Patent GB-902661-A (GB)
Title: Improvements in and relating to purification of hydrocarbons
IPC: C10G25/03
Filed: 1961-03-13
Abstract: Hydrocarbons are purified to remove sulphurcontaining compounds by (1) passing the feed in the liquid phase through a bed of a molecular sieve having a pore size of at least 3,8   at a rate such that the bed is maintained full of liquid; (2) desorbing the bed by passing a hot inert gas downwardly through the bed to remove adsorbed sulphur compounds; and (3) cooling the bed by passing hydrocarbon feed downwardly through the bed at a lower rate than in step (1), so as to cool the bed and refill it with liquid.  The feed may be propane, butane, propylene, light naphtha (C5-C8) boiling in the range 80 DEG -250 DEG F. or heavy naphtha (C8 to C13) boiling in the range 225 - 450 DEG F.  Contaminants may be hydrogen sulphide, carbonyl sulphide, mercaptans or thiophene present in amounts of 0,5 x 10-4 to 5% by weight; to remove hydrogen sulphide only, a 4   sieve may be used for normal mercaptans up to C7 the pore size must be at least 4,6   and for branched chain mercaptans, aromatic mercaptans or thiophene, the pore size should be at least 8 A.  Any synthetic molecular sieve of the A, D, K, T, X or Y type containing alkali or alkaline earth metals may be used or natural zeolites such as mordenite, chabazite or erionite.  A sodium zeolite X which has 10   pores is preferred. The hydrocarbon is preferably introduced at ambient temperature at a superficial velocity of 0,1 - 20 feet per minute.  Feed is stopped preferably at a point such that the bed has only sufficient adsorptive capacity to purify liquid remaining in the bed.  The bed is drained and liquid remaining in the interstices removed by reducing the pressure of passing hot or cold inert gas through the bed.  Suitable desorbing gases are methane, hydrogen, nitrogen and carbon monoxide which may be heated to 350 DEG -600 DEG F.ALSO:Hydrocarbons are purified to remove sulphur-containing compounds by (1) passing the feed in the liquid phase through a bed of a molecular sieve having a pore size of at least 3.8   at a rate such that the bed is maintained full of liquid; (2) desorbing the bed by passing a hot inert gas downwardly through the bed to remove adsorbed sulphur compounds; and (3) cooling the bed by passing hydrocarbon feed downwardly through the bed at a lower rate than in step (1), so as to cool the bed and refill it with liquid.  The feed may be propane, butane, propylene, light naphtha (C5-C8) boiling in the range 80-250 DEG F. or heavy naphtha (C8-C13) boiling in the range 225-450 DEG F. Contaminants may be hydrogen sulphide, carbonyl sulphide, mercaptans or thiophene present in amounts of 0.5 X 10-4 to 5% by weight; to remove hydrogen sulphide only, a 4   sieve may be used, for normal mercaptans up to C7 the pore size must be at least 4.6   and for branched chain mercaptans, aromatic mercaptans or thiophene, the pore size should be at least 8  .  Any synthetic molecular sieve of the A, D, K, T, X or Y type containing alkali or alkaline earth metals may be used or natural zeolites such as mordenite, chabazite or erionite.  A sodium zeolite X which has 10 pores is preferred.  The hydrocarbon is preferably introduced at ambient temperature at a superficial velocity ambient temperature at a superficial velocity of 0.1-20 feet per minute.  Feed is stopped preferably at a point such that the bed has only sufficient adsorptive capacity to purify liquid remaining in the bed.  The bed is drained and liquid remaining in the interstices removed by reducing the pressure of passing hot or cold inert gas through the bed.  Suitable desorbing gases are methane, hydrogen, nitrogen and carbon monoxide which may be heated to 350-600 DEG F.