bluuebunny/crossref_metadata_2025 huggingface dataset:
Epoxidation of Methyl Esters as Valuable Biomolecules: Monitoring of Reaction
Authors: Hájek Martin , Hájek Tomáš , Kocián David , Frolich Karel , Peller András
Published: March 2023

The paper is focused on the epoxidation of methyl esters prepared from oil crops with various profiles of higher fatty acids, especially unsaturated, which are mainly contained in the non-edible linseed and Camelina sativa oil (second generation). The novelty consists in the separation and identification of all products with oxirane ring formed through a reaction and in the determination of time course. Through the epoxidation, many intermediates and final products were formed, i.e., epoxides with different number and/or different position of oxirane rings in carbon chain. For the determination, three main methods (infrared spectroscopy, high-pressure liquid chromatography and gas chromatography with mass spectrometry) were applied. Only gas chromatography enables the separation of individual epoxides, which were identified on the base of the mass spectra, molecule ion and time course of products. The determination of intermediates enables: (i) control of the epoxidation process, (ii) determination of the mixture of epoxides in detail and so the calculation of selectivity of each product. Therefore, the epoxidation will be more environmentally friendly especially for advanced applications of non-edible oil crops containing high amounts of unsaturated fatty acids.
Improvement in Corrosion Resistance and Interfacial Contact Resistance Properties of 316L Stainless Steel by Coating with Cr, Ti Co-Doped Amorphous Carbon Films in the Environment of the PEMFCs
Authors: Mi Baosen , Wang Quan , Xu Yuhao , Qin Ziwei , Chen Zhuo , Wang Hongbin
Published: March 2023

In order to obtain films with high corrosion resistance and excellent interfacial contact resistance (ICR) on 316L stainless steel used for bipolar plates in proton-exchange membrane fuel cells (PEMFCs), Cr, Ti co-doped amorphous carbon films were prepared on 316L stainless steel. The preparation method for the coating was magnetron sputtering. The doping amount of the Ti element was controlled by a Cr target and a Ti target current. The change in the structure and properties of the coating after the change from Cr single-element doping to Cr and Ti co-doping was studied. The change rule of the structure and properties of the coating from Cr single-element doping to Cr and Ti co-doping was studied. An increase in the Ti content led to a decreased grain boundary, a flatter surface, and a higher sp2-hybridized carbon content. TiC and CrC nanocrystals were formed in the amorphous carbon structure together. The amorphous carbon films doped with Cr and Ti simultaneously achieved a low ICR and high corrosion resistance compared with single-Cr-doped amorphous carbon. The enhanced corrosion resistance was attributed to the decreasing grain boundary, the formation of the TiC crystal structure, and the smaller grain size. The best performance was obtained at a Ti target current of 2A. Compared with bare 316L stainless steel, the corrosion resistance of Cr, Ti co-doped amorphous carbon (Icorr = 5.7 × 10−8 A/cm2, Ti-2 sample) was greatly improved. Because Ti doping increased the content of sp2-hybridized carbon in the coating, the contact resistance of the coating decreased. Moreover, the interfacial contact resistance was 3.1 mΩ·cm2 in the Ti-2 sample, much lower than that of bare 316L stainless steel. After the potentiostatic polarization test, the coating still had excellent conductivity.
Five New Cantharidin Derivatives from the Insect Mylabris cichorii L. and Their Potential against Kidney Fibrosis In Vitro
Authors: Li Ke-Ming , Li Ji-Jun , Wan Li , Cheng Yong-Xian
Published: March 2023

Five new monoterpenoids including three 1-hydroxymethyl-2-methyl cantharimide-type derivatives (1, 2, and 5) and two 1,2-dimethyl cantharimide-type derivatives (3 and 4), together with three known compounds (6–8) were isolated from the insect Mylabris cichorii Linnaeus. The structures of these new compounds, including their absolute configurations, were characterized by detailed analysis of NMR, chemical derivatization, and quantum chemical ECD calculations. All of the compounds were tested for their biological activity against kidney fibrosis. The results revealed that compounds 2, 4, and 7 could inhibit kidney fibrosis in vitro at 40 μM by inhibiting the expression of fibronectin and collagen I in TGF-β1-induced NRK-52e cells.
Correlation between Magnetic and Dielectric Response of CoFe2O4:Li1+/Zn2+ Nanopowders Having Improved Structural and Morphological Properties
Authors: Afzia Mahwish , Khan Rafaqat Ali , Ismail Bushra , Zaki Magdi E. A. , Althagafi Talal M. , Alanazi Abdulaziz A. , Khan Afaq Ullah
Published: March 2023

The vast applicability of spinel cobalt ferrite due to its unique characteristics implies the need for further exploration of its properties. In this regard, structural modification at the O-site of spinel with Li1+/Zn2+ was studied in detail for exploration of the correlation between structural, magnetic, and dielectric properties of the doped derivatives. The CTAB-assisted coprecipitation method was adopted for the synthesis of the desired compositions owing to its cost effectiveness and size controlling ability. Redistribution of cations at T- and O-sites resulted in the expansion of the crystal lattice, but no distortion of the cubic structure was observed, which further supports the flexible crystal structure of spinel for accommodating larger Li1+/Zn2+ cations. Moreover, an XPS analysis confirmed the co-existence of the most stable oxidation states of Zn2+, Li1+, Co2+, and Fe3+ ions with unstable Co3+ and Fe2+ ions as well, which induces the probability of hopping mechanisms to a certain extent and is a well-established behavior of cobalt ferrite nanoparticles. The experimental results showed that Li1+/Zn2+ co-doped samples exhibit the best magnetic properties at dopant concentration x = 0.3. However, increasing the dopant content causes disturbance at both sites, resulting in decreasing magnetic parameters. It is quite evident from the results that dielectric parameters are closely associated with each other. Therefore, dopant content at x = 0.1 is considered the threshold value exhibiting the highest dielectric parameters, whereas any further increase would result in decreasing the dielectric parameters. The reduced dielectric properties and enhanced magnetic properties make the investigated samples a potential candidate for magnetic recording devices.
Bioactive Properties of Kakadu Plum-Blended Products
Authors: Zhou Yuntao , Phan Anh Dao Thi , Akter Saleha , Bobasa Eshetu Mulisa , Seididamyeh Maral , Sivakumar Dharini , Sultanbawa Yasmina
Published: March 2023

Kakadu plum (Terminalia ferdinandiana), endemic to Australia, is growing in popularity due to its high levels of vitamin C and strong antioxidant properties. In this study, Kakadu plum fruit powder was used as a functional food ingredient with other plant materials to develop value-added products to enhance their nutritional and commercial value. The present study determined the bioactive properties of nine products, including three Kakadu plum fruit powder samples produced from different processing batches and five Kakadu plum-blended products. Vitamin C, the total phenolic content, and the ellagic acid content were determined. Bioactive properties such as antioxidant, antidiabetic, and antimicrobial assays were also performed. Cytotoxicity was tested to obtain more specific product information regarding food safety. Kakadu plum-blended products showed lower cytotoxicity and lower bioactive properties (antioxidant and antibacterial activities) in comparison to Kakadu plum powder. However, overall, most of the bioactive properties were shown to be higher in the blends when compared with the commercial blueberry powder as a benchmark antioxidant product. Therefore, there is great potential for Kakadu plum to contribute to the growing functional food and ingredient markets.
Effect of Nano Nd2O3 on the Microstructure and High-Temperature Resistance of G@Ni Laser Alloying Coatings on Ti-6Al-4V Alloy
Authors: Wang Zifan , Meng Xiaoxi , Zhao Zhihuan , Chen Chuanzhong , Yu Huijun
Published: March 2023

Titanium and its alloys are widely used in high-end manufacturing fields. However, their low high-temperature oxidation resistance has limited their further application. Recently, laser alloying processing has attracted researchers to improve the surface properties of Ti, for which Ni coated graphite system is an excellent prospect due to its outstanding properties and metallurgical bonding between coating and substrate. In this paper, nanoscaled rare earth oxide Nd2O3 addition was added to Ni coated graphite laser alloying materials to research its influence on the microstructure and high-temperature oxidation resistance of the coating. The results proved that nano-Nd2O3 has an outstanding effect on refining coating microstructures, thus the high-temperature oxidation resistance was improved. Furthermore, with the addition of 1. 5 wt.% nano-Nd2O3, more NiO formed in the oxide film, which effectively strengthened the protective effect of the film. After 100 h of 800 °C oxidation, the oxidation weight gain per unit area of the normal coating was 14.571 mg/cm2, while that of the coating with nano-Nd2O3 addition was 6.244 mg/cm2, further proving that the addition of nano-Nd2O3 substantially improved the high-temperature oxidation properties of the coating.
Can Superhydrophobic PET Surfaces Prevent Bacterial Adhesion?
Authors: Caykara Tugce , Fernandes Sara , Braga Adelaide , Rodrigues Joana , Rodrigues Ligia R. , Silva Carla Joana
Published: March 2023

Prevention of bacterial adhesion is a way to reduce and/or avoid biofilm formation, thus restraining its associated infections. The development of repellent anti-adhesive surfaces, such as superhydrophobic surfaces, can be a strategy to avoid bacterial adhesion. In this study, a polyethylene terephthalate (PET) film was modified by in situ growth of silica nanoparticles (NPs) to create a rough surface. The surface was further modified with fluorinated carbon chains to increase its hydrophobicity. The modified PET surfaces presented a pronounced superhydrophobic character, showing a water contact angle of 156° and a roughness of 104 nm (a considerable increase comparing with the 69° and 4.8 nm obtained for the untreated PET). Scanning Electron Microscopy was used to evaluate the modified surfaces morphology, further confirming its successful modification with nanoparticles. Additionally, a bacterial adhesion assay using an Escherichia coli expressing YadA, an adhesive protein from Yersinia so-called Yersinia adhesin A, was used to assess the anti-adhesive potential of the modified PET. Contrarily to what was expected, adhesion of E. coli YadA was found to increase on the modified PET surfaces, exhibiting a clear preference for the crevices. This study highlights the role of material micro topography as an important attribute when considering bacterial adhesion.
Fine Structure Splitting of Phonon-Assisted Excitonic Transition in (PEA)2PbI4 Two-Dimensional Perovskites
Authors: Posmyk Katarzyna , Dyksik Mateusz , Surrente Alessandro , Zalewska Katarzyna , Śmiertka Maciej , Cybula Ewelina , Paritmongkol Watcharaphol , Tisdale William A. , Plochocka Paulina , Baranowski Michał
Published: March 2023

Two-dimensional van der Waals materials exhibit particularly strong excitonic effects, which causes them to be an exceptionally interesting platform for the investigation of exciton physics. A notable example is the two-dimensional Ruddlesden–Popper perovskites, where quantum and dielectric confinement together with soft, polar, and low symmetry lattice create a unique background for electron and hole interaction. Here, with the use of polarization-resolved optical spectroscopy, we have demonstrated that the simultaneous presence of tightly bound excitons, together with strong exciton–phonon coupling, allows for observing the exciton fine structure splitting of the phonon-assisted transitions of two-dimensional perovskite (PEA)2PbI4, where PEA stands for phenylethylammonium. We demonstrate that the phonon-assisted sidebands characteristic for (PEA)2PbI4 are split and linearly polarized, mimicking the characteristics of the corresponding zero-phonon lines. Interestingly, the splitting of differently polarized phonon-assisted transitions can be different from that of the zero-phonon lines. We attribute this effect to the selective coupling of linearly polarized exciton states to non-degenerate phonon modes of different symmetries resulting from the low symmetry of (PEA)2PbI4 lattice.
Association between the Inflammatory Potential of the Diet and Biological Aging: A Cross-Sectional Analysis of 4510 Adults from the Moli-Sani Study Cohort
Authors: Martínez Claudia F. , Esposito Simona , Di Castelnuovo Augusto , Costanzo Simona , Ruggiero Emilia , De Curtis Amalia , Persichillo Mariarosaria , Hébert James R. , Cerletti Chiara , Donati Maria Benedetta , de Gaetano Giovanni , Iacoviello Licia , Gialluisi Alessandro , Bonaccio Marialaura
Published: March 2023

Chronological age (CA) may not accurately reflect the health status of an individual. Rather, biological age (BA) or hypothetical underlying “functional” age has been proposed as a relevant indicator of healthy aging. Observational studies have found that decelerated biological aging or Δage (BA-CA) is associated with a lower risk of disease and mortality. In general, CA is associated with low-grade inflammation, a condition linked to the risk of the incidence of disease and overall cause-specific mortality, and is modulated by diet. To address the hypothesis that diet-related inflammation is associated with Δage, a cross-sectional analysis of data from a sub-cohort from the Moli-sani Study (2005–2010, Italy) was performed. The inflammatory potential of the diet was measured using the Energy-adjusted Dietary Inflammatory Index (E-DIITM) and a novel literature-based dietary inflammation score (DIS). A deep neural network approach based on circulating biomarkers was used to compute BA, and the resulting Δage was fit as the dependent variable. In 4510 participants (men 52.0%), the mean of CA (SD) was 55.6 y (±11.6), BA 54.8 y (±8.6), and Δage −0.77 (±7.7). In a multivariable-adjusted analysis, an increase in E-DIITM and DIS scores led to an increase in Δage (β = 0.22; 95%CI 0.05, 0.38; β = 0.27; 95%CI 0.10, 0.44, respectively). We found interaction for DIS by sex and for E-DIITM by BMI. In conclusion, a pro-inflammatory diet is associated with accelerated biological aging, which likely leads to an increased long-term risk of inflammation-related diseases and mortality.
Ellagitannins from Castanea sativa Mill. Leaf Extracts Impair H. pylori Viability and Infection-Induced Inflammation in Human Gastric Epithelial Cells
Authors: Piazza Stefano , Martinelli Giulia , Fumagalli Marco , Pozzoli Carola , Maranta Nicole , Giavarini Flavio , Colombo Luca , Nicotra Giovanna , Vicentini Silvia Francesca , Genova Francesca , De Fabiani Emma , Sangiovanni Enrico , Dell’Agli Mario
Published: March 2023

Helicobacter pylori (H. pylori) is an etiologic factor of peptic ulcer disease and gastric cancer. Virulent strains of H. pylori are correlated with the severity of gastritis, due to NF-κB activation and IL-8 expression at the epithelial level. Ellagitannins have been documented for antibacterial and anti-inflammatory activities, thus suggesting their potential use in gastritis. Recently, several authors, including our group, demonstrated that tannin-rich extracts from chestnut byproducts, at present considered agricultural waste, display promising biological activities. In this work, we detected high levels of polyphenols in hydroalcoholic extracts from chestnut leaves (Castanea sativa L.). Among polyphenols, the ellagitannin isomers castalagin and vescalagin (about 1% w/w of dry extract) were identified as potential bioactive compounds. In GES-1 cells infected by H. pylori, leaf extract and pure ellagitannins inhibited IL-8 release (IC50 ≈ 28 µg/mL and 11 µM, respectively). Mechanistically, the anti-inflammatory activity was partly due to attenuation of NF-κB signaling. Moreover, the extract and pure ellagitannins reduced bacterial growth and cell adhesion. A simulation of the gastric digestion suggested that the bioactivity might be maintained after oral administration. At the transcriptional level, castalagin downregulated genes involved in inflammatory pathways (NF-κB and AP-1) and cell migration (Rho GTPase). To the best of our knowledge, this is the first investigation in which ellagitannins from plant extracts have demonstrated a potential role in the interaction among H. pylori and human gastric epithelium.
Effect of Plant-Based Diets on Gut Microbiota: A Systematic Review of Interventional Studies
Authors: Sidhu Shaneerra Raajlynn Kaur , Kok Chin Wei , Kunasegaran Thubasni , Ramadas Amutha
Published: March 2023

Plant-based diets have grown increasingly popular across the globe, mainly for their health and environmental benefits. Several studies have identified a link between plant-based diets and the decreased risk of developing cardiovascular diseases, obesity, and other health issues. We systematically reviewed human interventions to identify the relationship between various plant-based food items and the gut microbiome, alongside the biochemical and anthropometric measurements as secondary findings. The study selection process was completed using the COVIDENCE platform. Overall, 203 studies were identified, of which 101 were chosen for title and abstract screening by two independent authors. Following this process, 78 studies were excluded, and the full texts and the reference lists of the remaining 23 records were reviewed using the review eligibility criteria. A manual search yielded five additional articles. In the end, 12 studies were included in the systematic review. We found evidence for short- to moderate-term beneficial effects of plant-based diets versus conventional diets (duration ≤ 13 months) on gut microbiome composition and biochemical and anthropometric measurements in healthy participants as well as obese, cardiovascular, and rheumatoid arthritis patients. However, contradictory results were observed for Enterobacteriaceae, at the family level, and for Faecalibacterium and Coprococcus, at the genus level, of gut microbiome composition. The relationship between plant-based diets and the gut microbiome, alongside their underlying metabolic and inflammatory effects, remains largely unexplored. Hence more interventional studies are needed to address these questions.
In Vitro Evaluation of Bioavailability of Se from Daily Food Rations and Dietary Supplements
Authors: Bawiec Piotr , Sawicki Jan , Łasińska-Pracuta Paulina , Czop Marcin , Sowa Ireneusz , Iłowiecka Katarzyna , Koch Wojciech
Published: March 2023

Bioavailability refers to a fraction of a substance that is potentially absorbed from the gastrointestinal tract and enters the systemic circulation (blood). This term is related to various substances, including minerals, that are present in a complex matrix of food which is consumed every day as natural products and pharmaceutical preparations, e.g., dietary supplements. The purpose of the study was to assess the bioavailability of Se from selected dietary supplements, with the simultaneous assessment of the effect the diet type (standard, basic and high-residue diets) has on relative bioavailability. The research included a two-stage in vitro model of digestion using cellulose dialysis tubes of the food rations with the addition of dietary supplements. Se was determined using the ICP-OES method. The bioavailability of Se from dietary supplements, in the presence of food matrix, was determined to be within the range of 19.31–66.10%. Sodium selenate was characterized by the highest value of this parameter, followed by organic forms and sodium selenite. The basic diet, characterized by moderate protein and high carbohydrate and fiber contents, positively influenced the bioavailability of Se. The bioavailability of Se was also influenced by the pharmaceutical form of the product—the highest was for tablets, followed by capsules and coated tablets.
Dietary Folate Deficiency Promotes Lactate Metabolic Disorders to Sensitize Lung Cancer Metastasis through MTOR-Signaling-Mediated Druggable Oncotargets
Authors: Chen Wan-Jing , Huang Su-Yu , Chen Yi-Wen , Liu Yi-Fang , Huang Rwei-Fen S.
Published: March 2023

Lactate metabolism plays a pivotal role in cancers but is often overlooked in lung cancer (LC). Folate deficiency has been linked to lung cancer development, but its impact on lactate metabolism and cancer malignancy is unclear. To investigate this, mice were fed either a folate-deficient (FD) or control diet and intrapleurally implanted with lung cancer cells pre-exposed to FD growth medium. Results showed that FD promoted lactate over-production and the formation of tumor oncospheroids (LCSs) with increased metastatic, migration, and invasion potential. Mice implanted with these cells and fed an FD diet developed hyperlactatemia in blood and lungs. This coincided with increased expression of hexokinase 2 (HK2), lactate dehydrogenase (LDH), and decreased expression of pyruvate dehydrogenase (PDH). Pre-treatment of the FD-LCS-implanted mice with the mTORC1 inhibitor, rapamycin, and the anti-metabolic drug metformin abolished FD/LCS-activated mTORC1 and its targets including HIF1α, HK2, LDH, and monocarboxylate transporters (MCT1 and MCT4), which coincided with the reduction in lactate disorders and prevention of LC metastasis. The findings suggest that dietary FD promotes lactate metabolic disorders that sensitize lung cancer metastasis through mTOR-signaling-mediated targets.
Interactive Effect of Irrigation Volume and Planting Density on Growth and Salt Uptake in Field-Grown Drip-Irrigated Suaeda salsa (L.) Pall.
Authors: Xu Qiang , Liu Hongguang , Li Mingsi , Li Pengfei
Published: March 2023

Planting halophytes such as Suaeda salsa (L.) Pall. under drip irrigation is a viable solution for the remediation of saline soils. We conducted this study to investigate the effects of different irrigation volumes and planting densities on the growth and salt uptake of Suaeda salsa under drip irrigation. The plant was cultivated in a field using drip irrigation at various irrigation volumes (3000 m·hm−2 (W1), 3750 m·hm−2 (W2), and 4500 m·hm−2 (W3)) and planting densities (30 plants·m−2 (D1), 40 plants·m−2 (D2), 50 plants·m−2 (D3), and 60 plants·m−2 (D4)) to examine the effects on growth and salt uptake. The study revealed that the amount of irrigation, planting density, and interaction between the two significantly affected the growth characteristics of Suaeda salsa. The plant height, stem diameter, and canopy width increased simultaneously with an increase in the irrigation volume. However, with an increasing planting density and the same irrigation volume, the plant height first increased and then decreased, while the stem diameter and canopy width decreased simultaneously. The biomass of D1 was the highest with the W1 irrigation, while that of D2 and D3 were highest with the W2 and W3 irrigations. The amount of irrigation, planting density, and their interaction significantly affected the ability of Suaeda salsa to absorb salt. The salt uptake increased initially and then decreased with an increasing irrigation volume. At the same planting density, the salt uptake of Suaeda salsa with the W2 treatment was 5.67~23.76% and 6.40~27.10% higher than that with W1 and W3, respectively. Using the multiobjective spatial optimization method, the scientific and reasonable irrigation volume for planting Suaeda salsa in arid areas was determined to be 3276.78~3561.32 m3·hm−2, and the corresponding planting density was 34.29~43.27 plants·m−2. These data can be a theoretical basis for planting Suaeda salsa under drip irrigation to improve saline–alkali soils.
Monitoring Drought Stress in Common Bean Using Chlorophyll Fluorescence and Multispectral Imaging
Authors: Javornik Tomislav , Carović-Stanko Klaudija , Gunjača Jerko , Vidak Monika , Lazarević Boris
Published: March 2023

Drought is a significant constraint in bean production. In this study, we used high-throughput phenotyping methods (chlorophyll fluorescence imaging, multispectral imaging, 3D multispectral scanning) to monitor the development of drought-induced morphological and physiological symptoms at an early stage of development of the common bean. This study aimed to select the plant phenotypic traits which were most sensitive to drought. Plants were grown in an irrigated control (C) and under three drought treatments: D70, D50, and D30 (irrigated with 70, 50, and 30 mL distilled water, respectively). Measurements were performed on five consecutive days, starting on the first day after the onset of treatments (1 DAT–5 DAT), with an additional measurement taken on the eighth day (8 DAT) after the onset of treatments. Earliest detected changes were found at 3 DAT when compared to the control. D30 caused a decrease in leaf area index (of 40%), total leaf area (28%), reflectance in specific green (13%), saturation (9%), and green leaf index (9%), and an increase in the anthocyanin index (23%) and reflectance in blue (7%). The selected phenotypic traits could be used to monitor drought stress and to screen for tolerant genotypes in breeding programs.
Kinetics of Microwave-Assisted Extraction Process Applied on Recovery of Peppermint Polyphenols: Experiments and Modeling
Authors: Pavlić Branimir , Kaplan Muammer , Zeković Zoran , Canli Oltan , Jovičić Nebojša , Bursać Kovačević Danijela , Bebek Markovinović Anica , Putnik Predrag , Bera Oskar
Published: March 2023

The aim of this work was to investigate the microwave-assisted extraction (MAE) kinetics of polyphenolic compounds from organic peppermint leaves. The phytochemicals of peppermint (Mentha piperita L.) are increasingly used in food technology due to their numerous biological activities. The processing of various plant materials by MAE and the production of high-quality extracts is becoming increasingly important. Therefore, the influence of microwave irradiation power (90, 180, 360, 600, and 800 W) on total extraction yield (Y), total polyphenols yield (TP), and flavonoid yield (TF) were investigated. Common empirical models (first-order, Peleg’s hyperbolic, Elovich’s logarithmic, and power-law model) were applied to the extraction process. The first-order kinetics model provided the best agreement with the experimental results in terms of statistical parameters (SSer, R2, and AARD). Therefore, the influences of irradiation power on the adjustable model parameters (k and Ceq) were investigated. It was found that irradiation power exerted a significant influence on k, while its influence on the asymptotic value of the response was negligible. The highest experimentally determined k (2.28 min−1) was obtained at an irradiation power of 600 W, while the optimal irradiation power determined by the maximum fitting curve determination predicted the highest k (2.36 min−1) at 665 W.
The Effects of Particle Size Distribution and Moisture Variation on Mechanical Strength of Biopolymer-Treated Soil
Authors: Fatehi Hadi , Ong Dominic E. L. , Yu Jimmy , Chang Ilhan
Published: March 2023

Biopolymers have recently shown great potential to replace traditional binding materials in geotechnical engineering; however, more research is required to reach a deeper understanding of biopolymer-treated soil behavior. The objective of this study was to investigate the most important parameters that affect the behavior of biopolymer-treated soil, including biopolymer content, dehydration time, soil type effect, and durability. Sodium alginate and agar biopolymers were used due to their stability under severe conditions and the reasonable costs to study these parameters. A broad range of soil particle sizes was used to optimize the kaolinite-sand combination. As one of the main concerns in the behavior of biotreated soils, durability was investigated under five cycles of wetting and drying. In addition, a comprehensive microstructural study was performed by FTIR analysis and SEM images, as well as chemical interaction analysis. The results indicated that the optimized biopolymer content was in the range of 0.5–1% (to soil weight) and the dehydration time was 14 days. A soil combination of 25% kaolinite and 75% sand provided the highest compressive strength. Under wetting and drying conditions, biopolymers significantly increased soil resistance against strength reduction and soil mass loss. This study provides an understanding how agar and sodium alginate changes the behavior of the soil and can be used as a reference for further studies in the future.
Effect of UV-C Irradiation and High Hydrostatic Pressure on Microbiological, Chemical, Physical and Sensory Properties of Fresh-Cut Potatoes
Authors: Pelaić Zdenka , Čošić Zrinka , Repajić Maja , Dujmić Filip , Balbino Sandra , Levaj Branka
Published: March 2023

UV-C irradiation and high hydrostatic pressure (HHP) successfully reduce the number of bacteria and their growth but can also affect phenolic and sugar content, as well as other physicochemical properties. Therefore, in this work, the effect of UV-C irradiation, HHP, and their combination, UV-C/HHP, on total aerobic mesophilic bacteria count (TAMBC), chlorogenic acid and sugar content, and other physicochemical properties of raw FCP were examined. Acrylamide and polycyclic aromatic hydrocarbons (PAH) were also monitored in treated FCP after frying. Vacuum-packed potato slices pretreated with an antibrowning agent were irradiated with UV-C (2.70 kJ m−2), treated with HHP (400 MPa/3 min) and combined UV-C/HHP, and stored for 15 days. The greatest reduction in TAMBC was achieved in the UV-C/HHP-treated samples, followed by the HHP treatment, and they both resulted in the slowest bacterial growth during storage. All treatments decreased the contents of chlorogenic acid, but the greatest reduction was observed in the HHP-treated samples. All treatments increased the content of reducing sugars, and UV-C/HHP did so significantly, which also led to an increase in acrylamide content in the fried FCP. PAH levels were below the established limits. Acceptable sensory attributes of all samples (raw, boiled, and fried) remained relatively stable during storage.
Secularization in Europe: Causes, Consequences, and Cultural Diversity
Authors: Moniz Jorge Botelho
Published: March 2023

This paper explores the timeliness and relevance of secularization theories in Europe. It seeks to understand how the classical theories of secularization—rationalization, societalization, functional differentiation, and existential security—and their theoretical innovations—namely, cultural diversity—help describe religious phenomena in a specific set of European countries—Austria, Italy, Poland, Portugal, Slovakia, and Spain. In this context, cultural diversity shows the strongest negative correlation with religiosity. These findings arise from the correlation between the different theories of secularization, the independent variables, and an index of religiosity, the dependent variable. Cultural diversity, as a good predictor to explain secularization in Europe, shows how contact with different religious and non-religious worldviews enhances a mutual fragilization that can lead individuals from uncertainty to the rejection of religious beliefs.
A Multicriteria Analysis to Support Natural Resource Governance: The Case of Chestnut Forests
Authors: Bruzzese Stefano , Blanc Simone , Novelli Silvia , Brun Filippo
Published: March 2023

Efficient natural resource management prevents and reduces negative impacts, such as environmental damage, misappropriation of resources, and conflicts; several strategies can be leveraged to conserve, protect, and enhance natural resources. Multicriteria decision analysis (MCDA) is useful in providing solutions to addressing decision choice problems. In this study, the natural resource under evaluation is the chestnut forest, with the objective of valorising its supply chains. The methodology applied is A’WOT, which allows previously identified factors, using a qualitative SWOT matrix, to be ordered through an objective quantification using the AHP (analytic hierarchy process), which is a multicriteria decision support method. The survey was conducted with a group of chestnut resource (n = 20) experts. The SWOT matrix identified a total of 20 factors: 6 strengths and 6 weaknesses and 4 factors each for opportunities and threats. The results express a clear stakeholder interest, which identifies the significant role of civil society in directing management choices for the provision and enhancement of ecosystem and vocational services. This study evaluated the adaptability of decision support tools applied to a real case of forest resource management to identify and order factors useful to enhance the resource and stimulate the supply chains to achieve greater added value. In a general sense, the methodological potential emerged to replicate or improve the research in other geographical regions, whether regional or extraregional, or even on a larger scale, such as on a national level.
Stability and Changes in the Spatial Distribution of China’s Population in the Past 30 Years Based on Census Data Spatialization
Authors: Xu Xiaofan , Tan Minghong , Liu Xiaoyu , Wang Xue , Xin Liangjie
Published: March 2023

As the world’s most populous country, China has experienced massive population growth and dramatic regional migration over the past 30 years. From 1990 to 2020, the national population increased by 24.4%, the urban population tripled, and the rural population declined by 41.0%. Combined with complex topographic features, unique characteristics of the population distribution have emerged. Many studies have examined changes in the spatial distribution of the population. However, few studies have examined the stability of certain aspects of this distribution over the last 30 years, particularly at the raster scale, which may provide important information for future research and development plans. Based on land use maps and nighttime light images, China’s census data from 1990 to 2020 was scaled down to a resolution of 1 km using a method called multiple linear regression based on spatial covariates. The results show that there were some striking features of both stability and change in the spatial distribution of China’s population over the past three decades. The population shares divided by the Hu line, the Qinling-Huaihe line, and the three-step staircase have remained almost unchanged. In contrast, the population share of the coastal region has risen from 23.7% to 29.0% during the study period. The urban areas have expanded by 1.35 times and their population has doubled. In addition, for every 1 km2 increase in the urban areas, an area of 29.4 km2 has been depopulated on average. This suggests that urbanization can alleviate population pressure in larger areas. However, the coastal regions and urban and peri-urban areas were the main areas of population density growth, so they required a great deal of attention for ecological protection.
A Machine Learning Approach to Derive Aerosol Properties from All-Sky Camera Imagery
Authors: Scarlatti Francesco , Gómez-Amo José L. , Valdelomar Pedro C. , Estellés Víctor , Utrillas María Pilar
Published: March 2023

We propose a methodology to derive the aerosol optical depth (AOD) and Angstrom exponent (AE) from calibrated images of an all-sky camera. It is based on a machine learning (ML) approach that establishes a relationship between AERONET measurements of AOD and AE and different signals derived from the principal plane radiance measured by an all-sky camera at three RGB channels. Gaussian process regression (GPR) has been chosen as machine learning method and applied to four models that differ in the input choice: RGB individual signals to predict spectral AOD; red signal only to predict spectral AOD and AE; blue-to-red ratio (BRR) signals to predict spectral AOD and AE; red signals to predict spectral AOD and AE at once. The novelty of our approach mostly relies on obtaining a cloud-screened and smoothed signal that enhances the aerosol features contained in the principal plane radiance and can be applied in partially cloudy conditions. In addition, a quality assurance criterion for the prediction has been also suggested, which significantly improves our results. When applied, our results are very satisfactory for all the models and almost all predictions are close to real values within ±0.02 for AOD and ±0.2 for AE, whereas the MAE is less than 0.005. They show an excellent agreement with AERONET measurements, with correlation coefficients over 0.92. Moreover, more than 87% of our predictions lie within the AERONET uncertainties (±0.01 for AOD, ±0.1 for AE) for all the output parameters of the best model. All the models offer a high degree of numerical stability with negligible sensitivities to the training data, atmospheric conditions and instrumental issues. All this supports the strength and efficiency of our models and the potential of our predictions. The optimum performance shown by our proposed methodology indicates that a well-calibrated all-sky camera can be routinely used to accurately derive aerosol properties. Together, all this makes the all-sky cameras ideal for aerosol research and this work may represent a significant contribution to the aerosol monitoring.
Investigating Drought and Flood Evolution Based on Remote Sensing Data Products over the Punjab Region in Pakistan
Authors: Ullah Rahat , Khan Jahangir , Ullah Irfan , Khan Faheem , Lee Youngmoon
Published: March 2023

Over the last five decades, Pakistan experienced its worst drought from 1998 to 2002 and its worst flood in 2010. This study determined the record-breaking impacts of the droughts (1998–2002) and the flood (2010) and analyzed the given 12-year period, especially the follow-on period when the winter wheat crop was grown. We identified the drought, flood, and warm and cold edges over the plain of Punjab Pakistan based on a 12-year time series (2003–2014), using the vegetation temperature condition index (VTCI) approach based on Aqua Moderate Resolution Imaging Spectroradiometer (MODIS) data products. During the year 2010, the Global Flood Monitoring System (GFMS) model applied to the real-time Tropical Rainfall Measuring Mission (TRMM) rainfall incorporated data products into the TRMM Multi-Satellite Precipitation Analysis (TMPA) for the flood detection/intensity, stream flow, and daily accumulative precipitation, and presented the plain provisions to wetlands. This study exhibits drought severity, warm and cold edges, and flood levels using the VTCI drought-monitoring approach, which utilizes a combination of the normalized difference vegetation index (NDVI) with land surface temperature (LST) data products. It was found that during the years 2003–2014, the VTCI had a positive correlation coefficient (r) with the cumulative precipitation (r = 0.60) on the day of the year (D-073) in the winter. In the year 2010, at D-201, there was no proportionality (nonlinear), and at D-217, a negative correlation was established. This revealed the time, duration, and intensity of the flood at D-201 and D-217, and described the heavy rainfall, stream flow, and flood events. At D-233 and D-281 during 2010, a significant positive correlation was noticed in normal conditions (r = 0.95 in D-233 and r = 0.97 in D-281 during the fall of 2010), which showed the flood events and normality. Notably, our results suggest that VTCI can be used for drought and wet conditions in both rain-fed and irrigated regions. The results are consistent with anomalies in the GFMS model using the spatial and temporal observations of the MODIS, TRMM, and TMPA satellites, which describe the dry and wet conditions, as well as flood runoff stream flow and flood detection/intensity, in the region of Punjab during 2010. It should be noted that the flood (2010) affected the area, and the production of the winter wheat crop has consistently declined from 19.041 to 17.7389 million tons.
Shallow Water Object Detection, Classification, and Localization via Phase-Measured, Bathymetry-Mode Backscatter
Authors: McCormack Bryan , Borrelli Mark
Published: March 2023

Detection, classification, and localization (DCL) techniques are being developed around the use of a phase-measuring sidescan sonar (PMSS) in very shallow waters. The instrument simultaneously collects co-located sidescan imagery and bathymetry in extreme shallow water environments (<1 m water depth). In addition to the bathymetry, an uncalibrated backscatter data set, referred to in this study as phase-measured, bathymetry-mode backscatter (BMB), is also collected. This BMB has been minimally addressed in the literature. This work aims to use the BMB to detect and differentiate between various objects on the seafloor, including unexploded ordnance (UXO), and placed marine debris, or ‘clutter’, such as lobster pots, boat propellers, and car tires. The differentiation from multiple seafloor types including mud, sand, and gravel and different types of objects occurred through various statistical analysis methods including binomial and multinomial logistic regression. These methods have been applied to create statistical regression models for several variables including phase-measured, bathymetry-mode backscatter amplitude, sounding distance from nadir, per-ping vessel roll, orientation offset between per-ping vessel heading and object orientation, and all combinations of these variables. These statistical tests produced maximum likelihood odds ratios of individual soundings being associated with the various seafloor and object types. Results from these analyses shows that DCL could be possible with phase-measured, bathymetry-mode backscatter from this PMSS system, though these results may not be representative for all bed types and phase-measuring systems.
The Social Solidarity Economy and the Hull-House Tradition of Social Work: Keys for Unlocking the Potential of Social Work for Sustainable Social Development
Authors: Tadesse Michael Emru , Elsen Susanne
Published: March 2023

Social work (SW) is criticized for its (i) inconsistent ontology, epistemology, and methodology and (ii) co-dependency with the capitalist hegemony, which is the main cause of multiple crises that primarily affect the most vulnerable. Addressing these issues is of paramount importance if SW is to achieve its core mandate of promoting social change, social development, social cohesion, and the empowerment and liberation of people. The purpose of this paper is to assert that SW can address these issues by learning from the (i) Settlement House Movement (SHM), especially the Hull-House tradition of SW; and (ii) current endeavors of the Social Solidarity Economy (SSE). We were led to this assertion because we noticed in our research, in the area of SSE of vulnerable groups and SW, remarkable similarities and potentials of these two approaches to help transform SW. Our argument is based on data and insight gained from (i) a narrative literature review on the history of SW and the nature of SSE; and (ii) a systematic scoping review of the SSE of People of African Descent (PAD) in Europe. In this paper, we elaborate on our key arguments and provide examples and recommendations.
Assessing COVID-19 Vaccine Booster Hesitancy Using the Modified 5C Scale in Zhejiang Province, China: A Cross-Sectional Study
Authors: Deng Xuan , Zhao Yuchen , Wang Shenyu , He Hanqing , Chen Zhiping , Zhou Yang , Yan Rui , Tang Xuewen , Zhu Yao , Xu Xiaoping
Published: March 2023

Following the rollout of a booster campaign to promote immunity against COVID-19 in China, this study aimed to assess booster hesitancy among adults who were fully vaccinated with primary doses across Zhejiang Province. Firstly, the modified 5C scale developed by a German research team was assessed for reliability and validity via a pre-survey in Zhejiang Province. Then, a 30-item questionnaire was established to conduct online and offline surveys during 10 November to 15 December 2021. Demographic characteristics and information on previous vaccination experience, vaccine type of primary doses, attitudes towards booster doses and awareness of SARS-CoV-2 infection were collected. Chi-square tests, pairwise comparison and multivariate logistic regression were performed in data analysis. In total, 4039 valid questionnaires were analyzed, with booster hesitancy of 14.81%. Dissatisfaction with previous vaccination experience of primary doses (ORs = 1.771~8.025), less confidence in COVID-19 vaccines (OR = 3.511, 95%CI: 2.874~4.310), younger age compared to the elderly aged 51–60 years old (2.382, 1.274~4.545), lower education level (ORs = 1.707~2.100), weaker awareness of social responsibility of prevention and control of COVID-19 (1.587, 1.353~1.859), inconvenience of booster vaccination (1.539, 1.302~1.821), complacency regarding vaccine efficacy as well as self-health status (1.224, 1.056~1.415) and excessive trade-offs before vaccination (1.184, 1.005~1.398) were positively associated with booster hesitancy. Therefore, intelligent means should be strengthened to optimize vaccination services. More influential experts and other significant figures should be supported to promote timely evidence-based information via various media platforms to reduce public hesitancy and increase booster uptake.
Is It Feasible to Preserve a Self-Sustaining Population of Yangtze Finless Porpoise in the Highest Density Section of Yangtze River?
Authors: Wang Weiping , Wang Chongrui , Yu Jinxiang , Wu Bin
Published: March 2023

Using the VORTEX v. 10. 5.0.0, population viability analysis (PVA) was performed for Yangtze finless porpoise (YFP, Neophocaena asiaeorientalis) in the highest density section between Hukou and Meilong section (HMS) of the Yangtze River. Baseline model showed that this population was in a relatively vulnerability state; the deterministic growth rate (Det-r) was −0.0230; the stochastic growth rate (Stoch-r) was −0.0385; the probability of extinction (PE) was 0.5690; the mean population size of extant populations (N-extant) was 22; the genetic diversity (GD) was 0.7698. Under the general protection model, the Det-r was 0.0015, and the Stoch-r was −0.0092; Under the medium protection model, the Det-r was 0.0219, and the Stoch-r was 0.0144; Under the optimal protection model, the Det-r was 0.0383, and the Stoch-r was 0.0357. Sensitivity analysis found that adult females breeding rate, sex ratio at birth, and mortality rate of juvenile YFP were sensitive to maintaining population stability. The PVA showed that the conservation of YFP population in HMS depends on: neutralization of all threats affecting YFP population in the HMS; maintenance and, whenever possible, enhancement of the functional connectivity of the waterbody, increasing the food resources of YFP and reducing the risk of injury to YFP caused by human.