bluuebunny/crossref_metadata_2025 huggingface dataset:
Severe Plastic Deformation of Fe-22Al-5Cr Alloy by Cross-Channel Extrusion with Back Pressure
Authors: Łyszkowski Radosław , Polkowski Wojciech , Czujko Tomasz
Published: November 2018

A new concept of the cross-channel extrusion (CCE) process under back pressure (BP) was proposed and tested experimentally. The obtained by finite element method (FEM) results showed that a triaxial compression occurred in the central zone, whereas the material was deformed by shearing in the outer zone. This led to the presence of a relatively uniformly deformed outer zone at 1 per pass and a strong deformation of the paraxial zone (3–5/pass). An increase in the BP did not substantially affect the accumulated strain but made it more uniform. The FEM results were verified using the physical modeling technique (PMT) by the extrusion of clay billet. The formation of the plane of the strongly flattened, and elongated grains were observed in the extrusion directions. With the increase in the number of passes, the shape of the resulting patterns expanded, indicating an increase in the deformation homogeneity. Finally, these investigations were verified experimentally for Fe-22Al-5Cr (at. %) alloy using of the purposely designed tooling. The effect of the CCE process is the fragmentation of the original material structure by dividing the primary grains. The complexity of the stress state leads to the rapid growth of microshear bands (MSB), grain defragmentation and the nucleation of new dynamically recrystallized grains about 200–400 nm size.
Linear Versus Nonlinear Acoustic Probing of Plasticity in Metals: A Quantitative Assessment
Authors: Espinoza Carolina , Feliú Daniel , Aguilar Claudio , Espinoza-González Rodrigo , Lund Fernando , Salinas Vicente , Mujica Nicolás
Published: November 2018

The relative dislocation density of aluminum and copper samples is quantitatively measured using linear Resonant Ultrasound Spectroscopy (RUS). For each metallic group, four samples were prepared with different thermomechanical treatments in order to induce changes in their dislocation densities. The RUS results are compared with Nonlinear Resonant Ultrasound Spectroscopy (NRUS) as well as Second Harmonic Generation (SHG) measurements. NRUS has a higher sensitivity by a factor of two to six and SHG by 14–62%. The latter technique is, however, faster and simpler. As a main result, we obtain a quantitative relation between the changes in the nonlinear parameters and the dislocation density variations, which in a first approximation is a linear relation between these differences. We also present a simple theoretical expression that explains the better sensitivity to dislocation content of the nonlinear parameters with respect to the linear ones. X-Ray diffraction measurements, although intrusive and less accurate, support the acoustics results.
Effect of Electric Current Pulse on Microstructure and Corrosion Resistance of Hypereutectic High Chromium Cast Iron
Authors: Lv Haiyang , Zhou Rongfeng , Li Lu , Ni Haitao , Zhu Jiang , Feng Tong
Published: November 2018

The effect of electric current pulse on the microstructure and corrosion resistance of hypereutectic high chromium cast iron was explored. The morphology of carbides in solidification microstructure was observed by an optical microscope and a scanning electron microscope and the composition was determined by an electron probe micro-analyzer. The microhardness of primary carbides and corrosion resistance of samples were also compared. Under the active of electric current pulse, the microstructure of hypereutectic high chromium cast iron was homogenized and its performance improved accordingly. On treatment by electric current, the morphology of primary carbides changed from thick long rods to hexagonal blocks or granular structures. The interlayer spacing of eutectic carbide decreased from ~26.3 μm to ~17.8 μm. Size statistics showed that the average diameter of primary carbide decreased from ~220 μm to ~60 μm. As a result, microhardness increased from 1412 HV to 1511 HV. No obvious microcrack propagation was found at the microindentation sites. The average length of microcracks decreased from ~20.7 μm to ~5.7 μm. Furthermore, corrosion resistance was remarkably enhanced. The average corrosion rate decreased from 2.65 mg/cm2·h to 1.74 mg/cm2·h after pulse current treatment.
Effect of the Preparation Method (Sol-Gel or Hydrothermal) and Conditions on the TiO2 Properties and Activity for Propene Oxidation
Authors: Cano-Casanova Laura , Amorós-Pérez Ana , Lillo-Ródenas María Ángeles , Román-Martínez María del Carmen
Published: November 2018

Since the two most commonly used methods for TiO2 preparation are sol-gel (SG) and hydrothermal (HT) synthesis, this study attempts to compare both methods in order to determine which one is the most suitable to prepare photocatalysts for propene oxidation. In addition, this work studies how the concentration of the HCl used for hydrolysis of the TiO2 precursor affects the properties of the obtained materials. Also, the effect of avoiding the post-synthesis heat-treatment in a selection of samples is investigated. The photocatalysts are characterized by XRD, N2 adsorption-desorption isotherms and UV-vis spectroscopy, and the study tries to correlate the properties with the photocatalytic performance of the prepared TiO2 samples in propene oxidation. TiO2 materials with high crystallinity, between 67% and 81%, and surface area (up to 134 m2/g) have been obtained both by SG and HT methods. In general, the surface area and pore volume of the TiO2-HT samples are larger than those of TiO2-SG ones. The TiO2-HT catalysts are, in general, more active than TiO2-SG materials or P25 in the photo-oxidation of propene. The effect of HCl presence during the TiO2 synthesis and of the post synthesis heat treatment are much more marked in the case of the SG materials.
Optimization of Detergent-Mediated Reconstitution of Influenza A M2 Protein into Proteoliposomes
Authors: Crouch Catherine H. , Bost Margaret H. , Kim Tae H. , Green Bryan M. , Arbuckle D. Stuart , Grossman Carl H. , Howard Kathleen P.
Published: November 2018

We report the optimization of detergent-mediated reconstitution of an integral membrane-bound protein, full-length influenza M2 protein, by direct insertion into detergent-saturated liposomes. Detergent-mediated reconstitution is an important method for preparing proteoliposomes for studying membrane proteins, and must be optimized for each combination of protein and membrane constituents used. The purpose of the reconstitution was to prepare samples for site-directed spin-labeling electron paramagnetic resonance (SDSL-EPR) studies. Our goals in optimizing the protocol were to minimize the amount of detergent used, reduce overall proteoliposome preparation time, and confirm the removal of all detergent. The liposomes were comprised of (1-palmitoyl-2-oleyl-sn-glycero-phosphocholine (POPC) and 1-palmitoyl-2-oleyl-sn-glycero-3-[phospho-rac-(1-glycerol)] (POPG), and the detergent octylglucoside (OG) was used for reconstitution. Rigorous physical characterization was applied to optimize each step of the reconstitution process. We used dynamic light scattering (DLS) to determine the amount of OG needed to saturate the preformed liposomes. During detergent removal by absorption with Bio-Beads, we quantified the detergent concentration by means of a colorimetric assay, thereby determining the number of Bio-Bead additions needed to remove all detergent from the final proteoliposomes. We found that the overnight Bio-Bead incubation used in previously published protocols can be omitted, reducing the time needed for reconstitution. We also monitored the size distribution of the proteoliposomes with DLS, confirming that the size distribution remains essentially constant throughout the reconstitution process.
Dealloying of Cu-Mg-Ca Alloys
Authors: Ben Mbarek Wael , Pineda Eloi , Escoda Lluïsa , Suñol Joan Josep , Khitouni Mohamed
Published: November 2018

The chemical dealloying of Cu-Mg-Ca alloys in free corrosion conditions was investigated for different alloy compositions and different leaching solutions. For some of the precursor alloys, a continuous, pure fcc copper with nanoporous structure can be obtained by dealloying in 0.04 M H2SO4 solution. Superficial nanoporous copper structures with extremely fine porous size were also obtained by dealloying in pure water and 0.1 M NaOH solutions. The dealloying of both amorphous and partially crystalline alloys was investigated obtaining bi-phase nanoporous/crystal composites with microstructures depending on the precursor alloy state. The fast dissolution of Mg and Ca makes the Cu-Mg-Ca system an ideal candidate for obtaining nanoporous copper structures with different properties as a function of different factors such as the alloy composition, the quenching process, and leaching conditions.
Cavitation-Dispersion Method for Copper Cementation from Wastewater by Iron Powder
Authors: Shishkin Andrei , Mironovs Viktors , Vu Hong , Novak Pavel , Baronins Janis , Polyakov Alexandr , Ozolins Jurijs
Published: November 2018

The circular economy for sustainable economic deployment is strongly based on the re-use of secondary products and waste utilization. In the present study, a new effective cementation method for recovering valuable metallic copper from industrial wastewater using Fe0 powders is reported. A high-speed mixer-disperser (HSMD) capable of providing a cavitation effect was used for the rapid intake, dispersion, and mixing of Fe0 powder in an acidic wastewater solution (pH ≈ 2.9) containing copper ions mainly in the form of CuSO4. Three iron powders/particles were tested as the cementation agent: particles collected from industrial dust filters (CMS), water-atomized iron-based powder AHC100.29, and sponge-iron powder NC100.24. The effects of mixing regimes and related mixing conditions on the effectiveness of the Cu cementation process were evaluated by comparison between the HSMD and a laboratory paddle mixer. It was observed that the use of cavitation provided more efficient copper removal during the copper cementation process in comparison to the standard experiments with the propeller mixer. Under the cavitation regime, about 90% of copper was cemented in the first five minutes and the final copper removal of 95% was achieved using all three Fe0 powders after seven minutes of cementation. In comparison, only around 55% of copper was cemented in the first seven minutes of cementation using the traditional mixing method.
Friction Stir Spot Welding-Brazing of Al and Hot-Dip Aluminized Ti Alloy with Zn Interlayer
Authors: Zhou Xingwen , Chen Yuhua , Li Shuhan , Huang Yongde , Hao Kun , Peng Peng
Published: November 2018

Friction stir spot welding (FSSW) of Al to Ti alloys has broad applications in the aerospace and automobile industries, while its narrow joining area limits the improvement of mechanical properties of the joint. In the current study, an Al-coating was prepared on Ti6Al4V alloy by hot-dipping prior to joining, then a Zn interlayer was used during friction stir joining of as-coated Ti alloy to the 2014-Al alloy in a lap configuration to introduce a brazing zone out of the stir zone to increase the joining area. The microstructure of the joint was investigated, and the joint strength was compared with the traditional FSSW joint to confirm the advantages of this new process. Because of the increase of the joining area, the maximum fracture load of such joint is 110% higher than that of the traditional FSSW joint under the same welding parameters. The fracture load of these joints depends on the joining width, including the width of solid-state bonding region in stir zone and brazing region out of stir zone.
A Combined Method to Model Dynamic Recrystallization Based on Cellular Automaton and a Phenomenological (CAP) Approach
Authors: Azarbarmas Morteza , Mirjavadi Seyed Sajad , Ghasemi Ali , Hamouda Abdel Magid
Published: November 2018

Titanium alloys with high stacking-fault energy show continuous dynamic recrystallization (CDRX) instead of discontinuous dynamic recrystallization (DDRX) during high-temperature deformation. During the CDRX mechanism, new recrystallized grains are generated by the progressive increasing of the low-angle boundary misorientations. In the present work, the CDRX phenomenon was modeled by using a cellular automaton (CA)-based method. The size of seeds was determined based on a phenomenological approach, and then the number and distribution of recrystallized grains as well as the topological changes were applied by utilizing the CA approach. In order to verify the capacity of the proposed model for predicting the microstructural characteristics, the experimental data of the hot-compressed TiNiFe alloy were used. Results showed that the presented model can accurately estimate the fraction of the recrystallized area. Moreover, the macroscopic flow curves of the alloy were well predicted by the present model.
Effect of Revolutionary Pitch on Interface Microstructure and Mechanical Behavior of Friction Stir Lap Welds of AA6082-T6 to Galvanized DP800
Authors: Li Shuhan , Chen Yuhua , Kang Jidong , Shalchi Amirkhiz Babak , Nadeau Francois
Published: November 2018

Friction stir lap welding of 1.5-mm thick 6082-T6 aluminum alloy to 2-mm thick galvanized DP800 steel (Zn-coated) was carried out. Optimal welding conditions were obtained aiming to defect-free joints with good mechanical properties. The interfacial intermetallic compounds (IMCs) at the stir zone and hook zone were characterized under different revolutionary pitches. With a revolutionary pitch of 1.0 mm/rev, maximum joint strength reached 71% of that of the aluminum alloy. In the meantime, the average thickness of IMC layer is less than 1 μm; Al3.2Fe in the Al-rich side and Al5Fe2 in the Fe-rich side at the interfaces of stir zone while Al6Fe and nanocrystalline close to Al3.2Fe at the interface of the hook zone. At a relatively lower revolutionary pitch (0.5 mm/rev), Zn was found with the aggregation of Si and Mn at the hook-zone interface, leading to the generation of Al-Fe-Si phase thus decreasing the thickness of the IMC layer. In the stir zone, the revolutionary pitch has a significant influence on the interfacial microstructures. The interfacial IMC layer at 1.0 mm/rev is simple and flat, but the one at 0.5 mm/rev becomes thicker and more complex. Stir zone aluminum under different revolutionary pitches is similar in microhardness and tensile behavior. The mechanical response of joints was modeled based on linear mixture law with an iso-strain assumption and neglection of the IMC layer. The modeling results are in good agreement with the experimental ones indicating the resultant interfaces act as good as the good boundaries between dissimilar Al/steel joints.
Impact of Warm Rolling Process Parameters on Crystallographic Textures, Microstructure and Mechanical Properties of Low-Carbon Boron-Bearing Steels
Authors: Zebarjadi Sar Mandana , Barella Silvia , Gruttadauria Andrea , Mombelli Davide , Mapelli Carlo
Published: November 2018

The effect of the warm rolling process on the microstructure and the mechanical properties of low-carbon high-boron steels are studied in this work. To investigate these effects, boron-bearing low-carbon steel, subjected to roll at three different temperatures, was studied symmetrically and asymmetrically. The results of the experimental trials achieved by mechanical and microstructural analysis revealed that the use of warm rolling can represent a favorable method to suppress strain aging completely, and to eliminate the fluting effect and yield point elongation. In addition, the tensile and elongation properties are modified with the formation of boron nitride precipitates and dislocations in different thermomechanical conditions.
Understanding Heterogeneity of a Slag-Derived Weathered Material: The Role of Automated SEM-EDS Analyses
Authors: Pietranik Anna , Kierczak Jakub , Tyszka Rafał , Schulz Bernhard
Published: November 2018

Slag heaps over years may evolve into complexly weathered zones, which are a challenging material for analyses as they contain phases from numerous sources and at different stages of weathering. However, the weathered zones are important parts of slag heaps, because they contain both primary and secondary phases enriched in metal(oid)s that may become soluble under specific conditions. The weathering reactions related to metal release or precipitation may be recorded in a heavy mineral fraction as the fraction contains predominately minerals with elevated toxic elements concentrations. Therefore, an automated SEM analysis on a polished section of included heavy mineral particles was applied in this paper for a rapid recognition of phases in a complex setting and their classification into detrital, primary and secondary phases. The approach was applied to a slag heap in Świętochłowice (Upper Silesia, Poland) and it consisted of analyzing magnetic and non-magnetic heavy mineral fractions from three distinct horizons noted A, B and C. Materials had been previously interpreted as being sourced from the heap itself (lowermost horizon C) and from artificially added materials used later for superficial site remediation (upper horizons A and B). Instead, automated SEM analysis demonstrated that horizon C is derived from the slag heap weathering, horizon B is derived predominately from the artificially added materials, whereas horizon A is a mixture of the B and C horizons. Additionally, when slag particles in horizons A and C are compared, the lowermost horizon C contains more slag-derived secondary phases, whereas horizon A contains more primary slag phases. Therefore, horizon A remains the most prone to releasing toxic elements because, considering its position as the uppermost horizon, it can be submitted to climatic solicitation (fast water circulation).
Mantle Evolution from Ocean to Arc: The Record in Spinel Peridotite Xenoliths in Mt. Pinatubo, Philippines
Authors: Payot Betchaida D. , Arai Shoji , Yoshikawa Masako , Tamura Akihiro , Okuno Mitsuru , Rivera Danikko John V.
Published: November 2018

A suite of peridotite xenoliths were collected from lahar flow deposits located close to the summit of Mt. Pinatubo. Spinel harzburgite is the most dominant lithology among dunites, pyroxenites and websterites. A rare spinel lherzolite xenolith (P12-7) is also present in this suite. The spinel lherzolite has well-preserved protogranular texture with very minimal presence of secondary amphibole, low Cr# in the chromian spinel, and depleted and hump shaped patterns of chondrite-normalized rare earth element (REE) patterns for the clinopyroxenes. In contrast, the spinel harzburgites contain abundant secondary amphiboles and orthopyroxenes, higher Cr# in the spinel, and slightly elevated patterns for the chondrite-normalized REE patterns for the amphiboles. The spinel lherzolite also exhibits higher olivine Fo content for a given spinel Cr# compared to the spinel harzburgites. The spinel lherzolite is interpreted as a typical residue from partial melting of abyssal peridotites whereas the spinel harzburgites may have formed via partial melting with subsequent modification during the influx of fluids in the mantle wedge. Our results suggest that fragments of MOR-derived lithosphere exist in the mantle wedge beneath the Philippine island arc. This work provides evidence for the conversion of abyssal to arc peridotites in the mantle wedge.
Ore Genesis and Geodynamic Setting of Laochang Ag-Pb-Zn-Cu Deposit, Southern Sanjiang Tethys Metallogenic Belt, China: Constraints from Whole Rock Geochemistry, Trace Elements in Sphalerite, Zircon U-Pb Dating and Pb Isotopes
Authors: Wei Chen , Ye Lin , Huang Zhilong , Gao Wei , Hu Yusi , Li Zhenli , Zhang Jiawei
Published: November 2018

The Laochang Ag-Pb-Zn-Cu deposit, located in the southern margin of the Sanjiang Tethys Metallogenic Belt (STMB), is the typical Ag-Pb-Zn-Cu deposit in this region. Its orebodies are hosted in the Carboniferous Yiliu Formation volcanic-sedimentary cycle and occur as stratiform, stratoid and lenticular. Whether or not the stratabound ore belong to the volcanogenic massive sulfide (VMS) deposit remains unclear and controversial. In this paper, the whole rock geochemistry, trace elements in sphalerite, U-Pb zircon chronology and Pb isotopes were investigated, aiming to provide significant insights into the genesis and geodynamic setting of the Laochang deposit. Lead isotope ratios of pyrite and sphalerite from the stratabound ore are 18.341 to 18.915 for 206Pb/204Pb; 15.376 to 15.770 for 207Pb/204Pb; and 38.159 to 39.200 for 208Pb/204Pb—which display a steep linear trend on Pb-Pb diagrams. This indicates a binary mixing of lead components derived from leaching between the host volcanic rock and mantle reservoir. Sphalerite from stratabound ores is relatively enriched in Fe, Mn, In, Sn, and Ga—similar to typical VMS deposits. Moreover, the Carboniferous volcanic rock hosting the stratabound Ag-Pb-Zn-Cu ores has a zircon U-Pb age of 312 ± 4 Ma; together with previous geochronological and geological evidences, thus, we consider that the stratabound mineralization occur in the Late Paleozoic (~323–308 Ma). Collectively, these geologic, geochemical, and isotopic data confirm that the stratabound ores should be assigned to Carboniferous VMS mineralization. In addition, volcanic rocks hosting the stratabound ore exhibit elevated high field strength elements (HFSEs, Nb, Ta, Zr and Hf) abundance, slight enrichment of light rare earth element (LREE), and depletion of Ba and Sr with obvious Nb-Ta anomalies. Such characteristics suggest that their magma is similar to typical oceanic island basalt. In addition, the oceanic island basalt (OIB)-like volcanic rocks were formed at Late Paleozoic, which could be approximately synchronous with the VMS mineralization at Laochang. Thus, it is suggested that the Laochang VMS mineralization was generated in the oceanic island setting prior to the initial subduction of the Changning-Menglian Paleo-Tethys Ocean.
Bioactive Natural Spirolactone-Type 6,7-seco-ent-Kaurane Diterpenoids and Synthetic Derivatives
Authors: Li Haonan , Jiao Runwei , Mu Jiahui , Xu Shengtao , Li Xu , Wang Xianhua , Li Zhanlin , Xu Jinyi , Hua Huiming , Li Dahong
Published: November 2018

Diterpenoids are widely distributed natural products and have caused considerable interest because of their unique skeletons and antibacterial and antitumor activities and so on. In light of recent discoveries, ent-kaurane diterpenoids, which exhibit a wide variety of biological activities, such as anticancer and anti-inflammatory activities, pose enormous potential to serve as a promising candidate for drug development. Among them, spirolactone-type 6,7-seco-ent-kaurane diterpenoids, with interesting molecular skeleton, complex oxidation patterns, and bond formation, exhibit attractive activities. Furthermore, spirolactone-type diterpenoids have many modifiable sites, which allows for linking to various substituents, suitable for further medicinal study. Hence, some structurally modified derivatives with improved cytotoxicity activities are also achieved. In this review, natural bioactive spirolactone-type diterpenoids and their synthetic derivatives were summarized.
Nano-Mediated Photodynamic Therapy for Cancer: Enhancement of Cancer Specificity and Therapeutic Effects
Authors: Mfouo Tynga Ivan , Abrahamse Heidi
Published: November 2018

Deregulation of cell growth and development lead to cancer, a severe condition that claims millions of lives worldwide. Targeted or selective approaches used during cancer treatment determine the efficacy and outcome of the therapy. In order to enhance specificity and targeting and obtain better treatment options for cancer, novel modalities are currently under development. Photodynamic therapy has the potential to eradicate cancer, and combination therapy would yield even greater outcomes. Nanomedicine-aided cancer therapy shows enhanced specificity for cancer cells and minimal side-effects coupled with effective cancer destruction both in vitro and in vivo. Nanocarriers used in drug-delivery systems are very capable of penetrating the cancer stem cell niche, simultaneously killing cancer cells and eradicating drug-resistant cancer stem cells, yielding therapeutic efficiency of up to 100-fold against drug-resistant cancer in comparison with free drugs. Safety precautions should be considered when using nano-mediated therapy as the effects of extended exposure to biological environments are still to be determined.
Effect of SiO2 Nanoparticles on the Performance of PVdF-HFP/Ionic Liquid Separator for Lithium-Ion Batteries
Authors: Caimi Stefano , Klaue Antoine , Wu Hua , Morbidelli Massimo
Published: November 2018

Safety concerns related to the use of potentially explosive, liquid organic electrolytes in commercial high-power lithium-ion batteries are constantly rising. One promising alternative is to use thermally stable ionic liquids (ILs) as conductive media, which are however, limited by low ionic conductivity at room temperature. This can be improved by adding fillers, such as silica or alumina nanoparticles (NPs), in the polymer matrix that hosts the IL. To maximize the effect of such NPs, they have to be uniformly dispersed in the matrix while keeping their size as small as possible. In this work, starting from a water dispersion of silica NPs, we present a novel method to incorporate silica NPs at the nanoscale level (<200 nm) into PVdF-HFP polymer clusters, which are then blended with the IL solution and hot-pressed to form separators suitable for battery applications. The effect of different amounts of silica in the polymer matrix on the ionic conductivity and cyclability of the separator is investigated. A membrane containing 10 wt.% of silica (with respect to the polymer) was shown to maximize the performance of the separator, with a room temperature ionic conductivity of of 1.22 mS cm − 1 . The assembled half-coin cell with LiFePO 4 and Li as the cathode and the anode exhibited a capacity retention of more than 80% at a current density of 2C and 60 ∘ C.
WS(1−x)Sex Nanoparticles Decorated Three-Dimensional Graphene on Nickel Foam: A Robust and Highly Efficient Electrocatalyst for the Hydrogen Evolution Reaction
Authors: Hussain Sajjad , Akbar Kamran , Vikraman Dhanasekaran , Afzal Rana Arslan , Song Wooseok , An Ki-Seok , Farooq Ayesha , Park Jun-Young , Chun Seung-Hyun , Jung Jongwan
Published: November 2018

To find an effective alternative to scarce, high-cost noble platinum (Pt) electrocatalyst for hydrogen evolution reaction (HER), researchers are pursuing inexpensive and highly efficient materials as an electrocatalyst for large scale practical application. Layered transition metal dichalcogenides (TMDCs) are promising candidates for durable HER catalysts due to their cost-effective, highly active edges and Earth-abundant elements to replace Pt electrocatalysts. Herein, we design an active, stable earth-abundant TMDCs based catalyst, WS(1−x)Sex nanoparticles-decorated onto a 3D porous graphene/Ni foam. The WS(1−x)Sex/graphene/NF catalyst exhibits fast hydrogen evolution kinetics with a moderate overpotential of ~−93 mV to drive a current density of 10 mA cm−2, a small Tafel slope of ~51 mV dec−1, and a long cycling lifespan more than 20 h in 0.5 M sulfuric acid, which is much better than WS2/NF and WS2/graphene/NF catalysts. Our outcomes enabled a way to utilize the TMDCs decorated graphene and precious-metal-free electrocatalyst as mechanically robust and electrically conductive catalyst materials.
The Effect of Ni Addition onto a Cu-Based Ternary Support on the H2 Production over Glycerol Steam Reforming Reaction
Authors: Polychronopoulou Kyriaki , Charisiou Nikolaos , Papageridis Kyriakos , Sebastian Victor , Hinder Steven , Dabbawala Aasif , AlKhoori Ayesha , Baker Mark , Goula Maria
Published: November 2018

In the present study, Ni/Ce-Sm-xCu (x = 5, 7, 10 at.%) catalysts were prepared using microwave radiation coupled with sol-gel and followed by wetness impregnation method for the Ni incorporation. Highly dispersed nanocrystallites of CuO and NiO on the Ce-Sm-Cu support were found. Increase of Cu content seems to facilitate the reducibility of the catalyst according to the H2 temperature-programmed reduction (H2-TPR). All the catalysts had a variety of weak, medium and strong acid/basic sites that regulate the reaction products. All the catalysts had very high XC3H8O3 for the entire temperature (400–750 °C) range; from ≈84% at 400 °C to ≈94% at 750 °C. Ni/Ce-Sm-10Cu catalyst showed the lowest XC3H8O3-gas implying the Cu content has a detrimental effect on performance, especially between 450–650 °C. In terms of H2 selectivity (SH2) and H2 yield (YH2), both appeared to vary in the following order: Ni/Ce-Sm-10Cu > Ni/Ce-Sm-7Cu > Ni/Ce-Sm-5Cu, demonstrating the high impact of Cu content. Following stability tests, all the catalysts accumulated high amounts of carbon, following the order Ni/Ce-Sm-5Cu < Ni/Ce-Sm-7Cu < Ni/Ce-Sm-10Cu (52, 65 and 79 wt.%, respectively) based on the thermogravimetric analysis (TGA) studies. Raman studies showed that the incorporation of Cu in the support matrix controls the extent of carbon graphitization deposited during the reaction at hand.
Nanoscale Morphology, Interfacial Hydrogen Bonding, Confined Crystallization and Greatly Improved Toughness of Polyamide 12/Polyketone Blends
Authors: Li Siyuan , Yang Yan , Zha Xiangjun , Zhou Yicun , Yang Wei , Yang Mingbo
Published: November 2018

Nanostructured polyamide 12(PA12)/polyketone (PK) blends were fabricated by melt compounding. The nanoscale droplet and domain-in-domain morphologies depending on PK content were observed. When the content of PK was 10 vol %, the impact strength of the blend jumped from 6.8 to 111.9 kJ/m2 and further improved with an increasing content of PK. The toughening mechanism was found to be closely related with the morphology change from nanoscale droplet morphology to domain-in-domain morphology owing to the strong interfacial hydrogen bonding. The nanoscale morphology confinement and interfacial hydrogen bonding enhances the crystallization kinetics, while it lowers down the thermodynamic stability of the crystals. The toughening mechanisms were discussed based on these factors.
Motility Disorders in Celiac Disease and Non-Celiac Gluten Sensitivity: The Impact of a Gluten-Free Diet
Authors: Usai-Satta Paolo , Oppia Francesco , Lai Mariantonia , Cabras Francesco
Published: November 2018

Background: There is evidence that digestive motor disorders are frequently present in untreated celiac disease (CD) patients. Similarly, non-celiac gluten sensitivity (NCGS) can be associated with gut motor disorders. In both cases, gut dysmotility can improve or be completely reversed with a gluten-free diet (GFD). Methods: A literature search for motility disorders in CD and NCGS patients was carried out using the online databases PubMed, Medline and Cochrane. Results: Esophageal, gastric, small bowel and gallbladder motor disorders are common in both children and adults with CD. Although the clinical consequences of these disorders are not clearly defined, gastric dysfunction could affect drug absorption and metabolism in the thyroid and neurological conditions associated with CD. The impact of a GFD on motility disorders is, however, controversial. No systematic studies are available on NCGS. NCGS frequently overlaps with irritable bowel syndrome (IBS) and similar pathophysiological mechanisms may be hypothesized. Conclusions: Mucosal damage may affect gut motility in untreated CD through perturbation of hormonal and neuro-immunomodulatory regulation. A persistent low-grade mucosal inflammation could explain the cases of persistent motor disorders despite a GFD. Further studies are needed to definitely assess the role of gut motor disorders in NCGS.
Latent Iron Deficiency as a Marker of Negative Symptoms in Patients with First-Episode Schizophrenia Spectrum Disorder
Authors: Kim Sung-Wan , Stewart Robert , Park Woo-Young , Jhon Min , Lee Ju-Yeon , Kim Seon-Young , Kim Jae-Min , Amminger Paul , Chung Young-Chul , Yoon Jin-Sang
Published: November 2018

Iron deficiency may alter dopaminergic transmission in the brain. This study investigated whether iron metabolism is associated with negative symptoms in patients with first-episode psychosis. The study enrolled 121 patients with first-episode schizophrenia spectrum disorder, whose duration of treatment was 2 months or less. Negative symptoms were measured using the Positive and Negative Syndrome Scale (PANSS) and Clinician-Rated Dimensions of Psychosis Symptom Severity (Dimensional) scale of the Diagnostic and Statistical Manual of Mental Disorders, Fifth Edition (DSM-5). Prominent negative symptoms were defined as moderate or severe negative symptoms on the Dimensional scale of the DSM-5. Iron deficiency was defined as a serum ferritin ≤ 20 ng/mL. Patients with iron deficiency were significantly more likely to have prominent negative symptoms (45.2 vs. 22.2%; p = 0.014) and a higher PANSS negative symptoms score (p = 0.046) than those with normal ferritin levels. Patients with prominent negative symptoms had significantly lower ferritin levels (p = 0.025). The significance of these results remained after controlling for the duration of illness and other confounding variables. Our finding of an independent association between iron deficiency and negative symptoms in patients at the very early stage of illness implies that iron dysregulation has an effect on negative symptoms in patients with schizophrenia. The possibility of therapeutic intervention with iron should be further investigated.
Kiwifruit Exchanges for Increased Nutrient Richness with Little Effect on Carbohydrate Intake, Glycaemic Impact, or Insulin Response
Authors: Monro John , Bentley-Hewitt Kerry , Mishra Suman
Published: November 2018

Background: Kiwifruit are nutrient-rich and have properties which indicate a low glycaemic impact compared with many cooked cereal foods, suggesting that they may be used for dietary enrichment of vitamin C without glycaemic cost. Aim: To develop tables for equi-carbohydrate and equi-glycaemic partial exchange of kiwifruit for glycaemic carbohydrate foods. Method: The available carbohydrate content of Zespri® Green and Zespri® SunGold kiwifruit was determined as sugars released during in vitro digestive analysis. Glycaemic potency was determined as grams of glucose equivalents (GGEs) in a clinical trial using 200 g (a two-kiwifruit edible portion) of each cultivar, non-diabetic subjects (n = 20), and a glucose reference. GGE values were also estimated for a range of carbohydrate foods in the New Zealand Food Composition Database for which available carbohydrate and glycaemic index values were available. The values allowed exchange tables to be constructed for either equi-carbohydrate or equi-glycaemic partial exchange of kiwifruit for the foods. Results: GGE values of both kiwifruit cultivars were low (“Hayward”, 6.6 glucose equivalents/100 g; “Zesy002”, 6.7 glucose equivalents/100 g). Partial equi-carbohydrate substitution of foods in most carbohydrate food categories substantially increased vitamin C with little change in glycaemic impact, while equi-glycaemic partial substitution by kiwifruit could be achieved with little change in carbohydrate intake. Conclusion: Equi-carbohydrate partial exchange of kiwifruit for starchy staple foods is a means of greatly increasing nutrient richness in a diet without the physiological costs of increased glycaemia and insulin responses or carbohydrate intake.
Herbs and Spices in the Treatment of Functional Gastrointestinal Disorders: A Review of Clinical Trials
Authors: Fifi Amanda C. , Axelrod Cara Hannah , Chakraborty Partha , Saps Miguel
Published: November 2018

More than fifty percent of all new patient visits to pediatric gastroenterology clinics consult for functional abdominal pain disorders (FAPDs). In 2005, a technical report of the American Academy of Pediatrics and the North American Pediatric Gastroenterology, Hepatology and Nutrition society (NASPGHAN) found limited or inconclusive evidence for most therapeutic interventions for this group of disorders. The report did not include studies on herbs and spices. Since then, there has been an increasing interest in the use of complementary and alternative medicine (CAM) for the treatment of chronic pain disorders in children. About 40% of parents of pediatric gastroenterology patients have utilized CAM. This review evaluated the published literature on the effectiveness of CAM, specifically the use of herbs and spices, for the treatment of FAPDs. We found little evidence for most of the commonly used herbs and spices. Despite its common use, research on the efficacy, safety, and optimal dosage remains limited. There is evidence to suggest the benefit of peppermint oil and STW 5 for the treatment of FAPDs in children. The paucity of data on most therapies underscores the need for large clinical trials to assess their efficacy.
Zwitterionic Cysteine Drug Coating Influence in Functionalization of Implantable Ti50Zr Alloy for Antibacterial, Biocompatibility and Stability Properties
Authors: Demetrescu Ioana , Dumitriu Cristina , Totea Georgeta , Nica Cristina I. , Dinischiotu Anca , Ionita Daniela
Published: November 2018

The present paper aims atincreasing the bioperformance of implantable Ti50Zr alloy using zwitterionic cysteine drug coating. Aspects such as stability, biocompatibility, and antibacterial effects were investigated with the help of various methods such as infrared spectroscopy (FT-IR), scanning electronic microscopy (SEM), electrochemical methods, contact angle determinations and cell response. The experimental data of zwitterionic cysteine coating indicate the existence of a hydration layer due to hydrophilic groups evidenced in FT-IR which is responsible for the decrease of contact angle and antibacterial capabilities. The electrochemical stability was evaluatedbased on Tafel plots and electrochemical impedance spectroscopy (EIS). The cell response to cysteine was determined with gingival fibroblasts measuring lactate dehydrogenase (LDH) activity, concentrations of nitric oxide (NO) and intracellular level of reactive oxygen species (ROS). All experimental results supported the increase of stability and better cells response of implantable Ti50Zr alloy coated with zwitterionic cysteine drug. The antibacterial index was measured against Staphylococcus aureus and Escherichia coli. It was demonstrated that the coating enhanced the production of intracellular ROS in time, which subsequently caused a significant increase in antibacterial index.
Multiscale Modification of Populus cathayana by Alkali Lignin Combined with Heat Treatment
Authors: Zhou Haizhen , Li Jingyu , Ma Erni
Published: November 2018

Chemical modification of wood with green modifiers is highly desirable for sustainable development. With the aim of enhancing the water resistance and dimensional stability of fast growing wood, modifications were conducted using renewable and toxicity-free industrial lignin combined with heat treatment. Poplar (Populus cathayana) samples first underwent impregnation with alkali lignin solution and were then subjected to heat treatment at 140–180 °C for two hours. The results indicated that the modified wood showed excellent leaching resistance. The alkali lignin treatment improved surface hydrophobicity and compression strength, and decreased moisture and water uptake, thereby reducing the dimensional instability of modified wood. These changes became more pronounced as the heat-treating temperature increased. Scanning electron microscopy, confocal laser scanning microscopy, and Fourier transform infrared spectroscopy evidenced that a multiscale improvement of the alkali lignin occurred in the cell lumen and cell wall of wood fibers and vessels, with small alkali lignin molecules reacting with the wood matrix. This study paves the way for developing an effective modification approach for fast growing wood, as well as promoting the reuse of industrial lignin for high-value applications, and improves the sustainable development of the forestry industry.
Strategies Christian Nurses Use to Create a Healing Environment
Authors: Pfeiffer Jane
Published: November 2018

From Nightingale forward, nursing has understood that interaction of person, nurse, and environment facilitates optimal outcomes. Yet, there remains a need for research on the paradigm concept of environment and creation of a healing environment. This classical, grounded theory study aimed to identify (1) strategies Christian nurses used to create a healing environment and enhance well-being, (2) outcomes they perceived resulting from these strategies, and (3) factors they regarded as either enhancing or inhibiting the creation of the healing environments. A criterion-based, purposive sample of Christian nurses (N = 15) was interviewed between June 2013 and January 2014 until data saturation was reached. Data were analyzed using constant comparative methods in consultation with a grounded theory expert. “Charting the healing path,” the core category, consists of four phases: helping patients get better, fostering the healing environment, charting a healing path, and observing outcomes. The “charting the healing path” model informs development of the environment domain of nursing knowledge. Knowing the patient, the juncture of nurse and patient points of view, and the resultant nurse–patient partnership promote best potential outcomes to be realized incrementally during, and after, hospitalization.
Assessing Pasture Degradation in the Brazilian Cerrado Based on the Analysis of MODIS NDVI Time-Series
Authors: Pereira Osvaldo , Ferreira Laerte , Pinto Flávia , Baumgarten Leandro
Published: November 2018

Around 55% of all Brazilian cattle production is located in the Cerrado biome, which also contains the largest pasture area in Brazil. Previous studies indicated that about 60% of these pastures were degraded by 2010. However, up-to-date and more precise estimates are necessary to access the extent and degree of degradation of the Cerrado pastures, since these areas constitute strategic land reserves for both livestock intensification and soybean expansion. Therefore, in this study, we estimated the area of degraded pastures in the Cerrado by analyzing the trends of cumulative NDVI anomalies over time used as a proxy for pasture degradation. The generated slope surface was segmented into two classes, comprising non-degraded and degraded pastures, which were correlated with socio-economic and biophysical variables. According to our study, around 39% of the Cerrado pastures are currently degraded, encompassing 18.2 million hectares, mostly in areas with a cattle carrying capacity below 1.0 AU ha−1. These areas, distributed in the northwest Cerrado, mostly within the Brazilian states of Maranhão, Piauí, and Bahia (i.e., Matopiba region), tend to be associated with decreasing rainfall patterns and low investments in soil conservation practices. The degraded areas also tend to be concentrated in municipalities with low human development indices (HDI).
Downscaling of Satellite OPEMW Surface Rain Intensity Data
Authors: Cersosimo Angela , Larosa Salvatore , Romano Filomena , Cimini Domenico , Di Paola Francesco , Gallucci Donatello , Gentile Sabrina , Geraldi Edoardo , Teodosio Nilo Saverio , Ricciardelli Elisabetta , Ripepi Ermann , Viggiano Mariassunta
Published: November 2018

This paper presents a geostatistical downscaling procedure to improve the spatial resolution of precipitation data. The kriging method with external drift has been applied to surface rain intensity (SRI) data obtained through the Operative Precipitation Estimation at Microwave Frequencies (OPEMW), which is an algorithm for rain rate retrieval based on Advanced Microwave Sounding Units (AMSU) and Microwave Humidity Sounder (MHS) observations. SRI data have been downscaled from coarse initial resolution of AMSU-B/MHS radiometers to the fine resolution of Spinning Enhanced Visible and InfraRed Imager (SEVIRI) flying on board the Meteosat Second Generation (MSG) satellite. Orographic variables, such as slope, aspect and elevation, are used as auxiliary data in kriging with external drift, together with observations from Meteosat Second Generation-Spinning Enhanced Visible and InfraRed Imager (MSG-SEVIRI) in the water vapor band (6.2 µm and 7.3 µm) and in thermal-infrared (10.8 µm and 8.7 µm). The validation is performed against measurements from a network of ground-based rain gauges in Southern Italy. It is shown that the approach provides higher accuracy with respect to ordinary kriging, given a choice of auxiliary variables that depends on precipitation type, here classified as convective or stratiform. Mean values of correlation (0.52), bias (0.91 mm/h) and root mean square error (2.38 mm/h) demonstrate an improvement by +13%, −37%, and −8%, respectively, for estimates derived by kriging with external drift with respect to the ordinary kriging.
Editorial for Special Issue “Optical Remote Sensing of Boreal Forests”
Authors: Rautiainen Miina , Pisek Jan
Published: November 2018

Boreal forests (or taiga) are the world’s largest terrestrial biome and represent one third of the world’s forest cover. [...]
Structural and Spectral Analysis of Cereal Canopy Reflectance and Reflectance Anisotropy
Authors: Kuester Theres , Spengler Daniel
Published: November 2018

The monitoring of agricultural areas is one of the most important topics for remote sensing data analysis, especially to assist food security in the future. To improve the quality and quantify uncertainties, it is of high relevance to understand the spectral reflectivity regarding the structural and spectral properties of the canopy. The importance of understanding the influence of plant and canopy structure is well established, but, due to the difficulty of acquiring reflectance data from numerous differently structured canopies, there is still a need to study the structural and spectral dependencies affecting top-of-canopy reflectance and reflectance anisotropy. This paper presents a detailed study dealing with two fundamental issues: (1) the influence of plant and canopy architecture changes due to crop phenology on nadir acquired cereal top-of-canopy reflectance, and (2) the anisotropic reflectance of cereal top-of-canopy reflectance and its inter-annual variations as affected by varying contents of biochemical constituents and changes on canopy structure across green phenological stages between tillering and inflorescence emergence. All of the investigations are based on HySimCaR, a computer-based approach using 3D canopy models and Monte Carlo ray tracing (drat). The achieved results show that the canopy architecture significantly influences top-of-canopy reflectance and the bidirectional reflectance function (BRDF) in the VNIR (visible and near infrared), and SWIR (shortwave infrared) wavelength ranges. In summary, it can be said that the larger the fraction of the radiation reflected by the plants, the stronger is the influence of the canopy structure on the reflectance signal. A significant finding for the anisotropic reflectance is that the relative row orientation of the cereal canopies is mapped in the 3D-shape of the BRDF. Summarised, this study provides fundamental knowledge for improving the retrieval of biophysical vegetation parameters of agricultural areas for current and upcoming sensors with large FOV (field of view) with respect to the quantification of uncertainties.