Patent EP-1969934-A1 (EP)
IPC: C07C217/90
Filed: 2007-03-12
Abstract: The 4-cycloallkyl or 4-aryl substituted phenoxyphenylamidine has general formula (I). The 4-cycloallkyl or 4-aryl substituted phenoxyphenylamidine having general formula (I), is new. R 1>H, mercapto or methyl linear or branched 1-8C alkyl, 1-12C alkyl, 2-12C alkenyl, 2-12C alkinyl, cyclic 3-8C alkyl, 4-8C alkenyl or 4-8C alkinyl, where single or multiple carbons are replaced with heteroatoms selected from N, O, P or S in ring system of all cyclic groups, which is selected from -R', -X, -OR', -NR' 2, SR', -SiR' 3, -COOR', CN or -CONR' 2, where R'=H or 1-12C alkyl, -SH, -SR 1>3, where R 1>3=1-12C alkyl; R 2>methyl or ethyl, linear or branched 2-8C alkyl, 1-12C alkyl, 2-12C alkenyl, 2-12C alkinyl, cyclic 3-8C alkyl, 4-8C alkenyl, 4-8C alkinyl, 5-18C aryl, 7-19C arylalkyl or 7-19C alkaryl, where single or multiple carbons are replaced with heteroatoms selected from N, O, P or S in ring system of all cyclic groups, which is selected from -R', -X, -OR', -NR', -SR', -SiR' 3, -COOR', CN or -CONR' 2, where R'=H or 1-12C alkyl; R 3>-CN, -SH, -SR 1>3, -OR', -(C=O)-R 1>3, ethyl or cyclopropyl, linear or branched 2-8C alkyl, 2-12C alkyl, 2-12C alkenyl, 2-12C alkinyl, 3-8C alkyl, 4-8C alkenyl, 4-8C alkinyl, 5-18C aryl, 7-19C arylalkyl or 7-19C alkaryl, where single or multiple carbons are replaced with heteroatoms selected from N, O, P or S in ring system of all cyclic groups, which is selected from -R', -X, -OR', -NR' 2, SR', -SiR' 3, -COOR', CN or -CONR' 2; R 4> and R 5>H, -X, -CN, -SH, -SR 1>3, -(C=O)-R 1>3, -CF 3, -CF 2H, or methyl, linear or branched 1-12C alkyl, 2-12C alkenyl, 2-12C alkinyl, haloalkyl, 3-8C alkyl, 4-8C alkenyl, 4-8C alkinyl, 5-18C aryl, 7-19C arylalkyl or 7-19C alkaryl, where single or multiple carbons are replaced with heteroatoms selected from N, O, P and S in the ring system of all cyclic groups, which is selected from -R' , -X, -OR'; R 6>H, halogen atom or 1-6C haloalkyl, fluoro, chloro, bromo. -CF 3 or -CHF 2; and R 7>phenyl, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl or cyclooctyl, 4-chlorophenyl, 4-ethylsulfonylphenyl, 4-trifluoromethylphenyl, 4-dimethylaminophenyl, 4-methoxyphenyl, 4-tert-butylphenyl, 4-acetylphenyl, 4-fluorophenyl, 2-ethylphenyl, 2-trifluoromethylphenyl, 2-isopropylphenyl, 2-methylphenyl, 2-fluorophenyl, 2-acetylphenyl, 2-methoxyphenyl, 2-chlorophenyl, 2(2-methylpropoxy)-phenyl, acyclic 3-12C alkyl, 4-12C alkenyl, 4-12C alkinyl, or 5-18C aryl, 7-19C arylalkyl or 7-19C alkaryl, where single or multiple carbons are replaced with heteroatoms selected from N, O, P or S in ring system of all cyclic groups, which is selected from -R', -X, -OR', -NR', -SR', -SiR' 3, -COOR', CN or -CONR' 2. Independent claims are included for: (1) a method for preparing 4-cycloallkyl or 4-aryl substituted phenoxyphenylamidines; (2) a method for protecting seeds from unwanted microorganisms, which involves treating of seeds with a 4-cycloallkyl or 4-aryl substituted phenoxyphenylamidines; and (3) a method for preventing undesired microorganisms, which involves applying 4-cycloallkyl or 4-aryl substituted phenoxyphenylamidines to the microorganisms or habitat. [Image] ACTIVITY : Fungicide. MECHANISM OF ACTION : None given.