bluuebunny/crossref_metadata_2025 huggingface dataset:
Supersaturation and Solubilization upon In Vitro Digestion of Fenofibrate Type I Lipid Formulations: Effect of Droplet Size, Surfactant Concentration and Lipid Type
Authors: Katev Vladimir , Tsibranska-Gyoreva Sonya , Vinarov Zahari , Tcholakova Slavka
Published: August 2021

Lipid-based formulations (LBF) enhance oral drug absorption by promoting drug solubilization and supersaturation. The aim of the study was to determine the effect of the lipid carrier type, drop size and surfactant concentration on the rate of fenofibrate release in a bicarbonate-based in vitro digestion model. The effect of the lipid carrier was studied by preparing type I LBF with drop size ≈ 2 µm, based on medium-chain triglycerides (MCT), sunflower oil (SFO), coconut oil (CNO) and cocoa butter (CB). The drop size and surfactant concentration effects were assessed by studying MCT and SFO-based formulations with a drop size between 400 nm and 14 µm and surfactant concentrations of 1 or 10%. A filtration through a 200 nm filter followed by HPLC analysis was used to determine the aqueous fenofibrate, whereas lipid digestion was followed by gas chromatography. Shorter-chain triglycerides were key in promoting a faster drug release. The fenofibrate release from long-chain triglyceride formulations (SFO, CNO and CB) was governed by solubilization and was enhanced at a smaller droplet size and higher surfactant concentration. In contrast, supersaturation was observed after the digestion of MCT emulsions. In this case, a smaller drop size and higher surfactant had negative effects: lower peak fenofibrate concentrations and a faster onset of precipitation were observed. The study provides new mechanistic insights on drug solubilization and supersaturation after LBF digestion, and may support the development of new in silico prediction models.
Point Mutations and Cytochrome P450 Can Contribute to Resistance to ACCase-Inhibiting Herbicides in Three Phalaris Species
Authors: Vázquez-García José G. , Torra Joel , Palma-Bautista Candelario , Alcántara-de la Cruz Ricardo , Prado Rafael De
Published: August 2021

Species of Phalaris have historically been controlled by acetyl-coenzyme A carboxylase (ACCase)-inhibiting herbicides; however, overreliance on herbicides with this mechanism of action has resulted in the selection of resistant biotypes. The resistance to ACCase-inhibiting herbicides was characterized in Phalaris brachystachys, Phalaris minor, and Phalaris paradoxa samples collected from winter wheat fields in northern Iran. Three resistant (R) biotypes, one of each Phalaris species, presented high cross-resistance levels to diclofop-methyl, cycloxydim, and pinoxaden, which belong to the chemical families of aryloxyphenoxypropionates (FOPs), cyclohexanediones (DIMs), and phenylpyrazolines (DENs), respectively. The metabolism of 14C-diclofop-methyl contributed to the resistance of the P. brachystachys R biotype, while no evidence of herbicide metabolism was found in P. minor or P. paradoxa. ACCase in vitro assays showed that the target sites were very sensitive to FOP, DIM, and DEN herbicides in the S biotypes of the three species, while the R Phalaris spp. biotypes presented different levels of resistance to these herbicides. ACCase gene sequencing confirmed that cross-resistance in Phalaris species was conferred by specific point mutations. Resistance in the P. brachystachys R biotype was due to target site and non-target-site resistance mechanisms, while in P. minor and P. paradoxa, only an altered target site was found.
Healing Efficiency of CNTs-Modified-UF Microcapsules That Provide Higher Electrical Conductivity and EMI Shielding Properties
Authors: Kosarli Maria , Polymerou Anastasia , Foteinidis Georgios , Vazouras Christos , Paipetis Alkiviadis
Published: August 2021

In this study, the effect of the addition of multi-walled carbon nanotubes (MWCNTs), at three percentages, into the urea-formaldehyde (UF) shell-wall of microcapsules on the healing efficiency is reported. The modified shell-wall created a conductive network in semi-conductive epoxies, which led to an improvement of the electromagnetic interference shielding effectiveness (EMI SE); utilizing the excellent electrical properties of the CNTs. The microcapsule’s mean diameter and shell wall were examined via scanning electron microscopy (SEM). Thermal stability was evaluated via thermogravimetric analysis (TGA). The healing efficiency was assessed in terms of fracture toughness, while the electrical properties were measured using impedance spectroscopy. The measurements of the EMI SE were carried out in the frequency range of 7–9 GHz. The derived results indicated that the incorporation of the CNTs resulted in a decrease in the mean size of the microcapsules, while the thermal stability remained unchanged. In particular, the introduction of 0.5% w/v CNTs did not affect the healing efficiency, while it increased the initial mechanical properties of the epoxy after the incorporation of the self-healing system by 27%. At the same time, it led to the formation of a conductive network, providing electrical conductivity to the epoxies. The experimental results showed that the SE increased on average 5 dB or more after introducing conductive microcapsules.
Research on Quality Characterization Method of Micro-Injection Products Based on Cavity Pressure
Authors: Wang Quan , Zhao Xiaomei , Zhang Jianpeng , Zhang Ping , Wang Xinwei , Yang Chaofeng , Wang Jinrong , Wu Zhenghuan
Published: August 2021

The cavity pressure in the injection molding process is closely related to the quality of the molded products, and is used for process monitoring and control, to upgrade the quality of the molded products. The experimental platform was built to carry out the cavity pressure experiment with a micro spline injection mold in the paper. The process parameters were changed, such as V/P switchover, mold temperature, melt temperature, packing pressure, and injection rate, in order to analyze the influence of the process parameters on the product weight. The peak cavity pressure and area under the pressure curve were the two attributes utilized in investigating the correlation between cavity pressure and part weight. The experimental results show that the later switchover allowed the injection to proceed longer and produce a heavier tensile specimen. By comparing different cavity pressure curves, the general shapes of the curves were able to indicate different types of shortage produced. When the V/P switchover position is 10 mm, the coefficient of determination (R2 value) of part weight, for the peak cavity pressure and area under the curve, were 0.7706 and 0.8565, respectively. This showed that the area under the curve appeared to be a better process and quality indicator than the peak cavity pressure.
Fully Recyclable Bio-Based Epoxy Formulations Using Epoxidized Precursors from Waste Flour: Thermal and Mechanical Characterization
Authors: Ferrari Francesca , Esposito Corcione Carola , Striani Raffaella , Saitta Lorena , Cicala Gianluca , Greco Antonio
Published: August 2021

Organic wastes represent an increasing pollution problem due to the exponential growth of their presence in the waste stream. Among these, waste flour cannot be easily reused by transforming it into high-value-added products. Another major problem is represented by epoxy-based thermosets, which have wide use but also poor recyclability. The object of the present paper is, therefore, to analyze both of these problems and come up with innovative solutions. Indeed, we propose a completely new approach, aimed at reusing the organic waste flour, by converting it into high-value epoxy-based thermosets that could be fully recycled into a reusable plastic matrix when added to the waste epoxy-based thermosets. Throughout the research activity, the organic waste was transformed into an epoxidized prepolymer, which was then mixed with a bio-based monomer cured with a cleavable ammine. The latter reactant was based on Recyclamine™ by Connora Technologies, and in this paper, we demonstrate that this original approach could work with the synthetized epoxy prepolymers derived from the waste flour. The cured epoxies were fully characterized in terms of their thermal, rheological, and flexural properties. The results obtained showed optimal recyclability of the new resin developed.
Valorization and Mechanical Recycling of Heterogeneous Post-Consumer Polymer Waste through a Mechano-Chemical Process
Authors: Capuano Roberta , Bonadies Irene , Castaldo Rachele , Cocca Mariacristina , Gentile Gennaro , Protopapa Antonio , Avolio Roberto , Errico Maria Emanuela
Published: August 2021

In this paper, a sustainable strategy to valorize and recycle heterogeneous polymer-based post-consumer waste is proposed. This strategy is based on a high-energy mechano-chemical treatment and has been applied to a polyolefin-rich fraction, coded as FIL/S, deriving from household plastic waste collection. This processing, performed in a planetary ball mill, allowed us to obtain fine grinding and, consequently, to induce an intimate mixing of the different polymer fractions and contaminants composing the FIL/S, as demonstrated by SEM analysis. As a result, an improvement in the deformability of the treated material was obtained, recording values for elongation at the break which were two and half times higher than the neat FIL/S. Finally, the addition of small amounts of organic peroxide during mechano-chemical treatment was tested, determining a more homogeneous morphology and a further improvement in mechanical parameters.
Combustion Instability of Swirl Premixed Flame with Dielectric Barrier Discharge Plasma
Authors: Deng Kai , Zhao Shenglang , Xue Chenyang , Hu Jinlin , Zhong Yi , Zhong Yingjie
Published: August 2021

The effects of plasma on the combustion instability of a methane swirling premixed flame under acoustic excitation were investigated. The flame image of OH planar laser-induced fluorescence and the fluctuation of flame transfer function showed the mechanism of plasma in combustion instability. The results show that when the acoustic frequency is less than 100 Hz, the gain in flame transfer function gradually increases with the frequency; when the acoustic frequency is 100~220 Hz, the flame transfer function shows a trend of first decreasing and then increasing with acoustic frequency. When the acoustic frequency is greater than 220 Hz, the flame transfer function gradually decreases with acoustic frequency. When the voltage exceeds the critical discharge value of 5.3 kV, the premixed gas is ionized and the heat release rate increases significantly, thereby reducing the gain in flame transfer function and enhancing flame stability. Plasma causes changes in the internal recirculation zone, compression, and curling degree of the flame, and thereby accelerates the rate of chemical reaction and leads to an increase in flame heat release rate. Eventually, the concentration of OH radicals changes, and the heat release rate changes accordingly, which ultimately changes the combustion instability of the swirling flame.
Pressure Fluctuation Reduction of a Centrifugal Pump by Blade Trailing Edge Modification
Authors: Huang Bin , Zeng Guitao , Qian Bo , Wu Peng , Shi Peili , Qian Dongqing
Published: August 2021

The pressure fluctuation inside centrifugal pumps is one of the main causes of hydro-induced vibration, especially at the blade-passing frequency and its harmonics. This paper investigates the feature of blade-passing frequency excitation in a low-specific-speed centrifugal pump in the perspective of local Euler head distribution based on CFD analysis. Meanwhile, the relation between local Euler head distribution and pressure fluctuation amplitude is observed and used to explain the mechanism of intensive pressure fluctuation. The impeller blade with ordinary trailing edge profile, which is the prototype impeller in this study, usually induces wake shedding near the impeller outlet, making the energy distribution less uniform. Because of this, the method of reducing pressure fluctuation by means of improving Euler head distribution uniformity by modifying the impeller blade trailing edge profile is proposed. The impeller blade trailing edges are trimmed in different scales, which are marked as model A, B, and C. As a result of trailing edge trimming, the impeller outlet angles at the pressure side of the prototype of model A, B, and C are 21, 18, 15, and 12 degrees, respectively. The differences in Euler head distribution and pressure fluctuation between the model impellers at nominal flow rate are investigated and analyzed. Experimental verification is also conducted to validate the CFD results. The results show that the blade trailing edge profiling on the pressure side can help reduce pressure fluctuation. The uniformity of Euler head circumferential distribution, which is directly related to the intensity of pressure fluctuation, is improved because the impeller blade outlet angle on the pressure side decreases and thus the velocity components are adjusted when the blade trailing edge profile is modified. The results of the investigation demonstrate that blade trailing edge profiling can be used in the vibration reduction of low specific impellers and in the engineering design of centrifugal pumps.
A Theoretical Model of Mitochondrial ATP Synthase Deficiencies. The Role of Mitochondrial Carriers
Authors: Mazat Jean-Pierre , Devin Anne , Yoboue Edgar , Ransac Stéphane
Published: August 2021

The m.8993T>G mutation of the mitochondrial MT-ATP6 gene is associated with NARP syndrome (neuropathy, ataxia and retinitis pigmentosa). The equivalent point mutation introduced in yeast Saccharomyces cerevisiae mitochondrial DNA considerably reduced the activity of ATP synthase and of cytochrome-c-oxidase, preventing yeast growth on oxidative substrates. The overexpression of the mitochondrial oxodicarboxylate carrier (Odc1p) was able to rescue the growth on the oxidative substrate by increasing the substrate-level phosphorylation of ADP coupled to the conversion of α-ketoglutarate (AKG) into succinate with an increase in Complex IV activity. Previous studies showed that equivalent point mutations in ATP synthase behave similarly and can be rescued by Odc1p overexpression and/or the uncoupling of OXPHOS from ATP synthesis. In order to better understand the mechanism of the ATP synthase mutation bypass, we developed a core model of mitochondrial metabolism based on AKG as a respiratory substrate. We describe the different possible metabolite outputs and the ATP/O ratio values as a function of ATP synthase inhibition.
Association between the Biophysical Environment in Coastal South China Sea and Large-Scale Synoptic Circulation Patterns: The Role of the Northwest Pacific Subtropical High and Typhoons
Authors: Liu Shuhong , Yang Yuanjian , Tang Danling , Yan Hong , Ning Guicai
Published: August 2021

Synoptic weather conditions can modulate short-term variations in the marine biophysical environment. However, the impact of large-scale synoptic circulation patterns (LSCPs) on variations in chlorophyll-a (chl-a) and sea surface temperature (SST) in the South China Sea (SCS) remains unclear. Using a T-mode principal component analysis method, four types of LSCP related to the Northwest Pacific subtropical high are objectively identified over the SCS for the summers of 2015–2018. Type 1 exhibits a lower chl-a concentration of <0.3 mg m−3 offshore of southern Vietnam with respect to the other three types. For Type 2, the high chl-a concentration zone (>0.3 mg m−3) along the coast of Guangdong exhibits the widest areas of coverage. The offshore chl-a bloom jet (>0.3 mg m−3) formed in southern Vietnam is the most obvious under Type 3. Under Type 4, the high chl-a concentration zone along the coast of Guangdong is the narrowest, while the chl-a concentration in the middle of the SCS is the lowest (<0.1 mg m−3). These type differences are mostly caused by the various monsoon circulations, local ocean mesoscale processes and resultant differences in localized precipitation, wind vectors, photosynthetically active radiation and SST. In particular, precipitation over land helps to transport nutrients from the land to the shore, which is conducive to the increase of chl-a. However, precipitation over ocean will dilute the upper seawater and reduce chl-a. Typhoons pump the deeper seawater with nutrients to the surface, and therefore make a positive contribution to chl-a in most offshore areas; however, they also disturb shallower water and hinder the growth of phytoplankton, making a negative contribution near the coast of Guangdong. In general, our findings will provide a better understanding of wind pump impact: the responses of marine biophysical environments to LSCPs.
An Adaptive Weighted Phase Optimization Algorithm Based on the Sigmoid Model for Distributed Scatterers
Authors: Li Shijin , Zhang Shubi , Li Tao , Gao Yandong , Zhou Xiaoqing , Chen Qianfu , Zhang Xiang , Yang Chao
Published: August 2021

Distributed scatterers (DSs) have been widely used in the time series interferometric synthetic aperture radar technique, which compensates for the insufficient density of persistent scatterers (PSs) in nonurban areas. In contrast to PS, DS is vulnerable to temporal and geometric decorrelation effects. Thus, phase optimization processing for DS is essential for reliable deformation parameter estimation. Advanced research has revealed that the application of all possible interferometric pairs will be more conducive to the reduction in phase biases. However, the low-coherence pixels will inevitably increase the difficulty of phase optimization and introduce unpredictable negative effects, which will reduce the effect of phase optimization. Therefore, this study proposed an advanced adaptive weighted phase optimization algorithm (AWPOA). In the AWPOA, the adaptive weighting strategy based on the sigmoid model was first proposed to assign more reasonable weights to pixels of different quality, which can efficiently reduce the negative influence of low-coherence pixels and improve the optimization performance. Moreover, coherence bias correction based on the second-kind statistics and an efficient solution strategy based on eigenvalue decomposition were derived and applied to achieve optimal phase series retrieval. The experimental results validated against both simulated and two sets of TerraSAR-X data demonstrated the overall superiority of the AWPOA over traditional phase optimization algorithms (POAs). Specifically, the processing efficiency of the eigenvalue decomposition solution strategy used in AWPOA was nearly 20 times faster than that of the PTA iterative solution strategy under the case without bias correction. Although bias correction increased the processing time, the optimization effect was significantly improved. Moreover, in terms of the quantitative evaluation indexes with the residual and the sum of the phase difference, the mean value of the improvement percentage of the AWPOA was increased by more than 12%, and the standard deviation was reduced by more than 1% over the traditional POAs, indicating its superior optimization performance and noise robustness.
Distributed Architecture for an Integrated Development Environment, Large Trace Analysis, and Visualization
Authors: Chen Kuang Piao Yonni , Ezzati-jivan Naser , Dagenais Michel R.
Published: August 2021

Integrated development environments (IDEs) provide many useful tools such as a code editor, a compiler, and a debugger for creating software. These tools are highly sophisticated, and their development requires a significant effort. Traditionally, an IDE supports different programming languages via plugins that are not usually reusable in other IDEs. Given the high complexity and constant evolution of popular programming languages, such as C++ and even Java, the effort to update those plugins has become unbearable. Thus, recent work aims to modularize IDEs and reuse the existing parser implementation directly in compilers. However, when IDE debugging tools are insufficient at detecting performance defects in large and multithreaded systems, developers must use tracing and trace visualization tools in their software development process. Those tools are often standalone applications and do not interoperate with the new modular IDEs, thus losing the power and the benefits of many features provided by the IDE. The structure and use cases of tracing tools, with the potentially massive execution traces, significantly differ from the other tools in IDEs. Thus, it is a considerable challenge, one which has not been addressed previously, to integrate them into the new modular IDEs. In this paper, we propose an efficient modular client–server architecture for trace analysis and visualization that solves those problems. The proposed architecture is well suited for performance analysis on Internet of Things (IoT) devices, where resource limitations often prohibit data collection, processing, and visualization all on the same device. The experimental evaluation demonstrated that our proposed flexible and reusable solution is scalable and has a small acceptable performance overhead compared to the standalone approach.
Hot Topics and Evolution of Frontier Research in Early Education: A Bibliometric Mapping of the Research Literature (2001–2020)
Authors: Wang Shutao , Lv Xinlei
Published: August 2021

The aim of the present study is to explore the evolving trend of research directions in the field of early education. In this research, CiteSpace and VOSviewer were used to visually analyze documents published in eight SSCI journals between 2001 and 2020. Through methods such as co-authorship analysis, cluster analysis, and cocitation analysis, this study found that child care, school readiness, early education quality, effortful control, executive function, self-regulation, and teacher–student relationships are hot topics in early education. Early education research has distinctive interdisciplinary characteristics.
Innovative Finance, Technological Adaptation and SMEs Sustainability: The Mediating Role of Government Support during COVID-19 Pandemic
Authors: Pu Ganlin , Qamruzzaman Md. , Mehta Ahmed Muneeb , Naqvi Farah Naz , Karim Salma
Published: August 2021

Small and medium enterprises (SMEs) survival is critical for economic sustainability due to the multifaceted role of the economy. Thus, halting SMEs operation hurts the aggregate economy. During the present pandemic, SMEs’ sustainability in Bangladesh is under-challenged because of limited market demand, supply constraints, financial incapacity, and capital restrictions. However, with the concerted effort from firms and the government, SME’s have been trying to reestablish from the unforeseen consequence by capitalizing on innovation, skills, and economic resources. The motivation of the study is to gauge the impact of innovative finance, technological adaptation, and the government’s role on SMEs’ sustainability during the COVID-19 pandemic in Bangladesh. As a study sample, 2000 SMEs were considered for data collection through a structured questionnaire from 10 December 2020, to 28 January 2021. A sample of 1895 SMEs was returned with their responses. However, after a careful data cleaning procedure, only a sample of 1395 (69.75%) responses was found suitable for study. The study applied structural equation modelling to explore causal effects and test the proposed hypothesis for the hypnotized model, i.e., more precisely, to explore the direct effects of technology adaptation and innovative finance and indirect effects through government support on SMEs. Study findings revealed that SMEs’ sustainability positively accelerates by applying innovative finance and integration of technological adaptation. In contrast, the mediating role of government was also established with indirect assessment. Study findings suggest that policy formulation and implementation must be initiated, focusing on effective online financial services, settling business transactions, and integrating IT advancements in operation.
DfMA: Towards an Integrated Strategy for a More Productive and Sustainable Construction Industry in Australia
Authors: Langston Craig , Zhang Weiwei
Published: August 2021

Design for manufacture and assembly (DfMA) is an important part of the future of the construction industry due to the promise of speed of project delivery, quality control, worker safety, and waste minimization onsite via the purposeful design for manufacture and assembly offsite. However, the adoption of DfMA in Australia has been slow. This paper investigates the barriers prohibiting widespread uptake and how digital construction will be a catalyst for improving use on commercial-scale projects. A total of six leading experts were interviewed to elicit their opinions, and seven recent case studies of high-rise modular apartment and hotel buildings constructed by Hickory were cross-referenced as evidence of DfMA capability. The experts suggested that the reasons for slow adoption in Australia were community mindset, government regulations and incentives, planning and building codes, unionization and business politics, finance, and supply chain management. The case studies suggest that compatible building type and transportation distance are also factors. These barriers can be addressed by the clever integration of building information modelling tools with lean construction processes as part of a proposed strategy leading to smarter (more productive) and better (more sustainable) outcomes predicated on growth in digital construction practices. The paper concludes with a proposed framework for change that conceptualizes the ‘ecosystem’ needed to support widespread DfMA in the Australian context, including the paradigm shift from building to manufacturing/assembly, the displacement of workers from onsite to offsite activity, and the expansion of interdisciplinary design and construct collaboration.
Effect of Water Vapor Injection on the Performance and Emissions Characteristics of a Spark-Ignition Engine
Authors: Hsueh Ming-Hsien , Lai Chao-Jung , Hsieh Meng-Chang , Wang Shi-Hao , Hsieh Chia-Hsin , Pan Chieh-Yu , Huang Wen-Chen
Published: August 2021

The exhaust emissions from Internal Combustion Engines (ICE) are currently one of the main sources of air pollution. This research presented a method for improving the exhaust gases and the performance of a Spark-Ignition (SI) engine using a water vapor injection system and a Non-Thermal Plasma (NTP) system. These two systems were installed on the intake manifold to investigate their effects on the engine’s performance and the characteristics of exhaust emission using different air/fuel (A/F) ratios and engine speeds. The temperatures of the injected water were adjusted to 5 and 25 °C, using a thermoelectric cooler (TEC) temperature control device. The total hydrocarbons (HC), nitrogen oxide (NOx), and engine torque were measured at different A/F ratios and engine speeds. The results indicated that the adaptation of the water vapor injection system and NTP system increased the content of the combustibles and combustion-supporting substances while achieving better emissions and torque. According to the test results, while the engine torque under 25 °C water+NTP was raised to 7.29%, the HC under 25 °C water+NTP and the NOx under 25 °C water were reduced to 16.31% and 11.88%, respectively. In conclusion, the water vapor injection and the NTP systems installed on the intake manifold could significantly reduce air pollution and improve engine performance for a more sustainable environment.
Teacher Competences for Active Learning in Engineering Education
Authors: Neves Renato Martins , Lima Rui M. , Mesquita Diana
Published: August 2021

The implementation of active learning strategies in engineering education still encounters barriers when facing conventional teaching-learning practices. This work aims to contribute to the discussion on teachers’ pedagogical competences required for active learning. This contribution is developed from the perceptions of 205 engineering teachers of Brazilian higher education institutions, centered on significant teaching competences necessary for teachers of engineering courses and how to develop them in the active learning context. The results show that essential competences identified by the participants are (I) teamwork (teachers’ cooperation); (II) teacher–student relationships (empathy); (III) feedback about students’ performance throughout the learning process; (IV) information and communication technology (ICT) competences; (V) selecting and adapting the teaching-learning methodologies to the class context; and (VI) creativity. A complementary logistic regression model suggested that female Ph.D. full-time teachers are more likely to employ active learning. Differences in active learning adoption among Brazilian regions were also captured by the model. The identified competences are essential for the sustainability of the innovation of teaching practices in the context of active learning, which may be used to inform more effective professional training of engineering teachers in the current globalized scenario.
Wood and Black Liquor-Based N-Doped Activated Carbon for Energy Application
Authors: Plavniece Ance , Volperts Aleksandrs , Dobele Galina , Zhurinsh Aivars , Kaare Kätlin , Kruusenberg Ivar , Kaprans Kaspars , Knoks Ainars , Kleperis Janis
Published: August 2021

Fuel cells, batteries and supercapacitors are critical to meet the rising global demand for clean, sustainable energy. Biomass-derived activated carbon can be obtained with tailored properties to fulfil the extensive need for low-cost, high-performance, catalyst and electrode materials. To investigate the possibility of nanoporous nitrogen-doped carbon materials as catalysts in fuel cells and electrodes in lithium-ion batteries, biomass precursors were thermochemically activated with NaOH at 800 °C, nitrogen was introduced using dicyandiamide and doping was performed at 800 °C. The chemical composition, porous structure, texture and electrochemical properties of the obtained materials change depending on the biomass precursor used. It has been found that the most promising precursor of the obtained materials is wood char, both as an oxygen reduction catalyst in fuel cells, which shows better properties than the commercial 20% Pt/C catalyst, and as an anode material in Li-ion batteries. However, catalysts based on black liquor and hybrid material have comparable properties with commercial 20% Pt/C catalyst and can be considered as a cheaper alternative.
Business Model and Principles of a Values-Based Bank—Case Study of MagNet Hungarian Community Bank
Authors: Győri Zsuzsanna , Khan Yahya , Szegedi Krisztina
Published: August 2021

The 2020–2021 global pandemic has brought significant changes to social and economic life. Companies must begin to rethink their business models and values to meet these new challenges. Given the process of intermediation, which has an indirect and catalytic impact, banks have a responsibility and opportunity to transform the economy by, for example, lending to projects that encourage decarbonization and/or green energy. The purpose of this paper is to examine the MagNet Hungarian Community Bank’s approach as a values-based bank in order to compare how the operation of the bank differs from that of traditional ones—even if these apply the Corporate Social Responsibility approach. The findings of an exploratory study of MagNet’s responsible and sustainable way of doing business can help other sectors and companies cope with the global crisis and be a part of the transition to an inclusive, fair, and decarbonised economy. The data for this study were collected using semi-structured interviews with eleven bankers and three customers of MagNet Bank in 2019, as well as bank documents. Using this information, we created a business model for the bank, using the Business Model Canvas method. Within the business model we highlighted how MagNet Bank integrates principles of the Global Alliance for Banking on Values, with the aim of truly integrating sustainability into the core of their corporate genetic makeup, instead of as a partial or insincere measure. With the projection of the models onto each other, we emphasize the role of values in the business model. The combination of the models indicates potential learning points for the further development and long-term success of the bank and serves as an example of good practices for others. This is especially relevant when considering the greater need for improved crisis and risk management due to the pandemic and for the integration of sustainability considerations into business operations which have increased the impetus in the financial sector towards sustainability.
Towards Sustainable Farm Production System: A Case Study of Corn Farming
Authors: Abbas Adnan , Zhao Chengyi , Ullah Waheed , Ahmad Riaz , Waseem Muhammad , Zhu Jianting
Published: August 2021

Many recent studies show that most of the crop production systems in developing countries are not environmentally sustainable. This study uses the life cycle assessment (LCA) to investigate the potential impacts of corn production in Pakistan on global warming and human health damages and also suggests mitigation strategies to reduce environmental impacts towards sustainable crop production based on the results. Land-based, mass-based, and energy-based functional units were used. IMPACT 2002+ methodology—a combination of IMPACT 2002, Eco-Indicator 99, CML, and intergovernmental panel on climate change (IPCC)—is used for the impact assessment. The results demonstrated that the global warming potential of one-ton production of corn, one-hectare corn farm, and production of 1000 MJ energy were 354.18, 34,569.90, and 1275.13 kg CO2 equivalents, respectively. The off-farm and on-farm emissions of nitrogen-based chemical fertilizers were the hotspots in the most impact categories. Moreover, human health damages followed by global warming as environmental externalities were also associated with corn production. We also highlighted the production areas with light, medium and extreme environmental externalities with Toba Tek Singh and Okara districts in the Punjab province of Pakistan being the most and least contributing districts towards global warming, respectively. Results further indicated that a 5 to 100% reduction of chemical fertilizers would mitigate the environmental impacts of corn production by 4.38 to 87.58% and 2.16 to 43.30% in terms of aquatic acidification and global warming, respectively. Modern farming systems and conservation technologies were suggested to reduce emissions and improve the environmental performance of corn production. Furthermore, agricultural extension and the ministry of agriculture should pay more attention to farmers’ education on emissions from farming inputs and their impact on climate.
Evaluating Factors Affecting Performance of Land Reform Beneficiaries in South Africa
Authors: Gandidzanwa Colleta , Verschoor Aart Jan , Sacolo Thabo
Published: August 2021

The ability of farmers to operate redistributed farms in a profitable and sustainable manner is crucial for both successful integration into agricultural value chains and sustainable production systems. The performance of redistributed farms is becoming increasingly important as the number of redistributed farms increases in light of correcting previous anomalies in land ownership in South Africa while ensuring continued food security. Although much has been done to assess the impact of land reform on macro variables, little has been done to unpack factors associated with the success of redistributed farms. Using a sample of 1956 redistributed farms across the nine provinces of South Africa, the current study employs an ordinary least square regression as well as a generalised logistic regression model to identify factors associated with the success (measured by net farm income and probability to operate at commercially viable scale) of the sampled farms. The results show that infrastructure, support (both technical and financial), and type of market used are significantly associated with the performance of redistributed farms. In addition, the results reveal disparities in performance across provinces and across gender categories. The study provides valuable insight to programme managers on the factors that needs to be enhanced in order to increase the odds of success for redistributed farms.
Linearizability of 2:−3 Resonant Systems with Quadratic Nonlinearities
Authors: Žulj Maja , Ferčec Brigita , Mencinger Matej
Published: August 2021

In this paper, the linearizability of a 2:−3 resonant system with quadratic nonlinearities is studied. We provide a list of the conditions for this family of systems having a linearizable center. The conditions for linearizablity are obtained by computing the ideal generated by the linearizability quantities and its decomposition into associate primes. To successfully perform the calculations, we use an approach based on modular computations. The sufficiency of the obtained conditions is proven by several methods, mainly by the method of Darboux linearization.
A Newton-Modified Weighted Arithmetic Mean Solution of Nonlinear Porous Medium Type Equations
Authors: Aruchunan Elayaraja , Chew Jackel Vui Lung , Muthuvalu Mohana Sundaram , Sunarto Andang , Sulaiman Jumat
Published: August 2021

The mathematical theory behind the porous medium type equation is well developed and produces many applications to the real world. The research and development of the fractional nonlinear porous medium models also progressed significantly in recent years. An efficient numerical method to solve porous medium models needs to be investigated so that the symmetry of the designed method can be extended to future fractional porous medium models. This paper contributes a new numerical method called Newton-Modified Weighted Arithmetic Mean (Newton-MOWAM). The solution of the porous medium type equation is approximated by using a finite difference method. Then, the Newton method is applied as a linearization approach to solving the system of nonlinear equations. As the system to be solved is large, high computational complexity is regulated by the MOWAM iterative method. Newton-MOWAM is formulated technically based on the matrix structure of the system. Some initial-boundary value problems with a different type of nonlinear diffusion term are presented. As a result, the Newton-MOWAM showed a significant improvement in the computation efficiency compared to the developed standard Weighted Arithmetic Mean iterative method. The analysis of efficiency, measured by the reduced number of iterations and computation time, is reported along with the convergence analysis.
CSR Communication among Tourism SMEs through Their Websites
Authors: Baniya Rojan , Thapa Brijesh
Published: August 2021

Small and Medium Enterprises (SMEs) in tourism are increasingly communicating their Corporate Social Responsibility (CSR) initiatives via their websites to build a positive image and promote customer relationships. This study examined such CSR engagement and communications by tourism SMEs in Nepal based on qualitative analysis of website content and in-depth interviews. Google search engine was used to select SMEs, and textual data were extracted from their websites. Following data saturation, a review of twenty-five websites was initially compared, and the obtained information was subsequently evaluated with information provided through individual interviews. Overall, CSR activities were largely practiced at a philanthropic level, and to some extent, at an ethical level. SMEs were primarily focused on activities related to social and environmental issues within the communities in which they operate. The results of this exploratory study provide an initial assessment of CSR among tourism SMEs in Nepal and could assist tourism associations/organizations with initiatives.
Onchocerciasis Fingerprints in the Geriatric Population: Does Host Immunity Play a Role?
Authors: Shintouo Cabirou Mounchili , Shey Robert Adamu , Mets Tony , Vanhamme Luc , Souopgui Jacob , Ghogomu Stephen Mbigha , Njemini Rose
Published: August 2021

One of the most debilitating consequences of aging is the progressive decline in immune function, known as immunosenescence. This phenomenon is characterized by a shift in T-cell phenotypes, with a manifest decrease of naive T-cells—dealing with newly encountered antigens—and a concomitant accumulation of senescent and regulatory T-cells, leading to a greater risk of morbidity and mortality in older subjects. Additionally, with aging, several studies have unequivocally revealed an increase in the prevalence of onchocerciasis infection. Most lymphatic complications, skin and eye lesions due to onchocerciasis are more frequent among the elderly population. While the reasons for increased susceptibility to onchocerciasis with age are likely to be multi-factorial, age-associated immune dysfunction could play a key role in the onset and progression of the disease. On the other hand, there is a growing consensus that infection with onchocerciasis may evoke deleterious effects on the host’s immunity and exacerbate immune dysfunction. Indeed, Onchocerca volvulus has been reported to counteract the immune responses of the host through molecular mimicry by impairing T-cell activation and interfering with the processing of antigens. Moreover, reports indicate impaired cellular and humoral immune responses even to non-parasite antigens in onchocerciasis patients. This diminished protective response may intensify the immunosenescence outcomes, with a consequent vulnerability of those affected to additional diseases. Taken together, this review is aimed at contributing to a better understanding of the immunological and potential pathological mechanisms of onchocerciasis in the older population.
Evidence of Taxonomic and Functional Recovery of Macroinvertebrate Communities Following River Restoration
Authors: England Judy , Hayes Chloe , White James , Johns Tim
Published: August 2021

River ecosystems have been heavily degraded globally due to channel hydromorphological modifications or alterations to catchment-wide processes. Restoration actions aimed at addressing these changes and restoring ecological integrity are increasing, but evidence of the effectiveness of these actions is variable. Using a rare 7-year before-after-control-impact (BACI) study of restoration of a lowland groundwater-fed river in England, UK, we explore changes in the macroinvertebrate community following the removal of impoundments and channel narrowing to aid restoration of physical processes. Restoration activity prompted significant taxonomic and functional responses of benthic invertebrate communities in the 4 years post-restoration. Specifically, significant gains in taxonomic and functional richness were evident following restoration, although corresponding evenness and diversity measures did not mirror these trends. Restoration activities prompted a shift to more rheophilic taxa and associated traits matching the physical changes to the channel and habitat composition. Temporal changes were clearer for taxonomic compositions compared to the functional properties of macroinvertebrate communities, indicating a functional redundancy effect of new colonists inhabiting restored reaches following restoration. The results highlight the value of long-term BACI studies in river restoration assessments, as well as project appraisals incorporating both taxonomic and functional observations. We highlight the urgent need of such studies to provide evidence to inform effective river restoration strategies to address future changes such as adaption to climate change and the biodiversity crisis.
Low Cost Activated Carbon for Removal of NOM and DBPs: Optimization and Comparison
Authors: Tafvizi Hoda , Chowdhury Shakhawat , Husain Tahir
Published: August 2021

Higher concentrations of disinfection byproducts (DBPs) in small water systems have been a challenge. Adsorption by tailored activated carbon (AC), developed from waste materials of a pulp and paper company using optimization of chemical activation by nitric acid followed by physical activation and metal coating, was tested for the removal of natural organic matter from water using synthetic and natural water. AC was coated with aluminum and iron salts in a ratio of 0.25 to 10.0% of metal: AC (wt:wt%). The optimization of dosage, pH, and time was performed to achieve the highest adsorption capacity. The modified AC of 0.75% Fe-AC and 1.0% Al-AC showed 35–44% improvement in DOC removal from natural water. An enhancement of 40.7% in THMs removal and 77.1% in HAAs removal, compared to non-modified, AC were achieved. The pseudo-second order was the best fitted kinetic model for DOC removal, representing a physiochemical mechanism of adsorption.
Morphodynamic Modelling with Uncertain Geometry Input
Authors: Siedersleben Jakob , Jocham Stefan , Aufleger Markus , Klar Robert
Published: August 2021

For morphodynamic modelling, riverbed survey data are essential as the basis for the evaluation of temporal riverbed development, mesh creation, and model calibration. To study the effects of uncertain geometry input on these issues, datasets of different spatial resolutions were analysed. As a result, cross-profile data were derived from high-resolution survey data, which are available for a river reach in the Upper Danube in Bavaria for several periods. Finally, the prediction quality of simulations based on cross-profile and high-resolution spatial data was assessed. The analysis of both datasets shows continuous riverbed erosion but of different magnitudes. However, complex riverbed geometry due to, e.g., scours, is depicted poorly by cross-profile data. In more homogenously characterised reaches, cross-profile data significantly more closely represents the riverbed geometry than the high-resolution spatial data base. Local misinterpretation of riverbed geometry by cross-profile data leads to deviations of calibration parameters in the entire study area. Consequently, these deviations in calibration outcome effect the model predictions. In this case, cross-profile calibration generally induces higher transport capacities, leading to more erosion in the study area compared to the model based on high-resolution spatial calibration. The general shape of predicted riverbed geometries is found to be similar but with local deviations, which are not limited to areas with complex river geometry.