bluuebunny/crossref_metadata_2025 huggingface dataset:
Flexural Response and Failure Analysis of Solid and Hollow Core Concrete Beams with Additional Opening at Different Locations
Authors: Sharaky Ibrahim A. , Elamary Ahmed S. , Alharthi Yasir M.
Published: December 2021

It is essential to make openings in structural concrete elements to accommodate mechanical and electrical needs. To study the effect of these openings on the performance of reinforced concrete (RC) elements, a numerical investigation was performed and validated using previous experimental work. The effect of the position and dimension of the opening and the beam length on the response of the beams, loads capacities, and failure modes was studied. The simulated RC beams showed different responses, loads capacities, and failure modes depending on the position and dimension of the opening. The transversal near support opening (TNSH) and longitudinal holes (LH) showed lower effects on the load capacities of the beams than the transversal near center opening (TNCH). The supreme reduction percentages of the load capacity (µu%) for beams with TNCH and TNSH were 37.21% and 30.34%, respectively (opening size = 150 × 150 mm2). In addition, the maximum µu% for beam with LH was 17.82% (opening size = 25% of the beam size). The TNSH with a width of less than 18.18% of the beam shear span (550 mm) had trivial effects on the beam’s load capacities (the maximum µu% = 1.26%). Although the beams with combined LH and TNCH or LH and TNSH showed different failure modes, they experienced nearly the same load reductions. Moreover, the length of the beam (solid or hollow) had a great effect on its failure mode and load capacity. Finally, equations were proposed and validated to calculate the yield load and post-cracking deflection for the concrete beams with a longitudinal opening.
Transformation of the Metastable Al6Fe Intermetallic Phase during Homogenization of a Binary Al-Fe Alloy
Authors: Arbeiter Jože , Vončina Maja , Šetina Batič Barbara , Medved Jožef
Published: December 2021

Within the scope of this research the transformation of the Al6Fe metastable phase was analyzed via Differential Scanning Calorimetry (DSC), optical and Scanning Electron Microscopy (SEM) and X-ray Diffraction (XRD). A binary Al-Fe1.1 low-impurity alloy was produced with refined raw materials in a controlled environment. With a cooling rate of 35 K/s, solidification of the Al6Fe metastable phase was achieved. The samples were homogenized at 600 °C for 2–24 h. Results of a qualitative analysis of metallographic samples show that the transformation began on grain boundaries, forming an Fe-phase free region, but after 2 h began to take place within the eutectic region. The transformation is mostly complete after 12 h, but after 24 h of homogenization it is fully complete as all samples, except the 24 h homogenized one, contain both the metastable Al6Fe and the stable Al13Fe4 phase.
Energy Absorbing Properties Analysis of Layers Structure of Titanium Alloy Ti6Al4V during Dynamic Impact Loading Tests
Authors: Głowacki Dominik , Moćko Wojciech , Marczak Michał , Głowacka Anna , Kraśkiewicz Cezary
Published: December 2021

This paper presents the testing methodology of specimens made of layers of titanium alloy Ti6Al4V in dynamic impact loading conditions. Tests were carried out using a drop-weight impact tower. The test methodology allowed us to record parameters as displacement or force. Based on recorded data, force and absorbed energy curves during plastic deformation and sheet perforation were created. The characteristics of the fractures were also analyzed. The impact test simulation was carried out in the ABAQUS/Explicit environment. Results for one, two, and three layers of titanium alloy were compared. The increase in force required to initialize the damage and the absorbed energy during plastic deformation can be observed with an increase in the number of layers. The increase in absorbed energy is close to linear. In the simulation process, parameters such as Huber–Mises–Hencky stress value, equivalent plastic strain, temperature increase, and stress triaxiality were analyzed.
Split Aptamers Immobilized on Polymer Brushes Integrated in a Lab-on-Chip System Based on an Array of Amorphous Silicon Photosensors: A Novel Sensor Assay
Authors: Nandimandalam Manasa , Costantini Francesca , Lovecchio Nicola , Iannascoli Lorenzo , Nascetti Augusto , de Cesare Giampiero , Caputo Domenico , Manetti Cesare
Published: December 2021

Innovative materials for the integration of aptamers in Lab-on-Chip systems are important for the development of miniaturized portable devices in the field of health-care and diagnostics. Herein we highlight a general method to tailor an aptamer sequence in two subunits that are randomly immobilized into a layer of polymer brushes grown on the internal surface of microfluidic channels, optically aligned with an array of amorphous silicon photosensors for the detection of fluorescence. Our approach relies on the use of split aptamer sequences maintaining their binding affinity to the target molecule. After binding the target molecule, the fragments, separately immobilized to the brush layer, form an assembled structure that in presence of a “light switching” complex [Ru(phen)2(dppz)]2+, emit a fluorescent signal detected by the photosensors positioned underneath. The fluorescent intensity is proportional to the concentration of the target molecule. As proof of principle, we selected fragments derived from an aptamer sequence with binding affinity towards ATP. Using this assay, a limit of detection down to 0.9 µM ATP has been achieved. The sensitivity is compared with an assay where the original aptamer sequence is used. The possibility to re-use both the aptamer assays for several times is demonstrated.
Effect of Electric Pulse Treatment on Hot-Dip Aluminizing Coating of Ductile Iron
Authors: Dong Jie , Yuan Shouqian , Sun Yongtao , Yang Shuangping , Xing Xiangdong , He Xiaomei
Published: December 2021

In this paper, hot-dip aluminizing of ferrite nodular cast iron was carried out after treating liquid aluminum with different electrical pulse parameters. Compared with that of conventional hot-dip aluminizing, the coating structure of the treated sample did not change, the surface was smooth and continuous, and the solidification structure was more uniform. When high voltage and large capacitance were used to treat the liquid aluminum, the thickness and compactness of the coating surface layer increased. The thickness of the alloy layer decreased, and, the compactness and the micro hardness increased, so the electric pulse had a certain inhibition on the formation of the alloy layer. The growth kinetics of the alloy layer showed that the rate-time index decreased from 0.60 for the conventional sample to 0.38 for the electric pulse treated sample. The growth of the alloy layer was controlled by diffusion and interface reaction, but only by diffusion. The AC impedance and polarization curves of the coating showed that the corrosion resistance of hot-dip coating on nodular cast iron was improved by electric pulse treatment.
Anelastic Behaviour of Commercial Die-Cast Magnesium Alloys: Effect of Temperature and Alloy Composition
Authors: Ang Hua Qian
Published: December 2021

The anelastic deformation, resulting from partial reversal of {101¯2} twinning, is studied at room temperature to 150 °C on several commercial die-cast magnesium alloys for the first time. The magnitude of anelastic strain decreases with increasing temperature. For inter-alloy comparison, AZ91 shows the largest maximum anelastic strain, while AM40 and AM60 show similar maximum anelastic strain. The phenomenon is discussed in terms of solid solution softening and hardening of slip planes and how they influence twinning. T5-aged AE44 consistently shows smaller magnitude of anelasticity compared to as-cast AE44, suggesting that the precipitates formed during ageing may decrease the twin-boundary mobility and further suppress untwinning. Presence of anelasticity poses a challenge to yield strength measurement using the conventional 0.2% offset method, and a more accurate and consistent method of using a higher offset strain or a lower modulus is proposed in this study.
A Pilot Study of Seamless Regeneration of Bone and Cartilage in Knee Joint Regeneration Using Honeycomb TCP
Authors: Takabatake Kiyofumi , Tsujigiwa Hidetsugu , Yoshida Aki , Furumatsu Takayuki , Kawai Hotaka , Oo May Wathone , Nakano Keisuke , Nagatsuka Hitoshi
Published: December 2021

The knee joint is a continuous structure of bone and cartilage tissue, making it difficult to regenerate using artificial biomaterials. In a previous study, we succeeded in developing honeycomb tricalcium phosphate (TCP), which has through-and-through holes and is able to provide the optimum microenvironment for hard tissue regeneration. We demonstrated that TCP with 300 μm pore diameters (300TCP) induced vigorous bone formation, and that TCP with 75 μm pore diameters (75TCP) induced cartilage formation. In the present study, we regenerated a knee joint defect using honeycomb TCP. 75TCP and 300TCP were loaded with transforming growth factor (TGF)-β alone or bone morphogenic protein (BMP)-2+TGF-β with or without Matrigel and transplanted into knee joint defect model rabbits. 75TCP showed no bone or cartilage tissue formation in any of the groups with TGF-β alone and BMP-2+TGF-β with/without Matrigel. However, for 300TCP and BMP-2+TGF-β with or without Matrigel, vigorous bone tissue formation was observed in the TCP holes, and cartilage tissue formation in the TCP surface layer was continuous with the existing cartilage. The cartilage area in the TCP surface was larger in the group without Matrigel (with BMP-2+TGF-β) than in the group with Matrigel (with BMP-2+TGF-β). Therefore, honeycomb TCP can induce the seamless regeneration of bone and cartilage in a knee joint.
Towards Efficient Acidic Catalysts via Optimization of SO3H-Organosilane Immobilization on SBA-15 under Increased Pressure: Potential Applications in Gas and Liquid Phase Reactions
Authors: Trejda Maciej , Kaszuba Ada , Nurwita Ardian , Ziolek Maria
Published: December 2021

In this paper, the optimization of the synthesis of catalysts based on acidic mesoporous silica of the SBA-15 type by post-synthesis immobilization of 3-(trihydroxysilyl)-1-propanesulfonic acid (TPS) under increased pressure up to 20 bar is reported. Sample structures and composition were examined by XRD measurement, low-temperature N2 adsorption/desorption and elemental analysis. The catalytic activities of the materials obtained were determined in both gas and liquid phase processes, i.e., by esterification of acetic acid and glycerol dehydration, respectively. The optimum pressure for modification leading to the highest number of acidic sites was found to be 10 bar. The final material was very active and stable in liquid phase processes; however, the stability in the gas-phase process was unsatisfactory due to the loss of sulphonic species from the catalyst surface.
Study on Durability and Pore Characteristics of Concrete under Salt Freezing Environment
Authors: Zheng Xinchao , Liu Fang , Luo Tao , Duan Yanfu , Yi Yu , Hua Cheng
Published: December 2021

The macroscopic mechanical properties and frost resistance durability of concrete are closely related to the changes in the internal pore structure. In this study, the two-dimensional and three-dimensional ICT (Industrial Computerized Tomography) pore characteristics of C30 concrete specimens before and after freezing and thawing in clean water, 5 wt.% NaCl, 5 wt.% CaCl2, and 5 wt.% CH3COOK solution environments are obtained through concrete frost resistance durability test and ICT scanning technology. The effects of pore structure changes on concrete frost resistance, durability, and compressive strength mechanical properties after freezing and thawing cycles in different salt solution environments are analyzed. This paper provides new means and ideas for the study of concrete pores. The results show that with the increase in the freezing and thawing times, the concrete porosity, two-dimensional pore area, three-dimensional pore volume, and pore number generally increase in any solution environment, resulting in the loss of concrete compressive strength, mortar spalling, and the decrease in the relative dynamic elastic modulus. Among them, the CH3COOK solution has the least influence on the concrete pore changes; the NaCl solution has the greatest influence on the change in the concrete internal porosity. The damage of CaCl2 solution to concrete is second only to the NaCl solution, followed by clean water. The increase in the concrete internal porosity from high to low is NaCl, CaCl2, clean water, and CH3COOK. The change in the pore volume of 0.1 to 1 mm3 after the freeze–thaw cycle is the main factor for reducing concrete strength. The test results have certain guiding value for the selection of deicing salt in engineering.
Machine Learning Methods Applied for Modeling the Process of Obtaining Bricks Using Silicon-Based Materials
Authors: Anton Costel , Curteanu Silvia , Lisa Cătălin , Leon Florin
Published: December 2021

Most of the time, industrial brick manufacture facilities are designed and commissioned for a particular type of manufacture mix and a particular type of burning process. Productivity and product quality maintenance and improvement is a challenge for process engineers. Our paper aims at using machine learning methods to evaluate the impact of adding new auxiliary materials on the amount of exhaust emissions. Experimental determinations made in similar conditions enabled us to build a database containing information about 121 brick batches. Various models (artificial neural networks and regression algorithms) were designed to make predictions about exhaust emission changes when auxiliary materials are introduced into the manufacture mix. The best models were feed-forward neural networks with two hidden layers, having MSE < 0.01 and r2 > 0.82 and, as regression model, kNN with error < 0.6. Also, an optimization procedure, including the best models, was developed in order to determine the optimal values for the parameters that assure the minimum quantities for the gas emission. The Pareto front obtained in the multi-objective optimization conducted with grid search method allows the user the chose the most convenient values for the dry product mass, clay, ash and organic raw materials which minimize gas emissions with energy potential.
Experimental and Numerical Investigations of Cement Bonding Properties
Authors: Lambrescu Ionut , Teodoriu Catalin , Amani Mahmood
Published: December 2021

Well integrity is of high importance during the entire well life span especially when renewable energy resources such as geothermal are designed to cover the increasing world energy demand. Many studies have documented the importance of the casing–cement interfacial bonding to ensure critical well integrity achievements; however, laboratory experiments and field data are not always aligned. Furthermore, Finite Element Analysis shows relatively high discrepancies compared with the results of various scholarly published works. The limitations in the FEA are most probably generated by the casing–cement interaction modeling parameters. Typically, the contact between casing and cement is modeled using the so-called CZM method, which includes the shear debonding process into the FEA. Several setups have been used in the past to determine the interfacial casing–cement bonding shear strength. Some of these setups are briefly summarized herein. The novelty of this paper consists in the combination of a relatively simple experimental setup with the finite element modeling of the experiment itself to demonstrate that it is important to acquire accurate laboratory data for debonding simulations and, thus, to improve the well integrity prediction. The aim of this paper is to better understand the limitations of the finite element method when modeling shear bonding of the cement and, in the same, to verify that the proposed experimental setup can be modelled using numerical approaches. The successful numerical simulation can later be used for upscaled models. The results confirm the experimental push down setup and aid engineers to further understand and validate CZM models and optimize the well design to achieve maximum well integrity potential. Our results are within 1% error from the average field data.
Novel Diazocrowns with Pyrrole Residue as Lead(II)Colorimetric Probes
Authors: Galiński Błażej , Luboch Elżbieta , Chojnacki Jarosław , Wagner-Wysiecka Ewa
Published: December 2021

Novel 18- and 23-membered diazomacrocycles were obtained with satisfactory yields by diazocoupling of aromatic diamines with pyrrole in reactions carried under high dilution conditions. X-ray structure of macrocycle bearing five carbon atoms linkage was determined and described. Compounds were characterized as chromogenic heavy metal ions receptors. Selective color and spectral response for lead(II) was found in acetonitrile and its mixture with water. Complexation properties of newly obtained macrocycles with a hydrocarbon chain were compared with the properties of their oligoether analogs. The influence of the introduction of hydrocarbon residue as a part of macrocycle on the lead(II) binding was discussed. Selective and sensitive colorimetric probe for lead(II) in aqueous acetonitrile with detection limit 56.1 μg/L was proposed.
Electromagnetic Wave Absorption and Mechanical Properties of CNTs@GN@Fe3O4/PU Multilayer Composite Foam
Authors: Gao Chunfu , He Xinsheng , Ye Fengchao , Wang Shuxin , Zhang Guang
Published: December 2021

With the development of intelligent communications and stealth technology in the military field, electromagnetic wave pollution cannot be ignored, and absorbing materials have entered people’s field of vision and gradually become a research hotspot. The ideal absorbing material should have the characteristics of “strong, wide, thin, and light”, but a single absorbing material often cannot meet the above conditions. At present, absorbing metal powder combined with two-dimensional carbon nanomaterials (such as carbon nanotubes, graphene, etc.) has became a trend. This article focus on a three-layer composite of Fe3O4, Carbon nanotubes@ Fe3O4, Carbon nanotubes@Graphene nano-platelets@ Fe3O4, which was synthesized by solvothermal method. The results show that the electromagnetic wave absorption performance of the three-layer foam at a thickness of 3.0 mm is more excellent. The minimum of RL can reach −67.0 dB, and the effective bandwidth is above 5.0 GHz. All this is due to the synergy of dielectric and magnetic loss between Fe3O4, CNTs, and GN, the increase of interface polarization and the path of electromagnetic wave reflection and scattering by three-layer foam.
Ultrasmooth Organic Films Via Efficient Aggregation Suppression by a Low-Vacuum Physical Vapor Deposition
Authors: Yoon Youngkwan , Lee Jinho , Lee Seulgi , Kim Soyoung , Choi Hee Cheul
Published: December 2021

Organic thin films with smooth surfaces are mandated for high-performance organic electronic devices. Abrupt nucleation and aggregation during film formation are two main factors that forbid smooth surfaces. Here, we report a simple fast cooling (FC) adapted physical vapor deposition (FCPVD) method to produce ultrasmooth organic thin films through effectively suppressing the aggregation of adsorbed molecules. We have found that thermal energy control is essential for the spread of molecules on a substrate by diffusion and it prohibits the unwanted nucleation of adsorbed molecules. FCPVD is employed for cooling the horizontal tube-type organic vapor deposition setup to effectively remove thermal energy applied to adsorbed molecules on a substrate. The organic thin films prepared using the FCPVD method have remarkably ultrasmooth surfaces with less than 0.4 nm root mean square (RMS) roughness on various substrates, even in a low vacuum, which is highly comparable to the ones prepared using conventional high-vacuum deposition methods. Our results provide a deeper understanding of the role of thermal energy employed to substrates during organic film growth using the PVD process and pave the way for cost-effective and high-performance organic devices.
Investigation of Polyetherimide Melt-Extruded Fibers Modified by Carbon Nanoparticles
Authors: Ivan’kova Elena , Vaganov Gleb , Didenko Andrey , Popova Elena , Elokhovskiy Vladimir , Bugrov Alexander , Svetlichnyi Valentin , Kasatkin Igor , Yudin Vladimir
Published: December 2021

The fibers based on thermoplastic partially crystalline polyetherimide R-BAPB modified by vapor grown carbon nanofibers (VGCF) were prepared by melt extrusion, exposed to orientational drawing, and crystallized. All of the samples were examined by scanning electron microscopy, X-ray scattering, and differential scanning calorimetry to study how the carbon nanofiller influences on the internal structure and crystallization behavior of the obtained R-BAPB fibers. The mechanical properties of the composite R-BAPB fibers were also determined. It was found that VGCF nanoparticles introduced into R-BAPB polyimide can act as a nucleating agent that leads, in turn, to significant changes in the composite fibers morphology as well as thermal and mechanical characteristics. VGCF are able to improve an orientation degree of the R-BAPB macromolecules along the fiber direction, accelerate crystallization rate of the polymer, and enhance the fiber stability during crystallization process.
The Influence of Tool Wear on the Mechanical Performance of AA6061-T6 Refill Friction Stir Spot Welds
Authors: de Carvalho Willian S. , Vioreanu Maura C. , Lutz Maxime R. A. , Cipriano Gonçalo P. , Amancio-Filho Sergio T.
Published: December 2021

The Refill Friction Stir Spot Welding (RFSSW) process—an alternative solid-state joining technology—has gained momentum in the last decade for the welding of aluminum and magnesium alloys. Previous studies have addressed the influence of the RFSSW process on the microstructural and mechanical properties of the AA6061-T6 alloy. However, there is a lack of knowledge on how the tool wear influences the welding mechanical behavior for this alloy. The present work intended to evaluate and understand the influence of RFSSW tool wear on the mechanical performance of AA6061-T6 welds. Firstly, the welding parameters were optimized through the Designing of Experiments (DoE), to maximize the obtained ultimate lap shear force (ULSF) response. Following the statistical analysis, an optimized condition was found that reached a ULSF of 8.45 ± 0.08 kN. Secondly, the optimized set of welding parameters were applied to evaluate the wear undergone by the tool. The loss of worn-out material was systematically investigated by digital microscopy and the assessment of tool weight loss. Tool-wear-related microstructural and local mechanical property changes were assessed and compared with the yielded ULSF, and showed a correlation. Further investigations demonstrated the influence of tool wear on the height of the hook, which was located at the interface between the welded plates and, consequently, its effects on the observed fracture mechanisms and ULSF. These results support the understanding of tool wear mechanisms and helped to evaluate the tool lifespan for the selected commercial RFSSW tool which is used for aluminum alloys.
Fast 4D On-the-Fly Tomography for Observation of Advanced Pore Morphology (APM) Foam Elements Subjected to Compressive Loading
Authors: Vopalensky Michal , Koudelka Petr , Sleichrt Jan , Kumpova Ivana , Borovinsek Matej , Vesenjak Matej , Kytyr Daniel
Published: December 2021

Observation of dynamic testing by means of X-ray computed tomography (CT) and in-situ loading devices has proven its importance in material analysis already, yielding detailed 3D information on the internal structure of the object of interest and its changes during the experiment. However, the acquisition of the tomographic projections is, in general, a time-consuming task. The standard method for such experiments is the time-lapse CT, where the loading is suspended for the CT scan. On the other hand, modern X-ray tubes and detectors allow for shorter exposure times with an acceptable image quality. Consequently, the experiment can be designed in a way so that the mechanical test is running continuously, as well as the rotational platform, and the radiographic projections are taken one after another in a fast, free-running mode. Performing this so-called on-the-fly CT, the time for the experiment can be reduced substantially, compared to the time-lapse CT. In this paper, the advanced pore morphology (APM) foam elements were used as the test objects for in-situ X-ray microtomography experiments, during which series of CT scans were acquired, each with the duration of 12 s. The contrast-to-noise ratio and the full-width-half-maximum parameters are used for the quality assessment of the resultant 3D models. A comparison to the 3D models obtained by time-lapse CT is provided.
Combined Freeze-Thaw and Chloride Attack Resistance of Concrete Made with Recycled Brick-Concrete Aggregate
Authors: Yu Yao , Wang Jian , Wang Ninghui , Wu Chenjie , Zhang Xiaojing , Wang Dezhi , Ma Zhipeng
Published: December 2021

The objective of this study was to investigate the physico-chemical properties of concrete made with recycled brick-concrete aggregate, which was the mixture from waste concrete and waste clay brick in a 7:3 ratio. Specifically, this paper investigated the mechanical properties, freeze-thaw resistance, and distribution of water-soluble chloride ions of concrete containing RBCA and fly ash (FA) against combined freeze-thaw and sodium chloride attack. Concrete containing RBCA replacement of natural coarse aggregate and fly ash replacement of Portland cement was subjected to 45 freeze-thaw cycles containing sodium chloride solution. It was discovered that the mechanical properties and freeze-thaw resistance to sodium chloride attack gradually decreased with increasing RBCA content. At the same time, a replacement level of 15% FA by weight resulted in significant improvements in compressive strength and resistance to combined freeze-thaw and chloride attack. Furthermore, using a replacement of 30% FA by weight markedly improved the resistance to chloride ion penetration of concrete due to the lowest water-soluble chloride content.
Experimental and Numerical Analysis of Multiple Low-Velocity Impact Damages in a Glass Fibered Composite Structure
Authors: Balasubramaniam Kaleeswaran , Ziaja Dominika , Jurek Michał , Fiborek Piotr , Malinowski Paweł
Published: December 2021

Glass fiber-reinforced polymer structures (GFRPS) are widely used in civil and mechanical fields due to their light weight and corrosion resistance. However, these structures are prone to damage with very-low-energy impacts. The reliability of such structures is of prime importance before their installation and usage. This study aimed to identify, visualize, localize, and verify multiple barely visible impact damage (BVID) in a GFRPS using a combination of guided waves (GW)-based online structural health monitoring (SHM) and thermal strain-based nondestructive testing (NDT) approaches. Global NDT techniques like the use of a laser Doppler vibrometer (LDV) and digital image correlation (DIC) were used in the experimental analysis. The effectiveness of the experimental LDV-GW process was also checked numerically with the spectral element method (SEM). A threshold-based baseline free SHM approach to effectively localize the damages was proposed along with quick DIC verification of composite structure with thermal loading based on short-pulse heating as an excitation source. This study analyzed combined experimental- and numerical-based SHM-NDT methods in characterizing the multiple BVIDs located in a GFRPS.
Review of the Effects of Supplementary Cementitious Materials and Chemical Additives on the Physical, Mechanical and Durability Properties of Hydraulic Concrete
Authors: Raghav Muralidharan , Park Taejoon , Yang Hyun-Min , Lee Seung-Yeop , Karthick Subbiah , Lee Han-Seung
Published: December 2021

Supplementary cementitious materials (SCMs) and chemical additives (CA) are incorporated to modify the properties of concrete. In this paper, SCMs such as fly ash (FA), ground granulated blast furnace slag (GGBS), silica fume (SF), rice husk ash (RHA), sugarcane bagasse ash (SBA), and tire-derived fuel ash (TDFA) admixed concretes are reviewed. FA (25–30%), GGBS (50–55%), RHA (15–20%), and SBA (15%) are safely used to replace Portland cement. FA requires activation, while GGBS has undergone in situ activation, with other alkalis present in it. The reactive silica in RHA and SBA readily reacts with free Ca(OH)2 in cement matrix, which produces the secondary C-S-H gel and gives strength to the concrete. SF addition involves both physical contribution and chemical action in concrete. TDFA contains 25–30% SiO2 and 30–35% CaO, and is considered a suitable secondary pozzolanic material. In this review, special emphasis is given to the various chemical additives and their role in protecting rebar from corrosion. Specialized concrete for novel applications, namely self-curing, self-healing, superhydrophobic, electromagnetic (EM) wave shielding and self-temperature adjusting concretes, are also discussed.
Multimodal Gold Nanostars as SERS Tags for Optically-Driven Doxorubicin Release Study in Cancer Cells
Authors: Minati Luca , Maniglio Devid , Benetti Filippo , Chiappini Andrea , Speranza Giorgio
Published: December 2021

Surface Enhanced Raman Scattering (SERS) active gold nanostars represent an opportunity in the field of bioimaging and drug delivery. The combination of gold surface chemical versatility with the possibility to tune the optical properties changing the nanoparticles shape constitutes a multimodal approach for the investigation of the behavior of these carriers inside living cells. In this work, SERS active star-shaped nanoparticles were functionalized with doxorubicin molecules and covered with immuno-mimetic thiolated polyethylene glycol (PEG). Doxorubicin-conjugate gold nanoparticles show an intense Raman enhancement, a good stability in physiological conditions, and a low cytotoxicity. The strong adsorption of the anticancer drug doxorubicin in close contact with the gold nanostars surface enables their use as SERS tag imaging probes in vivo. Upon laser irradiation of the nanoparticles, a strong SERS signal is generated by the doxorubicin molecules close to the nanostars surface, enabling the localization of the nanoparticles inside the cells. After long time irradiation, the SERS signal drops, indicating the thermally driven delivery of the drug inside the cell. Therefore, the combination of SERS and laser scanning confocal microscopy is a powerful technique for the real-time analysis of drug release in living cells.
Through-Plane and In-Plane Thermal Diffusivity Determination of Graphene Nanoplatelets by Photothermal Beam Deflection Spectrometry
Authors: Cabrera Humberto , Korte Dorota , Budasheva Hanna , Abbasgholi N. Asbaghi Behnaz , Bellucci Stefano
Published: December 2021

In this work, in-plane and through-plane thermal diffusivities and conductivities of a freestanding sheet of graphene nanoplatelets are determined using photothermal beam deflection spectrometry. Two experimental methods were employed in order to observe the effect of load pressures on the thermal diffusivity and conductivity of the materials. The in-plane thermal diffusivity was determined by the use of a slope method supported by a new theoretical model, whereas the through-plane thermal diffusivity was determined by a frequency scan method in which the obtained data were processed with a specifically developed least-squares data processing algorithm. On the basis of the determined values, the in-plane and through-plane thermal conductivities and their dependences on the values of thermal diffusivity were found. The results show a significant difference in the character of thermal parameter dependence between the two methods. In the case of the in-plane configuration of the experimental setup, the thermal conductivity decreases with the increase in thermal diffusivity, whereas with the through-plane variant, the thermal conductivity increases with an increase in thermal diffusivity for the whole range of the loading pressure used. This behavior is due to the dependence of heat propagation on changes introduced in the graphene nano-platelets structure by compression.
Metal–Organic Frameworks (MOFs) for Cancer Therapy
Authors: Saeb Mohammad Reza , Rabiee Navid , Mozafari Masoud , Verpoort Francis , Voskressensky Leonid G. , Luque Rafael
Published: December 2021

MOFs exhibit inherent extraordinary features for diverse applications ranging from catalysis, storage, and optics to chemosensory and biomedical science and technology. Several procedures including solvothermal, hydrothermal, mechanochemical, electrochemical, and ultrasound techniques have been used to synthesize MOFs with tailored features. A continued attempt has also been directed towards functionalizing MOFs via “post-synthetic modification” mainly by changing linkers (by altering the type, length, functionality, and charge of the linkers) or node components within the MOF framework. Additionally, efforts are aimed towards manipulating the size and morphology of crystallite domains in the MOFs, which are aimed at enlarging their applications window. Today’s knowledge of artificial intelligence and machine learning has opened new pathways to elaborate multiple nanoporous complex MOFs and nano-MOFs (NMOFs) for advanced theranostic, clinical, imaging, and diagnostic purposes. Successful accumulation of a photosensitizer in cancerous cells was a significant step in cancer therapy. The application of MOFs as advanced materials and systems for cancer therapy is the main scope beyond this perspective. Some challenging aspects and promising features in MOF-based cancer diagnosis and cancer therapy have also been discussed.
Description of Limit States in the Subsurface Layer of Loosened Subsoil in View of Critical State Soil Mechanics
Authors: Fedorowicz Jan , Fedorowicz Lidia , Kadela Marta
Published: December 2021

The article aims to present an effective numerical method for the behaviour analysis and safety assessment of a subsurface layer of subsoil in the existing or predicted states of mining and post-mining deformations. Based on our own analytical record, using the equations of the Modified Cam-Clay model, the description of limit states in the subsurface layer of subsoil was validated, making it consistent with in situ observations. The said effect was demonstrated by comparing numerical analyses of the subsoil layer subjected to the limit state, using the Modified Cam-Clay (MCC) model and the Coulomb-Mohr model (C-M). The article also presents the applicability potential of the numerical analysis of the loosened subsoil layer for the assessment of protection elements (e.g., geo-matresses) used under linear structures in the areas subjected to mining and post-mining impacts.
An Extended Analytical Solution of the Non-Stationary Heat Conduction Problem in Multi-Track Thick-Walled Products during the Additive Manufacturing Process
Authors: Mukin Dmitrii , Valdaytseva Ekaterina , Turichin Gleb , Vildanov Artur
Published: December 2021

An analytical model has been developed for calculating three-dimensional transient temperature fields arising in the direct deposition process to study the thermal behavior of multi-track walls with various configurations. The model allows the calculation of all characteristics of the temperature fields (thermal cycles, cooling rates, temperature gradients) in the wall during the direct deposition process at any time. The solution of the non-stationary heat conduction equation for a moving heat source is used to determine the temperature field in the deposited wall, taking into account heat transfer to the environment. The method considers the size of the wall and the substrate, the change in power from layer to layer, the change in the cladding speed, the interpass dwell time (pause time), and the heat source trajectory. Experiments on the deposition of multi-track block samples are carried out, as a result of which the values of the temperatures are obtained at fixed points. The proposed model makes it possible to reproduce temperature fields at various values of the technological process parameters. It is confirmed by comparisons with experimental thermocouple data. The relative difference in the interlayer temperature does not exceed 15%.
Influence of the Microstructure and Optical Constants on Plasmonic Properties of Copper Nanolayers
Authors: Rerek Tomasz , Derkowska-Zielinska Beata , Trzcinski Marek , Szczesny Robert , Naparty Mieczyslaw K. , Skowronski Lukasz
Published: December 2021

Copper layers with thicknesses of 12, 25, and 35 nm were thermally evaporated on silicon substrates (Si(100)) with two different deposition rates 0.5 and 5.0 Å/s. The microstructure of produced coatings was studied using atomic force microscopy (AFM) and powder X-ray diffractometer (XRD). Ellipsometric measurements were used to determine the effective dielectric functions <ε˜> as well as the quality indicators of the localized surface plasmon (LSP) and the surface plasmon polariton (SPP). The composition and purity of the produced films were analysed using X-ray photoelectron spectroscopy (XPS).
Mechanical Properties of Polymer-Based Blanks for Machined Dental Restorations
Authors: Ciocan Lucian Toma , Ghitman Jana , Vasilescu Vlad Gabriel , Iovu Horia
Published: December 2021

The tremendous technological and dental material progress led to a progressive advancement of treatment technologies and materials in restorative dentistry and prosthodontics. In this approach, CAD/CAM restorations have proven to be valuable restorative dental materials in both provisional and definitive restoration, owing to multifarious design, improved and highly tunable mechanical, physical and morphological properties. Thus far, the dentistry market offers a wide range of CAD/CAM restorative dental materials with highly sophisticated design and proper characteristics for a particular clinical problem or multiple dentistry purposes. The main goal of this research study was to comparatively investigate the micro-mechanical properties of various CAD/CAM restorations, which are presented on the market and used in clinical dentistry. Among the investigated dental specimens, hybrid ceramic-based CAD/CAM presented the highest micro-mechanical properties, followed by CAD/CAM PMMA-graphene, while the lowest micro-mechanical features were registered for CAD/CAM multilayered PMMA.
A Statistical Model of Fibre Distribution in a Steel Fibre Reinforced Concrete
Authors: Kobaka Janusz
Published: December 2021

The aim of the research was to create a model of steel fibre distribution in a Steel Fibre Reinforced Concrete space using statistical probability means. The model was created in order to better understand the behaviour of the composite under operating conditions. Four statistical distributions (Beta, Kumaraswamy, Three Parameter Beta and Generalised Transmuted Kumaraswamy) were examined to find the distribution that best described fibre settling phenomenon caused by manufacturing process conditions. In the next stage the chosen statistical distribution was adapted to create the model of steel fibre distribution in a Steel Fibre Reinforced Concrete space. The model took into account technological conditions such as vibrating time and properties such as consistency of the tested concrete. The model showed a good agreement with the real fibre distribution.
Non-Linear Probabilistic Modification of Miner’s Rule for Damage Accumulation
Authors: Blacha Łukasz
Published: December 2021

A non-linear modification to Miner’s rule for damage accumulation is proposed to reduce the scatter between experimental fatigue life and fatigue life predicted according to the original Miner’s sum. Based on P-s-n probability distribution and design s-n curves, the modification satisfies the assumption of equality between the mean damage degree (at the critical level) and fatigue life random variables, which is not covered in the original formulation. The adopted formulation shows the discrepancies between the fatigue lives predicted according to the design s-n curves and the estimated probability distribution. It also proves that it is inappropriate to apply a normal distribution to fatigue life analysis and that the model becomes non-linear only for non-normal distributions. The predictions according to the established model were compared to the predictions obtained with Miner’s rule.
On the Dynamics of Transient Plasmas Generated by Nanosecond Laser Ablation of Several Metals
Authors: Irimiciuc Stefan Andrei , Chertopalov Sergii , Novotný Michal , Craciun Valentin , Lancok Jan
Published: December 2021

The dynamics of transient plasma generated by UV ns-laser ablation of selected metals (Co, Cu, Ag, Bi) were investigated by the Langmuir Probe method in angle- and time-resolved modes. Multiple ionic and electronic structures were seen for all plasmas with some corresponding to anions or nanoparticle-dominated structures. The addition of an Ar atmosphere energetically confined the plasma and increased the charge density by several orders of magnitude. For pressure ranges exceeding 0.5 Pa fast ions were generated in the plasma as a result of Ar ionization and acceleration in the double layer defining the front of the plasma plume. Several correlations between the target nature plasma properties were attempted. The individual plasma structure expansion velocity increases with the melting point and decreases with the atomic mass while the corresponding charged particle densities decrease with the melting point, evidencing the relationship between the volatility of the sample and the overall abated mass.
Influence of Changes in the Shape of the Anode Channel in Polymer Electrolyte Fuel Cell on the Loss of Its Service Life
Authors: Sławiński Daniel , Soszko Michał , Tokarz Wojciech , Bykuć Sebastian
Published: December 2021

The fuel cell operation is associated with significant current density and durability problems, among other anode collectors. We used a numerical model based on flows with chemical reactions in a porous medium to solve these problems. We tested four variants of the anode channels. In the shape of the anode channel, we introduced changes to improve the current density. We also examined the influence of the channel shape on the stress field and rheological processes in the casing material. We verified the numerical model on the experimental data. Furthermore, we corrected the amount of the hydrogen stream and the produced water in the whole range of the cell’s operation. The test results show that it is possible to increase the current density in all operating fields of the fuel cell while maintaining a low mechanical load on graphite elements and their safe operation time.
Synthesis and Characterization of TiO2 Nanotubes (TiO2-NTs) Decorated with Platine Nanoparticles (Pt-NPs): Photocatalytic Performance for Simultaneous Removal of Microorganisms and Volatile Organic Compounds
Authors: Khezami Lotfi , Lounissi Imen , Hajjaji Anouar , Guesmi Ahlem , Assadi Aymen Amine , Bessais Brahim
Published: December 2021

This work reports on the effect of TiO2 nanotubes (TiO2-NTs), decorated wih platinum nanoparticles (Pt-NPs), on the removal of bacteria and volatile organic compounds (VOCs). The Pt-NPs were loaded onto the TiO2-NTs using the electrodeposition method at four decoration times (100, 200, 300, and 600 s). The realized Pt-NPs/TiO2-NTs nanocomposites were used for the degradation of cyclohexane, a highly toxic and carcinogenic VOC pollutant in the chemical industry. The achieved Pt-NPs/TiO2-NTs nanocomposites were characterized using X-ray diffraction (XRD), photoluminescence (PL), diffuse reflectance spectroscopy (UV–Vis), and scanning (SEM) and transmission (TEM) electron microscopy. To understand the photocatalytic and antibacterial behavior of the Pt-NPs/TiO2-NTs, simultaneous treatment of Escherichia coli and cyclohexane was conducted while varying the catalyst time decoration. We noticed a complete bacterial inactivation rate with 90% VOC removal within 60 min of visible light irradiation. Moreover, the Langmuir–Hinshelwood model correlated well with the experimental results of the photocatalytic treatment of indoor air.
The Role of Sintering Temperature and Dual Metal Substitutions (Al3+, Ti4+) in the Development of NASICON-Structured Electrolyte
Authors: Rusdi Hashlina , Rusdi Roshidah , Aziz Shujahadeen B. , Alsubaie Abdullah Saad , Mahmoud Khaled H. , Kadir Mohd F. Z.
Published: December 2021

The aim of this study is to synthesize Li1+xAlxTixSn2−2x(PO4) sodium super ion conductor (NASICON) -based ceramic solid electrolyte and to study the effect of dual metal substitution on the electrical and structural properties of the electrolyte. The performance of the electrolyte is analyzed based on the sintering temperature (550 to 950 °C) as well as the composition. The trend of XRD results reveals the presence of impurities in the sample, and from Rietveld Refinement, the purest sample is achieved at a sintering temperature of 950 °C and when x = 0.6. The electrolytes obey Vegard′s Law as the addition of Al3+ and Ti4+ provide linear relation with cell volume, which signifies a random distribution. The different composition has a different optimum sintering temperature at which the highest conductivity is achieved when the sample is sintered at 650 °C and x = 0.4. Field emission scanning electron microscope (FESEM) analysis showed that higher sintering temperature promotes the increment of grain boundaries and size. Based on energy dispersive X-ray spectroscopy (EDX) analysis, x = 0.4 produced the closest atomic percentage ratio to the theoretical value. Electrode polarization is found to be at maximum when x = 0.4, which is determined from dielectric analysis. The electrolytes follow non-Debye behavior as it shows a variety of relaxation times.
Investigation of Micromechanical Properties and Tribological Behavior of WE43 Magnesium Alloy after Deep Cryogenic Treatment Combined with Precipitation Hardening
Authors: Barylski Adrian , Aniołek Krzysztof , Dercz Grzegorz , Kowalewski Piotr , Kaptacz Sławomir , Rak Jan , Kupka Marian
Published: December 2021

This study investigated the micromechanical and tribological properties of WE43 alloy (Mg-Y-Nd-Zr) alloy subjected to cryogenic treatment and precipitation hardening. Microindentation tests were carried out in the range of load from 100 to 1000 mN. The introduction of deep cryogenic treatment (DCT) was shown to increase hardness and Young’s modulus, and reduce the total indentation work. As the load set during the tests increased, a gradual decrease in the measured values was observed, indicating a significant relationship between the indent size and the value of the measured parameters. Cryogenic treatment used in conjunction with precipitation hardening (after solutioning and after aging) reduces the tribological wear of the alloy. Tests have shown an almost twofold reduction in the area of the wear trace and in the volumetric wear of the alloy, as well as a more than twofold reduction in linear wear, with relatively small fluctuations in the coefficient of friction. Abrasion was the main mechanism of wear. Areas where microcutting, adhesion and plastic deformation occurred were also observed. The results indicate the significant effectiveness of the applied heat treatment in improving the service life of the WE43 alloy containing rare earth metals.