Patent EA-001106-B1 (EA)
Title: Fungicide mixture.
Inventor: MULLER BERND
IPC: A01N47/38
Filed: 1997-04-23
Abstract: 1. A fungicidal composition comprising  a) a carbamate of the formula I   where T is CH or N, n is 0, 1 or 2 and R is halogen, C1-C4-alkyl or C1-C4-haloalkyl, it being possible for the radicals R to be different when n is 2, and at least one of compounds from groups b)-d: b) an oxime ether of the formula II   where the substituents have the following meaning: X is oxygen or amino group (NH); Y is CH or N;  Z is oxygen, sulfur, amino group (NH) or C1-C4alkylamino group (N-C1-C4 alkyl); R' is C1-C6alkyl, C1-C6 haloalkyl, C3-C6 alkenyl, C2-C6 haloalkenyl, C3-C6 alkynyl, C3-C6 haloalkynyl, C3-C6 cycloalkylmethyl, or benzyl which may be partially or fully halogenated and/or may carry one to three residues selected from the following: cyano group, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy-, C1-C4 haloalkoxy- and C1-C4 alkylthio group; and  c.1) oxime ether carboxylic ester of formula IIIa    c.2) oxime ether carboxylic acid amide of formula IIIb   c.3) methoxyacrylic acid ester of formula IIIc   and/or d) an azole derivative IV, selected from the group of compounds IV.1-IV.17: 1-[(2RS,4RS; 2RS,4SR)-4-bromo-2-(2,4-dichlorophenyl)tetrahydrofuryl]-lH-1,2,4-triazol (IV.1), 2-(4-chlorophenyl)-3-cyclopropyl-1-(lH-1,2,4-triazol-1-yl)-butan-2-ol (IV.2), (+-)-4-chloro-4-[4-methyl-2-(lH-1,2,4-triazol-1-ylmethyl)-1,3-dioxolan-2-yl]phenyl-4-chlorophenyl ether (IV.3), (E)-(R,S)-1-(2,4-dichlorophenyl)-4,4-dimethyl-2-(1H-1,2,4-triazol-l-yl)-pent-l-en-3-ol (IV.4), (Z)-2-(1H-1,2,4-triazol-l-ylmethyl)-2-(4-fluorophenyl)-3-(2-chlorophenyl)oxiran (IV.5), 4-(4-chlorophenyl)-2-phenyl-2-(1H-1,2,4-triazolylmethyl)butyronitril (IV.6), 3-(2,4-dichlorophenyl)-6-fluoro-2-(lH-1,2,4-triazol-1-yl)chinazolin-4(3H)on (IV.7), Bis(4-fluorophenyl)(methyl)(lH-1,2,4-triazol-1-ylmethyl)silan (IV.8), (R,S)-2-(2,4-dichlorophenyl)-l-(lH-1,2,4-triazol-1-yl)hexan-2-ol (IV.9), (1RS,5RS;1RS,5SR)-5-(4-chlorobenzyl)-2,2-dimethyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol (IV.10), N-propyl-N-[2-(2,4,6-trichlorophenoxy)ethyl]imidazol-1-carboxamid (IV.11), (+-)-1-[2-(2,4-dichlorophenyl)-4-propyl-1,3-dioxolan-2-ylmethyl]-1H-l,2,4-triazol (IV.12), (R,S)-1-(4-chlorophenyl)-4,4-dimethyl-3-(lH-1,2,4-triazol-1-ylmethyl)pentan-3-ol (IV.13), (+-)-2-(2,4-dichlorophenyl)-3-(lH-1,2,4-triazolyl)propyl-1,1,2,2-tetrafluoroethyl ether (IV.14), (E)-1-[1-[[4-chloro-2-(trifluoromethyl)phenyl]imino]-2-propoxyethyl]-lH-imidazol (IV.15), (RS)-2,4'-difluoro-α-(lH-1,2,4-triazol-1-ylmethyl)benzhydroyl alkohol (IV.16), 2-p-chlorophenyl-2-(1H-1,2,4-triazol-1-ylmethyl)hexanenitril (IV.17) in  synergistically active amount. 2. A fungicidal composition as claimed in claim 1, comprising a compound of formula IIIa. 3. A fungicidal composition as claimed in claim 1, comprising a compound of formula IIIb. 4. A fungicidal composition as claimed in claim 1, comprising a compound of formula IIIc. 5. A fungicidal composition as claimed in claim 1, comprising one or more azole derivatives IV.1, IV.4, IV.5 and/or IV.10. 6. A method of controlling harmful fungi, which comprises treating the harmful fungi, their environment, or the plants, seeds, soils, areas, materials or spaces to be kept free from fungal infection with a compound of formula I as claimed in claim 1 and a compositions of formulas II, III and/or IV as claimed in claim 1. 7. The method defined in claim 6, wherein harmful fungi, their environment, or the plants, seeds, soils, areas, materials or spaces to be kept free from fungal infection are treated with a compound of formula I as claimed in claim 1 in the amount of from 0.005 to 0.5 kg/ha.