Patent GB-713735-A (GB)
Title: Improvements in and relating to organopolysiloxane lubricating compositions
IPC: C08L83/04
Filed: 1950-07-18
Abstract: A liquid organo-substituted polysiloxane and a minor proportion of an additive of general formula <FORM:0713735/IV (a)/1> where R is an alkyl radical containing from 1 to 4 carbon atoms and X is halogen are compounded to form a lubricating composition (see Group III). Preferably X is in the para-position.  The amount of additive may be from 0.5 to 10 per cent. based on the weight of the liquid organo-polysiloxane.  In the formula above R may be methyl, ethyl, propyl, isopropyl, butyl or isobutyl and X may be chlorine, bromine or fluorine.  The additive may be prepared by reacting a dialkyl di-halogenosilane with a dihalogeno phenyl-Grignard reagent in anhydrous ethyl ether (see Group IV (b)).  Specified poly-siloxanes to which the additives may be added include the liquid methyl-, ethyl-, propyl-, butyl-, isopropyl- and other alkyl-substituted polysiloxanes, the liquid aryl-substituted polysiloxanes, e.g. the phenyl-substituted polysiloxanes, polysiloxanes containing on the silicon atom or atoms differing hydrocarbon radicals, e.g. liquid methyl- and phenyl-substituted polysiloxanes, and polysiloxanes containing alkyl and aryl substituents on different silicon atoms such as may be obtained by hydrolyzing a mixture of dimethyl dichlorosilane and diphenyl dichlorosilane.  Preferred silicone oils are liquid methyl polysiloxanes containing an average of 1.9 to 3.0 methyl groups per silicon atom, and liquid methyl phenyl polysiloxanes containing an average over 1.9 to 2.5 total methyl and phenyl groups per silicon atom.  If desired, stabilizers against gelation, corrosion inhibitors, anti-oxidants and other additives may be incorporated in the compositions.  Example 2 describes a composition comprising a liquid oily methyl polysiloxane and about 3 per cent. of its weight of bis(p-chloro-phenyl)-dimethyl silane. Specifications 575,668, 586,187, 626,515, [Group III], and 650,800 are referred to.ALSO:Di-(halogenophenyl)-dialkyl silanes of general formula <FORM:0713735/IV(b)/1> where R is an alkyl radical containing from 1 to 4 carbon atoms (methyl, ethyl, propyl, isopropyl, butyl, isobutyl) and X is chlorine, bromine or fluorine, are prepared by reacting a dialkyl dihalogeno silane with a Grignard reagent prepared from a dihalogeno phenyl.  X is preferably in the para position.  The di-(halogenophenyl)-dialkyl silanes may be used as additives in lubricating compositions comprising silicone oils (see Group III). In an example dimethyl bis-(p-chlorophenyl)silane is prepared from p-chlorophenyl magnesium bromide and dimethyldichlorosilane in anhydrous ethyl ether.  Specifications 575,668 and 626,515 are referred to.ALSO:A lubricating composition comprises a liquid organo-substituted polysiloxane and a minor proportion of an additive of general formula <FORM:0713735/III/1> where R is an alkyl radical containing from 1 to 4 carbon atoms and x is halogen.  Preferably x is in the para-position.  The amount of additive may be from 0.5 to 10 per cent. based on the weight of the liquid organo-polysiloxane. In the formula above R may be methyl, ethyl, propyl, isopropyl, butyl or isobutyl and x may be chlorine, bromine or fluorine.  The additive may be prepared by reacting a dialkyl di-halogenosilane with a dihalogeno phenyl-Grignard reagent in anhydrous ethyl ether (see Group IV (b)).  Specified poly-siloxanes to which the additives may be added include the liquid methyl-, ethyl-, propyl-, butyl-, isopropyl- and other alkyl-substituted polysiloxanes, the liquid aryl-substituted polysiloxanes, e.g. the phenyl-substituted polysiloxanes, polysiloxanes containing on the silicon atom or atoms differing hydrocarbon radicals, e.g. liquid methyl- and phenyl-substituted polysiloxanes, and polysiloxanes containing alkyl and aryl substituents on different silicon atoms such as may be obtained by hydrolizing a mixture of dimethyl dichlorosilane and diphenyl dichlorosilane.  Preferred silicone oils are liquid methyl polysiloxanes containing an average of 1.9 to 3.0 methyl groups per silicon atom, and liquid methyl phenyl polysiloxanes containing an average of 1.9 to 2.5 total methyl and phenyl groups per silicon atom.  If desired stabilizers against gelation, corrosion inhibitors, anti-oxidants and other additives may be incorporated in the compostions.  Example 2 describes the testing of a lubricating composition comprising a liquid oily methyl polysiloxane and about 3 per cent. of its weight of bis(p-chlorophenyl)-dimethyl silane. Specifications 575,668, 586,187, [both in Group IV], 626,515 and 650,800, [Group IV (a)], are referred to.