Patent GB-727564-A (GB)
Title: Improvements in or relating to process for separating organic compounds
Filed: 1950-08-03
Abstract: In a process for recovering a urea adduct-forming compound from a mixture thereof with an inhibitor for urea-adduct formation and another organic compound by contacting the mixture with urea and separating the solid adduct, the urea is pretreated, in the presence of water, with an initiator for adduct formation comprising an aliphatic organic compound capable of forming a solid adduct with urea.  By this process, straight-chain organic hydrocarbons, alcohols, aldehydes, ketones, carboxylic acids, mercaptans, disulphides and esters containing 6 or more carbon atoms and monomethyl-branched chain esters having 4 or more methylene groups in the straight-chain portion of the molecule, are separated from other branched-chain and/or cyclic compounds. The feedstock may be diluted with diluents such as butane, pentane, isooctane, neohexane, benzene, toluene, xylene, cyclohexane, methylcyclohexane, ethyl ether and butyl ether.  The organic compounds may be treated in a tower reactor with urea mixed with cork, charcoal or porcelain, the urea having been pretreated with steam and with an adduct initiator such as cetane; the adduct may then be washed by passing a wash liquid, such as the diluents referred to above, through the tower. Alternatively, the organic compounds may be treated by forming a slurry with urea and filtering, or by a moving bed method.  The adduct may be decomposed by heating, by contacting with a urea solvent such as water or methanol, by heating with the washing liquid, or by stripping out the organic compound under vacuum. Part of the recovered organic compound may be recycled and may first be purified with adsorbent solids such as silica gel, clay or charcoal, or by extraction with a concentrated aqueous solution of a strong inorganic acid such as sulphuric or hydrofluoric acids, as is described in Specification 706,017, [Group III].  In the example, the treatment of gas oil is described.  Specification 671,459 also is referred to.ALSO:In a process for recovering a urea adduct-forming compound from a mixture thereof with an inhibitor for urea-adduct formation and another organic compound by contacting the mixture with urea and separating the solid adduct, the urea is pretreated, in the presence of water, with an initiator for adduct formation comprising an aliphatic organic compound capable of forming a solid adduct with urea.  By this process straight-chain organic hydrocarbons, alcohols, aldehydes, ketones, carboxylic acids, mercaptans, disulphides and esters containing six or more carbon atoms and monomethyl-branched chain esters having four or more methylene groups in the straight-chain portion of the molecule are separated from other branched-chain and/or cyclic compounds.  The feedstock may be diluted with diluents such as butane, pentane, iso-octane, neohexane, benzene, toluene, xylene, cyclohexane, methylcyclohexane, methyl ether and butyl ether.  The organic compounds may be treated in a tower reactor with urea mixed with cork, charcoal or porcelain, the urea having been pretreated with steam and with an adduct initiator such as cetane; the adduct may then be washed by passing a wash liquid, such as the diluents referred to above, through the tower. Alternatively, the organic compounds may be treated by forming a slurry with urea and filtering, or by a moving bed method.  The adduct may be decomposed by heating, by contacting with a urea solvent such as water or methanol, by heating with the washing liquid, or by stripping out the organic compound under vacuum.  Part of the recovered organic compound may be recycled and may first be purified with adsorbent solids such as silica gel, clay or charcoal, or by extraction with a concentrated aqueous solution of a strong inorganic acid such as sulphuric or hydrofluoric acids, as is described in Specification 706,017.  In the example, the treatment of gas oil is described.  Specification 671,459 also is referred to.