bluuebunny/crossref_metadata_2025 huggingface dataset:
On the need to build an alternative financial system
Authors: KUZNETSOV Sergei A. , OGNYANOVICH Aleksandr V. , KUZNETSOV Sergei S. , BLAGOVESHCHENSKAYA Elizaveta D.
Published: August 2023

Subject. The article underpins of the need to build a national financial system which will fully guarantee addressing socio-economic problems.
Objectives. The purpose is to create fundamental institutions for development of national concepts of economic and financial models, pricing methodologies, approaches designed to build a State model of a socially oriented economy that guarantees the functioning of all branches of financial and economic activity, and military, economic, and other types of national integrated security.
Methods. The paper uses tensor notation involving the use of elements of linear algebra, including operations with matrices and vectors, interval mathematics, and a set of methods and principles of scientific research and complex logical analysis and modeling of product and financial flows.
Results. We show the possibility of obtaining the country's resources for free when creating a shortage of means of payment under implementation of the basic principle of a market economy, i.e. free pricing. The paper offers financial and economic models of the main participants of financial and economic activity: legal entities, individuals, and State-owned enterprises and organizations. On their basis, we demonstrate closed cycles of money circulation, which formed the basis for building a national financial model. We propose to construct financial models using interval analysis, which correlates with the specifics of measured parameters in the financial and economic sphere.
Conclusions. The suggested approach is confirmed by the results of trial calculations. It has practical significance not only for the Russian economy, but can also be used in other countries.
TOXOPLASMOSE CONGÊNITA: PESPECTIVA DE PUÉRPERAS ATENDIDAS NO HOSPITAL UNIVERSITÁRIO SÃO FRANCISCO DE ASSIS – BRAGANÇA PAULISTA
Authors: Vanalli Lima Baptista Thayz
Published: August 2023

A toxoplasmose é uma doença causada pelo Toxoplasma gondii, que envolve sequelas graves. No Brasil, é considerada uma doença prevalente, porém, as políticas públicas, não são obrigatórias, aplicadas de formas diferentes em cada região do país. Ainda hoje, muitas gestantes não realizam o pré-natal adequadamente e se infectadas, a transmissão ao feto pode ocorrer sem identificação, gerando um diagnóstico tardio, afetando o tratamento medicamentoso do recém-nascido e agravo das sequelas. Este estudo objetivou sensibilizar as puérperas que não realizaram um pré-natal adequado, a entenderem a importância do tratamento da doença para a mesma e seu filho, além de praticarem estratégias eficazes para prevenção da contaminação. O estudo foi realizado no Hospital Universitário São Francisco de Assis, reuniu 25 participantes, que responderam um questionário contendo perguntas abertas e fechadas direcionado à prevenção, tratamento e transmissão da doença. Os resultados da pesquisa foram expostos de modo descritivo. Ao analisar o grau de conhecimento das entrevistadas constatou-se que 72% não conheciam a doença e 88% não receberam qualquer orientação profissional sobre as peculiaridades da mesma. Quando questionadas sobre as complicações que podem ocorrer com a transmissão, 12% que conheciam a doença citaram o mesmo exemplo: ‘’cegueira’’, desconhecendo o comprometimento a outros órgãos. Assim, evidenciou-se a necessidade da aplicação de estratégias em educação em saúde na região, incluindo a introdução no serviço terciário, com enfoque no atendimento farmacêutico especializado para toxoplasmose congênita, tendo em vista as lacunas presentes na atenção básica.
Vidas interrompidas por balas perdidas
Authors: Oliveira Janaine Voltolini de , Carvalho Maria João Leote de
Published: August 2023

Nos últimos anos o Brasil registrou um aumento das mortes violentas intencionais por arma de fogo, tendo os jovens representado mais de metade destes óbitos. Ao mesmo tempo, o país dobrou o número de registros de armas de fogo e as importações de armas longas. A crescente vitimização do público infantojuvenil após 32 anos da promulgação do Estatuto da Criança e do Adolescente mostra que garantir os direitos fundamentais, em especial à vida, ainda se apresenta como um enorme desafio para as políticas públicas, sobretudo quando combinado a um cenário de exclusão escolar e outros fatores como a ausência de oportunidades de lazer e inserção no mercado formal de trabalho, que, somados a outros, são determinantes da situação de vulnerabilidade social e contribuem para potencializar a violência. O objetivo deste artigo é discutir a cobertura da imprensa online sobre a violência letal contra crianças e adolescentes vítimas de balas perdidas no Brasil. Trata-se de um estudo exploratório, com enfoque qualitativo, elaborado a partir da coleta e análise de dados de 20 casos, publicados em 19 matérias jornalísticas disponíveis online sobre a mortandade do público infantojuvenil de 0 a 18 anos. Na análise de conteúdo dos fatos, constatou-se, que a cobertura da mídia sobre estes casos se concentra em divulgar, superficialmente, alguns dados dos crimes e outros fatos violentos relativos às ocorrências. Percebe-se que não há intenção em aprofundar a discussão do fenômeno social da violência, de compreender os problemas gerados pela insegurança pública ou mesmo aderir ao debate sobre políticas públicas. Este privilégio da ocorrência fortalece o sensacionalismo da notícia como estratégia de mercado, já que não se observa narrativas aprofundadas ou alguma preocupação direcionada a revelar os desfechos ou mesmo dar continuidade ao acompanhamento dos casos.
The Influence of Participatory Technology and Institutional Participation of Farmer Groups on Farmer Business Development
Authors: Romadi Ugik , Gunawan Gunawan , Mohammad Falah Haris
Published: August 2023

Janti Village, Jogoroto, Jombang has a corn productivity of 2020 reaching 84.5 Kw/Ha, this achievement exceeds national average corn productivity. However, this is inversely proportional to the unstable price of corn, which can even be far from the normal price. Besides, the lack of farmer participation makes the problem drag on longer. The existence of farmer group institutions is very important to solve this problem. In addition, the application of participatory technology to farmers also provides clear goals for future agricultural production activities. Therefore, it is necessary to be active and participate in the Janti Village farmer group members. The purpose of this study is to describe the influence of participatory technology (discussions, workshops, and action planning) and institutional participation of farmer groups (participation in planning, implementation, utilization of results, and evaluation) on farming development (social, economic, and environmental) in Janti Village. Jogoroto District, Jombang Regency. The research method uses descriptive quantitative data collection techniques namely interviews, observation, and questionnaires. Previously, the questionnaire had to be tested for validity and reliability tests to support the validity of the research data obtained. The sampling method used is a simple random sample. Then the data analysis used is multiple linear regression analysis using the ordinary least square method including data tabulation, estimation of multiple linear regression models, classical assumption tests, regression feasibility tests, and interpretation of multiple linear regression models. Results showed that there was no significant effect if independent variables moved independently on dependent variables. Meanwhile, if independent variables move simultaneously, there will be a significant influence between participatory technology and the institutional participation of farmer groups in the development of farming businesses.
Behavioural organisational factors affecting strategic management practice in urban councils in Zimbabwe
Authors: Edward Edward Chinongwa
Published: August 2023

The study sought to explore behavioural organisational factors affecting strategic management practice in urban councils in Zimbabwe. A quantitative research approach was adopted in the study with a population of 3031. A cluster sampling technique was adopted where a sample size of 341 professional employees were selected, using the Krejcie Morgan sample size determination table. A questionnaire was adopted in the collection of data after a pilot study and internal consistency was used to test for reliability, where Cronbach’s Alpha co-efficient of above 0.7 confirmed the reliability of the research instrument. SPSS version 23 was used in the analysis of data. Descriptive statistical techniques which involve mean, standard deviation, frequency and percentages were used in the data analysis. Organisational culture, organisational structure and technology innovativeness capability were used as variables for assessment. From the findings, it emerged that organisational culture, organisational structure and technology innovativeness capability have a significant influence in the practice of strategic management in urban councils in Zimbabwe.Key words: behavioural factors, organisational culture, organisational structure, strategic management, technology innovativeness capability
Global Stability Analysis of Full-Aircraft Transonic Buffet at Flight Reynolds Numbers
Authors: Sansica Andrea , Hashimoto Atsushi
Published: August 2023

Fully three-dimensional (3D) global stability analysis (GSA) is performed on the NASA Common Research Model at turbulent transonic buffet conditions. The framework here proposed is based on a Jacobian-free approach that enables GSA on large 3D grids, making this the first stability study on a full-aircraft at typical flight Reynolds numbers. The Reynolds-averaged Navier–Stokes solutions compare reasonably well with the available experiments and are used as base flows for the stability analyses. GSA is first performed at wind tunnel Reynolds number conditions, and a buffet-cell mode localized in the wing outboard region is found to be responsible for the onset. When the side-of-body (SOB) separation becomes larger at higher angles of attack, two additional modes are detected: a high-frequency mode localized in the SOB region and a low-frequency long-wavelength buffet-cell mode that may represent the link with the shock-oscillation instability found in two-dimensional airfoils. The existence of the buffet-cell mode is confirmed at flight Reynolds numbers. However, due to the presence of large SOB separation at the onset angle of attack, this mode is distributed along the whole wing and an SOB separation mode also appears. As well as characterizing buffet on industry-relevant geometries and flow conditions, this study proves that the proposed GSA framework is feasible for large 3D numerical grids and can represent a useful tool for buffet onset prediction during design and certification phases of commercial aircraft.
Educação permanente em saúde: desafios e potencialidades para o processo de trabalho
Authors: Fonseca Emanuel Nildivan Rodrigues da , Cunha Sabrina Márcia Resende de Almeida Santos , Carneiro Maria Tereza Divalda , Barbosa Khivia Kiss da Silva , Batista Mônica da Costa , Ferreira Fernanda Cruz Ramos , França Sandra Martins de , Marques Maria Lucia Fernandes de Carvalho , Bastos Maria de Lourdes Fernandes , Medeiros Emmanuela Costa de
Published: August 2023

Objetivo: Descrever os desafios e potencialidades da Educação Permanente em Saúde (EPS) no processo de trabalho. Métodos:  Estudo teórico, tipo revisão integrativa da literatura, realizada de Janeiro a Fevereiro de 2023, na fonte de dados Biblioteca Virtual em Saúde (BVS) e na base de dados CAPES, utilizando os descritores validados pelo DeCS/MeSH; Educação Permanente em Saúde e Processo de Trabalho, com os filtros texto completo e disponível, documentos tipo artigos científicos; ano de publicação 2018 a 2023, realizados em português. A população da pesquisa incluiu 222 artigos. Após a leitura de seus resumos, foram selecionados 21 artigos. Resultados: A educação permanente em saúde inclui uma dimensão ética e política, o que exige repensar cotidianamente o processo de trabalho, visando a defesa dos direitos sociais, exigindo uma política social formal. O modelo tradicional de organização do trabalho carece de flexibilidade e de atenção aos aspectos subjetivos, de campo e contextuais, e seu rigor dificulta o aprimoramento dos profissionais. Considerações finais: A EPS tem o potencial de alertar os profissionais de saúde para mudanças na prática profissional, qualificar os serviços por meio do trabalho em equipe, com o objetivo de organizar o trabalho para atender às necessidades de saúde da população.
Os impactos da COVID-19 em pacientes com transtorno obsessivo compulsivo
Authors: Lobato Kadiza Vieira , Lima Alex Silva , Gonçalves Ana Vitória Figueira Fagundes , Freitas André Pereira Silva , Morgado Felipe do Vale , Pereira Kaio Keven de Lucena , Antunes Maria Gizely Pinheiro , Costa Rodrigo Santiago da , Miranda Romulo Silva de , Aragão Andressa de Oliveira
Published: August 2023

Objetivo: Compreender a relação entre os fatores estressores impostos pela pandemia da COVID-19 e alterações significativas na apresentação clínica de pacientes com transtorno obsessivo compulsivo. Métodos: Trata-se de uma revisão integrativa com publicações realizadas entre 2020 e 2023 nas línguas inglesa, portuguesa ou espanhola e com conteúdo disponibilizado na íntegra de forma gratuita. Para nortear a pesquisa, utilizou-se o problema: “O paciente com transtorno obsessivo compulsivo (TOC) teve seu quadro clínico agravado por fatores estressantes inerentes à pandemia da COVID-19?”. A pesquisa foi realizada nas bases de dados PubMed, Acervo+ Index Base e MedLine para a qual foram utilizados os Descritores em Ciências da Saúde (DeCS) “obsessive-compulsive disorder”, “COVID-19” e “pandemia” com o operador booleano “AND”. Resultados: 14 artigos enquadrados nos critérios de inclusão e exclusão demonstraram que houveram mudanças comportamentais em pacientes com TOC no contexto pandêmico gerado pelo coronavírus, as quais variam desde a uma exacerbação dos sintomas, até desfechos mais graves. Considerações finais: Apesar de não se obter um consenso geral acerca do tema, a literatura ratifica que a pandemia alterou a dinâmica comportamental de pacientes com TOC. O medo de infecção e o tempo de exposição à mídia foram fatores determinantes em piores desfechos.
Cystic retroperitoneal dedifferentiated liposarcoma: A case report
Authors: Sorour Sara , Bao Bo , Wilson Mitchell Patrick , Low Gavin
Published: August 2023

Liposarcoma is the most common primary retroperitoneal sarcoma in adults. We report the case of an 86-year-old male who presented to the emergency department with frequent falls and unexplained weight loss that was found to have a cystic retroperitoneal dedifferentiated liposarcoma. Initial computed tomography revealed a large heterogeneous complex cystic hypoenhancing lesion in the left retroperitoneum. Subsequent magnetic resonance imaging demonstrates a multilocular cystic mass with microscopic lipid content, diffusion restriction, and enhancing nodular soft-tissue components. Histologic examination of the tissue sample following biopsy is consistent with cystic retroperitoneal dedifferentiated liposarcoma. Further management was not pursued due to the patient’s advanced age and frailty.
Unilateral Purtscher’s retinopathy – A rare case report
Authors: Chaurasiya Suraj Kumar , Lailung Saron , Agarwal Pradeep , Kohli Piyush
Published: August 2023

With retinal whitening (Purtscher’s flecken) and intraretinal hemorrhages, Purtscher’s retinopathy was initially reported as a symptom of sudden loss of vision following head trauma in 1910. A 28-year-old male patient presented with a history of sudden painless decrease of vision in his left eye (LE) for 1 week. He gave a history of head-and-neck injury following a road traffic accident. Unaided distance visual acuity was 20/20 in the right eye (RE) and 20/40 in the LE which improved up to 20/25 on pinhole at the time of presentation. On examination, the anterior segment was within normal limits. Fundus photo and ocular coherence tomography (OCT) showed normal in the RE; however, LE showed multiple white patches around the optic disc with flamed-shaped hemorrhages on the fundus photo and macular edema with discontinuity in the inner and outer retinal layer on OCT. The patient received oral steroids as treatment, and after 1 month of follow-up, had recovered to 20/20 visual acuity.
Clinical and laboratory studies in the complex diagnosis and treatment of uveitis in children
Authors:   Department of Biochemistry and Molecular Biology, Faculty of Medicine, Pirogov Russian National Research Medical University, Moscow, Russian Federation, Komarov O.S. , Zakharov V.B. ,   Department of Biochemistry and Molecular Biology, Faculty of Medicine, Pirogov Russian National Research Medical University, Moscow, Russian Federation, Galkina N.M. ,   Department of Biochemistry and Molecular Biology, Faculty of Medicine, Pirogov Russian National Research Medical University, Moscow, Russian Federation
Published: August 2023

This work is devoted to the analysis of the effectiveness of new clinical and laboratory studies and their possible application in treatment of uveitis in children. The paper assesses the study of the glutathione-reducing system as a factor in the vulnerability of eye tissues to the effects of free radicals and peroxidation products during inflammation. The dependence of the clinical picture of uveitis and the frequency of detection of eye tissue antigens in the blood was analyzed to assess the localization and stage of the pathological process, which will undoubtedly determine the tactics of the therapy. Evaluation of the main indicators of the activity of peroxidation processes in uveitis is proposed to be carried out according to the original method for determining the functional activity of polymorphonuclear leukocytes (PNLs). It was proved that there is a close relationship between the level of PNLs activity, the level of intensity of peroxide processes and the ophthalmic picture of uveitis. Based on the results obtained in the following work, the use of pharmaceutical antioxidants, both traditional and those known drugs in which antioxidant properties were discovered for the first time, was proposed. This paper offers a concept of the development of toxic-allergic uveitis, including successive stages of the formation of immune complexes, inflammation, an increase in the functional activity of PMNs, their chemotaxis into the inflammation zone, infiltration through the capillary walls in the eye tissue, which leads to an avalanche-like increase in the level of oxidants, depletion of endogenous reserves of antioxidants, damage to cell membranes. Understanding these processes serves as an explication for developing optimal treatment regimens for uveitis and other inflammatory ophthalmpathology. Keywords: uveitis, retinal antigens, glutathione system, antioxidants, polymorphonuclear leukocytes, peroxidation, reactive oxygen species
Ophthalmological manifestations of familial adenomatous colon polyposis
Authors: Yarovoy A.A. , Kotelnikova A.V. , Yarovaya V.A. , Matyaeva A.D. , Krasnova E.O.
Published: August 2023

Purpose. To describe a rare clinical case of bilateral ophthalmic manifestations of familial adenomatous polyposis of the colon. Material and methods. A multimodal imaging complex was carried out, which included the following methods: photo registration on the fundus camera Visucam 500 (Zeiss, Germany) and pediatric retinal camera RetCam 3 (Clarity, USA). Results. Familial adenomatous polyposis (FAP) is a hereditary disease of the colon characterized by adenomatous colon polyps, which in 100% of cases malignize into adenocarcinoma without proper early management. There are some forms of FAP with the eye fundus signs, which can serve as a signal to suspect and diagnose this disease. We report a case of fundus pigment spots in siblings whose mother was diagnosed with genetically confirmed FAP. Conclusions. The presence of randomly scattered pigmented neoplasms in the fundus, shaped like a comet, may be a sign of FAP. All patients at risk with a family history of adenocarcinoma of the large intestine should undergo an ophthalmological examination as a screening diagnostic method. Key words: familial adenomatous polyposis, adenocarcinoma of the colon, fundus pigment spots
Pengaruh Progressive Muscle Relaxation (PMR) Terhadap Tingkat Kelelahan Lansia Penyintas Covid 19 di Kota Pekanbaru Penelitian Dosen PemulaTahun ke 1 dari 1
Authors: Hamid Abdurrahman , Wisanti Eka , Ezdha Awaliyah Ulfah Ayudytha
Published: August 2023

Pendahuluan Kelelahan merupakan gejala terbanyak yang dialami oleh lansia penyintas covid 19 setelah demam dan sesak nafas dimana kejadiannya 30% dari seluruh lansia penyintas covid 19. Perawatan lansia penyintas covid 19 membutuhkan suatu intervensi yang mampu mempercepat pemulihan lansia dari kelelahan tersebut.  Tujuan Penelitian Tujuan Penelitian ini adalalah melihat pengaruh intevensi keperawatan Progressive Muscle Relaxation terhadap kelelahan pada lansia penyintas covid 19. Metode, Pada penelitian ini menggunakan desain penelitian quasy eksperimen dengan jenis pretest and post test without control group. Dengan menggunakan penghitungan sampel uji hipotesis  populasi  maka jumlah sampel  minimal yaitu 40 orang lansia, Pada penelitian ini metode sampling yang digunakan adalah multistage random sampling, Penelitian dilakukan pada bulan Juni-Agustus 2022. Analisa bivariat menggunakan Paired T Test. Hasil/temuan Hasil penelitian di dapatkan terdapat pengaruh Intervensi Keperawatan Progressive Muscle Relaxation terhadap tingkat kelelahan lansia penyintas covid 19 di kota pekanbaru dengan nilai p value 0,001 (<0.05). Hal ini dilihat dari adanya perubahan tingkat kelelahan sebelum dan setelah intervensi. Jika dikaitkan antara terapi PMR ini dengan kelelahan yaitu pada saat melakukan terapi ini terjadi pelepasan produksi hormon endorfin, enkefalin, dan serotonin selanjutnya akan muncul perasaan tenang dan rileks. Simpulan, Intervensi Keperawatan PMR ini dapat dijadikan salah satu alternative bentuk intervensi keperawatan untuk mengatasi masalah kelelahan pada lansia dan dapat dilakukan oleh perawat komunitas di Puskesmas.

 

Kata Kunci : Kelelahan; Lansia; Penyintas Covid 19; Progressive Muscle Relaxation,
HOLBACH’S AND EULER’S HYPOTHESES AND THEIR SOLUTIONS
Authors: Оруджов Н.З. , Оруджов З.С.
Published: August 2023

В статье рассматриваются три вопроса. 1. Проблема Эйлера. 2. Теорема Гольбаха. 3. Задача формул простых чисел. Доказаны две леммы и три теоремы для решения этих задач. Из них можно сделать шесть выводов. Тогда правильным шагом будет сначала доказать теорему Эйлера. Следующие два факта играют ключевую роль в доказательстве теоремы Эйлера: I. Доказана конкретная формула суммирования любого натурального числа с простым числом (Основная теорема). Это новая формула, а также новое направление в теории чисел. Можно надеяться, что эта формула найдет множество приложений в теории чисел. II.Освобождение (устранение) формулы Чебышева от логарифмирования. Хотя ошибок много, доказательство успешное. Затем с помощью теоремы Эйлера доказывается теорема Гольдбаха. Хотя количество способов представить любое натуральное число (N>5) в виде суммы простых чисел невелико, оно серьезно доказано. Также доказывается, с помощью формулы основной теоремы, что формулы для простых чисел не существует.

The article deals with three issues. 1. Euler’s problem. 2. Holbach’s theorem. 3. The problem of formulas of prime numbers. Two lemmas and three theorems are proved for solving these problems. Six conclusions can be drawn from them. Then the correct step would be to first prove Euler’s theorem. The following two facts play a key role in the proof of Euler’s theorem: I. A specific formula for the summation of any natural number with a prime number is proved (Main Theorem). This is a new formula, as well as a new direction in number theory. It is hoped that this formula will find many applications in number theory. II. Release (elimination) of the Chebyshev formula from logarithm. Although there are many errors, the proof is successful. Then, with the help of Euler’s theorem, Goldbach’s theorem is proved. Although the number of ways to represent any natural number (N>5) as a sum of prime numbers is small, it has been seriously proven. It is also proved, using the formula of the main theorem, that there is no formula for prime numbers.
ASSESSMENT OF GENERAL MELTED SOLIDS QUANTITIES OF GROUNDWATER ON A BASIS OF THE WORLD HEALTH ORGANIZATION (WHO) STANDARD FOR TOTAL DISSOLVED SOLIDS (TDS)
Authors: Раджабова Н.Д. , Шеримбетов В.Х.
Published: August 2023

При определении ситуаций, в которых экосистемы, зависящие от подземных вод, подвергаются воздействию различных факторов, каждое их обстоятельство требует определенного изучения компонентов. Тем не менее конкретная ситуация возникает в результате одновременного взаимодействия факторов внешней среды, и установление и исследование доминирующего элемента в формировании ситуации позволяет качественно оценить состояние объекта. В данной статье повышенные значения TDS, одного из переменных параметров подземных вод, формирующихся на глубине 13-17 метров в Амударьинском районе, классифицируются в соответствии со стандартом ВОЗ TDS.

In determining the situations inside which the Groundwater-dependent ecosystems are affected based on different factors, each of their circumstances requires a particular learning of the components. Notwithstanding, a specific situation arises from the simultaneous reciprocation of the environmental factors, and the ascertainment and disquisition of the dominant element in the formation of the situation makes that possible to qualitatively evaluate the object condition. In this article, elevated values of TDS, one of the variable parameters of groundwater formed at a deepness of 13-17 meter in Amudarya district, are classified owing to the WHO TDS standard.
THE “REVIVAL” PROGRAMME OF COMPREHENSIVE REHABILITATION OF YOUNG PEOPLE WITH MENTAL DISABILITIES WITH THE USE OF AUDIOCORRECTION
Authors: PYATKINA EKATERINA , GRININA ELENA , SHIPOVA LARISA , TEZIKOVA EUGENIA
Published: August 2023

The article reveals the structure, content and features of complex rehabilitation of young people with mental disabilities. The specifics of the “Revival” programme is a combination of traditional technologies and methods of psychological correction, implemented in individual and group classes, psychological trainings, with audiocorrection based on the Rulisten equipment (Tomatis therapy technology), as well as with classes of dance therapy, music therapy, bibliotherapy. The control diagnostics at the final stage of the programme implementation indicates positive dynamics of cognitive processes (attention, memory, thinking, speech), optimisation of the emotional state of clients, increasing the level of their communicative development. The results obtained testify to the effectiveness and expediency of including audiocorrection in the comprehensive rehabilitation of young people with mental disabilities.
INTENSIVE MOTHERING AND PARENTAL BURNOUT
Authors: APANOVICH TATIANA , SERYKH ANNA
Published: August 2023

The article is of a theoretical nature and is devoted to a basic review of scientific literature in the field of such an urgent problem as the emotional burnout of mothers in conjunction with priority parental attitudes. A brief description of the main concepts is given, the authors' view on this issue is reflected.
FEATURES AND EFFECTIVENESS OF SUPPORTING THE DEVELOPMENT OF PROJECT COMPETENCE OF A HEAD OF A PROFESSIONAL EDUCATIONAL ORGANISATION
Authors: ERMOLENKO VADIM
Published: August 2023

The article presents the results of the study on supporting the development of project competence of a head of a professional educational organisation. The author’s interpretation of this support is given, its features are revealed. The article proposes an approach to organising the support based on the combination of the idea of nonlinearity and criterion-level evaluation of the result. The author shows the effectiveness of the nonlinear model of support for the development of project competence in the conditions of practical management activity.
METHODS OF TEACHING CHORAL CONDUCTING IN CHINA (BASED ON THE WORKS OF XIAN XINGHAI AND HUANG ZI)
Authors: ZHANG YUTING
Published: August 2023

The article studies the specifics of the educational cycle of choir conducting in Chinese universities, highlights the origins of the formation of the style of choral compositions by Chinese authors, analyses Xian Xinghai’s choirs “On the Taihang Mountains”, “Yellow Water Ballad” and Huang Zi’s choir “Fluttering Flag” in the aspect of pedagogical problems. The most effective methods for working on the selected works at different stages of training are revealed. The musical, stylistic, rhythm and intonation features of the choirs are indicated, the importance of the imagery of the poetic texts is emphasised. The conclusion is made about the expansion of the educational process in Chinese institutions in the field of choral conducting.
CREATION OF A COMPETENCE ASSESSMENT COMPLEX FOR STATE CIVIL AND MUNICIPAL EMPLOYEES: THE EXPERIENCE IN DEVELOPING DIAGNOSTIC SCALES
Authors: KUDASHEV AZAT
Published: August 2023

The review of various modern approaches to the assessment of professional and personal qualities of employees of organisations is carried out, the features of the assessment of these qualities in state civil and municipal employees are shown. The necessity of measuring competencies with the use of test tasks in the format of mini-cases is substantiated. The process of developing tasks for six diagnostic scales using expert opinion is described, various aspects of validity are investigated: validity of constructs, criteria and content. The process of completing tasks is shown, prospects for improving the diagnostic procedure based on adaptive testing algorithms are outlined.
THE DIFFICULTIES OF TEACHING FIRE SAFETY MEASURES TO EMPLOYEES OF MEGALOPOLIS ORGANISATIONS
Authors: LOSEV KONSTANTIN , CHEKAREV LEONID
Published: August 2023

The article is devoted to the improvement of teaching fire safety rules to various groups of the population. Particular attention is paid to familiarising potential employees with obvious and potential threats to life and health. The authors analyse them in terms of detection and explain some features of the most common deviations from the norms, which, one way or another, increase the risk of emergency situations that prevent people from safely performing their work or official activities. The data related to the implementation of fire prevention instruction programmes and programmes of additional professional education are presented.
THE IMPLEMENTATION OF THE UNIFIED PRACTICE CONCEPT IN TRAINING OF RUSSIAN LANGUAGE AND LITERATURE TEACHERS: THE EMPIRICAL APPROACH
Authors: VILANDEBERK ANNA , SHUBINA NATALIA
Published: August 2023

The results of the approbation of the unified practice concept in training of Russian language and literature teachers at a pedagogical university are presented in the article. The main directions of its practical implementation are determined; the problems that impede the effective implementation of the concept are described; specific approaches to the organisation of practice at the undergraduate level are demonstrated.
COPING STRATEGIES IN HIGH SCHOOL STUDENTS WITH DIFFERENT LEVELS OF LIFE SATISFACTION
Authors: KASKEVICH EKATERINA
Published: August 2023

The paper analyses the results of the study of coping behaviour among senior high school students with different levels of life satisfaction. The influence of psychological characteristics of personality, such as “coping strategies”, “life satisfaction” during study in graduating classes, is considered. The results of the empirical research can be used by socio-psychological services of educational institutions that assist students in increasing life satisfaction and developing new adaptive strategies for overcoming difficult life situations.
HE INFLUENCE OF PARENTAL BEHAVIOUR OF FATHERS ON THE LEVEL OF CLAIMS OF DAUGHTERS
Authors: SHUMAKOV VADIM , TITOVA OLGA , KRYUKOV SERGEY , SHUMAKOVA OLGA
Published: August 2023

The article describes the influence of educational influences of parents on the psychological well-being and development of children. The results of the study of parental behaviour of fathers on the level of claims and self-esteem of daughters are presented. The authors provide the empirical data and characteristics of the relationship between daughters’ ideas about the criticality and closeness of their fathers as factors of parental behaviour and their relationship with self-esteem, initiative, evaluation of their own resources and the motive of self-esteem in girls.
THE POSSIBILITIES OF MUTUALLY COORDINATED SOLUTION OF EDUCATIONAL TASKS BY COLLECTIVE SUBJECTS FOCUSED ON THE FORMATION OF A PERSONALITY WITH A SAFE BEHAVIOUR TYPE
Authors: VLASOVA GALINA , RYABOVA ELENA , YASHKOVA ANASTASIA
Published: August 2023

The article deals with the problem of forming a personality of a safe type of behaviour, which can be solved by such collective subjects of education as student rescue teams. The inclusion of high school students in their activities makes it possible to combine theoretical training with active practical participation in relevant projects in society.
PROSOCIAL PERSONALITY ORIENTATION AND EMOTIONAL INTELLIGENCE: AN ANALYSIS OF RELATIONSHIPS AND PATTERNS
Authors: BELOV GEORGY , NEDOSHIVINA MARIIA
Published: August 2023

There is a large number of studies of emotional intelligence demonstrating its relationship with psychological well-being, mental and physical health nowadays. Our research is aimed at studying emotional intelligence in the context of prosocial behaviour. We consider emotional intelligence as a cognitive ability, possibly contributing to the prosocial orientation of an individual. The results obtained in the study using the Emotional Intelligence Test (EmIn) by D. Lyusin and the Personality Networking Strategies Method showed the presence of statistically significant relationships. In particular, the level of interpersonal emotional intelligence was positively associated with the prosocial orientation of an individual. The Прикладные исследования, технологии 85 findings of the study have significant theoretical and practical significance and can be used in the development of training programmes and improvement of the efficiency of intragroup processes.
THE APPLICATION OF AUDIOVISUAL MEANS OF EXPRESSION IN THE SPECIALIST TRAINING OF GRAPHIC DESIGN STUDENTS
Authors: KHABIBOVA ALEVTINA , KHIZHNYAK ELIZAVETA
Published: August 2023

The article is a description of the authors’ effective methods for teaching special disciplines ensuring the comprehensive development of graphic design students. The article lists the methodological techniques employed by the authors working with various artistic and digital instruments aimed at developing figurative representations which form audiovisual images through additional influence. A number of specific methods and techniques for teaching students the theoretical and practical disciplines have been tested in a formative experiment and realised in the form of a brief overview of the new approaches to training designers. It is a complex based on interdisciplinary integration, aimed at improving students’ professional competences.
A conjugated heat and mass transfer model to implement reaction in particle-resolved CFD simulations of catalytic fixed bed reactors
Authors: Kutscherauer Martin , Anderson Scott , Böcklein Sebastian , Mestl Gerhard , Turek Thomas , Wehinger Gregor D.
Published: August 2023

Modeling catalytic fixed bed reactors with a small tube-to-particle diameter ratio requires a detailed description of the interactions between fluid flow, intra-particle transport, and the chemical reaction(s) within the catalyst. Particle-resolved computational fluid dynamics (PRCFD) simulations are the most promising approach to accurately predict the behavior of these reactors, since they take explicitly into account the local packed bed structure. In this work, a conjugated heat and mass transfer model for use in PRCFD simulations is presented to couple the fluid flow through the fixed bed with transport and reaction in the porous catalyst, while guaranteeing the no-slip boundary condition at the fluid-solid interface. For this purpose, the solutions of the solid and fluid domain are computed separately and are coupled by calculation and updating the boundary condition at the particle surface. Due to the consideration of secondary gradients, the developed transfer model is also valid for unstructured calculation meshes containing non-orthogonal cells at the fluid-solid interface. Such meshes are often used to resolve complex geometries, such as a packed bed, in a computationally efficient manner. The coupling approach is validated using cases for which an analytical solution or literature correlations derived from experimental data are available. The simulation results of a short catalytic packed bed with rings catalyzing the partial oxidation of n-butane to maleic anhydride exemplify the potential of PRCFD involving reactions to analyze the catalyst performance in great detail.
Anticoagulant rodenticide novel candidates predicted by evolutionary docking
Authors: coll julio
Published: August 2023

To generate high-throughoutput numbers of putative anticoagulant rodenticides, a computational evolutionary method has been applied. In particular, the previously described DataWarrior Build-Evolutionary-Library was optimized to randomly generate made-on-demand brodifacoum-derived children libraries exploring new chemotypes for anticoagulant candidates. The generated children were selected by fitting the brodifacoum-docking cavity of rat-VKORC1 (vitamin K epoxide reductase complex 1) alphafold-modeled using the recent crystallographic human-VKORC1 complex. The non-toxic children predicting the highest affinities (lowest docking-scores) for wild type and resistant rat mutants (Spanish and European) and the lowest affinities for human VKORC1, were consensed by AutoDockVina docking to identify with increased accuracy those anticoagulant candidates predicting rat-VKORC1 nanomolar affinities. The resulting layout library of 150 candidates provided with multi-threshold-adjustable filters, constitute an step forward towards in silico fine-tuning elimination of any other off-target biological species. Chemical synthesis pathway predictions and experimental validations remain to be done
Dynamic Lone Pairs and Fluoride-Ion Disorder in Cubic-BaSnF4
Authors: Mercadier Briséïs , Coles Samuel , Duttine Mathieu , Legein Christophe , Body Monique , Borkiewicz Olaf , Lebedev Oleg , Morgan Benjamin , Masquelier Christian , Dambournet Damien
Published: August 2023

Introducing compositional or structural disorder within crystalline solid electrolytes is a common strategy for increasing their ionic conductivity. (M,Sn)F2 fluorites have previously been proposed to exhibit two forms of disorder within their cationic host frameworks: occupational disorder from randomly distributed M and Sn cations, and orientational disorder from Sn(II) stereoactive lone pairs. Here, we characterise the structure and fluoride-ion–dynamics of cubic-BaSnF4, using a combination of experimental and computational techniques. Rietveld refinement of XRD data confirms an average fluorite structure with {Ba,Sn} cation disorder, and the 119Sn Mo ̈ssbauer spectrum demonstrates the presence of stereoactive Sn(II) lone pairs. X-ray total-scattering PDF analysis and ab initio molecular dynamics simulations reveal a complex local structure with a high degree of intrinsic fluoride-ion disorder, where 1/3 of fluoride ions occupy octahedral “interstitial” sites: this fluoride-ion disorder is a consequence of repulsion between Sn lone pairs and fluoride ions that destabilises Sn-coordinated tetrahedral fluoride-ion sites. Variable-temperature 19F NMR experiments and analysis of our molecular dynamics simulations reveal highly inhomogeneous fluoride-ion dynamics, with fluoride ions in Sn-rich local environments significantly more mobile than those in Ba-rich environments. Our simulations also reveal dynamical reorientation of the Sn lone pairs that is biased by the local cation configuration and is coupled to the local fluoride-ion dynamics. We end by discussing the effect of host-framework disorder on long-range diffusion pathways in cubic BaSnF4 .
Computational Study on the Route of Cooperative Organocatalysis Utilizing Thiourea and Halogen Bond Donor Mixture
Authors: Novikov Alexander S. , Bolotin Dmitrii S.
Published: August 2023

A computational analysis of possible routes of cooperative catalysis involving hydrogen bond donating thiourea and halogen bond donating organocatalysts has been carried out at the M06-2X/SDD level of theory using the solvation model based on density (SMD). For the model systems involving thiourea and 2-iodoimidazolium or iodonium salt derivatives, the previously suggested route including sequential electrophilic activation of a reaction electrophile via XB-activated HB donor was ruled out.
Theoretical Insight into the Effect of Phosphorus Oxygenation on Nonradiative Decays: Comparative Analysis of P-Bridged Stilbene Analogs
Authors: Inai Naoto , Yamaguchi Shigehiro , Yanai Takeshi
Published: August 2023

Incorporation of phosphorus element into a 𝜋-conjugated skeleton offers valuable prospects for adjusting the electronic structure of the resulting functional 𝜋-electron systems. The trivalent phosphorus has the potential to decrease the LUMO level through the 𝜎∗-𝜋∗ interaction, which is further enhanced by its oxygenation to the pentavalent P center. This study shows that utilizing our computational analysis to examine excited-state dynamics based on radiative/nonradiative rate constants and fluorescence quantum yield (ΦF) is effective for analyzing the photophysical properties of P-containing organic dyes. We theoretically investigate how the trivalent phosphanyl group and pentavalent phosphine oxide moiety affect radiative and nonradiative decay processes. We evaluate four variations of P-bridged stilbene analogs. Our analysis reveals that the primary decay pathway for photo-excited bis-phosphanyl-bridged stil- bene is the intersystem crossing (ISC) to the triplet state and nonradiative. The oxidation of the phosphine moiety, however, suppresses the ISC due to the relative destabilization of the triplet states. The calculated rate constants match an increase in experimental ΦF from 0.07 to 0.98, as simulated from 0.23 to 0.94. The reduced HOMO–LUMO gap supports a red shift in the fluorescence spectra relative to the phosphine analog. The thiophene-fused variant with the non-oxidized trivalent P cen- ter exhibits intense emission with a high ΦF, 0.95. Our prediction indicates that the ISC transfer is obstructed owing to relatively destabilized triplet state induced by the thiophene substitution. Conversely, the thiophene-fused analog with the phosphine ox- ide moieties triggers a high-rate internal conversion mediated by conical intersection, leading to a decreased ΦF.
Representing Structures of the Multiple Conformational States of Proteins
Authors: Ramelot Theresa , Tejero Roberto , Montelione Gaetano
Published: August 2023

Biomolecules exhibit dynamic behavior that single-state models of their structures cannot fully capture. We review some recent advances for investigating multiple conformations of biomolecules, including experimental methods, molecular dynamics simulations, and machine learning. We also address the challenges associated with representing single- and multiple-state models in data archives, with a particular focus on NMR structures. Establishing standardized representations and annotations will facilitate effective communication and understanding of these complex models to the broader scientific community.
Realizing Solution-Phase Room Temperature Quantum Coherence in a Tetrathiafulvalene-Based Diradicaloid Complex
Authors: McNamara Lauren , Zhou Aimei , Rajh Tijana , Sun Lei , Anderson John
Published: August 2023

Molecular electron spins are promising candidates as scalable and tunable qubits but often suffer from air sensitivity or other undesirable decomposition pathways. Furthermore, significant spin‒lattice relaxation and nuclear spin-mediated decoherence limit their applications. While significant advances in the synthesis of new molecular electron spin qubit candidates have led to improved coherence lifetimes, one key question is whether coherence can be maintained under conditions relevant for employment as quantum sensors, for instance in solution and at room temperature for sensing in biological systems. Here we report a tetrathiafulvalene-based molecular qubit candidate with spin centered on a nuclear spin-free bridging ligand. This unique air and water-stable scaffold exhibits a long spin decoherence time of hundreds of nanoseconds at ambient temperatures and in nuclear spin-rich protonated solvents. These results distinguish this system as a promising candidate for the development of novel room temperature, solution-phase quantum sensing technologies, and suggest that molecular electron spin qubits can be ideal candidates for these applications.
The need for open, transdisciplinary, and ethical science in seismology
Authors: Dallo Irina , Herrmann Marcus , Supino Mariano , Bayona José A. , Khawaja Asim M. , Scaini Chiara
Published: August 2023

Reducing the seismic risk for societies requires a bridge between scientific knowledge and societal actions. In recent years, three subjects that facilitate this connection gained growing importance: open science, transdisciplinarity, and ethics. We outline their relevance in general and specifically at the example of `'dynamic seismic risk' as explored in a dedicated workshop. We argue that these reflections can be transferred to other research fields for improving their practical and societal relevance. We provide recommendations for scientists at all levels to make science more open, transdisciplinary, and ethical. Only with a transition can we, as scientists, address current societal challenges and increase societies' resilience to disasters.
Looks do invisível: Carne, ornamento, barroco e zen nos autorretratos de Kimiko Yoshida
Authors: Elias Meneghetti Maria Cristina
Published: August 2023

Desde 2001, a artista visual Kimiko Yoshida (Japão-França) tem produzido autorretratos em que a sua identidade desaparece sob trajes elaborados, pintura corporal e ornamentos. Os seus figurinos reconstituem pinturas conhecidas da história da arte euro-americana e a sua pele, integralmente coberta por tinta, numa remissão à pintura tradicional das gueixas japonesas, confunde-se com o fundo diante do qual ela posa. Neste artigo, olharemos para o percurso da artista, focando a forma como ela mesma transforma a sua carne em elemento plástico, inorgânico, apropriando-se do clichê em que foi transformada a imagem da mulher asiática pelo olhar ocidental. Atentaremos também para a tendência de abstração do corpo e de apagamento da individualidade presentes em seus autorretratos segundo princípios tanto da tradição espiritual do Japão como da Europa. Essas reflexões serão fundamentadas na teoria do ornamentalismo de Ainlin Cheng (2018), bem como no conceito de carne proposto por Deleuze em A lógica da sensação (1981).
Desorientar relações de poder para inventar modas
Authors: Greiner Christine , Druet Lucile
Published: August 2023

Quimonos, tatuagens, turbantes, túnicas, leques, pentes de cabelo, sandálias exóticas e muitos outros “adereços” fazem parte do imaginário ocidental há pelo menos três séculos. No entanto, esses objetos de desejo, sempre guardaram uma certa ambiguidade, transitando entre a fascinação e práticas autoritárias muito cruéis para estigmatizar os povos antípodas, que seriam aqueles que vivem do outro lado do mundo, tendo como referência geopolítica o Ocidente. [...]