Patent GB-600310-A (GB)
Title: Improvements in and relating to photographs and to sensitive photographic materials
IPC: G03C1/76
Filed: 1944-04-26
Abstract: 6 0 0,3 1 0. Compound sheet materials. KODAK, Ltd. (Eastman Kodak Co., Murray, A., Hanson, W. T., Evans, R. M., and Glassey, C. Q.). April 26, 1944, No. 7756. [Class 140] [Also in Group XX] Compound sheet material comprises a light-diffusing layer and a transparent layer between which is arranged a continuous or approximately continuous layer of air, having a thickness between .00005 inch and .005 inch, preferably not exceeding .001 inch. The light-diffusing layer and the transparent layer may be secured together at occasional points. The light-diffusing layer may be a transparent material having the light-diffusing medium in optical contact with the rear face thereof or distributed therethrough. The transparent layer may comprise two or more strata of different refractive indices. The cemented points may be distributed according to a half-tone screen or irregular textile pattern or in parallel lines. The occasional contact areas may be relief spots on the transparent support, and a thin interlayer may be used in this case. The light-diffusing layer may be cemented to the bottom of the transparent layer. As shown in Fig. 18, adhesive 52 picked up by a drum 53 is applied to the tops of relief areas 54 on the drum 55 and thence to a transparent pellicle 45 held in contact therewith by a roller 56. The pellicle 45 with the adhesive spots 44 is pressed into contact with a layer 43 by passage through rollers 57. Adhesive spots in flexible thermoplastic material or synthetic resin may be dried and adhesion effected, e.g. between a paper or lightdiffusing film support and a multicolour transparency by passage between heated rollers. Adhesion between a white reflecting support of paper, white plastic sheet, translucent glass, porcelain, or enamelled metal, and a transparent layer of regenerated cellulose, synthetic or natural plastic, or gelatin is provided by adhesive spots of glue, gelatin, casein, pitch wax, natural or synthetic resins or gums, rubber, or cellulose ester (which may be plasticised with glycerol, glycols, polyglycerols, oils, soft resins or pitches, tricresyl phosphate, or isoamyl phthalate) applied to either or both sheets by photo-mechanical printing (including offsetting) or by spraying. The drops may be formed by application to a sheet with a high wetting angle, or may be in the form of globules dispersed in a liquid in which the continuous phase containing colloid dries to a much thinner layer than the globules. Sets of contact spots (adhesive spots or relief areas) out of register may be provided on opposite sides of a central transparent film, and a thin transparent layer is secured on each side. As shown in Fig. 24, adhesive spots 44 are deposited on opposite sides of a transparent film 45 by intaglio printing rolls 66 dipping in wells 67 and wiped by brushes 68. Dry-mounting adhesive may be used, and the films, 43 joined therewith on opposite sides by heat under pressure. Films with relief areas may be secured to an inner transparent layer, or the relief areas of one film may be secured to the underside of another film with relief areas, and these latter secured to a plain transparent film. The air space may also comprise a hardened foam layer containing flattened cells, which may be formed of a transparent plastic such as a resin or of a dispersed colloid or rubber and may contain any gas such as air or vapour. The liquid foam may be coated on a transparent or light-diffusing film or on paper, and then dried. With rubber an oil solvent may be used and sulphur added to effect vulcanisation. Melted colloids or plastics may be used. Pressure may be applied to flatten the bubbles. A paper base may be first coated with a transparent layer, then with a foam layer, and then with a further transparent layer. Coating apparatus is described. The air space may also comprise a porous fibrous layer, e.g. of coarse paper or plastic fibres, which may be arranged between two transparent layers. Coating apparatus is described for successively applying adhesive and curved paper or plastic fibres to sheet material, and then pressing adhesive-coated sheet material in contact therewith. Either sheet material may be light-diffusing or both may be transparent. A light-diffusing support such as paper having large fibres extending from its surface may be attached by adhesive to a transparent layer.