batterydata/paper-abstracts huggingface dataset:
Wireless sensor networks composed of battery-powered sensor nodes are invaluable instruments for remote environment sensing. For sensor network applications, sensed readings are often collected in the form of aggregated data from a portion of a sensor network as requested by spatial aggregation queries. In a large distributed sensor network, queries can be issued from various locations at any time. Existing in-network query execution techniques execute queries independently that considerably overconsumes the precious energy of sensor nodes. As a result, the lifespan of a sensor network is inevitably shortened. In this paper, we propose a Materialized In-Network View (MINV) framework that precalculates aggregated data from clusters of sensor nodes as intermediate query results preserved in the network and made ready for queries. The executions of queries are performed as simple collections of these aggregated data. Thus, the quantities and sizes of messages transmitted among sensor nodes can be greatly reduced, thus prolonging the lifetime of a sensor network. Through extensive simulations, the effectiveness of our proposed framework is validated.
Efficient, durable and low cost electrocatalysts for O2 and CO2 reductions are required as alternate to expensive metal based catalysts in fuel cells and in the CO2 reduction process. Herein, we describe the synthesis of reduced graphene oxide (rGO)-nickel phthalocyanine (NiPc) composite (rGO-NiPc) as a bifunctional electrocatalyst for O2 and CO2 reductions. The composite material, rGO-NiPc is coated on glassy carbon (GC) electrode (GC/rGO-NiPc) and used as a low cost efficient electrocatalyst for O2 and CO2 reductions. The results show that the addition of rGO to NiPc increases the catalytic efficiency and electrochemical charge transfer rate of NiPc. GC/rGO-NiPc provides the low potentials, +0.25 and −0.11 V (vs RHE) for O2 and CO2 reductions, respectively in 0.1 M HClO4. Kinetic interpretation based on rotating disc electrode studies provides the support for the two electron pathway for CO2 reduction to CO in 0.1 M HClO4. Product analysis by 13C NMR confirms CO as the CO2 reduction product. GC/rGO-NiPc shows a facile four electron pathway for O2 reduction which can be exploited in fuel cells, metal-air batteries, chlor-alkali electrolyzers and oxygen sensing. In addition, GC/rGO-NiPc has efficient methanol tolerance capability for O2 reduction process which is suitable to use in fuel cells. Moreover, GC/rGO-NiPc shows the high operational stability more than an hour for both O2 and CO2 reductions in 0.1 M HClO4.
The aim was to learn about responsible management in private sector nano enterprises by telephone conversations with lead technologists and managers in companies in the US Midwest. The conversations took place between January and March of 2011. The marked increase starting in 2008 of prescriptive documents such as guidelines, codes of responsibility, and best practices in NanoEthicsBank offered an entry point for initiating the conversations. Had respondents noticed these documents and did they find them useful? Follow-up questions asked about the full life cycle of their products. The responses from 22 of the 25 organizations selected are categorized in 5 groups according to how they described their nano materials/business. A conception of responsible management in organizations is provided to underpin the analysis of the responses. This conception features virtues of concern, care, and foresight implied by a fundamental moral obligation. In the analysis, definitions from the Organization for Economic Cooperation and Development (OECD) and the International Standards Organization (ISO) are used as a basis of comparison in assessing respondents’ claims. Two important gaps are identified. One gap is between actual practices and the prescriptive use of the conception of responsible management in organizations. The other gap is between the actual use of nano terminology and OECD definitions.
The organophosphorus compounds tris(trimethylsilyl) phosphite (TMSP) and vinylene carbonate (VC) have been considered for use as functional additives to improve the electrochemical performance of Li1.1Mn1.86Mg0.04O4 (LMO)/graphite full cells. Our investigation reveals that the combination of VC and TMSP as additives enhances the cycling properties and storage performance of full cells at 60°C. The unique functions of the TMSP additive in the VC electrolyte are investigated via ex situ X-ray photoelectron spectroscopy (XPS) and 19F nuclear magnetic resonance (NMR) measurements. The TMSP additive effectively eliminates trace water and hydrogen fluoride (HF) and produces a protective film on the LMO cathode that alleviates manganese dissolution at 60°C.
Sensor localization is demanded by wireless sensor networks, since the collected sensor data are meaningless if the position of the generating sensor is not available. The traditional approach of using GPS for location determination is not suitable for sensor networks, due to the increased costs and resource usage. For this reason, sensors exchange Radio Frequency messages, so as to measure their respective distances and determine their locations by means of multilateral triangulation with sensors of known positions, called anchors. Such an approach, however, is particularly vulnerable to several kinds of attacks aiming at causing wrong position estimations with a malicious intention. Such attacks can be tolerated with proper countermeasures, belonging to the so called secure localization, but this is achieved at the expenses of high costs in terms of exchanged messages and exhausted sensor resources, such as the battery. For these reasons, it is crucial to use the secure localization only when needed in order to extend considerably the life span of the sensors. Therefore, we propose to model the interaction of an anchor with a sensor as a signaling game, and to use such a formalization to discipline the use of secure positioning methods based on the received messages from the anchors. We have proved with simulations that such a solution is more efficient than a naive one of always applying secure localization.
Vanadium pentoxide (V2O5) is an attractive cathode material for lithium-ion batteries (LIBs) because of its low cost, high abundance, and relatively high theoretical capacity (294mAhg−1 with two lithium insertions/extractions per unit formula at 2.0–4.0V). However, practical applications of V2O5 are hampered by its poor structural stability, low electrical conductivity, and slow ion diffusion kinetics, resulting in poor long-term cycling stability and rate performance. In this study, V2O5 nanoparticles are synthesized by a fast sol-gel method with citric acid (C6H8O7) at 400, 500, 600, and 700°C. The thickness of the amorphous layers on the surface of the V2O5 nanoparticles is controlled from approximately 4–5 to 1–2nm by adjusting the calcination temperature. The V2O5 nanoparticles synthesized at 600°C show better electrochemical performances than the other samples. They exhibit a high initial discharge capacity of 276mAhg−1 between 2.1 and 4.0V at a rate of 1C, and good capacity retention of 83% after 50 cycles. Even at 10C rate, a discharge capacity of about 168mAhg−1 is obtained after 100 cycles. The excellent rate capability and cycling stability are also achieved at current densities of 0.5–20C.
Herein, we designed a versatile cell for operando X-ray absorption spectroscopy (XAS) monitoring of chemical and physical transformations in liquid solutions and dispersions by fluorescence-yield detection. The cell operates under atmospheric pressure, and the composition of the gas phase can be varied, allowing monitoring of gas–liquid reactions. Samples can be examined as a flowing liquid-jet or as a sessile droplet. Both liquid-jet and droplet operations of the cell were demonstrated at the Ca K-edge through time-resolved studies of CaCO3 formation from CO2 and solid Ca(OH)2 in an aqueous suspension. The liquid-jet reaction was performed at 28 °C, and the droplet reaction was performed at ambient temperature, but both configurations had the scope to be modified for operations at higher temperatures. The liquid-jet volumes were recycled, permitting the use of the cell in a continuous sampling loop for process studies in larger reactor vessels. The jet supply tube was interchangeable, permitting adjustment of the jet size through the tubing bore size. Larger bore sizes minimized the pressure drop at the nozzle and thereby the risk of blockage of the liquid supply by the suspended particulates or growth of solid deposits. Sessile droplet operation enabled studies with minimal sample volumes and mechanical disturbances under controlled environmental conditions. The cell is portable and modular and is based on readily available standard vacuum equipment parts. Furthermore, the operation under a He atmosphere allows measurements above 4 keV, covering part of the tender X-ray range, and it is also applicable to the hard X-ray range.
Numerous studies have been published on the psychosis prodrome and have explored a wide array of its many aspects. However, the set of risk factors identified by these various efforts is not homogenous across studies. This could be due to unique population factors or relatively small sample sizes. Only few studies were conducted on Asian populations, whose socio-cultural characteristics differ – in some cases remarkably – from those in western populations. Singapore is a highly dense city-state in South-east Asia, with low rates of substance abuse. The Longitudinal Youth at Risk Study (LYRIKS) commenced in Singapore in 2008, designed to comprehensively assess a group of ultra high risk (UHR) individuals and identify clinical, social, neuropsychological and biological risk factors unique to the local population. 173 UHR individuals were recruited from this single-site study over 4years. Here, we detail aspects of the study methodology and report on the baseline social and clinical characteristics of the sample population. 78% of the UHR sample suffered from a psychiatric disorder, with Major Depressive Disorder present in more than half of the sample. The mean Global Assessment of Functioning (GAF) score was 57.4, which indicated a moderate level of impairment. Although the recruited sample did not differ significantly by social and clinical characteristics when compared to previously published reports, the conversion rate to psychosis was 3.5% (n=6) at 6months. Follow-up measures are currently underway to assess longitudinal incidence of psychosis and impact of risk factors on cognition, functioning and remission.
The term sepsis is used to designate a systemic condition of infection and inflammation associated with hemodynamic changes that result in organic dysfunction. Gestational sepsis can impair the development of the central nervous system and may promote permanent behavior alterations in the offspring. The aim of our work was to evaluate the effects of maternal sepsis on inflammatory cytokine levels and synaptic proteins in the hippocampus, neocortex, frontal cortex, and cerebellum of neonatal, young, and adult mice. Additionally, we analyzed the motor development, behavioral features, and cognitive impairments in neonatal, young and adult offspring.
The discovery and validation of biomarkers in neurological and neurodegenerative diseases is an important challenge for early diagnosis of disease and for the development of therapeutics. Epilepsy is often a consequence of brain insults such as traumatic brain injury or stroke, but as yet no biomarker exists to predict the development of epilepsy in patients at risk. Given the complexity of epilepsy, it is unlikely that a single biomarker is sufficient for this purpose, but a combinatorial approach may be needed to overcome the challenge of individual variability and disease heterogeneity. The goal of the present prospective study in the lithium–pilocarpine model of epilepsy in rats was to determine the discriminative utility of combinations of phenotypic biomarkers by examining their ability to predict epilepsy. For this purpose, we used a recent model refinement that allows comparing rats that will or will not develop spontaneous recurrent seizures (SRS) after pilocarpine-induced status epilepticus (SE). Potential biomarkers included in our study were seizure threshold and seizure severity in response to timed i.v. infusion of pentylenetetrazole (PTZ) and behavioral alterations determined by a battery of tests during the three weeks following SE. Three months after SE, video/EEG monitoring was used to determine which rats had developed SRS. To determine whether a biomarker or combination of biomarkers performed better than chance at predicting epilepsy after SE, derived data underwent receiver operating characteristic (ROC) curve analyses. When comparing rats with and without SRS and sham controls, the best intergroup discrimination was obtained by combining all measurements, resulting in a ROC area under curve (AUC) of 0.9592 (P<0.01), indicating an almost perfect discrimination or accuracy to predict development of SRS. These data indicate that a combinatorial biomarker approach may overcome the challenge of individual variability in the prediction of epilepsy.
Movement disorders are frequently encountered in the clinic, but establishing the correct diagnosis can be problematic, especially if the clinical presentation is complex. In this article, Adbo et al. provide a practical guide to pattern recognition in movement disorders and discuss how a clinically classified syndrome might be translated into an etiological diagnosis.
Objectives Sleep and vigilance disorders are among the most commonly reported symptoms following a concussion. The aim of the study was thus to investigate the effects of sport-related concussions on subjective and objective sleep quality. Methods Ten concussed athletes and 11 non-concussed athletes were included. Concussed athletes had a history of 4.6±2.1 concussions with at least one concussion during the last year. They were recorded for two consecutive nights in the laboratory and during a 10-min period of wakefulness. They completed questionnaires related to sleep quality and symptoms as well as neuropsychological tests and the CogSport computer battery. Results Concussed athletes reported more symptoms and worse sleep quality than control athletes, but no between-group differences were found on polysomnographic variables or on REM and NREM sleep quantitative EEG variables. However, concussed athletes showed significantly more delta activity and less alpha activity during wakefulness than did control athletes. Conclusion In spite of the subjective complaints in sleep quality of concussed athletes, no change was observed in objective sleep characteristics. However, concussions were associated with an increase in delta and a reduction in alpha power in the waking EEG. Sport-related concussions are thus associated with wakefulness problems rather than sleep disturbances.
Open fractures frequently result in serious complications for patients, including infections, wound healing problems, and failure of fracture healing, many of which necessitate subsequent operations. One of the most important steps in the initial management of open fractures is a thorough wound irrigation and debridement to remove any contaminants. There is, however, currently no consensus regarding the optimal approach to irrigating open fracture wounds during the initial operative procedure. The selection of both the type of irrigating fluid and the pressure of fluid delivery remain controversial. The primary objective of this study is to investigate the effects of irrigation solutions (soap vs. normal saline) and pressure (low vs. high; gravity flow vs. high; low vs. gravity flow) on re-operation within one year among patients with open fractures.
This investigation examined vagal modulation of arousal, as indexed by respiratory sinus arrhythmia (RSA), as a moderator of the covariance between interpretation biases and anxiety disorder symptom severity in a diverse sample of clinically anxious youth. A sample of 105 children with anxiety disorders (Mage = 10.07 years, SD = 1.22; range = 8–12 years; 57.1% female; 61.9% ethnic minority) and their mothers completed a battery of measures assessing interpretation biases and anxiety disorder symptom severity. Children also completed a behaviorally-indexed assessment of interpretation biases and participated in an anxiety-provoking speech task. Physiological assessment of RSA was collected at baseline (i.e., baseline RSA) and during the speech task (i.e., challenge RSA). The interaction between challenge RSA and both self-reported and behaviorally-indexed interpretation biases (adjusting for baseline RSA) was significant (ΔR2 = .05 and .04 respectively) in relation to maternal report of child anxiety symptoms. Specifically, among children with low (vs. high) challenge RSA, greater self-reported interpretation biases were significantly associated with maternal report of more severe child anxiety symptoms, and greater behaviorally-indexed interpretation biases were marginally associated with maternal report of more severe child anxiety. Interactions predicting child self-report of anxiety symptoms were not significant. Greater child interpretation biases coupled with lower challenge RSA were associated with maternal report of more severe child anxiety symptoms. Future work should examine whether interventions targeting RSA weaken the association between interpretation biases and anxiety symptoms in youth.
The rapid charging or discharging characteristics of battery energy storage system is an effective method to realize load shifting in distribution network and control the fluctuations of load power substantially. However, the type selection and capacity configuration of the batteries will be directly related to the economy of energy storage system for load shifting in the distribution network. An optimized model of hybrid battery energy storage system based on cooperative game model is proposed in this paper, in which lead-acid battery, lithium ion battery and vanadium redox flow battery are respectively regarded as the participants of the cooperative game model, the cost and benefit models are established in their corresponding game strategy spaces. The Nash equilibrium solutions of each game model obtained by genetic algorithm are applied to the planning and design of battery energy storage station with the most economical types of the batteries and the optimal capacity configuration of energy storage station. The simulation results verify the effectiveness of the proposed method and provide a theoretical basis for the planning and design of battery energy storage station.
Herein, we report for the first time synthesis and electrochemical supercapacitance performance of 3-D hierarchical porous “Green” carbon derived from Pongamia pinnata seed oil extract cake and its activation using different amounts of KOH. Also, nanocomposites of multiwalled carbon nanotubes (MWCNT) with various weight percentages of Ni and Co were prepared by hydrothermal method. Physico-chemical properties of “Green” carbon and nanocomposites were analyzed by Powder X-ray Diffraction, Brunner Emmett Teller surface area, Scanning Electron Microscopy-Elemental Dispersive Spectrum, Transmission Electron Microscopy and Raman techniques. KOH activated carbon was found associated with combination of micropores & mesopores while the nanocomposite with mixture of spinel NiCo2O4 and Ni(OH)2. Porous carbon activated with 2:1::KOH:C (KC2) and the nanocomposite with 1:1 Ni & Co (NC1) exhibited excellent electrochemical performance in three electrode system. Further, fabricated asymmetric supercapacitor (AS) device Ni-Co-MWCNT (NC1)//KC2 exhibited specific capacitance (Cs) of 177 F/g as determined by cyclic voltammetry at 10 mV/s and retained 90% even at 3000th cycle in life cycle test conducted at high current density of 50 A/g. In order to evaluate its practical performance, the AS device was charged to 1.8 V at 5 A/g and used successfully to power a calculator for more than 1 h.
Porous CuO nanosphere films have been successfully prepared through post-heat treatment of Cu2(OH)2CO3 nanosphere films, which were formed on copper foil immersed in a water-in-oil (W/O) microemulsion. The electrochemical performance of the porous CuO nanosphere film as anode materials for lithium ion batteries indicates that at the current density of 0.1C, it exhibits higher initial coulombic efficiency (70.4%) and reversible discharge capacity (799.7mAhg−1 after 100cycles) than the CuO nanorod film on copper foil, which was obtained via aqueous solution oxidation reaction followed by post-heating in N2 flow. The excellent performance can be attributed to the novel porous nanosphere structure grown on the current collecting substrate, which could not only shorten the diffusion path of lithium ion and provide appropriate contact area between electrode and electrolyte, but also increase the electrical conductivity of the electrode. More generally, the strategy based on synthesis within confined reaction media, rather than direct synthesis in bulk solution, offers a new approach to the design of micro/nanostructured transition metal oxides grown on the current collecting substrate used as anodes in lithium ion batteries with enhanced electrochemical performance.
Nanocomposite of benzenesulfonic functionalized multi-walled carbon nanotubes doped polyaniline (PANi/f-MWCNTs) was synthesized via a low-temperature in situ polymerization method. The PANi/f-MWCNTs composite has a thin film of PANi coating uniformly on the surface of the f-MWCNTs. The electrochemical results show that PANi/f-MWCNTs nanocomposite possesses good rate response, which could ascribe to the uniform structure and the better conductivity of composite as well as the in situ doping/de-doping process between the benzenesulfonic acid groups of f-MWCNTs and PANi chain. In addition, the composite also has better capacity and cyclability than PANi/p-MWCNTs composite. It could attribute to the presence of f-MWCNTs, which makes more electrolyte contact with PANi to participate in faradaic redox reactions and dopes with the PANi polymer chain through the benzenesulfonic acid groups to form stable polyemeraldine salts.
A multi-functional electrochromic material which modulates light over a wide spectral range and stores electrical energy is an intriguing substance, which would lead to a variety of novel applications, such as smart windows for energy-efficient buildings, solar power storage, nonemissive displays, electronic paper, optoelectronic switches, and variable-reflectance mirrors/surfaces. Developing such a versatile material entails merging the electrochromic phenomenon with electrical-chemical energy conversions in an electrochromic-battery platform. However, the challenges related to transition metal oxide electrochromic-batteries include poor energy storage, low optical contrast, and high fabrication cost. Here, we demonstrate the synthesis of aqueous nanocrystalline colloidal molybdenum oxide in a matrix of tungsten molybdenum oxide (MoO3-W0.71Mo0.29O3) for solution-processed fully reversible switching electrochromic-battery electrodes. The hybrid material exhibits both 50% optical contrast modulation over a wide optical bandwidth and an improved Columbic efficiency. An 8 × 8 cm2 energy storing smart (ESS) window is assembled to demonstrate a functional prototype that can power an LED for more than 10 min when charged under −2.5 V for 1 min. The enhanced electrochromic performance, high energy storage capacity, simple solution processability, versatility for large area fabrication, and low cost make this nanocrystalline MoO3-W.71Mo.29O3 composite a promising material with the potential to be deployed ubiquitously in energy-efficient smart window architectures.