bluuebunny/crossref_metadata_2025 huggingface dataset:
Dynamic and Post-Dynamic Recrystallization of Haynes 282 below the Secondary Carbide Solvus
Authors: Eriksson Emil , Hörnqvist Colliander Magnus
Published: January 2021

Thermomechanical processes, such as forging, are important steps during manufacturing of superalloy components. The microstructural development during processing, which controls the final component properties, is complex and depends on e.g., applied strain, strain rate and temperature. In this study, we investigate the effect of process parameters on the dynamic and post-dynamic recrystallization during hot compression of Ni-base superalloy Haynes 282. Specifically, we address the effect of deformation below the grain boundary carbide solvus temperature. During deformation, discontinuous and continuous dynamic recrystallization was observed at the grain boundaries, and particle-stimulated nucleation occurred at primary carbides. Strain rate was determined to be the governing factor controlling the recrystallization fraction for strain rates up to 0.5 s−1 above which adiabatic heating became the dominating factor. Careful examination of the temperature development during deformation showed that the response of the closed-loop temperature control system to adiabatic heating can have important effects on the interpretation of the observed behavior. During a 90 s post-deformation hold, grain growth and an increasing fraction of twin boundaries significantly changed the deformation-induced microstructure and texture. The microstructure developed during post-dynamic recrystallization was mainly controlled by the temperature and only weakly coupled to the prior deformation step.
Electrodeposition of Aluminium-Vanadium Alloys from Chloroaluminate Based Molten Salt Containing Vanadium Ions
Authors: Cvetković Vesna S. , Vukićević Nataša M. , Feldhaus Dominic , Milicevic-Neumann Ksenija , Barudžija Tanja S. , Friedrich Bernd , Jovićević Jovan N.
Published: January 2021

The Al-V alloys were synthetized by potentiostatic electrodeposition onto a glassy carbon electrode from equimolar AlCl3 + NaCl bath containing vanadium ions at 200 °C. The alloy deposits were characterized by X-ray diffraction, scanning electron microscopy, and energy dispersive spectroscopy. The deposits were identified as Al3V and AlV3 alloys. It was found that intermetallic alloys were synthetized during aluminium underpotential deposition onto vanadium metal that was previously deposited on the glassy carbon electrode by diffusion-controlled overpotential deposition. Alloys were the result of solid-state interdiffusion between the initially deposited vanadium and the subsequently deposited aluminium. As a source to secure a constant concentration of vanadium in the electrolyte during deposition, vanadium anodic dissolution, and VCl3 melt addition were studied. The effect of vanadium ion concentration in the electrolyte on the composition and the surface morphology of the obtained deposits was investigated. The results indicate that controlled vanadium and aluminium codeposition could be a further step to the successful development of an advanced technology for Al3V and AlV3 alloy synthesis.
An Overview of High Yield Strength Twinning-Induced Plasticity Steels
Authors: Yang Guanghui , Kim Jin-Kyung
Published: January 2021

Twinning-induced plasticity (TWIP) steel is a second-generation advanced high strength steel grade developed for automotive applications. TWIP steels exhibit an excellent combination of strength and ductility, mainly originating from the activation of deformation twinning. However, TWIP steels generally exhibit a relatively low yield strength (YS), which limits their practical applications. Thus, developing high YS TWIP steels without ductility loss is essential to increase their industrial applications. The present work summarizes and discusses the recent progress in improving the YS of TWIP steels, in terms of precipitation strengthening, solid solution strengthening, thermomechanical processing, and novel processes. Novel processes involving sub-boundary strengthening, multi-phase structure, and gradient structure as well as the control of thermomechanical processing (recovery annealing and warm rolling) and precipitation strengthening were found to result in an excellent combination of YS and total elongation.
Fabrication and Characterization of the Modified EV31-Based Metal Matrix Nanocomposites
Authors: Moheimani Seyed Kiomars , Dadkhah Mehran , Mosallanejad Mohammad Hossein , Saboori Abdollah
Published: January 2021

Metal matrix nanocomposites (MMNCs) with high specific strength have been of interest for numerous researchers. In the current study, Mg matrix nanocomposites reinforced with AlN nanoparticles were produced using the mechanical stirring-assisted casting method. Microstructure, hardness, physical, thermal and electrical properties of the produced composites were characterized in this work. According to the microstructural evaluations, the ceramic nanoparticles were uniformly dispersed within the matrix by applying a mechanical stirring. At higher AlN contents, however, some agglomerates were observed as a consequence of a particle-pushing mechanism during the solidification. Microhardness results showed a slight improvement in the mechanical strength of the nanocomposites following the addition of AlN nanoparticles. Interestingly, nanocomposite samples were featured with higher electrical and thermal conductivities, which can be attributed to the structural effect of nanoparticles within the matrix. Moreover, thermal expansion analysis of the nanocomposites indicated that the presence of nanoparticles lowered the Coefficient of Thermal Expansion (CTE) in the case of nanocomposites. All in all, this combination of properties, including high mechanical strength, thermal and electrical conductivity, together with low CTE, make these new nanocomposites very promising materials for electro packaging applications.
Optimization Study of Post-Weld Heat Treatment for 12Cr1MoV Pipe Welded Joint
Authors: Liu Zichen , Hu Xiaodong , Yang Zhiwei , Yang Bin , Chen Jingkai , Luo Yun , Song Ming
Published: January 2021

In order to clarify the role of different post-weld heat treatment processes in the manufacturing process, welding tests, post-weld heat treatment tests, and finite element analysis (FEA) are carried out for 12C1MoV steel pipes. The simulated temperature field and residual stress field agree well with the measured results, which indicates that the simulation method is available. The influence of post-weld heat treatment process parameters on residual stress reduction results is further analyzed. It is found that the post weld dehydrogenation treatment could not release residual stress obviously. However, the residual stress can be relieved by 65% with tempering treatment. The stress relief effect of “post weld dehydrogenation treatment + temper heat treatment” is same with that of “temper heat treatment”. The higher the temperature, the greater the residual stress reduction, when the peak temperature is at 650–750 °C, especially for the stress concentration area. The longer holding time has no obvious positive effect on the reduction of residual stress.
Effect of Alloying Elements on the Mechanical Properties of Mo3Si
Authors: Bi Wei , Sun Shunping , Bei Shaoyi , Jiang Yong
Published: January 2021

Molybdenum silicides are attractive high-temperature structural materials because of their excellent thermal stability and outstanding oxidation resistance at high temperatures. First-principles calculations were employed to investigate the effect of alloying elements (Cr, Nb, V, W, Al, Ga, and Ge) on the mechanical properties of Mo3Si. The structural stabilities of doped Mo3Si were calculated, showing that the Pm-3n structure was stable at the investigated low-doping concentration. The calculated elastic constants have also evaluated some essential mechanical properties of doped Mo3Si. Cr- and V-doping decreased the elastic modulus, while Al- and Nb-doping slightly increased the shear and Young’s modulus of Mo3Si. Furthermore, V-, Al- and Nb-doping decreased the B/G and Poisson ratio, suggesting that these elements could form strong covalent bonds, and decrease shear deformation and alloy ductility. Based on the three-dimensional contours and two-dimensional projection of the elastic modulus, Cr- and V-doping exhibited a significant influence on the anisotropy of the shear and Young’s modulus. According to charge density and density of states, the electronic structures of alloyed Mo3Si were further analyzed to reveal the doping effects.
Biocompatibility and Cellular Behavior of TiNbTa Alloy with Adapted Rigidity for the Replacement of Bone Tissue
Authors: Giner Mercè , Chicardi Ernesto , Costa Alzenira de Fátima , Santana Laura , Vázquez-Gámez María Ángeles , García-Garrido Cristina , Colmenero Miguel Angel , Olmo-Montes Francisco Jesús , Torres Yadir , Montoya-García María José
Published: January 2021

In this work, the mechanical and bio-functional behavior of a TiNbTa alloy is evaluated as a potential prosthetic biomaterial used for cortical bone replacement. The results are compared with the reference Ti c.p. used as biomaterials for bone-replacement implants. The estimated mechanical behavior for TiNbTa foams was also compared with the experimental Ti c.p. foams fabricated by the authors in previous studies. A TiNbTa alloy with a 20–30% porosity could be a candidate for the replacement of cortical bone, while levels of 80% would allow the manufacture of implants for the replacement of trabecular bone tissue. Regarding biocompatibility, in vitro TiNbTa, cellular responses (osteoblast adhesion and proliferation) were compared with cell growth in Ti c.p. samples. Cell adhesion (presence of filopodia) and propagation were promoted. The TiNbTa samples had a bioactive response similar to that of Ti c.p. However, TiNbTa samples show a better balance of bio-functional behavior (promoting osseointegration) and biomechanical behavior (solving the stress-shielding phenomenon and guaranteeing mechanical resistance).
A New Method for Weld Dilution Calculation through Chemical Composition Analysis
Authors: Zhang Zhanhui , Huang Xuefei , Yao Ping , Xue Jiaxiang
Published: January 2021

Aiming at existing methods unable to reveal the definition of dilution in welding accurately, such as the limited formula’s range of 0~1 mathematically, a new way which can be widely applied to various welds alloying either one or more compositions was proposed. Dilution values obtained using different methods through chemical composition analysis were compared and the effect of heat inputs on dilution was researched. The results show that the proposed method fabricated mathematically agrees well with the definition of dilution in welding. Especially, by dilution increasing to a level higher than the critical value, it reveals the fact that a weld can be concentrated as well when the filler wire is rich in the same composition as the substrate does. Besides, the method demonstrates that the gross dilution for a bead is a combined result that is affected by each individual composition. However, whether a composition is diluted or concentrated, composition’s concentrations are propelled by the increase of heat input toward that of the original substrate. During the process, the dilution value changes sharply before the heat input reaches the transition point (TP) of 0.18 kJ/mm, while once the heat input is beyond TP, the dilution becomes stable.
Untargeted Metabolomics Analysis Using FTIR and UHPLC-Q-Orbitrap HRMS of Two Curculigo Species and Evaluation of Their Antioxidant and α-Glucosidase Inhibitory Activities
Authors: Umar Abdul Halim , Ratnadewi Diah , Rafi Mohamad , Sulistyaningsih Yohana Caecilia
Published: January 2021

Curculigo orchioides and C. latifolia have been used as traditional medicines such as antidiabetic and anticancer. This study measured the total phenolics and flavonoid contents as well as analyzed the functional groups and chemical compounds using Fourier-transform infrared (FTIR) spectra and UHPLC-Q-Orbitrap-HRMS profiling for the discrimination of plant parts, geographical origin, and compounds that presumably have a significant contribution as antioxidant and α-glucosidase inhibitors on both plants. The total phenolics and flavonoids contents in Curculigo species varied from 142.09 to 452.47 mg gallic acid equivalent (GAE/g) and from 0.82 to 5.44 mg quercetin equivalent (QE/g), respectively. The lowest IC50 for antioxidant and α-glucosidase inhibitory activities is presented by C. latifolia from a higher altitude region. Principal component analysis (PCA) from FTIR and UHPLC-Q-Orbitrap-HRMS data could discriminate the plant parts and geographical origin. Partial least squares (PLS) analysis has identified several functional groups, such as O–H, C–H, C=O, C–C, C–O, and chemical compounds, unknown-185 and unknown-85, that are most likely to contribute to the antioxidant and α-glucosidase inhibitory activities.
Molecular Differences Based on Erythrocyte Fatty Acid Profile to Personalize Dietary Strategies between Adults and Children with Obesity
Authors: Jauregibeitia Iker , Portune Kevin , Gaztambide Sonia , Rica Itxaso , Tueros Itziar , Velasco Olaia , Grau Gema , Martín Alicia , Castaño Luis , Larocca Anna Vita , Di Nolfo Federica , Ferreri Carla , Arranz Sara
Published: January 2021

As the obesity epidemic continues to grow inexorably worldwide, the need to develop effective strategies to prevent and control obesity seems crucial. The use of molecular tools can be useful to characterize different obesity phenotypes to provide more precise nutritional recommendations. This study aimed to determine the fatty acid (FA) profile of red blood cell (RBC) membranes, together with the evaluation of their dietary intake and biochemical parameters, of children and adults with obesity. An observational study was carried out on 196 children (113 with normal weight and 83 with obesity) and 91 adults (30 with normal weight and 61 with obesity). Mature RBC membrane phospholipids were analyzed for FA composition by gas chromatography-mass spectrometry (GC-MS). Dietary habits were evaluated using validated food frequency questionnaires (FFQ). Children with obesity presented higher levels of ω-6 polyunsaturated FAs (mainly linoleic acid, p = 0.01) and lower values of ω-3 FAs (mainly DHA, p < 0.001) compared with adults. Regarding blood biochemical parameters, children with obesity presented lower levels of glucose, LDL cholesterol, and alanine aminotransferase compared with adults with obesity. These lipidomic differences could be considered to provide specific nutritional recommendations for different age groups, based on an adequate fat intake.
Free Saturated Oxo Fatty Acids (SOFAs) and Ricinoleic Acid in Milk Determined by a Liquid Chromatography-High-Resolution Mass Spectrometry (LC-HRMS) Method
Authors: Kokotou Maroula G. , Batsika Charikleia S. , Mantzourani Christiana , Kokotos George
Published: January 2021

Oxidized saturated fatty acids, containing a hydroxyl or an oxo functionality, have attracted little attention so far. Recent studies have shown that saturated hydroxy fatty acids, which exhibit cancer cell growth inhibition and may suppress β-cell apoptosis, are present in milk. Herein, we present the application of a liquid chromatography-high-resolution mass spectrometry (LC-HRMS) method for the detection and quantification of various saturated oxo fatty acids (SOFAs) previously unrecognized in milk. This robust and rapid analytical method, which involves simple sample preparation and a single 10-min run, revealed the presence of families of oxostearic acids (OSAs) and oxopalmitic acids (OPAs) in milk. 8OSA, 9OSA, 7OSA, 10OSA and 10OPA were found to be the most abundant SOFAs in both cow and goat milk. Higher contents of SOFAs were found in cow milk in comparison to goat milk. Together with SOFAs, ricinoleic acid, which is isobaric to OSA, was detected and quantified in all milk samples, following a “suspect” HRMS analysis approach. This unique natural fatty acid, which is the main component (>90%) of castor oil triglycerides, was estimated at mean content values of 534.3 ± 6.0 μg/mL and 460 ± 8.1 μg/mL in cow and goat milk samples, respectively.
Anchor Loss Reduction of Lamb Wave Resonator by Pillar-Based Phononic Crystal
Authors: Tong Yinjie , Han Tao
Published: January 2021

Energy leakage via anchors in substrate plates impairs the quality factor (Q) in microelectromechanical system (MEMS) resonators. Most phononic crystals (PnCs) require complicated fabrication conditions and have difficulty generating a narrow bandgap at high frequency. This paper demonstrates a pillar-based PnC slab with broad bandgaps in the ultra high frequency (UHF) range. Due to Bragg interference and local resonances, the proposed PnC structure creates notably wide bandgaps and shows great advantages in the high frequency, large electromechanical coupling coefficient (k2) thin film aluminum nitride (AlN) lamb wave resonator (LWR). The dispersion relations and the transmission loss of the PnC structure are presented. To optimize the bandgap, the influence of the material mechanical properties, lattice type, pillar height and pillar radius are explored. These parameters are also available to adjust the center frequency of the bandgap to meet the desirable operating frequency. Resonators with uniform beam anchors and PnC slab anchors are characterized. The results illustrate that the Q of the resonator improves from 1551 to 2384, and the mechanical energy leakage via the anchors is significantly decreased using the proposed PnC slab anchors. Moreover, employment of the PNC slab anchors has little influence on resonant frequency and induces no spurious modes. Pillar-based PnCs are promising in suppressing the anchor loss and further improving the Q of the resonators.
Review on Driving Circuits for Wide-Bandgap Semiconductor Switching Devices for Mid- to High-Power Applications
Authors: Ma Chao-Tsung , Gu Zhen-Huang
Published: January 2021

Wide-bandgap (WBG) material-based switching devices such as gallium nitride (GaN) high electron mobility transistors (HEMTs) and silicon carbide (SiC) metal-oxide-semiconductor field-effect transistors (MOSFETs) are considered very promising candidates for replacing conventional silicon (Si) MOSFETs for various advanced power conversion applications, mainly because of their capabilities of higher switching frequencies with less switching and conduction losses. However, to make the most of their advantages, it is crucial to understand the intrinsic differences between WBG- and Si-based switching devices and investigate effective means to safely, efficiently, and reliably utilize the WBG devices. This paper aims to provide engineers in the power engineering field a comprehensive understanding of WBG switching devices’ driving requirements, especially for mid- to high-power applications. First, the characteristics and operating principles of WBG switching devices and their commercial products within specific voltage ranges are explored. Next, considerations regarding the design of driving circuits for WBG switching devices are addressed, and commercial drivers designed for WBG switching devices are explored. Lastly, a review on typical papers concerning driving technologies for WBG switching devices in mid- to high-power applications is presented.
Continuous Particle Separation in Microfluidics: Deterministic Lateral Displacement Assisted by Electric Fields
Authors: García-Sánchez Pablo , Ramos Antonio
Published: January 2021

Advances in the miniaturization of microelectromechanical systems (MEMS) [...]
Understanding Material Removal Mechanism and Effects of Machining Parameters during EDM of Zirconia-Toughened Alumina Ceramic
Authors: Bilal Azat , Perveen Asma , Talamona Didier , Jahan Muhammad Pervej
Published: January 2021

Non-conductive structural ceramics are receiving ever-increasing attention due to their outstanding physical and mechanical properties and their critical applications in aerospace and biomedical industries. However, conventional mechanical machining seems infeasible for the machining of these superior ceramics due to their extreme brittleness and higher hardness. Electro discharge machining (EDM), well known for its machining of electrically conductive materials irrespective of materials hardness, has emerged as a potential machining technique due to its noncontact nature when complemented with an assistive electrode technique. This paper investigates the material removal mechanism and effects of machining parameters on machining speed and dimensional and profile accuracies of features machined on zirconia toughened alumina (ZTA) ceramics using assistive electrode EDM. Our experimental results demonstrate that both increasing peak current and pulse on time improves the MRR, however, it also aids in generating thicker layer on machined surface. In addition, pulse interval time is crucial for the machining of nonconductive ceramics, as larger value might cause the complete removal of intrinsic carbon layer which may lead to non/sparking condition. Higher peak current increases circularity whereas short pulse on and pulse off time aid in increasing circularity due to rough machining. In addition, taperness is found to be regulated by the peak current and pulse on time. Overall, thermal cracking and spalling appear to be a dominating material removal mechanism other than melting and evaporation for the EDM of ZTA.
Dynamic Modeling and Anti-Disturbing Control of an Electromagnetic MEMS Torsional Micromirror Considering External Vibrations in Vehicular LiDAR
Authors: Hua Yong , Wang Shuangyuan , Li Bingchu , Bai Guozhen , Zhang Pengju
Published: January 2021

Micromirrors based on micro-electro-mechanical systems (MEMS) technology are widely employed in different areas, such as optical switching and medical scan imaging. As the key component of MEMS LiDAR, electromagnetic MEMS torsional micromirrors have the advantages of small size, a simple structure, and low energy consumption. However, MEMS micromirrors face severe disturbances due to vehicular vibrations in realistic use situations. The paper deals with the precise motion control of MEMS micromirrors, considering external vibration. A dynamic model of MEMS micromirrors, considering the coupling between vibration and torsion, is proposed. The coefficients in the dynamic model were identified using the experimental method. A feedforward sliding mode control method (FSMC) is proposed in this paper. By establishing the dynamic coupling model of electromagnetic MEMS torsional micromirrors, the proposed FSMC is evaluated considering external vibrations, and compared with conventional proportion-integral-derivative (PID) controls in terms of robustness and accuracy. The simulation experiment results indicate that the FSMC controller has certain advantages over a PID controller. This paper revealed the coupling dynamic of MEMS micromirrors, which could be used for a dynamic analysis and a control algorithm design for MEMS micromirrors.
The Wafer-Level Integration of Single-Crystal LiNbO3 on Silicon via Polyimide Material
Authors: Yang Xiangyu , Geng Wenping , Bi Kaixi , Mei Linyu , Li Yaqing , He Jian , Mu Jiliang , Hou Xiaojuan , Chou Xiujian
Published: January 2021

In situ measurements of sensing signals in space platforms requires that the micro-electro-mechanical system (MEMS) sensors be located directly at the point to be measured and in contact with the subject to be measured. Traditional radiation-tolerant silicon-based MEMS sensors cannot acquire spatial signals directly. Compared to silicon-based structures, LiNbO3 single crystalline has wide application prospects in the aerospace field owing to its excellent corrosion resistance, low-temperature resistance and radiation resistance. In our work, 4-inch LiNbO3 and LiNbO3/Cr/Au wafers are fabricated to silicon substrate by means of a polyimide bonding method, respectively. The low-temperature bonding process (≤100 °C) is also useful for heterostructure to avoid wafer fragmentation results from a coefficient of thermal expansion (CTE) mismatch. The hydrophilic polyimide surfaces result from the increasing of -OH groups were acquired based on contact angle and X-ray photoelectron spectroscopy characterizations. A tight and defect-free bonding interface was confirmed by scanning electron microscopy. More importantly, benefiting from low-temperature tolerance and radiation-hardened properties of polyimide material, the bonding strength of the heterostructure based on oxygen plasma activation achieved 6.582 MPa and 3.339 MPa corresponding to room temperature and ultra-low temperature (≈ −263.15 °C), which meets the bonding strength requirements of aerospace applications.
Experimental Study of Bubble Formation from a Micro-Tube in Non-Newtonian Fluid
Authors: Kontaxi Georgia , Stergiou Yorgos G. , Mouza Aikaterini A.
Published: January 2021

Over the last few years, microbubbles have found application in biomedicine. In this study, the characteristics of bubbles formed when air is introduced from a micro-tube (internal diameter 110 μm) in non-Newtonian shear thinning fluids are studied. The dependence of the release time and the size of the bubbles on the gas phase rate and liquid phase properties is investigated. The geometrical characteristics of the bubbles are also compared with those formed in Newtonian fluids with similar physical properties. It was found that the final diameter of the bubbles increases by increasing the gas flow rate and the liquid phase viscosity. It was observed that the bubbles formed in a non-Newtonian fluid have practically the same characteristics as those formed in a Newtonian fluid, whose viscosity equals the asymptotic viscosity of the non-Newtonian fluid, leading to the assumption that the shear rate around an under-formation bubble is high, and the viscosity tends to its asymptotic value. To verify this notion, bubble formation was simulated using Computational Fluid Dynamics (CFD). The simulation results revealed that around an under-formation bubble, the shear rate attains a value high enough to lead the viscosity of the non-Newtonian fluid to its asymptotic value.
Micro Direct Methanol Fuel Cell Based on Reduced Graphene Oxide Composite Electrode
Authors: Liu Chaoran , Hu Sanshan , Yin Lu , Yang Wenli , Yu Juan , Xu Yumin , Li Lili , Wang Gaofeng , Wang Luwen
Published: January 2021

The effect of an anode composite electrode on the performance of a micro direct methanol fuel cell (μDMFC) is analyzed from sample preparation configurations and discussed in detail, with a specific focus on the catalyst layer and the micro-porous layer on the anode composite electrode. This study investigates the effects of Pt content, Pt-Ru molar ratio, Nafion content, catalyst support, and preparation method in the catalyst layer, along with the carbon loading and polytetrafluoroethylene (PTFE) content in the micro-porous layer, on the performance of the anode composite electrode. The results show that the anode composite electrode delivers the best performance with 30% Pt content, a 1:1.5 Pt-Ru molar ratio, 10% Nafion content on reduced graphene oxide as the catalyst support. The synthesis is optimized with the impregnation reduction method using NaBH4 as the reducing agent, with the addition of 1.5 mg/cm2 carbon loading and 5% PTFE.
A Novel Particle-Based Approach for Modeling a Wet Vertical Stirred Media Mill
Authors: Larsson Simon , Rodríguez Prieto Juan Manuel , Heiskari Hannu , Jonsén Pär
Published: January 2021

Modeling of wet stirred media mill processes is challenging since it requires the simultaneous modeling of the complex multiphysics in the interactions between grinding media, the moving internal agitator elements, and the grinding fluid. In the present study, a multiphysics model of an HIG5 pilot vertical stirred media mill with a nominal power of 7.5 kW is developed. The model is based on a particle-based coupled solver approach, where the grinding fluid is modeled with the particle finite element method (PFEM), the grinding media are modeled with the discrete element method (DEM), and the mill structure is modeled with the finite element method (FEM). The interactions between the different constituents are treated by loose (or weak) two-way couplings between the PFEM, DEM, and FEM models. Both water and a mineral slurry are used as grinding fluids, and they are modeled as Newtonian and non-Newtonian fluids, respectively. In the present work, a novel approach for transferring forces between grinding fluid and grinding media based on the Reynolds number is implemented. This force transfer is realized by specifying the drag coefficient as a function of the Reynolds number. The stirred media mill model is used to predict the mill power consumption, dynamics of both grinding fluid and grinding media, interparticle contacts of the grinding media, and the wear development on the mill structure. The numerical results obtained within the present study show good agreement with experimental measurements.
Geochemistry and Geochronology of the Neoproterozoic Backarc Basin Khzama Ophiolite (Anti-Atlas Mountains, Morocco): Tectonomagmatic Implications
Authors: Chaib Latifa , Ait Lahna Abdelhak , Admou Hassan , Youbi Nasrrddine , El Moume Warda , Tassinari Colombo Celso Gaeta , Mata João , Basei Miguel Angelo Stipp , Sato Kei , Marzoli Andrea , Bodinier Jean-Louis , Gärtner Andreas , Boumehdi Moulay Ahmed , Bensalah Mohamed Khalil , Soulaimani Abderrahmane , Hefferan Kevin , Maacha Lhou , Bajddi Amine
Published: January 2021

The Khzama ophiolite is a highly dismembered complex located in the Siroua inlier of the Moroccan Anti-Atlas Belt. It consists of ultramafic rocks, cumulate gabbros, sheeted dikes, pillow lavas, and an overlying volcano-sedimentary sequence. Three main tectonic slices of sheeted dike complexes are studied in detail along three rivers, exposing well preserved outcrops where individual dikes are clearly distinguishable from the intruded host rock (Assif n’Tinzla, Assif n’Tasriwine, and Assif n’Iriri). Sheeted dikes of the Khzama ophiolitic complex are basaltic to andesitic in composition, displaying a clear sub-alkaline nature. We identify two sets of dikes that originate from lower High-Ti series (HTS) lavas and overlying upper Low-Ti series (LTS) lava. The immobile trace-element signatures of these rocks point to a genesis on a backarc environment with magmas sourced in a supra-subduction zone (SSZ) at the spinel peridotite zone. The obtained SHRIMP U-Pb data of the gabbro represent the first radiometric age of zircon extracted from the mafic rocks that were intruded by the sheeted dike complex of the Khzama ophiolite. These grains yield a concordia age of 763 ± 5 Ma, which is consistent with the 761.1 + 1.9/−1.6 and 762 + 1/−2 Ma U-Pb zircon ages of plagiogranites of Siroua. Based on their mineralogy, modal proportions, and major element chemistry, the felsic dikes are classified as high silica–low alumina trondhjemites or plagiogranites. These plagiogranites were likely formed by the partial melting of mafic rocks rather than by extreme fractional crystallization. A plagiogranite dated at 777 ± 4.7 Ma (U-Pb on zircon) is significantly older than the ca. 762 Ma plagiogranites previously recorded for the Khzama locality, suggesting a long-lived supra-subduction zone (SSZ) with conditions for the hydrous melting of mafic rocks.
Partitioning and Surficial Segregation of Trace Elements in Iron Oxides in Hydrothermal Fluid Systems
Authors: Smagunov Nikolay , Tauson Vladimir , Lipko Sergey , Babkin Dmitriy , Pastushkova Taisa , Belozerova Olga , Bryansky Nikolay
Published: January 2021

Partitioning experiments were done by hydrothermal synthesis of crystals containing trace elements (TEs) by internal sampling of fluid at the temperature of 450 °C and pressure of 1 kbar. The crystal phases obtained were magnetite, hematite, and Ni-spinel, which were studied using X-ray diffraction (XRD), X-ray electron probe microanalysis (EPMA), laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), atomic absorption spectrometry (AAS), and atomic force microscopy (AFM). The solutions from the sampler’s fluid probes were analysed by AAS for TEs included elements of the iron group plus aluminium. The highest co-crystallisation coefficients of TE and Fe between mineral and fluid (DTE/Fe) in magnetite were measured for V, Al, Ni and Cr (in decreasing order of n units in value), a lower value was observed for Co (2 × 10−1), and still lower values for Ti, Zn, and Mn (n × 10−2–10−3). In hematite, DTE/Fe values were highest for Al and V (order of n units in value), while lower values characterised Ti, Cr, and Co (n × 10−1–10−3), and the lowest values were exhibited by Cu, Mn, and Zn (n × 10−5). Copper was confirmed to be the most incompatible with all minerals studied; however, Cu had a high content on crystal surfaces. This surficial segregation contributes to the average TE concentration even when a thin layer of nonautonomous phase (NAP) is enriched in the element of interest. The accumulation of TEs on the surface of crystals increased bulk content 1–2 orders of magnitude above the content of structurally-bound elements even in coarse crystals. The inverse problem—evaluation of TE/Fe ratios in fluids involved in the formation of magnetite-containing deposits—revealed that the most abundant metals in fluids were Fe followed by Mn, Zn, and Cu, which comprised 10 to 30% of the total iron content.
Effect of Dodecane-Oleic Acid Collector Mixture on the Evolution of Wetting Film between Air Bubble and Low-Rank Coal
Authors: Liao Yinfei , Song Xingwei , An Maoyan , Yang Zhe , Hao Xiaodong , Ren Hourui
Published: January 2021

The wetting film evolution process is essential for flotation, especially in bubble–particle attachment. A mixed collector has been proved effective in promoting flotation. In this paper, the effect of a mixed collector (MC) composed by n-dodecane (D) and oleic acid (OA) on wetting film evolution was investigated using the extended Derjagin–Landau–Verwey–Overbeek (EDLVO) theory, the Stefan–Reynolds model, induction time, and zeta potential measurement. The hydrophobic force constant between bubble and coal treated by different collectors was analyzed. The results showed that MC was superior in reducing the induction time and increasing the zeta potential. When bubbles interacted with coal treated by MC, they had relatively low interaction energy, high critical film thickness, and high drainage rate. The order of hydrophobic force constant was no reagent < D < OA < MC. It indicated that the hydrophobic interaction between bubbles and coal particles treated by MC was the strongest because of the synergistic effect of D and OA.
Flotation Behavior and Synergistic Mechanism of Benzohydroxamic Acid and Sodium Butyl-Xanthate as Combined Collectors for Malachite Beneficiation
Authors: Zhang Chenyang , Zhou Qiqi , An Bingxuan , Yue Tong , Chen Shengda , Liu Mengfei , He Jianyong , Zhu Jianyu , Chen Daixiong , Hu Bo , Sun Wei
Published: January 2021

Sulfuration flotation is the most widely used technology in malachite beneficiation. However, the inhomogeneity of malachite surfaces usually results in a non-uniform sulfuration surface. The motivation of this work is attempt to adopt different functional combination collectors to enhance the sulfuration flotation of malachite. Accordingly, the flotation behaviors and adsorption mechanisms of benzohydroxamic acid (BHA) and sodium butyl-xanthate (SBX) on the surface of malachite were systematically investigated using flotation tests, zeta-potential measurements, Fourier-transform infrared (FTIR) spectroscopy, Raman spectroscopy, and first-principle calculations. The test results of vulcanization flotation showed that the combined collectors of SBX with BHA possessed a higher recovery than only using SBH by 20%, indicating that there may be a synergistic effect between BHA and SBX. The IR and Raman spectroscopy demonstrated that both BHA and SBX could chemically adsorb onto the malachite surface. The density functional theory (DFT) calculation results further indicated that the combined adsorption energy of BHA and SBX was much lower than that of only BHA or SBX, which confirmed the synergistic effects of BHA and SBX on the malachite surface. This work may shed new light on the design and development of more efficient combined flotation reagents.
Development of Low-Alkali, Fly Ash/Slag Geopolymers: Predictive Strength Modelling and Analyses of Impact of Curing Temperatures
Authors: Ukritnukun Supphatuch , Koshy Pramod , Feng Clayton , Rawal Aditya , Castel Arnaud , Sorrell Charles Christopher
Published: January 2021

The present work analyses the effects of curing temperature (25, 40, 60 °C for 24 h), silicate modulus Ms value (1.5, 1.7, 2.0), and slag content (10, 20, 30, 40 wt%) on the compressive strength development (1, 7, 14, 28 days) of low-alkali geopolymer mortars with matrices from fly ash and blast furnace slag. These data were used to generate predictive models for 28-day compressive strength as a function of curing temperature and slag content. While the dominant variable for the 1-day compressive strength was the curing temperature, the slag content was dominant for the 28-day compressive strength. The ratio of the 1-day and 28-day compressive strengths as a function of curing temperature, Ms value, and slag content allows prediction of the maximal possible curing temperature and shows cold-weather casting to present an obstacle to setting. These data also allow prediction of the 28-day compressive strength using only the 1-day compressive strength.
Study on the Effect and Mechanism of Impurity Aluminum on the Solvent Extraction of Rare Earth Elements (Nd, Pr, La) by P204-P350 in Chloride Solution
Authors: Zhang Wenjie , Xie Xian , Tong Xiong , Du Yunpeng , Song Qiang , Feng Dongxia
Published: January 2021

Solvent extraction is the most widely used method for separation and purification of rare earth elements, and organic extractants such as di(2-ethylhexyl) phosphoric acid (P204) and di(1-methyl-heptyl) methyl phosphonate (P350) are most commonly used for industrial applications. However, the presence of impurity ions in the feed liquid during extraction can easily emulsify the extractant and affect the quality of rare earth products. Aluminum ion is the most common impurity ion in the feed liquid, and it is an important cause of emulsification of the extractant. In this study, the influence of aluminum ion was investigated on the extraction of light rare earth elements by the P204-P350 system in hydrochloric acid medium. The results show that Al3+ competes with light rare earths in the extraction process, reducing the overall extraction rate. In addition, the Al3+ stripping rate is low and there is continuous accumulation of Al3+ in the organic phase during the stripping process, affecting the extraction efficiency and even causing emulsification. The slope method and infrared detection were utilized to explore the formation of an extraction compound of Al3+ and the extractant P204-P350 that entered the organic phase as AlCl[(HA)2]2P350(o).
Stream Sediments of the Pestrinsk Silver-Bearing System (Northeastern Russia)
Authors: Makshakov Artem S. , Kravtsova Raisa G.
Published: January 2021

The composition, structure, and formation features of the exogenous anomalous geochemical fields (AGCFs) identified through stream sediments (SSs) are considered here within the Pestrinsk silver-bearing system and the Goltsovy silver-polymetallic deposit. The research was performed in the southern part of the Balygychan-Sugoy trough (northeastern Russia). The exogenous AGCFs of the main indicator elements of ores, formed in cryolithogenesis zone conditions, were studied. We used the results of multi-scale areal geochemical surveys of SSs. A survey of SSs at 1:200,000 scale was found to be effective at the stage of regional forecasting. Indeed, it is characterized by simplicity and the possibility of obtaining information operatively regarding the metallogeny of the area. It was found that at the local forecast stage, when prospecting for mineralization, the most effective was a survey of SSs at 1:50,000 scale. The AGCFs identified during this survey were distinguished by a richer component composition, higher contrast, and closer relationship with ores. During the lithochemical sampling of the watercourse heads, where alluvial sediments were found to be almost completely absent, a positive result was obtained by the bryolithochemical method, which is based on moss sampling together with a fine fraction of alluvium held by a moss cushion. The method enabled the sampling of watercourse heads and thus yielded information about the presence or absence of anomalous concentration fields of ore elements.
Optimising Dead-End Cake Filtration Using Poroelasticity Theory
Authors: Köry J. , Krupp A. , Please C. , Griffiths I.
Published: January 2021

Understanding the operation of filters used to remove particulates from fluids is important in many practical industries. Typically the particles are larger than the pores in the filter so a cake layer of particles forms on the filter surface. Here we extend existing models for filter blocking to account for deformation of the filter material and the cake layer due to the applied pressure that drives the fluid. These deformations change the permeability of the filter and the cake and hence the flow. We develop a new theory of compressible-cake filtration based on a simple poroelastic model in which we assume that the permeability depends linearly on local deformation. This assumption allows us to derive an explicit filtration law. The model predicts the possible shutdown of the filter when the imposed pressure difference is sufficiently large to reduce the permeability at some point to zero. The theory is applied to industrially relevant operating conditions, namely constant flux, maximising flux and constant pressure drop. Under these conditions, further analytical results are obtained, which yield predictions for optimal filter design with respect to given properties of the filter materials and the particles.
Development and Validation of a Method for Determining the Quercetin-3-O-glucuronide and Ellagic Acid Content of Common Evening Primrose (Oenothera biennis) by HPLC-UVD
Authors: Kim Tae Heon , Shin Hyun Young , Park Soon Yeong , Kim Hoon , Chung Dae Kyun
Published: January 2021

Toward the standardization of common evening primrose (Oenothera biennis) sprout extract (OBS-E), we aimed to obtain indicator compounds and use a validated method. HPLC-UVD allowed simultaneous quantification of the indicator compounds quercetin-3-O-glucuronide and ellagic acid. The method was validated in terms of specificity, linearity, precision, accuracy, and limit of detection/limit of quantification (LOD/LOQ). High specificity and linearity was demonstrated, with correlation coefficients of 1.0000 for quercetin-3-O-glucuronide and 0.9998 for ellagic acid. The LOD/LOQ values were 0.486/1.472 μg/mL for quercetin-3-O-glucuronide and 1.003/3.039 μg/mL for ellagic acid. Intra-day and inter-day variability tests produced relative standard deviation for each compound of <2%, a generally accepted precision criterion. High recovery rate were also obtained, indicating accuracy validation. The OBS-E prepared using various concentrations of ethanol were then analyzed. The 50% ethanol extract had highest content of quercetin-3-O-glucuronide, whereas the 70% ethanol extract possessed the lowest. However, the ellagic acid content was highest in the 70% ethanol extract and lowest in the 90% ethanol extract. Thus, quercetin-3-O-glucuronide and ellagic acid can be used industrially as indicator compounds for O. biennis sprout products, and our validated method can be used to establish indicator compounds for other natural products.
Dynamic Preference for NADP/H Cofactor Binding/Release in E. coli YqhD Oxidoreductase
Authors: Verma Rajni , Ellis Jonathan M. , Mitchell-Koch Katie R.
Published: January 2021

YqhD, an E. coli alcohol/aldehyde oxidoreductase, is an enzyme able to produce valuable bio-renewable fuels and fine chemicals from a broad range of starting materials. Herein, we report the first computational solution-phase structure-dynamics analysis of YqhD, shedding light on the effect of oxidized and reduced NADP/H cofactor binding on the conformational dynamics of the biocatalyst using molecular dynamics (MD) simulations. The cofactor oxidation states mainly influence the interdomain cleft region conformations of the YqhD monomers, involved in intricate cofactor binding and release. The ensemble of NADPH-bound monomers has a narrower average interdomain space resulting in more hydrogen bonds and rigid cofactor binding. NADP-bound YqhD fluctuates between open and closed conformations, while it was observed that NADPH-bound YqhD had slower opening/closing dynamics of the cofactor-binding cleft. In the light of enzyme kinetics and structural data, simulation findings have led us to postulate that the frequently sampled open conformation of the cofactor binding cleft with NADP leads to the more facile release of NADP while increased closed conformation sampling during NADPH binding enhances cofactor binding affinity and the aldehyde reductase activity of the enzyme.
Chitosan Nanoparticles-Insight into Properties, Functionalization and Applications in Drug Delivery and Theranostics
Authors: Jhaveri Jhanvi , Raichura Zarna , Khan Tabassum , Momin Munira , Omri Abdelwahab
Published: January 2021

Nanotechnology-based development of drug delivery systems is an attractive area of research in formulation driven R&D laboratories that makes administration of new and complex drugs feasible. It plays a significant role in the design of novel dosage forms by attributing target specific drug delivery, controlled drug release, improved, patient friendly drug regimen and lower side effects. Polysaccharides, especially chitosan, occupy an important place and are widely used in nano drug delivery systems owing to their biocompatibility and biodegradability. This review focuses on chitosan nanoparticles and envisages to provide an insight into the chemistry, properties, drug release mechanisms, preparation techniques and the vast evolving landscape of diverse applications across disease categories leading to development of better therapeutics and superior clinical outcomes. It summarizes recent advancement in the development and utility of functionalized chitosan in anticancer therapeutics, cancer immunotherapy, theranostics and multistage delivery systems.
Kinetic Behavior of Quaternary Ammonium Hydroxides in Mixed Methane and Carbon Dioxide Hydrates
Authors: Khan Muhammad Saad , Bavoh Cornelius Borecho , Foo Khor Siak , Shariff Azmi Mohd , Kassim Zamzila , Othman Nurzatil Aqmar Bt , Lal Bhajan , Ahmed Iqbal , Rahman Mohammad Azizur , Gomari Sina Rezaei
Published: January 2021

This study evaluates the kinetic hydrate inhibition (KHI) performance of four quaternary ammonium hydroxides (QAH) on mixed CH4 + CO2 hydrate systems. The studied QAHs are; tetraethylammonium hydroxide (TEAOH), tetrabutylammonium hydroxide (TBAOH), tetramethylammonium hydroxide (TMAOH), and tetrapropylammonium hydroxide (TPrAOH). The test was performed in a high-pressure hydrate reactor at temperatures of 274.0 K and 277.0 K, and a concentration of 1 wt.% using the isochoric cooling method. The kinetics results suggest that all the QAHs potentially delayed mixed CH4 + CO2 hydrates formation due to their steric hindrance abilities. The presence of QAHs reduced hydrate formation risk than the conventional hydrate inhibitor, PVP, at higher subcooling conditions. The findings indicate that increasing QAHs alkyl chain lengths increase their kinetic hydrate inhibition efficacies due to better surface adsorption abilities. QAHs with longer chain lengths have lesser amounts of solute particles to prevent hydrate formation. The outcomes of this study contribute significantly to current efforts to control gas hydrate formation in offshore petroleum pipelines.