bluuebunny/crossref_metadata_2025 huggingface dataset:
Optimization of Tilmicosin-Loaded Nanostructured Lipid Carriers Using Orthogonal Design for Overcoming Oral Administration Obstacle
Authors: Wen Jia , Gao Xiuge , Zhang Qian , Sahito Benazir , Si Hongbin , Li Gonghe , Ding Qi , Wu Wenda , Nepovimova Eugenie , Jiang Shanxiang , Wang Liping , Kuca Kamil , Guo Dawei
Published: February 2021

Tilmicosin (TMS) is widely used to treat bacterial infections in veterinary medicine, but the clinical effect is limited by its poor solubility, bitterness, gastric instability, and intestinal efflux transport. Nanostructured lipid carriers (NLCs) are nowadays considered to be a promising vector of therapeutic drugs for oral administration. In this study, an orthogonal experimental design was applied for optimizing TMS-loaded NLCs (TMS-NLCs). The ratios of emulsifier to mixed lipids, stearic acid to oleic acid, drugs to mixed lipids, and cold water to hot emulsion were selected as the independent variables, while the hydrodynamic diameter (HD), drug loading (DL), and entrapment efficiency (EE) were the chosen responses. The optimized TMS-NLCs had a small HD, high DL, and EE of 276.85 ± 2.62 nm, 9.14 ± 0.04%, and 92.92 ± 0.42%, respectively. In addition, a low polydispersity index (0.231 ± 0.001) and high negative zeta potential (−31.10 ± 0.00 mV) indicated the excellent stability, which was further demonstrated by uniformly dispersed spherical nanoparticles under transmission electron microscopy. TMS-NLCs exhibited a slow and sustained release behavior in both simulated gastric juice and intestinal fluid. Furthermore, MDCK-chAbcg2/Abcb1 cell monolayers were successfully established to evaluate their absorption efficiency and potential mechanism. The results of biodirectional transport showed that TMS-NLCs could enhance the cellular uptake and inhibit the efflux function of drug transporters against TMS in MDCK-chAbcg2/Abcb1 cells. Moreover, the data revealed that TMS-NLCs could enter the cells mainly via the caveolae/lipid raft-mediated endocytosis and partially via macropinocytosis. Furthermore, TMS-NLCs showed the same antibacterial activity as free TMS. Taken together, the optimized NLCs were the promising oral delivery carrier for overcoming oral administration obstacle of TMS.
Enhanced Stability of Indocyanine Green by Encapsulation in Zein-Phosphatidylcholine Hybrid Nanoparticles for Use in the Phototherapy of Cancer
Authors: Lee Eun-Hye , Lee Mi-Kyung , Lim Soo-Jeong
Published: February 2021

Indocyanine green (ICG) is a clinically approved near-infrared dye that has shown promise as a photosensitizer for the phototherapy of cancer. However, its chemical instability in an aqueous solution has limited its clinical application. Encapsulating ICG in liposomes, phosphatidylcholine nanoparticles (PC-NP), has shown partial effectiveness in stabilizing it. Prompted by our recent finding that the zein-phosphatidylcholine hybrid nanoparticles (Z/PC-NP) provide an advanced drug carrier compared to PC-NP, we herein investigated the potential of Z/PC-NP as an improved ICG formulation. Dynamic light scattering analysis, transmission electron microscopy, and Fourier-transform infrared spectroscopy studies showed that ICG was encapsulated in Z/PC-NP without hampering the high colloidal stability of the Z/PC-NP. During storage, the Z/PC-NP almost completely inhibited the ICG aggregation, whereas the PC-NP did so partially. The Z/PC-NP also more effectively blocked the ICG degradation compared to the PC-NP. The phototoxicity of ICG encapsulated in Z/PC-NP on cancer cells was twofold higher than that in the PC-NP. The ICG encapsulated in Z/PC-NP, but not in PC-NP, maintained its photocytotoxicity after four-day storage. These findings highlight the promising potential of Z/PC-NP as an ICG formulation that provides a higher stabilization effect than PC-NP.
Cationic Cellulose Nanocrystals-Based Nanocomposite Hydrogels: Achieving 3D Printable Capacitive Sensors with High Transparency and Mechanical Strength
Authors: Lai Po-Cheng , Yu Sheng-Sheng
Published: February 2021

Hydrogel ionotronics are intriguing soft materials that have been applied in wearable electronics and artificial muscles. These applications often require the hydrogels to be tough, transparent, and 3D printable. Renewable materials like cellulose nanocrystals (CNCs) with tunable surface chemistry provide a means to prepare tough nanocomposite hydrogels. Here, we designed ink for 3D printable sensors with cationic cellulose nanocrystals (CCNCs) and zwitterionic hydrogels. CCNCs were first dispersed in an aqueous solution of monomers to prepare the ink with a reversible physical network. Subsequent photopolymerization and the introduction of Al3+ ion led to strong hydrogels with multiple physical cross-links. When compared to the hydrogels using conventional CNCs, CCNCs formed a stronger physical network in water that greatly reduced the concentration of nanocrystals needed for reinforcing and 3D printing. In addition, the low concentration of nanofillers enhanced the transparency of the hydrogels for wearable electronics. We then assembled the CCNC-reinforced nanocomposite hydrogels with stretchable dielectrics into capacitive sensors for the monitoring of various human activities. 3D printing further enabled a facile design of tactile sensors with enhanced sensitivity. By harnessing the surface chemistry of the nanocrystals, our nanocomposite hydrogels simultaneously achieved good mechanical strength, high transparency, and 3D printability.
Polystyrene-Based Hydroxide-Ion-Conducting Ionomer: Binder Characteristics and Performance in Anion-Exchange Membrane Fuel Cells
Authors: Chae Ji Eon , Lee So Young , Yoo Sung Jong , Kim Jin Young , Jang Jong Hyun , Park Hee-Young , Park Hyun Seo , Seo Bora , Henkensmeier Dirk , Song Kwang Ho , Kim Hyoung-Juhn
Published: February 2021

Polystyrene-based polymers with variable molecular weights are prepared by radical polymerization of styrene. Polystyrene is grafted with bromo-alkyl chains of different lengths through Friedel–Crafts acylation and quaternized to afford a series of hydroxide-ion-conducting ionomers for the catalyst binder for the membrane electrode assembly in anion-exchange membrane fuel cells (AEMFCs). Structural analyses reveal that the molecular weight of the polystyrene backbone ranges from 10,000 to 63,000 g mol−1, while the ion exchange capacity of quaternary-ammonium-group-bearing ionomers ranges from 1.44 to 1.74 mmol g−1. The performance of AEMFCs constructed using the prepared electrode ionomers is affected by several ionomer properties, and a maximal power density of 407 mW cm−2 and a durability exceeding that of a reference cell with a commercially available ionomer are achieved under optimal conditions. Thus, the developed approach is concluded to be well suited for the fabrication of next-generation electrode ionomers for high-performance AEMFCs.
Novel Hydrogels of Chitosan and Poly(vinyl alcohol) Reinforced with Inorganic Particles of Bioactive Glass
Authors: Sánchez-Aguinagalde O. , Lejardi Ainhoa , Meaurio Emilio , Hernández Rebeca , Mijangos Carmen , Sarasua Jose-Ramon
Published: February 2021

Chitosan (CS) and poly(vinyl alcohol) (PVA) hydrogels, a polymeric system that shows a broad potential in biomedical applications, were developed. Despite the advantages they present, their mechanical properties are insufficient to support the loads that appear on the body. Thus, it was proposed to reinforce these gels with inorganic glass particles (BG) in order to improve mechanical properties and bioactivity and to see how this reinforcement affects levofloxacin drug release kinetics. Scanning electron microscopy (SEM), X-ray diffraction (XRD), swelling tests, rheology and drug release studies characterized the resulting hydrogels. The experimental results verified the bioactivity of these gels, showed an improvement of the mechanical properties and proved that the added bioactive glass does affect the release kinetics.
Improvement of the Centrifugal Force in Gravity Driven Method for the Fabrication of Highly Ordered and Submillimeter-Thick Colloidal Crystal
Authors: Chen Ting-Hui , Huang Shuan-Yu , Huang Syuan-Yi , Lin Jia-De , Huang Bing-Yau , Kuo Chie-Tong
Published: February 2021

In this paper, we propose a modified gravity method by introducing centrifugal force to promote the stacking of silica particles and the order of formed colloidal crystals. In this method, a monodispersed silica colloidal solution is filled into empty cells and placed onto rotation arms that are designed to apply an external centrifugal force to the filled silica solution. When sample fabrication is in progress, silica particles are forced toward the edges of the cells. The number of defects in the colloidal crystal decreases and the structural order increases during this process. The highest reflectivity and structural order of a sample was obtained when the external centrifugal force was 18 G. Compared to the samples prepared using the conventional stacking method, samples fabricated with centrifugal force possess higher reflectivity and structural order. The reflectivity increases from 68% to 90%, with an increase in centrifugal force from 0 to 18 G.
Role of Electrospinning Parameters on Poly(Lactic-co-Glycolic Acid) and Poly(Caprolactone-co-Glycolic acid) Membranes
Authors: Herrero-Herrero María , Gómez-Tejedor José Antonio , Vallés-Lluch Ana
Published: February 2021

Poly(lactic-co-glycolic acid) (PLGA) and poly(caprolactone-co-glycolic acid) (PCLGA) solutions were electrospun into membranes with tailored fiber diameter of 1.8 μm. This particular fiber diameter was tuned depending on the used co-polymer by adjusting the electrospinning parameters that mainly influence the fiber diameter. The greatest setting of the fiber diameter was achieved by varying the polymer solution parameters (polymer concentration, solvents and solvents ratio). PLGA was adequately electrospun with 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP), whereas PCLGA required a polar solvent (such as chloroform) with a lower dielectric constant. Moreover, due to the amorphous morphology of PCLGA, pyridine as salt had to be added to the starting solution to increase its conductivity and make it electrospinnable. Indeed, the electrospinning of this co-polymer presents notable difficulties due to its amorphous structure. Interestingly, PCLGA, having a higher glycolic acid molar fraction than commonly electrospun co-polymers (caprolactone:glycolic acid ratio of 45:55 instead of 90:10), could be successfully electrospun, which has not been reported to date. To an accurate setting of fiber diameter, the voltage and the distance from needle to collector were varied. Finally, the study of the surface tension, conductivity and viscosity of the polymer solutions allowed to correlate these particular characteristics of the solutions with the electrospinning variables so that prior knowledge of them enables predicting the required processing conditions.
Antibacterial Activity of Chitosan–Polylactate Fabricated Plastic Film and Its Application on the Preservation of Fish Fillet
Authors: Chang Shun-Hsien , Chen Ying-Ju , Tseng Hsiang-Jung , Hsiao Hsin-I , Chai Huey-Jine , Shang Kuo-Chung , Pan Chorng-Liang , Tsai Guo-Jane
Published: February 2021

This research prepared chitosan–PLA plastic films by extrusion, analyzed the physical and mechanical properties and antibacterial activity of the fabricated plastic films, and used them to preserve grouper fillet. We added chitosan (220 kDa, 93% DD) in the weight ratio of 0.5–2% into the PLA to prepare the chitosan–PLA films. With the increasing chitosan dosage, both the water vapor transmission rate and moisture content of chitosan–PLA films increased. Among the three doses of chitosan (0.5%, 1%, and 2%) added to PLA, 0.5% chitosan–PLA film had the highest antibacterial activity. This plastic film had an inhibitory efficiency of over 95% against Escherichia coli, Pseudomonas fluorescens, and Staphylococcus aureus. The action of covering the fish fillet with 0.5% chitosan–PLA film significantly reduced several microbes’ counting (i.e., mesophiles, psychrophiles, coliforms, Pseudomonas, Aeromonas, and Vibrio) and total volatile basic nitrogen (TVBN) value in the grouper fillets stored at 4 °C. Thus, such action prolongs the fish fillets’ shelf life to up to at least nine days, and this 0.5% chitosan–PLA film shows promising potential for preserving refrigerated fish.
Optimization Shape-Memory Situations of a Stimulus Responsive Composite Material
Authors: Lin Wei-Chun , Fan Fang-Yu , Cheng Hsing-Chung , Lin Yi , Shen Yung-Kang , Lai Jing-Shiuan , Wang Liping , Ruslin Muhammad
Published: February 2021

In these times of Industrial 4.0 and Health 4.0, people currently want to enhance the ability of science and technology, to focus on patient aspects. However, with intelligent, green energy and biomedicine these days, traditional three-dimensional (3D) printing technology has been unable to meet our needs, so 4D printing has now arisen. In this research, a shape-memory composite material with 3D printing technology was used for 4D printing technology. The authors used fused deposition modeling (FDM) to print a polylactic acid (PLA) strip onto the surface of paper to create a shape-memory composite material, and a stimulus (heat) was used to deform and recover the shape of this material. The deformation angle and recovery angle of the material were studied with various processing parameters (heating temperature, heating time, pitch, and printing speed). This research discusses optimal processing related to shape-memory situations of stimulus-responsive composite materials. The optimal deformation angle (maximum) of the stimulus-responsive composite material was found with a thermal stimulus for an optimal heating temperature of 190 °C, a heating time of 20 s, a pitch of 1.5 mm, and a printing speed of 80 mm/s. The optimal recovery angle (minimum) of this material was found with a thermal stimulus for an optimal heating temperature of 170 °C, a heating time of 90 s, a pitch of 2.0 mm, and a printing speed of 80 mm/s. The most important factor affecting both the deformation and recovery angle of the stimulus-responsive composite material was the heating temperature.
Catalytic Pyrolysis Kinetic Behavior and TG-FTIR-GC–MS Analysis of Metallized Food Packaging Plastics with Different Concentrations of ZSM-5 Zeolite Catalyst
Authors: Eimontas Justas , Striūgas Nerijus , Abdelnaby Mohammed Ali , Yousef Samy
Published: February 2021

Recently, the pyrolysis process has been adapted as a sustainable strategy to convert metallized food packaging plastics waste (MFPW) into energy products (paraffin wax, biogas, and carbon black particles) and to recover aluminum. Usually, catalysts are used in pyrolysis treatment to refine pyrolysis products and to increase their yield. In order to study the effect of a catalyst on the formulated volatile products, this work aims to study the pyrolysis behavior of MFPW in presence of catalyst, using TG-FTIR-GC–MS system. The pyrolysis experiments were conducted with ZSM-5 Zeolite catalyst with different concentrations (10, 30, and 50 wt.%) at different heating rates (5, 10, 15, 20, 25, and 30 °C/min). In addition, TG-FTIR system and GC-MS unit were used to observe and analyze the thermal and chemical degradation of the obtained volatile compounds at maximum decomposition peaks. In addition, the kinetic results of catalytic pyrolysis of ZSM-5/MFPW samples matched when model-free methods, a distributed activation energy model (DAEM), and an independent parallel reaction kinetic model (IPR) were used. The TGA-DTG results showed that addition of a catalyst did not have a significant effect on the features of the TGA-DTG curves with similar weight loss of 87–90 wt.% (without taking the weight of the catalyst into account). Meanwhile, FTIR results manifested strong presence of methane and high-intensity functional group of carboxylic acid residues, especially at high concentration of ZSM-5 and high heating rates. Likewise, GC-MS measurements showed that Benzene, Toluene, Hexane, p-Xylene, etc. compounds (main flammable liquid compounds in petroleum oil) generated catalysts exceeding 50%. Finally, pyrolysis kinetics showed that the whole activation energies of catalytic pyrolysis process of MFPW were estimated at 289 kJ/mol and 110, 350, and 174 kJ/mol for ZSM-5/MFPW samples (10, 30, and 50 wt.%, respectively), whereas DAEM and IPR approaches succeeded to simulate TGA and DTG profiles with deviations below <1.
Is the Polylactic Acid Fiber in Green Compost a Risk for Lumbricus terrestris and Triticum aestivum?
Authors: Huerta-Lwanga Esperanza , Mendoza-Vega Jorge , Ribeiro Oriana , Gertsen Henny , Peters Piet , Geissen Violette
Published: February 2021

Polylactic acid (PLA) bioplastic was introduced to the market as an environmentally friendly potential solution for plastic pollution. However, the effects of bioplastic debris mixed with composts on soil macroinvertebrates, plant growth and soil conditions are still unknown. Soil macroinvertebrates are soil health indicators. A reduction in their abundance is a sign of soil degradation. The objectives of this study were (i) to assess PLA debris in greenhouse composts, and (ii) to test the ecotoxicological effects of PLA debris mixed with compost on Lumbricus terrestris, a soil organism model, and on Triticum aestevium, a plant growth model. The study was comprised of three stages: (1) determine the PLA debris size distribution in composts; (2) assess the ecotoxicological effects of real-world concentrations (0% to 5%) of PLA mixed with compost on earthworm mortality and reproduction; and (3) assess the influence of compost mixed with real-world PLA concentrations on plant growth and physicochemical soil conditions. One percent of PLA debris was found in green composts, 40% of composted PLA debris measured between 1–10 mm, with a concentration of 82.8 ± 17.4 microplastics.gram−1 compost. A concentration of 1% PLA in composts resulted in significant mortality in earthworms. No significant effects of PLA mixed with composts were observed on plant growth or soil physicochemical conditions. Further studies are required in order to test the effect of this biopolymer on different earthworm and plant’ species.
Polypropylene/Ethylene—And Polar—Monomer-Based Copolymers/Montmorillonite Nanocomposites: Morphology, Mechanical Properties, and Oxygen Permeability
Authors: Castro-Landinez Juan Felipe , Salcedo-Galan Felipe , Medina-Perilla Jorge Alberto
Published: February 2021

This research reports the influence of polar monomer contents in ethylene vinyl acetate copolymer (EVA) and ethylene vinyl alcohol copolymer (EVOH) on the morphology, mechanical and barrier properties of polypropylene/ethylene copolymer (PP) reinforced with organically modified montmorillonite (MMT). PP/EVA and PP/EVOH (75/25 wt %) blends were reinforced with 3 wt % MMT in an internal mixer system. Samples were compression-molded into films of 300μ μm. The structural characterization was made using X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM), the mechanical properties were obtained by tension tests and the barrier properties by oxygen transmission rate (OTR). XRD patterns showed a combination of intercalated/exfoliated morphologies for the MMT, with higher d-001 interplanar distance increments for the blends with higher content of polar functional groups. SEM and TEM micrographs complement the results of the XRD analysis and show differences in the morphologies depending on the miscibility of the polyolefin and the polar monomer copolymer. Mechanical properties and oxygen permeability of composites exhibited a higher improvement, by the addition of MMT, for higher intermolecular interactions and most miscible polymeric system of the EVA. These results show that the higher the number of interactions, given by the VA or OH polar functional groups, the morphology and the miscibility between polyolefin and copolymer imply dispersion improvements of the nanocomposites and, in consequence, a higher improvement on the mechanical and barrier properties of the composite material.
Experimental Analysis of Heat-Affected Zone (HAZ) in Laser Cutting of Sugar Palm Fiber Reinforced Unsaturated Polyester Composites
Authors: Masoud Fathi , Sapuan S. M. , Ariffin Mohd Khairol Anuar Mohd , Nukman Y. , Bayraktar Emin
Published: February 2021

In this paper, the influence of processing input parameters on the heat-affected zone (HAZ) of three different material thicknesses of sugar palm fiber reinforced unsaturated polyester (SPF-UPE) composites cut with a CO2 laser was investigated. Laser power, traverse speed, and gas pressure were selected as the most influential input parameters on the HAZ to optimize the HAZ response with fixing all of the other input parameters. Taguchi’s method was used to determine the levels of parameters that give the best response to the HAZ. The significance of input parameters was also determined by calculating the max–min variance of the average of the signal-to-noise ratio (S/N) ratio for each parameter. Analysis of variation (ANOVA) was used to determine each input parameter’s contribution to the influence on HAZ depth. The general results show that the minimum levels of laser power and the highest levels of traverse speed and gas pressure gave the optimum response to the HAZ. Gas pressure had the most significant effect on the HAZ, with contribution decreases as the material thickness increased, followed by the traverse speed with contribution increases with the increase in material thickness. Laser power came third, with a minimal contribution to the effect on the HAZ, and it did not show a clear relationship with the change in material thickness. By applying the optimum parameters, the desired HAZ depth could be obtained at relatively low values.
Impact of Top Electrodes on the Nonvolatile Resistive Switching Properties of Citrus Thin Films
Authors: Lin Kai-Wen , Wang Ting-Yun , Chang Yu-Chi
Published: February 2021

Natural citrus thin films on an indium tin oxide (ITO)/glass substrate were synthesized using the solution method for resistive random access memory (RRAM) applications. The results indicated that the citrus memory device possessed stable resistive switching behavior. For a clear understanding of the role of the interface reaction between the top metal electrode and the citrus film, we investigated the influences of various top electrode (TE) materials on the resistive switching in TE/citrus/ITO devices. In comparison with Au/citrus/ITO and Ti/citrus/ITO devices, the Al/citrus/ITO device can be reproduced with a DC voltage of more than 100 times while only showing a slight decrease in the ON/OFF ratio. In addition, the Al/citrus/ITO device exhibited a high ON/OFF ratio of over 104 and an outstanding uniformity, which was attributed to the fast formation of a native oxide layer (AlOx), as confirmed by the line scan analysis. This indicated that the interface layer, created by the redox reaction between the Al electrode and citrus film, played an important role in the resistive switching properties of TE/citrus/ITO structures. These findings can serve as design guidelines for future bio-based RRAM devices.
Optimizing Flame Retardancy and Durability of Melamine-Formaldehyde/Solid-Urban-Waste Composite Panels
Authors: Esposito Corcione Carola , Ferrari Francesca , Striani Raffaella , Dubrulle Laura , Visconti Paolo , Zammarano Mauro , Greco Antonio
Published: February 2021

In our previous study, an innovative method for sterilization, inertization, and valorization of the organic fraction of municipal solid waste (OFMSW), to be recycled in the production of composite panels, was developed. In this follow-up work, the effects of fire retardants on fire performance, durability, and the mechanical properties of the composite panels based on OFMSW and melamine-formaldehyde resin were investigated. The performance of panels without fire retardants (control panels) was compared to panels containing either mono-ammonium phosphate (PFR) or aluminium trihydrate (ATH) at a mass fraction of 1% and 10% (modified panels). As shown by cone calorimetry, the total heat released was already low (about 31 MJ/m2 at 50 kW/m2) in the control panels, further decreased in the modified panels with the addition of fire retardants, and reached the lowest value (about 1.4 MJ/m2) with 10% mass fraction of PFR. Hence, the addition of fire retardants had a beneficial effect on the response to fire of the panels; however, it also reduced the mechanical properties of the panels as measured by flexural tests. The deterioration of the mechanical properties was particularly obvious in panels containing 10% mass fraction of fire retardants, and they were further degraded by artificial accelerated weathering, carried out by boiling tests. Ultimately, the panels containing PFR at a mass fraction of 1% offered the best balance of fire resistance, durability, and mechanical performance within the formulations investigated in this study.
The Development of Efficient Contaminated Polymer Materials Shredding in Recycling Processes
Authors: Flizikowski Józef , Kruszelnicka Weronika , Macko Marek
Published: February 2021

Recently, a dynamic increase in the number of polymer elements ending their life cycle has been observed. There are three main ways of dealing with polymer waste: reuse in an unchanged form, recycling (both material and energy), and disposal (mainly in the form of landfilling or incineration). The legislation of European countries promotes in particular two forms of waste management: reuse and recycling. Recycling processes are used to recover materials and energy especially from contaminated waste, which are structurally changed by other materials, friction, temperature, machine, process, etc. The recycling of polymers, especially of multi-plastic structural elements, requires the use of special technological installations and a series of preparatory operations, including crushing and separating. Due to the universality and necessity of materials processing in recycling engineering, in particular size reduction, the aim of this study is to organize and systematize knowledge about shredding in the recycling process of end-of-life polymeric materials. This could help properly design these processes in the context of sustainable development and circular economy. Firstly, an overview of the possibilities of end-of-life plastics management was made, and the meaning of shredding in the end-of-life pathways was described. Then, the development of comminution in recycling processes was presented, with special emphasis given to quasi-cutting as the dominant mode of comminution of polymeric materials. The phenomenon of quasi-cutting, as well as factors related to the material, the operation of the shredding machine, and the technological process affecting it were described. Research conducted on quasi-cutting as a phenomenon when cutting single material samples and quasi-cutting as a machine process was characterized. Then, issues regarding recycling potentials in the context of shredding were systematized. Considerations included the areas of material, technical, energy, human, and control potentials. Presented bases and models can be used to support the innovation of creative activities, i.e., environmentally friendly actions, that produce specific positive environmental results in the mechanical processing of recycled and reused materials. The literature survey indicates the need to explore the environmental aspect of the shredding process in recycling and connect the shredding process variables with environmental consequences. This will help to design and control the processes to get the lowest possible environmental burdens.
Enhancing Lignin Dissolution and Extraction: The Effect of Surfactants
Authors: Melro Elodie , Valente Artur J. M. , Antunes Filipe E. , Romano Anabela , Medronho Bruno
Published: February 2021

The dissolution and extraction of lignin from biomass represents a great challenge due to the complex structure of this natural phenolic biopolymer. In this work, several surfactants (i.e., non-ionic, anionic, and cationic) were used as additives to enhance the dissolution efficiency of model lignin (kraft) and to boost lignin extraction from pine sawdust residues. To the best of our knowledge, cationic surfactants have never been systematically used for lignin dissolution. It was found that ca. 20 wt.% of kraft lignin is completely solubilized using 1 mol L−1 octyltrimethylammonium bromide aqueous solution. A remarkable dissolution efficiency was also obtained using 0.5 mol L−1 polysorbate 20. Furthermore, all surfactants used increased the lignin extraction with formic acid, even at low concentrations, such as 0.01 and 0.1 mol L−1. Higher concentrations of cationic surfactants improve the extraction yield but the purity of extracted lignin decreases.
Mechanical Response and Analysis of Cracking Process in Hybrid TRM Composites with Flax Textile and Curauá Fibres
Authors: Ferrara Giuseppe , Pepe Marco , Toledo Filho Romildo Dias , Martinelli Enzo
Published: February 2021

In recent years, the use of plant fibres in Textile-Reinforced Mortar (TRM) composites emerged as a valuable solution to increase their sustainability. Several studies carried out to mechanically characterize the so-called Natural TRMs, although showing promising results, also emphasised some drawbacks due to a severe deformability of the system and to durability issues. This study aims at improving the mechanical behaviour of Natural TRMs including impregnated flax textile (Flax TRMs) by the addition of short curauá fibres within the matrix. Flax TRM specimens were tested in tension to assess the influence of the fibre-reinforced mortar on the composite response. The crack pattern developed during the test was investigated via Digital Image Correlation analysis and by means of an analytical simplified model proposed by the authors. The addition of curauá fibres resulted in a denser crack pattern and in a significant decrease of the mean crack width (around 20%). The overall tensile response of Flax TRMs including curauá fibres resulted closer to the ideal three-linear behaviour of strain-hardening TRM composites with respect to the conventional Flax TRMs by also presenting an increase of dissipated energy of around 45%. This study paves the way for further analysis aimed at enhancing the mechanical performance of Natural TRMs adopting sustainable improvement techniques.
Water-Borne ZnO/Acrylic Nanocoating: Fabrication, Characterization, and Properties
Authors: Vu Tien Viet , Nguyen Thien Vuong , Tabish Mohammad , Ibrahim Sehrish , Hoang Thi Huong Thuy , Gupta Ram K. , Dang Thi My Linh , Nguyen Tuan Anh , Yasin Ghulam
Published: February 2021

This work aims to explore how ZnO nanoparticles enhance the mechanical, photoaging, and self cleaning properties of water borne acrylic coating. Micro/nano ZnO particles (at 2 wt.% of total solid resin) were dispersed into the acrylic polymer matrices using ultrasonication to understand the effect of the size of the coating properties. The effect of ZnO particles on the properties of composite coatings (25 µm of thick) have been evaluated through various tests, such as abrasion measurement, ultraviolet/condensation (UV/CON) weathering aging, and methylene blue self cleaning. Experimental data indicated that the incorporation of ZnO particles enhanced both abrasion resistance and methylene blue removal efficiency of the water borne acrylic coatings, with nano ZnO particles being the best. However, the weathering degradation of nanocomposite coatings was more severe as compared to the coating with micro ZnO (at the same ZnO content).
‘Biker Revs’ on Pilgrimage: Motorbiking Vicars Visiting Sacred Sites
Authors: Dowson Ruth
Published: February 2021

In April 2014, a new Church of England diocese was instituted, combining three smaller dioceses covering a large area of Yorkshire. To mark the development of this new ‘mega-diocese’, a group of motorcycling vicars began to meet regularly and undertake ‘rides out’ across the diocese and further afield. This paper explores research undertaken with these motorbiking priests and their companions. The study followed an ethnographic approach, as the researcher is an ordained clergyperson embedded within the ‘Biker Revs’ community, though not a biker. The research comprised semi-structured interviews and informal conversations with the Biker Revs over several years. This research investigates the Biker Revs’ experiences and motivations for undertaking pilgrimages together, by motorbike. On these performative journeys, the Biker Revs initially visited sacred sites across the United Kingdom. As a basis for comparison, this paper utilizes Michalowski and Dubisch’s 2001 iconic ethnographic research on an American motorcycle pilgrimage, to analyze the group’s activities. The ordained bikers identified the group as a safe space for clergy, outside their parishes, whilst their spouses recognized the benefits of spending time with ‘others like me who understand the pressures of clergy life’. For some participants these pilgrimages provide a religious retreat, as together, they explore sacred landscapes and learn the stories of their holy destinations.
Investigating Pre-Competition-Related Discrete Emotions and Unaccustomed Religious Coping among Elite Student-Athletes: Implications for Reflexive Practice
Authors: Hagan John Elvis
Published: February 2021

Given that elite athletes experience a wide range of different emotions (e.g., anxiety, anger, dejection, excitement) toward upcoming sporting environments, it is surprising that researchers have given limited attention to the linkages between varied emotional experiences and diverse coping (unaccustomed) among athletes from diverse backgrounds. This study investigated the impact of religious coping, as opposed to conventional psychological skills, to ascertain whether these coping options influence elite student-athletes’ emotional reactions across gender, competitive status, and religion. Using a descriptive cross-sectional survey design, self-reported discrete emotions and religious coping were measured with the Sport Emotion Questionnaire (SEQ) and Brief-Religious Coping Scale (Brief RCOPE) after 300 selected athletes were conveniently chosen. A factorial multivariate analysis of covariance (MANCOVA) after controlling for age revealed no significant interactions for between-subject factors (gender, status, religion) across all the discrete emotions and religious coping dimensions. However, significant main effects were realized for competitive status and religion on only anger, anxiety, dejection, and negative religious coping. A follow-up multiple regression analysis identified religion as the most significant predictor of anger, anxiety, and dejection, whereas competitive status was the most associated variable for negative religious coping. Current findings suggest that athletes’ unpleasant or negative emotions were linked to negative religious coping, a maladaptive coping mechanism that may hinder attaining optimal emotional state prior to competition. Therefore, these athletes need purposeful strategies (e.g., positive religious coping, motivational strategies) that may improve weakened beliefs based on their struggles before competition. The development of appropriate psychological intervention framework that maintains respect for athletes’ religious identities for improved psychological well-being is also warranted.
The Categories of Jonathan Edwards’ Natural Philosophy Applied to Organic Chemistry: An Integrative Example
Authors: Johnson Dana E.
Published: February 2021

In addition to Jonathan Edwards’ extensive bibliography in philosophy and theology, there exists much writing devoted to natural philosophy where he makes reference to man’s ability to recognize God’s order, beauty, and goodness in Creation. The following demonstrates these categories specifically with regard to Edwards’ “Spider” papers, then as they apply to the more modern field of organic chemistry. Jonathan Edwards laid an important foundation for how to view the world that continues to support a healthy scientific enterprise.
Effect of the Illumination Angle on NDVI Data Composed of Mixed Surface Values Obtained over Vertical-Shoot-Positioned Vineyards
Authors: Towers Pedro C. , Poblete-Echeverría Carlos
Published: February 2021

Accurate quantification of the spatial variation of canopy size is crucial for vineyard management in the context of Precision Viticulture. Biophysical parameters associated with canopy size, such as Leaf Area Index (LAI), can be estimated from Vegetation Indices (VI) such as the Normalized Difference Vegetation Index (NDVI), but in Vertical-Shoot-Positioned (VSP) vineyards, common satellite, or aerial imagery with moderate-resolution capture information at nadir of pixels whose values are a mix of canopy, sunlit soil, and shaded soil fractions and their respective spectral signatures. VI values for each fraction are considerably different. On a VSP vineyard, the illumination direction for each specific row orientation depends on the relative position of sun and earth. Respective proportions of shaded and sunlit soil fractions change as a function of solar elevation and azimuth, but canopy fraction is independent of these variations. The focus of this study is the interaction of illumination direction with canopy orientation, and the corresponding effect on integrated NDVI. The results confirm that factors that intervene in determining the direction of illumination on a VSP will alter the integrated NDVI value. Shading induced considerable changes in the NDVI proportions affecting the final integrated NDVI value. However, the effect of shading decreases as the row orientation approaches the solar path. Therefore, models of biophysical parameters using moderate-resolution imagery should consider corrections for variations caused by factors affecting the angle of illumination to provide more general solutions that may enable canopy data to be obtained from mixed, integrated vine NDVI.
Automated Machine Learning for High-Throughput Image-Based Plant Phenotyping
Authors: Koh Joshua C.O. , Spangenberg German , Kant Surya
Published: February 2021

Automated machine learning (AutoML) has been heralded as the next wave in artificial intelligence with its promise to deliver high-performance end-to-end machine learning pipelines with minimal effort from the user. However, despite AutoML showing great promise for computer vision tasks, to the best of our knowledge, no study has used AutoML for image-based plant phenotyping. To address this gap in knowledge, we examined the application of AutoML for image-based plant phenotyping using wheat lodging assessment with unmanned aerial vehicle (UAV) imagery as an example. The performance of an open-source AutoML framework, AutoKeras, in image classification and regression tasks was compared to transfer learning using modern convolutional neural network (CNN) architectures. For image classification, which classified plot images as lodged or non-lodged, transfer learning with Xception and DenseNet-201 achieved the best classification accuracy of 93.2%, whereas AutoKeras had a 92.4% accuracy. For image regression, which predicted lodging scores from plot images, transfer learning with DenseNet-201 had the best performance (R2 = 0.8303, root mean-squared error (RMSE) = 9.55, mean absolute error (MAE) = 7.03, mean absolute percentage error (MAPE) = 12.54%), followed closely by AutoKeras (R2 = 0.8273, RMSE = 10.65, MAE = 8.24, MAPE = 13.87%). In both tasks, AutoKeras models had up to 40-fold faster inference times compared to the pretrained CNNs. AutoML has significant potential to enhance plant phenotyping capabilities applicable in crop breeding and precision agriculture.
Signal Photon Extraction Method for Weak Beam Data of ICESat-2 Using Information Provided by Strong Beam Data in Mountainous Areas
Authors: Zhang Zhiyu , Liu Xinyuan , Ma Yue , Xu Nan , Zhang Wenhao , Li Song
Published: February 2021

The Ice, Cloud, and land Elevation Satellite-2 (ICESat-2) can measure the elevations of the Earth’s surface using a sampling strategy with unprecedented spatial detail. In the daytime of mountainous areas where the signal–noise ratio (SNR) of weak beam data is very low, current algorithms do not always perform well on extracting signal photons from weak beam data (i.e., many signal photons were missed). This paper proposes an effective algorithm to extract signal photons from the weak beam data of ICESat-2 in mountainous areas. First, a theoretical equation of SNR for ICESat-2 measured photons in mountainous areas was derived to prove that the available information provided by strong beam data can be used to assist the signal extraction of weak beam data (that may have very low SNR in mountainous areas). Then, the relationship between the along-track slope and the noise level was used as the bridge to connect the strong and weak beam data. To be specific, the along-track slope of the weak beam was inversed by the slope–noise relationship obtained from strong beam data, and then was used to rotate the direction of the searching neighborhood in the Density-Based Spatial Clustering of Applications with Noise (DBSCAN) algorithm. With the help of this process, the number of signal photons included in the searching neighborhood will significantly increase in mountainous areas and will be easily detected from the measured noisy photons. The proposed algorithm was tested in the Tibetan Plateau, the Altun Mountains, and the Tianshan Mountains in different seasons, and the extraction results were compared with the results from the ATL03 datasets, the ATL08 datasets, and the classical DBSCAN algorithm. Based on the ground-truth signal photons obtained by visual inspection, the parameters of the classification precision, recall, and F-score of our algorithm and three other algorithms were calculated. The modified DBSCAN could achieve a good balance between the classification precision (93.49% averaged) and recall (89.34% averaged), and its F-score (more than 0.91) was higher than that of the other three methods, which successfully obtained a continuous surface profile from weak beam data with very low SNRs. In the future, the detected signal photons from weak beam data are promising to assess the elevation accuracy achieved by ICESat-2, estimate the along-track and cross-track slope, and further obtain the ground control points (GCPs) for stereo-mapping satellites in mountainous areas.
Spatial Representation of GPR Data—Accuracy of Asphalt Layers Thickness Mapping
Authors: Bezina Šime , Stančerić Ivica , Domitrović Josipa , Rukavina Tatjana
Published: February 2021

Information on pavement layer thickness is very important for determining bearing capacity, estimating remaining life and strengthening planning. Ground-penetrating radar (GPR) is a nondestructive testing (NDT) method used for determining the continuous pavement layer thickness in the travel direction. The data obtained with GPR in one survey line is suitable for the needs of repair and rehabilitation planning of roads and highways, but not for wider traffic areas such as airfield pavements. Spatial representation of pavement thickness is more useful for airfield pavements but requires a 3D model. In the absence of 3D GPR, a 3D model of pavement thickness can be created by additional processing of GPR data obtained from multiple survey lines. Five 3D models of asphalt pavements were created to determine how different numbers of survey lines affect their accuracy. The distance between survey lines ranges from 1 to 5 m. The accuracy of the 3D models is determined by comparing the asphalt layer thickness on the model with the values measured on 22 cores. The results, as expected, show that the highest accuracy is achieved for the 3D model created with a distance of 1 m between survey lines, with an average relative error of up to 1.5%. The lowest accuracy was obtained for the 3D model created with a distance of 4 m between the survey lines, with an average relative error of 7.4%.
Subpixel Change Detection Based on Radial Basis Function with Abundance Image Difference Measure for Remote Sensing Images
Authors: Li Zhenxuan , Shi Wenzhong , Zhu Yongchao , Zhang Hua , Hao Ming , Cai Liping
Published: February 2021

Recently, land cover change detection has become a research focus of remote sensing. To obtain the change information from remote sensing images at fine spatial and temporal resolutions, subpixel change detection is widely studied and applied. In this paper, a new subpixel change detection method based on radial basis function (RBF) for remote sensing images is proposed, in which the abundance image difference measure (AIDM) is designed and utilized to enhance the subpixel mapping (SPM) by borrowing the fine spatial distribution of the fine spatial resolution image to decrease the influence of the spectral unmixing error. First, the fine and coarse spatial resolution images are used to develop subpixel change detection. Second, linear spectral mixing modeling and the degradation procedure are conducted on the coarse and fine spatial resolution image to produce two temporal abundance images, respectively. Then, the designed AIDM is utilized to enhance the RBF-based SPM by comparing the two temporal abundance images. At last, the proposed RBF-AIDM method is applied for SPM and subpixel change detection. The synthetic images based on Landsat-7 Enhanced Thematic Mapper Plus (ETM+) and real case images based on two temporal Landsat-8 Operational Land Imager (OLI) images and one Moderate Resolution Imaging Spectroradiometer (MODIS) image are undertaken to validate the proposed method. The experimental results indicate that the proposed method can sufficiently decrease the influence of the spectral unmixing error and improve the subpixel change detection results.
EEMDS: An Effective Emergency Message Dissemination Scheme for Urban VANETs
Authors: Ullah Sami , Abbas Ghulam , Waqas Muhammad , Abbas Ziaul Haq , Tu Shanshan , Hameed Ibrahim A.
Published: February 2021

In Vehicular Adhoc Networks (VANETs), disseminating Emergency Messages (EMs) to a maximum number of vehicles with low latency and low packet loss is critical for road safety. However, avoiding the broadcast storm and dealing with large-scale dissemination of EMs in urban VANETs, particularly at intersections, are the challenging tasks. The problems become even more challenging in a dense network. We propose an Effective Emergency Message Dissemination Scheme (EEMDS) for urban VANETs. The scheme is based on our mobility metrics to avoid communication overhead and to maintain a stable cluster structure. Every vehicle takes into account its direction angle and path loss factor for selecting a suitable cluster head. Moreover, we introduce estimated link stability to choose a suitable relay vehicle that reduces the number of rebroadcasts and communication congestion in the network. Simulation results show that EEMDS provides an acceptable end-to-end delay, information coverage, and packet delivery ratio compared to the eminent EM dissemination schemes.