batterydata/paper-abstracts huggingface dataset:
This paper proposes a novel and fast sizing method under the constant daily load profile for sizing a stand-alone PV system. The term “efficient sizing” means that the approach did not use simulation but could get the result as good as those employing simulation. So, the sizing method is more efficient than the others. Traditionally, a typical day or a typical year’s solar irradiation profile is employed for the sizing task. However, facing the global warming crisis as well as the fact that no 2years would have the same weather condition for a single site, this approach statistically models the trend of climate change year by year and put it into the sizing formula, so that the results are optimal for the current weather condition and for the future as well. Hence, the suitable size for the PV array and the number of batteries are obtained by purely computation. This is different from the traditional sizing curve method. Although the traditional sizing curve method were satisfactory in the normal cases, they might fail in the extreme climate condition. This paper concludes the behavior of the extreme climate for at least 20years. So, the derived system may have statistical confidence for at least 20years of operation. A new reliability index (Loss of Power Probability) in terms of Extreme Value Theory is introduced. LPP provides upper bound reliability for application and rich information for many extreme events. A technological and economical comparison among the traditional daily energy balance method, sizing curve method and this approach is conducted and shows the usefulness of this approach.
Chlorination remains a predominant method for disinfecting drinking water. Electrogeneration of chlorine has the potential to become the favoured method of chlorine production if costs can be lowered and chlorine generation efficiencies can be improved. A novel perforated electrode flow through (PEFT) cell design has been developed to address these problems. The electrodes were made from low-cost graphite sheets and stainless steel mesh and separated by a non-conducting fabric membrane. This electrode configuration allows reduction of electrode separation to 0.1 mm or less, minimizing cell resistance and increasing electrical efficiency. The new PEFT configuration generates hypochlorite from a 0.5 mol L−1 brine at a current efficiency of better than 60%. As an inline in situ device, it produces chlorine concentrations known to be sufficient to disinfect water, from chloride concentrations as low as 0.004 mol L−1 (available in most natural waters) by a single pass of the water through the cell operating at 11 V. The possibility of a portable device operated by a 12-V battery is indicated.
In this work, the effect of ethyl acetate as a co-solvent is investigated on the low-temperature performance of the lithium-ion battery. The cyclic voltammetry measurements show that the solid electrolyte interface formation as a result of the reduction of ethyl acetate occurs in 2.15 V on the graphite surface which is higher than that of electrolyte without ethyl acetate in 1.97 V. Addition of ethyl acetate to electrolyte decreases the charge transfer resistance and also the total resistance of lithium-ion battery. The scanning electron microscopy images show that the morphologies of layers formed by reduction of electrolytes without and with ethyl acetate at room temperature are different due to the facile reduction of ethyl acetate. At 25 °C, the capacity retentions of the 18650-type graphite/LiCo1/3Ni1/3Mn1/3O2 (NMC111) full-cells without and with ethyl acetate are 96.84% and 93.16% after 50 cycles, respectively, compared to their initial discharge capacities. At − 40 °C, the cell without ethyl acetate cannot operate due to the electrolyte freezing while the cell containing ethyl acetate shows the 59.33% capacity retention compared to its discharge capacity at room temperature.
While the primary reason for nanostructuring lithium-ion active materials is commonly the realization of shorter diffusion pathways for ions and electrons, there are also other, less-expected phenomena occurring when leaving the microscale to enter the nanoscale. Herein, we will present one of these phenomena - the thermally induced fragmentation (i.e., “chopping”) of oleic acid-capped anatase TiO2 nanorods perpendicular to the [001] direction. This fragmentation results in the formation of ultrafine TiO2 nanoparticles with increased (001) facets. Due to this modified surface facets ratio and the advantageous utilization of carboxymethyl cellulose as binder, these ultrafine nanoparticles present an excellent rate performance and cycling stability – even for cathodic cut-off potentials as low as 0.1 V.
A selective and sensitive electrochemical sensor has been prepared for the determination of 6-benzylaminopurine (BAP) in complex matrices. It was fabricated by thoroughly mixing multiwall carbon nanotube@SnS2 (MWNT@SnS2) with molecularly imprinted chitosan (CHIT), and then covering on the surface of glassy carbon electrode (GCE). The core/shell-structured MWNT@SnS2 dramatically improved the sensitivity of the developed sensor through providing increased binding and preconcentration onto the modified GCE, while CHIT imprinted with BAP served as the selective recognition sites. Several experimental parameters such as pH, amount of modifier, extraction time, and incubation time were optimized. Under the optimal conditions, selective detection of BAP in a linear concentration range of 0.1 nM–10 mM was performed with the detection limit of 50 pM (3Sb/S). The relative standard deviation of repeatability and reproducibility of the sensor was 1.14 and 2.42 %, respectively. Furthermore, the sensor was successfully applied to the determination of BAP in vegetable and fruit samples, indicating the molecularly imprinted polymer-based electrochemical sensing platform might provide a rapid, sensitive, and cost-effective strategy for BAP determination and related food safety analysis.
Novel polymer electrolyte aimed for space-selective electrochromic imaging was prepared with poly(vinylbutyral) (PVB), poly(ethyleneglycole) (PEG2000) and tetrabutylammonium perchlorate (TBAP). A spreading of the electrochromic image is a shortcoming when the electrochromic image is space-selectively formed by electrochemical reaction. This is due to a cell formation between colored and uncolored parts through ionic conductor. In order to inhibit the spreading, it would be effective to apply a polymer electrolyte with very low ionic conductivity at room temperature to the imaging system. On this basis, the present electrolyte was designed to have large difference in ionic conductivity between high and low temperatures. Namely, this polymer electrolyte enables writing and erasing at high temperature due to high ionic conductivity, and the image is expected to be preserved without change at ambient temperature due to very low ionic conductivity. The thermal and conductive properties of the polymer electrolyte were analyzed. Further, space-selective electrochromic image was formed on the device with the present polymer electrolyte at 100°C, and was revealed to be stable without change for more than a week when the device was kept at 20°C.
The search for hydrogen storage materials capable of efficiently storing hydrogen in a compact and lightweight package is one of the most difficult challenges for the upcoming hydrogen economy. Liquid chemical hydrides with high gravimetric and volumetric hydrogen densities have the potential to overcome the challenges associated with hydrogen storage. Moreover, the liquid-phase nature of these hydrogen storage systems provides significant advantages of easy recharging, and the availability of the current liquid fuel infrastructure for recharging. In this review, we briefly survey the research progress in the development of diverse liquid-phase chemical hydrogen storage materials, including organic and inorganic chemical hydrides, with emphases on the syntheses of active catalysts for catalytic hydrogen generation and storage. Moreover, the advantages and drawbacks of each storage system are discussed.
The purpose of this study was to evaluate the individualized and standardized quality of life (QL) and psychological distress of patients participating in a Phase I trial of the novel therapeutic reovirus (Reolysin).
In this work, dendritic silver–copper (Ag–Cu) nanostructures were synthesised on a copper foil by electrodeposition and subsequently galvanic displacement reaction without any surfactant. The crystalline nature of the nanostructures was examined by X-ray diffraction, and the morphology of the material was investigated by field-emission scanning electron microscopy. The applied potential, displacement reaction time, and silver nitrate solution concentration exerted different effects on the nanoparticle shape. And a possible growth mechanism of the Ag–Cu dendrites was proposed based on the experimental results. The electrochemical properties of the Ag–Cu dendrite-modified electrode were characterised by linear sweep voltammetry. The reduction peak potential of hydrogen peroxide (H2O2) was about −0.25 V (vs. a saturated calomel electrode), which indicated that the as-synthesised Ag–Cu dendrites had favourable electroreduction activity towards hydrogen peroxide. At the same time, we found that the solution pH also affected the electrocatalytic ability of the dendrites for H2O2 reduction, which was important for the design of a NaBH4–H2O2 battery.
This paper presents, AmbiKraf, a non-emissive fabric display that subtly animates patterns on common fabrics. We use thermochromic inks and peltier semiconductor elements to achieve this technology. With this technology we have produced numerous prototypes from animated wall paintings to pixilated fabric displays. The ability of this technology to subtly and ubiquitously change the color of the fabric itself has made us able to merge different fields and technologies with AmbiKraf. In addition, with an animated room divider screen, Ambikraf merged its technology with Japanese Byobu art to tighten the gap between traditional arts and contemporary technologies. Through this AmbiKraf Byobu art installation and other installations, we discuss the impact of this technology as a ubiquitous fabric display. With focus to improvements of some limitations of the existing system, we present our future vision that enables us to merge this technology into more applications fields thus making this technology a platform for ubiquitous interactions on our daily peripherals.
Internal resistance is a key parameter that affects the power, energy, efficiency, lifetime, and safety of a lithium-ion battery. It grows due to chemical and mechanical battery wear during ageing. In this work, the effect of the jelly-roll winding curvature on impedance rise is investigated. NMC electrode samples, harvested from the curved as well as the flat regions of the jelly-roll from cycle-aged and calendar-aged prismatic cells (25 Ah, hard casing) are investigated by electrochemical impedance spectroscopy. After cycling, larger impedance rise is observed at the outer radius (concave) of the curved region compared to the inner radius (convex) or the flat region of the jelly-roll, and the difference increases with a decrease in the jelly-roll radius of curvature, from the cell skin towards the core. To identify the causes behind the observed difference in the impedance rise, investigations at different external compression (0 and 2.5 MPa) and temperature (5 and 25 °C) are performed. The results show that contact loss between the current collector and the active layer is the main source of the difference in impedance rise. Mechanical mechanisms that may cause the contact loss are discussed and design recommendations to mitigate the rise in impedance are given.
Li1+ x (Mn1/3Co1/3Ni1/3)1− x O2 (x ≥ 0) mixed oxides with different Li/M molar ratios (M = Mn1/3Co1/3Ni1/3) were obtained. The materials were characterized using chemical analysis, X-ray diffraction measurement, particle size distribution measurement, BET, and QOCV measurement. Rate performance and cycling performance were evaluated. Increased Li/M molar ratio, especially 1.10 < Li/M < 1.15, resulted in better cycling and rate performance as well as higher first cycle coulombic efficiency. As the discharge capacity is lower when Li/M molar ratio is greater than 1.10, the optimum ratio seems to be around 1.10.
Behaviour links physiological function with ecological processes and can be very sensitive towards environmental stimuli and chemical exposure. As such, behavioural indicators of toxicity are well suited for assessing impacts of pesticides at sublethal concentrations found in the environment. Recent developments in video-tracking technologies offer the possibility of quantifying behavioural patterns, particularly locomotion, which in general has not been studied and understood very well for aquatic macroinvertebrates to date. In this study, we aim to determine the potential effects of exposure to two neurotoxic pesticides with different modes of action at different concentrations (chlorpyrifos and imidacloprid) on the locomotion behaviour of the water louse Asellus aquaticus. We compare the effects of the different exposure regimes on the behaviour of Asellus with the effects that the presence of food and shelter exhibit to estimate the ecological relevance of behavioural changes. We found that sublethal pesticide exposure reduced dispersal distances compared to controls, whereby exposure to chlorpyrifos affected not only animal activity but also step lengths while imidacloprid only slightly affected step lengths. The presence of natural cues such as food or shelter induced only minor changes in behaviour, which hardly translated to changes in dispersal potential. These findings illustrate that behaviour can serve as a sensitive endpoint in toxicity assessments. However, under natural conditions, depending on the exposure concentration, the actual impacts might be outweighed by environmental conditions that an organism is subjected to. It is, therefore, of importance that the assessment of toxicity on behaviour is done under relevant environmental conditions.
MnO nanoparticles with diameter about 5nm are uniformly dispersed within a spherical carbon matrix by an in-situ adsorption approach. This unique nanostructure with rational design and engineering not only possesses large elastic buffering space to prevent MnO nanoparticles from agglomeration, but also improves lithium-storage properties because the carbon matrix provides continuous path for Li-ion and electron diffusion inside the composite spheres. The cell assembled with the nanostructure composite exhibits high reversible specific capacity of 501mAh/g (exceeding pure MnO particles of 199mAh/g) after 300 cycles at 0.5A/g, excellent cycling stability with 81% capacity retention after 300 cycles, and enhanced rate performance up to 161mAh/g at 5A/g with only 13% capacity fade after 200 cycles. Due to the scale-producible fabrication steps under low temperature for this approach, the method can be used for the preparation of other nanostructures with high performance.
Negative symptoms often inhibit the social integration of people suffering from schizophrenia. Reducing severe negative symptoms (SNS) in a clinically relevant way is a major unmet need. The aim of this study was to investigate whether Integrated Neurocognitive Therapy (INT), a group cognitive remediation therapy (CRT), reduces SNS in schizophrenia outpatients. INT was compared with Treatment As Usual (TAU) in a randomized-controlled trial (RCT). A total of 61 SNS outpatients participated in the study, 28 were allocated to the INT group and 33 to the TAU group. A test-battery was used at baseline, post-treatment at 15weeks, and 1-year-follow-up. Remission rates of SNS after therapy were significantly higher for INT compared to TAU. A trend favoring INT was obtained at follow-up. Furthermore, INT showed significantly higher functional outcome during follow-up compared to TAU. Regarding cognition, the strongest significant effect was found in attention post-treatment. No effects between groups on more complex neurocognition and social cognition were evident. SNS outpatients seem to accept INT group intervention as suggested by the high attendance rate.
In this paper we present our studies on the properties of battery electrolyte based on EC/DMC (ethylene carbonate/dimethyl carbonate, w/w ratio 2:5) and PEODME (poly(ethylene oxide) dimethyl ether) (M w =500) doped with LiCF3SO3–lithium trifluoromethanesulfonate (LiTf) and modified with TPFPB (tris(pentafluorophenyl)borane) as a potential anion trapping agent. We were particularly interested how this compound behaves in different solvents, e.g. battery mixture EC/DMC and model polymeric matrix PEODME. We also verified stability of the proposed solutions by means of DSC and FTIR, determined influence on conductivity and lithium transference numbers by impedance spectroscopy, and finally attempted to define mechanism of influence of boron addition on different systems.
A mixture of flammable organic solvent and nonflammable room temperature ionic liquid (RTIL) has been investigated as a new concept electrolyte to improve the safety of lithium-ion cells. This study focused on the use of N-methyl-N-propylpiperidinium bis (trifluoromethanesulfonyl) imide (PP13-TFSI) as the RTIL for the flame-retardant additive. It was found that a carbon negative electrode, both graphite and hard carbon, could be used with the mixed electrolyte. A 383562-size lithium-ion trial cell made with the mixed electrolyte showed good discharge capacity, which was equivalent to a cell with conventional organic electrolyte up to a discharge current rate of complete discharge in 1h. Moreover, the mixed electrolyte was observed to be nonflammable at ionic liquid contents of 40mass% or more. Thus the mixed electrolyte was found to realize both nonflammability and the good discharge performance of lithium-ion cells with carbon negative electrodes. These results indicate that RTILs have potential as a flame-retardant additive for the organic electrolytes used in lithium-ion cells.
The tripartite model (Clark and Watson, Journal of Abnormal Psychology, 100(3), 316–336 1991) was developed to explain both the strong comorbidity and the distinction between anxiety and depression. The model includes a shared general distress factor that is most strongly associated with Neuroticism/Negative Emotionality (N/NE); a unique depression factor, anhedonia, which is most strongly associated with low Positive Emotionality/Extraversion; and anxious arousal, a unique anxiety factor that subsequent research has shown to be most strongly related to panic/agoraphobia among the anxiety disorders (e.g., Mineka et al. Annual Review of Psychology, 49, 377–412 1998) and to have the weakest link to personality. The present study extends past work by demonstrating that narrower facets of personality domains show nuanced relations that are masked when only the broader domains are examined. Specifically, we investigated facet-level relations of the tripartite model’s symptom dimensions using three hierarchical personality measures (BFI-2, NEO-PI-3, and FI-FFM) and data from three separate samples (Ns = 353–451). In one sample, the tripartite-model dimensions were assessed twice across a 9.5-month interval. At the domain level, N/NE, Extraversion, and Conscientiousness were the strongest predictors of these factors. At the facet level, general distress and anhedonia were most strongly related to N/NE’s Depression facet; anhedonia also was substantially linked to the low Energy/Positive Temperament component of Extraversion. Finally, anxious arousal was best predicted by the Somatic Complaints facet of N/NE. This pattern of results was highly stable across measures, samples, and time points. Theoretical implications of the findings are discussed, including connecting these findings to the dimensional Hierarchical Taxonomy of Psychopathology framework.
Introductions of non-native fish have the potential to cause substantial economic and ecological losses. In the western United States, non-native brook trout (Salvelinus fontinalis) are widely established and pose a threat to the persistence of bull trout (Salvelinus confluentus), a native char listed as threatened under the US Endangered Species Act, due to competition and hybridization. With brook trout identified as a factor limiting the recovery of ESA-listed bull trout in the Malheur Watershed of eastern Oregon, managers are pursuing brook trout eradication efforts. Key to the eradication efforts is reliable monitoring to ensure success. Traditional monitoring practices have included mechanical sampling methods such as seining, netting, and electrofishing, all of which are labor intensive and limited in reliability. Environmental DNA (eDNA) is genetic material naturally shed by organisms that can be found in bulk environmental samples without isolating individual organisms. Sampling for eDNA can often be done with less time and expense than traditional methods, making it ideal for effectiveness monitoring following fish eradication efforts. This study placed a single fish in a live-car where the species was not otherwise present and used eDNA sampling to infer the likelihood of detection downstream. Results suggest that a single fish can be detected reliably up to 500 m downstream when multiple samples are taken. This eDNA sampling method provides managers with the ability to conduct eradication effectiveness monitoring reliably and rapidly and may also be used to detect new fish invasions as well as rare or cryptic species.
A manual purge line was added into the exterior fuel exhaust stream of a Ballard PEM stack in a Nexa™ power module. With the addition of manual exhaust purge, high levels of inert gases were intentionally added to the anode feed without changing normal operational procedures. A new method of determining the critical minimum flow rate in the anode exhaust stream was given by an anode mass balance. This type of operation makes dual use of membranes in the MEAs as both gas purifiers and as solid electrolytes. The PEM stack was successfully operated with up to ca. 7% nitrogen or carbon dioxide in the absence of a palladium-based hydrogen separator at ca. 200W power level. Nitrogen in the anode stream was concentrated from 7.5% to 91.6%. The system maintained a fuel efficiency of 99% at a manual purge rate of 2.22mls−1 and no auto purge. The fuel cell stack efficiency was 64% and the stack output efficiency was 75%. The overall system efficiency was 39%. After troublesome CO and H2S poisons were removed, a hydrocarbon reformate containing high levels of CO2 and H2O was further used in the Nexa™ stack. The size and complexity of the fuel processing system may be reduced at a specified power level by using this operational method.
A facile method that improves the initial specific capacity and capacity retention rate of lithium-sulfur (Li-S) batteries, using silica-back-coated nickel foam has been studied. A new cathode collector in which silica is back-coated onto the nickel foam is fabricated by a facile method that utilizes an ultrasonicator for reducing the electrolyte viscosity at the surface of the sulfur electrode using a polysulfide absorbent. The nickel foam provides more reaction sites than an aluminum current collector does, thus allowing the back-coated silica to absorb the polysulfides. This synergetic effect of nickel foam and silica suppresses the increasing viscosity of the electrolyte and leads to a higher initial specific capacity (1341 mAh/g) at a 0.2-C rate and a higher capacity retention rate after 150 cycles (85%), relative to pristine Li-S batteries (951 mAh/g and 79%, respectively).