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The structure and electrochemical characteristics of melted composite Ti0.10Zr0.15V0.35Cr0.10Ni0.30 + x% LaNi4Al0.4Mn0.3Co0.3 (x = 0, 1, 5) hydrogen storage alloys have been investigated systematically. XRD shows that though the main phase of the matrix alloy remains unchanged after LaNi4Al0.4Mn0.3Co0.3 alloy is added, a new specimen is formed. The amount of the new specimen increases with increasing x. SEM-EDS analysis indicates that the V-based solid solution phase is mainly composed of V, Cr and Ni; C14 Laves phase is mainly composed of Ni, Zr and V; the new specimen containing La is mainly composed of Zr, V and Ni. The electrochemical measurements suggest that the activation performance, the low temperature discharge ability, the high rate discharge ability and the cyclic stability of composite alloy electrodes increase greatly with the growth of x. The HRD is controlled by the charge-transfer reaction of hydrogen and the hydrogen diffusion in the bulk of the alloy under the present experimental conditions.
This paper examines the relationship between fiscal policy and the current account, drawing on a large sample of advanced, emerging, and low-income economies and using a variety of statistical methods: panel regressions, an analysis of large fiscal policy and current account changes, and panel vector autoregressions (VAR). On average, across estimation methods, a strengthening in the fiscal balance by 1 percentage point of GDP is associated with a current account improvement of about 0.3 percentage point of GDP. With our preferred estimation method (quarterly structural VAR using government consumption to identify fiscal policy shocks), the relationship is stronger, in the 0.3–0.5 range. The association is stronger in emerging markets and low-income countries; in economies that are more open to trade; and when the economy is somewhat overheated to begin with. The effect is, however, notably weaker during episodes of large fiscal policy and current account changes, suggesting that fiscal policy may have a more limited role in correcting large external imbalances.
The electrochemical behaviour and thermal stability of functional electrolyte additives for Li-ion batteries is investigated. The Li-ion cell systems is comprised of an anode of mesocarbon microbeads (MCMB) and a cathode (LiCoO2) in a solution of 1.1M LiPF6 dissolved in ethylene carbonate and ethylmethyl carbonate (EC:EMC; 4:6, v/v). Vinyl acetate (VA) and vinylene carbonate (VC) in an ionic electrolyte containing triphenylphosphate (TPP) are tested as functional electrolyte additives. The main analysis tools used in this study are cyclic voltammetry (CV), differential scanning calorimetry (DSC), electrochemical impedance spectroscopy (EIS), and scanning electron microscopy (SEM). Cells containing VA or VC exhibit excellent irreversible capacity, coulombic efficiency, rate capability and cycleability. These features confirming the effectiveness of VC addition for improving both the cell performance and the thermal stability of electrolytes in TPP-containing solutions for Li-ion batteries.
Metallic antimony with high capacity, abundant and a very appropriate reaction potential is considered as a promising anode material for LIBs. But poor cycle performance due to the huge volume expansion during cycling process seriously hinders its practical application. Here, Sb nanoparticles encapsulated into carbon nanosheets were prepared by a facile and scalable method. And the carbon nanosheets can effectively buffer the volume expansion and inhibit the aggregation of Sb nanoparticles during the lithiation/delithiation process. Finally, the as-prepared Sb@C nanosheets display superior rate capability (418 mAh g−1 can be observed even at 5.0 A g−1) and long cycle stability (449 mAh g−1 can be maintained after 1000 cycle at 2.0 A g−1). Furthermore, when coupled with LiFePO4/C cathode, the Sb@C//LiFePO4/C full cell also exhibits outstanding electrochemical performance.
Patients who suffer from alcohol use disorders (AUDs) usually go through various socio-behavioral and pathophysiological changes that take place in the brain and other organs. Recently, consumption of unhealthy food and excess alcohol along with a sedentary lifestyle has become a norm in both developed and developing countries. Despite the beneficial effects of moderate alcohol consumption, chronic and/or excessive alcohol intake is reported to negatively affect the brain, liver and other organs, resulting in cell death, organ damage/failure and death. The most effective therapy for alcoholism and alcohol related comorbidities is alcohol abstinence, however, chronic alcoholic patients cannot stop drinking alcohol. Therefore, targeted therapies are urgently needed to treat such populations. Patients who suffer from alcoholism and/or alcohol abuse experience harmful effects and changes that occur in the brain and other organs. Upon stopping alcohol consumption, alcoholic patients experience acute withdrawal symptoms followed by a protracted abstinence syndrome resulting in the risk of relapse to heavy drinking. For the past few decades, several drugs have been available for the treatment of AUDs. These drugs include medications to reduce or stop severe alcohol withdrawal symptoms during alcohol detoxification as well as recovery medications to reduce alcohol craving and support abstinence. However, there is no drug that completely antagonizes the adverse effects of excessive amounts of alcohol. This review summarizes the drugs which are available and approved by the FDA and their mechanisms of action as well as the medications that are under various phases of preclinical and clinical trials. In addition, the repurposing of the FDA approved drugs, such as anticonvulsants, antipsychotics, antidepressants and other medications, to prevent alcoholism and treat AUDs and their potential target mechanisms are summarized.
Summary Peripheral nerve injures are common and often result in impaired functional recovery. The majority of injuries involve the arm and/or the hand. The traditional treatment for peripheral nerve injuries is repair by using microsurgical techniques, either by primary nerve suture or nerve graft, but research to find more successful methods that could improve recovery is ongoing. Tubulisation has been investigated by several authors and is suggested as an alternative to microsurgical techniques. The resorbable poly[(R)-3-hydroxybutyrate] (PHB) is one of the materials that has been previously tested experimentally. In this prospective, randomised, assessor-blinded clinical study, PHB was investigated as an alternative to epineural suturing in the treatment of peripheral nerve injuries at the wrist/forearm level of the arm. Twelve patients, with a complete, common, sharp injury of the median and/or ulnar nerve at the wrist/forearm level, were treated by either using PHB or microsurgical epineural end-to-end suturing. All patients were assessed using a battery of tests, including evaluation of functional, sensory and motor recovery by means of clinical, neurophysiological, morphological and physiological evaluations at 2 weeks and 3, 6, 9, 12 and 18 months after surgery. No adverse events or complications considered as product related were reported, and thus PHB can be regarded as a safe alternative for microsurgical epineural suturing. The majority of the methods in the test battery showed no significant differences between the treatment groups, but one should consider that the study involved a limited number of patients and a high variability was reported for the evaluating techniques. However, sensory recovery, according to the British Medical Research Council score and parts of the manual muscle test, suggested that treating with PHB may be advantageous as compared to epineural suturing. This, however, should be confirmed by large-scale efficacy studies.
The design and testing of a robotic analyzer for autonomous TCO2 measurement from oceanographic moorings is described. The analyzer employs a conductimetric method of TCO2 measurement wherein CO2 from an acidified sample diffuses across a semi-permeable membrane into a NaOH solution decreasing the conductivity of the base. The instrument is capable of ∼850 analyses over a period of at least six months. It is designed to operate to depths of at least 1000m. TCO2 calibration is based on in situ standardization throughout a deployment. We report both laboratory and in situ tests of the analyzer. In the laboratory automated analyses over a period of 38 days at temperatures ranging from 8° to 25°C yielded a TCO2 accuracy and precision of ±2.7μmol/kg. In situ tests were conducted at the WHOI dock with a deployment of 8 weeks at in situ temperatures of 5°–13°C. The accuracy and precision of TCO2 analyses over the deployment period, based on in situ calibration, was ±3.6μmol/kg. Laboratory tests of reagent and standard solution stability are also reported. Standards, based on Certified Reference Material were followed for periods of up to 2 years. In all cases TCO2 increased. Drift of the standards was the equivalent of ∼1 to 3μmol/kg per 6 months. The conductivity indicator solution was found to be stable for at least 2 months.
We report a left parietal damaged, acalculic, non aphasic patient who showed a specific deficit in reading Arabic and spelled-out numerals. Word reading was flawless, while he showed a severe impairment in reading meaningless strings of phonemes (phonological alexia). He also showed a dissociation between the preserved ability to retrieve knowledge about general facts and the impairment in retrieving cardinal, personal and non-personal numerical facts. These findings point to a separate organization in the brain of the numerical domain.
Olivine LiFePO4 has been produced using Fe2O3 raw material by mechanical alloying (MA) and subsequent firing. X-ray diffraction (XRD) and Mössbauer spectroscopy analysis revealed that LiFePO4 prepared by MA had a well-ordered olivine-type LiFePO4 structure with an ionic state of Fe2+ by the reduction of Fe3+ precursor. It showed a maximum discharge capacity of 160mAhg−1 at C/20 (8.5mAg−1) when cycled from 2.5 to 4.3V. Compared to the LiFePO4 prepared by conventional solid-state method, MA synthesized LiFePO4 a displayed higher charge/discharge capacity and more stable cycle life because of the improvement of the electronic conductivity. It was originated from uniformly distributed fine particles and an increased specific surface area by MA process.
In this review, the technologies and working principles of different materials used in supercapacitors are explained. The most important supercapacitor active materials are discussed from both research and application perspectives, together with brief explanations of their properties, such as specific surface area and capacitance values. A review of different supercapacitor electrolytes is given and their positive and negative features are discussed. Finally, cell configurations are considered, pointing out the advantages and drawbacks of each configuration.
The purpose of the study is to report the results of reverse shoulder arthroplasty (RSA) after three types of initial treatment performed for complex proximal humeral fracture (PHF): conservative, reduction and internal fixation (RIF), or hemiarthroplasty.
Direct methanol fuel cell (DMFC), with benefits such as high energy efficiency, quick start capability and instantaneous refueling, is a promising power source to meet the ever-increasing power demand for portable electronic products. In this paper, a novel CO2-driven fuel-feed device was produced and equipped in a passive 8-cell DMFC twin-stack for long-term operation. It was shown that this fuel-feed device was capable of supplying methanol solution continuously in response to the change in discharging current of the stack. Stainless steel sheet was photochemically etched as current collectors based on MEMS techniques. Series interconnections between two neighbor cells were realized in banded configuration which avoided the external connection. TiN-plated mesh was placed between current collector and membrane electrode assembly (MEA), which was used to lessen the internal resistance of the stack. A peak power density of 16.9mWcm−2 was achieved with 4M methanol at ambient temperature and passive operation. The stack equipped with the fuel feed device successfully powered a sensor node for 39h with the consumption of 80ml of 4M methanol.
Electric fields (EFs) of around 100 mV/mm are present in normal healing wounds and induce the directional migration of epithelial cells. Reepithelialization during wound healing thus may be controlled in part by this electrical signal. In this study, the early transcriptional response of human epidermal keratinocytes to EFs is examined using microarrays. Increased expression of various chemokines, interleukins, and other inflammatory response genes indicates that EFs stimulate keratinocyte activation and immune stimulatory activity. Gene expression activity further suggests that interleukin 1 is either released or activated in EFs. Expression of the chemokine CCL20 steadily increases at 100 mV/mm over time until around 8 h after exposure. This chemokine is also expressed at field strengths of 300 mV/mm—above the level of endogenous wound fields. The early effects of EFs on epithelial gene expression activity identified in these studies suggest the importance of naturally occurring EFs both in repair mechanisms and for the possibility of controlling these responses therapeutically.
A new perspective in the use of electrochemical methods to deposit cobalt hydroxide thin films is presented. Ordered arrays of α-Co(OH)2 (hydrotalcite-like (Co-HT)) and β-Co(OH)2 nanoparticles were synthesized on transparent conductive oxide (TCO) substrates by localized cathodic electrogeneration of hydroxyl via the reduction of NO2 − (or NO3 −) ion precursors in solution containing Co2+ in very low concentration. The thin films, analyzed by X-ray diffraction and scanning electron microscopy were found to be composed of vertically oriented platelets with the crystallographic c-axis parallel to the substrate surface. Turbostratic disorder was not observed in the films. UV/Vis spectra and thermal gravimetric analyses (TGA) indicated distinct variation between the Co-HT structures. Films deposited at 60°C using a nitrite precursor generated uniform, vibrant-green mixed-valence Co-HT (Co2+/Co3+). Nitrate precursors yielded a “hydroxyl-deficient” Co-HT (Co2+ only). Films deposited at 95°C in nitrate solution yielded β-Co(OH)2. The films obtained in presence of nitrite were thicker than those obtained in nitrate. They were formed of β-Co(OH)2 and contained traces of Co-HT.
Malignant tumors and their various treatments such as chemotherapy, radiotherapy and hormonal therapy can deleteriously affect a large number of cancer patients and survivors on multiple dimensions of psychosocial and neurocognitive functioning. Oncology researchers and clinicians are increasingly cognizant of the negative effects of cancer and its treatments on the brain and its mental processes and cognitive outcomes. Nevertheless, effective interventions to treat cancer and treatment-related neurocognitive dysfunction (CRND), also known as chemobrain, are still lacking. The paucity of data on effective treatments for CRND is due, at least partly, to difficulties understanding its etiology, and a lack of reliable methods for assessing its presence and severity. This paper provides an overview of the incidence, etiology, and magnitude of CRND, and discusses the plausible contributions of psychological, motor function, and linguistic and behavioral complications to CRND. Strategies for reliable neuropsychological screening and assessment, and development and testing of effective ways to mitigate CRND are also discussed.
The present study examined the factor structure of the Personality Assessment Inventory Antisocial Features scale (PAI-ANT) in a non-forensic sample of 1257 undergraduate students. One to four-factor models were tested using exploratory factor analysis (EFA), with a four-factor solution exhibiting the best fitting model (Bentler 1995). Next examined was the convergent and discriminant validity of the PAI-ANT. Results indicated that the PAI-ANT four-factor model was significantly related to measures of general personality, pride, impulsivity, and attachment. Comparisons between the original three-factor model (as proposed by Morey 2007) and our derived four-factor model showed that both models generally had the expected pattern of relations for their respective factors although mixed findings were found for the sensation seeking and risk-taking scales. Findings for these scales indicated that individuals could crave excitement and also have some positive characteristics. The current findings suggest that the four-factor model of the PAI is the best way to interpret the PAI psychopathy scale, but that some caution is needed in interpreting the sensation seeking and risk-taking scales.
We argue that head movement, as an operation that builds head-adjunction structures in the syntax, has been used to model two empirically distinct classes of phenomena. One class has to do with displacement of heads (fully formed morphological words) to higher syntactic positions, and includes phenomena like verb second and verb initiality. The other class has to do with the construction of complex morphological words and is involved in various types of word formation. Based on the very different clusters of properties associated with these two classes of phenomena, we argue that they each should be accounted for by distinct grammatical operations, applying in distinct modules of the grammar, rather than by the one traditional syntactic head movement operation. We propose that the operation responsible for upward displacement of heads is genuine syntactic movement (Internal Merge) and has the properties of syntactic phrasal movement, including the ability to affect word order, the potential to give rise to interpretive effects, and the locality associated with Internal Merge. On the other hand, word formation is the result of postsyntactic amalgamation, realized as either Lowering (Embick and Noyer 2001) or its upward counterpart, Raising. This operation, we argue, has properties that are not associated with narrow syntax: it is morphologically driven, it results in word formation, it does not exhibit interpretive effects, and it has stricter locality conditions (the Head Movement Constraint). The result is a view of head movement that not only accounts for the empirical differences between the two classes of head movement phenomena, but also lays to rest numerous perennial theoretical problems that have heretofore been associated with the syntactic head adjunction view of head movement. In addition, the framework developed here yields interesting new predictions with respect to the expected typology of head movement patterns.
A novel two-step solvothermal approach was firstly applied to acquire ultrathin lithium iron (II) phosphate (LiFePO4) nanosheet (with thickness about 28 nm) with exposed (010) surface facets. The iron hydroxyl phosphate Fe3(PO4)2(OH)2 nanosheet fabricated in the first solvothermal step was proved to be effective template for ultrathin LiFePO4 formation after solvothermal lithiation in the second solvothermal step. Importantly, the two-step solvothermal lithiation could produce ultrathin nanosheets while one-step solvothermal based on Fe(II) fabrication could only produce nanoplate-like particles. The as-synthesized nanosheets has shortened Li-ion diffusion path and high robustness in the structure during high C-rate electrochemical tests. Based on comparison with bulk LiFePO4 and nano-plate LiFePO4, the LiFePO4 nanosheet exhibits quite high specific discharge capacity of 169, 165, 159, 142, and 121 mAh g−1, at C-rate of 0.1, 0.2, 0.5, 1, and 5C, respectively, and excellent cycling performance with capacity kept at 121 mAh g−1 with no obvious fading under 500 times cycles. The newly developed method can provide useful references to other olivine type LiMPO4 cathodes and even have potential to find more applications in the synthesis of functional materials.
Developments in electronic tagging technologies have provided unprecedented insight into the movements and behavior of marine predators. Concurrent information on the prey of these tracked animals, however, is mostly lacking. We developed and tested a prototype autonomous echosounder (aka the sonar tag) for deployment on large marine animals intended to provide quantification of their prey fields.
In e-learning environments, instructional design has evolved from “one instructional design for many learners” to “one design for one learner” or “many designs for one learner”. By using the capabilities of semantic web, World Wide Web led the interchange of information about data (e.i., metadata) as well as documents. Such capabilities also indicated a new kind of challenge for instructional designers to design a common framework that allows content to be shared and reused within and across applications.
Gas evolution has been examined for different types of battery-related electrode materials via in situ differential electrochemical mass spectrometry (DEMS). Besides standard graphite also a novel silicon-based negative electrode was examined and it was shown that the evolution of hydrogen and ethylene is considerably reduced on this material compared to graphite. Oxygen evolution was proven to happen on the oxidative reaction of a Li2O2 electrode, besides a certain oxidation of the electrolyte. The 4.5V plateau upon the oxidation of Li[Ni0.2Li0.2Mn0.6]O2 was likewise proven to be linked to oxygen evolution. Also in this case electrolyte oxidation was shown to be a side reaction. Layered positive electrode materials Li(Ni,Co,Al)O2 and Li(Ni,Mn,Co)O2 were also examined. The influence of different parameters on the CO2 evolution in lithium-ion batteries was shown up. The amount of CO2 formation is increased by high temperatures and cell voltages, while the addition of vinylene carbonate (VC) decreases it. Li(Ni,Mn,Co)O2 shows much less CO2 evolution than Li(Ni,Co,Al)O2.
In the present study, the cyto-genotoxic effects of 12 CSCs prepared from a diverse set of cigarettes on human B lymphoblastoid cells were compared using five in vitro assays. The cells were exposed to CSCs at doses of 2.5, 5.0, 7.5, 10.0, and 12.5×10−3 cigarette/ml for 24h in neutral red uptake and CCK-8 assays, at doses of 1.0, 2.0, 3.0, 4.0, and 5.0×10−3 cigarette/ml for 3h in cell apoptosis assay, at doses of 6.0, 8.0, 10.0, 12.0, and 14.0×10−3 cigarette/ml for 4h in comet assay, and at doses of 1.0, 2.0, 4.0, 6.0, and 8.0×10−3 cigarette/ml for 4h in micronucleus assay. The potency of 12 CSCs to induce corresponding toxic effects in each assay was calculated, and the correlations between the results in five assays were analyzed. Our investigation showed that the results of 12 CSCs in CCK-8 and cell apoptosis assays were positive, the results of 11 CSCs in neutral red uptake and comet assays were positive, and 9 CSCs could induce significantly the micronuclei in micronucleus assay. It was found that the potency to induce the cytotoxic effects among 12 CSCs ranged 9.694 folds in neutral red uptake assay and 6.43 folds in CCK-8 assay, the potency to induce cell apoptosis among 12 CSCs ranged 8.191 folds, the potency to induce DNA damage among 12 CSCs ranged 29.199 folds, the potency to induce micronuclei among 12 CSCs ranged 5.879 folds. Moreover, the good correlations were found between any two assays. It was suggested that the cyto-genotoxicity of CSCs from different brands of cigarettes varied greatly, comet assay might be a sensitive assay in assessing the genotoxicity induced by CSCs.