bluuebunny/crossref_metadata_2025 huggingface dataset:
The Application of Phytohormones as Biostimulants in Corn Smut Infected Hungarian Sweet and Fodder Corn Hybrids
Authors: Szőke Lóránt , Moloi Makoena , Kovács Gabriella , Biró Györgyi , Radócz László , Hájos Mária , Kovács Béla , Rácz Dalma , Danter Mátyás , Tóth Brigitta
Published: September 2021

The main goal of this research was to investigate the effects of corn smut (Ustilago maydis DC. Corda) infection on the morphological (plant height, and stem diameter), and biochemical parameters of Zea mays L. plants. The biochemical parameters included changes in the relative chlorophyll, malondialdehyde (MDA), and photosynthesis pigments’ contents, as well as the activities of antioxidant enzymes—ascorbate peroxidase (APX), guaiacol peroxidase (POD), and superoxide dismutase (SOD). The second aim of this study was to evaluate the impact of phytohormones (auxin, cytokinin, gibberellin, and ethylene) on corn smut-infected plants. The parameters were measured 7 and 11 days after corn smut infection (DACSI). Two hybrids were grown in a greenhouse, one fodder (Armagnac) and one a sweet corn (Desszert 73). The relative and the absolute amount of photosynthetic pigments were significantly lower in the infected plants in both hybrids 11 DACSI. Activities of the antioxidant enzymes and MDA content were higher in both infected hybrids. Auxin, cytokinin, and gibberellin application diminished the negative effects of the corn smut infection (CSI) in the sweet corn hybrid. Phytohormones i.e., auxin, gibberellin, and cytokinin can be a new method in protection against corn smut.
On the Effect of Electron Streaming and Existence of Quasi-Solitary Mode in a Strongly Coupled Quantum Dusty Plasma—Far and Near Critical Nonlinearity
Authors: Chaudhuri Shatadru , Chowdhury Asesh Roy
Published: September 2021

A strongly coupled quantum dusty plasma consisting of electrons and dust with the ions in the background is considered when there is streaming of electrons. It is observed that the streaming gives rise to both the slow and fast modes of propagation. The nonlinear mode is then analyzed by the reductive perturbation approach, resulting in the KdV-equation. In the critical situation where non-linearity vanishes, the modified scaling results in the MKdV equation. It is observed that both the KdV and MKdV equations possess quasi-solitary wave solution, which not only has the character of a soliton but also has a periodic nature. Such types of solitons are nowadays called nanopteron solitons and are expressed in terms of cnoidal-type elliptic functions.
Electrostatic Ion-Acoustic Shock Waves in a Magnetized Degenerate Quantum Plasma
Authors: Jahan Sharmin , Sharmin Booshrat E. , Chowdhury Nure Alam , Mannan Abdul , Roy Tanu Shree , Mamun A A
Published: September 2021

A theoretical investigation has been carried out to examine the ion-acoustic shock waves (IASHWs) in a magnetized degenerate quantum plasma system containing inertialess ultra-relativistically degenerate electrons, and inertial non-relativistic positively charged heavy and light ions. The Burgers equation is derived by employing the reductive perturbation method. It can be seen that under the consideration of non-relativistic positively charged heavy and light ions, the plasma model only supports the positive electrostatic shock structure. It is also observed that the charge state and number density of the non-relativistic heavy and light ions enhance the amplitude of IASHWs, and the steepness of the shock profile is decreased with ion kinematic viscosity. The findings of our present investigation will be helpful in understanding the nonlinear propagation of IASHWs in white dwarfs and neutron stars.
Capsule Independent Antimicrobial Activity Induced by Nanochitosan against Streptococcus pneumoniae
Authors: Alqahtani Fulwah Y. , Aleanizy Fadilah S. , El Tahir Eram , Alowais Hessa , Binkelaib Assalh , Alwathlan Bdour , Al-Bdrawy Asmaa , Håkansson Anders P. , Alsarra Ibrahim
Published: September 2021

Background: Streptococcus pneumoniae remains a major cause of community-acquired pneumonia, meningitis, and other diseases, contributing significantly to high morbidity and mortality worldwide. Although it responds to antibiotics, their use is becoming limited due to the rise in antibiotic resistance, which necessitates the development of new therapeutics. Nanotechnology is used to counteract antimicrobial resistance. In this regard, polymeric nanoparticles (NPs) made of natural, biodegradable, biocompatible, and cationic polymers such as Chitosan (CNPs) exhibit wide-spectrum antimicrobial activity. Therefore, this study aimed to prepare CNPs, characterize their physiochemical characteristics: particle size (PZ), polydispersity index (PDI), and zeta potential (ZP), and investigate their antimicrobial activity against Streptococcus pneumoniae TIGR4 (virulent serotype 4) and its capsular mutant (∆cps). Methods: CNPs were prepared at 1, 2.5, and 5 mg/mL concentrations using the ion gelation method. Then, PZ, PDI, and ZP were characterized using a Zetasizer. Transmission electron microscopy (TEM) was used to visualize the CNP’s morphology. Broth and agar dilution methods were used to assess their antimicrobial activity. Cytotoxicity of prepared NPs on A549 cells and their effect on pneumococcal hemolysis were also investigated. Results: Spherical CNPs were produced with PZ ranging from 133.3 nm ± 0.57 to 423 nm ± 12.93 PDI < 0.35, and ZP from 19 ± 0.115 to 27 ± 0.819. The prepared CNPs exhibited antibacterial activity against TIGR4 and its capsule mutant with a minimum inhibitory concentration (MIC90) of 0.5 to 2.5 mg/mL in a non-acidic environment. The hemolysis assay results revealed that CNPs reduced bacterial hemolysis in a concentration-dependent manner. Their mammalian cytotoxicity results indicated that CNPs formed from low concentrations of Chitosan (Cs) were cytocompatible. Conclusion: Nanochitosan particles showed anti-pneumococcal activity regardless of the presence of capsules. They resulted in a concentration-dependent reduction in bacterial hemolysis and were cytocompatible at a lower concentration of Cs. These findings highlight the potential of CNPs in the treatment of pneumococcal diseases.
Biodegradable Binary and Ternary Complexes from Renewable Raw Materials
Authors: Folentarska Agnieszka , Łagiewka Jakub , Krystyjan Magdalena , Ciesielski Wojciech
Published: September 2021

The aim of this paper is to investigate the interactions between polysaccharides with different electrical charges (anionic and neutral starches) and proteins and fats in food ingredients. Another objective is to understand the mechanisms of these systems and the interdependence between their properties and intermolecular interactions. At present, there are not many studies on ternary blends composed of natural food polymers: polysaccharides of different electrical charge (anionic and neutral starches), proteins and lipids. Additionally, there are no reports concerning what type of interactions between polysaccharide, proteins and lipids exist simultaneously when the components are mixed in different orders. This paper intends to fill this gap. It also presents the application of natural biopolymers in the food and non-food industries.
Effect of Hyaluronic Acid on the Differentiation of Mesenchymal Stem Cells into Mature Type II Pneumocytes
Authors: Della Sala Francesca , di Gennaro Mario , Lista Gianluca , Messina Francesco , Ambrosio Luigi , Borzacchiello Assunta
Published: September 2021

Hyaluronic acid (HA) is an essential component of the extracellular matrix (ECM) of the healthy lung, playing an important role in the structure of the alveolar surface stabilizing the surfactant proteins. Alveolar type II (ATII) cells are the fundamental element of the alveolus, specializing in surfactant production. ATII cells represent the main target of lung external lesion and a cornerstone in the repair process of pulmonary damage. In this context, knowledge of the factors influencing mesenchymal stem cell (MSC) differentiation in ATII cells is pivotal in fulfilling therapeutic strategies based on MSCs in lung regenerative medicine. To achieve this goal, the role of HA in promoting the differentiation of MSCs in mature Type II pneumocytes capable of secreting pulmonary surfactant was evaluated. Results demonstrated that HA, at a specific molecular weight can greatly increase the expression of lung surfactant protein, indicating the ability of HA to influence MSC differentiation in ATII cells.
Effect of Aluminum Flakes on Mechanical and Optical Properties of Foam Injection Molded Parts
Authors: Kim Donghwi , Ryu Youngjae , Lee Ju-Heon , Cha Sung Woon
Published: September 2021

Injection research using aluminum flakes has been conducted to realize metallic textures on the surface of plastic products. Several studies have focused on the effect of the orientation and quality of the flakes when using conventional injection molding methods; however, limited studies have focused on the foam injection molding method. In this study, we examined the orientation of aluminum flakes through foam injection with an inert gas and observed the changes in texture using a spectrophotometer and a gloss meter. The mechanical properties were also studied because the rigidity of the product, which is affected by the weight reduction that occurs during foaming, is an important factor. The results demonstrate that under foam injection molding, reflectance and gloss increased by 6% and 7 GU, respectively, compared to those obtained using conventional injection molding; furthermore, impact strength and flexural modulus increased by 62% and 15%, respectively. The results of this research can be applied to incorporate esthetic improvements to products and to develop functional parts.
Influence of Infill Pattern on Mechanical Behavior of Polymeric and Composites Specimens Manufactured Using Fused Filament Fabrication Technology
Authors: Martín María Jesús , Auñón Juan Antonio , Martín Francisco
Published: September 2021

This paper presents the results of a comparative evaluation of the tensile strength behaviors of parts obtained by additive manufacturing using fused filament fabrication (FFF) technology. The study investigated the influences of the deposition printing parameters for both polymers and fiber-reinforced polymers. Polymeric materials that are widely used in FFF were selected, including acrylonitrile butadiene styrene (ABS), polylactic acid (PLA), and nylon. Carbon and glass continuous fibers were used to reinforce the nylon matrix in composite materials. The study utilized two manufacturing methods. Polymers were manufactured using an Ultimaker 2 Extended+ device and the fiber-reinforced polymer specimens were obtained using a Markforged Mark Two printer. The entire set of specimens was eventually subjected to destructive monoaxial tensile tests to measure their responses. The main goal of this study was to estimate the effect of the different infill patterns applied (zig-zag, concentric, and four different orientations lines) on the mechanical properties of pure thermoplastic materials and reinforced polymers. Results show a spectacular increase in the tensile stress at break, which for polymers reaches an average value of 27.53 MPa compared to 94.51 MPa in the case of composites (increase of 70.87%). A similar increase occurs in the case of tensile stress at yield with values of 31.87 MPa and 105.98 MPa, respectively, which represents an increase of 69.93%. The influence of the infill of the fiber is decisive, reaching, in the 0-0 arrangement, mean values of 220.18 MPa for tensile stress at break and 198.26 MPa for tensile stress at yield.
The Use of Computed Tomography in the Study of Microstructure of Molded Pieces Made of Poly(3-hydroxybutyric-co-3-hydroxyvaleric acid) (PHBV) Biocomposites with Natural Fiber
Authors: Frącz Wiesław , Janowski Grzegorz , Pruchniak Maciej , Wałek Łukasz
Published: September 2021

In order to determine the structure homogeneity of biocomposites filled with fibers, as well as the evaluation of fibers’ arrangement and their orientation on the sample cross-section at varied injection rates, a study was conducted using computed tomography (CT). The main advantage of this test is the fact that in order to assess the microstructure on cross-sections, the samples do not have to be processed mechanically, which allows for presenting the actual image of the microstructure. The paper presents the issues of such tests for the biocomposite of poly (3-hydroxybutyric-co-3-hydroxyvaleric acid) (PHBV)-hemp fibers. It should be emphasized that CT scanning of PHBV-hemp fiber biocomposites is quite difficult to perform due to the similar density of the fibers and the polymer matrix. Due to the high difficulty of distinguishing fibers against the background of the polymer matrix during CT examination, a biocomposite containing 15% hemp fibers was analyzed. The samples for testing were manufactured using the injection molding process at variable injection rates, i.e., 10, 35 and 70 cm3/s. The images obtained by computed tomography show the distribution of hemp fibers and their clusters in the PHBV matrix and the degree of porosity on the sample cross-section. There were significant microstructural differences for the samples injected at the highest injection rates, including, among others, the occurrence of a smaller number of fibers and pores on the surface layer of the molded piece. The phenomenon observed was verified by testing chosen mechanical properties, shrinkage and water absorption of the samples. Some properties improved with an increasing injection rate, while others deteriorated and vice versa. An analysis of biocomposites’ microstructures using computed tomography provides a wide range of possibilities for future research, including an assessment of the structure of the molded parts. These tests may allow one, for example, to detect the cause of molded piece properties decreasing in a specific area as a result of a high degree of fiber disorientation, as well as the defects resulting from high porosity of the material. Such analyses can be particularly useful for producers that deal with the injection molding of pieces molded with specific properties.
Biopolymer Nanocomposite Materials Based on Poly(L-lactic Acid) and Inorganic Fullerene-like WS2 Nanoparticles
Authors: Naffakh Mohammed
Published: September 2021

In the current study, inorganic fullerene (IF)-like tungsten disulphide (WS2) nanoparticles from layered transition metal dichalcogenides (TMDCs) were introduced into a poly(L-lactic acid) (PLLA) polymer matrix to generate novel bionanocomposite materials through an advantageous melt-processing route. The effectiveness of employing IF-WS2 on the morphology and property enhancement of the resulting hybrid nanocomposites was evaluated. The non-isothermal melt–crystallization and melting measurements revealed that the crystallization and melting temperature as well as the crystallinity of PLLA were controlled by the cooling rate and composition. The crystallization behaviour and kinetics were examined by using the Lui model. Moreover, the nucleating effect of IF-WS2 was investigated in terms of Gutzow and Dobreva approaches. It was discovered that the incorporation of increasing IF-WS2 contents led to a progressive acceleration of the crystallization rate of PLLA. The morphology and kinetic data demonstrate the high performance of these novel nanocomposites for industrial applications.
Critical Solutal Marangoni Number Correlation for Short-Scale Convective Instabilities in Drying Poly(vinyl acetate)-Methanol Thin Films
Authors: Tönsmann Max , Scharfer Philip , Schabel Wilhelm
Published: September 2021

A new empiric correlation for the critical solutal Marangoni number as function of the Péclet and Schmidt numbers is proposed. It is based on previously published experimental flow field data in drying poly(vinyl acetate)-methanol films with an initial thickness in the range of 20–100 μm and an initial solvent load of 1 to 2 gMeOH/gPVAc, as well as newly derived concentration profile measurements and 1D drying simulations. The analysis accounts for realistic transient material properties and describes the occurrence of short-scale convective Marangoni (in)stabilities during the entire drying process with an accuracy of 9%. In addition, the proposed correlation qualitatively follows trends known from theory. As convective Marangoni instabilities in drying polymer films may induce surface deformations, which persist in the dry film, the correlation may facilitate future process design for either thin films with uniform thickness or deliberate self-assembly.
The Effect of Hybridisation on Mechanical Properties and Water Absorption Behaviour of Woven Jute/Ramie Reinforced Epoxy Composites
Authors: Tezara Cionita , Hadi Agung Efriyo , Siregar Januar Parlaungan , Muhamad Zalinawati , Hamdan Mohammad Hazim Mohamad , Oumer Ahmed Nurye , Jaafar Jamiluddin , Irawan Agustinus Purna , Rihayat Teuku , Fitriyana Deni Fajar
Published: September 2021

Recently, the most critical issue related to the use of natural fibre-reinforced polymer composites (NFRPC) is the degradation properties of composites exposed to the environment. NFRPC’s moisture absorption behaviour has adverse effects on the composite’s mechanical properties and dimensional stability. The purpose of this study is to analyse the mechanical properties of epoxy composites reinforced by jute–ramie hybridisation. This study also analysed the effect of stacking sequence hybridisation of the jute–ramie composite on water absorption behaviour. A five-layer different type of stacking sequence of single and hybrid jute–ramie is produced with the hand lay-up method. The results obtained from this study found that the mechanical properties and water absorption behaviour of a single jute fibre are lower compared to a single ramie fibre. The hybrid of jute–ramie has been able to increase the performance of composite compared to pure jute composites. The mechanical properties of the hybrid jute–ramie composite show a reduction effect after exposure to an aqueous environment due to the breakdown of fibre matrix interfacial bonding. However, after 28 days of immersion, all types of the stacking sequence’s mechanical properties are still higher than that of pure epoxy resin. In conclusion, the appropriate sequence of stacking and selecting the material used are two factors that predominantly affect the mechanical properties and water absorption behaviour. The hybrid composites with the desired and preferable properties can be manufactured using a hand-lay-up technique and used in the various industrial applications.
Effect of Nucleating Additives on Short- and Long-Term Tensile Strength and Residual Stresses of Welded Polypropylene Samples
Authors: Wübbeke Andrea , Schöppner Volker , Arndt Theresa , Maras Jan-Ole , Fitze Marcus , Moltzahn Christian , Wu Tao , Niendorf Thomas
Published: September 2021

Additives such as nucleating agents are often used in the processing of plastic products not only for improving production efficiency but also for enhancing mechanical performance. In this work, the short- and long-term tensile strength, the morphology as well as the residual stresses of the welded polypropylene (PP) samples with different fillers (carbon black and special beta-nucleating agents) and different dimensionless joining paths are analyzed. Results obtained are then compared with those that are representative of the initial, filler-free samples. It is shown that, upon using the special beta-nucleating agent, superior long-term tensile strength can be achieved compared to the samples without additives or with carbon black agent (e.g., for the dimensionless joining path of 0.95, the long-term tensile strength of a PP nature sample is characterized by around 400 MPa, whereas by adding beta-nucleating agent 1% the value can be increased by 400% to reach around 2050 MPa). However, adding beta-nucleating agent 1% yields inferior short-term tensile strength. The hole drilling method (HDM) is used for the analysis of residual stresses. It is found that the residual stresses in the weld seam are characterized by low values of the tensile stresses. The residual stresses in the weld seam also can be converted from tensile into compressive stresses by adding the beta nucleating agent. However, this has the disadvantage that with a higher proportion by weight of the beta nucleating agent, the short-term tensile strength of the welded joint becomes lower than that of the other tested bonds.
Influences of Slenderness and Eccentricity on the Mechanical Properties of Concrete-Filled GFRP Tube Columns
Authors: Guan Hongbo , Xia Yifei , Wang Jinli , Mbonyintege Arsene Hugo
Published: September 2021

The existence of either eccentricity or slenderness has a significant effect on the mechanical properties of a structure or member. These properties can change the working mechanism, failure mode, and bearing capacity of the structure or member. A concrete-filled, glass fibre-reinforced, polymer tube composite column has the same problem. We carried out experiments on the influences of eccentricity and slenderness on the mechanical properties of concrete-filled, glass fibre-reinforced, polymer tube composite columns. The experimentally recorded stress–strain relationships are presented graphically, and the ultimate axial stresses and strains and the FRP tube hoop strains at rupture were tabulated. The results indicate that the influences of slenderness and eccentricity on the composite columns were significant with regard to the axial strain, hoop strain, ultimate bearing capacity, lateral displacement, and failure mode. Based on the existing research literature and the results reported in this paper, the bearing capacity formula of a composite slender column under an eccentric load was established. The theoretical results were in good agreement with the experimental results.
FT-IR Study, Thermal Analysis, and Evaluation of the Antibacterial Activity of a MK-Geopolymer Mortar Using Glass Waste as Fine Aggregate
Authors: Dal Poggetto Giovanni , D’Angelo Antonio , Blanco Ignazio , Piccolella Simona , Leonelli Cristina , Catauro Michelina
Published: September 2021

Food containers made from glass are separately collected from urban solid waste at 76% in most parts of Europe. The cullet glass finds its way to re-melting, while the debris is often disposed of. With this contribution, we suggest an upcycling process where glass debris is simply ground without any washing operation and added to an alkali-activated paste. Metakaolin-based geopolymer mortar added with coarsely ground glass waste as fine aggregate has been prepared via alkali activation with NaOH and Na-silicate. After 7, 14 and 28 days of room temperature curing time, the 3D geopolymer network was investigated by Fourier-transform infrared spectroscopy (FT-IR). Vibrational spectra revealed the geopolymerization occurrences, results which have been supported by both FT-IR deconvoluted spectra and thermogravimetric analysis (TGA). Finally, the antibacterial properties were investigated against both gram-negative (E. coli) and gram-positive (E. faecalis) bacterial strains. The results suggest the ability of the 28 days cured geopolymers to inhibit the growth of the gram-negative bacterium assayed.
High-Resolution Bioprinting of Recombinant Human Collagen Type III
Authors: Gibney Rory , Patterson Jennifer , Ferraris Eleonora
Published: September 2021

The development of commercial collagen inks for extrusion-based bioprinting has increased the amount of research on pure collagen bioprinting, i.e., collagen inks not mixed with gelatin, alginate, or other more common biomaterial inks. New printing techniques have also improved the resolution achievable with pure collagen bioprinting. However, the resultant collagen constructs still appear too weak to replicate dense collagenous tissues, such as the cornea. This work aims to demonstrate the first reported case of bioprinted recombinant collagen films with suitable optical and mechanical properties for corneal tissue engineering. The printing technology used, aerosol jet® printing (AJP), is a high-resolution printing method normally used to deposit conductive inks for electronic printing. In this work, AJP was employed to deposit recombinant human collagen type III (RHCIII) in overlapping continuous lines of 60 µm to form thin layers. Layers were repeated up to 764 times to result in a construct that was considered a few hundred microns thick when swollen. Samples were subsequently neutralised and crosslinked using EDC:NHS crosslinking. Nanoindentation and absorbance measurements were conducted, and the results show that the AJP-deposited RHCIII samples possess suitable mechanical and optical properties for corneal tissue engineering: an average effective elastic modulus of 506 ± 173 kPa and transparency ≥87% at all visible wavelengths. Circular dichroism showed that there was some loss of helicity of the collagen due to aerosolisation. SDS-PAGE and pepsin digestion were used to show that while some collagen is degraded due to aerosolisation, it remains an inaccessible substrate for pepsin cleavage.
Data-Driven State Prediction and Sensor Fault Diagnosis for Multi-Agent Systems with Application to a Twin Rotational Inverted Pendulum
Authors: Lu Xin , Liu Xiaoxu , Li Bowen , Zhong Jie
Published: September 2021

When a multi-agent system is subjected to faults, it is necessary to detect and classify the faults in time. This paper is motivated to propose a data-driven state prediction and sensor fault classification technique. Firstly, neural network-based state prediction model is trained through historical input and output data of the system. Then, the trained model is implemented to the real-time system to predict the system state and output in absence of fault. By comparing the predicted healthy output and the measured output, which can be abnormal in case of sensor faults, a residual signal can be generated. When a sensor fault occurs, the residual signal exceeds the threshold, a fault classification technique is triggered to distinguish fault types. Finally, the designed data-driven state prediction and fault classification algorithms are verified through a twin rotational inverted pendulum system with leader-follower mechanism.
Alts: An Adaptive Load Balanced Task Scheduling Approach for Cloud Computing
Authors: Mubeen Aroosa , Ibrahim Muhammad , Bibi Nargis , Baz Mohammad , Hamam Habib , Cheikhrouhou Omar
Published: September 2021

According to the research, many task scheduling approaches have been proposed like GA, ACO, etc., which have improved the performance of the cloud data centers concerning various scheduling parameters. The task scheduling problem is NP-hard, as the key reason is the number of solutions/combinations grows exponentially with the problem size, e.g., the number of tasks and the number of computing resources. Thus, it is always challenging to have complete optimal scheduling of the user tasks. In this research, we proposed an adaptive load-balanced task scheduling (ALTS) approach for cloud computing. The proposed task scheduling algorithm maps all incoming tasks to the available VMs in a load-balanced way to reduce the makespan, maximize resource utilization, and adaptively minimize the SLA violation. The performance of the proposed task scheduling algorithm is evaluated and compared with the state-of-the-art task scheduling ACO, GA, and GAACO approaches concerning average resource utilization (ARUR), Makespan, and SLA violation. The proposed approach has revealed significant improvements concerning the makespan, SLA violation, and resource utilization against the compared approaches.
Liquid Hot Water Pretreatment of Lignocellulosic Biomass at Lab and Pilot Scale
Authors: Jimenez-Gutierrez Jose M. (Chema) , Verlinden Rob A. J. , van der Meer Peter C. , van der Wielen Luuk A. M. , Straathof Adrie J. J.
Published: September 2021

Liquid hot water pretreatment is considered to be a promising method for increasing biomass digestibility due to the moderate operational conditions without chemical additions. A necessary step towards the scalability of this pretreatment process is performing pilot plant trials. Upscaling was evaluated with a scaling factor of 500, by using 50 mL in the laboratory and 25 L in a pilot plant batch reactor. Pretreatment times were varied from 30 to 240 min, and temperatures used were 180–188 °C, while applying similar heating profiles at both scales. The initial mass fraction of poplar wood chips ranged from 10% to 16%. Liquid hot water pretreatment at laboratory and pilot scale led to analogous results. The acetic acid analysis of the liquid and solid fractions obtained after pretreatment indicated that complete deacetylation of poplar biomass can be achieved.
Temperature Stress Analysis of Super-Long Frame Structures Accounting for Differences in the Linear Expansion Coefficients of Steel and Concrete
Authors: Jia Yigang , Lu Liangjian , Wu Guangyu , Zhang Bo , Wang Huibin
Published: September 2021

Temperature stress analysis is of prime importance to ensure the adequate servicing of super-long frame structures during their service life. The existing design codes and recommendations for reinforced concrete (RC) structures provide methodologies for the reinforcement of design elements that neglect differences in the linear expansion coefficients of steel and concrete. In this paper, we present a numerical method based on a degenerated three-dimensional solid virtual laminated element for simulating and analyzing the temperature stress of a two-layer super-long frame reinforced concrete structure subjected to allover cooling action, whereby the difference in the linear expansion coefficients of steel and concrete are taken into consideration. The results show that the difference in the linear expansion coefficients of steel and concrete, with different constraints, affects the temperature stress experienced by each material in the structure, and this difference adversely affects attempts to avoid structure cracking.
SimilarityLab: Molecular Similarity for SAR Exploration and Target Prediction on the Web
Authors: Shave Steven , Auer Manfred
Published: September 2021

Exploration of chemical space around hit, experimental, and known active compounds is an important step in the early stages of drug discovery. In academia, where access to chemical synthesis efforts is restricted in comparison to the pharma-industry, hits from primary screens are typically followed up through purchase and testing of similar compounds, before further funding is sought to begin medicinal chemistry efforts. Rapid exploration of druglike similars and structure–activity relationship profiles can be achieved through our new webservice SimilarityLab. In addition to searching for commercially available molecules similar to a query compound, SimilarityLab also enables the search of compounds with recorded activities, generating consensus counts of activities, which enables target and off-target prediction. In contrast to other online offerings utilizing the USRCAT similarity measure, SimilarityLab’s set of commercially available small molecules is consistently updated, currently containing over 12.7 million unique small molecules, and not relying on published databases which may be many years out of date. This ensures researchers have access to up-to-date chemistries and synthetic processes enabling greater diversity and access to a wider area of commercial chemical space. All source code is available in the SimilarityLab source repository.
A Preliminary Assessment of the ‘Greenness’ of Halide-Free Ionic Liquids—An MCDA Based Approach
Authors: Maniam Kranthi Kumar , Paul Shiladitya
Published: September 2021

With the growing interests in non-aqueous media for diversified applications, ionic liquids (ILs) are frequently considered as green solvents. While the environmental, health, and safety assessments of the commercially developed ILs and their ‘greenness’ status are in debate, research focus is shifting towards the application of halide-free ILs for diversified applications. To clarify the situation on their greenness, and to understand if they really possess safe characteristics, we performed an initial assessment of 193 halide free ionic liquids composed of four groups of cations (imidazolium, pyridinium, pyrrodilinium, piperidinum) and 5 groups of anions (acetate, propionate, butyrate, alkanesulfonates, alkylsulfates). The ‘Technique for Order of Preference by Similarity to Ideal Solutions’ (TOPSIS), a multi-criteria decision analysis (MCDA) tool that allows ranking many alternatives is applied by carrying out the assessment against 14 criteria that includes hazard statements, precautionary statements, biodegradability, and toxicity towards different organisms. The ranking results obtained against the set of criteria considered show that the halide free ILs placed between recommended polar solvents: methanol and ethanol can be considered to be safer alternatives in terms of ‘greenness’. The study in this work provides an initial assessment of the halide-free ionic liquids evaluated against 14 criteria in terms of their safety characteristics (“green character”) using the MCDA-TOPSIS approach.
CFD Simulation and Performance Investigation on a Novel Bionic Spider-Web-Type Flow Field for PEM Fuel Cells
Authors: Xie Qizhen , Zheng Minggang
Published: September 2021

The products generated by the electrochemical reaction in the PEM fuel cell (PEMFC) are mainly concentrated in the flow field on the cathode side of the bipolar plate, and the oxygen introduced on the cathode has higher requirements to improve its diffusion performance by using the flow field structure. For this reason, the optimization of the cathode flow field of the PEMFC is essential. Inspired by the structure of a spider web, this paper proposes a novel spider-web-type flow field. In this kind of flow field, the shape of a polygonal structure and the number of layers of spiral flow channels are the two most crucial variables. In order to explore the impact of these two variables on the cathode flow field, complete three-dimensional PEMFC models with different values of the two variables were established, and the models were simulated by the method of CFD. By observing the results of oxygen distribution, the water removal performance and fuel cell output performance of different schemes, the optimal scheme of the polygonal structure and layer number are determined. Compared with the traditional flow field, it is proved that the optimization scheme is desirable in improving the performance of the cathode flow field in PEMFC.
Experimental Simulation of Hydrate Formation Process in a Circulating Device
Authors: Hečko Dávid , Mičko Pavol , Holubčík Michal , Kapjor Andrej
Published: September 2021

This paper focuses on the model of gas hydrate formation in an experimental device, which allows the circulation of the resulting mixture (water and gas) and significantly accelerates the process of hydrate formation in the laboratory. A 3D model was developed to better imagine the placement of individual parts of the device. The kinetics of hydrate formation were predicted from equilibrium values of chemical potentials. The aim of solving the equations of state gases in the mathematical model was to optimize the parameters involved in the formation of hydrates. The prediction of the mathematical model was verified by numerical simulation. The mathematical model and numerical simulation predict the chemical reaction evolving over time and determine the amount of crystallized water in the reactor. A remarkable finding is that the deviation of the model and simulation at the initiation the calculation of crystallized water starts at 76% and decreases over time to 2%. Subsequently, the number of moles of bound gas in the hydrate acquires the same percentage deviations. The amount of water supplied to the reactor is expressed by both methods identically with a maximum deviation of 0.10%. The different character is shown by the number of moles of gas remaining in the reactor. At the beginning of the calculation, the deviation of both methods is 0%, but over time the deviation slowly increases, and at the end it expresses the number of moles in the reactor with a deviation of 0.14%. By previous detection, we can confirm that the model successfully determines the amount of methane hydrate formed in the reactor of the experimental equipment. With the attached pictures from the realized experiment, we confirmed that the proposed method of hydrate production is tested and takes minutes. The article calculates the energy efficiency of natural gas hydrate in the proposed experimental device.
Real-Time Monitoring of Microalgal Biomass in Pilot-Scale Photobioreactors Using Nephelometry
Authors: Thoré Eli S. J. , Schoeters Floris , Spit Jornt , Van Miert Sabine
Published: September 2021

The increasing cultivation of microalgae in photobioreactors warrants efficient and non-invasive methods to quantify biomass density in real time. Nephelometric turbidity assessment, a method that measures light scatter by particles in suspension, was introduced already several decades ago but was only recently validated as a high-throughput tool to monitor microalgae biomass. The light scatter depends on the density of the suspended particles as well as on their physical properties, but so far there are hardly any accounts on how nephelometric assessment relates to classic methods such as dry weight and spectrophotometric measurement across a broad biomass density range for different microalgae species. Here, we monitored biomass density online and in real time during the semi-continuous cultivation of three commercial microalgae species Chloromonas typhlos, Microchloropsis gaditana and Porphyridium purpureum in pilot-scale photobioreactors, and relate nephelometric turbidity to dry weight and optical density. The results confirm a relatively strong (R2 = 0.87–0.93) and nonlinear relationship between turbidity and biomass density that differs among the three species. Overall, we demonstrate how nephelometry can be used to monitor microalgal biomass in photobioreactors, and provide the necessary means to estimate the biomass density of the studied species from turbidity data to facilitate automated biomass monitoring.
Cell Length Growth in the Fission Yeast Cell Cycle: Is It (Bi)linear or (Bi)exponential?
Authors: Pesti Benedek , Nagy Zsófia , Papp László , Sipiczki Matthias , Sveiczer Ákos
Published: September 2021

Fission yeast is commonly used as a model organism in eukaryotic cell growth studies. To describe the cells’ length growth patterns during the mitotic cycle, different models have been proposed previously as linear, exponential, bilinear and biexponential ones. The task of discriminating among these patterns is still challenging. Here, we have analyzed 298 individual cells altogether, namely from three different steady-state cultures (wild-type, wee1-50 mutant and pom1Δ mutant). We have concluded that in 190 cases (63.8%) the bilinear model was more adequate than either the linear or the exponential ones. These 190 cells were further examined by separately analyzing the linear segments of the best fitted bilinear models. Linear and exponential functions have been fitted to these growth segments to determine whether the previously fitted bilinear functions were really correct. The majority of these growth segments were found to be linear; nonetheless, a significant number of exponential ones were also detected. However, exponential ones occurred mainly in cases of rather short segments (<40 min), where there were not enough data for an accurate model fitting. By contrast, in long enough growth segments (≥40 min), linear patterns highly dominated over exponential ones, verifying that overall growth is probably bilinear.
Optimization Design of Centrifugal Pump Flow Control System Based on Adaptive Control
Authors: Wang Yuqin , Zhang Haodong , Han Zhibo , Ni Xiaoqiang
Published: September 2021

In this paper, in order to improve the control characteristics of the centrifugal pump flow control system, a mathematical model of the centrifugal pump flow control system was established based on an analysis of the basic structures, such as the frequency converter, motor, and centrifugal pump. Based on the adaptive control theory, the recursive least squares algorithm with a forgetting factor was used to estimate the real-time parameters of the centrifugal pump control system, and the self-tuning PID control method was used to optimize the mathematical model of the centrifugal pump flow control system. The simulation results showed that the adjustment time of the optimized system was shortened by 16.58%, and the maximum overshoot was reduced by 83.90%, which improved the rapidity and stability of the transient response of the system. This showed that adaptive control had a significant effect on improving the robustness and anti-interference ability of the centrifugal pump control system. In order to further verify the accuracy of the self-tuning PID control method, a flow adaptive control system test platform was built. The test results showed that under the conditions of constant frequency and variable frequency, the actual flow rate of the centrifugal pump was always kept near the set flow rate, the error was small, and it had better real-time followability. The research results showed that adaptive control could revise the parameters in real-time according to changes to the centrifugal pump control system, which improved the stability and robustness of the system. Therefore, adaptive PID control could effectively improve the adaptability of centrifugal pumps to various complex working conditions and improve the working efficiency of centrifugal pumps.
Biotransformation of Citrus Waste-II: Bio-Sorbent Materials for Removal of Dyes, Heavy Metals and Toxic Chemicals from Polluted Water
Authors: Mahato Neelima , Agarwal Pooja , Mohapatra Debananda , Sinha Mukty , Dhyani Archana , Pathak Brajesh , Tripathi Manwendra K. , Angaiah Subramania
Published: September 2021

Industrial processes and anthropogenic activities generate huge amounts of wastes in the form of chemicals, such as heavy metals, dyes, fertilizers, pharmaceutically active chemicals, battery effluents and so on. When these chemicals are left untreated and discarded in the ground or surface waters, they not only cause pollution and harm the ecosystem but also cause toxic effects on the health of human beings, animals and food crops. There are several methods of removal of these toxic materials from the wastewaters, and adsorption by bio-sorbents has been demonstrated as one of the most inexpensive, efficient and convenient methods. Citrus is one of the largest grown fruit crops in the tropical and subtropical regions on the planet. After processing of the fruits at food processing industries, approximately half of the fruit mass is discarded as waste, which causes a number of pollution problems. Alternately, this biomass can be converted to bio-sorbents for the removal of harmful and toxic chemicals from the industrial effluents and wastewaters. The first part of this article contains a thorough review on the biotransformation of citrus waste for the production of biofuel and valuable compounds by fermentation involving microorganisms. The second and concluding part reviews the recent progress in biotransformation of citrus waste biomass (that may be remaining post-extraction of valuable compounds/biofuel generation) into efficient adsorbent substrate materials and their adsorption capacities. The article also includes the details of the synthesis process and mechanisms of adsorption processes.
Numerical Characterization of Acoustic Cavitation Bubbles with Respect to the Bubble Size Distribution at Equilibrium
Authors: Kerboua Kaouther , Hamdaoui Oualid , Alghyamah Abdulaziz
Published: September 2021

In addition to bubble number density, bubble size distribution is an important population parameter governing the activity of acoustic cavitation bubbles. In the present paper, an iterative numerical method for equilibrium size distribution is proposed and combined to a model for bubble counting, in order to approach the number density within a population of acoustic cavitation bubbles of inhomogeneous sizing, hence the sonochemical activity of the inhomogeneous population based on discretization into homogenous groups. The composition of the inhomogeneous population is analyzed based on cavitation dynamics and shape stability at 300 kHz and 0.761 W/cm2 within the ambient radii interval ranging from 1 to 5 µm. Unstable oscillation is observed starting from a radius of 2.5 µm. Results are presented in terms of number probability, number density, and volume probability within the population of acoustic cavitation bubbles. The most probable group having an equilibrium radius of 3 µm demonstrated a probability in terms of number density of 27%. In terms of contribution to the void, the sub-population of 4 µm plays a major role with a fraction of 24%. Comparisons are also performed with the homogenous population case both in terms of number density of bubbles and sonochemical production of HO•,HO2•, and H• under an oxygen atmosphere.
Parallelization of a 3-Dimensional Hydrodynamics Model Using a Hybrid Method with MPI and OpenMP
Authors: Ahn Jung Min , Kim Hongtae , Cho Jae Gab , Kang Taegu , Kim Yong-seok , Kim Jungwook
Published: September 2021

Process-based numerical models developed to perform hydraulic/hydrologic/water quality analysis of watersheds and rivers have become highly sophisticated, with a corresponding increase in their computation time. However, for incidents such as water pollution, rapid analysis and decision-making are critical. This paper proposes an optimized parallelization scheme to reduce the computation time of the Environmental Fluid Dynamics Code-National Institute of Environmental Research (EFDC-NIER) model, which has been continuously developed for water pollution or algal bloom prediction in rivers. An existing source code and a parallel computational code with open multi-processing (OpenMP) and a message passing interface (MPI) were optimized, and their computation times compared. Subsequently, the simulation results for the existing EFDC model and the model with the parallel computation code were compared. Furthermore, the optimal parallel combination for hybrid parallel computation was evaluated by comparing the simulation time based on the number of cores and threads. When code parallelization was applied, the performance improved by a factor of approximately five compared to the existing source code. Thus, if the parallel computational source code applied in this study is used, urgent decision-making will be easier for events such as water pollution incidents.