bluuebunny/crossref_metadata_2025 huggingface dataset:
Music Teacher Online: Problems and Solutions
Authors: Карасева М.В.
Published: April 2022

В работе сделан социально-психологический анализ первого этапа перехода на онлайн-обучение в период пандемии COVID-19 весной 2020 года, дается оценка перспектив развития музыкального онлайн-образования с разных позиций. На основе изучения, отбора и апробации автором оптимальных для проведения онлайн-занятий устройств записи и передачи звука и видео сделан обзор основного оборудования и приемов работы с ним как для педагога, так и для ученика— с позиции нужд музыкального обучения и в пределах бюджетного ценового сегмента. Даны практические рекомендации, как организовать занятия в режиме онлайн по сольфеджио и другим предметам музыкально-теоретического цикла, а также некоторые общие советы относительно проведения занятий по музыкально-исполнительским дисциплинам.

This paper contains a socio-psychological analysis of the first steps in e-learning during the COVID-19 virus pandemic in spring of 2020. An assessment of the prospects for the development of on-line music education from different perspectives is presented. Based on the author’s study and testing the recording and transmission devices the most convenient devices and software for musical e-classes have been chosen by the author. An overview of the basis equipment and methodology for working with them is made for the teacher as well as for the student from the standpoint of the music education needs and within the budget price segment. Recommendations on organizing solfeggio classes and other subjects of the musical-theoretical cycle are given, as well as some general tips on conducting classes in music performing disciplines.
“Pastorale” by Beethoven: Between a Musical Portrait of Nature and Symphonic “Psychedelia”
Authors: Коробова А.Г.
Published: April 2022

Статья посвящена рассмотрению Шестой симфонии Бетховена в контексте традиций пасторальной инструментальной музыки и — шире — жанра европейской пасторали, проявившей себя практически во всех видах и родах музыки. Основное внимание направлено на пересечение ретроспективных и перспективных парадигм жанра, что позволяет объемнее высветить феномен «Пасторальной». Для репрезентативности исторического сравнения автор использует обобщенную схему «вчера — сегодня — завтра», помещая в её центр опуса венского классика. Данная схема мыслится не механически как необратимый вектор времени, а скорее типологически, когда «вчера» может присутствовать в «сегодня» и даже в «завтра». Данная схема помогает акцентировать значимые моменты в контрапункте таких линий, определяющих жанровую «текстуру» произведения Бетховена, как старая традиция рождественской пасторали, «натурализованная» георгика эпохи Просвещения, характеристическая инструментальная музыка с происходящей в ней модуляцией от риторического изображения природы к ее чувственно‑эмоциональному переживанию. Подчеркивается значение «Пасторальной симфонии» Бетховена в последующей истории — и как образца жанра, и как побуждающей к культурному диалогу этико‑философской концепции («Фантастическая симфония» Г. Берлиоза), и как узнаваемого музыкального топоса классической пасторали, утраченной дисгармоничным миром посмодернистской эпохи («Симфония» Л. Берио).

The article is devoted to the consideration of Beethoven’s Sixth Symphony in the context of the traditions of pastoral instrumental music and, more broadly, the genre of European pastoral, which manifested itself in almost all types and kinds of music. The main focus is on the intersection of retrospective and prospective paradigms of the genre, which makes it possible to highlight the “Pastoral” phenomenon in more detail. For the representativity of historical comparison, the author uses the generalized scheme “yesterday — today — tomorrow”, placing the opus by Vienna Classic in its center. This scheme is not thought of mechanically as an irreversible vector of time, but rather typologically, when “yesterday” can be present in “today” and even “tomorrow”. This scheme helps to accentuate significant moments in the counterpoint of such lines defining the genre “texture” of Beethoven’s work as the old tradition of the Christmas pastoral, the “naturalized” georgics of the Enlightenment, characteristic instrumental music with the transition occurring in it from a rhetorical depiction of nature to its sensory‑emotional experience. The significance of Beethoven’s “Pastoral Symphony” in subsequent history is emphasized — both as an example of a genre, and as an ethical‑philosophical concept stimulating a cultural dialogue (Symphonie Fantastique by H. Berlioz), and as a recognizable musical topos of a classical pastoral, lost by the disharmonious world of the postmodern era (Sinfonia by L. Berio).
From Beethoven to Martinů: Approaching the Problem of the Spiritual and Style Traditions in European Music
Authors: Гаврилова Н.А.
Published: April 2022

Классик чешской музыки ХХ века Богуслав Мартину создал свою стилевую концепцию в опоре на национальную и общеевропейскую традиции искусства; одной из отправных точек его творчества, содержащего прозрения в будущее, послужило наследие Людвига ван Бетховена, особенно его поздние произведения. Воздействие музыканта такого масштаба, как Бетховен, на творчество Богуслава Мартину в данной статье рассматривается в трех аспектах: героико-драматическая и лирико-жанровая концепции симфонизма как основа музыкальной драматургии; феномен позднего стиля; «звездное небо над нами и нравственный закон внутри нас» (Кант) как творческое кредо. Девятая симфония, вершинное достижение Бетховена-симфониста, обобщила основные идеи названных концепций и послужила ориентиром для музыкантов двух следующих столетий. Поздний стиль Бетховена стал предтечей стилевых реалий в искусстве XX века. В статье отмечаются черты преемственности с творчеством венского классика и вместе с тем новизна интерпретации классической модели в условиях искусства XX века.

The classic of Czech music of the 20th century Bohuslav Martinu created his own stylistic concept based on national and European art traditions. One of the starting points of his work, containing anticipations into the future, was the legacy of Ludwig van Beethoven, especially his late works. The influence of a musician of such a scale as Beethoven on the work of Bohuslav Martinů is considered in this article in three aspects: heroic-dramatic and lyric-genre concepts of symphony as the basis of musical drama; “The starry sky above us and the moral law within us” (Kant) as a creative Credo; phenomenon of late style. The Ninth Symphony, the summit achievement of Beethoven as a symphonist, summarized the main ideas of these concepts and served as a reference point for musicians for the next two centuries. Beethoven’s late style became the forerunner of stylistic realities in 20th-century musical art. The article notes the traits of continuity with the work of the Viennese classic and at the same time the novelty of the interpretation of the classical model in the art of the twentieth century.
M. P. Mussorgsky’s “Shamil”. Study and Reconstruction Effort
Authors: Виноградова А.С. , Лебедева-Емелина А.В.
Published: April 2022

В статье впервые представлено неизвестное сочинение Мусоргского для мужского хора и фортепиано (1859), названное В. Г. Каратыгиным «Маршем Шамиля». Даны характеристики автографа и музыкальной стилистики хора; выявлен обширный исторический контекст; на основе сохранившегося авторского клавира впервые реконструирован полный нотный текст (публикуется в Приложении к статье). Параллели с фрагментами оперы Ц. А. Кюи «Кавказский пленник» (1858) служат инструментом музыкально-исторического анализа сочинения Мусоргского. Составлена летопись творческих встреч формирующегося балакиревского кружка на фоне одновременно свершающихся событий политической жизни Российской Империи (победного окончания Кавказской войны и появления плененного имама Шамиля в Петербурге). Исследуются связи мелодики хора Мусоргского с ритуальными песнопениями (закирами-зикрами). Выдвигается предположение, что «Шамиль» был задуман автором в качестве варианта более крупного музыкально-драматического сочинения. Предлагается иное название — Хор свиты Шамиля.

Authors present for the first time the unknown Mussorgsky’s composition for the male choir and piano (1859), later called by V. G. Karatygin “Marsh Shamil”. The characteristics of the autograph and musical style of the choir are given; a vast historical context is revealed; on the basis of the surviving author’s piano score, the full musical text was reconstructed for the first time (published in the Appendix to this article). Parallels with fragments of Ts. A. Cui’s opera “The Prisoner of the Caucasus” (1858) serve as a tool for a musicalhistorical analysis of Mussorgsky’s work. A chronicle of meetings of the emerging Balakirev circle against the background of simultaneously occurring events in the political life of the Russian Empire (the victorious end of the Caucasian War and the appearance of the captive Imam Shamil in St. Petersburg) was compiled. The connections of the melody of the Mussorgsky choir with ritual chants (zakir-dhikrs) are investigated. It is suggested that “Shamil” was conceived by the author as a variant of a larger musical and dramatic composition. A different name is proposed — the Shamil Suite Choir.
The Riddle of Tchaikovsky’s Song (op. 60 № 5)
Authors: Моисеев Григорий Анатольевич
Published: April 2022

Двенадцать романсов ор. 60, посвященных императрице Марии Федоровне (1886), являются наиболее многосоставным камерно-вокальным опусом П. И. Чайковского. Особое место принадлежит в нем романсу № 5 «Простые слова». С одной стороны, он относится к группе сочинений, написанных Чайковским на свой собственный текст, и уже необычным названием привлекает к себе внимание. С другой - является редко исполняемым, малоизученным. При этом в научной литературе он получил разноречивые оценки: от острокритических до недоуменных. В сравнении с общеизвестными шедеврами этого опуса он блекнет, производя впечатление некого «вставного номера». Тем не менее он порождает ряд вопросов. К кому обращается «лирический герой»? От кого исходит обращение? Какова вообще его «тема»? Автор статьи предлагает свое прочтение. Аналитические наблюдения над словесным и музыкальным рядом заставляют предположить, что композитор работал в жанре музыкального портрета и изобразил императора Александра III. Это может дать ключ к новому пониманию не только данного романса, но и всего цикла ор. 60 как музыковедами, так и исполнителями. В приложении впервые публикуется авторизованная копия романса «Простые слова» из собрания Научной библиотеки Государственного Эрмитажа.

Twelve Romances, Op. 60 dedicated to Empress Maria Feodorovna (1886), is P. I. Tchaikovsky’s most multipart chamber vocal opus. No. 5 Simple Words occupies a special place in it. On the one hand, it belongs to a group of songs, for which Tchaikovsky used his own texts and is singled out by its unusual title. On the other, it is understudied and rarely performed. Furthermore, researchers assess it very differently: they either criticize it or find it perplexing. It pales in comparison with the famous masterpieces of this opus, making the impression of an inset piece. Nevertheless, it raises a number of questions. Who does the protagonist address? From whom does the appeal come? What is its subject? The author of this paper offers his own interpretation. His analysis of the text and the music suggests that in Simple Words Tchaikovsky depicted Emperor Alexander III in the genre of a musical portrait. This may provide clues to a new understanding of this song and of the entire Op. 60 cycle. An authorized copy of Simple Words from the collection of the State Hermitage Scientific Library is published in the Appendix for the first time.
Bridging the Gap between H- and J-Aggregates: Classification and Supramolecular Tunability for Excitonic Band Structures in 2-Dimensional Molecular Aggregates
Authors: Deshmukh Arundhati , Geue Niklas , Bradbury Nadine , Atallah Timothy , Chuang Chern , Pengshung Monica , Cao Jianshu , Sletten Ellen , Neuhauser Daniel , Caram Justin
Published: April 2022

Molecular aggregates with long-range excitonic couplings have drastically different photophysical properties compared to their monomer counterparts. From Kasha’s model for 1-dimensional systems, positive or negative excitonic couplings lead to blue or red shifted optical spectra with respect to the monomers, labelled H-and J-aggregates respectively. The overall excitonic couplings in higher dimensional systems are much more complicated and cannot be simply classified from their spectral shifts alone. Here, we provide a unified classification for extended 2D aggregates using temperature dependent peak shifts, thermal broadening and quantum yields. We discuss the examples of six 2D aggregates with J-like absorption spectra but quite drastic changes quantum yields and superradiance. We find the origin of the differences is, in fact, a different excitonic band structure where the bright state is lower energy than the monomer but still away from the band edge. We call this an ‘I-aggregate’. Our results provide a description of the complex excitonic behaviors that cannot be explained solely on Kasha’s model. Further, such properties can be tuned with the packing geometries within the aggregates providing supramolecular pathways for controlling them. This will allow for precise optimizations of aggregate properties in their applications across the areas of optoelectronics, photonics, excitonic energy transfer, and shortwave infrared technologies.
Structure-Activity Relationships of Antibody-Drug Conjugates: A Systematic Review of Chemistry on the Trastuzumab Scaffold
Authors: Matikonda Siddharth , Mclaughlin Ryan , Shrestha Pradeep , Lipshultz Carol , Schnermann Martin
Published: April 2022

Antibody-drug conjugates (ADCs) are a rapidly growing class of cancer therapeutics. The goal of ADCs is to overcome the low therapeutic index of conventional cytotoxic agents. However, realizing this goal has been a significant challenge. Consisting of an antibody linked to a therapeutic payload, ADCs comprise many components which can be modified, including the target, payload, linker, and bioconjugation method. Many approaches have been developed to improve the physical properties, potency, and selectivity of ADCs. The anti-HER-2 antibody trastuzumab, first approved in 1998, has emerged as an exceptional targeting agent for ADCs, as well as a broadly used platform for testing new technologies, The extensive work in this area enables the comparison of various linker strategies, payloads, drug-to-antibody ratios (DAR), and mode of attachment. In this review, these conjugates, ranging from the first clinically approved trastuzumab ADC, Kadcyla (T-DM1) to the latest variants, are described with the goal of providing a broad overview and comparison of existing and emerging conjugate technologies.
Severe Slugging Flow Identification from Topological Indicators
Authors: Casolo Simone
Published: April 2022

In this work, a topological data analysis pipeline was used to identify the onset of severe slug flow in offshore petroleum production systems. Severe slugging is a multiphase flow regime known to be very inefficient and potentially harmful to process equipment. Data from a pressure sensor located in wells is utilized to obtain topological indicators capable of revealing the occurrence of severe slugging. Signal data were processed by means of Takens embedding to produce point clouds, analyzed by persistent homology. Topological methods based on persistence diagrams are shown to be useful in identifying severe slugging and in classifying different flow regimes from pressure signals of producing wells with supervised machine learning.
Versatile biogenesis of Silver-Copper nanoparticles over arylated pulp sugarcane bagasse- derived biochar: high catalytic performance
Authors: Snoussi Youssef , Chehimi Mohamed M. , Ammar Souad , El Garah Mohamed , Khalil Ahmed M.
Published: April 2022

Agrowaste-derived materials for the supporting of nanocatalysts is attracting a great attention due to the abundance and the physicochemical features they provide as bio-sourced underlying materials. The main idea is built around the conversion of junk material into functional material, a journey of waste from "trash to treasure". Herein, we suggest a versatile method to elaborate phytochemically reduced Ag/Cu nanoparticles supported on aryl-sulfonated sugarcane bagasse pulp-derived biochar. Biochar was first prepared by a slow pyrolysis of the biomass at 500°C under N2:H2 95%:5% inert atmosphere. Thereafter, in-situ arylation of the biochar surface has been performed to obtain SO3H-biochar. Silver and copper ions loading in SO3H-biochar has been established via a wet impregnation in a hydroalcoholic medium. Finally, the natural liquid extract of sugarcane bagasse has been employed to reduce the metallic ions instead of the toxic NaBH4 very commonly used, the obtained SO3H-biochar@Ag/Cu has been characterized by XRD, XPS, SEM and RAMAN spectroscopy. The catalytic activity of the nanocomposite has been investigated in the oxidative degradation of malachite green oxalate. A total mineralization of the dye has been registered and the experimental data was found to give a relatively good fitting to the pseudo-first-order model with a mineralization apparent constant rate equals to 65 10-3 min-1.
Pretargeted Imaging Beyond the Blood-Brain-Barrier
Authors: Shalgunov Vladimir , Lopes van den Broek Sara Irence , Vang Andersen Ida , García Vázquez Rocío , Raval Nakul , Palner Mikael , Mori Yuki , Schäfer Gabriela , Mikula Hannes , Beschorner Natalie , Nedergaard Maiken , Syvänen Stina , Barz Matthias , Knudsen Gitte Moos , Battisti Umberto Maria , Herth Matthias
Published: April 2022

Pretargeting is a powerful nuclear imaging strategy to achieve enhanced imaging contrast for nanomedicines. It reduces the radiation burden to healthy tissue. Pretargeting is based on bioorthogonal chemistry. The most attractive reaction for this purpose is currently the tetrazine ligation, which occurs between trans-cyclooctene (TCO) tags and tetrazines (Tzs). Pretargeted imaging beyond the blood-brain-barrier (BBB) has not been reported thus far. In this study, we developed Tz imaging agents that are capable to ligate in vivo to targets beyond the BBB. We chose to develop 18F-labeled Tzs as they can be applied to positron emission tomography (PET) - the most powerful molecular imaging technology. Fluorine-18 is an ideal radionuclide for PET due to its almost ideal decay properties. Fluorine-18 also allows - as a non-metal radionuclide - to develop Tzs with physicochemical properties enabling passive brain diffusion. In order to develop these imaging agents, we applied a rational drug design approach. This approach was based on estimated and experimental determined parameters such as the BBB score, pretargeted autoradiography contrast, in vivo input and washout curves as well as on metabolism studies. From initially 18 developed structures, five Tzs were selected to be tested on their in vivo click performance. Whereas all selected structures clicked in vivo into the brain, [18F]18 displayed the most favorable characteristics with respect to brain pretargeting. [18F]18 is our lead compound for future pretargeted imaging studies based on BBB-penetrant monoclonal antibodies. Pretargeting beyond the BBB will allow us to image targets beyond the BBB that are currently not imageable. For example, soluble protein isoforms could be imaged. These proteins are valuable drug targets for several neurodegenerative diseases and can currently not be imaged. Imaging would allow for diagnosis of these diseases, identifying responders from non-responders or to monitor treatment. Consequently, imaging will provide valuable information to accelerate drug development and greatly benefit patient care.
An Open-Source Molecular Builder and Free Energy Preparation Workflow
Authors: Bieniek Mateusz , Cree Ben , Pirie Rachael , Horton Joshua , Tatum Natalie , Cole Daniel
Published: April 2022

Automated free energy calculations for the prediction of binding free energies of congeneric series of ligands to a protein target are growing in popularity, but building reliable initial binding poses for the ligands is challenging. Here, we introduce the open-source FEgrow workflow for building user-defined congeneric series of ligands in protein binding pockets for input to free energy calculations. For a given ligand core and receptor structure, FEgrow enumerates and optimises the bioactive conformations of the grown functional group(s), making use of hybrid machine learning / molecular mechanics potential energy functions where possible. Low energy structures are optionally scored using the gnina convolutional neural network scoring function, and output for more rigorous protein–ligand binding free energy predictions. We illustrate use of the workflow by building and scoring binding poses for ten congeneric series of ligands bound to targets from a standard, high quality dataset of protein–ligand complexes. Furthermore, we build a set of 13 inhibitors of the SARS-CoV-2 main protease from the literature, and use free energy calculations to retrospectively compute their relative binding free energies. FEgrow is freely available at https://github.com/cole- group/FEgrow, along with a tutorial.
Antimicrobial activities of hydrazones with a 2,4-dichloro moiety.
Authors: Babalola Sodeeq , Igie Nosakhare , Idris Abdullah , Hamza Asmau , Sanni Yenken , Muhammad Hayatudeen , Erumiseli Godwin , Bakare Lateef
Published: April 2022

The goal of this research was to come up with novel antibacterial agents. Two hydrazones with a 2,4-dichloro moiety were synthesized by conventional synthetic methods with good yields. The success of the synthesis was confirmed by structure determination techniques; FITR and NMR analyses. The synthesized hydrazones were evaluated for antimicrobial activity using strains of bacterial and fungi. The two hydrazones demonstrated significant antibacterial and antifungal activities that were comparable to those of ciprofloxacin and fluconazole, respectively. Specifically, compound 3b with a para nitro group on its aniline fragment indicated a broader spectrum of activity compared to compound 3a. Additionally, the two hydrazones were active against bacterial strains such as Staphylococcus aureus, Campylobacter fetus, Proteus, mirabilis, and methicillin-resistant Staphylococcus aureus, which were resistant to ciprofloxacin with a ZI of between 25-31 mm and MIC of 12.5 μg/ml for Proteus mirabilis and 25 μg/ml for others, accordingly. Amazingly, the two hydrazones demonstrated bactericidal and fungicidal activity between 25 μg/ml and 100 μg/ml against all the sensitive bacterial and fungal strains. The two hydrazones with a 2,4-dichloro moiety have been identified as leads and are recommended for further in-vivo efficacy studies.
Rethinking the Boundary Conditions in the Particle-in-a-Box Mind Experiment
Authors: Chen Jixin
Published: April 2022

In this manuscript, I speculated that the energy density distributions along space and time in a quantum system are uniform according to the 1st law of thermodynamics. Thus, the complementary energy contributions are added to the classical solutions of the 1D particle in a box problem, making the energy density a complex distribution function over space and time. Then the concept is extended to the free rotation problem with a Hamiltonian slightly different than the classical Schrödinger equation. The picturized energy distribution functions and associated time evolution are described in movies for comparison between example classical wave functions and the energy density functions. The wave functions for the hydrogen atom are then guessed based on the historical solutions.
GEOGRAPHIC FUNCTIONS OF TRANSPORT
Authors: Яковлева Светлана Ивановна
Published: April 2022

Цель исследования - выявить основные географические функции транспорта как активного организатора пространства. Новизна исследования: впервые представлена система географических функций транспорта как разных направлений его влияния на основные аспекты территориальной организации других видов деятельности на разных пространственных уровнях. Актуальность исследования связана с тем, что транспорт является важнейшим видом деятельности, а транспортные сети - элементом каркаса освоенной территории. Важно иметь комплексное и системное представление о силе влияния транспорта на пространственное развитие территории, чтобы использовать транспорт как инструмент (способ) активного развития территорий разного уровня. Важно учитывать и объективно оценивать характер реализации функций транспорта, необходимость их укрепления (усиления) в Стратегиях и Программах регионального развития.

The purpose of the study is to identify the main geographical functions of transport as an active organizer of space. The novelty of the study: for the first time, a system of geographical functions of transport is presented as different directions of its influence on the main aspects of the territorial organization of other types of activities at different spatial levels. The relevance of the study is due to the fact that transport is the most important type of activity, and transport networks are an element of the framework of the developed territory. It is important to have a comprehensive and systematic understanding of the strength of the influence of transport on the spatial development of a territory in order to use transport as a tool (method) for the active development of territories at different levels. It is important to take into account and objectively assess the nature of the implementation of transport functions, the need for their strengthening (strengthening) in the Strategies and Programs of regional development.
CURRENT STATES OF REGENERATIVE AMINATION
Authors: Михайлов Степан Петрович , Долуда Валентин Юрьевич , Сульман Михаил Геннадьевич , Матвеева Валентина Геннадьевна
Published: April 2022

Процесс восстановительного аминирования лежит в основе полученная различных ценных химических веществ. Одним из важных классов таких химикатов являются N-содержащие функциональные соединения, которые можно применять в качестве исходного материала или растворителя для синтеза фармацевтических препаратов и агрохимикатов. В последние годы было проведено множество исследований по поиску наиболее активного и селективного гетерогенного катализатора реакции восстановительного аминирования. Настоящая обзорная статья посвящена изучению каталитического поведения различных гетерогенных катализаторов при восстановительном аминировании левулиновой кислоты и ее производного. Было проведено сравнение выходов пирролидона при аналогичных условиях реакции. В обзоре также рассматривалось проведение исследуемой реакции как в реакторах периодического действия, так и в проточных реакторах непрерывного действия.

The process of reductive amination underlies the production of various valuable chemicals. One important class of such chemicals are N-containing functional compounds that can be used as a starting material or solvent for the synthesis of pharmaceuticals and agrochemicals. In recent years, many studies have been carried out to find the most active and selective heterogeneous catalyst for the reductive amination reaction. This review article is devoted to the study of the catalytic behavior of various heterogeneous catalysts in the reductive amination of levulinic acid and its derivative. The yields of pyrrolidone were compared under similar reaction conditions. The review also considered the performance of the reaction under study both in batch reactors and in continuous flow reactors.
PRINCE G.N. TRUBETSKOY AT THE LOCAL COUNCIL OF THE ORTHODOX RUSSIAN CHURCH 1917-1918
Authors: Иферов Роман Григорьевич
Published: April 2022

Князь Г.Н. Трубецкой, как представитель генерального штаба действующей армии, был заметной фигурой в составе Поместного Собора РПЦ 1917-1918 гг. Важнейшими деяниями Трубецкого на Соборе стали: речь в защиту патриаршества на пленарном заседании; авторство «формулы перехода» Отдела о Высшем Церковном Управлении; участие в соборном посольстве в Киев и составлении документа об отказе Собора от общения с большевиками по поводу еженедельного академического издания «Церковный Вестник». Однако его деятельность на Соборе не получила должной научной оценки. Решению данной задачи посвящена настоящая статья. В статье на основе анализа комплекса опубликованных и архивных документов показано, что дипломатический опыт Г.Н. Трубецкого оказался востребованным при решении острых дискуссионных вопросов.

Prince G.N. Trubetskoy, as a representative of the general staff of the acting army, was a notable figure in the Local Council of the Russian Orthodox Church in 1917-1918. The most important acts of Trubetskoy at the Council were: a speech in defense of the patriarchate at the plenary session; authorship of the «transition formula» of the department of the Higher Church Administration; participation in the Council's embassy to Kiev and preparation of the document on the refusal of the Council to communicate with the Bolsheviks regarding the weekly academic publication «Church Bulletin». His activities at the Council, however, did not receive a proper scholarly appraisal. The present article is devoted to solving this problem. Based on an analysis of a set of published and archival documents, the article shows that G. N. Trubetskoy's diplomatic experience was in demand when dealing with acute discussion issues.
ARCHIVES OF RUSSIAN EMIGRANTS: LETTERS OF A.I. KONOVALOV AND V.M. ZENZINOV IN THE FUND OF A.F. KERENSKY. 1939 - 1948
Authors: Леонтьева Ольга Геннадьевна
Published: April 2022

Статья посвящена вопросам изучения эпистолярного наследия русских эмигрантов - архивной россике. В частности, в статье изложены результаты изучения писем А.Ф. Коновалова и В.М. Зензинова к А.Ф. Керенскому за 1939-1949 гг. Особое внимание автором было уделено изучению содержания переписки. В письмах затронуты не только проблемы политического характера и изложены мнения авторов по вопросам расстановки сил в Европе после Второй мировой войны, но и дана характеристика военного и послевоенного быта русских эмигрантов во Франции и США. В письмах изложены мнения русского зарубежья о возможном послевоенном сотрудничестве с Советским Союзом.

The article is devoted to the study of the epistolary heritage of Russian emigrants - Rossika. In particular, the article presents the results of studying the letters of A.F. Konovalov and V.M. Zenzinov to A.F. Kerensky for 1939-1949. Special attention was paid to the study of the content of correspondence. The letters touched not only on political issues and set out the authors ' views on the balance of power in Europe after the World War II, but also gave a description of the pre-war and postwar life of Russian immigrants in France and the United States. The letters set out the views of the Russian Diaspora on possible post-war cooperation with the Soviet Union.
STUDY OF THE FORMATION OF COMPETENCIES OF THE UNEMPLOYED DURING THE NON-NORMATIVE EMPLOYMENT CRISIS
Authors: Белоусов Максим Владимирович , Пряжникова Елена Юрьевна
Published: April 2022

Представлены результаты формирующего эксперимента, проведенного со сложной социальной группой безработных, находящихся в периоде ненормативного кризиса занятости. Отражено разделение безработных граждан в зависимости от длительности нахождения в кризисе занятости. Установлено, что психологическое сопровождение формирования компетенций безработных в период кризиса занятости должно зависеть от устойчивости психологического состояния безработных, быть направлено на формирование у безработных устойчивого психологического состояния (в частности, на снижение уровня тревожности и стресса и развитие навыков эмоционального интеллекта), учитывать потребности в развитии компетенций в разных группах безработных. Имплементация описанных программ на практике позволит стабилизировать и улучшить эмоциональное состояние клиентов, развить личные и профессиональные компетенции, востребованные рынком труда, что позволит безработным гражданам прийти к профессиональному самоопределению и трудоустроиться.

The article presents the results of a formative experiment conducted with a complex social group of unemployed people who are in the period of non-normative employment crisis. The division of unemployed citizens depending on the duration of stay in the employment crisis is reflected. It has been established that psychological support for the formation of competencies of the unemployed during the employment crisis should depend on the stability of the psychological state of the unemployed; be aimed at the formation of a stable psychological state in the unemployed, in particular at reducing the level of anxiety and stress and developing emotional intelligence skills; take into account the needs for the development of competencies in different groups of the unemployed. The implementation of the described programs in practice will stabilize and improve the emotional state of clients, develop personal and professional competencies demanded by the labor market, which will allow unemployed citizens to come to professional self-determination and find a job.
ATTITUDE TO VACCINOPROPHYLAXIS AS A REFLECTION OF THE LEVEL OF DEVELOPMENT OF LIFE SAFETY META-COMPETENCIES IN FUTURE LABOR SUBJECTS
Authors: Демиденко Надежда Николаевна , Шверина Надежда Михайловна
Published: April 2022

Вопросы безопасности являются особенно важными в связи с актуальными вызовами в отношении здоровья, профессиональной деятельности и жизни человека. Дисциплина «Безопасность жизнедеятельности» обладает существенным ресурсом развития метакомпетенций у студентов как будущих субъектов труда. Представлены результаты исследования, цель которого - изучение отношения студентов к вакцинопрофилактике как отражение уровня сформированности метакомпетенций будущих специалистов. Проанализированы психологические причины отказа от вакцинации, дается представление об уровне сформированности метакомпетенций обучающихся как будущих субъектов труда в вопросах безопасности жизнедеятельности.

Safety issues are particularly important in connection with current challenges in relation to health, professional activity and human life. The discipline «Life safety» has a significant resource for the development of meta-competencies among students as future subjects of labor. The results of the study are presented, the purpose of which is to study the attitude of students to vaccination as a reflection of the level of metacompetencies of future specialists. The psychological reasons for refusal of vaccination are analyzed, an idea is given about the level of formation of students' meta-competencies as future subjects of labor in matters of life safety.
MOBILITYASSELF-DETERMINATIONOFYOUTH
Authors: Евстифеева Елена Александровна , Филиппченкова Светлана Игоревна , Майкова Элеонора Юрьевна , Харченко Андрей Юрьевич
Published: April 2022

Анализируется проблема выбора приоритетной значимости мобильности в ценностно-смысловой структуре сознания у молодежи, влияющей на формирование у неё глобальной идентичности как доминирующей, понижающей при этом иерархический статус самоидентичности как рефлексивной оси целостности человека и других социальных идентификаций. Выборку исследования составили 190 студентов Кыргызско-Российского Славянского университета им. Б.Н. Ельцина (г. Бишкек). Инструментарий исследования: авторская анкета духовно-нравственных ценностей молодежи, методика диагностики уровня рефлексивности А.В. Карпова, методика диагностики уровня субъективного контроля (УСК) Дж. Роттера, методика Д.А. Леонтьева «Смыложизненные ориентации», экспресс-опросник «Индекс толерантности» Г.У. Солдатовой и др., рефлексивный опросник Т.П. Скрипкиной и опросник SF-36 (качество жизни). Результаты исследования демонстрируют, что мобильность вытесняет традиционные духовно-нравственные ценности, идентифицируется как глобальная идентичность в виде таких субъектно-личностных качеств, как доверительность, коммуникативные навыки, толерантность к неопределенности.

The article analyzes the problem of choosing the priority significance of mobility in the value-semantic structure of consciousness among young people, which influences the formation of a global identity as a dominant one, while lowering the hierarchical status of self-identity as a reflexive axis of human integrity and other social identifications. The study sample consisted of 190 students of the Kyrgyz-Russian Slavic University. B.N. Yeltsin (Bishkek). Research tools: the author's questionnaire on the spiritual and moral values of young people, a method for diagnosing the level of reflexivity A.V. Karpov, the method of diagnosing the level of subjective control (USK) by J. Rotter, the method of D.A. Leontiev «Smarty life orientations», express questionnaire «Index of tolerance» G.U. Soldatova and others, a reflective questionnaire by T.P. Skripkina and questionnaire SF - 36 (quality of life). The results of the study demonstrate that mobility displaces traditional spiritual and moral values, which is identified as a global identity in the form of such subject-personal qualities as: trust, communication skills, tolerance for uncertainty.
MODEL OF PEDAGOGICAL INTERACTION IN THE PROCESS OF MUSICAL AND AESTHETIC EDUCATION OF SENIOR PRESCHOOL CHILDREN
Authors: Корнакова Марина Георгиевна
Published: April 2022

Теоретическая проблема исследования - разработка концепции целостной модели педагогического взаимодействия, ориентированного на музыкально-эстетическое воспитание личности в условиях дошкольного образования. Цель исследования - обосновать, разработать и апробировать модель педагогического взаимодействия, ориентированного на музыкально-эстетическое воспитание личности в условиях дошкольного образования. Предложена модель педагогического взаимодействия, представляющая комплекс организационно-педагогических условий для передачи познавательного, эмоционально-ценностного, практического и коммуникативного опыта в процессе музыкально-эстетического воспитания дошкольников. Охарактеризованы целевой, методологический, содержательно-организационный и оценочно-результативный блоки модели. Описана реализация модели, позволяющая поэтапно формировать музыкально-эстетическую воспитанность как интегративное качество личности дошкольника в интегративной образовательной среде, созданной с помощью педагогического взаимодействия. Приведены данные апробации модели в базовых образовательных организациях, подтверждающие ее продуктивность.

The theoretical problem of the research is the development of the concept of a holistic model of pedagogical interaction, focused on the musical and aesthetic education of the individual in the context of preschool education. The purpose of the study is to substantiate, develop and test a model of pedagogical interaction focused on the musical and aesthetic education of the individual in the conditions of preschool education. A model of pedagogical interaction is proposed, which represents a complex of organizational and pedagogical conditions for the transfer of cognitive, emotional, value, practical and communicative experience in the process of musical and aesthetic education of preschool children. The target, methodological, content-organizational and evaluative-effective blocks of the model are characterized. The implementation of the model is described, which makes it possible to gradually form musical and aesthetic education as an integrative quality of a preschooler's personality in an integrative educational environment created with the help of pedagogical interaction. The data of approbation of the model in basic educational organizations confirming its productivity are given.
Pacific Peoples Leadership in the Aotearoa-New Zealand Public Sector
Authors:   , Fagaloa Tutaima
Published: April 2022

Pacific people have experienced a turbulent introduction to life in New Zealand. The result has seen an over-representation of Pacific people in unemployment, health disparity, crime, and poor education outcomes (Marriott & Sims, 2014). Since the 1980s, Pacific public sector leadership roles have been established to support Pacific people and their communities. These public sector roles are the focus of this study. By strengthening Pacific leaders and leadership in the Aotearoa-New Zealand public sector, Pacific people and their outcomes can be improved.

The aim of my research was to explore the experiences of Pacific leaders in the New Zealand public sector. The methodological approach used for this study was phenomenology which is aimed at illuminating specific experiences and meanings as they are perceived by the interviewees (Hycner, 1985; Lester, 1999; Paea, 2009). Pacific methods, such as Fa’afaletui (Tamasese, 2010) and Talanoa (Vaioleti, 2006), were adopted to best draw out such experiences from the leaders, with attention to the strengths of their leadership.

The study discovered five themes: 1) Negotiation of multi-ethnic Pacific and Western constructs of leadership; 2) Creating safe environments for Pacific public sector leaders; 3) Valuing Pacific leaders as knowledge experts; 4) Access to equal employment opportunities; and 5) Growing Pacific leadership. The themes are located within a cultural metaphor of the Tuiga, a traditional Samoan headdress.

The study offers recommendations for government and public sector agencies to better support Pacific leaders by genuinely integrating Pacific cultural capital within the policy, funding and workforce development areas of the public sector; provide safe environments by addressing racist and discriminatory practices within all levels of the public service with a specific focus on planning and funding, and workforce development units; value the contribution Pacific leaders and staff make to the public sector through promotion, reward and acknowledgement, ensuring Pacific leaders and staff access equal opportunities to develop and be remunerated equally; and build an agency-wide pipeline for future Pacific public workforce to develop into leadership roles.
UAV Path Planning Based on an Improved Ant Colony Algorithm
Authors: Song Hui , Jia Minghan , Lian Yihang , Fan Yijing , Liang Keshan
Published: April 2022

Reviews and experimental verification have found that existing solution methods can be used to solve UAV path planning problems, but each approximate solution has its own advantages and disadvantages. For example, ant colony algorithm easily falls into the local optimum in the process of realizing path planning. In order to prevent too low pheromones on the longer path and too high pheromones in the shorter path, the upper and lower limits of pheromones as well as their volatile factors are set to avoid falling into the local optimum. Secondly, multi-heuristic factors are introduced, and the overall length of the path serves as an adaptive heuristic function factor that determines the probability of state transition, which affects the probability of ants choosing the corresponding path. The experimental results show that the path length planned by the improved algorithm is 93.6% of the original algorithm, and the optimal path length variance is only 14.22% of the original algorithm. The improved ant colony algorithm shortens the optimal path length and solves the UAV path planning problem in terms of local optima. At the same time, multiple enlightening factors are introduced to increase the suitability of UAV for complex environments and improve the performance of UAV.
Application of Technology in the Fault Diagnosis of Large Centrifugal Pump Units
Authors: Shi Lian
Published: April 2022

In order to promote the stability of centrifugal pump units and maximize the role of centrifugal pumps, this paper analyzes the composition and basic working principle of centrifugal pumps, presents the main concerns of centrifugal pump maintenance, and finally investigates the common faults and maintenance methods of centrifugal pumps for reference.
Gambaran Pelayanan Kefarmasian dan Kepuasan Konsumen Apotek Puri Medika di Kecamatan Buayan Kota Kebumen
Authors: Felia Lisa , Miyarso Chondrosuro , Intiyani Rafila
Published: April 2022

Standar pelayanan kefarmasian merupakan tolak ukur yang digunakan sebagai acuan bagi para tenaga kefarmasian dalam penyelenggarakan  berbagai pelayanan kefarmasian. Dalam pelayanan kefarmasian kepuasan menjadi bagian yang sangat penting karena kepuasan  pasien  tidak dapat dipisahkan dari kualitas pelayanan Kesehatan. Tujuan penelitian ini adalah untuk mengetahui gambaran pelayanan dan kepuasaan konsumen dalam menerima pelayanan obat yang diberikan oleh petugas Apotek Puri Medika. Penelitian ini menggunakan metode observasional deskriptif. Instrumen penelitian ini menggunakan kuesioner, jumlah responden 78 orang dengan purposive sampling Penelitian ini menunjukkan bahwa dengan uraian nilai TCR (Tingkat Capaian Responden) tertinggi yaitu dimensi bukti langsung yaitu 83% (sangat puas), dimensi kehandalan 79,4% (puas), dimensi empati 78,2 (puas), dimensi jaminan 77% (puas, dan dimensi ketanggapan 75% (puas). Sehingga dapat disimpulkan bahwa gambaran pelayanan kefarmasian di Apotek Puri Medika mendapatkan kepuasan konsumen di Apotek Puri Medika menurut lima dimensi mendapatkan kategori puas dengan skor nilai 78,6%.
FORMULASI DAN EFEK ANTIOKSIDAN MASKER GEL PEEL OFF EKSTRAK DAUN NANGKA (Artocarpus heterophyllus Lam.)
Authors: Ambarwati Nur , Kiromah Naelaz Zukhruf Wakhidatul , Rahayu Titi Pudji
Published: April 2022

Masker gel peel off salah satu cara untuk merawat kulit. PVA berfungsi dalam memberikan efek peel off karena mampu membuat lapisan film sehingga lebih mudah dikelupas setelah kering. Daun nangka dapat digunakan sebagai sumber antioksidan alami. Tujuan penelitian ini untuk mengetahui formula terbaik dari perbedaan konsentrasi PVA yang di uji antioksidannya menggunakan metode DPPH dan pembanding vitamin C. Metode penelitian yaitu penelitian kuantitatif bersifat eksperimental. Hasil penelitian ini adalah hasil evaluasi sifat fisik meliputi organoleptis formula 1, 2, 3 memiliki bentuk sediaan gel, bau wangi, dan warna hijau. Sediaan homogen dan memiliki nilai pH formula 1, 2, 3 yaitu 4,5-5,5. Daya mengering formula 1, 2, 3 adalah 16-29 menit, daya lekat 8 detik, daya sebar 4-6 cm. Formula 1, 2, dan 3 memasuki persyaratan fisik sediaan masker gel peel off. Formula 2 adalah formula yang diuji antioksidan karena memiliki pH lebih basa dari formula 1 dan memiliki waktu sediaan mengering lebih lama dari formula 3. Hasil nilai IC50 vitamin C 7,63 µg/L, ekstrak 26,44 µg/L, dan sediaan 32,68 µg/L, sehingga sediaan dikatakan memiliki sifat antioksidan yang sangat kuat. Kesimpulan sediaan masker gel peel off dapat digunakan untuk perawatan kulit wajah sebagai antioksidan. Saran melakukan uji iritasi dan uji kesukaan pada masyarakat.
narrativa transmedia del restaurante Masterchef
Authors: Rodríguez Víctor Álvarez
Published: April 2022

Este trabajo es una investigación sobre el desarrollo de la narrativa transmedia televisiva como ejercicio experiencial. Se busca identificar y explorar la eficacia de este tipo de acciones dentro del mercado publicitario actual.