bluuebunny/crossref_metadata_2025 huggingface dataset:
Synthesis of New Complex Ferrite Li0.5MnFe1.5O4: Chemical–Physical and Electrophysical Research
Authors: Mataev Mukhametkali , Madiyarova Altynai , Patrin Gennady , Abdraimova Moldir , Nurbekova Marzhan , Durmenbayeva Zhadyra
Published: July 2024

In this article, the sol–gel method was used as a synthesis method, which shows the physicochemical nature of the synthesis of a new complex material, ferrite Li0.5MnFe1.5O4. The structure and composition of the synthesized ferrite were determined by X-ray phase analysis. According to analysis indicators, it was found that our compound is a single-phase, spinel-structured, and syngony-cubic type of compound. The microstructure of the compound and the quantitative composition of the elements contained within it were analyzed under a scanning electron microscope (SEM). Under a scanning electron microscope, microsystems were taken from different parts of Li0.5MnFe1.5O4-type crystallite; the elemental composition of crystals was analyzed; and the general type of surface layer of complex ferrite was shown. As a result, given the fact that the compound consists of a single phase, the clarity of its construction was determined by the topography and chemical composition of the compound. As a result, it was found that the newly synthesized complex ferrites correspond to the formula Li0.5MnFe1.5O4. The particles of the formed compounds have a large size (between 50.0 μm or 20.0 μm and 10.0 μm). Electrophysical measurements were carried out on an LCR-800 unit at intervals of 293–483 K and at frequencies of 1.5 and 10 kHz. An increase in frequency to 10 kHz led to a decrease in the value ε in the range of the studied temperature (293–483 K).
Revisiting the Effect of the Resistance to Gas Accumulation in Constant Volume Systems on the Membrane Time Lag
Authors: Leszczynski Peter Jr. , Lashkari Siamak , Kruczek Boguslaw
Published: July 2024

The time-lag method is commonly used to determine membrane permeability, diffusivity and solubility in a single gas permeation experiment in a constant volume system. An unwritten assumption on which this method relies is that there is no resistance to gas accumulation in the downstream receiver of the system. However, this is not the case, even with the specially designed receiver used in this study when, in addition to tubing, the receiver utilizes an additional accumulation tank. The resistance to gas accumulation originates from a finite diffusivity (Knudsen diffusion) of gases in tubing, which are magnified by “resistance-free” accumulation tank(s). As a result of the resistance to gas accumulation, the time lag of the membrane is underestimated, which leads to an overestimation of gas diffusivity in the membrane. The experimentally predicted resistances in different configurations of the receiver, expressed by the difference in the time lag at two different receiver locations, were several times greater than the theoretically predicted values. A high molecular PPO membrane was used to demonstrate this effect. The time lags measured at different locations differed by as much as 30%. The diffusivity of nitrogen in a PPO of 4.04 × 10−12 m2/s determined at the optimum configuration of the receiver is at least 50% lower than the literature-reported values.
Remediation of Heavy Metal Pollution from Coal Mine Effluent Using Metal-Organic Frameworks (MOF): Impact of Water Media, Operational Factors and Metal Characteristics
Authors: Bi Guangxu , Li Xiangyu , Du Xiaochong , Sun Xinhua , Yao Wenpeng
Published: July 2024

The energy sector is the sector that generates the highest amount of environmental contamination, especially in water sources, mostly in the case of coal-based energy production. The aim of this study was to examine a significant contamination source, heavy metal contamination, in coal mining effluents. The current investigation introduces an MOF platform based on zirconium clusters and isophthalic acid with NH2-MIP-SO3H mixed amine and sulfonic acid functional groups in order to remove the most common heavy metal ions in coal mining effluents, including Hg, Cd, Pb, and Cu ions. The water matrix and the operational conditions were identified to be very influential in the removal process, such as the pH of water, the initial metal concentration and operating time. NH2-MIP-SO3H offers a great removal efficiency of metals starting from 745.83 mg/g for Cd, 673.67 mg/g for Cu, 589.85 mg/g for Hg, and 481.66 mg/g for Pb ions, with the Langmuir equation for equilibrium and pseudo-second-order equation for kinetics being the ideal models to express the equilibrium and kinetic data, respectively. A significant impact of water pH was found to occur, with the NH2-MIP-SO3H platform performing best at pH 6. Reuse of NH2-MIP-SO3H demonstrates excellent reusability, sustaining 90% of initial performance over eight regeneration cycles. The interaction of functional group-functional metal was the dominant mechanism in the removal process. The NH2-MIP-SO3H unique approach to heavy metal removal provides a very hopeful outlook for additional investigations in larger-scale studies.
Acceleration of Iron-Rich Olivine CO2 Mineral Carbonation and Utilization for Simultaneous Critical Nickel and Cobalt Recovery
Authors: Wang Fei , Dreisinger David
Published: July 2024

CO2 mineral carbonation is an important method to sequester carbon dioxide (CO2) in the form of stable mineral carbonates for permanent storage. The slow kinetics of carbonation, especially for iron-rich olivine, is the major challenge for potential application. This work proposes methods to accelerate the mineral carbonation process of different materials in the general mineral grouping of divalent metals–olivine for simultaneous nickel and cobalt recovery. It is found that nickel-olivine is facile for mineral carbonation compared to ferrous and magnesium olivine. Ferrous olivine is the most difficult form of olivine to carbonate as illustrated in both thermodynamics and experimental test results. The increase in iron content in olivine inhibits the CO2 mineral carbonation process by forming an iron-silica-rich passivation interlayer. The use of a reducing gas or reagent can enhance the mineral carbonation of olivine probably through hindering oxidation of Fe(Ⅱ). The addition of sodium nitrilotriacetate (NTA) as a metal complexing agent is much more efficient for the acceleration than usage of a reducing atmosphere. The combination of sodium bicarbonate/CO2 gas supply and NTA can enhance the diffusion of all divalent metal ions from the reacting olivine surface, thereby limiting the formation of the passivation interlayer. Meanwhile, highly selective nickel and cobalt leaching can be simultaneously achieved along with the CO2 mineral carbonation, 94% nickel, and 92% cobalt leaching as well as 47% mineral carbonation versus only 10% iron and 1% magnesium leached in 2 h. This work provides a novel direction to achieve critical metals recovery with accelerated mineral carbonation process.
Modes of Occurrence, Migration, and Evolution Pathways of Lithium and Gallium during Combustion of an Al-Rich Coal, Inner Mongolia, China
Authors: Feng Lili , Bian Kaixuan , Zhang Kailong , Geng Jiawei , Zheng Yanmin , Li Xiao
Published: July 2024

The modes of occurrence, migration, and evolution pathways of lithium (Li) and gallium (Ga) during combustion of an Al-rich coal from Inner Mongolia, China, were investigated using methods of simulated combustion experiments, the sequential chemical extraction procedure (SCEP), and the thermodynamic equilibrium calculation. Mineralogical and chemical compositions of the feed coal and combustion ash were analyzed by X-ray fluorescence (XRF), X-ray diffraction (XRD), inductively coupled plasma mass spectrometry (ICP-MS), and scanning electron microscopy (SEM). The study reveals that Li and Ga are significantly enriched in the ash after combustion, with the contents reaching up to 1086 μg/g and 133 μg/g, respectively. The primary modes of occurrence of Li and Ga in the ash are quartz and aluminosilicates, and sulfides, respectively. Li, in the form of LiAlSi4O10 (s), primarily occurs in hematite, glass, and quartz below 800 °C. However, it migrates into the glass phase, mullite, and quartz above 1000 °C. On the other hand, Ga exists as Ga4S5 (s) and transforms into Ga2S (g) as the temperature rises from 800 °C to 1000 °C, maintaining this gaseous form until 1200 °C. Ga4S5 (s) predominantly occurs in the glass phase at 600 °C, whereas mullite and quartz become its dominant modes of occurrence in industrial combustion ashes and ashes obtained from simulated combustion above 600 °C.
Durability of Non-Heat-Cured Geopolymer Mortars Containing Metakaolin and Ground Granulated Blast Furnace Slag
Authors: Işıkdağ Burak , Mutlu Hidayet Alper
Published: July 2024

This study presents the durability, strength and microstructure of non-heat-cured geopolymer mortars (GMs) containing metakaolin (MK), ground granulated blast furnace slag (GGBFS), potassium hydroxide (KOH), sodium metasilicate (Na2SiO3), CEN sand and network water. Optimum MK, GGBFS and activator solution ratios were investigated, and the compressive strength of non-heat-cured 28-day GMs reached 55 MPa. Analysis of GMs using scanning electron microscopy (SEM), energy-dispersive X-ray spectrophotometry (EDX) and X-ray powder diffraction (XRD) revealed alumino-silicate formation, potassium from KOH solution and calcium from GGBFS. It showed that the grains containing high silica in the form of quartz crystals were found in the gel formation. The strength and durability of MK- and GGBFS-based GMs exposed to freeze–thawing, a high temperature, wear loss, magnesium sulfate (MgSO4), sodium sulfate (Na2SO4) and HCl solutions were found to be sufficient.
Heavy Mineral and Zircon Age Constraints on Provenance of Cenozoic Sandstones in the Gulf of Mexico Subsurface
Authors: Morton Andrew C. , Strickler Michael E. , Fanning C. Mark
Published: July 2024

Combined heavy mineral analysis and detrital zircon geochronology have enabled us to track detritus supplied by the ancestral river systems draining the North American continent into the deep subsurface of the Gulf of Mexico, in both the coastal plain and the offshore deep water areas. During deposition of the Paleocene–Eocene Wilcox Group, sandstones in the western part of the area are interpreted as the products of the Rosita system derived via paleo-Rio Grande material, with a large component of sediment shed from the Western Cordillera. By contrast, samples from wells further east have high proportions of zircons derived from the Yavapai-Mazatzal Province and are attributed to the Rockdale system with sediment fed predominantly by the paleo-Colorado or paleo-Colorado-Brazos. There is evidence that sediment from the Rosita system occasionally extended into the central Gulf of Mexico, and, likewise, data indicate that the Rockdale system sporadically supplied sediment to the western part of the basin. During the Late Eocene of the central Gulf of Mexico (Yegua Formation) there was a distinct shift in provenance. The earlier Yegua sandstones have a large Grenville zircon component and are most likely to have had a paleo-Mississippi origin, whereas the later Yegua sandstones are dominated by zircons of Western Cordilleran origin, similar to Wilcox sandstones fed by the Rosita system via the paleo-Rio Grande. The switch from paleo-Mississippi to paleo-Rio Grande sourcing implies there was a major reorganisation of drainage patterns during the Late Eocene. Miocene sandstones in the deepwater Gulf of Mexico were principally sourced from the paleo-Mississippi, although the paleo-Red River is inferred to have contributed to the more westerly-located wells.
Slag after Smelting of Anode Mud: Role of Sulphiding Sintering
Authors: Sokolovskaya Lyudmila , Kvyatkovskiy Sergey , Kozhakhmetov Sultanbek , Semenova Anastassiya , Sukurov Bulat , Dyussebekova Maral , Shakhalov Alexander
Published: July 2024

The study object was slag from the Balkhash copper smelter, obtained by re-melting anode mud containing nonferrous metals. The process flow for processing these slags includes sintering with Na2SO4, Na2CO3, and coal, followed by soda-alkaline leaching of the sinter and extraction of metals from the solution into marketable products. Since sintering is the main operation providing high selectivity, the composition of the products of this process was studied. The main transformations during sintering were determined, and the optimal parameters were identified. The structures of slags and sintered materials obtained during the experiments were studied by electron-probe microanalysis. Sintering was performed at 600–800 °C. The best results for sulphidization of slag components were obtained at 800 °C; a further increase in temperature leads to the smelting of sinter particles and slows down sulphidization. The optimal quantities of additives, based on the weight of the slag, are Na2SO4—45%, Na2CO3—15%, and reducing agent—41%, with a sintering time of 2 h. These conditions enable the sulphidization of non-ferrous metals in the slag to the entire depth of the polymetallic globules. The distinct concentration of harmful impurities (Ni, As, and Sb) was observed in the fine structure of the polymetallic globules.
Silver and Carbon Nanomaterials/Nanocomplexes as Safe and Effective ACE2-S Binding Blockers on Human Skin Cell Lines
Authors: Hotowy Anna , Strojny-Cieślak Barbara , Ostrowska Agnieszka , Zielińska-Górska Marlena , Kutwin Marta , Wierzbicki Mateusz , Sosnowska Malwina , Jaworski Sławomir , Chwalibóg André , Kotela Ireneusz , Sawosz Chwalibóg Ewa
Published: July 2024

(1) Background: Angiotensin-converting enzyme 2 (ACE2) is a crucial functional receptor of the SARS-CoV-2 virus. Although the scale of infections is no longer at pandemic levels, there are still fatal cases. The potential of the virus to infect the skin raises questions about new preventive measures. In the context of anti-SARS-CoV-2 applications, the interactions of antimicrobial nanomaterials (silver, Ag; diamond, D; graphene oxide, GO and their complexes) were examined to assess their ability to affect whether ACE2 binds with the virus. (2) Methods: ACE2 inhibition competitive tests and in vitro treatments of primary human adult epidermal keratinocytes (HEKa) and primary human adult dermal fibroblasts (HDFa) were performed to assess the blocking capacity of nanomaterials/nanocomplexes and their toxicity to cells. (3) Results: The nanocomplexes exerted a synergistic effect compared to individual nanomaterials. HEKa cells were more sensitive than HDFa cells to Ag treatments and high concentrations of GO. Cytotoxic effects were not observed with D. In the complexes, both carbonic nanomaterials had a soothing effect against Ag. (4) Conclusions: The Ag5D10 and Ag5GO10 nanocomplexes seem to be most effective and safe for skin applications to combat SARS-CoV-2 infection by blocking ACE2-S binding. These nanocomplexes should be evaluated through prolonged in vivo exposure. The expected low specificity enables wider applications.
Infrared Matrix-Isolation and Theoretical Studies of the Reactions of Bis(benzene)chromium with Ozone
Authors: Kugel Roger W. , Ault Bruce S.
Published: July 2024

Reactions of bis(benzene)chromium (Bz2Cr) and ozone (O3) were studied using low-temperature argon matrix-isolation infrared spectroscopy with supporting DFT calculations. When Bz2Cr and O3 were co-deposited, they reacted upon matrix deposition to produce two new prominent peaks in the infrared spectrum at 431 cm−1 and 792 cm−1. These peaks increased upon annealing the matrix to 35 K and decreased upon UV irradiation at λ = 254 nm. The oxygen-18 and mixed oxygen-16,18 isotopic shift pattern of the peak at 792 cm−1 is consistent with the antisymmetric stretch of a symmetric ozonide species. DFT calculations of many possible ozonide products of this reaction were made. The formation of a hydrogen ozonide (H2O3) best fits the original peaks and the oxygen-18 isotope shift pattern. Energy considerations lead to the conclusion that the chromium-containing product of this reaction is the coupled product benzene-chromium-biphenyl-chromium-benzene (BzCrBPCrBz). 2Bz2Cr+O3→H2O3+BzCrBPCrBz, ∆Ecalc=−52.13kcal/mol.
Dye Sorption from Mixtures on Chitosan Sorbents
Authors: Filipkowska Urszula , Jóźwiak Tomasz
Published: July 2024

This article presents studies on the sorption of the anionic dyes Reactive Black 5 (RB5) and Reactive Yellow 84 (RY84) from solutions of single dyes and from dye mixtures onto three chitosan sorbents–chitin, chitosan DD75% and chitosan DD95%. In this work, the influence of pH on sorption efficiency, the sorption equilibrium time for the tested anionic dyes and the sorption capacity in relation to the individual dyes and their mixtures were determined. It has been found that the sorption process for both dyes was most effective at pH 3 for chitin and chitosan DD75 and at pH 4 for chitosan DD95%. The obtained results were described by the double Langmuir equation (Langmuir 2). The obtained constants made it possible to determine the affinity of the tested dyes for the three sorbents and the sorption capacity of the sorbents. For RB5, the highest sorption capacity for chitosan DD95% was achieved with sorption from a single solution–of 742 mg/g DM and with sorption from mixed dyes–of 528 mg/g DM. For RY84, the highest efficiency was also achieved for chitosan DD95% and was 760 mg/g DM for a single dye solution and 437 mg/g DM for a mixture of dyes.
Improvement of Echinacea purpurea and Ganoderma lucidum Extracts with Cell Model on Influenza A/B Infection
Authors: Chen Bo-Kai , Chan Chi-Ho , Tsao Arthur , Wang Chin-Kun
Published: July 2024

Since 2019, COVID-19 has been raging around the world. Respiratory viral infectious diseases such as influenza and respiratory syncytial virus (RSV) infection are also prevalent, with influenza having the ability to cause seasonal pandemics. While vaccines and antiviral drugs are available to prevent and treat disease, herbal extracts would be another option. This study investigated the inhibitory effects of extracts of Echinacea purpurea (EP) and Ganoderma lucidum (G. lucidum) and the advanced G. lucidum drink (AG) on influenza A/B viruses. To determine whether EP and G. lucidum extracts enhance cell immunity and thus prevent virus infection or act to directly suppress viruses, cell survival and hemagglutination (HA) assays were used in this study. Cells were treated with samples at different concentrations (each sample concentration was tested from the highest non-cytotoxic concentration) and incubated with influenza A/B for 24 h, with the results showing that both G. lucidum and EP extracts and mixtures exhibited the ability to enhance cell survival against viruses. In the HA assay, AG and EP extract showed good inhibitory effect on influenza A/B viruses. All of the samples demonstrated an improvement of the mitochondrial membrane potential and improved resistance to influenza A/B virus infection. EP and G. lucidum extracts at noncytotoxic concentrations increased cell viability, but only AG and EP extract directly decreased influenza virus titers. In conclusion, results indicate the ability of EP and G. lucidum extract to prevent viruses from entering cells by improving cell viability and mitochondrial dysfunction and EP extract showed direct inhibition on viruses and prevented viral infection at post-infection strategy.
Stability of Nitrogen-Doped Activated Carbon as an Electrocatalyst for the Oxygen Reduction Reaction in Various Storage Media
Authors: Zhang Tao , Zuo Songlin
Published: July 2024

Besides outstanding catalytic performance, the stability of nitrogen-doped carbon materials during storage is equally crucial for practical applications. Therefore, we conducted the first investigation into the stability of highly nitrogen-doped activated carbon (AC-NC-T) obtained by modifying activated carbon with CO2/NH3 in different storage media (air, vacuum and N2). The results of the catalysis of the oxygen reduction reaction and the activation of peroxymonosulfate for degrading bisphenol A by AC-NC-T show that the catalytic activity of AC-NC-T stored in air decays most prominently, while the performance attenuated only marginally when stored in vacuum and N2. The results from N2 adsorption isotherms, Raman spectroscopy, elemental and X-ray photoelectron spectroscopy indicate that the decline in catalytic activity is due to the presence of oxygen in the environment, causing a decrease in absolute contents of pyridinic N (N-6) and graphitic nitrogen (N-Q). After being stored in an air atmosphere for 28 days, the absolute contents of N-6 and N-Q in AC-NC-950 decreased by 19.3% and 12.1%, respectively. However, when stored in a vacuum or N2, the reduction in both was less than 7%. This study demonstrates that reducing oxygen concentration during storage is crucial for preserving high catalytic activity of nitrogen-containing carbon materials.
Domino Reactions Enable Zn-Mediated Direct Synthesis of Spiro-Fused 2-Oxindole-α-Methylene-γ-Butyrolactones/Lactams from Isatin Derivatives and 2-(Bromomethyl)acrylates
Authors: Mukthapuram Prathap Reddy , Natarajan Amarnath
Published: July 2024

Isatin-derived spirocyclic cores are found in several biologically active molecules. Here, we report nucleophilic domino reactions for the synthesis of α-methylene-γ-butyrolactone/lactam containing spirocyclic oxindoles. The Zn-mediated one-step reaction accommodates a range of substrates and can be used to rapidly generate focused libraries of highly substituted spirocyclic compound.
Size Uniformity of CsPbBr3 Perovskite Quantum Dots via Manganese-Doping
Authors: Zhang Mi , Han Xue , Yang Changgang , Zhang Guofeng , Guo Wenli , Li Jialu , Chen Zhihao , Li Bin , Chen Ruiyun , Qin Chengbing , Hu Jianyong , Yang Zhichun , Zeng Ganying , Xiao Liantuan , Jia Suotang
Published: July 2024

The achievement of size uniformity and monodispersity in perovskite quantum dots (QDs) requires the implementation of precise temperature control and the establishment of optimal reaction conditions. Nevertheless, the accurate control of a range of reaction variables represents a considerable challenge. This study addresses the aforementioned challenge by employing manganese (Mn) doping to achieve size uniformity in CsPbBr3 perovskite QDs without the necessity for the precise control of the reaction conditions. By optimizing the Mn:Pb ratio, it is possible to successfully dope CsPbBr3 QDs with the appropriate concentrations of Mn²⁺ and achieve a uniform size distribution. The spectroscopic measurements on single QDs indicate that the appropriate Mn²⁺ concentrations can result in a narrower spectral linewidth, a longer photoluminescence (PL) lifetime, and a reduced biexciton Auger recombination rate, thus positively affecting the PL properties. This study not only simplifies the size control of perovskite QDs but also demonstrates the potential of Mn-doped CsPbBr3 QDs for narrow-linewidth light-emitting diode applications.
Exploring the Therapeutic Potential of 5-Fluorouracil-Loaded Calcium Carbonate Nanoparticles Combined with Natural Compound Thymoquinone for Colon Cancer Treatment
Authors: Deng Xi , Yang Zhongming , Chan Kim Wei , Abu Bakar Md Zuki
Published: July 2024

Given the need for novel and effective therapies for colon cancer, this study aimed to investigate the effects of 5-fluorouracil-loaded calcium carbonate nanoparticles (5FU-CaCO3np) combined with thymoquinone (TQ) against colon cancer. A shaking incubator and a high-speed homogenizer were used to prepare the optimal 5FU-CaCO3np, with characterizations of physicochemical properties, in vitro drug release profile, and biocompatibility. In vitro experiments and molecular docking were employed to evaluate the therapeutic potential of the combination for colon cancer treatment. Study results revealed that 5FU-CaCO3np with a size of approximately 130 nm was synthesized using the high-speed homogenizer. Its favorable biocompatibility, pH sensitivity, and sustained release properties facilitated reduced toxic side effects of 5-FU on NIH3T3 normal cells and enhanced inhibitory effects on CT26 colon cancer cells. The combination of 5FU-CaCO3np (1.875 μM) and TQ (30 μM) showed significantly superior anti-colon cancer effects to 5FU-CaCO3np alone in terms of cell proliferation and migration inhibition, cell apoptosis induction, and spheroid growth suppression in CT26 cells (p < 0.05), with strong interactions between the drugs and targets (E-cadherin, Bcl-2, PCNA, and MMP-2). These results provide evidence for 5FU-CaCO3np as a novel regimen against colon cancer. Combining 5FU-CaCO3np and TQ may offer a new perspective for colon cancer therapy.
Advanced Neural Network-Based Equalization in Intensity-Modulated Direct-Detection Optical Systems: Current Status and Future Trends
Authors: Xu Zhaopeng , Ji Tonghui , Wu Qi , Lu Weiqi , Ji Honglin , Yang Yu , Qiao Gang , Tang Jianwei , Cheng Chen , Liu Lulu , Wang Shangcheng , Liang Junpeng , Sun Zhongliang , Fan Linsheng , Wei Jinlong , Shieh William
Published: July 2024

Intensity-modulated direct-detection (IM/DD) optical systems are most widely employed in short-reach optical interconnects due to their simple structure and cost-effectiveness. However, IM/DD systems face mixed linear and nonlinear channel impairments, mainly induced by the combination of square-law detection and chromatic dispersion, as well as the utilization of low-cost non-ideal transceivers. To solve this issue, recent years have witnessed a growing trend of introducing machine learning technologies such as neural networks (NNs) into IM/DD systems for channel equalization. NNs usually present better system performance than traditional approaches, and various types of NNs have been investigated. Despite the excellent system performance, the associated high computational complexity is a major drawback that hinders the practical application of NN-based equalizers. This paper focuses on the performance and complexity trade-off of NNs employed in IM/DD systems, presenting a systematic review of the current status of NN-based equalizers as well as a number of effective complexity reduction approaches. The future trends of leveraging advanced NN in IM/DD links are also discussed.
Human Vital Signs Signal Monitoring and Repairment with an Optical Fiber Sensor Based on Deep Learning
Authors: Gao Haochun , Wang Qing , Zhou Jing , Yu Changyuan
Published: July 2024

Optical fiber sensors have been widely applied for their advantages such as small size, lightweight, and strong electronic interference robustness. Compared with current electronic sensors, optical fiber sensors perform better in measuring parameters in harsh environments, which makes them suitable for more and more applications, such as target tracing and detection and monitoring of health signs in medical services. However, due to fiber optic sensor failure, improper transmission and storage, or other reasons, missing data occur from time to time. Therefore, effective missing value processing methods are desirable as they can be used to facilitate data processing or analysis. In the present study, gated recurrent unit (GRU) interpolation is performed by using the generative adversarial network (GAN) model to process the irregular delay relationship between the data before and after the collection of incomplete vital signs data. Furthermore, a data interpolation model based on VS-E2E-GAN is proposed to reconstruct vital signs signals. The ROC curve (AUC), metrics including mean squared error (MSE), and accuracy (ACC) of experiments reach 0.901, 0.777, and 0.908, respectively, which indicates that the proposed VS-E2E-GAN model performs well in terms of vital signs data imputation and repairment, has strong robustness when compared with other works, and has potential clinical application in health monitoring, smart home, and so on.
Perfect Off-Axis Optical Vortex Lattice
Authors: Tai Yuping , Qin Xueyun , Li Chenying , Wei Wenjun , Zhang Hao , Li Xinzhong
Published: July 2024

Optical vortex lattices (OVLs) with diverse modes show potential for a wide range of applications, such as high-capacity optical communications, optical tweezers, and optical measurements. However, vortices in typical regulated OVLs often exhibit irregular shapes, such as being narrow and elongated. The resulting increase in asymmetry negatively impacts the efficiency of particle trapping. Additionally, the vortex radii expand with an increase in topological charge (TC), limiting the TC value of the vortices and hindering their ability to fully utilize orbital angular momentum (OAM). Herein, we propose an alternative approach to custom OVLs using off-axis techniques combined with amplitude modulation. Amplitude modulation enables the precise generation of an OVL with perfect vortex properties, known as a perfect off-axis OVL. Further, the number of vortices in the perfect off-axis OVL, the off-axis distances, and the TC can be freely modulated while maintaining a circular mode. This unique OVL will promote new applications, such as the complex manipulation of multi-particle systems and optical communication based on OAM.
Facile Preparation of Superhydrophobic PDMS Polymer Films with Good Mechanical Strength Based on a Wear-Resistant and Reusable Template
Authors: Chen Zhi , Lu Shuang , Wei Yumeng , Zhang Guojun , Han Fenglin
Published: July 2024

In this paper, a new method involving a wear-resistant and reusable template is proposed for the preparation of high-mechanical-strength superhydrophobic polymer film based on wire electrical discharge machining (WEDM). A solid−liquid-contact-angle simulation model was established to obtain surface-texture types and sizes that may achieve superhydrophobicity. The experimental results from template preparation show that there is good agreement between the simulation and experimental results for the contact angle. The maximum contact angle on the template can reach 155.3° given the appropriate triangular surface texture and WEDM rough machining. Besides, the prepared superhydrophobic template exhibits good wear resistance and reusability. PDMS superhydrophobic polymer films were prepared by the template method, and their properties were tested. The experimental results from the preparation of superhydrophobic polymer films show that the maximum contact angle of the polymer films can be up to 154.8° and that these films have good self-cleaning and anti-icing properties, wear resistance, bending resistance, and ductility.
Assessing Intra-Bundle Impregnation in Partially Impregnated Glass Fiber-Reinforced Polypropylene Composites Using a 2D Extended-Field and Multimodal Imaging Approach
Authors: Sidlipura Sujith , Ayadi Abderrahmane , Lagardère Deléglise Mylène
Published: July 2024

This study evaluates multimodal imaging for characterizing microstructures in partially impregnated thermoplastic matrix composites made of woven glass fiber and polypropylene. The research quantifies the impregnation degree of fiber bundles within composite plates manufactured through a simplified compression resin transfer molding process. For comparison, a reference plate was produced using compression molding of film stacks. An original surface polishing procedure was introduced to minimize surface defects while polishing partially impregnated samples. Extended-field 2D imaging techniques, including polarized light, fluorescence, and scanning electron microscopies, were used to generate images of the same microstructure at fiber-scale resolutions throughout the plate. Post-processing workflows at the macro-scale involved stitching, rigid registration, and pixel classification of FM and SEM images. Meso-scale workflows focused on 0°-oriented fiber bundles extracted from extended-field images to conduct quantitative analyses of glass fiber and porosity area fractions. A one-way ANOVA analysis confirmed the reliability of the statistical data within the 95% confidence interval. Porosity quantification based on the conducted multimodal approach indicated the sensitivity of the impregnation degree according to the layer distance from the pool of melted polypropylene in the context of simplified-CRTM. The findings underscore the potential of multimodal imaging for quantitative analysis in composite material production.
Color Stability of Single-Shade Resin Composites in Direct Restorations: A Systematic Review and Meta-Analysis of Randomized Controlled Trials
Authors: Leal Caroline de Farias Charamba , Miranda Samille Biasi , Alves Neto Everardo Lucena de , Freitas Keitry , de Sousa Wesley Viana , Lins Rodrigo Barros Esteves , de Andrade Ana Karina Maciel , Montes Marcos Antônio Japiassú Resende
Published: July 2024

The objective was to compare the color match and color stability behavior of single- and multi-shade resin-based composites (RBCs) used for direct restorations. This review was conducted according to the Preferred Reporting Items for Systematic Reviews and Meta-Analyses guidelines. Randomized clinical trials evaluating the shade performance of single-shade RBCs in direct restorations were included. A search of the scientific literature was performed in five databases (April 2024). The meta-analysis was performed using RevMan 5.4, calculating the risk difference (RD) and 95% confidence interval (CI) of the dichotomous outcome using a random effects model. Bias was assessed using the RoB 2.0 tool, and certainty of evidence was assessed using the GRADEpro tool. Four studies were selected, with 263 restorations analyzed. The results showed comparable performance between single-shade RBCs and multi-shade RBCs in terms of color match and color stability over 12 months. Three studies had a low risk of bias with all expected results, and one study had some concerns. The certainty of evidence for color stability was considered low for all follow-up periods due to the small number of events and sample size. According to the United States Public Health Service Evaluation (USPHS) and the World Dental Federation (FDI), there is comparable clinical color performance between single-shade and multi-shade RBCs over 12 months.
Preparation and Structural-Thermodynamical Investigation of Renewable Copolyesters Based on Poly (Ethylene Succinate) and Polyisosorbide
Authors: Bouyahya Chaima , Klonos Panagiotis A. , Zamboulis Alexandra , Xanthopoulou Eleftheria , Ainali Nina Maria , Majdoub Mustapha , Kyritsis Apostolos , Bikiaris Dimitrios N.
Published: July 2024

A series of novel renewable copolymers based on poly(ethylene succinate) (PESu) and poly(isosorbide succinate) (PISSu), with the Isosorbide (Is)/PESu molar ratio varying from 5/95 to 75/25, were synthesized in-situ and studied in this work. A sum of characterization techniques was employed here for the structural and thermo-dynamical characterization. The sophisticated technique of dielectric spectroscopy, along with proper analysis, enabled the molecular dynamics mapping of both the local and segmental types, which is presented for such materials for the first time. With increasing the Is fraction, shorter copolymeric entities were gradually formed. Based on the overall findings, the systems were found to be homogeneous, e.g., exhibiting single glass transitions, with the two polymer segments being found to be excellently distributed. The latter is indirect, although strong, evidence for the successful copolymerization. The thermal degradation mechanism for the copolymers was exhaustingly explored employing analytical pyrolysis. The systems exhibited, in general, good thermal stability, according to the thermogravimetric analysis. Confirming one of the initial scopes for the present systems, isosorbide plays here the role of hardener (PISSu) over the soft polymer (PESu), and this is reflected in the monotonic increase of the glass transition temperature, Tg, from −16 to ~56 °C. The introduction of Is results in an increase in constraints (hardening of the matrix), while there seems to be an overall densification of the polymer (decrease of the free volume).
Development, Characterization, and Cellular Toxicity Evaluation of Solid Dispersion-Loaded Hydrogel Based on Indomethacin
Authors: Dahma Zaid , Ibáñez-Escribano Alexandra , Fonseca-Berzal Cristina , García-Rodríguez Juan José , Álvarez-Álvarez Covadonga , Torrado-Salmerón Carlos , Torrado-Santiago Santiago , de la Torre-Iglesias Paloma Marina
Published: July 2024

Indomethacin (IND) as a non-selective cyclooxygenase 1 and 2 inhibitor administered orally causes numerous adverse effects, mostly related to the gastrointestinal tract. Moreover, when applied exogenously in topical preparations, there are obstacles to its permeation through the stratum corneum due to its low water solubility and susceptibility to photodegradation. In this work, solid dispersions (SDs) of IND with low-substituted hydroxypropyl cellulose (LHPC) were developed. The IND—SDs were incorporated into a hydroxypropyl guar (HPG) hydrogel to enhance drug solubility on the skin. The hydrogels were characterized by scanning electron microscopy (SEM), differential scanning calorimetry (DSC), powder X-ray diffraction (XRPD), Fourier-transform infrared spectroscopy (FTIR), viscosity, drug release, and unspecific cytotoxicity in mammalian cells. SEM showed a highly porous structure for SD hydrogels. DSC and XRPD studies showed that amorphous IND species were formed; therefore, these hydrogels exhibited superior drug release in comparison with IND raw material hydrogels. FTIR evidenced the presence of the hydrogen bond in the SD hydrogel. The rheology parameter viscosity increased across gels formulated with SDs in comparison with hydrogels with pure IND. In addition, IND—SD hydrogels combine the advantages of a suitable viscosity for dermal use and no potentially hazardous skin irritation. This study suggests that the formulated IND—SD hydrogels represent a suitable candidate for topical administration.
Assessing the Impact of Fly Ash and Recycled Concrete Aggregates on Fibre-Reinforced Self-Compacting Concrete Strength and Durability
Authors: Velumani Senthil Kumar , Venkatraman Sreevidya
Published: July 2024

Driven by the insatiable demand for construction materials, excessive quarrying for natural aggregates and the demand for raw materials for cement production pose significant environmental challenges, including habitat loss and resource depletion. To address these concerns, this study investigates the use of fibre-reinforced self-compacting concrete (FR-SCC) with high-volume fly ash (HVFA) and varying levels of recycled concrete aggregates (RCA) as substitutes for fine and coarse aggregates. This approach aims to simultaneously address environmental concerns by reducing reliance on virgin resources by utilizing the recycled aggregates and enhancing the performance of concrete through the combined benefits of fly ash and fibre reinforcement. In this study, Self-Compacting Concrete (SCC) mixes were created with 50% of fly ash replaced with conventional cement content, which was taken from the previous literature. Fine and coarse aggregate utilized in this investigation were replaced with processed recycled aggregates at varying levels from 0% to 100% at an interval of 25%, offering a promising solution to alleviate the environmental burden associated with excessive quarrying while contributing to sustainable construction practices. Additionally, replacement levels of aggregate synthetic polypropylene fibres (PF) were added into the concrete matrix up to 1% at an interval of 0.25%. This research contributes to the development of sustainable construction practices by promoting resource efficiency and minimizing environmental impact. The study found that SCC mixes with fibres and recycled aggregates maintained self-compactability, with polypropylene fibres and fly ash improving workability and cohesion. With this combination of materials, the highest strength value of 55.31 MPa was observed and the study promotes sustainable construction by reducing reliance on virgin resources and minimizing environmental impact.
Evaluation of GPM IMERG Early, Late, and Final Run in Representing Extreme Rainfall Indices in Southwestern Iran
Authors: Keikhosravi-Kiany Mohammad Sadegh , Balling Robert C.
Published: July 2024

The growing concerns about floods have highlighted the need for accurate and detailed precipitation data as extreme precipitation occurrences can lead to catastrophic floods, resulting in significant economic losses and casualties. Integrated Multi-satellitE Retrievals for the Global Precipitation Measurement (GPM IMERG) is a commonly used high-resolution gridded precipitation dataset and is recognized as trustworthy alternative sources of precipitation data. The aim of this study is to comprehensively evaluate the performance of GPM IMERG Early (IMERG-E), Late (IMERG-L), and Final Run (IMERG-F) in precipitation estimation and their capability in detecting extreme rainfall indices over southwestern Iran during 2001–2020. The Asfezari gridded precipitation data, which are developed using a dense of ground-based observation, were utilized as the reference dataset. The findings indicate that IMERG-F performs reasonably well in capturing many extreme precipitation events (defined by various indices). All three products showed a better performance in capturing fixed and non-threshold precipitation indices across the study region. The findings also revealed that both IMERG-E and IMERG-L have problems in rainfall estimation over elevated areas showing values of overestimations. Examining the effect of land cover type on the accuracy of the precipitation products suggests that both IMERG-E and IMERG-L show large and highly unrealistic overestimations over inland water bodies and permanent wetlands. The results of the current study highlight the potential of IMERG-F as a valuable source of data for precipitation monitoring in the region.
The Burden of Administrative Household Labor—Measuring Temporal Workload, Mental Workload, and Satisfaction
Authors: Dethier Erik , Stevens Gunnar , Boden Alexander
Published: July 2024

This research paper investigates the temporal and mental workload as well as work satisfaction regarding bureaucratic, administrative household labor, with a focus on socio-demographic differences. The study utilizes a paid online survey with 617 socio-demographically distributed participants. The results show significant differences in the temporal workload of different chore categories and in the quality of work, whereby satisfaction and mental workload are examined. In addition, the influences of gender, age, and education are analyzed, revealing differences in temporal and mental workload as well as work satisfaction. Our findings confirm prevailing literature showing that women have lower work satisfaction and a higher workload. In addition, we also discovered that younger people and groups of people with higher incomes have a higher level of satisfaction and a higher workload. In our study, a perceived high mental workload does not necessarily go hand in hand with a low level of satisfaction. This study contributes to the understanding of the bureaucratic burden on adults in their households and the variety of activities to manage private life.
The Impact of Green Human Resource Management Practices on Brand Citizenship Behavior and Employee Turnover Intention: A Mixed Methods Approach
Authors: Hajj Hussein Safaa , Bou Zakhem Najib
Published: July 2024

In light of the escalating necessity for sustainability within Lebanese small to medium-sized enterprises, these organizations are considered contributors to ecological damage. As a consequence, many of these enterprises adopted green human resource management practices encouraging employees toward sustainable behaviors. This is in conformity with the principles of the circular economy that aim to shun resource depletion and resonate with the country’s currency devaluation, political instability, and lack of access to resources. Given this background, this study aims to examine the influence of green human resource management practices on organizational pride, brand citizenship behavior, and turnover intention, moderated by individual green values. This study adopted a mixed-methods approach, collecting quantitative data from 202 employees working for small to medium-sized enterprises through a questionnaire, and qualitative insights through semi-structured interviews from eight managers; these were then analyzed using PLS-SEM and thematic analysis. The results showed that green human resource management practices lead to an increase in organizational pride, which positively influences brand citizenship behavior and negatively affects turnover intention. Individual green values positively moderate the aforementioned relationships. Understanding such detailed interrelationships adds insights into the literature of green practices. Moreover, this is the initial empirical investigation that integrates these concepts within the small to medium-sized enterprise context and provides comprehensive insights to stakeholders to enhance sustainability through appropriate human resource management strategies.
Environmental and Economic Evaluation of the Sequential Combination of Coagulation–Flocculation with Different Electro-Fenton-Based Configurations for the Treatment of Raw Textile Wastewater
Authors: Dobrosz-Gómez Izabela , Salazar-Sogamoso Luis-Miguel , Castaño-Sánchez Juan-Camilo , Salazar-López Daniel-Ovidio , Gómez-García Miguel-Ángel
Published: July 2024

This study reports, for the first time, on the assessment of a multistage sequential system composed of coagulation–flocculation with different electro-Fenton-based configurations, followed by neutralization (N), for the treatment of raw textile wastewater heavily contaminated with acid black 194 dye and other pollutants. Electrochemical peroxidation (ECP-N), electro-Fenton (EF-N) and peroxi-coagulation (PC-N) were tested at laboratory scale and compared in terms of their efficiency for the removal of organic matter and color, current efficiency and energetic parameter, operating cost and environmental sustainability using life cycle analysis conducted in large-scale virtual reactors. The three electro-Fenton-based systems complied with current environmental standards (color removal > 87%, COD < 400 mg/L, among others) requiring different electrolysis times: ECP-N (52 min) < PC-N (120 min) < EF-N (160 min); energy consumptions: ECP-N (2.27 kWh/m3) < PC-N (4.28 kWh/m3) < EF-N (33.2 kWh/m3); operational costs: ECP-N (2.63 USD/m3) < EF-N (6.65 USD/m3) < PC-N (6.98 USD/m3); among others. Electricity (for ECP-N and EF-N) and reagents (for ECP-N and PC-N) were found as main environmental hotspots. ECP-N presented the lowest carbon footprint of 10.3 kg CO2-Eq/FU (<PC-N (26.3 kg CO2-Eq/FU) < EF-N (38.0 kg CO2-Eq/FU), had lower incidence in all the impact categories analyzed (ReCiPe-2016 at midpoint level) and can be considered technically, economically and environmentally sustainable for large-scale applications.