Patent SG-11201811335U-A (SG)
Title: Quinolinyldiamido transition metal complexes, production and use thereof
Inventor: HAGADORN JOHN
IPC: C08F10/06
Filed: 2017-06-21
Abstract: INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property 1#11101111 0 11101 010 11111 3E1 0 01111011111110101011111011110 III OEN Organization International Bureau (10) International Publication Number (43) International Publication Date .....0\"\"\" WO 2018/005201 Al 04 January 2018 (04.01.2018) WIP0 I PCT (51) International Patent Classification: Xin; 7218 Commons Walk Lane, Humble, TX 77369 C07F 7/00 (2006.01) CO8F 4/64 (2006.01) (US). GORYUNOV, Georgy, P.; Apt. 127, 3 Dachnaya C08F 10/06 (2006.01) CO8F 4/642 (2006.01) Street, Kokoshkino, Moscow, 143390 (RU). SHARIKOV, (21) International Application Number: Mikhaill; Apt. B-1322, 1 Leninskie Gory, Moscow, 119234 (RU). UBORSKY, Dmitry, V.; Apt. 136, Bldg. 3 Aly- PCT/US2017/038606 mova St., Moscow, 107392 (RU). VOSKOBOYNIKOV, (22) International Filing Date: Alexander, Z.; Akademika Koroleva Street 5, Apt. 93, 21 June 2017 (21.06.2017) Moscow, 129515 (RU). (25) Filing Language: English (74) Agent: BELL, Catherine, L. et al.; ExxonMobil Chemical (26) Publication Language: English Company, Law Department, P.O. Box 2149, Baytown, TX 77522-2149 (US). (30) Priority Data: (81) Designated States (unless otherwise indicated, for every 62/357,033 30 June 2016 (30.06.2016) US kind of national protection available): AE, AG, AL, AM, 16185512.7 24 August 2016 (24.08.2016) EP AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, (71) Applicant: EXXONMOBIL CHEMICAL PATENTS CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, INC. [US/US]; 5200 Bayway Drive, Baytown, TX 77520 DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, (US). HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, (72) Inventors: HAGADORN, John, R.; 4838 Knickerbock-MG, MK, MN, MW, MX, MY MZ, NA, NG, NI, NO, NZ, — er Street, Houston, TX 77035 (US). PALAFOX, Patrick, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, J.; 155 Cross Creek Parkway, Apt. 438, Hattiesburg, MS SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, = 39402 (US). JIANG, Peijun; 119 Mariner Cove Court, ou TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. League City, TX 77573 (US). GAO, Yaohua; 4300 Bay = Area Blvd., Apt. 1322, Houston, TX 77058 (US). CHEN, = Title: TRANSITION METAL COMPLEXES, PRODUCTION AND USE THEREOF (54) QUINOLINYLDIAMIDO = = _ ° i t . . el = f& N N N N 'W N 'W I I ,,N ,N _,..N • = Hf Hf Hf 11 I-If - -- 19 - ' I 1101 N' I . N' I 110 N' I 1110 \"NMe 2 \"NMe 2 'NMe 2 \"NMe 2 = — NMe 2 NMe2 NMe2 NMe2 Aiik _ ® lir IP = (Q1)Hf(NMe 2 ) 2 (Q2)Hf(NMe (Q3)Hf(NMe 2 ) 2 (Q4)Hf(NMe 2 ) 2 2 ) 2 = = = = Si 0 1110 0 40 161 N = 0 i' 10 ri' 40 0,11, I r.- 1 , 6 NI' f N ----INI Hf Hf N w ir 'Me ilo 110 'Me IP 'Me N' H I N' I N C I Me N' H I ®® ® Me Me Me Me 1-1 (Q1)HfMe 2 (Q2)HfMe 2 (Q3)HfMe 2 (Q4)HfMe 2 1-1 0 ei kr) © FIG. 1 © -.... 00 N (57) : Quinolinyldiamido transition metal complexes are disclosed for use in alkene polymerization to produce multimodal polyolefms. [Continued on next page] WO 2018/005201 Al MIDEDIMOMOIDEIREEMOOVIIMMIIMOINEVOIMIE (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Published: — with international search report (Art. 21(3))