bluuebunny/crossref_metadata_2025 huggingface dataset:
Desoxybenzoin
Authors: Allen C. F. H. , Barker W. E.
Published: November 2003

Desoxybenzoin

product: desoxybenzoin
1,2‐Dibromocyclohexane
Authors: Snyder H. R. , Brooks L. A.
Published: November 2003

1,2‐Dibromocyclohexane

product: 1,2‐Dibromocyclohexane
Ethyl α,β‐Dibromo‐β‐phenylpropionate
Authors: Abbott T. W. , Althousen Darrell
Published: November 2003

Ethyl α,β‐dibromo‐β‐phenylpropionate

solvent: petroleum ether

product: Ethyl α,β‐dibromo‐β‐phenylpropionate
Methyl Isopropyl Carbinol
Authors: Drake Nathan L. , Cooke Giles B.
Published: November 2003

Methyl isopropyl carbinol

reactant: 600 g. (4.9 moles) of isopropyl bromide

reactant: 200 g. (4.5 moles) of acetaldehyde

product: methyl isopropyl carbinol
Phenylpropiolic Acid
Authors: Abbott T. W.
Published: November 2003

Phenylpropiolic acid

product: phenylpropiolic acid

reactant: α,β‐dibromocinnamic acid
Phenyl Thienyl Ketone
Authors: Minnis Wesley
Published: November 2003

Phenyl thienyl ketone

solvent: 1 l. of petroleum ether

product: Phenyl thienyl ketone
Succinic Anhydride
Authors: Fieser Louis F. , Martin E. L. , Shriner R. L. , Struck H. C.
Published: November 2003

Succinic anhydride

reactant: 118 g. (1 mole) of succinic acid

product: succinic anhydride
Thiophene
Authors: Phillips Ross
Published: November 2003

Thiophene

product: thiophene
Uramil
Authors: Hartman W. W. , Sheppard O. E.
Published: November 2003

Uramil

product: uramil
Benzalphthalide
Authors: Weiss Richard
Published: November 2003

Benzalphthalide

reactant: 100 g. (0.67 mole) of phthalic anhydride

product: benzalphthalide
Isobutyl Bromide
Authors: Noller C. R. , Dinsmore R.
Published: November 2003

Isobutyl bromide

reactant: 518 g. (643 cc., 7 moles) of dry isobutyl alcohol

reactant: 695 g. (244 cc., 2.56 moles) of phosphorus tribromide

product: isobutyl bromide

product:
sec.
‐butyl

product:
n
‐propyl

product: isopropyl
2,4‐Dinitrophenylhydrazine
Authors: Allen C. F. H.
Published: November 2003

2,4‐Dinitrophenylhydrazine

product: 2,4‐Dinitrophenylhydrazine
p‐Fluorobenzoic Acid
Authors: Schiemann G. , Winkelmüller W.
Published: November 2003

p‐Fluorobenzoic acid

intermediate:p‐carbethoxybenzenediazonium fluoborate

product:p‐fluorobenzoic acid

product: Ethylp‐aminobenzoate
N‐Nitrosomethylaniline
Authors: Hartman W. W. , Roll L. J.
Published: November 2003

N‐nitrosomethylaniline

product: N‐Nitrosomethylaniline
Tricarbomethoxymethane
Authors: Corson B. B. , Sayre J. L.
Published: November 2003

Tricarbomethoxymethane

product: tricarbomethoxymethane

solvent: 70 cc. of petroleum ether
2,6‐Dimethylpyridine
Authors: Singer Alvin , McElvain S. M.
Published: November 2003

2,6‐Dimethylpyridine

intermediate: 1,4‐dihydro‐3,5‐dicarbethoxy‐2,6‐dimethylpyridine

intermediate: 3,5‐dicarbethoxy‐2,6‐dimethylpyridine

product: 2,6‐Dimethylpyridine
Diphenylmethane
Authors: Hartman W. W. , Phillips Ross
Published: November 2003

Diphenylmethane

product: diphenylmethane
2‐Hydroxy‐3,5‐diiodobenzoic Acid
Authors: Woollett G. H. , Johnson W. W.
Published: November 2003

2‐Hydroxy‐3,5‐diiodobenzoic acid

reactant: Twenty‐five grams (0.18 mole) of salicylic acid

reactant: 62 g. (0.38 mole) of iodine monochloride

product: diiodosalicylic acid

product: 4‐hydroxy‐3,5‐diiodobenzoic acid
β‐Hydroxyethyl Methyl Sulfide
Authors: Windus Wallace , Shildneck P. R.
Published: November 2003

β‐Hydroxyethyl methyl sulfide

reactant: 302 g. (3.75 moles) of ethylene chlorohydrin

product: β‐hydroxyethyl methyl sulfide
2‐Nitrothiophene
Authors: Babasinian V. S.
Published: November 2003

2‐Nitrothiophene

product: Mononitrothiophene

solvent: petroleum ether
Phenylglyoxal
Authors: Riley H. A. , Gray A. R.
Published: November 2003

Phenylglyoxal

product: phenylglyoxal
n
‐Propyl Sulfide
Authors: Bost R. W. , Conn M. W.
Published: November 2003

n
‐Propyl sulfide

solvent: 200‐cc. portions of petroleum ether

product: propyl sulfide
p‐Nitrobenzyl Bromide
Authors: Coleman G. H. , Honeywell G. E.
Published: November 2003

p‐Nitrobenzyl bromide

reactant: 300 g. (2.2 moles) of technicalp‐nitrotoluene

solvent: 4 l. of hot ligroin

product:p‐Nitrobenzyl bromide
Benzoylene Urea
Authors: Lange N. A. , Sheibley F. E.
Published: November 2003

Benzoylene urea

product: benzoylene urea
p‐Bromobenzaldehyde
Authors: Coleman George H. , Honeywell G. E.
Published: November 2003

p‐bromobenzaldehyde

product:p‐bromobenzaldehyde
Ethyl Ethoxalylpropionate
Authors: Cox Richard F. B. , McElvain S. M.
Published: November 2003

Ethyl ethoxalylpropionate

product: Ethyl ethoxalylpropionate
Ethyl Methylmalonate
Authors: Cox Richard F. B. , McElvain S. M. , Weiner Nathan
Published: November 2003

Ethyl methylmalonate

reactant: Three hundred forty‐five grams (1.7 moles) of ethyl ethoxalylpropionate

product: ethyl methylmalonate
2‐Acetothienone
Authors: Johnson John R. , May G. E.
Published: November 2003

2‐Acetothienone

product: 2‐acetothienone
α‐Chloroanthraquinone
Authors: Scott W. J. , Allen C. F. H.
Published: November 2003

α‐Chloroanthraquinone

product: α‐chloroanthraquinone
Methyl Benzyl Ketone
Authors: Herbst R. M. , Manske R. H. , Julian Percy L. , Oliver John J.
Published: November 2003

Methyl benzyl ketone

reactant: 136 g. (1 mole) of phenylacetic acid

product: methyl benzyl ketone

byproduct: dibenzyl ketone
p
‐Nitrobenzaldehyde
Authors: Lieberman S. V. , Connor Ralph
Published: November 2003

p
‐Nitrobenzaldehyde

reactant: 50 g. (0.36 mole) of
p
‐nitrotoluene

intermediate:
p
‐nitrobenzaldiacetate

product:
p
‐nitrobenzoic acid

product:
p
‐bromobenzaldehyde

intermediate:
p
‐bromobenzaldiacetate

product:
p
‐nitrobenzaldehyde
Protocatechualdehyde
Authors: Buck Johannes S. , Zimmermann F. J.
Published: November 2003

Protocatechualdehyde

product: Protocatechualdehyde
Acridone
Authors: Allen C. F. H. , McKee G. H. W.
Published: November 2003

Acridone

intermediate: 42.7 g. (0.2 mole) of N‐phenylanthranilic acid

product: acridone
Benzimidazole
Authors: Wagner E. C. , Millett W. H.
Published: November 2003

Benzimidazole

reactant: 54 g. (0.5 mole) ofo‐phenylenediamine

product: benzimidazole

product: 2‐methyl‐benzimidazole
Dichloroacetic Acid
Authors: Cope Arthur C. , Clark John R. , Connor Ralph
Published: November 2003

Dichloroacetic acid

product: dichloroacetic acid
Hexamethylene Glycol
Authors: Lazier W. A. , Hill J. W. , Amend W. J.
Published: November 2003

Hexamethylene glycol

reactant: 252 g. (1.25 moles) of ethyl adipate

product: Hexamethylene glycol
Triphenylmethylsodium
Authors: Renfrow W. B. , Hauser C. R.
Published: November 2003

Triphenylmethylsodium

reactant: 63 g. (0.226 mole) of pure triphenylchloromethane

solvent: ligroin
9‐Anthraldehyde; 2‐Ethoxy‐1‐Naphthaldehyde
Authors: Fieser (A) L. F. , Hartwell J. L. , Jones J. E. , Wood (B) J. H. , Bost R. W.
Published: November 2003

9‐anthraldehyde; 2‐ethoxy‐1‐naphthaldehyde

product: 9‐Anthraldehyde

reactant: 22.5 g. (0.13 mole) of anthracene

product: 2‐Ethoxy‐1‐naphthaldehyde
D
‐Arabinose
Authors: Braun Géza
Published: November 2003

D
‐arabinose

product: arabinose

product:
D
‐arabinose

product: diphenylhydrazone
1,2,3‐Benzotriazole
Authors: Damschroder R. E. , Peterson W. D.
Published: November 2003

1,2,3‐Benzotriazole

product: 1,2,3‐Benzotriazole
Dehydroacetic Acid
Authors: Arndt F.
Published: November 2003

Dehydroacetic acid

product: dehydroacetic acid
α,α‐Dichloroacetamide
Authors: Clark John R. , Shibe W. J. , Connor Ralph
Published: November 2003

α,α‐Dichloroacetamide

product: Dichloroacetamide
2,2′‐Dinitrobiphenyl
Authors: Fuson Reynold C. , Cleveland E. A.
Published: November 2003

2,2′‐Dinitrobiphenyl

product: 2,2′‐dinitrobiphenyl
N‐Methylformanilide
Authors: Fieser L. F. , Jones J. E.
Published: November 2003

N‐methylformanilide

product: N‐Methylformanilide
Pentaacetyl
d
‐Glucononitrile
Authors: Clarke H. T. , Nagy S. M.
Published: November 2003

Pentaacetyl
d
‐glucononitrile

product: pentaacetyl
d
‐glucononitrile
Acenaphthenol‐7
Authors: Cason James
Published: November 2003

Acenaphthenol‐7

intermediate:
Acenaphthenol acetate

reactant: 154 g. (1 mole) of acenaphthene

product: acenaphthenol
Acetoacetanilide
Authors: Williams Jonathan W. , Krynitsky John A.
Published: November 2003

Acetoacetanilide

product: acetoacetanilide
2‐Hydroxy‐1,4‐naphthoquinone
Authors: Fieser L. F. , Martin E. L.
Published: November 2003

2‐Hydroxy‐1,4‐naphthoquinone

product: 2‐hydroxy‐1,4‐naphthoquinone

intermediate: methoxynaphthoquinone
Resacetophenone
Authors: Cooper S. R.
Published: November 2003

Resacetophenone

product: resacetophenone
9‐Aminoacridine
Authors: Albert Adrien , Ritchie Bruce
Published: November 2003

9‐Aminoacridine

intermediate: 9‐chloroacridine

product: 9‐aminoacridines
Azobenzene
Authors: Bigelow H. E. , Robinson D. B.
Published: November 2003

Azobenzene

product: azobenzene
Diphenylacetylene
Authors: Smith Lee Irvin , Falkof M. M.
Published: November 2003

Diphenylacetylene

solvent: stilbene dibromide

product: diphenylacetylene
1,1‐Cyclobutanedicarboxylic Acid and Cyclobutanecarboxylic Acid
Authors: Heisig G. B. , Stodola F. H.
Published: November 2003

1,1‐Cyclobutanedicarboxylic acid and cyclobutanecarboxylic acid

product: 1,1‐cyclobutanedicarboxylic acid

product: cyclobutanecarboxylic acid

reactant: ethyl pentane‐1,1,5,5‐tetracarboxylate
β,β‐Dimethylacrylic Acid
Authors: Smith Lee Irvin , Prichard W. W. , Spillane Leo J.
Published: November 2003

β,β‐dimethylacrylic acid

product: Dimethylacrylic acid

solvent: petroleum ether
β‐Dimethylaminopropiophenone Hydrochloride
Authors: Maxwell Charles E.
Published: November 2003

β‐dimethylaminopropiophenone hydrochloride

product: β‐dimethylaminopropiophenone hydrochloride

reactant: 60 g. (58.5 ml., 0.5 mole) of acetophenone
Ethyl Benzoylacetate
Authors: McElvain S. M. , Weber K. H.
Published: November 2003

Ethyl benzoylacetate

product: ethyl benzoylactetate
Mandelic Acid
Authors: Aston J. G. , Newkirk J. D. , Jenkins D. M. , Dorsky Julian
Published: November 2003

Mandelic Acid

intermediate: dichloroacetophenone

product: mandelic acid
β‐Phenylethylamine
Authors: Robinson John C. , Snyder H. R.
Published: November 2003

β‐Phenylethylamine

product: β‐phenylethylamine

byproduct: Di‐(β‐phenylethyl)‐amine

product:n‐hexylamine

product: 3,4‐dimethoxyphenylethylamine

product:o‐methylphenylethylamine

product:m‐methylphenylethylamine

product:p‐methylphenylethylamine

product: 3,4‐methylenedioxyphenylethylamine
Tetrahydrofurfuryl Bromide
Authors: Smith L. H.
Published: November 2003

Tetrahydrofurfuryl bromide

reactant: 96 g. (56.5 ml., 0.36 mole) of redistilled phosphorus tribromide

reactant: 102 g. (1 mole) of redistilled tetrahydrofurfuryl alcohol

product: tetrahydrofurfuryl bromide
Tetraphenylcyclopentadienone
Authors: Johnson John R. , Grummitt Oliver
Published: November 2003

Tetraphenylcyclopentadienone

product: tetraphenylcyclopentadienone
4‐Amino‐4H‐1,2,4‐Triazole
Authors: Allen C. F. H. , Bell Alan
Published: November 2003

4‐Amino‐4H‐1,2,4‐triazole

reactant: 148 g. (2 moles) of ethyl formate

product: 4‐amino‐1,2,4‐triazole hydrochloride

product: 4‐Amino‐1,2,4‐triazole
2‐Chlorolepidine
Authors: Kaslow C. E. , Lauer W. M.
Published: November 2003

2‐Chlorolepidine

product: 2‐chlorolepidine

solvent: 250 ml. of petroleum ether
nor
‐Desoxycholic Acid
Authors: Riegel Byron , Moffett R. B. , McIntosh A. V.
Published: November 2003

nor
‐desoxycholic acid

product:
nor
‐desoxycholic acid

product: bisnor‐Desoxycholic acid
3,12‐Diacetoxy‐
bisnor
‐Cholanyldiphenylethylene
Authors: Riegel Byron , Moffett R. B. , McIntosh A. V.
Published: November 2003

3,12‐Diacetoxy‐
bisnor
‐cholanyldiphenylethylene

intermediate: 102 g. (0.25 mole) of methyl desoxycholate in 700 ml. of dry benzene

product: 3,12‐diacetoxy‐
bisnor
‐cholanyldiphenylethylene
2,6‐Dichloroaniline and 2,6‐Dibromoaniline
Authors: Seikel Margaret K.
Published: November 2003

2,6‐Dichloroaniline and 2,6‐dibromoaniline

intermediate: 3,5‐dichlorosulfanilamide

product: 2,6‐dichloroaniline

intermediate: 3,5‐dibromosulfanilamide

product: 2,6‐dibromoaniline
Ethyl Hydrazinecarboxylate and Diaminobiuret
Authors: Allen C. F. H. , Bell Alan
Published: November 2003

Ethyl hydrazinecarboxylate and diaminobiuret

product: diaminobiuret

product: Ethyl hydrazinecarboxylate
4‐Methylcarbostyril
Authors: Lauer W. M. , Kaslow C. E.
Published: November 2003

4‐Methylcarbostyril

product: 4‐methylcarbostyril
2‐Amino‐4‐Nitrophenol
Authors: Hartman W. W. , Silloway H. L.
Published: November 2003

2‐Amino‐4‐nitrophenol

product: 2‐amino‐4‐nitrophenol
Benzoylacetanilide
Authors: Kibler Charles J. , Weissberger A.
Published: November 2003

Benzoylacetanilide

solvent: 50 ml. of petroleum ether

product: benzoylacetanilide
1‐
n
‐Butylpyrrolidine
Authors: Coleman George H. , Nichols Gust , Martens Ted F.
Published: November 2003

1‐
n
‐Butylpyrrolidine

product: 1‐
n
‐butylpyrrolidine
Diazomethane
Authors: Redemann C. Ernst , Rice F. O. , Roberts R. , Ward H. P.
Published: November 2003

Diazomethane

product: diazomethane

intermediate: 15.8 g. (0.1 mole) of N‐nitroso‐β‐methylaminoisobutyl methyl ketone
2,5‐Dimethylmandelic Acid
Authors: Riebsomer J. L. , Irvine James
Published: November 2003

2,5‐Dimethylmandelic acid

intermediate:
Ethyl 2,5‐dimethylphenylhydroxymalonate

product: 2,5‐dimethylmandelic acid
β‐
d
‐Glucose‐2,3,4,6‐Tetraacetate
Authors: McCloskey Chester M. , Coleman George H.
Published: November 2003

β‐
d
‐Glucose‐2,3,4,6‐tetraacetate

reactant: 82.2 g. (0.2 mole) of acetobromoglucose

product: β‐
d
‐Glucose‐2,3,4,6‐tetraacetate (2,3,4,6‐tetraacetyl‐β‐
d
‐glucose)
m
‐Hydroxybenzaldehyde
Authors: Woodward R. B.
Published: November 2003

m
‐Hydroxybenzaldehyde

reactant: 100 g. (0.66 mole) of
m
‐nitrobenzaldehyde

product:
m
‐Hydroxybenzaldehyde
Isobutyronitrile
Authors: Kent R. E. , McElvain S. M.
Published: November 2003

Isobutyronitrile

product: isobutyronitrile
Methyl Sebacamate
Authors: Bishop W. S.
Published: November 2003

Methyl sebacamate

reactant: 216 g. (1 mole) of methyl hydrogen sebacate

intermediate: ω‐carbomethoxypelargonyl chloride

product: methyl sebacamate
2‐Nitro‐4‐Methoxyaniline
Authors: Fanta Paul E. , Tarbell D. S.
Published: November 2003

2‐Nitro‐4‐methoxyaniline

intermediate: 2‐nitro‐4‐methoxyacetanilide

product: 2‐Nitro‐4‐methoxyaniline
Nitrosobenzene
Authors: Coleman George H. , McCloskey Chester M. , Stuart Frank A.
Published: November 2003

Nitrosobenzene

product: nitrosobenzene
Allyl Lactate
Authors: Rehberg Chessie E.
Published: November 2003

Allyl lactate

byproduct: benzene‐allyl alcohol binary azeotrope

byproduct: allyl ether

product: allyl lactate
3‐Amino‐1H‐1,2,4‐triazole
Authors: Sjostedt Georg , Gringas Leopold
Published: November 2003

3‐Amino‐1H‐1,2,4‐triazole

product: 3‐amino‐1,2,4‐triazole
Di‐(
p
‐Chlorophenyl)Acetic Acid
Authors: Grummitt Oliver , Buck Allen , Egan Richard
Published: November 2003

Di‐(
p
‐chlorophenyl)acetic acid

solvent: 400 ml. of diethylene glycol

reactant: 49.5 g. (0.14 mole) of 1,1‐di‐(
p
‐chlorophenyl)‐2,2,2‐trichloroethane

product: di‐(
p
‐chlorophenyl) acetic acid

byproduct: di‐(
p
‐chlorophenyl) methane
Lepidine
Authors: Neumann Fred W. , Sommer Nolan B. , Kaslow C. E. , Shriner R. L.
Published: November 2003

Lepidine

reactant: 20 g. (0.11 mole) of pure 2‐chlorolepidine

catalyst: 3 g. of palladium on carbon

product: 6‐Methyllepidine

product: 8‐Methyllepidine

product: 5,8‐Dimethyllepidine

product: 6,8‐Dimethyllepidine

product: 6‐Methoxylepidine monohydrate

product: 5,8‐Dimethoxylepidine

product: 2‐Methyl‐6‐methoxyquinoline

product: Lepidine
Muconic Acid
Authors: Guha P. C. , Sankaran D. K.
Published: November 2003

Muconic acid

intermediate: 1130 g. (3.14 moles) of diethyl α,δ‐dibromoadipate

product: muconic acid
Ozone
Authors: Smith L. I. , Greenwood F. L. , Hudrlik O.
Published: November 2003

Ozone

product: ozone
β‐Alanine
Authors: Ford Jared H.
Published: November 2003

β‐Alanine

product: β‐alanine
Biallyl
Authors: Turk Amos , Chanan Henry
Published: November 2003

Biallyl

reactant: 459 g. (6 moles) of dry, freshly distilled allyl chloride

product: biallyl
Diethylaminoacetonitrile
Authors: Allen C. F. H. , VanAllan J. A.
Published: November 2003

Diethylaminoacetonitrile

product: Diethylaminoacetonitrile
3,5‐Dimethyl‐4‐Carbethoxy‐2‐Cyclohexen‐1‐One and 3,5‐Dimethyl‐2‐Cyclohexen‐1‐One
Authors: Horning E. C. , Denekas M. O. , Field R. E.
Published: November 2003

3,5‐Dimethyl‐4‐carbethoxy‐2‐cyclohexen‐1‐One and 3,5‐Dimethyl‐2‐Cyclohexen‐1‐One

product: 3,5‐dimethyl‐4‐carbethoxy‐2‐cyclohexen‐1‐one

product: 3,5‐dimethyl‐2‐cyclohexen‐1‐one
2,3‐Diphenylindone (2,3‐Diphenyl‐1‐Indenone)
Authors: Allen C. F. H. , Gates J. W. , VanAllan J. A.
Published: November 2003

2,3‐Diphenylindone (2,3‐diphenyl‐1‐indenone)

product: 2,3‐diphenylindone
m
‐Nitrodimethylaniline
Authors: Fitch Howard M.
Published: November 2003

m
‐nitrodimethylaniline

reactant: 363 g. (3.0 moles) of dimethylaniline

product:
p
‐nitrodimethylaniline

product:
m
‐nitrodimethylaniline
m
‐Thiocresol
Authors: Tarbell D. S. , Fukushima D. K.
Published: November 2003

m
‐Thiocresol

reactant: 80 g. (0.75 mole) of
m
‐toluidine

product:
m
‐thiocresol
p
‐Toluic Acid
Authors: Tuley W. F. , Marvel C. S.
Published: November 2003

p
‐Toluic acid

product:
p
‐toluic acid
o
‐Toluidinesulfonic Acid
Authors: Allen C. F. H. , VanAllan J. A.
Published: November 2003

o
‐Toluidinesulfonic acid

product:
o
‐toluidinesulfonic acid
2‐Acetothienone
Authors: Kosak Alvin I. , Hartough Howard D.
Published: November 2003

2‐Acetothienone

reactant: 76–80 g. of unchanged thiophene

product: 2‐acetothienone
2‐Acetylfluorene
Authors: Ray F. E. , Rieveschl George
Published: November 2003

2‐Acetylfluorene

reactant: 80 g. (0.48 mole) of fluorene

solvent: 100‐ml. portion of petroleum ether

product: 2‐acetylfluorene
o
‐Aminobenzaldehyde
Authors: Smith Lee Irvin , Opie J. W.
Published: November 2003

o
‐Aminobenzaldehyde

product:
o
‐Aminobenzaldehyde
Benzoyl Disulfide
Authors: Frank Robert L. , Blegen James R.
Published: November 2003

Benzoyl disulfide

product: Benzoyl disulfide
3‐Carbethoxycoumarin
Authors: Horning E. C. , Horning M. G. , Dimmig D. A.
Published: November 2003

3‐Carbethoxycoumarin

reactant: 61 g. (0.50 mole) of salicylaldehyde

product: 3‐carbethoxycoumarin
2‐Hydroxycinchoninic Acid
Authors: Jacobs Thomas L. , Winstein S. , Linden Gustave B. , Robson Jean H. , Levy Edward F. , Seymour Dexter
Published: November 2003

2‐Hydroxycinchoninic acid

reactant: 600 g. (4.1 moles) of isatin

intermediate: N‐acetylisatin

product: 2‐Hydroxycinchoninic acid
α‐Phenylthiourea
Authors: Frank Robert L. , Smith Paul V.
Published: November 2003

α‐Phenylthiourea

product: α‐Phenylthiourea
Ethyl 2‐Pyridylacetate
Authors: Woodward R. B. , Kornfeld E. C.
Published: November 2003

Ethyl 2‐pyridylacetate

product: ethyl 2‐pyridylacetate

product: Methyl 2‐pyridylacetate
m
‐Nitrobenzaldehyde Dimethylacetal
Authors: Icke Roland N. , Redemann C. Ernst , Wisegarver Burnett B. , Alles Gordon A.
Published: November 2003

m
‐Nitrobenzaldehyde dimethylacetal

product:
m
‐
Nitrobenzaldehyde dimethylacetal
.
p
‐Nitrobenzonitrile
Authors: Miller Charles S.
Published: November 2003

p
‐nitrobenzonitrile

product:
p
‐nitrobenzonitrile
α‐Phenylcinnamonitrile
Authors: Wawzonek Stanley , Smolin Edwin M.
Published: November 2003

α‐Phenylcinnamonitrile

product: α‐Phenylcinnamonitrile
1,2,5‐Trihydroxypentane
Authors: Grummitt Oliver , Stearns James A. , Arters A. A.
Published: November 2003

1,2,5‐Trihydroxypentane

reactant: 680 ml. (714 g., 7 moles) of redistilled tetrahydrofurfuryl alcohol

intermediate: 1,2,5‐triacetoxypentane

product: 1,2,5‐trihydroxypentane
9‐Acetylanthracene
Authors: Merritt Charles , Braun Charles E.
Published: November 2003

9‐Acetylanthracene

product: 9‐acetylanthracene

reactant: Technical grade anthracene
p
‐Aminotetraphenylmethane
Authors: Witten Benjamin , Reid E. Emmet
Published: November 2003

p
‐Aminotetraphenylmethane

product:
p
‐Aminotetraphenylmethane
n
‐Butylacetylene
Authors: Campbell Kenneth N. , Campbell Barbara K.
Published: November 2003

n
‐butylacetylene

product:
n
‐butylacetylene

product:
n
‐propylacetylene

product:
n
‐Amylacetylene

product: isoamylacetylene

product:
n
‐Hexylacetylene
N‐Methyl‐2,3‐Dimethoxybenzylamine
Authors: Balcom Don M. , Noller C. R.
Published: November 2003

N‐methyl‐2,3‐dimethoxybenzylamine

product: N‐methyl‐2,3‐dimethoxybenzylamine

reactant: 2,3‐dimethoxybenzaldehyde employed was a darkcolored product supplied by the Monsanto Chemical Company or Eastman Kodak Company
Phenylacetylene
Authors: Campbell Kenneth N. , Campbell Barbara K.
Published: November 2003

Phenylacetylene

product: phenylacetylene
α‐Phenylglutaric Anhydride
Authors: Horning E. C. , Finelli A. F.
Published: November 2003

α‐phenylglutaric anhydride

product: α‐Phenylglutaric Anhydride
Arylureas:
p
‐Bromophenylurea
Authors: Kurzer Frederick
Published: November 2003

Arylureas:
p
‐bromophenylurea

product:
p
‐bromophenylurea

:
p
‐Tolylurea

:
m
‐Tolylurea

:
o
‐Tolylurea

: 1‐(4‐Biphenylyl)urea

: 1‐(2‐Biphenylyl)urea

:
p
‐Methoxyphenylurea

:
p
‐Ethoxyphenylurea

:
m
‐Ethoxyphenylurea

:
o
‐Ethoxyphenylurea

:
m
‐Bromophenylurea

:
o
‐Bromophenylurea

:
o
‐Chlorophenylurea
o
‐Chlorophenylcyanamide
Authors: Kurzer Frederick
Published: November 2003

o
‐Chlorophenylcyanamide

product:
o
‐chlorophenylcyanamide

product: α‐naphthylcyanamide
2,6‐Dinitroaniline
Authors: Schultz Harry P.
Published: November 2003

2,6‐Dinitroaniline

product: 2,6‐dinitroaniline
N,N′‐Diphenylbenzamidine
Authors: Hontz Arthur C. , Wagner E. C.
Published: November 2003

N,N′‐diphenylbenzamidine

product: N,N′‐diphenylbenzamidine
O‐Methylcaprolactim
Authors: Benson Richard E. , Cairns Theodore L.
Published: November 2003

O‐Methylcaprolactim

product: O‐methylcaprolactim

product: O‐ethyl
Abietic Acid
Authors: Harris G. C. , Sanderson T. F.
Published: November 2003

Abietic acid

intermediate: isomerized rosin, 245 g. (0.72 mole)

product: abietic acid
2‐Aminobenzophenone
Authors: Scheifele H. J. , DeTar D. F.
Published: November 2003

2‐Aminobenzophenone

intermediate:
p
‐toluenesulfonylanthranilic acid

product: 2‐aminobenzophenone

byproduct: Phenyl
p
‐tolyl sulfone

product: 4′‐Methyl‐2‐aminobenzophenone
ε‐Aminocaproic Acid
Authors: Meyers Cal Y. , Miller Leonard E.
Published: November 2003

ε‐Aminocaproic acid

product: ε‐aminocaproic acid
tert
‐Butyl Hypochlorite
Authors: Teeter H. M. , Bell E. W.
Published: November 2003

tert
‐butyl hypochlorite

product:
tert
‐Butyl hypochlorite
Cyclohexene Sulfide
Authors: van Tamelen Eugene E.
Published: November 2003

Cyclohexene sulfide

product: cyclohexene sulfide

reactant: cyclohexene oxide
Diethyl Δ
2
‐Cyclopentenylmalonate
Authors: Moffett Robert Bruce
Published: November 2003

Diethyl Δ
2
‐cyclopentenylmalonate

product: Diethyl Δ
2
‐cyclopentenylmalonate
5,5‐Dimethyl‐2‐pyrrolidone
Authors: Moffett R. B.
Published: November 2003

5,5‐Dimethyl‐2‐pyrrolidone

product: 5,5‐dimethyl‐2‐pyrrolidone

solvent: petroleum ether
Methylglyoxal‐ω‐Phenylhydrazone
Authors: Reynolds George A. , VanAllan J. A.
Published: November 2003

Methylglyoxal‐ω‐phenylhydrazone

product: Methylglyoxal‐ω‐phenylhydrazone
Naphthalene‐1,5‐disulfonyl Chloride
Authors: Caesar P. D.
Published: November 2003

Naphthalene‐1,5‐disulfonyl chloride

product: naphthalene‐1,5‐disulfonyl chloride
Sodium Nitromalonaldehyde Monohydrate
Authors: Fanta Paul E.
Published: November 2003

Sodium Nitromalonaldehyde Monohydrate

product: sodium nitromalonaldehyde monohydrate
10‐Undecynoic Acid
Authors: Khan N. A.
Published: November 2003

10‐Undecynoic acid

solvent: petroleum ether

product: 10‐undecynoic acid
Benzoguanamine
Authors: Simons J. K. , Saxton M. R.
Published: November 2003

Benzoguanamine

product: Benzoguanamine
Creosol
Authors: Schwarz R. , Hering H.
Published: November 2003

Creosol

product: creosol
Furfural Diacetate
Authors: Bertz R. T.
Published: November 2003

Furfural diacetate

product: furfural diacetate
1,5‐Naphthalenedithiol
Authors: Caesar P. D.
Published: November 2003

1,5‐Naphthalenedithiol

product: 1,5‐naphthalenedithiol

product: phenoxybenzene‐4,4′‐dithiol

product:m‐sulfhydrylbenzoic acid
4‐Phenyl‐
m
‐Dioxane
Authors: Shriner R. L. , Ruby Philip R.
Published: November 2003

4‐Phenyl‐
m
‐dioxane

product: 4‐phenyl‐
m
‐dioxane
3‐Thenoic Acid
Authors: Campaigne E. , LeSuer William M.
Published: November 2003

3‐Thenoic acid

product: 3‐thenoic acid
Cetylmalonic Ester
Authors: Floyd Don E. , Miller Sidney E.
Published: November 2003

Cetylmalonic ester

reactant: 312 g. (1 mole) of ethyl stearate

product: cetylmalonic ester

product: Cetylmalonic acid
Hemimellitene
Authors: Brasen W. R. , Hauser C. R.
Published: November 2003

Hemimellitene

product: Hemimellitine
o
‐Methylbenzyl Alcohol
Authors: Brasen W. R. , Hauser C. R.
Published: November 2003

o
‐Methylbenzyl alcohol

intermediate:
o‐Methylbenzyl acetate

intermediate: 2‐methylbenzylethyldimethylammonium bromide

product:
o‐Methylbenzyl alcohol

intermediate: 2,3‐dimethylbenzyl acetate

product: 2,3‐dimethylbenzyl alcohol
2‐Methylbenzyldimethylamine
Authors: Brasen W. R. , Hauser C. R.
Published: November 2003

2‐Methylbenzyldimethylamine

intermediate: benzyltrimethylammonium iodide

product:
2‐Methylbenzyldimethylamine

product: 2,3‐dimethylbenzyldimethylamine
o
‐Phthalaldehyde
Authors: Bill J. C. , Tarbell D. S.
Published: November 2003

o
‐Phthalaldehyde

intermediate: α,α,α′,α′‐tetrabromo‐
o
‐xylene (344–370 g.)

product:
o
‐phthalaldehyde
Sodium β‐Styrenesulfonate and β‐Styrenesulfonyl Chloride
Authors: Rondestvedt Christian S. , Bordwell F. G.
Published: November 2003

Sodium β‐Styrenesulfonate and β‐Styrenesulfonyl Chloride

solvent: 800 ml. of ethylene chloride

reactant: dioxane

product: 95 + % pure sodium β‐styrenesulfonate

product: β‐styrenesulfonyl chloride

byproduct: 2,4‐diphenylbutane‐1,4‐sultone

byproduct: sodium 2‐phenyl‐2‐hydroxyethane‐1‐sulfonate
n
‐Butyl Glyoxylate
Authors: Wolf Frank J. , Weijlard John
Published: November 2003

n
‐butyl glyoxylate

reactant: 325 g. (1.24 moles) of di‐
n
‐butyl
d
‐tartrate

product:
n
‐butyl glyoxylate
Ethyl Isocyanide
Authors: Jackson H. L. , McKusick B. C.
Published: November 2003

Ethyl isocyanide

reactant: 530 g. (3.40 moles) of ethyl iodide

product: ethyl isocyanide
Ethyl N‐Phenylformimidate
Authors: Roberts Royston M. , Vogt Paul J.
Published: November 2003

Ethyl N‐phenylformimidate

intermediate: N,N′‐diphenylformamidine

product: Ethyl N‐phenylformimidate
2‐Furfuryl Mercaptan
Authors: Kofod Helmer
Published: November 2003

2‐Furfuryl mercaptan

product: 2‐furfuryl mercaptan
Hexamethylbenzene
Authors: Cullinane N. M. , Chard S. J. , Dawkins C. W. C.
Published: November 2003

Hexamethylbenzene

product: hexamethylbenzene
o‐Methoxyphenylacetone
Authors: Heinzelman R. V.
Published: November 2003

o‐Methoxyphenylacetone

intermediate:1‐(o‐Methoxyphenyl)‐2‐nitro‐1‐propene

product:o‐Methoxyphenylacetone.
trans
‐
o
‐Nitro‐α‐Phenylcinnamic Acid
Authors: DeTar DeLos F.
Published: November 2003

trans
‐
o
‐Nitro‐α‐phenylcinnamic acid

product:
trans
‐
o
‐Nitro‐α‐phenylcinnamic acid
2‐Phenylcycloheptanone
Authors: Gutsche C. David , Johnson Herbert E.
Published: November 2003

2‐Phenylcycloheptanone

intermediate: 360 g. (2.0 moles) of ethyl N‐benzylcarbamate

intermediate: 415 g. (2.0 moles) of ethyl N‐nitroso‐N‐benzylcarbamate

product: 2‐phenylcycloheptanone

solvent: petroleum ether

byproduct: methyl benzyl ether

product: 2‐(
o
‐Methylphenyl)cycloheptanone

product: 2‐(
p
‐Methylphenyl)cycloheptanone

product: 2‐(
o
‐Methoxyphenyl)cycloheptanone

product: 2‐(
m
‐Methoxyphenyl)cycloheptanone

product: 2‐(
p
‐Methoxyphenyl)cycloheptanone
p
‐Toluenesulfenyl Chloride
Authors: Kurzer Frederick , Powell J. Roy
Published: November 2003

p
‐Toluenesulfenyl chloride

product: (0.2 mole) of
p
‐toluenethiol
N,N‐Dimethylselenourea
Authors: Bennett Frank , Zingaro Ralph
Published: November 2003

N,N‐Dimethylselenourea

product: N,N‐Dimethylselenourea

reactant: 37 g. (0.5 mole) of dimethylcyanamide
D
‐Gulonic‐γ‐lactone
Authors: Karabinos J. V.
Published: November 2003

D
‐Gulonic‐γ‐lactone

product:
D
‐gulonic‐γ‐lactone
4‐Iodoveratrole
Authors: Janssen Donald E. , Wilson C. V.
Published: November 2003

4‐Iodoveratrole

reactant: silver trifluoroacetate

product: 4‐Iodoveratrole
Propiolaldehyde
Authors: Sauer J. C.
Published: November 2003

Propiolaldehyde

product: propiolaldehyde
2‐Pyrrolealdehyde
Authors: Silverstein Robert M. , Ryskiewicz Edward E. , Willard Constance
Published: November 2003

2‐Pyrrolealdehyde

product: 2‐pyrrolealdehyde

solvent: petroleum ether
Tetraethyltin
Authors: Van Der Kerk G. J. M. , Luijten J. G. A.
Published: November 2003

Tetraethyltin

product: tetraethyltin
Diaminouracil Hydrochloride
Authors: Sherman Wm. R. , Taylor E. C.
Published: November 2003

Diaminouracil hydrochloride

product: diaminouracil hydrochloride
Diethyl Benzoylmalonate
Authors: Price John A. , Tarbell D. S.
Published: November 2003

Diethyl benzoylmalonate

reactant: 20.2 g. (0.2 mole) of triethylamine

reactant: 21.7 g. (0.2 mole) of ethyl chlorocarbonate

product: Diethyl benzoylmalonate
3,4‐Dinitro‐3‐Hexene
Authors: Bisgrove D. E. , Brown J. F. , Clapp L. B.
Published: November 2003

3,4‐Dinitro‐3‐hexene

reactant: 247 g. (205 ml., 2.0 moles) of 1‐chloro‐1‐nitropropane

product: 3,4‐dinitro‐3‐hexene

byproduct: potassium 1‐nitropropylnitronate

product: 2,3‐Dinitro‐2‐butene
3‐
n
‐Heptyl‐5‐cyanocytosine
Authors: Kehm Barbara B. , Whitehead Calvert W.
Published: November 2003

3‐
n
‐Heptyl‐5‐cyanocytosine

intermediate: N‐
n
‐heptylurea

intermediate: 3‐
n
‐heptylureidomethylenemalononitrile

product: 3‐
n
‐heptyl‐5‐cyanocytosine
Parabanic Acid
Authors: Murray Joseph I.
Published: November 2003

Parabanic acid

product: parabanic acid
4‐Bromo‐2‐Heptene
Authors: Greenwood F. L. , Kellert M. D. , Sedlak J.
Published: November 2003

4‐bromo‐2‐heptene

byproduct: succinimide

product: 4‐bromo‐2‐heptene
6‐Ketohendecanedioic Acid
Authors: Durham Lois J. , McLeod Donald J. , Cason James
Published: November 2003

6‐Ketohendecanedioic acid

reactant: 89.3 g. (0.5 mole) of δ‐carbomethoxyvaleryl chloride

product: 6‐ketohendecanedioic acid

reactant: 100 g. (0.63 mole) of redistilled commercial methyl hydrogen adipate
trans
‐2‐Methyl‐2‐Dodecenoic Acid
Authors: Allen C. Freeman , Kalm Max J.
Published: November 2003

trans
‐2‐Methyl‐2‐dodecenoic acid

product: 2‐methyl‐2‐dodecenoic acid

solvent: Commercial hexane

product: 2‐methyl‐2‐eicosenoic acid

product: 2‐methyl‐2‐hexacosenoic acid

product: 2,4‐dimethyl‐2‐pentacosenoic acid
2‐Vinylthiophene
Authors: Emerson W. S. , Patrick T. M.
Published: November 2003

2‐Vinylthiophene

reactant: 336 g. (318 ml., 4.0 moles) of thiophene

product: 2‐vinylthiophene
Indole‐3‐Aldehyde
Authors: James Philip N. , Snyder H. R.
Published: November 2003

Indole‐3‐aldehyde

reactant: 288 ml. (274 g., 3.74 moles) of freshly distilled dimethylformamide

catalyst: 86 ml. (144 g., 0.94 mole) of freshly distilled phosphorus oxychloride

reactant: 100 g. (0.85 mole) of indole

product: indole‐3‐aldehyde
Methylenecyclohexane and N,N‐Dimethylhydroxylamine Hydrochloride
Authors: Cope Arthur C. , Ciganek Engelbert
Published: November 2003

Methylenecyclohexane and N,N‐dimethylhydroxylamine hydrochloride

reactant: 49.4 g. (0.35 mole) of N,N‐dimethylcyclohexylmethylamine

product: methylenecyclohexane

product: N,N‐dimethylhydroxylamine hydrochloride
β‐Methyl‐β‐phenylglutaric Acid
Authors: McElvain S. M. , Clemens David H.
Published: November 2003

β‐Methyl‐β‐phenylglutaric acid

product: β‐Methyl‐β‐phenylglutaric acid
Diethyl Acetamidomalonate
Authors: Zambito Arthur J. , Howe Eugene E.
Published: November 2003

Diethyl acetamidomalonate

product: diethyl acetamidomalonate
N,N‐Dimethylaminomethylferrocene Methiodide
Authors: Lednicer Daniel , Hauser Charles R.
Published: November 2003

N,N‐Dimethylaminomethylferrocene methiodide

reactant: 43.2 g. (0.422 mole) of bis(dimethylamino)‐methane

intermediate: dimethylaminomethylferrocene

product: N,N‐dimethylaminomethylferrocene methiodide
α,β‐Diphenylpropionic Acid
Authors: Hauser Charles R. , Dunnavant W. R.
Published: November 2003

α,β‐Diphenylpropionic acid

reactant: 14.2 g. (0.104 mole) of phenylacetic acid

reactant: 13.2 g. (0.104 mole) of benzyl chloride

product: α,β‐diphenylpropionic acid

solvent: 60 ml. of petroleum ether
Ferrocenylacetonitrile
Authors: Lednicer Daniel , Hauser Charles R.
Published: November 2003

Ferrocenylacetonitrile

product: ferrocenylacetonitrile
Hydroxyurea
Authors: Deghenghi R.
Published: November 2003

Hydroxyurea

product: hydroxyurea
Neopentyl Alcohol
Authors: Hoffman Joseph
Published: November 2003

Neopentyl alcohol

intermediate: neopentyl alcohol and water

product: neopentyl alcohol
α,α,α′,α′‐Tetramethyltetramethylene Glycol
Authors: Jenner E. L.
Published: November 2003

α,α,α′,α′‐Tetramethyltetramethylene glycol

product: α,α,α′,α′‐tetramethyltetramethylene glycol
α,α,α‐Trichloroacetanilide
Authors: Sukornick Bernard
Published: November 2003

α,α,α‐Trichloroacetanilide

product: α,α,α‐Trichloroacetanilide

reactant: 265 g. (1 mole) of hexachloroacetone
t
‐Butyl Cyanoacetate
Authors: Ireland Robert E. , Chaykovsky Michael
Published: November 2003

t
‐Butyl cyanoacetate

reactant: 296 g. (4 moles) of dry
t
‐butyl alcohol

product:
t
‐Butyl cyanoacetate
N,N‐Diethyl‐1,2,2‐trichlorovinylamine
Authors: Speziale A. J. , Freeman R. C.
Published: November 2003

N,N‐diethyl‐1,2,2‐trichlorovinylamine

intermediate: N,N‐Diethyl‐2,2,2‐trichloroacetamide

product: N,N‐diethyl‐1,2,2‐trichlorovinylamine

byproduct: tri‐
n
‐butylphosphine oxide

byproduct: phosphine oxide
Norcarane
Authors: Smith R. D. , Simmons H. E.
Published: November 2003

Norcarane

product: norcarane

reactant: 53.3 g. (0.65 mole) of cyclohexene

reactant: 190 g. (0.71 mole) of methylene iodide
Phenacylamine Hydrochloride
Authors: Baumgarten Henry E. , Petersen James M.
Published: November 2003

Phenacylamine Hydrochloride

byproduct: sodium chloride

product: phenacylamine hydrochloride

product: 2‐Aminocyclopentanone

product: 2‐Aminocyclohexanone

product: 3‐Amino‐2‐heptanone

product:p‐Bromophenacylamine

product:p‐Chlorophenacylamine

product:p‐Methoxyphenacylamine

product:p‐Nitrophenacylamine

product:p‐Methylphenacylamine

product:p‐Phenylphenacylamine

product: α‐Aminovalerophenone

product: 2‐Amino‐1‐tetralone

product: 2‐Amino‐4,4‐dimethyl‐1‐tetralone

product: Desylamine (2‐amino‐2‐phenylacetophenone)

product: Phenacylamine
N‐Phenylmaleimide
Authors: Cava M. P. , Deana A. A. , Muth K. , Mitchell M. J.
Published: November 2003

N‐Phenylmaleimide

intermediate:
Maleanilic acid

solvent: 500 ml. of petroleum ether

product: N‐phenylmaleimide
Ruthenocene
Authors: Bublitz D. E. , McEwen William E. , Kleinberg Jacob
Published: November 2003

Ruthenocene

product: ruthenocene
3β‐Acetoxyetienic Acid
Authors: Staunton J. , Eisenbraun E. J.
Published: November 2003

3β‐Acetoxyetienic acid

product: 3β‐hydroxyetienic acid
Adamantane
Authors: Schleyer Paul von R. , Donaldson M. M. , Nicholas R. D. , Cupas C.
Published: November 2003

Adamantane

reactant: 200 g. (1.51 moles) of purified dicyclopentadiene

intermediate:
endo
‐tetrahydrodicyclopentadiene

product: adamantane

solvent: 250 ml. of petroleum ether
Allene
Authors: Cripps H. N. , Kiefer E. F.
Published: November 2003

Allene

product: allene

byproduct: 2‐chloropropene
2‐Cyano‐6‐Methylpyridine
Authors: Feely Wayne E. , Evanega George , Beavers Ellington M.
Published: November 2003

2‐Cyano‐6‐methylpyridine

intermediate:
1‐Methoxy‐2‐methylpyridinium methyl sulfate
.

reactant: 109 g. (1.0 mole) of dry powdered 2‐picoline‐1‐oxide

product: 2‐cyano‐6‐methylpyridine

byproduct: 4‐cyano‐2‐methylpyridine

product: 2‐cyano‐4,6‐dimethylpyridine

product: 2‐cyanoquinoline

product: 1‐cyanoisoquinoline
2‐Cyclopentenone
Authors: DePuy Charles H. , Eilers K. L.
Published: November 2003

2‐Cyclopentenone

product: 2‐cyclopentenone
Hexahydrogallic Acid and Hexahydrogallic Acid Triacetate
Authors: Burgstahler Albert W. , Bithos Zoe J.
Published: November 2003

Hexahydrogallic acid and hexahydrogallic acid triacetate

solvent: 100 ml. of 30–40° petroleum ether

product: hexahydrogallic acid

product:
Hexahydrogallic acid triacetate
1‐Aminopyridinium Iodide
Authors: Gösl R. , Meuwsen A.
Published: November 2003

1‐Aminopyridinium iodide

product: 1‐aminopyridinium iodide

product: methylhydrazinium hydrogen sulfate

product: ethylhydrazinium hydrogen oxalate

product: butylhydrazinium hydrogen sulfate

product: 1‐aminopiperidinium hydrogen oxalate

product: 1,1‐dibutylhydrazinium hydrogen oxalate

product: 1,1,1‐trimethylhydrazinium hydrogen oxalate

product: 1‐amino‐2‐methylpyridinium iodide

product: 1‐amino‐2,4‐dimethylpyridinium iodide

product: 1‐amino‐2,6‐dimethylpyridinium iodide

product: 1‐amino‐2,4,6‐trimethylpyridinium iodide

product: 1‐aminoquinolinium iodide
Bromocyclopropane
Authors: Meek John S. , Osuga David T.
Published: November 2003

Bromocyclopropane

byproduct: carbon dioxide

product: bromocyclopropane
9‐Chloroanthracene
Authors: Nonhebel D. C.
Published: November 2003

9‐Chloroanthracene

product: 9‐chloroanthracene

solvent: petroleum ether

product: 1‐chloropyrene
α‐(N,N‐Dimethylamino)Phenylacetonitrile
Authors: Taylor Harold M. , Hauser Charles R.
Published: November 2003

α‐(N,N‐dimethylamino)phenylacetonitrile

product: α‐(N,N‐dimethylamino)phenylacetonitrile
2‐Mercaptopyrimidine
Authors: Crosby Donald G. , Berthold Robert V. , Johnson Herbert E.
Published: November 2003

2‐Mercaptopyrimidine

reactant: 176 g. (0.80 mole) of commercial‐grade 1,1,3,3‐tetraethyoxypropane

intermediate: 2‐mercaptopyrimidine hydrochloride

product: 2‐mercaptopyrimidine

product: 2‐mercaptopyrimidine bisulfate
Tropylium Fluoborate
Authors: Conrow Kenneth
Published: November 2003

Tropylium fluoborate

product: tropylium fluoborate
N‐(2‐Bromoallyl)Ethylamine
Authors: Bottini Albert T. , Olsen Robert E.
Published: November 2003

N‐(2‐bromoallyl)ethylamine

product: N‐(2‐bromoallyl)ethylamine
3‐Bromothiophene
Authors: Gronowitz S. , Raznikiewicz T.
Published: November 2003

3‐Bromothiophene

reactant: 1283 g. (4.00 moles) of 2,3,5‐tribromothiophene

product: 3‐bromothiophene

byproduct: 2‐bromothiophene
α,α‐Difluorotoluene and Benzenesulfinyl Fluoride
Authors: Sheppard William A.
Published: November 2003

α,α‐difluorotoluene and benzenesulfinyl fluoride

product: α,α‐difluorotoluene

product: benzenesulfinyl fluoride
1,3‐Dihydro‐3,5,7‐Trimethyl‐2H‐Azepin‐2‐One
Authors: Paquette Leo A.
Published: November 2003

1,3‐Dihydro‐3,5,7‐trimethyl‐2H‐azepin‐2‐one

byproduct: phenol

product: 1,3‐dihydro‐3,5,7‐trimethyl‐2H‐azepin‐2‐one
α,α‐Dimethyl‐β‐Phenethylamine
Authors: Ritter John J. , Kalish Joseph
Published: November 2003

α,α‐Dimethyl‐β‐phenethylamine

intermediate:
N‐Formyl‐α,α‐dimethyl‐β‐phenethylamine
.

product: α,α‐dimethyl‐β‐phenethylamine
α‐Ethyl‐α‐Methylsuccinic Acid
Authors: Prout F. S. , Aguilar V. N. , Girard F. H. , Lee D. D. , Shoffner J. P.
Published: November 2003

α‐Ethyl‐α‐methylsuccinic acid

product: α‐ethyl‐α‐methylsuccinic acid

product: ethyl 2,3‐dicyano‐3‐methylpentanoate
Mesitoic Acid
Authors: Sokol Phillip E.
Published: November 2003

Mesitoic acid

product: mesitoic acid
Pentachlorobenzoic Acid
Authors: Pearson D. E. , Cowan Dorotha
Published: November 2003

Pentachlorobenzoic acid

reactant: hexachlorobenzene (142.4 g., 0.5 mole

product: pentachlorobenzoic acid
4,6,8‐Trimethylazulene
Authors: Hafner K. , Kaiser H.
Published: November 2003

4,6,8‐Trimethylazulene

product: 4,6,8‐trimethylazulene

solvent: 400 ml. of petroleum ether
N‐Chlorocyclohexylideneimine
Authors: Alt G. H. , Knowles W. S.
Published: November 2003

N‐Chlorocyclohexylideneimine

product: N‐Chlorocyclohexylideneimine
p
‐Chlorophenyl Isothiocyanate
Authors: van der Kerk G. J. M. , Pluygers C. W. , de Vries G.
Published: November 2003

p
‐Chlorophenyl isothiocyanate

solvent: 200 ml. of petroleum ether

product:
p
‐chlorophenyl isothiocyanate

product: phenyl isothiocyanate

product:
p
‐phenylene diisothiocyanate

product:
p
‐acetylaminophenyl isothiocyanate

product:
p
‐ethoxyphenyl isothiocyanate

product:
p
‐bromophenyl isothiocyanate
Diethyl [O‐Benzoyl]ethyltartronate
Authors: Larsen E. H. , Lawesson S.‐O.
Published: November 2003

Diethyl [O‐benzoyl]ethyltartronate

product: diethyl [O‐benzoyl]ethyltartronate
N‐Mono‐ and N,N‐Disubstituted Ureas and Thioureas: Cyclohexylurea and 2,6‐Dimethylphenylthiourea
Authors: Neville Roy G. , McGee John J.
Published: November 2003

N‐mono‐ and N,N‐disubstituted ureas and thioureas: Cyclohexylurea and 2,6‐Dimethylphenylthiourea

product: cyclohexylurea

product: 2,6‐dimethylphenylthiourea

product: benzylurea

product: phenylurea

product:t‐butylurea

product: N‐(2‐benzothiazolyl)urea

product: dibenzylthiourea

product:t‐butylthiourea
Tetramethylbiphosphine Disulfide
Authors: Parshall G. W.
Published: November 2003

Tetramethylbiphosphine disulfide

reactant: 135 g. (83 ml., 0.80 mole) of thiophosphoryl chloride

product: tetramethylbiphosphine disulfide
1,1,3‐Trichloro‐
n
‐nonane
Authors: Vofsi D. , Asscher M.
Published: November 2003

1,1,3‐Trichloro‐
n
‐nonane

product: 1,1,3‐trichloro‐
n
‐nonane
2‐Acetamido‐3,4,6‐tri‐
O
‐acetyl‐2‐deoxy‐α‐
D
‐Glucopyranosyl Chloride
Authors: Horton Derek
Published: November 2003

2‐Acetamido‐3,4,6‐tri‐
O
‐acetyl‐2‐deoxy‐α‐
D
‐glucopyranosyl chloride

product: 2‐acetamido‐3,4,6‐tri‐
O
‐acetyl‐2‐deoxy‐α‐
D
‐glucopyranosyl chloride
2,2′‐Dichloro‐α,α′‐Epoxybibenzyl
Authors: Mark V.
Published: November 2003

2,2′‐Dichloro‐α,α′‐epoxybibenzyl

product: 2,2′‐Dichloro‐α,α′‐epoxybibenzyl

product: o‐Bromophenyl

product: m‐Bromophenyl

product: o‐Fluorophenyl

product: 3,4‐Dichlorophenyl

product: m‐Nitrophenyl

product: p‐Cyanophenyl

product: p‐Formylphenyl

product: 1‐Naphthyl

product: 2‐Thienyl

product: 2‐Pyridyl
3,4‐Dichloro‐1,2,3,4‐tetramethylcyclobutene
Authors: Criegee R.
Published: November 2003

3,4‐Dichloro‐1,2,3,4‐tetramethylcyclobutene

product: 3,4‐Dichloro‐1,2,3,4‐tetramethylcyclobutene
Hexaphenylbenzene
Authors: Fieser Louis F.
Published: November 2003

Hexaphenylbenzene

reactant: 8.0 g. of tetraphenylcyclopentadienone (0.021 mole)

reactant: 8.0 g. of diphenylacetylene (0.043 mole)

intermediate:
meso
‐Stilbene dibromide

product: Hexaphenylbenzene
3‐Hydroxyglutaronitrile
Authors: Johnson F. , Panella J. P.
Published: November 2003

3‐Hydroxyglutaronitrile

byproduct: 4‐chloro‐3‐hydroxybutyronitrile and 4‐hydroxycrotononitrile

product: 3‐Hydroxyglutaronitrile

product: 2‐amino‐6‐bromopyridine
Methyl Benzenesulfinate
Authors: Field Lamar , Locke J. Michael
Published: November 2003

Methyl benzenesulfinate

product: methyl benzenesulfinate
o
‐Nitrobenzaldehyde
Authors: Kalir A.
Published: November 2003

o
‐Nitrobenzaldehyde

intermediate:
o
‐nitrobenzylpyridinium bromide

intermediate: N‐(
p
‐dimethylaminophenyl)‐α‐(
o
‐nitrophenyl)nitrone

product:
o
‐nitrobenzaldehyde

product: fluoro‐o‐nitrobenzaldehydes

reactant: Fluoro‐2‐nitrobenzylpyridinium Bromide

intermediate: N‐(p‐dimethylaminophenyl)‐ α‐(fluoro‐o‐nitrophenyl)nitrone
Perchlorofulvalene
Authors: Mark V.
Published: November 2003

Perchlorofulvalene

reactant: 47.5 g. (0.100 mole) of decachlorobi‐2,4‐cyclopentadienyl

solvent: 200 ml. of petroleum ether

reactant: 25.2 g. (0.121 mole) of triisopropyl phosphite in 25 ml. of petroleum ether

product: perchlorofulvalene

reactant: diisopropyl hydrogen phosphite

reactant: triisopropyl phosphate
exo
‐
cis
‐Bicyclo[3.3.0]Octane‐2‐Carboxylic Acid
Authors: Dowbenko R.
Published: November 2003

exo
‐
cis
‐Bicyclo[3.3.0]octane‐2‐carboxylic acid

reactant: 325 g. (3.0 moles) of
cis,cis
‐1,5‐cyclooctadiene

solvent: 3 l. of chloroform

intermediate: 2‐(trichloromethyl)bicyclo[3.3.0]octane

product:
exo
‐
cis
‐bicyclo[3.3.0]octane‐2‐carboxylic acid
Cyclobutylamine
Authors: Werner Newton W. , Casanova Joseph
Published: November 2003

Cyclobutylamine

product: cyclobutylamine
1,3‐Cyclohexadiene
Authors: Schaefer John P. , Endres Leland
Published: November 2003

1,3‐Cyclohexadiene

product: 1,3‐cyclohexadiene
4‐Heptanone
Authors: Davis Robert , Granito Charles , Schultz Harry P.
Published: November 2003

4‐Heptanone

reactant: 370 ml. (4 moles) of
n
‐butyric acid

product: 4‐heptanone
Isophthalaldehyde
Authors: Ackerman J. H. , Surrey A. R.
Published: November 2003

Isophthalaldehyde

product: isophthalaldehyde
Unsolvated
n
‐Butylmagnesium Chloride
Authors: Bryce‐Smith D. , Blues E. T.
Published: November 2003

Unsolvated
n
‐butylmagnesium chloride

solvent: 60 ml. of methylcyclohexane

product:
n
‐butylmagnesium chloride

product:
n
‐butane

solvent: light petroleum
p
‐Bromodiphenylmethane
Authors: Galun A. B. , Kalir A.
Published: November 2003

p
‐Bromodiphenylmethane

intermediate: 1‐phenyl‐2,2,2‐trichloroethanol

intermediate: 146 g. (0.40 mole) of 1‐
p
‐bromophenyl‐1‐phenyl‐2,2,2‐trichloroethane

product:
p
‐Bromodiphenylmethane
t
‐Butyl carbamate
Authors: Loev Bernard , Kormendy Minerva F. , Goodman Marjorie M.
Published: November 2003

t
‐Butyl carbamate

product:
t
‐butyl carbamate
Phenylglyoxal
Authors: Mikol Gerard J. , Russell Glen A.
Published: November 2003

Phenylglyoxal

intermediate: phenylglyoxal hemimercaptal

product: phenylglyoxal

product: 2‐(methylsulfinyl)acetophenone
2,2,4‐Trimethyl‐3‐Oxovaleryl Chloride
Authors: Elam Edward U. , Gott P. Glenn , Hasek Robert H.
Published: November 2003

2,2,4‐Trimethyl‐3‐oxovaleryl chloride

product: 2,2,4‐trimethyl‐3‐oxovaleryl chloride
7‐Cyanoheptanal
Authors: Ohno Masaji , Naruse Norio , Terasawa Isao
Published: November 2003

7‐Cyanoheptanal

intermediate: 2‐chlorocyclooctanone oxime hydrochloride

intermediate: 2‐methoxycyclooctanone oxime

product: 7‐cyanoheptanal

byproduct: 2,4‐dinitrophenylhydrazone

solvent: methanol‐triethylamine
1,2‐Cyclononadiene
Authors: Skattebøl L. , Solomon S.
Published: November 2003

1,2‐Cyclononadiene

reactant:
cis
‐cyclooctene, 178 g. (214 ml., 1.62 moles)

intermediate: 9,9‐dibromobicyclo[6.1.0]nonane

product: 1,2‐cyclononadiene
trans
‐Cyclooctene
Authors: Cope Arthur C. , Bach Robert D.
Published: November 2003

trans
‐Cyclooctene

reactant: 155.3 g. (1 mole) of N,N‐dimethylcyclooctylamine

intermediate: 100 g. (0.34 mole) of N,N,N‐trimethylcyclooctylammonium iodide

byproduct:
cis
‐cyclooctene

product:
trans
‐cyclooctene
Arylbenzenes: 3,4‐Dichlorobiphenyl
Authors: Hey D. H. , Perkins M. J.
Published: November 2003

Arylbenzenes: 3,4‐dichlorobiphenyl

reactant: Thirty‐eight grams (0.1 mole) of bis‐3,4‐dichlorobenzoyl peroxide

byproduct: 3,4‐dichlorobenzoic acid

solvent: 100 ml. of petroleum ether

product: 3,4‐dichlorobiphenyl

byproduct: biphenyl
trans
‐4,4′‐Dimethoxystilbene
Authors: Findlay J. W. A. , Turner A. B.
Published: November 2003

trans
‐4,4′‐Dimethoxystilbene

byproduct: 2,3‐dichloro‐5,6‐dicyanohydroquinone

product:
trans
‐4,4′‐dimethoxystilbene
Methylenecyclohexane Oxide
Authors: Corey E. J. , Chaykovsky Michael
Published: November 2003

Methylenecyclohexane oxide

intermediate:
Dimethyloxosulfonium methylide

product:
Methylenecyclohexane oxide

solvent: Matheson, Coleman and Bell anhydrous dimethyl sulfoxide
Phenols: 6‐Methoxy‐2‐Naphthol
Authors: Kidwell R. L. , Murphy M. , Darling S. D.
Published: November 2003

Phenols: 6‐Methoxy‐2‐naphthol

reactant: 95 g., of 6‐bromo‐2‐methoxynaphthalene

product: 6‐methoxy‐2‐naphthol
R(+)‐ and S(−)‐α‐Phenylethylamine
Authors: Ault Addison
Published: November 2003

R(+)‐ and S(−)‐α‐phenylethylamine

product:
(S)‐(−)‐α‐Phenylethylamine

intermediate: (−)‐amine (+)‐hydrogen tartrate salt

product:
(R)‐
(+)‐α‐
Phenylethylamine

intermediate: (+)‐amine sulfate
Tetramethyl‐
p
‐phenylenediamine
Authors: Hünig S. , Quast H. , Brenninger W. , Frankenfield E.
Published: November 2003

Tetramethyl‐
p
‐phenylenediamine

reactant: 54 g. (0.5 mole) of powdered
p
‐phenylenediamine

reactant: 320 ml. (3.4 mole) of dimethyl sulfate

reactant: 100 ml. of ethanolamine

product: Tetramethyl‐
p
‐phenylenediamine
2,4,6‐Triphenylphenoxyl
Authors: Dimroth K. , Berndt A. , Perst H. , Reichardt C.
Published: November 2003

2,4,6‐Triphenylphenoxyl

intermediate: 2,4,6‐triphenylaniline

intermediate: 2,4,6‐triphenylphenol

product: 2,4,6‐triphenylphenoxyl
2,4,6‐Triphenylpyrylium Tetrafluoroborate
Authors: Dimroth K. , Reichardt C. , Vogel K.
Published: November 2003

2,4,6‐Triphenylpyrylium tetrafluoroborate

product: 2,4,6‐triphenylpyrylium tetrafluoroborate

reactant: 19 ml. (19 g., 0.95 mole) of anhydrous hydrofluoric acid

reactant: 126 ml. (142 g., 1.00 mole) of distilled boron trifluoride etherate