Patent GB-1531067-A (GB)
Title: Polyisocyanurate foams
IPC: C08G18/50
Filed: 1976-12-09
Abstract: 1531067 Polyisocyanurate foams TEXACO DEVELOPMENT CORP 9 Dec 1976 [8 March 1976] 51339/76 Heading C3R A urethane-modified polyisocyanurate rigid foam comprises the reaction product obtained by bringing together in the presence of a blowing agent, an aromatic polyisocyanate, an isocyanurate group-formation catalyst and a polyol comprising an alkylene oxide adduct of aniline prepared by reacting 2À5 to 15 moles of an alkylene oxide, generally having 2-4 carbon atoms, per mole of aniline. The polyol preferably has an OH number of from 150 to 1000 and may be an ethylene oxide or propylene oxide adduct of aniline or a mixed ethylene oxide/propylene oxide adduct of aniline. When a mixture of alkylene oxides is used in preparing the polyol the alkylene oxides may be added to aniline either sequentially or as a mixture. The polyol is preferably employed in an amount from 0À1 to 0À8 equivalent per equivalent of polyisocyanate. The aromatic polyisocyanate is preferably a methylene-bridged polyphenyl polyisocyanate mixture containing from 20- 100% wt. of methylene diphenyldiisocyanate isomers, but may also be m- or p-phenylene diisocyanate, 2,4- or 2,6-tolylene diisocyanate, dianisidine diisocyanate, bitolylene diisocyanate, naphthalene - 1,4 - diisocyanate, diphenylene - 4,4<SP>1</SP> - diisocyanate, xylylene diisocyanates, bis(4 - isocyanatophenyl)methane, bis - (3 - methyl - 4 - isocyanatophenyl)methane or 4,4<SP>1</SP> - diphenylpropane diisocyanate. The blowing agent may be an aliphatic halocarbon, water, low boiling hydrocarbons or a thermally unstable compound, e.g. N,N<SP>1</SP> - dimethyl - N,N<SP>1</SP> - dinitrosoterephthalamide. The catalyst may be a strong base, an alkali metal salt of a carboxylic acid or an aliphatic tertiary amine, e.g. a quaternary ammonium hydroxide, alkali metal hydroxide or alkoxide, sodium or potassium acetate, potassium octoate, sodium benzoate, trimethylamine, tributylamine, N,N<SP>1</SP> - di - (C 1 -C 2 )- alkylpiperazine, triethylenediamine, 2,4,6-tris- (dimethylaminomethyl)phenol or N,N<SP>1</SP>,N<SP>11</SP>- tris - (dimethyl - 3 - aminopropyl) - s - hexahydrotriazine. Optional additives include a flame retardant, e.g. tris - (chloroethyl) phosphate, tris(2,3 - dibromopropyl) phosphate, triphenyl phosphite, diammonium phosphate, antimony oxide, diethyl - N,N - bis- (2 - hydroxyethyl)aminomethyl phosphonate, a chlorendic acid derivative or a phosphoruscontaining polyol; fillers, e.g. hydrated alumina, polyethylene, aluminium powder, clay or talc; emulsifiers or stabilizers, e.g. a polydimethylsiloxane, a polyoxyalkylene block copolymer of a silane, or ethylene oxide modified sorbitan, monopalmitate or polypropylene ether glycol. The foam may be prepared by the one-shot or quasi-prepolymer method. In typical examples rigid foams are prepared by the one-shot process either by spraying or by handmix box pouring from the following formulation-aniline/ethylene oxide adduct, a methylene-bridged polyphenyl polyisocyanate mixture, a silicone-polyether, potassium octoate, tris[N,N-dimethyl-3-aminopropyl]symhexahydrotriazine, tris(chloroethyl) phosphate and trichloromonofluoromethane.