Patent GB-1005608-A (GB)
Title: Improvements in or relating to the manufacture of polymers containing urethane and/or carbonamide groups
IPC: C08G69/00
Filed: 1963-02-06
Abstract: A process for the production of polymers containing urethane and/or carbonamide groups comprises reacting with an organic polyisocyanate a polyester formed by the condensation of a polybasic or aliphatic carboxylic acid, or its ester, prepared by copolymerizing aromatic vinyl compounds with fatty acids or their esters containing conjugated double chords, with a polyhydric alcohol, said polyester having an hydroxy number of 25-300 and an acid number of 0.1-100. The araliphatic acid may be used in combination with aliphatic dicarboxylic acids having 5 to 10 carbon atoms and/or aromatic dicarboxylic acids and/or dimerized fatty acids and/or monocarboxylic acids having more than 5 carbon atoms.  The polybasic araliphatic carboxylic acids for the production of the polyesters may be obtained by cationic polymerization of conjugated fatty acids with styrene or its homologues in a ratio of 0.1 to 5 mols. of styrene per mol. of conjugated unsaturated fatty acid at below 200 DEG  C.  Alternatively the araliphatic carboxylic acid may be obtained by copolymerizing the reactants in the presence of an organic peroxide and an alkylmercaptan reducing agent.  Many fatty acids are specified. Many polyhydric alcohols, e.g. alkylene glycols, poloxy alkylene glycols, glycerine, trimethylolpropane, hexanetriol, pentaerythritol and adducts of ethylene oxide with polyhydric alcohols may be used to prepare the polyesters which mostly have an average M.W. of 800-6000, an OH number of 25-300 and acid number of 0.1 to 5.  Polyisocyanates may be aromatic or acyclic, e.g. phenylene diisocyanate or hexamethylene diisocyanate.  In Example (1) isomerized safflower oil fatty acids were copolymerized with alphamethyl styrene and styrene and the polymerized acid condensed with dietaylene glycol and pentaerythritol and finally with toluene diisocyanate; (2) isomerized soya oil fatty acid methyl ester was polymerized with styrene and the product condensed with diethylene glycol and then with diphenyl methane 441-diisocyanate; (7) the methyl ester of Example (2) was condensed with trimethylol propane and diethylene glycol and a solution of the polyester so obtained in methyl acetate/butyl acetate reacted with a polyisocyanate derived from toluene diisocyanate and trimethylolpropane to produce a lacquer.  In Example (3) a copolymer of isomerized soya oil fatty acids and styrene was reacted with diethylene glycol and to the polyester were added: chalk, water, triethylamine, alkylphenol, polyglycolether and diphenylmethane 441-diisocyanate and a foam was formed.  Specification 988,737 is referred to.ALSO:Araliphatic polycarboxylic acids and esters thereof are produced by copolymerizing aromatic vinyl compounds, e.g. styrene and its homologues, with fatty acids or their esters containing conjugated double bonds.  The polymerization may be cationic with 0.1 to 5 mols. of styrene or its homologues per mol. of unsaturated conjugated fatty acid, or alternatively the polymerization is effected in the presence of an organic peroxide and an alkyl mercaptan reducing agent.  In examples, styrene and/or alpha methyl styrene are polymerized with (1) isomerized safflower oil fatty acids, (2) isomerized soya oil fatty acid methyl ester. Specification 988,737 is referred to.