Patent GB-883522-A (GB)
Title: Improvements in or relating to bituminous compositions
IPC: C07D303/16
Filed: 1958-05-19
Abstract: Compositions comprising a bituminous material and a polyepoxy ester having at least 8 carbon atoms in the molecule may be used to coat concret, asphalt, wood, metals (steel or tin) and glass, and in particular roads, by brushing, spraying or rolling with the aid of screeds, trowels, shovels and brooms.  Specified bitumens are straight run and blown asphaltic, the residues from the distillation of catalytically cracked gas oils, Edeleanu extracts of petroleum distillates, coal tar, refined coal tar and coal tar pitch.  Long lists of polyepoxy esters are given of which the polyglycidyl esters of dimerized and trimerized unsaturated acids are preferred.  Epoxy curing agents may also be added. a long list being given, and the following being used in the examples:-diethylene triamine, and (8) a mixture of hexahydrophthalic anhydride and benzyl dimethylamine. Conventional epoxy resins may also be added, and solvents such as xylene, benzene, and petroleum distillates may also be used, but solid particles, e.g. sand, rocks, shells, quartz, and Al2O3 may be added to the composition before and/or after it is applied to surfaces, and the various components of the composition may be mixed in various orders.  Specifications 639,551, 691,543, 718,851, 763,559, 818,810, 819,107 and 860,287 are referred to.ALSO:Epoxy resin compositions comprise a bituminous material and a poly epoxy ester having at least 8 carbon atoms in the molecule. Bitumens specified are straight run and blown asphaltic, the residues from the distillation of catalytically cracked gas oil, Edeleanu extracts of petroleum distillates, coal tar, refined coal tar and coal tar pitch. Long lists of polyepoxy esters are given, of which the following are used in examples: the triglycidyl ester of trimerized linoleic; (3) the diglycidyl esters of 1,20-eicoanedoioc acid, of 1.18-octadecanedioic acid, and of dimerized rosin acids; (5) the diglycidyl ester of dimerized linoleic acid; and (8) dimethyl 8, 9, 12, 13-diepoxyeicosane -1, 20- dioate, diethyl 7, 8, 11, 12-diepoxyoctadecane -1,18- dioate, glycerol tri(8,9-epoxy-dodecanoate, and glycerol tri (10,11-epoxy octadecanoate).  Epoxy curing agents exemplified are diethylene triamine, and (8) a mixture of hexa-hydrophthalic anhydride and benzyl dimethylamine: other curing agents listed include, KOH, NaOH, Na phenoxide, formic and oxalic acids, phthalic anhydride, dimerized or trimerized 8, 12-eisocadiene-1, 20-dioic acid, AlCl3, ZnCl2, FeCl3, Zn fluoborat and fluosilicate, Mg perchlorate, phosphoric acid, diethyl or n-butyl orthophosphate, hexaethyl tetraphosphate, soluble adducts of amines and polyepoxides, or salts thereof, as described in Specifications 691,543 and 718,851, polyamides, and a long list of amines and amides including triethanol-amine and diallylamine. There may also be present conventional epoxy resins: in Ex. (6) there are included the poly-glycidyl ethers of bis phenol A, glycerine, resorcinol and ethylene glycol: elsewhere there are mentioned the poly glycidyl ether of sorbitol and poly allyl glycidyl ether.  Solvents such as xylene, benzene, and petroleum distillates may also be present.  The main use of these compositions is for coating asphalt, concrete, wood, metal or glass, and in particular roads and runways.  Inert solid particles may be added to the compositions when used in this way, e.g. sand, rock, corundum, shells, quartz and Al2O3. Specifications 639,551, 763,559, 818,810, 819,107 and 860,287 also are referred to.ALSO:Poly glycidyl esters of dimerized and trimerized linoleic, trimerized linoleic and dimerized resin acids and of the adduct of methyl abietate and maleic anhydride are prepared by reacting the alkali metal salts of the acids with epichlorhydrin with or without benzyl trimethyl ammonium chloride. In Preparation V trimerized linoleic acid is reacted with diglycidyl ether in the presence of diethanolamine to produce a poly-(glycidyl-glyceryl) ester containing 2 to 3 <FORM:0883522/IV (b)/1> groups.  Specifications 639,551, 691,543, 718,851, 763,559, 818,810, 819,107 and 860,287 are referred to.ALSO:Bituminous compositions comprise a bituminous material and a polyepoxy ester having at least 8 carbon atoms in the molecule. Bituminous materials specified are straight run and blown asphaltic, bitumens the residues from the distillation of catalytically cracked gas oil, Edeleanu extracts of petroleum distillates, coal tar, refined coal tar, and coal tar pitch.  Long lists of polyepoxy etsers are given of which the polyglycidyl esters of dimerized and trimerized unsaturated acids (e.g. linoleic, linolenic and resin acids) are preferred, other exemplified esters being the diglycidyl esters of dioic acids in Ex (3) and the dimethyl, diethyl and glycerol esters of epoxy acids in Ex (8).  Epoxy curing agents may also be added and are listed at length, the following being used in examples:-diethylene triamine and (8) a mixture of hexahydrophthalic anhydride and benzyl dimethylamine. Conventional epoxy resins may also be present: in Ex (6) there are included the polyglycidyl ethers of bisphenol A, glycerine, resorcinol and ethylene glycol.  Solvents such as xylene, benzene and petroleum distillates may also be used.  The main use of these compositions is for coating asphalt, concrete, wood, metal or glass, and in particular roads and runways.  Inert solid particles may be added to the compositions when used in this way, e.g. sand, rock, corundum, shells, quartz and alumina.  Specifications 639,551, 691,543, 718,851, 763,559, 818,810, 819,107 and 860,287 are referred to.