bluuebunny/crossref_metadata_2025 huggingface dataset:
The intersectionality of race, disability, gender, and employment through the Project SEARCH lens
Authors: Buncher Amanda , Daston Maryellen
Published: May 2022

BACKGROUND: People with intellectual and developmental disabilities (IDD) face chronically low rates of employment and high rates of poverty. These effects are amplified for women and ethnic minorities. Project SEARCH was developed to help address this disparity in employment. OBJECTIVE: This report looks at the demographic make-up of Project SEARCH participants and compares employment outcomes by gender, race and ethnicity, and disability type. METHODS: Authors examined data from 3,773 interns in the United States during the 2018-19 program year. Data were entered by representatives of 523 licensed program sites into the Project SEARCH database, which is accessed via a secure online Member Portal. RESULTS: The demographic make-up of Project SEARCH interns was representative of the U.S. population, but with some overrepresentation of racial and ethnic minorities and underrepresentation of females, consistent with patterns of enrollment in special education. There were no large differences in employment outcomes of Project SEARCH graduates based on race, ethnicity, gender, or disability type. Some small differences were observed, and these will be explored further in future studies. CONCLUSIONS: Project SEARCH serves a diverse population effectively and equitably. However, there are some differences in outcomes that warrant further investigation.
An evaluation of pre-qualification respiratory physiotherapy curricula on the island of Ireland
Authors: Fullen Brona M. , O’ Shea Orlagh , O’ Neill Brenda , Moran Fidelma , Cahalan Roisin , Phelan Deirdre , Hanrahan Ciara , Broderick Julie
Published: May 2022

BACKGROUND: Respiratory physiotherapy is a core area of practice, but little is known about pre-qualification physiotherapy curricula across institutions. The purpose of this study was to identify and categorise the pre-qualification content of respiratory physiotherapy curricula across the island of Ireland. METHODS: This cross-sectional survey was conducted remotely and eight respiratory module coordinators/teaching leads participated. Respiratory physiotherapy curricular topics and assessment details from each participating institution were documented. Curricular topics were then grouped and categorised into discrete broader curricular topic areas by agreement. A representative from each higher education institution rated the curricular topic from their programme as ‘foundation’, ‘core’, ‘not essential but desirable’ or ‘broadly relevant’. Assessment strategies for each programme were documented. RESULTS: From 246 individual topics, seven broad category areas were generated which were operationally defined and divided into 41 content topics. Of the content topics 18 out of 41 (44%) topics were unanimously rated as core to the respiratory module by each participating programme. A diverse range of assessment strategies were employed across programmes with all including written and practical components. CONCLUSION: Between programmes and institutions, there was a reasonably high degree of overlap of the respiratory physiotherapy topic areas which are delivered within or outside of core respiratory modules. Content appears to be broadly standardised and appears to support the preparedness of graduates for practice in this area. The identification of ‘core’ respiratory topics in this study may be useful for the design of new respiratory physiotherapy modules or ongoing curricular review.
Factors influencing the analytical representation of creep crack development in Alloy 939
Authors: Holdsworth S.R.
Published: May 2022

Creep crack growth rates originally gathered for the 𝛾′ strengthened cast nickel based superalloy Alloy-939 in terms of apparent stress intensity factor are re-evaluated as a function of the time dependent C* parameter, with crack propagation rates being insensitive to grain size at 750 and 850 °C. However, whereas a˙C(Ka) rates at 750 °C are significantly lower than those at 850 °C, equivalent a˙C(C*) rates are relatively insensitive to temperature, comparing well with the plane strain a˙C(C*) rates predicted using an approximate reference stress based C* model. While overall CT-specimen creep crack growth times for Alloy-939 can be predicted using uniaxial creep-rupture strength data when expressed in terms of reference stress at 850 °C, this appears not to be possible at 750 °C. The observation is explained with respect to evidence provided by a modified time dependent failure assessment diagram. The influence is examined of thermal transient durations at 850 °C (from 750 °C), or at 750 °C (from 850 °C) on a˙C(Ka) creep crack growth rates and tR(𝜎ref) overall lives.
How do implant threads and diameters affect the all-on-four success? A 3D finite element analysis study
Authors: Zor Zeynep Fatma , Kılınç Yeliz , Erkmen Erkan , Kurt Ahmet
Published: May 2022

BACKGROUND: The effect of different thread designs and diameters on the all-on-four concept is unclear. OBJECTIVE: The aim of the study was to clarify the differences in stress distribution of dental implants with various thread designs and diameters based on the all-on-four concept with three dimensional (3D) finite element analysis (FEA). METHODS: A 3D model of a totally edentulous mandible was used to perform the FEA. Four different models (M1, M2, M3, and M4) including 3.5 and 4.3 mm diameter dental implants with active and passive threaded designs were generated. The dental implants were positioned according to the all-on-four concept. The Von Mises stresses on dental implants and maximum and minimum principal stresses (Pmax and Pmin) on bony structures were calculated under vertical, oblique and horizontal loads. RESULTS: For Von Mises stresses, the highest stress values were detected on the distal implants for all models. Distal implants had also the highest stress values for vertical loading. The Von Mises stresses were found to be concentrated around the implant’s neck. In all models the highest Pmax and Pmin stresses occurred in the bone surrounding the distal implant. It was noted that the active threaded implants showed the highest Pmax and Pmin stress values. CONCLUSION: The implant thread design and diameter might have a strong influence on the stress values in the all-on-four concept.
Is zirconium or stainless steel the most suitable crown material for less dentin stress in endodontically treated teeth?
Authors: Guduk Omer Faruk , Sivrikaya Efe Can , Yilmaz Nagehan , Baygin Ozgul , Tuzuner Tamer
Published: May 2022

BACKGROUND: Stainless steel crowns (SSCs), which have been used frequently in the treatment of first permanent molars in children until now, has become less applicable due to its poor aesthetic appearance. Zirconia crowns (ZCs) have become more popular due to their aesthetic advantage. However, stress transmission of ZCs to dental tissues under occlusal forces in endodontically treated teeth has not been described. OBJECTIVE: The aim of this study was to compare the stress distribution of different crown materials (ZCS, SSCs) and adhesive materials on dentin in endodontically treated permanent teeth and to specify the crown-adhesive model with lower stress. METHODS: Finite element analysis (FEA) was used to apply a force of 300 N from the inner part of the buccal tubercles (vertical loading) and a lingo-buccal at an angle of 30 degrees (oblique loading) of the first permanent molars (FPM) with different crown (ZCS, SSCs) and adhesive (Glass ionomer cement, Resin modified glass ionomer cement, Resin cement) materials in twelve separate models. The von Mises values obtained from the models were compared and the optimal stress values were determined by FEA. RESULTS: The lowest stress values of dentin were found in zirconia crown model with glass ionomer cement (GIC) adhesive under vertical loading (26,793 Mpa). In the zircon crown and GIC adhesive model, less von Mises stress occurred on the dentin under all conditions. CONCLUSIONS: ZCs and GIC adhesive may be recommended for teeth with a high probability of dentin fracture.
FEATURES OF PROVING FORENSIC GENETIC EXAMINATION FOR KINSHIP, PATERNITY, MATERNITY IN CIVIL PROCEEDINGS
Authors:   Alfred Nobel University, Todoroshko Tetiana А. , Bila Аlona V. ,   Alfred Nobel University
Published: May 2022

This article is devoted to the problem of the use of forensic genetic examination in civil proceedings as a means of proof. The urgency of the topic is determined by the fact that forensic examinations and research using DNA analysis are currently the only scientific method of accurately establishing kinship between individuals. DNA profile analysis is individual in nature and is accepted by the court only as an analysis made by public laboratories, which must serve as unbiased evidence. In addition, to date, the country has a situation related to hostilities in the area of the Anti-Terrorism Operation in eastern Ukraine, and there is an urgent question about the identification of human remains. The article analyzes three stages of forensic examination, namely a limited list of materials for DNA testing, regulations for delivery of samples in accordance with the law, registration of examination results and transmission to the customer in the form of an expert opinion. It is noted that if there is an interest in conducting an additional independent examination, it is possible to contact a foreign laboratory to obtain reliable results of the analysis. In cases of disputed paternity, a forensic examination is conducted exclusively by an employee of the center - a forensic expert who is entrusted with the examination. The selection is carried out subject to the simultaneous appearance of the probable father, mother and child with the presentation of original identity documents: passports for probable parents and birth certificates for the child. According to the Code of Civil Procedure of Ukraine, any evidence regarding the origin of paternity, maternity, kinship may be grounds for establishing this fact. But evidence such as photographs, videos, letters, and witness testimonies cannot properly establish family ties. This increases the importance of forensic genetic examination in the system of evidence. Therefore, the circumstances of the case, which by law must be confirmed by certain means of proof, cannot be confirmed by other means of proof. Based on this, it is emphasized the need to amend the Family Code, which will determine that forensic examination should be the only means of proof in cases of establishing the fact of family ties. Thus, it is necessary to bring the consideration of such cases to a single approach. Another problem - the problem of delaying these categories of cases - should be solved with the help of the Civil Procedure Code of Ukraine, which should specify the provision on the need to conduct a mandatory examination in court at the preparatory stage of civil proceedings. The article also substantiates the proposal to introduce a single register of genetic expertise (genomic information), which will have a wider range of modern possibilities in the theory of evidence.
JUDICIAL PRACTICE ON THE ADOPTION OF DECISION ON CONFORMITY OF VALUE ADDED TAXPAYER TO THE CRITERIA OF THE TAXPAYER’S RISK BY THE STATE TAX SERVICE BODIES OF UKRAINE
Authors:   Alfred Nobel University, Voronin Vladislav V.
Published: May 2022

The article is devoted to the analysis of judicial practice on the recognition by the State Tax Service bodies of Ukraine (hereinafter - the State Tax Service of Ukraine) of the competence of the value added taxpayers to the risk criteria of taxpayers. This article analyzes the grounds for making decisions on compliance of value added taxpayers with the taxpayer’s risk criterion, analyzes such taxpayer risk criteria, provides analysis of decisions of the Supreme Court of Ukraine and lower courts concerning disputes on recognition of taxpayers’ compliance with risk criteria, the validity and legality of the legal position of the State Tax Service of Ukraine and the legality of such actions by regulatory authorities in terms of electronic document management and compliance with their defined procedure. The problematic issues that have arisen in the tax sphere in electronic document management are identified and solutions are proposed. It is determined that one of the problematic areas of value added tax administration is the adoption of decisions by regulatory authorities on compliance of taxpayers with risk criteria. The terminology is analyzed and it is determined that the value added tax (hereinafter - VAT) is an indirect tax, which is determined and levied in accordance with the provisions of the current Tax Code of Ukraine (hereinafter - the Tax Code of Ukraine). Therefore, VAT is a national indirect, ie one that is a component of prices for goods, works and services supplied and provided, and includes tax liabilities for goods and services supplied, tax credit for such goods (services) and obligations the payment of tax to the state budget. It is analyzed that the taxpayer is obliged to draw up a tax invoice and register in the Unified Register of Tax Invoices, have the necessary economic and industrial capabilities, staff, etc., to carry out business operations for the supply of goods, works or services declared activity. In addition, the laws of Ukraine establish clear grounds for suspending the registration of tax invoices, including compliance of the taxpayer with the risk criterion. Thus, the legislator has defined a clear list of conditions under which at least one of which, namely but not limited to registration on invalid documents, lack of open bank accounts, failure to report VAT and the availability of regulatory authorities information about the risk of business transactions. Such inclusion of the payer in the list of risk puts the company in a critical position and virtually terminates the activities of the payer and its counterparties in the tax chain, as all tax credit received from such a company is blocked, which creates additional tax burden on business.
FORMATION OF COMPETENCE OF THE LOCAL AUTHORITY SELF-GOVERNMENT AS THE MAIN PHENOMENOLOGY OF DECENTRALIZATION OF POWERS OF PUBLIC AUTHORITY IN UKRAINE
Authors:   Main Department tax service of Ukraine in Odessa region, Baymuratov Maxim M.
Published: May 2022

The article is devoted to the study of the formation of competence of the local authority selfgovernment as the main phenomenology of decentralization of powers of public authority in Ukraine. The author notes that the world experience and the experience of independent development of Ukraine suggest that the most productive mechanism for uniting society around the fundamental values of civil society is the development of local self-government. The article is devoted to large-scale reform of local self-government, which is aimed at overcoming the centralized Soviet system and the formation of a decentralized system of local government, as well as increasing the powers of self-governing bodies to develop the territories. Some particularly problematic issues have been studied, which significantly hinder the solution of current problems in the field of “competence content” of public authorities. These include the lack of general theoretical definition of competence, lack of scientific understanding of the system of properties of competence, as well as recognition of the existence and formation of their own competence in local governments as self-governing (municipal) public authorities. The author points out that the success of the reform of decentralization of public power in the framework of municipal reform leads to the transformation of the competencies of local governments, especially in the context of forming a block of powers of their own competence and executive bodies. The author of the article offers an ontological and axiological analysis of the sphere of competence of local self-government bodies in its modern sense. It is emphasized that the “alpha and omega” of the competence of local governments should be strategic procedural guidelines that reflect the dependence of the competences of local public authorities on the interests and will of residents of local communities. It is revealed that the system of individual, group and collective interests of a person determines the objectification of the need to form their own competence for local governments. It is a doctrinal conclusion that the process of reforming public authorities is directly related to the process of forming the competence of local governments, which in conditions of decentralization and deconcentration, form their own competence base of powers and subjects. The topical issues of forming the own competence of the local self-government body are given and analysed. The author of the article argues that this process is the main phenomenology of decentralization of public authority in Ukraine. The author’s opinion is substantiated that decentralization is one of the most successful reforms of recent times, but at the same time, some problems of both organizational and applied nature remain unresolved, which negatively affects the prospects of decentralization in Ukraine.
HUMAN RIGHTS CITIES AS A NEW PHENOMENON OF THE MODERN MUNICIPAL DEVELOPMENT
Authors:   Alfred Nobel University, Bocharova Natalia V.
Published: May 2022

This article is devoted to the one of the significant phenomena of recent decades in the area of municipal government has been the emergence on a global scale of cities that have declared themselves human rights defenders or of human rights cities. Scientific understanding and analysis of the process of emergence of human rights cities began in parallel with the emergence of this paradox of urban development in foreign countries. One of the first European cities where human rights became part of municipal politics was Barcelona. It was here that the position of Commissioner for Civil Rights was founded, which later became the Barcelona Department of Civil Rights. The initiative was carried out in order to overcome the effects of «new» waves of migration and the growing racial, ethnic and religious diversity in the city. New perspectives on human rights cities were defined at the latest World Urban Human Rights Forum (WHRCF), an annual event in Gwangju, the Republic of Korea. This year the Forum was held from 7 to 10 October with the theme: «Human rights in times of challenge: a new social contract». In total, 3012 participants from 76 countries and 322 cities from all over the world took part in the event. The Final Declaration of the 11th Forum of WHRCF expresses deep concern about the diverse threats to human rights and democracy due to violence, discrimination, inequality, sustainable development, climate change and environmental disasters and identifies five areas for further work. The article examines the use in the practice of municipal administration of foreign countries for the protection of human rights, defined in international human rights documents at the global and regional levels. The reasons and factors for the involvement of cities in human rights activities are analyzed, specific examples of the work of local governments to ensure both the entire spectrum of internationally recognized human rights and certain areas of combating racism, discrimination, xenophobia and exclusion are given. The examples given in this article testify to the presence of a steady trend of involving modern cities in human rights activities. This world experience needs to be carefully studied and implemented in the practice of municipal government in Ukraine. Modern crisis phenomena, such as the coronavirus pandemic or the migrant crisis in Europe, make this task even more relevant. It is concluded that this world experience requires careful study and implementation in the practice of municipal government in Ukraine. Modern crisis phenomena, such as the coronavirus pandemic or the migrant crisis in Europe, make this task even more relevant.
THE ROLE OF TERRITORIAL COMMUNITIES IN THE FORMATION OF PHENOMENOLOGY OF MODERN ECOLOGICAL CONSTITUTIONALISM
Authors:   Institute of Legislation of The Verkhovna Rada of Ukraine, Potapchuk Anna V.
Published: May 2022

The article is devoted to the study of the phenomenology of environmental constitutionalism in terms of the influence of local communities on environmental human rights, providing them with new content and local content in the global environmental crisis, constitutionalization of legal systems and the formation of global constitutionalism. The opinion is substantiated that the formation of the constitutional and legal level of environmental human rights is evidence of the state’s recognition of its natural rights through further constitutional legalization, which is especially important in the global environmental crisis. Increasing the level and scope of sufficient quality, proper and optimal constitutional and legal regulation of environmental rights is a reliable guarantee and demonstration of readiness of man, society, state and the entire international community to function sustainably in the new difficult conditions of human existence. It is emphasized that environmental rights, which have a constitutional and normative level, are in fact accompanied by significant meta-legal and quasi-legal phenomena that form the basis of everyday life of a particular person, building, so to speak, the philosophical state of everyday life. The human life cycle takes place at the local level of the society within the territorial community as a territorial human community that exists in the context of local self-government. The author notes that environmental constitutionalism is seen as a complex multilevel, multidimensional, teleological and normatively determined phenomenon at the intersection of national constitutional law, general international law, international human rights law and general environmental law (national and international). It has a direct connection with the person, his groups and groups operating in the relevant territory of a particular state, carrying out its life cycle. That is why territorial communities play a fundamental role in its formation and definition. It is concluded that the above provisions allow us to assert about the phenomenology of environmental constitutionalism that, by and large, it acts as a complex multilevel, multidimensional, teleological and normatively determined phenomenon at the junction of national constitutional law, general international law, human rights law and general environmental law (national and international). They transformed into the object of normative legal identification, historical and legal contextualization and pragmatic axiology from the level of phenomenology and the object of purely applied the scientific and doctrinal level. Because it has a direct connection with the person, his groups and collectives functioning in the corresponding territory of the concrete state, carrying out the life cycle, and territorial communities play in its formation and definition a fundamental role.
If it feeds, it leads : eating, media, identity, and ecofeminist food journalism
Authors:   , Jones Joseph Paul
Published: May 2022

This project explored contemporary food journalism and placed it in the larger context of American history, asking how such media made eating a matter of public concern. In other words, it asked: how does food journalism invite us to our eating identities and what are the ethical obligations of food journalists? I used Critical Discourse Analysis (CDA) to examine three contemporary media outlets, each originating at a different point in food journalism's history: The New York Times Food section, TV Food Network, and Vox Media's Eater. I historically contextualized these outlets and their content, further using them to make a larger critique of the current social order. Incorporating the history of food, media, consumerism, and the political economic institutions of the U.S., I also investigated how the active negotiation of civic/eating/consumer identities transformed into ethically compromised positions of hyperindividualism. This occurred within a context of a neoliberal consensus where market fundamentalism dominates the political conversations of worldmaking. Individuals are now expected to be isolated entrepreneurs, conforming to the needs of 'the market.' I thus argue that food media is neoliberalized and food journalists must match the logic of this worldview or face exclusion from a commercialized attention economy built on surveillance, predictability, and control. Taking the long view, I delineate how the liberalism that created modern journalism transformed into neoliberal media. Keeping residual elements of liberalism's once progressive project, I deconstruct the misguided presuppositions of neo/liberalism and offer a counterhegemonic approach to journalism and food media. Establishing a position of ecofeminist food journalism, I then explore how such media invites new, more caring citizens and better feeds the social and ecological connections necessary for democratic, human, and multi-species flourishing.
Protected percolation: a new universality class pertaining to quantum critical systems
Authors:   , Fayfar Sean Daniel
Published: May 2022

We describe a new universality class - dubbed protected percolation - that we show to be relevant to quantum critical systems. Percolation theory describes phase transitions where long-range order is lost when parts of a system become disconnected from other parts; in the vicinity of the transition, critical behavior is observed, captured by universal power laws. Protected percolation has the added restriction that only sites from the system spanning connection can be removed. We developed a new technique to simulate protected percolation, and we used it to determine the critical exponents of this new universality class in 2, 3, and 4 dimensions. We relate the exponents analytically to those of standard percolation. The Harris criterion predicts whether a phase transition is stable against impurities. We prove that protected percolation violates this criterion in 3 dimensions and higher, implying that impurities result in the loss of universal behavior in systems governed by protected percolation. We investigated the change in critical exponents for various types of impurities, focusing on the case for three dimensions where protected percolation models quantum critical systems. We detail how our simulations can be used for direct comparison to experimental results on such quantum critical systems.
Der rechtliche Rahmen des Flughafens Zürich
Authors: Abegg Andreas
Published: May 2022

Der Flugverkehr verursacht bedeutende Emissionen, weshalb sich der Luftverkehr im Allgemeinen und die Flughafen Zürich AG im Besonderen mit Forderungen zur Reduktion von Lärm und dem Ausstoss von CO2 konfrontiert sehen. Mit Gebühren soll der Zunahme der Emissionen entgegengewirkt werden. Flughafengebühren führen jedoch zu einem Spannungsfeld zwischen den wirtschaftlichen, politischen und umweltschützerischen Interessen der einzelnen Gruppen. Der vorliegende Tagungsband widmet sich der Frage, wie aus rechtlicher und ökonomischer Sicht mit diesem Spannungsverhältnis umgegangen werden kann und soll.
Analysis of the TREC and KREC Levels in the Dried Blood Spots of Healthy Newborns with Different Gestational Ages and Weights
Authors: Cheremokhin Dmitrii A. , Shinwari Khyber , Deryabina Svetlana S. , Bolkov Michail A. , Tuzankina Irina A. , Kudlay Dmitrii A.
Published: May 2022

ABSTRACT Inborn errors of immunity can be detected by evaluating circular DNA (cDNA) fragments of T- and B-cell receptors (TREC and KREC) resulting from the receptor gene rearrangement in T and B cells. Maturation and activation of the fetal immune system is known to proceed gradually according to the gestational age, which highlights the importance of the immune status in premature infants at different gestational ages. In this article, we evaluated TREC and KREC levels in infants of various gestational ages by real-time PCR with taking into account the newborns weight and sex. The 95% confidence intervals for TREC and KREC levels (expressed in the number of cDNA copies per 105 cells) were established for different gestational groups. The importance of studying immune system development in newborns is informed by the discovered dependence of the level of naive markers on the gestational stage in the early neonatal period.
Genomic Estimated Breeding Valueof Milk Performance and Fertility Traits in the Russian Black-and-White Cattle Population
Authors: Sharko Fedor S. , Khatib Abdulrahman , Prokhortchouk Egor B.
Published: May 2022

A breakthrough in cattle breeding was achieved with the incorporation of animal genomic data into breeding programs. The introduction of genomic selection has a major impact on traditional genetic assessment systems and animal genetic improvement programs. Since 2010, genomic selection has been officially introduced in the evaluation of the breeding and genetic potential of cattle in Europe, the U.S., Canada, and many other developed countries. The purpose of this study is to develop a system for a genomic evaluation of the breeding value of the domestic livestock of Black-and-White and Russian Holstein cattle based on 3 milk performance traits: daily milk yield (kg), daily milk fat (%), and daily milk protein content (%) and 6 fertility traits: age at first calving (AFC), calving interval (CI), calving to first insemination interval (CFI), interval between first and last insemination (IFL), days open (DO), and number of services (NS). We built a unified database of breeding animals from 523 breeding farms in the Russian Federation. The database included pedigree information on 2,551,529 cows and 69,131 bulls of the Russian Holstein and Black-and-White cattle breeds, as well as information on the milk performance of 1,597,426 cows with 4,771,366 completed lactations. The date of birth of the animals included in the database was between 1975 and 2017. Genotyping was performed in 672 animals using a BovineSNP50 v3 DNA Analysis BeadChip microarray (Illumina, USA). The genomic estimated breeding value (GEBV) was evaluated only for 644 animals (427 bulls and 217 cows) using the single-step genomic best linear unbiased prediction animal model (ssGBLUP-AM). The mean genetic potential was +0.88 and +1.03 kg for the daily milk yield, -0.002% for the milk fat content, and 0.003 and 0.001% for the milk protein content in the cows and bulls, respectively. There was negative genetic progress in the fertility traits in the studied population between 1975 and 2017. The reliability of the estimated breeding value (EBV) for genotyped bulls ranged from 89 to 93% for the milk performance traits and 85 to 90% for the fertility traits, whereas the reliability of the genomic estimated breeding value (GEBV) varied 54 to 64% for the milk traits and 23 to 60% for the fertility traits. This result shows that it is possible to use the genomic estimated breeding value with rather high reliability to evaluate the domestic livestock of Russian Holstein and Black-and-White cattle breeds for fertility and milk performance traits. This system of genomic evaluation may help bring domestic breeding in line with modern competitive practices and estimate the breeding value of cattle at birth based on information on the animals genome.
Effect of Additional Amino Acid Replacements on the Properties of Multi-point Mutant Bacterial Formate Dehyderogenase PseFDH SM4S
Authors: Pometun Anastasiya A. , Parshin Pavel D. , Galanicheva Natalia P. , Shaposhnikov Leonid A. , Atroshenko Denis L. , Pometun Eugeniy V. , Burmakin Vladislav V. , Kleymenov Sergey Yu. , Savin Svyztoslav S. , Tishkov Vladimir I.
Published: May 2022

Formate dehydrogenase from Pseudomonas sp. 101 bacterium (PseFDH, EC 1.2.1.2) is a research model for the elucidation of the catalytic mechanism of 2-oxyacid D-specific dehydrogenases enzyme superfamily. The enzyme is actively used for regeneration of the reduced form of NAD(P)H in chiral synthesis with oxidoreductases. A multi-point mutant PseFDH SM4S with an improved thermal and chemical stability has been prepared earlier in this laboratory. To further improve the properties of the mutant, additional single-point replacements have been introduced to generate five new PseFDH mutants. All new enzymes have been highly purified, and their kinetic properties and thermal stability studied using analysis of thermal inactivation kinetics and differential scanning calorimetry. The E170D amino acid change in PseFDH SM4S shows an increase in thermal stability 1.76- and 10-fold compared to the starting mutant and the wild-type enzyme, respectively.
Lexical stylistics of the Ukrainian language in the reception of Ivan Ohiienko
Authors:   Kamyanets-Podilskіy National Ivan Ohііеnko University, Popovych Anzhelika
Published: May 2022

Ivan Ohiienko made a signifi cant contribution to the formation and development of Ukrainian language Stylistics. His reasoning on certain stylistic issues is recorded in such scientifi c investigations as «The Science of Native Language Duties», «Ukrainian Literary Language History», «Our Literary Language: How to Write and Speak in Literature», «Grammatical and Stylistic Dictionary of Shevchenko’s Language» etc.ºíêàThe purpose of our article is to determine Ivan Ohiienko’s contribution to the development of Ukrainian Language Lexical Stylistics.Among the stylistic concepts, the concepts of lexical stylistics are clearly dis-tinguished. I. Ohiienko payed attention to the stylistic load of synonyms, archaisms, neologisms, dialectisms, terms, borrowed words, vulgarisms, provincialisms, etc.The linguist argued for the need to use archaisms in the artistic style to give the text artistry, a description of a bygone era, the archaic coloring of the speech of the characters, providing teaching pathos and more. I. Ohiienko considered it appropriate to use old slavonic in the confessional style.The stylistic use of «local language» (dialectisms) is limited to the conscious use in the characters’ language, and in works of regional purpose. Unacceptable dialect words in the scientifi c style.I. Ohiienko singled out specifi c features of the use of foreign languages: in the presence of Ukrainian words-equivalents to replace borrowing; to refuse frivolous use of foreign words; do not use tracing words; in journalistic style unknown to the general public to explain other languages. The scientist was fi rmly convinced that the use of foreign words does not contribute not only to Ukrainian language development, but also to spiritual culture development in general.According to I. Ohiienko, synonyms should not only be known, but also felt, in particu-lar, the correct use of stylistic synonyms, which diff er in relation to diff erent functional styles.Thus, I. Ohiienko’s reseaches on the problems of the History Ukrainian literary language development are also important for Stylistics development.
Linguistic construction of Ivan Ohiienko's epistolary: gender aspect
Authors:   Kamyanets-Podilskіy National Ivan Ohііеnko University, Shevchuk Zoreslava
Published: May 2022

This article is devoted to analysing the means of communication through correspond-ence between Ivan Ohiienko and male/female representatives In particular, аttention is being given to the various levels of communication behavior, which refl ect a stereotypical view of gender roles in in the course of speech communication. This article stipulates that the emotional and evaluative language is predominance in communication with women. The article explores that Ivan Ohiienko employs essentially lexemes, which have neu-tral and estimated meanings during correspondence with men. The article determines the major word usage of etiquette formulas of the accosts, which express special respect and gratitude to the addressee. Analysis of the text array showed that Ivan Ohiienko commonly used the diminutive forms, which are related to parametric representations (about the proportions, that is. an indication of the size is given), phraseological constructions, which emphasize metropolitan’s language. The article determines, that rhetorical questions, ex-clamation sentences, which added excessive expressiveness are аn important means of argument impact on men or women in the letters of Ivan Ohiienko and provide a mecha-nism for pragmatic impact on gender model of the world. Ivan Ohiienko used attitudinal, instructive sentences in almost every letter to men or women Mostly etiquette formulas of the requests are accompanied by imperatives (with request, will you please, you are welcome) The article acknowledges that emotional explanations and deeper exposure of internal emotions of Ivan Ohiienko to the depicted events are displayed through the usage of situational lexical and stylistic tools (specifi cally irony, which provides displaying of the specifi c form of critical reality perception), insert constructions, repetitions, etc. Ivan Ohiienko is characterized as a skilled literary critic, editor, stylist, describing the accom-plishments of his female colleagues, friends, in the letters to women.
Ivan Ohiienko's ideas in the formation of the national-patriotic personality of the future teacher of literature
Authors:   Hlukhiv National Pedagogical University named after Oleksandr Dovzhenko, Tsinko Svitlana
Published: May 2022

The article highlights the role of Ivan Ohiienko’s ideas, published in the work «Science of Native Language Responsibility», in shaping a national-patriotic person-ality of the future teacher of literature.The author notes that the majority of I. Ohiienko’s ideas about children upbring-ing are intertwined with the requirements and objectives of modern pedagogy, and the realities of our time not only provide reasons for studying his experience, but also encourage the revival and implementation of his ideas.Our time encourages to studying the scientifi c heritage of Ukrainian scholars, a special place among which belongs to Ivan Ohiienko – a world-famous fi gure of science and education.Ivan Ohiienko’s ideas set down in the work «The Science of Native Language Responsibility» are important and relevant in general and in the fi eld of education in particular, because most of his ideas about children upbringing are intertwined with the requirements and objectives of modern pedagogy.In our opinion, Ivan Ohiienko’s ideas should be implemented fi rst of all by teach-ers with the support of the state and the government.Ivan Ohiienko assigns a priority role in forming the national-patriotic personality to the school, teacher, and family. Therefore, forming a professionally oriented per-sonality of the future literature teacher is impossible without relying on the pedagogi-cal and national-linguistic ideas of the prominent Ukrainian scholar Ivan Ohiienko.The article presents tasks for both collective and individual students’ work, de-signed to develop creativity, critical thinking, non-standard approach to solving the problem; contribute to the national-patriotic personality formation of the future teach-er. For example: to comment in the form of an essay the proposed quotations from the work of Ivan Ohiienko: «It is not free to change the spelling too soon, because it lowers the general literacy of the people» [4, р. 19]; to design and present a project «The relevance of Ivan Ohiienko’s ideas in modern society and education»; to make a mental map «The science of responsibility to the native language of every citizen» (based on the ideas of Ivan Ohiienko), etc.
Multi-element lyrical system as a narrative strategy in Yuri Klen's cycle "Circle of Life"
Authors:   Kamyanets-Podilskіy National Ivan Ohііеnko University, Volkovynska Inna
Published: May 2022

The article deals with the problems of narratological organization of lyrics. There is some disproportion in the study of narratological features of works in relation to their genre and genus nature. Researchers often draw the attention of narratological strategy of epic works. The peculiarities of the organization of the narrative of lyrical works are among the least studied aspects of narratological discourse The practice of world poetry demonstrates that the sonnet has become an accu-mulative expression of feelings and an intense lyrical beginning. Combining sonnets into cycles leads to an increase in the role of narrative structures, narrative epics.Yurii Klen’s poetic cycle «Kolo zhyttove» as a multi-element lyrical system is characterized by the pulsation of narrative focalization, shifts in the narrator’s point of view and changes in the forms of the lyrical subject. The evolution of the forms of the lyrical subject can be conditionally represented in the following algorithm: from the subject (which is presented as another)  to the removed narrator  again to the subject, but which is not only «another», but also becomes a kind of container of the author’s voice and humanity in general.The lyrical autonomy of each individual sonnet is overcome by the epic cohesion of the cycle in order to create a generalized picture of all-encompassing and individual existence. Such a dual unity of the sonnet cycle in the artistic consciousness of Yurii Klen made it possible to quite naturally combine a multi-element lyrical system with various manifestations of narrative strategy. The result was a dynamic universal pro-jection on a separate and common being.The narrative strategy of the cycle emphasizes the leading motive of the work  a per-son, once in the world, becomes an integral part of it. But he perceives the macrocosm as alien and hostile and does not feel her organic unity with it. A person is doomed to search for himself and his coordinates in the reality that surrounds him all his life. But the reward is a possible and desirable awareness of one's own essence in harmony with the world. That is, a person passes the cherished circle as a symbol of eternal return and perfection
Origin and functioning anthroponyms in novels by Roman Ivanychuk "Fourth measurement»
Authors:   Kamyanets-Podilskіy National Ivan Ohііеnko University, Marchuk Liudmyla
Published: May 2022

The article reveals the functioning of anthroponyms in a historical novel, presents the etymological analysis of proper names, highlights the achievements in anthro-ponymic research of Ukrainian linguists. Such names have been known since the pre-Christian period, and in fi ction play a specifi c function – the creation of temporal and spatial background.Each literary and artistic anthroponym in the work must perform certain func-tions. R. Ivanychuk often chooses the names of the characters, determining the na-tionality, age, personality, appearance, and so on. The writer’s own names become a powerful expressive factor. Often they provide invaluable information in the text for the interpretation of the whole work, sometimes such that it is not expressed in other ways in the work. They express the text stylistically, color it.Anthroponymy in a literary text not only contains semantic information, but also expresses non-textual parameters of the author’s image, as the choice of anthroponyms for a writer is a manifestation of his literary individuality and artistic skill against the background of real socio-historical reality and his background knowledge.In the works of Roman Ivanychuk, anthroponyms are an eff ective method of ex-pressing the author’s point of view, which is one of the components of the structural and textual parameters of the author’s image.Nominative literary and artistic anthroponyms are the basis of artistic onomas-ticon. The presence of such onyms confi rms the authenticity of the characters and events. The main part of literary anthroponyms that perform a nominative function are names, surnames, drawn by the author from real life.
An IoT Application for Effective Management of Agriculture Resources
Authors: Vaibhav R. Chavan
Published: May 2022

Several issues related to traditional agriculture have hindered the growth of nation. Thus, solution to this mode of agriculture is adoption of smart agriculture. Therefore, the aim of this research is to make the agriculture smart by adopting innovative and advanced technologies such as Internet of things (IoT) and Wireless Sensor Network (WSN) enabled automation in agriculture. In recent times, IoT and WSN based technologies can be applied in several research fields. IoT enables various applications employed in crop growth monitoring and selection of irrigation decision support system. The technology like Raspberry Pi used recently in irrigation system of agriculture for improvement of crop productivity. This research paper focuses on various parameters of IoT related to agriculture such as soil moisture sensor, floodwater detector, temperature tracking sensor, humidity and light intensity sensor, etc. The sensors are associated to web server through raspberry pi controller. It detects the each activity of field and transfer the information to web server. The result outcomes assist the former to know about the actual scenario of field in real time through buzzer and can smartly do watering and showering fertilizer to the field in very efficient manner without trying too hard and quality of the crops will be get improved.
Sentimental Analysis Using Twitter Data
Authors: Prof. Pradeep N. Fale  , Uddesh Shelkhi  , Vaibhav Kosare  , Saurav Chaudhari  , Vinay Sharma
Published: May 2022

Online media are becoming extra attention those days. Public and personal evaluation on a extensive collection of topics are communicated and unfold always by diverse on line media. Twitter is one of the on line media this is obtaining prominence. Twitter gives association’s short and compelling method to research clients' viewpoints closer to the primary to accomplishment within side the industrial Centre. Building up a software for belief research is a manner to cope with be applied to computationally degree clients' insights. This paper investigates the plan of a end examination, setting apart a massive degree of tweets. Prototyping is applied on this flip of events. Results set up clients' factor of view thru tweets into fantastic and negative, that is addressed in a pie define and html page. Nonetheless, this system has desired to create on an internet utility framework, but due to restrict of Django which may be bartered with a Linux employee or LAMP, for added this system ought to be finished.
An Experimental Study on Strength and Durability Properties of GGBS based Geopolymer Concrete
Authors: Geena George  , Basavaraj G Totar
Published: May 2022

Huge amount of energy is consumed during for the manufacture of OPC , also emits CO2 and other greenhouse gases leads to global warming. Nowadays the production of Portland cement and consumption of concrete is increasing enormously. Geopolymer concrete is considered as a new approach towards sustainability in which different industrial by products are used to replace OPC as a binder completely which minimizes the CO2 emission. In this study, attempt is made to develop GGBS based geopolymer and the characteristic strength is studied. The concentration of sodium hydroxide solution was kept up as 10M. The compressive, split tensile and flexural strength of the GGBS based geopolymer concrete was studied at different ages like 3, 7, 28 days. Microstructural study has been conducted with SEM analysis to study the effect of temperature in curing of geopolymer.Also conducted the durability studies on geopolymer concrete exposed to severe exposure such as acidic and basic environments.