An Investigation of the Batch Adsorption Capacity for the Removal of Phosphate from Wastewater Using Both Unmodified and Functional Nanoparticle-Modified Biochars
Authors: Vaiškūnaitė Rasa 
Published: November 2024

One of the most widely employed methods for adsorption is the utilization of biochar produced during pyrolysis. Biochar has attracted considerable attention due to its oxygen-containing functional groups and relatively high specific surface area. In alignment with the principles of cleaner production, the sludge generated from sewage treatment plants is typically classified as waste. However, it can be effectively repurposed as an adsorbent following pyrolysis and subsequent nanoparticle modification. This environmentally friendly approach presents an ecological alternative to conventional water treatment methods. The objective of this study is to evaluate the efficiency of batch adsorption for the removal of phosphate from wastewater using both unmodified and modified sewage sludge biochars (SSBs) that were produced at various temperatures (300 °C, 400 °C, 500 °C, and 600 °C) and modified with zero-valent iron nanoparticles (nZVI-SSB300, nZVI-SSB400, nZVI-SSB500, and nZVI-SSB600). The findings indicate that biochar modified with functional nanoparticles is a highly effective adsorbent for the removal of phosphate from wastewater. As demonstrated by the research results, the adsorption capacity of modified biochar is approximately 3 to 3.5 times greater than that of the unmodified variants. The phosphate removal efficiency with modified biochars was optimal with nZVI-SSB600. In experiments with a phosphate concentration (25 mg/L), the modified sorbent biochar exhibited an equilibrium adsorption capacity of 23.74 mg/g, translating to a phosphate removal efficiency of 60%. Under similar test conditions, at an initial phosphate concentration of 50 mg/L, the adsorption capacity improved to 25.67 mg/g (75% efficiency); at 75 mg/L, it reached 27.97 mg/g (80%); at 100 mg/L, it was 28.44 mg/g (85%); and at 125 mg/L, it achieved 29.48 mg/g (89%). The models confirmed the observed adsorption behavior, yielding a maximum phosphate adsorption capacity (qe) of 19.00 mg/g for the 600 °C pyrolysis of modified biochar at the primary phosphate concentration (25 mg/L). Furthermore, this study indicates that the influence of solution pH on phosphate adsorption remains stable and maximal (nZVI-SSB600, ranging from 16.87 to 20.46 mg/g) within the pH range of 3 to 8. On average, the modified biochar (nZVI-SSB) demonstrated 20 to 30% superior adsorption performance compared to the unmodified biochar (SSB). Additionally, significant differences were noted between various ambient temperatures, ranging from 5 °C to 25 °C. As the ambient temperature increased, the sorption capacity of the adsorbent exhibited a considerable improvement. With a primary concentration of phosphate (100 mg/g) at 5 °C, the adsorption capacity of nZVI-SSB600 was measured at 7.99 mg/g; this increased to 14.33 mg/g at 10 °C, 21.79 mg/g at 20 °C, and 28.44 mg/g at 25 °C. This research highlights the potential application of biochar in wastewater treatment for phosphate removal, simultaneously enabling the effective utilization of generated sewage sludge waste through pyrolysis and coating with zero-iron nanoparticles, resulting in a sustainable solution.