Patent GB-840830-A (GB)
Title: Process for the production of thixotropic oils
IPC: B01J13/00
Filed: 1958-01-20
Abstract: Thixotropic oils are obtained by a process in which 1 mol. of a drying or non-drying oil is catalytically inter-esterified with 0.5-2.5 mols. of a polyhydric alcohol, the product thus obtained being then reacted with such a quantity of a diisocyanate as is substantially equivalent to the free hydroxyl groups present, the polyhydric alcohol and/or the diisocyanate having symmetrical molecular structures.  Oils which may be treated include linseed, soya, wood or olive oil; polyhydric alcohols which may be used are trimethylolpropane, perhydro-bisphenol, butenediol, 2:2 - dimethylpropane-1:3-diol, and ethylene glycol; suitable diisocyanates are toluene-2:6-diisocyanate, 3:5-diethyltoluene - 2:6 - diisocyanate, dicyclohexylmethane - 4:41 - diisocyanate, p - phenylene diisocyanate, cyclohexane - 1:4 - diisocyanate, 1:5 - dimethyl - 2:4 - diisocyanatobenzene, and -cyclohexane-4:4-diisocyanate; the preferred interesterification catalyst is lithium naphthenate.  The interesterification temperature should not exceed 300 DEG  C. and the reaction of the product obtained with the diisocyanate should desirably be carried out in solution in a solvent.  Suitable solvents are hydrocarbons such as white spirit and styrene, esters, ketones, and, if excess of diisocyanate is used, aliphatic alcohols, so that excess diisocyanate is eliminated.  The products obtained may be used in conjunction with film formers such as alkyd resins, unsaturated polyesters, modified natural and synthetic resins, cellulose derivatives and stand oils.ALSO:Thixotropic oils are obtained by a process in which 1 mol. of a drying or non-drying oil is catalytically inter-esterified with 0.5-2.5 mols. of a polyhydric alcohol, the product thus obtained being then reacted with such a quantity of a diisocyanate as is substantially equivalent to the free hydroxyl groups present, the polyhydric alcohol and/or the diisocyanate having symmetrical molecular structures.  Oils which may be treated include linseed, soya, wood, or olive oil; polyhydric alcohols which may be used are trimethylolpropane, perhydro-bisphenol, butenediol, 2:2-dimethylpropane-1:3-diol, and ethylene glycol; suitable diisocyanates are toluene-2:6-diisocyanate, 3:5-diethyltoluene - 2:6 - diisocyanate, dicyclohexylmethane - 4:41 - diisocyanate, p - phenylene diisocyanate, cyclohexane - 1:4 - diisocyanate, 1:5 - dimethyl - 2:4 - diisocyanatobenzene and - cyclohexane - 4:4 - diisocyanate; the preferred interesterification catalyst is lithium naphthenate.  The interesterification temperature should not exceed 300 DEG  C. and the reaction of the product obtained with the diisocyanate should desirably be carried out in solution in a solvent.  Suitable solvents are hydrocarbons such as white spirit and styrene, esters, ketones and, if excess of diisocyanate is used, aliphatic alcohols, so that excess diisocyanate is eliminated.  The products obtained may be used in conjunction with film formers such as alkyd resins, unsaturated polyesters, modified natural and synthetic resins, cellulose derivatives and stand oils in paints, or added to lacquers or enamels to prevent settling of pigments, or, as in one example, in conjunction with a mixture of a linseed oil alkyd resin in white spirit, a maleonate resin in xylene, titanium dioxide and cobalt, lead and manganese naphthenate driers to form an enamel.