Oligofluorenes (a trimer, pentamer, and heptamer) with one @entity68068 unit in the center (OFnK: n=3, 5, or 7) were synthesized and used as models to understand the origin of the low-energy emission band in the photoluminescence and electroluminescence spectra of some @entity66100 . All compounds form glasses with T(g) at 30 degrees C (OF3 K), 50 degrees C (OF5 K) and 57 degrees C (OF7 K). Oligomers OF5 K and OF7 K exhibit smectic liquid crystal phases that undergo transition to isotropic melts at 107 and 205 degrees C, respectively. Oligomer OF5 K could be obtained in form of single crystals. The X-ray structure analysis revealed the helical nature of the molecule and a helix reversal defect located at the central @entity68068 unit. The packing pattern precludes formation of excimers. Electrochemical properties were investigated by cyclic voltammetry. The ionization potential (I(p)) and electron affinity (E(a)) were calculated from these data. Studies of the photophysical properties of OFnK in solution and thin film by steady-state and time-resolved fluorescence spectroscopic measurements suggest efficient funneling of excitation energy from the photoexcited @entity11965 segments to the low-energy @entity68068 sites by both intra- and intermolecular hopping events whereby they give rise to green emission. Intermolecular energy transfer was investigated by using a model system composed of a highly defect free @entity66100 @entity64937 doped by OFnK. F  rster-type energy transfer takes place from @entity64937 to OFnK. The energy-transfer efficiency increases predictably with increasing concentration of OFnK.

Monodisperse oligofluorenes with keto defect as models to investigate the origin of green emission from XXXX : synthesis, self-assembly, and photophysical properties.

@entity68068 :: ('CHEBI:17922', 'Chemical') :: ['fluorenone'] @entity11965 :: ('MESH:C041509', 'Chemical') :: ['fluorene'] @entity66100 :: ('CHEBI:60582', 'Chemical') :: ['polyfluorenes', 'polyfluorene'] @entity64937 :: ('200162', 'Gene') :: ['PF2/6']
@entity66100 :: (CHEBI:60582,Chemical) :: ['polyfluorenes']
