bluuebunny/crossref_metadata_2025 huggingface dataset:
The Flammability and Thermal Stability of Filling Epoxy Foam Plastics for Construction Purposes
Authors: Samchenko Svetlana , Ushkov Maxim , Erofeev Vladimir , Ushkov Valentin , Stepina Irina
Published: October 2024

An effective type of polymer heat-insulating material (foams) based on reactive oligomers is casting epoxy foams with high technological and operational parameters. However, polyepoxide foams are highly flammable, which significantly restrains their application in the construction industry. The aim of this work was to develop effective methods for reducing the flammability of filling epoxy foams. In order to achieve the objective, the following objectives were addressed: determining the influence of the chemical nature and content of additive and reactive bromine- and phosphorus-containing compounds on the thermal stability, flammability and operational properties of filling epoxy foams, and the development of polyepoxy foams of reduced flammability with high-quality physical and mechanical characteristics. When estimating the flammability of epoxy foams, we used both state-approved methods and the methods described in scientific and technical literature. The thermal properties of epoxy foams were studied with the help of multimodular thermoanalytical complex DuPont-9900. The data on the influence of the apparent density of foams and oxygen concentration in the oxidant flow on the flame propagation speed on the horizontal surface of polyepoxy foams are presented. It was revealed that the chemical nature of amine hardeners does not affect the thermal stability and flammability of epoxy foams. It was established that phosphate plasticizers are ineffective flame retardants of foamed epoxy resin, and the chemical structure of additive organobromic flame retardants insignificantly affects their efficiency. It was shown that microencapsulated flame retardants are inferior in flame retardant efficiency to additive flame retardants. It was found that effective flame retardants for casting polyepoxy foams are phosphorus-containing oligoether methacrylate and epoxidized waste from the production of tetrabromodiphenylpropane. The results of this research will form the basis for the production of an experimental industrial batch of samples of pouring epoxy foams of reduced flammability.
Multiscale Analysis of Surface Topography for Engineering Applications in the Casting Industry
Authors: Gogolewski Damian , Kozior Tomasz , Zmarzły Paweł
Published: October 2024

This paper presents the results of studies aimed at assessing the impact of the molding process on the variability of surface irregularities of casting models. This research was conducted using a selected multiscale method, i.e., wavelet transformation, in both discrete and continuous perspective. The test samples were made both based on traditional methods of manufacturing casting models, i.e., machining of aluminum and wood, as well as using three additive technologies. The impact of the forming process on the variability of the topography of the produced models was evaluated. This research comprehensively relates to the assessment of the applicability of additive technologies, which are increasingly used in various industrial areas, as well as the impact of the process on surface topography in relation to scale. The statistical assessment based on the ANOVA analysis demonstrated that it is possible to distinguish between the surfaces before and after a specific number of forming cycles. Studies have shown that the impact of the forming process is relatively small, mainly affecting the long-term irregularity components, and there are no functional dependencies in terms of the impact of the forming process on the variation in surface topography in relation to the manufacturing method or its parameters.
Microstructure and Properties of Aluminum Alloy/Diamond Composite Materials Prepared by Laser Cladding
Authors: Huang Shuhui , Zhao Yilin , Xie Haofeng , Guo Hong , Peng Lijun , Zhang Wenjing
Published: October 2024

In this article, AlSi10Mg aluminum alloy was used as the substrate to prepare aluminum alloy/diamond composite materials with laser cladding technology. The effects of the composition and laser power on the microstructure and thermal properties of the composite materials were studied. The results show that the prefabrication of tungsten carbide layer on the diamond surface enhances the wettability of diamond with aluminum alloy and reduces the laser reflection, which ensures the implementability of laser cladding technology for the preparation of aluminum alloy/diamond composites. The laser power and components determine the temperature of the molten pool and thus the state of the organization of the composite material to be formed by cladding. With the increase in the diamond content, the density, specific heat, mechanical properties, and average linear thermal expansion coefficient of the composite material gradually decrease, while the thermal conductivity first increases and then decreases. The thermal conductivity of the aluminum alloy/diamond composite material prepared by laser cladding is 200.68 W/mK, and the linear thermal expansion coefficient is 1.904 × 10−5/K, which are superior to those of the matrix AlSi10Mg aluminum alloy.
Prediction and Analysis of Borosilicate Glass Surface Deformation Induced by Flame Jet
Authors: Wang Biling , Zhai Yutang , Zhang Xinming , Qi Xinxin , Fu Weijie
Published: October 2024

To address the issues of low processing efficiency, poor forming accuracy, and internal damage in glass material processing, this study proposes the use of flame jet forming. However, the mechanism of flame jet processing requires further elucidation. This research investigates the relationship between the indentation morphology on the glass surface and the inlet velocity of the flame jet. A theoretical model was established through mathematical analysis to reflect this relationship. The model’s accuracy was validated using numerical simulation methods. By comparing experimental data with theoretical model results, surface tension was incorporated, and the model was iteratively optimized using MATLAB R2024a. The final optimized model demonstrated an absolute error range of 0.009 to 0.069 mm. This study confirms the feasibility of flame jet processing and enriches the understanding of its mechanism, providing a novel, efficient, and precise method for processing glass materials.
Disconnected Stationary Solutions in 3D Kolmogorov Flow and Their Relation to Chaotic Dynamics
Authors: Evstigneev Nikolay M. , Karamysheva Taisia V. , Magnitskii Nikolai A. , Ryabkov Oleg I.
Published: October 2024

This paper aims to investigate the nonlinear transition to turbulence in generalized 3D Kolmogorov flow. The difference between this and classical Kolmogorov flow is that the forcing term in the x direction sin(y) is replaced with sin(y)cos(z). This drastically complicates the problem. First, a stability analysis is performed by deriving the analog of the Orr–Sommerfeld equation. It is shown that for infinite stretching, the flow is stable, contrary to classical forcing. Next, a neutral curve is constructed, and the stability of the main solution is analyzed. It is shown that for the cubic domain, the main solution is linearly stable, at least for 0<R≤100. Next, we turn our attention to the numerical investigation of the solutions in the cubic domain. The main feature of this problem is that it is spatially periodic, allowing one to apply a relatively simple pseudo-spectral numerical method for its investigation. We apply the method of deflation to find distinct solutions in the discrete system and the method of arc length continuation to trace the bifurcation solution branches. Such solutions are called disconnected solutions if these are solutions not connected to the branch of the main solution. We investigate the influence of disconnected solutions on the dynamics of the system. It is demonstrated that when disconnected solutions are formed, the nonlinear transition to turbulence is possible, and dangerous initial conditions are these disconnected solutions.
Risk Factor Analysis Including Inflammatory Markers for ICU Admission and Survival After Pneumonectomy
Authors: Turktan Mediha , Gulec Ersel , Avcı Alper , Hatıpoglu Zehra , Unal Ilker
Published: October 2024

Background and Objectives: To assess the impact of preoperative inflammatory parameters on the necessity for intensive care unit (ICU) admission and survival after pneumonectomy. Materials and Methods: We enrolled 207 adult patients who underwent pneumonectomy between December 2016 and January 2022. We collected data from patients’ electronic medical records. Results: The preoperative albumin level was statistically lower, need for blood transfusion was higher, and length of hospital stay was longer in ICU-admitted patients (p = 0.017, p = 0.020, and p = 0.026, respectively). In multivariate analysis, intra-pericardial pneumonectomy and postoperative complications were predictive factors for ICU admission (OR = 3.46; 95%CI: 1.45–8.23; p = 0.005 and OR = 5.10; 95%CI: 2.21–11.79; p < 0.001, respectively). Sleeve or pericardial pneumonectomy (p = 0.010), intraoperative vascular injury (p = 0.003), the need for mechanical ventilation (p < 0.001), acute renal failure (p = 0.018), sepsis (p = 0.008), respiratory failure (p < 0.001), pneumonia (p = 0.025), the need for blood transfusion (p = 0.047), elevated blood urea nitrogen (BUN) (p = 0.046), and elevated creatinine levels (p = 0.004) were more common in patients who died within 28 days. Patients who died within 90 days exhibited higher preoperative neutrophil-to-lymphocyte ratio (NLR) values (p = 0.019) and serum creatinine levels (p = 0.008), had a greater prevalence of sleeve or intra-pericardial pneumonectomy (p = 0.002), the need for mechanical ventilation (p < 0.001), intraoperative vascular injury (p = 0.049), sepsis (p < 0.001), respiratory failure (p = 0.019), and contralateral pneumonia (p = 0.008) than those who did not. Conclusions: Intra-pericardial pneumonectomy and postoperative complications are independent predictors of ICU admission after pneumonectomy. Tracheal sleeve and intra-pericardial procedures, intraoperative and postoperative complications, the need for blood transfusion, preoperative NLR ratio, BUN and creatinine levels may also be potential risk factors for mortality.
Impact of Infrabony Defects Treatment on Periodontal Markers and Glycated Hemoglobin Using Platelet-Rich Fibrin, Guided Tissue Regeneration, and Access-Flap Surgery
Authors: Stefanescu Ada , Sufaru Irina-Georgeta , Martu Cristian , Anton Diana-Maria , Rotundu Gabriel , Earar Kamel
Published: October 2024

Background and Objectives: This study evaluated the outcomes of single open-flap debridement, open-flap debridement (OFD) plus resorbable membrane placement, and OFD with resorbable membrane placement plus platelet-rich fibrin (PRF) in terms of periodontal clinical parameters and glycated hemoglobin (HbA1c) levels in 24 adult patients with stage 3 grade C periodontitis and type II diabetes mellitus. Materials and Methods: The primary outcome measure for this study was the clinical attachment level (CAL); secondary outcomes included additional periodontal parameters, such as the plaque index (PI), bleeding on probing (BOP), probing depth (PD), as well as glycated hemoglobin (HbA1c) levels to evaluate the systemic impact of the treatments on glycemic control. The parameters were assessed before and at three and six months post-surgery. In Group A, the flap was sutured closed; in Group B, an absorbable collagen membrane was placed over the defect; and in Group C, PRF was utilized in the defect, with two additional PRF membranes used to cover the defect. The wound healing index (WHI) was recorded at 7 and 14 days after the surgery. Results: The initial findings indicated no significant differences in the periodontal parameters among the three groups. However, improvements in the PD and CAL were most notable in Group C, followed by Group B, with Group A showing the slightest improvement. At six months, there was a highly significant difference in the CAL (p < 0.001). Group C (4.92 ± 0.35) and Group B (4.99 ± 0.31) demonstrated the most significant improvements in the CAL compared to Group A (5.89 ± 0.57). At seven days post-surgery, Group C demonstrated significant healing, with 85% of the sites showing complete healing. By the 14-day mark, all sites in Group C indicated complete healing. Although the HbA1c values did not exhibit statistically significant differences among the groups at baseline, at the 6-month evaluation, all groups showed significantly lower values than baseline. However, the comparison between groups revealed significantly improved values for Group C. Conclusions: The study’s results suggest that PRF is an exceptional material for infrabony defects treatment and notably improves HbA1c levels.
Process of Reliability of the Ventilatory Workload Kinetic Index and Prioritization in the Intrahospital Clinical Setting
Authors: Godoy-Abarca Loretto , Muñoz-Vega Andrea , Pinochet Urzúa Ramón , del Sol Mariano , Escobar-Cabello Máximo , Valenzuela Vásquez Jorge , Valenzuela-Aedo Fernando , Díaz-Caro Camila , Soto-Rodríguez Francisco Javier , Muñoz-Cofré Rodrigo
Published: October 2024

Background and Objectives: The Ventilatory Workload Kinetic Index (VWKI) has been proposed as a clinical instrument to evaluate ventilatory balance–imbalance. However, the regulated application of scales that allow an integral evaluation of the object of study and their subsequent reliability evaluation should be continuous. The objective was to determine the reliability of the VWKI between two evaluators and its applicability in the clinical field of physiotherapy. Materials and Methods: The methodology was divided into three stages: (i) induction period, (ii) application of the VWKI, and (iii) assessment of reliability. Results: The VWKI total score obtained excellent inter-rater reliability (ICC = 0.913, p < 0.05). The airway resistance (AR) showed moderate inter-rater reliability (ICC = 0.528, p < 0.05), while the use of accessory musculature (UAM) showed poor inter-rater reliability (ICC = 0.483, p < 0.05). In the physiotherapy care prioritization system, for both evaluator A (EA) and evaluator B (EB), the total VWKI score was significantly higher in priority 1 (p = 0.001; p < 0.05, respectively). Regarding the total VWKI score by services, it was observed that both EA and EB rated the VWKI significantly higher in the intensive care unit (ICU) than in medicine and the other services (p = 0.001, p = 0.0001 and p < 0.05, p < 0.05, respectively). Conclusions: VWKI is highly reliable in the total score. It is also consistent with the system of prioritization of physiotherapy care and the ability to determine the severity of clinical respiratory symptoms.
Urethral Strictures After Endoscopic Enucleation of the Prostate and Its Associated Clinical Outcomes in Aging Men
Authors: Hou Chen-Pang , Wu Jen-Hsuan , Weng Shu-Chuan , Lin Yu-Hsiang , Chen Chien-Lun , Tsai Han-Yu , Chen Yu-Ting , Juang Horng-Heng
Published: October 2024

Background and Objectives: Benign prostatic hyperplasia is a common condition among aging men, leading to bladder outlet obstruction and associated lower urinary tract symptoms. Surgical intervention, particularly endoscopic enucleation of the prostate, has become increasingly popular over traditional methods such as transurethral resection of the prostate. However, urethral strictures remain a major postoperative complication. This study evaluated the incidence, risk factors, and clinical outcomes of urethral strictures after endoscopic enucleation of the prostate. Materials and Methods: This study retrospectively analyzed prospectively collected data from 246 patients who underwent either thulium laser enucleation of the prostate or bipolar transurethral enucleation of the prostate at Chang Gung Memorial Hospital between October 2018 and December 2022. Patients were evaluated preoperatively using uroflowmetry, International Prostate Symptom Score (IPSS), and other relevant clinical metrics. Follow-up assessments at 2 weeks, 3 months, and 6 months post-surgery included uroflowmetry, IPSS evaluation, and cystoscopy when indicated. A urethral stricture was deemed to be present if a 5.5 mm fiber cystoscope was unable to pass through the urethra. Results: Of the 246 patients, 23 (9.3%) developed urethral strictures, with the membranous urethra being the most common site (69.2%). Patients with strictures had significantly smaller prostate volumes and enucleated tissue weights, higher trial without catheter (TWOC) failure rates, and a higher postoperative urinary tract infection (UTI) incidence. Multivariate analysis identified smaller prostate size, lower resected tissue weight, TWOC failure, and postoperative UTI as significant risk factors for stricture formation. The type of energy source used for enucleation (bipolar or Thulium laser) was not identified as a factor influencing the incidence of urethral stricture. Conclusions: Urethral strictures constitute a major complication following endoscopic enucleation of the prostate, particularly in patients with smaller prostates and those experiencing postoperative complications such as UTIs and TWOC failure. These findings underscore the importance of careful surgical technique and rigorous postoperative monitoring to reduce the incidence of this complication.
Mitigating Membrane Fouling in Abattoir Wastewater Treatment: Integration of Pretreatment Step with Zwitterion Modified Graphene Oxide–Polyethersulfone Composite Membranes
Authors: Motloutsi Meladi L. , Matebese Funeka , Motsa Mxolisi M. , Managa Muthumuni , Moutloali Richard M.
Published: October 2024

Composite polyethersulfone (PES) membranes containing N-aminoethyl piperazine propane sulfonate (AEPPS)-modified graphene oxide (GO) were integrated with either of the two pretreatment processes (activated carbon (AC) adsorption or polyelectrolyte coagulation) to assess their effectiveness in mitigating membrane fouling during the treatment of abattoir wastewater. The AEPPS@GO-modified membranes, as compared to the pristine PES membranes, showed improved hydrophilicity, with water uptake increasing from 72 to 118%, surface porosity increasing from 2.34 to 27%, and pure water flux (PWF) increasing from 235 to 673 L.m−2h−1. The modified membranes presented improved antifouling properties, with the flux recovery ratio (FRR) increasing from 59.5 to 93.3%. This study compared the effectiveness of the two pretreatment processes, AC, coagulation, and the integrated system (coagulation/AC-UF membrane), in the removal of natural organic matter (NOM) and improvement of abattoir wastewater’s pH, electrical conductivity, TDS, and turbidity. The integrated systems produced improved water quality in terms of pH, EC, TDS, turbidity, and organic content. The fluorescence excitation–emission matrix (FEEM) analysis exhibited almost no fluorescence peak post-treatment following organic loading removal. The quality of the water met the South African non-potable water reuse standards. The sole membrane treatment systems exhibited good fouling resistance without the pretreatment systems; however, integrating these systems can offer extended longer filtration periods, thereby assisting in cost aspects of the abattoir wastewater treatment system.
Editorial for Special Issue “Casting Alloy Design and Characterization”
Authors: da Costa Eleani Maria , dos Santos Carlos Alexandre
Published: October 2024

Solidification, the genesis of metallic materials, is a complex phenomenon encompassing fluid flow, heat transfer, phase transformation, liquid–solid interface, solute redistribution, gas trapping, and others [...]
Research on Fault Prediction of Power Devices in Rod Control Power Cabinets Based on BiTCN-Attention Transfer Learning Model
Authors: Chen Zhi , Ye Liqi , Jian Yifan , Chen Meiyuan , Min Yuan
Published: October 2024

The Insulated Gate Bipolar Transistor (IGBT) is the key power device in the rod control power cabinet of nuclear power plants; its reliable operation is of great significance for ensuring the safe and economical operation of the nuclear power plants. Therefore, it is necessary to conduct fault prediction research on IGBT to achieve better condition-based maintenance and improve its operational reliability. However, power cabinets often operate under multiple, complex working conditions, so predicting IGBT faults from single working condition data usually has limitations and low accuracy. Its failure probability has an important relationship with the actual operating conditions of the cabinet. In order to improve the reliability and maintainability of the control power cabinet in nuclear power plants, this paper takes IGBTs in the rod control power cabinet as the object and makes full use of the data of IGBTs under multiple working conditions to carry out research on the cross-condition fault prediction of IGBTs under multiple-source working conditions. A transfer learning (TL) model based on a bidirectional time convolutional network (BiTCN) combined with attention was proposed to solve the problem of low accuracy of cross-operating fault prediction in a multi-source domain. Firstly, an IGBT fault simulation model was built to collect the life cycle state data of the module under different working conditions. Then, after pre-processing such as removing outliers, kernel principal component analysis (KPCA) was used to integrate all source domain data, obtain source domain characterization data, and train the BiTCN-attention model. Finally, the BiTCN-attention model trained in the source domain was transferred, and the model was fine-tuned according to the target domain data. Simulation results show that the accuracy of the proposed BiTCN-attention transfer learning prediction method can reach more than 99%, which is significantly better than that of the recurrent neural network transfer learning (RNN-TL) model, long short-term memory network transfer learning (LSTM-TL) model, gated cyclic unit transfer learning (GRU-TL) model, and time convolutional network transfer learning (TCN-TL) model. This method can not only reduce the inconsistency of fault characteristic values caused by changes in working conditions but also accurately predict the degradation trend when only early fault data are available, providing an effective solution for IGBT fault prediction across working conditions in multi-source domains.
Twenty Years of Lyme Borreliosis in the Netherlands: Temporal Trends in Seroprevalence and Risk Factors
Authors: Hoeve-Bakker B. , van den Berg Oda , Doppenberg H. , van der Klis Fiona , van den Wijngaard Cees , Kluytmans Jan , Thijsen Steven , Kerkhof Karen
Published: October 2024

Lyme borreliosis (LB) is not notifiable in many European countries, and the patchwork of surveillance strategies in Europe perpetuates knowledge gaps. In the Netherlands, LB incidence has been estimated from recurring general practitioner surveys since the 1990s. To complement the incidence data, this study aimed to estimate the prevalence of antibodies against Borrelia burgdorferi sensu lato in the general population of the Netherlands in 1995/1996, identify risk factors for seropositivity, and compare these findings to data from 2016/2017 to identify temporal trends. Sera from participants (n = 8041, aged 0–80 years) in a cross-sectional nationwide surveillance study were assessed for the presence of antibodies against B. burgdorferi s.l., using a screening ELISA and immunoblot confirmation. Risk factors associated with seropositivity were evaluated using multivariable analysis. A significant difference in weighted seroprevalence was observed between 1995/1996 (2.8%) and 2016/2017 (4.3%). In both cohorts, the seroprevalence was significantly higher among men than among women, and increased with age and tick bite frequency. The upward trend in age-specific seropositivity in individuals over 50 was steeper in 2016/2017 than in 1995/1996, possibly due to improved fitness among contemporary elderly, allowing increased outdoor activities. This study highlights significant trends in the seroprevalence of B. burgdorferi s.l. antibodies in the general population of the Netherlands over 20 years. The doubling of seroprevalence underscores the increasing burden of LB, and the importance of continued surveillance. Targeted interventions, particularly for elderly populations, may help raise awareness to the risks of tick bites and reduce the growing disease burden and societal costs associated with LB.
Magnetic Mineral Dissolution in Heqing Core Lacustrine Sediments and Its Paleoenvironment Significance
Authors: Lei Peng , Xu Xinwen , Yang Ziyi , Wang Qiongqiong , Hou Lirong , Jin Yi , Wu Qiubin
Published: October 2024

The magnetic parameters within lacustrine sediments serve as invaluable proxies for deciphering the paleoenvironmental and paleoclimatic conditions. However, the dissolution of magnetic minerals can significantly alter detrital magnetic mineral assemblages, thereby complicating their interpretation in paleoenvironmental reconstructions. In an effort to clarify the impact of this dissolution on the grain size of magnetic minerals in lacustrine sediments, we undertook a thorough analysis of the rock magnetic properties on samples from the interval characterized by low ARM (anhysteretic remanent magnetization)/SIRM (saturation isothermal remanent magnetization) values between 140 and 320 ka in the Heqing (HQ) lacustrine drill core, located in Southwest China. Temperature-dependent magnetic susceptibility and FORC diagrams revealed a predominance of single-vortex and pseudo-single domain (PSD) magnetite and maghemite within the sample. When compared to samples from both the glacial and interglacial periods, the high SIRM, elevated magnetic susceptibility, and low ARM/SIRM ratio intervals from 140 to 320 ka suggested a high concentration of magnetic minerals coupled with a relatively low concentration of fine-grained particles in the sediments. The reductive dissolution of the fine-grained magnetic oxides is responsible for the reduction in the fine-grained magnetic particles in this interval. Our findings indicate that pedogenic fine-grained magnetite and maghemite are the first to dissolve, followed by the dissolution of coarser-grained iron oxides into finer particles. This process underscores the complex interplay between magnetic mineral dissolution and grain size distribution in lacustrine sediments, with significant implications for the reliability of paleoenvironmental interpretations derived from magnetic parameters.
Effect of Rate-Dependent Breakage on Strength and Deformation of Granular Sample—A DEM Study
Authors: Das Soukat Kumar , Abuel-Naga Hossam
Published: October 2024

The mechanical response of granular materials is influenced significantly by both the magnitude and strain rate. While traditionally considered rate-independent in the quasi-static regime, granular media can exhibit rate effects in certain instances. This research uses two-dimensional discrete element modelling (DEM) to investigate the rate effects in one-dimensional compression tests by comparing non-crushable with crushable granular samples. This study indicates that micromechanical properties such as particle breakage and contact force distributions are predominant factors in dictating the macroscopic responses of the material. The DEM simulations highlight differences in macroscopic changes between crushable and non-crushable samples, demonstrating a clear correlation between mechanical properties and underlying microstructural features. Notably, the distribution of contact forces varies with strain rates, influencing the degree of particle breakage and, consequently, the overall rate-dependent behaviour. Further, this study explores the impact of post-breakage contact creation and progressive force redistribution, which contributes to observable differences in macroscopic stress under varying loading rates, which is quantified using coordination number, particle velocity, and fabric tensor profiles at two loading rates.
Investigating Physicochemical Methods to Recover Rare-Earth Elements from Appalachian Coals
Authors: Yesenchak Rachel , Montross Scott , Sharma Shikha
Published: October 2024

The demand for rare-earth elements is expected to grow due to their use in critical technologies, including those used for clean energy generation. There is growing interest in developing unconventional rare-earth element resources, such as coal and coal byproducts, to help secure domestic supplies of these elements. Within the U.S., Appalachian Basin coals are particularly enriched in rare-earth elements, but recovery of the elements is often impeded by a resistant aluminosilicate matrix. This study explores the use of calcination and sodium carbonate roasting pre-treatments combined with dilute acid leaching to recover rare-earth elements from Appalachian Basin coals and underclay. The results suggest that rare-earth element recovery after calcination is dependent on the original mineralogy of samples and that light rare-earth minerals may be more easily decomposed than heavy rare-earth minerals. Sodium carbonate roasting can enhance the recovery of both light and heavy rare-earth elements. Maximum recovery in this study, ranging from 70% to 84% of total rare-earth elements, was achieved using a combination of calcination and sodium carbonate roasting, followed by 0.25 M citric acid leaching.
Laser-Induced Breakdown Spectroscopy Applied to the Quantification of K, Ca, Mg and Mn Nutrients in Organo-Mineral, Mineral P Fertilizers and Rock Fertilizers
Authors: Cervantes Cesar , Marangoni Bruno S. , Nicolodelli Gustavo , Senesi Giorgio S. , Villas-Boas Paulino R. , Silva Caroline S. , Nogueira Ana Rita A. , Benites Vinicius M. , Milori Débora M. B. P.
Published: October 2024

A low-cost laser-induced breakdown spectroscopy (LIBS) instrument equipped with a charge-coupled device (CCD) was tested in the atmospheric environment for the quantification of K, Ca, Mg, and Mn in some organo–mineral fertilizers, mineral P fertilizers, and rock fertilizers of various compositions and origins, using flame atomic absorption spectrometry (FAAS) as the reference technique. The correlation analysis performed between each CCD pixel and the corresponding element concentration measured by FAAS allowed to choose the most appropriate K, Ca, Mg and Mn emission lines for LIBS analysis. The normalization process applied to LIBS spectra to correct physical matrix effects and small fluctuations was able to increase the linear correlation of the calibration curves between LIBS data and FAAS data by an average of 0.15 points of the R-value for all elements of interest. The R values of calibration curves were 0.97, 0.96, 0.86 and 0.84, for K, Ca, Mg and Mn, respectively. The limits of detection (LOD) were 66 mg/kg (K), 35 mg/kg (Ca), 5.4 mg/kg (Mg) and 0.8 mg/kg (Mn) when using LIBS in the quantification model. The cross-validation (leave-one-out) analysis yielded an absolute average error of 12% (K), 21% (Ca), 8% (Mg) and 13% (Mn) when LIBS data were correlated to FAAS ones. These results showed that the calibration models used were close to the optimization limit and satisfactory for K, Ca, Mg, and Mn quantification in the fertilizers and rocks examined.
Spontaneous Magnetization Induced by Antiferromagnetic Toroidal Ordering
Authors: Hayami Satoru
Published: October 2024

The magnetic toroidal dipole moment, which is induced by a vortex-type spin texture, manifests itself in parity-breaking physical phenomena, such as a linear magnetoelectric effect and nonreciprocal transport. We elucidate that a staggered alignment of the magnetic toroidal dipole can give rise to spontaneous magnetization even under antiferromagnetic structures. We demonstrate the emergence of uniform magnetization by considering the collinear antiferromagnetic structure with the staggered magnetic toroidal dipole moment on a bilayer zigzag chain. Based on the model calculations, we show that the interplay between the collinear antiferromagnetic mean field and relativistic spin-orbit coupling plays an important role in inducing the magnetization.
In Situ Transformed CoOOH@Co3S4 Heterostructured Catalyst for Highly Efficient Catalytic OER Application
Authors: Ahmed Abu Talha Aqueel , Sree Vijaya Gopalan , Meena Abhishek , Inamdar Akbar I. , Im Hyunsik , Cho Sangeun
Published: October 2024

The deprived electrochemical kinetics of the oxygen evolution reaction (OER) catalyst is the prime bottleneck and remains the major obstacle in the water electrolysis processes. Herein, a facile hydrothermal technique was implemented to form a freestanding polyhedron-like Co3O4 on the microporous architecture of Ni foam, its reaction kinetics enhanced through sulfide counterpart transformation in the presence of Na2S, and their catalytic OER performances comparatively investigated in 1 M KOH medium. The formed Co3S4 catalyst shows outstanding catalytic OER activity at a current density of 100 mA cm−2 by achieving a relatively low overpotential of 292 mV compared to the pure Co3O4 catalyst and the commercial IrO2 catalyst. This enhancement results from the improved active centers and conductivity, which boost the intrinsic reaction kinetics. Further, the optimized Co3S4 catalyst exhibits admirable prolonged durability up to 72 h at varied current rates with insignificant selectivity decay. The energy dispersive X-ray spectroscopy (EDX) and Raman spectra measured after the prolonged OER stability test reveal a partial transformation of the active catalyst into an oxyhydroxide phase (i.e., CoOOH@Co3S4), which acts as an active catalyst phase during the electrolysis process.
Optimization of Contact Pad Design for Silver Nanowire-Based Transparent Heater to Improve Heating Characteristics
Authors: Chu Seo Bum , Ma Yoohan , Jung Jinwook , Jo Sungjin , Hyun Dong Choon , Roh Jae-Seung , Kim Jongbok , Ko Dongwook
Published: October 2024

Transparent heaters are gaining significant attention for applications such as antifog glass, smart windows, and smart farm greenhouses. A transparent heater basically consists of transparent conducting materials that serve as a heating area and contact pad electrode to apply power. To fabricate a transparent heater, materials with excellent light transmittance and low sheet resistance are required. Among various transparent conducting materials, such as Indium Tin Oxide (ITO), carbon nanotube (CNT), graphene, and silver nanowires (AgNWs), AgNWs are particularly favored due to their good electrical, optical, and mechanical properties. However, in order to improve the heating characteristics of transparent heaters, research is essential not only on improving the properties of transparent conducting materials but also on the design of contact pad electrodes that can uniformly improve current distribution. Here, we explore various shapes of contact pad electrodes for AgNW-based transparent heaters to improve current distribution. Shapes such as line, spot, twisted, and parallel-type contact pad electrodes are designed and investigated to optimize overall heating characteristics. We analyze the heating properties of these transparent heaters with various contact pad electrodes, demonstrating how their specific shape and size affect heating characteristics and uniformity. We also investigate the optimal shape of the contact pad electrode to minimize transmission loss through UV-VIS spectroscopy. As a result, we confirm that the shape of the contact pad electrode was important for simultaneously achieving high heating characteristics of 120 °C, good heating uniformity, and over 80% transparency in an AgNW-based transparent heater.
The Superconducting Mechanism in BiS2-Based Superconductors: A Comprehensive Review with Focus on Point-Contact Spectroscopy
Authors: Romano Paola , Pelella Aniello , Di Bartolomeo Antonio , Giubileo Filippo
Published: October 2024

The family of BiS2-based superconductors has attracted considerable attention since their discovery in 2012 due to the unique structural and electronic properties of these materials. Several experimental and theoretical studies have been performed to explore the basic properties and the underlying mechanism for superconductivity. In this review, we discuss the current understanding of pairing symmetry in BiS2-based superconductors and particularly the role of point-contact spectroscopy in unravelling the mechanism underlying the superconducting state. We also review experimental results obtained with different techniques including angle-resolved photoemission spectroscopy, scanning tunnelling spectroscopy, specific heat measurements, and nuclear magnetic resonance spectroscopy. The integration of experimental results and theoretical predictions sheds light on the complex interplay between electronic correlations, spin fluctuations, and Fermi surface topology in determining the coupling mechanism. Finally, we highlight recent advances and future directions in the field of BiS2-based superconductors, underlining the potential technological applications.
Efficacy of Nusinersen Treatment in Type 1, 2, and 3 Spinal Muscular Atrophy: Real-World Data from a Single-Center Study
Authors: Lemska Anna , Ruminski Piotr , Szymarek Jakub , Studzinska Sylwia , Mazurkiewicz-Beldzinska Maria
Published: October 2024

Background: Spinal muscular atrophy (SMA) is an inherited neuromuscular disease characterized by progressive muscle weakness and atrophy due to the absence of the survival motor neuron 1 (SMN1) gene. SMA is classified into types 0 through 4 based on the age of symptom onset and the severity of motor function decline. Recent advances in SMA treatment, including nusinersen, onasemnogene abeparvovec, and risdiplam, have significantly improved the prognosis of SMA patients. This study evaluated the safety and efficacy of nusinersen in pediatric patients with SMA types 1, 2, and 3 in a real-world clinical setting. Methods: This prospective observational single-center study assessed the treatment effects of nusinersen in 23 pediatric patients with genetically confirmed SMA over a 22-month observation period. All the participants received intrathecal loading doses of 12 mg of nusinersen on days 1, 14, 28, and 63, followed by maintenance doses every four months. Functional assessments were conducted using the CHOP-INTEND scale. Data were collected during routine patient visits, including clinical laboratory tests and vital sign parameters, and adverse events were recorded. The inclusion criteria were defined by the national reimbursement program for nusinersen treatment in Poland. Results: Initially, 37 patients ranging from 1 month old to 18 years old were included, but 23 were ultimately observed due to changes in treatment regimens or assessment scales. The patients showed significantly improved CHOP-INTEND scores over the 22-month period. At 6 months, the average increase was 4.2 points, continuing to 17.8 points at 22 months. By the end of the study, 100% of patients showed either stabilization or improvement, with significant clinical improvements observed in several patients. Nusinersen was generally well-tolerated, with post-lumbar puncture headache and lower back pain being the most common adverse events. Conclusions: Nusinersen treatment significantly enhances motor function in pediatric patients with SMA types 1, 2, and 3. This study demonstrates the importance of early and sustained treatment, with most patients showing the continuous improvement or stabilization of motor function. These findings support the use of nusinersen as an effective therapy for SMA; however, further research is needed to understand the long-term outcomes and optimize treatment strategies.
Predictors of Food Insecurity and Food Assistance Program Usage Among Puerto Ricans Before and During the COVID-19 Pandemic in Holyoke, Massachusetts
Authors: Treloar Destiny , Taylor Dorceta , Bell Ashley
Published: October 2024

Background/Objectives: Puerto Rican households often face elevated rates of food insecurity. Frequently, households experiencing food insecurity turn to federal and emergency nutrition assistance for urgent or prolonged aid. This study analyzes factors influencing food insecurity and food assistance program involvement among Puerto Ricans in Holyoke, Massachusetts, amidst the COVID-19 pandemic. Methods: Using a combination of community-based participatory recruitment, purposive sampling, and web-based tools, we collected 284 survey responses. Our paper employed Pearson’s chi-square, logistic regression, and hierarchical linear models to assess relationships between demographic and household attributes and food access outcomes. Results: Variables such as having children in the household and age significantly influenced food relief participation and food insecurity outcomes. Puerto Rican heritage and low educational attainment were strong predictors of obtaining federal food aid. Low-income participants disproportionately faced food shortages and depended on emergency food initiatives. Our findings indicate that demographic and household factors significantly influence food insecurity and accessibility. Conclusions: Our study demonstrates that the pandemic made it challenging for households to obtain consistent, safe, and affordable nourishment. The impacts were unequally spread; hence, Puerto Rican communities and low-income groups were most affected.
Probiotic Milk and Oat Beverages with Increased Protein Content: Survival of Probiotic Bacteria Under Simulated In Vitro Digestion Conditions
Authors: Pawlos Małgorzata , Szajnar Katarzyna , Znamirowska-Piotrowska Agata
Published: October 2024

Background: The increasing prevalence of plant-based dietary preferences, driven by lactose intolerance, allergies, and adherence to vegan diets, has necessitated the exploration of alternative food matrices for probiotic delivery. Objectives: This study aimed to evaluate the effects of whey protein isolate, pea protein isolate, and soy protein isolate on the viability of L. casei and L. johnsonii during simulated in vitro gastrointestinal digestion. Furthermore, the study investigated the impact of two distinct matrices—cow’s milk and an oat-based beverage—on the survival of these probiotic strains. Fermented products were prepared using cow’s milk and an oat-based beverage as matrices, with simulated digestion performed following a seven-day storage period at 5 °C. The in vitro digestion model encompassed oral, gastric, and small intestinal phases, with probiotic viability assessed using the plate-deep method at each stage. Methods: Before digestion, L. casei exhibited higher populations than L. johnsonii in both matrices. Including 3% soy and pea protein, isolates promoted the growth of L. casei in both fermented milk and oat beverages. However, a marked reduction in probiotic viability was observed during the gastric phase, with L. casei counts decreasing by 6.4–7.8 log cfu g−1 in fermented milk and 3.1–4 log cfu g−1 in oat beverages, while L. johnsonii demonstrated similar reductions. Conclusion: These findings underscore the protective role of dairy components on probiotic viability, while the oat-based matrix exhibited a reduced capacity for sustaining probiotic populations throughout digestion. Future research should focus on optimizing plant-based matrices to enhance probiotic stability during gastrointestinal transit.
Low Caloric Intake Confers Cardiovascular Protection and Improves Functional Capacity Without Affecting Immunological Response in Sedentary Older Adults
Authors: Moura-Maia Meiry de Souza , Brill Boris , Paula-Vieira Rosa Helena Ramos , Ramos-Gomes Nycole Vieira , Melamed Dobroslav , Silva-Reis Anamei , Wolpp Eduarda Teodora Rachid , Moreira-Silva Naiara Nadia , Bella Yanesko Fernandes , Vieira Rodolfo P.
Published: October 2024

Background: Aging is characterized by a decline in the cardiovascular hemodynamic response, which may be aggravated by undernutrition. However, no study has evaluated whether low caloric intake may affect cardiovascular hemodynamics and its possible relation with functional capacity and immune response in older adults. Methods: Sixty-one older adults of both genders were enrolled in this study and were classified as normocaloric (n = 18) and hypocaloric (n = 43). All volunteers were evaluated for cardiovascular hemodynamics using impedance cardiography (PhysioFlow®); functional capacity by the 1′ sit-to-stand test with SpO2 monitoring; whole-blood analysis using an automated hematocytometer (Sysmex®); and levels of IL-6, TNF-alpha, IL-10, and Klotho by ELISA. Results: The hypocaloric group presented impaired functional capacity, measured by a reduced number of sit-to-stand repetitions (p < 0.0251) and impaired delta of SpO2 (p < 0.0307). In contrast, the hypocaloric group presented an improved stroke volume (p < 0.0352), systemic vascular resistance (p < 0.0075), and systemic vascular resistance index (p < 0.0184). In addition, no changes were observed in the whole-blood analysis (p > 0.05) or for IL-6 (p > 0.05), TNF-alpha (p < 0.05), IL-10 (p < 0.05), and Klotho (p > 0.05). Conclusions: A long-term hypocaloric diet in eutrophic older adults’ resulted in an enhanced cardiovascular hemodynamic response but was associated with reduced functional capacity without changes in the immune response.
The Therapeutic Effects of Lactic Acid Bacteria Isolated from Spotted Hyena on Dextran Sulfate Sodium-Induced Ulcerative Colitis in Mice
Authors: Xu Mengen , Hu Miao , Han Jingbo , Wang Lei , He Yuanyuan , Kulyar Md. F. , Zhang Xiaohu , Lu Yaozhong , Mu Siyang , Su Hang , Cao Jintao , Li Jiakui
Published: October 2024

Background: Inflammatory bowel disease (IBD) is a chronic condition characterized by recurrent episodes and an unclear etiology. Given the limitations of current therapeutic options, which include suboptimal efficacy and significant side effects, there is a pressing need to explore novel treatments. Probiotics derived from diverse species have been identified as a promising approach for managing IBD, owing to their anti-inflammatory properties and their ability to regulate gut flora, among other beneficial effects. Methods: In this study, three strains of lactic acid bacteria (LAB) were isolated from the feces of the scavenger spotted hyena (Crocuta crocuta), a scavenging mammal. Based on their capability to survive within and adhere to the gastrointestinal tract, along with their profile of antibiotic resistance, a high-quality strain of Lactobacillus acidophilus (LA) was selected and demonstrated to be safe for mice. Subsequently, the therapeutic efficacy of LA was evaluated using a dextran sulfate sodium (DSS)-induced model of ulcerative colitis in mice. Results: The results indicated that LA restored the disease activity index and improved histopathological lesions in the model group. It also reduced inflammation and oxidative stress and significantly restored the expression of mucins and intestinal tight junction (TJ) proteins (ZO-1, Occludin). Furthermore, LA corrected the DSS-induced disruption of the intestinal flora, leading to a significant decrease in the prevalence of potentially harmful bacterial genera, such as Bacteroides, and an increase in beneficial bacterial genera, including Lactobacillus. In conclusion, Lactobacillus acidophilus LA1, isolated from spotted hyena feces, has potential as a functional supplement for alleviating symptoms of IBD and regulating intestinal flora.