batterydata/paper-abstracts huggingface dataset:
In this paper, a review on electrochemical porous etching of semiconductors is proposed. After a brief history, chemical and electrochemical etching of semiconductors are considered and the pore formation models are discussed. The influences of the key parameters on porous etching are illustrated by listing the numerous pore morphologies reported in the literature. A short inventory of typical applications in various fields is given in the conclusion.
Advanced transportation sensors use a wireless medium to communicate and use data fusion techniques to provide complete information. Large-scale use of intelligent transportation sensors can lead to data bottlenecks in an ad-hoc wireless sensor network, which needs to be reliable and should provide a framework to sensors that constantly join and leave the network. A possible solution is to use public transportation vehicles as data fusion nodes or cluster heads. This paper presents a mathematical programming approach to use public transportation vehicles as cluster heads. The mathematical programming solution seeks to maximize benefit achieved by covering both mobile and stationary sensors, while considering cost/penalty associated with changing cluster head locations. A simulation is developed to capture realistic considerations of a transportation network. This simulation is used to validate the solution provided by the mathematical model.
To decrease the payback time of the photovoltaic (PV) system and make it financially attractive, we propose a Photovoltaic Customer Grid Supply System (PCGSS) with bi-directional power flow, so the surplus energy fully or partially is delivered of the grid, following its needs, while, for critical operating conditions, the grid supplies the loads directly. For this purpose, a new management algorithm is proposed to optimize the generated power and allows the system to act as a distributed source inside the utility grid. Two scenarios are considered; in the first, the grid absorbs all the power delivered by the distributed system, while in the second, the power is injected to the grid based on the its requirements. Furthermore, to meet the proposed objectives, the PV system is strictly sized to supply only the high priority loads, in addition, the system has to work at the Maximum Power Point (MPP) or at the Limited Power Point (LPP) modes to meet the management algorithm requests. To reach the LPP, a modified Perturbation and Observation (P&O) algorithm is used. Meanwhile, to sustain the functionality of the system and to assure the continues supply of energy, a battery system has been integrated with the PV system.
Concerns over air quality reduction resulting from burning fossil fuels have driven the development of clean and renewable energy sources. Supercapacitors, batteries and solar cells serve as eco-friendly energy storage and conversion systems vitally important for the sustainable development of human society. However, many diverse elements influence the performance of energy storage and conversion systems. The overall efficiency of systems depends on the specific structure and properties of incorporated functional materials. Carbon materials, such as graphene, are especially promising for materials development in the energy storage and conversion fields. Graphene, a two-dimensional (2D) carbon material only a single atom thick, has massless Dirac fermions (electron transport is governed by Dirac's equation), displays outstanding electrical conductivity, superior thermal conductivity and excellent mechanical properties. 2D free-standing graphene films and powders have paved the way for promising energy applications. Recently, much effort has been spent trying to improve the number of active sites in electrode materials within 3D network/aerogel structures derived from graphene. This is because graphene aerogels are promising materials for energy systems due to their porous hierarchical structure which affords rapid electron/ion transport, superior chemical and physical stability, and good cycle performance. This review aims to summarize the synthetic methods, mechanistic aspects, and energy storage and conversion applications of novel 3D network graphene, graphene derivatives and graphene-based materials. Areas of application include supercapacitors, Li-batteries, H2 and thermal energy storage, fuel cells and solar cells.
Three classes of p-type redox active molecules, i.e. triarylamine derivatives, phenothiazine/phenoxazine derivatives, and transition metal complexes are presented in this paper. Their structures, redox potentials and applications for molecular wiring and redox targeting of carbon-free insulating battery materials are discussed in detail.
Poly(o-anisidine)-dodecylbenzenesulfonate (POA-DBSA) coatings were synthesized on stainless steel from aqueous solution containing o-anisidine and dodecylbenzene sulfonic acid by using cyclic voltammetry. These coatings were characterized by Fourier transform infrared spectroscopy (FTIR), UV–vis absorption spectroscopy, scanning electron microscopy (SEM) and cyclic voltammetry (CV). Corrosion tests of these coatings were carried out in aqueous 3% NaCl solution by using open circuit potential (OCP) measurements, potentiodynamic polarization technique, cyclic potentiodynamic polarization measurements and electrochemical impedance spectroscopy (EIS). The results reveal that POA-DBSA acts as a corrosion protective coating on steel and reduces the corrosion rate (CR) of steel almost by a factor of 14.5.
The monoclinic form of Li3Cr2(PO4)3 is galvanostatically cycled in a half cell versus lithium as anode. For the first time active redox behaviour of trivalent chromium in a phosphate matrix at around 4.8V vs. Li+/Li is demonstrated. The coulombic efficiency ideally approaches 80%. Based on extensive XPS analyses, a possible oxidation scenario is suggested, which considers the formation of both diphosphorus(V) pentaoxide and chromyl(IV) compounds. Further possible parasitic reactions like the formation of a solid electrolyte interface at the cathode side are discussed.
Objective The current study evaluated part of the Multifactorial Model of Driving Safety to elucidate the relative importance of cognitive function and a limited range of standard measures of visual function in relation to the Capacity to Drive Safely. Capacity to Drive Safely was operationalized using three validated screening measures for older drivers. These included an adaptation of the well validated Useful Field of View (UFOV) and two newer measures, namely a Hazard Perception Test (HPT), and a Hazard Change Detection Task (HCDT). Method Community dwelling drivers (n =297) aged 65–96 were assessed using a battery of measures of cognitive and visual function. Results Factor analysis of these predictor variables yielded factors including Executive/Speed, Vision (measured by visual acuity and contrast sensitivity), Spatial, Visual Closure, and Working Memory. Cognitive and Vision factors explained 83–95% of age-related variance in the Capacity to Drive Safely. Spatial and Working Memory were associated with UFOV, HPT and HCDT, Executive/Speed was associated with UFOV and HCDT and Vision was associated with HPT. Conclusion The Capacity to Drive Safely declines with chronological age, and this decline is associated with age-related declines in several higher order cognitive abilities involving manipulation and storage of visuospatial information under speeded conditions. There are also age-independent effects of cognitive function and vision that determine driving safety.
The role of N-acetylaspartate in the brain is unclear. Here we used specific antibodies against N-acetylaspartate and immunocytochemistry of carbodiimide-fixed adult rodent brain to show that, besides staining of neuronal cell bodies in the grey matter, N-acetylaspartate labelling was present in oligodendrocytes/myelin in white matter tracts. Immunoelectron microscopy of the rat hippocampus showed that N-acetylaspartate was concentrated in the myelin. Also neuronal cell bodies and axons contained significant amounts of N-acetylaspartate, while synaptic elements and astrocytes were low in N-acetylaspartate. Mitochondria in axons and neuronal cell bodies contained higher levels of N-acetylaspartate compared to the cytosol, compatible with synthesis of N-acetylaspartate in mitochondria. In aspartoacylase knockout mice, in which catabolism of N-acetylaspartate is blocked, the levels of N-acetylaspartate were largely increased in oligodendrocytes/myelin. In these mice, the highest myelin concentration of N-acetylaspartate was found in the cerebellum, a region showing overt dysmyelination. In organotypic cortical slice cultures there was no evidence for N-acetylaspartate-induced myelin toxicity, supporting the notion that myelin damage is induced by the lack of N-acetylaspartate for lipid production. Our findings also implicate that N-acetylaspartate signals on magnetic resonance spectroscopy reflect not only vital neurons but also vital oligodendrocytes/myelin.
This paper presents a novel electrochemical lithium-ion cell model which can be used in battery control units. Based on classical single-particle approaches, a lumped-parameter nonlinear model is developed that is able to predict accurately the terminal voltages for arbitrary loads, and even for potentiostatic operation. The key points are: (1) an incorporation of the electrolyte potential, (2) a modal decomposition of the partial differential equation of the liquid phase lithium-ion concentration, (3) a correct handling of the SOC-dependent diffusivity in the insertion materials of both electrodes, and (4) a consideration of temperature-dependent kinetic processes. A combined parameter analysis and identification is successfully applied for the parameterization of the model. Using a Fisher-information matrix approach in combination with a sensitivity analysis, the identifiability of each parameter is estimated in dependence on the measurement information. Using this information, it is possible to choose a small number of relevant experiments which are sufficient to fully parameterize the model.
Brain p38α mitogen-activated protein kinase (MAPK), a potential therapeutic target for cognitive dysfunction based on the neuroinflammation-synaptic dysfunction cycle of pathophysiology progression, offers an innovative pharmacological strategy via inhibiting the same activated target in both glia and neurons, thereby enhancing the possibility for efficacy. The highly selective, brain-penetrant p38αMAPK inhibitor MW150 attenuates cognitive dysfunction in two distinct Alzheimer’s disease (AD)-relevant models and avoids the problems encountered with previous mixed-kinase inhibitor drug candidates. Therefore, it is essential that the glial effects of this CNS-active kinase inhibitor be addressed in order to anticipate future use in clinical investigations.
LiNi0.5Co0.44Fe0.06VO4 cathode material has been synthesized by a citric acid:polyethylene glycol polymeric method at 723K for 5h in air. The surface of the LiNi0.5Co0.44Fe0.06VO4 was coated with various wt.% of Al2O3 by a wet chemical procedure and heat treated 873K for 2h in air. The samples were characterized by XRD, FTIR, SEM, and TEM techniques. XRD patterns expose that the complete crystalline phase occurred at 723K and there was no indication of new peaks for the coated samples. FTIR spectra show that the complete removal of organic residues and the formation of LiNi0.5Co0.44Fe0.06VO4. TG/DTGA results reveal that the formation of LiNi0.5Co0.44Fe0.06VO4 occurred between 480 and 670K and the complete crystalline occurred at 723K. SEM micrographs show the various morphological stages of the polymeric intermediates. TEM micrographs of the pristine LiNi0.5Co0.44Fe0.06VO4 reveal that the particle size ranged from 130 to 150nm and Al2O3 coating on the fine particles was compact and had an average thickness of about 15nm. The charge–discharge experiments were carried out between 2.8 and 4.9V (versus Li) at a current rate of 0.15C. The 1.0wt.% Al2O3 coated sample had the best electrochemical performance, with an initial capacity of 65mAhg−1 and capacity retention of 60% after 50 cycles. The electrochemical impedance behavior suggests that the failure of pristine cathode performance is associated with an increase in the impedance growth on the surface of the cathode material upon continuous cycling.
In this study, PANI/MnO2 nanocomposite was synthesized by the reaction of polyaniline (PANI) and KMnO4 in the aqueous medium. Material was characterized by X-ray diffraction, nitrogen sorption, scanning electron microscopy, transmission electron microscopy, thermogravimetric analysis, and FT-IR. PANI/MnO2 modified electrode was investigated in the simultaneous detection of all four DNA bases (guanine, adenine, thymine, and cytosine) using cyclic and differential pulse voltammetries. pH was optimized to obtain the best peak potential separation and response current. This enabled us for the simultaneous voltammetric determination of all four DNA bases at physiological condition (pH 7). PANI/MnO2 nanocomposite exhibited high-current sensitivity for these analytes compared to MnO2 and PANI modified electrodes. Under the optimum conditions, PANI/MnO2 exhibited low detection limit, good sensitivity, and wide linear range for the simultaneous detection of G, A, T, and C. Moreover, the proposed method was successfully applied in the determination of G, A, T, and C contents in a calf thymus DNA sample with satisfactory results. The reliability and stability of the modified electrode provide a good possibility for applying the technique in the routine analysis for a selected class of electroactive organic/bio-molecules.
Metallic zinc (Zn) is one of the most promising anodes for aqueous batteries, but so far its applicability for rechargeable systems remains elusive, mainly owing to the free water-induced parasitic reactions. Here, we report a new “water-in-deep eutectic solvent (water-in-DES)” electrolyte (~30 mol.% H2O in a eutectic mixture of urea/LiTFSI/Zn(TFSI)2; TFSI, bis(trifluoromethanesulfonyl)imide), in which all water molecules participate in DES's internal interaction (H-bonding and coordinating) network, leading to a suppressed reactivity with Zn anode from both thermodynamic and electrochemical aspects. Inheriting characteristics from aqueous and DES media, this electrolyte enables stable and reversible Zn plating/stripping with over twentyfold enhancement in cycling life compared to routine aqueous electrolytes, even at low rates. With these merits, a desirable rechargeability (>90% capacity retention after 300 cycles at 0.1 C) is achieved for a 1.92 V (average dicharge voltage) Zn/LiMn2O4 battery, together with a practical energy density of 52 Wh/kg (pouch cell, 2 Ah, ~9.8 × excess Zn on anode).
Information on the feeding rate by free-ranging odontocetes is necessary for assessing potential conflicts with fishing activities. One way of obtaining a proxy for feeding events in homeothermic predators is to measure stomach temperature, which drops during prey ingestion. In this study, stomach temperature pills (STPs) were deployed in eight narwhals (Monodon monoceros) in East Greenland (2012-2013). A coded message with information on the temperature was transmitted from the STP and received and relayed by a satellite-linked radio transmitter attached to the back of the whale. Meal size and prey composition were estimated from samples collected from the Inuit hunt of narwhals.
These findings suggest that the CAINS scale endorses good convergent validity for the assessment of negative symptoms and is very useful in the prediction of psychosocial functioning. In addition, the CAINS dimensions might provide advantages over old assessment scales on disentangling the complex associations between negative symptoms and cognitive impairment.
In this paper, nanofibrous membranes based on poly(vinylidene fluoride) (PVdF) doped with ion-complex (SiO2-PAALi) were prepared by electrospinning technique and the corresponding composite gel-polymer electrolytes (CGPEs) were obtained after being activated in liquid electrolyte. The microstructure, physical and electrochemical performances of the nanofibrous membranes and the corresponding CGPEs were studied by various measurements such as Fourier Transform Infrared Spectroscopy(FTIR), Scanning Electron Microscope (SEM), Differential Scanning Calorimetry (DSC), Thermal Gravimetric Analysis (TGA), Stress-strain test, Linear Sweep Voltammetry (LSV), AC impedance measurement and Charge/discharge cycle test. As to the ion-complex doped nanofibrous membranes, PVdF can provide mechanical support with network structure composed of fully interconnection; while the ion-complexes are absorbed onto the surface of the PVdF nanofibers evenly instead of being aggregated. With the help of doped ion-complex, the prepared nanofibrous membranes present good liquid electrolyte absorbability, excellent mechanical performance, and high decomposition temperature. For the corresponding CGPEs, they possess high ionic conductivity, wide electrochemical window, and good charge/discharge cycle performance.
We describe the preparation of Prussian Blue films with several thicknesses, and their characterization by means of cyclic voltammetry and polarized reflection FTIR spectroscopy. The electrochemical experiments demonstrated a direct relationship between the film thickness and its intrinsic conductivity. The vibrational spectra showed asymmetrical bands in the vicinity of the cyanide stretching band. The s-polarization bands showed a shift to higher frequencies, while the p-polarization bands showed a downshift with increasing film thickness. The presence of shifted cyanide stretching bands in the s- and p-polarizations is attributed to the columnar shape of Prussian Blue grains formed in the growth process.
Automotive Shredder Residue (ASR) generation in EU is approximately 2–2.5 million t/y, constituting 10% of total hazardous waste in the EU. Currently, about 75% of ELVs total weight is recycled while the remaining 25% (ASR). Not surprisingly, Europe is the world’s largest vehicle producer as about 30% of the 50 million cars produced globally are manufactured in the EU. Worldwide, ASR is considered an increasingly problematic waste, consisting of a large number of different materials that basically remains unprocessed and directed to landfills. The aim of this study is to provide an overview of the ASR problem and the options for processing this waste in order to minimize the waste directed to landfills.
A small library of stereoisomeric pseudopeptides able to make gels in different solvents has been prepared and their attitude to make gels in the presence of several metal ions was evaluated. Four benzyl esters and four carboxylic acids, all containing a moiety of azelaic acid (a long chain dicarboxylic acid) coupled with four different pseudopeptide moieties sharing the same skeleton (a phenyl group one atom apart from the oxazolidin-2-one carboxylic group), were synthesized in solution, by standard coupling reaction. The tendency of these pseudopeptides to form gels was evaluated using the inversion test of 10 mM solutions of pure compounds and of stoichiometric mixtures of pseudopeptides and metal ions. To obtain additional information on the molecular association, the gel samples were left dry in the air to form xerogels that were further analyzed using SEM and XRD. The formation of gel containing Zn(II) or Cu(II) ions gave good results in term of incorporation of the metal ions, while the presence of Cu(I), Al(III) and Mg(II) gave less satisfactory results. This outcome is a first insight in the formation of stable LMWGs formed by stoichiometric mixtures of pseudopeptides and metal ions. Further studies will be carried out to develop similar compounds of pharmacological interest.
Objectives To investigate the relationship between physical qualities and match activity profiles of recreational Australian football players. Design Prospective cohort study. Methods Forty players from three recreational Australian football teams (Division One, Two and Three) underwent a battery of fitness tests (vertical jump, 10 and 40m sprint, 6m×30m repeated sprint test, Yo-Yo intermittent recovery level Two and 2-km time trial). The activity profiles of competitive match-play were quantified using 10-Hz Global Positioning System units. Results Division One players possessed greater maximum velocity, Yo-Yo level Two and 2-km time trial performances than Division Two and Three players. In addition, Division One players covered greater relative distance, and relative distances at moderate- and high-intensities during match-play than Division Two and Three players. Division Two players had better 2-km time trial performances than Division Three players. Positive associations (P <0.05) were found between 10m acceleration, maximum velocity, Yo-Yo level Two and 2-km time trial performances and relative distance, and relative distances covered at moderate- and high-intensities during match-play. Moderate relationships were found between vertical jump and relative distance and high-intensity running. Conclusions Sub-elite Australian football players competing at a higher level exhibit greater physical qualities and match-play activity profiles than lesser-skilled recreational players. Acceleration and maximum velocity, 2-km time trial and Yo-Yo level Two performances discriminate between players of different playing levels, and are related to physical match performance in recreational Australian football. The development of these qualities is likely to contribute to improved match performance in recreational Australian football players.
For the past 25 years NIH Image and ImageJ software have been pioneers as open tools for the analysis of scientific images. We discuss the origins, challenges and solutions of these two programs, and how their history can serve to advise and inform other software projects.
In this study, we developed a novel free-standing sensor based on hierarchical zinc-doped nickel hydroxide nanosheets vertically attached three-dimensional (3D) framework (Zn-doped Ni(OH)2 NSs/3DF) via a mild and facile hydrothermal reaction for non-enzymatic glucose detection. The Zn-doped Ni(OH)2 NSs/3DF-based sensor exhibited a good sensitivity of 52μAμM−1 cm−2, wide linear detection range of 7.9nM to 15.2μM, and a low detection limit of 26.6nM. Besides, the respectable selectivity and excellent stability of such sensor were also demonstrated. The achieved results were due to the formation of the Zn-doped Ni(OH)2 NSs, which played an important role for promoting the electroactive sites and surface area, leading to the improvement of electrocatalytic activity towards glucose oxidation. In addition, the successful fabrication of a unique self-supported 3D hierarchical architecture not only produced the enhanced charge conductivity but also assisted to the sensing stability because it effectively avoided the agglomeration or exfoliation of NSs. The remarkable sensing activity and stability of the Zn-doped Ni(OH)2 NSs/3DF-based sensor offered a facile and appropriate approach towards glucose detection, which is highly promising to apply for practical clinical analyses.
We report novel hierarchical TiO2 nanorod (NR)/porous Co(OH)2 nanowall array electrodes for high-performance supercapacitors fabricated using a two-step process that involves hydrothermal and electrodeposition techniques. Field-emission scanning electron microscope images reveal a bilayer structure consisting of TiO2 NR arrays with porous Co(OH)2 nanowalls. Compared with the bare TiO2 NRs, the hierarchical TiO2 NRs/Co(OH)2 electrodes showed improved pseudocapacitive performance in a 2-M KOH electrolyte solution, exhibiting an areal specific capacitance of 274.3 mF cm−2 at a scan rate of 5mV s−1. The electrodes exhibited good stability, retaining 82.5% of the initial capacitance after 4000 cycles. The good pseudocapacitive performance of the hierarchical nanostructures is mainly due to the porous structure, which provides fast ion and electron transfer, a large surface area, short ion diffusion paths, and a favourable volume change during the cycling process.