batterydata/paper-abstracts huggingface dataset:
Lithium-rich layered oxides, xLi2MnO3·(1−x)LiMO2(M = Ni, Mn, Co), have been under intense investigation as high-performance cathode materials for lithium ion batteries due to their high discharge capacity, low cost and environmental benignity. Unfortunately, the commercialized application of these cathode materials have so far been hindered by their severe capacity and voltage fading during high voltage cycling (>4.5 V vs. Li/Li+). In an attempt to overcome these problems, herein, highly crystalline Al2O3 layer from the hydrolysis of aluminum isopropoxide are coated on 0.5Li2MnO3·0.5LiNi0.5Co0.2Mn0.3O2 with controlling the growth of Al2O3 crystals. The coin cell with bare cathode material delivers a high discharge capacity over 268.2 mAh g−1 between 2.0 V and 4.8 V, while the Al2O3 coated cathode material shows the excellent cycling stability corresponding to 98% capacity retention after 100 cycles at 1C. More importantly, the highly crystalline Al2O3 coated cathode materials exhibit a significantly lower discharge voltage decay compared to the bare cathode materials, which could be ascribed to the suppression of the layered-to-spinel transformation by compact and highly crystalline Al2O3 layer. The results here will shed light on developing cathode materials with special structures and superior electrochemical properties for high-performance lithium ion batteries.
The Jewish ultra-orthodox (Haredi) Talmud Torah schools have been consistently resistant to the process of standardization in content, measurement, and evaluation, in contrast to the Israeli state education system which has progressed steadily in these areas. Talmud Torah schools are private elementary schools for ultra-orthodox boys. Studies are religious and the main subject of study is the Gemara (Talmud). For religious and ideological reasons these schools insist on total independence at all levels and resist assessment or regulation of any kind and as a result have rarely been studied by Israeli or international researchers. The present study examined the contribution of a unique Gemara study program to a sample of 159 sixth grade boys in Talmud Torah schools. Students completed questionnaires to evaluate general ability and language skills, Aramaic vocabulary skills, and knowledge of Gemara. After the intervention, the test results of the experimental group were found to be superior to those of the control group. The findings also provide first insights into the performance of ultra-orthodox students on verbal and general ability measures compared to the general Israeli school population. Thus, this study provides the first standardized measurement and evaluation of learning and literacy in the previously inaccessible Haredi student population.
Carbon-coated lithium iron phosphate (LiFePO4/C) was hydrothermally synthesized from commercial LiOH, FeSO4 and H3PO4 as raw materials and glucose as carbon precursor in aqueous solution at 180°C for 6h followed by being fired at 750°C for 6h. The samples were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and constant current charge–discharge cycling test. The results show that the synthesized powders are in situ coated with carbon precursor produced from glucose. At ambient temperature (25±2°C), the specific discharge capacities are 154mAhg−1 at 0.2C and 136mAhg−1 at 5C rate, and the cycling capacity retention rate reaches 98% over 90 cycles. The excellent electrochemical performance can be correlated with the in situ formation of carbon precursor/carbon, thus leading to the even distribution of carbon and the enhancement of conductibility of individual grains.
4-Chloro-2-carboxyphenoxyacetic acid (CCPA) residues have occasionally been observed in crops treated with 4-chloro-2-methylphenoxyacetic acid (MCPA). The oral toxicity of MCPA and CCPA was compared in a 4-week rat study at a dietary concentration of 2000ppm. CCPA was also given at 12,000ppm (equivalent to 1g/kg bodyweight/day). MCPA at 2000ppm caused reduced food consumption and body weight gain and increased water consumption in females only. Changes in clinical chemistry confirmed the liver as a target organ. Increased serum creatinine and urobilinogen, degenerated transitional epithelial cells in the urine showed that the kidney was also affected. Response to CCPA was confined to the 12,000ppm dose. The target organs were liver and kidney as for MCPA. Microscopic examination revealed an increased severity of basophilic tubules and calcification at the outer/inner medulla transition in the kidneys. The results demonstrate that CCPA is less toxic than MCPA, that CCPA has no different toxicological end points when compared to MCPA, and that any risks associated with consumption of CCPA will not be underestimated if the CCPA residue is treated as if it were parent MCPA. Based on the MCPA–CCPA comparison, criteria for read across and minimal information requirements are proposed.
p63, a member of p53 family, has a significant role in the development and maintenance of stratified epithelia. However, a persistent dispute remained over the last decade concerning the interpretation of the severe failure of p63-null embryos to develop stratified epithelia. In this study, by investigating both p63-deficient strains, we demonstrated that p63-deficient epithelia failed to develop beyond ectodermal stage as they remained a monolayer of non-proliferating cells expressing K8/K18. Importantly, in the absence of p63, corneal-epithelial commitment (which occurs at embryonic day 12.5 of mouse embryogenesis) was hampered 3 weeks before corneal stem cell renewal (that begins at P14). Taken together, these data illustrate the significant role of p63 in epithelial embryogenesis, before and independently of other functions of p63 in adult stem cells regulation. Transcriptome analysis of laser captured-embryonic tissues confirmed the latter hypothesis, demonstrating that a battery of epidermal genes that were activated in wild-type epidermis remained silent in p63-null tissues. Furthermore, we defined a subset of novel bona fide p63-induced genes orchestrating first epidermal stratification and a subset of p63-repressed mesodermal-specific genes. These data highlight the earliest recognized action of ΔNp63 in the induction epidermal morphogenesis at E11.5. In the absence of p63, a mesodermal program is activated while epidermal morphogenesis does not initiate.
Bordetella spp. are not normally included when considering the opportunistic bacterial species that are typically involved in respiratory tract infections in individuals with cystic fibrosis (CF). By using a combination of bacterial genotyping and 16S rDNA sequencing, Bordetella spp. were identified in cultures obtained from 43 individuals with CF. Most (n = 23) patients were infected with Bordetella bronchiseptica/parapertussis; five were infected with Bordetella hinzii, four with Bordetella petrii, three with Bordetella avium, and eight with unidentified Bordetella spp. Consideration should be given to the presence of these organisms in the evaluation of CF sputum cultures.
Nanoparticles may be formed on a substrate by mixing precursor solutions deposited by an ink-jet printer, as described in patent US2013316482 (A1). A first solution is deposited on a substrate from a first ink-jet print cartridge. Then, a second solution is deposited on the substrate from a second ink-jet print cartridge. The solutions may be printed in an array of droplets on the substrate. Nanoparticles form when droplets of the first solution overlap with droplets of the second solution. In one example, the nanoparticles may be gold nanoparticles (Au NPs) formed from mixing a first solution of 1,2-dichlorobenze (DCB) and oleylamine and a second solution of gold chloride trihydrite and dimethyl sulfoxide (DMSO). The nanoparticles may be incorporated into optoelectronic devices.
Wireless computational grids are evolving due to rapid growth in wireless devices to provide any time any where computing and communication services. Wireless devices are considered as important resources for job execution in a wireless grid. However, they are unreliable due to unstable wireless connections, frequent mobility, and device resource constraints such as limited processing capacity, limited battery life, low communication bandwidth, etc. Consumers and providers in a wireless grid have potential conflicting interests: consumers prefer reliable resources at minimum cost for job execution whereas providers prefer efficient utilization of resources with a maximum profit. Hence it is necessary to design a resource brokering mechanism that assures job(s) execution and satisfies needs of consumers and providers. This paper proposes a software agent based resource brokering scheme that employs a resource brokering agency consisting of a set of software agents which discover and recommend reliable devices, negotiate resource cost using non-cooperative bargaining game, and schedule jobs. Device reliability is modeled by using parameters like processing rate, memory, bandwidth and battery power. Discount function is employed in bargaining game based on job deadline, previous offers of an opponent, and dynamics in the grid market. Adaptive negotiation process is applied by exercising different discount strategies (aggressive or conservative or linear) based on the negotiation status of a player. The scheme is simulated to evaluate performance parameters like resource utilization rate, expected profit, job completion time and job execution rate. We observed that the proposed scheme performs better than the existing resource brokering scheme.
The influences of temperature on the formation losses and subsequent electrical performance of Li x (Ni1/3Co1/3Mn1/3) y O2 (NCM)/graphite lithium-ion cells were investigated. It was shown that the total capacity loss during formation of a full cell at 25 °C consists of losses on the positive and negative electrode to about one half each. The losses of the negative electrode (ca. 10%) are due to solid electrolyte interphase (SEI) formation on graphite but are masked by the losses of the positive side (ca. 20%) which are mainly caused by a kinetic inhibition of NCM and are theoretically reversible when the cell is discharged to very low potentials. The total loss of a full cell fits with the loss of the positive electrode. With increased temperature the ratio of losses on positive and negative electrode decreases as the diffusion coefficient of lithium in NCM increases. In total, an elevated formation temperature leads to increased irreversible losses on both electrodes and significantly lower cell performance of graphite. The upper cut-off voltage has an influence on the positive electrode formation losses in a reversible manner. The constituents of the SEI identified via the combination of XPS and FTIR are mainly RCH2OCO2Li, RCOOLi and LiF for the outer SEI and mainly Li2CO3, Li2O and LiF for the inner SEI.
Variable temperature ionic conductivity, viscosity and 1H NMR spin-lattice relaxation times, linewidths and chemical shifts measurements were determined for various concentrations of aqueous ammonium metavanadate (NH4VO3) and vanadyl sulfate (VOSO4) over the temperature range of 20–100 °C. Concentration ranges of 0.05–2 M and 0.05–0.2 M were investigated for VOSO4 and NH4VO3 respectively in 2 M H2SO4. Results show ion and proton transport processes that are mediated strongly by increasing solution viscosity, especially in the case of VOSO4. Activation energies calculated from ionic conductivity and solution viscosity show greater energy being needed for translational ion dynamics with increasing concentration for both solutions. Additionally, data suggest that with greater metal ion concentration ion association is more prevalent for the vanadyl ion. The differences between the transport capabilities of the two solution are discussed in terms of the 1H NMR, ionic conductivity and viscosity data.
In this article, sub-C size cylindrical NiMH cells were constructed for the performance investigation under long-term overcharge and elevated temperatures. The influence of operated conditions on cell performance and electrode materials was examined. The experimental results revealed that the NiMH cells had good tolerance for 1-month overcharge at a 0.2C rate, remaining the capacity and capacity-rate performance and showing promise as a candidate for backup power sources. However, the sub-C size NiMH cells did not exhibit good performance at elevated temperatures, and the cycling stability with 100% DOD (depth of discharge) at temperature of >50°C is necessary to be further improved. The deterioration of electrochemical capacity and cycling stability at elevated temperatures was analyzed and the reasons were discussed.
This paper focuses on the design of security enforcement mechanisms for the prevention of denial of service (DoS) attacks in wireless sensor networks. In the first part, we identify the requirement for security enforcement using auction theory, which allows us to detect non-cooperative nodes. Our novel scheme for preventing DoS attacks is called Secure Auction based Routing (SAR). In the proposed protocol, nodes prefer to participate in forwarding incoming packets and gaining reputation in the network. Nodes willing to do so must compete against each other, and the competition is based on auction theory. The amount of bid that each node offers is equal to its utility value; and the price that a winner of a bid pays is a reduction in its original battery power. Since a node’s truthful bidding is shown to be a dominant strategy, in order to prevent DoS attack, nodes that do not bid truthfully should be isolated. In the second part, we formulate the attack–defense problem as a non-cooperative, two-player, non-zero-sum game between an attacker and a wireless sensor network. We show that this game achieves Nash equilibrium, thus leading to a defense strategy for the network. We propose two novel schemes. The first one is called Utility based Dynamic Source Routing (UDSR), which incorporates the total utility of each en-route node in data packets, where utility is the difference between gain and cost for each node. The second scheme is based on a watch-list, where each node earns a rating from its neighbors, based on its previous cooperation in the network. Simulation results show that the proposed game theoretic framework significantly increases the chance of success in defense strategy for the wireless sensor network.
Battery storage systems can help to integrate excess Photovoltaic (PV) energy into the local energy systems but also increase the request for higher self-consumption rates of the households. This study uses a spatially resolved approach with hourly time steps to analyze the influence of batteries on the domestic residual loads on a regional scale. A domestic energy component is developed consisting of a PV-system model, the demand component, and a battery storage device. The study area is located in the south of Bavaria and 4906 households with PV-systems between 3 and 10 kWp power were selected assuming a battery capacity of 6.2 kWh in average. Three charging strategies for domestic battery storage systems are assessed: (1) Maximization of self-consumption, (2) Fixed feed-in limit of 70% of the PV-peak power, and (3) Daily dynamic feed-in limit based on ideal forecasts. The best result is obtained through the third strategy with a self-consumption of 78.5% on average and the highest reduction of the grid flows by 20% by damping grid excesses. The influence of the charging strategy rises with increasing size of PV- and battery storage systems and therefore residual loads. Regional variations are further caused by the meteorological conditions, different PV- and battery sizes and parameters and demand profiles on municipal scale. Consequently, a sufficient sample size with different set-ups is recommended for a full evaluation of battery charging strategies.
A 4 V asymmetric capacitor has been assembled using non-porous activated mesophase carbon microbeads (AMCMB) as the negative electrode, a graphitized carbon (GMCMB) as the positive electrode and quaternary alkyl ammonium based organic electrolyte. AMCMB has been heated under the reduction atmosphere of hydrogen/nitrogen after a chemical activation. It has small specific surface area (24.48 m2 g−1), but delivers a large capacitance value due to the irreversible “electrochemical activation” in the initial galvanostatic charge–discharge process. The storage charge behavior of AMCMB has also been investigated by ex situ XRD, Raman spectroscopy, cyclic voltammetry and electrochemical impedance spectroscopy. In terms of specific capacity, energy density, power density and cycle ability, the AMCMB/GMCMB capacitor is superior the other capacitors like AC/graphite, AC/AC.
Heterocyclic amines (HCAs), a group of genotoxic compounds formed during the heating of proteinaceous food items, have been known since the late 1970s. However, the genotoxic effect of these compounds in the low dose region has not yet been thoroughly studied. Here we used a sensitive flow cytometer-based micronucleus assay in mice to determine the frequency of micronucleated erythrocytes (fMPCE) of the three common HCAs, 2-amino-1-methyl-6-phenylimidazo[4,5-b]pyridine (PhIP), 2-amino-3,8-dimethylimidazo[4,5-f]quinoxaline (MeIQx), and 2-amino-3-methylimidazo[4,5-f]quinoline (IQ), in the low dose region. We especially looked for any deviation from linearity of the dose–response curves. Male Balb/C mice were intra peritoneally injected with different doses of either PhIP (0–36mg/kg b.w.), MeIQx (0–90mg/kg b.w.) or IQ (0–40mg/kg b.w.). In the case of PhIP, we found a significant dose–response relationship, while MeIQx and IQ did not display an increased fMPCE level. This flow cytometer method allows for determination of the DNA content of micronuclei. All three HCAs tested here yielded a low DNA content of micronuclei, indicating that they do not possess aneugenic effects. A comparison between the HCAs and acrylamide (AA), another heat induced genotoxic compound, revealed that the slope of the dose–response curve is about 10 times steeper for PhIP than AA. In spite of this, AA probably constitutes a higher human risk than HCAs since the intake is about a 100- to 1000-fold higher than the intake of HCAs.
Increasing costs of electricity supply from the local grid, the decreasing photovoltaic (PV) technology costs and the decreasing PV feed-in-tariff according to the current German Renewable Energy Sources Act (EEG) will in the future raise the monetary incentives to increase the self-consumption of PV energy. This is of great interest in commercial buildings as there mostly is sufficient place to install high capacities of photovoltaic panels on their own roofs. Furthermore, the electricity purchase price from the local grid for commercial consumers nowadays is about 20€ct/kWh, which is higher than the cost of generation of electricity from solar panels (about 8–12€ct/kWh). Additionally, the load profiles in commercial applications have a high correlation with the generated solar energy. Hence, there is a great opportunity for economic savings. This paper presents optimization results with respect to self-consumption and degree of self-sufficiency for a supermarket in Aachen, Germany. The optimization is achieved using real measurement data of load profile and solar radiation. Besides, techno-economic analyses and sensitivity analyses have been carried out to demonstrate the influence of different PV system sizes, PV system costs and interest rates. Moreover, to raise self-consumption different battery sizes with different battery system costs have been investigated and analysed for 2015 and 2025 scenarios as well. The results show that the installation of a PV system can reduce the electricity costs through self-consumption of self-generated PV energy. Also, applying battery energy storages in combination with PV systems can reduce the electricity costs even more, assuming that the battery costs can be reduced down to 200€/kWh in the future.
Micro-hybrid vehicles (μH) are currently starting to dominate the European market and seize constantly growing share of other leading markets in the world. On the one hand, the additional functionality of μH reduces the CO2 emissions and improves the fuel economy, but, on the other hand, the additional stress imposed on the lead-acid battery reduces significantly its expected service life in comparison to conventional vehicles. Because of that μH require highly accurate battery state detection solutions. They are necessary to ensure the vehicle reliability requirements, prolong service life and reduce warranty costs. This paper presents an electrical model based on Butler-Volmer equation. The main novelty of the presented approach is its ability to predict accurately dynamic response of a battery considering a wide range of discharge current rates, state-of-charges and temperatures. Presented approach is fully implementable and adaptable in state-of-the-art low-cost platforms. Additionally, shown results indicate that it is applicable as a supporting tool for state-of-charge and state-of-health estimation and scalable for the different battery technologies and sizes. Validation using both static pulses and dynamic driving profile resulted in average absolute error of 124 mV regarding cranking current rate of 800 A respectively.
We previously found that subjects with amnestic mild cognitive impairment exhibit a pro-inflammatory immune profile in the cerebrospinal fluid similar to multiple sclerosis, a central nervous system autoimmune disease. We therefore hypothesized that early neuroinflammation would reflect increases in brain amyloid burden during amnestic mild cognitive impairment.
Methyl phenyl bis-methoxydiethoxysilane (MPBMDS) was prepared and its effects were investigated as an additive in 1.0moldm−3 LiPF6-propylene carbonate (PC)/dimethyl carbonate (DMC) (1:1, v/v) electrolyte for lithium ion batteries. The electrochemical properties of the electrolyte with MPBMDS were characterized by discharge/charge tests, cyclic voltammetry, electrochemical impedance spectroscopy, scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The addition of MPBMDS can effectively prevent the decomposition and the co-intercalation of PC. In addition, burning tests showed that the addition of 4–13wt.% MPBMDS to the bare PC-based electrolyte effectively reduces the flammability. This eco-friendly compound provides a new promising direction for the development of bi- or multi-functional additives for lithium ion batteries.
Including information on: Thailand’s solar white elephants: 15 years of solar battery charging Integrated PV/gas-turbine system for satisfying peak demands Charge conduction and PV properties of DDE-based Schottky device Field-aided collection in GaInP2 top solar cells PV roofing design issues and integration into buildings
Caregiving to a family member with cancer might have health implications. However, limited research has investigated the psychophysical health of home-cared cancer patients family caregivers. In a previous study, we have found that a prolonged worry in daily life is a crucial variable compared to caregivers’ psychophysical symptomatology. This investigation was designed to further examine the well-being of family caregivers, explore the domains of worry, and assess to what extent “content-dependent” worry could be associated with the caregivers’ health