Patent GB-1209312-A (GB)
Title: Improvements in and relating to cross-linkable coating compositions
Inventor: MARRIOTT ANTHONY GEOFFREY
IPC: D06M15/29
Filed: 1967-02-15
Abstract: 1,209,312. Coated flexible sheet materials. DUNLOP CO. Ltd. 2 Feb., 1968 [15 Feb., 1967], No. 7153/67. Heading B2E. [Also in Division D1] A coating on a flexible sheet material is produced by applying to a solid surface a composition comprising water, a polymer whose crosslinking is catalysed by hydrogen ions, and a vaporizable base (defined as a 'basic compound vaporizable at or below the temperature of cross-linking of the polymer and preferably above room temperature), the pH of the composition during its application to the solid surface being greater than 7, drying the composition on the solid surfacing, and heating the dried composition in contact with a surface of the flexible sheet material to vaporize the vaporizable base and cross-link the polymer. The solid surface to which the composition is applied initially is either a surface of the flexible sheet material or a release surface, the film of dried composition being subsequently stripped from the release surface by any film transfer technique. The flexible sheet materials employed are natural leather or synthetic flexible sheet materials having the appearance of natural leather, e.g. a mat of interpenetrated crimped continuous filaments bonded together with an elastomeric or resinous material which may have a layer of staple fibres and/or a woven fabric attached to it; cellular plastics material maintained in a compressed condition by means of an adhesive, cellular plastics material attached to a fibrous material or a further cellular plastics material; two superimposed sheets of cellular plastics material at least one of which sheets has a fibrous material distributed within it. A preferred substrate is obtained by saturating a nylon woven fabric with a SBR latex containing resorcinol as filler, laying it while still wet onto a compressed polyesterurethane foam layer and at the same time bringing a needled non-woven fabric comprising nylon filaments and polypropylene fibres onto the other side of the fabric. The polymers specified comprise units derived from the monomers methylol acrylamide,. methylol methacrylamide, an ether of an unsaturated methylol amide, hydroxy ethyl acrylate or methacrylate, hydroxy propyl methacrylate, acrylic acid, methacrylic acid, itaconic acid, cinnamic acid and units derived from one or more further monomers which are copolymerisable therewith, specifically alkyl (>C 4 ) of methacrylic acid, alkyl esters of acrylic acids, e.g. ethylacrylate, butadiene, isoprene, styrene, α- methyl styrene, methyl methacrylate and acrylonitrile. A potentially thermosetting aninoplast e.g. a melamine-aldehyde, urea-formaldehyde or a benzoguanamine-aldehyde resin may be added to the polymeric composition as a crosslinking agent. Examples of suitable vaporizable bases are ammonia, morpholine, trimethylamine, triethylamine and diethylaminoethanol. The cross-linking may be accelerated by the use of an acid catalyst and/or by heating. The polymer may be present as a solution, dispersion, emulsion in the water and the composition may also include a pigment arid/or a plasticiser. The composition may be applied to solid surface by spraying, brushing or dipping. The coating on the solid surface may be embossed before the polymer has been substantially cross-linked. If the solid surface is a release surface this may be suitably embossed such that the coating after transfer is embossed. Suitable release surfaces may be of any plastics material, glass, paper or polished metal. The finished product may be used in shoe uppers, shoe linings, upholstery, clothing and handbags.