Patent GB-746809-A (GB)
Title: Improvements in pneumatic tyre and method of making same
IPC: B60C1/00
Filed: 1954-06-28
Abstract: A tubeless tyre comprising a carcase of cord fabric coated with natural rubber or butadienestyrene copolymer has a liner composed of a blend of (A) from 45 to 75 per cent by weight of a reaction product of (1) from 0.1 to 4.0 parts of a 2,6 - dimethylol - 4 - hydrocarbon substituted phenol resin and (2) 100 parts of butyl rubber; and (B) from 55 to 25 per cent of either natural rubber or butadiene-styrene copolymer.  The blend is preferably prepared by first mixing the butyl rubber with 25 to 75 parts of carbon black, adding the resol phenolic resin and then masticating the mix for a time ranging from 3 minutes at 400 DEG  F. to 60 minutes at 300 DEG  F. The reacted butyl is then mixed with natural rubber or butadiene-styrene copolymer which has already been mixed with additional carbon black, the usual compounding agents such as hydrocarbon oil, zinc oxide, stearic acid, benzothiazyldisulphide, tetramethyl thiuram monosulphide and sulphur being added at this stage.  Suitable 2,6-dimethyl-4-hydrocarbon substituted phenols for reacting with the butyl are those wherein the para-hydrocarbon substituent is an alkyl group such as tertiary-butyl or tertiary-octyl, a cycloalkyl group such as cyclohexyl, an aryl group such as phenyl or an aralkyl group such as benzyl and cumyl. The reaction of the butyl rubber may be accelerated by the addition of from 0.1 to 2.0 parts of an accelerator such as a heavy metal chloride, particularly stannous, stannic, iron or zinc chloride, or an organic sulphonic acid such as p-toluene or beta-naphthalene sulphonic acid or mixed alkane sulphonic acids such as a mixture containing methane, ethane and propane sulphonic acids.ALSO:A tubeless tyre comprising a carcase 11 of cord fabric coated with natural or GR-S (butadiene-styrene copolymer) rubber, has a liner 14 composed of a blend of (A) from 45 to 75 per cent by weight of a reaction product of 19 from 0.1 to 4.0 parts of a 2, 6 dimethylol - 4 - hydrocarbon substituted phenol resin and 2) 100 parts of butyl rubber, and (B) from 55 to 25 per cent of either natural or GR-S rubber.  The blend is preferably prepared by first mixing the butyl rubber with 25 to 75 parts of carbon black, adding the resol phenolic resin and then masticating the mix for a time ranging from 3 minutes at 400 DEG F. to 60 minutes at 300 DEG F., preferably for 5 to 25 minutes at 350-375 DEG F.  The reacted butyl is then mixed with natural or GR-S rubber which has already been mixed with additional carbon black, the usual compounding agents such as hydrocarbon oil, zinc oxide, stearic acid, benzothiazyldisulphide, tetramethyl thiuram, monosulphide and sulphur being added at this stage. Suitable 2, 6-dimethylol-4-hydrocarbon substituted phenols for reacting with the butyl are those wherein the para-hydrocarbon substituent is an alkyl group such as tertiary-butyl or tertiary-octyl, a cycloalkyly group such as cyclohexyl, an aryl group such as, phenyl or an aralkyl group such as benzyl and cumyl.  The reaction of the butyl rubber may be accelerated by the addition of from 0.1 to 2.0 parts of an accelerator such as a heavy metal chloride, particularly stannous, stannic, iron or zinc chloride or an organic sulphonic acid such as p-toluen or betanaphthalene sulphonic acids or mixed alkane sulphonic acids such as a mixture containing methane, ethane and propane sulphonic acids.