Patent GB-796383-A (GB)
Title: Abrasive cleansers
IPC: C11D3/14
Filed: 1956-06-01
Abstract: A substantially dry particulate germicidal abrasive cleansing composition comprises (a) a major proportion, preferably 60-95 per cent by weight, of a water-insoluble inorganic siliceous abrasive material such as silica, feldspar, pumice, volcanic ash, diatomaceous earth, bentonite or talc; (b) a heterocyclic N-chloroimide, of which preferred examples of many mentioned are dichloro- and trichloro-cyanuric acid, N-chlorosuccinimide, and 1 : 3-dichloro-5 : 5-dimethyl hydantoin and which may suitably be present in amounts of 0.1-10 per cent; and (c) an organic detergent compound which is stable in the presence of the chloroimide.  This detergent is preferably included in amounts of 0.5-15 per cent and may, in addition to soap, be (i) anion-active, such as an alkali-metal, ammonium, amine, alkylolamine, or alkaline-earth metal salt of an alkylaryl sulphonic acid, a sulphuric acid ester of a polyhydric alcohol incompletely esterified with higher fatty acids, a higher fatty ester of an hydroxysulphonic acid, a fatty acid ethanolamide sulphate, a fatty acid amide of an aminoalkyl sulphonic acid, or a sulphuric acid ester of a long-chain fatty alcohol; or (ii) cation-active, such as a long-chain alkyl quaternary ammonium salt such as cetyl trimethylammonium chloride or cetyl pyridinium chloride or the condensation product of unsymmetrical N(diethyl)-ethylene diamine and oleyl chloride; or (iii) non-ionic such as a polyoxyethylene ether of an alkylphenol, a longchain alcohol, or a propylene oxide polymer.  Sodium dodecylbenzene sulphonate is the preferred detergent.  The compositions may also contain up to 25 per cent of other adjuvant materials, such as the alkali-metal carbonates, bicarbonates, phosphates and polyphosphates, sulphates, chlorides, silicates and borates, together with minor amounts of wood pulp, sawdust, magnesite, whiting, sodium carboxymethylcellulose, melamine, anti-caking agents, optical brighteners, and perfumes.ALSO:A substantially dry particulate germicidal abrasive cleansing composition comprises: (a) a major proportion, preferably 60-95 per cent by weight, of a water-insoluble inorganic siliceous abrasive material such as silica, feldspar, pumice, volcanic ash, diatomaceous earth, bentonite or talc; (b) a heterocyclic N-chloroimide, of which preferred examples of many mentioned are dichloro- and trichloro-cyanuric acid, N-chlorosuccinimide, and 1 : 3-dichloro-5 : 5-dimethyl hydantoin and which may suitably be present in amounts of 0.1-10 per cent; and (c) an organic detergent compound which is stable in the presence of the chloroimide.  This detergent is preferably included in amounts of 0.5-15 per cent and may, in addition to soap, be (i) anion-active, such as an alkali-metal, ammonium, amine, alkylolamine, or alkaline-earth metal salt of an alkylaryls ulphonic acid, a sulphuric acid ester of a polyhydric alcohol incompletely esterified with higher fatty acids, a higher fatty ester of an hydroxysulphonic acid, a fatty acid ethanolamide sulphate, a fatty acid amide of an amino-alkyl sulphonic acid, or a sulphuric acid ester of a long-chain fatty alcohol, or (ii) cationactive, such as a long-chain alkyl quaternary ammonium salt such as cetyl trimethylammonium chloride or cetyl pyridinium chloride, or the condensation product of unsymmetrical N-(diethyl)-ethylene diamine and oleyl chloride, or (iii) non-ionic such as a polyoxyethylene ether of an alkylphenol, a long-chain alcohol, or a propylene oxide polymer.  Sodium dodecylbenzene sulphonate is the preferred detergent.  The compositions may also contain up to 25 per cent of other adjuvant materials such as the alkali-metal carbonates, bicarbonates, phosphates and polyphosphates, sulphates, chlorides, silicates and borates, together with minor amounts of wood pump, sawdust, magnesite, whiting, sodium carboxymethylcellulose, melamine, anti-caking agents, optical brighteners and perfumes.