Final report for SIM.QM-S12: supplementary comparison for trace elements in natural water
Authors: Grinberg Patricia , Nadeau Kenny , Yang Lu , Mester Zoltan , Fung Wai-hong , Tse Chun-wai , Merrick Jeffrey , White Ian , Schipp Isaac , Acosta Osvaldo , Puelles Mabel , Quino Jose Luis Gonzales , Sena Rodrigo Caciano de , Almeida Marcelo Dominguez de , Dutra Emily Silva , Jingbo Chao , Lijie Dong , Kakoulides Elias , Karanikolopoulos G , Stathoudaki E , Tripathy Sushree Swarupa , Toppo Dibya Dolridge , Pokhariyal Jyoti , Krishna Anuj , Vinod Chinky , Taneja Lakhan , Elishian Christine , Komalasari Isna , Baharom Norliza , Kadir Haslina Binti Abdul , Solis Elmer Carrasco , Uribe Christian , Junsay Alleni Tongson , Laurio Christian D , Maniego Johnester D , Gatchalian Clarissa J , Guerrero Jan-Ervin C , Strzelec Michal , Bojanowska-Czajka Anna , Warzywoda Beata , Jaćimović Radojko , Zuliani Tea , Phukphatthanachai Pranee , Laitip Nunnapus , Thiengmanee Usana , Napoli Romina , Ferreira Elizabeth 
Published: January 2024

Main text

The SIM Supplementary Comparison SIM.QM-S12 for Trace Elements in Natural Water was undertaken to assess and demonstrate the analytical capabilities of national metrology institutes (NMIs) and designated institutes (DIs) of SIM members (or other regions) for the accurate determination of trace elements in natural water at µg/kg levels.

Evidence of successful participation in formal, relevant international comparisons is needed to document calibration and measurement capability claims (CMCs) made by NMIs and DIs.

Seventeen NMIs and DIs participated. Participants were requested to evaluate the mass fractions, expressed in µg/kg, of arsenic, cadmium, lead and antimony in a natural mineral groundwater that was spiked with the respective elements. A variety of instrumental techniques including inductively coupled plasma mass spectrometry (ICP-MS), isotope dilution ICP-MS (ID-ICP-MS), inductively coupled plasma optical emission spectrometry (ICP-OES), electrothermal atomic absorption spectrometry (ETAAS) and hydride generation flame atomic absorption spectrometry (HG-FAAS) were used by the participants for the determination.

The NIST decision tree was used to assign the SCRV estimate for the proposed measurands and to calculate the degrees of equivalence of each national measurement standard following the IAWG Guidance on Using NIST Decision Tree for Comparison Reporting from 30 June 2023.

Successful participation in SIM.QM-S12 demonstrates measurement for determination of elements in water matrices. Considering the IAWG Core Capability Matrix, this material falls into the matrix challenge called "Water/aqueous", which corresponds to the CCQM amount-of-substance category fresh water, and so will support CMCs for the metalloids and semi-metals at mass fraction levels below 50 µg/kg (As and Sb measurements) and transition elements at mass fraction levels below 50 µg/kg (except Hg) (for Cd and Pb measurements).

To reach the main text of this paper, click on Final Report. Note that this text is that which appears in Appendix B of the BIPM key comparison database https://www.bipm.org/kcdb/.

The final report has been peer-reviewed and approved for publication by the CCQM, according to the provisions of the CIPM Mutual Recognition Arrangement (CIPM MRA).