Patent SG-11201804364S-A (SG)
Title: Methods for gas phase oxidative desulphurization of hydrocarbons using cuznal catalysts promoted with vib metal oxides
Inventor: KOSEOGLU OMER
IPC: B01J23/00
Filed: 2017-01-03
Abstract: INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property -' Organization International Bureau ires.. 00) (43) International Publication Date .... ....r .....) 13 July 2017 (13.07.2017) WI P0 I P CT (10) WO International 1111111111113111111111111111111111111111111111111111111111111111111111111111111111111111 2017/120130 Publication Number Al (51) International Patent Classification: (71) Applicants: SAUDI ARABIAN OIL COMPANY BOM 23/885 (2006.01) BO1J 35/02 (2006.01) [SA/SA]; Box 5000, Dhahran 31311 (SA). BORESKOV B01J 23/00 (2006.01) BO1J 35/10 (2006.01) INSTITUTE OF CATALYSIS [RU/RU]; Lavrentieva 5, B01J 37/03 (2006.01) BOlD 53/48 (2006.01) Novosibirsk 630090 (RU). BO1J 35/00 (2006.01) (72) Inventors; and (21) International Application Number: (71) Applicants (for US only): KOSEOGLU, Omer, Refa PCT/US2017/012017 [US/SA]; P.O. Box 8560, Saudi Aramco, Dhahran 31311 (SA). JIN, Yaming [US/SA]; P.O. Box 5060, Saudi Ara- (22) International Filing Date: mco, Dhahran 31311 (SA). ISMAGILOV, Zinfer 3 January 2017 (03.01.2017) [RU/RU]; Ul. Pravdy 1, Apt. 3, Novosibirsk 630090 (RU). (25) Filing Language: English YASHNIK, Svetlana [RU/RU]; Ul. Uchenykh 8, Apt. 116, Novosibirsk 630090 (RU). SALNIKOV, Anton (26) Publication Language: English [RU/RU]; Ul. Polevaya 14, Apt. 128, Novosibirsk 630128 (30) Priority Data: (RU). KERZHENTSEV, Mikhail [RU/MD]; Ul. Pol- 14/987,141 4 January 2016 (04.01.2016) US evaya 14, Apt. 128, Novosibirsk 630128 (RU). PARMON, Valentin [RU/RU]; Ul. Voyevodskogo 4, Novosibirsk 630128 (RU). (74) Agent: HANSON, Norman, D.; Abelman, Frayne & Schwab, 666 Third Avenue, New York, NY 10017 (US). [Continued on next page] (54) Title: METHODS FOR GAS PHASE OXIDATIVE DESULPHURIZATION OF HYDROCARBONS USING CUZNAL CATALYSTS PROMOTED WITH VIB METAL OXIDES (57) : A catalytic composition is disclosed, which exhibits an X- foiinula, ZnO, CuO, Fla 1 ray amorphous oxide with a spinel and crystals of and at least one Group VIB metal oxide, and preferably, at least one acid - Sulfur removal ; % A (Liquid phasei analysis) is oxide of B, P, or Si, as well. The composition is useful in oxidative 4n for removing sulfur from gaseous hydrocarbons. processes Su lfur remova l, % N. ) C O a d i 0 CD 0 0 CD 0 0 C;) O C --A--V628 -4--V637 -0-V653 4t-- --- -t ------- ..e -------' . 4V 325 350 400 425 450 Bed Temperature (`C) B Ratio: Sulfur Removal to Fuel Oxidation ) 130 Al 111111111111111 20 -8-V628 c o ,-3 -A-V636 Qzi 16 -c-- - ves - 7 - - 7 --E-V653 o 7312 >, ° 8 0 E 2 ..... Il 0 325 350 375 400 425 450 Bed Temperature CC) IN Il C ei O WO 2017/120130 Al I IIIII IMOMOIDIONOIDEMOMOHMIIMMIONIONVOIMIE (81) Designated States (unless otherwise indicated, for every (84) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, kind of regional protection available): ARIPO (BW, GH, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, LY, NA, QA, SM, MA, MD, ME, MG, MK, MN, MW, MX, MY, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, MZ, PT, SL, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Published: GA, US, UZ, VC, VN, ZA, ZM, ZW. — with international search report (Art. 21(3))