bluuebunny/crossref_metadata_2025 huggingface dataset:
Therapeutic Effect on Swallowing Function and on Hydration Status of a New Liquid Gum-Based Thickener in Independently-Living Older Patients with Oropharyngeal Dysphagia
Authors: Tomsen Noemí , Bolívar-Prados Mireia , Ortega Omar , Clavé Pere
Published: October 2023

ThickenUp® Gel Express (TUGE) is a new, xanthan- and acacia-gum-based, liquid, thickening product. In independently living older adults with oropharyngeal dysphagia (OD), we assessed: (1) the rheological properties of TUGE; (2) its therapeutic effect at four viscosity levels (achieved by 5 g, 10 g, 20 g and 30 g of TUGE in water + Omnipaque X-ray contrast) versus thin liquid; and (3) the effect on hydration status and gastrointestinal tolerance after fourteen days. Shear viscosity of TUGE was measured in SI units (mPa·s at 50 s−1). The Penetration Aspiration Scale (PAS) score and the swallow response at each viscosity level was assessed with videofluoroscopy (VFS), and in the 14-day study we assessed fluid intake, hydration, and tolerance. Thickened fluids with TUGE were unaffected (−0.3%) by α-salivary amylase (α-SA). The shear viscosity values with VFS were 49.41 ± 2.38, 154.83 ± 10.22, 439.33 ± 11.72 and 672.5 ± 35.62 mPa·s. We studied 60 independently living adults (70 ± 11.4 years) with mild OD (PAS 4.1 ± 2.2, 25% aspirations). TUGE caused a shear-viscosity-dependent improvement in PAS at 150–670 mPa·s and in safety of swallow, slightly increased oral residue, did not affect pharyngeal residue and reduced time to laryngeal vestibule closure (−27%) at 670 mPa·s. Fluid intake with TUGE (1488 mL/day) was well tolerated, and hydration status improved. In conclusion, TUGE was unaffected by α-SA and strongly improved safety of swallow in a viscosity-dependent manner without affecting pharyngeal residue. Fourteen-day treatment of thickened fluids with TUGE is safe and well tolerated and improves hydration status in older adults with dysphagia.
Effect of Docosahexaenoic Acid Encapsulation with Whey Proteins on Rat Growth and Tissue Endocannabinoid Profile
Authors: Wang Jun , Ossemond Jordane , Le Gouar Yann , Boissel Françoise , Dupont Didier , Pédrono Frédérique
Published: October 2023

Modifying the food structure allows a nutrient to be delivered differently, which can modify not only its digestion process but also its subsequent metabolism. In this study, rats received 3 g of omelette daily containing docosahexaenoic acid (DHA) as crude oil or previously encapsulated with whey proteins, whereas a control group received a DHA-free omelette. The results showed that DHA encapsulation markedly induced a different feeding behaviour so animals ate more and grew faster. Then, after four weeks, endocannabinoids and other N-acyl ethanolamides were quantified in plasma, brain, and heart. DHA supplementation strongly reduced endocannabinoid derivatives from omega-6 fatty acids. However, DHA encapsulation had no particular effect, other than a great increase in the content of DHA-derived docosahexaenoyl ethanolamide in the heart. While DHA supplementation has indeed shown an effect on cannabinoid profiles, its physiological effect appears to be mediated more through more efficient digestion of DHA oil droplets in the case of DHA encapsulation. Thus, the greater release of DHA and other dietary cannabinoids present may have activated the cannabinoid system differently, possibly more locally along the gastrointestinal tract. However, further studies are needed to evaluate the synergy between DHA encapsulation, fasting, hormones regulating food intake, and animal growth.
Nurturing through Nutrition: Exploring the Role of Antioxidants in Maternal Diet during Pregnancy to Mitigate Developmental Programming of Chronic Diseases
Authors: Diniz Mariana S. , Magalhães Carina C. , Tocantins Carolina , Grilo Luís F. , Teixeira José , Pereira Susana P.
Published: October 2023

Chronic diseases represent one of the major causes of death worldwide. It has been suggested that pregnancy-related conditions, such as gestational diabetes mellitus (GDM), maternal obesity (MO), and intra-uterine growth restriction (IUGR) induce an adverse intrauterine environment, increasing the offspring’s predisposition to chronic diseases later in life. Research has suggested that mitochondrial function and oxidative stress may play a role in the developmental programming of chronic diseases. Having this in mind, in this review, we include evidence that mitochondrial dysfunction and oxidative stress are mechanisms by which GDM, MO, and IUGR program the offspring to chronic diseases. In this specific context, we explore the promising advantages of maternal antioxidant supplementation using compounds such as resveratrol, curcumin, N-acetylcysteine (NAC), and Mitoquinone (MitoQ) in addressing the metabolic dysfunction and oxidative stress associated with GDM, MO, and IUGR in fetoplacental and offspring metabolic health. This approach holds potential to mitigate developmental programming-related risk of chronic diseases, serving as a probable intervention for disease prevention.
Foraging Wild Edibles: Dietary Diversity in Expanded Food Systems
Authors: Bellows Anne C. , Raj Sudha , Pitstick Ellen , Potteiger Matthew R. , Diemont Stewart A. W.
Published: October 2023

Human food foraging in community forests offers extensive and expandable sources of food and high-quality nutrition that support chronic disease prevention and management and are underrepresented in US diets. Despite severe gaps in non-commercial “wild food” data, research in Syracuse, NY, identified substantial amounts of five key antioxidant phytochemicals in locally available, forageable foods with the potential to augment local dietary diversity and quality. Findings endorse the need for micro- and macro-nutrient research on an expanded range of forageable foods, community nutrition education on those foods, an expanded study on antioxidant phytochemical function, and the inclusion of forageables in the food system definition.
Understanding the Gut–Brain Axis and Its Therapeutic Implications for Neurodegenerative Disorders
Authors: Zheng Yadong , Bonfili Laura , Wei Tao , Eleuteri Anna Maria
Published: October 2023

The gut–brain axis (GBA) is a complex bidirectional communication network connecting the gut and brain. It involves neural, immune, and endocrine communication pathways between the gastrointestinal (GI) tract and the central nervous system (CNS). Perturbations of the GBA have been reported in many neurodegenerative disorders (NDDs), such as Alzheimer’s disease (AD), Parkinson’s disease (PD), and amyotrophic lateral sclerosis (ALS), among others, suggesting a possible role in disease pathogenesis. The gut microbiota is a pivotal component of the GBA, and alterations in its composition, known as gut dysbiosis, have been associated with GBA dysfunction and neurodegeneration. The gut microbiota might influence the homeostasis of the CNS by modulating the immune system and, more directly, regulating the production of molecules and metabolites that influence the nervous and endocrine systems, making it a potential therapeutic target. Preclinical trials manipulating microbial composition through dietary intervention, probiotic and prebiotic supplementation, and fecal microbial transplantation (FMT) have provided promising outcomes. However, its clear mechanism is not well understood, and the results are not always consistent. Here, we provide an overview of the major components and communication pathways of the GBA, as well as therapeutic approaches targeting the GBA to ameliorate NDDs.
Searching for Natural Aurora a Kinase Inhibitors from Peppers Using Molecular Docking and Molecular Dynamics
Authors: Siudem Paweł , Szeleszczuk Łukasz , Paradowska Katarzyna
Published: October 2023

Natural products are the precursors of many medicinal substances. Peppers (Piper, Capsicum, Pimienta) are a rich source of compounds with potential multidirectional biological activity. One of the studied directions is antitumor activity. Little research has been carried out so far on the ability of the compounds contained in peppers to inhibit the activity of Aurora A kinase, the overexpression of which is characteristic of cancer development. In this study, molecular docking methods, as well as molecular dynamics, were used, looking for compounds that could inhibit the activity of Aurora A kinase and trying to determine whether there is a relationship between the stimulation of the TRPV1 receptor and the inhibition of Aurora A kinase. We compared our results with anticancer activity studied earlier on MCF-7 cell lines (breast cancer cells). Our research indicates that the compounds contained in peppers can inhibit Aurora A. Further in vitro research is planned to confirm the obtained results.
Development of a Novel Peptide with Antimicrobial and Mineralising Properties for Caries Management
Authors: Zhang Olivia Lili , Niu John Yun , Yu Ollie Yiru , Mei May Lei , Jakubovics Nicholas Stephen , Chu Chun Hung
Published: October 2023

The purpose of the study is to develop a novel peptide for caries management. Gallic-Acid-Polyphemusin-I (GAPI) was synthesised by grafting Polyphemusin I (PI) and gallic acid (GA). Biocompatibility was evaluated using a Cell Counting Kit-8 Assay. Antimicrobial properties were assessed using minimum inhibitory concentration (MIC) and minimum bactericidal/fungicidal concentration (MBC/MFC). The bacterial and fungal morphology after GAPI treatment was investigated using transmission electron microscopy (TEM). The architecture of a consortium biofilm consisting of Streptococcus mutans, Lacticaseibacillus casei and Candida albicans was evaluated using scanning electron microscopy (SEM) and confocal laser scanning microscopy. The growth kinetics of the biofilm was examined using a propidium monoazide–quantitative polymerase chain reaction. The surface and calcium-to-phosphorus molar ratio of GAPI-treated enamel after pH cycling were examined with SEM and energy-dispersive X-ray spectroscopy. Enamel crystal characteristics were analysed using X-ray diffraction. Lesion depths representing the enamel’s mineral loss were assessed using micro-computed tomography. The MIC of GAPI against S. mutans, L. casei and C. albicans were 40 μM, 40 μM and 20 μM, respectively. GAPI destroyed the biofilm’s three-dimensional structure and inhibited the growth of the biofilm. SEM showed that enamel treated with GAPI had a relatively smooth surface compared to that treated with water. The calcium-to-phosphorus molar ratio of enamel treated with GAPI was higher than that of the control. The lesion depths and mineral loss of the GAPI-treated enamel were less than the control. The crystallinity of the GAPI-treated enamel was higher than the control. This study developed a biocompatible, mineralising and antimicrobial peptide GAPI, which may have potential as an anti-caries agent.
Stabilized Astaxanthin Nanoparticles Developed Using Flash Nanoprecipitation to Improve Oral Bioavailability and Hepatoprotective Effects
Authors: Ghosh Antara , Banik Sujan , Yamada Kohei , Misaka Shingen , Prud’homme Robert K. , Sato Hideyuki , Onoue Satomi
Published: October 2023

In this study, we developed stabilized astaxanthin (AX) nanoparticles (sNP/AX) to improve the physicochemical properties, oral bioavailability, and hepatoprotection of AX. A flash nanoprecipitation technique was used with a multi-inlet vortex mixer to prepare the sNP/AX. Vitamins E (VE) and C (VC) were used as co-stabilizers with poloxamer 407 as a stabilizer to inhibit the oxidative degradation of AX during sNP/AX formation and storage. VC stabilized AX in the aqueous phase during the preparation, whereas VE markedly improved the storage stability of sNP/AX, as evidenced by the AX contents remaining at 94 and 81% after 12 weeks of storage at 4 °C and 25 °C, respectively. The mean sNP/AX diameter was 215 nm, which resulted in higher AX release properties than those of crystalline AX. Rats, orally administered sNP/AX (33.2 mg AX/kg), exhibited higher systemic exposure to AX, whereas oral absorption in the crystalline AX group was negligible. In the rat hepatic injury model, oral pretreatment with sNP/AX (33.2 mg AX/kg) markedly attenuated hepatic damage, as shown by the histopathological analysis and reduced levels of plasma biomarkers for hepatic injury. These findings suggest that strategically including antioxidative additives in the sNP/AX has the potential to improve the physicochemical and nutraceutical properties of AX.
Reconstructing Depth Images for Time-of-Flight Cameras Based on Second-Order Correlation Functions
Authors: Wang Tian-Long , Ao Lin , Zheng Jie , Sun Zhi-Bin
Published: October 2023

Depth cameras are closely related to our daily lives and have been widely used in fields such as machine vision, autonomous driving, and virtual reality. Despite their diverse applications, depth cameras still encounter challenges like multi-path interference and mixed pixels. Compared to traditional sensors, depth cameras have lower resolution and a lower signal-to-noise ratio. Moreover, when used in environments with scattering media, object information scatters multiple times, making it difficult for time-of-flight (ToF) cameras to obtain effective object data. To tackle these issues, we propose a solution that combines ToF cameras with second-order correlation transform theory. In this article, we explore the utilization of ToF camera depth information within a computational correlated imaging system under ambient light conditions. We integrate compressed sensing and non-training neural networks with ToF technology to reconstruct depth images from a series of measurements at a low sampling rate. The research indicates that by leveraging the depth data collected by the camera, we can recover negative depth images. We analyzed and addressed the reasons behind the generation of negative depth images. Additionally, under undersampling conditions, the use of reconstruction algorithms results in a higher peak signal-to-noise ratio compared to images obtained from the original camera. The results demonstrate that the introduced second-order correlation transformation can effectively reduce noise originating from the ToF camera itself and direct ambient light, thereby enabling the use of ToF cameras in complex environments such as scattering media.
Diversity of Leaf Glands and Their Putative Functions in Rhamnaceae Species
Authors: Iwamoto Lucas , Vicentini Thales Augusto , Ramos Felipe Paulino , Ribeiro Carimi Cortez , Teixeira Simone Pádua
Published: October 2023

Leaf glands are found in many Rhamnaceae species, the buckthorn family, and are frequently used in taxonomic studies of the group, especially because they are easily visible to the naked eye. Despite the many records and extensive use in the taxonomy of the family, few studies deal with the classification of these glands and their roles for the plant. Thus, this study aimed to unravel the type, functioning, and putative functions of the leaf glands of three Brazilian forest species: Colubrina glandulosa Perkins, Gouania polygama (Jacq.) Urb., and Rhamnidium elaeocarpum Reissek. Leaves were collected and processed for surface, anatomical, histochemical, and ultrastructural analyses. In addition, the presence of visitor animals was registered in the field. The leaf glands of C. glandulosa and G. polygama are defined as extrafloral structured nectaries due to their anatomical structure, interaction with ants, and the presence of reduced sugars and of a set of organelles in the secretory cells. The unusual mechanism of nectar release and exposure in an apical pore stands out in G. polygama. The glands of R. elaeocarpum are ducts or cavities that secrete phenolic oil resin. Their presence is an atypical condition in the family, although they are often confused with mucilage reservoirs, much more common in Rhamnaceae. The extrafloral nectary, secretory cavity, and duct are associated with plant protection against phytophages, either by attracting patrol ants or by making the organs deterrent. Our data, combined with other previously obtained data, attest to the great diversity of gland types found in Rhamnaceae species.
Breeding of Modern Rose Cultivars Decreases the Content of Important Biochemical Compounds in Rose Hips
Authors: Kunc Nina , Hudina Metka , Mikulic-Petkovsek Maja , Osterc Gregor
Published: October 2023

This study aimed to determine the content and composition of bioactive compounds in autochthonous rose hips (R. pendulina, R. spinosissima, and R. gallica) and to compare them with the content of bioactive compounds in some cultivars (‘Harstad’, ‘Bourgogne’, ‘Mount Everest’, ‘Poppius’, ‘Fruhlingsduft’, ‘Single Cherry’, ‘Fruhlingsmorgen’, ‘Violacea’, and ‘Splendens’) derived from these main species. Due to insufficient information on how bioactive compound content changes when crossing roses, this study also sought to ascertain whether modern rose hip cultivars are still a sufficiently rich source of bioactive compounds and could, therefore, be potentially used as a functional food. All material was collected in the Arboretum Volčji Potok (Slovenia). The ascorbic acid content was highest in the ‘Harstad’ cultivar (12.79 g/kg FW), and the total organic acid content varied from 1.57 g/kg FW (R. spinosissima) to 34.39 g/kg FW (‘Harstad’). Of all the carotenoids analyzed, only lycopene and β-carotene were present in all the samples. The total carotenoid content was highest in the ‘Fruhlingsmorgen’ cultivar (100.84 mg/kg FW), derived from R. spinosissima, and lowest in the main species, R. spinosissima (9.26 mg/kg FW). It can be concluded, therefore, that the content of bioactive compounds in rose hips of modern cultivars is generally lower than in rose hips of old cultivars and original species included in this study. The research results confirm that modern breeding strategies are mainly focused on goals such as abundant flowering and resistance to diseases and pests and not so much on the content of bioactive compounds.
Dense Cover, but Not Allelopathic Potential, of Naturalized Alien Cenchrus echinatus L. Threatens the Native Species in Urban Vegetation
Authors: Hassan Mahmoud O. , Mohamed Howida Y. , Okla Mohammad K. , Kiani Bushra Hafeez , Amro Ahmed
Published: October 2023

Exotic plants usually exhibit problems for native species where they coexist. This study evaluated the effect of naturalized alien Cenchrus echinatus L. on native plants in urban vegetation. A field trial was conducted to assess the effect of this species on the cover and diversity of the native vegetation. The allelopathic potential of such species was examined. Sites comprising C. echinatus had a lower cover than some native species. Lower floristic diversity was observed at higher densities of this plant. The soil under this plant attained lower N, P, and K contents. This soil had no effect on the germination and growth of native species. It also comprised germinable seeds of some species which were absent from the standing vegetation. Exotic C. echinatus may exert negative effects on the native vegetation of the urban plant communities. A dense cover of this species may inhibit the germination of native species, leading to a reduction in their cover. Reduction in cover and diversity of native species may not be attributed to allelopathy. These results suggest that naturalized C. echinatus may be more competitive than the native ones, particularly at higher densities. Furthermore, it may represent a threat to the native plants in the urban vegetation.
Efficacy of Lemon Myrtle Essential Oil as a Bio-Fungicide in Inhibiting Citrus Green Mould
Authors: Rahman Mohammad M. , Wills Ronald B. H. , Bowyer Michael C. , Vuong Van Q. , Golding John B. , Kirkman Timothy , Pristijono Penta
Published: October 2023

The effectiveness of lemon myrtle (LM) (Backhousia citriodora) essential oil (EO) was investigated to combat Penicillium digitatum by in vitro agar diffusion and vapour assay and in artificially infected oranges. The main constituent of LM EO was revealed as citral when analysed in gas chromatography–mass spectrometry. Pure citral was also included in the experiment for comparison. The in vitro fungal growth was significantly inhibited by LM EO at 1, 2, 3, 4 and 5 μL per disc while complete growth inhibition by both the pure citral and LM EO occurred at 4 and 5 μL per disc. Inoculated fruits treated by dipping in 1000 μL L−1 LM EO solutions for 5, 10, 15, 30 and 120 s showed significantly lower fungal wounds compared to control. While longer dipping times led to some rind injuries, fruits with a 5 and 10 s dip were found free from any injury. The evaluation after dipping and storage confirmed that the fruits maintained the sensory attributes and were not compromised by the incorporation of the essential oil. The results of this study indicate that LM EO can be a promising alternative to synthetic fungicides for preserving the quality of citrus fruits during storage.
Enhanced Thermal and Dielectric Properties of Polyarylene Ether Nitrile Nanocomposites Incorporated with BN/TiO2-Based Hybrids for Flexible Dielectrics
Authors: You Yong , Chen Siyi , Yang Shuang , Li Lianjun , Wang Pan
Published: October 2023

Outstanding high-temperature resistance, thermal stability, and dielectric properties are fundamental for dielectric materials used in harsh environments. Herein, TiO2 nanoparticles are decorated on the surface of BN nanosheets by internal crosslinking between polydopamine (PDA) and polyethyleneimine (PEI), forming three-dimensional novel nanohybrids with a rough surface. Then, an ether nitrile (PEN) matrix is introduced into the polyarylene to form polymer-based nanocomposite dielectric films. Meanwhile, the structure and micromorphology of the newly prepared nanohybrids, as well as the dielectric and thermal properties of PEN nanocomposites, are investigated in detail. The results indicate that TiO2 nanoparticles tightly attach to the surface of BN, creating a new nanohybrid that significantly enhances the comprehensive performance of PEN nanocomposites. Specifically, compared to pure PEN, the nanocomposite film with a nanofiller content of 40 wt% exhibited an 8 °C improvement in the glass transition temperature (Tg) and a 162% enhancement in the dielectric constant at 1 kHz. Moreover, the dielectric constant–temperature coefficient of the nanocomposite films remained below 5.1 × 10−4 °C−1 within the temperature range of 25–160 °C, demonstrating excellent thermal resistance. This work offers a method for preparing highly thermal-resistant dielectric nanocomposites suitable for application in elevated temperature environments.
Thin Films of a Complex Polymer Compound for the Inhibition of Iron Alloy Corrosion in a H3PO4 Solution
Authors: Avdeev Yaroslav G. , Nenasheva Tatyana A. , Luchkin Andrei Yu. , Marshakov Andrei I. , Kuznetsov Yurii I.
Published: October 2023

The etching of iron alloy items in a H3PO4 solution is used in various human activities (gas and oil production, metalworking, transport, utilities, etc.). The etching of iron alloys is associated with significant material losses due to their corrosion. It has been found that an efficient way to prevent the corrosion of iron alloys in a H3PO4 solution involves the formation of thin complex compound films consisting of the corrosion inhibitor molecules of a triazole derivative (TrzD) on their surface. It has been shown that the protection of iron alloys with a mixture of TrzD + KNCS in a H3PO4 solution is accompanied by the formation of a thin film of coordination polymer compounds thicker than 4 nm consisting of TrzD molecules, Fe2+ cations and NCS−. The layer of the complex compound immediately adjacent to the iron alloy surface is chemisorbed on it. The efficiency of this composition as an inhibitor of iron alloy corrosion and hydrogen bulk sorption by iron alloys is determined by its ability to form a coordination polymer compound layer, as experimentally confirmed by electrochemical, AFM and XPS data. The efficiency values of inhibitor compositions 5 mM TrzD + 0.5 mM KNCS and 5 mM TrzD + 0.5 mM KNCS + 200 mM C6H12N4 at a temperature of 20 ± 1 °C are 97% and 98%, respectively. The kinetic parameters of the limiting processes of hydrogen evolution and permeation into an iron alloy in a H3PO4 solution were determined. A significant decrease in both the reaction rate of hydrogen evolution and the rate of hydrogen permeation into the iron alloy by the TrzD and its mixtures in question was noted. The inhibitor compositions 5 mM TrzD + 0.5 mM KNCS and 5 mM TrzD + 0.5 mM KNCS + 200 mM C6H12N4 decreased the total hydrogen concentration in the iron alloy up to 9.3- and 11-fold, respectively. The preservation of the iron alloy plasticity in the corrosive environment containing the inhibitor under study was determined by a decrease in the hydrogen content in the alloy bulk.
Enhancement of the Structure, Thermal, Linear/Nonlinear Optical Properties, and Antibacterial Activity of Poly (vinyl alcohol)/Chitosan/ZnO Nanocomposites for Eco-Friendly Applications
Authors: Abdelfattah E. M. , Elzanaty H. , Elsharkawy W. B. , Azzam M. A. , Elqahtani Z. M. , Alotibi S. , Alyami M. , Fahmy T.
Published: October 2023

The preparation of poly (vinyl alcohol)/chitosan/ZnO (PVA/Cs/ZnO) nanocomposite films as bioactive nanocomposites was implemented through an environmentally friendly approach that included mixing, solution pouring, and solvent evaporation. The nanocomposite films were characterized using various techniques such as X-ray diffraction (XRD), Fourier-transform infrared (FT-IR) spectroscopy, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and UV-Vis spectroscopy. The XRD study revealed the encapsulation of nanoparticles by the PVA/Cs blend matrix. The DSC results showed that the addition of ZnO NPs increased glass transition and melting temperature values of the PVA/Cs blend. ATR-FTIR spectra detected an irregular shift (either red or blue) in some of the characteristic bands of the PVA/Cs nanocomposite, indicating the existence of intra/intermolecular hydrogen bonding creating an interaction between the OH groups of PVA/Cs and ZnO nanoparticles. A thermogravimetric (TGA) analysis demonstrated that the nanocomposites achieved better thermal resistance than a pure PVA/Cs blend and its thermal stability was enhanced with increasing concentration of ZnO nanoparticles. UV analysis showed that with an increase in the content of ZnO NPs, the optical bandgap of PVA/Cs was decreased from 4.43 eV to 3.55 eV and linear and nonlinear parameters were enhanced. Our optical results suggest the use of PVA/Cs/ZnO nanocomposite films for various optoelectronics applications. PVA/Cs/ZnO nanocomposites exhibited significant antibacterial activity against Gram-positive and Gram-negative bacteria. It was found that nanocomposite samples were more effective against Gram-positive compared to Gram-negative bacteria.
Alginate Modified Magnetic Polypyrrole Nanocomposite for the Adsorptive Removal of Heavy Metal
Authors: Mashkoor Fouzia , Shoeb Mohd , Jeong Changyoon
Published: October 2023

The presence of heavy metals with high acute toxicity in wastewater poses a substantial risk to both the environment and human health. To address this issue, we developed a nanocomposite of alginate-encapsulated polypyrrole (PPy) decorated with α-Fe2O3 nanoparticles (Alg@Mag/PPy NCs), fabricated for the removal of mercury(II) from synthetic wastewater. In the adsorption experiments, various parameters were examined to identify the ideal conditions. These parameters included temperature (ranging from 298 to 323 K), initial pH levels (ranging from two to nine), interaction time, amount of adsorbent (from 8 to 80 mg/40 mL), and initial concentrations (from 10 to 200 mg/L). The results of these studies demonstrated that the removal efficiency of mercury(II) was obtained to be 95.58% at the optimum pH of 7 and a temperature of 303 K. The analysis of adsorption kinetics demonstrated that the removal of mercury(II) adhered closely to the pseudo-second-order model. Additionally, it displayed a three-stage intraparticle diffusion model throughout the entire adsorption process. The Langmuir model most accurately represented equilibrium data. The Alg@Mag/PPy NCs exhibited an estimated maximum adsorption capacity of 213.72 mg/g at 303 K, surpassing the capacities of most of the other polymer-based adsorbents previously reported. The thermodynamic analysis indicates that the removal of mercury(II) from the Alg@Mag/PPy NCs was endothermic and spontaneous in nature. In summary, this study suggests that Alg@Mag/PPy NCs could serve as a promising choice for confiscating toxic heavy metal ions from wastewater through adsorption.
Spherical CaCO3: Synthesis, Characterization, Surface Modification and Efficacy as a Reinforcing Filler in Natural Rubber Composites
Authors: Longkaew Khansinee , Gibaud Alain , Tessanan Wasan , Daniel Philippe , Phinyocheep Pranee
Published: October 2023

Natural rubber (NR), an important natural polymer derived from the Hevea brasiliensis tree, has been widely used in the rubber industry owing to its excellent elastic properties. However, it requires reinforcing fillers to improve its mechanical properties for the manufacturing of rubber products. Generally, calcium carbonate (CaCO3) is employed as a non-reinforcing filler. This work aimed to synthesize spherical-shaped CaCO3 at a submicrometric scale without and with surface treatment and explore its utilization as a reinforcing filler in NR composites. The morphological shape and polymorphic phase of CaCO3 were investigated using SEM, TEM, XRD, ATR-FTIR and Raman techniques. The mechanical properties of various amounts (0 to 60 phr) of CaCO3-filled NR composites were explored. As a result, the NR/treated CaCO3 composites provided higher tensile strength than the NR/untreated CaCO3 composites and pure NR at all filler loadings. This may have been due to the improved interfacial interaction between NR and CaCO3 with the improved hydrophobicity of CaCO3 after treatment with olive soap. The optimal filler loading was 20 phr for the highest tensile strength of the rubber composites. In addition, the elongation at break of the NR/treated CaCO3 was slightly decreased. Evidence from SEM and FTIR revealed the vaterite polymorph and shape stability of CaCO3 particles in the NR matrix. The results demonstrate that the particle size and surface treatment of the filler have essential effects on the mechanical property enhancement of the rubber composites. Synthesized spherical CaCO3 could be a potential reinforcing filler with broader application in polymer composites.
The Influence of Styrene Content in Solution Styrene Butadiene Rubber on Silica-Filled Tire Tread Compounds
Authors: Um Gi-Yong , Kwon Taehoon , Lee Seong Hwan , Kim Woong , Kim Jungsoo , Kim Hee Joong , Lee Jin Hong
Published: October 2023

In tire tread applications, achieving enhanced abrasion resistance, wet grip, and rolling resistance is crucial for optimizing overall performance. To realize improvements in these attributes for silica-filled tire tread compounds, it becomes imperative to improve the dispersity of silica filler by investigating the effect of each component in the tire tread compound. In this work, we study the effect of styrene content within solution styrene butadiene rubber (SSBR) on the properties of tire tread compounds. A higher styrene segment within SSBR contributes to increased silica dispersion and crosslink density. Thus, tire tread compounds featuring SSBR with increased styrene content not only improve physical and mechanical properties, but also enhance major characteristics tailored for tire tread applications. These findings provide valuable insights into advancing the reinforced performance of tire tread compounds through the strategic utilization of SSBR enriched in styrene content.
On the Effect of Non-Thermal Atmospheric Pressure Plasma Treatment on the Properties of PET Film
Authors: Maliszewska Irena , Gazińska Małgorzata , Łojkowski Maciej , Choińska Emilia , Nowinski Daria , Czapka Tomasz , Święszkowski Wojciech
Published: October 2023

The aim of the work was to investigate the effect of non-thermal plasma treatment of an ultra-thin polyethylene terephthalate (PET) film on changes in its physicochemical properties and biodegradability. Plasma treatment using a dielectric barrier discharge plasma reactor was carried out in air at room temperature and atmospheric pressure twice for 5 and 15 min, respectively. It has been shown that pre-treatment of the PET surface with non-thermal atmospheric plasma leads to changes in the physicochemical properties of this polymer. After plasma modification, the films showed a more developed surface compared to the control samples, which may be related to the surface etching and oxidation processes. After a 5-min plasma exposure, PET films were characterized by the highest wettability, i.e., the contact angle decreased by more than twice compared to the untreated samples. The differential scanning calorimetry analysis revealed the influence of plasma pretreatment on crystallinity content and the melt crystallization behavior of PET after soil degradation. The main novelty of the work is the fact that the combined action of two factors (i.e., physical and biological) led to a reduction in the content of the crystalline phase in the tested polymeric material.
Removal of Pyridine from Aqueous Solutions Using Lignite, Coking Coal, and Anthracite: Adsorption Kinetics
Authors: Xu Hongxiang , Li Shan , Wang Jingzheng , Deng Jiushuai , Huang Gen , Sang Qun , Cui Jiahua
Published: October 2023

A novel coking wastewater treatment technique is proposed based on the principles of the circular economy. By utilizing coal as an adsorbent for organic pollutants in coking wastewater, the treated coal can be introduced into the coking system after the adsorption and flocculation sedimentation processes. This creates a closed-loop system with zero coking wastewater emissions. We investigated the potential of adsorption for the removal of pyridine. Batch experiments were conducted using lignite, coking coal, and anthracite as adsorbents. Both coking coal and anthracite showed favorable adsorption properties for the chosen contaminants. The experimental data were analyzed utilizing various models, including pseudo-first-order and pseudo-second-order kinetic equations, as well as intraparticle diffusion and Bangham. This study aimed to identify the rate-limiting step in the adsorption process. The results revealed that the adsorption of pyridine onto the three coal types followed pseudo-second-order kinetics. The rate-limiting mechanisms may include both boundary-layer diffusion and intraparticle diffusion. The effect of pH on coal adsorption and the activation energy of pyridine adsorption by coking coal were also examined. Adsorption offers a promising approach in advanced wastewater treatment, with coking coal emerging as a cost-effective adsorbent for addressing persistent organic pollutants during the adsorption process.
Optimization of the Flashing Processes in Mineral Metallurgy Based on CFD Simulations
Authors: Xiao Yiting , Pan Zhengbin , Xin Haotong , Xia Chongmao , Wang Xuefeng , Li Qifang , Kong Bo
Published: October 2023

In mineral metallurgy, the flashing unit is key to returning the slurry to atmospheric conditions. Its primary function is to achieve pressure letdown, and during the process, shock waves are generated to maximize energy dissipation. Investigating the location and expansion of shock waves is the focal point of this study due to their importance in flashing unit design. A CFD model coupled with a homogeneous relaxation model (HRM) was used to simulate the flashing process of mineral slurry. The flow behavior, including velocity, pressure, and the shape and location of the shock waves, were obtained using simulation under different unit design and operating parameters. These results would provide valuable insights into the design of flashing units and guidance for the safe operation and maintenance of devices.
Productivity Equation of Fractured Vertical Well with Gas–Water Co-Production in High-Water-Cut Tight Sandstone Gas Reservoir
Authors: Wei Benchi , Nie Xiangrong , Zhang Zonghui , Ding Jingchen , Shayireatehan Reyizha , Ning Pengzhan , Deng Dingtian , Cao Yi
Published: October 2023

Due to the high water saturation in high-water-cut tight sandstone gas reservoirs, factors such as threshold pressure gradient (TPG) and stress sensitivity (SS) cannot be overlooked in terms of their impact on seepage parameters. Therefore, this paper primarily investigates the seepage mechanisms in tight, high-water-cut sandstone gas reservoirs. While considering the influence of water saturation on various seepage mechanisms, it establishes a gas well productivity equation under stable seepage conditions and presents an analysis of the influencing factors. In a comparison of the unobstructed flow rates calculated using the productivity equation developed in this paper with those obtained from conventional gas well productivity equations and actual gas well productivity tests, the new equation demonstrates smaller errors. This provides a theoretical basis for evaluating productivity and making rational production allocation decisions in high-water-cut tight sandstone gas reservoirs.
Stope Structural Parameters Design towards Green and Deep Mining: A Review
Authors: Zhou Xin , Zhao Xingdong , Qu Qingdong , Shi Jingyu
Published: October 2023

A reliable design of stopes is critical to ensure both safety and efficiency in mining operations. The evolving mining methods and technologies as well as increasing mining depth dictate the need to continually improve stope designs. This paper presents a comprehensive review in order to compare and consolidate various stope design methods. This review covers various aspects of stope design, including design principles, factors to consider, and the diverse range of design methods available. The results led to the classification of various methods encompassing engineering analogies, fundamentals, numerical simulations, and industrial tests. Of particular significance, the review furnishes detailed insights into the research conducted on each method, as well as each method’s practical performance in engineering applications. Furthermore, the review highlights the inherent limitations in current design methods and suggests potential avenues for future research. Finally, by comprehensively considering the functional roles and advantages of each design method, it overcomes the limitations of relying solely on a single method for stope structural parameter design, and a general process is proposed.
Effect of Time and Temperature in Sous-Vide Heat Treatment on Selected Physicochemical Properties of Horsemeat
Authors: Stanisławczyk Renata , Żurek Jagoda , Rudy Mariusz , Gil Marian , Krajewska Anna , Dziki Dariusz
Published: October 2023

The sous-vide technique is most commonly used for meat preparation, offering superior nutritional retention, a delicate texture, and enhanced juiciness in the resulting dishes. The purpose of this study was to analyze the effect of time and temperature in sous-vide heat treatment on selected physicochemical properties of horsemeat. Samples of m. longissimus thoracis were heated to 55, 60, 65 °C for 4, 8, 12, and 24 h, and the impact of these heat treatment parameters on chemical composition, physicochemical properties, amount of heme pigments, and color parameters of the tested raw material was determined. Horsemeat subjected to sous-vide heat treatment at 55 °C for 4 h was characterized by a high proportion of red color and oxymyoglobin. Sous-vide treatment carried out at low temperatures and for a short period of time reduces the amount of weight loss and the increase in the TBARS index, allowing the preservation of the red color of the raw material studied. Prolonging the duration or increasing the temperature of sous-vide processing results in a deterioration of the mentioned parameters and also leads to significant changes in the chemical composition of horsemeat, including a significant reduction in the water content and increase in the amount of fat in horsemeat.
An Experimental Method to Add New Prosthetic Teeth in the Removable Partial Denture Framework: TIG Cold Welding and Preformed Pins
Authors: Cumbo Enzo , Messina Pietro , Gallina Giuseppe , Scardina Giuseppe Alessandro
Published: October 2023

The need to modify removable partial dentures equipped with a metal framework in order to add other prosthetic teeth to replace natural teeth lost by the patient could lead to laboratory procedures so complex as to require the creation of new prostheses with a heavy economic burden. The creation of preformed metal pins to be welded using the economical TIG cold welding method could represent a valid alternative solution with the aim of modifying the prostheses using a reinforced resin capable of adequately resisting masticatory loads. This study evaluates and compares the mechanical robustness and the clinical reliability of these modified prostheses in cases of junctions of one or two contiguous prosthetic teeth. The 6-month follow-up demonstrated the total validity of the method via the absence of significant breakages or detachments in all of the patients analyzed; on the other hand, the prostheses modified using the traditional method and used as controls showed a high incidence of fractures.
Parental Influence and Intergenerational Transmission of Religious Belief, Attitudes, and Practices: Recent Evidence from the United States
Authors: Gemar Adam
Published: October 2023

A traditionally salient topic of empirical investigation in the sociology of religion, this paper seeks to offer a recent investigation into the intergenerational transmission of religion and the parental forms of religious engagement that predict adult engagement with religion. The study of this paper explores the intergenerational transmission of religion, focusing on the parental forms of religious identity and engagement that influence religious identity, beliefs, and practices in adulthood. By analyzing the 2018 GSS dataset in the United States with multiple regression analyses, I found strong parental and childhood influences on adult religiosity, religious service attendance, and belief in God. Indeed, this engagement often mirrors parental engagement for these variables. However, while paternal religious identity often predicts these religious variables, I found that the religious identity and engagement of parents generally do not predict religious identity in adulthood. Ultimately, while these results generally show strong predictive mechanisms of intergenerational transmission, they also illustrate that these relationships are variably dependent on the form of parental and adult religious engagement, and which parent participates or is associated with that engagement.
Rigid Polyethylene Terephthalate Packaging Waste: An Investigation of Waste Composition and Its Recycling Potential in Austria
Authors: Gabriel Viktoria Helene , Schaffernak Andreas , Pfitzner Manuel , Fellner Johann , Tacker Manfred , Apprich Silvia
Published: October 2023

The need for increased recycling of plastic packaging waste (PPW) is apparent from a legal and waste management perspective and, therefore, further waste streams need to be investigated in detail in terms of their recycling potential. Polyethylene terephthalate (PET) PW is already closed-loop recyclable (bottle-to-bottle recycling); however, other rigid PET PW is mainly thermally recovered. Explicit quantitative and qualitative data on rigid PET packaging waste are limited. Therefore, this study investigates the composition and packaging characteristics of rigid PET packaging waste contained in separate waste collection as well as in the mixed PET sorting stream in Austria by conducting a manual sorting analysis. Furthermore, the waste volume is projected, and the recycling potential is extrapolated according to new European recycling rate reporting formats. The results show that approximately 11% of separate collection represents rigid PET packaging waste. Most PW derives from food packaging and is transparent. Contained residues with more than 1% of the total packaging weight might negatively impact the sortability. The applicable net quantity indicator (ALR) amounts to 0.888 at the stage of sorting. The volume of rigid PET PW is extrapolated to 26–36 kt in 2020 with a high-quality recycling rate of 25%, which contributes 2.6% to the Austrian PPW recycling target of 50%.
Conductive Polymer-Based Interactive Shelving System for Real-Time Inventory Management
Authors: Sikkandhar Musafargani , Lim Ruiqi , Damalerio Ramona B. , Toh Wei Da , Cheng Ming-Yuan
Published: October 2023

Stockouts constitute a major challenge in the retail industry. Stockouts are caused by errors related to manual stockkeeping and by the misplacement of items on shelves. Such errors account for up to 4% of lost sales. Real-time inventory management systems for misplaced items or missing stock detection in retail stores are limited. Accordingly, a conductive polymer-based interactive shelving system for real-time inventory management is developed. The system comprises an 80 × 48 sensor array fabricated by screen-printing a piezoresistive carbon-based conductive polymer layer onto gold interdigitated electrodes deposited on a flexible substrate. Each sensing pixel has dimensions of 5 mm × 5 mm and a sensing area of 4 mm × 4 mm. The sensor mat can detect the shape and weight features of stockkeeping units (SKUs), which can then be analyzed by a TensorFlow model for SKU identification. The developed system is characterized for functional resistance range, uniformity, repeatability, and durability. The accuracy of SKU identification achieved using shape features only and the accuracy of SKU identification achieved using both shape and weight features is 95% and 99.2%, respectively. The key novelty of the work is the development of a deep learning-embedded interactive smart shelving system for retail inventory management by using the shape and weight features of SKU. Also, the developed system helps to detect the SKU if they are stacked one over the other. Furthermore, multiple sensor mats implemented on various shelves in a retail store can be modularized and integrated for monitoring under the control of a single PC. Accordingly, the proposed retail inventory tracking system can facilitate the development of automated “humanless” shops.