Patent GB-923845-A (GB)
Title: A stock solution for the stabilization of hydrogen peroxide
IPC: C01B15/037
Filed: 1961-03-28
Abstract: A stock solution for stabilizing hydrogen peroxide consists of a soluble stannate and a complexing agent for tin which is stable to hydrogen peroxide in a sufficient amount to prevent the precipitation of stannate, and acidified to a pH below 5, e.g. between 1 and 4. The mole ratio of complexing agent to tin may be between 0,5:1 and 20:1.  The stannate may be derived from an alkali metal, alkaline earth metal (including magnesium) or ammonium ion, e.g. sodium stannate of concentration between 0,05% and 10% by weight calculated as Na2Sn(OH)6. The stannate may be first polymerized, but only to such an extent as it is still water-soluble, the polymerization being stopped by addition of complexing agent.  The complexing agent may be inorganic, soluble phosphate compounds such as ortho and/or metaphosphates, polyphosphates, pyrophosphates, polymetaphosphates, hexametaphosphates, tripolyphosphates, tetraphosphates as their salts or as the free acid, e.g. sodium pyrophosphate.  The complexing agent may also include or be an amino carboxyl compound, preferably containing at least one N,N (dicarboxylalkyl) amino group N=(R,COOX)2 where R is an alkylene radical of one or two carbon atoms, X is hydrogen, alkali metal, alkaline earth metal, or ammonium ion, the two X's being the same or different.  A polycarboxy amine may be used containing a plurality of N,N(dicarboxyalkyl) amine groups in the molecule, preferably with two adjacent carbon atoms in the molecule each directly attached to at least one of the N,N(dicarboxyalkyl) amine groups.  Such a compound may be a water soluble N,N-(dicarboxyalkyl) amino substituted carbocyclic compound having a saturated ring, e.g. 1,2-diamino cyclohexane - N,N,N1,N1-tetraacetic acid.  The pH of the solution may be adjusted with a mineral acid, e.g. nitric, sulphuric or phosphoric, or with a strong organic acid, e.g. citric, lactic, gluconic, malic.  The amount of solution used for stabilization is such as to introduce amounts of stannate equivalent to 0,5 to 200 milligrams No2Sn(OH)6 per litre of peroxide solution.  Specifications 404,361 and 893,069 are referred to.ALSO:A solution used for stabilizing hydrogen peroxide comprises an aqueous solution of a soluble stannate and a complexing agent for tin in a sufficient amount to prevent the precipitation of stannate, and acidified to a pH below 5.  The complexing agent is an amino carboxyl compound, preferably containing at least one N,N-(dicarboxyalkyl) amino group, N=(R.COO.X)2 where R is an alkylene radical with one or two carbon atoms, X is hydrogen, an alkali, alkaline earth metal, magnesium, or ammonium ion.  A polycarboxy amine may be used with at least each of two adjacent carbon atoms attached to at least one of the N,N-(dicarboxyalkyl) amino groups.  The amino groups may be attached to adjacent atoms of a saturated carbocyclic ring, e.g. 1,2 - diaminocyclohexane-N,N,N1,N1-tetraacetic acid.  The stannate may be derived from an alkali or alkaline earth metal, magnesium or ammonium ion.  The mole ratio of complexing agent to tin is between 0.5:1 and 20:1.  Specifications 409,361 and 893,069 are referred to.