Boron isotope systematics of Higashi-akaishi mantle wedge peridotites (Sanbagawa belt, Japan): implications for fluid recycling in subduction zones
Authors: De Hoog Cees-Jan , Hattori Keiko , Clarke Eleri 
Published: March 2021

&lt;p&gt;Boron provides an efficient tracer of fluids in subduction zones, due to its high concentration in surface reservoirs, low concentration in the mantle, and large isotope fractionation. The Higashi-akaishi peridotite body in Sanbagawa UHP belt, Japan, is composed of partially serpentinised dunites and harzburgites, which are interpreted to be exhumed mantle wedge peridotites. Compositions of olivine (Fo90-94, NiO 0.28-0.48 wt%, MnO 0.10-0.16 wt%) and chromite (Cr# &gt;0.7, TiO&lt;sub&gt;2&lt;/sub&gt; &lt;0.4 wt%) confirm its origin as highly refractory fore-arc mantle. Several generations of olivine and serpentine can be recognised in the samples, and were analysed in-situ for their B content and B isotopic composition by SIMS. Coarse-grained primary mantle olivine has low [B] (1-3 &amp;#181;g/g), but is still significantly B-enriched compared to typical mantle olivine, and has &amp;#948;&lt;sup&gt;11&lt;/sup&gt;B of -10 to -3 &amp;#8240;. Lower B contents in olivine cores compared to rims suggests diffusive incorporation of B from slab-derived fluids at high temperature. &amp;#160;Later fine-grained olivine neoblasts, products of dynamic recrystallization, have higher [B] (3-11 &amp;#181;g/g) and higher &amp;#948;&lt;sup&gt;11&lt;/sup&gt;B (-7 to +2&amp;#8240;). Platy antigorite associated with the olivine neoblasts have similar [B] (4-12 &amp;#181;g/g) but higher &amp;#948;&lt;sup&gt;11&lt;/sup&gt;B (-4 to +6&amp;#8240;). Late-stage greenschist-facies overprint resulted in lizardite veining with high [B] (18-52 &amp;#181;g/g) and a narrow range of &amp;#948;&lt;sup&gt;11&lt;/sup&gt;B (-2 to -1&amp;#8240;).&lt;/p&gt;&lt;p&gt;We envisage the following scenario. Coarse-grained mantle olivine acquired B from slab-derived fluids when the peridotites were dragged down by mantle corner flow and positioned near the slab-mantle interface. The values of &amp;#948;&lt;sup&gt;11&lt;/sup&gt;B (-10 to -3&amp;#8240;) are consistent with fluids from dehydrating slab at ca. 110-150 km depth, but are potentially affected by diffusion-controlled kinetic isotope fractionation. High temperatures (&gt; 650-700&amp;#176;C) prevented the peridotites from serpentinisation. Subsequently the rocks were down-dragged in a subduction channel where olivine neoblasts formed first and platy antigorite crystallized later when temperature dropped below 650&amp;#176;C. Both phases show heavier &amp;#948;&lt;sup&gt;11&lt;/sup&gt;B than coarse-grained olivine; the values are consistent with fluids from dehydrating slab at ca. 70-100 km depth. Finally, the peridotites were exposed to crust-derived B-rich fluids with low &amp;#948;&lt;sup&gt;11&lt;/sup&gt;B during exhumation and amalgamation with crustal units, forming lizardite veining during greenschist-facies overprint.&lt;/p&gt;&lt;p&gt;This study shows that mantle olivine may scavenge significant amounts of B from percolating fluids by diffusive re-equilibration or dynamic recrystallisation, lowering the B content of such fluids and potentially modifying their B isotopic composition.&lt;/p&gt;