bluuebunny/crossref_metadata_2025 huggingface dataset:
Creep Deformation Modeling of Glutinous Rice Cakes (Mochi)
Authors: Chuang George Chao‐Chi , Yeh An‐I
Published: June 2007

The viscoelastic properties of glutinous rice cakes (mochi) made by extrusion at different conditions (water contents of 45–55% and barrel temperatures of 75–95°C) and commercial rice cakes were studied by a creep test. The maximum compliances of extruded mochi were 0.15–4.23 1/kPa. Among the extruded samples, the mochi extruded at 75°C with a water content of 55% was the one that yielded the largest maximum compliance. At the same barrel temperature, the creep compliance increased with the water content. Four models with different numbers of elements (spring and dashpot) were employed to fit the experimental data. The model coefficients were able to provide the corresponding elastic and viscous behavior of the sample. The 3‐element model (a spring in series with a Kelvin‐Voigt model) did not exhibit steady‐state compliance as observed in the experimental data. The 4‐element (Burger's model), modified 4‐element (an approximation of Burger's model), and 6‐element model (adding one more Kelvin model to the Burger's model) yielded R2 > 0.99. Results showed that the 4‐element model was adequate to describe the creep behavior of mochi.
In Vitro Starch Digestibility of Tortillas Elaborated by Different Masa Preparation Procedures
Authors: Bello‐Pérez Luis A. , Rendón‐Villalobos J. Rodolfo , Agama‐Acevedo Edith , Islas‐Hernández José Juan
Published: June 2007

Starch digestibility was evaluated in freshly prepared tortillas elaborated from masa obtained from different procedures (laboratory‐made masa, commercial masa, and nixtamalized corn flour) and from laboratory‐made masa with added commercial hydrocolloid, and stored for 24, 48, and 74 hr. Tortillas prepared with commercial masa had the highest available starch (AS) content and the commercial tortillas had the lowest, showing a decrease in AS content when storage time increased. Tortilla of commercial masa showed the lowest resistant starch (RS) content that agrees with the AS measured. However, tortilla of laboratory‐made masa presented the highest AS and RS contents. RS increased with storage time, a pattern that is related to the starch retrogradation phenomenon observed when retrograded resistant starch (RRS) was quantified. Commercial tortillas showed predicted glycemic index (pGI) values of 62–75% using a chewing/dialysis procedure (semi in vitro method). Index values were lower than those determined in vitro. The pGI of tortillas decreased, and the values were different depending on the method used to prepare the masa and tortilla. Commercial tortilla and tortilla of NCF had the lowest pGI. Therefore, the procedure to obtain masa and thereafter obtain tortillas influenced the starch digestibility of the product.
Quality Characteristics of Fresh and Dried White Salted Noodles Enriched with Flour from Hull‐less Barley Genotypes of Diverse Amylose Content
Authors: Lagassé S. L. , Hatcher D. W. , Dexter J. E. , Rossnagel B. G. , Izydorczyk M. S.
Published: June 2007

Fresh and dried white salted noodles (WSN) were prepared by incorporating up to 40% flour from hull‐less barley (HB) genotypes with normal amylose, waxy, zero amylose waxy (ZAW), and high amylose (HA) starch into a 60% extraction Canada Prairie Spring White (cv. AC Vista) wheat flour. The HB flours, depending on genotype, contained four to six times the concentration of β‐glucan of the wheat flour, offering potential health benefits. The HB‐enriched noodles were made with conventional equipment without difficulty. Noodles containing 40% HB flour required less work input during sheeting, probably due to higher optimum water absorption and weakening of the dough due to dilution of wheat gluten. The addition of HB flour had a negative impact on WSN color and appearance, as evident from decreased brightness, increased redness, and more visible specking. The impact of HB flour on cooked WSN texture varied by starch type. Enrichment with HA or normal starch HB flour produced WSN with bite and chewiness values equivalent to or superior to the wheat flour control. Addition of waxy and ZAW HB flour resulted in WSN with lower values for bite and chewiness. The diversity of HB starch types allows tailoring of WSN texture to satisfy specific markets. HB flour also has potential as an ingredient in novel noodle products targeting health‐conscious consumers who associate darker colored cereal‐based foods with superior nutritional composition.
Effects of Salt and Alkaline Reagents on Dynamic Rheological Properties of Raw Oriental Wheat Noodles
Authors: Wu Jianping , Beta Trust , Corke Harold
Published: June 2007

To gain further understanding of the functionality of ingredients in oriental wheat noodles, the rheological properties of raw noodles made using high protein (Red Bicycle) or low protein (Sandow) wheat flours and various additives (salt or alkaline reagents at concentrations of 0, 0.1, 0.5, 1.0, 2.0, 3.0, and 4.0%) were investigated using frequency sweep and temperature sweep oscillatory tests. Generally, both the elastic modulus(G′) and viscous modulus (G″) of raw noodles increased when various levels of salt or alkaline (kansui and NaOH) reagents were included in the formulation, with the exception of Red Bicycle noodles where the G″ was not significantly affected by the salt. The G′was significantly decreased in the presence of sodium chloride at concentrations ≤4.0% and kansui at <0.5%. The change in rheological properties of raw noodles was related to the wheat flour quality, type, level of additive, and frequency. The G′, G″, phase angle, and complex viscosity changed in a similar pattern when raw noodles were heated from 25 to 100°C. These parameters decreased initially with increasing temperature until they reached a valley and then increased either to a plateau or continuously in noodles containing kansui. The appearance of valley points at 75.5 and 77.2°C during heating of Sandow and Red Bicycle noodles containing salt, and 89.4, and 83.2°C during heating of Sandow and Red Bicycle noodles containing kansui, respectively, was not associated with starch gelatinization as determined using differential scanning calorimetry. The continuous increase in G′, G″, and complex viscosity observed with noodles containing kansui during the hold period at 100°C was attributed to the high pH environment and not to the inactivation of α‐amylase.
Corn Gluten Meal Odorants and Volatiles After Treatment to Improve Flavor
Authors: Wu Y. V. , Payne‐Wahl K. L. , Vaughn S. F.
Published: June 2007

Production of corn gluten meal (CGM), a high‐protein coproduct from wet milling of corn, is increasing as production of fuel ethanol from corn increases. Unpleasant taste and odor have limited the use of CGM in human food. Adjustment of pH and extraction with water have been reported to reduce the off‐flavor of CGM but the improvement is not enough for substantial addition of CGM to the human diet. More study of CGM is needed. In this study, volatile compounds released under different conditions of pH, water extraction, and temperature were identified and compared using solid‐phase microextraction‐gas chromatography‐mass spectrometry (SPME‐GC‐MS). The water‐extractable portion, which improves the taste of CGM by its absence, was dried and analyzed by SPME‐GC‐MS. In addition, materials extractable from CGM with methylene chloride were identified by gas chromatography‐mass spectrometry (GC‐MS). Further, the spontaneous generation of a CGM‐like odor accompanied by a change in physical appearance of the CGM sample was described. Flavors and odors known to be associated with the identified CGM compounds were listed. Some possible origins of the volatiles, from degradation of corn constituents or as fermentation products of the corn steeping process, were noted.
Comparison of Methods for Gluten Strength Assessment
Authors: Gaines C. S. , Reid J. Frégeau , Vander Kant C. , Morris C. F.
Published: June 2007

Five methods that employed very different testing principles and procedures for assessing gluten quality were compared for 33 North American soft red and white wheats. The three methods analyzed flour (alveograph work, lactic acid solvent retention capacity, and mixograph peak time) and two methods employed ground wheat meal (Glutomatic gluten index and SDS sedimentation volume). Compared against the normalized mean of all five assessments, the ability of the assessment methods to evaluate gluten quality decreased in the order: alveograph work, lactic acid solvent retention capacity, mixograph peak time, Glutomatic gluten index, and SDS sedimentation volume. The methods utilizing flour were substantially superior predictive methods; however, the two meal‐based methods could be sufficient for early generation screening when flour is not available.
Preparation of High‐Quality Protein‐Based Extruded Pellets Expanded by Microwave Oven
Authors: Aguilar‐Palazuelos E. , de J. Zazueta‐Morales J. , Martínez‐Bustos F.
Published: June 2007

The aim of this work was to study the effects of extrusion barrel temperature (75–140°C) and feed moisture (16–30%) on the production of third‐generation snacks expanded by microwave heating. A blend of potato starch (50%), quality protein maize (QPM) (35%), and soybean meal (SM) (15%) was used in the preparation of the snacks. A laboratory single extruder with a 1.5 × 20.0 × 100 mm die‐nozzle and a central composite routable experimental design were used. Expansion index (EI) and bulk density (BD) were measured in expanded pellets, viscosity at 83°C (V83), thermal properties, and relative crystallinity were measured in extruded pellets. EI increased and BD decreased when the barrel temperature was increased, while the feed moisture effect was not significant. V83 increased when feed moisture increased. Extrusion modified the crystalline structures of the pellets and the X‐ray data suggests the formation of new structures, probably due to the development of amylose‐lipid complexes. The maximum expansion of pellets was found at barrel temperatures of 123–140°C, and feed moisture of 24.5–30%. It is possible to obtain a functional third‐generation snack with good expansion characteristics using a microwave oven, and this snack has health benefits due to the addition of QPM and SM.
Quantitative Analysis of Fat Content in Rice by Near‐Infrared Spectroscopy Technique
Authors: Wang H. L. , Wan X. Y. , Bi J. C. , Wang J. K. , Jiang L. , Chen L. M. , Zhai H. Q. , Wan J. M.
Published: June 2007

Fat content in rice is one of the most important nutritional quality properties. But the chemical analysis of fat content is time‐consuming and costly and could result in poor reproduction between replicates. Near‐infrared spectroscopy (NIRS) can solve those problems by providing a rapid, nondestructive, and quantitative analysis. Based on the NIRS technique and partial least squares (PLS) algorithm, four calibration models were established to quantitatively analyze fat content in brown rice grain and flour and milled rice grain and flour with 248 representative samples. The determination coefficients (R2) of these calibration models were 0.79, 0.84, 0.89, and 0.91, respectively, with the corresponding root mean square errors 0.16, 0.14, 0.09, and 0.08%. The R2 were 0.73, 0.81, 0.81, and 0.89 with the corresponding root mean square errors 0.17, 0.15, 0.12, and 0.09%, respectively, in cross validation. The R2 were 0.62, 0.80, 0.81, and 0.87, respectively, with the root mean square errors 0.25, 0.31, 0.28, and 0.30% in external validation. These results indicate that the method of NIRS has relatively high accuracy in the prediction of rice fat content. The four calibration models established in the present study should be useful for nutrient quality improvement in rice breeding.
Polymer Conformation Structure of Wheat Proteins and Gluten Subfractions Revealed by ATR‐FTIR
Authors: Li W. , Dobraszczyk B. J. , Dias A. , Gil A. M.
Published: June 2007

The polymer conformation structure of gluten extracted from a Polish wheat cultivar, Korweta, and gluten subfractions obtained from 2 U.K. breadmaking and biscuit flour cultivars, Hereward and Riband, was investigated using attenuated total reflectance Fourier transform infrared spectroscopy (ATR‐FTIR). The results showed the conformation of proteins varied between flour, hydrated flour, and hydrated gluten. The β‐sheet structure increased progressively from flour to hydrated flour and to hydrated gluten. In hydrated gluten protein fractions comprising gliadin, soluble glutenin, and gel protein, β‐sheet structure increased progressively from soluble gliadin and glutenin to gluten and gel protein; β‐sheet content was also greater in the gel protein from the breadmaking flour Hereward than the biscuit flour Riband.
Effect of Hydrophilic Gums on the Quality of Frozen Dough: Electron Microscopy, Protein Solubility, and Electrophoresis Studies
Authors: Sharadanant R. , Khan K.
Published: June 2007

Hydrophilic gums have been shown to improve the shelf‐life stability of frozen doughs during long periods of frozen storage. The objective of this research was to determine the effect of gums on starch and protein characteristics of frozen doughs using electron microscopy and electrophoresis studies. Frozen doughs, supplemented with three levels of gum arabic, carboxy methyl cellulose (CMC), kappa (κ) carrageenan, and locust bean gum, were studied after day 1 and after 4, 8, 12, and 16 weeks of frozen storage. Changes in the ultra structure of the frozen doughs were investigated, as well as the solubilities and composition of dough proteins by SDS‐PAGE. Scanning electron micrographs of doughs evaluated on day 0 (unfrozen) showed starch granules securely embedded in the gluten matrix. However, after 8 and 16 weeks of frozen storage, the frozen control dough without the gum additives clearly showed damage to the gluten network, and the starch granules appeared to be separated from the gluten. Doughs with locust bean gum and gum arabic showed better retention of the gluten network compared with the frozen control evaluated after different periods of storage. The SDS‐soluble protein content increased while residue protein content decreased as the frozen storage time increased. After each frozen storage period, the control dough without the gum additive had the highest amount of SDS‐soluble proteins and the lowest amount of residue proteins when compared with the doughs treated with gums. κ‐Carrageenan and locust bean gum had the lowest amount of SDS‐soluble proteins compared with doughs with CMC and gum arabic. The frozen control had the lowest amount of residue proteins at any particular time of frozen storage. κ‐Carrageenan treated doughs had the highest amount of residue proteins, followed by doughs with locust bean gum. Doughs with gum arabic and CMC had the lowest amount of residue proteins but still higher than the control doughs.
In Vitro Bile Acid Binding Capacity of Milled Wheat Bran and Milled Extruded Wheat Bran at Five Specific Mechanical Energy Levels
Authors: Kahlon T. S. , de J. Berrios J. , Smith G. E. , Pan J. L.
Published: June 2007

The in vitro binding of bile acids of milled wheat bran (MWB) and milled extruded wheat bran (MEB) at five specific mechanical energy (SME) levels of 120 (MEB‐120), 177 (MEB‐177), 234 (MEB‐234), 291 (MEB‐291), and 358 (MEB‐358) Whr/kg on a fat‐free dry weight basis was determined using a mixture of bile acids secreted in human bile at duodenal physiological pH 6.3. Relative to cholestyramine (bile acid binding, cholesterol lowering drug) in vitro bile acid binding capacity on dry matter, total dietary fiber (TDF), and insoluble dietary fiber (IDF) basis was for MWB: 21, 43, 45%; the range for MEB was 18–21%, 34–41%, and 36–43%, respectively. MWB resulted in significantly higher bile acid binding than that of MEB at 120, 234, and 291 Whr/kg on a dry matter, TDF, and IDF basis. These results demonstrate the relative health‐promoting potential of MWB = MEB‐177 = MEB‐358 > MEB‐120 = MEB‐234 = MEB‐291 as indicated by the bile acid binding on a dry matter basis. Data suggest that significant improvement in health‐promoting (cholesterol‐lowering and cancer‐preventing) potential could be obtained in WB by milling (low‐cost processing) the bran to finer particle sizes and extruding (high‐cost technology). Milling WB to small particle size (weighted mean 0.508 mm) increased surface area, in addition it may have induced changes in the physical and chemical characteristics of WB or created new linkages, binding sites of the proteins, starches, and nonstarch polysaccharides, which significantly increased the bile acid binding ability of the MWB.
Explaining Rice Milling Quality Variation Using Historical Weather Data Analysis
Authors: Cooper N. T. W. , Siebenmorgen T. J. , Counce P. A. , Meullenet J.‐F.
Published: June 2007

Rice quality, specifically head rice yield (HRY), can vary inexplicably from one lot to another, and from year to year. In an effort to correlate air temperatures during various growth stages to HRY, growth staging data expressed in degree day units was used to predict the occurrence of sequential growth stages within a set of 17‐year historical data, which included HRY and 50% heading dates for two long‐grain rice cultivars, (Oryza sativa L) Newbonnet and Lemont, and area weather data. HRY was most strongly affected by the average daily low temperature (or nighttime temperature) during the R8 developmental stage. Lower HRY were associated with high nighttime air temperatures during this stage for both Newbonnet and Lemont. When used as a single variable in a regression model, the nighttime temperature during the R8 developmental stage explained over 25% of the variation in HRY.
Comparison of Quality Characteristics and Breadmaking Functionality of Hard Red Winter and Hard Red Spring Wheat
Authors: Maghirang E. B. , Lookhart G. L. , Bean S. R. , Pierce R. O. , Xie F. , Caley M. S. , Wilson J. D. , Seabourn B. W. , Ram M. S. , Park S. H. , Chung O. K. , Dowell F. E.
Published: June 2007

Various whole‐kernel, milling, flour, dough, and breadmaking quality parameters were compared between hard red winter (HRW) and hard red spring (HRS) wheat. From the 50 quality parameters evaluated, values of only nine quality characteristics were found to be similar for both classes. These were test weight, grain moisture content, kernel size, polyphenol oxidase content, average gluten index, insoluble polymeric protein (%), free nonpolar lipids, loaf volume potential, and mixograph tolerance. Some of the quality characteristics that had significantly higher levels in HRS than in HRW wheat samples included grain protein content, grain hardness, most milling and flour quality measurements, most dough physicochemical properties, and most baking characteristics. When HRW and HRS wheat samples were grouped to be within the same wheat protein content range (11.4–15.8%), the average value of many grain and breadmaking quality characteristics were similar for both wheat classes but significant differences still existed. Values that were higher for HRW wheat flour were color b*, free polar lipids content, falling number, and farinograph tolerance. Values that were higher for HRS wheat flour were geometric mean diameter, quantity of insoluble polymeric proteins and gliadins, mixograph mix time, alveograph configuration ratio, dough weight, crumb grain score, and SDS sedimentation volume. This research showed that the grain and flour quality of HRS wheat generally exceeds that of HRW wheat whether or not samples are grouped to include a similar protein content range.
Isolation of Zein Using 100% Ethanol
Authors: Lawton John W.
Published: June 2007

Traditionally, zein is isolated and recovered from corn gluten meal (GCM) using aqueous alcohol as the solvent. Recovery of zein from this solvent is inconvenient and costly. Zein is insoluble in 100% ethanol at room temperature, but it is soluble at 120°C in ethanol. Absolute ethanol effectively extracted zein from CGM, distillers dried grains (DDG), and ground corn. Zein was extracted from CGM with absolute ethanol in a high‐pressure reactor at 130°C. After extracting at 130°C for 45 min, the solution was pumped out of the extractor and allowed to cool. Upon cooling, the zein precipitated from solution. The precipitate was removed from the solution and air‐dried, resulting in 14% recovery of the starting material. The recovered precipitate had an average protein content of >90% on a dry basis, accounting for ≈20% of the CGM protein and recovered ≈35% of its zein. No differences were seen in the amount of zein extracted from CGM samples that were hand‐collected off the dewatering screen and gently dried, versus commercial CGM samples. The commercial CGM did produce a greater amount of solubles. The extraction procedure also worked at temperatures as low as 90°C. The lower temperature did produce lower yields of extracted zein. The zein extracted at the lower temperatures was less brown, but zein extracted at either temperature was almost fully soluble in traditional zein solvents.
Effects of Amylose, Corn Protein, and Corn Fiber Contents on Production of Ethanol from Starch‐Rich Media
Authors: Wu X. , Zhao R. , Wang D. , Bean S. R. , Seib P. A. , Tuinstra M. R. , Campbell M. , O'Brien A.
Published: June 2007

The effects of amylose, protein, and fiber contents on ethanol yields were evaluated using artificially formulated media made from commercial corn starches with different contents of amylose, corn protein, and corn fiber, as well as media made from different cereal sources including corn, sorghum, and wheat with different amylose contents. Second‐order response‐surface regression models were used to study the effects and interactions of amylose, protein, and fiber contents on ethanol yield and conversion efficiency. The results showed that the amylose content of starches had a significant (P < 0.001) effect on ethanol conversion efficiency. No significant effect of protein content on ethanol production was observed. Fiber did not show a significant effect on ethanol fermentation either. Conversion efficiencies increased as the amylose content decreased, especially when the amylose content was >35%. The reduced quadratic model fits the conversion efficiency data better than the full quadratic model does. Fermentation tests on mashes made from corn, sorghum, and wheat samples with different amylose contents confirmed the adverse effect of amylose content on fermentation efficiency. High‐temperature cooking with agitation significantly increased the conversion efficiencies on mashes made from high‐amylose (35–70%) ground corn and starches. A cooking temperature of ≥160°C was needed on high‐amylose corn and starches to obtain a conversion efficiency equal to that of normal corn and starch.
Relationships Between the Microstructure, Physical Features, and Chemical Composition of Different Maize Accessions from Latin America
Authors: Narváez‐González Ernesto David , de Dios Figueroa‐Cárdenas Juan , Taba Suketoshi , Tostado Eduardo Castaño , Peniche Ramón Álvar Martínez , Sánchez Froylán Rincón
Published: June 2007

Chemical composition (moisture, total lipids, protein, and apparent amylose) and some physical features (1,000 kernel weight, hardness, and anatomical composition) were determined in 71 accessions representing races of maize from Latin America. Their microstructural characteristics (size and compaction of endosperm cell bodies, pericarp thickness, horny‐floury endosperm ratio, and morphology and size of starch granules) were also evaluated using environmental scanning electron microscopy (ESEM). Compaction was the most important microstructural feature of the maize kernels, representing kernel hardness. Highly compact kernels tended to be hard, with high protein, pericarp, and hard‐endosperm content and high pericarp thickness, but with low moisture, amylose content, and kernel weight and size. The opposite was observed in the least compact kernels. Highly compact kernels tended to have small, polygonal starch granules (<10 μm), while the least compact kernels contained large, spherical granules (>10 μm). These results suggest that microstructure is responsible for the physical features of maize kernels and that microstructure is related to chemical composition.
Compression Deformation and Structural Relationships of Medium Grain Cooked Rice
Authors: Ogawa Yukiharu , Wood Delilah F. , Whitehand Linda C. , Orts William J. , Glenn Gregory M.
Published: June 2007

Cooked rice quality is based on a number of factors including texture. Texture and structure of foods are closely related and aspects of the relationship can be explored by correlating compression measurements to structural observations of the compressed material. To obtain compression measurements, single cooked, milled rice grains were compressed in a texture analyzer to a specific percentage (% compression) of the original grain; the uncompressed grain is 0%. The experiment, using single grains in each case, was repeated multiple times. Compression percentages of 20, 30, 40, 50, 60, and 70% were measured against a constant resistance force in the texture analyzer. Structures of cooked rice grains at the various compression levels were compared by brightfield and fluorescence microscopy. The outside of an uncompressed, intact, cooked rice grain is swollen and distorted while the interior has three or more odd‐shaped holes (voids). Each void is largest in the center of the grain and decreases in size toward the peripheral edges becoming fine cracks toward the outermost portion of the void. The voids tended to increase in area up to 40% compression and then decrease in area upon further compression. Percent compression versus resistance force was a curvilinear relationship. With increasing % compression, cell shapes became increasingly more rounded, although there wasn't much effect on the integrity of cell walls with increasing % compression. The degree to which grain structure changed during the various compression tests, combined with the curvilinear behavior of resistance force versus % compression, indicates that the voids and cell walls have an effect on texture.
Formation of Homopolymers and Heteropolymers Between Wheat Flour and Several Protein Sources by Transglutaminase‐Catalyzed Cross‐Linking
Authors: Bonet A. , Blaszczak W. , Rosell C. M.
Published: June 2007

The effect of different protein sources (soy flour, lupin flour, egg albumin, gelatin powder, protein‐rich beer yeast flour) on wheat dough functionality was tested by determining gluten index, texture properties, and thermomechanical parameters. Transglutaminase (TG) was also added to improve the dough functionality by forming cross‐links. The presence of protein sources had a significant effect on the gluten index, with the exception of lupin flour. Gelatin and the presence of TG resulted in significant single effects on the texture properties of the wheat‐protein dough. All the protein sources significantly modified the mixing characteristics of the dough or the thermal behavior. Capillary electrophoresis studies of the water‐soluble, salt‐soluble, and glutenin proteins indicated that interactions were mainly within proteins, thus homologous polymers. Scanning electron microscopy studies of the doughs made from blends of wheat and protein sources doughs supported the formation of heterologous structures in the wheat‐lupin blends. The combination of TG and lupin would be a promising method to be used on the treatment of insect‐damaged or weak flours, to increase the gluten strength.
Debranching of β‐Dextrins to Explore Branching Patterns of Amylopectins from Three Maize Genotypes
Authors: Xia Huan , Thompson Donald B.
Published: June 2007

The amylopectin (AP) branching pattern is a fundamental feature of AP fine structure but a little‐studied one. In this work, we followed enzyme digestion over time for AP from three maize genotypes (wx, du wx, and AP of ae VII). The objective was to describe differences in the progress of β‐amylolysis and in subsequent debranching of β‐limit dextrins (β‐LD). During the progress of β‐amylolysis, changes in the distribution of short residual chains show that the enzyme favors hydrolysis farthest from branch points. On treating β‐LD with isoamylase (IA) alone, debranching was incomplete. Using IA and pullulanase (PUL) sequentially, a similar increase in the DP 5–7 region and the peak at DP 6 were observed for all samples, indicating a common element in the branching pattern. This similarity suggests that, despite differences in the proportion of short to long B chains, the most closely associated branch points may be arranged in a similar way for these AP. We suggest that the increase in DP 6 after PUL digestion would result from debranching of linear DP 6 residual B chains that originally had two branch points, consistent with interior segment length (ISL) of 1 or 2.
Influence of Flour Chlorination and Ingredient Formulation on the Quality Attributes of Pancakes
Authors: Finnie S. M. , Bettge A. D. , Morris C. F.
Published: June 2007

Soft wheat flour is commonly chlorinated in North America for the production of cakes and pancakes. The oxidative properties of chlorine gas cause chemical modifications to flour components that enhance processing and end‐use functionality of the intended food products. The objectives of this study were 1) to compare how untreated and chlorine‐treated commercial soft wheat flour perform in a standard pancake formulation and 2) to compare how the individual ingredients in a standard pancake formulation influence quality attributes of pancakes made with untreated as well as chlorine‐treated commercial soft wheat flour. Two portions of the same soft wheat flour, one chlorinated and the other un‐chlorinated, were used to study the effects of flour chlorination on batter viscosity, geometry, and texture quality attributes of pancakes. Commercial pancake formula ingredients were evaluated at different concentrations for their individual influence on quality attributes of pancakes. Differences in means (ANOVA) were used to evaluate the influence of the sources of pancake quality variation. The results indicate that flour chlorination had a significant influence on pancake batter viscosity, geometry, and texture, with chlorinated flour producing a more viscous batter, a larger and thicker pancake that was softer, more cohesive and resilient. The evaluation of a wide range of formula ingredient concentrations indicated that none could wholly substitute for chlorination. Individual ingredients did dramatically influence pancake batter viscosity, geometry, and texture, especially soy flour, dextrose, and leavening agents. However, sucrose and shortening had nonsignificant influences on the end‐use quality of both chlorinated and unchlorinated pancakes.
Physical and Sensory Characteristics of Extruded Products Made from Two Oat Lines with Different β‐Glucan Concentrations
Authors: Yao Ni , Jannink Jean‐Luc , Alavi Sajid , White Pamela J.
Published: June 2007

The impact of extrusion on physical and sensory properties and on the in vitro bile acid (BA) binding was examined for N979 and Jim oat (Avena sativa) lines with 8.1 and 4.8% β‐glucan, respectively. Based on hardness and edibility of products made from Jim oats, moisture concentrations of 16–25% and temperatures of 165–180°C were selected for N979 extrusion. Jim‐based cereal had a significantly greater (P < 0.05) expansion ratio than did N979‐based cereal at most moistures. N979 cereal was browner, but not harder, than Jim cereal. Extruded products from N979 and Jim oats had 5.29–5.99% and 3.38–3.94% β‐glucan, respectively. Changing extrusion temperature or moisture content did not affect β‐glucan concentration in the products. N979 cereal made at 165°C and 16% moisture had greater BA binding than at other conditions, and had crunchiness comparable to cereals made at other conditions. BA binding of Cheerios brand breakfast cereal was close to that of N979 cereal made at 180°C and 18% moisture, but lower than cereals made at other conditions. Cereals made from Jim and N979 oats were browner, harder, coarser, and crunchier than Cheerios breakfast cereal. Proper processing and preparation techniques should be considered when producing extruded products from high β‐glucan oats.
Effects of Ground Corn Particle Size on Ethanol Yield and Thin Stillage Soluble Solids
Authors: Naidu Kalpana , Singh Vijay , Johnston David B. , Rausch Kent D. , Tumbleson M. E.
Published: June 2007

The effects of ground corn particle size on ethanol yield and soluble solids in thin stillage was evaluated using a 2‐L laboratory dry‐grind procedure. The procedure was optimized for grinding, liquefaction, sacchari‐fication, and fermentation parameters. The optimized procedure was reproducible with a coefficient of variation of 3.6% in ethanol yield. Five particle size distributions of ground corn were obtained using a cross‐beater mill equipped with five screens (0.5, 2, 3, 4, and 5 mm). Particle size had an effect on ethanol yield and on soluble solids concentration in thin stillage. The highest ethanol yield of 12.6 mL/100 mL of beer was achieved using a 0.5‐mm screen in the cross‐beater mill. Treatment using the 0.5‐mm mill screen resulted in soluble solids concentration of 25.1 g/L and was higher than soluble solids concentrations obtained with other screens. No differences in soluble solid concentrations were observed in samples of thin stillage obtained from 2, 3, 4, and 5‐mm screens which had a mean yield of 16.2 g/L. By optimizing particle size for maximum ethanol yield and minimum solids in thin stillage, dry‐grind corn plants could realize reduced capital and operating costs.
Investigation of Digestibility In Vitro and Physicochemical Properties of A‐ and B‐Type Starch from Soft and Hard Wheat Flour
Authors: Liu Q. , Gu Z. , Donner E. , Tetlow I. , Emes M.
Published: June 2007

In this study, the functional properties of A‐ and B‐type wheat starch granules from two commercial wheat flours were investigated for digestibility in vitro, chemical composition (e.g., amylose, protein, and ash content), gelatinization, retrogradation, and pasting properties. The branch chain length and chain length distribution of these A‐ and B‐type wheat starch granules were also determined using high‐performance anion exchange chromatography (HPAEC). Wheat starches with different granular sizes not only had different degrees of enzymatic hydrolysis and thermal and pasting properties, but also different molecular characteristics. Different amylose content, protein content, and branch chain length of amylopectin in A‐ and B‐type wheat starch granules could also be the major factors besides granular size for different digestibility and other functional properties of starch. The data indicate that different wheat cultivars with different proportion of A‐ and B‐type granular starch could result in different digestibility in wheat products.
Influences of Baking and Thawing Conditions on Quality of Par‐Baked French Bread
Authors: Park Chul Soo , Baik Byung‐Kee
Published: June 2007

We examined the effects of baking time and temperature for the preparation of par‐baked French bread, and of thawing and second baking conditions on the characteristics of bread prepared from par‐baked bread. Par‐baked French bread with loaf volume and crumb structure comparable to fully baked bread (control) was obtained with ≥6 min baking at 218°C, which increased the crumb temperature to 97°C. Freezing, thawing, and second baking of par‐baked bread decreased loaf volume by ≥100 mL. The second baking time of par‐baked bread, which was adjusted to have the bread crumb subjected to 97°C for 14 min based on the crumb temperature profile, produced a darker crust of bread compared with the control. The par‐baked bread with 6 min of initial baking at 218°C and frozen at ‐30°C required 12 min of second baking after thawing for 180 min to ≈20°C to produce crust color, crumb moisture, and firmness comparable to that of the control. When thawing time of par‐baked bread was shortened from 180 to 0 min, the second baking time required to yield crust color similar to the control increased from 12 to 16 min. The crumb moisture content was higher in bread baked for 16 min without thawing par‐baked bread than those baked after thawing for 45 or 180 min. Lowering the initial baking temperature of par‐baked bread from 246 to 163°C with the adjustment of baking time from 4 to 12 min decreased crumb firmness of the re‐baked (218°C, 16 min) bread from 2.5 to 1.5 N at 2 hr after baking and from 9.8–10.3 to 6.2–6.3 N at 48 hr.
Correlation Between NIR Spectra and RVA Parameters During Germination of Maize
Authors: Juhász Réka , Gergely Szilveszter , Szabóki Árpád , Salgó András
Published: June 2007

The physical, chemical, and morphological changes of maize seeds during germination were investigated using near‐infrared spectroscopy (NIR) and a method based on the Rapid Visco Analyser (RVA). Near‐infrared spectra provide information about both chemical and physical changes that occur in maize seed. The RVA curves make it possible to follow the process of germination. Four RVA parameters (peak viscosity, final viscosity, trough, and setback) were linearly correlated with germination time (R = 0.64–0.96), while the first derivatives of RVA curves contain specific information about starch structure. Water‐soluble protein (WSP) content of germinated maize seeds was measured using a flow injection analyser; this technique proved to be suitable for monitoring germination by following the mobilization of proteins. WSP and RVA parameters were highly correlated (R2 = 0.82–0.95) with predicted values calculated from NIR spectra of dry samples. Strong intercorrelations existed between NIR spectra and viscosity data from the beginning of the swelling and gelatinization process. The NIR and RVA methods and WSP measurements are sensitive tools for investigating the physiological status of maize seeds during germination. Detecting early phase of germination and predicting functional properties rapidly and nondestructively may enhance the importance of NIR spectroscopic methods in agricultural quality control.
Extraction of Antioxidants from Wheat Bran Using Conventional Solvent and Microwave‐Assisted Methods
Authors: Oufnac David S. , Xu Zhimin , Sun Ting , Sabliov Cristina , Prinyawiwatkul Witoon , Godber J. Samuel
Published: June 2007

Total phenolic and tocopherol contents and free radical scavenging capability of wheat bran extracted using conventional and microwave‐assisted solvent extraction methods were studied. Three different solvents (methanol, acetone, and hexane) were used in the conventional solvent extraction. Methanol was the most effective solvent, producing higher extraction yield (4.86%), total phenolic compound content (241.3 μg of catechin equivalent/g of wheat bran), and free radical scavenging capability (0.042 μmol of trolox equivalent/g of wheat bran) than either acetone or hexane. However, there was no significant difference in the total tocopherol contents (13.6–14.8 μg/g of wheat bran) among the three different solvent extraction methods. Microwave‐assisted solvent extraction using methanol significantly increased the total phenolic compound content to 467.5 and 489.5 μg of catechin equivalent; total tocopherol content to 18.7 and 19.5 μg; and free radical scavenging capability to 0.064 and 0.072 μmol of trolox equivalent/g of wheat bran at extraction temperatures of 100 and 120°C, respectively. However, extraction yields of conventional methanol solvent and microwave‐assisted methanol extractions at different temperatures were not significantly different.
Polyphenolics and Antioxidant Capacity of White and Blue Corns Processed into Tortillas and Chips
Authors: Pozo‐Insfran David Del , Serna Saldivar Sergio O. , Brenes Carmen H. , Talcott Stephen T.
Published: June 2007

White and blue corns of Mexican and American origins were lime‐cooked to obtain nixtamals with optimal moisture (48–50%) for tortillas and chips. Blue kernels had less bulk density, softer endosperm and, consequently, required less cooking time than the white kernels. The optimum cooking regime for the white kernels was 100°C for 20 min, while the optimum for both pigmented genotypes was 90°C for 0 min (until the lime‐cooking solution reached 90°C). Doughs, tortillas, and chips were characterized by total soluble phenolics (TSP), anthocyanins (ACN), and antioxidant capacity (AOX). A dough acidification procedure using fumaric acid (pH 5.2) was assessed as a means to improve TSP, ACN, and AOX retention. The Mexican blue corn had higher AOX (16%) than the American blue genotype, although the latter had a threefold higher TSP content (12.1 g/kg, dwb). Mexican and American blue corns had higher AOX capacity (29.6 and 25.6 μM trolox equivalents [TE]/g dwb), respectively, than the white corn (17.4 μM TE/g). White corns did not have detectable amounts of ACN, while blue Mexican and American kernels contained 342 and 261 mg/kg. Lime cooking had the greatest negative impact on the stability of TSP, ACN, and AOX. However, the acidification reduced ACN, TSP, and AOX losses by 8–23, 3–14, and 4–15%, respectively. Similar ACN losses were observed for both types of blue kernels when processed into nixtamal/dough (47%); however, ACN losses in tortillas and chips manufactured from the American blue genotype were higher (63 and 81%, respectively) than those of Mexican blue corn products (54 and 75%). ACN losses were highly correlated to TSP (r = 0.91) and AOX capacity losses (r = 0.94).
A Gas Chromatography Procedure for Determining Milled Rice Surface Lipid Content
Authors: Bergman C. J. , Goffman F. D.
Published: June 2007

Rice (Oryza sativa, L.) degree of milling (DM) is a quantification of the amount of bran that has been removed from kernels during the milling process. Historically it has been determined using a time‐consuming continuous solvent extraction (CSE) procedure to measure the surface lipid content. The objective of this research was to develop a gas chromatography (GC) method for rice surface lipids. The GC procedure was highly correlated with several other methods for DM including a commonly used CSE procedure and it demonstrated repeatability within acceptable analytical limits. Other aspects in support of the utility of this procedure are that it requires a relatively small amount of sample, organic solvent, and technician time. Consequently, this GC method for rice surface lipids measurement is suitable for use in determining rice DM in cultivar development programs and studies that require the analysis of a large number of samples.
Effect of Solvent and Temperature on Secondary and Tertiary Structure of Zein by Circular Dichroism
Authors: Selling Gordon W. , Hamaker Sharon A. H. , Sessa David J.
Published: June 2007

Circular dichroism studies were performed on zein to determine how the secondary and tertiary structure changes with different solvents, temperatures, or pH. Alcoholic solvent type and common denaturants such as SDS and low amounts of urea had little effect on the secondary structure of zein. Utilization of dimethylformamide or acetic acid as solvent gave changes in tertiary structure. Solutions of zein in 8M urea produced solutions with large changes in tertiary structure. The dissolution of zein in 50 mM sodium hydroxide produces a zein with large changes in secondary and tertiary structure and little loss in primary structure. Increasing the temperature of zein to 70°C in 80% ethanol‐water gave reversible changes in the primary structure (20% reduction in absolute magnitude of [θ]λ at 208 and 222 nm) and tertiary structure (40% reduction in absolute magnitude of [θ]λ at 268 nm).
Distribution of Protein Composition in Bread Wheat Flour Mill Streams and Relationship to Breadmaking Quality
Authors: Wang Y. G. , Khan K. , Hareland G. , Nygard G.
Published: June 2007

Wheat protein quantity and composition are important parameters for wheat baking quality. The objective of this study was to use fractionation techniques to separate the proteins of flour mill streams into various protein fractions, to examine the distribution of these protein fractions, and to establish a relationship between protein composition and breadmaking quality. Nine break streams, nine reduction streams, and three patent flours obtained from three samples of Nekota (a hard red winter wheat) were used in this study. A solution of 0.3M NaI + 7.5% 1‐propanol was used to separate flour protein into monomeric and polymeric proteins. The protein fractions, including gliadin, albumin+globulin, HMW‐GS, and LMW‐GS, were precipitated with 0.1M NH4Ac‐MeOH or acetone. The fractions were statistically analyzed for their distribution in the mill streams. The quantities of total flour protein and protein fractions in flour were significantly different among mill streams. The ratio of polymeric to monomeric proteins in break streams was significantly greater than in the reduction streams. The relationship between protein composition and breadmaking quality showed that the quantities of total flour protein, albumin+ globulin, HMW‐GS, and LMW‐GS in flour were significantly and positively correlated with loaf volume. The ratio of HMW‐GS to LMW‐GS had little association with loaf volume. The gliadin content in total flour protein was negatively and significantly correlated with loaf volume. These results indicated that the quantity and composition of protein among the mill streams was different, and this resulted in differences in breadmaking quality.
Release of Bound Lipids in Cereal Starches Upon Hydrolysis by Glucoamylase
Authors: Kitahara Kanefumi , Tanaka Takako , Suganuma Toshihiko , Nagahama Tomonori
Published: June 2007

The raw starch granules from corn, rice, and wheat were hydrolyzed by practically pure glucoamylase (Rhizopus niveus). The bound lipids remaining in the residual starches were investigated, of which the major components of the lipids, free fatty acids (FFA) in corn starch, FFA and phospholipids (PL) in rice starch, and PL in wheat starch were determined. In each case, the bound FFA and PL were decreased to some extent during the initial stage of hydrolysis. During the later stages, the FFA continued to gradually decrease, while the level of PL stabilized. It was interesting that some of the bound lipids were released from the granules upon glucoamylase hydrolysis, differing from the model amylose‐lipid complexes. Furthermore, the structures of the residual starches were investigated. The blue value and λmax of the starches were increased by partial hydrolysis of the starch granules using practically pure glucoamylase. Two gel‐permeation chromatography analyses revealed that the relative amount of amylose fraction was increased by glucoamylase hydrolysis, and also that the increments were reduced by the defatting of bound lipids. The results suggest that the increase in amylose fraction is attributable to the existence of bound lipids in the granules.
Content and Composition of Nonstarchy Polysaccharides in Endosperms of Sorghum Varying in Hardness During Four Developmental Stages
Authors: Kavitha R. , Chandrashekar A.
Published: June 2007

Estimates of nonstarchy polysaccharide (NSP) contents and compositions are reported for flours from three sorghum cultivars varying in hardness at four developmental stages. Samples were collected at 21, 28, 35, and 42 days after anthesis (DAA),. The total NSP content in flour appeared to increase slightly from 21 to 35 DAA and then level off or decrease slightly for all three cultivars. Gas liquid chromatography analysis of the water‐insoluble NSP fraction revealed that the pentose content decreased and hexose content increased as the grain matured. The soft and intermediate cultivars contained higher contents of NSP than did the hard cultivar at all the four stages of development studied. Also, the pentose content was higher than the hexose content in the water‐insoluble NSP fraction of soft sorghum endosperm when compared to the hard sorghum endosperm.