bluuebunny/crossref_metadata_2025 huggingface dataset:
A Review on Friction Stir Welding/Processing: Numerical Modeling
Authors: Akbari Mostafa , Asadi Parviz , Sadowski Tomasz
Published: August 2023

Friction stir welding (FSW) is a manufacturing process that many industries have adopted to join metals in a solid state, resulting in unique properties. However, studying aspects like temperature distribution, stress distribution, and material flow experimentally is challenging due to severe plastic deformation in the weld zone. Therefore, numerical methods are utilized to investigate these parameters and gain a better understanding of the FSW process. Numerical models are employed to simulate material flow, temperature distribution, and stress state during welding. This allows for the identification of potential defect-prone zones. This paper presents a comprehensive review of research activities and advancements in numerical analysis techniques specifically designed for friction stir welding, with a focus on their applicability to component manufacturing. The paper begins by examining various types of numerical methods and modeling techniques used in FSW analysis, including finite element analysis, computational fluid dynamics, and other simulation approaches. The advantages and limitations of each method are discussed, providing insights into their suitability for FSW simulations. Furthermore, the paper delves into the crucial variables that play a significant role in the numerical modeling of the FSW process.
Changes in Areal Surface Textures Due to Ball Burnishing
Authors: Swirad Slawomir
Published: August 2023

The description of the areal texture of the surface is more comprehensive than that of roughness profiles. Ball burnishing led to an improvement in surface quality. In this work, the changes in areal surface textures due to ball burnishing were studied. Three surfaces of steel, two after milling and one after grinding, were subjected to ball burnishing. In the burnishing process, the burnishing pressure and width were variable parameters. Surface topographies before and after burnishing were measured using a white light interferometer. Ball burnishing was found to lead to a decrease in surface amplitude. The highest relative reduction was 94%. The changes in roughness height were greater with a higher amplitude of the surface texture before burnishing. The hybrid parameters also decreased as a result of ball burnishing. The characteristics of changes in spatial parameters mainly depended on the surface texture before burnishing.
Development of a Resilience Parameter for 3D-Printable Shape Memory Polymer Blends
Authors: Cavender-Word Truman J. , Roberson David A.
Published: August 2023

The goal of this paper was to establish a metric, which we refer to as the resilience parameter, to evaluate the ability of a material to retain tensile strength after damage recovery for shape memory polymer (SMP) systems. In this work, three SMP blends created for the additive manufacturing process of fused filament fabrication (FFF) were characterized. The three polymer systems examined in this study were 50/50 by weight binary blends of the following constituents: (1) polylactic acid (PLA) and maleated styrene-ethylene-butylene-styrene (SEBS-g-MA); (2) acrylonitrile butadiene styrene (ABS) and SEBS-g-MA); and (3) PLA and thermoplastic polyurethane (TPU). The blends were melt compounded and specimens were fabricated by way of FFF and injection molding (IM). The effect of shape memory recovery from varying amounts of initial tensile deformation on the mechanical properties of each blend, in both additively manufactured and injection molded forms, was characterized in terms of the change in tensile strength vs. the amount of deformation the specimens recovered from. The findings of this research indicated a sensitivity to manufacturing method for the PLA/TPU blend, which showed an increase in strength with increasing deformation recovery for the injection molded samples, which indicates this blend had excellent resilience. The ABS/SEBS blend showed no change in strength with the amount of deformation recovery, indicating that this blend had good resilience. The PLA/SEBS showed a decrease in strength with an increasing amount of initial deformation, indicating that this blend had poor resilience. The premise behind the development of this parameter is to promote and aid the notion that increased use of shape memory and self-healing polymers could be a strategy for mitigating plastic waste in the environment.
Fast-Setting Concrete for Repairing Cement Concrete Pavement
Authors: Rudnicki Tomasz , Stałowski Przemysław
Published: August 2023

The paper presents the results of laboratory tests and the complete results of the implementation of the Sprint fast-setting concrete technology used during the reinstallation of the concrete pavement of the DK50 road (the Młodzieszyn bypass). The problem of concrete pavement repair is related to economic and social costs and, above all, to long repair time. After an extensive analysis of various technologies, the authors created a dedicated solution, which, based on commonly existing materials, allows for a very quick repair of the existing pavement. The obtained properties of the fast-setting concrete allow the maintenance of rheological parameters for 2 h from its production and to install the mixture of the consistency of class S3/S4, while the obtained compressive strength exceeds 25 MPa within 6 h of installation. The concrete parameters obtained after 24 h show a strength exceeding 40 MPa, and after 28 days—exceeding 60 MPa. The tensile strength at shattering exceeds 5 MPa, while the tensile strength at flexural strength exceeds 7 MPa. In addition, all parameters of the fast-setting concrete meet the highest requirements currently set for newly built concrete pavement loaded by very heavy traffic. The most important parameter is the possibility to shorten the repair time of concrete pavement to one day, significantly reducing the social costs associated with closing a single lane or the entire road. An important element of the presented technology is the possibility of producing the mixture at a stationary concrete batching plant, and in the future—with the use of bags for patching potholes in road pavement.
Wave Propagation in the Viscoelastic Functionally Graded Cylindrical Shell Based on the First-Order Shear Deformation Theory
Authors: Zhou Yunying , Liu Dongying , Hou Dinggui , Liu Jiahuan , Li Xiaoliang , Yue Zhijie
Published: August 2023

Based on the first-order shear deformation theory (FSDT) and Kelvin–Voigt viscoelastic model, one derives a wave equation of longitudinal guide waves in viscoelastic orthotropic cylindrical shells, which analytically solves the wave equation and explains the intrinsic meaning of the wave propagation. In the numerical examples, the velocity curves of the first few modes for the elastic cylindrical shell are first calculated, and the results of the available literature are compared to verify the derivation and programming. Furthermore, the phase velocity curves and attenuation coefficient curves of the guide waves for a functionally graded (FG) shell are calculated, and the effects of viscoelastic parameters, material gradient patterns, material volume fractions, and size ratios on the phase velocity curves and attenuation curves are studied. This study can be widely used to analytically model the wave propagating in inhomogeneous viscoelastic composite structures and present a theoretical basis for the excellent service performance of composite structures and ultrasonic devices.
Research on Optical Fiber Ring Resonator Q Value and Coupling Efficiency Optimization
Authors: Li Shengkun , Tian Xiaowen , Tian Sining
Published: August 2023

The coupling efficiency of the fiber ring resonator has an important influence on the scale factor of the resonant fiber gyroscope. In order to improve the scale factor of the gyroscope, the coupling efficiency of the fiber ring resonator and its influential factors on the scale factor of the gyroscope are analyzed and tested. The results show that the coupling efficiency is affected by both the splitting ratio of the coupler and the loss in the cavity. When the coupling efficiency approaches 0.75 at the under-coupling state, the scaling factor of the gyroscope is the highest. This provides a theoretical reference and an experimental basis for the enhancement of the scaling factor of the resonant fiber gyroscope with the fiber ring resonator as the sensitive unit, providing options for multiple applications such as sea, land, sky and space.
Zirconia-Toughened Alumina (ZTA) Nanoceramics with a Gradient Microstructure: A Comparative Study of ZTA Ceramics with Fibrous and Granular Morphology
Authors: Bódis Eszter , Károly Zoltán
Published: August 2023

ZrO2-toughened Al2O3 (ZTA) ceramic composites with a porosity gradient and with improved mechanical properties have a wide range of possible applications. We fabricated nanofibrous and nanogranular Y-ZTA and Ce-ZTA composites with a gradient microstructure by creating a temperature gradient during SPS sintering, with the use of asymmetric graphite tool arrangement (ASY). In this study, we examined the morphology effect of the starting materials on the sintering process and on the final microstructure, as well as the mechanical properties of the composites. A large temperature difference was established for both the granular and fibrous samples fabricated in the ASY configuration, which resulted in gradient porosity along the ceramics bodies: the upper part of the ceramics showed a highly porous fine microstructure, while the opposite side was highly densified. The final microstructure of the composites can be tailored by varying the morphology of the starting ceramics or the graphite configuration. A highly porous skeleton-like structure was formed by sintering fibres in the ASY configuration, whereas the granular precursors resulted in a much less porous composite. The microstructure affected the mechanical properties of the composite. Improved hardness and more than 50% higher compression strength were obtained for the granular Ce-ZTA samples as compared to the fibrous sample. Gradient porosity with fibrous or granular morphology promotes the penetration of bioactive nanosized hydroxyapatite (HAp) into the pore structure. Fibrous ZTA absorbs HAp more effectively due to its higher porosity as well as its bimodal pore structure.
Preparation of Reactive Indicator Papers Based on Silver-Containing Nanocomposites for the Analysis of Chloride Ions
Authors: Gorbunova Marina O. , Uflyand Igor E. , Zhinzhilo Vladimir A. , Zarubina Anastasiya O. , Kolesnikova Tatiana S. , Spirin Maxim G. , Dzhardimalieva Gulzhian I.
Published: August 2023

In recent decades, metal-containing nanocomposites have attracted considerable attention from researchers. In this work, for the first time, a detailed analysis of the preparation of reactive indicator papers (RIPs) based on silver-containing nanocomposites derived from silver fumarate was carried out. Thermolysis products are silver-containing nanocomposites containing silver nanoparticles uniformly distributed in a stabilizing carbon matrix. The study of the optical properties of silver-containing nanocomposites made it possible to outline the prospects for their application in chemical analysis. RIPs were made by impregnating a cellulose carrier with synthesized silver fumarate-derived nanocomposites, which change their color when interacting with chlorine vapor. This made it possible to propose a method for the determination of chloride ions with preliminary oxidation to molecular chlorine, which is then separated from the solution by gas extraction. The subsequent detection of the active zone of RIPs using colorimetry makes it possible to identify mathematical dependences of color coordinates on the concentration of chloride ions. The red (R) color coordinate in the RGB (red-green-blue) system was chosen as the most sensitive and promising analytical signal. Calibration plots of exponential and linear form and their equations are presented. The limit of detection is 0.036 mg/L, the limits of quantification are 0.15–2.4 mg/L, and the time of a single determination is 25 min. The prospects of the developed technique have been successfully shown in the example of the analysis of the natural waters of the Don River, pharmaceuticals, and food products.
Simulation and Optimization of Hemispherical Resonator’s Equivalent Bottom Angle for Frequency-Splitting Suppression
Authors: Gao Zhiyong , Wang Shang , Wang Zhi , Ding Xukai
Published: August 2023

As an inertial sensor with excellent performance, the hemispherical resonator gyro is widely used in aerospace, weapon navigation and other fields due to its advantages of high precision, high reliability, and long life. Due to the uneven distributions of material properties and mass of the resonator in the circumferential direction, the frequencies of the two 4-antinodes vibration modes (operational mode) of resonator in different directions are different, which is called frequency splitting. Frequency splitting is the main error source affecting the accuracy of the hemispherical resonator gyro and must be suppressed. The frequency splitting is related to the structure of the resonator. For the planar-electrode-type hemispherical resonator gyro, in order to suppress the frequency splitting from the structure, improve the accuracy of the hemispherical resonator gyro, and determine and optimize the equivalent bottom angle parameters of the hemispherical resonator, this paper starts from the thin shell theory, and the 4-antinodes vibration mode and waveform precession model of the hemispherical resonator are researched. The effect of the equivalent bottom angle on the 4-antinodes vibration mode frequency value under different boundary conditions is theoretically analyzed and simulated. The simulation results show that the equivalent bottom angle affects the 4-antinodes vibration mode of the hemispherical resonator through radial constraints. The hemispherical resonator with mid-surface radius R=15 mm and shell thickness h=1 mm is the optimization object, and the stem diameter D and fillet radius R1 are experimental factors, with the 4-antinodes vibration mode frequency value and mass sensitivity factor as the response indexes. The central composite design is carried out to optimize the equivalent bottom angle parameters. The optimized structural parameters are: stem diameter D=7 mm, fillet radii R1=1 mm, R2=0.8 mm. The simulation results show that the 4-antinodes vibration mode frequency value is 5441.761 Hz, and the mass sensitivity factor is 3.91 Hz/mg, which meets the working and excitation requirements wonderfully. This research will provide guidance and reference for improving the accuracy of the hemispherical resonator gyro.
A Fully Integrated RFID Reader SoC
Authors: Hu Jian-Guo , Mei Wen-Zhuo , Wu Jin , Li Jia-Wei , Wang De-Ming
Published: August 2023

The traditional RFID reader module relies on a discrete original design. This design integrates a microcontroller, high-frequency RFID reader IC and other multiple chips onto a PCB board, leading to bottlenecks in cost, power consumption, stability and reliability. To align with the trend towards high integration, miniaturization and low power consumption in RFID reader, this paper introduces a fully integrated RFID Reader SoC. The SoC employs the open-source Cortex-M0 core to integrate the RF transceiver, analog circuits, baseband protocol processing, memory and interface circuits into one chip. It’s compatible with ISO/IEC 14443 A-type and B-type and ISO/IEC 15693 transmission protocols and rates. Manufactured using a 0.18 μm process, the chip is compatible with multiple standards. The optimized design of the digital baseband control circuit results in a chip area of only 11.95 mm2 offering clear advantages in both area and integration compared to similar work.
Polyphenols’ Impact on Selected Biomarkers of Brain Aging in Healthy Middle-Aged and Elderly Subjects: A Review of Clinical Trials
Authors: Ziegler Tobias , Tsiountsioura Melina , Meixner-Goetz Lisa , Cvirn Gerhard , Lamprecht Manfred
Published: August 2023

With a constantly growing elderly population, incidences of neurodegenerative diseases are also rising and are expected to further increase over the next years, while costing health systems across the world trillions of dollars. Therefore, biomarkers to detect manifestations of brain aging early and interventions to slow down its pace are of great interest. In the last years, the importance of the neurotrophins brain-derived neurotrophic factor (BDNF) and nerve growth factor (NGF) in the context of cognitive function and the aging brain has increased, besides the already well-established amyloid-beta (Aβ) and tau plaques. Due to their wide range of beneficial health effects as well as their antioxidant and anti-inflammatory properties, a class of secondary plant-metabolites, the so-called polyphenols, gained increasing attention. In this review, we discuss the roles of BDNF, Aβ, NGF, and tau proteins as biomarkers of brain aging and the effect of dietary polyphenol interventions on these biomarkers, assessed via blood analysis, magnetic resonance imaging (MRI), and positron emission tomography (PET).
Severity of Clinical Mastitis and Bacterial Shedding
Authors: Krebs Isabel , Zhang Yanchao , Wente Nicole , Leimbach Stefanie , Krömker Volker
Published: August 2023

The aim of this cross-sectional study was to investigate associated factors of the severity of clinical mastitis (CM). Milk samples of 249 cases of CM were microbiologically examined, of which 27.2% were mild, 38.5% moderate, and 34.3% severe mastitis. The samples were incubated aerobically and anaerobically to investigate the role of aerobic and anaerobic microorganisms. In addition, the pathogen shedding was quantitatively examined, and animal individual data, outside temperature and relative humidity, were collected to determine associated factors for the severity of CM. The pathogen isolated the most was Escherichia coli (35.2%), followed by Streptococcus spp. (16.4%). Non-aureus staphylococci (NaS) (15.4%) and other pathogens (e.g., Staphylococcus aureus, coryneforms) (15.4%) were the pathogens that were isolated the most for mild mastitis. Moderate mastitis was mostly caused by E. coli (38%). E. coli was also the most common pathogen in severe mastitis (50.6%), followed by Streptococcus spp. (16.4%), and Klebsiella spp. (10.3%). Obligate anaerobes (Clostridium spp.) were isolated in one case (0.4%) of moderate mastitis. The mortality rate (deceased or culled due to the mastitis in the following two weeks) was 34.5% for severe mastitis, 21.7% for moderate mastitis, and 4.4% for mild mastitis. The overall mortality rate of CM was 21.1%. The pathogen shedding (back logarithmized) was highest for severe mastitis (55,000 cfu/mL) and E. coli (91,200 cfu/mL). High pathogen shedding, low previous somatic cell count (SCC) before mastitis, high outside temperature, and high humidity were associated with severe courses of mastitis.
Therapeutic Outcomes of High Dose-Dexamethasone versus Prednisolone + Azathioprine, Rituximab, Eltrombopag, and Romiplostim Strategies in Persistent, Chronic, Refractory, and Relapsed Immune Thrombocytopenia Patients
Authors: Hamed Eman Mostafa , Ibrahim Ahmed R. N. , Meabed Mohamed Hussein , Khalaf Ahmed M. , El Demerdash Doaa Mohamed , Elgendy Marwa O. , Saeed Haitham , Salem Heba F. , Rabea Hoda
Published: August 2023

Background: Primary immune thrombocytopenia (ITP) is an inflammatory autoimmune disease that can be managed with several treatment options. However, there is a lack of comparative data on the efficacy of these options in different phases of the disease. Aim of the study: This study aimed to evaluate the efficacy of high-dose Dexamethasone (HD-DXM), Prednisolone + Azathioprine, Rituximab, Eltrombopag, and Romiplostim schedules in persistent, chronic refractory or relapsed Egyptian ITP patients with a platelet count ≤30 × 109/L. The primary outcome measure was a sustained increase in platelet counts over 50 × 109/L for an additional 12 months without additional ITP regimens. The study also aimed to identify a suitable treatment regimen with a long remission duration for each phase of ITP. Results: Prednisolone + Azathioprine was significantly more effective in achieving an overall response in persistent patients than Romiplostim, high-dose Dexamethasone, and Rituximab. (90.9% vs. 66.6, [Odds ratio, OR: 5; confidence interval, CI 95% (0.866–28.86)], 45%, [OR: 0.082, CI 95% (0.015–0.448)] and, 25%, [OR: 30, CI 95% (4.24–211.8)], respectively, p-value < 0.01). Eltrombopag was significantly more effective in achieving a durable response in refractory ITP than HD-DXM, Rituximab, and Prednisolone; (80% compared to 32.2% [OR: 0.119, CI 95% (0.035–0.410)], 22.2% [OR:0.071, CI 95% (0.011–0.455)], and 18.1% [OR: 0.056, CI 95% (0.009–0.342)], respectively, p-value < 0.01). Conclusions: Finally, Eltrombopag following HD-DXM showed the highest percentage of patients with complete treatment-free survival times of at least 330 days. These findings could help clinicians choose the most appropriate treatment for their patients with ITP based on the phase of the disease. This trial is registered in clinicaltrials.gov with registration number NCT05861297.
Surface-Modified Carboxylated Cellulose Nanofiber Hydrogels for Prolonged Release of Polyhexamethylene Biguanide Hydrochloride (PHMB) for Antimicrobial Applications
Authors: O-chongpian Pichapar , Chaiwarit Tanpong , Jantanasakulwong Kittisak , Rachtanapun Pornchai , Worajittiphon Patnarin , Kantrong Nutthapong , Jantrawut Pensak
Published: August 2023

The surface modification of cellulose nanofibers (CNFs) using a 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO)/sodium bromide (NaBr)/sodium hypochlorite (NaClO) system was successful in improving their hydrophilicity. Following that, we fabricated hydrogels containing carboxylated cellulose nanofibers (c-CNFs) and loaded them with polyhexamethylene biguanide (PHMB) using a physical crosslinking method, aiming for efficient antimicrobial uses. The morphological and physicochemical properties of all hydrogel formulations were characterized, and the results revealed that the 7% c-CNFs-2 h loaded with PHMB formulation exhibited desirable characteristics such as regular shape, high porosity, good mechanical properties, suitable gel content, and a good maximum swelling degree. The successful integration of PHMB into the c-CNF matrix was confirmed by FTIR analysis. Furthermore, the 7% c-CNFs-2 h loaded with the PHMB formulation demonstrated PHMB contents exceeding 80% and exhibited a prolonged drug release pattern for up to 3 days. Moreover, this formulation displayed antibacterial activity against S. aureus and P. aeruginosa. In conclusion, the novel approach of c-CNF hydrogels loaded with PHMB through physical crosslinking shows promise as a potential system for prolonged drug release in topical drug delivery while also exhibiting excellent antibacterial activity.
Preparation and Performance of H-PDMS/PMHS/OTS Hybrid Nanosilica Hydrophobic and Self-Cleaning Coatings on Phosphogypsum Surface
Authors: Yang Guang , Chen Zhonghua , Lv Changwei , Deng Lei , Luo Xiaofeng , Li Yi , He Songtao , Liu Qibin
Published: August 2023

Hemihydrate phosphogypsum, an industrial solid waste product of phosphoric acid production, is abundant and inexpensive. If the problem of poor water resistance is solved, this material could be substituted for cement and other traditional energy-consuming cementitious materials in the construction industry. This approach would confer important economic and environmental benefits while promoting the resource utilization of phosphogypsum (PG). In this study, hydrophobic and self-cleaning coatings of H-PDMS/PMHS/OTS hybrid nanosilica were prepared on a post-hydroxylated PG surface using sol–gel and impregnation methods. The water contact angle, Fourier-transform infrared spectroscopy, Three-dimensional surface morphology and roughness analysis, X-ray photoelectron spectroscopy, scanning electron microscopy, surface abrasion tests, and tape adhesion tests were used to evaluate the hydrophobicity of the coatings. The results demonstrated that the in situ reaction produced a hydrophobic siloxane/nanosilica hybrid network that bonded to the PG surface via hydrogen bonding, making the otherwise completely hydrophilic PG hydrophobic (PGH-3, contact angle (CA) = 144.1°). The PGH-3 sample exhibited excellent chemical stability, maintaining a contact angle greater than 135° under strongly acidic or alkaline conditions. The contact angle remained at 123.7° after 50 tape-bonding tests. After 100 wear cycles, the contact angle remained at 121.9°. This study presents an environmentally friendly method and a straightforward application procedure to impart hydrophobicity to solid waste PG. Its potential is thus demonstrated in the field of PG-based construction materials and the comprehensive utilization of solid waste.
Fabrication of Tri-Directional Poly(2,5-benzimidazole) Membrane Using Direct Casting for Vanadium Redox Flow Battery
Authors: Jang Jung-Kyu , Kim Tae-Ho
Published: August 2023

In vanadium redox flow batteries (VRFBs), simultaneously achieving high proton conductivity, low vanadium-ion permeability, and outstanding chemical stability using electrolyte membranes is a significant challenge. In this study, we report the fabrication of a tri-directional poly(2,5-benzimidazole) (T-ABPBI) membrane using a direct casting method. The direct-cast T-ABPBI (D-T-ABPBI) membrane was fabricated by modifying the microstructure of the membrane while retaining the chemical structure of ABPBI, having outstanding chemical stability. The D-T-ABPBI membrane exhibited lower crystallinity and an expanded free volume compared to the general solvent-cast T-ABPBI (S-T-ABPBI) membrane, resulting in enhanced hydrophilic absorption capabilities. Compared to the S-T-ABPBI membrane, the enhanced hydrophilic absorption capability of the D-T-ABPBI membrane resulted in a decrease in the specific resistance (the area-specific resistance of S-T-ABPBI and D-T-ABPBI membrane is 1.75 and 0.98 Ωcm2, respectively). Additionally, the D-T-ABPBI membrane showed lower vanadium permeability (3.40 × 10−7 cm2 min−1) compared to that of Nafion 115 (5.20 × 10−7 cm2 min−1) due to the Donnan exclusion effect. Owing to the synergistic effects of these properties, the VRFB assembled with D-T-ABPBI membrane had higher or equivalent coulomb efficiencies (>97%) and energy efficiencies (70–91%) than Nafion 115 at various current densities (200–40 mA cm−2). Furthermore, the D-T-ABPBI membrane exhibited stable performance for over 300 cycles at 100 mA cm−2, suggesting its outstanding chemical stability against the highly oxidizing VO2+ ions during practical VRFB operation. These results indicate that the newly fabricated D-T-ABPBI membranes are promising candidates for VRFB application.
Effects of Additives on the Mechanical and Fire Resistance Properties of Pultruded Composites
Authors: Romanovskaia Natalia , Minchenkov Kirill , Gusev Sergey , Klimova-Korsmik Olga , Safonov Alexander
Published: August 2023

Under high temperatures, fiber-reinforced polymers are destroyed, releasing heat, smoke, and harmful volatile substances. Therefore, composite structural elements must have sufficient fire resistance to meet the requirements established by building codes and regulations. Fire resistance of composite materials can be improved by using mineral fillers as flame-retardant additives in resin compositions. This article analyzes the effect of fire-retardant additives on mechanical properties and fire behavior of pultruded composite profiles. Five resin mixtures based on vinyl ester epoxy and on brominated vinyl ester epoxy modified with alumina trihydrate and triphenyl phosphate were prepared for pultrusion of strip profiles of 150 mm × 3.5 mm. A series of tests have been conducted to determine mechanical properties (tensile, flexural, compression, and interlaminar shear) and fire behavior (ignitability, flammability, combustibility, toxicity, smoke generation, and flame spread) of composites. It was found that additives impair mechanical properties of materials, as they the take place of reinforcing fibers and reduce the volume fraction of reinforcing fibers. Profiles based on non-brominated vinyl ester epoxy have higher tensile, compressive, and flexural properties than those based on brominated vinyl ester epoxy by 7%, 30%, and 36%, respectively. Profiles based on non-brominated epoxy resin emit less smoke compared to those based on brominated epoxy resin. Brominated epoxy-based profiles have a flue gas temperature which is seven times lower compared to those based on the non-brominated epoxy. Mineral fillers retard the spread of flame over the composite material surface by as much as 4 times and reduce smoke generation by 30%.
Multi-Layer Fabric Composites Combined with Non-Newtonian Shear Thickening in Ballistic Protection—Hybrid Numerical Methods and Ballistic Tests
Authors: Roszak Maciej , Pyka Dariusz , Bocian Mirosław , Barsan Narcis , Dragašius Egidijus , Jamroziak Krzysztof
Published: August 2023

Multi-layer fabrics are commonly used in ballistics shields with a lower bulletproof class to protect against pistol and revolver bullets. In order to additionally limit the dynamic deflection of the samples, layers reinforced with additional materials, including non-Newtonian fluids compacted by shear, are additionally used. Performing a wide range of tests in each case can be very problematic; therefore, there are many calculation methods that allow, with better or worse results, mapping of the behavior of the material in the case of impact loads. The search for simplified methods is very important in order to simplify the complexity of numerical fabric models while maintaining the accuracy of the results obtained. In this article, multi-layer composites were tested. Two samples were included in the elements subjected to shelling. In the first sample, the outer layers consisted of aramid fabrics in a laminate with a thermoplastic polymer matrix. The middle layer contained a non-Newtonian shear-thickening fluid enclosed in hexagonal (honeycomb) cells. The fluid was produced using polypropylene glycol and colloidal silica powder with a diameter of 14 µm in the proportions of 60/40. The backing plate was made using a 12-layer composite made of Twaron® para-aramid fabrics with a DCPD matrix—not yet used in a wide range of ballistics. Then, numerical simulations were carried out in the Abaqus/Explicit dynamic analysis. The Johnson–Cook constitutive strength model was used to describe the behavior of elastic–plastic materials constituting the elements of the projectiles. For the non-Newtonian fluid, a Up-Us EOS was used. The inner layers of the fabric were treated as an orthotropic material. Complete homogenization of the sample layers was carried out, thanks to which each layer was treated as a homogeneous continuum. As a parameter of fracture mechanics for shield components, the strain criterion was used with the smooth particles hydrodynamics method (SPH). Then, the results of simulations were compared with the results of the ballistic test for both samples placed next to each other, which resulted in the formation of a multi-layer composite in one ballistic test subjected to impact loads during firing with a 9 × 19 mm Parabellum FMJ projectile with an initial velocity of 370 ± 10 m/s. The results of numerical tests are very similar to the ballistic tests, which indicates the correct mapping of the process and the correct conduct of layer homogenization. The applied proportions of the components in the non-Newtonian fluid allowed a reduction in the deflection compared to previous studies. Additionally, the proposal to use a DCPD matrix allowed to obtain a much lower deflection value compared to other materials, which is a novelty in the field of production of ballistic shields.
Preparation and Characterization of a One-Step Electrospun Poly(Lactic Acid)/Wormwood Oil Antibacterial Nanofiber Membrane
Authors: Tang Xiaoyan , Guo Xun , Duo Yongchao , Qian Xiaoming
Published: August 2023

With the continuous improvement of the standard of living, people are increasingly inclined towards natural, green, and environmentally friendly products. Plant-based products that are safe, natural, non-toxic, and beneficial to human health are often more favored. Poly(lactic acid) (PLA) is a polymer obtained through lactate polymerization using renewable plant resources such as corn and has excellent biocompatibility and biodegradability. It is widely used in the field of food packaging. Wormwood oil (WO) is an oil extracted from the stems and leaves of Artemisia plants, and it has broad-spectrum antibacterial properties. In this article, through electrospinning technology, wormwood oil was directly incorporated into PLA, giving the PLA nanofiber membrane antioxidant and antibacterial functions. Various parameters such as voltage (11 KV, 13 KV, 15 KV), spinning solution concentration (8%, 10%, 12%), distance (15 cm, 17 cm, 19 cm), and feeding rate (0.4 mL/h, 0.5 mL/h, 0.6 mL/h) were explored, and the resulting spun fibers were characterized. Through SEM characterization, it was found that when the spinning voltage was 13 KV, the spinning solution concentration was 10%, the distance was 17 cm, and the feeding rate was 0.5 mL/h, the nanofiber membrane had a smooth morphology without bead formation, with an average diameter of 260 nm. The nanofiber membrane was characterized using FTIR, TG, and SEM, confirming the successful incorporation of artemisia essential oil into PLA. The prepared antimicrobial nanofilm was subjected to antimicrobial testing, and the results showed that as the concentration of the essential oil increased, the inhibition zones also increased. When wormwood oil concentration was 4%, the diameter of the inhibition zone for Staphylococcus aureus increased from 1.0 mm to 3.5 mm, while the diameter of the inhibition zone for Escherichia coli increased from 2.0 mm to 4.5 mm.
A General Deep Learning Method for Computing Molecular Parameters of a Viscoelastic Constitutive Model by Solving an Inverse Problem
Authors: Ye Minghui , Fan Yuan-Qi , Yuan Xue-Feng
Published: August 2023

Prediction of molecular parameters and material functions from the macroscopic viscoelastic properties of complex fluids are of great significance for molecular and formulation design in fundamental research as well as various industrial applications. A general learning method for computing molecular parameters of a viscoelastic constitutive model by solving an inverse problem is proposed. The accuracy, convergence and robustness of a deep neural network (DNN)-based numerical solver have been validated by considering the Rolie-Poly model for modeling the linear and non-linear steady rheometric properties of entangled polymer solutions in a wide range of concentrations. The results show that as long as the DNN could be trained with a sufficiently high accuracy, the DNN-based numerical solver would rapidly converge to its solution in solving an inverse problem. The solution is robust against small white noise disturbances to the input stress data. However, if the input stress significantly deviates from the original stress, the DNN-based solver could readily converge to a different solution. Hence, the resolution of the numerical solver for inversely computing molecular parameters is demonstrated. Moreover, the molecular parameters computed by the DNN-based numerical solver not only reproduce accurately the steady viscoelastic stress of completely monodisperse linear lambda DNA solutions over a wide range of shear rates and various concentrations, but also predict a power law concentration scaling with a nearly same scaling exponent as those estimated from experimental results.
Recent Progress in Fill Media Technology for Wet Cooling Towers
Authors: Hashemi Zahra , Zamanifard Abdolmajid , Gholampour Maysam , Liaw Jane-Sunn , Wang Chi-Chuan
Published: August 2023

Cooling towers are extensively utilized in diverse industries for efficient heat dissipation. Fill media are a critical component, facilitating heat and mass exchange between water and air, impacting overall cooling tower efficiency. Given its vital importance, this study comprehensively reviews recent advancements in fill media technology, illuminating cooling tower technology progress and exploring the effects of different fill media configurations and materials on cooling tower performance. It should be noted that the majority of research is focused on the Range of 2.5 °C to 25 °C and Approach of 1 °C to 9 °C. Through comprehensive analysis and evaluation, the effects of various fill media on heat transfer efficiency, water cooling capacity, and energy consumption are intensively summarized. By understanding these effects, engineers and designers can make rational decisions to optimize cooling tower performance and ensure efficient heat dissipation. Notably, in some reported cases, new fill media enhanced cooling range, effectiveness, and the Merkel number by 28%, 85%, and 131%, respectively. Ultimately, this paper serves as a valuable resource for academics, researchers, and professionals in the field of cooling tower design and thermal management. The insights provided in this study can help industries achieve greater energy efficiency, sustainability, and overall operational excellence.
Extraction and Purification of Kiwifruit Seed Oil Using Three-Phase Partitioning: An Efficient and Value-Adding Method for Agro-Industrial Residue Utilization
Authors: Liu Bangfu , Li Xiufang , Liu Qingchun , Tan Zhijian
Published: August 2023

Kiwifruit seeds are usually discarded as waste in the kiwifruit processing industry. However, kiwifruit seeds are rich in oil, which implies their value as a potential resource. Therefore, three-phase partitioning (TPP) using ammonium sulfate and n-butanol has been developed to extract kiwifruit seed oil (KSO) from discarded kiwifruit seeds. The factors influencing the extraction process have been investigated. The highest extraction yield of 36.06% for KSO was obtained under the following conditions: an extraction time of 18 h, a liquid-solid ratio of 4:1, an amount of ammonium sulfate of 28.5 wt%, and a phase ratio (top phase/bottom phase) of 1/1. The composition of obtained KSO was analyzed by gas chromatography-mass spectrometry (GC-MS), and the results indicated the high content of α-linolenic acid. This simple and low-cost method can be used as an efficient approach for utilizing the value of kiwifruit seeds.
Determination of Ten Plant Growth Regulators in Bean Sprouts by Mixed Solid Phase Extraction Columns Separation and LC-MS/MS
Authors: Cai Chenggang , Yao Feng , Li Chuanpeng , Xiang Yannan , Wu Pinggu , Hu Zhengyan , Wang Junlin , Zhu Ruiyu
Published: August 2023

(1) Background: Plant growth regulators (PGRs) can accelerate growth or improve the quality and quantity of bean sprouts but are forbidden to use in bean sprout cultivation, as the sprouting process’s increased chemicals will disturb the PGRs analysis. This article aimed to increase the accuracy and level of sensitivity of the LC-MS/MS method for the simultaneous analysis of 10 PGRs after mixed solid phase extraction (SPE) purification. (2) Methods: An LC-MS/MS detection method for 10 kinds of PGRs was established based on ESI ionization in the positive ion mode for 6-furfurylaminopurine (6-KT), paclobutrazol (PBZ), indole-2-acetic acid (IAA), and indole-3-butyric acid (IBA) and in the negative ion mode for gibberellin A3 (GA3), 2,4-dichlorophenoxy acetic acid (2,4-D), 4-chlorophenoxyacetic acid (4-CPA), forchlorfenuron (FCF), thidiazuron (TDZ), and 6-benzyl adenine (6-BA). (3) Results: The 10 PGR compounds were detected within a concentration range of 1.0–50 ng/mL. The average recovery was 68.3–97.3% with relative standard deviations (RSD) of 4.6–15.2% (n = 6); the limit of detection (LOD) and limit of quantification (LOQ) were found to be 2 and 5 ng/g, respectively. PGRs were surveyed in 36 soybean sprouts and 33 mungbean sprouts; the results showed that 4-CPA and IAA were detected in 10 soybean sprouts and 10 mungbean sprouts, respectively. Five samples contained both 4-CPA and IAA. (4) Conclusions: The established method is simple, rapid, accurate, and highly sensitive for the detection of PGR residues in bean sprout products.
Design Method of Three-Component Optic Fiber Balance Based on Fabry–Perot Displacement Sensor
Authors: Xu Bin , Yu Shien , Zhang Jianzhong
Published: August 2023

This article proposes a new type of three-component optic fiber balance based on Fabry–Perot displacement measurement technology based on the structure of the pulse wind tunnel balance. This paper systematically introduces the force measurement principle and design process of a three-component optic fiber balance and conducts relevant simulation analysis and experimental verification. The simulation results show that the Fabry–Perot sensor can achieve significant sensitivity to cavity length changes, and when used in existing balance structures, sensitivity gains can be achieved by changing the probe height without the need to modify the original structure of the balance. Finally, the feasibility of the design method was verified through calibration experiments: the optic fiber balance has high sensitivity and good linearity compared to simulation sensitivity, the error is less than 6%, and the calibration accuracy of each component is better than 0.13%, which is better than the existing traditional strain balance (0.37%). The pulse wind tunnel force measurement test has a short test time and a large model mass, and the balance needs to have a large stiffness to meet the short-term force measurement requirements. The introduction of more sensitive optic fiber balance force measurement technology is expected to solve the contradiction between the stiffness and sensitivity of force measurement systems.
Effect of Smoke Caused by Fires on the Enzymatic Activity of Forest Soils in the North Caucasus (Russian Federation)
Authors: Nizhelskiy Mikhail Sergeevich , Kazeev Kamil Shagidullovich , Vilkova Valeria Valerievna , Fedorenko Anastasia Nikolaevna , Shkhapatsev Aslan Kaplanovich , Kolesnikov Sergey Iliych
Published: August 2023

Forest fires can have a significant impact on soils, resulting in changes in biological indicators. Due to fire, high temperatures, and intensive generation of smoke from burning materials of different origin, the activity of soil enzymes is decreased. In this study are presented the results of modelling experiments on the impact of smoke on forest soils (Cambisols according to the World Reference Base for Soil Resources rating) of the Republic of Adygea, Nickel settlement (Russia). The findings demonstrated significant smoke exposure on the enzymatic activity of this type of soil. A decrease in the activity of such enzymes as catalase, peroxidase, polyphenol oxidase, and invertase within 60 min after soil treatment with smoke from burning materials of plant origin (pine sawdust) was established. A significant decrease in the activity of catalase relative to the control by 36%, phenoloxidases by 54–58%, and invertase from the hydrolase class by 31% was found. The integral index of soil enzymatic activity (IIEA) of the studied soils was also calculated. In addition, one of the informative diagnostic indicators is the pH of the soil suspension. The pH value for fumigated water was also determined to identify differences with the suspension. A reduction in the pH towards acidification was observed. The obtained findings may be used in a comprehensive assessment of pyrogenic effects on forest soils. Moreover, indicators are sensitive to this effect, which was confirmed by the results of the present research.
Progressing Sustainable Development through Social Entrepreneurship: Modelling Intentional Predictors for Bangladesh Using the Value–Belief–Norm Model
Authors: Fazal Syed Ali , Mamun Abdullah Al , Hayat Naeem , Peris Sandy Francis , Ali Mohd Helmi , Jamaluddin Hasmida
Published: August 2023

Considering the diverse social and environmental issues globally, social entrepreneurship could be the most relevant solution to address social issues by employing a sustainable economic model, particularly for developing nations with limited government support. Hence, we examined social entrepreneurship intention among working adults in Bangladesh using an extended version of the value–belief–norm model. We used a cross-sectional design to arrange an online questionnaire and collect quantitative data from 187 respondents. SEM-PLS was used for analysis. Findings revealed a significant positive effect of openness to change, self-enhancement, and self-transcendence on problem awareness. Problem awareness was found to significantly affect outcome efficacy and social entrepreneurship intention. Finally, personal norms showed significant positive effects on social entrepreneurship intention. The mediating role of problem awareness and personal norms was further confirmed. Apart from extending the lens of VBN and enriching the current literature, insights from this study could assist policymakers, social organizations, and social entrepreneurs in formulating relevant policies and sustaining social ventures.
The Response of CSR to Economic Policy Uncertainty: Evidence from China
Authors: Zou Hailiang , Wang Ruijing , Qi Guoyou
Published: August 2023

The dynamics and instability of economic policies exercise considerable influence on firm behaviors. This study aims to explore the impact of economic policy uncertainty on the level of CSR that firms are engaged in and the heterogeneity of this impact across firms. Using a dataset of Chinese-listed companies from 2011 to 2019, which consists of 837 different firms and 4551 firm-year observations, the results show a negative response of CSR to economic policy uncertainty in China, which is mitigated by the political connections and resource slack that firms possess. These findings underscore the importance of a predictable business environment for CSR behaviors and the capability of firms to cope with uncertainty.
Dynamic Relationship between Agricultural Water Use and the Agricultural Economy in the Inner Mongolia Section of the Yellow River Basin
Authors: Ye Zhigang , Miao Ping , Li Ning , Wang Yong , Meng Fanhao , Zhang Rong , Yin Shan
Published: August 2023

Water is a crucial resource for agricultural development in the Yellow River Basin. However, the effects of water shortages on the region’s agricultural development are becoming increasingly evident, creating a need to examine the relationship between agricultural water use (AWU) and the agricultural economy. This study uses panel vector autoregression to analyze the relationship between AWU and the agricultural economy in the Inner Mongolia section of the Yellow River Basin from 1998 to 2018. The results indicate the following: (1) AWU in the Inner Mongolia section of the Yellow River Basin significantly declined during the study period, showing clear differences in the AWU’s effectiveness among regions; (2) agriculture in the region stabilized after significant growth, and the share of primary-sector industries in the national economy also stabilized after significant decline; (3) in the long run, AWU and the agricultural economy become cointegrated with the AWU Granger-causing agricultural economy. By deepening our understanding of agricultural water demand in the Yellow River Basin, these findings provide theoretical justification for establishing water-conserving irrigation systems and making sustainable use of water resources.