RESEARCH OF HEAT RESISTANCE OF CARBON-CARBON COMPOSITE MATERIALS WITH PROTECTIVE COATINGS OBTAINED USING FUNCTIONALLY ACTIVE CHARGES
Authors: Sereda Dmytro 
Published: July 2024

This study focuses on the development of protective coatings for carbon-carbon composite materials (CCСM) used in high-temperature processes in aerospace engineering. CСCM have limitations due to their susceptibility to oxidation, erosion, and burnout in gas streams. Our research is aimed at creating protective coatings using functionally active charges (FAC) obtained under non-stationary temperature conditions and improving the performance of composites. The aim of our study is to identify the optimal compositions of powders for chromium-alloyed protective coatings using functionally active charges to increase the heat resistance of the working surface. We analyzed various methods of obtaining protective coatings, including chemical-thermal and liquid-phase saturation methods, to find out their peculiarities in interaction with the CCСM matrix and changes in their mechanical properties. In addition to the traditional methods, we have investigated the method of saturating the surface with a solid phase in an active gas environment using FAС, which are obtained under non-stationary temperature conditions. This method provides high quality coatings, reduces processing time and makes it possible to work at high temperatures depending on the composition of the spray coatings. Much attention was paid to the problem associated with chemical interaction and formation of carbide phases, which are important for ensuring the stability of coatings under high temperature conditions. Experimental studies include a factorial experiment to determine the compositions of powder mixtures that provide high heat resistance. Various independent variables, such as the content of chromium, silicon, titanium, and aluminum, were considered, taking into account their influence on the physical and mechanical properties of coatings. Particular attention was paid to the optimization of the parameters of thermal autoinitiation of the functionally active charge under process conditions. Regression equations are presented to evaluate the dependence of the wear resistance of coatings on the autoinitiation parameters and the content of alloying elements. The analysis of the study results includes the construction of three-dimensional graphical dependencies for optimizing the composition of powdered CBA in the Cr-Al-Ti and Cr-Al-Si systems. In practice, chromium-aluminum-siliconized coatings obtained under isothermal conditions, when tested for heat resistance, have a more porous surface through which oxygen penetrates to the surface of the HCCM. Compared to the coatings obtained using FAS, the heat resistance is 1.5-1.7 times higher, which can be explained by the higher concentration of chromium, aluminum, silicon, and titanium, which contribute to the formation of protective oxide membraness. The low-porosity surface of the coatings obtained using functionally active layers prevents oxygen from entering the material, contributing to the formation of oxide protective membranes such as SiO2, TiO2, Cr2O3, Al2O3.