Patent GB-1089998-A (GB)
Title: Improvements in and relating to concentrates containing active oxygen
IPC: C11D3/39
Filed: 1964-12-31
Abstract: Detergent compositions comprise liquid aqueous concentrate containing active oxygen, that is aqueous solutions containing 3 to 90% by weight of hydrogen peroxide, and as a stabilizer, at least one surface active amine oxide having the general formula <FORM:1089998/C4-C5/1> in which R1 represents a saturated alkyl group containing 6-20 carbon atoms, X is an oxygen or sulphur atom, R2 is an ethylene, propylene, or hydroxy propylene residue, n=0, or an integer in the range 1 to 18; R3 represents a group containing at least 3 carbon atoms which may be substituted by hydroxyl groups, R4 and R5 each represent a saturated alkyl or alkoxy group containing at most 5 carbon atoms. Preferred values are n=0 or 1 to 10, R3 is 3 or 4 carbon atoms and the groups R4 and R5 contain at most 3 carbon atoms.  The pH of the concentrate is preferably greater than 1 and may be in the range 3 to 8.  The preferred peroxide content is 10 to 70% most preferably 10 to 40% by weight and the peroxide may be present wholly or partly as its adducts with urea, melamine, alkali metal borates, alkali metal ortho- or polyphosphates dissolved or suspended in water.  The concentration of the amine oxide present preferably lies in the range 2 to 40% by weight and the quantity of stabilizer may constitute 10-200% by weight referred to the hydrogen peroxide content in free or combined form.  The composition may contain other known stabilizers. The amine oxide exemplified is <FORM:1089998/C4-C5/2> (alkyl from coconut fatty acid) and the composition may be employed in cleaning and bleaching of textiles, bleaching human hair, permanent waving, and other cosmetic treatments.ALSO:A liquid aqueous concentrate containing active oxygen, that is aqueous solutions containing 3 to 90% by weight of hydrogen peroxide, contain as a stabilizer at least one surface-active amine oxide having the general formula <FORM:1089998/C1/1> in which R1 represents a saturated alkyl group containing 6-20 carbon atoms, X is an oxygen or sulphur atom, R2 is an ethylene, propylene, or hydroxy propylene residue, n=0, or an integer in the range 1 to 18; R3 represents a group containing at least 3 carbon atoms which may be substituted by hydroxyl groups, R4 and R5 each represent a saturated alkyl or alkoxy group containing at most 5 carbon atoms.  Preferred values are n=0 or 1 to 10, R3 is 3 or 4 carbon atoms and the groups R4 and R5 contain at most 3 carbon atoms.  The pH of the concentrate is preferably greater than 1 and may be in the range 3 to 8.  The preferred peroxide content is 10 to 70% most preferably 10 to 40% by weight, and the peroxide may be present wholly or partly as its adducts with urea, melamine, alkali metal borates, alkali metal ortho or polyphosphates dissolved or suspended in water.  The concentration of the amine oxide present preferably lies in the range 2 to 40% by weight and the quantity of stabilizer may constitute 10-200% by weight referred to the hydrogen peroxide content in free or combined form.  The composition may contain other known stabilizers.  The amine oxide exemplified is <FORM:1089998/C1/2> (alkyl from coconut fatty acid) and the composition may be employed in cleaning and bleaching of textiles, bleaching human hair, permanent waving, and other cosmetic treatments.ALSO:A liquid aqueous concentrate containing active oxygen, that is aqueous solutions containing 3 to 90% by weight of hydrogen peroxide, contain as a stabiliser at least one surface active amine oxide having the general formula <FORM:1089998/D1-D2/1> in which, R1 represents a saturated alkyl group containing 6-20 carbon atoms, X is an oxygen or sulphur atom, R2 is an ethylene, propylene, or hydroxy propylene residue, n=O, or an integer in the range 1 to 18; R3 represents a group containing at least 3 carbon atoms which may be substituted by hydroxyl groups, R4 and R5 each represent a saturated alkyl or alkoxy group containing at most 5 carbon atoms. Preferred values are n=0 or 1 to 10, R3 is 3 or 4 carbon atoms and the groups R4 and R5 contain at most 3 carbon atoms. The pH of the concentrate is preferably greater than 1 and may be in the range 3 to 8.  The preferred peroxide content is 10 to 70% most preferably 10 to 40% by weight and the peroxide may be present wholly or partly as its adducts with urea, melamine, alkali metal borates, alkali metal ortho or polyphosphates dissolved or suspended in water. The concentration of the amine oxide present preferably lies in the range 2 to 40% by weight and the quantity of stabiliser may constitute 10-200% by weight referred to the hydrogen peroxide content in free or combined form.  The composition may contain other known stabilisers.  The amine oxide exemplified is <FORM:1089998/D1-D2/2> (alkyl from coconut fatty acid) and the composition may be employed in cleaning and bleaching of textiles, bleaching human hair, permanent waving, and other cosmetic treatments.