Patent GB-863762-A (GB)
Title: Removal of components of liquid mixtures using solid absorbents
IPC: B01D15/04
Filed: 1959-02-09
Abstract: A process for transferring components from a liquid mixture to a solid capable of adsorbing said components, comprises passing the liquid mixture downwards through a bed of the solid while simultaneously passing downwards through the bed a stream of inert gas or vapour in an amount such that the gas or vapour withdrawn from the bed is at least ten volumes per volume of the liquid mixture, and recovering as effluent, liquid denuded of the transferred components. The passage of the liquid mixture may be discontinued before the adsorbable components appear in substantial concentration in the effluent, whereupon a second liquid is passed downwards through the bed simultaneously with an inert gas or vapour, the second liquid enriched in the previously adsorbed component is recovered as effluent, and the flow of the second liquid after the solid has been regenerated is discontinued, contacting of the solid with the liquid mixture being repeated.  An inert gas or a liquid which does not elute the absorbed component may be passed through the bed after the passage of the liquid mixture is discontinued and prior to passage of said second liquid through said bed.  The absorbent particles of diameters between 1/64th and 1/4 inch are of uniform size and have an average liquid film thickness of 0.01 to 1 times the average normal particle diameter.  The process may be employed to purify many absorbents such as activated carbon, ion-exchange resins, activated bauxite, activated alumina and molecular sieves of five Angstroms pore diameter.  Two samples of crude aqueous hydrogen peroxide solution, containing 21% hydrogen peroxide, were treated using a quaternary ammonium type resin.  The solutions had been produced by the oxidation of isopropyl alcohol with molecular oxygen and differed only slightly in carboxylic acid content.  In both cases the adsorbent was placed in a 16-inch bed of 1 inch diameter.  In one case the normal flooded bed mode of operation was used to treat a feed 0.08 N in carboxylic acids while in the other case the feed which was 0.1 N in carboxylic acids was distributed over the resin by a stream of carbon dioxide-air mixture, charged at 550 ft. per hour superficial velocity.  Acid removal before break-through achieved by utilisation of the invention, 158 milliequivalents, was 33% greater than the 119 - milliequivalent capacity obtained by flooded-bed operation.  In the application of the process to the treatment of oils, filter clays are suitable for neutralizing the acidity of acid-treated oils, while clays of the fuller's earth type, activated bauxite and activated alumina are used for decolorizing lubricating oils.  Particularly exemplified is the removal of normal paraffin constituents from a waxy 100-distillate of a mixture of East Texas and Louisiana crude oils (which distillate has been solvent-extracted to remove constituents of low-viscosity index and has a pour point of 80 DEG  F.), the distillate being treated with a five Angstrom molecular sieve zeolite of the calcium-exchanged type A.ALSO:A process for transferring components from a liquid mixture to a solid capable of adsorbing said components comprises passing the liquid mixture downwards through a bed of the solid while simultaneously passing downwards through the bed a stream of inert gas or vapour in an amount such that the gas or vapour withdrawn from the bed is at least ten volumes per volume of the liquid mixture, and recovering as effluent, liquid denuded of the transferred components.  The passage of the liquid mixture may be discontinued before the adsorbable components appear in substantial concentration in the effluent, whereupon a second liquid is passed downwards through the bed simultaneously with an inert gas or vapour, the second liquid enriched in the previously adsorbed component is recovered as effluent, and the flow of the second liquid after the solid has been regenerated is discontinued, contacting of the solid with the liquid mixture being repeated.  An inert gas or a liquid which does not elute the absorbed component may be passed through the bed after the passage of the liquid mixture is discontinued and prior to passage of said second liquid through said bed.  The absorbent particles of diameters between 1/64 th and 1/4 inch are of uniform size and have an average liquid film thickness of 0,01 to 1 times the average normal particle diameter.  The process may be employed to purify many absorbents such as activated carbon, ion-exchange resins, activated bauxite, activated alumina and molecular sieves of five Angstroms pore diameter.