Question: What 45th head of state and head of government of the United States, is associated with a parish church of the Episcopal Diocese of New York?

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Episcopal Diocese of Nebraska: The Episcopal Diocese of Nebraska is the diocese of the Episcopal Church in the United States of America with jurisdiction over the state of Nebraska, except for two congregations which are in the "Santee Mission" of the Episcopal Diocese of South Dakota.  It is in Province VI.  Its cathedral, Trinity Episcopal Cathedral, is in Omaha, as are the diocese's offices.  It incorporates the former Episcopal Diocese of The Platte.

Episcopal Diocese of West Virginia: The Episcopal Diocese of West Virginia is a diocese of the Episcopal Church in the United States of America encompassing all 55 counties within the state of West Virginia.  The Episcopal Diocese of West Virginia was formed from the Episcopal Diocese of Virginia, one of the nine original Dioceses of the Episcopal Church in the United States of America, by an act of the General Convention in 1877.

Episcopal Diocese of South Florida: The Episcopal Diocese of South Florida was a diocese of the Episcopal Church in the United States of America, which was created in 1922 out of what had been the Missionary Jurisdiction of Southern Florida, sometimes called the Missionary District of Southern Florida.  which had been split off in 1892 from the Episcopal Diocese of Florida.  Its northern line was the southern boundaries of the counties of Levy.  Alachua, Putnam and St. Johns.  and covered the southern two-thirds of the Florida peninsula.  Its see city was Orlando, Florida.  In 1969, it was divided into three new dioceses as follows: the Episcopal Diocese of Central Florida with its see at Orlando, the Episcopal Diocese of Southeast Florida with its see at Miami and the Episcopal Diocese of Southwest Florida, with its see at St. Petersburg.

President of the United States: The President of the United States (informally referred to as "POTUS") is the head of state and head of government of the United States.  The president directs the executive branch of the federal government and is the commander-in-chief of the United States Armed Forces.

Episcopal Diocese of Tennessee: The Episcopal Diocese of Tennessee is the diocese of the Episcopal Church in the United States of America that covers roughly Middle Tennessee.  A single diocese spanned the entire state until 1982, when the Episcopal Diocese of West Tennessee was created; the Diocese of Tennessee was again split in 1985 when the Episcopal Diocese of East Tennessee was formed.  It is headquartered in Nashville, Tennessee.

Jennifer Baskerville-Burrows: Jennifer Lynn Baskerville-Burrows is an American Anglican bishop in the Episcopal Church.  In October 2016, she was elected bishop of the Episcopal Diocese of Indianapolis, and she was consecrated on April 29, 2017.  She is the first African-American woman to be elected a diocesan bishop.  Prior to her consecration, she served as Director of Networking in the Diocese of Chicago.  Previously, she was a priest in the Episcopal Diocese of Central New York, the Episcopal Diocese of Newark, and the Episcopal Diocese of California.  In addition to her parish ministry, she has been Director of Alumni and Church Relations at Church Divinity School of the Pacific and a chaplain to Syracuse University.

Episcopal Diocese of Rochester: The Episcopal Diocese of Rochester is the diocese of the Episcopal Church in the United States of America with jurisdiction over eight counties in west central New York.  It is bounded on the north by Lake Ontario, on the east by the Episcopal Diocese of Central New York, on the south by the Episcopal Diocese of Central Pennsylvania and on the west by the Episcopal Diocese of Western New York.  It is in Province 2 and has no cathedral.  Its diocesan offices are in Rochester.

Episcopal Church in Minnesota: The Episcopal Church in Minnesota, also known as the Episcopal Diocese of Minnesota, is a diocese of the Episcopal Church in the United States of America which has jurisdiction over all of Minnesota, except Clay County, which is in the Episcopal Diocese of North Dakota.  It is in Province VI and its offices are in Minneapolis.  It has two cathedrals: the Cathedral of Our Merciful Saviour in Faribault and St. Mark's Episcopal Cathedral in Minneapolis.  As of December 2013, there were 20,964 members.  It has 110 faith communities (this includes 105 churches and the organizations Episcopal Homes of Minnesota, the Episcopal House of Prayer, The Sheltering Arms Foundation, Breck School, and Shattuck-St.  Mary’s School).  It affiliated with the Minnesota Council of Churches, The Joint Religious Legislative Coalition, and The Resource Center for Churches.  Henry Benjamin Whipple was the first bishop of the Episcopal Church in Minnesota.  Brian Prior is the current bishop.  The Diocese of Duluth was established as a Missionary Diocese from the Diocese of Minnesota in 1895 and was merged back into the Diocese of Minnesota on May 24, 1955.

Episcopal Diocese of the Virgin Islands: The Episcopal Diocese of the Virgin Islands is a diocese of the Episcopal Church in the United States of America (ECUSA) which includes both the United States Virgin Islands and the British Virgin Islands.  The diocese is a part of Province II of the Episcopal Church.  The current Diocesan Bishop of the Virgin Islands is the Edward Ambrose Gumbs.  The cathedral church of the diocese is the Cathedral Church of All Saints, Charlotte Amalie.  The diocese currently comprises 14 churches.  There is a functioning parish school on St. Thomas All Saints Cathedral School there was an academic campus on St. Croix, St. Dunstan's Episcopal High School.  St. Dunstan's closed in the 1990s.  There is also the St. Georges School located on the parish property of St. Georges Episcopal Church in Road Town, Tortola in the British Virgin Islands, which also opened the St. Georges School (Secondary Division) in Palestina Estate near to the St. Paul's Episcopal Church in Sea Cow's Bay, Tortola in the British Virgin Islands.  There is also the St. Mary's School located on the parish property of the St. Mary's Episcopal Church in Valley, Virgin Gorda in the British Virgin Islands.

St. James Episcopal Church (Hyde Park, New York): St. James Episcopal Church is a parish church of the Episcopal Diocese of New York, located at 4526 Albany Post Road (U.S. Route 9) in Hyde Park, New York, across the street from the Vanderbilt Mansion National Historic Site.  The church is associated with Franklin Delano Roosevelt, the 32nd President of the United States, whose family estate is located 2.7 miles south of the church.  Roosevelt served in the vestry and as senior warden of the church, even during his presidency, and he, his wife Eleanor, and their family regularly attended service there whenever they were in Hyde Park.

Supporting paragraphs: St. James Episcopal Church (Hyde Park, New York) President of the United States
Answer: Franklin Delano Roosevelt