Patent GB-1342659-A (GB)
Title: Coating composition
IPC: C09D133/12
Filed: 1971-04-19
Abstract: 1342659 Acrylic polymer coating compositions UNION CARBIDE CORP 19 April 1971 [10 April 1970] 26591/71 Heading C3P A coating composition producible into films of improved physical properties when applied to a substrate and dried comprises a dispersion of a homopolymer of methyl methacrylate or a copolymer of methyl methacrylate with another monomer having at least one ethylenically unsaturated valence bond in an organic liquid medium, a plasticizer and a high boiling solvent combined in the coating composition with the plasticizer, said organic liquid being one in which said polymer or copolymer is substantially insoluble, said plasticizer comprising an ester plasticizer characterized by having a volatility such that the loss of plasticizer from a porous asbestos bed will be no more than 30 weight per cent after a drying period of about 6 hours at a temperature of up to 329‹ F. and being further characterized by having a solvency between 0À530 and 0À580, said high boiling solvent being characterized by having a solvency between 0À4 and 0À7 and the amount of high boiling solvent being between 10 and 200 parts by weight per 100 parts by weight of polymer. The above solvency values are the ratios of the polar to nonpolar solubility parameters of the substance concerned, the total solubility parameter A of a substance being the square root of its cohesive energy density, and the nonpolar parameter (a) and polar parameter (b) being obtained from the equation A<SP>2</SP> = a<SP>2</SP> + b<SP>2</SP>. The organic liquid medium may be an acyclic, alicyclic or naphthenic hydrocarbon. Specified plasticizers are Esterdiol-204 bis-(isodecyl phthalate), ethylene glycol bis-(isodecyl phthalate), propylene glycol bis-(isodecyl phthalate), propionyloxyethyl tridecyl phthalate, 2-ethylhexane-1,3-diol/6-hydroxyhexanoic acid/propionic acid (1/3/2 moles), Esterdiol-204/6-hydroxyhexanoic acid/isopentanoic acid (1/3/2 moles), Esterdiol-204/phthalic acid/nonanoic acid (3/1À5/ 2À7 moles), acetoxyethyl tridecyl phthalate and Esterdiol-204 bis-(tridecyl phthalate). (Esterdiol is 2,2 - dimethyl - 3 - hydroxypropyl 2,2 - dimethyl-3-hydroxypropionate.) Specified high boiling solvents are ethylene glycol monoethyl ether acetate, ethylene glycol monobutyl ether acetate, 2-ethylhexyl acetate, diethylene glycol monobutyl ether acetate, 2-ethylhexane-1,3- diol diacetate, n-butyl 6-acetoxyhexanoate, 2- ethylhexyl acetate/diethylene glycol diacetate (55 : 45) and 2-ethylhexyl acetate/diethylene glycol monobutyl ether acetate/diethylene glycol diacetate (30 : 50 : 20). The compositions, which may additionally contain metallic flakes and pigments such as titanium dioxide, may be prepared by grinding the plasticizer with pigment and pigment dispersant, adding a mixture of organic liquid and high boiling solvent and finally adding the polymer dispersion and a levelling agent. The compositions may be thinned for spray application. Numerous comonomers are specified for copolymerization with methyl methacrylate to form the polymer component. In the examples the polymer is a homopolymer of methyl methacrylate, and the compositions are sprayed on to primed metal panels and baked.