Patent GB-1225032-A (GB)
Title: Ultrasonic acoustical analysis
IPC: G01N29/02
Filed: 1968-03-05
Abstract: 1,225,032. Acoustic analysis of fluids; phase comparators; piezoelectric transducers. MICROTEK INSTRUMENTS CORP. 5 March, 1968 [31 March, 1967], No. 10599/68. Headings H3A, H4D and H4J. A sound cell for use in the analysis of fluids comprises a cavity for containing a fluid, a pair of piezoelectric transducers disposed spaced apart in the cavity with their active faces facing each other, and transducer holding means including sharp-edged lips for making substantially linear contact with the active faces of the transducers. The invention is applicable to analysis of liquids or gases, e.g. the pseudobinary gas effluent of a chromatograph column. In the embodiment described a sound cell 10 (Fig. 2) comprises two piezoelectric transducers 20, 21 sprung against sharp-edged lips 28 of mounts 24 forming extensions of members 15, 16 which seal off cavity 14 in body 11. One transducer acts as an acoustic transmitter and the other as a receiver. The fluid to be analysed enters cell 10 through port 12 and flows through the cell symmetrically (to cancel out Doppler effects) via passages 30, 31, 32, 33, 34 to outlet 13. The cell may be used at elevated temperatures and pressures. Constructional details are given. For analysis of a chromatograph column sample comprising a carrier gas and an unknown gas component two sound cells are used, one containing the sample and the other containing the carrier alone. Sound velocity (and hence gas composition) is determined in the two cells either (a) by the "sing-around" method in which reception of a transmitted pulse triggers a subsequent transmission and the resulting pulse repetition frequency is determined or (b) by comparing the relative phases of transmitted and received continuous wave signals in the two cells. Phase stability is ensured by the particular transducer mounting, and by maintaining the sound cells, an oscillator for driving the transmitters, and preamplifiers for the receivers, in constant-temperature electrically-screened enclosures, details of which are given (Fig. 1, not shown). Phase comparison (Figs. 5 and 6).-Selector switch 205 enables any two of the three signals constituted by the transmitter drive oscillator 200 output, the receiver output of one cell and the receiver output of the second cell to be passed to channels 1 and 2 for phase comparison. A record of the relative amplitudes of the two signals may also be made to assist analysis. For gas analysis the signal frequency may be in the megahertz range and is then first changed to the kilohertz range in mixers 220, 221 supplied with a signal from stable beat frequency oscilator 211. The mixer outputs are squared by Schmitt trigger circuits 226, 227 and then differentiated to provide negative pulses occurring once in each square wave cycle. A bi-stable circuit 228 is triggered "on" by the negative pulses of one channel and "off" by those of the other channel, so that its mark/space ratio is proportional to the interchannel phase difference. The bi-stable output is averaged to provide D.C. voltages at 229, 230 which respectively increase and decrease linearly with phase difference as the difference proceeds from zero to 360 degrees and which exhibit a discontinuity (i.e. a jump to or from zero) once in each complete 360 degrees cycle of phase. For measuring time-varying phase shifts greater than 360 degrees, the discontinuities in a selected one of the D.C. voltages at 229, 230 are detected by means of phase-inverting amplifiers 241, 242, low-pass filters 243, 244 and differentiators 245, 246, which drive bidirectional counter 247 such that at any time the count is equal to the number of complete cycles of phase. An analogue D.C. voltage proportional to the count is derived by unit 248 and added in unit 239 to the selected voltage from 229 or 230. The sum voltage thus represents the total phase shift and is applied via switched-gain amplifier 250 and attenuator 266, 267, 261 to strip recorder 280. Switch 235 permits polarity selection so that the recorder response is unidirectional irrespective of whether the phase shift represents a lag or a lead. Phase delays 212, 213 allow a predetermined phase offset between channels 1 and 2 to prevent jitter around the 0 degrees phase position.