bluuebunny/crossref_metadata_2025 huggingface dataset:
Petrology and origin of amoeboid olivine aggregates in CR chondrites
Authors: WEISBERG Michael K. , CONNOLLY Harold C. , EBEL Denton S.
Published: January 2010

Abstract— Amoeboid olivine aggregates (AOAs) are irregularly shaped, fine‐grained aggregates of olivine and Ca, Al‐rich minerals and are important primitive components of CR chondrites. The AOAs in CR chondrites contain FeNi metal, and some AOAs contain Mn‐rich forsterite with up to 0.7 MnO and Mn:Fe ratios greater than one. Additionally, AOAs in the CR chondrites do not contain secondary phases (nepheline and fayalitic olivine) that are found in AOAs in some CV chondrites. The AOAs in CR chondrites record a complex petrogenetic history that included nebular gas‐solid condensation, reaction of minerals with the nebular gas, small degrees of melting, and sintering of the assemblage. A condensation origin for the Mn‐rich forsterite is proposed. The Mn‐rich forsterite found in IDPs, unequilibrated ordinary chondrite matrix, and AOAs in CR chondrites may have had a similar origin.

A type A calcium, aluminum‐rich inclusion (CAI) with an AOA attached to its Wark‐Lovering rim is also described. This discovery reveals a temporal relationship between AOAs and type A inclusions. Additionally, a thin layer of forsterite is present as part of the Wark‐Lovering rim, revealing the crystallization of olivine at the end stages of Wark‐Lovering rim formation. The Ca, Al‐rich nodules in the AOAs may be petrogenetically related to the Ca, Al‐rich minerals in Wark‐Lovering rims on type A CAIs. AOAs are chondrite components that condensed during the final stage of Wark‐Lovering rim formation but, in general, were temporally, spatially, or kinetically isolated from reacting with the nebula vapor during condensation of the lower temperature minerals that were commonly present as chondrule precursors.
Anomalous Mössbauer parameters in the second generation regolith Ghubara meteorite
Authors: VERMA H. C. , TRIPATHI R. P.
Published: January 2010

Abstract— We conducted Mössbauer spectroscopic studies on the Ghubara meteorite which had been described as at least two‐generation regolith breccia on the macro scale. The isomer shift and quadrupole splitting of the Fe‐Ni part are quite different from those obtained in ordinary chondrites, reflecting shock effects. We observed a large amount of magnetite that may have come from weathering of, primarily, the silicate fraction. We found very similar iron mineralogy in the Densmore meteorite.
The orbit, atmospheric dynamics, and initial mass of the Park Forest meteorite
Authors: BROWN P. , PACK D. , EDWARDS W. N. , REVELLE D. O. , YOO B. B. , SPALDING R. E. , TAGLIAFERRI E.
Published: January 2010

Abstract— The fireball accompanying the Park Forest meteorite fall (L5) was recorded by ground‐based videographers, satellite systems, infrasound, seismic, and acoustic instruments. This meteorite shower produced at least 18 kg of recovered fragments on the ground (Simon et al. 2004). By combining the satellite trajectory solution with precise ground‐based video recording from a single site, we have measured the original entry velocity for the meteoroid to be 19.5 ± 0.3 km/s. The earliest video recording of the fireball was made near the altitude of 82 km. The slope of the trajectory was 29° from the vertical, with a radiant azimuth (astronomical) of 21° and a terminal height measured by infrared satellite systems of 18 km. The meteoroid's orbit has a relatively large semi‐major axis of 2.53 ± 0.19 AU, large aphelion of 4.26 ± 0.38 AU, and low inclination. The fireball reached a peak absolute visual magnitude of −22, with three major framentation episodes at the altitudes of 37, 29, and 22 km. Acoustic recordings of the fireball airwave suggest that fragmentation was a dominant process in production of sound and that some major fragments from the fireball remained supersonic to heights as low as ˜10 km. Seismic and acoustic recordings show evidence of fragmentation at 42, 36, 29, and 17 km. Examination of implied energies/initial masses from all techniques (satellite optical, infrasound, seismic, modeling) leads us to conclude that the most probable initial mass was (11 ± 3) × 103 kg, corresponding to an original energy of ˜0.5 kt TNT (2.1 times 1012 J) and a diameter of 1.8 m. These values correspond to an integral bolometric efficiency of 7 ± 2%. Early fragmentation ram pressures of <1 MPa and major fragmentations occurring with ram pressures of 2–5 MPa suggest that meter‐class stony near‐Earth asteroids (NEAs) have tensile strengths more than an order of magnitude lower than have been measured for ordinary chondrites. One implication of this observation is that the rotation period for small, fast‐rotating NEAs is likely to be >30 seconds.
Pressure effects on martian crustal magnetization near large impact basins
Authors: KLETETSCHKA Gunther , CONNERNEY John E. P. , NESS Norman F. , ACUÑA Mario H.
Published: January 2010

Abstract— Martian crust endured several large meteoroid impacts subsequent to the demise of an early global magnetic field. Shock pressures associated with these impacts demagnetized parts of the crust, to an extent determined by shock resistance of magnetic materials in the crust. Impacts that form large basins generate pressures in excess of 1 GPa within a few crater radii of their impact sites. Crustal materials near the surface experience significantly reduced impact pressure, which varies with depth and distance from the impact point. We present new demagnetization experiments on magnetite (Fe3O4), hematite (α‐Fe2O3), and titanohematite (Fe2‐xTixO3 where x <0.2). Our measurements show that pressures of ˜1 GPa are sufficient to partially demagnetize all of these minerals. The efficiency of demagnetization by impact pressure is proportional to the logarithm of the minerals' magnetic coercivity. The impact pressure magnetic response from exsolved titanohematite samples is consistent with the magnetization decay near Prometheus impact basin and may point to an oxidized igneous rock in Terra Sirenum region at the time of acquisition of magnetic remanence. The remaining magnetic anomalies near large impact basins suggest moderate crustal coercivity. These anomalies point to titanomagnetite as a magnetic carrier and more reduced condition during crustal formation.
Potassium diffusion in melilite: Experimental studies and constraints on the thermal history and size of planetesimals hosting CAIs
Authors: ITO Motoo , GANGULY Jibamitra
Published: January 2010

Abstract— Among the calcium‐aluminum‐rich inclusions (CAIs), excess 41K (41K*), which was produced by the decay of the short‐lived radionuclide 41Ca (t1/2 = 0.1 Myr), has so far been detected in fassaite and in two grains of melilites. These observations could be used to provide important constraints on the thermal history and size of the planetesimals into which the CAIs were incorporated, provided the diffusion kinetic properties of K in these minerals are known. Thus, we have experimentally determined K diffusion kinetics in the melilite end‐members, åkermanite and gehlenite, as a function of temperature (900–1200 °C) and crystallographic orientation at 1 bar pressure. The closure temperature of K diffusion in melilite, Tc(K:mel), for the observed grain size of melilite in the CAIs and cooling rate of 10–100 °C/Myr, as calculated from our diffusion data, is much higher than that of Mg in anorthite. The latter was calculated from the available Mg diffusion data in anorthite. Assuming that the planetesimals were heated by the decay of 26Al and 60Fe, we have calculated the size of a planetesimal as a function of the accretion time tf such that the peak temperature at a specified radial distance rc equals Tc(K:mel). The ratio (rc/R)3 defines the planetesimal volume fraction within which 41K* in melilite grains would be at least partly disturbed, if these were randomly distributed within a planetesimal. A similar calculation was also carried out to define R versus tf relation such that 26Mg* was lost from ˜50% of randomly distributed anorthite grains, as seems to be suggested by the observational data. These calculations suggest that ˜60% of melilite grains should retain 41K* if ˜50% of anorthite grains had retained 26Mg*. Assuming that tf was not smaller than the time of chondrule formation, our calculations yield minimum planetesimal radius of ˜20–30 km, depending on the choice of planetesimal surface temperature and initial abundance of the heat producing isotope 60Fe.
Radiogenic isotope investigation of the St‐Robert H5 fall
Authors: POIRIER André , DOUCELANCE Régis , GARIÉPY Clément
Published: January 2010

Abstract— The St‐Robert H5 chondrite yields a mineral/whole‐rock Pb‐Pb age of 4565 ± 23 Ma (2σ) comparable to the accepted age of most chondrites. The regression of chondrule data give a similar age of 4566 ± 7 Ma (2σ). These results imply that no major perturbation affected the Pb‐Pb systematics of this meteorite's parent body within the first few billion years following its accretion. Re and Os concentrations along with Os isotopic compositions of whole‐rock fragments, surface fusion crusts and metal phases are also reported. The whole rock measurements for this ordinary chondrite are characterized by high Re/Os ratio coupled with relatively high 187Os/188Os (compared to average ordinary chondrites), that we interpret as a long term Re enrichment. As for most chondrites, no precise geochronological information could be extracted from the Re/Os systematics, although most data plot near the IIIAB reference isochron (Smoliar et al. 1996). From the fusion crust results, we rule out the possibility that atmospheric entry caused the perturbations in the Re‐Os system, since melted crust analysis yields among the most concordant data points. Evidence from metal phases suggests that a very recent process perturbed the isochron, relocating Re from kamacite toward troilite.
NWA 1152 and Sahara 00182: New primitive carbonaceous chondrites with affinities to the CR and CV groups
Authors: SMITH Caroline L. , RUSSELL Sara S. , GOUNELLE Matthieu , GREENWOOD Richard C. , FRANCHI Ian A.
Published: January 2010

Abstract— We have investigated the mineralogy, petrography, bulk chemistry, and light element isotope composition of the ungrouped chondrites North West Africa (NWA) 1152 and Sahara 00182.

NWA 1152 contains predominantly type 1 porphyritic olivine (PO) and porphyritic olivinepyroxene (POP) chondrules. Chondrule silicates are magnesium‐rich (Fo98.8 ± 1.2, n = 36; Fs2.3 ± 2.1 Wo1.2 ± 0.3, n = 23). Matrix comprises ˜40 vol% of the sample and is composed of a micron sized silicate groundmass with larger silicate, sulfide, magnetite, and Fe‐Ni metal (Ni ˜50 wt%) grains. Phyllosilicates were not observed in the matrix. Refractory inclusions are rare (0.3 vol%) and are spinel pyroxene aggregates or amoeboid olivine aggregates; melilite is absent from the refractory inclusions. Sahara 00182 contains predominantly type 1 PO chondrules, POP chondrules are less common. Most chondrules contain blebs of, and are often rimmed with, Fe‐Ni metal and sulfide. Chondrule phenocrysts are magnesium‐rich (Fo92.2 ± 0.6, n = 129; Fs4.4 ± 1.8 Wo1.3 ± 1.1, n = 16). Matrix comprises ˜30 vol% of the meteorite and is predominantly sub‐micron silicates, with rare larger silicate gains. Matrix Fe‐Ni metal (mean Ni = 5.8 wt%) and sulfide grains are up to mm scale. No phyllosilicates were observed in the matrix. Refractory inclusions are rare (1.1 vol%) and melilite is absent. The oxygen isotope composition of NWA 1152 falls within the range of the CV chondrites with δ17O = −3.43%0 δ18O = 0.70%0 and is similar to Sahara 00182, δ17O = −3.89%0, δ18O = −0.19%0 (Grossman and Zipfel 2001).

Based on mineralogical and petrographic characteristics, we suggest NWA 1152 and Sahara 00182 show many similarities with the CR chondrites, however, oxygen isotopes suggest affinity with the CVs. Thus, neither sample can be assigned to any of the currently known carbonaceous chondrite groups based on traditionally recognized characteristics. Both samples demonstrate the complexity of inter‐ and intra‐group relationships of the carbonaceous chondrites. Whatever their classification, N WA 1152 and Sahara 00182 represent a source of relatively pristine solar system material.
High‐pressure phases in shock‐induced melt veins of the Umbarger L6 chondrite: Constraints of shock pressure
Authors: XIE Zhidong , SHARP Thomas G.
Published: January 2010

Abstract— We report a previously undocumented set of high‐pressure minerals in shock‐induced melt veins of the Umbarger L6 chondrite. High‐pressure minerals were identified with transmission electron microscopy (TEM) using selected area electron diffraction and energy‐dispersive X‐ray spectroscopy. Ringwoodite (Fa30), akimotoite (En11Fs89), and augite (En42Wo33Fs25) were found in the silicate matrix of the melt vein, representing the crystallization from a silicate melt during the shock pulse. Ringwoodite (Fa27) and hollandite‐structured plagioclase were also found as polycrystalline aggregates in the melt vein, representing solid state transformation or melting with subsequent crystallization of entrained host rock fragments in the vein. In addition, Fe2SiO4‐spinel (Fa66‐Fa99) and stishovite crystallized from a FeO‐SiO2‐rich zone in the melt vein, which formed by shock melting of FeO‐SiO2‐rich material that had been altered and metasomatized before shock. Based on the pressure stabilities of the high‐pressure minerals, ringwoodite, akimotoite, and Ca‐clinopyroxene, the melt vein crystallized at approximately 18 GPa. The Fe2SiO4‐spinel + stishovite assemblage in the FeO‐SiO2‐rich melts is consistent with crystallization of the melt vein matrix at the pressure up to 18 GPa. The crystallization pressure of ˜18 GPa is much lower than the 45–90 GPa pressure one would conclude from the S6 shock effects in melt veins (Stöffler et al. 1991) and somewhat less than the 25–30 GPa inferred from S5 shock effects (Schmitt 2000) found in the bulk rock.
Dynamical and compositional assessment of near‐Earth object mission targets
Authors: BINZEL Richard P. , PEROZZI Ettore , RIVKIN Andrew S. , ROSSI Alessandro , HARRIS Alan W. , BUS Schelte J. , VALSECCHI Giovanni B. , SLIVAN Stephen M.
Published: January 2010

Abstract— Using an H‐plot analysis, we identify 234 currently known near‐Earth objects that are accessible for rendezvous with a “best case” delta‐V of less than 7 km/s. We provide a preliminary compositional interpretation and assessment of these potential targets by summarizing the taxonomic properties for 44 objects. Results for one‐half (22) of this sample are based on new spectroscopic measurements presented here. Our approach provides an easy‐to‐update method for giving guidelines to both observers and mission analysts for focusing on objects for which actual mission opportunities are most likely to be found. Observing prospects are presented for categorizing the taxonomic properties of the most accessible targets that are not yet measured.
Simulation of the interaction of galactic cosmic ray protons with meteoroids: On the production of 3H and light noble gas isotopes in isotropically irradiated thick gabbro and iron targets
Authors: LEYA I. , BEGEMANN F. , WEBER H. W. , WIELER R. , MICHEL R.
Published: January 2010

Abstract— Thick spherical targets, one made of gabbro (R = 25 cm) and one made of iron (R = 10 cm), were irradiated isotropically with 1.6 GeV protons at Laboratoire National Saturne (LNS)/Saclay to simulate the interactions of galactic cosmic ray protons with meteoroids in space. At various depths, both artificial meteoroids contained a large number of high‐purity, single‐element target foils and chemical compounds of up to 28 target elements. In these individual target foils, the elemental production rates of radionuclides and noble gas isotopes were measured. Here, we report the results for the light noble gas isotopes 3,4He, 20,21,22Ne, and 36,38,39Ar for the most cosmochemically relevant target elements as well as for some meteoritic material from Jilin, Farmington, and Cape York. From 3He analyses done several years apart, 3H diffusive losses during sample storage have been obtained, and direct as well as cumulative 3He production rates for O, Mg, Al, Si, Fe, Ni, and the meteoritic material are given. Losses by diffusion of tritium from metallic Mg and Fe are found to occur on time scales of months, while metallic Al, Si, and stone meteorites are much more retentive. The production rate ratios P(3H)/P(3He)d obtained in the simulation experiments are 0.73, 1.28, and 1.16 for O, Al, and Si, respectively. These rates are based on our best knowledge about the 3H and 3He production rates and should, therefore, replace data published earlier (Leya et al. 2000a). The earlier calculations for 4He, 20,21,22Ne, and 36,38,39Ar remain valid.

The new modeled correlation 3Hecum/21Ne versus 22Ne/21Ne for chondrites exposed to cosmic rays with an energy spectrum characterized by a modulation parameter of φ = 650 MeV is in fair agreement with the empirical relationship (“Berne plot”). However, for small meteorites and little shielding in larger ones, there are systematic differences that most likely are due to an underestimation of the spallogenic 22Ne/21Ne ratio by ˜2%.
Ejecta formation and crater development of the Mjølnir impact
Authors: SHUVALOV Valery , DYPVIK Henning
Published: January 2010

Abstract— Crater‐ejecta correlation is an important element in the analysis of crater formation and its influence on the geological evolution. In this study, both the ejecta distribution and the internal crater development of the Jurassic/Cretaceous Mjølnir crater (40 km in diameter; located in the Barents Sea) are investigated through numerical simulations. The simulations show a highly asymmetrical ejecta distribution, and underscore the importance of a layer of surface water in ejecta distribution. As expected, the ejecta asymmetry increases as the angle of impact decreases. The simulation also displays an uneven aerial distribution of ejecta.

The generation of the central high is a crucial part of crater formation. In this study, peak generation is shown to have a skewed development, from approximately 50–90 sec after impact, when the peak reaches its maximum height of 1‐1.5 km. During this stage, the peak crest is moved about 5 km from an uprange to a downrange position, ending with a final central position which has a symmetrical appearance that contrasts with its asymmetrical development.
Halite and stable chlorine isotopes in the Zag H3–6 breccia
Authors: Bridges J. C. , Banks D. A. , Smith M. , Grady M. M.
Published: January 2010

Abstract— Zag is an H3‐6 chondrite regolith breccia within which we have studied 14 halite grains ≤3 mm. The purity of the associated NaCl‐H2O brine is implied by freezing characteristics of fluid inclusions in the halite and EPMA analyses together with a lack of other evaporite‐like phases in the Zag H3–6 component. This is inconsistent with multi‐stage evolution of the fluid involving scavenging of cations in the Zag region of the parent body. We suggest that the halite grains are clastic and did not crystallize in situ. Halite and water‐soluble extracts from Zag have light Cl isotopic compositions, δ37Cl = −1.4 to −2.8%. Previously reported bulk carbonaceous chondrite values are approximately δ37Cl = +3 to +4%. This difference is too great to be the result of fractionation during evaporation, and instead, we suggest that Cl isotopes in chondrites are fractionated between a light reservoir associated with fluids and a heavier reservoir associated with higher temperature phases such as phosphates and silicates. Extraterrestrial carbon released at 600 °C from the H3–4 matrix has δ13C = −20%, consistent with poorly graphitized material being introduced into the matrix rather than indigenous carbonate derived from a brine. We have also examined 28 other H chondrite falls to ascertain how widespread halite or evaporite‐like mineral assemblages are in ordinary chondrites. We did not find any more to add to Zag (H3‐6) and Monahans (H5), which suggests that such highly soluble phases were not usually preserved on the parent bodies.
Pyroxene microstructure in the Northwest Africa 856 martian meteorite
Authors: Leroux Hugues , Devouard Bertrand , Cordier Patrick , Guyot François
Published: January 2010

Abstract— Transmission electron microscopy was used to examine pyroxene microstructure in the Northwest Africa (NWA) 856 martian meteorite to construct its cooling and shock histories. All pyroxenes contain strained coherent pigeonite/augite exsolution lamellae on (001). The average width and periodicity of lamellae are 80 and 400 nm, respectively, indicating a cooling rate below 0.1 °C/hr for the parent rock. Pigeonite and augite are topotactic, with strained coherent interfaces parallel to (001). The closure temperature for Ca‐Fe, Mg interdiffusion, estimated from the composition at the augite pigeonite interface, is about 700 °C. Tweed texture in augite reveals that a spinodal decomposition occurred. Locally, tweed evolved toward secondary pigeonite exsolutions on (001). Due to the decreasing diffusion rate with decreasing temperature, “M‐shaped” concentration profiles developed in augite lamellae. Pigeonite contains antiphase boundaries resulting from the C2/c to P21/c space group transition that occurred during cooling. The reconstructive phase transition from P21/c clinopyroxene to orthopyroxene did not occur. The deformation (shock) history of the meteorites is revealed by the presence of dislocations and mechanical twins. Dislocations are found in glide configuration, with the [001](100) glide system preferentially activated. They exhibit strong interaction with the strained augite/pigeonite interfaces and did not propagate over large distances. Twins are found to be almost all parallel to (100) and show moderate interaction with the augite/pigeonite interfaces. These twins are responsible for the plastic deformation of the pyroxene grains. Comparison with microstructure of shocked clinopyroxene (experimentally or naturally shocked) suggests that NWA 856 pyroxenes are not strongly shocked.
SUPRACENTER: Locating fireball terminal bursts in the atmosphere using seismic arrivals
Authors: EDWARDS W. N. , HILDEBRAND A. R.
Published: January 2010

Abstract— Terminal bursts and fragmentations of meteoritic fireballs in the atmosphere may now be accurately located in four dimensions (three spatial + temporal) using seismic arrival times of their acoustic waves recorded by seismometer, camera, microphone, and/or infrasound stations on the ground. A computer program, SUPRACENTER, calculates travel times by ray tracing through realistic atmospheres (that include winds) and locates source positions by minimization of travel time residuals. This is analogous to earthquake hypocenter location in the solid Earth but is done through a variably moving medium. Inclusion of realistic atmospheric ray tracing has removed the need for the simplifying assumption of an isotropic atmosphere or an approximation to account for “wind drift.” This “drift” is on the order of several km when strong, unidirectional winds are present in the atmosphere at the time of a fireball's occurrence. SUPRACENTER‐derived locations of three seismically recorded fireballs: 1) the October 9, 1997 El Paso superbolide; 2) the January 25, 1989 Mt. Adams fireball; and 3) the May 6, 2000 Morávka fireball (with its associated meteorite fall), are consistent with (and, probably, an improvement upon) the locations derived from eyewitness, photographic, and video observations from the respective individual events. If direct acoustic seismic arrivals can be quickly identified for a fireball event, terminal burst locations (and, potentially, trajectory geometry and velocity information) can be quickly derived, aiding any meteorite recovery efforts during the early days after the fall. Potentially, seismic records may yield enough trajectory information to assist in the derivation of orbits for entering projectiles.
Shocked rocks and impact glasses from the El'gygytgyn impact structure, Russia
Authors: GUROV Eugene P. , KOEBERL Christian
Published: January 2010

Abstract— The El'gygytgyn impact structure is about 18 km in diameter and is located in the central part of Chukotka, arctic Russia. The crater was formed in volcanic rock strata of Cretaceous age, which include lava and tuffs of rhyolites, dacites, and andesites. A mid‐Pliocene age of the crater was previously determined by fission track (3.45 ± 0.15 Ma) and 40Ar/39Ar dating (3.58 ± 0.04 Ma). The ejecta layer around the crater is completely eroded. Shock‐metamorphosed volcanic rocks, impact melt rocks, and bomb‐shaped impact glasses occur in lacustrine terraces but have been redeposited after the impact event.

Clasts of volcanic rocks, which range in composition from rhyolite to dacite, represent all stages of shock metamorphism, including selective melting and formation of homogeneous impact melt. Four stages of shocked volcanic rocks were identified: stage I (≤35 GPa; lava and tuff contain weakly to strongly shocked quartz and feldspar clasts with abundant PFs and PDFs; coesite and stishovite occur as well), stage II (35–45 GPa; quartz and feldspar are converted to diaplectic glass; coesite but no stishovite), stage III (45–55 GPa; partly melted volcanic rocks; common diaplectic quartz glass; feldspar is melted), and stage IV (>55 GPa; melt rocks and glasses). Two main types of impact melt rocks occur in the crater: 1) impact melt rocks and impact melt breccias (containing abundant fragments of shocked volcanic rocks) that were probably derived from (now eroded) impact melt flows on the crater walls, and 2) aerodynamically shaped impact melt glass “bombs” composed of homogeneous glass. The composition of the glasses is almost identical to that of rhyolites from the uppermost part of the target. Cobalt, Ni, and Ir abundances in the impact glasses and melt rocks are not or only slightly enriched compared to the volcanic target rocks; only the Cr abundances show a distinct enrichment, which points toward an achondritic projectile. However, the present data do not allow one to unambiguously identify a meteoritic component in the El'gygytgyn impact melt rocks.
Structural evidence from shock metamorphism in simple and complex impact craters: Linking observations to theory
Authors: Dence Michael R.
Published: January 2010

Abstract— The structure of Canadian impact craters formed in crystalline rocks is analyzed using shock metamorphism and evidence for movement along shear zones. The analysis is based on an interpretation that, beyond the near field region, shock pressure attenuates down axis as P ˜ R−2, in agreement with nuclear test and computed results, and as P ˜ R−3 near the surface. In both simple and complex craters, the transient cavity is defined by the limit of fragmentation due to direct and reflected shock waves. The intersection of the transient cavity with hemispheric shock isobars indicates that the transient cavity has a parabolic form. Weakening by dilation during early uplift allows late stage slumping of the walls of simple craters. This is controlled by a spheroidal primary shear of radius rs ∼ 2dt, where dt is the depth of the transient crater due to excavation and initial compression. With increasing crater diameter, the size of the transient cavity decreases relative to the shock imprint, suggesting that fragmentation and excavation is limited by progressively earlier collapse of the margins under gravity. Central peak formation in complex craters may be initiated by relaxation of the shock‐compressed central parautochthone, so the primary shear, lubricated by friction melting, meets below the crater floor and drives the continuing upward motion.
Unusual large chromite crystals in the Saint Aubin iron meteorite
Authors: Fehr Karl Thomas , Carion Alain
Published: January 2010

Abstract— In the Saint Aubin octahedrite, chromite crystals of up to 3 cm occur enclosed in the metal phase. They are twinned along [111] according to the spinel law and display pseudohexagonal shapes in cross‐sections. The crystals are homogeneous and exhibit compositions close to pure chromite endmember. Vanadium is the only additional element observed in appreciable amounts of up to 0.73 wt%. Chromite in the Saint Aubin meteorite crystallized from liquids with very low amounts of Cr and O close to the Fe‐FeS join as indicated by its composition and phase relations. The growth of large chromite crystals implies stable supersaturated conditions for a long period in the meteorite parent body of Saint Aubin.
The frequency of compound chondrules and implications for chondrule formation
Authors: Ciesla Fred J. , Lauretta Dante S. , Hood Lon L.
Published: January 2010

Abstract— The properties of compound chondrules and the implications that they have for the conditions and environment in which chondrules formed are investigated. Formulae to calculate the probability of detecting compound chondrules in thin sections are derived and applied to previous studies. This reinterpretation suggests that at least 5% of chondrules are compounds, a value that agrees well with studies in which whole chondrules were removed from meteorites. The observation that adhering compounds tend to have small contact arcs is strengthened by application of these formulae. While it has been observed that the secondaries of compound chondrules are usually smaller than their primaries, these same formulae suggest that this could be an observation bias. It is more likely than not that thin section analyses will identify compounds with secondaries that are smaller than their primaries. A new model for chondrule collisional evolution is also developed. From this model, it is inferred that chondrules would have formed, on average, in areas of the solar nebula that had solids concentrated at least 45 times over the canonical solar value.
Experimental study of the degradation of polymers: Application to the origin of extended sources in cometary atmospheres
Authors: Fray N. , Bénilan Y. , Cottin H. , Gazeau M.‐C. , Minard R. D. , Raulin F.
Published: January 2010

Abstract— This paper presents some preliminary results concerning the degradation of refractory nitrogenated polymers, which could be responsible for the CN extended source in comets. We are studying hexamethylenetetramine (HMT) and HCN polymers. Both compounds have been irradiated or heated to simulate the degradation processes they undergo in the cometary atmosphere. We show that, even if both compounds are quite stable under photolysis, the heating leads to a much more efficient degradation with the formation of HCN, NH3, and other heavier compounds. Moreover, the thermal degradation of HCN polymers appears to be more efficient than that of HMT. Thus, the HCN polymers seem to be better candidates for the CN extended source. We are now developing a new reactor to quantify the production of gaseous molecules and to detect in situ CN radicals.
Physical properties of rocks from the upper part of the Yaxcopoil‐1 drill hole, Chicxulub crater
Authors: Popov Y. , Romushkevich R. , Bayuk I. , Korobkov D. , Mayr S. , Burkhardt H. , Wilhelm H.
Published: January 2010

Abstract— Physical properties were determined in a first step on post‐impact tertiary limestones from the depth interval of 404–666 m of the Yaxcopoil‐1 (Yax‐1) scientific well, drilled in the Chicxulub impact crater (Mexico). Thermal conductivity, thermal diffusivity, density, and porosity were measured on 120 dry and water‐saturated rocks with a core sampling interval of 2–2.5 m. Nondestructive, non‐contact optical scanning technology was used for thermal property measurements including thermal anisotropy and inhomogeneity. Supplementary petrophysical properties (acoustic velocities, formation resisitivity factor, internal surface, and hydraulic permeability) were determined on a selected subgroup of representative samples to derive correlations with the densely measured parameters, establishing estimated depth logs to provide calibration values for the interpretation of geophysical data. Significant short‐ and long‐scale variations of porosity (1–37%) turned out to be the dominant factor influencing thermal, acoustic, and hydraulic properties of this post impact limestone formation. Correspondingly, large variations of thermal conductivity, thermal diffusivity, acoustic velocities, and hydraulic permeability were found. These variations of physical properties allow us to subdivide the formation into several zones. A combination of experimental data on thermal conductivity for dry and water‐saturated rocks and a theoretical model of effective thermal conductivity for heterogeneous media have been used to calculate thermal conductivity of mineral skeleton and pore aspect ratio for every core under study. The results on thermal parameters are the necessary basis for the determination of heat flow density, demonstrating the necessity of dense sampling in the case of inhomogeneous rock formations.
Magnetostratigraphy of the impact breccias and post‐impact carbonates from borehole Yaxcopoil‐1, Chicxulub impact crater, Yucatán, Mexico
Authors: Rebolledo‐Vieyra Mario , Urrutia‐Fucugauchi Jaime
Published: January 2010

Abstract— We report the magnetostratigraphy of the sedimentary sequence between the impact breccias and the post‐impact carbonate sequence conducted on samples recovered by Yaxcopoil‐1 (Yax‐1). Samples of impact breccias show reverse polarities that span up to ∼56 cm into the post‐impact carbonate lithologies. We correlate these breccias to those of PEMEX boreholes Yucatán‐6 and Chicxulub‐1, from which we tied our magnetostratigraphy to the radiometric age from a melt sample from the Yucatán‐6 borehole. Thin section analyses of the carbonate samples showed a significant amount of dark minerals and glass shards that we identified as the magnetic carriers; therefore, we propose that the mechanism of magnetic acquisition within the carbonate rocks for the interval studied is detrital remanent magnetism (DRM). With these samples, we constructed the scale of geomagnetic polarities where we find two polarities within the sequence, a reverse polarity event within the impact breccias and the base of the post‐impact carbonate sequence (up to 794.07 m), and a normal polarity event in the last ∼20 cm of the interval studied. The polarities recorded in the sequence analyzed are interpreted to span from chron 29r to 29n, and we propose that the reverse polarity event lies within the 29r chron. The magnetostratigraphy of the sequence studied shows that the horizon at 794.11 m deep, interpreted as the K/T boundary, lies within the geomagnetic chron 29r, which contains the K/T boundary.
Paleomagnetic and rock magnetic study of the Yaxcopoil‐1 impact breccia sequence, Chicxulub impact crater (Mexico)
Authors: Urrutia‐Fucugauchi J. , Soler‐Arechalde A. M. , Rebolledo‐Vieyra M. , Vera‐Sanchez P.
Published: January 2010

Abstract— Results of a detailed paleomagnetic and rock magnetic study of samples of the impact breccia sequence cored in the Yaxcopoil‐1 (Yax‐1) borehole between about 800 m and 896 m are presented. The Yax‐1 breccia sequence occurs from 794.63 m to 894.94 m and consists of redeposited melt‐rich, clast‐size sorted, fine‐grained suevites; melt‐rich, no clast‐size sorting, medium‐grained suevites; coarse suevitic melt agglomerates; coarse melt‐rich heterogeneous suevites; brecciated suevites; and coarse carbonate and silicate melt suevites. The low‐field susceptibility ranges from −0.3 to 4018 times 10−6 SI, and the NRM intensity ranges from 0.02 mA/m up to 37510 mA/m. In general, the NRM intensity and magnetic susceptibility present wide ranges and are positively correlated, pointing to varying magnetic mineral contents and textures of the melt‐rich breccia sequence. The vectorial composition and magnetic stability of NRM were investigated by both stepwise alternating field and thermal demagnetization. In most cases, characteristic single component magnetizations are observed. Both upward and downward inclinations are present through the sequence, and we interpret the reverse magnetization as the primary component in the breccias. Both the clasts and matrix forming the breccia appear to have been subjected to a wide range of temperature/pressure conditions and show distinct rock magnetic properties. An extended interval of remanence acquisition and secondary partial or total remagnetization may explain the paleomagnetic results.
Impactites of the Yaxcopoil‐1 drilling site, Chicxulub impact structure: Petrography, geochemistry, and depositional environment
Authors: Dressler Burkhard O. , Sharpton Virgil L. , Schwandt Craig S. , Ames Doreen
Published: January 2010

Abstract— The impact breccias encountered in drill hole Yaxcopoil‐1 (Yax‐1) in the Chicxulub impact structure have been subdivided into six units. The two uppermost units are redeposited suevite and suevite, and together are only 28 m thick. The two units below are interpreted as a ground surge deposit similar to a pyroclastic flow in a volcanic regime with a fine‐grained top (unit 3; 23 m thick; nuée ardente) and a coarse breccia (unit 4; ∼15 m thick) below. As such, they consist of a mélange of clastic matrix breccia and melt breccia. The pyroclastic ground surge deposit and the two units 5 and 6 below are related to the ejecta curtain. Unit 5 (∼24 m thick) is a silicate impact melt breccia, whereas unit 6 (10 m thick) is largely a carbonate melt breccia with some clastic‐matrix components. Unit 5 and 6 reflect an overturning of the target stratigraphy. The suevites of units 1 and 2 were deposited after emplacement of the ejecta curtain debris. Reaction of the super‐heated breccias with seawater led to explosive activity similar to phreomagmatic steam explosion in volcanic regimes. This activity caused further brecciation of melt and melt fragments. The fallback suevite deposit of units 1 and 2 is much thinner than suevite deposits at larger distances from the center of the impact structure than the 60 km of the Yax‐1 drill site. This is evidence that the fallback suevite deposit (units 1 and 2) originally was much thicker. Unit 1 exhibits sedimentological features suggestive of suevite redeposition. Erosion possibly has occurred right after the K/T impact due to seawater backsurge, but erosion processes spanning thousands of years may also have been active. Therefore, the top of the 100 m thick impactite sequence at Yaxcopoil, in our opinion, is not the K/T boundary.
Evidence for ocean water invasion into the Chicxulub crater at the Cretaceous/Tertiary boundary
Authors: Goto Kazuhisa , Tada Ryuji , Tajika Eiichi , Bralower Timothy J. , Hasegawa Takashi , Matsui Takafumi
Published: January 2010

Abstract— The possibility of ocean water invasion into the Chicxulub crater following the impact at the Cretaceous/Tertiary boundary was investigated based on examination of an impactite between approximately 794.63 and 894.94 m in the Yaxcopoil‐1 (Yax‐1) core. The presence of cross lamination in the uppermost part of the impactite suggests the influence of an ocean current at least during the sedimentation of this interval. Abundant occurrence of nannofossils of late Campanian to early Maastrichtian age in the matrices of samples from the upper part of the impactite suggests that the carbonate sediments deposited on the inner rim margin and outside the crater were eroded and transported into the crater most likely by ocean water that invaded the crater after its formation. The maximum grain size of limestone lithics and vesicular melt fragments, and grain and bulk chemical compositions show a cyclic variation in the upper part of the impactite. The upward fining grain size and the absence of erosional contact at the base of each cycle suggest that the sediments were derived from resuspension of units elsewhere in the crater, most likely by high energy currents association with ocean water invasion.
The activity of chromite in multicomponent spinels: Implications for T‐fO2 conditions of equilibrated H chondrites
Authors: Kessel Ronit , Beckett John R. , Huss Gary R. , Stolper Edward M.
Published: January 2010

Abstract— Activities of chromite in multicomponent spinels with compositions similar to those of H chondrites were experimentally determined by equilibrating Pt‐alloys with spinel at known temperature and fO2. Our results are consistent with predictions based on the spinel solid solution model incorporated into the MELTS program. Therefore, we combined literature formulations for the activities of components in spinel, the ferromagnesian silicates, and alloys with measured and literature (bulk alloy) compositions of the meteoritic phases to constrain T‐fO2 conditions for the H‐group chondrites Avanhandava (H4), Allegan (H5), and Guareña (H6).

Log10fO2 values based on the assemblage of olivine + orthopyroxene + metal are 2.19–2.56 log units below the iron‐wüstite (IW) buffer for any equilibration temperature between 740 and 990 °C, regardless of petrographic type. Only lower limits on fO2 could be determined from spinel + metal equilibria because of the extremely low concentrations of Cr in the alloys of equilibrated H chondrites (≤3 ppb). Log10fO2 values required by spinel + metal equilibria are inconsistent with those for olivine + orthopyroxene + metal if equilibration temperatures were at or above those inferred from olivine‐spinel thermometry. This probably indicates that the closure for spinel + metal equilibria occurred under retrograde conditions at temperatures below ∼625 °C for Allegan and Guareña and below ∼660 °C for Avanhandava.
Thuathe, a new H4/5 chondrite from Lesotho: History of the fall, petrography, and geochemistry
Authors: Reimold W. U. , Buchanan P. C. , Ambrose D. , Koeberl C. , Franchi I. , Lalkhan C. , Schultz L. , Franke L. , Heusser G.
Published: January 2010

Abstract— On July 21, 2002, a meteorite fall occurred over the Thuathe plateau of western Lesotho. The well‐defined strewn field covers an area of 1.9 times 7.4 km. Many of the recovered specimens display a brecciated texture with leucocratic, angular to subrounded clasts in a somewhat darker groundmass. Mineralogical and chemical data, as well as oxygen isotopic analysis, indicate that Thuathe is an H4/5, S2/3 meteorite, with local H3 or H6 character. A number of anomalous features include somewhat high Co contents of kamacite and taenite relative to normal H‐group chondrites. Oxygen isotopic data plot at the edge of the normal H chondrite data field. Variable contents of metallic mineral phases and troilite result in a heterogeneous bulk composition (e.g., with regard to Si, Fe, and Mg), resulting in a spread of major element ratios that is not consistent with previously accepted H‐group composition. Trace element abundances are generally consistent with H chondritic composition, and Kr and Xe isotopic data agree with an H4 classification for this meteorite. Noble gas analysis gave U, Th‐4He gas retention and K‐Ar ages typical for H chondrites; no major thermal event affected this material since ∼3.7 Ga. The exposure age for Thuathe is 5 Ma, somewhat lower than for other H chondrites. Cosmogenic nuclide analysis indicates a pre‐atmospheric radius of this meteorite between 35 and 40 cm. In the absence of evidence for solar gases, we classify Thuathe as a fragmental breccia.

Numerous narrow, black veins cut across samples of Thuathe and are the result of a brittle deformation event that also caused local melting, especially in portions rich in sulfide. The formation of these veinlets is not the result of locally enhanced shock pressures (i.e., of shock melting) but rather of shearing under brittle conditions with local, friction‐related temperature excursions causing melting mostly of Fe‐sulfide and FeNi‐metal but also, locally, of silicate minerals. Frictional temperature excursions must have attained values in excess of 1500 °C to permit complete melting of forsteritic olivine.
Sodium‐metasomatism in chondrules in CO3 chondrites: Relationship to parent body thermal metamorphism
Authors: Tomeoka Kazushige , Itoh Daisuke
Published: January 2010

Abstract— We have studied the mineralogy and petrology of mesostases of 783 type I chondrules in seven CO3 chondrites that range in petrologic subtype from 3.0 to 3.7. Chondrule mesostases in the CO chondrite of subtype 3.0 consist mainly of primary glass and plagioclase, while chondrule mesostases in the CO chondrites of higher subtypes (3.2–3.7) contain various amounts of nepheline in addition to glass and plagioclase. Nepheline has replaced glass and plagioclase, forming finegrained aggregates and thin parallel lamellar intergrowths with plagioclase. The nephelinization has proceeded preferentially from the outer margins of chondrules toward the inside. Although the degree of nephelinization differs widely among chondrules in each of the metamorphosed chondrites, our modal analyses and bulk chemical analyses of individual mesostases indicate that the amounts of nepheline in chondrules systematically increase with the increasing petrologic subtype of the host chondrites. Nepheline also has a tendency to increase in grain size with increasing petrologic subtype. We conclude that nepheline in chondrules in the CO3 chondrites has formed largely as a result of effects related to heating on the meteorite parent body. We suggest that nepheline initially formed as hydrous nepheline under the presence of aqueous fluids and subsequently was dehydrated after exhaustion of aqueous fluids. The degree of hydrothermal activity must have increased with increasing degree of heating, and thus, chondrules in more thermally metamorphosed chondrites produced larger amounts of nepheline. The results imply that CO3 chondrites have gone through low‐grade aqueous alteration and subsequent dehydration at the early stage of heating on the meteorite parent body.
I‐Xe measurements of CAIs and chondrules from the CV3 chondrites Mokoia and Vigarano
Authors: Whitby J. A. , Russell S. S. , Turner G. , Gilmour J. D.
Published: January 2010

Abstract— I‐Xe analyses were carried out for chondrules and refractory inclusions from the two CV3 carbonaceous chondrites Mokoia and Vigarano (representing the oxidized and reduced subgroups, respectively). Although some degree of disturbance to the I‐Xe system is evident in all of the samples, evidence is preserved of aqueous alteration of CAIs in Mokoia 1 Myr later than the I‐Xe age of the Shallowater standard and of the alteration of a chondrule (V3) from Vigarano ∼0.7 Myr later than Shallowater. Other chondrules in Mokoia and Vigarano experienced disturbance of the I‐Xe system millions of years later and, in the case of one Vigarano chondrule (VS1), complete resetting of the I‐Xe system after decay of essentially all 129I, corresponding to an age more than 80 Myr after Shallowater. Our interpretation is that accretion and processing to form the Mokoia and Vigarano parent bodies must have continued for at least 4 Myr and 80 Myr, respectively. The late age of a chondrule that shows no evidence for any aqueous alteration or significant thermal processing after its formation leads us to postulate the existence of an energetic chondrule‐forming mechanism at a time when nebular processes are not expected to be important.