bluuebunny/crossref_metadata_2025 huggingface dataset:
Hot Spots for Protein Partnerships at the Surface of Cholinesterases and Related α/β Hydrolase Fold Proteins or Domains—A Structural Perspective
Authors: Bourne Yves , Marchot Pascale
Published: December 2017

The hydrolytic enzymes acetyl- and butyryl-cholinesterase, the cell adhesion molecules neuroligins, and the hormonogenic macromolecule thyroglobulin are a few of the many members of the α/β hydrolase fold superfamily of proteins. Despite their distinctive functions, their canonical subunits, with a molecular surface area of ~20,000 Å2, they share binding patches and determinants for forming homodimers and for accommodating structural subunits or protein partners. Several of these surface regions of high functional relevance have been mapped through structural or mutational studies, while others have been proposed based on biochemical data or molecular docking studies. Here, we review these binding interfaces and emphasize their specificity versus potentially multifunctional character.
DL_ANALYSER Notation for Atomic Interactions (DANAI): A Natural Annotation System for Molecular Interactions, Using Ethanoic Acid Liquid as a Test Case
Authors: Yong Chin , Todorov Ilian
Published: December 2017

The DL_ANALYSER Notation for Atomic Interactions, DANAI, is the notation syntax to describe interactions between molecules. This notation can annotate precisely the detailed atomistic interactions without having to resolve to diagrammatic illustrations, and yet can be interpreted easily by both human users and computational means. By making use of the DL_F Notation, a universal atom typing scheme for molecular simulations, DANAI contains the expression of atomic species in a natural chemical sense. It is implemented within DL_ANALYSER, a general analysis software program for DL_POLY molecular dynamics simulation software. By making references to the molecular dynamics simulations of pure ethanoic acid liquid, it is shown that DL_ANALYSER can identify and distinguish a variety of hydrogen bond and hydrophobic contact networks through the use of the DANAI expression. It was found that the carboxylic groups preferentially orientated in a “head-to-tail” conformation to form hydrogen bonds between the carbonyl oxygen and hydroxyl hydrogen, resulting in a series of linear structures that intertwined with pockets of methyl clusters.
Extracting Fitness Relationships and Oncogenic Patterns among Driver Genes in Cancer
Authors: Zhang Xindong , Gao Lin , Jia Songwei
Published: December 2017

Driver mutation provides fitness advantage to cancer cells, the accumulation of which increases the fitness of cancer cells and accelerates cancer progression. This work seeks to extract patterns accumulated by driver genes (“fitness relationships”) in tumorigenesis. We introduce a network-based method for extracting the fitness relationships of driver genes by modeling the network properties of the “fitness” of cancer cells. Colon adenocarcinoma (COAD) and skin cutaneous malignant melanoma (SKCM) are employed as case studies. Consistent results derived from different background networks suggest the reliability of the identified fitness relationships. Additionally co-occurrence analysis and pathway analysis reveal the functional significance of the fitness relationships with signaling transduction. In addition, a subset of driver genes called the “fitness core” is recognized for each case. Further analyses indicate the functional importance of the fitness core in carcinogenesis, and provide potential therapeutic opportunities in medicinal intervention. Fitness relationships characterize the functional continuity among driver genes in carcinogenesis, and suggest new insights in understanding the oncogenic mechanisms of cancers, as well as providing guiding information for medicinal intervention.
Design, Synthesis and Structure-Activity Relationship of Novel Aphicidal Mezzettiaside-Type Oligorhamnosides and Their Analogues
Authors: Zhao Hui , Wei Zhuwen , Jiang Zhiyan , Li Sumei , Liao Yixian , Guo Yiming , Tang Yongmei , Chen Weihao , Zhong Guohua , Song Gaopeng
Published: December 2017

Oligosaccharides have been used for an environmentally friendly insect control in the agricultural industry. In order to discover novel eco-friendly pesticides, a series of partially acetylated oligorhamnoses mezzettiasides, 2–8, and their analogues, 9–14, with biosurfactant characteristics were designed and synthesized, some of which exhibited comparable to or even stronger aphicidal activity than pymetrozine. Preliminary SAR studies demonstrated that the aphicidal activity of mezzettiasides analogs is highly dependent on their structures, including both the sugar length and the substitutes on the sugar. Among them, trirhamnolipid 9 displayed the strongest aphicidal activity, with an LC50 of 0.019 mmol/L, indicating that the biosurfactant 9 may have potential for use as an environmentally friendly agricultural pesticide.
Amine-Functionalized Sugarcane Bagasse: A Renewable Catalyst for Efficient Continuous Flow Knoevenagel Condensation Reaction at Room Temperature
Authors: Qiao Yanhui , Teng Junjiang , Wang Shuangfei , Ma Hao
Published: December 2017

A biomass-based catalyst with amine groups (–NH2), viz., amine-functionalized sugarcane bagasse (SCB-NH2), was prepared through the amination of sugarcane bagasse (SCB) in a two-step process. The physicochemical properties of the catalyst were characterized through FT-IR, elemental analysis, XRD, TG, and SEM-EDX techniques, which confirmed the –NH2 group was grafted onto SCB successfully. The catalytic performance of SCB-NH2 in Knoevenagel condensation reaction was tested in the batch and continuous flow reactions. Significantly, it was found that the catalytic performance of SCB-NH2 is better in flow system than that in batch system. Moreover, the SCB-NH2 presented an excellent catalytic activity and stability at the high flow rate. When the flow rate is at the 1.5 mL/min, no obvious deactivation was observed and the product yield and selectivity are more than 97% and 99% after 80 h of continuous reaction time, respectively. After the recovery of solvent from the resulting solution, a white solid was obtained as a target product. As a result, the SCB-NH2 is a promising catalyst for the synthesis of fine chemicals by Knoevenagel condensation reaction in large scale, and the modification of the renewable SCB with –NH2 group is a potential avenue for the preparation of amine-functionalized catalytic materials in industry.
Synthesis and Evaluation of Biological Activities of Aziridine Derivatives of Urea and Thiourea
Authors: Kowalczyk Aleksandra , Pieczonka Adam , Rachwalski Michał , Leśniak Stanisław , Stączek Paweł
Published: December 2017

In the present paper, we report the synthesis and evaluation of in vitro antimicrobial activities of aziridine-thiourea derivatives. A series of aziridines in reaction with isocyanates and isothiocyanates to obtain urea and thiourea derivatives were used. The structures of all new products were confirmed based on spectroscopic data (1H-NMR, 13C-NMR, HR-MS). These compounds were screened for their in vitro antimicrobial activity against a panel of Gram-positive and Gram-negative strains of bacteria. Six of the tested compounds appeared to be promising agents against reference strains of Escherichia coli, Staphylococcus aureus and Staphylococcus epidermidis. Subsequently, compounds exhibiting promising antibacterial activity were tested against twelve clinical isolates of S. aureus from three different sources of infection. The most bactericidal compounds (MIC = 16–32 µg/mL) showed better antibacterial activity against MRSA than ampicillin and streptomycin. The in vitro cytotoxicity analysis on L929 murine fibroblast and HeLa human tumor cell line using the MTT assay allowed us to select the least toxic compounds for future investigation.
Highly Efficient, Rapid, and Simultaneous Removal of Cationic Dyes from Aqueous Solution Using Monodispersed Mesoporous Silica Nanoparticles as the Adsorbent
Authors: Qin Peige , Yang Yixin , Zhang Xiaoting , Niu Jiahua , Yang Hui , Tian Shufang , Zhu Jinhua , Lu Minghua
Published: December 2017

In this work, a highly efficient and rapid method for simultaneously removing cationic dyes from aqueous solutions was developed by using monodispersed mesoporous silica nanoparticles (MSNs) as the adsorbents. The MSNs were prepared by a facile one-pot method and characterized by scanning electron microscopy, transmission electron microscopy, Fourier-transform infrared spectroscopy, and Brunauer-Emmett-Teller. Experimental results demonstrated that the as-prepared MSNs possessed a large specific surface area (about 585 m2/g), uniform particle size (about 30 nm), large pore volume (1.175 cm3/g), and narrow pore size distribution (1.68 nm). The materials showed highly efficient and rapid adsorption properties for cationic dyes including rhodamine B, methylene blue, methyl violet, malachite green, and basic fuchsin. Under the optimized conditions, the maximum adsorption capacities for the above mentioned cationic dyes were in the range of 14.70 mg/g to 34.23 mg/g, which could be achieved within 2 to 6 min. The probable adsorption mechanism of MSNs for adsorption of cationic dyes is proposed. It could be considered that the adsorption is mainly controlled by electrostatic interactions and hydrogen bonding between the cationic dyes and MSNs. As a low-cost, biocompatible, and environmentally friendly material, MSNs have a potential application in wastewater treatment for removing some environmental cationic contaminants.
Antibacterial, Antiproliferative, and Immunomodulatory Activity of Silver Nanoparticles Synthesized with Fucans from the Alga Dictyota mertensii
Authors: Fernandes-Negreiros Marília , Araújo Machado Raynara , Bezerra Fabiana , Nunes Melo Maria , Alves Monique , Alves Filgueira Luciana , Morgano Marcelo , Trindade Edvaldo , Costa Leandro , Rocha Hugo
Published: December 2017

In this study, we aimed to synthesize silver nanoparticles containing fucans from Dictyota mertensii (Martius) Kützing using an environmentally friendly method and to characterize their structure as well as antiproliferative, immunomodulatory, and antibacterial effects. Fucan-coated silver nanoparticles (FN) were characterized by Fourier-transform infrared analysis, dynamic light scattering, zeta potential, atomic force microscopy, energy dispersive X-ray spectroscopy, and inductively coupled plasma emission spectrometry. They were evaluated for their effect on cell viability, minimum inhibitory bactericidal concentration, and release of nitric oxide and cytokines. The FN were successfully synthesized using an environmentally friendly method. They were size-stable for 16 months, of a spherical shape, negative charge (−19.1 mV), and an average size of 103.3 ± 43 nm. They were able to inhibit the proliferation of the melanoma tumor cell line B16F10 (60%). In addition, they had immunomodulatory properties: they caused an up to 7000-fold increase in the release of nitric oxide and cytokines (IL-10; IL-6 and TNF-α) up to 7000 times. In addition, the FN showed inhibitory effect on Gram-positive and -negative bacteria, with MIC values of 50 µg/mL. Overall, the data showed that FN are nanoparticles with the potential to be used as antitumor, immunomodulatory, and antibacterial agents.
Report on Second International Conference on Natural Products for Cancer Prevention and Therapy Held in Kayseri, Turkey, 8–11 November 2017
Authors: Yerer Mükerrem , Bishayee Anupam
Published: December 2017

Scientific experts from eight countries gathered[...]
Nutrition and Liver Disease
Authors: Mandato Claudia , Di Nuzzi Antonella , Vajro Pietro
Published: December 2017

Malnutrition in children and adults with advanced liver disease represents a tremendous challenge as the nutritional problems are multifactorial. This Editorial comments the articles appearing in this special issue of Nutrients, “Nutrition and Liver disease” dealing with multiple diagnostic and therapeutic features that relate the outcomes of liver disease to nutrition. To improve quality of life and prevent nutrition-related medical complications, patients diagnosed with advanced liver disease should have their nutritional status promptly assessed and be supported by appropriate dietary interventions. Furthermore specific food supplements and/or restriction diets are often necessary for those with hepatic conditions associated with an underlying metabolic or nutritional or intestinal disease.
Is Skin Coloration Measured by Reflectance Spectroscopy Related to Intake of Nutrient-Dense Foods? A Cross-Sectional Evaluation in Australian Young Adults
Authors: Ashton Lee , Pezdirc Kristine , Hutchesson Melinda , Rollo Megan , Collins Clare
Published: December 2017

The current study examines associations between the dietary intakes of nutrient-dense foods, measured using brief indices and skin coloration, measured using reflectance spectroscopy in young adults. This is a cross-sectional analysis of 148 young Australian males and females (55% female) aged 18 to 25 years. Dietary intake was assessed using a validated food frequency questionnaire, with responses used to calculate two dietary indices: (i) the Australian Recommended Food Score (ARFS); and (ii) the Fruit And Vegetable VAriety Score (FAVVA). Skin yellowness was measured at three body locations using reflectance spectroscopy. Associations were assessed using Spearman’s correlation coefficients, regression analysis, and agreement using weighted kappa (Kw). Significant, moderate correlations were found between skin yellowness and diet index scores for the ARFS (ρ = 0.30, p < 0.001) and FAVVA score (ρ = 0.39, p < 0.001). These remained significant after adjustment for confounders (total fat intake, sex, skin lightness) and for agreement based on categorical rankings. Results suggest that measurement of skin coloration by reflectance spectroscopy can be used as an indicator of overall dietary quality and variety in young adults. Further exploration in diverse populations is required.
Small Intestinal Absorption of Methylsulfonylmethane (MSM) and Accumulation of the Sulfur Moiety in Selected Tissues of Mice
Authors: Wong Thomas , Bloomer Richard , Benjamin Rodney , Buddington Randal
Published: December 2017

The principal dietary sources of sulfur, the amino acids methionine and cysteine, may not always be consumed in adequate amounts to meet sulfur requirements. The naturally occurring organosulfur compound, methylsulfonylmethane (MSM), is available as a dietary supplement and has been associated with multiple health benefits. Absorption of MSM by the small intestine and accumulation of the associated sulfur moiety in selected tissues with chronic (8 days) administration were evaluated using juvenile male mice. Intestinal absorption was not saturated at 50 mmol, appeared passive and carrier-independent, with a high capacity (at least 2 g/d-mouse). The 35S associated with MSM did not increase in serum or tissue homogenates between days 2 and 8, indicating a stable equilibrium between intake and elimination was established. In contrast, proteins isolated from the preparations using gel electrophoresis revealed increasing incorporation of 35S in the protein fraction of serum, cellular elements of blood, liver, and small intestine but not skeletal muscle. The potential contributions of protein synthesis using labeled sulfur amino acids synthesized by the gut bacteria and posttranslational sulfation of proteins by incorporation of the labeled sulfate of MSM in 3′-phosphoadenosine 5′-phosphosulfate (PAPS) and subsequent transfer by sulfotransferases are discussed.
Dietary Fiber and Metabolic Syndrome: A Meta-Analysis and Review of Related Mechanisms
Authors: Chen Jia-Ping , Chen Guo-Chong , Wang Xiao-Ping , Qin Liqiang , Bai Yanjie
Published: December 2017

(1) Background: Dietary fiber intake may provide beneficial effects on the components of metabolic syndrome (MetS); however, observational studies reported inconsistent results for the relationship between dietary fiber intake and MetS risk. We conducted a meta-analysis to quantify previous observational studies and a narrative review to summarize mechanisms involved in the potential relationship. (2) Methods: The literature was searched on PubMed and Web of Science until 28 November 2017. A random-effects model was used to calculate the summary risk estimates. Eleven cross-sectional studies and three cohort studies were included in the meta-analysis. Results from the original studies were reported as odds ratios (ORs) or relative ratios (RRs) of the MetS associated with different levels of dietary fiber intake, and the ORs/RRs comparing the highest with lowest categories of the intake were pooled. (3) Results: For the cross-sectional studies, the pooled OR was 0.70 (95% confidence interval (CI): 0.61–0.82) with evidence of high heterogeneity (I2 = 74.4%, p < 0.001) and publication bias (p for Egger’s test < 0.001). After removing four studies, results remained significant (OR = 0.67, 95% CI: 0.58–0.78) and the heterogeneity was largely reduced (I2 = 32.4%, p = 0.181). For the cohort studies, the pooled RR was 0.86 (95% CI: 0.70–1.06). (4) Conclusion: Although the meta-analysis suggests an inverse association between dietary fiber intake and risk of MetS, and the association was supported by a wide range of mechanism studies, the findings are limited by insufficient cohort data. More prospective studies are needed to further verify the association between dietary fiber intake and the risk of MetS.
PqsA Promotes Pyoverdine Production via Biofilm Formation
Authors: Kang Donghoon , Turner Kelly , Kirienko Natalia
Published: December 2017

Biofilms create an impermeable barrier against antimicrobial treatment and immune cell access, severely complicating treatment and clearance of nosocomial Pseudomonas aeruginosa infections. We recently reported that biofilm also contributes to pathogen virulence by regulating the production of the siderophore pyoverdine. In this study, we investigated the role of PqsA, a key cell-signaling protein, in this regulatory pathway. We demonstrate that PqsA promotes pyoverdine production in a biofilm-dependent manner. Under nutritionally deficient conditions, where biofilm and pyoverdine are decoupled, PqsA is dispensable for pyoverdine production. Interestingly, although PqsA-dependent pyoverdine production does not rely upon Pseudomonas quinolone signal (PQS) biosynthesis, exogenous PQS can also trigger biofilm-independent production of pyoverdine. Adding PQS rapidly induced planktonic cell aggregation. Moreover, these clumps of cells exhibit strong expression of pyoverdine biosynthetic genes and show substantial production of this siderophore. Finally, we surveyed the relationship between biofilm formation and pyoverdine production in various clinical and environmental isolates of P. aeruginosa to evaluate the clinical significance of targeting biofilm during infections. Our findings implicate PqsA in P. aeruginosa virulence by regulating biofilm formation and pyoverdine production.
PLMA-b-POEGMA Amphiphilic Block Copolymers as Nanocarriers for the Encapsulation of Magnetic Nanoparticles and Indomethacin
Authors: Skandalis Athanasios , Sergides Andreas , Bakandritsos Aristides , Pispas Stergios
Published: December 2017

We report here on the utilization of poly(lauryl methacrylate)-b-poly(oligo ethylene glycol methacrylate) (PLMA-b-POEGMA) amphiphilic block copolymers, which form compound micelles in aqueous solutions, as nanocarriers for the encapsulation of either magnetic iron oxide nanoparticles or iron oxide nanoparticles, and the model hydrophobic drug indomethacin in the their hydrophobic core. The mixed nanostructures were characterized using dynamic light scattering (DLS) and transmission electron microscopy (TEM) in terms of their structure and solution properties. Magnetophoresis experiments showed that the mixed solutions maintain the magnetic properties of the initial iron oxide nanoparticles. Results indicate that the cumulative hydrophilic/hydrophobic balance of all components determines the colloidal stability of the nanosystems. The effect of salt and bovine serum albumin (BSA) protein concentration on the structure of the mixed nanostructures was also investigated. Disintegration of the mixed nanostructures was observed in both cases, showing the importance of these parameters in the structure formation and stability of such complex mixed nanosystems.
Preparation of Antibacterial Cellulose Paper Using Layer-by-Layer Assembly for Cooked Beef Preservation at Ambient Temperature
Authors: Li Hui , Cui Rongqi , Peng Lincai , Cai Shengbao , Li Pan , Lan Tianqing
Published: December 2017

Positively-charged ε-poly(l-lysine) (ε-PL) and negatively-charged carboxymethyl cellulose (CMC) were alternately deposited on a cellulose paper surface by the layer-by-layer (LBL) assembly technique. The formation of ε-PL/CMC multilayers was confirmed by X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectra (FTIR), and zeta potential measurement. The morphologies of the multilayer-modified cellulose paper were observed by scanning electron microscopy (SEM). The ε-PL/CMC multilayers effectively improved not only the antibacterial activity of cellulose paper against both Escherichia coli and Staphylococcus aureus, but also the cellulose paper tensile strength property. Cellulose paper modified with a (ε-PL/CMC)4.5 multilayer exhibited the strongest antibacterial activity, selected for preserving cooked beef for nine days at ambient temperature, could extend the shelf-life of beef for about three days compared with common commercial PE films. The prepared antibacterial paper did not show any evidence of the cytotoxic effect since it could not increase the cytoplasmic lactate dehydrogenase release from L-929 fibroblast cells in contact with the antibacterial paper, suggesting the possibility of utilization in food packaging field.
New Development of Membrane Base Optoelectronic Devices
Authors: Hamui Leon , Sánchez-Vergara María , Sánchez-Ruiz Rocío , Ruanova-Ferreiro Diego , Ballinas Indili Ricardo , Álvarez-Toledano Cecilio
Published: December 2017

It is known that one factor that affects the operation of optoelectronic devices is the effective protection of the semiconductor materials against environmental conditions. The permeation of atmospheric oxygen and water molecules into the device structure induces degradation of the electrodes and the semiconductor. As a result, in this communication we report the fabrication of semiconductor membranes consisting of Magnesium Phthalocyanine-allene (MgPc-allene) particles dispersed in Nylon 11 films. These membranes combine polymer properties with organic semiconductors properties and also provide a barrier effect for the atmospheric gas molecules. They were prepared by high vacuum evaporation and followed by thermal relaxation technique. For the characterization of the obtained membranes, Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS) were used to determine the chemical and microstructural properties. UV-ViS, null ellipsometry, and visible photoluminescence (PL) at room temperature were used to characterize the optoelectronic properties. These results were compared with those obtained for the organic semiconductors: MgPc-allene thin films. Additionally, semiconductor membranes devices have been prepared, and a study of the device electronic transport properties was conducted by measuring electrical current density-voltage (J-V) characteristics by four point probes with different wavelengths. The resistance properties against different environmental molecules are enhanced, maintaining their semiconductor functionality that makes them candidates for optoelectronic applications.
Improving Kinetics of “Click-Crosslinking” for Self-Healing Nanocomposites by Graphene-Supported Cu-Nanoparticles
Authors: Kargarfard Neda , Diedrich Norman , Rupp Harald , Döhler Diana , Binder Wolfgang
Published: December 2017

Investigation of the curing kinetics of crosslinking reactions and the development of optimized catalyst systems is of importance for the preparation of self-healing nanocomposites, able to significantly extend their service lifetimes. Here we study different modified low molecular weight multivalent azides for a capsule-based self-healing approach, where self-healing is mediated by graphene-supported copper-nanoparticles, able to trigger “click”-based crosslinking of trivalent azides and alkynes. When monitoring the reaction kinetics of the curing reaction via reactive dynamic scanning calorimetry (DSC), it was found that the “click-crosslinking” reactivity decreased with increasing chain length of the according azide. Additionally, we could show a remarkable “click” reactivity already at 0 °C, highlighting the potential of click-based self-healing approaches. Furthermore, we varied the reaction temperature during the preparation of our tailor-made graphene-based copper(I) catalyst to further optimize its catalytic activity. With the most active catalyst prepared at 700 °C and the optimized set-up of reactants on hand, we prepared capsule-based self-healing epoxy nanocomposites.
Antibacterial Films Made of Ionic Complexes of Poly(γ-glutamic acid) and Ethyl Lauroyl Arginate
Authors: Gamarra-Montes Ana , Missagia Beatriz , Morató Jordi , Muñoz-Guerra Sebastián
Published: December 2017

The biocide agent LAE (ethyl αN-lauroyl l-arginate chloride) was coupled with poly(γ-glutamic acid) (PGGA) to form stable ionic complexes with LAE:PGGA ratios of 1 and 0.5. The nanostructure adopted by these complexes and its response to thermal changes were examined in detail by Differential scanning calorimetry (DSC) and X-ray diffraction (XRD) using synchrotron radiation in real time. A layered biphasic structure with LAE filling the space between the polypeptidic sheets was adopted in these complexes. The complexes were stable up to above 250 °C, non-water soluble, and were able to form consistent transparent films. The release of LAE from the complexes upon incubation in aqueous buffer was examined and found to depend on both pH and complex composition. The antibacterial activity of films made of these complexes against Gram-positive (L. monocytogenes and S. aureus) and Gram-negative (E. coli and S. enterica) bacteria was preliminary evaluated and was found to be very high against the formers and only moderate against the later. The bactericide activity displayed by the LAE·PGGA complexes was directly related with the amount of LAE that was released from the film to the environment.
Melamine–Glyoxal–Glutaraldehyde Wood Panel Adhesives without Formaldehyde
Authors: Xi Xuedong , Pizzi Antonio , Amirou Siham
Published: December 2017

(MGG’) resin adhesives for bonding wood panels were prepared by a single step procedure, namely reacting melamine with glyoxal and simultaneously with a much smaller proportion of glutaraldehyde. No formaldehyde was used. The inherent slow hardening of this resin was overcome by the addition of N-methyl-2-pyrrolidone hydrogen sulphate ionic liquid as the adhesive hardener in the glue mix. The plywood strength results obtained were comparable with those obtained with melamine–formaldehyde resins pressed under the same conditions. Matrix assisted laser desorption ionisation time of flight (MALDI ToF) and Fourier transform Infrared (FTIR) analysis allowed the identification of the main oligomer species obtained and of the different types of linkages formed, as well as to indicate the multifaceted role of the ionic liquid. These resins are proposed as a suitable substitute for equivalent formaldehyde-based resins.
Effects of Fluoro Substitution on the Electrochromic Performance of Alternating Benzotriazole and Benzothiadiazole-Based Donor–Acceptor Type Copolymers
Authors: Zhang Yan , Kong Lingqian , Ju Xiuping , Zhao Jinsheng
Published: December 2017

Two new donor–acceptor type electrochromic copolymers containing non-fluorinated and di-fluorinated benzothiadiazole analogues, namely P(TBT-TBTh) and P(TBT-F-TBTh), were synthesized successfully through chemical polymerization. Both polymers were measured by cyclic voltammetry, UV-vis spectroscopy, colorimetry and thermogravimetric analysis to study the influence of fluoro substitution on the electrochromic performance. The results demonstrated that the two polymer films displayed well-defined redox peaks in pairs during the p-type doping, and showed distinct color change from dark gray blue to light green for P(TBT-TBTh) with the band gap of 1.51 eV, and from gray blue to celandine green for P(TBT-F-TBTh) with the band gap of 1.58 eV. P(TBT-F-TBTh) presented lower highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energy levels, and better stability than P(TBT-TBTh). It was found that the two fluorine atoms participated in not only inductive effects but also mesomeric effects in the P(TBT-F-TBTh) backbone. In addition, the polymers exhibited high optical contrasts, short response time, and favorable coloration efficiency, especially in the near infrared region. The characterization results indicated that the two reported polymers can be the potential choice as electrochromic materials.
A Facial Strategy for Catalyst and Reducing Agent Synchronous Separation for AGET ATRP Using Thiol-Grafted Cellulose Paper as Reducing Agent
Authors: Jiang Xiaowu , Han Jie , Cao Lunan , Bao Yan , Shi Jian , Zhang Jing , Ni Lingli , Chen Jing
Published: December 2017

Atom Transfer Radical Polymerization (ATRP) has been a powerful tool to synthesize well-defined functional polymers, which are widely used in biology, drug/gene delivery and antibacterial materials, etc. However, the potential toxic residues in polymer reduced its service life and limited its applications. In order to overcome the problem, in this work, a novel polymerization system of activators generated by electron transfer for atom transfer radical polymerization (AGET ATRP) for synchronous separation of the metal catalyst and byproduct of reducing agent was developed, using thiol-grafted cellulose paper (Cell-SH) as a solid reducing agent. The polymerization kinetics were investigated in detail, and the “living” features of the novel polymerization system were confirmed by chain-end analysis and chain extension experiment for the resultant polymethyl methacrylate (PMMA). It is noted that the copper residual in obtained PMMA was less than 20 ppm, just by filtering the sheet-like byproduct of the reducing agent.
High-Tg, Low-Dielectric Epoxy Thermosets Derived from Methacrylate-Containing Polyimides
Authors: Chen Chien-Han , Lee Kuan-Wei , Lin Ching-Hsuan , Ho Ming-Jaan , Hsu Mao-Feng , Hsiang Shou-Jui , Huang Nan-Kun , Juang Tzong-Yuan
Published: December 2017

Three methacrylate-containing polyimides (Px–MMA; x = 1–3) were prepared from the esterification of hydroxyl-containing polyimides (Px–OH; x = 1–3) with methacrylic anhydride. Px–MMA exhibits active ester linkages (Ph–O–C(=O)–) that can react with epoxy in the presence of 4-dimethylaminopyridine (DMAP), so Px–MMA acted as a curing agent for a dicyclopentadiene-phenol epoxy (HP7200) to prepare epoxy thermosets (Px–MMA/HP7200; x = 1–3) thermosets. For property comparisons, P1–OH/HP7200 thermosets were also prepared. The reaction between active ester and epoxy results in an ester linkage, which is less polar than secondary alcohol resulting from the reaction between phenolic OH and epoxy, so P1–MMA/HP7200 are more hydrophobic and exhibit better dielectric properties than P1–OH/HP7200. The double bond of methacrylate can cure at higher temperatures, leading to epoxy thermosets with a high-Tg and moderate-to-low dielectric properties.
Actualizing Unique Type and Token Values as a Solution to the Problem of Evil
Authors: Søvik Atle
Published: December 2017

Concerning the problem of evil, I suggest that God's goodness and omnipotence causes God to want to actualize many different values and things, not solely angels in heaven, but also type unique values like independence, self-formation, creativity, and surprise, and token unique goods like animals and human beings. Such a universe as ours, though, requires undisturbed indeterministic self-formation as actualized by a good God to give those token unique beings access to those type unique values and allow them the opportunity to live forever with God after completion of this self-formation.
The Effect of Materialistic Value-Orientation on Religiosity in Bangladesh: An Empirical Investigation
Authors: Masoom Muhammad Rehan , Sarker Md Moniruzzaman
Published: December 2017

The rising middle-class of the developing nations is found to be emphasizing more on the acquisition of goods and property in the pursuit of the good life. This often leads towards the materialistic value-orientation and form materialism. Religiosity, conversely, implies restraining from the earthy pleasure in the form of happy life, and often imposes prohibitory behavioral rules in the economic sphere. Hence, ‘Materialism’ and ‘Religiosity’ are two of the most incompatible yet dominant components of normative value-systems that are always in contention with each other. Literature is abundant to relate ‘Emotional Connection’, ‘Subjective Well-Being’, ‘Happiness’ or ‘Life Satisfaction’ with that of ‘Materialism’ and ‘Religiosity’; nonetheless, what is hardly addressed is the effect of materialistic value-orientation to the religiosity in the transitional societies. This paper investigates materialism and religiosity in the developing economy context like Bangladesh and outlines the underlying relationships between the constructs. A survey on a sample of four hundred and twelve (412) respondents using self-administered questionnaires is the source of quantitative information that is used to formulate the tentative explanations of the variables of interest. Age is considered as a moderator. A negative relationship between the level of materialism and religiosity is found, if materialism is considered as a reflective construct, and religiosity is treated as a second-order formative construct in the structural equation modeling.
Automated Sensing of Wave Inundation across a Rocky Shore Platform Using a Low-Cost Camera System
Authors: Power Hannah , Kinsela Michael , Stringari Caio , Kendall Murray , Morris Bradley , Hanslow David
Published: December 2017

Rocky coastlines are frequently used for recreation, however, they are often highly exposed and hazardous environments resulting in high risk to visitors. Traditional approaches to managing human safety in coastal settings (such as the surf lifesaving clubs that have proven effective on beaches) are not necessarily transferable to rock platforms due to their often remote and fragmented distribution and the different recreational uses. As such, a different approach is required. To address this, we present a low-cost camera system to assess the wave hazard on a high-visitation rocky shore platform: the Figure Eight Pools Rock Platform, New South Wales, Australia. The camera system is shown to be highly effective and allows identification of both the distance and frequency of wave inundation on the platform using a novel pixel analysis technique. Nearshore wave height is shown to be the primary factor driving inundation frequencies along the cross-platform transect investigated with some influence from wave period. The remotely sensed camera data are used to develop a preliminary overwash hazard rating system, and analysis of the first month of data collected suggests that the platform is highly hazardous to visitors. Future work will expand this hazard rating system, developing a predictive tool that estimates the overwash hazard level based on forecast wave and tide conditions to improve visitor safety at the site.
An Approach to Improve the Positioning Performance of GPS/INS/UWB Integrated System with Two-Step Filter
Authors: Li Zengke , Wang Ren , Gao Jingxiang , Wang Jian
Published: December 2017

The integration of Inertial Navigation System (INS) and Global Positioning System (GPS) single-point-positioning (SPP) mode cannot meet the requirements of high-accuracy navigation. Range observation through ultra-wideband (UWB) is an effective means to enhance the reliability and accuracy of GPS/INS integrated navigation, particularly in environments where GPS availability is poor. Because it is difficult for UWB signal to achieve large-scale intervention coverage, an enhanced GPS/INS/UWB integrated scheme with positioning error correction is proposed to improve the position accuracy in the UWB signal outage scenario. The position difference between the GPS/INS integrated solution and the GPS/INS/UWB integrated solution is predicated as the error correction for GPS/INS/UWB integrated navigation in a UWB signal challenging environment. Position correction information in the north and east directions is input to the two-step filter to decrease the error of GPS/INS integrated navigation in single-point-positioning. In order to validate the proposed method, a real experiment is conducted. The results indicate that the enhanced GPS/INS/UWB integrated scheme with positioning error correction is able to improve the position accuracy of GPS/INS/UWB integrated navigation when UWB signal is unavailable.
Addendum: Using Satellite Data for the Characterization of Local Animal Reservoir Populations of Hantaan Virus on the Weihe Plain, China. Remote Sens. 2017, 9, 1076
Authors: Yu Pengbo , Li Yidan , Xu Bo , Wei Jing , Li Shen , Dong Jianhua , Qu Jianhui , Xu Jing , Huang Zheng , Ma Chaofeng , Yang Jing , Zhang Guogang , Chen Bin , Huang Shanqian , Shi Chunming , Gao Hongwei , Liu Feng , Tian Huaiyu , Stenseth Nils , Xu Bing , Wang Jingjun
Published: December 2017

After publication of the research paper[...]
The VIS/NIR Land and Snow BRDF Atlas for RTTOV: Comparison between MODIS MCD43C1 C5 and C6
Authors: Vidot Jérôme , Brunel Pascal , Dumont Marie , Carmagnola Carlo , Hocking James
Published: December 2017

A monthly mean land and snow Bidirectional Reflectance Distribution Function (BRDF) atlas for visible and near infrared parts of the spectrum has been developed for Radiative Transfer for Television Infrared Observation Satellite (TIROS) Operational Vertical sounder (TOVS) (RTTOV). The atlas follows the methodology of the RTTOV University of Wisconsin infrared land surface emissivity (UWIREMIS) atlas, i.e., it combines satellite retrievals and a principal component analysis on a dataset of hyper-spectral surface hemispherical reflectance or albedo. The current version of the BRDF atlas is based on the Collection 5 of the Moderate Resolution Imaging (MODIS) MCD43C1 Climate Modeling Grid BRDF kernel-driven model parameters product. The MCD43C1 product combines both Terra and Aqua satellites over a 16-day period of acquisition and is provided globally at 0.05° of spatial resolution. We have improved the RTTOV land surface BRDF atlas by using the last Collection 6 of MODIS product MCD43C1. We firstly found that the MODIS C6 product improved the quality index of the BRDF model as compared with that of C5. When compared with clear-sky top of atmosphere (TOA) reflectance of Spinning Enhanced Visible and InfraRed Imagers (SEVIRI) solar channels over snow-free land surfaces, we showed that the reflectances are simulated with an absolute accuracy of 3% to 5% (i.e., 0.03–0.05 in reflectance units) when either the satellite zenith angle or the solar zenith angle is below 70°, regardless of the MODIS collection. For snow-covered surfaces, we showed that the comparison with in situ snow spectral albedo is improved with C6 with an underestimation of 0.05 in the near infrared.
Application of Coupled-Wave Wentzel-Kramers-Brillouin Approximation to Ground Penetrating Radar
Authors: Prokopovich Igor , Popov Alexei , Pajewski Lara , Marciniak Marian
Published: December 2017

This paper deals with bistatic subsurface probing of a horizontally layered dielectric half-space by means of ultra-wideband electromagnetic waves. In particular, the main objective of this work is to present a new method for the solution of the two-dimensional back-scattering problem arising when a pulsed electromagnetic signal impinges on a non-uniform dielectric half-space; this scenario is of interest for ground penetrating radar (GPR) applications. For the analytical description of the signal generated by the interaction of the emitted pulse with the environment, we developed and implemented a novel time-domain version of the coupled-wave Wentzel-Kramers-Brillouin approximation. We compared our solution with finite-difference time-domain (FDTD) results, achieving a very good agreement. We then applied the proposed technique to two case studies: in particular, our method was employed for the post-processing of experimental radargrams collected on Lake Chebarkul, in Russia, and for the simulation of GPR probing of the Moon surface, to detect smooth gradients of the dielectric permittivity in lunar regolith. The main conclusions resulting from our study are that our semi-analytical method is accurate, radically accelerates calculations compared to simpler mathematical formulations with a mostly numerical nature (such as the FDTD technique), and can be effectively used to aid the interpretation of GPR data. The method is capable to correctly predict the protracted return signals originated by smooth transition layers of the subsurface dielectric medium. The accuracy and numerical efficiency of our computational approach make promising its further development.
Assessing Different Feature Sets’ Effects on Land Cover Classification in Complex Surface-Mined Landscapes by ZiYuan-3 Satellite Imagery
Authors: Chen Weitao , Li Xianju , He Haixia , Wang Lizhe
Published: December 2017

Land cover classification (LCC) in complex surface-mined landscapes has become very important for understanding the influence of mining activities on the regional geo-environment. There are three characteristics of complex surface-mined areas limiting LCC: significant three-dimensional terrain, strong temporal-spatial variability of surface cover, and spectral-spatial homogeneity. Thus, determining effective feature sets are very important as input dataset to improve detailed extent of classification schemes and classification accuracy. In this study, data such as various feature sets derived from ZiYuan-3 stereo satellite imagery, a feature subset resulting from a feature selection (FS) procedure, training data polygons, and test sample sets were firstly obtained; then, feature sets’ effects on classification accuracy was assessed based on different feature set combination schemes, a FS procedure, and random forest algorithm. The following conclusions were drawn. (1) The importance of feature set could be divided into three grades: the vegetation index (VI), principal component bands (PCs), mean filters (Mean), standard deviation filters (StDev), texture measures (Textures), and topographic variables (TVs) were important; the Gaussian low-pass filters (GLP) was just positive; and none were useless. The descending order of their importance was TVs, StDev, Textures, Mean, PCs, VI, and GLP. (2) TVs and StDev both significantly outperformed VI, PCs, GLP, and Mean; Mean outperformed GLP; all other pairs of feature sets had no difference. In general, the study assessed different feature sets’ effects on LCC in complex surface-mined landscapes.
Prediction of Soil Organic Matter by VIS–NIR Spectroscopy Using Normalized Soil Moisture Index as a Proxy of Soil Moisture
Authors: Hong Yongsheng , Yu Lei , Chen Yiyun , Liu Yanfang , Liu Yaolin , Liu Yi , Cheng Hang
Published: December 2017

Soil organic matter (SOM) is an important parameter of soil fertility, and visible and near-infrared (VIS–NIR) spectroscopy combined with multivariate modeling techniques have provided new possibilities to estimate SOM. However, the spectral signal is strongly influenced by soil moisture (SM) in the field. Interest in using spectral classification to predict soils in the moist conditions to minimize the influence of SM is growing. The objective of this study was to investigate the transferability of two approaches, SM–based cluster method with known SM (classifying the VIS–NIR spectra into different SM clusters to develop models separately), the normalized soil moisture index (NSMI)–based cluster method with unknown SM (utilizing NSMI to indicate the SM and establish models separately), to predict SOM directly in moist soil spectra. One hundred and twenty one soil samples were collected from Central China, and eight SM levels were obtained for each sample through rewetting experiments. Their reflectance spectra and SOM concentrations were measured in the laboratory. Partial least square-support vector machine (PLS-SVM) was employed to construct SOM prediction models. Specifically, prediction models were developed for NSMI–based clusters with unknown SM data. The models were assessed through three statistics in the processes of calibration and validation: the coefficient of determination (R2), root mean square error (RMSE) and the ratio of the performance to deviation (RPD). Results showed that the variable SM led to reduced VIS–NIR reflectance nonlinearly across the entire spectral range. NSMI was an effective spectral index to indicate the SM. Classifying the VIS–NIR spectra into different SM clusters in known SM states could improve the performance of PLS-SVM models to acceptable prediction accuracies (R2cv = 0.69–0.77, RPD = 1.79–2.08). The estimation of SOM, when using the NSMI–based cluster method with unknown SM (RPD = 1.95–2.04), was similar to the use of the SM–based cluster method with known SM (RPD = 1.79–2.08). The predictive results (RPD = 1.87–2.06) demonstrated that the NSMI-–based cluster method has potential for application outside the laboratory for SOM prediction without knowing the SM explicitly, and this method is also easy to carry out and only requires spectral information.
Vertical Accuracy Simulation of Stereo Mapping Using a Small Matrix Charge-Coupled Device
Authors: Guan Zhichao , Jiang Yonghua , Zhang Guo
Published: December 2017

At present, without ground control points (GCPs), the positioning accuracy of remote sensing images often fails to meet the growing requirements for mapping accuracy. Multi-load synergy to improve accuracy without GCPs by eliminating the impact of stereo accuracy, which is caused by on-orbit measurement error, is urgently needed to improve large-scale mapping. In this study, we analyzed error sources in stereo imaging mode and found that vertical accuracy depends on the relative accuracy of attitude during symmetric stereoscopic mapping. With the assistance of small matrix charge-coupled device (CCD) images and the block adjustment method, relative accuracy of attitude was improved, allowing for the improvement in vertical accuracy without GCPs. The simulation results show that vertical accuracy in symmetric stereo mode is not affected by attitude system error. After the restoration of imaging attitude processed by a sequence of matrix CCD images, the relative accuracy of the attitude increased, and the accuracy of the elevation without GCPs improved significantly. The results demonstrate the feasibility of small matrix CCD-assisted stereo mapping.