bluuebunny/crossref_metadata_2025 huggingface dataset:
Design Optimization of Wearable Multiband Antenna Using Evolutionary Algorithm Tuned with Dipole Benchmark Problem
Authors: Januszkiewicz Łukasz , Barba Paolo Di , Kawecki Jarosław
Published: September 2021

In this paper we present the optimal design of wearable four band antenna that is suitable to work in the fifth-generation wireless systems as well as in cellular systems and in unlicensed bands. The design of the antenna relies on a careful study of optimization algorithms that are suitable for antenna design. We have proposed a benchmark problem to compare different optimization algorithms. It is the space of voltage standing wave ratio and the gain of dipole antenna that was identified for wide range of dipole length and radius. Using this pre-calculated data, we have tuned the parameters of optimization routine for optimal performance with our benchmark. After this, we optimized the geometry of four-band wearable antenna. In the optimization process, we used finite-difference time-domain method together with simplified model of human body. The antenna design was assessed with a fabricated prototype.
A Consolidated Review of Path Planning and Optimization Techniques: Technical Perspectives and Future Directions
Authors: Gul Faiza , Mir Imran , Abualigah Laith , Sumari Putra , Forestiero Agostino
Published: September 2021

In this paper, a review on the three most important communication techniques (ground, aerial, and underwater vehicles) has been presented that throws light on trajectory planning, its optimization, and various issues in a summarized way. This kind of extensive research is not often seen in the literature, so an effort has been made for readers interested in path planning to fill the gap. Moreover, optimization techniques suitable for implementing ground, aerial, and underwater vehicles are also a part of this review. This paper covers the numerical, bio-inspired techniques and their hybridization with each other for each of the dimensions mentioned. The paper provides a consolidated platform, where plenty of available research on-ground autonomous vehicle and their trajectory optimization with the extension for aerial and underwater vehicles are documented.
Prediction Comparison of Stand Parameters and Two Ecosystem Services through New Growth and Yield Model System for Mixed Nothofagus Forests in Southern Chile
Authors: Moreno-Meynard Paulo , Palmas Sebastian , Gezan Salvador A.
Published: September 2021

Forest managers need tools to predict the behavior of forests not only for the main stand parameters, such as basal area and volume, but also for ecosystem services such as timber volume and carbon sequestration. Useful tools to predict these parameters are growth and yield model systems with several possible options for modeling, such as the whole stand-level model, with or without diameter distribution generation, individual tree-level model, and compatibility models. However, those tools are scarce or developed mainly for forest plantations that are mostly located in the northern hemisphere. Thus, this study focuses on analyzing predictions of several growth and yield models built for native mixed Nothofagus forests from southern Chile, using the simulator Nothopack. A dataset of 19 permanent plots with three measurements were used for comparing the different models. Individual tree-level simulation presented the best goodness-of-fit statistics for stand parameters and ecosystem services. For example, the basal area gave an R2emp of 0.97 and 0.87 at 6 and 12 years of projection. However, the stand-level simulations with a generation of diameter distribution and both compatibility models showed satisfactory performance, both in accuracy and bias control. The simulator Nothopack, which has the capability of obtaining detailed outputs, is a useful tool to support management plans for these forest ecosystems.
A Review on Clustering Techniques: Creating Better User Experience for Online Roadshow
Authors: Lim Zhou-Yi , Ong Lee-Yeng , Leow Meng-Chew
Published: September 2021

Online roadshow is a relatively new concept that has higher flexibility and scalability compared to the physical roadshow. This is because online roadshow is accessible through digital devices anywhere and anytime. In a physical roadshow, organizations can measure the effectiveness of the roadshow by interacting with the customers. However, organizations cannot monitor the effectiveness of the online roadshow by using the same method. A good user experience is important to increase the advertising effects on the online roadshow website. In web usage mining, clustering can discover user access patterns from the weblog. By applying a clustering technique, the online roadshow website can be further improved to provide a better user experience. This paper presents a review of clustering techniques used in web usage mining, namely the partition-based, hierarchical, density-based, and fuzzy clustering techniques. These clustering techniques are analyzed from three perspectives: their similarity measures, the evaluation metrics used to determine the optimality of the clusters, and the functional purpose of applying the techniques to improve the user experience of the website. By applying clustering techniques in different stages of the user activities in the online roadshow website, the advertising effectiveness of the website can be enhanced in terms of its affordance, flow, and interactivity.
A Comprehensive Review of the Composition, Nutritional Value, and Functional Properties of Camel Milk Fat
Authors: Bakry Ibrahim A. , Yang Lan , Farag Mohamed A. , Korma Sameh A. , Khalifa Ibrahim , Cacciotti Ilaria , Ziedan Noha I. , Jin Jun , Jin Qingzhe , Wei Wei , Wang Xingguo
Published: September 2021

Recently, camel milk (CM) has been considered as a health-promoting icon due to its medicinal and nutritional benefits. CM fat globule membrane has numerous health-promoting properties, such as anti-adhesion and anti-bacterial properties, which are suitable for people who are allergic to cow’s milk. CM contains milk fat globules with a small size, which accounts for their rapid digestion. Moreover, it also comprises lower amounts of cholesterol and saturated fatty acids concurrent with higher levels of essential fatty acids than cow milk, with an improved lipid profile manifested by reducing cholesterol levels in the blood. In addition, it is rich in phospholipids, especially plasmalogens and sphingomyelin, suggesting that CM fat may meet the daily nutritional requirements of adults and infants. Thus, CM and its dairy products have become more attractive for consumers. In view of this, we performed a comprehensive review of CM fat’s composition and nutritional properties. The overall goal is to increase knowledge related to CM fat characteristics and modify its unfavorable perception. Future studies are expected to be directed toward a better understanding of CM fat, which appears to be promising in the design and formulation of new products with significant health-promoting benefits.
Fungal Biovalorization of a Brewing Industry Byproduct, Brewer’s Spent Grain: A Review
Authors: Marcus Andrew , Fox Glen
Published: September 2021

The beer industry is a major producer of solid waste globally, primarily in the form of brewer’s spent grain (BSG), which due to its low value has historically been diverted to livestock as feed or to landfills. However, its high moisture content and chemical composition positions BSG as an ideal candidate for further processing with microbial fermentation. Recent research has focused on filamentous fungi and the ability of some species therein to degrade the predominant recalcitrant cellulolignin components of BSG to produce valuable compounds. Many species have been investigated to biovalorize this waste stream, including those in the genuses Aspergillus, Penicillium, Rhyzopus, and Trichoderma, which have been used to produce a wide array of highly valuable enzymes and other functional compounds, and to increase the nutritional value of BSG as an animal feed. This review of recent developments in the application of filamentous fungi for the valorization of BSG discusses the biochemical makeup of BSG, the biological mechanisms underlying fungi’s primacy to this application, and the current applications of fungi in this realm.
Survival of Escherichia coli O157:H7 during Moderate Temperature Dehydration of Plant-Based Foods
Authors: Rana Yadwinder Singh , Eberly Philip M. , Suehr Quincy J. , Hildebrandt Ian M. , Marks Bradley P. , Snyder Abigail B.
Published: September 2021

The effect of moderate-temperature (≤60 °C) dehydration of plant-based foods on pathogen inactivation is unknown. Here, we model the reduction of E. coli O157:H7 as a function of product-matrix, aw, and temperature under isothermal conditions. Apple, kale, and tofu were each adjusted to aw 0.90, 0.95, or 0.99 and inoculated with an E. coli O157:H7 cocktail, followed by isothermal treatment at 49, 54.5, or 60.0 °C. The decimal reduction time, or D-value, is the time required at a given temperature to achieve a 1 log reduction in the target microorganism. Modified Bigelow-type models were developed to determine D-values which varied by product type and aw level, ranging from 3.0–6.7, 19.3–55.3, and 45.9–257.4 min. The relative impact of aw was product dependent and appeared to have a non-linear impact on D-values. The root mean squared errors of the isothermal-based models ranged from 0.75 to 1.54 log CFU/g. Second, we performed dynamic drying experiments. While the isothermal results suggested significant microbial inactivation might be achieved, the dehydrator studies showed that the combination of low product temperature and decreasing aw in the pilot-scale system provided minimal inactivation. Pilot-scale drying at 60 °C only achieved reductions of 3.1 ± 0.8 log in kale and 0.67 ± 0.66 log in apple after 8 h, and 0.69 ± 0.67 log in tofu after 24 h. This illustrates the potential limitations of dehydration at ≤60 °C as a microbial kill step.
Histone Acetylation Changes in Plant Response to Drought Stress
Authors: Li Shuang , He Xu , Gao Yuan , Zhou Chenguang , Chiang Vincent L. , Li Wei
Published: September 2021

Drought stress causes recurrent damage to a healthy ecosystem because it has major adverse effects on the growth and productivity of plants. However, plants have developed drought avoidance and resilience for survival through many strategies, such as increasing water absorption and conduction, reducing water loss and conversing growth stages. Understanding how plants respond and regulate drought stress would be important for creating and breeding better plants to help maintain a sound ecosystem. Epigenetic marks are a group of regulators affecting drought response and resilience in plants through modification of chromatin structure to control the transcription of pertinent genes. Histone acetylation is an ubiquitous epigenetic mark. The level of histone acetylation, which is regulated by histone acetyltransferases (HATs) and histone deacetylases (HDACs), determines whether the chromatin is open or closed, thereby controlling access of DNA-binding proteins for transcriptional activation. In this review, we summarize histone acetylation changes in plant response to drought stress, and review the functions of HATs and HDACs in drought response and resistance.
Relationship between Heart Rate Variability and Functional Fitness in Breast Cancer Survivors: A Cross-Sectional Study
Authors: Martins Alexandre D. , Brito João Paulo , Oliveira Rafael , Costa Tiago , Ramalho Fátima , Santos-Rocha Rita , Pimenta Nuno
Published: September 2021

Background: Breast cancer is the most common malignancy among women worldwide. The treatments may also cause neuromuscular and skeletal disorders; therefore, the aim of this study was to verify the existence of a relationship between heart rate variability and different functional fitness parameters in women survivors of breast cancer. Methods: This cross-sectional study included 25 women survivors of breast cancer, with a mean ± SD age, height, and body mass of 50.8 ± 8.8 years, 1.6 ± 0.7 m, and 67.1 ± 12.3 kg, respectively. Patients underwent measurements of heart rate variability with time and frequency domain analyses, as well as a “30 s chair-stand test”, “6 min walking test”, “timed up and go test”, and “ball throwing test”. Results: A multiple linear regression analysis showed that from the heart rate variability frequency domain, high frequency explained 21% (R2 = 0.21) of the “30 s chair-stand test” performance. Conclusion: The findings of this study highlight high frequency as a predictor of “30 s chair-stand test” performance, regardless of age and time after diagnosis, suggesting its usefulness as a clinical indicator of functionality in breast cancer survivors. This study presents a straightforward and non-invasive methodology predicting functional fitness in women breast cancer survivors potentially applicable to clinical practice.
Factors Facilitating and Hindering Development of a Medication Use Review Service in Eastern Europe and Iran-Cross-Sectional Exploratory Study
Authors: Tuula Anita , Volmer Daisy , Jõhvik Liisa , Rutkovska Ieva , Trečiokienė Indre , Merks Piotr , Waszyk-Nowaczyk Magdalena , Drozd Mariola , Tatarević Alena , Radovanlija Maja , Pacadi Carmen , Meštrović Arijana , Viola Réka , Soós Gyöngyvér , Rais Cristina , Táerel Adriana-Elena , Kuzelova Magdalena , Zare Marziyeh , Peymani Payam , Oona Marje , Scott Michael
Published: September 2021

Polypharmacy is a common issue in patients with chronic diseases. Eastern-European countries and Iran are exploring possibilities for implementing the Medication Use Review (MUR) as a measure for optimizing medication use and ensuring medication safety in polypharmacy patients. The aim of this study was to gain insights into the development of the community pharmacy sector and map facilitators and barriers of MUR in Eastern Europe and Iran. The representatives of the framework countries received a questionnaire on community pharmacy sector indicators, current and future developments of pharmacies, and factors encouraging and hindering MUR. To answer the questionnaire, all representatives performed document analysis, literature review, and qualitative interviews with key stakeholders. The socio-ecological model was used for inductive thematic analysis of the identified factors. Current community pharmacist competencies in framework countries were more related to traditional pharmacy services. Main facilitators of MUR were increase in polypharmacy and pharmaceutical waste, and access to patients’ electronic list of medications by pharmacists. Main barriers included the service being unfamiliar, lack of funding and private consultation areas. Pharmacists in the framework countries are well-placed to provide MUR, however, the service needs more introduction and barriers mostly on organizational and public policy levels must be addressed.
Weed Control, Growth, Nodulation, Quality and Storability of Peas as Affected by Pre- and Postemergence Herbicides
Authors: Abdallah Ibrahim S. , Abdelgawad Karima F. , El-Mogy Mohamed M. , El-Sawy Mohamed B. I. , Mahmoud Hend A. , Fahmy Mahmoud A. M.
Published: September 2021

Weeds represent a major constraint for successful pea cultivation, resulting in loss of green pea yield and quality. Two field experiments were carried out during the winter seasons of 2018/2019 and 2019/2020. The objectives of the current study were to evaluate the efficacy of pendimethalin, butralin, fluazifop butyl, bentazon, and hoeing on weed control, and their impact on pea growth, nodule formation, yield, quality, and storability. The results indicated that hoeing and fluazifop butyl were the most effective treatments for weed control in terms of the lowest values of total weed dry weight. The bentazon and fluazifop butyl herbicides didn’t affect active nodules number, plant height, plant weight, root length, or number of leaves and branches. Additionally, bentazon and hoeing resulted in the highest total yield per plant and protein content. Butralin and pendimetalin achieved the lowest yield, and butralin also resulted in the lowest plant height and weight. Bentazon-treated peas had the highest chemical compositions in terms of chlorophyll, carotenoids, total sugar, and vitamin C contents in pea pods at harvest and during cold storage at 4 °C and 95 RH for 45 days. No detectable residues of the four herbicides under study were detected in green pods, suggesting that pods can be safely consumed at the time of harvesting. It can be concluded that nodules formation in pea was not affected significantly by the application of the tested herbicides, except pendimethalin and butralin. Furthermore, bentazon had a positive impact on nodules formation and pods quality and could be used effectively for controlling the broadleaf weeds, and it was simultaneously a selective and safe herbicide in pea cultivation.
Anti-Inflammatory Effect of Muscle-Derived Interleukin-6 and Its Involvement in Lipid Metabolism
Authors: Nara Hidetoshi , Watanabe Rin
Published: September 2021

Interleukin (IL)-6 has been studied since its discovery for its role in health and diseases. It is one of the most important pro-inflammatory cytokines. IL-6 was reported as an exacerbating factor in coronavirus disease. In recent years, it has become clear that the function of muscle-derived IL-6 is different from what has been reported so far. Exercise is accompanied by skeletal muscle contraction, during which, several bioactive substances, collectively named myokines, are secreted from the muscles. Many reports have shown that IL-6 is the most abundant myokine. Interestingly, it was indicated that IL-6 plays opposing roles as a myokine and as a pro-inflammatory cytokine. In this review, we discuss why IL-6 has different functions, the signaling mode of hyper-IL-6 via soluble IL-6 receptor (sIL-6R), and the involvement of soluble glycoprotein 130 in the suppressive effect of hyper-IL-6. Furthermore, the involvement of a disintegrin and metalloprotease family molecules in the secretion of sIL-6R is described. One of the functions of muscle-derived IL-6 is lipid metabolism in the liver. However, the differences between the functions of IL-6 as a pro-inflammatory cytokine and the functions of muscle-derived IL-6 are unclear. Although the involvement of myokines in lipid metabolism in adipocytes was previously discussed, little is known about the direct relationship between nonalcoholic fatty liver disease and muscle-derived IL-6. This review is the first to discuss the relationship between the function of IL-6 in diseases and the function of muscle-derived IL-6, focusing on IL-6 signaling and lipid metabolism in the liver.
Hypergraph Application on Business Process Performance
Authors: Bouafia Khawla , Molnár Bálint
Published: September 2021

The modeling of the graphical representation of business processes (BP) or workflows in enterprise information systems (IS) is often to represent various activities, entities, relations, functions, and communicate between them in an enterprise to achieve the major goal of operational support. In this work, we decided to use graph representation approaches, especially hypergraphs to depict the complex relationships that exist among the artifacts and constituents of BP for more efficient and accurate manipulations. We used bipartite and further hypergraph formats for storing and curating data. We have investigated the various descriptive languages and representation models of BP as process modeling, workflow and process integration, and object-oriented (OO) languages. We have carried out experiments using different approach combinations, but for observing quiltedrepresentation, we focused on the main consistencies of “DBP”. As the final approach, we used the “DBP” stream and data schemes that are defined by us to proceed with using pure Python for manually generating data and external Python libraries to store, curate, and visualize “DBP”.
A Novel Joint TDOA/FDOA Passive Localization Scheme Using Interval Intersection Algorithm
Authors: Ai Lingyu , Pang Min , Shan Changxu , Sun Chao , Kim Youngok , Zhou Biao
Published: September 2021

Due to the large measurement error in the practical non-cooperative scene, the passive localization algorithms based on traditional numerical calculation using time difference of arrival (TDOA) and frequency difference of arrival (FDOA) often have no solution, i.e., the estimated result cannot meet the localization background knowledge. In this context, this paper intends to introduce interval analysis theory into joint FDOA/TDOA-based localization algorithm. The proposed algorithm uses the dichotomy algorithm to fuse the interval measurement of TDOA and FDOA for estimating the velocity and position of a moving target. The estimation results are given in the form of an interval. The estimated interval must contain the true values of the position and velocity of the radiation target, and the size of the interval reflects the confidence of the estimation. The point estimation of the position and the velocity of the target is given by the midpoint of the estimation interval. Simulation analysis shows the efficacy of the algorithm.
Sensory Nerve Conduction Velocity Predicts Improvement of Hand Function with Nerve Gliding Exercise Following Carpal Tunnel Release Surgery
Authors: Tamaru Yoshiki , Yanagawa Akiyoshi , Matsugi Akiyoshi
Published: September 2021

This study aims to investigate the effects of nerve gliding exercise following carpal tunnel release surgery (NGE-CTRS) and the probing factors affecting the effect of NGE-CTRS on hand function. A total of 86 patients after CTRS participated. Grip strength (grip-s), pinch strength (pinch-s), Semmes-Weinstein monofilament test (SWMT), two-point discrimination (2PD), numbness, pain, and Phalen test (Phalen) were measured and compared between pre- and post-NGE-CTRS. The results showed that the combination of surgery and NGE significantly improved the postoperative grip-s, pinch-s, SWMT, 2PD, numbness, and Phalen; however, no improvement was observed in pain. Background factors that influenced the improved grip-s and pinch-s included gender and preoperative sensory nerve conduction velocity (SCV). Additionally, numbness and Phalen were not affected by age, gender, fault side, bilateral, trigger finger, dialysis, thenar eminence atrophy, motor nerve conduction velocity, SCV, the start of treatment, and occupational therapy intervention. In conclusion, the combination of surgical procedures and NGE showed a high improvement. SCV and time-to-start treatment of intervention for carpal tunnel syndrome may be useful in predicting the function after the intervention.
Telemedicine Strategy to Rescue CPAP Therapy in Sleep Apnea Patients with Low Treatment Adherence: A Pilot Study
Authors: Garmendia Onintza , Farré Ramon , Ruiz Concepción , Suarez-Girón Monique , Torres Marta , Cebrian Raisa , Saura Laura , Monasterio Carmen , Negrín Miguel A. , Montserrat Josep M.
Published: September 2021

Patients with sleep apnea are usually treated with continuous positive airway pressure (CPAP). This therapy is very effective if the patient′s adherence is satisfactory. However, although CPAP adherence is usually acceptable during the first months of therapy, it progressively decreases, with a considerable number of patients accepting average treatment duration below the effectiveness threshold (4 h/night). Herein, our aim was to describe and evaluate a novel telemedicine strategy for rescuing CPAP treatment in patients with low adherence after several months/years of treatment. This two-week intervention includes (1) patient support using a smartphone application, phone and voice recorder messages to be answered by a nurse, and (2) daily transmission and analysis of signals from the CPAP device and potential variation of nasal pressure if required. On average, at the end of the intervention, median CPAP adherence considerably increased by 2.17 h/night (from 3.07 to 5.24 h/night). Interestingly, the procedure was able to markedly rescue CPAP adherence: the number of patients with poor adherence (<4 h/night) was considerably reduced from 38 to 7. After one month, adherence improvement was maintained (median 5.09 h/night), and only 13 patients had poor adherence (<4 h/night). This telemedicine intervention (103€ per included patient) is a cost-effective tool for substantially increasing the number of patients with CPAP adherence above the minimum threshold for achieving positive therapeutic effects.
Influence of the Computer-Aided Static Navigation Technique on the Accuracy of the Orthodontic Micro-Screws Placement: An In Vitro Study
Authors: Torres Paulina Rodríguez , Gil Sergio Toledano , Zubizarreta-Macho Álvaro , Pérez María Bufalá , Deglow Elena Riad , Tzironi Georgia , Martínez Alberto Albaladejo , Montero Sofía Hernández
Published: September 2021

To analyze the influence of the computer-aided static navigation technique on the accuracy of placement of orthodontic micro-screws. One hundred and thirty-eight orthodontic micro-screws were randomly assigned to the following study groups: Group A. orthodontic micro-screw placement using a computer-aided static navigation technique (n = 69); B. orthodontic micro-screw placement using the conventional freehand technique (n = 69). In addition, the accuracy in the canine–premolar, premolar and molar sectors was analyzed in each study group. Cone-beam computed tomography and intraoral scans were taken both prior and subsequent to orthodontic micro-screw placement. The images were then uploaded using a 3D implant planning software, where the deviation and horizontal angles were analyzed using a multivariate linear model. These measurements were taken at the coronal entry point and apical endpoint between the planned orthodontic micro-screws. In addition, any complications resulting from micro-screw placement, such as spot perforations, were also analyzed in all dental sectors. The statistical analysis showed significant differences between the two study groups with regard to the coronal entry-point, apical end-point (p < 0.001) and angular deviations (p < 0.001) between the computer-aided static navigation technique and freehand technique study groups. Moreover, statistically significant differences were showed between the different dental sectors (p < 0.001). Additionally, twelve root perforations were observed at the conventional free hand technique study group while there were no root perforations in the computer-aided static navigation technique study group. The results showed that the computer-aided static navigation technique enables a more accurate orthodontic micro-screw placement with less intraoperative complications when compared with the conventional freehand technique.
Is the Prevalence of Equinus Foot in Cerebral Palsy Overestimated? Results from a Meta-Analysis of 4814 Feet
Authors: Horsch Axel , Klotz Matthias C. M. , Platzer Hadrian , Seide Svenja , Zeaiter Nancy , Ghandour Maher
Published: September 2021

Background: Equinus is a common foot deformity in patients with cerebral palsy (CP). However, its prevalence is scarcely reported in the literature. Therefore, we conducted this review to estimate the prevalence of equinus foot in CP. Methods: Eight databases were searched. Our primary outcome was the prevalence of equinus foot in CP patients. Subgroup analysis was conducted based on study design, the laterality of CP, and whether equinus foot was defined or not. Results: The prevalence of equinus foot in CP was 93% (95% CI: 71–99). The prevalence was 99% (95% CI: 55–100), 96% (95% CI: 57–100), and 65% (95% CI: 37–86) in unilateral, both, and bilateral CP, respectively. Based on study design, equinus foot prevalence was 92% (95% CI: 34–100) in case series and 62% (95% CI: 47–74) in cohort studies. Four studies reported definition criteria for equinus foot, with a pooled prevalence rate of equinus foot of 99% (95% CI: 36–100) compared to a rate of 89% (95% CI: 59–98) among studies that lacked a definition criterion. Conclusions: This is the first meta-analysis to address the prevalence of equinus foot in CP patients. Although its prevalence is very high, our findings should be interpreted with caution due to the presence of multiple limitations, such as the lack of standardized definition criteria for equinus foot, the inappropriate study design, the wide confidence interval of equinus foot rate, and the small number of studies investigating it as a primary outcome.
Bulk Chemical and Optical Spectroscopy Characterisations of Dissolved Organic Matter Extracted from the Tropical Coastal Sediment
Authors: Dzulkafli Noor Fazreen , Mahdzir Akbariah , Hara Hirofumi
Published: September 2021

The study of organic matter characterisation in coastal sediment is useful for understanding how dissolved organic matter (DOM) reactivity influences the fate of pollutants in the aquatic environment. However, there is little information available on the structural properties of DOM in coastal sediment. Chemical analysis, UV-Visible (UV-Vis) absorbance, fluorescence, and Fourier-transform infrared (FTIR) spectroscopy were used in this work to characterise and compare the components of water-extractable organic matter (WEOM) fractions from sediment from an estuary, a coastal area, and a port in Peninsular Malaysia, Malaysia. The elemental analysis (H/C and C/N ratios) of the three samples differed, which coincided with the findings of optical indices estimated from UV-Visible and fluorescent spectroscopy analyses. WEOM had an average output of 7.05 to 8.47 mg/L and was very dominating with heavy fraction organic carbon (HFOC). In DOM-KS and DOM-K sediments, the allochthonous component with a high degree of condensation and the aromatic compound was the dominating composition. Meanwhile, the DOM-KT possessed a high autochthonous composition as well as carboxylic and phenolic content. Correlation analysis indicates that the aromaticity index SUVA254 and humification index (HIX) have positive correlations. The combined results of the chemical and spectroscopic analyses indicate that different coastal ecosystems, with the integration of various human and land activities, produce variations in DOM in the coastal area.
Organizational Structure and Artificial Intelligence. Modeling the Intraorganizational Response to the AI Contingency
Authors: Rudko Ihor , Bashirpour Bonab Aysan , Bellini Francesco
Published: September 2021

Different and profound are the consequences of the further development of artificial intelligence (AI) on society. One of the manifestations of the upcoming changes is the plethora of novel ways in which companies may organize labor and capital. So far, the influence of AI on organizational structure has been mainly studied from either a technological or a broader decision-making perspective. Our paper provides a unique take on the topic, emphasizing the distinctive role of human agency and its function in the upcoming AI-driven organizational changes. Relying on the existing academic literature, we theorized a set of hypotheses concerning best fits to the AI contingency on both macro and meso-organizational levels. To test whether the hypothesized changes might encounter organizational inertia or resistance from jobholders, multiple correspondence analysis (MCA) was applied to the online survey results. Four types of current and potential jobholders were distinguished according to their explicit attitudes towards hypothesized organizational changes: skeptics, doubtful skeptics, optimists, and doubtful optimists, the latter consisting primarily of emerging adults. Finally, we developed a model of intraorganizational response to the AI contingency based on four theoretical groups of individuals, as determined by the analysis. Our findings showed doubtful optimists to be the most important group, able to set organizational trends and positively influence skeptics and doubtful skeptics. Accordingly, promoters of AI-driven organizational changes are advised to design their communication efforts around emerging adults. As the survey was conducted amid the COVID-19 pandemic, its sociological and managerial implications are relevant to the looming reality of the postpandemic world.
Whole-Genome Resequencing Points to Candidate DNA Loci Affecting Body Temperature under Cold Stress in Siberian Cattle Populations
Authors: Igoshin Alexander , Yudin Nikolay , Aitnazarov Ruslan , Yurchenko Andrey A. , Larkin Denis M.
Published: September 2021

Despite the economic importance of creating cold resilient cattle breeds, our knowledge of the genetic basis of adaptation to cold environments in cattle is still scarce compared to information on other economically important traits. Herein, using whole-genome resequencing of animals showing contrasting phenotypes on temperature maintenance under acute cold stress combined with the existing SNP (single nucleotide polymorphism) functional annotations, we report chromosomal regions and candidate SNPs controlling body temperature in the Siberian cattle populations. The SNP ranking procedure based on regional FST calculations, functional annotations, and the allele frequency difference between cold-tolerant and cold-sensitive groups of animals pointed to multiple candidate genes. Among these, GRIA4, COX17, MAATS1, UPK1B, IFNGR1, DDX23, PPT1, THBS1, CCL5, ATF1, PLA1A, PRKAG1, and NR1I2 were previously related to thermal adaptations in cattle. Other genes, for example KMT2D and SNRPA1, are known to be related to thermogenesis in mice and cold adaptation in common carp, respectively. This work could be useful for cattle breeding strategies in countries with harsh climates, including the Russian Federation.
Multiscale Analysis of Mechanical Properties of 3D Orthogonal Woven Composites with Randomly Distributed Voids
Authors: Gong Yaohua , Huang Tao , Zhang Xun’an , Suo Yongyong , Jia Purong , Zhao Shuyi
Published: September 2021

Voids are common defects in 3D woven composites because of the complicated manufacturing processes of the composites. In this study, a micro–meso multiscale analysis was conducted to evaluate the influence of voids on the mechanical properties of three-dimensional orthogonal woven composites. Statistical analysis was implemented to calculate the outputs of models under the different scales. A method is proposed to generate the reasonable mechanical properties of the microscale models considering randomly distributed voids and fiber filaments. The distributions of the generated properties agree well with the calculated results. These properties were utilized as inputs for the mesoscale models, in which void defects were also considered. The effects of these defects were calculated and investigated. The results indicate that tensile and shear strengths were more sensitive to the microscale voids, while the compressive strength was more influenced by mesoscale voids. The results of this study can provide a design basis for evaluating the quality of 3D woven composites with void defects.
Modification of Gold Zeolitic Supports for Catalytic Oxidation of Glucose to Gluconic Acid
Authors: Walkowiak Adrian , Wolska Joanna , Wojtaszek-Gurdak Anna , Sobczak Izabela , Wolski Lukasz , Ziolek Maria
Published: September 2021

Activity of gold supported catalysts strongly depends on the type and composition of support, which determine the size of Au nanoparticles (Au NPs), gold-support interaction influencing gold properties, interaction with the reactants and, in this way, the reaction pathway. The aim of this study was to use two types of zeolites: the three dimensional HBeta and the layered two-dimensional MCM-36 as supports for gold, and modification of their properties towards the achievement of different properties in oxidation of glucose to gluconic acid with molecular oxygen and hydrogen peroxide. Such an approach allowed establishment of relationships between the activity of gold catalysts and different parameters such as Au NPs size, electronic properties of gold, structure and acidity of the supports. The zeolites were modified with (3-aminopropyl)-trimethoxysilane (APMS), which affected the support features and Au NPs properties. Moreover, the modification of the zeolite lattice with boron was applied to change the strength of the zeolite acidity. All modifications resulted in changes in glucose conversion, while maintaining high selectivity to gluconic acid. The most important findings include the differences in the reaction steps limiting the reaction rate depending on the nature of the oxidant applied (oxygen vs. H2O2), the important role of porosity of the zeolite supports, and accumulation of negative charge on Au NPs in catalytic oxidation of glucose.
Oxidation of MBE-Grown ZnTe and ZnTe/Zn Nanowires and Their Structural Properties
Authors: Gas Katarzyna , Kret Slawomir , Zaleszczyk Wojciech , Kamińska Eliana , Sawicki Maciej , Wojtowicz Tomasz , Szuszkiewicz Wojciech
Published: September 2021

Results of comparative structural characterization of bare and Zn-covered ZnTe nanowires (NWs) before and after thermal oxidation at 300 °C are presented. Scanning electron microscopy, energy-dispersive X-ray spectroscopy, high-resolution transmission electron microscopy, and Raman scattering not only unambiguously confirm the conversion of the outer layer of the NWs into ZnO, but also demonstrate the influence of the oxidation process on the structure of the inner part of the NWs. Our study shows that the morphology of the resulting ZnO can be improved by the deposition of thin Zn shells on the bare ZnTe NWs prior to the oxidation. The oxidation of bare ZnTe NWs results in the formation of separated ZnO nanocrystals which decorate crystalline Te cores of the NWs. In the case of Zn-covered NWs, uniform ZnO shells are formed, however they are of a fine-crystalline structure or partially amorphous. Our study provides an important insight into the details of the oxidation processes of ZnTe nanostructures, which could be of importance for the preparation and performance of ZnTe based nano-devices operating under normal atmospheric conditions and at elevated temperatures.
Micromagnetic Microstructure- and Stress-Independent Materials Characterization in Reactor Safety Research
Authors: Zimmer Cyril , Rallabandi Yashashwini Nikhitha , Szielasko Klaus , Eichheimer Christian , Luke Michael , Youssef Sargon
Published: September 2021

Reactor safety research aims at the safe operation of nuclear power plants during their service life. In this respect, Fraunhofer IZFP’s micromagnetic multiparameter, microstructure, and stress analysis (3MA) has already made a significant contribution to the understanding of different aging mechanisms of component materials and their characterization. The basis of 3MA is the fact that microstructure and mechanical stress determine both the mechanical and magnetic material behavior. The correlation between features of magnetic and mechanical material behavior enables the micromagnetic prediction of mechanical properties and stress, both of which can decisively influence the service life. The Federal Ministry for Economic Affairs and Energy (BMWi) funded this research, handling the mutually superimposed microstructural and stress-dependent influences, a substantial challenge, especially under practical conditions. This superposition leads to ambiguities in the micromagnetic features. The 3MA testing system has been extended by more sophisticated evaluation methods being able to cope with more complex datasets. Investigations dealing with the expansion of the feature extraction and machine learning methods have led to a more precise distinction between microstructural and stress-dependent influences. This approach provides the basis for future applications in reactor safety.
Investigation of Mechanical Properties and Salt Spray Corrosion Test Parameters Optimization for AA8079 with Reinforcement of TiN + ZrO2
Authors: Sathish T. , Mohanavel V. , Arunkumar T. , Raja T. , Rashedi Ahmad , Alarifi Ibrahim M. , Badruddin Irfan Anjum , Algahtani Ali , Afzal Asif
Published: September 2021

This work mainly focuses on increasing the mechanical strength and improving the corrosion resistance of an aluminum alloy hybrid matrix. The composites are prepared by the stir casting procedure. For this work, aluminum alloy 8079 is considered as a base material and titanium nitride and zirconium dioxide are utilized as reinforcement particles. Mechanical tests, such as the ultimate tensile strength, wear, salt spray corrosion test and microhardness test, are conducted effectively in the fabricated AA8079/TiN + ZrO2 composites. L9 OA statistical analysis is executed to optimize the process parameters of the mechanical and corrosion tests. ANOVA analysis defines the contribution and influence of each parameter. In the tensile and wear test, parameters are chosen as % of reinforcement (3%, 6% and 9%), stirring speed (500, 550 and 600 rpm) and stirring time (20, 25 and 30 min). Similarly, in the salt spray test and microhardness test, the selected parameters are: percentage of reinforcement (3%, 6% and 9%), pH value (3, 6 and 9), and hang time (24, 48 and 72 h). The percentage of reinforcement highly influenced the wear and microhardness test, while the stirring time parameter extremely influenced the ultimate tensile strength. From the corrosion test, the hang time influences the corrosion rate. The SEM analysis highly reveals the bonding of each reinforcement particle to the base material.
Design of Self-Supported Flexible Nanostars MFe-LDH@ Carbon Xerogel-Modified Electrode for Methanol Oxidation
Authors: Abdelrazek Ghada M. , EL-Deeb Mohamed M. , Farghali Ahmed A. , Pérez-Cadenas Agustín F. , Abdelwahab Abdalla
Published: September 2021

Layered double hydroxides (LDHs) have emerged as promising electrodes materials for the methanol oxidation reaction. Here, we report on the preparation of different LDHs with the hydrothermal process. The effect of the divalent cation (i.e., Ni, Co, and Zn) on the electrochemical performance of methanol oxidation was investigated. Moreover, nanocomposites of LDHs and carbon xerogels (CX) supported on nickel foam (NF) substrate were prepared to investigate the role of carbon xerogel. The results show that NiFe-LDH/CX/NF is an efficient electrocatalyst for methanol oxidation with a current density that reaches 400 mA·m−2 compared to 250 and 90 mA·cm−2 for NiFe-LDH/NF and NF, respectively. In addition, all LDH/CX/NF nanocomposites show excellent stability for methanol oxidation. A clear relationship is observed between the electrodes crystallite size and their activity to methanol oxidation. The smaller the crystallite size, the higher the current density delivered. Additionally, the presence of carbon xerogel in the nanocomposites offer 3D interconnected micro/mesopores, which facilitate both mass and electron transport.
Synthesis and Characterization of a Trifunctional Photoinitiator Based on Two Commercial Photoinitiators with α-Hydroxyl Ketone Structure
Authors: Zhong Rong , Hu Hui , Zhou Yanfang
Published: September 2021

A trifunctional photoinitiator based on commercial photoinitiators 2-hydroxy-2-methylpropiophenone (Irgacure1173) and 2-hydroxy-4′-(2-hydroxyethoxy)-2-methylpropiophenone (Irgacure2959) was synthesized by an esterization reaction. Its structure was characterized by UV-Vis spectrometry, Infrared Transformed Fourier, Proton Nuclear Magnetic Resonance Spectra, 13 Carbon Nuclear Magnetic Resonance Spectra, Mass Spectrometry, and Thermogravimetry. In addition, its photoinitiating activity was investigated. The results showed that the novel photoinitiator had good photoinitiating activity and thermal stability compared to commercial photoinitiators. The migration of the residual photoinitiator in the cured film was lower than that of 1173 and 2959.
Complications of Intra-Arterial tPA for Iatrogenic Branch Retinal Artery Occlusion: A Case Report through Multimodal Imaging and Literature Review
Authors: Dalzotto Katherine , Richards Paige , Boulter Tyler D. , Kay Marilyn , Mititelu Mihai
Published: September 2021

Background and Objectives: To document, through multimodal imaging, the post-procedural clinical course and visual outcome of a patient who received intra-arterial tissue plasminogen activator (tPA) for acute iatrogenic branch retinal artery occlusion (BRAO), and to review the literature and guidelines regarding the use of tPA for retinal arterial occlusions. Methods: A 28-year-old female patient who sustained an iatrogenic BRAO and subsequently received intra-arterial tPA was followed through her post-interventional course of 3 months with serial exams and multimodal imaging, including color fundus photography, visual field testing, spectral domain optical coherence tomography (SD-OCT), and OCT angiography (OCT-A). Results: A patient with history of left internal cerebral artery (ICA) aneurysm and baseline visual acuity (VA) of 20/20 developed an acutely symptomatic BRAO after undergoing a neuroendovascular procedure and was acutely treated with tPA through the left ophthalmic artery. At two weeks follow-up, a central posterior pole hemorrhage was noted although VA was preserved. A superior altitudinal defect was shown on automated perimetry. VA dropped to 20/50 at 7 weeks follow-up and hyperreflective material deep to the attachment between the posterior hyaloid and the internal limiting membrane (ILM) consistent with hemorrhage was noted on SD-OCT. At 11 weeks follow-up, VA returned to 20/20, SD-OCT revealed a membrane bridging the foveal depression, OCT-A showed decreased vascularity in the inferior macula, and the visual field defect was stable by automated perimetry. Conclusions: Intraocular hemorrhage is a possible complication of intra-arterial tPA administration for BRAO, and a careful analysis of risks, benefits, and goals of this procedure must be considered by both provider and patient before such intervention.
The Risk of Clostridioides difficile Infection in Cirrhotic Patients Receiving Norfloxacin for Secondary Prophylaxis of Spontaneous Bacterial Peritonitis—A Real Life Cohort
Authors: Girleanu Irina , Trifan Anca , Huiban Laura , Muzica Cristina , Nemteanu Roxana , Teodorescu Andreea , Singeap Ana Maria , Cojocariu Camelia , Chiriac Stefan , Petrea Oana , Zenovia Sebastian , Nastasa Robert , Cuciureanu Tudor , Stanciu Carol
Published: September 2021

Background and Objectives: Spontaneous bacterial peritonitis (SBP) is a life-threatening complication of liver cirrhosis. Antibiotic prophylaxis is effective but can lead to an increased incidence of Clostridioides difficile infection (CDI). The aim of this study was to evaluate the incidence of CDI and the risk factors in cirrhotic patients with a previous episode of SBP receiving norfloxacin as secondary prophylaxis. Materials and Methods: We performed a prospective, cohort study including patients with liver cirrhosis and SBP, successfully treated over a 2-year period in a tertiary university hospital. All the patients received secondary prophylaxis for SBP with norfloxacin 400 mg/day. Results: There were 122 patients with liver cirrhosis and SBP included (mean age 57.5 ± 10.8 years, 65.5% males). Alcoholic cirrhosis was the major etiology accounting for 63.1% of cases. The mean MELD score was 19.7 ± 6.1. Twenty-three (18.8%) of all patients developed CDI during follow-up, corresponding to an incidence of 24.8 cases per 10,000 person-years. The multivariate Cox regression analysis demonstrated that alcoholic LC etiology (HR 1.40, 95% CI 1.104–2.441, p = 0.029) and Child-Pugh C class (HR 2.50, 95% CI 1.257–3.850, p = 0.034) were independent risk factors for CDI development during norfloxacin secondary prophylaxis. The development of CDI did not influence the mortality rates in cirrhotic patients with SBP receiving norfloxacin. Conclusions: Cirrhotic patients with SBP and Child-Pugh C class and alcoholic liver cirrhosis had a higher risk of developing Clostridioides difficile infection during norfloxacin secondary prophylaxis. In patients with alcoholic Child-Pugh C class liver cirrhosis, alternative prophylaxis should be evaluated as SBP secondary prophylaxis.