bluuebunny/crossref_metadata_2025 huggingface dataset:
Co-Activating Lattice Oxygen of TiO2-NT and SnO2 Nanoparticles on Superhydrophilic Graphite Felt for Boosting Electrocatalytic Oxidation of Glyphosate
Authors: He Wenyan , Bai Sheng , Ye Kaijie , Xu Siyan , Dan Yinuo , Chen Moli , Fang Kuo
Published: November 2024

Glyphosate (GH) wastewater potentially poses hazards to human health and the aquatic environment, due to its persistence and toxicity. A highly superhydrophilic and stable graphite felt (GF)/polydopamine (PDA)/titanium dioxide nanotubes (TiO2-NT)/SnO2/Ru anode was fabricated and characterized for the degradation of glyphosate wastewater. Compared to control anodes, the GF/PDA/TiO2-NT/SnO2/Ru anode exhibited the highest removal efficiency (near to 100%) and a yield of phosphate ions of 76.51%, with the lowest energy consumption (0.088 Wh/L) for degrading 0.59 mM glyphosate (GH) at 7 mA/cm2 in 30 min. The exceptional activity of the anode may be attributed to the co-activation of lattice oxygen in TiO2-NT and SnO2 by coupled Ru, resulting in a significant amount of •O2− and oxygen vacancies as active sites for glyphosate degradation. After electrolysis, small molecular acids and inorganic ions were obtained, with hydroxylation and dephosphorization as the main degradation pathways. Eight cycles of experiments confirmed that Ru doping prominently enhanced the stability of the GF/PDA/TiO2-NT/SnO2/Ru anode due to its high oxygenophilicity and electron-rich ability, which promoted the generation and utilization efficiency of active free radicals and defects-associated oxygen. Therefore, this study introduces an effective strategy for efficiently co-activating lattice oxygen in SnO2 and TiO2-NT on graphite felt to eliminate persistent organophosphorus pesticides.
Semiconductor Quantum Dots: Synthesis, Properties and Applications
Authors: Feng Donghai , Zhang Guofeng , Li Yang
Published: November 2024

Semiconductor nanoparticles of sizes smaller than exciton Bohr diameters undergo quantum confinement and are called quantum dots (QDs), which exhibit size-dependent physicochemical properties [...]
Nano-Selenium Modulates NF-κB/NLRP3 Pathway and Mitochondrial Dynamics to Attenuate Microplastic-Induced Liver Injury
Authors: Shen Qi , Liu Yunjie , Li Jiakui , Zhou Donghai
Published: November 2024

Background: Microplastics (PS-MPs) are a new type of pollutant with definite hepatotoxicity. Selenium, on the other hand, has natural, protective effects on the liver. Objectives/Methods: The purpose of this experiment is to find out whether nano-selenium (SeNP) can alleviate liver damage caused by microplastics. Initially, we established through in vitro experiments that SeNP has the ability to enhance the growth of healthy mouse liver cells, while microplastics exhibit a harmful impact on normal mouse hepatocyte cell suspensions, leading to a decrease in cell count. Subsequently, through in vivo experiments on male ICR mice, we ascertained that SeNPs alleviated the detrimental impacts of PS-MPs on mouse liver. Results: SeNPs hinder the signaling pathway of NF-κB/NLRP3 inflammatory vesicles, which is crucial for reducing inflammation induced by PS-MPs. In terms of their mechanism, SeNPs hinder the abnormalities in mitochondrial fission, biogenesis, and fusion caused by PS-MPs and additionally enhance mitochondrial respiration. This enhancement is crucial in averting disorders in energy metabolism and inflammation. Conclusions: To summarize, the use of SeNPs hindered inflammation by regulating mitochondrial dynamics, thus relieving liver damage caused by PS-MPs in mice. The anticipated outcomes offer new research directions that can be referenced in terms of inflammatory injuries caused by PS-MPs.
Pinus densiflora Root Extract Attenuates Osteoarthritis Progression by Inhibiting Inflammation and Cartilage Degradation in Interleukin-1β and Monosodium Iodoacetate-Induced Osteoarthritis Models
Authors: Park Young , Shin Dong , Lee Hak , Hwang Hai , Kim Jae , Kim Byeong , Lee Sang , Lee Sang , Kim Min , Yang Hye , Kim Myung-Sunny , Bae Jun
Published: November 2024

Background: Osteoarthritis (OA) is a common degenerative joint condition caused by an imbalance between cartilage synthesis and degradation, which disrupts joint homeostasis. This study investigated the anti-inflammatory and joint-improving effects of Pinus densiflora root extract powder (PDREP) in both in vitro and in vivo OA models. Methods/Results: In an in vitro OA model, in which SW1353 human chondrosarcoma cells were treated with interleukin (IL)-1β, PDREP treatment significantly reduced the mRNA levels of matrix metalloproteinase (MMP)-1, MMP-3, and MMP-13 while enhancing collagen type II alpha 1 (Col2a1) mRNA level, and decreased IL-6 and prostaglandin E2 (PGE2) levels. In addition, PDREP inhibited the phosphorylation of extracellular signal-regulated kinases (ERK), c-Jun N-terminal kinase (JNK), p38, nuclear factor-kappa B (NF-κB), and the expression of inducible nitric oxide synthase (iNOS). In a monosodium iodoacetate (MIA)-induced OA rat model, the administration of PDREP resulted in decreased OA clinical indices, improved weight-bearing indices and gait patterns, reduced histological damage, and lowered serum inflammatory cytokine and MMPs expression. Furthermore, PDREP downregulated the phosphorylation of ERK, JNK, p38, and NF-κB, as well as the expression of iNOS, consistent with the in vitro findings. Conclusions: These results suggest that PDREP exhibits anti-inflammatory and joint-improving effects and has potential as a therapeutic strategy or functional food for the treatment of OA.
Anti-Inflammatory Effects of Cordyceps Cs-HK1 Fungus Exopolysaccharide on Lipopolysaccharide-Stimulated Macrophages via the TLR4/MyD88/NF-κB Pathway
Authors: Zhu Yan-Yu , Dong Yu-Han , Gu Fang-Ting , Zhao Zi-Chen , Huang Lin-Xi , Cheng Wai-Yin , Wu Jian-Yong
Published: November 2024

Chronic inflammation is a common factor in the pathological processes of multiple human diseases. EPS-LM, an exopolysaccharide (EPS) from the Cordyceps sinensis fungus Cs-HK1, has shown notable anti-inflammatory activities in previous studies. This study aimed to investigate the major signaling events mediating the anti-inflammatory effects of EPS-LM in lipopolysaccharide (LPS)-stimulated RAW 264.7 macrophage cell culture. EPS-LM treatment significantly reduced LPS-induced production of pro-inflammatory mediators, including nitric oxide (NO) and reactive oxygen species (ROS). It also suppressed the expression levels of Toll-like receptor 4 (TLR4) and myeloid differentiation primary response gene 88 (MyD88), subsequently delaying the translocation of nuclear factor-kappa B (NF-κB) to the nucleus. Additionally, co-immunoprecipitation (Co-IP) experiments demonstrated that EPS-LM inhibited the binding of TLR4 to MyD88. The ability of EPS-LM to inhibit the TLR4/MyD88/NF-κB pathway, coupled with its capacity to reduce oxidative stress, underscores its multifaceted anti-inflammatory effects. These effects render EPS-LM as a promising candidate for the comprehensive management of various inflammatory and oxidative stress-related conditions, protecting against cell damage.
Breastfeeding Beyond Six Months: Evidence of Child Health Benefits
Authors: Froń Anita , Orczyk-Pawiłowicz Magdalena
Published: November 2024

Breastfeeding is globally recognized as the optimal method of infant nutrition, offering health benefits for both the child and the mother, making it a public health priority. However, the potential advantages of breastfeeding extend well beyond initial months. Breast milk adapts to the evolving needs of the growing infant, and its immunological, microbiological, and biochemical properties have been associated with enhanced protection against infections and chronic diseases, improved growth and development, and lower rates of hospitalization and mortality. This review explores the evidence supporting the continuation of breastfeeding beyond six months. More meticulous studies employing consistent methodologies and addressing confounders are essential. This will enable a more accurate determination of the extent and mechanisms of the positive impact of prolonged breastfeeding and allow for the implementation of effective public health strategies.
Trends in the Prevalence and Factors Associated with Undernutrition in Tunisian Children Aged 0–23 Months
Authors: Elmighrabi Nagwa Farag , Fleming Catharine A. K. , Agho Kingsley E.
Published: November 2024

Background: In recent years, undernutrition has remained a significant public health issue in Tunisia, increasing the risk of illness and mortality in young children. Therefore, this study aims to analyse the prevalence and factors contributing to undernutrition among Tunisian children aged 0–23 months. Methods: The study included 3265 children aged 0–23 months from the 2011–2023 Tunisia Multiple Indicator Cluster Surveys (MICS). Trends and logistic regression analyses were used to determine the prevalence and predictors of undernutrition. Results: The prevalence of stunting, wasting, and underweight in infants and children aged 0–23 months has increased by 3.3%, 0.5%, and 2.1%, respectively. Stunting and underweight were more common among infants aged 0–5 months (11.8% for stunting, 8.9% for underweight, p < 0.01), and first-time mothers (8.3% for stunting, 4.1% for underweight, p < 0.01). In 2023, compared to 2011, the odds of stunting, wasting, and being underweight had increased by 22%, 16%, and 70%, respectively. Infants aged 0–5 months had higher odds of undernutrition in all three indices. Children of obese or overweight mothers, and those who started breastfeeding late, were more likely to be stunted. Boys had significantly higher odds of wasting and underweight. Children with low birth weight, and duration of breastfeeding > 12 months, had significantly higher odds of being underweight. Conclusions: This study shows that infants aged 0–5 months, first-time mothers, boys, and children from poor households in Tunisia are at a higher risk of undernutrition. To address the growing issue of undernutrition in Tunisian children, enhancing maternal and child health and nutrition services, improving parental education, and implementing community-based programs that provide breastfeeding and nutritional education to infants born to new mothers and mothers with high/low BMI is recommended.
Bibliometric Analysis of Research Trends and Prospective Directions of Lung Microbiome
Authors: Du Chunjing , Zhang Yi , Zhang Hanwen , Zhang Hua , Liu Jingyuan , Shen Ning
Published: November 2024

The lung microbiome has emerged as a pivotal area of research in human health. Despite the increasing number of publications, there is a lack of research that comprehensively and objectively presents the current status of lung microbiome-related studies. Thus, this study aims to address this gap by examining over two decades of publications through bibliometric analysis. The original bibliographic data of this study were obtained from the Web of Science Core Collection, focusing on publications from 2003 to 2023. The analysis included the data extraction and examination of authors, affiliations, countries, institutions, abstracts, keywords, references, publication dates, journals, citations, H-indexes, and journal impact factors. A total of 845 publications were identified, showing an increasing trend in both publications and citations over the years, particularly in the last decade. The analysis highlighted the most productive authors, institutions, and countries/regions, and identified potential partners for interested researchers. Co-citation analysis revealed that lung microbiome- and infectious/pulmonary disease-related studies are at the forefront of the field. The hotspots and frontiers of the lung microbiome field have progressed from basic composition to exploring specific mechanisms and the clinical value of diseases. In conclusion, this study provides a comprehensive overview of the current research status and trends in the field of the lung microbiome over the past two decades and highlights the areas that need more attention and research efforts. It offers valuable insights for researchers and institutions and identifies key hotspots and frontiers, which can serve as references for related researchers and future research.
Combination Treatment of Resistant Acute Promyelocytic Leukemia Cells with Arsenic Trioxide and Anti-Apoptotic Gene Inhibitors
Authors: Giansanti Manuela , Ottone Tiziana , Travaglini Serena , Voso Maria Teresa , Graziani Grazia , Faraoni Isabella
Published: November 2024

Background: Arsenic trioxide (ATO) is an anticancer agent for treating acute promyelocytic leukemia (APL). However, 5–10% of patients fail to respond, developing relapsed/refractory disease. The aim of this study was to identify potential new therapeutic approaches for ATO-unresponsive APL by targeting the anti-apoptotic genes that contribute to drug resistance. Methods: RNA expression of dysregulated genes involved in the apoptotic pathway was analyzed by comparing ATO-resistant APL cell clones generated in our lab with the corresponding sensitive clones, at basal levels and after 48 h of treatment with ATO. Results: ATO-resistant APL cells showed upregulation of APAF1, BCL2, BIRC3, and NOL3 genes, while CD70 and IL10 genes were downregulated, compared to ATO-sensitive cells. Treatment with ATO strongly increased the expression of the anti-apoptotic genes BIRC3, NOL3, and BCL2A1 and significantly downregulated BCL2 in ATO-sensitive clones. Although all these genes can be relevant to ATO-resistance, we selected BCL2 and BIRC3 as druggable targets. A direct correlation between BCL2 expression and the sensitivity to the BCL2 inhibitor venetoclax was observed, indicating BCL2 as predictive biomarker of the response. Moreover, the combination of venetoclax with ATO exerted synergistic cytotoxic effects, thus reverting the resistance to ATO. APL treatment with SMAC mimetics such as LCL161 and xevinapant (inhibitors of BIRC3) was not as effective as the BCL2 inhibitor as a monotherapy but exerted synergistic effects in combination with ATO in cells with low BIRC expression. Conclusions: This study demonstrates the therapeutic potential of venetoclax in combination with ATO in vitro and strongly encourages further investigation of relapsed/refractory APL with high BCL2 expression.
Sustainable Intervention: Grape Pomace Flour Ameliorates Fasting Glucose and Mitigates Streptozotocin-Induced Pancreatic Damage in a Type 2 Diabetes Animal Model
Authors: Piccoli Raphaela Cassol , Simões William Sanabria , Custódio Solange Vega , Goularte Kelen Cristiane Machado , Luduvico Karina Pereira , de Mello Julia Eisenhardt , de Souza Anita Avila , Teixeira Ana Carolina , da Costa Diego Araujo , Barschak Alethéa Gatto , Deniz Bruna Ferrary , Almeida Wellington de , Pereira Paula , Nicolai Marisa , Spanevello Roselia Maria , Stefanello Francieli Moro , Tavares Rejane Giacomelli , Palma Maria Lídia
Published: November 2024

Background/Objectives: Type 2 Diabetes Mellitus (T2DM) is characterized by hyperglycemia, increased risk of cardiovascular diseases, and oxidative imbalances. This study aimed to investigate the impact of dietary supplementations with ‘Arinto’ grape pomace flour (GPF) (WGPF) and ‘Touriga Nacional’ GPF (RGPF) in an animal model of T2DM. Methods: T2DM was induced by a high-fat diet (HFD) for 28 days and a single dose of streptozotocin (STZ) (35 mg/kg) on the 21st day. Forty adult male Wistar rats were divided into five groups: Control (CT), T2DM, T2DM + Metformin (250 mg/kg), T2DM + 10% ‘Arinto’ GPF (WGPF), and T2DM + 10% ‘Touriga Nacional’ GPF (RGPF). On the 21st day of the experimental protocol, animals were submitted to an oral glucose tolerance test. An oral glucose tolerance test, oxidative stress parameters, biochemical analysis, and pancreas histological analyses were performed. Results: T2DM impaired glucose tolerance, elevated serum triglycerides and cholesterol, increased oxidative damage in the liver, and induced pancreatic histological abnormalities. However, supplementation with WGPF and RGPF demonstrated positive effects, mitigating glycemic and lipid disruptions, ameliorating oxidative stress, and protecting pancreatic Islets β-cells. Conclusions: Our findings highlight the protective effects of WGPF and RGPF in the adverse impacts of T2DM. Additionally, our study emphasizes the innovative use of grape pomace, a winemaking by-product, promoting sustainability by transforming waste into functional foods with significant health benefits.
A Low-Cost Modulated Laser-Based Imaging System Using Square Ring Laser Illumination for Depressing Underwater Backscatter
Authors: Hao Yansheng , Yuan Yaoyao , Zhang Hongman , Zhang Shao , Zhang Ze
Published: November 2024

Underwater vision data facilitate a variety of underwater operations, including underwater ecosystem monitoring, topographical mapping, mariculture, and marine resource exploration. Conventional laser-based underwater imaging systems with complex system architecture rely on high-cost laser systems with high power, and software-based methods can not enrich the physical information captured by cameras. In this manuscript, a low-cost modulated laser-based imaging system is proposed with a spot in the shape of a square ring to eliminate the overlap between the illumination light path and the imaging path, which could reduce the negative effect of backscatter on the imaging process and enhance imaging quality. The imaging system is able to achieve underwater imaging at long distance (e.g., 10 m) with turbidity in the range of 2.49 to 7.82 NTUs, and the adjustable divergence angle of the laser tubes enables the flexibility of the proposed system to image on the basis of application requirements, such as the overall view or partial detail information of targets. Compared with a conventional underwater imaging camera (DS-2XC6244F, Hikvision, Hangzhou, China), the developed system could provide better imaging performance regarding visual effects and quantitative evaluation (e.g., UCIQUE and IE). Through integration with the CycleGAN-based method, the imaging results can be further improved, with the UCIQUE increased by 0.4. The proposed low-cost imaging system with a compact system structure and low consumption of energy could be equipped with platforms, such as underwater robots and AUVs, to facilitate real-world underwater applications.
Water Deprivation and Sowing Times Alter Plant–Pollination Interactions and Seed Yield in Sunflower, Helianthus annuus L. (Asteraceae)
Authors: Ali Qasim , Ali Mudssar , Khan Fawad Zafar Ahmad , Noureldeen Ahmed , Alghamdi Akram , Darwish Hadeer , Fatima Akash , Jalali Ahmad Ibrahim , Prendergast Kit , Saeed Shafqat
Published: November 2024

Climate change effects, including temperature extremes and water stress, cause abiotic stress in plants. These changes directly affect flowering and the flower reward system for pollinators, influencing plant–pollinator interactions and ultimately seed production in flowering plants. Here, we tested the effects of water deprivation on the behavior of various pollinator species, plant–pollinator interactions, and the seed yield of sunflower, Helianthus annuus L. (Asteraceae). Sunflower was sown during four different months (January–April) and subjected to two different water availability levels (well-watered and water-deprived). Pollinator abundance was recorded five times a day (8:00 am, 10:00 am, 12:00 pm, 2:00 pm, and 4:00 pm) from flower heads and the florets. In addition, foraging behavior was also recorded. We found that lowest abundance, visit duration, and visitation rate occurred in April-sown sunflower. The European honey bee Apis mellifera L. (Hymenoptera: Apidae) was the most abundant visitor to sunflower, the hover fly Eristalinus aeneus (Diptera: Syrphidae) exhibited the longest visit duration, while Xylocopa sp. (Hymenoptera: Apidae) exhibited the highest visitation rate. The visitation rate of bees was significantly affected by water stress, with more bee visits occurring under well-watered conditions. Additionally, plant parameters, including flower head diameter, head weight, seed number, and seed weight, were significantly lower in the water-deprived treatments in April-sown sunflower. Open flowers without the pollination exclusion cages showed a higher yield, indicating the pollination dependence of sunflower. In conclusion, the plant modifications induced by sowing months and water-deprived conditions may alter pollinator behavior and may ultimately affect sunflower yield.
Anatomical-Foliar Diversity of Agave salmiana subsp. salmiana (Asparagaceae) in Three Populations of the Teotihuacán Region (Mexico)
Authors: Sandoval-Zapotitla Estela , Chávez-Güitrón Lorena E. , Salinas-Pérez Florencia del C. , Rosas Ulises , Vallejo-Zamora Alejandro
Published: November 2024

Agave salmiana Otto ex Salm-Dyck is an endemic Mexican plant distributed from 1230 to 2460 m above sea level, native to the arid zones of central and southern Mexico. It is a traditionally used species, with morphotypes ranging from wild to cultivated, with an ample cultural and management history. The species is important because it generates employment, and its products are used for self-consumption and are marketed as raw materials; however, little is known about its leaf anatomical description or studies that report the variation in its characters in terms of its level of management and its altitudinal gradient. To address this, we collected leaf samples from three localities of the Teotihuacan region in the State of Mexico (Mexico) and obtained anatomical leaf sections; with these, we also obtained thirty-eight parameters to quantitatively describe leaf anatomy. Thus, in this study, the general anatomical description of the leaf of Agave salmiana subsp. salmiana is presented. Unique leaf characters and others shared with the species of the genus were identified for the leaf of A. salmiana subsp. salmiana. In addition, significant variation was observed when comparing the three sampled localities (78.95%). From the analysis of anatomical characters, abaxial outer periclinal wall length, length of adaxial palisade parenchyma cells, fiber length, surface area of abaxial epidermal cells, width of abaxial palisade parenchyma cells, and total length of parenchyma in adaxial palisade were found to distinguish individuals from the three localities analyzed and the differences are related to management and altitude gradients.
Investigating Genetic Diversity and Correlations Between Mineral Concentration and Neurotoxin (β-ODAP) Content in the Lathyrus Genus
Authors: Abdallah Fadoua , Kehel Zakaria , El Kalchi Mohamed Amine , Amri Ahmed , el Baouchi Adil , Triqui Zine El Abidine , Amri Moez , Kumar Shiv
Published: November 2024

Grass pea (Lathyrus sativus L.) is a nutritious legume crop well-adapted to fragile agro-ecosystems that can survive under challenging climatic conditions. The cultivation of grass pea faces stigma primarily due to the presence of β-N-Oxalyl-L-α, β-diaminopropionic acid (β-ODAP), which is associated with a risk of inducing neurolathyrism upon prolonged consumption of its grains as a staple diet. The grass pea improvement program of the International Center for Agricultural Research in the Dry Areas (ICARDA) aims to reduce β-ODAP content to a safe level along with improving yield potential and nutritional quality of grass pea. In this study, 183 germplasm accessions representing 13 different Lathyrus species and 11 L. sativus breeding lines were evaluated for β-ODAP content based on Rao protocol and mineral concentration using ICP-OES. Significant variability was observed among the accessions for the studied traits. The results showed low β-ODAP content and high mineral concentration in 25 accessions of crop wild relatives, which included L. cicera, L. ochrus, and L. cassius, with one accession IG65277 of L. cassius, in addition to two lines, IG117034 and ACC1335, of L. sativus having very low β-ODAP content. Furthermore, some accessions of L. pseudocicera, L. aphaca, L. cicera, L. marmoratus, L. gorgoni, and L. tingitanus also showed low β-ODAP content. The results showed significant positive correlations among different trait combinations, viz., K and P (r = 0.193 ***), K and Fe (r = 0.177 ***), Mn and Fe (r = 0.210 ***), Mn and Se (r = 0.137 ***), β-ODAP and Mg (r = 0.158 **), and β-ODAP and Ca (r = 0.140 **). L. cicera, L. ochrus, and L. cassius were identified as a great source for improving the mineral concentration and reducing β-ODAP content in the cultivated grass pea.
Evaluation of Different Concentrations of Antimicrobial Quaternary Polymers on the Behavior of Gelatin- and Starch-Based Films
Authors: Cottet Celeste , Fernández-García M. , Peltzer M. A.
Published: November 2024

Nowadays, incorporating quaternary ammonium groups into polymers is one of the most promising strategies for preparing antimicrobial biomaterials for general applications. The main objective of this work was to evaluate the effect of different concentrations of antimicrobial quaternary polymers in gelatin- and starch-based films for the development of active materials intended for applications in food packaging and medical fields. Two antimicrobial biobased polymers, called MeFPIAx (MeFPIA1 and MeFPIA2), were previously synthesized through the radical polymerization of itaconic acid (IA), followed by their subsequent functionalization and modification. Both polymers were incorporated into a new blend of gelatin and starch (15% w/w, 4:1 mass ratio), using glycerol (30% w/w) as a plasticizer. Films were prepared using the casting technique from aqueous dispersions of the polymers and their structure was characterized by Fourier Transform Infrared Spectroscopy with Attenuated Total Reflectance (FTIR-ATR). The findings of this study showed the addition of MeFPIAx had a significant effect (p < 0.05), resulting in films with higher tensile strength (TS) and a higher Young’s modulus (YM), with values close to 20 MPa and exceeding 250 MPa, respectively. On the other hand, elongation at break (EB) values lower than 80% were obtained. Additionally, the swelling was reduced from ~400% to 100% and a reduction in water vapor permeability (Pw) was observed, thanks to the increased interaction between the polymeric chains. Differential scanning calorimetry (DSC) scans showed that the addition of MeFPIAx increased the glass transition temperatures (Tg) from 29 °C to 65 °C. Furthermore, thermogravimetry analysis (TGA) indicated an increase in the initial degradation temperatures, suggesting that the films were more thermally resistant. Finally, the films exhibited slight antioxidant activity but significant antimicrobial activity, achieving bacterial reduction values greater than 70% with the incorporation of MeFPIAx polymers against Gram-positive Staphylococcus aureus.
Adding Mandarin Peel Waste to a Biodegradable Polymeric Matrix: Reinforcement or Degradation Effect?
Authors: Titone Vincenzo , Mistretta Maria Chiara , Botta Luigi
Published: November 2024

In the current context, the use of fillers derived from fruit and vegetable waste is a crucial approach to mitigate waste and promote sustainable resource use, thus contributing to product life cycle completion and the achievement of sustainability goals. This study focuses on incorporating an endemic waste hitherto considered irrelevant within a biodegradable matrix. The resulting biocomposites were carefully characterized mechanically, rheologically, and morphologically to identify the connections between processability, structure, and properties. The results show that the presence of the filler results in an increase in the stiffness of the material (up to 27% in elastic modulus) accompanied by a decrease in tensile strength (approximately 50%) and elongation at break, which is on average about 7% at the highest filler content. This behavior was attributed to poor interfacial adhesion and the influence of a degradation process caused by the presence of citric acid and/or impurities in the filler.
High Modulus Epoxy/GO-PANI Self-Healing Materials Without Catalyst by Molecular Engineering and Nanocomposite Fabrication
Authors: Kim Geonwoo , Caglayan Cigdem , Yun Gun Jin
Published: November 2024

Nowadays, self-healing materials have been studied actively in electronics, soft robotics, aerospace, and automobiles because they can prolong the life span of the materials. However, overcoming the trade-off relationship between mechanical properties and self-healing performance is challenging. Herein, graphene oxide-polyaniline (GO-PANI) filler was introduced to overcome this challenge because GO has a highly excellent modulus, and nitrogen atoms in PANI can endow a self-healing ability through hydrogen bonds. Aside from the hydrogen bond in PANI, the hydrogen bond in the carbonyl group and the disulfide exchange bond in the epoxy matrix also helped the materials heal efficiently. Therefore, the modulus of SV-GPN1 (Self-healing Vitrimer-GO-PANI1) reached 770 MPa, and a 65.0% healing efficiency was demonstrated. The modulus and self-healing efficiency were enhanced after adding GO-PANI filler. The self-healing ability, however, deteriorated when adding more GO-PANI filler because it hindered the collision between the molecules. Meanwhile, SV-GPN1 was excellent in reproducibility, which was proven by the experiment that 16.50 mm thick SV-GPN1 also displayed a self-healing ability. Thus, SV-GPN1 can be applied to structural materials in industries like aerospace because of its self-healing ability, excellent modulus, and reproducibility.
The Use of Rubber-Polymer Composites in Bitumen Modification for the Disposal of Rubber and Polymer Waste
Authors: Akkenzheyeva Anar , Haritonovs Viktors , Bussurmanova Akkenzhe , Merijs-Meri Remo , Imanbayev Yerzhan , Serikbayeva Akmaral , Sydykov Serik , Ayapbergenov Yerbolat , Jankauskas Martynas , Trumpels Anatolijs , Aimova Murshida , Turkmenbayeva Maira
Published: November 2024

The use of rubber-polymer composites ELTC (End of Life Tire Compound) for bitumen modification was investigated. ELTC contains not only devulcanized rubber from used car tires, but also used plastics (polymers) such as polyethylene (PE) and polypropylene (PP). ELTC is obtained using the method of rubber devulcanization using a selective catalyst that allows selectively decomposing sulfide bonds at relatively low temperatures, while preserving most of the macromolecular chains. The characteristics of the asphalt binder improved after the modification of ELTC. After modification, the base asphalt binder became more homogeneous, and the thermal stability of the base asphalt binder increased. ELTC is evenly distributed, the compatibility between the components of the modified asphalt binder is good, which proves the uniformity of the modified asphalt binders. The results show that all ELTC formulations improve the softening temperature and increase their resistance to plastic deformation in the summer.
Preparation and Exploration of Spherical Fe-C Micro-Electrolysis Materials for the Removal of Crystal Violet
Authors: Dai Min , Wei Xixi , Lin Chihpeng , Xie Chunsheng , Lai Zimin , Zhu Wencan , Guo Junhao , Peng Changsheng
Published: November 2024

In this paper, the spherical Fe-C micro-electrolysis materials (Fe-C MEM) were prepared using iron powder, activated carbon powder, corn straw, and bentonite as the raw materials. The preparation conditions optimized by single factor test showed Fe-C MEM had a high crystal violet removal and strength under 1:1 of Fe/C ratio, 2% corn straw content, 25% bentonite content, and 900 °C sintering temperature. The porous Fe-C MEM had a high specific surface area of 108.069 m2/g with an even distribution of zero-valent iron and carbon. The maximum removal capacity of CV by Fe-C MEM was 105.48 mg/g at 25 °C. The CV removal was a spontaneous endothermic process. The mechanism of CV removal by Fe-C MEM was adsorption combined with degradation. Fe-C MEM has a good performance in dye wastewater treatment.
Recovery of Lesser-Known Strategic Metals: The Gallium and Germanium Cases
Authors: Robla Jose , Alonso Manuel , Alguacil Francisco
Published: November 2024

Being not as popular as other elements, such as cobalt, lithium, and rare earth elements, both gallium and germanium have wide use in target developments/industries, thus making them valuable and strategically critical metals. The principal sources for the recovery of both metals are secondary wastes of the bauxite (gallium) or zinc (germanium) industries; also, their recycling from waste materials is necessary. The characteristics of these materials make hydrometallurgical operations widely useful in recovering both gallium and germanium from the various sources containing them. The present work reviews the most recent applications (in 2024) of the various operations applied to the recovery of gallium or germanium from various resources.
Preparation and Characterization of Transferable Encapsulated Dye-Sensitized Solar Cells
Authors: Hartwich Patrick , Naidu Vakamulla Raghu Swathi , Müller Maurice , Pritzel Christian , Haring Bolívar Peter , Killian Manuela S.
Published: November 2024

The increasing demand for sustainable energy as a means to combat the impact of climate change is addressed via a novel concept in the present work. Herein presented are developed transferable encapsulated dye-sensitized solar cells, canonically “solar capsules”, for photovoltaic applications on alternative surfaces, such as facades. The solar capsule assembly houses all the components necessary for photovoltaic energy conversion, enclosed within a semiconductor nanotubular array, making them truly unique in their construction. This capsule-style unit enables an easy transfer and draft onto a wide range of materials and surfaces for photovoltaic functionalization and applications. This type of dye-sensitized solar cell typically consists of transferred solar capsules and two additional electrodes. The design and construction of solar capsules means they have a high economic viability as they can seamlessly be up-scaled using commercially established techniques such as anodization and subsequent functionalization. This work demonstrates a working model of such transferable solar capsules by fabricating TiO2 nanotubes that are functionalized via facile dip- and spin-coating techniques in a wet lab at ambient conditions. These prototypes are characterized in bulk and are thoroughly investigated at the nanoscale for information on the chemical distribution of the constituents, as they may be influenced during the manufacturing process.
Hyperbolic Evolutionary Model for Equivalent Modulus of Sand and Characterization of Its Cyclic Hardening Properties
Authors: Wu Xueqing , Shao Longtan , Tian Xiaojian , Xia Pingxin
Published: November 2024

The cyclic hardening characteristics of soil hold significant importance for understanding its performance, and the evolution of the deformation modulus serves as a crucial indicator of the hardening properties. Deformations can be classified into elastic and plastic deformations and expressed in terms of modulus; however, their roles in the cyclic hardening process remain unclear. In this study, the elastic and plastic moduli were separated using the hyperbolic evolutionary model, which characterized the evolutionary properties of both to reflect the cyclic hardening process. A series of cyclic triaxial shear tests was conducted utilizing ISO sand and emery as test materials. A hyperbolic evolution model relating the equivalent modulus to the number of cycles was established, and the effect of various test conditions on the elastic modulus is discussed. The results indicate that: (1) the relationship between the equivalent modulus and the number of cycles is hyperbolic; and (2) the parameters k and b of the hyperbolic evolution model correspond to the elastic and plastic moduli, allowing for the separation of the evolution of both from that of the deformation modulus. The hyperbolic evolution model of the equivalent modulus proposed in this paper offers new insight into the cyclic hardening properties of sand.
Mechanistic Insights into the Interaction Between Kinin Receptors and Histamine H2 Receptor Pathways in Oxidative Stress
Authors: Gregnani Marcos Fernandes , Martins Leonardo , Fogel Wieslawa Agnieszka
Published: November 2024

Reactive oxygen species (ROS) encompass various molecular oxygen derivatives naturally produced during aerobic metabolism, including superoxide anions, hydrogen peroxide, and hydroxyl radicals. Excessive ROS production leads to oxidative distress, causing cellular damage and contributing to various pathologies, often alongside inflammation. Endogenous sources of ROS include mitochondrial activity and NADPH oxidases. The antioxidant system, comprising enzymes such as superoxide dismutase, peroxiredoxin, and catalase, mitigates ROS-induced damage. This review explores the regulation of ROS by membrane receptors, focusing on B1 and B2 kinin receptors and histamine H2 receptors, which are implicated in vasodilation, angiogenesis, inflammation, and gastric acid secretion. Understanding these interactions provides insights into ROS modulation and its role in disease mechanisms.
Diasporas and Religious Identities: Insights from Anthropological Perspectives
Authors: Levy André
Published: November 2024

For many years, anthropology contributed significantly to the reinforcement of “dominant notions of culture and identity as being closely tied to specific territories” (Jansen and Löfving 2009, p [...]
Buildings, Lands, and Rents: Understanding the Process and Impact of Monastic Suppression in Spain
Authors: Congost Rosa
Published: November 2024

In Ancien Régime Spain, ecclesiastical wealth consisted of not only land, but also the rental income raised from tenancies of which the Church was proprietor. Therefore, the suppression of monasteries and convents in Spain cannot be studied only in terms of the transfer of their principal estates. The incoming Liberal State appropriated the Church’s rents for its own use, although many had fallen into abeyance before the suppressions began. To assess the true impact of ecclesiastical confiscation, it is necessary to consider how far developments in religious sensibility, whether or not associated with new conceptions of property, before and after the liberal revolution, may have affected the treatment of these rents. In this article, I aim to examine the geographical distribution of the different property rights of the regular clergy in Spain under the Ancien Régime and to observe the role of the Liberal State in their evolution and in the fate of monastery and convent buildings. We will see, in all cases, the significant roles of the payers and receivers of different types of rents. Thus, territories with the same legal regime and similar institutions passed through the process in very different ways.
Bible Narratives and Youth Religious Identity: An Italian Exploratory Study
Authors: Caputo Michele , Rompianesi Tommaso
Published: November 2024

Our article analyzes data from a broader exploratory Italian study on youth imaginaries and the role of narratives in attributing meaning to the world. The research gathered responses from 872 young people (aged 18 to 23) through a digital questionnaire. The data were analyzed with quantitative methodology using descriptive statistics. Our research questions can be formulated as follows: What level of familiarity do respondents have with biblical narratives? What narrative themes and categories do they use to define those stories? In relation to these elements, what are the characteristics of the respondents’ subgroups that defined themselves as “Religious”, “Indifferent/Agnostic”, and “Atheist”? The questionnaire items analyzed in this article provide an account of the respondents’ familiarity with some biblical narratives and their characters (Abraham, Jacob, and Ruth), as well as their choices related to the stories’ narrative themes and categories. The results from our sample open the field for further investigations, particularly in contexts characterized by different religious backgrounds (e.g., Protestant contexts), which may offer more nuanced interpretations of the educational process in relation to religious identity.
Fault Kinematics of the 2022 Delingha Mw 5.6 and Mw 5.7 Earthquakes Revealed by InSAR Observations
Authors: Wang Xuening , Wu Donglin , Liu Lian , Li Chenglong , Bai Yongliang , Huang Xing
Published: November 2024

Between January and April 2022, three moderate earthquakes (Mw 5.6 on 23 January, Mw 5.7 on 25 March, and Mw 5.1 on 15 April) struck the Hala Lake area of Delingha, Qinghai, China. Their seismogenic faults are poorly mapped, resulting in an unclear understanding of their kinematics and regional seismotectonics. In this study, we employed Interferometric Synthetic Aperture Radar (InSAR) observations to reconstruct the coseismic deformation fields of the Mw 5.6 and 5.7 events. We then utilized a Bayesian inversion algorithm to delineate the fault geometries of the two events, and further resolved their coseismic fault slip. Our results reveal that these earthquakes ruptured different fault planes: the fault plane of the Mw 5.6 event dips westward at an angle of 60°, while the Mw 5.7 event ruptured as a nearly vertical fault with a dipping angle of 89°. The finite-fault slip inversions further demonstrate that the coseismic rupture of the Mw 5.6 event was predominantly concentrated between depths of 2 km and 7 km, with a maximum slip of 0.18 m; in contrast, the Mw 5.7 event was mainly concentrated between depths of 2 km and 9 km, with a maximum slip of 0.4 m. We calculated the coseismic Coulomb failure stress change (ΔCFS) induced by these two earthquakes. Integrating the analysis of ΔCFS and the spatial distribution of aftershocks, we argue that the sequence earthquakes were triggered by the proceeding earthquakes.
Improved Phase Gradient Autofocus Method for Multi-Baseline Circular Synthetic Aperture Radar Three-Dimensional Imaging
Authors: Yi Shiliang , Xie Hongtu , Zhang Yuanjie , Wu Zhitao , Ge Mengfan , Zhu Nannan , Lu Zheng , Qin Pengcheng
Published: November 2024

Multi-baseline circular synthetic aperture radar (MB CSAR) can be applied to obtain a three-dimensional (3D) image of the observation scene. However, the phase error caused by radar platform motion or atmospheric propagation delay restricts its 3D imaging capabilities. The phase error calibration of MB CSAR data is an essential step in the 3D imaging procedure due to the limited accuracy of positioning sensors. Phase gradient autofocus (PGA) is widely utilized to estimate the phase errors but is subject to shifts in the direction perpendicular to the line of sight and long iteration time in some sub-apertures. In this paper, an improved PGA method for MB CSAR 3D imaging is proposed, which can suppress the shifts and reduce computation time. This method is based on phase gradient estimation, but the prominent units are selected with an energy criterion. Then, weighted phase gradient estimation is presented to suppress the influence of prominent units with poor quality. Finally, a contrast criterion is adopted to reach faster convergence. The experimental results based on the measured MB CSAR data (Gotcha dataset) demonstrate the validity and feasibility of the proposed phase error calibration method for MB CSAR 3D imaging.
Novel, Cost Effective, and Reliable Method for Thermal Conductivity Measurement
Authors: Janek Marian , Kudelcik Jozef , Hardon Stefan , Gutten Miroslav
Published: November 2024

This study describes the development and utilization of a novel setup for measuring the thermal conductivity of polyurethane composites with various nanoparticle contents. Measurements were conducted using both an experimental setup and a professional instrument, the TPS 2500 S, with results demonstrating high agreement with the precision of the measurements. The setup was further validated using a standard reference material with a thermal conductivity of 0.200 W/m/K. Additionally, the reliability of the setup was confirmed by its stability against ambient temperature variations between 20 and 30 degrees Celsius. This research presents a cost-effective method for measuring the thermal conductivity of polyurethane composites. Data processing involves noise reduction and smoothing techniques to ensure reliable results. The setup offers 5% accuracy and proves to be versatile for both research and educational applications.
Double Decomposition and Fuzzy Cognitive Graph-Based Prediction of Non-Stationary Time Series
Authors: Chen Junfeng , Guan Azhu , Cheng Shi
Published: November 2024

Deep learning models, such as recurrent neural network (RNN) models, are suitable for modeling and forecasting non-stationary time series but are not interpretable. A prediction model with interpretability and high accuracy can improve decision makers’ trust in the model and provide a basis for decision making. This paper proposes a double decomposition strategy based on wavelet decomposition (WD) and empirical mode decomposition (EMD). We construct a prediction model of high-order fuzzy cognitive maps (HFCM), called the WE-HFCM model, which considers interpretability and strong reasoning ability. Specifically, we use the WD and EDM algorithms to decompose the time sequence signal and realize the depth extraction of the signal’s high-frequency, low-frequency, time-domain, and frequency domain features. Then, the ridge regression algorithm is used to learn the HFCM weight vector to achieve modeling prediction. Finally, we apply the proposed WE-HFCM model to stationary and non-stationary datasets in simulation experiments. We compare the predicted results with the autoregressive integrated moving average (ARIMA) and long short-term memory (LSTM) models.For stationary time series, the prediction accuracy of the WE-HFCM model is about 45% higher than that of the ARIMA, about 35% higher than that of the SARIMA model, and about 16% higher than that of the LSTM model. For non-stationary time series, the prediction accuracy of the WE-HFCM model is 69% higher than that of the ARIMA and SARIMA models.
Adaptive Sharding for UAV Networks: A Deep Reinforcement Learning Approach to Blockchain Optimization
Authors: Lu Kaiyin , Zhang Xinguang , Zhai Tianbo , Zhou Mengjie
Published: November 2024

As unmanned aerial vehicle (UAV) technology expands into diverse applications, the demand for enhanced performance intensifies. Blockchain sharding technology offers promising avenues for improving data processing capabilities and security in drone networks. However, the inherent mobility of UAVs and their dynamic operational environment pose significant challenges to conventional sharding techniques, often resulting in communication latencies and data synchronization delays that compromise efficiency. This study presents a novel blockchain-based adaptive sharding framework specifically designed for UAV ecosystems. Our research extends beyond improving data transmission rates to encompass an enhanced Asynchronous Advantage Actor–Critic algorithm, tailored to address long-term optimization objectives in aerial networks. The proposed optimizations focus on dual objectives: enhancing data security while concurrently accelerating processing speeds. By addressing the limitations of traditional approaches, this work aims to facilitate seamless communication and foster innovation in UAV networks. The adaptive sharding framework, coupled with the refined A3C algorithm, presents a comprehensive solution to the unique challenges faced by mobile aerial systems in blockchain implementation.