiation-induced F+ centers in them. Thermal destruction of these centers is observed in the temperature range of 375–550 K for electron-irradiated and 500–700 K for ion-irradiated samples. It is shown that the decrease in the concentration of F+ centers is associated with the emptying of traps responsible for thermoluminescence (TL) peaks in the specified temperature range. In the samples irradiated with an ion beam, previously unidentified paramagnetic centers with g = 1.963 and 1.986 were found, the formation of which is likely to involve Zr3+ ions and oxygen vacancies. Thermal destruction of these centers occurs in the temperature range from 500 to 873 K.
Effects of Power and Laser Speed on the Mechanical Properties of AlSi7Mg0.6 Manufactured by Laser Powder Bed Fusion
Authors: Vaudreuil Sébastien , Bencaid Salah-Eddine , Vanaei Hamid Reza , El Magri Anouar
Published: December 2022

The AlSi7Mg0.6 alloy, with its good tolerance against strain, is used in laser powder bed fusion (LPBF) to produce parts with complex geometries for aerospace engineering. Production of parts with good mechanical strength requires, however, the optimization of laser parameters. This study thus evaluated the influence of scanning speed, laser power, and strategy on several mechanical properties (tensile/resilience/hardness) to identify an optimal processing region. Results have shown the profound influence of laser power and scanning speed on mechanical properties, with a limited influence from the laser strategy. Tensile strength values ranging from 122 to 394 MPa were obtained, while Young’s Modulus varied from 17 to 29 GPa, and the elongation at break ranged from 2.1 to 9.8%. Surface plots of each property against laser power and speed revealed a region of higher mechanical properties. This region is found when using 50 µm thick layers for energy densities between 25 and 35 J/mm3. Operating at higher values of energy density yielded sub-optimal properties, while a lower energy density resulted in poor performances. Results have shown that any optimization strategy must not only account for the volumic energy density value, but also for laser power itself when thick layers are used for fabrication. This was shown through parts exhibiting reduced mechanical performances that were produced within the optimal energy density range, but at low laser power. By combining mid-speed and power within the optimal region, parts with good microstructure and limited defects such as balling, keyhole pores, and hot cracking will be produced. Heat-treating AlSi7Mg0.6 parts to T6 temper negatively affected mechanical performances. Adapted tempering conditions are thus required if improvements are sought through tempering.
Effective BMP-2 Release and Mineralization on a Graphene Oxide/Polyvinylpyrrolidone Hydrogel Forming Poly (ε-Caprolactone) Nanofibrous Scaffolds
Authors: Jeong Jin-Oh , Jeong Sung-In , Lim Youn-Mook , Park Jong-Seok
Published: December 2022

PCL nanofibrous scaffolds are widely used as bone scaffolds, and they can increase the efficiency of bone regeneration by loading drugs and/or growth factors onto them. However, to obtain a more effective bone regeneration effect, it is necessary to increase drug loading and release efficiency. In this study, conductive hydrogel forming nanofibrous scaffolds were prepared to increase drug efficiency. GO has an excellent conductivity and biocompatibility, making it an efficient conductive polymer for bone differentiation. Electrospun PCL was immersed in a mixed solution of GO and PVP and then crosslinked using gamma-ray irradiation. It was confirmed that GO/PVP-PCL was successfully prepared through its characterization (morphology, thermal, chemical, electrical, and biological properties). In addition, drug-release efficiency was confirmed by electrical stimulation after loading the sample with BMP-2, a bone-regeneration growth factor. Compared to PCL, it was confirmed that GO/PVP-PCL has an approximately 20% improved drug-release efficiency and an excellent mineralization of the scaffolds using SBF. After culturing MG63 cells on GO/PVP-PCL, a high effect on osteodifferentiation was confirmed by ALP activity. Therefore, GO/PVP-PCL prepared by a gamma-ray-induced crosslinking reaction is expected to be used as biomaterial for bone-tissue engineering.
Determination of the Pressure Dependence of Raman Mode for an Alumina–Glass Pair in Hertzian Contact
Authors: Delbé Karl , De Sousa Cyril , Grizet François , Paris Jean-Yves , Yahiaoui Malik
Published: December 2022

Optimising the performance of materials requires, among other things, the characterisation of residual stresses during the design stage. Raman spectroscopy offers access to these residual stresses at the micrometre scale when this inelastic light scattering is active in these materials. In this case, the relationship between the Raman mode shift and the pressure must be known. High-pressure cells with diamond anvils or bending instruments coupled to Raman spectrometers are habitually used to determine this relationship. In this article, we propose a new method that involves a Hertzian contact to obtain this relationship. A device that compresses an alumina ball against a transparent glass plane is connected to a Raman spectrometer. Under these conditions, the contact pressure can be as high as 1.5 GPa. The contact between the glass plane and the ball is observed through a diaphragm. Several hundred Raman spectra are recorded depending on the contact diameter. The spectral profiles obtained represent the shift in the Raman modes of alumina and glass along the contact diameter. Hertz’s theory accurately describes the pressure profile as a function of position for elastic materials. Therefore, the contact diameter can be measured by fitting the spectral profile with a function identical to the Hertz profile. We then deduce the maximum pressure. Next, the calculated pressure profile along the contact diameter is correlated with the spectral profile. We obtain a pressure dependence of the Raman mode with a coefficient equal to 2.07 cm−1/GPa for the Eg modes of alumina at 417 cm−1, which is in good agreement with the literature. In the case of glass, we refine the measurement of the Q3 mode shift at 1096 cm−1 in the studied pressure range compared to the literature. We find a coefficient of 4.31 cm−1/GPa. This work on static contacts opens up promising prospects for investigations into dynamic contacts in tribology.
A New Hydrometallurgical Process for Metal Extraction from Electric Arc Furnace Dust Using Ionic Liquids
Authors: Teimouri Samaneh , Potgieter Johannes Herman , Lundström Mari , Billing Caren , Wilson Benjamin P.
Published: December 2022

This research proposes a new hydrometallurgical method for Zn, In, and Ga extraction, along with Fe as a common impurity, from electric arc furnace dust (EAFD), using ionic liquids. EAFD is a metal-containing waste fraction generated in significant amounts during the process of steelmaking from scrap material in an electric arc furnace. With valuable metal recovery as the main goal, two ionic liquids, [Bmim+HSO4−] and [Bmim+Cl−], were studied in conjunction with three oxidants: Fe2(SO4)3, KMnO4, and H2O2. The results indicated that the best combination was [Bmim+HSO4−] with [Fe2(SO4)3]. An experimental series subsequently demonstrated that the combination of 30% v/v [Bmim+HSO4−], 1 g of [Fe2(SO4)3], S/L ratio = 1/20, a 240 min leaching time, and a temperature of 85 °C was optimal, resulting in maximum extractions of 92.7% Zn, 97.4% In, and 17.03% Ga. In addition, 80.2% of the impurity metal Fe was dissolved. The dissolution kinetics of these four elements over a temperature range of 55–85 °C was found to be diffusion controlled. The remaining phases present in the leached residue were low amounts of ZnO, Fe3O4, ZnFe2O4, and traces of Ca(OH)2 and MnO2, and additional sharp peaks indicative of PbSO4 and CaSO4 appeared within the XRD pattern. The intensity of the peaks related to ZnO and Fe3O4 were observed to have decreased considerably during leaching, whereas some of the refractory ZnFe2O4 phase remained. SEM-EDS analysis revealed that the initial EAFD morphology was composed of spherical-shaped fine-grained particle agglomerates, whereas the leached residue was dominated by calcium sulphate (Ca(SO4))-rich needle-shaped crystals. The results clearly demonstrate that [Bmim+HSO4−] is able to extract the target metals due to its acidic properties.
Synthesis Method of Unsolvated Organic Derivatives of Metal Borohydrides
Authors: Wegner Wojciech , Fijalkowski Karol J.
Published: December 2022

A new, scalable, wet-chemistry single-pot method of synthesising pure unsolvated organic derivatives of metal borohydrides is presented. The metathetic reaction in a weakly coordinating solvent is exemplified by the synthesis of [(n-C4H9)4N][Y(BH4)4] and [Ph4P][Y(BH4)4] systems. For the latter compound, the crystal structure was solved and described. Organic borohydride salts obtained by the new method can find various applications, e.g., can be used as precursors in synthesis of hydrogen-rich mixed-metal borohydrides—promising materials for solid-state chemical storage of hydrogen.
Seismic Response Analysis of Steel–Concrete Composite Frame Structures with URSP Connectors
Authors: Duan Linli , Nie Xin , Su Han , Tan Jike
Published: December 2022

The uplift-restricted and slip-permitted (URSP) connector is a new type of connector used in steel–concrete composite structures that has been proven to improve the structural performance of negative moment regions. Since this connector changes the interface restraint between the slab and steel beam, there is an imperative to study the seismic performance of steel–concrete composite frame systems with this new type of connector. In this study, the dynamic behavior of composite frame structures with URSP connectors under seismic loads was numerically investigated. First, a beam–shell mixed model was used and complex interfaces of different connectors were considered while establishing a numerical model to conduct elasto–plastic time history analysis under various seismic loads. This numerical model was validated with the frame sub-assemblage experimental results of quasi-static cyclic tests. Second, the model analysis results of structures with URSP connectors were obtained and compared with those of traditional structures. Third, dynamic response results including roof displacement, inter-story displacement, and the distribution and failure modes of plastic hinges were analyzed and compared. The comparisons indicated that the arrangement of full-span URSP connectors had a non-negligible influence on the dynamic behavior of the systems. The arrangement increased the maximum inter-story displacement by 31.5% and induced adverse effects in certain cases, which is not suggested in the application of URSP connectors. The partial arrangement of URSP connectors had little influence on the dynamic behavior of the systems, and the frame systems still showed a good seismic performance, which was the same as the traditional composite structural system. These findings may promote the application of URSP connectors in composite structures.
Accurate Flow Characterization of A6082 for Precision Simulation of a Hot Metal Forming Process
Authors: Park Jeong-Hwi , Ji Su-Min , Choi Jeong-Muk , Joun Man-Soo
Published: December 2022

The flow behaviors of metallic materials are sensitive to state variables, including strain, strain rate, and temperature. In particular, the temperature effect on the flow behavior is of great importance. The flow information is usually obtained at the sample strain rates and temperatures from the hot cylinder compression test. However, this test is inevitably exposed to undesirable effects of friction and temperature on flow characterization. This study reveals their impact on the flow curve of an A6082 alloy. The unique features of its flow behavior and the inaccuracy of as-received, primitive flow information are emphasized. Using a systematic way of correcting the friction and temperature effects, the flow curves with high accuracy in terms of the compression load–stroke curve obtained from the test are calculated. It was revealed that the both the friction and temperature compensation of the primitive flow curves bring a minor change in the flow curves of the A6082 alloy, which is quite different from other commercial light metals. This phenomenon caused by the unique features of the flow behavior of the A6082 or other aluminum alloys will be critical to solving various process and quality matters confronted by the engineers in the hot metal forming industry.
Development of Lightweight Cricket Pads Using Knitted Flexible Thermoplastic Composites with Improved Impact Protection
Authors: Ahmad Tauheed , Jamshaid Hafsa , Mishra Rajesh Kumar , Chandan Vijay , Nazari Shabnam , Ivanova Tatiana Alexiou , Ahamad Naseer , Ahmed Sharjeel , Petru Michal , Kučera Lubos
Published: December 2022

Cricket is one of the most popular global sports, and cricket pads are important personal protective gear used for shock absorption and peak deceleration of the impact forces of the cricket ball for both batsmen and wicket keepers. The materials selection of the padding should be considered according to requirements. In the present study, flexible composites were manufactured using knitted unidirectional thermoplastic composite prepregs. Prepregs were fabricated using thermoplastic yarns, e.g., High Density Polyethylene (HDPE), Polypropylene (PP), and Low Melting Polyester (LMPE). Para-aramid (Kevlar) and Flax yarns were used as inlay. The structures were stacked in three and five layers, and hot compression was used to convert thermoplastic yarn into matrix. A total of twelve samples were prepared, and their mechanical properties were evaluated. Tensile and flexural properties, short beam strength, and impact properties were optimized using the multi-criteria decision-making (MCDM) technique for order performance by similarity to ideal solution (TOPSIS). This approach was used to select the best material for use in cricket pads. The candidate samples were ranked using statistical techniques. The optimum sample was found to be FP5, i.e., Flax with polypropylene using five layers, which exhibited the maximum impact strength. The results showed that the mechanical properties were improved in general by increasing the number of layers. The significance and percentage contribution of each factor was obtained by ANOVA (α = 0.10) and pie chart, which showed Factors A and C (inlay yarn and number of layers) to be the main contributors. The optimal samples showed superior impact-related performance compared to a market sample cricket pad.
Research on the Formation Characteristics of the Shaped Charge Jet from the Shaped Charge with a Trapezoid Cross-Section
Authors: Ma Bin , Huang Zhengxiang , Wu Yongzhong , Wang Yuting , Jia Xin , Gao Guangyue
Published: December 2022

The formation characteristics of the shaped charge jet (SCJ) from the shaped charge with a trapezoid cross-section is analyzed in this work. A theoretical model was developed to analyze the collapsing mechanism of the liner driven by the charge with a trapezoid cross-section. Based on the theoretical model, the axial and radial velocities of the SCJ from different trapezoid cross-section charges. The pressure model was employed to calculate the velocity for the subcaliber shaped charge, which was verified through numerical simulation. The results show that the influence of the angle of the trapezoidal charge (acute angle) on the axial velocity of the SCJ is not distinct, whereas the variation of the radial velocity of the shaped charge jet is obvious as the change in the angle of the trapezoidal charge. In addition, the related X-ray experiments were conducted to verify the theory. The theoretical results correlate with the experimental results reasonably well.
Band Structure and Quantum Transport of Bent Bilayer Graphene
Authors: Wang Xue , Xu Lei
Published: December 2022

We investigate the band structures and transport properties of a zigzag-edged bent bilayer graphene nanoribbon under a uniform perpendicular magnetic field. Due to its unique geometry, the edge and interface states can be controlled by an electric field or local potential, and the conductance exhibits interesting quantized behavior. When Zeeman splitting is considered, the edge states are spin-filtered, and a weak quantum spin Hall (WQSH) phase appears. In the presence of an electric field or local potential, a WQSH-QH junction or WQSH-spin-unbalanced QSH junction can be achieved, respectively, while fully spin-polarized currents appear in the interface region. Zeeman splitting lifts the spin degeneracy, leading to a WQSH around zero energy with a quantized two-terminal conductance of 4e2/h, which is robust against weak nonmagnetic disorder. These results provide a way to manipulate the band structures and transport properties of the system using an electric field, local potential, and Zeeman splitting.
Microstructure and Mechanical Properties of β-Titanium Ti-15Mo Alloy Produced by Combined Processing including ECAP-Conform and Drawing
Authors: Gatina Svetlana A. , Polyakova Veronika V. , Polyakov Alexander V. , Semenova Irina P.
Published: December 2022

At present, researchers pay great attention to the development of metastable β-titanium alloys. A task of current importance is the enhancement of their strength and fatigue properties. An efficient method for increasing the strength of such alloys could be severe plastic deformation. The object of this study was a medical metastable β-titanium alloy Ti-15Mo (ASTM F2066). The alloy in the (α + β) state was for the first time deformed by combined processing, including equal channel angular pressing-conform and drawing. Such processing enabled the production of long-length rods with a length of 1500 mm. The aim of the work was to study the effect of the combined processing on the alloy’s microstructure and mechanical properties. An ultrafine-grained structure with an average size of structural elements less than 100 nm was obtained. At the same time, high strength and ductility (σuts = 1590 MPa, δ = 10%) were achieved, which led to a record increase in the endurance limit (σ−1 = 710 MPa) under tension-compression terms.
Properties of Light Cementitious Composite Materials with Waste Wood Chips
Authors: Guo Huijuan , Wang Peihan , Li Qiuyi , Liu Guoying , Fan Qichang , Yue Gongbing , Song Shuo , Zheng Shidong , Wang Liang , Guo Yuanxin
Published: December 2022

The CO2 emissions from the cement industry and the production of waste wood chips are increasing with the rapid growth of the construction industry. In order to develop a green environmental protection building material with low thermal conductivity and up to standard mechanical properties, in this study, pine waste wood chips were mixed into cement-based materials as fine aggregate, and three different kinds of cementitious binders were used, including sulfur aluminate cement (SAC), ordinary Portland cement (OPC), and granulated blast furnace slag (GBFS), to prepare a recycled light cementitious composite material. The mechanical, thermal conductivity, shrinkage, water absorption, and pore structure of a wood chip light cementitious composite material were studied by changing the Ch/B (the mass ratio of wood chip to binder). The results showed that the strength, dry density, and thermal conductivity of the specimens decreased significantly with the increase in the Ch/B, while the shrinkage, water absorption, and pore size increased with the increase in the Ch/B. By comparing three different kinds of cementitious binders, the dry density of the material prepared with OPC was 942 kg/m3, the compressive strength of the material prepared with SAC was 13.5 MPa, and the thermal conductivity of the material prepared with slag was the lowest at 0.15 W/m/K. From the perspective of low-cost and low-carbon emissions, it was determined that the best way to prepare a light cementitious composite with waste wood chips is to use granulated blast furnace slag (GBFS) as the cementitious binder.
A Review of Key Properties of Thermoelectric Composites of Polymers and Inorganic Materials
Authors: Wood Nathan D. , Gillie Lisa J. , Cooke David J. , Molinari Marco
Published: December 2022

This review focusses on the development of thermoelectric composites made of oxide or conventional inorganic materials, and polymers, with specific emphasis on those containing oxides. Discussion of the current state-of-the-art thermoelectric materials, including the individual constituent materials, i.e., conventional materials, oxides and polymers, is firstly presented to provide the reader with a comparison of the top-performing thermoelectric materials. Then, individual materials used in the inorganic/polymer composites are discussed to provide a comparison of the performance of the composites themselves. Finally, the addition of carbon-based compounds is discussed as a route to improving the thermoelectric performance. For each topic discussed, key thermoelectric properties are tabulated and comparative figures are presented for a wide array of materials.
Optimisation of Embodied Carbon and Compressive Strength in Low Carbon Concrete
Authors: Nukah Promise D. , Abbey Samuel J. , Booth Colin A. , Nounu Ghassan
Published: December 2022

To improve the prediction of compressive strength and embodied carbon of low carbon concrete using a program algorithm developed in MATLAB, 84 datasets of concrete mix raw materials were used. The influence of water, silica fume and ground granular base slag was found to have a significant impact on the extent of low carbon concrete behaviour in terms of compressive strength and embodied carbon. While the concrete compressive strength for normal concrete increases with reducing water content, it is observed that the low carbon concrete using lightweight aggregate material increases in compressive strength with an increase in embodied carbon. From the result of the analysis, a function was developed that was able to predict the associated embodied carbon of a concrete mix for a given water-to-cement ratio. The use of an alkaline solution is observed to increase the compressive strength of low carbon concrete when used in combination with ground granular base slag and silica fume. It is further shown that ground granular base slag contributes significantly to an increase in the compressive strength of Low carbon concrete when compared with pulverised fly ash. The optimised mix design program resulted in a 26% reduction in embodied carbon and an R2 value of 0.9 between the measured compressive strength and the optimised compressive strength.
Glutathione Fluorescence Sensing Based on a Co-Doped Carbon Dot/Manganese Dioxide Nanocoral Composite
Authors: Le Thi-Hoa , Lee Hyun-Jong , Tran Quang-Nhat
Published: December 2022

Glutathione (GSH) is an antioxidant thiol that has a vital role in the pathogenesis of various human diseases such as cardiovascular disease and cancer. Hence, it is necessary to study effective methods of GSH evaluation. In our work, an effective GSH sensor based on a nitrogen and phosphorus co-doped carbon dot (NPCD)-MnO2 nanocoral composite was fabricated. In addition to utilizing the strong fluorescence of the NPCDs, we utilized the reductant ability of the NPCDs themselves to form MnO2 and then the NPCD-MnO2 nanocoral composite from MnO4−. The characteristics of the nanocoral composite were analyzed using various electron microscopy techniques and spectroscopic techniques. The overlap between the absorption spectrum of MnO2 and the fluorescence emission spectrum of the NPCDs led to effective fluorescence resonance energy transfer (FRET) in the nanocoral composite, causing a decrease in the fluorescent intensity of the NPCDs. A linear recovery of the fluorescent intensity of the NPCDs was observed with the GSH level raising from 20 to 250 µM. Moreover, our GSH sensor showed high specificity and sensing potential in real samples with acceptable results.
Thermal Properties of Porous Silicon Nanomaterials
Authors: Fedorov Aleksandr S. , Teplinskaia Anastasiia S.
Published: December 2022

The thermal properties, including the heat capacity, thermal conductivity, effusivity, diffusivity, and phonon density of states of silicon-based nanomaterials are analyzed using a molecular dynamics calculation. These quantities are calculated in more detail for bulk silicon, porous silicon, and a silicon aerocrystal (aerogel), including the passivation of the porous internal surfaces with hydrogen, hydroxide, and oxygen ions. It is found that the heat capacity of these materials increases monotonically by up to 30% with an increase in the area of the porous inner surface and upon its passivation with these ions. This phenomenon is explained by a shift of the phonon density of states of the materials under study to the low-frequency region. In addition, it is shown that the thermal conductivity of the investigated materials depends on the degree of their porosity and can be changed significantly upon the passivation of their inner surface with different ions. It is demonstrated that, in the various simulated types of porous silicon, the thermal conductivity changes by 1–2 orders of magnitude compared with the value for bulk silicon. At the same time, it is found that the nature of the passivation of the internal nanosilicon surfaces affects the thermal conductivity. For example, the passivation of the surfaces with hydrogen does not significantly change this parameter, whereas a passivation with oxygen ions reduces it by a factor of two on average, and passivation with hydroxyl ions increases the thermal conductivity by a factor of 2–3. Similar trends are observed for the thermal effusivities and diffusivities of all the types of nanoporous silicon under passivation, but, in that case, the changes are weaker (by a factor of 1.5–2). The ways of tuning the thermal properties of the new nanostructured materials are outlined, which is important for their application.
Buckling Behavior of Sandwich Cylindrical Shells Covered by Functionally Graded Coatings with Clamped Boundary Conditions under Hydrostatic Pressure
Authors: Sofiyev Abdullah H. , Fantuzzi Nicholas , Ipek Cengiz , Tekin Gülçin
Published: December 2022

The buckling behavior of sandwich shells with functionally graded (FG) coatings operating under different external pressures was generally investigated under simply supported boundary conditions. Since it is very difficult to determine the approximation functions satisfying clamped boundary conditions and to solve the basic equations analytically within the framework of first order shear deformation theory (FOST), the number of publications on this subject is very limited. An analytical solution to the buckling problem of FG-coated cylindrical shells under clamped boundary conditions subjected to uniform hydrostatic pressure within the FOST framework is presented for the first time. By mathematical modeling of the FG coatings, the constitutive relations and basic equations of sandwich cylindrical shells within the FOST framework are obtained. Analytical solutions of the basic equations in the framework of the Donnell shell theory, obtained using the Galerkin method, is carried out using new approximation functions that satisfy clamped boundary conditions. Finally, the influences of FG models and volume fractions on the hydrostatic buckling pressure within the FOST and classical shell theory (CT) frameworks are investigated in detail.