bluuebunny/crossref_metadata_2025 huggingface dataset:
Association between lack of angiogenic response in muscle tissue and high expression of angiostatic ELR‐negative CXC chemokines in patients with juvenile dermatomyositis: Possible link to vasculopathy
Authors: Fall Ndate , Bove Kevin E. , Stringer Keith , Lovell Daniel J. , Brunner Hermine I. , Weiss Jennifer , Higgins Gloria C. , Bowyer Susanne L. , Graham T. Brent , Thornton Sherry , Grom Alexei A.
Published: September 2005

Objective

To investigate the relationship between the vasculopathy of juvenile dermatomyositis (juvenile DM) and the balance between the angiostatic ELR− and angiogenic ELR+ CXC chemokines in the muscle of patients with the disease.

Methods

The expression of 3 ELR− CXC chemokines (interferon‐inducible protein 10 [IP‐10], monokine induced by interferon‐γ, and interferon‐inducible T cell α‐chemoattractant) and 2 ELR+ CXC chemokines was quantitated in muscle biopsy samples from 7 patients with juvenile DM and 7 healthy children, by real‐time polymerase chain reaction. The findings were correlated with various histopathologic features, with particular emphasis on the degree of vasculopathy. Synovial biopsy specimens from patients with juvenile rheumatoid arthritis (JRA) were used for additional comparison.

Results

The angiostatic ELR− chemokines were expressed at high levels, while the angiogenic ELR+ chemokines were barely detectable, in most juvenile DM samples. This contrasted sharply with the findings in both normal muscle biopsy specimens and JRA synovial tissue specimens. The expression of the ELR− chemokines in juvenile DM samples correlated with the intensity of mononuclear cell infiltration. Furthermore, the juvenile DM samples with the highest degree of capillary loss had the highest levels of ELR− CXC chemokines. The presence of IP‐10 in juvenile DM muscle specimens was confirmed by immunohistochemistry analysis. In addition, immunohistochemical staining of muscle tissue revealed that CXCR3, a receptor utilized by ELR− CXC chemokines, was expressed in vascular endothelial cells.

Conclusion

Increased expression of the interferon‐induced angiostatic ELR− CXC chemokines is a feature of juvenile DM that parallels the degree of vasculopathy in patients with the disease. Collectively, these findings are consistent with a model in which a subset of inflammatory cells secrete angiostatic ligands, which then contribute to a local atrophying effect on the muscle's vasculature via a receptor‐mediated process.
Cruciate ligament laxity and femoral intercondylar notch narrowing in early‐stage knee osteoarthritis
Authors: Quasnichka Helen L. , Anderson‐MacKenzie Janet M. , Tarlton John F. , Sims Trevor J. , Billingham Michael E. J. , Bailey Allen J.
Published: September 2005

Objective

The influence of the cruciate ligaments in spontaneous osteoarthritis (OA) is not understood, although ligament rupture is known to cause secondary OA. Additionally, femoral notch narrowing at the anterior cruciate ligament (ACL) insertion site is associated with disease severity, but it is unknown whether ligament deterioration precedes or follows osteophyte formation. We examined cruciate ligament mechanics and metabolism and the intercondylar notch width in OA‐prone Dunkin‐Hartley (DH) guinea pigs at ages up to and including the age at OA onset (24 weeks), and compared the data with those in age‐matched controls (Bristol strain 2 [BS2] guinea pigs).

Methods

Guinea pigs were assessed at 3, 6, 9, 12, 16, 20, 24, and 36 weeks of age. ACLs were mechanically tested, and the intercondylar notch width index (NWI) was determined. Cruciate ligament metabolism was determined by measuring the following markers of collagen turnover: matrix metalloproteinase 2 (MMP‐2), tissue inhibitor of metalloproteinases 2, C‐terminal type I procollagen propeptide (PICP), and the immature collagen‐derived crosslink dihydroxylysinonorleucine (DHLNL).

Results

DH guinea pigs had significantly laxer ACLs than did BS2 guinea pigs, at 12, 16, and 24 weeks. We observed elevated levels of pro and active MMP‐2, PICP, and DHLNL in the cruciate ligaments of DH animals at most ages, compared with BS2 guinea pigs. The NWI in DH animals was significantly lower than that in BS2 guinea pigs at 24 and 36 weeks.

Conclusion

In DH guinea pigs, laxer ACLs, which are associated with increased collagen turnover, may cause joint instability and predispose these animals to the early onset of OA. Decreased intercondylar notch width in the DH animals indicates that bone remodeling at the ACL insertion site is a response to elevated ACL laxity.
Accuracy and precision of quantitative assessment of cartilage morphology by magnetic resonance imaging at 3.0T
Authors: Eckstein Felix , Charles H. Cecil , Buck Robert J. , Kraus Virginia B. , Remmers Ann E. , Hudelmaier Martin , Wirth Wolfgang , Evelhoch Jeffrey L.
Published: September 2005

Objective

Quantitative magnetic resonance imaging (MRI) of articular cartilage represents a powerful tool in osteoarthritis (OA) research, but has so far been confined to a field strength of 1.5T. The aim of this study was to evaluate the precision of quantitative MRI assessments of human cartilage morphology at 3.0T and to correlate the measurements at 3.0T with validated measurements at 1.5T.

Methods

MR images of the knee of 15 participants with OA and 15 healthy control subjects were acquired using Siemens 1.5T and 3.0T scanners. Double oblique coronal scans were obtained at 1.5T with a 1.5‐mm partition thickness, at 3.0T with a 1.5‐mm partition thickness, and at 3.0T with a 1.0‐mm partition thickness. Cartilage volume, thickness, and surface area of the femorotibial cartilage plates were quantified using proprietary software.

Results

For 1.5‐mm partition thickness at 1.5T, the precision error was 3.0% and 2.6% for cartilage volume and cartilage thickness, respectively. The error was smaller for a 1.5‐mm partition thickness at 3.0T (2.6% and 2.5%) and still smaller for a 1.0‐mm partition thickness at 3.0T (2.1% and 2.0%). Correlation coefficients between values obtained at 3.0T and 1.5T were high (r ≥ 0.96), with no significant deviation between the two field strengths.

Conclusion

Quantitative MRI measurement of cartilage morphology at 3.0T (partition thickness 1 mm) was found to be accurate and tended to be more reproducible than at 1.5T (partition thickness 1.5 mm). Imaging at 3.0T may therefore provide superior ability to detect changes in cartilage status over time and to determine responses to treatment with structure‐modifying drugs.
Monozygotic twins clinically discordant for scleroderma show concordance for fibroblast gene expression profiles
Authors: Zhou Xiaodong , Tan Filemon K. , Xiong Momiao , Arnett Frank C. , Feghali‐Bostwick Carol A.
Published: September 2005

Objective

Fewer than 5% of monozygotic (MZ) and dizygotic (DZ) twin pairs are clinically concordant for systemic sclerosis (SSc), yet the majority of MZ twins are concordant for antinuclear antibodies. To discover genetic versus nongenetic molecular pathways important to the pathogenesis of SSc, we compared global gene expression patterns in twins discordant for SSc.

Methods

Total RNA from dermal fibroblasts of 15 discordant twin pairs (10 MZ and 5 DZ) and 5 normal controls were used in microarray analysis. Aberrantly expressed genes were confirmed using quantitative real‐time reverse transcriptase–polymerase chain reaction.

Results

Lesional and nonlesional fibroblasts from SSc patients showed no significant differences in gene expression, while SSc patients had gene profiles that were significantly different from those of unaffected DZ twins and normal controls. Unaffected MZ twins, however, were not significantly different from SSc patients. Unsupervised hierarchical clustering segregated the fibroblast samples as originating from 2 major groups. Group A contained 5 discordant MZ twin pairs, 3 affected MZ twins, and 3 affected DZ twins. Group B contained all 5 normal population controls, all 5 healthy DZ twins, 2 discordant MZ twins, and 2 discordant DZ twin pairs. Normal fibroblasts incubated with serum from an SSc‐affected patient or with serum from her unaffected MZ twin sister developed the increased expression of COL1A2, SPARC, and CTGF typically seen in SSc fibroblasts.

Conclusion

These results demonstrate that dermal fibroblasts from SSc patients and from 40–50% of their genetically identical but clinically unaffected MZ twins exhibit a similar gene expression pattern which can be induced in normal fibroblasts by sera from both. Thus, a stronger genetic predisposition to SSc (than can be detected clinically) is apparent at the molecular level in skin fibroblasts.
Influence of heme oxygenase 1 modulation on the progression of murine collagen‐induced arthritis
Authors: Devesa Isabel , Ferrándiz Maria Luisa , Terencio María Carmen , Joosten Leo A. B. , van den Berg Wim B. , Alcaraz María José
Published: September 2005

Objective

Heme oxygenase 1 (HO‐1) can be induced by inflammatory mediators as an adaptive response. The objective of the present study was to determine the consequences of HO‐1 modulation in the murine collagen‐induced arthritis (CIA) model.

Methods

DBA/1J mice were treated with an inhibitor of HO‐1, tin protoporphyrin IX (SnPP), or with an inducer of HO‐1, cobalt protoporphyrin IX (CoPP), from day 22 to day 29 after CIA induction. The clinical evolution of disease was monitored visually. At the end of the experiment, joints were examined for histopathologic changes. Cytokine levels in paws were measured by enzyme‐linked immunosorbent assay. Levels of HO‐1, cyclooxygenase 2 (COX‐2), and prostaglandin E2 (PGE2) were determined. Effects of treatments on the early phase of disease and after prophylactic administration were also assessed.

Results

CoPP strongly induced HO‐1, resulting in the inhibition of cartilage erosion accompanied by extensive fibrosis in the joint. Levels of tumor necrosis factor α (TNFα), interleukin‐2 (IL‐2), and IL‐10 were inhibited by CoPP, whereas levels of vascular endothelial growth factor were increased. Treatment with SnPP significantly reduced the severity of CIA, with inhibition of joint inflammation and cartilage destruction. The levels of PGE2, IL‐1β, and TNFα were also significantly reduced by SnPP treatment, which did not modify COX‐2 protein expression. SnPP was more effective than CoPP in preventing the development of CIA (prophylactic administration).

Conclusion

HO‐1 is induced during CIA. Although overexpression of this protein causes some beneficial effects, strategies aimed at HO‐1 overexpression cannot slow the progression of the chronic inflammatory disease, whereas treatment with SnPP, which inhibits HO‐1, exerts prophylactic and therapeutic effects.
Standard assays do not predict the efficiency of commercial cellulase preparations towards plant materials
Authors: Kabel Mirjam A. , van der Maarel Marc J.E.C. , Klip Gert , Voragen Alphons G.J. , Schols Henk A.
Published: September 2005

Commercial cellulase preparations are potentially effective for processing biomass feedstocks in order to obtain bioethanol. In plant cell walls, cellulose fibrils occur in close association with xylans (monocotyls) or xyloglucans (dicotyls). The enzymatic conversion of cellulose/xylans is a complex process involving the concerted action of exo/endocellulases and cellobiases yielding glucose and xylanases yielding xylooligomers and xylose. An overview of commonly measured cellulase‐, cellobiase‐, and xylanase‐activity, using respectively filter paper, cellobiose, and AZCL‐dyed xylan as a substrate of 14 commercially available enzyme preparations from several suppliers is presented. In addition to these standardized tests, the enzyme‐efficiency of degrading native substrates was studied. Grass and wheat bran were fractionated into a water unsoluble fraction (WUS), which was free of oligosaccharides and starch. Additionally, cellulose‐ and xylan‐rich fractions were prepared by alkaline extraction of the WUS and were enzymatically digested. Hereby, the capability of cellulose and xylan conversion of the commercial enzyme preparations tested was measured. The results obtained showed that there was a large difference in the performance of the fourteen enzyme samples. Comparing all results, it was concluded that the choice of an enzyme preparation is more dependent on the characteristics of the substrate rather than on standard enzyme‐activities measured. © 2005 Wiley Periodicals, Inc.
Chemical and Chemoenzymatic Synthesis of S‐Linked Ganglioside Analogues and Their Protein Conjugates for Use as Immunogens
Authors: Rich Jamie R. , Wakarchuk Warren W. , Bundle David R.
Published: September 2005

Analogues of the tumor‐associated gangliosides GM3 and GM2 containing terminal S‐linked neuraminic acid residues and an amino terminated, truncated ceramide homologue have been synthesized and conjugated to a protein. The synthesis involved coupling of a S‐linked sialyl α(2→3) galactose disaccharide with a glucosyl sphingosine analogue, followed by elaboration and deprotection to give amino‐terminated glycosyl ceramide 1. Glycosyltransferase‐catalyzed extension of the trisaccharide 1 provided access to the modified GM2 tetrasaccharide 2 or sulphur‐containing GD3 analogue 30. Owing to their potentially enhanced resistance to endogenous exo‐glycoside hydrolases and their inherent non‐self character, carbohydrate antigens containing non‐reducing terminal thioglycosidic linkages may be more immunogenic than O‐linked antigens and may stimulate the production of antibodies capable of recognizing naturally occurring oligosaccharides. Our initial results suggest that in fact these antigens are viable immunogens and furthermore, that immune sera cross reacts with O‐gangliosides in the context of a heterologous glycoprotein conjugate.
Three Distinct Read‐Out Modes for Enzyme Activity Can Operate in a Semi‐Wet Supramolecular Hydrogel
Authors: Tamaru Shun‐ichi , Kiyonaka Shigeki , Hamachi Itaru
Published: September 2005

Assays of hydrolytic enzyme activity, such as of glycosidases and phosphatase, as well as several proteases, using a semi‐wet supramolecular hydrogel array composed of a glycosylated amino acetate are described. It has been demonstrated that the microcavity formed by gel fibrils is suitable to immobilize native enzymes without denaturation under semi‐wet conditions, and thus the nanofiber has been rationally used as a sensing domain to monitor enzymatic reactions. By using a fluorogenic substrate, reducing the size of the hydrogel can significantly improve the problem of suppressed diffusion within the gel matrix thus making the hydrogel a promising semi‐wet matrix for evaluating enzyme activity. Confocal laser scanning microscopy observations have shown that an environmentally sensitive fluorescent probe accumulates in the hydrophobic domain of the gel fiber and emits fluorescence more strongly upon hydrolytic cleavage of the substrate peptides. Not only a simple environmentally sensitive probe but also a FRET (fluorescence resonance energy transfer)‐type read‐out mode can be devised to analyze the enzymatic hydrolysis‐triggered redistribution of the probe between the nanospace and the nanofiber to accomplish a more clearly distinguished enzyme assay. Thus, it is clear that three distinct read‐out modes, that is, 1) fluorogenic substrates, 2) substrates bearing an environmentally sensitive probe, or 3) a substrate exhibiting FRET, can operate under the semi‐wet hydrogel conditions used in these investigations. In addition, owing to the unique properties of the present supramolecular hydrogel in semi‐wet conditions, that is, its phase‐segregation properties and dynamics, the supramolecular substrate/enzyme array has successfully been used for high‐throughput screening of single and multiple enzymes based on their activity, lysate analysis, and quantitative evaluation of inhibitor potency and selectivity.
Lower Main‐Group Element Complexes with a Soft Scorpionate Ligand: The Structural Influence of Stereochemically Active Lone Pairs
Authors: Dodds Christopher A. , Reglinski John , Spicer Mark D.
Published: September 2005

The syntheses and structures of complexes of the fifth period elements indium and antimony, and the sixth period element bismuth with the soft scorpionate ligand, hydrotris(methimazolyl)borate (TmMe) are reported. A considerable variety of structural motifs were obtained by reaction of the main‐group element halide and NaTmMe. The indium(III) complexes took the form [In(κ3‐TmMe)2]+. This motif could not, however, be isolated for antimony(III), the dominant product being [Sb(κ3‐TmMe)(κ1‐TmMe)X] (X=Br, I). An iodo‐bridged species [Sb(κ3‐TmMe)I(μ2‐I)]2, analogous to a previously reported bismuth complex, was also isolated. Reaction of antimony(III) acetate with NaTmMe results in a remarkable species in which three different ligand binding modes are observed. In each antimony complex the influence of the nonbonded electron pair is observed in the structure. Bismuth halides form complexes analogous to those of antimony, with directional lone pairs, but in addition, reaction of Bi(NO3)3 with NaTmMe results in a complex with a regular S6 coordination sphere and a nonstereochemically active lone pair. Comparisons are drawn with known TmMe complexes of As, Sn, and Bi in which the stereochemical influence of the lone pairs is negligible and with TmMe complexes of Te and Bi in which the lone pairs are stereochemically active. This study highlights the ability of TmMe to coordinate in a variety of modes as dictated by the metal centre with no adverse effects on the stability of the complexes formed.
Protonation, Deprotonation, and Protonation: Conjugated Photochemical Reactions of Ferrocenylazophenol
Authors: Men Yi , Korupoju Srinivas R. , Kurihara Masato , Mizutani Jun , Nishihara Hiroshi
Published: September 2005

4‐Ferrocenylazophenol (FAP) and 8‐(4‐ferrocenylazophenoxy)octanyl‐ 1‐bromide (FAOB) have been synthesized and their protonation and photochemical behavior have been investigated. FAP showed reversible protonation and deprotonation behavior in the presence of trifluoroacetic acid and potassium tert‐butylate, respectively. FAP and FAOB exhibit high photoreactivity, which was induced through excitation of not only the π–π* band by UV light but also the d–π* band by green light. The photoreaction of FAP and FAOB in ethanol or acetonitrile with a trace amount of water afforded phenylhydrazonocyclopentadiene (PHP) derivatives, indicating that hydrolysis of the photoexcited species occurs.
Extremely Base‐Resistant Organic Phosphazenium Cations
Authors: Schwesinger Reinhard , Link Reinhard , Wenzl Peter , Kossek Sebastian , Keller Manfred
Published: September 2005

A series of peralkylated polyaminophosphazenium cations exhibiting extraordinary base resistance under phase‐transfer conditions were efficiently synthesized from readily available starting materials. Their half lives under these conditions exceed those of the most stable conventional organic cations by factors of up to 3000.
Acceleration of Organic Reactions through Aqueous Solvent Effects
Authors: Pirrung Michael C.
Published: September 2005

The parallels between organic reactions conducted with water as the solvent and reactions conducted under high pressure can be understood in light of theories of aqueous solvation and hydrophobic effects. Such parallels provide powerful tools for promoting reactions of nonpolar compounds.
Importance of Cations in the Properties of Zintl Phases: The Electronic Structure of and Bonding in Metallic Na6TlSb4
Authors: Mudring Anja‐V. , Corbett John D.
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
The Crystal and Molecular Structure of Bis(tetramethylammonium) Pentachlorooxomolybdate(V)‐Acetonitrile(1:1).
Authors: Seyedsadjadi S. A. , Ghammamy S. , Rezaeibehbahani G.
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Thallium(III) Selenite, Tl2(SeO3)3.
Authors: Harrison William T. A.
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Sodium Calcium Orthovanadate, NaCa4(VO4)3.
Authors: Ben Yahia Hamdi , Gaudin Etienne , Darriet Jacques
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
The PrPS4 Type Structure and a Filled Variant: The Compounds TbPS4 and LiEuPS4.
Authors: Joergens Stefan , Alili Lirija , Mewis Albrecht
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Oxotellurates(IV) of Lanthanides. Part 2. The Isotypic Series M2Te5O13 (M: Dy—Lu).
Authors: Meier Steffen F. , Schleid Thomas
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Strongly Birefringent Pb3O2Cl2 Nanobelts.
Authors: Sigman Michael B. Jr. , Korgel Brian A.
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Crystal Growth, Thermoelectric Properties, and Electronic Structure of AgBi3S5 and AgSbxBi3‐xS5 (x = 0.3).
Authors: Kim Jun‐Ho , Chung Duck‐Young , Bilc Daniel , Loo Sim , Short Jarrod , Mahanti Subhendra D. , Hogan Tim , Kanatzidis Mercouri G.
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Synthesis and Properties of Na2Sr1.5Nb3‐xRuxO10 (x = 0.5, 1.0, 1.5) Series Compounds.
Authors: Wang Zhongbing , Chen Zuyao , Li Mingde , Cao Liezhao
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Observation of Unusual Hysteretic Magnetic Properties of the Rare Earth Intermetallic Compound PrMnSi2: Magnetic Susceptibility, Magnetization, Heat Capacity, and Electronic Band Structure Studies.
Authors: Kim Sang‐Hwan , Seo Dong‐Kyun , Kremer Reinhard K. , Koehler Juergen , Villesuzanne Antoine , Whangbo Myung‐Hwan
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Magnetic, Electrical, and Thermodynamic Properties of the LaxHo1‐xNi2 Solid Solutions.
Authors: Cwik J. , Palewski T. , Nenkov K. , Burkhanov G. S.
Published: September 2005

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Spin Reorientation and Magnetic Anisotropy in Y2Co17‐xCrx (x = 1.17—3.0) Compounds.
Authors: Fuquan B. , Tegus O. , Dagula W. , Brueck E. , de Boer F. R. , Buschow K. H. J.
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Phase Diagram of the Ag2S—HgS—SnS2 System and Single Crystal Preparation, Crystal Structure and Properties of Ag2HgSnS4.
Authors: Parasyuk O. V. , Chykhrij S. I. , Bozhko V. V. , Piskach L. V. , Bogdanyuk M. S. , Olekseyuk I. D. , Bulatetska L. V. , Pekhnyo V. I.
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Phase Diagrams of the Quasi‐Binary Systems Cu2S—SiS2 and Cu2SiS3—PbS and the Crystal Structure of the New Quaternary Compound Cu2PbSiS4.
Authors: Olekseyuk I. D. , Piskach L. V. , Zhbankov O. Ye. , Parasyuk O. V. , Kogut Yu. M.
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
On the Reactivity of Li8‐yMnyP4 Toward Lithium.
Authors: Gillot F. , Monconduit L. , Morcrette M. , Doublet M.‐L. , Dupont L. , Tarascon J.‐M.
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Eu8(NCN)5‐δI6+2δ (δ = 0.05): A Novel Rare‐Earth Carbodiimide Iodide Containing Oligomeric Tritetrahedral Eu8 Clusters.
Authors: Liao Wuping , Fokwa Boniface P. T. , Dronskowski Richard
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
High Pressure and High Temperature Synthesis and Characterization of a New Mixed Valence Perovskite Oxide Eu0.62K0.38TiO3.
Authors: Miao Ji‐Peng , Lue Zhe , Sui Yu , Huang Xi‐Qiang , Liu Zhi‐Guo , Qian Zheng‐Nan , Zheng Zhi‐Ren , Zhang Zhi‐Guo , Su Wen‐Hui
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
1∞ [Li3(NbSe4)×4MeCN] — A Novel Soluble Tetrachalcogenoniobate.
Authors: Feuerhake Robert , Sahin Huelya , Fenske Dieter
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Asymmetric Dihydroxylation Catalyzed by Ionic Polymer‐Supported Osmium Tetroxide.
Authors: Lee Byoung Se , Mahajan Suresh , Janda Kim D.
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Enantioselective Formation of Stereogenic Carbon—Fluorine Centers by a Simple Catalytic Method.
Authors: Marigo Mauro , Fielenbach Doris , Braunton Alan , Kjaersgaard Anne , Joergensen Karl Anker
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Direct Asymmetric α‐Fluorination of Aldehydes.
Authors: Steiner Derek D. , Mase Nobuyuki , Barbas Carlos F. III
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Synthesis of C3‐Symmetric Tris(β‐hydroxy amide) Ligands and Their Ti(IV) Complex‐Catalyzed Enantioselective Alkynylation of Aldehydes.
Authors: Fang Tao , Du Da‐Ming , Lu Shao‐Feng , Xu Jiaxi
Published: September 2005

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A Sequential Palladium‐Catalyzed Alder‐Ene‐Reductive Amination Reaction.
Authors: Kressierer Christoph J. , Mueller Thomas J. J.
Published: September 2005

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Spiro‐Cyclopropanation from Oxoallylsilanes.
Authors: Barbero Asuncion , Castreno Pilar , Pulido Francisco J.
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Mild and Regioselective Bromination of Aromatic Compounds with N,N,N′,N′‐Tetrabromobenzene‐1,3‐disulfonylamide and Poly(N‐bromobenzene‐1,3‐disulfonylamide).
Authors: Ghorbani‐Vaghei Ramin , Jalili Hamid
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Mild Regioselective Monobromination of Activated Aromatics and Heteroaromatics with N‐Bromosuccinimide in Tetrabutylammonium Bromide.
Authors: Ganguly Nemai C. , De Prithwiraj , Dutta Sanjoy
Published: September 2005

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Regioselective Iodination of Activated Arenes Using Phenyl Trimethylammonium Dichloroiodate in Ionic Liquid under Microwave Irradiation.
Authors: Tilve Rutuja D. , Kanetkar Vinod R.
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Rapid Debromination of vic‐Dibromoalkanes with Zinc Powder in Acetic Acid under Microwave Irradiation.
Authors: Kuang Chunxiang , Yang Qing , Senboku Hisanori , Tokuda Masao
Published: September 2005

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Dinitrogen Tetroxide‐Impregnated Charcoal (N2O4/Charcoal): Selective Nitrosation of Amines, Amides, Ureas, and Thiols.
Authors: Iranpoor Nasser , Firouzabadi Habibi , Pourali Ali Reza
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Synthesis of Allenamides by Copper‐Catalyzed Coupling of Allenyl Halides with Amides, Carbamates, and Ureas.
Authors: Trost Barry M. , Stilles Dylan T.
Published: September 2005

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Enantioselective Synthesis of Cyclic Amides and Amines Through Mo‐Catalyzed Asymmetric Ring‐Closing Metathesis.
Authors: Sattely Elizabeth S. , Cortez G. Alexander , Moebius David C. , Schrock Richard R. , Hoveyda Amir H.
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Facile Oxidative Conversion of Alcohols to Esters Using Molecular Iodine.
Authors: Mori Naoshi , Togo Hideo
Published: September 2005

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A Catalytic Asymmetric Three‐Component 1,4‐Addition/Aldol Reaction: Enantioselective Synthesis of the Spirocyclic System of Vannusal A.
Authors: Nicolaou K. C. , Tang Wenjun , Dagneau Philippe , Faraoni Raffaella
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Cobalt‐Catalyzed Hydroazidation of Olefins: Convenient Access to Alkyl Azides.
Authors: Waser Jerome , Nambu Hisanori , Carreira Erick M.
Published: September 2005

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Synthesis of New Active o‐Nitrophenyl Carbamates
Authors: Simon Monika , Csunderlik Carol , Cotarca Livius , Caproiu Miron Teodor , Neda Ion , Turoczi Maria Cristina , Volpicelli Raffaella
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Synthesis and Antiarrhythmic Activity of 5‐Amino‐exo‐3‐azatricyclo[5.2.1.02,6]decan‐4‐one.
Authors: Gorpinchenko V. A. , Yatsynich E. A. , Petrov D. V. , Karachurina L. T. , Khisamutdinova R. Yu. , Baschenko N. Zh. , Dokichev V. A. , Tomilov Yu. V. , Yunusov M. S. , Nefedov O. M.
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Polystyrene‐Supported Phosphine‐Catalyzed Aza‐Baylis—Hillman Reactions and the Relationship Between Resin Loading Level and Catalyst Efficiency.
Authors: Zhao Lin‐Jing , He Helen Song , Shi Min , Toy Patrick H.
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Ruthenium‐Catalyzed Intermolecular Coupling Reactions of Arylamines with Ethylene and 1,3‐Dienes: Mechanistic Insight on Hydroamination vs ortho‐C—H Bond Activation.
Authors: Yi Chae S. , Yun Sang Young
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Copper‐ and Palladium‐Containing Perovskites: Catalysts for the Ullmann and Sonogashira Reactions.
Authors: Lohmann Sophie , Andrews Stephen P. , Burke Brenda J. , Smith Martin D. , Attfield J. Paul , Tanaka Hirohisa , Kaneko Kimiyoshi , Ley Steven V.
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Direct Synthesis of Trimethyl(2‐phenoxyethyl)silanes from Aromatic Fluorides.
Authors: Grecian Scott A. , Hadida Sabine , Warren Stephen D.
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Synthesis of Nitrogen‐Containing Phenoxyacetic Acid Derivatives.
Authors: Yamansarova E. T. , Kukovinets O. S. , Zainullin R. A. , Galin F. Z. , Abdullin M. I.
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Liquid‐Phase Parallel Synthesis of 4‐Sulfonylbenzoic Acids.
Authors: Trifilenkov A. S. , Il'in A. P. , Kravchenko D. V. , Dorogov M. V. , Tkachenko S. E. , Ivashchenko A. V.
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
Superparamagnetic Nanoparticle‐Supported Catalysis of Suzuki Cross‐Coupling Reactions.
Authors: Stevens Philip D. , Fan Jinda , Gardimalla Hari M. R. , Yen Max , Gao Yong
Published: September 2005

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Rhodium‐Catalyzed Arylation Using Arylboron Compounds: Efficient Coupling with Aryl Halides and Unexpected Multiple Arylation of Benzonitrile.
Authors: Ueura Kenji , Satoh Tetsuya , Miura Masahiro
Published: September 2005

For Abstract see ChemInform Abstract in Full Text.
New Simple Chiral Phosphine Oxazolidine Ligands: Easy Synthesis and Application in the Palladium‐Catalyzed Asymmetric Allylic Alkylation.
Authors: Braga Antonio L. , Sehnem Jasquer A. , Luedtke Diogo S. , Zeni Gilson , Silveira Claudio C. , Marchi Miriam I.
Published: September 2005

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Diastereospecific Synthesis of trans‐2,3‐Diaryl‐1‐aminocyclopropanecarboxylic Acids.
Authors: Pan Chengxue , Su Guifa , Qin Jiangke
Published: September 2005

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Dihydroaromatic Boronic Esters as Building Blocks for the Synthesis of Phenanthrenes and Phenanthridines.
Authors: Hilt Gerhard , Hess Wilfried , Schmidt Frank
Published: September 2005

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Kinetic Resolution of Racemic Epoxides Using a Chiral Diamine Catalyst.
Authors: Gayet Arnaud , Andersson Pher G.
Published: September 2005

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Novel Ozone‐Mediated Cleavage of the Benzhydryl Protecting Group from Aziridinyl Esters.
Authors: Patwardhan Aniruddha P. , Lu Zhenjie , Pulgam Reddy , Wulff William D.
Published: September 2005

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Spiroheterocyclic Compounds Based on 2‐Bromobutanolides.
Authors: Kochikyan T. V.
Published: September 2005

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The gem‐Dialkyl Effect in Electron Transfer Reactions: Rapid Synthesis of Seven‐Membered Rings Through an Electrochemical Annulation.
Authors: Sperry Jeffrey B. , Wright Dennis L.
Published: September 2005

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Efficient Protiodesilylation of Unactivated C(sp3)—SiMe2Ph Bonds Using Tetrabutylammonium Fluoride.
Authors: Heitzman Cheryl L. , Lambert William T. , Mertz Eric , Shotwell J. Brad , Tinsley Jennifer M. , Va Porino , Roush William R.
Published: September 2005

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A New, Expeditious Entry to the Benzophenanthrofuran Framework by a Pd‐Catalyzed C‐ and O‐Arylation/PIFA‐Mediated Oxidative Coupling Sequence.
Authors: Churruca Fatima , SanMartin Raul , Tellitu Imanol , Dominguez Esther
Published: September 2005

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Titanium‐Mediated Alkylative Coupling of N‐Acylpyrroles.
Authors: Epstein Oleg L. , Seo Jung Min , Masalov Nikolai , Cha Jin Kun
Published: September 2005

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Construction of Substituted N‐Hydroxyindoles: Synthesis of a Nocathiacin I Model System.
Authors: Nicolaou K. C. , Lee Sang Hyup , Estrada Anthony A. , Zak Mark
Published: September 2005

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Efficient and Catalytic Conversion of Epoxides into 1,3‐Dioxolanes with LiBF4.
Authors: Kazemi F. , Kiasat A. R. , Ebrahimi S.
Published: September 2005

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Benzoyl and/or Benzyl Substituted 1,2,3‐Triazoles as Potassium Channel Activators. Part 8.
Authors: Calderone Vincenzo , Giorgi Irene , Livi Oreste , Martinotti Enrica , Mantuano Elisabetta , Martelli Alma , Nardi Antonio
Published: September 2005

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A Convenient Synthesis of 1‐[6‐Fluoro‐(2S)‐3H,4H‐dihydro‐2H‐2‐chromenyl]‐(1R)‐1,2‐ethanediol and 1‐[6‐Fluoro‐(2R)‐3H,4H‐dihydro‐2H‐2‐chromenyl]‐(1R)‐1,2‐ethanediol.
Authors: Yu An‐Guang , Wang Nai‐Xing , Xing Ya‐Lan , Zhang Jun‐Ping , Yang Yun‐Xu , Wang Wu‐Wei , Sheng Rui‐long
Published: September 2005

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Rhodium‐Catalyzed Asymmetric 1,4‐Addition of Arylboronic Acids to Coumarins: Asymmetric Synthesis of (R)‐Tolterodine.
Authors: Chen Gang , Tokunaga Norihito , Hayashi Tamio
Published: September 2005

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Monolayer Protected Au Cluster (MPC)‐Bound Ru—Carbene Complex: Synthesis and Its Catalytic Activity in Ring‐Closing Olefin Metathesis.
Authors: Lee Bang Sook , Namgoong Sung Keon , Lee Sang‐gi
Published: September 2005

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Synthesis of Pyridine‐Thioethers via Mono‐ and Tricationic Pyridinium Salts.
Authors: Schmidt Andreas , Mordhorst Thorsten
Published: September 2005

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Microwave‐Promoted Synthesis of Amino‐Substituted 2‐Pyridone Derivatives via Palladium‐Catalyzed Amination Reaction.
Authors: Heo Jung‐Nyoung , Song Young Seob , Kim Bum Tae
Published: September 2005

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Triphenyl Phosphonium Perchlorate‐Catalyzed Imino Diels—Alder Synthesis of Azabicyclo[2.2.2]octan‐5‐ones.
Authors: Shanthi Gnanamani , Perumal Paramasivan T.
Published: September 2005

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Chelation‐Controlled Intermolecular Alkene and Alkyne Hydroacylation: The Utility of β‐Thioacetal Aldehydes.
Authors: Willis Michael C. , Randell‐Sly Helen E. , Woodward Robert L. , Currie Gordon S.
Published: September 2005

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Synthesis of Isomeric Pyridooxazinones, Pyridopyridazines and Triazolopyridopyridazines from o‐Aroylpyridinecarboxylic Acids.
Authors: Youssef Mohamed Salah K. , Fahmy Amin F. , Halim Mohamed S. Abdel , Hassan Mamdouh A.
Published: September 2005

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Thermally Induced Tandem Cycloaddition of 2‐Alkyl‐3‐phenylcyclopropenones to 6‐Aryl‐1,5‐diazabicyclo[3.1.0]hexanes.
Authors: Molchanov A. P. , Sipkin D. I. , Koptelov Yu. B. , Kostikov R. R.
Published: September 2005

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Antileishmanial Agents. Part 4. Synthesis and Antileishmanial Activity of Novel Terpenyl Pyrimidines.
Authors: Chandra Naveen , Ramesh Ramesh , Ashutosh Ashutosh , Goyal Neena , Suryawanshi S. N. , Gupta Suman
Published: September 2005

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Synthesis and Biological Activity of Some Mono‐ and Bis(ω‐ammonioalkyl)uracil Bromides
Authors: Zobov V. V. , Aslyamova A. A. , Berezinskii L. A. , Reznik V. S. , Akamsin V. D. , Galyametdinova I. V. , Giniyatullin R. H. , Nafikova A. A. , Latypov Sh. K.
Published: September 2005

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Heteroannulation of Nitroketene N,S‐Arylaminoacetals with POCl3: A Novel Highly Regioselective Synthesis of Unsymmetrical 2,3‐Substituted Quinoxalines.
Authors: Venkatesh C. , Singh B. , Mahata P. K. , Ila H. , Junjappa H.
Published: September 2005

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Synthesis and Functionalization of 3‐Ethylquinoxalin‐2(1H)‐one.
Authors: Mamedov V. A. , Kalinin A. A. , Gubaidullin A. T. , Isaikina O. G. , Litvinov I. A.
Published: September 2005

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An Iodoacetamide‐Based Free Radical Cyclization Approach to the 7,12‐Dihydro‐indolo[3,2‐d][1]benzazepin‐6(5H)‐one (Paullone) System.
Authors: Bremner John B. , Sengpracha Waya
Published: September 2005

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Ring‐Closing Metathesis (RCM) for the Synthesis of Cyclic Sulfoximines.
Authors: Bolm Carsten , Villar Helene
Published: September 2005

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Synthesis of Kinetically Stabilized 1‐Silanaphthalenes and Their Properties.
Authors: Shinohara Akihiro , Takeda Nobuhiro , Sasamori Takahiro , Tokitoh Norihiro
Published: September 2005

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Palladium‐Catalyzed Phosphorus—Carbon Bond Formation: Cross‐Coupling Reactions of Alkyl Phosphinates with Aryl, Heteroaryl, Alkenyl, Benzylic, and Allylic Halides and Triflates.
Authors: Bravo‐Altamirano Karla , Huang Zhihong , Montchamp Jean‐Luc
Published: September 2005

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γ‐Butyltelluro‐2‐butanol: A Route to Reactive 1,4‐Dianion Intermediates.
Authors: Princival Jefferson L. , de Barros Simone M. G. , Comasseto Joao V. , Dos Santos Alcindo A.
Published: September 2005

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Stannylated Allylsulfones as Versatile New Building Blocks.
Authors: Kazmaier Uli , Wesquet Alexander
Published: September 2005

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Enantioselective Catalytic Diamination of Alkenes with a Bisimidoosmium Oxidant.
Authors: Muniz Kilian , Nieger Martin
Published: September 2005

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Heterocycle‐Substituted Carbohydrate Oxazolines.
Authors: DeCastro Michael , Marzabadi Cecilia H.
Published: September 2005

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New Cytotoxic Bisindole Alkaloids with Protein Tyrosine Kinase Inhibitory Activity from a Myxomycete Lycogala epidendrum.
Authors: Hosoya Takahiro , Yamamoto Yukinori , Uehara Yoshimasa , Hayashi Masahiko , Komiyama Kanki , Ishibashi Masami
Published: September 2005

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Epoxytwinol A, a Novel Unique Angiogenesis Inhibitor with C2 Symmetry, Produced by a Fungus
Authors: Kakeya Hideaki , Onose Rie , Koshino Hiroyuki , Osada Hiroyuki
Published: September 2005

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Bioactive Marine Metabolites. Part 132. Mycapolyols A—F, New Cytotoxic Metabolites of Mixed Biogenesis from the Marine Sponge Mycale izuensis
Authors: Phuwapraisirisan Preecha , Matsunaga Shigeki , Fusetani Nobuhiro
Published: September 2005

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A Novel and Convenient Method for the Synthesis of Phenstatin.
Authors: Wu Maojiang , Ji Qinggang , Yang Chunhao , Xie Yuyuan
Published: September 2005

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Exploitation of CO‐Operative Directed ortho‐Metalation (DoM) by 1,3‐Related ‐OMOM Groups in the Development of a Fully Regio‐Controlled Synthesis of Atranol from Orcinol.
Authors: Banwell Martin G. , Chand Satish
Published: September 2005

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A Cobalt‐Free Oxygen‐Permeable Membrane Based on the Perovskite‐Type Oxide Ba0.5Sr0.5Zn0.2Fe0.8 O3‐δ.
Authors: Wang Haihui , Tablet Cristina , Feldhoff Armin , Caro Juergen
Published: September 2005

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Theory of Manganites
Authors: Hotta Takashi , Dagotto Elbio
Published: September 2005

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The Development of Crystal Growth Technology
Authors: Scheel Hans J.
Published: September 2005

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Determination of Dispersion and Supported Metal Crystallite Size
Authors: Anderson J. A. , Fernandez‐Garcia M. , Martinez‐Arias A.
Published: September 2005

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Characterization of Supported Metal Catalysts by Spectroscopic Techniques
Authors: Fernandez‐Garcia M. , Anderson J. A.
Published: September 2005

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Linking Multiple Bonds Between Metal Atoms: Clusters, Dimers of “Dimers” and Higher Ordered Assemblies
Authors: Chisholm Malcolm H. , Macintosh Ann M.
Published: September 2005

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Recent Advances in Catalytic, Enantioselective α Aminations and α Oxygenations of Carbonyl Compounds
Authors: Janey Jacob M.
Published: September 2005

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Metathesis Reactions in Total Synthesis
Authors: Nicolaou K. C. , Bulger Paul G. , Sarlah David
Published: September 2005

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Rapid Progress in Palladium‐Catalyzed Reactions: Novel Palladium‐Catalyzed Reactions Recently Discovered
Authors: Tsuji Jiro
Published: September 2005

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Polydepsipeptides: A Systematic Investigation of Guest—Host Effects
Authors: Mammi Stefano , Goodman Murray
Published: September 2005

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Fluorine‐Containing Amino, Hydroxy and Mercapto Acids, Versatile Tools for Peptide and Depsipeptide Modification
Authors: Burger Klaus , Hennig Lothar
Published: September 2005

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Recent Carbohydrate‐Based Chemoselective Ligation Applications
Authors: Langenhan Joseph M. , Thorson Jon S.
Published: September 2005

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The Invention of the Alkynol Cycloisomerization Reaction: Application to the Synthesis of Digitoxin
Authors: McDonald Frank E.
Published: September 2005

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Heterocyclic Chemistry Using Microwave‐Assisted Approaches
Authors: Besson Thierry , Brain Christopher T.
Published: September 2005

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Generation of Triplet Carbenes Through Photolysis of Iodonium Ylides
Authors: Lenington Matthew J. , deLuca JoAnn P.
Published: September 2005

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Microwave‐Assisted Solid‐Phase Synthesis
Authors: Stadler Alexander , Kappe C. Oliver
Published: September 2005

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A Timely Reassessment of Early Prediction in the Bioavailability of Orally Administered Drugs
Authors: Larsen Tim , Link Andreas
Published: September 2005

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N‐Containing Compounds of Macromycetes
Authors: Liu Ji‐Kai
Published: September 2005

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Applications of Two‐Phase Anaerobic Degradation in Industrial Wastewater Treatment
Authors: Ke Shuizhou , Shi Zhou , Fang Herbert H. P.
Published: September 2005

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Reaction Progress Kinetic Analysis: A Powerful Methodology for Mechanistic Studies of Complex Catalytic Reactions
Authors: Blackmond Donna G.
Published: September 2005

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Sensitivity Analysis for Chemical Models
Authors: Saltelli Andrea , Ratto Marco , Tarantola Stefano , Campolongo Francesca
Published: September 2005

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Mechanochemistry: The Mechanical Activation of Covalent Bonds
Authors: Beyer Martin K. , Clausen‐Schaumann Hauke
Published: September 2005

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Return Electron Transfer in Radical Ion Pairs of Triplet Multiplicity
Authors: Roth Heinz D.
Published: September 2005

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Determination of Water‐ and Fat‐Soluble Vitamins in Different Matrices Using High‐Performance Liquid Chromatography
Authors: Jedlicka A. , Klimes J.
Published: September 2005

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Pulsed Gradient Spin—Echo (PGSE) Diffusion and 1H,19F Heteronuclear Overhauser Spectroscopy (HOESY) NMR Methods in Inorganic and Organometallic Chemistry: Something Old and Something New
Authors: Pregosin Paul S. , Kumar P. G. Anil , Fernandez Ignacio
Published: September 2005

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Nuclear Magnetic Resonance Imaging
Authors: Watanabe Tokuko
Published: September 2005

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Nuclear Spin Relaxation in Liquids and Gases
Authors: Ludwig R.
Published: September 2005

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Structures of the Trisulfur Oxides S3O and S3O×+: Branched Rings, Not Open Chains
Authors: Wong Ming Wah , Steudel Ralf
Published: September 2005

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Heavy‐Metal Aromatic and Conjugated Species: Rings, Oligomers, and Chains of Tin in Li9‐xEuSn6+x, Li9‐xCaSn6+x, Li5Ca7Sn11, Li6Eu5Sn9, LiMgEu2Sn3, and LiMgSr2Sn3.
Authors: Todorov Iliya , Sevov Slavi C.
Published: September 2005

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Crystal Chemistry and Microwave Dielectric Properties of Ba3MNb2‐xSbxO9 (M: Mg, Ni, Zn).
Authors: Lufaso Michael W. , Hopkins Elizabeth , Bell Steven M. , Llobet Anna
Published: September 2005

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Photodegradation Catalyst Discovery by High‐Throughput Experiment.
Authors: Dai Qi X. , Xiao Hai Y. , Li Wen S. , Na Yan Q. , Zhou Xiao P.
Published: September 2005

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Ag+‐Inserted NbO2F as a Novel Photocatalyst.
Authors: Murase Takashi , Irie Hiroshi , Hashimoto Kazuhito
Published: September 2005

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Synthesis and Characterization of Ti‐HMS and CoMo/Ti‐HMS Oxide Materials with Varying Ti Content.
Authors: Zepeda T. A. , Fierro J. L. G. , Pawelec B. , Nava R. , Klimova T. , Fuentes G. A. , Halachev T.
Published: September 2005

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Synthesis, Electrochemistry, and Structural Studies of Lithium Intercalation of a Nanocrystalline Li2MnO3‐Like Compound.
Authors: Jain Gaurav , Yang Jingsi , Balasubramanian Mahalingam , Xu Jun John
Published: September 2005

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Attempts to Prepare t‐BuCN5S3 and the Unexpected Isolation of a Covalent Modification of Tetrasulfur‐Pentanitrogen Chloride S4N5Cl.
Authors: Knapp Carsten , Lork Enno , Borrmann Tobias , Stohrer Wolf‐Dieter , Mews Ruediger
Published: September 2005

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Structural Characterization of the First Hydroxo‐Bridged Plutonium Compound, (PuO2)2(IO3) (μ2‐OH)3.
Authors: Bean Amanda C. , Abney Kent , Scott Brian L. , Runde Wolfgang
Published: September 2005

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Unusual Syntheses, Structures, and Electronic Properties of Compounds Containing Ternary, T3‐Type Supertetrahedral M/Sn/S Anions [M5Sn(μ3‐S)4 (SnS4)4]10‐ (M: Zn, Co).
Authors: Zimmermann Christian , Anson Christopher E. , Weigend Florian , Clerac Rodolphe , Dehnen Stefanie
Published: September 2005

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Synthesis and Crystal Structure Determination by X‐Ray Powder Diffraction of Nickel Tetrametaphosphimate Octahydrate Ni2(PO2NH)4×8H2O.
Authors: Roemer S. Rebecca , Schnick Wolfgang
Published: September 2005

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