Patent GB-943712-A (GB)
Title: Separation of a polybasic acid from its salts
IPC: C01B25/234
Filed: 1961-01-24
Abstract: A polybasic acid having a dissociation constant of at least 1 x 10-3 is separated from an aqueous solution of the acid and its salts, free from those salts which form stable metalloanionic complexes with the polybasic acid; by a process comprising contacting a column or bed of an anion exchange resin, the exchangeable ions of which are the monovalent ions common to the acid, with the aqueous acidic salt solution, which solution is at least 0.5 N with respect to the acid, and eluting the column or bed with water or a dilute aqueous solution of the acid. It is advantageous to use as eluant a dilute solution of the acid of the concentration required to maintain the monovalent ions on the exchange resin.  Specified acids are phosphoric, pyrophosphoric, glycerophcophoric, phosphorous, sulphuric, sulphurous, selenious, arsenic, oxalic, malonic, maleic and o-phthalic acids.  The salts from which the acid is separated are preferably alkali metal, alkaline earth or heavy metal salts. Particular mention is made of the separation of sulphuric acid from steel mill pickle liquors, and from transitional element sulphates, and the recovery of phosphoric acid from metal phosphatizing solutions. The process may be carried out batchwise or continuously and at atmospheric pressures and temperatures up to 90 DEG  C. Suitable anion exchange resins specified are the resinous condensation products of phenol, formaldehyde and alkylene polyamines; the nitrogen-containing resinous compounds comprising the reaction products of a primary or secondary and a halomethylated cross-linked copolymer of a monovinyl aromatic hydrocarbon and a divinyl aromatic hydrocarbon; the strongly basic quaternary ammonium anion exchange resins comprising the reaction products of a tertiary amine and a halomethylated insoluble cross-linked vinyl aromatic resin; and the sulphonium anion exchange resins made by reacting a halomethylated cross-linked copolymer of a monovinylaryl hydrocarbon and a divinylaryl hydrocarbon with a dialkyl, a dihydroxyalkyl or an alkyl hydroxy alkyl sulphide. Examples describe the separation of sulphuric acid from ferrous sulphate, nickel sulphate and sodium bisulphate, and phosphoric acid from sodium dihydrogen phosphate using Dowex I resin as the anion exchange resin. ("Dowex" is a Registered Trade Mark.)ALSO:A polybasic acid having a dissociation constant of at least 1X10-3 is separated from an equeous solution of the acid and its salts, free from those salts which form stable metallo-anionic complexes with the polybasic acid by a process comprising contacting a column or bed of an anion exchange resin, the exchangeable ions of which are the monovalent ions common to the acid, with the aqueous acidic salt solution, which solution is at least 0.5N with respect to the acid, and eluting the column or bed with water or a dilute aqueous solution of the acid.  It is advantageous to use as eluant a dilute solution of the acid of the concentration required to maintain the monovalent ions on the exchange resin.  Acids mentioned include oxalic, malonic, maleic, glycerophosphonic and o-phthalic acids.  The salts from which the acids are separated are preferably alkali metal, alkaline earth or heavy metal salts.  The process may be carried out batchwise or continuously and at atmospheric pressure and temperatures up to 90 DEG C.  Suitable anion exchange resins specified are the resinous condensation products of phenol, formaldehyde and alkylene polyamines; the nitrogen-containing resinous compounds comprising the reaction products of a primary or secondary amine and a halomethylated cross-linked copolymer of a monovinyl aromatic hydrocarbon and a divinylaryl aromatic hydrocarbon; the strongly basic quaternary ammonium anion exchange resins comprising the reaction products of a tertiary amine and a halomethylated insoluble crosslinked vinyl aromatic resin; and the sulphonium anion exchange resins made by reacting a halomethylated cross-linked copolymer of a monovinyl hydrocarbon and a divinyl hydrocarbon with a dialkyl, a dihydroxy alkyl or an alkyl hydroxyalkyl sulphide.ALSO:A polybasic acid having a dissociation constant of at least 1 X 10-3 is separated from an aqueous solution of the acid and its salts, free from those salts which form stable metalloanionic complexes with the polybasic acid, by a process comprising contacting a column or bed of an anion exchange resin, the exchangeable ions of which are the monovalent ions common to the acid, with the aqueous acidic salt solution, which solution is at least 0,5 N with respect to the acid, and eluting the column or bed with water or a dilute aqueous solution of the acid. It is advantageous to use as eluant, a dilute solution of the acid of the concentration required to maintain the monovalent ions on the exchange resin.  Specified acids are phosphoric, pyrophosphoric, glycerophosphoric, phosphorus, sulphuric, sulphurous, selenious, arsenic, oxalic, malonic, maleic and o-phthalic acids.  The salts from which the acid is separated are preferably alkali metal, alkaline earth or heavy metal salts.  Particular mention is made of the separation of sulphuric acid from steel mill pickle liquors, and from transitional element sulphates, and the recovery of phosphoric acid from metal phosphatizing solutions.  The process may be carried out batchwise or continuously and at atmospheric pressure and temperatures up to 90  DEG C.  Suitable anion exchange resins specified are the resinous condensation products of phenol, formaldehyde and alkylene polyamines; the nitrogen-containing resinous compounds comprising the reaction products of a primary or secondary amine and a halomethylated cross-linked copolymer of a monovinyl aromatic hydrocarbon and a divinylaryl aromatic hydrocarbon; the strongly basic quarternary ammonium anion exchange resins comprising the reaction products of a tertiary amine and a halomethylated insoluble crosslinked vinyl aromatic resin; and the sulphonium anion exchange resins made by reacting a halomethylated cross-linked copolymer of a monovinylaryl hydrocarbon and a divinylaryl hydrocarbon with a dialkyl, a dihydroxyalkyl or an alkyl hydroxyalkyl sulphide. Examples describe the separation of sulphuric acid from ferrous sulphate, nickel sulphate and sodium bisulphate, and phosphoric acid from sodium dihydrogen phosphate using Dowex I resin as the anion exchange resin.  ("Dowex" is a Trade Mark).