Patent GB-712535-A (GB)
Title: Improvements in the separation of acetylene from gaseous mixtures
IPC: C07C7/11
Filed: 1951-10-12
Abstract: Acetylene is recovered from gas mixtures obtained in high temperature decomposition or partial combustion of natural gas and similar low molecular paraffin hydrocarbons by treating the gas mixture, preferably under a pressure between 2 and 10 atmospheres, with a washing liquid which contains besides water more than 50 per cent by weight of an organic solvent which has dissolving power for acetylene, which is miscible with water and which has a higher boiling-point than water, heating the washing <PICT:0712535/IV (b)/1> liquid at a pressure between 0.15 and 0.5 atmosphere, and evaporating at that pressure at least part of the water in order to free the washing liquid from acetylene.  The washing liquid containing the acetylene may be heated while flowing down a column thereby expelling acetylene with at least part of the water contained in the washing liquid in gaseous form.  The washing liquid may have a water content between 0.5 and 10 per cent by weight.  The acetylene thus obtained and the residual gas freed from acetylene may be washed with a small amount of water, and the resulting liquids are used to form part of the washing liquid in the acetylene recovery process outlined above. The organic solvent for the acetylene may be an aliphatic ketone boiling above 100 DEG  C., acetals of aldehydes, aliphatic ethers containing a hydrophylic group, e.g. a hydroxy group in addition to the ether oxygen atom such as glycol monoethers, carboxylic acid esters containing further hydrophilic groups either in the acid or in the alkyl radical, e.g. lactic acid esters or glycol monoesters of lower carboxylic acids, lactones or lactams, e.g. a butyrolactone or a butyrolactam substituted in the nitrogen atom by a saturated lower aliphatic hydrocarbon radical, i.e. the methyl or propyl radical.  In the Figure, the gas containing acetylene enters through A into the absorber B where it comes into counter-current with the solvent entering through pipe U, the gas freed from acetylene leaves through pipe C and may be led into a washing tower D where it is stripped of solvent vapour by water running in countercurrent from pipe E to pipe F.  The tail gas is discharged through pipe H.  The solvent containing acetylene passes through pipe J into the stripper K, and the recovered acetylene is discharged through pipe L into washing unit M with water running from pipe N to pipe O.  The acetylene freed from solvent water leaves the apparatus through pipe P.  The water passing from the washing unit D through pipe F is combined with the water coming from the washing unit M through line O, and the total is added to the solvent in line J.  From the stripper K, the solvent runs through pipe Q into column R where it is subjected to vacuum distillation to remove some of the water so that the composition of the solvent becomes the same as when it entered the absorber B, and the solvent is led back through a cooler via pipe U to the absorber B.  All acetylene still contained in the solvent when leaving K is expelled in column R and passes to cooler S where the water vapour is condensed, the water being led back partly through pipe T into column R and partly removed through pipe V.  The acetylene leaving the cooler S is mixed by way of pipe W with the acetylene coming from the absorber through line L.  In the example a gas mixture containing acetylene is treated with aqueous g -butyrolactone.