Patent IL-101105-A (IL)
Title: Fluoroalkenyl compounds their preparation and nematodicidal insecticidal and acaricidal compositions containing them
IPC: C07D207/16
Filed: 1992-02-28
Abstract: Compounds of the formula wherein n=1, 3, 5, 7, 9 or 11; Q is CH2NHR6, CH2NO2, CH2N=CHR2, CH2N=C=O, CH2N+R3R4R5W, OSO2CH3, OSO2C6H4CH4 CH3 or (C=O)-R11 each of X, Y, and Z is independently H or F, provided that at least one of X and Y is F and further provided that when Q is (C=O)-R11 each of X, Y, and Z is F; W- is an agronomically acceptable anion; R2 is a substituted aromatic group; R3, R4, and R5 are independently hydrogen; a lower alkyl group, optionally 187 י" ג בתמוז התש" ס - July 16, 2000 substituted with at least one group selected from hydroxy, alkoxy, halo, nitro, amino, thiol, alkylthio, carboxyl, alkoxy-carbonyl, and phenyl; one of R3, R4, and R5 is hydroxy and the other two are hydrogen; or R3, R4, and R5 taken together with the nitrogen of Q form a cyclic quaternary ammonium group; R6 is hydrogen; an aliphatic group, optionally substituted with at least one group selected from hydroxy, alkoxy, halo, nitro, amino, thiol, alkylthio, carboxyl, alkoxycarbonyl, and phenyl; an amino acid amide of Q; (C=O)-R7; C1-C12 alkylamines, optionally substituted with at least one group selected from hydroxy, alkoxy, halo, nitro, amino, thiol, alkylthio, carboxyl, alkoxycarbonyl, and phenyl; C2-C12 aliphatic carboxylic acids, their esters, thiol esters, and amides, all optionally substituted with at least one group selected from hydroxy, alkoxy, halo, nitro, amino, thiol, alkylthio, carboxyl, alkoxycarbonyl, and phenyl; dihydro- 3-oxo-pyrazolidinyl; or phenyl or thiophene, optionally substituted with at least one group selected from hydroxy, alkoxy, halo, nitro, amino, thiol, alkylthio, carboxyl, alkoxycarbonyl, and phenyl; R6 taken with the nitrogen of Q is guanidine; hydrazine; alkyl or aryl hydrazine, optionally substituted with at least one group selected from hydroxy, alkoxy, halo, nitro, amino, thiol, alkylthio, carboxyl, alkoxycarbonyl, and phenyl; or an alkyl or aryl sulfonamide, optionally substituted with at least one group selected from hydroxy, alkoxy, halo, nitro, amino, thiol, alkylthio, carboxyl, alkoxycarbonyl, and phenyl; R7 is (C=O)-R14; C1-C12 aliphatic group optionally substituted with at least one group selected from hydroxy, alkoxy, halo, nitro, amino, thiol, esters, or amides thereof, all optionally substituted with at least one group selected from hydroxy, alkoxy, halo, nitro, amino, thiol, alkylthio, carboxyl, alkoxycarbonyl, and phenyl; or a N, O, or S group such that when taken with the carboxamide is a urea, semicarbazide, carbamate, or thiocarbamate group, alloptionally substituted with an alkyl or aryl group, optionally substituted with at least one group selected from hydroxy, alkoxy, halo, nitro, amino, thiol, alkylthio, carboxyl, alkoxy-carbonyl, and phenyl; R11 is -OR12, -SR12, halogen, -NHOH, or -NR12R13; each of R12 and R13 is independently hydrogen; an aliphatic or an aromatic group, optionally substituted with at least one group selected from hydroxy, alkoxy, halo, nitro, amino, thiol, alkylthio, carboxyl, alkoxycarbonyl, and phenyl; a C1-C12 aliphatic amine, optionally substituted with at least one group selected from hydroxy, alkoxy, halo, nitro, amino, thiol, alkylthio, carboxyl, alkoxycarbonyl, and phenyl; or a C2-C12 aliphatic carboxylic acid radical, optionally substituted with at least one group selected from hydroxy, alkoxy, halo, nitro, amino, thiol, alkylthio, carboxyl, alkoxycarbonyl, and phenyl; or R12 and R13 taken together with the N or R11 are a protein amino acid or a cyclic group selected from morpholine, piperidine, piperazine, or pyrrolidine, optionally substituted with at least one group selected from hydroxy, alkoxy, halo, nitro, amino, thiol, alkylthio, carboxyl, alkoxy-carbonyl, and phenyl; R14 is OH, alkoxy, NH2, or NHNH2; or any agronomically acceptable salt thereof; provided that when n is 1 and each of X, Y, and Z is F, Q is not CH2NH2 or a mineral acid salt of CH2NH2. 188 י" ג בתמוז התש" ס - July 16, 2000