Patent GB-891656-A (GB)
Title: A process for the production of plastics
IPC: C08G18/77
Filed: 1959-03-23
Abstract: In a process for the production of cross-linked plastics of high molecular weight from organic polyisocyanates and linear or branched condensation and/or polymerization products, which products contain at least two hydroxyl groups and have a molecular weight exceeding 800, there is used an aromatic polyisocyanate of the formula <FORM:0891656/IV (a)/1> in which R represents oxygen or sulphur, X represents O-aryl, O-aralkyl, O-cycloalkaryl, S-aryl, S-aralkyl, S-cycloalkaryl, N-(aryl)2, NH-alkaryl, NH-cycloalkaryl or N-aryl-N-alkyl; Y and Z represent the same substituents as X or may represent O-alkyl, O-cycloalkyl, S-alkyl, S-cycloalkyl, N-(alkyl)2 or N-(cycloalkyl)2, and X, Y and Z can be the same or different and can also be unsaturated and/or can contain as further substituents halogen, alkoxy, thioether, carboxylic acid ester or sulphone groups, said polyisocyanates containing at least two NCO groups bonded to an aromatic ring.  The specified polyisocyanates can be used in admixture with a polyisocyanate which is free from phosphorus.  It may be used in amount greater than that necessary for linear lengthening of the chain to give a product containing free NCO groups which can be reacted with a compound of molecular weight below 500 containing at least two hydrogen atoms capable of reacting with such groups.  The resulting product can then be reacted with a further quantity of a diisocyanate which need not be one containing phosphorus.  The mixture of reactants may be applied in a solvent as a coating composition, or may be mixed with fillers and pressed and shaped while hot.  Reaction can also be effected in the presence of water, basic accelerators and emulsifiers to give a foamed product. The polyisocyanates can be prepared by the process of Specification 891,654.  Polyesters, polyethers, polythioethers, polyacetals and polyesteramides are suitable compounds of M.Wt. above 800.  Suitable compounds of M.Wt. below 500 are glycols (which may contain urea, urethane, carbonamide or ester groups or tertiary nitrogen atoms or aromatic ring systems) and diamines.  Fillers for mouldable compositions specified are sawdust, chalk, carbon black or colloidal silica. In an Example (6) polybutylene glycol and di-(p - isocyanatophenyl) phosphoro - (N - methyl-N-phenyl)-monoamidate are reacted, the product is stirred with 1,4-butylene glycol, and the mixture is poured into moulds and heated.ALSO:In a process for the production of foamed cross-linked plastics of high molecular weight from organic polyisocyanates and linear or branched condensation and/or polymerization products, which products contain at least two hydroxyl groups and have a molecular weight exceeding 800, there is used an aromatic polyisocyanate of the formula <FORM:0891656/V/1> in which R represents oxygen or sulphur, X represents o-aryl, o-aralkyl, o-cycloalkaryl, s-aryl, s-aralkyl, s-cycloalkaryl, N(aryl)2, NH-alkaryl, NH-cycloalkaryl or N-aryl-N-alkyl; Y and Z represent the same substituents as X or may represent o-alkyl, o-cycloalkyl, s-alkyl, s-cycloalkyl, N(alkyl)2, or N(cycloalkyl)2, and X, Y and Z can be the same or different and can also be unsaturated and/or can contain as further substituents halogen, alkoxy, thioether, carboxylic, acid, ester or sulphone groups, said polyisocyanates containing at least two NCO groups bonded to an aromatic ring.  The specified polyisocyanates can be prepared by the process of Specification 891,654 and can be used in admixture with a polyisocyanate which is free from phosphorus.  Reaction in the presence of water, basic accelerators and emulsifying agents gives a foamed product. Polyesters, polyethers, polythioethers, polyocetals and polyesteramides are suitable compounds of molecular weight above 800.  In a typical Example (3) there are mixed together an adipic acid/phthalic acid/hexanetriol polyester, an adipic acid/hexanetriol/1,3-butylene glycol polyester and an activator mixture of bisdiethylamino-ethyl adipate and an aqueous solution of the sodium salt of castor oil sulphate. Tri-(p-isocyanatophenyl) phosphate is then stirred in to give a foamed product.