Patent GB-933683-A (GB)
IPC: C08G77/48
Abstract: 933,683. Polyurethane containing silicon. FARBENFABRIKEN BAYER A.G. May 26, 1961 [May 27, 1960; April 22, 1961], No. 19184/61. Classes 2(5) and 2(7) [Also in Group V] A process for preparing a polyurethane plastic comprises reacting a polyester or polyesteramide (having a molecular weight of at least 500, a hydroxyl number of not more than 225 and an acid number not substantially more than 10), with an organic polyisocyanate and simultaneously or subsequently with an organo-silicon compound which contains at least one group having one or more reactive hydrogen atoms as determined by the Zerewitinoff method, said group or groups being attached to a carbon atom bonded directly to a silicon atom. A cross-linking agent or chainextender such as a polyhydric alcohol or polyamine can be included in the reaction mixture. The silicon compound may be one having the average general formula RnR<SP>1</SP>mSiO 4 -n 2    in which R, which contains no aliphatic unsaturation, represents an alkyl or aryl radical or an -X-Y group; R<SP>1</SP> represents a divalent -X- radical linking together one Si atom and one O atom; at least some of the R's being hydrocarbon radicals and in the case of m=O at least one of the R's being an -X-Y group; X represents an alkylene or nitrogen-interrupted alkylene radical; Y represents an -OH, -COOH, -NH 2 , -NH(XOH), -N(XOH) 2 , or group; X<SP>1</SP> represents an alkylene radical; X<SP>11</SP> represents a hydrogen atom or an alkyl or aryl radical; n has a value from 2 to 3; m and o are zero or integers from 1-30; q is an integer from I to 300. The reactive hydrogen atom does not have to be present at the time the organo silicon compound is added to the reaction mixture. Thus Si-X-O bridges are split during reaction with the diisocyanate to form a group containing reactive hydrogen. The polyurethanes can be prepared as a millable gum by the process of Specification 700,610, a casting, as in Specification 700,608 or as a coating by the process described in Specification 722,723. A mixture of polyester with equivalent amount of polyisocyanate and one of the silicon compounds can be used as a lacquer. A mixture of polyester, silicon compound and excess polyisocyanate, mixed with cross-linking agent can be put in a mould to give a cast polyurethane. In preparing storable adducts the silicon compound can be added to a mixture which yields a hydroxyl group-containing polyurethane which is cured by adding further polyisocyanate or an organic peroxide, sulphur or formaldehyde. An organo-silicon compound having a plurality of hydroxyl groups can be used in the preparation of the polyester. Silicon containing compounds can also be added to the reaction mixture in preparing foams. In examples (1) a mixture of poly-(dimethylsilmethylene-oxane-dimethylsiloxane) copolymer and a polyester of ethylene glycol and adipic acid is reacted with naphthylene-1,5-diisocyanate. Butane-1,4-diol is stirred in and the melt is cast into moulds and heated; (2b) bis-(#,#<SP>1</SP>-dihydroxyethylaminomethylene) tetramethylsiloxane (compound A) is used as the silicon compound in a rather similar process; (3) a foamed product is prepared by mixing poly-(dimethylsilmethylene-oxane-dimethylsiloxane) copolymer and a polyester of adipic and phthalic acids and trimethylolpropane and then adding a polysiloxane polyalkylene oxide copolymer, N- methyl - tN<SP>1</SP> - (N - dimethylaminoethyl)- piperazine, aqueous sulphonated castor oil and diphenylmehane-4,4<SP>1</SP>-diisocyanate. In Examples 4 to 14 a generally similar procedure to that in Example 1 is used and the silicon compounds used have the formulae where n represents 8, 100 or 300, or where n=3 or In Example 15 a silicon compound of the first formula is reacted with naphthylene-1,5- diisocyanate. The NCO containing product is reacted with polyester and dehydrated. Naphthalene-1,5-diisocyanate and butane-1,4-diol are added and the mixture is reacted to give an elastomer. Specification 769,680 also is referred to.