bluuebunny/crossref_metadata_2025 huggingface dataset:
A Group-Based Energy-Efficient Dual Priority Scheduling for Real-Time Embedded Systems
Authors: Ge Yongqi , Liu Rui
Published: April 2020

As the limitation of energy consumption of real-time embedded systems becomes more and more strict, it has been difficult to ignore the time overhead and energy consumption of context switches for fixed-priority tasks with preemption scheduling (FPP) in multitasking environments. In addition, the scheduling for different types of tasks may disrupt each other and affect system reliability. A group-based energy-efficient dual priority scheduling (GEDP) is proposed in this paper. The GEDP isolates different types of tasks to avoid the disruption. Furthermore, it also reduces context switches effectively, thus decreasing system energy consumption. As many studies ignored the context switches’ overhead in the worst-case response time (WCRT) model, and it will affect the accuracy of WCRT, thereby affecting the system schedulability. Consequently, the WCRT model is improved based on considering context switches’ overhead. The GEDP is designed and implemented in Linux, and the time overhead and energy consumption of context switches is compared in different situations with GEDP and FPP. The experimental results show that GEDP can reduce context switches by about 1% and decrease energy consumption by about 0.6% for given tasks.
Insecticidal Activity of 11 Bt toxins and 3 Transgenic Maize Events Expressing Vip3Aa19 to Black Cutworm, Agrotis ipsilon (Hufnagel)
Authors: Yan Xiaorui , Lu Junjiao , Ren Meifeng , He Yin , Wang Yueqin , Wang Zhenying , He Kanglai
Published: April 2020

Black cutworm (BCW), Agrotis ipsilon (Hufnagel), is an occasional pest of maize that can cause considerable economic loss and injury to corn seedlings. This research mainly assessed the susceptibility of BCW neonates to 11 Bt toxins (Cry1Ab, Cry1Ac, Cry1Ah, Cry1F, Cry1Ie, Cry1B, Cry2Aa, Vip3_ch1, Vip3_ch4, Vip3Ca2, Vip3Aa19) by exposing neonates to an artificial diet containing Bt toxins and evaluated the efficacy of three transgenic maize events (C008, C009, C010) expressing Vip3Aa19 toxin against BCW. The toxin-diet bioassay data indicated that Vip3Aa19 protein (LC50 = 0.43 μg/g) was the most active against BCW. Chimeric protein Vip3_ch1 (LC50 = 5.53 μg/g), Cry1F (LC50 = 83.62 μg/g) and Cry1Ac (LC50 = 184.77 μg/g) were less toxic. BCW was very tolerant to the other Bt toxins tested, with LC50 values more than 200 μg/g. Greenhouse studies were conducted with artificial infestations at the whorl stage by placing second-instar BCW larvae into whorl leaf and the fourth-instar larvae at the base of maize seedings. These results suggest that these transgenic maize events expressing Vip3Aa19 can provide effective control for BCW.
Predation Pressure in Tea (Camellia sinensis) Plantations in Southeastern China Measured by the Sentinel Prey Method
Authors: Imboma Titus S. , Gao De-ping , You Min-sheng , You Shijun , Lövei Gabor L
Published: April 2020

Tea (Camellia sinensis) is an important food product with thousands of years of human use. Being a non-washable food, no pesticide residues are allowed, which increases the importance of natural means of plant protection. Predation, a component of natural pest control, is an important contributor to this, but its level and sustainability are not known in most of the areas of tea production. We quantified predation intensity using the artificial sentinel prey method in a tea-growing landscape containing remnants of the original forest vegetation in Fujian Province, China. The most common predators were chewing arthropods (49.8% of predation events) and birds (48.1%). Overall, predation rates at the edges of forest fragments (18.9% d-1) were lower than either in fragment interiors (25.4%d−1) or in the surrounding tea plantations (19.2–24.1%d-1). Arthropod predation was higher inside, and at the edge of, forest fragments than within plantations, and generally decreased with increasing distance from a fragment edge, indicating limited spillover of arthropod predators from the native habitat remnants to the cultivated matrix at the local scale. Bird predation, though, showed a different trend: it was lower on the inside of forest fragments than in the tea planation, and bird attack rates increased at increasing distances (up to 40 m) from the forest fragment edge. We also found a reciprocal relationship between attack rates by birds and arthropods, suggesting intra-guild predation. Measures protecting arthropod natural enemies could increase the combined pest suppression effect, contributing to pesticide-free tea production in China.
i-Sustainability Plus Theory as an Innovative Path towards Sustainable World Founded on Blue-Green Ubiquitous Cities (Case Studies: Denmark and South Korea)
Authors: Doost Mohammadian Hamid , Rezaie Fatemeh
Published: April 2020

Nowadays, the new concept of urban living is required as a path to struggle with urbanization challenges in order to maintain the world and make cities better settings for living through creating high quality of life and liveability. To achieve such areas, developing sustainability, urban planning based on Information Technology, Information Communication Technology infrastructure, and innovative management play important roles. So, authors try to find out new concepts of urban life concerned with these indicators through sustainability, innovation, ubiquitous, and smartness to create a sustainable and modern world through smart cities. Based on authors’ researches, Blue-Green infrastructure based on environmentally friendly, green strategies, sustainable water management, and ubiquitous services focusing on digitalization and high technologies are required to make a modern world. Fundamentally, innovation management in technology, business and marketing has important roles in designing such areas by keeping up with growing demands and low resources of energies. In this research, i-Sustainability Plus is introduced as a theory to create Blue-Green Ubiquitous cities as modern sustainable and liveable urban areas. Such areas could make the world a better place for living through sustainable development and improving quality of human life.
Enhancing Strength and Toughness of Hierarchical Composites through Optimization of Position and Orientation of Nanotubes: A Computational Study
Authors: Liu Qiang , Lomov Stepan V. , Gorbatikh Larissa
Published: April 2020

Hierarchical composites that combine microscopic fibers and carbon nanotubes (CNTs) offer opportunities to further improve mechanical properties. Motivated by the experimental evidence that the spatial distribution of CNTs has a significant effect on the strength and toughness of these composites, we developed a novel modelling tool to help us explore mechanisms of strengthening and toughening in an efficient way. The spatial position and orientation of CNTs are chosen as design variables and their optimization is performed on the example of a unidirectional fiber-reinforced composite (FRC) subjected to transverse tensile loading. The model relies on the use of genetic algorithm and finite element method. Our modelling results show that the CNT network with an optimized morphology suppresses stress concentrations in the matrix near the fibers. The optimized morphology is shown to activate a new strengthening and toughening mechanism—diffusion of damage at micro-scale. It allows substantial increase in the consumption of the strain energy by matrix cracking, delocalization of damage, and with it, improvement of the strength and toughness. When the network morphology of 1.0 wt% of CNTs is optimized, the strength and toughness are increased by 49% and 65%, respectively, compared to the pristine FRC. The same amount of homogenously distributed CNTs in the composite leads to only 2% of the strength increase accompanied by a 13% decrease in toughness. The work emphasizes the importance of optimizing spatial position and orientation of CNTs for the strength and toughness improvements of composites.
Properties and Skin Compatibility of Films Based on Poly(Lactic Acid) (PLA) Bionanocomposites Incorporating Chitin Nanofibrils (CN)
Authors: Coltelli Maria-Beatrice , Aliotta Laura , Vannozzi Alessandro , Morganti Pierfrancesco , Panariello Luca , Danti Serena , Neri Simona , Fernandez-Avila Cristina , Fusco Alessandra , Donnarumma Giovanna , Lazzeri Andrea
Published: April 2020

Nanobiocomposites suitable for preparing skin compatible films by flat die extrusion were prepared by using plasticized poly(lactic acid) (PLA), poly(butylene succinate-co-adipate) (PBSA), and Chitin nanofibrils as functional filler. Chitin nanofibrils (CNs) were dispersed in the blends thanks to the preparation of pre-nanocomposites containing poly(ethylene glycol). Thanks to the use of a melt strength enhancer (Plastistrength) and calcium carbonate, the processability and thermal properties of bionanocomposites films containing CNs could be tuned in a wide range. Moreover, the resultant films were flexible and highly resistant. The addition of CNs in the presence of starch proved not advantageous because of an extensive chain scission resulting in low values of melt viscosity. The films containing CNs or CNs and calcium carbonate resulted biocompatible and enabled the production of cells defensins, acting as indirect anti-microbial. Nevertheless, tests made with Staphylococcus aureus and Enterobacter spp. (Gram positive and negative respectively) by the qualitative agar diffusion test did not show any direct anti-microbial activity of the films. The results are explained considering the morphology of the film and the different mechanisms of direct and indirect anti-microbial action generated by the nanobiocomposite based films.
Brachial Plexus Injuries in Sport Medicine: Clinical Evaluation, Diagnostic Approaches, Treatment Options, and Rehabilitative Interventions
Authors: Belviso Immacolata , Palermi Stefano , Sacco Anna Maria , Romano Veronica , Corrado Bruno , Zappia Marcello , Sirico Felice
Published: April 2020

The brachial plexus represents a complex anatomical structure in the upper limb. This “network” of peripheral nerves permits the rearrangement of motor efferent fibers, coming from different spinal nerves, in several terminal branches directed to upper limb muscles. Moreover, afferent information coming from different cutaneous regions in upper limb are sorted in different spinal nerves through the brachial plexus. Severe brachial plexus injuries are a rare clinical condition in the general population and in sport medicine, but with dramatic consequences on the motor and sensory functions of the upper limb. In some sports, like martial arts, milder injuries of the brachial plexus can occur, with transient symptoms and with a full recovery. Clinical evaluation represents the cornerstone in the assessment of the athletes with brachial plexus injuries. Electrodiagnostic studies and imaging techniques, like magnetic resonance and high-frequency ultrasound, could be useful to localize the lesion and to define an appropriate treatment and a functional prognosis. Several conservative and surgical techniques could be applied, and multidisciplinary rehabilitative programs could be performed to guide the athlete toward the recovery of the highest functional level, according to the type of injury.
Mitochondrial Functioning and Its Relation to Higher-Order Cognitive Processes
Authors: Burgoyne Alexander P. , Engle Randall W.
Published: April 2020

One of the most replicated findings in psychology is the positive manifold between cognitive ability measures (Jensen 1998; Spearman 1904) [...]
Assessing an Improved Bayesian Model for Directional Motion Based Wave Inference
Authors: Mas-Soler Jordi , Souto-Iglesias Antonio , Simos Alexandre N.
Published: April 2020

An innovative Bayesian motion-based wave inference method is derived and assessed in this work. The evaluation of the accuracy of the proposed prior distribution has been carried out using the results obtained during a dedicated experimental campaign with a scale model an Oil and Gas (O&G) semisubmersible platform. As for the Bayesian statistical inference approaches, the features of the proposed novel prior distribution, as well as the hypotheses adopted, are discussed. It has been found that significant improvements can be obtained if the new approach is adopted to estimate the sea conditions from measured vessel motions. Finally, it is possible to highlight a substantial reduction of the computing time when the sea conditions are estimated by means of the improved Bayesian method, if compared with the conventional approaches for motion-based wave inference.
An Improved Underwater Electric Field-Based Target Localization Combining Subspace Scanning Algorithm And Meta-EP PSO Algorithm
Authors: Shang Wenjing , Xue Wei , Li Yingsong , Wu Xiangshang , Xu Yidong
Published: April 2020

In this paper, we propose an improved three-dimensional underwater electric field-based target localization method. This method combines the subspace scanning algorithm and the meta evolutionary programming (meta-EP) particle swarm optimization (PSO) algorithm. The subspace scanning algorithm is applied as the evaluation function of the electric field-based underwater target locating problem. The meta-EP PSO method is used to select M elite particles by the q-tournament selection method, which could effectively reduce the computational complexity of the three-dimensional underwater target localization. Moreover, the proposed meta-EP PSO optimization algorithm can avoid subspace scanning trapping into local minima. We also analyze the positioning performance of the uniform circular and cross-shaped electrodes arrays by using the subspace scanning algorithm combined with meta–EP PSO. According to the simulation, the calculation amount of the proposed algorithm is greatly reduced. Moreover, the positioning accuracy is effectively improved without changing the positioning accuracy and search speed.
A Method of Navigational Information Display Using Augmented Virtuality
Authors: Gralak Rafał
Published: April 2020

The preliminary research experiments described herein were aimed to choose an appropriate mixed reality technology for the construction of navigational information display method to be used onboard ships in restricted waters. The method assumes a possibly faithful representation of the environment and the actual navigational situation on a spatial decision support system (SDSS) interface during ship navigation and maneuvering in restricted waters. The paper also presents the architecture and process of building a SDSS, where the method of navigational information display using augmented virtuality was applied.
Underlying Conditions and Clinical Spectrum of Chronic Pulmonary Aspergillosis (CPA): An Experience from a Tertiary Care Hospital in Karachi, Pakistan
Authors: Iqbal Nousheen , Irfan Muhammad , Mushtaq Ammar , Jabeen Kauser
Published: April 2020

The incidence of chronic pulmonary aspergillosis (CPA) is especially increasing in high tuberculosis (TB) burden countries. Despite a high estimated CPA burden in Pakistan, actual data on CPA are not available. The aim of the current study is to determine the underlying conditions and clinical spectrum of CPA at a tertiary care hospital in Karachi, Pakistan. This is a retrospective chart review study in patients admitted with CPA from January 2012 to December 2017. A total of 67 patients were identified during the study period. Mean age of CPA patients was 45.9 ± 15 years, 44 (65.7%) were male and 19 (28.4%) had diabetes. The most common type of CPA was simple aspergilloma (49.2%) followed by chronic cavitary pulmonary aspergillosis (CCPA) (44.7%). TB was the underlying cause of CPA in 58 (86.6%) patients followed by bronchiectasis caused by allergic bronchopulmonary aspergillosis (ABPA) 8 (11.9%). Aspergillus flavus was identified in 17 (47.2%), followed by A. fumigatus in 13 (36.1%) CPA patients. Isolation of multiple Aspergillus species was found in 10 (25.6%) patients. Itraconazole was given in 27 (40.3%) patients and a combination therapy of itraconazole and surgery was given in 21 (31.34%) patients. We found aspergilloma and CCPA as the most prevalent forms of CPA in our setting. Further large prospective studies using Aspergillus specific immunoglobulin G (IgG) antibodies testing are required for better understanding of CPA in Pakistan.
Impact of ITS-Based Sequencing on Antifungal Treatment of Patients with Suspected Invasive Fungal Infections
Authors: Guenter Sara , Gorkiewicz Gregor , Halwachs Bettina , Kashofer Karl , Thueringer Andrea , Wurm Phillip , Zollner-Schwetz Ines , Valentin Thomas , Prattes Juergen , Wunsch Stefanie , Ullrich Elisabeth , Zurl Christoph , Hoenigl Martin , Krause Robert
Published: April 2020

Molecular techniques including the sequencing of fungal-specific DNA targets are increasingly used in the diagnosis of suspected invasive fungal infections. In contrast to established biomarkers like galactomannan or 1-3-β-d-glucan, the clinical impact of these methods remains unknown. We retrospectively investigated the impact of ITS1-sequencing on antifungal treatment strategies in 71 patients (81 samples) with suspected invasive fungal infections. ITS-sequencing either confirmed already ongoing antifungal therapy (19/71 patients, 27%), led to a change in antifungal therapy (11/71, 15%) or supported the decision to withhold antifungal treatment (34/71, 48%) (in seven of 71 patients, ITS-sequencing results were obtained postmortem). ITS-sequencing results led to a change in antifungal therapy in a relevant proportion of patients, while it confirmed therapeutic strategies in the majority. Therefore, ITS-sequencing was a useful adjunct to other fungal diagnostic measures in our cohort.
Melting and Recrystallization of Copper Nanoparticles Prepared by Microwave-Assisted Reduction in the Presence of Triethylenetetramine
Authors: Jheng Li-Cheng , Wang Yen-Zen , Huang Wen-Yao , Ho Ko-Shan , Tsai Cheng-Hsien , Huang Ching-Tang , Tsai Huang-Shian
Published: April 2020

The small sized copper nanoparticles (Cu-NPs), prepared in the presence of triethylene tetramine (TETA) and assisted with microwave irradiation, have an extremely low melting temperature. Melting of the small sizezd Cu-NPs can be triggered by the heat generated from the e-beam irradiation during SEM and TEM image construction. The dispersed Cu atoms around the agglomerated big Cu particles can undergo recrystallization immediately due to the strong driving force of the huge temperature difference to normal melting temperature (Tm = 1085 °C). Some of the Cu-NPs with bigger sizes also recrystallize and agglomerate into dense, big particles. According to X-ray diffraction patterns, these particles can agglomerate into compact, ordered Cu crystals in less than five minutes at 60 °C. The melting and recrystallization related endothermic and exothermic phase transitions of Cu-NPs can be found from differential scanning calorimeter (DSC) thermograms and optical microscopic pictures.
Effect of Gradient Energy Density on the Microstructure and Mechanical Properties of Ti6Al4V Fabricated by Selective Electron Beam Additive Manufacture
Authors: Hsu Ta-I , Jhong Yu-Ting , Tsai Meng-Hsiu
Published: April 2020

Selective Electron Beam Additive Manufacturing (SEBAM) is a promising powder bed fusion additive manufacturing technique for titanium alloys that select particular area melting in different energy density for producing complexly shaped biomedical devices. For most commercial Ti6Al4V porous medical devices, the gradient energy density is usually applied to manufacture in one component during the SEBAM process which selects different energy density built on particular zones. This paper presents gradient energy density base characterization study on an SEBAM built rectangular specimen with a size of 3 mm × 20 mm × 60 mm. The specimen was divided into three zones were built in gradient energy density from 16 to 26.5 J/mm3. The microstructure and mechanical properties were investigated by means of scanning electron microscopy, X-ray diffraction, transmission electron microscopy and mechanical test. The α′ martensitic and lack of fusion were observed in the low energy density (LED) built zone. However, no α′ phase and no irregular pores were observed both in overlap energy density (OED) and high energy density (HED) built zones located at the middle and bottom of the specimen respectively. This implies the top location and lower energy density have positive effects on the cooling rate but negative effects on densification. The subsequence mechanical properties result also supports this point. Moreover, the intermetallic Ti3Al found in the bottom may be due to the heat transfer from the following melting layer. Furthermore, the microstructure evolution in gradient energy built zones is discussed based on the findings of the microstructure and thermal history correlation analysis.
Well-Defined Diblock Poly(ethylene glycol)-b-Poly(ε-caprolactone)-Based Polymer-Drug Conjugate Micelles for pH-Responsive Delivery of Doxorubicin
Authors: Jafari Amin , Yan Lingyue , Mohamed Mohamed Alaa , Wu Yun , Cheng Chong
Published: April 2020

Nanoparticles have emerged as versatile carriers for various therapeutics and can potentially treat a wide range of diseases in an accurate and disease-specific manner. Polymeric biomaterials have gained tremendous attention over the past decades, owing to their tunable structure and properties. Aliphatic polyesters have appealing attributes, including biodegradability, non-toxicity, and the ability to incorporate functional groups within the polymer backbone. Such distinctive properties have rendered them as a class of highly promising biomaterials for various biomedical applications. In this article, well-defined alkyne-functionalized poly(ethylene glycol)-b-poly(ε-caprolactone) (PEG-b-PCL) diblock copolymer was synthesized and studied for pH-responsive delivery of doxorubicin (DOX). The alkyne-functionalized PEG-b-PCL diblock copolymer was prepared by the synthesis of an alkyne-functionalized ε-caprolactone (CL), followed by ring-opening polymerization (ROP) using PEG as the macroinitiator. The alkyne functionalities of PEG-b-PCL were modified through copper(I)-catalyzed alkyne-azide cycloaddition (CuAAC) click reaction to graft aldehyde (ALD) groups and obtain PEG-b-PCL-g-ALD. Subsequently, DOX was conjugated on PEG-b-PCL-g-ALD through the Schiff base reaction. The resulting PEG-b-PCL-g-DOX polymer-drug conjugate (PDC) self-assembled into a nano-sized micellar structure with facilitated DOX release in acidic pH due to the pH-responsive linkage. The nanostructures of PDC micelles were characterized using transmission electron microscopy (TEM) and dynamic light scattering (DLS). In vitro studies of the PDC micelles, revealed their improved anticancer efficiency towards MCF-7 cells as compared to free DOX.
Active Transiency: A Novel Approach to Expedite Degradation in Transient Electronics
Authors: Jamshidi Reihaneh , Chen Yuanfen , Montazami Reza
Published: April 2020

Transient materials/electronics is an emerging class of technology concerned with materials and devices that are designed to operate over a pre-defined period of time, then undergo controlled degradation when exposed to stimuli. Degradation/transiency rate in solvent-triggered devices is strongly dependent on the chemical composition of the constituents, as well as their interactions with the solvent upon exposure. Such interactions are typically slow, passive, and diffusion-driven. In this study, we are introducing and exploring the integration of gas-forming reactions into transient materials/electronics to achieve expedited and active transiency. The integration of more complex chemical reaction paths to transiency not only expedites the dissolution mechanism but also maintains the pre-transiency stability of the system while under operation. A proof-of-concept transient electronic device, utilizing sodium-bicarbonate/citric-acid pair as gas-forming agents, is demonstrated and studied vs. control devices in the absence of gas-forming agents. While exhibiting enhanced transiency behavior, substrates with gas-forming agents also demonstrated sufficient mechanical properties and physical stability to be used as platforms for electronics.
Phase Evolution, Filler-Matrix Interactions, and Piezoelectric Properties in Lead Zirconate Titanate (PZT)-Filled Polymer-Derived Ceramics (PDCs)
Authors: Eichhorn Franziska , Kellermann Simone , Betke Ulf , Fey Tobias
Published: April 2020

PZT-silsesquioxane-based 0-3 hybrid materials are prepared by mixing lead zirconate titanate (Pb(Zr,Ti)O3; PZT) powder with a [R-SiO3/2]n (R = H, CH3, CH=CH2, C6H5) silsequioxane preceramic polymer. A PZT load up to 55 vol.% can be reached in the final composite. The piezoelectric and mechanical properties are investigated as a function of the filler content and are compared with theoretical models and reference samples made of the pure preceramic polymer or PZT filler. The piezoelectric response of the composites, as expressed by the relative permittivity and the piezoelectric coefficients d33 and g33, increases with an increasing PZT content. The bending strength of the composites ranges between 15 MPa and 31 MPa without a clear correlation to the filler content. The thermal conductivity increases significantly from 0.14 W∙m−1∙K−1 for the pure polymer-derived ceramic (PDC) matrix to 0.30 W∙m−1∙K−1 for a sample containing 55 vol.% PZT filler. From X-ray diffraction experiments (XRD), specific interactions between the filler and matrix are observed; the crystallization of the PDC matrix in the presence of the PZT filler is inhibited; conversely, the PDC matrix results in a pronounced decomposition of the filler compared to the pure PZT material.
Complex Corrosion Properties of AISI 316L Steel Prepared by 3D Printing Technology for Possible Implant Applications
Authors: Hlinka Josef , Kraus Martin , Hajnys Jiri , Pagac Marek , Petrů Jana , Brytan Zbigniew , Tański Tomasz
Published: April 2020

This paper deals with the investigation of complex corrosion properties of 3D printed AISI 316L steel and the influence of additional heat treatment on the resulting corrosion and mechanical parameters. There was an isotonic solution used for the simulation of the human body and a diluted sulfuric acid solution for the study of intergranular corrosion damage of the tested samples. There were significant microstructural changes found for each type of heat treatment at 650 and 1050 °C, which resulted in different corrosion properties of the tested samples. There were changes of corrosion potential, corrosion rate and polarization resistance found by the potentiodynamic polarization method. With regard to these results, the most appropriate heat treatment can be applied to applications with intended use in medicine.
Effects of Recessed-Gate Structure on AlGaN/GaN-on-SiC MIS-HEMTs with Thin AlOxNy MIS Gate
Authors: Kim Hyun-Seop , Kang Myoung-Jin , Kim Jeong Jin , Seo Kwang-Seok , Cha Ho-Young
Published: April 2020

This study investigated the effects of a thin aluminum oxynitride (AlOxNy) gate insulator on the electrical characteristics of AlGaN/GaN-on-SiC metal-insulator-semiconductor high electron mobility transistors (MIS-HEMTs). The fabricated AlGaN/GaN-on-SiC MIS-HEMTs exhibited a significant reduction in gate leakage and off-state drain currents in comparison with the conventional Schottky-gate HEMTs, thus enhancing the breakdown voltage. The effects of gate recess were also investigated while using recessed MIS-HEMT configuration. The Johnson’s figures of merit (= fT × BVgd) for the fabricated MIS-HEMTs were found to be in the range of 5.57 to 10.76 THz·V, which is the state-of-the-art values for GaN-based HEMTs without a field plate. Various characterization methods were used to investigate the quality of the MIS and the recessed MIS interface.
Preparation and Reflectance Spectrum Modulation of Cr2O3 Green Pigment by Solution Combustion Synthesis
Authors: Ai Shuhe , Zheng Huade , Yu Jincheng
Published: April 2020

An amorphous precursor of Cr2O3 pigment was prepared via solution combustion synthesis. After calcination at 1000 °C for 1.0 h, the precursor was converted into well-crystallized submicron Cr2O3 crystals with uniform particle distribution and low aggregation. Furthermore, Ti, Co, and Fe were doped into the lattice of Cr2O3, and the effects of these dopants on the reflectance spectroscopy modulation as well as chromatic properties were investigated in detail. As a result, a series of Cr2O3 pigment samples sharing similar spectra within the wavelength from 400 to 1600 nm with green plants could be successfully fabricated.
How Reproducible are Electrochemical Impedance Spectroscopic Data for Dye-Sensitized Solar Cells?
Authors: Becker Mariia , Bertrams Maria-Sophie , Constable Edwin C. , Housecroft Catherine E.
Published: April 2020

Dye-sensitized solar cell (DSC) technology has been broadly investigated over the past few decades. The sandwich-type structure of the DSC makes the manufacturing undemanding under laboratory conditions but results in the need for reproducible measurements for acceptable DSC characterization. Electrochemical impedance spectroscopy (EIS) offers the possibility to study complex electronic systems and is commonly used for solar cells. There is a tendency in the literature to present impedance data only for one representative device. At the same time, as current density–voltage plots illustrate, measurements can vary within one set of DSCs with identical components. We present multiple DSC impedance measurements on “identical” devices prepared using two different dyes and present a statistical analysis regarding the reproducibility.
Evaluation of the Effect of Fiber Type, Length, and Content on Asphalt Properties and Asphalt Mixture Performance
Authors: Guo Fucheng , Li Rui , Lu Shuhua , Bi Yanqiu , He Haiqi
Published: April 2020

Fiber-reinforced asphalt mixture has been widely used in pavement engineering to not only prevent asphalt binder leakage but also improve engineering properties of asphalt mixture. However, the research on three key parameters, namely fiber type, fiber length, and fiber content, which significantly affect the performance of fiber-reinforced asphalt mixture, have seldom been conducted systematically. To determine these three key parameters in the support of the application of fibers in mixture scientifically, three commonly used fibers were selected, basalt fiber, polyester fiber, and lignin fiber, and the testing on fibers, fiber-reinforced asphalt binders, and fiber-reinforced asphalt mixtures was conducted afterwards. The results showed: the favorable fiber type was basalt fiber; the favorable basalt fiber length was 6mm; the engineering properties including high temperature stability, low temperature crack resistance, and water susceptibility were clearly improved by the added basalt fiber, and the optimum basalt fiber content was 0.4 wt.%. The obtained results may be valuable from a practical point of view to engineers and practitioners.
Fretting and Fretting Corrosion Processes of Ti6Al4V Implant Alloy in Simulated Oral Cavity Environment
Authors: Klekotka Marcin , Dąbrowski Jan Ryszard , Rećko Katarzyna
Published: April 2020

The paper presents the results of in vitro studies of fretting and fretting corrosion processes of Ti6Al4V implant alloy in the environment of natural saliva and self-made mucin-based artificial saliva solutions. The study was performed on a specially designed fretting pin-on-disc tester, which was combined with a set used for electrochemical research. The open circuit potential measurements and potentiodynamic method were used for corrosion tests. The worn surfaces were subjected to microscopic observations and an evaluation of wear. Results were interpreted using the dissipated energy and third-body approaches. The X-ray diffraction analysis showed that titanium oxides constitute over 80% of the friction products. Special attention was paid to the role of saliva and its substitutes, which in certain cases can lead to the intensification of fretting wear. On the basis of the received results, a new phenomenological model of fretting corrosion processes was proposed. This model involves the formation of an abrasive paste that is a combination of metal oxides and the organic components of saliva.
Composite Sulfonated Polyether-Ether Ketone Membranes with SBA-15 for Electrochemical Energy Systems
Authors: Rico-Zavala A. , Pineda-Delgado J. L. , Carbone A. , Saccà A. , Passalacqua E. , Gurrola M.P. , Alvarez A. , Rivas S. , Ledesma-García J. , Arriaga L.G.
Published: April 2020

The aim of this work is the evaluation of a Sulfonated Poly Ether-Ether Ketone (S-PEEK) polymer modified by the addition of pure Santa Barbara Amorphous-15 (SBA-15, mesoporous silica) and SBA-15 previously impregnated with phosphotungstic acid (PWA) fillers (PWA/SBA-15) in order to prepare composite membranes as an alternative to conventional Nafion® membranes. This component is intended to be used as an electrolyte in electrochemical energy systems such as hydrogen and methanol Proton Exchange Membrane Fuel Cell (PEMFC) and Electrochemical Hydrogen Pumping (EHP). The common requirements for all the applications are high proton conductivity, thermomechanical stability, and fuel and oxidant impermeability. The morphology of the composite membranes was investigated by Scanning Electron Microscopy- Energy Dispersive X-ray Spectroscopy (SEM-EDS) analysis. Water Uptake (Wup), Ion Exchange Capacity (IEC), proton conductivity, methanol permeability and other physicochemical properties were evaluated. In PEMFC tests, the S-PEEK membrane with a 10 wt.% SBA-15 loading showed the highest performance. For EHP, the inclusion of inorganic materials led to a back-diffusion, limiting the compression capacity. Concerning methanol permeability, the lowest methanol crossover corresponded to the composites containing 5 wt.% and 10 wt.% SBA-15.
Design and Optimization of the Local Laser Treatment to Improve the Formability of Age Hardenable Aluminium Alloys
Authors: Piccininni Antonio , Palumbo Gianfranco
Published: April 2020

The research of innovative methodologies to improve the Aluminium alloys formability at room temperature still remains an open question: the local modification of the material properties via short-term heat treatments followed by the stamping at room temperature is reported to be an effective alternative to the forming in warm conditions. In the present work, such a methodology has been applied to the deep drawing of an age-hardenable Aluminium alloy (AA6082-T6) using an experimental/numerical approach. A preliminary extensive material characterization was aimed at investigating the material behaviour: (i) in the as-received condition (peak hardening), (ii) in the supersaturated condition (obtained by physical simulation) and (iii) after being locally solutioned via laser heating. A Finite Element based approach (Abaqus CAE, v. 6.17) was then used to design the laser treatment of the blanks to be subsequently deep drawn at room temperature: a 2D axisymmetric model of the deep drawing process was coupled with the optimization platform modeFRONTIER in order to define the radial extent of the laser heat treated area able to maximize the Limit Drawing Ratio. The experimental tests were finally conducted for validation purposes and revealed the effectiveness of the adopted approach which allowed to improve the drawability of more than 20% with respect to the as received condition (T6).
Exploring the Critical Thickness of Organic Semiconductor Layer for Enhanced Piezoresistive Sensitivity in Field-Effect Transistor Sensors
Authors: Thuau Damien , Begley Katherine , Dilmurat Rishat , Ablat Abduleziz , Wantz Guillaume , Ayela Cédric , Abbas Mamatimin
Published: April 2020

Organic semiconductors (OSCs) are promising transducer materials when applied in organic field-effect transistors (OFETs) taking advantage of their electrical properties which highly depend on the morphology of the semiconducting film. In this work, the effects of OSC thickness (ranging from 5 to 15 nm) on the piezoresistive sensitivity of a high-performance p-type organic semiconductor, namely dinaphtho [2,3-b:2,3-f] thieno [3,2–b] thiophene (DNTT), were investigated. Critical thickness of 6 nm thin film DNTT, thickness corresponding to the appearance of charge carrier percolation paths in the material, was demonstrated to be highly sensitive to mechanical strain. Gauge factors (GFs) of 42 ± 5 and −31 ± 6 were measured from the variation of output currents of 6 nm thick DNTT-based OFETs engineered on top of polymer cantilevers in response to compressive and tensile strain, respectively. The relationship between the morphologies of the different thin films and their corresponding piezoresistive sensitivities was discussed.
Microwave-Assisted Glycerol Etherification Over Sulfonic Acid Catalysts
Authors: Aguado-Deblas Laura , Estevez Rafael , Russo Marco , La Parola Valeria , Bautista Felipa M. , Testa Maria Luisa
Published: April 2020

Glycerol is the main by-product of biodiesel production. For this reason, its valorization into value-added products, by using green procedures, represents an important goal. Different sulfonic acid silica- or titania-based catalysts were prepared, characterized and tested in the glycerol etherification process, assisted by microwaves, in order to obtain biodiesel additives. The surface and structural properties of the catalysts were investigated by means of N2 adsorption isotherms, thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS) and acid capacity measurements by X-Ray Fluorescence Spectroscopy (XRF). The best performance in terms of activity was achieved in the presence of the sulfonic function directly linked to the amorphous silica. By the correlation of the structure properties of the materials and their activity, the performance of the catalysts was shown to be influenced mainly by the surface area, pore volume and acidity. Recycling experiments performed over the most active systems showed that the sulfonic silica-based materials maintained their performance during several cycles.
Soft-Lithography of Polyacrylamide Hydrogels Using Microstructured Templates: Towards Controlled Cell Populations on Biointerfaces
Authors: Díaz Lantada Andrés , Mazarío Picazo Noelia , Guttmann Markus , Wissmann Markus , Schneider Marc , Worgull Matthias , Hengsbach Stefan , Rupp Florian , Bade Klaus , Plaza Gustavo R.
Published: April 2020

Polyacrylamide hydrogels are interesting materials for studying cells and cell–material interactions, thanks to the possibility of precisely adjusting their stiffness, shear modulus and porosity during synthesis, and to the feasibility of processing and manufacturing them towards structures and devices with controlled morphology and topography. In this study a novel approach, related to the processing of polyacrylamide hydrogels using soft-lithography and employing microstructured templates, is presented. The main novelty relies on the design and manufacturing processes used for achieving the microstructured templates, which are transferred by soft-lithography, with remarkable level of detail, to the polyacrylamide hydrogels. The conceived process is demonstrated by patterning polyacrylamide substrates with a set of vascular-like and parenchymal-like textures, for controlling cell populations. Final culture of amoeboid cells, whose dynamics is affected by the polyacrylamide patterns, provides a preliminary validation of the described strategy and helps to discuss its potentials.
Characteristics of Heat Resistant Aluminum Alloy Composite Core Conductor Used in overhead Power Transmission Lines
Authors: Qiao Kun , Zhu Anping , Wang Baoming , Di Chengrui , Yu Junwei , Zhu Bo
Published: April 2020

The heat resistant aluminum alloy wire composite material core conductor (ACCC/HW) which was used in overhead transmission lines is developed and studied in this work. The composite material core is carbon fiber/glass cloth reinforced modified epoxy resin composite. Tensile stress tests and stress-strain tests of both composite core and conductor are taken at 25 °C and 160 °C. Sag test, creep test and current carrying capacity test of composite conductor are taken. The stress of composite conductor are 425.2 MPa and 366.9 MPa at 25 °C and 160 °C, respectively. The sag of conductor of 50 m length are 95 mm, 367 mm, and 371 mm at 25 °C, 110 °C, and 160 °C, respectively. The creep strain are 271 mm/km, 522 mm/km, and 867 mm/km after 10 years under the tension of 15% RTS (Rated Tensile Strength), 25% RTS and 35% RTS at 25 °C, and 628 mm/km under 25% RTS at 160 °C, according to the test result and calculation. The carrying capacity of composite conductor is basically equivalent to ACSR (Aluminum Conductor Steel Reinforced). ACCC/HW is suitable in overhead transmission lines, and it has been used in 50 kV power grid, according to the results.
Use of Slag from the Combustion of Solid Municipal Waste as A Partial Replacement of Cement in Mortar and Concrete
Authors: Czop Monika , Łaźniewska-Piekarczyk Beata
Published: April 2020

In Europe, the use of wastes in the cement and construction industry follows the assumptions of sustainability and the idea of circular economy. At present, it is observed that cement plants introduce wastes to the cement in the form of so-called mineral additives. The most often used mineral additives are: fly ash with silica fume, granulated blast furnace slag and silica fume. The use of mineral additives in the cement is related to the fact that the use of the most expensive component of cement—Portland cement clinker—is limited. The purpose of the article is a preliminary evaluation of the suitability of slag from the municipal solid waste incineration plant for its use as a replacement of cement. In this article, slag from the municipal solid waste incineration (MSWI) replaces cement in the quantity of 30%, and presents the content of oxides and elements of slag from the MSWI. The obtained results are compared to the requirements that the crushed and granulated blast furnace slag need to meet to be suitable for use as an additive of type II to the concrete. The conducted analyses confirmed that the tested slag meets the requirements for the granulated blast furnace slag as an additive to the concrete in the following parameters: CaO ≤ 18.0%, SO3 ≤ 2.5% and Cl ≤ 0.1%. At the same time, mechanical features were tested of the designed mortars which consisted of a mixture of Portland cement (CEM I) with 30% of slag admixture. The designed mortar after 28 days of maturing reached a compressive strength of 32.0 MPa, and bending strength of 4.0 MPa. When compared to the milled granulated blast furnace slag (GBFS), the obtained values are slightly lower. Furthermore, the hardened mortars were subject to a leachability test to check the impact on the environment. Test results showed that the aqueous extracts from mixtures with 30% of slag admixtures slightly exceed the limits and do not pose a sufficiant threat to the environment as to eliminate the MSWI slag from economical use.
FE Analyses of Hyperelastic Solids under Large Bending: The Role of the Searle Parameter and Eulerian Slenderness
Authors: Oyedeji Falope Federico , Lanzoni Luca , Tarantino Angelo Marcello
Published: April 2020

A theoretical model concerning the finite bending of a prismatic hyperelastic solid has been recently proposed. Such a model provides the 3D kinematics and the stress field, taking into account the anticlastic effects arising in the transverse cross sections also. That model has been used later to extend the Elastica in the framework of finite elasticity. In the present work, Finite Element (FE) analyses of some basic structural systems subjected to finite bending have been carried out and the results have been compared with those provided by the theoretical model performed previously. In the theoretical formulation, the governing equation is the nonlinear local relationship between the bending moment and the curvature of the longitudinal axis of the bent beam. Such a relation has been provided in dimensionless form as a function of the Mooney–Rivlin constitutive constants and two kinematic dimensionless parameters termed Eulerian slenderness and compactness index of the cross section. Such parameters take relevance as they are involved in the well-known Searle parameter for bent solids. Two significant study cases have been investigated in detail. The results point out that the theoretical model leads to reliable results provided that the Eulerian slenderness and the compactness index of the cross sections do not exceed fixed threshold values.
Data-Oriented Constitutive Modeling of Plasticity in Metals
Authors: Hartmaier Alexander
Published: April 2020

Constitutive models for plastic deformation of metals are typically based on flow rules determining the transition from elastic to plastic response of a material as function of the applied mechanical load. These flow rules are commonly formulated as a yield function, based on the equivalent stress and the yield strength of the material, and its derivatives. In this work, a novel mathematical formulation is developed that allows the efficient use of machine learning algorithms describing the elastic-plastic deformation of a solid under arbitrary mechanical loads and that can replace the standard yield functions with more flexible algorithms. By exploiting basic physical principles of elastic-plastic deformation, the dimensionality of the problem is reduced without loss of generality. The data-oriented approach inherently offers a great flexibility to handle different kinds of material anisotropy without the need for explicitly calculating a large number of model parameters. The applicability of this formulation in finite element analysis is demonstrated, and the results are compared to formulations based on Hill-like anisotropic plasticity as reference model. In future applications, the machine learning algorithm can be trained by hybrid experimental and numerical data, as for example obtained from fundamental micromechanical simulations based on crystal plasticity models. In this way, data-oriented constitutive modeling will also provide a new way to homogenize numerical results in a scale-bridging approach.
Effect of Adhesion on Mechanical and Tribological Properties of Glass Fiber Composites, Based on Ultra-High Molecular Weight Polyethylene Powders with Various Initial Particle Sizes
Authors: Panin Sergey V. , Kornienko Lyudmila A. , Huang Qitao , Buslovich Dmitry G. , Bochkareva Svetlana A. , Alexenko Vladislav O. , Panov Iliya L. , Berto Filippo
Published: April 2020

The aim of this study was to assess the effect of adhesion between the non-polar, ultra-high molecular weight polyethylene (UHMWPE) matrix and the glass fiber fillers of various lengths treated with the commercially available “KH-550” agent, on the mechanical and tribological properties of the UHMWPE-based composites. The motivation was to find the optimal compositions of the polymer composite, for the compression sintering manufacturing of lining plates for the protection of marine venders and construction vehicles, as well as transport equipment. It was shown that the initial powder size at equal molecular weight determined the distribution patterns of the glass fibers in the matrix, and, as a consequence, the mechanical and tribological properties of the composites. Based on the obtained experimental data and the results of the calculation by a developed computer algorithm, control parameters were determined to give practical recommendations (polymer powder size and glass fiber length), for the production of the UHMWPE-composites having specified mechanical and tribological characteristics. The “GUR4022 + 10% LGF” composite, loaded with the chopped 3 mm glass fibers treated with the “KH-550”, was recommended for severe operating conditions (high loads, including impact and abrasive wear). For mild operating conditions (including cases when the silane coupling agent could not be used), the “GUR2122 + 10% MGF” and “GUR2122 + 10% LGF” composites, based on the fine UHMWPE powder, were recommended. However, the cost and technological efficiency of the filler (flowability, dispersibility) and polymer powder processing should be taken into account, in addition to the specified mechanical and tribological properties.