bluuebunny/crossref_metadata_2025 huggingface dataset:
A Study on Verification of Waterproofing Method Properties for Performance Grading in Apartment Houses-Upper Slab of the Underground Structure
Authors: An Ki-won , Kim Byoung-il
Published: August 2023

This study evaluates waterproofing methods for underground structures in multi-unit residential buildings. The objective is to select effective methods and establish performance ratings. Experimental assessments are conducted and scores are assigned for ranking. In this regard, waterproofing methods used in the upper slab of the top floor of multi-unit residential building underground structures were investigated, and they were categorized as composite waterproofing, sheet waterproofing, and membrane waterproofing methods. For performance evaluation purposes, experiments were conducted on qualified materials and scores were assigned to each test specimen, with a total score of 100 points. Based on the test results, scores for disqualified materials were deducted and, ultimately, the rankings of waterproofing materials and methods for the upper slab of the top floor of underground structures were determined based on the total aggregated scores. Subsequently, through proximity performance evaluation, the applied waterproofing methods were experimentally verified for defect issues based on the presence or absence of a proximity layer. This led to the ranking and performance grading of a total of 12 materials. The results confirmed the necessity of a proximity layer-dependent waterproofing method and highlighted the superiority of the composite waterproofing method with a proximity layer. Additionally, differences in installation methods and material properties between sheet and membrane waterproofing methods were identified, resulting in variations in performance grading.
Estimation of Uniform Risk Spectra Suitable for the Seismic Design of Structures
Authors: Buendía Luis , Niño Mauro , Reinoso Eduardo , González Carlos
Published: August 2023

The aim of this paper is to present a performance-based method to estimate uniform risk spectra (URS) for the seismic design and assessment of structures. These spectra, computed with the proposed methodology, provide the lateral capacity (in terms of spectral acceleration) that should be given to a structure, characterized by a reference single degree of freedom system, to achieve a predetermined exceedance rate of economic loss. This procedure involves the seismic hazard assessment necessary to define a seismic design level consistent with the accepted loss value, using a large enough number of synthetic seismic records of several magnitudes, which were obtained by means of an improved empirical Green function method. The statistics of the expected losses of a reference single degree of freedom system are obtained using Monte Carlo simulation, considering the seismic demand and the lateral strength of the structure as random variables. The method is divided into two main stages: (1) definition of the seismic hazard at the site of interest and (2) the probabilistic analysis of the seismic performance in terms of an economical loss ratio of nonlinear SDOF. To illustrate the proposed methodology and, subsequently, to validate it, a URS was computed for a site located in the Mexico City lake-bed zone, and its use in the design of three reinforced concrete frames is shown. The results show that the proposed spectra provide a sufficient approximation between the seismic risk level considered in the seismic design and that of the designed structure. It is concluded that the proposed procedure is a significant improvement over others considered in the literature and a useful research tool for the further development of risk-based earthquake engineering.
Spatio-Temporal Evolution and Influencing Factors of Integrated Urban–Rural Development in Northeast China under the Background of Population Shrinkage
Authors: Sun Yige , Yang Qingshan , Liu Jian
Published: August 2023

Population shrinkage has had a certain negative impact on urban and rural development in many aspects. The impact of population shrinkage on urban–rural integration has become one of the core scientific issues that needs to be addressed in the current research on promoting the goal of common prosperity in China. Northeast China is a typical region in China that is experiencing a decrease in population and economic activity. Investigating the integrated development of urban and rural areas in this region is highly important for revitalizing Northeast China. This research paper focuses on 32 prefecture-level cities in Northeast China and utilizes spatial correlation analysis and the Geographical Weighted Regression model to uncover the evolving spatial patterns and influential factors affecting integrated urban–rural development in the context of population decline. The findings revealed the following: (1) The level of integrated urban–rural development in Northeast China continues to rise despite the shrinking population. During the comprehensive population decline stage, the growth rate of the urban–rural coupling coordination degree surpasses that of the initial stage. The areas with high values of urban–rural coupling coordination degree shift from northeastern Heilongjiang to four sub-provincial cities. The spatial correlation between urban–rural coupling and coordinated development weakens, with the main type being low–low agglomeration. (2) Factors such as economic development level, labor force size, urbanization level, level of openness, urban–rural accessibility, and proportion of built-up areas significantly correlate with urban–rural coupling and coordination. The influence of each factor varies in magnitude and direction across different locations. Labor force size and urban–rural accessibility have the most-significant impact on integrated urban–rural development, with labor force size having a positive effect and urban–rural accessibility having a negative effect. The impact of the economic development level follows a pattern of initial increase and subsequent decrease as the population shrinks. (3) Although population decline does not hinder integrated urban–rural development in Northeast China, it is closely connected to changes in the factors influencing such development. To capitalize on the development opportunities presented by national policies, Northeast China should adopt a model of urban–rural development that promotes rural growth through cities. This entails attracting talented individuals to return, enhancing the flow of urban–rural development elements in both directions, and creating a spatial development pattern characterized by “big city, big agriculture, and big ecosystem”. By doing so, the revitalization of Northeast China can be achieved.
Transient Thermoelastic Analysis of Rectangular Plates with Time-Dependent Convection and Radiation Boundaries
Authors: Zhang Zhong , Sun Ying , Xiang Ziru , Qian Wangping , Shao Xuejun
Published: August 2023

Approximate analytical solutions are presented for the transient thermoelastic problem of rectangular plates with time-dependent convection and radiation boundaries. To include the nonlinear radiation boundary, the whole heating process is divided into several time steps, and a linearized approximation is used to simplify the radiation term for each step. The one-dimensional transient temperature along the thickness direction is solved using the technique of the separation of variables. The displacement and stress solutions are obtained by applying the state-space method to the three-dimensional thermoelasticity equations. The accuracy of the present solutions is demonstrated by comparison with the reported results in the open literature and the finite element solutions. In the numerical examples, two kinds of thermal boundaries, namely, time-independent convection boundaries and time-dependent convection and radiation boundaries, are considered to show the availability of the present solutions.
Qualitative and Quantitative Scientometric Analysis of Bioclimatic Retrofitting in Commercial Buildings from 2008 to 2022
Authors: Heidari Ali , Olivieri Francesca
Published: August 2023

The present study offers a thorough scientometric analysis of the practice of bioclimatic retrofitting in commercial buildings, which is considered a crucial approach for mitigating energy consumption and addressing the challenges posed by climate change. Since Scopus offers advanced tools for literature search and analysis, its database was used to acquire bibliographic data for nearly 400 published papers using a bibliometric search, a scientometric methodology, and an in-depth qualitative analysis. The scientometric procedure utilizes various quantitative dimensions, such as the number of intermediate citations, occurrences, average publication year, and general connection power. A retrospective examination of research publication patterns spanning 2008 to May 2022 has unveiled an upward trajectory in scholarly investigations pertaining to commercial buildings during this 15-year period. Nevertheless, research on the topics of bioclimatic design, retrofitting strategies, and green building practices in the context of commercial buildings exhibits a more gradual incline, displaying an almost linear trend between the years 2016 and 2020. Additionally, the study provides qualitative perspectives on the research environment. The paper delineates various focal points of research within the field, encompassing thermal comfort in the context of energy management and climate control, ventilation systems, sustainable development as it pertains to architectural designs and green buildings, retrofitting strategies in commercial buildings to enhance energy efficiency, the interplay between carbon dioxide levels and energy resources, the utilization of solar energy, the relationship between energy conservation and atmospheric temperature, and the application of building energy simulation techniques.
Diffusion Behavior of Iodine in the Micro/Nano-Porous Graphite for Nuclear Reactor at High Temperature
Authors: Qi Ming-Bo , Lian Peng-Fei , Li Peng-Da , Zhang He-Yao , Cheng Jin-Xing , Wang Qing-Bo , Tang Zhong-Feng , Pan T. J. , Song Jin-Liang , Liu Zhan-Jun
Published: August 2023

The diffusion behavior of iodine in micro/nano-porous graphite under high-temperature conditions was studied using analysis methods such as Rutherford backscattering Spectrometry, scanning electron microscopy, X-ray diffraction, and Raman spectroscopy. The results indicate that iodine diffusion leads to the Lattice Contractions in Microcrystals, a decrease in interlayer spacing, and a rise of defect density. And the reversal or repair of microstructure change was observed: the microcrystal size of the graphite increases, the interlayer spacing appears to return to the initial state, and the defect density decreases, upon diffusion of iodine out of iodine-loaded graphite. The comparative study comparing the iodine diffusion performance of nanoporous graphite (G400 and G450) between microporous graphite (G500), showed that nanoporous graphite exhibits a better barrier to the iodine diffusion. The study on the diffusion behavior of iodine in micro/nano-porous graphite holds substantial academic and engineering value for the screening, design, and performance optimization of nuclear graphite.
Artificial Intelligence in Urooncology: What We Have and What We Expect
Authors: Froń Anita , Semianiuk Alina , Lazuk Uladzimir , Ptaszkowski Kuba , Siennicka Agnieszka , Lemiński Artur , Krajewski Wojciech , Szydełko Tomasz , Małkiewicz Bartosz
Published: August 2023

Introduction: Artificial intelligence is transforming healthcare by driving innovation, automation, and optimization across various fields of medicine. The aim of this study was to determine whether artificial intelligence (AI) techniques can be used in the diagnosis, treatment planning, and monitoring of urological cancers. Methodology: We conducted a thorough search for original and review articles published until 31 May 2022 in the PUBMED/Scopus database. Our search included several terms related to AI and urooncology. Articles were selected with the consensus of all authors. Results: Several types of AI can be used in the medical field. The most common forms of AI are machine learning (ML), deep learning (DL), neural networks (NNs), natural language processing (NLP) systems, and computer vision. AI can improve various domains related to the management of urologic cancers, such as imaging, grading, and nodal staging. AI can also help identify appropriate diagnoses, treatment options, and even biomarkers. In the majority of these instances, AI is as accurate as or sometimes even superior to medical doctors. Conclusions: AI techniques have the potential to revolutionize the diagnosis, treatment, and monitoring of urologic cancers. The use of AI in urooncology care is expected to increase in the future, leading to improved patient outcomes and better overall management of these tumors.
Anti-Inflammatory and Immune Properties of Polyunsaturated Fatty Acids (PUFAs) and Their Impact on Colorectal Cancer (CRC) Prevention and Treatment
Authors: Tojjari Alireza , Choucair Khalil , Sadeghipour Arezoo , Saeed Azhar , Saeed Anwaar
Published: August 2023

Colorectal cancer (CRC) remains a leading cause of death from cancer worldwide, with increasing incidence in the Western world. Diet has become the focus of research as a significant risk factor for CRC occurrence, and the role of dietary polyunsaturated fatty acids (PUFAs) has become an area of interest given their potential role in modulating inflammation, particularly in the pro-carcinogenic inflammatory environment of the colon. This work reviews the main types of PUFAs, their characteristics, structure, and physiologic role. We then highlight their potential role in preventing CRC, their signaling function vis-à-vis tumorigenic signaling, and their subsequent potential role in modulating response to different treatment modalities. We review pre-clinical and clinical data and discuss their potential use as adjunct therapies to currently existing treatment modalities. Given our understanding of PUFAs’ immune and inflammation modulatory effects, we explore the possible combination of PUFAs with immune checkpoint inhibitors and other targeted therapies.
Cu/CuO-Decorated Peanut-Shell-Derived Biochar for the Efficient Degradation of Tetracycline via Peroxymonosulfate Activation
Authors: Zhao Jianhui , Li Huan , Wang Yuanzhou , Yu Jingjie , Li Ning , Wang Shaopo
Published: August 2023

Biochar (BC) usually has abundant surface functional groups, well-developed pore structures and high specific surface areas, which can combine with transition metals for peroxymonosulfate (PMS) activation to degrade organics. In this paper, BC modified with Cu/CuO was prepared by a modified impregnation pyrolysis method using peanut shells as raw materials. The morphology, structure and physicochemical properties were analyzed. Results showed that the originally smooth BC surface was modified into a rough structure with distributed metal particles, and the specific surface area of the modified Cu/CuO-BC700 (i.e., Cu/CuO-BC) increased from the initial 22.57 to 192.64 m2/g. The Cu/CuO-BC was employed for PMS activation and tetracycline (TC) degradation, achieving a removal efficiency of 93.2% at TC initial concentration 20 mg/L, PMS concentration 0.5 mM and catalyst dosage 0.1 g/L after 30 min. The influence of co-existing anions in the actual water on TC degradation followed the order of HCO3− > H2PO4− > Cl−, and HA had an inhibitory effect on TC degradation. A variety of active species participated in TC degradation, and the free radical pathway played a dominant role. Furthermore, the Cu/CuO-BC could maintain the degradation efficiency of TC up to 80% even after five consecutive cycles. The Cu/CuO-BC maintained high activity through redox reactions between catalytically generated active species and the cycling of metal ions (Cu+/Cu2+).
Cognitive Alterations in Old Mice Are Associated with Intestinal Barrier Dysfunction and Induced Toll-like Receptor 2 and 4 Signaling in Different Brain Regions
Authors: Brandt Annette , Kromm Franziska , Hernández-Arriaga Angélica , Martínez Sánchez Inés , Bozkir Haktan Övül , Staltner Raphaela , Baumann Anja , Camarinha-Silva Amélia , Heijtz Rochellys Diaz , Bergheim Ina
Published: August 2023

Emerging evidence implicate the ‘microbiota–gut–brain axis’ in cognitive aging and neuroinflammation; however, underlying mechanisms still remain to be elucidated. Here, we assessed if potential alterations in intestinal barrier function and microbiota composition as well as levels of two key pattern-recognition receptors namely Toll-like receptor (TLR) 2 and TLR4, in blood and different brain regions, and depending signaling cascades are paralleling aging associated alterations of cognition in healthy aging mice. Cognitive function was assessed in the Y-maze and intestinal and brain tissue and blood were collected in young (4 months old) and old (24 months old) male C57BL/6 mice to determine intestinal microbiota composition by Illumina amplicon sequencing, the concentration of TLR2 and TLR4 ligands in plasma and brain tissue as well as to determine markers of intestinal barrier function, senescence and TLR2 and TLR4 signaling. Cognitive function was significantly impaired in old mice. Also, in old mice, intestinal microbiota composition was significantly altered, while the relative abundance of Gram-negative or Gram-positive bacteria in the small and large intestines at different ages was not altered. Moreover, intestinal barrier function was impaired in small intestine of old mice, and the levels of TLR2 and TLR4 ligands were also significantly higher in both portal and peripheral blood. Furthermore, levels of TLR2 and TLR4 ligands, and downstream markers of TLR signaling were higher in the hippocampal and prefrontal cortex of old mice compared to young animals. Taken together, our results suggest that even in ‘healthy’ aging, cognitive function is impaired in mice going along with an increased intestinal translocation of TLR ligands and alterations of TLR signaling in several brain regions.
High-Performance MEMS Oxygen Sensors Based on Au/TiO2 Films
Authors: Jiao Mingzhi , Zhao Xiaohu , He Xinjian , Wang Gang , Zhang Wei , Rong Qian , Nguyen DucHoa
Published: August 2023

High-performance microelectromechanical system (MEMS) oxygen sensors were realized by successful preparation of Au nanofilms over TiO2 thin films through successive sputtering on commercial MEMS microhotplates. Oxygen sensing performance of 3 and 6 nm thick Au over TiO2 thin films were compared with that of pure TiO2 thin films. It was shown that 6 nm thick Au over TiO2 thin films have the best sensitivity toward oxygen. The prepared TiO2 thin films were characterized using SEM, EDS, XPS, and a gas testing instrument. The results show that Au decoration has little influence on the surface morphologies of TiO2 thin films. However, Au decoration has a strong influence on the surface properties of the composite films. The favorable performance of 6 nm Au-doped TiO2 thin films is attributed to factors such as catalytical performance, height of Schottky contact, and number of oxygen vacancies. This work makes contributions to low power consumption and high-performance oxygen sensors for Internet of Things applications.
Translation and Validation Study of the Hypoglycemia Fear Survey in a Greek Population of Children and Adolescents with Type 1 Diabetes Mellitus and their Parents
Authors: Kostopoulou Eirini , Andreopoulou Ourania , Daskalaki Sophia , Kotanidou Eleni , Vakka Angeliki , Galli-Tsinopoulou Assimina , Spiliotis Bessie E. , Gonder-Frederick Linda , Fouzas Sotirios
Published: August 2023

The present study attempted to translate and culturally adapt an established research instrument, the Hypoglycemia Fear Survey (HFS) questionnaire, to the Greek population and evaluate its validity and internal consistency so that it can be used for the assessment of hypoglycemia fear in Greek children and adolescents with T1DM and their parents. One hundred Greek children and adolescents with T1DM, 54 males, 6–18 years old, and one of their parents participated in this validation study. The participants completed the translated Greek HFS, which includes one version for children (CHFS) and one for parents (PHFS). Exploratory Factor Analysis (EFA) was used to assess construct validity. Internal consistency was assessed using Cronbach’s alpha, and convergent validity was established by estimating the correlation coefficients between the scores of the HFS scales/subscales and the different constructs of the Pediatric Quality of Life Inventory. The CHFS and PHFS exhibited adequate internal consistency for the total score and the Worry subscale, but lower consistency for the Behavior subscale. High test–retest reliability was also shown. We conclude that the Greek version of the HFS is a valid and reliable instrument to assess the fear of hypoglycemia in Greek children and adolescents with T1DM and their parents.
Sugar Intake among Preschool-Aged Children in the Guelph Family Health Study: Associations with Sociodemographic Characteristics
Authors: Mahajan Anisha , Haines Jess , Yu Jessica , Darlington Gerarda , Buchholz Andrea C. , Duncan Alison M. , Ma David W. L. ,   on behalf of the Guelph Family Health Study
Published: August 2023

Background: It is crucial to develop strategies targeted to promote healthy eating patterns in vulnerable populations, especially young children from diverse sociodemographic groups. Thus, the study objective was to investigate the associations between child age, child sex, child ethnicity, parent number of years living in Canada, annual household income, parent education and parent marital status with total, free and added sugar intakes in young children. Methods: This cross-sectional study was a secondary analysis of data gathered in the Guelph Family Health Study. The study included 267 children (129M; 138F) from 210 families aged 1.5 to 5 years. Parents completed questionnaires for children on sociodemographic characteristics and an online 24-hour diet recall. The associations between sociodemographic characteristics and sugar intakes were determined using generalized estimating equations applied to linear regression models. Results: The mean age of the children was 3.5 ± 1.2 years (mean ± std dev.). As children’s age increased, there was a greater intake of free and added sugar (β^ = 8.6, p = 0.01, 95% CI = 2.4 to 14.7 and β^ = 6.5, p = 0.03, 95% CI = 0.8 to 12.2, respectively). Those children who identified as white had a higher total sugar intake than children of other ethnicities (β^ = 31.0, p = 0.01, 95% CI = 7.2 to 54.7). Additionally, higher annual household income was associated with lower was free sugar intake in children (β^ = −2.4, p = 0.02, 95% CI = −4.5 to −0.4). Conclusions: This study underscores the significant influence of multiple sociodemographic characteristics on sugar intake in young children, providing valuable insights for public health policy and nutrition interventions. Moreover, this study highlights the need for early behaviour interventions focusing on reducing sugar intake in young children, while considering sociodemographic factors.
Perceived Quality of Life and Life Satisfaction: Does the Role of Gender, Age, Skills, and Psychological Factors Remain Relevant after the COVID-19 Pandemic?
Authors: Branquinho Cátia , Moraes Bárbara , Noronha Catarina , Ferreira Tomás , Neto Rodrigues Nuno , Gaspar de Matos Margarida
Published: August 2023

Background: After two years of psychological, physical, social, economic, environmental, and societal challenges, this paper examines the psychological health and well-being of Portuguese students based on their socioemotional skills (SSES), positive youth development (PYD), depression, anxiety, and stress (DASS), as well as the relationship between these variables and their influence on perceived quality of life and life satisfaction. Methods: This study examined 3235 students from lower to upper secondary, half of whom were female (M = 14.46 ± 1.883 years old). Using SPSS software, descriptive statistics were determined for all variables; mean differences between age and gender were found using ANOVA and the post hoc Scheffe test. Linear regressions with the Enter method were used to study how to predict perceived quality of life and satisfaction with life. Results: Males had scores indicating more SSES|optimism, emotional control, resilience, confidence, sociability, creativity, energy, a sense of belonging to school, and PYD. Girls had better skills for cooperating and relating to teachers but more test anxiety and DASS. Younger adolescents had better psychological health, greater skills, and a better perception of quality of life and life satisfaction when compared to older adolescents. Age, gender, SSES, PYD, and the DASS variables can explain 69% of the variance in life satisfaction, while these variables can explain 60.5% of the variance in perceived quality of life. Conclusions: These results point to the relevance of SSES for psychological health and well-being, suggesting that interventions should focus on promoting these variables, paying special attention to female gender and age-related challenges.
Genital GVHD in Female Children and Adolescents: A Systematic Review of Case Reports and Case Series
Authors: Tsimeki Maria , Tsimpidakis Antonios , Roidi Stella , Gregoriadis Themos , Soldatou Alexandra , Kitra Vasiliki , Michala Lina
Published: August 2023

Genital graft-versus-host disease (GVHD) after hematopoietic stem cell transplantation (HSCT) is an underdiagnosed manifestation of chronic GVHD. Few articles have been published in pediatric populations, and there are no established guidelines for the management of this condition in children. This study aims to provide a systematic literature review of the published studies and cases of genital (vulvovaginal) GVHD in girls and adolescents post HSCT, with a focus on the time of diagnosis and clinical manifestations. The authors searched for English-language articles published after 1990, which included full patient details. Thirty-two cases of female patients under 20 years of age were identified. The median time of diagnosis was 381 days (IQR: 226–730 days), and 83% of patients developed Grade 3 vulvovaginal GVHD. Based on these observations, an early pediatric gynecologic examination of these patients, soon within the first year after HSCT, could be suggested for early diagnosis, treatment initiation and prevention of long-term complications.
Consistently High Frequency of Scooter Injuries in Children—Retrospective Data Analysis in a Level I Trauma Centre
Authors: Schuller Andrea , Hohensteiner Anna , Sator Thomas , Pichler Lorenz , Dangl Theresia , Nass Cornelia , Jaindl Manuela , Schwendenwein Elisabeth , Tiefenboeck Thomas M. , Payr Stephan
Published: August 2023

The aim of this retrospective study was to present an epidemiological overview of paediatric nonelectric-scooter-related injuries, focusing on changes in injury mechanism and frequency. A retrospective, descriptive data analysis at a Level I trauma centre, including patients aged from 0 to 18 years injured by riding nonelectric scooters, was performed. The observation period ranged from January 2015 to December 2022. The total study population consisted of 983 (mean age: 7.9 ± 4.0 years) children and adolescents, with most patients being male (800/983; 81.4%). The frequency of nonelectric scooter injuries was relatively consistent over the observation period. Patients sustained mostly minor injuries (lacerations, bone contusions, sprains) (527/983; 53.6%), followed by head injuries (238/983; 24.5%), limb fractures (166/983; 16.9%) and trunk injuries (52/983; 5.3%). However, a few patients sustained severe injuries, including skull fractures (7/238; 2.9%), intracranial haematoma (4/238; 1.7%) or lacerations of abdominal organs (4/52; 7.7%). This study presented a consistently high frequency of scooter injuries in children. Children under 15 years were the most affected by scooter-related injuries. Although most injuries were minor, serious injuries occurred that should not be underestimated. Hence, we emphasise the use of protection gear and recommend raising awareness among parents and children.
Body Mass Index, Physical Activity, Cardiorespiratory Endurance and Quality of Life among Children with Physical Disabilities
Authors: Supramaniam Nimale , Zanudin Asfarina , Azmi Nor Azura
Published: August 2023

Background: Children with physical disabilities (PD) have reduced levels of physical activity (PA) compared to typically developing children, which increases their risk of becoming overweight and obese, which leads to numerous adverse health consequences. This study aimed to determine the differences between groups classified by body mass index (BMI) percentile in terms of PA levels, cardiorespiratory endurance and quality of life (QoL), and also to evaluate the relationship between BMI percentile and PA levels, cardiorespiratory endurance and QoL in children and adolescents with physical disabilities. Methods: A total of 172 children and adolescents with PD aged between 5 and 17 years from Hospital Tunku Azizah were included in this cross-sectional study. The BMI percentile was calculated to determine the weight status. PA levels were assessed with the Physical Activity Questionnaire for Older Children (PAQ-C), cardiorespiratory endurance was measured by the Six-Minute Walk Test (6MWT) and QoL was measured by the Paediatric Quality of Life Inventory version 2.0 (PedsQL 2.0). Results: According to the BMI percentile, 70.3% had a healthy BMI percentile (50th to 84th percentile), 11.6% were overweight (50th to 84th percentile), 11% were underweight (0–49th percentile) and 7.0% were obese (95th percentile and above). Most children reported a healthy weight, and the rates of being overweight and obese were higher in children who could ambulate without aids (6.4% and 3.5%, respectively) compared to those who used walking aids (5.2% and 3.5%, respectively). Significant differences were found in the PAQ-C, 6MWT and PedsQL 2.0 scores between different BMI percentile groups (p < 0.05). There were also significant correlations between the BMI percentile and the PAQ-C (r = 0.209, p < 0.001), 6MWT (r = 0.217, p < 0.001) and PedsQL 2.0 (r = 0.189, p < 0.001). Conclusion: The rate of being overweight and obese is greater among children who ambulate without aids than among those with aids. An increase in the BMI percentile can reduce the QoL in different ways. This study suggests that children with PD who can walk without aids are at a greater risk of being overweight and obese. Hence, the engagement of this population in PA is crucial for their weight management.
Increasing Vaccine Uptake during Pregnancy by Using Prenatal Education Classes: An Effective Tool for Health Communication and Promotion
Authors: Triunfo Stefania , Perossini Silvia , Burdin Esther , De Angeli Elena Claudia , Francesi Maria , Garolfi Alessandra , Moretti Jessica , Paruscio Ilenia , Tassielli Miriam , Tremolada Marta , Gemelli Simona , Pedrina Deborah , Marconi Anna Maria
Published: August 2023

Childbirth education classes represent an antenatal tool for supporting pregnant women and couples in increasing knowledge on pregnancy, delivery, breastfeeding, and newborn care. The aim of this study was to investigate the impact of an additional lesson during the prenatal course regarding the advantage of vaccination to mitigation of maternal anxiety. An observational study was designed that included participants in childbirth education classes and compared courses enhanced by the extra lesson on vaccination during pregnancy versus those who did not receive it. Assessment of the impact of prenatal educational on vaccination was measured by using validated questionnaires (State-Trait Anxiety Inventory, STAI; Perceived Stress Scale, PSS; World Health Organization- Five Well-Being Index, WHO-5). A total of 145 pregnant women participated to the investigation by answering to the online survey. Of them, 33 patients (22.8%) belonged to the course without a lesson on vaccine, while 112 (77.2%) participated to online prenatal education that included an additional meeting on the usefulness of getting vaccinated during pregnancy. No statistical differences were found between study groups in terms of demographics and perinatal outcomes. Participants in the enriched course reported lower basal anxiety levels than those without the vaccine lesson (STAI-State, normal score < 40, 30 vs. 19%, p-value 0.041; STAI-State, mild score 40–50, 78 vs. 67%, p-value 0.037). With reference to the prior two weeks, maternal wellbeing level was improved by the added class (score > 13 as measurement of wellbeing: 62% vs. 80%, p-value < 0.05). Moderate perceived stress assessed by PSS was found in those pregnant women without prenatal education on vaccination (64 vs. 50%, p-value 0.042). The introduction of a lesson regarding vaccination during pregnancy in the program of prenatal education courses improved maternal anxiety levels and wellbeing, in addition to reducing perceived stress.
The Effect of Food Allergen Exclusion on the Growth of Saudi Children
Authors: Bin Obaid Manar Abdulaziz , AlSedairy Sahar Abdulaziz , Alghamdi Hamza Ali , Aljameel Ghzail M. , Alidrissi Eman , AlZahrani Mofareh , Binobead Manal Abdulaziz
Published: August 2023

With a variety of symptoms that can impede children’s development, food allergies are an important public health concern. With the help of information from the King Fahad Medical City Hospital in Riyadh, we looked at how restricting certain foods affected the growth of Saudi children who had food allergies. An anonymous self-administered questionnaire asking about the individuals’ demographics and their restricted eating habits was completed by 72 children (48 boys and 24 girls) between the ages of 2 and 14. The sensitivity of six allergens (hen eggs, cow milk, fish, wheat, peanuts, and soybeans), anthropometric indices, specific Immunoglobulin E (IgE) levels, and sensitivity were examined. The Statistical Package for Social Science (SPSS), version 26, was used to analyze the data. Chi-square and t-tests were used to examine the relationships between various category variables. According to the findings, most of the mothers of the children were between the ages of 30 and 40 (80.6%), had a college degree (72.3%), were unemployed (59.7%), and had a monthly family income between 5000 and 15,000 SAR (69.4%). Both sexes had specific IgE antibodies for allergens in classes 2 and 3, with boys having noticeably (p ≤ 0.05) higher quantities than girls. While females were more sensitive to fish and peanuts, boys were more likely than girls to show specific IgE sensitivity to egg white, cow milk, wheat, and soybeans. Both sexes’ allergy levels were considerably (p ≤ 0.01) higher in children aged 5.01 to 10 than in other age groups. In terms of classifications of thinness, overweightness, and obesity, boys were slenderer than girls, and a greater percentage of boys than girls were overweight or obese. The exclusion of hen eggs, cow milk, wheat, and peanuts from the diet had a significant and detrimental effect on body mass index (BMI) and height-for-age ratio among children with impaired growth, in contrast to the demographic factors, which had a significant and favorable effect on the growth of other children. In conclusion, restrictions on food allergens impairs growth in Saudi children, particularly boys’ growth.
Projections of Changes in Atmospheric Conditions Leading to Storm Surges along the Coast of Santos, Brazil
Authors: Sondermann Marcely , Chou Sin Chan , Tavares Priscila , Lyra André , Marengo José A. , Souza Celia Regina de Gouveia
Published: August 2023

This study aims to assess the changes in the atmospheric conditions favorable to storm surges over the Santos Coast in Southeast Brazil. Storm surges can favor high sea level rises and coastal erosion, affecting people and strategic structures in coastal areas. The assessment of the atmospheric conditions was based on the downscaling of climate simulations of the Brazilian Earth System Model by the Eta regional climate model at higher spatial resolution. The detection scheme used by the model was able to reproduce the three observed atmospheric patterns favorable to storm surges found by recent studies: Pattern 1 is characterized by a cyclone on the synoptic scale over the ocean; Pattern 2 presents an intense wind fetch from the southeast; Pattern 3 is characterized by winds parallel to the coast. The simulations underestimated the number of cases in Patterns 1 and 2. However, it overestimated the number of days in Pattern 3. The model presented more intense winds in the three patterns. The storm surges characterized by Pattern 1 will become more intense. However, it will be equal to or less frequent. In Pattern 2, the number of events will decrease. Nevertheless, these episodes will be associated with more precipitation along the coastline. Pattern 3 will have a similar number of storm surges.
Features of Tribooxidation of the High-Entropy Coating (AlCrZrTiTa)N during Dry High-Speed Cutting
Authors: Kovalev Anatoly , Wainstein Dmitry , Konovalov Egor , Vakhrushev Vladimir , Fox-Rabinovich German , Fox-Rabinovich Michael , Dmitrievskii Stanislav , Tomchuk Alexandr
Published: August 2023

The high-entropy PVD coating (AlCrZrTiTa)N, characterized by its high hardness (50–60 GPa), elastic modulus above 300 MPa, and high heat resistance up to 1300 °C, is used for coating cutting tools operating under extreme metalworking conditions. The nanostructured monolayer 3 μm PVD coating was deposited on cutting plates in the hybrid arc deposition PVD coater. The coating had an amorphous nanocrystalline microstructure with a grain size of about 10–50 nm. The samples of SS 304 steel were investigated during dry high-speed (600 m/min) cutting. Raman spectroscopy was used to study the formation of tribooxides on the tool surface at the running-in stage of the cutting. After 130 m of cutting, Cr2O3 oxide appears on the wear surface while other elements are bound with N atoms. When the cutting length is increased to up to 260 m, oxide Al2O3 · ZrO2 (mullite) and amorphous oxides TaO2 and CrO2 are formed. The method EELFS made it possible to determine the amorphous nanocrystalline structure of triboceramics based on CrO2 and Al2O3 · ZrO2. The nearest atomic surrounding of Cr-Cr, O-O, and Cr-O and their subsequent comparison with the available literature data allow us to calculate the equilibrium lattice constants of the CrO2 unit cell, which are equal to (a, b) = 4.3754 Å and c = 0.5927. The triboceramic films on the base of non-equilibrium mullite Al2O3·ZrO2 have an amorphous structure. In the first coordination sphere, the interatomic distances of Zr-O and Al-O were 1.79 and 1.89 Å. An accelerated adaptive reaction to extreme external stimuli, at the very beginning of the running-in stage, is established. The tribological adaptability of the high-entropy ultra-fine amorphous nanocrystalline coating under extremely loaded dry high-speed cutting is based on non-equilibrium phenomena: the partial oxidation of fragments of the nitride and dynamic formation of protective tribooxides, which have a good thermal barrier and frictional properties. These factors interact synergistically and determine the life of the cutting tool.
Imidazol(in)ium-2-Thiocarboxylate Zwitterion Ligands: Structural Aspects in Coordination Complexes
Authors: Elorriaga David , Parra-Cadenas Blanca , Pérez-Ramos Paula , Soengas Raquel G. , Carrillo-Hermosilla Fernando , Rodríguez-Solla Humberto
Published: August 2023

Azolium-2-thiocarboxylate zwitterion ligands have emerged as a promising class of compounds in the field of coordination chemistry due to their unique structural features and versatile applications. These ligands are characterized by a positively charged azolium ring and a negatively charged thiocarboxylate moiety, making them capable of forming stable coordination complexes with various metal ions. One of the key structural aspects that make these ligands attractive for coordination chemistry is their ability to adopt diverse coordination modes with metal centers. The nature of these ligands enables them to engage in both monodentate and bidentate coordination, resulting in the formation of chelated complexes with enhanced stability and controlled geometry or the formation of polynuclear structures. This versatility in coordination behavior allows for the design of tailored ligands with specific metal-binding preferences, enabling the creation of unique and finely tuned coordination architectures. The azolium-2-thiocarboxylate zwitterionic ligands offer a promising platform for the design of coordination complexes with diverse structural architectures.
Effects of Sintering Processes on Microstructure Evolution, Crystallite, and Grain Growth of MoO2 Powder
Authors: Lee Jongbeom , Jeong Jinyoung , Lee Hyowon , Park Jaesoung , Jang Jinman , Jeong Haguk
Published: August 2023

MoO2 micro-powders with a mean pore size of 3.4 nm and specific surface area of 2.5 g/cm3 were compacted by dry pressing, then pressureless sintered at a temperature of 1000–1150 °C for 2 h or for a sintering time of 0.5–12 h at 1050 °C in an N2 atmosphere. Then, their microstructure evolution for morphology, crystallite, and grain growth were investigated. By sintering at a certain temperature and times, the irregular shape of the MoO2 powders transformed into an equiaxed structure, owing to the surface energy, which contributed to faster grain growth at the initial stage of sintering. The crystallite and grain sizes exponentially increased with the sintering time, and the growth exponent, n, was approximately 2.8 and 4, respectively. This indicates that the crystallite growth is governed by dislocation-mediated lattice diffusion, and the grain growth is determined by surface diffusion-controlled pore mobility. The increase in sintering temperature increased both crystallite and grain size, which obeyed the Arrhenius equation, and the activation energies were determined to be 95.65 and 76.95 kJmol−1 for crystallite and grain growths, respectively.
Palliative Gastrectomy Improves the Survival of Patients with Metastatic Early-Onset Gastric Cancer: A Retrospective Cohort Study
Authors: An Hang , Wang Peng-Yuan , Liu Yu-Cun
Published: August 2023

Background: Recent studies have found that patients with incurable gastric cancer might benefit from palliative gastrectomy, but the impact of palliative gastrectomy on metastatic early-onset gastric cancer (mEOGC) patients remains unclear. Methods: We analyzed mEOGC patients enrolled in the Surveillance, Epidemiology, and End Results registry from January 2004 to December 2018. Propensity score matching (PSM) analysis with 1:1 matching and the nearest-neighbor matching method were used to ensure well-balanced characteristics between the groups of patients with palliative gastrectomy and those without surgery. Kaplan–Meier survival analysis and Cox proportional hazards regression models were used to evaluate the overall survival (OS) and cause-specific survival (CSS) risk with corresponding 95% confidence intervals (CIs). Results: Of 3641 mEOGC patients, 442 (12.1%) received palliative gastrectomy. After PSM, 596 patients were included in the analysis, with 298 in each group. For the matched cohort, the median survival was 8 months, and the 5-year survival was 4.0%. The median OS of mEOGC patients undergoing palliative gastrectomy was significantly longer than that of patients without surgery (13 months vs. 6 months, p < 0.001), and palliative gastrectomy remained an independent protective factor after adjusting for confounders (HR 0.459, 95% CI 0.382–0.552, p < 0.001), and the protective effect was robust in the subgroup analysis. Similar results were indicated in CSS. Stratified analyses by treatment modality also warranted the superiority of palliative-gastrectomy-based treatment in improving OS and CSS. Conclusions: mEOGC patients with palliative gastrectomy had a significantly longer survival time than patients without surgery. Exploratory analysis confirmed that surgery-based therapy modality was superior in improving survival time.
From Cultural Safety to Anti-Racism: Reflections on Addressing Inequities in Palliative Care
Authors: Bulle Seana , Arya Amit , Dosani Naheed
Published: August 2023

The purpose of palliative care is to ease the suffering of individuals with a serious and often life-limiting illness throughout the course of their disease by providing holistic care that considers the physical, spiritual, and psychosocial dimensions of health and well-being. Research shows that a palliative approach to care is cost-effective for the healthcare system and results in improved quality of life for patients and their loved ones. However, it is well-documented in the literature that structurally vulnerable populations have greater difficulty accessing equitable and culturally safe palliative care. Several domains are identified as contributing factors to the disparities seen in the literature, including systemic racism, cultural differences around death and suffering, and language barriers. Although Canada has had a national palliative care framework since 2018, ongoing issues of access and equity continue to disproportionately impact certain groups, including racially marginalized, immigrant, and low-income communities. In this commentary, successes and ongoing gaps in providing culturally safe and anti-racist palliative care are explored. In these proposed interventions, we advocate for a palliative approach to care that is grounded in equity, justice, and human rights.
An Update of Knowledge of the Bacterial Assemblages Associated with the Mexican Caribbean Corals Acropora palmata, Orbicella faveolata, and Porites porites
Authors: Hernández-Zulueta Joicye , Díaz-Pérez Leopoldo , Echeverría-Vega Alex , Nava-Martínez Gabriela Georgina , García-Salgado Miguel Ángel , Rodríguez-Zaragoza Fabián A.
Published: August 2023

In this study, the bacterial microbiota associated with apparently healthy corals of Acropora palmata, Orbicella faveolata, and Porites porites and the surrounding seawater and sediment were evaluated via the MiSeq Illumina sequencing of the V4 region of 16S rRNA at three reef sites in the Mexican Caribbean. Bacterial assemblages associated with apparently healthy corals and sediments showed no significant differences between sites. The colonies of A. palmata showed a dominance of families Amoebophilaceae, Spirochaetaceae, Myxococcaceae, and Cyclobacteriaceae. Meanwhile, the colonies of O. faveolata and P. porites revealed a high prevalence of the Rhodobacteraceae and Kiloniellaceae families. The families Rhodobacteraceae, Cryomorphaceae, Cyanobiaceae, and Flavobacteriaceae were predominant in seawater samples, while Pirellulaceae, Nitrosococcaceae, and Woeseiaceae were predominant in sediments. Variations in A. palmata bacterial assemblages were correlated with salinity, sea surface temperature, and depth. These variables, along with nitrate, phosphate, and ammonium concentrations, were also correlated with changes in the bacterial composition of P. porites, seawater, and sediments. However, none of the environmental variables were related to the bacterial taxa of O. faveolata. Aerobic chemoheterotrophy and fermentation, followed by nitrate reduction and ureolysis, were the metabolic functions with the highest occurrence in the bacterial assemblages associated with all substrates.