bluuebunny/crossref_metadata_2025 huggingface dataset:
Holocene trends in the foraminifer record from the Norwegian Sea and the North Atlantic Ocean
Authors: Andersson C. , Pausata F. S. R. , Jansen E. , Risebrobakken B. , Telford R. J.
Published: April 2010

Abstract. The early to mid-Holocene thermal optimum is a well-known feature in a wide variety of paleoclimate archives from the Northern Hemisphere. Reconstructed summer temperature anomalies from across northern Europe show a clear maximum around 6 ka. For the marine realm, Holocene trends in sea-surface temperature reconstructions for the North Atlantic and Norwegian Sea do not exhibit a consistent pattern of early to mid-Holocene warmth. Sea-surface temperature records based on alkenones and diatoms generally show the existence of a warm early to mid-Holocene optimum. In contrast, several foraminifer and radiolarian based temperature records from the North Atlantic and Norwegian Sea show a cool mid-Holocene anomaly and a trend towards warmer temperatures in the late Holocene. In this paper, we revisit the foraminifer record from the Vøring Plateau in the Norwegian Sea. We also compare this record with published foraminifer based temperature reconstructions from the North Atlantic and with modelled (CCSM3) upper ocean temperatures. Model results indicate that while the seasonal summer warming of the sea-surface was stronger during the mid-Holocene, sub-surface depths experienced a cooling. This hydrographic setting can explain the discrepancies between the Holocene trends exhibited by phytoplankton and zooplankton based temperature proxy records.
Simulation of the last glacial cycle with a coupled climate ice-sheet model of intermediate complexity
Authors: Ganopolski A. , Calov R. , Claussen M.
Published: April 2010

Abstract. A new version of the Earth system model of intermediate complexity, CLIMBER-2, which includes the three-dimensional polythermal ice-sheet model SICOPOLIS, is used to simulate the last glacial cycle forced by variations of the Earth's orbital parameters and atmospheric concentration of major greenhouse gases. The climate and ice-sheet components of the model are coupled bi-directionally through a physically based surface energy and mass-balance interface. The model accounts for the time-dependent effect of aeolian dust on planetary and snow albedo. The model successfully simulates the temporal and spatial dynamics of the major Northern Hemisphere (NH) ice sheets, including rapid glacial inception, strong asymmetry between the ice-sheet growth phase and glacial termination. Spatial extent and elevation of the ice sheets during the last glacial maximum agree reasonably well with palaeoclimate reconstructions. A suite of sensitivity experiments demonstrates that simulated ice-sheet evolution during the last glacial cycle is very sensitive to some parameters of the surface energy and mass-balance interface and dust module. The possibility of a considerable acceleration of the climate ice-sheet model is discussed.
Interhemispheric coupling and warm Antarctic interglacials
Authors: Holden P. B. , Edwards N. R. , Wolff E. W. , Lang N. J. , Singarayer J. S. , Valdes P. J. , Stocker T. F.
Published: April 2010

Abstract. Ice core evidence indicates that even though atmospheric CO2 concentrations did not exceed ~300 ppm at any point during the last 800 000 years, East Antarctica was at least ~3–4 °C warmer than pre-industrial (CO2 ~280 ppm) in each of the last four interglacials. During the previous three interglacials, this anomalous warming was short lived (~3 000 years) and apparently occurred before the completion of Northern Hemisphere deglaciation. Hereafter, we refer to these periods as "Warmer than Present Transients" (WPTs). We here present transient 800 kyr simulations using the intermediate complexity model GENIE-1 which suggest that WPTs could be explained as a consequence of the meltwater-forced slowdown of the Atlantic Meridional Overturning Circulation (AMOC) during glacial terminations. It is well known that a slowed AMOC would increase southern Sea Surface Temperature (SST) through the bipolar seesaw. Observational data supports this hypothesis, suggesting that the AMOC remained weak throughout the terminations preceding WPTs, strengthening rapidly at a time which coincides closely with peak Antarctic temperature. In order to investigate model and boundary condition uncertainty, we additionally present three ensembles of transient GENIE-1 simulations across Termination II (135 000 to 124 000 BP) and three snapshot HadCM3 simulations at 130 000 Before Present (BP). These simulations together reproduce both the timing and magnitude of WPTs, and point to the potential importance of an albedo feedback associated with West Antarctic Ice Sheet (WAIS) retreat.
Vegetation response to the African Humid Period termination in central Cameroon (7° N) – new pollen insight from Lake Mbalang
Authors: Vincens A. , Buchet G. , Servant M. ,   ECOFIT Mbalang collaborators
Published: April 2010

Abstract. A new pollen sequence from the Lake Mbalang (7°19' N, 13°44' E, 1110 m a.s.l.) located on the eastern Adamawa plateau, in central Cameroon, is presented in this paper to analyze the Holocene African Humid Period (AHP) termination and related vegetation changes at 7° N in tropical Africa, a region where any data are today available. This sequence, spanning the last 7000 cal. yr BP, shows that the vegetation response to this transitional climatic episode was neither abrupt nor really gradual. Forest degradation in this area is initially registered as early as 6100 cal. yr BP and modern savanna was definitely established at 3000 cal. yr BP and stabilized at 2400 cal. yr BP; but a slight forest regeneration episode is observed between 5200 and 4200 cal. yr BP. Moreover, in this area with modern high rainfall, increasing in the length of the dry season during the AHP termination, from 6100 cal. yr BP onward, has primarily controlled vegetation dynamics and above all the disappearance of a forested environment on the Adamawa plateau. Compared to previous studies undertaken in northern tropical and central Africa, this work clearly shows that the response of vegetation to transitional episodes between climatic extremes such as the AHP termination might be different in timing, mode and amplitude according to the regional climate and hydrology of the study sites, but also according to the stability of vegetation before and during these climatic transitions.
Mechanisms and time scales of glacial inception simulated with an Earth system model of intermediate complexity
Authors: Calov R. , Ganopolski A. , Kubatzki C. , Claussen M.
Published: April 2010

Abstract. We investigate glacial inception and glacial thresholds in the climate-cryosphere system utilising the Earth system model of intermediate complexity CLIMBER-2, which includes modules for atmosphere, terrestrial vegetation, ocean and interactive ice sheets. The latter are described by the three-dimensional polythermal ice-sheet model SICOPOLIS. A bifurcation which represents glacial inception is analysed with two different model setups: one setup with dynamical ice-sheet model and another setup without it. The respective glacial thresholds differ in terms of maximum boreal summer insolation at 65° N (hereafter referred as Milankovich forcing (MF)). The glacial threshold of the configuration without ice-sheet dynamics corresponds to a much lower value of the MF compared to the full model. If MF attains values only slightly below the aforementioned threshold there is fast transient response. Depending on the value of MF relative to the glacial threshold, the transient response time of inland-ice volume in the model configuration with ice-sheet dynamics ranges from 10 000 to 100 000 years. We investigate implications of these time scales for past glacial inceptions and for the overdue Holocene glaciation hypothesis by Ruddiman (W. F. Ruddiman, Climatic Change 2003, Vol. 61, 261–293). We also have shown that the asynchronous coupling between climate and inland-ice components allows one sufficient realistic simulation of glacial inception and, at the same time, a considerable reduction of computational costs.
Extracting a common high frequency signal from northern Quebec black spruce tree-rings with a Bayesian hierarchical model
Authors: Boreux J.-J. , Naveau P. , Guin O. , Perreault L. , Bernier J.
Published: April 2010

Abstract. Dendrochronology, the scientific dating method based on the analysis of tree-ring growth patterns, has been frequently applied in climatology. The basic premise of dendroclimatology is that tree rings can be viewed as climate proxies, i.e. rings are assumed to contain some hidden information about past climate. From a statistical perspective, this extraction problem can be understood as the search of a hidden variable which represents the common signal within a collection of tree-ring width series. Classical average-based techniques used in dendrochronology have been, with different degrees of success (depending on tree species, regional factors and statistical methods), applied to estimate the mean behavior of this latent variable. Still, a precise quantification of uncertainties associated to the hidden variable distribution is difficult to assess. To model the error propagation throughout the extraction procedure, we propose and study a Bayesian hierarchical model that focuses on extracting an inter-annual high frequency signal. Our method is applied to black spruce (Picea mariana) tree-rings recorded in northern Quebec and compared to a classical average-based techniques used by dendrochronologists.
Simulated effects of a seasonal precipitation change on the vegetation in tropical Africa
Authors: Cassignat C. , Gritti E. S. , Flores O. , Bonnefille R. , Chalié F. , Guiot J. , Jolly D.
Published: April 2010

Abstract. Pollen data collected in Africa at high (Kuruyange, valley swamp, Burundi) and low altitude (Lake Victoria; Ngamakala, pond, Congo) showed that after 6 ky Before Present (BP), pollen of deciduous trees increase their relative percentage, thus suggesting the beginning of a drier climate and/or an increase of the dry season length. Until now, pollen-climate transfer functions only investigated mean annual precipitation, hence omitting the potential effect of a change in precipitation seasonality. In the present study, we use an equilibrium biosphere model (i.e. BIOME3.5) to estimate the sensitivity of equatorial African vegetation to such changes, at specific sites. Climatic scenarios, differing only by the monthly distribution of the current annual amount of precipitations, are tested at the above three locations in equatorial Africa. Soil nature, monthly temperatures and cloudiness are kept constant at their present day values. A good agreement is shown between model simulations and current biomes assemblages, as reconstructed from pollen data. To date, the increase of the deciduous forest component in the palaeodata around 6 ky has been interpreted as the beginning of the drier climate period. However, our results demonstrate that a seasonal change of the precipitation distribution should likely induce such reconstructed changes toward drier vegetation types. This study confirms the necessity of taking into account seasonal changes in the hydrological balance when palaeoecologists wish to reconstruct vegetation composition or to infer quantitative climate parameters, such as temperature and precipitation, from pollen or vegetation proxy.
Characteristics of cold-warm variation in the Hetao region and its surrounding areas in China during the past 5000 yr
Authors: Li M. , Ge Q. , Hao Z. , Zheng J. , He S.
Published: April 2010

Abstract. Using six long-term temperature proxy data series derived from different natural evidences, including pollens and lake-sediments, we reconstructed a temperature series with a 100-year time resolution for the past 5000 yr in the Hetao region and its surrounding areas. The resulting series suggests that, on a millennial timescale, temperatures in the region were higher than the mean value of the whole series during the 5000~2600 yr before present (yr BP) period, and became relatively low comparing with the average temperature of the whole series after 2600 yr BP. Within these two periods, temperature fluctuations comprising numerous short, multi-centennial intervals also existed. A comparison between our reconstructed series and other series in China and across the Northern Hemisphere indicate that, on a long-term scale, cold–warm variations had been in phase across the whole hemisphere during the past 5000 yr; on the century to multi-century scale, the beginning and the ending times varied from region to region, thus implying that climate changes did not occur simultaneously in different regions.
Glacial cycles: exogenous orbital changes vs. endogenous climate dynamics
Authors: Kaufmann R. K. , Juselius K.
Published: April 2010

Abstract. We use a statistical model, the cointegrated vector autoregressive model, to assess the degree to which variations in Earth's orbit and endogenous climate dynamics can be used to simulate glacial cycles during the late Quaternary (390 kyr–present). To do so, we estimate models of varying complexity and compare the accuracy of their in-sample simulations. Results indicate that strong statistical associations between endogenous climate variables are not enough for statistical models to reproduce glacial cycles. Rather, changes in solar insolation associated with changes in Earth's orbit are needed to simulate glacial cycles accurately. Also, results suggest that non-linear dynamics, threshold effects, and/or free oscillations may not play an overriding role in glacial cycles.
Coral Cd/Ca and Mn/Ca records of El Niño variability in the Gulf of California
Authors: Carriquiry J. D. , Villaescusa J. A.
Published: April 2010

Abstract. We analyzed the trace element ratios Cd/Ca and Mn/Ca in three coral colonies (Pavona gigantea, Pavona clivosa and Porites panamensis) from Cabo Pulmo reef, Southern Gulf of California, Mexico, to assess the oceanographic changes caused by El Niño – Southern Oscillation (ENSO) events in the Eastern Tropical North Pacific (ETNP). The interannual variations in the coral Cd/Ca and Mn/Ca ratios show clear evidence that incorporation of Cd and Mn in the coral skeleton are influenced by ENSO conditions, but the response for each metal is controlled by different process. The Mn/Ca ratios were significantly higher during ENSO years (p<0.05) relative to non-ENSO years for the three species of coral. In contrast, the Cd/Ca was systematically lower during ENSO years, but it was significant (p<0.05) only in P. gigantea. The decrease in the incorporation of Cd, and the marked increase in Mn during the mature phase of El Niño indicate strongly reduced vertical mixing in the Gulf of California. The oceanic warming during El Niño events produces a relaxation of upwelling and a stabilization of the thermocline which acts as a physical barrier limiting the transport of Cd from deeper waters into the surface layer. In turn, this oceanic condition can increase the residence time of particulate-Mn in surface waters, which in turn increases the photo-reduction of particulate-Mn and the release of the available Mn into the dissolved phase. These results provide validation for using Mn/Ca and Cd/Ca in biogenic carbonates as tracers of changes in ocean stratification and trade wind weakening and/or collapse in the ETNP during ENSO episodes.
Impact of brine-induced stratification on the glacial carbon cycle
Authors: Bouttes N. , Paillard D. , Roche D. M.
Published: April 2010

Abstract. During the cold period of the Last Glacial Maximum (LGM, about 21 000 years ago) atmospheric CO2 was around 190 ppm (Monnin et al., 2001), much lower than the pre-industrial concentration of 280 ppm. The causes of this substantial drop remain partially unresolved, despite intense research. Understanding the origin of reduced atmospheric CO2 during glacial times is crucial to comprehend the evolution of the different carbon reservoirs within the Earth system (atmosphere, terrestrial biosphere and ocean). In this context, the ocean is believed to play a major role as it can store large amounts of carbon (Sigman and Boyle, 2000), especially in the abyss, which is a carbon reservoir that is thought to have expanded during glacial times. To create this larger reservoir, one possible mechanism is to produce very dense glacial waters, thereby stratifying the deep ocean and reducing the carbon exchange between the deep and surface ocean (Paillard and Parrenin, 2004). The existence of such very dense waters has been inferred in the LGM deep Atlantic from sediment pore water salinity (Adkins et al., 2002). Based on these observations, we study the impact of a brine mechanism on the glacial carbon cycle. This mechanism relies on the formation and rapid sinking of brines, very salty water released during sea ice formation, which brings salty dense water down to the bottom of the ocean. It provides two major features: a direct link from the surface to the deep ocean along with an efficient way of setting a strong stratification. We show with the CLIMBER-2 coupled carbon-climate model (Petoukhov et al., 2000) that such a brine mechanism can account for a significant decrease in atmospheric CO2 and contribute to the glacial-interglacial change. This mechanism can be amplified by low vertical diffusion resulting from the brine-induced stratification. The results obtained substantially improve the modeled glacial distribution of oceanic δ13C as well as the deep ocean salinity in line with reconstructions from sediment cores (Curry and Oppo, 2005; Adkins et al., 2002), suggesting that such a mechanism could have played an important role during glacial times.
Modeling of RO/NF membrane rejections of PhACs and organic compounds: a statistical analysis
Authors: Yangali-Quintanilla V. , Kim T.-U. , Kennedy M. , Amy G.
Published: April 2010

Abstract. Rejections of pharmaceutical compounds (Ibuprofen, Diclofenac, Clofibric acid, Naproxen, Primidone, Phenacetin) and organic compounds (Dichloroacetic acid, Trichloroacetic acid, Chloroform, Bromoform, Trichloroethene, Perchloroethene, Carbontetrachloride, Carbontetrabromide) by NF (Filmtec, Saehan) and RO (Filmtec, Saehan, Toray, Koch) membranes were studied. Chloroform presented the lowest rejection due to small molar volume, equivalent width and length. Diclofenac and Primidone showed high rejections related to high molar volume and length. Dichloroacetic acid and Trichloroacetic acid presented good rejections caused by charge exclusion instead of steric hindrance mechanism influencing rejection. Bromoform and Trichloroethene showed low rejections due to small length and equivalent width. Carbontetrabromide, Perchloroethene and Carbontetrachloride with higher equivalent width than BF and TCE presented better rejections. A qualitative analysis of variables using Principal Component Analysis was successfully implemented for reduction of physical-chemical compound properties that influence membrane rejection of PhACs and organic compounds. Properties such as dipole moment, molar volume, hydrophobicity/hydrophilicity, molecular length and equivalent width were found to be important descriptors for simulation of membrane rejection. For membranes used in the experiments, we may conclude that charge repulsion was an important mechanism of rejection for ionic compounds. After analysis with Multiple Linear Regression, we also may conclude that membrane rejection of neutral compounds was well predicted by molar volume, length, equivalent width, hydrophobicity/hydrophilicity and dipole moment. Molecular weight was a poor descriptor variable for rejection modelling. We were able to provide acceptable statistical significance for important results.
Hydraulic modelling of drinking water treatment plant operations
Authors: Worm G. I. M. , Mesman G. A. M. , van Schagen K. M. , Borger K. J. , Rietveld L. C.
Published: April 2010

Abstract. The flow through a unit of a drinking water treatment plant is one of the most important parameters in terms of a unit's effectiveness. In the present paper, a new EPAnet library is presented with the typical hydraulic elements for drinking water treatment processes well abstraction, rapid sand filtration and cascade and tower aeration. Using this treatment step library, a hydraulic model was set up, calibrated and validated for the drinking water treatment plant Harderbroek. With the actual valve position and pump speeds, the flows were calculated through the several treatment steps. A case shows the use of the model to calculate the new setpoints for the current frequency converters of the effluent pumps during a filter backwash.
Micro-components survey of residential indoor water consumption in Chiang Mai
Authors: Otaki Y. , Otaki M. , Pengchai P. , Ohta Y. , Aramaki T.
Published: April 2010

Abstract. The direct measurement of the micro-components of water consumption (i.e., consumption by each residential activity, such as toilet, laundry, bath, and kitchen) both in the dry season and in the rainy season was conducted in Chiang Mai, Thailand. It was expected that rainfall differences between the dry and rainy season could influence awareness for water resources so that water consumption in the dry season may be smaller than that in the rainy season. It was also examined that whether the differences in water resources such as public waterworks or non-public waterworks like community waterworks, mountainous water and groundwater, affect the water use amount. A small-sized accumulative water meter was developed for measurement. This survey can provide the important information for water demand estimation and water supply planning in middle-developed countries where their water consumption should be expected to increase from here on.
Removal of both dissolved and particulate iron from groundwater
Authors: Teunissen K. , Abrahamse A. , Leijssen H. , Rietveld L. , van Dijk H.
Published: April 2010

Abstract. Iron is the primary source for discolouration problems in the drinking water distribution system. The removal of iron from groundwater is a common treatment step in the production of drinking water. Even when clear water meets the drinking water standards, the water quality in the distribution system can deteriorate due to settling of iron (hydroxide) particles or post-treatment flocculation of dissolved iron. Therefore it is important to remove dissolved and particulate iron to a large extent. This paper describes the study towards the current iron removal processes and experimental work towards improving removal of dissolved and particulate iron. The study was carried out at groundwater treatment plant Harderbroek, consisting of aeration, rapid sand filtration and tower aeration. The research contains two parts: 1) a particle fingerprint of the treatment, resulting in a quantification of particles breaking through the rapid sand filtration. 2) Small column experiments on the oxidation and filterability of iron. The fingerprint showed that operational events such as switching on/off of filters and backwashing have a significant impact on the volume concentration of particles breaking through the filter. A frequency plot of the different size ranges of particles indicates that mainly the filterability of the middle size ranges (2–7 μm) of particles was influenced by switching a filter on/off. A backwash event mainly affects the bigger particle size ranges. The column experiments showed that in the cascade effluent the majority of the iron is dissolved iron(II), indicating that the oxidation of iron(II) to iron(III) is the rate determining step at Harderbroek, which is limited by pH. Dosing caustic soda resulted in a significant increase of the oxidation rate and improved the removal of iron(II) in the column. Crushed limestone filtration gave promising results, but the contact time applied was too short to completely oxidize iron(II).
Water quality and treatment of river bank filtrate
Authors: de Vet W. W. J. M. , van Genuchten C. C. A. , van Loosdrecht M. C. M. , van Dijk J. C.
Published: April 2010

Abstract. In drinking water production, river bank filtration has the advantages of dampening peak concentrations of many dissolved components, substantially removing many micropollutants and removing, virtually completely, the pathogens and suspended solids. The production aquifer is not only fed by the river bank infiltrate but also by water percolating through covering layers. In the polder areas, these top layers consist of peat and deposits from river sediments and sea intrusions. This paper discusses the origin and fate of macro pollutants in river bank filtrate, based on extensive full-scale measurements in well fields and treatment systems of the Drinking Water Company Oasen in the Netherlands. First, it clarifies and illustrates redox reactions and the mixing of river bank filtrate and polder water as the dominant processes determining the raw water quality for drinking water production. Next, full-scale results are elaborated on to evaluate trickling filtration as an efficient and proven one-step process to remove methane, iron, ammonium and manganese. The interaction of methane and manganese removal with nitrification in these systems is further analyzed. Methane is mostly stripped during trickling filtration and its removal hardly interferes with nitrification. Under specific conditions, microbial manganese removal may play a dominant role.
NOM removal technologies – Norwegian experiences
Authors: Ødegaard H. , Østerhus S. , Melin E. , Eikebrokk B.
Published: April 2010

Abstract. The paper gives an overview of the methods for removal of natural organic matter (NOM), particularly humic substances (HS), in water with focus on the Norwegian experiences. It is demonstrated that humic substances may be removed by a variety of methods, such as; molecular sieving through nanofiltration membranes, coagulation with subsequent floc separation (including granular media or membrane filtration), oxidation followed by biofiltration and sorption processes including chemisorption (ion exchange) and physical adsorption (activated carbon). All these processes are in use in Norway and the paper gives an overview of the operational experiences.
Optimized conditions for application of organic flocculant aids in water purification
Authors: Polasek P.
Published: April 2010

Abstract. The application of organic flocculant aid (OFA) to a system undergoing aggregation has a direct effect on the quality of purified water as well as the settleability of resultant agglomerates. The optimum conditions for OFA application exist when the formation of aggregates by means of destabilisation (aggregation – CPE) reagent reaches flocculation optimum, i.e. the measure of flocculation γ=1, prior to OFA addition. Such method of OFA application is called the Post-Orthokinetic Agglomeration (POA) process. The POA process results in the formation of the fastest settleable agglomerates and the best quality of purified water matching that attainable without the use of OFA. Recirculation of the sludge conditioned by OFA back to the process of particle aggregation was found undesirable as it adversely affects the purified water quality as well as the settleability of produced agglomerates.
Assessing the internal consistency of the CARINA database in the Indian sector of the Southern Ocean
Authors: Lo Monaco C. , Álvarez M. , Key R. M. , Lin X. , Tanhua T. , Tilbrook B. , Bakker D. C. E. , van Heuven S. , Hoppema M. , Metzl N. , Ríos A. F. , Sabine C. L. , Velo A.
Published: April 2010

Abstract. Carbon and carbon-relevant hydrographic and hydrochemical ancillary data from previously not publicly available cruises were retrieved and recently merged to a new data base, CARINA (CARbon IN the Atlantic). The initial North Atlantic project, an international effort for ocean carbon synthesis, was extended to include the Arctic Mediterranean Seas (Arctic Ocean and Nordic Seas) and all three sectors of the Southern Ocean. Of a total of 188 cruises, 37 cruises are part of the Southern Ocean. The present work focuses on data collected in the Indian sector (20° S–70° S; 30° E–150° E). The Southern Indian Ocean dataset covers the period 1992–2004 and includes seasonal repeated observations. Parameters including salinity, dissolved inorganic carbon (TCO2), total alkalinity (TA), oxygen, nitrate, phosphate and silicate were examined for cruise-to-cruise and overall consistency. In addition, data from an existing, quality controlled data base (GLODAP) were introduced in the CARINA analysis to improve data coverage in the Southern Ocean. A global inversion was performed to synthesize the information deduced from objective comparisons of deep measurements (>1500 m) at nearby stations (generally <220 km). The corrections suggested by the inversion were allowed to vary within a fixed envelope, thus accounting for ocean interior variability. The adjustments applied to CARINA data and those recommended for GLODAP data, in order to obtain a consistent merged dataset, are presented and discussed. The final outcome of this effort is a new quality controlled data base for TCO2 and other properties of the carbon system that can now be used to investigate the natural variability or stability of ocean chemistry and the accumulation of anthropogenic carbon. This data product also offers an important new synthesis of seasonal to decadal observations to validate ocean biogeochemical models in a region where available historical data were very sparse.
CARINA alkalinity data in the Atlantic Ocean
Authors: Velo A. , Perez F. F. , Brown P. , Tanhua T. , Schuster U. , Key R. M.
Published: April 2010

Abstract. Data on carbon and carbon-relevant hydrographic and hydrochemical parameters from previously non-publicly available cruise data sets in the Arctic, Atlantic and Southern Ocean have been retrieved and merged to a new database: CARINA (CARbon IN the Atlantic). These data have gone through rigorous quality control (QC) procedures to assure the highest possible quality and consistency. The data for most of the measured parameters in the CARINA data base were objectively examined in order to quantify systematic differences in the reported values, i.e. secondary quality control. Systematic biases found in the data have been corrected in the data products, i.e. three merged data files with measured, calculated and interpolated data for each of the three CARINA regions; Arctic, Atlantic and Southern Ocean. Out of a total of 188 cruise entries in the CARINA database, 98 were conducted in the Atlantic Ocean and of these, 75 cruises report alkalinity values. Here we present details of the secondary QC on alkalinity for the Atlantic Ocean part of CARINA. Procedures of quality control, including crossover analysis between cruises and inversion analysis of all crossover data are briefly described. Adjustments were applied to the alkalinity values for 16 of the cruises in the Atlantic Ocean region. With these adjustments the CARINA database is consistent both internally as well as with GLODAP data, an oceanographic data set based on the World Hydrographic Program in the 1990s. Based on our analysis we estimate the internal accuracy of the CARINA-ATL alkalinity data to be 3.3 μmol kg−1. The CARINA data are now suitable for accurate assessments of, for example, oceanic carbon inventories and uptake rates and for model validation.
Atlantic Ocean CARINA data: overview and salinity adjustments
Authors: Tanhua T. , Steinfeldt R. , Key R. M. , Brown P. , Gruber N. , Wanninkhof R. , Perez F. , Körtzinger A. , Velo A. , Schuster U. , van Heuven S. , Bullister J. L. , Stendardo I. , Hoppema M. , Olsen A. , Kozyr A. , Pierrot D. , Schirnick C. , Wallace D. W. R.
Published: April 2010

Abstract. Water column data of carbon and carbon-relevant hydrographic and hydrochemical parameters from 188 previously non-publicly available cruise data sets in the Arctic, Atlantic and Southern Ocean have been retrieved and merged into a new database: CARINA (CARbon IN the Atlantic). The data have gone through rigorous quality control procedures to assure the highest possible quality and consistency. The data for the pertinent parameters in the CARINA database were objectively examined in order to quantify systematic differences in the reported values, i.e. secondary quality control. Systematic biases found in the data have been corrected in the data products, i.e. three merged data files with measured, calculated and interpolated data for each of the three CARINA regions, i.e. Arctic, Atlantic and Southern Ocean. Ninety-eight of the cruises in the CARINA database were conducted in the Atlantic Ocean, defined here as the region south of the Greenland-Iceland-Scotland Ridge and north of about 30° S. Here we present an overview of the Atlantic Ocean synthesis of the CARINA data and the adjustments that were applied to the data product. We also report details of the secondary QC for salinity for this data set. Procedures of quality control – including crossover analysis between stations and inversion analysis of all crossover data – are briefly described. Adjustments to salinity measurements were applied to the data from 10 cruises in the Atlantic Ocean region. Based on our analysis we estimate the internal accuracy of the CARINA-ATL salinity data to be 4.1 ppm. With these adjustments the CARINA database is consistent both internally as well as with GLODAP data, an oceanographic data set based on the World Hydrographic Program in the 1990s (Key et al., 2004), and is now suitable for accurate assessments of, for example, oceanic carbon inventories and uptake rates and for model validation.
Atlantic CFC data in CARINA
Authors: Steinfeldt R. , Tanhua T. , Bullister J. L. , Key R. M. , Rhein M. , Köhler J.
Published: April 2010

Abstract. Water column data of carbon and carbon-relevant parameters have been collected and merged into a new database called CARINA (CARbon IN the Atlantic). In order to provide a consistent data set, all data have been examined for systematic biases and adjusted if necessary (secondary quality control (QC)). The CARINA data set is divided into three regions: the Arctic/Nordic Seas, the Atlantic region and the Southern Ocean. Here we present the CFC data for the Atlantic region, including the chlorofluorocarbons CFC-11, CFC-12 and CFC-113 as well as carbon tetrachloride (CCl4). The methods applied for the secondary quality control, a crossover analyses, the investigation of CFC ratios in the ocean and the CFC surface saturation are presented. Bases on the results, the CFC data of some cruises are adjusted by a certain factor or given a "poor" quality flag.
Nordic Seas and Arctic Ocean CFC data in CARINA
Authors: Jeansson E. , Olsson K. A. , Tanhua T. , Bullister J. L.
Published: April 2010

Abstract. Water column data of carbon and carbon relevant hydrographic and hydrochemical parameters from 188 previously non-publicly available cruises in the Arctic, Atlantic, and Southern Ocean have been retrieved and merged into a new database: CARINA (CARbon IN the Atlantic). The data have been subject to rigorous quality control (QC) in order to ensure highest possible quality and consistency. The data for most of the parameters included were examined in order to quantify systematic biases in the reported values, i.e. secondary quality control. Significant biases have been corrected for in the data products, i.e. the three merged files with measured, calculated and interpolated values for each of the three CARINA regions; the Arctic Mediterranean Seas (AMS), the Atlantic (ATL) and the Southern Ocean (SO). The Arctic Mediterranean Seas is comprised of the Arctic Ocean and the Nordic Seas, and the quality control was carried out separately in these two areas. Here we present an overview of the QC of the CFC data for the Arctic Mediterranean Seas, including the chlorofluorocarbons CFC-11, CFC-12 and CFC-113, as well as carbon tetrachloride (CCl4). For the secondary QC of the CFCs we used a combination of tools, including the evaluation of depth profiles and CFC ratios, surface saturations and a crossover analysis. This resulted in a multiplicative adjustment of some cruise data, while some other cruises were flagged with questionable quality, which excluded them from the final data product.
EPOCA/EUR-OCEANS data-mining compilation on the impacts of ocean acidification
Authors: Nisumaa A.-M. , Pesant S. , Bellerby R. G. J. , Delille B. , Middelburg J. , Orr J. C. , Riebesell U. , Tyrrell T. , Wolf-Gladrow D. , Gattuso J.-P.
Published: April 2010

Abstract. The uptake of anthropogenic CO2 by the oceans has led to a rise in the oceanic partial pressure of CO2, and to a decrease in pH and carbonate ion concentration. This modification of the marine carbonate system is referred to as ocean acidification. Numerous papers report the effects of ocean acidification on marine organisms and communities but few have provided details concerning full carbonate chemistry and complementary observations. Additionally, carbonate system variables are often reported in different units, calculated using different sets of dissociation constants and on different pH scales. Hence the direct comparison of experimental results has been problematic and often misleading. The need was identified to (1) gather data on carbonate chemistry, biological and biogeochemical properties, and other ancillary data from published experimental data, (2) transform the information into common framework, and (3) make data freely available. The present paper is the outcome of an effort to integrate ocean carbonate chemistry data from the literature which has been supported by the European Network of Excellence for Ocean Ecosystems Analysis (EUR-OCEANS) and the European Project on Ocean Acidification (EPOCA). A total of 166 papers were identified, 86 contained enough information to readily compute carbonate chemistry variables, and 67 datasets were archived at PANGAEA – The Publishing Network for Geoscientific & Environmental Data. This data compilation is regularly updated as an ongoing mission of EPOCA. Data access: http://doi.pangaea.de/10.1594/PANGAEA.735138
NORPERM, the Norwegian Permafrost Database – a TSP NORWAY IPY legacy
Authors: Juliussen H. , Christiansen H. H. , Strand G. S. , Iversen S. , Midttømme K. , Rønning J. S.
Published: April 2010

Abstract. NORPERM – The Norwegian Permafrost Database was developed at the Geological Survey of Norway during the International Polar Year (IPY) 2007–2009 as the main data legacy of the IPY research project Permafrost Observatory Project: A Contribution to the Thermal State of Permafrost in Norway and Svalbard (TSP NORWAY). This paper describes the structural and technical design of NORPERM. NORPERM follows the IPY data policy of open, free, full and timely release of IPY data, and the borehole metadata description follows the Global Terrestrial Network for Permafrost (GTN-P) standard. The ground temperature data infrastructure in Norway and Svalbard is also presented, focussing on the TSP NORWAY permafrost observatory installations in the North Scandinavian Permafrost Observatory and Nordenskiöld Land Permafrost Observatory, as the data providers for NORPERM. Further developments of the database, possibly towards a regional database for the Nordic area, are also discussed. The purpose of NORPERM is to store ground temperature data safely and in a standard format for use in future research. NORPERM stores temperature time series from various depths in boreholes and from the air, snow cover, ground-surface or upper ground layer recorded by miniature temperature data-loggers, and temperature profiles with depth in boreholes obtained by occasional manual logging. It contains all the temperature data from the TSP NORWAY research project, totalling 32 boreholes and 98 sites with miniature temperature data-loggers for continuous monitoring of micrometeorological conditions, and 6 temperature depth profiles obtained by manual borehole logging. The amount of data in the database will gradually increase as data from older, previous projects are added. NORPERM also provides links to near real-time permafrost temperatures obtained by GSM data transfer.
Measuring hydrodynamics and sediment transport processes in the Dee estuary
Authors: Bolaños R. , Souza A.
Published: April 2010

Abstract. The capability of monitoring and predicting the marine environment leads to a more sustainable development of coastal and offshore regions. Therefore, the continuous measurement of environmental processes become an important source of information. The present paper shows data collected during 6 years, and in particular during 2008, in the Dee Estuary. The data aims to improve the observations of the mobile sediments in coastal areas and its forcing hydrodynamics and turbulence. Data involves the deployment of instrumented rigs measuring sediment in suspension, currents, waves, sea level, sediment size and bedforms as well as cruise work including grab sampling, CTD profiles and side-scan sonar. The data covers flood and ebb tides during spring and neap periods with moderate and mild wave events, thus, having a good coverage of the processes needed to improve knowledge of sediment transport and the parameterizations used in numerical modelling. The data, in raw and treated, is being banked at BODC (British Oceanographic Data Centre, http://www.bodc.ac.uk/) which is the formal British organization for looking after and distributing data concerning the marine environment.
LANL* V1.0: a radiation belt drift shell model suitable for real-time and reanalysis applications
Authors: Koller J. , Reeves G. D. , Friedel R. H. W.
Published: April 2010

Abstract. We describe here a new method for calculating the magnetic drift invariant, L*, that is used for modeling radiation belt dynamics and for other space weather applications. L* (pronounced L-star) is directly proportional to the integral of the magnetic flux contained within the surface defined by a charged particle moving in the Earth's geomagnetic field. Under adiabatic changes to the geomagnetic field L* is a conserved quantity, while under quasi-adiabatic fluctuations diffusion (with respect to a particle's L*) is the primary term in equations of particle dynamics. In particular the equations of motion for the very energetic particles that populate the Earth's radiation belts are most commonly expressed by diffusion in three dimensions: L*, energy (or momentum), and pitch angle (the dot product of velocity and the magnetic field vector). Expressing dynamics in these coordinates reduces the dimensionality of the problem by referencing the particle distribution functions to values at the magnetic equatorial point of a magnetic "drift shell" (or L-shell) irrespective of local time (or longitude). While the use of L* aids in simplifying the equations of motion, practical applications such as space weather forecasting using realistic geomagnetic fields require sophisticated magnetic field models that, in turn, require computationally intensive numerical integration. Typically a single L* calculation can require on the order of 105 calls to a magnetic field model and each point in the simulation domain and each calculated pitch angle has a different value of L*. We describe here the development and validation of a neural network surrogate model for calculating L* in sophisticated geomagnetic field models with a high degree of fidelity at computational speeds that are millions of times faster than direct numerical field line mapping and integration. This new surrogate model has applications to real-time radiation belt forecasting, analysis of data sets involving tens of satellite-years of observations, and other problems in space weather.
Simulation of land surface temperatures: comparison of two climate models and satellite retrievals
Authors: Edwards J. M.
Published: April 2010

Abstract. Recently there has been significant progress in the retrieval of land surface temperature from satellite observations. Satellite retrievals of surface temperature offer several advantages, including broad spatial coverage, and such data are potentially of great value in assessing general circulation models of the atmosphere. Here, retrievals of the land surface temperature over the contiguous United States are compared with simulations from two climate models. It is found that these two models generally simulate the diurnal range of surface temperature realistically, but show significant warm biases during the summer. The models' diurnal cycle of surface temperature is related to their surface flux budgets. Differences in the diurnal cycle of the surface flux budget between the models are found to be more pronounced than those in the diurnal cycle of surface temperature.
ECHMERIT V1.0 – a new global fully coupled mercury-chemistry and transport model
Authors: Jung G. , Hedgecock I. M. , Pirrone N.
Published: April 2010

Abstract. Mercury is a global pollutant due to its long lifetime in the atmosphere. Its hemispheric transport patterns and eventual deposition are therefore of major concern. For the purpose of global atmospheric mercury chemistry and transport modelling the ECHMERIT model was developed. ECHMERIT, based on the global circulation model ECHAM5 differs from most global mercury models in that the emissions, chemistry (including general tropospheric chemistry and mercury chemistry), transport and deposition are coupled on-line to the GCM. The chemistry mechanism includes an online calculation of photolysis rate constants using the Fast-J photolysis mechanism, the CBM-Z tropospheric gas-phase mechanism and aqueous-phase chemistry based on the MECCA mechanism. Additionally, a mercury chemistry mechanism that incorporates gas and aqueous phase mercury chemistry is included. A detailed description of the model, including the wet and dry deposition modules, and the implemented emissions is given in this technical report. First model testing and evaluation show a satisfactory model performance for surface ozone and mercury mixing ratios (with a mean bias of 1.46 nmol/mol for ozone and a mean bias of 13.55 fmol/mol for TGM when compared with EMEP station data). Requirements regarding measurement data and emission inventories which could considerably improve model skill are discussed.
Simplified aerosol modeling for variational data assimilation
Authors: Huneeus N. , Boucher O. , Chevallier F.
Published: April 2010

Abstract. We have developed a simplified aerosol model together with its tangent linear and adjoint versions for the ultimate aim of optimizing global aerosol and aerosol precursor emission using variational data assimilation. The model was derived from the general circulation model LMDz; it groups together the 24 aerosol species simulated in LMDz into 4 species, namely gaseous precursors, fine mode aerosols, coarse mode desert dust and coarse mode sea salt. The emissions have been kept as in the original model. Modifications, however, were introduced in the computation of aerosol optical depth and in the processes of sedimentation, dry and wet deposition and sulphur chemistry to ensure consistency with the new set of species and their composition. The simplified model successfully manages to reproduce the main features of the aerosol distribution in LMDz. The largest differences in aerosol load are observed for fine mode aerosols and gaseous precursors. Differences between the original and simplified models are mainly associated to the new deposition and sedimentation velocities consistent with the definition of species in the simplified model and the simplification of the sulphur chemistry. Furthermore, simulated aerosol optical depth remains within the variability of monthly AERONET observations for all aerosol types and all sites throughout most of the year. Largest differences are observed over sites with strong desert dust influence. In terms of the daily aerosol variability, the model is less able to reproduce the observed variability from the AERONET data with larger discrepancies in stations affected by industrial aerosols. The simplified model however, closely follows the daily simulation from LMDz. Sensitivity analyses with the tangent linear version show that the simplified sulphur chemistry is the dominant process responsible for the strong non-linearity of the model.