Patent ES-279159-A1 (ES)
Title: Manufacture of granular fertilizers
IPC: C05B7/00
Filed: 1962-07-12
Abstract: A granular fertilizer comprising ammonium phosphate, particularly of N : P ratio between 1.4 and 2.2, is produced by recirculating granules of the fertilizer in a continuous stream through at least two regions so that in the first region the granules are treated with phosphoric acid and then with ammonia, the partial pressure of ammonia in the first region being higher than the ammonia pressure caused by the decomposition of the said ammonium phosphate at the working temperature, and in the second region the gaseous atmosphere therein is treated with a current of a gas of volume at least sufficient to remove, at the rate of recirculation, the water vaporized in and carried over from the first region and insufficient to remove any substantial quantity of ammonia, the rate of circulation through the two regions being also such that in the first region the ammonia has sufficient time to react with the phosphoric acid to form ammonium phosphate of the desired N : P ratio, controlling the rate of addition of the ammonia and acid, and hence the rate of removal of the granular product, and the rate of recirculation of the granules in the stream so that at least most of the granules remain discrete and free-flowing and are ammoniated to the desired level, and removing from the recirculating stream in a region removed from the first region a granular product in an amount substantially equivalent to the phosphoric acid and ammonia added in the first region and of the required moisture content. The limiting concentration of the phosphoric acid may be that below which more water is introduced to the recirculating stream of granules than can be adequately evaporated by the heat of reaction of the phosphoric acid and the ammonia. The ammonia used may be anhydrous. The average moisture content of the granules in the first region is preferably at <PICT:0964354/C1/1> least 0.1% less than that at which the granules lose their discrete identities at the temperature of the first region. At least one acid, e.g. nitric or sulphuric, may be used in addition to the phosphoric acid, and the additional acids may be introduced with the phosphoric acid in the first region. The lower limits of the concentrations of the additional acids are governed by the amount of water introduced thereby, and the acids may be ammoniated at points in the recirculating stream outside the first and second regions. The rate of recirculation of the granules may be sufficiently fast to cause the formation of thin skins of acid on each granule. The ratio of the recirculation of the granules to the rate of removal of the granular product may be at least 20 : 1, preferably between 30 : 1 and 80 : 1. One or more fertilizer salts and/or additives, e.g. urea or potassium salts, and pesticides or fungicides which remain stable under the reaction conditions prevailing may be added concurrently with the acid and ammonia to the recirculating stream of granules. The gas in the second region, of volume sufficient to remove the water vapour formed in the first region, may be counter-current to the recirculating stream of granules. In the first region this stream may be passed through a vessel which is adapted so as to be substantially sealed by the recirculating stream of granules entering and leaving it, and the vessel may be modified to permit a gas to pass through it co-currently with the granules. The recirculation may be effected in a single reactor. Example 1 refers to a complete granular fertilizer which is produced in the reactor, shown in the accompanying diagram. The fertilizer contains 23% N, 11 1/2 % P2O5 and 11 1/2 % K2O, based on ammonium nitrate, ammonium phosphate, and potassium chloride, respectively. Phosphoric acid and ammonia are fed into the inner drum 1, and nitric acid and ammonia are introduced to the bed of the previously prepared fertilizer of the above composition. Potassium chloride is fed on to the bed in the outer drum. The strength of the materials used is given, as well as their rate of addition. The operating temperature is 85 DEG C., the dew point 80 DEG C. The production rate is also given. Example 2 refers to the production of a diammonium phosphate. Specifications 907,900, 916,447 and 950,775 are referred to.