Patent GB-1027813-A (GB)
Title: A process for the deposition of pigmented resinous films on metal objects
Inventor: GENTLES JAMES KEITH
IPC: C09D5/44
Filed: 1962-02-27
Abstract: Metal particles are coated electro-phoretically using a dispersion of pigmented resin, and made by first incorporating a pigment into a resin containing free acid groups, and then dispersing it in an aqueous medium containing a base, e.g. ammonia, triethanolamine, or alkali metal hydroxide, preferably present in excess of the amount to neutralise the acid groups.  As resins containing acid groups, these may be used alkyd, or acrylic type resins may be co-polymers e.g. a copolymer of acrylamide, an alkyl acrylate, acrylic, or methacrylic acid with styrene or vinyl toluene.  The coating is finally stored at 140 DEG  to 200 DEG C. for 30 to 60 minutes.  The resin coating is improved at the storing stage by adding pine oil or other resins to render the coating more flowable e.g. alkoxymethyl amino-plast-condensation products such as methoxy methyl melamine ether, or methoxy methyl benzo guanamine ether.  Viscosity reducers may also be added e.g. as non-ionic condensation product of nonyl phenol and ethylene oxide.  In examples the following components were heated together to form the resin component (1) acrylamide, methacrylic acid, butyl acrylate and styrene, which may mixed with butylated melamine formaldehyde resin, (2) trimellitic anhydride, propylene glycol, and linseed oil fatty acids.  This resin is then ground with finely powdered TiO2 and butanol and mixed with a high speed stirrer with water containing ammonia to form the coating medium.  This is applied at 60-250V and at C.D. up to 4 A.S. inch the coated surface being the anode.  The coating is finally stoved.ALSO:A coating composition for coating articles electrophoretically consists of an aqueous dispersion of a pigmented synthetic resin, made by first incorporating a pigment into a resin containing free acid groups, and then dispersing it in an aqueous medium containing a base, e.g. ammonia, triethanolamine or sodium hydroxide. The resin may be alkyd, or acrylic type resins used as such or copolymerized with styrene or vinyl toluene, and may then be blended with other alkoxy-methyl amino-plast condensation products which render the coating more flowable. In examples, the following components were heated together (1) linseed oil fatty acids, propylene glycol or glycerol, and trimellitic anhydride, with butyl carbitol as solvent, (2) acryl amide, ethyl acrylate, acrylic or methacrylic acid, and styrene or vinyl toluene; this copolymer may be further treated with formaldehyde and triethylamine as catalyst, thus introducing N-methylol groups into the polymer, (3) acryl amide, methacrylic acid, butyl acrylate, styrene, di-tertiary butyl peroxide, and tertiary dodecyl mercaptan, with butanol as solvent.  The products may be blended with methoxy methyl melamine ether, alkoxy-methyl urea ether, or methoxy methyl benzo-guanamine ether.  The resin is ground with TiO2 or other pigment, and butanol and mixed with water containing ammonia or an organic base in a high-speed stirrer. Viscosity reducers e.g. pine oil, or a non-ionic condensation product of nonyl phenyl ether and ethylene oxide.  The coated article is then stoved at 140 DEG  to 200 DEG  C.