bluuebunny/crossref_metadata_2025 huggingface dataset:
Anoxic sediments off Central Peru record interannual to multidecadal changes of climate and upwelling ecosystem during the last two centuries
Authors: Gutiérrez D. , Sifeddine A. , Reyss J. L. , Vargas G. , Velazco F. , Salvatteci R. , Ferreira V. , Ortlieb L. , Field D. , Baumgartner T. , Boussafir M. , Boucher H. , Valdés J. , Marinovic L. , Soler P. , Tapia P.
Published: April 2010

Abstract. High-resolution paleo-environmental and paleo-ecological archives in laminated sequences are present in selected areas from the upper continental Peruvian margin within the oxygen minimum zone. We present initial results of a multidisciplinary study (the PALEOPECES project) that aims to reconstruct environmental and ecosystem variability during the past 200 years from high-resolution records. We report chronology development, sediment structure, elemental, organic, and mineralogical compositions of a box core collected at 300 m depth off Pisco, central Peru. An average sedimentation rate of 2.2 mm y-1 was estimated from downcore excess 210Pb activities for the last 100-150 years. Extending this rate further downcore indicates that a slump located at 52 cm depth from the top of the core can be correlated with a large tsunami that struck the coast of central Peru in 1746. X-ray analyses reveal laminated structures composed of couplets of light and dark laminae. Observations under polarized microscope show that light laminae are dominated by more dense, detrital and terrigenous material, while dark laminae are less dense with greater concentrations of amorphous biogenic silica. Downcore variations in dry bulk density and X-ray radioscopy of gray level show similar patterns, including a major shift at 34 cm depth (ca. mid-nineteenth century). A finely laminated sequence, which may include annual varves, is present between 34 cm depth and the slump layer. Sediment characteristics of the sequence suggest increased seasonality of terrigenous versus biogenous sedimentation during the corresponding period. In addition to a mid-nineteenth century change and considerable multidecadal variability in TOC, there is a positive trend in the past 50 years. Mineralogical analyses from a Fourier Transformed Infrared Spectroscopy (FTIR) of the upper core covering the last 25 years, indicate higher concentrations of the mineral fraction (quartz, feldspar, kaolinite and illite) in layers including large El Niño events (1982-1983, 1986-1987 and 1997-1998), with the largest peak during the 1997-1998 episode. These results confirm that anoxic sediments off Pisco are suitable archives to investigate interannual and decadal changes in oceanographic conditions and climate of the northern Humboldt upwelling system.
Review of: El Niño influence over South America during the mid-holocene
Authors: Jorgetti T. , Silva Dias P. L. , Braconnot P.
Published: April 2010

Abstract. This work reports on the relationship between the Pacific Ocean sea surface temperature variability and precipitation over South America in the IPSL coupled model simulations of the present and the 6 kyr Before Present (Mid-Holocene) climate. The model results suggests that the control exerted by ENSO on precipitation in South America was less frequent in the Mid-Holocene compared to the present climate and that the spatial distribution of the ENSO influence is considerably different in the two periods.
Heavy rainfall episodes in Ecuador during El Niño events and associated regional atmospheric circulation and SST patterns
Authors: Bendix A. , Bendix J.
Published: April 2010

Abstract. To date very little is known about the relation between regional circulation patterns and sea surface temperature development in the Niño 1,2 region and the occurrence of heavy precipitation in Ecuador and northern Peru. The current study uses a comprehensive data set of 2544 Meteosat-3 imagery to investigate the dynamics of heavy precipitation during El Niño in 1991/92. Rainfall maps are retrieved by means of an adjusted version of the Convective Stratiform Technique (CST) and Cloud Motion Winds (CMW) are extracted from image sequences by using a special cross-correlation approach. A spatial factor analysis is applied to extract specific weather situations with heavy precipitation during El Niño events. The factor analysis yielded 16 factors. It has been proven that the factor patterns with the highest variance explanation also occur during the rainy season of non-El Niño years. However, 6 El Niño-specific situations could be derived which cause heavy rainfall, especially in coastal Ecuador and northern Peru. Multi-channel Sea Surface Temperatures (MCSST) and cloud motion winds are used to describe atmospheric and oceanic dynamics for these specific weather situations. The analysis shows that high SSTs in combination with strong SST gradients off the coast and warm SST bubbles lead to regional differences in moist instability and heavy rainfall. Both large scale circulation (reversal of the Walker cell) and regional dynamics (extended land-sea-breeze system) have been proven to contribute to El Niño rainfall.
ENSO and sandy beach macrobenthos of the tropical East Pacific: some speculations
Authors: Vanagt T. , Beekman E. , Vincx M. , Degraer S.
Published: April 2010

Abstract. The influence of the ENSO cycle on marine fauna and flora has only recently been given the attention it deserves. The very strong 1997–1998 El Niño and its obvious effects on marine biota was a key point in ENSO research, but unfortunately few quantitative data about the 1997–1998 El Niño itself are available. To gather information about the effect of ENSO on the macrobenthos, we performed a bi-weekly transect monitoring on an Ecuadorian sandy beach in 2000–2001, during the strong La Niña following the 1997–1998 El Niño, and in the normal period of 2002–2004. In this paper, intertidal macrofaunal densities at higher taxonomic level are used to compare a La Niña phase with the 'normal' situation. The few existing documents about El Niño and sandy beach macrobenthos, and scattered data from previous and current research, were used to complete the picture. Total macrobenthos densities were 300% lower during the La Niña phase compared with equal months in the normal phase. Especially Crustacea and Mollusca showed a marked increase in densities towards the normal situation (94% and 341% respectively). Polychaeta and Echinodermata, however, showed higher densities during the La Niña phase (22% and 73% respectively). Two possible explanations are proposed. (1) Low densities during the La Niña could be due to the very strong preceding El Niño, suggesting the populations were still recovering. This hypothesis is supported by previous work done in the south of Peru. This is, however, a cold water system, compared to the Ecuadorian warm water system. (2) The second hypothesis states that a La Niña will have a very severe impact on the intertidal macrofauna of a warm water system like the Ecuadorian coast.
Opposing oceanic and atmospheric ENSO influences on the Ross Sea Region, Antarctica
Authors: Bertler N. A. N. , Naish T. R. , Mayewski P. A. , Barrett P. J.
Published: April 2010

Abstract. Here we discuss the cause and effect of opposing atmospheric and oceanic ENSO forcings in the Ross Sea, that lead to a net warming in the eastern Ross Sea and a net cooling in the western Ross Sea during El Niño years. During La Niña years the opposite is observed. The oceanic ENSO effect causes a ~1 K warming with a 3 month lag during El Niño years in comparison to La Niña time periods. During El Niño events, the atmospheric ENSO effect leads to a shift and weakening of the Amundsen Sea Low, causing enhanced import of colder West Antarctic air masses into the western Ross Sea. We find that this indirect ENSO effect is about one order of magnitude stronger (up to 15 K) in the western Ross Sea than the direct effect (~1 K), leading to a net cooling during El Niño and net warming during La Niña events.
Evaluation of atmospheric instability indices in Greece
Authors: Marinaki A. , Spiliotopoulos M. , Michalopoulou H.
Published: April 2010

Abstract. The potential of instability indices in assessing atmospheric instability is examined for the areas of Attica, Thessaly and Central Aegean and Crete, Greece. Generally, many indices have been developed to estimate the troposphere's stability for forecasting purposes. At this study several instability indices, commonly used in Meteorology, are computed based on radiosonde data. Firstly, the indices are computed for several months based on the 00:00 and 12:00 UTC radiosonde data during the period 1981–2003. Statistical methods were used to compare and test the effectiveness of these indices in the described area using meteorological data from seventeen meteorological stations of Greece. Thus, the potential of monitoring the atmospheric instability conditions is examined. The next stage of this study is an effort to test the thresholds of the existing indices in order to improve the results of these indices. It seems that this effort can make a good simulation to the assessment of instability, contributing to local level weather forecasting.
A mesoscale convective system trapped along the Spanish Mediterranean Coast
Authors: Sánchez-Laulhé J. M.
Published: April 2010

Abstract. This paper describes the evolution of a mesoscale convective system (MCS) developed over the Alboran Sea on 7 February 2005, using surface, upper-air stations, radar and satellite observations, and also data from an operational numerical model. The system developed during the night as a small convective storm line in an environment with slight convective instability, low precipitable water and strong low-level vertical wind shear near coast. The linear MCS moved northwards reaching the Spanish coast. Then it remained trapped along the coast for more than twelve hours, following the coast more than five hundred kilometres. The MCS here described had a fundamental orographic character due to: (1) the generation of a low-level storm inflow parallel to the coast, formed by blocking of the onshore flow by coastal mountains and (2) the orientation of both the mesoscale ascent from the sea towards the coastal mountains and the midlevel rear inflow from the coastal mountains to the sea. The main motivation of this work was to obtain a better understanding of the mechanisms relevant to the formation of heavy rainfall episodes occurring at Spanish Mediterranean coast associated with this kind of stationary or slowly moving MCSs.
Intense storms in the Mediterranean: a first description from the ERA-40 perspective
Authors: Genovés A. , Campins J. , Jansà A.
Published: April 2010

Abstract. The study of the Mediterranean cyclones from a climatological point of view has been one of the objectives of the first phase of WMO WWRP MEDEX (MEDiterranean EXperiment) project. It has been revealing itself like a good procedure for extracting conclusions about their characteristics and behaviour. The implementation on ECMWF ERA-40 reanalysis of the method for detecting and tracking the cyclones developed at the Centro Meteorológico Territorial (CMT) in Illes Balears of the Instituto Nacional de Meteorología (INM, Spain) has allowed the selection of the most intense storms occurred for the last 45 years. This selection has been based on the value of the cyclones' circulation. The areas of maximum intensification for those cyclones have been obtained and the existence of preferential zones of intensification has been verified. Finally a first sight of those cases has allowed to initiate the check up of the ability of the ERA-40 re-analyses for reproducing these intense Mediterranean storms.
Study of 11 September 2004 hailstorm event using radar identification of 2-D systems and 3-D cells
Authors: Ceperuelo M. , Llasat M. C. , López L. , García-Ortega E. , Sánchez J. L.
Published: April 2010

Abstract. The most important hail event recorded in the region of the Ebro Valley (NE Spain) in 2004 was the 11 September episode. Large hailstones (some of them with a diameter of over 30 mm) caused important damages in agriculture and properties. The hail event affected an area of 3848 ha and was caused by several multicellular systems. The aim of this paper is the analysis of the associated convective structures using the meteorological radar as well as the MM5 mesoscale model, thermodynamic data and a hailpad network. To achieve this end, the new hailstorm analysis tool RHAP (Rainfall events and Hailstorms Analysis Program) has been applied. It identifies tracks and characterises precipitation systems and convective cells, taking into account 2-D and 3-D structures. The event has also been studied with the TITAN software (Thunderstorm Identification, Tracking, Analysis and Nowcasting) in an attempt to compare both methods. Results show that the episode had a strong convective activity with CAPE values over 4000 J/kg and with hail-forming cells characterised by VIL (Vertical Integrated Liguid) exceeding 40 kg/m2, VILD (VIL density) over 4 g/m3, HP (Hail Probability) of 100% and SHP (Severe Hail Probability) of over 75%. The hail cells evolved into multicellular systems that lasted between 70 and 90 min. Finally, the comparison of RHAP and TITAN has shown significant correlations between methods.
Mediterranean cloud system variability inferred from satellite observations
Authors: Chaboureau J.-P. , Claud C.
Published: April 2010

Abstract. The variability of Mediterranean cloud systems is investigated using 8.5 years (from January 1987 to June 1995) of TIROS-N Operational Vertical Sounder (TOVS) observations acquired aboard the National Oceanic and Atmospheric Administration (NOAA) series of operational polar satellites. Cloud systems and troughs are detected using retrievals of cloud top pressure (CTP) and temperature of the lower stratosphere (TLS). Cloud systems have a typical size of a few hundred kilometres with a larger occurrence between March and October. The largest cloud systems occur preferentially in May and October and downstream of a midlatitude upper level trough. Finally, severe precipitation events over the Alpine region are associated to a warm TLS anomaly upstream the cloud system, showing once more the impact of the upper levels on the weather over the area.
Towards a climatology of sensitivities of Mediterranean high impact weather − first approach
Authors: Homar V. , Jansà A. , Campins J. , Ramis C.
Published: April 2010

Abstract. During recent years, great interest has grown within the operational weather community on the adaptable component of observational networks. Decisions regarding where to deploy new observations of special value under threatening weather, or regarding permanent changes in observational strategies need support from sensitivity studies that determine areas where the addition of observations would optimally improve the skill of numerical predictions. Within the context of the MEDEX project (http://medex.inm.uib.es), the sensitivities of a collection of severe weather episodes in the Mediterranean have been computed using the MM5 Adjoint Modeling system. Various approaches are explored trying to summarize the results for the diversity of cases that produce high impact weather (HIW; mainly heavy rain and strong winds) in the Mediterranean region. A first attempt uses an objective classification of the trajectories of the most intense cyclone types from the ERA-40 reanalyses. Sensitivities are then computed for each group of frequent trajectories, providing a prototype sensitivity field for each of the most frequent intense cyclones in the Mediterranean. However, a large portion of HIW episodes in the Mediterranean are not linked to significantly intense cyclones within the climatology. Consequently, a subjective classification of HIW events is also performed and the sensitivity fields for an example case is shown to complete the study. Although the sensitive areas for Mediterranean HIW are not particularly confined, it is remarkable how poorly sampled areas by the regular observing networks such as North Africa and the eastern North-Atlantic are highlighted in the results.
The effect of sub-grid rainfall variability on the water balance and flux exchange processes resolved at climate scale: the European region contrasted to Central Africa and Amazon rainforests
Authors: Wang D. , Anagnostou E. N. , Wang G.
Published: April 2010

Abstract. This paper investigates the effect of sub-grid rainfall variability on the simulation of land surface hydrologic processes of three regions (Europe, Africa and Amazon) with contrasting precipitation and vegetation characteristics. The sub-grid rainfall variability is defined in terms of the rainfall coverage fraction at the model's grid cells, and the statistical distribution of rain rates within the rain-covered areas. A statistical-dynamic approach is devised to incorporate the above variability properties into the canopy interception process of a land surface model. Our results reveal that incorporation of sub-grid rainfall variability significantly impacts the land-atmosphere water vapor exchanges. Specifically, it alters the partitioning between runoff and total evapotranspiration as well as the partitioning among the three components of evapotranspiration (canopy interception loss, ground evaporation and plant transpiration). This further influences the soil water, and to a lesser effect surface/vegetation temperatures and surface heat fluxes. It is shown that, overall, rainfall variability exerts less of an impact on the land-atmosphere flux exchanges over Europe compared to Africa and Amazon.
EnKF assimilation of simulated spaceborne Doppler observations of vertical velocity: impact on the simulation of a supercell thunderstorm and implications for model-based retrievals
Authors: Lewis W. E. , Tripoli G. J.
Published: April 2010

Abstract. Recently, a number of investigations have been made that point to the robust effectiveness of the Ensemble Kalman Filter (EnKF) in convective-scale data assimilation. These studies have focused on the assimilation of ground-based Doppler radar observations (i.e. radial velocity and reflectivity). The present study differs from these investigations in two important ways. First, in anticipation of future satellite technology, the impact of assimilating spaceborne Doppler-retrieved vertical velocity is examined; second, the potential for the EnKF to provide an alternative to instrument-based microphysical retrievals is investigated. It is shown that the RMS errors of the analyzed fields produced by assimilation of vertical velocity alone are in general better than those obtained in previous studies: in most cases assimilation of vertical velocity alone leads to analyses with small errors (e.g. <1 ms-1 for velocity components) after only 3 or 4 assimilation cycles. The microphysical fields are notable exceptions, exhibiting lower errors when observations of reflectivity are assimilated together with observations of vertical velocity, likely a result of the closer relationship between reflectivity and the microphysical fields themselves. It is also shown that the spatial distribution of the error estimates improves (i.e. approaches the true errors) as more assimilation cycles are carried out, which could be a significant advantage of EnKF model-based retrievals.
Cyclones in the Mediterranean region: present and future climate scenarios derived from a general circulation model (HadAM3P)
Authors: Anagnostopoulou Chr. , Tolika K. , Flocas H. , Maheras P.
Published: April 2010

Abstract. In this paper, an attempt is made to assess and evaluate the skill of the Hadley Center atmospheric General Circulation Model (HadAM3P) in generating successfully the frequency and intensity of severe cyclones (<1000 hPa) in the Mediterranean region. The cyclonic occurrence is studied in three regions of enhanced cyclonic activity: Gulf of Genoa, Southern Italy and Cyprus. It was found that the HadAM3P predicts a future decrease of the frequency of the severe cyclones at the SLP level, but the future cyclones will be more intense (deeper), especially at the 500 hPa level.
Data access and analysis with distributed federated data servers in climateprediction.net
Authors: Massey N. , Aina T. , Allen M. , Christensen C. , Frame D. , Goodman D. , Kettleborough J. , Martin A. , Pascoe S. , Stainforth D.
Published: April 2010

Abstract. climateprediction.net is a large public resource distributed scientific computing project. Members of the public download and run a full-scale climate model, donate their computing time to a large perturbed physics ensemble experiment to forecast the climate in the 21st century and submit their results back to the project. The amount of data generated is large, consisting of tens of thousands of individual runs each in the order of tens of megabytes. The overall dataset is, therefore, in the order of terabytes. Access and analysis of the data is further complicated by the reliance on donated, distributed, federated data servers. This paper will discuss the problems encountered when the data required for even a simple analysis is spread across several servers and how webservice technology can be used; how different user interfaces with varying levels of complexity and flexibility can be presented to the application scientists, how using existing web technologies such as HTTP, SOAP, XML, HTML and CGI can engender the reuse of code across interfaces; and how application scientists can be notified of their analysis' progress and results in an asynchronous architecture.
Applications of "Integrated Data Viewer'' (IDV) in the classroom
Authors: Nogueira R. , Cutrim E. M.
Published: April 2010

Abstract. Conventionally, weather products utilized in synoptic meteorology reduce phenomena occurring in four dimensions to a 2-dimensional form. This constitutes a road-block for non-atmospheric-science majors who need to take meteorology as a non-mathematical and complementary course to their major programs. This research examines the use of Integrated Data Viewer-IDV as a teaching tool, as it allows a 4-dimensional representation of weather products. IDV was tested in the teaching of synoptic meteorology, weather analysis, and weather map interpretation to non-science students in the laboratory sessions of an introductory meteorology class at Western Michigan University. Comparison of student exam scores according to the laboratory teaching techniques, i.e., traditional lab manual and IDV was performed for short- and long-term learning. Results of the statistical analysis show that the Fall 2004 students in the IDV-based lab session retained learning. However, in the Spring 2005 the exam scores did not reflect retention in learning when compared with IDV-based and MANUAL-based lab scores (short term learning, i.e., exam taken one week after the lab exercise). Testing the long-term learning, seven weeks between the two exams in the Spring 2005, show no statistically significant difference between IDV-based group scores and MANUAL-based group scores. However, the IDV group obtained exam score average slightly higher than the MANUAL group. Statistical testing of the principal hypothesis in this study, leads to the conclusion that the IDV-based method did not prove to be a better teaching tool than the traditional paper-based method. Future studies could potentially find significant differences in the effectiveness of both manual and IDV methods if the conditions had been more controlled. That is, students in the control group should not be exposed to the weather analysis using IDV during lecture.
Data integration with the Climate Science Modelling Language
Authors: Woolf A. , Lawrence B. , Lowry R. , Kleese van Dam K. , Cramer R. , Gutierrez M. , Kondapalli S. , Latham S. , Lowe D. , O'Neill K. , Stephens A.
Published: April 2010

Abstract. The Climate Science Modelling Language (CSML) has been developed by the NERC DataGrid (NDG) project as a standards-based data model and XML markup for describing and constructing climate science datasets. It uses conceptual models from emerging standards in GIS to define a number of feature types, and adopts schemas of the Geography Markup Language (GML) where possible for encoding. A prototype deployment of CSML is being trialled across the curated archives of the British Atmospheric and Oceanographic Data Centres. These data include a wide range of data types – both observational and model – and heterogeneous file-based storage systems. CSML provides a semantic abstraction layer for data files, and is exposed through higher level data delivery services. In NDG these will include file instantiation services (for formats of choice) and the web services of the Open Geospatial Consortium (OGC).
Flood routing modelling with Artificial Neural Networks
Authors: Peters R. , Schmitz G. , Cullmann J.
Published: April 2010

Abstract. For the modelling of the flood routing in the lower reaches of the Freiberger Mulde river and its tributaries the one-dimensional hydrodynamic modelling system HEC-RAS has been applied. Furthermore, this model was used to generate a database to train multilayer feedforward networks. To guarantee numerical stability for the hydrodynamic modelling of some 60 km of streamcourse an adequate resolution in space requires very small calculation time steps, which are some two orders of magnitude smaller than the input data resolution. This leads to quite high computation requirements seriously restricting the application – especially when dealing with real time operations such as online flood forecasting. In order to solve this problem we tested the application of Artificial Neural Networks (ANN). First studies show the ability of adequately trained multilayer feedforward networks (MLFN) to reproduce the model performance.
Calibration and uncertainty issues of a hydrological model (SWAT) applied to West Africa
Authors: Schuol J. , Abbaspour K. C.
Published: April 2010

Abstract. Distributed hydrological models like SWAT (Soil and Water Assessment Tool) are often highly over-parameterized, making parameter specification and parameter estimation inevitable steps in model calibration. Manual calibration is almost infeasible due to the complexity of large-scale models with many objectives. Therefore we used a multi-site semi-automated inverse modelling routine (SUFI-2) for calibration and uncertainty analysis. Nevertheless, the question of when a model is sufficiently calibrated remains open, and requires a project dependent definition. Due to the non-uniqueness of effective parameter sets, parameter calibration and prediction uncertainty of a model are intimately related. We address some calibration and uncertainty issues using SWAT to model a four million km2 area in West Africa, including mainly the basins of the river Niger, Volta and Senegal. This model is a case study in a larger project with the goal of quantifying the amount of global country-based available freshwater. Annual and monthly simulations with the "calibrated" model for West Africa show promising results in respect of the freshwater quantification but also point out the importance of evaluating the conceptual model uncertainty as well as the parameter uncertainty.
Radar rainfall estimates in an alpine environment using inverse hydrological modelling
Authors: Marx A. , Kunstmann H. , Bárdossy A. , Seltmann J.
Published: April 2010

Abstract. The quality of hydrological modelling is limited due to the restricted availability of high resolution temporal and spatial input data such as temperature, global radiation, and precipitation. Radar-based rain measurements provide good spatial information. On the other hand, using radar data is accompanied by basic difficulties such as clutter, shielding, variations of Z/R-relationships, beam-resolution and attenuation. Instead of accounting for all errors involved separately, a robust Z/R-relationship is estimated in this study for the short range (up to 40 km distance) using inverse hydrological modelling for a continuous period of three months in summer 2001. River gauge measurements from catchment sizes around 100 km2 are used to estimate areal precipitation and finally Z/R-relationships using a calibrated hydrological model. The study is performed in the alpine Ammer catchment with very short reaction times of the river gauges to rainfall events.
An interdisciplinary scenario analysis to assess the water availability and water consumption in the Upper Ouémé catchment in Benin
Authors: Giertz S. , Diekkrüger B. , Jaeger A. , Schopp M.
Published: April 2010

Abstract. This paper presents an interdisciplinary scenario analysis to assess the influence of global and regional change on future water availability and water consumption in the Upper Ouémé catchment in central Benin. For the region three development scenarios were evolved. These scenarios are combined with climate change scenarios based on the IPCC (Intergovernmental Panel on Climate Change). In the modelling approach the quantification of the land use/land cover change is performed by the cellular automata model CLUE-S. The future climate scenarios are computed with the regional climate model REMO driven by the global ECHAM model. Using this data different land use and climate change scenarios can be calculated with the conceptual hydrological model UHP-HRU to assess the effects of global changes on the future water availability in Benin. To analyse the future water availability also the water consumption has to be taken into account. Due to high population growth an increase in water need in the future is expected for the region. To calculate the future household water consumption data from a regional survey and demographic projections are used. Development of the water need for animal husbandry is also considered. The first test run of the modelling approach was performed for the development scenario 'business as usual' combined with the IPCC scenario B2 for the year 2025. This test demonstrates the applicability of the approach for an interdisciplinary scenario analysis. A continuous run from 2000–2025 will be simulated for different scenarios as soon as the input data concerning land use/land cover and climate are available.
Model based distributed water balance monitoring of the White Volta catchment in West Africa through coupled meteorological-hydrological simulations
Authors: Wagner S. , Kunstmann H. , Bárdossy A.
Published: April 2010

Abstract. Sustainable water management requires the quantification of the spatial and temporal changes of water balance variables. Fully distributed hydrological simulations of these variables are especially in regions with weak infrastructure challenging, because the required meteorological input data are often not available in a sufficient spatial and temporal resolution. One possibility to deal with this limitation is to provide the required input data with a meteorological model. This combination results in a one way meteorological-hydrological coupling system. Within the framework of the GLOWA-Volta project it is investigated to what extent meteorological models are able to provide the required meteorological fields with sufficient accuracy for the hydrological modeling. For this study the mesoscale meteorological model MM5 and the fully distributed water balance simulation model WaSiM-ETH were first adapted and validated separately. The research area is the White Volta catchment in the semi-arid to sub-humid climate zone in West Africa. The meteorological simulations tend toward overestimating measured precipitation sums. The coupled meteorological-hydrological runoff simulations show similar model performances as the simulations driven by observations indicating the potential of this system for a contemporary estimation of the terrestrial water balance.
Common problematic aspects of coupling hydrological models with groundwater flow models on the river catchment scale
Authors: Barthel R.
Published: April 2010

Abstract. Model coupling requires a thorough conceptualisation of the coupling strategy, including an exact definition of the individual model domains, the "transboundary" processes and the exchange parameters. It is shown here that in the case of coupling groundwater flow and hydrological models – in particular on the regional scale – it is very important to find a common definition and scale-appropriate process description of groundwater recharge and baseflow (or "groundwater runoff/discharge") in order to achieve a meaningful representation of the processes that link the unsaturated and saturated zones and the river network. As such, integration by means of coupling established disciplinary models is problematic given that in such models, processes are defined from a purpose-oriented, disciplinary perspective and are therefore not necessarily consistent with definitions of the same process in the model concepts of other disciplines. This article contains a general introduction to the requirements and challenges of model coupling in Integrated Water Resources Management including a definition of the most relevant technical terms, a short description of the commonly used approach of model coupling and finally a detailed consideration of the role of groundwater recharge and baseflow in coupling groundwater models with hydrological models. The conclusions summarize the most relevant problems rather than giving practical solutions. This paper aims to point out that working on a large scale in an integrated context requires rethinking traditional disciplinary workflows and encouraging communication between the different disciplines involved. It is worth noting that the aspects discussed here are mainly viewed from a groundwater perspective, which reflects the author's background.
Modelling the runoff response in the Mulde catchment (Germany)
Authors: Fleischbein K. , Lindenschmidt K.-E. , Merz B.
Published: April 2010

Abstract. The paper presents two different levels of regionalization used to represent the spatial distribution of landscape parameters for the hydrological modelling of the Mulde. The aim of this investigation was to find out how the discretisation level affects quality of modelling with the hydrological modelling system J2000. Furthermore we improved our understanding of the applicability and reliability of the distributed model J2000 on the macro-scale. Spatial information was aggregated in two different discretisation levels: subbasins (SB) and hydrological response polygons (HRP). A J2000 simulation was carried out for both discretisation levels based on a 1 year calibration and a 3 year validation period. Simulations performed well for both levels of spatial discretisation. The results seemed to be better in the more complex discretisation approach, where the Nash-Sutcliffe coefficient was higher. We can conclude that our first results show more accurate simulations produced by the HRP discretisation approach, the visual inspection shows a better application of the SB approach to the reproduction of the base flow.
Varying spatial patterns of trend and seasonality in Eurasian runoff time series
Authors: Rödel R.
Published: April 2010

Abstract. Atmospheric circulation indices can be used to explain the variability of runoff on a continental scale. Beside well-known regional anomalies of precipitation and runoff that correlate with phases of the North Atlantic Oscillation (NAO) there are also drifting fields of annual discharge anomalies. Following the trend of the NAO, these fields move along a longitudinal axis from western Europe to the Lena catchment in Siberia and back again. The same pattern is observable in the changing flow regimes. This paper describes the origin and causes of these anomaly fields and explains them as the results of important climate variations in the northern hemisphere.
Three-dimensional simulation of the Ring effect in observations of scattered sun light using Monte Carlo radiative transfer models
Authors: Wagner T. , Beirle S. , Deutschmann T.
Published: April 2010

Abstract. We present a new technique for the quantitative simulation of the "Ring effect" for scattered light observations from various platforms and under different atmospheric situations. The method is based on radiative transfer calculations at only one wavelength λ0 in the wavelength range under consideration, and is thus computationally fast. The strength of the Ring effect is calculated from statistical properties of the photon paths for a given situation, which makes Monte Carlo radiative transfer models in particular appropriate. We quantify the Ring effect by the so called rotational Raman scattering probability, the probability that an observed photon has undergone a rotational Raman scattering event. The Raman scattering probability is independent from the spectral resolution of the instrument and can easily be converted into various definitions used to characterise the strength of the Ring effect. We compare the results of our method to the results of previous studies and in general good quantitative agreement is found. In addition to the simulation of the Ring effect, we developed a detailed retrieval strategy for the analysis of the Ring effect based on DOAS retrievals, which allows the precise determination of the strength of the Ring effect for a specific wavelength while using the spectral information within a larger spectral interval around the selected wavelength. Using our technique, we simulated synthetic satellite observation of an atmospheric scenario with a finite cloud illuminated from different sun positions. The strength of the Ring effect depends systematically on the measurement geometry, and is strongest if the satellite points to the side of the cloud which lies in the shadow of the sun.
An experimental technique for the direct measurement of N2O5 reactivity on ambient particles
Authors: Bertram T. H. , Thornton J. A. , Riedel T. P.
Published: April 2010

Abstract. An experimental approach for the direct measurement of trace gas reactivity on ambient aerosol particles has been developed. The method utilizes a newly designed entrained aerosol flow reactor coupled to a custom-built chemical ionization mass spectrometer. The experimental method is described via application to the measurement of the N2O5 reaction probability, γ (N2O5). Laboratory investigations on well characterized aerosol particles show that measurements of γ (N2O5) observed with this technique are in agreement with previous observations, using conventional flow tube methods, to within ±20% at atmospherically relevant particle surface area concentrations (0–1000 μm2 cm−3). Uncertainty in the measured γ (N2O5) is discussed in the context of fluctuations in potential ambient biases (e.g., temperature, relative humidity and trace gas loadings). Under ambient operating conditions we estimate a single-point uncertainty in γ (N2O5) that ranges between ± (1.3×10-2 + 0.2×γ (N2O5)), and ± (1.3×10-3 + 0.2×γ (N2O5)) for particle surface area concentrations of 100 to 1000 μm2 cm−3, respectively. Examples from both laboratory investigations and field observations are included alongside discussion of future applications for the reactivity measurement and optimal deployment locations and conditions.
Experimental characterization of the COndensation PArticle counting System for high altitude aircraft-borne application
Authors: Weigel R. , Hermann M. , Curtius J. , Voigt C. , Walter S. , Böttger T. , Lepukhov B. , Belyaev G. , Borrmann S.
Published: April 2010

Abstract. A characterization of the ultra-fine aerosol particle counter COPAS (COndensation PArticle counting System) for operation on board the Russian high altitude research aircraft M-55 Geophysika is presented. The COPAS instrument consists of an aerosol inlet and two dual-channel continuous flow Condensation Particle Counters (CPCs) operated with the chlorofluorocarbon FC-43. It operates at pressures between 400 and 50 hPa for aerosol detection in the particle diameter (dp) range from 6 nm up to 1 μm. The aerosol inlet, designed for the M-55, is characterized with respect to aspiration, transmission, and transport losses. The experimental characterization of counting efficiencies of three CPCs yields dp50 (50% detection particle diameter) of 6 nm, 11 nm, and 15 nm at temperature differences (ΔT) between saturator and condenser of 17°C, 30°C, and 33°C, respectively. Non-volatile particles are quantified with a fourth CPC, with dp50=11 nm. It includes an aerosol heating line (250°C) to evaporate H2SO4-H2O particles of 11 nm<dp<200 nm at pressures between 70 and 300 hPa. An instrumental in-flight inter-comparison of the different COPAS CPCs yields correlation coefficients of 0.996 and 0.985. The particle emission index for the M-55 in the range of 1.4–8.4×1016 kg−1 fuel burned has been estimated based on measurements of the Geophysika's own exhaust.
Aerosol quantification with the Aerodyne Aerosol Mass Spectrometer: detection limits and ionizer background effects
Authors: Drewnick F. , Hings S. S. , Alfarra M. R. , Prevot A. S. H. , Borrmann S.
Published: April 2010

Abstract. Systematic laboratory experiments were performed to investigate quantification of various species with two versions of the Aerodyne Aerosol Mass Spectrometer, a Quadrupole Aerosol Mass Spectrometer (Q-AMS) and a compact Time-of-Flight Aerosol Mass Spectrometer (c-ToF-AMS). Here we present a new method to continuously determine the detection limits of the AMS analyzers during regular measurements, yielding detection limit (DL) information under various measurement conditions. Minimum detection limits range from 0.03 μg m−3 (nitrate, sulfate, and chloride) up to 0.5 μg m−3 (organics) for the Q-AMS. Those of the c-ToF-AMS are found between 0.003 μg m−3 (nitrate, sulfate) and 0.03 μg m−3 (ammonium, organics). The DL values found for the c-ToF-AMS were ~10 times lower than those of the Q-AMS, mainly due to differences in ion duty cycle. Effects causing an increase of the detection limits include long-term instrument contamination, measurement of high aerosol mass concentrations and short-term instrument history. The self-cleaning processes which reduce the instrument background after measurement of large aerosol concentrations as well as the influences of increased instrument background on mass concentration measurements are discussed. Finally, improvement of detection limits by extension of averaging time intervals, selected or reduced ion monitoring, and variation of particle-to-background measurement ratio are investigated.
Validation of water vapour profiles (version 13) retrieved by the IMK/IAA scientific retrieval processor based on full resolution spectra measured by MIPAS on board Envisat
Authors: Milz M. , Clarmann T. v. , Bernath P. , Boone C. , Buehler S. A. , Chauhan S. , Deuber B. , Feist D. G. , Funke B. , Glatthor N. , Grabowski U. , Griesfeller A. , Haefele A. , Höpfner M. , Kämpfer N. , Kellmann S. , Linden A. , Müller S. , Nakajima H. , Oelhaf H. , Remsberg E. , Rohs S. , Russell III J. M. , Schiller C. , Stiller G. P. , Sugita T. , Tanaka T. , Vömel H. , Walker K. , Wetzel G. , Yokota T. , Yushkov V. , Zhang G.
Published: April 2010

Abstract. Vertical profiles of stratospheric water vapour measured by the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) with the full resolution mode between September 2002 and March 2004 and retrieved with the IMK/IAA scientific retrieval processor were compared to a number of independent measurements in order to estimate the bias and to validate the existing precision estimates of the MIPAS data. The estimated precision for MIPAS is 5 to 10% in the stratosphere, depending on altitude, latitude, and season. The independent instruments were: the Halogen Occultation Experiment (HALOE), the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS), the Improved Limb Atmospheric Spectrometer-II (ILAS-II), the Polar Ozone and Aerosol Measurement (POAM III) instrument, the Middle Atmospheric Water Vapour Radiometer (MIAWARA), the Michelson Interferometer for Passive Atmospheric Sounding, balloon-borne version (MIPAS-B), the Airborne Microwave Stratospheric Observing System (AMSOS), the Fluorescent Stratospheric Hygrometer for Balloon (FLASH-B), the NOAA frostpoint hygrometer, and the Fast In Situ Hygrometer (FISH). For the in-situ measurements and the ground based, air- and balloon borne remote sensing instruments, the measurements are restricted to central and northern Europe. The comparisons to satellite-borne instruments are predominantly at mid- to high latitudes on both hemispheres. In the stratosphere there is no clear indication of a bias in MIPAS data, because the independent measurements in some cases are drier and in some cases are moister than the MIPAS measurements. Compared to the infrared measurements of MIPAS, measurements in the ultraviolet and visible have a tendency to be high, whereas microwave measurements have a tendency to be low. The results of χ2-based precision validation are somewhat controversial among the comparison estimates. However, for comparison instruments whose error budget also includes errors due to uncertainties in spectrally interfering species and where good coincidences were found, the χ2 values found are in the expected range or even below. This suggests that there is no evidence of systematically underestimated MIPAS random errors.
Stratospheric isotopic water profiles from a single submillimeter limb scan by TELIS
Authors: de Lange A. , Landgraf J. , Hoogeveen R.
Published: April 2010

Abstract. Around 490 GHz relatively strong HDO and H218O emission lines can be found in the submillimeter thermal-emission spectrum of the Earth's atmosphere, along with lines of the principal isotopologue of water vapour. These can be used for remote sensing of the rare/principal isotope ratio in the stratosphere. A sensitivity study has been performed for retrieval simulations of water isotopologues from balloon-borne measurements by the limb sounder TELIS (TErahertz and submillimeter LImb Sounder). The study demonstrates the capability of TELIS to determine, from a single limb scan, the profiles for H218O and HDO between 20 km and 37 km with a retrieval error of ≈3 and a spatial resolution of 1.5 km, as determined by the width of the averaging kernel. In addition HDO can be retrieved in the range of 10–20 km, albeit with a strongly deteriorated retrieval error. Expected uncertainties in instrumental parameters have only limited impact on the retrieval results.
Determination of aerosol properties from MAX-DOAS observations of the Ring effect
Authors: Wagner T. , Deutschmann T. , Platt U.
Published: April 2010

Abstract. The first quantitative comparison of MAX-DOAS observations of the Ring effect with model simulations is presented. It is performed for a large variety of viewing geometries (solar zenith angles: 45° to 90°, elevation angles: 3°, 6°, 10°, 18°, 90°; three different azimuth angles), which allows a comprehensive test of our capabilities to measure and simulate the Ring effect. In addition to the Ring effect, also the observed O4 absorptions (optical densities) and radiances are compared with model simulations. In general good agreement is found for all measured quantities. From several sensitivity studies it is found that for most measurement situations, the aerosol optical depth has usually the strongest influence on the observed quantities, but also other aerosol properties like e.g. the vertical distribution have a significant effect. In some aspects, the qualitative dependence of the Ring effect on aerosol properties is similar to that of the O4 absorption. This can be understood, since both quantities depend strongly on the light path length in the lower atmosphere. However, since the Ring effect depends also on the properties of the scattering processes, in specific cases observation of the Ring effect can provide complementary information to that retrieved from the O4 observations. This is e.g. possible for measurements at small relative azimuth angles, from which information on the aerosol phase function can be derived. Observations at large solar zenith angle might allow the retrieval of stratospheric aerosol properties, even in cases with very low aerosol optical depths. In addition, Ring effect observations in zenith direction are rather sensitive to the aerosol optical depth (in contrast to O4 observations), which might allow to retrieve information on aerosol properties from existing zenith UV data sets prior to the MAX-DOAS era.