bluuebunny/crossref_metadata_2025 huggingface dataset:
Leaf Removal Applied to a Sprawling Canopy to Regulate Fruit Ripening in Cabernet Sauvignon
Authors: O’Brien Patrick , Collins Cassandra , De Bei Roberta
Published: May 2021

Under the effects of climate change, it is becoming increasingly common to observe excessively fast grape sugar accumulation while phenolic and flavour development are lagging behind. The aim of this research was to quantify the impacts of three different leaf removal techniques on the canopy architecture and ripening of Cabernet Sauvignon trained in a sprawl trellis system. Treatments were performed at veraison (~14 °Brix) and included (i) control; (ii) leaf plucking in the bunch zone; (iii) leaf plucking the top two-thirds of shoots, apical to the bunches; and (iv) shoot trimming. On the date of harvest, no significant difference in total soluble solids was observed between treatments. Other results including the effect of the treatments on fruit acidity, anthocyanins, phenolics, and tannins were somewhat inconclusive. While various other studies have shown the potential of leaf removal to achieve slower grape sugar accumulation without affecting the concentration of anthocyanins, phenolics, and tannins, the results of this study do not indicate a decrease in the rate of grape sugar accumulation as a result of the investigated defoliation techniques. Given the cost of implementing these treatments, the results of this study do not support the use of these methods for the purpose of delaying fruit ripening in a hot Australian climate.
Hibiscus sabdariffa, a Treatment for Uncontrolled Hypertension. Pilot Comparative Intervention
Authors: Al-Anbaki Marwah , Cavin Anne-Laure , Nogueira Renata Campos , Taslimi Jaafar , Ali Hayder , Najem Mohammed , Shukur Mahmood Mustafa , Abdullah Khaleel Ibrahim , Saad Mohammed Abdulqader , Ramadhan Hasan Hasan , Marcourt Laurence , Félix Fabien , Vinh Tri Low-Der’s Nicolas , Ferreira Queiroz Emerson , Wolfender Jean-Luc , Watissée Marie , Graz Bertrand
Published: May 2021

In Iraq, in 2019, there were about 1.4 million Internally Displaced Persons (IDP); medical treatments were often interrupted. The feasibility of using Hibiscus sabdariffa (HS) decoction to curb hypertension was evaluated. A multicentric comparative pilot intervention for 121 participants with high blood pressure (BP) (≥140/90 mmHg) was conducted. Participants of the intervention group (with or without conventional medication) received HS decoction on a dose regimen starting from 10 grams per day. BP was measured five times over six weeks. The major active substances were chemically quantified. Results: After 6 weeks, 61.8% of participants from the intervention group (n = 76) reached the target BP < 140/90 mmHg, compared to 6.7% in the control group (n = 45). In the intervention group, a mean (±SD) reduction of 23.1 (±11.8) mmHg and 12.0 (±11.2) for systolic and diastolic BP, respectively, was observed, while in the control group the reduction was 4.4 (±10.2)/3.6 (±8.7). The chemical analysis of the starting dose indicated a content of 36 mg of total anthocyanins and 2.13 g of hibiscus acid. The study shows the feasibility of using HS decoction in IDP’s problematic framework, as hibiscus is a safe, local, affordable, and culturally accepted food product.
Physiological Responses of Ocimum basilicum, Salvia officinalis, and Mentha piperita to Leaf Wounding
Authors: Vrakas Konstantinos , Florou Efterpi , Koulopoulos Athanasios , Zervoudakis George
Published: May 2021

The investigation about the leaf wounding effect on plant physiological procedures and on leaf pigments content will contribute to the understanding of the plants’ responses against this abiotic stress. During the experiment, some physiological parameters such as photosynthesis, transpiration and stomatal conductance as well as the chlorophyll and anthocyanin leaf contents of Ocimum basilicum, Salvia officinalis, and Mentha piperita plants were measured for about 20–40 days. All the measurements were conducted on control and wounded plants while in the latter, they were conducted on both wounded and intact leaves. A wide range of responses was observed in the wounded leaves, that is: (a) immediate decrease of the gas exchange parameters and long-term decrease of almost all the measured variables from O. basilicum, (b) immediate but only short-term decrease of the gas exchange parameters and no effect on pigments from M. piperita, and (c) no effect on the gas exchange parameters and decrease of the pigments content from S. officinalis. Regarding the intact leaves, in general, they exhibited a similar profile with the control ones for all plants. These results imply that the plant response to wounding is a complex phenomenon depending on plant species and the severity of the injury.
Individual and Combined Effects of Booting and Flowering High-Temperature Stress on Rice Biomass Accumulation
Authors: Mahmood Aqib , Wang Wei , Ali Iftikhar , Zhen Fengxian , Osman Raheel , Liu Bing , Liu Leilei , Zhu Yan , Cao Weixing , Tang Liang
Published: May 2021

Extreme temperature events as a consequence of global climate change result in a significant decline in rice production. A two-year phytotron experiment was conducted using three temperature levels and two heating durations to compare the effects of heat stress at booting, flowering, and combined (booting + flowering) stages on the production of photosynthates and yield formation. The results showed that high temperature had a significant negative effect on mean net assimilation rate (MNAR), harvest index (HI), and grain yield per plant (YPP), and a significant positive effect under treatment T3 on mean leaf area index (MLAI) and duration of photosynthesis (DOP), and no significant effect on biomass per plant at maturity (BPPM), except at the flowering stage. Negative linear relationships between heat degree days (HDD) and MNAR, HI, and YPP were observed. Conversely, HDD showed positive linear relationships with MLAI and DOP. In addition, BPPM also showed a positive relationship with HDD, except at flowering, for both cultivars and Wuyunjing-24 at combined stages. The variation of YPP in both cultivars was mainly attributed to HI compared to BPPM. However, for biomass, from the first day of high-temperature treatment to maturity (BPPT-M), the main change was caused by MNAR followed by DOP and then MLAI. The projected alleviation effects of multiple heat stress at combined stages compared to single-stage heat stress would help to understand and evaluate rice yield formation and screening of heat-tolerant rice cultivars under current scenarios of high temperature during the rice-growing season.
Influence of Silver Nanoparticles on the Biological Indicators of Haplic Chernozem
Authors: Kolesnikov Sergey , Tsepina Natalia , Minnikova Tatiana , Kazeev Kamil , Mandzhieva Saglara , Sushkova Svetlana , Minkina Tatiana , Mazarji Mahmoud , Singh Rupesh Kumar , Rajput Vishnu D.
Published: May 2021

In recent years, silver nanoparticles (AgNPs) are increasingly used in various industries due to their antibacterial properties, which lead to an increase in pollution of the environment and soil ecosystems. However, the ecological effects of soil pollution by AgNPs were poorly studied than that with AgNPs of other metal-based NPs. The aim of this study is to assess the influence of AgNPs on the biological properties of Haplic Chernozem. Silver was introduced into the soil in the form of AgNPs with a concentration of 0.5; 1; 5; 10; 50, and 100 mg/kg in laboratory conditions. The influence of AgNPs on the biological properties of Haplic Chernozem was assessed 30 days after contamination. The degree of reduction in biological properties depends on the AgNPs concentration in the soil. This study showed that the sensitivity to contamination by AgNPs in the total number of bacteria and enzymatic activity was more than that in the abundance of bacteria of the genus Azotobacter. The integrated index of biological state (IIBS) of Haplic Chernozem was decreased by contamination with AgNPs. Silver nanoparticles in the concentration of 10 mg/kg caused a decrease in the indicator by 13% relative to the control. It also decreased IIBS by doses of 50 and 100 mg/kg by 22 and 27% relative to the control. All used biological indicators could be used for biomonitoring, biodiagnosis, bioindication, and regulation of ecological condition of soil contamination by AgNPs.
Foliar Endophytic Fungi from the Endangered Eastern Mountain Avens (Geum peckii, Rosaceae) in Canada
Authors: Adams Sarah J. , Robicheau Brent M. , LaRue Diane , Browne Robin D. , Walker Allison K.
Published: May 2021

Eastern Mountain Avens (Geum peckii Pursh, Rosaceae) is a globally rare and endangered perennial plant found only at two coastal bogs within Digby County (Nova Scotia, Canada) and at several alpine sites in the White Mountains of New Hampshire (USA). In Canada, the G. peckii population has declined over the past forty years due in part to habitat degradation. We investigated the culturable foliar fungi present in G. peckii leaves at five locations with varying degrees of human impact within this plant species’ Canadian range. Fungal identifications were made using ITS rDNA barcoding of axenic fungal cultures isolated from leaf tissue. Differences in foliar fungal communities among sites were documented, with a predominance of Gnomoniaceae (Class: Sordariomycetes, Phylum: Ascomycota). Habitats with more human impact showed lower endophytic diversities (10–16 species) compared to the pristine habitat (27 species). Intriguingly, several fungi may represent previously unknown taxa. Our work represents a significant step towards understanding G. peckii’s mycobiome and provides relevant data to inform conservation of this rare and endangered plant.
Effects of Elevated CO2 and Heat on Wheat Grain Quality
Authors: Wang Xizi , Liu Fulai
Published: May 2021

Wheat is one of the most important staple foods in temperate regions and is in increasing demand in urbanizing and industrializing countries such as China. Enhancing yield potential to meet the population explosion around the world and maintaining grain quality in wheat plants under climate change are crucial for food security and human nutrition. Global warming resulting from greenhouse effect has led to more frequent occurrence of extreme climatic events. Elevated atmospheric CO2 concentration (eCO2) along with rising temperature has a huge impact on ecosystems, agriculture and human health. There are numerous studies investigating the eCO2 and heatwaves effects on wheat growth and productivity, and the mechanisms behind. This review outlines the state-of-the-art knowledge regarding the effects of eCO2 and heat stress, individually and combined, on grain yield and grain quality in wheat crop. Strategies to enhance the resilience of wheat to future warmer and CO2-enriched environment are discussed.
Allelopathy of Lantana camara as an Invasive Plant
Authors: Kato-Noguchi Hisashi , Kurniadie Denny
Published: May 2021

Lantana camara L. (Verbenaceae) is native to tropical America and has been introduced into many other countries as an ornamental and hedge plant. The species has been spreading quickly and has naturalized in more than 60 countries as an invasive noxious weed. It is considered to be one of the world’s 100 worst alien species. L. camara often forms dense monospecies stands through the interruption of the regeneration process of indigenous plant species. Allelopathy of L. camara has been reported to play a crucial role in its invasiveness. The extracts, essential oil, leachates, residues, and rhizosphere soil of L. camara suppressed the germination and growth of other plant species. Several allelochemicals, such as phenolic compounds, sesquiterpenes, triterpenes, and a flavonoid, were identified in the extracts, essential oil, residues, and rhizosphere soil of L. camara. The evidence also suggests that some of those allelochemicals in L. camara are probably released into the rhizosphere soil under the canopy and neighboring environments during the decomposition process of the residues and as leachates and volatile compounds from living plant parts of L. camara. The released allelochemicals may suppress the regeneration process of indigenous plant species by decreasing their germination and seedling growth and increasing their mortality. Therefore, the allelopathic property of L. camara may support its invasive potential and formation of dense monospecies stands.
Tritordeum: Creating a New Crop Species—The Successful Use of Plant Genetic Resources
Authors: Ávila Carmen M. , Rodríguez-Suárez Cristina , Atienza Sergio G.
Published: May 2021

Hexaploid tritordeum is the amphiploid derived from the cross between the wild barley Hordeum chilense and durum wheat. This paper reviews the main advances and achievements in the last two decades that led to the successful development of tritordeum as a new crop. In particular, we summarize the progress in breeding for agronomic performance, including the potential of tritordeum as a genetic bridge for wheat breeding; the impact of molecular markers in genetic studies and breeding; and the progress in quality and development of innovative food products. The success of tritordeum as a crop shows the importance of the effective utilization of plant genetic resources for the development of new innovative products for agriculture and industry. Considering that wild plant genetic resources have made possible the development of this new crop, the huge potential of more accessible resources, such as landraces conserved in gene banks, goes beyond being sources of resistance to biotic and abiotic stresses. In addition, the positive result of tritordeum also shows the importance of adequate commercialization strategies and demonstrative experiences aimed to integrate the whole food chain, from producers to end-point sellers, in order to develop new products for consumers.
Determining the Optimal Conditions for the Production by Supercritical CO2 of Biodegradable PLGA Foams for the Controlled Release of Rutin as a Medical Treatment
Authors: Valor Diego , Montes Antonio , Monteiro Marilia , García-Casas Ignacio , Pereyra Clara , Martínez de la Ossa Enrique
Published: May 2021

Poly(D,L,-lactide-co-glycolide) (PLGA) foam samples impregnated with rutin were successfully produced by supercritical foaming processes. A number of parameters such as pressure (80–200 bar), temperature (35–55 °C), depressurization rate (5–100 bar/min), ratio lactide:glycolide of the poly(D,L,-lactide-co-glycolide) (50:50 and 75:25) were studied to determine their effect on the expansion factor and on the glass transition temperature of the polymer foams and their consequences on the release profile of the rutin entrapped in them. The impregnated foams were characterized by scanning electron microscopy, differential scanning calorimetry, and mercury intrusion porosimetry. A greater impregnation of rutin into the polymer foam pores was observed as pressure was increased. The release of rutin in a phosphate buffer solution was investigated. The controlled release tests confirmed that the modification of certain variables would result in considerable differences in the drug release profiles. Thus, five-day drug release periods were achieved under high pressure and temperature while the depressurization rate remained low.
Novel Polyimide/Copper-Nickel Ferrite Composites with Tunable Magnetic and Dielectric Properties
Authors: Hamciuc Corneliu , Asandulesa Mihai , Hamciuc Elena , Roman Tiberiu , Olariu Marius Andrei , Pui Aurel
Published: May 2021

Heat-resistant magnetic polymer composites were prepared by incorporating cerium-doped copper-nickel ferrite particles, having the general formula Ni1-xCuxFe1.92Ce0.08O4 (x: 0.0, 0.3, 0.6, 1.0), into a polyimide matrix. The effects of particle type and concentration on the thermal, magnetic, and electrical properties of the resulting composites were investigated. The samples were characterized by FTIR, scanning electron microscopy, X-ray diffractometry, thermogravimetric analysis, differential scanning calorimetry, vibrating sample magnetometer, and broadband dielectric spectroscopy. The composites exhibited high thermal stability, having initial decomposition temperatures between 495 and 509 °C. Saturation magnetization (Ms), magnetic remanence (Mr), and coercivity (Hc) were found in range of 2.37–10.90 emu g−1, 0.45–2.84 emu g−1, and 32–244 Oe, respectively. The study of dielectric properties revealed dielectric constant values of 3.0–4.3 and low dielectric losses of 0.016–0.197 at room temperature and a frequency of 1 Hz.
Polymeric Dopant-Free Hole Transporting Materials for Perovskite Solar Cells: Structures and Concepts towards Better Performances
Authors: Desoky Mohamed M. H. , Bonomo Matteo , Barbero Nadia , Viscardi Guido , Barolo Claudia , Quagliotto Pierluigi
Published: May 2021

Perovskite solar cells are a hot topic of photovoltaic research, reaching, in few years, an impressive efficiency (25.5%), but their long-term stability still needs to be addressed for industrial production. One of the most sizeable reasons for instability is the doping of the Hole Transporting Material (HTM), being the salt commonly employed as a vector bringing moisture in contact with perovskite film and destroying it. With this respect, the research focused on new and stable “dopant-free” HTMs, which are inherently conductive, being able to effectively work without any addition of dopants. Notwithstanding, they show impressive efficiency and stability results. The dopant-free polymers, often made of alternated donor and acceptor cores, have properties, namely the filming ability, the molecular weight tunability, the stacking and packing peculiarities, and high hole mobility in absence of any dopant, that make them very attractive and a real innovation in the field. In this review, we tried our best to collect all the dopant-free polymeric HTMs known so far in the perovskite solar cells field, providing a brief historical introduction, followed by the classification and analysis of the polymeric structures, based on their building blocks, trying to find structure–activity relationships whenever possible. The research is still increasing and a very simple polymer (PFDT–2F–COOH) approaches PCE = 22% while some more complex ones overcome 22%, up to 22.41% (PPY2).
Interlayer Adhesion Analysis of 3D-Printed Continuous Carbon Fibre-Reinforced Composites
Authors: Kuncius Tomas , Rimašauskas Marius , Rimašauskienė Rūta
Published: May 2021

Carbon fibre-reinforced materials are becoming more and more popular in various fields of industries because of their lightweight and perfect mechanical properties. Additive manufacturing technologies can be used for the production of complex parts from various materials including composites. Fused deposition modelling (FDM) is an excellent technology for the production of composite structures reinforced with short or continuous carbon fibre. In this study, modified FDM technology was used for the production of composites reinforced with continuous carbon fibre. The main aim of this study is to evaluate the shear strength of 3D-printed composite structures. The influence of printing layer height and line width on shear strength was analysed. Results showed that layer height has a significant influence on shear strength, while the influence of printing line width on shear strength is slightly smaller. Reduction of layer height from 0.4 mm to 0.3 mm allows increasing shear strength by about 40 percent. Moreover, the influence of the shear area and overlap length on shear force showed linear dependency, in which the shear area is increasing the shear force increasing proportionally. Finally, the results obtained can be used for the design and development of new 3D-printed composite structures.
Interfacial Compatibility on the Crystal Transformation of Isotactic Poly (1-Butene)/Herb Residue Composite
Authors: Wang Bo , Mao Shuangdan , Lin Fuhua , Zhang Mi , Zhao Yuying , Zheng Xiuhong , Wang Hui , Luo Jun
Published: May 2021

Isotactic poly (1-butene) (iPB) has excellent properties which are recognized as a green and energy saving product. However, the most stable and valuable crystal form I had a spontaneous transformation that took as long as seven days to complete. As a special solid waste, the herb residue (HR) is rich in cellulose which has great potential to accelerate the crystal transformation of the iPB. However, the polarity of HR results in the interface compatibility with non-polar iPB. In this study, the HR was modified by silane coupling agent (KH570) to obtain KHR and the iPB/HR composite was prepared. The FTIR spectrum was indicated that the organic functional groups of KH570 successfully graft onto the surface of HR and the water contact angle test was indicated that the hydrophilicity of the KHR was greatly decreased. The complete crystal transformation time is 7 days for iPB, 6 days for iPB+5% HR but only 3 days for iPB+5% KHR. The addition of the HR and KHR improve the thermal stability of the composite and this beneficial effect is more obvious for KHR. After annealing for 5 days, the physical properties value include tensile strength, flexural strength, and HDT of iPB+5% HR reach that of pure iPB after annealing for 7 days, but only 3 days for iPB+5% KHR. The TG analysis and SEM photographs give clear evidence that the beneficial effect of KH570 modified HR on improving the interface compatibility with iPB.
Influence of Fillers and Ionic Liquids on the Crosslinking and Performance of Natural Rubber Biocomposites
Authors: Maciejewska Magdalena , Sowińska Anna
Published: May 2021

This work concerns the effect of fillers and ionic liquids on the cure characteristics of natural rubber (NR) compounds, as well as the mechanical and thermal properties of the vulcanizates. Three types of white filler were applied, such as cellulose, nanosized silica and hydrotalcite, to modify the performance of NR composites. Additionally, ionic liquids (ILs) with bromide anion and different cations, i.e., 1-butyl-3-methylimidazolium (Bmi) and 1-butyl-3-methylpyrrolidinium (Bmpyr), were used to improve the cure characteristics of NR compounds and functional properties of the vulcanizates. The type of filler and the structure of ILs were proved to affect the rheometric properties and cure characteristics of NR compounds as well as the performance of the NR vulcanizates. Owing to the adsorption of curatives onto the surface, silica reduced the activity of the crosslinking system, prolonging the optimal vulcanization time of NR compounds and reducing the crosslinking degree of the elastomer. However, silica-filled NR exhibited the highest thermal stability. Hydrotalcite increased the crosslink density and, consequently, the mechanical properties of the vulcanizates, but deteriorated their thermal stability. ILs beneficially influenced the cure characteristics of NR compounds, as well as the crosslink density and mechanical performance of the vulcanizates, particularly those filled with silica. Cellulose did not significantly affect the vulcanization of NR compounds and crosslink density of the vulcanizates compared to the unfilled elastomer, but deteriorated their tensile strength. On the other hand, cellulose improved the thermal stability and did not considerably alter the damping properties of the vulcanizates.
Analysis of the Storage Stability Property of Carbon Nanotube/Recycled Polyethylene-Modified Asphalt Using Molecular Dynamics Simulations
Authors: Yu Caihua , Hu Kui , Yang Qilin , Wang Dandan , Zhang Wengang , Chen Guixiang , Kapyelata Chileshe
Published: May 2021

Carbon nanotubes (CNTs) can improve the storage properties of modified asphalt by enhancing the interfacial adhesion of recycled polyethylene (RPE) and base asphalt. In this study, the interaction of CNT/RPE asphalt was investigated using molecular dynamics simulation. The base asphalt was examined using a 12-component molecular model and verified by assessing the following properties: its four-component content, elemental contents, radial distribution function (RDF) and glass transition temperature. Then, the adhesion properties at the interface of the CNT/RPE-modified asphalt molecules were studied by measuring binding energy. The molecular structural stability of CNTs at the interface between RPE and asphalt molecules was analyzed through the relative concentration distribution. The motion of molecules in the modified asphalt was studied in terms of the mean square displacement (MSD) and diffusion coefficient. The results showed that CNTs improved the binding energy between RPE and base asphalt. CNTs not only weakened the repulsion of RPE with asphaltenes and resins, but also promoted the interaction of RPE with light components, which facilitated the compatibility of RPE with the base asphalt. The change in the interaction affected the molecular motion, and the molecular diffusion coefficient in the CNT/RPE-modified asphalt system was significantly smaller than that of RPE-modified asphalt. Moreover, the distribution of the asphaltene component was promoted by CNTs, resulting in the enhancement of the storage stability of RPE-modified asphalt. The property indexes indicated that the storage stability was significantly improved by CNTs, and better viscoelastic properties were also observed. Our research provides a foundation for the application of RPE in pavement engineering.
UV Polymerization of Methacrylates—Preparation and Properties of Novel Copolymers
Authors: Worzakowska Marta
Published: May 2021

More environmentally friendly polymeric materials for use in corrosive conditions were obtained in the process of UV polymerization of terpene methacrylate monomers: geranyl methacrylate and citronellyl methacrylate and the commercially available monomer methyl methacrylate. Selected properties (solvent resistance, chemical resistance, glass transition temperature, thermal stability, and decomposition course during heating) were evaluated. It was found that the properties of the materials directly depended on the monomer percentage and the conditioning temperatures used. An increase in the geranyl or citronellyl methacrylate monomer content in the copolymers reduced the solubility and chemical resistance of the materials post-cured at 50 °C. The samples post-cured at 120 °C were characterized by high resistance to polar and non-polar solvents and the chemical environment, regardless of the percentage composition. The glass transition temperatures for samples conditioned at 120 °C increased with increasing content of methyl methacrylate in the copolymers. The thermal stability of copolymers depended on the conditioning temperatures used. It was greater than 200 °C for most copolymers post-cured at 120 °C. The process of pyrolysis of copolymers led to the emission of geranyl methacrylate, citronellyl methacrylate, and methyl methacrylate monomers as the main pyrolysis volatiles.
Marginal Adaptation and Micropermeability of Class II Cavities Restored with Three Different Types of Resin Composites—A Comparative Ten-Month In Vitro Study
Authors: Yantcheva Sevda Mihailova
Published: May 2021

The development of composite materials is subject to the desire to overcome polymerization shrinkage and generated polymerization stress. An indicator characterizing the properties of restorative materials, with specific importance for preventing secondary caries, is the integrity and durability of marginal sealing. It is a reflection of the effects of polymerization shrinkage and generated stress. The present study aimed to evaluate and correlate marginal integrity and micropermeability in second-class cavities restored with three different types of composites, representing different strategies to reduce polymerization shrinkage and stress: nanocomposite, silorane, and bulk-fill composite after a ten-month ageing period. Thirty standardized class ΙΙ cavities were prepared on extracted human molars. Gingival margins were 1 mm apical to the cementoenamel junction. Cavities were randomly divided into three groups, based on the composites used: FiltekUltimate-nanocomposite; Filtek Silorane LS-silorane; SonicFill-bulk-fill composite. All specimens were subjected to thermal cycles after that, dipped in saline for 10-mounds. After ageing, samples were immersed in a 2% methylene blue. Thus prepared, they were covered directly with gold and analyzed on SEM for assessment of marginal seal. When the SEM analysis was completed, the teeth were included into epoxy blocks and cut longitudinally on three slices for each cavity. An assessment of microleakage on stereomicroscope followed. Results were statistically analyzed. For marginal seal evaluation: F.Ultimate and F.Silorane differ statistically with more excellent results than SonicFill for marginal adaptation to the gingival margin, located entirely in the dentin. For microleakage evaluation: F.Ultimate and F.Silorane differ statistically with less microleakage than SonicFill. Based on the results obtained: a strong correlation is found between excellent results for marginal adaptation to the marginal gingival ridge and micropermeability at the direction to the axial wall. We observe a more significant influence of time at the gingival margin of the cavities. There is a significant increase in the presence of marginal fissures (p = 0.001). A significant impact of time (p < 0.000) and of the material (p < 0.000) was found in the analysis of the microleakage.
Manufacturing and Characterisation of Polymeric Membranes for Water Treatment and Numerical Investigation of Mechanics of Nanocomposite Membranes
Authors: Acarer Seren , Pir İnci , Tüfekci Mertol , Türkoğlu Demirkol Güler , Tüfekci Neşe
Published: May 2021

In this study, polyethersulfone (PES) and polyvinylidene fluoride (PVDF) microfiltration membranes containing polyvinylpyrrolidone (PVP) with and without support layers of 130 and 150 μm thickness are manufactured using the phase inversion method and then experimentally characterised. For the characterisation of membranes, Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and pore size analysis are performed, the contact angle and water content of membranes are measured and the tensile test is applied to membranes without support layers. Using the results obtained from the tensile tests, the mechanical properties of the halloysite nanotube (HNT) and nano-silicon dioxide (nano SiO2) reinforced nanocomposite membranes are approximately determined by the Mori–Tanaka homogenisation method without applying any further mechanical tests. Then, plain polymeric and PES and PVDF based nanocomposite membranes are modelled using the finite element method to determine the effect of the geometry of the membrane on the mechanical behaviour for fifteen different geometries. The modelled membranes compared in terms of three different criteria: equivalent stress (von Mises), displacement, and in-plane principal strain. Based on the data obtained from the characterisation part of the study and the numerical analysis, the membrane with the best performance is determined. The most appropriate shape and material for a membrane for water treatment is specified as a 1% HNT doped PVDF based elliptical membrane.
Development of Bioinspired Functional Chitosan/Cellulose Nanofiber 3D Hydrogel Constructs by 3D Printing for Application in the Engineering of Mechanically Demanding Tissues
Authors: Kamdem Tamo Arnaud , Doench Ingo , Walter Lukas , Montembault Alexandra , Sudre Guillaume , David Laurent , Morales-Helguera Aliuska , Selig Mischa , Rolauffs Bernd , Bernstein Anke , Hoenders Daniel , Walther Andreas , Osorio-Madrazo Anayancy
Published: May 2021

Soft tissues are commonly fiber-reinforced hydrogel composite structures, distinguishable from hard tissues by their low mineral and high water content. In this work, we proposed the development of 3D printed hydrogel constructs of the biopolymers chitosan (CHI) and cellulose nanofibers (CNFs), both without any chemical modification, which processing did not incorporate any chemical crosslinking. The unique mechanical properties of native cellulose nanofibers offer new strategies for the design of environmentally friendly high mechanical performance composites. In the here proposed 3D printed bioinspired CNF-filled CHI hydrogel biomaterials, the chitosan serves as a biocompatible matrix promoting cell growth with balanced hydrophilic properties, while the CNFs provide mechanical reinforcement to the CHI-based hydrogel. By means of extrusion-based printing (EBB), the design and development of 3D functional hydrogel scaffolds was achieved by using low concentrations of chitosan (2.0–3.0% (w/v)) and cellulose nanofibers (0.2–0.4% (w/v)). CHI/CNF printed hydrogels with good mechanical performance (Young’s modulus 3.0 MPa, stress at break 1.5 MPa, and strain at break 75%), anisotropic microstructure and suitable biological response, were achieved. The CHI/CNF composition and processing parameters were optimized in terms of 3D printability, resolution, and quality of the constructs (microstructure and mechanical properties), resulting in good cell viability. This work allows expanding the library of the so far used biopolymer compositions for 3D printing of mechanically performant hydrogel constructs, purely based in the natural polymers chitosan and cellulose, offering new perspectives in the engineering of mechanically demanding hydrogel tissues like intervertebral disc (IVD), cartilage, meniscus, among others.
Functional Properties of Antimicrobial Neem Leaves Extract Based Macroalgae Biofilms for Potential Use as Active Dry Packaging Applications
Authors: Oyekanmi A. A. , Kumar U. Seeta Uthaya , H. P. S. Abdul Khalil , Olaiya N. G. , Amirul A. A. , Rahman A. A. , Nuryawan Arif , Abdullah C. K. , Rizal Samsul
Published: May 2021

Antimicrobial irradiated seaweed–neem biocomposite films were synthesized in this study. The storage functional properties of the films were investigated. Characterization of the prepared films was conducted using SEM, FT-IR, contact angle, and antimicrobial test. The macroscopic and microscopic including the analysis of the functional group and the gas chromatography-mass spectrometry test revealed the main active constituents present in the neem extract, which was used an essential component of the fabricated films. Neem leaves’ extracts with 5% w/w concentration were incorporated into the matrix of seaweed biopolymer and the seaweed–neem bio-composite film were irradiated with different dosages of gamma radiation (0.5, 1, 1.5, and 2 kGy). The tensile, thermal, and the antimicrobial properties of the films were studied. The results revealed that the irradiated films exhibited improved functional properties compared to the control film at 1.5 kGy radiation dosage. The tensile strength, tensile modulus, and toughness exhibited by the films increased, while the elongation of the irradiated bio-composite film decreased compared to the control film. The morphology of the irradiated films demonstrated a smoother surface compared to the control and provided surface intermolecular interaction of the neem–seaweed matrix. The film indicated an optimum storage stability under ambient conditions and demonstrated no significant changes in the visual appearance. However, an increase in the moisture content was exhibited by the film, and the hydrophobic properties was retained until nine months of the storage period. The study of the films antimicrobial activities against Staphylococcus aureus (SA), and Bacillus subtilis (BS) indicated improved resistance to bacterial activities after the incorporation of neem leaves extract and gamma irradiation. The fabricated irradiated seaweed–neem bio-composite film could be used as an excellent sustainable packaging material due to its effective storage stability.
Effect of Core Architecture on Charpy Impact and Compression Properties of Tufted Sandwich Structural Composites
Authors: Chen Chen , Wang Peng , Legrand Xavier
Published: May 2021

This study presents a novel sandwich structure that replaces the polypropylene (PP) foam core with a carbon fiber non-woven material in the tufting process and the liquid resin infusion (LRI) process. An experimental investigation was conducted into the flatwise compression properties and Charpy impact resistance of sandwich composites. The obtained results validate an enhancement to the mechanical properties due to the non-woven core and tufting yarns. Compared to samples with a pure foam core and samples without tufting threads, the compressive strength increased by 45% and 86%, respectively. The sample with a non-woven layer and tufting yarns had the highest Charpy absorbed energy (23.85 Kj/m2), which is approximately 66% higher than the samples without a non-woven layer and 90% higher than the samples without tufting yarns. Due to the buckling of the resin cylinders in the Z-direction that occurred in all of the different sandwich samples during the compression test, the classical buckling theory was adopted to analyze the differences between the results. The specific properties of the weight gains are discussed in this paper. The results show that the core layers have a negative effect on impact resistance. Nevertheless, the addition of tufting yarns presents an obvious benefit to all of the specific properties.
Thermally Activated Delayed Fluorescence in Commercially Available Materials for Solution-Process Exciplex OLEDs
Authors: Tseng Zong-Liang , Huang Wei-Lun , Yeh Tzu-Hung , Xu You-Xun , Chiang Chih-Hsun
Published: May 2021

Organic light-emitting diodes (OLEDs) have developed rapidly in recent years. Thermally activated delayed fluorescent (TADF) molecules open a path to increase exciton collection efficiency from 25% to 100%, and the solution process provides an alternative technology to achieve lower cost OLEDs more easily. To develop commercial materials as exciplex hosts for high-performance and solution-processed OLEDs, we attempted to use 4,4′-cyclohexylidenebis[N,N-bis(4-methylphenyl)benzenamine (TAPC), poly(9-vinylcarbazole) (PVK), N,N′-Di(1-naphthyl)-N,N′-diphenyl-(1,1′-biphenyl)-4,4′-diamine (NPB), and poly(N,N’-bis-4-butylphenyl-N,N’-bisphenyl)benzidine (Poly-TPD) as the donors and 2,4,6-tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazine (POT2T) as the acceptor to obtain the TADF effect. All donors and the acceptor were purchased from chemical suppliers. Our work shows that excellent TADF properties and high-efficiency exciplex OLEDs with low turn-on voltage and high luminance can be achieved with a simple combination of commercial materials.
Orthodox Christian Bulgarians Coping with Natural Disasters in the Pre-Modern Ottoman Balkans
Authors: Detrez Raymond
Published: May 2021

Premodern Ottoman society consisted of four major religious communities—Muslims, Orthodox Christians, Armenian Christians, and Jews; the Muslim and Christian communities also included various ethnic groups, as did Muslim Arabs and Turks, Orthodox Christian Bulgarians, Greeks, and Serbs who identified, in the first place, with their religious community and considered ethnic identity of secondary importance. Having lived together, albeit segregated within the borders of the Ottoman Empire, for centuries, Bulgarians and Turks to a large extent shared the same world view and moral value system and tended to react in a like manner to various events. The Bulgarian attitudes to natural disasters, on which this contribution focuses, apparently did not differ essentially from that of their Turkish neighbors. Both proceeded from the basic idea of God’s providence lying behind these disasters. In spite of the (overwhelmingly Western) perception of Muslims being passive and fatalistic, the problem whether it was permitted to attempt to escape “God’s wrath” was coped with in a similar way as well. However, in addition to a comparable religious mental make-up, social circumstances and administrative measures determining equally the life conditions of both religious communities seem to provide a more plausible explanation for these similarities than cross-cultural influences.
Enhancement of a District Heating Substation as Part of a Low-Investment Optimization Strategy for District Heating Systems
Authors: Vannahme Anna , Ehrenwirth Mathias , Schrag Tobias
Published: May 2021

In an ongoing project, low-investment measures for the optimization of district heating systems are analyzed. The optimization strategies are collected in a catalog, which is the core of a guideline. The application of this guideline is demonstrated using two concrete district heating networks as examples. In this study, the improvement of an analog controlled district heating substation by an electronic controller is investigated. High supply temperatures and heat losses are often a challenge in district heating networks. The district heating substations have a major influence on the network return temperatures. The comparison of the two substation setups with analog and electronic controllers is carried out by laboratory measurement. It can be shown that the return temperatures can be reduced by an average of 20 K in winter and transition, as well as 16 K in summer. The district heating network losses are calculated for one of both specific district heating networks. They are calculated from the ratio of network losses to generated energy. The generated energy is the sum of network losses and consumer demand. The thermal losses of the network can be reduced by 3%. The volume flow in the heating network can be reduced to a quarter. Therefore, the pumping energy requirement drops sharply since these changes cubically affect the volume flow.
Environmental Transformation and the Current State of Hydrogeological Condition in the Wojkowice Area—Southern Poland
Authors: Różkowski Jacek , Rahmonov Oimahmad , Zarychta Roksana , Zarychta Adrian
Published: May 2021

Based on the analysis and interpretation of maps, remote sensing data published in the literature, and environmental reconnaissance, this article discusses environmental transformations in the Wojkowice area in southern Poland (up to the year 2020). A comprehensive analysis was carried out concerning spatial development, mining activity, hydrogeological conditions and the biotic environment. The current state of the hydrogeological conditions was also characterized. Mining activity in the vicinity of the studied town caused significant changes in its relief, which contributed to its area dropping by about 5 m. In fact, these terrain forms are overgrown by various forms of vegetation that colonized these areas both naturally and as a result of forest reclamation. The contemporary vegetation of Wojkowice differs from the potential natural vegetation, which is an indicator of the complete anthropogenization of the natural environment. Over 100 years of industrial activity in Wojkowice has also contributed to a strong transformation of the groundwater. There has been a quantitative depletion of usable groundwater in the Triassic and Carboniferous formations. With inflows to the ore mines of up to 17 m3/min, the groundwater table has dropped by more than 60 m. The aquifer of Muschelkalk has been practically drained. At present, wells extract the waters from the Röth aquifer. There has been a major transformation of groundwater chemistry. The waters of the Triassic carbonate complex are anthropogenically transformated and are characterized by increased mineralization, multi-ionic types and usually with a quality class III and IV, and, therefore, they require some treatment.
Remote Sensing Monitoring of Advancing and Surging Glaciers in the Tien Shan, 1990–2019
Authors: Zhou Sugang , Yao Xiaojun , Zhang Dahong , Zhang Yuan , Liu Shiyin , Min Yufang
Published: May 2021

The advancing of glaciers is a manifestation of dynamic glacial instability. Glaciers in the Tien Shan region, especially in the Central Tien Shan, show instability, and advancing glaciers have been recently detected. In this study, we used Landsat TM/ETM+/OLI remote sensing images to identify glaciers in the Tien Shan region from 1990 to 2019 and found that 48 glaciers advanced. Among them, thirty-four glaciers exhibited terminal advances, and 14 glaciers experienced advances on the tributary or trunk. Ten of the glaciers experiencing terminal advances have been identified as surging glaciers. These 48 glaciers are distributed in the western part of the Halik and Kungey Mountain Ranges in the Central Tien Shan, and Fergana Mountains in the Western Tien Shan, indicating that the Tien Shan is also one of the regions where advancing and surging glaciers are active. From 1990 to 2019, a total of 169 times advances occurred on 34 terminal advancing glaciers in the Tien Shan region; the highest number of advancing and surging of glaciers occurred in July (26 and 14 times, respectively). With reference to the existing literature and the present study, the surge cycle in the Tien Shan is longer than that in other regions at high latitudes in Asia, lasting about 35–60 years. Surging glaciers in the Tien Shan region may be affected by a combination of thermal and hydrological control. An increase in temperature and precipitation drives surging glaciers, but the change mechanism is still difficult to explain based on changes in a single climate variable, such as temperature or precipitation.
Spatial Analyses and Susceptibility Modeling of Thermokarst Lakes in Permafrost Landscapes along the Qinghai–Tibet Engineering Corridor
Authors: Yin Guoan , Luo Jing , Niu Fujun , Zhou Fujun , Meng Xianglian , Lin Zhanju , Liu Minghao
Published: May 2021

Thermokarst lakes (TLs) caused by the thaw of massive ground ice in ice-rich permafrost landscapes are increasing and have strong impacts on the hydro–ecological environment and human infrastructure on the Qinghai–Tibet Plateau (QTP), however, its spatial distribution characteristics and environmental controls have not been underrepresented at the local scale. Here, we analyzed the spatial distribution of small TLs along the Qinghai–Tibet Engineering Corridor (QTEC) based on high-resolution (up to 2.0 m) satellite images. The TLs gathered in the plains and upland plateau and covered 8.3% of the QTEC land. We deployed a random-frost method to investigate the suitable environmental conditions for TLs. Climate including summer rainfall and the air temperature was the most important factor controlling the TL distribution, followed by topography and soil characteristics that affected the ground ice content. TL susceptibility was mapped based on the combinations of climate, soil, and topography grid data. On average, around 20% of the QTEC area was in a high to very-high-susceptibility zone that is likely to develop TLs in response to climate change. This study improved the understanding of controlling factors for TL development but also provided insights into the conditions of massive ground ice and was helpful to assess the impacts of climate change on ecosystem processes and engineering design.