Patent GB-682703-A (GB)
Title: A process of and apparatus for electrodialyzing liquids
IPC: C25B13/04
Filed: 1950-04-12
Abstract: 682,703. Electro-dialysis. NEDERLANDSE CENTRALE ORGANISATIE VOOR TOEGEPAST - NATUURWETENS - CHAPPELIJK ONDERZOEK. April 12,1950 [April 12, 1949], No. 8974/50. Class 41. In a process for electro-dialysis of a liquid in a three-chamber apparatus the liquid is passed through a middle compartment not wider than 5 mm. in a turbulent state so that its composition is maintained substantially constant. In the apparatus shown in Fig. 1, liquid to be treated is passed by a pump 1 through a pipe 11 into the electro-dialysis cell 20. The distance between the membranes 22 and 23 is less than 5 mm. and the rate of flow is such as to maintain the liquid in a turbulent state. The membrane 22 separates the cell 20 from a cathode cell 25 having an inlet 30 and an outlet 31 for rinsing liquid. The membrane 23 separates the cell 20 from an anode chamber 24, with an inlet 33 and an outlet 32 for the anode rinsing liquid. The liquid from the cell 20 flows through a pipe 41 into an expansion chamber 40, from which liquid may be returned through a pipe 42 to the pump 1 for re-circulation. If the liquid is sufficiently purified or treated, it can be removed through a conduit 2. Treatment may be carried out continuously by adding a small quantity of untreated liquid through conduit 43 and removing an equal quantity of purified liquid from the expansion vessel 40. In the arrangement shown in Fig. 5, a frame 140 contains a refrigerator 141 and six electro-dialysis cells 142 separated by anode and cathode compartments. The liquid to be purified is circulated by pump 143 through a pipe 145, refrigerator 141, cells 142, pipe 146, expansion chamber 147 and conduit 148 back to the pump. The anode rinsing liquid is circulated by a pump 162 and the cathode rinsing liquid by a pump 170. Fresh anode rinsing liquid is supplied from vessel 149 containing a dilute acid and vessel 150 containing a solution of an ionizable salt, while fresh cathode rinsing liquid is supplied from the vessel 150 and from a vessel 151 containing an alkali solution. The electro-dialysis cell may be provided with a frame 70, Fig. 9, of electrically-insulating material, formed with gratings 73 and holes 74, the liquid flowing through the frame in sinuous paths as indicated, whereby the liquid is maintained in a turbulent state. The membranes of the cell may be clamped between the grating and gratings provided in the electrode compartments. Fig. 17 shows a battery of electrodialysis cells in three groups, in each group the cells being connected in parallel both for the liquid to be purified and for the electric current, and the three groups being connected electrically in series. The liquid to be purified is supplied through a pipe line 301 and circulated by a pump 302 through a refrigerator 303 to the battery 300 and through a pipe-line 304 to an expansion vessel 305. Part of the liquid from this vessel is led back to the pump 302, mixed with fresh liquid, and part is led through valve 306 to an expansion vessel 321 of battery 320, which is provided with a refrigerator 323 and a pump 322. The liquid leaving the cells of this battery enters an expansion vessel 325, from which part of the liquid flows to expansion vessel 321 and part to expansion vessel 341 of battery 340. In this battery the purified liquid is removed through valve 346 and pipe-line 347. The rinsing liquids are supplied by pipe-lines 307, 308 to each of the three groups of cells. Examples are given of the application of the process of the invention to the restoration of sour milk to good condition and the production of isinglass from press juice resulting from production of fish meal, syrup and whey powder for human consumption from beet-sugar molasses and concentrated whey, respectively, and a milk sugar bakery product from milk sugar molasses. Specification 637,425 is referred to.