Patent EA-004991-B1 (EA)
Title: High pressure extraction
Inventor: NICKLIN DONALD JAMES
IPC: B01J19/24
Filed: 2002-06-04
Abstract: 1. A process arrangement for treating one or more materials, the arrangement comprising one or more vessels located beneath a surface of the ground, the one or more vessels adapted to receive the one or more materials or part thereof, the one or more vessels including a reaction zone, entry means for feeding at least one of the materials to the reaction zone and exit means for retrieving treated material from the reaction zone, wherein: at least one vessel extends to a depth below the surface sufficient to generate pressure from a hydrostatic head in the entry and/or exit means and the entry means comprises at least two tubes. 2. The process arrangement of claim 1 further comprising two or more vessels located beneath a surface of the ground, each vessel adapted to receive at least one material, the vessels each including a reaction zone, entry means for feeding at least one of the materials to the respective reaction zone and exit means for retrieving treated material from the reaction zone, wherein: additional vessels extend to a depth below the surface sufficient to generate pressure from a hydrostatic head in the entry and/or exit means and at least two of the vessels are adapted for thermal exchange therebetween. 3. The process arrangement of claim 2 wherein at least one of the additional vessels has an entry means comprising at least two tubes. 4. The process arrangement of any preceding claim wherein at least one of the vessels has an entry means comprising an array of tubes having 7 or more tubes. 5. The process arrangement of claim 4 wherein at least one of the vessels has an entry means comprising an array of tubes having 20 or more tubes. 6. The process arrangement of claim 5 wherein at least one of the vessels has an entry means comprising an array of tubes having between 50 and 200 tubes. 7. The process arrangement of claim 5 wherein at least of the vessels has an entry means comprising an array of tubes having more than 200 tubes. 8. The process arrangement of any one of the preceding claims wherein one or more of the vessels extend at least 100 metres below the surface of the ground. 9. The process arrangement of claim 8 wherein one or more of the vessels extend at least 500 metres below the ground surface. 10. The process arrangement of claim 9 wherein the entry means of at least one vessel is formed as continuous tubes. 11. The process arrangement of claim 10 wherein one or more of the continuous tubes have at least part of their side walls formed by rock. 12. The process arrangement of claim 10 wherein one or more of the continuous tube are formed by Interconnected metallic tubular sections. 13. The process arrangement of any one of the preceding claims wherein each of the tubes has a diameter in the range of 250 mm to 100 mm. 14. The processing arrangement of claim 13 wherein each of the tubes has a diameter around 50 mm. 15. The process arrangement of any one of claim 1 to claim 3 wherein the entry means connects the reaction zone to the surface of the ground. 16. The process arrangement of claim 15 wherein the exit means of at least one vessel is formed as a continuous exit tube. 17. The process arrangement of claim 16 wherein the exit tube has at least part of its side walls formed by rock. 18. The process arrangement of claim 16 wherein the exit means of at least one vessel is formed by interconnected tubular sections. 19. The process arrangement of any one of claim 1 to claim 3 wherein one or more exit means connects the reaction zone to the surface of the ground. 20. The process arrangement of any one of claim 1 to claim 3 wherein the exit means of at least one vessel includes one or more gas collectors. 21. The process arrangement of any one of claim 1 to claim 3 wherein the exit means of at least one vessel includes a choking valve to control the back pressure on the treated material. 22. The process arrangement of any of claim 1 to claim 3 wherein the entry means and exit means are formed in a downwardly directed bore. 23. The process arrangement of claim 22 wherein the bore is substantially vertical. 24. The process arrangement of claim 2 or claim 3 wherein the at least two vessels are in heat exchanging proximity to each other. 25. The process arrangement of claim 24 wherein the at least two vessels are adapted for thermal exchange therebetween through heat exchange means. 26. The process arrangement of claim 25 wherein the heat exchange means is a heat transferring wall section common to at least two vessels. 27. The process arrangement of claim 25 wherein the heat exchange means comprises a liquid located in a circulation system wherein the liquid is circulated into heat exchanging contact with at least two vessels. 28. The process arrangement of either claim 1 or claim 2 further comprising an access shaft adapted to provide access below the surface of the ground to at least one vessel. 29. A reactor assembly comprising at least two reaction chambers each formed with an inlet means for delivering process materials to a reaction zone, an outlet means for retrieving treated process materials or their products from the reaction zone wherein the inlet means and outlet means are located in downwardly extending subterranean passages, at least two of the reaction chambers are adapted for thermal exchange therebetween and the inlet means comprises an array of 50 or more tubes. 30. The reactor assembly of claim 29 wherein one or more of the reactor chambers are formed with an extended U shaped configuration. 31. The reactor assembly of claim 29 wherein one of the reaction chambers is located substantially within the confines of at least one other of the reaction chambers. 32. The reactor assembly of claim 29 wherein the reaction chambers are adapted for thermal exchange through heat exchange means. 33. The reactor assembly of claim 32 wherein the heat exchange means comprises a circulation system for circulating a heat conducting liquid into heat exchanging contact with at least two reaction chambers. 34. The reactor assembly of any one of claims 29 to 33 further comprising one or more subterranean communication channels providing a pathway for fluid in an outlet means of one reaction chamber to transfer to an inlet means of another reaction chamber. 35. A method of conducting two processes under pressurised conditions comprising the steps of: introducing materials for a first process Into a first reactor located substantially underground and formed by a downwardly extending inlet tube communicating with a processing zone, said processing zone communicating with an upwardly extending outlet tube arrangement: introducing further materials for a second process into a second reactor located substantially underground and formed by a downwardly extending inlet tube communicating with a processing zone, said processing zone communicating with an upwardly extending outlet tube arrangement, initiating the first and second processes; and transferring heat between the reactors wherein one of the processes is hydrothermal dewatering of coal. 36. The method of claim 35 wherein the other of the processes is coal liquefaction. 37. The method of claim 36 wherein coal which has undergone hydrothermal dewatering in the first process is subject to liquefaction in the second process. 38. A method of hydrothermal dewatering of coal in an underground reactor comprising one or more delivery tubes communicating with a reaction chamber which in turn communicates with one or more exit tubes, the method comprising the steps of: delivering a coal slurry through the one or more delivery tubes to the reaction zone; and initiating the hydrothermal dewatering process such that the process occurs substantially in conditions of decreasing pressure as the material rises in the one or more exit tubes. 39. The method of claim 38 further including the step of: maintaining an upward directed flow of the slurry substantially throughout hydrothermal dewatering of the coal. 40. The method of claim 39 wherein the velocity of material is controlled by pump pressure. 41. The method of claim 39 wherein the upward directed flow of the slurry is maintained throughout hydrothermal dewatering of at least 50% of the coal. 42. The method of claim 38 wherein a velocity of the slurry is in the range of 0.5 metre per second to 3 metres per second. 43. The method of claim 42 wherein the velocity is around 1 metre per second. 44. The method of claim 43 wherein a concentration of coal in the slurry is selected to control the heat production of the reaction and thereby control the temperature in the reaction zone. 45. The method of claim 43 wherein the concentration of as mined coal in the slurry is between 40% weight percentage and 65% weight percentage. 46. The method of claim 45 wherein the concentration of coal in the slurry is around 50% weight percentage. 47. The method of any one of claims 39 to 46 wherein the coal is brown coal.