bluuebunny/crossref_metadata_2025 huggingface dataset:
Environmental and Cost Assessments of Marine Alternative Fuels for Fully Autonomous Short-Sea Shipping Vessels Based on the Global Warming Potential Approach
Authors: Laryea Harriet , Schiffauerova Andrea
Published: November 2024

This research paper presents an effective approach to reducing marine pollution and costs by determining the optimal marine alternative fuels framework for short-sea shipping vessels, with a focus on energy efficiency. Employing mathematical models in a Python environment, the analyses are tailored specifically for conventional and fully autonomous high-speed passenger ferries (HSPFs) and tugboats, utilizing bottom-up methodologies, ship operating phases, and the global warming potential approach. The study aims to identify the optimal marine fuel that offers the highest Net Present Value (NPV) and minimal emissions, aligning with International Maritime Organization (IMO) regulations and environmental objectives. Data from the ship’s Automatic Identification System (AIS), along with specifications and port information, were integrated to assess power, energy, and fuel consumption, incorporating parameters of proposed marine alternative fuels. This study examines key performance indicators (KPIs) for marine alternative fuels used in both conventional and autonomous vessels, specifically analyzing total mass emission rate (TMER), total global warming potential (TGWP), total environmental impact (TEI), total environmental damage cost (TEDC), and NPV. The results show that hydrogen (H2-Ren, H2-F) fuels and electric options produce zero emissions, while traditional fuels like HFO and MDO exhibit the highest TMER. Sensitivity and stochastic analyses identify critical input variables affecting NPV, such as fuel costs, emission costs, and vessel speed. Findings indicate that LNG consistently yields the highest NPV, particularly for autonomous vessels, suggesting economic advantages and reduced emissions. These insights are crucial for optimizing fuel selection and operational strategies in marine transportation and offer valuable guidance for decision-making and investment in the marine sector, ensuring regulatory compliance and environmental sustainability.
Cold Intermediate Water Formation in the Black Sea Triggered by March 2022 Cold Intrusions
Authors: Çokacar Tülay
Published: November 2024

In mid-March 2022, a Siberian High brought intense cold air masses, leading to severe weather conditions across southern Europe, including the Black Sea region. This study investigates the spatial and temporal evolution of cold intermediate water (CIW) masses in the Black Sea, with a particular focus on the successive anomalously cold episodes that occurred in March 2022. The research underscores the significance of the northwestern continental slope and cyclonic gyres, especially as the only cold-water mass observations during the warm winters of 2020 and 2021 were concentrated in these areas. Following two warm winters, the cold episodes of March 2022 revealed notable convection and simultaneous cooling, particularly in the cyclonic interior and the Rim Current periphery, excluding the northeastern periphery. Subsequently, cold waters spreading isopycnally throughout the summer months were transported laterally and reached these regions. Argo float measurements provided clear evidence of widespread replenishment of the CIW, indicating that it is not confined to specific areas. The study also highlights regional variability in the characteristics of CIW formation, which is influenced by local dynamics and preconditioning temperatures. The temperatures of CIW increased from west to east, in line with the sea surface temperature gradient. Notably, thicker and colder CIW was found in the western cyclonic gyre compared to the eastern cyclonic area. Furthermore, the study confirms that the warming trend in CIW, identified in previous research, not only continues but has intensified during the recent period analyzed. These findings, observed under the extreme conditions analyzed in this research, offer valuable insights into the widespread occurrence of CIW formation in the Black Sea. Additionally, the study confirms that the warming trend in CIW, identified in previous studies, continued in the region throughout the warm winter period and after the cold spell in 2022. These insights contribute to a deeper understanding of CIW dynamics and their response to extreme weather events in the Black Sea.
Patterns in Anthropogenic Nitrogen and Water Quality Leading to Phytoplankton Blooms in Urban Estuaries
Authors: Dugdale Richard C. , Parker Alexander E. , Wilkerson Frances P.
Published: November 2024

The San Francisco Estuary (SFE) ecosystem receives anthropogenic ammonium (NH4) from agricultural runoff and sewage treatment plants and has low chlorophyll levels. As observed in other aquatic systems, NH4 at concentrations < 4 µmol/L inhibits nitrate (NO3) uptake by phytoplankton and can reduce the frequency with which phytoplankton assimilate all available inorganic nitrogen (i.e., NO3 and NH4); paradoxically, elevated NH4 can reduce the chances of phytoplankton blooms in some high NH4 ecosystems. For blooms to occur, NH4 must first be reduced to non-repressive levels, then NO3 uptake can occur and is accompanied by more rapid carbon (C) uptake and chlorophyll accumulation. The consequence of this sequence is that when NO3 uptake, C uptake, or chlorophyll concentrations are plotted against ambient NH4, a rectangular hyperbola results. Here, these relationships are statistically described for a variety of SFE field data, and their management applications are discussed. These relationships enable ambient NH4 to be used to predict both the likelihood of blooms and to investigate historical changes in productivity when no rate measurements were made. We apply the statistical relationship to a 40-year time series from the SFE during which there was an ecosystem-scale change in the estuarine foodweb with a drastic decline in pelagic fishes (the pelagic organism decline) and suggest that this period aligned with the lowest annual primary production and highest NH4. The relationship may be generalizable to other high-nitrogen, low-growth systems and aid nutrient management decisions, assuming potential limitations are considered.
Formalizing Sustainable Urban Mobility Management: An Innovative Approach with Digital Twin and Integrated Modeling
Authors: Grotto Andrea , Casas Pau Fonseca i , Zubaryeva Alyona , Sparber Wolfram
Published: November 2024

Background: Urban mobility management faces growing challenges that require the analysis and optimization of sustainable solutions. Digital twins (DTs) have emerged as innovative tools for this assessment, but their implementation requires standardized procedures and languages; Methods: As part of a broader methodology for continuous DT validation, this study focuses on the conceptual validation phase, presenting a conceptualization approach through formalization using Specification and Description Language (SDL), agnostic to simulation tools. The conceptual validation was achieved through stakeholder engagement in the Bolzano context, producing 41 SDL diagrams that define both elements common to different urban realities and specific local data collection procedures; Results: The feasibility of implementing this stakeholder-validated conceptualization was demonstrated using Simulation of Urban MObility (SUMO) for traffic simulation and optimization criteria calculation, and its framework SUMO Activity GenerAtion (SAGA) for generating an Activity-Based Modeling (ABM) mobility demand that can be improved through real sensor data; Conclusions: The SDL approach, through its graphical representation (SDL/GR), enables conceptual validation by enhancing stakeholder communication while defining a framework that, while adapting to the monitoring specificities of different urban realities, maintains a common and rigorous structure, independent of the chosen implementation tools and programming languages.
Quality of Life and Symptom Burden in Non-Small-Cell Lung Cancer Patients Receiving Second-Line Chemotherapy Compared with Immunotherapy
Authors: Stylianou Christos , Kalemikerakis Ioannis , Konstantinidis Theocharis , Kafazi Alkmena , Alevizopoulos Nektarios , Parissopoulos Stelios , Govina Ourania
Published: November 2024

Background and Objectives: The burdened symptomatology accompanying advanced non-small-cell lung cancer (NSCLC) is associated with poor prognosis and lower quality of life (QoL). Although both chemotherapy and immunotherapy increase survival, they are still associated with reduced functionality due to their toxicity. This study aimed to estimate the QoL and symptom burden of NSCLC patients receiving second-line chemotherapy compared to patients receiving second-line immunotherapy. Materials and Methods: This comparative, prospective study, conducted from January 2020 to December 2021, included 111 NSCLC patients who were divided into two groups: 61 patients receiving second-line chemotherapy and 50 patients receiving second-line immunotherapy. Patients’ QoL and symptom burden were estimated using the European Organisation for Research and Treatment of Cancer Quality of Life Questionnaire Core 30 (EORTC QLQ C-30) (value range 0–100) from treatment cycle 1 to 6. Results: The QoL (mean score > 50) and functionality dimensions (mean score > 50) were moderate to good in both treatment groups, while the symptom burden did not appear to be a serious problem (mean score < 50). From cycle 3 to cycle 5, QoL was significantly better in the immunotherapy group. From cycle 3, the role and social functioning scores were higher in the immunotherapy group, while emotional and cognitive functioning were higher from cycle 2 (p <0.05). The chemotherapy group experienced higher levels of nausea/vomiting, constipation and financial difficulties in all the cycles (p < 0.05). Fatigue and appetite loss were significantly greater from cycle 2 and insomnia was significantly greater from cycle 3. On the contrary, the immunotherapy group experienced higher levels of diarrhea in cycles 5 and 6 (p < 0.05). Conclusions: Although both therapy groups did not report significantly impaired QoL and severe symptoms, it seems that QoL improved in the immunotherapy group, which reported a lower symptom burden compared to the chemotherapy group.
Optimizing Treatment Strategies for Distal Radius Fractures in Osteoporosis: A Comparative Review
Authors: Gullborg Eric J. , Kim Jason H. , Ward Caitlin M. , Simcock Xavier C.
Published: November 2024

Osteoporosis is a common yet underdiagnosed condition that increases the risk of fractures, contributing to substantial morbidity, mortality, and healthcare costs. Distal radius fractures (DRFs) are some of the most common fractures associated with osteoporosis and often precede more severe fractures. Managing DRFs in patients with osteoporosis can be a challenge due to altered bone quality, which can affect healing and surgical fixation. This review examines both operative and nonoperative management strategies for DRFs in osteoporotic patients, emphasizing the importance of individualized treatment. Surgical interventions, like open reduction and internal fixation (ORIF) with plating, can facilitate early mobilization and improved alignment, especially in more active patients. However, osteoporosis poses risks such as hardware failure, infection, and malunion, calling for careful patient selection. Conversely, nonoperative management may be more suitable for patients with lower functional demands or higher surgical risks, despite the increased risk of malunion. By adapting treatment strategies to individual patient characteristics, orthopedic surgeons can optimize outcomes, minimize complications, and potentially prevent future fractures. Both operative and nonoperative treatments can yield positive outcomes when personalized to the patient’s needs.
Analysis of Technological Pathways and Development Suggestions for Blast Furnace Low-Carbon Ironmaking
Authors: Li Haifeng , Zhao Yan , Guo Chengqian , Li Junqi
Published: November 2024

Under the global dual-carbon background, heightened public awareness of climate change and strengthened carbon taxation policies are increasing pressure on the steel industry to transition. Given the urgent need for carbon reduction, the exploration of low-carbon pathways in a blast furnace (BF) metallurgy emerges as crucial. Evaluating both asset retention and technological maturity, the development of low-carbon technologies for BFs represents the most direct and effective technical approach. This article introduces global advancements in low-carbon metallurgical technologies for BFs, showcasing international progress encompassing hydrogen enrichment, oxygen enrichment, carbon cycling technologies, biomass utilization, and carbon capture, utilization, and storage (CCUS) technologies. Hydrogen enrichment is identified as the primary technological upgrade currently, although its carbon emission reduction potential is limited to 10% to 30%, insufficient to fundamentally address high carbon emissions from BFs. Therefore, this article innovatively proposes a comprehensive low-carbon metallurgical process concept with the substitution of carbon-neutral biomass fuels at the source stage—intensification of hydrogen enrichment in the process stage—fixation of CCUS at the end stage (SS-IP-FE). This process integrates the cleanliness of biomass, the high-efficiency of hydrogen enrichment, and the thoroughness of carbon fixation through CCUS, synergistically enhancing overall effectiveness. This integrated strategy holds promise for achieving a 50% reduction in carbon emissions from BFs in the long processes. Critical elements of these core technologies are analyzed, assessing their cost-effectiveness and emission reduction potential, underscoring comprehensive low-carbon metallurgy as a pivotal direction for future steel industry development with high technological feasibility and emission reduction efficacy. The article also proposes a series of targeted recommendations, suggesting short-term focus on technological optimization, the medium-term enhancement of technology research and application, and the long-term establishment of a comprehensive low-carbon metallurgical system.
Microstructure and Wear Behavior of AlxCoCuNiTi (x = 0, 0.4, and 1) High-Entropy Alloy Coatings
Authors: Ma Mingxing , Wang Zhixin , Zhu Chengjun , Dong Ying , Zhao Liang , Liu Lixin , Zhu Dachuan , Zhang Deliang
Published: November 2024

AlxCoCuNiTi (x = 0, 0.4, and 1) high-entropy alloy coatings on 45 steel substrates were prepared by laser cladding, and their phase structure, microstructure, element partition, and wear behavior were investigated. The results show that the AlxCoCuNiTi (x = 0, 0.4, and 1) coatings have a dual-phase structure of FCC and BCC. With the increase of x from 0 to 1, the content of the FCC phase decreases from 66.9 wt.% to 14.3 wt.%, while the content of the BCC phase increases from 33.1 wt.% to 85.7 wt.%. When x = 0.4, the lattice constants of the two phases are the largest, and their densities are the smallest. The microstructure of the AlxCoCuNiTi (x = 0, 0.4, and 1) coatings is composed of BCC-phase dendrites and FCC-phase interdendrite regions. Ti is mainly enriched in the primary phase or BCC dendrites, Cu is enriched in the interdendrite regions, and Al is enriched in the dendrites. The friction coefficients of AlxCoCuNiTi (x = 0, 0.4, and 1) coatings during wear tests are 0.691, 0.691, and 0.627, respectively. The lowering of the wear friction coefficient when increasing the Al content is mainly related to the change in phase structure, microstructure, and wear mechanism.
Crack Control in Additive Manufacturing by Leveraging Process Parameters and Lattice Design
Authors: Lee Jun Hak , Park Seong Je , Yang Jeongho , Moon Seung Ki , Park Jiyong
Published: November 2024

This study investigates the design of additive manufacturing for controlled crack propagation using process parameters and lattice structures. We examine two lattice types—octet-truss (OT) and diamond (DM)—fabricated via powder bed fusion with Ti-6Al-4V. Lattice structures are designed with varying densities (10%, 30%, and 50%) and process using two different laser energies. Using additive-manufactured specimens, Charpy impact tests are conducted to evaluate the fracture behavior and impact energy levels of the specimens. Results show that the type of the lattice structures, the density of the lattice structures, and laser energy significantly influence crack propagation patterns and impact energy. OT exhibits straighter crack paths, while DM demonstrates more random fracture patterns. Higher-density lattices and increased laser energy generally improve the impact energy. DM consistently outperformed OT in the impact energy for angle specimens, while OT showed superior performance in stair specimens. Finally, a case study demonstrates the potential for combining OT and DM structures to guide crack propagation along predetermined paths, offering a novel approach to protect critical components during product failure.
Sorption Properties of Bentonite-Based Organoclays with Amphoteric and Nonionic Surfactants in Relation to Polycyclic Aromatic Hydrocarbons
Authors: Dudnikova Tamara , Burachevskaya Marina , Minkina Tatyana , Mandzhieva Saglara , Zamulina Inna , Perelomov Leonid , Gertsen Maria
Published: November 2024

Polycyclic aromatic hydrocarbons (PAHs) are a major scientific challenge due to their profound impact on public and environmental health. Therefore, studying ways to detoxify PAHs is important. In this research, the adsorption ability of bentonite modified with five surfactants, including amphoteric (cocoamphodiacetate disodium and sodium cocoiminodipropionate) and nonionic (lauramine oxide, cocamide diethanolamine, and alkylpolyglucoside) substances for the adsorption of high-molecular benzo(a)pyrene and low-molecular naphthalene from the PAH group was studied. The bentonite and bentonite-based organoclays were characterized using X-ray diffraction and Fourier transform infrared spectroscopy. The results showed that the maximum adsorption of benzo(a)pyrene by organoclays increased compared with the initial mineral. The adsorption of benzo(a)pyrene is higher than that of naphthalene. The adsorption process of benzo(a)pyrene by bentonite and organoclays is predominantly monolayer, as it is better described by the Langmuir model (R2 0.77–0.98), while naphthalene is predominantly multilayer, described by the Freundlich model (R2 0.86–0.96). According to the effectiveness of sorption capacities of organoclays—including the degree of sorption, Langmuir and Freundlich constants, the value of maximum adsorption, Gibbs free energy, and the index of favorability of the adsorption process—the most effective modification was found. For the adsorption of benzo(a)pyrene the best was cocoamphodiacetate disodium, and for naphthalene it was sodium cocoiminodipropionate.
Investigating the Timing of Carbonate Precipitations and Their Potential Impact on Fossil Preservation in the Hell Creek Formation
Authors: Yamamura Daigo
Published: November 2024

Because fossilized skeletal remains and enclosing sedimentary rocks experience similar diagenetic conditions (i.e., temperature, pressure, and pore fluid interaction,) enclosing sedimentary rocks may provide insight into bone diagenesis. A fossil assemblage, including in situ dinosaur fossils, was discovered in Makoshika State Park near Glendive, MT. Fossil-bearing sandstone is a crevasse splay deposit, and fossils show no sorting or preferred orientation. Bone-bearing sandstone exhibits evidence for intense diagenesis, suggesting a maximum temperature of ~90 °C. Concretion associated with fossils includes two distinctive matrices: dark- and light-colored matrices. Another concretion was found in channel sandstone near the base of the outcrop. These carbonate phases have distinctive isotopic compositions; δ13C values for dark-colored matrices, light-colored matrices, and spheroidal concretion are −7.5, 2.1, and −22.4‰ (VPDB), respectively, and their δ18O values are 16.4, 25.9, and 17.8‰ (VSMOW), respectively. In contrast, fossilized bone δ13C and δ18O values were −4.4‰ (VPDB) and 20.6‰ (VSMOW), respectively, suggesting fractionation with pore fluid was limited. Early carbonate precipitation evidenced by grain coating may have reduced interaction between pore fluids and fossils. Although concretion formation and permineralization do not appear to directly aid in fossil preservation, concretions preserve valuable evidence for diagenetic history.
Reply to Hosseini Monjezi, B.; Lützenkirchen, J. Comment on “Zhou et al. Adsorption Behaviors of Lanthanum (III) and Yttrium (III) Ions on Gibbsite. Minerals 2023, 13, 1530”
Authors: Zhou Zongke , Wan Quan , Yu Wenbin , Nie Xin , Yang Shuguang , Yang Shuqin , Qin Zonghua
Published: November 2024

The interaction between aluminum (hydr)oxides and inorganic substances has received widespread attention in the fields of ore deposit geochemistry, mineral processing, and environmental protection [...]
Petrogenesis and Geochronology of Late Devonian Intrusive Rocks in Eastern Tianshan, Xinjiang, China: Subduction Constraints of the North Tianshan Ocean
Authors: Meng Yong , Zhang Xin , Wang Kai , Zhao Haibo , Han Yuan , Qi Yaogang , Li Zuochen
Published: November 2024

We conducted a study on the petrology, geochemistry, and zircon U–Pb dating of Late Devonian intrusive rocks in the Tulargen area of the Eastern Tianshan Orogenic Belt, Xinjiang, China. These intrusive rocks primarily consist of gabbro (382 ± 5 Ma), tonalite (370.9 ± 2.7 Ma), and biotite monzogranite (362.8 ± 4.4 Ma). Gabbro belongs to the low-K calc-alkaline series of quasi-aluminous rocks, with a high Al2O3 content (16.46–20.34 wt.%) and Mg# value (64.55–67.73). Tonalite and biotite monzogranite, which belong to the high-K calc-alkaline series, are metaluminous or weakly peraluminous and also exhibit high Al2O3 contents (14.6–15.87 wt.%) and Mg# values (40.12–62.47). These rocks are enriched in light rare-earth and large-ion lithophile elements (Rb, Ba, and K) and depleted in heavy rare-earth and high-field-strength elements (e.g., Ta, Nb, and Ti), characteristics typical of island-arc magmatic rocks. Gabbro melts are primarily derived from the mantle and result from the partial melting of a depleted mantle that has undergone fluid metasomatism due to subducted plates. Tonalite exhibits high 176Hf/177Hf and εHf(t) values, with a younger two-stage model age (tDM2) derived from partial juvenile crust melting. The source magma of the biotite monzogranite originated from partial metabasalt melting at a medium crustal depth combined with a new lower crustal material. We concluded that the Late Devonian intrusive rocks in this area formed within the island-arc tectonic setting are associated with the subduction of the North Tianshan Ocean.
Harnessing a Safe Novel Lipid Nanoparticle: Targeted Oral Delivery to Colonic Epithelial and Macrophage Cells in a Colitis Mouse Model
Authors: Mow Rabeya Jafrin , Kuczma Michal Pawel , Shi Xiaodi , Mani Sridhar , Merlin Didier , Yang Chunhua
Published: November 2024

A novel lipid nanoparticle (nLNP), formulated with three essential lipids to mimic ginger-derived exosomal particles, shows strong potential for delivering IL-22 mRNA specifically to the colon, presenting a unique oral drug delivery system for inflammatory bowel disease (IBD). However, its cellular targets and uptake behavior in healthy versus diseased colons remain unclear. Understanding these aspects is crucial for fully elucidating its targeting effectiveness in inflamed colon tissue. This study investigates the nLNP’s cellular targets in healthy and diseased mouse colons. Flow cytometry compared nLNP uptake in healthy mice and a DSS-induced acute colitis model. The results revealed efficient internalization of nLNP by colonic epithelial cells in healthy and inflamed mice. In non-inflamed mice, the small number of colonic macrophages resulted in minimal uptake of nLNP by these cells. In inflamed mice, macrophages migrated to the damaged epithelium, where nLNP uptake was significantly increased, highlighting the nLNP’s ability to target both epithelial and macrophage cells during inflammation. Additionally, safety assessments showed that the nLNP neither altered in vitro kinase activities nor exhibited immunotoxicity or induced in vivo toxicity at the maximum tolerated oral dose. These findings underscore the nLNP’s safety and potential as a promising epithelial/macrophage-targeted drug delivery platform for oral ulcerative colitis (UC) treatment.
The Effect of Solute Elements Co-Segregation on Grain Boundary Energy and the Mechanical Properties of Aluminum by First-Principles Calculation
Authors: Zhang Xuan , Wan Yuxuan , Chen Cuifan , Zhang Liang
Published: November 2024

The segregation of solute atoms at grain boundary (GB) has an important effect on the GB characteristics and the properties of materials. The study of multielement co-segregation in GBs is still in progress and deserves further research at the atomic scale. In this work, first-principles calculations were carried out to investigate the effect of Mg and Cu co-segregation on the energetic and mechanical properties of the Al Σ5(210) GB. The segregation tendency of Mg at the GB in the presence of Cu is characterized, indicating a preference for substitutional segregation far away from Cu atoms. Cu segregation can facilitate the segregation of Mg due to their mutual attractive energy. The GB energy results show that Mg and Cu co-segregation significantly decreases GB energy and thus enhances the stability of the Al Σ5(210) GB. First-principles tensile test calculations indicate that Cu effectively counteracts the weakening effect of Mg segregation in the GB, particularly with the high concentration of Cu segregation. The phenomenon of Cu compensating the strength of the GB is attributed to an increase of charge density and the formation of newly formed Cu-Al bonds. Conversely, Mg segregation weakens the strengthening effect of Cu on the GB, but it can increase the strength of the GB when high concentrations of Cu atoms are present in the GB. The ICOHP and Bader charge analysis exhibits that the strengthening effect of Mg is attributed to charge transfer with surrounding Al and Cu, which enhances the Cu-Al and Al-Al bonds. The results provide a further understanding of the interplay between co-segregated elements and its influence on the energetic and mechanical properties of grain boundary.
Structural, Mechanical, and Optical Properties of Laminate-Type Thin Film SWCNT/SiOxNy Composites
Authors: Shmagina Elizaveta , Antonov Maksim , Kasikov Aarne , Volobujeva Olga , Khabushev Eldar M. , Kallio Tanja , Bereznev Sergei
Published: November 2024

The development of new encapsulating coatings for flexible solar cells (SCs) can help address the complex problem of the short lifespan of these devices, as well as optimize the technological process of their production. In this study, new laminate-type protective composite coatings were prepared using a silicon oxynitride thin-film matrix obtained by curing the pre-ceramic polymer perhydropolysilazane (PHPS) through two low-temperature methods: (i) thermal annealing at 180 °C and (ii) exposure to UV radiation at wavelengths of 185 and 254 nm. Single-walled carbon nanotubes (SWCNTs) were used as fillers via dry transfer, facilitating their horizontal orientation within the matrix. The optical, adhesive, and structural properties of the matrix films and SiOxNy/SWCNT composite coatings, along with their long-term stability, were studied using Fourier transform infrared spectroscopy (FTIR), UV-Vis spectroscopy, HR-SEM, spectral ellipsometry, and a progressive-load scratch test. In this work, the optical constants of PHPS-derived films were systematically studied for the first time. An antireflection effect was observed in the composites revealing their two-component nature associated with (i) the refractive index of the SiOxNy matrix film and (ii) the embedding of a SWCNT filler into the SiOxNy matrix. The curing method of PHPS was shown to significantly affect the resulting properties of the films. In addition to being used as protective multifunctional coatings for SCs, both SiOxNy/SWCNT composites and SiOxNy matrix films also function as broadband optical antireflective coatings. Furthermore, due to the very low friction coefficients observed in the mechanical tests, they show potential as scratch resistant coatings for mechanical applications.
The Role of Freeze-Drying as a Multifunctional Process in Improving the Properties of Hydrogels for Medical Use
Authors: Odziomek Kacper , Drabczyk Anna K. , Kościelniak Paulina , Konieczny Patryk , Barczewski Mateusz , Bialik-Wąs Katarzyna
Published: November 2024

Background/Objectives: Freeze-drying is a dehydration method that extends the shelf life and stability of drugs, vaccines, and biologics. Recently, its role has expanded beyond preservation to improve novel pharmaceuticals and their carriers, such as hydrogels, which are widely studied for both drug delivery and wound healing. The main aim of this study was to explore the multifunctional role of freeze-drying in improving the physicochemical properties of sodium alginate/poly(vinyl alcohol)-based hydrogels for medical applications. Methods: The base matrix and hydrogels containing a nanocarrier-drug system, were prepared by chemical cross-linking and then freeze-dried for 24 h at −53 °C under 0.2 mBa. Key analyses included determination of gel fraction, swelling ratio, FT-IR, SEM, TG/DTG, in vitro drug release and kinetics, and cytotoxicity assessment. Results: Freeze-drying caused an increase in the gel fraction of the hydrogel with the dual drug delivery system from 55 ± 1.6% to 72 ± 0.5%. Swelling ability was pH-dependent and remained in the same range (175–282%). Thermogravimetric analysis showed that freeze-dried hydrogels exhibited higher thermal stability than their non-freeze-dried equivalents. The temperature at 10% weight loss increased from 194.0 °C to 198.9 °C for the freeze-dried drug-loaded matrix, and from 188.4 °C to 203.1 °C for the freeze-dried drug-free matrix. The average pore size of the freeze-dried hydrogels was in the range of 1.07 µm ± 0.54 to 1.74 µm ± 0.92. In vitro drug release revealed that active substances were released in a controlled and prolonged way, according to the Korsmeyer–Peppas model. The cumulative amount of salicylic acid released at pH = 9.0 after 96 h was 63%, while that of fluocinolone acetonide reached 73%. Both hydrogels were non-toxic to human fibroblast cells, maintaining over 90% cell viability after 48 h of incubation. Conclusions: The results show a high potential for commercialisation of the obtained hydrogels as medical dressings.
Introduction: Is Environmental Virtue Ethics a ‘Virtuous’ Anthropocentrism?
Authors: Pouteau Sylvie , Hess Gérald
Published: November 2024

The field of environmental ethics has been built as a response to environmental blindness [...]
When Communicative Worlds Collide: Strategies for Negotiating Misalignments in Attentional Social Presence
Authors: Turner Jeanine Warisse , Foss Sonja K.
Published: November 2024

A significant issue facing communicators in the current multicommunicative environment is securing the attention of potential audience members who are likely to be engrossed in their digital devices. The theory of attentional social presence suggests that communicators secure their attention using one of four types of social presence—budgeted, competitive, entitled, and invitational. In this essay, the theory of attentional social presence is extended by identifying strategies interactants use to resolve misalignments in expected or preferred types of social presence. The research design involved interviews with 32 individuals about their experiences with misalignment in attentional social presence. Transcripts of the interviews were coded following the qualitative approach of grounded theory. Three primary strategies emerged from the analysis—prescribing to eliminate misalignment, rationalizing to overlook misalignment, and co-creating to resolve misalignment. Understanding various methods for negotiating mismatches among chosen types of social presence will allow communicators to create more satisfying and productive interactions.
High-Performance Vis–NIR Photodetectors Based on Two-Dimensional Bi2Te3 Thin Film and Applications
Authors: Fu Zhendong , Liu Xuefang , Wang Fuguo , Du Langlang , Sun Wenbao , Sun Yueyu , Song Xiaoxian , Zhang Haiting , Yao Jianquan
Published: November 2024

Two-dimensional materials have excellent optoelectronic properties and have great significance in the field of photodetectors. We have prepared a thin film photodetector based on bismuth telluride (Bi2Te3) topological insulator using dual-temperature-zone vapor deposition technology. Due to the high-quality lattice structure of Bi2Te3 and the uniform and dense surface morphology of the Bi2Te3 thin film, the device exhibits excellent photoelectric response and Vis–NIR spectral range. Under 405 nm illumination, the responsivity is 5.6 mA/W, the specific detectivity is 1.22 × 107 Jones, and the response time is 262/328 ms. We designed a photodetector single-point scanning imaging system and successfully achieved high-resolution imaging at a wavelength of 532 nm. This work provides guidance for the application of two-dimensional materials, especially Bi2Te3, in the fields of photodetectors and imaging.
High-Extinction Photonic Filters by Cascaded Mach–Zehnder Interferometer-Coupled Resonators
Authors: Chen Hao-Zhong , Ho Kung-Lin , Wang Pei-Hsun
Published: November 2024

In this study, we demonstrate high-extinction stop-band photonic filters based on Mach–Zehnder interferometer (MZI)-coupled silicon nitride (Si3N4) resonators fabricated using I-line lithography technology. Leveraging the low-loss silicon nitride waveguide, our approach enables the creation of stable, high-performance filters suitable for applications in quantum and nonlinear photonics. With destructive interference at the feedback loop, photonic filters with an extinction ratio of 35 dB are demonstrated with four cascaded MZI-coupled resonators. This cascading design not only enhances the filter’s extinction but also improves its spectral sharpness, providing a more selective stop-band profile. Experimental results agree well with the theoretical results, showing linear scaling of extinction ratios with the number of cascaded MZI-coupled resonators. The scalability of this architecture opens the possibility for further integration and optimization in complex photonic circuits, where high extinction ratios and precise wavelength selectivity are critical for advanced signal processing and quantum information applications.
Analysis of the Optimum Performance for Polymer and Polymer–Nanocomposite-modified Asphalt by Using Multicriteria Decision Analysis
Authors: Alas Mustafa , Albrka Shaban Ismael , Eltwati Ahmed , Ali Ahmed Suliman B. , Al Allam Allam Musbah
Published: November 2024

The influence of Acrylate Styrene Acrylonitrile (ASA) and ASA/nanosilica (ASA/Si) additives was investigated by using a dynamic shear rheometer (DSR). Firstly, an ASA polymer was blended with the virgin asphalt binder at two different concentrations (3% ASA and 5% ASA). After observing that 5% ASA was the optimum concentration for modification, nanosilica particles were further incorporated into the 5% ASA-modified asphalt binder with two different percentages (5% ASA 3%Si; 5% ASA 5%Si). Frequency sweep tests were conducted across various frequencies at elevated temperatures. The experimental outcomes were analyzed using master curves, rutting, and fatigue resistance parameter plots. Additionally, to provide a more holistic analysis, two different multicriteria decision analysis (MCDA) techniques, namely the Preference Ranking Organization Method for Enrichment Evaluations (PROMETHEE) and the Technique for the Order of Preference by a Similarity to Ideal Solution (TOPSIS), were conducted to identify the best-performing asphalt binder by considering three different parameters: workability, performance under different conditions, and cost. The frequency sweep tests showed that the 5% ASA 5%Si asphalt worked best in terms of resistance to rutting. On the other hand, the virgin binder performed better than all modified binders when it failed to resist fatigue. On the other hand, the PROMETHEE analysis identified the 5% ASA-modified asphalt binder as the optimal choice, while the TOPSIS analysis determined that the 5% ASA 3%Si-modified binder provided the best performance. The differences between the experimental results and the MCDA were due to using more than one evaluation parameter and looking at how well the asphalt binder worked at different temperature ranges at the same time.
Development and Characterization of 3D-Printed PLA/Exfoliated Graphite Composites for Enhanced Electrochemical Performance in Energy Storage Applications
Authors: dos Santos Ananias Lima , de Souza Francisco Cezar Ramos , Martins da Costa João Carlos , Gonçalves Daniel Araújo , Passos Raimundo Ribeiro , Pocrifka Leandro Aparecido
Published: November 2024

This research introduces a new way to create a composite material (PLA/EG) for 3D printing. It combines polylactic acid (PLA) with exfoliated graphite (EG) using a physical mixing method, followed by direct mixing in a single-screw extruder. Structural and vibrational analyses using X-ray diffraction and Fourier transform infrared spectroscopy confirmed the PLA/EG’s formation (composite). The analysis also suggests physical adsorption as the primary interaction between the two materials. The exfoliated graphite acts as a barrier (thermal behavior), reducing heat transfer via TG. Electrochemical measurements reveal redox activity (cyclic voltammetry) with a specific capacitance of ~ 6 F g−1, low solution resistance, and negligible charge transfer resistance, indicating ion movement through a Warburg diffusion process. Additionally, in terms of complex behavior (electrochemical impedance spectroscopy), the PLA/EG’s actual capacitance C’(ω) displayed a value greater than 1000 μF cm−2, highlighting the composite’s effectiveness in storing charge. These results demonstrate that PLA/EG composites hold significant promise as electrodes in electronic devices. The methodology used in this study not only provides a practical way to create functional composites but also opens doors for new applications in electronics and energy storage.
Wood Plastic Composite Based on Recycled High-Density Polyethylene and Wood Waste (Sawdust)
Authors: Oliveros-Gaviria Camilo , Cumbalaza Edwin , Mina-Hernandez Jose Herminsul , Valencia-Zapata Mayra Eliana , Suarez-Bonilla Juan Nicolas , Martinez-Mera Nicolas
Published: November 2024

The current work presents the reformulation of a composite based on high-density polyethylene obtained through the recycling of blow-molded containers (rHDPE) with natural fiber residues (wood sawdust). This material is technically and industrially known as WPC (wood plastic composite). The original formulation of this material contains 34% high-density polyethylene and 60% sawdust by weight fraction, while the remaining components include additives and coupling agents such as wax (Coupling Agent TPW 813 for plastic woods), stearic acid, and color pigment. The composite material was processed using the profile extrusion method, from which samples were obtained to conduct various experimental tests. The mechanical analysis revealed that both the strength and Young’s modulus of the tensile and flexural properties slightly increased with the addition of sawdust to the composite. Additionally, the stiffness was higher compared to high-density polyethylene, indicating a direct relationship between these properties and the amount of sawdust incorporated. Besides this, other characterization methods were performed on the material, including density, hardness, and compression tests, as well as differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), natural and accelerated aging tests, Vicat softening temperature, and heat deflection temperature analysis (HDT). The initial evaluation provides a guide to enhance the most important properties with the aim of using the extruded profiles as pergolas in the real estate sector. Therefore, new formulations are developed with the assistance of Minitab 21 software, maintaining a constant proportion of materials that do not affect the mechanical properties, such as wax, stearic acid, and color pigment. Once the formulations are made, each one is characterized through tensile tests to determine which has the best performance. The formulation with the highest strength is re-characterized using the techniques mentioned in the starting material to obtain a material with the most optimal characteristics.
Synthesis and Evaluation of Polyurethane as Waterproof Adhesion Layer for Steel Bridge Deck
Authors: Chen Yan , Hu Jianying , Wu Xiaonan , Duan Shaochan , Wang Hongyu , Ma Tao
Published: November 2024

Service life of traditional steel bridge deck pavement is significantly shortened due to the failure of waterproof adhesion. To improve the interlayer bonding performance and extend its service life, polyurethane is proposed as a waterproof adhesion layer (WAL) for a steel bridge deck. This study aims to synthesize polyurethane WAL by free radical solution polymerization under different types and dosages of crosslinking agents as well as the mixing ratio of an acrylic co-blend. Tensile properties, water resistance, glass transition temperatures, thermal stability, and adhesive strength of the polyurethane binder are evaluated. The results demonstrate that polyurethane WAL yields desirable performance by using a hydroxyl molar ratio of 1/3 and an acrylic co-blend of 65%. Specifically, the tensile strength and breaking elongation of polyurethane WAL reach the maximum values of 6.466 MPa and 268.4%, respectively. The water absorption rate of polyurethane WAL is less than 4%. Glass transition temperatures of polyurethane WAL are between −80 °C and 60 °C, respectively. Polyurethane WAL features remarkable high- and low-temperature performance and thermal stability. Finally, adhesion strength between polyurethane WAL and the steel plate reaches up to 5.21 MPa. The outcome of this study facilitates the design and application of polyurethane waterproofing adhesion layers for steel bridge decks.
Stress Zoning Characteristics of Goaf Side and Quantitative Evaluation of Surrounding Rock Stability
Authors: Zhang Hongkai , Guo Xiaofei , Yang Kunlin
Published: November 2024

Aiming to maintain the stability of the mining roadway and the next working-face roadway in the goaf side of a coal mine, a systematic study was carried out, through theoretical analysis, numerical simulation, field case analysis, and other methods, of the synergistic change mechanism in the stress distribution and plastic zone development morphology of the roadway’s surrounding rock in the goaf side under mining disturbance. It was revealed that, under the influence of mining, the goaf side will form a high-deviatoric-stress environment, which directly affects the shape and stability of the plastic zone of the roadway’s surrounding rock. Based on the characteristics of the principal stress ratio and the morphological development law of the plastic zone of the surrounding rock, the side of the goaf is divided into four regions: unloading zone, high-deviatoric-stress zone, low-deviatoric-stress zone, and original-stress zone. And the corresponding mine pressure behavior zoning is proposed: fracture zone, butterfly failure zone, elliptical failure zone, and circular failure zone. A quantitative evaluation method for the stability of the roadway surrounding rock based on the plastic zone morphology criterion was established, and combined with the division of mine pressure, the stability of the surrounding rock on the side of the goaf was quantitatively evaluated.
Numerical Simulation of the Coal Measure Gas Accumulation Process in Well Z-7 in Qinshui Basin
Authors: Yan Gaoyuan , Song Yu , Quan Fangkai , Cheng Qiangqiang , Wu Peng
Published: November 2024

The process of coal measure gas accumulation is relatively complex, involving multiple physicochemical processes such as migration, adsorption, desorption, and seepage of multiphase fluids (e.g., methane and water) in coal measure strata. This process is constrained by multiple factors, including geological structure, reservoir physical properties, fluid pressure, and temperature. This study used Well Z-7 in the Qinshui Basin as the research object as well as numerical simulations to reveal the processes of methane generation, migration, accumulation, and dissipation in the geological history. The results indicate that the gas content of the reservoir was basically zero in the early stage (before 25 Ma), and the gas content peaks all appeared after the peak of hydrocarbon generation (after 208 Ma). During the peak gas generation stage, the gas content increased sharply in the early stages. In the later stage, because of the pressurization of the hydrocarbon generation, the caprock broke through and was lost, and the gas content decreased in a zigzag manner. The reservoirs in the middle and upper parts of the coal measure were easily charged, which was consistent with the upward trend of diffusion and dissipation and had a certain relationship with the cumulative breakout and seepage dissipation. The gas contents of coal, shale, and tight sandstone reservoirs were positively correlated with the mature hydrocarbon generation of organic matter in coal seams, with the differences between different reservoirs gradually narrowing over time.
Impact of Acid Rain on Release Characteristics of Heavy Metals in Low-Sulfur Tailings with Strong Acid Neutralization Capacity: A Case Study from Northern Guangxi, China
Authors: Shu Xiaohua , Zhang Dinghua , Zhang Qian , Ai Tao , Zhang Xuehong , Liu Jie
Published: November 2024

Tailing ponds are major sources of heavy metal pollution. Previous studies primarily focused on tailings with high sulfur content, with limited attention to low-sulfur tailings. This study explored the release behavior of Pb, Zn, and Cd from low-sulfur tailings under simulated acid rain conditions, considering factors such as pH, particle size, and weathering degree. Samples were collected from a lead–zinc tailing pond in the karst regions of northern Guangxi, China. Batch leaching experiments indicated that even with high acid neutralization capacity (ANC = 166.57–167.45 kg H2SO4/t), substantial heavy metal leaching occurred under acidic conditions (pH 2–3), with Pb, Zn, and Cd concentrations increasing 4–6 times compared to neutral conditions. Leachate concentrations were slightly higher in coarser particles than in finer ones, while weathering further enhanced metal release, particularly for Cd. These findings suggest that acid neutralization alone may not be sufficient to prevent heavy metal leaching in low-sulfur tailings exposed to acid rain. However, due to the laboratory scale of this study, further validation through field-scale or mesocosm experiments is necessary to confirm the observed trends and assess their implications for environmental risk management in karst regions.