bluuebunny/crossref_metadata_2025 huggingface dataset:
Bleeding that BARCs may bite…
Authors: Belardi Jorge A. , Albertal Mariano
Published: December 2014

Key Points

The presence of major bleeding according to a standardized bleeding classification [Bleeding Academic Research Consortium (BARC)] is associated with increased risk of major adverse cardiac events and death.

BARC predictive power is similar to the bleeding Thrombolysis in Myocardial Infarction criteria.

The use of BARC in clinical trials and international registries will enable comparison of bleeding rates between studies.
ChemInform Abstract: ScFe5P3, ScRu6P4, U2Mo30P19, and Other Ternary Phosphides with a Metal to Phosphorus Ratio Close to 2:1.
Authors: Jeitschko Wolfgang , Albering Joerg H. , Brink Reinhold , Jakubowski‐Ripke Ursula , Reinbold Elke J.
Published: December 2014

The new ternary phosphides ScFe5P3 (I), Sc(Ta0.18Fe0.82)Fe4P3 (II), ZrFe5P3 (III), ScRu6P4 (IV), ErRu6P4 (V), ZrCr6P4 (VI), Nd2Ru12P7 (VII), and U2Mo30P19 (VIII) are prepared from mixtures of the elements in most cases with elemental Sn as a flux (alumina crucibles, 650—950 °C, 7—10 d).
ChemInform Abstract: Synthesis and Crystal Structure of δ‐TaON, a Metastable Polymorph of Tantalum Oxide Nitride.
Authors: Luedtke Tobias , Schmidt Alexander , Goebel Caren , Fischer Anna , Becker Nils , Reimann Christoph , Bredow Thomas , Dronskowski Richard , Lerch Martin
Published: December 2014

δ‐TaON is prepared by ammonolysis of amorphous Ta2O5 precursor derived via a modified Pechini route (NH3 stream, 760 °C, 1 h; 43% yield).
ChemInform Abstract: Thermoelectrical Properties of Lutetium‐Doped Bi2Te3 Bulk Samples Prepared from Flower‐Like Nanopowders.
Authors: Yang Jingjing , Wu Fang , Zhu Zheng , Yao Lan , Song Hongzhang , Hu Xing
Published: December 2014

LuxBi2‐xTe3 (x = 0, 0.1, 0.23, 0.4) nanoflowers are prepared by hydrothermal treatment of LuCl3, BiCl3, and Te with NaBH4 as reductant and EDTA as complexing agent (autoclave, 433 K, 24 h).
ChemInform Abstract: Synthesis and Characterization of F‐Doped Nanocrystalline Li4Ti5O12/C Compounds for Lithium‐Ion Batteries.
Authors: Han Xiaona , Zhao Zhen , Xu Yunlong , Liu Dong , Zhang Huang , Zhao Chongjun
Published: December 2014

F‐doped and carbon coated Li4Ti5O11.7F0.3/C composite anode materials are synthesized by solid state reactions of ball milled mixtures of Li2CO3, TiO2, lithium citrate, and LiF (800 °C, 12 h).
ChemInform Abstract: Prussian Blues a a Cathode Material for Lithium Ion Batteries.
Authors: Shen Lian , Wang Zhaoxiang , Chen Liquan
Published: December 2014

The electrochemical performances of Fe4[Fe(CN)6]3 and FeFe(CN)6 (obtained by coprecipitation methods) as cathode materials for lithium ion batteries are evaluated.
ChemInform Abstract: Fe4[Fe(CN)6]3: A Cathode Material for Sodium‐Ion Batteries.
Authors: Sun He , Sun Haobo , Wang Wei , Jiao Handong , Jiao Shuqiang
Published: December 2014

The title compound is synthesized by precipitation from aqueous solutions of FeCl3 and Na4Fe(CN)6 at room temperature and characterized by XRD, SEM, TEM, electrochemical measurements, and first‐principles plane‐wave pseudopotential calculations.
ChemInform Abstract: Excellent Electrochemical Performance of Tin Monosulfide (SnS) as a Sodium‐Ion Battery Anode.
Authors: Dutta Prasit Kumar , Sen Uttam Kumar , Mitra Sagar
Published: December 2014

SnS nanorods are synthesized from mixtures of SnCl2 dissolved in acetone and aqueous triethanolamine, thioacetamide, and ammonia solutions (room temperature, 16 h) followed by annealing the obtained precipitate at 500 °C for 5 h under N2 atmosphere.
ChemInform Abstract: Synthesis of Highly Active and Stable Spinel‐Type Oxygen Evolution Electrocatalysts by a Rapid Inorganic Self‐Templating Method.
Authors: Ma Tian Yi , Dai Sheng , Jaroniec Mietek , Qiao Shi Zhang
Published: December 2014

The spinel‐phase metal oxides MnxCo3‐xO4‐δ (x = 0.8, 1.0, 1.2, 1.4) are synthesized by a rapid self‐templating mechanism from EtOH solutions containing CoCl2, MnCl2, KOH, and water (room temperature, sonication).
ChemInform Abstract: Ga2SbCl7O — A Molecular Gallium Antimony Chloride Oxide Synthesized from a GaCl3 Melt.
Authors: Eich Andreas , Schnakenburg Gregor , Beck Johannes
Published: December 2014

Colorless, highly hygroscopic crystals of the title compound are synthesized from a mixture of Sb, SbCl3, Sb2O3, GaCl3, and Te (glass ampule, Ar, 6 x 10‐2 mbar, 50 °C, 19 d).
ChemInform Abstract: Syntheses, Crystal Structures, Transport Properties, and Theoretical Studies of Five Members of the MAn2Q5 Family: SrU2S5, BaU2Se5, PbU2S5, BaTh2S5, and BaU2Te5.
Authors: Prakash Jai , Tarasenko Mariya S. , Mesbah Adel , Lebegue Sebastien , Malliakas Christos D. , Ibers James A.
Published: December 2014

SrU2S5 (I), BaU2Se5 (II), PbU2S5 (III), BaTh2S5 (IV), and BaU2Te5 (V) are prepared by high‐temperature solid‐state reactions of SrS2, Ba, Th, S, Se, Te, Sb2S3 (flux), Pb, CsCl (flux), and depleted U (evacuated silica tubes, complex heating schedules).
ChemInform Abstract: Synthesis and Crystal Structure of the Iron(III) Oxotellurate(IV) Phosphate Oxide Chloride Fe11(TeO3)2(TeO4)3 (PO4)2O4Cl3.
Authors: Zimmermann Iwan , Johnsson Mats
Published: December 2014

Orange single crystals of the title compound are obtained from an equimolar mixture of TeO2, FeCl3, FeCl2, Fe2O3, and (NH4)H2PO4 (evacuated silica tube, 550 °C, 70 h).
ChemInform Abstract: Divalent Copper Selenate Complex: Two Types of Octahedral Coordination in the Unit Cell and Disordered 1,4‐Diazabicyclo[2.2.2]octane.
Authors: Rekik Walid , Loulou Nkhili Nouha , Naili Houcine , Dahaoui Slimane
Published: December 2014

Single crystals of the new compound (H2dabco)[Cu(H2O)6] [Cu(SeO4)2(H2O)4]2 are prepared in good yield (not given) from aqueous solutions of CuCO3·2Cu(OH)2, DABCO, and H2SeO4 in the molar ratio of 1:1:2 at room temperature.
ChemInform Abstract: Time‐Resolved Assembly of Cluster‐in‐Cluster {Ag12}‐in‐{W76} Polyoxometalates under Supramolecular Control.
Authors: Zhan Caihong , Cameron Jamie M. , Gao Jing , Purcell Jamie W. , Long De‐Liang , Cronin Leroy
Published: December 2014

Compounds (IV), (V), and (VI) are separated sequentially from the same mother liquor as a function of solvent evaporation time (slow evaporation at room temperature).
ChemInform Abstract: X‐Ray Characterization, Electronic Band Structure, and Thermoelectric Properties of the Cluster Compound Ag2Tl2Mo9Se11.
Authors: Gougeon Patrick , et al. et al.
Published: December 2014

Single crystals of Ag2.25Tl1.75Mo9Se11 are prepared by reaction of an excess of Ag powder with Tl2Mo9Se11 single crystals in sealed silica tubes at 800 °C during two weeks.
ChemInform Abstract: New Data on Heteroarene Thiocyanation by Anodic Oxidation of NH4SCN. The Processes of Electroinduced Nucleophilic Aromatic Substitution of Hydrogen.
Authors: Kokorekin Vladimir A. , Sigacheva Vera L. , Petrosyan Vladimir A.
Published: December 2014

Potentiostatic electrolysis of NH4SCN in an undivided cell is used to perform the anodic thiocyanation of various aromatic substrates under mild conditions.
ChemInform Abstract: Efficient Generation and Increased Reactivity in Cationic Gold via Broensted Acid or Lewis Acid Assisted Activation of an Imidogold Precatalyst.
Authors: Han Junbin , Shimizu Naoto , Lu Zhichao , Amii Hideki , Hammond Gerald B. , Xu Bo
Published: December 2014

Imido gold precatalysts activated by Broensted or Lewis acids are excellent catalysts applicable for most common gold‐catalyzed reactions.
ChemInform Abstract: Fc‐PIP Catalyzed Asymmetric Synthesis of cis‐2,3‐Dihydrobenzofurans.
Authors: Jiang Shanshan , Hu Bin , Yu Xingxin , Deng Weiping
Published: December 2014

The amidine‐ferrocene hybrid catalyst FPIP, attributed with central and planar chirality, is highly effective and selective in the intramolecular Michael addition‐lactonization tandem reaction of a variety of enone acids to afford the title compounds with good diastereo‐ and excellent enantioselectivities.
ChemInform Abstract: Air‐ and Water‐Tolerant Rare Earth Guanidinium BINOLate Complexes as Practical Precatalysts in Multifunctional Asymmetric Catalysis.
Authors: Robinson Jerome R. , Fan Xinyuan , Yadav Jagjit , Carroll Patrick J. , Wooten Alfred J. , Pericas Miquel A. , Schelter Eric J. , Walsh Patrick J.
Published: December 2014

The usability of the title complexes is shown in several asymmetric and mechanistically diverse reactions including Michael additions, aza‐Michael additions, and direct Aldol reactions.
ChemInform Abstract: Palladium(II)‐Catalyzed Enantioselective C(sp3)—H Activation Using a Chiral Hydroxamic Acid Ligand.
Authors: Xiao Kai‐Jiong , Lin David W. , Miura Motofumi , Zhu Ru‐Yi , Gong Wei , Wasa Masayuki , Yu Jin‐Quan
Published: December 2014

The absolute configurations of compounds (III) and (V) are tentatively assigned in analogy to that of (Vc) which is determined by X‐ray crystallographic analysis.
ChemInform Abstract: Enantiospecific sp2—sp3 Coupling of Secondary and Tertiary Boronic Esters.
Authors: Bonet Amadeu , Odachowski Marcin , Leonori Daniele , Essafi Stephanie , Aggarwal Varinder K.
Published: December 2014

For the first time, a general method for coupling electron‐rich aromatic and heteroaromatic compounds with enantioenriched secondary and tertiary boronic esters is described.
ChemInform Abstract: Enantioselective Hydrogenation of α,β‐Disubstituted Nitroalkenes.
Authors: Li Shengkun , Huang Kexuan , Zhang Xumu
Published: December 2014

The first rhodium‐catalyzed, highly chemo‐ and enantioselective hydrogenation of a variety of α,β‐disubstituted nitroalkenes (I) and (III) is reported.
ChemInform Abstract: Rhodium(II)‐Catalyzed Intramolecular Cycloisomerizations of Methylenecyclopropanes with N‐Sulfonyl 1,2,3‐Triazoles.
Authors: Chen Kai , Zhu Zi‐Zhong , Zhang Yong‐Sheng , Tang Xiang‐Ying , Shi Min
Published: December 2014

Several intramolecular tandem reactions of methylenecyclopropanes with rhodium(II) azavinyl carbenes are realized.
ChemInform Abstract: β‐(Carbonatoxy)alkyl Radicals: A New Subset of β‐(Ester)alkyl Radical Fragmentation During Copper(I)‐Mediated Synthesis of 1,1‐Dichloro‐1‐alkenes.
Authors: Ram Ram N. , Tittal Ram K.
Published: December 2014

Treatment of substrates (I) with CuCl/bipy produces alkenes (II).
ChemInform Abstract: Synthesis of Novel Chiral Diamino Alcohols and Their Application in Copper‐Catalyzed Asymmetric Allylic Oxidation of Cycloolefins.
Authors: Faraji Laleh , Samadi Saadi , Jadidi Khosrow , Notash Behrouz
Published: December 2014

A small library of new enantiomerically pure (S,S)‐diamino alcohols are synthesized and applied as chiral ligands in the copper‐catalyzed asymmetric allylic oxidation reaction of cycloolefins.
ChemInform Abstract: Mild Propargylic Oxidation Using a Diacetoxyiodobenzene/tert‐Butyl Hydroperoxide Protocol.
Authors: Zhao Yi , Ng Angela Wan Ting , Yeung Ying‐Yeung
Published: December 2014

A mild method is presented for the oxidation of alkynes to α,β‐alkynoic ketones.
ChemInform Abstract: Partial Reduction of Esters to Aldehydes Using a Novel Modified Red‐Al Reducing Agent.
Authors: Shin Won Kyu , Kang Daehoon , An Duk Keun
Published: December 2014

Various aldehydes are synthesized from both aromatic and aliphatic esters in absence of any additives using a modified Red‐Al.
ChemInform Abstract: Phosphine‐ and Hydrogen‐Free: Highly Regioselective Ruthenium‐Catalyzed Hydroaminomethylation of Olefins.
Authors: Guelak Samet , Wu Lipeng , Liu Qiang , Franke Robert , Jackstell Ralf , Beller Matthias
Published: December 2014

A new, highly regioselective (n:iso up to <99:1) hydrogen‐ and ligand‐free hydroaminomethylation of terminal alkenes is reported.
ChemInform Abstract: Studies on Copper(I)‐Catalyzed Highly Regio‐ and Stereo‐Selective Hydroboration of Alkynamides.
Authors: He Guangke , Chen Shan , Wang Qiang , Huang Hai , Zhang Qijun , Zhang Dongming , Zhang Rong , Zhu Hongjun
Published: December 2014

Interestingly, the regioselectivity of the present hydroboration is found to be opposite to that observed in the carbometallation reaction of alkynamides.
ChemInform Abstract: Urea‐Induced Acid Amplification: A New Approach for Metal‐Free Insertion Chemistry.
Authors: Couch Erica D. , Auvil Tyler J. , Mattson Anita E.
Published: December 2014

A difluoroboronate substituted urea is shown to be an efficient catalyst for O—H and S—H insertion reactions of α‐aryldiazoacetates to produce a wide variety of α‐acyloxyesters and α‐mercaptoesters, respectively.
ChemInform Abstract: Copper‐Catalyzed Decarboxylative Trifluoromethylation of Propargyl Bromodifluoroacetates.
Authors: Ambler Brett R. , Peddi Santosh , Altman Ryan A.
Published: December 2014

The reaction can be scaled up.
ChemInform Abstract: A Very Mild and Selective Method for O‐Benzoylation of Hydroxamic Acids.
Authors: Zheng Yongsheng , Liu Muqiong , Yuan Yu
Published: December 2014

The DABCO mediated reaction of hydroxamic acids with benzoyl peroxide provides the corresponding O‐benzoylated products.
ChemInform Abstract: Sequential Hydroformylation/Diels—Alder Processes: One‐Pot Synthesis of Polysubstituted Cyclohexenes, Cyclohexadienes, and Phthalates from Alkynes.
Authors: Fang Xianjie , Jackstell Ralf , Beller Matthias
Published: December 2014

Various alkynes are efficiently converted into the corresponding products in good yields and with excellent diastereoselectivity through palladium‐catalyzed hydroformylation followed by an Diels—Alder reaction of amides, aldehydes, and dienophiles.
ChemInform Abstract: Synthesis, Antibacterial and Antioxidant Properties of Novel Ethylenoindolophanes — A New Class of Cyclophanes.
Authors: Rajakumar Perumal , Venkatesan Nagarathinam , Mohanraj Gunasekaran
Published: December 2014

All the indole based ethylenophanes, synthesized via a McMurry coupling key step, show antibacterial and antioxidant activity similar to that of commercially available drugs.
ChemInform Abstract: Ionic Liquid Promoted Synthesis of β‐Enamino Ketones and Esters under Microwave Irradiation.
Authors: Singh Ashima , Gupta Neeru , Sharma M. L. , Singh Jasvinder
Published: December 2014

The catalyst can be recycled and reused twice without significant loss of activity.
ChemInform Abstract: Organocatalytic Synthesis of Optically Active β‐Branched α‐Amino Esters via Asymmetric Biomimetic Transamination.
Authors: Su Cunxiang , Xie Ying , Pan Hongjie , Liu Mao , Tian Hua , Shi Yian
Published: December 2014

An asymmetric biomimetic transamination process for β‐branched α‐keto esters (I) with a hydroquinine‐derived chiral base and 4‐cyano‐benzylamine as the nitrogen source is reported.
ChemInform Abstract: Enzyme‐Catalyzed Cascade Synthesis of Hydroxyiminoacetamides.
Authors: Knezevic Anamarija , Vinkovic Vladimir , Marakovic Nikola , Sinko Goran
Published: December 2014

A synthesis of hydroxyiminoacetamide (IV), a key compound for the preparation of acetylcholinesterase reactivators, is developed.
ChemInform Abstract: Asymmetric Cascade Reaction to Allylic Sulfonamides from Allylic Alcohols by Palladium(II)/Base‐Catalyzed Rearrangement of Allylic Carbamates.
Authors: Bauer Johannes Moritz , Frey Wolfgang , Peters Rene
Published: December 2014

A catalytic asymmetric method for the transformation of allylic alcohols into sulfonyl‐protected chiral allylic amines is presented.
ChemInform Abstract: Toluene as a Novel Carrier of Xanthates—Preparation, Use and Surrogate of S‐Tri‐ and Di‐Chloromethyl Xanthates.
Authors: Dumeunier Raphael , Huber Annika
Published: December 2014

The re‐aromatizing loss of toluene by radical initiated fragmentation of substrates (II) and (IV) renders possible the transformation of dithiocarbonyl group and a tri‐ or dichloromethyl group to olefins.
ChemInform Abstract: Ruthenium Catalyzed Regioselective Coupling of Terminal Alkynes, Amine and Carbon Dioxide Leading to anti‐Markovnikov Adducts.
Authors: Watile Rahul A. , Bhanage Bhalchandra M.
Published: December 2014

The reaction proceeds with excellent regioselectivity providing predominantly Z‐isomers of anti‐Markovnikov adducts.
ChemInform Abstract: Highly Diastereodivergent Synthesis of Tetrasubstituted Cyclohexanes Catalyzed by Modularly Designed Organocatalysts.
Authors: Rana Nirmal K. , Huang Huicai , Zhao John C.‐G.
Published: December 2014

Depending on the temperature the reaction of nitroolefins with keto aldehydes of type (II) can be used to synthesize either 1,2‐syn or 1,2‐anti nitrocyclohexane products (III) and (IV).
ChemInform Abstract: Gold‐Catalyzed Diastereoselective Cycloisomerization of Alkylidene‐Cyclopropane‐Bearing 1,6‐Diynes.
Authors: Zheng Hongchao , Adduci Laura L. , Felix Ryan J. , Gagne Michel R.
Published: December 2014

Treatment of 1,6‐diynes (syntheses described) according to A) proceeds diastereoselectively to produce the important 1,2‐trimethylenenorbornane core bearing an exocyclic alkene function.
ChemInform Abstract: Direct Synthesis of Pentafluoroethyl Copper from Pentafluoropropionate as an Economical C2F5 Source: Application to Pentafluoroethylation of Arylboronic Acids and Aryl Bromides.
Authors: Serizawa Hiroki , Aikawa Kohsuke , Mikami Koichi
Published: December 2014

The synthesis of pentafluoroethyl copper from a cuprate reagent and ethyl pentafluoropropionate is reported.
ChemInform Abstract: Copper‐Catalyzed Nucleophilic Trifluoromethylation of Benzylic Chlorides.
Authors: Miyake Yoshihiro , Ota Shin‐ichi , Shibata Masashi , Nakajima Kazunari , Nishibayashi Yoshiaki
Published: December 2014

Benzylic chlorides bearing less electron‐donating groups, like tolyl and phenyl residues, fail to give the title reaction.
ChemInform Abstract: [3 + 3] Annulation of Allylic Phosphoryl‐Stabilized Carbanions/Phosphorus Ylides and Vinyl Azides: A Practice Strategy for Synthesis of Polyfunctionalized Anilines.
Authors: Liu Shen , Chen Wenteng , Luo Jing , Yu Yongping
Published: December 2014

Michael addition of vinyl azides (II) and (V) with allylic phosphorous ylides or allylic‐stabilized‐stabilized carbanions followed by Wittig or Horner—Wadsworth—Emmons initiated [3 + 3] annulation afford highly functionalized anilines (III) and (VI) in good to excellent yields.
ChemInform Abstract: Synthesis of Tertiary Propargylamines via a Rationally Designed Multicomponent Reaction of Primary Amines, Formaldehyde, Arylboronic Acids and Alkynes.
Authors: Wang Jiayi , Shen Qiaoying , Li Pinzhen , Peng Yanqing , Song Gonghua
Published: December 2014

The title reaction represents a combination of the Petasis borono‐Mannich reaction of aldehydes, amines as well as boronic acids to afford secondary amines, which in turn are used in the so called A3‐coupling with aldehydes and alkynes.
ChemInform Abstract: Stereocontrol in Synthesis of Homoallylic Amines. Syn Selective Direct Allylation of Hydrazones with Allylboronic Acids.
Authors: Das Arindam , Alam Rauful , Eriksson Lars , Szabo Kalman J.
Published: December 2014

Unless otherwise mentioned the products are isolated as single diastereomers.
ChemInform Abstract: General Silver‐Catalyzed Hydroazidation of Terminal Alkynes by Combining TMS‐N3 and H2O: Synthesis of Vinyl Azides.
Authors: Liu Zhenhua , Liao Peiqiu , Bi Xihe
Published: December 2014

An anti‐markovnikov hydroazidation of terminal alkynes is described.
ChemInform Abstract: Acceleration of the Dakin Reaction by Trifluoroacetic Acid.
Authors: Natu Arun D. , Burde Ameya S. , Limaye Rohan A. , Paradkar Madhusudan V.
Published: December 2014

Trifluoroacetic acid is shown to accelerate the Dakin reaction and the use of SeO2 is essential for the reaction either as carbonyl activator or as a participator in the reaction by intermediately forming peroxyselenic acid.
ChemInform Abstract: Betti Base as an Efficient Ligand for Copper‐Catalyzed Ullmann Coupling of Phenol with Aryl Halides.
Authors: Yang Li , Yang Qichao , Shi Jianxin , Wang Yufang , Zhang Mingjie
Published: December 2014

A new catalyst is presented for the synthesis of diaryl ethers from aromatic phenols and aryl halides.
ChemInform Abstract: Palladium‐Catalyzed Formylation of Aryl Halides with tert‐Butyl Isocyanide.
Authors: Jiang Xiao , Wang Jin‐Mei , Zhang Ying , Chen Zhong , Zhu Yong‐Ming , Ji Shun‐Jun
Published: December 2014

The title reaction provides a strategy for the synthesis of important aldehydes with moderate to excellent yields.
ChemInform Abstract: Nickel‐Catalyzed α‐Arylation of Ketones with Phenol Derivatives.
Authors: Takise Ryosuke , Muto Kei , Yamaguchi Junichiro , Itami Kenichiro
Published: December 2014

The nickel‐catalyzed α‐arylation of ketones with readily available phenol derivatives (esters and carbamates) provides access to useful α‐arylketones.
ChemInform Abstract: Metal‐Free Synthesis of 1,3,5‐Trisubstituted Benzenes by the Cyclotrimerization of Enaminones or Alkynes in Water.
Authors: Wan Jie‐Ping , Lin Yunfang , Hu Kaikai , Liu Yunyun
Published: December 2014

Cyclotrimerization reactions of both enaminones and electron deficient terminal alkynes are efficiently performed in water in the presence of lactic acid.
ChemInform Abstract: Metal‐Free, Efficient Oxyfluorination of Olefins for the Synthesis of α‐Fluoroketones.
Authors: Yang Qiang , Mao Liu‐Liang , Yang Bin , Yang Shang‐Dong
Published: December 2014

Inexpensive and easily available unsaturated olefins as starting compounds, wide functional group tolerance, and atom economic conditions are key features of this reaction.
ChemInform Abstract: PEG1000‐Based Dicationic Acidic Ionic Liquid as an Efficient Catalyst for Mannich‐Type Reaction in Water.
Authors: Ren Yi‐Ming , Shao Juan‐Juan , Wu Zhi‐Chuan , Yang Ren‐Chun , Zhang Ze , Tao Ting‐Xian
Published: December 2014

The reaction is performed in water, and the catalyst can be reused in six runs with only a slight loss of activity.
ChemInform Abstract: Palladium‐Catalyzed Formal Arylacylation of Allenes Employing Acid Chlorides and Arylboronic Acids.
Authors: Tatsumi Kenta , Fujihara Tetsuaki , Terao Jun , Tsuji Yasushi
Published: December 2014

The title reaction affords the corresponding α,β‐unsaturated ketones (IV), (VI), and (VIII) regio‐ and stereoselectively.
ChemInform Abstract: Synthesis and Characterization of Bisoxazolines‐ and Pybox‐Copper(II) Complexes and Their Application in the Coupling of α‐Carbonyls with Functionalized Amines.
Authors: Jia Wei‐Guo , Li Dan‐Dan , Dai Yuan‐Chen , Zhang Hui , Yan Li‐Qin , Sheng En‐Hong , Wei Yun , Mu Xiao‐Long , Huang Kuo‐Wei
Published: December 2014

The copper‐catalyzed amination of ketones (I) and esters (IV) is reported [30 examples].
ChemInform Abstract: Palladium‐Catalyzed Oxidative Carbonylative Coupling of Arylboronic Acids with Terminal Alkynes to Alkynones.
Authors: Natte Kishore , Chen Jianbin , Neumann Helfried , Beller Matthias , Wu Xiao‐Feng
Published: December 2014

The first examples of an oxidative carbonylative coupling of arylboronic acids with alkynes, a missing link in carbonylative coupling reactions, are given
ChemInform Abstract: Tertiary Amide‐Based Knoevenagel‐Type Reactions: A Direct, General, and Chemoselective Approach to Enaminones.
Authors: Huang Pei‐Qiang , Ou Wei , Xiao Kai‐Jiong , Wang Ai‐E
Published: December 2014

Basis of the presented approach is the in situ activation of amide carbonyl with triflic anhydride and a subsequent reaction with carbanions generated in situ from carbonyl compounds.
ChemInform Abstract: Rhodium‐Catalyzed Asymmetric Arylation of β,γ‐Unsaturated α‐Ketoamides for the Construction of Nonracemic γ,γ‐Diarylcarbonyl Compounds.
Authors: Wang Juanjuan , Wang Min , Cao Peng , Jiang Liyin , Chen Guihua , Liao Jian
Published: December 2014

A simple, new, chiral sulfinylphosphine ligand is developed, which promotes excellent 1,4‐selectivities and enantioselectivities in the rhodium‐catalyzed conjugate addition of arylboronic acids to β,γ‐unsaturated α‐ketoamides.
ChemInform Abstract: Rhodium(III)‐Catalyzed Cross‐Coupling of Alkenylboronic Acids and N‐Pivaloyloxylamides.
Authors: Feng Chao , Loh Teck‐Peng
Published: December 2014

A novel and effective method for enamide synthesis using Rh(III)‐catalyzed umpolung amidation between N‐pivaloyloxyl amides and alkenylboronic acids is presented.
ChemInform Abstract: Green Synthesis of Benzamides in Solvent‐ and Activation‐Free Conditions.
Authors: Alalla Affef , Merabet‐Khelassi Mounia , Aribi‐Zouioueche Louisa , Riant Olivier
Published: December 2014

An improved method for the synthesis of acetamides with isopropenyl acetate is also shown.
ChemInform Abstract: Efficient Palladium‐Catalyzed Double Carbonylation of o‐Dibromobenzenes: Synthesis of Thalidomide.
Authors: Chen Jianbin , Natte Kishore , Spannenberg Anke , Neumann Helfried , Beller Matthias , Wu Xiao‐Feng
Published: December 2014

A convenient procedure for the double carbonylation of o‐dibromobenzenes (I) in the presence of various 2‐aminopyridines and naturally occurring amines, e.g. (IIf), providing N‐substituted phthalimides such as (IV) is reported.
ChemInform Abstract: Synthesis of N‐Styrenyl Amidines from α,β‐Unsaturated Nitrones and Isocyanates Through CO2 Elimination and Styrenyl Migration.
Authors: Mo Dong‐Liang , Pecak Wiktoria H. , Zhao Meng , Wink Donald J. , Anderson Laura L.
Published: December 2014

A new method for the synthesis of N‐styrenyl amidines is described.
ChemInform Abstract: Copper Iodide Nanoparticles‐Catalyzed Cyanation of Aryl Halides Using Non‐toxic K4[Fe(CN)6] in the Presence of 1,2‐Bis(5‐tetrazolyl)benzene as an Efficient Ligand.
Authors: Maham Mehdi , Bahari Siavash
Published: December 2014

The significant advantages of this protocol are high yields, elimination of dangerous and toxic reagents and a simple work‐up procedure.
ChemInform Abstract: Palladium‐Catalyzed/Norbornene‐Mediated ortho‐Amination/N‐Tosylhydrazone Insertion Reaction: An Approach to the Synthesis of ortho‐Aminated Vinylarenes.
Authors: Zhou Ping‐Xin , Ye Yu‐Ying , Ma Jun‐Wei , Zheng Lan , Tang Qian , Qiu Yi‐Feng , Song Bo , Qiu Zi‐Hang , Xu Peng‐Fei , Liang Yong‐Min
Published: December 2014

Aryl iodides, N‐benzoyloxyamines and N‐tosylhydrazones are used for the preparation of various title compounds.
ChemInform Abstract: Palladium Catalyzed Intramolecular Acylcyanation of Alkenes Using α‐Iminonitriles.
Authors: Rondla Naveen R. , Ogilvie Jodi M. , Pan Zhongda , Douglas Christopher J.
Published: December 2014

The title reaction affords functionalized indanones (II) in moderate to high yields and tolerates substitution at various positions on the aromatic ring including electron donating and electron withdrawing groups.
ChemInform Abstract: Synthesis of 1,4‐Enamino Ketones by [3,3]‐Rearrangements of Dialkenylhydroxylamines.
Authors: Pecak Wiktoria H. , Son Jongwoo , Burnstine Amy J. , Anderson Laura L.
Published: December 2014

A new method for the synthesis of 1,4‐enamino ketones through rearrangement of dialkenylhydroxylamines generated in situ by addition of N‐alkenylnitrones to allenes is described.
ChemInform Abstract: Rhodium(I)‐Catalyzed Cycloisomerization of Benzylallene‐Alkynes Through C—H Activation.
Authors: Kawaguchi Yasuaki , Yasuda Shigeo , Kaneko Akira , Oura Yuki , Mukai Chisato
Published: December 2014

A novel Rh‐catalyzed cycloisomerization of a variety of benzylallene‐alkyne substrates giving tricyclic products in moderate to good yields is presented.
ChemInform Abstract: Asymmetric Synthesis of γ‐Lactones Through Reaction of Sulfoxonium Ylides, Aldehydes, and Ketenes.
Authors: Peraino Nicholas J. , Ho Han‐Jen , Mondal Mukulesh , Kerrigan Nessan J.
Published: December 2014

The synthesis of enantioenriched γ‐lactones (IV) starting from chiral tetrafluoroborate (I) is studied.
ChemInform Abstract: Palladium‐Catalyzed Oxidative Difunctionalization of Alkenes with α‐Carbonyl Alkyl Bromides Initiated Through a Heck‐Type Insertion: A Route to Indolin‐2‐ones.
Authors: Fan Jian‐Hong , Wei Wen‐Ting , Zhou Ming‐Bo , Song Ren‐Jie , Li Jin‐Heng
Published: December 2014

A new palladium‐catalyzed oxidative difunctionalization reaction of N‐arylalkenes with primary, secondary, and tertiary α‐carbonyl alkyl bromides affording indolinones is presented.
ChemInform Abstract: NIS‐Mediated Regioselective Amidation of Indole with Quinazolinone and Pyrimidone.
Authors: Ghosh Suman Kr , Nagarajan Rajagopal
Published: December 2014

A direct regioselective C2 amidation of pyrroles and indoles with pyrimidone and quinazolinone derivatives is developed.
ChemInform Abstract: Chiral Phosphoramide‐Catalyzed Enantioselective Synthesis of 2,3′‐Diindolylarylmethanes from Indol‐2‐yl Carbinols and Indoles.
Authors: Qi Shuai , Liu Chao‐You , Ding Jin‐Ying , Han Fu‐She
Published: December 2014

The first asymmetric addition of indol carbinols (I) with indol derivatives (II) and (IV) catalyzed by a BINOL‐derived phosphoramide affords title compounds (III) and (V) in high yields as well as high enantioselectivities.
ChemInform Abstract: Flexible and Practical Synthesis of 3‐Oxyindoles Through Gold‐Catalyzed Intermolecular Oxidation of O‐Ethynylanilines.
Authors: Shu Chao , Li Long , Xiao Xin‐Yu , Yu Yong‐Fei , Ping Yi‐Fan , Zhou Jin‐Mei , Ye Long‐Wu
Published: December 2014

The reaction does not need to exclude moisture or air (“open flask”).
ChemInform Abstract: Phosphine‐Catalyzed Asymmetric [4 + 1] Annulation of Activated α,β‐Unsaturated Ketones with Morita—Baylis—Hillman Carbonates: Enantioselective Synthesis of Spirooxindoles Containing Two Adjacent Quaternary Stereocenters.
Authors: Hu Fang‐Le , Wei Yin , Shi Min
Published: December 2014

The title reaction is promoted by a bifunctional thiourea‐phosphine catalyst derived from an axially chiral binaphthyl scaffold affording spirooxindoles (III) with high enantioselectivities but only moderate diastereoselectivities.
ChemInform Abstract: Palladium Nanomaterials in Catalytic Intramolecular C—H Amination Reactions.
Authors: Chng Leng Leng , Yang Jun , Wei Yifeng , Ying Jackie Y.
Published: December 2014

Palladium nanoparticles on carbon support are prepared and successfully used as catalyst for the conversion of 2‐acetaminobiphenyls (I) to carbazoles (II) (16 examples).
ChemInform Abstract: Thionium‐Based One‐Pot Construction of Homo‐/Heterodimeric Pyrroloindoline from Tryptamine.
Authors: Tayu Masanori , Higuchi Kazuhiro , Ishizaki Takako , Kawasaki Tomomi
Published: December 2014

A one‐pot dimerization of two tryptamine derivatives is developed to yield homo‐ as well as heterodimeric mixtures of racemic (IV) and meso (V) products.
ChemInform Abstract: Ketone Synthesized Cobaloxime/Organocobaloxime Catalysts for Cyclic Carbonate Synthesis from CO2 and Epoxides: Characterization and Electrochemistry.
Authors: Kilic Ahmet , Kilic Mehmet Veysi , Ulusoy Mahmut , Durgun Mustafa , Aytar Emine , Dagdevren Metin , Yilmaz Ismail
Published: December 2014

A new dioxime ligand is prepared and used for the synthesis of a series of mono‐ and trinuclear cobaloxime/organocobaloxime complexes (10 examples; detailed physical and physico‐chemical data).
ChemInform Abstract: Bi(OTf)3‐Catalyzed Intramolecular Amination of Triazenylaryl Allylic Alcohols: A Stereoselective, High‐Yield Synthesis of (E)‐3‐Alkenyl 2H‐Indazoles.
Authors: Yang Weijun , Yang Zhigen , Xu Lijun , Zhang Lili , Xu Xin , Miao Maozhong , Ren Hongjun
Published: December 2014

Among six catalysts tested for the intramolecular amination of (I) to yield (II), Bi(OTf)3 is the most effective.
ChemInform Abstract: Facile One‐Pot Synthesis of 1,3,5‐Trisubstituted Pyrazoles from α,β‐Enones.
Authors: Yu Jin , Kim Ko Hoon , Moon Hye Ran , Kim Jae Nyoung
Published: December 2014

The title compounds (III) are obtained by efficient one‐pot synthesis from α,β‐enones and arylhydrazine hydrochlorides.
ChemInform Abstract: Synthesis of 2,3‐Dihydro‐1H‐indazoles by Rh(III)‐Catalyzed C—H Cleavage of Arylhydrazines.
Authors: Yao Jinzhong , Feng Ruokun , Lin Cong , Liu Zhanxiang , Zhang Yuhong
Published: December 2014

A series of 2,3‐dihydro‐1H‐indazoles is prepared via a Rh‐catalyzed activation of arylhydrazines and olefin addition.
ChemInform Abstract: One‐Pot Multi‐Component Synthesis of Mono‐ and Bis‐indolylimidazole Derivatives Using Zn2+ @KSF and Their Antibacterial Activity.
Authors: Mahmoodi Nosrat O. , Nikokar Iraj , Farhadi Marzieh , Ghavidast Atefeh
Published: December 2014

Some of the title compounds (IV) and (VI) show promising antibacterial activities.
ChemInform Abstract: Palladium‐Catalyzed α‐Arylation of Sultams with Aryl and Heteroaryl Iodides.
Authors: Rene Olivier , Fauber Benjamin P. , Malhotra Sushant , Yajima Herbert
Published: December 2014

An operationally simple one‐step process for Pd(0)‐catalyzed α‐arylation of 1,3‐propane sultames using a zinc‐base is reported.
ChemInform Abstract: Direct Synthesis of 4‐Fluoroisoxazoles Through Gold‐Catalyzed Cascade Cyclization—Fluorination of 2‐Alkynone O‐Methyl Oximes.
Authors: Jeong Yunkyung , Kim Bom‐I , Lee Jae Kyun , Ryu Jae‐Sang
Published: December 2014

The optimized conditions are successfully applied to the preparation of various isoxazole structures which represent an important heterocyclic scaffold.
ChemInform Abstract: Palladium‐Catalyzed Microwave‐Assisted Direct Arylation of Imidazo[2,1‐b]thiazoles with Aryl Bromides: Synthesis and Mechanistic Study.
Authors: Zhu Yi‐Shuo , Shi Benyi , Fang Ran , Wang Xiaoxuan , Jing Huanwang
Published: December 2014

The direct regioselective C—H arylation of various imidazo[2,1‐b]thiazole derivatives such as (I), (IV), and (VI) with a range of aryl bromides (II) is described.
ChemInform Abstract: Synthesis and Insecticidal Evaluation of Novel Phthalic Diamides Containing 1,2,3‐Triazoles via Click Reaction.
Authors: Chen Yinbo , Xiao Youxin , Shao Xusheng , Xu Xiaoyong , Li Zhong
Published: December 2014

The bioassays show that most of the new compounds (III), (V) exhibit favorable activity against army worm (Mythimna separata).
ChemInform Abstract: Entry to Highly Hindered Chiral β‐Amino Triazoles Bearing a gem‐Diaryl Group by Azide‐Alkyne Click Chemistry.
Authors: Sadu Venkata Subbaiah , Roy Harendra Nath , Arigala Pitchaiah , Hwang In‐Taek , Lee Kee‐In
Published: December 2014

Highly hindered β‐amino 1,2,3‐triazole derivatives bearing a gem‐diaryl group are obtained by copper (I)‐catalyzed Huisgen cycloaddition of terminal alkynes with unmasked azidoamines derived from amino acids.
ChemInform Abstract: 1,2,3‐Triazoles from Carbonyl Azides and Alkynes: Filling the Gap.
Authors: Haldon Estela , Alvarez Eleuterio , Nicasio M. Carmen , Perez Pedro J.
Published: December 2014

The [3 + 2] cycloaddition of electron deficient N‐carbamoyl azides (II) and (IV) with alkynes (I) is realized for the first time using a copper‐based catalyst system.
ChemInform Abstract: 3‐Halotetrahydropyran‐4‐one Derivatives from Homopropargyl Acetal.
Authors: Aaseng Jon Erik , Iqbal Naseem , Tungen Joern Eivind , Sperger Christian A. , Fiksdahl Anne
Published: December 2014

A gold(I)‐catalyzed regioselective method for the preparation of 3‐halo‐tetrahydropyranone derivatives from homopropargyl acetal is reported.
ChemInform Abstract: O‐Benzenedisulfonimide as a Recyclable Homogeneous Organocatalyst for an Efficient and Facile Synthesis of 4‐Amidotetrahydropyran Derivatives Through Prins—Ritter Reaction.
Authors: Subba Reddy B. V. , Ghanty Supriya
Published: December 2014

A highly diastereoselective synthesis of the title compounds is achieved using a o‐benzenedisulfonimide as catalyst under mild conditions.
ChemInform Abstract: A Copper(II) Perchlorate‐Promoted Tandem Reaction of Internal Alkynol and Salicyl N‐Tosylhydrazone: Direct Access to Isochromeno[3,4‐b]chromene.
Authors: Siyang Hai Xiao , Wu Xu Rui , Ji Xiao Yue , Wu Xin Yan , Liu Pei Nian
Published: December 2014

The presented tandem reaction involves cycloisomerization, formal [4 + 2] cycloaddition and an elimination process.
ChemInform Abstract: FeCl3‐Catalyzed Tandem Prins and Friedel—Crafts Cyclization: A Highly Diastereoselective Route to Polycyclic Ring Structures.
Authors: Ghosh Arun K. , Keyes Chad , Veitschegger Anne M.
Published: December 2014

An efficient procedure is elaborated for the preparation of functionalized tetraline derivatives such as (III), (V), and (VII) from trans‐ or cis‐alkenols.
ChemInform Abstract: Three Component Solvent‐Free Synthesis of Chroman‐2,4‐dione‐based Heterocyclic Ketene Aminal (HKA) Derivatives by “GAP” Chemistry.
Authors: Yu Fu‐Chao , Hao Xiao‐Pan , Jiang Xiu‐Yang , Yan Sheng‐Jiao , Lin Jun
Published: December 2014

The title compounds (IV), (VI), (VIII), (X) are efficiently and regioselectively obtained by cascade reaction of ketene aminals with triethoxymethane (II), and 4‐hydroxy coumarin derivatives (III) without any catalyst and solvent.
ChemInform Abstract: Synthesis of Functionalized Chromones Through Sequential Reactions in Aqueous Media.
Authors: Mehrparvar Saber , Balalaie Saeed , Rabbanizadeh Mahnaz , Rominger Frank , Ghabraie Elmira
Published: December 2014

The sequential four‐component reaction of chromone aldehydes (I), meldrum′s acid (II), coumarin (IV) or pyrone (VI) in the presence of primary alcohols (III) leads to coupled products (V) and (VII), respectively.
ChemInform Abstract: Highly Regioselective Lithiation of Pyridines Bearing an Oxetane Unit by N‐Butyllithium.
Authors: Rouquet Guy , Blakemore David C. , Ley Steven V.
Published: December 2014

The regioselective ortho‐lithiation of pyridine derivatives containing a 3‐oxetane substituent is achieved for the first time.
ChemInform Abstract: Ligand‐Enabled Triple C—H Activation Reactions: One‐Pot Synthesis of Diverse 4‐Aryl‐2‐quinolinones from Propionamides.
Authors: Deng Youqian , Gong Wei , He Jian , Yu Jin‐Quan
Published: December 2014

4‐Aryl‐2‐quinolinones are prepared from propionamides in one pot by pyridine ligand‐promoted triple sequential C—H activation reactions and a stereospecific Heck reaction.
ChemInform Abstract: Direct Asymmetric Dearomatization of Pyridines and Pyrazines by Iridium‐Catalyzed Allylic Amination Reactions.
Authors: Yang Ze‐Peng , Wu Qing‐Feng , You Shu‐Li
Published: December 2014

The first iridium‐catalyzed intramolecular asymmetric allylic dearomatization reaction of pyridines and pyrazines is developed.
ChemInform Abstract: Copper‐Based Metal—Organic Frameworks as Reusable Heterogeneous Catalysts for the One‐Pot Syntheses of Imidazo[1,2‐a]pyridines.
Authors: Puthiaraj Pillaiyar , Ramu Andy , Pitchumani Kasi
Published: December 2014

The catalyst can be reused at least 5 times with only a slight decrease in yield.
ChemInform Abstract: Titanium Dioxide Supported on MWCNTs as an Eco‐Friendly Catalyst in the Synthesis of 3,4‐Dihydropyrimidin‐2‐(1H)‐ones Accelerated under Microwave Irradiation.
Authors: Safari Javad , Gandomi‐Ravandi Soheila
Published: December 2014

Some transition metal oxides supported on multi‐walled carbon nanotubes are prepared and applied as heterogenous catalysts in the Biginelli condensation of aldehydes, β‐dicarbonyl compounds, and (thio)urea.
ChemInform Abstract: Indium(III) Trifluoromethanesulfonate: A Reusable Catalyst for the Solvent‐Free Synthesis of Some Quinazolinones/Thiones.
Authors: Karami Bahador , Khodabakhshi Saeed , Karami Sajad
Published: December 2014

The introduced method leading to quinazolinones (IV) and (VI) and thiones (VIII) has advantages such as avoidance of organic solvents, high yields of pure products, short reaction times, and operational simplicity.
ChemInform Abstract: Synthesis of Quinazolines via CuO Nanoparticles Catalyzed Aerobic Oxidative Coupling of Aromatic Alcohols and Amidines.
Authors: Zhang Wu , Guo Fei , Wang Fei , Zhao Na , Liu Liang , Li Jia , Wang Zhenghua
Published: December 2014

CuO nanoparticles are found to be efficient catalysts for the reaction of N‐arylamidines (I) and (IV) and aromatic aldehydes (II) or benzyl alcohols (VI) to afford quinazolines (III) and (V), resp., in good to high yields.
ChemInform Abstract: One‐Pot Synthesis of 2‐Amino‐4(3H)‐quinazolinones via Ring‐Opening of Isatoic Anhydride and Palladium‐Catalyzed Oxidative Isocyanide‐Insertion.
Authors: Ji Fei , Lv Mei‐Fang , Yi Wen‐Bin , Cai Chun
Published: December 2014

The title reaction is applicable to a range of amines (II), isatoic anhydrides (I), and isocyanides (III) and affords the target heterocycles (IV) in moderate to high yields.
ChemInform Abstract: Synthesis of Antiprotozoal Diamines by Regioselective Insertion of Nitrogen into a Bicyclic Ring System.
Authors: Mohsin Noor‐ul‐Amin , Seebacher Werner , Faist Johanna , Belaj Ferdinand , Saf Robert , Kaiser Marcel , Brun Reto , Weis Robert
Published: December 2014

The new compounds (II) and (IV) show only weak antiprotozoal activity, whereas reduction products (III) and (V) exhibit distinct antiplasmodial and antitrypanosomal activities.
ChemInform Abstract: Copper‐Catalyzed Reductive Coupling of Aryl Sulfonyl Chlorides with H‐Phosphonates Leading to S‐Aryl Phosphorothioates.
Authors: Bai Jie , Cui Xiuling , Wang Hui , Wu Yangjie
Published: December 2014

A novel, simple, and efficient protocol for the synthesis of S‐aryl phosphorothioates (III) (20 examples) under base‐free conditions is developed.
ChemInform Abstract: An Efficient Synthesis of 1,3‐Dialkylimidazole‐2‐selenones.
Authors: Tian Fengshou , Chen Yahong , Wu Lan , Li Peng , Lu Shiwei
Published: December 2014

Optimum reaction conditions are studied for the synthesis of title compounds (II) from 1,3‐dialkylimidazole salts (I) and selenium.
ChemInform Abstract: Total Synthesis of Aphadilactones A—D.
Authors: Yin Jian‐Peng , Gu Min , Li Ying , Nan Fa‐Jun
Published: December 2014

A mixture of four diastereoisomers is synthesized in 11 steps and 7% overall yield.
ChemInform Abstract: Total Synthesis of Jiadifenolide.
Authors: Paterson Ian , Xuan Mengyang , Dalby Stephen M.
Published: December 2014

The stereocontrolled total synthesis of title compound (I), a potent neurotrophic agent, is described.
ChemInform Abstract: Perfluoroalkylsulfonyl Fluoride‐Mediated Abnormal Beckmann Rearrangement of Steroid 17‐Oximes with Acid‐Labile Groups.
Authors: Gui Jinghan , Wang Yun , Tian Hailong , Gao Yuqi , Tian Weisheng
Published: December 2014

8 examples
ChemInform Abstract: ZnBr2‐Catalyzed and Microwave‐Assisted Synthesis of 2,3‐Unsaturated Glucosides of Hindered Phenols and Alcohols.
Authors: Bound D. James , Bettadaiah B. K. , Srinivas P.
Published: December 2014

ZnBr2 is shown to be an efficient catalyst for the Ferrier reaction under microwave irradiation.
ChemInform Abstract: A Convenient Strategy for Synthesizing the Agelas Alkaloids Clathrodin, Oroidin, and Hymenidin and Their (Un)saturated Linker Analogues.
Authors: Zula Ales , Kikelj Danijel , Ilas Janez
Published: December 2014

Linker amines (I) are prepared as key intermediates for the synthesis of title alkaloids (II).
ChemInform Abstract: A New Enantioselective Synthesis of the anti‐Parkinson Agent Safinamide.
Authors: Reddi Anjaneyulu , Mujahid Mohammad , Sasikumar Murugesan , Muthukrishnan Murugan
Published: December 2014

The presented approach allows a convenient generation of a diverse range of analogues of safinamide.
ChemInform Abstract: Organic‐Functionalized, Substituted Polyoxovanadium and Vanadoniobates: Synthesis, Structure and Application
Authors: Gao Yuanzhe , Chi Yingnan , Hu Changwen
Published: December 2014

Review: 155 refs.
ChemInform Abstract: Oxidation Potentials in Iron and Steel Making
Authors: Matousek J. W.
Published: December 2014

Review: 20 refs.
ChemInform Abstract: The Zintl—Klemm Concept ‐ A Historical Survey
Authors: Nesper Reinhard
Published: December 2014

Review: 92 refs.
ChemInform Abstract: Impact of Crystal Chemistry upon Spin Orientation Transitions in Magnetic Perovskites
Authors: Raveau Bernard , Motin Seikh Md.
Published: December 2014

Review: 45 refs.
ChemInform Abstract: Pentacoordination for Pincer and Related Terdentate Coordination Compounds: Revisiting Structural Properties and Trends for D8 Transition Metal Systems
Authors: Roddick Dean M. , Zargarian Davit
Published: December 2014

Review: 116 refs.
ChemInform Abstract: The Electron is a Catalyst
Authors: Studer Armido , Curran Dennis P.
Published: December 2014

Review: 66 refs.
ChemInform Abstract: Application of Langlois′ Reagent in Trifluoromethylation Reactions
Authors: Zhang Cai
Published: December 2014

Review: [40 refs.
ChemInform Abstract: Effects of Ultrasound and Microwaves on Selective Reduction: Catalyst Preparation and Reactions
Authors: Wu Zhilin , Borretto Emily , Medlock Jonathan , Bonrath Werner , Cravotto Giancarlo
Published: December 2014

Review: 145 refs.
ChemInform Abstract: Carbon—Carbon Bond Formation via Electron Transfer: Anodic Coupling
Authors: Schäfer Hans‐J.
Published: December 2014

Review: 57 refs.
ChemInform Abstract: Pushing Flow Chemistry to New Limits: Development of a Flow Process Towards Spirangien A
Authors: Juerjens Gerrit , Kirschning Andreas
Published: December 2014

Review: 12 refs.
ChemInform Abstract: gt‐C3N4 — The First Stable Binary Carbon(IV) Nitride
Authors: Kroke Edwin
Published: December 2014

Review: 44 refs.
ChemInform Abstract: The Asymmetric Hetero‐Diels—Alder Reaction in the Syntheses of Biologically Relevant Compounds
Authors: Eschenbrenner‐Lux Vincent , Kumar Kamal , Waldmann Herbert
Published: December 2014

Review: 84 refs.
ChemInform Abstract: Recent Developments in the Chemistry of gem‐Halonitro Compounds
Authors: Soengas Raquel G. , Acurcio Rita C. , Silva Artur M. S.
Published: December 2014

Review: [66 refs.
ChemInform Abstract: α‐Amination of Phosphonates: A Direct Synthesis of α‐Amino Phosphonic Acids and Their Derivatives
Authors: McDonald Stacey L. , Wang Qiu
Published: December 2014

Review: [20 refs.
ChemInform Abstract: A General Overview of the Organocatalytic Intramolecular Aza‐Michael Reaction
Authors: Sanchez‐Rosello Maria , Acena Jose Luis , Simon‐Fuentes Antonio , del Pozo Carlos
Published: December 2014

Review: 83 refs.
ChemInform Abstract: Synthesis of Aryl(di)azinylmethanes and Bis(di)azinylmethanes via Transition‐Metal‐Catalyzed Cross‐Coupling Reactions
Authors: De Houwer Johan , Maes Bert U. W.
Published: December 2014

Review: [51 refs.
ChemInform Abstract: The (Not So) Ephemeral Trifluoromethanide Anion
Authors: Santschi Nico , Gilmour Ryan
Published: December 2014

Review: 13 refs.
ChemInform Abstract: Processive Catalysis
Authors: van Dongen Stijn F. M. , Elemans Johannes A. A. W. , Rowan Alan E. , Nolte Roeland J. M.
Published: December 2014

Review: processive catalysis and advances made in emulating it through supramolecular chemistry; 38 refs.
ChemInform Abstract: Reactivity and Stability of Glucosinolates and Their Breakdown Products in Foods
Authors: Hanschen Franziska S. , Lamy Evelyn , Schreiner Monika , Rohn Sascha
Published: December 2014

Review: [176 refs.
ChemInform Abstract: Asymmetric 1,3‐Dipolar Cycloadditons of Stabilized Azomethine Ylides with Nitroalkenes
Authors: Nejera Carmen , Sansano Jose M.
Published: December 2014

Review: as a route for the synthesis of polysubstituted nitro‐prolines and ‐pyrrolidins; 88 refs.
ChemInform Abstract: Recent Advances in α‐Alkylation Reactions Using Alcohols with Hydrogen Borrowing Methodologies
Authors: Obora Yasushi
Published: December 2014

Review: 142 refs.
ChemInform Abstract: Some Recent Advances in Transition‐Metal‐Catalyzed ortho Sp2 C—H Functionalization Using Ru, Rh, and Pd
Authors: Rao Yu , Shan Gang , Yang XingLin
Published: December 2014

Review: 77 refs.
ChemInform Abstract: Transition Metal Mediated Functionalization of O‐Carboranes
Authors: Xie Zuo Wei
Published: December 2014

Review: 10 refs.
ChemInform Abstract: Enantioselective Heterogeneous Broensted Acid Catalysis
Authors: Mutyala Anil Kumar , Patil Nitin T.
Published: December 2014

Review: 29 refs.
ChemInform Abstract: The Role of Pyrimidines and Its Derivatives in Heterocyclic Chemistry
Authors: Pareek Aastha , Rani Priyanka , Kumar Navneet , Sharma Pratima , Kishore D.
Published: December 2014

Review: 38 refs.
ChemInform Abstract: Palladium‐Catalyzed Approach to the Synthesis of Five‐Membered O‐Heterocycles
Authors: Kaur Navjeet
Published: December 2014

Review: 268 refs.
ChemInform Abstract: 4,7‐Dihydroindole: A Synthon for the Preparations of 2‐Substituted Indoles
Authors: Kilic Haydar , Bayindir Sinan , Saracoglu Nurullah
Published: December 2014

Review: 61 refs.
ChemInform Abstract: 2‐Chloroquinoline‐3‐carbaldehyde II: Synthesis, Reactions and Applications
Authors: Abdel‐Wahab Bakr F. , Khidre Rizk E.
Published: December 2014

Review: data from 1979 to 1999; 44 refs.
ChemInform Abstract: Magnetoelasticity
Authors: Zrinyi M.
Published: December 2014

Review: 57 refs.
ChemInform Abstract: The Phenomenological Theory of Magnetization Relaxation (Review Article)
Authors: Baryakhtar V. G. , Danilevich A. G.
Published: December 2014

Review: 38 refs.