Patent ES-230689-A1 (ES)
Title: Ammonium nitrate of reduced tendency to caking and setting on storage and method of producing same
IPC: C06B23/00
Filed: 1956-08-31
Abstract: Ammonium nitrate having a reduced tendency to cake contains at least 0.025 per cent, preferably 0.04 per cent., of an additive comprising a salt of the condensation product of 1 mol. of formaldehyde and 2 mols. of a monomethylnaphthalene sulphonic acid which is soluble in a saturated aqueous ammonium nitrate solution, e.g. the sodium, potassium, or ammonium salt (see Group IV (b) Abridgment). The additive may consist of a single salt, or a mixture of salts containing two or more cations and/or derived from two or more monomethylnaphthalene monosulphonic acids. The ammonium nitrate may be crystallized in the presence of the additive, when crystals in the form of laths, plates, scales or fine hairs are produced. Crystallization may be effected in the ordinary manner, by graining with mechanical agitation, or by spray crystallization. A product having a bulk density of 0.45-0.55 gm./c.c. may be produced by crystallization of an aqueous solution containing not more than 73 per cent of ammonium nitrate and 0.1-0.4 per cent., preferably 0.2 per cent, of the additive. Such crystallization may be effected by rapid or slow cooling to ambient temperature with or without stirring, and the resulting crystals may be separated from the mother liquid and dried at a temperature of 40-50 DEG C. Crystallization from a solution containing more than 73 per cent of ammonium nitrate may produce a product having a bulk density of above 0.6 gm./c.c. The additive, in the form of aqueous solution, may be added to previously formed ammonium nitrate in the moist or dry state, the water evaporated, and the product cooled to a temperature below 32.3 DEG C. while maintained in agitation. The moist ammonium nitrate may be ammonium nitrate crystals moistened with ammonium nitrate solution obtained by partial crystallization. The previously formed ammonium nitrate in the moist or dry state may alternatively be mixed with the powdered additive, as such or mixed with a carrier. Such a mixture may, for example, be produced by moistening kieselguhr with an aqueous solution of the additive and drying. Specification 743,602 is referred to.ALSO:An additive for modifying the crystal habit of ammonium nitrate (see Group III) comprises a salt of the condensation product of 1 mol. of formaldhyde and 2 mols. of a monomethylnaphthalene sulphonic acid which is soluble in a saturated aqueous ammonium nitrate solution, e.g. the sodium, potassium or ammonium salt. The condensation product may be produced by reacting formaldehyde at a temperature of 85-95 DEG C., with the crude monosulphonation reaction product obtained by reacting 1-methyl-naphthalene and/or 2-methylnaphthalene at a temperature of 40-165 DEG C., preferably 115-135 DEG C., with an excess of sulphuric acid. The formaldehyde and crude monosulphonic acid are preferably first well mixed at a temperature below that of condensation. The reaction product may be cooled, neutralized with a suitable base and evaporated to dryness. Excess acid may first be removed by the addition of barium carbonate. 2-Methylnaphthalene-8-sulphonic acid may be purified by neutralizing with barium carbonate, crystallizing the barium salt, and decomposing with sulphuric acid to reproduce the acid. Other methylnaphthalene-sulphonic acids specified are 1-methylnaphthalene - 3 -, 4 -, 5 -, 6 - and 7 - sulphonic acid and 2-methylnaphthalene-6- and 7-sulphonic acid. Examples (1), (7), (10), (11) and (15) exemplify the production of the formaldehyde condensation products, and the preparation of the naphthalene sulphonic acid used as a starting material. Specification 743,602, [Group III], is referred to.