Patent GB-880046-A (GB)
Title: Process for separation of thorium from uranium
IPC: C01F15/00
Filed: 1959-09-01
Abstract: Organic solvent solutions of thorium and uranyl nitrates are treated with aqueous solutions of sulphates, oxalates or bisulphates which selectively precipitate the thorium as an insoluble compound which remains in the aqueous phase, whilst leaving the uranium dissolved in the organic phase.  The initial organic solvent solution may consist of an alkyl phosphate, phosphonate or phosphinate, optionally with a hydrocarbon diluent such as heptane, hexane, octane, xylene or aliphatic petroleum fractions.  The thorium precipitant is preferably sulphuric or oxzalic acid but water soluble salts thereof such as the ammonium, alkali metal, and amine salts, or magnesium sulphate may be employed.  The uranium in the organic phase may be recovered by extraction with water or a solution of an alkali metal carbonate. The thorium extraction/precipitation may take place in countercurrent; thus the organic solution may first be treated with the theoretical amount of sulphate ion to precipitate the thorium content, followed by a second operation using the precipitant in excess, the aqueous extract from this second operation passing to the first stage. According to Examples, (1) a solution of thorium and uranyl nitrates was obtained by alkali attack on monozite followed by rare earth extraction with hydrochloric or sulphuric acid, after which thorium and uranium values were taken up with nitric acid and the resulting aqueous solution extracted with tributyl phosphate in an aliphatic diluent.  Such a nitrate solution was treated at 45 DEG -50 DEG C. with a 1M oxalic acid solution; the aqueous phase was separated and the thorium oxalate precipitate was filtered off, dried and calcined at 950-1000 DEG C. to form thorium oxide (3).  A solution of thorium, uranyl and europium nitrates in tributyl phosphate and an aliphatic diluent, was treated with sulphuric acid at 25 DEG C. and the thorium sulphate precipitate withdrawn in the aqueous phase, from which it was precipitated by cooling to 5 DEG C. and filtering. A further example relates to precipitation using an ammonium sulphate solution, which has the effect of reducing the residual contamination with europium.ALSO:Organic solvent solutions of thorium and uranyl nitrates are treated with aqueous solutions of oxalate ions thereby selectively precipitating the thorium as an oxalate which remains in the aqueous phase, whilst leaving the uranium dissolved in the organic phase.  The initial organic solvent solution may consist of an alkyl phosphate, phosphonate or phosphinate, optionally with a hydrocarbon diluent such heptane, hexane, octane, xylene or aliphatic petroleum fractions.  The thorium precipitant is preferably oxalic acid but water soluble salts thereof such as the ammonium, alkali metal, and amine salts, may be employed.  The thorium extraction precipitation may take place in countercurrent; thus the organic solution may first be treated with the theoretical amount of oxalate ion to precipitate the thorium content, followed by a second operation using the precipitant in excess, the aqueous extract from this second operation passing to the first stage.  According to Example 1, a solution of thorium and uranyl nitrates was obtained by alkali attack on monazite, followed by rare earth extraction with hydrochloric or sulphuric acid, after which the thorium and uranium values were taken up with nitric acid and the resulting aqueous solution extracted with tributyl phosphate in an aliphatic diluent. Such a nitrate solution was treated at 45 DEG -50 DEG C. with a 1M oxalic acid solution; the aqueous phase was separated and the thorium oxalate precipitate was filtered off.