bluuebunny/crossref_metadata_2025 huggingface dataset:
Zur Reduktion von Pyridin‐Derivaten mit Lithiumaluminiumhydrid
Authors: Bohlmann Ferdinand , Bohlmann Magdalene
Published: June 2010

Werden Pyridin‐Derivate, die in 3‐ und 5‐Stellung Ester‐ oder Cyangruppen tragen, mit Lithiumaluminiumhydrid reduziert, so wird zuerst der Ring angegriffen. Dagegen werden bei 2.4‐ und 6‐substituierten Pyridinen die funktionellen Gruppen reduziert, ohne daß der Kern in Mitleidenschaft gezogen wird. Die Unterschiede lassen sich durch die verschiedene Polarisierung der Pyridin‐Derivate erklären. Bei der katalytischen Hydrierung wurden ähnliche Unterschiede festgestellt.
Synthese des 2‐Vinyl‐ und des 2‐Styryl‐isatogens
Authors: Kröhnke Fritz , Kröhnke Gertraude , Vogt Isolde
Published: June 2010

Es wird die Darstellung des 2‐Vinyl‐ und des 2‐Styryl‐isatogens sowie ihrer Vorprodukte und die Kondensation von Cinnamyl‐pyridinium‐Salzen mit Aldehyden mitgeteilt.
Umphenacylierungen am Pyridinstickstoff
Authors: Kröhnke Fritz , Ellegast Konrad
Published: June 2010

Substituierte Phenacyl‐cyclammonium‐Salze können beim Erhitzen mit Methylketonen unter bestimmten Voraussetzungen den substituierten Phenacylrest gegen den des Methylketons austauschen. Es handelt sich um eine Gleichgewichtsbeziehung, die an ziemlich enge Temperaturgrenzen gebunden ist.
Selektives Bromieren von Methylketonen und Bromierungen mit Bromketonen
Authors: Kröhnke Fritz , Ellegast Konrad
Published: June 2010

Mit ω‐Tribrom‐acetophenon können einige spezifische Bromierungen erfolgreich durchgeführt werden. – Die Arbeit beschäftigt sich ferner mit der selektiven Bromierung von fettaromatischen Ketonen und dem Gleichgewicht bei der Bromierung von Methylketonen.
Über Radikalsalze mit temperaturabhängigem magnetischem Moment
Authors: Kainer Helmuth , Hausser Karl H.
Published: June 2010

Die aus 4.4′‐Dimethoxy‐diphenylamin und Antimonpentachlorid von H. Wieland erhaltene Verbindung ist ein Radikalsalz (χm = + 510·10−6; t = 22°C). Die paramagnetische Susceptibilität folgt nicht dem Curie‐Weissschen Gesetz.
Über Einschlußverbindungen, VI. Mitteil.: Änderung der Redoxpotentiale in Einschlußverbindungen
Authors: Cramer Friedrich
Published: June 2010

Das Redox‐Potential von Methylenblau und Dichlorphenol‐indophenol ist in Einschlußverbindungen erhöht; das Verhalten dieser Verbindungen ähnelt dem des Gelben Fermentes. Einschließende Verbindungen werden als Modelle für Apofermente aufgefaßt.
Zur Konstitution des α‐Pyridoins
Authors: Cramer Friedrich , Krum Werner
Published: June 2010

α‐Pyridoin liegt auch in neutraler und schwach saurer Lösung als reines Endiol vor. Die Endiolform wird durch die Ausbildung innermolekularer Wasserstoffbrücken von den OH‐Gruppen zu den N‐Atomen des Pyridinringes stabïlisiert. Die Wasserstoffbrücken sind sehr stabil und ändern das reaktive Verhalten des Acyloins in entscheidender Weise. – Die sehr empfindlichen K‐Endiolaten des Pyridoins und Furoins wurden isoliert.
Planning for online courses at rural community colleges
Authors: Leist Jay , Travis Jon
Published: June 2010

Rural community colleges often expand their online course offerings in an ad hoc manner. Due to limited resources and competing priorities, the necessary, careful planning for online instruction is often forgotten.
Essential tasks and skills for online community college faculty
Authors: Smith Vernon C.
Published: June 2010

The professional role, tasks, and skills of online community college faculty are evolving. This chapter describes the factors that influence the skill set needed for online faculty to be successful.
Web 2.0 and emerging technologies in online learning
Authors: Diaz Veronica
Published: June 2010

As online learning continues to grow, so do the free or nearly free Web 2.0 and emerging online learning technologies available to faculty and students. This chapter explores the implementation process and corresponding considerations of adapting such tools for teaching and learning. Issues addressed include copyright, intellectual property, support, and privacy.
Potential of social networking sites for distance education student engagement
Authors: Lester Jaime , Perini Michael
Published: June 2010

This chapter explores the potential of social networking sites for increasing student engagement for distance education learners. The authors present a modified student engagement model with a focus on the integration of technology, specifically social networking sites for community college distance education learners. The chapter concludes with challenges and implications for integrating social networking sites in the classroom and on the college level.
Biocatalytic Redox Reactions for Organic Synthesis: Nonconventional Regeneration Methods
Authors: Hollmann Frank , Arends Isabel W. C. E. , Buehler Katja
Published: June 2010

Redox enzymes have tremendous potential as catalysts for preparative organic chemistry. Their usually high selectivity, paired with their catalytic efficiency under mild reaction conditions, makes them potentially very valuable tools for synthesis. The number of interesting monooxygenases, dehydrogenases, reductases, oxidases, and peroxidases is steadily increasing and the tailoring of a given biocatalyst is more and more becoming standard technology. However, their cofactor dependency still represents a major impediment en route to true preparative applicability. Currently, three different approaches to deal with this ‘cofactor challenge’ are being pursued: using whole cells, biomimetic approaches comprising enzymatic cofactor regenerations systems, and ‘unconventional’ nonenzymatic regeneration. The latter technique offers the promise of enabling simple, easily applicable, and robust reaction schemes, for example, by circumventing the ‘cofactor challenge’ and introducing redox power directly to the enzyme’s active sites.
Oxidation Products of Organic Trisulfanes: Molecular Structures and Energies of Various Isomers of the Dimethyltrisulfane Oxides Me2S3O and Me2S3O and of 1,3–tBu2S3O2
Authors: Steudel Ralf , Drozdova Yana
Published: June 2010

Ab initio MO calculations (MP 2/6–311 G**//HF/6–311 G**) have been performed for several isomers (including rotamers) of Me2S3O and Me2S3O2. MeS(O)SSMe exists as five rotamers; the most stable form (1a) has a helical backbone CSSSC with S‐S bond lengths of 206.0 (SIISII) and 212.4 pm (SIISII). The most stable rotamer of MeS‐S(O)SMe (2a), is less stable than 1a by 10.7 kJ mol‐1; it is of Cs, symmetry, while a rotamer of Cs symmetry (2b) is less stable than 2a by only 1.4 kJ mol‐1. Both 2a and 2b are stabilized by O ⃛ H hydrogen bonds. The S‐S bond lengths of 2a are 210.0 and 212.0 pm; the CSSSC chain is not helical (CSSS torsion angles 166.3 and –75.4°). The 1,3‐dioxide MeS(O)‐SS(O)Me (3) has two equivalent chiral centers and exists as diastereomers. The most stable isomer 3a (RR)/(SS) is of C2 symmetry with methyl groups trans to each other; the SO bonds form an angle of about 90°. The meso form 3b is less stable than 3a by 17.2 kJ mol‐1 and the rotamers 3c and 3d are less stable by 25.6 kJ mol‐1 and 28.4 kJ mol‐1, respectively. The trisulfane‐1.2–dioxide MeS(O)‐S(O)SMe has two nonequivalent chiral centers and exists as five isomers. The most stable form, the (RS)/(SR) form 4a, is less stable than 3a by 21.4 kJ mol‐1 and is characterized by SS bonds of 220.9 (SIIISIII) and 208.3 pm (SIIISII). The rotamer 4b is less stable by 5.9 kJ mol‐1. The isomers 4c, 4d, and 4e are all of (SS)/(RR) configuration and are less stable than 4a by 6.3, 12.7, and 12.0 kJ mol‐1. For comparison, ab initio MO calculations (HF/6–311 G*) for tBuS(O)SS(O)‐tBu yielded two diastereomers of practically identically energy that both contain helical CSSSC backbones. The (RS) form is less stable than the (RR)/(SS) form by 1.8 kJ mol‐1.
Hemoprotein Models Based on a Covalent Helix–Heme–Helix Sandwich: 1. Design, Synthesis, and Characterization
Authors: Nastri Flavia , Lombardi Angela , Morelli Giancarlo , Maglio Ornella , D'Auria Gabriella , Pedone Carlo , Pavone Vincenzo
Published: June 2010

In this paper we describe the design, synthesis, and spectroscopic characterization of a covalent helix–heme–helix sandwich named FeIII mimochrome I. It contains deuterohemin bound through both propionyl groups to two identical N‐and C‐terminal protected nonapeptides as α‐helical scaffolds. Each peptide moiety bears a His residue in the central position, which acts as axial ligand to the metal ion. The newly developed synthetic strategy is based on a combination of solution and solid‐phase methodologies. It represents a powerful method for obtaining a large variety of analogues containing two symmetric or unsymmetric peptide chains covalently bound to the deuteroporphyrin ring. UV/Visible spectroscopic characterization in buffered 2,2,2‐trifluoroethanol/water solution proves low‐spin bis(his‐tidine) iron(III) coordination; circular dichroism (CD) measurements show an α‐helical conformation for the peptide moieties. Thus, all the data are in agreement with the designed hypothetical model regarding both the iron(III) coordination and the peptide chain structural organization.
The N3 Position of N9‐Substituted Adenine as a Metal Ion Binding Site: Structural and Solution Studies with PdII and PtII Complexes of N6′, N6′,N 9‐Trimethyladenine
Authors: Meiser Cordula , Song Bin , Freisinger Eva , Peilert Matthias , Sigel Helmut , Lippert Bernhard
Published: June 2010

Steric blockage of the N1 and N7 sites of 9‐methyladenine for metal complexation is achieved by twofold methylation of the exocyclic amino group. With 6′,6′,9‐trimethyladenine (TrimeA), binding of MII(dien) (M = Pt, Pd) as well as of trans‐[Pt(NH3)2Cl]+ therefore takes place through N 3. X‐ray crystal structure determinations and NMR spectroscopic studies of three compounds are reported, and the effects of PtII and PdII on the geometry and the acid‐base properties of the TrimeA ligand have been measured and compared with those of the free base. TrimeA has a very pronounced self‐stacking tendency in water (K85M−1 according to the isodesmic model of indefinite noncooperative self‐association). Acidity constants derived from potentiometric pH titrations, spectrophotometry, and NMR shift experiments display excellent agreement with each other. Twofold protonated TrimeA, that is H2(TrimeA)2+, carries protons at the N7 and N1 sites; the acidity constants are pKHH2(TrimeA) = – 0.75 and pKHH(TrimeA) = 4.15. These values compare well with those of other adenine residues. Protonation of [Pt(dien)‐(TrimeA‐N3)]2+ occurs at the N7 position, as shown by spectrophotometry and NMR spectroscopy. The acidity constant of the H+ (N7) site in this complex is low, that is pKHH[Pt(dien)(TrimeA)] = 0.3 (as determined by spectrophotometry), but it is not as low as that for the same site when a proton resides at N1 of unmetalated TrimeA. The pKa of the doubly protonated complex, pKHH2[Pt(dien)(TrimeA)], in which the second acidic proton is situated at N1, is about–1.2 ± 0.3. These findings indicate that upon metalation of N3, the sequence of adenine protonation is reversed. While the N7 site still displays basic properties, the N1 site has undergone a dramatic loss in basicity.
The Chemical Synthesis of C‐Ring Aryl Taxoids
Authors: Nicolaou K. C. , Claiborne Christopher F. , Paulvannan Kumarapandian , H. D. Postema Maarten , Guy Rodney K.
Published: June 2010

We designed and targeted for synthesis the C‐ring aryl taxoids 2a‐c in order to develop methods for the construction of the taxoid skeleton and to test their cytotoxicity against tumor cells. Compound 2a was synthesized by a convergent route from hydrazone 5 and aldehyde 4. Key steps included a Shapiro reaction to join 5 and 4, a McMurry coupling to construct the 8‐membered ring, a carbonate opening to introduce the 2‐benzoate group, and an allylic oxidation followed by side‐chain attachment. A similar sequence led to compound 2c, whereas attempts to attain 2b were thwarted by the lability of the benzyl group during the carbonate opening. The biological activity of 2a and 2c against tumor cells was considerably less than that of taxol.
Synthesis and Reactions of a Chemical Model of the Urocanase Reaction
Authors: Winter Joachim , Rétey János
Published: June 2010

Using a convergent synthetic strategy starting from nicotinic acid and imidazole, we have prepared the (E) and (Z) isomers of 1‐benzyl‐3‐carbamoyl‐5‐[2‐(ethoxycarbonylmethylene)‐2‐(1‐(p‐to‐lylsulfamoyl)imidazol‐4‐yl)ethyl]pyridinium bromide (21) as models of the urocanase reaction. Domino reactions of both (E)‐21 and (Z)‐21 led to the same spirocyclic compound, (3aRS)‐11‐[9‐([D7]benzyl)‐5‐ethoxy‐1‐(p‐tolylsulfamoyl)‐1H,9H‐furo[2,3‐g]imidazo[5,4‐f]isoquinolyl]carboxamide (33), which was isolated and spectroscopically characterised. A possible sequence of reactions leading to 33 shows a number of analogies to the conversions catalysed by the enzyme urocanase. Removal of the p‐tolylsulfamoyl protecting group of (E)‐21 and (Z)‐21 under mild conditions led to the highly reactive model compounds (E)‐4 and (Z)‐4, which were identified by 1H NMR spectroscopy, but could not be isolated, owing to their instability. To facilitate the monitoring of the reaction cascade by NMR spectroscopy (Z)‐21 was prepared in which the benzyl group was fully deuterated. Its deprotection to (Z)‐4 started a reaction cascade, which led, after purification, to a main product. According to investigations by UV and 1H NMR spectroscopy it seems very likely that 1‐([D7]benzyl)‐3‐carbamoyl‐7‐(ethoxycarbonylmethyl)‐imidazo[4,5‐f]isoquinolinium bromide (27) was formed. The presumed mechanism of its formation again shows similarities with the postulated mechanism of action of urocanase.
A Novel Palladium‐Catalyzed Asymmetric Cyclocarbonylation of Allylic Alcohols to γ‐Butyrolactones
Authors: Yu Wing‐Yiu , Bensimon Corinne , Alper Howard
Published: June 2010

A catalyst system based on [Pd2(dba)3]·CHCl3/(‐)‐BPPM has been found to effect asymmetric cyclocarbonylation of certain prochiral allylic alcohols to produce good yields of optically enriched γ‐butyrolactones. The reaction was performed under an atmosphere of H2 (400 psi) and CO (400 psi) at 100°C in methylene chloride for 48 hours. Asymmetric cyclocarbonylation of allylic alcohols with aliphatic substituents proceeded with moderate enantioselectivities (ee = 25–43%). However, enantiomeric excesses of up to 83% were obtained for substrates containing aromatic substituents, in which case the ee was found to be more sensitive to steric, rather than to electronic factors. Recrystallization of the lactones containing an aromatic group from a mixture of CH2Cl2/Et2O/hexanes (0.5/1.0/8.5), by slow evaporation of the solvent or at low temperature, improved the enantiopurities to >98% ee on a reproducible basis. The asymmetric center of the aromatic lactones was assigned the (S)‐configuration based on the X‐ray crystal structure analysis of enantiopure (S)‐(+)‐3,3‐dimethyl‐2‐(2′‐methylphenyl)‐γ‐butyrolactone (2k). A hydridopalladium intermediate is believed to play a key role in this reaction. Enantioselectivity is thought to be brought about by the preferential formation of 6b. The carbon skeleton of 6b fits into the chiral scaffold of (‐)‐BPPM.
Hetero‐Diels–Alder Reaction with Thiazolyl Oxabutadienes—Model Studies Toward the Synthesis of Directly Linked C‐Disaccharide
Authors: Dondoni Alessandro , Kniezo Ladislav , Martinkova Miroslava , Imrich Jan
Published: June 2010

A method for the construction of substituted pyranoses by means of the hetero‐Diels–Alder (HDA) reaction of ethyl vinyl ether with 1‐oxabuta‐1,3‐dienes bearing a thiazolyl ring at C‐2 is described. The cycloaddition with 1‐(thiazol‐2‐yl)‐2‐penten‐1‐one (2) occurred with good endo/exo selectivity to give cis‐ and trans‐3,4‐dihydro‐2H‐pyrans 3a and 3b in a ca. 9:1 ratio and 91% overall yield. The elaboration of 3a through the conversion of the thiazole ring into the formyl group and reduction of the latter to alcohol, followed by hydroxylation of the double bond through hydroboration–oxidation led to the ethyl 2,3‐dideoxypyranoside 8. The asymmetric version of this synthetic sequence started from the HDA cycloaddition of the same alkene with the chiral oxabutadiene 10 bearing the D‐galacto‐pentopyranosid‐5‐yl moiety at C‐3. This reaction afforded a mixture of the four diastereomeric cycloadducts—3,4‐dihydro‐2H‐pyrans 11a,b and 12a,b—in 97% overall yield. The reaction was moderately endo and face selective. A high level of endo selectivity (96%) was obtained by the use of catalytic Eu(fod)3. The elaboration of the endo cycloadducts 11a and 12a by the same synthetic sequence as that developed for 3a (i.e. thiazolyl‐to‐formyl conversion and hydroxylation of the double bond) gave the uncommon C‐disaccharides 15 and 16 featuring two directly linked pyranose rings.
Axially Chiral Catenanes and π‐Electron‐Deficient Receptors
Authors: Asakawa Masumi , Ashton Peter R. , Boyd Sue E. , Brown Christopher L. , Menzer Stephan , Pasini Dario , Stoddart J. Fraser , Tolley Malcolm S. , White Andrew J. P. , Williams David J. , Wyatt Paul G.
Published: June 2010

The design of a new class of chiral [2]catenanes is reported. The self‐assembly of [2]catenanes comprising one or two 3,3′‐bitolyl spacers in the π‐electron‐deficient component, and bis‐p‐phenylene‐34‐crown‐10 (BPP 34 C 10) as the π‐electron‐rich component, is described. The X‐ray crystal structures, together with solution‐state dynamic1H NMR spectroscopic studies, show that the degree of order characterizing the molecular structures is substantially different from that of the “parent” [2]‐catenane, comprising cyclobis(paraquat‐p‐phenylene) and BPP34C10. When appropriately substituted in theirorthopositions, bitolyl compounds can support axial chirality: the self‐assembly of axially chiral [2]catenanes, comprising one or two 3,3′‐disubstituted‐2,2′‐dihydroxy‐1,1′‐binaphthyl spacers, has been achieved in good yields, showing that the introduction of the bulky, axially chiral spacer and the consequent distortion of the cavity of the π‐electron‐deficient component still permits good molecular recognition between the components leading to efficient catenane production. X‐ray crystallography suggests that this recognition is driven by hydrogen bonding and π‐π stacking interactions between the complementary subunits. The hydroxyl groups on the chiral spacer were further functionalized as benzoyl esters in a [2]catenane as well as in the tetracationic cyclophanes; that is, chemistry can be done on these catenanes. The chiral tetracationic cyclophanes exhibit good enantiomeric differentiation toward the D‐ and L‐enantiomers of aromatic amino acids in water and theirN‐acetylated derivatives in organic solvents.
The Nickel‐Catalyzed Carbonylative Cycloaddition of Allyl Halides and Acetylenes: An Efficient Tool for Cyclopentane Annelation
Authors: del Moral Daniel , Ricart Susagna , Moretó Josep M.
Published: June 2010

From a practical synthetic point of view, the nickel‐mediated carbonylative cycloaddition of alkynes and allyl halides is a straightforward method for obtaining the cyclopentane skeleton in high yields and with controlled stereochemistry, especially when considering the efficiency of the intermolecular version of the reaction. The efforts to make the previously stoichiometric process catalytic in nickel, after experimental mechanistic observations, are reported herein. The unexpected intervention of iron as a reductant and the isolation of a final dimeric species that exhibits interesting tautomeric behavior are also presented. An extension of the reaction to new substrates has led to the conclusion that, although the steric and electronic effects of the alkyne substituents are generally irrelevant in relation to the adducts and their yields, those of the allylic counterpart may have a significant influence on the outcome of the reaction. However, the presence of the amine moiety in the alkyne completely inhibited the reaction. The feasibility of a multicentered reaction was verified with a triacetylene in which up to 12 bonds were created at once and in good yield.
Synthesis of Hierarchical Macro‐/Mesoporous Solid‐Solution Photocatalysts by a Polymerization–Carbonization–Oxidation Route: The Case of Ce0.49Zr0.37Bi0.14O1.93
Authors: Xi Guangcheng , Ye Jinhua
Published: June 2010

A hierarchical macro‐/mesoporous Ce0.49Zr0.37Bi0.14O1.93 solid‐solution network has been synthesized on a large scale by means of a simple and general polymerization–carbonization–oxidation synthetic route. The as‐prepared product has been characterized by SEM, XRD, TEM, BET surface area measurement, UV/Vis diffuse‐reflectance spectroscopy, energy‐dispersive X‐ray spectroscopy (EDS), and photoelectrochemistry measurements. The photocatalytic activity of the product has been demonstrated through the photocatalytic degradation of methyl orange. Structural characterization has indicated that the hierarchical macro‐/mesoporous solid‐solution network not only contains numerous macropores, but also possesses an interior mesoporous structure. The mesopore size and BET surface area of the network have been measured as 2–25 nm and 140.5 m2 g−1, respectively. The hierarchical macro‐/mesoporous solid‐solution network with open and accessible pores was found to be well‐preserved after calcination at 800 °C, indicating especially high thermal stability. Due to its high specific surface area, the synergistic effect of the coupling of macropores and mesopores, and its high crystallinity, the Ce0.49Zr0.37Bi0.14O1.93 solid‐solution material shows a strong structure‐induced enhancement of visible‐light harvest and exhibits significantly improved visible‐light photocatalytic activity in the photodegradation of methyl orange compared with those of its other forms, such as mesoporous hollow spheres and bulk particles.
The Cobalt Way to Angucyclinones: Asymmetric Total Synthesis of the Antibiotics (+)‐Rubiginone B2, (−)‐Tetrangomycin, and (−)‐8‐O‐Methyltetrangomycin
Authors: Kesenheimer Christian , Kalogerakis Aris , Meißner Anja , Groth Ulrich
Published: June 2010

A cobalt(I)‐mediated convergent and asymmetric total synthesis of angucyclinones with an aromatic B ring has been developed. In the course of our research, we synthesized three naturally occurring anguclinone derivatives, namely, (+)‐rubiginone B2(1), (−)‐8‐O‐methyltetrangomycin (2), and (−)‐tetrangomycin (3). By combining 3‐hydroxybenzoic acid, 3‐methoxybenzoic acid, citronellal, and geraniol as starting materials in a convergent way, we were able to synthesize chiral triyne chains, which were cyclized with [CpCo(C2H4)2] (Cp=cyclopentadienyl) by means of an intramolecular [2+2+2] cycloaddition to their corresponding tetrahydrobenzo[a]anthracenes. Successive oxidation and deprotection steps led to the above‐mentioned natural products1–3.
ChemInform Abstract: Local Density Functional Study of Copper Clusters: A Comparison Between Real Clusters, Model Surface Clusters, and the Actual Metal Surface.
Authors: Crispin Xavier , Bureau Christophe , Geskin Victor , Lazzaroni Roberto , Bredas Jean‐Luc
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Polytypism in the Nb3TeI7 System.
Authors: Smith Mark D. , Miller Gordon J.
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Preparation and Crystal Structure of the Ternary Carbides Ln12Os5C15 with Ln: Y, Pr, Nd, Sm, Gd—Tm.
Authors: Huefken Thomas , Wachtmann Klaus H. , Jeitschko Wolfgang
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Neutron Diffraction Studies of the Crystal and Magnetic Structures of PrCu2Sn2 and NdCu2Sn2.
Authors: Baran S. , Hofmann M. , Szytula A.
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: The Structure of Cesium Tellurate(VI) by Combined EXAFS and Powder X‐Ray Diffraction.
Authors: Weller Mark T. , Pack Maria J. , Binsted Norman , Dann Sandra E.
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Phase Equilibria in the Tb—Ti—Ge System at 1070 K.
Authors: Morozkin A. V. , Seropegin Yu. D. , Sviridov I. A. , Moskalev V. A.
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Liquid—Solid Equilibria in the Al‐Rich Corner of the Al—Mn—Cr System.
Authors: Schenk T. , Durand‐Charre M. , Audier M.
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Effect of Cu Powder as an Additive Material on the Inner Pressure of a Sealed‐Type Ni—MH Rechargeable Battery Using a Zr‐Based Alloy as an Anode.
Authors: Kim Dong‐Myung , Lee Ho , Cho Kurn , Lee Jai‐Young
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Identification of Active Crystalline Phase in La‐K‐Cu‐V Mixed Oxide for the Simultaneous Removal of Nitrogen Oxides and Diesel Soot.
Authors: Teraoka Yasutake , Shangguan Wengfeng , Jansson Kjell , Nygren Mats , Kagawa Shuichi
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Preparation of LiTaO3 Powders at Reduced Temperatures by a Polymerized Complex Method.
Authors: Szanics Judit , Okubo Toru , Kakihana Masato
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: The First True Inorganic Fullerenes?
Authors: Parilla P. A. , Dillon A. C. , Jones K. M. , Riker G. , Schulz D. L. , Ginley D. S. , Heben M. J.
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Oligomeric Tetrahedral Anions in Borophosphates: Six‐Membered Rings with Open and Cyclic Phosphate Branchings in the Crystal Structure of K6Cu2 [B4P8O28(OH)6].
Authors: Boy Insan , Cordier Gerhard , Kniep Ruediger
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Bridged 1,6‐Dithienylhexa‐1,3,5‐trienes as Highly Photoluminescent and Stable Thiophene‐Based π‐Conjugated Systems.
Authors: Blanchard Philippe , Brisset Hugues , Riou Amedee , Hierle Rolland , Roncali Jean
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Stereochemical Assignment of Cyano‐Substituted Ozonides by the NMR Spectroscopy.
Authors: Huh Tae Sung
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Enantioselective Alkylation of Lactams and Lactones via Lithium Enolate Formation Using a Chiral Tetradentate Lithium Amide in the Presence of Lithium Bromide.
Authors: Matsuo Jun‐ichi , Kobayashi Shu , Koga Kenji
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Chiral Zirconium‐Catalyzed Asymmetric Mannich‐Type Reactions Using Acylhydrazones as Imine Equivalents.
Authors: Kobayashi Shu , Hasegawa Yoshiki , Ishitani Haruro
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Hydrolysis of 2‐Alkoxyalk‐2‐enals.
Authors: Mamashvili T. N. , Keiko N. A. , Sarapulova G. I. , Voronkov M. G.
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Reaction of α‐Ethoxyacrolein with Diethyl Malonate.
Authors: Keiko N. A. , Chuvashev Yu. A. , Kuznetsova T. A. , Sherstyannikova L. V. , Voronkov M. G.
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Flash Vacuum Pyrolysis of Pyrazoles (I) as an Alternative Way to Study Vinylcarbenes.
Authors: Moyano Elizabeth L. , Yranzo Gloria I. , Elguero Jose
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Organic Synthesis with Anion‐Exchange Resins: Reaction of Imines with Active Methylene Compounds.
Authors: Konwar Dilip , Dutta Dilip Kumar , Goswami Birendra Nath
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: A General Strategy for Five‐Membered Heterocycle Synthesis by Cycloelimination of Alkynyl Ketones, Amides, and Thioamides.
Authors: Wipf Peter , Rahman Leera T. , Rector Stacey R.
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Transition Metal‐Catalyzed Cyclization of 2‐Allylphenol to 2,3‐Dihydro‐2‐methylbenzofuran Without β‐Elimination.
Authors: Hori Kazushige , Kitagawa Hideki , Miyoshi Akio , Ohta Tetsuo , Furukawa Isao
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Synthesis of 4‐Hydroxy‐2‐cyclopentenone Derivatives by [3 + 2] Annulation of β‐Heteroatom‐Substituted Acryloylsilanes and Lithium Enolate of Methyl Ketones.
Authors: Takeda Kei , Ohtani Yasuhiro , Ando Emi , Fujimoto Ken‐ichi , Yoshii Eiichi , Koizumi Toru
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: An Organic Catalytic System for Dehydrogenative Oxidation.
Authors: Hirao Toshikazu , Fukuhara Shinya
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Regioselective Reduction of the Homoisoflavone System with Dialkylboranes in the Presence of Palladium Catalysts.
Authors: Hoshino Yukio , Tanaka Hiroto , Takeno Noboru
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Palladium‐Catalyzed Transfer Hydrogenation of Azobenzenes and Oximes Using Ammonium Formate.
Authors: Jnaneshwara G. K. , Sudalai A. , Deshpande V. H.
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Fast and Selective Homogeneous Hydrogenation with Nickel(II) Phosphane Catalysts.
Authors: Angulo Ingrid M. , Kluwer Alexander M. , Bouwman Elisabeth
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Facile Synthesis of β‐Keto Esters from Methyl Acetoacetate and Acid Chloride: The Barium Oxide/Methanol System.
Authors: Yuasa Yoshifumi , Tsuruta Haruki
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: General Procedure for Acylation of 3° Alcohols: Scandium Triflate/DMAP Reagent.
Authors: Zhao Hong , Pendri Annapurna , Greenwald Richard B.
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: New Facile Alkoxycarbonylating Agent, Alkyl Pyrazole‐1‐carboxylates. The Preparation and the Utilities.
Authors: Kashima Choji , Tsuruoka Shiro , Mizuhara Saori
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Synthesis and Characterization of the Tetrahydroxyphosphonium Hexafluorometalates P(OH)4+MF6‐ (M: As, Sb).
Authors: Minkwitz Rolf , Schneider Stefan
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Crystal Structure and Spectroscopic Characterization of a Green VIV Compound, Na8(VO)2(SO4)6.
Authors: Nielsen Kurt , Boghosian Soghomon , Fehrmann Rasmus , Berg Rolf Willestofte
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Characterization of Na5P3O10 Polymorphs by 23Na MAS, 23Na MQMAS, and 31P MAS NMR Spectroscopy.
Authors: Fyfe Colin A. , Meyer zu Altenschildesche Holger , Skibsted Joergen
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Scaling of Transition Temperature and CuO2 Plane Buckling in a High‐Temperature Superconductor.
Authors: Chmaissem O. , Jorgensen J. D. , Short S. , Knizhnik A. , Eckstein Y. , Shaked H.
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Thermochemistry of Zirconium and Hafnium Pyrophosphates and Pyroarsenates.
Authors: Karyakin N. V. , Chernorukov N. G. , Korytseva A. K. , Chernorukov G. N.
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Electrochemical Synthesis for the Control of γ‐Fe2O3 Nanoparticle Size. Morphology, Microstructure, and Magnetic Behavior.
Authors: Pascal C. , Pascal J. L. , Favier F. , Moubtassim M. L. Elidrissi , Payen C.
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Kinetic Study of MOCVD Fabrication of Copper(I) and Copper(II) Oxide Films.
Authors: Condorelli Guglielmo G. , Malandrino Graziella , Fragala Ignazio L.
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Molecular Growth from a Mo176 to a Mo248 Cluster.
Authors: Mueller A. , Shah Syed Q. N. , Boegge H. , Schmidtmann M.
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: An Oxidatively Coupled Dimer of Paracetamol.
Authors: Clegg William , Teat Simon J. , Prasad Korlakunte V. R. , Ristic Radoljub I. , Sheen David B. , Shepherd Evelyn A. , Sherwood John N. , Vrcelj Ranko M.
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Novel Chiral P,N‐Ferrocene Ligands in Palladium‐Catalyzed Asymmetric Allylic Alkylations.
Authors: Zhang Wanbin , Yondea Yoh‐ichi , Kida Toshiyuki , Nakatsuji Yohji , Ikeda Isao
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Palladium‐Catalyzed Allylic Alkylation Using Pyridino‐Oxazolines and Quinolino‐Oxazolines as Ligands — Influence of Steric Factors.
Authors: Bremberg Ulf , Rahm Fredrik , Moberg Christina
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Synthesis of Enantiomerically Pure (R)‐ and (S)‐2‐Ethoxycarbonylmethyl‐2‐hydroxy‐cyclohexanones.
Authors: Garcia Ruano Jose L. , Barros David , Maestro M. Carmen , Alcudia Ana , Fernandez Inmaculada
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Bis(oxazoline) Derived Cationic Aqua Complexes: Highly Effective Catalysts for Enantioselective Diels—Alder Reactions.
Authors: Ghosh Arun K. , Cho Hanna , Cappiello John
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Synthesis and Diels—Alder Reaction of Acetylenic Sulfonate.
Authors: Lee Albert W. M. , Chan W. H. , Zhong Z. P. , Lee K. F. , Yeung Anissa B. W.
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Synthesis of Spiro Ethers by Ring Closing Metathesis.
Authors: Maier Martin E. , Bugl Michael
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Selective Dehydrogenation of Isopropanol on Low‐Percentage Supported Bimetallic Rhenium‐Containing Catalysts.
Authors: Ryashentseva M. A.
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Enantioselective Hydrogenation of Olefins with Iridium—Phosphanodihydrooxazole Catalysts.
Authors: Lightfoot Andrew , Schnider Patrick , Pfaltz Andreas
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: The Formation of a Novel Pd/C—Ethylenediamine Complex Catalyst: Chemoselective Hydrogenation Without Deprotection of the O‐Benzyl and N‐Cbz Groups.
Authors: Sajiki Hironao , Hattori Kazuyuki , Hirota Kosaku
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: 1H‐Benzotriazol‐1‐yl Methanesulfonate: A Regioselective N‐Mesylating Reagent.
Authors: Kim Sun Young , Sung Nack‐Do , Choi Joong‐Kwon , Kim Sung Soo
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Carbonyl Olefination by Means of a gem‐Dichloride—Cp2Ti[P(OEt)3]2 System.
Authors: Takeda Takeshi , Sasaki Rika , Fujiwara Tooru
Published: June 2010

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.