Patent GB-1123490-A (GB)
Title: Germicidal detergent compositions
IPC: C11D3/48
Filed: 1966-07-20
Abstract: Biodegradable, water-miscible, polyethers, which are mixed with elemental iodine to form germicidal detergents, have the formula: R0-A-X-(MH)a wherein R0 is H or X(MH)a, A is a straight chain C8- 22 hydrocarbyl radical, X is O, S, <FORM:1123490/C3/1> NH, NR, N, PO4, SO3NH, SO3NR, SO3N, SNH, SNR, or SN, a is 1 when X is O, S, <FORM:1123490/C3/2> NH, NR, PO4, SO3NR, SNH or SNR and a is 2 when X is <FORM:1123490/C3/3> N, SO3N, or SN, R is C1- 4 alkyl and M is R1R11 in which each of R1 and R11 is oxyethylene or oxypropylene, or mixtures of oxyethylene and oxypropylene groups, providing that oxyethylene and oxypropylene groups are present in M, the total weight ratio of oxyethylene to oxypropylene in M being from 1.3:1 to 15:1 and M constituting from 55 to 80 weight percent of the polyether.  They are prepared by a two-step reaction which comprises (1) the condensation acid, amide, amine, orthophosphate, sulphonamide, thioamide, or mixtures thereof, with ethylene oxide, or propylene oxide, or a mixture of ethylene oxide and propylene oxide having an ethylene oxide to propylene oxide weight ratio of at least 1, or a propylene oxide to ethylene oxide weight ratio of at least 1, followed by (2) the condensation of the product from (1), with ethylene oxide, or propylene oxide, or a mixture of ethylene oxide and propylene oxide having an ethylene oxide to propylene oxide weight ratio of at least 1, or a propylene oxide to ethylene oxide weight ratio of at least 1.  The polyethers may have a "block" and/or "heteric" structure.  The condensation is generally carried out in the presence of an alkaline catalyst at elevated temperature and pressure.  The compositions, which contain 0.01 to 0.5 parts of iodine per part of polyether, are used in aqueous acid form and may contain stabilizers, e.g. ethanol, isopropanol and surfactants such as the polyether.ALSO:A germicidal detergent composition comprises elemental iodine and a biodegradable, water-miscible, non-ionic surfactant of the formula: Ro-A-X-(MH)a, wherein Ro is H or X(MH)a, A is a C8-22 straight chain hydrocarbon radical, X is O, S, <FORM:1123490/C4-C5/1> NH, NR, N, PO4, SO3NH, SO3NR, SO3N, SNH, SNR or SN, a is 1 when X is O, S, <FORM:1123490/C4-C5/2> and is 2 when X is C-N, N, SO3N, or SN, R is C1-4 alkyl and M is R1R11 in which each of R1 and R11 is oxypropylene or oxyethylene or mixtures of oxyethylene and oxypropylene groups providing that oxyethylene and oxypropylene groups are present in M, the total wt. ratio of oxyethylene to oxypropylene in M being from 1.3:1 to 15:1, and M constituting from 55 to 80% by wt. of the total surfactant. The compositions may be aqueous, acidic and contain stabilizing agents, e.g. a biodegradable surfactant or alcohols.ALSO:A germicidal detergent composition comprises elemental iodine and a biodegradable, water-miscible, non-ionic surfactant of the formula: R DEG -A-X-(MH)a wherein R DEG  is H or X(MH)a, A is a C8-22 straight chain hydrocarbon radical, X is O, S, <FORM:1123490/A5-A6/1> , <FORM:1123490/A5-A6/2> , NH, NR, N, PO4, SO3NH, SO3NR, SO3N, SNH, SNR, or SN, a is 1 when X is O, S, <FORM:1123490/A5-A6/3> , NH, NR, PO4, SO3NH, SO3NR, SNH, or SNR, and is 2 when X is <FORM:1123490/A5-A6/4> , N, SO3N, or SN, R is C1-4 alkyl, and M is R1R11 in which each of R1 and R11 is oxypropylene or oxyethylene or mixtures of oxyethylene and oxypropylene groups providing that oxyethylene and oxypropylene groups are present in M, the total weight ratio of oxyethylene to oxypropylene in M being from 1.3:1 to 15:1, and M constituting from 55 to 80 wt.% of the total surfactant. The compositions may contain stabilising agents e.g. a biodegradable surfactant or alcohols, appropriate acids to give a desired pH, and water.