bluuebunny/crossref_metadata_2025 huggingface dataset:
The Geometric Series Hypothesis of Leaf Area Distribution and Its Link to the Calculation of the Total Leaf Area per Shoot of Sasaella kongosanensis ‘Aureostriatus’
Authors: Meng Yong , Ratkowsky David A. , Yao Weihao , Heng Yi , Shi Peijian
Published: January 2025

Total leaf area per shoot (AT) can reflect the photosynthetic capacity of a shoot. A prior study hypothesized that AT is proportional to the product of the sum of the individual leaf widths per shoot (LKS) and the maximum individual leaf length per shoot (WKS), referred to as the Montgomery–Koyama–Smith equation (MKSE). However, empirical evidence does not support such a proportional relationship hypothesis, as AT was found to allometrically scale with LKSWKS, i.e., AT∝LKSWKSα, where α≠1, referred to as the power law equation (PLE). Given that there is variation in the total number of leaves per shoot (n), little is known about whether the leaf area distribution has an explicit mathematical link with the sorted leaf area sequence per shoot, and it is unknown whether the mathematical link can affect the prediction accuracy of the MKSE and PLE. In the present study, the leaves of 500 shoots of a dwarf bamboo (Sasaella kongosanensis ‘Aureostriatus’) were scanned, and the leaf area, length, and width values were obtained by digitizing the leaf images. We selected the shoots with n ranging from 3 to 10, which accounted for 76.6% of the totally sampled shoots (388 out of 500 shoots). We used the formula for the sum of the first j terms (j ranging from 1 to n) of a geometric series (GS), with the mean of the quotients of any adjacent two terms (denoted as q¯A) per shoot as the common ratio of the GS, to fit the cumulative leaf area observations. Mean absolute percentage error (MAPE) was used to measure the goodness of fit of the GS. We found that there were 367 out of 388 shoots (94.6%) where 1 < q¯A < 1.618 and MAPE < 15%, and these 367 shoots were defined as valid samples. The GS hypothesis for leaf area distribution was supported by the result that the MAPE values for most valid samples (349 out of 367, i.e., 95.1%) were smaller than 5%. Here, we provide a theoretical basis using the GS hypothesis to demonstrate the validity of the MKSE and PLE. The MAPE values for the two equations to predict AT were smaller than 5%. This work demonstrates that the leaf area sequence per shoot follows a GS and provides a useful tool for the calculation of total leaf area per shoot, which is helpful to assess the photosynthetic capacity of plants.
Affecting of Glyphosate Tolerance and Metabolite Content in Transgenic Arabidopsis thaliana Overexpressing EPSPS Gene from Eleusine indica
Authors: Chen Jingchao , Li Zhiling , Yu Haiyan , Cui Hailan , Li Xiangju
Published: January 2025

Long-term use of the global non-selective herbicide glyphosate for weed control has caused resistance in weeds. Overproducing of the target of glyphosate 5-enolpyruvylshikimate-3-phosphate synthase (EPSPS) is one of the resistance mechanisms in weeds. However, few studies have measured the effects on tolerance levels and metabolite content in model plant species overexpressing EPSPS from weeds. We assessed the resistance levels of transgenic Arabidopsis thaliana overexpressing EPSPS from Eleusine indica, and its effects on metabolite content using the method of both quasi-targeted and targeted metabolomics. The results showed that the average resistance index of the transgenic lines was 4.7 and the exogenous E. indica EPSPS expression levels were 265.3- to 532.0-fold higher than those in the wild-type (WT) line. The EPSPS protein ranged from 148.5 to 286.2 μg g−1, which was substantially higher than that in the WT line (9.1 μg g−1). 103 metabolites associated with flavone and flavonol biosynthesis, the metabolism of aromatic amino acids, energy metabolism, and auxin synthesis were significantly higher in the transgenic glyphosate-resistant individuals (R) than in the WT individuals. The results of quantitative analysis show that pyruvate, sedoheptulose 7-phosphate, and gluconic acid amounts in R plants were 1.1-, 1.6- and 1.3-fold higher than those in WT plants, respectively. However, both citric and glyceric acid levels were 0.9-fold lower than those in WT plants. The abundance of other metabolites in the glycolytic and pentose phosphate pathways of central carbon metabolism was similar in the WT and transgenic plants. Glutamic acid was significantly more abundant in the transgenic line than in the WT plants. In contrast, asparagine, glutamine, and lysine were less abundant. However, the concentration of other amino acids did not change significantly. Overexpression of E. indica EPSPS in A. thaliana conferred a moderate level of tolerance to glyphosate. Metabolites associated with flavone and flavonol biosynthesis, the metabolism of aromatic amino acids, and energy metabolism were significantly increased. The results of this study will be useful for evaluating the characterisation and risk assessment of transgenic plants, including identification of unintended effects of the respective transgenic modifications.
Effects of Exogenous Boron on Salt Stress Responses of Three Mangrove Species
Authors: Yang Jingjun , Wei Haihang , Lei Pifeng , Qin Jie , Tian Hongdeng , Fan Donghan , Zhang Jihui , Qin Zhenkai , Huang Xiaoying , Liu Xiu
Published: January 2025

Salt stress is common but detrimental to plant growth, even in mangroves that live in saline areas. Boron (B) is an essential micronutrient that performs an important role in many functions in plants; however, its protective role under salt stress is poorly understood, especially in long-lived woody plants. In this study, we conducted an indoor experiment under simulated tidal conditions with four treatments (10‰ salinity, 40‰ salinity, 40‰ salinity + 100 μM B, and 40‰ salinity + 500 μM B) and three mangrove species (Avicennia marina, Aegiceras corniculatum, and Bruguiera gymnorrhiza) to investigate the effects of exogenous B on salt tolerance in plant growth, morphology, physiology, and leaf anatomy. The results showed that exogenous low-concentration B treatment (100 μM B) improved the performance of mangrove species under high salinity stress, especially in terms of physiology and leaf anatomy, while high-concentration B treatment (500 μM B) had adverse effects. Additionally, we found that the response to exogenous B varied among species in physiology and leaf anatomy, such as proline, malondialdehyde, activity of antioxidant enzymes, palisade tissue, and spongy tissue, which may be related to the salt tolerance of different species. This study may provide useful insights into the alleviation of salt stress by B in mangrove growth and development, which may facilitate mangrove cultivation and afforestation in a saline environment.
Competitive Pasture Species to Suppress the Growth of Annual Riceflower (Pimelea trichostachya Lindl.) at Different Planting Densities and Spatial Arrangements
Authors: Saleem Rashid , Bajwa Ali , Campbell Shane , Fletcher Mary T. , Kalaipandian Sundaravelpandian , Adkins Steve W.
Published: January 2025

This study assessed the effectiveness of four competitive pasture species—Premier digit grass (Digitaria eriantha Steud. var. Premier), Rhodes grass (Chloris gayana Kunth.), sabi grass (Urochloa mosambicensis Hack.), and buffel grass (Pennisetum ciliare L.) against the toxic annual riceflower (Pimelea trichostachya Lindl.) at varying planting densities and ratios. At six plants pot−1, with a 66:33 grass-to-weed ratio, riceflower biomass decreased by 73.7%, 82.5%, 73.7%, and 60.6% when grown alongside Premier digit, Rhodes, sabi, and buffel grasses, respectively. Similarly, with four plants pot−1 at a 75:25 ratio, reductions were 69.1%, 79.8%, 71.0%, and 44.5%, respectively. Annual riceflower experienced the greatest suppression when grown with Rhodes grass, showing aggressivity index (AI) values of −60.2 and −67.2 and relative crowding coefficient (RCC) values of 0.4 for both six and four plants pot−1. Premier digit grass also suppressed riceflower effectively, with riceflower AI values of −35.6 and −36.7 and RCC values of 0.5 and 0.6. Buffel grass had the least impact, with riceflower AI values of −41.1 and −27.9 and RCC values of 0.9 and 2.0. Sabi grass also demonstrated good suppressive effects, though slightly less than the top two species. Higher planting densities generally resulted in stronger riceflower suppression. The results highlight the importance of considering planting density, arrangement, and key plant traits when selecting pasture species for successful weed control. Based on these findings, we conclude that Premier digit grass and Rhodes grass show promising potential for effective suppression of annual riceflower growth.
Long-Term Salinity-Responsive Transcriptome in Advanced Breeding Lines of Tomato
Authors: Sadder Monther T. , Ali Ahmad Abdelrahim Mohamed , Alsadon Abdullah A. , Wahb-Allah Mahmoud A.
Published: January 2025

Soil salinity and the scarcity of freshwater resources are two of the most common environmental constraints that negatively affect plant growth and productivity worldwide. The tomato (Solanum lycopersicum Mill.) plant is moderately sensitive to salinity. The identification of salinity-responsive genes in tomato that control long-term salt tolerance could provide important guidelines for its breeding programs and genetic engineering. In this study, a holistic approach of RNA sequencing combined with measurements of physiological and agronomic traits were applied in two advanced tomato breeding lines (susceptible L46 and tolerant L56) under long-term salinity stress (9.6 dS m−1). Genotype L56 showed the up-regulation of known and novel differentially expressed genes (DEGs) that aid in the salinity tolerance, which was supported by a high salt tolerance index (81%). Genotype L46 showed both similar and different gene families of DEGs. For example, 22 paralogs of CBL-interacting kinase genes were more up-regulated in L56 than in L45. In addition, L56 deployed more SALT OVERLY SENSITIVE paralogs than L45. However, both genotypes showed the up-regulation of ROS-detoxifying enzymes and ROS-scavenging proteins under salinity stress. Therefore, L56 was more effective in conveying the stress message downstream along all available regulatory pathways. The salt-tolerant genotype L56 is genetically robust, as it shows an enhanced expression of a complete network of salt-responsive genes in response to saline conditions. In contrast, the salt-susceptible genotype L46 shows some potential genetic background. Both genotypes have great potential in future breeding programs.
Enhanced Mechanical and Acoustic Properties of Basalt Fiber/Polyurethane Composites by Silane Coupling Agents
Authors: Ge Mengchen , Li Xiaodong , Han Fei , Su Xing , Jiang Hao , Liu Youhao , Wang Yangwei , Zou Meishuai
Published: January 2025

Modified basalt microfiber-reinforced polyurethane elastomer composites were prepared by a semi-prepolymer method with two different silane coupling agents (KH550 and KH560) in this study. Infrared spectroscopy was used to quantify the degree of microphase separation and analyze the formation of hydrogen bonding in polyurethane. The interfacial surface and the morphology of fibers and composites from tensile fracture were examined by a scanning electron microscope. Further measurements were performed on an electronic universal testing machine for characterizing the mechanical properties of composites. Moreover, the loss factor and transmission loss of composite materials were obtained from dynamic thermomechanical analysis and acoustic impedance tube, respectively. The suitable concentrations in the modification of basalt fibers were established at 1% for KH550 and 1.5% for KH560. The best overall performance was obtained in KH550-BMF/PUE group, as the properties increased by 31% in tensile strength, 37% in elongation at break, and 21% in acoustic insulation.
Review of the Synthesis and Degradation Mechanisms of Some Biodegradable Polymers in Natural Environments
Authors: Yao Xiao , Yang Xue , Lu Yisang , Qiu Yinyuan , Zeng Qinda
Published: January 2025

The escalating demand for sustainable materials has been fueling the rapid proliferation of the biopolymer market. Biodegradable polymers within natural habitats predominantly undergo degradation mediated by microorganisms. These microorganisms secrete enzymes that cleave long-chain polymers into smaller fragments for metabolic assimilation. This review is centered around dissecting the degradation mechanisms of specific biodegradable polymers, namely PLA, starch-based polymers, and plant fiber-based polymers. Recent investigations have unveiled that PLA exhibits augmented biocompatibility when combined with HA, and its degradation is subject to the influence of enzymatic and abiotic determinants. In the case of starch-based polymers, chemical or physical modifications can modulate their degradation kinetics, as evidenced by Wang et al.’s superhydrophobic starch-based nanocomposite cryogel. For plant fiber-based polymers, the effects of temperature, humidity, and cellulose degradation on their properties, along with the implications of various treatments and additives, are probed, as exemplified by Liu et al.’s study on jute/SiO2/PP composites. Specifically, with respect to PLA, the polymerization process and the role of catalysts such as SnCl2 in governing the structure and biodegradability are expounded in detail. The degradation of PLA in SBF and its interaction with β-TCP particles constitute crucial aspects. For starch-based polymers, the enzymatic degradation catalyzed by amylase and glucosidase and the environmental impacts of temperature and humidity, in addition to the structural ramifications of amylose and amylopectin, are further elucidated. In plant fiber-based polymers, the biodegradation of cellulose and the effects of plasma treatment, electron beam irradiation, nanoparticles, and crosslinking agents on water resistance and stability are explicated with experimental substantiation. This manuscript also delineates technological accomplishments. PLA incorporated with HA demonstrates enhanced biocompatibility and finds utility in drug delivery systems. Starch-based polymers can be engineered for tailored degradation. Plant fiber-based polymers acquire water resistance and durability through specific treatments or the addition of nanoparticles, thereby widening their application spectrum. Synthetic and surface modification methodologies can be harnessed to optimize these materials. This paper also consolidates reaction conditions, research techniques, their merits, and demerits and delves into the biodegradation reaction mechanisms of these polymers. A comprehensive understanding of these degradation mechanisms is conducive to their application and progression in the context of sustainable development and environmental conservation.
Advances in Electrically and Thermally Conductive Functional Nanocomposites Based on Carbon Nanotubes
Authors: Shchegolkov Alexandr V. , Shchegolkov Aleksei V. , Kaminskii Vladimir V. , Iturralde Pablo , Chumak Maxim A.
Published: January 2025

The paper presents a review of CNTs synthesis methods and their application as a functional filler to obtain polymer composites for various technical purposes for strain gauges, electrical heating, anti-static coatings, electrically conductive compounds, etc. Various synthesis methods allow CNTs with different morphology and structural properties to be created, which expands the possibilities of the application of such nanoscale structures. Polymers can provide such effects as ‘shape memory’ and self-repair of mechanical defects. Different combinations of polymers and dispersed fillers influence the change in electrical and thermal conductivity, as well as the positive temperature coefficient of resistance, which makes it possible to achieve the effect of temperature self-regulation during electrical heating. CNTs make it possible to form PTCR (positive temperature coefficient of resistance) in elastomers at lower concentrations, which makes it possible to preserve mechanical strength and use more efficient modes of heat generation. For strain gauges, CNTs improve sensitivity to mechanical effects and extend the measurement range. The use of thermoplastic elastomers provides the temperature of PTCR operation for electric heating at the level of 200 °C (voltage 240 V), which allows such heaters to operate at a power supply from a household electrical network. CNTs-based strain gauges can provide structural condition monitoring of composite materials.
Synthesis and Characterization of UV-Curable Resin with High Refractive Index for a Luminance-Enhancing Prism Film
Authors: Song Jin Han , Hong Seung-Mo , Park Seok Kyu , Kwon Hyeok Ki , Hwang Seok-Ho , Oh Jong-Min , Koo Sang-Mo , Lee Giwon , Park Chulhwan
Published: January 2025

A novel monomer, 9-bis[4-(2-hydroxyethoxy)phenyl]fluorene di(mercaptopropionate), with a highly refractive index, purity, and excellent UV-curable properties, is synthesized through an optimized Fischer esterification process, reacting 9,9-bis[4-(2-hydroxyethoxy)phenyl]fluorene with 3-mercaptopropionic acid. The structural characterization of this monomer is performed using Fourier-transform infrared spectroscopy, nuclear magnetic resonance spectroscopy, high-performance liquid chromatography, and liquid chromatography-mass spectrometry. The synthesis conditions are optimized using a design-of-experiments approach. UV-curable resins are obtained by incorporating the synthesized monomer as the thiol component. The effects of thiol content on the UV-curing behavior, refractive index, shrinkage, adhesion to the polyethylene terephthalate (PET) foil, and viscoelastic recovery are examined. The thermal properties are assessed using differential scanning calorimetry and thermogravimetric analysis. Field-emission scanning electron microscopy confirms the successful replication of the prism film. In edge-lit light-emitting diode (LED) backlight units, the prism film showed increased luminance with higher thiol monomer content in the UV-curable resin while maintaining stable color coordinates. This novel highly refractive index monomer can be utilized in luminance-enhancing prism films, thereby contributing to future innovations in the display film industry.
Effects of Beech Wood Surface Treatment with Polyethylenimine Solution Prior to Finishing with Water-Based Coating
Authors: Palija Tanja , Rančić Milica , Djikanović Daniela , Radotić Ksenija , Petrič Marko , Pavlič Matjaž , Jaić Milan
Published: January 2025

The surfaces of beech wood samples were treated with polyethylenimine (PEI) solutions at three different concentrations—0.5%, 1% and 2%—and two molecular weights—low molecular weight (LMW) and high molecular weight (HMW). The effects of PEI surface treatment of wood were characterized by FT-IR spectroscopy, the penetration depth of PEI (EPI fluorescence spectroscopy), the bonding position of PEI (by SEM), the wetting and surface energy, and the water uptake. After PEI treatment, the samples were coated with a water-based transparent acrylic coating (WTAC). The dry film thickness, the penetration depth of the coating, the adhesion strength and the surface roughness of the coated wood surface were evaluated. EPI fluorescence and SEM micrographs showed that PEI HMW chains were deposited on the surface, in contrast to PEI LMW, which penetrates deeper into layers of the wood cells. Treatment with a 1% PEI HMW solution resulted in a 72% reduction in water uptake of the wood (compared to untreated samples after 5 min of applying water droplets to the surface) and a 23.2% reduction in surface energy (compared to untreated samples) while maintaining the adhesion strength of the applied WTAC. The lower water uptake of the treated wood samples reduced the roughness of the coated surface, which is particularly important when the wood surface is finished with water-based coatings.
Synthesis, Electrical Conductivity, and Wave-Absorption Performances of Bamboo-Based Composites Co-Doped with Graphene Oxide and Polyaniline
Authors: Wang Jin , Wu Wangjun , Zhang Wenfu , Zhao Ying , Wang Hongyan , Yuan Shaofei , Zhang Jian
Published: January 2025

Bamboo was carbonized and further modified via co-doping with graphene oxide (GO) and polyaniline (PANI) to prepare microwave absorption composites (GO/PANI/CB) by in situ polymerization of 1R-(-)-Camphorsulfonic acid (L-CSA). The conductivity of GO/PANI/CB reached 2.17 ± 0.05 S/cm under the optimized process conditions. The oxygen-containing group of GO reacts with PANI to form hydrogen bonds and thus polymerize. The GO and PANI particles covered the carbonized bamboo (CB) surface in a disordered aggregation form. Based on the measuring method of the vector network analyzer (VNA), the microwave-absorption performance of GO/PANI/CB was investigated. With 30% addition of GO/PANI/CB, the minimum reflection loss (RLmin) at 7.12 GHz with a thickness of 3.5 mm of samples reached −49.83 dB. The effective absorption bandwidth (<−10 dB) is as high as 4.72 GHz with a frequency range of 11.68–16.40 GHz and a thickness of 2 mm. Compared with many PANI based electromagnetic wave absorbing materials reported in recent years, GO/PANI/CB provides improved microwave-absorption performance while maintaining high absorption bandwidth. GO/PANI/CB exhibited the advantages of simple preparation, low cost, renewability, light texture, thinness, wide absorption bandwidth, and strong absorption ability, and can be used for new microwave absorption materials.
Revolutionizing Dental Polymers: The Versatility and Future Potential of Polyetheretherketone in Restorative Dentistry
Authors: Taymour Noha , Abd El-Fattah Ahmed , Kandil Sherif , Fahmy Amal E. , Al-Qahtani Naif H. , Khaled Abdulrahman , Al-Dulaijan Yousif A. , Gepreel Mohamed Abdel-Hady
Published: January 2025

Polyetheretherketone (PEEK) has emerged as a revolutionary material in modern dentistry because of its unique combination of mechanical strength, biocompatibility, and versatility. This literature review examines the current applications and future potential of PEEK in various dental disciplines. PEEK’s favorable properties, including its low specific weight, high strength-to-weight ratio, and ability to be easily machined, have led to its adoption in prosthetics, implantology, and dental esthetic restorations. This material has shown promise for fabricating crowns, bridges, removable partial denture frameworks, and implant components. PEEK’s radiolucency and bone-like elastic modulus make it particularly suitable for dental implants and abutments. Additionally, its resistance to degradation and compatibility with various surface treatments enhances its long-term performance in the oral environment. While challenges such as bonding to other dental materials and aesthetic limitations exist, ongoing research is addressing these issues through surface modifications and composite formulations. As the dental field continues to evolve, PEEK’s adaptability and biocompatibility position it a key player in the development of next-generation dental materials and techniques, potentially transforming patient care and treatment outcomes in dentistry.
Highly Stable Flexible SERS-Imprinted Membrane Based on Plasmonic MOF Material for the Selective Detection of Chrysoidin in Environmental Water
Authors: Liu Xinyi , Li Hongji , Wang Dandan , Lu Jian , Wu Yilin , Sun Wei
Published: January 2025

Chrysoidin (CG) can be ingested into the human body through the skin and cause chronic toxicity, so the detection of CG levels in the environment is crucial. In this study, we synthesize F-Ag@ZIF-8/PVC molecular-imprinted membranes (FZAP-MIM) by an innovative combination of SERS detection, membrane separation, and a molecular-imprinted technique in order to perform the analysis of CG in water. The plasmonic MOF material as a SERS substrate helps to enrich the target and realize the spatial overlap of the target with the nanoparticle tip “hotspot”. To avoid the poor reproducibility of Raman signals caused by the random arrangement of the powder substrate, polyvinyl chloride (PVC) is used to provide support and protection for the powder substrate. PVC has excellent dirt immunity and chemical stability, enabling the substrate to maintain Raman performance under complex and extreme detection conditions. FAZP-MIM has outstanding sensitivity and selectivity and can quickly and accurately capture targets even in the presence of similar structural interferences. The method showed superior recoveries in spiked recovery tests of real water samples and is expected to be practically applied to the trace detection of organic dye molecules in the environment.
Biorefinery of Lignocellulosic and Marine Resources for Obtaining Active PVA/Chitosan/Phenol Films for Application in Intelligent Food Packaging
Authors: Lopretti Correa Mary Isabel , Batista-Menezes Diego , Rezende Stephany Cunha de , Santamaria-Echart Arantzazu , Barreiro Maria-Filomena , Vega-Baudrit Jose Roberto
Published: January 2025

This study focuses on the extraction of phenolic compounds from the fermentation of Phanerochaete chrysosporium and Gloeophyllum trabeum. The main goal was to synthesize phenol/chitosan microspheres and PVA films and characterized using FTIR, TGA, DSC, SEM, and mechanical tests to evaluate their physical, chemical, and mechanical properties for antimicrobial packaging applications. Homogeneous chitosan microspheres loaded with lignin-derived phenols were obtained, showing controlled release of antimicrobial compounds. The incorporation of phenolic microspheres into PVA/chitosan films resulted in significant improvements in mechanical properties: the films exhibited an elastic modulus of 36.14 ± 3.73 MPa, tensile strength of 12.01 ± 1.14 MPa, and elongation at break of 65.19 ± 5.96%. Thermal tests revealed that chitosan-containing films had enhanced thermal stability, with decomposition temperatures (T10) reaching 116.77 °C, compared to 89.28 °C for pure PVA. In terms of antimicrobial activity, PVA/chitosan/phenol films effectively reduced Lactobacillus growth and milk acidity, maintaining quality for up to 96 h at room temperature, outperforming controls with acetic acid and H2O2. The films also inhibit yeast growth for one week. In conclusion, phenols can be effective antimicrobial agents in dairy, but their use should be monitored. Additionally, PVA/chitosan-phenol films offer biodegradability, antimicrobial properties, and sustainability for diverse applications.
Study on the Aging Effects of Relative Humidity on the Primary Chemical Components of Palm Leaf Manuscripts
Authors: Zhang Wenjie , Wang Shan , Guo Hong
Published: January 2025

Palm Leaf Manuscripts represent a significant component of the world’s cultural heritage. Investigating their primary chemical components and understanding the transformations these materials undergo under environmental influences are crucial for elucidating their material characteristics and aging mechanisms and developing effective strategies for preventive conservation. This study utilized infrared absorption spectroscopy and X-ray diffraction analysis to examine changes in the primary chemical components of Palm Leaf Manuscripts under varying relative humidity conditions over extended periods. The findings reveal that dry environments lead to surface cracking, while humid environments promote mold growth, both of which contribute to the degradation of the primary chemical components. These degradative processes reduce cellulose crystallinity and thermal stability. The deterioration is particularly severe under high humidity, with hemicellulose degrading faster and more extensively than cellulose under the same conditions. After 200 days of aging at 10% RH and 90% RH, cellulose degradation reached 19.82% and 54.40%, respectively, while hemicellulose degradation was 34.78% and 64.28%. Correspondingly, the relative crystallinity of cellulose decreased by 8.01% and 13.11%. In contrast, samples maintained at 50% RH exhibited minimal deterioration, with cellulose and hemicellulose degrading by only 4.08% and 13.55%, respectively, and a 6.61% reduction in cellulose crystallinity. These results suggest that a relative humidity of 50% is optimal for the preservation of Palm Leaf Manuscripts. This study offers significant insights into the ageing mechanisms and preventive conservation of Palm Leaf Manuscripts, as well as other cellulose-based organic heritage materials.
Polydopamine Coated Nonspherical Magnetic Nanocluster for Synergistic Dual Magneto-Photothermal Cancer Therapy
Authors: García-García Gracia , Lázaro Marina , Urquiza Pedro , Romacho Tania , Delgado Ángel V. , Iglesias Guillermo R.
Published: January 2025

Local hyperthermia is gaining considerable interest due to its promising antitumor effects. In this context, dual magneto-photothermal cancer therapy holds great promise. For this purpose, the use of nanomaterials has been proposed. Therefore, the aim of this research is to develop a dual magneto-photothermal agent consisting of polydopamine-coated nonspherical magnetic nanoclusters. The physicochemical characterization of the nanoclusters was performed by electron microscopy, electron dispersive X-ray, dynamic light scattering, electrophoretic mobility, thermogravimetric analysis, and Fourier transform infrared spectroscopy. The biocompatibility of the nanoclusters was evaluated using human skin M1 fibroblasts. The potential of the nanoclusters as dual magneto-photothermal agents was investigated by applying an alternating magnetic field (18 kA/m and 165 kHz) and/or NIR laser (850 nm, 0.75 W/cm2). Nanoclusters showed a size of 350 nm consisting of nonspherical magnetic particles of 11 nm completely coated with polydopamine. In addition, they were superparamagnetic and did not significantly affect cell viability at concentrations below 200 µg/mL. Finally, the SAR values obtained for the nanoclusters demonstrated their suitability for magnetotherapy and phototherapy (71 and 41 W/g, respectively), with a synergistic effect when used together (176 W/g). Thus, this work has successfully developed polymeric-coated magnetic nanoclusters with the potential for dual magneto-photothermal cancer therapy.
Differences in Rejuvenation Mechanisms and Physical Properties of Aged Styrene–Butadiene–Styrene (SBS)-Modified Bitumen by Mono-Epoxy and Di-Epoxy Compounds
Authors: Chiang Kingsley C. K. , Zhu Bohan , Liu Lingxiao , Li Haozongyang , Chen Cheng , Tang Shixian , Xing Chengwei
Published: January 2025

Studying the mechanisms and effects of rejuvenators on SBS-modified bitumen is crucial for repairing degraded SBS and recycling aged SBS-modified bitumen (ASMB), thereby contributing to the sustainable development of bitumen pavements. This research examines the roles of mono-epoxy Alkyl (C12-C14) glycidyl ether (AGE) and di-epoxy 1,6-Hexanediol diglycidyl ether (HDE) under the catalysis of N,N-dimethyl benzyl amine (BDMA) in repairing degraded SBS chains. Aromatic oil (ORSMB)-, AGE–aromatic oil (ARSMB)-, and HDE–aromatic oil (HRSMB)-rejuvenated bitumen are analyzed for their chemical structures, physical properties, and rheological properties. Fluorescence microscopy (FM) and Fourier transform infrared spectroscopy (FTIR) reveal that HDE chemically reconnects degraded SBS chains, enhancing ASMB properties, while AGE improves ASMB properties through physical softening. HDE balances high-temperature properties and improves mid-temperature fatigue resistance through a rigid repair effect and flexible chain structure. AGE enhances mid-temperature fatigue resistance but significantly reduces high-temperature rutting resistance due to a softening effect. The findings demonstrate that HDE restores ASMB ductility chemically, while AGE improves crack resistance through physical softening. These differences in rejuvenation mechanisms provide a theoretical basis for optimizing rejuvenator design and advancing bitumen pavement recycling.
Cleavable Bio-Based Epoxy Matrix for More Eco-Sustainable Thermoset Composite Components
Authors: Rossitti Ilaria , Bolis Arianna , Sambucci Matteo , Sarasini Fabrizio , Tirillò Jacopo , Valente Marco
Published: January 2025

Cleavable bio-based epoxy resin systems are emerging, eco-friendly, and promising alternatives to the common thermoset ones, providing quite comparable thermo-mechanical properties while enabling a circular and green end-of-life scenario of the composite materials. In addition to being designed to incorporate a bio-based resin greener than the conventional fully fossil-based epoxies, these formulations involve cleaving hardeners that enable, under mild thermo-chemical conditions, the total recycling of the composite material through the recovery of the fiber and matrix as a thermoplastic. This research addressed the characterization, processability, and recyclability of a new commercial cleavable bio-resin formulation (designed by the R-Concept company) that can be used in the fabrication of fully recyclable polymer composites. The resin was first studied to investigate the influence of the different post-curing regimes (room temperature, 100 °C, and 140 °C) on its thermal stability and glass transition temperature. According to the results obtained, the non-post-cured resin displayed the highest Tg (i.e., 76.6 °C). The same post-curing treatments were also probed on the composite laminates (glass and carbon) produced via a lab-scale vacuum-assisted resin transfer molding system, evaluating flexural behavior, microstructure, and dynamic-mechanical characteristics. The post-curing at 100 °C would enhance the crosslinking of polymer chains, improving the mechanical strength of composites. With respect to the non-post-cured laminates, the flexural strength improved by 3% and 12% in carbon and glass-based composites, respectively. The post-curing at 140 °C was instead detrimental to the mechanical performance. Finally, on the laminates produced, a chemical recycling procedure was implemented, demonstrating the feasibility of recovering both thermoplastic-based resin and fibers.
Optimization of Copper Recovery from Cyanide Leaching Solutions Used in Gold–Copper Ore Processing Using Probabilistic–Deterministic Experimental Design
Authors: Kassymova Dinara , Sapinov Ruslan , Kushakova Larissa , Kulenova Natalya , Shoshay Zhanserik , Adylkanova Meruert
Published: January 2025

This article presents a study on the precipitation of copper from the cyanide leaching solutions used for gold–copper ores, both with and without the addition of a sulphidizer (Na2S). Mathematical models were developed to summarize the effects of the pH, initial copper concentration, and Na2S stoichiometric ratio on the precipitation process, using an experimental design based on a probabilistic–deterministic method. Varying the stoichiometric ratio of Na2S has a minimal impact on the precipitation process. However, the presence of a sulphidizer is significant, as the precipitation process occurs at pH levels of 5 and below. The initial concentration of copper in the solution was identified as the most significant factor. At copper concentrations of 0.34% and 1.55% (pH = 3), the precipitation rates were 51.48% and 47.6%, respectively. This study also determined that the most effective method across the entire range of copper concentrations in the solution was the precipitation of copper in the form of copper cyanide hydrate (CuCN∙nH2O) without the addition of Na2S. At copper concentrations of 0.34% and 1.55% (pH = 3), the precipitation rates were 86.47% and 85%, respectively. The pH level was the most significant factor influencing this process, as copper deposition without Na2S did not occur at a pH of 5. The obtained models allow us to accurately predict the influence of factors on the deposition process. Aided by the mathematical model of precipitation (without Na2S), we selected the conditions for an enlarged experiment using 20 L of solution (Cu = 0.34%, pH = 3.2), which showed the high efficiency of the method. The calculated recovery amounted to 86%, where practical recovery was 87.2%, and divergence was ≥1.2%.
Physical Modeling of High-Pressure Flooding and Development of Oil Displacement Agent for Carbonate Fracture-Vuggy Reservoir
Authors: Li Jinghui , Zhang Wen , Qu Bochao , Zhen Enlong , Qian Zhen , Ma Shufen , Qin Fei , You Qing
Published: January 2025

The fracture-cavity carbonate reservoir in Tahe oilfield is buried deep (more than 5000 m). The reservoir has low permeability, strong heterogeneity, large size, diverse forms of connectivity, and complex spatial distribution. In conventional water flooding, it is difficult to improve oil recovery effectively because of small water flood sweep and large injection pressure. Pressure flooding is a new water injection technique that can change the reservoir pore space. Combined with an oil displacement agent, pressure flooding is expected to improve the recovery rate of carbonate reservoirs. In this paper, the influence factors of pressure flooding technology are studied, and a set of surfactant systems suitable for high-temperature and high-salt reservoirs is developed. The results show that only an appropriate injection flow can produce microfractures. Only an appropriate displacement rate can optimize the effects of pressure flooding. With an increase in crude oil viscosity, the recovery rate after pressure flooding decreases gradually. A complex fracture network is formed in reservoirs after pressure flooding. The new surfactant system has good interfacial tension reduction properties and excellent stability. Pressure flooding experiments with the addition of a surfactant showed that the system can help to improve the recovery of pressure flooding.
Preliminary Exploration on Short-Term Prediction of Local Geomagnetically Induced Currents Using Hybrid Neural Networks
Authors: Fang Yihao , Liu Jin , Jiang Haiyang , Chen Wenhao
Published: January 2025

During extreme space weather events, transient geomagnetic disturbances initiated by solar eruptive activities can induce geomagnetically induced currents (GICs), which have severe impacts on power grid systems and oil/gas pipelines. Observations indicate that GICs in power grids are characterized by large fluctuation amplitudes, broad frequency ranges, and significant randomness. Their behavior is influenced by several factors, including the sources of space weather disturbance, Earth’s electrical conductivity distribution, the structural integrity and performance of power grid equipment, and so on. This paper presents a hybrid prediction using actual GIC data from power grids and deep learning techniques. We employ various technical methods, including complete ensemble empirical mode decomposition with adaptive noise (CEEMDAN), convolutional neural networks (CNNs), long short-term memory (LSTM) networks, and attention mechanisms, to investigate short-term prediction methods for local grid GICs. The study uses GIC monitoring samples from 8 November 2004 for model training and testing. The results are evaluated using the coefficient of determination R2, root mean square error (RMSE), and mean absolute error (MAE). Preliminary research suggests that the combined CEEMDAN–CNN–LSTM–attention model significantly improves prediction accuracy and reduces the time delay in GIC prediction during geomagnetic storms compared to using LSTM neural networks alone.
Optimizing Large-Scale Inorganic Processes: Model-Based Digital Design of RH-DS Apparatus
Authors: Szczeblewski Sławomir , Wachowiak Maciej , Gębicki Jacek
Published: January 2025

The design of industrial installations using digital design techniques (digital twin), aligned with the concept of Industry 4.0, provides a tool to optimize maintenance costs, process gas emissions, energy consumption and to reduce the risks associated with production testing. Modern manufacturing plants conduct chemical processes by combining production experience with model-based research. Analyzing processes using advanced digital techniques can replace traditional methods of technological process balancing. The methodology based on the digital twin already serves as a holistic system of process connections, supporting production, research and development, production planning, and quality control. This paper presents the digital design, optimization, and comparison of process data obtained through simulations for two different types of ammonia recovery units in soda ash production using the ammonia–soda process. Using specialized modeling software and relying on historical data, engineering assumptions, and new concepts, virtual models were created in which the material and thermal balances of the process were simulated. This research is divided into two stages. In the first stage, a model-based approach and model optimization techniques are presented, while in the second stage, the preparation of models of the distillation installation is presented, and the influence of various structural parameters of the equipment on the temperature profile and gas flow rate in the ammonia recovery section is discussed. The process of the research method, based on simulations in a virtual environment, allows for evaluating the implementation potential of the proposed concepts, optimizing process parameters, and redefining the approach to conducting chemical processes. A series of simulations conducted in studies on ammonia recovery indicated a potential increase in gaseous ammonia recovery by up to 14.09%, taking into account the type of distillation apparatus or the height of the packing section.
The Movement Mode of the Microworld Particle
Authors: Li Jinhai
Published: January 2025

Most physicists are dissatisfied with the current explanation of quantum mechanics, and want to find a method to solve this problem. However, this problem has not been solved perfectly up to now. In this paper, annihilation-generation movement (AGM) is developed according to the electron motion in hydrogen atoms. To verify the AGM, a curved surface that fits the dark fringe of the single-slit diffraction is proposed. Based on the AGM, the wave function of a free electron is rewritten and the double-slit experiment can be understood. Here, we show that the AGM is an alternative physical image that can be used to solve the puzzles of quantum mechanics, such as Heisenberg’s uncertainty principle and steady-state transition. We anticipate that we can find a new way to explain quantum mechanics based on AGM.
Effects of an Inertization System on Waste Plastic Pyrolysis in a Fixed Bed Reactor
Authors: Papuga Saša , Vecchio Ciprioti Stefano , Djurdjevic Milica , Kolundzija Aleksandra
Published: January 2025

This paper reports the results of a study on the significance of the inertization system configuration of a laboratory-scale fixed bed batch reactor with regard to the yield of pyrolysis oil and reactor conversion. Two typical reactor inertization systems were investigated depending on whether the carrier gas (nitrogen in this study) was added from the top or from the bottom of the reactor. Polypropylene (PP) packaging waste (100 g) was used as a model sample. A factorial experimental design was adopted for one categorical parameter, the arrangement of parts of the reactor inertization system. All experiments were conducted at 475 °C, with a carrier gas flow rate of 0.1 L/min and a reaction time of 90 min. Statistical analysis and processing of the results showed that the configuration of the inertization system had a remarkable impact on the pyrolysis oil and gas yield, while its impact on the overall reactor conversion was negligible. When applying the two observed methods of reactor inertization, the average yields of pyrolysis oil and gas differed by 1.7% and 1.8%, respectively. All of the applied statistical treatments had a significance level of 0.05, i.e., there was only a 5% chance of incorrectly rejecting the hypothesis of equality of arithmetic means of pyrolysis yields when the two different methods of reactor inertization were applied. The explanation of this behavior is attributed to the temperature change inside the reactor, which shows that this particular fixed bed reactor suffers from local overheating in its middle part. Local overheating of the middle part of the reactor is more pronounced in the case of inerting the reactor from the bottom, which leads to greater excessive cracking of volatile products compared to the mode of inerting the reactor from the top part and thus greater formation of non-condensable gases, i.e., a reduction in the yield of pyrolytic oil.
Monitoring Brazilian Food Security Based on Emergy Concepts: A Proposed Approach
Authors: Nacimento Rafael Araujo , Canever Mario Duarte , Terra dos Santos Luiz Carlos , Almeida Cecília , Agostinho Feni , Giannetti Biagio Fernando
Published: January 2025

This study enhances the discussion on food security by examining trade equity between food consumers and the supply chain from an emergy perspective. The objective is to develop a food security indicator for Brazil as a case study that provides a holistic view of the historical relationship (from 1995 to 2022) between the emergy and money received by consumers and the emergy and money supplied by the food chain. Each item in the Brazilian food basket was evaluated using the Emergy Exchange Ratio (EER) indicator, which measures the advantages and disadvantages that consumers and the food chain experience in their exchanges. The results indicate that processed food items such as oils and butter generally provide greater net emergy benefits to consumers compared to fresh food items like meat, bananas, tomatoes, and potatoes, which often favor the supply chain. Furthermore, the findings highlight that vulnerable populations face significant challenges in achieving food security due to their increased efforts to generate income relative to the emergy they receive for their social welfare. The proposed food security indicator reveals that consumers enjoyed a more balanced trade since the mid-1990s; however, this trend has recently begun to reverse, underscoring the need for policies that ensure fairer exchanges. This work contributes to discussions on food security by considering an emergy-based approach with the modified Emergy per Money Ratio (EMR) as a complement to traditionally used approaches.
Effects of Green Mussel Shells (Perna viridis) and Chitosan Extracted from Milkfish (Chanos chanos) Scales on the Compressive Strength of Mortar and Concrete
Authors: Lejano Bernardo , Elevado Kenneth Jae , Chua Lorenzo Martin , Cuartero Simon Rohi , Fabian Vince Philip , Rase Alyanna Ysabel
Published: January 2025

It is estimated that in the construction industry, cement production contributes to 7% of global CO2 emissions. Because of this, alternative materials, including biological resources and wastes, are being explored to determine their viability as substitutes for conventional concrete aggregates. This study investigates the feasibility of using green mussel shells (GMSs) as a partial cement replacement and chitosan derived from milkfish scales as an additive in concrete. Addressing environmental concerns tied to cement production, the research evaluates the potential of GMSs and chitosan to enhance mortar and concrete properties. This study was conducted in two phases: phase one focused on mortar with varying percentages of GMSs (0%, 5%, 10%, 15%, and 20%) and chitosan (0%, 0.25%, 0.50%, 0.75%, and 1%), while phase two applied the phase one results that resulted in the highest compressive strength of concrete. The results indicate that 10% GMS and 0.25% chitosan improved mortar strength by 38.74%, although high GMS levels reduced workability. In concrete, 10% GMS without chitosan decreased compressive strength by up to 47% due to magnesium impurities in GMSs, verified by FTIR analysis. This study highlights GMSs’ and chitosan’s potential but emphasizes impurity management for its application feasibility.