Patent GB-1105413-A (GB)
Title: Method and apparatus for detecting traces of substances
Inventor: BARRINGER ANTHONY RENE
IPC: G01J3/12
Filed: 1964-10-16
Abstract: 1,105,413. Photo-electric spectrometers. BARRINGER RESEARCH Ltd. Oct. 14, 1965 [Oct. 16, 1964], No. 42416/64. Heading G1A. The presence in a quantity of matter of a substance, having an absorption line at a characteristic wavelength with a characteristic linewidth, is detected (and the amount of it in the quantity of matter may be determined) by photo-electrically measuring the absorption of a beam of electromagnetic energy passing through the matter and filtered so as to contain only energy components centred on and immediately adjacent the characteristic wavelength of the substance, the absorption of the beam at the absorption linewidth being compared with that outside the absorption linewidth. The embodiment described relates to a spectrophotometer designed to measure the weight of minute quantities of mercury in a substance and to avoid measurement errors introduced by interfering substances with a broad absorption bandwidth e.g. benzene, which tend to mask the mercury line. Light from a mercury vapour lamp 10 (Fig. 1), is caused to emit light with a deliberately broadened linewidth (of about 0.1 Š) about the characteristic absorption wavelength (of linewidth about 0.05 Š) by maintaining it at a temperature of 100‹C. The beam passes into the absorption chamber 11 where it is reflected back and forth between curved and plane mirrors 15, 16 before leaving the chamber. An interference filter 21 eliminates all emission lines other than the broadened mercury line, from the beam. A half-silvered mirror 22 directs part of the beam towards a first photo-multiplier 12 while the rest is transmitted to an optical filter 13 containing dense mercury vapour. This absorbs the central portion of the emission line, leaving only two sidebands on either side of the absorption wavelength, which are submitted to a second photomultiplier 14 which acts as a reference since the sidebands should be generally unaffected by any absorption by mercury present in the absorption chamber 11. When there is mercury in the chamber the absorption of the emission line at the absorption wavelength results in a reduction in the output of the photo-multiplier 12. In operation, the outputs of the photo-multipliers 12, 14 are made equal when there is no mercury in the absorption chamber. Mercury is obtained from the sample by heating the latter in a sample cell (46). A special controllable air pumping system Fig. 6 (not shown) is used to pass the mercury vapour mixed with air at a known dilution, through the absorption chamber (11). At any time, the density of the mercury in the chamber is obtainable by switching a readout meter (35) to read the output of a differential amplifier (29) connected to the photo-multiplier outputs Fig. 3, (not shown). The total weight of mercury emitted from the sample after a particular time is read from the output of an integrator (30) which follows the differential amplifier (29). When the weight has reached a predetermined level a scaler (32) advances one count to indicate this and resets the integrator. The final increase in weight is read on the meter (35). The sensitivity of the apparatus can be increased by a range selector (42). The effect of interfering substances is to absorb equally at the central and side portions of the emission line, but as it is required that the reference photomultiplier output remains constant, it is continously compared with a reference signal level and the high voltage supply to both photo-multipliers is varied accordingly. A meter (40) indicates the variation of the high voltage supplied by the interference compensator (39). Calibration of the spectrophotometer is effected by passing a known weight of mercury through the absorption chamber and the final reading of scaler and meter (35) obtained. It is stated that the invention could be applied to investigation of liquid or solid samples and that radiation in other parts of the electromagnetic spectrum besides u.v., visible and i.r. e.g. X-rays or micro-waves may be used. Distribution of elements in the earth's or moon's atmosphere may be investigated, using the sun as source.