Patent GB-987334-A (GB)
Title: Improvements in or relating to sub-halide distillation process for aluminium
IPC: C01F7/62
Filed: 1963-03-08
Abstract: <PICT:0987334/C1/1> <PICT:0987334/C1/2> Aluminium is recovered from crude Al, e.g. alloys, by contacting at 1000-1400 DEG  C. with gaseous AlCl3 (or AlBr3) to give at least in part AlCl, which is then decomposed at a lower temperature to Al and AlCl3; at least part (e.g. 1-40%) of the AlCl3 is condensed, non-condensable gases are exhausted, and AlCl3 is evaporated and recirculated. AlCl3 may be condensed by absorbing in a molten salt bath containing at least 50% mole AlCl3 with Na, K, Ni, Pb, Cr, Fe (II) or Co chlorides.  In Fig. 1, Al-containing material is fed from hopper 11 to converter 10, heated by means of electrodes 12 and 13, and is treated with AlCl3 entering from 14.  AlCl is decomposed at 18; pure Al being removed at 21, and AlCl3 gas passing out at 20.  Part may return via pump 23 to the converter, or the whole may be passed into condenser 30 containing molten salt bath 31, agitated by propellers 38 and 39, where AlCl3 is absorbed by passing it under baffle 32. Gases, e.g. H2, CH4, N2, are stripped at 36 of residual AlCl3 and discharged at 37.  The enriched salt may be returned via 60 to the condenser, or passed via heat exchanger 41 to evaporator 45 having graphite or metal electrodes for passage of heating current, from which vaporized AlCl3 returns via heater 26 to the converter, and the lean salt passes through cooler 52 and filter 56 to the condenser.  AlCl3 may be replenished by Cl2 fed in at 67 which reacts with the Al.  In the modification shown in Fig. 2, AlCl is decomposed in 80 by contact with a spray of molten Al produced from pool 82 by propeller 84. AlCl3 is absorbed in 31, from which the rich salt is passed into section 88 (separated from 80 by partition 89) where it floats on the Al, heated by the decomposition reaction in 80, which causes AlCl3 to vaporize, while lean salt is removed through 93.  Specification 987,335 is referred to.ALSO:<PICT:0987334/C6-C7/1> <PICT:0987334/C6-C7/2> Aluminium is recovered from crude Al, e.g. alloys, by contacting at 1000-1400 DEG  C. with gaseous AlCl3 (or AlBr3) to give at least in part AlCl, which is then decomposed at a lower temperature to Al and AlCl3; at least part (e.g. 1-40%) of the AlCl3 is condensed, non-condensable gases are exhausted, and AlCl3 is evaporated and re-circulated.  AlCl3 may be condensed by absorbing in a molten salt bath containing at least 50 mole per cent AlCl3 with Na, K, Ni, Pb, Cr, Fe (II) or Co chlorides. In Fig. 1, Al-containing material is fed from hopper 11 to converter 10, heated by means of electrodes 12 and 13, and is treated with AlCl3 entering from 14. AlCl is decomposed at 18; pure Al being removed at 21, and AlCl3 gas passing out at 20.  Part may return via pump 23 to the converter, or the whole may be passed into condenser 30 containing molten salt bath 31, agitated by propellers 38 and 39, where AlCl3 is absorbed by passing it under baffle 32.  Gases, e.g. H2, CH4, N2, are stripped at 36 of residual AlCl3 and discharged at 37.  The enriched salt may be returned via 60 to the condenser, or passed via heat exchanger 41 to evaporator 45 having graphite or metal electrodes for passage of heating current, from which vaporized AlCl3 returns via heater 26 to the converter, and the lean salt passes through cooler 52 and filter 56 to the condenser.  AlCl3 may be replenished by Cl2 fed in at 67 which reacts with the Al.  In the modification shown in Fig. 2, AlCl is decomposed in 80 by contact with a spray of molten Al produced from pool 82 by propeller 84. AlCl3 is absorbed in 31, from which the rich salt is passed into section 88 (separated from 80 by partition 89) where it floats on the Al, heated by the decomposition reaction in 80, which causes AlCl3 to vaporize, while lean salt is removed through 93.  Specification 987,335 is referred to.