Patent SG-11201908901U-A (SG)
Title: Catalyst compositions and their use in aromatic alkylation processes
Inventor: IDE MATTHEW
IPC: B01J29/08
Filed: 2018-03-19
Abstract: INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (43) International Publication Date 04 October 2018 (04.10.2018) Hu omits I E IOMOIMIONONHOMEHOIS (10) International Publication Number WO 2018/183009 Al WIPO I PCT (51) International Patent Classification: B01J 29/00 (2006.01) C07C 2/66 (2006.01) BO1J 29/03 (2006.01) BO1J 29/18 (2006.01) BO1J 29/08 (2006.01) BO1J 35/10 (2006.01) BO1J 29/70 (2006.01) BO1J 37/00 (2006.01) BO1J 29/80 (2006.01) BO1J 35/02 (2006.01) (21) International Application Number: PCT/US2018/023077 (22) International Filing Date: (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). (25) Filing Language: (26) Publication Language: (30) Priority Data: 19 March 2018 (19.03.2018) English English Published: with international search report (Art. 21(3)) before the expiration of the time limit for amending the claims and to be republished in the event of receipt of amendments (Rule 48.2(h)) 62/478,340 29 March 2017 (29.03.2017) US 62/478,237 29 March 2017 (29.03.2017) US 17174273.7 02 June 2017 (02.06.2017) EP (71) Applicant: EXXONMOBIL CHEMICAL PATENTS INC. [US/US]; 5200 Bayway Drive, Baytown, TX 77520 (US). (72) Inventors: IDE, Matthew, S.; 1 Woods End Drive, Doylestown, PA 18902 (US). LOVELESS, Brett, T.; 14005 N. Lake Branch Lane, Houston, TX 77044 (US). LEVIN, Doron; 350 North 4th Avenue, Highland Park, NJ 08904 (US). LONERGAN, William, W.; 17410 Mount Riga Drive, Humble, TX 77346 (US). VINCENT, Matthew, J.; 1720 Buttercup Lane, Kingwood, TX 77339 (US). TAI, Wei-Ping; 502 Heritage Oak Drive, Yardley, PA 19067 (US). BARRAI, Federico; 3833 Dunlavy, Apt. 323, Houston, TX 77006 (US). (74) Agent: TYUS, Darryl, M. et al.; ExxonMobil Chemical Company, Law Department, P.O. Box 2149, Baytown, TX 77522-2149 (US). (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, 1-1 TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. O O pc (54) Title: CATALYST COMPOSITIONS AND THEIR USE IN AROMATIC ALKYLATION PROCESSES 1-1 (57) : Catalyst compositions comprising a zeolite and a mesoporous support or binder are disclosed. The mesoporous support or binder comprises a mesoporous metal oxide having a particle diameter of greater than or equal to 20 tm at 50% of the cumulative O pore size distribution (d 5 0). Also disclosed are processes for producing a mono-alkylated aromatic compound (e.g., ethylbenzene or \" cumene) which exhibit improved yield of the mono- alkylated aromatic compound using alkylation catalysts comprising one or more 0 of these catalyst compositions.