Patent GB-990111-A (GB)
Title: Fungicidal compositions
Inventor: LAMBIE ALAN JAMES
IPC: D06M13/35
Filed: 1960-05-07
Abstract: The invention comprises reaction products of maleic acid and maleic anhydride and the salts formed with metals and ammonia of <FORM:0990111/C2/1> wherein R1, R2, R3 and R4 are hydrogen, halogen, alkyl, alkoxy or nitro and X is hydrogen. Specified salts are the lithium, sodium, calcium and basic copper salts. The invention also comprises the following compounds (given with their methods of preparation).  (1) methyl beta - 2 - (41,51,61,71 - tetrachlorobenzotriazolyl)-butyrate from beta - 2 - (41,51,61,71 - tetrachlorobenzotriazolyl) - butyric acid and diazomethane; (2) N-(N1,N1-diethylcarboxyamido methyl) - 4,5,6,7 - tetrachlorobenzotriazole from N1,N1 - diethylchloroacetamide and 4,5,6,7-tetrachlorobenzotriazole sodium salt; (3) N-carbethoxy -4,5,6,7 - tetrachlorobenzotriazole from ethyl chloroformate and 4,5,6,7-tetrachlorobenzotriazole sodium salt; (4) N-methoxy methyl - 4,5,6,7 - tetrachlorobenzotriazole from chloro dimethyl ether and 4,5,6,7-tetrachlorobenzotriazole sodium salt; (5) N-dimethylcarbomoyl-, N-methyl carbamoylmethyl, N-(alpha - acetomorpholido) -, N - benzotriazolylmethyl - and N - carbamoyl methyl-, 4,5,6,7-tetrachlorobenzotriazole from 4,5,6,7 - tetrachlorobenzotriazole sodium salt and respectively dimethyl carbamoyl chloride, N-methyl chloracetamide, alpha - chloroacetomorpholide, 1-chloromethylbenzotriazole and chloracetamide; (6) 4,5,7 - trichlorobenzotriazole from 5,6 - diamino - 1,2,4 - trichlorobenzene by diazotization and ring closure; (7) 6-chloro-5-methoxy benzotriazole from 5-methoxybenzotriazole and chlorine (4,5,6 - trichlorobenzotriazole is prepared similarly); and (8) N - methoxy carbonyl methyl - 4,5,6,7 - tetrachlorobenzotriazole from methyl chloroacetate and 4,5,6,7: tetrachlorobenzotriazole sodium salt.ALSO:A white lead base gloss paint contains 4,5,6,7-tetrachlorobenzotriazole to protect it against fungal attack.ALSO:A fungicidal composition comprises as active ingredient: <FORM:0990111/A5-A6/1> wherein R1, R2, R3 and R4 may be the same or different and are hydrogen, halogen, alkyl, alkoxy or nitro radicals, wherein R5 is hydrogen; an alkyl group; a substituted alkyl group; an acetyl group; a group of the formula -COR6, wherein R6 is a hydroxy, alkoxy, aryloxy, aralkoxy, amino, alkylamino, dialkylamino or disubstituted amino wherein the two N substituents are joined in a ring, group, e.g. to form a morpholine group; or the cation of a salt formed with metals, ammonia or amines or which contains as the active ingredient the reaction product of maleic acid or anhydride, with a of the above formula, or substituted derivatives thereof as defined, and a surface-active agent and/or solid diluent. Specified substituted alkyl groups R5 are -(CH2)n.COR6, -CH(CH2.COR7).COR6 or -CH(CH3).CH2.COR6, wherein R6 and R7 are as specified for R6 above and n = 1 to 3, benzotriazolylmethyl, hydroxymethyl, chloromethyl, carboxyalkyl. The compositions or the active ingredients thereof may be used to treat plants, wood, paper, fabrics, wool, cotton, linen, synthetic fibres, plastics, sacking jute, paints, varnishes, adhesives, plaster, and glues to protect them against fungal attack. These materials may be sprayed, coated or dipped in liquid compositions containing the active ingredients or the active ingredients may be incorporated therein during manufacture.  The compositions may be in the form of emulsions, emulsifiable concentrates, solutions, dispersions, suspensions, wettable powders and dusts and may contain anionic, nonionic or cationic surface-active agents, stickers, fertilizers and other fungicides, e.g. sulphur, T.M.T.D., nickel hydroxide, copper oxide and copper oxychloride.