Hafnium isotopic record of crustal maturation during Middle Triassic magmatism in the Southern Alps (Italy)
Authors: Storck Julian-Christopher , Wotzlaw Jörn-Frederik , Karakas Ozge , Brack Peter , Gerdes Axel , Ulmer Peter 
Published: March 2020

&lt;p&gt;Tracing the origin and evolution of magmas on their pathway through the lithosphere is key to understanding the magmatic processes that eventually produce eruptions. For ancient magmatic provinces, isotope-geochemical tracers are powerful tools to probe the source regions and magma-crust interaction during ascent and storage.&lt;/p&gt;&lt;p&gt;We present new hafnium isotopic compositions of ID-TIMS dated zircons to trace the evolution of the Middle Triassic magmatic province in the Southern Alps (northern Italy) at high temporal resolution [1]. Systematic changes in hafnium isotopic composition with time reveal a coherent temporal evolution from depleted mantle signatures towards crust-dominated signatures within less than four million years. This trend can be ascribed to progressive influence of a crustal source, incorporated into the reservoir from which these zircons crystallized. Towards the end of the magmatic episode, the &amp;#949;Hf compositions abruptly revert within one-million-years back towards more juvenile compositions mainly recorded by the mafic to intermediate intrusive pulses (e.g. Monzoni and Predazzo), the effusive climax of basaltic lavas and the post-intrusive ash beds (e.g. Punta Grohmann) in the Dolomite region. We interpret the variation of Hf-isotopic signatures over time as a protracted contamination signal induced by interaction of the mantle-derived magmas with the lower crust.&lt;/p&gt;&lt;p&gt;The dataset obtained in this study is further implemented into a two-component mixing model employing a range of potential crust and mantle endmember Hf isotope signatures and Hf concentrations which is directly translated into crustal melt/total melt (=sum of crustal and mantle-derived melt) ratios over time. Based on these observations we explored the thermal evolution and crustal melting as a function of time, lithology, water content and magma flux for a lower crustal magmatic system by numerical modelling. Dykes and sills of basaltic composition are incrementally emplaced at the mantle-crust boundary, which leads to changes in crustal over mantle melt ratios over time. Initial intrusions of basaltic dykes into the relatively cold lower crust cause only limited crustal melting and assimilation but ensuing magma injections into progressively hotter crust results in more extensive partial melting and assimilation of crustal material. Subsequent intrusions into the magmatic lower-crustal roots cannibalize previous intrusions with progressively less isotopic contrast due to dilution with mantle-derived magmas. This is potentially accompanied by an increase in magma flux, e.g. by delamination of dense lower crustal cumulates into the subcontinental lithospheric mantle.&lt;/p&gt;&lt;p&gt;The observed trends in hafnium isotopic composition therefore do not necessarily require tectonic re-organizations or changes in mantle sources. Instead these trends may trace variations in mantle-crust interaction during thermally induced chemical maturation of the lower crustal magmatic roots progressively replacing ancient pelitic to mafic lower crustal lithologies by juvenile cumulates.&lt;/p&gt;&lt;p&gt;&amp;#160;&lt;/p&gt;&lt;p&gt;[1] Storck, J.-C., Wotzlaw, J.-F., Karakas, O., Brack, P., Gerdes, A., Ulmer, P. Hafnium isotopic record of mantle-crust interaction in an evolving continental magmatic system, Earth and Planetary Science Letters, &lt;em&gt;(in press)&lt;/em&gt;.&lt;/p&gt;