Patent GB-1115758-A (GB)
Title: Adhesive primer compositions
Inventor: DUMOULIN JEAN
IPC: C09D175/04
Filed: 1966-12-19
Abstract: An adhesive primer composition comprises (a) a branched isocyanate terminated organic polymer of M.W. at least 400 and containing 0.1 to 20% by weight of free isocyanate groups, and for each 100 parts by weight of (a); (b) 10 to 100 parts by weight of an organoalkoxysilane of the formula RnR1mSi(OR11)4-m-n where R is a monovalent hydrocarbon radical containing one or more double bonds and is optionally substituted by halogen, an acrylyloxyalkyl or methacrylyloxyalkyl radical, R1 is a monovalent, saturated or aromatic hydrocarbon radical, R11 is alkyl or alkoxyalkyl, n is 1 or 2, m is 0 or 1 and m + n is at most 2 and (c) 50 to 1000 parts by weight of an inert anhydrous organic solvent for (a) and (b).  The primer optionally contains, per 100 parts by weight of (a); (d) up to 100 parts by weight of an alkoxysilane of the formula <FORM:1115758/C3/1> wherein R111 is alkylene of 3 to 6 carbon atoms, RIV is a monovalent hydrocarbon radical, x is 0 or 1, and Y is -NH2, -NH-CrH2r -NH2, or -O-CrH2r-NH2, where r is 2 to 6, the proportions of (a) and (d) being such that the -NCO groups in (a) are in excess of the -NH2 groups in (d).  In examples, the compound (a) is a polymer obtained by reacting trimethylolpropane \sB butanediol-1,3 with toluene 2,4-diisocyanate, compound (b) is vinyl-[tri-(methoxyethoxy)] silane or 3-(trimethoxy) silyl propyl methacrylate, solvent (c) is ethyl acetate and compound (d) when used is (gamma - aminopropyl) triethoxysilane or [(gamma-aminopropoxy) propyl] triethoxysilane.  The primer composition is useful as an undercoat for bonding substrates with a cold-curable organopolysiloxane composition.  A typical organopolysiloxane composition comprises a dihydroxy-dimethylpolysiloxane oil, a dimethylpolysiloxane oil blocked at each end by a trimethylsilyl group, methyl-triacetoxysilane, silica of combustion treated with octamethylcyclotetrasiloxane and optionally such compounds as acetylene black, calcium carbonate, diatomaceous silica, titanium dioxide, a compound of formula C16H36O4SnTi, iron oxide, and ethyl polysilicate.ALSO:Surfaces such as wood, steel, iron, copper, aluminium, glass, cotton, wool, cellulose, acetates, paper, concrete, plaster, ceramics, synthetic resins such as melamine-formaldehyde, urea-formaldehyde, alkyd, acrylic, phenolic and epoxy resins and natural and synthetic rubbers may be coated with compositions comprising (a) a branched, isocyanate-terminated organic polymer of M.W. at least 400 and containing 0.1 to 20% by weight of free isocyanate groups, and for each 100 parts by weight of (a); (b) 10 to 100 parts by weight of an organoalkoxysilane of the formula: RnR\svmSi(OR\yF)4-m-n where R is a monovalent hydrocarbon radical containing one or more double bonds and optionally substituted by halogen, an acrylyloxyalkyl or methacrylyloxyalkyl radical, R\sv is a monovalent, saturated or aromatic hydrocarbon radical, R2\yF is alkyl or alkoxyalkyl, n is 1 or 2, m is 0 or 1, and m + n is at most 2 and (c) 50 to 1000 parts by weight of an inert, anhydrous organic solvent.  The coatings dry and set at ambient temperature to provide waterproof coatings on the various surfaces.