bluuebunny/crossref_metadata_2025 huggingface dataset:
Native Trees as a Provider of Vital Urban Ecosystem Services in Urbanizing New Zealand: Status Quo, Challenges and Prospects
Authors: Jang Jihwi , Woo Su-Young
Published: January 2022

In New Zealand, over 87% of the population currently resides in cities. Urban trees can face a myriad of complex challenges including loss of green space, public health issues, and harm to the existence of urban dwellers and trees, along with domestic greenhouse gas (GHG) and air pollutant emissions. Despite New Zealand being a biodiversity hotspot in terms of natural environments, there is a lack of knowledge about native tree species’ regulating service (i.e., tree development and eco-physiological responses to low air quality, GHG, rising air temperatures, and drought) and how they grow in built-up environments such as cities. Therefore, we argue for the value of these native species in terms of ecosystem services and insist that they need to be viewed in relation to how they will respond to urban abiotic extremes and climate change. We propose to diversify planted forests for several reasons: (1) to improve awareness of the benefits of diverse planted urban forests; (2) to foster native tree research in urban environments, finding new keystone species; and (3) to improve the evidence of urban ecosystem resilience based on New Zealand native trees’ regulating services. This article aims to re-evaluate our understanding of whether New Zealand’s native trees can deal with environmental stress conditions similarly to more commonly planted alien species.
Degemination in Emirati Pidgin Arabic: A Sociolinguistic Perspective
Authors: Altakhaineh Abdel Rahman Mitib , Al-Namer Abdul-Salam , Alnamer Sulafah
Published: January 2022

This study examines the production of geminates in Emirati Pidgin Arabic (EPA) spoken by blue-collar workers in the United Arab Emirates. A simple naming test was designed to test the production of geminates to determine whether the EPA speakers would produce a geminated or degeminated phoneme. Following that, a semi-structured interview was conducted with a subset of the study cohort to obtain the participants’ own explanation of where they degeminated the consonants. Our findings suggest that the exercising of this choice functions as a sociolinguistic strategy, akin to the one observed by Labov in his study of Martha’s Vineyard. In particular, our findings show that speakers of EPA are inclined to degeminate consonantal geminates to establish themselves as members of a particular social group. The reasons for wanting to achieve this aim were given as follows: to claim privileges only available to members of this group (such as employment); and to distinguish themselves from the dominant cultural group. The study concludes that degemination in EPA has developed into a sociolinguistic solidarity marker.
Bias against Vitamin C in Mainstream Medicine: Examples from Trials of Vitamin C for Infections
Authors: Hemilä Harri , Chalker Elizabeth
Published: January 2022

Evidence has shown unambiguously that, in certain contexts, vitamin C is effective against the common cold. However, in mainstream medicine, the views on vitamin C and infections have been determined by eminence-based medicine rather than evidence-based medicine. The rejection of the demonstrated benefits of vitamin C is largely explained by three papers published in 1975—two published in JAMA and one in the American Journal of Medicine—all of which have been standard citations in textbooks of medicine and nutrition and in nutritional recommendations. Two of the papers were authored by Thomas Chalmers, an influential expert in clinical trials, and the third was authored by Paul Meier, a famous medical statistician. In this paper, we summarize several flaws in the three papers. In addition, we describe problems with two recent randomized trial reports published in JAMA which were presented in a way that misled readers. We also discuss shortcomings in three recent JAMA editorials on vitamin C. While most of our examples are from JAMA, it is not the only journal with apparent bias against vitamin C, but it illustrates the general views in mainstream medicine. We also consider potential explanations for the widespread bias against vitamin C.
Evaluation of Three Automated Extraction Systems for the Detection of SARS-CoV-2 from Clinical Respiratory Specimens
Authors: Lim Ho-Jae , Jung Hye-Soo , Park Min-Young , Baek Young-Hyun , Kannappan Balaji , Park Jin-Young , Yang Jae-Hyun , Seol Ja-Hwan , Lee Min-Woo , Jung Sun-Kyung , Lee Sun-Hwa , Park Jung-Eun , Yang Yong-Jin
Published: January 2022

Severe acute respiratory syndrome coronavirus (SARS-CoV-2) is highly contagious and causes coronavirus disease 2019 (COVID-19). Reverse transcription quantitative polymerase chain reaction (RT-qPCR) is the most accurate and reliable molecular assay to detect active SARS-CoV-2 infection. However, a rapid increase in test subjects has created a global bottleneck in testing capacity. Given that efficient nucleic acid extraction greatly affects reliable and accurate testing results, we compared three extraction platforms: MagNA Pure 96 DNA and Viral NA Small Volume kit on MagNA Pure 96 (Roche, Basel, Switzerland), careGENETM Viral/Pathogen HiFi Nucleic Acid Isolation kit (WELLS BIO Inc., Seoul, Korea) on KingFisher Flex (Thermo Fisher Scientific, Rocklin, CA, USA), and SGRespiTM Pure kit (Seegene Inc., Seoul, Korea) on Maelstrom 9600 (Taiwan Advanced Nanotech Inc., Taoyuan, Taiwan). RNA was extracted from 245 residual respiratory specimens from the different types of samples (i.e., NPS, sputum, and saliva) using three different kits. The 95% limits of detection of median tissue culture infectious dose per milliliter (TCID50/mL) for the MagNA Pure 96, KingFisher Flex, and Maelstrom 9600 were 0.37–3.15 × 101, 0.41–3.62 × 101, and 0.33–1.98 × 101, respectively. The KingFisher Flex platform exhibited 99.2% sensitivity and 100% specificity, whereas Maelstrom 9600 exhibited 98.3–100% sensitivity and 100% specificity. Bland–Altman analysis revealed a 95.2% concordance between MagNA Pure 96 and KingFisher Flex and 95.4% concordance between MagNA Pure 96 and Maelstrom 9600, indicating that all three platforms provided statistically reliable results. This suggests that two modifying platforms, KingFisher Flex and Maelstrom 9600, are accurate and scalable extraction platforms for large-scale SARS-CoV-2 clinical detection and could help the management of COVID-19 patients.
Does Surgical Repair Benefit Pipkin Type I Femoral Head Fractures?: A Systematic Review and Meta-Analysis
Authors: Tsai Sung Huang Laurent , Tai Wei-Che , Fu Tsai-Sheng , Tischler Eric H. , Rahman Rafa , Lim Yong-Kuan , Yu Yi-Hsun , Su Chun-Yi
Published: January 2022

Background: Femoral head fractures are rare injuries with or without traumatic dislocations. The management of these fractures is crucial to prevent the development of severe complications and to achieve optimal functional outcomes. Wide treatment options for Pipkin 1 femoral head fractures range from fragment excision, fixation following open reduction with internal fixation, or conservative treatment such as close reduction alone after fracture dislocation. However, the best decision making remains controversial not only due to lack of large trials, but also inconsistent results reported. Therefore, we aim to compare the operative with nonoperative outcomes of Pipkin type 1 patients. Patients and Methods: We systemically searched MEDLINE, EMBASE, Cochrane library, In-Process & Other Non-Indexed Citations to identify studies assessing outcomes of Pipkin type 1 patients after conservative treatment, and open reduction with excision or fixation. Data on comparison of clinical outcomes of each management were extracted including arthritis, heterotopic ossification (HO), avascular necrosis (AVN), and functional scores (Thompson Epstein, Merle’ d Augine and Postel Score). We performed a meta-analysis with the available data. Results: Eight studies (7 case series and 1 RCT) were included in this study. In a pooled analysis, the overall rate of arthritis was 37% (95% CI, 2–79%), HO was 20% (95% CI, 2–45%), and AVN was 3% (95% CI, 0–16%). In comparison of management types, the excision group reached the best functional outcomes including Thompson Epstein Score (poor to worse, 9%; 95% CI, 0–27%) and Merle d’ Aubigne and Postel Score (poor to worse, 18%; 95% CI, 3–38%); ORIF group had the highest AVN rate (11%; 95% CI, 0–92%); conservative treatment had the highest arthritis rate (67%; 95% CI: 0–100%) and lowest HO rate (2%; 95% CI, 0–28%). Discussion: This meta-analysis demonstrates that different procedures lead to various clinical outcomes: fragment excision may achieve better function, conservative treatment may result in a higher arthritis rate, while ORIFs may have a higher AVN rate. These findings may assist surgeons in tailoring their decision-making to specific patient profiles. Future RCTs with multicenter efforts are needed to validate associations found in this study. Level of Evidence: II, systematic review and meta-analysis.
Surveillance of Pathogenicity of Rhizoctonia solani Japanese Isolates with Varied Anastomosis Groups and Subgroups on Arabidopsis thaliana
Authors: Abdelghany Mai Mohsen Ahmed , Kurikawa Maria , Watanabe Megumi , Matsui Hidenori , Yamamoto Mikihiro , Ichinose Yuki , Toyoda Kazuhiro , Kouzai Yusuke , Noutoshi Yoshiteru
Published: January 2022

Rhizoctonia solani is a necrotrophic plant pathogen with a wide host range. R. solani is a species complex consisting of thirteen anastomosis groups (AGs) defined by compatibility of hyphal fusion reaction and subgroups based on cultural morphology. The relationship between such classifications and host specificity remains elusive. Here, we investigated the pathogenicity of seventeen R. solani isolates (AG-1 to 7) in Japan towards Arabidopsis thaliana using leaf and soil inoculations. The tested AGs, except AG-3 and AG-6, induced symptoms in both methods with variations in pathogenicity. The virulence levels differed even within the same AG and subgroup. Some isolates showed tissue-specific infection behavior. Thus, the AGs and their subgroups are suggested to be not enough to define the virulence (host and tissue specificity) of R. solani. We also evaluated the virulence of the isolates on Arabidopsis plants pretreated with salicylic acid, jasmonic acid, and ethylene. No obvious effects were detected on the symptom formation by the virulence isolates, but ethylene and salicylic acid slightly enhanced the susceptibility to the weak and nonvirulent isolates. R. solani seems to be able to overcome the induced defense by these phytohormones in the infection to Arabidopsis.
A Predictive Maintenance System for Reverse Supply Chain Operations
Authors: Gayialis Sotiris P. , Kechagias Evripidis P. , Konstantakopoulos Grigorios D. , Papadopoulos Georgios A.
Published: January 2022

Background: Reverse supply chains of machinery and equipment face significant challenges, and overcoming them is critical for effective customer service and sustainable operation. Maintenance and repair services, strongly associated with the reverse movement of equipment, are among the most demanding reverse supply chain operations. Equipment is scattered in various locations, and multiple suppliers are involved in its maintenance, making it challenging to manage the related reverse supply chain operations. Effective maintenance is essential for businesses-owners of the equipment, as reducing costs while improving service quality helps them gain a competitive advantage. Methods: To enhance reverse supply chain operations related to equipment maintenance, this paper presents the operational framework, the methodological approach, and the architecture for developing a system that covers the needs for predictive maintenance in the service supply chain. It is based on Industry 4.0 technologies, such as the Internet of things, machine learning, and cloud computing. Results: As a result of the successful implementation of the system, effective equipment maintenance and service supply chain management is achieved supporting the reverse supply chain. Conclusions: This will eventually lead to fewer good-conditioned spare part replacements, just in time replacements, extended equipment life cycles, and fewer unnecessary disposals.
Fabrication, Structure, Performance, and Application of Graphene-Based Composite Aerogel
Authors: Wei Dequan , Liu Xiang , Lv Shenghua , Liu Leipeng , Wu Lei , Li Zexiong , Hou Yonggang
Published: January 2022

Graphene-based composite aerogel (GCA) refers to a solid porous substance formed by graphene or its derivatives, graphene oxide (GO) and reduced graphene oxide (rGO), with inorganic materials and polymers. Because GCA has super-high adsorption, separation, electrical properties, and sensitivity, it has great potential for application in super-strong adsorption and separation materials, long-life fast-charging batteries, and flexible sensing materials. GCA has become a research hotspot, and many research papers and achievements have emerged in recent years. Therefore, the fabrication, structure, performance, and application prospects of GCA are summarized and discussed in this review. Meanwhile, the existing problems and development trends of GCA are also introduced so that more will know about it and be interested in researching it.
Effect of Oxalic Acid Treatment on Conductive Coatings Formed by Ni@Ag Core–Shell Nanoparticles
Authors: Pajor-Świerzy Anna , Pawłowski Radosław , Sobik Piotr , Kamyshny Alexander , Szczepanowicz Krzysztof
Published: January 2022

Low-cost metallic nanoink based on nickel–silver core–shell nanoparticles (Ni@Ag NPs) was used for the formation of conductive metallic coatings with low sintering temperature, which can be successfully applied for replacement of currently used silver-based nanoinks in printed electronics. The effect of oxalic acid (OA) on the sintering temperature and conductivity of coatings formed by Ni@Ag NPs was evaluated. It was found that the addition of OA to the ink formulation and post-printing treatment of deposited films with this acid provided a noticeable decrease in the sintering temperature required for obtaining conductive patterns that is especially important for utilizing the polymeric substrates. The obtained resistivity of metallic coatings after sintering at temperature as low as 100 °C was found to be 30 µΩ·cm, only ~4 times higher compared to the resistivity of bulk Ni that is promising for future application of such materials for fabrication of low-cost flexible printed patterns.
Characterizing the Chemical Structure of Ti3C2Tx MXene by Angle-Resolved XPS Combined with Argon Ion Etching
Authors: Lu Yangfan , Li Dongsheng , Liu Fu
Published: January 2022

Angle-resolved XPS combined with argon ion etching was used to characterize the surface functional groups and the chemical structure of Ti3C2Tx MXene. Survey scanning obtained on the sample surface showed that the sample mainly contains C, O, Ti and F elements, and a little Al element. Analyzing the angle-resolved narrow scanning of these elements indicated that a layer of C and O atoms was adsorbed on the top surface of the sample, and there were many O or F related Ti bonds except Ti–C bond. XPS results obtained after argon ion etching indicated staggered distribution between C–Ti–C bond and O–Ti–C, F–Ti bond. It is confirmed that Ti atoms and C atoms were at the center layer of Ti3C2Tx MXene, while O atoms and F atoms were located at both the upper and lower surface of Ti3C2 layer acting as surface functional groups. The surface functional groups on the Ti3C2 layer were determined to include O2−, OH−, F− and O−–F−, among which F atoms could also desorb from Ti3C2Tx MXene easily. The schematic atomic structure of Ti3C2Tx MXene was derived from the analysis of XPS results, being consistent with theoretical chemical structure and other experimental reports. The results showed that angle-resolved XPS combing with argon ion etching is a good way to analysis 2D thin layer materials.
Electrorheological Fluids of GO/Graphene-Based Nanoplates
Authors: Wang Yudong , Yuan Jinhua , Zhao Xiaopeng , Yin Jianbo
Published: January 2022

Due to their unique anisotropic morphology and properties, graphene-based materials have received extensive attention in the field of smart materials. Recent studies show that graphene-based materials have potential application as a dispersed phase to develop high-performance electrorheological (ER) fluids, a kind of smart suspension whose viscosity and viscoelastic properties can be adjusted by external electric fields. However, pure graphene is not suitable for use as the dispersed phase of ER fluids due to the electric short circuit caused by its high electrical conductivity under electric fields. However, graphene oxide (GO) and graphene-based composites are suitable for use as the dispersed phase of ER fluids and show significantly enhanced property. In this review, we look critically at the latest developments of ER fluids based on GO and graphene-based composites, including their preparation, electrically tunable ER property, and dispersed stability. The mechanism behind enhanced ER property is discussed according to dielectric spectrum analysis. Finally, we also propose the remaining challenges and possible developments for the future outlook in this field.
Microwave Heating as an Innovative Road Maintenance Technology: Aging Effect on Binder and Feasibility Evaluation
Authors: Sha Aimin , Lou Baowen , Barbieri Diego Maria , Hoff Inge
Published: January 2022

The microwave heating/healing technique is regarded as a green maintenance approach for asphalt pavements thanks to its promising environmental and economic benefits. However, the main concern about this technology is represented by the possible aging effect generated on bituminous binders. Currently, there is a significant lack of studies dealing with this topic. Based on these premises, the main purpose of this study is to appraise the feasibility of implementing microwave-based maintenance operations considering the associated aging effect. The assessment of fatigue life after cyclic microwave heating (MH) based on a linear amplitude sweep (LAS) test and the changes in the chemical groups detected through Fourier transform infrared (FTIR) spectroscopy document the aging phenomenon. The results indicate that the microwave aging degree on bituminous binder is nonlinear with MH cycles. The microwave radiation causes a distinct aging impact on binders during the first 10 cycles, then the values become constant. Furthermore, a feasibility analysis of MH technology is developed, encompassing four main multidisciplinary aspects: evaluation of microwave aging degree, working mechanism of MH equipment, safety assessment, and economic and ecological considerations. Despite the associated aging issue, the MH method is an efficient technology, considering its various advantages (i.e., rapidity of execution, uniform and non-pollutant treatment, and deep penetration). Meanwhile, the use of steel slag as a microwave absorber bolsters the sustainability of MH technology. This study provides a new perspective to evaluate the microwave heating technique in road engineering comprising the generated aging effect. Practice-oriented recommendations are also formulated regarding the safe implementation of MH technical operations.
Defect Passivation and Carrier Reduction Mechanisms in Hydrogen-Doped In-Ga-Zn-O (IGZO:H) Films upon Low-Temperature Annealing for Flexible Device Applications
Authors: Velichko Rostislav , Magari Yusaku , Furuta Mamoru
Published: January 2022

Low-temperature activation of oxide semiconductor materials such as In-Ga-Zn-O (IGZO) is a key approach for their utilization in flexible devices. We previously reported that the activation temperature can be reduced to 150 °C by hydrogen-doped IGZO (IGZO:H), demonstrating a strong potential of this approach. In this paper, we investigated the mechanism for reducing the activation temperature of the IGZO:H films. In situ Hall measurements revealed that oxygen diffusion from annealing ambient into the conventional Ar/O2-sputtered IGZO film was observed at >240 °C. Moreover, the temperature at which the oxygen diffusion starts into the film significantly decreased to 100 °C for the IGZO:H film deposited at hydrogen gas flow ratio (R[H2]) of 8%. Hard X-ray photoelectron spectroscopy indicated that the near Fermi level (EF) defects in the IGZO:H film after the 150 °C annealing decreased in comparison to that in the conventional IGZO film after 300 °C annealing. The oxygen diffusion into the film during annealing plays an important role for reducing oxygen vacancies and subgap states especially for near EF. X-ray reflectometry analysis revealed that the film density of the IGZO:H decreased with an increase in R[H2] which would be the possible cause for facilitating the O diffusion at low temperature.
On the Recycling of Water Atomized Powder and the Effects on Properties of L-PBF Processed 4130 Low-Alloy Steel
Authors: Abdelwahed Marawan , Casati Riccardo , Larsson Anna , Petrella Stefano , Bengtsson Sven , Vedani Maurizio
Published: January 2022

The microstructure and mechanical properties of a 4130-grade steel processed by L-PBF using a feedstock of low-cost water atomized powder have been investigated considering the effects of powder recycling. Chemical analysis of the recycled powder showed a constant amount of alloying elements with a slight reduction in oxygen content. The as-built microstructure was mainly composed of a martensitic structure separated by a high fraction of low-angle grain boundaries, suggesting the application of a direct tempering treatment starting from the as-built condition as a cost-effective post-process thermal treatment rather than the conventional quench and tempering treatment. Moreover, the degree of anisotropy generated by L-PBF in as-built specimens could be reduced after performing either the direct tempering or the quench and tempering treatments. The possible degradation of powder properties on the steel performance was also investigated. After various powder recycling events, no significant deterioration in tensile properties was measured, indicating that the water atomized powder could be a sustainable feedstock candidate for L-PBF.
Analysis of Damage Evolution in Concrete under Fatigue Loading by Acoustic Emission and Ultrasonic Testing
Authors: Thiele Marc , Pirskawetz Stephan
Published: January 2022

The fatigue process of concrete under compressive cyclic loading is still not completely explored. The corresponding damage processes within the material structure are especially not entirely investigated. The application of acoustic measurement methods enables a better insight into the processes of the fatigue in concrete. Normal strength concrete was investigated under compressive cyclic loading with regard to the fatigue process by using acoustic methods in combination with other nondestructive measurement methods. Acoustic emission and ultrasonic signal measurements were applied together with measurements of strains, elastic modulus, and static strength. It was possible to determine the anisotropic character of the fatigue damage caused by uniaxial loading based on the ultrasonic measurements. Furthermore, it was observed that the fatigue damage seems to consist not exclusively of load parallel oriented crack structures. Rather, crack structures perpendicular to the load as well as local compacting are likely components of the fatigue damage. Additionally, the ultrasonic velocity appears to be a good indicator for fatigue damage beside the elastic modulus. It can be concluded that acoustic methods allow an observation of the fatigue process in concrete and a better understanding, especially in combination with further measurement methods.
Analyses of Vibration Signals Generated in W. Nr. 1.0038 Steel during Abrasive Water Jet Cutting Aimed to Process Control
Authors: Tyč Martin , Hlaváčová Irena M. , Barták Pavel
Published: January 2022

The presented research was aimed at finding a suitable tool and procedure for monitoring undercuts or other problems such as cutting without abrasive or inappropriate parameters of the jet during the abrasive water jet (AWJ) cutting of hard-machined materials. Plates of structural steel RSt 37-2 of different thickness were cut through by AWJ with such traverse speeds that cuts of various qualities were obtained. Vibrations of the workpiece were monitored by three accelerometers mounted on the workpiece by a special block that was designed for this purpose. After detecting and recording vibration signals through the National Instruments (NI) program Signal Express, we processed this data by means of the LabVIEW Sound and Vibration Toolkit. Statistical evaluation of data was performed, and RMS was identified as the parameter most suitable for online vibration monitoring. We focus on the analysis of the relationship between the RMS and traverse speed.
Piston-Based Material Extrusion of Ti-6Al-4V Feedstock for Complementary Use in Metal Injection Molding
Authors: Waalkes Lennart , Längerich Jan , Imgrund Philipp , Emmelmann Claus
Published: January 2022

Piston-based material extrusion enables cost savings for metal injection molding users when it is utilized as a complementary shaping process for green parts in small batch sizes. This, however, requires the use of series feedstock and the production of sufficiently dense green parts in order to ensure metal injection molding-like material properties. In this paper, a methodological approach is presented to identify material-specific process parameters for an industrially used Ti-6Al-4V metal injection molding feedstock based on the extrusion force. It was found that for an optimum extrusion temperature of 95 °C and printing speed of 8 mm/s an extrusion force of 1300 N ensures high-density green parts without under-extrusion. The resulting sintered part properties exhibit values comparable to metal injection molding in terms of part density (max. 99.1%) and tensile properties (max. yield strength: 933 MPa, max. ultimate tensile strength: 1000 MPa, max. elongation at break: 18.5%) depending on the selected build orientation. Thus, a complementary use could be demonstrated in principle for the Ti-6Al-4V feedstock.
Preparation and Properties of Thermoplastic Polyurethane Composites Filled with Powdered Buckwheat Husks
Authors: Włoch Marcin , Landowska Paulina
Published: January 2022

Bio-based fillers for the polymer composites are still interesting from the scientific and industrial point of view, due to their low cost and renewable nature. In this work partially green composites were obtained by the mixing of thermoplastic poly(ester-urethane) with the unmodified and modified (by acetylation) grinded buckwheat husks. Obtained biocomposites were characterized in the terms of their chemical structure (FTIR), microstructure (SEM), thermal stability (TGA), thermomechanical properties (DMTA), and selected mechanical properties. The results showed that introduction of grinded buckwheat husks (even if the amount is 60 wt%) permit retaining high values of tensile strength (around 8–10 MPa), but the increasing amount of applied filler is connected with the decreasing of elongation at break. It can result from good interaction between the polymer matrix and the bio-based filler (confirmed by high values of polymer matrix-filler interaction parameter determined from Pukánszky’s model for the tensile strength of composites). The applied chemical treatment results in changing of mechanical properties of filler and composites. Obtained results confirmed the possibility of using powdered buckwheat husks as filler for thermoplastic polyurethane.
Photocatalytic Degradation of 4,4′-Isopropylidenebis(2,6-dibromophenol) on Sulfur-Doped Nano TiO2
Authors: Kisała Joanna B. , Hörner Gerald , Barylyak Adriana , Pogocki Dariusz , Bobitski Yaroslav
Published: January 2022

In present work, we examine the photocatalytic properties of S-doped TiO2 (S1, S2) compared to bare TiO2 (S0) in present work. The photocatalytic tests were performed in alkaline aqueous solutions (pH = 10) of three differently substituted phenols (phenol (I), 4,4′-isopropylidenebisphenol (II), and 4,4′-isopropylidenebis(2,6-dibromophenol) (III)). The activity of the catalysts was evaluated by monitoring I, II, III degradation in the reaction mixture. The physicochemical properties (particle size, ζ-potential, Ebg, Eu, E0cb, E0vb, σo, KL) of the catalysts were established, and we demonstrated their influence on degradation reaction kinetics. Substrate degradation rates are consistent with first-order kinetics. The apparent conversion constants of the tested compounds (kapp) in all cases reveal the sulfur-loaded catalyst S2 to show the best photocatalytic activity (for compound I and II S1 and S2 are similarly effective). The different efficiency of photocatalytic degradation I, II and III can be explained by the interactions between the catalyst and the substrate solution. The presence of bromine substituents in the benzene ring additionally allows reduction reactions. The yield of bromide ion release in the degradation reaction III corresponds to the Langmuir constant. The mixed oxidation-reduction degradation mechanism results in higher degradation efficiency. In general, the presence of sulfur atoms in the catalyst network improves the degradation efficiency, but too much sulfur is not desired for the reduction pathway.
Benefit of Unsaturated Soil Mechanics Approach on the Modeling of Early-Age Behavior of Rammed Earth Building
Authors: Chauhan Parul , Prime Noémie , Plé Olivier
Published: January 2022

Rammed earth has the potential to reduce the carbon footprint and limit the energy consumption in the building sector due to its sustainable characteristics. Still, its use is not generalized due to a lack of understanding of the material behavior, notably its sensitivity to water. The coupled hydro-mechanical behavior has been recently studied in the framework of unsaturated soil mechanics, using suction as the parameter to represent the hydric state. This dependency of the mechanical behavior on the hydric state leads to uncertainty of the drying period required to progress in the construction process. Notably, the drying period before building the next floor is unknown. To determine the drying period, thermo-hydro-mechanical coupled finite element method simulations were carried out on a single wall by using the unsaturated soil mechanics approach and safety criterion recommendations from the practical guide for rammed earth construction in France. It was determined that it takes significant time for the construction of additional floor both in ‘summer-like’ and ‘winter-like’ environmental conditions, whereas the walls were far away from the ultimate failure state. Thus the drying periods were overestimated. It was concluded that the safety criterion from the practical guide is very conservative and drying periods can be reduced without significantly compromising the safety factor.
Amine Plasma-Polymerization of 3D Polycaprolactone/β-Tricalcium Phosphate Scaffold to Improving Osteogenic Differentiation In Vitro
Authors: Kim Hee-Yeon , Kim Byung-Hoon , Kim Myung-Sun
Published: January 2022

This study aims to investigate the surface characterization and pre-osteoblast biological behaviors on the three-dimensional (3D) poly(ε-caprolactone)/β-tricalcium phosphate (β-TCP) scaffold modified by amine plasma-polymerization. The 3D PCL scaffolds were fabricated using fused deposition modeling (FDM) 3D printing. To improve the pre-osteoblast bioactivity, the 3D PCL scaffold was modified by adding β-TCP nanoparticles, and then scaffold surfaces were modified by amine plasma-polymerization using monomer allylamine (AA) and 1,2-diaminocyclohexane (DACH). After the plasma-polymerization of PCL/β-TCP, surface characterizations such as contact angle, AFM, XRD, and FTIR were evaluated. In addition, mechanical strength was measured by UTM. The pre-osteoblast bioactivities were evaluated by focal adhesion and cell proliferation. Osteogenic differentiation was investigated by ALP activity, Alizarin red staining, and Western blot. Plasma-polymerization induced the increase in hydrophilicity of the surface of the 3D PCL/β-TCP scaffold due to the deposition of amine polymeric thin film on the scaffold surface. Focal adhesion and proliferation of pre-osteoblast improved, and osteogenic differentiation was increased. These results indicated that 3D PCL/β-TCP scaffolds treated with DACH plasma-polymerization showed the highest bioactivity compared to the other samples. We suggest that 3D PCL/β-TCP scaffolds treated with DACH and AA plasma-polymerization can be used as a promising candidate for osteoblast differentiation of pre-osteoblast.
Modelling the Relations of Rheological Characteristics with Composition of Plaster Mortar
Authors: Moskalova Khrystyna , Lyashenko Tatiana , Aniskin Aleksej
Published: January 2022

The rheological properties of fresh plaster mortars, with varied contents of porous fillers and polymer admixtures, have been studied. The quantities of fine limestone and expanded perlite, and dosages of methyl hydroxy ethyl cellulose and ethylene vinyl acetate were varied in the experiment. Effective viscosity (at a shear rate from 0.045 to 5.705 s−1) and the thixotropy of the mixes were determined with rotational viscometer for 18 compositions (according to the design of the experiment). Each of the 18 viscosity curves were described with the Ostwald–de-Waele equation. The Experimental–Statistical models describing the dependencies of the parameters of the rheological model and of mix thixotropy on the composition factors were built on the obtained data. ES-models have allowed the individual and synergetic effects of mix components on the rheological characteristics to be evaluated. The expanded perlite powder can increase the viscosity by two times, probably due to its pozzolanic effect increasing the content of the CSH phase during cement hydration. The thixotropy can be increased by the quantity of limestone. The computational experiments with ES-models have made it possible for the information set, without a noticeable interrelation between rheological characteristics, to be stratified into subsets, in which such interrelations differ significantly.
FEM Simulation of the Riveting Process and Structural Analysis of Low-Carbon Steel Tubular Rivets Fracture
Authors: Jasinski Jaroslaw Jan , Tagowski Michal
Published: January 2022

Riveted joints are a common way to connect elements and subassemblies in the automotive industry. In the assembly process, tubular rivets are loaded axially with ca. 3 kN forces, and these loads can cause cracks and delamination in the rivet material. Such effects at the quality control stage disqualify the product in further assembly process. The article presents an analysis of the fracture mechanism of E215 low-carbon steel tubular rivets used to join modules of driver and passenger safety systems (airbags) in vehicles. Finite element method (FEM) simulation and material testing were used to verify the stresses and analysis of the rivet fracture. Numerical tests determined the state of stress during rivet forming using the FEM-EA method based on the explicit integration of central differences. Light microscopy (LM), scanning electron microscopy (SEM) and chemical composition analysis (SEM-EDS) were performed to investigate the microstructure of the rivet material and to analyze the cracks. Results showed that the cause of rivet cracking is the accumulation and exceeding of critical tensile stresses in the rivet flange during the tube processing and the final riveting (forming) process. Moreover, it was discovered that rivet fracture is largely caused by structural defects (tertiary cementite Fe,Mn3CIII along the boundaries of prior austenite grains) in the material resulting from the incorrectly selected parameters of the final heat treatment of the prefabricate (tube) from which the rivet was produced. The FEM simulation of the riveting and structural characterization results correlated well, so the rivet forming process and fracture mechanism could be fully investigated.
Phonolite Material as Catalyst Support for the Hydrotreatment of Gas Oil and Vegetable Oil Type Feedstocks
Authors: de Paz Carmona Héctor , Frątczak Jakub , Tišler Zdeněk , Hidalgo Herrador José Miguel
Published: January 2022

Phonolite material has shown to be promising catalyst support for the deoxygenation of triglycerides. In this work, we continue with our previous research by synthesising and testing three acid-treated phonolite-supported Co-Mo, Ni-Mo and Ni-W catalysts for the hydrotreating of atmospheric gas oil and co-processing with rapeseed oil at industrial operating conditions (350–370 °C, WHSV 1–2 h−1, 5.5 MPa) in the continuous regime for more than 270 h. The phonolite-supported catalysts showed hydrotreating activity comparable with commercial catalysts, together with a complete conversion of triglycerides into n-alkanes. During co-processing, the Ni-promoted catalyst showed strong stability, with similar activity previous to the rapeseed oil addition. Our results enable us to evaluate the suitability of phonolite as catalyst support for the development of plausible alternatives to conventional hydrotreating catalysts for the co-processing of middle distillates with vegetable oils.
Fabrication and Mechanical Testing of the Uniaxial Graded Auxetic Damper
Authors: Al-Rifaie Hasan , Novak Nejc , Vesenjak Matej , Ren Zoran , Sumelka Wojciech
Published: January 2022

Auxetic structures can be used as protective sacrificial solutions for impact protection with lightweight and excellent energy-dissipation characteristics. A recently published and patented shock-absorbing system, namely, Uniaxial Graded Auxetic Damper (UGAD), proved its efficiency through comprehensive analytical and computational analyses. However, the authors highlighted the necessity for experimental testing of this new damper. Hence, this paper aimed to fabricate the UGAD using a cost-effective method and determine its load–deformation properties and energy-absorption potential experimentally and computationally. The geometry of the UGAD, fabrication technique, experimental setup, and computational model are presented. A series of dog-bone samples were tested to determine the exact properties of aluminium alloy (AW-5754, T-111). A simplified (elastic, plastic with strain hardening) material model was proposed and validated for use in future computational simulations. Results showed that deformation pattern, progressive collapse, and force–displacement relationships of the manufactured UGAD are in excellent agreement with the computational predictions, thus validating the proposed computational and material models.
High Thermoelectric Performance Achieved in Sb-Doped GeTe by Manipulating Carrier Concentration and Nanoscale Twin Grains
Authors: Li Chao , Song Haili , Dai Zongbei , Zhao Zhenbo , Liu Chengyan , Yang Hengquan , Cui Chengqiang , Miao Lei
Published: January 2022

Lead-free and eco-friendly GeTe shows promising mid-temperature thermoelectric applications. However, a low Seebeck coefficient due to its intrinsically high hole concentration induced by Ge vacancies, and a relatively high thermal conductivity result in inferior thermoelectric performance in pristine GeTe. Extrinsic dopants such as Sb, Bi, and Y could play a crucial role in regulating the hole concentration of GeTe because of their different valence states as cations and high solubility in GeTe. Here we investigate the thermoelectric performance of GeTe upon Sb doping, and demonstrate a high maximum zT value up to 1.88 in Ge0.90Sb0.10Te as a result of the significant suppression in thermal conductivity while maintaining a high power factor. The maintained high power factor is due to the markable enhancement in the Seebeck coefficient, which could be attributed to the significant suppression of hole concentration and the valence band convergence upon Sb doping, while the low thermal conductivity stems from the suppression of electronic thermal conductivity due to the increase in electrical resistivity and the lowering of lattice thermal conductivity through strengthening the phonon scattering by lattice distortion, dislocations, and twin boundaries. The excellent thermoelectric performance of Ge0.90Sb0.10Te shows good reproducibility and thermal stability. This work confirms that Ge0.90Sb0.10Te is a superior thermoelectric material for practical application.
Physicochemical Characterization of Cherry Pits-Derived Biochar
Authors: Frišták Vladimír , Bošanská Diana , Pipíška Martin , Ďuriška Libor , Bell Stephen M. , Soja Gerhard
Published: January 2022

Although the suitability of some biochars for contaminants’ sorption separation has been established, not all potential feedstocks have been explored and characterized. Here, we physicochemically characterized cherry pit biochar (CPB) pyrolyzed from cherry pit biomass (CP) at 500 °C, and we assessed their As and Hg sorption efficiencies in aqueous solutions in comparison to activated carbon (AC). The basic physicochemical and material characterization of the studied adsorbents was carried out using pH, electrical conductivity (EC), cation exchange capacity (CEC), concentration of surface functional groups (Boehm titration), and surface area (SA) analysis; elemental C, H, N analysis; and Fourier-transform infrared spectroscopy (FTIR) and scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM–EDX). AsO43− anions and Hg2+ cations were selected as model contaminants used to test the sorption properties of the sorption materials. Characterization analyses confirmed a ninefold increase in SA in the case of CPB. The total C concentration increased by 26%, while decreases in the total H and N concentrations were observed. The values of carbonate and ash contents decreased by about half due to pyrolysis processes. The concentrations of surface functional groups of the analyzed biochar obtained by Boehm titration confirmed a decrease in carboxyl and lactone groups, while an increase in phenolic functional groups was observed. Changes in the morphology and surface functionality of the pyrolyzed material were confirmed by SEM–EDX and FTIR analyses. In sorption experiments, we found that the CPB showed better results in the sorption separation of Hg2+ than in the sorption separation of AsO43−. The sorption efficiency for the model cation increased in the order CP < CPB < AC and, for the model anion, it increased in the order CPB < CP < AC.
Effects of Oxygen Partial Pressure and Substrate Temperature on the Structure and Morphology of Sc and Y Co-Doped ZrO2 Solid Electrolyte Thin Films Prepared via Pulsed Laser Deposition
Authors: Rabo Jennet R. , Takayanagi Makoto , Tsuchiya Takashi , Nakajima Hideki , Terabe Kazuya , Cervera Rinlee Butch M.
Published: January 2022

Scandium (Sc) and yttrium (Y) co-doped ZrO2 (ScYSZ) thin films were prepared on a SiO2-Si substrate via pulsed laser deposition (PLD) method. In order to obtain good quality thin films with the desired microstructure, various oxygen partial pressures (PO2) from 0.01 Pa to 10 Pa and substrate temperatures (Ts) from 25 °C to 800 °C were investigated. X-ray diffraction (XRD) patterns results showed that amorphous ScYSZ thin films were formed at room substrate temperature while cubic polycrystalline thin films were obtained at higher substrate temperatures (Ts = 200 °C, 400 °C, 600 °C, 800 °C). Raman spectra revealed a distinct Raman shift at around 600 cm−1 supporting a cubic phase. However, a transition from cubic to tetragonal phase can be observed with increasing oxygen partial pressure. Photoemission spectroscopy (PES) spectra suggested supporting analysis that more oxygen vacancies in the lattice can be observed for samples deposited at lower oxygen partial pressures resulting in a cubic structure with higher dopant cation binding energies as compared to the tetragonal structure observed at higher oxygen partial pressure. On the other hand, dense morphologies can be obtained at lower  PO2 (0.01 Pa and 0.1 Pa) while more porous morphologies can be obtained at higher PO2 (1.0 Pa and 10 Pa).
Meso- and Macro-Mechanical Analysis of the Frost-Heaving Effect of Void Water on Asphalt Pavement
Authors: Fu Jiancun , Shen Aiqin
Published: January 2022

In cold regions, many types of structural damages are caused by the frost heaving of asphalt pavements. Hence, it is important to quantitatively determine the frost-heaving effect of asphalt pavement using a mechanical method to control frost-heaving damage. In this study, first, the internal voids of the asphalt mixture were regarded as a single void, and the water phase transition generating the freezing water in the voids was simulated using a simplified hollow sphere model to create a uniform internal pressure. Second, the prediction equation of the equivalent linear expansion coefficient was proposed by taking the phase transition of water in the saturated asphalt mixture voids into account. A step function was used during the phase transition of water to determine the sudden change in the equivalent linear expansion coefficient, heat capacity, density, and thermal conductivity. Finally, the typical cooling conditions were simulated with the water phase transition and the nonwater phase transition. The experimental results showed that the proposed model could accurately simulate the effect of frost heaving. Higher stress and strain were generated on the surface and in the interior of the pavement, and the positions of maximum stress and strain occurred on the pavement surface under the frost-heaving conditions. The compressive strength of the asphalt mixture in a uniaxial compression test is about 4.5–6 MPa with a single freeze–thaw cycle. Furthermore, when frost heaving occurs on the asphalt pavement between 5.8 and 6.5 MPa, the numerical simulation method can be used to calculate the internal stress of the structure, which found that the compressive stress under the frost-heaving condition was the same magnitude as the compressive strength under the freeze–thaw testing condition.