bluuebunny/crossref_metadata_2025 huggingface dataset:
Challenges and contradictions in the development of the North and the Arctic: demographic dimension
Authors:   Institute of socio-economic and energy problems of the North, Komi Science Centre Ural Branch of the RАS, Fauzer V.V. , Smirnov A.V. ,   Institute of socio-economic and energy problems of the North, Komi Science Centre Ural Branch of the RАS, Lytkina T.S. ,   Institute of socio-economic and energy problems of the North, Komi Science Centre Ural Branch of the RАS, Fauzer G.N. ,   Institute of socio-economic and energy problems of the North, Komi Science Centre Ural Branch of the RАS
Published: April 2022

The North and the Arctic have been in the focus of attention of the Russian statehood for more than one century. The North and the Arctic have been in the focus of attention of the Russian statehood for more than one century. They received special attention, provided socio-economic preferences. The North of Russia had a development strategy, a unified legislative base, while the Arctic as part of the North was mostly a transport artery and protective borders of Russia. The situation changed after the separation of the Arctic territories from the North. Since 2014, most of the strategic documents concerned the Arctic, and least of all the northern territories. Artificial competition aroused between the regions for access to material, financial and human resources. The paper identifies the following types of conflicts: between the northern and arctic regions and regions located outside of them; between the Arctic and non-Arctic regions of the Russian North; between indigenous and small-numbered peoples of the North and resource companies; between the indigenous and old-time population and migrants (newcomers). The authors outline that the allocation of the Arctic territories also determined a different development vector of the Arctic and the North of Russia. The economy of the Arctic more often represent large corporations, and own funds of enterprises dominate in the structure of investments in the Arctic regions; in the regions of the North, the structure of investments is more dispersed, less concentrated and corporate. The Arctic settlement system includes large, medium and small industrial cities and single-industry settlements, stationary and rotational; in the North, there are more agricultural villages, administrative regional centers and service settlements. The Arctic settlement system, in comparison with the northern one, is generally urban, more concentrated, more industrial and less settled. The viewpoint on the overpopulation of territories and the need to “unload” the network of settlements already created here, on the need for a total transition to a rotational model of development has more grounds in the North than in the Arctic.
A CONCEPTUAL APPROACH TO THE SMART PARADIGM IN THE DIGITAL ECONOMY
Authors:   Odesа Polytechnic National University, Yatskevych Inna
Published: April 2022

The purpose of the work is to study the SMART-paradigm in the digital economy and draw certain conclusions. The paper defines the influence of information and communication technologies on the development of the digital economy. Thus, in recent decades, information and communication technologies have become the main driver of innovation and stimulating changes in organizations (companies, other institutions) and the development of innovative production in smart factories. This situation contributes to the development of innovations and the formation of the SMART-paradigm. The paper studies the evolution of the formation of the concept of "SMART" and systematizes the directions of the concept of the SMART- paradigm (smart environment, smart country, smart city, smart housing, smart country). In scientific sources, it is noted that the SMART-paradigm is characterized by: self-adjustment, self-adaptation, self-configuration, self- control, self-healing, independent functioning, which is the source of self- organization and the process of new quality and the development of structures and systems that require "smart organizations" that support the development of e-commerce technologies and digital business using the high-performance computing systems and networks needed to dynamically respond to changing economic trends. It is substantiated that the emergence and development of the SMART- paradigm is due to the replacement of the industrial economy with a digital economy with the increasing influence of digital technologies on business processes of companies and production. The paper notes that SMART- technologies involve the use of computer systems and microprocessors to perform daily tasks and exchange information. SMART-technologies today are directly interconnected with a person, with analogues of his replacement in the process of their functioning. The "human component" in the content and functioning of SMART-technologies is constantly demonstrated. The problems of the development of SMART-technologies in modern conditions (legal, organizational, methodological, informational) are systematized and investigated. It is determined that the development of SMART-technologies contributed to the formation of the principles of the SMART-paradigm in the digital economy - smart organization, smart company, smart factory.
ASSESSMENT OF ENTERPRISE’S COMPETITIVENESS
Authors:   O. M. Beketov National University of Urban Economy in Kharkiv, Tsyhenko Anna
Published: April 2022

The article analyzes the conceptual approaches to the formation of a system for ensuring the competitiveness of economic entities in the face of new challenges, taking into account the future prospects of economic development. An important element in the formation of competitiveness in martial law were not only indicators of efficiency of the enterprise, but also the type of activity. The article notes that construction companies are most relevant in the period of military conflicts and the postwar period. The construction industry is the basis for the formation of a system of restoration of peaceful life, restoration of residential, industrial, and later commercial real estate, material and technical base. Thus, the article assessed the competitiveness of construction companies in order to determine their potential to work in the new large, which is highly relevant. The main tasks of assessing the competitiveness of a construction company were identified as a set of factors that affect the final indicators (results) of the enterprise. The article proposes an algorithm for assessing the competitiveness of the enterprise by the method of in-depth analysis of the financial and economic condition of insolvent enterprises. The main objectives of the analysis of competitiveness by the proposed method are the dynamics and currency structure of the balance sheet of the enterprise; sources of own funds; structure of accounts payable; asset structure; profitability of the enterprise. To fully analyze the competitiveness of the enterprise, the following indicators were calculated and conclusions were made on the impact of their change on the economic situation: autonomy ratio, financial stability ratio, working capital turnover ratio, working capital turnover time, inventory turnover ratio, inventory turnover time and others. The efficiency of the enterprise and its competitiveness are determined by rating based on a comprehensive analysis. The article proposes a comprehensive algorithm for assessing the competitiveness rating of construction companies based on data from financial and economic work and planning, which allows to ensure mobility, system, multifunctionality and integration of competitiveness assessment processes. The results of the study can be used by construction companies, customers, developers, investors, suppliers and other stakeholders engaged in construction activities.
PROSECUTOR'S OFFICE IN THE MECHANISM OF SEPARATION OF POWERS IN UKRAINE
Authors:   Lviv State University of Internal Affairs, Kovaliv Myroslav , Skrynkovskyy Ruslan ,   Lviv University of Business and Law, Yesimov Serhii ,   Lviv State University of Internal Affairs, Nazar Yurii ,   Lviv State University of Internal Affairs, Khmyz Mariana ,   Ivan Franko National University of Lviv, Yosyfovych Danylo ,   Lviv State University of Internal Affairs, Tyrkalo Yuriy ,   Lviv Polytechnic National University, Kaydrovych Khrystyna ,   Lviv University of Business and Law
Published: April 2022

The article with the use of a comprehensive systematic analysis of legal phenomena, in the context of the Constitution of Ukraine, current legislation, considers the role and place of the prosecutor's office in the mechanism of separation of powers. The urgency of the study is due to the participation of the Prosecutor's Office of Ukraine in the state mechanism for ensuring and protecting the rights and freedoms of citizens, which has scientific- theoretical and practical significance. It is noted that the Prosecutor's Office of Ukraine is one of the main law enforcement agencies, whose activities are aimed at ensuring the protection of human and civil rights and freedoms. In the system of separation of powers, the prosecutor's office occupies a secluded place. This definition of the legal status allows the prosecutor's office to more effectively perform the main task – the protection of the rights and freedoms of citizens. It is the independence of the prosecutor's office that is a necessary condition for ensuring the protection of constitutional rights. It is stated that the current stage of development of the prosecutor's office indicates constant changes in its legal status. This means that there is no ideal prosecutor's office, because the legislation and society in the country are developing dynamically and bringing the law on the prosecutor's office in line with the realities of life is a regularity. Specific features of the prosecutorial power indicate that it should be part of the system of checks and balances in relations with branches of government.
PUBLIC ADMINISTRATION IN THE FIELD OF DEVELOPMENT OF EDUCATIONAL HEALTH SPACE IN UKRAINE
Authors:   Interregional Academy of Personnel Management, Oleksiienko Oleksandra
Published: April 2022

The position on the construction of the optimal strategy of changes in education as a complex area of security significance, given its specifics (scale, conservatism, inertia) is substantiated. Scientific definitions and approaches to the concept of «health» are analyzed, on the basis of which it is necessary to introduce it into the state discourse. Attention is paid to the analysis of factors that influence the formation of public administration by creating an educational health space. Emphasis is placed on the introduction of state health programs, as innovative strategies for marketing management and logistics consulting, making appropriate decisions. The practice of public health management in foreign countries is covered. The legal aspects of public-private partnership in the implementation of the creation of a healthy educational space in Ukraine are revealed. Analysis of trends in the improvement of public administration technologies for the preservation of human health, strengthening and shaping the health of the younger generation and their effective implementation in the life of each individual through education, upbringing and culture; disseminating and promoting the skills of a healthy lifestyle, conscious responsibility of the community and the individual for maintaining and improving their own health and the health of family members; formation of strategic health-preserving potential in the field of education in Ukraine.
Application of High Pressure and Near-Critical Fluids, NCF's – a Tool for Novel Processes in Roche
Authors: Tiegs Carsten
Published: April 2022

The development of new processes by means of near-critical fluids, NCF's, has gained increasing importance in the last few years. These processes include physical separation processes for especially thermolabile substances as well as chemical reactions in and with NCF's.In this contribution, a short phenomenological description of the physical properties of near-critical fluids is given and their influence on the other compounds is discussed. Some general considerations with respect to high-pressure applications of NCF' s along with a rough overwiew of Roche activities in this field are described.
Synthesis and styrene copolymerization of bromo, chloro, and fluoro ring-substituted 2-methoxyethyl phenylcyanoacrylates
Authors: Aviles Fernanda , Lee Grace D. , Madrid Mae I. Z. , Maya Jullisa J. , Nuelle Andrew S. , Padilla Nancy , Pappas Gia K. , Patel Rechal K. , Schroeder Emily , Shethwala Farheen , Villa Jordan , Villegas Misael , Rocus Sara M. , Schjerven William S. , Kharas Gregory B
Published: April 2022

Novel halogen ring-substituted 2-methoxyethyl phenylcyanoacrylates, RPhCH=C(CN)CO2CH2CH2OCH3 (where R is 2-bromo, 3-bromo, 4-bromo, 2-chloro, 3-chloro, 4-chloro, 2-fluoro, 3-fluoro, 4-fluoro, 2-trifluoromethyl, 3-trifluoromethyl, 4-trifluoromethyl) were prepared and copolymerized with styrene. The acrylates were synthesized by the piperidine catalyzed Knoevenagel condensation of ring-substituted benzaldehydes and 2-methoxyethyl cyanoacetate, and characterized by CHN analysis, IR, 1H and 13C NMR. All the acrylates were copolymerized with styrene in solution with radical initiation (ABCN) at 70C. The compositions of the copolymers were calculated from nitrogen analysis.
Rapid Online Oxidation of Proteins and Peptides via Electrospray-Accelerated Ozonation
Authors: Borotto Nicholas , Richards Talitha
Published: April 2022

When combined with mass spectrometry, solution-phase labeling such as oxidative foot printing, hydrogen/deuterium exchange, and covalent labeling are powerful tools for the analysis of protein conformation. The throughput of these work-flows, however, is frequently limited due to their reliance on slow labeling reactions, proteolysis, and chromatographic separations to be fully realized. Here, we present an ozone-driven oxidation reaction that occurs on the microsecond time-scale during the electrospray ionization (ESI) process. Selective oxidation of methionine and tryptophan residues in pep-tides and proteins occurs spontaneously upon the introduction of ozone into the ESI chamber. Trp and Met residues are frequently buried in folded proteins and thus, when applied to natively folded cytochrome C and carbonic anhydrase, little oxidation is observed. When these proteins are denatured and ozonated, a dramatic increase in the number of oxidation events and yield is measured. This methodology’s applicability to any instrument equipped with an ESI source, facile interpretation of results, limited sample handling, high-throughput nature, and rapid labeling reaction makes this technique a promising new tool for the analysis of protein folding.
Conformational energy benchmark for longer n-alkane chains
Authors: Ehlert Sebastian , Grimme Stefan , Hansen Andreas
Published: April 2022

We present the first benchmark set focusing on the conformational energies of highly flexible, long n-alkane chains, termed ACONFL. Unbranched alkanes are ubiquitous building blocks in nature, so the goal is to be able to calculate their properties most accurately to improve the modeling of, e.g, complex (biological) systems. Very accurate DLPNO-CCSD(T1)/CBS reference values are provided, which allow for a statistical meaningful evaluation of even the best available density functional methods. The performance of established and modern (dispersion corrected) density functionals is comprehensively assessed. The recently introduced r²SCAN-V functional shows excellent performance, similar to efficient composite DFT methods like B97-3c and r²SCAN-3c, which provide an even better cost-accuracy ratio, while almost reaching the accuracy of much more computationally demanding hybrid or double hybrid functionals with large QZ AO basis sets. In addition, we investigated the performance of common wavefunction methods, where MP2/CBS surprisingly performs worse compared to simple D4 dispersion corrected Hartree–Fock. Furthermore, we investigate the performance of several semiempirical and force field methods, which are commonly used for the generation of conformational ensembles in multilevel workflows or in large scale molecular dynamics studies. Outstanding performance is obtained by the recently introduced general force field, GFN-FF, while other commonly applied methods like the universal force field yield large errors. We recommend the ACONFL as a helpful benchmark set for parameterization of new semiempirical or force field methods and machine learning potentials as well as a meaningful validation set for newly developed DFT or dispersion methods.
Construction of balanced, chemically dissimilar training, validation and test sets for machine learning on molecular datasets
Authors: Tricarico Giovanni A. , Hofmans Johan , Lenselink Eelke B. , López-Ramos Miriam , Dréanic Marie-Pierre , Stouten Pieter F. W.
Published: April 2022

When preparing training, validation and test sets for machine learning on molecular datasets, it is desirable to combine two requirements: 1) robustness, i.e. making a test set that is chemically dissimilar from the training set; 2) data balance, i.e. ensuring that the proportion of data points and the distribution of data labels (categorical) / data values (continuous) are as homogeneous as possible among the sets, for each individual property to model, while partitioning the overall set of compounds as required. Recent literature shows that meeting both these requirements simultaneously is sometimes very difficult. This is especially true for multi-task learning, but also for single-task learning if one aims to balance the distribution of data labels or values, too. In this work we present a method that resolves this issue by first carrying out a chemistry-guided clustering of the initial dataset to ensure the separation of chemical matter, and subsequently applying linear programming to select the lists of clusters that – once assembled into the final sets – result in the best possible data balance.
Rethinking Modern Hospital Architecture Through COVID-19
Authors: Park Jeffrey KiHyun
Published: April 2022

Lately, the premier ateliers of contemporary architecture -- such as Herzog & de Meuron, or the Office of Metropolitan Architecture -- are showing increasing interest in hospital design, once the realm of highly specialized architectural firms. This trend towards reevaluating hospital design and architecture is most opportune, as the COVID-19 pandemic urges us all to rethink the ways in which our healthcare institutions can be better designed. This commentary is a discussion on the emerging issues of contemporary hospital architecture, especially as reinforced by the pandemic. For instance, while hospital architecture today focuses on individualized care, providing each patient with hotel-like rooms, the pandemic has reminded us of the issue of capacity and inequality in these limited and costly spaces. To what extent should hospitals be centralized or decentralized? Specialized or despecialized? This commentary discusses how COVID-19 has provided insight into some of contemporary hospital architecture’s greatest problems; specifically, it argues that the hospital of the future must exist on a more decentralized platform, both physically and digitally, and be more flexible in function.
The Climate Change- Attributed Economic Cost of Extreme Weather
Authors:   , Newman Rebecca
Published: April 2022

Climate change is changing the nature of extreme weather events across the globe. Extreme event attribution is used to quantify the extent to which anthropogenic climate change is responsible for the change in frequency or severity of a specific extreme weather event. Using this quantification, we can estimate the proportion of economic costs from a specific extreme weather event that are attributable to climate change. However, research is yet to use this approach to estimate the value of climate change-attributed economic costs from extreme weather that have already been experienced globally. In this paper, extreme event attribution data has been collected, allowing us to estimate an average fraction of attributable risk (i.e. the portion of risk for which climate change is responsible) for different classes of extreme weather events – including heatwaves, droughts, floods, storms, wildfires, and cold waves. We then combine this with existing economic cost data from EM-DAT, including the number of deaths (converted using a value of statistical life) and economic damages, to approximate the climate change-attributed global cost of extreme weather using extrapolated reasoning. From this, we estimate that US$2.90 trillion in economic costs from extreme weather are attributable to climate change over the period from 2000 to 2019, equivalent to an annual average cost of US$145 billion. This shows that present estimations of the global cost of climate change are largely underestimated. This attribution-based estimate is higher than estimates from some Integrated Assessment Models, including William Nordhaus’s DICE model, which are designed to measure the total economic impact of climate change inclusive of, but not limited to, extreme weather-related costs. This demonstrates that the crude nature of climate inputs in existing climate-economy modelling has a limited ability to capture costs from tail-end extreme weather events. The experimental attribution-based approach to global estimation is a best first-attempt which provides a new, alternative tool for measuring the costs of climate change.
Massage Therapy to Relieve Menopausal Symptoms: A Systematic Review
Authors: Listiana Eka , Anggorowati Anggorowati , Susilawati Dwi
Published: April 2022

Objective: This study aims to analyze the duration, time, and results of massage therapy in reducing symptoms of menopause. Methods: A systematic review through maternity nursing articles to analyze the effects of massage therapy in reducing menopausal symptoms. The inclusion criteria in this study are 1) related articles about massage therapy. 2) Articles that contain interventions used in reducing menopausal symptoms. 3) Articles use English in writing. 4) Articles published after 2010. 5) Articles published have a complete section. Search articles using electronic databases namely Sciene Direct, Pubmed, PMC, Google Schoolar and Scopus. Articles that meet the inclusion criteria will be collected and analyzed systematically. Results: In a systematic review it is explained that massage therapy can reduce menopausal symptoms but in the location and duration of the intervention still need consideration from further researchers. Conclusion: Based on the results of the study, massage therapy carried out in the back area is recommended to reduce menopausal symptoms.
PENGEMBANGAN E-LKPD BERBASIS PROBLEM SOLVING PADA MATERI PERTUMBUHAN DAN PERKEMBANGAN UNTUK MELATIH KETERAMPILAN BERPIKIR KRITIS SISWA KELAS XII SMA
Authors: Novitasari Febriana , Puspitawati Rinie Pratiwi
Published: April 2022

Berpikir kritis merupakan kemampuan untuk menganalisis, bernalar secara sistematis serta memecahkan masalah. Keterampilan berpikir kritis dapat dilatihkan melalui Lembar Kerja Peserta Didik (LKPD). Oleh sebab itu, pengembangan E-LKPD berbasis problem solving sangat diperlukan guna memenuhi tuntutan pembelajaran abad 21 tentang kecakapan literasi digital pada siswa serta untuk melatih keterampilan berpikir kritis. Tujuan penelitian yaitu untuk menghasilkan E-LKPD berbasis problem solving pada materi pertumbuhan dan perkembangan untuk melatih keterampilan berpikir kritis siswa kelas XII SMA yang layak ditinjau dari validitas, kepraktisan, dan keefektivan. Penelitian ini merupakan jenis penelitian pengembangan dengan model ADDIE (Analysis, Design, Development, Implementation, and Evaluation).   Data yang diperoleh berupa validitas ditinjau berdasarkan aspek tampilan, isi, serta bahasa oleh ahli media dan ahli materi, kepraktisan ditinjau berdasarkan aktivitas dan respons siswa terhadap penggunaan E-LKPD, sedangkan keefektivan ditinjau berdasarkan ketercapaian indikator berpikir kritis. Hasil penelitian menunjukkan bahwa E-LKPD sangat valid untuk melatih keterampilan berpikir kritis dengan tampilan dan bahasa yang baik. Hal tersebut sejalan dengan hasil kepraktisan dan keefektivan yang menyatakan bahwa E-LKPD sangat praktis untuk digunakan siswa dalam pembelajaran dan mampu melatih keterampilan berpikir kritis melalui fitur problem solving yang tersedia. Dengan demikian, dapat disimpulkan bahwa E-LKPD berbasis problem solving pada materi pertumbuhan dan perkembangan untuk melatih keterampilan berpikir kritis dinyatakan sangat valid, sangat praktis, dan sangat efektif.
PENGARUH SMARTPHONE TERHADAP MOTIVASI DAN HASIL BELAJAR BIOLOGI MATERI SISTEM EKSKRESI KELAS XI SMA
Authors: Rahma Aulia , Sandika Bayu
Published: April 2022

Tujuan penelitian ini untuk mengetahui pengaruh pembelajaran berbantuan smartphone terhadap motivasi belajar dan hasil belajar siswa pada materi sistem ekskresi di kelas XI IPA. Penelitian ini menggunakan pendekatan kuantitatif inferensial dengan jenis penelitian quasi eksperiment dengan desain nonequivalent group posttest only. Populasi pada penelitian ini yaitu siswa kelas XI IPA 3 dan XI IPA 4 yang berjumlah 68 siswa. Teknik pengambilan sampel menggunakan teknik purposive sampling. Metode pengumpulan data menggunakan tes dan angket. Analisis data menggunakan Independent T-test. Berdasarkan hasil penelitian ini dikatahui bahwa pembelajaran berbantuan smartphone berpengaruh secara signifikan terhadap motivasi belajar dan hasil belajar siswa pada materi sistem ekskresi di kelas XI IPA, ditunjukkan dengan Sig (2-tailed) sebesar 0,002<0,05 maka Ha diterima dan H0 ditolak.
Integrated reporting in commercial organizations
Authors: Kirkach Yu. N.
Published: April 2022

The article is devoted to the study of the essence of integrated reporting (IR). It shows that the unresolved environmental problems, the growth of the world’s population, the shortage of natural resources result in changes in the information requirements of stakeholders and, as a consequence, to the contents of companies’ reporting. In order to achieve the business goals interested parties need reports that systematically reflects the creation of company value through the complex interconnection of strategy, organizational management, operating, financial and investment activities, as well as the risk environment. Integrated reporting is capable of providing such information, combining financial and non-financial information about the company’s strategy, its achievements and management style. The main purpose of the IR is to summarize retrospective and prospective data demonstrating the process of value creation. The research reveals the problem of the lack of common understanding what IR is and the very idea of generating IR, along with the identity of the concepts of “integrated reporting” and “integrated report”, which does not comply with the International Standard for Integrated Reporting. The results of the research make it possible to determine the place of each type of report in the reporting composition and prove that the published integrated reports of Russian companies are actually integrated reporting, as they include consolidated financial statements and an integrated report, which meets the requirements of the International Integrated Reporting Standard.
PELATIHAN PEMBUATAN VIDEO PEMBELAJARAN MENGGUNAKAN APLIKASI KINEMASTER BAGI GURU MGMP PAI TINGKAT SMA DI KABUPATEN BANTUL
Authors: Revianti Siska Lidya , Astuti Femi Dwi , Anggoro Pius Dian Widi
Published: April 2022

Proses belajar mengajar di sekolah tingkat SMA di Kabupaten Bantul pada masa darurat Covid-19 dilakukan secara daring. Semua proses pembelajaran beralih dari pembelajaran tatap muka (PTM) di kelas ke pembelajaran jarak jauh (PJJ) yang banyak dilakukan dengan menggunakan teknologi ponsel cerdas atau smartphone. Guru-guru pendidikan agama Islam yang tergabung dalam Musyawarah Guru Mata Pelajaran Pendidikan Agama Islam (MGMP-PAI) Tingkat SMA se-kabupaten Bantul memiliki kesulitan dalam mengubah materi pembelajaran dari materi PTM menjadi materi PJJ. Selain permasalahan kesediaan perangkat komputer yang masih terbatas, pihak mitra juga mengalami kendala dalam pembuatan video pembelajaran karena belum memiliki keahlian dan pengetahuan yang cukup memadai. Melalui pengabdian ini akan diberikan pelatihan dengan menggunakan aplikasi Kinemaster untuk editing video dan membuat materi pembelajaran yang menarik di ponsel cerdas. Pengabdian ini diawali dengan melakukan analisa situasi dan kebutuhan Mitra, mengidentifikasi permasalahan, menentukan tujuan dan rencana kegiatan, melaksanakan pelatihan, monitoring dan evaluasi. Pengabdian diikuti oleh 35 peserta, dilaksanakan secara online melalui pertemuan dengan menggunakan aplikasi Zoom. Antusias dari para peserta pengabdian ini sangat baik, terbukti dari hasil kuesioner dari peserta pelatihan yang menyatakan bahwa isi materi pelatihan sesuai dengan kebutuhan mereka dan cara penyampaian materi dalam pelatihan juga baik dan jelas.
How language shapes interpersonal distance: An analysis of pronominal forms of address in Spanish, Polish and Italian
Authors: Baran Marek , Urbaniak Ewa
Published: April 2022

The aim of the present article is to compare the formal and functional aspects of pronominal forms of address in three languages: Spanish, Polish and Italian. The classic typology of the category analysed divides it in two groups: the T-forms applied in the conversations between the participants of symmetrical relations and the V-forms considered reverential and asymmetrical. The present study demonstrates and analyses the pronominal systems in two Romance languages, Spanish and Italian, and a Slavic language, Polish. We classify the pronouns according to the confidentiality/distance parameter, showing the similarities and differences between the formal characteristics, as well as the socio-cultural factors that determine the election of determined pronominal form of address.
Молибдаты и вольфраматы семейства аллюодита: кристаллохимия, состав и ионная подвижность
Authors: Солодовников С.Ф. , Гуляева О.А. , Савина А.А. , Юдин В.Н. , Бузлуков А.Л. , Солодовникова З.А. , Золотова Е.С. , Спиридонова Т.С. , Хайкина Е.Г. , Стефанович С.Ю. , Медведева Н.И. , Бакланова Я.В. , Денисова Т.А.
Published: April 2022

Рассмотрены особенности строения, нестехиометрия и ионная подвижность молибдатов, вольфраматов и других соединений, кристаллизующихся в структурном типе аллюодита (Na, Ca)(Fe, Mn, Mg)3(PO4)3 с общей кристаллохимической формулой по П. Муру X(2)X(1)M(1)M(2)2(TO4)3, где X — крупные катионы Na+, Ca2+, K+, Pb2+ и др. с КЧ = 8; M — октаэдрические катионы, T = P, As, V, S, Mo, W. На основе этой формулы и заселенностей соответствующих позиций выведены возможные пределы составов двойных молибдатов и вольфраматов типа аллюодита. Рассмотрены виды искажения (сверхструктуры) аллюодита, выделено несколько групп фаз, различающихся симметрией, числом анионов в ячейке и векторной связью с ячейкой исходной структуры аллюодита. Показано, что ключевую роль в переносе катионов натрия в фазах типа аллюодита играют цепочки частично дефектных позиций X(2) и X(1), идущие вдоль оси c. Для фосфатов и сульфатов со структурой аллюодита характерен преимущественно одномерный транспорт ионов натрия, однако, согласно данным расчетов карт сумм валентных усилий, ЯМР спектроскопии и ab initio расчетов, в сложных молибдатах и вольфраматах есть возможность двухмерной проводимости в плоскости (100) за счет перетока ионов Na+ между каналами X(2)—X(2) и X(1)—X(1) через мостиковую позицию M(1). Показано, что в семействе родственных аллюодиту (псевдо)ромбических тройных молибдатов Na10Cs4M5(MoO4)12 (M = Mn, Co) и Na25Cs8R5(MoO4)24 (R = Fe, Sc, In) также возможна двухмерная диффузия ионов натрия через последовательные зигзагообразные ионные перескоки с вероятной реализацией трехмерного транспорта при повышенных температурах.
Осаждение пленочных структур PtxIr(1–x), методом MOCVD из комбинации прекурсоров Me3Pt(acac)Py и Ir(СО)2(acac)
Authors: Доровских С.И. , Караковская К.И. , Викулова Е.С. , Корольков И.В. , Корецкая Т.П. , Максимовский Е.А. , Морозова Н.Б.
Published: April 2022

Исследованы MOCVD процессы осаждения пленочных структур PtxIr(1–x) в присутствии H2 и O2 в интервале температур 260—300 °C на Si и Ti подложках из комбинации прекурсоров Me3Pt(acac)Py и Ir(СО)2(acac), где acac = ацетилацетонато(-), Py = пиридин. По данным РФА пленки, как правило, представляют собой твердые растворы состава PtxIr(1–x). Образцы, полученные в присутствии O2, характеризуются минимальным содержанием примесей, однородным составом и соотношением металлов Pt:Ir, близким к экспериментально заданному. В присутствии H2 в интервале температур 280—300 °C формируются Ir-обогащенные слои PtxIr(1–x) с неоднородным распределением металлов по толщине. Поверхность пленочных структур PtxIr(1–x), синтезированных в присутствии водорода, сформирована мелкими частицами размером до 10 нм или агломератами частиц размером 20—32 нм, полученных в присутствии кислорода. Слои PtxIr(1–x) имеют преимущественно столбчатую структуру. Структура пленок, осажденных в атмосфере кислорода, становится более рыхлой, чем слоев, синтезированных в аналогичных условиях в атмосфере водорода. Толщины пленок, полученных в H2 или O2, лежат в интервалах 300—450 нм или 750—800 нм соответственно.
FUNCTIONS OF THE INFORMATION SECURITY AND CYBERSECURITY SYSTEM OF CRITICAL INFORMATION INFRASTRUCTURE
Authors: Khlaponin Yuri , Kozubtsova Lesya , Kozubtsov Igor , Shtonda Roman
Published: April 2022

The subject of research in the scientific article is the system of Information Protection and cybersecurity of critical information infrastructure objects. An information security and cybersecurity system is a complex set of software, cryptographic, organizational, and other tools, methods, and measures designed to protect information and cybersecurity. Since the system of Information Protection and cybersecurity of critical information infrastructure facilities is relatively new, there is no single view on what functions this system should perform. As a result, the process of its formation and formation as a system continues. There was a need to define functions for further evaluation of the effectiveness of its functioning as a system. Evaluation is supposed to be carried out both in the process of creation, acceptance, and daily operation. Partial performance indicators are required to implement the procedure for evaluating the effectiveness of the information security system and cybersecurity of critical information infrastructure facilities. Using these indicators, it is possible to characterize the degree of achievement of the system's tasks assigned to it. The following performance indicators are proposed according to the functions: ID identification of cybersecurity risks; PR Cyber Defense; DE detection of cyber incidents; RS response to cyber incidents; RC restoration of the state of cybersecurity. The scientific novelty of the obtained result lies in the fact that Universal functions are proposed that the information security and cybersecurity system should implement at critical information infrastructure facilities. The presented study does not exhaust all aspects of this problem. The theoretical results obtained in the course of scientific research form the basis for further justification of indicators and criteria for evaluating the effectiveness of the information security and cybersecurity system.
SYSTEM TO COLLECT INFORMATION WHEN TRANSFERRING DATA TO RADIO CHANNELS
Authors: Zhurakovskyi Bohdan , Nedashkivskiy Oleksiy
Published: April 2022

This article is devoted to solving the problem of information protection in radio channels, by applying comprehensive measures to protect against possible attacks aimed at intercepting and substituting transmitted data. The aim of the work is to analyze the security of wireless networks, identify methods for their protection and create a model for protecting wireless networks. In order to achieve this goal, the following list of tasks was performed: the existing solutions in the field of information protection through radio networks were analyzed; the description of the offered developed model is made; algorithms, experiments, experiments of this model are described. A means of protecting information through radio networks has been developed, the application of which has a significant increase in the level of information security in the radio channel. The practical value of this development is that the theoretical and practical results are recommended for implementation in organizations that use the radio channel to transmit confidential information with high security requirements
Phenomena of microvascular myocardial injury in patients with primary ST-segment elevation myocardial infarction: Prevalence and association with clinical characteristics
Authors: Vyshlov E. V. , Alexeeva Ya. A. , Ussov W. Yu. , Mochula O. V. , Ryabov V. V.
Published: April 2022

Aim. The aim of this study was to evaluate the prevalence of microvascular obstruction (MVO) and intramyocardial hemorrhage (IMH), their combination, and relationship to the clinical and anamnestic characteristics in patients with primary STEMI after coronary reperfusion.

Material and Methods. A single-center observational cohort study comprised a total of 60 patients with primary STEMI and successful coronary reperfusion within 12 hours of the onset of symptoms. All patients were studied using a contrast-enhanced cardiac magnetic resonance imaging (CE-MRI) at day 2 after STEMI. The study protocol was registered on ClinicalTrials.gov (Identifier: NCT03677466).

Results. The total occurrence rate of MVO and IMH phenomena was 68.3% including MVO only in 17% of patients, IMH only in 15% of cases, combination of MVO and IMH in 36% cases, and without a microvascular myocardial injury in 32% of cases. The patients with MVO only and combination of MVO and IMH experienced a longer time of ischemia versus patients without these conditions: 205 (140–227) and 193 (95–400) versus 130 (91–160) min (p = 0.049). On the contrary, the time of myocardial ischemia did not differ between patients with IMH only (113 min) and patients without it. Then, patients were assigned to the group of pharmaco-invasive strategy of coronary reperfusion (PIS) (n = 39) and the group of primary percutaneous intervention (PPCI) (n = 21). The incidence of MVO only and IMH only was equal in PIS and PPCI groups: 17.9% versus 14.2% and 12.8% versus 19.1% in PIS and PPCI groups, respectively. The tendency to a decrease in the incidence of combined MVO and IMH was observed in PIS group compared to PPCI group: 30.8% versus 47.6% (p = 0.09).

Conclusion. The combination of MVO and IMH phenomena in patients with primary STEMI after coronary reperfusion developed more often than each of these phenomena separately. The development of MVO only and combination of MVO and IMH was associated with a longer duration of myocardial ischemia. A total frequency of combination of MVO and IMH phenomena in patients with primary STEMI after coronary reperfusion was as high as 68.3%. Combination of these phenomena developed more frequently than each of them separately: 36% versus 17% (MVO only) and 15% (IMH only). No difference was observed in the duration of myocardial ischemia between the groups with MVO only and without it. The thrombolysis did not increase the occurrence of IMH in PIS group compared with PPCI group. There was a tendency to a decrease in the incidence of combination of MVO and IMH in PIS group compared to PPCI group: 30.8 versus 47.6% (р = 0.09).
NEW TRENDS AND OLD IDEOLOGICAL INSTRUCTIONS IN CHINESE EDUCATION
Authors:   Lomonosov Moscow State University, Mashkina O.
Published: April 2022

The article examines the role of conceptual worldview positions laid down in antiquity and passed into a set of socialist values and continue to play an important role in the modern system of education and upbringing in China.
ON THE QUESTION OF THE POSSIBILITIES OF APPLYING SOCIO-PHILOSOPHICAL ANALYSIS TO SMART TECHNOLOGIES: KEY ASPECTS
Authors:   Tomsk Polytechnic University, Netesova M. , Ardashkin I.
Published: April 2022

The article discusses the key aspests of the concepts of socio-philosophical analysis, applicable to the phenomenon of smart technologies in modern reality. The purpose, essence, and specificity of socio-philosophical analysis in the existing system of methods of scientific cognition are determined. Approaches to the study of socio – philosophical analysis as a significant means of understanding the essence and the most general laws of development and transformations of social life are considered. The article presents scientific and philosophical approaches to the problem of both domestic (Stepin V. S., Berkut V. P.,) and foreign authors (Michael M. Bell, Wenceslao J. Gonzalez), which require considering the social dimension of technology and the role of economic values in technology and the formation of a new type of society. The possibility of applying socio-philosophical analysis as a private scientific methodology in solving scientific problems is considered. The ambivalence of smart technologies in the social perception of society is demonstrated. The conclusion is formulated about the insufficient formation of a socio-philosophical framework that corresponds to the modern goals facing society, aimed at solving important problems for the present moment.
SOCIO-ECOLOGICAL ASPECTS OF INFORMATION AND COMMUNICATIVE EFFECTS
Authors: Nefedev S.
Published: April 2022

The article, from the standpoint of the «memetic» and «network» paradigms, examines the factors, mechanisms and socio-ecological consequences of information and communication influences. The phenomenon and mechanisms of information infection, the role of meme-viral influences in the processes of socio-cultural evolution are analyzed. The prospects for the development of effective research and socio-performative methods and technologies based on the joint use of the principle of viral information and communication influences and the «network» approach are studied. The ways of determining the intensity of «information infection» of the social space and the degree of «cognitive damage» of the population are discussed. It is shown that important socio-ecological problems of an information civilization are: the problem of uncontrollable side effects of information and communication influences and a tendency to the loss of human-centeredness (dehumanization) of network forms of social organization and control over them by a person.
THE IDEA OF THE FUTURE IN CONDITIONS OF UNCERTAINTY: POSSIBILITIES AND METHODS OF RESEARCH
Authors:   Kuban State Technological University, Tuchina O. , Trunova E.
Published: April 2022

The article discusses the theoretical approach and methodology of the study of ideas about the future in a transitive society. The problem of studying the image of the future belongs to the category of interdisciplinary, including research in the field of philosophy, political science, psychology, pedagogy, and sociology. The implementation of the research tasks is associated with the consideration and empirical study of the key socio-psychological factors of the perception of global, national, local risks of the modern world by adolescents and young people. The novelty of the proposed approach is associated with its interdisciplinarity, which involves the creation of a model for forming the image of the future of adolescents and young people in cognitive, emotional, and behavioral dimensions
THE NATURE AND LANDSCAPE OF SOCIAL MEMORY IN POSTMODERN SOCIETY
Authors:   National Research Tomsk Polytechnic University, Loyko O. , Fyodorova N.
Published: April 2022

The article is devoted to the study of social memory as a special way of preserving the value-semantic field of culture. The article examines the cultural and historical landscape of social memory, its difference from historical memory, and concludes that in postmodern society there is a natural process of reconstruction-reactivation – recategorization of the content of social memory. It is suggested that this process, being natural and historically determined, nevertheless needs constant adjustments in order to objectively understand its content.
AGROECOSYSTEM - THE BASIS OF AGRICULTURE OF THE FUTURE OR COEVOLUTION OF HUMAN ECONOMIC AND SOIL ECOSYSTEM IN THE COORDINATES OF SUSTAINABLE DEVELOPMENTNAME OF THE ARTICLE
Authors:   Centеr «Eco-Accord», Tsittser O. , Speranskaya O.
Published: April 2022

Sustainable development as applied to agriculture is, first of all, ecologically balanced land use, historical examples of which in many countries testify: the preservation and enhancement of soil fertility combined with the maintenance of biodiversity in the environment, a reasonable balance in production that does not lead to depletion of the soil cover and its pollution with chemicals, prevention in the fight against pests and diseases of cultivated plants - always give positive and prolonged results. The time has come to move away from industrial directions in agriculture and widely introduce environmentally friendly alternatives in agriculture and agricultural production in general.
STUDY OF THE HISTORY OF REGIONS AND SETTLEMENTS - THE MAIN TASK OF REGIONAL SCIENTISTS AND LOCAL HISTORIANS (ON THE STUDY OF NATURAL OBJECTS AND MONUMENTS HISTORICAL AND CULTURAL HERITAGE IN THE FRAMEWORK OF WRITING THE HISTORY OF TATAR VILLAGES AND VILLAGES WITHIN THE OKA-SURA INTERFLUVE AND NEIGHBORING TERRITORIES OF HISTORICALLY COMPACT TATARS LIVING IN THE VOLGA-URALS)
Authors: Burkhanov A. , Garaeva A.
Published: April 2022

In this publication, the author focuses on the main results and issues, directions and tasks of studying unique nature objects and monuments of historical and cultural heritage as part of writing the history of Tatar villages and villages on the example interfluve and neighboring territories of historically compact Tatars living in Volga, Urals, Siberia. Based on the experience of his own research and colleagues, the author focuses on the main directions and tasks of preserving and using nature and historical and cultural heritage. The author considers the development of tourism and the education of young people for love of their native land to be the most important task.
VALUABLE AND NOTABLE NATURAL MONUMENTS IN THE TERRITORY OF THE PRUT TOLTRY
Authors:   Tiraspol State University, Volontir N.
Published: April 2022

The article describes unique, amazing and inimitable creations of nature, which can rightfully claim to be included in the list of world attractions. First of all, these are the so-called Prut Toltry or coral fossilized reefs, uniquely beautiful landscapes, especially pronounced in the four Prut regions of the Republic of Moldova – Brichany, Edintsy, Ryshkany and Glodeny. Several examples of natural monuments (geological and paleontological natural monuments and protected areas) of the Prut Toltry are given, which have a special scientific, ecological, historical, cultural, tourist, aesthetic and cognitive value.
GEOLOGICAL LANDMARKS AS A BASIS FOR TOURISM DEVELOPMENT IN THE SOUTH-EASTERN CRIMEA
Authors:   Insitute of Geography RAS, Adaeva D.
Published: April 2022

The article proves the necessity of the development of tourism in the South-East Crimea, based on the geological attractions of the region, including those that are parts of the existing protected areas. The importance of promoting geotourism within the potential geopark in the Sudak-Feodosiya region for the sustainable development of the coastal area, maintaining local communities, and implementing tasks for the geo-conservation of unique geological objects is emphasized. The author offers a list of the most relevant and complete methodological approaches for the inventory of geological heritage sites and their assessment, also aiming the development of tourism and education. A list of geodiversity elements potential for consideration as key objects for inclusion in tourist routes is given: the Karadag volcanic massif, the Alchak and Meganom capes, a section of the Middle-Upper Jurassic sediments on the ridge Biyuk-Yanishar, Karaul-Oba mountain range, etc.