Patent ES-268051-A1 (ES)
Title: Manufacture of carbon black
IPC: C09C1/50
Filed: 1961-06-08
Abstract: <PICT:0926450/III/1> <PICT:0926450/III/2> In the production of furnace black wherein a make hydrocarbon is injected into hot turbulent combustion gases to decompose therein, the make hydrocarbon is injected in liquid phase as a sheet of thickness 0,005-0,1 inch in the form of an expanding hollow cone, the angle of spread being not less than 60 degrees or greater than 120 degrees, and which extends at least 3 inch beyond the point of injection. The hot combustion gases may be derived from a plurality of burners in an end wall or may be tangentially injected so as to make a helically flowing stream within an elongated furnace chamber and the effluent is passed from the down stream end of the chamber, the C black being separated and collected. The hydrocarbon feed may have a mean molecular weight of 150-350 and 75-100% aromatic content and is injected at not more than 100 p.s.i. as a hollow cone initiated coaxially and near one end of the furnace chamber. The hydrocarbon feed may have a V.O.P. characterization factor of 9-10,9, and may be a heavy high boiling hydrocarbon such as tars, residues or extracts from coal or petroleum. In Fig. 1 a C black furnace has chambers 1 and 7 with cooler 2, lined with refractory 3 and 9, firebrick 4, heat insulant 5 and metal jacket 6. Combustion zone 7 at, e.g. 2200 DEG -3500 DEG F. is fed with, e.g. fuel gas or liquid hydrocarbon (which may be preheated to 250 DEG F.) and air or free O2 containing gas via tangential ports 8. The furnace may be circular or rectangular in cross-section. The fuel may be burnt outside the furnace and the hot combustion gases injected into 1, 7 or between them to give a helical stream. Chamber 10, fed with air under pressure is connected to chamber 7 via ports 8 fitted with burner tubes and fuel inlets as in Fig. 2 (not shown). Hydrocarbon feed injector 16 can be adjusted in sleeve 18 by screws 20 in collar 21 and flange 22. The injector is shown in Fig. 3, detailed in Fig. 4 (not shown) feed pipe 23 is surrounded by tubes 24 and 26 with air space 25, passages 27, and 30, and p walls 28 and 29. Plate 31, 1-3 inch diameter, is recessed to 1/32 -\ba1/4 inch at 32 and threaded at 33 to receive movable plug 34 with port 35 which has a conical seat 36 and forms with cone 37 an adjustable opening 38. Cone 37 is fixed to stem 39 which is fixed to shaft 40 and has a hand wheel 41. Shaft 40 is threaded at 42 and extends through valve caps 43 welded to tube 24 with packing gland 44 and lock nut 45. Hydrocarbon is fed via pipes 46 and 23 to plug 34 and exit port 35 via exits 47. Cooling H2O is fed via pipes 48 and 27 to holes 49 in plate 50 and to exit 51. If gas is used for cooling, steam, air or combustible gas is fed via tube 27 to the furnace. Plug 34 extends to 52 set in bearing 53. A longitudinal injection furnace is illustrated in Figs. 5 and 6 (not shown). Specifications 669,968 and 878,202 are referred to.ALSO:Synthetic or natural rubber may be compounded with furnace C black (see Group III). The C black is made by injecting into hot turbulent combustion gases a make hydrocarbon in the liquid phase as a sheet 0,005-0,1 inch thick in the form of an expanding hollow cone, the angle of spread being not less than 60 degrees or greater than 120 degrees, and which extends at least 3 inches beyond the point of injection. Specifications 669,968 and 878,202 are referred to.