Patent GB-942454-A (GB)
Title: Surface-coating compositions
IPC: C08L61/20
Filed: 1960-01-07
Abstract: A thermosetting coating composition comprises a compatible mixture of at least one thermosetting alkylated aminoplast resin, at least one thermoplastic acrylic polymer, which consists at least predominantly of units derived from one or more esters of acrylic and/or methacrylic acid, and a polyepoxide.  The alkylated aminoplast may be one obtained by alkylation with an alkanol having 1 to 8 carbon atoms or cyclohexanol, of a condensate of an aldehyde, particularly formaldehyde, with urea, N,N1-ethyleneurea, dicyandiamide or an aminotriazine; alkylated aminoplasts used in the examples are butylated or methylated melamine-formaldehyde condensate, butylated urea-formaldehyde condensate and butylated benzoguanamine-formaldehyde condensate. The acrylic polymer may be polymethylmethacrylate or a copolymer consisting predominantly of esters of the formula <FORM:0942454/C3/1> where R is hydrogen or methyl and R1 is benzyl, cyclohexyl, or an alkyl group having 1 to 10 carbon atoms, copolymerized with one or more other copolymerizable monoethylenically unsaturated compounds. The copolymer may comprise from 1 to 4% of a monoethylenically a ,b -unsaturated carboxylic acid or an alkali metal or ammonium salt thereof, such as acrylic, methacrylic, itaconic, maleic, fumaric, aconitic, citraconic or crotonic acid and from 1 to 10% by weight of a copolymerizable monoethylenically unsaturated compound having a CH2=C< group and a polar group such as 2-ureidoethyl vinyl ether, 2,2-dimethyl-2-ureidoethy vinyl ether, glycidyl acrylate or methacrylate, acrylamide, methacrylamide, N-alkylacrylamide, N-alkylmethacrylamide, N-methacrylamideothyl-N,N1-ethyleneurea, N-(b -(a -acryloxyacetamido)ethyl)- N,N1-ethyleneurea and N-(b -(a -methacryloxyacetamido)ethyl) - N,N1 - ethyleneurea.  The balance of the polymer may comprise other copolymerizable compounds such as acrylonitrile, methacrylonitrile, styrene, vinyl toluene and a -methyl styrene. The polyepoxides contemplated are those which contain at least two epoxy groups, those used in the examples being condensation products of epichlorhydrin with glycerine, ethylene glycol, 4,41-isopropylidenebisphenol or a mixture of ethylene glycol and diethylene glycol. The copolymers are preferably prepared by solution polymerization in an organic solvent in the presence of an initiator such as an azo catalyst, t-butyl peracetate, benzoyl peroxide, t-butyl hydroperoxide or cumene hydroperoxide. The coating compositions may be prepared by dissolving the polymer, the aminoplast and the polyepoxide in a solvent such as those specified in Specification 939,211, and pigments referred to in that Specification may also be added. Specifications 518,057 and 579,698 also are referred to.ALSO:Coating compositions which may be applied to substrates by brushing, spraying, dipping or roller coating, followed by drying and curing by baking, comprise organic solvent solutions of a compatible mixture of at least one thermosetting alkylated aminoplast resin, at least one thermoplastic acrylic polymer, which consists at least predominantly of units derived from one or p  more esters of acrylic and/or methacrylic acid, and a polylpoxide (see Division C3).  The compositions may be used for coating metals, wood, ceramics, brick, stone, and concrete surfaces, e.g. as finishing topcoats for automobiles, or for the decoration of tin cans or other canisters, and are particularly suitable for the coating of asbestos cement products where curing in an autoclave in direct contact with steam is encountered.  Examples describe the coating of a sheet of asbestos-cement composition made up of several laminations, veneered with a composition containing Portland cement, asbestos fibres, mineral oxide pigments and extenders and textured by means of embossing rolls.  Other examples describe the coating of panels of aluminium, chromium, chrome-plated steel and cold-rolled steel, castings of iron, steel, bronze, brass, aluminium and alloys thereof, and of ceramic insulator bodies.  Specifications 518,057 and 579,698 are referred to.ALSO:Cloth tapes, paper and ceramic insulator bodies are impregnated with a solution comprising a 40% toluene solution of a copolymer of methyl methacrylate and N-(b -(a -methacryloxyacetamido) ethyl)-N, N1-ethylene urea, mixed with a 40% solution in the monobutyl ether of diethylene glycol of a polyepoxide formed by condensation of epichlorhydrin with 4, 41-isopropylidene bisphenol, and with a 60% xylene solution of n-butylated benzoguanamine formaldehyde condensate, followed by drying and curing by heating.  The impregnating solution may also contain a small quantity of paraffin wax to reduce blocking, and the copolymer may also be derived from ethyl acrylate in addition to the two monomers specified.  Thin translucent paper is made transparent by impregnation with a composition of the above constitution followed by drying by heating at 150 DEG F.  Specifications 518,057 and 579,698 are referred to.