Patent EP-0109342-B1 (EP)
Title: Moulding compositions of semi-rigid copolyamides derived from dimeric fatty acids, elastomers and optionally conventional polyamides
IPC: C08L77/08
Filed: 1983-09-02
Granted: 1986-09-17
Abstract: 1. Polyamid-based moulding compositions having excellent flexibility and resilience characteristics, especially at temperatures as low as those ranging from 0-40 degrees C, characterised in that they comprise, by way of obligatory constituents : (1) a semi-rigid copolyamide prepared from fatty acid dimers, (2) and at least one elastomer containing sequences compatible with or reactive with the copolyamide (1) and belonging to the group consisting of : (a) olefinic copolymers derived from an aliphatic alpha-olefine containing from 2 to 6 carbon atoms and at least one compound belonging to the class of alpha,beta-unsaturated monocarboxylic or dicarboxylic acids containing from 3 to 8 carbon atoms, lower alkyl esters of these acids and anhydrides derived from these acids ; (b) olefinic copolymers containing carboxyl and/or carboxylate groups and derived from ethylene and at least one alpha-olefine having from 3 to 6 carbon atoms ; (c) olefinic copolymers containing carboxyl and/or carboxylate groups and derived from ethylene, at least one alpha-olefine having from 3 to 6 carbon atoms and at least one non-conjugated aliphatic diene containing at least 5 carbon atoms ; (d) copolyester-amides obtained from (i) an acid compound containing 1 to 100 mole-% of a diacid or derivative having from 15 to 60 carbon atoms and 0 to 99 mole-% of at least one other difunctional reagent chosen from amongst diacids, aminoacids, hydroxyacids and their derivatives which form esters or amides, these compounds having a number of carbon atoms at most equal to 12, (ii) a dihydroxylic compond with can be a linear, branched or cyclic diol having from 2 to 8 carbon atoms and/or a macromolecular dihydroxylic compound having a molecular weight of between 500 and 5000, such as a polyoxyethylene glycol, polytetrahydrofuran or polyoxypropylene glycol and (iii) an amine compound comprising at least one diamine and/or at least one aminoalcohol having a number of carbon atoms at most equal to 5, it being possible to omit the compound (iii) in cases where the acid compound (i) already contains an amine-type reagent ; (e) polyurethanes obtained from (i) an aliphatic polyester and/or an aliphatic polyether with a terminal hydroxyl group and having a molecular weight of between 500 and 4000, (ii) an aliphatic diol containing 2 to 8 carbon atoms and optionally having a substituent of the nitro, chloro, bromo or fluoro type and (iii) an aromatic diisocyanate ; (f) organopolysiloxane and polyurethane block copolymers obtained by reaction of (i) a polysiloxane macrodiol (or polysiloxane macrodiisocyanate) produced by the reaction of an alpha,omega-hydrogenopolysiloxane of the formula :   see diagramm : EP0109342,P17,F1   in which n is a number between 10 and 80 and the substituents R, which may be identical or different, represent methyl, vinyl or phenyl groups, with a primary ethylenic monoalcohol (or ethylenic monoisocyanate) and (ii) a short diol and a short diisocyanate ; (g) copolymers of unsaturated monomers, having at least one elastomeric phase and obtained in the form of particles of size between 0.05 and 1.5 um by emulsion polymerisation of an alkyl acrylate, an alkyl methacrylate or a conjugated aliphatic diene, at least one unsaturated comonomer which carries a carboxylic acid group or derivative thereof, amine group or derivative thereof, nitrile group, sulphonic acid group or derivative thereof, and optionally at least one other ethylenically unsaturated comonomer ; the amount of elastomeric phase (2), which may comprise one or more elastomers, representing 4% to 60% by weight of the combination of semi-rigid copolyamide (1) + elastomeric phase (2).