Patent GB-369716-A (GB)
Title: Improvements in the manufacture and production of conversion products of rubber
IPC: C08C19/04
Filed: 1931-02-06
Abstract: Conversion products of rubber are prepared by acting on rubber and the like in solid form or in solution with an aliphatic per-acid, or with a mixture behaving as an aliphatic per-acid, at a temperature not exceeding 45 DEG  C.  The products differ from rubber in being more soluble in organic solvents, the solutions having a lower viscosity than rubber solutions.  These solutions are suitable for use as coating compositions and for the preparation of films or threads.  In combination with resins, cellulose carboxylates, cellulose ethers and nitrocellulose, coatings fast to water are obtained, which may also be used as adhesives in the preparation of emery paper or tape.  Softening agents such as aryl phosphates, inorganic or organic fillers may be added.  Suitable aliphatic per-acids are those which contain up to 4 carbon atoms such as per-formic, per-acetic and per-propionic acid, and halogen substituted per-acids.  Instead of the per-acid, mixtures which behave as per-acid such as a mixture of acetic anhydride and hydrogen peroxide may be used, or a mixture of acetic acid and inorganic per-compounds, such as per-sulphuric acid, per-phosphoric acid and the like.  An agent assisting esterification may be employed such as sulphuric acid, phosphoric acid, or sodium fluoride.  Numerous examples for the preparation of the products are given of which the following is typical.  100 parts of rubber in 1500 parts chloroform are stirred at 5 DEG  C. with 900 parts of 15 per cent solution of per propionic acid in propionic acid until a viscous solution is formed.  The acid is washed out with water and the product treated with steam.  A snow white loose powder is obtained containing about 20 per cent of oxygen, and becoming plastic in hot water.  The examples include treatment of guttapercha, rubber obtained by spraying latex in hot air, and the rubber-like polymerization product of butadiene.ALSO:Conversion products of rubber are prepared by acting on rubber and the like in solid form or in solution with an aliphatic per-acid, or with a mixture behaving as an aliphatic peracid, at a temperature not exceeding 45 DEG  C.  The products are stated to contain acylated hydroxyl groups, which may be hydrolysed by alkali, and the hydrolysis product condensed with aldehyde to yield hard insoluble products.  The initial condensation products differ from rubber in being more soluble in organic solvents, the solutions having a lower viscosity than rubber solutions. Suitable aliphatic per-acids are those which contain up to 4 carbon atoms such as per-formic, per-acetic, and per-propionic acid, and halogen substituted per-acids.  The amount of per-acid used is from 20-400 per cent, preferably from 100-200 per cent by weight of the rubber, generally 1 mol. proportion for each double linkage in the rubber. The reaction may be carried out at ordinary temperature or at any temperature up to 45 DEG  C., above which degradation occurs. Instead of the per-acid, mixtures which behave as per-acid such as a mixture of acetic anhydride and hydrogen peroxide may be used, or a mixture of acetic acid and inorganic per-compounds, such as per-sulphuric acid, per-phosphoric acid and the like.  It is not essential to employ anhydrous reagents.  An agent assisting esterification may be employed such as sulphuric acid, phosphoric acid, or sodium fluoride.  If solid rubber is treated the reaction is stopped after the rubber is strongly swollen or after it has been dissolved.  Examples for the preparation of the products are given.ALSO:Conversion products of rubber are prepared by acting on rubber and the like in solid form or in solution with an aliphatic per-acid, or with a mixture behaving as an aliphatic per-acid, at a temperature not exceeding 45 DEG  C.  The products are stated to contain acylated hydroxyl groups, which may be hydrolysed by alkali, and the hydrolysis product condensed with aldehyde to yield hard insoluble products.  The initial condensation products differ from rubber in being more soluble in organic solvents, the solutions having a lower viscosity than rubber solutions.  These solutions are suitable for use as coating compositions and for the preparation of films or threads.  In combination with resins, cellulose carboxylates, cellulose ethers and nitrocellulose, coatings fast to water are obtained, which may be used as adhesives in the preparation of emery paper or tape.  Softening agents such as aryl phosphates, inorganic or organic fillers may also be added.  Suitable aliphatic per-acids are those which contain up to four carbon atoms such as per-acetic acid, and halogen substituted per-acids.  The amount of per-acid used is from 20-400 per cent, preferably from 100-200 per cent by weight of the rubber, generally 1 mol. proportion for each double linkage in the rubber.  The reaction may be carried out at ordinary temperature or at any temperature up to 45 DEG  C., above which degradation occurs.  Instead of the per-acid, mixtures which behave as per-acid such as a mixture of acetic anhydride and hydrogen peroxide may be used, or a mixture of acetic acid and inorganic per-compounds, such as per-sulphuric acid, per-phosphoric acid and the like.  It is not essential to employ anhydrous reagents.  An agent assisting esterification may be employed such as sulphuric acid, phosphoric acid, or sodium fluoride.  If solid rubber is treated the reaction is stopped after the rubber is strongly swollen or after it has been dissolved.  Numerous examples for the preparation of the products are given of which the following is typical.  100 parts of rubber in 1500 parts chloroform are stirred at 5 DEG  C. with 900 parts of 15 per cent solution of per-propionic acid in propionic acid until a viscous solution is formed.  The acid is washed out with water and the product treated with steam.  A snow-white loose powder is obtained containing about 20 per cent of oxygen, and becoming plastic in hot water.  The examples include treatment of guttapercha, rubber obtained by spraying latex in hot air, and the rubber-like polymerization product of butadiene.