Patent GB-923419-A (GB)
Title: Improvements in or relating to herbicidal compositions
IPC: A01N43/66
Filed: 1959-12-11
Abstract: A plant growth control and herbicidal composition capable when applied in one application at a sufficient rate of imparting both an immediate and a long-lasting soil sterilant effect against the growth of grasses and deep-rooted and leafy plants, comprises as the essntial active ingredients an alkali metal chlorate and a triazine compound having the formula <FORM:0923419/VI/1> wherein X represents a H atom, or a heterocyclic radical containing a nitrogen atom in the ring, or a hydrocarbon radical having from one to eight carbon atoms, which hydrocarbon radical may be substituted, and which is attached to the triazine nucleus through a carbon, oxygen, or sulphur atom or through an imino group of the formula -NR-, where R is a hydrogen atom, or a hydrocarbon radical which contains 1-8 C atoms and which may be substituted, Y and Z, which may be the same or different represent halogen atoms or hydroxyl, mercapto or amino groups or heterocyclic radicals containing an N atom in the ring or hydrocarbon radicals which may be substituted containing 1-8 C p  atoms attached to the triazine nucleus through a C, O or S atom or through an aimino group of the formula -NR-, where R has the meaning defined above. Preferred forms of the compounds are those of the general formula <FORM:0923419/VI/2> wherein R1, R2, R3 and R4 which may be the same or different represent hydrogen or aliphatic hydrocarbon radicals having from one to six carbon atoms, such as methyl, ethyl, isopropyl, butyl, propyl, isobutyl, isoamyl, amyl, tert-butyl, hexyl, isohexyl, sec-butyl, allyl, butenyl, and propenyl, not more than three of R1, R2, R3 and R4 representing hydrogen, and Y representing a halogen atom, such as chlorine or bromine.  These compounds can be used if desired in the form of their amine salts, formed with inorganic or organic acids, such as hydrochloric acid, sulfuric acid, phosphoric acid, acetic acid and formic acid.  In general, it is preferred that one of R1 and R2 and one of R3 and R4 be alkyl, and the other hydrogen.  The chlorates are preferably sodium and potassium and preferably are mixed with a fire-retardant e.g. magnesium chloride, calcium chloride but preferably a polyborate e.g. sodium pentaborate.  The segregation of the materials in the mixture is prevented by co-crystallizing two or more of the components so that they are present together in the crystals composing the composition and preferred combinations are of a mixture of from 10 to 45% of sodium or potassium chlorate co-crystallized with from 90 to 55% of sodium or potassium pentaborate, and of a mixture of from 90 to 55% of sodium or potassium metaborate co-crystallized with from 10 to 45% of sodium or potassium chlorate, with the triazine compound present during the co-crystallization so that it is incorporated in the crystals. The specified active ingredients are 2,4 - dichloro - 6 - methoxy - s - triazine, 2,4-dichloro - 6 - ethylamino - s - triazine, 2 - chloro-4,6 - bis(methoxy) - s - triazine, 2 - chloro - 4,6-bis(allylamino) - s - triazine, 2 - chloro - 4,6-bis(hydroxyethylamino) - s - triazine, 2 - chloro-4 - cyclohexylamino - 6 - cyclohexyl - methylamino - s - triazine, 2 - chloro - 4,6 - bis(piperidyl) - s - triazine, 2 - chloro - 4,6 - bis(morpholino) - s - triazine - 2 - chloro - 4 - methylamino-6 - amino - s - triazine, 2 - chloro - 4 - ethylamino - 6 - amino - s - triazine, 2 - chloro - 4-hydroxyethylamino - 6 - amino - s - triazine, 2-chloro - 4 - diethylamino - 6 - amino - s - triazine, 2,4,6 - tris)methoxy) - s - triazine, 2,4,6-tris(ethoxy) - s - triazine, 2,4,6 - tris (b -chloroethoxy) - s - triazine, 2,4,6 - tris(ethylmercapto) - s - triazine, 2,4,6 - tris(ethylamino)-s - triazine, 2 - amino - 4,6 - bis(diethylamino)-s - triazine, 2 - methyl - 4,6 - bis(amino) - s - triazine, 2,4 - dichloro - 6 - n - propylamino - s - triazine, 2 - chloro - 4 - ethoxy - 6 - ethylamino - s-triazine, 2 - chloro - 4,6 - bis(benzylamino) - s-triazine, 2 - chloro - 4,6 - bis(hydroxyethylamino) - s - triazine, 2,4 - dihydroxy - 6 - diethylamino - s - triazine, 2 - hydroxy - 4,6 - bis (diethylamino) - s - triazine, 2 - ethoxy - 4,6-bis(ethylamino) - s - triazine, 2,4,6 - tris - n - propoxy - s - triazine, 2,4,6 - tris(b - ethoxyethoxy)-s - triazine, 2 - chloro - 4,6 - bis(ethylamino) - s-triazine, 2 - chloro - 4,6 - bis(methylamino) - s-triazine, 2 - chloro - 4 - ethylamino - 6 - methylamino - s - triazine, 2 - chloro - 4 - ethylpropylamino - 6 - ethylamino - s - triazine, 2 - chloro-4,6 - bis(isopropylamino) - s - triazine, 2-bromo - 4,6 - bis(ethylamino) - s - triazine, 2-chloro - 4,6 - bis(n - butylamino) - s - triazine, 2 - chloro - 4,6 - bis (n - propylamino) - s - triazine, 2 - chloro - 4,6 - bis(diethylamino) - s - triazine, 2 - chloro - 4,6 - bis(isoamylamino) - s-triazine, 2 - chloro - 4,6 - bis(diisopropylamino)-s - triazine, 2 - chloro - 4,6 - bis(dimethylamino)-s - triazine, 2 - bromo - 4,6 - bis(isopropylamino)-s - triazine, 2 - chloro - 4 - diethylamino - 6-ethylamino - s - triazine, 2 - bromo - 4 - dimethylamino - 6 - methylamino - s - triazine, 2-bromo - 4,6 - bis(hexylamino) - s - triazine, 2-chloro - 4 - isopropylamino - 6 - diethylamino-s - triazine, 2 - chloro - 4 - tertiary butylamino-6 - ethylamino - s - triazine, 2 - chloro - 4 - tertiary butylamino - 6 - diethylamino - s - triazine, 2 - chloro - 4,6 - bis (tertiary butylamino)-s - triazine, 2 - chloro - 4 - ethylmethylamino-6 - isopropylamino - s - triazine, 2 - bromo - 4,6-bis(isopropylamino) - s - triazine, 2 - chloro - 4,6-bis(ethylamino) - s - triazine, 2 - chloro - 4-ethylamino - 6 - diethylamino - s - triazine, 2-chloro - 4,6 - bis(isopropylamino) - s - triazine, 2 - chloro - 4 - isopropylamino - 6 - diethylamino-s-triazine.